WorldWideScience

Sample records for acid gas emissions

  1. Government review of the countdown companies' 1991 acid gas emissions audits

    Energy Technology Data Exchange (ETDEWEB)

    1993-08-01

    An acid gas emissions verification program was implemented in Ontario in 1990 as part of a program for regulating emissions that are precursors to acid rain. The verification program applied to four companies, three in the metals industry and one electric utility. These emitters were required to limit annual SO[sub 2] and nitrogen oxides emissions to specified levels in stages according to a set schedule. The four companies were required to prepare and submit sulfur mass balance procedures manuals, determine the overall uncertainty of their respective annual emissions, and engage an independent auditor to develop an audit protocol manual and conduct audits of the reported emissions. For Ontario Hydro, the auditor was also required to evaluate the continuous flue gas monitoring systems at the utility's fossil-fuel power plants. The auditors confirmed that the metallurgical companies' reported emissions were within the required limits. For Ontario Hydro, the audit also confirmed that both SO[sub 2] and nitrogen oxide emissions were within the limits specified for 1991. The auditor also indicated that there were no major discrepancies with the procedures manuals that affected the calculated SO[sub 2] and nitrogen oxides emissions. 6 refs., 2 tabs.

  2. Investigating animal health effects of sour gas acid forming emissions

    International Nuclear Information System (INIS)

    Edwards, W.C.

    1992-01-01

    The effects of sour gas well blowout emissions on livestock are reviewed. Guidelines for safe drilling operations in hydrogen sulfide environments, general hazards and characteristics of hydrogen sulfide, and guidelines for field investigation into the effects of sour gas and acid emissions on livestock are discussed. A case history involving the Ross No. 2 gas well blowout of July 1985 in Rankin County, Mississippi is presented. The blowout lasted for 72 days, and at peak discharge the 500 ppM radius was ca 3.5 miles. A cattle embryo transplant operation located one half mile from the well was affected by the blowout. Examination by a local veterinarian of the cattle demonstrated eye irritation, epiphora, nasal discharge and coughing. After one and a half months of exposure, most animals showed clinical signs of a severe dry hacking cough, epiphora, dry rales over the thoracic inlet, and a bronchial popping sound over the lateral thorax. All animals had eye irritation. Of 55 animals showing signs of respiratory distress and eye irritations, 15 were still clinically ill in May of 1986. 7 refs., 1 tab

  3. Retrofit acid gas emission control for municipal waste incineration application of dry sorbent injection

    International Nuclear Information System (INIS)

    Zmuda, J.T.; Smith, P.V.

    1991-01-01

    Dry sorbent injection (DSI) has been successfully demonstrated on coal fired boiler applications as a means of reducing sulfur dioxide emissions. More recently, the dry sorbent injection process was applied to an existing municipal waste incinerator to provide acid gas emission controls. The results obtained from the successful demonstration of the sorbent injection system on an existing municipal incinerator are presented. Removal efficiencies of compounds such as HCl, SO 2 , SO 3 , mercury, and others by the use of sorbent injection are shown. Effects of the DSI system on downstream equipment, such as electrostatic precipitators, fabric filters, ash handling systems, and waste management is included. The impacts of the DSI system on the furnace is also discussed. In this paper a discussion of dry sorbent injection as a means of reducing acid gas and other emissions from existing municipal waste incinerators which may be affected by the regulations is presented. An application case study will outline typical exhaust conditions, expected pollution reductions, capital and operating costs, and type of available sorbents and their costs

  4. Literature review of acid forming emissions in livestock

    International Nuclear Information System (INIS)

    Prior, M.G.; Lopez, A.

    1992-01-01

    A review is presented of the effects of acid forming emissions such as sulfur and nitrogen oxides in livestock. Topics discussed include uptake of airborne pollutants, types of acid-forming pollutants, sources of sulfur-containing emissions, sour gas, and farm animal toxicity caused by carbon disulfide, carbonyl sulfide, ethyl sulfide, methyl sulfide, hydrogen sulfide, methylmercaptan, ethylmercaptan, propylmercaptan, nitrogen oxides, ozone, sulfur, and sulfur dioxide. A review is presented of field data including effects of emissions from gas plants, gas well blowouts, animal nutrition in west central Alberta, and experimental studies on goats and cows. 96 refs., 10 tabs

  5. Power station stack gas emissions

    International Nuclear Information System (INIS)

    Hunwick, Richard J.

    2006-01-01

    There are increasing awareness and pressure to reduce emissions of acid rain and photochemical smog. There is a need to produce new control system and equipment to capture those emissions. The most visible form of pollutions are the chimney smoke, dust and particles of fly ash from mineral matter in the fuel. Acid gases are hard on structures and objects containing limestone. Coal fired power generation is likely to be able to sustain its competitive advantage as a clean source of electricity in comparison with nuclear power and natural gas

  6. Trade-off in emissions of acid gas pollutants and of carbon dioxide in fossil fuel power plants with carbon capture

    International Nuclear Information System (INIS)

    Tzimas, Evangelos; Mercier, Arnaud; Cormos, Calin-Cristian; Peteves, Stathis D.

    2007-01-01

    This paper investigates the impact of capture of carbon dioxide (CO 2 ) from fossil fuel power plants on the emissions of nitrogen oxides (NO X ) and sulphur oxides (SO X ), which are acid gas pollutants. This was done by estimating the emissions of these chemical compounds from natural gas combined cycle and pulverized coal plants, equipped with post-combustion carbon capture technology for the removal of CO 2 from their flue gases, and comparing them with the emissions of similar plants without CO 2 capture. The capture of CO 2 is not likely to increase the emissions of acid gas pollutants from individual power plants; on the contrary, some NO X and SO X will also be removed during the capture of CO 2 . The large-scale implementation of carbon capture is however likely to increase the emission levels of NO X from the power sector due to the reduced efficiency of power plants equipped with capture technologies. Furthermore, SO X emissions from coal plants should be decreased to avoid significant losses of the chemicals that are used to capture CO 2 . The increase in the quantity of NO X emissions will be however low, estimated at 5% for the natural gas power plant park and 24% for the coal plants, while the emissions of SO X from coal fired plants will be reduced by as much as 99% when at least 80% of the CO 2 generated will be captured

  7. Assessment of greenhouse gas emissions from natural gas

    International Nuclear Information System (INIS)

    Anon

    2000-01-01

    The study, 'Assesment of greenhouse gas emission from natural gas' by independent consultants Energetics Pty Ltd, shows that natural gas has significantly fewer greenhouses gas emissions than either black or brown cola for the defined life cycle stages. The life cycle emissions from natural gas use by an Australian Major User are approximately 50% less than the emissions from Victorian brown coal and approximately 38% less than the emissions from Australian average black coal. Australian Best Practice gas fired electricity generation is estimated to emit between 514 and 658 kg CO 2 e/MWh. By comparison, Australian Best Practice coal-fired electricity generation is estimated to emit between 907 and 1,246 kg CO 2 e/MWh for black and brown coal respectively. Greenhouse gas emissions from Australian Best Practice gas-fired electricity generation using combined cycle gas turbines (including full fuel cycle emissions) vary from 41% to 46% of the emissions from brown coal-fired electricity generation and 57% to 64% of emissions from black coal-fired electricity generation. Greenhouse gas emissions from direct gas supply water heating range from 1,470 to 2,042 kilograms per annum. This compares with emissions of 1,922 to 2,499 kg for electric heating from gas-fired electricity generation and 3,975 to 5,393 kg for coal-fired electricity generation. The implications for greenhouse policy nationally are also discussed, emphasising the need to review national energy policy, currently tied to 'fuel neutrality' doctrine

  8. HONO (nitrous acid) emissions from acidic northern soils

    Science.gov (United States)

    Maljanen, Marja; Yli-Pirilä, Pasi; Joutsensaari, Jorma; Martikainen, Pertti J.

    2015-04-01

    The photolysis of HONO (nitrous acid) is an important source of OH radical, the key oxidizing agent in the atmosphere, contributing also to removal of atmospheric methane (CH4), the second most important greenhouse gas after carbon dioxide (CO2). The emissions of HONO from soils have been recently reported in few studies. Soil HONO emissions are regarded as missing sources of HONO when considering the chemical reactions in the atmosphere. The soil-derived HONO has been connected to soil nitrite (NO2-) and also directly to the activity of ammonia oxidizing bacteria, which has been studied with one pure culture. Our hypothesis was that boreal acidic soils with high nitrification activity could be also sources of HONO and the emissions of HONO are connected with nitrification. We selected a range of dominant northern acidic soils and showed in microcosm experiments that soils which have the highest nitrous oxide (N2O) and nitric oxide (NO) emissions (drained peatlands) also have the highest HONO production rates. The emissions of HONO are thus linked to nitrogen cycle and also NO and N2O emissions. Natural peatlands and boreal coniferous forests on mineral soils had the lowest HONO emissions. It is known that in natural peatlands with high water table and in boreal coniferous forest soils, low nitrification activity (microbial production of nitrite and nitrate) limits their N2O production. Low availability of nitrite in these soils is the likely reason also for their low HONO production rates. We also studied the origin of HONO in one peat soil with acetylene and other nitrification inhibitors and we found that HONO production is not closely connected to ammonium oxidation (nitrification). Acetylene blocked NO emissions but did not affect HONO or N2O emissions, thus there is another source behind HONO emission from these soils than ammonium oxidation. It is still an open question if this process is microbial or chemical origin.

  9. Life-cycle greenhouse gas emissions of shale gas, natural gas, coal, and petroleum.

    Science.gov (United States)

    Burnham, Andrew; Han, Jeongwoo; Clark, Corrie E; Wang, Michael; Dunn, Jennifer B; Palou-Rivera, Ignasi

    2012-01-17

    The technologies and practices that have enabled the recent boom in shale gas production have also brought attention to the environmental impacts of its use. It has been debated whether the fugitive methane emissions during natural gas production and transmission outweigh the lower carbon dioxide emissions during combustion when compared to coal and petroleum. Using the current state of knowledge of methane emissions from shale gas, conventional natural gas, coal, and petroleum, we estimated up-to-date life-cycle greenhouse gas emissions. In addition, we developed distribution functions for key parameters in each pathway to examine uncertainty and identify data gaps such as methane emissions from shale gas well completions and conventional natural gas liquid unloadings that need to be further addressed. Our base case results show that shale gas life-cycle emissions are 6% lower than conventional natural gas, 23% lower than gasoline, and 33% lower than coal. However, the range in values for shale and conventional gas overlap, so there is a statistical uncertainty whether shale gas emissions are indeed lower than conventional gas. Moreover, this life-cycle analysis, among other work in this area, provides insight on critical stages that the natural gas industry and government agencies can work together on to reduce the greenhouse gas footprint of natural gas.

  10. Sulphur recovery and sulphur emissions at Alberta sour gas plants : annual report for 2005

    International Nuclear Information System (INIS)

    2005-01-01

    The sulphur recovery of Alberta's grandfathered sour gas plants is monitored by the Alberta Energy and Utilities Board. This report provides an annual summary of industry performance for sulphur recovery at large acid gas flaring sour gas plants, and sulphur recovery at all acid gas injection sour gas plants. It follows Interim Directive (ID) 2001-3 which stipulates guidelines for sulphur recovery for the province of Alberta. It includes a list of grandfathered and non grandfathered plants in Alberta. Grandfathered sulphur recovery plants that exceed expectations have the option to file a sulphur emission performance credit report and can use the credits to meet some of their sulphur requirement in the future. Acid gas flaring plants face more stringent requirements and cannot earn credits. Several plants have degrandfathered in the past 5 years. Eleven have made upgrades, 4 have been relicensed to meet the requirements for new plants, and 4 have shut down. Forty-one grandfathered plants remain. Sulphur emissions have decreased 39 per cent for grandfathered acid gas flaring plants, and 28 per cent for grandfathered sulphur recovery plants. 10 tabs., 3 figs

  11. Flue gas emissions from gas-fired cogeneration units <25 MWe

    International Nuclear Information System (INIS)

    Nielsen, M.; Wit, J. de

    1997-01-01

    A total of 900 MW e gas driven combined heat and power (CHP) has now been established in Denmark based on gas engines and gas turbine units less than 25 MW e each. Of the 900 MW e approx. 750 MW e are based on gas engines. Biogas is used as fuel for some 32 MW e of these. Emission limits for NO x and CO are 650 mg/nm 3 (ref. 5% O 2 and electrical efficiency 30% LCV). There is at present no limit for unburned hydrocarbons (UHC) for gas engines or gas turbines. The average emission of unburned hydrocarbons for the Danish gas engine driven CHP units is equal to approx. 3,5% of the fuel used. It is the target of this report to provide the basis for evaluating the planned UHC limit and possible adjustments of the present limit for NO x emission. The average NO x emission from gas turbines slightly exceeds the NO x emission from gas engines. This is due to a number of older gas turbines. Modern gas turbines can achieve significantly lower NO x emission compared to engines. The NO x emission from biogas driven engines is significantly higher than that of natural gas driven units. This is mainly due to NO x -unfavourable engine settings and the use of older units, as there are no legislation concerning NO x emission for the majority of these biogas driven units. The emission of CO and UHC is lower from gas turbines than from gas engines. The NO x emission can be reduced by SCR Catalyst systems. In Denmark 3 gas engine installations use this commercially available technology. Oxidation catalyst for UHC reduction at modern gas engine installations has proven relatively unsuccesful in Denmark until now. Only limited reductions are achieved and many catalysts are toxificated in less than 100 hours of operation. However, long-term field testing of promising UHC reducing catalysts is now being made. UHC reduction by incineration is at the prototype stage. No such plant has yet been set up in Denmark. (Abstract Truncated)

  12. Shale gas production: potential versus actual greenhouse gas emissions

    OpenAIRE

    O'Sullivan, Francis Martin; Paltsev, Sergey

    2012-01-01

    Estimates of greenhouse gas (GHG) emissions from shale gas production and use are controversial. Here we assess the level of GHG emissions from shale gas well hydraulic fracturing operations in the United States during 2010. Data from each of the approximately 4000 horizontal shale gas wells brought online that year are used to show that about 900 Gg CH[subscript 4] of potential fugitive emissions were generated by these operations, or 228 Mg CH[subscript 4] per well—a figure inappropriately ...

  13. Role of natural gas in meeting an electric sector emissions reduction strategy and effects on greenhouse gas emissions

    International Nuclear Information System (INIS)

    Lenox, Carol; Kaplan, P. Ozge

    2016-01-01

    With advances in natural gas extraction technologies, there is an increase in the availability of domestic natural gas, and natural gas is gaining a larger share of use as a fuel in electricity production. At the power plant, natural gas is a cleaner burning fuel than coal, but uncertainties exist in the amount of methane leakage occurring upstream in the extraction and production of natural gas. At higher leakage levels, the additional methane emissions could offset the carbon dioxide emissions reduction benefit of switching from coal to natural gas. This analysis uses the MARKAL linear optimization model to compare the carbon emissions profiles and system-wide global warming potential of the U.S. energy system over a series of model runs in which the power sector is required to meet a specific carbon dioxide reduction target across a number of scenarios in which the availability of natural gas changes. Scenarios are run with carbon dioxide emissions and a range of upstream methane emission leakage rates from natural gas production along with upstream methane and carbon dioxide emissions associated with production of coal and oil. While the system carbon dioxide emissions are reduced in most scenarios, total carbon dioxide equivalent emissions show an increase in scenarios in which natural gas prices remain low and, simultaneously, methane emissions from natural gas production are higher. - Highlights: • MARKAL analysis of energy system GHG emissions reduction scenarios. • High methane leakage can eliminate the benefit that natural gas brings over coal. • A robust GHG reduction strategy takes into account upstream emissions for all fuels.

  14. Greenhouse gas emissions increase global warming

    OpenAIRE

    Mohajan, Haradhan

    2011-01-01

    This paper discusses the greenhouse gas emissions which cause the global warming in the atmosphere. In the 20th century global climate change becomes more sever which is due to greenhouse gas emissions. According to International Energy Agency data, the USA and China are approximately tied and leading global emitters of greenhouse gas emissions. Together they emit approximately 40% of global CO2 emissions, and about 35% of total greenhouse gases. The developed and developing industrialized co...

  15. Economic growth and greenhouse gas emissions

    Energy Technology Data Exchange (ETDEWEB)

    Ansuategi, Alberto [Environment Department, University of York, York (United Kingdom); Escapa, Marta [Foundations of Economic Analysis Department, University of the Basque Country, Bilbao (Spain)

    2002-01-01

    Recent empirical research has examined the relationship between certain indicators of environmental degradation and income, concluding that in some cases an inverted U-shaped relationship, which has been called an environmental Kuznets curve (EKC), exists between these variables. Unfortunately, this inverted U-shaped relationship does not hold for greenhouse gas emissions. One explanation of the absence of EKC-like behavior in greenhouse gas emissions is that greenhouse gases are special pollutants that create global, not local, disutility. But the international nature of global warming is not the only reason that prevents de-linking greenhouse gas emissions from economic growth. The intergenerational nature of the negative impact of greenhouse gas emissions may have also been an important factor preventing the implementation of greenhouse gas abatement measures in the past. In this paper we explore the effect that the presence of intergenerational spillovers has on the emissions-income relationship. We use a numerically calibrated overlapping generations model of climate-economy interactions. We conclude that: (1) the intertemporal responsibility of the regulatory agency, (2) the institutional capacity to make intergenerational transfers and (3) the presence of intergenerationally lagged impact of emissions constitute important determinants of the relationship between economic growth and greenhouse gas emissions.

  16. Measurement of non-enteric emission fluxes of volatile fatty acids from a California dairy by solid phase micro-extraction with gas chromatography/mass spectrometry

    Science.gov (United States)

    Alanis, Phillip; Sorenson, Mark; Beene, Matt; Krauter, Charles; Shamp, Brian; Hasson, Alam S.

    Dairies are a major source of volatile organic compounds (VOCs) in California's San Joaquin Valley; a region that experiences high ozone levels during summer. Short-chain carboxylic acids, or volatile fatty acids (VFAs), are believed to make up a large fraction of VOC emissions from these facilities, although there are few studies to substantiate this. In this work, a method using a flux chamber coupled to solid phase micro-extraction (SPME) fibers followed by analysis using gas chromatography/mass spectrometry was developed to quantify emissions of six VFAs (acetic acid, propanoic acid, butanoic acid, pentanoic acid, hexanoic acid and 3-methyl butanoic acid) from non-enteric sources. The technique was then used to quantify VFA fluxes from a small dairy located on the campus of California State University Fresno. Both animal feed and animal waste are found to be major sources of VFAs, with acetic acid contributing 70-90% of emissions from the sources tested. Measured total acid fluxes during spring (with an average temperature of 20 °C) were 1.84 ± 0.01, 1.06 ± 0.08, (1.3 ± 0.5) × 10 -2, (1.7 ± 0.2) × 10 -2 and (1.2 ± 0.5) × 10 -2 g m -2 h -1 from silage, total mixed rations, flushing lane, open lot and lagoon sources, respectively. VFA emissions from the sources tested total 390 ± 80 g h -1. The data indicate high fluxes of VFAs from dairy facilities, but differences in the design and operation of dairies in the San Joaquin Valley as well as seasonal variations mean that additional measurements must be made to accurately determine emissions inventories for the region.

  17. Acid Gas Removal from Natural Gas with Alkanolamines

    DEFF Research Database (Denmark)

    Sadegh, Negar

    commercially for the removal of acid gas impurities from natural gas. Alkanolamines, simple combinations of alcohols and ammonia, are the most commonly used category of chemical solvents for acid gas capture. This Ph.D. project is aboutthermodynamics of natural gas cleaning process with alkanolamines......Some 40 % of the world’s remaining gas reserves are sour or acid, containing large quantities of CO2 and H2S and other sulfur compounds. Many large oil and gas fields have more than 10 mole % CO2 and H2S content. In the gas processing industry absorption with chemical solvents has been used...... pressure on acid gas solubility was also quantitatively investigated through both experimental and modeling approaches....

  18. National Greenhouse Gas Emission Inventory

    Data.gov (United States)

    U.S. Environmental Protection Agency — The National Greenhouse Gas Emission Inventory contains information on direct emissions of greenhouse gases as well as indirect or potential emissions of greenhouse...

  19. The greenhouse gas emissions performance of cellulosic ethanol supply chains in Europe

    Directory of Open Access Journals (Sweden)

    Bauen Ausilio

    2009-08-01

    Full Text Available Abstract Background Calculating the greenhouse gas savings that may be attributed to biofuels is problematic because production systems are inherently complex and methods used to quantify savings are subjective. Differing approaches and interpretations have fuelled a debate about the environmental merit of biofuels, and consequently about the level of policy support that can be justified. This paper estimates and compares emissions from plausible supply chains for lignocellulosic ethanol production, exemplified using data specific to the UK and Sweden. The common elements that give rise to the greatest greenhouse gas emissions are identified and the sensitivity of total emissions to variations in these elements is estimated. The implications of including consequential impacts including indirect land-use change, and the effects of selecting alternative allocation methods on the interpretation of results are discussed. Results We find that the most important factors affecting supply chain emissions are the emissions embodied in biomass production, the use of electricity in the conversion process and potentially consequential impacts: indirect land-use change and fertiliser replacement. The large quantity of electricity consumed during enzyme manufacture suggests that enzymatic conversion processes may give rise to greater greenhouse gas emissions than the dilute acid conversion process, even though the dilute acid process has a somewhat lower ethanol yield. Conclusion The lignocellulosic ethanol supply chains considered here all lead to greenhouse gas savings relative to gasoline An important caveat to this is that if lignocellulosic ethanol production uses feedstocks that lead to indirect land-use change, or other significant consequential impacts, the benefit may be greatly reduced. Co-locating ethanol, electricity generation and enzyme production in a single facility may improve performance, particularly if this allows the number of energy

  20. Modelling emissions from natural gas flaring

    Directory of Open Access Journals (Sweden)

    G. Ezaina Umukoro

    2017-04-01

    Full Text Available The world today recognizes the significance of environmental sustainability to the development of nations. Hence, the role oil and gas industry plays in environmental degrading activities such as gas flaring is of global concern. This study presents material balance equations and predicts results for non-hydrocarbon emissions such as CO2, CO, NO, NO2, and SO2 etc. from flaring (combustion of 12 natural gas samples representing composition of natural gas of global origin. Gaseous emission estimates and pattern were modelled by coding material balance equations for six reaction types and combustion conditions with a computer program. On the average, anticipated gaseous emissions from flaring natural gas with an average annual global flaring rate 126 bcm per year (between 2000 and 2011 in million metric tonnes (mmt are 560 mmt, 48 mmt, 91 mmt, 93 mmt and 50 mmt for CO2, CO, NO, NO2 and SO2 respectively. This model predicted gaseous emissions based on the possible individual combustion types and conditions anticipated in gas flaring operation. It will assist in the effort by environmental agencies and all concerned to track and measure the extent of environmental pollution caused by gas flaring operations in the oil and gas industry.

  1. Agricultural sources of greenhouse gas emissions

    International Nuclear Information System (INIS)

    Rochette, P.

    2003-01-01

    The author described different sources of greenhouse gas emissions resulting from agricultural activities and the process by which carbon dioxide, nitrous oxide, and methane are generated on Canadian farms. The author also proposed some practices that would contribute to the reduction of greenhouse gas emissions. A brief description of the greenhouse effect was also provided with special emphasis on the agricultural sector. In 1996, the Canadian agricultural sector was responsible for approximately 10 per cent of greenhouse gas emissions in the country. Given the increase in farm animals and more intensive agricultural activities, it is estimated that greenhouse gas emissions generated by the agricultural sector will increase by 20 per cent by 2010 if current practices remain in effect. The most optimistic scenarios indicate that the agricultural sector could achieve or even exceed Canada's Kyoto Protocol commitments mainly through organic material sequestration in soils. The possibility for farmers to sell greenhouse gas credits could motivate farmers into adopting various practices that reduce emissions of greenhouse gases. However, the author indicated that the best motivation for farmers is the fact that adopting such practices would also lead to more efficient agricultural production. 5 refs., 4 figs

  2. Earthworms change the quantity and composition of dissolved organic carbon and reduce greenhouse gas emissions during composting.

    Science.gov (United States)

    Nigussie, Abebe; Bruun, Sander; de Neergaard, Andreas; Kuyper, Thomas W

    2017-04-01

    Dissolved organic carbon (DOC) has recently been proposed as an indicator of compost stability. We assessed the earthworms' effect on DOC content and composition during composting, and linked compost stability to greenhouse gas emissions and feeding ratio. Earthworms reduced total DOC content, indicating larger stability of vermicompost than of thermophilic compost. The concentrations of humic acid and fulvic acid were reduced by earthworms, whereas there was no significant effect on hydrophobic neutrals and hydrophilics. The humic acid fraction was depleted more quickly than the other compounds, indicating humic acid degradation during composting. The optimum feeding ratio decreased DOC content compared to the high feeding ratio. The lowest N 2 O emissions were also observed at the optimum feeding ratio. Our study confirmed the use of DOC content and composition as an indicator of compost stability and suggested that feeding ratio should be considered when assessing the earthworms' effect on stabilisation and greenhouse gas emissions. Copyright © 2017 Elsevier Ltd. All rights reserved.

  3. Greenhouse gas emissions from hydroelectric reservoirs

    International Nuclear Information System (INIS)

    Rosa, L.P.; Schaeffer, R.

    1994-01-01

    In a recent paper, Rudd et al. have suggested that, per unit of electrical energy produced, greenhouse-gas emissions from some hydroelectric reservoirs in northern Canada may be comparable to emissions from fossil-fuelled power plants. The purpose of this comment is to elaborate these issues further so as to understand the potential contribution of hydroelectric reservoirs to the greenhouse effect. More than focusing on the total budget of carbon emissions (be they in the form of CH 4 or be they in the form of CO 2 ), this requires an evaluation of the accumulated greenhouse effect of gas emissions from hydroelectric reservoirs and fossil-fuelled power plants. Two issues will be considered: (a) global warming potential (GWP) for CH 4 ; and (b) how greenhouse-gas emissions from hydroelectric power plants stand against emissions from fossil-fuelled power plants with respect to global warming

  4. Air quality and greenhouse gas emissions (Chapter 3)

    CSIR Research Space (South Africa)

    Winkler, H

    2016-01-01

    Full Text Available Shale gas development (SGD) presents opportunities and risks with regards to air pollution and greenhouse gas (GHG) emissions. There is a potential opportunity to reduce emissions, if shale gas replaces ‘dirtier’ (more emissions-intensive) fuels...

  5. Reservoir Greenhouse Gas Emissions at Russian HPP

    Energy Technology Data Exchange (ETDEWEB)

    Fedorov, M. P.; Elistratov, V. V.; Maslikov, V. I.; Sidorenko, G. I.; Chusov, A. N.; Atrashenok, V. P.; Molodtsov, D. V. [St. Petersburg State Polytechnic University (Russian Federation); Savvichev, A. S. [Russian Academy of Sciences, S. N. Vinogradskii Institute of Microbiology (Russian Federation); Zinchenko, A. V. [A. I. Voeikov Main Geophysical Observatory (Russian Federation)

    2015-05-15

    Studies of greenhouse-gas emissions from the surfaces of the world’s reservoirs, which has demonstrated ambiguity of assessments of the effect of reservoirs on greenhouse-gas emissions to the atmosphere, is analyzed. It is recommended that greenhouse- gas emissions from various reservoirs be assessed by the procedure “GHG Measurement Guidelines for Fresh Water Reservoirs” (2010) for the purpose of creating a data base with results of standardized measurements. Aprogram for research into greenhouse-gas emissions is being developed at the St. Petersburg Polytechnic University in conformity with the IHA procedure at the reservoirs impounded by the Sayano-Shushenskaya and Mainskaya HPP operated by the RusHydro Co.

  6. Assessing the Greenhouse Gas Emissions from Natural Gas Fired Power Plants

    Science.gov (United States)

    Hajny, K. D.; Shepson, P. B.; Rudek, J.; Stirm, B. H.; Kaeser, R.; Stuff, A. A.

    2017-12-01

    Natural gas is often discussed as a "bridge fuel" to transition to renewable energy as it only produces 51% the amount of CO2 per unit energy as coal. This, coupled with rapid increases in production fueled by technological advances, has led to a near tripling of natural gas used for electricity generation since 2005. One concern with this idea of a "bridge fuel" is that methane, the primary component of natural gas, is itself a potent greenhouse gas with 28 and 84 times the global warming potential of CO2 based on mass over a 100 and 20 year period, respectively. Studies have estimated that leaks from the point of extraction to end use of 3.2% would offset the climate benefits of natural gas. Previous work from our group saw that 3 combined cycle power plants emitted unburned CH4 from the stacks and leaked additional CH4 from equipment on site, but total loss rates were still less than 2.2%. Using Purdue's Airborne Laboratory for Atmospheric Research (ALAR) we completed additional aircraft based mass balance experiments combined with passes directly over power plant stacks to expand on the previous study. In this work, we have measured at 12 additional natural gas fired power plants including a mix of operation types (baseload, peaking, intermediate) and firing methods (combined cycle, simple thermal, combustion turbine). We have also returned to the 3 plants previously sampled to reinvestigate emissions for each of those, to assess reproducibility of the results. Here we report the comparison of reported continuous emissions monitoring systems (CEMS) data for CO2 to our emission rates calculated from mass balance experiments, as well as a comparison of calculated CH4 emission rates to estimated emission rates based on the EPA emission factor of 1 g CH4/mmbtu natural gas and CEMS reported heat input. We will also discuss emissions from a coal-fired plant which has been sampled by the group in the past and has since converted to natural gas. Lastly, we discuss the

  7. CO Emissions from Gas Engines Operating on Biomass Producer Gas

    DEFF Research Database (Denmark)

    Ahrenfeldt, Jesper; Jensen, T. K.; Henriksen, Ulrik Birk

    2004-01-01

    High carbon monoxide (CO) emission from gas engines fueled by producer gas is a concerning problem in the struggle to make biomass gasification for heat and power production a success. CO emissions from engines operating on biomass producer gases are high, especially at very lean conditions where...

  8. OPTIMIZING TECHNOLOGY TO REDUCE MERCURY AND ACID GAS EMISSIONS FROM ELECTRIC POWER PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    Jeffrey C. Quick; David E. Tabet; Sharon Wakefield; Roger L. Bon

    2005-10-01

    Maps showing potential mercury, sulfur, chlorine, and moisture emissions for U.S. coal by county of origin were made from publicly available data (plates 1, 2, 3, and 4). Published equations that predict mercury capture by emission control technologies used at U.S. coal-fired utilities were applied to average coal quality values for 169 U.S. counties. The results were used to create five maps that show the influence of coal origin on mercury emissions from utility units with: (1) hot-side electrostatic precipitator (hESP), (2) cold-side electrostatic precipitator (cESP), (3) hot-side electrostatic precipitator with wet flue gas desulfurization (hESP/FGD), (4) cold-side electrostatic precipitator with wet flue gas desulfurization (cESP/FGD), and (5) spray-dry adsorption with fabric filter (SDA/FF) emission controls (plates 5, 6, 7, 8, and 9). Net (lower) coal heating values were calculated from measured coal Btu values, and estimated coal moisture and hydrogen values; the net heating values were used to derive mercury emission rates on an electric output basis (plate 10). Results indicate that selection of low-mercury coal is a good mercury control option for plants having hESP, cESP, or hESP/FGD emission controls. Chlorine content is more important for plants having cESP/FGD or SDA/FF controls; optimum mercury capture is indicated where chlorine is between 500 and 1000 ppm. Selection of low-sulfur coal should improve mercury capture where carbon in fly ash is used to reduce mercury emissions. Comparison of in-ground coal quality with the quality of commercially mined coal indicates that existing coal mining and coal washing practice results in a 25% reduction of mercury in U.S. coal before it is delivered to the power plant. Further pre-combustion mercury reductions may be possible, especially for coal from Texas, Ohio, parts of Pennsylvania and much of the western U.S.

  9. Greenhouse gas emission from Australian coal mining

    International Nuclear Information System (INIS)

    Williams, D.

    1998-01-01

    Since 1997, when the Australian Coal Association (ACA) signed a letter of Intent in respect of the governments Greenhouse Challenge Program, it has encouraged its member companies to participate. Earlier this year, the ACA commissioned an independent scoping study on greenhouse gas emissions in the black coal mining industry This was to provide background information, including identification of information gaps and R and D needs, to guide the formulation of a strategy for the mitigation of greenhouse gas emissions associated with the mining, processing and handling of black coals in Australia. A first step in the process of reducing emission levels is an appreciation of the source, quantity and type of emissions om nine sites. It is shown that greenhouse gas emissions on mine sites come from five sources: energy consumption during mining activities, the coal seam gas liberated due to the extraction process i.e. fugitive emissions, oxidation of carbonaceous wastes, land use, and embodied energy. Also listed are indications of the degree of uncertainty associated with each of the estimates

  10. Does Increased Extraction of Natural Gas Reduce Carbon Emissions?

    International Nuclear Information System (INIS)

    Aune, F.R.; Golombek, R.; Kittelsen, S.A. C.

    2004-01-01

    Without an international climate agreement, extraction of more natural gas could reduce emissions of CO2 as more 'clean' natural gas may drive out ''dirty'' coal and oil. Using a computable equilibrium model for the Western European electricity and natural gas markets, we examine whether increased extraction of natural gas in Norway reduces global emissions of CO2. We find that both in the short run and in the long run total emissions are reduced if the additional quantity of natural gas is used in gas power production in Norway. If instead the additional quantity is exported directly, total emissions increase both in the short run and in the long run. However, if modest CO2-taxes are imposed, increased extraction of natural gas will reduce CO2 emissions also when the additional natural gas is exported directed

  11. Uncertainties in the Norwegian greenhouse gas emission inventory

    Energy Technology Data Exchange (ETDEWEB)

    Flugsrud, Ketil; Hoem, Britta

    2011-11-15

    The national greenhouse gas (GHG) emission inventory is compiled from estimates based on emission factors and activity data and from direct measurements by plants. All these data and parameters will contribute to the overall inventory uncertainty. The uncertainties and probability distributions of the inventory input parameters have been assessed based on available data and expert judgements.Finally, the level and trend uncertainties of the national GHG emission inventory have been estimated using Monte Carlo simulation. The methods used in the analysis correspond to an IPCC tier 2 method, as described in the IPCC Good Practice Guidance (IPCC 2000) (IPCC 2000). Analyses have been made both excluding and including the sector LULUCF (land use, land-use change and forestry). The uncertainty analysis performed in 2011 is an update of the uncertainty analyses performed for the greenhouse gas inventory in 2006 and 2000. During the project we have been in contact with experts, and have collected information about uncertainty from them. Main focus has been on the source categories where changes have occured since the last uncertainty analysis was performed in 2006. This includes new methodology for several source categories (for example for solvents and road traffic) as well as revised uncertainty estimates. For the installations included in the emission trading system, new information from the annual ETS reports about uncertainty in activity data and CO2 emission factor (and N2O emission factor for nitric acid production) has been used. This has improved the quality of the uncertainty estimates for the energy and manufacturing sectors. The results show that the uncertainty level in the total calculated greenhouse gas emissions for 2009 is around 4 per cent. When including the LULUCF sector, the total uncertainty is around 17 per cent in 2009. The uncertainty estimate is lower now than previous analyses have shown. This is partly due to a considerable work made to improve

  12. Effect of different dietary strategies on gas emissions and growth performance in post- weaned piglets

    Directory of Open Access Journals (Sweden)

    G. Montalvo

    2013-10-01

    Full Text Available The objective of this study was to assess the effects of different dietary strategies in post-weaned piglets on gas emissions and animal performance. Eighty piglets were allotted in ten environmentally-controlled chambers. Piglets were fed with five different isoenergetic diets: control, low protein (LP, inclusion of sugar beet pulp (SBP, addition of benzoic acid (BA and a combination of LP, SBP and BA (LP+SBP+BA. The gases analyzed were ammonia (NH3, methane (CH4, nitrous oxide (N2O and carbon dioxide (CO2. For NH3, the most effective treatment was LP, with a reduction of 61%. The LP+SBP+BA reduced NH3 emission by 51%, the inclusion of SBP by 43% and the least effective technique was BA, which decreased by 9.5%, compared to control. The CH4 emission was reduced by 30% for LP, but was increased by 23% for SBP and 24.6% for LP+SBP+BA. Benzoic acid did not differ from control group. The N2O emission did not show statistically differences, and CO2 and carbon dioxide equivalent (CO2eq emission increased with LP+SBP+BA (14 and 15% respectively, but were not affected by other diets. No effect of dietary treatment was observed on the growth performances compared with control group (p >0.05. We can conclude that the best technique to reduce NH3 emission was LP. Inclusion of SBP decreases NH3 emission, but can increase greenhouse gas emissions. It would be interesting to evaluate the effect of higher percentages of BA because the promising results. Combining techniques is not a good strategy to obtain an additive effect in gas emissions reduction.

  13. Problems in maintenance of herd health associated with acid forming emissions

    International Nuclear Information System (INIS)

    Kostuch, M.

    1992-01-01

    The effects of sour gas plant emissions on dairy herds are described. A veterinarian establishing a practice in Rocky Mountain House, Alberta, found that dairy herds in that area suffered from a disproportionately higher occurrence of health problems than Minnesota herds with similar types of management. These problems are postulated to result from acid-forming emissions from two large sour gas plants in the area (the Ram River and Gulf Strachan plants). Health problems found in dairy cattle in the Rocky Mountain House area were: unthriftiness, increased susceptibility to infectious diseases, reproductive problems, and 'downer' animals (cows unable to stand up unassisted). Problems related to the reproductive organs were the most apparent. Clinical observations of problems in dairy herds are described. Since the levels of emissions from the plants have decreased, incidence of problems in dairy herds has also decreased. 1 ref., 2 figs

  14. Characterisation of acid pollutant emissions in ceramic tile manufacture

    Directory of Open Access Journals (Sweden)

    Monfort, E.

    2011-08-01

    Full Text Available One of the environmental impacts associated with ceramics manufacture is the air emission of acid compounds stem from the presence of impurities in the raw materials and/or fuels. The present study was undertaken to identify the significant gaseous pollutants of an acid nature, to determine their concentrations, and to obtain the characteristic emission factors in spray dryers and firing kilns. The results show that, in spray dryers, the emission levels of the different acid pollutants are far below the current emission limit values applied in the European Union (EU. In firing kilns, the most significant acid pollutant emissions, compared with the recommended EU emission limit values (ELV-BAT, correspond to HF and HCl emissions, indicating that these emissions need to be corrected by appropriate cleaning systems before such emissions are released into the air. On the other hand, the results indicate that SO2 and NOx emissions in the Castellón industrial ceramic sector lie below the ELV–BAT proposed in the European ceramic industry BREF, owing to the widespread use of natural gas as fuel and of raw materials with reduced sulphur contents.

    Uno de los impactos medioambientales asociado a la fabricación de productos cerámicos es la emisión a la atmósfera de compuestos ácidos debido a la presencia de impurezas en las materias primas y/o combustibles. Los objetivos del presente estudio son: identificar los contaminantes gaseosos de naturaleza ácida significativos, determinar su concentración y obtener factores de emisión de los secaderos por atomización y los hornos de cocción. Los resultados obtenidos, en el caso de los secaderos por atomización, muestran que los niveles de emisión de los diferentes contaminantes ácidos se encuentran alejados de los valores límite de emisiones aplicados actualmente en la Unión Europea (UE. En cuanto a los hornos de cocción, la emisión más significativa de

  15. Methane emissions from the natural gas industry

    International Nuclear Information System (INIS)

    Harrison, M.R.; Cowgill, R.M.; Campbell, L.M.; Lott, R.A.

    1993-01-01

    The U.S. EPA and the United Nation's Intergovernmental Panel on Climate Change (IPCC) have suggested that global warming could be reduced if more energy was generated using natural gas rather than fuels such as coal. An increased use of natural gas instead of coal would decrease global warming since methane emits less carbon dioxide (CO 2 ) than any fossil fuel. However, methane is a more potent as a greenhouse gas than CO 2 , and leakage from the gas system could reduce or eliminate the inherent advantage of natural gas. For this reason, methane emissions must be quantified before a national policy on preferred fuels is developed. Therefore, GRI and EPA have developed this confunded program to quantify methane emissions from the U.S. gas industry. This paper presents, for general industry review, the approach and methodology that the project is using to determine the emissions. The study will measure or calculate all gas industry methane emissions - from production at the wellhead, through the system, to the customer's meter. When these data are combined with data from other studies, a definitive comparison of the relative environmental impact of using methane versus other fuels will be possible. The study will also provide data that can be used by the industry to identify cost-effective mitigation techniques to reduce losses. The methane emissions project is being conducted in three phases: the first two phases have identified and ranked all known potential methane-emitting sources and established methods for measuring, calculating, and extrapolating emissions from those sources. The third phase, which is currently in progress, will gather sufficient data to achieve the accuracy goal. This paper briefly summarizes the methodology being used for the completion of the third phase

  16. Suggested guidelines for gas emission monitoring at danish landfills

    DEFF Research Database (Denmark)

    Kjeldsen, Peter; Scheutz, Charlotte

    2015-01-01

    Landfill gas is produced on waste disposal sites receiving organic waste resulting in emission of methane. Regulation requires that the landfill gas is managed in order to reduce emissions, but very few suggestions exist to how the landfill gas management activities are monitored, what requirements...... to the ability of the landfill gas management to reduce the emission should be set up, and how criteria are developed for when the monitoring activities can be terminated. Monitoring procedures are suggested centred on a robust method for measuring the total methane emission from the site, and quantitative...

  17. Greenhouse gas emissions related to Dutch food consumption

    NARCIS (Netherlands)

    Kramer, KJ; Moll, HC; Nonhebel, S; Wilting, HC

    The consumption of food products involves emissions of greenhouse gases. Emissions occur in the various stages of the life cycle of food products. In this paper we discuss the greenhouse gas emissions, CO2, CH4, and N2O, related to Dutch household food consumption. Combinations of greenhouse gas

  18. Greenhouse gas emissions from shale gas and coal for electricity generation in South Africa

    Directory of Open Access Journals (Sweden)

    Brett Cohen

    2014-03-01

    Full Text Available There is increased interest, both in South Africa and globally, in the use of shale gas for electricity and energy supply. The exploitation of shale gas is, however, not without controversy, because of the reported environmental impacts associated with its extraction. The focus of this article is on the greenhouse gas footprint of shale gas, which some literature suggests may be higher than what would have been expected as a consequence of the contribution of fugitive emissions during extraction, processing and transport. Based on some studies, it has been suggested that life-cycle emissions may be higher than those from coal-fired power. Here we review a number of studies and analyse the data to provide a view of the likely greenhouse gas emissions from producing electricity from shale gas, and compare these emissions to those of coal-fired power in South Africa. Consideration was given to critical assumptions that determine the relative performance of the two sources of feedstock for generating electricity � that is the global warming potential of methane and the extent of fugitive emissions. The present analysis suggests that a 100-year time horizon is appropriate in analysis related to climate change, over which period the relative contribution is lower than for shorter periods. The purpose is to limit temperature increase in the long term and the choice of metric should be appropriate. The analysis indicates that, regardless of the assumptions about fugitive emissions and the period over which global warming potential is assessed, shale gas has lower greenhouse gas emissions per MWh of electricity generated than coal. Depending on various factors, electricity from shale gas would have a specific emissions intensity between 0.3 tCO2/MWh and 0.6 tCO2/MWh, compared with about 1 tCO2/MWh for coal-fired electricity in South Africa.

  19. Monitoring greenhouse gas emissions from landfill sites

    International Nuclear Information System (INIS)

    Eade, G.

    2001-01-01

    Methane is the chief component of natural gas, but also occurs naturally by the anaerobic decomposition of organic matter in swamp areas, at landfill sites, in fact at any location where organic deposits are present. Carbon dioxide is also produced by the decomposition of organic material as well as being the primary by-product of combustion. This article focuses on techniques to test a wide variety of combustible and toxic gases, including surface emission testing of landfill sites. Specifically, it describes the Methane Emission Monitoring System (MEMS) developed by Hetek Solutions Inc., whose primary objective is to to effectively locate surface emissions of methane gas from active landfill sites using flame ionization (FI) technology, and to plot the 'hot spots' using a Differential Global Positioning System (DGPS), which provides sub-metre accuracy for plotting emissions locations at landfill sites. The FI equipment is installed on all-terrain vehicles (ATVs). Several thousand kilometers of pipeline inspections have been performed in Alberta and Saskatchewan using this system in the mid-1990s. The mobile FI/ATV units have been redesigned for landfill gas emission testing, equipped with new DGPS equipment and interface software. They meet the New Source Performance Standards (NSPS) drafted in the United States in 1996, which requires all landfill sites to be inspected for methane gas emissions. Using the FI/ATV combination, productivity over conventional walking inspection procedures increased some 400 per cent, while monitoring accuracy is equivalent to or better than those provided by previous conventional methods. The company can also provide the Optical Methane Detector (OMD) system using infrared technology. They are capable of performing 14,000 measurements per second, thus providing immediate response. To date, ATV emissions testing has been proven to be very effective in various types of gas detection. When interfaced with DGPS technology, computer

  20. Greenhouse Gas and Noxious Emissions from Dual Fuel Diesel and Natural Gas Heavy Goods Vehicles.

    Science.gov (United States)

    Stettler, Marc E J; Midgley, William J B; Swanson, Jacob J; Cebon, David; Boies, Adam M

    2016-02-16

    Dual fuel diesel and natural gas heavy goods vehicles (HGVs) operate on a combination of the two fuels simultaneously. By substituting diesel for natural gas, vehicle operators can benefit from reduced fuel costs and as natural gas has a lower CO2 intensity compared to diesel, dual fuel HGVs have the potential to reduce greenhouse gas (GHG) emissions from the freight sector. In this study, energy consumption, greenhouse gas and noxious emissions for five after-market dual fuel configurations of two vehicle platforms are compared relative to their diesel-only baseline values over transient and steady state testing. Over a transient cycle, CO2 emissions are reduced by up to 9%; however, methane (CH4) emissions due to incomplete combustion lead to CO2e emissions that are 50-127% higher than the equivalent diesel vehicle. Oxidation catalysts evaluated on the vehicles at steady state reduced CH4 emissions by at most 15% at exhaust gas temperatures representative of transient conditions. This study highlights that control of CH4 emissions and improved control of in-cylinder CH4 combustion are required to reduce total GHG emissions of dual fuel HGVs relative to diesel vehicles.

  1. Emissions from hydroelectric reservoirs and comparison of hydroelectricity, natural gas and oil

    International Nuclear Information System (INIS)

    Gagnon, L.; Chamberland, A.

    1993-01-01

    When reservoirs are created, a small fraction of the flooded organic matter decomposes into humic acids, carbon dioxide (CO 2 ), methane (CH 4 ), nitrogen, phosphorus, and other elements. The major greenhouse gases produced are CO 2 and CH 4 . For northern projects, Canadian studies on emissions from hydroelectric reservoirs have reached similar conclusions: Emissions, including methane, are less than 35 kg CO 2 equivalent per MWh. Using a typical project in northern Quebec as the basis for analysis, none of the studies dispute the considerable advantages of hydroelectricity regarding greenhouse gas emissions. Taking into account all components of energy systems, emissions of greenhouse gases from natural-gas power plants are 24 to 26 times greater than emissions from hydroelectric plants. The Freshwater Institute, in an article published in Ambio suggests that emissions from hydroelectric plants could be a significant source of greenhouse gases. This conclusion does not apply to most hydroelectric projects for two reasons: First, the Freshwater Institute's studies concerned flooded peatlands and shallow reservoirs that are not typical of most hydro projects; and second, the Institute analyzed a hydro project with a ratio of flooded area to energy production that is 6 to 10 times higher than typical projects in Canada. 7 refs, 4 tabs

  2. Role of natural gas in meeting an electric sector emissions ...

    Science.gov (United States)

    With advances in natural gas extraction technologies, there is an increase in availability of domestic natural gas, and natural gas is gaining a larger share of use as a fuel in electricity production. At the power plant, natural gas is a cleaner burning fuel than coal, but uncertainties exist in the amount of methane leakage occurring upstream in the extraction and production of natural gas. At high leakage levels, these methane emissions could outweigh the benefits of switching from coal to natural gas. This analysis uses the MARKAL linear optimization model to compare the carbon emissions profiles and system-wide global warming potential of the U.S. energy system over a series of model runs in which the power sector is asked to meet a specific CO2 reduction target and the availability of natural gas changes. Scenarios are run with a range of upstream methane emission leakage rates from natural gas production. While the total CO2 emissions are reduced in most scenarios, total greenhouse gas emissions show an increase or no change when both natural gas availability and methane emissions from natural gas production are high. Article presents summary of results from an analyses of natural gas resource availability and power sector emissions reduction strategies under different estimates of methane leakage rates during natural gas extraction and production. This was study was undertaken as part of the Energy Modeling Forum Study #31:

  3. Coal fired flue gas mercury emission controls

    International Nuclear Information System (INIS)

    Wu, Jiang; Pan, Weiguo; Cao, Yan; Pan, Weiping

    2015-01-01

    Mercury (Hg) is one of the most toxic heavy metals, harmful to both the environment and human health. Hg is released into the atmosphere from natural and anthropogenic sources and its emission control has caused much concern. This book introduces readers to Hg pollution from natural and anthropogenic sources and systematically describes coal-fired flue gas mercury emission control in industry, especially from coal-fired power stations. Mercury emission control theory and experimental research are demonstrated, including how elemental mercury is oxidized into oxidized mercury and the effect of flue gas contents on the mercury speciation transformation process. Mercury emission control methods, such as existing APCDs (air pollution control devices) at power stations, sorbent injection, additives in coal combustion and photo-catalytic methods are introduced in detail. Lab-scale, pilot-scale and full-scale experimental studies of sorbent injection conducted by the authors are presented systematically, helping researchers and engineers to understand how this approach reduces the mercury emissions in flue gas and to apply the methods in mercury emission control at coal-fired power stations.

  4. Coal fired flue gas mercury emission controls

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Jiang; Pan, Weiguo [Shanghai Univ. of Electric Power (China); Cao, Yan; Pan, Weiping [Western Kentucky Univ., Bowling Green, KY (United States)

    2015-05-01

    Mercury (Hg) is one of the most toxic heavy metals, harmful to both the environment and human health. Hg is released into the atmosphere from natural and anthropogenic sources and its emission control has caused much concern. This book introduces readers to Hg pollution from natural and anthropogenic sources and systematically describes coal-fired flue gas mercury emission control in industry, especially from coal-fired power stations. Mercury emission control theory and experimental research are demonstrated, including how elemental mercury is oxidized into oxidized mercury and the effect of flue gas contents on the mercury speciation transformation process. Mercury emission control methods, such as existing APCDs (air pollution control devices) at power stations, sorbent injection, additives in coal combustion and photo-catalytic methods are introduced in detail. Lab-scale, pilot-scale and full-scale experimental studies of sorbent injection conducted by the authors are presented systematically, helping researchers and engineers to understand how this approach reduces the mercury emissions in flue gas and to apply the methods in mercury emission control at coal-fired power stations.

  5. Acid gas control process and apparatus for waste fired incinerators

    International Nuclear Information System (INIS)

    Kubin, P.Z.; Stepan, J.E.

    1992-01-01

    This patent describes a process for reducing noxious emission produced in a waste material incinerator. It comprises incinerating solid waste material in a furnace section of the waste material incinerator; providing an additive to an additive supply storage unit; conveying the additive to an additive injection means that communicates with the furnace section of the waste material incinerator; injecting the additive into a turbulent reaction zone of the furnace section such that acid gas content, acid dewpoint temperature and the level of corrosion in the incinerator are reduced

  6. Estimating greenhouse gas emissions using emission factors from the Sugarcane Development Company, Ahvaz, Iran

    Directory of Open Access Journals (Sweden)

    Amir Zahedi

    2018-05-01

    Full Text Available Background: Greenhouse gas (GHG emissions are increasing worldwide. They have harmful effects on human health, animals, and plants and play a major role in global warming and acid rain. Methods: This research investigated carbon dioxide (CO2 and CH4 emissions obtained from different parts of the Hakim Farabi, Dobal Khazaei, and Ramin factories which produce ethanol and yeast. Seasonal rates of CO2 at the soil surface at the studied sites were estimated from measurements made on location and at intervals with manual chambers. This study aimed to assess the production rate of GHG emissions (CH4, CO2 in the sugar production units of Hakim Farabi, Dobal Khazaei, and Ramin factories. Results: Mean concentrations of CO2 and CH4 emissions are respectively 279 500.207 and 3087.07 tons/ year from the Hakim Farabi agro-industry, 106 985.24 and 1.14 tons/year at the Dobal Khazaei ethanol producing factory, and 124 766.17 and 1.93 tons/year at the Ramin leavening producing factory. Conclusion: Sugar plant boilers and the burning of sugarcane contributed the most CO2 and CH4 emissions, respectively. Moreover, lime kilns and diesel generators showed the least carbon dioxide and methane emissions, respectively.

  7. Future forecast for life-cycle greenhouse gas emissions of LNG and city gas 13A

    International Nuclear Information System (INIS)

    Okamura, Tomohito; Furukawa, Michinobu; Ishitani, Hisashi

    2007-01-01

    The objective of this paper is to analyze the most up-to-date data available on total greenhouse-gas emissions of a LNG fuel supply chain and life-cycle of city gas 13A based on surveys of the LNG projects delivering to Japan, which should provide useful basic-data for conducting life-cycle analyses of other product systems as well as future alternative energy systems, because of highly reliable data qualified in terms of its source and representativeness. In addition, the life-cycle greenhouse-gas emissions of LNG and city-gas 13A in 2010 were also predicted, taking into account not only the improvement of technologies, but also the change of composition of LNG projects. As a result of this analysis, the total amount of greenhouse-gas emissions of the whole city-gas 13A chain at present was calculated to be 61.91 g-CO 2 /MJ, and the life-cycle greenhouse-gas emissions of LNG and city-gas 13A in 2010 could be expected to decrease by about 1.1% of the current emissions

  8. Lifecycle greenhouse gas emissions of coal, conventional and unconventional natural gas for electricity generation

    Science.gov (United States)

    An analysis of the lifecycle greenhouse gas (GHG) emissions associated with natural gas use recently published by Howarth et al. (2011) stated that use of natural gas produced from shale formations via hydraulic fracturing would generate greater lifecycle GHG emissions than petro...

  9. Emissions credits from natural gas vehicles

    International Nuclear Information System (INIS)

    Anderson, J.F.; Kodjak, D.

    1997-01-01

    Dedicated natural gas vehicles (NGVs) often are capable of testing to lower than federally required engine certification standards. NGVs often meet inherently low emission vehicle (ILEV) and ultra low emission vehicle (ULEV) standards. Over the useful life of the vehicle, a significant amount of mobile source emission reduction credits (MSERCs) can be generated. This paper will discuss key elements of establishing a workable methodology to quantify the emissions benefits generated through the purchase and use of heavy-duty natural gas vehicles instead of heavy-duty diesel vehicles. The paper will focus on a public fleet of transit buses owned by the Massachusetts Bay Transit Agency, the Massachusetts Port Authority, and a private fleet of waste haulers. Public fleets may generate emission credits as a key compliance option to offset emission shortfalls from changes to the Employee Commute Options (ECO) program, the Inspection and Maintenance program, and facilitate annual surface transportation conformity. Private fleets may generate emission credits for open market trading to area and stationary sources seeking to buy credits from mobile sources, where allowed by EPA and state policy

  10. Opportunities to reduce methane emissions in the natural gas industry

    Energy Technology Data Exchange (ETDEWEB)

    Cowgill, R.M. [Radian Corporation, Austin, TX (United States)

    1995-12-31

    The U.S. Environmental Protection Agency (EPA) and the Gas Research Institute (GRI) cofunded a project to quantify methane (CH{sub 4}) emissions from the U.S. natural gas industry. Methane, the major constituent of natural gas, is a potent greenhouse gas that is believed to increase the effect of global warming when released to the atmosphere. Reducing emissions from natural gas systems would lessen the greenhouse gas effect attributable to atmospheric CH{sub 4}. Further, mitigation methods to reduce emissions of natural gas, a marketable resource, could save money and increase energy efficiency. This presentation summarizes the major sources and quantity of methane being emitted to the atmosphere for all segments of the U.S. gas industry: production; processing; storage; transmission; and distribution. A description of how those emissions were determined is included here, as well as a discussion of which sources are potential candidates for reducing emissions. (author)

  11. Opportunities to reduce methane emissions in the natural gas industry

    Energy Technology Data Exchange (ETDEWEB)

    Cowgill, R M [Radian Corporation, Austin, TX (United States)

    1996-12-31

    The U.S. Environmental Protection Agency (EPA) and the Gas Research Institute (GRI) cofunded a project to quantify methane (CH{sub 4}) emissions from the U.S. natural gas industry. Methane, the major constituent of natural gas, is a potent greenhouse gas that is believed to increase the effect of global warming when released to the atmosphere. Reducing emissions from natural gas systems would lessen the greenhouse gas effect attributable to atmospheric CH{sub 4}. Further, mitigation methods to reduce emissions of natural gas, a marketable resource, could save money and increase energy efficiency. This presentation summarizes the major sources and quantity of methane being emitted to the atmosphere for all segments of the U.S. gas industry: production; processing; storage; transmission; and distribution. A description of how those emissions were determined is included here, as well as a discussion of which sources are potential candidates for reducing emissions. (author)

  12. Opportunities to reduce methane emissions in the natural gas industry

    International Nuclear Information System (INIS)

    Cowgill, R.M.

    1995-01-01

    The U.S. Environmental Protection Agency (EPA) and the Gas Research Institute (GRI) cofunded a project to quantify methane (CH 4 ) emissions from the U.S. natural gas industry. Methane, the major constituent of natural gas, is a potent greenhouse gas that is believed to increase the effect of global warming when released to the atmosphere. Reducing emissions from natural gas systems would lessen the greenhouse gas effect attributable to atmospheric CH 4 . Further, mitigation methods to reduce emissions of natural gas, a marketable resource, could save money and increase energy efficiency. This presentation summarizes the major sources and quantity of methane being emitted to the atmosphere for all segments of the U.S. gas industry: production; processing; storage; transmission; and distribution. A description of how those emissions were determined is included here, as well as a discussion of which sources are potential candidates for reducing emissions. (author)

  13. State and Territory Greenhouse Gas Emissions 2004

    International Nuclear Information System (INIS)

    2006-06-01

    This document provides an overview of the latest available estimates of greenhouse gas emissions for Australia's States and Territories. Australia's total greenhouse gas emissions in 2004 amounted to 564.7 million tonnes. The State and Territory breakdown was: New South Wales: 158.7 million tonnes (Mt); Queensland: 158.5 Mt; Victoria: 123.0 Mt; Western Australia: 68.5 Mt; South Australia: 27.6 Mt; Northern Territory: 15.6 Mt; Tasmania: 10.7 Mt; ACT: 1.2 Mt. The summary of State and Territory inventories presented in this document reports estimates of greenhouse gas emissions for each State and Territory for the period 1990 to 2004. It is the first time that a complete annual time-series has been reported

  14. Alternative Fuels Data Center: Wisconsin Reduces Emissions With Natural Gas

    Science.gov (United States)

    Trucks Wisconsin Reduces Emissions With Natural Gas Trucks to someone by E-mail Share Alternative Fuels Data Center: Wisconsin Reduces Emissions With Natural Gas Trucks on Facebook Tweet about Alternative Fuels Data Center: Wisconsin Reduces Emissions With Natural Gas Trucks on Twitter Bookmark

  15. Methane emissions from U.S. natural gas operations

    International Nuclear Information System (INIS)

    Lott, R.A.

    1992-01-01

    The Gas Research Institute and the U.S. Environmental Protection Agency are cofunding and comanaging a program to evaluate methane emissions from U.S. natural gas operations. The purpose of the program is to provide an emissions inventory accurate enough for global climate modeling and for addressing the policy question of ''whether encouraging the increased use of natural gas is a viable strategy for reducing the U.S. contribution to global warming''. The program is comprised of three phases: Scoping, Methods Development, and Implementation. The purpose of Phase I was to define the problem. Phase II of the program concentrated on developing techniques for measuring steady state or fugitive emissions and for calculating the highly variable unsteady emissions from the variety of sources that comprise the gas industry. Because of the large number of sources within each source type, techniques were also developed for extrapolating emissions data to similar sources within the industry. Phase III of the program was started in early 1992 and should be completed in early 1994. The purpose of the current phase of the program is to collect sufficient data to achieve the accuracy goal of determining emissions to within ± 0.5 percent of production. Based on the limited amount of data collected to date, methane emissions from the U.S. gas industry appear to be in the range of 1 percent of production. (au) (19 refs.)

  16. Influence of liquid and gas flow rates on sulfuric acid mist removal from air by packed bed tower

    Directory of Open Access Journals (Sweden)

    Jafari Mohammad Javad

    2012-12-01

    Full Text Available Abstract The possible emission of sulfuric acid mists from a laboratory scale, counter-current packed bed tower operated with a caustic scrubbing solution was studied. Acid mists were applied through a local exhaust hood. The emissions from the packed bed tower were monitored in three different categories of gas flow rate as well as three liquid flow rates, while other influencing parameters were kept almost constant. Air sampling and sulfuric acid measurement were carried out iso-kinetically using USEPA method 8. The acid mists were measured by the barium-thorin titration method. According to the results when the gas flow rate increased from 10 L/s to 30 L/s, the average removal efficiency increased significantly (p 3, respectively. L/G of 2–3 was recommended for designing purposes of a packed tower for sulfuric acid mists and vapors removal from contaminated air stream.

  17. Particle emissions from compressed natural gas engines

    International Nuclear Information System (INIS)

    Ristovski, Z.D.; Morawska, L.; Hitchins, J.; Thomas, S.; Greenaway, C.; Gilbert, D.

    2000-01-01

    This paper presents the results of measurements conducted to determine particle and gas emissions from two large compressed natural gas (CNG) spark ignition (SI) engines. Particle size distributions in the range from 0.01-30 μm, and gas composition were measured for five power settings of the engines: 35, 50, 65, 80 and 100% of full power. Particle emissions in the size range between 0.5 and 30 μm, measured by the aerodynamic particle sizer (APS), were very low at a level below two particles cm -3 . These concentrations were comparable with average ambient concentration, and were not considered in the succeeding analysis. Both engines produce significant amounts of particles in the size range between 0.015 and 0.7 μm, measured by the scanning mobility particle size (SMPS). Maximum number of concentrations of about 1 x 10 7 particles cm -3 were very similar for both engines. The CMDs were in the range between 0.020 and 0.060 μm. The observed levels of particulate emission are in terms of number of the same order as emissions from heavy duty diesel engines (Morawska et al., Environ. Sci. Tech. 32, 2033-2042). On the other hand, emissions of CO and NO x of 5.53 and 3.33 g k W h -1 , respectively, for one of the tested engines, were considerably lower than set by the standards. According to the specifications for the gas emissions, provided by the US EPA (US EPA, 1997), this engine can be considered as a 'low-emission' engine, although emissions of submicrometer particles are of the same order as heavy-duty vehicles. (Author)

  18. NOx emission reduction from gas turbines

    International Nuclear Information System (INIS)

    Groppi, G.; Lietti, L.; Forzatti, P.

    2001-01-01

    NO x emissions from gas turbines are a serious environmental concern. Primary control technologies significantly reduce NO x formation, which however is still too high to match increasingly strict emission laws. Catalytic processes can provide lower NO x emissions both as primary and secondary control methods, but their economics should be carefully addressed [it

  19. Compendium of Greenhouse Gas Emissions Estimation Methodologies for the Oil and Gas Industry

    Energy Technology Data Exchange (ETDEWEB)

    Shires, T.M.; Loughran, C.J. [URS Corporation, Austin, TX (United States)

    2004-02-01

    This document is a compendium of currently recognized methods and provides details for all oil and gas industry segments to enhance consistency in emissions estimation. This Compendium aims to accomplish the following goals: Assemble an expansive collection of relevant emission factors for estimating GHG emissions, based on currently available public documents; Outline detailed procedures for conversions between different measurement unit systems, with particular emphasis on implementation of oil and gas industry standards; Provide descriptions of the multitude of oil and gas industry operations, in its various segments, and the associated emissions sources that should be considered; and Develop emission inventory examples, based on selected facilities from the various segments, to demonstrate the broad applicability of the methodologies. The overall objective of developing this document is to promote the use of consistent, standardized methodologies for estimating GHG emissions from petroleum industry operations. The resulting Compendium documents recognized calculation techniques and emission factors for estimating GHG emissions for oil and gas industry operations. These techniques cover the calculation or estimation of emissions from the full range of industry operations - from exploration and production through refining, to the marketing and distribution of products. The Compendium presents and illustrates the use of preferred and alternative calculation approaches for carbon dioxide (CO2), methane (CH4), and nitrous oxide (N2O) emissions for all common emission sources, including combustion, vented, and fugitive. Decision trees are provided to guide the user in selecting an estimation technique based on considerations of materiality, data availability, and accuracy. API will provide (free of charge) a calculation tool based on the emission estimation methodologies described herein. The tool will be made available at http://ghg.api.org/.

  20. Toxic fluoride gas emissions from lithium-ion battery fires.

    Science.gov (United States)

    Larsson, Fredrik; Andersson, Petra; Blomqvist, Per; Mellander, Bengt-Erik

    2017-08-30

    Lithium-ion battery fires generate intense heat and considerable amounts of gas and smoke. Although the emission of toxic gases can be a larger threat than the heat, the knowledge of such emissions is limited. This paper presents quantitative measurements of heat release and fluoride gas emissions during battery fires for seven different types of commercial lithium-ion batteries. The results have been validated using two independent measurement techniques and show that large amounts of hydrogen fluoride (HF) may be generated, ranging between 20 and 200 mg/Wh of nominal battery energy capacity. In addition, 15-22 mg/Wh of another potentially toxic gas, phosphoryl fluoride (POF 3 ), was measured in some of the fire tests. Gas emissions when using water mist as extinguishing agent were also investigated. Fluoride gas emission can pose a serious toxic threat and the results are crucial findings for risk assessment and management, especially for large Li-ion battery packs.

  1. Particle Emissions from Domestic Gas Cookers

    DEFF Research Database (Denmark)

    Glarborg, Peter; Livbjerg, Hans; Wagner, Ayten Yilmaz

    2010-01-01

    The authors experimentally studied the formation of submicron particles from a domestic gas cooker in a compartment free from external particle sources. The effects of fuel (methane, natural gas, odorant-free natural gas), primary aeration, flow rate, and fuel sulphur content on particle emissions...... of the emitted particles were found to have a mean value of about 7 nm for partially premixed flames, increasing to ∼10 nm for nonpremixed flames. The quantity of primary air had a strong impact on the particle emissions, showing a minimum at a primary aeration level of 60-65%. Presence of sulphur in small...... quantities may enhance particle formation under some conditions, but results were not conclusive....

  2. Greenhouse gas emissions trading and project-based mechanisms. Proceedings - CATEP

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-01-01

    Greenhouse gas emissions trading and project-based mechanisms for greenhouse gas reduction are emerging market-based instruments for climate change policy. This book presents a selection of papers from an international workshop co-sponsored by the OECD and Concerted Action on Tradeable Emissions Permits (CATEP), to discuss key research and policy issues relating to the design and implementation of these instruments. The papers cover the experience of developing and transition countries with greenhouse gas emissions trading and project-based mechanisms. In addition, the papers examine the use of tradeable permits in policy mixes and harmonisation of emissions trading schemes, as well as transition issues relating to greenhouse gas emissions trading markets.

  3. OPIC Greenhouse Gas Emissions Inventory

    Data.gov (United States)

    Overseas Private Investment Corporation — Independent analysis details quantifying the greenhouse gas ("GHG") emissions directly attributable to projects to which the Overseas Private Investment Corporation...

  4. Methodology for reporting 2011 B.C. public sector greenhouse gas emissions

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-12-15

    In order to reduce its greenhouse gas emissions, British Columbia promulgated legislation under which the public sector is expected to become carbon neutral starting in 2010 and provincial public sector organizations (PSOs) must report their emissions annually. The aim of this report is to present the emission factors and methodology for calculating and reporting PSO emissions used in 2011. Emission factors represent the amount of greenhouse gas emitted from a specific activity. This document provides emission factors for all in scope categories: stationary sources, indirect emissions, mobile sources and business travel; it also presents a sample calculation of greenhouse gas emissions. The government of British Columbia developed SMARTTool, a web-based program which calculates and reports emissions from stationary sources, indirect emissions and mobile sources. In addition the SMART Travel Emissions Calculator was created to report business travel greenhouse gas emissions through SMARTTool.

  5. Improving the technology of purification of gas emissions petrochemical industries

    OpenAIRE

    USMANOVA R.R.; ZAIKOV G.E.

    2014-01-01

    The technology of cleaning of gas emissions flares in the production of synthetic rubber. Developed dynamic scrubber for scrubbing gas emissions. Complex studies served as the basis for the design of an air purification system of industrial premises. Purification of gas emissions before combustion in flares has significantly reduced air pollution by toxic substances.

  6. Accounting For Greenhouse Gas Emissions From Flooded ...

    Science.gov (United States)

    Nearly three decades of research has demonstrated that the inundation of rivers and terrestrial ecosystems behind dams can lead to enhanced rates of greenhouse gas emissions, particularly methane. The 2006 IPCC Guidelines for National Greenhouse Gas Inventories includes a methodology for estimating methane emissions from flooded lands, but the methodology was published as an appendix to be used a ‘basis for future methodological development’ due to a lack of data. Since the 2006 Guidelines were published there has been a 6-fold increase in the number of peer reviewed papers published on the topic including reports from reservoirs in India, China, Africa, and Russia. Furthermore, several countries, including Iceland, Switzerland, and Finland, have developed country specific methodologies for including flooded lands methane emissions in their National Greenhouse Gas Inventories. This presentation will include a review of the literature on flooded land methane emissions and approaches that have been used to upscale emissions for national inventories. We will also present ongoing research in the United States to develop a country specific methodology. The research approaches include 1) an effort to develop predictive relationships between methane emissions and reservoir characteristics that are available in national databases, such as reservoir size and drainage area, and 2) a national-scale probabilistic survey of reservoir methane emissions. To inform th

  7. Accouting for Greenhouse Gas Emissions from Reservoirs

    Science.gov (United States)

    Beaulieu, J. J.; Deemer, B. R.; Harrison, J. A.; Nietch, C. T.; Waldo, S.

    2016-12-01

    Nearly three decades of research has demonstrated that the impoundment of rivers and the flooding of terrestrial ecosystems behind dams can increase rates of greenhouse gas emission, particularly methane. The 2006 IPCC Guidelines for National Greenhouse Gas Inventories includes a methodology for estimating methane emissions from flooded lands, but the methodology was published as an appendix to be used as a `basis for future methodological development' due to a lack of data. Since the 2006 Guidelines were published there has been a 6-fold increase in the number of peer reviewed papers published on the topic including reports from reservoirs in India, China, Africa, and Russia. Furthermore, several countries, including Iceland, Switzerland, and Finland, have developed country specific methodologies for including flooded lands methane emissions in their National Greenhouse Gas Inventories. This presentation will include a review of the literature on flooded land methane emissions and approaches that have been used to upscale emissions for national inventories. We will also present ongoing research in the United States to develop a country specific methodology. In the U.S., research approaches include: 1) an effort to develop predictive relationships between methane emissions and reservoir characteristics that are available in national databases, such as reservoir size and drainage area, and 2) a national-scale probabilistic survey of reservoir methane emissions linked to the National Lakes Assessment.

  8. Urban form and greenhouse gas emissions in Finland

    International Nuclear Information System (INIS)

    Harmaajaervi, Irmeli

    2003-01-01

    Finland's regional form is becoming more concentrated, while urban sprawl is causing growth centres to become fragmented. The effects caused by these changes on greenhouse gas emissions were studied up to the year 2010, when, in accordance with the Kyoto protocol, Finland's greenhouse gas emissions should be reduced to the 1990 level. The urban form affects especially transportation inside regions, the potential to utilise district heating and the need for infrastructure. By preventing urban sprawl and by encouraging teleworking and some lifestyle changes, it would be possible to reduce annual transportation emissions by the year 2010 by 1.1 million tonnes CO 2 eq., i.e. 27%, the emissions from residential and service buildings by 1.1 million tonnes CO 2 eq., i.e. 5%, and the emissions from municipal infrastructure by 0.1 million tonnes CO 2 eq., i.e. 6%. Altogether, it is possible to reduce the greenhouse gas emissions by 2.3 million tonnes, which amounts to 15% of Finland's target for emissions reductions in 2010. If the target-oriented scenario is realised, the subsequent decrease of emissions would accelerate. To stop urban sprawl, measures are required in planning, land use and housing policy as well as in transportation and tax policies. Additionally, more needs to be done in regard to co-operation, interaction and information dissemination. This paper introduces a report which estimates, for the first time, the effects caused by changes in the regional and urban forms on the levels of greenhouse gas emissions in Finland

  9. Hazardous air pollutant emissions from gas-fired combustion sources: emissions and the effects of design and fuel type

    Energy Technology Data Exchange (ETDEWEB)

    England, G.C.; McGrath, T.P. [GE-Energy and Environmental Research Corp., Irvine, CA (United States); Gilmer, L. [Equilon Enterprises, Bellaire, TX (United States); Seebold, J.G. [Chevron Research and Technology Co., Richmond, CA (United States); Lev-On, M. [ARCO, Los Angeles, CA (United States); Hunt, T. [American Petroleum Institute, Washington, DC (United States)

    2001-07-01

    Air emissions from gas-fired combustion devices such as boilers, process heaters, gas turbines and stationary reciprocating engines contain hazardous air pollutants (HAPs) subjected to consideration under the federal clean air act (CAA). This work presents a recently completed major research project to develop an understanding of HAP emissions from gas-fired boilers and process heaters and new HAP emission factors based on field emission tests of gas-fired external combustion devices used in the petroleum industry. The effect of combustion system design and operating parameters on HAP emissions determined by both field and research tests are discussed. Data from field tests of gas-fired petroleum industry boilers and heaters generally show very low emission levels of organic HAPs. A comparison of the emission data for boilers and process heaters, including units with and without various forms of NO{sub x} emission controls, showed no significant difference in organic HAP emission characteristics due to process or burner design. This conclusion is also supported by the results of research tests with different burner designs. Based on field tests of units fired with natural gas and various petroleum industry process gases and research tests in which gas composition was intentionally varied, organic HAP emissions were not determined to be significantly affected by the gas composition. Research data indicate that elevated organic HAP emission levels are found only under extreme operating conditions (starved air or high excess air combustion) associated with poor combustion. (author)

  10. Hazardous air pollutant emissions from gas-fired combustion sources: emissions and the effects of design and fuel type

    International Nuclear Information System (INIS)

    England, G.C.; McGrath, T.P.; Gilmer, L.; Seebold, J.G.; Lev-On, M.; Hunt, T.

    2001-01-01

    Air emissions from gas-fired combustion devices such as boilers, process heaters, gas turbines and stationary reciprocating engines contain hazardous air pollutants (HAPs) subjected to consideration under the federal clean air act (CAA). This work presents a recently completed major research project to develop an understanding of HAP emissions from gas-fired boilers and process heaters and new HAP emission factors based on field emission tests of gas-fired external combustion devices used in the petroleum industry. The effect of combustion system design and operating parameters on HAP emissions determined by both field and research tests are discussed. Data from field tests of gas-fired petroleum industry boilers and heaters generally show very low emission levels of organic HAPs. A comparison of the emission data for boilers and process heaters, including units with and without various forms of NO x emission controls, showed no significant difference in organic HAP emission characteristics due to process or burner design. This conclusion is also supported by the results of research tests with different burner designs. Based on field tests of units fired with natural gas and various petroleum industry process gases and research tests in which gas composition was intentionally varied, organic HAP emissions were not determined to be significantly affected by the gas composition. Research data indicate that elevated organic HAP emission levels are found only under extreme operating conditions (starved air or high excess air combustion) associated with poor combustion. (author)

  11. Dedicated natural gas vehicle with low emission

    NARCIS (Netherlands)

    Voogd, A. de; Weide, J. van der; Konig, A.; Wegener, R.

    1995-01-01

    In the introduction an overview is given of international activities in the field of natural gas vehicles. The main incentives for the use of natural gas in vehicles are: emission reduction in urban areas, fuel diversification, and long term availability. Heavy duty natural gas engines are mainly

  12. Energy market reform and greenhouse gas emission reductions

    International Nuclear Information System (INIS)

    Anon.

    1999-01-01

    The report reviews micro-economic reform in the energy market and measures the impact that energy market reform is expected to have on greenhouse gas outcomes. It indicates that reform in the electricity and gas industries is delivering what was promised, an efficient market with lower energy prices and, over the longer term, will deliver a gradually reducing rate of greenhouse gas emissions per unit of energy produced. It also recognises that energy market reform has removed some barriers to the entry of less greenhouse gas intense fuels. These trends will result in reduced greenhouse gas intensity in the supply of energy and significant reductions in the growth in greenhouse gas emissions compared to what may have been expected without the reforms

  13. Accounting for Greenhouse Gas Emissions from Reservoirs ...

    Science.gov (United States)

    Nearly three decades of research has demonstrated that the impoundment of rivers and the flooding of terrestrial ecosystems behind dams can increase rates of greenhouse gas emission, particularly methane. The 2006 IPCC Guidelines for National Greenhouse Gas Inventories includes a methodology for estimating methane emissions from flooded lands, but the methodology was published as an appendix to be used as a ‘basis for future methodological development’ due to a lack of data. Since the 2006 Guidelines were published there has been a 6-fold increase in the number of peer reviewed papers published on the topic including reports from reservoirs in India, China, Africa, and Russia. Furthermore, several countries, including Iceland, Switzerland, and Finland, have developed country specific methodologies for including flooded lands methane emissions in their National Greenhouse Gas Inventories. This presentation will include a review of the literature on flooded land methane emissions and approaches that have been used to upscale emissions for national inventories. We will also present ongoing research in the United States to develop a country specific methodology. In the U.S., research approaches include: 1) an effort to develop predictive relationships between methane emissions and reservoir characteristics that are available in national databases, such as reservoir size and drainage area, and 2) a national-scale probabilistic survey of reservoir methane em

  14. Request for Correction 12003 Greenhouse Gas Emissions Reporting from the Petroleum and Natural Gas Industry

    Science.gov (United States)

    Request for Correction by the U.S. Chamber of Commerce for information in Greenhouse Gas Emissions Reporting from the Petroleum Gas Industry that regarding methane emissions, volatile organic compounds, and hazardous air pollutants.

  15. The methane emissions of the Swiss gas industry

    International Nuclear Information System (INIS)

    Xinmin, J.

    2004-01-01

    This article presents a method for the estimation of the methane emissions caused by the Swiss gas industry. Based on new data on the Swiss gas infrastructure, current emission levels are estimated for methane - one of the major greenhouse gases. The methodology and modelling used, which is based on previous studies on this topic, are discussed. Results are presented that show that the estimates provided by the current study are consistent with earlier data. Scenarios are presented that show that a steady decrease in methane emissions emanating from the Swiss gas industry's installations can be expected by the year 2012. The data used in the study and its results are presented in tabular and graphical form and commented on

  16. Greenhouse Gas Emissions from Hydroelectric Reservoirs in Tropical Regions

    International Nuclear Information System (INIS)

    Pinguelli Rosa, L.; Aurelio dos Santos, M.; Oliveira dos Santos, E.; Matvienko, B.; Sikar, E.

    2004-01-01

    This paper discusses emissions by power-dams in the tropics. Greenhouse gas emissions from tropical power-dams are produced underwater through biomass decomposition by bacteria. The gases produced in these dams are mainly nitrogen, carbon dioxide and methane. A methodology was established for measuring greenhouse gases emitted by various power-dams in Brazil. Experimental measurements of gas emissions by dams were made to determine accurately their emissions of methane (CH4) and carbon dioxide (CO2) gases through bubbles formed on the lake bottom by decomposing organic matter, as well as rising up the lake gradient by molecular diffusion. The main source of gas in power-dams reservoirs is the bacterial decomposition (aerobic and anaerobic) of autochthonous and allochthonous organic matter that basically produces CO2 and CH4. The types and modes of gas production and release in the tropics are reviewed

  17. Estimating greenhouse gas emissions of European cities--modeling emissions with only one spatial and one socioeconomic variable.

    Science.gov (United States)

    Baur, Albert H; Lauf, Steffen; Förster, Michael; Kleinschmit, Birgit

    2015-07-01

    Substantive and concerted action is needed to mitigate climate change. However, international negotiations struggle to adopt ambitious legislation and to anticipate more climate-friendly developments. Thus, stronger actions are needed from other players. Cities, being greenhouse gas emission centers, play a key role in promoting the climate change mitigation movement by becoming hubs for smart and low-carbon lifestyles. In this context, a stronger linkage between greenhouse gas emissions and urban development and policy-making seems promising. Therefore, simple approaches are needed to objectively identify crucial emission drivers for deriving appropriate emission reduction strategies. In analyzing 44 European cities, the authors investigate possible socioeconomic and spatial determinants of urban greenhouse gas emissions. Multiple statistical analyses reveal that the average household size and the edge density of discontinuous dense urban fabric explain up to 86% of the total variance of greenhouse gas emissions of EU cities (when controlled for varying electricity carbon intensities). Finally, based on these findings, a multiple regression model is presented to determine greenhouse gas emissions. It is independently evaluated with ten further EU cities. The reliance on only two indicators shows that the model can be easily applied in addressing important greenhouse gas emission sources of European urbanites, when varying power generations are considered. This knowledge can help cities develop adequate climate change mitigation strategies and promote respective policies on the EU or the regional level. The results can further be used to derive first estimates of urban greenhouse gas emissions, if no other analyses are available. Copyright © 2015 Elsevier B.V. All rights reserved.

  18. Top-down Constraints on Emissions: Example for Oil and Gas Operations

    Science.gov (United States)

    Petron, G.; Sweeney, C.; Karion, A.; Brewer, A.; Hardesty, R.; Banta, R. M.; Frost, G. J.; Trainer, M.; Miller, B. R.; Conley, S. A.; Kofler, J.; Newberger, T.; Higgs, J. A.; Wolter, S.; Guenther, D.; Andrews, A. E.; Dlugokencky, E. J.; Lang, P. M.; Montzka, S. A.; Edwards, P. M.; Dube, W. P.; Brown, S. S.; Helmig, D.; Hueber, J.; Rella, C.; Jacobson, G. A.; Wolfe, D. E.; Bruhwiler, L.; Tans, P. P.; Schnell, R. C.

    2012-12-01

    In many countries, human-caused emissions of the two major long lived greenhouse gases, carbon dioxide and methane, are primarily linked to the use of fossil fuels (coal, oil and natural gas). Fugitive emissions of natural gas (mainly CH4) from the oil and gas exploration and production sector may also be an important contributor to natural gas life cycle/greenhouse gas footprint. Fuel use statistics have traditionally been used in combination with fuel and process specific emission factors to estimate CO2 emissions from fossil-fuel-based energy systems (power plants, motor vehicles…). Fugitive emissions of CH4, in contrast, are much harder to quantify. Fugitive emission levels may vary substantially from one oil and gas producing basin to another and may not scale with common activity data, such as production numbers. In the USA, recent efforts by the industry, States and the US Environmental Protection Agency have focused on developing new bottom-up inventory methodologies to assess methane and volatile organic compounds emissions from oil and gas producing basins. The underlying assumptions behind these inventories are multiple and result de facto in large uncertainties. Independent atmospheric-based estimates of emissions provide another valuable piece of information that can be used to evaluate inventories. Over the past year, the NOAA Earth System Research Laboratory has used its expertise in high quality GHG and wind measurements to evaluate regional emissions of methane from two oil and gas basins in the Rocky Mountain region. Results from these two campaigns will be discussed and compared with available inventories.

  19. Earthworms change the quantity and composition of dissolved organic carbon and reduce greenhouse gas emissions during composting

    DEFF Research Database (Denmark)

    Nigatu, Abebe Nigussie; Bruun, Sander; de Neergaard, Andreas

    2017-01-01

    Dissolved organic carbon (DOC) has recently been proposed as an indicator of compost stability. We assessed the earthworms' effect on DOC content and composition during composting, and linked compost stability to greenhouse gas emissions and feeding ratio. Earthworms reduced total DOC content......, indicating larger stability of vermicompost than of thermophilic compost. The concentrations of humic acid and fulvic acid were reduced by earthworms, whereas there was no significant effect on hydrophobic neutrals and hydrophilics. The humic acid fraction was depleted more quickly than the other compounds......, indicating humic acid degradation during composting. The optimum feeding ratio decreased DOC content compared to the high feeding ratio. The lowest N2O emissions were also observed at the optimum feeding ratio. Our study confirmed the use of DOC content and composition as an indicator of compost stability...

  20. Quantifying greenhouse gas emissions from waste treatment facilities

    DEFF Research Database (Denmark)

    Mønster, Jacob

    to be in-stalled in any vehicle and thereby enabling measurements wherever there were roads. The validation of the measurement method was done by releasing a controlled amount of methane and quantifying the emission using the release of tracer gas. The validation test showed that even in areas with large...... treatment plants. The PhD study reviewed and evaluated previously used methane measurement methods and found the tracer dispersion method promising. The method uses release of tracer gas and the use of mobile equipment with high analytical sensitivity, to measure the downwind plumes of methane and tracer...... ranged from 10 to 92 kg per hour and was found to change in even short timescales of a few hours. The periods with large emissions correlated with a drop in methane utilization, indicating that emissions came from the digesters tanks or gas storage/use. The measurements indicated that the main emissions...

  1. Measurement of fugitive emissions from gas processing plants in Alberta

    Energy Technology Data Exchange (ETDEWEB)

    Chambers, A. [Alberta Research Council, Edmonton, AB (Canada)

    2004-07-01

    This paper presents a new gas visualization camera created to detect leaks. An outline of the device's projected entry into the oil and gas industry was provided, and included: a demonstration of Differential Absorption Light Detection and Ranging (DIAL) and leak cameras to measure and reduce fugitive emissions; a comparison of DIAL measured emissions with estimated emissions; and a review of methods to measure particulate emissions. In addition, a background of gas leak visualisation technology was presented along with an an overview of DIAL and its results from sour gas plants. The results of a survey conducted in 2003 were presented, including leaks identified and repaired as well as a follow up leak survey. An analysis of pre and post-repair hydrocarbon emissions from the Deepcut area revealed a 60 per cent reduction with savings of $140,000 as well as additional savings from reduced carbon emissions. A similar survey conducted in another plant measured emissions from condensate tanks before and after cooler installation as well as from surrounding well sites, quantifying an 80 per cent reduction in methane emissions. Tasks identified for future research concerned particulate emissions and the development of Lidar methods which can currently identify particulates, but are not yet able to quantify them. Other tasks included a complete DIAL data workup and reporting; the quantification of both methane and carbon emissions reduction at a sour gas plant; a comparison of measured emissions with methods that estimate fugitives; and a complete review of particulate measurements. tabs, figs.

  2. Prototype demonstration of dual sorbent injection for acid gas control on municipal solid waste combustion units

    Energy Technology Data Exchange (ETDEWEB)

    None

    1994-05-01

    This report gathered and evaluated emissions and operations data associated with furnace injection of dry hydrated lime and duct injection of dry sodium bicarbonate at a commercial, 1500 ton per day, waste-to-energy facility. The information compiled during the project sheds light on these sorbents to affect acid gas emissions from municipal solid waste combustors. The information assesses the capability of these systems to meet the 1990 Clean Air Act and 1991 EPA Emission Guidelines.

  3. Integrated cost-effectiveness analysis of greenhouse gas emission abatement. The case of Finland

    Energy Technology Data Exchange (ETDEWEB)

    Lehtilae, A.; Tuhkanen, S. [VTT Energy, Espoo (Finland). Energy Systems

    1999-11-01

    In Finland greenhouse gas emissions are expected to increase during the next decades due to economic growth, particularly in the energy intensive industrial sectors. The role of these industries is very central in the national economy. The emission control according to the Kyoto Protocol will therefore be quite difficult and costly. The study analyses the cost-effectiveness of different technical options for reducing the emissions of carbon dioxide, methane, and nitrous oxide in Finland. The analysis is performed with the help of a comprehensive energy system model for Finland, which has been extended to cover all major sources of methane and nitrous oxide emissions in the energy sector, industry, waste management and agriculture. The focus being on technical options, no consideration is given to possible policy measures, emission trading or joint implementation in the study. Under the boundary conditions given for the development of the Finnish energy economy, cost-effective technical measures in the energy system include increases in the use of wood biomass, natural gas and wind energy, increases in the contribution of CHP to the power supply, and intensified energy conservation in all end-use sectors. Additional cost-effective measures are landfill gas recovery, utilisation of the combustible fraction of waste and catalytic conversion of N{sub 2}O in nitric acid production. With baseline assumptions, the direct annual costs of emission abatement are calculated to be about 2000 MFIM (330 M{epsilon}) in 2010. The marginal costs are estimated to be about 230 FIM (40 {epsilon}) per tonne of CO{sub 2}-equivalent in 2010. The cost curie derived from the analysis could be used in further analyses concerning emissions trading. (orig.) 109 refs. SIHTI Research Programme

  4. Norwegian gas sales and the impacts on European CO2 emissions

    International Nuclear Information System (INIS)

    Berg, E.; Boug, P.; Kverndokk, S.

    2001-01-01

    This paper has studied the impacts on Western European CO 2 emissions of a reduction in Norwegian gas sales. Such impacts are due to changes in energy demand, energy supply, and environmental and political regulations. The gas supply model DYNOPOLY was used to analyse the effects on Russian and Algerian gas exports of a reduction in Norwegian gas supply. The effects on the demand side and the effects of committing to CO 2 targets were analysed using the energy demand model SEEM. If Western European countries commit to their announced CO 2 emissions targets, reduced Norwegian gas sales will have no impact on emissions. The consumption of oil and coal will increase slightly, while the total energy consumption will go down. Also, a reduction in Norwegian gas sales will have only minor impacts on the CO 2 emissions from Western Europe when no emissions regulations are considered

  5. 2012 Stakeholder Workshop on Natural Gas in the Inventory of U.S. Greenhouse Gas Emissions and Sinks

    Science.gov (United States)

    This page describes EPA's September 2012 stakeholder workshop on key aspects of the estimates of greenhouse gas emissions from the natural gas sector in the Inventory of U.S. Greenhouse Gas Emissions and Sinks.

  6. Technology Opportunities to Reduce U.S. Greenhouse Gas Emissions

    Energy Technology Data Exchange (ETDEWEB)

    National Lab Directors, . .

    2001-04-05

    The rise in greenhouse gas emissions from fossil fuel combustion and industrial and agricultural activities has aroused international concern about the possible impacts of these emissions on climate. Greenhouse gases--mostly carbon dioxide, some methane, nitrous oxide and other trace gases--are emitted to the atmosphere, enhancing an effect in which heat reflected from the earth's surface is kept from escaping into space, as in a greenhouse. Thus, there is concern that the earth's surface temperature may rise enough to cause global climate change. Approximately 90% of U.S. greenhouse gas emissions from anthropogenic sources come from energy production and use, most of which are a byproduct of the combustion of fossil fuels. On a per capita basis, the United States is one of the world's largest sources of greenhouse gas emissions, comprising 4% of the world's population, yet emitting 23% of the world's greenhouse gases. Emissions in the United States are increasing at around 1.2% annually, and the Energy Information Administration forecasts that emissions levels will continue to increase at this rate in the years ahead if we proceed down the business-as-usual path. President Clinton has presented a two-part challenge for the United States: reduce greenhouse gas emissions and grow the economy. Meeting the challenge will mean that in doing tomorrow's work, we must use energy more efficiently and emit less carbon for the energy expended than we do today. To accomplish these goals, President Clinton proposed on June 26, 1997, that the United States ''invest more in the technologies of the future''. In this report to Secretary of Energy Pena, 47 technology pathways are described that have significant potential to reduce carbon dioxide emissions. The present study was completed before the December 1997 United Nations Framework Convention on Climate Change and is intended to provide a basis to evaluate technology

  7. Modelling combustion reactions for gas flaring and its resulting emissions

    Directory of Open Access Journals (Sweden)

    O. Saheed Ismail

    2016-07-01

    Full Text Available Flaring of associated petroleum gas is an age long environmental concern which remains unabated. Flaring of gas maybe a very efficient combustion process especially steam/air assisted flare and more economical than utilization in some oil fields. However, it has serious implications for the environment. This study considered different reaction types and operating conditions for gas flaring. Six combustion equations were generated using the mass balance concept with varying air and combustion efficiency. These equations were coded with a computer program using 12 natural gas samples of different chemical composition and origin to predict the pattern of emission species from gas flaring. The effect of key parameters on the emission output is also shown. CO2, CO, NO, NO2 and SO2 are the anticipated non-hydrocarbon emissions of environmental concern. Results show that the quantity and pattern of these chemical species depended on percentage excess/deficiency of stoichiometric air, natural gas type, reaction type, carbon mass content, impurities, combustion efficiency of the flare system etc. These emissions degrade the environment and human life, so knowing the emission types, pattern and flaring conditions that this study predicts is of paramount importance to governments, environmental agencies and the oil and gas industry.

  8. CO and PAH emissions from engines operating on producer gas

    DEFF Research Database (Denmark)

    Ahrenfeldt, Jesper

    2005-01-01

    High carbon monoxide (CO) emission from gas engines fueled by producer gas is a concerning problem in the struggle to make biomass gasification for heat and power production a success. The standing regulations concerning CO emissions from gas engine based power plants in most EU countries are so ...

  9. The growth response of Alternanthera philoxeroides in a simulated post-combustion emission with ultrahigh [CO2] and acidic pollutants

    International Nuclear Information System (INIS)

    Xu Chengyuan; Griffin, Kevin L.; Blazier, John C.; Craig, Elizabeth C.; Gilbert, Dominique S.; Sritrairat, Sanpisa; Anderson, O. Roger; Castaldi, Marco J.; Beaumont, Larry

    2009-01-01

    Although post-combustion emissions from power plants are a major source of air pollution, they contain excess CO 2 that could be used to fertilize commercial greenhouses and stimulate plant growth. We addressed the combined effects of ultrahigh [CO 2 ] and acidic pollutants in flue gas on the growth of Alternanthera philoxeroides. When acidic pollutants were excluded, the biomass yield of A. philoxeroides saturated near 2000 μmol mol -1 [CO 2 ] with doubled biomass accumulation relative to the ambient control. The growth enhancement was maintained at 5000 μmol mol -1 [CO 2 ], but declined when [CO 2 ] rose above 1%, in association with a strong photosynthetic inhibition. Although acidic components (SO 2 and NO 2 ) significantly offset the CO 2 enhancement, the aboveground yield increased considerably when the concentration of pollutants was moderate (200 times dilution). Our results indicate that using excess CO 2 from the power plant emissions to optimize growth in commercial green house could be viable. - Diluted post-combustion emission gas from fossil fuel fired power plants stimulate the growth of C 3 plant.

  10. Life cycle greenhouse gas emissions from U.S. liquefied natural gas exports: implications for end uses.

    Science.gov (United States)

    Abrahams, Leslie S; Samaras, Constantine; Griffin, W Michael; Matthews, H Scott

    2015-03-03

    This study analyzes how incremental U.S. liquefied natural gas (LNG) exports affect global greenhouse gas (GHG) emissions. We find that exported U.S. LNG has mean precombustion emissions of 37 g CO2-equiv/MJ when regasified in Europe and Asia. Shipping emissions of LNG exported from U.S. ports to Asian and European markets account for only 3.5-5.5% of precombustion life cycle emissions, hence shipping distance is not a major driver of GHGs. A scenario-based analysis addressing how potential end uses (electricity and industrial heating) and displacement of existing fuels (coal and Russian natural gas) affect GHG emissions shows the mean emissions for electricity generation using U.S. exported LNG were 655 g CO2-equiv/kWh (with a 90% confidence interval of 562-770), an 11% increase over U.S. natural gas electricity generation. Mean emissions from industrial heating were 104 g CO2-equiv/MJ (90% CI: 87-123). By displacing coal, LNG saves 550 g CO2-equiv per kWh of electricity and 20 g per MJ of heat. LNG saves GHGs under upstream fugitive emissions rates up to 9% and 5% for electricity and heating, respectively. GHG reductions were found if Russian pipeline natural gas was displaced for electricity and heating use regardless of GWP, as long as U.S. fugitive emission rates remain below the estimated 5-7% rate of Russian gas. However, from a country specific carbon accounting perspective, there is an imbalance in accrued social costs and benefits. Assuming a mean social cost of carbon of $49/metric ton, mean global savings from U.S. LNG displacement of coal for electricity generation are $1.50 per thousand cubic feet (Mcf) of gaseous natural gas exported as LNG ($.028/kWh). Conversely, the U.S. carbon cost of exporting the LNG is $1.80/Mcf ($.013/kWh), or $0.50-$5.50/Mcf across the range of potential discount rates. This spatial shift in embodied carbon emissions is important to consider in national interest estimates for LNG exports.

  11. Accounting for Greenhouse Gas Emissions from Reservoirs

    Science.gov (United States)

    Nearly three decades of research has demonstrated that the impoundment of rivers and the flooding of terrestrial ecosystems behind dams can increase rates of greenhouse gas emission, particularly methane. The 2006 IPCC Guidelines for National Greenhouse Gas Inventories includes ...

  12. Greenhouse Gas Emissions Trading for the Transport Sector

    International Nuclear Information System (INIS)

    Holmgren, Kristina; Belhaj, Mohammed; Gode, Jenny; Saernholm, Erik; Zetterberg, Lars; Aahman, Markus

    2006-12-01

    In this study we have analysed different options to apply emissions trading for greenhouse gas emissions to the transport sector. The main focus has been on the EU transport sector and the possibility to include it in the current EU ETS in the trading period beginning in 2013. The purpose was to study how different alternatives will affect different actors. Focus has been on three sub-sectors; road transport, aviation and shipping. The railway sector has only been treated on a general level. The study includes the following three parts: 1. An economic analysis of the consequences of greenhouse gas emissions trading for the transport sector including an analysis of how the total cost for reaching an emission target will be affected by an integrated emissions trading system for the transport sector and the industry (currently included sectors) compared to separate systems for the sectors, 2. An analysis of design possibilities for the different sub-sectors. Discussion of positive and negative aspects with different choices of design parameters, such as trading entity, covered greenhouse gases, allocation of emission allowances and monitoring systems, 3. Examination of the acceptance among different actors for different options of using greenhouse gas emissions trading in the transport sector. When setting up an emissions trading scheme there are a number of design parameters that have to be analysed in order to find an appropriate system, with limited administrative and transaction costs and as small distortions as possible to competitiveness

  13. Revised emission factors for gas engines including start/stop emissions

    Energy Technology Data Exchange (ETDEWEB)

    Nielsen, Malene; Boll Illerup, J.; Birr-Petersen, K.

    2008-06-15

    Liberalisation of the electricity market has led to Danish gas engine plants increasingly converting to the spot and regulating power markets. In order to offer regulating power, plants need to be able to start and stop the engines at the plants quickly. The liberalisation causes a considerable change of operation practice of the engines e.g. less full load operation hours /year. The project provides an inventory determining the scale of the emissions during the start and stop sequence as well as proposals for engine modifications aimed at reducing start/stop emissions. This report includes calculation of emission factors as well as an inventory of total emissions and reduction potentials. (au)

  14. Atmospheric emissions from the upstream oil and gas industry

    International Nuclear Information System (INIS)

    Taylor, B.G.S.

    1994-01-01

    The results are presented of a study set up to determine the nature and levels of atmospheric emissions resulting from United Kingdom oil and gas exploration and production activities. The study was commissioned by the UK Offshore Operators Association. Emissions by the upstream oil and gas industry of common pollutants, such as carbon monoxide, sulphur dioxide and nitrous oxide, and ozone depletion chemicals were shown in each case to be less than 1% of total UK emissions. Greenhouse gas emissions in the industry arise mainly from production operations with a small but significant contribution from onshore activities. Carbon dioxide is the major component followed in descending order by nitrogen oxides, methane and volatile organic compounds. In 1991, these emissions formed 3.2%, 4.6%, 2.9% and 2.8% of the UK totals respectively; overall this represented only about 3% of UK global warming emissions. The evidence of this study illustrates that the industry, which produces 67% of the UK's primary energy, is successfully managing its operations in an environmentally responsible way. (3 figures, 3 tables) (UK)

  15. Predicting emissions from oil and gas operations in the Uinta Basin, Utah.

    Science.gov (United States)

    Wilkey, Jonathan; Kelly, Kerry; Jaramillo, Isabel Cristina; Spinti, Jennifer; Ring, Terry; Hogue, Michael; Pasqualini, Donatella

    2016-05-01

    In this study, emissions of ozone precursors from oil and gas operations in Utah's Uinta Basin are predicted (with uncertainty estimates) from 2015-2019 using a Monte-Carlo model of (a) drilling and production activity, and (b) emission factors. Cross-validation tests against actual drilling and production data from 2010-2014 show that the model can accurately predict both types of activities, returning median results that are within 5% of actual values for drilling, 0.1% for oil production, and 4% for gas production. A variety of one-time (drilling) and ongoing (oil and gas production) emission factors for greenhouse gases, methane, and volatile organic compounds (VOCs) are applied to the predicted oil and gas operations. Based on the range of emission factor values reported in the literature, emissions from well completions are the most significant source of emissions, followed by gas transmission and production. We estimate that the annual average VOC emissions rate for the oil and gas industry over the 2010-2015 time period was 44.2E+06 (mean) ± 12.8E+06 (standard deviation) kg VOCs per year (with all applicable emissions reductions). On the same basis, over the 2015-2019 period annual average VOC emissions from oil and gas operations are expected to drop 45% to 24.2E+06 ± 3.43E+06 kg VOCs per year, due to decreases in drilling activity and tighter emission standards. This study improves upon previous methods for estimating emissions of ozone precursors from oil and gas operations in Utah's Uinta Basin by tracking one-time and ongoing emission events on a well-by-well basis. The proposed method has proven highly accurate at predicting drilling and production activity and includes uncertainty estimates to describe the range of potential emissions inventory outcomes. If similar input data are available in other oil and gas producing regions, then the method developed here could be applied to those regions as well.

  16. Country-Level Life Cycle Assessment of Greenhouse Gas Emissions from Liquefied Natural Gas Trade for Electricity Generation.

    Science.gov (United States)

    Kasumu, Adebola S; Li, Vivian; Coleman, James W; Liendo, Jeanne; Jordaan, Sarah M

    2018-02-20

    In the determination of the net impact of liquefied natural gas (LNG) on greenhouse gas emissions, life cycle assessments (LCA) of electricity generation have yet to combine the effects of transport distances between exporting and importing countries, country-level infrastructure in importing countries, and the fuel sources displaced in importing countries. To address this, we conduct a LCA of electricity generated from LNG export from British Columbia, Canada with a three-step approach: (1) a review of viable electricity generation markets for LNG, (2) the development of results for greenhouse gas emissions that account for transport to importing nations as well as the infrastructure required for power generation and delivery, and (3) emissions displacement scenarios to test assumptions about what electricity is being displaced in the importing nation. Results show that while the ultimate magnitude of the greenhouse gas emissions associated with natural gas production systems is still unknown, life cycle greenhouse gas emissions depend on country-level infrastructure (specifically, the efficiency of the generation fleet, transmission and distribution losses and LNG ocean transport distances) as well as the assumptions on what is displaced in the domestic electricity generation mix. Exogenous events such as the Fukushima nuclear disaster have unanticipated effects on the emissions displacement results. We highlight national regulations, environmental policies, and multilateral agreements that could play a role in mitigating emissions.

  17. Analysis of carbon dioxide emission of gas fuelled cogeneration plant

    International Nuclear Information System (INIS)

    Nordin, Adzuieen; Amin, M; Majid, A

    2013-01-01

    Gas turbines are widely used for power generation. In cogeneration system, the gas turbine generates electricity and the exhaust heat from the gas turbine is used to generate steam or chilled water. Besides enhancing the efficiency of the system, the process assists in reducing the emission of CO 2 to the environment. This study analyzes the amount of CO 2 emission by Universiti Teknologi Petronas gas fuelled cogeneration system using energy balance equations. The results indicate that the cogeneration system reduces the CO 2 emission to the environment by 60%. This finding could encourage the power plant owners to install heat recovery systems to their respective plants

  18. Analysis of carbon dioxide emission of gas fuelled cogeneration plant

    Science.gov (United States)

    Nordin, Adzuieen; Amin, M.; Majid, A.

    2013-12-01

    Gas turbines are widely used for power generation. In cogeneration system, the gas turbine generates electricity and the exhaust heat from the gas turbine is used to generate steam or chilled water. Besides enhancing the efficiency of the system, the process assists in reducing the emission of CO2 to the environment. This study analyzes the amount of CO2 emission by Universiti Teknologi Petronas gas fuelled cogeneration system using energy balance equations. The results indicate that the cogeneration system reduces the CO2 emission to the environment by 60%. This finding could encourage the power plant owners to install heat recovery systems to their respective plants.

  19. Estimating greenhouse gas emissions of European cities — Modeling emissions with only one spatial and one socioeconomic variable

    International Nuclear Information System (INIS)

    Baur, Albert H.; Lauf, Steffen; Förster, Michael; Kleinschmit, Birgit

    2015-01-01

    Substantive and concerted action is needed to mitigate climate change. However, international negotiations struggle to adopt ambitious legislation and to anticipate more climate-friendly developments. Thus, stronger actions are needed from other players. Cities, being greenhouse gas emission centers, play a key role in promoting the climate change mitigation movement by becoming hubs for smart and low-carbon lifestyles. In this context, a stronger linkage between greenhouse gas emissions and urban development and policy-making seems promising. Therefore, simple approaches are needed to objectively identify crucial emission drivers for deriving appropriate emission reduction strategies. In analyzing 44 European cities, the authors investigate possible socioeconomic and spatial determinants of urban greenhouse gas emissions. Multiple statistical analyses reveal that the average household size and the edge density of discontinuous dense urban fabric explain up to 86% of the total variance of greenhouse gas emissions of EU cities (when controlled for varying electricity carbon intensities). Finally, based on these findings, a multiple regression model is presented to determine greenhouse gas emissions. It is independently evaluated with ten further EU cities. The reliance on only two indicators shows that the model can be easily applied in addressing important greenhouse gas emission sources of European urbanites, when varying power generations are considered. This knowledge can help cities develop adequate climate change mitigation strategies and promote respective policies on the EU or the regional level. The results can further be used to derive first estimates of urban greenhouse gas emissions, if no other analyses are available. - Highlights: • Two variables determine urban GHG emissions in Europe, assuming equal power generation. • Household size, inner-urban compactness and power generation drive urban GHG emissions. • Climate policies should consider

  20. Estimating greenhouse gas emissions of European cities — Modeling emissions with only one spatial and one socioeconomic variable

    Energy Technology Data Exchange (ETDEWEB)

    Baur, Albert H., E-mail: Albert.H.Baur@campus.tu-berlin.de; Lauf, Steffen; Förster, Michael; Kleinschmit, Birgit

    2015-07-01

    Substantive and concerted action is needed to mitigate climate change. However, international negotiations struggle to adopt ambitious legislation and to anticipate more climate-friendly developments. Thus, stronger actions are needed from other players. Cities, being greenhouse gas emission centers, play a key role in promoting the climate change mitigation movement by becoming hubs for smart and low-carbon lifestyles. In this context, a stronger linkage between greenhouse gas emissions and urban development and policy-making seems promising. Therefore, simple approaches are needed to objectively identify crucial emission drivers for deriving appropriate emission reduction strategies. In analyzing 44 European cities, the authors investigate possible socioeconomic and spatial determinants of urban greenhouse gas emissions. Multiple statistical analyses reveal that the average household size and the edge density of discontinuous dense urban fabric explain up to 86% of the total variance of greenhouse gas emissions of EU cities (when controlled for varying electricity carbon intensities). Finally, based on these findings, a multiple regression model is presented to determine greenhouse gas emissions. It is independently evaluated with ten further EU cities. The reliance on only two indicators shows that the model can be easily applied in addressing important greenhouse gas emission sources of European urbanites, when varying power generations are considered. This knowledge can help cities develop adequate climate change mitigation strategies and promote respective policies on the EU or the regional level. The results can further be used to derive first estimates of urban greenhouse gas emissions, if no other analyses are available. - Highlights: • Two variables determine urban GHG emissions in Europe, assuming equal power generation. • Household size, inner-urban compactness and power generation drive urban GHG emissions. • Climate policies should consider

  1. OPIC Greenhouse Gas Emissions Analysis Details

    Data.gov (United States)

    Overseas Private Investment Corporation — Summary project inventory with independent analysis to quantify the greenhouse gas ("GHG") emissions directly attributable to projects to which the Overseas Private...

  2. Modeling Greenhouse Gas Emissions from Enteric Fermentation

    NARCIS (Netherlands)

    Kebreab, E.; Tedeschi, L.; Dijkstra, J.; Ellis, J.L.; Bannink, A.; France, J.

    2016-01-01

    Livestock directly contribute to greenhouse gas (GHG) emissions mainly through methane (CH4) and nitrous oxide (N2O) emissions. For cost and practicality reasons, quantification of GHG has been through development of various types of mathematical models. This chapter addresses the utility and

  3. Does the Swedish consumer's choice of food influence greenhouse gas emissions?

    International Nuclear Information System (INIS)

    Wallen, Anna; Brandt, Nils; Wennersten, Ronald

    2004-01-01

    Consumer's choice of food can influence the environment. In Sweden, in common with many other countries, consumers need to be given information so they can make environmentally informed shopping choices. However, what is the most advantageous dietary choice to lower greenhouse emissions? This study investigates the greenhouse gas emissions associated with food production for food consumed in Sweden annually. Specifically, this study compares greenhouse gas emissions associated with a nutritionally and environmentally sustainable diet with the average consumption of food in Sweden 1999. The study concludes that the change in energy use and greenhouse gas emission associated with this change of diet is negligible. Lowering greenhouse gas emissions by changing food production processes results in more profound changes than teaching consumers to make environmentally correct choices. There is a basic need for a reduction or a replacement of the use of fossil fuels to produce and distribute our food in order to reach any significant reduction in the emission of greenhouse gases. Swedish agricultural policy does not provide ways to reduce greenhouse gas emissions. In Sweden therefore there is an immediate need to design policy instruments with the primary aim of reducing the greenhouse effect

  4. Dissolved organic carbon and nitrogen mineralization strongly affect co2 emissions following lime application to acidic soil

    International Nuclear Information System (INIS)

    Shaaban, M.; Peng, Q.; Lin, S.; Wu, Y.

    2014-01-01

    Emission of greenhouse gases from agricultural soils has main contribution to the climatic change and global warming. Dynamics of dissolved organic carbon (DOC) and nitrogen mineralization can affect CO/sub 2/ emission from soils. Influence of DOC and nitrogen mineralization on CO/sub 2/ emissions following lime application to acidic soil was investigated in current study. Laboratory experiment was conducted under aerobic conditions with 25% moisture contents (66% water-filled pore space) at 25 degree C in the dark conditions. Different treatments of lime were applied to acidic soil as follows: CK (control), L (low rate of lime: 0.2g lime / 100 g soil) and H (high rate of lime: 0.5g lime /100g soil). CO/sub 2/ emissions were measured by gas chromatography and dissolved organic carbon, NH4 +-N, NO/sub 3/ --N and soil pH were measured during incubation study. Addition of lime to acidic soil significantly increased the concentration of DOC and N mineralization rate. Higher concentrations of DOC and N mineralization, consequently, increased the CO/sub 2/ emissions from lime treated soils. Cumulative CO/sub 2/ emission was 75% and 71% higher from L and H treatments as compared to CK. The results of current study suggest that DOC and N mineralization are critical in controlling gaseous emissions of CO/sub 2/ from acidic soils following lime application. (author)

  5. Greenhouse gas emission measurement and economic analysis of Iran natural gas fired power plants

    International Nuclear Information System (INIS)

    Shahsavari Alavijeh, H.; Kiyoumarsioskouei, A.; Asheri, M.H.; Naemi, S.; Shahsavari Alavije, H.; Basirat Tabrizi, H.

    2013-01-01

    This study attempts to examine the natural gas fired power plants in Iran. The required data from natural gas fired power plants were gathered during 2008. The characteristics of thirty two gas turbine power plants and twenty steam power plants have been measured. Their emission factor values were then compared with the standards of Energy Protection Agency, Euro Union and World Bank. Emission factors of gas turbine and steam power plants show that gas turbine power plants have a better performance than steam power plants. For economic analysis, fuel consumption and environmental damages caused by the emitted pollutants are considered as cost functions; and electricity sales revenue are taken as benefit functions. All of these functions have been obtained according to the capacity factor. Total revenue functions show that gas turbine and steam power plants are economically efficient at 98.15% and 90.89% of capacity factor, respectively; this indicates that long operating years of power plants leads to reduction of optimum capacity factor. The stated method could be implemented to assess the economic status of a country’s power plants where as efficient capacity factor close to one means that power plant works in much better condition. - Highlights: • CO 2 and NO x emissions of Iran natural gas fired power plants have been studied. • CO 2 and NO x emission factors are compared with EPA, EU and World Bank standards. • Costs and benefit as economic functions are obtained according to capacity factor. • Maximum economic profit is obtained for gas turbine and steam power plants. • Investment in CO 2 reduction is recommended instead of investment in NO x reduction

  6. Estimation of methane emission from California natural gas industry.

    Science.gov (United States)

    Kuo, Jeff; Hicks, Travis C; Drake, Brian; Chan, Tat Fu

    2015-07-01

    Energy generation and consumption are the main contributors to greenhouse gases emissions in California. Natural gas is one of the primary sources of energy in California. A study was recently conducted to develop current, reliable, and California-specific source emission factors (EFs) that could be used to establish a more accurate methane emission inventory for the California natural gas industry. Twenty-five natural gas facilities were surveyed; the surveyed equipment included wellheads (172), separators (131), dehydrators (17), piping segments (145), compressors (66), pneumatic devices (374), metering and regulating (M&R) stations (19), hatches (34), pumps (2), and customer meters (12). In total, 92,157 components were screened, including flanges (10,101), manual valves (10,765), open-ended lines (384), pressure relief valves (358), regulators (930), seals (146), threaded connections (57,061), and welded connections (12,274). Screening values (SVs) were measured using portable monitoring instruments, and Hi-Flow samplers were then used to quantify fugitive emission rates. For a given SV range, the measured leak rates might span several orders of magnitude. The correlation equations between the leak rates and SVs were derived. All the component leakage rate histograms appeared to have the same trend, with the majority of leakage ratesGas Research Institute (EPA/GRI) study. Twenty-five natural gas facilities in California were surveyed to develop current, reliable, and California-specific source emission factors (EFs) for the natural gas industry. Screening values were measured by using portable monitoring instruments, and Hi-Flow samplers were then used to quantify fugitive emission rates. The component-level average EFs derived in this study are often smaller than the corresponding ones in the 1996 EPA/GRI study. The smaller EF values from this study might be partially attributable to the employment of the leak detection and repair program by most, if not all

  7. Unregulated greenhouse gas and ammonia emissions from current technology heavy-duty vehicles.

    Science.gov (United States)

    Thiruvengadam, Arvind; Besch, Marc; Carder, Daniel; Oshinuga, Adewale; Pasek, Randall; Hogo, Henry; Gautam, Mridul

    2016-11-01

    The study presents the measurement of carbonyl, BTEX (benzene, toluene, ethyl benzene, and xylene), ammonia, elemental/organic carbon (EC/OC), and greenhouse gas emissions from modern heavy-duty diesel and natural gas vehicles. Vehicles from different vocations that included goods movement, refuse trucks, and transit buses were tested on driving cycles representative of their duty cycle. The natural gas vehicle technologies included the stoichiometric engine platform equipped with a three-way catalyst and a diesel-like dual-fuel high-pressure direct-injection technology equipped with a diesel particulate filter (DPF) and a selective catalytic reduction (SCR). The diesel vehicles were equipped with a DPF and SCR. Results of the study show that the BTEX emissions were below detection limits for both diesel and natural gas vehicles, while carbonyl emissions were observed during cold start and low-temperature operations of the natural gas vehicles. Ammonia emissions of about 1 g/mile were observed from the stoichiometric natural gas vehicles equipped with TWC over all the driving cycles. The tailpipe GWP of the stoichiometric natural gas goods movement application was 7% lower than DPF and SCR equipped diesel. In the case of a refuse truck application the stoichiometric natural gas engine exhibited 22% lower GWP than a diesel vehicle. Tailpipe methane emissions contribute to less than 6% of the total GHG emissions. Modern heavy-duty diesel and natural gas engines are equipped with multiple after-treatment systems and complex control strategies aimed at meeting both the performance standards for the end user and meeting stringent U.S. Environmental Protection Agency (EPA) emissions regulation. Compared to older technology diesel and natural gas engines, modern engines and after-treatment technology have reduced unregulated emissions to levels close to detection limits. However, brief periods of inefficiencies related to low exhaust thermal energy have been shown to

  8. Construction and Operation of a Ventilated Hood System for Measuring Greenhouse Gas and Volatile Organic Compound Emissions from Cattle

    Directory of Open Access Journals (Sweden)

    Yongjing Zhao

    2011-12-01

    Full Text Available Recent interest in greenhouse gas emissions from ruminants, such as cattle, has spawned a need for affordable, precise, and accurate methods for the measurement of gaseous emissions arising from enteric fermentation. A new head hood system for cattle designed to capture and quantify emissions was recently developed at the University of California, Davis. The system consists of two head hoods, two vacuum pumps, and an instrumentation cabinet housing the required data collection equipment. This system has the capability of measuring carbon dioxide, methane, ethanol, methanol, water vapor, nitrous oxide, acetic acid emissions and oxygen consumption in real-time. A unique aspect of the hoods is the front, back, and sides are made of clear polycarbonate sheeting allowing the cattle a full range of vision during gas sampling. Recovery rates for these slightly negative pressure chambers were measured ranging from 97.6 to 99.3 percent. This system can capture high quality data for use in improving emission inventories and evaluating gaseous emission mitigation strategies.

  9. A global gas flaring black carbon emission rate dataset from 1994 to 2012

    Science.gov (United States)

    Huang, Kan; Fu, Joshua S.

    2016-11-01

    Global flaring of associated petroleum gas is a potential emission source of particulate matters (PM) and could be notable in some specific regions that are in urgent need of mitigation. PM emitted from gas flaring is mainly in the form of black carbon (BC), which is a strong short-lived climate forcer. However, BC from gas flaring has been neglected in most global/regional emission inventories and is rarely considered in climate modeling. Here we present a global gas flaring BC emission rate dataset for the period 1994-2012 in a machine-readable format. We develop a region-dependent gas flaring BC emission factor database based on the chemical compositions of associated petroleum gas at various oil fields. Gas flaring BC emission rates are estimated using this emission factor database and flaring volumes retrieved from satellite imagery. Evaluation using a chemical transport model suggests that consideration of gas flaring emissions can improve model performance. This dataset will benefit and inform a broad range of research topics, e.g., carbon budget, air quality/climate modeling, and environmental/human exposure.

  10. The Impact of a Potential Shale Gas Development in Germany and the United Kingdom on Pollutant and Greenhouse Gas Emissions

    Science.gov (United States)

    Weger, L.; Cremonese, L.; Bartels, M. P.; Butler, T. M.

    2016-12-01

    Several European countries with domestic shale gas reserves are considering extracting this natural gas resource to complement their energy transition agenda. Natural gas, which produces lower CO2 emissions upon combustion compared to coal or oil, has the potential to serve as a bridge in the transition from fossil fuels to renewables. However, the generation of shale gas leads to emissions of CH4 and pollutants such as PM, NOx and VOCs, which in turn impact climate as well as local and regional air quality. In this study, we explore the impact of a potential shale gas development in Europe, specifically in Germany and the United Kingdom, on emissions of greenhouse gases and pollutants. In order to investigate the effect on emissions, we first estimate a range of wells drilled per year and production volume for the two countries under examination based on available geological information and on regional infrastructural and economic limitations. Subsequently we assign activity data and emissions factors to the well development, gas production and processing stages of shale gas generation to enable emissions quantification. We then define emissions scenarios to explore different storylines of potential shale gas development, including low emissions (high level of regulation), high emissions (low level of regulation) and middle emissions scenarios, which influence fleet make-up, emission factor and activity data choices for emissions quantification. The aim of this work is to highlight important variables and their ranges, to promote discussion and communication of potential impacts, and to construct possible visions for a future shale gas development in the two study countries. In a follow-up study, the impact of pollutant emissions from these scenarios on air quality will be explored using the Weather Research and Forecasting model with chemistry (WRF-Chem) model.

  11. The EU Greenhouse Gas Emissions Trading Scheme

    NARCIS (Netherlands)

    Woerdman, Edwin; Woerdman, Edwin; Roggenkamp, Martha; Holwerda, Marijn

    2015-01-01

    This chapter explains how greenhouse gas emissions trading works, provides the essentials of the Directive on the European Union Emissions Trading Scheme (EU ETS) and summarizes the main implementation problems of the EU ETS. In addition, a law and economics approach is used to discuss the dilemmas

  12. Australia’s Consumption-based Greenhouse Gas Emissions

    DEFF Research Database (Denmark)

    Levitt, Clinton J.; Saaby, Morten; Sørensen, Anders

    2017-01-01

    We use data from the World Input-Output Database in a multiregional input–output model to analyse Australian consumption-based greenhouse gas emissions for the years 1995 to 2009. We find that the emission content of Australian macroeconomic activity has changed over the 15-year period. Consumption...

  13. Wellbeing impacts of city policies for reducing greenhouse gas emissions

    DEFF Research Database (Denmark)

    Hiscock, Rosemary; Mudu, Pierpaolo; Braubach, Matthias

    2014-01-01

    To mitigate climate change, city authorities are developing policies in areas such as transportation, housing and energy use, to reduce greenhouse gas emissions. In addition to their effects on greenhouse gas emissions, these policies are likely to have consequences for the wellbeing...... and subjective aspects which can be measured quantitatively; our review of measures informs the development of a theoretical model linking wellbeing to policies which cities use to reduce greenhouse gas emissions. Finally, we discuss the extent to which the links proposed in the conceptual model are supported...

  14. Leveling the playing field of transportation fuels: Accounting for indirect emissions of natural gas

    International Nuclear Information System (INIS)

    Sexton, Steven; Eyer, Jonathan

    2016-01-01

    Natural gas transportation fuels are credited in prior studies with greenhouse gas emissions savings relative to petroleum-based fuels and relative to the total emissions of biofuels. These analyses, however, overlook a source of potentially large indirect emissions from natural gas transportation fuels, namely the emissions from incremental coal-fired generation caused by price-induced substitutions away from natural-gas-fired electricity generation. Because coal-fired generation emits substantially more greenhouse gases and criteria air pollutants than natural-gas-fired generation, this indirect coal-use change effect diminishes potential emissions savings from natural gas transportation fuels. Estimates from a parameterized multi-market model suggest the indirect coal-use change effect rivals in magnitude the indirect land-use change effect of biofuels and renders natural gas fuels as carbon intensive as petroleum fuels. - Highlights: •Natural gas used in transport causes indirect emissions in the electricity sector. •These emissions result from increased coal use in electricity generation. •They rival in magnitude indirect land use change (ILUC) emissions of biofuels. •Natural gas fuels are estimated to be as carbon intensive as the petroleum fuels. •Policy ignores indirect emissions from natural gas.

  15. Effects of nitrogen fertilizer application on greenhouse gas emissions and economics of corn production.

    Science.gov (United States)

    Kim, Seungdo; Dale, Bruce E

    2008-08-15

    Nitrogen fertilizer plays an important role in corn cultivation in terms of both economic and environmental aspects. Nitrogen fertilizer positively affects corn yield and the soil organic carbon level, but it also has negative environmental effects through nitrogen-related emissions from soil (e.g., N20, NOx, NO3(-) leaching, etc.). Effects of nitrogen fertilizer on greenhouse gas emissions associated with corn grain are investigated via life cycle assessment. Ecoefficiency analysis is also used to determine an economically and environmentally optimal nitrogen application rate (NAR). The ecoefficiency index in this study is defined as the ratio of economic return due to nitrogen fertilizer to the greenhouse gas emissions of corn cultivation. Greenhouse gas emissions associated with corn grain decrease as NAR increases at a lower NAR until a minimum greenhouse gas emission level is reached because corn yield and soil organic carbon level increase with NAR. Further increasing NAR after a minimum greenhouse gas emission level raises greenhouse gas emissions associated with corn grain. Increased greenhouse gas emissions of corn grain due to nitrous oxide emissions from soil are much higher than reductions of greenhouse gas emissions of corn grain due to corn yield and changes in soil organic carbon levels at a higher NAR. Thus, there exists an environmentally optimal NAR in terms of greenhouse gas emissions. The trends of the ecoefficiency index are similar to those of economic return to nitrogen and greenhouse gas emissions associated with corn grain. Therefore, an appropriate NAR could enhance profitability as well as reduce greenhouse gas emissions associated with corn grain.

  16. Methane Emissions from Natural Gas in the Urban Region of Boston, Massachusetts

    Science.gov (United States)

    McKain, K.; Down, A.; Raciti, S. M.; Budney, J.; Hutyra, L.; Floerchinger, C. R.; Herndon, S. C.; Zahniser, M. S.; Nehrkorn, T.; Jackson, R. B.; Phillips, N. G.; Wofsy, S. C.

    2014-12-01

    Methane emissions from the natural gas supply chain must be quantified to assess environmental impacts of natural gas and to develop emission reduction strategies. We report natural gas emission rates for one year in the urban region of Boston, MA, using an atmospheric measurement and modeling framework. Continuous methane observations from four stations are combined with a high-resolution transport model to quantify the regional average emission rate, 20.6 ± 1.7 (95 % CI) g CH4 m-2 yr-1. Simultaneous observations of atmospheric ethane, compared with the ethane to methane ratio in pipeline gas, demonstrate that natural gas accounted for 58 - 100 % of methane emissions, depending on season. Using government statistics and geospatial data on energy consumption, we estimate the fractional loss rate to the atmosphere from all downstream components of the natural gas system, including transmission, distribution, and end-use, was 2.9 ± 0.3 % in the Boston urban region, compared to 1.1 % inferred by the Massachusetts greenhouse gas inventory.

  17. Cogeneration, renewables and reducing greenhouse gas emissions

    International Nuclear Information System (INIS)

    Naughten, B.; Dlugosz, J.

    1996-01-01

    The MENSA model is used to assess the potential role of cogeneration and selected new renewable energy technologies in cost-effectively reducing Greenhouse gas emissions. The model framework for analyzing these issues is introduced, together with an account of relevant aspects of its application. In the discussion of selected new renewable energy technologies, it is shown how microeconomic reform may encourage these technologies and fuels, and thereby reduce sector wide carbon dioxide emissions. Policy scenarios modelled are described and the simulation results are presented. Certain interventions in microeconomic reform may result in economic benefits while also reducing emissions: no regrets' opportunities. Some renewable energy technologies are also shown to be cost-effective in the event that targets and timetables for reducing Greenhouse gas emissions are imposed. However, ad hoc interventions in support of particular renewables options are unlikely to be consistent with a least cost approach to achieving environmental objectives. (author). 5 tabs., 5 figs., 21 refs

  18. Mitigating greenhouse gas emissions: Voluntary reporting

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-10-01

    The Voluntary Reporting Program, developed pursuant to Section 1605(b) of the Energy Policy Act of 1992, permits corporations, government agencies, households, and voluntary organizations to report on their emissions of greenhouse gases, and on actions taken that have reduced or avoided emissions or sequestered carbon, to the Energy Information Administration (EIA). This, the second annual report of the Voluntary Reporting Program, describes information provided by the participating organizations on their aggregate emissions and emissions reductions, as well as their emissions reduction or avoidance projects, through 1995. This information has been compiled into a database that includes reports from 142 organizations and descriptions of 967 projects that either reduced greenhouse gas emissions or sequestered carbon. Fifty-one reporters also provided estimates of emissions, and emissions reductions achieved, for their entire organizations. The projects described actions taken to reduce emissions of carbon dioxide from energy production and use; to reduce methane and nitrous oxide emissions from energy use, waste management, and agricultural processes; to reduce emissions of halocarbons, such as CFCs and their replacements; and to increase carbon sequestration.

  19. Greenhouse gas emissions related to agriculture and land-use practices

    International Nuclear Information System (INIS)

    Burke, L.M.; Lashof, D.A.

    1990-01-01

    This paper reports on the effects of increasing trace gas concentrations and concomitant climate change on agriculture which are likely to be substantial. With cropland and pasture now covering 2 , CH 4 , and N 2 O. Land clearing for agriculture and other purposes is responsible for 10 to 30% of total net CO 2 emissions; the rest is due to fossil fuel combustion. In addition, intentional burning of agricultural wastes, grasslands, and forests makes a significant contribution to global emissions of CO, CH 4 , NO x and N 2 O. Methane emissions from anaerobic respiration in rice (Oryza sativa L.) paddies and domestic animal remains account for 30 to 50% of the global total, making agriculture the dominant anthropogenic source of this gas. The amount of N 2 O emitted as a result of N fertilizer applications is highly uncertain, but may be on the order of 10% of total N 2 O emissions. Future agricultural greenhouse gas emissions will be affected by population growth, economic development, and agricultural practices. Greenhouse gas emissions are likely to increase substantially in the future unless steps are taken to control them. Investigating potential approaches to reducing these emissions while expanding production presents a major challenge to the agricultural research community

  20. LANDFILL GAS EMISSIONS MODEL (LANDGEM) VERSION 3.02 USER'S GUIDE

    Science.gov (United States)

    The Landfill Gas Emissions Model (LandGEM) is an automated estimation tool with a Microsoft Excel interface that can be used to estimate emission rates for total landfill gas, methane, carbon dioxide, nonmethane organic compounds, and individual air pollutants from municipal soli...

  1. CO and PAH Emissions from Engines Operating on Biomass Producer Gas

    DEFF Research Database (Denmark)

    Ahrenfeldt, Jesper; Jensen, Torben Kvist; Henriksen, Ulrik Birk

    2003-01-01

    High carbon monoxide (CO) emission from gas engines fueled by producer gas is a concerning problem in the struggle to make biomass gasification for heat and power production a success. The standing regulations concerning CO emissions from producer gas engine based power plants in most EU countrie...

  2. Quantifying methane emissions from natural gas production in north-eastern Pennsylvania

    Directory of Open Access Journals (Sweden)

    Z. R. Barkley

    2017-11-01

    Full Text Available Natural gas infrastructure releases methane (CH4, a potent greenhouse gas, into the atmosphere. The estimated emission rate associated with the production and transportation of natural gas is uncertain, hindering our understanding of its greenhouse footprint. This study presents a new application of inverse methodology for estimating regional emission rates from natural gas production and gathering facilities in north-eastern Pennsylvania. An inventory of CH4 emissions was compiled for major sources in Pennsylvania. This inventory served as input emission data for the Weather Research and Forecasting model with chemistry enabled (WRF-Chem, and atmospheric CH4 mole fraction fields were generated at 3 km resolution. Simulated atmospheric CH4 enhancements from WRF-Chem were compared to observations obtained from a 3-week flight campaign in May 2015. Modelled enhancements from sources not associated with upstream natural gas processes were assumed constant and known and therefore removed from the optimization procedure, creating a set of observed enhancements from natural gas only. Simulated emission rates from unconventional production were then adjusted to minimize the mismatch between aircraft observations and model-simulated mole fractions for 10 flights. To evaluate the method, an aircraft mass balance calculation was performed for four flights where conditions permitted its use. Using the model optimization approach, the weighted mean emission rate from unconventional natural gas production and gathering facilities in north-eastern Pennsylvania approach is found to be 0.36 % of total gas production, with a 2σ confidence interval between 0.27 and 0.45 % of production. Similarly, the mean emission estimates using the aircraft mass balance approach are calculated to be 0.40 % of regional natural gas production, with a 2σ confidence interval between 0.08 and 0.72 % of production. These emission rates as a percent of production are

  3. Quantifying methane emissions from natural gas production in north-eastern Pennsylvania

    Science.gov (United States)

    Barkley, Zachary R.; Lauvaux, Thomas; Davis, Kenneth J.; Deng, Aijun; Miles, Natasha L.; Richardson, Scott J.; Cao, Yanni; Sweeney, Colm; Karion, Anna; Smith, MacKenzie; Kort, Eric A.; Schwietzke, Stefan; Murphy, Thomas; Cervone, Guido; Martins, Douglas; Maasakkers, Joannes D.

    2017-11-01

    Natural gas infrastructure releases methane (CH4), a potent greenhouse gas, into the atmosphere. The estimated emission rate associated with the production and transportation of natural gas is uncertain, hindering our understanding of its greenhouse footprint. This study presents a new application of inverse methodology for estimating regional emission rates from natural gas production and gathering facilities in north-eastern Pennsylvania. An inventory of CH4 emissions was compiled for major sources in Pennsylvania. This inventory served as input emission data for the Weather Research and Forecasting model with chemistry enabled (WRF-Chem), and atmospheric CH4 mole fraction fields were generated at 3 km resolution. Simulated atmospheric CH4 enhancements from WRF-Chem were compared to observations obtained from a 3-week flight campaign in May 2015. Modelled enhancements from sources not associated with upstream natural gas processes were assumed constant and known and therefore removed from the optimization procedure, creating a set of observed enhancements from natural gas only. Simulated emission rates from unconventional production were then adjusted to minimize the mismatch between aircraft observations and model-simulated mole fractions for 10 flights. To evaluate the method, an aircraft mass balance calculation was performed for four flights where conditions permitted its use. Using the model optimization approach, the weighted mean emission rate from unconventional natural gas production and gathering facilities in north-eastern Pennsylvania approach is found to be 0.36 % of total gas production, with a 2σ confidence interval between 0.27 and 0.45 % of production. Similarly, the mean emission estimates using the aircraft mass balance approach are calculated to be 0.40 % of regional natural gas production, with a 2σ confidence interval between 0.08 and 0.72 % of production. These emission rates as a percent of production are lower than rates found in any

  4. Are greenhouse gas emissions from international shipping a type of marine pollution?

    International Nuclear Information System (INIS)

    Shi, Yubing

    2016-01-01

    Whether greenhouse gas emissions from international shipping are a type of marine pollution is a controversial issue and is currently open to debate. This article examines the current treaty definitions of marine pollution, and applies them to greenhouse gas emissions from ships. Based on the legal analysis of treaty definitions and relevant international and national regulation on this issue, this article asserts that greenhouse gas emissions from international shipping are a type of ‘conditional’ marine pollution. - Highlights: • Greenhouse gas (GHG) emissions from international shipping are a type of ‘conditional’ marine pollution. • Shipping CO 2 may be treated as marine pollution under the 1972 London Dumping Convention. • Countries have adopted different legislation concerning the legal nature of GHG emissions from ships. • Regulating CO 2 emissions from ships as marine pollution may expedite global GHG emissions reduction.

  5. Greenhouse Gas Emissions from Excavation on Residential Construction Sites

    Directory of Open Access Journals (Sweden)

    Perry Forsythe

    2014-12-01

    Full Text Available Despite considerable research concerning the manifestation of greenhouse gases in the usage of buildings, little has been done concerning emissions arising from the construction process itself. This paper specifically examines emissions arising from cut and fill excavation on residential construction sites. Even though such excavation is often seen as being economical in terms of providing a flat base for concrete raft slab construction, the environmental consequences of this approach need to be considered more fully in terms of impact on the environment. This is particularly important when steeply sloping sites are involved and for different soil types. The paper undertakes a study that quantitatively assesses the cumulative greenhouse gas emissions caused by cut and fill excavation on 52 residential projects in Australia for a range of slope and soil types. The paper presents results from the study and concludes that greenhouse gas emissions increase as site slope increases; the building footprint area (as distinct from Gross Floor Area, exposes the need to reduce the area of the building to reduce greenhouse gas emissions; excavation of rock soils creates higher emissions than other soil types; and cut and fill excavation on steeply slope sites increase emissions. Potential alternative construction includes suspended floor construction systems which involve less excavation.

  6. Greenhouse Gas Emissions from Excavation on Residential Construction Sites

    Directory of Open Access Journals (Sweden)

    Perry Forsythe

    2014-12-01

    Full Text Available Despite considerable research concerning the manifestation of greenhouse gases in the usage of buildings, little has been done concerning emissions arising from the construction process itself. This paper specifically examines emissions arising from cut and fill excavation on residential construction sites. Even though such excavation is often seen as being economical in terms of providing a flat base for concrete raft slab construction, the environmental consequences of this approach need to be considered more fully in terms of impact on the environment. This is particularly important when steeply sloping sites are involved and for different soil types. The paper undertakes a study that quantitatively assesses the cumulative greenhouse gas emissions caused by cut and fill excavation on 52 residential projects in Australia for a range of slope and soil types. The paper presents results from the study and concludes that greenhouse gas emissions increase as site slope increases; the building footprint area (as distinct from Gross Floor Area, exposes the need to reduce the area of the building to reduce greenhouse gas emissions; excavation of rock soils creates higher emissions than other soil types; and cut and fill excavation on steeply slope sites increase emissions. Potential alternative construction includes suspended floor construction systems which involve less excavation. 

  7. Acid dispersion abatement: the use of flue gas desulphurisation in the UK

    Energy Technology Data Exchange (ETDEWEB)

    Longhurst, J.W.S.; Health, B.A.; Gibber, D.C. [Manchester Metropolitan University, Manchester (United Kingdom). Atmospheric Research and Information Centre, Dept. of Environmental and Geographical Sciences

    1995-12-31

    This paper reviews and evaluates the development of the UK flue gas desulphurisation (FGD) programme. This programme on establishment in 1986 represented a planned and coherent approach to acid deposition abatement which would progressively reduce emissions whilst maintaining the UK`s coal fired power generation capacity. It was anticipated that at least 12000 MW of electricity generating plant would be retrofitted with FGD. The programme has effectively been abandoned in favour of market based approach to emission control which sets the targets to be achieved but not the means. As a consequence the retrofitted capacity in 1995 is just 6000 MW. 17 refs., 1 tab.

  8. Near-Zero Emissions Oxy-Combustion Flue Gas Purification

    Energy Technology Data Exchange (ETDEWEB)

    Minish Shah; Nich Degenstein; Monica Zanfir; Rahul Solunke; Ravi Kumar; Jennifer Bugayong; Ken Burgers

    2012-06-30

    The objectives of this project were to carry out an experimental program to enable development and design of near zero emissions (NZE) CO{sub 2} processing unit (CPU) for oxy-combustion plants burning high and low sulfur coals and to perform commercial viability assessment. The NZE CPU was proposed to produce high purity CO{sub 2} from the oxycombustion flue gas, to achieve > 95% CO{sub 2} capture rate and to achieve near zero atmospheric emissions of criteria pollutants. Two SOx/NOx removal technologies were proposed depending on the SOx levels in the flue gas. The activated carbon process was proposed for power plants burning low sulfur coal and the sulfuric acid process was proposed for power plants burning high sulfur coal. For plants burning high sulfur coal, the sulfuric acid process would convert SOx and NOx in to commercial grade sulfuric and nitric acid by-products, thus reducing operating costs associated with SOx/NOx removal. For plants burning low sulfur coal, investment in separate FGD and SCR equipment for producing high purity CO{sub 2} would not be needed. To achieve high CO{sub 2} capture rates, a hybrid process that combines cold box and VPSA (vacuum pressure swing adsorption) was proposed. In the proposed hybrid process, up to 90% of CO{sub 2} in the cold box vent stream would be recovered by CO{sub 2} VPSA and then it would be recycled and mixed with the flue gas stream upstream of the compressor. The overall recovery from the process will be > 95%. The activated carbon process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx, thus exceeding the performance targets of >99% and >95%, respectively. The process was also found to be suitable for power plants burning both low and high sulfur coals. Sulfuric acid process did not meet the performance expectations. Although it could achieve high SOx (>99%) and NOx (>90%) removal efficiencies, it could not produce by

  9. Greenhouse gas emissions in the Netherlands 1990-1996: Updated methodology

    NARCIS (Netherlands)

    Spakman J; Olivier JGJ; Loon MMJ van; LAE

    1997-01-01

    This inventory of greenhouse gas emissions in the Netherlands has been prepared according to the IPCC Guidelines and complies with the obligations under the European Union's Greenhouse Gas Monitoring Mechanism and the UN-FCCC for emission reports on greenhouse gases not covered under the Montreal

  10. Methane emissions due to oil and natural gas operations in the Netherlands

    International Nuclear Information System (INIS)

    Oonk, J.; Vosbeek, M.E.J.P.

    1995-01-01

    The Netherlands is the 4th largest natural gas producer, with about 4% of the total world natural gas production. Also, significant amounts of oil are extracted. For this reason it can be expected that methane emissions from oil and natural gas operations contribute significantly to total methane emissions. Estimates so far, made by both the Dutch government and the industry vary widely. A renewed estimate is made of methane emissions from oil and natural gas production, based on a detailed engineering study of sources of methane in the system and quantification of source strengths. The estimate is validated by interpretation of atmospheric measurements. 1990 methane emissions from natural gas production were estimated to be 62 to 108 kton. The main cause of methane emissions is the venting of off-gases from processes and passing-valve emissions in the off-shore. Emissions from oil production were estimated to be 14 kton, mainly caused by venting of off-gases from processes. Best feasible options for emission reduction are: identification and replacement of leaking valves, and reuse or re-compression of off-gases from processes. Both options are existing policy in the Netherlands. 23 figs., 38 tabs., 2 appendices, 53 refs

  11. 6.1 Greenhouse gas emissions and climate change

    International Nuclear Information System (INIS)

    2004-01-01

    In Austria, greenhouse gas emissions (GHG) have increased by about 10 % between 1990 and 2001. This means that already in 2001 the emissions reached the level projected with current measures for 2010. Thus Austria is far from complying with the 13 % reduction required under the Kyoto Protocol, meaning that GHG emissions will have to be reduce annually by 1.4 million tons of CO 2 -equivalents to fulfill its protocol obligation. It is shown that 2001 GHG emissions had increased by 9.6 % since the base year 1990, the main reason for this increase is the growing use of fossil fuels and the resulting increase in CO 2 emissions. The highest growth rates can be observed in the transport sector by almost half (+ 49 %). Basically, greenhouse gas emission trends depend on a number of factors, about two thirds of them are caused by energy production, so the most important parameters affecting GHG are the trends of energy consumption, the energy mix and the following factors: population growth, economic growth, outdoor temperature and the resulting heating requirements, improvement of energy efficiency, the proportion of renewable energy sources such as electricity generation in hydroelectric power stations (which influences the need for supplementary power production in thermal power plants), the mix of fossil fuels, for example in caloric power plants (natural gas combustion produces about 40 % less CO 2 per energy unit than coal combustion), the structure and price effects of energy market liberalization, which influence the use of various fuels in electricity production and the import of electricity, world market prices for energy, structural changes in the economy and in the behavior of consumers. Changes in important driving forces and in GHG emissions, sector emissions trends and Austrian, European and global emissions projections are provided. (nevyjel)

  12. Greenhouse Gas Emissions Calculator for Grain and Biofuel Farming Systems

    Science.gov (United States)

    McSwiney, Claire P.; Bohm, Sven; Grace, Peter R.; Robertson, G. Philip

    2010-01-01

    Opportunities for farmers to participate in greenhouse gas (GHG) credit markets require that growers, students, extension educators, offset aggregators, and other stakeholders understand the impact of agricultural practices on GHG emissions. The Farming Systems Greenhouse Gas Emissions Calculator, a web-based tool linked to the SOCRATES soil…

  13. Portuguese agriculture and the evolution of greenhouse gas emissions-can vegetables control livestock emissions?

    Science.gov (United States)

    Mourao, Paulo Reis; Domingues Martinho, Vítor

    2017-07-01

    One of the most serious externalities of agricultural activity relates to greenhouse gas emissions. This work tests this relationship for the Portuguese case by examining data compiled since 1961. Employing cointegration techniques and vector error correction models (VECMs), we conclude that the evolution of the most representative vegetables and fruits in Portuguese production are associated with higher controls on the evolution of greenhouse gas emissions. Reversely, the evolution of the output levels of livestock and the most representative animal production have significantly increased the level of CO 2 (carbon dioxide) reported in Portugal. We also analyze the cycle length of the long-term relationship between agricultural activity and greenhouse gas emissions. In particular, we highlight the case of synthetic fertilizers, whose values of CO 2 have quickly risen due to changes in Portuguese vegetables, fruit, and animal production levels.

  14. Modeling greenhouse gas emissions from dairy farms.

    Science.gov (United States)

    Rotz, C Alan

    2017-11-15

    Dairy farms have been identified as an important source of greenhouse gas emissions. Within the farm, important emissions include enteric CH 4 from the animals, CH 4 and N 2 O from manure in housing facilities during long-term storage and during field application, and N 2 O from nitrification and denitrification processes in the soil used to produce feed crops and pasture. Models using a wide range in level of detail have been developed to represent or predict these emissions. They include constant emission factors, variable process-related emission factors, empirical or statistical models, mechanistic process simulations, and life cycle assessment. To fully represent farm emissions, models representing the various emission sources must be integrated to capture the combined effects and interactions of all important components. Farm models have been developed using relationships across the full scale of detail, from constant emission factors to detailed mechanistic simulations. Simpler models, based upon emission factors and empirical relationships, tend to provide better tools for decision support, whereas more complex farm simulations provide better tools for research and education. To look beyond the farm boundaries, life cycle assessment provides an environmental accounting tool for quantifying and evaluating emissions over the full cycle, from producing the resources used on the farm through processing, distribution, consumption, and waste handling of the milk and dairy products produced. Models are useful for improving our understanding of farm processes and their interacting effects on greenhouse gas emissions. Through better understanding, they assist in the development and evaluation of mitigation strategies for reducing emissions and improving overall sustainability of dairy farms. The Authors. Published by the Federation of Animal Science Societies and Elsevier Inc. on behalf of the American Dairy Science Association®. This is an open access article

  15. Reducing Greenhouse Gas Emissions from Agricultural Wetlands in Borneo

    Science.gov (United States)

    Abdul, H.; Fatah, L.; Nursyamsi, D.; Kazuyuki, I.

    2011-12-01

    At the forum G20 meeting in 2009, Indonesian President delivered Indonesia's commitment to reduce national greenhouse gas (GHG) emissions by 26% in 2020 by unilateral action and by 41% with support of other countries. To achieve the target, Indonesian government has put forestry, agriculture (including peatlands), energy, industry and transportation as main responsible sectors. Development of crop with low GHG emissions, increasing C sequestration and the use of organic fertilizers are among the activities to be carried out in 2010-2020 period to minimize GHG emissions from agricultural sectors. Three experiments have been carried out to elucidate the reflectivity of crop selection, soil ameliorants and organic fertilizers on GHG emissions from agricultural wetlands in Borneo. Firstly, gas samples were collected in weekly basis from oil palm, paddy, and vegetables fields and analyzed for methane (CH4) and nitrous oxide (N2O) concentrations by a gas chromatography. Secondly, coal fly ash, dolomite and ZnSO4 were incorporated into a pot containing peat and/or alluvial soils taken from wetlands in South Kalimantan. The air samples were taken and analyzed for CH4 by a gas chromatography. Finally, microbial consortium are isolated from soil, sediment and cow dung. The microbes were then propagated and used in a rice straw composting processes. The CO2, CH4 and N2O emissions from composting vessel were measured at one, two and four weeks of composting processes. The results showed that shifting the use of peatlands for oil palm to vegetable field reduced the GHG emissions by about 74% and that to paddy field reduce the GHG emissions by about 82%. The CH4 emissions from paddy field can be further reduced by applying dolomite. However, the use of coal fly ash and ZnSO4 increased CH4 emissions from peat soil cultivated to rice. The use of microbe isolated from saline soil could reduce GHG emissions during the composting of rice straw. The social aspect of GHG reduction in

  16. Greenhouse gas emission reduction options and strategies

    International Nuclear Information System (INIS)

    Kane, R.L.

    1994-01-01

    This paper describes the energy-related components of the Clinton Administration's Climate Change Action Plan. The Action Plan was formulated to meet the Administration's commitment of returning US emissions of greenhouse gases to 1990 levels by the year 2000. The paper discusses what the energy industry and energy consumers will be requested to do in order to meet this commitment. Several themes addressed in this paper include: (1) the largely voluntary nature of the actions identified in the Action Plan; (2) consideration of diverse opportunities to reduce emissions; (3) the outlook for US greenhouse gas emissions after 2000; and (4) actions involved for speeding the utilization of new, energy efficient technologies both domestically and abroad. The value of employing a diverse set of activities and the important role of technology improvements will be explored further in section 10 of this volume: ''Greenhouse Gas Emission Mitigation Strategies.'' Papers presented there include the utilization of more efficient fossil energy technologies, energy conservation and demand-side management programs, renewable energy and reforestation, and carbon dioxide capture and disposal

  17. Gas Emission Prediction Model of Coal Mine Based on CSBP Algorithm

    Directory of Open Access Journals (Sweden)

    Xiong Yan

    2016-01-01

    Full Text Available In view of the nonlinear characteristics of gas emission in a coal working face, a prediction method is proposed based on cuckoo search algorithm optimized BP neural network (CSBP. In the CSBP algorithm, the cuckoo search is adopted to optimize weight and threshold parameters of BP network, and obtains the global optimal solutions. Furthermore, the twelve main affecting factors of the gas emission in the coal working face are taken as input vectors of CSBP algorithm, the gas emission is acted as output vector, and then the prediction model of BP neural network with optimal parameters is established. The results show that the CSBP algorithm has batter generalization ability and higher prediction accuracy, and can be utilized effectively in the prediction of coal mine gas emission.

  18. Methane emissions from natural gas pipelines - current estimates, technologies and practices

    International Nuclear Information System (INIS)

    Lang, M.C.; Crook, L.

    1997-01-01

    Methane is the major component of natural gas. World-wide methane emissions from gas systems is estimated to be between 50 and 25 tera grams or about 5 percent of the world-wide total of anthropogenic methane emissions. Technologies and practices are described that are currently being used or are planned to be used in the US to both measure and/or reduce methane emissions from natural gas pipelines. One of the technologies that is described includes a high flow sampling instrument. One of the practices that is described is the current voluntary program conducted by the US Environmental Protection Agency called the Natural Gas Star program. This program supports research into best management practices, information sharing and technology transfer to promote methane emissions reductions profitably. (R.P.)

  19. Estimate of methane emissions from the U.S. natural gas industry

    International Nuclear Information System (INIS)

    Kirchgessner, D.A.; Lott, R.A.; Cowgill, R.M.; Harrison, M.R.; Shires, T.M.

    1997-01-01

    Global methane emissions from the fossil fuel industries have been poorly quantified and, in many cases, emissions are not well-known even at the country level. Historically, methane emissions from the U.S. gas industry have been based on sparse data, incorrect assumptions, or both. As a result, the estimate of the contribution these emissions make to the global methane inventory could be inaccurate. For this reason the assertion that global warming could be reduced by replacing coal and oil fuels with natural gas could not be defended. A recently completed, multi year study conducted by the U.S. Environmental Protection Agency's Office of Research and Development and the Gas Research Institute, had the objective of determining methane emissions from the U.S. gas industry with an accuracy of ± 0.5% of production. The study concluded that, in the 1992 base year, methane emissions from the industry were 314 ± 105 Bscf or 6.04 ± 2.01 Tg (all conversions to international units are made at 15.56 o C and 101.325 kPa). (author)

  20. The Natural Gas Vehicle Challenge 1992: Exhaust emissions testing and results

    Science.gov (United States)

    Rimkus, W. A.; Larsen, R. P.; Zammit, M. G.; Davies, J. G.; Salmon, G. S.; Bruetsch, R. I.

    The Natural Gas Vehicle (NGV) Challenge '92, was organized by Argonne National Laboratory. The main sponsors were the U.S. Department of Energy the Energy, Mines, and Resources -- Canada, and the Society of Automotive Engineers. It resulted in 20 varied approaches to the conversion of a gasoline-fueled, spark-ignited, internal combustion engine to dedicated natural gas use. Starting with a GMC Sierra 2500 pickup truck donated by General Motors, teams of college and university student engineers worked to optimize Chevrolet V-8 engines operating on natural gas for improved emissions, fuel economy, performance, and advanced design features. This paper focuses on the results of the emission event, and compares engine mechanical configurations, engine management systems, catalyst configurations and locations, and approaches to fuel control and the relationship of these parameters to engine-out and tailpipe emissions of regulated exhaust constituents. Nine of the student modified trucks passed the current levels of exhaust emission standards, and some exceeded the strictest future emissions standards envisioned by the U.S. Environmental Protection Agency. Factors contributing to good emissions control using natural gas are summarized, and observations concerning necessary components of a successful emissions control strategy are presented.

  1. Direct greenhouse gas emissions of the game industry in South Africa

    African Journals Online (AJOL)

    Direct greenhouse gas emissions of the game industry in South Africa. ... Previous greenhouse gas (GHG) inventories did not include game as an emissions source. Recently game farming has ... AJOL African Journals Online. HOW TO USE ...

  2. Reducing greenhouse gas emissions from u.s. transportation

    Science.gov (United States)

    2010-01-01

    This report examines the prospects for substantially reducing the greenhouse gas (GHG) emissions from the U.S. transportation sector, which accounts for 27 percent of the GHG emissions of the entire U.S. economy and 30 percent of the world's transpor...

  3. Reducing greenhouse gas emissions through operations and supply chain management

    International Nuclear Information System (INIS)

    Plambeck, Erica L.

    2012-01-01

    The experiences of the largest corporation in the world and those of a start-up company show how companies can profitably reduce greenhouse gas emissions in their supply chains. The operations management literature suggests additional opportunities to profitably reduce emissions in existing supply chains, and provides guidance for expanding the capacity of new “zero emission” supply chains. The potential for companies to profitably reduce emissions is substantial but (without effective climate policy) likely insufficient to avert dangerous climate change. - Highlights: ► Describes how firms are profitably reducing greenhouse gas emissions in their supply chains ► Highlights academic literature relevant to supply chain emission reduction

  4. Accounting For Greenhouse Gas Emissions From Flooded Lands

    Science.gov (United States)

    Nearly three decades of research has demonstrated that the inundation of rivers and terrestrial ecosystems behind dams can lead to enhanced rates of greenhouse gas emissions, particularly methane. The 2006 IPCC Guidelines for National Greenhouse Gas Inventories includes a method...

  5. Greenhouse Gas Emissions in the Netherlands 1990-2010. National Inventory Report 2012

    Energy Technology Data Exchange (ETDEWEB)

    Coenen, P.W.H.G.; Van der Hoek, K.W.; Te Molder, R.; Droege, R. [Netherlands Organisation for Applied Scientific Research TNO, P.O. Box 80015, NL-3508 TA Utrecht (Netherlands); Van der Maas, C.W.M.; Zijlema, P.J.; Van den Berghe, A.C.W.M. [NL Agency, P.O. Box 8242, NL-3503 RE Utrecht (Netherlands); Baas, K. [Statistics Netherlands CBS, P.O. Box 24500, NL-2490 HA Den Haag (Netherlands); Te Biesebeek, J.D.; Brandt, A.T. [Dutch Emission Authority, P.O. Box 91503, IPC 652, NL-2509 EC Den Haag (Netherlands); Geilenkirchen, G. [Netherlands Environmental Assessment Agency PBL, P.O. Box 303 NL-3720 AH Bilthoven (Netherlands); Montfoort, J.A.; Peek, C.J.; Vonk, J.; Van den Wyngaert, I. [Alterra Wageningen UR, P.O. Box 47 NL-6700 AA Wageningen (Netherlands)

    2012-03-15

    The total greenhouse gas emission from the Netherlands in 2010 increased by approximately 6% compared to the emission in 2009. This increase is mainly the result of increased fuel combustion in the energy sector and space heating. In 2010, total direct greenhouse gas emissions (excluding emissions from LULUCF - land use, land use change and forestry) in the Netherlands amounted to 210.1 Tg CO2 eq. This is approximately 1.5% below the emissions in the base year (213.3 Tg CO2 eq). This report documents the 2012 Netherlands' annual submission of its greenhouse gas emission inventory in accordance with the guidelines provided by the United Nations Framework Convention on Climate Change (UNFCCC), the Kyoto Protocol and the European Union's Greenhouse Gas Monitoring Mechanism. The report comprises explanations of observed trends in emissions; a description of an assessment of key sources and their uncertainty; documentation of methods, data sources and emission factors applied; and a description of the quality assurance system and the verification activities performed on the data.

  6. Greenhouse Gas Emissions in the Netherlands 1990-2009. National Inventory Report 2011

    Energy Technology Data Exchange (ETDEWEB)

    Coenen, P.W.H.G.; Van der Hoek, K.W.; Te Molder, R.; Droege, R. [Netherlands Organisation for Applied Scientific Research TNO, P.O. Box 80015, NL-3508 TA Utrecht (Netherlands); Van der Maas, C.W.M.; Zijlema, P.J.; Van den Berghe, A.C.W.M. [NL Agency, P.O. Box 8242, NL-3503 RE Utrecht (Netherlands); Baas, K. [Statistics Netherlands CBS, P.O. Box 24500, NL-2490 HA Den Haag (Netherlands); Te Biesebeek, J.D.; Brandt, A.T. [Dutch Emission Authority, P.O. Box 91503, IPC 652, NL-2509 EC Den Haag (Netherlands); Geilenkirchen, G. [Netherlands Environmental Assessment Agency PBL, P.O. Box 303 NL-3720 AH Bilthoven (Netherlands); Montfoort, J.A.; Peek, C.J.; Vonk, J.; Van den Wyngaert, I. [Alterra Wageningen UR, P.O. Box 47 NL-6700 AA Wageningen (Netherlands)

    2012-03-15

    The total greenhouse gas emission from the Netherlands in 2010 increased by approximately 6% compared to the emission in 2009. This increase is mainly the result of increased fuel combustion in the energy sector and space heating. In 2010, total direct greenhouse gas emissions (excluding emissions from LULUCF - land use, land use change and forestry) in the Netherlands amounted to 210.1 Tg CO2 eq. This is approximately 1.5% below the emissions in the base year (213.3 Tg CO2 eq). This report documents the 2012 Netherlands' annual submission of its greenhouse gas emission inventory in accordance with the guidelines provided by the United Nations Framework Convention on Climate Change (UNFCCC), the Kyoto Protocol and the European Union's Greenhouse Gas Monitoring Mechanism. The report comprises explanations of observed trends in emissions; a description of an assessment of key sources and their uncertainty; documentation of methods, data sources and emission factors applied; and a description of the quality assurance system and the verification activities performed on the data.

  7. Greenhouse Gas Emissions in the Netherlands 1990-2009. National Inventory Report 2011

    International Nuclear Information System (INIS)

    Van der Maas, C.W.M.; Coenen, P.W.H.G.; Van der Hoek, K.W.; Te Molder, R.; Droege, R.; Zijlema, P.J.; Van den Berghe, G.; Baas, K.; Te Biesebeek, J.D.; Brandt, A.T.; Geilenkirchen, G.; Peek, C.J.; Vonk, J.; Van den Wyngaert, I.

    2011-04-01

    The total greenhouse gas emission from the Netherlands in 2009 decreased by approximately 3% compared to the emission in 2008. This decrease is a result of the economic crisis, especially due to the decrease in the industrial production. In 2009, total direct greenhouse gas emissions (excluding emissions from LULUCF - land use, land use change and forestry) in the Netherlands amount to 198.9Tg CO2 eq. This is nearly 7 % below the emissions in the base year 1990 (213.2 Tg CO2 eq). This report documents the 2011 Netherlands' annual submission of its greenhouse gas emission inventory in accordance with the guidelines provided by the United Nations Framework Convention on Climate Change (UNFCCC), the Kyoto Protocol and the European Union's Greenhouse Gas Monitoring Mechanism. The report comprises explanations of observed trends in emissions; a description of an assessment of key sources and their uncertainty; documentation of methods, data sources and emission factors applied; and a description of the quality assurance system and the verification activities performed on the data.

  8. Greenhouse Gas Emissions in the Netherlands 1990-2009. National Inventory Report 2011

    Energy Technology Data Exchange (ETDEWEB)

    Coenen, P W.H.G.; Van der Hoek, K W; Te Molder, R; Droege, R [Netherlands Organisation for Applied Scientific Research TNO, P.O. Box 80015, NL-3508 TA Utrecht (Netherlands); Van der Maas, C W.M.; Zijlema, P J; Van den Berghe, A C.W.M. [NL Agency, P.O. Box 8242, NL-3503 RE Utrecht (Netherlands); Baas, K [Statistics Netherlands CBS, P.O. Box 24500, NL-2490 HA Den Haag (Netherlands); Te Biesebeek, J D; Brandt, A T [Dutch Emission Authority, P.O. Box 91503, IPC 652, NL-2509 EC Den Haag (Netherlands); Geilenkirchen, G [Netherlands Environmental Assessment Agency PBL, P.O. Box 303 NL-3720 AH Bilthoven (Netherlands); Montfoort, J A; Peek, C J; Vonk, J; Van den Wyngaert, I [Alterra Wageningen UR, P.O. Box 47 NL-6700 AA Wageningen (Netherlands)

    2012-03-15

    The total greenhouse gas emission from the Netherlands in 2010 increased by approximately 6% compared to the emission in 2009. This increase is mainly the result of increased fuel combustion in the energy sector and space heating. In 2010, total direct greenhouse gas emissions (excluding emissions from LULUCF - land use, land use change and forestry) in the Netherlands amounted to 210.1 Tg CO2 eq. This is approximately 1.5% below the emissions in the base year (213.3 Tg CO2 eq). This report documents the 2012 Netherlands' annual submission of its greenhouse gas emission inventory in accordance with the guidelines provided by the United Nations Framework Convention on Climate Change (UNFCCC), the Kyoto Protocol and the European Union's Greenhouse Gas Monitoring Mechanism. The report comprises explanations of observed trends in emissions; a description of an assessment of key sources and their uncertainty; documentation of methods, data sources and emission factors applied; and a description of the quality assurance system and the verification activities performed on the data.

  9. Greenhouse Gas Emissions in the Netherlands 1990-2010. National Inventory Report 2012

    Energy Technology Data Exchange (ETDEWEB)

    Coenen, P. W.H.G.; Van der Hoek, K. W.; Te Molder, R.; Droege, R. [Netherlands Organisation for Applied Scientific Research TNO, P.O. Box 80015, NL-3508 TA Utrecht (Netherlands); Van der Maas, C. W.M.; Zijlema, P. J.; Van den Berghe, A. C.W.M. [NL Agency, P.O. Box 8242, NL-3503 RE Utrecht (Netherlands); Baas, K. [Statistics Netherlands CBS, P.O. Box 24500, NL-2490 HA Den Haag (Netherlands); Te Biesebeek, J. D.; Brandt, A. T. [Dutch Emission Authority, P.O. Box 91503, IPC 652, NL-2509 EC Den Haag (Netherlands); Geilenkirchen, G. [Netherlands Environmental Assessment Agency PBL, P.O. Box 303 NL-3720 AH Bilthoven (Netherlands); Montfoort, J. A.; Peek, C. J.; Vonk, J.; Van den Wyngaert, I. [Alterra Wageningen UR, P.O. Box 47 NL-6700 AA Wageningen (Netherlands)

    2012-03-15

    The total greenhouse gas emission from the Netherlands in 2010 increased by approximately 6% compared to the emission in 2009. This increase is mainly the result of increased fuel combustion in the energy sector and space heating. In 2010, total direct greenhouse gas emissions (excluding emissions from LULUCF - land use, land use change and forestry) in the Netherlands amounted to 210.1 Tg CO2 eq. This is approximately 1.5% below the emissions in the base year (213.3 Tg CO2 eq). This report documents the 2012 Netherlands' annual submission of its greenhouse gas emission inventory in accordance with the guidelines provided by the United Nations Framework Convention on Climate Change (UNFCCC), the Kyoto Protocol and the European Union's Greenhouse Gas Monitoring Mechanism. The report comprises explanations of observed trends in emissions; a description of an assessment of key sources and their uncertainty; documentation of methods, data sources and emission factors applied; and a description of the quality assurance system and the verification activities performed on the data.

  10. Evaluation of greenhouse gas emissions from waste management approaches in the islands.

    Science.gov (United States)

    Chen, Ying-Chu

    2017-07-01

    Concerns about waste generation and climate change have attracted worldwide attention. Small islands, which account for more than one-sixth of the global land area, are facing problems caused by global climate change. This study evaluated the greenhouse gas emissions from five small islands surrounding Taiwan. These islands - Penghu County, Liuqui Island, Kinmen County, Matsu Island and Green Island - have their own waste management approaches that can serve as a guideline for waste management with greenhouse gas mitigation. The findings indicate that the total annual greenhouse gas emissions of the islands ranged from 292.1 to 29,096.2 [metric] tonne CO 2 -equivalent. The loading waste volumes and shipping distances were positively related to greenhouse gas emissions from transportation. The greenhouse gas emissions from waste-to-energy plants, mainly carbon dioxide and nitrous oxide, can be offset by energy recovery (approximately 38.6% of greenhouse gas emissions from incineration). In addition, about 34% and 11% of waste generated on the islands was successfully recycled and composted, respectively. This study provides valuable insights into the applicability of a policy framework for waste management approaches for greenhouse gas mitigation.

  11. Real-time emission factor measurements of isocyanic acid from light duty gasoline vehicles.

    Science.gov (United States)

    Brady, James M; Crisp, Timia A; Collier, Sonya; Kuwayama, Toshihiro; Forestieri, Sara D; Perraud, Véronique; Zhang, Qi; Kleeman, Michael J; Cappa, Christopher D; Bertram, Timothy H

    2014-10-07

    Exposure to gas-phase isocyanic acid (HNCO) has been previously shown to be associated with the development of atherosclerosis, cataracts and rheumatoid arthritis. As such, accurate emission inventories for HNCO are critical for modeling the spatial and temporal distribution of HNCO on a regional and global scale. To date, HNCO emission rates from light duty gasoline vehicles, operated under driving conditions, have not been determined. Here, we present the first measurements of real-time emission factors of isocyanic acid from a fleet of eight light duty gasoline-powered vehicles (LDGVs) tested on a chassis dynamometer using the Unified Driving Cycle (UC) at the California Air Resources Board (CARB) Haagen-Smit test facility, all of which were equipped with three-way catalytic converters. HNCO emissions were observed from all vehicles, in contrast to the idealized laboratory measurements. We report the tested fleet averaged HNCO emission factors, which depend strongly on the phase of the drive cycle; ranging from 0.46 ± 0.13 mg kg fuel(-1) during engine start to 1.70 ± 1.77 mg kg fuel(-1) during hard acceleration after the engine and catalytic converter were warm. The tested eight-car fleet average fuel based HNCO emission factor was 0.91 ± 0.58 mg kg fuel(-1), within the range previously estimated for light duty diesel-powered vehicles (0.21-3.96 mg kg fuel(-1)). Our results suggest that HNCO emissions from LDGVs represent a significant emission source in urban areas that should be accounted for in global and regional models.

  12. Greenhouse gas and livestock emissions and climate change

    DEFF Research Database (Denmark)

    Caro, Dario

    2018-01-01

    The paper summarizes the current knowledge about the impact of livestock sector on climate change. The main sources of greenhouse gas (GHG) emissions from livestock are described and the contribution of livestock sector to the global GHG emissions is presented on the basis of the latest results...... obtained from the scientific research. The most recent mitigation strategies for reducing greenhouse gas emissions from livestock sector are also discussed. The paper aims to provide a general overview of an emergent environmental issue such as the impact of livestock sector on climate change. While...... the paper is easy to understand for non-expert readers, it may also be a relevant reference point for academic researchers and for policy makers aimed at achieving the sustainability of livestock/food sector....

  13. Greenhouse gas emissions of Dutch biomass. Quantification of greenhouse gases emission of Dutch biomass for electricity and heat

    International Nuclear Information System (INIS)

    Koop, K.; Yildiz, I.

    2010-09-01

    The greenhouse gas emissions of all available flows of the biomass chain have been established. This report has the following aims: (1) to establish the greenhouse gas emission of Dutch biomass available for generating electricity and heat; (2) to obtain insight in the opportunities and threats for using the potential of the biomass chains that have the highest potential to reduce greenhouse gas emissions. This report can be seen as a supplement to the report 'Availability of Dutch biomass for electricity and heat in 2020' (2009) [nl

  14. Mitigating gas emissions at signalised intersections using wireless vehicle detectors

    Directory of Open Access Journals (Sweden)

    Moses Kwasi Torkudzor

    2015-09-01

    Full Text Available Traffic congestion on roads wastes travel times and increases fuel consumption as well as gas emissions which are dangerous to human health. This has led to growing concern about environmental protection and energy conservation and a number of studies to increase fuel economy and reduce gas emissions. To increase travel times so as to reduce fuel consumption and gas emissions, traffic signals at intersections must be well implemented. It is therefore necessary to employ the current technology of wireless sensor networks to enhance the optimisation of the signalised intersections so as to address such a concern. In this study, a vehicular traffic control model was developed to optimise a signalised intersection, using wireless vehicle detectors. Real-time traffic volume gathered were analysed to obtain the peak hour traffic volume causing congestion. The intersection was modelled and simulated in Synchro7 as an actuated signalised model using results from the analysed data. The model for morning peak and evening peak periods gave optimal cycle lengths which result in the reduction of gas emissions, fuel consumption and delay at the intersection.

  15. Greenhouse gas emissions in an agroforestry system in the southeastern USA

    Science.gov (United States)

    Agroforestry systems may provide diverse ecosystem services and economic benefits that conventional agriculture cannot, e.g. potentially mitigating greenhouse gas emissions by enhancing nutrient cycling, since tree roots can capture nutrients not taken up by crops. However, greenhouse gas emission ...

  16. Quantifying and reporting greenhouse gas emissions at local level

    Directory of Open Access Journals (Sweden)

    Sόwka Izabela

    2017-01-01

    Full Text Available Cities as global centers of consumption and production often are a significant and growing source of greenhouse gas (GHG emissions. At the same time, local authorities are increasingly taking action on climate change by focusing on reducing GHG emissions and efficiency improvement opportunities. To assess and reduce the overall greenhouse gas emission level from an urban area, it is necessary to identify all the activities and processes which generate these emissions. GHG inventory gives an opportunity to get wider knowledge for city’s community about spatial emission processes and emissions contribution of key sources categories at the local scale. Inventory is being used for decision-making purposes and strategic planning in emission reduction policy. The goal of this paper was to clarify the major methodological challenges of GHG monitoring at the urban level. The paper is based on the discussion of different methods and approaches to assessing GHG emissions at the local level. It is presented sectoral GHGs emission trends in selected urban areas and compared CO2 emission level in different countries and metropolises and variable European cities guidance. The study determines the inventory tools of GHGs emission taking into account the characteristics of main sources at local levels.

  17. Gas breakthrough and emission through unsaturated compacted clay in landfill final cover

    International Nuclear Information System (INIS)

    Ng, C.W.W.; Chen, Z.K.; Coo, J.L.; Chen, R.; Zhou, C.

    2015-01-01

    Highlights: • Explore feasibility of unsaturated clay as a gas barrier in landfill cover. • Gas breakthrough pressure increases with clay thickness and degree of saturation. • Gas emission rate decreases with clay thickness and degree of saturation. • A 0.6 m-thick clay layer may be sufficient to meet gas emission rate limit. - Abstract: Determination of gas transport parameters in compacted clay plays a vital role for evaluating the effectiveness of soil barriers. The gas breakthrough pressure has been widely studied for saturated swelling clay buffer commonly used in high-level radioactive waste disposal facility where the generated gas pressure is very high (in the order of MPa). However, compacted clay in landfill cover is usually unsaturated and the generated landfill gas pressure is normally low (typically less than 10 kPa). Furthermore, effects of clay thickness and degree of saturation on gas breakthrough and emission rate in the context of unsaturated landfill cover has not been quantitatively investigated in previous studies. The feasibility of using unsaturated compacted clay as gas barrier in landfill covers is thus worthwhile to be explored over a wide range of landfill gas pressures under various degrees of saturation and clay thicknesses. In this study, to evaluate the effectiveness of unsaturated compacted clay to minimize gas emission, one-dimensional soil column tests were carried out on unsaturated compacted clay to determine gas breakthrough pressures at ultimate limit state (high pressure range) and gas emission rates at serviceability limit state (low pressure range). Various degrees of saturation and thicknesses of unsaturated clay sample were considered. Moreover, numerical simulations were carried out using a coupled gas–water flow finite element program (CODE-BRIGHT) to better understand the experimental results by extending the clay thickness and varying the degree of saturation to a broader range that is typical at different

  18. Gas breakthrough and emission through unsaturated compacted clay in landfill final cover

    Energy Technology Data Exchange (ETDEWEB)

    Ng, C.W.W.; Chen, Z.K.; Coo, J.L. [Department of Civil and Environmental Engineering, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong); Chen, R., E-mail: chenrui1005@hotmail.com [Shenzhen Key Laboratory of Urban and Civil Engineering for Disaster Prevention and Mitigation, Harbin Institute of Technology Shenzhen Graduate School, Shenzhen 518055 (China); Zhou, C. [Department of Civil and Environmental Engineering, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong)

    2015-10-15

    Highlights: • Explore feasibility of unsaturated clay as a gas barrier in landfill cover. • Gas breakthrough pressure increases with clay thickness and degree of saturation. • Gas emission rate decreases with clay thickness and degree of saturation. • A 0.6 m-thick clay layer may be sufficient to meet gas emission rate limit. - Abstract: Determination of gas transport parameters in compacted clay plays a vital role for evaluating the effectiveness of soil barriers. The gas breakthrough pressure has been widely studied for saturated swelling clay buffer commonly used in high-level radioactive waste disposal facility where the generated gas pressure is very high (in the order of MPa). However, compacted clay in landfill cover is usually unsaturated and the generated landfill gas pressure is normally low (typically less than 10 kPa). Furthermore, effects of clay thickness and degree of saturation on gas breakthrough and emission rate in the context of unsaturated landfill cover has not been quantitatively investigated in previous studies. The feasibility of using unsaturated compacted clay as gas barrier in landfill covers is thus worthwhile to be explored over a wide range of landfill gas pressures under various degrees of saturation and clay thicknesses. In this study, to evaluate the effectiveness of unsaturated compacted clay to minimize gas emission, one-dimensional soil column tests were carried out on unsaturated compacted clay to determine gas breakthrough pressures at ultimate limit state (high pressure range) and gas emission rates at serviceability limit state (low pressure range). Various degrees of saturation and thicknesses of unsaturated clay sample were considered. Moreover, numerical simulations were carried out using a coupled gas–water flow finite element program (CODE-BRIGHT) to better understand the experimental results by extending the clay thickness and varying the degree of saturation to a broader range that is typical at different

  19. Effects of nitrogen loading on greenhouse gas emissions in salt marshes

    Science.gov (United States)

    Tang, J.; Moseman-Valtierra, S.; Kroeger, K. D.; Morkeski, K.; Mora, J.; Chen, X.; Carey, J.

    2014-12-01

    Salt marshes play an important role in global and regional carbon and nitrogen cycling. We tested the hypothesis that anthropogenic nitrogen loading alters greenhouse gas (GHG, including CO2, CH4, and N2O) emissions and carbon sequestration in salt marshes. We measured GHG emissions biweekly for two growing seasons across a nitrogen-loading gradient of four Spartina salt marshes in Waquoit Bay, Massachusetts. In addition, we conducted nitrogen addition experiments in a pristine marsh by adding low and high nitrate to triplicate plots bi-weekly during the summer. The GHG flux measurements were made in situ with a state-of-the-art mobile gas measurement system using the cavity ring down technology that consists of a CO2/CH4 analyzer (Picarro) and an N2O/CO analyzer (Los Gatos). We observed strong seasonal variations in greenhouse gas emissions. The differences in gas emissions across the nitrogen gradient were not significant, but strong pulse emissions of N2O were observed after nitrogen was artificially added to the marsh. Our results will facilitate model development to simulate GHG emissions in coastal wetlands and support methodology development to assess carbon credits in preserving and restoring coastal wetlands.

  20. Combining policy instruments to curb greenhouse gas emissions

    International Nuclear Information System (INIS)

    Bahn, O.

    2001-01-01

    The Kyoto Protocol has set greenhouse gas emission reduction targets for selected countries. To comply with these reduction requirements, decision-makers may use market-based instruments on a national or international basis. This paper advocates the combining of national emission taxes with international trade of emission permits. As a numerical application, this paper analyses macro-economic impacts of such a strategy for Switzerland. (Author)

  1. The effects of Norwegian gas export on the global CO2 emission

    International Nuclear Information System (INIS)

    1996-01-01

    This report analyses how a limitation of Norway's gas export might affect the global CO 2 emission. In principle, a reduction of this export can lead to decreased or increased CO 2 emission depending on changes in several conditions that individually have conflicting emission effects. What the total effect will be can only become clear after a thorough empirical analysis of the supply and demand structure. The model calculations presented in the report show that the global emission will probably increase if Norway reduces the gas export. A gas export reduction of 10 million tonne oil equivalents in 2015 will increase the global emission by 1.4 and 7.5 million tonne CO 2 depending on the assumption made for alternative gas supplies to the European market and for market conditions in the importing countries. 4 refs., 32 figs., 44 tabs

  2. 75 FR 57275 - Information Collection; Supplier Greenhouse Gas Emissions Inventory Pilot

    Science.gov (United States)

    2010-09-20

    ...] Information Collection; Supplier Greenhouse Gas Emissions Inventory Pilot AGENCY: Federal Acquisition Service... Greenhouse Gas (GHG) Emissions Inventory pilot. Public comments are particularly invited on: Whether this... Inventory pilot, and whether it will have practical utility; whether our estimate of the public burden of...

  3. Emission quantification using the tracer gas dispersion method: The influence of instrument, tracer gas species and source simulation

    DEFF Research Database (Denmark)

    Delre, Antonio; Mønster, Jacob; Samuelsson, Jerker

    2018-01-01

    The tracer gas dispersion method (TDM) is a remote sensing method used for quantifying fugitive emissions by relying on the controlled release of a tracer gas at the source, combined with concentration measurements of the tracer and target gas plumes. The TDM was tested at a wastewater treatment...... plant for plant-integrated methane emission quantification, using four analytical instruments simultaneously and four different tracer gases. Measurements performed using a combination of an analytical instrument and a tracer gas, with a high ratio between the tracer gas release rate and instrument...... precision (a high release-precision ratio), resulted in well-defined plumes with a high signal-to-noise ratio and a high methane-to-tracer gas correlation factor. Measured methane emission rates differed by up to 18% from the mean value when measurements were performed using seven different instrument...

  4. State and Territory Greenhouse Gas Emissions. An overview

    International Nuclear Information System (INIS)

    2005-04-01

    This document is a summary of the latest available estimates of greenhouse gas emissions for the States and Territories. They are taken from the national inventory and show emissions for 2002, the latest year for which national statistics on fuel and electricity consumption are available. The report shows that Australia's total greenhouse gas emissions in 2002 amounted to 541.8 million tonnes. The State and Territory breakdown was: New South Wales: 151.5 million tonnes (Mt); Queensland: 145.1 Mt; Victoria: 117.0 Mt; Western Australia: 70.4 Mt; South Australia: 30.9 Mt; Northern Territory: 17.7 Mt; Tasmania: 7.2 Mt; ACT: 1.3 Mt. The State and Territory inventories are the first of what will be an annual series. The national inventory and State and Territory inventories are all prepared according to the international rules and procedures applicable to Australia's Kyoto 108% emissions target. The national inventory undergoes regular independent international review

  5. Greenhouse Gas Emissions in the Netherlands 1990-2011. National Inventory Report 2013

    Energy Technology Data Exchange (ETDEWEB)

    Coenen, P. W.H.G.; Droege, R. [Netherlands Organisation for Applied Scientific Research TNO, P.O. Box 80015, NL-3508 TA Utrecht (Netherlands); Zijlema, P. J. [NL Agency, P.O. Box 8242, NL-3503 RE Utrecht (Netherlands); Arets, E. J.M.M. [Alterra Wageningen UR, P.O. Box 47 NL-6700 AA Wageningen (Netherlands); Baas, K. [Statistics Netherlands CBS, P.O. Box 24500, NL-2490 HA Den Haag (Netherlands); Van den Berghe, A. C.W.M. [Rijkswaterstaat, P.O. Box 8242, NL-3503 RE Utrecht (Netherlands); Brandt, A. T. [Dutch Emissions Authority NEa, P.O. Box 91503, NL-2509 EC Den Haag (Netherlands); Geilenkirchen, G. [PBL Netherlands Environmental Assessment Agency, P.O. Box 303 NL-3720 AH Bilthoven (Netherlands); Van der Maas, C. W.M.; Te Biesebeek, J. D.; Van der Hoek, K. W.; Te Molder, R.; Montfoort, J. A.; Peek, C. J.; Vonk, J. [National Institute of Public Health and Environmental Protection RIVM, Bilthoven (Netherlands)

    2013-04-15

    Total greenhouse gas emissions from The Netherlands in 2011 decreased by approximately 7 per cent compared with 2010 emissions. This decrease is mainly the result of decreased fuel combustion in the Energy sector (less electricity production) and in the petrochemical industry. Fuel use for space heating decreased due to the mild winter compared with the very cold 2010 winter. In 2011, total direct greenhouse gas emissions (excluding emissions from LULUCF (land use, land use change and forestry) in The Netherlands amounted to 194.4 Tg CO2 eq. This is approximately 9 per cent below the emissions in the base year 2 (213.2 Tg CO2 eq). This report documents the Netherlands' 2012 annual submission of its greenhouse gas emissions inventory in accordance with the guidelines provided by the United Nations Framework Convention on Climate Change (UNFCCC), the Kyoto Protocol and the European Union's Greenhouse Gas Monitoring Mechanism. The report comprises explanations of observed trends in emissions; a description of an assessment of key sources and their uncertainty; documentation of methods, data sources and emission factors applied; and a description of the quality assurance system and the verification activities performed on the data.

  6. Greenhouse Gas Emissions in the Netherlands 1990-2011. National Inventory Report 2013

    Energy Technology Data Exchange (ETDEWEB)

    Coenen, P.W.H.G.; Droege, R. [Netherlands Organisation for Applied Scientific Research TNO, P.O. Box 80015, NL-3508 TA Utrecht (Netherlands); Zijlema, P.J. [NL Agency, P.O. Box 8242, NL-3503 RE Utrecht (Netherlands); Arets, E.J.M.M. [Alterra Wageningen UR, P.O. Box 47 NL-6700 AA Wageningen (Netherlands); Baas, K. [Statistics Netherlands CBS, P.O. Box 24500, NL-2490 HA Den Haag (Netherlands); Van den Berghe, A.C.W.M. [Rijkswaterstaat, P.O. Box 8242, NL-3503 RE Utrecht (Netherlands); Brandt, A.T. [Dutch Emissions Authority NEa, P.O. Box 91503, NL-2509 EC Den Haag (Netherlands); Geilenkirchen, G. [PBL Netherlands Environmental Assessment Agency, P.O. Box 303 NL-3720 AH Bilthoven (Netherlands); Van der Maas, C.W.M.; Te Biesebeek, J.D.; Van der Hoek, K.W.; Te Molder, R.; Montfoort, J.A.; Peek, C.J.; Vonk, J. [National Institute of Public Health and Environmental Protection RIVM, Bilthoven (Netherlands)

    2013-04-15

    Total greenhouse gas emissions from The Netherlands in 2011 decreased by approximately 7 per cent compared with 2010 emissions. This decrease is mainly the result of decreased fuel combustion in the Energy sector (less electricity production) and in the petrochemical industry. Fuel use for space heating decreased due to the mild winter compared with the very cold 2010 winter. In 2011, total direct greenhouse gas emissions (excluding emissions from LULUCF (land use, land use change and forestry) in The Netherlands amounted to 194.4 Tg CO2 eq. This is approximately 9 per cent below the emissions in the base year 2 (213.2 Tg CO2 eq). This report documents the Netherlands' 2012 annual submission of its greenhouse gas emissions inventory in accordance with the guidelines provided by the United Nations Framework Convention on Climate Change (UNFCCC), the Kyoto Protocol and the European Union's Greenhouse Gas Monitoring Mechanism. The report comprises explanations of observed trends in emissions; a description of an assessment of key sources and their uncertainty; documentation of methods, data sources and emission factors applied; and a description of the quality assurance system and the verification activities performed on the data.

  7. Localization of fugitive methane emission from natural gas distribution network of Titas Gas

    Directory of Open Access Journals (Sweden)

    Mandal Pradip C.

    2017-03-01

    Full Text Available The aim of this paper is to localize the fugitive leaks from the above ground facilities of the existing system of Titas Gas (TG after developing mathematical model for fugitive emission. Soap screening techniques and Gasurveyor 500 series instrument were used in this study for detecting potential leaks. Leaked gas was quantified using either Hi-Flow gas sampler or bagging measurements system. The results show that the respective potential gas leaking point of City Gate Station (CGS, commercial Regulating and Metering Station (RMS, industrial RMS, residential RMS and Town Bordering Station (TBS/ District Regulating Station (DRS are scrubber dump valve (average leak rate 217.00 L/min, insulating point (average leak rate 4.04 L/min, tube fitting connector (average leak rate 8.00 L/min, connector (average leak rate 1.55 L/min and pressure relief valve (average leak rate 437.92 L/min. Fugitive methane emission can be reduced by stopping leaks of fittings or components having high KLeak value.

  8. METHANE EMISSIONS FROM THE NATURAL GAS INDUSTRY VOLUME 15: GAS-ASSISTED GLYCOL PUMPS

    Science.gov (United States)

    The 15-volume report summarizes the results of a comprehensive program to quantify methane (CH4) emissions from the U.S. natural gas industry for the base year. The objective was to determine CH4 emissions from the wellhead and ending downstream at the customer's meter. The accur...

  9. Laboratory Investigation of Trace Gas Emissions from Biomass Burning on DoD Bases

    Science.gov (United States)

    Burling, I. R.; Yokelson, R. J.; Griffith, D. W.; Roberts, J. M.; Veres, P. R.; Warneke, C.; Johnson, T. J.

    2009-12-01

    Vegetation representing fuels commonly managed with prescribed fires was collected from five DoD bases and burned under controlled conditions at the USFS Firelab in Missoula, MT. The smoke emissions were measured with a large suite of state-of-the-art instrumentation. Seventy-seven fires were conducted and the smoke composition data will improve DoD land managers’ ability to assess the impact of prescribed fires on local air quality. A key instrument used in the measurement of the gas phase species in smoke was an open-path FTIR (OP-FTIR) spectrometer, built and operated by the Universities of Montana and Wollongong. The OP-FTIR has to date detected and quantified 20 gas phase species - CO2, CO, H2O, N2O, NO2, NO, HONO, NH3, HCl, SO2, CH4, CH3OH, HCHO, HCOOH, C2H2, C2H4, CH3COOH, HCN, propylene and furan. The spectra were analyzed using a non-linear least squares fitting routine that included reference spectra recently acquired at the Pacific Northwest National Laboratories. Preliminary results from the OP-FTIR analysis are reported here. Of particular interest, gas-phase nitrous acid (HONO) was detected simultaneously by the OP-FTIR and negative-ion proton-transfer chemical ionization spectrometer (NI-PT-CIMS), with preliminary fire-integrated molar emission ratios (relative to NOx) ranging from approximately 0.03 to 0.20, depending on the vegetation type. HONO is an important precursor in the production of OH, the primary oxidizing species in the atmosphere. There existed little previous data documenting HONO emissions from either wild or prescribed fires. The non-methane organic emissions were dominated by oxygenated species, which can be further oxidized and thus involved in secondary aerosol formation. Elevated amounts of gas-phase HCl were also detected in the smoke, with the amounts varying depending on location and vegetation type.

  10. Improving material management to reduce greenhouse gas emissions

    NARCIS (Netherlands)

    Hekkert, Marko Peter

    2000-01-01

    Climate change due to greenhouse gas emissions caused by human actions is probably one of the major global environmental problems that we face today. In order to reduce the risk of climate change and the potential effects thereof, the emission of greenhouse gases like carbon dioxide (CO2) and

  11. Mobile measurement of methane emissions from natural gas developments in northeastern British Columbia, Canada

    Science.gov (United States)

    Atherton, Emmaline; Risk, David; Fougère, Chelsea; Lavoie, Martin; Marshall, Alex; Werring, John; Williams, James P.; Minions, Christina

    2017-10-01

    North American leaders recently committed to reducing methane emissions from the oil and gas sector, but information on current emissions from upstream oil and gas developments in Canada are lacking. This study examined the occurrence of methane plumes in an area of unconventional natural gas development in northwestern Canada. In August to September 2015 we completed almost 8000 km of vehicle-based survey campaigns on public roads dissecting oil and gas infrastructure, such as well pads and processing facilities. We surveyed six routes 3-6 times each, which brought us past over 1600 unique well pads and facilities managed by more than 50 different operators. To attribute on-road plumes to oil- and gas-related sources we used gas signatures of residual excess concentrations (anomalies above background) less than 500 m downwind from potential oil and gas emission sources. All results represent emissions greater than our minimum detection limit of 0.59 g s-1 at our average detection distance (319 m). Unlike many other oil and gas developments in the US for which methane measurements have been reported recently, the methane concentrations we measured were close to normal atmospheric levels, except inside natural gas plumes. Roughly 47 % of active wells emitted methane-rich plumes above our minimum detection limit. Multiple sites that pre-date the recent unconventional natural gas development were found to be emitting, and we observed that the majority of these older wells were associated with emissions on all survey repeats. We also observed emissions from gas processing facilities that were highly repeatable. Emission patterns in this area were best explained by infrastructure age and type. Extrapolating our results across all oil and gas infrastructure in the Montney area, we estimate that the emission sources we located (emitting at a rate > 0.59 g s-1) contribute more than 111 800 t of methane annually to the atmosphere. This value exceeds reported bottom

  12. Hydrocarbon emissions from gas engine CHP-units. 2011 measurement program

    Energy Technology Data Exchange (ETDEWEB)

    Van Dijk, G.H.J. [KEMA, Arnhem (Netherlands)

    2012-06-15

    In December 2009, the Ministry of Infrastructure and Environment (IandM) issued the Decree on Emission Limits for Middle Sized Combustion Installations (BEMS). This decree imposes a first-time emission limit value (ELV) of 1500 mg C/m{sup 3}{sub o} at 3% O{sub 2} for hydrocarbons emitted by gas engines. IandM used the findings of two hydrocarbon emission measurement programs, executed in 2007 and 2009, as a guideline for this initial ELV. The programs did reveal substantial variation in the hydrocarbon emissions of the gas engines tested. This variation, and especially the uncertainty as to the role of engine and/or other parameters causing such variation, was felt to hamper further policy development. IandM therefore commissioned KEMA to perform follow-up measurements on ten gas engine CHP-units in 2011. Aim of this 2011 program is to assess hydrocarbon emission variation in relation to engine parameters and process conditions including maintenance status, and to atmospheric conditions. The 2011 program comprised two identical measurement sessions, one in spring and one in winter.

  13. Air pollution from industrial waste gas emissions is associated with cancer incidences in Shanghai, China.

    Science.gov (United States)

    Cong, Xiaowei

    2018-05-01

    Outdoor air pollution may be associated with cancer risk at different sites. This study sought to investigate outdoor air pollution from waste gas emission effects on multiple cancer incidences in a retrospective population-based study in Shanghai, China. Trends in cancer incidence for males and females and trends in waste gas emissions for the total waste gas, industrial waste gas, other waste gas, SO 2 , and soot were investigated between 1983 and 2010 in Shanghai, China. Regression models after adjusting for confounding variables were constructed to estimate associations between waste gas emissions and multiple cancer incidences in the whole group and stratified by sex, Engel coefficient, life expectancy, and number of doctors per 10,000 populations to further explore whether changes of waste gas emissions were associated with multiple cancer incidences. More than 550,000 new cancer patients were enrolled and reviewed. Upward trends in multiple cancer incidences for males and females and in waste gas emissions were observed from 1983 to 2010 in Shanghai, China. Waste gas emissions came mainly from industrial waste gas. Waste gas emissions was significantly positively associated with cancer incidence of salivary gland, small intestine, colorectal, anus, gallbladder, thoracic organs, connective and soft tissue, prostate, kidney, bladder, thyroid, non-Hodgkin's lymphoma, lymphatic leukemia, myeloid leukemia, and other unspecified sites (all p emissions and the esophagus cancer incidence was observed (p emissions was associated with multiple cancer incidences.

  14. Coal fired flue gas mercury emission controls

    CERN Document Server

    Wu, Jiang; Pan, Weiguo; Pan, Weiping

    2015-01-01

    Mercury (Hg) is one of the most toxic heavy metals, harmful to both the environment and human health. Hg is released into the atmosphere from natural and anthropogenic sources and its emission control has caused much concern. This book introduces readers to Hg pollution from natural and anthropogenic sources and systematically describes coal-fired flue gas mercury emission control in industry, especially from coal-fired power stations. Mercury emission control theory and experimental research are demonstrated, including how elemental mercury is oxidized into oxidized mercury and the effect of

  15. Emission Characteristics of Gas-Fired Boilers based on Category-Specific Emission Factor from Field Measurements in Beijing, China

    Science.gov (United States)

    Itahashi, S.; Yan, X.; Song, G.; Yan, J.; Xue, Y.

    2017-12-01

    Gas-fired boilers will become the main stationary sources of NOx in Beijing. However, the knowledge of gas-fired boilers in Beijing is limited. In the present study, the emission characteristics of NOx, SO2, and CO from gas-fired boilers in Beijing were established using category-specific emission factors (EFs) from field measurements. In order to obtain category-specific EFs, boilers were classified through influence analysis. Factors such as combustion mode, boiler type, and installed capacity were considered critical for establishing EFs because they play significant roles in pollutant formation. The EFs for NOx, CO, and SO2 ranged from 1.42-6.86 g m-3, 0.05-0.67 g m-3 and 0.03-0.48 g m-3. The emissions of NOx, SO2, and CO for gas-fired boilers in Beijing were 11121 t, 468 t, and 222 t in 2014, respectively. The emissions were spatially allocated into grid cells with a resolution of 1 km × 1 km, and the results indicated that top emitters were in central Beijing. The uncertainties were quantified using a Monte Carlo simulation. The results indicated high uncertainties in CO (-157% to 154%) and SO2 (-127% to 182%) emissions, and relatively low uncertainties (-34% to 34%) in NOx emission. Furthermore, approximately 61.2% and 96.8% of the monitored chamber combustion boilers (CCBs) met the standard limits for NOx and SO2, respectively. Concerning NOx, low-NOx burners and NOx emission control measures are urgently needed for implementing of stricter standards. Adopting terminal control measures is unnecessary for SO2, although its concentration occasionally exceeds standard limits, because reduction of its concentration can be achieved thorough control of the sulfur content of natural gas at a stable low level. Furthermore, the atmospheric combustion boilers (ACBs) should be substituted with CCBs, because ACBs have a higher emission despite lower gross installed capacity. The results of this study will enable in understanding and controlling emissions from gas

  16. Embodied greenhouse gas emission by Macao

    International Nuclear Information System (INIS)

    Li, J.S.; Chen, G.Q.; Lai, T.M.; Ahmad, B.; Chen, Z.M.; Shao, L.; Ji, Xi

    2013-01-01

    Comprehensive inventory of cities' greenhouse gas emissions (GHG) is the basis for cities to make appropriate mitigation plans. However, previous studies on cities' GHG emissions consider emissions occurring within the city boundary (Scope 1) and out of boundary electricity emissions (Scope 2), but neglect indirect emissions associated with commodities consumed by cities (Scope 3), resulting in emission leakage. To cope with this problem, a systematic accounting covering all 3 scopes is presented in a case study of Macao for the years 2005–2009, based on the latest embodied emission intensity databases for China and for the world. The results show that total emissions are dominated by indirect emissions mainly embodied in imports, which is 3–4 times direct emissions during the period concerned. It is verified that accounting under Scopes 1 and 2 cannot capture the full picture of cities' emissions, especially cities like Macao which are dominated by service industry and inevitably sustained by massive materials and services from other regions. Our study suggests that Macao should adjust its current GHG mitigation policies which consider only its emissions occurring within its border, as Macao is a net GHG emissions importer. This work is the first assessment of Macao's embodied GHG emissions. - Highlights: • A systematic accounting procedure is presented to inventory a city's GHG emissions. • A comprehensive review of GHG emissions is performed for Macao. • Indirect GHG emissions dominate Macao's embodied GHG emissions. • Macao induced large amount of GHG emissions in other regions through trade. • The variation in GHG emission structure against socio-economic changes is revealed

  17. Assessing fugitive emissions of CH4 from high-pressure gas pipelines

    Science.gov (United States)

    Worrall, Fred; Boothroyd, Ian; Davies, Richard

    2017-04-01

    The impact of unconventional natural gas production using hydraulic fracturing methods from shale gas basins has been assessed using life-cycle emissions inventories, covering areas such as pre-production, production and transmission processes. The transmission of natural gas from well pad to processing plants and its transport to domestic sites is an important source of fugitive CH4, yet emissions factors and fluxes from transmission processes are often based upon ver out of date measurements. It is important to determine accurate measurements of natural gas losses when compressed and transported between production and processing facilities so as to accurately determine life-cycle CH4 emissions. This study considers CH4 emissions from the UK National Transmission System (NTS) of high pressure natural gas pipelines. Mobile surveys of CH4 emissions using a Picarro Surveyor cavity-ring-down spectrometer were conducted across four areas in the UK, with routes bisecting high pressure pipelines and separate control routes away from the pipelines. A manual survey of soil gas measurements was also conducted along one of the high pressure pipelines using a tunable diode laser. When wind adjusted 92 km of high pressure pipeline and 72 km of control route were drive over a 10 day period. When wind and distance adjusted CH4 fluxes were significantly greater on routes with a pipeline than those without. The smallest leak detectable was 3% above ambient (1.03 relative concentration) with any leaks below 3% above ambient assumed ambient. The number of leaks detected along the pipelines correlate to the estimated length of pipe joints, inferring that there are constant fugitive CH4 emissions from these joints. When scaled up to the UK's National Transmission System pipeline length of 7600 km gives a fugitive CH4 flux of 4700 ± 2864 kt CH4/yr - this fugitive emission from high pressure pipelines is 0.016% of the annual gas supply.

  18. The effect of lactic acid bacteria included as a probiotic or silage inoculant on in vitro rumen digestibility, total gas and methane production

    NARCIS (Netherlands)

    Ellis, J.L.; Bannink, A.; Hindrichsen, I.K.; Kinley, R.D.; Pellikaan, W.F.; Milora, N.L.; Dijkstra, J.

    2016-01-01

    Through alterations in silage and rumen fermentation, lactic acid bacteria (LAB) silage inoculants may affect OM digestibility and methane (CH4) emissions. In order to identify LAB that may have beneficial effects on CH4 emissions and/or OM digestibility in vivo, a series of in vitro gas production

  19. Modeling of municipal greenhouse gas emissions. Calculation of greenhouse gas emissions and the reduction possibilities of Dutch municipalities

    NARCIS (Netherlands)

    Vries de, Willem

    2011-01-01

    Summary Municipalities represent an active governmental layer in the Netherlands. They often have ambitions to reduce greenhouse gas emissions. In this way the municipalities take responsibility to reduce the threat of global warming. To implement effect

  20. Incorporating greenhouse gas (GHG) emissions in long range transportation planning.

    Science.gov (United States)

    2014-05-01

    Greenhouse gas (GHG) emissions continue to be an important focus area for state, local, and federal : agencies. The transportation sector is the second biggest contributor to GHG emissions in the U.S., and : Texas contributes the highest emissions am...

  1. Optimal greenhouse gas emissions in NGCC plants integrating life cycle assessment

    International Nuclear Information System (INIS)

    Bernier, Etienne; Maréchal, François; Samson, Réjean

    2012-01-01

    The optimal design of an energy-intensive process involves a compromise between costs and greenhouse gas emissions, complicated by the interaction between optimal process emissions and supply chain emissions. We propose a method that combines generic abatement cost estimates and the results of existing (LCA) life cycle assessment studies, so that supply chain emissions are properly handled during optimization. This method is illustrated for a (NGCC) natural gas combined cycle power plant model with the following design and procurement options: procurement of natural gas from low-emissions producers, fuel substitution with (SNG) synthetic natural gas from wood, and variable-rate CO 2 capture and sequestration from both the NGCC and SNG plants. Using multi-objective optimization, we show two Pareto-optimal sets with and without the proposed LCA method. The latter can then be shown to misestimate CO 2 abatement costs by a few percent, penalizing alternate fuels and energy-efficient process configurations and leading to sub-optimal design decisions with potential net losses of the order of $1/MWh. Thus, the proposed LCA method can enhance the economic analysis of emissions abatement technologies and emissions legislation in general. -- Highlights: ► Multi-objective optimization and LCA used for process design considering supply chain. ► Off-site emissions in LCA reveal potential future indirect taxes for energy consumers. ► Generic abatement cost curves provide a mitigation model for off-site emissions. ► Off-site mitigation precedes CO 2 capture or biogas substitution in NGCC plant. ► Profitability estimation of capture or substitution depends on off-site mitigation.

  2. Greenhouse gas emissions from the production and use of alternative transport fuels

    International Nuclear Information System (INIS)

    Le Cornu, J.K.

    1990-01-01

    A number of the commonly proposed alternative transport fuels were ranked according to both the cumulative greenhouse gas emissions and the production costs incurred between the recovery of the prime resource and the fuel's end use by the Australian transport fleet. An examination of the emissions of each greenhouse gas at each production stage confirmed the common presumption that the low levels of secondary greenhouse gas emissions involved contribute little to the overall greenhouse impact of a fuel's production and use. From a greenhouse point of view the transport fuels studied could be reasonable well ranked by considering their carbon dioxide emissions alone. A possible exception may apply in the case of the compressed natural gas option, which may need to separate consideration of the effect of fugitive emissions of methane from gas distribution systems. An assumption involved in reaching this result was that nitrous oxide emissions, on which there was inadequate hard data, would not form more than 1% of the total nitrogen oxide emissions. At such an emission level it could contribute up to 5% of a fuel's total greenhouse impact. It is concluded that apart from some small niche opportunities, there is no Australian alternative transport fuel option whose production cost and greenhouse impact makes it one which policy should favour over other fuels. It is stressed that this is no more than a preliminary scouting study of generic options, which addresses only greenhouse issues. 17 refs., 1 tab., 8 figs

  3. How to globally reduce the greenhouse gas emissions from sewage systems?

    International Nuclear Information System (INIS)

    Batz, S. de; Bonardet, P.; Trouve, J.P.

    2007-01-01

    A reliable and exhaustive measurement of the global greenhouse gas emissions from a given sewage plant must be performed prior to the implementation of any abatement measure. The method presented in this paper takes into consideration both the direct emissions but also the indirect ones generated by the plant activity and identified using a life cycle-type approach. Three examples of projects or realizations are presented in this paper to illustrate the different means of abatement of greenhouse gas emissions from a sewage plant in a global way. The first example concerns a project of abatement of the electricity consumption of a plant for sludges and fats digestion and biogas valorization. A 85% global abatement of CO 2 emissions is obtained thanks to the substitution of the aerobic digestion process by an anaerobic one. The second example presents an optimization of the greenhouse gas emissions of the municipal sewage plant of Valenton (Paris region) thanks to a valorization of sludges as fertilizers and fuels and to the recovery of the process heat. The last example concerns the Seine-aval sewage plant which gathers several projects of improvement: setting up of a second biogas turbine, redesign of the heat loop, use of river transport for a significant abatement of greenhouse gas emissions. (J.S.)

  4. Cradle to grave GHG emissions analysis of shale gas hydraulic fracking in Western Australia

    Directory of Open Access Journals (Sweden)

    Bista Sangita

    2017-01-01

    Full Text Available Western Australia has globally significant onshore gas resources, with over 280 trillion cubic feet of economically recoverable gas located in five shale basins. The Western Australian Government and gas industry have promoted the development of these resources as a “clean energy source” that would “help to reduce global carbon emissions” and provide a “transition fuel” to a low carbon economy. This research examines those claims by reviewing existing literature and published data to estimate the life cycle greenhouse gas (GHG pollution that would result from the development of Western Australia’s onshore gas basins using hydraulic fracking. Estimates of carbon pollution from each stage in gas development, processing, transport and end-use are considered in order to establish total life-cycle emissions in tonnes of carbon-dioxide equivalent (CO2e. The emissions estimates draw from published research on emissions from shale gas development in other jurisdictions as well as industry or government reported emissions from current technology for gas processing and end-use as applicable. The current policy and regulatory environment for carbon pollution and likely resulting GHG mitigation measures has also been considered, as well as the potential for the gas to displace or substitute for other energy sources. In areas where there is uncertainty, conservative emissions estimates have been used. Modelling of GHG emissions has been undertaken for two comparison resource development and utilisation scenarios; Australian domestic and 100% export i.e. no domestic use. Each scenario corresponds to a different proportionate allocation of emissions accounted for domestic emissions in Australia and emissions accounted for in other jurisdictions. Emissions estimates for the two scenarios are 245–502 MTCO2e/year respectively over a resource development timeframe of 20 years. This is roughly the same as Australia’s total GHG emissions in 2014

  5. Methane Emissions from the Natural Gas Transmission and Storage System in the United States.

    Science.gov (United States)

    Zimmerle, Daniel J; Williams, Laurie L; Vaughn, Timothy L; Quinn, Casey; Subramanian, R; Duggan, Gerald P; Willson, Bryan; Opsomer, Jean D; Marchese, Anthony J; Martinez, David M; Robinson, Allen L

    2015-08-04

    The recent growth in production and utilization of natural gas offers potential climate benefits, but those benefits depend on lifecycle emissions of methane, the primary component of natural gas and a potent greenhouse gas. This study estimates methane emissions from the transmission and storage (T&S) sector of the United States natural gas industry using new data collected during 2012, including 2,292 onsite measurements, additional emissions data from 677 facilities and activity data from 922 facilities. The largest emission sources were fugitive emissions from certain compressor-related equipment and "super-emitter" facilities. We estimate total methane emissions from the T&S sector at 1,503 [1,220 to 1,950] Gg/yr (95% confidence interval) compared to the 2012 Environmental Protection Agency's Greenhouse Gas Inventory (GHGI) estimate of 2,071 [1,680 to 2,690] Gg/yr. While the overlap in confidence intervals indicates that the difference is not statistically significant, this is the result of several significant, but offsetting, factors. Factors which reduce the study estimate include a lower estimated facility count, a shift away from engines toward lower-emitting turbine and electric compressor drivers, and reductions in the usage of gas-driven pneumatic devices. Factors that increase the study estimate relative to the GHGI include updated emission rates in certain emission categories and explicit treatment of skewed emissions at both component and facility levels. For T&S stations that are required to report to the EPA's Greenhouse Gas Reporting Program (GHGRP), this study estimates total emissions to be 260% [215% to 330%] of the reportable emissions for these stations, primarily due to the inclusion of emission sources that are not reported under the GHGRP rules, updated emission factors, and super-emitter emissions.

  6. Greenhouse gas emissions trading: Cogen case studies in the early trading market

    International Nuclear Information System (INIS)

    Buerer, Mary Jean

    2001-01-01

    An increasing number of companies are interested in opportunities to trade their reduction in greenhouse gas emissions from cogeneration on the emerging greenhouse gas emissions market. Only the UK and Denmark currently have emissions trading schemes, but they are under development in other European countries. Two frameworks currently exist for trading. Baseline-and-credit trading is used in Canada where companies can take part in two voluntary schemes (Greenhouse Gas Emission Reduction Trading Pilot or Clean Air Canada Inc). An example project from the CHP unit at DuPont's Maitland chemical production facility is given, with details of the baselines and calculations used. The other option is company-wide emissions trading. The example given here features the CHP units at BP's refinery and chemicals operations in Texas. The potential revenue from emission reduction projects could help to boost the economics of cogeneration projects

  7. Greenhouse gas emissions of pilot buildings in 2009-2011; Pilottikiinteistoejen kasvihuonekaasupaeaestoet vuosina 2009-2011

    Energy Technology Data Exchange (ETDEWEB)

    Riihimaki, M.

    2012-07-01

    The Julia 2030 use of premises project sought to reduce the greenhouse gas emissions of selected pilot buildings by 10 per cent over the period from 2009 to 2011 by changing patterns of use. The project also provided an opportunity for further refinement of a climate calculator developed and maintained by WWF for reckoning greenhouse gas emissions of this kind. The use of premises project covered a total of 32 pilot buildings in Helsinki, Espoo, Vantaa, Kauniainen, Kirkkonummi and Kerava. These buildings included nurseries and schools, swimming baths, offices, multi-purpose activity buildings, depots, a sports hall and a health centre. The combined greenhouse gas emissions of the pilot buildings in 2011 amounted to 10,416 tCO{sub 2}e, which was 8 per cent lower than the total of 11,293 tCO{sub 2}e recorded in 2009. This means that the project fell slightly short of its targeted 10 per cent reduction in greenhouse gas emissions. The total greenhouse gas emissions of the pilot buildings adjusted for heating requirement amounted to 10,733 tCO{sub 2}e in 2011, which was about 7 per cent lower than in 2009. Reckoned on a per capita basis for employees or visitors, the total greenhouse gas emissions adjusted for heating requirement fell in 25 buildings, but increased in seven buildings over the period from 2009 to 2011. Particularly significant emission reductions were achieved in Vantaa, where all buildings were able to cut their emissions by between 9 and 45 per cent. The principal cause of greenhouse gas emissions in the pilot buildings was heating consumption, which also accounts for the increase in their unadjusted greenhouse gas emissions over the cold winters of 2009 and 2010. The second most important emission source in the pilot buildings was electricity consumption. Air travel contributed significantly to the overall greenhouse gas emissions of the pilot buildings used by employees taking work-related flights, whereas the contribution of paper consumption and

  8. Are greenhouse gas emissions from international shipping a type of marine pollution?

    Science.gov (United States)

    Shi, Yubing

    2016-12-15

    Whether greenhouse gas emissions from international shipping are a type of marine pollution is a controversial issue and is currently open to debate. This article examines the current treaty definitions of marine pollution, and applies them to greenhouse gas emissions from ships. Based on the legal analysis of treaty definitions and relevant international and national regulation on this issue, this article asserts that greenhouse gas emissions from international shipping are a type of 'conditional' marine pollution. Copyright © 2016 Elsevier Ltd. All rights reserved.

  9. Study of gas emission from the internal chambers of cryogenic equipment

    International Nuclear Information System (INIS)

    Matyash, Y.I.; Fel'dman, R.G.; Ivakhnenko, Z.N.; Myasnikov, V.M.

    1986-01-01

    One of the methods of improving the efficiency of cryogenic gas equipment (CGE) is adsorption purification of the working medium. The type and quantity of adsorben can be decided after knowing the qualitative and quantitative nature of gas emissions. Gas emissions were studied by the chromatographic method using a heat-conduction detectory. This method made it possible to determine simultaneously the impurities which differ significantly in terms of physicochemical properties. It was established that carbon dioxide and hydrocarbons are continuously emitted in the gaseous medium of the CGE at a constant rate. For the type of machine which was studied, the rates of gas emission were as follows: carbon dioxide and ethane - 0.2 mg/h; ethylene and methane - 0.1 mg/h; propylene, N-butane, and isobutane - 0.2 mg/h

  10. Acid Gas to Syngas (AG2S™) technology applied to solid fuel gasification: Cutting H_2S and CO_2 emissions by improving syngas production

    International Nuclear Information System (INIS)

    Bassani, Andrea; Pirola, Carlo; Maggio, Enrico; Pettinau, Alberto; Frau, Caterina; Bozzano, Giulia; Pierucci, Sauro; Ranzi, Eliseo; Manenti, Flavio

    2016-01-01

    Highlights: • Coal gasification with improved yield and reduced emissions. • AG2S™ process converts H_2S and CO_2 into syngas, elemental sulfur and water. • Techno-economic simulation of AG2S™ process is carried out. • Industrial case-study on the Sotacarbo S.p.A. gasification pilot plant is proposed. - Abstract: The paper deals with the application of the novel Acid Gas To Syngas (AG2S™) technology to the gasification of solid fuels. The AG2S technology is a completely new effective route of processing acid gases: H_2S and CO_2 are converted into syngas (CO and H_2) by means of a regenerative thermal reactor. To show the application of the AG2S technology, modeling and simulation advances for gasification systems are initially discussed. The multi-scale, multi-phase, and multi-component coal gasification system is described by means of detailed kinetic mechanisms for coal pyrolysis, char heterogeneous reactions and for successive gas-phase reactions. These kinetic mechanisms are then coupled with transport resistances resulting in first-principles dynamic modeling of non-ideal reactors of different types (e.g., downdraft, updraft, traveling grate), also including the catalytic effect of ashes. The generalized approach pursued in developing the model allows characterizing the main phenomena involved in the coal gasification process, including the formation of secondary species (e.g., COS, CS_2). This tool is here further validated on literature data and, then, adopted to demonstrate the AG2S effectiveness, where H_2S and CO_2 emissions are reduced with an increase of syngas production. The resulting process solution is more economically appealing with respect to the traditional Claus process and finds several application areas.

  11. A national inventory of greenhouse gas (GHG), criteria air contaminants (CAC) and hydrogen sulphide (H2S) emissions by the upstream oil and gas industry : volume 1, overview of the GHG emissions inventory : technical report

    International Nuclear Information System (INIS)

    2004-09-01

    A detailed inventory of greenhouse gas (GHG) emissions from the upstream oil and gas sector in Canada was presented along with explanations of the methodologies and data sources used. This report is based on previous work done on methane and volatile organic compound emissions from the upstream oil and gas sector for the period of 1990 to 1995, but it includes key improvements in identifying primary types of emissions sources such as emissions from fuel combustion, flaring, venting, fugitive equipment leaks and accidental releases. It also includes criteria air contaminants and hydrogen sulfide emissions, an analysis of GHG emission intensities and a change in the definition of volatile organic compounds from comprising all non-methane hydrocarbons to comprising all non-methane and non-ethane hydrocarbons. The report covers portions of the upstream oil and gas industry in Canada plus the natural gas transmission and natural gas distribution industries with reference to well drilling, oil production, and natural gas production, processing, transmission and distribution. Accidents and equipment failures are also included. The report reveals the total GHG emissions by source type, sub-sector, facility type and sub-type for the year 2000 at the national level. In 2000, the total carbon dioxide equivalent GHG emissions from the entire oil and gas sector were 101,211 kilo tonnes. For the upstream oil and gas sector alone, total GHG emissions were 84,355 kilo tonnes, representing 12 per cent of Canada's total national emissions of GHGs in 2000. This is an increase of about 25 per cent from 1995 levels. The biggest primary source of these emissions is fuel combustion, which accounts for 40.8 per cent of the total. This report also includes a provincial breakdown of GHG emissions for the natural gas transmission, storage and distribution sub-sectors in Canada for the year 2000. refs., tabs., figs

  12. REDUCING GREENHOUSE GAS EMISSIONS AND THE INFLUENCES ON ECONOMIC DEVELOPMENT

    Directory of Open Access Journals (Sweden)

    ANGHELUȚĂ PETRICĂ SORIN

    2016-06-01

    Full Text Available In the recent years, there has been observed a degradation of the environment. This has negative effects on human activities. Besides the influence of the environment on people, also the economic crisis had a negative contribution. The imbalances manifested in the environment influence the economic systems. This article presents an analysis of the greenhouse gas emissions. Also, there is a link between the greenhouse gas emissions and the economic development. In the situation in which the environmental pollution is increasingly affecting humanity, the transition to an economy with reduced greenhouse gas emissions appears to be a viable solution. This transition provides a number of opportunities, as well. Therefore, one of these opportunities is the one related to the employment. In this regard, retraining people working in polluting industries is very important

  13. Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 2: SOx/Nox/Hg Removal for High Sulfur Coal

    Energy Technology Data Exchange (ETDEWEB)

    Nick Degenstein; Minish Shah; Doughlas Louie

    2012-05-01

    The goal of this project is to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxy-combustion technology. The objective of Task 2 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning high sulfur coal in oxy-combustion power plants. The goal of the program was not only to investigate a new method of flue gas purification but also to produce useful acid byproduct streams as an alternative to using a traditional FGD and SCR for flue gas processing. During the project two main constraints were identified that limit the ability of the process to achieve project goals. 1) Due to boiler island corrosion issues >60% of the sulfur must be removed in the boiler island with the use of an FGD. 2) A suitable method could not be found to remove NOx from the concentrated sulfuric acid product, which limits sale-ability of the acid, as well as the NOx removal efficiency of the process. Given the complexity and safety issues inherent in the cycle it is concluded that the acid product would not be directly saleable and, in this case, other flue gas purification schemes are better suited for SOx/NOx/Hg control when burning high sulfur coal, e.g. this project's Task 3 process or a traditional FGD and SCR.

  14. Spectrum analysis of national greenhouse gas emission: a case study of Germany

    International Nuclear Information System (INIS)

    Su, Meirong; Pauleit, Stephan; Xu, Chao

    2016-01-01

    It is essential to abstract the key information from accounting results of greenhouse gas (GHG) emissions because it can provide a highly generalized and clear picture of GHG emissions, which is especially helpful for the public and policy makers. To clearly display the composition of GHG emissions, the concept of spectrum analysis is introduced and defined in this paper. Next, a multilayer analysis framework for national GHG emissions was proposed, which is represented by a pyramid of three layers: total emissions (first layer), emissions decomposed by gas type or sector (second layer), and emissions decomposed by both gas type and sector (third layer). Based on the analysis results from the first to third layers, the main compositional information of national GHG emissions was gradually summarized and analyzed until a spectrum of GHG emissions was acquired. The spectrum of GHG emissions displays the compositional structure of national GHG emissions in the different layers, which is helpful in identifying priorities for emissions reduction. A case study of Germany's GHG emissions during 1990-2012 was conducted, which indicated that CO_2 and the energy sector were the biggest contributors to the total GHG emissions. Some suggestions for reducing GHG emissions are offered based on the obtained results. And the potential development of spectrum analysis for GHG emissions is also expected from aspects of both research and technology. (orig.)

  15. Spectrum analysis of national greenhouse gas emission: a case study of Germany

    Energy Technology Data Exchange (ETDEWEB)

    Su, Meirong [Dongguan University of Technology, School of Chemistry and Environmental Engineering, Dongguan, Guangdong Province (China); Beijing Normal University, State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Beijing (China); Technical University of Munich, Strategic Landscape Planning and Management, Freising (Germany); Pauleit, Stephan; Xu, Chao [Technical University of Munich, Strategic Landscape Planning and Management, Freising (Germany)

    2016-10-15

    It is essential to abstract the key information from accounting results of greenhouse gas (GHG) emissions because it can provide a highly generalized and clear picture of GHG emissions, which is especially helpful for the public and policy makers. To clearly display the composition of GHG emissions, the concept of spectrum analysis is introduced and defined in this paper. Next, a multilayer analysis framework for national GHG emissions was proposed, which is represented by a pyramid of three layers: total emissions (first layer), emissions decomposed by gas type or sector (second layer), and emissions decomposed by both gas type and sector (third layer). Based on the analysis results from the first to third layers, the main compositional information of national GHG emissions was gradually summarized and analyzed until a spectrum of GHG emissions was acquired. The spectrum of GHG emissions displays the compositional structure of national GHG emissions in the different layers, which is helpful in identifying priorities for emissions reduction. A case study of Germany's GHG emissions during 1990-2012 was conducted, which indicated that CO{sub 2} and the energy sector were the biggest contributors to the total GHG emissions. Some suggestions for reducing GHG emissions are offered based on the obtained results. And the potential development of spectrum analysis for GHG emissions is also expected from aspects of both research and technology. (orig.)

  16. Greenhouse gas emissions, energy consumption and economic growth: A panel cointegration analysis from Canadian industrial sector perspective

    International Nuclear Information System (INIS)

    Hamit-Haggar, Mahamat

    2012-01-01

    This paper investigates the long-run and the causal relationship between greenhouse gas emissions, energy consumption and economic growth for Canadian industrial sectors over the period 1990–2007. The empirical findings suggest that in the long-run equilibrium, energy consumption has a positive and statistically significant impact on greenhouse gas emissions whereas a non-linear relationship is found between greenhouse gas emissions and economic growth, consistent with the environmental Kuznets curve. The short-run dynamics conveys that there is a unidirectional Granger causality running from energy consumption to greenhouse gas emissions; from economic growth to greenhouse gas emissions and a weak unidirectional causality running from greenhouse gas emissions to energy consumption; from economic growth to energy consumption. In the long-run however, there seems to be a weak one way causality flowing from energy consumption and economic growth to greenhouse gas emissions. - Highlights: ► A long-run and a causal relationship between greenhouse gas emissions, energy consumption and economic growth is investigated. ► Energy consumption has a positive impact on greenhouse gas emissions in the long run. ► Unidirectional causality runs from energy consumption and economic growth to greenhouse gas emissions. ► A weak unidirectional causality runs from greenhouse gas emissions and economic growth to energy consumption.

  17. ICT and greenhouse gas emissions; IKT og klimagassutslipp

    Energy Technology Data Exchange (ETDEWEB)

    2009-08-15

    ICT can go from being a part of the climate challenge to be an important part of the solution by simplify, rationalize and replace a variety of features and services. ICT's contribute through production and operation for approx. 2.5 % of global greenhouse gas emissions. At the same time estimates show that ICT could help to reduce total greenhouse gas emissions by up to 15 % by 2020 through a series of measures. ICT can, for example. contribute to reduce travel activity through remote collaboration, the transition from material to virtual products and by greater energy efficiency in buildings and vehicles. Through remote collaboration, green tender rounds and change of focus from products to services, can authorities reduce their own emissions. In addition, the authorities go ahead as good examples by illustrating how environment benefits from governmental ICT investments. If we assume that video conferencing can replace 1 of 5 flights among the 140 000 state employees, this can lead to a reducted emission of 14 600 tonnes of CO{sub 2} per year. (AG)

  18. Geostatistical modeling of the gas emission zone and its in-place gas content for Pittsburgh-seam mines using sequential Gaussian simulation

    Science.gov (United States)

    Karacan, C.O.; Olea, R.A.; Goodman, G.

    2012-01-01

    Determination of the size of the gas emission zone, the locations of gas sources within, and especially the amount of gas retained in those zones is one of the most important steps for designing a successful methane control strategy and an efficient ventilation system in longwall coal mining. The formation of the gas emission zone and the potential amount of gas-in-place (GIP) that might be available for migration into a mine are factors of local geology and rock properties that usually show spatial variability in continuity and may also show geometric anisotropy. Geostatistical methods are used here for modeling and prediction of gas amounts and for assessing their associated uncertainty in gas emission zones of longwall mines for methane control.This study used core data obtained from 276 vertical exploration boreholes drilled from the surface to the bottom of the Pittsburgh coal seam in a mining district in the Northern Appalachian basin. After identifying important coal and non-coal layers for the gas emission zone, univariate statistical and semivariogram analyses were conducted for data from different formations to define the distribution and continuity of various attributes. Sequential simulations performed stochastic assessment of these attributes, such as gas content, strata thickness, and strata displacement. These analyses were followed by calculations of gas-in-place and their uncertainties in the Pittsburgh seam caved zone and fractured zone of longwall mines in this mining district. Grid blanking was used to isolate the volume over the actual panels from the entire modeled district and to calculate gas amounts that were directly related to the emissions in longwall mines.Results indicated that gas-in-place in the Pittsburgh seam, in the caved zone and in the fractured zone, as well as displacements in major rock units, showed spatial correlations that could be modeled and estimated using geostatistical methods. This study showed that GIP volumes may

  19. Thermodynamic modelling of acid gas removal from natural gas using the Extended UNIQUAC model

    DEFF Research Database (Denmark)

    Sadegh, Negar; Stenby, Erling Halfdan; Thomsen, Kaj

    2017-01-01

    Thermodynamics of natural gas sweetening process needs to be known for proper design of natural gas treating plants. Absorption with aqueous N-Methyldiethanolamine is currently the most commonly used process for removal of acid gas (CO2 and H2S) impurities from natural gas. Model parameters...... for the Extended UNIQUAC model have already been determined by the same authors to calculate single acid gas solubility in aqueous MDEA. In this study, the model is further extended to estimate solubility of CO2 and H2S and their mixture in aqueous MDEA at high pressures with methane as a makeup gas....

  20. Methane emission from naturally ventilated livestock buildings can be determined from gas concentration measurements

    DEFF Research Database (Denmark)

    Bjerg, B; Zhang, Guoqiang; Madsen, J

    2012-01-01

    Determination of emission of contaminant gases as ammonia, methane, or laughing gas from natural ventilated livestock buildings with large opening is a challenge due to the large variations in gas concentration and air velocity in the openings. The close relation between calculated animal heat pr...... to investigate the influence of feed composition on methane emission in a relative large number of operating cattle buildings and consequently it can support a development towards reduced greenhouse gas emission from cattle production.......Determination of emission of contaminant gases as ammonia, methane, or laughing gas from natural ventilated livestock buildings with large opening is a challenge due to the large variations in gas concentration and air velocity in the openings. The close relation between calculated animal heat...... ventilated, 150 milking cow building. The results showed that the methane emission can be determined with much higher precision than ammonia or laughing gas emissions, and, for methane, relatively precise estimations can be based on measure periods as short as 3 h. This result makes it feasible...

  1. The importance of addressing methane emissions as part of a comprehensive greenhouse gas management strategy

    Energy Technology Data Exchange (ETDEWEB)

    Bylin, Carey [U.S. Environmental Protection Agency (EPA), Washington, DC (United States); Robinson, Donald; Cacho, Mariella; Russo, Ignacio; Stricklin, Eric [ICF International, Fairfax, VA (United States); Rortveit, Geir Johan [Statoil, Stavanger (Norway); Chakraborty, A.B. [Oil and Natural Gas Corporation Ltda. (ONGC), Dehradun (India); Pontiff, Mike [Newfield, The Woodlands, TX, (United States); Smith, Reid [British Petroleum (BP), London (United Kingdom)

    2012-07-01

    Given the climate forcing properties of greenhouse gases (GHGs) and the current state of the global economy, it is imperative to mitigate emissions of GHGs cost-effectively. Typically, CO{sub 2} is the main focus of most companies' and governments' GHG emissions reductions strategies. However, when considering near-term goals, it becomes clear that emissions reductions of other GHGs must be pursued. One such GHG is methane, the primary component of natural gas. Reducing GHG emissions and generating profits are not necessarily a mutually exclusive endeavor as illustrated by the United States Environmental Protection Agency's (EPA) Natural Gas STAR Program. The Program is a worldwide voluntary, flexible partnership of oil and gas companies which promotes cost-effective technologies and practices to reduce methane emissions from oil and natural gas operations. In an effort to meet environmental goals without sacrificing profitability, Natural Gas STAR partner companies have identified over 60 cost-effective best practices to reduce their methane emissions, which they report to the EPA. This paper discusses: 1) the importance of reducing methane emissions and its economic impact, 2) a comparison of methane emission reduction projects relative to other greenhouse gas reduction projects in the oil and gas industry, 3) the value of source-specific methane emissions inventories, and 4) methane emission reduction opportunities from hydraulically fractured gas well completions and centrifugal compressor wet seals. From the analyses and examples in this paper, it can be concluded that methane emission reduction projects can be readily identified, profitable, and effective in mitigating global climate change. (author)

  2. Monitoring gas and heat emissions at Norris Geyser Basin, Yellowstone National Park, USA based on a combined eddy covariance and Multi-GAS approach

    Science.gov (United States)

    Lewicki, J. L.; Kelly, P. J.; Bergfeld, D.; Vaughan, R. G.; Lowenstern, J. B.

    2017-11-01

    We quantified gas and heat emissions in an acid-sulfate, vapor-dominated area (0.04-km2) of Norris Geyser Basin, located just north of the 0.63 Ma Yellowstone Caldera and near an area of anomalous uplift. From 14 May to 3 October 2016, an eddy covariance system measured half-hourly CO2, H2O and sensible (H) and latent (LE) heat fluxes and a Multi-GAS instrument measured (1 Hz frequency) atmospheric H2O, CO2 and H2S volumetric mixing ratios. We also measured soil CO2 fluxes using the accumulation chamber method and temperature profiles on a grid and collected fumarole gas samples for geochemical analysis. Eddy covariance CO2 fluxes ranged from - 56 to 885 g m- 2 d- 1. Using wavelet analysis, average daily eddy covariance CO2 fluxes were locally correlated with average daily environmental parameters on several-day to monthly time scales. Estimates of CO2 emission rate from the study area ranged from 8.6 t d- 1 based on eddy covariance measurements to 9.8 t d- 1 based on accumulation chamber measurements. Eddy covariance water vapor fluxes ranged from 1178 to 24,600 g m- 2 d- 1. Nighttime H and LE were considered representative of hydrothermal heat fluxes and ranged from 4 to 183 and 38 to 504 W m- 2, respectively. The total hydrothermal heat emission rate (H + LE + radiant) estimated for the study area was 11.6 MW and LE contributed 69% of the output. The mean ± standard deviation of H2O, CO2 and H2S mixing ratios measured by the Multi-GAS system were 9.3 ± 3.1 parts per thousand, 467 ± 61 ppmv, and 0.5 ± 0.6 ppmv, respectively, and variations in the gas compositions were strongly correlated with diurnal variations in environmental parameters (wind speed and direction, atmospheric temperature). After removing ambient H2O and CO2, the observed variations in the Multi-GAS data could be explained by the mixing of relatively H2O-CO2-H2S-rich fumarole gases with CO2-rich and H2O-H2S-poor soil gases. The fumarole H2O/CO2 and CO2/H2S end member ratios (101.7 and 27

  3. Monitoring gas and heat emissions at Norris Geyser Basin, Yellowstone National Park, USA based on a combined eddy covariance and Multi-GAS approach

    Science.gov (United States)

    Lewicki, Jennifer L.; Kelly, Peter; Bergfeld, Deborah; Vaughan, R. Greg; Lowenstern, Jacob B.

    2017-01-01

    We quantified gas and heat emissions in an acid-sulfate, vapor-dominated area (0.04-km2) of Norris Geyser Basin, located just north of the 0.63 Ma Yellowstone Caldera and near an area of anomalous uplift. From 14 May to 3 October 2016, an eddy covariance system measured half-hourly CO2, H2O and sensible (H) and latent (LE) heat fluxes and a Multi-GAS instrument measured (1 Hz frequency) atmospheric H2O, CO2 and H2S volumetric mixing ratios. We also measured soil CO2 fluxes using the accumulation chamber method and temperature profiles on a grid and collected fumarole gas samples for geochemical analysis. Eddy covariance CO2 fluxes ranged from − 56 to 885 g m− 2 d− 1. Using wavelet analysis, average daily eddy covariance CO2 fluxes were locally correlated with average daily environmental parameters on several-day to monthly time scales. Estimates of CO2emission rate from the study area ranged from 8.6 t d− 1 based on eddy covariance measurements to 9.8 t d− 1 based on accumulation chamber measurements. Eddy covariance water vapor fluxes ranged from 1178 to 24,600 g m− 2 d− 1. Nighttime H and LEwere considered representative of hydrothermal heat fluxes and ranged from 4 to 183 and 38 to 504 W m− 2, respectively. The total hydrothermal heat emission rate (H + LE + radiant) estimated for the study area was 11.6 MW and LE contributed 69% of the output. The mean ± standard deviation of H2O, CO2 and H2S mixing ratios measured by the Multi-GAS system were 9.3 ± 3.1 parts per thousand, 467 ± 61 ppmv, and 0.5 ± 0.6 ppmv, respectively, and variations in the gas compositions were strongly correlated with diurnal variations in environmental parameters (wind speed and direction, atmospheric temperature). After removing ambient H2O and CO2, the observed variations in the Multi-GAS data could be explained by the mixing of relatively H2O-CO2-H2S-rich fumarole gases with CO2-rich and H2O-H2S-poor soil gases. The

  4. Characteristics of dioxin emissions from a Waelz plant with acid and basic kiln mode.

    Science.gov (United States)

    Hung, Pao Chen; Chi, Kai Hsien; Chen, Mei Lien; Chang, Moo Been

    2012-01-30

    The concentrations of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) were measured in the flue gas of a Waelz plant operated in acid and basic modes, respectively. To abate (PCDD/F) and other pollutants, the plant operates with a post-treatment of flue gases by activated carbon injection and subsequent filtration. Relatively high PCDD/F discharge by fly ashes is found with acid kiln mode of the Waelz process. Therefore, basic kiln mode of the Waelz process is investigated and compared in this plant. With the adsorbent injection rate of 7 kg/h (95 mg/Nm(3)), the PCDD/F concentration in stack gas was measured as 0.123 ng I-TEQ/Nm(3) in the basic operating mode. The added Ca(OH)(2) reacted with metal catalysts and HCl((g)) in the flue gas and thus effectively suppressed the formation of PCDD/Fs. PCDD/F concentrations in fly ashes sampled from the dust settling chamber, cyclone, primary filter and secondary filter in basic kiln mode were significantly lower than that in acid kiln mode. Total PCDD/F emission on the basis of treating one kg of electric arc furnace dust in the basic operation mode was 269 ng I-TEQ/kg EAF-dust treated which was significantly lower than that in acid mode (640 ng I-TEQ/kg EAF-dust treated). Copyright © 2011 Elsevier B.V. All rights reserved.

  5. Fundamental thermochemical properties of amino acids: gas-phase and aqueous acidities and gas-phase heats of formation.

    Science.gov (United States)

    Stover, Michele L; Jackson, Virgil E; Matus, Myrna H; Adams, Margaret A; Cassady, Carolyn J; Dixon, David A

    2012-03-08

    The gas-phase acidities of the 20 L-amino acids have been predicted at the composite G3(MP2) level. A broad range of structures of the neutral and anion were studied to determine the lowest energy conformer. Excellent agreement is found with the available experimental gas-phase deprotonation enthalpies, and the calculated values are within experimental error. We predict that tyrosine is deprotonated at the CO(2)H site. Cysteine is predicted to be deprotonated at the SH but the proton on the CO(2)H is shared with the S(-) site. Self-consistent reaction field (SCRF) calculations with the COSMO parametrization were used to predict the pK(a)'s of the non-zwitterion form in aqueous solution. The differences in the non-zwitterion pK(a) values were used to estimate the free energy difference between the zwitterion and nonzwitterion forms in solution. The heats of formation of the neutral compounds were calculated from atomization energies and isodesmic reactions to provide the first reliable set of these values in the gas phase. Further calculations were performed on five rare amino acids to predict their heats of formation, acidities, and pK(a) values.

  6. Advanced gas-emission anode design for microfluidic fuel cell eliminating bubble accumulation

    International Nuclear Information System (INIS)

    Zhang, Hao; Xuan, Jin; Wang, Huizhi; Leung, Dennis Y C; Xu, Hong; Zhang, Li

    2017-01-01

    A microfluidic fuel cell is a low cost, easily fabricated energy device and is considered a promising energy supplier for portable electronics. However, the currently developed microfluidic fuel cells that are fed with hydrocarbon fuels are confronted with a bubble problem especially when operating at high current density conditions. In this work, a gas-emission anode is presented to eliminate the gas accumulation at the anode. This gas-emission anode is verified as a valid design for discharging gaseous products, which is especially beneficial for stable operation of microfluidic fuel cells. The electrochemical performance of a counter-flow microfluidic fuel cell equipped with a gas-emission anode was measured. The results indicate that the specific design of the gas-emission anode is essential for reducing the oxygen reduction reaction parasitic effect at the anode. Fuel utilization of 76.4% was achieved at a flow rate of 0.35 µ l min −1 . Current–voltage curves of single electrodes were measured and the parasitic effect at the anode was identified as the main performance limiting factor in the presented anode design. (paper)

  7. Evaluation of greenhouse gas emission risks from storage of wood residue

    International Nuclear Information System (INIS)

    Wihersaari, Margareta

    2005-01-01

    The use of renewable energy sources instead of fossil fuels is one of the most important means of limiting greenhouse gas emissions in the near future. In Finland, wood energy is considered to be a very important potential energy source in this sense. There might, however, still be some elements of uncertainty when evaluating biofuel production chains. By combining data from a stack of composting biodegradable materials and forest residue storage research there was an indication that rather great amounts of greenhouse gases maybe released during storage of wood chip, especially if there is rapid decomposition. Unfortunately, there have not been many evaluations of greenhouse gas emissions of biomass handling and storage heaps. The greenhouse gas emissions are probably methane, when the temperature in the fuel stack is above the ambient temperature, and nitrous oxide, when the temperature is falling and the decaying process is slowing down. Nowadays it is still rather unusual to store logging residue as chips, because the production is small, but in Finland storage of bark and other by-products from the forest industry is a normal process. The evaluations made indicate that greenhouse gas emissions from storage can, in some cases, be much greater than emissions from the rest of the biofuel production and transportation chain

  8. FIRST CONNECTION BETWEEN COLD GAS IN EMISSION AND ABSORPTION: CO EMISSION FROM A GALAXY–QUASAR PAIR

    Energy Technology Data Exchange (ETDEWEB)

    Neeleman, Marcel; Prochaska, J. Xavier [Department of Astronomy and Astrophysics, UCO/Lick Observatory, University of California, 1156 High Street, Santa Cruz, CA 95064 (United States); Zwaan, Martin A.; Kampen, Eelco van; Møller, Palle [European Southern Observatory, Karl-Schwarzschild-strasse 2, D-85748 Garching bei München (Germany); Kanekar, Nissim [National Centre for Radio Astrophysics, Tata Institute of Fundamental Research, Pune 411007 (India); Christensen, Lise; Fynbo, Johan P. U. [Dark Cosmology Centre, Niels Bohr Institute, University of Copenhagen, Juliane Maries Vej 30, DK-2100 Copenhagen (Denmark); Dessauges-Zavadsky, Miroslava [Observatoire de Genève, Université de Genève, 51 Ch. des Maillettes, 1290 Sauverny (Switzerland); Zafar, Tayyaba, E-mail: marcel@ucsc.edu [Australian Astronomical Observatory, P.O. Box 915, North Ryde, NSW 1670 (Australia)

    2016-04-01

    We present the first detection of molecular emission from a galaxy selected to be near a projected background quasar using the Atacama Large Millimeter/submillimeter Array (ALMA). The ALMA detection of CO(1−0) emission from the z = 0.101 galaxy toward quasar PKS 0439–433 is coincident with its stellar disk and yields a molecular gas mass of M{sub mol} ≈ 4.2 × 10{sup 9} M{sub ⊙} (for a Galactic CO-to-H{sub 2} conversion factor), larger than the upper limit on its atomic gas mass. We resolve the CO velocity field, obtaining a rotational velocity of 134 ± 11 km s{sup −1} and a resultant dynamical mass of ≥4 × 10{sup 10} M{sub ⊙}. Despite its high metallicity and large molecular mass, the z = 0.101 galaxy has a low star formation rate, implying a large gas consumption timescale, larger than that typical of late-type galaxies. Most of the molecular gas is hence likely to be in a diffuse extended phase, rather than in dense molecular clouds. By combining the results of emission and absorption studies, we find that the strongest molecular absorption component toward the quasar cannot arise from the molecular disk, but is likely to arise from diffuse gas in the galaxy’s circumgalactic medium. Our results emphasize the potential of combining molecular and stellar emission line studies with optical absorption line studies to achieve a more complete picture of the gas within and surrounding high-redshift galaxies.

  9. Assessing the difference. Greenhouse gas emissions of electricity generation chains

    International Nuclear Information System (INIS)

    Spadaro, J.V.; Langlois, L.; Hamilton, B.

    2000-01-01

    Greenhouse gases have to the potential to influence global climate change by interfering with the natural process of heat exchange between the earth's atmosphere and outer space. Reducing atmospheric GHG concentrations have become an international priority as evidenced by the signing of the Kyoto Protocol, which would reduce emissions from industrialized countries (Annex 1) by about 5% below 1990 levels during the commitment period 2008-12. There are a number of technical options that could be implemented in order to achieve the proposed reduction target. As for emissions related to electricity generation, perhaps the most important factor over the near term is the improvement in efficiency of using energy at all the stages of the fuel cycle, including fuel preparation and transportation, fuel-to-electricity conversion at the power plant and at the point of end-use (which has not been considered here). Strategies for reducing methane releases during fuel mining and during gas transmission are very relevant. Switching to less carbon intensive or low carbon fuels, such as gas, nuclear power and renewables, will play a major role in reducing emissions. These changes are technically feasible using present day knowledge and experience, require minimal changes in consumer lifestyle, and represent reasonable capital turnover (gas and nuclear for baseload generation and renewables in niche markets or for peak load applications). This article has presented information on GHG emission factors for different fuels using a Full Energy Chain approach, which attempts to quantify the environmental emissions from all stages of electricity generation, i.e. 'cradle-to-grave'. Fossil-fueled technologies have the highest emission factors, with coal typically twice as high as natural gas. Considering the large variations in fuel- to-electricity conversion technology, it can be said that GHG emission factors can be an order of magnitude higher than current solar PV systems and up to two

  10. Greenhouse gas emissions from the energy sector

    International Nuclear Information System (INIS)

    Mbuthi, P.N.

    1998-01-01

    This study quantifies greenhouse gas emissions from Kenya's energy activities. It is organised in four major sections, namely, an overview of the energy sector; data sources and methodology of analysis; results and recommendations for future climate change mitigation

  11. Greenhouse gas emissions from South Africa

    CSIR Research Space (South Africa)

    Scholes, RJ

    1996-05-01

    Full Text Available of CO2. These gases included 350 Tg CO2 (65.6% of the effect), 183 Tg CH4 (34.2%) and 1.2 Tg N2O (0.2%). The mining and burning of coal contributed more than 80% of the greenhouse gas emissions from South African territory....

  12. Detecting gas leaks by ultrasonic emission

    DEFF Research Database (Denmark)

    Rasmussen, Karsten Bo; Henriksen, Eigil

    1997-01-01

    The emission of noise in the frequency range 10 kHz to 25.6 kHz from an experimental gas leak in a flanged joint has been experimentally investigated. The overall conclusion is that the emitted noise is almost frequency independent in level within the considered frequency range.A small PC program...

  13. Reducing the Green House Gas Emissions from the Transportation Sector

    Directory of Open Access Journals (Sweden)

    Oyewande Akinnikawe

    2010-02-01

    Full Text Available In the United States, two thirds of the carbon monoxide and about one third of carbon dioxide emissions come from the transportation sector. Ways to reduce these emissions in the future include replacing gasoline and diesel by biofuels, or by blend of biofuels with conventional gasoline and diesel, or by compressed natural gas (CNG, or by replacing internal combustion engines by electric motors powered by hydrogen fuel cells or battery-powered electric vehicles recharged from the electric grid. This presentation will review these technologies the fuel production pathways, when they are likely to be available, and by what fraction transportation sector green house gas emissions could be reduced by each. A well-to-wheels (WTW analysis is performed on each vehicle/ fuel technology using the GREET model and the total energy use, the CO 2 emissions, NO x emissions, SO x emissions for the life cycle of the vehicle technologies are calculated. Prospects for reducing foreign oil dependence as well as mitigating green house gases emission from the transportation sector will be considered in the analysis.

  14. Reducing greenhouse gas emissions and improving air quality: Two global challenges.

    Science.gov (United States)

    Erickson, Larry E

    2017-07-01

    There are many good reasons to promote sustainable development and reduce greenhouse gas emissions and other combustion emissions. The air quality in many urban environments is causing many premature deaths because of asthma, cardiovascular disease, chronic obstructive pulmonary disease, lung cancer, and dementia associated with combustion emissions. The global social cost of air pollution is at least $3 trillion/year; particulates, nitrogen oxides and ozone associated with combustion emissions are very costly pollutants. Better air quality in urban environments is one of the reasons for countries to work together to reduce greenhouse gas emissions through the Paris Agreement on Climate Change. There are many potential benefits associated with limiting climate change. In the recent past, the concentrations of greenhouse gases in the atmosphere have been increasing and the number of weather and climate disasters with costs over $1 billion has been increasing. The average global temperature set new record highs in 2014, 2015, and 2016. To reduce greenhouse gas emissions, the transition to electric vehicles and electricity generation using renewable energy must take place in accord with the goals of the Paris Agreement on Climate Change. This work reviews progress and identifies some of the health benefits associated with reducing combustion emissions. © 2017 American Institute of Chemical Engineers Environ Prog, 36: 982-988, 2017.

  15. Research on forecast technology of mine gas emission based on fuzzy data mining (FDM)

    Energy Technology Data Exchange (ETDEWEB)

    Xu Chang-kai; Wang Yao-cai; Wang Jun-wei [CUMT, Xuzhou (China). School of Information and Electrical Engineering

    2004-07-01

    The safe production of coalmine can be further improved by forecasting the quantity of gas emission based on the real-time data and historical data which the gas monitoring system has saved. By making use of the advantages of data warehouse and data mining technology for processing large quantity of redundancy data, the method and its application of forecasting mine gas emission quantity based on FDM were studied. The constructing fuzzy resembling relation and clustering analysis were proposed, which the potential relationship inside the gas emission data may be found. The mode finds model and forecast model were presented, and the detailed approach to realize this forecast was also proposed, which have been applied to forecast the gas emission quantity efficiently.

  16. Total greenhouse gas emissions related to the Dutch crop production system

    NARCIS (Netherlands)

    Kramer, K.J.; Moll, H.C.; Nonhebel, S.

    1999-01-01

    This article discusses the greenhouse gas emissions (CO2, CH4, N2O) related to Dutch agricultural crop production. Emissions occur during agricultural processes (direct emissions) as well as in the life cycle of the required inputs (indirect emissions). An integrated approach assesses the total

  17. Limiting net greenhouse gas emissions in the United States

    Energy Technology Data Exchange (ETDEWEB)

    Bradley, R A; Watts, E C; Williams, E R [eds.

    1991-09-01

    In 2988 the Congress requested DOE produce a study on carbon dioxide inventory and policy to provide an inventory of emissions sources and to analyze policies to achieve a 20% reduction in carbon dioxide emissions in 5 to 10 years and a 50% reduction in 15 to 20 years. This report presents the results of that study. Energy and environmental technology data were analyzed using computational analysis models. This information was then evaluated, drawing on current scientific understanding of global climate change, the possible consequences of anthropogenic climate change (change caused by human activity), and the relationship between energy production and use and the emission of radiactively important gases. Topics discussed include: energy and environmental technology to reduce greenhouse gas emissions, fossil energy production and electricity generation technologies, nuclear energy technology, renewable energy technologies, energy storage, transmission, and distribution technology, transportation, technology, industrial technology, residential and commercial building technology, greenhouse gas removal technology, approaches to restructuring the demand for energy.

  18. Effects of natural gas composition on performance and regulated, greenhouse gas and particulate emissions in spark-ignition engines

    International Nuclear Information System (INIS)

    Amirante, R.; Distaso, E.; Di Iorio, S.; Sementa, P.; Tamburrano, P.; Vaglieco, B.M.; Reitz, R.D.

    2017-01-01

    Highlights: • The influence of natural gas composition is investigated. • Real-time methane/propane fuel mixtures were realized. • IMEP, HRR and MBF were used to evaluate the effects on engine performance. • Gaseous, greenhouse and Particulate emissions were studied. • The propane content strongly influenced performance and emissions. - Abstract: In vehicles fueled with compressed natural gas, a variation in the fuel composition can have non-negligible effects on their performance, as well as on their emissions. The present work aimed to provide more insight on this crucial aspect by performing experiments on a single-cylinder port-fuel injected spark-ignition engine. In particular, methane/propane mixtures were realized to isolate the effects of a variation of the main constituents in natural gas on engine performance and associated pollutant emissions. The propane volume fraction was varied from 10 to 40%. Using an experimental procedure designed and validated to obtain precise real-time mixture fractions to inject directly into the intake manifold. Indicative Mean Effective Pressure, Heat Release Rate and Mass Burned Fraction were used to evaluate the effects on engine performance. Gaseous emissions were measured as well. Particulate Mass, Number and Size Distributions were analyzed with the aim to identify possible correlations existing between fuel composition and soot emissions. Emissions samples were taken from the exhaust flow, just downstream of the valves. Opacity was measured downstream the Three-Way Catalyst. Three different engine speeds were investigated, namely 2000, 3000 and 4000 rpm. Stoichiometric and full load conditions were considered in all tests. The results were compared with pure methane and propane, as well as with natural gas. The results indicated that both performance and emissions were strongly influenced by the variation of the propane content. Increasing the propane fraction favored more complete combustion and increased NO

  19. Implications of greenhouse gas emission mitigation scenarios for the main Asian regions

    NARCIS (Netherlands)

    van Ruijven, B.J.|info:eu-repo/dai/nl/304834521; van Vuuren, D.P.|info:eu-repo/dai/nl/11522016X; van Vliet, J.; Mendoza Beltran, A.; Deetman, S.; den Elzen, M.G.J.

    2012-01-01

    In order to limit global mean temperature increase, long-term greenhouse gas emissions need to be reduced. This paper discusses the implications of greenhouse gas emission reductions for major Asian regions (China, India, Indonesia, South-East Asia, Japan and Korea) based on results from the IMAGE

  20. Life Cycle Assessment of Greenhouse Gas Emissions

    NARCIS (Netherlands)

    Reijnders, L.; Chen, W.Y.; Suzuki, T.; Lackner, M.

    2015-01-01

    Life cycle assessments of greenhouse gas emissions have been developed for analyzing products "from cradle to grave": from resource extraction to waste disposal. Life cycle assessment methodology has also been applied to economies, trade between countries, aspects of production, and waste

  1. Fugitive emission inventory from Brazilian oil and gas industry (2000-2005) and discussion of mitigation measures

    Energy Technology Data Exchange (ETDEWEB)

    Carloni, Flavia A.; D' Avignon, Alexandre; La Rovere, Emilio L. [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia (COPPE). Centro Clima

    2008-07-01

    The objective of this work is to evaluate current emissions of GHGs within the Brazilian oil and gas industry, specifically the fugitive emissions arising from exploration and production. Besides, projects for mitigating these emissions and opportunities for the national industry are investigated. Results show that N{sub 2}O contributes little to fugitive emissions from the oil and gas industry, principally from gas sector. NMVOC emissions are significant, principally from the oil sector. In relation to CO{sub 2} and CH{sub 4} emissions, the oil sector emits more CO{sub 2} while the gas sector contributes more to CH{sub 4} emissions. In both sectors flaring is the activity that emits most CO{sub 2}. In relation to CH{sub 4} the principal contribution to emissions are from exploration and production onshore, although offshore activities as a whole play a greater part in the national industry. The results make it clear that the use of gas from flaring activity is a great opportunity for emission mitigation projects. From a business point of view, methane emissions could mean lost opportunities in selling natural gas. The Kyoto Protocol mechanisms, as the Clean Development Mechanism and Joint Implementation actions, provide the opportunity to stimulate investments in projects for reducing flaring and venting of associated gas. (author)

  2. Nitrogen enriched combustion of a natural gas internal combustion engine to reduce NO.sub.x emissions

    Science.gov (United States)

    Biruduganti, Munidhar S.; Gupta, Sreenath Borra; Sekar, R. Raj; McConnell, Steven S.

    2008-11-25

    A method and system for reducing nitrous oxide emissions from an internal combustion engine. An input gas stream of natural gas includes a nitrogen gas enrichment which reduces nitrous oxide emissions. In addition ignition timing for gas combustion is advanced to improve FCE while maintaining lower nitrous oxide emissions.

  3. Reducing greenhouse gas emissions from the Ontario automotive sector

    International Nuclear Information System (INIS)

    Anon.

    1995-11-01

    A variety of options to reduce greenhouse gas emissions from the automotive sector in Ontario over the next decade were discussed. Each option was assessed in terms of practicality and implications for implementation. I was concluded that improvements in fuel economy anticipated from advancing technology, with or without new mandated standards, will not be enough to offset the impact of growth in vehicle fleet size and kilometres driven. If the goal is to stabilize greenhouse gas emissions, other measures such as reducing the fleet size and vehicle kilometres travelled and accelerated vehicle retirement (scrappage) programs must be considered. Key constraints on expansion of the alternative fuel fleet were identified. These include: (1) limited availability of an adequate range of alternative fuel vehicles at competitive prices, (2) limited refuelling facility infrastructure in the case of natural gas, limited range and fuel storage capacity for natural gas; (3)current limited fuel ethanol production capacity, and (4) market perceptions of performance, reliability and safety. tabs

  4. Multi-objective optimisation of wastewater treatment plant control to reduce greenhouse gas emissions.

    Science.gov (United States)

    Sweetapple, Christine; Fu, Guangtao; Butler, David

    2014-05-15

    This study investigates the potential of control strategy optimisation for the reduction of operational greenhouse gas emissions from wastewater treatment in a cost-effective manner, and demonstrates that significant improvements can be realised. A multi-objective evolutionary algorithm, NSGA-II, is used to derive sets of Pareto optimal operational and control parameter values for an activated sludge wastewater treatment plant, with objectives including minimisation of greenhouse gas emissions, operational costs and effluent pollutant concentrations, subject to legislative compliance. Different problem formulations are explored, to identify the most effective approach to emissions reduction, and the sets of optimal solutions enable identification of trade-offs between conflicting objectives. It is found that multi-objective optimisation can facilitate a significant reduction in greenhouse gas emissions without the need for plant redesign or modification of the control strategy layout, but there are trade-offs to consider: most importantly, if operational costs are not to be increased, reduction of greenhouse gas emissions is likely to incur an increase in effluent ammonia and total nitrogen concentrations. Design of control strategies for a high effluent quality and low costs alone is likely to result in an inadvertent increase in greenhouse gas emissions, so it is of key importance that effects on emissions are considered in control strategy development and optimisation. Copyright © 2014 Elsevier Ltd. All rights reserved.

  5. Analysis of Sustainable Technologies for Acid Gas Removal

    OpenAIRE

    Dal Pozzo, Alessandro

    2017-01-01

    Acid gases, such as sulphur dioxide and hydrogen halides and – in a broad sense – carbon dioxide, are typical pollutants generated by combustion processes. Their removal by means of solid sorbents represent an efficient and cost-effective approach in dry acid gas treatment systems for waste incineration flue gas, while for CO2 capture the process is exploratively studied as a promising alternative to amine scrubbing. The present study addressed both aspects. In waste incineration flue gas ...

  6. High-global warming potential F-gas emissions in California: comparison of ambient-based versus inventory-based emission estimates, and implications of refined estimates.

    Science.gov (United States)

    Gallagher, Glenn; Zhan, Tao; Hsu, Ying-Kuang; Gupta, Pamela; Pederson, James; Croes, Bart; Blake, Donald R; Barletta, Barbara; Meinardi, Simone; Ashford, Paul; Vetter, Arnie; Saba, Sabine; Slim, Rayan; Palandre, Lionel; Clodic, Denis; Mathis, Pamela; Wagner, Mark; Forgie, Julia; Dwyer, Harry; Wolf, Katy

    2014-01-21

    To provide information for greenhouse gas reduction policies, the California Air Resources Board (CARB) inventories annual emissions of high-global-warming potential (GWP) fluorinated gases, the fastest growing sector of greenhouse gas (GHG) emissions globally. Baseline 2008 F-gas emissions estimates for selected chlorofluorocarbons (CFC-12), hydrochlorofluorocarbons (HCFC-22), and hydrofluorocarbons (HFC-134a) made with an inventory-based methodology were compared to emissions estimates made by ambient-based measurements. Significant discrepancies were found, with the inventory-based emissions methodology resulting in a systematic 42% under-estimation of CFC-12 emissions from older refrigeration equipment and older vehicles, and a systematic 114% overestimation of emissions for HFC-134a, a refrigerant substitute for phased-out CFCs. Initial, inventory-based estimates for all F-gas emissions had assumed that equipment is no longer in service once it reaches its average lifetime of use. Revised emission estimates using improved models for equipment age at end-of-life, inventories, and leak rates specific to California resulted in F-gas emissions estimates in closer agreement to ambient-based measurements. The discrepancies between inventory-based estimates and ambient-based measurements were reduced from -42% to -6% for CFC-12, and from +114% to +9% for HFC-134a.

  7. Greenhouse-gas emissions from biomass energy use: Comparison with other energy technologies

    International Nuclear Information System (INIS)

    Morris, G.P.; Norman, N.A.; Gleick, P.H.

    1991-01-01

    Recently a major new concern has arisen: the accumulation of greenhouse gases in the atmosphere. It is now generally believed that continued emissions of these gases are current or increasing levels will lead to significant climatic changes with the potential for dramatic, adverse impacts. Since the major anthropogenic source of greenhouse gas emissions is energy production and use, it is essential to future energy policy to understand how energy sources differ with respect to greenhouse gas emissions. Characterizing the greenhouse gas emissions associated with biomass energy use is extremely complicated. It is necessary to consider both the source and alternative use of the biomass material and its alternative disposal (if any), as well as the biomass energy application itself. It is desirable also to consider not just CO 2 emissions, but also CH 4 and N 2 O, both potent greenhouse gases. The authors' analysis shows that in many cases biomass energy use can actually help to ameliorate the greenhouse effect by converting emissions that would have been CH 4 into the less potent greenhouse gas CO 2 . In many cases the beneficial effect is very dramatic. This major new research result should help increase public support for biomass research and development, and for further development of waste conversion technology and installations

  8. Methane emissions from the global oil and gas supply chain: recent advances and next steps

    Science.gov (United States)

    Zavala Araiza, D.; Herndon, S. C.; Roscioli, J. R.; Yacovitch, T. I.; Knighton, W. B.; Johnson, M.; Tyner, D. R.; Hamburg, S.

    2017-12-01

    A wide body of research has characterized methane emissions from the oil and gas system in the US. In contrast, empirical data is limited for other significant oil and gas producing regions across the world. As a consequence, measuring and characterizing methane emissions across global oil and gas operations will be crucial to the design of effective mitigation strategies. Several countries have announced pledges to reduce methane emissions from this system (e.g., North America, Climate and Clean Air Coalition [CCAC] ministers). In the case of Canada, the federal government recently announced regulations supporting a 40-45% reduction of methane emissions from the oil and gas production systems. For these regulations to be effective, it is critical to understand the current methane emission patterns. We present results from a coordinated multiscale (i.e., airborne-based, ground-based) measurement campaign in Alberta, Canada. We use empirically derived emission estimates to characterize site-level emissions and derive an emissions distribution. Our work shows that many major sources of emissions are unmeasured or underreported. Consistent with previous studies in the US, a small fraction of sites disproportionately account for the majority of emissions: roughly 20% of sites accounted for 75% of emissions. An independent airborne-based regional estimate was 40% lower than the ground-based regional estimate, but not statistically different. Finally, we summarize next steps as part of the CCAC Oil and Gas Methane Study: ongoing work that is targeting oil and gas sectors/production regions with limited empirical data on methane emissions. This work builds on the approach deployed in quantifying methane emissions from the oil and gas supply chain in the US, underscoring the commitment to transparency of the collected data, external review, deployment of multiple methodologies, and publication of results in peer-reviewed journals.

  9. Impact of cutting meat intake on hidden greenhouse gas emissions in an import-reliant city

    Science.gov (United States)

    Yau, Y. Y.; Thibodeau, B.; Not, C.

    2018-06-01

    Greenhouse gas emissions embodied in trade is a growing concern for the international community. Multiple studies have highlighted drawbacks in the territorial and production-based accounting of greenhouse gas emissions because it neglects emissions from the consumption of goods in trade. This creates weak carbon leakage and complicates international agreements on emissions regulations. Therefore, we estimated consumption-based emissions using input-output analysis and life cycle assessment to calculate the greenhouse gas emissions hidden in meat and dairy products in Hong Kong, a city predominately reliant on imports. We found that emissions solely from meat and dairy consumption were higher than the city’s total greenhouse gas emissions using conventional production-based calculation. This implies that government reports underestimate more than half of the emissions, as 62% of emissions are embodied in international trade. The discrepancy emphasizes the need of transitioning climate targets and policy to consumption-based accounting. Furthermore, we have shown that dietary change from a meat-heavy diet to a diet in accordance with governmental nutrition guidelines could achieve a 67% reduction in livestock-related emissions, allowing Hong Kong to achieve the Paris Agreement targets for 2030. Consequently, we concluded that consumption-based accounting for greenhouse gas emissions is crucial to target the areas where emissions reduction is realistically achievable, especially for import-reliant cities like Hong Kong.

  10. Application of microturbines to control emissions from associated gas

    Science.gov (United States)

    Schmidt, Darren D.

    2013-04-16

    A system for controlling the emission of associated gas produced from a reservoir. In an embodiment, the system comprises a gas compressor including a gas inlet in fluid communication with an associated gas source and a gas outlet. The gas compressor adjusts the pressure of the associated gas to produce a pressure-regulated associated gas. In addition, the system comprises a gas cleaner including a gas inlet in fluid communication with the outlet of the gas compressor, a fuel gas outlet, and a waste product outlet. The gas cleaner separates at least a portion of the sulfur and the water from the associated gas to produce a fuel gas. Further, the system comprises a gas turbine including a fuel gas inlet in fluid communication with the fuel gas outlet of the gas cleaner and an air inlet. Still further, the system comprises a choke in fluid communication with the air inlet.

  11. Greenhouse gas emissions from industrial activities

    International Nuclear Information System (INIS)

    Kinyanjui, L.N.

    1998-01-01

    This study considers greenhouse gas emissions stemming from industrial activities such as cement production; limestone use and lime production. The Intergovernmental Panel on Climate Change (IPCC) (1995a) methodology for industrial sector was applied for the three components selected. Limitations hindering the handling of other industrial process are listed as budgetary and time. Data sources and recommendations are listed

  12. Greenhouse gas emissions from high demand, natural gas-intensive energy scenarios

    International Nuclear Information System (INIS)

    Victor, D.G.

    1990-01-01

    Since coal and oil emit 70% and 30% more CO 2 per unit of energy than natural gas (methane), fuel switching to natural gas is an obvious pathway to lower CO 2 emissions and reduced theorized greenhouse warming. However, methane is, itself, a strong greenhouse gas so the CO 2 advantages of natural gas may be offset by leaks in the natural gas recovery and supply system. Simple models of atmospheric CO 2 and methane are used to test this hypothesis for several natural gas-intensive energy scenarios, including the work of Ausubel et al (1988). It is found that the methane leaks are significant and may increase the total 'greenhouse effect' from natural gas-intensive energy scenarios by 10%. Furthermore, because methane is short-lived in the atmosphere, leaking methane from natural gas-intensive, high energy growth scenarios effectively recharges the concentration of atmospheric methane continuously. For such scenarios, the problem of methane leaks is even more serious. A second objective is to explore some high demand scenarios that describe the role of methane leaks in the greenhouse tradeoff between gas and coal as energy sources. It is found that the uncertainty in the methane leaks from the natural gas system are large enough to consume the CO 2 advantages from using natural gas instead of coal for 20% of the market share. (author)

  13. Life cycle assessment of greenhouse gas emissions

    NARCIS (Netherlands)

    Reijnders, L.; Chen, W.Y.; Seiner, J.; Suzuki, T.; Lackner, M.

    2012-01-01

    Life cycle assessments of greenhouse gas emissions have been developed for analyzing products "from cradle to grave": from resource extraction to waste disposal. Life cycle assessment methodology has also been applied to economies, trade between countries, aspects of production and to waste

  14. Life cycle assessment of greenhouse gas emissions

    NARCIS (Netherlands)

    Reijnders, L.; Chen, W.-Y.; Suzuki, T.; Lackner, M.

    2017-01-01

    Life cycle assessments of greenhouse gas emissions have been developed for analyzing products “from cradle to grave”: from resource extraction to waste disposal. Life cycle assessment methodology has also been applied to economies, trade between countries, aspects of production, and waste

  15. Using Willie's Acid-Base Box for Blood Gas Analysis

    Science.gov (United States)

    Dietz, John R.

    2011-01-01

    In this article, the author describes a method developed by Dr. William T. Lipscomb for teaching blood gas analysis of acid-base status and provides three examples using Willie's acid-base box. Willie's acid-base box is constructed using three of the parameters of standard arterial blood gas analysis: (1) pH; (2) bicarbonate; and (3) CO[subscript…

  16. Australia's Greenhouse Challenge is a positive step towards abatement of gas emissions

    International Nuclear Information System (INIS)

    Anon.

    1997-01-01

    Australian industry has responded favourably to the Federal Government's Greenhouse Clallenge Program (GCP) which has focused on curbing greenhouse gas emission from the manufacturing, mining and energy sector. It is a carefully shaped program which prompts companies and groups to thoroughly review their individual operations and identify areas where credible new or addition emission control can be employed. There are now 42 companies and associations that have signed agreements in GCP. Together they account for some 15 % of Australia's total greenhouse gas emissions. It is expected that by 2000 the emission increase will be cut to 7 % and the total emissions cut by 16 million tonnes for the 42 companies concerned

  17. Greenhouse gas emissions from nitrogen fertilizer use in China

    International Nuclear Information System (INIS)

    Kahrl, Fredrich; Li, Yunju; Su, Yufang; Tennigkeit, Timm; Wilkes, Andreas; Xu, Jianchu

    2010-01-01

    The use of synthetic nitrogen (N) fertilizers is an important driver of energy use and greenhouse gas (GHG) emissions in China. This paper develops a GHG emission factor for synthetic N fertilizer application in China. Using this emission factor, we estimate the scale of GHG emissions from synthetic nitrogen fertilizer use in Chinese agriculture and explore the potential for GHG emission reductions from efficiency improvements in N fertilizer production and use. The paper concludes with a discussion on costs and financing for a large-scale fertilizer efficiency improvement program in China, and how a GHG mitigation framework might contribute to program design.

  18. Greenhouse gas emissions from dairy manure management: a review of field-based studies.

    Science.gov (United States)

    Owen, Justine J; Silver, Whendee L

    2015-02-01

    Livestock manure management accounts for almost 10% of greenhouse gas emissions from agriculture globally, and contributes an equal proportion to the US methane emission inventory. Current emissions inventories use emissions factors determined from small-scale laboratory experiments that have not been compared to field-scale measurements. We compiled published data on field-scale measurements of greenhouse gas emissions from working and research dairies and compared these to rates predicted by the IPCC Tier 2 modeling approach. Anaerobic lagoons were the largest source of methane (368 ± 193 kg CH4 hd(-1) yr(-1)), more than three times that from enteric fermentation (~120 kg CH4 hd(-1) yr(-1)). Corrals and solid manure piles were large sources of nitrous oxide (1.5 ± 0.8 and 1.1 ± 0.7 kg N2O hd(-1) yr(-1), respectively). Nitrous oxide emissions from anaerobic lagoons (0.9 ± 0.5 kg N2O hd(-1) yr(-1)) and barns (10 ± 6 kg N2O hd(-1) yr(-1)) were unexpectedly large. Modeled methane emissions underestimated field measurement means for most manure management practices. Modeled nitrous oxide emissions underestimated field measurement means for anaerobic lagoons and manure piles, but overestimated emissions from slurry storage. Revised emissions factors nearly doubled slurry CH4 emissions for Europe and increased N2O emissions from solid piles and lagoons in the United States by an order of magnitude. Our results suggest that current greenhouse gas emission factors generally underestimate emissions from dairy manure and highlight liquid manure systems as promising target areas for greenhouse gas mitigation. © 2014 John Wiley & Sons Ltd.

  19. Comparing the greenhouse gas emissions from three alternative waste combustion concepts.

    Science.gov (United States)

    Vainikka, Pasi; Tsupari, Eemeli; Sipilä, Kai; Hupa, Mikko

    2012-03-01

    Three alternative condensing mode power and combined heat and power (CHP) waste-to-energy concepts were compared in terms of their impacts on the greenhouse gas (GHG) emissions from a heat and power generation system. The concepts included (i) grate, (ii) bubbling fluidised bed (BFB) and (iii) circulating fluidised bed (CFB) combustion of waste. The BFB and CFB take advantage of advanced combustion technology which enabled them to reach electric efficiency up to 35% and 41% in condensing mode, respectively, whereas 28% (based on the lower heating value) was applied for the grate fired unit. A simple energy system model was applied in calculating the GHG emissions in different scenarios where coal or natural gas was substituted in power generation and mix of fuel oil and natural gas in heat generation by waste combustion. Landfilling and waste transportation were not considered in the model. GHG emissions were reduced significantly in all of the considered scenarios where the waste combustion concepts substituted coal based power generation. With the exception of condensing mode grate incinerator the different waste combustion scenarios resulted approximately in 1 Mton of fossil CO(2)-eq. emission reduction per 1 Mton of municipal solid waste (MSW) incinerated. When natural gas based power generation was substituted by electricity from the waste combustion significant GHG emission reductions were not achieved. Copyright © 2011 Elsevier Ltd. All rights reserved.

  20. Comparing the greenhouse gas emissions from three alternative waste combustion concepts

    International Nuclear Information System (INIS)

    Vainikka, Pasi; Tsupari, Eemeli; Sipilä, Kai; Hupa, Mikko

    2012-01-01

    Highlights: ► Significant GHG reductions are possible by efficient WtE technologies. ► CHP and high power-to-heat ratio provide significant GHG savings. ► N 2 O and coal mine type are important in LCA GHG emissions of FBC co-combustion. ► Substituting coal and fuel oil by waste is beneficial in electricity and heat production. ► Substituting natural gas by waste may not be reasonable in CHP generation. - Abstract: Three alternative condensing mode power and combined heat and power (CHP) waste-to-energy concepts were compared in terms of their impacts on the greenhouse gas (GHG) emissions from a heat and power generation system. The concepts included (i) grate, (ii) bubbling fluidised bed (BFB) and (iii) circulating fluidised bed (CFB) combustion of waste. The BFB and CFB take advantage of advanced combustion technology which enabled them to reach electric efficiency up to 35% and 41% in condensing mode, respectively, whereas 28% (based on the lower heating value) was applied for the grate fired unit. A simple energy system model was applied in calculating the GHG emissions in different scenarios where coal or natural gas was substituted in power generation and mix of fuel oil and natural gas in heat generation by waste combustion. Landfilling and waste transportation were not considered in the model. GHG emissions were reduced significantly in all of the considered scenarios where the waste combustion concepts substituted coal based power generation. With the exception of condensing mode grate incinerator the different waste combustion scenarios resulted approximately in 1 Mton of fossil CO 2 -eq. emission reduction per 1 Mton of municipal solid waste (MSW) incinerated. When natural gas based power generation was substituted by electricity from the waste combustion significant GHG emission reductions were not achieved.

  1. Reduction of greenhouse gas in power industry by emission trading system

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Eun Myung; Lee, Kee Hoon [Korea Energy Economics Institute, Euiwang (Korea)

    1999-04-01

    The rules governing their implementation and operation for implementing the Kyoto Protocol including emissions permit trading, project-based credit trading and the Clean Development Mechanism are to be decided at future talks. How these policies are eventually designed will determine the effectiveness of the Protocol. However, it has been passive and insufficient to deal with the Kyoto Protocol since there is no obligation on reduction of greenhouse gas emissions. Therefore, the issues on emissions permit trading are analyzed and the strategies for utilizing the Kyoto mechanism effectively are presented through reviewing the existing negotiation strategies. Moreover, how to use emissions permit trading in the power industry, the largest greenhouse gas emissions industry, is examined by dividing into two sections, domestic and abroad. (author). 62 refs., 2 figs., 42 tabs.

  2. Methane emissions from natural gas infrastructure and use in the urban region of Boston, Massachusetts.

    Science.gov (United States)

    McKain, Kathryn; Down, Adrian; Raciti, Steve M; Budney, John; Hutyra, Lucy R; Floerchinger, Cody; Herndon, Scott C; Nehrkorn, Thomas; Zahniser, Mark S; Jackson, Robert B; Phillips, Nathan; Wofsy, Steven C

    2015-02-17

    Methane emissions from natural gas delivery and end use must be quantified to evaluate the environmental impacts of natural gas and to develop and assess the efficacy of emission reduction strategies. We report natural gas emission rates for 1 y in the urban region of Boston, using a comprehensive atmospheric measurement and modeling framework. Continuous methane observations from four stations are combined with a high-resolution transport model to quantify the regional average emission flux, 18.5 ± 3.7 (95% confidence interval) g CH4 ⋅ m(-2) ⋅ y(-1). Simultaneous observations of atmospheric ethane, compared with the ethane-to-methane ratio in the pipeline gas delivered to the region, demonstrate that natural gas accounted for ∼ 60-100% of methane emissions, depending on season. Using government statistics and geospatial data on natural gas use, we find the average fractional loss rate to the atmosphere from all downstream components of the natural gas system, including transmission, distribution, and end use, was 2.7 ± 0.6% in the Boston urban region, with little seasonal variability. This fraction is notably higher than the 1.1% implied by the most closely comparable emission inventory.

  3. Accounting for greenhouse gas emissions outside the national borders in FENCH-GHG energy planning

    International Nuclear Information System (INIS)

    Vate, J.F. van de

    1996-01-01

    This paper aims at providing guidance to the workshop discussion on the accountability of full-energy-chain greenhouse gas emissions from the use of energy sources if emissions did not take place inside the national borders of a country. Examples of such emissions are those from the generation of imported electricity or from mining and transportation of coal and natural gas. The FENCH-GHG approach, if used in energy planning, would automatically take such greenhouse gas emissions, which are inherent to energy systems, into account. The paper raises the basics, practicality and the feasibility of dealing with extra-boundary emissions in energy planning. (author). 3 refs

  4. Rice management interventions to mitigate greenhouse gas emissions: a review.

    Science.gov (United States)

    Hussain, Saddam; Peng, Shaobing; Fahad, Shah; Khaliq, Abdul; Huang, Jianliang; Cui, Kehui; Nie, Lixiao

    2015-03-01

    Global warming is one of the gravest threats to crop production and environmental sustainability. Rice, the staple food of more than half of the world's population, is the most prominent cause of greenhouse gas (GHG) emissions in agriculture and gives way to global warming. The increasing demand for rice in the future has deployed tremendous concerns to reduce GHG emissions for minimizing the negative environmental impacts of rice cultivation. In this review, we presented a contemporary synthesis of existing data on how crop management practices influence emissions of GHGs in rice fields. We realized that modifications in traditional crop management regimes possess a huge potential to overcome GHG emissions. We examined and evaluated the different possible options and found that modifying tillage permutations and irrigation patterns, managing organic and fertilizer inputs, selecting suitable cultivar, and cropping regime can mitigate GHG emissions. Previously, many authors have discussed the feasibility principle and the influence of these practices on a single gas or, in particular, in the whole agricultural sector. Nonetheless, changes in management practices may influence more than one gas at the same time by different mechanisms or sometimes their effects may be antagonistic. Therefore, in the present attempt, we estimated the overall global warming potential of each approach to consider the magnitude of its effects on all gases and provided a comprehensive assessment of suitable crop management practices for reducing GHG emissions in rice culture.

  5. Wellbeing Impacts of City Policies for Reducing Greenhouse Gas Emissions

    Directory of Open Access Journals (Sweden)

    Rosemary Hiscock

    2014-11-01

    Full Text Available To mitigate climate change, city authorities are developing policies in areas such as transportation, housing and energy use, to reduce greenhouse gas emissions. In addition to their effects on greenhouse gas emissions, these policies are likely to have consequences for the wellbeing of their populations for example through changes in opportunities to take physical exercise. In order to explore the potential consequences for wellbeing, we first explore what ‘wellbeing’ is and how it can be operationalised for urban planners. In this paper, we illustrate how wellbeing can be divided into objective and subjective aspects which can be measured quantitatively; our review of measures informs the development of a theoretical model linking wellbeing to policies which cities use to reduce greenhouse gas emissions. Finally, we discuss the extent to which the links proposed in the conceptual model are supported by the literature and how cities can assess wellbeing implications of policies.

  6. Greenhouse gas emission factor development for coal-fired power plants in Korea

    International Nuclear Information System (INIS)

    Jeon, Eui-Chan; Myeong, Soojeong; Sa, Jae-Whan; Kim, Jinsu; Jeong, Jae-Hak

    2010-01-01

    Accurate estimation of greenhouse gas emissions is essential for developing an appropriate strategy to mitigate global warming. This study examined the characteristics of greenhouse gas emission from power plants, a major greenhouse gas source in Korea. The power plants examined use bituminous coal, anthracite, and sub-bituminous coal as fuel. The CO 2 concentration from power plants was measured using GC-FID with methanizer. The amount of carbon, hydrogen, and calorific values in the input fuel was measured using an elemental analyzer and calorimeter. For fuel analysis, CO 2 emission factors for anthracite, bituminous coal, and sub-bituminous coal were 108.9, 88.4, and 97.9 Mg/kJ, respectively. The emission factors developed in this study were compared with those for IPCC. The results showed that CO 2 emission was 10.8% higher for anthracite, 5.5% lower for bituminous coal, and 1.9% higher for sub-bituminous coal than the IPCC figures.

  7. Full energy chain analysis of greenhouse gas emissions from different energy sources

    International Nuclear Information System (INIS)

    Vate, J.F. van de

    1996-01-01

    The field of work of the Advisory Group Meeting/Workshop, i.e. full-energy chain emissions of greenhouse gases, is defined, and its environment, i.e. the Earth Summit -the 1992 UN Conference on Environment and Development in Rio-, is discussed. It is inferred that countries that ratified the Earth Summit's Convention on Climate Change have committed themselves to lower the greenhouse gas emissions from their energy use, and that this can be done most effectively by accounting in energy planning for the full-energy chain emissions of all greenhouse gases. The scatter in literature values of greenhouse gas emission factors of the full energy chain of individual energy sources is discussed. The scatter among others is due to different analytical methods, data bases and system boundaries, and due to neglect of the non-CO 2 greenhouse gases and professional biases. Generic values for greenhouse gas emission factors of energy and materials use are proposed. (author). 10 refs, 2 tabs

  8. Estimation of Energy Consumption and Greenhouse Gas Emissions of Transportation in Beef Cattle Production

    Directory of Open Access Journals (Sweden)

    Narayanan Kannan

    2016-11-01

    Full Text Available Accounting for transportation is an important part of the life cycle analysis (LCA of beef cattle production because it is associated with energy consumption and greenhouse gas emissions. This paper describes the development and application of a model that estimates energy consumption and greenhouse gas emissions of transport in beef cattle production. The animal transport model is based on the weight and number of animals in each weight category, type of trailer, vehicle, and fuel used. The energy consumption and greenhouse gas emission estimates of animal feed transportation are based on the weight of a truckload and the number of truckloads of feed transported. Our results indicate that a truckload is travelling approximately 326 km in connection with beef cattle production in the study region. The fuel consumption amounts to 24 L of fossil fuel per 1000 kg of boneless beef. The corresponding greenhouse gas emission is 83 kg. It appears from our results that the majority of energy consumption and greenhouse gas emissions are associated with sending the finished cattle to slaughterhouses and bringing feeder cattle to feedlots. Our results point out appreciable reductions in energy consumption and greenhouse gas emissions by changing from conventional fuel to bio-fuel.

  9. No tillage and liming reduce greenhouse gas emissions from poorly drained agricultural soils in Mediterranean regions

    International Nuclear Information System (INIS)

    García-Marco, Sonia; Abalos, Diego; Espejo, Rafael; Vallejo, Antonio; Mariscal-Sancho, Ignacio

    2016-01-01

    No tillage (NT) has been associated to increased N_2O emission from poorly drained agricultural soils. This is the case for soils with a low permeable Bt horizon, which generates a perched water layer after water addition (via rainfall or irrigation) over a long period of time. Moreover, these soils often have problems of acidity and require liming application to sustain crop productivity; changes in soil pH have large implications for the production and consumption of soil greenhouse gas (GHG) emissions. Here, we assessed in a split-plot design the individual and interactive effects of tillage practices (conventional tillage (CT) vs. NT) and liming (Ca-amendment vs. not-amendment) on N_2O and CH_4 emissions from poorly drained acidic soils, over a field experiment with a rainfed triticale crop. Soil mineral N concentrations, pH, temperature, moisture, water soluble organic carbon, GHG fluxes and denitrification capacity were measured during the experiment. Tillage increased N_2O emissions by 68% compared to NT and generally led to higher CH_4 emissions; both effects were due to the higher soil moisture content under CT plots. Under CT, liming reduced N_2O emissions by 61% whereas no effect was observed under NT. Under both CT and NT, CH_4 oxidation was enhanced after liming application due to decreased Al"3"+ toxicity. Based on our results, NT should be promoted as a means to improve soil physical properties and concurrently reduce N_2O and CH_4 emissions. Raising the soil pH via liming has positive effects on crop yield; here we show that it may also serve to mitigate CH_4 emissions and, under CT, abate N_2O emissions. - Highlights: • The effect of tillage and liming on GHG was studied in poorly drained acidic soils. • NT reduced N_2O emissions, global warming potential and greenhouse gases intensity. • Liming reduced N_2O and CH_4 emissions under CT; no effect was observed under NT. • NT and liming provide an opportunity for N_2O and CH_4 mitigation.

  10. No tillage and liming reduce greenhouse gas emissions from poorly drained agricultural soils in Mediterranean regions

    Energy Technology Data Exchange (ETDEWEB)

    García-Marco, Sonia, E-mail: sonia.garcia@upm.es [Departamento de Química y Tecnología de los Alimentos, E.T.S.I. Agronómica, Alimentaria y de Biosistemas, Universidad Politécnica de Madrid, Ciudad Universitaria, 28040 Madrid (Spain); Abalos, Diego, E-mail: diego.abalosrodriguez@wur.nl [Departamento de Química y Tecnología de los Alimentos, E.T.S.I. Agronómica, Alimentaria y de Biosistemas, Universidad Politécnica de Madrid, Ciudad Universitaria, 28040 Madrid (Spain); Espejo, Rafael, E-mail: rafael.espejo@upm.es [Departamento de Producción Agraria, E.T.S.I. Agronómica, Alimentaria y de Biosistemas, Universidad Politécnica de Madrid, Ciudad Universitaria, 28040 Madrid (Spain); Vallejo, Antonio, E-mail: antonio.vallejo@upm.es [Departamento de Química y Tecnología de los Alimentos, E.T.S.I. Agronómica, Alimentaria y de Biosistemas, Universidad Politécnica de Madrid, Ciudad Universitaria, 28040 Madrid (Spain); Mariscal-Sancho, Ignacio, E-mail: i.mariscal@upm.es [Departamento de Producción Agraria, E.T.S.I. Agronómica, Alimentaria y de Biosistemas, Universidad Politécnica de Madrid, Ciudad Universitaria, 28040 Madrid (Spain)

    2016-10-01

    No tillage (NT) has been associated to increased N{sub 2}O emission from poorly drained agricultural soils. This is the case for soils with a low permeable Bt horizon, which generates a perched water layer after water addition (via rainfall or irrigation) over a long period of time. Moreover, these soils often have problems of acidity and require liming application to sustain crop productivity; changes in soil pH have large implications for the production and consumption of soil greenhouse gas (GHG) emissions. Here, we assessed in a split-plot design the individual and interactive effects of tillage practices (conventional tillage (CT) vs. NT) and liming (Ca-amendment vs. not-amendment) on N{sub 2}O and CH{sub 4} emissions from poorly drained acidic soils, over a field experiment with a rainfed triticale crop. Soil mineral N concentrations, pH, temperature, moisture, water soluble organic carbon, GHG fluxes and denitrification capacity were measured during the experiment. Tillage increased N{sub 2}O emissions by 68% compared to NT and generally led to higher CH{sub 4} emissions; both effects were due to the higher soil moisture content under CT plots. Under CT, liming reduced N{sub 2}O emissions by 61% whereas no effect was observed under NT. Under both CT and NT, CH{sub 4} oxidation was enhanced after liming application due to decreased Al{sup 3+} toxicity. Based on our results, NT should be promoted as a means to improve soil physical properties and concurrently reduce N{sub 2}O and CH{sub 4} emissions. Raising the soil pH via liming has positive effects on crop yield; here we show that it may also serve to mitigate CH{sub 4} emissions and, under CT, abate N{sub 2}O emissions. - Highlights: • The effect of tillage and liming on GHG was studied in poorly drained acidic soils. • NT reduced N{sub 2}O emissions, global warming potential and greenhouse gases intensity. • Liming reduced N{sub 2}O and CH{sub 4} emissions under CT; no effect was observed under NT

  11. Implementation of NOx emissions standard in the Gas Transmission Company in the Netherlands

    International Nuclear Information System (INIS)

    Veenstra, T.; Coors, P.; Rosmalen, R.J.

    1992-01-01

    In 1987 and 1990 new NO x emission standards came in force for firing installations (boilers, gas turbines and engines). Gasunie (the gas transportation company in The Netherlands) owns 55 gas turbines and 10 gas engines for the gastransport system, with a total capacity of about 570 MW, installed in 8 compressor stations. Having the most stringent emission levels of Europe (together with Germany) Gasunie reduced the total NO x amount from 3600 tons of NO x in 1987 to 630 tons of NO x in 1990. This reduction was mostly based on our own development of a new precombustion chamber for the lean burn gas engines. Besides that studies and research were carried out for NO x reduction on the gas turbine to meet the current legislation (115 ppm NO x ) and a strategy is made to meet future emission standards. This is necessary because the expected future NO x standards for stand alone gas turbines will be about half of the present standards

  12. Bayesian Learning and the Regulation of Greenhouse Gas Emissions

    OpenAIRE

    Karp, Larry; Zhang, Jiangfeng

    2001-01-01

    We study the importance of anticipated learning - about both environmental damages and abatement costs - in determining the level and the method of controlling greenhouse gas emissions. We also compare active learning, passive learning, and parameter uncertainty without learning. Current beliefs about damages and abatement costs have an important effect on the optimal level of emissions, However, the optimal level of emissions is not sensitive either to the possibility of learning about damag...

  13. Effect of water injection on nitric oxide emissions of a gas turbine combustor burning natural gas fuel

    Science.gov (United States)

    Marchionna, N. R.; Diehl, L. A.; Trout, A. M.

    1973-01-01

    The effect of direct water injection on the exhaust gas emissions of a turbojet combustor burning natural gas fuel was investigated. The results are compared with the results from similar tests using ASTM Jet-A fuel. Increasing water injection decreased the emissions of oxides of nitrogen (NOX) and increased the emissions of carbon monoxide and unburned hydrocarbons. The greatest percentage decrease in NOX with increasing water injection was at the lowest inlet-air temperature tested. The effect of increasing inlet-air temperature was to decrease the effect of the water injection. The reduction in NOX due to water injection was almost identical to the results obtained with Jet-A fuel. However, the emission indices of unburned hydrocarbons, carbon monoxide, and percentage nitric oxide in NOX were not.

  14. Integrated process for synthetic natural gas production from coal and coke-oven gas with high energy efficiency and low emission

    International Nuclear Information System (INIS)

    Man, Yi; Yang, Siyu; Qian, Yu

    2016-01-01

    Highlights: • A novel coal and coke-oven gas to SNG (CGtSNG) process is proposed. • Energy efficiency of CGtSNG increases 8% compared to coal-to-SNG process. • CGtSNG reduces 60% CO_2 emission and 72% effluent discharge. • CGtSNG proposes an idea of using redundant coke-oven gas for producing SNG production. - Abstract: There was a rapid development of coal to synthetic natural gas (SNG) projects in the last few years in China. The research from our previous work and some other researchers have found coal based SNG production process has the problems of environmental pollution and emission transfer, including CO_2 emission, effluent discharge, and high energy consumption. This paper proposes a novel co-feed process of coal and coke-oven gas to SNG process by using a dry methane reforming unit to reduce CO_2 emissions, more hydrogen elements are introduced to improve resource efficiency. It is shown that the energy efficiency of the co-feed process increases by 4%, CO_2 emission and effluent discharge is reduced by 60% and 72%, whereas the production cost decreases by 16.7%, in comparison to the conventional coal to SNG process. As coke-oven gas is a waste gas in most of the coking plant, this process also allows to optimize the allocation of resources.

  15. Laboratory measurements of trace gas emissions from biomass burning of fuel types from the southeastern and southwestern United States

    Science.gov (United States)

    Burling, I. R.; Yokelson, R. J.; Griffith, D. W. T.; Johnson, T. J.; Veres, P.; Roberts, J. M.; Warneke, C.; Urbanski, S. P.; Reardon, J.; Weise, D. R.; Hao, W. M.; de Gouw, J.

    2010-11-01

    Vegetation commonly managed by prescribed burning was collected from five southeastern and southwestern US military bases and burned under controlled conditions at the US Forest Service Fire Sciences Laboratory in Missoula, Montana. The smoke emissions were measured with a large suite of state-of-the-art instrumentation including an open-path Fourier transform infrared (OP-FTIR) spectrometer for measurement of gas-phase species. The OP-FTIR detected and quantified 19 gas-phase species in these fires: CO2, CO, CH4, C2H2, C2H4, C3H6, HCHO, HCOOH, CH3OH, CH3COOH, furan, H2O, NO, NO2, HONO, NH3, HCN, HCl, and SO2. Emission factors for these species are presented for each vegetation type burned. Gas-phase nitrous acid (HONO), an important OH precursor, was detected in the smoke from all fires. The HONO emission factors ranged from 0.15 to 0.60 g kg-1 and were higher for the southeastern fuels. The fire-integrated molar emission ratios of HONO (relative to NOx) ranged from approximately 0.03 to 0.20, with higher values also observed for the southeastern fuels. The majority of non-methane organic compound (NMOC) emissions detected by OP-FTIR were oxygenated volatile organic compounds (OVOCs) with the total identified OVOC emissions constituting 61 ± 12% of the total measured NMOC on a molar basis. These OVOC may undergo photolysis or further oxidation contributing to ozone formation. Elevated amounts of gas-phase HCl and SO2 were also detected during flaming combustion, with the amounts varying greatly depending on location and vegetation type. The fuels with the highest HCl emission factors were all located in the coastal regions, although HCl was also observed from fuels farther inland. Emission factors for HCl were generally higher for the southwestern fuels, particularly those found in the chaparral biome in the coastal regions of California.

  16. Investigating GHGs and VOCs emissions from a shale gas industry in Germany and the UK

    Science.gov (United States)

    Cremonese, L.; Weger, L.; Denier Van Der Gon, H.; Bartels, M. P.; Butler, T. M.

    2017-12-01

    The shale gas and shale oil production boom experienced in the US led the country to a significant reduction of foreign fuel imports and an increase in domestic energy security. Several European countries are considering to extract domestic shale gas reserves that might serve as a bridge in the transition to renewables. Nevertheless, the generation of shale gas leads to emissions of CH4 and pollutants such as PM, NOx and VOCs, which in turn impact local and regional air quality and climate. Results from numerous studies investigating greenhouse gas and pollutant emissions from shale oil and shale gas extraction in North America can help in estimating the impact of such industrial activity elsewhere, when local regulations are taken into consideration. In order to investigate the extent of emissions and their distribution from a potential shale gas industry in Germany and the United Kingdom, we develop three drilling scenarios compatible with desired national gas outputs based on available geological information on potential productivity ranges of the reservoirs. Subsequently we assign activity data and emissions factors to wells under development, as well as to producing wells (from activities at the well site up until processing plants) to enable emissions quantification. We then define emissions scenarios to explore different shale gas development pathways: 1) implementation of "high-technology" devices and recovery practices (low emissions); 2) implementation of "low-technology" devices and recovery practices (high emissions), and 3) intermediate scenarios reflecting assumptions on local and national settings, or extremely high emission events (e.g. super-emitters); all with high and low boundaries of confidence driven by uncertainties. A comparison of these unconventional gas production scenarios to conventional natural gas production in Germany and the United Kingdom is also planned. The aim of this work is to highlight important variables and their ranges, to

  17. Deep greenhouse gas emission reductions in Europe: Exploring different options

    International Nuclear Information System (INIS)

    Deetman, Sebastiaan; Hof, Andries F.; Pfluger, Benjamin; Vuuren, Detlef P. van; Girod, Bastien; Ruijven, Bas J. van

    2013-01-01

    Most modelling studies that explore emission mitigation scenarios only look into least-cost emission pathways, induced by a carbon tax. This means that European policies targeting specific – sometimes relatively costly – technologies, such as electric cars and advanced insulation measures, are usually not evaluated as part of cost-optimal scenarios. This study explores an emission mitigation scenario for Europe up to 2050, taking as a starting point specific emission reduction options instead of a carbon tax. The purpose is to identify the potential of each of these policies and identify trade-offs between sectoral policies in achieving emission reduction targets. The reduction options evaluated in this paper together lead to a reduction of 65% of 1990 CO 2 -equivalent emissions by 2050. More bottom-up modelling exercises, like the one presented here, provide a promising starting point to evaluate policy options that are currently considered by policy makers. - Highlights: ► We model the effects of 15 climate change mitigation measures in Europe. ► We assess the greenhouse gas emission reduction potential in different sectors. ► The measures could reduce greenhouse gas emissions by 60% below 1990 levels in 2050. ► The approach allows to explore arguably more relevant climate policy scenarios

  18. Reduction of NOx emissions when burning low heating value gas

    International Nuclear Information System (INIS)

    Gustafsson, R.; Oskarsson, J.; Waldheim, L.

    1993-09-01

    On the gasification of nitrogen-rich fuel the nitrogen from the fuel goes into the gas phase in the form of ammonia and hydrogen cyanide and also nitrogen containing tars. When the gas is combusted the nitrogen compounds are oxidized to a great extent to NO x and, therefore, high NO x emissions can be found on the combustion of low heating value gas produced from energy forest wood chips as is also the case with direct combustion of nitrogen rich fuels. An experimental study has been carried out where the important parameters for designing a combustion chamber for low heating value gases have been studied in order to obtain maximum reduction of NO x emissions. The effect of tar cracking using dolomite on these emissions and the effect of parameters such as the addition of steam has also been tested. The tests were carried out with energy forest wood chips with 0.3% nitrogen. The gasification was carried out in a pyrolysis reactor, operated to yield a low heating value gas, and which was coupled to a simplified gas turbine combustion chamber at atmospheric pressure. The results show that the main part of the nitrogen in the fuel is found as ammonia in the low heating value gas. With this type of gasification the conversion of fuel nitrogen to ammonia in the gas is equivalent to 500-600 mg/MJ, calculated as NO 2 . Only very low amounts of hydrogen cyanide have been noted and no nitrogen containing tar components have been found. No apparent effect of steam additions has been noted. On the other hand the distribution of air in the combustion chamber and residence time during the under stoichiometric conditions are of great importance for the NO x reduction. Depending on the air distribution the emissions of NO 2 varied between 100 and 250 mg/MJ, calculated as NO 2 . 23 refs, 11 figs, 2 tabs

  19. Assessment of Methane Emissions – Impact of Using Natural Gas Engines in Unconventional Resource Development

    Energy Technology Data Exchange (ETDEWEB)

    Nix, Andrew [West Virginia Univ., Morgantown, WV (United States); Johnson, Derek [West Virginia Univ., Morgantown, WV (United States); Heltzel, Robert [West Virginia Univ., Morgantown, WV (United States); Oliver, Dakota [West Virginia Univ., Morgantown, WV (United States)

    2018-04-08

    Researchers at the Center for Alternative Fuels, Engines, and Emissions (CAFEE) completed a multi-year program under DE-FE0013689 entitled, “Assessing Fugitive Methane Emissions Impact Using Natural Gas Engines in Unconventional Resource Development.” When drilling activity was high and industry sought to lower operating costs and reduce emissions they began investing in dual fuel and dedicated natural gas engines to power unconventional well equipment. From a review of literature we determined that the prime-movers (or major fuel consumers) of unconventional well development were the service trucks (trucking), horizontal drilling rig (drilling) engines, and hydraulic stimulation pump (fracturing) engines. Based on early findings from on-road studies we assessed that conversion of prime movers to operate on natural gas could contribute to methane emissions associated with unconventional wells. As such, we collected significant in-use activity data from service trucks and in-use activity, fuel consumption, and gaseous emissions data from drilling and fracturing engines. Our findings confirmed that conversion of the prime movers to operate as dual fuel or dedicated natural gas – created an additional source of methane emissions. While some gaseous emissions were decreased from implementation of these technologies – methane and CO2 equivalent emissions tended to increase, especially for non-road engines. The increases were highest for dual fuel engines due to methane slip from the exhaust and engine crankcase. Dedicated natural gas engines tended to have lower exhaust methane emissions but higher CO2 emissions due to lower efficiency. Therefore, investing in currently available natural gas technologies for prime movers will increase the greenhouse gas footprint of the unconventional well development industry.

  20. Data for generation of all Tables and Figures for AIMS-ES publication in 2016 pertaining to dry sorbent injection of trona for acid gas control

    Data.gov (United States)

    U.S. Environmental Protection Agency — emissions data and removal efficiencies for coal combustion utilizing PM control devices and dry sorbent injection of trona specifically for acid gas control. This...

  1. Influence of the gas mixture radio on the correlations between the excimer XeCl emission and the sealed gas temperature in dielectric barrier discharge lamps

    CERN Document Server

    Xu Jin Zhou; Ren Zhao Xing

    2002-01-01

    For dielectric barrier discharge lamps filled with various gas mixture ratios, the correlations between the excimer XeCl emission and the sealed gas temperature have been founded, and a qualitative explication is presented. For gas mixture with chlorine larger than 3%, the emission intensity increases with the sealed gas temperature, while with chlorine about 2%, the emission intensity decreases with the increasing in the gas temperature, and could be improved by cooling water. However, if chlorine is less than 1.5%, the discharge appears to be a mixture mode with filaments distributed in a diffused glow-like discharge, and the UV emission is independent on the gas temperature

  2. Dioxin and furan emissions from landfill gas-fired combustion units

    International Nuclear Information System (INIS)

    Caponi, F.R.; Wheless, E.; Frediani, D.

    1998-01-01

    The 1990 Federal Clean Air Act Amendments require the development of maximum achievable control technology standards (MACT) for sources of hazardous air pollutants, including landfill gas-fired combustion sources. The Industrial Combustion Coordinated Rulemaking (ICCR) Federal Advisory Committee is a group of stakeholders from the public and private sector whose charge is to develop recommendations for a unified set of federal toxic air emissions regulations. Specifically, the group will establish MACT standards for industrial-commercial-institutional combustion sources. The ICCR proceedings have given rise to considerable interest in potential dioxin and furan emissions from landfill gas-fired combustion units. In order to establish the potential of dioxin and furan emissions from this group of combustion sources, a world-wide literature search was conducted. A total of 22 references were evaluated. The references covered a wide range of test programs, testing methodologies and combustion equipment type. The most abundant data were for landfill gas-fired flares (shrouded and afterburners) and I.C. engines. Because of limitations in obtaining actual test reports with complete lab data and QA/QC results, and a lack of knowledge as to the exact types of waste received at the European landfills, the test data from these sources, for the purposes of this paper, are considered qualitative. The conclusion reached from review of the test data is that there is a potential for dioxin and furan emissions from landfill gas-fired combustion units, but at very low levels for well operated systems

  3. The marginal costs of greenhouse gas emissions

    International Nuclear Information System (INIS)

    Tol, R.S.J.

    1999-01-01

    Estimates of the marginal costs of greenhouse gas emissions are on important input to the decision how much society would want to spend on greenhouse gas emission reduction. Marginal cost estimates in the literature range between $5 and $25 per ton of carbon. Using similar assumptions, the FUND model finds marginal costs of $9--23/tC, depending on the discount rate. If the aggregation of impacts over countries accounts for inequalities in income distribution or for risk aversion, marginal costs would rise by about a factor of 3. Marginal costs per region are an order of magnitude smaller than global marginal costs. The ratios between the marginal costs of CO 2 and those of CH 4 and N 2 O are roughly equal to the global warming potentials of these gases. The uncertainty about the marginal costs is large and right-skewed. The expected value of the marginal costs lies about 35% above the best guess, the 95-percentile about 250%

  4. Possibilities of using ISO 1406X standards in the management of greenhouse gas emissions

    International Nuclear Information System (INIS)

    Fabian, G.; Priesol, J.

    2009-01-01

    Aim of this paper is to define and describe using of ISO 1406X standards for organization, which production of greenhouse gas emissions represents an important environmental aspect especially in terms of financial benefits accruing from trading with saved / reduced emissions. Following the main aim of this paper, we have set the following sub-objectives and tasks: - Define and describe the algorithm of implementation of program on greenhouse gas emissions according to the requirements and guidelines of the ISO 1406X in the organization; - Create a model of comprehensive management of greenhouse gas emissions standards as described.

  5. Need for a marginal methodology in assessing natural gas system methane emissions in response to incremental consumption.

    Science.gov (United States)

    Mac Kinnon, Michael; Heydarzadeh, Zahra; Doan, Quy; Ngo, Cuong; Reed, Jeff; Brouwer, Jacob

    2018-05-17

    Accurate quantification of methane emissions from the natural gas system is important for establishing greenhouse gas inventories and understanding cause and effect for reducing emissions. Current carbon intensity methods generally assume methane emissions are proportional to gas throughput so that increases in gas consumption yield linear increases in emitted methane. However, emissions sources are diverse and many are not proportional to throughput. Insights into the causal drivers of system methane emissions, and how system-wide changes affect such drivers are required. The development of a novel cause-based methodology to assess marginal methane emissions per unit of fuel consumed is introduced. The carbon intensities of technologies consuming natural gas are critical metrics currently used in policy decisions for reaching environmental goals. For example, the low-carbon fuel standard in California uses carbon intensity to determine incentives provided. Current methods generally assume methane emissions from the natural gas system are completely proportional to throughput. The proposed cause-based marginal emissions method will provide a better understanding of the actual drivers of emissions to support development of more effective mitigation measures. Additionally, increasing the accuracy of carbon intensity calculations supports the development of policies that can maximize the environmental benefits of alternative fuels, including reducing greenhouse gas emissions.

  6. Greenhouse gas emissions in milk and dairy product chains

    DEFF Research Database (Denmark)

    Flysjö, Anna Maria

    Reducing greenhouse gas emissions from dairy products is one important step towards a more sustainable dairy sector. To ensure effective mitigation, reliable assessment methods are required. The present PhD thesis focuses on some of the most critical methodological aspects influencing the carbon ...... throughout the value chain – from cow to consumer.......Reducing greenhouse gas emissions from dairy products is one important step towards a more sustainable dairy sector. To ensure effective mitigation, reliable assessment methods are required. The present PhD thesis focuses on some of the most critical methodological aspects influencing the carbon...... footprint (CF) of milk and dairy products, namely; estimating CH4 and N2O emissions; accounting for land use change; co-product handling; and defining the functional unit. In addition, the CF is calculated for different types of dairy products, and suggestions on various mitigation measures are presented...

  7. Quantifying the relative contribution of natural gas fugitive emissions to total methane emissions in Weld County Colorado using δ13CH4 analysis

    Science.gov (United States)

    Rella, C.; Jacobson, G. A.; Crosson, E.; Sweeney, C.; Karion, A.; Petron, G.

    2012-12-01

    Fugitive emissions of methane into the atmosphere are a major concern facing the natural gas production industry. Given that the global warming potential of methane is many times greater than that of carbon dioxide (Forster et al. 2007), the importance of quantifying methane emissions becomes clear. Companion presentations at this meeting describe efforts to quantify the overall methane emissions in two separate gas producing areas in Colorado and Utah during intensive field campaigns undertaken in 2012. A key step in the process of assessing the emissions arising from natural gas production activities is partitioning the observed methane emissions between natural gas fugitive emissions and other sources of methane, such as from landfills or agricultural activities. One method for assessing the contribution of these different sources is stable isotope analysis. In particular, the δ13CH4 signature of natural gas (-37 permil) is significantly different that the signature of other significant sources of methane, such as landfills or ruminants (-50 to -70 permil). In this paper we present measurements of δ13CH4 in Colorado in Weld County, a region of intense natural gas production, using a mobile δ13CH4¬ analyzer capable of high-precision measurements of the stable isotope ratio of methane at ambient levels. This analyzer was used to make stable isotope measurements at a fixed location near the center of the gas producing region, from which an overall isotope ratio for the regional emissions is determined. In addition, mobile measurements in the nocturnal boundary layer have been made, over a total distance of 150 km throughout Weld County, allowing spatially resolved measurements of this isotope signature. Finally, this analyzer was used to quantify the isotopic signature of those individual sources (natural gas fugitive emissions, concentrated animal feeding operations, and landfills) that constitute the majority of methane emissions in this region, by making

  8. Invasive floating macrophytes reduce greenhouse gas emissions from a small tropical lake.

    Science.gov (United States)

    Attermeyer, K; Flury, S; Jayakumar, R; Fiener, P; Steger, K; Arya, V; Wilken, F; van Geldern, R; Premke, K

    2016-02-05

    Floating macrophytes, including water hyacinth (Eichhornia crassipes), are dominant invasive organisms in tropical aquatic systems, and they may play an important role in modifying the gas exchange between water and the atmosphere. However, these systems are underrepresented in global datasets of greenhouse gas (GHG) emissions. This study investigated the carbon (C) turnover and GHG emissions from a small (0.6 km(2)) water-harvesting lake in South India and analysed the effect of floating macrophytes on these emissions. We measured carbon dioxide (CO2) and methane (CH4) emissions with gas chambers in the field as well as water C mineralization rates and physicochemical variables in both the open water and in water within stands of water hyacinths. The CO2 and CH4 emissions from areas covered by water hyacinths were reduced by 57% compared with that of open water. However, the C mineralization rates were not significantly different in the water between the two areas. We conclude that the increased invasion of water hyacinths and other floating macrophytes has the potential to change GHG emissions, a process that might be relevant in regional C budgets.

  9. Invasive floating macrophytes reduce greenhouse gas emissions from a small tropical lake

    Science.gov (United States)

    Attermeyer, K.; Flury, S.; Jayakumar, R.; Fiener, P.; Steger, K.; Arya, V.; Wilken, F.; van Geldern, R.; Premke, K.

    2016-02-01

    Floating macrophytes, including water hyacinth (Eichhornia crassipes), are dominant invasive organisms in tropical aquatic systems, and they may play an important role in modifying the gas exchange between water and the atmosphere. However, these systems are underrepresented in global datasets of greenhouse gas (GHG) emissions. This study investigated the carbon (C) turnover and GHG emissions from a small (0.6 km2) water-harvesting lake in South India and analysed the effect of floating macrophytes on these emissions. We measured carbon dioxide (CO2) and methane (CH4) emissions with gas chambers in the field as well as water C mineralization rates and physicochemical variables in both the open water and in water within stands of water hyacinths. The CO2 and CH4 emissions from areas covered by water hyacinths were reduced by 57% compared with that of open water. However, the C mineralization rates were not significantly different in the water between the two areas. We conclude that the increased invasion of water hyacinths and other floating macrophytes has the potential to change GHG emissions, a process that might be relevant in regional C budgets.

  10. Sectoral roles in greenhouse gas emissions and policy implications for energy utilization and carbon emissions trading: a case study of Beijing, China.

    Science.gov (United States)

    Ge, Jianping; Lei, Yalin; Xu, Qun; Wang, Xibo

    2016-01-01

    In this study, a decomposition and emissions matrix is developed to identify the roles (giver or taker) played by the sectors in the greenhouse gas emissions for the economy of Beijing in China. Our results indicate that services were the most important emitter if we consider the total (direct and indirect) emissions. In addition to Construction, Scientific studies and technical services and Finance sectors of services were the largest takers. They have a large role in boosting greenhouse gas emissions throughout the economy of Beijing. As the basis and supporter of production activities, the electricity production and the transportation sectors were the greatest givers. More emphasis should be placed on using clean energy and carbon capture and storage technologies to reduce emissions within these sectors. Based on the roles played by these sectors in greenhouse gas emissions, some policy implications were proposed for energy utilization and carbon emissions trading.

  11. Multi-sectorial convergence in greenhouse gas emissions.

    Science.gov (United States)

    Oliveira, Guilherme de; Bourscheidt, Deise Maria

    2017-07-01

    This paper uses the World Input-Output Database (WIOD) to test the hypothesis of per capita convergence in greenhouse gas (GHG) emissions for a multi-sectorial panel of countries. The empirical strategy applies conventional estimators of random and fixed effects and Arellano and Bond's (1991) GMM to the main pollutants related to the greenhouse effect. For reasonable empirical specifications, the model revealed robust evidence of per capita convergence in CH 4 emissions in the agriculture, food, and services sectors. The evidence of convergence in CO 2 emissions was moderate in the following sectors: agriculture, food, non-durable goods manufacturing, and services. In all cases, the time for convergence was less than 15 years. Regarding emissions by energy use, the largest source of global warming, there was only moderate evidence in the extractive industry sector-all other pollutants presented little or no evidence. Copyright © 2017 Elsevier Ltd. All rights reserved.

  12. Greenhouse Gas Emissions in the Netherlands 1990-2007. National Inventory Report 2009

    International Nuclear Information System (INIS)

    Van der Maas, C.W.M.; Brandes, L.J.; Baas, K.; Van den Born, G.J.; Geilenkirchen, G.; Te Molder, R.; Nijdam, D.S.; Olivier, J.G.J.; Peek, C.J.; Van Schijndel, M.W.; Van der Sluis, S.M.; Coenen, P.W.H.G; Zijlema, P.J.; Van den Berghe, G.; Guis, B.

    2009-04-01

    This report documents the 2009 Netherlands annual submission of its greenhouse gas emission inventory in accordance with the guidelines provided by the United Nations Framework Convention on Climate Change (UNFCCC), the Kyoto Protocol and the European Union's Greenhouse Gas Monitoring Mechanism. The report comprises explanations of observed trends in emissions; a description of an assessment of key sources and their uncertainty; documentation of methods, data sources and emission factors applied; and a description of the quality assurance system and the verification activities performed on the data

  13. 76 FR 57105 - Greenhouse Gas Emissions Standards and Fuel Efficiency Standards for Medium- and Heavy-Duty...

    Science.gov (United States)

    2011-09-15

    ... CFR Parts 523, 534, and 535 Greenhouse Gas Emissions Standards and Fuel Efficiency Standards for...-2010-0079; FRL-9455-1] RIN 2060-AP61; 2127-AK74 Greenhouse Gas Emissions Standards and Fuel Efficiency... Heavy-Duty National Program that will reduce greenhouse gas emissions and fuel consumption for on-road...

  14. 75 FR 81952 - Greenhouse Gas Emissions Standards and Fuel Efficiency Standards for Medium- and Heavy-Duty...

    Science.gov (United States)

    2010-12-29

    ...-HQ-OAR-2010-0162; FRL-9219-4; NHTSA 2010-0079] RIN 2060-AP61; RIN 2127-AK74 Greenhouse Gas Emissions... will increase fuel efficiency and reduce greenhouse gas emissions for on-road heavy-duty vehicles...-Duty National Program that will increase fuel efficiency and reduce greenhouse gas emissions for on...

  15. CO2 emissions, natural gas and renewables, economic growth: Assessing the evidence from China.

    Science.gov (United States)

    Dong, Kangyin; Sun, Renjin; Dong, Xiucheng

    2018-05-31

    This study aims to test the environmental Kuznets curve (EKC) for carbon dioxide (CO 2 ) emissions in China by developing a new framework based on the suggestion of Narayan and Narayan (2010). The dynamic effect of natural gas and renewable energy consumption on CO 2 emissions is also analyzed. Considering the structural break observed in the sample, a series of econometric techniques allowing for structural breaks is utilized for the period 1965-2016. The empirical results confirm the existence of the EKC for CO 2 emissions in China. Furthermore, in both the long-run and the short-run, the beneficial effects of natural gas and renewables on CO 2 emission reduction are observable. In addition, the mitigation effect of natural gas on CO 2 emissions will be weakened over time, while renewables will become progressively more important. Finally, policy suggestions are highlighted not only for mitigating CO 2 emissions, but also for promoting growth in the natural gas and renewable energy industries. Copyright © 2018 Elsevier B.V. All rights reserved.

  16. Greenhouse gas emissions from on-site wastewater treatment systems

    Science.gov (United States)

    Somlai-Haase, Celia; Knappe, Jan; Gill, Laurence

    2016-04-01

    Nearly one third of the Irish population relies on decentralized domestic wastewater treatment systems which involve the discharge of effluent into the soil via a percolation area (drain field). In such systems, wastewater from single households is initially treated on-site either by a septic tank and an additional packaged secondary treatment unit, in which the influent organic matter is converted into carbon dioxide (CO2) and methane (CH4) by microbial mediated processes. The effluent from the tanks is released into the soil for further treatment in the unsaturated zone where additional CO2 and CH4 are emitted to the atmosphere as well as nitrous oxide (N2O) from the partial denitrification of nitrate. Hence, considering the large number of on-site systems in Ireland and internationally, these are potential significant sources of greenhouse gas (GHG) emissions, and yet have received almost no direct field measurement. Here we present the first attempt to quantify and qualify the production and emissions of GHGs from a septic tank system serving a single house in the County Westmeath, Ireland. We have sampled the water for dissolved CO2, CH4 and N2O and measured the gas flux from the water surface in the septic tank. We have also carried out long-term flux measurements of CO2 from the drain field, using an automated soil gas flux system (LI-8100A, Li-Cor®) covering a whole year semi-continuously. This has enabled the CO2 emissions from the unsaturated zone to be correlated against different meteorological parameters over an annual cycle. In addition, we have integrated an ultraportable GHG analyser (UGGA, Los Gatos Research Inc.) into the automated soil gas flux system to measure CH4 flux. Further, manual sampling has also provided a better understanding of N2O emissions from the septic tank system.

  17. Emissions of CH4 from natural gas production in the United States using aircraft-based observations

    Science.gov (United States)

    Sweeney, Colm; Karion, Anna; Petron, Gabrielle; Ryerson, Thomas; Peischl, Jeff; Trainer, Michael; Rella, Chris; Hardesty, Michael; Crosson, Eric; Montzka, Stephen; Tans, Pieter; Shepson, Paul; Kort, Eric

    2014-05-01

    New extraction technologies are making natural gas from shale and tight sand gas reservoirs in the United States (US) more accessible. As a result, the US has become the largest producer of natural gas in the world. This growth in natural gas production may result in increased leakage of methane, a potent greenhouse gas, offsetting the climate benefits of natural gas relative to other fossil fuels. Methane emissions from natural gas production are not well quantified because of the large variety of potential sources, the variability in production and operating practices, the uneven distribution of emitters, and a lack of verification of emission inventories with direct atmospheric measurements. Researchers at the NOAA Earth System Research Laboratory (ESRL) have used simple mass balance approaches in combination with isotopes and light alkanes to estimate emissions of CH4 from several natural gas and oil plays across the US. We will summarize the results of the available aircraft and ground-based atmospheric emissions estimates to better understand the spatial and temporal distribution of these emissions in the US.

  18. Potential for greenhouse gas emission reductions using surplus electricity in hydrogen, methane and methanol production via electrolysis

    International Nuclear Information System (INIS)

    Uusitalo, Ville; Väisänen, Sanni; Inkeri, Eero; Soukka, Risto

    2017-01-01

    Highlights: • Greenhouse gas emission reductions using power-to-x processes are studied using life cycle assessment. • Surplus electricity use led to greenhouse gas emission reductions in all studied cases. • Highest reductions can be achieved by using hydrogen to replace fossil based hydrogen. • High reductions are also achieved when fossil transportation fuels are replaced. - Abstract: Using a life cycle perspective, potentials for greenhouse gas emission reductions using various power-to-x processes via electrolysis have been compared. Because of increasing renewable electricity production, occasionally surplus renewable electricity is produced, which leads to situations where the price of electricity approach zero. This surplus electricity can be used in hydrogen, methane and methanol production via electrolysis and other additional processes. Life cycle assessments have been utilized to compare these options in terms of greenhouse gas emission reductions. All of the power-to-x options studied lead to greenhouse gas emission reductions as compared to conventional production processes based on fossil fuels. The highest greenhouse gas emission reductions can be gained when hydrogen from steam reforming is replaced by hydrogen from the power-to-x process. High greenhouse gas emission reductions can also be achieved when power-to-x products are utilized as an energy source for transportation, replacing fossil transportation fuels. A third option with high greenhouse gas emission reduction potential is methane production, storing and electricity conversion in gas engines during peak consumption hours. It is concluded that the power-to-x processes provide a good potential solution for reducing greenhouse gas emissions in various sectors.

  19. Estimating Greenhouse Gas Emissions Level of A Natural Gas Pipeline – Case Study from A to B Point in West Java-Indonesia

    Directory of Open Access Journals (Sweden)

    Dianita Cindy

    2016-01-01

    Full Text Available Indonesia is one of the highest greenhouse emitters in the world. As a response of this problem, Indonesia declared the national action plan to focus on national greenhouse gas (GHG reduction by 26 % by 2020. To achieve this target, Government puts energy sector as one of the top priorities since it is the second strongest contributor to national GHG emissions. The main purpose of this paper is to apply the method of fugitive emissions calculation to the existing natural gas pipeline in Indonesia. Fugitive emissions are the major component of GHG emissions from natural gas systems and methane (CH4, the primary component of natural gas pipeline, is a potent GHG. Tiered approaches from Interstate Natural Gas Association of America (INGAA are implemented in this paper as the estimation guidelines. A case study of a natural gas pipeline system in Indonesia is analyzed to compare the GHG emissions level resulted from Tier 1 and Tier 2 methods. In these methods, the input data are pipeline length, the number of compressor stations, and the number of meter and pressure regulation stations. In this case, the GHG emissions level of Tier 2 is significantly different from Tier 1. The variation of pipeline length shows that for the length under 479.2 miles, Tier 1 gives lower amount of CO2 equivalent than Tier 2. The differences of these estimation methods and results can be furtherly developed to provide relevant information and recommendation for the Companies and Government to record the emissions level from natural gas transmission pipeline according to their needs and purposes.

  20. Quantifying greenhouse gas emissions from municipal solid waste dumpsites in Cameroon.

    Science.gov (United States)

    Ngwabie, N Martin; Wirlen, Yvette L; Yinda, Godwin S; VanderZaag, Andrew C

    2018-03-02

    Open dumpsites that receive municipal solid waste are potentially significant sources of greenhouse gas (GHG) emissions into the atmosphere. There is little data available on emissions from these sources, especially in the unique climate and management of central Africa. This research aimed at quantifying CH 4 , N 2 O and CO 2 emissions from two open dumpsites in Cameroon, located in Mussaka-Buea, regional headquarters of the South West Region and in Mbellewa-Bamenda, regional headquarters of the North West Region. Emissions were measured during the wet season (May 2015 and August 2016) at the Mussaka and Mbellewa dumpsites respectively. Dumpsite surfaces were partitioned into several zones for emission measurements, based on the current activity and the age of the waste. Static flux chambers were used to quantify gas emission rates thrice a day (mornings, afternoons and evenings). Average emissions were 96.80 ± 144 mg CH 4 m -2  min -1 , 0.20 ± 0.43 mg N 2 O m -2  min -1 and 224.78 ± 312 mg CO 2 m -2  min -1 in the Mussaka dumpsite, and 213.44 ± 419 mg CH 4 m -2  min -1 , 0.15 ± 0.15 mg N 2 O m -2  min -1 and 1103.82 ± 1194 mg CO 2 m -2  min -1 at the Mbellewa dumpsite. Emissions as high as 1784 mg CH 4 m -2  min -1 , 2.3 mg N 2 O m -2  min -1 and 5448 mg CO 2 m -2  min -1 were measured from both dumpsites. Huge variations observed in emissions between the different zones on the waste surface were likely a result of the heterogeneous nature of the waste, different stages in waste decomposition and different environmental conditions within the waste. Management activities that disturb waste, such as spreading and compressing potentially increase gas emissions, while covering waste with a layer of soil potentially mitigate gas emissions. Recommendations were for dumpsites to be upgraded to sanitary landfills, and biogas production from such landfills should be exploited to reduce CH 4 emissions

  1. The Genealogical Tree of Ethanol: Gas-phase Formation of Glycolaldehyde, Acetic Acid, and Formic Acid

    Science.gov (United States)

    Skouteris, Dimitrios; Balucani, Nadia; Ceccarelli, Cecilia; Vazart, Fanny; Puzzarini, Cristina; Barone, Vincenzo; Codella, Claudio; Lefloch, Bertrand

    2018-02-01

    Despite the harsh conditions of the interstellar medium, chemistry thrives in it, especially in star-forming regions where several interstellar complex organic molecules (iCOMs) have been detected. Yet, how these species are synthesized is a mystery. The majority of current models claim that this happens on interstellar grain surfaces. Nevertheless, evidence is mounting that neutral gas-phase chemistry plays an important role. In this paper, we propose a new scheme for the gas-phase synthesis of glycolaldehyde, a species with a prebiotic potential and for which no gas-phase formation route was previously known. In the proposed scheme, the ancestor is ethanol and the glycolaldehyde sister species are acetic acid (another iCOM with unknown gas-phase formation routes) and formic acid. For the reactions of the new scheme with no available data, we have performed electronic structure and kinetics calculations deriving rate coefficients and branching ratios. Furthermore, after a careful review of the chemistry literature, we revised the available chemical networks, adding and correcting several reactions related to glycolaldehyde, acetic acid, and formic acid. The new chemical network has been used in an astrochemical model to predict the abundance of glycolaldehyde, acetic acid, and formic acid. The predicted abundance of glycolaldehyde depends on the ethanol abundance in the gas phase and is in excellent agreement with the measured one in hot corinos and shock sites. Our new model overpredicts the abundance of acetic acid and formic acid by about a factor of 10, which might imply a yet incomplete reaction network.

  2. Life cycle greenhouse gas emissions of anesthetic drugs.

    Science.gov (United States)

    Sherman, Jodi; Le, Cathy; Lamers, Vanessa; Eckelman, Matthew

    2012-05-01

    Anesthesiologists must consider the entire life cycle of drugs in order to include environmental impacts into clinical decisions. In the present study we used life cycle assessment to examine the climate change impacts of 5 anesthetic drugs: sevoflurane, desflurane, isoflurane, nitrous oxide, and propofol. A full cradle-to-grave approach was used, encompassing resource extraction, drug manufacturing, transport to health care facilities, drug delivery to the patient, and disposal or emission to the environment. At each stage of the life cycle, energy, material inputs, and emissions were considered, as well as use-specific impacts of each drug. The 4 inhalation anesthetics are greenhouse gases (GHGs), and so life cycle GHG emissions include waste anesthetic gases vented to the atmosphere and emissions (largely carbon dioxide) that arise from other life cycle stages. Desflurane accounts for the largest life cycle GHG impact among the anesthetic drugs considered here: 15 times that of isoflurane and 20 times that of sevoflurane on a per MAC-hour basis when administered in an O(2)/air admixture. GHG emissions increase significantly for all drugs when administered in an N(2)O/O(2) admixture. For all of the inhalation anesthetics, GHG impacts are dominated by uncontrolled emissions of waste anesthetic gases. GHG impacts of propofol are comparatively quite small, nearly 4 orders of magnitude lower than those of desflurane or nitrous oxide. Unlike the inhaled drugs, the GHG impacts of propofol primarily stem from the electricity required for the syringe pump and not from drug production or direct release to the environment. Our results reiterate previous published data on the GHG effects of these inhaled drugs, while providing a life cycle context. There are several practical environmental impact mitigation strategies. Desflurane and nitrous oxide should be restricted to cases where they may reduce morbidity and mortality over alternative drugs. Clinicians should avoid

  3. Decarbonising meat : Exploring greenhouse gas emissions in the meat sector

    NARCIS (Netherlands)

    Aan Den Toorn, S. I.; Van Den Broek, M. A.; Worrell, E.

    Consumption of meat is an important source of global greenhouse gas (GHG) emission and deep decarbonisation of the whole meat production chain is required to be able to meet global climate change (CC) mitigation goals. Emissions happen in different stages of meat production ranging from agricultural

  4. Greenhouse gas emissions from aviation and marine transportation : mitigation potential and policies

    Science.gov (United States)

    2009-12-01

    This paper provides an overview of greenhouse gas (GHG) emissions : from aviation and marine transportation and the various mitigation options to reduce these emissions. Reducing global emissions by 50 to 80 percent below 1990 levels by 2050reduct...

  5. Decoupling of greenhouse gas emissions from global agricultural production

    DEFF Research Database (Denmark)

    Bennetzen, Eskild Hohlmann; Smith, Pete; Porter, John Roy

    2016-01-01

    Since 1970 global agricultural production has more than doubled; contributing ~1/4 of total anthropogenic greenhouse gas (GHG) burden in 2010. Food production must increase to feed our growing demands, but to address climate change, GHG emissions must decrease. Using an identity approach, we...... estimate and analyse past trends in GHG emission intensities from global agricultural production and land-use change and project potential future emissions. The novel Kaya-Porter identity framework deconstructs the entity of emissions from a mix of multiple sources of GHGs into attributable elements...... to increase food security whilst reducing emissions. The identity approach presented here could be used as a methodological framework for more holistic food systems analysis....

  6. Accounting for time-dependent effects in biofuel life cycle greenhouse gas emissions calculations.

    Science.gov (United States)

    Kendall, Alissa; Chang, Brenda; Sharpe, Benjamin

    2009-09-15

    This paper proposes a time correction factor (TCF) to properly account for the timing of land use change-derived greenhouse gas emissions in the biofuels life cycle. Land use change emissions occur at the outset of biofuel feedstock production, and are typically amortized over an assumed time horizon to assign the burdens of land use change to multiple generations of feedstock crops. Greenhouse gas intensity calculations amortize emissions by dividing them equally over a time horizon, overlooking the fact that the effect of a greenhouse gas increases with the time it remains in the atmosphere. The TCF is calculated based on the relative climate change effect of an emission occurring at the outset of biofuel feedstock cultivation versus one amortized over a time horizon. For time horizons between 10 and 50 years, the TCF varies between 1.7 and 1.8 for carbon dioxide emissions, indicating that the actual climate change effect of an emission is 70-80% higher than the effect of its amortized values. The TCF has broad relevance for correcting the treatment of emissions timing in other life cycle assessment applications, such as emissions from capital investments for production systems or manufacturing emissions for renewable energy technologies.

  7. Monitoring soil greenhouse gas emissions from managed grasslands

    Science.gov (United States)

    Díaz-Pinés, Eugenio; Lu, Haiyan; Butterbach-Bahl, Klaus; Kiese, Ralf

    2014-05-01

    Grasslands in Central Europe are of enormous social, ecological and economical importance. They are intensively managed, but the influence of different common practices (i.e. fertilization, harvesting) on the total greenhouse gas budget of grasslands is not fully understood, yet. In addition, it is unknown how these ecosystems will react due to climate change. Increasing temperatures and changing precipitation will likely have an effect on productivity of grasslands and on bio-geo-chemical processes responsible for emissions of carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O). In the frame of the TERENO Project (www.tereno.net), a long-term observatory has been implemented in the Ammer catchment, southern Germany. Acting as an in situ global change experiment, 36 big lysimeters (1 m2 section, 150 cm height) have been translocated along an altitudinal gradient, including three sites ranging from 600 to 860 meters above sea level. In addition, two treatments have been considered, corresponding to different management intensities. The overall aim of the pre-alpine TERENO observatory is improving our understanding of the consequences of climate change and management on productivity, greenhouse gas balance, soil nutritional status, nutrient leaching and hydrology of grasslands. Two of the sites are equipped with a fully automated measurement system in order to continuously and accurately monitor the soil-atmosphere greenhouse gas exchange. Thus, a stainless steel chamber (1 m2 section, 80 cm height) is controlled by a robotized system. The chamber is hanging on a metal structure which can move both vertically and horizontally, so that the chamber is able to be set onto each of the lysimeters placed on the field. Furthermore, the headspace of the chamber is connected with a gas tube to a Quantum Cascade Laser, which continuously measures CO2, CH4, N2O and H2O mixing ratios. The chamber acts as a static chamber and sets for 15 minutes onto each lysimeter

  8. Evaluating measurements of carbon dioxide emissions using a precision source--A natural gas burner.

    Science.gov (United States)

    Bryant, Rodney; Bundy, Matthew; Zong, Ruowen

    2015-07-01

    A natural gas burner has been used as a precise and accurate source for generating large quantities of carbon dioxide (CO2) to evaluate emissions measurements at near-industrial scale. Two methods for determining carbon dioxide emissions from stationary sources are considered here: predicting emissions based on fuel consumption measurements-predicted emissions measurements, and direct measurement of emissions quantities in the flue gas-direct emissions measurements. Uncertainty for the predicted emissions measurement was estimated at less than 1%. Uncertainty estimates for the direct emissions measurement of carbon dioxide were on the order of ±4%. The relative difference between the direct emissions measurements and the predicted emissions measurements was within the range of the measurement uncertainty, therefore demonstrating good agreement. The study demonstrates how independent methods are used to validate source emissions measurements, while also demonstrating how a fire research facility can be used as a precision test-bed to evaluate and improve carbon dioxide emissions measurements from stationary sources. Fossil-fuel-consuming stationary sources such as electric power plants and industrial facilities account for more than half of the CO2 emissions in the United States. Therefore, accurate emissions measurements from these sources are critical for evaluating efforts to reduce greenhouse gas emissions. This study demonstrates how a surrogate for a stationary source, a fire research facility, can be used to evaluate the accuracy of measurements of CO2 emissions.

  9. Historical and future emission of hazardous air pollutants (HAPs) from gas-fired combustion in Beijing, China.

    Science.gov (United States)

    Xue, Yifeng; Nie, Lei; Zhou, Zhen; Tian, Hezhong; Yan, Jing; Wu, Xiaoqing; Cheng, Linglong

    2017-07-01

    The consumption of natural gas in Beijing has increased in the past decade due to energy structure adjustments and air pollution abatement. In this study, an integrated emission inventory of hazardous air pollutants (HAPs) emitted from gas-fired combustion in Beijing was developed for the period from 2000 to 2014 using a technology-based approach. Future emission trends were projected through 2030 based on current energy-related and emission control policies. We found that emissions of primary HAPs exhibited an increasing trend with the rapid increase in natural gas consumption. Our estimates indicated that the total emissions of NO X , particulate matter (PM) 10 , PM 2.5 , CO, VOCs, SO 2 , black carbon, Pb, Cd, Hg, As, Cr, Cu, Ni, Zn, polychlorinated dibenzo-p-dioxins and dibenzofurans, and benzo[a]pyrene from gas-fired combustion in Beijing were approximately 22,422 t, 1042 t, 781 t, 19,097 t, 653 t, 82 t, 19 t, 0.6 kg, 0.1 kg, 43 kg, 52 kg, 0.3 kg, 0.03 kg, 4.3 kg, 0.6 kg, 216 μg, and 242 g, respectively, in 2014. To mitigate the associated air pollution and health risks caused by gas-fired combustion, stricter emission standards must be established. Additionally, combustion optimization and flue gas purification system could be used for lowering NO X emissions from gas-fired combustion, and gas-fired facilities should be continuously monitored based on emission limits. Graphical abstract Spatial distribution and typical live photos of gas-fired boiler in Beijing.

  10. Environmental Accounts of the Netherlands. Greenhouse gas emissions by Dutch economic activities

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-08-15

    Climate change is one of the major global challenges of our time. There is abundant scientific evidence that the emission of greenhouse gases caused by economic activities contributes to climate change. Accelerating emissions of carbon dioxide, methane, and other greenhouse gases since the beginning of the 20th century have increased the average global temperature by about 0.8C and altered global precipitation patterns. Combustion of fossil fuels, deforestation, but also specific agricultural activities and industrial processes are the main drivers of the increased emission of greenhouse gasses. Enhanced concentrations of greenhouse gasses in the atmosphere will increase global temperatures by radiative forcing. Likewise, climate change has a direct impact on all kinds of economic processes. These impacts may be positive or negative, but it is expected that the overall impact will be primarily negative. In order to design effective mitigation policies, one must have a good conception of the economic driving forces of climate change. The air emission accounts can be used to analyse the environmental implications in terms of greenhouse gas emissions, of production and consumption patterns. Because of their compatibility with the national accounts, greenhouse gas data can be directly linked to the economic drivers of global warming. There are several frameworks for estimating the greenhouse gas emissions for a country, yielding different results. Well-known are the emissions reported to the UNFCCC (United National Framework Convention on Climate Change) in particular under the Kyoto Protocol, but also environment statistics as well as the air emission accounts provide independent greenhouse gas estimates. The differences are not the result of disputes about the accuracy of the estimates themselves, but arise from different interpretations of what has to be counted. The inclusion or exclusion of certain elements depends on the concepts and definitions that underlie

  11. Quantification and Controls of Wetland Greenhouse Gas Emissions

    Energy Technology Data Exchange (ETDEWEB)

    McNicol, Gavin [Univ. of California, Berkeley, CA (United States)

    2016-05-10

    Wetlands cover only a small fraction of the Earth’s land surface, but have a disproportionately large influence on global climate. Low oxygen conditions in wetland soils slows down decomposition, leading to net carbon dioxide sequestration over long timescales, while also favoring the production of redox sensitive gases such as nitrous oxide and methane. Freshwater marshes in particular sustain large exchanges of greenhouse gases under temperate or tropical climates and favorable nutrient regimes, yet have rarely been studied, leading to poor constraints on the magnitude of marsh gas sources, and the biogeochemical drivers of flux variability. The Sacramento-San Joaquin Delta in California was once a great expanse of tidal and freshwater marshes but underwent drainage for agriculture during the last two centuries. The resulting landscape is unsustainable with extreme rates of land subsidence and oxidation of peat soils lowering the surface elevation of much of the Delta below sea level. Wetland restoration has been proposed as a means to slow further subsidence and rebuild peat however the balance of greenhouse gas exchange in these novel ecosystems is still poorly described. In this dissertation I first explore oxygen availability as a control on the composition and magnitude of greenhouse gas emissions from drained wetland soils. In two separate experiments I quantify both the temporal dynamics of greenhouse gas emission and the kinetic sensitivity of gas production to a wide range of oxygen concentrations. This work demonstrated the very high sensitivity of carbon dioxide, methane, and nitrous oxide production to oxygen availability, in carbon rich wetland soils. I also found the temporal dynamics of gas production to follow a sequence predicted by thermodynamics and observed spatially in other soil or sediment systems. In the latter part of my dissertation I conduct two field studies to quantify greenhouse gas exchange and understand the carbon sources for

  12. Greenhouse gas emissions during composting of dairy manure: Delaying pile mixing does not reduce overall emissions

    Science.gov (United States)

    The effect of the timing of pile mixing on greenhouse gas (GHG) emissions during dairy manure composting was determined using large flux chambers designed to completely cover replicate pilot-scale compost piles. GHG emissions from compost piles that were mixed at 2, 3, 4, or 5 weeks after initial c...

  13. Concentrations of nitrous acid, nitric acid, nitrite and nitrate in the gas and aerosol phase at a site in the emission zone during ESCOMPTE 2001 experiment

    Science.gov (United States)

    Acker, K.; Möller, D.; Auel, R.; Wieprecht, W.; Kalaß, D.

    2005-03-01

    Ground-based measurements were performed at the "Expérience sur Site pour COntraindre les Modèles de Pollution atmosphérique et de Transport d`Emissions" (ESCOMPTE) field site E3 (Realtor) about 30 km north of the urban environment of Marseille and east of the industrial centre Berre pond to investigate the formation of nitrous and nitric acid and to detect the distribution of reactive N-species between the gas and particle phase during photochemical pollution events. A wet denuder sampling for gases followed by a steam jet collection for aerosols was both coupled to anion chromatographic analysis. The analytical system provided data continuously with 30-min time resolution between June 13 and July 13, 2001. Indications for heterogeneous formation of nitrous acid during nighttime and daytime on ground and aerosol surfaces were found, the average HNO 2/NO 2 ratio was 6%. Highest concentrations were observed during two episodes of strong pollution accumulation when sea breeze transported industrial, traffic and urban pollution land-inwards. After nocturnal heterogeneous formation (about 0.1 ppb v h -1 were estimated corresponding to increasing HNO 2/NO 2 ratios) and accumulation processes up to 1.2 ppb v HNO 2 were observed. Their photolysis produces up to 5-9×10 6 OH cm -3 s -1 and will contribute significantly to initiation of the daily photochemistry in the lowest part of the troposphere. For the key tropospheric species, HNO 3 daily peaks up to 4 ppb v were detected.

  14. Nitrous oxide emissions and soil mineral nitrogen status following application of hog slurry and inorganic fertilisers to acidic soils under forage grass

    International Nuclear Information System (INIS)

    Mkhabela, M.S.; Gordon, R.; Madani, A.; Burton, D.; Hart, W.

    2008-01-01

    This paper examined the influence of hog slurry and inorganic fertilizers on nitrous oxide (N 2 O) emissions and soil inorganic nitrogen (N) composition. Factors controlling N 2 O production were also identified. The study was comprised of 3 field experiments conducted during the summer months of 2005 on 2 acidic soils seeded with forage grass at a site in Nova Scotia. Treatments included hog slurry; ammonium sulphate; potassium nitrate; and an unamended control site. Emissions were measured using vented polyvinyl chloride static chambers. Gas fluxes and NO 2 measurements were analyzed using gas chromatography. Data were then subjected to analysis of variance (ANOVA). N 2 O flux and soil mineral N data from each sampling day were analyzed separately. Cumulative N 2 O losses were also calculated. Results demonstrated that the addition of hog slurry resulted in lower N 2 O emissions than the samples containing potassium nitrate fertilizer. The study also demonstrated that nitrate (NO 3 ) production drives NO 2 production in acidic soils. It was concluded that further research is needed to verify results obtained during the study. 29 refs., 3 tabs., 3 figs

  15. A plasma process controlled emissions off-gas demonstration

    International Nuclear Information System (INIS)

    Battleson, D.; Kujawa, S.T.; Leatherman, G.

    1995-01-01

    Thermal technologies are currently identified as playing an important role in the treatment of many DOE waste streams, and emissions from these processes will be scrutinized by the public, regulators, and stakeholders. For some time, there has been a hesitancy by the public to accept thermal treatment of radioactive contaminated waste because of the emissions from these processes. While the technology for treatment of emissions from these processes is well established, it is not possible to provide the public complete assurance that the system will be in compliance with air quality regulations 100% of the operating time in relation to allowing noncompliant emissions to exit the system. Because of the possibility of noncompliant emissions and the public's concern over thermal treatment systems, it has been decided that the concept of a completely controlled emissions off-gas system should be developed and implemented on Department of Energy (DOE) thermal treatment systems. While the law of conservation of mass precludes a completely closed cycle system, it is possible to apply the complete control concept to emissions

  16. Particulate Matter Emission from Dual Fuel Diesel Engine Fuelled with Natural Gas

    Directory of Open Access Journals (Sweden)

    Stelmasiak Zdzisław

    2017-06-01

    Full Text Available The paper presents the results of examination of particulate matter emission from the Diesel engine FPT 1.3 MJT simultaneously fuelled with diesel oil and natural gas CNG. The basic premise for engine adaptation was the addition of a small amount of CNG to reduce exhaust gas opacity and particulate matter emission. At this assumption, diesel oil remained the basic fuel, with contribution amounting to 0,70-0,85 of total energy delivered to the engine. The dual fuel engine was examined using an original controller installed in the Diesel engine FPT 1.3 MJT which controlled the diesel fuel dose. The dose of the injected natural gas was controlled by changing the opening time of gas injectors at constant pressure in the gas collector. The examined issues included the exhaust gas opacity, and the total number and fractional distribution of the emitted particles. The measurements were performed at twenty selected measuring points corresponding to the New European Driving Cycle (NEDC test. The performed tests have demonstrated a positive effect of gas addition on exhaust gas opacity and particulate matter emission. Depending on test conditions, the exhaust gas opacity was reduced by 10÷92%, and the total number of particles by 30÷40%. The performed tests have revealed that a small addition of gas can reduce the load of the DPF filter, extend its lifetime, and increase engine reliability. Longer time intervals between successive DPF filter regenerations improve ecological properties of the engine.

  17. Panorama 2009 - greenhouse gas emissions and the transport sector

    International Nuclear Information System (INIS)

    2008-01-01

    The fact that the transport sector is growing quickly brings advantages, such as quick access to any geographical location on earth, but also disadvantages: noise, congestion and polluting emissions such as carbon dioxide (CO 2 ), the greenhouse gas (GHG) primarily responsible for global warming. In the effort to bring GHG emissions under control, improving results in the transport sector is a prime long-term objective. What proportion of CO 2 emissions generated at global and national level are due to the road, air, maritime and rail transport sectors, respectively? What mechanisms can be used to reduce GHG emissions in the transport sector at large?

  18. Fuel prices, emission standards, and generation costs for coal vs natural gas power plants.

    Science.gov (United States)

    Pratson, Lincoln F; Haerer, Drew; Patiño-Echeverri, Dalia

    2013-05-07

    Low natural gas prices and stricter, federal emission regulations are promoting a shift away from coal power plants and toward natural gas plants as the lowest-cost means of generating electricity in the United States. By estimating the cost of electricity generation (COE) for 304 coal and 358 natural gas plants, we show that the economic viability of 9% of current coal capacity is challenged by low natural gas prices, while another 56% would be challenged by the stricter emission regulations. Under the current regulations, coal plants would again become the dominant least-cost generation option should the ratio of average natural gas to coal prices (NG2CP) rise to 1.8 (it was 1.42 in February 2012). If the more stringent emission standards are enforced, however, natural gas plants would remain cost competitive with a majority of coal plants for NG2CPs up to 4.3.

  19. Greenhouse gas emission reduction by means of fuel switching in electricity generation: Addressing the potentials

    International Nuclear Information System (INIS)

    Delarue, Erik; D'haeseleer, William

    2008-01-01

    Many countries committed themselves in the Kyoto protocol to reduce greenhouse gas (GHG) emissions. Some of these targeted emission reductions could result from a switch from coal-fired to gas-fired electricity generation. The focus in this work lies on Western Europe, with the presence of the European Union Emission Trading Scheme (EU ETS). For the switching to occur, several conditions have to be fulfilled. First, an economical incentive must be present, i.e. a sufficiently high European Union Allowance (EUA) price together with a sufficiently low natural gas price. Second, the physical potential for switching must exist, i.e. at a given load, there must remain enough power plants not running to make switching possible. This paper investigates what possibilities exist for switching coal-fired plants for gas-fired plants, dependent on the load level (the latter condition above). A fixed allowance cost and a variable natural gas price are assumed. The method to address GHG emission reduction potentials is first illustrated in a methodological case. Next, the GHG emission reduction potentials are addressed for several Western European countries together with a relative positioning of their electricity generation. GHG emission reduction potentials are also compared with simulation results. GHG emission reduction potentials tend to be significant. The Netherlands have a very widespread switching zone, so GHG emission reduction is practically independent of electricity generation. Other counties, like Germany, Spain and Italy could reduce GHG emissions significantly by switching. With an allowance cost following the switch level of a 50% efficient gas-fired plant and a 40% efficient coal-fired plant in the summer season (like in 2005), the global GHG emission reduction (in the electricity generating sector) for the eight modeled zones could amount to 19%

  20. Constructing a Spatially Resolved Methane Emission Inventory of Natural Gas Production and Distribution over Contiguous United States

    Science.gov (United States)

    Li, X.; Omara, M.; Adams, P. J.; Presto, A. A.

    2017-12-01

    Methane is the second most powerful greenhouse gas after Carbon Dioxide. The natural gas production and distribution accounts for 23% of the total anthropogenic methane emissions in the United States. The boost of natural gas production in U.S. in recent years poses a potential concern of increased methane emissions from natural gas production and distribution. The Emission Database for Global Atmospheric Research (Edgar) v4.2 and the EPA Greenhouse Gas Inventory (GHGI) are currently the most commonly used methane emission inventories. However, recent studies suggested that both Edgar v4.2 and the EPA GHGI largely underestimated the methane emission from natural gas production and distribution in U.S. constrained by both ground and satellite measurements. In this work, we built a gridded (0.1° Latitude ×0.1° Longitude) methane emission inventory of natural gas production and distribution over the contiguous U.S. using emission factors measured by our mobile lab in the Marcellus Shale, the Denver-Julesburg Basin, and the Uintah Basin, and emission factors reported from other recent field studies for other natural gas production regions. The activity data (well location and count) are mostly obtained from the Drillinginfo, the EPA Greenhouse Gas Reporting Program (GHGRP) and the U.S. Energy Information Administration (EIA). Results show that the methane emission from natural gas production and distribution estimated by our inventory is about 20% higher than the EPA GHGI, and in some major natural gas production regions, methane emissions estimated by the EPA GHGI are significantly lower than our inventory. For example, in the Marcellus Shale, our estimated annual methane emission in 2015 is 600 Gg higher than the EPA GHGI. We also ran the GEOS-Chem methane simulation to estimate the methane concentration in the atmosphere with our built inventory, the EPA GHGI and the Edgar v4.2 over the nested North American Domain. These simulation results showed differences in

  1. Talisman Energy Inc. progress on reducing greenhouse gas emissions. Revised ed.

    International Nuclear Information System (INIS)

    2001-01-01

    Talisman Energy Inc., as the largest independent Canadian oil and gas producer, is committed to supporting the Voluntary Challenge and Registry (VCR) Program. To this effect, voluntary measures have been implemented for achieving energy efficiency and greenhouse gas emissions reductions. Some of those measures include a yearly electrical audit in each field, the establishment of facility design and equipment procurement practices, gas well deliverability testing, gas conservation and flare reduction, a new energy data management system, senior management monitoring of greenhouse gas emissions reductions, and several others. Each of these measures was briefly described, and the base year quantification was included along with projections and target setting. Section 6 of the document introduced the measures to achieve targets, followed by section 7 containing results achieved. In section 8, the topic of education, training and awareness was discussed. A brief acknowledgements section was included at the end of the document. 10 tabs., 6 figs

  2. The development of an ultra-low-emission gas-fired cyclonic combustor

    International Nuclear Information System (INIS)

    Xiong, Tian-yu; Khinkis, M.J.; Coppin, W.P.

    1991-01-01

    A gas-fired cyclonic combustor has been developed for relatively low-temperature direct-air heating applications that require ultra-low pollutant emissions. High-lean premixed combustion with a flame stabilizer is adopted to achieve ultra-low emissions and high turndown operation. On the basis of analytical studies and cold modeling, a 350-kW test combustor was designed and successfully tested. Experimental results obtained using natural gas and ambient air demonstrated that the test combustor can operate steadily at high excess air up to 80% to 100% over a large turndown range up to 40:1. At design operating conditions, NO x emissions as low as 0.6 vppm and CO and total hydrocarbon (THC) emissions below 3 vppm were achieved. Over the full operating range, NO x emissions from 0.3 to 1.0 vppm and CO and THC emissions below 4 vppm were demonstrated. In all tests, concentrations of NO 2 were less than 40% of the total NO x emissions -- lower than the level of NO 2 emissions from combustion processes required for good indoor air quality (0.5 vppm). This paper presents the concept of high-lean premixed ultra-low-emission cyclonic combustion, design specifications for the combustion system, and the major experimental results, including flame stability, emissions, and turndown performance. 13 refs., 12 figs., 1 tab

  3. Identification of urban gas leaks and evaluation of methane emission inventories using mobile measurements

    Science.gov (United States)

    Zazzeri, Giulia; Lowry, Dave; Fisher, Rebecca E.; France, James L.; Butler, Dominique; Lanoisellé, Mathias; Nisbet, Euan G.

    2017-04-01

    Leakages from the natural gas distribution network, power plants and refineries account for the 10% of national methane emissions in the UK (http://naei.defra.gov.uk/), and are identified as a major source of methane in big conurbations (e.g. Townsend-Small et al., 2012; Phillips et al., 2013). The National Atmospheric Emission Inventories (NAEI) website provides a list of gas installations, but emissions from gas leakage, which in the inventories are estimated on the basis of the population distribution, are difficult to predict, which makes their estimation highly uncertain. Surveys with a mobile measurement system (Zazzeri et al., 2015) were carried out in the London region for detection of fugitive natural gas and in other sites in the UK (i.e. Bacton, Southampton, North Yorkshire) to identify emissions from various gas installations. The methane isotopic analysis of air samples collected during the surveys, using the methodology in Zazzeri et al. (2015), allows the calculation of the δ13C signature characterising natural gas in the UK. The isotopic value of the natural gas supply to SE London has changed a little in recent years, being close to -34 ‰ over 1998-99 period (Lowry et al., 2001) and close to -36 ‰ since at least 2002. Emissions from gas installations, such as pumping stations in NE England (-41 ± 2 ‰ ) were detected, but some of them were not listed in the inventories. Furthermore, the spatial distribution of the gas leaks identified during the surveys in the London region does not coincide with the distribution suggested by the inventories. By locating both small gas leaks and emissions from large gas installations, we can verify how these methane sources are targeted by national emission inventories. Lowry, D., Holmes, C.W., Rata, N.D., O'Brien, P., and Nisbet, E.G., 2001, London methane emissions: Use of diurnal changes in concentration and δ13C to identify urban sources and verify inventories: Journal of Geophysical Research

  4. Experimental Study of Natural Gas Temperature Effects on the Flame Luminosity and No Emission

    Directory of Open Access Journals (Sweden)

    S. M. Javadi

    2012-06-01

    Full Text Available The flame radiation enhancement in gas-fired furnaces significantly improves the thermal efficiency without significantly affecting the NOx emissions. In this paper, the effects of inlet natural gas preheating on the flame luminosity, overall boiler efficiency, and NO emission in a 120 kW boiler have been investigated experimentally. Flame radiation is measured by use of laboratory pyranometer with photovoltaic sensor. A Testo350XL gas analyzer is also used for measuring the temperature and combustion species. The fuel is preheated from the room temperature to 350°C. The experimental measurements show that the preheating of natural gas up to about 240°C has no considerable effect on the flame luminosity. The results show that increasing the inlet gas temperature from 240°C, abruptly increases the flame luminosity. This luminosity increase enhances the boiler efficiency and also causes significant reduction in flame temperature and NO emission. The results show that increasing the inlet gas temperature from 240°C to 300°C increases the flame luminous radiation by 60% and boiler efficiency by 20%; while the maximum flame temperature and the boiler NO emission show a 10% and 8% decrease respectively.

  5. The life cycle greenhouse gas emissions implications of power and hydrogen production for oil sands operations

    International Nuclear Information System (INIS)

    McKellar, J.M.; Bergerson, J.A.; MacLean, H.L.

    2009-01-01

    'Full text:' The Alberta Oil Sands represent a major economic opportunity for Canada, but the industry is also a significant source of greenhouse gas (GHG) emissions. One of the sources of these emissions is the use of natural gas for the production of electricity, steam and hydrogen. Due to concerns around resource availability and price volatility, there has been considerable discussion regarding the potential replacement of natural gas with an alternative fuel. While some of the options are non-fossil and could potentially reduce GHG emissions (e.g., nuclear, geothermal, biomass), others have the potential to increase emissions. A comparative life cycle assessment was completed to investigate the relative GHG emissions, energy consumption and financial implications of replacing natural gas with coal, coke, asphaltenes or bitumen for the supply of electricity, steam and hydrogen to oil sands operations. The potential use of carbon capture and storage (CCS) was also investigated as a means of reducing GHG emissions. Preliminary results indicate that, without CCS, the natural gas systems currently in use have lower life cycle GHG emissions than gasification systems using any of the alternative fuels analysed. However, when CCS is implemented in both the coke gasification and natural gas systems, the coke systems have lower GHG emissions and financial costs than the natural gas systems (assuming a 30-year project life and a natural gas price of 6.5 USD/gigajoule). The use of CCS does impose a financial penalty though, indicating that it is unlikely to be implemented without some financial incentive. While this study has limitations and uncertainties, the preliminary results indicate that although the GHG emissions of oil sands development pose a challenge to Canada, there are opportunities available for their abatement. (author)

  6. Application of meta-omics techniques to understand greenhouse gas emissions originating from ruminal metabolism.

    Science.gov (United States)

    Wallace, Robert J; Snelling, Timothy J; McCartney, Christine A; Tapio, Ilma; Strozzi, Francesco

    2017-01-16

    Methane emissions from ruminal fermentation contribute significantly to total anthropological greenhouse gas (GHG) emissions. New meta-omics technologies are beginning to revolutionise our understanding of the rumen microbial community structure, metabolic potential and metabolic activity. Here we explore these developments in relation to GHG emissions. Microbial rumen community analyses based on small subunit ribosomal RNA sequence analysis are not yet predictive of methane emissions from individual animals or treatments. Few metagenomics studies have been directly related to GHG emissions. In these studies, the main genes that differed in abundance between high and low methane emitters included archaeal genes involved in methanogenesis, with others that were not apparently related to methane metabolism. Unlike the taxonomic analysis up to now, the gene sets from metagenomes may have predictive value. Furthermore, metagenomic analysis predicts metabolic function better than only a taxonomic description, because different taxa share genes with the same function. Metatranscriptomics, the study of mRNA transcript abundance, should help to understand the dynamic of microbial activity rather than the gene abundance; to date, only one study has related the expression levels of methanogenic genes to methane emissions, where gene abundance failed to do so. Metaproteomics describes the proteins present in the ecosystem, and is therefore arguably a better indication of microbial metabolism. Both two-dimensional polyacrylamide gel electrophoresis and shotgun peptide sequencing methods have been used for ruminal analysis. In our unpublished studies, both methods showed an abundance of archaeal methanogenic enzymes, but neither was able to discriminate high and low emitters. Metabolomics can take several forms that appear to have predictive value for methane emissions; ruminal metabolites, milk fatty acid profiles, faecal long-chain alcohols and urinary metabolites have all

  7. Greenhouse gas emissions from agricultural soils in Austria

    International Nuclear Information System (INIS)

    Strebl, F.; Gebetsroither, E.; Orthofer, R.

    2002-07-01

    This report documents the calculations of anthropogenic greenhouse gas emissions in Austria of the IPCC-sector 'Agricultural Soils' for the period 1980 to 2001. According to available information, CH 4 emissions from agricultural soils are very small and thus irrelevant. N 2 O emissions were calculated according to the IPCC method; emission sources considered include direct emissions from nitrogen inputs to soils (mineral and organic fertilizers, crop residues, sewage sludge application, biological fixation) as well as indirect emissions (from atmospheric nitrogen deposition and nitrogen leaching) plus emissions from nitrogen input through grazing animal excreta. NH 3 and NO x emissions were calculated according to the CORINAIR method; sources considered were nitrogen inputs through fertilization as well as emissions from unfertilized cultures. In the year 1990 total emissions were 5.680 t N 2 O-N, 24.628 t NH 3 -N and 1.376 t NO x N. In the period 1980-2001 there were considerable fluctuations of emissions, caused by an inter annual variability of crop production and fertilizer consumption data. However, there are no significant emission trends in the past 20 years. Uncertainties were determined through a Monte-Carlo-based simulation; the standard deviation of a normal uncertainty distribution is 24 % for N 2 O, 13 % for NH 3 , and 18 % for NO x . (author)

  8. Laboratory measurements of trace gas emissions from biomass burning of fuel types from the southeastern and southwestern United States

    Directory of Open Access Journals (Sweden)

    I. R. Burling

    2010-11-01

    Full Text Available Vegetation commonly managed by prescribed burning was collected from five southeastern and southwestern US military bases and burned under controlled conditions at the US Forest Service Fire Sciences Laboratory in Missoula, Montana. The smoke emissions were measured with a large suite of state-of-the-art instrumentation including an open-path Fourier transform infrared (OP-FTIR spectrometer for measurement of gas-phase species. The OP-FTIR detected and quantified 19 gas-phase species in these fires: CO2, CO, CH4, C2H2, C2H4, C3H6, HCHO, HCOOH, CH3OH, CH3COOH, furan, H2O, NO, NO2, HONO, NH3, HCN, HCl, and SO2. Emission factors for these species are presented for each vegetation type burned. Gas-phase nitrous acid (HONO, an important OH precursor, was detected in the smoke from all fires. The HONO emission factors ranged from 0.15 to 0.60 g kg−1 and were higher for the southeastern fuels. The fire-integrated molar emission ratios of HONO (relative to NOx ranged from approximately 0.03 to 0.20, with higher values also observed for the southeastern fuels. The majority of non-methane organic compound (NMOC emissions detected by OP-FTIR were oxygenated volatile organic compounds (OVOCs with the total identified OVOC emissions constituting 61 ± 12% of the total measured NMOC on a molar basis. These OVOC may undergo photolysis or further oxidation contributing to ozone formation. Elevated amounts of gas-phase HCl and SO2 were also detected during flaming combustion, with the amounts varying greatly depending on location and vegetation type. The fuels with the highest HCl emission factors were all located in the coastal regions, although HCl was also observed from fuels farther inland. Emission factors for HCl were generally higher for the southwestern fuels

  9. International markets for greenhouse gas emission reduction policies - possibilities for integrating developing countries

    DEFF Research Database (Denmark)

    Halsnæs, K.; Olhoff, A.

    2005-01-01

    Greenhouse gas (GHG) emissions are affecting a global common: the climate, and as a global environmental problem with a public good character it provides attractive opportunities for minimising control costs through the use of emission trading markets. This paper introduces cost and benefit princ...... principles that can be applied to the assessment of global markets for GHG emission reduction options and evaluates the scope for and the potential economic gains of such markets.......Greenhouse gas (GHG) emissions are affecting a global common: the climate, and as a global environmental problem with a public good character it provides attractive opportunities for minimising control costs through the use of emission trading markets. This paper introduces cost and benefit...

  10. Volatile organic compound emissions from the oil and natural gas industry in the Uintah Basin, Utah: oil and gas well pad emissions compared to ambient air composition

    Science.gov (United States)

    Warneke, C.; Geiger, F.; Edwards, P. M.; Dube, W.; Pétron, G.; Kofler, J.; Zahn, A.; Brown, S. S.; Graus, M.; Gilman, J. B.; Lerner, B. M.; Peischl, J.; Ryerson, T. B.; de Gouw, J. A.; Roberts, J. M.

    2014-10-01

    Emissions of volatile organic compounds (VOCs) associated with oil and natural gas production in the Uintah Basin, Utah were measured at a ground site in Horse Pool and from a NOAA mobile laboratory with PTR-MS instruments. The VOC compositions in the vicinity of individual gas and oil wells and other point sources such as evaporation ponds, compressor stations and injection wells are compared to the measurements at Horse Pool. High mixing ratios of aromatics, alkanes, cycloalkanes and methanol were observed for extended periods of time and for short-term spikes caused by local point sources. The mixing ratios during the time the mobile laboratory spent on the well pads were averaged. High mixing ratios were found close to all point sources, but gas well pads with collection and dehydration on the well pad were clearly associated with higher mixing ratios than other wells. The comparison of the VOC composition of the emissions from the oil and natural gas well pads showed that gas well pads without dehydration on the well pad compared well with the majority of the data at Horse Pool, and that oil well pads compared well with the rest of the ground site data. Oil well pads on average emit heavier compounds than gas well pads. The mobile laboratory measurements confirm the results from an emissions inventory: the main VOC source categories from individual point sources are dehydrators, oil and condensate tank flashing and pneumatic devices and pumps. Raw natural gas is emitted from the pneumatic devices and pumps and heavier VOC mixes from the tank flashings.

  11. Methods and techniques for measuring gas emissions from agricultural and animal feeding operations.

    Science.gov (United States)

    Hu, Enzhu; Babcock, Esther L; Bialkowski, Stephen E; Jones, Scott B; Tuller, Markus

    2014-01-01

    Emissions of gases from agricultural and animal feeding operations contribute to climate change, produce odors, degrade sensitive ecosystems, and pose a threat to public health. The complexity of processes and environmental variables affecting these emissions complicate accurate and reliable quantification of gas fluxes and production rates. Although a plethora of measurement technologies exist, each method has its limitations that exacerbate accurate quantification of gas fluxes. Despite a growing interest in gas emission measurements, only a few available technologies include real-time, continuous monitoring capabilities. Commonly applied state-of-the-art measurement frameworks and technologies were critically examined and discussed, and recommendations for future research to address real-time monitoring requirements for forthcoming regulation and management needs are provided.

  12. Reduction of greenhouse gas emission on a medium-pressure boiler using hydrogen-rich fuel control

    International Nuclear Information System (INIS)

    Hsieh, S.-C.; Jou, Chih-Ju G.

    2007-01-01

    The increasing emission of greenhouse gases from the combustion of fossil fuel is believed to be responsible for global warming. A study was carried out to probe the influence of replacing fuel gas with hydrogen-rich refinery gas (R.G.) on the reduction of gas emission (CO 2 and NO x ) and energy saving. Test results show that the emission of CO 2 can be reduced by 16.4% annually (or 21,500 tons per year). The NO x emission can be 8.2% lower, or 75 tons less per year. Furthermore, the use of refinery gas leads to a saving of NT$57 million (approximately US$1.73 million) on fuel costs each year. There are no CO 2 , CO, SO x , unburned hydrocarbon, or particles generated from the combustion of added hydrogen. The hydrogen content in R.G. employed in this study was between 50 and 80 mol%, so the C/H ratio of the feeding fuel was reduced. Therefore, the use of hydrogen-rich fuel has practical benefits for both energy saving and the reduction of greenhouse gas emission

  13. Boiler briquette coal versus raw coal: Part I--Stack gas emissions.

    Science.gov (United States)

    Ge, S; Bai, Z; Liu, W; Zhu, T; Wang, T; Qing, S; Zhang, J

    2001-04-01

    Stack gas emissions were characterized for a steam-generating boiler commonly used in China. The boiler was tested when fired with a newly formulated boiler briquette coal (BB-coal) and when fired with conventional raw coal (R-coal). The stack gas emissions were analyzed to determine emission rates and emission factors and to develop chemical source profiles. A dilution source sampling system was used to collect PM on both Teflon membrane filters and quartz fiber filters. The Teflon filters were analyzed gravimetrically for PM10 and PM2.5 mass concentrations and by X-ray fluorescence (XRF) for trace elements. The quartz fiber filters were analyzed for organic carbon (OC) and elemental carbon (EC) using a thermal/optical reflectance technique. Sulfur dioxide was measured using the standard wet chemistry method. Carbon monoxide was measured using an Orsat combustion analyzer. The emission rates of the R-coal combustion (in kg/hr), determined using the measured stack gas concentrations and the stack gas emission rates, were 0.74 for PM10, 0.38 for PM2.5, 20.7 for SO2, and 6.8 for CO, while those of the BB-coal combustion were 0.95 for PM10, 0.30 for PM2.5, 7.5 for SO2, and 5.3 for CO. The fuel-mass-based emission factors (in g/kg) of the R-coal, determined using the emission rates and the fuel burn rates, were 1.68 for PM10, 0.87 for PM2.5, 46.7 for SO2, and 15 for CO, while those of the BB-coal were 2.51 for PM10, 0.79 for PM2.5, 19.9 for SO2, and 14 for CO. The task-based emission factors (in g/ton steam generated) of the R-coal, determined using the fuel-mass-based emission factors and the coal/steam conversion factors, were 0.23 for PM10, 0.12 for PM2.5, 6.4 for SO2, and 2.0 for CO, while those of the BB-coal were 0.30 for PM10, 0.094 for PM2.5, 2.4 for SO2, and 1.7 for CO. PM10 and PM2.5 elemental compositions are also presented for both types of coal tested in the study.

  14. Boiler Briquette Coal versus Raw Coal: Part I-Stack Gas Emissions.

    Science.gov (United States)

    Ge, Su; Bai, Zhipeng; Liu, Weili; Zhu, Tan; Wang, Tongjian; Qing, Sheng; Zhang, Junfeng

    2001-04-01

    Stack gas emissions were characterized for a steam-generating boiler commonly used in China. The boiler was tested when fired with a newly formulated boiler briquette coal (BB-coal) and when fired with conventional raw coal (R-coal). The stack gas emissions were analyzed to determine emission rates and emission factors and to develop chemical source profiles. A dilution source sampling system was used to collect PM on both Teflon membrane filters and quartz fiber filters. The Teflon filters were analyzed gravimetrically for PM 10 and PM 2.5 mass concentrations and by X-ray fluorescence (XRF) for trace elements. The quartz fiber filters were analyzed for organic carbon (OC) and elemental carbon (EC) using a thermal/optical reflectance technique. Sulfur dioxide was measured using the standard wet chemistry method. Carbon monoxide was measured using an Orsat combustion analyzer. The emission rates of the R-coal combustion (in kg/hr), determined using the measured stack gas concentrations and the stack gas emission rates, were 0.74 for PM 10 , 0.38 for PM 25 , 20.7 for SO 2 , and 6.8 for CO, while those of the BB-coal combustion were 0.95 for PM 10 , 0.30 for PM 2 5 , 7.5 for SO 2 , and 5.3 for CO. The fuel-mass-based emission factors (in g/kg) of the R-coal, determined using the emission rates and the fuel burn rates, were 1.68 for PM 10 , 0.87 for PM 25 , 46.7 for SO 2 , and 15 for CO, while those of the BB-coal were 2.51 for PM 10 , 0.79 for PM 2.5 , 19.9 for SO 2 , and 14 for CO. The task-based emission factors (in g/ton steam generated) of the R-coal, determined using the fuel-mass-based emission factors and the coal/ steam conversion factors, were 0.23 for PM 10 , 0.12 for PM 2.5 , 6.4 for SO 2 , and 2.0 for CO, while those of the BB-coal were 0.30 for PM 10 , 0.094 for PM 2.5 , 2.4 for SO 2 , and 1.7 for CO. PM 10 and PM 2.5 elemental compositions are also presented for both types of coal tested in the study.

  15. Emissions of Monoxide of Carbon and Methane in an atmospheric burner of natural gas

    International Nuclear Information System (INIS)

    Amell A, A.A.; Gil B, E.; Cadavid S, F.J.

    1999-01-01

    In Colombia, the development of gas equipment industry has been characterized by a copy of foreign systems, without going further on the basic principles of operation and design of gas appliances. In order to guarantee an efficient and safe use of this energetic during the present plan of massive use of gas in the country, is necessary to know and dominate all the main phenomena influencing the design and operation of gas appliances, among them is the rate of primary aeration. In this study we analyze the production of CO and CH4 emissions in a premixed atmospheric burner when we modify pressure supply, tip size, injector size, mixer length and diameter of the throat. Results show that mixer geometry has a great influence on CO and CH4 emissions. When aeration rate was less or equal than 0.5 for power greater than 2.3 kw, CO emissions were beyond critic boundary. In the other hand, when we increased gas pressure supply, we observed those CH4 emissions decreased

  16. Real-time exhaust gas modular flowmeter and emissions reporting system for mobile apparatus

    Science.gov (United States)

    Breton, Leo Alphonse Gerard (Inventor)

    2002-01-01

    A real-time emissions reporting system includes an instrument module adapted to be detachably connected to the exhaust pipe of a combustion engine to provide for flow of exhaust gas therethrough. The instrument module includes a differential pressure probe which allows for determination of flow rate of the exhaust gas and a gas sampling tube for continuously feeding a sample of the exhaust gas to a gas analyzer or a mounting location for a non-sampling gas analyzer. In addition to the module, the emissions reporting system also includes an elastomeric boot for detachably connecting the module to the exhaust pipe of the combustion engine, a gas analyzer for receiving and analyzing gases sampled within the module and a computer for calculating pollutant mass flow rates based on concentrations detected by the gas analyzer and the detected flowrate of the exhaust gas. The system may also include a particulate matter detector with a second gas sampling tube feeding same mounted within the instrument module.

  17. Emissions and efficiency of a domestic gas stove burning natural gases with various compositions

    International Nuclear Information System (INIS)

    Yungchang Ko; Tahui Lin

    2003-01-01

    The heating value of a fuel, which depends on its composition, strongly affects burner performance. Using the same gas stove to burn natural gas with various heating values is inappropriate and hazardous due to the possible occurrence of incomplete combustion (i.e. a great increase of CO emissions and/or soot formation), liftoff, flashback and inadequate heat input. In this study, we aim to assess the effects of changes in gas composition on burner performance and propose suitable design or operational factors of domestic gas stoves burning natural gas with various heating values. A single gas burner, originally designed for burning natural gas with low heating value, is adopted to investigate the effects of variations in gas composition on the burner performance. The influence of five significant parameters, including gas composition, primary aeration, gas flow rate (heat input), gas supply pressure, and loading height, on the thermal efficiency and CO emissions were reported and discussed. Using natural gas with high heating value instead of natural gas with low heating value results in a decrease in thermal efficiency (due to higher thermal input) and an increase in CO emission (caused by incomplete combustion). These problems can be significantly improved by decreasing the gas pressure to a suitable value, by enlarging the primary aeration to a favorable level, by selecting a proper thermal input, or by adjusting the optimized heating height. (Author)

  18. Greenhouse gas emission quantification from wastewater treatment plants, using a tracer gas dispersion method

    DEFF Research Database (Denmark)

    Delre, Antonio; Mønster, Jacob; Scheutz, Charlotte

    2017-01-01

    Plant-integrated methane (CH4) and nitrous oxide (N2O) emission quantifications were performed at five Scandinavian wastewater treatment plants, using a ground-based remote sensing approach that combines a controlled release of tracer gas from the plant with downwind concentration measurements. CH4...... emission factors were between 1 and 21% of CH4 production, and between 0.2 and 3.2% of COD influent. The main CH4 emitting sources at the five plants were sludge treatment and energy production units. The lowest CH4 emission factors were obtained at plants with enclosed sludge treatment and storage units...... in international guidelines. This study showed that measured CH4 and N2O emission rates from wastewater treatment plants were plant-specific and that emission rates estimated using models in current guidelines, mainly meant for reporting emissions on the country scale, were unsuitable for Scandinavian plant...

  19. Stakeholder resource information on greenhouse gas emissions

    International Nuclear Information System (INIS)

    1997-01-01

    Some of the many measures which have already been taken by the petroleum industry to safeguard the air, land and water were described in a background paper produced by the Petroleum Communication Foundation. It is entitled 'Canada's oil and gas industry and our global environment'. This complementary report includes a brief review of greenhouse gases and related issues such as the nature of global warming, Canadian emissions in a global context, the relationship between the economy and the environment, mitigation possibilities and successes achieved by actions such as those undertaken by the Voluntary Challenge and Registry (VCR) program. Also included are notes and quotes from authoritative sources regarding emissions, emissions control and success stories. A sample presentation was also provided that could be used to discuss global warming issues with general audiences and other communication activities. figs

  20. Modeling of greenhouse gas emission from livestock

    Directory of Open Access Journals (Sweden)

    Sanjo eJose

    2016-04-01

    Full Text Available The effects of climate change on humans and other living ecosystems is an area of on-going research. The ruminant livestock sector is considered to be one of the most significant contributors to the existing greenhouse gas (GHG pool. However the there are opportunities to combat climate change by reducing the emission of GHGs from ruminants. Methane (CH4 and nitrous oxide (N2O are emitted by ruminants via anaerobic digestion of organic matter in the rumen and manure, and by denitrification and nitrification processes which occur in manure. The quantification of these emissions by experimental methods is difficult and takes considerable time for analysis of the implications of the outputs from empirical studies, and for adaptation and mitigation strategies to be developed. To overcome these problems computer simulation models offer substantial scope for predicting GHG emissions. These models often include all farm activities while accurately predicting the GHG emissions including both direct as well as indirect sources. The models are fast and efficient in predicting emissions and provide valuable information on implementing the appropriate GHG mitigation strategies on farms. Further, these models help in testing the efficacy of various mitigation strategies that are employed to reduce GHG emissions. These models can be used to determine future adaptation and mitigation strategies, to reduce GHG emissions thereby combating livestock induced climate change.

  1. Measurements and modeling to quantify emissions of methane and VOCs from shale gas operations: Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Presto, Albert A [Carnegie Mellon Univ., Pittsburgh, PA (United States)

    2017-06-30

    The objectives of the project were to determine the leakage rates of methane and ozone-forming Volatile Organic Compounds (VOCs) and the emission rates of air toxics from Marcellus shale gas activities. Methane emissions in the Marcellus Shale region were differentiated between “newer” sources associated with shale gas development and “older” sources associated with coal or conventional natural gas exploration. This project conducted measurements of methane and VOC emissions from both shale and non-shale natural gas resources. The initial scope of the project was the Marcellus Shale basin, and measurements were conducted in both the western wet gas regions (southwest PA and WV) and eastern dry gas region (northeast PA) of the basin. During this project, we obtained additional funding from other agencies to expand the scope of measurements to include additional basins. The data from both the Marcellus and other basins were combined to construct a national analysis of methane emissions from oil & gas production activities.

  2. Modeling to Evaluate Contribution of Oil and Gas Emissions to Air Pollution.

    Science.gov (United States)

    Thompson, Tammy M; Shepherd, Donald; Stacy, Andrea; Barna, Michael G; Schichtel, Bret A

    2017-04-01

    Oil and gas production in the Western United States has increased considerably over the past 10 years. While many of the still limited oil and gas impact assessments have focused on potential human health impacts, the typically remote locations of production in the Intermountain West suggests that the impacts of oil and gas production on national parks and wilderness areas (Class I and II areas) could also be important. To evaluate this, we utilize the Comprehensive Air quality Model with Extensions (CAMx) with a year-long modeling episode representing the best available representation of 2011 meteorology and emissions for the Western United States. The model inputs for the 2011 episodes were generated as part of the Three State Air Quality Study (3SAQS). The study includes a detailed assessment of oil and gas (O&G) emissions in Western States. The year-long modeling episode was run both with and without emissions from O&G production. The difference between these two runs provides an estimate of the contribution of the O&G production to air quality. These data were used to assess the contribution of O&G to the 8 hour average ozone concentrations, daily and annual fine particulate concentrations, annual nitrogen deposition totals and visibility in the modeling domain. We present the results for the Class I and II areas in the Western United States. Modeling results suggest that emissions from O&G activity are having a negative impact on air quality and ecosystem health in our National Parks and Class I areas. In this research, we use a modeling framework developed for oil and gas evaluation in the western United States to determine the modeled impacts of emissions associated with oil and gas production on air pollution metrics. We show that oil and gas production may have a significant negative impact on air quality and ecosystem health in some national parks and other Class I areas in the western United States. Our findings are of particular interest to federal

  3. Emissions of CH4 from natural gas production in the United States using aircraft-based observations (Invited)

    Science.gov (United States)

    Sweeney, C.; Ryerson, T. B.; Karion, A.; Peischl, J.; Petron, G.; Schnell, R. C.; Tsai, T.; Crosson, E.; Rella, C.; Trainer, M.; Frost, G. J.; Hardesty, R. M.; Montzka, S. A.; Dlugokencky, E. J.; Tans, P. P.

    2013-12-01

    New extraction technologies are making natural gas from shale and tight sand gas reservoirs in the United States (US) more accessible. As a result, the US has become the largest producer of natural gas in the world. This growth in natural gas production may result in increased leakage of methane, a potent greenhouse gas, offsetting the climate benefits of natural gas relative to other fossil fuels. Methane emissions from natural gas production are not well quantified because of the large variety of potential sources, the variability in production and operating practices, the uneven distribution of emitters, and a lack of verification of emission inventories with direct atmospheric measurements. Researchers at the NOAA Earth System Research Laboratory (ESRL) have used simple mass balance approaches to estimate emissions of CH4 from several natural gas and oil plays across the US. We will summarize the results of the available aircraft and ground-based atmospheric emissions estimates to better understand the spatial and temporal distribution of these emissions in the US.

  4. Study on performance and emission characteristics of a single cylinder diesel engine using exhaust gas recirculation

    Directory of Open Access Journals (Sweden)

    Anantha Raman Lakshmipathi

    2017-01-01

    Full Text Available Exhaust gas re-circulation is a method used in compression ignition engines to control and reduce NOx emission. These emissions are controlled by reducing the oxygen concentration inside the cylinder and thereby reducing the flame temperature of the charge mixture inside the combustion chamber. In the present investigation, experiments were performed to study the effect of exhaust gas re-circulation on performance and emission characteristics in a four stroke single cylinder, water cooled and constant speed diesel engine. The experiments were performed to study the performance and emissions for different exhaust gas re-circulation ratios of the engine. Performance parameters such as brake thermal efficiency, indicated thermal efficiency, specific fuel consumption, total fuel consumption and emission parameters such as oxides of nitrogen, unburned hydrocarbons, carbon monoxide, carbon dioxide and smoke opacity were measured. Reductions in NOx and CO2 were observed but other emissions like HC, CO, and smoke opacity were found to have increased with the usage of exhaust gas re-circulation. The 15% exhaust gas re-circulation was found optimum for the engine in the aspects of performance and emission.

  5. Innovative technologies for greenhouse gas emission reduction in steel production

    Directory of Open Access Journals (Sweden)

    D. Burchart-Korol

    2016-01-01

    Full Text Available The main goal of the study was to present the most significant technological innovations aiming at reduction of greenhouse gas emission in steel production. Reduction of greenhouse gas and dust pollution is a very important aspect in the iron and steel industry. New solutions are constantly being searched for to reduce greenhouse gases (GHG. The article presents the most recent innovative technologies which may be applied in the steel industry in order to limit the emission of GHG. The significance of CCS (CO2 Capture and Storage and CCU (CO2 Capture and Utilization in the steel industry are also discussed.

  6. Greenhouse gas emissions from integrated urban drainage systems

    DEFF Research Database (Denmark)

    Mannina, Giorgio; Butler, David; Benedetti, Lorenzo

    2018-01-01

    As sources of greenhouse gas (GHG) emissions, integrated urban drainage systems (IUDSs) (i.e., sewer systems, wastewater treatment plants and receiving water bodies) contribute to climate change. This paper, produced by the International Working Group on Data and Models, which works under the IWA...

  7. Performance and exhaust emissions in a natural-gas fueled dual-fuel engine; Tennen gas dual fuel kikan no seino oyobi haiki tokusei

    Energy Technology Data Exchange (ETDEWEB)

    Shioji, M.; Ishiyama, T.; Shibata, H. [Kyoto Univ., Kyoto (Japan). Inst. of Atomic Energy; Ikegami, M. [Fukui Institute of Technology, Fukui (Japan). Faculty of Engineering

    2000-07-25

    In order to establish the optimum fueling in a natural gas fueled dual fuel engine, tests were made for some operational parameters and their combination on the engine performances and the exhaust emissions. The results show that the gas oil quantity should be increased and gas oil injection timing should be advanced to suppress unburned hydrocarbon emission at middle and low output range, while the quantity should be reduced and the timing should be retarded to avoid onset of knock at high loads. The unburned hydrocarbon emission and the thermal efficiency are improved at the same load avoiding too lean natural gas premixture by restriction of intake charge air. However the improvement is limited because the ignition and initial combustion of pilot diesel fuel is deteriorated when the cylinder pressure is excessively lowered by throttling. The increase in pilot gas oil amount is effective for low-load operation and the adequate combination of throttle control and equivalence ratio ensures low hydrocarbon emission and the thermal efficiency comparable to diesel operation. (author)

  8. Greenhouse gas emissions in salt marshes and their response to nitrogen loading

    Science.gov (United States)

    Tang, J.; Moseman-Valtierra, S.; Kroeger, K. D.; Morkeski, K.; Carey, J.

    2015-12-01

    Salt marshes play an important role in global and regional carbon and nitrogen cycling. Anthropogenic nitrogen loading may alter greenhouse gas (GHG, including CO2, CH4, and N2O) emissions and carbon sequestration in salt marshes. We measured GHG emissions biweekly for two growing seasons across a nitrogen-loading gradient of four Spartina salt marshes in Waquoit Bay, Massachusetts. In addition, we conducted nitrogen addition experiments in a pristine marsh by adding low and high nitrate bi-weekly during the summer. The GHG flux measurements were made in situ with a state-of-the-art mobile gas measurement system using the cavity ring down technology that consists of a CO2/CH4 analyzer (Picarro) and an N2O/CO analyzer (Los Gatos). We observed strong seasonal variations in greenhouse gas emissions. The differences in gas emissions across the nitrogen gradient (between 1 and 10 gN m-2y-1) were not significant, but strong pulse emissions of N2O were observed after nitrogen was artificially added to the marsh. We found that the studied salt marsh was a significant carbon sink (NEP ~ 380 gC m-2y-1). CH4 fluxes are 3 orders of magnitude less than CO2 fluxes in the salt marsh. Carbon fluxes are driven by light, salinity, tide, and temperature. We conclude that restoration or conservation of this carbon sink has a significant social benefit for carbon credit.

  9. [Effects of superphosphate addition on NH3 and greenhouse gas emissions during vegetable waste composting].

    Science.gov (United States)

    Yang, Yan; Sun, Qin-ping; Li, Ni; Liu, Chun-sheng; Li, Ji-jin; Liu, Ben-sheng; Zou, Guo-yuan

    2015-01-01

    To study the effects of superphosphate (SP) on the NH, and greenhouse gas emissions, vegetable waste composting was performed for 27 days using 6 different treatments. In addition to the controls, five vegetable waste mixtures (0.77 m3 each) were treated with different amounts of the SP additive, namely, 5%, 10%, 15%, 20% and 25%. The ammonia volatilization loss and greenhouse gas emissions were measured during composting. Results indicated that the SP additive significantly decreased the ammonia volatilization and greenhouse gas emissions during vegetable waste composting. The additive reduced the total NH3 emission by 4.0% to 16.7%. The total greenhouse gas emissions (CO2-eq) of all treatments with SP additives were decreased by 10.2% to 20.8%, as compared with the controls. The NH3 emission during vegetable waste composting had the highest contribution to the greenhouse effect caused by the four different gases. The amount of NH3 (CO2-eq) from each treatment ranged from 59.90 kg . t-1 to 81.58 kg . t-1; NH3(CO2-eq) accounted for 69% to 77% of the total emissions from the four gases. Therefore, SP is a cost-effective phosphorus-based fertilizer that can be used as an additive during vegetable waste composting to reduce the NH3 and greenhouse gas emissions as well as to improve the value of compost as a fertilizer.

  10. Quantifying the relative contribution of natural gas fugitive emissions to total methane emissions in Colorado, Utah, and Texas using mobile δ13CH4 analysis

    Science.gov (United States)

    Rella, C.; Crosson, E.; Petron, G.; Sweeney, C.; Karion, A.

    2013-12-01

    Fugitive emissions of methane into the atmosphere are a major concern facing the natural gas production industry. Because methane is more energy-rich than coal per kg of CO2 emitted into the atmosphere, it represents an attractive alternative to coal for electricity generation, provided that the fugitive emissions of methane are kept under control. A key step in assessing these emissions in a given region is partitioning the observed methane emissions between natural gas fugitive emissions and other sources of methane, such as from landfills or agricultural activities. One effective method for assessing the contribution of these different sources is stable isotope analysis, using the δ13CH4 signature to distinguish between natural gas and landfills or ruminants. We present measurements of mobile field δ13CH4 using a spectroscopic stable isotope analyzer based on cavity ringdown spectroscopy, in three intense natural gas producing regions of the United States: the Denver-Julesburg basin in Colorado, the Uintah basin in Utah, and the Barnett Shale in Texas. Mobile isotope measurements of individual sources and in the nocturnal boundary layer have been combined to establish the fraction of the observed methane emissions that can be attributed to natural gas activities. The fraction of total methane emissions in the Denver-Julesburg basin attributed to natural gas emissions is 78 +/- 13%. In the Uinta basin, which has no other significant sources of methane, the fraction is 96% +/- 15%. In addition, results from the Barnett shale are presented, which includes a major urban center (Dallas / Ft. Worth). Methane emissions in this region are spatially highly heterogeneous. Spatially-resolved isotope and concentration measurements are interpreted using a simple emissions model to arrive at an overall isotope ratio for the region. (left panel) Distribution of oil and gas well pads (yellow) and landfills (blue) in the Dallas / Ft. Worth area. Mobile nocturnal measurements

  11. Greenhouse Gas Emissions from Asphalt Pavement Construction: A Case Study in China.

    Science.gov (United States)

    Ma, Feng; Sha, Aimin; Lin, Ruiyu; Huang, Yue; Wang, Chao

    2016-03-22

    In China, the construction of asphalt pavement has a significant impact on the environment, and energy use and greenhouse gas (GHG) emissions from asphalt pavement construction have been receiving increasing attention in recent years. At present, there is no universal criterion for the evaluation of GHG emissions in asphalt pavement construction. This paper proposes to define the system boundaries for GHG emissions from asphalt pavement by using a process-based life cycle assessment method. A method for evaluating GHG emissions from asphalt pavement construction is suggested. The paper reports a case study of GHG emissions from a typical asphalt pavement construction project in China. The results show that the greenhouse gas emissions from the mixture mixing phase are the highest, and account for about 54% of the total amount. The second highest GHG emission phase is the production of raw materials. For GHG emissions of cement stabilized base/subbase, the production of raw materials emits the most, about 98%. The GHG emission for cement production alone is about 92%. The results indicate that any measures to reduce GHG emissions from asphalt pavement construction should be focused on the raw materials manufacturing stage. If the raw materials production phase is excluded, the measures to reduce GHG emissions should be aimed at the mixture mixing phase.

  12. CANDU reactors and greenhouse gas emissions

    International Nuclear Information System (INIS)

    Andseta, S.; Thompson, M.J.; Jarrell, J.P.; Pendergast, D.R.

    1999-01-01

    This paper was originally presented at the 11th Pacific Basin Nuclear Conference, Banff, Alberta, Canada, May 3-7, 1998. It has been updated to include additional lifecycle data on chemical releases from ore treatment and CANDU fuel fabrication. It is sometimes stated that nuclear power plants can supply electricity with zero emissions of greenhouse gases. In fact, consideration of the entire fuel cycle indicates that some greenhouse gases are generated during their construction and decommissioning and by the preparation of fuel and other materials required for their operation. This follows from the use of fossil fuels in the preparation of materials and during the construction and decommissioning of the plants. This paper reviews life cycle studies of several different kinds of power plants. Greenhouse gases generated by fossil fuels during the preparation of fuel and heavy water used by operating CANDU power plants are estimated. The total greenhouse gas emissions from CANDU nuclear plants, per unit of electricity ultimately produced, are very small in comparison with emissions from most other types of power plants. (author)

  13. CANDU reactors and greenhouse gas emissions

    International Nuclear Information System (INIS)

    Andseta, S.; Thompson, M.J.; Jarrell, J.P.; Pendergast, D.R.

    1998-01-01

    This paper was originally presented at the 11th Pacific Basin Nuclear Conference, Banff, Alberta, Canada, May 3-7, 1998. It has been updated to include additional lifecycle data on chemical releases from ore treatment and CANDU fuel fabrication. It is sometimes stated that nuclear power plants can supply electricity with zero emissions of greenhouse gases. In fact, consideration of the entire fuel cycle indicates that some greenhouse gases are generated during their construction and decommissioning and by the preparation of fuel and other materials required for their operation. This follows from the use of fossil fuels in the preparation of materials and during the construction and decommissioning of the plants. This paper reviews life cycle studies of several different kinds of power plants. Greenhouse gases generated by fossil fuels during the preparation of fuel and heavy water used by operating CANDU power plants are estimated. The total greenhouse gas emissions from CANDU nuclear plants, per unit of electricity ultimately produced, are very small in comparison with emissions from most other types of power plants. (author)

  14. Greenhouse gas emissions from beef cattle pen surfaces in North Dakota.

    Science.gov (United States)

    Rahman, Shafiqur; Borhan, Md Saidul; Swanson, Kendall

    2013-01-01

    There is a global interest to quantify and mitigate greenhouse gas (GHG) (e.g. methane-CH4, nitrous oxide-N2O and carbon dioxide-CO2) emissions in animal feeding operations. The goal of this study was to quantify GHG emissions from the feedlot pen surface under North Dakota climatic conditions. In this study gaseous flux from the pen surfaces was generated using a custom-made wind tunnel at different times of the year (summer, fall, winter and spring). Gaseous fluxes (air samples) were drawn in the Tedlar bags using a vacuum chamber and gas concentrations were measured using a gas chromatograph within 24 h of sampling. The CH4 concentrations and flux rates (FRs) or flux among the months were not significantly different. Overall CH4, CO2 and N2O concentrations over a 7-month period were 2.66, 452 and 0.67 ppm, respectively. Estimated overall CH4, CO and N2O FRs were 1.32, 602 and 0.90 g m(-2) d(-1), respectively. Estimated emission rates using the wind tunnel were 38 g hd(-1) d(-1), 17 kg hd(-1) d(-1) and 26 g hd(-1) d(-1) for CH4, CO2 and N2O, respectively. The emission factors for GHG estimated in the research for North Dakota climate were the first of its kind, and these emission estimates can be used as a basis for planning and implementing management practices to minimize GHG emissions.

  15. Emissions from oil and gas operations in the United States and their air quality implications.

    Science.gov (United States)

    Allen, David T

    2016-06-01

    The energy supply infrastructure in the United States has been changing dramatically over the past decade. Increased production of oil and natural gas, particularly from shale resources using horizontal drilling and hydraulic fracturing, made the United States the world's largest producer of oil and natural gas in 2014. This review examines air quality impacts, specifically, changes in greenhouse gas, criteria air pollutant, and air toxics emissions from oil and gas production activities that are a result of these changes in energy supplies and use. National emission inventories indicate that volatile organic compound (VOC) and nitrogen oxide (NOx) emissions from oil and gas supply chains in the United States have been increasing significantly, whereas emission inventories for greenhouse gases have seen slight declines over the past decade. These emission inventories are based on counts of equipment and operational activities (activity factors), multiplied by average emission factors, and therefore are subject to uncertainties in these factors. Although uncertainties associated with activity data and missing emission source types can be significant, multiple recent measurement studies indicate that the greatest uncertainties are associated with emission factors. In many source categories, small groups of devices or sites, referred to as super-emitters, contribute a large fraction of emissions. When super-emitters are accounted for, multiple measurement approaches, at multiple scales, produce similar results for estimated emissions. Challenges moving forward include identifying super-emitters and reducing their emission magnitudes. Work done to date suggests that both equipment malfunction and operational practices can be important. Finally, although most of this review focuses on emissions from energy supply infrastructures, the regional air quality implications of some coupled energy production and use scenarios are examined. These case studies suggest that both

  16. Assessing fugitive emissions of CH4 from high-pressure gas pipelines in the UK

    Science.gov (United States)

    Clancy, S.; Worrall, F.; Davies, R. J.; Almond, S.; Boothroyd, I.

    2016-12-01

    Concern over the greenhouse gas impact of the exploitation of unconventional natural gas from shale deposits has caused a spotlight to be shone on to the entire hydrocarbon industry. Numerous studies have developed life-cycle emissions inventories to assess the impact that hydraulic fracturing has upon greenhouse gas emissions. Incorporated within life-cycle assessments are transmission and distribution losses, including infrastructure such as pipelines and compressor stations that pressurise natural gas for transport along pipelines. Estimates of fugitive emissions from transmission, storage and distribution have been criticized for reliance on old data from inappropriate sources (1970s Russian gas pipelines). In this study, we investigate fugitive emissions of CH4 from the UK high pressure national transmission system. The study took two approaches. Firstly, CH4 concentration is detected by driving along roads bisecting high pressure gas pipelines and also along an equivalent distance along a route where no high pressure gas pipeline was nearby. Five pipelines and five equivalent control routes were driven and the test was that CH4 measurements, when adjusted for distance and wind speed, should be greater on any route with a pipe than any route without a pipe. Secondly, 5 km of a high pressure gas pipeline and 5 km of equivalent farmland, were walked and soil gas (above the pipeline where present) was analysed every 7 m using a tunable diode laser. When wind adjusted 92 km of high pressure pipeline and 72 km of control route were drive over a 10 day period. When wind and distance adjusted CH4 fluxes were significantly greater on routes with a pipeline than those without. The smallest leak detectable was 3% above ambient (1.03 relative concentration) with any leaks below 3% above ambient assumed ambient. The number of leaks detected along the pipelines correlate to the estimated length of pipe joints, inferring that there are constant fugitive CH4 emissions from

  17. Greenhouse-gas emissions from soils increased by earthworms

    NARCIS (Netherlands)

    Lubbers, I.M.; Groenigen, van K.J.; Fonte, S.J.; Six, J.; Brussaard, L.; Groenigen, van J.W.

    2013-01-01

    Earthworms play an essential part in determining the greenhouse-gas balance of soils worldwide, and their influence is expected to grow over the next decades. They are thought to stimulate carbon sequestration in soil aggregates, but also to increase emissions of the main greenhouse gases carbon

  18. Use of landfill gas will save money and reduce emissions

    International Nuclear Information System (INIS)

    Espinosa, G.G.

    1991-01-01

    The City of Glendale, California has commenced on a project to transport landfill gas (LFG) from the Scholl Canyon Landfill to the Grayson Power Plant. At the plant the LFG will be used to produce electricity in existing steam electric generating units and combustion turbines. The LFG will reduce the natural gas consumed at the plant resulting in a substantial cost savings for the City. This project also offers significant environmental improvements. First, the elimination of flaring at the landfill will reduce emissions. Second, the LFG will reduce NO x emissions from the power plant. This paper will describe the existing collection system at the landfill as well as the design of the compression and piping system to transport the LFG to the power plant. It will also outline the in-plant modifications to the fuel delivery system and examine some of the emission implications of how the fuel is utilized

  19. Abatement of ammonia emissions from digested manure using gas-permeable membranes

    Science.gov (United States)

    A new strategy to avoid ammonia emissions from anaerobically digested swine manure was tested using the gas-permeable membrane process. Evaluation of the efficiency of ammonia recovery from digestate as well as mitigation of ammonia emissions to the atmosphere were carried out. Digestate was colle...

  20. Greenhouse gas emissions - a global challenge

    International Nuclear Information System (INIS)

    Aarebrot, Eivind; Langvik, Sveinung

    2000-01-01

    The article describes some greenhouse gas emission challenges in the Norwegian petroleum industry. Some of the conclusions are that the national taxation policies are insufficient and that international co-operation is essential in order to obtain significant pollution abatement. The mechanisms for this are not yet in place. Some possible measures are mentioned. The main solution to the problems internationally seems to be international co-operation projects generally with quota trade in order to meet the Kyoto agreement obligations

  1. UK emissions of the greenhouse gas nitrous oxide

    Science.gov (United States)

    Skiba, U.; Jones, S. K.; Dragosits, U.; Drewer, J.; Fowler, D.; Rees, R. M.; Pappa, V. A.; Cardenas, L.; Chadwick, D.; Yamulki, S.; Manning, A. J.

    2012-01-01

    Signatories of the Kyoto Protocol are obliged to submit annual accounts of their anthropogenic greenhouse gas emissions, which include nitrous oxide (N2O). Emissions from the sectors industry (3.8 Gg), energy (14.4 Gg), agriculture (86.8 Gg), wastewater (4.4 Gg), land use, land-use change and forestry (2.1 Gg) can be calculated by multiplying activity data (i.e. amount of fertilizer applied, animal numbers) with simple emission factors (Tier 1 approach), which are generally applied across wide geographical regions. The agricultural sector is the largest anthropogenic source of N2O in many countries and responsible for 75 per cent of UK N2O emissions. Microbial N2O production in nitrogen-fertilized soils (27.6 Gg), nitrogen-enriched waters (24.2 Gg) and manure storage systems (6.4 Gg) dominate agricultural emission budgets. For the agricultural sector, the Tier 1 emission factor approach is too simplistic to reflect local variations in climate, ecosystems and management, and is unable to take into account some of the mitigation strategies applied. This paper reviews deviations of observed emissions from those calculated using the simple emission factor approach for all anthropogenic sectors, briefly discusses the need to adopt specific emission factors that reflect regional variability in climate, soil type and management, and explains how bottom-up emission inventories can be verified by top-down modelling. PMID:22451103

  2. Analysis and control design of sustainable policies for greenhouse gas emissions

    International Nuclear Information System (INIS)

    Chu, Bing; Duncan, Stephen; Papachristodoulou, Antonis; Hepburn, Cameron

    2013-01-01

    Reducing greenhouse gas emissions is now an urgent priority. Systems control theory, and in particular feedback control, can be helpful in designing policies that achieve sustainable levels of emissions of CO 2 (and other greenhouse gases) while minimizing the impact on the economy, and at the same time explicitly addressing the high levels of uncertainty associated with predictions of future emissions. In this paper, we describe preliminary results for an approach where model predictive control (MPC) is applied to a model of the UK economy (UK 4see model) as a test bed to design sustainable policies for greenhouse gas emissions. Using feedback control, the policies are updated on the basis of the actual emissions, rather than on the predicted level of emissions. The basic structure and principle of the UK 4see model is described and its implementation in Simulink is presented. A linearized state space model is obtained and model predictive control is applied to design policies for CO 2 emissions. Simulation results are presented to demonstrate the effectiveness of the proposed method. The preliminary results obtained in this paper illustrate the strength of the proposed design approach and form the basis for future research on using systems control theory to design optimal sustainable policies

  3. Biofuels, land use change, and greenhouse gas emissions: some unexplored variables.

    Science.gov (United States)

    Kim, Hyungtae; Kim, Seungdo; Dale, Bruce E

    2009-02-01

    Greenhouse gas release from land use change (the so-called "carbon debt") has been identified as a potentially significant contributor to the environmental profile of biofuels. The time required for biofuels to overcome this carbon debt due to land use change and begin providing cumulative greenhouse gas benefits is referred to as the "payback period" and has been estimated to be 100-1000 years depending on the specific ecosystem involved in the land use change event. Two mechanisms for land use change exist: "direct" land use change, in which the land use change occurs as part of a specific supply chain for a specific biofuel production facility, and "indirect" land use change, in which market forces act to produce land use change in land that is not part of a specific biofuel supply chain, including, for example, hypothetical land use change on another continent. Existing land use change studies did not consider many of the potentially important variables that might affect the greenhouse gas emissions of biofuels. We examine here several variables that have not yet been addressed in land use change studies. Our analysis shows that cropping management is a key factor in estimating greenhouse gas emissions associated with land use change. Sustainable cropping management practices (no-till and no-till plus cover crops) reduce the payback period to 3 years for the grassland conversion case and to 14 years for the forest conversion case. It is significant that no-till and cover crop practices also yield higher soil organic carbon (SOC) levels in corn fields derived from former grasslands or forests than the SOC levels that result if these grasslands or forests are allowed to continue undisturbed. The United States currently does not hold any of its domestic industries responsible for its greenhouse gas emissions. Thus the greenhouse gas standards established for renewable fuels such as corn ethanol in the Energy Independence and Security Act (EISA) of 2007 set a

  4. Mechanisms of acid, weakly acidic and gas reflux after anti-reflux surgery

    NARCIS (Netherlands)

    Bredenoord, A. J.; Draaisma, W. A.; Weusten, B. L. A. M.; Gooszen, H. G.; Smout, A. J. P. M.

    2008-01-01

    BACKGROUND: Whereas it is well documented that fundoplication reduces acid reflux, the effects of the procedure on non-acid and gas reflux and the mechanisms through which this is achieved have not been fully elucidated. METHODS: In 14 patients, reflux was measured with impedance-pH monitoring

  5. How best management practices affect emissions in gas turbine power plants - an important factor to consider when strengthening emission standards.

    Science.gov (United States)

    Zeng, Jinghai; Xing, Min; Hou, Min; England, Glenn C; Yan, Jing

    2018-04-27

    The Beijing Municipal Environmental Protection Bureau (EPB) is considering strengthening the Emission Standard of Air Pollutants for Stationary Gas Turbines, originally published in 2011 (DB11/847-2011), with a focus on reducing nitrogen oxides (NOx) emissions. A feasibility study was conducted to evaluate the current operation of twelve (12) existing combined-cycle gas turbine power plants and the design of two (2) new plants in Beijing and their emission reduction potential, in comparison with a state-of-the-art power plant in California, United States. The study found that Best Management Practices (BMPs) could potentially improve the emission level of the power plants, and should be implemented to minimize emissions under current design characteristics. These BMPs include (1) more frequent tuning of turbine combustors; (2) onsite testing of natural gas characteristics in comparison to turbine manufacturer's specifics and tuning of turbine to natural gas quality; (3) onsite testing of aqueous ammonia to ensure adequate ammonia concentration in the mixed solution, and the purity of the solution; (4) more careful inspection of the heat recovery steam generator (HRSG), and the selective catalytic reduction (SCR) during operation and maintenance; (5) annual testing of the catalyst coupon on the SCR to ensure catalyst effectiveness; and (6) annual ammonia injection grid (AIG) tuning. The study found that without major modification to the plants, improving the management of the Beijing gas turbine power plants may potentially reduce the current hourly-average NOx emission level of 5-10 parts per million (ppm, ranges reflects plant variation) by up to 20%. The exact improvement associated with each BMP for each facility requires more detailed analysis, and requires engagement of turbine, HRSG, and SCR manufacturers. This potential improvement is an important factor to consider when strengthening the emission standard. However it is to be noted that with the continuous

  6. Natural-gas fueled spark-ignition (SI) and compression-ignition (CI) engine performance and emissions

    Energy Technology Data Exchange (ETDEWEB)

    Korakianitis, T.; Namasivayam, A.M.; Crookes, R.J. [School of Engineering and Materials Science, Queen Mary University of London (United Kingdom)

    2011-02-15

    Natural gas is a fossil fuel that has been used and investigated extensively for use in spark-ignition (SI) and compression-ignition (CI) engines. Compared with conventional gasoline engines, SI engines using natural gas can run at higher compression ratios, thus producing higher thermal efficiencies but also increased nitrogen oxide (NO{sub x}) emissions, while producing lower emissions of carbon dioxide (CO{sub 2}), unburned hydrocarbons (HC) and carbon monoxide (CO). These engines also produce relatively less power than gasoline-fueled engines because of the convergence of one or more of three factors: a reduction in volumetric efficiency due to natural-gas injection in the intake manifold; the lower stoichiometric fuel/air ratio of natural gas compared to gasoline; and the lower equivalence ratio at which these engines may be run in order to reduce NO{sub x} emissions. High NO{sub x} emissions, especially at high loads, reduce with exhaust gas recirculation (EGR). However, EGR rates above a maximum value result in misfire and erratic engine operation. Hydrogen gas addition increases this EGR threshold significantly. In addition, hydrogen increases the flame speed of the natural gas-hydrogen mixture. Power levels can be increased with supercharging or turbocharging and intercooling. Natural gas is used to power CI engines via the dual-fuel mode, where a high-cetane fuel is injected along with the natural gas in order to provide a source of ignition for the charge. Thermal efficiency levels compared with normal diesel-fueled CI-engine operation are generally maintained with dual-fuel operation, and smoke levels are reduced significantly. At the same time, lower NO{sub x} and CO{sub 2} emissions, as well as higher HC and CO emissions compared with normal CI-engine operation at low and intermediate loads are recorded. These trends are caused by the low charge temperature and increased ignition delay, resulting in low combustion temperatures. Another factor is

  7. Open-source LCA tool for estimating greenhouse gas emissions from crude oil production using field characteristics.

    Science.gov (United States)

    El-Houjeiri, Hassan M; Brandt, Adam R; Duffy, James E

    2013-06-04

    Existing transportation fuel cycle emissions models are either general and calculate nonspecific values of greenhouse gas (GHG) emissions from crude oil production, or are not available for public review and auditing. We have developed the Oil Production Greenhouse Gas Emissions Estimator (OPGEE) to provide open-source, transparent, rigorous GHG assessments for use in scientific assessment, regulatory processes, and analysis of GHG mitigation options by producers. OPGEE uses petroleum engineering fundamentals to model emissions from oil and gas production operations. We introduce OPGEE and explain the methods and assumptions used in its construction. We run OPGEE on a small set of fictional oil fields and explore model sensitivity to selected input parameters. Results show that upstream emissions from petroleum production operations can vary from 3 gCO2/MJ to over 30 gCO2/MJ using realistic ranges of input parameters. Significant drivers of emissions variation are steam injection rates, water handling requirements, and rates of flaring of associated gas.

  8. Organic Rankine cycle saves energy and reduces gas emissions for cement production

    International Nuclear Information System (INIS)

    Wang, Huarong; Xu, Jinliang; Yang, Xufei; Miao, Zheng; Yu, Chao

    2015-01-01

    We investigated ORCs (organic Rankine cycles) integrated with typical China cement production line. The dry air at the kiln cooler outlet with the temperature of 220 °C was the waste heat. The fluids of hexane, isohexane, R601, R123 and R245fa were selected for ORCs based on the critical temperature criterion. The developed ORC verified the thermodynamics analysis. The NPV (net present value) and PBP (payback period) methods were applied to evaluate the economic performance. The LCA (life cycle assessment) was applied to evaluate the environment impacts. ORCs could generate 67,85,540–81,21,650 kWh electricity per year, equivalent to save 2035–2436 tons standard coal and reduce 7743–9268 tons CO 2 emission, for a 4000 t/d cement production line. ORCs reduced gas emissions of CO 2 by 0.62–0.74%, SO 2 by 3.83–4.59% and NO x by 1.36–1.63%. The PBP (payback period) was 2.74–3.42 years. The ORCs had the reduction ratios of EIL (environment impact load) by 1.49–1.83%, GWP (global warming potential) by 0.74–0.92%, AP (acidification potential) by 2.34–2.84%, EP (eutrophication potential) by 0.96–1.22% and HTP (human toxicity potential) by 2.38–2.89%. The ORC with R601 as the fluid had the best economic performance and significant gas emission reductions. ORCs had good economic performance and reduce the gas emissions. - Highlights: • Organic Rankine Cycles were integrated with the cement production line. • Five organic fluids were used as the working fluids for ORCs. • Thermal, economic and gas emission performances were analyzed. • R601 was the best fluid for ORC with the heat source temperature of 220 °C. • ORCs had good economic and gas emission reduction performances

  9. NOAA Mobile Laboratory Measures Oil and Gas Emissions

    Science.gov (United States)

    Kofler, J. D.; Petron, G.; Dube, W. P.; Edwards, P. M.; Brown, S. S.; Geiger, F.; Patrick, L.; Crepinsek, S.; Chen, H.; Miller, B. R.; Montzka, S. A.; Lang, P. M.; Newberger, T.; Higgs, J. A.; Sweeney, C.; Guenther, D.; Karion, A.; Wolter, S.; Williams, J.; Jordan, A.; Tans, P. P.; Schnell, R. C.

    2012-12-01

    A van capable of continuous real time measurements of CH4 , CO2, CO, Water Vapor, Ozone, NO, NO2, Volatile Organic Compounds VOCs including aromatics and other traces gases was driven in the oil and gas fields of the Uintah Basin in northeastern Utah. Compressor Stations, processing plants, oil and gas well heads. Separators, condensate tanks, evaporation pond disposal facilities, holding tanks, hydraulic fracturing sites, gas pipelines and more were studied using the van. The mobile measurements provide a powerful tool to get to the source of the emissions and reveal the unique chemical signature of each of the stages and components of oil and gas production as well as the overall basin and background gas concentrations. In addition to a suite of gas analyzers, the van includes a meteorological system (temperature, humidity, and wind speed and direction), GPS tracking, flask sampling system and a batter power system. Aspects of the vans hardware, sampling methods and operations are discussed along with a few highlights of the measurements.

  10. Correlation between arterial blood gas analysis and peripheral blood gas analysis in acid-base unbalance state

    Directory of Open Access Journals (Sweden)

    Hyun Lee Kim

    2012-06-01

    Full Text Available Acid-base unbalance is most common problem in severe ill patient, especially in condition of abnormal renal function state. Acid-base unbalances are respiratory acidosis, respiratory alkalosis, metabolic acidosis, and metabolic alkalosis. Metabolic acidosis is frequently appeared in clinical state. Arterial blood gas analysis is considered as a basic test to the intensive care unit patient and emergency state. Recently some researches were done, comparing with arterial blood gas analysis and venous blood gas analysis. Because of venous blood sampling is safer than arterial blood gas analysis, and beside not so different among them for detecting pH, pCO2, HCO3, except pO2 measuring. This research was done in emergency room, and for explaining no different between arterial blood gas analysis and peripheral blood gas analysis result in acid-base unbalance state patient. Especially in kidney functions decreased state. : The study was done from March, 2010 to January, 2011. The object was 89 peoples who came to emergency room for treating internal medicine problem. (Women 53, average age: 66.7±12.1 Then compare between arterial blood gas analysis and peripheral blood gas analysis. Result: The mean arterial minus venous difference for pH, pCO2, and bicarbonate was −0.0170, 2.6528, and 0.6124. Bland-Altman plot was done for predicting agreement of two groups, and the scale was pH −2.95 to 4.17, pCO2 −4.45 to 9.76, bicarbonate −2.95 to 4.16, in 95% relative. Conclusion: The peripheral blood gas pH, pCO2, bicarbonate level is almost same as arterial blood gas analysis results. And enough to measuring acid-base unbalance state, in absent of arterial blood testing.

  11. Room chamber assessment of the pollutant emission properties of (nominally) low-emission unflued gas heaters

    Energy Technology Data Exchange (ETDEWEB)

    Brown, S.K.; Mahoney, K.J., Min Cheng [CSIRO Manufacturing and Infrastructure Technology, Victoria (Australia)

    2004-07-01

    Pollutant emissions from unflued gas heaters were assessed in CSIRO'a Room Dynamic Environmental Chamber. This paper describes the chamber assessment procedure and presents findings for major commercial heaters that are nominally 'low-emission'. The chamber was operated at controlled conditions of temperature, humidity, ventilation and air mixing, representative of those encountered in typical indoor environments. A fixed rate of heat removal from the chamber air ensured that the heaters operated at constant heating rates, typically {approx}6 MJ/h which simulated operation of a heater after warm-up in an insulated dwelling in south-east Australia. The pollutants assessed were nitrogen dioxide, carbon monoxide, formaldehyde, VOCs and respirable suspended particulates. One type of heater was lower emitting for nigroen dioxide, but emitted greater amounts of carbon monoxide and formaldehyde (the latter becoming significant to indoor air quality). When operated with low line pressure of slight misalignment of the gas burner, this heater became a hazardous source of these pollutants. Emissions from the heates changed little after continous operation for up to 2 months. (au)

  12. Greenhouse effect gas emission: an assessment without measuring; Emissions de gaz a effet de serre: une mesure sans capteur

    Energy Technology Data Exchange (ETDEWEB)

    Anon.

    2005-02-01

    The European directive 2003/87/CE creates a market for greenhouse effect gases (GEG) emission quotas. The setting of this market implies for each enterprise to make an inventory of its own GEG emissions. The gases involved in this assessment are those concerned in international agreements, namely CO{sub 2}, CH{sub 4}, N{sub 2}O, C{sub n}H{sub m}F{sub p}, C{sub n}F{sub 2n+2} and SF{sub 6}. The French agency for the environment and the management of energy (ADEME) proposes a method to make a consistent inventory that is based on equivalencies that are listed, for instance the production of a ton of steel generates 870 kg of carbon emission equivalent, this value falls to 300 kg in the case of steel made from recycled materials, another example: the extraction and the transport to the refinery of one ton of crude oil represents 61 kg of carbon emission equivalent. 3 levels of completion are considered: the first level takes into account only the gas emissions that follow directly from the enterprise's activities. The second level adds to the first level the gas emissions due to the transport of energy, goods and people involved in the enterprise's activities. The third level integrates to the second level the gas emissions issued from the production of the energy and goods necessary to the enterprise's activities. The lack of accuracy of this method is assessed to be less than 20% in the best cases. (A.C.)

  13. Constraining Methane Emissions from Natural Gas Production in Northeastern Pennsylvania Using Aircraft Observations and Mesoscale Modeling

    Science.gov (United States)

    Barkley, Z.; Davis, K.; Lauvaux, T.; Miles, N.; Richardson, S.; Martins, D. K.; Deng, A.; Cao, Y.; Sweeney, C.; Karion, A.; Smith, M. L.; Kort, E. A.; Schwietzke, S.

    2015-12-01

    Leaks in natural gas infrastructure release methane (CH4), a potent greenhouse gas, into the atmosphere. The estimated fugitive emission rate associated with the production phase varies greatly between studies, hindering our understanding of the natural gas energy efficiency. This study presents a new application of inverse methodology for estimating regional fugitive emission rates from natural gas production. Methane observations across the Marcellus region in northeastern Pennsylvania were obtained during a three week flight campaign in May 2015 performed by a team from the National Oceanic and Atmospheric Administration (NOAA) Global Monitoring Division and the University of Michigan. In addition to these data, CH4 observations were obtained from automobile campaigns during various periods from 2013-2015. An inventory of CH4 emissions was then created for various sources in Pennsylvania, including coalmines, enteric fermentation, industry, waste management, and unconventional and conventional wells. As a first-guess emission rate for natural gas activity, a leakage rate equal to 2% of the natural gas production was emitted at the locations of unconventional wells across PA. These emission rates were coupled to the Weather Research and Forecasting model with the chemistry module (WRF-Chem) and atmospheric CH4 concentration fields at 1km resolution were generated. Projected atmospheric enhancements from WRF-Chem were compared to observations, and the emission rate from unconventional wells was adjusted to minimize errors between observations and simulation. We show that the modeled CH4 plume structures match observed plumes downwind of unconventional wells, providing confidence in the methodology. In all cases, the fugitive emission rate was found to be lower than our first guess. In this initial emission configuration, each well has been assigned the same fugitive emission rate, which can potentially impair our ability to match the observed spatial variability

  14. Quantifying the relative contribution of natural gas fugitive emissions to total methane emissions in Colorado and Utah using mobile stable isotope (13CH4) analysis

    Science.gov (United States)

    Rella, Chris; Jacobson, Gloria; Crosson, Eric; Karion, Anna; Petron, Gabrielle; Sweeney, Colm

    2013-04-01

    Fugitive emissions of methane into the atmosphere are a major concern facing the natural gas production industry. Because methane is more energy-rich than coal per kg of CO2 emitted into the atmosphere, it represents an attractive alternative to coal for electricity generation. However, given that the global warming potential of methane is many times greater than that of carbon dioxide (Solomon et al. 2007), the importance of quantifying the fugitive emissions of methane throughout the natural gas production and distribution process becomes clear (Howarth et al. 2011). A key step in the process of assessing the emissions arising from natural gas production activities is partitioning the observed methane emissions between natural gas fugitive emissions and other sources of methane, such as from landfills or agricultural activities. One effective method for assessing the contribution of these different sources is stable isotope analysis. In particular, the 13CH4 signature of natural gas (-35 to -40 permil) is significantly different that the signature of other significant sources of methane, such as landfills or ruminants (-45 to -70 permil). In this paper we present measurements of mobile field 13CH4 using a spectroscopic stable isotope analyzer based on cavity ringdown spectroscopy, in two intense natural gas producing regions of the United States: the Denver-Julesburg basin in Colorado, and the Uintah basin in Utah. Mobile isotope measurements in the nocturnal boundary layer have been made, over a total path of 100s of km throughout the regions, allowing spatially resolved measurements of the regional isotope signature. Secondly, this analyzer was used to quantify the isotopic signature of those individual sources (natural gas fugitive emissions, concentrated animal feeding operations, and landfills) that constitute the majority of methane emissions in these regions, by making measurements of the isotope ratio directly in the downwind plume from each source. These

  15. Combustion and emission characteristics of a natural gas-fueled diesel engine with EGR

    International Nuclear Information System (INIS)

    Abdelaal, M.M.; Hegab, A.H.

    2012-01-01

    Highlights: ► An existed DI diesel engine has been modified to suit dual fuel operation with EGR. ► Comparative study has been conducted between different operating modes. ► Dual fuel mode exhibits better performance at high loads than diesel. ► Dual fuel mode exhibits lower NOx and higher HC emissions than diesel. ► EGR improves performance at part loads and emissions of dual fuel mode. - Abstract: The use of natural gas as a partial supplement for liquid diesel fuel is a very promising solution for reducing pollutant emissions, particularly nitrogen oxides (NOx) and particulate matters (PM), from conventional diesel engines. In most applications of this technique, natural gas is inducted or injected in the intake manifold to mix uniformly with air, and the homogenous natural gas–air mixture is then introduced to the cylinder as a result of the engine suction. This type of engines, referred to as dual-fuel engines, suffers from lower thermal efficiency and higher carbon monoxide (CO) and unburned hydrocarbon (HC) emissions; particularly at part load. The use of exhaust gas recirculation (EGR) is expected to partially resolve these problems and to provide further reduction in NOx emission as well. In the present experimental study, a single-cylinder direct injection (DI) diesel engine has been properly modified to run on dual-fuel mode with natural gas as a main fuel and diesel fuel as a pilot, with the ability to employ variable amounts of EGR. Comparative results are given for various operating modes; conventional diesel mode, dual-fuel mode without EGR, and dual-fuel mode with variable amounts of EGR, at different operating conditions; revealing the effect of utilization of EGR on combustion process and exhaust emission characteristics of a pilot ignited natural gas diesel engine.

  16. Emission of Gas and Al2O3 Smoke in Gas-Al Particle Deflagration: Experiments and Emission Modeling for Explosive Fireballs

    Science.gov (United States)

    Ranc-Darbord, Isabelle; Baudin, Gérard; Genetier, Marc; Ramel, David; Vasseur, Pierre; Legrand, Julien; Pina, Vincent

    2018-03-01

    Emission of gas and Al2O3 smoke within the deflagration of H2{-}O2-{N2{-}CO2}-Al particles has been studied in a closed combustion chamber at pressures of up to 18 bar and at gas temperatures of up to 3700 K. Measurements of radiance intensity were taken using a five wavelength pyrometer (0.660 μ m, 0.850 μ m, 1.083 μ m, 1.260 μ m, 1.481 μ m) and a grating spectrometer in the range (4.10 μ m to 4.30 μ m). In order to characterize the aluminum oxide smoke size and temperature, an inversion method has been developed based on the radiation transfer equation and using pyrometer measurements and thermochemical calculations of Al2O3 smoke volume fractions. Temperatures in combustion gas have been determined using a method based on the assumed blackbody head of the 4.26 μ m CO2 emission line and on its spectral shift with pressure and temperature. For validation purpose, this method has been applied to measurements obtained when calibrated alumina particles are injected in a combustion chamber prior to gaseous deflagrations. This mathematical inversion method was developed to investigate explosive fireballs.

  17. Emission reductions through precombustion chamber design in a natural gas, lean burn engine

    International Nuclear Information System (INIS)

    Crane, M.E.; King, S.R.

    1992-01-01

    A study was conducted to evaluate the effects of various precombustion chamber design, operating and control parameters on the exhaust emissions of a natural gas engine. Analysis of the results showed that engine-out total hydrocarbons and oxides of nitrogen (NO x ) can be reduced, relative to conventional methods, through prechamber design. More specifically, a novel staged prechamber yielded significant reductions in NO x and total hydrocarbon emissions by promoting stable prechamber and main chamber ignition under fuel-lean conditions. Precise fuel control was also critical when balancing low emissions and engine efficiency (i.e., fuel economy). The purpose of this paper is to identify and explain positive and deleterious effects of natural gas prechamber design on exhaust emissions

  18. Pile mixing increases greenhouse gas emissions during composting of dairy manure

    Science.gov (United States)

    The effect of pile mixing on greenhouse gas (GHG) emissions from stored dairy manure was determined using large flux chambers designed to completely cover pilot-scale manure piles. GHG emissions from piles that were mixed four times during the 80 day trial were about 20% higher than unmixed piles. ...

  19. Trace gas emissions from a sun and shade grown ornamental crop

    Science.gov (United States)

    Previous work has begun to establish baseline approximations for greenhouse gas (GHG) (CO2, CH4, and N2O) emissions of several horticultural crops, though much work is still needed to expand contingencies for multiple best management practices. In this study, GHG emissions from one shade-grown speci...

  20. METHANE EMISSIONS FROM THE NATURAL GAS INDUSTRY VOLUME 1: EXECUTIVE SUMMARY

    Science.gov (United States)

    The 15-volume report summarizes the results of a comprehensive program to quantify methane (CH4) emissions from the U.S. natural gas industry for the base year. The objective was to determine CH4 emissions from the wellhead and ending downstream at the customer's meter. The accur...

  1. Energy consumption and GHG emissions from the upstream oil and gas sector in Canada: an overview

    International Nuclear Information System (INIS)

    Bhargava, A.; Timilsina, G.

    2004-01-01

    After electricity generation, the oil and gas sector is the most emission intensive industry in Canada. This paper presents statistical data and research by the Canadian Energy Research Institute (CERI). The aim of the research was to provide a comparative evaluation between Alberta's energy consumption and Canada-wide consumption. Data revealed that energy consumption and greenhouse gas (GHG) emissions have increased faster in Alberta in comparison to the rest of Canada, but have slowed since 1997, while emissions in the rest of Canada still continued to increase. Aggregate emission intensities were presented. It was noted that there were no significant changes in fuel mix in either Alberta or the country as a whole. Key factors contributing to rapid increase in energy consumption and GHG emissions after 1996 were: increased energy intensive production and increased use of natural gas. Charts of oil and gas use were presented in energy consumption, economic output and GHG emissions, also indicating that Canadian trends followed Alberta trends. A list of reduction measures in the oil and gas sector were provided, with figures of total reductions and cost. Future actions were outlined and included: ratification of the Kyoto Accord, the negotiation of sectoral agreements, important elements such as cost cap and percentages of reduction; the limited ability to reduce emissions at lower cost per tonne within the oil and gas sector; technology breakthroughs; and adoption of new practices such as the use of alternate fuels in energy intensive processes. tabs, figs

  2. Energy consumption and GHG emissions from the upstream oil and gas sector in Canada: an overview

    Energy Technology Data Exchange (ETDEWEB)

    Bhargava, A.; Timilsina, G. [Canadian Energy Research Inst., Calgary, AB (Canada)

    2004-07-01

    After electricity generation, the oil and gas sector is the most emission intensive industry in Canada. This paper presents statistical data and research by the Canadian Energy Research Institute (CERI). The aim of the research was to provide a comparative evaluation between Alberta's energy consumption and Canada-wide consumption. Data revealed that energy consumption and greenhouse gas (GHG) emissions have increased faster in Alberta in comparison to the rest of Canada, but have slowed since 1997, while emissions in the rest of Canada still continued to increase. Aggregate emission intensities were presented. It was noted that there were no significant changes in fuel mix in either Alberta or the country as a whole. Key factors contributing to rapid increase in energy consumption and GHG emissions after 1996 were: increased energy intensive production and increased use of natural gas. Charts of oil and gas use were presented in energy consumption, economic output and GHG emissions, also indicating that Canadian trends followed Alberta trends. A list of reduction measures in the oil and gas sector were provided, with figures of total reductions and cost. Future actions were outlined and included: ratification of the Kyoto Accord, the negotiation of sectoral agreements, important elements such as cost cap and percentages of reduction; the limited ability to reduce emissions at lower cost per tonne within the oil and gas sector; technology breakthroughs; and adoption of new practices such as the use of alternate fuels in energy intensive processes. tabs, figs.

  3. An Experimental and Computational Study of the Gas-Phase Acidities of the Common Amino Acid Amides.

    Science.gov (United States)

    Plummer, Chelsea E; Stover, Michele L; Bokatzian, Samantha S; Davis, John T M; Dixon, David A; Cassady, Carolyn J

    2015-07-30

    Using proton-transfer reactions in a Fourier transform ion cyclotron resonance mass spectrometer and correlated molecular orbital theory at the G3(MP2) level, gas-phase acidities (GAs) and the associated structures for amides corresponding to the common amino acids have been determined for the first time. These values are important because amino acid amides are models for residues in peptides and proteins. For compounds whose most acidic site is the C-terminal amide nitrogen, two ions populations were observed experimentally with GAs that differ by 4-7 kcal/mol. The lower energy, more acidic structure accounts for the majority of the ions formed by electrospray ionization. G3(MP2) calculations predict that the lowest energy anionic conformer has a cis-like orientation of the [-C(═O)NH](-) group whereas the higher energy, less acidic conformer has a trans-like orientation of this group. These two distinct conformers were predicted for compounds with aliphatic, amide, basic, hydroxyl, and thioether side chains. For the most acidic amino acid amides (tyrosine, cysteine, tryptophan, histidine, aspartic acid, and glutamic acid amides) only one conformer was observed experimentally, and its experimental GA correlates with the theoretical GA related to side chain deprotonation.

  4. Estimating mercury emissions from a zinc smelter in relation to China's mercury control policies

    International Nuclear Information System (INIS)

    Wang, S.X.; Song, J.X.; Li, G.H.; Wu, Y.; Zhang, L.; Wan, Q.; Streets, D.G.; Chin, Conrad K.; Hao, J.M.

    2010-01-01

    Mercury concentrations of flue gas at inlet/outlet of the flue gas cleaning, electrostatic demister, reclaiming tower, acid plant, and mercury contents in zinc concentrate and by-products were measured in a hydrometallurgical zinc smelter. The removal efficiency of flue gas cleaning, electrostatic demister, mercury reclaiming and acid plant was about 17.4%, 30.3%, 87.9% and 97.4% respectively. Flue gas cleaning and electrostatic demister captured 11.7% and 25.3% of the mercury in the zinc concentrate, respectively. The mercury reclaiming tower captured 58.3% of the mercury in the zinc concentrate. About 4.2% of the mercury in the zinc concentrate was captured by the acid plant. Consequently, only 0.8% of the mercury in the zinc concentrate was emitted to the atmosphere. The atmospheric mercury emission factor was 0.5 g t -1 of zinc produced for the tested smelter, indicating that this process offers the potential to effectively reduce mercury emissions from zinc smelting. - Modern scale production equipped with acid plant and Hg reclaiming tower will significantly reduce Hg emissions from zinc smelters in China.

  5. Greenhouse gas emission impacts of carsharing in North America

    Science.gov (United States)

    2010-06-01

    This report presents the results of a study evaluating the greenhouse gas (GHG) emission changes that result from individuals participating in a carsharing organization. In this study, the authors conducted a survey of carsharing members across the c...

  6. Trace gas emissions from burning Florida wetlands

    Science.gov (United States)

    Cofer, Wesley R.; Levine, Joel S.; Winstead, Edward L.; Lebel, Peter J.; Koller, Albert M.; Hinkle, C. Ross

    1990-02-01

    Measurements of biomass burn-produced trace gases are presented that were obtained using a helicopter at low altitudes above burning Florida wetlands on November 9, 1987, and from both helicopter and light-aircraft samplings on November 7, 1988. Carbon dioxide (CO2) normalized emission ratios (ΔX/ΔCO2; V/V; where X is trace gas) for carbon monoxide (CO), hydrogen (H2), methane (CH4), total nonmethane hydrocarbons (TNMHC), and nitrous oxide (N2O) were obtained over burning graminoid wetlands consisting primarily of Spartina bakeri and Juncus roemerianus. Some interspersed scrub oak (Quercus spp) and saw palmetto (Screnoa repens) were also burned. No significant differences were observed in the emission ratios determined for these gases from samples collected over flaming, mixed, and smoldering phases of combustion during the 1987 fire. Combustion-categorized differences in emission ratios were small for the 1988 fire. Combustion efficiency was relatively good (low emission ratios for reduced gases) for both fires. We believe that the consistently low emission ratios were a unique result of graminoid wetlands fires, in which the grasses and rushes (both small-size fuels) burned rapidly down to standing water and were quickly extinguished. Consequently, the efficiency of the combustion was good and the amount and duration of smoldering combustion was greatly diminished.

  7. Greenhouse gas emissions from solid waste in Beijing: The rising trend and the mitigation effects by management improvements.

    Science.gov (United States)

    Yu, Yongqiang; Zhang, Wen

    2016-04-01

    Disposal of solid waste poses great challenges to city managements. Changes in solid waste composition and disposal methods, along with urbanisation, can certainly affect greenhouse gas emissions from municipal solid waste. In this study, we analysed the changes in the generation, composition and management of municipal solid waste in Beijing. The changes of greenhouse gas emissions from municipal solid waste management were thereafter calculated. The impacts of municipal solid waste management improvements on greenhouse gas emissions and the mitigation effects of treatment techniques of greenhouse gas were also analysed. Municipal solid waste generation in Beijing has increased, and food waste has constituted the most substantial component of municipal solid waste over the past decade. Since the first half of 1950s, greenhouse gas emission has increased from 6 CO2-eq Gg y(-1)to approximately 200 CO2-eq Gg y(-1)in the early 1990s and 2145 CO2-eq Gg y(-1)in 2013. Landfill gas flaring, landfill gas utilisation and energy recovery in incineration are three techniques of the after-emission treatments in municipal solid waste management. The scenario analysis showed that three techniques might reduce greenhouse gas emissions by 22.7%, 4.5% and 9.8%, respectively. In the future, if waste disposal can achieve a ratio of 4:3:3 by landfill, composting and incineration with the proposed after-emission treatments, as stipulated by the Beijing Municipal Waste Management Act, greenhouse gas emissions from municipal solid waste will decrease by 41%. © The Author(s) 2016.

  8. Life cycle greenhouse gas emissions estimation for small hydropower schemes in India

    International Nuclear Information System (INIS)

    Varun; Prakash, Ravi; Bhat, I.K.

    2012-01-01

    This paper presents for the first time correlations for greenhouse gas (GHG) emissions from small hydropower schemes in India. In this paper an attempt has been made to develop life cycle GHG emissions correlations for three different types of small hydropower schemes (run-of river, canal based and dam-toe) in India. It has been found out that GHG emissions depend on the head and capacity of the small hydropower project. The results obtained from correlations show good agreement with the estimated results using EIO-LCA (Economic Input–Output-Life Cycle Assessment) technique. These correlations may be useful for the development of new small hydropower (SHP) schemes, as they can be used to predict life cycle GHG emissions based on capacity, head and type of SHP schemes. -- Highlights: ► A study has been carried out for the Life Cycle Greenhouse gas emissions estimation for SHP schemes in India. ► Around 145 SHP schemes have been studied and their GHG emissions have been estimated. ► Based upon these results correlations have been developed for three different types of SHP schemes.

  9. Fuel use and greenhouse gas emissions of world fisheries

    Science.gov (United States)

    Parker, Robert W. R.; Blanchard, Julia L.; Gardner, Caleb; Green, Bridget S.; Hartmann, Klaas; Tyedmers, Peter H.; Watson, Reg A.

    2018-04-01

    Food production is responsible for a quarter of anthropogenic greenhouse gas (GHG) emissions globally. Marine fisheries are typically excluded from global assessments of GHGs or are generalized based on a limited number of case studies. Here we quantify fuel inputs and GHG emissions for the global fishing fleet from 1990-2011 and compare emissions from fisheries to those from agriculture and livestock production. We estimate that fisheries consumed 40 billion litres of fuel in 2011 and generated a total of 179 million tonnes of CO2-equivalent GHGs (4% of global food production). Emissions from the global fishing industry grew by 28% between 1990 and 2011, with little coinciding increase in production (average emissions per tonne landed grew by 21%). Growth in emissions was driven primarily by increased harvests from fuel-intensive crustacean fisheries. The environmental benefit of low-carbon fisheries could be further realized if a greater proportion of landings were directed to human consumption rather than industrial uses.

  10. Emission characteristics of iso-propanol/gasoline blends in a spark-ignition engine combined with exhaust gas re-circulation

    Directory of Open Access Journals (Sweden)

    Gong Jing

    2014-01-01

    Full Text Available Experiments were carried out in a spark-ignition engine fueled with iso-propanol/gasoline blends. Emission characteristics of this engine were investigated experimentally, including gaseous emissions (HC, CO, NOx and particulate matter emission in term of number and size distributions. The effects of different iso-propanol percentages, loads and exhaust gas recirculation rates on emissions were analyzed. Results show that the introduction of exhaust gas recirculation reduces the NOx emission and NOx emission gives the highest value at full load condition. HC and CO emissions present inconspicuous variations at all the loads except the load of 10%. Additionally, HC emission shows a sharp increase for pure propanol when the exhaust gas recirculation rate is up to 5%, while little variation is observed at lager exhaust gas recirculation rates. Moreover, the particulate matter number concentration increases monotonically with the increase of load and the decrease of exhaust gas recirculation rate. There exists a critical spark timing that produces the highest particulate matter number concentration at all the blending ratios.

  11. From prototype to product. The development of low emission natural gas- and biogas buses

    Energy Technology Data Exchange (ETDEWEB)

    Ekelund, M. [Strateco Development AB, Haninge (Sweden)

    1998-01-01

    The objective of this report is to show the development of natural gas and bio gas buses and trucks since the termination of the `Co-Nordic GasBus Project`, to which KFB was a major contributor and one of the initiators. Sweden have some 325 heavy duty methane vehicles of which almost 100 are bio gas operated. Scania and Volvo have produced, or have orders for, 500 gas buses to 6 different countries since 1990. The Project objectives were obtained and the significantly reduced emission levels aimed for, were shown. The international bus manufacturing industry followed, and have since shown the same low levels of emissions from gas bus engines. Sweden has taken the lead in the use of bio gas, by operating nearly 100 buses and trucks. Bio gas is still an underestimated fuel when it comes to supply, as it can provide fuel for 50% of the domestic use of diesel oil. Future development need to include control systems for more stable emissions, lower weight cylinders, less costly compressors, cleaning equipment and storage cylinders as well as more fuel efficient engines that can reduce mainly the discharge of CO2, NOx and CH4 further. Societal costs, regardless of who pays, for methane operated buses is still somewhat higher compared with best use of diesel + CRT technology. As commercialization develops, it is expected that the price of the vehicle will be reduced and emissions improved. It is therefore expected that the stake holders costs will be lower then that of diesel technology in the future

  12. The possibilities of municipal operations to control greenhouse gas emissions of road traffic

    Energy Technology Data Exchange (ETDEWEB)

    Saeily, S.

    2004-07-01

    Kyoto protocol obligates industrialized countries to decrease their greenhouse gas emissions averagely by 5,2 percent from the 1990 level before 2008-2012. Finland is committed to stabilize its greenhouse gas emissions to the level of year 1990 before 2008-2012. Carbon monoxide, hydrocarbon, nitric oxide, sulphur dioxide, particles and carbon dioxide are regarded as hazardous emissions of road traffic. These gases are generated by impure burning which is generally expected. From these gases carbon dioxide is considered to be the actual greenhouse gas. Nitric oxide, vaporizing hydrocarbons, sulphur dioxide and carbon monoxide are considered to be indirect greenhouse gases. 20 percent of Finland's carbon dioxide emissions comes from road traffic. Actions aimed to decrease greenhouse gas emissions can be executed at various levels. The smaller the size of an actor is, the more specific the possible actions are. The actions of public administration are based on controlling economy, traffic systems and maintenance of order. The actions of private companies and communities are based on economical profitability. Decisions of individual persons are still the most significant factor in decreasing green house gases generated by passenger traffic. In this study an operations model was developed for municipalities to reduce their greenhouse gas emissions. As a case city of the study was the city of Tampere. Tampere is the third largest city in Finland and has over 15,000 employees. A more specific set of measures was introduced to three different operational units, the University Hospital of Tampere, the primary school of Tammela and the amusement park Saerkaenniemi. For each unit suitable measures were searched by studying the unit's traffic-related significance to help to decrease the unit's greenhouse gas emissions. The traffic generated by municipal operations is mainly related to commuting, work-related, customer and maintenance traffic. Measures which are

  13. Direct measurements of methane emissions from abandoned oil and gas wells in Pennsylvania.

    Science.gov (United States)

    Kang, Mary; Kanno, Cynthia M; Reid, Matthew C; Zhang, Xin; Mauzerall, Denise L; Celia, Michael A; Chen, Yuheng; Onstott, Tullis C

    2014-12-23

    Abandoned oil and gas wells provide a potential pathway for subsurface migration and emissions of methane and other fluids to the atmosphere. Little is known about methane fluxes from the millions of abandoned wells that exist in the United States. Here, we report direct measurements of methane fluxes from abandoned oil and gas wells in Pennsylvania, using static flux chambers. A total of 42 and 52 direct measurements were made at wells and at locations near the wells ("controls") in forested, wetland, grassland, and river areas in July, August, October 2013 and January 2014, respectively. The mean methane flow rates at these well locations were 0.27 kg/d/well, and the mean methane flow rate at the control locations was 4.5 × 10(-6) kg/d/location. Three out of the 19 measured wells were high emitters that had methane flow rates that were three orders of magnitude larger than the median flow rate of 1.3 × 10(-3) kg/d/well. Assuming the mean flow rate found here is representative of all abandoned wells in Pennsylvania, we scaled the methane emissions to be 4-7% of estimated total anthropogenic methane emissions in Pennsylvania. The presence of ethane, propane, and n-butane, along with the methane isotopic composition, indicate that the emitted methane is predominantly of thermogenic origin. These measurements show that methane emissions from abandoned oil and gas wells can be significant. The research required to quantify these emissions nationally should be undertaken so they can be accurately described and included in greenhouse gas emissions inventories.

  14. LMDI decomposition analysis of greenhouse gas emissions in the Korean manufacturing sector

    International Nuclear Information System (INIS)

    Jeong, Kyonghwa; Kim, Suyi

    2013-01-01

    In this article, we decomposed Korean industrial manufacturing greenhouse gas (GHG) emissions using the log mean Divisia index (LMDI) method, both multiplicatively and additively. Changes in industrial CO 2 emissions from 1991 to 2009 may be studied by quantifying the contributions from changes in five different factors: overall industrial activity (activity effect), industrial activity mix (structure effect), sectoral energy intensity (intensity effect), sectoral energy mix (energy-mix effect) and CO 2 emission factors (emission-factor effect). The results indicate that the structure effect and intensity effect played roles in reducing GHG emissions, and the structure effect played a bigger role than the intensity effect. The energy-mix effect increased GHG emissions, and the emission-factor effect decreased GHG emissions. The time series analysis indicates that the GHG emission pattern was changed before and after the International Monetary Fund (IMF) regime in Korea. The structure effect and the intensity effect had contributed more in emission reductions after rather than before the IMF regime in Korea. The structure effect and intensity effect have been stimulated since the high oil price period after 2001. - Highlights: • We decomposed greenhouse gas emissions of Korea's manufacturing industry using LMDI. • The structure effect and intensity effect play a role in reducing GHG emissions. • The role of structure effect was bigger than intensity effect. • The energy-mix effect increased and the emission-factor effect decreased GHG emissions. • The GHG emission pattern has been changed before and after IMF regime in Korea

  15. Performance and Exhaust Emissions in a Natural-Gas Fueled Dual-Fuel Engine

    Science.gov (United States)

    Shioji, Masahiro; Ishiyama, Takuji; Ikegami, Makoto; Mitani, Shinichi; Shibata, Hiroaki

    In order to establish the optimum fueling in a natural gas fueled dual fuel engine, experiments were done for some operational parameters on the engine performances and the exhaust emissions. The results show that the pilot fuel quantity should be increased and its injection timing should be advanced to suppress unburned hydrocarbon emission in the middle and low output range, while the quantity should be reduced and the timing retarded to avoid onset of knock at high loads. Unburned hydrocarbon emission and thermal efficiency are improved by avoiding too lean natural gas mixture by restricting intake charge air. However, the improvement is limited because the ignition of pilot fuel deteriorates with excessive throttling. It is concluded that an adequate combination of throttle control and equivalence ratio ensures low hydrocarbon emission and the thermal efficiency comparable to diesel operation.

  16. Life-cycle comparison of greenhouse gas emissions and water consumption for coal and shale gas fired power generation in China

    International Nuclear Information System (INIS)

    Chang, Yuan; Huang, Runze; Ries, Robert J.; Masanet, Eric

    2015-01-01

    China has the world's largest shale gas reserves, which might enable it to pursue a new pathway for electricity generation. This study employed hybrid LCI (life cycle inventory) models to quantify the ETW (extraction-to-wire) GHG (greenhouse gas) emissions and water consumption per kWh of coal- and shale gas-fired electricity in China. Results suggest that a coal-to-shale gas shift and upgrading coal-fired power generation technologies could provide pathways to less GHG and water intensive power in China. Compared to different coal-fired generation technologies, the ETW GHG emissions intensity of gas-fired CC (combined cycle) technology is 530 g CO 2 e/kWh, which is 38–45% less than China's present coal-fired electricity. Gas-fired CT (combustion turbine) technology has the lowest ETW water consumption intensity at 960 g/kWh, which is 34–60% lower than China's present coal-fired electricity. The GHG-water tradeoff of the two gas-fired power generation technologies suggests that gas-fired power generation technologies should be selected based on regional-specific water resource availabilities and electricity demand fluctuations in China. However, the low price of coal-fired electricity, high cost of shale gas production, insufficient pipeline infrastructures, and multiple consumers of shale gas resources may serve as barriers to a coal-to-shale gas shift in China's power sector in the near term. - Highlights: • The GHG and water footprints of coal- and shale gas-fired electricity are estimated. • A coal-to-shale gas shift can enable less GHG and water intensive power in China. • The GHG emissions of shale gas-fired combined cycle technology is 530 g CO 2 e/kWh. • The water consumption of shale gas-fired combustion turbine technology is 960 g/kWh. • Shale gas-fired power generation technologies selection should be regional-specific

  17. Greenhouse gas emissions from tropical forest degradation: an underestimated source

    Directory of Open Access Journals (Sweden)

    Timothy R. H. Pearson

    2017-02-01

    Full Text Available Abstract Background The degradation of forests in developing countries, particularly those within tropical and subtropical latitudes, is perceived to be an important contributor to global greenhouse gas emissions. However, the impacts of forest degradation are understudied and poorly understood, largely because international emission reduction programs have focused on deforestation, which is easier to detect and thus more readily monitored. To better understand and seize opportunities for addressing climate change it will be essential to improve knowledge of greenhouse gas emissions from forest degradation. Results Here we provide a consistent estimation of forest degradation emissions between 2005 and 2010 across 74 developing countries covering 2.2 billion hectares of forests. We estimated annual emissions of 2.1 billion tons of carbon dioxide, of which 53% were derived from timber harvest, 30% from woodfuel harvest and 17% from forest fire. These percentages differed by region: timber harvest was as high as 69% in South and Central America and just 31% in Africa; woodfuel harvest was 35% in Asia, and just 10% in South and Central America; and fire ranged from 33% in Africa to only 5% in Asia. Of the total emissions from deforestation and forest degradation, forest degradation accounted for 25%. In 28 of the 74 countries, emissions from forest degradation exceeded those from deforestation. Conclusions The results of this study clearly demonstrate the importance of accounting greenhouse gases from forest degradation by human activities. The scale of emissions presented indicates that the exclusion of forest degradation from national and international GHG accounting is distorting. This work helps identify where emissions are likely significant, but policy developments are needed to guide when and how accounting should be undertaken. Furthermore, ongoing research is needed to create and enhance cost-effective accounting approaches.

  18. Reductions in greenhouse gas emissions and cost by shipping at lower speeds

    International Nuclear Information System (INIS)

    Lindstad, Haakon; Asbjornslett, Bjorn E.; Stromman, Anders H.

    2011-01-01

    CO 2 emissions from maritime transport represent a significant part of total global greenhouse gas (GHG) emissions. According to the International Maritime Organization (), maritime transport emitted 1046 million tons (all tons are metric) of CO 2 in 2007, representing 3.3% of the world's total CO 2 emissions. The International Maritime Organization (IMO) is currently debating both technical and market-based measures for reducing greenhouse gas emissions from shipping. This paper presents investigations on the effects of speed reductions on the direct emissions and costs of maritime transport, for which the selection of ship classes was made to facilitate an aggregated representation of the world fleet. The results show that there is a substantial potential for reducing CO 2 emissions in shipping. Emissions can be reduced by 19% with a negative abatement cost (cost minimization) and by 28% at a zero abatement cost. Since these emission reductions are based purely on lower speeds, they can in part be performed now. - Highlights: → We investigates the effects of speed reductions for maritime transport. → The selection of ship classes represent the words fleet. → The transport volumes are kept constant. → The model includes both cost and emissions as a function of speed. → The results show that there is a substantial potential for reducing CO 2 emissions from shipping.

  19. Methodology for inventorying greenhouse gas emissions from global cities

    International Nuclear Information System (INIS)

    Kennedy, Christopher; Steinberger, Julia; Gasson, Barrie; Hansen, Yvonne; Hillman, Timothy; Havranek, Miroslav; Pataki, Diane; Phdungsilp, Aumnad; Ramaswami, Anu; Mendez, Gara Villalba

    2010-01-01

    This paper describes the methodology and data used to determine greenhouse gas (GHG) emissions attributable to ten cities or city-regions: Los Angeles County, Denver City and County, Greater Toronto, New York City, Greater London, Geneva Canton, Greater Prague, Barcelona, Cape Town and Bangkok. Equations for determining emissions are developed for contributions from: electricity; heating and industrial fuels; ground transportation fuels; air and marine fuels; industrial processes; and waste. Gasoline consumption is estimated using three approaches: from local fuel sales; by scaling from regional fuel sales; and from counts of vehicle kilometres travelled. A simplified version of an intergovernmental panel on climate change (IPCC) method for estimating the GHG emissions from landfill waste is applied. Three measures of overall emissions are suggested: (i) actual emissions within the boundary of the city; (ii) single process emissions (from a life-cycle perspective) associated with the city's metabolism; and (iii) life-cycle emissions associated with the city's metabolism. The results and analysis of the study will be published in a second paper.

  20. Long-term greenhouse gas emission reductions-what's possible, what's necessary?

    International Nuclear Information System (INIS)

    Bode, Sven

    2006-01-01

    Climate is changing (WMO, Press release No. 695, 2003) and there is increasing evidence that this is due to human activity (IPCC, Climate Change 2001-The Scientific Basis, Cambridge University Press, Cambridge, 2001). One way to react is to reduce greenhouse gas emissions into the atmosphere. Although this approach generally does not cause much objection, disagreements do occur when concrete emission targets are to be set. Against this background, the following article provides an arithmetic approach for the determination of long-term emission targets where the US and the EU are studied as examples

  1. Liability rules for international trading of greenhouse gas emissions quotas

    DEFF Research Database (Denmark)

    Haites, E.; Missfeldt, F.

    2001-01-01

    To reduce the costs of mitigating greenhouse gas emissions in accordance with the Kyoto protocol, international trades of emissions quotas are allowed. The revenue from the sale of quotas may exceed the sanctions for non-compliance if these penalties are weak or poorly enforced. Under...... these circumstances emissions trading enables a country to benefit financially through non-compliance. To counter non-compliance due to trading a range of liability proposals have been suggested. Using a simple global model, we analyze the economic and environmental performance of these proposals for the first...

  2. Greenhouse Gas Emissions From Energy Systems: Comparison And Overview

    International Nuclear Information System (INIS)

    Dones, R.; Heck, T.; Hirschberg, S.

    2004-01-01

    The paper provides an overview and comparison of Greenhouse Gas Emissions associated with fossil, nuclear and renewable energy systems. In this context both the direct technology-specific emissions and the contributions from full energy chains within the Life Cycle Assessment framework are considered. Examples illustrating the differences between countries and regional electricity mixes are also provided. Core results presented here are based on the work performed at PSI, and by partners within the Swiss Centre for Life-Cycle Inventories. (author)

  3. Greenhouse Gas Emissions From Energy Systems: Comparison And Overview

    Energy Technology Data Exchange (ETDEWEB)

    Dones, R.; Heck, T.; Hirschberg, S

    2004-03-01

    The paper provides an overview and comparison of Greenhouse Gas Emissions associated with fossil, nuclear and renewable energy systems. In this context both the direct technology-specific emissions and the contributions from full energy chains within the Life Cycle Assessment framework are considered. Examples illustrating the differences between countries and regional electricity mixes are also provided. Core results presented here are based on the work performed at PSI, and by partners within the Swiss Centre for Life-Cycle Inventories. (author)

  4. Technological substitution options for controlling greenhouse gas emissions

    International Nuclear Information System (INIS)

    Barbier, E.B.; Burgess, J.C.; Pearce, D.W.

    1991-01-01

    This chapter is concerned with technological options for greenhouse gas substitution. The authors interpret the term substitution to exclude energy conservation/efficiency measures, investments in afforestation (sinks), and greenhouse gas removal or abatement technologies. Their working definition of greenhouse gas substitution includes (1) replacement technologies, for example, substituting a greenhouse gas technology with a nongreenhouse gas technology; and (2) reduction technologies, for example, substituting a greenhouse gas technology with an alternative technology that reduces greenhouse gas emissions. Essentially, replacement technologies involve 100 percent reduction in CO 2 ; reduction technologies involve a partial reduction in CO 2 . Of the man-made sources of greenhouse gases, energy is the most important and is expected to contribute to at least half of the global warming effect in the near future. The majority of this impact is from fossil fuel combustion as a source of carbon dioxide (CO 2 ), although fossil fuels also contribute significantly to methane (CH 4 ), to nitrous oxide (N 2 O), and to low-level ozone (O 3 ) through production of various nitrogen gases (NO x ) and carbon monoxide (CO). This study analyzes the available greenhouse gas substitutions and their costs. The authors concentrate particularly on substitutions for fossil-fuel combustion and CFC production and consumption. They conclude by summarizing the potential for greenhouse gas substitution, the cost-effectiveness of the various options and the design of incentives for substitution

  5. An international research program on acid rain and emissions in Asia

    International Nuclear Information System (INIS)

    Foell, W.K.

    1992-01-01

    Strong economic and population growth will accelerate the rapid development of fossil fuel energy systems throughout Asia. If the present trends continue, by early next century Asian emissions of SO 2 will exceed the present emission levels in North America and Europe combined. In response to the concern that these emissions have the potential to cause significant damage in Asia, a group of international specialists has established a project on Acid Rain and Emissions in Asia. In the initial phase of this project, work is underway to develop an integrated assessment model to assist policy makers in evaluating options to reduce precursor emissions and to catalyze the process of international policy dialogue on acid rain in Asia. 8 refs., 3 figs., 1 tab

  6. Simulating greenhouse gas (GHG) allowance cost and GHG emission reduction in Western Europe

    International Nuclear Information System (INIS)

    Delarue, Erik; Lamberts, Hans; D'haeseleer, William

    2007-01-01

    Due to the growing concern for global warming, the EU25 have implemented the European Union Greenhouse Gas Emission Trading Scheme (EU ETS). In the first trading period (2005-2007), part of the targeted GHG emission reductions presumably will have to result from a switch from coal fired electricity generation to gas fired electricity generation. It is possible to calculate the allowance cost necessary to switch a certain coal fired plant with a certain gas fired plant in the merit order. The allowance cost obtained is a so called switching point. When comparing historic European Union Allowance (EUA) prices (2005) with the corresponding historic switching points, the EUA prices were found high enough to cause a certain switch in the summer season. This finding leads to the use of switching points in establishing allowance cost profiles for several scenarios. A variable gas price profile is used in the simulation tool E-Simulate to simulate electricity generation and related GHG emissions in an eight zonal model representing Western Europe. Several GHG allowance cost profile scenarios are examined. For each scenario, electricity generation in the considered countries is clarified. The focus however lies on the GHG emission reduction potentials. These potentials are addressed for each scenario

  7. RE: Request for Correction, Technical Support Document, Greenhouse Gas Emissions Reporting from the Petroleum and Natural Gas Industry

    Science.gov (United States)

    The Industrial Energy Consumers of America (IECA) joins the U.S. Chamber of Commerce in its request for correction of information developed by the Environmental Protection Agency (EPA) in a background technical support document titled Greenhouse Gas Emissions Reporting from the Petroleum and Natural Gas Industry

  8. In situ N{sub 2}O emissions are not mitigated by hippuric and benzoic acids under denitrifying conditions

    Energy Technology Data Exchange (ETDEWEB)

    Krol, D.J., E-mail: dominika.krol@teagasc.ie; Forrestal, P.J.; Lanigan, G.J.; Richards, K.G.

    2015-04-01

    Ruminant urine patches deposited onto pasture are a significant source of greenhouse gas nitrous oxide (N{sub 2}O) from livestock agriculture. Increasing food demand is predicted to lead to a rise in ruminant numbers globally, which, in turn will result in elevated levels of urine-derived N{sub 2}O. Therefore mitigation strategies are urgently needed. Urine contains hippuric acid and together with one of its breakdown products, benzoic acid, has previously been linked to mitigating N{sub 2}O emissions from urine patches in laboratory studies. However, the sole field study to date found no effect of hippuric and benzoic acid concentration on N{sub 2}O emissions. Therefore the aim of this study was to investigate the in situ effect of these urine constituents on N{sub 2}O emissions under conditions conducive to denitrification losses. Unadulterated bovine urine (0 mM of hippuric acid, U) was applied, as well as urine amended with either benzoic acid (96 mM, U + BA) or varying rates of hippuric acid (8 and 82 mM, U + HA1, U + HA2). Soil inorganic nitrogen (N) and N{sub 2}O fluxes were monitored over a 66 day period. Urine application resulted in elevated N{sub 2}O flux for 44 days. The largest N{sub 2}O fluxes accounting for between 13% (U) and 26% (U + HA1) of total loss were observed on the day of urine application. Between 0.9 and 1.3% of urine-N was lost as N{sub 2}O. Cumulative N{sub 2}O loss from the control was 0.3 kg N{sub 2}O–N ha{sup −1} compared with 11, 9, 12, and 10 kg N{sub 2}O–N ha{sup −1} for the U, U + HA1, U + HA2, and U + BA treatments, respectively. Incremental increases in urine HA or increase in BA concentrations had no effect on N{sub 2}O emissions. Although simulation of dietary manipulation to reduce N{sub 2}O emissions through altering individual urine constituents appears to have no effect, there may be other manipulations such as reducing N content or inclusion of synthetic inhibitory products that warrant further investigation

  9. Canada's nuclear industry, greenhouse gas emissions, and the Kyoto Protocol

    International Nuclear Information System (INIS)

    Pendergast, D.R.; Duffey, R.B.; Tregunno, D.

    1998-01-01

    The Kyoto Protocol of the United Nations Framework Convention on Climate change, dated December 10, 1997 committed Canada to reduce greenhouse gases to 6% below 1990 levels by 2008-2012. Other nations also committed to varying degrees of reduction. The Protocol includes provisions for credit to the 'developed' counties for initiatives which lead to greenhouse gas reduction in the 'developing' countries and for the sharing of credit between 'developed' countries for projects undertaken jointly. The rules and details for implementation of these guidelines remain to be negotiated. We begin our study by establishing the magnitude of greenhouse gas emissions already avoided by the nuclear industry in Canada since the inception of commercial power plants in 1971. We then review projections of energy use in Canada and anticipated increase in electricity use up to the year 2020. These studies have anticipated no (or have 'not permitted') further development of nuclear electricity production in spite of the clear benefit with respect to greenhouse gas emission. The studies also predict a relatively small growth of electricity use. In fact the projections indicate a reversal of a trend toward increased per capita electricity use which is contrary to observations of electricity usage in national economies as they develop. We then provide estimates of the magnitude of greenhouse gas reduction which would result from replacing the projected increase in fossil fuel electricity by nuclear generation through the building of more plants and/or making better use of existing installations. This is followed by an estimate of additional nuclear capacity needed to avoid CO 2 emissions while providing the electricity needed should per capita usage remain constant. Canada's greenhouse gas reduction goal is a small fraction of international commitments. The Kyoto agreement's 'flexibility mechanism' provisions provide some expectation that Canada could obtain some credit for greenhouse gas

  10. CO2 emission costs and Gas/Coal competition for power production

    International Nuclear Information System (INIS)

    Santi, Federico

    2005-01-01

    This paper demonstrates how a CO 2 emission reduction programme can change the competition between the two power production technologies which will probably dominate the future of the Italian power industry: the coal fired USC steam power plant and the natural gas fired CCGT power plant. An economic value of the CO 2 emission is calculated, in order to make the short-run-marginal-cost (or the long-run-marginal-cost). equal for both technologies, under a CO 2 emission trading scheme and following a single-plant specific CO 2 emission homogenizing approach [it

  11. Assessment of alternative disposal methods to reduce greenhouse gas emissions from municipal solid waste in India.

    Science.gov (United States)

    Yedla, Sudhakar; Sindhu, N T

    2016-06-01

    Open dumping, the most commonly practiced method of solid waste disposal in Indian cities, creates serious environment and economic challenges, and also contributes significantly to greenhouse gas emissions. The present article attempts to analyse and identify economically effective ways to reduce greenhouse gas emissions from municipal solid waste. The article looks at the selection of appropriate methods for the control of methane emissions. Multivariate functional models are presented, based on theoretical considerations as well as the field measurements to forecast the greenhouse gas mitigation potential for all the methodologies under consideration. Economic feasibility is tested by calculating the unit cost of waste disposal for the respective disposal process. The purpose-built landfill system proposed by Yedla and Parikh has shown promise in controlling greenhouse gas and saving land. However, these studies show that aerobic composting offers the optimal method, both in terms of controlling greenhouse gas emissions and reducing costs, mainly by requiring less land than other methods. © The Author(s) 2016.

  12. Greenhouse Gas Emissions in the Netherlands 1990-2006. National Inventory Report 2008

    International Nuclear Information System (INIS)

    Van der Maas, C.W.M.; Ruyssenaars, P.G.; Van den Born, G.J.; Brandes, L.J.; Hoen, A.; Te Molder, R.; Nijdam, D.S.; Olivier, J.G.J.; Peek, C.J.; Coenen, P.W.H.G.; Vreuls, H.H.J.; Van den Berghe, G.; Baas, K.; Guis, B.

    2008-01-01

    This report represents the 2008 Netherlands' annual inventory submission under the Kyoto Protocol and the United Nations Framework Convention on Climate Change (UNFCCC), as well as the European Union's Greenhouse Gas Monitoring Mechanism. It has been prepared following the relevant guidelines, which also refer to Revised 1996 IPCC Guidelines and IPCC Good Practice guidance and Uncertainty Management reports, provide a format for the definition of source categories and for calculation, documentation and reporting of emissions. The guidelines aim at facilitating verification, technical assessment and expert review of the inventory information by independent Expert Review Teams of the UNFCCC. Therefore, the inventories should be transparent, consistent, comparable, complete and accurate as elaborated in the UNFCCC Guidelines for reporting and be prepared using good practice as described in the IPCC Good Practice Guidance. This National Inventory Report (NIR) 2008 therefore provides explanations of the trends in greenhouse gas emissions, activity data and (implied) emission factors for the period 1990-2006. It also summarises descriptions of methods and data sources of Tier 1 assessments of the uncertainty in annual emissions and in emission trends; it presents an assessment of key sources following the Tier 1 and Tier 2 approaches of the IPCC Good Practice Guidance; and describes Quality Assurance and Quality Control activities. This report provides no specific information on the effectiveness of government policies for reducing greenhouse gas emissions. This information can be found in the annual Environmental Balance (in Dutch: 'Milieubalans') prepared by the Netherlands' Environmental Assessment Agency (MNP) and the 4th National Communication (NC4) prepared by the government of the Netherlands. So-called Common Reporting Format (CRF) spreadsheet files, containing data on emissions, activity data and implied emission factors, accompany this report. The complete set

  13. NORM emissions from heavy oil and natural gas fired power plants in Syria

    International Nuclear Information System (INIS)

    Al-Masri, M.S.; Haddad, Kh.

    2012-01-01

    Naturally occurring radioactive materials (NORM) have been determined in fly and bottom ash collected from four major Syrian power plants fired by heavy oil and natural gas. 210 Pb and 210 Po were the main NORM radionuclides detected in the fly and bottom ash. 210 Pb activity concentrations have reached 3393 ± 10 Bq kg −1 and 4023 ± 7 Bq kg −1 in fly ash and bottom ash, respectively; lower values of 210 Po were observed due to its high volatility. In addition, 210 Po and 210 Pb annual emissions in bottom ash from mixed (heavy oil and natural gas) fired power plants varied between 2.7 × 10 9 –7.95 × 10 9 Bq and 3.5 × 10 9 –10 10 Bq, respectively; higher emissions of 210 Po and 210 Pb from gas power plants being observed. However, the present study showed that 210 Po and 210 Pb emissions from thermal power plants fired by natural gas are much higher than the coal power plants operated in the World. - Highlights: ► NORM have been determined in fly and bottom ash collected from Syrian power plants fired by heavy oil and natural gas. ► 210 Pb and 210 Po were the main NORM radionuclides detected in the fly and bottom ash. ► 210 Po and 210 Pb annual emissions from these power plants were estimated.

  14. Evaluation of calcium superphosphate as an additive to reduce gas emissions from rabbit manure

    Directory of Open Access Journals (Sweden)

    Fernando Estellés Barber

    2014-12-01

    Full Text Available Techniques to reduce the emission of air pollutants from livestock production are demanded. In this study, the effect of an additive (calcium superphosphate on gas emissions from rabbit manure was investigated and compared with a control where no additive was used. Calcium superphosphate was applied at a rate of 100 g/m2 per week in a manure pit during 2 cycles of growing rabbits. Manure samples were collected weekly and then chemically and microbiologically analysed. Gas emissions (ammonia, carbon dioxide, methane and nitrous oxide were determined in 2 open flux chambers. No differences were observed in gas emissions between the treated and control samples except for ammonia emissions, which were reduced by 33% when the additive was applied (P<0.05. No statistical differences were obtained in the microbial content between control and treatment, as results showed a high variability. Dry matter content and pH were the most influential parameters on the emission of gases from manure. According to these results, the application of calcium superphosphate may be considered as an effective technique to reduce ammonia emission from rabbit manure. The additive may also be potentially effective in other species, but additional research is necessary to investigate its performance.

  15. Possibilities of Reducing Greenhouse Gas Emissions in Hotels and Camps Along the Adriatic Coast

    International Nuclear Information System (INIS)

    Kurek, J.

    1998-01-01

    The article presents a possibility of reducing greenhouse gas emissions in hotels and camps along the Adriatic Coast, through equipment modernisation, efficient use of various energy forms (electric energy, oil, gas) including solar energy. An elaborate quantitative analysis the greenhouse gas emissions and possible ways of reducing them have been carried out in 180 hotels with their own boiler rooms and 70 camps with solar hot water system. The representatives of the two specified groups were chosen in order to perform the quantitative analysis. Considering that the reduction of the carbon emission is the basic condition for the prevention of climate changes, the assumptions were made in line with their reducing. The starting point is that the combustion of a litre of fuel causes 2,5 kg CO 2 , while the generation of 1 kWh of electric energy and use of 1 m 3 of water emit 0,5 kg of CO 2 respectively. Thereby it is necessary to bear in mind that the reduction of emissions can be achieved directly in hotel boiler rooms and, in a wider perspective, in plants through the reduction of the electric energy and water consumption, i.e. solar energy consumption The article ends with a review of possible emission reductions which are to be carried out. According to the calculation presented, the share of the reduction of greenhouse gas emission in hotels and camps along the Adriatic Coast principate with 1% in the obligatory 5% emission reduction of the Republic of Croatia till the year 2012 related to the Kyoto Protocol. (author)

  16. Greenhouse gas emissions from alternative futures of deforestation and agricultural management in the southern Amazon.

    Science.gov (United States)

    Galford, Gillian L; Melillo, Jerry M; Kicklighter, David W; Cronin, Timothy W; Cerri, Carlos E P; Mustard, John F; Cerri, Carlos C

    2010-11-16

    The Brazilian Amazon is one of the most rapidly developing agricultural areas in the world and represents a potentially large future source of greenhouse gases from land clearing and subsequent agricultural management. In an integrated approach, we estimate the greenhouse gas dynamics of natural ecosystems and agricultural ecosystems after clearing in the context of a future climate. We examine scenarios of deforestation and postclearing land use to estimate the future (2006-2050) impacts on carbon dioxide (CO(2)), methane (CH(4)), and nitrous oxide (N(2)O) emissions from the agricultural frontier state of Mato Grosso, using a process-based biogeochemistry model, the Terrestrial Ecosystems Model (TEM). We estimate a net emission of greenhouse gases from Mato Grosso, ranging from 2.8 to 15.9 Pg CO(2)-equivalents (CO(2)-e) from 2006 to 2050. Deforestation is the largest source of greenhouse gas emissions over this period, but land uses following clearing account for a substantial portion (24-49%) of the net greenhouse gas budget. Due to land-cover and land-use change, there is a small foregone carbon sequestration of 0.2-0.4 Pg CO(2)-e by natural forests and cerrado between 2006 and 2050. Both deforestation and future land-use management play important roles in the net greenhouse gas emissions of this frontier, suggesting that both should be considered in emissions policies. We find that avoided deforestation remains the best strategy for minimizing future greenhouse gas emissions from Mato Grosso.

  17. Comparative study of gas-analyzing systems designed for continuous monitoring of TPP emissions

    Science.gov (United States)

    Kondrat'eva, O. E.; Roslyakov, P. V.

    2017-06-01

    Determining the composition of combustion products is important in terms of both control of emissions into the atmosphere from thermal power plants and optimization of fuel combustion processes in electric power plants. For this purpose, the concentration of oxygen, carbon monoxide, nitrogen, and sulfur oxides in flue gases is monitored; in case of solid fuel combustion, fly ash concentration is monitored as well. According to the new nature conservation law in Russia, all large TPPs shall be equipped with continuous emission monitoring and measurement systems (CEMMS) into the atmosphere. In order to ensure the continuous monitoring of pollutant emissions, direct round-the-clock measurements are conducted with the use of either domestically produced or imported gas analyzers and analysis systems, the operation of which is based on various physicochemical methods and which can be generally used when introducing CEMMS. Depending on the type and purposes of measurement, various kinds of instruments having different features may be used. This article represents a comparative study of gas-analysis systems for measuring the content of polluting substances in exhaust gases based on various physical and physicochemical analysis methods. It lists basic characteristics of the methods commonly applied in the area of gas analysis. It is proven that, considering the necessity of the long-term, continuous operation of gas analyzers for monitoring and measurement of pollutant emissions into the atmosphere, as well as the requirements for reliability and independence from aggressive components and temperature of the gas flow, it is preferable to use optical gas analyzers for the aforementioned purposes. In order to reduce the costs of equipment comprising a CEMMS at a TPP and optimize the combustion processes, electrochemical and thermomagnetic gas analyzers may also be used.

  18. Anthropogenic and volcanic emission impacts on SO2 dynamics and acid rain profiles. Numerical study using WRF-Chem in a high-resolution modeling

    Science.gov (United States)

    Vela, A. V.; González, C. M.; Ynoue, R.; Rojas, N. Y.; Aristizábal, B. H.; Wahl, M.

    2017-12-01

    Eulerian 3-D chemistry transport models (CTM) have been widely used for the study of air quality in urban environments, becoming an essential tool for studying the impacts and dynamics of gases and aerosols on air quality. However, their use in Colombia is scarce, especially in medium-sized cities, which are experimenting a fast urban growth, increasing the risk associated with possible air pollution episodes. In the densely populated medium-sized Andean city of Manizales, Colombia - a city located on the western slopes of the central range of the Andes (urban population 368000; 2150 m.a.s.l), there is an influence of the active Nevado del Ruiz volcano, located 28 km to the southwest. This natural source emits daily gas and particle fluxes, which could influence the atmospheric chemistry of the city and neighboring towns. Hence, the zone presents a unique combination of anthropogenic and volcanic sulfur gas emissions, which affects SO2 dynamics in the urban area, influencing also in the formation of acid rain phenomenon in the city. Therefore, studies analyzing the relative contribution of anthropogenic and volcanic emission could contribute with a deep understanding about causes and dynamics of both acid rain phenomenon and ambient SO2 levels in Manizales. This work aimed to analyze the influence of anthropogenic (on-road vehicular and industrial point-sources) and volcanic sulfur emissions in SO2 atmospheric chemistry dynamics, evaluating its possible effects on acid rain profiles. Ambient SO2 levels and day-night rain samples were measured and used to analyze results obtained from the application of the fully-coupled on-line WRF-Chem model. Two high-resolution simulations were performed during two dry and wet one-week periods in 2015. Analysis of SO2 dispersion patterns and comparison with SO2 observations in the urban area were performed for three different scenarios in which natural and anthropogenic emissions were simulated separately. Results suggest that

  19. Assessing the greenhouse gas emissions from poultry fat biodiesel

    DEFF Research Database (Denmark)

    Jørgensen, Andreas; Bikker, Paul; Herrmann, Ivan Tengbjerg

    2012-01-01

    This article attempts to answer the question: What will most likely happen in terms of emitted greenhouse gases if the use of poultry fat for making biodiesel used in transportation is increased? Through a well-to-wheel assessment, several different possible scenarios are assessed, showing...... that under average conditions, the use of poultry fat biodiesel instead of diesel leads to a slight reduction (6%) in greenhouse gas emissions. The analysis shows that poultry fat is already used for different purposes and using poultry fat for biodiesel will therefore remove the poultry fat from its...... original use. This implies that even though the use of biodiesel is assumed to displace petrochemical diesel, the ‘original user’ of the poultry fat will have to find a substitute, whose production leads to a greenhouse gas emissions comparable to what is saved through driving on poultry fat biodiesel...

  20. Factors influencing pollutant gas emissions of VOC recuperative incinerators-Large-scale parametric study

    International Nuclear Information System (INIS)

    Salvador, S.; Commandre, J.-M.; Kara, Y.

    2006-01-01

    This work establishes quantitative links between the operation parameters-plus one geometrical parameter-and the gas pollutant emissions of a recuperative incinerator (RI) of volatile organic compounds (VOCs). Using experimental design methodology, and based on a large number of experiments carried out on a half-industrial-scale pilot unit, mathematical expressions are established to calculate each of the pollutant emissions from the value of all the operation and design parameters. The gas emissions concerned are total hydrocarbons, and CO and NO x emissions, while the control parameters are the flow rate of the treated air flow, the concentration of VOCs in the air flow, the preheating temperature of the flow, and the temperature at the exit of the combustion chamber. One design parameter-the aperture of the diaphragms-is also considered. We show that the constraining emissions are only that of CO and NO x . Polynomials to predict them with a high accuracy are established. The air preheating temperature has an effect on the natural gas consumption, but not on CO and NO x emissions. There is an optimal value for the aperture of the diaphragms, and this value is quantitatively established. If the concentration of VOCs in the air flow is high, CO and NO x emissions both decrease and a high rate of efficiency in VOC destruction is attained. This demonstrates that a pre-concentration of VOCs in the air flow prior to treatment by RI is recommended. (author)

  1. The comparison of greenhouse gas emissions in sewage treatment plants with different treatment processes.

    Science.gov (United States)

    Masuda, Shuhei; Sano, Itsumi; Hojo, Toshimasa; Li, Yu-You; Nishimura, Osamu

    2018-02-01

    Greenhouse gas emissions from different sewage treatment plants: oxidation ditch process, double-circulated anoxic-oxic process and anoxic-oxic process were evaluated based on the survey. The methane and nitrous oxide characteristics were discussed based on the gaseous and dissolved gas profiles. As a result, it was found that methane was produced in the sewer pipes and the primary sedimentation tank. Additionally, a ventilation system would promote the gasification of dissolved methane in the first treatment units. Nitrous oxide was produced and emitted in oxic tanks with nitrite accumulation inside the sewage treatment plant. A certain amount of nitrous oxide was also discharged as dissolved gas through the effluent water. If the amount of dissolved nitrous oxide discharge is not included, 7-14% of total nitrous oxide emission would be overlooked. Based on the greenhouse gas calculation, electrical consumption and the N 2 O emission from incineration process were major sources in all the plants. For greenhouse gas reduction, oxidation ditch process has an advantage over the other advanced systems due to lower energy consumption, sludge production, and nitrogen removal without gas stripping. Copyright © 2017 Elsevier Ltd. All rights reserved.

  2. Development of an innovative uav-mounted screening tool for landfill gas emissions

    DEFF Research Database (Denmark)

    Fjelsted, Lotte; Thomasen, T. B.; Valbjørn, I. L.

    2015-01-01

    Identification of landfill gas emission hot spots are potentially a very time consuming process, and the use of an Unmanned Aerial Vehicle (UAV) based screening tool could be an effective investigation strategy. In this study, the potential use of a long-wave thermal infrared camera was investiga......Identification of landfill gas emission hot spots are potentially a very time consuming process, and the use of an Unmanned Aerial Vehicle (UAV) based screening tool could be an effective investigation strategy. In this study, the potential use of a long-wave thermal infrared camera...

  3. Earth observations for estimating greenhouse gas emissions from deforestation in developing countries

    International Nuclear Information System (INIS)

    DeFries, Ruth; Achard, Frederic; Brown, Sandra; Herold, Martin; Murdiyarso, Daniel; Schlamadinger, Bernhard; Souza, Carlos de

    2007-01-01

    In response to the United Nations Framework Convention on Climate Change (UNFCCC) process investigating the technical issues surrounding the ability to reduce greenhouse gas (GHG) emissions from deforestation in developing countries, this paper reviews technical capabilities for monitoring deforestation and estimating emissions. Implementation of policies to reduce emissions from deforestation require effective deforestation monitoring systems that are reproducible, provide consistent results, meet standards for mapping accuracy, and can be implemented at the national level. Remotely sensed data supported by ground observations are key to effective monitoring. Capacity in developing countries for deforestation monitoring is well-advanced in a few countries and is a feasible goal in most others. Data sources exist to determine base periods in the 1990s as historical reference points. Forest degradation (e.g. from high impact logging and fragmentation) also contribute to greenhouse gas emissions but it is more technically challenging to measure than deforestation. Data on carbon stocks, which are needed to estimate emissions, cannot currently be observed directly over large areas with remote sensing. Guidelines for carbon accounting from deforestation exist and are available in approved Intergovernmental Panel on Climate Change (IPCC) reports and can be applied at national scales in the absence of forest inventory or other data. Key constraints for implementing programs to monitor greenhouse gas emissions from deforestation are international commitment of resources to increase capacity, coordination of observations to ensure pan-tropical coverage, access to free or low-cost data, and standard and consensual protocols for data interpretation and analysis

  4. Identification studies about take measures for mitigate of gas emissions greenhouse effect in energy Sector

    International Nuclear Information System (INIS)

    1999-11-01

    In the Unit Nations Convention about Climatic change has get stability of greenhouse effects in atmosphere concentrations. In the framework to Uruguay Project URU/95/631 have been defined the need to identify, measures, practices, process and technologies for reduce some emissions furthermore in Energy sector. Emission impact, cost-benefit, direct or iundirect, national programs, factibility such as social, politics and Institutional agreements was considered in the present work. It was given emissions proyected for 15 years period 1999-2013 of the following atmospheric pollutants: carbon dioxide,carbon monoxide, nitrogen oxides, sulfur oxides and methane.Eight stages was applied the emission evaluation: natural gas; without natural gas; transport; industrial; Montevidean bus- car demand; natural gas uses in bus-taxi; nitrogen oxides control in thermic centrals; catalytic converters in gasoline cars

  5. Fuel-cycle greenhouse gas emissions impacts of alternative transportation fuels and advanced vehicle technologies

    International Nuclear Information System (INIS)

    Wang, M. Q.

    1998-01-01

    At an international conference on global warming, held in Kyoto, Japan, in December 1997, the United States committed to reduce its greenhouse gas (GHG) emissions by 7% over its 1990 level by the year 2012. To help achieve that goal, transportation GHG emissions need to be reduced. Using Argonne's fuel-cycle model, I estimated GHG emissions reduction potentials of various near- and long-term transportation technologies. The estimated per-mile GHG emissions results show that alternative transportation fuels and advanced vehicle technologies can help significantly reduce transportation GHG emissions. Of the near-term technologies evaluated in this study, electric vehicles; hybrid electric vehicles; compression-ignition, direct-injection vehicles; and E85 flexible fuel vehicles can reduce fuel-cycle GHG emissions by more than 25%, on the fuel-cycle basis. Electric vehicles powered by electricity generated primarily from nuclear and renewable sources can reduce GHG emissions by 80%. Other alternative fuels, such as compressed natural gas and liquefied petroleum gas, offer limited, but positive, GHG emission reduction benefits. Among the long-term technologies evaluated in this study, conventional spark ignition and compression ignition engines powered by alternative fuels and gasoline- and diesel-powered advanced vehicles can reduce GHG emissions by 10% to 30%. Ethanol dedicated vehicles, electric vehicles, hybrid electric vehicles, and fuel-cell vehicles can reduce GHG emissions by over 40%. Spark ignition engines and fuel-cell vehicles powered by cellulosic ethanol and solar hydrogen (for fuel-cell vehicles only) can reduce GHG emissions by over 80%. In conclusion, both near- and long-term alternative fuels and advanced transportation technologies can play a role in reducing the United States GHG emissions

  6. Fuel-cycle greenhouse gas emissions impacts of alternative transportation fuels and advanced vehicle technologies.

    Energy Technology Data Exchange (ETDEWEB)

    Wang, M. Q.

    1998-12-16

    At an international conference on global warming, held in Kyoto, Japan, in December 1997, the United States committed to reduce its greenhouse gas (GHG) emissions by 7% over its 1990 level by the year 2012. To help achieve that goal, transportation GHG emissions need to be reduced. Using Argonne's fuel-cycle model, I estimated GHG emissions reduction potentials of various near- and long-term transportation technologies. The estimated per-mile GHG emissions results show that alternative transportation fuels and advanced vehicle technologies can help significantly reduce transportation GHG emissions. Of the near-term technologies evaluated in this study, electric vehicles; hybrid electric vehicles; compression-ignition, direct-injection vehicles; and E85 flexible fuel vehicles can reduce fuel-cycle GHG emissions by more than 25%, on the fuel-cycle basis. Electric vehicles powered by electricity generated primarily from nuclear and renewable sources can reduce GHG emissions by 80%. Other alternative fuels, such as compressed natural gas and liquefied petroleum gas, offer limited, but positive, GHG emission reduction benefits. Among the long-term technologies evaluated in this study, conventional spark ignition and compression ignition engines powered by alternative fuels and gasoline- and diesel-powered advanced vehicles can reduce GHG emissions by 10% to 30%. Ethanol dedicated vehicles, electric vehicles, hybrid electric vehicles, and fuel-cell vehicles can reduce GHG emissions by over 40%. Spark ignition engines and fuel-cell vehicles powered by cellulosic ethanol and solar hydrogen (for fuel-cell vehicles only) can reduce GHG emissions by over 80%. In conclusion, both near- and long-term alternative fuels and advanced transportation technologies can play a role in reducing the United States GHG emissions.

  7. Formation of itraconazole-succinic acid cocrystals by gas antisolvent cocrystallization.

    Science.gov (United States)

    Ober, Courtney A; Gupta, Ram B

    2012-12-01

    Cocrystals of itraconazole, an antifungal drug with poor bioavailability, and succinic acid, a water-soluble dicarboxylic acid, were formed by gas antisolvent (GAS) cocrystallization using pressurized CO(2) to improve itraconazole dissolution. In this study, itraconazole and succinic acid were simultaneously dissolved in a liquid solvent, tetrahydrofuran, at ambient conditions. The solution was then pressurized with CO(2), which decreased the solvating power of tetrahydrofuran and caused crystallization of itraconazole-succinic acid cocrystals. The cocrystals prepared by GAS cocrystallization were compared to those produced using a traditional liquid antisolvent, n-heptane, for crystallinity, chemical structure, thermal behavior, size and surface morphology, potential clinical relevance, and stability. Powder X-ray diffraction, Fourier transform infrared spectroscopy, differential scanning calorimetry, and scanning electron microscopy analyses showed that itraconazole-succinic acid cocrystals with physical and chemical properties similar to cocrystals produced using a traditional liquid antisolvent technique can be prepared by CO(2) antisolvent cocrystallization. The dissolution profile of itraconazole was significantly enhanced through GAS cocrystallization with succinic acid, achieving over 90% dissolution in less than 2 h. The cocrystals appeared stable against thermal stress for up to 4 weeks under accelerated stability conditions, showing only moderate decreases in their degree of crystallinity but no change in their crystalline structure. This study shows the utility of an itraconazole-succinic acid cocrystal for improving itraconazole bioavailability while also demonstrating the potential for CO(2) to replace traditional liquid antisolvents in cocrystal preparation, thus making cocrystal production more environmentally benign and scale-up more feasible.

  8. Measuring Greenhouse Gas Emissions and Sinks Across California Land Cover

    Science.gov (United States)

    Fischer, M. L.

    2017-12-01

    Significant reductions in greenhouse gas (GHG) emissions are needed to limit rising planetary temperatures that will otherwise limit Earth's capacity to support life, introducing geopolitical instability. To help mitigate this threat, California has legislated landmark reductions in state-level greenhouse gas (GHG) emissions that set an example for broader action. Beginning with relatively assured reduction of current emissions to 1990 levels by 2020, future goals are much more challenging with 40% and 80% reductions below 1990 emissions by 2030 and 2050, respectively. While the majority of the reductions must focus on fossil fuels, inventory estimates of non-CO2 GHG emissions (i.e., CH4, N2O, and industrial compounds) constitute 15% of the total, suggesting reductions are required across multiple land use sectors. However, recent atmospheric inversion studies show methane and nitrous oxide (CH4 & N2O) emissions exceed current inventory estimates by factors of 1.2-1.8 and 1.6-2.6 (at 95% confidence), respectively, perhaps constituting up to 30% of State total emissions. The discrepancy is likely because current bottom-up models used for inventories do not accurately capture important management or biophysical factors. In the near term, process level experiments and sector-specific inversions are being planned to quantify the factors controlling non-CO2 GHG emissions for several of the dominant emission sectors. For biosphere carbon, California forests lands, which also depend on the combination of management, climate, and weather, lost above ground carbon from 2001-2010, and may be expected to lose soil and root carbon as a longer-term result. Here, it is important to identify and apply the best principles in forestry and agriculture to increase carbon stocks in depleted forest and agricultural areas, focusing on approaches that provide resilience to future climate and weather variations. Taken together, improved atmospheric, plant, and soil observations, together

  9. Interpretation of Series National Standards of China on “Greenhouse Gas Emissions Accounting and Reporting for Enterprises”

    Science.gov (United States)

    Chen, Liang; Zong, Jianfang; Guo, Huiting; Sun, Liang; Liu, Mei

    2018-05-01

    Standardization is playing an increasingly important role in reducing greenhouse gas emission and in climatic change adaptation, especially in the “three” greenhouse gas emission aspects (measurement, report, verification). Standardization has become one of the most important ways in mitigating the global climate change. Standardization Administration of China (SAC) has taken many productive measures in actively promoting standardization work to cope with climate change. In April 2014, SAC officially approved the establishment of “National Carbon Emission Management Standardization Technical Committee” In November 2015, SAC officially issued the first 11 national standards on carbon management including > and the requirements of the greenhouse gas emissions accounting and reporting in 10 sectors including power generation, power grid, iron and steel, chemical engineering, electrolytic aluminum, magnesium smelting, plate glass, cement, ceramics and civil aviation, which proposes unified requirements of “what to calculate and how to calculate” the greenhouse gas emission for enterprises. This paper focuses on the detailed interpretation of the main contents of the first 11 national standards, so as to provide technical supports for users of the standards and to comprehensively promote the emission reduction of greenhouse gas at the enterprise level.

  10. Estimating the Impact of US Agriculture Subsidies on Greenhouse Gas Emissions

    Science.gov (United States)

    Eshel, G.; Martin, P. A.

    2006-12-01

    It has been proposed in the popular media that US agricultural subsidies contribute deleteriously to both the American diet and environment. In this view, subsidies render mostly corn-based, animal products and sweeteners artificically cheap, leading to enhanced consumption. Problems accompanying this structure mentioned include enhanced meat, fat and sugar consumption and the associated enhancement of obesity, cardiovascular diseases, type II diabetes and possible various types of cancer, as well as air, soil and water pollution. Often overlooked in these discussions is the potential enhancement of greenhouse gas emissions accompanying this policy-based steering of food consumption toward certain products at the expense of others, possibly more nutritionally and environmentally benign. If such enhancements are in fact borne out by data, the policies that give rise to them will prove to constitute government-sponsored enhancement of greenhouse gas emissions, in contrast to any climate change mitigation efforts. If so, they represent low- hanging fruits in the national effort to reduce greenhouse gas emissions which may one day be launched. Agriculture subsidies impact the emissions of CO2 (by direct energy consumption), nitrous oxide (by land use alteration and manure management), and methane (by ruminant digestion and manure treatment). Quantifying the impacts of agricultural subsidies is complicated by many compounding and conflicting effects (many related to human behavior rather than the natural sciences) and the relatively short data timeseries. For example, subsidy policies change over time, certain subsidy types are introduced or eliminated, food preferences change as nutritional understanding (or propaganda) shift, etc. Despite the difficulties, such quantification is crucial to better estimate the overall effect and variability of dietary choices on greenhouse gas emissions, and ultimately minimize environmental impacts. In this study, we take preliminary

  11. Life Cycle Energy Consumption and Greenhouse Gas Emissions Analysis of Natural Gas-Based Distributed Generation Projects in China

    Directory of Open Access Journals (Sweden)

    Hansi Liu

    2017-10-01

    Full Text Available In this paper, we used the life-cycle analysis (LCA method to evaluate the energy consumption and greenhouse gas (GHG emissions of natural gas (NG distributed generation (DG projects in China. We took the China Resources Snow Breweries (CRSB NG DG project in Sichuan province of China as a base scenario and compared its life cycle energy consumption and GHG emissions performance against five further scenarios. We found the CRSB DG project (all energy input is NG can reduce GHG emissions by 22%, but increase energy consumption by 12% relative to the scenario, using coal combined with grid electricity as an energy input. The LCA also indicated that the CRSB project can save 24% of energy and reduce GHG emissions by 48% relative to the all-coal scenario. The studied NG-based DG project presents major GHG emissions reduction advantages over the traditional centralized energy system. Moreover, this reduction of energy consumption and GHG emissions can be expanded if the extra electricity from the DG project can be supplied to the public grid. The action of combining renewable energy into the NG DG system can also strengthen the dual merit of energy conservation and GHG emissions reduction. The marginal CO2 abatement cost of the studied project is about 51 USD/ton CO2 equivalent, which is relatively low. Policymakers are recommended to support NG DG technology development and application in China and globally to boost NG utilization and control GHG emissions.

  12. Curbing Air Pollution and Greenhouse Gas Emissions from Industrial Boilers in China

    Energy Technology Data Exchange (ETDEWEB)

    Shen, Bo [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Price, Lynn K [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Lu, Hongyou [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Liu, Xu [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Tsen, Katherine [Univ. of California, Berkeley, CA (United States); Xiangyang, Wei [National Energy Conservation Center (China); Yunpeng, Zhang [National Energy Conservation Center (China); Jian, Guan [China Special Equipment Inspection & Test Inst. (China); Rui, Hou [China Machinery Industry Conservation & Resource Utilization Center (China); Junfeng, Zhang [China National Offshore Oil Corp. (China); Yuqun, Zhuo [Tsinghua Univ., Beijing (China); Shumao, Xia [China Energy Conservation & Environmental Protection Group (China); Yafeng, Han [Xi' an Jiatong Univ. (China); Manzhi, Liu [China Univ. of Mining and Technology (China)

    2015-10-28

    China’s industrial boiler systems consume 700 million tons of coal annually, accounting for 18% of the nation’s total coal consumption. Together these boiler systems are one of the major sources of China’s greenhouse gas (GHG) emissions, producing approximately 1.3 gigatons (Gt) of carbon dioxide (CO2) annually. These boiler systems are also responsible for 33% and 27% of total soot and sulfur dioxide (SO2) emissions in China, respectively, making a substantial contribution to China’s local environmental degradation. The Chinese government - at both the national and local level - is taking actions to mitigate the significant greenhouse gas (GHG) emissions and air pollution related to the country’s extensive use of coal-fired industrial boilers. The United States and China are pursuing a collaborative effort under the U.S.-China Climate Change Working Group to conduct a comprehensive assessment of China’s coal-fired industrial boilers and to develop an implementation roadmap that will improve industrial boiler efficiency and maximize fuel-switching opportunities. Two Chinese cities – Ningbo and Xi’an – have been selected for the assessment. These cities represent coastal areas with access to liquefied natural gas (LNG) imports and inland regions with access to interprovincial natural gas pipelines, respectively.

  13. MAGA, a new database of gas natural emissions: a collaborative web environment for collecting data.

    Science.gov (United States)

    Cardellini, Carlo; Chiodini, Giovanni; Frigeri, Alessandro; Bagnato, Emanuela; Frondini, Francesco; Aiuppa, Alessandro

    2014-05-01

    The data on volcanic and non-volcanic gas emissions available online are, as today, are incomplete and most importantly, fragmentary. Hence, there is need for common frameworks to aggregate available data, in order to characterize and quantify the phenomena at various scales. A new and detailed web database (MAGA: MApping GAs emissions) has been developed, and recently improved, to collect data on carbon degassing form volcanic and non-volcanic environments. MAGA database allows researchers to insert data interactively and dynamically into a spatially referred relational database management system, as well as to extract data. MAGA kicked-off with the database set up and with the ingestion in to the database of the data from: i) a literature survey on publications on volcanic gas fluxes including data on active craters degassing, diffuse soil degassing and fumaroles both from dormant closed-conduit volcanoes (e.g., Vulcano, Phlegrean Fields, Santorini, Nysiros, Teide, etc.) and open-vent volcanoes (e.g., Etna, Stromboli, etc.) in the Mediterranean area and Azores, and ii) the revision and update of Googas database on non-volcanic emission of the Italian territory (Chiodini et al., 2008), in the framework of the Deep Earth Carbon Degassing (DECADE) research initiative of the Deep Carbon Observatory (DCO). For each geo-located gas emission site, the database holds images and description of the site and of the emission type (e.g., diffuse emission, plume, fumarole, etc.), gas chemical-isotopic composition (when available), gas temperature and gases fluxes magnitude. Gas sampling, analysis and flux measurement methods are also reported together with references and contacts to researchers expert of each site. In this phase data can be accessed on the network from a web interface, and data-driven web service, where software clients can request data directly from the database, are planned to be implemented shortly. This way Geographical Information Systems (GIS) and

  14. Rough surface mitigates electron and gas emission

    International Nuclear Information System (INIS)

    Molvik, A.

    2004-01-01

    Heavy-ion beams impinging on surfaces near grazing incidence (to simulate the loss of halo ions) generate copious amounts of electrons and gas that can degrade the beam. We measured emission coefficients of η e (le) 130 and η 0 ∼ 10 4 respectively, with 1 MeV K + incident on stainless steel. Electron emission scales as η e ∝ 1/cos(θ), where θ is the ion angle of incidence relative to normal. If we were to roughen a surface by blasting it with glass beads, then ions that were near grazing incidence (90 o ) on smooth surface would strike the rims of the micro-craters at angles closer to normal incidence. This should reduce the electron emission: the factor of 10 reduction, Fig. 1(a), implies an average angle of incidence of 62 o . Gas desorption varies more slowly with θ (Fig. 1(b)) decreasing a factor of ∼2, and along with the electron emission is independent of the angle of incidence on a rough surface. In a quadrupole magnet, electrons emitted by lost primary ions are trapped near the wall by the magnetic field, but grazing incidence ions can backscatter and strike the wall a second time at an azimuth where magnetic field lines intercept the beam. Then, electrons can exist throughout the beam (see the simulations of Cohen, HIF News 1-2/04). The SRIM (TRIM) Monte Carlo code predicts that 60-70% of 1 MeV K + ions backscatter when incident at 88-89 o from normal on a smooth surface. The scattered ions are mostly within ∼10 o of the initial direction but a few scatter by up to 90 o . Ion scattering decreases rapidly away from grazing incidence, Fig. 1(c ). At 62 deg. the predicted ion backscattering (from a rough surface) is 3%, down a factor of 20 from the peak, which should significantly reduce electrons in the beam from lost halo ions. These results are published in Phys. Rev. ST - Accelerators and Beams

  15. Greenhouse gas emission controls : differentiated vs. flat rate targets : impacts and concerts

    International Nuclear Information System (INIS)

    Heydanek, D.

    1997-01-01

    Continuing the discussion on differentiation in greenhouse gas emission targets and timetables for all nations, the different implications of differentiation vs. flat rate controls were examined. A scenario of how different targets for different countries based on national circumstances might be implemented, was presented. Implications of differentiation for the Dow Chemical Company were also reviewed. For more than 20 years, Dow has practiced leading edge energy efficiency in environmental management systems and has committed to a series of environmental, health and safety goals. The company believes that at the international level, fully differentiated targets and timetables need to be negotiated, party by party, by the 150 nations who agreed to stabilize greenhouse gas emissions at 1990 levels by year 2000. It was suggested that a strong disincentive exists to delivering energy efficiency beyond compliance. It was predicted that despite efficiency, the energy intensive assets in place today in Annex I countries will be disadvantaged and prematurely retired as the costs of greenhouse gas emission controls grow and exert pressure to move productive capacity offshore

  16. Natural gas fugitive emissions rates constrained by global atmospheric methane and ethane.

    Science.gov (United States)

    Schwietzke, Stefan; Griffin, W Michael; Matthews, H Scott; Bruhwiler, Lori M P

    2014-07-15

    The amount of methane emissions released by the natural gas (NG) industry is a critical and uncertain value for various industry and policy decisions, such as for determining the climate implications of using NG over coal. Previous studies have estimated fugitive emissions rates (FER)--the fraction of produced NG (mainly methane and ethane) escaped to the atmosphere--between 1 and 9%. Most of these studies rely on few and outdated measurements, and some may represent only temporal/regional NG industry snapshots. This study estimates NG industry representative FER using global atmospheric methane and ethane measurements over three decades, and literature ranges of (i) tracer gas atmospheric lifetimes, (ii) non-NG source estimates, and (iii) fossil fuel fugitive gas hydrocarbon compositions. The modeling suggests an upper bound global average FER of 5% during 2006-2011, and a most likely FER of 2-4% since 2000, trending downward. These results do not account for highly uncertain natural hydrocarbon seepage, which could lower the FER. Further emissions reductions by the NG industry may be needed to ensure climate benefits over coal during the next few decades.

  17. Climate change science : high quality greenhouse gas emissions data are a cornerstone of programs to address climate change

    Science.gov (United States)

    2009-02-24

    This testimony focuses on (1) the importance of quality data on emissions in the context of a program intended to limit greenhouse gas emissions, and (2) key considerations in developing reliable data on greenhouse gas emissions. This testimony is ba...

  18. 5th international exhaust gas and particulate emissions forum. Proceedings; 5. Internationales Forum Abgas- und Partikelemissionen. Beitraege

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-12-11

    The Proceedings of the 5th International Exhaust Gas and Particulate Emissions Forum contains 22 printed contributions as well as a CD-ROM. The titles of them are: (1) Diesel Emissions Control in the United States - 2010 and Beyond; (2) The MBE90 commercial vehicle engine for EPA '07 emissions regulations; (3) Concepts for engines and exhaust-gas cleaning systems for heavy duty trucks of the future; (4) HD Engine Technology for Near-Zero Emissions and Lowest Cost of Ownership; (5) (Partially-) Homogeneous Diesel Combustion; (6) Exhaust gas sensors for NOx storage catalysts and ammonia-SCR systems; (7) Sensors for modern exhaust gas after-treatment systems; (8) New reducing agents for low NOx-SCR Techno-logy; (9) Exhaust gas Aftertreatment on Lean Burn Gasoline Direct Injection Engines: The System of TWC and NOx-Storage Catalyst; (10) New Platinum/Palladium based catalyzed filter technologies for future passenger car applications; (11) Development of a Roadway Hydrocarbon Sorption Model and Characterization of a Novel PM Generator; (12) Requirements for current and future particulate measurement instrumentation from the point of view of the Physikalisch-Technische Bundesanstalt; (13) Standardized dilution conditions for gravimetric PM sampling - measures to assure results that correlate; (14) Particle Counting according PMP; (15) Future high-confidence measurement of diesel particulate emissions for approval and development; (16) New developments in optical instrumentation for exhaust gas; (17) Simultaneous Detection of Gaseous and Particulate Exhaust Components by Photoacoustic Spectroscopy; (18) Boundaries of modern exhaust gas instrumentation; (19) Raising quality and reducing application effort through efficient data input to the particulate filter load model for a EURO5 diesel car; (20) Stop-start operation of diesel engines - modified require-ment for exhaust gas after-treatment?; (21) Particulates emission with Biodiesel B30 impact on CSF management; (22

  19. 5th international exhaust gas and particulate emissions forum. Proceedings; 5. Internationales Forum Abgas- und Partikelemissionen. Beitraege

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-12-11

    The Proceedings of the 5th International Exhaust Gas and Particulate Emissions Forum contains 22 printed contributions as well as a CD-ROM. The titles of them are: (1) Diesel Emissions Control in the United States - 2010 and Beyond; (2) The MBE90 commercial vehicle engine for EPA '07 emissions regulations; (3) Concepts for engines and exhaust-gas cleaning systems for heavy duty trucks of the future; (4) HD Engine Technology for Near-Zero Emissions and Lowest Cost of Ownership; (5) (Partially-) Homogeneous Diesel Combustion; (6) Exhaust gas sensors for NOx storage catalysts and ammonia-SCR systems; (7) Sensors for modern exhaust gas after-treatment systems; (8) New reducing agents for low NOx-SCR Techno-logy; (9) Exhaust gas Aftertreatment on Lean Burn Gasoline Direct Injection Engines: The System of TWC and NOx-Storage Catalyst; (10) New Platinum/Palladium based catalyzed filter technologies for future passenger car applications; (11) Development of a Roadway Hydrocarbon Sorption Model and Characterization of a Novel PM Generator; (12) Requirements for current and future particulate measurement instrumentation from the point of view of the Physikalisch-Technische Bundesanstalt; (13) Standardized dilution conditions for gravimetric PM sampling - measures to assure results that correlate; (14) Particle Counting according PMP; (15) Future high-confidence measurement of diesel particulate emissions for approval and development; (16) New developments in optical instrumentation for exhaust gas; (17) Simultaneous Detection of Gaseous and Particulate Exhaust Components by Photoacoustic Spectroscopy; (18) Boundaries of modern exhaust gas instrumentation; (19) Raising quality and reducing application effort through efficient data input to the particulate filter load model for a EURO5 diesel car; (20) Stop-start operation of diesel engines - modified require-ment for exhaust gas after-treatment?; (21) Particulates emission with Biodiesel B30 impact on CSF management; (22

  20. Greenhouse Gas Emission Accounting and Management of Low-Carbon Community

    Directory of Open Access Journals (Sweden)

    Dan Song

    2012-01-01

    Full Text Available As the major source of greenhouse gas (GHG emission, cities have been under tremendous pressure of energy conservation and emission reduction for decades. Community is the main unit of urban housing, public facilities, transportation, and other properties of city's land use. The construction of low-carbon community is an important pathway to realize carbon emission mitigation in the context of rapid urbanization. Therefore, an efficient carbon accounting framework should be proposed for CO2 emissions mitigation at a subcity level. Based on life-cycle analysis (LCA, a three-tier accounting framework for the carbon emissions of the community is put forward, including emissions from direct fossil fuel combustion, purchased energy (electricity, heat, and water, and supply chain emissions embodied in the consumption of goods. By compiling a detailed CO2 emission inventory, the magnitude of carbon emissions and the mitigation potential in a typical high-quality community in Beijing are quantified within the accounting framework proposed. Results show that emissions from supply chain emissions embodied in the consumption of goods cannot be ignored. Specific suggestions are also provided for the urban decision makers to achieve the optimal resource allocation and further promotion of low-carbon communities.

  1. Emissions implications of future natural gas production and use in the U.S. and in the Rocky Mountain region.

    Science.gov (United States)

    McLeod, Jeffrey D; Brinkman, Gregory L; Milford, Jana B

    2014-11-18

    Enhanced prospects for natural gas production raise questions about the balance of impacts on air quality, as increased emissions from production activities are considered alongside the reductions expected when natural gas is burned in place of other fossil fuels. This study explores how trends in natural gas production over the coming decades might affect emissions of greenhouse gases (GHG), volatile organic compounds (VOCs) and nitrogen oxides (NOx) for the United States and its Rocky Mountain region. The MARKAL (MARKet ALlocation) energy system optimization model is used with the U.S. Environmental Protection Agency's nine-region database to compare scenarios for natural gas supply and demand, constraints on the electricity generation mix, and GHG emissions fees. Through 2050, total energy system GHG emissions show little response to natural gas supply assumptions, due to offsetting changes across sectors. Policy-driven constraints or emissions fees are needed to achieve net reductions. In most scenarios, wind is a less expensive source of new electricity supplies in the Rocky Mountain region than natural gas. U.S. NOx emissions decline in all the scenarios considered. Increased VOC emissions from natural gas production offset part of the anticipated reductions from the transportation sector, especially in the Rocky Mountain region.

  2. Potential Greenhouse Gas Emissions Reductions from Optimizing Urban Transit Networks

    Science.gov (United States)

    2016-05-01

    Public transit systems with efficient designs and operating plans can reduce greenhouse gas (GHG) emissions relative to low-occupancy transportation modes, but many current transit systems have not been designed to reduce environmental impacts. This ...

  3. Techno-economic Analysis of Acid Gas Removal and Liquefaction for Pressurized LNG

    Science.gov (United States)

    Lee, S. H.; Seo, Y. K.; Chang, D. J.

    2018-05-01

    This study estimated the life cycle cost (LCC) of an acid gas removal and a liquefaction processes for Pressurized LNG (PLNG) production and compared the results with the cost of normal LNG production. PLNG is pressurized LNG that is liquefied at a higher pressure and temperature than normal LNG. Due to the high temperature, the energy for liquefaction is reduced. The allowable CO2 concentration in PLNG is increased up to 3 mol% when the product pressure 25 bar. An amine process with 35 wt% of diethanolamine (DEA) aqueous solution and a nitrogen expansion cycle were selected for the acid gas removal and the liquefaction processes, respectively. Two types of CO2 concentration in the feed gas were investigated to analyze their impacts on the acid gas removal unit. When the CO2 concentration was 5 mol%, the acid gas removal unit was required for both LNG and PLNG production. However, the acid gas removal unit was not necessary in PLNG when the concentration was 0.5 mol% and the pressure was higher than 15 bar. The results showed that the LCC of PLNG was reduced by almost 35% relative to that of LNG when the PLNG pressure was higher than 15 bar.

  4. Aligning corporate greenhouse-gas emissions targets with climate goals

    NARCIS (Netherlands)

    Krabbe, Oskar; Linthorst, Giel; Blok, Kornelis; Crijns-Graus, Wina; Vuuren, Van Detlef P.; Höhne, Niklas; Faria, Pedro; Aden, Nate; Pineda, Alberto Carrillo

    2015-01-01

    Corporate climate action is increasingly considered important in driving the transition towards a low-carbon economy. For this, it is critical to ensure translation of global goals to greenhouse-gas (GHG) emissions reduction targets at company level. At the moment, however, there is a lack of

  5. Aligning corporate greenhouse-gas emissions targets with climate goals

    NARCIS (Netherlands)

    Krabbe, Oskar; Linthorst, Giel; Blok, Kornelis|info:eu-repo/dai/nl/07170275X; Crijns-Graus, Wina|info:eu-repo/dai/nl/308005015; Van Vuuren, Detlef P.|info:eu-repo/dai/nl/11522016X; Höhne, Niklas; Faria, Pedro; Aden, Nate; Pineda, Alberto Carrillo

    2015-01-01

    Corporate climate action is increasingly considered important in driving the transition towards a low-carbon economy. For this, it is critical to ensure translation of global goals to greenhouse-gas (GHG) emissions reduction targets at company level. At the moment, however, there is a lack of clear

  6. 77 FR 51499 - Greenhouse Gas Emissions Standards and Fuel Efficiency Standards for Medium- and Heavy-Duty...

    Science.gov (United States)

    2012-08-24

    ... DEPARTMENT OF TRANSPORTATION National Highway Traffic Safety Administration 49 CFR Part 535 [NHTSA 2012-0126] RIN 2127-AK74 Greenhouse Gas Emissions Standards and Fuel Efficiency Standards for Medium... purpose of reducing greenhouse gas (GHG) emissions because the GHG standards fundamentally regulate fuel...

  7. Greenhouse Gas Emissions, Energy Consumption and Economic Growth: A Panel Cointegration Analysis for 16 Asian Countries.

    Science.gov (United States)

    Lu, Wen-Cheng

    2017-11-22

    This research investigates the co-movement and causality relationships between greenhouse gas emissions, energy consumption and economic growth for 16 Asian countries over the period 1990-2012. The empirical findings suggest that in the long run, bidirectional Granger causality between energy consumption, GDP and greenhouse gas emissions and between GDP, greenhouse gas emissions and energy consumption is established. A non-linear, quadratic relationship is revealed between greenhouse gas emissions, energy consumption and economic growth, consistent with the environmental Kuznets curve for these 16 Asian countries and a subsample of the Asian new industrial economy. Short-run relationships are regionally specific across the Asian continent. From the viewpoint of energy policy in Asia, various governments support low-carbon or renewable energy use and are reducing fossil fuel combustion to sustain economic growth, but in some countries, evidence suggests that energy conservation might only be marginal.

  8. Greenhouse Gas Emissions, Energy Consumption and Economic Growth: A Panel Cointegration Analysis for 16 Asian Countries

    Science.gov (United States)

    2017-01-01

    This research investigates the co-movement and causality relationships between greenhouse gas emissions, energy consumption and economic growth for 16 Asian countries over the period 1990–2012. The empirical findings suggest that in the long run, bidirectional Granger causality between energy consumption, GDP and greenhouse gas emissions and between GDP, greenhouse gas emissions and energy consumption is established. A non-linear, quadratic relationship is revealed between greenhouse gas emissions, energy consumption and economic growth, consistent with the environmental Kuznets curve for these 16 Asian countries and a subsample of the Asian new industrial economy. Short-run relationships are regionally specific across the Asian continent. From the viewpoint of energy policy in Asia, various governments support low-carbon or renewable energy use and are reducing fossil fuel combustion to sustain economic growth, but in some countries, evidence suggests that energy conservation might only be marginal. PMID:29165399

  9. Greenhouse Gas Emissions, Energy Consumption and Economic Growth: A Panel Cointegration Analysis for 16 Asian Countries

    Directory of Open Access Journals (Sweden)

    Wen-Cheng Lu

    2017-11-01

    Full Text Available This research investigates the co-movement and causality relationships between greenhouse gas emissions, energy consumption and economic growth for 16 Asian countries over the period 1990–2012. The empirical findings suggest that in the long run, bidirectional Granger causality between energy consumption, GDP and greenhouse gas emissions and between GDP, greenhouse gas emissions and energy consumption is established. A non-linear, quadratic relationship is revealed between greenhouse gas emissions, energy consumption and economic growth, consistent with the environmental Kuznets curve for these 16 Asian countries and a subsample of the Asian new industrial economy. Short-run relationships are regionally specific across the Asian continent. From the viewpoint of energy policy in Asia, various governments support low-carbon or renewable energy use and are reducing fossil fuel combustion to sustain economic growth, but in some countries, evidence suggests that energy conservation might only be marginal.

  10. The second generation model of greenhouse gas emissions: background and initial development

    International Nuclear Information System (INIS)

    Baron, R.; Wise, M.A.; Edmonds, J.A.; Pitcher, H.M.; Barns, D.

    1992-01-01

    The analysis of greenhouse gas emissions has made enormous progress during the course of the past decade. We have progressed from the use of simple time-trend extrapolations to the analysis of emissions of several greenhouse gases with parallel but independent behavioral and optimization models of energy, manufacturing, agriculture, and land-use systems. But our ability to examine potential future scenarios of greenhouse gas emissions is limited because modeling tools adequate to the task of integrating analyses of technologies and human activities on a global scale with regional detail, including energy production and consumption, agriculture, manufacture, capital formation, and land-use, along with the interdependencies between these categories, do not yet exist. The first generation of models were specialty models which focused on a particular aspect of the emissions problem without regard to how that activity interacted with other human and natural activities. The natural science pertaining to greenhouse warming now emphasizes the variety of gases associated with potential changes in the radiative composition of the atmosphere: CO 2 , CH 4 , CO, N 2 O, NO x , SO 2 , VOC's, chlorofluorocarbons, (CFC's) and CFC substitutes. Human activities generating the emissions of these gases are interdependent; actions taken to limit emissions from one segment of the economy will affect other segments of the economy. Policy issues such as the recycling of revenues from a carbon tax, land-use changes due to to tree-planting to sequestrate carbon dioxide or extensive development of biomass energy resources, require a more comprehensive modeling approach in which the relationship between technology, institutions, land use, economics and human activity is explicitly represented. The purpose of this paper is to describe briefly the design of a model which is capable of addressing greenhouse gas emissions and the consequences of alternative policy options. 7 refs

  11. Greenhouse Gas Emissions from Solid and Liquid Organic Fertilizers Applied to Lettuce.

    Science.gov (United States)

    Toonsiri, Phasita; Del Grosso, Stephen J; Sukor, Arina; Davis, Jessica G

    2016-11-01

    Improper application of nitrogen (N) fertilizer and environmental factors can cause the loss of nitrous oxide (NO) to the environment. Different types of fertilizers with different C/N ratios may have different effects on the environment. The focus of this study was to evaluate the effects of environmental factors and four organic fertilizers (feather meal, blood meal, fish emulsion, and cyano-fertilizer) applied at different rates (0, 28, 56, and 112 kg N ha) on NO emissions and to track CO emissions from a lettuce field ( L.). The study was conducted in 2013 and 2014 and compared preplant-applied solid fertilizers (feather meal and blood meal) and multiple applications of liquid fertilizers (fish emulsion and cyano-fertilizer). Three days a week, NO and CO emissions were measured twice per day in 2013 and once per day in 2014 using a closed-static chamber, and gas samples were analyzed by gas chromatography. Preplant-applied solid fertilizers significantly increased cumulative NO emissions as compared with control, but multiple applications of liquid fertilizers did not. Emission factors for NO ranged from 0 to 0.1% for multiple applications of liquid fertilizers and 0.6 to 11% for preplant-applied solid fertilizers, which could be overestimated due to chamber placement over fertilizer bands. In 2014, solid fertilizers with higher C/N ratios (3.3-3.5) resulted in higher CO emissions than liquid fertilizers (C/N ratio, 0.9-1.5). Therefore, organic farmers should consider the use of multiple applications of liquid fertilizers as a means to reduce soil greenhouse gas emissions while maintaining high yields. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  12. Potential for the reduction of greenhouse gas emissions through the use of mobility services

    DEFF Research Database (Denmark)

    Grischkat, Sylvie; Hunecke, Marcel; Böhler, Susanne

    2014-01-01

    gas emissions per person and year was found to be 78 kg in an optimistic scenario and 25 kg in a pessimistic scenario. Extrapolated to the German metropolitan population, behaviour-related measures alone could result in a 1.8 million ton (optimistic scenario) or 0.6 million ton (pessimistic scenario......This study evaluates potential for the reduction of greenhouse gas emissions in the passenger transport sector achievable through the use of mobility services. Beside car-sharing and -pooling, six services targeted at improving and encouraging the use of urban public transportation were considered......) reduction of greenhouse gas emissions, respectively. In order to exploit this potential fully, however, target group specific information should be obtained and communication strategies developed, as addressed in this paper. This study further presents the limitation of reduction potential quantification...

  13. Indicators for the international comparison of energy consumption and greenhouse-gas emissions

    International Nuclear Information System (INIS)

    Hohmann, R.; Steiner, S.; Koch, P.

    2007-11-01

    This comprehensive report for the Swiss Federal Office of Energy (SFOE) examines the energy consumption and greenhouse-gas emissions of various Swiss economical sectors including industry, services, households and traffic. Comparisons are made with the corresponding areas in the European Union and other countries. In spite of the relatively good situation in the Swiss industrial sector, further investigation is recommended. Room for improvement in the services sector is mentioned and average performance as far as energy consumption in households is concerned is noted. It is estimated that a considerable potential for improvement is available in this sector. Motorised traffic is quoted as being the main source of greenhouse-gas emissions, Switzerland being the second worst European country in this respect. Estimates are made concerning the potential for emission reductions in the various areas

  14. How to prevent greenhouse gas emissions in electrical installations: lighting energy savings and solar energy approaches

    Energy Technology Data Exchange (ETDEWEB)

    Yavuz, C.; Aksoy, C. [Sakarya University, Faculty of Engineering, Electrical and Electronics Engineering Department, Serdivan (Turkey)

    2012-07-01

    Day by day greenhouse gas emissions increase dramatically. A passive adaptive method of lighting energy savings, daylight responsive systems are considered one of the best solutions for energy efficiency, saving and prevent CO{sub 2} emissions. Results of an annual experiment which was held in Sakarya University proves the necessity of daylight responsive systems with a 41% energy saving and 942.5 kg of prevented CO{sub 2} emissions Thinking this prevention is realized just only in a 36 m{sup 2} room with the use of 8 luminaries spreading such systems to nationwide, a major amount of greenhouse gas emissions would be prohibited. On the other hand energy saving is not the only way to reduce CO{sub 2} emissions. Again in Sakarya University a project has started to investigate the possibility of illumination of a complete building by using solar energy. This paper evaluates these mentioned systems both in energy efficiency, greenhouse gas emissions prevention and economic point of views. (author)

  15. [Greenhouse gas emissions, carbon leakage and net carbon sequestration from afforestation and forest management: A review.

    Science.gov (United States)

    Liu, Bo Jie; Lu, Fei; Wang, Xiao Ke; Liu, Wei Wei

    2017-02-01

    Forests play an important role in climate change mitigation and concentration of CO 2 reduction in the atmosphere. Forest management, especially afforestation and forest protection, could increase carbon stock of forests significantly. Carbon sequestration rate of afforestation ranges from 0.04 to 7.52 t C·hm -2 ·a -1 , while that of forest protection is 0.33-5.20 t C·hm -2 ·a -1 . At the same time, greenhouse gas (GHG) is generated within management boundary due to the production and transportation of the materials consumed in relevant activities of afforestation and forest management. In addition, carbon leakage is also generated outside boundary from activity shifting, market effects and change of environments induced by forest management. In this review, we summarized the definition of emission sources of GHG, monitoring methods, quantity and rate of greenhouse gas emissions within boundary of afforestation and forest management. In addition, types, monitoring methods and quantity of carbon leakage outside boundary of forest management were also analyzed. Based on the reviewed results of carbon sequestration, we introduced greenhouse gas emissions within boundary and carbon leakage, net carbon sequestration as well as the countervailing effects of greenhouse gas emissions and carbon leakage to carbon sequestration. Greenhouse gas emissions within management boundary counteract 0.01%-19.3% of carbon sequestration, and such counteraction could increase to as high as 95% considering carbon leakage. Afforestation and forest management have substantial net carbon sequestration benefits, when only taking direct greenhouse gas emissions within boundary and measurable carbon leakage from activity shifting into consideration. Compared with soil carbon sequestration measures in croplands, afforestation and forest management is more advantageous in net carbon sequestration and has better prospects for application in terms of net mitigation potential. Along with the

  16. Monthly carbon emissions from natural-gas flaring and cement manufacture in the United States

    International Nuclear Information System (INIS)

    Blasing, T.J.; Hand, Kimberly

    2007-01-01

    Annual data on carbon emissions from fossil-fuel combustion and cement manufacture have been used in studies of the carbon cycle for the last few decades. However, annual data do not specify carbon emissions on the seasonal time-scales relevant to biospheric uptake and other processes affecting the carbon cycle. Estimates of monthly emissions from fossil-fuel consumption in the US have shown that an increasing percentage of the annual emissions are occurring during the growing season; however, carbon emitted from flaring natural gas at well sites was not accounted for in those emissions estimates, nor was carbon emitted during cement manufacture. Here we show that emissions from flaring, which amount around 0.1 % of all fossil-fuel carbon emissions in the US, have no clear and persistent annual pattern that can be detected in the data. In contrast, carbon emissions from cement manufacture, which add about 0.7% to carbon emissions from fossil fuels in the US, have a clear and persistent annual pattern including low values in late winter and early spring. In this paper, we provide a few remarks on carbon emissions from natural-gas flaring before presenting monthly emissions estimates. We then focus on the methodology for calculating carbon emissions from cement manufacture before presenting and discussing the monthly emissions estimates

  17. Papers of the Canadian Institute conference: Reduction, management and trading of greenhouse gas emissions

    International Nuclear Information System (INIS)

    2003-01-01

    This conference provided an opportunity for experts from various fields to discuss and exchange views and the latest information on a wide range of topics related to the reduction, management and trading of greenhouse gas emissions. The papers dealt with pertinent issues such as: (1) short and long term impacts of the Kyoto Protocol ratification for industries operating in Quebec, necessary changes and required investment, (2) calculation mechanisms for the allocation of permits, audit systems for the reduction and registration of emissions, (3) Canadian and international emission trading market, opportunities and associated risks, (4) preparation of an emission trading contract, (5) the establishment of a greenhouse gas (GHG) emission reduction and management system within companies, and (6) measures implemented by governments to assist industry in meeting emission reduction targets. Of the sixteen papers presented at the conference, 4 have been processed separately for inclusion in this database. refs., tabs., figs

  18. Gas emissions from mining voids in Lorraine iron-bearing basin

    International Nuclear Information System (INIS)

    Grabowski, D.; Pokryszka, Z.

    2003-01-01

    A study carried out in the iron basin of Lorraine (France) put the spot on the existence of under-oxygenated and noxious gas emissions (carbon dioxide, radon..) in built-up areas related to former mining works. Site investigations showed that the gas flow was mainly due to natural ventilation mechanisms. A further study is in progress in order to better understand the origin of the atmosphere modification within the old mine workings. (authors)

  19. Assessing Greenhouse Gas emissions in the Greater Toronto Area using atmospheric observations (Invited)

    Science.gov (United States)

    Vogel, F. R.; Chan, E.; Huang, L.; Levin, I.; Worthy, D.

    2013-12-01

    Urban areas are said to be responsible for approximately 75% of anthropogenic Greenhouse Gases (GHGs) emissions while comprising only two percent of the land area [1]. This limited spatial expansion should facilitate a monitoring of anthropogenic GHGs from atmospheric observations. As major sources of emissions, cities also have a huge potential to drive emissions reductions. To effectively manage emissions, cities must however, first measure and report these publicly [2]. Modelling studies and measurements of CO2 from fossil fuel burning (FFCO2) in densely populated areas does, however, pose several challenges: Besides continuous in-situ observations, i.e. finding an adequate atmospheric transport model, a sufficiently fine-grained FFCO2 emission model and the proper background reference observations to distinguish the large-scale from the local/urban contributions to the observed FFCO2 concentration offsets ( ΔFFCO2) are required. Pilot studies which include the data from two 'sister sites*' in the vicinity of Toronto, Canada helped to derive flux estimates for Non-CO2 GHGs [3] and improve our understanding of urban FFCO2 emissions. Our 13CO2 observations reveal that the contribution of natural gas burning (mostly due to domestic heating) account for 80%×7% of FFCO2 emissions in the Greater Toronto Area (GTA) during winter. Our 14CO2 observations in the GTA, furthermore, show that the local offset of CO2 (ΔCO2) between our two sister sites can be largely attributed to urban FFCO2 emissions. The seasonal cycle of the observed ΔFFCO2 in Toronto, combined with high-resolution atmospheric modeling, helps to independently assess the contribution from different emission sectors (transportation, primary energy and industry, domestic heating) as predicted by a dedicated city-scale emission inventory, which deviates from a UNFCCC-based inventory. [1] D. Dodman. 2009. Blaming cities for climate change? An analysis of urban greenhouse gas emissions inventories

  20. Subjective Well-Being Approach to Environmental Valuation: Evidence for Greenhouse Gas Emissions

    Science.gov (United States)

    Beja, Edsel L., Jr.

    2012-01-01

    The subjective well-being approach to environmental valuation is applied to analyze the valuation of greenhouse gas emissions with a fairness-adjustment in the valuation exercise. Results indicate that industrialized countries have high willingness-to-pay to reduce emissions. Developing countries differ in their valuations. Results indicate that…

  1. METHANE EMISSIONS FROM THE NATURAL GAS INDUSTRY VOLUME 13: CHEMICAL INJECTION PUMPS

    Science.gov (United States)

    The 15-volume report summarizes the results of a comprehensive program to quantify methane (CH4) emissions from the U.S. natural gas industry for the base year. The objective was to determine CH4 emissions from the wellhead and ending downstream at the customer's meter. The accur...

  2. Managing soil organic carbon in agriculture: the net effect on greenhouse gas emissions

    International Nuclear Information System (INIS)

    Marland, Gregg; West, Tristram O.; Schlamadinger, Bernhard; Canella, Lorenza

    2003-01-01

    A change in agricultural practice can increase carbon sequestration in agricultural soils. To know the net effect on greenhouse gas emissions to the atmosphere, however, we consider associated changes in CO 2 emissions resulting from the consumption of fossil fuels, emissions of other greenhouse gases and effects on land productivity and crop yield. We also consider how these factors will evolve over time. A change from conventional tillage to no-till agriculture, based on data for average practice in the U.S.; will result in net carbon sequestration in the soil that averages 337 kg C/ha/yr for the initial 20 yr with a decline to near zero in the following 20 yr, and continuing savings in CO 2 emissions because of reduced use of fossil fuels. The long-term results, considering all factors, can generally be expected to show decreased net greenhouse gas emissions. The quantitative details, however, depend on the site-specific impact of the conversion from conventional to no-till agriculture on agricultural yield and N 2 O emissions from nitrogen fertilizer

  3. Quebec inventory of greenhouse gas emissions in 2008 and their evolution since 1990

    International Nuclear Information System (INIS)

    Leblond, V.; Paradis, J.; Bougie, R.; Goulet, M.; Leclerc, N.; Nolet, E.

    2010-11-01

    This document presented an inventory of greenhouse gas (GHG) emissions produced by human activity in Quebec between 1990 and 2008. In 2008, 82.7 Mt of carbon dioxide (CO 2 ) equivalent were released in Quebec, which represents a 1.2 percent reduction from 1990 levels. Quebec had the second lowest GHG emissions per capita in 2008 and was 1 of only 3 only provinces in Canada to have a reduction in GHG emissions since 1990. This document also presented data regarding GHG emissions released by sector, notably from industrial combustion such as the TransCanada Energy cogeneration facilities; industrial processes; residential, commercial and institutional buildings; agriculture; sanitary landfills; and electric power production. Quebec's reduction in GHG emissions can be attributed primarily to advances in energy efficiency technology that have been adopted by the industrial sector. In addition, some industrial combustion facilities have been closed and landfill facilities have begun to use systems to capture methane gas. In contrast, automobile traffic increased over the study period, and was responsible for an important increase in GHG emissions since 1990. 6 tabs., 4 figs.

  4. 75 FR 25323 - Light-Duty Vehicle Greenhouse Gas Emission Standards and Corporate Average Fuel Economy Standards...

    Science.gov (United States)

    2010-05-07

    ... Greenhouse Gas Emission Standards and Corporate Average Fuel Economy Standards; Final Rule #0;#0;Federal... Fuel Economy Standards; Final Rule AGENCY: Environmental Protection Agency (EPA) and National Highway... reduce greenhouse gas emissions and improve fuel economy. This joint Final Rule is consistent with the...

  5. Effects of levan-type fructan on growth performance, nutrient digestibility, diarrhoea scores, faecal shedding of total lactic acid bacteria and coliform bacteria, and faecal gas emission in weaning pigs.

    Science.gov (United States)

    Lei, Xin Jian; Kim, Yong Min; Park, Jae Hong; Baek, Dong Heon; Nyachoti, Charles Martin; Kim, In Ho

    2018-03-01

    The use of antibiotics as growth promoters in feed has been fully or partially banned in several countries. The objective of this study was to evaluate effects of levan-type fructan on growth performance, nutrient digestibility, faecal shedding of lactic acid bacteria and coliform bacteria, diarrhoea scores, and faecal gas emission in weaning pigs. A total of 144 weaning pigs [(Yorkshire × Landrace) × Duroc] were randomly allocated to four diets: corn-soybean meal-based diets supplemented with 0, 0.1, 0.5, or 1.0 g kg -1 levan-type fructan during this 42-day experiment. During days 0 to 21 and 0 to 42, average daily gain and average daily feed intake were linearly increased (P bacteria counts were linearly increased (P = 0.001). The results indicate that dietary supplementation with increasing levan-type fructan enhanced growth performance, improved nutrient digestibility, and increased faecal lactic acid bacteria counts in weaning pigs linearly. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

  6. Exergy analysis of waste emissions from gas flaring

    Directory of Open Access Journals (Sweden)

    Olawale Saheed ISMAIL

    2016-07-01

    Full Text Available Gas flaring produces a stream of waste gases at high temperature and pressure which contains carbon monoxide, Hydrogen Sulphide etc. The resultant effect of which is detrimental to our planet and, consequently, to the life of both the living and the non-living things. It’s well known that gas flaring contributes in no small measure to the global warming. Exergy analysis is applied in this work to analyze waste emissions from gas flaring so as to have a model through which impact of gas flaring can be measured. The study considers both the thermo-mechanical exergy and the chemical exergy of these gases. Relevant data on gas flaring activities in the Niger-Delta region of Nigeria between the periods of fifteen (15 years was obtained from the Nigerian National Petroleum Corporation (NNPC. A computer program (Exergy Calculator was developed based on the equations generated in the Model. Exergy associated with gas flaring activities in Nigeria between the periods of 1998 through 2012 was calculated. The results show that 1 mscf (in thousand cubic feet of flared gases generate 0.000041 MWh of energy leading to a value of 440158.607 MWh of energy for the period under review.The analysis provides important conclusions and recommendations for improving oil platforms operationsin in order to safeguard the environment, health of the populace, and maximize recovered exergy from gas flaring.

  7. Remote and Onsite Direct Measurements of Emissions from Oil and Natural Gas Production

    Science.gov (United States)

    Environmentally responsible oil and gas production requires accurate knowledge of emissions from long-term production operations1, which can include methane, volatile organic compounds, and hazardous air pollutants. Well pad emissions vary based on the geologically-determined com...

  8. Energy Intensity and Greenhouse Gas Emissions from Oil Production in the Eagle Ford Shale

    Energy Technology Data Exchange (ETDEWEB)

    Yeh, Sonia; Ghandi, Abbas; Scanlon, Bridget R.; Brandt, Adam R.; Cai, Hao; Wang, Michael Q.; Vafi, Kourosh; Reedy, Robert C.

    2017-01-30

    A rapid increase in horizontal drilling and hydraulic fracturing in shale and “tight” formations that began around 2000 has resulted in record increases in oil and natural gas production in the U.S. This study examines energy consumption and greenhouse gas (GHG) emissions from crude oil and natural gas produced from ~8,200 wells in the Eagle Ford Shale in southern Texas from 2009 to 2013. Our system boundary includes processes from primary exploration wells to the refinery entrance gate (henceforth well-to-refinery or WTR). The Eagle Ford includes four distinct production zones—black oil (BO), volatile oil (VO), condensate (C), and dry gas (G) zones—with average monthly gas-to-liquids ratios (thousand cubic feet per barrel—Mcf/bbl) varying from 0.91 in the BO zone to 13.9 in the G zone. Total energy consumed in drilling, extracting, processing, and operating an Eagle Ford well is ~1.5% of the energy content of the produced crude and gas in the BO and VO zones, compared with 2.2% in the C and G zones. On average, the WTR GHG emissions of gasoline, diesel, and jet fuel derived from crude oil produced in the BO and VO zones in the Eagle Ford play are 4.3, 5.0, and 5.1 gCO2e/MJ, respectively. Comparing with other known conventional and unconventional crude production where upstream GHG emissions are in the range 5.9–30 gCO2e/MJ, oil production in the Eagle Ford has lower WTR GHG emissions.

  9. Regulations for Greenhouse Gas Emissions from Passenger Cars and Trucks

    Science.gov (United States)

    EPA and the National Highway Traffic Safety Administration (NHTSA) are taking coordinated steps to enable the production of a new generation of clean vehicles, through reduced greenhouse gas (GHG) emissions and improved fuel use from onroad vehicles.

  10. Source limitation of carbon gas emissions in high-elevation mountain streams and lakes

    Science.gov (United States)

    Crawford, John T.; Dornblaser, Mark M.; Stanley, Emily H.; Clow, David W.; Striegl, Robert G.

    2015-01-01

    Inland waters are an important component of the global carbon cycle through transport, storage, and direct emissions of CO2 and CH4 to the atmosphere. Despite predictions of high physical gas exchange rates due to turbulent flows and ubiquitous supersaturation of CO2—and perhaps also CH4—patterns of gas emissions are essentially undocumented for high mountain ecosystems. Much like other headwater networks around the globe, we found that high-elevation streams in Rocky Mountain National Park, USA, were supersaturated with CO2 during the growing season and were net sources to the atmosphere. CO2concentrations in lakes, on the other hand, tended to be less than atmospheric equilibrium during the open water season. CO2 and CH4 emissions from the aquatic conduit were relatively small compared to many parts of the globe. Irrespective of the physical template for high gas exchange (high k), we found evidence of CO2 source limitation to mountain streams during the growing season, which limits overall CO2emissions. Our results suggest a reduced importance of aquatic ecosystems for carbon cycling in high-elevation landscapes having limited soil development and high CO2 consumption via mineral weathering.

  11. Greenhouse gas emissions from heavy-duty natural gas, hybrid, and conventional diesel on-road trucks during freight transport

    Science.gov (United States)

    Quiros, David C.; Smith, Jeremy; Thiruvengadam, Arvind; Huai, Tao; Hu, Shaohua

    2017-11-01

    Heavy-duty on-road vehicles account for 70% of all freight transport and 20% of transportation-sector greenhouse gas (GHG) emissions in the United States. This study measured three prevalent GHG emissions - carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O) - from seven heavy-duty vehicles, fueled by diesel and compressed natural gas (CNG), and compliant to the MY 2007 or 2010 U.S. EPA emission standards, while operated over six routes used for freight movement in California. Total combined (tractor, trailer, and payload) weights were 68,000 ± 1000 lbs. for the seven vehicles. Using the International Panel on Climate Change (IPCC) radiative forcing values for a 100-year time horizon, N2O emissions accounted for 2.6-8.3% of total tailpipe CO2 equivalent emissions (CO2-eq) for diesel vehicles equipped with Diesel Oxidation Catalyst, Diesel Particulate Filter, and Selective Catalytic Reduction system (DOC + DPF + SCR), and CH4 emissions accounted for 1.4-5.9% of CO2-eq emissions from the CNG-powered vehicle with a three-way catalyst (TWC). N2O emissions from diesel vehicles equipped with SCR (0.17-0.30 g/mi) were an order of magnitude higher than diesel vehicles without SCR (0.013-0.023 g/mi) during highway operation. For the vehicles selected in this test program, we measured 11-22% lower CO2-eq emissions from a hybrid compared to conventional diesel vehicles during transport over lower-speed routes of the freight transport system, but 20-27% higher CO2-eq emissions during higher-speed routes. Similarly, a CNG vehicle emitted up to 15% lower CO2-eq compared to conventional diesel vehicles over more neutral-grade highway routes, but emitted up to 12% greater CO2-eq emissions over routes with higher engine loads.

  12. Improvement of gas chromatographic analysis for organic acids and ...

    African Journals Online (AJOL)

    Yomi

    2010-08-27

    Aug 27, 2010 ... short retention time and fair recognition peak of the compounds were obtained under the ... GC for acid and solvent analysis from ABE fermentation ... FID was kept at 230°C. Nitrogen gas was used as a carrier gas at a.

  13. A forward looking, actor based, indicator for climate gas emissions

    Energy Technology Data Exchange (ETDEWEB)

    Ericson, Torgeir; Randers, Joergen

    2011-04-15

    The most commonly used Norwegian indicator for climate change displays historical emissions and compare with Norway's Kyoto target. This indicator says little about future emissions, about the ongoing Norwegian effort to reduce climate gas emissions, or about its effect on sustainability. In this paper we propose an indicator that improves on these weaknesses. We present a forward looking climate indicator that in addition to historic data includes business as usual scenarios, different proposals for future domestic emissions, and national or international commitments and agreements. This indicator presents - in one graph - a broad diversity of views on how the climate challenge should be handled from now and into the future. This indicator-graph may contribute to a more transparent discussion of available policy options. (Author)

  14. Separate effects of flooding and anaerobiosis on soil greenhouse gas emissions and redox sensitive biogeochemistry

    Science.gov (United States)

    Gavin McNicol; Whendee L. Silver

    2014-01-01

    Soils are large sources of atmospheric greenhouse gases, and both the magnitude and composition of soil gas emissions are strongly controlled by redox conditions. Though the effect of redox dynamics on greenhouse gas emissions has been well studied in flooded soils, less research has focused on redox dynamics without total soil inundation. For the latter, all that is...

  15. Greenhouse gas emission management in the US - current regional initiatives compared with international carbon trading programs

    International Nuclear Information System (INIS)

    Rink, A.G.; Law, S.

    2009-01-01

    In the United States (US) there are currently voluntary reporting programs (EPA Climate Leaders, Carbon Disclosure Project and The Climate Registry), organized market-based trading platforms (Chicago Climate Exchange and The Green Exchange) and proposed regional mandatory cap and trade programs in California, the Northeast, the West and the Midwest. The past success of the US Acid Rain 'cap-and-trade' system market-based format together with the availability of the European Union Emission Trading Scheme to serve as a template for future greenhouse gas regulations is promising as the US can participate in the world wide carbon markets already established. (author)

  16. Air Emission Projections During Acid Cleaning of F-Canyon Waste Header No.2

    International Nuclear Information System (INIS)

    CHOI, ALEXANDER

    2004-01-01

    The purpose of this study was to develop the air emission projections for the maintenance operation to dissolve and flush out the scale material inside the F-Canyon Waste Header No.2. The chemical agent used for the dissolution is a concentrated nitric acid solution, so the pollutant of concern is the nitric acid vapor. Under the very conservative operating scenarios considered in this study, it was determined that the highest possible rate of nitric acid emission during the acid flush would be 0.048 lb. per hr. It turns out that this worst-case air emission projection is just below the current exemption limit of 0.05 lb. per hr. for permit applications

  17. CRITERIA POLLUTANT EMISSIONS FROM INTERNAL COMBUSTION ENGINES IN THE NATURAL GAS INDUSTRY VOLUME 1. TECHNICAL REPORT

    Science.gov (United States)

    The report summarizes emission factors for criteria pollutants (NOx, CO, CH4, C2H6, THC, NMHC, and NMEHC) from stationary internal combustion engines and gas turbines used in the natural gas industry. The emission factors were calculated from test results from five test campaigns...

  18. The potential of natural gas as a bridging technology in low-emission road transportation in Germany

    Directory of Open Access Journals (Sweden)

    Wang-Helmreich Hanna

    2012-01-01

    Full Text Available Greenhouse gas emission reductions are at the centre of national and international efforts to mitigate climate change. In road transportation, many politically incentivised measures focus on increasing the energy efficiency of established technologies, or promoting electric or hybrid vehicles. The abatement potential of the former approach is limited, electric mobility technologies are not yet market-ready. In a case study for Germany, this paper focuses on natural gas powered vehicles as a bridging technology in road transportation. Scenario analyses with a low level of aggregation show that natural gas-based road transportation in Germany can accumulate up to 464 million tonnes of CO2-equivalent emission reductions until 2030 depending on the speed of the diffusion process. If similar policies were adopted EU-wide, the emission reduction potential could reach a maximum of about 2.5 billion tonnes of CO2-equivalent. Efforts to promote natural gas as a bridging technology may therefore contribute to significant emissions reductions.

  19. Experimental investigation of engine emissions with marine gas oil-oxygenate blends

    Energy Technology Data Exchange (ETDEWEB)

    Nabi, Md. Nurun, E-mail: nurun.nabi@ntnu.no [Rajshahi University of Engineering and Technology (Bangladesh); Norwegian University of Science and Technology (NTNU) (Norway); Hustad, Johan Einar, E-mail: johan.e.hustad@ntnu.no [Norwegian University of Science and Technology (NTNU) (Norway)

    2010-07-15

    This paper investigates the diesel engine performance and exhaust emissions with marine gas oil-alternative fuel additive. Marine gas oil (MGO) was selected as base fuel for the engine experiments. An oxygenate, diethylene glycol dimethyl ether (DGM), and a biodiesel (BD) jatropha oil methyl ester (JOME) with a volume of 10% were blended with the MGO fuel. JOME was derived from inedible jatropha oil. Lower emissions with diesel-BD blends (soybean methyl ester, rapeseed methyl ester etc.) have been established so far, but the effect of MGO-BD (JOME) blends on engine performance and emissions has been a growing interest as JOME (BD) is derived from inedible oil and MGO is frequently used in maritime transports. No phase separation between MGO-DGM and MGO-JOME blends was found. The neat MGO, MGO-DGM and MGO-JOME blends are termed as MGO, Ox10 and B10 respectively. The experiments were conducted with a six-cylinder, four-stroke, turbocharged, direct-injection Scania DC 1102 (DI) diesel engine. The experimental results showed significant reductions in fine particle number and mass emissions, PM and smoke emissions with Ox10 and B10 fuels compared to the MGO fuel. Other emissions including total unburned hydrocarbon (THC), carbon monoxide (CO) and engine noise were also reduced with the Ox10 and B10 fuels, while maintaining similar brake specific fuel consumption (BSFC) and thermal efficiency with MGO fuel. Oxides of nitrogen (NOx) emissions, on the other hand, were slightly higher with the Ox10 and B10 fuels at high engine load conditions.

  20. Experimental study of influence characteristics of flue gas fly ash on acid dew point

    Science.gov (United States)

    Song, Jinhui; Li, Jiahu; Wang, Shuai; Yuan, Hui; Ren, Zhongqiang

    2017-12-01

    The long-term operation experience of a large number of utility boilers shows that the measured value of acid dew point is generally lower than estimated value. This is because the influence of CaO and MgO on acid dew point in flue gas fly ash is not considered in the estimation formula of acid dew point. On the basis of previous studies, the experimental device for acid dew point measurement was designed and constructed, and the acid dew point under different smoke conditions was measured. The results show that the CaO and MgO in the flue gas fly ash have an obvious influence on the acid dew point, and the content of the fly ash is negatively correlated with the temperature of acid dew point At the same time, the concentration of H2SO4 in flue gas is different, and the acid dew point of flue gas is different, and positively correlated with the acid dew point.

  1. Greenhouse gas emissions in Hawaii. Household and visitor expenditure analysis

    International Nuclear Information System (INIS)

    Konan, Denise Eby; Chan, Hing Ling

    2010-01-01

    This paper focuses on petroleum use and greenhouse gas emissions associated with economic activities in Hawaii. Data on economic activity, petroleum consumption by type (gasoline, diesel, aviation fuel, residual, propane), and emissions factors are compiled and analyzed. In the baseline year 1997, emissions are estimated to total approximately 23.2 million metric tons of carbon, 181 thousand metric tons of nitrous oxide, and 31 thousand metric tons of methane in terms of carbon-equivalent global warming potential over a 100-year horizon. Air transportation, electricity, and other transportation are the key economic activity responsible for GHG emissions associated with fossil fuel use. More than 22% of total emissions are attributed to visitor expenditures. On a per person per annum basis, emission rates generated by visitor demand are estimated to be higher than that of residents by a factor of 4.3 for carbon, 3.2 for methane, and 4.8 for nitrous oxide. (author)

  2. An assessment of the torrefaction of North American pine and life cycle greenhouse gas emissions

    International Nuclear Information System (INIS)

    McNamee, P.; Adams, P.W.R.; McManus, M.C.; Dooley, B.; Darvell, L.I.; Williams, A.; Jones, J.M.

    2016-01-01

    Highlights: • Torrefaction of North American pine improves fuel properties. • Comparative LCA is presented of wood pellet and torrefied wood pellet supply. • Torrefied pellets offer energy and greenhouse gas savings but increase land use. • Torgas use is crucial for emission savings to offset fossil fuel use as utility fuel. • Shipping contributes largest emissions and long distance favours torrefied pellets. - Abstract: Bioenergy is increasingly being used to meet EU objectives for renewable energy generation and reducing greenhouse gas (GHG) emissions. Problems with using biomass however include high moisture contents, lower calorific value and poor grindability when compared to fossil fuels. Torrefaction is a pre-treatment process that aims to address these issues. In this paper four torrefaction treatments of pine were performed and a mass–energy balance calculated. Using experimental data, a pellet production supply chain incorporating torrefaction was modelled and compared to an existing wood pellet system to determine life-cycle GHG emissions. Two utility fuels, wood chips and natural gas, were considered to provide process heat in addition to volatile gases released during torrefaction (torgas). Experimental results show that torrefaction reduces the moisture content and increases the calorific value of the fuels. Increasing torrefaction temperature and residence time results in lower mass and energy yields. GHG emissions reduce with increasing torrefaction severity. Emissions from drying & torrefaction and shipping are the highest GHG contributors to the supply chain. All 4 torrefaction conditions assessed outperformed traditional wood pellet supply chain emissions but more land is required which increases with temperature and residence time. Sensitivity analysis results show that emissions increase significantly where natural gas is used for utility fuel and no torgas is utilised.

  3. Canadian options for greenhouse gas emission reduction (COGGER)

    International Nuclear Information System (INIS)

    Robinson, J.; Fraser, M.; Haites, E.; Harvey, D.; Jaccard, M.; Reinsch, A.; Torrie, R.

    1993-09-01

    A panel was formed to assess the feasibility and cost of energy-related greenhouse gas (GHG) emissions reduction in Canada. The panel studies focused on the potential for increased energy efficiency and fuel switching and their effect in reducing CO 2 emissions by reviewing the extensive literature available on those topics and assessing their conclusions. Economically feasible energy savings are estimated mostly in the range of 20-40% savings by the year 2010 relative to a reference-case projection, with a median of 23%. The panel concluded that achieving the identified economic potential for increased energy efficiency by 2010 will depend on development of additional demand-side management or energy efficiency programs that go well beyond current policies and programs. Fuel switching will play a much smaller role in stabilizing energy-related CO 2 emissions than improved energy efficiency. Technology substitution and broader structural change would enable Canada to achieve significant reductions in CO 2 emissions; however, more research is needed on achieving emission reductions that would approach the levels estimated to be required globally for stabilization of atmospheric CO 2 concentrations. Achieving such emissions reductions would likely require a combination of significant improvements in energy efficiency, major changes in energy sources, and substantial changes in economic activity and life styles, relative to that projected in most reference-case forecasts. 5 refs., 1 fig., 10 tabs

  4. Marine energy consumption, national economic activity, and greenhouse gas emissions from international shipping

    International Nuclear Information System (INIS)

    Chang, Ching-Chih

    2012-01-01

    The causal relationships among marine energy consumption, greenhouse gas emissions from international shipping, and economic growth for Kyoto Protocol Annex I countries for the period of 1990 to 2006 are discussed. The real gross domestic product is used as a proxy for economic activity. The United States is also discussed because it was the main global polluter before 2006. The co-integration methodology and an error-correction model are used to examine the causal relationships. The empirical results show that marine energy consumption and GDP are the main factors of increased GHG emissions in the short-run, and that economic activity significantly increased emissions in the long-run. Emissions from shipping are more closely related to marine energy consumption than to economic activity. Hence, policies for mitigating greenhouse gas emissions from marine shipping need to focus on greater energy efficiency in the design of ship engines and hulls. - Highlights: ► Energy consumption and GDP are the main causes to increased GHG emissions in the shipping industry. ► Emissions from shipping are more closely related to energy consumption than to GDP. ► Policies to mitigate GHG emissions from shipping industry should focus on the engine and hull design.

  5. Compliance with future emission standards of mobile machines by developing a monovalent natural gas combustion process

    International Nuclear Information System (INIS)

    Prehn, Sascha; Wichmann, Volker; Harndorf, Horst; Beberdick, Wolfgang

    2014-01-01

    Within the presented project a monovalent natural gas engine is being developed. Based on a serial diesel engine the operation mode of this prototype is changed to a spark ignition concept. The long term purpose of this new engine is an agricultural application. One major objective of the project is the investigation and evaluation of a combustion process, able to fulfil the performance requests as well as the European emission limits for nitrogen oxides NO x , and carbon monoxide CO of mobile machinery, which become into law in October 2014 (EU stage IV). At the time there are no legislative regulations existing regarding the methane emissions of the observed engines. To get a benefit in greenhouse gas emissions compared to diesel or gasoline engines the methane emissions have to be minimized while operating in natural gas mode. In the course of the current project an engine operation with a methane emission less than 0.5 g/kWh (representing the EURO VI limit for heavy duty vehicles) could be demonstrated. In contrast to diesel engines for agricultural applications it is possible to comply with the emission standards without using a high sophisticated after treatment system consisting of diesel oxidation catalyst (DOC), particulate filter (DPF) and SCR catalyst. The usage of a three way catalyst optimized for high methane conversions is sufficient for a stoichiometry gas operation with exhaust gas recirculation. Therefore a significant cost advantage is given.

  6. Greenhouse gas emissions from the international maritime transport of New Zealand's imports and exports

    International Nuclear Information System (INIS)

    Fitzgerald, Warren B.; Howitt, Oliver J.A.; Smith, Inga J.

    2011-01-01

    Greenhouse gas emissions from international maritime transport are exempt from liabilities under the Kyoto Protocol. Research into quantifying these emissions is ongoing, and influences policy proposals to reduce emissions. This paper presents a cargo-based analysis of fuel consumption and greenhouse gas emissions from New Zealand's international maritime transport of goods. Maritime transport moves 99.5% (by mass) of New Zealand's internationally traded products. It is estimated that 73% of visiting vessels' activity can be directly attributed to the movement of goods in and out of New Zealand. A cargo-based methodology was used to estimate that the international maritime transport of New Zealand's imports and exports consumed 2.5 million tonnes (Mt; 2.6 billion litres) of fuel during the year 2007, which generated 7.7 Mt of carbon dioxide (CO 2 ) emissions. Double-counting of emissions would occur if a similar method was applied to all New Zealand's trading partners. In contrast, since few large vessels refuel in New Zealand, the National Greenhouse Gas Inventory listed 2007 international maritime transportation emissions as 0.98 Mt of CO 2 , calculated from fuel bunkered for international transport. The results, therefore, show a significant difference between activity-based and bunker-fuel methodologies in quantifying New Zealand's emissions. International policy implications are discussed. - Research highlights: → Cargo-based analysis of GHG emissions from New Zealand's international maritime transport of goods. → 7.7 Mt of CO 2 estimated from international maritime transport of NZ's 2007 imports and exports. → 73% of visiting vessels' 2007 activity attributed to the movement of goods in and out of NZ. → The results were significantly different from NZ's GHG Inventory bunker-fuel derived emissions figure. → Detailed approach for international transport emissions regional/national assessments described.

  7. Variable composition hydrogen/natural gas mixtures for increased engine efficiency and decreased emissions

    Energy Technology Data Exchange (ETDEWEB)

    Sierens, R.; Rosseel, E.

    2000-01-01

    It is well known that adding hydrogen to natural gas extends the lean limit of combustion and that in this way extremely low emission levels can be obtained: even the equivalent zero emission vehicle (EZEV) requirements can be reached. The emissions reduction is especially important at light engine loads. In this paper results are presented for a GM V8 engine. Natural gas, pure hydrogen and different blends of these two fuels have been tested. The fuel supply system used provides natural gas/hydrogen mixtures in variable proportion, regulated independently of the engine operating condition. The influence of the fuel composition on the engine operating characteristics and exhaust emissions has been examined, mainly but not exclusively for 10 and 20% hydrogen addition. At least 10% hydrogen addition is necessary for a significant improvement in efficiency. Due to the conflicting requirements for low hydrocarbons and low NO{sub x} determining the optimum hythane composition is not straight-forward. For hythane mixtures with a high hydrogen fraction, it is found that a hydrogen content of 80% or less guarantees safe engine operation (no backfire nor knock), whatever the air excess factor. It is shown that to obtain maximum engine efficiency for the whole load range while taking low exhaust emissions into account, the mixture composition should be varied with respect to engine load.

  8. ON THE STUDY OF GHG (GREENHOUSE GAS EMISSIONS IN RICE PRODUCTION SYSTEMS IN DARGAZ, IRAN

    Directory of Open Access Journals (Sweden)

    Ghorbanali RASSAM

    2015-12-01

    Full Text Available The most important issue which has attracted the attention of many scientists is the climate change and global warming due to greenhouse gas emission which has caused the world faced with a great human and environmental disaster. In this study, the amount of greenhouse gas (GHG emissions was estimated in the semi-traditional and semi-mechanized rice production systems in Dargaz region, Iran. All the agricultural and consuming inputs procedures responsible for greenhouse gas emissions were collected and recorded in both systems. The amount of GHG emission in semi-traditional and semi-mechanized was 813.17 and 968.31 kg CO2-eq ha-1, respectively. The fuel consumption with the share of 38.22% in semi-traditional method and 43.32% in semi-mechanized system had the largest share in GHG emission and using Nitrogen fertilizer on farms with the share of 31.97% in semi-traditional method and 26.91% in semi-mechanized system is in the second place of GHG emission. The semi-traditional system had greater GHG emissions in the unit of tone of harvested grain and unit of energy output. The use of alternative methods such as conservation tillage and organic fertilizers can be effective in improving the environmental status of the production area.

  9. 76 FR 65971 - Greenhouse Gas Emissions Standards and Fuel Efficiency Standards for Medium- and Heavy-Duty...

    Science.gov (United States)

    2011-10-25

    ... DEPARTMENT OF TRANSPORTATION National Highway Traffic Safety Administration 49 CFR Parts 523 and 535 [NHTSA 2010-0079; EPA-HQ-OAR-2010-0162; FRL-9455-1] RIN 2127-AK74 Greenhouse Gas Emissions... fuel efficiency and reduce greenhouse gas emissions for on-road heavy-duty vehicles, responding to the...

  10. 76 FR 59922 - Greenhouse Gas Emissions Standards and Fuel Efficiency Standards for Medium- and Heavy-Duty...

    Science.gov (United States)

    2011-09-28

    ... DEPARTMENT OF TRANSPORTATION National Highway Traffic Safety Administration 49 CFR Part 535 [NHTSA 2010-0079; EPA-HQ-OAR-2010-0162; FRL-9455-1] RIN 2127-AK74 Greenhouse Gas Emissions Standards and Fuel... comprehensive Heavy-Duty National Program that will increase fuel efficiency and reduce greenhouse gas emissions...

  11. Protocol for the quantification of greenhouse gas emissions from waste management activities

    International Nuclear Information System (INIS)

    2013-10-01

    The Waste Sector GHG Protocol is intended to provide guidelines for calculating and reporting greenhouse gas (GHG) emissions associated with a waste management service, over a specific time period (usually one year) and based on simple operational data. The Protocol itself has evolved with time, going through 4 version updates. The different versions correspond to evolutions initiated by the original Entreprises pour l'Environnement Working Group (Seche Environnement, Suez Environnement and Veolia Environnement) but also to the suggestions and feedback provided by several waste associations that have reviewed and commented on the Protocol. As a result, several worldwide associations have validated and used the Protocol for their own greenhouse gas inventories. The version 5 of the Waste Sector GHG Protocol has received the 'Built on the GHG Protocol' label. With such label, the Waste Sector Protocol reinforces its desire to be the reference tool for the waste sector by ensuring its users of a total and transparent coherence and conformity with the GHG Protocol Corporate Standard's requirements. The Protocol is also available on the following web page: http://www.ghgprotocol.org/Tools-Built-on-GHG-Protocol. The Waste Sector GHG Protocol aims at: Providing a consistent and transparent approach to quantify, report and verify GHG direct (scope 1), indirect (scope 2) and avoided emissions of waste management actors; Establishing best practice across the waste sector for the implementation of coherent and homogeneous GHG emissions inventories; Explaining waste sector's particularities in terms of GHG emissions (diffuse emission from landfills, GHG avoided emissions, carbon sequestration); Helping companies to take proper commitments and stakeholders to understand and verify those commitments. The Protocol consists of a manual with two additional documents: A 'Frequently Asked Questions' document; A 'Follow-up of modifications

  12. Reduction of energy cost and CO2 emission for the furnace using energy recovered from waste tail-gas

    International Nuclear Information System (INIS)

    Jou, Chih-Ju G.; Wu, Chung-Rung; Lee, Chien-Li

    2010-01-01

    In this research, the waste tail gas emitted from petrochemical processes, e.g. catalytic reforming unit, catalytic cracking unit and residue desulfurization unit, was recovered and reused as a replacement of natural gas (NG). On-site experimental results show that both the flame length and orange-yellowish brightness decrease with more proportion of waste gas fuel added to the natural gas, and that the adiabatic temperature of the mixed fuel is greater than 1800 o C. A complete replacement of natural gas by the recovered waste gas fuel will save 5.8 x 10 6 m 3 of natural gas consumption, and 3.5 x 10 4 tons of CO 2 emission annually. In addition, the reduction of residual O 2 concentration in flue gases from 4% to 3% will save 1.1 x 10 6 m 3 of natural gas consumption, reduce 43.0% of NO x emission, and 1.3 x 10 3 tons of CO 2 emission annually. Thus, from the viewpoint of the overall economics and sustainable energy policy, recovering the waste tail gas energy as an independent fuel source to replace natural gas is of great importance for saving energy, reducing CO 2 emission reduction, and lowering environmental impact.

  13. Identification of Cyclopentenyl Fatty Acids by Gas Liquid Chromatography and Mass Spectrometry

    DEFF Research Database (Denmark)

    Shukla, V. K. S.; Abdel-Moety, E. M.; Larsen, Elfinn

    1979-01-01

    The straight chain fatty acids and the cyclopentenyl fatty acids present in the lipids of Hydnocarpus wightiana seeds were separated as their pyrrolidides by means of gas chromatography. A gas chromatography-mass spectrometry system confirmed the complete separation and permitted the identification...

  14. Cradle-to-gate greenhouse gas emissions of battery electric and internal combustion engine vehicles in China

    International Nuclear Information System (INIS)

    Qiao, Qinyu; Zhao, Fuquan; Liu, Zongwei; Jiang, Shuhua; Hao, Han

    2017-01-01

    Highlights: •Cradle-to-gate greenhouse gas emissions of internal combustion engine and battery electric vehicles are compared. •Greenhouse gas emissions of battery electric vehicles are 50% higher than internal combustion engine vehicles. •Traction battery production causes about 20% greenhouse gas emissions increase. •10% variations of curb weight, electricity and Li-ion battery production affect the results by 7%, 4% and 2%. •Manufacturing technique improvement, vehicle recycling and energy structure optimization are major mitigation opportunities. -- Abstract: Electric drive vehicles are equipped with totally different propulsion systems compared with conventional vehicles, for which the energy consumption and cradle-to-gate greenhouse gas emissions associated with vehicle production could substantially change. In this study, the life cycle energy consumption and greenhouse gas emissions of vehicle production are compared between battery electric and internal combustion engine vehicles in China’s context. The results reveal that the energy consumption and greenhouse gas emissions of a battery electric vehicle production range from 92.4 to 94.3 GJ and 15.0 to 15.2 t CO 2 eq, which are about 50% higher than those of an internal combustion engine vehicle, 63.5 GJ and 10.0 t CO 2 eq. This substantial change can be mainly attributed to the production of traction batteries, the essential components for battery electric vehicles. Moreover, the larger weight and different weight distribution of materials used in battery electric vehicles also contribute to the larger environmental impact. This situation can be improved through the development of new traction battery production techniques, vehicle recycling and a low-carbon energy structure.

  15. Limiting net greenhouse gas emissions in the United States

    Energy Technology Data Exchange (ETDEWEB)

    Bradley, R A; Watts, E C; Williams, E R [eds.

    1991-09-01

    In 1988, Congress requested that DOE produce a study on carbon dioxide inventory and policy to provide an inventory of emissions sources and to analyze policies to achieve a 20% reduction in carbon dioxide emissions in 5 to 10 years and a 50% reduction in 15 to 20 years. Energy and environmental technology data were analyzed using computational analysis models. This information was then evaluated, drawing on current scientific understanding of global climate change, the possible consequences of anthropogenic climate change (change caused by human activity) and the relationship between energy production and use and the emission of radiatively important gases. Topics discussed include: state of the science in estimating atmosphere/climate change relationships, the potential consequences of atmosphere/climate change, us greenhouse emissions past and present, an approach to analyzing the technical potential and cost of reducing US energy-related greenhouse gas emissions, current policy base and National Energy Strategy actions, fiscal instruments, regulatory instruments, combined strategies and instruments, macroeconomic impacts, carbon taxation and international trade, a comparison to other studies.

  16. Addressing biogenic greenhouse gas emissions from hydropower in LCA.

    Science.gov (United States)

    Hertwich, Edgar G

    2013-09-03

    The ability of hydropower to contribute to climate change mitigation is sometimes questioned, citing emissions of methane and carbon dioxide resulting from the degradation of biogenic carbon in hydropower reservoirs. These emissions are, however, not always addressed in life cycle assessment, leading to a bias in technology comparisons, and often misunderstood. The objective of this paper is to review and analyze the generation of greenhouse gas emissions from reservoirs for the purpose of technology assessment, relating established emission measurements to power generation. A literature review, data collection, and statistical analysis of methane and CO2 emissions are conducted. In a sample of 82 measurements, methane emissions per kWh hydropower generated are log-normally distributed, ranging from micrograms to 10s of kg. A multivariate regression analysis shows that the reservoir area per kWh electricity is the most important explanatory variable. Methane emissions flux per reservoir area are correlated with the natural net primary production of the area, the age of the power plant, and the inclusion of bubbling emissions in the measurement. Even together, these factors fail to explain most of the variation in the methane flux. The global average emissions from hydropower are estimated to be 85 gCO2/kWh and 3 gCH4/kWh, with a multiplicative uncertainty factor of 2. GHG emissions from hydropower can be largely avoided by ceasing to build hydropower plants with high land use per unit of electricity generated.

  17. Possibilities for the reduction of CO2- and CH4-emissions of natural gas

    International Nuclear Information System (INIS)

    Muessig, S.

    1994-01-01

    The use of fossil fuels increases the portion of greenhouse gases, especially CO 2 and CH 4 . In this paper firstly the specific emission rates of these greenhouse gases for the various fuels are compared. Secondly possibilities for the reduction of CO 2 and CH 4 for natural gas which are relatively small anyhow are discussed. Thirdly the use of renewable energy within the gas industry and the ocean and into depleted reservoirs are discussed. It is shown that the efficient use of energy of the fossil fuel natural gas is most successful in all branches of gas consumption to decrease emission. Combined-cycle processes, cogeneration as well as modern domestic heating systems are described. Fuel cells and the application of hydrogen is shortly discussed. (orig.)

  18. Quantifying Fugitive Methane Emissions from Natural Gas Production with Mobile Technology

    Science.gov (United States)

    Tsai, T.; Rella, C.; Crosson, E.

    2013-12-01

    Quantification of fugitive methane (CH4) emissions to determine the environmental impact of natural gas production is challenging with current methods. We present a new mobile method known as the Plume Scanner that can quickly quantify CH4 emissions of point sources. The Plume Scanner is a direct measurement technique which utilizes a mobile Picarro cavity ring-down spectrometer and a gas sampling system based on AirCore technology [1]. As the Plume Scanner vehicle drives through the plume, the air is simultaneously sampled at four different heights, and therefore, the spatial CH4 distribution can be captured (Fig. 1). The flux of the plume is then determined by multiplying the spatial CH4 distribution data with the anemometer measurements. In this way, fugitive emission rates of highly localized sources such as natural gas production pads can be made quickly (~7 min). Verification with controlled CH4 releases demonstrate that under stable atmospheric conditions (Pasquill stability class is C or greater), the Plume Scanner measurements have an error of 2% and a repeatability of 15% [2]. Under unstable atmospheric conditions (Class A or B), the error is 6%, and the repeatability increases to 70% due to the variability of wind conditions. Over two weeks, 275 facilities in the Barnett Shale were surveyed from public roads by sampling the air for elevations in CH4 concentration, and 77% were found leaking. Emissions from 52 sites have been quantified with the Plume Scanner (Fig. 2), and the total emission is 4,900 liters per min (lpm) or 39,000 metric tons/yr CO2e. 1. Karion, A., C. Sweeney, P. Tans, and T. Newberger (2010), AirCore: An innovative atmospheric sampling system, J. Atmos. Oceanic Tech, 27, 1839-1853. 2. F. Pasquill (1961), The estimation of the dispersion of wind borne material, Meterol. Mag., 90(1063), 33-49 Figure 1. Plume Scanner Cartoon Figure 2. Distribution of methane fugitive emissions with error bars associated with the Pasquill stability classes

  19. 77 FR 49489 - Oil and Natural Gas Sector: New Source Performance Standards and National Emission Standards for...

    Science.gov (United States)

    2012-08-16

    ..., centrifugal compressors, reciprocating compressors, pneumatic controllers and storage vessels. This action... organic compound (VOC) emissions from gas wells, centrifugal compressors, reciprocating compressors... emissions from wet seal centrifugal compressors located between the wellhead and the point at which the gas...

  20. The analysis of energy consumption and greenhouse gas emissions of a large-scale commercial building in Shanghai, China

    Directory of Open Access Journals (Sweden)

    Xin Wang

    2016-02-01

    Full Text Available Reasonable test, diagnosis, and analysis are meaningful for building energy efficiency retrofit and management. Energy consumption and greenhouse gas emission of a large-scale commercial building are described in this article. Basic information about energy consumption equipment is included in the investigation. Further diagnoses about the operational state of air-conditioning water systems, and ducted systems were implemented. Energy consumption decreased 200 kWh/m2 per year from 2007 to 2009 after energy-saving reconstruction in 2006. Next, a carbon audit was carried out; this comprised CO2 emission statistics associated with the energy use and categorization and structural analysis (categorization refers to energy categorization and structural analysis means the composition and its proportion relationship of all kinds of primary energy and secondary energy in energy production or consumption. Greenhouse gas emissions could be less than 150 kg/m2 per year from 2007 to 2009. An analysis of the correlation between CO2 emissions, building gross domestic product, and energy efficiency is also presented. This article makes an analysis on the energy utilization and energy-saving reconstruction of a public commercial building in Shanghai and then makes an analysis of carbon audit about greenhouse gas emissions related to energy utilization (it analyzes the status of building’s energy utilization and greenhouse gas emissions, to have a more comprehensive understanding on the internal relationship between energy consumption and its greenhouse gas emissions and provide researchful reference data for the development with reduction strategies of greenhouse gas emission in future building.

  1. Tradeoffs between costs and greenhouse gas emissions in the design of urban transit systems

    International Nuclear Information System (INIS)

    Griswold, Julia B; Madanat, Samer; Horvath, Arpad

    2013-01-01

    Recent investments in the transit sector to address greenhouse gas emissions have concentrated on purchasing efficient replacement vehicles and inducing mode shift from the private automobile. There has been little focus on the potential of network and operational improvements, such as changes in headways, route spacing, and stop spacing, to reduce transit emissions. Most models of transit system design consider user and agency cost while ignoring emissions and the potential environmental benefit of operational improvements. We use a model to evaluate the user and agency costs as well as greenhouse gas benefit of design and operational improvements to transit systems. We examine how the operational characteristics of urban transit systems affect both costs and greenhouse gas emissions. The research identifies the Pareto frontier for designing an idealized transit network. Modes considered include bus, bus rapid transit (BRT), light rail transit (LRT), and metro (heavy) rail, with cost and emissions parameters appropriate for the United States. Passenger demand follows a many-to-many travel pattern with uniformly distributed origins and destinations. The approaches described could be used to optimize the network design of existing bus service or help to select a mode and design attributes for a new transit system. The results show that BRT provides the lowest cost but not the lowest emissions for our large city scenarios. Bus and LRT systems have low costs and the lowest emissions for our small city scenarios. Relatively large reductions in emissions from the cost-optimal system can be achieved with only minor increases in user travel time. (letter)

  2. Policy Considerations for Greenhouse Gas Emissions from Freshwater Reservoirs

    Directory of Open Access Journals (Sweden)

    Kirsi Mäkinen

    2010-06-01

    Full Text Available Emerging concern over greenhouse gas (GHG emissions from wetlands has prompted calls to address the climate impact of dams in climate policy frameworks. Existing studies indicate that reservoirs can be significant sources of emissions, particularly in tropical areas. However, knowledge on the role of dams in overall national emission levels and abatement targets is limited, which is often cited as a key reason for political inaction and delays in formulating appropriate policies. Against this backdrop, this paper discusses the current role of reservoir emissions in existing climate policy frameworks. The distance between a global impact on climate and a need for local mitigation measures creates a challenge for designing appropriate mechanisms to combat reservoir emissions. This paper presents a range of possible policy interventions at different scales that could help address the climate impact of reservoirs. Reservoir emissions need to be treated like other anthropogenic greenhouse gases. A rational treatment of the issue requires applying commonly accepted climate change policy principles as well as promoting participatory water management plans through integrated water resource management frameworks. An independent global body such as the UN system may be called upon to assess scientific information and develop GHG emissions policy at appropriate levels.

  3. Future Greenhouse Gas and Local Pollutant Emissions for India: Policy Links and Disjoints

    Energy Technology Data Exchange (ETDEWEB)

    Garg, A. [Project Management Cell, NATCOM Project, Winrock International India, 7, Poorvi Marg, Vasant Vihar, New Delhi - 110057 (India); Shukla, P.R. [Public Systems Group, Indian Institute of Management, Vastrapur, Ahmedabad 380015 (India); Ghosh, D. [Kennedy School of Government, Harvard University (United States); Kapshe, M.; Rajesh, N. [Indian Institute of Management, Vastrapur, Ahmedabad 380015 (India)

    2003-07-01

    This paper estimates the future greenhouse gas (GHG) and local pollutant emissions for India under various scenarios. The reference scenario assumes continuation of the current official policies of the Indian government and forecasts of macro-economic, demographic and energy sector indicators. Other scenarios analyzed are the economic growth scenarios (high and low), carbon mitigation scenario, sulfur mitigation scenario and frozen (development) scenario. The main insight is that GHG and local pollutant emissions from India, although connected, do not move in synchronization in future and have a disjoint under various scenarios. GHG emissions continue to rise while local pollutant emissions decrease after some years. GHG emission mitigation therefore would have to be pursued for its own sake in India. National energy security concerns also favor this conclusion since coal is the abundant national resource while most of the natural gas has to be imported. The analysis of contributing factors to this disjoint indicates that sulfur reduction in petroleum oil products and penetration of flue gas desulfurisation technologies are the two main contributors for sulfur dioxide (SO2) mitigation. The reduction in particulate emissions is mainly due to enforcing electro-static precipitator efficiency norms in industrial units, with cleaner fuels and vehicles also contributing substantially. These policy trends are already visible in India. Another insight is that high economic growth is better than lower growth to mitigate local pollution as lack of investible resources limits investments in cleaner environmental measures. Our analysis also validates the environmental Kuznets' curve for India as SO2 emissions peak around per capita GDP of US$ 5,300-5,400 (PPP basis) under various economic growth scenarios.

  4. Quantifying the relative contribution of natural gas fugitive emissions to total methane emissions in Colorado, Utah, and Texas using mobile isotopic methane analysis based on Cavity Ringdown Spectroscopy

    Science.gov (United States)

    Rella, Chris; Winkler, Renato; Sweeney, Colm; Karion, Anna; Petron, Gabrielle; Crosson, Eric

    2014-05-01

    Fugitive emissions of methane into the atmosphere are a major concern facing the natural gas production industry. Because methane is more energy-rich than coal per kg of carbon dioxide emitted into the atmosphere, it represents an attractive alternative to coal for electricity generation, provided that the fugitive emissions of methane are kept under control. A key step in assessing these emissions in a given region is partitioning the observed methane emissions between natural gas fugitive emissions and other sources of methane, such as from landfills or agricultural activities. One effective method for assessing the contribution of these different sources is stable isotope analysis, using the isotopic carbon signature to distinguish between natural gas and landfills or ruminants. We present measurements of methane using a mobile spectroscopic stable isotope analyzer based on cavity ringdown spectroscopy, in three intense natural gas producing regions of the United States: the Denver-Julesburg basin in Colorado, the Uintah basin in Utah, and the Barnett Shale in Texas. Performance of the CRDS isotope analyzer is presented, including precision, calibration, stability, and the potential for measurement bias due to other atmospheric constituents. Mobile isotope measurements of individual sources and in the nocturnal boundary layer have been combined to establish the fraction of the observed methane emissions that can be attributed to natural gas activities. The fraction of total methane emissions in the Denver-Julesburg basin attributed to natural gas emissions is 78 +/- 13%. In the Uinta basin, which has no other significant sources of methane, the fraction is 96% +/- 15%. In addition, results from the Barnett shale are presented, which includes a major urban center (Dallas / Ft. Worth). Methane emissions in this region are spatially highly heterogeneous. Spatially-resolved isotope and concentration measurements are interpreted using a simple emissions model to

  5. Emission characterization and evaluation of natural gas-fueled cogeneration microturbines and internal combustion engines

    International Nuclear Information System (INIS)

    Canova, Aldo; Chicco, Gianfranco; Genon, Giuseppe; Mancarella, Pierluigi

    2008-01-01

    The increasing diffusion of small-scale energy systems within the distributed generation (DG) paradigm is raising the need for studying the environmental impact due to the different DG solutions in order to assess their sustainability. Addressing the environmental impact calls for building specific models for studying both local and global emissions. In this framework, the adoption of natural gas-fueled DG cogeneration technologies may provide, as a consequence of cogeneration enhanced overall energy efficiency and of natural gas relatively low carbon content, a significant reduction of global impact in terms of CO 2 emissions with respect to the separate production of electricity and heat. However, a comprehensive evaluation of the DG alternatives should take into account as well the impact due to the presence of plants spread over the territory that could increase the local pollution, in particular due to CO and NO x , and thus could worsen the local air quality. This paper provides an overview on the characterization of the emissions from small-scale natural gas-fueled cogeneration systems, with specific reference to the DG technologies nowadays most available in the market, namely, microturbines and internal combustion engines. The corresponding local and global environmental impacts are evaluated by using the emission balance approach. A numerical case study with two representative machines highlights their different emission characteristics, also considering the partial-load emission performance

  6. Energy utilization and greenhouse-gas emissions: Transportation sector, topical report

    International Nuclear Information System (INIS)

    Darrow, K.G.

    1992-06-01

    The objective of the report is to compare the emissions of greenhouse gases for alternative end-use technologies in the transportation sector. Scientists assert that global warming is occurring and will continue to occur as a result of increasing concentrations of certain gases in the atmosphere. Carbon dioxide (CO2), methane (CH4), and nitrous oxide (N2O) are the focus of this analysis because they are believed to cause three-fourths of the global warming effect and because energy production and use are a significant source of these emissions. Greenhouse gas emissions in the energy sector occur during energy production, conversion, transportation and end-use. This analysis compares alternative transportation sector fuel/technology choices in terms of their total fuel-cycle emissions of greenhouse gases. The emphasis of this report is on the end use comparison. The fuel-cycle emissions comparison was developed in a companion report

  7. Multispectral Observations of Explosive Gas Emissions from Santiaguito, Guatemala

    Science.gov (United States)

    Carn, S. A.; Watson, M.; Thomas, H.; Rodriguez, L. A.; Campion, R.; Prata, F. J.

    2016-12-01

    Santiaguito volcano, Guatemala, has been persistently active for decades, producing frequent explosions from its actively growing lava dome. Repeated release of volcanic gases contains information about conduit processes during the cyclical explosions at Santiaguito, but the composition of the gas phase and the amount of volatiles released in each explosion remains poorly constrained. In addition to its persistent activity, Santiaguito offers an exceptional opportunity to investigate lava dome degassing processes since the upper surface of the active lava dome can be viewed from the summit of neighboring Santa Maria. In January 2016 we conducted multi-spectral observations of Santiaguito's explosive eruption plumes and passive degassing from multiple perspectives as part of the first NSF-sponsored `Workshop on Volcanoes' instrument deployment. Gas measurements included open-path Fourier-Transform infrared (OP-FTIR) spectroscopy from the Santa Maria summit, coincident with ultraviolet (UV) and infrared (IR) camera and UV Differential Optical Absorption Spectroscopy (DOAS) from the El Mirador site below Santiaguito's active Caliente lava dome. Using the OP-FTIR in passive mode with the Caliente lava dome as the source of IR radiation, we were able to collect IR spectra at high temporal resolution prior to and during two explosions of Santiaguito on 7-8 January, with volcanic SO2 and H2O emissions detected. UV and IR camera data provide constraints on the total SO2 burden in the emissions (and potentially the volcanic ash burden), which coupled with the FTIR gas ratios provides new constraints on the mass and composition of volatiles driving explosions at Santiaguito. All gas measurements indicate significant volatile release during explosions with limited degassing during repose periods. In this presentation we will present ongoing analysis of the unique Santiaguito gas dataset including estimation of the total volatile mass released in explosions and an

  8. Future methane emissions from the heavy-duty natural gas transportation sector for stasis, high, medium, and low scenarios in 2035.

    Science.gov (United States)

    Clark, Nigel N; Johnson, Derek R; McKain, David L; Wayne, W Scott; Li, Hailin; Rudek, Joseph; Mongold, Ronald A; Sandoval, Cesar; Covington, April N; Hailer, John T

    2017-12-01

    Today's heavy-duty natural gas-fueled fleet is estimated to represent less than 2% of the total fleet. However, over the next couple of decades, predictions are that the percentage could grow to represent as much as 50%. Although fueling switching to natural gas could provide a climate benefit relative to diesel fuel, the potential for emissions of methane (a potent greenhouse gas) from natural gas-fueled vehicles has been identified as a concern. Since today's heavy-duty natural gas-fueled fleet penetration is low, today's total fleet-wide emissions will be also be low regardless of per vehicle emissions. However, predicted growth could result in a significant quantity of methane emissions. To evaluate this potential and identify effective options for minimizing emissions, future growth scenarios of heavy-duty natural gas-fueled vehicles, and compressed natural gas and liquefied natural gas fueling stations that serve them, have been developed for 2035, when the populations could be significant. The scenarios rely on the most recent measurement campaign of the latest manufactured technology, equipment, and vehicles reported in a companion paper as well as projections of technology and practice advances. These "pump-to-wheels"(PTW) projections do not include methane emissions outside of the bounds of the vehicles and fuel stations themselves and should not be confused with a complete wells-to-wheels analysis. Stasis, high, medium, and low scenario PTW emissions projections for 2035 were 1.32%, 0.67%, 0.33%, and 0.15% of the fuel used. The scenarios highlight that a large emissions reductions could be realized with closed crankcase operation, improved best practices, and implementation of vent mitigation technologies. Recognition of the potential pathways for emissions reductions could further enhance the heavy-duty transportation sectors ability to reduce carbon emissions. Newly collected pump-to-wheels methane emissions data for current natural gas technologies

  9. Improvement performance and emissions in a diesel engine dual-fueled with natural gas; Tennen gas dual fuel diesel kikan no seino haishutsu gas tokusei no kaizen

    Energy Technology Data Exchange (ETDEWEB)

    Nakayama, S; Okamoto, T; Kusaka, J; Daisho, Y; Kihara, R; Saito, T [Waseda University, Tokyo (Japan)

    1997-10-01

    This paper deals with a study on combustion and emission characteristics of a direct injection diesel engine dual-fueled with natural gas. Dual fueling systems tend to emit high unburned fuel especially at low load, resulting in a decreased thermal efficiency. This is because natural gas-air mixtures are too lean for flame to propagate under low load conditions. Intake charge heating and uncooled EGR are very useful to improve emissions and thermal efficiency at low load. Such favorable effects are supported by NO kinetic simulations. 2 refs., 13 figs.

  10. Gas-phase chemical characteristics of Asian emission plumes observed during ITCT 2K2 over the eastern North Pacific Ocean

    Science.gov (United States)

    Nowak, J. B.; Parrish, D. D.; Neuman, J. A.; Holloway, J. S.; Cooper, O. R.; Ryerson, T. B.; Nicks, D. K.; Flocke, F.; Roberts, J. M.; Atlas, E.; de Gouw, J. A.; Donnelly, S.; Dunlea, E.; Hübler, G.; Huey, L. G.; Schauffler, S.; Tanner, D. J.; Warneke, C.; Fehsenfeld, F. C.

    2004-12-01

    The gas-phase chemical characteristics of emission plumes transported from Asia across the Pacific Ocean observed during the Intercontinental Transport and Chemical Transformation experiment in 2002 (ITCT 2K2) are described. Plumes measured in the troposphere from an aircraft were separated from the background air in data analysis using 1-s measurements of carbon monoxide (CO), total reactive nitrogen (NOy), and other gas-phase species along with back trajectory analysis. On the basis of these measurements, Asian transport plumes with CO mixing ratios greater than 150 ppbv were observed on seven flights. Correlations between 1-s observations of CO, ozone (O3), and NOy are used to characterize the plumes. The NOy/CO ratios were similar in each plume and significantly lower than those derived from estimated Asian emission ratios, indicating substantial removal of soluble NOy species during transport. Observations of nitric oxide (NO), nitrogen dioxide (NO2), nitric acid (HNO3), peroxyacetyl nitrate (PAN), peroxypropionyl nitrate (PPN), and alkyl nitrates are used with the NOy measurements to further distinguish the transport plumes by their NOy partitioning. NOy was primarily in the form of PAN in plumes that were transported in cold high-latitude and high-altitude regions, whereas in plumes transported in warmer, lower latitude and altitude regions, NOy was mainly HNO3. Additional gas-phase species enhanced in these plumes include sulfuric acid, methanol, acetone, propane, and ethane. The O3/CO ratio varied among the plumes and was affected by the mixing of anthropogenic and stratospheric influences. The complexity of this mixing prevents the determination of the relative contribution of anthropogenic and stratospheric influences to the observed O3 levels.

  11. [Investigation on the gas temperature of a plasma jet at atmospheric pressure by emission spectrum].

    Science.gov (United States)

    Li, Xue-chen; Yuan, Ning; Jia, Peng-ying; Niu, Dong-ying

    2010-11-01

    A plasma jet of a dielectric barrier discharge in coaxial electrode was used to produce plasma plume in atmospheric pressure argon. Spatially and temporally resolved measurement was carried out by photomultiplier tubes. The light emission signals both from the dielectric barrier discharge and from the plasma plume were analyzed. Furthermore, emission spectrum from the plasma plume was collected by high-resolution optical spectrometer. The emission spectra of OH (A 2sigma + --> X2 II, 307.7-308.9 nm) and the first negative band of N2+ (B2 sigma u+ --> X2 IIg+, 390-391.6 nm) were used to estimate the rotational temperature of the plasma plume by fitting the experimental spectra to the simulated spectra. The rotational temperature obtained is about 443 K by fitting the emission spectrum from the OH, and that from the first negative band of N2+ is about 450 K. The rotational temperatures obtained by the two method are consistent within 5% error band. The gas temperature of the plasma plume at atmospheric pressure was obtained because rotational temperature equals to gas temperature approximately in gas discharge at atmospheric pressure. Results show that gas temperature increases with increasing the applied voltage.

  12. Emissions from Biomass Burning in the Yucatan

    Science.gov (United States)

    Yokelson, R.; Crounse, J. D.; DeCarlo, P. F.; Karl, T.; Urbanski, S.; Atlas, E.; Campos, T.; Shinozuka, Y.; Kapustin, V.; Clarke, A. D.; hide

    2009-01-01

    In March 2006 two instrumented aircraft made the first detailed field measurements of biomass burning (BB) emissions in the Northern Hemisphere tropics as part of the MILAGRO project. The aircraft were the National Center for Atmospheric Research C-130 and a University of Montana/US Forest Service Twin Otter. The initial emissions of up to 49 trace gas or particle species were measured from 20 deforestation and crop residue fires on the Yucatan peninsula. This included two trace gases useful as indicaters of BB (HCN and acetonitrile) and several rarely, or never before, measured species: OH, peroxyacetic acid, propanoic acid, hydrogen peroxide, methane sulfonic acid, and sulfuric acid. Crop residue fires emitted more organic acids and ammonia than deforestation fires, but the emissions from the main fire types were otherwise fairly similar. The Yucatan fires emitted unusually amounts of SO2 and particle chloride, likely due to a strong marine influence on the peninsula.

  13. Were mercury emission factors for Chinese non-ferrous metal smelters overestimated? Evidence from onsite measurements in six smelters

    International Nuclear Information System (INIS)

    Zhang Lei; Wang Shuxiao; Wu Qingru; Meng Yang; Yang Hai; Wang Fengyang; Hao Jiming

    2012-01-01

    Non-ferrous metal smelting takes up a large proportion of the anthropogenic mercury emission inventory in China. Zinc, lead and copper smelting are three leading sources. Onsite measurements of mercury emissions were conducted for six smelters. The mercury emission factors were 0.09–2.98 g Hg/t metal produced. Acid plants with the double-conversion double-absorption process had mercury removal efficiency of over 99%. In the flue gas after acid plants, 45–88% was oxidized mercury which can be easily scavenged in the flue gas scrubber. 70–97% of the mercury was removed from the flue gas to the waste water and 1–17% to the sulfuric acid product. Totally 0.3–13.5% of the mercury in the metal concentrate was emitted to the atmosphere. Therefore, acid plants in non-ferrous metal smelters have significant co-benefit on mercury removal, and the mercury emission factors from Chinese non-ferrous metal smelters were probably overestimated in previous studies. - Highlights: ► Acid plants in smelters provide significant co-benefits for mercury removal (over 99%). ► Most of the mercury in metal concentrates for smelting ended up in waste water. ► Previously published emission factors for Chinese metal smelters were probably overestimated. - Acid plants in smelters have high mercury removal efficiency, and thus mercury emission factors for Chinese non-ferrous metal smelters were probably overestimated.

  14. Emission of gaseous organic pollutants and flue gas treatment technology

    International Nuclear Information System (INIS)

    Chmielewski, A.G.; Sun, Y.

    2007-01-01

    Gaseous organic pollutants are emitted into atmosphere from various sources, creating a threat to the environment and man. New, economical technologies are needed for flue gas treatment. Emission sources of pollutants are reviewed and different treatment technologies are discussed in this report. (authors)

  15. Assessment of Methane Emissions from Oil and Gas Production Pads using Mobile Measurements

    Science.gov (United States)

    Journal Article Abstract --- "A mobile source inspection approach called OTM 33A was used to quantify short-term methane emission rates from 218 oil and gas production pads in Texas, Colorado, and Wyoming from 2010 to 2013. The emission rates were log-normally distributed with ...

  16. Greenhouse gas emissions and management practices that impact them in US rice systems

    Science.gov (United States)

    Previous reviews have quantified factors affecting greenhouse gas (GHG) emissions from Asian rice (Oryza sativa L.) systems, but not from rice systems typical for the United States, which often vary considerably particularly in practices (i.e., water and carbon management) that affect emissions. Usi...

  17. Intelligent Bioreactor Management Information System (IBM-IS) for Mitigation of Greenhouse Gas Emissions

    Energy Technology Data Exchange (ETDEWEB)

    Paul Imhoff; Ramin Yazdani; Don Augenstein; Harold Bentley; Pei Chiu

    2010-04-30

    Methane is an important contributor to global warming with a total climate forcing estimated to be close to 20% that of carbon dioxide (CO2) over the past two decades. The largest anthropogenic source of methane in the US is 'conventional' landfills, which account for over 30% of anthropogenic emissions. While controlling greenhouse gas emissions must necessarily focus on large CO2 sources, attention to reducing CH4 emissions from landfills can result in significant reductions in greenhouse gas emissions at low cost. For example, the use of 'controlled' or bioreactor landfilling has been estimated to reduce annual US greenhouse emissions by about 15-30 million tons of CO2 carbon (equivalent) at costs between $3-13/ton carbon. In this project we developed or advanced new management approaches, landfill designs, and landfill operating procedures for bioreactor landfills. These advances are needed to address lingering concerns about bioreactor landfills (e.g., efficient collection of increased CH4 generation) in the waste management industry, concerns that hamper bioreactor implementation and the consequent reductions in CH4 emissions. Collectively, the advances described in this report should result in better control of bioreactor landfills and reductions in CH4 emissions. Several advances are important components of an Intelligent Bioreactor Management Information System (IBM-IS).

  18. Effect of Formic Acid on In Vitro Ruminal Fermentation and Methane Emission

    Directory of Open Access Journals (Sweden)

    Kanber Kara

    2015-10-01

    Full Text Available In this study, it was aimed to investigate the effects of formic acid on the in vitro methane production and in vitro ruminal fermentation of alfalfa hay. Effect of 0.0 (control group: YF0, 0.1, 0.2, 0.3, 0.4 and 0.5 ml/L (experimental groups: YF1, YF2, YF3, YF4, and YF5 respectively formic acid (Amasil85-liquid addition to rumen fluid on ruminal fermentation parameters of alfalfa hay were determined by using in vitro gas production techniques. Methane production of in vitro incubation increased (to about 20% with addition of linearly increased formic acid. Linearly increased levels of formic acid addition to rumen fluid has significantly changed the production of in vitro total gas production, metabolic energy (ME and organic matter digestibility (OMD at linear, quadratic and cubic. The addition of 0.1 ml/L and 0.2 ml/L formic acid to rumen fluid significantly decreased in vitro total gas production, ME and OMD however addition of 0.3 ml/L and 0.4 ml/L formic acid was not changed in vitro gas production, ME and OMD levels and 0.5 ml/L formic acid was significantly increased all these parameters. Ruminal pH was not changed by addition of formic acid. Formic acid is a safe feed additive because of its properties antibacterial and flavorings and also is used as a fermentation promoter in silage. In this study it has been observed that all doses of formic acid increased in vitro enteric methane production and low doses decreased in vitro total gas production, ME and OMD and high doses have increased all these parameters. High doses have a positive effect on ME and OMD; however formic acid should be used at limited levels in diets due to the negative effect of increasing greenhouse gases. The effect of formic acid addition to the feed raw matter and rations of all livestock would be beneficial to investigate in terms of digestive system parameters and global warming, further in vitro and in vivo studies.

  19. Greenhouse gas emissions from municipal wastewater treatment plants

    Science.gov (United States)

    Parravicini, Vanessa; Svardal, Karl

    2016-04-01

    by a person in Germany or Austria (10.6 t CO2e/p/a, UBA, 2016). The results indicate that GHG emissions from WWTP have at global scale a small impact, as also highlighted by the Austrian national inventory report (NIR, 2015), where the estimated CO2e emissions from WWTPs account for only 0.23% of the total CO2e emission in Austria. References IPCC (2006). Intergovernmental Panel on Climate Change, Guidelines for National Greenhouse Gas Inventories, Prepared by the National Greenhouse Gas Inventories Program, Eggleston H.S., Buendia L., Miwa K., Ngara T. and Anabe K. (eds). Published: IGES, Japan. http://www.ipcc-nggip.iges.or.jp/public/2006gl/. NIR (2015). Austria's National Inventory Report 2015. Submission under the United Nations Framework Convention on Climate Change and under the Kyoto Protocol. Reports, Band 0552, ISBN: 978-3-99004-364-6, Umweltbundesamt, Wien. Parravicini V., Valkova T., Haslinger J., Saracevic E., Winkelbauer A., Tauber J., Svardal K., Hohenblum P., Clara M., Windhofer G., Pazdernik K., Lampert C. (2015). Reduktionspotential bei den Lachgasemissionen aus Kläranlagen durch Optimierung des Betriebes (ReLaKO). The research project was financially supported by the Ministry for agriculture, forestry, Environment and Water Management. Project leader: TU Wien, Institute for Water Quality, Ressources and Waste Management; Project partner: Umweltbundesamt GmbH. Final report: http://www.bmlfuw.gv.at/service/publikationen/wasser/Lachgasemissionen---Kl-ranlagen.html. UBA (2016). German average carbon footprint. Umweltbundesamt, Januar 2016, http://uba.klimaktiv-co2-rechner.de/de_DE/page/footprint/

  20. Uncovering China’s greenhouse gas emission from regional and sectoral perspectives

    International Nuclear Information System (INIS)

    Liu, Zhu; Geng, Yong; Lindner, Soeren; Guan, Dabo

    2012-01-01

    Understanding China’s GHG (greenhouse gas) emission status is critical for achieving the national mitigation plan. While much attention has addressed China’s national level GHG emission, less is known about its regional and sectoral emission features. In this paper China’s regional and sectoral GHG emission patterns and their driving forces were explored by using upgraded energy consumption data. We constructed a detailed GHG inventory for each province in the year 2009 which covering 28 sectors and further expanded time-serious inventories during 1997–2009. We then conducted variation and index decomposition analysis to explore its sectoral/regional disparity and features. Results showed significant differences of sectoral emission intensity among different provinces, implying a huge disparity of technology level. Since less developed provinces still apply energy intensive technologies, they had contributed to most of national emission increment during 1997–2009 and made the whole country towards carbon intensive direction. Our research outcomes indicate that the inequity of technology level among regions has already become a main barrier for China’s CO 2 mitigation. Such a reality deserves more attention from both researchers and policy makers so that appropriate carbon reduction policies can be raised. -- Highlights: ► We present spacial and sectoral disparity and drivers on green house gas (GHG) emission in 30 Chinese provinces. ► We indicated a huge difference of technology level among regions. ► Different industrial structure and development stage further result in GHG intensive in China's poor regions. ► Inequity of technology level among regions has already become a main barrier for China's GHG mitigation.