Preliminary investigation Area 12 fleet operations steam cleaning discharge area Nevada Test Site

International Nuclear Information System (INIS)

1996-07-01

This report documents the characterization activities and findings of a former steam cleaning discharge area at the Nevada Test Site. The former steam cleaning site is located in Area 12 east of Fleet Operations Building 12-16. The characterization project was completed as a required condition of the ''Temporary Water Pollution Control Permit for the Discharge From Fleet Operations Steam Cleaning Facility'' issued by the Nevada Division of Environmental Protection. The project objective was to collect shallow soil samples in eight locations in the former surface discharge area. Based upon field observations, twelve locations were sampled on September 6, 1995 to better define the area of potential impact. Samples were collected from the surface to a depth of approximately 0.3 meters (one foot) below land surface. Discoloration of the surface soil was observed in the area of the discharge pipe and in localized areas in the natural drainage channel. The discoloration appeared to be consistent with the topographically low areas of the site. Hydrocarbon odors were noted in the areas of discoloration only. Samples collected were analyzed for bulk asbestos, Toxicity Characteristic Leaching Procedure (TCLP) metals, total petroleum hydrocarbons (TPHs), volatile organic compounds (VOCs), semi-volatile organic compounds (Semi-VOCs), and gamma scan

Observations of changes in residual gas and surface composition with discharge cleaning in PLT

International Nuclear Information System (INIS)

Dylla, H.F.; Bol, K.; Cohen, S.A.; Hawryluk, R.J.; Meservey, E.B.; Rossnagel, S.M.

1978-10-01

Hydrogen discharge cleaning of the PLT vacuum vessel has been studied by mass spectroscopy of desorbed gases and surface analysis of exposed samples. Several modes of vessel conditioning have been studied to date: (1) a high power discharge cleaning (PDC) mode, with a peak power density to the vessel wall P/sub s/ approximately 0.6 w/cm 2 and a peak electron temperature T/sub e/ approximately 100 ev; (2) low power (Taylor-type) discharge cleaning (TDC) with P/sub s/ approximately 0.05 w/cm 2 and T/sub e/ equal to or less than 5 eV. The predominant residual gases produced during PDC are CH 4 (1-5 x 10 -6 torr) and CO (1-10 x 10 -7 torr), whereas TDC produced primarily H 2 O (1-2 x 10 -6 torr) and CH 4 (1-10 x 10 -7 torr). In situ surface analysis of hydrocarbon-covered stainless steel has shown significant decreases in carbon coverage occurring after 10 3 -10 4 pulses of either cleaning mode. Observed changes in oxygen coverage are more difficult to interpret because of the presence of the nascent oxide layer on the stainless steel substrates

Effects of discharge cleaning on the production of runaway electrons in TORTUS tokamak

Energy Technology Data Exchange (ETDEWEB)

Cross, R C; Liu, J R; Giannone, L. (Sydney Univ. (Australia). School of Physics)

1983-06-01

Experimental results are presented on the production of runaway electrons as a function of wall cleanliness in the TORTUS tokamak. When the walls are clean, the production rate decreases as the filling pressure increases. When the walls are contaminated by oxygen, the production rate can increase when the filling pressure is increased, owing to the production of water vapour during tokamak discharges. These results resolve the differences reported in the literature on the production of runaways as a function of filling pressure. It is also observed that the runaway electron instability seen in other devices is suppressed when the walls are discharge-cleaned.

The study of discharge cleaning in the JFT-2 tokamak with surface observation by AES

International Nuclear Information System (INIS)

Gomay, Yoshio; Tazima, Teruhiko; Fujisawa, Noboru; Suzuki, Norio; Konoshima, Shigeru

1976-07-01

Noticeable correlations were observed between the changes of discharge characteristics, wall conditions and typical mass peaks with discharge cleaning in the JFT-2 tokamak. Atomic composition of the vacuum wall surface observed by AES becomes constant with continuing discharge cleaning in the level except hydrogen and helium: 30-50% C, 20-30% Mo, 15-30% stainless steel elements and 10-15% O. The stable reproducible plasma with Z sub(eff)=4.5 was obtained in this wall condition. The limiter and vacuum wall materials (Mo and 304 stainless steel, respectively), carbon and oxygen were observed depositing on the wall in the thickness of about 300 A at the minimum inner radius of the vacuum chamber and 40 A nearly at the maximum after 2900 cleaning pulses. The mechanism determining the wall condition is also discussed. (auth.)

Cleaning method of aluminium surface by argon discharge for photon factory

International Nuclear Information System (INIS)

Mizuno, Hajime; Yamaguchi, Hiroshi; Watabe, Hiromi; Horikoshi, Gen-ichi; Mathewson, A.G.

1978-01-01

In the Photon Factory program of High Energy Research Laboratory, in which the electron storage ring as a photon source stores the electron beam of 2.5 GeV and 500 mA, beam intensity the probability of gas discharge from the inner surface of doughnut wall due to electron bombardment (for 100 eV electorns) must be limited to 1 x 10 -6 or less, according to the estimation by A.G. Mathewson and others. The pressure inside the ring can be maintained at 1 x 10 -9 Torr only with the above probability value. The standard surface treatment of degreasing and evacuation for 24 hours with heating at 150 deg. C can be of no practical use. Since the ion bombardment of surfaces by argon glow discharge is effective for decreasing the probability, the reduction of the probability by argon discharge cleaning was measured with the surface of aluminium, which is planned to be used as the doughnut material. Two methods were employed for the measurement; the one is analysis of gases being discharged, by introducting them to the analyzing chamber during argon discharge and the other is the measurement of the probability when bombardment with electrons of 100 eV is applied, after stopping argon introduction and evacuating after argon discharge had been performed for a definite period. As a result, the probability of approximately 2 x 10 -5 at the beginning of electron beam incidence was obtained by adding argon discharge cleaning to the standard method. This is estimated to correspondent to approximately 25 mA of beam intensity, which is equivalent to 1/20 of the planned value. (Wakatsuki, Y.)

Feasibility of arc-discharge and plasma-sputtering methods in cleaning plasma-facing and diagnostics components of fusion reactors

Energy Technology Data Exchange (ETDEWEB)

Hakola, Antti, E-mail: antti.hakola@vtt.fi [VTT Technical Research Centre of Finland, VTT (Finland); Likonen, Jari [VTT Technical Research Centre of Finland, VTT (Finland); Karhunen, Juuso; Korhonen, Juuso T. [Department of Applied Physics, Aalto University (Finland); Aints, Märt; Laan, Matti; Paris, Peeter [Department of Physics, University of Tartu (Estonia); Kolehmainen, Jukka; Koskinen, Mika; Tervakangas, Sanna [DIARC-Technology Oy, Espoo (Finland)

2015-10-15

Highlights: • Feasibility of the arc-discharge and plasma-sputtering techniques in removing deposited layers from ITER-relevant samples demonstrated. • Samples with the size of an A4 paper can be cleaned from 1-μm thick deposited layers in 10–20 minutes by the arc-discharge method. • The plasma-sputtering method is 5–10 times slower but the resulting surfaces are very smooth. • Arc-discharge method could be used for rapid cleaning of plasma-facing components during maintenance shutdowns of ITER, plasma sputtering is preferred for diagnostics mirrors. - Abstract: We have studied the feasibility of arc-discharge and plasma-sputtering methods in removing deposited layers from ITER-relevant test samples. Prototype devices have been designed and constructed for the experiments and the cleaning process is monitored by a spectral detection system. The present version of the arc-discharge device is capable of removing 1-μm thick layers from 350-mm{sup 2} areas in 4–8 s, but due to the increased roughness of the cleaned surfaces and signs of local melting, mirror-like surfaces cannot be treated by this technique. The plasma-sputtering approach, for its part, is some 5–10 times slower in removing the deposited layers but no changes in surface roughness or morphology of the samples could be observed after the cleaning phase. The arc-discharge technique could therefore be used for rapid cleaning of plasma-facing components during maintenance shutdowns of ITER while in the case of diagnostics mirrors plasma sputtering is preferred.

Effects of discharge cleaning on the production of runaway electrons in TORTUS tokamak

International Nuclear Information System (INIS)

Cross, R.C.; Liu, J.R.; Giannone, L.

1983-01-01

Experimental results are presented on the production of runaway electrons as a function of wall cleanliness in the TORTUS tokamak. When the walls are clean, the production rate decreases as the filling pressure increases. When the walls are contaminated by oxygen, the production rate can increase when the filling pressure is increased, owing to the production of water vapour during tokamak discharges. These results resolve the differences reported in the literature on the production of runaways as a function of filling pressure. It is also observed that the runaway electron instability seen in other devices is suppressed when the walls are discharge-cleaned. (author)

Waste cleaning using CO2-acid microemulsion

International Nuclear Information System (INIS)

Park, Kwangheon; Sung, Jinhyun; Koh, Moonsung; Ju, Minsu

2011-01-01

Frequently we need to decontaminate radioactive wastes for volume reduction purposes. Metallic contaminants in wastes can be removed by dissolution to acid; however, this process produces a large amount of liquid acid waste. To reduce this 2ndary liquid waste, we suggest CO 2 -acid emulsion in removing metallic contaminants. Micro- and macro-emulsion of acid in liquid/supercritical CO 2 were successfully made. The formation region of microemulsion (water or acid in CO 2 ) was measured, and stability of the microemulsion was analyzed with respect to surfactant types. We applied micro- and macro-emulsion containing acid to the decontamination of radioactive metallic parts contaminated on the surface. The cleaning methods of micro- and macro-emulsion seemed better compared to the conventional acid cleaning. Moreover, these methods produce very small amount of secondary wastes. (author)

Cleaning of niobium surface by plasma of diffuse discharge at atmospheric pressure

Science.gov (United States)

Tarasenko, V. F.; Erofeev, M. V.; Shulepov, M. A.; Ripenko, V. S.

2017-07-01

Elements composition of niobium surface before and after plasma treatment by runaway electron preionized diffuse discharge was investigated in atmospheric pressure nitrogen flow by means of an Auger electron spectroscopy. Surface characterizations obtained from Auger spectra show that plasma treatment by diffuse discharge after exposure of 120000 pulses provides ultrafine surface cleaning from carbon contamination. Moreover, the surface free energy of the treated specimens increased up to 3 times, that improve its adhesion property.

Is peracetic acid suitable for the cleaning step of reprocessing flexible endoscopes?

Science.gov (United States)

Kampf, Günter; Fliss, Patricia M; Martiny, Heike

2014-09-16

The bioburden (blood, protein, pathogens and biofilm) on flexible endoscopes after use is often high and its removal is essential to allow effective disinfection, especially in the case of peracetic acid-based disinfectants, which are easily inactivated by organic material. Cleaning processes using conventional cleaners remove a variable but often sufficient amount of the bioburden. Some formulations based on peracetic acid are recommended by manufacturers for the cleaning step. We performed a systematic literature search and reviewed the available evidence to clarify the suitability of peracetic acid-based formulations for cleaning flexible endoscopes. A total of 243 studies were evaluated. No studies have yet demonstrated that peracetic acid-based cleaners are as effective as conventional cleaners. Some peracetic acid-based formulations have demonstrated some biofilm-cleaning effects and no biofilm-fixation potential, while others have a limited cleaning effect and a clear biofilm-fixation potential. All published data demonstrated a limited blood cleaning effect and a substantial blood and nerve tissue fixation potential of peracetic acid. No evidence-based guidelines on reprocessing flexible endoscopes currently recommend using cleaners containing peracetic acid, but some guidelines clearly recommend not using them because of their fixation potential. Evidence from some outbreaks, especially those involving highly multidrug-resistant gram-negative pathogens, indicated that disinfection using peracetic acid may be insufficient if the preceding cleaning step is not performed adequately. Based on this review we conclude that peracetic acid-based formulations should not be used for cleaning flexible endoscopes.

Letter from A & R Transport about Section 308 of the Clean Water Act Discharge of Perfluorinated Compounds

Science.gov (United States)

January 16, 2009 letter from Kenneth E. Pate, VP of Safety and Risk Management of A & R Transport, Inc. to EPA Clean Water Enforcement Branch, about an Information Request about the Section 308 of the Clean Water Act, discharge of pefluorinated compounds.

Revisions to the Clean Water Act Regulatory Definition of Discharge of Dredged Material; Final Rule

Science.gov (United States)

The U.S. Army Corps of Engineers (Corps) and the Environmental Protection Agency (EPA) promulgated a final rule Amending a Clean Water Act (CWA) section 404 regulation that defines the term discharge of dredged material.

Tank 12H Acidic Chemical Cleaning Sample Analysis And Material Balance

International Nuclear Information System (INIS)

Martino, C. J.; Reboul, S. H.; Wiersma, B. J.; Coleman, C. J.

2013-01-01

A process of Bulk Oxalic Acid (BOA) chemical cleaning was performed for Tank 12H during June and July of 2013 to remove all or a portion of the approximately 4400 gallon sludge heel. Three strikes of oxalic acid (nominally 4 wt % or 2 wt %) were used at 55 deg C and tank volumes of 96- to 140-thousand gallons. This report details the sample analysis of a scrape sample taken prior to BOA cleaning and dip samples taken during BOA cleaning. It also documents a rudimentary material balance for the Tank 12H cleaning results

Experimental Study on Indoor Air Cleaning Technique of Nano-Titania Catalysis Under Plasma Discharge

International Nuclear Information System (INIS)

Gao Deli; Yang Xuechang; Zhou Fei; Wu Yuhuang

2008-01-01

In this study, a new technique of air cleaning by plasma combined with catalyst was proposed, which consisted of electrostatic precipitation, volatile organic compounds (VOCs) decomposition and sterilization. A novel indoor air purifier based on this technique was adopted. The experimental results showed that formaldehyde decomposition by the plasma-catalyst hybrid system was more efficient than that by plasma only. Positive discharge was better than negative discharge in formaldehyde removal. Meanwhile, the outlet concentration of ozone byproduct was effectively reduced by the nano-titania catalyst.

Comparison of trace metals in intake and discharge waters of power plants using clean techniques

International Nuclear Information System (INIS)

Salvito, D.T.; Allen, H.E.

1995-01-01

In order to determine the impact to receiving waters of trace metals potentially discharged from a once-through, non-contact cooling water system from a power plant, a study was conducted utilizing clean sampling and analytical techniques for a series of metals. Once-through, non-contact cooling water at power plants is frequently discharged back to the fresh or saline waterbody utilized for its intake water. This water is used to cool plant condensers. Intake and discharge data were collected and evaluated using paired t-tests. Study results indicate that there is no measurable contribution of metals from non-contact cooling water from this power plant

Utilisation of CO2, fixation of nitrogen and exhaust gas cleaning in electric discharge with electrode catalysis

International Nuclear Information System (INIS)

Marcela, M.; Imrich, M.; Mario, J.

2001-01-01

The method reported here provides a contribution to CO 2 utilisation, nitrogen fixation and combustion exhaust cleaning using synergetic effect of electric discharge with heterogeneous catalysis on electrodes. The efficiency of CO 2 removal is about 40-65%. The process of CO 2 removal is always accompanied by NO x , VOC, SX and other component removal and is connected with O 2 formation. The final product of process is powder with fractal microstructure, low specific weight, water insoluble suitable for use as nitrogen containing fertilizer. The main component (95%) of solid product is amorphous condensate of amino acids with about 5% of metal organic compound with catalytic properties. The condensate has character of statistical proteinoid. Its creation seems to play important role during formation of life in pre-biotic Earth

Deuteration of metals through electric discharges

International Nuclear Information System (INIS)

Balderas G, L.M.

1995-01-01

In this work deuteration of titanium and a stainless steel through electrical discharges in a vacuum chamber was performed at different thermodynamic conditions. The samples were plates of 0.03 x 4.5 x 54 cm. The titanium sample was first cleaning with chloroform. The oxide layer was removed by cleaning the sample with a 1:1:1 mixture of water, nitric acid and sulphuric acid. Later was rinsed in water and dried with acetone. Finally, was treated with HCl to form an hydride layer on the surface. The stainless steel sample was only cleaned with soap and cleaning with acetone. The samples were cleaning at low pressure for several days with high temperature short cycles. The deuterium was loaded to the chamber at room temperature having absorption on the titanium samples at 10 3 at 10 1 mbar. Afterwards that the samples were heated up at 330 C and was observed the deuterium absorption in the same pressure range. Forced deuteration through electrical discharges between the sample and the chamber was tried obtaining absorption in the range of 10 3 at 10 2 mbar, however the deuterium absorption only was observed in specific cases. In order to detect neutron emission or released particles in this experiment were used alanine detectors and series of plastic CR-39 and borate films. No neutron were detected in the passive systems used in the experiments. (Author)

Effectiveness acidic pre-cleaning for copper-gold ore

Directory of Open Access Journals (Sweden)

Antonio Clareti Pereira

Full Text Available Abstract The presence of copper-bearing minerals is known to bring on many challenges during the cyanidation of gold ore, like high consumption of cyanide and low extraction of metal, which are undesirable impacts on the auriferous recovery in the subsequent process step. The high copper solubility in cyanide prevents the direct use of classical hydrometallurgical processes for the extraction of gold by cyanidation. Additionally, the application of a conventional flotation process to extract copper is further complicated when it is oxidized. As a result, an acid pre-leaching process was applied in order to clean the ore of these copper minerals that are cyanide consumers. The objective was to evaluate the amount of soluble copper in cyanide before and after acidic cleaning. From a gold ore containing copper, the study selected four samples containing 0.22%, 0.55%, 1.00% and 1.36% of copper. For direct cyanidation of the ore without pre-treatment, copper extraction by cyanide complexing ranged from 8 to 83%. In contrast, the pre-treatment carried out with sulfuric acid extracted 24% to 99% of initial copper and subsequent cyanidation extracted 0.13 to 1.54% of initial copper. The study also showed that the copper contained in the secondary minerals is more easily extracted by cyanide (83%, being followed by the copper oxy-hydroxide minerals (60%, while the copper contained in the manganese oxide is less complexed by cyanide (8% a 12%. It was possible to observe that minerals with low acid solubility also have low solubility in cyanide. Cyanide consumption decreased by about 2.5 times and gold recovery increased to above 94% after acidic pre-cleaning.

Cleaning and conditioning of the walls of plasma devices by glow discharges in hydrogen

International Nuclear Information System (INIS)

Waelbroeck, F.; Winter, J.; Ali-Khan, I.; Wienhold, P.; Dietz, K.J.

1980-12-01

The influence of a number of parameters on the cleaning and preconditioning efficiency of a combined rf and glow (RG) discharge is studied experimentally. The emphasis is laid on problems of oxygen removal from the surface. The important parameters are the wall temperature Tsub(W), the pump speed SP, the current Isub(G)D of the glow discharge and the hydrogen pressure P 2 . In a device with a ratio SP/S = 0,1 ms -1 (S: inner area), a rapid deoxidation is achieved when T-W >= 200 0 C. At room temperature, the oxide layer is reduced from a (carbon-free) surface when 1 to 2% of methane is added to the hydrogen: carbon monoxide is formed and evacuated. Admixture of other gases such as He, Ne do not increase the cleaning efficiency. An equation derived from a simplified model describes semi-quantitatively the observed parametric dependances. The tendency for arc spots to occur during the initial phases of the discharge depends on the preconditioning of the wall: a prolonged bake-out at 200 0 C leads to the non-appearance of arcs in all cases examined. Problems arise when a quadrupole residual gas analyser is used to measure the partial pressure of water in hydrogen. These are analysed and a conditioning technique is described which has proven to be appropriate in our measurements. (orig.)

The experience with JET's combined dc/Rf glow discharge cleaning (GDC) system

International Nuclear Information System (INIS)

Pearce, R.J.H.; Andrew, P.; Bryan, S.

1996-01-01

The JET Tokamak was fitted with four new electrodes of novel design, each powered from individual computer controlled dc and RF supplies. Details of enhancements and problems from 15 months experience with the system are outlined. Experiments were performed to assess the effect of RF on the glow discharge characteristics, and to establish stable glow at low pressure and high voltage. JET combined RF/dc glow discharge cleaning (GDC) had no significant advantages over pure dc GDC, provided highly stable dc current control was obtained. In fact, the mechanically weak electrode inductor spiral required to allow RF posed a distinct disadvantage. The electrodes were converted to simple plates, following damage caused by halo currents during Tokamak plasma disruptions. The performance of these electrodes was assessed. Future developments in the JET GDC system are outlined. (Author)

Acid leaching of coal: to produce clean fuels from Turkish lignite

Energy Technology Data Exchange (ETDEWEB)

Seferinoglu, Meryem [Mineral Research and Exploration Directorate (Turkey)], email: meryem_seferinoglu66@yahoo.com; Duzenli, Derya [Ankara Central Laboratory (Turkey)

2011-07-01

With the increasing concerns about the environment, energy producers and governments are looking at developing clean energy sources. However, Turkey has limited clean energy resources and is using low grade coal which has high sulphur content as an alternative energy source. The aim of this paper is to study the possibility of generating clean fuel from Edirne Lignite and to get a better understanding of chemical mechanisms involved in coal leaching with hydrofluoric acid (HF) solutions. Leaching was conducted on Edirne Lignite with HF solution at ambient temperature and the effects of parameters such as reaction time and concentration of acid solutions on the process were evaluated. The optimum conditions were found and it was shown that ash levels can be reduced from 28.9% to 10.5% and the calorific value increased by 500kcal/kg with the HF leaching method. This study demonstrated that the production of clean fuel from high sulphur lignite is possible.

Is peracetic acid suitable for the cleaning step of reprocessing flexible endoscopes?

OpenAIRE

Kampf, Günter; Fliss, Patricia M; Martiny, Heike

2014-01-01

The bioburden (blood, protein, pathogens and biofilm) on flexible endoscopes after use is often high and its removal is essential to allow effective disinfection, especially in the case of peracetic acid-based disinfectants, which are easily inactivated by organic material. Cleaning processes using conventional cleaners remove a variable but often sufficient amount of the bioburden. Some formulations based on peracetic acid are recommended by manufacturers for the cleaning step. We performed ...

Elimination of inter-discharge helium glow discharge cleaning with lithium evaporation in NSTX

Directory of Open Access Journals (Sweden)

R. Maingi

2017-08-01

Full Text Available Operation in the National Spherical Torus Experiment (NSTX typically used either periodic boronization and inter-shot helium glow discharge cleaning (HeGDC, or inter-shot lithium evaporation without boronization, and initially with inter-shot HeGDC. To assess the viability of operation without HeGDC, dedicated experiments were conducted in which Li evaporation was used while systematically shrinking the HeGDC between shots from the standard 10min to zero (10→6.5→4→0. Good shot reproducibility without HeGDC was achieved with lithium evaporations of 100mg or higher; evaporations of 200–300mg typically resulted in very low ELM frequency or ELM-free operation, reduced wall fueling, and improved energy confinement. The use of HeGDC before lithium evaporation modestly reduced Dα in the outer scrape-off layer, but not at the strike point. Pedestal electron and ion temperature also improved modestly, suggesting that HeGDC prior to lithium evaporation is a useful tool for experiments that seek to maximize plasma performance.

Characterization of the Tokamak Novillo in cleaning regime

International Nuclear Information System (INIS)

Lopez C, R.; Melendez L, L.; Valencia A, R.; Chavez A, E.; Colunga S, S.; Gaytan G, E.

1992-02-01

In this work the obtained results of the investigation about the experimental characterization of those low energy pulsed discharges of the Tokamak Novillo are reported. With this it is possible to fix the one operation point but appropriate of the Tokamak to condition the chamber in the smallest possible time for the cleaning discharges regime before beginning the main discharge. The characterization of the cleaning discharges in those Tokamaks is an unique process and characteristic of each device, since the good points of operation are consequence of those particularities of the design of the machine. In the case of the Tokamak Novillo, besides characterizing it a contribution is made to the cleaning discharges regime which consists on the one product of the current peak to peak of plasma by the duration of the discharge Ip t like reference parameter for the optimization of the operation of the device in the cleaning discharge regime. The maximum value of the parameter I (p) t, under different work conditions, allowed to find the good operation point to condition the discharges chamber of the Tokamak Novillo in short time and to arrive to a regime in which is not necessary the preionization for the obtaining of the cleaning discharges. (Author)

Atmospheric plasma generation for LCD panel cleaning

Science.gov (United States)

Kim, Gyu-Sik; Won, Chung-Yuen; Choi, Ju-Yeop; Yim, C. H.

2007-12-01

UV lamp systems have been used for cleaning of display panels of TFT LCD or Plasma Display Panel (PDP). However, the needs for high efficient cleaning and low cost made high voltage plasma cleaning techniques to be developed and to be improved. Dielectric-barrier discharges (DBDs), also referred to as barrier discharges or silent discharges have for a long time been exclusively related to ozone generation. In this paper, a 6kW high voltage plasma power supply system was developed for LCD cleaning. The -phase input voltage is rectified and then inverter system is used to make a high frequency pulse train, which is rectified after passing through a high-power transformer. Finally, bi-directional high voltage pulse switching circuits are used to generate the high voltage plasma. Some experimental results showed the usefulness of atmospheric plasma for LCD panel cleaning.

Determination of fusaric acid in maize using molecularly imprinted SPE clean-up

Science.gov (United States)

A new liquid chromatography method to detect fusaric acid in maize is reported based on molecularly imprinted polymer solid phase extraction clean-up (MISPE) using mimic-templated molecularly-imprinted polymers. Picolinic acid was used as a toxin analog for imprinting polymers during a thermolytic s...

An intense lithium ion beam source using vacuum baking and discharge cleaning techniques

International Nuclear Information System (INIS)

Moschella, J.J.; Kusse, B.R.; Longfellow, J.P.; Olson, J.C.

1991-01-01

We have developed a high-purity, intense, lithium ion beam source which operates at 500 kV and 120 A/cm 2 with pulse widths of 125 ns full width half maximum. The beams were generated using a lithium chloride anode in planar magnetically insulated geometry. We have found that the combination of vacuum baking of the anode at 250 degree C followed by the application of 100 W of pure argon, steady-state, glow discharge cleaning reduced the impurity concentration in the beam to approximately 10% (components other than chlorine or lithium were considered impurities). Although the impurities were low, the concentration of chlorine in the 1+ and 2+ charge states was significant (∼25%). The remaining 65% of the beam consisted of Li + ions. Without the special cleaning process, over half the beam particles were impurities. It was determined that these impurities entered the beam at the anode surface but came originally from material in the vacuum chamber. After the cleaning process, recontamination was observed to occur in approximately 6 min. This long recontamination time, which was much greater than the expected monolayer formation time, was attributed to the elevated temperature of the anode. We also compared the electrical characteristics of the beams produced by LiCl anodes to those generated by a standard polyethylene proton source. In contrast to the polyethylene anode, the LiCl source exhibited a higher impedance, produced beams of lower ion current efficiency and had longer turn on times

Deuteration of metals through electric discharges; Deuteracion de metales bajo descargas electricas

Energy Technology Data Exchange (ETDEWEB)

Balderas G, L M

1996-12-31

In this work deuteration of titanium and a stainless steel through electrical discharges in a vacuum chamber was performed at different thermodynamic conditions. The samples were plates of 0.03 x 4.5 x 54 cm. The titanium sample was first cleaning with chloroform. The oxide layer was removed by cleaning the sample with a 1:1:1 mixture of water, nitric acid and sulphuric acid. Later was rinsed in water and dried with acetone. Finally, was treated with HCl to form an hydride layer on the surface. The stainless steel sample was only cleaned with soap and cleaning with acetone. The samples were cleaning at low pressure for several days with high temperature short cycles. The deuterium was loaded to the chamber at room temperature having absorption on the titanium samples at 10{sup 3} at 10{sup 1} mbar. Afterwards that the samples were heated up at 330 C and was observed the deuterium absorption in the same pressure range. Forced deuteration through electrical discharges between the sample and the chamber was tried obtaining absorption in the range of 10{sup 3} at 10{sup 2} mbar, however the deuterium absorption only was observed in specific cases. In order to detect neutron emission or released particles in this experiment were used alanine detectors and series of plastic CR-39 and borate films. No neutron were detected in the passive systems used in the experiments. (Author).

Impact of Acid Cleaning on the Performance of PVDF UF Membranes in Seawater Reverse Osmosis Pretreatment

KAUST Repository

Alsogair, Safiya

2016-05-05

Low-pressure membrane systems such as Microfiltration (MF) and Ultrafiltration (UF) have been presented as viable option to pre-treatment systems in potable water applications. UF membranes are sporadically backwashed with ultra-filtered water to remove deposited matter from the membrane and restore it. Several factors that may cause permeability and selectivity decrease are involved and numerous procedures are applicable to achieve this objective. Membrane cleaning is the most important step required to maintain the characteristics of the membrane. This research was made with the purpose of investigating the effects of acid cleaning during chemically enhanced backwashing (CEB) on the performance of ultrafiltration (UF) membranes in seawater reverse osmosis (SWRO) pretreatment. To accomplish this, the questions made were: Does the acid addition (before or after the alkali CEB) influence the overall CEB cleaning effectiveness on Dow UF membrane? Does the CEB order of alkali (NaOCl) and acid (H2SO4) affect the overall CEB cleaning effectiveness? If yes, which order is better/worse? What is the optimal acid CEB frequency that will ensure the most reliable performance of the UF?. To answer this queries, a series of sequences were carried out with different types of chemical treatments: Only NaOCl, daily NaOCl plus weekly acid, daily NaOCl plus daily acid, and weekly acid plus daily NaOCl. To investigate the consequence of acid by studying the effect of operational data like the trans-pressure membrane, resistance or permeability and support that by the analytical experiments (organic, inorganic and microbial characterization). Microorganisms were removed almost completely at hydraulic cleaning and showed no difference with addition of acid. As a conclusion of the operational data the organic and inorganic chatacterization resulted in the elimination of the first sequence due to the acummulation of fouling over time, which produces that the cleaning increases downtime

Vessel Sewage Discharges

Science.gov (United States)

Vessel sewage discharges are regulated under Section 312 of the Clean Water Act, which is jointly implemented by the EPA and Coast Guard. This homepage links to information on marine sanitation devices and no discharge zones.

Corrective Action Decision Document (CADD), Area 12 fleet operations steam cleaning discharge area, Nevada Test Site Corrective Action Unit 339

International Nuclear Information System (INIS)

Bonn, J.F.

1996-12-01

This Corrective Action Decision Document (CADD) incorporates the methodology used for evaluating the remedial alternatives completed for a former steam cleaning discharge area at the Nevada Test Site (NTS). The former steam cleaning site is located in Area 12, east of the Fleet Operations Building 12-16. The discharge area has been impacted by Resource Conservation and Recovery Act (RCRA) F Listed volatile organic compounds (VOCs) and petroleum hydrocarbons waste. Based upon these findings, resulting from Phase 1 and Phase 2 site investigations, corrective action is required at the site. To determine the appropriate corrective action to be proposed, an evaluation of remedial alternatives was completed. The evaluation was completed using a Corrective Measures Study (CMS). Based on the results of the CMS, the favored closure alternative for the site is plugging the effluent discharge line, removing the sandbagged barrier, completing excavation of VOC impacted soils, and fencing the soil area impacted by total petroleum hydrocarbons (TPH), east of the discharge line and west of the soil berm. Management of the F Listed VOCs are dictated by RCRA. Due to the small volume of impacted soil, excavation and transportation to a Treatment Storage and Disposal Facility (TSDF) is the most practical method of management. It is anticipated that the TPH (as oil) impacted soils will remain in place based upon; the A through K Analysis, concentrations detected (maximum 8,600 milligrams per kilogram), expected natural degradation of the hydrocarbons over time, and the findings of the Phase 2 Investigation that vertical migration has been minimal

Corrective Action Decision Document (CADD), Area 12 fleet operations steam cleaning discharge area, Nevada Test Site Corrective Action Unit 339

Energy Technology Data Exchange (ETDEWEB)

Bonn, J.F.

1996-12-01

This Corrective Action Decision Document (CADD) incorporates the methodology used for evaluating the remedial alternatives completed for a former steam cleaning discharge area at the Nevada Test Site (NTS). The former steam cleaning site is located in Area 12, east of the Fleet Operations Building 12-16. The discharge area has been impacted by Resource Conservation and Recovery Act (RCRA) F Listed volatile organic compounds (VOCs) and petroleum hydrocarbons waste. Based upon these findings, resulting from Phase 1 and Phase 2 site investigations, corrective action is required at the site. To determine the appropriate corrective action to be proposed, an evaluation of remedial alternatives was completed. The evaluation was completed using a Corrective Measures Study (CMS). Based on the results of the CMS, the favored closure alternative for the site is plugging the effluent discharge line, removing the sandbagged barrier, completing excavation of VOC impacted soils, and fencing the soil area impacted by total petroleum hydrocarbons (TPH), east of the discharge line and west of the soil berm. Management of the F Listed VOCs are dictated by RCRA. Due to the small volume of impacted soil, excavation and transportation to a Treatment Storage and Disposal Facility (TSDF) is the most practical method of management. It is anticipated that the TPH (as oil) impacted soils will remain in place based upon; the A through K Analysis, concentrations detected (maximum 8,600 milligrams per kilogram), expected natural degradation of the hydrocarbons over time, and the findings of the Phase 2 Investigation that vertical migration has been minimal.

Water cleaning by pulsed corona discharges

NARCIS (Netherlands)

Grabowski, L.R.; Veldhuizen, van E.M.; Rutgers, W.R.

2004-01-01

Direct electrical energization methods for water cleaning are under investigation in the framework of the ytriD-project1. The emphasis of the first stage of the project is optimization of the reactor configuration regarding the energy efficiency. A comparison is made between a batch reactor and an

Closure report for CAU 339: Area 12 Fleet Operations steam-cleaning discharge area, Nevada Test Site

International Nuclear Information System (INIS)

1997-12-01

This Closure Report (CR) provides documentation of the completed corrective action at the Area 12 Fleet Operations site located in the southeast portion of the Area 12 Camp at the Nevada Test Site (NTS). Field work was performed in July 1997 as outlined in the Corrective Action Plan (CAP). The CAP was approved by the Nevada Division of Environmental Protection (NDEP) in June 1997. This site is identified in the Federal Facility Agreement and Consent Order (FFACO) as Corrective Action Site (CAS) Number 12-19-01 and is the only CAS in Corrective Action Unit (CAU) 339. The former Area 12 Fleet Operations Building 12-16 functioned as a maintenance facility for light- and heavy-duty vehicles from approximately 1965 to January 1993. Services performed at the site included steam-cleaning, tire service, and preventative maintenance on vehicles and equipment. Past activities impacted the former steam-cleaning discharge area with volatile organic compounds (VOCs) and total petroleum hydrocarbons (TPH) as oil

Removal of NO2 and O3 generated from corona discharge in indoor air cleaning with MnO2 catalyst

International Nuclear Information System (INIS)

Ge, H; Yu, R; Zhu, Y M; Mi, D

2013-01-01

The production rules and removal efficiency of harmful byproducts such as NO 2 and O 3 generated from DC corona discharge in indoor air cleaning were investigated. The production behaviours of NO 2 and O 3 and the relationship between the amount of catalyst (MnO 2 ) and the removal rate of harmful byproducts were experimentally studied. Further, indoor application tests were carried out in a closed room with 90 m 3 . The results showed that the concentrations of NO 2 and O 3 produced by corona discharge linearly increased with discharge time. The NO 2 yield is larger than O 3 by almost one order of magnitude under the same discharge power. To satisfy the demand of Standard of Indoor Air Quality (GB/T18883-2002), the power consumption of unit volume should be less than 1 W m −3 and the catalyst MnO 2 consumptions in positive-negative corona discharge were 200 cm 3 W −1 and 100 cm 3 W −1 , respectively.

Environmental Compliance Guide. Guidance manual for Department of Energy compliance with the Clean Water Act: National Pollutant Discharge Elimination System (NPDES)

Energy Technology Data Exchange (ETDEWEB)

1982-07-01

This manual provides general guidance for Department of Energy (DOE) officials for complying with Sect. 402 of the Clean Water Act (CWA) of 1977 and amendments. Section 402 authorizes the US Environmental Protection Agency (EPA) or states with EPA approved programs to issue National Pollutant Discharge Elimination System (NPDES) permits for the direct discharge of waste from a point source into waters of the United States. Although the nature of a project dictates the exact information requirements, every project has similar information requirements on the environmental setting, type of discharge(s), characterization of effluent, and description of operations and wastewater treatment. Additional information requirements for projects with ocean discharges, thermal discharges, and cooling water intakes are discussed. Guidance is provided in this manual on general methods for collecting, analyzing, and presenting information for an NPDES permit application. The NPDES program interacts with many sections of the CWA; therefore, background material on pertinent areas such as effluent limitations, water quality standards, toxic substances, and nonpoint source pollutants is included in this manual. Modifications, variances, and extensions applicable to NPDES permits are also discussed.

A survey of prosthetic eye wearers to investigate mucoid discharge

Directory of Open Access Journals (Sweden)

Pine K

2012-05-01

Full Text Available Keith Pine1, Brian Sloan2, Joanna Stewart3, Robert J Jacobs11Department of Optometry and Vision Science, 2Department of Ophthalmology, New Zealand National Eye Centre, 3Section of Epidemiology and Biostatistics, School of Population Health, University of Auckland, Auckland, New ZealandBackground: This study aimed to better understand the causes and treatments of mucoid discharge associated with prosthetic eye wear by reviewing the literature and surveying anophthalmic patients.Methods: An anonymous questionnaire was completed by 429 prosthetic eye wearers who used visual analog scales to self-measure their discharge experience for four discharge characteristics: frequency, color, volume, and viscosity. These characteristics were analyzed with age, ethnicity, years wearing a prosthesis, eye loss cause, removal and cleaning regimes, hand-washing behavior, age of current prosthesis, and professional repolishing regimes as explanatory variables. Eighteen ocularists’ Web sites containing comments on the cause and treatment of discharge were surveyed.Results: Associations were found between discharge frequency and cleaning regimes with more frequent cleaning accompanying more frequent discharge. Color was associated with years of wearing and age, with more years of wearing and older people having less colored discharge. Volume was associated with cleaning regimes with more frequent cleaners having more volume. Viscosity was associated with cleaning regimes and years of wearing with more frequent cleaning and shorter wearing time accompanying more viscous discharge. No associations were found between discharge characteristics and ethnicity, eye loss cause, hand washing, age of current prosthesis, or repolishing regimes. Forty-seven percent of ocularists’ Web sites advised that discharge was caused by surface deposits on the prosthesis, 29% by excessive handling of the prosthesis, and 24% by other causes.Conclusions: A standardized treatment

Experiments on cleaning effects of TDC, GDC and ECR-DC in the JFT-2M tokamak

International Nuclear Information System (INIS)

Matsuzaki, Y.; Ogawa, H.; Miura, Y.; Ohtsuka, H.; Suzuki, N.; Yamauchi, T.; Tani, T.; Mori, M.

1987-01-01

The cleaning effects of Taylor-type discharge cleaning (TDC), glow discharge cleaning (GDC) and ECR discharge cleaning (ECR-DC) were studied in the JFT-2M tokamak by comparing the properties of resulting tokamak plasmas, by observing the surface composition of samples and by residual gas analysis. The operational parameters of the three discharge cleaning techniques were as follows; the plasma current for TDC is 20 kA, the DC current for GDC is 3 A and the RF power for ECR-DC is 2.3 kW. Parameters of the tokamak plasmas such as loop voltages, radiation losses, spectra emission of oxygen, maximum mean electron densities and profiles of electron temperature were improved as the TDC and ECR-DC proceeded. Changes in the surface composition of samples were measured by Auger electron spectrosopy. The results showed that during the TDC and ECR-DC oxygen was reduced, while GDC reduced mainly carbon. Residual gas analysis performed during discharge cleaning corroborated these results. (orig.)

ToF-SIMS Investigation of the Effectiveness of Acid-Cleaning procedures for Genesis Solar Wind Collectors

Science.gov (United States)

Goreva, Y. S.; Humanyun, M.; Burnett, D. S.; Jurewicz, A. J.; Gonzalez, C. P.

2014-01-01

ToF-SIMS images of Genesis sample surfaces contain an incredible amount of important information, but they also show that the crash-derived surface contamination has many components, presenting a challenge to cleaning. Within the variability, we have shown that there are some samples which appear to be clean to begin with, e.g. 60471, and some are more contaminated. Samples 60493 and 60500 are a part of a focused study of the effectiveness of aqua regia and/or sulfuric acid cleaning of small flight Si implanted with Li-6 using ToF-SIMS.

Conditioning of SST-1 Tokamak Vacuum Vessel by Baking and Glow Discharge Cleaning

International Nuclear Information System (INIS)

Khan, Ziauddin; George, Siju; Semwal, Pratibha; Dhanani, Kalpeshkumar R.; Pathan, Firozkhan S.; Paravastu, Yuvakiran; Raval, Dilip C.; Babu, Gattu Ramesh; Khan, Mohammed Shoaib; Pradhan, Subrata

2016-01-01

Highlights: • SST-1 Tokamak was successfully commissioned. • Vacuum vessel was pumped down to 4.5 × 10"–"8 mbar after baking and continuous GDC. • GDC reduced the water vapour by additional 57% while oxygen was reduced by 50%. • Under this condition, an initial plasma breakdown with current of 40 kA for 75 ms was achieved. - Abstract: Steady-state Superconducting Tokamak (SST-1) vacuum vessel (VV) adopts moderate baking at 110 ± 10 °C and the limiters baking at 250 ± 10 °C for ∼ 200 h followed by glow discharge cleaning in hydrogen (GDC-H) with 0.15 A/m"2 current density towards its conditioning prior to plasma discharge experiment. The baking in SST-1 reduces the water (H_2O) vapor by 95% and oxygen (O_2) by 60% whereas the GDC reduces the water vapor by an additional 57% and oxygen by another 50% as measured with residual gas analyzer. The minimum breakdown voltage for H-GDC in SST-1 tokamak was experimentally observed to 300 V at 8 mbar cm. As a result of these adherences, SST-1 VV achieves an ultimate of 4.5 × 10"−"8 mbar with two turbo-molecular pumps with effective pumping speed of 3250 l/s. In the last campaign, SST-1 has achieved successful plasma breakdown, impurity burn through and a plasma current of ∼ 40 kA for 75 ms.

Conditioning of SST-1 Tokamak Vacuum Vessel by Baking and Glow Discharge Cleaning

Energy Technology Data Exchange (ETDEWEB)

Khan, Ziauddin, E-mail: ziauddin@ipr.res.in; George, Siju; Semwal, Pratibha; Dhanani, Kalpeshkumar R.; Pathan, Firozkhan S.; Paravastu, Yuvakiran; Raval, Dilip C.; Babu, Gattu Ramesh; Khan, Mohammed Shoaib; Pradhan, Subrata

2016-02-15

Highlights: • SST-1 Tokamak was successfully commissioned. • Vacuum vessel was pumped down to 4.5 × 10{sup –8} mbar after baking and continuous GDC. • GDC reduced the water vapour by additional 57% while oxygen was reduced by 50%. • Under this condition, an initial plasma breakdown with current of 40 kA for 75 ms was achieved. - Abstract: Steady-state Superconducting Tokamak (SST-1) vacuum vessel (VV) adopts moderate baking at 110 ± 10 °C and the limiters baking at 250 ± 10 °C for ∼ 200 h followed by glow discharge cleaning in hydrogen (GDC-H) with 0.15 A/m{sup 2} current density towards its conditioning prior to plasma discharge experiment. The baking in SST-1 reduces the water (H{sub 2}O) vapor by 95% and oxygen (O{sub 2}) by 60% whereas the GDC reduces the water vapor by an additional 57% and oxygen by another 50% as measured with residual gas analyzer. The minimum breakdown voltage for H-GDC in SST-1 tokamak was experimentally observed to 300 V at 8 mbar cm. As a result of these adherences, SST-1 VV achieves an ultimate of 4.5 × 10{sup −8} mbar with two turbo-molecular pumps with effective pumping speed of 3250 l/s. In the last campaign, SST-1 has achieved successful plasma breakdown, impurity burn through and a plasma current of ∼ 40 kA for 75 ms.

L-Reactor 186-basin cleaning alternatives

International Nuclear Information System (INIS)

Turcotte, M.D.S.

1983-01-01

Operation of L Reactor will necessitate annual cleaning of the L Area 186 basins. Alternatives are presented for sediment discharge due to 186-basin cleaning activities as a basis for choosing the optimal cleaning method. Current cleaning activities (i.e. removal of accumulated sediments) for the P, C and K-Area 186 basins result in suspended solids concentrations in the effluent waters above the NPDES limits, requiring an exemption from the NPDES permit for these short-term releases. The objective of mitigating the 186-basin cleaning activities is to decrease the suspended solids concentrations to within permit limits while continuing satisfactory operation of the basins

Study on residual discharge time of lead-acid battery based on fitting method

Science.gov (United States)

Liu, Bing; Yu, Wangwang; Jin, Yueqiang; Wang, Shuying

2017-05-01

This paper use the method of fitting to discuss the data of C problem of mathematical modeling in 2016, the residual discharge time model of lead-acid battery with 20A,30A,…,100A constant current discharge is obtained, and the discharge time model of discharge under arbitrary constant current is presented. The mean relative error of the model is calculated to be about 3%, which shows that the model has high accuracy. This model can provide a basis for optimizing the adaptation of power system to the electrical motor vehicle.

A national discharge load of perfluoroalkyl acids derived from industrial wastewater treatment plants in Korea

Energy Technology Data Exchange (ETDEWEB)

Kim, Hee-Young; Seok, Hyun-Woo [Department of Civil and Environmental Engineering, Pusan National University, Busan 46241 (Korea, Republic of); Kwon, Hye-Ok; Choi, Sung-Deuk [School of Urban and Environmental Engineering, Ulsan National Institute of Science and Technology, Ulsan 44919 (Korea, Republic of); Seok, Kwang-Seol [Chemical Research Division, National Institute of Environmental Research, Incheon 22689 (Korea, Republic of); Oh, Jeong Eun [Department of Civil and Environmental Engineering, Pusan National University, Busan 46241 (Korea, Republic of)

2016-09-01

Levels of 11 perfluoroalkyl acids (PFAAs), including perfluorooctanoic acid (PFOA) and perfluorooctane sulfonic acid (PFOS), were measured in wastewater (influent and effluent) and sludge samples collected from 25 industrial wastewater treatment plants (I-WWTPs) in five industrial sectors (chemicals, electronics, metals, paper, and textiles) in South Korea. The highest ∑{sub 11}PFAAs concentrations were detected in the influent and effluent from the paper (median: 411 ng/L) and textile (median: 106 ng/L) industries, and PFOA and PFOS were the predominant PFAAs (49–66%) in wastewater. Exceptionally high levels of PFAAs were detected in the sludge associated with the electronics (median: 91.0 ng/g) and chemical (median: 81.5 ng/g) industries with PFOS being the predominant PFAA. The discharge loads of 11 PFAAs from I-WWTP were calculated that total discharge loads for the five industries were 0.146 ton/yr. The textile industry had the highest discharge load with 0.055 ton/yr (PFOA: 0.039 ton/yr, PFOS: 0.010 ton/yr). Municipal wastewater contributed more to the overall discharge of PFAAs (0.489 ton/yr) due to the very small industrial wastewater discharge compared to municipal wastewater discharge, but the contribution of PFAAs from I-WWTPs cannot be ignored. - Highlights: • 11 PFAAs in wastewater and sludge from 5 industrial sectors were investigated. • PFOA and PFOS were the dominant in wastewater while PFOS was predominant in sludge. • The total discharge loads from 5 industrial sectors 0.146 ton/yr. • The textile industry showed the highest discharge load with 0.055 ton/yr.

Corrective action plan for CAU Number 339: Area 12 Fleet Operations, Steam Cleaning Discharge Area, Nevada Test Site

International Nuclear Information System (INIS)

1997-05-01

The purpose of this Corrective Action Plan (CAP) is to provide the method for implementing the corrective action alternative as provided in the Corrective Action Decision Document (CADD). Detailed information of the site history and results of previous characterizations can be found in the Work Plan, the Preliminary Investigation Report, and the Phase 2 Characterization Report. Previous characterization investigations were completed as a condition of the Temporary Water Pollution Control Permit issued by the Nevada Division of Environmental Protection (NDEP) on July 14, 1992. The scope of this report is to prepare a CAP based upon the selected remedial alternative for closure of the Area 12, Building 12-16 Fleet Operations steam cleaning discharge area. The effluent discharge area has been impacted by volatile organic compounds (VOCs) and total petroleum hydrocarbons (TPH) as oil. The maximum hydrocarbon and VOC concentrations detected in the Preliminary and Phase 2 Site Characterization Investigations are summarized

Baking and helium glow discharge cleaning of SST-1 tokamak with graphite plasma facing components

International Nuclear Information System (INIS)

Semwal, Pratibha; Khan, Ziauddin; Raval, Dilip

2015-01-01

Graphite plasma facing components (PFCs) were installed inside SST-1 vacuum vessel. Prior to installation, all the graphite tiles were baked at 1000 °C in a vacuum furnace operated below 1.0 X 10 -5 mbar. However due to the porous structure of graphite, they absorb a significant amount of water vapour from air during the installation process. Rapid desorption of water vapour requires high temperature bake-out of the PFCs at ≥ 250 °C. In SST-1 the PFCs were baked at 250 °C using hot nitrogen gas facility to remove the absorbed water vapour. Also device with large graphite surface area has the disadvantage that a large quantity of hydrogen gets trapped inside it during plasma discharges which makes density control difficult. Helium (He) glow discharge cleaning (GDC) effectively removes this stored hydrogen as well as other impurities like oxygen and hydrocarbon within few nanometers from the surface by particle induced desorption. Before plasma operation in SST-1 tokamak, both baking of PFCs and He-GDC were carried out so that these impurities were removed effectively. The mean desorption yield of hydrogen was found to be 0.48. In this paper, the results of effect of baking and He-GDC experiments of SST-1 will be presented in detail. (author)

Baking and helium glow discharge cleaning of SST-1 Tokamak with graphite plasma facing components

Science.gov (United States)

Semwal, P.; Khan, Z.; Raval, D. C.; Dhanani, K. R.; George, S.; Paravastu, Y.; Prakash, A.; Thankey, P.; Ramesh, G.; Khan, M. S.; Saikia, P.; Pradhan, S.

2017-04-01

Graphite plasma facing components (PFCs) were installed inside the SST-1 vacuum vessel. Prior to installation, all the graphite tiles were baked at 1000 °C in a vacuum furnace operated below 1.0 × 10-5 mbar. However due to the porous structure of graphite, they absorb a significant amount of water vapour from air during the installation process. Rapid desorption of this water vapour requires high temperature bake-out of the PFCs at ≥ 250 °C. In SST-1 the PFCs were baked at 250 °C using hot nitrogen gas facility to remove the absorbed water vapour. Also device with large graphite surface area has the disadvantage that a large quantity of hydrogen gets trapped inside it during plasma discharges which makes density control difficult. Helium glow discharge cleaning (He-GDC) effectively removes this stored hydrogen as well as other impurities like oxygen and hydrocarbon within few nano-meters from the surface by particle induced desorption. Before plasma operation in SST-1 tokamak, both baking of PFCs and He-GDC were carried out so that these impurities were removed effectively. The mean desorption yield of hydrogen was found to be 0.24. In this paper the results of baking and He-GDC experiments of SST-1 will be presented in detail.

Edge-carboxylated graphene nanoflakes from nitric acid oxidised arc-discharge material

OpenAIRE

NICOLOSI, VALERIA

2010-01-01

PUBLISHED Graphene nanoflakes (GNFs) with average diameters of 30 nm have been prepared by a single-step oxidation procedure using single-wall carbon nanotube arc-discharge material and nitric acid. The GNFs are predominately single sheets containing a small number of internal defects. The edges are decorated with primarily carboxylic acid groups which allow facile chemical functionalisation and cross-linking of the fragments using multivalent cations

Respiratory Symptoms in Hospital Cleaning Staff Exposed to a Product Containing Hydrogen Peroxide, Peracetic Acid, and Acetic Acid.

Science.gov (United States)

Hawley, Brie; Casey, Megan; Virji, Mohammed Abbas; Cummings, Kristin J; Johnson, Alyson; Cox-Ganser, Jean

2017-12-15

Cleaning and disinfecting products consisting of a mixture of hydrogen peroxide (HP), peracetic acid (PAA), and acetic acid (AA) are widely used as sporicidal agents in health care, childcare, agricultural, food service, and food production industries. HP and PAA are strong oxidants and their mixture is a recognized asthmagen. However, few exposure assessment studies to date have measured HP, PAA, and AA in a health care setting. In 2015, we performed a health and exposure assessment at a hospital where a new sporicidal product, consisting of HP, PAA, and AA was introduced 16 months prior. We collected 49 full-shift time-weighted average (TWA) air samples and analyzed samples for HP, AA, and PAA content. Study participants were observed while they performed cleaning duties, and duration and frequency of cleaning product use was recorded. Acute upper airway, eye, and lower airway symptoms were recorded in a post-shift survey (n = 50). A subset of 35 cleaning staff also completed an extended questionnaire that assessed symptoms reported by workers as regularly occurring or as having occurred in the previous 12 months. Air samples for HP (range: 5.5 to 511.4 ppb) and AA (range: 6.7 to 530.3 ppb) were all below established US occupational exposure limits (OEL). To date, no full-shift TWA OEL for PAA has been established in the United States, however an OEL of 0.2 ppm has been suggested by several research groups. Air samples for PAA ranged from 1.1 to 48.0 ppb and were well below the suggested OEL of 0.2 ppm. Hospital cleaning staff using a sporicidal product containing HP, PAA, and AA reported work-shift eye (44%), upper airway (58%), and lower airway (34%) symptoms. Acute nasal and eye irritation were significantly positively associated with increased exposure to the mixture of the two oxidants: HP and PAA, as well as the total mixture (TM)of HP, PAA, and AA. Shortness of breath when hurrying on level ground or walking up a slight hill was significantly associated

Respiratory Symptoms in Hospital Cleaning Staff Exposed to a Product Containing Hydrogen Peroxide, Peracetic Acid, and Acetic Acid

Science.gov (United States)

Hawley, Brie; Casey, Megan; Virji, Mohammed Abbas; Cummings, Kristin J.; Johnson, Alyson; Cox-Ganser, Jean

2017-01-01

Cleaning and disinfecting products consisting of a mixture of hydrogen peroxide (HP), peracetic acid (PAA), and acetic acid (AA) are widely used as sporicidal agents in health care, childcare, agricultural, food service, and food production industries. HP and PAA are strong oxidants and their mixture is a recognized asthmagen. However, few exposure assessment studies to date have measured HP, PAA, and AA in a health care setting. In 2015, we performed a health and exposure assessment at a hospital where a new sporicidal product, consisting of HP, PAA, and AA was introduced 16 months prior. We collected 49 full-shift time-weighted average (TWA) air samples and analyzed samples for HP, AA, and PAA content. Study participants were observed while they performed cleaning duties, and duration and frequency of cleaning product use was recorded. Acute upper airway, eye, and lower airway symptoms were recorded in a post-shift survey (n = 50). A subset of 35 cleaning staff also completed an extended questionnaire that assessed symptoms reported by workers as regularly occurring or as having occurred in the previous 12 months. Air samples for HP (range: 5.5 to 511.4 ppb) and AA (range: 6.7 to 530.3 ppb) were all below established US occupational exposure limits (OEL). To date, no full-shift TWA OEL for PAA has been established in the United States, however an OEL of 0.2 ppm has been suggested by several research groups. Air samples for PAA ranged from 1.1 to 48.0 ppb and were well below the suggested OEL of 0.2 ppm. Hospital cleaning staff using a sporicidal product containing HP, PAA, and AA reported work-shift eye (44%), upper airway (58%), and lower airway (34%) symptoms. Acute nasal and eye irritation were significantly positively associated with increased exposure to the mixture of the two oxidants: HP and PAA, as well as the total mixture (TM) of HP, PAA, and AA. Shortness of breath when hurrying on level ground or walking up a slight hill was significantly associated

Chemical cleaning of UK AGR boilers

International Nuclear Information System (INIS)

Rudge, A.; Turner, P.; Ghosh, A.; Clary, W.; Tice, D.

2002-01-01

For the first time in their operational lives, UK advanced gas-cooled reactor once-through boilers have been chemically cleaned. Chemical cleaning was necessary to avoid lost output resulting from boiler pressure drops, which had been increasing for a number of years. Chemical cleaning of these boilers presents a number of unique difficulties. These include lack of access to the boilers, highly sensitised 316H superheater sections that cannot be excluded from the cleaning flow path, relatively thin boiler tube walls and an intolerance to boiler tube failure because of the role of the boilers in nuclear decay heat removal. The difficulties were overcome by implementing the clean in a staged manner, starting with an extensive materials testwork programme to select and then to substantiate the cleaning process. The selected process was based on ammoniated citric acid plus formic acid for the principal acid cleaning stage. Materials testwork was followed by an in-plant trial clean of six boiler tubes, further materials testwork and the clean of a boiler tube in a full-scale test rig. An overview is presented of the work that was carried out to demonstrate that the clean could be carried out safely, effectively and without leading to unacceptable corrosion losses. Full-scale chemical cleaning was implemented by using as much of the existing plant as possible. Careful control and monitoring was employed to ensure that the cleaning was implemented according to the specified design, thus ensuring that a safe and effective clean was carried out. Full-scale cleaning has resulted in significant boiler pressure drop recovery, even though the iron burden was relatively low and cleaning was completed in a short time. (orig.)

No positive effect of Acid etching or plasma cleaning on osseointegration of titanium implants in a canine femoral condyle press-fit model

DEFF Research Database (Denmark)

Saksø, Henrik; Jakobsen, Thomas Vestergaard; Mortensen, Mikkel Saksø

2013-01-01

Implant surface treatments that improve early osseointegration may prove useful in long-term survival of uncemented implants. We investigated Acid Etching and Plasma Cleaning on titanium implants.......Implant surface treatments that improve early osseointegration may prove useful in long-term survival of uncemented implants. We investigated Acid Etching and Plasma Cleaning on titanium implants....

Cleaning device for recycling pump motor cooling system in nuclear reactor

International Nuclear Information System (INIS)

Katayama, Kenjiro; Kondo, Takahisa; Shindo, Kenjiro; Akimoto, Jun.

1996-01-01

The cleaning device of the present invention comprises a cleaning water supply pump, a filter for filtering the cleaning water and a cap member for isolating the inside of a motor casing from the inside of a reactor pressure vessel. A motor in the motor casing and a pump in the reactor pressure vessel are removed, the cap member is attached to the upper end of the motor casing to isolate the inside of the motor casing from the inside of the reactor pressure vessel. If the cleaning water supply pump is operated in this state, the cleaning water flows from a returning pipeline for cooling water circulation, connected to the motor casing to supply pipelines through a heat exchange and is discharged. The discharged water passes through a filter and is sent again, as the cleaning water, to the cleaning water supply pump. With such procedures, the recycling pump motor cooling system in the BWR type reactor can be cleaned without disposing a cyclone separator and irrespective of presence or absence of reactor coolants in the reactor pressure vessel. (I.N.)

Gas plant cleaning case history

Energy Technology Data Exchange (ETDEWEB)

Woods, B

1971-03-22

Basic steps to be taken before using any cleaning method are select a responsible group and give it full responsibility; know the problem, what type of fouling, lab samples, amount of material, time and cost; sell the idea to management; maintain the cleaning equipment; and follow up each cleaning operation. These principles have been applied to advantage in the amine contractor at Taylor, a vessel 60 ft high with 78-in. OD, containing carbon steel deck trays with stainless steel caps. The original attempt to clean with wire scrapers manually involved much lost time and several crews. There was limited space in the tray vessels, design created areas difficult to clean, working conditions were unpleasant, equipment downtime was extended, labor cost was high, and the final result was not satisfactory. Chemical cleaning was substituted, preceded by a water wash. Five hours of caustic wash with a 3% solution at 170$F were followed by a water wash, an acid wash, 1-hr neutralization with a weak soda ash solution, and finally passivation to eliminate iron oxide. For the acid wash, sulfamic acid was found best, in 10% concentration for 4 hr. Cascading was most economical, but flooding has been employed sometimes at 2-1/2 times the cost, to reach all the dark corners.

Baking and helium glow discharge cleaning of SST-1 Tokamak with graphite plasma facing components

International Nuclear Information System (INIS)

Semwal, P; Khan, Z; Raval, D C; Dhanani, K R; George, S; Paravastu, Y; Prakash, A; Thankey, P; Ramesh, G; Khan, M S; Saikia, P; Pradhan, S

2017-01-01

Graphite plasma facing components (PFCs) were installed inside the SST-1 vacuum vessel. Prior to installation, all the graphite tiles were baked at 1000 °C in a vacuum furnace operated below 1.0 × 10 -5 mbar. However due to the porous structure of graphite, they absorb a significant amount of water vapour from air during the installation process. Rapid desorption of this water vapour requires high temperature bake-out of the PFCs at ≥ 250 °C. In SST-1 the PFCs were baked at 250 °C using hot nitrogen gas facility to remove the absorbed water vapour. Also device with large graphite surface area has the disadvantage that a large quantity of hydrogen gets trapped inside it during plasma discharges which makes density control difficult. Helium glow discharge cleaning (He-GDC) effectively removes this stored hydrogen as well as other impurities like oxygen and hydrocarbon within few nano-meters from the surface by particle induced desorption. Before plasma operation in SST-1 tokamak, both baking of PFCs and He-GDC were carried out so that these impurities were removed effectively. The mean desorption yield of hydrogen was found to be 0.24. In this paper the results of baking and He-GDC experiments of SST-1 will be presented in detail. (paper)

Cleaning up coal-fired plants : multi-pollutant technology

Energy Technology Data Exchange (ETDEWEB)

Granson, E.

2009-06-15

Coal is the source of 41 per cent of the world's electricity. Emission reduction technologies are needed to address the rapid growth of coal-fired plants in developing countries. This article discussed a multi-pollutant technology currently being developed by Natural Resources Canada's CANMET Energy Technology Centre. The ECO technology was designed to focus on several types of emissions, including sulfur oxides (SOx), nitrogen oxides (NOx), mercury and particulates, as well as acid gases and other metals from the exhaust gas of coal-fired plants. The ECO process converts and absorbs incoming pollutants in a wet electrostatic precipitator while at the same time producing a valuable fertilizer. The ECO system is installed as part of the plant's existing particulate control device and treats flue gas in 3 process steps: (1) a dielectric barrier discharge reactor oxidizes gaseous pollutants to higher oxides; (2) an ammonia scrubber then removes sulfur dioxide (SO{sub 2}) not converted by the reactor while also removing the NOx; and (3) the wet electrostatic precipitator captures acid aerosols produced by the discharge reactor. A diagram of the ECO process flow was included. It was concluded that the systems will be installed in clean coal plants by 2015. 2 figs.

Regeneration of Acid Orange 7 Exhausted Granular Activated Carbon Using Pulsed Discharge Plasmas

International Nuclear Information System (INIS)

Wang Huijuan; Guo He; Liu Yongjie; Yi Chengwu

2015-01-01

In this paper, a pulsed discharge plasma (PDP) system with a multi-needle-to-plate electrodes geometry was set up to investigate the regeneration of acid orange 7 (AO7) exhausted granular activated carbon (GAC). Regeneration of GAC was studied under different conditions of peak pulse discharge voltage and water pH, as well as the modification effect of GAC by the pulse discharge process, to figure out the regeneration efficiency and the change of the GAC structure by the PDP treatment. The obtained results showed that there was an appropriate peak pulse voltage and an optimal initial pH value of the solution for GAC regeneration. Analyses of scanning electron microscope (SEM), Boehm titration, Brunauer-Emmett-Teller (BET), Horvath-Kawazoe (HK), and X-ray Diffraction (XRD) showed that there were more mesopore and macropore in the regenerated GAC and the structure turned smoother with the increase of discharge voltage; the amount of acidic functional groups on the GAC surface increased while the amount of basic functional groups decreased after the regeneration process. From the result of the XRD analysis, there were no new substances produced on the GAC after PDP treatment. (paper)

Characteristics of 2-heptanone decomposition using nanosecond pulsed discharge plasma

Science.gov (United States)

Nakase, Yuki; Fukuchi, Yuichi; Wang, Douyan; Namihira, Takao; Akiyama, Hidenori; Kumamoto University Collaboration

2015-09-01

Volatile organic compounds (VOC) evaporate at room temperature. VOCs typically consist of toluene, benzene and ethyl acetate, which are used in cosmetics, dry cleaning products and paints. Exposure to elevated levels of VOCs may cause headaches, dizziness and irritation to the eyes, nose, and throat; they may also cause environmental problems such as air pollution, acid rain and photochemical smog. As such, they require prompt removal. Nanosecond pulsed discharge is a kind of non-thermal plasma consisting of a streamer discharge. Several advantages of nanosecond pulsed discharge plasma have been demonstrated by studies of our research group, including low heat loss, highly energetic electron generation, and the production of highly active radicals. These advantages have shown ns pulsed discharge plasma capable of higher energy efficiency for processes, such as air purification, wastewater treatment and ozone generation. In this research, nanosecond pulsed discharge plasma was employed to treat 2-heptanone, which is a volatile organic compound type and presents several harmful effects. Characteristics of treatment dependent on applied voltage, gas flow rate and input energy density were investigated. Furthermore, byproducts generated by treatment were also investigated.

Impact of Acid Cleaning on the Performance of PVDF UF Membranes in Seawater Reverse Osmosis Pretreatment

KAUST Repository

Alsogair, Safiya

2016-01-01

required to maintain the characteristics of the membrane. This research was made with the purpose of investigating the effects of acid cleaning during chemically enhanced backwashing (CEB) on the performance of ultrafiltration (UF) membranes in seawater

Clean coal technologies

International Nuclear Information System (INIS)

Aslanyan, G.S.

1993-01-01

According to the World Energy Council (WEC), at the beginning of the next century three main energy sources - coal, nuclear power and oil will have equal share in the world's total energy supply. This forecast is also valid for the USSR which possesses more than 40% of the world's coal resources and continuously increases its coal production (more than 700 million tons of coal are processed annually in the USSR). The stringent environmental regulations, coupled with the tendency to increase the use of coal are the reasons for developing different concepts for clean coal utilization. In this paper, the potential efficiency and environmental performance of different clean coal production cycles are considered, including technologies for coal clean-up at the pre-combustion stage, advanced clean combustion methods and flue gas cleaning systems. Integrated systems, such as combined gas-steam cycle and the pressurized fluidized bed boiler combined cycle, are also discussed. The Soviet National R and D program is studying new methods for coal utilization with high environmental performance. In this context, some basic research activities in the field of clean coal technology in the USSR are considered. Development of an efficient vortex combustor, a pressurized fluidized bed gasifier, advanced gas cleaning methods based on E-beam irradiation and plasma discharge, as well as new catalytic system, are are presented. In addition, implementation of technological innovations for retrofitting and re powering of existing power plants is discussed. (author)

Characterization of micro-organisms isolated from dairy industry after cleaning and fogging disinfection with alkyl amine and peracetic acid.

Science.gov (United States)

Bore, E; Langsrud, S

2005-01-01

To characterize micro-organisms isolated from Norwegian dairy production plants after cleaning and fogging disinfection with alkyl amine/peracetic acid and to indicate reasons for survival. Microbial samples were collected from five dairy plants after cleaning and fogging disinfection. Isolates from two of these production plants, which used fogging with alkylamino acetate (plant A), and peracetic acid (plant B), were chosen for further characterization. The sequence of the 16S ribosomal DNA, fatty acid analysis and biochemical characteristics were used to identify isolates. Three isolates identified as Rhodococcus erythropolis, Methylobacterium rhodesianum and Rhodotorula mucilaginosa were isolated from plant A and one Sphingomonas sp. and two M. extorquens from plant B. Different patterns of resistance to seven disinfectants in a bactericidal suspension test and variable degree of attachment to stainless steel were found. The strains with higher disinfectant resistance showed lower degree of attachment than susceptible strains. The study identifies and characterizes micro-organisms present after cleaning and fogging disinfection. Both surface attachment and resistance were shown as possible reasons for the presence of the isolates after cleaning and disinfection. These results contribute to the awareness of disinfectant resistance as well as attachment as mechanisms of survival in dairy industry. It also strengthens the argument of frequent alternation of disinfectants in the food processing industry to avoid the establishment of resistant house strains.

Degradation of gas-liquid gliding arc discharge on Acid Orange II

International Nuclear Information System (INIS)

Yan, J.H.; Liu, Y.N.; Bo, Zh.; Li, X.D.; Cen, K.F.

2008-01-01

The effects of pH value, initial concentration of dye solution and temperature on the degradation efficiency of Acid Orange II (AO7) using gas-liquid gliding arc discharge were investigated. The influences of pH value and temperature on degradation efficiency were not apparent. Increasing initial solution concentration caused the decrease of degradation rate and the increase of absolute degradation quantity. Considering energy efficiency and absolute degradation quantity, the gas-liquid gliding arc discharge is fit for treating high concentration organic wastewater. A possible mineralization pathway was proposed through the analysis of intermediate products detected by gas chromatograph coupled with mass spectrophotometer (GC-MS) and ion chromatograph (IC). Hydroxyl radicals reacted with the azo linkage-bearing carbon of a hydroxy-substituted ring, leading to the cleavage of -C-N- and degradation of AO7. The solution biodegradability was significantly improved (BOD 5 /COD from 0.02 to 0.43). The toxicity of intermediate products was lower than that of the initial Acid Orange II

Power generation from chemically cleaned coals: do environmental benefits of firing cleaner coal outweigh environmental burden of cleaning?

DEFF Research Database (Denmark)

Ryberg, Morten W.; Owsianiak, Mikolaj; Laurent, Alexis

2015-01-01

Power generation from high-ash coals is a niche technology for power generation, but coal cleaning is deemed necessary to avoid problems associated with low combustion efficiencies and to minimize environmental burdens associated with emissions of pollutants originating from ash. Here, chemical...... beneficiation of coals using acid and alkali–acid leaching procedures is evaluated as a potential coal cleaning technology employing life cycle assessment (LCA). Taking into account the environmental benefits from firing cleaner coal in pulverized coal power plants and the environmental burden of the cleaning...... itself, it is demonstrated that for a wide range of cleaning procedures and types of coal, chemical cleaning generally performs worse than combustion of the raw coals and physical cleaning using dense medium separation. These findings apply for many relevant impact categories, including climate change...

Acid-base status of soils in groundwater discharge zones — relation to surface water acidification

Science.gov (United States)

Norrström, Ann Catrine

1995-08-01

Critical load calculations have suggested that groundwater at depth of 2 m in Sweden is very sensitive to acid load. As environmental isotope studies have shown that most of the runoff in streams has passed through the soil, there is a risk in the near future of accelerated acidification of surface waters. To assess the importance of the last soil horizon of contact before discharge, the upper 0-0.2m of soils in seven discharge zones were analysed for pools of base cations, acidity and base saturation. The sites were about 3-4 m 2 in size and selected from two catchments exposed to different levels of acid deposition. The soils in the seven sites had high concentrations of exchangeable base cations and consequently high base saturation. The high correlation ( r2 = 0.74) between base saturation in the soils of the discharge zones and mean pH of the runoff waters suggested that the discharge zone is important for surface water acidification. The high pool of exchangeable base cations will buffer initially against the acid load. As the cation exchange capacity (meq dm -3) and base saturation were lower in the sites from the catchment receiving lower deposition, these streams may be more vulnerable to acidification in the near future. The high concentration of base cations in non-exchangeable fractions may also buffer against acidification as it is likely that some of these pools will become exchangeable with time.

Reconstructing the history of 14C discharges from Sellafield. Part 2. Aquatic discharges

International Nuclear Information System (INIS)

Cook, G.T.; MacKenzie, A.B.; Naysmith, F.H.; Anderson, R.; Naysmith, P.; Kershaw, P.J.

2004-01-01

Prior to 1984, the reported marine 14 C discharges from Sellafield were estimates: 0.2 TBq per annum from 1952 to 1969 and 1 TBq per annum until 1984 when measurements commenced. The relationship between the net excess 14 C activity in annually collected Nori (Porphyra umbilicalis) seaweed samples and the annual discharges (estimated and measured) implies that the discharges were not as constant as the estimates. Based on the relationship between post-1984 measured discharges and the excess 14 C in the seaweed, two simple empirical models were used to re-calculate the discharges between 1967 and 1984. Gamma-spectrometry measurements on the seaweed also indicate that Porphyra is a sensitive indicator of changes in discharge of other radionuclides, brought about by the introduction of new waste clean-up technologies within Sellafield. (author)

Re-design of ITER Glow Discharge Cleaning system based on a fixed electrode concept

International Nuclear Information System (INIS)

Yang, Y.; Maruyama, S.; Kiss, G.; O’Connor, M.; Zhang, Y.; Pitts, R.A.; Shimada, M.; Fang, T.; Wang, Y.; Wang, M.; Pan, Y.; Li, B.; Li, L.

2014-01-01

Highlights: •This paper summarizes the approved new design of ITER GDC. •It is based on the fixed electrode design instead of the previous movable concept. •Estimates were made on the glow current density. •R and D topics on initiation, steady state and heat load were presented. •Other relevant considerations were listed in an exhaustive manner. -- Abstract: A new design of ITER Glow Discharge Cleaning (GDC) system based on a fixed electrode concept replaces the previous design which was based on a movable electrode integrated with the ITER In-Vessel-Viewing-System. Recently the conceptual design of the GDC system was reviewed successfully on the functions, safety, operation and maintenance. The design proposed was checked against the requirements and found to be feasible. This paper gives an overall description of the requirements from physics and operation viewpoints and introduces the design at the conceptual level. Main R and D activities are listed and summarized. Further detailed studies are to be performed in the following design stage

Evaluation of natural amelioration of acidic deep mine discharges in Western Pennsylvania

International Nuclear Information System (INIS)

Lambert, D.C.; Dzombak, D.A.; Aljoe, W.W.

1999-01-01

Abandoned mine drainage (AMD) has long been the most serious water quality and watershed degradation problem in the Appalachian region of the U.S. and in some other areas of the nation. In several areas of western Pennsylvania, deep mine discharges that were reliably described as highly acidic in the 1960s and 1970s have shown natural amelioration of CO 2 acidity. A number of different factors, including mine flooding and overburden chemistry, may cause improvement in mine water quality. The authors are studying the hydrologic and geochemical factors responsible for improvements over time in the quality of water discharges from abandoned deep mines. The project is focused on the study of a set of mine water discharges associated with abandoned, interconnected deep mines in the Uniontown Syncline of Western Pennsylvania. This area was studied extensively under Pennsylvania's Operation Scarlift in the early 1970s, and one year of monthly water quality data are available from 1974-75. The mined-out coal basin of the Uniontown Syncline is unique in that different mining methods were employed in the same coal seam over the basin. The resulting discharges are from flooded, unflooded, and partially flooded abandoned underground coal mines. This paper presents an overview of the hydraulic system in the mine network of the Uniontown Syncline along with a summary of selected data from the 1974-75 and 1998-99 studies. Preliminary interpretations of these data in relation to the Scarlift data are also presented

Cleaning the feed-water pipeline internal surfaces

International Nuclear Information System (INIS)

Podkopaev, V.A.

1984-01-01

The procedure of cleaning the feed-water pipeline internal surfaces at the Chernobylsk-4 power unit is described. Cleaning was conducted in five stages. Pipelines were cleaned from mechanical impurities at the first stage. At the second stage the pipelines were washing by water heated up to 80 deg C. At the third stage nitric acid was added to 95-100 deg C water the acid concentration in the circuit = 60 mg/l, purification period = 14 h. At the fourth stage hydrogen peroxide was added to the circuit at 95-100 deg C (the solution concentration was equal to 5-6 mg/l, the solution stayed in the circuit for 1 h 20 min). At the fifth stage sodium nitrite concentrated to 20 mg/l was introduced to the circuit in 75 minutes; this promoted strengthening of the oxide layer in the circuit on the base of nitric acid and hydrogen peroxide. Data on the water acidity in the circuit, water electric conductivity and iron concentration after the fourth stage and on completion of the circuit cleaning are presented. The described method of cleaning enables to save scarce reagents and use cheaper ones

Cleaning the feed-water pipeline internal surfaces

Energy Technology Data Exchange (ETDEWEB)

Podkopaev, V.A.

1984-12-01

The procedure of cleaning the feed-water pipeline internal surfaces at the Chernobylsk-4 power unit is described. Cleaning was conducted in five stages. Pipelines were cleaned from mechanical impurities at the first stage. At the second stage the pipelines were washed by water heated up to 80 deg C. At the third stage nitric acid was added to 95-100 deg C water with the acid concentration in the circuit = 60 mg/l, purification period = 14 h. At the fourth stage hydrogen peroxide was added to the circuit at 95-100 deg C (the solution concentration was equal to 5-6 mg/l, the solution stayed in the circuit for 1 h 20 min). At the fifth stage sodium nitrite concentrated to 20 mg/l was introduced to the circuit in 75 minutes; this promoted strengthening of the oxide layer in the circuit on the base of nitric acid and hydrogen peroxide. Data on the water acidity in the circuit, water electric conductivity and iron concentration after the fourth stage and on completion of the circuit cleaning are presented. The described method of cleaning enables to save scarce reagents and use cheaper ones.

Degradation of Acid Orange 7 Dye in Two Hybrid Plasma Discharge Reactors

Science.gov (United States)

Shen, Yongjun; Lei, Lecheng; Zhang, Xingwang; Ding, Jiandong

2014-11-01

To get an optimized pulsed electrical plasma discharge reactor and to increase the energy utilization efficiency in the removal of pollutants, two hybrid plasma discharge reactors were designed and optimized. The reactors were compared via the discharge characteristics, energy transfer efficiency, the yields of the active species and the energy utilization in dye wastewater degradation. The results showed that under the same AC input power, the characteristics of the discharge waveform of the point-to-plate reactor were better. Under the same AC input power, the two reactors both had almost the same peak voltage of 22 kV. The peak current of the point-to-plate reactor was 146 A, while that of the wire-to-cylinder reactor was only 48.8 A. The peak powers of the point-to-plate reactor and the wire-to-cylinder reactor were 1.38 MW and 1.01 MW, respectively. The energy per pulse of the point-to-plate reactor was 0.2221 J, which was about 29.4% higher than that of the wire-to-cylinder reactor (0.1716 J). To remove 50% Acid Orange 7 (AO7), the energy utilizations of the point-to-plate reactor and the wire-to-cylinder reactor were 1.02 × 10-9 mol/L and 0.61 × 10-9 mol/L, respectively. In the point-to-plate reactor, the concentration of hydrogen peroxide in pure water was 3.6 mmol/L after 40 min of discharge, which was higher than that of the wire-to-cylinder reactor (2.5 mmol/L). The concentration of liquid phase ozone in the point-to-plate reactor (5.7 × 10-2 mmol/L) was about 26.7% higher than that in the wire-to-cylinder reactor (4.5 × 10-2 mmol/L). The analysis results of the variance showed that the type of reactor and reaction time had significant impacts on the yields of the hydrogen peroxide and ozone. The main degradation intermediates of AO7 identified by gas chromatography and mass spectrometry (GCMS) were acetic acid, maleic anhydride, p-benzoquinone, phenol, benzoic acid, phthalic anhydride, coumarin and 2-naphthol. Proposed degradation pathways were

Degradation of Acid Orange 7 Dye in Two Hybrid Plasma Discharge Reactors

International Nuclear Information System (INIS)

Shen Yongjun; Ding Jiandong; Lei Lecheng; Zhang Xingwang

2014-01-01

To get an optimized pulsed electrical plasma discharge reactor and to increase the energy utilization efficiency in the removal of pollutants, two hybrid plasma discharge reactors were designed and optimized. The reactors were compared via the discharge characteristics, energy transfer efficiency, the yields of the active species and the energy utilization in dye wastewater degradation. The results showed that under the same AC input power, the characteristics of the discharge waveform of the point-to-plate reactor were better. Under the same AC input power, the two reactors both had almost the same peak voltage of 22 kV. The peak current of the point-to-plate reactor was 146 A, while that of the wire-to-cylinder reactor was only 48.8 A. The peak powers of the point-to-plate reactor and the wire-to-cylinder reactor were 1.38 MW and 1.01 MW, respectively. The energy per pulse of the point-to-plate reactor was 0.2221 J, which was about 29.4% higher than that of the wire-to-cylinder reactor (0.1716 J). To remove 50% Acid Orange 7 (AO7), the energy utilizations of the point-to-plate reactor and the wire-to-cylinder reactor were 1.02 × 10 −9 mol/L and 0.61 × 10 −9 mol/L, respectively. In the point-to-plate reactor, the concentration of hydrogen peroxide in pure water was 3.6 mmol/L after 40 min of discharge, which was higher than that of the wire-to-cylinder reactor (2.5 mmol/L). The concentration of liquid phase ozone in the point-to-plate reactor (5.7 × 10 −2 mmol/L) was about 26.7% higher than that in the wire-to-cylinder reactor (4.5 × 10 −2 mmol/L). The analysis results of the variance showed that the type of reactor and reaction time had significant impacts on the yields of the hydrogen peroxide and ozone. The main degradation intermediates of AO7 identified by gas chromatography and mass spectrometry (GCMS) were acetic acid, maleic anhydride, p-benzoquinone, phenol, benzoic acid, phthalic anhydride, coumarin and 2-naphthol. Proposed degradation

Chemical cleaning, decontamination and corrosion

International Nuclear Information System (INIS)

Gadiyar, H.S.; Das Chintamani; Gaonkar, K.B.

1991-01-01

Chemical cleaning of process equipments and pipings in chemical/petrochemical industries is necessitated for improving operation, for preventing premature failures and for avoiding contamination. In developing a chemical formulation for cleaning equipments, the important aspects to be considered include (i) effective removal of corrosion products and scales, (ii) minimum corrosion of the base metal, (iii) easy to handle chemicals and (iv) economic viability. As on date, a wide variety of chemical formulations are available, many of them are either proprietory or patented. For evolving an effective formulation, knowledge of the oxides of various metals and alloys on the one hand and acid concentration, complexing agents and inhibitors to be incorporated on the other, is quite essential. Organic acids like citric acid, acetic acid and formic acid are more popular ones, often used with EDTA for effective removal of corrosion products from ferrous components. The report enumerates some of the concepts in developing effective formulations for chemical cleaning of carbon steel components and further, makes an attempt to suggest simple formulations to be developed for chemical decontamination. (author). 6 refs., 3 fi gs., 4 tabs

Discharge and infection in retinoblastoma post-enucleation sockets

Directory of Open Access Journals (Sweden)

Mourits DL

2017-03-01

Full Text Available Daphne L Mourits,1 Dyonne T Hartong,1 Andries E Budding,2 Machteld I Bosscha,1 H Stevie Tan,1 Annette C Moll1 1Department of Ophthalmology, VU University Medical Center, 2Department of Microbiology, Academic Medical Center, Amsterdam, the Netherlands Purpose: To investigate the causes and treatment options for socket discharge and infection in patients enucleated for retinoblastoma (Rb. Methods: A questionnaire was filled out by (parents of ocular prosthesis-wearing patients with a history of enucleation as treatment for Rb. We collected data on patients’ characteristics, cleaning habits of the prosthesis, frequency of socket irritation, discharge, and infection, and use of antibiotics. With ordinal logistic regression analysis, factors related to the outcome parameters (frequency of irritation, mucoid and purulent discharge were identified. In a subset of young asymptomatic and symptomatic patients, a swab culture of the socket was performed to determine the presence of microorganisms. Results: A total of 186 patients or their parents (mean age of the patients: 17.3 years, ranging from 0.8 to 88.3 years filled out the questionnaire. Irritation, mucoid discharge, and purulent discharge were frequently (once a month or more often experienced in 75 (39.5%, 127 (66.8%, and 15 (13.2% sockets, respectively. Younger age was associated with a higher frequency of mucoid and purulent discharge. Radiation therapy, chemotherapy, gender, age at surgery, cleaning frequency, and nocturnal wear were not associated with the outcome parameters. In a subgroup of 26 patients, the sockets were swabbed and cultured. All symptomatic patients had a positive bacterial culture versus 15% (2/13 of the asymptomatic patients (P<0.001. Common cold was correlated with both symptoms and presence of bacteria. Haemophilus influenzae and Staphylococcus aureus were the species most frequently cultured. Conclusion: Ocular prosthesis-wearing patients often experienced mucoid

Glow discharging device

International Nuclear Information System (INIS)

Maeno, Katsuki; Kawasaki, Kozo; Hiratsuka, Hajime; Kawashima, Shuichi.

1989-01-01

In a thermonuclear device, etc. impurities adsorbed to inner walls of a vacuum vessel by glow discharge are released to clean the vacuum vessel for preventing intrusion of the impurities into plasmas. The object of the present invention is to minimize the capacity of a power source equipment for the glow discharge device to the least extent. That is, a stabilization resistance is connected in series between each of a plurality of anodes which are inserted and arranged at the inside of a vacuum vessel as a cathode and a power source respectively. The resistance value R is selected so as to satisfy the relation: R < (Vi - Vm)/Ii, in which Vi: glow discharge starting voltage, Vm: glow discharge keeping voltage, Ii: glow discharge starting current. Accordingly, if a voltage is applied from a power source to a plurality of anodes, scattering of electric discharge between the anodes can be suppressed and the effect of voltage drop during discharge by the stabilization resistance can be eliminated. As a result, it is possible to provide an economically advantageous glow discharge device with the capacity for the power source facility being to the least extent. (K.M.)

Discharge and infection in retinoblastoma post-enucleation sockets.

Science.gov (United States)

Mourits, Daphne L; Hartong, Dyonne T; Budding, Andries E; Bosscha, Machteld I; Tan, H Stevie; Moll, Annette C

2017-01-01

To investigate the causes and treatment options for socket discharge and infection in patients enucleated for retinoblastoma (Rb). A questionnaire was filled out by (parents of) ocular prosthesis-wearing patients with a history of enucleation as treatment for Rb. We collected data on patients' characteristics, cleaning habits of the prosthesis, frequency of socket irritation, discharge, and infection, and use of antibiotics. With ordinal logistic regression analysis, factors related to the outcome parameters (frequency of irritation, mucoid and purulent discharge) were identified. In a subset of young asymptomatic and symptomatic patients, a swab culture of the socket was performed to determine the presence of microorganisms. A total of 186 patients or their parents (mean age of the patients: 17.3 years, ranging from 0.8 to 88.3 years) filled out the questionnaire. Irritation, mucoid discharge, and purulent discharge were frequently (once a month or more often) experienced in 75 (39.5%), 127 (66.8%), and 15 (13.2%) sockets, respectively. Younger age was associated with a higher frequency of mucoid and purulent discharge. Radiation therapy, chemotherapy, gender, age at surgery, cleaning frequency, and nocturnal wear were not associated with the outcome parameters. In a subgroup of 26 patients, the sockets were swabbed and cultured. All symptomatic patients had a positive bacterial culture versus 15% (2/13) of the asymptomatic patients ( P socket infection. These complaints were found to decrease with increasing age, but did not seem to be influenced by cleaning or wearing habits. Symptomatic sockets, with and without discharge, were correlated with the presence of pathogenic bacteria for which local antibiotic treatment seemed effective in most cases.

Alternative Chemical Cleaning Methods for High Level Waste Tanks: Simulant Studies

Energy Technology Data Exchange (ETDEWEB)

Rudisill, T. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); King, W. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Hay, M. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Jones, D. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2015-11-19

Solubility testing with simulated High Level Waste tank heel solids has been conducted in order to evaluate two alternative chemical cleaning technologies for the dissolution of sludge residuals remaining in the tanks after the exhaustion of mechanical cleaning and sludge washing efforts. Tests were conducted with non-radioactive pure phase metal reagents, binary mixtures of reagents, and a Savannah River Site PUREX heel simulant to determine the effectiveness of an optimized, dilute oxalic/nitric acid cleaning reagent and pure, dilute nitric acid toward dissolving the bulk non-radioactive waste components. A focus of this testing was on minimization of oxalic acid additions during tank cleaning. For comparison purposes, separate samples were also contacted with pure, concentrated oxalic acid which is the current baseline chemical cleaning reagent. In a separate study, solubility tests were conducted with radioactive tank heel simulants using acidic and caustic permanganate-based methods focused on the “targeted” dissolution of actinide species known to be drivers for Savannah River Site tank closure Performance Assessments. Permanganate-based cleaning methods were evaluated prior to and after oxalic acid contact.

Primordial Synthesis of Amines and Amino Acids in a 1958 Miller H2S-Rich Spark Discharge Experiment

Science.gov (United States)

Parker, Eric T.; Cleaves, Henderson J.; Dworkin, Jason P.; Glavin, Daniel P.; Callahan, Michael; Aubrey, Andrew; Lazcano, Antonio; Bada, Jeffrey L.

2011-01-01

Archived samples from a previously unreported 1958 Stanley Miller electric discharge experiment containing hydrogen sulfide (H2S) were recently discovered and analyzed using high-performance liquid chromatography and time-of-flight mass spectrometry. We report here the detection and quantification of primary amine-containing compounds in the original sample residues, which were produced via spark discharge using a gaseous mixture of H2S, CH4, NH3, and CO2. A total of 23 amino acids and 4 amines, including 7 organosulfur compounds, were detected in these samples. The major amino acids with chiral centers are racemic within the accuracy of the measurements, indicating that they are not contaminants introduced during sample storage. This experiment marks the first synthesis of sulfur amino acids from spark discharge experiments designed to imitate primordia! environments. The relative yield of some amino acids, in particular the isomers of aminobutyric acid, are the highest ever found in a spark discharge experiment. The simulated primordial conditions used by Miller may serve as a model for early volcanic plume chemistry and provide insight to the possible roles such plumes may have played in abiotic organic synthesis. Additionally, the overall abundances of the synthesized amino acids in the presence of H2S are very similar to the abundances found in some carbonaceous meteorites, suggesting that H2S may have played an important role in prebiotic reactions in early solar system environments.

Electrohydraulic Discharges and Nonthermal Plasma for Water Treatment

Czech Academy of Sciences Publication Activity Database

Locke, B.R.; Sato, M.; Hoffman, M.R.; Chang, J.S.; Šunka, Pavel

2006-01-01

Roč. 45, č. 1 (2006), s. 882-905 ISSN 0888-5885 Institutional research plan: CEZ:AV0Z20430508 Keywords : Electrical discharges * water cleaning * environmental applications * liquid phase reactor Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 1.518, year: 2006

Technology for cleaning of Pb-Bi adhering to steel (1). Basic tests

International Nuclear Information System (INIS)

Saito, Shigeru; Sasa, Toshinobu; Umeno, Makoto; Kurata, Yuji; Kikuchi, Kenji; Futakawa, Masatoshi

2004-12-01

The accelerator driven system (ADS) is proposed to transmute minor actinides (MA) in high-level waste from spent fuels of nuclear power reactors. Liquid Pb-Bi alloy is a candidate material for spallation target and coolant of ADS. Pb-Bi cleaning technology is required to reduce radiation exposure during maintenance service and to decontaminate replaced components. In this study, three cleaning methods were tested; silicon oil cleaning at 170degC, mixture of acetic acid and nitric acid cleaning. Specimens were prepared by immersion in melted Pb-Bi. After silicon oil tests, most of Pb-Bi remained on the surface of the specimens. It was found that blushing was needed to remove Pb-Bi effectively. On the other hands, Pb-Bi was easily dissolved and almost removed in the mixed acid and nitric acid. Silicon oil cleaning did not affect on base metals. The surface of base metals was slightly blacked after mixed acid cleaning. F82H base metals were corroded by nitric acid. (author)

Dischargers_Example.png | ECHO | US EPA

Science.gov (United States)

ECHO, Enforcement and Compliance History Online, provides compliance and enforcement information for approximately 800,000 EPA-regulated facilities nationwide. ECHO includes permit, inspection, violation, enforcement action, and penalty information about facilities regulated under the Clean Air Act (CAA) Stationary Source Program, Clean Water Act (CWA) National Pollutant Elimination Discharge System (NPDES), and/or Resource Conservation and Recovery Act (RCRA). Information also is provided on surrounding demographics when available.

Removal of particles by ICRF cleaning in HT-7 superconducting tokamak

International Nuclear Information System (INIS)

Hu Jiansheng; Li Jiangang; Zhang Shouyin; Gu Xuemao; Zhang Xiaodong; Zhao Yanping; Gong Xianzu; Kuang Guangli; Li Chengfu; Luo Jiarong; Wang Xiaoming; Gao Xiang; Wan Baonian; Xie Jikang; Wan Yuanxi

2001-01-01

The ICRF (Ion Cyclotron Range Frequency) cleaning technique has been used as a routine wall cleaning method in the HT-7 superconducting tokamak. In a wide range of toroidal field, the removal rate of residual gas by ICRF cleaning was about twenty times higher than that of glow discharge cleaning (GDC). At different gas pressure and RF power levels, the ICRF cleaning is studied carefully. A good impurity cleaning effect and a very high hydrogen removal rate were obtained. The removal rate of hydrogen by 5 kW ICRF cleaning achieved was 1.6 x 10 -5 Torr.l/s. And the relationships among pressure P, outgassing rate Q, atomic layers L absorbed on surface and the cleaning mode were discussed briefly

REVIEW OF ALTERNATIVE ENHANCED CHEMICAL CLEANING OPTIONS FOR SRS WASTE TANKS

Energy Technology Data Exchange (ETDEWEB)

Hay, M.; Koopman, D.

2009-08-01

A literature review was conducted to support the Task Technical and Quality Assurance Plan for Alternative Enhanced Chemical Cleaning (AECC) for sludge heel removal funded as part of the EM-21 Engineering and Technology program. The goal was to identify potential technologies or enhancements to the baseline oxalic acid cleaning process for chemically dissolving or mobilizing Savannah River Site (SRS) sludge heels. The issues with the potentially large volume of oxalate solids generated from the baseline process have driven an effort to find an improved or enhanced chemical cleaning technology for the tank heels. This literature review builds on a previous review conducted in 2003. A team was charged with evaluating the information in these reviews and developing recommendations of alternative technologies to pursue. The new information in this report supports the conclusion of the previous review that oxalic acid remains the chemical cleaning agent of choice for dissolving the metal oxides and hydroxides found in sludge heels in carbon steel tanks. The potential negative impact of large volumes of sodium oxalate on downstream processes indicates that the amount of oxalic acid used for chemical cleaning needs to be minimized as much as possible or the oxalic acid must be destroyed prior to pH adjustment in the receipt tank. The most straightforward way of minimizing the volume of oxalic acid needed for chemical cleaning is through more effective mechanical cleaning. Using a mineral acid to adjust the pH of the sludge prior to adding oxalic acid may also help to minimize the volume of oxalic acid used in chemical cleaning. If minimization of oxalic acid proves insufficient in reducing the volume of oxalate salts, several methods were found that could be used for oxalic acid destruction. For some waste tank heels, another acid or even caustic treatment (or pretreatment) might be more appropriate than the baseline oxalic acid cleaning process. Caustic treatment of high

Basic study for gas cleaning using discharge and electrophoresis

International Nuclear Information System (INIS)

Su, Zhen-Zhou; Sawada, Jun; Takashima, Kazunori; Katsura, Shinji; Mizuno, Akira

2004-01-01

A NO x removal method using discharge plasma and electrophoresis for exhaust control was studied. The 65-50% of NO was oxidized to NO 2 or HNO 3 by the discharge plasma with specific input energy of 45J/l. The electrophoresis was carried out to concentrate the NO 2 or HNO 3 adsorbed on the adsorbents. As a result, 80% of the adsorbed nitrate ions were found in the anode region. A combination of molecular sieve pellets of 13X and glass fiber cloth was tested for the collection of nitrate ions. The ability of simultaneous concentration of nitrate ions and sulfate ions using electrophoresis was examined

Clean vehicles as an enabler for a clean electricity grid

Science.gov (United States)

Coignard, Jonathan; Saxena, Samveg; Greenblatt, Jeffery; Wang, Dai

2018-05-01

California has issued ambitious targets to decarbonize transportation through the deployment of electric vehicles (EVs), and to decarbonize the electricity grid through the expansion of both renewable generation and energy storage. These parallel efforts can provide an untapped synergistic opportunity for clean transportation to be an enabler for a clean electricity grid. To quantify this potential, we forecast the hourly system-wide balancing problems arising out to 2025 as more renewables are deployed and load continues to grow. We then quantify the system-wide balancing benefits from EVs modulating the charging or discharging of their batteries to mitigate renewable intermittency, without compromising the mobility needs of drivers. Our results show that with its EV deployment target and with only one-way charging control of EVs, California can achieve much of the same benefit of its Storage Mandate for mitigating renewable intermittency, but at a small fraction of the cost. Moreover, EVs provide many times these benefits if two-way charging control becomes widely available. Thus, EVs support the state’s renewable integration targets while avoiding much of the tremendous capital investment of stationary storage that can instead be applied towards further deployment of clean vehicles.

Amino Acids Generated from Hydrated Titan Tholins: Comparison with Miller-Urey Electric Discharge Products

Science.gov (United States)

Cleaves, H. James, II; Neish, Catherine; Callahan, Michael P.; Parker, Eric; Fernandez, Facundo M.; Dworkin, Jason P.

2014-01-01

Various analogues of Titan haze particles (termed tholins) have been made in the laboratory. In certain geologic environments on Titan, these haze particles may come into contact with aqueous ammonia (NH3) solutions, hydrolyzing them into molecules of astrobiological interest. A Titan tholin analogue hydrolyzed in aqueous NH3 at room temperature for 2.5 years was analyzed for amino acids using highly sensitive ultra-high performance liquid chromatography coupled with fluorescence detection and time-of-flight mass spectrometry (UHPLC-FDToF-MS) analysis after derivatization with a fluorescent tag. We compare here the amino acids produced from this reaction sequence with those generated from room temperature Miller-Urey (MU) type electric discharge reactions. We find that most of the amino acids detected in low temperature MU CH4N2H2O electric discharge reactions are generated in Titan simulation reactions, as well as in previous simulations of Triton chemistry. This argues that many processes provide very similar mixtures of amino acids, and possibly other types of organic compounds, in disparate environments, regardless of the order of hydration. Although it is unknown how life began, it is likely that given reducing conditions, similar materials were available throughout the early Solar System and throughout the universe to facilitate chemical evolution.

The "F" in SAFE: Reliability of assessing clean faces for trachoma control in the field.

Directory of Open Access Journals (Sweden)

Sheila K West

2017-11-01

Full Text Available Although facial cleanliness is part of the SAFE strategy for trachoma there is controversy over the reliability of measuring a clean face. A child's face with no ocular and nasal discharge is clean and the endpoint of interest, regardless of the number of times it must be washed to achieve that endpoint. The issue of reliability rests on the reproducibility of graders to assess a clean face. We report the reproducibility of assessing a clean face in a field trial in Kongwa, Tanzania.Seven graders were trained to assess the presence and absence of nasal and ocular discharge on children's faces. Sixty children ages 1-7 years were recruited from a community and evaluated independently by seven graders, once and again about 50 minutes later. Intra-and inter-observer variation was calculated using unweighted kappa statistics. The average intra-observer agreement was kappa = 0.72, and the average inter-observer agreement was kappa = 0.78.Intra-observer and inter-observer agreement was substantial for the assessment of clean faces using trained Tanzania staff who represent a variety of educational backgrounds. As long as training is provided, the estimate of clean faces in children should be reliable, and reflect the effort of families to keep ocular and nasal discharge off the faces. These data suggest assessment of clean faces could be added to trachoma surveys, which already measure environmental improvements, in districts.

Rapid and simple clean-up and derivatizaton procedure for the gas chromatographic determination of acidic drugs in plasma

NARCIS (Netherlands)

Roseboom, H.; Hulshoff, A.

1979-01-01

A rapid and simple clean-up and derivatization procedure that can be generally applied to the gas chromatographie (GC) determination of acidic drugs of various chemical and therapeutic classes is described. The drugs are extracted from acidified plasma with chloroform containing 5% of isopropanol,

Supersonic CO electric-discharge lasers

Science.gov (United States)

Hason, R. K.; Mitchner, M.; Stanton, A.

1975-01-01

Laser modeling activity is described which involved addition of an option allowing N2 as a second diatomic gas. This option is now operational and a few test cases involving N2/CO mixtures were run. Results from these initial test cases are summarized. In the laboratory, a CW double-discharge test facility was constructed and tested. Features include: water-cooled removable electrodes, O-ring construction to facilitate cleaning and design modifications, increased discharge length, and addition of a post-discharge observation section. Preliminary tests with this facility using N2 yielded higher power loadings than obtained in the first-generation facility. Another test-section modification, recently made and as yet untested, will permit injection of secondary gases into the cathode boundary layer. The objective will be to vary and enhance the UV emission spectrum from the auxiliary discharge, thereby influencing the level of photoionization in the main discharge region.

Oxalate Mass Balance During Chemical Cleaning in Tank 5F

Energy Technology Data Exchange (ETDEWEB)

Poirier, M.; Fink, S.

2011-07-08

The Savannah River Site (SRS) is preparing Tank 5F for closure. The first step in preparing the tank for closure is mechanical sludge removal. Following mechanical sludge removal, SRS performed chemical cleaning with oxalic acid to remove the sludge heel. Personnel are currently assessing the effectiveness of the chemical cleaning to determine whether the tank is ready for closure. SRS personnel collected liquid samples during chemical cleaning and submitted them to Savannah River National Laboratory (SRNL) for analysis. Following chemical cleaning, they collected a solid sample (also known as 'process sample') and submitted it to SRNL for analysis. The authors analyzed these samples to assess the effectiveness of the chemical cleaning process. Analysis of the anions showed the measured oxalate removed from Tank 5F to be approximately 50% of the amount added in the oxalic acid. To close the oxalate mass balance, the author collected solid samples, leached them with nitric acid, and measured the concentration of cations and anions in the leachate.

EPA Enforcement and Compliance History Online: Water Discharge Monitoring Report Data Sets for FY2013

Data.gov (United States)

U.S. Environmental Protection Agency — Integrated Compliance Information System (ICIS) National Pollutant Discharge Elimination System (NPDES) Discharge Monitoring Report (DMR) data sets for Clean Water...

EPA Enforcement and Compliance History Online: Water Discharge Monitoring Report Data Sets for FY2010

Data.gov (United States)

U.S. Environmental Protection Agency — Integrated Compliance Information System (ICIS) National Pollutant Discharge Elimination System (NPDES) Discharge Monitoring Report (DMR) data sets for Clean Water...

EPA Enforcement and Compliance History Online: Water Discharge Monitoring Report Data Sets for FY2015

Data.gov (United States)

U.S. Environmental Protection Agency — Integrated Compliance Information System (ICIS) National Pollutant Discharge Elimination System (NPDES) Discharge Monitoring Report (DMR) data sets for Clean Water...

EPA Enforcement and Compliance History Online: Water Discharge Monitoring Report Data Sets for FY2014

Data.gov (United States)

U.S. Environmental Protection Agency — Integrated Compliance Information System (ICIS) National Pollutant Discharge Elimination System (NPDES) Discharge Monitoring Report (DMR) data sets for Clean Water...

EPA Enforcement and Compliance History Online: Water Discharge Monitoring Report Data Sets for FY2009

Data.gov (United States)

U.S. Environmental Protection Agency — Integrated Compliance Information System (ICIS) National Pollutant Discharge Elimination System (NPDES) Discharge Monitoring Report (DMR) data sets for Clean Water...

EPA Enforcement and Compliance History Online: Water Discharge Monitoring Report Data Sets for FY2016

Data.gov (United States)

U.S. Environmental Protection Agency — Integrated Compliance Information System (ICIS) National Pollutant Discharge Elimination System (NPDES) Discharge Monitoring Report (DMR) data sets for Clean Water...

Sunoco Pipeline, L.P. Clean Water Act Settlement - 2017

Science.gov (United States)

EPA, and the U.S. Department of Justice announced that Sunoco Pipeline, L.P. (Sunoco) has agreed to pay a civil penalty for alleged violation of the Clean Water Act stemming from a 2012 gasoline discharge near Wellington, Ohio.

The problem of auto-discharge in lead-acid batteries; O problema da auto-descarga em baterias chumbo acido

Energy Technology Data Exchange (ETDEWEB)

Avaca, L A; Gonzalez, E R; Tremiliosi Filho, G; Silva, C.C. da; Maezuru, M [Sao Paulo Univ., Sao Carlos, SP (Brazil). Inst. de Fisica e Quimica

1985-12-31

Storage batteries used together with photovoltaic cells in remote locations must have special characteristics to fit the charge and discharge profiles to which they are submitted. Therefore, to avoid over dimensioning of the photovoltaic cells, the batteries must have particularly low self-discharge characteristics. The problem of self-discharge is directly connected to the degree of technological development in the fabrication of the batteries. The self-discharge of the SLI batteries made locally was measured under standardized conditions and the results were correlated with the kinetics of the electrochemical hydrogen evolution reaction on the lead alloys in acid medium. (author). 7 figs., 4 tabs., 11 refs

Ensuring clean air: Developing a clean air strategy for British Columbia

International Nuclear Information System (INIS)

1992-04-01

In 1992, a clean air strategy will be developed to incorporate views of British Columbians on ways to meet goals related to air quality. A discussion paper is presented to provide information to those interested in participation in developing this strategy. The paper gives information on air quality issues important to the province, including local air quality, urban smog, ozone layer depletion, and global climate change. The views and concerns expressed by stakeholders who attended the Clean Air Conference in 1991 are summarized. The process used to develop the clean air strategy is outlined and some outcomes to be anticipated from the strategy are suggested, including policies and priorities for action to ensure clean air. Air pollutants of concern are total reduced sulfur, mainly from pulp mills and gas processing plants; smoke from wood burning; sulfur dioxide from pulp mills and gas plants; hydrogen fluoride from aluminum smelting; ground-level ozone in urban areas; and acid rain. Elements of a clean air strategy include a smoke management policy, management strategies for greenhouse gases and ozone smog, ozone layer protection measures, regional air quality management plans, and long-term planning efforts in energy use, transportation modes, community design, and land use. 12 refs., 14 figs., 2 tabs

Concentration-Discharge Behavior of Contaminants in a Stream Impacted by Acid Mine Drainage

Science.gov (United States)

Shaw, M. E.; Klein, M.; Herndon, E.

2017-12-01

Acid mine drainage (AMD) has severely degraded streams throughout the Appalachian coal region of the United States. AMD occurs when pyrite contained in coal is exposed to water and air during mining activities and oxidized to release high concentrations of sulfate, metals, and acidity into water bodies. Little is known about the concentration-discharge (CQ) relationships of solutes in AMD-impacted streams due to the complicated nature of acid mine drainage systems. For example, streams may receive inputs from multiple sources that include runoff, constructed treatment systems, and abandoned mines that bypass these systems to continue to contaminate the streams. It is important to understand the CQ relationships of contaminants in AMD-impacted streams in order to elucidate contaminant sources and to predict effects on aquatic ecosystems. Here, we study the CQ behaviors of acid and metals in a contaminated watershed in northeastern Ohio where limestone channels have been installed to remediate water draining from a mine pool into the stream. Stream chemistry was measured in samples collected once per day or once per hour during storm events, and stream flow was measured continuously at the watershed outlet. Increases in stream velocity during storm events resulted in an increase in pH (from 3 to 6) that subsequently decreased back to 3 as flow decreased. Additionally, Fe and Mn concentrations in the stream were high during baseflow (7 and 15 mg/L, respectively) and decreased with increasing discharge during storm events. These results indicate that the treatment system is only effective at neutralizing stream acidity and removing metals when water flow through the limestone channel is continuous. We infer that the acidic and metal-rich baseflow derives from upwelling of contaminated groundwater or subsurface flow from a mine pool. Ongoing studies aim to isolate the source of this baseflow contamination and evaluate the geochemical transformations that occur as it

OXALATE MASS BALANCE DURING CHEMICAL CLEANING IN TANK 6F

Energy Technology Data Exchange (ETDEWEB)

Poirier, M.; Fink, S.

2011-07-22

The Savannah River Remediation (SRR) is preparing Tank 6F for closure. The first step in preparing the tank for closure is mechanical sludge removal. Following mechanical sludge removal, SRS performed chemical cleaning with oxalic acid to remove the sludge heel. Personnel are currently assessing the effectiveness of the chemical cleaning to determine whether the tank is ready for closure. SRR personnel collected liquid samples during chemical cleaning and submitted them to Savannah River National Laboratory (SRNL) for analysis. Following chemical cleaning, they collected a solid sample (also known as 'process sample') and submitted it to SRNL for analysis. The authors analyzed these samples to assess the effectiveness of the chemical cleaning process. Analysis of the anions showed the measured oxalate removed from Tank 6F to be approximately 50% of the amount added in the oxalic acid. To close the oxalate mass balance, the author collected solid samples, leached them with nitric acid, and measured the concentration of cations and anions in the leachate. Some conclusions from this work are: (1) Approximately 65% of the oxalate added as oxalic acid was removed with the decanted liquid. (2) Approximately 1% of the oxalate (added to the tank as oxalic acid) formed precipitates with compounds such as nickel, manganese, sodium, and iron (II), and was dissolved with nitric acid. (3) As much as 30% of the oxalate may have decomposed forming carbon dioxide. The balance does not fully account for all the oxalate added. The offset represents the combined uncertainty in the analyses and sampling.

LC-MS/MS determination of tranexamic acid in human plasma after phospholipid clean-up.

Science.gov (United States)

Fabresse, Nicolas; Fall, Fanta; Etting, Isabelle; Devillier, Philippe; Alvarez, Jean-Claude; Grassin-Delyle, Stanislas

2017-07-15

Tranexamic acid is a widely used antifibrinolytic drug but its pharmacology and pharmacokinetics remains poorly understood. Owing to the recent knowledge on phospholipid-induced matrix effects during human plasma analysis, our aim was to develop a liquid chromatography-mass spectrometry method for the quantitation of tranexamic acid after efficient sample clean-up. Sample preparation consisted in phospholipid removal and protein precipitation. Hydrophilic interaction liquid chromatography was used and the detection was achieved with multiple reaction monitoring. The method was validated according to the European Medicine Agency guideline in the range 1.0-1000.0μg/mL. The performance of the method was excellent with a precision in the range 1.2-3.0%, an accuracy between 88.4 and 96.6% and a coefficient of variation of the internal standard-normalized matrix factor below 6.7%. This method is suitable for the quantification of tranexamic acid in the wide range of concentrations observed during clinical studies, with all the advantages related to phospholipid removal. Copyright © 2017 Elsevier B.V. All rights reserved.

Method of cleaning alkaline metal

International Nuclear Information System (INIS)

Kawakami, Yukio; Naito, Kesahiro; Iizawa, Katsuyuki; Nakasuji, Takashi

1981-01-01

Purpose: To prevent scattering of used sodium and aqueous alkaline solution when cleaning used sodium and metallic sodium adhering to equipment with an aqueous alkaline solution. Method: A sodium treating container is filled with an aqueous alkaline solution, and stainless steel gauze is sunk in the container. Equipment to be cleaned such as equipment with sodium adhering to it are retained under the gauze and are thus cleaned. On the other hand, the surface of the aqueous alkaline solution is covered with a fluid paraffin liquid covering material. Thus, the hydrogen produced by the reaction of the sodium and the aqueous alkaline solution will float up, pass through the liquid covering material and be discharged. The sodium will pass through the gauze and float upwardly while reacting with the aqueous alkaline solution in a partic ulate state to the boundary between the aqueous alkaline solution and up to the covering material, and thus the theratment reaction will continue. Thus, the cover material prevents the sodium and the aqueous alkaline solution from scattering. (Kamimura, M.)

Study on out-gassing by baking and glow discharge during wall conditioning of vacuum chamber

International Nuclear Information System (INIS)

Wang Zhiwen; Wei Weixing; Zhao Yuanqing; He Yanhe; Liao Yikui

2007-01-01

The model of out-gassing by baking and glow discharge cleaning (GDC) is set up. The properties of them are studied. Out-gassing by baking is from bulk and it obeys the diffusion equation. Out-gassing of glow discharge cleaning is mainly on surface, it is inducement out-gassing by sputtering. Thus the properties of out-gassing for baking and GDC on the HL-1M tokamak are analyzed. Some empirical formulas are given. (authors)

Investigation of cleaning reagents for calcium chromate spills

International Nuclear Information System (INIS)

Dillard, B.M.

1979-01-01

Cleaning of calcium chromate spills can be a problem due to the insolubility of the material and the corrosiveness of several possible cleaning agents on the stainless steel equipment. Because of OSHA Standards for Cr(VI) exposure, it is necessary to remove spills as efficiently as possible in order to prevent the contaminant from becoming airborne. This study involved the comparison of several possible cleaning agents by studying the solubility of calcium chromate in each reagent. Two general types of reagents for dissolution of calcium chromate were investigated; those which act by conversion of the insoluble calcium chromate to a more soluble salt and to H 2 CrO 4 , and those which appear to act as complexing agents and thereby dissolve the calcium chromate. The most efficient of the reagents investigated was hydrochloric acid. However, even dilute solutions of halide acids destroy passivity of stainless steel causing pitting and stress-corrosion. Acetic acid and nitric acid were somewhat less efficient than hydrochloric acid in dissolving calcium chromate. However, both reagents are noncorrosive with stainless steel, nitric acid tending to favor passivity of the materials. Therefore, it is recommended that dilute solutions of either of these two acids be used for removal of calcium chromate spills in conjunction with mechanical methods that might be necessary, depending on the magnitude of the spill

Investigation of Alternative Approaches for Cleaning Mott Porous Metal Filters

International Nuclear Information System (INIS)

Poirier, M.R.

2003-01-01

The Department of Energy selected Caustic Side Solvent Extraction (CSSX) as the preferred cesium removal technology for Savannah River Site (SRS) waste. As a pretreatment step for the CSSX flowsheet, the incoming salt solution that contains entrained sludge is contacted with monosodium titanate (MST) to adsorb strontium and select actinides. The resulting slurry is filtered to remove the sludge and MST. Filter fouling occurs during this process. At times, personnel can increase the filtrate rate by backpulsing or scouring. At other times, the filtrate rate drops significantly and only chemical cleaning will restore filter performance. The current baseline technology for filter cleaning uses 0.5 M oxalic acid. The Salt Processing Project (SPP) at SRS, through the Tanks Focus Area, requested an evaluation of other cleaning agents to determine their effectiveness at removing trapped sludge and MST solids compared with the baseline oxalic acid method. A review of the technical literature identified compounds that appear effective at dissolving solid compounds. Consultation with the SPP management team, engineering personnel, and researchers led to a selection of oxalic acid, nitric acid, citric acid, and ascorbic acid for testing. Tests used simulated waste and actual waste as follows. Personnel placed simulated or actual SRS High Level Waste sludge and MST in a beaker. They added the selected cleaning agents, stirred the beakers, and collected supernate samples periodically analyzing for dissolved metals

Microwave induced plasma discharge in multi-cell superconducting radio-frequency cavity

International Nuclear Information System (INIS)

Ahmed, Shahid; Mammosser, John D.

2015-01-01

A R&D effort for in situ cleaning of 1.5 GHz Superconducting Radio Frequency (SRF) cavities at room temperature using the plasma processing technique has been initiated at Jefferson Lab. This is a step toward the cleaning of cryomodules installed in the Continuous Electron Beam Accelerator Facility (CEBAF). For this purpose, we have developed an understanding of plasma discharge in a 5-cell CEBAF-type SRF cavity having configurations similar to those in the main accelerator. The focus of this study involves the detailed investigations of developing a plasma discharge inside the cavity volume and avoids the breakdown condition in the vicinity of the ceramic RF window. A plasma discharge of the gas mixture Ar–O 2 (90%:10%) can be established inside the cavity volume by the excitation of a resonant 4π/5 TM 010 -mode driven by a klystron. The absence of any external magnetic field for generating the plasma is suitable for cleaning cavities installed in a complex cryomodule assembly. The procedures developed in these experimental investigations can be applied to any complex cavity structure. Details of these experimental measurements and the observations are discussed in the paper

Microwave induced plasma discharge in multi-cell superconducting radio-frequency cavity

Energy Technology Data Exchange (ETDEWEB)

Ahmed, Shahid, E-mail: shahid.ahmed@ieee.org [BML Munjal University, Gurgaon, Haryana 123413 (India); Mammosser, John D. [Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)

2015-07-15

A R&D effort for in situ cleaning of 1.5 GHz Superconducting Radio Frequency (SRF) cavities at room temperature using the plasma processing technique has been initiated at Jefferson Lab. This is a step toward the cleaning of cryomodules installed in the Continuous Electron Beam Accelerator Facility (CEBAF). For this purpose, we have developed an understanding of plasma discharge in a 5-cell CEBAF-type SRF cavity having configurations similar to those in the main accelerator. The focus of this study involves the detailed investigations of developing a plasma discharge inside the cavity volume and avoids the breakdown condition in the vicinity of the ceramic RF window. A plasma discharge of the gas mixture Ar–O{sub 2} (90%:10%) can be established inside the cavity volume by the excitation of a resonant 4π/5 TM{sub 010}-mode driven by a klystron. The absence of any external magnetic field for generating the plasma is suitable for cleaning cavities installed in a complex cryomodule assembly. The procedures developed in these experimental investigations can be applied to any complex cavity structure. Details of these experimental measurements and the observations are discussed in the paper.

Microwave induced plasma discharge in multi-cell superconducting radio-frequency cavity

Science.gov (United States)

Ahmed, Shahid; Mammosser, John D.

2015-07-01

A R&D effort for in situ cleaning of 1.5 GHz Superconducting Radio Frequency (SRF) cavities at room temperature using the plasma processing technique has been initiated at Jefferson Lab. This is a step toward the cleaning of cryomodules installed in the Continuous Electron Beam Accelerator Facility (CEBAF). For this purpose, we have developed an understanding of plasma discharge in a 5-cell CEBAF-type SRF cavity having configurations similar to those in the main accelerator. The focus of this study involves the detailed investigations of developing a plasma discharge inside the cavity volume and avoids the breakdown condition in the vicinity of the ceramic RF window. A plasma discharge of the gas mixture Ar-O2 (90%:10%) can be established inside the cavity volume by the excitation of a resonant 4π/5 TM010-mode driven by a klystron. The absence of any external magnetic field for generating the plasma is suitable for cleaning cavities installed in a complex cryomodule assembly. The procedures developed in these experimental investigations can be applied to any complex cavity structure. Details of these experimental measurements and the observations are discussed in the paper.

Microwave induced plasma discharge in multi-cell superconducting radio-frequency cavity.

Science.gov (United States)

Ahmed, Shahid; Mammosser, John D

2015-07-01

A R&D effort for in situ cleaning of 1.5 GHz Superconducting Radio Frequency (SRF) cavities at room temperature using the plasma processing technique has been initiated at Jefferson Lab. This is a step toward the cleaning of cryomodules installed in the Continuous Electron Beam Accelerator Facility (CEBAF). For this purpose, we have developed an understanding of plasma discharge in a 5-cell CEBAF-type SRF cavity having configurations similar to those in the main accelerator. The focus of this study involves the detailed investigations of developing a plasma discharge inside the cavity volume and avoids the breakdown condition in the vicinity of the ceramic RF window. A plasma discharge of the gas mixture Ar-O2 (90%:10%) can be established inside the cavity volume by the excitation of a resonant 4π/5 TM010-mode driven by a klystron. The absence of any external magnetic field for generating the plasma is suitable for cleaning cavities installed in a complex cryomodule assembly. The procedures developed in these experimental investigations can be applied to any complex cavity structure. Details of these experimental measurements and the observations are discussed in the paper.

Unexpected 226Ra build-up in wet-process phosphoric-acid plants

International Nuclear Information System (INIS)

Lardinoye, M.H.; Weterings, K.; Berg, W.B. van de

1982-01-01

During an investigation of the distribution of radium and uranium over the different process streams in phosphoric-acid production and in the nitrophosphate route, a higher than average radiation level was detected in the vicinity of some piping and vessels near the gypsum filters. This higher radiation level is caused by radium which is present in very low concentrations in the phosphates used for fertilizer production. Detectable radiation levels around vessels and piping in other phosphoric-acid works have since been determined. In all factories the filter part and especially the washing-acid section showed the highest radiation level. In the piping of the gypsum filter, through which the washing acid is discharged, a scaling of barium sulphate and calcium sulphate with a higher radium concentration is formed. The radium ions appeared to be incorporated in the barium sulphate lattice, hence the solubility of the radium precipitate is very low. The danger of internal contamination in cleaning operations by radioactive intake or inhalation of radon is very small in the cases described. The risk of external radiation can be prevented by periodically cleaning the equipment in which the radioactive scaling is formed. (author)

76 FR 15998 - Notice of Lodging of Consent Decree Under the Clean Water Act

Science.gov (United States)

2011-03-22

..., treatment plant, and landfill. To address two mines with discharges into the Ohio River Basin, Defendants... DEPARTMENT OF JUSTICE Notice of Lodging of Consent Decree Under the Clean Water Act Notice is..., Defendants will perform injunctive relief with two components. To address four mines with discharges into the...

Savannah River Site Tank Cleaning: Corrosion Rate For One Versus Eight Percent Oxalic Acid Solution

International Nuclear Information System (INIS)

Ketusky, E.; Subramanian, K.

2011-01-01

Until recently, the use of oxalic acid for chemically cleaning the Savannah River Site (SRS) radioactive waste tanks focused on using concentrated 4 and 8-wt% solutions. Recent testing and research on applicable dissolution mechanisms have concluded that under appropriate conditions, dilute solutions of oxalic acid (i.e., 1-wt%) may be more effective. Based on the need to maximize cleaning effectiveness, coupled with the need to minimize downstream impacts, SRS is now developing plans for using a 1-wt% oxalic acid solution. A technology gap associated with using a 1-wt% oxalic acid solution was a dearth of suitable corrosion data. Assuming oxalic acid's passivation of carbon steel was proportional to the free oxalate concentration, the general corrosion rate (CR) from a 1-wt% solution may not be bound by those from 8-wt%. Therefore, after developing the test strategy and plan, the corrosion testing was performed. Starting with the envisioned process specific baseline solvent, a 1-wt% oxalic acid solution, with sludge (limited to Purex type sludge-simulant for this initial effort) at 75 C and agitated, the corrosion rate (CR) was determined from the measured weight loss of the exposed coupon. Environmental variations tested were: (a) Inclusion of sludge in the test vessel or assuming a pure oxalic acid solution; (b) acid solution temperature maintained at 75 or 45 C; and (c) agitation of the acid solution or stagnant. Application of select electrochemical testing (EC) explored the impact of each variation on the passivation mechanisms and confirmed the CR. The 1-wt% results were then compared to those from the 8-wt%. The immersion coupons showed that the maximum time averaged CR for a 1-wt% solution with sludge was less than 25-mils/yr for all conditions. For an agitated 8-wt% solution with sludge, the maximum time averaged CR was about 30-mils/yr at 50 C, and 86-mils/yr at 75 C. Both the 1-wt% and the 8-wt% testing demonstrated that if the sludge was removed from

The Clean Air Act

International Nuclear Information System (INIS)

Coburn, L.L.

1990-01-01

The Clean Air Act amendments alter the complex laws affecting atmospheric pollution and at the same time have broad implications for energy. Specifically, the Clean Air Act amendments for the first time deal with the environmental problem of acid deposition in a way that minimizes energy and economic impacts. By relying upon a market-based system of emission trading, a least cost solution will be used to reduce sulfur dioxide (SO 2 ) emissions by almost 40 percent. The emission trading system is the centerpiece of the Clean Air Act (CAA) amendments effort to resolve energy and environmental interactions in a manner that will maximize environmental solutions while minimizing energy impacts. This paper will explore how the present CAA amendments deal with the emission trading system and the likely impact of the emission trading system and the CAA amendments upon the electric power industry

Alternative Enhanced Chemical Cleaning Basic Studies Results FY09

Energy Technology Data Exchange (ETDEWEB)

Hay, M.; King, W.

2010-05-05

Due to the need to close waste storage tanks, chemical cleaning methods are needed for the effective removal of the heels. Oxalic acid is the preferred cleaning reagent for sludge heel dissolution, particularly for iron-based sludge, due to the strong complexing strength of the oxalate. However, the large quantity of oxalate added to the tank farm from oxalic acid based chemical cleaning has significant downstream impacts. Optimization of the oxalic acid cleaning process can potentially reduce the downstream impacts from chemical cleaning. To optimize oxalic acid usage, a detailed understanding of the chemistry of oxalic acid based sludge dissolution is required. Additionally, other acid systems may be required for specific waste components with low solubility in oxalic acid and as a means to reduce oxalic acid usage in general. Solubility tests were conducted using non-radioactive, pure metal phases known to be the primary phases present in High Level Waste sludge. The metal phases studied included the aluminum phases gibbsite and boehmite and the iron phases magnetite and hematite. Hematite and boehmite are expected to be the most difficult iron and aluminum phases to dissolve. These mineral phases have been identified in both SRS and Hanford High Level Waste sludge. Acids evaluated for dissolution included oxalic, nitric, and sulfuric acids. The results of the solubility tests indicate that oxalic and sulfuric acids are more effective for the dissolution of the primary sludge phases. For boehmite, elevated temperature will be required to promote effective phase dissolution in the acids studied. Literature reviews, thermodynamic modeling, and experimental results have all confirmed that pH control using a supplemental proton source (additional acid) is critical for minimization of oxalic acid usage during the dissolution of hematite. These results emphasize the importance of pH control in optimizing hematite dissolution in oxalic acid and may explain the somewhat

Alternative Enhanced Chemical Cleaning Basic Studies Results FY09

International Nuclear Information System (INIS)

Hay, M.; King, W.

2010-01-01

Due to the need to close waste storage tanks, chemical cleaning methods are needed for the effective removal of the heels. Oxalic acid is the preferred cleaning reagent for sludge heel dissolution, particularly for iron-based sludge, due to the strong complexing strength of the oxalate. However, the large quantity of oxalate added to the tank farm from oxalic acid based chemical cleaning has significant downstream impacts. Optimization of the oxalic acid cleaning process can potentially reduce the downstream impacts from chemical cleaning. To optimize oxalic acid usage, a detailed understanding of the chemistry of oxalic acid based sludge dissolution is required. Additionally, other acid systems may be required for specific waste components with low solubility in oxalic acid and as a means to reduce oxalic acid usage in general. Solubility tests were conducted using non-radioactive, pure metal phases known to be the primary phases present in High Level Waste sludge. The metal phases studied included the aluminum phases gibbsite and boehmite and the iron phases magnetite and hematite. Hematite and boehmite are expected to be the most difficult iron and aluminum phases to dissolve. These mineral phases have been identified in both SRS and Hanford High Level Waste sludge. Acids evaluated for dissolution included oxalic, nitric, and sulfuric acids. The results of the solubility tests indicate that oxalic and sulfuric acids are more effective for the dissolution of the primary sludge phases. For boehmite, elevated temperature will be required to promote effective phase dissolution in the acids studied. Literature reviews, thermodynamic modeling, and experimental results have all confirmed that pH control using a supplemental proton source (additional acid) is critical for minimization of oxalic acid usage during the dissolution of hematite. These results emphasize the importance of pH control in optimizing hematite dissolution in oxalic acid and may explain the somewhat

Investigation of Combined High-Frequency and Arc Discharges

International Nuclear Information System (INIS)

Taran, V.S.; Nezovibatko, Yu.N.; Marinin, V.G.; Shvets, O.M.; Ridozub, V.N.; Gasilin, V.V.

2001-01-01

In this paper we analyze experiment with arc and high-frequency (HF) plasma sources carried out in modified devise of the ''Bulat'' type. The HF-sources and combined discharges have attracted considerable attention for surface cleaning and coating. The utilization of such discharges allows decreasing droplet fraction formation and providing better adhesion and microhardness values. The existence of HF-field in plasma allows obtaining either conductive or dielectric coatings and they can be deposited on any substrates. (author)

Unexpected /sup 226/Ra build-up in wet-process phosphoric-acid plants

Energy Technology Data Exchange (ETDEWEB)

Lardinoye, M.H.; Weterings, K. (Stamicarbon B.V., Geleen (Netherlands)); van de Berg, W.B. (Unie van Kunstmestfabrieken, Utrecht (Netherlands))

1982-04-01

During an investigation of the distribution of radium and uranium over the different process streams in phosphoric-acid production and in the nitrophosphate route, a higher than average radiation level was detected in the vicinity of some piping and vessels near the gypsum filters. This higher radiation level is caused by radium which is present in very low concentrations in the phosphates used for fertilizer production. Detectable radiation levels around vessels and piping in other phosphoric-acid works have since been determined. In all factories the filter part and especially the washing-acid section showed the highest radiation level. In the piping of the gypsum filter, through which the washing acid is discharged, a scaling of barium sulphate and calcium sulphate with a higher radium concentration is formed. The radium ions appeared to be incorporated in the barium sulphate lattice, hence the solubility of the radium precipitate is very low. The danger of internal contamination in cleaning operations by radioactive intake or inhalation of radon is very small in the cases described. The risk of external radiation can be prevented by periodically cleaning the equipment in which the radioactive scaling is formed.

Materials and boiler rig testing to support chemical cleaning of once-through AGR boilers

International Nuclear Information System (INIS)

Tice, D.R.; Platts, N.; Raffel, A.S.; Rudge, A.

2002-01-01

An extensive programme of work has been carried out to evaluate two candidate inhibited cleaning solutions for possible implementation on plant, which would be the first chemical clean of an AGR boiler. The two candidate cleaning solutions considered were a Stannine-inhibited citric acid/formic acid mixture (GOM106) and inhibited hydrofluoric acid. Citric acid-based cleaning processes are widely used within the UK Power Industry. The GOM106 solution, comprising a mixture of 3% citric acid, 0.5% formic acid and 0.05% Stannine LTP inhibitor, buffered with ammonia to pH 3.5, was developed specifically for the AGR boilers during the 1970's. Although a considerable amount of materials testing work was carried out by British Energy's predecessor companies to produce a recommended cleaning procedure there were some remaining concerns with the use of GOM106, from these earlier studies, for example, an increased risk of pitting attack associated with the removal of thick 9Cr oxide deposits and a risk of unacceptable damage in critical locations such as the upper transition joints and other weld locations. Hence, additional testing was still required to validate the solution for use on plant. Inhibited hydrofluoric acid (HFA) was also evaluated as an alternative reagent to GOM106. HFA has been used extensively for cleaning mild and low'alloy steel boiler tubes in fossil-fired plant in the UK and elsewhere in Europe and is known to remove oxide quickly. Waste treatment is also easier than for the GOM106 process and some protection against damage to the boiler tube materials is provided by complexing of fluoride with ferric ion. Validation of the potential reagents and inhibitors was achieved by assessing the rate and effectiveness of oxide removal from specimens of helical boiler tubing and welds, together with establishing the extent of any metal loss or localised damage. The initial materials testing resulted in the inhibited ammoniated citric / formic acid reagent being

Clean Coal Day '94 Hokkaido International Seminar; Clean coal day '94 Hokkaido kokusai seminar

Energy Technology Data Exchange (ETDEWEB)

NONE

1994-06-01

The lectures given at the seminar were 1) Coal energy be friendly toward the earth, 2) Clean coal technology in the United Kingdom, and 3) How clean coal should be in Australia. In lecture 1), remarks are made on the importance of coal and its future, coal that protects forest, whether coal is a dirty fuel, coal combustion tests started relative to environmental pollution, acid rain in China and coal combustion, briquets effective in energy conservation, etc. In lecture 2), remarks are made on the importance of coal utilization in the United Kingdom, current state of coal utilization in power generation, problems related to gasification furnaces, problems related to combustors, problems related to high-temperature gas cleaning, function of cleaning filters, advantages of high-temperature gas treatment, actualities of gas combustors, studies of gas combustors, etc. In lecture 3), remarks are made on Australia's coal situation, problems related to clean coal technology, problems related to coal preparation technology, potentialities of Australian brown coal, coal utilization in power generation, need of new technology development, current state of coal utilization in Australia, coal utilization in metal-making industry, international cooperation on technology, etc. (NEDO)

Comparison of Sterile and Clean Dressing Techniques in Post ...

African Journals Online (AJOL)

Pharmacotherapy Group, Faculty of Pharmacy, University of Benin, Benin City, ... Chinese hospital, and to compare their impact on wound healing and the cost of the ... up to the time of their discharge. Results: Twelve (18.5 %) patients out of those who received sterile or clean .... identified using automated means [13,14].

Process for cleaning radioactively contaminated metal surfaces

International Nuclear Information System (INIS)

Mihram, R.G.; Snyder, G.A.

1975-01-01

A process is described for removing radioactive scale from a ferrous metal surface, including the steps of initially preconditioning the surface by contacting it with an oxidizing solution (such as an aqueous solution of an alkali metal permanganate or hydrogen peroxide), then, after removal or decomposition of the oxidizing solution, the metallic surface is contacted with a cleaning solution which is a mixture of a mineral acid and a complexing agent (such as sulfuric acid and oxalic acid), and which preferably contains a corrosion inhibitor. A final step in the process is the treatment of the spent cleaning solution containing radioactive waste materials in solution by adding a reagent selected from the group consisting of calcium hydroxide or potassium permanganate and an alkali metal hydroxide to thereby form easily recovered metallic compounds containing substantially all of the dissolved metals and radioactivity. (auth)

Biodiesel production using fatty acids from food industry waste using corona discharge plasma technology.

Science.gov (United States)

Cubas, A L V; Machado, M M; Pinto, C R S C; Moecke, E H S; Dutra, A R A

2016-01-01

This article aims to describe an alternative and innovative methodology to transform waste, frying oil in a potential energy source, the biodiesel. The biodiesel was produced from fatty acids, using a waste product of the food industry as the raw material. The methodology to be described is the corona discharge plasma technology, which offers advantages such as acceleration of the esterification reaction, easy separation of the biodiesel and the elimination of waste generation. The best conditions were found to be an oil/methanol molar ratio of 6:1, ambient temperature (25 °C) and reaction time of 110 min and 30 mL of sample. The acid value indicates the content of free fatty acids in the biodiesel and the value obtained in this study was 0.43 mg KOH/g. Peaks corresponding to octadecadienoic acid methyl ester, octadecanoic acid methyl ester and octadecenoic acid methyl ester, from the biodiesel composition, were identified using GC-MS. A major advantage of this process is that the methyl ester can be obtained in the absence of chemical catalysts and without the formation of the co-product (glycerin). Copyright © 2015 Elsevier Ltd. All rights reserved.

Silvering substrates after CO2 snow cleaning

Science.gov (United States)

Zito, Richard R.

2005-09-01

There have been some questions in the astronomical community concerning the quality of silver coatings deposited on substrates that have been cleaned with carbon dioxide snow. These questions center around the possible existence of carbonate ions left behind on the substrate by CO2. Such carbonate ions could react with deposited silver to produce insoluble silver carbonate, thereby reducing film adhesion and reflectivity. Carbonate ions could be produced from CO2 via the following mechanism. First, during CO2 snow cleaning, a small amount of moisture can condense on a surface. This is especially true if the jet of CO2 is allowed to dwell on one spot. CO2 gas can dissolve in this moisture, producing carbonic acid, which can undergo two acid dissociations to form carbonate ions. In reality, it is highly unlikely that charged carbonate ions will remain stable on a substrate for very long. As condensed water evaporates, Le Chatelier's principle will shift the equilibrium of the chain of reactions that produced carbonate back to CO2 gas. Furthermore, the hydration of CO2 reaction of CO2 with H20) is an extremely slow process, and the total dehydrogenation of carbonic acid is not favored. Living tissues that must carry out the equilibration of carbonic acid and CO2 use the enzyme carbonic anhydrase to speed up the reaction by a factor of one million. But no such enzymatic action is present on a clean mirror substrate. In short, the worst case analysis presented below shows that the ratio of silver atoms to carbonate radicals must be at least 500 million to one. The results of chemical tests presented here support this view. Furthermore, film lift-off tests, also presented in this report, show that silver film adhesion to fused silica substrates is actually enhanced by CO2 snow cleaning.

Chemical cleaning and decontamination of equipments in Rajasthan Atomic Power Station-2, Kota, NPCIL

International Nuclear Information System (INIS)

Pal, P.K.; Saini, S.L.

2008-01-01

Heat exchanger of End Shield Cooling System of RAPS-2 made up of 70:30 cupronickel was cleaned with a cleaning solution containing 5% sulphamic acid for periods of around 10 hours at a temperature of 60 deg C. The cleaning was attempted to remove the deposit inside the tube of heat exchanger to make a path of the probe to go inside the tube for eddy current testing for measurement of wall thinning. During the campaign 20 kg of CaCO 3 and 5 kg of SiO 2 were removed. Pre-cooler of heat transport system of RAPS-2 made up of monel was cleaned with a cleaning solution containing 5% citric acid, 1% ascorbic acid and 1% NTA at 50-60 deg C temperature for about 20 hours. The cleaning was attempted to remove the deposit inside the tube of pre cooler to make a path of the probe to go inside the tube for eddy current testing for measurement of wall thinning. For the pre-cooler a decontamination factor of 2 to 3 was obtained. The paper describes about the analysis of the deposit, the cleaning process, and schematic diagram of the process. (author)

Uranium pollution in an estuary affected by pyrite acid mine drainage and releases of naturally occurring radioactive materials

International Nuclear Information System (INIS)

Villa, M.; Manjon, G.; Hurtado, S.; Garcia-Tenorio, R.

2011-01-01

Highlights: → Huelva estuary is affected by former phosphogypsum releases and pyrite acid mine drainage. → Time evolution of uranium concentration is analyzed after halting of NORM releases. → Two new contamination sources are preventing the complete uranium cleaning: (1) The leaching of phosphogypsum stacks located close to Tinto River. (2) Pyrite acid mine drainage. → High uranium concentrations are dissolved in water and precipitate subsequently. - Abstract: After the termination of phosphogypsum discharges to the Huelva estuary (SW Spain), a unique opportunity was presented to study the response of a contaminated environmental compartment after the cessation of its main source of pollution. The evolution over time of uranium concentrations in the estuary is presented to supply new insights into the decontamination of a scenario affected by Naturally Occurring Radioactive Material (NORM) discharges. The cleaning of uranium isotopes from the area has not taken place as rapidly as expected due to leaching from phosphogypsum stacks. An in-depth study using various techniques of analysis, including 234 U/ 238 U and 230 Th/ 232 Th ratios and the decreasing rates of the uranium concentration, enabled a second source of uranium contamination to be discovered. Increased uranium levels due to acid mine drainage from pyrite mines located in the Iberian Pyrite Belt (SW Spain) prevent complete uranium decontamination and, therefore, result in levels nearly twice those of natural background levels.

Surface cleaning of metal wire by atmospheric pressure plasma

International Nuclear Information System (INIS)

Nakamura, T.; Buttapeng, C.; Furuya, S.; Harada, N.

2009-01-01

In this study, the possible application of atmospheric pressure dielectric barrier discharge plasma for the annealing of metallic wire is examined and presented. The main purpose of the current study is to examine the surface cleaning effect for a cylindrical object by atmospheric pressure plasma. The experimental setup consists of a gas tank, plasma reactor, and power supply with control panel. The gas assists in the generation of plasma. Copper wire was used as an experimental cylindrical object. This copper wire was irradiated with the plasma, and the cleaning effect was confirmed. The result showed that it is possible to remove the tarnish which exists on the copper wire surface. The experiment reveals that atmospheric pressure plasma is usable for the surface cleaning of metal wire. However, it is necessary to examine the method for preventing oxidization of the copper wire.

Aquifer restoration system improvement using an acid fluid purge

International Nuclear Information System (INIS)

Hodder, E.A.; Peck, C.A.

1992-01-01

The implementation of a water pump acid purge procedure at a free-phase liquid hydrocarbon recovery site has increased water pump operational run times and improved the effectiveness of the aquifer restoration effort. Before introduction of this technique, pumps at some locations would fail within 14 days of operation due to CaSO 4 .2H 2 O (calcium sulfate) precipitate fouling. After acid purge implementation at these locations, pump operational life improved to an average of over 110 days. Other locations, where pump failures would occur within one month, were improved to approximately six months of operation. The increase in water pump run time has also improved the liquid hydrocarbon recovery rate by 2,000 gallons per day; representing a 20% increase for the aquifer restoration system. Other concepts tested in attempts to prolong pump life included: specially designed electric submersible pumps, submersible pump shrouds intended to reduce the fluid pressure shear that enhances CaSO 4 .2H 2 O precipitation, and high volume pneumatic gas lift pumps. Due to marginal pump life improvement or other undesirable operational features, these concepts were primarily ineffective. The purge apparatus utilizes an acid pump, hose, and discharge piping to deliver the solution directly into the inlet of an operating water pump. The water pumps used for this activity require stainless steel construction with Teflon or other acid resistant bearings and seals. Purges are typically conducted before sudden discharge pressure drops (greater than 15 psig) occur for the operating water pump. Depending on volume of precipitate accumulation and pump type, discharge pressure is restored after introduction of 10 to 40 gallons of hydrochloric acid solution. The acid purge procedure outlined herein eliminates operational downtime and does not require well head pump removal and the associated costs of industry cleaning procedures

Atmospheric discharges from nuclear facilities during decommissioning: German experiences

Energy Technology Data Exchange (ETDEWEB)

Braun, H.; Goertz, R.; Weil, L.

1997-08-01

In Germany, a substantial amount of experience is available with planning, licensing and realization of decommissioning projects. In total, a number of 18 nuclear power plants including prototype facilities as well as 6 research reactors and 3 fuel cycle facilities have been shut down finally and are at different stages of decommissioning. Only recently the final {open_quotes}green field{close_quotes} stage of the Niederaichbach Nuclear Power Plant total dismantlement project has been achieved. From the regulatory point of view, a survey of the decommissioning experience in Germany is presented highlighting the aspects of production and retention of airborne radioactivity. Nuclear air cleaning technology, discharge limits prescribed in licences and actual discharges are presented. As compared to operation, the composition of the discharged radioactivity is different as well as the off-gas discharge rate. In practically all cases, there is no significant amount of short-lived radionuclides. The discussion further includes lessons learned, for example inadvertent discharges of radionuclides expected not to be in the plants inventory. It is demonstrated that, as for operation of nuclear power plants, the limits prescribed in the Ordinance on Radiological Protection can be met using existing air cleaning technology, Optimization of protection results in public exposures substantially below the limits. In the frame of the regulatory investigation programme a study has been conducted to assess the airborne radioactivity created during certain decommissioning activities like decontamination, segmentation and handling of contaminated or activated parts. The essential results of this study are presented, which are supposed to support planning for decommissioning, for LWRs, Co-60 and Cs-137 are expected to be the dominant radionuclides in airborne discharges. 18 refs., 2 figs., 1 tab.

Clean Air Act amendments of 1991: Detailed summary of titles

International Nuclear Information System (INIS)

1990-01-01

;Contents: Provisions for Attainment and Maintenance of National Ambient Air Quality Standards; Provisions Relating to Mobile Sources; Hazardous Air Pollutants; Acid Deposition Control; Permits; Stratospheric Ozone Protection; Provisions Relating to Enforcement; Miscellaneous Provisions; Clean Air Research; Disadvantaged Business Concerns; Clean Air Employment Transition Assistance

Preliminary fluid channel design and thermal-hydraulic analysis of glow discharge cleaning permanent electrode

Energy Technology Data Exchange (ETDEWEB)

Cai, Lijun, E-mail: cailj@swip.ac.cn [Southwestern Institute of Physics, Chengdu (China); Lin, Tao; Wang, Yingqiao; Wang, Mingxu [Southwestern Institute of Physics, Chengdu (China); Maruyama, So; Yang, Yu; Kiss, Gabor [ITER Organization, Route de Vinon-sur-Verdon, CS 90 046, 13067 St. Paul Lez Durance Cedex (France)

2016-11-01

Highlights: • The plasma facing closure cap has to survive after 30,000 thermal heat load cycles. • 0.35 MW/m2 radiation heat load plus nuclear heat load are very challenging for stainless steel. • Multilayer structure has been designed by using advanced welding and drilling technology to solve the neutron heating problem. • Accurate volumetric load application in analysis model by CFX has been mastered. - Abstract: Glow discharge cleaning (GDC) shall be used on ITER device to reduce and control impurity and hydrogenic fuel out-gassing from in-vessel plasma facing components. After first plasma, permanent electrode (PE) will be used to replace Temporary Electrode (TE) for subsequent operation. Two fundamental scenarios i.e., GDC and Plasma Operation State (POS) should be considered for electrode design, which requires the heat load caused by plasma radiation and neutron heating must be taken away by cooling water flowing inside the electrode. In this paper, multilayer cooling channels inside PE are preliminarily designed, and snakelike route in each layer is adopted to improve the heat exchange. Detailed thermal-hydraulic analyses have been done to validate the design feasibility or rationality. The analysis results show that during GDC the cooling water inlet and outlet temperature difference is far less than the allowable temperature rise under water flow rate 0.15 kg/s compromised by many factors. For POS, the temperature rise and pressure drop are within the design goals, but high thermal stress occurs on the front surface of closure cap of electrode. After several iterations of optimization of the closure cap, the equivalent strain range after 30,000 loading cycles for POS is well below 0.3% design goals.

Studies of reaction difference between γ-ray and glow discharge on hydrogenation of unsaturated fatty acid esters

International Nuclear Information System (INIS)

Sakoda, Tatsuya; Nieda, Hiroshi; Kitahara, Kazuta; Ando, Kiyomi

2000-01-01

Hydrogenation of unsaturated fatty acid esters using an inductively coupled plasma at low pressure was performed, and electron temperature and density were measured using a double-probe in order to investigate the reaction difference between γ-ray and glow discharge on hydrogenation. In this experiment, unsaturated fatty acid esters were partly hydrogenated by the hydrogen plasma that had electron temperature of 3.5 eV, which was more efficient than γ-ray irradiation method. As a result, it was found that the plasma can effectively supply electrons that had the optimum energy for hydrogenation at the interface of fatty acids as well as excited atoms and ions. Also, the plasma generated at low pressure would be possible to convert unsaturated fatty acids into saturated fatty acids without breaking the starting monomer. (author)

Response of lead-acid batteries to chopper-controlled discharge

Science.gov (United States)

Cataldo, R. L.

1978-01-01

The preliminary results of simulated electric vehicle, chopper, speed controller discharge of a battery show energy output losses at up to 25 percent compared to constant current discharges at the same average discharge current of 100 A. These energy losses are manifested as temperature rises during discharge, amounting to a two-fold increase for a 400-A pulse compared to the constant current case. Because of the potentially large energy inefficiency, the results suggest that electric vehicle battery/speed controller interaction must be carefully considered in vehicle design.

78 FR 58986 - Dry Cargo Residue Discharges in the Great Lakes

Science.gov (United States)

2013-09-25

...), U.S. Department of Transportation, West Building Ground Floor, Room W12-140, 1200 New Jersey Avenue... impacts would be included through a prohibition of limestone and clean stone DCR discharges within 3...

Recent results on cleaning and conditioning the ATF vacuum system

International Nuclear Information System (INIS)

Langley, R.A.; Clark, T.L.; Glowienka, J.C.; Goulding, R.H.; Mioduszewski, P.K.; Rasmussen, D.A.; Rayburn, T.F.; Schaich, C.R.; Shepard, T.D.; Simpkins, J.E.; Yarber, J.L.

1990-01-01

Techniques for cleaning and conditioning the vacuum vessel of the Advanced Toroidal Facility (ATF) and its internal components are described. The vacuum vessel cleaning technique combines baking to 150 degree C and glow discharges with hydrogen gas. Chromium gettering is used to further condition the system. The major internal components are the anodized aluminum baffles in the Thomson scattering system, a graphite-shielded ICRF antenna, two graphite limiters, and a diagnostic graphite plate. Three independent heating systems are used to bake some of the major components of the system. The major characteristics used for assessing cleanliness and conditioning progress are the maximum pressure attained during bakeout, the results of gas analysis, and revelant plasma parameters (e.g., time to radiative decay). Details of the various cleaning and conditioning procedures and results are presented

Vessel Sewage Discharges: Statutes, Regulations, and Related Laws and Treaties

Science.gov (United States)

Vessel sewage discharges can be regulated under multiple statutes, regulations, and laws/treaties, including the Clean Water Act, Title XIV, MARPOL Annex IV and the Vessel General Permit. This page describes how these are applied to vessel sewage.

Investigation of effective forensic cleaning methods for bullet and cartridge case samples

Science.gov (United States)

Shuherk, Cassie Marie

Bullet and cartridge case evidence may potentially link weapons and crimes through the comparison of toolmark patterns. This analysis relies on the clarity of the toolmarks and the ability of the examiner to identify patterns on the evidence. These patterns may be distorted by debris such as soil, blood, cyanoacrylate, and construction materials. Despite the potential importance of bullet and cartridge case evidence, few investigations of proper cleaning methods have been conducted. The present study was designed to examine the effects of various cleaning solutions and application methods on copper and brass bullets and cartridge cases. Additionally, this research investigated the efficacy of these cleaning protocols on the common evidence contaminants blood and cyanoacrylate. No cleaning method was found to be universally effective on both contaminant types and nondestructive to the metal surface. Ultrasonication was the most efficient application method employed when used in conjunction with an appropriate cleaning solution. Acetone proved to be safe and successful at removing heavy cyanoacrylate deposits from brass cartridge cases without damaging the metal. Although sulfuric acid removed most of the cyanoacrylate from the brass cartridge case, ultrasonication of the fumed cartridge cases in sulfuric acid caused the nickel-plated primer caps to turn black. Additionally, etching occurred when sulfuric acid was allowed to dry on the cartridge case surface. Citric acid, salt-flour-vinegar paste, TergazymeRTM, and water did not effectively remove the cyanoacrylate from the cartridge cases, but the solutions were safe to use on the brass and sometimes resulted in a shinier surface. Regardless of the cleaning method employed, the bloodstained bullets retained most or all of the underlying brown tarnish. Ultrasonication with sulfuric acid was successful at removing some blood-initiated tarnishing; however, the removal of residues was not complete, making it difficult

Clean Coal Day '94 Hokkaido International Seminar; Clean coal day '94 Hokkaido kokusai seminar

Energy Technology Data Exchange (ETDEWEB)

NONE

1994-06-01

The lectures given at the seminar were 1) Coal energy be friendly toward the earth, 2) Clean coal technology in the United Kingdom, and 3) How clean coal should be in Australia. In lecture 1), remarks are made on the importance of coal and its future, coal that protects forest, whether coal is a dirty fuel, coal combustion tests started relative to environmental pollution, acid rain in China and coal combustion, briquets effective in energy conservation, etc. In lecture 2), remarks are made on the importance of coal utilization in the United Kingdom, current state of coal utilization in power generation, problems related to gasification furnaces, problems related to combustors, problems related to high-temperature gas cleaning, function of cleaning filters, advantages of high-temperature gas treatment, actualities of gas combustors, studies of gas combustors, etc. In lecture 3), remarks are made on Australia's coal situation, problems related to clean coal technology, problems related to coal preparation technology, potentialities of Australian brown coal, coal utilization in power generation, need of new technology development, current state of coal utilization in Australia, coal utilization in metal-making industry, international cooperation on technology, etc. (NEDO)

Determination of regression functions for the charging and discharging processes of valve regulated lead-acid batteries

Directory of Open Access Journals (Sweden)

Vukić Vladimir Đ.

2012-01-01

Full Text Available Following a deep discharge of AGM SVT 300 valve-regulated lead-acid batteries using the ten-hour discharge current, the batteries were charged using variable current. In accordance with the obtained results, exponential and polynomial functions for the approximation of the specified processes were analyzed. The main evaluation instrument for the quality of the implemented approximations was the adjusted coefficient of determination R-2. It was perceived that the battery discharge process might be successfully approximated with both an exponential and the second order polynomial function. On all the occasions analyzed, values of the adjusted coefficient of determination were greater than 0.995. The charging process of the deeply discharged batteries was successfully approximated with the exponential function; the measured values of the adjusted coefficient of determination being nearly 0.95. Apart from the high measured values of the adjusted coefficient of determination, polynomial approximations of the second and third order did not provide satisfactory results regarding the interpolation of the battery charging characteristics. A possibility for a practical implementation of the procured regression functions in uninterruptible power supply systems was described.

ANALYSIS OF SAMPLES FROM TANK 5F CHEMICAL CLEANING

Energy Technology Data Exchange (ETDEWEB)

Poirier, M.; Fink, S.

2011-03-07

The Savannah River Site (SRS) is preparing Tank 5F for closure. The first step in preparing the tank for closure is mechanical sludge removal. Following mechanical sludge removal, SRS performed chemical cleaning with oxalic acid to remove the sludge heel. Personnel are currently assessing the effectiveness of the chemical cleaning. SRS personnel collected liquid samples during chemical cleaning and submitted them to Savannah River National Laboratory (SRNL) for analysis. Following chemical cleaning, they collected a solid sample (also known as 'process sample') and submitted it to SRNL for analysis. The authors analyzed these samples to assess the effectiveness of the chemical cleaning process. The conclusions from this work are: (1) With the exception of iron, the dissolution of sludge components from Tank 5F agreed with results from the actual waste demonstration performed in 2007. The fraction of iron removed from Tank 5F by chemical cleaning was significantly less than the fraction removed in the SRNL demonstrations. The likely cause of this difference is the high pH following the first oxalic acid strike. (2) Most of the sludge mass remaining in the tank is iron and nickel. (3) The remaining sludge contains approximately 26 kg of barium, 37 kg of chromium, and 37 kg of mercury. (4) Most of the radioactivity remaining in the residual material is beta emitters and {sup 90}Sr. (5) The chemical cleaning removed more than {approx} 90% of the uranium isotopes and {sup 137}Cs. (6) The chemical cleaning removed {approx} 70% of the neptunium, {approx} 83% of the {sup 90}Sr, and {approx} 21% of the {sup 60}Co. (7) The chemical cleaning removed less than 10% of the plutonium, americium, and curium isotopes. (8) The chemical cleaning removed more than 90% of the aluminium, calcium, and sodium from the tank. (9) The cleaning operations removed 61% of lithium, 88% of non-radioactive strontium, and 65% of zirconium. The {sup 90}Sr and non-radioactive strontium were

Influence of wet chemical cleaning on quantum efficiency of GaN photocathode

International Nuclear Information System (INIS)

Wang Xiao-Hui; Gao Pin; Wang Hong-Gang; Li Biao; Chang Ben-Kang

2013-01-01

GaN samples 1–3 are cleaned by a 2:2:1 solution of sulfuric acid (98%) to hydrogen peroxide (30%) to de-ionized water; hydrochloric acid (37%); or a 4:1 solution of sulfuric acid (98%) to hydrogen peroxide (30%). The samples are activated by Cs/O after the same annealing process. X-ray photoelectron spectroscopy after the different ways of wet chemical cleaning shows: sample 1 has the largest proportion of Ga, N, and O among the three samples, while its C content is the lowest. After activation the quantum efficiency curves show sample 1 has the best photocathode performance. We think the wet chemical cleaning method is a process which will mainly remove C contamination. (condensed matter: electronic structure, electrical, magnetic, and optical properties)

Contamination spike simulation and measurement in a clean metal vapor laser

International Nuclear Information System (INIS)

Lin, C.E.; Yang, C.Y.

1990-01-01

This paper describes a new method for the generation of contamination-induced voltage spikes in a clean metal vapor laser. The method facilitates the study of the characteristics of this troublesome phenomenon in laser systems. Analysis of these artificially generated dirt spikes shows that the breakdown time of the laser tube is increased when these spike appear. The concept of a Townsend discharge is used to identify the parameter which changes the breakdown time of the discharges. The residual ionization control method is proposed to generate dirt spikes in a clean laser. Experimental results show that a wide range of dirt spike magnitudes can be obtained by using the proposed method. The method provides easy and accurate control of the magnitude of the dirt spike, and the laser tube does not become polluted. Results based on the measurements can be used in actual laser systems to monitor the appearance of dirt spikes and thus avoid the danger of thyratron failure

Influence of sodium carbonate on decomposition of formic acid by pulsed discharge plasma inside bubble in water

Science.gov (United States)

Iwabuchi, Masashi; Takahashi, Katsuyuki; Takaki, Koichi; Satta, Naoya

2016-07-01

The influence of sodium carbonate on the decomposition of formic acid by discharge inside bubbles in water was investigated experimentally. Oxygen or argon gases were injected into the water through a vertically positioned glass tube, in which the high-voltage wire electrode was placed to generate plasmas at low applied voltage. The concentration of formic acid was determined by ion chromatography. In the case of sodium carbonate additive, the pH increased owing to the decomposition of the formic acid. In the case of oxygen injection, the percentage of conversion of formic acid increased with increasing pH because the reaction rate of ozone with formic acid increased with increasing pH. In the case of argon injection, the percentage of conversion was not affected by the pH owing to the high rate loss of hydroxyl radicals.

Performance of lead-acid batteries. Experimental study and discharge process modelling; Desempenho de baterias chumbo-acido. Estudo experimental e modelamento do processo de descarga

Energy Technology Data Exchange (ETDEWEB)

Barreto, G; Bottura, C P [Universidade Estadual de Campinas, SP (Brazil); Oliveira, M G [Universidade Estadual de Campinas, SP (Brazil). Inst. de Quimica

1985-12-31

Commercial lead-acid batteries performance when continuously discharge is valued in this work. The model relating battery capacity and discharge current is confirmed through the analysis of experimental results relating voltage to time for various discharge currents. Such model was determined for the tested batteries and can be interpreted in terms of diffusional limitations and plate passivation. (author). 2 figs., 1 tab., 12 refs

Evaluating The Operation Of Three Air Cleaners Working Individually In A Clean Room

DEFF Research Database (Denmark)

Ardkapan, Siamak Rahimi; Afshari, Alireza; Bergsøe, Niels Christian

2011-01-01

The use of portable air cleaners is becoming increasingly popular in many countries including Denmark. Portable air cleaners are known for not only removing but also generating particles and gases. To clarify this, three air cleaning technologies were evaluated. They were nonthermal plasma......, photochemical air purifier and corona discharge ionizer. The concentrations of ultrafine particles, ozone and total volatile organic compounds were measured both in a duct and in a clean room. It was found that the studied air cleaning technologies increased the ozone level in the clean room and the duct....... The increase of ozone level in the clean room was more than that was measured in the duct. Additionally, it was found that the number of ultrafine particles in the room increased due to the generated ozone. The number of generated particles changed with the season. The study leads to the recommendation...

Fossil fuels. Commercializing clean coal technologies

International Nuclear Information System (INIS)

Fultz, Keith O.; Sprague, John W.; Kirk, Roy J.; Clark, Marcus R. Jr.; Greene, Richard M.; Buncher, Carole S.; Kleigleng, Robert G.; Imbrogno, Frank W.

1989-03-01

Coal, an abundant domestic energy source, provides 25 percent of the nation's energy needs, but its use contributes to various types of pollution, including acid rain. The Department of Energy (DOE) has a Clean Coal Technology (CCT) program whose goal is to expand the use of coal in an environmentally safe manner by contributing to the cost of projects demonstrating the commercial applications of emerging clean coal technologies. Concerned about the implementation of the CCT program, the Chairman, Subcommittee on Energy and Power, House Committee on Energy and Commerce, requested GAO to report on (1) DOE's process of negotiating cooperative agreements with project sponsors, (2) changes DOE has made to the program, (3) the status of funded projects, and (4) the interrelationship between acid rain control proposals and the potential commercialization of clean coal technologies. Under the CCT program, DOE funds up to 50 percent of the cost of financing projects that demonstrate commercial applications of emerging clean coal technologies. DOE has conducted two solicitations for demonstration project proposals and is planning a third solicitation by May 1989. The Congress has appropriated $400 million for the first solicitation, or round one of the program, $575 million for round two, and $575 million for round three, for a total of $1.55 billion. For the round-one solicitation, DOE received 51 proposals from project sponsors. As of December 31, 1988, DOE had funded nine projects and was in the process of negotiating cooperative financial assistance agreements with sponsors of four projects. In September 1988, DOE selected 16 round-two projects from 55 proposals submitted and began the process of negotiating cooperative agreements with the project sponsors. The Congress has debated the need to reduce acid rain-causing emissions associated with fossil fuel combustion. The 100th Congress considered but did not enact about 20 acid rain control bills. On February 9, 1989

Determination of mycophenolic acid in mest products using mixed mode reversed phase-anion exchange clean-up and liquid chromatography-high-resolution mass spectrometry

DEFF Research Database (Denmark)

Sørensen, Louise Marie; Nielsen, Kristian Fog; Jacobsen, Thomas

2008-01-01

A method for determination of mycophenolic acid (MPA) in dry-cured ham, fermented sausage and liver pate is described. MPA was extracted from meat with bicarbonate-acetonitrile, further cleaned-up by mixed mode reversed phase-anion exchange and detected using a LC-MS system with electrospray...

An X-ray photoelectron spectroscopic study of a nitric acid/argon ion cleaned uranium metal surface at elevated temperature

International Nuclear Information System (INIS)

Paul, A.J.; Sherwood, P.M.A.

1987-01-01

X-ray photoelectron spectroscopy has been used to study the surface of uranium metal cleaned by nitric acid treatment and argon ion etching, followed by heating in a high vacuum. The surface is shown to contain UOsub(2-x) species over the entire temperature range studied. Heating to temperatures in the range 400-600 0 C generates a mixture of this oxide, the metal and a carbide and/or oxycarbide species. (author)

Recent results on cleaning and conditioning the ATF vacuum system

International Nuclear Information System (INIS)

Langley, R.A.; Clark, T.L.; Glowienka, J.C.

1989-01-01

Techniques for cleaning and conditioning the vacuum vessel of the Advanced Toroidal Facility (ATF) and its internal components are described. The vacuum vessel cleaning technique combines baking to 150/degree/C and glow discharges with hydrogen gas. Chromium gettering is used to further condition the system. The major internal components are the anodized aluminum baffles in the Thomson scattering system, a graphite-shielded ICRF antenna, two graphite limiters, and a diagnostic graphite plate. Three independent heating systems are used to bake some of the major components of the system. The major characteristics used for assessing cleanliness and conditioning progress are the maximum pressure attained during bakeout, the results of gas analysis, and relevant plasma parameters (e.g., time to radiative decay). Details of the various cleaning and conditioning procedures and results are presented. 5 refs., 8 figs., 3 tabs

Practical Approaches for Assessment of Daily and Post-discharge Room Disinfection in Healthcare Facilities.

Science.gov (United States)

Deshpande, Abhishek; Donskey, Curtis J

2017-09-01

Cleaning and disinfection in healthcare facilities is essential to ensure patient safety. This review examines practical strategies used to assess and improve the effectiveness of daily and post-discharge manual cleaning in healthcare facilities. Effective implementation of cleaning interventions requires objective monitoring of staff performance with regular feedback on performance. Use of fluorescent markers to assess thoroughness of cleaning and measurement of residual ATP can provide rapid and objective feedback to personnel and have been associated with improved cleaning. Direct observation of cleaning and interviews with front-line staff are useful to identify variations and deficiencies in practice that may not be detected by other methods. Although not recommended for routine monitoring, cultures can be helpful for outbreak investigations. Monitoring and feedback can be effective in improving cleaning and disinfection in healthcare facilities. Ongoing commitment within institutions is needed to sustain successful cleaning and disinfection programs.

Protecting integrated circuits from excessive charge accumulation during plasma cleaning of multichip modules

Science.gov (United States)

Rodenbeck, Christopher T; Girardi, Michael

2015-04-21

Internal nodes of a constituent integrated circuit (IC) package of a multichip module (MCM) are protected from excessive charge during plasma cleaning of the MCM. The protected nodes are coupled to an internal common node of the IC package by respectively associated discharge paths. The common node is connected to a bond pad of the IC package. During MCM assembly, and before plasma cleaning, this bond pad receives a wire bond to a ground bond pad on the MCM substrate.

Unexpected 226Ra build-up in wet-process phosphoric-acid plants.

Science.gov (United States)

Lardinoye, M H; Weterings, K; van de Berg, W B

1982-04-01

During an investigation of the distribution of radium and uranium over the different process streams in phosphoric-acid production and in the nitrophosphate route, a higher than average radiation level was detected in the vicinity of some piping and vessels near the gypsum filtres. This higher radiation level is caused by radium, which, as a decay product in the 238U series, is present in very low concentrations (1-50 pCi 226R/g) in the phosphates used for fertilizer production. Specific research later on established that there were detectable radiation levels around vessels and piping in other phosphoric-acid works as well. It turned out that in all factories the filter part, and especially the washing-acid section showed the highest radiation-level. In the piping of the gypsum filter, through which the washing acid is discharged, a scaling of bariumsulphate and calciumsulphate with a higher radiumconcentration (+/- 0.1 Ci/g) is formed. The radium ions appeared to be incorporated in the bariumsulphate lattice, hence the solubility of the radium precipitate is very low. The danger of internal pollution, for example in cleaning operations by radio-active intake or inhallation of radon is very small in the cases described. The risk of external radiation can be prevented by periodically cleaning (every 1-3 yr) the equipment in which the radio-active scaling is formed.

Closure report for CAU 93: Area 6 steam cleaning effluent ponds, Nevada Test Site. Volume 1

International Nuclear Information System (INIS)

1997-12-01

The Steam Cleaning Effluent Ponds (SCEP) waste unit is located in Area 6 at the Nevada Test Site. The SCEPs are evaporation basins formerly used for the disposal of untreated liquid effluent discharged from steam cleaning activities associated with Buildings 6-623 and 6-800. This closure report documents the strategy and analytical results that support the clean closure or closure in place of each of the components within CAU 93. In addition, the report documents all deviations from the approved closure plan and provides rationale for all deviations

Closure report for CAU 93: Area 6 steam cleaning effluent ponds, Nevada Test Site. Volume 2

International Nuclear Information System (INIS)

1997-11-01

The Steam Cleaning Effluent Ponds (SCEP) waste unit is located in Area 6 at the Nevada Test Site. The SCEPs are evaporation basins formerly used for the disposal of untreated liquid effluent discharged from steam cleaning activities associated with Buildings 6-623 and 6-800. This report contains Appendix B which provides all of the laboratory summary data sheets for the Area 6 SCEPs closure activities

Closure report for CAU 93: Area 6 steam cleaning effluent ponds, Nevada Test Site. Volume 2

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-11-01

The Steam Cleaning Effluent Ponds (SCEP) waste unit is located in Area 6 at the Nevada Test Site. The SCEPs are evaporation basins formerly used for the disposal of untreated liquid effluent discharged from steam cleaning activities associated with Buildings 6-623 and 6-800. This report contains Appendix B which provides all of the laboratory summary data sheets for the Area 6 SCEPs closure activities.

Clean Air Markets - Monitoring Surface Water Chemistry

Science.gov (United States)

Learn about how EPA uses Long Term Monitoring (LTM) and Temporily Integrated Monitoring of Ecosystems (TIME) to track the effect of the Clean Air Act Amendments on acidity of surface waters in the eastern U.S.

Failure modes of valve-regulated lead-acid batteries for electric bicycle applications in deep discharge

Energy Technology Data Exchange (ETDEWEB)

Guo, Yonglang; Tang, Shengqun [College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108 (China); Meng, Gang; Yang, Shijun [Hubei Camel Storage Battery Co. Ltd., Gucheng 441705 (China)

2009-06-01

The 36 or 48 V valve-regulated lead-acid (VRLA) battery packs have been widely applied to the power sources of electric bicycles or light electric scooters in China. The failure modes of the 12 V/10 Ah VRLA batteries have been studied by the cycle life test at C{sub 2} discharge rate and 100% depth of discharge (DOD). It indicates that the main cause of the battery failure in this cycle duty is the softening and shedding of positive active mass (PAM) rather than individual water loss, recombination efficiency or sulfation, etc. When the electrolyte saturation falls to a certain extent, the high oxygen recombination current leads to the depolarization of the negative plate and the shift of the positive plate to a higher potential. The violent oxygen evolution accelerates the softening of PAM and the end of cycle life. (author)

Clean coal technology: The new coal era

Energy Technology Data Exchange (ETDEWEB)

1994-01-01

The Clean Coal Technology Program is a government and industry cofunded effort to demonstrate a new generation of innovative coal processes in a series of full-scale showcase`` facilities built across the country. Begun in 1986 and expanded in 1987, the program is expected to finance more than $6.8 billion of projects. Nearly two-thirds of the funding will come from the private sector, well above the 50 percent industry co-funding expected when the program began. The original recommendation for a multi-billion dollar clean coal demonstration program came from the US and Canadian Special Envoys on Acid Rain. In January 1986, Special Envoys Lewis and Davis presented their recommendations. Included was the call for a 5-year, $5-billion program in the US to demonstrate, at commercial scale, innovative clean coal technologies that were beginning to emerge from research programs both in the US and elsewhere in the world. As the Envoys said: if the menu of control options was expanded, and if the new options were significantly cheaper, yet highly efficient, it would be easier to formulate an acid rain control plan that would have broader public appeal.

40 CFR 403.5 - National pretreatment standards: Prohibited discharges.

Science.gov (United States)

2010-07-01

... problems; (8) Any trucked or hauled pollutants, except at discharge points designated by the POTW. (c) When... to respond. (4) POTWs may develop Best Management Practices (BMPs) to implement paragraphs (c)(1) and.... (e) EPA enforcement actions under section 309(f) of the Clean Water Act. If, within 30 days after...

Influence of acid diffusion on the performance of lead-acid cells

Energy Technology Data Exchange (ETDEWEB)

Kappus, W.; Bohmann, J.

1983-11-01

A model for the discharge performance of the lead-acid cell is proposed. Diffusion of acid into the porous electrodes, which is connected with diffusional polarization, is considered as the principal factor in the transport process. The end of discharge is determined either by acid depletion inside the electrodes or by exhaustion of the active material, where utilization of the active material as a function of the acid density and the specific current is determined from empirical expressions. Curves of diffusional polarizations as a function of the discharge time are presented. Calculated discharge capacities show the influence of various parameters such as electrode thickness, current, and acid density. Tubular and pasted plates are considered.

Extending CO2 cryogenic aerosol cleaning for advanced optical and EUV mask cleaning

Science.gov (United States)

Varghese, Ivin; Bowers, Charles W.; Balooch, Mehdi

2011-11-01

Cryogenic CO2 aerosol cleaning being a dry, chemically-inert and residue-free process is used in the production of optical lithography masks. It is an attractive cleaning option for the mask industry to achieve the requirement for removal of all printable soft defects and repair debris down to the 50nm printability specification. In the technique, CO2 clusters are formed by sudden expansion of liquid from high to almost atmospheric pressure through an optimally designed nozzle orifice. They are then directed on to the soft defects or debris for momentum transfer and subsequent damage free removal from the mask substrate. Unlike aggressive acid based wet cleaning, there is no degradation of the mask after processing with CO2, i.e., no critical dimension (CD) change, no transmission/phase losses, or chemical residue that leads to haze formation. Therefore no restriction on number of cleaning cycles is required to be imposed, unlike other cleaning methods. CO2 aerosol cleaning has been implemented for several years as full mask final clean in production environments at several state of the art mask shops. Over the last two years our group reported successful removal of all soft defects without damage to the fragile SRAF features, zero adders (from the cleaning and handling mechanisms) down to a 50nm printability specification. In addition, CO2 aerosol cleaning is being utilized to remove debris from Post-RAVE repair of hard defects in order to achieve the goal of no printable defects. It is expected that CO2 aerosol cleaning can be extended to extreme ultraviolet (EUV) masks. In this paper, we report advances being made in nozzle design qualification for optimum snow properties (size, velocity and flux) using Phase Doppler Anemometry (PDA) technique. In addition the two new areas of focus for CO2 aerosol cleaning i.e. pellicle glue residue removal on optical masks, and ruthenium (Ru) film on EUV masks are presented. Usually, the residue left over after the pellicle

Collective phenomena in volume and surface barrier discharges

Science.gov (United States)

Kogelschatz, U.

2010-11-01

Barrier discharges are increasingly used as a cost-effective configuration to produce non-equilibrium plasmas at atmospheric pressure. This way, copious amounts of electrons, ions, free radicals and excited species can be generated without significant heating of the background gas. In most applications the barrier is made of dielectric material. Major applications utilizing mainly dielectric barriers include ozone generation, surface cleaning and modification, polymer and textile treatment, sterilization, pollution control, CO2 lasers, excimer lamps, plasma display panels (flat TV screens). More recent research efforts are devoted to biomedical applications and to plasma actuators for flow control. Sinusoidal feeding voltages at various frequencies as well as pulsed excitation schemes are used. Volume as well as surface barrier discharges can exist in the form of filamentary, regularly patterned or diffuse, laterally homogeneous discharges. The physical effects leading to collective phenomena in volume and surface barrier discharges are discussed in detail. Special attention is paid to self-organization of current filaments and pattern formation. Major similarities of the two types of barrier discharges are elaborated.

Clean exergy biotechnical complex for recycling carbon dioxide from flue gas stations

International Nuclear Information System (INIS)

Stolyarenko, G.

2013-01-01

A main problem, impedimental to the use of smoke gases as raw material for the production of pure carbon dioxide, is formation at incineration of fuel of such toxic connections as oxide of carbon(II), nitrogen oxides, and benzo (a) pyrene, formaldehyde, vapors of hydrochloric and hydrofluoric acids, toxic metals. Suppressions of formation CO, NO x and other harmful admixtures in smoke gases it is possible to attain on the stage of burning with the use of new technology: electronic catalysis of flame in the discharge zone. Method of heterophasic ozonization minimizes content CO and NO x and other toxic admixtures in smoke gases. Photosynthesis - by converting pure CO 2 into hydrocarbons with the use of solar energy - enables to receive on a commercial scale genetically modified cyano-bacteria (blue-green algae). Oils got from them, a gaseous and diesel fuel during incineration results in the decline of maintenance of toxic connections in smoke gases. Thus achieves the creation of clean energy bio-complex. (author)

Unexpected /sup 226/Ra build-up in wet-process phosphoric-acid plants

Energy Technology Data Exchange (ETDEWEB)

Lardinoye, M.H.; Weterings, K.; van de Berg, W.B.

1982-04-01

During an investigation of the distribution of radium and uranium over the different process streams in phosphoric-acid production and in the nitrophosphate route, a higher than average radiation level was detected in the vicinity of some piping and vessels near the gypsum filtres. This higher radiation level is caused by radium, which, as a decay product in the /sup 238/U series, is present in very low concentrations (1-50 pCi 226R/g) in the phosphates used for fertilizer production. Specific research later on established that there were detectable radiation levels around vessels and piping in other phosphoric-acid works as well. It turned out that in all factories the filter part, and especially the washing-acid section showed the highest radiation-level. In the piping of the gypsum filter, through which the washing acid is discharged, a scaling of bariumsulfate and calciumsulfate with a higher radium concentration (+/- 0.1 Ci/g) is formed. The radium ions appeared to be incorporated in the bariumsulphate lattice, hence the solubility of the radium precipitate is very low. The danger of internal pollution, for example in cleaning operations by radioactive intake or inhalation of radon is very small in the cases described. The risk of external radiation can be prevented by periodically cleaning (every 1-3 yr) the equipment in which the radioactive scaling is formed.

Correlating Cleaning Thoroughness with Effectiveness and Briefly Intervening to Affect Cleaning Outcomes: How Clean Is Cleaned?

Directory of Open Access Journals (Sweden)

Robert Clifford

Full Text Available The most efficient approach to monitoring and improving cleaning outcomes remains unresolved. We sought to extend the findings of a previous study by determining whether cleaning thoroughness (dye removal correlates with cleaning efficacy (absence of molecular or cultivable biomaterial and whether one brief educational intervention improves cleaning outcomes.Before-after trial.Newly built community hospital.90 minute training refresher with surface-specific performance results.Dye removal, measured by fluorescence, and biomaterial removal and acquisition, measured with culture and culture-independent PCR-based assays, were clandestinely assessed for eight consecutive months. At this midpoint, results were presented to the cleaning staff (intervention and assessments continued for another eight consecutive months.1273 surfaces were sampled before and after terminal room cleaning. In the short-term, dye removal increased from 40.3% to 50.0% (not significant. For the entire study period, dye removal also improved but not significantly. After the intervention, the number of rooms testing positive for specific pathogenic species by culturing decreased from 55.6% to 36.6% (not significant, and those testing positive by PCR fell from 80.6% to 53.7% (P = 0.016. For nonspecific biomaterial on surfaces: a removal of cultivable Gram-negatives (GN trended toward improvement (P = 0.056; b removal of any cultivable growth was unchanged but acquisition (detection of biomaterial on post-cleaned surfaces that were contaminant-free before cleaning worsened (P = 0.017; c removal of PCR-based detection of bacterial DNA improved (P = 0.046, but acquisition worsened (P = 0.003; d cleaning thoroughness and efficacy were not correlated.At this facility, a minor intervention or minimally more aggressive cleaning may reduce pathogen-specific contamination, but not without unintended consequences.

Alternative Chemical Cleaning Methods for High Level Waste Tanks: Actual Waste Testing with SRS Tank 5F Sludge

Energy Technology Data Exchange (ETDEWEB)

King, William D. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Hay, Michael S. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2016-08-30

Solubility testing with actual High Level Waste tank sludge has been conducted in order to evaluate several alternative chemical cleaning technologies for the dissolution of sludge residuals remaining in the tanks after the exhaustion of mechanical cleaning and sludge sluicing efforts. Tests were conducted with archived Savannah River Site (SRS) radioactive sludge solids that had been retrieved from Tank 5F in order to determine the effectiveness of an optimized, dilute oxalic/nitric acid cleaning reagent toward dissolving the bulk non-radioactive waste components. Solubility tests were performed by direct sludge contact with the oxalic/nitric acid reagent and with sludge that had been pretreated and acidified with dilute nitric acid. For comparison purposes, separate samples were also contacted with pure, concentrated oxalic acid following current baseline tank chemical cleaning methods. One goal of testing with the optimized reagent was to compare the total amounts of oxalic acid and water required for sludge dissolution using the baseline and optimized cleaning methods. A second objective was to compare the two methods with regard to the dissolution of actinide species known to be drivers for SRS tank closure Performance Assessments (PA). Additionally, solubility tests were conducted with Tank 5 sludge using acidic and caustic permanganate-based methods focused on the “targeted” dissolution of actinide species.

Investigation of cleaning and regeneration methods for reliable construction of DNA cantilever biosensors

DEFF Research Database (Denmark)

Quan, Xueling; Yi, Sun; Heiskanen, Arto

to clean and regenerate the sensing surface of cantilever biosensors. Perchloric acid potential sweep, potassium hydroxide-hydrogen peroxide, and piranha cleaning are investigated here. Peak-current potential differences from cyclic voltammetry, X-ray photo-electron spectroscopy and fluorescence detection...

Optimization of waste water discharge and waste water cleaning on the basis of measurements of the organic pollutant load; Optimierung von Abwasserableitung und Abwasserreinigung durch Messung der organischen Abwasserbelastung

Energy Technology Data Exchange (ETDEWEB)

Haeck, M. [Dr. Bruno Lange GmbH Berlin, Duesseldorf (Germany)

1999-07-01

The spectral absorption coefficient (SAC) is a sum parameter for describing the organic pollutant load of waste water. It is based on a purely physical measuring technique and can be monitored continuously and directly in the medium by means of the described UV process probe. From this arise numerous opportunities for optimizing waste water discharge and cleaning. (orig.) [German] Der spektrale Absorptionskoeffizient (SAK) ist ein Summenparameter zur Beschreibung der organischen Abwasserbelastung. Er basiert auf einem rein physikalischen Messverfahren und kann mit der hier vorgestellten UV-Prozess-Sonde kontinuierlich und direkt im Medium erfasst werden. Daraus ergeben sich zahlreiche Moeglichkeiten zur Optimierung von Abwasserableitung und -reinigung. (orig.)

Optimal sulfur amino acid to lysine ratio for post weaning piglets reared under clean or unclean sanitary conditions

Directory of Open Access Journals (Sweden)

Roselyn Kahindi

2017-12-01

Full Text Available Two 14-day experiments, each with 90 (Duroc × [Yorkshire × Landrace]; 7.3 ± 0.6 kg piglets, were conducted to determine the optimum sulfur amino acid (SAA to lysine (Lys ratio (SAA:Lys for piglets when reared under clean or unclean sanitary conditions using performance and non-performance response criteria. Piglets were randomly assigned to the following dietary treatments. The basal diet contained 1.18% standardized ileal digestible (SID Lys, and the SAA:Lys was 52%. In diets 2 to 5, the basal diet was supplemented with 4 graded levels of dl-Met to make SAA:Lys of 56%, 60%, 64% and 68%. In Exp. 1, piglets were housed in disinfected clean room. In Exp. 2, piglets were housed in a room previously occupied by other pigs and was not disinfected. On the last day, blood was collected to measure plasma urea nitrogen (PUN and one pig per pen was euthanized to collect jejunal tissue to measure villus height (VH, crypt depth (CD, and VH:CD. In Exp. 1, increasing SAA:Lys linearly and quadratically increased VH and VH:CD (P < 0.05. In Exp. 2, increasing SAA:Lys linearly increased (P < 0.05 VH and VH:CD and linearly and quadratically decreased PUN (P < 0.05. Estimated PUN and VH-based optimum SAA:Lys requirements for clean and unclean sanitary condition were 60%, 63% and 66%, respectively.

Microwave Photocatalysis of Mono-Chloroacetic Acid over Nanoporous Titanium(IV) Oxide Thin Films Using Mercury Electrodeless Discharge Lamps

Czech Academy of Sciences Publication Activity Database

Církva, Vladimír; Žabová, Hana; Hájek, Milan

2008-01-01

Roč. 198, č. 1 (2008), s. 13-17 ISSN 1010-6030 R&D Projects: GA ČR GA104/06/0992; GA ČR GA104/07/1212 Institutional research plan: CEZ:AV0Z40720504 Keywords : microwave-assisted photocatalysis * electrodeless discharge lamp * mono-chloroacetic acid Subject RIV: CH - Nuclear ; Quantum Chemistry Impact factor: 2.362, year: 2008

Optimization Analysis on Parameters of Cleaning Sieve of Rape Combine of "Bi Lang 4LZ(Y)-1.0"

OpenAIRE

Wu Mingliang; Tang Lun; Guan Chunyun; Tang Chuzhou

2014-01-01

Against the phenomenon of high impurity rate and cane and pod shell are difficult to discharge at the end of the sieve for rape combine of "Bi Lang 4LZ(Y)-1.0". This study take cleaning sieve of rape combine of "Bi Lang 4LZ(Y)-1.0" as study object, analyzed the movement of materials on sieve, established the virtual prototype model of the cleaning sieve of this rape combine, taken materials and cleaning sieve all at the best motion state as constraint conditions and optimized the structure an...

TORR system polishes oily water clean

International Nuclear Information System (INIS)

Mowers, J.

2002-01-01

The TORR (total oil recovery and remediation) system utilizes a specially patented polymer material, similar to styrofoam, which is used to get rid of non-soluble hydrocarbons from water. An application in Fort Smith, Northwest Territories, is described where it was used to recover diesel oil, which had been seeping into the groundwater over a period of 20 years. About 100,000 gallons of heating oil had leached into the water; TORR removed the non-soluble hydrocarbons, while another piece of equipment removed the soluble portions. After treatment the water tested consistently at non-detectable levels and was clean enough to be discharged into the town's sewer system. The system is considered ideal for oil spills clean-up underground, onshore, or the open sea, but it also has many potentially useful applications in industrial and oilfield applications. Water used in steam injection and water floods to produce heavy oil and SAGD applications are some of the obvious ones that come to mind. Cleaning up the huge tailings ponds at the mining and processing of oil sands, and removing diluent from water that is used to thin out bitumen in pipelines so that it can be transported to processing plants, are other promising areas of application. Several field trials to test the effectiveness of the system in these type of applications are scheduled for the summer and fall of 2002

Cleaning fluid emulsions

Energy Technology Data Exchange (ETDEWEB)

Prikryl, J; Kotyza, R; Krulikovsky, J; Mjartan, V; Valisova, I

1981-09-15

Composition of cleaning fluid emulsion are presented for drilling small diameter wells in clay soils, at high drill bit rotation velocity. The emulsions have lubricating properties and the abilty to improve stability of the drilled soil. The given fluids have a high fatty acid content with 12-24 carbon atoms in a single molecule, with a predominance of resinous acids 1-5% in mass, and having been emulsified in water or clay suspension without additives, or in a clay suspension with high-molecular polymer additives (glycobate cellulose compounds and/or polysaccharides, and/or their derivatives) in an amount of 0.1-3% per mass; thinning agents - huminite or lignite compounds in the amount of 0.01 to 0.5% in mass; weighting material - barite or lime 0.01 to 50% per mass; medium stabilizers - organic poly-electrolyte with polyacrylate in the amount of 0.05 to 2% in mass, or alkaline chloride/alkaline-ground metals 1-10% per mass. A cleaning emulsion fluid was prepared in the laboratory according to the given method. Add 3 kg tall oil to a solution of 1 kg K/sub 2/CO/sub 3/ per 100 l of water. Dynamic viscosity was equal to 1.4 x 10-/sup 3/ Pa/s. When drilling in compacted clay soils, when the emulsions require improved stability, it is necessary to add the maximum amount of tall oil whose molecules are absorbed by the clay soil and increase its durability.

Chemical cleaning of AGR boilers

International Nuclear Information System (INIS)

Moore, S.V.; Moore, W.; Rantell, A.

1978-01-01

AGR boilers are likely to require post service chemical cleaning to remove accumulated oxides at intervals of 15 - 35 kh. The need to clean will be based on an assessment of such factors as the development of flow imbalances through parallel tubes induced by the formation of rough oxide surfaces, an increasing risk of localised corrosion as the growth of porous oxides proceeds and the risk of tube blockage caused by the exfoliation of steam-grown oxides. The study has shown what heterogeneous multilayer oxides possessing a range of physical and chemical properties form on the alloy steels. They include porous and compact magnetites, chromium spinels and sesquioxide. Ammoniated citric acid has been shown to remove deposited and water-grown magnetites from the carbon and alloy steels but will not necessarily remove the substituted spinels grown on the alloy steels or the potentially spalling steam-grown magnetite on the A1SI 316 superheater. Citric acid supplemented with the reducing agent glyoxal completely removes all oxides from the boiler except the protective inner spinel formed on the 316. Removal of the spinels and compact magnetites occurs more by undercutting and physical detachment than by the dissolution. (author)

Evaporation and wet oxidation of steam generator cleaning solutions

International Nuclear Information System (INIS)

Baldwin, P.N. Jr.

1996-01-01

Ethylene diamine tetra acetic acid (EDTA) is used in metal-cleaning formulations. Usually the form of the EDTA used is the tetra ammonium salt. When these powerful cleaning solutions are used in steam generators, they attract the key metals of interest--iron and copper. A reduction in the volume of these cleaners and EDTA destruction is required to meet waste management and disposal standards. One method of volume reduction is described: concentration by evaporation. Once volume is reduced, the liquid waste can then be further volume reduced and treated for EDTA content through the use of wet oxidation. The effect of this process on the total organic carbon (TOC) in the form of EDTA contained in the copper as well as the iron spent cleaning solutions is reviewed, including regression analysis of selected benchmark and production data. A regressive analysis is made of the relationship between the EDTA and the TOC analyzed in the wet-oxidation batch residuals as well as the summary effects of hydrogen peroxide, sulfuric acid, and reaction time on the percentage of TOC destroyed

The influence of acid diffusion on the performance of lead-acid cells

Science.gov (United States)

Kappus, W.; Bohmann, J.

1983-11-01

A model for the discharge performance of the lead-acid cell is proposed. Diffusion of acid into the porous electrodes, which is connected with diffusio Curves of diffusional polarizations as a function of the discharge time are presented. Calculated discharge capacities show the influence of various pa

The effects of different additives in electrolyte of AGM batteries on self-discharge

Energy Technology Data Exchange (ETDEWEB)

Yazd, M. Safari; Molazemi, A. [Department of Chemistry, Faculty of Science, Ferdowsi University of Mashhad, P.O. Box 91775-1111 (Iran); Moayed, M.H. [Metallurgical and Materials Engineering Department, Faculty of Engineering, Ferdowsi University of Mashhad, P.O. Box 91775-1111 (Iran)

2006-07-14

Hydrogen and oxygen evolution at the negative and positive electrodes in AGM batteries are the main reasons of self-discharging. The self-discharge of five AGM batteries was investigated by measuring different potential between two electrodes during 48 days. Five different battery electrolytes were used including 35% (w/w) H{sub 2}SO{sub 4} without additives and the remaining contain 7.1, 9.94, and 21.3gl{sup -1} sodium sulfate, 4gl{sup -1} boric acid, 3gl{sup -1} citric acid, and finally 0.7 and 1gl{sup -1} stearic acid except one containing boric acid that the concentration of H{sub 2}SO{sub 4} was 36% (w/w). The results revealed that the rate of self-discharge for battery without additive was 0.01Vday{sup -1}. The battery with boric acid showed the lowest rate of self-discharge with 0.0025Vday{sup -1}. It was also found that stearic and citric acids are comparatively appropriate additives for decreasing the self-discharge. They caused a decrease of the self-discharge rate to 0.005 and 0.0075Vday{sup -1} on appropriate concentration, respectively. In compared to other additives, sodium sulfate showed to be not an appropriate additive for decreasing battery self-discharging. The rate of 0.03Vday{sup -1} of self-discharging was obtained for the battery containing all selected concentration of sodium sulfate during first 4 days of measuring. (author)

Surface modification of polyvinyl alcohol/malonic acid nanofibers by gaseous dielectric barrier discharge plasma for glucose oxidase immobilization

International Nuclear Information System (INIS)

Afshari, Esmail; Mazinani, Saeedeh; Ranaei-Siadat, Seyed-Omid; Ghomi, Hamid

2016-01-01

Highlights: • We fabricated polyvinyl alcohol/malonic acid nanofibers using electrospinning. • The surface nanofibers were modified by gaseous (air, nitrogen, CO_2 and argon) dielectric barrier discharge. • Among them, air plasma had the most significant effect on glucose oxidase immobilization. • Chemical analysis showed that after modification of nanofibers by air plasma, the carboxyl group increased. • After air plasma treatment, reusability and storage stability of glucose oxidase immobilized on nanofibers improved. - Abstract: Polymeric nanofiber prepares a suitable situation for enzyme immobilization for variety of applications. In this research, we have fabricated polyvinyl alcohol (PVA)/malonic acid nanofibers using electrospinning. After fabrication of nanofibers, the effect of air, nitrogen, CO_2, and argon DBD (dielectric barrier discharge) plasmas on PVA/malonic acid nanofibers were analysed. Among them, air plasma had the most significant effect on glucose oxidase (GOx) immobilization. Attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectrum analysis and X-ray photoelectron spectroscopy (XPS) results revealed that in case of air plasma modified nanofibers, the carboxyl groups on the surface are increased. The scanning electron microscopy (SEM) images showed that, after GOx immobilization, the modified nanofibers with plasma has retained its nanofiber structure. Finally, we analysed reusability and storage stability of GOx immobilized on plasma modified and unmodified nanofibers. The results were more satisfactory for modified nanofibers with respect to unmodified ones.

Surface modification of polyvinyl alcohol/malonic acid nanofibers by gaseous dielectric barrier discharge plasma for glucose oxidase immobilization

Energy Technology Data Exchange (ETDEWEB)

Afshari, Esmail, E-mail: e.afshari@mail.sbu.ac.ir [Laser and Plasma Research Institute, Shahid Beheshti University, Evin, 1983963113 Tehran (Iran, Islamic Republic of); Mazinani, Saeedeh [Amirkabir Nanotechnology Research Institute (ANTRI), Amirkabir University of Technology, 15875-4413, Tehran (Iran, Islamic Republic of); Ranaei-Siadat, Seyed-Omid [Protein Research Center, Shahid Beheshti University, Evin, 1983963113 Tehran (Iran, Islamic Republic of); Ghomi, Hamid [Laser and Plasma Research Institute, Shahid Beheshti University, Evin, 1983963113 Tehran (Iran, Islamic Republic of)

2016-11-01

Highlights: • We fabricated polyvinyl alcohol/malonic acid nanofibers using electrospinning. • The surface nanofibers were modified by gaseous (air, nitrogen, CO{sub 2} and argon) dielectric barrier discharge. • Among them, air plasma had the most significant effect on glucose oxidase immobilization. • Chemical analysis showed that after modification of nanofibers by air plasma, the carboxyl group increased. • After air plasma treatment, reusability and storage stability of glucose oxidase immobilized on nanofibers improved. - Abstract: Polymeric nanofiber prepares a suitable situation for enzyme immobilization for variety of applications. In this research, we have fabricated polyvinyl alcohol (PVA)/malonic acid nanofibers using electrospinning. After fabrication of nanofibers, the effect of air, nitrogen, CO{sub 2}, and argon DBD (dielectric barrier discharge) plasmas on PVA/malonic acid nanofibers were analysed. Among them, air plasma had the most significant effect on glucose oxidase (GOx) immobilization. Attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectrum analysis and X-ray photoelectron spectroscopy (XPS) results revealed that in case of air plasma modified nanofibers, the carboxyl groups on the surface are increased. The scanning electron microscopy (SEM) images showed that, after GOx immobilization, the modified nanofibers with plasma has retained its nanofiber structure. Finally, we analysed reusability and storage stability of GOx immobilized on plasma modified and unmodified nanofibers. The results were more satisfactory for modified nanofibers with respect to unmodified ones.

Annual report, spring 2015. Alternative chemical cleaning methods for high level waste tanks-corrosion test results

Energy Technology Data Exchange (ETDEWEB)

Wyrwas, R. B. [Savannah River Site (SRS), Aiken, SC (United States)

2015-07-06

The testing presented in this report is in support of the investigation of the Alternative Chemical Cleaning program to aid in developing strategies and technologies to chemically clean radioactive High Level Waste tanks prior to tank closure. The data and conclusions presented here were the examination of the corrosion rates of A285 carbon steel and 304L stainless steel when interacted with the chemical cleaning solution composed of 0.18 M nitric acid and 0.5 wt. % oxalic acid. This solution has been proposed as a dissolution solution that would be used to remove the remaining hard heel portion of the sludge in the waste tanks. This solution was combined with the HM and PUREX simulated sludge with dilution ratios that represent the bulk oxalic cleaning process (20:1 ratio, acid solution to simulant) and the cumulative volume associated with multiple acid strikes (50:1 ratio). The testing was conducted over 28 days at 50°C and deployed two methods to invest the corrosion conditions; passive weight loss coupon and an active electrochemical probe were used to collect data on the corrosion rate and material performance. In addition to investigating the chemical cleaning solutions, electrochemical corrosion testing was performed on acidic and basic solutions containing sodium permanganate at room temperature to explore the corrosion impacts if these solutions were to be implemented to retrieve remaining actinides that are currently in the sludge of the tank.

PWR steam generator chemical cleaning. Phase I: solvent and process development. Volume II

International Nuclear Information System (INIS)

Larrick, A.P.; Paasch, R.A.; Hall, T.M.; Schneidmiller, D.

1979-01-01

A program to demonstrate chemical cleaning methods for removing magnetite corrosion products from the annuli between steam generator tubes and the tube support plates in vertical U-tube steam generators is described. These corrosion products have caused steam generator tube ''denting'' and in some cases have caused tube failures and support plate cracking in several PWR generating plants. Laboratory studies were performed to develop a chemical cleaning solvent and application process for demonstration cleaning of the Indian Point Unit 2 steam generators. The chemical cleaning solvent and application process were successfully pilot-tested by cleaning the secondary side of one of the Indian Point Unit 1 steam generators. Although the Indian Point Unit 1 steam generators do not have a tube denting problem, the pilot test provided for testing of the solvent and process using much of the same equipment and facilities that would be used for the Indian Point Unit 2 demonstration cleaning. The chemical solvent selected for the pilot test was an inhibited 3% citric acid-3% ascorbic acid solution. The application process, injection into the steam generator through the boiler blowdown system and agitation by nitrogen sparging, was tested in a nuclear environment and with corrosion products formed during years of steam generator operation at power. The test demonstrated that the magnetite corrosion products in simulated tube-to-tube support plate annuli can be removed by chemical cleaning; that corrosion resulting from the cleaning is not excessive; and that steam generator cleaning can be accomplished with acceptable levels of radiation exposure to personnel

Impact of an Environmental Cleaning Intervention on the Presence of Methicillin-Resistant Staphylococcus aureus and Vancomycin-Resistant Enterococci on Surfaces in Intensive Care Unit Rooms

Science.gov (United States)

Goodman, Eric R.; Platt, Richard; Bass, Richard; Onderdonk, Andrew B.; Yokoe, Deborah S.; Huang, Susan S.

2009-01-01

OBJECTIVES To evaluate the adequacy of discharge room cleaning and the impact of a cleaning intervention on the presence of methicillin-resistant Staphylococcus aureus (MRSA) and vancomycin-resistant enterococci (VRE) on environmental surfaces in intensive care unit (ICU) rooms. DESIGN Prospective environmental study. SETTING AND SAMPLE Convenience sample of ICU rooms in an academic hospital. METHODS AND INTERVENTION The intervention consisted of (1) a change from the use of pour bottles to bucket immersion for applying disinfectant to cleaning cloths, (2) an educational campaign, and (3) feedback regarding adequacy of discharge cleaning. Cleaning of 15 surfaces was evaluated by inspecting for removal of a preapplied mark, visible only with an ultraviolet lamp (“black light”). Six surfaces were cultured for MRSA or VRE contamination. Outcomes of mark removal and culture positivity were evaluated by χ2 testing and generalized linear mixed models, clustering by room. RESULTS The black-light mark was removed from 44% of surfaces at baseline, compared with 71% during the intervention (P <.001). The intervention increased the likelihood of removal of black-light marks after discharge cleaning (odds ratio, 4.4; P < .001), controlling for ICU type (medical vs surgical) and type of surface. The intervention reduced the likelihood of an environmental culture positive for MRSA or VRE (proportion of cultures positive, 45% at baseline vs 27% during the intervention; adjusted odds ratio, 0.4; P = .02). Broad, flat surfaces were more likely to be cleaned than were doorknobs and sink or toilet handles. CONCLUSIONS Increasing the volume of disinfectant applied to environmental surfaces, providing education for Environmental Services staff, and instituting feedback with a black-light marker improved cleaning and reduced the frequency of MRSA and VRE contamination. PMID:18624666

Senate begins clean air legislation debate

International Nuclear Information System (INIS)

Yates, M.

1990-01-01

This article reports on Senate debate on the Clean Air Act Amendments of 1989. Topics include acid rain provisions, administration objections, costs of the bill including disparity of costs in different regions and cost-sharing proposals, and the effects the current energy policy will have on the bill. Presidential, Senate, and subcommittee views on the bill are presented

Clean Water Act (CWA) Action Plan Implementation Priorities: Changes to Improve Water Quality, Increase Compliance and Expand Transparency

Science.gov (United States)

The Clean Water Act (CWA) Action Plan Implementation Priorities describes the new approaches to revamp the National Pollutant Discharge Elimination System (NPDES) permitting, compliance and enforcement program.Issued May 11, 2011

Cleaning and decontamination: Experimental feedback from PHENIX

International Nuclear Information System (INIS)

Masse, F.; Rodriguez, G.

1997-01-01

After the first few years of operation of PHENIX, it proved necessary to clean, then decontaminate sodium-polluted components, particularly large components such as the intermediate heat exchangers (IHX) and the primary pumps (PP). Ibis document presents the evolution of the cleaning and decontamination processes used, and specifies the reasons for this evolution. As regards the cleaning, experimental feedback and a greater rigour with respect to the hydrogen hazard have resulted in a modification of the process. The new cleaning process used at present (since 1994) is described in greater detail in this document. The main steps are: cold CO 2 bubbling in water, followed by hot CO 2 bubbling, spraying phase, then drying for inspection before immersion. In order to optimize and validate the process, the cleaning and decontamination plant has been highly instrumented, which, in particular, has allowed confirmation of the contention that the major part of the sodium is eliminated during the bubbling phases. With respect to decontamination, the objective is to perfect an efficient process that allows both human intervention with no particular biological shield for repair or maintenance of the components, and requalification of the materials after the decontamination operation. Owing to the high operating temperature of Fast Breeder Reactor components (400 to 550 deg. C), the activated corrosion products deposited on the components melt into the metal. The decontamination process therefore consists in either dissolving the deposits on the surface, or dissolving a thickness of about less than ten micrometers of the base metal. The reference process for austenitic-type steels is the SPm process, which consists in immersing the component in a sulphuric-phosphoric bath (sulphuric acid and phosphoric acid) at a temperature of 60 deg. C for 6 hours. The problem linked to this process is the treatment of the effluents that are produced, particularly phosphate releases. A

Response of lead-acid batteries to chopper-controlled discharge: Preliminary results

Science.gov (United States)

Cataldo, R. L.

1978-01-01

The preliminary results of simulated electric vehicle, chopper, speed controller discharge of a battery show energy output losses up to 25 percent compared to constant current discharges at the same average discharge current of 100 amperes. These energy losses are manifested as temperature rises during discharge, amounting to a two-fold increase for a 400-ampere pulse compared to the constant current case. Because of the potentially large energy inefficiency, the results suggest that electric vehicle battery/speed controller interaction must be carefully considered in vehicle design.

Effects of beach cast cleaning on beach quality, microbial food web, and littoral macrofaunal biodiversity

Science.gov (United States)

Malm, Torleif; Råberg, Sonja; Fell, Sabine; Carlsson, Per

2004-06-01

At the end of the summer, drifting filamentous red algae cover shallow bottoms and accumulate in huge cast walls on the open shores of the non-tidal central Baltic Sea. The hypotheses that beach cleaning increases water clarity, decreases the organic content of the sand, and increases the species diversity in the shallow zone closest to the shore, were tested through field investigations and experiments. Cleaned shorelines were compared with un-cleaned shorelines at two sites with different intensity of beach cleaning in a rural area of SE Sweden. The results show that water clarity was significantly increased off the intensively cleaned beach but not off the moderately cleaned one. Similarly, the total leakage of nitrogenous compounds decreased off the intensively cleaned beach, but not off the moderately cleaned. The organic content of the sand was lower on both cleaned beaches compared with nearby un-cleaned beaches. The total animal biomass was significantly lower on the intensively cleaned beach compared with the un-cleaned beach, but the moderately cleaned beach gave no such effect. The difference in biodiversity and community structure between cleaned and un-cleaned beaches was insignificant. The most obvious difference in species composition was a much higher number of planktivore opossum shrimps of the genus Mysis and Praunus on the un-cleaned beaches. The bacterial production and the amount of ciliates larger than 20 mm were also higher on un-cleaned beaches, indicating that the microbial food web off the un-cleaned beaches is stimulated by the discharge of decomposing algal material. The conclusion of the study is that mechanical cleaning reduces the organic content of the beach sand and may change the water quality and microbial production, but the effect on the macrofaunal biodiversity is insignificant.

Chemical dynamics of acidity and heavy metals in a mine water-polluted soil during decontamination using clean water.

Science.gov (United States)

Chen, A; Lin, C; Lu, W; Ma, Y; Bai, Y; Chen, H; Li, J

2010-03-15

A column leaching experiment was conducted to investigate the chemical dynamics of the percolating water and washed soil during decontamination of an acidic mine water-polluted soil. The results show that leaching of the contaminated soil with clean water rapidly reduced soluble acidity and ion concentrations in the soils. However, only soil column was eliminated after 30 leaching cycles. It is likely that the stored acidity continues to be released to the percolating water over a long period of time. During the column leaching, dissolved Cu and Pb were rapidly leached out, followed by mobilization of colloidal Cu and Pb from the exchangeable and the oxide-bound fractions as a result of reduced ionic strength in the soil solution. The soluble Fe contained in the soil was rare, probably because the soil pH was not sufficiently low; marked mobility of colloidal Fe took place after the ionic strength of the percolating water was weakened and the mobilized Fe was mainly derived from iron oxides. In contrast with Cu, Pb and Fe, the concentration of leachate Zn and Mn showed a continuously decreasing trend during the entire period of the experiment. (c) 2009 Elsevier B.V. All rights reserved.

Carbon steel corrosion prevention during chemical cleaning of steam generator secondary side components

International Nuclear Information System (INIS)

Fulger, M.; Lucan, D.; Velciu, L.

2009-01-01

During operation of a nuclear power plant, many contaminants, such as solid particles or dissolved species are formed in the secondary circuit, go into steam generator and deposit as scales on heat transfer tubing, support plate or as sludge on tube sheet. By accumulation of these impurities, heat transfer is reduced and the integrity of the steam generator tubing is influenced. Chemical cleaning is a qualified, efficient measure to improve steam generator corrosion performance. The corrosion mechanism can be counteracted by the chemical cleaning of the deposits on the tube sheet and the scales on the heat transfer tubing. The major component of the scales is magnetite, which can be dissolved using an organic chelating agent (ethylenediaminetetraacetic acid, EDTA) in combination with a complexing agent such as citric acid in an alkaline reducing environment. As the secondary side of SG is a conglomerate of alloys it is necessary to choose an optimal chemical cleaning solution for an efficient cleaning properties and at the same time with capability of corrosion prevention of carbon steel components during the process. The paper presents laboratory tests initiated to confirm the ability of this process to clean the SG components. The experiments followed two paths: - first, carbon steel samples have been autoclavized in specific secondary circuit solutions of steam generator to simulate the deposits constituted during operation of this equipment; - secondly, autoclavized samples have been cleaned with a solvent composed of EDTA citric acid, hydrazine of pH = 5 and temperature of 85 deg. C. Before chemical cleaning, the oxide films were characterized by surface analysis techniques including optical microscopy, scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS). Applied to dissolve corrosion products formed in a steam generator, the solvents based on chelating agents are aggressive toward carbon steels and corrosion inhibitors are

X-ray photoelectron spectroscopy analysis of cleaning procedures for synchrotron radiation beamline materials at the Advanced Photon Source

International Nuclear Information System (INIS)

Li, Y.; Ryding, D.; Liu, C.; Kuzay, T.M.; McDowell, M.W.; Rosenberg, R.A.

1994-01-01

TZM (a high temperature molybdenum alloy), machinable tungsten, and 304 stainless steel were cleaned using environmentally safe, commercially available cleaning detergents. The surface cleanliness was evaluated by x-ray photoelectron spectroscopy (XPS). It was found that a simple alkaline detergent is very effective at removal of organic and inorganic surface contaminants or foreign particle residue from machining processes. The detergent can be used with ultrasonic agitation at 140 F to clean the TZM molybdenum, machinable tungsten, and 304 stainless steel. A citric-acid-based detergent was also found to be effective at cleaning metal oxides, such as iron oxide, molybdenum oxide, as well as tungsten oxides at mild temperatures with ultrasonic agitation, and it can be used to replace strong inorganic acids to improve cleaning safety and minimize waste disposal and other environmental problems. The efficiency of removing the metal oxides depends on both cleaning temperature and time

Clean exergy biotechnical complex for recycling carbon dioxide from flue gas stations

Energy Technology Data Exchange (ETDEWEB)

Stolyarenko, G. [Cherkassy State Technological University, Cherkassy (Ukraine)

2013-07-01

A main problem, impedimental to the use of smoke gases as raw material for the production of pure carbon dioxide, is formation at incineration of fuel of such toxic connections as oxide of carbon(II), nitrogen oxides, and benzo (a) pyrene, formaldehyde, vapors of hydrochloric and hydrofluoric acids, toxic metals. Suppressions of formation CO, NO{sub x} and other harmful admixtures in smoke gases it is possible to attain on the stage of burning with the use of new technology: electronic catalysis of flame in the discharge zone. Method of heterophasic ozonization minimizes content CO and NO{sub x} and other toxic admixtures in smoke gases. Photosynthesis - by converting pure CO{sub 2} into hydrocarbons with the use of solar energy - enables to receive on a commercial scale genetically modified cyano-bacteria (blue-green algae). Oils got from them, a gaseous and diesel fuel during incineration results in the decline of maintenance of toxic connections in smoke gases. Thus achieves the creation of clean energy bio-complex. (author)

Annual Report, Fall 2016: Alternative Chemical Cleaning of Radioactive High Level Waste Tanks - Corrosion Test Results

International Nuclear Information System (INIS)

Wyrwas, R. B.

2016-01-01

The testing presented in this report is in support of the investigation of the Alternative Chemical Cleaning program to aid in developing strategies and technologies to chemically clean radioactive High Level Waste tanks prior to tank closure. The data and conclusions presented here were the examination of the corrosion rates of A285 carbon steel and 304L stainless steel exposed to two proposed chemical cleaning solutions: acidic permanganate (0.18 M nitric acid and 0.05M sodium permanganate) and caustic permanganate. (10 M sodium hydroxide and 0.05M sodium permanganate). These solutions have been proposed as a chemical cleaning solution for the retrieval of actinides in the sludge in the waste tanks, and were tested with both HM and PUREX sludge simulants at a 20:1 ratio.

Annual Report, Fall 2016: Alternative Chemical Cleaning of Radioactive High Level Waste Tanks - Corrosion Test Results

Energy Technology Data Exchange (ETDEWEB)

Wyrwas, R. B. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2016-09-01

The testing presented in this report is in support of the investigation of the Alternative Chemical Cleaning program to aid in developing strategies and technologies to chemically clean radioactive High Level Waste tanks prior to tank closure. The data and conclusions presented here were the examination of the corrosion rates of A285 carbon steel and 304L stainless steel exposed to two proposed chemical cleaning solutions: acidic permanganate (0.18 M nitric acid and 0.05M sodium permanganate) and caustic permanganate. (10 M sodium hydroxide and 0.05M sodium permanganate). These solutions have been proposed as a chemical cleaning solution for the retrieval of actinides in the sludge in the waste tanks, and were tested with both HM and PUREX sludge simulants at a 20:1 ratio.

EM-31 Alternative and Enhanced Chemical Cleaning Program

International Nuclear Information System (INIS)

King, Bill

2010-01-01

King's introduction to his presentation made 5 important points: (1) Numerous SRS tanks scheduled for closure (contract commitments); (2) Cannot remove all sludge by mechanical means due to obstructions; (3) Chemical removal technology needed (likely oxalic acid); (4) Post - dissolution neutralization required prior to transfer to compliant tanks; (5) Sodium oxalate salts precipitate on neutralization and have negative downstream impacts. There were three SRS chemical cleaning programs in 2010: Baseline: 8wt percent OA batch contact, ECC: 1-3 wt. percent OA with oxalate destruction, and the Alternative/Enhanced Chemical Cleaning (EM-31). This talk is on the EM-31 program.

Electrochemical fabrication of clean dendritic Au supported Pt clusters for electrocatalytic oxidation of formic acid

International Nuclear Information System (INIS)

Xia Yue; Liu Jun; Huang Wei; Li Zelin

2012-01-01

Highlights: ► A smooth Au surface was rebuilt into clean dendrite via square wave potential pulses. ► It was performed in blank H 2 SO 4 solution without Au(III) species and other additives. ► Dendritic Au provided certain advantage for dispersing Pt due to its unique structure. ► Pt-decorated dendritic Au demonstrated high activity for the HCOOH electrooxidation. - Abstract: We report here the fabrication of clean dendritic gold (DG) directly on a smooth Au electrode via square wave potential pulses (SWPPs) in a blank H 2 SO 4 solution containing no Au(III) species and additives. The effects of potential range, frequency and duration time of SWPPs and H 2 SO 4 concentration on the construction of DG were systematically investigated. A possible mechanism was proposed to explain the growth of DG. The whole process was templateless and surfactantless, and therefore effectively avoided possible contaminations that occurred in other synthetic routes. Further, the prepared DG electrode functioned as a scaffold to support electrodeposited Pt clusters, producing Pt-decorated DG (Pt-DG) electrodes. The electrocatalytic properties of Pt-DG electrodes with various Pt loadings were examined for the oxidation of formic acid. The low Pt loading Pt-DG demonstrated different electrochemical behavior from that on Pt-decorated smooth gold (Pt-SG) and on Pt-decorated gold nanoparticles because there were more defect sites like steps and edges on the DG surface. Ensemble effect, as well as electronic effect, accounts for the improved electrocatalytic activity of low Pt loading Pt-DG.

Battery Technology Stores Clean Energy

Science.gov (United States)

2008-01-01

Headquartered in Fremont, California, Deeya Energy Inc. is now bringing its flow batteries to commercial customers around the world after working with former Marshall Space Flight Center scientist, Lawrence Thaller. Deeya's liquid-cell batteries have higher power capability than Thaller's original design, are less expensive than lead-acid batteries, are a clean energy alternative, and are 10 to 20 times less expensive than nickel-metal hydride batteries, lithium-ion batteries, and fuel cell options.

Acid rain. Les pluies acides

Energy Technology Data Exchange (ETDEWEB)

Curren, T

1979-11-28

This report was produced for the use of Members of Parliament and House of Commons committees. The document describes the formation of acid rain, emissions of acidifying pollutants in North America, the growth of the problem and its environmental effects on aquatic and terrestrial ecosystems, human health and man-made structures. Areas of Canada which are most susceptible are identified. Actions taken by Parliament are given, including the formation of a sub-committee on acid rain and the passing of Bill C-51 in 1980 to amend the Clean Air Act, bringing it closer to a similar law in the U.S. A chronology of government responses to acid rain at the international, national and provincial level, is given. The most recent government actions included the passing of the US Clean Air Act by the Senate, the amending of the act into law, and commencement of negotiations to develop a Canada-US Air Quality Accord. 10 refs.

Ecological effectiveness of oil spill countermeasures: how clean is clean?

International Nuclear Information System (INIS)

Baker, J.M.

1999-01-01

This paper with 94 references examines background levels of hydrocarbons and the difficulty of defining clean. Processes and timescales for natural cleaning, and factors affecting natural cleaning timescales are considered. Ecological advantages and disadvantages of clean-up methods are highlighted, and five case histories of oil spills are summarised. The relationships between ecological and socio-economic considerations, and the need for a net environmental benefit analysis which takes into account the advantages and disadvantages of clean-up responses and natural clean-up are discussed. A decision tree for evaluating the requirement for shore clean-up is illustrated. (UK)

Short communication: Reactivity of diacetyl with cleaning and sanitizing agents.

Science.gov (United States)

Rincon-Delgadillo, M I; Lopez-Hernandez, A; Rankin, S A

2013-01-01

Diacetyl is used to impart a buttery flavor to numerous food products such as sour cream, cottage cheese, vegetable oil-based spreads, baked goods, and beverages. Recent studies have linked exposure to high concentrations of diacetyl and the onset of bronchiolitis obliterans. Due to the reported risks that diacetyl may pose, many food companies have altered practices to reduce worker exposure to diacetyl, including the use of personal respirators, improved air handling systems, and adequate cleaning practices. Commonly used cleaning and sanitizing agents may be reactive with diacetyl; however, the efficacy of these chemicals has not been studied in detail and remains unclear. The objective of this work was to study the reaction chemistry of diacetyl with common industrial cleaning and sanitizing chemicals. The reactions were assessed at equimolar concentrations and analyzed by gas chromatography-mass spectrometry. Peroxyacetic acid was most reactive with diacetyl (95% reduction in diacetyl), followed by sodium hypochlorite (76% reduction), and hydrogen peroxide (26% reduction). Benzalkonium chloride (BAC) did not react with diacetyl. Acetic acid was detected as the main product of reactions of diacetyl with peroxyacetic acid, sodium hypochlorite, and hydrogen peroxide. 1,1-Dichloro-2-propanone and 1,1,1-trichloropropanone were also identified as volatile reaction products in the sodium hypochlorite reactions. Copyright © 2013 American Dairy Science Association. Published by Elsevier Inc. All rights reserved.

Design and research on discharge performance for aluminum-air battery

Science.gov (United States)

Liu, Zu; Zhao, Junhong; Cai, Yanping; Xu, Bin

2017-01-01

As a kind of clean energy, the research of aluminum air battery is carried out because aluminum-air battery has advantages of high specific energy, silence and low infrared. Based on the research on operating principle of aluminum-air battery, a novel aluminum-air battery system was designed composed of aluminum-air cell and the circulation system of electrolyte. A system model is established to analyze the polarization curve, the constant current discharge performance and effect of electrolyte concentration on the performance of monomer. The experimental results show that the new energy aluminum-air battery has good discharge performance, which lays a foundation for its application.

Risk in cleaning: chemical and physical exposure.

Science.gov (United States)

Wolkoff, P; Schneider, T; Kildesø, J; Degerth, R; Jaroszewski, M; Schunk, H

1998-04-23

occupants. The variety and duration of the emissions depend inter alia on the use of fragrances and high boiling VOCs. Some building materials appear to increase their VOC emission through wet cleaning and thus may affect the IAQ. Particles and dirt contain a great variety of both volatile and non-volatile substances, including allergens. While the volatile fraction can consist of more than 200 different VOCs including formaldehyde, the non-volatile fraction can contain considerable amounts (> 0.5%) of fatty acid salts and tensides (e.g. linear alkyl benzene sulphonates). The level of these substances can be high immediately after the cleaning process, but few studies have been conducted concerning this problem. The substances partly originate from the use of cleaning agents. Both types are suspected to be airway irritants. Cleaning activities generate dust, mostly by resuspension, but other occupant activities may also resuspend dust over longer periods of time. Personal sampling of VOCs and airborne dust gives higher results than stationary sampling. International bodies have proposed air sampling strategies. A variety of field sampling techniques for VOC and surface particle sampling is listed.

Association between Residential Proximity to PERC Dry Cleaning Establishments and Kidney Cancer in New York City

Directory of Open Access Journals (Sweden)

Jing Ma

2009-01-01

Full Text Available Perchloroethylene (PERC is commonly used as a dry cleaning solvent and is believed to be a human carcinogen, with occupational exposure resulting in elevated rates of kidney cancer. Living near a dry cleaning facility using PERC has been demonstrated to increase the risk of PERC exposure throughout the building where the dry cleaning is conducted, and in nearby buildings. We designed this study to test the hypothesis that living in an area where there are many PERC dry cleaners increases PERC exposure and the risk of kidney cancer. We matched the diagnosis of kidney cancer from hospitalization discharge data in New York City for the years 1994–2004 by zip code of patient residence to the zip code density of dry cleaners using PERC, as a surrogate for residential exposure. We controlled for age, race, gender, and median household income. We found a significant association between the density of PERC dry cleaning establishments and the rate of hospital discharges that include a diagnosis of kidney cancer among persons 45 years of age and older living in New York City. The rate ratio increased by 10 to 27% for the populations in zip codes with higher density of PERC dry cleaners. Because our exposure assessment is inexact, we are likely underestimating the real association between exposure to PERC and rates of kidney cancer. Our results support the hypothesis that living near a dry cleaning facility using PERC increases the risk of PERC exposure and of developing kidney cancer. To our knowledge, this study is the first to demonstrate an association between residential PERC exposure and cancer risk.

Association between Residential Proximity to PERC Dry Cleaning Establishments and Kidney Cancer in New York City

International Nuclear Information System (INIS)

Ma, J.; Lessner, L.; Lessner, L.; Carpenter, D.O.; Schreiber, J.

2010-01-01

Perchloroethylene (PERC) is commonly used as a dry cleaning solvent and is believed to be a human carcinogen, with occupational exposure resulting in elevated rates of kidney cancer. Living near a dry cleaning facility using PERC has been demonstrated to increase the risk of PERC exposure throughout the building where the dry cleaning is conducted, and in nearby buildings. We designed this study to test the hypothesis that living in an area where there are many PERC dry cleaners increases PERC exposure and the risk of kidney cancer. We matched the diagnosis of kidney cancer from hospitalization discharge data in New York City for the years 1994-2004 by zip code of patient residence to the zip code density of dry cleaners using PERC, as a surrogate for residential exposure. We controlled for age, race, gender, and median household income. We found a significant association between the density of PERC dry cleaning establishments and the rate of hospital discharges that include a diagnosis of kidney cancer among persons 45 years of age and older living in New York City. The rate ratio increased by 10 to 27% for the populations in zip codes with higher density of PERC dry cleaners. Because our exposure assessment is inexact, we are likely underestimating the real association between exposure to PERC and rates of kidney cancer. Our results support the hypothesis that living near a dry cleaning facility using PERC increases the risk of PERC exposure and of developing kidney cancer. To our knowledge, this study is the first to demonstrate an association between residential PERC exposure and cancer risk.

Performance Modeling of a Vanadium Redox Flow Battery during Discharging

International Nuclear Information System (INIS)

Yang, W.W.; He, Y.L.; Li, Y.S.

2015-01-01

A two-dimensional quasi-steady-state model is presented to simulate coupled mass-species-charge transfer and electrochemical reactions in all vanadium redox flow battery. Emphasis is located on examining the influences of applied current density, initial vanadium concentration, initial acid concentration and electrolyte flow rate on overpotentials in both electrodes, ohmic loss in electrolyte phase as well as battery discharging voltage. It is indicated that overpotential in negative electrode is the dominant factor causing the loss of battery discharging voltage at relatively lower or higher state of charge, while ohmic loss in electrolyte phase is dominant when discharging at moderate state of charge. Increasing initial vanadium concentration, the battery discharging voltage is significantly increased due to the reduced overpotentials in both electrodes. With the increase in initial acid concentration, the battery discharging voltage is also obviously increased because of increased open circuit voltage and decreased ohmic loss in electrolyte phase. As the electrolyte flow rate increases, the total discharging time is extended due to the retarded concentration polarization and the battery discharging voltage is obviously increased at lower state of charge

Submarine Groundwater Discharge in the Coastal Zone

Science.gov (United States)

Bakti, Hendra

2018-02-01

Indonesia is one of the archipelagic countries that has the longest coastline in the world. Because it is located in the tropics, in general it has a very high rainfall. Each island has a different morphology which is composed of a variety of rocks with different hydrogeological properties. This natural condition allows for the presence of groundwater in different amount in each island. The difference in groundwater hydraulics gradients in aquifer continuous to the sea has triggered the discharge of groundwater to offshore known as submarine groundwater discharge (SGD). Its presence can be as seepage or submarine springs with components derived from land and sea and a mixture between them. The understanding of SGD phenomenon is very important because it can be useful as a source of clean water in coastal areas, affecting marine health, and improving marine environment.

SODIUM ALUMINOSILICATE FOULING AND CLEANING OF DECONTAMINATED SALT SOLUTION COALESCERS

International Nuclear Information System (INIS)

Poirier, M.; Thomas Peters, T.; Fernando Fondeur, F.; Samuel Fink, S.

2008-01-01

During initial non-radioactive operations at the Modular Caustic Side Solvent Extraction Unit (MCU), the pressure drop across the decontaminated salt solution coalescer reached ∼10 psi while processing ∼1250 gallons of salt solution, indicating possible fouling or plugging of the coalescer. An analysis of the feed solution and the 'plugged coalescer' concluded that the plugging was due to sodium aluminosilicate solids. MCU personnel requested Savannah River National Laboratory (SRNL) to investigate the formation of the sodium aluminosilicate solids (NAS) and the impact of the solids on the decontaminated salt solution coalescer. Researchers performed developmental testing of the cleaning protocols with a bench-scale coalescer container 1-inch long segments of a new coalescer element fouled using simulant solution. In addition, the authors obtained a 'plugged' Decontaminated Salt Solution coalescer from non-radioactive testing in the MCU and cleaned it according to the proposed cleaning procedure. Conclusions from this testing include the following: (1) Testing with the bench-scale coalescer showed an increase in pressure drop from solid particles, but the increase was not as large as observed at MCU. (2) Cleaning the bench-scale coalescer with nitric acid reduced the pressure drop and removed a large amount of solid particles (11 g of bayerite if all aluminum is present in that form or 23 g of sodium aluminosilicate if all silicon is present in that form). (3) Based on analysis of the cleaning solutions from bench-scale test, the 'dirt capacity' of a 40 inch coalescer for the NAS solids tested is calculated as 450-950 grams. (4) Cleaning the full-scale coalescer with nitric acid reduced the pressure drop and removed a large amount of solid particles (60 g of aluminum and 5 g of silicon). (5) Piping holdup in the full-scale coalescer system caused the pH to differ from the target value. Comparable hold-up in the facility could lead to less effective cleaning and

Plutonium discharges to the sanitary sewer: Health impacts at the Livermore Water Reclamation Plant

International Nuclear Information System (INIS)

Balke, B.K.

1993-01-01

The Lawrence Livermore National Laboratory (LLNL) is the largest discharger of sewage treated by the Livermore Water Reclamation (LWRP), contributing approximately 7% by volume of the LWRP influent LILNL operations, as potential sources both of industrial pollutants and radioactivity, are therefore of particular concern to the LWRP. For this reason, LLNL has maintained vigorous wastewater discharge control and monitoring programs. In particular, the monitoring program has demonstrated that, except in a few rare instances, the concentration of contaminants in LLNL effluent have always remained below the appropriate regulatory standards. The exceptions have generally been due to inadvertent discharges of metals-bearing solutions produced by metal plating or cleaning operations

Plasma discharge in ferritic first wall vacuum vessel of the Hitachi Tokamak HT-2

International Nuclear Information System (INIS)

Abe, Mitsushi; Nakayama, Takeshi; Asano, Katsuhiko; Otsuka, Michio

1997-01-01

A tokamak discharge with ferritic material first wall was tried successfully. The Hitachi Tokamak HT-2 had a stainless steel SUS304 vacuum vessel and modified to have a ferritic plate first wall for experiments to investigate the possibility of ferritic material usage in magnetic fusion devices. The achieved vacuum pressure and times used for discharge cleaning was roughly identical with the stainless steel first wall or the original HT-2. We concluded that ferritic material vacuum vessel is possible for tokamaks. (author)

Alternatives to Organic Solvents in Industrial Cleaning Processes

DEFF Research Database (Denmark)

Jacobsen, Thomas

1998-01-01

To control chemical hazards in work places, substitution of harmful substances with less harmful or non-toxic products is now a method used in many countries and in many companies. It has previously been demonstrated that it is desirable and possible to use non-volatile, low-toxic vegetable...... cleaning agents in offset printing companies instead of volatile, toxic organic solvents. The present study is based on a project with the aim of defining other industrial processes, where organic solvents used for cleaning or degreasing can be replaced by non-volatile, low-toxic products, which are based...... on esters from fatty acids of vegetable origin (vegetable esters - VE).The study indicates that industrial cleaning/degreasing with organic solvents may be substituted with VEs on metal surfaces and on some coated surfaces, in manufacture of paints and inks, use of paints, use of inks (printing), metal...

Plasma Cleaning

Science.gov (United States)

Hintze, Paul E.

2016-01-01

NASA's Kennedy Space Center has developed two solvent-free precision cleaning techniques: plasma cleaning and supercritical carbon dioxide (SCCO2), that has equal performance, cost parity, and no environmental liability, as compared to existing solvent cleaning methods.

EM-31 Alternative And Enhanced Chemical Cleaning Program For Sludge Heel Removal - 11220

International Nuclear Information System (INIS)

King, W.; Hay, M.; Wiersma, B.; Pennebaker, F.

2010-01-01

Mixtures of oxalic acid with nitric acid have been shown to be superior to oxalic acid alone for the dissolution of iron-rich High Level Waste sludge heels. Optimized conditions resulting in minimal oxalate usage and stoichiometric iron dissolution (based on added oxalate ion) have been determined for hematite (a primary sludge iron phase) in oxalic/nitric acid mixtures. The acid mixtures performed better than expected based on the solubility of hematite in the individual acids through a synergistic effect in which the preferred 1:1 Fe:oxalate complex is formed. This allows for the minimization of oxalate additions to the waste stream. Carbon steel corrosion rates were measured in oxalic/nitric acid mixtures to evaluate the impacts of chemical cleaning with these solutions on waste tank integrity. Manageable corrosion rates were observed in the concentration ranges of interest for an acid contact timescale of 1 month. Kinetics tests involving hematite and gibbsite (a primary sludge aluminum phase) have confirmed that (ge)90% solids dissolution occurs within 3 weeks. Based on these results, the chemical cleaning conditions recommended to promote minimal oxalate usage and manageable corrosion include: 0.5 wt. % oxalic acid/0.175 M nitric acid mixture, 50 C, 2-3 week contact time with agitation.

Collective Phenomena In Volume And Surface Barrier Discharges

Science.gov (United States)

Kogelschatz, U.

2010-07-01

Barrier discharges are increasingly used as a cost-effective means to produce non-equilibrium plasmas at atmospheric pressure. This way, copious amounts of electrons, ions, free radicals and excited species can be generated without appreciable gas heating. In most applications the barrier is made of dielectric material. In laboratory experiments also the use of resistive, ferroelectric and semiconducting materials has been investigated, also porous ceramic layers and dielectric barriers with controlled surface conductivity. Major applications utilizing mainly dielectric barriers include ozone generation, surface cleaning and modification, polymer and textile treatment, sterilization, pollution control, CO2 lasers, excimer lamps, plasma display panels (flat TV screens). More recent research efforts are also devoted to biomedical applications and to plasma actuators for flow control. Sinu- soidal feeding voltages at various frequencies as well as pulsed excitation schemes are used. Volume as well as surface barrier discharges can exist in the form of filamentary, regularly patterned or laterally homogeneous discharges. Reviews of the subject and the older literature on barrier discharges were published by Kogelschatz (2002, 2003), by Wagner et al. (2003) and by Fridman et al. (2005). A detailed discussion of various properties of barrier discharges can also be found in the recent book "Non-Equilibrium Air Plasmas at Atmospheric Pressure" by Becker et al. (2005). The physical effects leading to collective phenomena in volume and surface barrier discharges will be discussed in detail. Special attention will be given to self-organization of current filaments. Main similarities and differences of the two types of barrier discharges will be elaborated.

Effects of organic acid pickling on the corrosion resistance of magnesium alloy AZ31 sheet

DEFF Research Database (Denmark)

Nwaogu, Ugochukwu Chibuzoh; Blawert, C.; Scharnagl, N.

2010-01-01

mu m of the contaminated surface was required to reach corrosion rates less than 1 mm/year in salt spray condition. Among the three organic acids examined, acetic acid is the best choice. Oxalic acid can be an alternative while citric acid is not suitable for cleaning AZ31 sheet, because......Organic acids were used to clean AZ31 magnesium alloy sheet and the effect of the cleaning processes on the surface condition and corrosion performance of the alloy was investigated. Organic acid cleanings reduced the surface impurities and enhanced the corrosion resistance. Removal of at least 4...

Frequent occurrence of Osteomalacia among grazing cattle caused by hydrofluoric acid contained in the flue gas discharged by a chemical plant

Energy Technology Data Exchange (ETDEWEB)

Hupka, E; Luy, P

1929-01-01

In 1928 a number of animals grazing in the vicinity of a chemical plant fell ill to a disease which was diagnosed as fluorosis. But the symptoms shown by the diseased animals were in many respects different from those commonly associated with such cases. The two front legs became lame, toes and ankles were swollen. The pulse rate was higher, an increased body temperature was measured and pain was felt. In some cases the hind legs became stiff. Furthermore, an enormous loss of weight was observed and swellings appeared along the ribs. The milk production decreased. All these symptoms indicate osteomalacia. The grass on which these animals fed was examined but it was found lush and in no way lacking in Ca and phosphoric acid (osteomalacia is a deficiency of these two minerals). The toxicant was found to be the fluorine deposited on the grass and plants. Hydrofluoric acid attacks the calcium in the bones and dissolves it. The consequence is osteoporosis. The fluorine is discharged with the flue gas of the nearby chemical plant. The disease did not occur outside the range of the chemical plant. The condition of the animals visibly improved during winter time when they were fed with fodder coming from an unpolluted area. The chemical physiological examinations which were conducted showed that the calcium of the bones is used to neutralize the hydrofluoric acid. The by-product of this neutralizing process, phosphoric acid, is discharged with the urine. 12 references.

Is this an arc or a glow discharge?

International Nuclear Information System (INIS)

Puchkarev, V.F.; Bochkarev, M.B.

1994-01-01

A well known criterion for distinguishing an arc discharge from a glow discharge is a low voltage drop (10--30 V) and a high current density that varies from a few tens to 10 6 A/cm 2 depending on arc type. The high current density is an attribute of arcs with cathode spots. The authors report here a study of the mechanism of emission in cathode spot arc where they realized a spotless discharge with a low voltage drop (30--50 V) and a high mean current density (10 4 --10 6 A/cm 2 ). The discharge was initiated between a broad cathode and point anode. The cathode was a smooth tungsten sphere electrode of about 100 μm in diameter. The point anode was made of various materials (Mo, Cu, Cd) with initial radius 1 μm. Before the experiment the cathode was cleaned by heating at 2,000 K at high vacuum (10 -8 Torr). The discharge was initiated by self-breakdown when electrodes under the voltage 200--500 V were brought to close proximity with each other. The cathode-anode spacing d at the moment of breakdown was estimated to be < 1 μm. The discharge current was varied within 1--3 A by changing the applied voltage and impedance of coaxial cable generator. The discharge burned during 100--1,000 ns. After the single discharge the cathode and anode were examined with a scanning electron microscope. The cathode surface exposed to the discharge was smooth, i.e. no erosion pits similar to arc craters were found on the cathode surface. The anode was shortened after discharge by 5--50 μm depending on current, material and cone angle. A high current density and low voltage drop implies that this is an arc discharge, while the cold cathode and the absence f cathode spot trace are pertinent to a dense glow discharge. The mechanism of emission involving secondary electron emission is to be discussed

Temperature control of thermal-gas-dynamical installation in cleaning oil-well tubes

Science.gov (United States)

Penner, V. A.; Martemyanov, D. B.; Pshenichnikova, V. V.

2017-08-01

The article provides the study results of cleaning oil-well tubes, the oil-well tube failure reasons for service by their types have been considered. The chemical method of cleaning oil-well tubes as the least expensive has been reviewed when acid solution moves to the interptube space mixing up with oil and liquidates paraffin and pitches deposits on the internal pipe surface. Except the chemical method of pipes cleaning the mechanical one was considered as well. Also the disadvantages -such as the low productivity of cleaning and design complexity- of this deposits removal method on the internal oil-well tube surface have been considered. An effective method for cleaning oil-well tubing from paraffin and pitches by the thermodynamic plant based on the aircraft engine has been introduced for the first time. The temperature distribution graph in the gas stream at the engine output has been given.

Controlling the cost of clean air - A new clean coal technology

International Nuclear Information System (INIS)

Kindig, J.K.; Godfrey, R.L.

1991-01-01

This article presents the authors' alternative to expensive coal combustion products clean-up by cleaning the coal, removing the sulfur, before combustion. Topics discussed include sulfur in coal and the coal cleaning process, the nature of a new coal cleaning technology, the impact on Clean Air Act compliance, and the economics of the new technology

Removal of NO and SO2 in Corona Discharge Plasma Reactor with Water Film

Institute of Scientific and Technical Information of China (English)

贺元吉; 董丽敏; 杨嘉祥

2004-01-01

In this paper, a novel type of a corona discharge plasma reactor was designed, which consists of needle-plate-combined electrodes, in which a series of needle electrodes are placed in a glass container filled with flue gas, and a plate electrode is immersed in the water. Based on this model, the removal of NO and SO2 was tested experimentally. In addition, the effect of streamer polarity on the reduction of SO2 and NO was investigated in detail. The experimental results show that the corona wind formed between the high-voltage needle electrode and the water by corona discharge enhances the cleaning efficiency of the flue gas because of the presence of water,and the cleaning efficiency will increase with the increase of applied dc voltage within a definite range. The removal efficiency of SO2 up to 98%, and about 85% of NOx removal under suitable conditions is obtained in our experiments.

Laser cleaning of sulfide scale on compressor impeller blade

International Nuclear Information System (INIS)

Tang, Q.H.; Zhou, D.; Wang, Y.L.; Liu, G.F.

2015-01-01

Highlights: • The effects of sulfide layers and fluence values on the mechanism of laser cleaning were experimentally established. • The specimen surface with sulfide scale becomes slightly smoother than that before laser cleaning. • The mechanism of laser cleaning the sulfide scale of stainless steel is spallation without oxidization. • It would avoid chemical waste and dust pollution using a fiber laser instead of using nitric acids or sandblasting. - Abstract: Sulfide scale on the surface of a compressor impeller blade can considerably reduce the impeller performance and its service life. To prepare for subsequent remanufacturing, such as plasma spraying, it needs to be removed completely. In the corrosion process on an FV(520)B stainless steel, sulfide scale is divided into two layers because of different outward diffusion rates of Cr, Ni and Fe. In this paper, the cleaning threshold values of the upper and inner layers and the damage threshold value of the substrate were investigated using a pulsed fiber laser. To obtain experimental evidence, scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS) and 3D surface profilometry were employed to investigate the two kinds of sulfide layers on specimens before, during, and after laser cleaning.

Enhanced incorporation of fatty acid into phosphatidyl choline that parallels histamine discharge in mast cells

International Nuclear Information System (INIS)

Castle, J.D.; Castle, A.M.; Ma, A.K.; Stukenbrok, H.

1984-01-01

Purified rat peritoneal and pleural mast cells preincubated briefly with radioactively labeled fatty acid were treated with A23187, which bypasses primary receptors in stimulating exocytosis. An enhanced incorporation of fatty acid into phosphatidyl choline (PC) that occurred in parallel with histamine release at 24-25 degrees C was observed and was initially proportional to the total amount of histamine discharged. Enhanced PC labeling and histamine secretion were also proportional at temperatures ranging from 17-37 degrees C. Both radioactive linoleic and palmitic acids were incorporated selectively at the beta-position of the glycerol backbone of PC. PC labeling by [3H]choline was not detectably different in control and stimulated cells, and phosphatidic acid did not exhibit selectively enhanced beta-acylation. Thus, the stimulated labeling in A23187-treated cells may occur secondary to the action of a phospholipase A2 that favors PC as a substrate. Other peritoneal cell types exhibit a very similar A23187-stimulated selective labeling of PC. Therefore, autoradiography has been used to provide a direct demonstration that in purified preparations, mast cells are the principal cell type engaged in A23187-elicited incorporation of fatty acid into PC. The efficacy of this approach has relied on special procedures devised to obtain significantly different autoradiographic grain densities between control and stimulated preparations that can be attributed to differences in the level of [3H]palmitate-labeled PC. Preliminary tests using compound 48/80 as a secretory stimulus for mast cells have identified a similar selectively enhanced PC labeling. In either case, however, consideration of possible relationships between PC metabolism and the secretory process are premature since they have not been tested directly

Cheap non-toxic non-corrosive method of glass cleaning evaluated by contact angle, AFM, and SEM-EDX measurements.

Science.gov (United States)

Dey, Tania; Naughton, Daragh

2017-05-01

Glass surface cleaning is the very first step in advanced coating deposition and it also finds use in conserving museum objects. However, most of the wet chemical methods of glass cleaning use toxic and corrosive chemicals like concentrated sulfuric acid (H 2 SO 4 ), piranha (a mixture of concentrated sulfuric acid and 30% hydrogen peroxide), and hydrogen fluoride (HF). On the other hand, most of the dry cleaning techniques like UV-ozone, plasma, and laser treatment require costly instruments. In this report, five eco-friendly wet chemical methods of glass cleaning were evaluated in terms of contact angle (measured by optical tensiometer), nano-scale surface roughness (measured by atomic force microscopy or AFM), and elemental composition (measured by energy dispersive x-ray spectroscopy or SEM-EDX). These glass cleaning methods are devoid of harsh chemicals and costly equipment, hence can be applied in situ in close proximity with plantation such as greenhouse or upon subtle objects such as museum artifacts. Out of these five methods, three methods are based on the chemical principle of chelation. It was found that the citric acid cleaning method gave the greatest change in contact angle within the hydrophilic regime (14.25° for new glass) indicating effective cleansing and the least surface roughness (0.178 nm for new glass) indicating no corrosive effect. One of the glass sample showed unique features which were traced backed to the history of the glass usage.

Evaluation of optimal reuse system for hydrofluoric acid wastewater

Energy Technology Data Exchange (ETDEWEB)

Won, Chan-Hee [Department of Environmental Engineering, Chonbuk National University, 567 Bakje-daero, Deokjin-Gu, Jeonju, Jeollabuk-Do, 561-756 (Korea, Republic of); Choi, Jeongyun [R and D Center, Samsung Engineering Co. Ltd., 415-10 Woncheon-Dong, Youngtong-Gu, Suwon, Gyeonggi-Do, 443-823 (Korea, Republic of); Chung, Jinwook, E-mail: jin-wook.chung@samsung.com [R and D Center, Samsung Engineering Co. Ltd., 415-10 Woncheon-Dong, Youngtong-Gu, Suwon, Gyeonggi-Do, 443-823 (Korea, Republic of)

2012-11-15

Highlights: Black-Right-Pointing-Pointer Coagulation and ion exchange technologies were ineffective in removing fluoride. Black-Right-Pointing-Pointer Polyamide RO was more efficacious than cellulose RO due to its high flux and rejection. Black-Right-Pointing-Pointer Spiral wound RO system was more preferential to disc tube RO system for reusing raw hydrofluoric acid wastewater. Black-Right-Pointing-Pointer Combined coagulation and RO technology can be applied to reuse raw hydrofluoric acid wastewater. - Abstract: The treatment of hydrofluoric acid (HF) wastewater has been an important environmental issue in recent years due to the extensive use of hydrofluoric acid in the chemical and electronics industries, such as semiconductor manufacturers. Coagulation/precipitation and ion exchange technologies have been used to treat HF wastewater, but these conventional methods are ineffective in removing organics, salts, and fluorides, limiting its reuse for water quality and economic feasibility. One promising alternative is reverse osmosis (RO) after lime treatment. Based on pilot-scale experiment using real HF wastewater discharged from semiconductor facility, the spiral wound module equipped with polyamide membranes has shown excellent flux and chemical cleaning cycles. Our results suggest that coagulation/precipitation and spiral wound RO constitute the optimal combination to reuse HF wastewater.

Performances in Tank Cleaning

Directory of Open Access Journals (Sweden)

Fanel-Viorel Panaitescu

2018-03-01

Full Text Available There are several operations which must do to maximize the performance of tank cleaning. The new advanced technologies in tank cleaning have raised the standards in marine areas. There are many ways to realise optimal cleaning efficiency for different tanks. The evaluation of tank cleaning options means to start with audit of operations: how many tanks require cleaning, are there obstructions in tanks (e.g. agitators, mixers, what residue needs to be removed, are cleaning agents required or is water sufficient, what methods can used for tank cleaning. After these steps, must be verify the results and ensure that the best cleaning values can be achieved in terms of accuracy and reliability. Technology advancements have made it easier to remove stubborn residues, shorten cleaning cycle times and achieve higher levels of automation. In this paper are presented the performances in tank cleaning in accordance with legislation in force. If tank cleaning technologies are effective, then operating costs are minimal.

Chemical cleaning of steam generators: application to Nogent 1

International Nuclear Information System (INIS)

Fiquet, J.M.; Veysset, J.P.; Esteban, L.; Saurin, P.

1991-01-01

EDF has patented a chemical cleaning process for PWR steam generators, based on the use of a mixture or organic acids in order to dissolve iron oxides and copper with a single solution and clean dented crevices. Qualification tests have permitted to demonstrate effectiveness of the solution and its innocuousness related to steam generator materials. The process, the licence of which belongs to SOMAFER RA and Framatome has been implemented in France at Nogent. The goal was to dissolve iron oxides allowing metallic particles, aggregated on the tubesheet, to be released and mechanically removed. The effectiveness was satisfactory and this treatment is to be extended to other units. (author)

Use of a fluorescent chemical as a quality indicator for a hospital cleaning program.

Science.gov (United States)

Blue, Jennifer; O'Neill, Cindy; Speziale, Paul; Revill, Jeff; Ramage, Lee; Ballantyne, Lisa

2008-01-01

Hamilton Health Sciences is a large teaching hospital with over 1,000 beds and consists of three acute care sites, one Regional Cancer Center and two Rehabilitation/Chronic Care facilities. An environmental cleaning pilot project was initiated at the acute care Henderson site, following an outbreak of vancomycin-resistant Enterococcus (VRE). Healthcare-associated infections (HAI) due to antibiotic-resistant organisms are increasing in Southern Ontario. Environmental cleaning plays a key role in eradicating resistant organisms that live in hospital environments, thereby helping to reduce HAIs. The environmental cleaning practices on the Orthopaedic Unit were identified as a contributing factor to the VRE outbreak after visual assessments were completed using a Brevis GlitterBug product, a chemical that fluoresces under an ultraviolet (UV) lamp. These findings led to a hospital-wide cleaning improvement initiative on all units except critical care areas. The GlitterBug potion was employed by Infection Control and Customer Support Services (CSS) as a tool to evaluate the daily cleaning of patient washrooms as well as discharge cleaning of contact precaution isolation rooms. Over a four-week period, the GlitterBug potion was applied to seven frequently touched standard targets in randomly selected patient bathrooms on each unit and 14 frequently touched targets prior to cleaning in the rooms used for isolation. The targets were then evaluated using the UV lamp to detect objects that were not cleaned and the results were recorded on a standardized form. The rate of targets cleaned versus the targets missed was calculated. The overall rate for daily cleaning of bathrooms and cleaning of isolation rooms was poor with only 23% of the targets cleaned. Based on these findings, several interventions were implemented. This resulted in a significant improvement in cleaning practices during the pilot project. Greater than 80% of the targets were cleaned compared to the baseline

The performance of a soluble lead-acid flow battery and its comparison to a static lead-acid battery

International Nuclear Information System (INIS)

Zhang, C.P.; Sharkh, S.M.; Li, X.; Walsh, F.C.; Zhang, C.N.; Jiang, J.C.

2011-01-01

Highlights: → We compared the electrochemical characteristics of two types of the batteries. → SLAFB shows as good performance as SLAB under the same current density. → The cycle life of two batteries is strongly influenced by the depth of discharge. → The cycle life of SLAFB can be extended by treatment with hydrogen peroxide. - Abstract: The electrochemistry of static lead-acid and soluble lead-acid flow batteries is summarised and the differences between the two batteries are highlighted. A general comparison of the performance of an unoptimised soluble lead-acid flow laboratory cell and a commercial lead-acid battery during charge and discharge is reported. The influence of the depth of discharge on cycle life for both batteries is also considered. The flow battery was found to have a better charge efficiency than the static one, but the cells were found to have comparable energy efficiencies. The self-discharge characteristics of the soluble lead-acid battery were also measured and compared to reported values for a commercial static battery. Some self-discharge of the soluble lead-acid flow battery is observed during prolonged periods on open-circuit but the battery could recover its normal performance after a single charge-discharge cycle.

In-situ reactive of x-ray optics by glow discharge

International Nuclear Information System (INIS)

Johnson, E.D.; Garrett, R.F.

1987-01-01

We have developed a method of in-situ reactive glow discharge cleaning of x-ray optical surfaces which is capable of complete removal of carbon contamination. Our work is the first to successfully clean an entire optical system in-situ and characterize its performance at short wavelengths (as low as 10 /angstrom/). The apparatus required is quite simple and can easily be fitted to most existing UHV (ultra high vacuum) mirror boxes of monochromators. The advantages of this technique over previously available methods include dramatic improvements in instrument performance and reductions in down time since the whole process typically takes a few days. This paper will briefly describe our results and detail the experimental considerations for application of the technique on different monochromator geometries. Possible improvements and extensions of the technique are also discussed

Clean Cities Fact Sheet

Energy Technology Data Exchange (ETDEWEB)

2004-01-01

This fact sheet explains the Clean Cities Program and provides contact information for all coalitions and regional offices. It answers key questions such as: What is the Clean Cities Program? What are alternative fuels? How does the Clean Cities Program work? What sort of assistance does Clean Cities offer? What has Clean Cities accomplished? What is Clean Cities International? and Where can I find more information?

Development of chemical cleaning formulation for service water system of FBTR

International Nuclear Information System (INIS)

Velmurugan, S.; Narasimhan, S.V.; Das, P.C.; Mathur, P.K.

1995-01-01

Service water system of Fast Breeder Test Reactor (FBTR) was found to be corroded and at few locations, the corrosion product oxides were choking the smaller diameter pipelines. An attempt was made to develop a chemical cleaning formulation to chemically remove the oxides using a surface conditioner and chelating agents. Of the several complexants tested, hydroxyethylethylene diamine tetraacetic acid (HEDTA) was found to be better than other complexants from the point of view of oxide dissolution efficiency, solubility etc. A two stage chemical cleaning process involving conditioning of the oxide layer with 0.1% tannic acid followed by exposure of the conditioned oxide layer with a formulation containing 1% HEDTA + 0.5% Sodium Gluconate +0.2% hexamine was recommended to remove the corrosion product oxide present in the service water system. (author). 4 refs., 2 tabs

Laser surface cleaning

International Nuclear Information System (INIS)

Freiwald, J.G.; Freiwald, D.A.

1994-01-01

The objective of this work is a laboratory demonstration that red-lead primer and two-part epoxy paints can be stripped from concrete and metal surfaces using surface cleaning systems based on pulsed-repetition CO 2 lasers. The three goals are to: (1) demonstrate coatings removal, including surface pore cleaning; (2) demonstrate that there is negligible release of ablated contaminants to the environment; and (3) demonstrate that the process will generate negligible amounts of additional waste compared to competing technologies. Phase 1 involved site visits to RMI and Fernald to assess the cleaning issues for buildings and parts. In addition, Phase 1 included detailed designs of a more powerful system for industrial cleaning rates, including laser, articulating optics, ablated-material capture suction nozzle attached to a horizontal raster scanner for floor cleaning, and filtration system. Some concept development is also being done for using robots, and for parts cleaning. In Phase 2 a transportable 6 kW system will be built and tested, with a horizontal surface scanner for cleaning paint from floors. The laboratory tests will again be instrumented. Some concept development will continue for using robots, and for parts cleaning. This report describes Phase 1 results

Discharge of landfill leachate to streambed sediments impacts the mineralization potential of phenoxy acid herbicides depending on the initial abundance of tfdA gene classes

DEFF Research Database (Denmark)

Pazarbasi, Meric Batioglu; Milosevic, Nemanja; Malaguerra, Flavio

2013-01-01

discharge to SM3, and lower herbicide mass discharges to SM1 and SM2 were determined due to groundwater discharge rates and herbicide concentrations. SM1-sediment with the lowest abundance of tfdA gene classes had the slowest mineralization, whereas SM2- and SM3-sediments with more abundant tfdA genes had......To understand the role of abundance of tfdA gene classes belonging to β- and γ-proteobacteria on phenoxy acid herbicide degradation, streambed sediments were sampled around three seepage meters (SMs) installed in a landfill-impacted groundwater–surface water interface. Highest herbicide mass...... faster mineralization. The observed difference in mineralization rates between discharge zones was simulated by a Monod-based kinetic model, which confirmed the role of abundance of tfdA gene classes. This study suggests presence of specific degraders adapted to slow growth rate and high yield strategy...

Ultra-clean

International Nuclear Information System (INIS)

Hergenroether, K.

1987-01-01

No other method guarantees such a thorough cleaning of contaminated materials' surfaces. Only ultrasound can reach those cavities crevices and corners where any manual cleaning fails. Furthermore there is no cumbersome and time-consuming manual decontamination which often has to be carried out in glove boxes and hot cells. Depending on the design the cleaning effect can reach from removing adhering dirt particles to removing complete surface layers. (orig./PW) [de

Clean Energy Solutions Center: Assisting Countries with Clean Energy Policy

Science.gov (United States)

advice on financing instruments. In a recent keynote to the Climate and Clean Energy Investment Forum renewable energy technologies in the country. Informing Energy Access and Clean Energy Project Finance understanding and knowledge of how to design policies that enable financing and encourage investment in clean

Plasma cleaning of beamline optical components: Contamination and gas composition effects

International Nuclear Information System (INIS)

Rosenberg, R.A.; Smith, J.A.; Wallace, D.J.

1992-01-01

We have initiated a program to study the impact of gas composition on the carbon removal rate during plasma cleaning of optical components, and of possible contamination due to the plasma processing. The measurements were performed in a test chamber designed to simulate the geometry of the grating/Codling mirror section of a Grasshopper monochromator. Removal rates were determined for a direct-current (dc) (Al electrode) discharge using a quartz crystal microbalance coated with polymethylmethacrylate, located at the position of the grating. Auger electron spectroscopy analysis of strateg- ically located, gold-coated stainless steel samples was employed to determine contamination. The relative removal rates of the gases studied were 3% C 2 F 6 /O 2 much-gt O 2 +H 2 O>O 2 ∼N 2 O>H 2 >N 2 . Although the C 2 F 6 /O 2 gas mixture showed a 20 times greater removal rate than its nearest competitor, it also caused significant contamination to occur. Contamination studies were performed for both dc and radio-frequency (rf) discharges. For the dc discharge we found that great care must be taken in order to avoid Al contamination; for the rf discharge, significant Fe contamination was observed

High performance discharges and capabilities in Alcator C-Mod

International Nuclear Information System (INIS)

Porkolab, M.

1996-01-01

Alcator C-Mod is a compact, diverted, shaped, high magnetic field (B = 9 T) tokamak operating at the Massachusetts Institute of Technology Plasma Fusion Center. The machine interior is all metallic, and the walls and divertor region are covered with molybdenum tiles. The vacuum vessel is a continuous, thick wall stainless steel construction, prototypical of future fusion devices (e.g., ITER). Typical discharge cleaning utilizes ECDC, or electron-cyclotron discharge cleaning, in the steady state at low magnetic field (0.0875 T). While its dimensions are compact (R = 0.67 m, a = 0.22 m, K = 1.8), C-Mod is designed to operate up to 2.5 MA at 9.0 T magnetic field. To present date the machine has operated at currents up to 1.5 MA at B = 5.3 T, and magnetic fields up to 8.0 T at I p = 1.2 MA. Due to the high current density, line average densities of 4.0 x 10 20 m -3 are obtained with gas fueling, and peak densities in excess of 1.0 x 10 21 m -3 have been obtained with pellet fueling. Typical pulse lengths are up to 2.0 seconds, with a flat-top of typically 1.0 sec. Presently the device is equipped with 4.0 MW of ICRF heating power operating at 80 MHz, but this capability is being upgraded to 8.0 MW with the addition of 4.0 MW of tunable ICRF power operating at 40.80 MHz. A 20 pellet/pulse deuterium injector is operational, and a 4 pellet Li injector is also operational. To reduce the influx of metallic impurities during high power operation, recently boronization of the machine interior was begun prior to plasma discharges, this allowed plasma operation with full auxiliary power capability without excessive radiative power losses from the plasma core. 7 refs

Efficient methods of nanoimprint stamp cleaning based on imprint self-cleaning effect

Energy Technology Data Exchange (ETDEWEB)

Meng Fantao; Chu Jinkui [Key Laboratory for Micro/Nano Technology and System of Liaoning Province, Dalian University of Technology, 116024 Dalian (China); Luo Gang; Zhou Ye; Carlberg, Patrick; Heidari, Babak [Obducat AB, SE-20125 Malmoe (Sweden); Maximov, Ivan; Montelius, Lars; Xu, H Q [Division of Solid State Physics, Lund University, Box 118, S-22100 Lund (Sweden); Nilsson, Lars, E-mail: ivan.maximov@ftf.lth.se [Department of Food Technology, Engineering and Nutrition, Lund University, Box 117, S-22100 Lund (Sweden)

2011-05-06

Nanoimprint lithography (NIL) is a nonconventional lithographic technique that promises low-cost, high-throughput patterning of structures with sub-10 nm resolution. Contamination of nanoimprint stamps is one of the key obstacles to industrialize the NIL technology. Here, we report two efficient approaches for removal of typical contamination of particles and residual resist from stamps: thermal and ultraviolet (UV) imprinting cleaning-both based on the self-cleaning effect of imprinting process. The contaminated stamps were imprinted onto polymer substrates and after demolding, they were treated with an organic solvent. The images of the stamp before and after the cleaning processes show that the two cleaning approaches can effectively remove contamination from stamps without destroying the stamp structures. The contact angles of the stamp before and after the cleaning processes indicate that the cleaning methods do not significantly degrade the anti-sticking layer. The cleaning processes reported in this work could also be used for substrate cleaning.

How clean is clean?---How clean is needed?

International Nuclear Information System (INIS)

Hays, A.K.

1991-01-01

This paper will provide an overview of cleaning qualifications used in a variety of industries: from small-scale manufacturer's of precision-machined products to large-scale manufacturer's of electronics (printed wiring boards and surface mount technology) and microelectronics. Cleanliness testing techniques used in the production of precision-machined products, will be described. The on-going DOD program to obtain high-reliability electronics, through the use of military specifications for cleaning and cleanliness levels, will be reviewed. In addition, the continually changing cleanroom/materials standards of the microelectronics industry will be discussed. Finally, we will speculate on the role that new and improved analytical techniques and sensor technologies will play in the factories of the future. 4 refs., 1 tab

The Clean Development Mechanism and Sustainable Development in China's Electricity Sector

Institute of Scientific and Technical Information of China (English)

Paul A. Steenhof

2005-01-01

The Clean Development Mechanism,a flexibility mechanism contained in the Kyoto Protocol, offers China an important tool to attract investment in clean energy technology and processes into its electricity sector. The Chinese electricity sector places centrally in the country's economy and environment, being a significant contributor to the acid rain and air pollution problems that plague many of China's cities and regions, and therefore a focus of many related energy and environmental policies.China's electricity sector has also been the subject of a number of economic analyses that have showed that it contains the highest potential for clean energy investment through the Clean Development Mechanism of any economic sector in China. This mechanism, through the active participation from investors in more industrialized countries, can help alleviate the environmental problems attributable to electricity generation in China through advancing such technology as wind electricity generation, dean coal technology, high efficient natural gas electricity generation, or utilization of coal mine methane. In this context, the Clean Development Mechanism also compliments a range of environmental and energy policies which are strategizing to encourage the sustainable development of China's economy.

Chemical cleaning of PWR steam generators: application at Nogent 1

International Nuclear Information System (INIS)

Fiquet, J.M.; Veysset, J.P.; Esteban, L.; Saurin, P.

1990-01-01

EDF has developed and patented a chemical cleaning process for PWR steam generators, based on the use of a mixture of organic acids in order to: - dissolve iron oxides and copper with a single solution; - clean dented crevices. Qualification tests have permitted to demonstrate effectiveness of the solution and its inocuousness related to steam generator materials. The process, the license of which belongs to SOMAFER R.A. and FRAMATOME, has been implemented in France at Nogent. The goal was to dissolve iron oxides allowing metallic particles, aggregated on the tubesheet, to be released and mechanically removed. The effectiveness was satisfactory and this treatment is to be extended to other units [fr

Analysis of the Clean Air Act Amendments of 1990: A forecast of the electric utility industry response to Title IV, Acid Deposition Control

International Nuclear Information System (INIS)

Molburg, J.C.; Fox, J.A.; Pandola, G.; Cilek, C.M.

1991-10-01

The Clean Air Act Amendments of 1990 incorporate, for the first time, provisions aimed specifically at the control of acid rain. These provisions restrict emissions of sulfur dioxide (SO 2 ) and oxides of nitrogen (NO x ) from electric power generating stations. The restrictions on SO 2 take the form of an overall cap on the aggregate emissions from major generating plants, allowing substantial flexibility in the industry's response to those restrictions. This report discusses one response scenario through the year 2030 that was examined through a simulation of the utility industry based on assumptions consistent with characterizations used in the National Energy Strategy reference case. It also makes projections of emissions that would result from the use of existing and new capacity and of the associated additional costs of meeting demand subject to the emission limitations imposed by the Clean Air Act. Fuel-use effects, including coal-market shifts, consistent with the response scenario are also described. These results, while dependent on specific assumptions for this scenario, provide insight into the general character of the likely utility industry response to Title IV

Discharges to the environment and environmental protection at CEGB power stations

International Nuclear Information System (INIS)

Wright, J.K.

1981-01-01

The subject is discussed under the headings: introduction (scope of paper will cover the principles, methods and results obtained in environmental protection in relation to atmospheric discharges made routinely during power generation); air pollution control; nuclear power stations (type of discharge, annual discharges, environmental monitoring); fossil fuelled power stations; health effects; trace elements; long range transport and acid rain; future coal fired plant; carbon dioxide. (U.K.)

National Ignition Facility Incorporates P2/E2 in Aqueous Parts Cleaning of Optics Hardware

International Nuclear Information System (INIS)

Gabor, K

2001-01-01

When completed, Lawrence Livermore National Laboratory's (LLNL) National Ignition Facility (NIF) will be the world's largest laser with experimental capabilities applicable to stockpile stewardship, energy research, science and astrophysics. As construction of the conventional facilities nears completion, operations supporting the installation of specialized laser equipment have come online. Playing a critical role in the precision cleaning of mechanical parts from the NIF beamline are three pieces of aqueous cleaning equipment. Housed in the Optics Assembly Building (OAB), adjacent to NIF's laser bay, are the large mechanical parts gross cleaner (LMPGC), the large mechanical parts precision cleaner (LMPPC), and the small mechanical parts gross and precision cleaner (SMPGPC). These aqueous units, designed and built by Sonic Systems, Inc., of Newtown, Pennsylvania, not only accommodate parts that vary greatly in size, weight, geometry, surface finish and material, but also produce cleaned parts that meet the stringent NIF cleanliness standards (MIL-STD-1246C Level 83 for particles and A/10 for non-volatile residue). Each unit was designed with extensive water- and energy-conserving features, and the technology used minimizes hazardous waste generation associated with solvent wipe cleaning, the traditional method for cleaning laser mechanical components. The LMPGC provides preliminary gross cleaning for large mechanical parts. Collection, filtration and reuse of the wash and primary rinse water in the LMPGC limit its routine discharge to the volume of the low-pressure, deionized secondary rinse. After an initial gross cleaning in the LMPGC, a large mechanical part goes to the LMPPC. This piece of equipment, unique because of its size, consists of four 2700-gallon tanks. Parts held securely on specialized metal pallets (jointly weighing up to 1500 pounds) move through the tanks on an automated system. Operators program all movement, speeds and process times to

Clean coal technology and advanced coal-based power plants

International Nuclear Information System (INIS)

Alpert, S.B.

1991-01-01

Clean Coal Technology is an arbitrary terminology that has gained increased use since the 1980s when the debate over acid raid issues intensified over emissions of sulfur dioxide and nitrogen oxides. In response to political discussions between Prime Minister Brian Mulroney of Canada and President Ronald Reagan in 1985, the US government initiated a demonstration program by the Department of Energy (DOE) on Clean Coal Technologies, which can be categorized as: 1. precombustion technologies wherein sulfur and nitrogen are removed before combustion, combustion technologies that prevent or lower emissions as coal is burned, and postcombustion technologies wherein flue gas from a boiler is treated to remove pollutants, usually transforming them into solids that are disposed of. The DOE Clean Coal Technology (CCT) program is being carried out with $2.5 billion of federal funds and additional private sector funds. By the end of 1989, 38 projects were under way or in negotiation. These projects were solicited in three rounds, known as Clean Coal I, II, and III, and two additional solicitations are planned by DOE. Worldwide about 100 clean coal demonstration projects are being carried out. This paper lists important requirements of demonstration plants based on experience with such plants. These requirements need to be met to allow a technology to proceed to commercial application with ordinary risk, and represent the principal reasons that a demonstration project is necessary when introducing new technology

Surface modification of polyvinyl alcohol/malonic acid nanofibers by gaseous dielectric barrier discharge plasma for glucose oxidase immobilization

Science.gov (United States)

Afshari, Esmail; Mazinani, Saeedeh; Ranaei-Siadat, Seyed-Omid; Ghomi, Hamid

2016-11-01

Polymeric nanofiber prepares a suitable situation for enzyme immobilization for variety of applications. In this research, we have fabricated polyvinyl alcohol (PVA)/malonic acid nanofibers using electrospinning. After fabrication of nanofibers, the effect of air, nitrogen, CO2, and argon DBD (dielectric barrier discharge) plasmas on PVA/malonic acid nanofibers were analysed. Among them, air plasma had the most significant effect on glucose oxidase (GOx) immobilization. Attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectrum analysis and X-ray photoelectron spectroscopy (XPS) results revealed that in case of air plasma modified nanofibers, the carboxyl groups on the surface are increased. The scanning electron microscopy (SEM) images showed that, after GOx immobilization, the modified nanofibers with plasma has retained its nanofiber structure. Finally, we analysed reusability and storage stability of GOx immobilized on plasma modified and unmodified nanofibers. The results were more satisfactory for modified nanofibers with respect to unmodified ones.

Plasma pressure in the discharge column of the Novillo Tokamak

International Nuclear Information System (INIS)

Gaytan G, E.

1995-01-01

The design and construction of an acquisition system for the measurement of the plasma pressure in the Novillo Tokamak is described in detail. The system includes a high voltage ramp generator, a hardware and a software interface with a personal computer. It is used to determine experimentally the variations of the pressure in the plasma column in the cleaning and main discharges. The measurement of the pressure is made with a Pirani sensor adapted to the acquisition hardware and synchronized with the discharge in the plasma. The software is made in object oriented programming as a graphic interface designed to be used easily. It controls the acquisition, records the data, displays in graphic form the results and save the measurements. The graphic interface is a building block that can be used in different acquisition tasks. The ramp generator can deliver a signal of 200 V peak to peak with a current of 200 m A and offset control. The acquisition time is 2.5 μ s for every measurement, 8192 measurements can be stored in the acquisition board for every discharge. (Author)

Clean data

CERN Document Server

Squire, Megan

2015-01-01

If you are a data scientist of any level, beginners included, and interested in cleaning up your data, this is the book for you! Experience with Python or PHP is assumed, but no previous knowledge of data cleaning is needed.

Annealing free, clean graphene transfer using alternative polymer scaffolds.

Science.gov (United States)

Wood, Joshua D; Doidge, Gregory P; Carrion, Enrique A; Koepke, Justin C; Kaitz, Joshua A; Datye, Isha; Behnam, Ashkan; Hewaparakrama, Jayan; Aruin, Basil; Chen, Yaofeng; Dong, Hefei; Haasch, Richard T; Lyding, Joseph W; Pop, Eric

2015-02-06

We examine the transfer of graphene grown by chemical vapor deposition (CVD) with polymer scaffolds of poly(methyl methacrylate) (PMMA), poly(lactic acid) (PLA), poly(phthalaldehyde) (PPA), and poly(bisphenol A carbonate) (PC). We find that optimally reactive PC scaffolds provide the cleanest graphene transfers without any annealing, after extensive comparison with optical microscopy, x-ray photoelectron spectroscopy, atomic force microscopy, and scanning tunneling microscopy. Comparatively, films transferred with PLA, PPA, PMMA/PC, and PMMA have a two-fold higher roughness and a five-fold higher chemical doping. Using PC scaffolds, we demonstrate the clean transfer of CVD multilayer graphene, fluorinated graphene, and hexagonal boron nitride. Our annealing free, PC transfers enable the use of atomically-clean nanomaterials in biomolecule encapsulation and flexible electronic applications.

Annealing free, clean graphene transfer using alternative polymer scaffolds

International Nuclear Information System (INIS)

Wood, Joshua D; Doidge, Gregory P; Carrion, Enrique A; Koepke, Justin C; Datye, Isha; Behnam, Ashkan; Hewaparakrama, Jayan; Aruin, Basil; Chen, Yaofeng; Lyding, Joseph W; Kaitz, Joshua A; Dong, Hefei; Haasch, Richard T; Pop, Eric

2015-01-01

We examine the transfer of graphene grown by chemical vapor deposition (CVD) with polymer scaffolds of poly(methyl methacrylate) (PMMA), poly(lactic acid) (PLA), poly(phthalaldehyde) (PPA), and poly(bisphenol A carbonate) (PC). We find that optimally reactive PC scaffolds provide the cleanest graphene transfers without any annealing, after extensive comparison with optical microscopy, x-ray photoelectron spectroscopy, atomic force microscopy, and scanning tunneling microscopy. Comparatively, films transferred with PLA, PPA, PMMA/PC, and PMMA have a two-fold higher roughness and a five-fold higher chemical doping. Using PC scaffolds, we demonstrate the clean transfer of CVD multilayer graphene, fluorinated graphene, and hexagonal boron nitride. Our annealing free, PC transfers enable the use of atomically-clean nanomaterials in biomolecule encapsulation and flexible electronic applications. (paper)

Milliken Clean Coal Technology Demonstration Project. Environmental monitoring report, July--September 1996

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-05-01

New York State Electric and Gas Corporation (NYSEG) has installed and is presently operating a high-efficiency flue gas desulfurization (FGD) system to demonstrate innovative emissions control technology and comply with the Clean Air Act Amendments of 1990. The host facility for this demonstration project is NYSEG`s Milliken Station, in the Town of Lansing, New York. The primary objective of this project is to demonstrate a retrofit of energy-efficient SO{sub 2} and NO{sub x} control systems with minimal impact on overall plant efficiency. The demonstration project has added a forced oxidation, formic acid-enhanced wet limestone FGD system, which is expected to reduce SO{sub 2} emissions by at least 90 percent. NYSEG also made combustion modifications to each boiler and plans to demonstrate selective non-catalytic reduction (SNCR) technology on unit 1, which will reduce NO{sub x} emissions. Goals of the proposed demonstration include up to 98 percent SO{sub 2} removal efficiency while burning high-sulfur coal, 30 percent NO{sub x} reductions through combustion modifications, additional NO{sub x} reductions using SNCR technology, production of marketable commercial-grade gypsum and calcium chloride by-products to minimize solid waste disposal, and zero wastewater discharge.

Plasma cleaning techniques and future applications in environmentally conscious manufacturing

Energy Technology Data Exchange (ETDEWEB)

Ward, P.P.

1995-07-01

Plasmas have frequently been used in industry as a last step surface preparation technique in an otherwise predominantly wet-etch process. The limiting factor in the usefulness of plasma cleaning techniques has been the rate at which organic materials are removed. Recent research in the field of plasma chemistry has provided some understanding of plasma processes. By controlling plasma conditions and gas mixtures, ultra-fast plasma cleaning and etching is possible. With enhanced organic removal rates, plasma processes become more desirable as an environmentally sound alternative to traditional solvent or acid dominated process, not only as a cleaning tool, but also as a patterning and machining tool. In this paper, innovations in plasma processes are discussed including enhanced plasma etch rates via plasma environment control and aggressive gas mixtures. Applications that have not been possible with the limited usefulness of past plasma processes are now approaching the realm of possibility. Some of these possible applications will be discussed along with their impact to environmentally conscious manufacturing.

High-resolution clean-sc

NARCIS (Netherlands)

Sijtsma, P.; Snellen, M.

2016-01-01

In this paper a high-resolution extension of CLEAN-SC is proposed: HR-CLEAN-SC. Where CLEAN-SC uses peak sources in “dirty maps” to define so-called source components, HR-CLEAN-SC takes advantage of the fact that source components can likewise be derived from points at some distance from the peak,

Controlling the clean room atmosphere

International Nuclear Information System (INIS)

Meeks, R.F.

1979-01-01

Several types of clean rooms are commonly in use. They include the conventional clean room, the horizontal laminar flow clean room, the vertical laminar flow clean room and a fourth type that incorporates ideas from the previous types and is known as a clean air bench or hood. These clean rooms are briefly described. The origin of contamination and methods for controlling the contamination are discussed

Destruction of 4-phenolsulfonic acid in water by anodic contact glow discharge electrolysis.

Science.gov (United States)

Yang, Haiming; An, Baigang; Wang, Shaoyan; Li, Lixiang; Jin, Wenjie; Li, Lihua

2013-06-01

Destruction of 4-phenolsulfonic acid (4-PSA) in water was carried out using anodic contact glow discharge electrolysis. Accompanying the decay of 4-PSA, the amount of total organic carbon (TOC) in water correspondingly decreased, while the sulfonate group of 4-PSA was released as sulfate ion. Oxalate and formate were obtained as minor by-products. Additionally, phenol, 1,4-hydroquinone, hydroxyquinol and 1,4-benzoquinone were detected as primary intermediates in the initial stages of decomposition of 4-PSA. A reaction pathway involving successive attacks of hydroxyl and hydrogen radicals was assumed on the basis of the observed products and kinetics. It was revealed that the decay of both 4-PSA and TOC obeyed a first-order rate law. The effects of different Fe ions and initial concentrations of 4-PSA on the degradation rate were investigated. It was found that the presence of Fe ions could increase the degradation rate of 4-PSA, while initial concentrations lower than 80 mmol/L had no significant effect on kinetic behaviour. The disappearance rate of 4-PSA was significantly affected by pH.

Deep cleaning of a metallurgical zinc leaching residue and recovery of valuable metals

Science.gov (United States)

Xing, Peng; Ma, Bao-zhong; Zeng, Peng; Wang, Cheng-yan; Wang, Ling; Zhang, Yong-lu; Chen, Yong-qiang; Wang, Shuo; Wang, Qiu-yin

2017-11-01

Huge quantities of zinc leaching residues (ZLRs) generated from zinc production are dumped continuously around the world and pose a potential environmental threat because of their considerable amounts of entrained heavy metals (mainly lead). Most ZLRs have not been properly treated and the valuable metals in them have not yet been effectively recovered. Herein, the deep cleaning of a ZLR and recovery of valuable metals via a hydrometallurgical route were investigated. The cleaning process consists of two essential stages: acid leaching followed by calcium chloride leaching. The optimum conditions for extracting zinc, copper, and indium by acid leaching were a sulfuric acid concentration of 200 g·L-1, a liquid/solid ratio of 4:1 (mL/g), a leaching time of 2 h, and a temperature of 90°C. For lead and silver extractions, the optimum conditions were a calcium chloride concentration of 400 g·L-1, a pH value of 1.0, a leaching time of 1 h, and a temperature of 30°C. After calcium chloride leaching, silver and lead were extracted out and the lead was finally recovered as electrolytic lead by electrowinning. The anglesite phase, which poses the greatest potential environmental hazard, was removed from the ZLR after deep cleaning, thus reducing the cost of environmental management of ZLRs. The treatment of chlorine and spent electrolyte generated in the process was discussed.

Evaluation of boiler chemical cleaning techniques

International Nuclear Information System (INIS)

1993-04-01

The EPRI/SGOG process, which has been selected by Ontario Hydro for use at the Bruce A station, is described. This process consists of alternating iron removal and copper removal steps, the two metals which comprise the bulk of the deposit in the Bruce A SGs. The iron removal solvent consists of ethylenediameinetetraacetic acid (EDTA), hydrazine, ammonium hydroxide and a proprietary corrosion inhibitor CCI-801. The copper removal solvent consists of EDTA, ethylene diamine and hydrogen peroxide. Ontario Hydro proposes to clean a bank of four SGs in parallel employing a total of six copper removal steps and four iron removal steps. Cleaning all eight SGs in a single Bruce A unit will generate 2,200 m 3 of liquid waste which will be treated by a wet air oxidation process. The iron and copper sludges will be buried in a landfill site while the liquid waste will be further treated by the Bruce sewage treatment plant. Some ammonia vapour will be generated through the wet air oxidation process and will be vented through a stack on top of the high bay of the spent solvent treatment plant. With the exception of the proprietary corrosion inhibitor, all chemicals that will be employed in the cleaning and waste treatment operations are standard industrial chemicals which are well characterized. No extraordinary hazards are anticipated with their use as long as adequate safety precautions are taken

Consistent approach to air-cleaning system duct design

International Nuclear Information System (INIS)

Miller, W.H.; Ornberg, S.C.; Rooney, K.L.

1981-01-01

Nuclear power plant air-cleaning system effectiveness is dependent on the capability of a duct system to safely convey contaminated gas to a filtration unit and subsequently to a point of discharge. This paper presents a logical and consistent design approach for selecting sheet metal ductwork construction to meet applicable criteria. The differences in design engineers' duct construction specifications are acknowledged. Typical duct construction details and suggestions for their effective use are presented. Improvements in duct design sections of ANSI/ASME N509-80 are highlighted. A detailed leakage analysis of a control room HVAC system is undertaken to illustrate the effects of conceptual design variations on duct construction requirements. Shortcomings of previously published analyses and interpretations of a current standard are included

Ship for the cleaning of water from oil, fuel oil, and other floating objects

Energy Technology Data Exchange (ETDEWEB)

Nentvih, V

1969-12-31

The newly designed ship for the cleaning of water surface from floating pollution has its bow section built much lower than its main hull. A slanted platform leads to a channel guiding the water into a centrifuge which separates oil from water. Oil proceeds to a reservoir for reprocessing while water is discharged from the ship. A variable ballast controls the depth of submersion of the platform. The ship is equilibrated by means of a built-in air float.

The Clean Coal Program's contributions to addressing the requirements of the Clean Air Act Amendments of 1990

International Nuclear Information System (INIS)

Miller, R.L.

1992-01-01

The purpose of this paper is to examine the potential contributions of the US Department of Energy's Clean Coal Program (CCP) to addressing the requirements of the Clean Air Act (CAA) Amendments of 1990 (CAA90). Initially funded by Congress in 1985, the CCP is a government and industry co-funded effort to demonstrate a new generation of more efficient, economically feasible, and environmentally acceptable coal technologies in a series of full- scale ''showcase'' facilities built across the country. The CCP is expected to provide funding for more than $5 billion of projects during five rounds of competition, with at least half of the funding coming from the private sector. To date, 42 projects have been selected in the first 4 rounds of the CCP. The CAA and amendments form the basis for regulating emissions of air pollutants to protect health and the environment throughout the United States. Although the origin of the CAA can be traced back to 1955, many amendments passed since that time are testimony to the iterative process involved in the regulation of air pollution. Three key components of CAA90, the first major amendments to the CAA since 1977, include mitigation measures to reduce levels of (1) acid deposition, (2) toxic air pollutants, and (3) ambient concentrations of air pollutants. This paper focuses on the timeliness of clean coal technologies in contributing to these provisions of CAA90

Is dry cleaning all wet?

International Nuclear Information System (INIS)

Ryan, M.

1993-01-01

Chemical solvents from dry cleaning, particularly perchloroethylene (perc), have contributed to groundwater contamination, significant levels of air pollution in and around cleaners, and chemical accumulation in food. Questions are being raised about the process of cleaning clothes with chemical, and other less toxic cleaning methods are being explored. The EPA has focused attention on the 50 year old Friedburg method of cleaning, Ecoclean, which uses no dangerous chemicals and achieves comparable results. Unfortunately, the cleaning industry is resistant to change, so cutting back on amount of clothes that need dry cleaning and making sure labels aren't exaggerating when they say dry clean only, is frequently the only consumer option now

Analysis of the Clean Air Act Amendments of 1990: A forecast of the electric utility industry response to Title IV, Acid Deposition Control

Energy Technology Data Exchange (ETDEWEB)

Molburg, J.C.; Fox, J.A.; Pandola, G.; Cilek, C.M.

1991-10-01

The Clean Air Act Amendments of 1990 incorporate, for the first time, provisions aimed specifically at the control of acid rain. These provisions restrict emissions of sulfur dioxide (SO{sub 2}) and oxides of nitrogen (NO{sub x}) from electric power generating stations. The restrictions on SO{sub 2} take the form of an overall cap on the aggregate emissions from major generating plants, allowing substantial flexibility in the industry`s response to those restrictions. This report discusses one response scenario through the year 2030 that was examined through a simulation of the utility industry based on assumptions consistent with characterizations used in the National Energy Strategy reference case. It also makes projections of emissions that would result from the use of existing and new capacity and of the associated additional costs of meeting demand subject to the emission limitations imposed by the Clean Air Act. Fuel-use effects, including coal-market shifts, consistent with the response scenario are also described. These results, while dependent on specific assumptions for this scenario, provide insight into the general character of the likely utility industry response to Title IV.

Analysis of the Clean Air Act Amendments of 1990: A forecast of the electric utility industry response to Title IV, Acid Deposition Control

Energy Technology Data Exchange (ETDEWEB)

Molburg, J.C.; Fox, J.A.; Pandola, G.; Cilek, C.M.

1991-10-01

The Clean Air Act Amendments of 1990 incorporate, for the first time, provisions aimed specifically at the control of acid rain. These provisions restrict emissions of sulfur dioxide (SO[sub 2]) and oxides of nitrogen (NO[sub x]) from electric power generating stations. The restrictions on SO[sub 2] take the form of an overall cap on the aggregate emissions from major generating plants, allowing substantial flexibility in the industry's response to those restrictions. This report discusses one response scenario through the year 2030 that was examined through a simulation of the utility industry based on assumptions consistent with characterizations used in the National Energy Strategy reference case. It also makes projections of emissions that would result from the use of existing and new capacity and of the associated additional costs of meeting demand subject to the emission limitations imposed by the Clean Air Act. Fuel-use effects, including coal-market shifts, consistent with the response scenario are also described. These results, while dependent on specific assumptions for this scenario, provide insight into the general character of the likely utility industry response to Title IV.

Hazardous gas treatment by atmospheric discharges

International Nuclear Information System (INIS)

Mizeraczyk, J.

2005-01-01

The emissions of NO x ; SO x , CO 2 and volatile organic compounds (VOCs) including fluorocarbons to the atmosphere influence heavily our environment, NO x and SO x emitted to the atmosphere are the major cause of acid rains, while CO 2 and VOCs emissions cause the greenhouse effect which leads to abnormal global heating of the atmosphere and creating in a temperature inversion layer that traps gaseous pollutants. Therefore, there is an increasing interest in controlling these emissions. A new technique, which uses the plasma processes induced by energetic electrons, emerges as one of the most effective methods of reducing concentrations of the emitted gaseous pollutants. Various plasma techniques have been tested for gaseous pollution control. The electron bean irradiation was found to be physically and economically efficient for NO x and SO x reduction in the exhaust gases from electrical and heat power plants. The capability of the non-thermal plasmas, produced in atmospheric pressure electrical discharges, for decomposition of the gaseous pollutants has been widely tested. These atmospheric pressure electrical discharges are dielectric barrier discharges, pulsed and de corona discharges (in the reactors with the point-to-plate, wire-cylinder and wire-plate geometries, in the reactors with flow stabilized corona torch and corona radical shower), gliding discharges, inductively coupled high-frequency discharges, ac surface discharges, ac discharges in the packed bed reactors, and microwave torch discharges. In this paper, after reviewing the methods and devices used for producing the non-thermal plasmas for gaseous pollutant control, some results of the laboratory experiments on the plasmas abatement of NO x ; SO x and various VOCs will be presented, followed by a discussion on the energy efficiency and by-products. Also some results obtained in the pilot-plants will be given. finally other possible applications of the presented plasma devices for controlling

Plasma cleaning for waste minimization

Energy Technology Data Exchange (ETDEWEB)

Ward, P.P.

1993-07-01

Although plasma cleaning is a recognized substitute for solvent cleaning in removing organic contaminants, some universal problems in plasma cleaning processes prevent wider use of plasma techniques. Lack of understanding of the fundamental mechanisms of the process, unreliable endpoint detection techniques, and slow process times make plasma cleaning processes less than desirable. Our approach to address these plasma cleaning problems is described. A comparison of plasma cleaning rates of oxygen and oxygen/sulfur hexafluoride gases shows that fluorine-containing plasmas can enhance etch rates by 400% over oxygen alone. A discussion of various endpoint indication techniques is discussed and compared for application suitability. Work toward a plasma cleaning database is discussed. In addition to the global problems of plasma cleaning, an experiment where the specific mixed-waste problem of removal of machine oils from radioactive scrap metal is discussed.

WINDOW-CLEANING

CERN Multimedia

Environmental Section / ST-TFM

2001-01-01

The two-month window-cleaning session on the Meyrin, Prévessin and LEP sites will soon begin. The cleaning contractors will work from Monday to Saturday, every week from 4.00 a.m. to 8.00 p.m. The work will be organised so as to disturb users as little as possible. In any event, a work notice will be left in each office 24 hours beforehand. To prevent any damage to documents or items which could occur despite the precautions taken, please clear completely the window-sills and the area immediately around them. If, however, for valid reasons, the work cannot be done on the scheduled day, please inform the Environmental Section by telephoning: 73753 / 74233 / 72242 If you are going to be absent during this two-month period, we should be grateful if you would clear the above mentioned areas before your departure. REMINDER To allow more thorough cleaning of the entrance doors to buildings and also facilitate the weekly work of the cleaning contractors, we ask you to make use of the notice boards at the...

Avalanche boron fusion by laser picosecond block ignition with magnetic trapping for clean and economic reactor

Czech Academy of Sciences Publication Activity Database

Hora, H.; Korn, Georg; Eliezer, S.; Nissim, N.; Lalousis, P.; Giuffrida, Lorenzo; Margarone, Daniele; Picciotto, A.; Miley, G. H.; Moustaizis, S.; Martinez-Val, J.M.; Barty, C.P.J.; Kirchhoff, G.J.

2016-01-01

Roč. 4, Oct (2016), 1-9, č. článku e35. ISSN 2095-4719 R&D Projects: GA MŠk EF15_008/0000162 Grant - others:ELI Beamlines(XE) CZ.02.1.01/0.0/0.0/15_008/0000162 Institutional support: RVO:68378271 Keywords : boron fusion energy * dielectric nonlinear force explosion * economic reactor * environmentally clean energy Subject RIV: BL - Plasma and Gas Discharge Physics

ALTERNATIVE AND ENHANCED CHEMICAL CLEANING: BASIC STUDIES RESULTS FY2010

Energy Technology Data Exchange (ETDEWEB)

King, W.; Hay, M.

2011-01-24

In an effort to develop and optimize chemical cleaning methods for the removal of sludge heels from High Level Waste tanks, solubility tests have been conducted using nonradioactive, pure metal phases. The metal phases studied included the aluminum phase gibbsite and the iron phases hematite, maghemite, goethite, lepidocrocite, magnetite, and wustite. Many of these mineral phases have been identified in radioactive, High Level Waste sludge at the Savannah River and Hanford Sites. Acids evaluated for dissolution included oxalic, nitric, and sulfuric acids and a variety of other complexing organic acids. The results of the solubility tests indicate that mixtures of oxalic acid with either nitric or sulfuric acid are the most effective cleaning solutions for the dissolution of the primary metal phases in sludge waste. Based on the results, optimized conditions for hematite dissolution in oxalic acid were selected using nitric or sulfuric acid as a supplemental proton source. Electrochemical corrosion studies were also conducted (reported separately; Wiersma, 2010) with oxalic/mineral acid mixtures to evaluate the effects of these solutions on waste tank integrity. The following specific conclusions can be drawn from the test results: (1) Oxalic acid was shown to be superior to all of the other organic acids evaluated in promoting the dissolution of the primary sludge phases. (2) All iron phases showed similar solubility trends in oxalic acid versus pH, with hematite exhibiting the lowest solubility and the slowest dissolution. (3) Greater than 90% hematite dissolution occurred in oxalic/nitric acid mixtures within one week for two hematite sources and within three weeks for a third hematite sample with a larger average particle size. This dissolution rate appears acceptable for waste tank cleaning applications. (4) Stoichiometric dissolution of iron phases in oxalic acid (based on the oxalate concentration) and the formation of the preferred 1:1 Fe to oxalate complex

Establishment of a clean chemistry laboratory at JAERI. Clean laboratory for environmental analysis and research (CLEAR)

Energy Technology Data Exchange (ETDEWEB)

Hanzawa, Yukiko; Magara, Masaaki; Watanabe, Kazuo [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment; and others

2003-02-01

The JAERI has established a facility with a cleanroom: the Clean Laboratory for Environmental Analysis and Research (CLEAR). This report is an overview of the design, construction and performance evaluation of the CLEAR in the initial stage of the laboratory operation in June 2001. The CLEAR is a facility to be used for analyses of ultra trace amounts of nuclear materials in environmental samples for the safeguards, for the CTBT verification and for researches on environmental sciences. One of the special features of the CLEAR is that it meets double requirements of a cleanroom and for handling of nuclear materials. As another feature of the CLEAR, much attention was paid to the construction materials of the cleanroom for trace analysis of metal elements using considerable amounts of corrosive acids. The air conditioning and purification system, specially designed experimental equipment to provide clean work surfaces, utilities and safety systems are also demonstrated. The potential contamination from the completed cleanroom atmosphere during the analytical procedure was evaluated. It can be concluded that the CLEAR has provided a suitable condition for reliable analysis of ultra trace amounts of nuclear materials and other heavy elements in environmental samples. (author)

Wet precipitators for sulphuric acid plants

International Nuclear Information System (INIS)

Ojanpera, R.O.

1989-01-01

Both the service requirements and design construction details have changed considerably in recent years for wet electrostatic precipitators as used for gas cleaning ahead of metallurgical sulphuric acid plants. Increased concern over acid quality has resulted in more emphasis on dust efficiencies compared to collection of acid mist. Also, higher static operating pressures have caused large structural loads on casing and internal components. In this paper these two issues are addressed in the following ways: Recognition that all dusts do not collect similarly. The mechanism by which various dusts collect affect the design of the entire wet gas cleaning system. Use of both traditional and newer materials of construction to accommodate the higher design pressures while still maintaining corrosion resistance

Current Performance of an Aerobic Passive Wetlands Treating Acid Mine Drainage Flow From Underground Mine Seals at Moraine State Park, Butler County, Pennsylvania

Science.gov (United States)

Winter, J. A.; Fredrick, K.

2008-12-01

Coal mining was conducted in the area of Moraine State Park prior to the establishing the park and associated Lake Arthur. A total of 69 underground mine entries were sealed during the 1960's to the early 1970's along the proposed northern shore of Lake Arthur. Seals were constructed using a flyash/cement mixture that was pumped into boreholes to place bulkheads in the mine entries, then filling between the bulkheads, and injecting grout into the adjacent strata to form a grout curtain. During 1979 and 1980, a study was performed by the United States Department of the Interior, Bureau of Mines, to determine the long term effectiveness of the underground mine sealing and reclamation work. Not all seals were successful. One of these mine entry seals was leaking and depositing iron hydroxides on the shoreline. During 1995-96, a passive wetlands treatment system was designed and constructed to treat an acid mine drainage (amd) discharge emanating from one of these sealed mines. The system consists of a primary settling pond, a cattail vegetated pond, and a final polishing pond prior to discharge to Lake Arthur. The design life of the system was estimated at twelve years. After twelve years it was believed the precipitate in the ponds would need to be removed and the system rehabilitated to continue treating the amd discharge. A maintenance plan was considered, however only minimal maintaining of the area was implemented. Six sets of water quality samples were collected and analyzed for standard amd parameters of alkalinity, acidity, pH, iron, manganese, aluminum, sulfate, and total suspended solids. Precipitation data and flow rates were collected and an analysis was done to determine if flow varied seasonally. The water quality data was compared to flow and precipitation amounts. Sludge precipitate samples were collected from the first settling pond to estimate the deposition rate and to determine how long the ponds can continue to function before they would require

Automated cleaning of electronic components

International Nuclear Information System (INIS)

Drotning, W.; Meirans, L.; Wapman, W.; Hwang, Y.; Koenig, L.; Petterson, B.

1994-01-01

Environmental and operator safety concerns are leading to the elimination of trichloroethylene and chlorofluorocarbon solvents in cleaning processes that remove rosin flux, organic and inorganic contamination, and particulates from electronic components. Present processes depend heavily on these solvents for manual spray cleaning of small components and subassemblies. Use of alternative solvent systems can lead to longer processing times and reduced quality. Automated spray cleaning can improve the quality of the cleaning process, thus enabling the productive use of environmentally conscious materials, while minimizing personnel exposure to hazardous materials. We describe the development of a prototype robotic system for cleaning electronic components in a spray cleaning workcell. An important feature of the prototype system is the capability to generate the robot paths and motions automatically from the CAD models of the part to be cleaned, and to embed cleaning process knowledge into the automatically programmed operations

Angina - discharge

Science.gov (United States)

Chest pain - discharge; Stable angina - discharge; Chronic angina - discharge; Variant angina - discharge; Angina pectoris - discharge; Accelerating angina - discharge; New-onset angina - discharge; Angina-unstable - discharge; ...

Seasonal Arsenic Accumulation in Stream Sediments at a Groundwater Discharge Zone

DEFF Research Database (Denmark)

MacKay, Allison A.; Gan, Ping; Yu, Ran

2014-01-01

Seasonal changes in arsenic and iron accumulation rates were examined in the sediments of a brook that receives groundwater discharges of arsenic and reduced iron. Clean glass bead columns were deployed in sediments for known periods over the annual hydrologic cycle to monitor changes in arsenic...... and iron concentrations in bead coatings. The highest accumulation rates occurred during the dry summer period (July-October) when groundwater discharges were likely greatest at the sample locations. The intermediate flow period (October-March), With higher surface water: levels, was associated with losses...... of arsenic and iron from bead column coatings at. depths below 2-6 cm. Batch incubations indicated iron releases from solids to be induced by biological reduction of iron (oxy)hydroxide solids. Congruent arsenic releases during incubation were limited by the high arsenic sorption capacity (0.536 mg...

Doping of magnetite nanoparticles facilitates clean harvesting of diatom oil as biofuel for sustainable energy

Science.gov (United States)

Kumar, Vikas; Singh, Ramesh; Thakur, Shipra; Ballabh Joshi, Khashti; Vinayak, Vandana

2018-04-01

Photosynthetic unicellular brown algae diatoms are considered as photobioreactors (PBRs) that synthesize and store oil in the form of lipid droplets and the much of the crude oil we use comes from fossil diatoms. The clean extraction of this crude oil from diatoms is difficult task. The construction of green chemical protocols for the clean separation of diatom oil from cells without killing or to harm the diatom cells is still in its primitive stage. In this report we would like to propose that facile doping of magnetite on diatoms can be used for clean oil separation in PBRs. We doped magnetite nanoparticles onto the surface of diatom Diadesmis confervaceae a diatom which oozes oil naturally. Doping magnetite onto diatoms can also facilitate easy separation of oil when cells are kept in an electromagnetic field. The cell wall of diatom besides having SiOH group has 281 amino acids of which 187–188 amino acids are conserved and are known for metal binding sites. The magnetite nanoparticles bind to the SiOH groups and metal binding sites of amino acids. The presence of appropriate amine functionalized linkers forming peptide aminosilane shells can further facilitate the binding of peptide/polypeptides which can be used in drug delivery. Besides this the magnetite doped diatoms have wide applications in removal of phosphates and chromium from waste water too.

Advanced mask cleaning for 0.20-μm technology: an integrated user-supplier approach

Science.gov (United States)

Poschenrieder, Rudolf; Hay, Bernd; Beier, Matthias; Hourd, Andrew C.; Stuemer, Harald; Gairing, Thomas M.

1998-12-01

A newly developed photomask final cleaning system, STEAG HamaTech's Advanced Single Substrate Cleaner, ASC 500, was assessed and optimized at the Siemens mask shop in Munich, Germany, under production conditions within the Esprit European Semiconductor Equipment Assessment programme (SEA). The project was carried out together with the active participation of Compugraphics Intl. Ltd. (UK), DuPont Photomasks, Inc. (Germany; Photronics-MZD, Germany). The results of the assessment are presented, focusing on the cleaning performance at the 0.25 micrometer defect level on photomasks, equipment reliability and Cost of Ownership data. A reticle free of soft defects on glass and on chrome down to the 0.25 micrometer level requires an excellent cleaning process and the use of high-end inspection tools like the KLA STARlight. In order to get a full understanding of the nature of the detected features additional investigations on the blank quality have been carried out. These investigations include the questions whether a detection is a hard or a soft defect and whether small defects on chrome are able to move on the reticle surface. Final cleaning recipes have been optimized in respect to cleaning efficiency while maintaining high throughput and low Cost of Ownership. A benchmark comparison against other final cleaning tools at the partner's maskshops showed the leading data of the ASC 500. It was found that a cleaning program which includes several substrate flips and a combination of the available cleaning methods acid- dispense, water pressure jet clean, brush and megasonic clean was best suitable to achieve these goals. In particular the use of the brush unit was shown to improve the yield while not adding damage to the plate.

Reactor water clean-up device

International Nuclear Information System (INIS)

Tanaka, Koji; Egashira, Yasuo; Shimada, Fumie; Igarashi, Noboru.

1983-01-01

Purpose: To save a low temperature reactor water clean-up system indispensable so far and significantly simplify the system by carrying out the reactor water clean-up solely in a high temperature reactor water clean-up system. Constitution: The reactor water clean-up device comprises a high temperature clean-up pump and a high temperature adsorption device for inorganic adsorbents. The high temperature adsorption device is filled with amphoteric ion adsorbing inorganic adsorbents, or amphoteric ion adsorbing inorganic adsorbents and anionic adsorbing inorganic adsorbents. The reactor water clean-up device introduces reactor water by the high temperature clean-up pump through a recycling system to the high temperature adsorption device for inorganic adsorbents. Since cations such as cobalt ions and anions such as chlorine ions in the reactor water are simultaneously removed in the device, a low temperature reactor water clean-up system which has been indispensable so far can be saved to realize the significant simplification for the entire system. (Seki, T.)

Microbial water quality in clean water tanks following inspection and cleaning

DEFF Research Database (Denmark)

Christensen, Sarah Christine Boesgaard; Esbjørn, Anne; Mollerup, Finn

Increased bacterial counts are often registered in drinking water leaving clean water tanks after the tanks have been emptied, inspected and cleaned by flushing. To investigate the reason for the increased bacterial concentrations and consequently limit it, samples from two clean water tanks befo...... start-up of the tanks, which may indicate that a substantial part of the bacteria in the drinking water leaving the tanks originated from the sand filter. This was supported by 16S DNA analyses....

Fouling characteristics and cleaning strategies of NF membranes for the advanced treatment of antibiotic production wastewater.

Science.gov (United States)

Wang, Jianxing; Li, Kun; Yu, Dawei; Zhang, Junya; Wei, Yuansong

2017-04-01

The nanofiltration (NF) membrane fouling characteristics and cleaning strategies were investigated through a laboratory-scale NF fouling test treating membrane bioreactor (MBR) effluent and MBR-granular activated carbon (GAC) effluent of an antibiotic production wastewater by DK and NF90 membranes, respectively. Results showed that organic fouling is the main NF membrane fouling for treating both the MBR effluent and MBR-GAC effluent. Soluble microbial by-product (SMP)-like and aromatic protein-like substances were the dominant components in the foulants, whereas humic-like substances had little contribution to the NF fouling. The fouling of DK was more severe than that of NF90. However, foulants respond by UV 254 were more easily to foul NF90 membrane. It could get satisfactory effect using combined cleaning of acid (HCl, pH 2.0∼2.5) and alkali (NaOH + 0.3 wt% NaDS, pH 10.0∼10.5). The favorable cleaning strategy is "acid + alkali" for treating MBR-GAC effluent, while it is "alkali + acid" for treating MBR effluent.

Acid fractionation for low level liquid waste cleanup and recycle

International Nuclear Information System (INIS)

Gombert, D. II; McIntyre, C.V.; Mizia, R.E.; Schindler, R.E.

1990-01-01

At the Idaho Chemical Processing Plant, low level liquid wastes containing small amounts of radionuclides are concentrated via a thermosyphon evaporator for calcination with high level waste, and the evaporator condensates are discharged with other plant wastewater to a percolation pond. Although all existing discharge guidelines are currently met, work has been done to reduce all waste water discharges to an absolute minimum. In this regard, a 15-tray acid fractionation column will be used to distill the mildly acidic evaporator condensates into concentrated nitric acid for recycle in the plant. The innocuous overheads from the fractionator having a pH greater than 2, are superheated and HEPA filtered for atmospheric discharge. Nonvolatile radionuclides are below detection limits. Recycle of the acid not only displaces fresh reagent, but reduces nitrate burden to the environment, and completely eliminates routine discharge of low level liquid wastes to the environment

Limonene and tetrahydrofurfuryl alcohol cleaning agent

Science.gov (United States)

Bohnert, George W.; Carter, Richard D.; Hand, Thomas E.; Powers, Michael T.

1996-05-07

The present invention is a tetrahydrofurfuryl alcohol and limonene or terpineol cleaning agent and method for formulating and/or using the cleaning agent. This cleaning agent effectively removes both polar and nonpolar contaminants from various electrical and mechanical parts and is readily used without surfactants, thereby reducing the need for additional cleaning operations. The cleaning agent is warm water rinsable without the use of surfactants. The cleaning agent can be azeotropic, enhancing ease of use in cleaning operations and ease of recycling.

Limonene and tetrahydrofurfurly alcohol cleaning agent

Science.gov (United States)

Bohnert, George W.; Carter, Richard D.; Hand, Thomas E.; Powers, Michael T.

1997-10-21

The present invention is a tetrahydrofurfuryl alcohol and limonene cleaning agent and method for formulating and/or using the cleaning agent. This cleaning agent effectively removes both polar and nonpolar contaminants from various electrical and mechanical parts and is readily used without surfactants, thereby reducing the need for additional cleaning operations. The cleaning agent is warm water rinsable without the use of surfactants. The cleaning agent can be azeotropic, enhancing ease of use in cleaning operations and ease of recycling.

Clean Hands Count

Medline Plus

Full Text Available ... has been rented. This feature is not available right now. Please try again later. Published on May ... 34 How The Clean Hands - Safe Hands System Works - Duration: 3:38. Clean Hands-Safe Hands 5, ...

Response of lead-acid batteries to chopper-controlled discharge. [for electric vehicles

Science.gov (United States)

Cataldo, R. L.

1978-01-01

The results of tests on an electric vehicle battery, using a simulated electric vehicle chopper-speed controller, show energy output losses up to 25 percent compared to constant current discharges at the same average current of 100 A. However, an energy output increase of 22 percent is noticed at the 200 A average level and 44 percent increase at the 300 A level using pulse discharging. Because of these complex results, electric vehicle battery/speed controller interactions must be considered in vehicle design.

Aqueous citric acid as a promising cleaning agent of whey evaporators

DEFF Research Database (Denmark)

Hedegaard, Martina Vavrusova; P. Johansen, Nikolaj; Garcia, André Castilho

2017-01-01

concentration of citric acid was the most effective for all the investigated volumes. From the citric acid solutions, spontaneously supersaturated in calcium citrate tetrahydrate during scale dissolution in the smaller volumes for all citric acid concentrations, calcium citrate tetrahydrate slowly precipitated...... in acceptable purity for technical use. Dissolution efficiency of aqueous solutions of 0.200 mol L−1 nitric acid combined with 0.100, 0.500, and 1.00 mol L−1 citric acid with final volumes of 100, 50, and 25 mL showed synergistic effect especially for the higher concentrations and lower volumes of two acids...

Clean air and energy: from conflict to reconciliation

International Nuclear Information System (INIS)

Kolstad, C.D.; Schulze, W.D.; Williams, M.D.

1982-01-01

Unconstrained energy resource development in the Rocky Mountain west is likely to threaten the environment and the health and well-being of the people. Impacts may be associated with visibility degradation, toxic concentrations of gases, and deposition of acidic or toxic substances. Because the possible benefits of energy development in the region are very large, there is great concern that constraints imposed by air quality regulation may preclude the use of important resources or make unduly expensive energy produced from the region. The conflict between energy and clean air in the region is exacerbated by non-energy sources, such as copper smelters and urban areas, that already pose significant environmental threats. The hard policy question is not how to preserve clean air resources or how to develop energy but how to achieve and balance both goals. The effects and regulatory costs and benefits of air pollution control are discussed, and policy directions to protect air quality while pursuing energy development are presented

Report on a survey in fiscal 1999. Survey and study on the 'measures for promoting discharge right transaction/joint implementation (JI) / clean development mechanism (CDM) project'; 1999 nendo 'haishutsuken torihiki / JI / CDM project suishin hosaku' ni kansuru chosa kenkyu hokokusho

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

The third conference (COP3) of the United Nations Framework Convention on Climate Change held in December 1997 in Kyoto has adopted the Kyoto mechanisms (the 'discharge right transaction', the 'joint implementation (JI)' among advanced countries, and the 'clean development mechanism (CDM)' applied to developing countries). The Kyoto mechanisms are intended to provide flexibility to the methods to achieve the greenhouse effect gas reduction targets established in the Kyoto Protocol. The Kyoto mechanisms are considered to be implemented even during the year 2000, whose details are scheduled to be decided at COP6. Since the advanced countries have established the targets for reduction of greenhouse effect gas emission, governments and research institutes are taking various approaches. In addition, since the targets for reduction of greenhouse effect gas emission have been established, discussions are indispensable on methodology to establish the quantity of discharge and absorption of greenhouse effect gases (the so-called base line) when no project exists, as required to calculate the discharge reduction quantity as a result of implementing the project. The present survey has held study meetings attended by learned people, and compiled the results of the discussions. (NEDO)

Clean coal technologies: A business report

International Nuclear Information System (INIS)

Anon.

1993-01-01

The book contains four sections as follows: (1) Industry trends: US energy supply and demand; The clean coal industry; Opportunities in clean coal technologies; International market for clean coal technologies; and Clean Coal Technology Program, US Energy Department; (2) Environmental policy: Clean Air Act; Midwestern states' coal policy; European Community policy; and R ampersand D in the United Kingdom; (3) Clean coal technologies: Pre-combustion technologies; Combustion technologies; and Post-combustion technologies; (4) Clean coal companies. Separate abstracts have been prepared for several sections or subsections for inclusion on the data base

Financing clean energy market creation. Clean energy ventures, venture capitalists and other investors

Energy Technology Data Exchange (ETDEWEB)

Teppo, T. [Helsinki Univ. of Technology, Espoo (Finland). Development and Management in Industry

2006-07-01

Many factors have emerged for change towards cleaner and more efficient technologies and services: climate change, increasing oil demands, and rising living standards in many parts of the world are putting an ever-increasing strain on the environment. Recently, these drivers have fueled the formation of a clean energy venture capital market where both independent venture capitalists (VCs) and corporate venture capitalists (CVCs) have invested in clean energy start-ups. Financing of clean energy market creation is the focus of this dissertation. The dissertation contributes to several bodies of literature in the area of entrepreneurship, new industry creation, corporate venturing, and venture capital research. The dissertation uses a grounded theory approach. The study is guided by three data collection approaches with an emphasis on the first two. First, interviews with European and North American VC and CVC firms that have invested in the clean energy sector were carried out. Second, a clean energy venture financing survey that consisted of qualitative, essay-format questions and some quantitative questions was carried out. Third, interviews with clean energy stakeholders were carried out in order to gain a better understanding of the emerging sector. The research results consist of three main findings. First, the research results suggest that clean energy ventures face the following three main entrepreneurial challenges: financing, market education, and growth management. A further study of three clean energy industry categories revealed additional challenges that varied according to the industry development stage. Second, the results demonstrate that, from a venture capitalist perspective, clean energy venture risk characteristics can be divided into two groups: generally recognized risk characteristics and cognitive risk characteristics. The identified generally recognized risk characteristics were market demand and adaptation, incompatibility with the VC model

Technological procedure for chemical cleaning prior to re-pyritization of H2O-H2S isotopic exchange installations

International Nuclear Information System (INIS)

Stefanescu, I.; Smaranda, D.; Titescu, Gh.

1996-01-01

In normal operation the anti-corrosive shielding of the GS installations undergo a slow, irreversible degradation in time so that after 6 - 8 years their protection characteristics break down. In order to put them back in operation the regeneration of anti-corrosive is required. The procedure achieved at ICIS - Rm.Valcea consists in chemical cleaning of the impaired layers and re-pyritization of the interior surface of installations. Chemical cleaning include the following operations: - mechanical cleaning; - water washing; - alkaline washing with sodium hydroxide, tri-sodium phosphate and sodium tri-polyphosphate; - final mechanical cleaning; - neutralizing washing; - chemical cleaning with phosphoric acid solution; - neutralizing washing. After applying this procedure, the surface is prepared for the pyritization regeneration of the anti-corrosive shielding which ensures the prolongation of the equipment service lifetime with another six year period

Chemical cleaning review

International Nuclear Information System (INIS)

Dow, B.L.; Thomas, R.C.

1995-01-01

Three main chemical processes for cleaning steam generators have evolved from the early work of the industry. Of the more than 50 chemical cleanings carried out to date most have been considered a success by the utilities performing them. (author)

Clean coal technology

International Nuclear Information System (INIS)

Abelson, P.H.

1990-01-01

One of the major technology challenges in the next decade will be to develop means of using coal imaginatively as a source of chemicals and in a more energy-efficient manner. The Clean Air Act will help to diminish the acid rain but will not reduce CO 2 emissions. The Department of Energy (DOE) is fostering many innovations that are likely to have a positive effect on coal usage. Of the different innovations in the use of coal fostered by DOE, two are of particular interest. One is the new pressurized fluid bed combustion (PFBC) combined-cycle demonstration. The PFBC plant now becoming operational can reduce SO 2 emissions by more than 90% and NO x emissions by 50-70%. A second new technology co-sponsored by DOE is the Encoal mild coal gasification project that will convert a sub-bituminous low-BTU coal into a useful higher BTU solid while producing significant amounts of a liquid fuel

Microwave discharge electrodeless lamps (MDEL). Part VII. Photo-isomerization of trans-urocanic acid in aqueous media driven by UV light from a novel Hg-free Dewar-like microwave discharge thermally-insulated electrodeless lamp (MDTIEL). Performance evaluation.

Science.gov (United States)

Horikoshi, Satoshi; Sato, Tatsuro; Sakamoto, Kazutami; Abe, Masahiko; Serpone, Nick

2011-07-01

A novel mercury-free Dewar-like (double-walled structure) microwave discharge thermally-insulated electrodeless lamp (MDTIEL) was fabricated and its performance evaluated using the photo-isomerization of trans-urocanic acid (trans-UA) in aqueous media as a test process driven by the emitted UV light when ignited with microwave radiation. The photo-isomerization processes trans-UA → cis-UA and cis-UA → trans-UA were re-visited using light emitted from a conventional high-pressure Hg light source and examined for the influence of UV light irradiance and solution temperature; the temperature dependence of the trans → cis process displayed a negative activation energy, E(a) = -1.3 cal mol(-1). To control the photo-isomerization of urocanic acid from the heat usually dissipated by a microwave discharge electrodeless lamp (single-walled MDEL), it was necessary to suppress the microwave-initiated heat. For comparison, the gas-fill in the MDEL lamp, which typically consists of a mixture of Hg and Ar, was changed to the more eco-friendly N(2) gas in the novel MDTIEL device. The dynamics of the photo-isomerization of urocanic acid driven by the UV wavelengths of the N(2)-MDTIEL light source were compared to those from the more conventional single-walled N(2)-MDEL and Hg/Ar-MDEL light sources, and with those from the Hg lamp used to irradiate, via a fiber optic, the photoreactor located in the wave-guide of the microwave apparatus. The heating efficiency of a solution with the double-walled N(2)-MDTIEL was compared to the efficiency from the single-walled N(2)-MDEL device. Advantages of N(2)-MDTIEL are described from a comparison of the dynamics of the trans-UA → cis-UA process on the basis of unit surface area of the lamp and unit power consumption. The considerably lower temperature on the external surface of the N(2)-MDTIEL light source should make it attractive in carrying out photochemical reactions that may be heat-sensitive such as the photothermochromic

Laser cleaning of particulates from paper: Comparison between sized ground wood cellulose and pure cellulose

International Nuclear Information System (INIS)

Arif, S.; Kautek, W.

2013-01-01

Visible laser cleaning of charcoal particulates from yellow acid mechanical ground wood cellulose paper was compared with that from bleached sulphite softwood cellulose paper. About one order of magnitude of fluence range is available for a cleaning dynamics between the cleaning threshold and the destruction threshold for two laser pulses. Wood cellulose paper exhibited a higher destruction threshold of the original paper than that of the contaminated specimen because of heat transfer from the hot or evaporating charcoal particulates. In contrast, the contaminated bleached cellulose paper exhibited a higher destruction threshold due to shading by the particulates. The graphite particles are not only detached thermo-mechanically, but also by evaporation or combustion. A cleaning effect was found also outside the illuminated areas due to lateral blasting. Infrared measurements revealed dehydration/dehydrogenation reactions and cross-links by ether bonds together with structural changes of the cellulose chain arrangement and the degree of crystallinity.

Steam cleaning device

International Nuclear Information System (INIS)

Karaki, Mikio; Muraoka, Shoichi.

1985-01-01

Purpose: To clean complicated and long objects to be cleaned having a structure like that of nuclear reactor fuel assembly. Constitution: Steams are blown from the bottom of a fuel assembly and soon condensated initially at the bottom of a vertical water tank due to water filled therein. Then, since water in the tank is warmed nearly to the saturation temperature, purified water is supplied from a injection device below to the injection device above the water tank on every device. In this way, since purified water is sprayed successively from below to above and steams are condensated in each of the places, the entire fuel assembly elongated in the vertical direction can be cleaned completely. Water in the reservoir goes upward like the steam flow and is drained together with the eliminated contaminations through an overflow pipe. After the cleaning has been completed, a main steam valve is closed and the drain valve is opened to drain water. (Kawakami, Y.)

Baking of tandem accelerator tube by low voltage arc discharge

International Nuclear Information System (INIS)

Nakajima, Yutaka

1982-01-01

In designing the accelerating tube for a static tandem accelerator in Kyushu University, the basic policy was as described below: individual unit composing the accelerating tube should fully withstand the electric field of 2 MV/m, and electric discharge must not be propagated from one unit to the adjacent unit when these are assembled to the accelerating tube. The accelerating tube units are each 25 cm in length, and both high and low energy sides are composed of 20 units, respectively. Although about 10 -9 Torr vacuum was obtained at the both ends of the accelerating tube by baking the tube at 300 to 350 deg C with electric heaters wound outside the tube in the conventional method, vast outgas was generated, which decreased vacuum by two or three figures if breakdown occurred through the intermediary of outgas. As a method of positively outgassing and cleaning the electrodes inside the accelerating tube, it was attempted to directly bake all the electrodes in the accelerating tube by causing strong arc discharge flowing H 2 gas in the tube. As a result of considering the conditions for this method, the low voltage arc discharge was employed using oxide cathodes. Thus, after implementing 10A arc discharge for several hours, the voltage was able to be raised to 10 MV almost immediately after the vacuum recovery, and further, after another conditioning for several hours, it was successful to raise voltage up to 11 MV. (Wakatsuki, Y.)

Overview of shoreline cleaning agents

International Nuclear Information System (INIS)

Clayton, J.

1992-01-01

Chemical cleaning agents may be used to promote release of stranded oil from shorelines for reasons including biological sensitivity of indigenous fauna and flora to the oil, amenity considerations of the shoreline, or concern about refloating of the oil and subsequent stranding on adjacent shorelines. While use of chemical cleaning agents may be appropriate under proper toxic responses in circumstances, certain limitations should be recognized. The potential for toxic responses in indigenous fauna and flora to the cleaning agents must be considered. Enhanced penetration of oil into permeable shorelines following treatment with chemical cleaning agents also is not desirable. However, if conditions related to toxicity and substrate permeability are determined to be acceptable, the use of chemical cleaning agents for treatment of stranded oil can be considered. Chemical agents for cleaning oiled shorelines can be grouped into three categories: (1) non-surfactant-based solvents, (2) chemical dispersants, and (3) formulations especially designed to release stranded oil from shoreline substrates (i.e., shoreline-cleaning-agents). Depending on the specific circumstances present on an oiled shoreline, it is generally desirable that chemical agents used for cleaning will release oil from shoreline substrate(s) to surface waters. Recovery of the oil can then be accomplished by mechanical procedures such as booming and skimming operations

''How clean is clean'' in the United States federal and Washington State cleanup regulations

International Nuclear Information System (INIS)

Landau, H.G.

1993-01-01

The enactment of legislation and promulgation of implementing regulations generally involves the resolution of conflicting goals. Defining ''How Clean is Clean?'' in federal and state cleanup laws, regulations, and policies is no exception. Answering the ''How Clean is Clean?'' question has resulted in the identification of some important and sometimes conflicting goals. Continuing resolution of the following conflicting goals is the key to effect cleanup of hazardous waste sites: Expediency vs. Fairness; Flexibility vs. Consistency; Risk Reduction vs. Risk Causation; and Permanence vs. Cost Effectiveness

Surface fixation of dried blood by glutaraldehyde and peracetic acid.

Science.gov (United States)

Kampf, G; Bloss, R; Martiny, H

2004-06-01

The difficulties of successful prion inactivation by chemical agents has led to changes in recommendations regarding the reprocessing of instruments including flexible endoscopes. One of the changes is the preference for peracetic acid instead of glutaraldehyde in order to avoid fixation of organic material, but the surface fixation by various active agents has not been fully investigated. We used a standardized amount of dried blood soil on metal carriers (on average 22 mg). One part of the carriers was exposed to different disinfectants (four based on peracetic acid, three based on glutaraldehyde, two based on quaternary ammonium compounds (QAC), one based on QAC and amines, one based on phenols and one cleaning agent) and air dried. The difference compared with the non-exposed soiled carrier was taken as the measure of blood removal by exposure to the disinfectants. In addition the other part of the carriers was exposed to a cleaning agent and air dried. The cleaning agent itself was capable of removing more than 99% of the dried blood and served as a control for non-fixation. The rate of fixation of dried blood was calculated as the ratio of the weight of residual soil on 'soiled, disinfected and cleaned' carriers and on 'soiled and disinfected' carriers. All experiments were repeated eight times. Blood removal varied between 90.3% +/- 1.5% (phenol-based disinfectant) and peracetic acid. No other preparations showed a potential for blood fixation (peracetic acid, and support the evidence that effective cleaning should precede the chemical disinfection. Copyright 2004 The Hospital Infection Society

Determination of preservatives in cosmetics, cleaning agents and pharmaceuticals using fast liquid chromatography.

Science.gov (United States)

Baranowska, Irena; Wojciechowska, Iwona; Solarz, Natalia; Krutysza, Ewa

2014-01-01

This paper reports the development of a method for simultaneously determining five preservatives in cosmetics, cleaning agents and pharmaceuticals by fast liquid chromatography. Methylisothiazolinone, methylchloroisothiazolinone, benzyl alcohol, sodium benzoate and methylparaben were separated on a Chromolith Fast Gradient reversed-phase 18e column using gradient elution with acetonitrile and a 0.1% aqueous solution of formic acid, with a run time of 3 min. The preparation of solid and liquid samples included ultrasonic extraction with methanol with recoveries ranging from 69 to 119%. The developed method was used to analyze samples of cosmetics (66 samples), cleaning agents (five samples) and pharmaceutical industry products (17 samples).

Benchmarks of Global Clean Energy Manufacturing

Energy Technology Data Exchange (ETDEWEB)

Sandor, Debra [National Renewable Energy Lab. (NREL), Golden, CO (United States); Chung, Donald [National Renewable Energy Lab. (NREL), Golden, CO (United States); Keyser, David [National Renewable Energy Lab. (NREL), Golden, CO (United States); Mann, Margaret [National Renewable Energy Lab. (NREL), Golden, CO (United States); Engel-Cox, Jill [National Renewable Energy Lab. (NREL), Golden, CO (United States)

2017-01-01

The Clean Energy Manufacturing Analysis Center (CEMAC), sponsored by the U.S. Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy (EERE), provides objective analysis and up-to-date data on global supply chains and manufacturing of clean energy technologies. Benchmarks of Global Clean Energy Manufacturing sheds light on several fundamental questions about the global clean technology manufacturing enterprise: How does clean energy technology manufacturing impact national economies? What are the economic opportunities across the manufacturing supply chain? What are the global dynamics of clean energy technology manufacturing?

Diamond-cleaning investigations

International Nuclear Information System (INIS)

Derry, T.E.

Four parcels of diamonds which either had or had not been cleaned using the usual techniques, chiefly involving etch in molten potassium nitrate were supplied by De Beers Diamond Research Laboratories. Each parcel contained about 40 stones, amounting to about 10 carats. Half the diamonds in each parcel were cleaned by a standard procedure involving half an hours ultrasonic agitation in a 20% solution of the commercial detergent 'Contrad' which is effectively a surfactant and chelating agent. Visual comparisons by a number of observers who were not told the stones' histories, established that these diamonds generally had a more sparkling appearance after the cleaning procedure had been applied

Keeping condensers clean

Energy Technology Data Exchange (ETDEWEB)

Wicker, K.

2006-04-15

The humble condenser is among the biggest contributors to a steam power plant's efficiency. But although a clean condenser can provide great economic benefit, a dirty one can raise plant heat rate, resulting in large losses of generation revenue and/or unnecessarily high fuel bills. Conventional methods for cleaning fouled tubes range form chemicals to scrapers to brushes and hydro-blasters. This article compares the available options and describes how one power station, Omaha Public Power District's 600 MW North Omaha coal-fired power station, cleaned up its act. The makeup and cooling water of all its five units comes from the Missouri River. 6 figs.

National Alliance for Clean Energy Incubators New Mexico Clean Energy Incubator

Energy Technology Data Exchange (ETDEWEB)

Roberts, Suzanne S.

2004-12-15

The National Alliance for Clean Energy Incubators was established by the National Renewable Energy Laboratory (NREL) to develop an emerging network of business incubators for entrepreneurs specializing in clean energy enterprises. The Alliance provides a broad range of business services to entrepreneurs in specific geographic locales across the U.S. and in diverse clean energy technology areas such as fuel cells, alternative fuels, power generation, and renewables, to name a few. Technology Ventures Corporation (TVC) participates in the Alliance from its corporate offices in Albuquerque, NM, and from its sites in Northern and Southern New Mexico, California, and Nevada. TVC reports on the results of its attempts to accelerate the growth and success of clean energy and energy efficiency companies through its array of business support services. During the period from September 2002 through September 2004, TVC describes contributions to the Alliance including the development of 28 clients and facilitating capital raises exceeding $35M.

Characterization of electrical discharges during spark anodization of zirconium in different electrolytes

International Nuclear Information System (INIS)

Santos, Janaina S.; Lemos, Sherlan G.; Gonçalves, Wesley N.; Bruno, Odemir M.; Pereira, Ernesto C.

2014-01-01

The evolution of the electrical discharges parameters during spark anodization of metallic Zr under galvanostatic regime have been investigated by image analysis in phosphoric and oxalic acid electrolytes. The experiments were recorder using a high-speed video camera during the entire anodization with a resolution of 1.7 ms for determination of discharge lifetime and a standard resolution of 33 ms (real-time imaging) for determination of the average area and discharge population density. The discharge behavior was dependent of the current density, electrolyte composition and anodization time. During breakdown process, sparks discharges are progressively turned to micro-arcs, which can be seen by enlargement of discharge area, gradual increase of lifetime and reduction of discharge population density. A factorial design was used to estimate the effects of experimental conditions on the discharge behavior. The current density and electrolyte composition were the most important factors that affected the discharge population density. The anodization time and the electrolyte composition were the main factor that influenced the discharge area and lifetime. In comparison with the voltage vs. time curve, the results demonstrate important features of the process and the changes of the electrical discharges characteristics during the experiments

Rejection of Organic Micropollutants by Clean and Fouled Nanofiltration Membranes

Directory of Open Access Journals (Sweden)

Lifang Zhu

2015-01-01

Full Text Available The rejection of organic micropollutants, including three polycyclic aromatic hydrocarbons (PAHs and three phthalic acid esters (PAEs, by clean and fouled nanofiltration membranes was investigated in the present study. The rejection of organic micropollutants by clean NF90 membranes varied from 87.9 to more than 99.9%, while that of NF270 membranes ranged from 32.1 to 92.3%. Clear time-dependence was observed for the rejection of hydrophobic micropollutants, which was attributed to the adsorption of micropollutants on the membrane. Fouling with humic acid had a negligible influence on the rejection of organic micropollutants by NF90 membranes, while considerable effects were observed with NF270 membranes, which are significantly looser than NF90 membranes. The observed enhancement in the rejection of organic micropollutants by fouled NF270 membranes was attributed to pore blocking, which was a dominating fouling mechanism for loose NF membranes. Changes in the ionic strength (from 10 to 20 mM reduced micropollutant rejection by both fouled NF membranes, especially for the rejection of dimethyl phthalate and diethyl phthalate by NF270 membranes (from 65.8 to 25.0% for dimethyl phthalate and 75.6 to 33.3% for diethyl phthalate.

Sustainable development with clean coal

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-08-01

This paper discusses the opportunities available with clean coal technologies. Applications include new power plants, retrofitting and repowering of existing power plants, steelmaking, cement making, paper manufacturing, cogeneration facilities, and district heating plants. An appendix describes the clean coal technologies. These include coal preparation (physical cleaning, low-rank upgrading, bituminous coal preparation); combustion technologies (fluidized-bed combustion and NOx control); post-combustion cleaning (particulate control, sulfur dioxide control, nitrogen oxide control); and conversion with the integrated gasification combined cycle.

Clean Energy Progress Report

Energy Technology Data Exchange (ETDEWEB)

NONE

2011-07-01

For the past several years, the IEA and others have been calling for a clean energy revolution to achieve global energy security, economic growth and climate change goals. This report analyses for the first time progress in global clean energy technology deployment against the pathways that are needed to achieve these goals. It provides an overview of technology deployment status, key policy developments and public spending on RDD&D of clean energy technologies.

Flow Alteration and Chemical Reduction: Air Stripping to Lessen Subsurface Discharges of Mercury to Surface Water

Science.gov (United States)

Brooks, S. C.; Bogle, M.; Liang, L.; Miller, C. L.; Peterson, M.; Southworth, G. R.; Spalding, B. P.

2009-12-01

Mercury concentrations in groundwater, surface water, and biota near an industrial facility in Oak Ridge, Tennessee remain high some 50 years after the original major releases from the facility to the environment. Since the mid-1980s, various remedial and abatement actions have been implemented at the facility, including re-routing water flows, armoring contaminated stream banks, relining or cleanout of facility storm drains, and activated charcoal treatment of groundwater and sump discharges. These actions were taken to reduce inorganic mercury inputs from the facility to the stream; a strategy that assumes limiting the inorganic mercury precursor will reduce Hg methylation and its subsequent bioaccumulation. To date, such actions have reduced mercury loading from the site by approximately 90% from levels typical of the mid 1980's, but waterborne mercury at the facility boundary remains roughly 100 times the typical local background concentration and methylmercury accumulation in aquatic biota exceed standards for safe consumption by humans and wildlife. In 2008 and 2009, a series of investigations was initiated to explore innovative approaches to further control mercury concentrations in stream water. Efforts in this study focused on decreasing waterborne inorganic mercury inputs from two sources. The first, a highly localized source, is the discharge point of the enclosed stormdrain network whereas the second is a more diffuse short reach of stream where metallic Hg in streambed sediments generates a continued input of dissolved Hg to the overlying water. Moving a clean water flow management discharge point to a position downstream of the contaminated reach reduced mercury loading from the streambed source by 75% - 100%, likely by minimizing resuspension of Hg-rich fine particulates and changing characteristic hyporheic flow path length and residence time. Mercury in the stormdrain discharge exists as highly reactive dissolved Hg(II) due to residual chlorine in

Treatment of waste water from flue gas cleaning; Behandlung von Abwasser der Rauchgasreinigung

Energy Technology Data Exchange (ETDEWEB)

Ogiermann, Klaus; Meyerhoff, Thomas [Berkefeld - VWS Deutschland GmbH, Celle (Germany); Hagen, Klaus [Berkefeld - VWS Deutschland GmbH, Bayreuth (Germany); Basabe, Juan Luis [HPD Process Engineering S.A., Bilbao (Spain); Vendrup, Michael [Krueger A/S, Soeborg (Denmark)

2012-11-01

Strict limits must be adhered to for treating waste water incurred during flue gas desulphurisation (FGD). One and two-stage precipitation processes have proven themselves in FGD waste water treatment. Metals can be removed with the MetClean {sup registered} process. Another option is evaporation. Waste water ZLD systems (Zero Liquid Discharge) recover, via a falling film evaporator with subsequent crystallisation, more than 98 % of the water and produce, aside from the condensate, only solid material that can be disposed of in landfill. A further development, named ZLD CoLD trademark, significantly reduces the investment and operating costs of this solution. (orig.)

Clean Energy Policy Analysis: Impact Analysis of Potential Clean Energy Policy Options for the Hawaii Clean Energy Initiative (HCEI)

Energy Technology Data Exchange (ETDEWEB)

Busche, S.; Doris, E.; Braccio, R.; Lippert, D.; Finch, P.; O' Toole, D.; Fetter, J.

2010-04-01

This report provides detailed analyses of 21 clean energy policy options considered by the Hawaii Clean Energy Initiative working groups for recommendation to the 2010 Hawaii State Legislature. The report considers the impact each policy may have on ratepayers, businesses, and the state in terms of energy saved, clean energy generated, and the financial costs and benefits. The analyses provide insight into the possible impacts, both qualitative and quantitative, that these policies may have in Hawaii based on the experience with these policies elsewhere. As much as possible, the analyses incorporate Hawaii-specific context to reflect the many unique aspects of energy use in the State of Hawaii.

Experimental Studies of Anode Sheath Phenomena in a Hall Thruster Discharge

International Nuclear Information System (INIS)

Dorf, L.; Raitses, Y.; Fisch, N.J.

2004-01-01

Both electron-repelling and electron-attracting anode sheaths in a Hall thruster were characterized by measuring the plasma potential with biased and emissive probes [L. Dorf, Y. Raitses, V. Semenov, and N.J. Fisch, Appl. Phys. Let. 84 (2004) 1070]. In the present work, two-dimensional structures of the plasma potential, electron temperature, and plasma density in the near-anode region of a Hall thruster with clean and dielectrically coated anodes are identified. Possible mechanisms of anode sheath formation in a Hall thruster are analyzed. The path for current closure to the anode appears to be the determining factor in the anode sheath formation process. The main conclusion of this work is that the anode sheath formation in Hall thrusters differs essentially from that in the other gas discharge devices, like a glow discharge or a hollow anode, because the Hall thruster utilizes long electron residence times to ionize rather than high neutral pressures

Laser cleaning of Rakowicze sandstone

NARCIS (Netherlands)

Nijland, T.G.; Wijffels, T.J.

2003-01-01

Decisions about the cleaning of natural stone should always be made within the awareness of direct and indirect damage that may be the result of cleaning. During the last decade, laser cleaning of objects and monuments of natural stone has become increasingly popular. Whereas a considerable amount

Surface cleaning in thin film technology

International Nuclear Information System (INIS)

Mattox, D.M.

1978-01-01

A ''clean surface'' is one that contains no significant amounts of undesirable material. This paper discusses the types and origin of various contaminants. Since cleaning is often equated with adhesion, the mechanisms of adhesion to oxide, metal, and organic surfaces are reviewed and cleaning processes for these surfaces are outlined. Techniques for monitoring surface cleaning are presented, and the importance of storage of clean surfaces is discussed. An extensive bibliography is given. 4 figs., 89 references

Accelerated solvent extraction method with one-step clean-up for hydrocarbons in soil

International Nuclear Information System (INIS)

Nurul Huda Mamat Ghani; Norashikin Sain; Rozita Osman; Zuraidah Abdullah Munir

2007-01-01

The application of accelerated solvent extraction (ASE) using hexane combined with neutral silica gel and sulfuric acid/ silica gel (SA/ SG) to remove impurities prior to analysis by gas chromatograph with flame ionization detector (GC-FID) was studied. The efficiency of extraction was evaluated based on the three hydrocarbons; dodecane, tetradecane and pentadecane spiked to soil sample. The effect of ASE operating conditions (extraction temperature, extraction pressure, static time) was evaluated and the optimized condition obtained from the study was extraction temperature of 160 degree Celsius, extraction pressure of 2000 psi with 5 minutes static extraction time. The developed ASE with one-step clean-up method was applied in the extraction of hydrocarbons from spiked soil and the amount extracted was comparable to ASE extraction without clean-up step with the advantage of obtaining cleaner extract with reduced interferences. Therefore in the developed method, extraction and clean-up for hydrocarbons in soil can be achieved rapidly and efficiently with reduced solvent usage. (author)

Economic and environmental impacts of proposed changes to Clean Water Act thermal discharge requirements

International Nuclear Information System (INIS)

Veil, J.A.

1994-01-01

This paper examines the economic and environmental impact to the power industry of limiting thermal mixing zones to 1000 feet and eliminating the Clean Water Act section 316(a) variance. Power companies were asked what they would do if these two conditions were imposed. Most affected plants would retrofit cooling towers and some would retrofit diffusers. Assuming that all affected plants would proportionally follow the same options as the surveyed plants, the estimated capital cost of retrofitting cooling towers or diffusers at all affected plants exceeds $20 billion. Since both cooling towers and diffusers exert an energy penalty on a plant's output, the power companies must generate additional power. The estimated cost of the additional power exceeds $10 billion over 20 years. Generation of the extra power would emit over 8 million tons per year of additional carbon dioxide. Operation of the new cooling towers would cause more than 1.5 million gallons per minute of additional evaporation

Fire protection for clean rooms

International Nuclear Information System (INIS)

Kirson, D.

1990-01-01

The fire protection engineer often must decide what size fire can be tolerated before automatic fire suppression systems actuate. Is it a wastepaper basket fire, a bushel basket fire...? In the case of state-of-the-art clean rooms, the answer clearly is not even an incipient fire. Minor fires in clean rooms can cause major losses. This paper discusses what a clean room is and gives a brief overview of the unique fire protection challenges encountered. The two major causes of fire related to clean rooms in the semiconductor industry are flammable/pyrophoric gas fires in plastic ducts and polypropylene wet bench fires. This paper concentrates on plastic ductwork in clean rooms, sprinkler protection in ductwork, and protection for wet benches

Complying with Clean Air Act acid rain provisions: A case history of required air quality analyses

International Nuclear Information System (INIS)

McComb, G.G. Jr.; Naperkoski, G.J.; Rogers, F.A.

1990-01-01

Clean Air Act Amendments being considered by Congress require SO 2 emissions reductions from numerous large power generation sources nationwide. As currently written, these amendments also require that the affected sources must continue to comply with all provisions of the existing Clean Air Act while achieving the required reductions. United Engineers and Constructors is presently assisting utilities in the evaluation of compliance options for units totaling over 18,000 MW. The methods of achieving compliance with the probable requirements of the Act most often include the retrofit installation of SO 2 scrubbers. A study designed to determine permitting issues and the scope of air quality analyses required to demonstrate the regulatory acceptability of installation of wet scrubbing systems has been completed for units totaling a portion of the above-referenced 18,000 MW. The study results show that, under certain commonly occurring circumstances, there is a risk of creating National Ambient Air Quality Standards contraventions for SO 2 and NO 2 when scrubbers are installed at an existing facility. Any such contraventions subject the plant to state and/or federal enforcement actions. In addition, installation of materials handling equipment for lime stone can trigger Prevention of Significant Deterioration requirements as a major modification. This paper is divided into two major areas. The first deals with the air quality regulatory requirements imposed upon installation of pollution control equipment. The first section is further sub-divided into two sections: one covering requirements emanating from the 1977 Clean Air Act Amendments and its implementing regulations and the other the regulatory requirements of the new Clean Air Act Amendments. This section on regulatory requirements provides background information for the understanding of the second major section of the paper which gives the results of the hypothetical case study

7 CFR 51.2083 - Clean.

Science.gov (United States)

2010-01-01

... 7 Agriculture 2 2010-01-01 2010-01-01 false Clean. 51.2083 Section 51.2083 Agriculture Regulations... FRESH FRUITS, VEGETABLES AND OTHER PRODUCTS 1,2 (INSPECTION, CERTIFICATION, AND STANDARDS) United States Standards for Grades of Almonds in the Shell Definitions § 51.2083 Clean. Clean means that the shell is...

Dry-cleaning of graphene

International Nuclear Information System (INIS)

Algara-Siller, Gerardo; Lehtinen, Ossi; Kaiser, Ute; Turchanin, Andrey

2014-01-01

Studies of the structural and electronic properties of graphene in its pristine state are hindered by hydrocarbon contamination on the surfaces. Also, in many applications, contamination reduces the performance of graphene. Contamination is introduced during sample preparation and is adsorbed also directly from air. Here, we report on the development of a simple dry-cleaning method for producing large atomically clean areas in free-standing graphene. The cleanness of graphene is proven using aberration-corrected high-resolution transmission electron microscopy and electron spectroscopy

Dry-cleaning of graphene

Energy Technology Data Exchange (ETDEWEB)

Algara-Siller, Gerardo [Central Facility for Electron Microscopy, Group of Electron Microscopy of Materials Science, Ulm University, Albert-Einstein-Allee 11, Ulm 89081 (Germany); Department of Chemistry, Technical University Ilmenau, Weimarer Strasse 25, Ilmenau 98693 (Germany); Lehtinen, Ossi; Kaiser, Ute, E-mail: ute.kaiser@uni-ulm.de [Central Facility for Electron Microscopy, Group of Electron Microscopy of Materials Science, Ulm University, Albert-Einstein-Allee 11, Ulm 89081 (Germany); Turchanin, Andrey [Faculty of Physics, University of Bielefeld, Universitätsstr. 25, Bielefeld 33615 (Germany)

2014-04-14

Studies of the structural and electronic properties of graphene in its pristine state are hindered by hydrocarbon contamination on the surfaces. Also, in many applications, contamination reduces the performance of graphene. Contamination is introduced during sample preparation and is adsorbed also directly from air. Here, we report on the development of a simple dry-cleaning method for producing large atomically clean areas in free-standing graphene. The cleanness of graphene is proven using aberration-corrected high-resolution transmission electron microscopy and electron spectroscopy.

STUDY OF DESTRUCTION PROCESSES OF SYNTHETIC SURFACE-ACTIVE SUBSTENCES (SURFFACTANTS IN BARRIER DISCHARGE

Directory of Open Access Journals (Sweden)

V.I. Grinevich

2012-06-01

Full Text Available Kinetic data of degradation on aqueous solutions of surfactants in the plasma of barrier discharge are presented. The possible mechanism of proceeding processes is offered and considered. It is shown that the treatment in a barrier discharge results in decomposition efficiency of 95%. It is established that the main product of degradation are carboxylic acids.

Comparison of NF membrane fouling and cleaning by two pretreatment strategies for the advanced treatment of antibiotic production wastewater.

Science.gov (United States)

Wang, Jianxing; Li, Kun; Yu, Dawei; Zhang, Junya; Wei, Yuansong; Chen, Meixue; Shan, Baoqing

2016-01-01

The nanofiltration (NF) membrane fouling characteristics and cleaning strategies were investigated and compared for treating membrane bioreactor (MBR) effluent and MBR-granular activated carbon (GAC) effluent of an antibiotic production wastewater by DK membrane. Results showed that the fouling of treating MBR effluent was more severe than that of treating MBR-GAC effluent. After filtering for 216 h, the difference of membrane flux decline was obvious between MBR effluent and MBR-GAC effluent, with 14.9% and 10.3% flux decline, respectively. Further study showed that organic fouling is the main NF membrane fouling in the advanced treatment of antibiotic production wastewater for both of the two different effluents. Soluble microbial by-product like and tyrosine-like substances were the dominant components in the foulants, whereas humic-like substances existing in the effluents had little contribution to the NF membrane fouling. A satisfactory efficiency of NF chemical cleaning could be obtained using combination of acid (HCl, pH 2.0-2.5) and alkali (NaOH + 0.3 wt% NaDS, pH 10.0-10.5). The favorable cleaning strategy is acid-alkali for treating the MBR-GAC effluent, while it is alkali-acid for treating the MBR effluent.

Investment threshold and management reflection for industrial system cleaning: a case for China.

Science.gov (United States)

Fang, Yiping

2012-03-01

The recognition that industrial activity plays an essential role in a sustainable society is now widespread. To understand the causal relationship between industrial pollution abatement expenditure and industrial system cleaning level in China is of considerable importance, especially under extremely rapid industrial growth and serious pressure of industrial pollutants abatement context. We use composite index assessment method and regression analysis in this paper. We establish the mathematical model between composite industrial cleaner index and investment intensity for industrial pollutants abatement, and analyze the effects of industrial pollutants treatment and discharge indicators on composite industrial cleaner index in China. Results show that: (1) There is significant nonlinear relationship between composite industrial cleaner index and investment intensity for industrial pollutants abatement. (2) From single indicator perspective, the effect of investment intensity on pollutants treatment indicators is positively, on the contrary, the effect of investment intensity on pollutants discharge indicators is negatively; (3) From decomposition cleaner index perspective, the effect of pollutants discharge level (process control) is higher than pollutants treatment capacity (end-of-pipe) on composite industrial cleaner index; (4) There is threshold between investment intensity and composite cleaner industrial index, it is a crucial reference scale for industrial environmental management in selected period.

Efficient methods of piping cleaning

Directory of Open Access Journals (Sweden)

Orlov Vladimir Aleksandrovich

2014-01-01

Full Text Available The article contains the analysis of the efficient methods of piping cleaning of water supply and sanitation systems. Special attention is paid to the ice cleaning method, in course of which biological foil and various mineral and organic deposits are removed due to the ice crust buildup on the inner surface of water supply and drainage pipes. These impurities are responsible for the deterioration of the organoleptic properties of the transported drinking water or narrowing cross-section of drainage pipes. The co-authors emphasize that the use of ice compared to other methods of pipe cleaning has a number of advantages due to the relative simplicity and cheapness of the process, economical efficiency and lack of environmental risk. The equipment for performing ice cleaning is presented, its technological options, terms of cleansing operations, as well as the volumes of disposed pollution per unit length of the water supply and drainage pipelines. It is noted that ice cleaning requires careful planning in the process of cooking ice and in the process of its supply in the pipe. There are specific requirements to its quality. In particular, when you clean drinking water system the ice applied should be hygienically clean and meet sanitary requirements.In pilot projects, in particular, quantitative and qualitative analysis of sediments adsorbed by ice is conducted, as well as temperature and the duration of the process. The degree of pollution of the pipeline was estimated by the volume of the remote sediment on 1 km of pipeline. Cleaning pipelines using ice can be considered one of the methods of trenchless technologies, being a significant alternative to traditional methods of cleaning the pipes. The method can be applied in urban pipeline systems of drinking water supply for the diameters of 100—600 mm, and also to diversion collectors. In the world today 450 km of pipelines are subject to ice cleaning method.Ice cleaning method is simple

Waste acid recycling via diffusion dialysis

Energy Technology Data Exchange (ETDEWEB)

Steffani, C.

1995-05-26

Inorganic acids are commonly used for surface cleaning and finishing of metals. The acids become unuseable due to contamination with metals or diluted and weakened. Diffusion dialysis has become a way to recover the useable acid and allow separation of the metals for recovery and sale to refineries. This technique is made possible by the use of membranes that are strong enough to withstand low ph and have long service life.

Pickering Unit 1 chemical cleaning

International Nuclear Information System (INIS)

Smee, J.L.; Fiola, R.J.; Brennenstuhl, K.R.; Zerkee, D.D.; Daniel, C.M.

1995-01-01

The secondary sides of all 12 boilers at Pickering Unit 1 were chemically cleaned in 1994 by the team of Ontario Hydro, B and W International (Cambridge, Ontario) and B and W Nuclear Technologies (Lynchburg, Virginia). A multi-step EPRI/SGOG process was employed in a similar manner to previous clearings at Units 5 and 6 in 1992 and 1993, respectively. A major innovation with the Unit 1 cleaning was the incorporation of a crevice cleaning step, the first time this had been done on Ontario Hydro plants. In addition, six boilers were cleaned in parallel compared to three at a time in previous Pickering cleanings. This significantly reduced cleaning time. A total of 6,770 kg of sludge was removed through direct chemical dissolution. It consisted of 66% iron/nickel oxides and 28% copper metal. A total of 1,600,000 L (420,000 US gallons) of liquid waste was produced. It was processed through the spent solvent treatment facility located at the Bruce Nuclear Power Development site. Visual inspection performed after the cleaning indicated that the crevices between the boiler tubes and the tube support structure were completely clear of deposit and the general condition of the tubing and lattice bars appeared to be in 'as new' condition. (author)

Experimental design for extraction and quantification of phenolic compounds and organic acids in white "Vinho Verde" grapes.

Science.gov (United States)

Dopico-García, M S; Valentão, P; Guerra, L; Andrade, P B; Seabra, R M

2007-01-30

An experimental design was applied for the optimization of extraction and clean-up processes of phenolic compounds and organic acids from white "Vinho Verde" grapes. The developed analytical method consisted in two steps: first a solid-liquid extraction of both phenolic compounds and organic acids and then a clean-up step using solid-phase extraction (SPE). Afterwards, phenolic compounds and organic acids were determined by high-performance liquid chromatography (HPLC) coupled to a diode array detector (DAD) and HPLC-UV, respectively. Plackett-Burman design was carried out to select the significant experimental parameters affecting both the extraction and the clean-up steps. The identified and quantified phenolic compounds were: quercetin-3-O-glucoside, quercetin-3-O-rutinoside, kaempferol-3-O-rutinoside, isorhamnetin-3-O-glucoside, quercetin, kaempferol and epicatechin. The determined organic acids were oxalic, citric, tartaric, malic, shikimic and fumaric acids. The obtained results showed that the most important variables were the temperature (40 degrees C) and the solvent (acid water at pH 2 with 5% methanol) for the extraction step and the type of sorbent (C18 non end-capped) for the clean-up step.

Pancreatitis - discharge

Science.gov (United States)

Chronic pancreatitis - discharge; Pancreatitis - chronic - discharge; Pancreatic insufficiency - discharge; Acute pancreatitis - discharge ... You were in the hospital because you have pancreatitis. This is a swelling of the pancreas. You ...

The lead-acid eloflux cell. Research tool and candidate for advanced batteries

Energy Technology Data Exchange (ETDEWEB)

Kullmeine, U.; Kappus, W.

1982-12-01

The discharge capacity of usual lead-acid cells is limited by several mechanisms among which acid depletion is the most incisive. It is shown that the use of the so-called eloflux principle which is characterized by the flow of electrolyte through the porous electrodes, allows a significant deepe discharge and that by avoiding acid depletion the study of the other limiting processes and their functional dependence on the discharge conditions is possible. From the results it is concluded that an eloflux lead-acid cell is a promising candidate for advanced batteries with high energy density and performance.

Development of Tubular Type Underwater Discharge Reactor to decompose Fe-EDTA from aqueous solution

International Nuclear Information System (INIS)

Kang, Duck-Won; Kim, Seok-Tae; Kim, Jin Kil; Ki, Hyung-Dong

2007-01-01

In case of a nuclear industry, the wastewater is hardly generated in normal operating conditions aside from laundry rooms, particularly for wastewater contaminated by radioactive materials. However if the steam generator (SG) chemical cleaning works are carrying out, it is another story. In this case we have to predict wastewater production at least from several tons to several hundreds tons during the works. Actually Kori Unit 4 in Korea is preparing the advanced sludge conditioning agents (ASCAs) project at the next overhaul period, June-2007, to remove the tube sheet scale, and we are predicting that the 200 . 250 tons waste solutions are going to produce during this works. SG chemical cleaning waste solution containing chelating agents such as EDTA is hardly easy to purify and radioactive materials included in this solution make much harder. Therefore we must have technologies to purify this chemical cleaning waste solution. The best wastewater treatment system should have great adaptability, low environmental impact, low amount of hazardous waste, and low capital and operating costs. In this study we developed the underwater spark discharge system (USDS) to decompose Fe-EDTA from aqueous solution which is contaminated with radioactive materials

Enhanced Chemical Cleaning: Effectiveness Of The UV Lamp To Decompose Oxalates

International Nuclear Information System (INIS)

Ketusky, E.; Huff, T.; Sudduth, C.

2010-01-01

Enhanced Chemical Cleaning is a new process scheduled to begin cleaning Savannah River Site High Level Waste Tanks in 2012. It is an improvement over the current chemical cleaning method, in that it minimizes downstream impacts on the High Level Waste System. It is based on a state of the art scale removal process used on the secondary side of nuclear power plants, with modifications to accommodate the unique constraints created by the tanks. Both Enhanced Chemical Cleaning and the scale removal process are founded on dissolving metal oxides/hydroxides using oxalic acid, with subsequent oxalate decomposition via hydroxylation using ozone or peroxide, and UV light as a catalyst. A divergence Enhanced Chemical Cleaning has from nuclear power scale removal is the significantly increased solids concentration during oxalate decomposition. These solids can limit the ability of the UV light to create hydroxyl radicals, either by limiting the ability of the light to penetrate through the solution, or by increasing the fouling rate on the UV light. Both will decrease the overall catalytic effectiveness, thereby decreasing the concentration of formed hydroxyl radicals. The hydroxyl radicals are the driving force behind the oxalate decomposition. To understand the impact of increased solids, testing was performed using a medium pressure UV light inside an ozone supplied Oxalate Decomposition Reactor. Using a dissolved metal sludge simulant with an initial oxalate concentration greater than 12,000 ppm, and an initial pH of about 2.0, the spent acid solution was recirculated through the reactor, while the UV light was allowed to foul. For the first few hours, the oxalate decomposition rate was about 1,300 ppm/hour. After about 3 hours, enough time for the UV lamp to foul, the oxalate decomposition rate decreased to about 500 ppm/hour. The decomposition rate then remained roughly constant for the next 16 hours. Overall, testing showed that the oxalate destruction rate decreased

Incineration and flue gas cleaning in China - a Review

International Nuclear Information System (INIS)

Buekens, Alfons; Yan, Mi; Jiang, Xuguan; Li, Xiaodong; Lu, Shengyong; Chi, Yong; Yan, Jianhua; Cen, Kefa

2010-01-01

Waste incineration is rapidly developing in China. Different technologies are proposed for Municipal Solid Waste (MSW), Hazardous Waste (HW), and Medical Waste (MW). The required technologies are either imported, or developed locally. Some data are cited to illustrate these rapid developments. Incinerator flue gas arises at rather limited scale (10,000-100,000 Nm 3 /h), compared to power generation, yet the number of pollutants to be counted with is huge: dust and grit, acid gases, NO x , selected heavy metals, aerosols and nanoparticles, Polycyclic Aromatic Hydrocarbons, and dioxins. Major options in flue gas cleaning can be derived from Best Available Technologies (BAT), as were developed in the European Union. Hence, E.U. practice is analyzed in some detail, by considering the present situation in selected E.U. countries (Germany, Sweden, the Netherlands, Denmark, Belgium). A comparison is made with China. Also, the situation in Japan is examined. Based on this wide experience, a number of technical suggestions regarding incineration, flue gas cleaning, and emission control are formulated. Also, the possibility of co incineration is considered. Starting from the particular experience of Zhejiang University (as a designer of Fluid Bed and Rotary Kiln plant, with large experience in Fluid Bed processes, coal firing, gasification and pyrolysis, and actively monitoring thermal units throughout China) some specific Case Studies are examined, e.g., a fluidized bed incinerator and its gas cleaning system (MSWI and HWI from ITPE). Some attention is paid to the potential threats in China from uncontrolled combustion sources. As a conclusion, some recommendations are formulated regarding flue gas cleaning in Developing Nations at large and in China in particular. (author)

Laser paper cleaning: the method of cleaning historical books

Science.gov (United States)

Zekou, Evangelini; Tsilikas, Ioannis; Chatzitheodoridis, Elias; Serafetinides, Alexander A.

2016-01-01

Conservation of cultural heritage treasures is the most important issue for transferring knowledge to the public through the next generation of students, academics, and researchers. Although this century is authenticating e-books and information by means of electronic text, still historical manuscripts as content as well as objects are the main original recourses of keeping a record of this transformation. The current work focuses on cleaning paper samples by the application of pulsed light, which is interventional. Experiments carried out using paper samples that are artificially colonized with Ulocladium chartarum. Paper is treated by Nd:YAG laser light. The available wavelength is 1064 nm, at various fluences, repetition rates and number of pulses. Two types of paper are stained with fungi colonies, which grow on substrates of clean paper, as well as on paper with ink text. The first type of paper is Whatman No.1056, which is closer to pure cellulose. The second type of paper is a page of a cultural heritage book published in 1926. Cleaning is performed using laser irradiation, thus defining the damage threshold of each sample. The treatment on paper Watman showed a yellowing, especially on areas with high concentration of fungi. The second sample was more durable to the exposure, performing the best results at higher fluences. Eventually, the paper samples are characterized, with optical microscopy and SEM/EDX analyses, prior to and after cleaning.

Summary report of the Banff clean energy dialogue : towards a truly Canadian clean energy strategy

Energy Technology Data Exchange (ETDEWEB)

NONE

2010-07-01

A clean energy strategy will allow Canada to seize opportunities for prosperity in a low-carbon future, while also contributing to the country's economic growth. This report outlined the conclusions drawn by representatives of major energy corporations and policy-makers who gathered to discuss Canada's clean energy plans for the future. Attendants at the meeting concluded that energy conservation and energy efficiency will play a prominent role in a successful clean energy strategy. However, a price on carbon is needed to emphasize the fundamental relationship between energy and the environment. A successful strategy will feature the following 4 overarching principles: (1) economic opportunity, (2) social responsibility, (3) environmental stewardship, and (4) international strategy in relation to trade and development of new markets. The role that federal, provincial and municipal governments will play in developing and implementing the strategy was also presented. The meeting was divided into the following 6 working sessions: (1) global context for a clean energy strategy, (2) why a Canadian clean energy strategy? Why now?, (3) key pillars of a Canadian clean energy strategy, (4) key building blocks of a national clean energy strategy, (5) a balanced Canadian framework, and (6) next steps. 1 fig.

Cleaning of biomaterial surfaces: protein removal by different solvents.

Science.gov (United States)

Kratz, Fabian; Grass, Simone; Umanskaya, Natalia; Scheibe, Christian; Müller-Renno, Christine; Davoudi, Neda; Hannig, Matthias; Ziegler, Christiane

2015-04-01

The removal of biofilms or protein films from biomaterials is still a challenging task. In particular, for research investigations on real (applied) surfaces the reuse of samples is of high importance, because reuse allows the comparison of the same sample in different experiments. The aim of the present study was to evaluate the cleaning efficiency of different solvents (SDS, water, acetone, isopropanol, RIPA-buffer and Tween-20) on five different biomaterials (titanium, gold, PMMA (no acetone used), ceramic, and PTFE) with different wettability which were covered by layers of two different adsorbed proteins (BSA and lysozyme). The presence of a protein film after adsorption was confirmed by transmission electron microscopy (TEM). After treatment of the surfaces with the different solvents, the residual proteins on the surface were determined by BCA-assay (bicinchoninic acid assay). Data of the present study indicate that SDS is an effective solvent, but for several protein-substrate combinations it does not show the cleaning efficiency often mentioned in literature. RIPA-buffer and Tween-20 were more effective. They showed very low residual protein amounts after cleaning on all examined material surfaces and for both proteins, however, with small differences for the respective substrate-protein combinations. RIPA-buffer in combination with ultrasonication completely removed the protein layer as confirmed by TEM. Copyright © 2015 Elsevier B.V. All rights reserved.

Heart pacemaker - discharge

Science.gov (United States)

Cardiac pacemaker implantation - discharge; Artificial pacemaker - discharge; Permanent pacemaker - discharge; Internal pacemaker - discharge; Cardiac resynchronization therapy - discharge; CRT - discharge; ...

Multi-perspective comparisons and mitigation implications of SO2 and NO x discharges from the industrial sector of China: a decomposition analysis.

Science.gov (United States)

Jia, Junsong; Gong, Zhihai; Gu, Zhongyu; Chen, Chundi; Xie, Dongming

2018-04-01

This study is the first attempt to investigate the drivers of Chinese industrial SO 2 and NO x emissions from both periodic and structural perspectives through a decomposition analysis using the logarithmic mean Divisia index (LMDI). The two pollutants' emissions were decomposed into output effects, structural effects, clean production effects, and pollution abatement effects. The results showed that China's industrial SO 2 discharge increased by 1.14 Mt during 2003-2014, and the contributions from the four effects were 23.17, - 1.88, - 3.80, and - 16.36 Mt, respectively. Likewise, NO x discharge changed by - 3.44 Mt over 2011-2014, and the corresponding contributions from the four effects were 2.97, - 0.62, - 1.84, and - 3.95 Mt. Thus, the output effect was mainly responsible for the growth of the two discharges. The average annual contribution rates of SO 2 and NO x from output were 14.33 and 5.97%, respectively, but pollution abatement technology presented the most obvious mitigating effects (- 10.11 and - 7.92%), followed by the mitigating effects of clean production technology (- 2.35 and - 3.7%), and the mitigation from the structural effect was the weakest (- 1.16 and - 1.25%, respectively), which meant pollutant reduction policies related to industrial structure adjustment should be a long-term measure for the two discharges. In addition, the sub-sectors of I20 (manufacture of raw chemical materials and chemical products), I24 (manufacture of non-metallic mineral products), and I26 (smelting and pressing of non-ferrous metals) were the major contributors to both discharges. Thus, these sub-sectors should be given priority consideration when designing mitigation-related measures. Last, some particular policy implications were recommended for reducing the two discharges, including that the government should seek a technological discharge reduction route.

Enhanced degradation of p-chlorophenol in a novel pulsed high voltage discharge reactor.

Science.gov (United States)

Bian, Wenjuan; Ying, Xiangli; Shi, Junwen

2009-03-15

The yields of active specie such as ozone, hydrogen peroxide and hydroxyl radical were all enhanced in a novel discharge reactor. In the reactor, the original formation rate of hydroxyl radical was 2.27 x 10(-7) mol L(-1)s(-1), which was about three times than that in the contrast reactor. Ozone was formed in gas-phase and was transferred into the liquid. The characteristic of mass transfer was better in the novel reactor than that in the contrast reactor, which caused much higher ozone concentration in liquid. The dissociation of hydrogen peroxide was more evident in the former, which promoted the formations of hydroxyl radical. The p-chlorophenol (4-CP) degradation was also enhanced. Most of the ozone transferred into the liquid and hydrogen peroxide generated by discharge could be utilized by the degradation process of 4-CP. About 97% 4-CP was removed in 36 min discharge in the novel reactor. Organic acids such as formic, acetic, oxalic, propanoic and maleic acid were generated and free chloride ions were released in the degradation process. With the formation of organic acid, the pH was decreased and the conductivity was increased.

Enhanced degradation of p-chlorophenol in a novel pulsed high voltage discharge reactor

Energy Technology Data Exchange (ETDEWEB)

Bian Wenjuan [School of Chemistry and Chemical Engineering, Soochow University, Suzhou 215123 (China)], E-mail: bwenjuan@suda.edu.cn; Ying Xiangli; Shi Junwen [School of Chemistry and Chemical Engineering, Soochow University, Suzhou 215123 (China)

2009-03-15

The yields of active specie such as ozone, hydrogen peroxide and hydroxyl radical were all enhanced in a novel discharge reactor. In the reactor, the original formation rate of hydroxyl radical was 2.27 x 10{sup -7} mol L{sup -1} s{sup -1}, which was about three times than that in the contrast reactor. Ozone was formed in gas-phase and was transferred into the liquid. The characteristic of mass transfer was better in the novel reactor than that in the contrast reactor, which caused much higher ozone concentration in liquid. The dissociation of hydrogen peroxide was more evident in the former, which promoted the formations of hydroxyl radical. The p-chlorophenol (4-CP) degradation was also enhanced. Most of the ozone transferred into the liquid and hydrogen peroxide generated by discharge could be utilized by the degradation process of 4-CP. About 97% 4-CP was removed in 36 min discharge in the novel reactor. Organic acids such as formic, acetic, oxalic, propanoic and maleic acid were generated and free chloride ions were released in the degradation process. With the formation of organic acid, the pH was decreased and the conductivity was increased.

Enhanced degradation of p-chlorophenol in a novel pulsed high voltage discharge reactor

International Nuclear Information System (INIS)

Bian Wenjuan; Ying Xiangli; Shi Junwen

2009-01-01

The yields of active specie such as ozone, hydrogen peroxide and hydroxyl radical were all enhanced in a novel discharge reactor. In the reactor, the original formation rate of hydroxyl radical was 2.27 x 10 -7 mol L -1 s -1 , which was about three times than that in the contrast reactor. Ozone was formed in gas-phase and was transferred into the liquid. The characteristic of mass transfer was better in the novel reactor than that in the contrast reactor, which caused much higher ozone concentration in liquid. The dissociation of hydrogen peroxide was more evident in the former, which promoted the formations of hydroxyl radical. The p-chlorophenol (4-CP) degradation was also enhanced. Most of the ozone transferred into the liquid and hydrogen peroxide generated by discharge could be utilized by the degradation process of 4-CP. About 97% 4-CP was removed in 36 min discharge in the novel reactor. Organic acids such as formic, acetic, oxalic, propanoic and maleic acid were generated and free chloride ions were released in the degradation process. With the formation of organic acid, the pH was decreased and the conductivity was increased

The Clean Energy Manufacturing Analysis Center (CEMAC): Providing Analysis and Insights on Clean Technology Manufacturing

Energy Technology Data Exchange (ETDEWEB)

Johnson, Nicholi S [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

2017-09-28

The U.S. Department of Energy's Clean Energy Manufacturing Analysis Center (CEMAC) provides objective analysis and up-to-date data on global supply chains and manufacturing of clean energy technologies. Policymakers and industry leaders seek CEMAC insights to inform choices to promote economic growth and the transition to a clean energy economy.

Enhanced antimony(V) removal using synergistic effects of Fe hydrolytic flocs and ultrafiltration membrane with sludge discharge evaluation.

Science.gov (United States)

Ma, Baiwen; Wang, Xing; Liu, Ruiping; Qi, Zenglu; Jefferson, William A; Lan, Huachun; Liu, Huijuan; Qu, Jiuhui

2017-09-15

The integration of adsorbents with ultrafiltration (UF) membranes is a promising method for alleviating membrane fouling and reducing land use. However, a number of problems have become apparent concerning the granular adsorbents used currently, such as high running cost, high chance of causing membrane surface damage, low in situ chemical cleaning efficiency, etc. Herein, to overcome these disadvantages, loose in situ hydrolyzed flocs were directly injected into the membrane tank, providing strong adsorption ability at low cost. To test the feasibility of this method, the heavy metal pollutant antimony (Sb (V)) in a water plant was chosen at a test case, which is similar to arsenic and difficult to remove. We found that Fe-based flocs integrated with an UF membrane showed a large potential advantage in removing Sb(V), even after running for 110 days. We demonstrated that the observed slow transmembrane pressure development could be ascribed to the loose floc cake layer formed, even though some extracellular polymeric substances were induced during operation. We also found that the floc cake layer was easily removed by washing with feed water or dissolved by in situ chemical cleaning under strongly acidic conditions, and many primary membrane pores were clearly observed. In addition, a relative long sludge discharge interval was feasible for this technology and the effluent quality was good, including the turbidity, chromaticity and iron concentration. Based on the excellent performance, these flocs integrated with UF membranes indeed show potential for application in water treatment. Copyright © 2017 Elsevier Ltd. All rights reserved.

Shoulder replacement - discharge

Science.gov (United States)

Total shoulder arthroplasty - discharge; Endoprosthetic shoulder replacement - discharge; Partial shoulder replacement - discharge; Partial shoulder arthroplasty - discharge; Replacement - shoulder - discharge; Arthroplasty - shoulder - discharge

Evaluation of the potential of soil remediation by direct multi-channel pulsed corona discharge in soil.

Science.gov (United States)

Wang, Tie Cheng; Qu, Guangzhou; Li, Jie; Liang, Dongli

2014-01-15

A novel approach, named multi-channel pulsed corona discharge in soil, was developed for remediating organic pollutants contaminated soil, with p-nitrophenol (PNP) as the model pollutant. The feasibility of PNP degradation in soil was explored by evaluating effects of pulse discharge voltage, air flow rate and soil moisture on PNP degradation. Based on roles of chemically active species and evolution of degradation intermediates, PNP degradation processes were discussed. Experimental results showed that about 89.4% of PNP was smoothly degraded within 60min of discharge treatment at pulse discharge voltage 27kV, soil moisture 5% and air flow rate 0.8Lmin(-1), and the degradation process fitted the first-order kinetic model. Increasing pulse discharge voltage was found to be favorable for PNP degradation, but not for energy yield. There existed appropriate air flow rate and soil moisture for obtaining gratifying PNP degradation efficacy. Roles of radical scavenger and measurement of active species suggested that ozone, H2O2, and OH radicals played very important roles in PNP degradation. CN bond in PNP molecule was cleaved, and the main intermediate products such as hydroquinone, benzoquinone, catechol, phenol, acetic acid, formic acid, oxalic acid, NO2(-) and NO3(-) were identified. Possible pathway of PNP degradation in soil in such a system was proposed. Copyright © 2013 Elsevier B.V. All rights reserved.

Mechanical cleaning of graphene

NARCIS (Netherlands)

Goossens, A.M.; Calado, V.E.; Barreiro, A.; Watanabe, K.; Taniguchi, T.; Vandersypen, L.M.K.

2012-01-01

Contamination of graphene due to residues from nanofabrication often introduces background doping and reduces electron mobility. For samples of high electronic quality, post-lithography cleaning treatments are therefore needed. We report that mechanical cleaning based on contact mode atomic force

Treatment of bilge and oily drain water of tankers and current measures against combustible oil gas discharge; Tanker no biruji yudakusui shori oyobi kanensei sekiyu gas haishutsu taiskau no genjo

Energy Technology Data Exchange (ETDEWEB)

Agatsuma, Y.

1996-07-25

This paper describes the current actual conditions on treatment of bilge discharged from engine area and oily drain water from cargo area of tankers. Clean bilge among various bilges discharged from engine area such as vapor drain, fresh water, rainwater, seawater and condensed water is directly dumped into the sea after temporary storage in a clean tank. Oily bilge is produced mainly by mixing of clean bilge and leakage oil from main engines and various auxiliaries. Oily bilge is dumped into the sea under comparative monitoring of the bilge quality with the dumping standard by oil concentration monitoring and control equipment after the primary treatment in a treatment tank and the secondary treatment in a bilge separator. Oily drain water from cargo area contains water ballast for cargo oil tanks, wash water for tanks and lines, and bilge produced in pump room. The oily drain water is dumped under a specific condition. However, water ballast for specific ballast tanks is excluded from the oily drain water. 2 figs.

''In sutu'' radiation cleaning of underground water contaminated with cyanides - six years of experience

International Nuclear Information System (INIS)

Pastuszek, F.; Vacek, K.; Vondruska, V.

1993-01-01

Underground water, contaminated with cyanides, has been successfully cleaned using the hydraulic barrier method (assembly of pumped wells) since 1986. The average cyanide concentrations in the outflow exceeded 35 mg per litre. Contamination had to be eliminated before the discharge into the sewer system. The radiation approach ''in situ'' i.e. decomposition of cyanides by barrier, was applied and is still being used today. The cyanide concentration was lowered more than one order of magnitude. This process was approved by the Czechoslovak radiation security authorities and further applications of ''in situ'' regeneration of underground water contamination is anticipated. (author)

Metal speciation and potential bioavailability changes during discharge and neutralisation of acidic drainage water.

Science.gov (United States)

Simpson, Stuart L; Vardanega, Christopher R; Jarolimek, Chad; Jolley, Dianne F; Angel, Brad M; Mosley, Luke M

2014-05-01

The discharge of acid drainage from the farm irrigation areas to the Murray River in South Australia represents a potential risk to water quality. The drainage waters have low pH (2.9-5.7), high acidity (up to 1190 mg L(-1) CaCO3), high dissolved organic carbon (10-40 mg L(-1)), and high dissolved Al, Co, Ni and Zn (up to 55, 1.25, 1.30 and 1.10 mg L(-1), respectively) that represent the greatest concern relative to water quality guidelines (WQGs). To provide information on bioavailability, changes in metal speciation were assessed during mixing experiments using filtration (colloidal metals) and Chelex-lability (free metal ions and weak inorganic metal complexes) methods. Following mixing of drainage and river water, much of the dissolved aluminium and iron precipitated. The concentrations of other metals generally decreased conservatively in proportion to the dilution initially, but longer mixing periods caused increased precipitation or adsorption to particulate phases. Dissolved Co, Mn and Zn were typically 95-100% present in Chelex-labile forms, whereas 40-70% of the dissolved nickel was Chelex-labile and the remaining non-labile fraction of dissolved nickel was associated with fine colloids or complexed by organic ligands that increased with time. Despite the different kinetics of precipitation, adsorption and complexation reactions, the dissolved metal concentrations were generally highly correlated for the pooled data sets, indicating that the major factors controlling the concentrations were similar for each metal (pH, dilution, and time following mixing). For dilutions of the drainage waters of less than 1% with Murray River water, none of the metals should exceed the WQGs. However, the high concentrations of metals associated with fine precipitates within the receiving waters may represent a risk to some aquatic organisms. Crown Copyright © 2013. Published by Elsevier Ltd. All rights reserved.

National Clean Fleets Partnership (Fact Sheet)

Energy Technology Data Exchange (ETDEWEB)

2012-01-01

Provides an overview of Clean Cities National Clean Fleets Partnership (NCFP). The NCFP is open to large private-sector companies that have fleet operations in multiple states. Companies that join the partnership receive customized assistance to reduce petroleum use through increased efficiency and use of alternative fuels. This initiative provides fleets with specialized resources, expertise, and support to successfully incorporate alternative fuels and fuel-saving measures into their operations. The National Clean Fleets Partnership builds on the established success of DOE's Clean Cities program, which reduces petroleum consumption at the community level through a nationwide network of coalitions that work with local stakeholders. Developed with input from fleet managers, industry representatives, and Clean Cities coordinators, the National Clean Fleets Partnership goes one step further by working with large private-sector fleets.

On the mechanism of high-voltage discharge initiation in high-voltage accelerator accelerating tubes

International Nuclear Information System (INIS)

Zheleznikov, F.G.

1983-01-01

Experimental investigation into physical natupe of discharge processes in high-voltage accelerator accelerating tubes in the absence of the accelerated particle beam are conducted. The installation for the study of the mechanism of initiating vacuum isolation conductivity is used in the experiments. The vacuum chamber of the installation is made of steel and sealed with rubber packings. Electrodes 300-360 mm in diameter are made of stainless steel. Two variants of cleaning technology were used before electrode assembling: 1) degreasing by organic solvents; 2) cleaning by fine grinding cloth with successive washing by rectificated alcohol. Analysis of the obtained data shows that forma. tion of background flux of charged particles in interelectrode gap is caused by external photoelectric effect, excited by X radiation, which initiates the formation of intensive internal field in microfilms of non-conducting impurities on the electrode surfaces. The secondary electron emission plays the minor role at that

Design, test and start up of a cleaning system for the moderator tank bottom of Atucha I Nuclear Power Plant

International Nuclear Information System (INIS)

Duca, J.; Gerber, O.; Ibero, M.; Riga, N.

1989-01-01

In order to perform the cleaning of the moderator tank bottom, during the repair of the Atucha I nuclear power plant (CNA I) failure, the Empresa Nuclear Argentina de Centrales Electricas (ENACE S.A.) designed a system with the following requirements (asked by CNA I): a) To aspirate and retain free solid particles, uranium dioxide pellets and coolant channels isolations (foils) of minor size settled at the moderator tank bottom, being the reactor at middle loop state. b) To allow a radially cleaning up to 1.4 m from the extracted channel. c) To design a lay-out attaining the ALARA dose exposure. The designed system basically consists in: a) Flexible intake for suction: allows the movement inside the moderator tank and provides the adequate speed to raise the particles. b) Filter: retains the aspirated particles, pellets and foils. Its capacity is 1.8 dm 3 and the minimum size of retained particles is 200 m. The ALARA dose exposure concept is attained due to that the filter is located inside the moderator tank. c) Filtering column: contains the filter and allows the entrance of the extraction and exchange tool (for the flexible intake and filter). d) Suction hose: connects the filtering column with the pump. Its flexibility allows its use in any channel maintaining the same positions of the discharge pump and the return piping. e) Discharge pump: it is a canned centrifugal pump with low-low net positive suction head. f) Return piping: discharges the filtered water into the moderator tank. The system fulfilled satisfactorily all requirements during its operation. (Author)

Fabrication of TiO2/Carbon Photocatalyst using Submerged DC Arc Discharged in Ethanol/Acetic Acid Medium

Science.gov (United States)

Saraswati, T. E.; Nandika, A. O.; Andhika, I. F.; Patiha; Purnawan, C.; Wahyuningsih, S.; Rahardjo, S. B.

2017-05-01

This study aimed to fabricate a modified photocatalyst of TiO2/C to enhance its performance. The fabrication was achieved using the submerged direct current (DC) arc-discharge method employing two graphite electrodes, one of which was filled with a mixture of carbon powder, TiO2, and binder, in ethanol with acetic acid added in various concentrations. The arc-discharge method was conducted by flowing a current of 10-20 A (~20 V). X-ray diffraction (XRD) patterns showed significant placements of the main peak characteristics of TiO2, C graphite, and titanium carbide. The surface analysis using Fourier transform infrared spectroscopy (FTIR) revealed that fabricated TiO2/C nanoparticles had stretching vibrations of Ti-O, C-H, C═O, C-O, O-H and C═C in the regions of 450-550 cm-1, 2900-2880 cm-1, 1690-1760 cm-1, 1050-1300 cm-1, 3400-3700 cm-1 and ~1600 cm-1, respectively. In addition, the study investigated the photocatalysts of unmodified and modified TiO2/C for photodegradation of methylene blue (MB) dye solution under mercury lamp irradiation. The effectiveness of the degradation was defined by the decrease in 60-minute absorbance under a UV-Vis spectrophotometer. Modified TiO2/C proved to be significantly more efficient in reducing dye concentrations, reaching ~70%. It indicated that the oxygen-containing functional groups have been successfully attached to the surface of the nanoparticles and played a role in enhancing photocatalytic activity.

Heat exchanger cleaning

International Nuclear Information System (INIS)

Gatewood, J.R.

1980-01-01

A survey covers the various types of heat-exchange equipment that is cleaned routinely in fossil-fired generating plants, the hydrocarbon-processing industry, pulp and paper mills, and other industries; the various types, sources, and adverse effects of deposits in heat-exchange equipment; some details of the actual procedures for high-pressure water jetting and chemical cleaning of some specific pieces of equipment, including nuclear steam generators. (DN)

EM-21 Alternative Enhanced Chemical Cleaning Program For Sludge Heel Removal

International Nuclear Information System (INIS)

Hay, M.; King, W.; Martino, C.

2009-01-01

Preliminary studies in the EM-21 Alternative Chemical Cleaning Program have focused on understanding the dissolution of Hematite (a primary sludge heel phase) in oxalic acid, with a focus on minimizing oxalic acid usage. Literature reviews, thermodynamic modeling, and experimental results have all confirmed that pH control, preferably using a supplemental proton source, is critical to oxalate minimization. With pH control, iron concentrations as high as 0.103 M have been obtained in 0.11 M oxalic acid. This is consistent with the formation of a 1:1 (iron:oxalate) complex. The solubility of Hematite in oxalic acid has been confirmed to increase by a factor of 3 when the final solution pH decreases from 5 to below 1. This is consistent with literature predictions of a shift in speciation from a 1:3 to 1:1 as the pH is lowered. Above a solution pH of 6, little Hematite dissolves. These results emphasize the importance of pH control in optimizing Hematite dissolution in oxalic acid.

Vertically Aligned Graphene Sheets Membrane for Highly Efficient Solar Thermal Generation of Clean Water.

Science.gov (United States)

Zhang, Panpan; Li, Jing; Lv, Lingxiao; Zhao, Yang; Qu, Liangti

2017-05-23

Efficient utilization of solar energy for clean water is an attractive, renewable, and environment friendly way to solve the long-standing water crisis. For this task, we prepared the long-range vertically aligned graphene sheets membrane (VA-GSM) as the highly efficient solar thermal converter for generation of clean water. The VA-GSM was prepared by the antifreeze-assisted freezing technique we developed, which possessed the run-through channels facilitating the water transport, high light absorption capacity for excellent photothermal transduction, and the extraordinary stability in rigorous conditions. As a result, VA-GSM has achieved average water evaporation rates of 1.62 and 6.25 kg m -2 h -1 under 1 and 4 sun illumination with a superb solar thermal conversion efficiency of up to 86.5% and 94.2%, respectively, better than that of most carbon materials reported previously, which can efficiently produce the clean water from seawater, common wastewater, and even concentrated acid and/or alkali solutions.

Air cleaning using regenerative silica gel wheel

DEFF Research Database (Denmark)

Fang, Lei

2011-01-01

This paper discussed the necessity of indoor air cleaning and the state of the art information on gas-phase air cleaning technology. The performance and problems of oxidation and sorption air cleaning technology were summarized and analysed based on the literature studies. Eventually, based...... on an experimental study, a technology called clean air heat pump is proposed as a practical approach for indoor air cleaning....

Green Cleaning Label Power

Science.gov (United States)

Balek, Bill

2012-01-01

Green cleaning plays a significant and supportive role in helping education institutions meet their sustainability goals. However, identifying cleaning products, supplies and equipment that truly are environmentally preferable can be daunting. The marketplace is inundated with products and services purporting to be "green" or environmentally…

Gas turbine cleaning upgrade (compressor wash)

Energy Technology Data Exchange (ETDEWEB)

Asplund, P [Gas Turbine Efficiency, Jarfalla (Sweden)

1999-12-31

The influence of gas turbine degradation on operating costs is high. Gas turbine cleaning is one of many actions taken for power recovery and is to consider as preventive maintenance. It is generally performed within the industrial field and occasionally within the aero sector. In order to meet the gas turbine development win high blade loads and ever-increasing temperatures, together with emission Aces and environmental regulations, more efficient and careful cleaning methods are needed. Following a survey about potentials for cost reduction in gas turbine operation a new man-hour and water saving cleaning method has been evaluated for a standard process. Compared with traditional cleaning methods, the new method is water,- cost,- weight and space saving due to a new washing technique. Traditional methods are based on using different nozzles for ON and OFF-line cleaning, which rise the demand for complicated systems. In the new method the same nozzle installation, same liquid flow and pressure is used for both ON and OFF-line cleaning. This gives a cost reduction of appr. 20.000 - 30.000 USD per gas turbine depending on installation and size. Evaluation of the new method shows significantly improved ON -line cleaning performance and thus OFF -line cleaning is required only during scheduled stops. (orig.) 10 refs.

Gas turbine cleaning upgrade (compressor wash)

Energy Technology Data Exchange (ETDEWEB)

Asplund, P. [Gas Turbine Efficiency, Jarfalla (Sweden)

1998-12-31

The influence of gas turbine degradation on operating costs is high. Gas turbine cleaning is one of many actions taken for power recovery and is to consider as preventive maintenance. It is generally performed within the industrial field and occasionally within the aero sector. In order to meet the gas turbine development win high blade loads and ever-increasing temperatures, together with emission Aces and environmental regulations, more efficient and careful cleaning methods are needed. Following a survey about potentials for cost reduction in gas turbine operation a new man-hour and water saving cleaning method has been evaluated for a standard process. Compared with traditional cleaning methods, the new method is water,- cost,- weight and space saving due to a new washing technique. Traditional methods are based on using different nozzles for ON and OFF-line cleaning, which rise the demand for complicated systems. In the new method the same nozzle installation, same liquid flow and pressure is used for both ON and OFF-line cleaning. This gives a cost reduction of appr. 20.000 - 30.000 USD per gas turbine depending on installation and size. Evaluation of the new method shows significantly improved ON -line cleaning performance and thus OFF -line cleaning is required only during scheduled stops. (orig.) 10 refs.

Factors Affecting the Discharge of Micro-Plastic Fibers from Household Laundry

Science.gov (United States)

Lange, N.

2017-12-01

Every day millions of loads of laundry are done in in the United States alone. Many, if not most, include synthetic fibers. During washing, micro-plastic fibers are released from the fabric, and discharged into the wastewater. These fibers have been detected in fresh water throughout the world and all of the oceans. These micro-plastic fibers are an emerging environmental contaminant that can adversely affect wildlife and are highly bio-accumulated in aquatic food-chains. Additionally, like other plastics, micro-fibers are not readily biodegraded and persist in the environment for a long time. In this research, I explored the effect of the way we wash clothes on the amount of micro-plastic fibers that are shed by common clothing materials containing man-made fibers. I collected discharge samples from wash and rinse cycles of a washing machine. I collected samples from a control wash using no detergent and then repeated five times. Next, I repeated the experiment five times using four different types of detergent. Large amounts of micro-plastic fibers were released during all wash cycles. However, the numbers decreased during the later rinse cycles. The use of laundry detergent increased the number of micro-plastic fibers released into the wash-water. Deep cleaning detergents produced over ten times more fibers than the no-detergent control. The gentlest detergent only released two times more fibers than the control. Therefore, it would be possible to affect the number of fibers released into the wastewater simply by selection of detergent. The ultimate goal of my research is to develop an optimized detergent that minimizes the number of micro-plastic fibers generated by washing and still effectively clean clothes.

Methanol and ethanol vapor conversion in gas discharge with strongly non-uniform distribution of electric field on atmospheric pressure

International Nuclear Information System (INIS)

Golota, V.I.; Zavada, L.M.; Kotyukov, O.V.; Kudin, D.V.; Rodionov, S.V.; Pis'menetskoj, A.S.; Dotsenko, Yu.V.

2010-01-01

The barrierless gas discharge of negative polarity with strongly non-uniform distribution of electrical field in the methanol and ethanol vapour was studied. It is shown that level of methanol and ethanol conversion depended from power consumed by the discharge and exposition time for gas mixture in discharge zone. The condition for deep conversion of the methanol and ethanol vapours were determined. The water and carbon dioxide are the end products for the methanol and ethanol conversion. Formaldehyde and formic acid are the intermediates products in the conversion of methanol. And ethanol has a number of different compounds, including acetic acid, acetaldehyde, etc.

Clean room actuators

Energy Technology Data Exchange (ETDEWEB)

Higuchi, Toshiro

1987-06-01

This report explains on the present status of the clean room actuators including the author's research results. In a clean room, there exists a possibility of dust generation, even when a direct human work is eliminated by the use of robots or automatic machines, from the machines themselves. For this, it is important to develop such clean robots and transfer/positioning mechanism that do not generate dusts, and to develop an actuator and its control technique. Topics described in the report are as follows: 1. Prevention of dust diffusion by means of sealing. 2. Elimination of mechanical contact (Linear induction motor and pneumatic float, linear motor and magnetic attraction float, linear motor and air bearing, and magnetic bearing). 3. Contactless actuator having a positioning mechanism (Use of linear step motor and rotary contactless actuator). (15 figs, 11 refs)

Atomic hydrogen cleaning of EUV multilayer optics

Science.gov (United States)

Graham, Samuel, Jr.; Steinhaus, Charles A.; Clift, W. Miles; Klebanoff, Leonard E.; Bajt, Sasa

2003-06-01

Recent studies have been conducted to investigate the use of atomic hydrogen as an in-situ contamination removal method for EUV optics. In these experiments, a commercial source was used to produce atomic hydrogen by thermal dissociation of molecular hydrogen using a hot filament. Samples for these experiments consisted of silicon wafers coated with sputtered carbon, Mo/Si optics with EUV-induced carbon, and bare Si-capped and Ru-B4C-capped Mo/Si optics. Samples were exposed to an atomic hydrogen source at a distance of 200 - 500 mm downstream and angles between 0-90° with respect to the source. Carbon removal rates and optic oxidation rates were measured using Auger electron spectroscopy depth profiling. In addition, at-wavelength peak reflectance (13.4 nm) was measured using the EUV reflectometer at the Advanced Light Source. Data from these experiments show carbon removal rates up to 20 Å/hr for sputtered carbon and 40 Å/hr for EUV deposited carbon at a distance of 200 mm downstream. The cleaning rate was also observed to be a strong function of distance and angular position. Experiments have also shown that the carbon etch rate can be increased by a factor of 4 by channeling atomic hydrogen through quartz tubes in order to direct the atomic hydrogen to the optic surface. Atomic hydrogen exposures of bare optic samples show a small risk in reflectivity degradation after extended periods. Extended exposures (up to 20 hours) of bare Si-capped Mo/Si optics show a 1.2% loss (absolute) in reflectivity while the Ru-B4C-capped Mo/Si optics show a loss on the order of 0.5%. In order to investigate the source of this reflectivity degradation, optic samples were exposed to atomic deuterium and analyzed using low energy ion scattering direct recoil spectroscopy to determine any reactions of the hydrogen with the multilayer stack. Overall, the results show that the risk of over-etching with atomic hydrogen is much less than previous studies using RF discharge cleaning

Plasma Discharge Process in a Pulsed Diaphragm Discharge System

Science.gov (United States)

Duan, Jianjin; Hu, Jue; Zhang, Chao; Wen, Yuanbin; Meng, Yuedong; Zhang, Chengxu

2014-12-01

As one of the most important steps in wastewater treatment, limited study on plasma discharge process is a key challenge in the development of plasma applications. In this study, we focus on the plasma discharge process of a pulsed diaphragm discharge system. According to the analysis, the pulsed diaphragm discharge proceeds in seven stages: (1) Joule heating and heat exchange stage; (2) nucleated site formation; (3) plasma generation (initiation of the breakdown stage); (4) avalanche growth and plasma expansion; (5) plasma contraction; (6) termination of the plasma discharge; and (7) heat exchange stage. From this analysis, a critical voltage criterion for breakdown is obtained. We anticipate this finding will provide guidance for a better application of plasma discharges, especially diaphragm plasma discharges.

40 CFR 63.744 - Standards: Cleaning operations.

Science.gov (United States)

2010-07-01

... system with equivalent emission control. (e) Exempt cleaning operations. The following cleaning...) Cleaning of aircraft and ground support equipment fluid systems that are exposed to the fluid, including... 40 Protection of Environment 10 2010-07-01 2010-07-01 false Standards: Cleaning operations. 63.744...

Significant OH production under surface cleaning and air cleaning conditions: Impact on indoor air quality.

Science.gov (United States)

Carslaw, N; Fletcher, L; Heard, D; Ingham, T; Walker, H

2017-11-01

We report measurements of hydroxyl (OH) and hydroperoxy (HO 2 ) radicals made by laser-induced fluorescence spectroscopy in a computer classroom (i) in the absence of indoor activities (ii) during desk cleaning with a limonene-containing cleaner (iii) during operation of a commercially available "air cleaning" device. In the unmanipulated environment, the one-minute averaged OH concentration remained close to or below the limit of detection (6.5×10 5  molecule cm -3 ), whilst that of HO 2 was 1.3×10 7  molecule cm -3 . These concentrations increased to ~4×10 6 and 4×10 8  molecule cm -3 , respectively during desk cleaning. During operation of the air cleaning device, OH and HO 2 concentrations reached ~2×10 7 and ~6×10 8  molecule cm -3 respectively. The potential of these OH concentrations to initiate chemical processing is explored using a detailed chemical model for indoor air (the INDCM). The model can reproduce the measured OH and HO 2 concentrations to within 50% and often within a few % and demonstrates that the resulting secondary chemistry varies with the cleaning activity. Whilst terpene reaction products dominate the product composition following surface cleaning, those from aromatics and other VOCs are much more important during the use of the air cleaning device. © 2017 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

Cleaning up a biodiesel plant

International Nuclear Information System (INIS)

Wallace, Paula

2012-01-01

Full text: The project at Biodiesel Producers Limited in Victoria involved remediation of a wastewater treatment process containing a large covered anaerobic lagoon, an aerobic sequencing batch reactor (SBR) and a series of downstream open ponds. The pond downstream of the SBR was heavily loaded with a thick hard grease cap. The CAL was believed to have a metre-plus grease cap and the SBR had developed a thick foam cap that prevented aeration and mixing. Environmental Biotech was called in to assist with bioremediation using its Grease Eradication System bacteria cultures, with the aim of reducing the fats, oil and grease in the CAL discharge to less than 150 milligrams per litre, eliminating the stable fat foam in the SBR to allow the denitrification sequencing program to be reinstated and to clean up the hard fat layer from the surfaces of the comany's open ponds. The inflow to the CAL was designed for a flow of 210kL per day with a loading of 6900mg/L biochemical oxygen demand and FOG of 425mg/L. The actual load, as measured by Environmental Biotech, was 100kL with 20,000mg/L BOD and 1800mg/L (180kg) FOG. The CAL had been in use for more than two years, generating methane but assumed to be working well in the breakdown of chemical oxygen demand and FOG. In December 2009 the quality of the effluent began to decrease, overloading the SBR with FOG. It caused the formation of dense foam on aeration and mixing. The foam would not break down despite a variety of methods being employed and would overflow from the walls of the SBR. “Due to the foaming issue the SBR became a large holding tank for the fat and because of the reduced mixing, the solids were settling on the bottom of the tank,” Environmental Biotech project manager and franshisee Craig Barr said. “We were brought in to start work inApril 2010 and initially we slug dosed the CAL with 400 litres of GES bacteria in addition to a constant metered dosing rate of 400 litres per fortnight with the

Double discharges in unipolar-pulsed dielectric barrier discharge xenon excimer lamps

International Nuclear Information System (INIS)

Liu Shuhai; Neiger, Manfred

2003-01-01

Excitation of dielectric barrier discharge xenon excimer lamps by unipolar short square pulses is studied in this paper. Two discharges with different polarity are excited by each voltage pulse (double discharge phenomenon). The primary discharge occurs at the top or at the rising flank of the applied unipolar square pulse, which is directly energized by the external circuit. The secondary discharge with the reversed polarity occurs at the falling flank or shortly after the falling flank end (zero external voltage) depending on the pulse width, which is energized by the energy stored by memory charges deposited by the primary discharge. Fast-speed ICCD imaging shows the primary discharge has a conic discharge appearance with a channel broadening on the anode side. This channel broadening increases with increasing the pulse top level. Only the anode-side surface discharge is observed in the primary discharge. The surface discharge on the cathode side which is present in bipolar sine voltage excitation is not observed. On the contrary, the secondary discharge has only the cathode-side surface discharge. The surface discharge on the anode side is not observed. The secondary discharge is much more diffuse than the primary discharge. Time-resolved emission measurement of double discharges show the secondary discharge emits more VUV xenon excimer radiation but less infrared (IR) xenon atomic emission than the primary discharge. It was found that the IR xenon atomic emission from the secondary discharge can be reduced by shortening the pulse width. The energy efficiency of unipolar-pulsed xenon excimer lamps (the overall energy efficiency of double discharges) is much higher than that obtained under bipolar sine wave excitation. The output VUV spectrum under unipolar pulse excitation is found to be identical to that under sine wave excitation and independent of injected electric power

Manufacturing of NAA laboratory clean room

International Nuclear Information System (INIS)

Suwoto; Hasibuan, Djaruddin

2001-01-01

The ''NAA laboratory clean room'' has been built in the Reactor Serba Guna G.A. Siwabessy building. The erection of ''AAN laboratory clean room'' doing by started of preparation of the ''manufacturing procedure'' refer to ''Design and manufacturing neutron activation analysis clean room laboratory''. Manufacturing process and erection doing refer to procedures makes. By providing of the ''AAN laboratory clean room'' can be cocluded that the research activity and the user sevises in P2TRR well meet to be done

Private Exploration Primitives for Data Cleaning

OpenAIRE

Ge, Chang; Ilyas, Ihab F.; He, Xi; Machanavajjhala, Ashwin

2017-01-01

Data cleaning, or the process of detecting and repairing inaccurate or corrupt records in the data, is inherently human-driven. State of the art systems assume cleaning experts can access the data (or a sample of it) to tune the cleaning process. However, in many cases, privacy constraints disallow unfettered access to the data. To address this challenge, we observe and provide empirical evidence that data cleaning can be achieved without access to the sensitive data, but with access to a (no...

76 FR 16646 - Circadian, Inc., Clean Energy Combustion, Inc. (n/k/a Clean Energy Combustion Systems, Inc...

Science.gov (United States)

2011-03-24

... SECURITIES AND EXCHANGE COMMISSION [File No. 500-1] Circadian, Inc., Clean Energy Combustion, Inc. (n/k/a Clean Energy Combustion Systems, Inc.), Collectible Concepts Group, Inc., Communitronics of... is a lack of current and accurate information concerning the securities of Clean Energy Combustion...

Carbon pricing comes clean

International Nuclear Information System (INIS)

De Wit, Elisa

2011-01-01

Together with the Clean Energy Bill, the implications of the Australian Federal Government's climate change legislative package are far reaching. Norton Rose gives business a heads-up in this breakdown of the draft legislation underpinning the carbon pricing and clean energy scheme. It is a summary of Norton Rose's full analysis.

Cleaning and extraction apparatus in a nuclear fuel reprocessing

International Nuclear Information System (INIS)

Nakamura, Yoshiaki.

1983-01-01

Purpose : To eliminate the requirement for the decomposition and cleaning of a centrifugal extractor upon re-processing of FBR type reactor fuels, by preventing solid fission products from depositing on a rotary body of the centrifugal extractor. Constitution : A cleaning and extraction apparatus comprising a combination of a centrifugal cleaner and a centrifugal extractor is used for shortening the contact time between the process liquid and the extraction solvent in FBR type reactor fuel re-processing, and variable parameters are adjusted so that the following equation can be satisfied for avoiding the deposition of solids onto the rotary body of the centrifugal extractor: lsub(e). (rsub(le) 2 + rsub(2r) 2 ) . Nsub(e) . Qsub(c)/ lsub(c) (rsub(lc) 2 + rsub(2c) 2 ) . Nsub(c) . Qsub(e) < 0.8 where Qsub(c) : flow rate to be processed in a centrifugal cleaner, lsub(c) : length of the rotary body, rsub(2c) : radius of a rotary body, rsub(le) : distance from the center to the liquid-extracting hole of the rotary body center to the liquid-extraction hole, Nsub(c) : number of revolution of the rotary body, Qsub(e) : amount of flowrate to be treated in the centrifugal extractor, lsub(e) : length of the rotary body, rsub(2e) : radius for the rotary body, rsub(le) : distance from the center of the rotary body to the liquid discharging aperture and Nsub(e) : number of rotation of the rotary body. (Ikeda, J.)

Sonochemical cleaning efficiencies in dental instruments

Science.gov (United States)

Tiong, T. Joyce; Walmsley, A. Damien; Price, Gareth J.

2012-05-01

Ultrasound has been widely used for cleaning purposes in a variety of situations, including in dental practice. Cleaning is achieved through a combination of acoustically driven streaming effects and sonochemical effects arising from the production of inertial cavitation in a liquid. In our work, various dental instruments used for endodontic (root canal) treatment have been evaluated for their efficiency in producing sonochemical effects in an in-vitro cleaning environment. The areas where cavitation was produced were mapped by monitoring chemiluminescence from luminol solutions and this was correlated with their cleaning efficiencies - assessed by the ability to bleach a dye, to form an emulsion by mixing immiscible components and also to remove ink from a glass surface. The results showed good correlation (Pearson's coefficient > 0.9) between the cavitation and cleaning efficiencies, suggesting that the former plays an important role in cleaning. The methods developed and the results will be beneficial in endodontics research in order to optimise future root canal instruments and treatments.

Pre-staining thin layer chromatography method for amino acid ...

African Journals Online (AJOL)

Jane

2010-12-13

Dec 13, 2010 ... inexpensive and the results obtained were clean and reproducible. However, it is suitable for the high throughput screening of amino acid-producing strains. Key words: Thin layer chromatography, pre-staining, amino acid detection. INTRODUCTION. Several analytical techniques have been often used for.

Oxidation of clofibric acid in aqueous solution using a non-thermal plasma discharge or gamma radiation

Science.gov (United States)

Madureira, Joana; Ceriani, Elisa; Pinhão, Nuno; Marotta, Ester; Melo, Rita; Cabo Verde, Sandra; Paradisi, Cristina; Margaça, Fernanda M. A.

2017-11-01

In this work, we study degradation of clofibric acid (CFA) in aqueous solution using either ionizing radiation from a $^{60}$Co source or a non-thermal plasma produced by discharges in the air above the solution. The results obtained with the two technologies are compared in terms of effectiveness of CFA degradation and its by-products. In both cases the CFA degradation follows a quasi-exponential decay in time well modelled by a kinetic scheme which considers the competition between CFA and all reaction intermediates for the reactive species generated in solution as well as the amount of the end product formed. A new degradation law is deduced to explain the results. Although the end-product CO$_2$ was detected and the CFA conversion found to be very high under the studied conditions, HPLC analysis reveals several degradation intermediates still bearing the aromatic ring with the chlorine substituent. The extent of mineralization is rather limited. The energy yield is found to be higher in the gamma radiation experiments.

Uniquely Strongly Clean Group Rings

Institute of Scientific and Technical Information of China (English)

WANG XIU-LAN

2012-01-01

A ring R is called clean if every element is the sum of an idempotent and a unit,and R is called uniquely strongly clean (USC for short) if every element is uniquely the sum of an idempotent and a unit that commute.In this article,some conditions on a ring R and a group G such that RG is clean are given.It is also shown that if G is a locally finite group,then the group ring RG is USC if and only if R is USC,and G is a 2-group.The left uniquely exchange group ring,as a middle ring of the uniquely clean ring and the USC ring,does not possess this property,and so does the uniquely exchange group ring.

Rudimentary Cleaning Compared to Level 300A

Science.gov (United States)

Arpin, Christina Y. Pina; Stoltzfus, Joel

2012-01-01

A study was done to characterize the cleanliness level achievable when using a rudimentary cleaning process, and results were compared to JPR 5322.1G Level 300A. While it is not ideal to clean in a shop environment, some situations (e.g., field combat operations) require oxygen system hardware to be maintained and cleaned to prevent a fire hazard, even though it cannot be sent back to a precision cleaning facility. This study measured the effectiveness of basic shop cleaning. Initially, three items representing parts of an oxygen system were contaminated: a metal plate, valve body, and metal oxygen bottle. The contaminants chosen were those most likely to be introduced to the system during normal use: oil, lubricant, metal shavings/powder, sand, fingerprints, tape, lip balm, and hand lotion. The cleaning process used hot water, soap, various brushes, gaseous nitrogen, water nozzle, plastic trays, scouring pads, and a controlled shop environment. Test subjects were classified into three groups: technical professionals having an appreciation for oxygen hazards; professional precision cleaners; and a group with no previous professional knowledge of oxygen or precision cleaning. Three test subjects were in each group, and each was provided with standard cleaning equipment, a cleaning procedure, and one of each of the three test items to clean. The results indicated that the achievable cleanliness level was independent of the technical knowledge or proficiency of the personnel cleaning the items. Results also showed that achieving a Level 300 particle count was more difficult than achieving a Level A nonvolatile residue amount.

Cleaning metal filters by pulse-jet

International Nuclear Information System (INIS)

Pickard, P.; Perry, R.A.

1986-01-01

Cleanable metal filters have an established use in the Nuclear Industry. The filters that have been installed in the past have not proved to be sufficiently cleanable. A series of tests were undertaken to study the application of pulse-jet cleaning to metal fibre filter elements. The efficiency of dust removal was examined under various operating conditions. A very high degree of particulate removal was achieved, with a return to almost clean pressure drop. The effectiveness of cleaning was found to vary inversely with blowback pressure. The position of the blowback nozzle with respect to the filter element throat was also found to be important to cleaning efficiency. Under the test conditions the effect of re-entrainment when cleaning on line was found to be minimal. (author)

Washing away your sins in the brain: physical cleaning and priming of cleaning recruit different brain networks after moral threat.

Science.gov (United States)

Tang, Honghong; Lu, Xiaping; Su, Rui; Liang, Zilu; Mai, Xiaoqin; Liu, Chao

2017-07-01

The association between moral purity and physical cleanliness has been widely discussed recently. Studies found that moral threat initiates the need of physical cleanliness, but actual physical cleaning and priming of cleaning have inconsistent effects on subsequent attitudes and behaviors. Here, we used resting-state functional magnetic resonance imaging to explore the underlying neural mechanism of actual physical cleaning and priming of cleaning. After recalling moral transgression with strong feelings of guilt and shame, participants either actually cleaned their faces with a wipe or were primed with cleanliness through viewing its pictures. Results showed that actual physical cleaning reduced the spontaneous brain activities in the right insula and MPFC, regions that involved in embodied moral emotion processing, while priming of cleaning decreased activities in the right superior frontal gyrus and middle frontal gyrus, regions that participated in executive control processing. Additionally, actual physical cleaning also changed functional connectivity between insula/MPFC and emotion related regions, whereas priming of cleaning modified connectivity within both moral and sensorimotor areas. These findings revealed that actual physical cleaning and priming of cleaning led to changes in different brain regions and networks, providing neural evidence for the inconsistent effects of cleanliness on subsequent attitudes and behaviors. © The Author (2017). Published by Oxford University Press.

Slurry discharge management-beach profile prediction

Energy Technology Data Exchange (ETDEWEB)

Bravo, R.; Nawrot, J.R. [Southern Illinois University at Carbondale, Carbondale, IL (United States). Dept. of Civil Engineering

1996-11-01

Mine tailings dams are embankments used by the mining industry to retain the tailings products after the mineral preparation process. Based on the acid-waste stereotype that all coal slurry is acid producing, current reclamation requires a four foot soil cover for inactive slurry disposal areas. Compliance with this requirement is both difficult and costly and in some case unnecessary, as not all the slurry, or portions of slurry impoundments are acid producing. Reduced costs and recent popularity of wetland development has prompted many operators to request reclamation variances for slurry impoundments. Waiting to address slurry reclamation until after the impoundment is full, limits the flexibility of reclamation opportunities. This paper outlines a general methodology to predict the formation of the beach profile for mine tailings dams, by the discharge volume and location of the slurry into the impoundment. The review is presented under the perspective of geotechnical engineering and waste disposal management emphasizing the importance of pre-planning slurry disposal land reclamation. 4 refs., 5 figs.

Advances in telescope mirror cleaning

Science.gov (United States)

Blanken, Maarten F.; Chopping, Alan K.; Dee, Kevin M.

2004-09-01

Metrology and cleaning techniques for telescope mirrors are generally well established. CO2 cleaning and water washing are mainly used. Water washing has proven to be the best method of removing oil and water stains and restoring the aluminium to nearly fresh values. The risk of water getting to unwanted places such as electronics or other optics prevents this method from being employed more often. Recently the Isaac Newton Group introduced a new cleaning technique for their telescope mirrors, which reduces the risks discussed above. This technique uses water vapour instead of water to wash the mirror. The advantage of this method is that the amount of water needed is drastically reduced. In addition the pressure of the vapour will blow away any large dust particles on the mirror and the temperature shock between the vapour and the mirror will help to de-bond the dust particles. Adding a soapy solution will help to clean oil and watermarks of the mirror. This paper describes the vapour cleaning method, tests that have been done and the overall findings.

ENHANCED CHEMICAL CLEANING: EFFECTIVENESS OF THE UV LAMP TO DECOMPOSE OXALATES

Energy Technology Data Exchange (ETDEWEB)

Ketusky, E.; Huff, T.; Sudduth, C.

2010-01-19

Enhanced Chemical Cleaning is a new process scheduled to begin cleaning Savannah River Site High Level Waste Tanks in 2012. It is an improvement over the current chemical cleaning method, in that it minimizes downstream impacts on the High Level Waste System. It is based on a state of the art scale removal process used on the secondary side of nuclear power plants, with modifications to accommodate the unique constraints created by the tanks. Both Enhanced Chemical Cleaning and the scale removal process are founded on dissolving metal oxides/hydroxides using oxalic acid, with subsequent oxalate decomposition via hydroxylation using ozone or peroxide, and UV light as a catalyst. A divergence Enhanced Chemical Cleaning has from nuclear power scale removal is the significantly increased solids concentration during oxalate decomposition. These solids can limit the ability of the UV light to create hydroxyl radicals, either by limiting the ability of the light to penetrate through the solution, or by increasing the fouling rate on the UV light. Both will decrease the overall catalytic effectiveness, thereby decreasing the concentration of formed hydroxyl radicals. The hydroxyl radicals are the driving force behind the oxalate decomposition. To understand the impact of increased solids, testing was performed using a medium pressure UV light inside an ozone supplied Oxalate Decomposition Reactor. Using a dissolved metal sludge simulant with an initial oxalate concentration greater than 12,000 ppm, and an initial pH of about 2.0, the spent acid solution was recirculated through the reactor, while the UV light was allowed to foul. For the first few hours, the oxalate decomposition rate was about 1,300 ppm/hour. After about 3 hours, enough time for the UV lamp to foul, the oxalate decomposition rate decreased to about 500 ppm/hour. The decomposition rate then remained roughly constant for the next 16 hours. Overall, testing showed that the oxalate destruction rate decreased

Coolant clean-up system in nuclear reactor

International Nuclear Information System (INIS)

Tsuburaya, Hirobumi; Akita, Minoru; Shiraishi, Tadashi; Kinoshita, Shoichiro; Okura, Minoru; Tsuji, Akio.

1987-01-01

Purpose: To ensure a sufficient urging pressure at the inlet of a coolant clean-up system pump in a nuclear reactor and eliminate radioactive contaminations to the pump. Constitution: Coolant clean-up system (CUW) pump in a nuclear reactor is disposed to the downstream of a filtration desalter and, for compensating the insufficiency of the urging pressure at the pump inlet, the reactor water intake port to the clean-up system is disposed to the downstream of the after-heat removing pump and the heat exchanger. By compensating the net positive suction head (NPSH) of the clean-up system from the residual heat removing system, the problems of insufficient NPSH for the CUW pump upon reactor shut-down can be dissolved and, accordingly, the reactor clean-up system can be arranged in the order of the heat exchanger, clean-up device and pump. Thus, the CUW pump acts on reactor water after cleaned-up in the clean-up device to reduce the radioactivity contamination to the pump. (Kawakami, Y.)

Amino acid and fatty acid compositions of Rusip from fermented Anchovy fish (Stolephorussp)

Science.gov (United States)

Koesoemawardani, D.; Hidayati, S.; Subeki

2018-04-01

Rusip is a typical food of Bangka Belitung Indonesia made from fermented anchovy. This study aims to determine the properties of chemistry, microbiology, composition of amino acids and fatty acids from fermented fish spontaneously and non spontaneously. Spontaneous rusip treatment is done by anchovy fish (Stolephorussp) after cleaning and added salt 25% (w/w) and palm sugar 10% (w/w). While, non-spontaneous rusip is done by adding a culture mixture of Streptococcus, Leuconostoc, and Lactobacillus bacteria 2% (w/v). The materials are then incubated for 2 weeks. The data obtained were then performed t-test at the level of 5%. Spontaneous and non-spontaneous rusip fermentation process showed significant differences in total acid, reducing sugar, salt content, TVN, total lactic acid bacteria, total mold, and total microbial. The dominant amino acid content of spontaneous and non-spontaneous rusip are glutamic acid and aspartic acid, while the dominant fatty acids in spontaneous and non-spontaneous rusip are docosahexaenoic acid, palmitic acid, oleic acid, arachidonic acid, stearic acid, eicosapentaenoic acid, palmitoleic acid, and myristic acid.

49 CFR 174.615 - Cleaning cars.

Science.gov (United States)

2010-10-01

... 49 Transportation 2 2010-10-01 2010-10-01 false Cleaning cars. 174.615 Section 174.615... Requirements for Division 6.1 (Poisonous) Materials § 174.615 Cleaning cars. (a) [Reserved] (b) After Division 6.1 (poisonous) materials are unloaded from a rail car, that car must be thoroughly cleaned unless...

Cleaning verification: A five parameter study of a Total Organic Carbon method development and validation for the cleaning assessment of residual detergents in manufacturing equipment.

Science.gov (United States)

Li, Xue; Ahmad, Imad A Haidar; Tam, James; Wang, Yan; Dao, Gina; Blasko, Andrei

2018-02-05

A Total Organic Carbon (TOC) based analytical method to quantitate trace residues of clean-in-place (CIP) detergents CIP100 ® and CIP200 ® on the surfaces of pharmaceutical manufacturing equipment was developed and validated. Five factors affecting the development and validation of the method were identified: diluent composition, diluent volume, extraction method, location for TOC sample preparation, and oxidant flow rate. Key experimental parameters were optimized to minimize contamination and to improve the sensitivity, recovery, and reliability of the method. The optimized concentration of the phosphoric acid in the swabbing solution was 0.05M, and the optimal volume of the sample solution was 30mL. The swab extraction method was 1min sonication. The use of a clean room, as compared to an isolated lab environment, was not required for method validation. The method was demonstrated to be linear with a correlation coefficient (R) of 0.9999. The average recoveries from stainless steel surfaces at multiple spike levels were >90%. The repeatability and intermediate precision results were ≤5% across the 2.2-6.6ppm range (50-150% of the target maximum carry over, MACO, limit). The method was also shown to be sensitive with a detection limit (DL) of 38ppb and a quantitation limit (QL) of 114ppb. The method validation demonstrated that the developed method is suitable for its intended use. The methodology developed in this study is generally applicable to the cleaning verification of any organic detergents used for the cleaning of pharmaceutical manufacturing equipment made of electropolished stainless steel material. Copyright © 2017 Elsevier B.V. All rights reserved.

Effectuality of Cleaning Workers' Training and Cleaning Enterprises' Chemical Health Hazard Risk Profiling.

Science.gov (United States)

Suleiman, Abdulqadir M; Svendsen, Kristin V H

2015-12-01

Goal-oriented communication of risk of hazards is necessary in order to reduce risk of workers' exposure to chemicals. Adequate training of workers and enterprise priority setting are essential elements. Cleaning enterprises have many challenges and the existing paradigms influence the risk levels of these enterprises. Information on organization and enterprises' prioritization in training programs was gathered from cleaning enterprises. A measure of enterprises' conceptual level of importance of chemical health hazards and a model for working out the risk index (RI) indicating enterprises' conceptual risk level was established and used to categorize the enterprises. In 72.3% of cases, training takes place concurrently with task performances and in 67.4% experienced workers conduct the trainings. There is disparity between employers' opinion on competence level of the workers and reality. Lower conceptual level of importance was observed for cleaning enterprises of different sizes compared with regional safety delegates and occupational hygienists. Risk index values show no difference in risk level between small and large enterprises. Training of cleaning workers lacks the prerequisite for suitability and effectiveness to counter risks of chemical health hazards. There is dereliction of duty by management in the sector resulting in a lack of competence among the cleaning workers. Instituting acceptable easily attainable safety competence level for cleaners will conduce to risk reduction, and enforcement of attainment of the competence level would be a positive step.

Removal of model proteins by means of low-pressure inductively coupled plasma discharge

International Nuclear Information System (INIS)

Kylian, O; Rauscher, H; Gilliland, D; Bretagnol, F; Rossi, F

2008-01-01

Surgical instruments are intended to come into direct contact with the patients' tissues and thus interact with their first immune defence system. Therefore they have to be cleaned, sterilized and decontaminated, in order to prevent any kind of infections and inflammations or to exclude the possibility of transmission of diseases. From this perspective, the removal of protein residues from their surfaces constitutes new challenges, since certain proteins exhibit high resistance to commonly used sterilization and decontamination techniques and hence are difficult to remove without inducing major damages to the object treated. Therefore new approaches must be developed for that purpose and the application of non-equilibrium plasma discharges represents an interesting option. The possibility to effectively remove model proteins (bovine serum albumin, lysozyme and ubiquitin) from surfaces of different materials (Si wafer, glass, polystyrene and gold) by means of inductively coupled plasma discharges sustained in different argon containing mixtures is demonstrated and discussed in this paper

Removal of model proteins by means of low-pressure inductively coupled plasma discharge

Energy Technology Data Exchange (ETDEWEB)

Kylian, O; Rauscher, H; Gilliland, D; Bretagnol, F; Rossi, F [European Commission, Joint Research Centre, Institute for Health and Consumer Protection, Via E Fermi 2749, 21027 Ispra (Italy)], E-mail: francois.rossi@jrc.it

2008-05-07

Surgical instruments are intended to come into direct contact with the patients' tissues and thus interact with their first immune defence system. Therefore they have to be cleaned, sterilized and decontaminated, in order to prevent any kind of infections and inflammations or to exclude the possibility of transmission of diseases. From this perspective, the removal of protein residues from their surfaces constitutes new challenges, since certain proteins exhibit high resistance to commonly used sterilization and decontamination techniques and hence are difficult to remove without inducing major damages to the object treated. Therefore new approaches must be developed for that purpose and the application of non-equilibrium plasma discharges represents an interesting option. The possibility to effectively remove model proteins (bovine serum albumin, lysozyme and ubiquitin) from surfaces of different materials (Si wafer, glass, polystyrene and gold) by means of inductively coupled plasma discharges sustained in different argon containing mixtures is demonstrated and discussed in this paper.

Acrylic vessel cleaning tests

International Nuclear Information System (INIS)

Earle, D.; Hahn, R.L.; Boger, J.; Bonvin, E.

1997-01-01

The acrylic vessel as constructed is dirty. The dirt includes blue tape, Al tape, grease pencil, gemak, the glue or residue form these tapes, finger prints and dust of an unknown composition but probably mostly acrylic dust. This dirt has to be removed and once removed, the vessel has to be kept clean or at least to be easily cleanable at some future stage when access becomes much more difficult. The authors report on the results of a series of tests designed: (a) to prepare typical dirty samples of acrylic; (b) to remove dirt stuck to the acrylic surface; and (c) to measure the optical quality and Th concentration after cleaning. Specifications of the vessel call for very low levels of Th which could come from tape residues, the grease pencil, or other sources of dirt. This report does not address the concerns of how to keep the vessel clean after an initial cleaning and during the removal of the scaffolding. Alconox is recommended as the cleaner of choice. This acrylic vessel will be used in the Sudbury Neutrino Observatory

Clean-room robot implementation

International Nuclear Information System (INIS)

Comeau, J.L.

1982-01-01

A robot has been incorporated in a clean room operation in which vacuum tube parts are cleaned just prior to final assembly with a 60 lb/in 2 blast of argon gas. The robot is programmed to pick up the parts, manipulate/rotate them as necessary in the jet pattern and deposit them in a tray precleaned by the robot. A carefully studied implementation plan was followed in the procurement, installation, modification and programming of the robot facility. An unusual configuration of one tube part required a unique gripper design. A study indicated that the tube parts processed by the robot are 12% cleaner than those manually cleaned by an experienced operator

Outsourcing Housekeeping: An insight into two cleaning companies, SOL and N-Clean, in Helsinki, Finland

OpenAIRE

Hussain, Samra

2016-01-01

The purpose of the author was to find to get an insight into the cleaning companies, in Helsin-ki, Finland, which the hotel industry is using as an external supplier for their housekeeping de-partment. The author has looked into the cleaning companies training process for the cleaning staff, employee demographics, quality control and process of handling complaints. The ad-vantages and disadvantages of outsourcing housekeeping in the hotel sector are also investi-gated. The research method...

Ultrasonic aqueous cleaning as a replacement for chlorinated solvent cleaning

International Nuclear Information System (INIS)

Thompson, L.M.; Simandl, R.F.

1992-01-01

The Oak Ridge Y-12 Plant has been involved in the replacement of chlorinated solvents since 1982. One of the most successful replacement efforts has been the substitution of vapor degreasers or soak tanks using chlorinated solvents with ultrasonic cleaning using aqueous detergents. Recently, funding was obtained from the Department of Energy Office (DOE) of Technology Development to demonstrate this technology. A unit has been procured and installed in the vacuum pump shop area to replace the use of a solvent soak tank. Initially, the solvents used in the shop were CFC-113 and a commercial brand cleaner which contained both perchloroethylene and methylene chloride. While the ultrasonic unit was being procured, a terpene-based solvent was used. Generally, parts were soaked overnight in order to soften baked-on vanish. Many times, wire brushing was used to help remove remaining contamination. Initial testing with the ultrasonic cleaner indicated cleaning times of 20 min were as effective as the overnight solvent soaks in removing contamination. Wire brushing was also not required following the ultrasonic cleaning as was sometimes required with the solvent soak

Studies on nitric oxide removal in simulated gas compositions under plasma-dielectric/catalytic discharges

International Nuclear Information System (INIS)

Rajanikanth, B.S.; Rout, Satyabrata

2001-01-01

Application of pulsed electrical discharges for gas cleaning is gaining prominence, mainly from the energy consideration point of view. This present paper presents recent work on applying the electrical discharge plasma technology for treating gaseous pollutants, in general, and nitric oxide, in particular, as this is one of the major contributors to air pollution. The present work focuses attention on pulsed electrical discharge technique for nitric oxide removal from simulated gas compositions and study of effect of packed dielectric pellets, with and without a coating of catalyst, on the removal process. Experiments were conducted in a cylindrical corona reactor energized by repetitive high voltage pulses. The effects of various parameters, viz. pulse voltage magnitude, pulse frequency, initial nitric oxide concentration and gas mixture composition on nitric oxide removal efficiency, are discussed. When the reactors were filled with different dielectric pellets like, barium titanate, alumina, and alumina coated with palladium catalyst, the improvement in nitric oxide removal efficiency is studied and discussed. The power dissipated in the reactor and the energy consumed per nitric oxide molecule removed was calculated. Further results and comparative study of various cases are presented in the paper

Clean Energy Solutions Center Services

Energy Technology Data Exchange (ETDEWEB)

2016-03-01

The Solutions Center offers no-cost expert policy assistance, webinars and training forums, clean energy policy reports, data, and tools provided in partnership with more than 35 leading international and regional clean energy organizations.

Emulsion type dry cleaning system

International Nuclear Information System (INIS)

Kohanawa, Osamu; Matsumoto, Hiroyo.

1988-01-01

Protective clothing against radioactive contamination used in the radiation controlled areas of nuclear plants has been washed by the same wet washing as used for underwear washing, but recently dry cleaning is getting used in place of wet washing, which generates a large quantity of laundry drain. However, it was required to use wet washing once every five to ten dry cleanings for washing protective clothing, because conventional dry cleaning is less effective in removing water-soluble soils. Therefore, in order to eliminate wet washing, and to decrease the quantity of laundry drains, the emulsion type dry cleaning system capable of removing both oil-soluble and water-soluble soils at a time has been developed. The results of developmental experiments and actual application are presented in this paper. (author)

Permeability recovery of fouled forward osmosis membranes by chemical cleaning during a long-term operation of anaerobic osmotic membrane bioreactors treating low-strength wastewater.

Science.gov (United States)

Wang, Xinhua; Hu, Taozhan; Wang, Zhiwei; Li, Xiufen; Ren, Yueping

2017-10-15

Anaerobic osmotic membrane bioreactor (AnOMBR) has gained increasing interests in wastewater treatment owing to its simultaneous recovery of biogas and water. However, the forward osmosis (FO) membrane fouling was severe during a long-term operation of AnOMBRs. Here, we aim to recover the permeability of fouled FO membranes by chemical cleaning. Specifically speaking, an optimal chemical cleaning procedure was searched for fouled thin film composite polyamide FO (TFC-FO) membranes in a novel microfiltration (MF) assisted AnOMBR (AnMF-OMBR). The results indicated that citric acid, disodium ethylenediaminetetraacetate (EDTA-2Na), hydrochloric acid (HCl), sodium dodecyl sulfate (SDS) and sodium hydroxide (NaOH) had a low cleaning efficiency of less than 15%, while hydrogen peroxide (H 2 O 2 ) could effectively remove foulants from the TFC-FO membrane surface (almost 100%) through oxidizing the functional group of the organic foulants and disintegrating the colloids and microbe flocs into fine particles. Nevertheless, the damage of H 2 O 2 to the TFC-FO membrane was observed when a high cleaning concentration and a long duration were applied. In this case, the optimal cleaning conditions including cleaning concentration and time for fouled TFC-FO membranes were selected through confocal laser scanning microscope (CLSM) and scanning electron microscopy (SEM) images and the flux recovery rate. The results suggested that the optimal cleaning procedure for fouled TFC-FO membranes was use of 0.5% H 2 O 2 at 25 °C for 6 h, and after that, the cleaned TFC-FO membrane had the same performance as a virgin one including water flux and rejection for organic matters and phosphorus during the operation of AnMF-OMBR. Copyright © 2017 Elsevier Ltd. All rights reserved.

Coal surface control for advanced physical fine coal cleaning technologies

Energy Technology Data Exchange (ETDEWEB)

Morsi, B.I.; Chiang, S.H.; Sharkey, A.; Blachere, J.; Klinzing, G.; Araujo, G.; Cheng, Y.S.; Gray, R.; Streeter, R.; Bi, H.; Campbell, P.; Chiarlli, P.; Ciocco, M.; Hittle, L.; Kim, S.; Kim, Y.; Perez, L.; Venkatadri, R.

1992-01-01

This final report presents the research work carried out on the Coal Surface Control for Advanced Physical Fine Coal Cleaning Technologies project, sponsored by the US Department of Energy, Pittsburgh Energy Technology Center (DOE/PETC). The project was to support the engineering development of the selective agglomeration technology in order to reduce the sulfur content of US coals for controlling SO[sub 2] emissions (i.e., acid rain precursors). The overall effort was a part of the DOE/PETCs Acid Rain Control Initiative (ARCI). The overall objective of the project is to develop techniques for coal surface control prior to the advanced physical fine coal cleaning process of selective agglomeration in order to achieve 85% pyrite sulfur rejection at an energy recovery greater than 85% based on run-of-mine coal. The surface control is meant to encompass surface modification during grinding and laboratory beneficiation testing. The project includes the following tasks: Project planning; methods for analysis of samples; development of standard beneficiation test; grinding studies; modification of particle surface; and exploratory R D and support. The coal samples used in this project include three base coals, Upper Freeport - Indiana County, PA, Pittsburgh NO. 8 - Belmont County, OH, and Illinois No. 6 - Randolph County, IL, and three additional coals, Upper Freeport - Grant County- WV, Kentucky No. 9 Hopkins County, KY, and Wyodak - Campbell County, WY. A total of 149 drums of coal were received.

Synthesis and characteristics of Ag/Pt bimetallic nanocomposites by arc-discharge solution plasma processing.

Science.gov (United States)

Pootawang, Panuphong; Saito, Nagahiro; Takai, Osamu; Lee, Sang-Yul

2012-10-05

Arc discharge in solution, generated by applying a high voltage of unipolar pulsed dc to electrodes of Ag and Pt, was used as a method to form Ag/Pt bimetallic nanocomposites via electrode erosion by the effects of the electric arc at the cathode (Ag rod) and the sputtering at the anode (Pt rod). Ag/Pt bimetallic nanocomposites were formed as colloidal particles dispersed in solution via the reduction of hydrogen radicals generated during discharge without the addition of chemical precursor or reducing agent. At a discharge time of 30 s, the fine bimetallic nanoparticles with a mean particle size of approximately 5 nm were observed by transmission electron microscopy (TEM). With increasing discharge time, the bimetallic nanoparticle size tended to increase by forming an agglomeration. The presence of the relatively small amount of Pt dispersed in the Ag matrix could be observed by the analytical mapping mode of energy-dispersive x-ray spectroscopy and high-resolution TEM. This demonstrated that the synthesized particle was in the form of a nanocomposite. No contamination of other chemical substances was detected by x-ray photoelectron spectroscopy. Hence, solution plasma could be a clean and simple process to effectively synthesize Ag/Pt bimetallic nanocomposites and it is expected to be widely applicable in the preparation of several types of nanoparticle.

Simulation of the influence of flue gas cleaning system on the energetic efficiency of a waste-to-energy plant

Energy Technology Data Exchange (ETDEWEB)

Grieco, E.; Poggio, A. [Politecnico di Torino, Corso Duca degli Abruzzi 24, Torino 10121 (Italy)

2009-09-15

Municipal solid waste incinerators are designed to enhance the electrical efficiency obtained by the plant as much as possible. For this reason strong integration between the flue gas cleaning system and the heat recovery system is required. To provide higher electrical efficiencies acid gas neutralization process has the major importance in flue gas cleaning system. At least four technologies are usually applied for acid gas removal: dry neutralization with Ca(OH){sub 2} or with NaHCO{sub 3}, semi-dry neutralization with milk of lime and wet scrubbing. Nowadays, wet scrubbers are rarely used as a result of the large amount of liquid effluents produced; wet scrubbing technology is often applied as a final treatment after a dry neutralization. Operating conditions of the plant were simulated by using Aspen Plus in order to investigate the influences of four different technologies on the electrical efficiency of the plant. The results of the simulations did not show a great influence of the gas cleaning system on the net electrical efficiency, as the difference between the most advantageous technology (neutralization with NaHCO{sub 3}) and the worst one, is about 1%. (author)

Clean Energy Policy Analyses: Analysis of the Status and Impact of Clean Energy Policies at the Local Level

Energy Technology Data Exchange (ETDEWEB)

Busche, S.

2010-12-01

This report takes a broad look at the status of local clean energy policies in the United States to develop a better understanding of local clean energy policy development and the interaction between state and local policies. To date, the majority of clean energy policy research focuses on the state and federal levels. While there has been a substantial amount of research on local level climate change initiatives, this is one of the first analyses of clean energy policies separate from climate change initiatives. This report is one in a suite of reports analyzing clean energy and climate policy development at the local, state, and regional levels.

Clean Energy Policy Analyses. Analysis of the Status and Impact of Clean Energy Policies at the Local Level

Energy Technology Data Exchange (ETDEWEB)

Busche, S. [National Renewable Energy Lab. (NREL), Golden, CO (United States)

2010-12-01

This report takes a broad look at the status of local clean energy policies in the United States to develop a better understanding of local clean energy policy development and the interaction between state and local policies. To date, the majority of clean energy policy research focuses on the state and federal levels. While there has been a substantial amount of research on local level climate change initiatives, this is one of the first analyses of clean energy policies separate from climate change initiatives. This report is one in a suite of reports analyzing clean energy and climate policy development at the local, state, and regional levels.

Overview of material migration and mixing, fuel retention and cleaning of ITER-like castellated structures in TEXTOR

International Nuclear Information System (INIS)

Litnovsky, A.; Philipps, V.; Wienhold, P.; Kreter, A.; Kirschner, A.; Matveev, D.; Brezinsek, S.; Sergienko, G.; Pospieszczyk, A.; Schweer, B.; Schulz, C.; Schmitz, O.; Coenen, J.W.; Samm, U.; Krieger, K.; Hirai, T.; Emmoth, B.; Rubel, M.; Bazylev, B.; Breuer, U.

2011-01-01

Plasma-facing components (PFCs) in ITER will be castellated by splitting them into small-size blocks to maintain the thermo-mechanical stability. However, there are concerns in particular on retention of codeposited radioactive fuel in the gaps. An R and D program is underway in TEXTOR addressing this acute issue of castellation. Material migration and fuel inventory are investigated using long- and short-term discharge-resolved experiments with castellated structures in TEXTOR. Significant impurity transport to the gaps was detected and results were in part quantitatively reproduced with 3D-GAPS code. Deposits containing up to 70 at.% of tungsten on the gap areas closest to the plasma were detected in recent experiments. Deposition in the gaps accompanied by metal mixing demand for development of effective cleaning techniques. In experiments with ITER-like castellation, the gaps were cleaned from carbonaceous deposits using oxygen plasmas at 350 deg. C. This contribution contains an overview of experimental and modeling results along with recommendations for PFCs in ITER.

Conceptual Model of Uranium in the Vadose Zone for Acidic and Alkaline Wastes Discharged at the Hanford Site Central Plateau

Energy Technology Data Exchange (ETDEWEB)

Truex, Michael J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Szecsody, James E. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Qafoku, Nikolla [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Serne, R. Jeffrey [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

2014-09-01

Historically, uranium was disposed in waste solutions of varying waste chemistry at the Hanford Site Central Plateau. The character of how uranium was distributed in the vadose zone during disposal, how it has continued to migrate through the vadose zone, and the magnitude of potential impacts on groundwater are strongly influenced by geochemical reactions in the vadose zone. These geochemical reactions can be significantly influenced by the disposed-waste chemistry near the disposal location. This report provides conceptual models and supporting information to describe uranium fate and transport in the vadose zone for both acidic and alkaline wastes discharged at a substantial number of waste sites in the Hanford Site Central Plateau. The conceptual models include consideration of how co-disposed acidic or alkaline fluids influence uranium mobility in terms of induced dissolution/precipitation reactions and changes in uranium sorption with a focus on the conditions near the disposal site. This information, when combined with the extensive information describing uranium fate and transport at near background pH conditions, enables focused characterization to support effective fate and transport estimates for uranium in the subsurface.

Design and operation of off-gas cleaning systems at high level liquid waste conditioning facilities

International Nuclear Information System (INIS)

1988-01-01

The immobilization of high level liquid wastes from the reprocessing of irradiated nuclear fuels is of great interest and serious efforts are being undertaken to find a satisfactory technical solution. Volatilization of fission product elements during immobilization poses the potential for the release of radioactive substances to the environment and necessitates effective off-gas cleaning systems. This report describes typical off-gas cleaning systems used in the most advanced high level liquid waste immobilization plants and considers most of the equipment and components which can be used for the efficient retention of the aerosols and volatile contaminants. In the case of a nuclear facility consisting of several different facilities, release limits are generally prescribed for the nuclear facility as a whole. Since high level liquid waste conditioning (calcination, vitrification, etc.) facilities are usually located at fuel reprocessing sites (where the majority of the high level liquid wastes originates), the off-gas cleaning system should be designed so that the airborne radioactivity discharge of the whole site, including the emission of the waste conditioning facility, can be kept below the permitted limits. This report deals with the sources and composition of different kinds of high level liquid wastes and describes briefly the main high level liquid waste solidification processes examining the sources and characteristics of the off-gas contaminants to be retained by the off-gas cleaning system. The equipment and components of typical off-gas systems used in the most advanced (large pilot or industrial scale) high level liquid waste solidification plants are described. Safety considerations for the design and safe operation of the off-gas systems are discussed. 60 refs, 31 figs, 17 tabs

Improved performance of parallel surface/packed-bed discharge reactor for indoor VOCs decomposition: optimization of the reactor structure

International Nuclear Information System (INIS)

Jiang, Nan; Hui, Chun-Xue; Li, Jie; Lu, Na; Shang, Ke-Feng; Wu, Yan; Mizuno, Akira

2015-01-01

The purpose of this paper is to develop a high-efficiency air-cleaning system for volatile organic compounds (VOCs) existing in the workshop of a chemical factory. A novel parallel surface/packed-bed discharge (PSPBD) reactor, which utilized a combination of surface discharge (SD) plasma with packed-bed discharge (PBD) plasma, was designed and employed for VOCs removal in a closed vessel. In order to optimize the structure of the PSPBD reactor, the discharge characteristic, benzene removal efficiency, and energy yield were compared for different discharge lengths, quartz tube diameters, shapes of external high-voltage electrode, packed-bed discharge gaps, and packing pellet sizes, respectively. In the circulation test, 52.8% of benzene was removed and the energy yield achieved 0.79 mg kJ −1 after a 210 min discharge treatment in the PSPBD reactor, which was 10.3% and 0.18 mg kJ −1 higher, respectively, than in the SD reactor, 21.8% and 0.34 mg kJ −1 higher, respectively, than in the PBD reactor at 53 J l −1 . The improved performance in benzene removal and energy yield can be attributed to the plasma chemistry effect of the sequential processing in the PSPBD reactor. The VOCs mineralization and organic intermediates generated during discharge treatment were followed by CO x selectivity and FT-IR analyses. The experimental results indicate that the PSPBD plasma process is an effective and energy-efficient approach for VOCs removal in an indoor environment. (paper)

Discharge time dependence of a solution plasma process for colloidal copper nanoparticle synthesis and particle characteristics

International Nuclear Information System (INIS)

Pootawang, Panuphong; Saito, Nagahiro; Lee, Sang Yul

2013-01-01

In this study, we investigate a new synthetic route, termed the solution plasma process, for the synthesis of colloidal copper nanoparticles (CuNPs) in the presence of an amide and acid capping agent. Gelatin and ascorbic acid were selected as the capping agents to protect the particles against coalescence and oxidation side reaction. Using a high voltage power supply, CuNPs were rapidly formed by 1 min after the discharge. The size and shape of the CuNPs were dependent on the discharge time and were clearly influenced by the effect of the capping agents under two characteristics of the discharge medium (pH and temperature). With a long discharge time, the CuNP size tended to decrease with the formation of anisotropic particle morphologies: spherical, cubic, hexagonal, triangular and rod-like shapes. The decrease in CuNP size as a function of discharge time could be explained by the dissolution of CuNPs in a lower pH solution. After 5 min discharge the capping agent evidently allowed the protection of the synthesized CuNPs against oxidation with the presence of anisotropic CuNP shapes. It is demonstrated that the CuNP shape could be tuned from spherical to anisotropic shapes without the undesirable oxidation by adjusting the discharge time of the solution plasma. These advantages are valuable for material engineering to design the properties of Cu-based nanoparticles for the desired applications. (paper)

Apparatuses, Systems and Methods for Cleaning Photovoltaic Devices

KAUST Repository

Eitelhuber, Georg

2013-01-01

Embodiments of solar panel cleaning apparatuses, solar panel cleaning systems, and solar panel cleaning methods are disclosed. In certain embodiments, the disclosed solar panel cleaning apparatuses, systems and methods do may not require any water

Nipple Discharge

Science.gov (United States)

... any unexpected nipple discharge evaluated by a doctor. Nipple discharge in men under any circumstances could be a problem and needs further evaluation. One or both breasts may produce a nipple discharge, either spontaneously or when you squeeze your ...

Webinar: Green Cleaning for Improved Health: The Return on Investment of Green Cleaning in Schools

Science.gov (United States)

A page to register to view the June 22, 2017, webinar in the IAQ Knowledge-to-Action Professional Training Webinar Series: Green Cleaning for Improved Health: The Return on Investment of Green Cleaning in Schools

Lung surgery - discharge

Science.gov (United States)

... Lung biopsy - discharge; Thoracoscopy - discharge; Video-assisted thoracoscopic surgery - discharge; VATS - discharge ... milk) for 2 weeks after video-assisted thoracoscopic surgery and 6 to 8 weeks after open surgery. ...

Integrated preservation and sample clean up procedures for studying water ingestion by recreational swimmers via urinary biomarker determination.

Science.gov (United States)

Cantú, Ricardo; Shoemaker, Jody A; Kelty, Catherine A; Wymer, Larry J; Behymer, Thomas D; Dufour, Alfred P; Magnuson, Matthew L

2017-08-22

The use of cyanuric acid as a biomarker for ingestion of swimming pool water may lead to quantitative knowledge of the volume of water ingested during swimming, contributing to a better understanding of disease resulting from ingestion of environmental contaminants. When swimming pool water containing chlorinated cyanurates is inadvertently ingested, cyanuric acid is excreted quantitatively within 24 h as a urinary biomarker of ingestion. Because the volume of water ingested can be quantitatively estimated by calculation from the concentration of cyanuric acid in 24 h urine samples, a procedure for preservation, cleanup, and analysis of cyanuric acid was developed to meet the logistical demands of large scale studies. From a practical stand point, urine collected from swimmers cannot be analyzed immediately, given requirements of sample collection, shipping, handling, etc. Thus, to maintain quality control to allow confidence in the results, it is necessary to preserve the samples in a manner that ensures as quantitative analysis as possible. The preservation and clean-up of cyanuric acid in urine is complicated because typical approaches often are incompatible with the keto-enol tautomerization of cyanuric acid, interfering with cyanuric acid sample preparation, chromatography, and detection. Therefore, this paper presents a novel integration of sample preservation, clean-up, chromatography, and detection to determine cyanuric acid in 24 h urine samples. Fortification of urine with cyanuric acid (0.3-3.0 mg/L) demonstrated accuracy (86-93% recovery) and high reproducibility (RSD urine suggested sufficient cyanuric acid stability for sample collection procedures, while longer holding times suggested instability of the unpreserved urine. Preserved urine exhibited a loss of around 0.5% after 22 days at refrigerated storage conditions of 4 °C. Published by Elsevier B.V.

Waste acid detoxification and reclamation

International Nuclear Information System (INIS)

Brouns, T.M.; Stewart, T.L.

1988-01-01

Economically feasible processes that reduce the volume, quantity, and toxicity of metal-bearing waste acids by reclaiming, reusing, and recycling spent acids and metal salts are being developed and demonstrated. The acids used in the demonstrations are generated during metal-finishing operations used in nuclear fuel fabrication; HF-HNO 3 , HNO 3 , and HNO 3 -H 2 SO 4 wastes result from Zr etching, Cu stripping, and chemical milling of U. At discharge, wastes contain high concentrations of acid and one major metal impurity. The waste minimization process used to reclaim acid from these three streams incorporates three processes for acid regeneration and reclamation. Normally, HNO 3 remains in the bottoms when an aqueous acid solution is distilled; however, in the presence of H 2 SO 4 , HNO 3 will distill to the overhead stream. In this process, nitrates and fluorides present as free acid and metal salts can be reclaimed as acid for recycle to the metal-finishing processes. Uranium present in the chemical milling solution can be economically recovered from distillation bottoms and refined. Using acid distillation, the volume of chemical milling solution discharged as waste can be reduced by as much as 60% depending on the H 2 SO 4 concentration. A payback period of 2.2 years has been estimated for this process. The development and demonstration of precipitation and distillation processes for detoxification and reclamation of waste acid is supported by the US Department of Energy's Hazardous Waste Remedial Actions Program (HAZWRAP)

Tracking Clean Energy Progress 2013

Energy Technology Data Exchange (ETDEWEB)

NONE

2013-06-01

Tracking Clean Energy Progress 2013 (TCEP 2013) examines progress in the development and deployment of key clean energy technologies. Each technology and sector is tracked against interim 2020 targets in the IEA Energy Technology Perspectives 2012 2°C scenario, which lays out pathways to a sustainable energy system in 2050. Stark message emerge: progress has not been fast enough; large market failures are preventing clean energy solutions from being taken up; considerable energy efficiency remains untapped; policies need to better address the energy system as a whole; and energy-related research, development and demonstration need to accelerate. Alongside these grim conclusions there is positive news. In 2012, hybrid-electric vehicle sales passed the 1 million mark. Solar photovoltaic systems were being installed at a record pace. The costs of most clean energy technologies fell more rapidly than anticipated.

Clean energy, non-clean energy, and economic growth in the MIST countries

International Nuclear Information System (INIS)

Pao, Hsiao-Tien; Li, Yi-Ying; Hsin-Chia Fu

2014-01-01

This paper explores the causal relationship between clean (renewable/nuclear) and non-clean energy consumption and economic growth in emerging economies of the MIST (Mexico, Indonesia, South Korea, and Turkey) countries. The panel co-integration tests reveal that there is a long-term equilibrium relationship among GDP, capital formation, labor force, renewable/nuclear, and fossil fuel energy consumption. The panel causality results indicate that (1) there is a positive unidirectional short-run causality from fossil fuel energy consumption to economic growth with a bidirectional long-run causality; (2) there is a unidirectional long-run causality from renewable energy consumption to economic growth with positive bidirectional short-run causality, and a long-run causality from renewable to fossil fuel energy consumption with negative short-run feedback effects; and (3) there is a bidirectional long-run causality between nuclear energy consumption and economic growth and a long-run causality from fossil fuel energy consumption to nuclear energy consumption with positive short-run feedback effects. These suggest that MIST countries should be energy-dependent economies and that energy conservation policies may depress their economic development. However, developing renewable and nuclear energy is a viable solution for addressing energy security and climate change issues, and creating clean and fossil fuel energy partnerships could enhance a sustainable energy economy. - Highlights: • This novel study can provide more robust bases to strengthen sustainable energy policy settings. • Fossil fuel/nuclear energy use and economic growth is bidirectional causality. • Renewable energy consumption long term causes economic growth. • There is substitutability between renewable and fossil fuel energy. • Clean and non-clean energy partnerships can achieve a sustainable energy economy

Problems of clean coals production as a sources of clean energy generation; Problemy produkcji czystych wegli jako zrodlo wytwarzania czystej energii

Energy Technology Data Exchange (ETDEWEB)

Blaschke, W. [Polish Academy of Sciences, Krakow (Poland). Mineral and Energy Economy Institute

2004-07-01

The paper advises of clean coal technology programme objectives. Issues connected with clean coals preparation for combustion have been discussed. The quality of steam fine coals has been presented, including those used in the commercial power industry. A small supply of 'clean coals' has been started in Poland, related however to a limited demand. Factors affecting the reduction in clean coal production have been discussed. The fact that there are no significant reasons to constrain supplies of clean coals has been emphasised. The quality of coal in deposits is very good, and the condition of preparation enables production of clean coal. Clean energy generation from clean coal requires only cooperation between the hard coal mining industry and the commercial power industry, passing over particular sectoral interests. 15 refs.

Apparatuses, Systems and Methods for Cleaning Photovoltaic Devices

KAUST Repository

Eitelhuber, Georg

2013-02-14

Embodiments of solar panel cleaning apparatuses, solar panel cleaning systems, and solar panel cleaning methods are disclosed. In certain embodiments, the disclosed solar panel cleaning apparatuses, systems and methods do may not require any water or other cleaning liquids in the whole cleaning process, which makes them prominent well suited in for water-deficit environments such as deserts. In one embodiment, the solar panel cleaning apparatus comprises one or more rotatable brushes each having a rotational axis and a drive configured to move each of the one or more rotatable brushes in a direction that is not perpendicular to the rotational axis. The solar panel cleaning apparatus is may be configured such that the angle of the rotational axis of at least one of the one or more rotatable brushes is adjustable relative to the direction of travel.

Cleaning Process Development for Metallic Additively Manufactured Parts

Science.gov (United States)

Tramel, Terri L.; Welker, Roger; Lowery, Niki; Mitchell, Mark

2014-01-01

Additive Manufacturing of metallic components for aerospace applications offers many advantages over traditional manufacturing techniques. As a new technology, many aspects of its widespread utilization remain open to investigation. Among these are the cleaning processes that can be used for post finishing of parts and measurements to verify effectiveness of the cleaning processes. Many cleaning and drying processes and measurement methods that have been used for parts manufactured using conventional techniques are candidates that may be considered for cleaning and verification of additively manufactured parts. Among these are vapor degreasing, ultrasonic immersion and spray cleaning, followed by hot air drying, vacuum baking and solvent displacement drying. Differences in porosity, density, and surface finish of additively manufactured versus conventionally manufactured parts may introduce new considerations in the selection of cleaning and drying processes or the method used to verify their effectiveness. This presentation will review the relative strengths and weaknesses of different candidate cleaning and drying processes as they may apply to additively manufactured metal parts for aerospace applications. An ultrasonic cleaning technique for exploring the cleanability of parts will be presented along with an example using additively manufactured Inconel 718 test specimens to illustrate its use. The data analysis shows that this ultrasonic cleaning approach results in a well-behaved ultrasonic cleaning/extraction behavior. That is, it does not show signs of accelerated cavitation erosion of the base material, which was later confirmed by neutron imaging. In addition, the analysis indicated that complete cleaning would be achieved by ultrasonic immersion cleaning at approximately 5 minutes, which was verified by subsequent cleaning of additional parts.

Enhanced Synthesis of Alkyl Amino Acids in Miller's 1958 H2S Experiment

Science.gov (United States)

Parker, Eric T.; Cleaves, H. James; Callahan, Michael P.; Dworkin, James P.; Glavin, Daniel P.; Lazcano, Antonio; Bada, Jeffrey L.

2011-01-01

Stanley Miller's 1958 H2S-containing experiment, which included a simulated prebiotic atmosphere of methane (CH4), ammonia (NH3), carbon dioxide (CO2), and hydrogen sulfide (H2S) produced several alkyl amino acids, including the alpha-, beta-, and gamma-isomers of aminobutyric acid (ABA) in greater relative yields than had previously been reported from his spark discharge experiments. In the presence of H2S, aspariic and glutamic acids could yield alkyl amino acids via the formation of thioimide intermediates. Radical chemistry initiated by passing H2S through a spark discharge could have also enhanced alkyl amino acid synthesis by generating alkyl radicals that can help form the aldehyde and ketone precursors to these amino acids. We propose mechanisms that may have influenced the synthesis of certain amino acids in localized environments rich in H2S and lightning discharges, similar to conditions near volcanic systems on the early Earth, thus contributing to the prebiotic chemical inventory of the primordial Earth.

Treatment of Dye Wastewater by Using a Hybrid Gas/Liquid Pulsed Discharge Plasma Reactor

International Nuclear Information System (INIS)

Lu Na; Li Jie; Wu Yan; Masayuki, Sato

2012-01-01

A hybrid gas/liquid pulsed discharge plasma reactor using a porous ceramic tube is proposed for dye wastewater treatment. High voltage pulsed discharge plasma was generated in the gas phase and simultaneously the plasma channel was permeated through the tiny holes of the ceramic tube into the water phase accompanied by gas bubbles. The porous ceramic tube not only separated the gas phase and liquid phase but also offered an effective plasma spreading channel. The effects of the peak pulse voltage, additive gas varieties, gas bubbling rate, solution conductivity and TiO 2 addition were investigated. The results showed that this reactor was effective for dye wastewater treatment. The decoloration efficiency of Acid Orange II was enhanced with an increase in the power supplied. Under the studied conditions, 97% of Acid Orange II in aqueous solution was effectively decolored with additive oxygen gas, which was 51% higher than that with argon gas, and the increasing O 2 bubbling rate also benefited the decoloration of dye wastewater. Water conductivity had a small effect on the level of decoloration. Catalysis of TiO 2 could be induced by the pulsed discharge plasma and addition of TiO 2 aided the decoloration of Acid Orange II.

Clean fuel for demanding environmental markets

Energy Technology Data Exchange (ETDEWEB)

Josewicz, W.; Natschke, D.E. [Acurex Environmental Corp., Research Triangle Park, NC (United States)

1995-12-31

Acurex Environmental Corporation is bringing Clean Fuel to the environmentally demand Krakow market, through the cooperative agreement with the U.S. Department of Energy. Clean fuel is a proprietary clean burning coal-based energy source intended for use in stoves and hand stoked boilers. Clean Fuel is a home heating fuel that is similar in form and function to raw coal, but is more environmentally friendly and lower in cost. The heating value of Clean Fuel is 24,45 kJ/kg. Extensive sets of confirmation runs were conducted in the Academy of Mining and Metallurgy in the Krakow laboratories. It demonstrated up to 54 percent reduction of particulate matter emission, up to 35 percent reduction of total hydrocarbon emissions. Most importantly, polycyclic aromatic hydrocarbons (toxic and carcinogens compounds) emissions were reduced by up to 85 percent, depending on species measured. The above comparison was made against premium chunk coal that is currently available in Krakow for approximately $83 to 93/ton. Clean Fuel will be made available in Krakow at a price approximately 10 percent lower than that of the premium chunk coal.