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Sample records for acero inoxidable duplex

  1. Sigma-phase formation in weldments of cast super duplex stainless steel; Formacion de fase sigma en uniones soldadas de acero inoxidable super duplex fundido

    Energy Technology Data Exchange (ETDEWEB)

    Garin, J. L.; Mannheim, R. L.; Camus, M. A.

    2011-07-01

    This paper describes the microstructural characteristics of weldments of cast super duplex stainless steel (J93404), being subjected to annealing processes to induce formation of sigma-phase at high temperatures. The influence of heating time at 1073 K, 1123 K and 1173 K upon precipitation of sigma in the heat affected zone, base metal and fusion zone of the weldments was analyzed. The experimental results revealed the formation of this intermetallic compound throughout decomposition of the ferritic phase into austenite and sigma. At earlier stages of the transformation the phase rapidly nucleates and growth along the ferrite-austenite grain boundaries, and then massively advances towards the bulk of the ferritic zone with greater effectiveness as temperature increases. The formation of sigma-phase in all weldments resembles the Johnson-Mehl-Avramis mechanism stated for nucleation and growth. (Author) 27 refs.

  2. Análisis de los transitorios de ruido electroquímico para aceros inoxidables 316 Y – DUPLEX 2205 en NaCl Y FeCl

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    Almeraya-Calderón, F.

    2012-04-01

    Full Text Available This work shows the results obtained from electrochemical noise measurements for different materials exhibiting pitting corrosion. The transients presented in the potential and current time, correlates with the scanning electron microscopy (SEM surface analysis. Electrochemical measurements were made at different exposure times to obtain the correlation. The materials used were stainless steel austenitic 316 and duplex 2205, immersed in ferric chloride (FeCl3 and sodium chloride (NaCl electrolytes. SEM analysis shows that the transients observed in the time series, really correspond to the activity of pit nucleation developed over the surface of the electrodes.

    En este trabajo se muestran los resultados obtenidos de las mediciones de ruido electroquímico para diferentes materiales que exhiben corrosión por picaduras. Los transitorios presentados en las series de tiempo en corriente y en potencial, se correlacionan con el análisis superficial de microscopía electrónica de barrido (MEB. Las mediciones electroquímicas fueron realizadas a diferentes tiempos de exposición, para obtener una correlación. Los materiales usados fueron los aceros inoxidables 316 y dúplex 2205, inmersos en cloruro férrico (FeCl3 y cloruro de sodio (NaCl como electrolitos. Los análisis por MEB, muestran que los transitorios observados en las series de tiempo, corresponden realmente con la actividad de la nucleación de picaduras desarrollada sobre la superficie de los electrodos.

  3. Sinterabilidad y propiedades del acero pulvimetalúrgico HCx diluido con aceros inoxidables

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    Gordo, E.

    2005-12-01

    Full Text Available HCx is a powder metallurgy steel developed to combine the corrosion resistance of stainless steel with the wear resistance of tool steels. Therefore, HCx appears to be a suitable material for wear applications in aggressive environments, as valve seat inserts in automotive engines. In this work dilution of HCx with two stainless steels, one ferritic (430 and another austenitic (316L, in percentages up to 15 % in mass, has been studied to improve process conditions, especially compressibility. The sinterability of diluted materials was studied through vacuum sintering at temperatures from 1.200 °C to 1.260 °C. Finally, properties of sintered materials were determined. The results are discussed in relation to the microstructure evolution.

    El acero pulvimetalúrgico HCx ha sido desarrollado para combinar la resistencia a corrosión de los aceros inoxidables con la resistencia al desgaste de los aceros de herramientas. Aparece así como un material adecuado para componentes sometidos a desgaste en un ambiente agresivo, como los asientos de válvulas en motores de automóviles. En este trabajo se estudia la dilución del HCx con dos aceros inoxidables, uno ferrítico (430 y otro austenítico (316L, en porcentajes hasta 15 % en masa, para mejorar las condiciones de procesado, especialmente la compresibilidad. La sinterabilidad de los materiales diluidos se ha estudiado mediante sinterización en vacío, a temperaturas entre 1.200 °C y 1.260 °C, y se han determinado las propiedades de los materiales sinterizados. Los resultados se discuten en relación a la evolución microestructural.

  4. Influence of the filler material on the pitting corrosion in welded duplex stainless; Influencia del material de aporte en la resistencia a corrosion por picadura en uniones soldadas de un acero inoxidable duplex

    Energy Technology Data Exchange (ETDEWEB)

    Munez, C. J.; Utrilla, M. V.; Urena, A.; Otero, E.

    2007-07-01

    In this work, it has been studied the pitting corrosion resistance of welding duplex stainless steel 2205. Unions were made by GMAW process with different fillers: duplex ER 2209 and two austenitic (ER 316LSi and ER 308LSi). the microstructure obtained with the duplex ER 2209 filler is similar to the duplex 2205 base material, but the unions produced with the austenitic fillers cause a decrease of the phases relation{alpha}/{gamma}. To evaluate the influence of the filler on the weld, the pitting corrosion resistance was determined by electrochemical critical pitting temperature test (TCP) and the mechanical properties by the hardness. The phases imbalance produced for the dissimilar fillers bring out a variation of the pitting corrosion resistance and the mechanical properties. (Author)

  5. Metalografía en color de los aceros inoxidables mediante la técnica de ataque coloreado

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    Fosca, C.

    1996-08-01

    Full Text Available The color metallography by tint etching allows the identification and quantification by optical microscopy of phases and constituents present in the microstructure of a great number alloys. The principle of this technique consists of the build up of an interference film on the alloy surface as consequence of electrochemical reactions between the metallic surface and the tint etching reagent. The application of the tint etching to the metallographic analysis of stainless steels enable the identification and quantification, by image analysis, of secondary phases, as ferrite in the austenitic stainless steels, or secondary austenite and sigma phase in the duplex stainless steels.

    La metalografía en color mediante la técnica de ataque coloreado permite la identificación y cuantificación, por el contraste de color, de diversas fases y constituyentes presentes en la microestructura de un gran número de aleaciones. La técnica consiste en depositar una película de interferencia en la superficie del material como consecuencia de reacciones electroquímicas entre el metal y el reactivo de ataque coloreado. La aplicación de la técnica de ataque coloreado en los aceros inoxidables permite la identificación y cuantificación, mediante análisis de imagen, de fases secundarias como la ferrita en los aceros inoxidables austeníticos o la austenita secundaria y la fase sigma en los aceros inoxidables dúplex.

  6. Aceros inoxidables de nuevo diseño resistentes a la corrosión localizada

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    Otero, E.

    2005-04-01

    Full Text Available A new material, usually, is a classic material with small modifications. The modifications provide new and/or superior properties to the material, making it competitive. The development of a new austenitic stainless steel based on the modified AISI 304 is described in the present work. This new steel shows a pitting corrosion resistance similar, or even better, than AISI 316. The behaviour of a stainless duplex steel with a low content in Ni is also described here. Its pitting corrosion resistance is similar than a conventional duplex steel. In both cases the ratio properties/price turns out to be competitive. The work was carried out by Acerinox S.A. inside the general plan of I + D, which is developed in collaboration with several public research centers whose principal activities are related to Science and Technology of Materials

    Un nuevo material suele ser un material clásico al que pequeñas modificaciones proporcionan nuevas y/o mejores propiedades, haciéndolo competitivo desde el punto de vista del mercado. De acuerdo con esta filosofía, se describe en el presente trabajo el desarrollo de un nuevo acero inoxidable austenítico sobre la base del AISI 304 modificado, con propiedades de resistencia a la corrosión por picadura similares o, incluso, superiores a un AISI 316, y el de un acero inoxidable dúplex, de bajo contenido en níquel y comportamiento frente a la corrosión por picadura similar a un dúplex convencional. En ambos casos, la relación prestaciones/precio resulta ser competitiva. El trabajo se inscribe en el marco del plan general de I+D que desarrolla Acerinox S.A. en colaboración con varios centros públicos de investigación en el área de la Ciencia y Tecnología de los Materiales

  7. Estudio del fenómeno de Strain Ageing en el acero inoxidable metaestable 301 LN

    OpenAIRE

    Hevin, Lucas

    2014-01-01

    Un acero inoxidable metaestable es una aleación que presenta el efecto TRIP: Transformation Induced Plasticity. El acero estudiado, EN 1.4318/AISI 301 LN, tiene una estructura austenítica que puede transformarse en martensita por deformación. Tiene una buena resistencia a corrosión, buena conformabilidad, y una combinación de límite elástico y de deformación máxima muy superior a otros aceros. Con dicha transformación martensítica se puede aumentar el límite elástico y la resistencia a tracci...

  8. Análisis de soldabilidad de aceros inoxidables con aceros de medio y bajo carbono por SMAW

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    José Luddey Marulanda Arevalo

    2013-12-01

    Full Text Available Se presenta un estudio de la soldabilidad de aceros inoxidables austeníticos AISI 304 y AISI 316 con aceros de bajo y medio carbono AISI 1020 – AISI 1045, empleando como materiales de aporte los electrodos EutecTrode® 52 NG, 54 NG y 57 NG, mediante el proceso de arco eléctrico con electrodo revestido (SMAW. Para analizar la soldabilidad de estos electrodos cuando se realiza la unión de aceros inoxidables con aceros al carbono, se practicaron pruebas metalográficas y ensayos mecánicos de dureza, doblez y tracción, con el fin de observar el comportamiento tanto de la zona afectada térmicamente como del cordón de soldadura, a partir del cambio en las propiedades mecánicas y metalúrgicas en las diferentes regiones de las uniones soldadas. Durante el proceso de soldadura se siguió una especificación del procedimiento de soldadura (WPS, para que los resultados fueran repetibles, minimizando los problemas de agrietamiento en caliente, agrietamiento en frío, formación de fase sigma y precipitación de carburos.

  9. Propiedades mecánicas de las uniones por láser de aceros inoxidables dúplex

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    Amigó, V.

    2005-04-01

    Full Text Available The welded joints of stainless steels always present problems for the microstructural modifications that occur in the heat affected zone. Particularly, duplex stainless steels present very important changes when the weld pool solidifies forming fundamentally ferritic structures with some austenite in grain boundaries. These microstructural modifications, and those which occur in the HAZ, justify the mechanical properties of the joint and mainly those of plasticity, being all of them influenced by the processing conditions. In this work the influence of the laser welding speed on the tensile behaviour of duplex stainless steel welded joints is presented. The microstructure of the obtained seams and of the heat affected zone will be evaluated by means of optic and scanning electron microscopy. Also, different microhardness profiles have been obtained to evaluate the modifications in the mechanical properties both in the seam and the zone of thermal affection.

    Las uniones soldadas de aceros inoxidables siempre presentan problemas por las modificaciones microestructurales que suceden en la zona afectada por el calor. Particularmente, los aceros inoxidables dúplex presentan cambios microestructurales muy importantes al solidificar el cordón y formar estructuras, fundamentalmente ferríticas, con formación de austenita en borde de grano. Estas modificaciones microestructurales, junto a las que suceden en la ZAC, son las que justifican las propiedades mecánicas de la unión y fundamentalmente las de plasticidad. Y todo ello en función de las condiciones de procesado. En este trabajo se presenta la influencia de la velocidad de soldeo en las propiedades a tracción de uniones soldadas por láser de chapas de acero inoxidables dúplex. La microestructura de los cordones obtenidos y de la zona afectada por el calor se ha evaluado mediante microscopía óptica y electrónica de barrido, y se han obtenido diferentes perfiles de microdureza que

  10. ESTUDIO DE LA SOLDABILIDAD Y CORROSIÓN DEL ACERO INOXIDABLE AISI 904L CON LOS AGENTES UTILIZADOS EN LA LIXIVIACIÓN DEL COBRE

    OpenAIRE

    Ramón Cortés P; Jaime Villanueva A; Ernesto Ponce L; Manuel Rojas M; Eduardo Rojas Z

    2004-01-01

    La alta agresividad de las soluciones utilizadas en el proceso de lixiviación del cobre y los cuidados especiales que se debe tener para evitar la formación de fases sensibles a estos agentes en la soldadura de aceros inoxidables, ha exigido el desarrollo de nuevos aceros inoxidables que sean más resistentes a la corrosión, manteniendo las propiedades de resistencia a la tracción, al impacto y ductilidad. Es el caso de acero inoxidable AISI 904L, un acero super austenítico de última generació...

  11. Comportamiento frente a corrosión bajo tensión en ambiente marino de armaduras de acero inoxidable dúplex

    OpenAIRE

    Fernández Robles, José Jaime

    2015-01-01

    La utilización de barras corrugadas de acero inoxidable en estructuras de hormigón armado, se está mostrando como una alternativa con gran futuro en estructuras expuestas a ambientes muy agresivos o que requieran vidas en servicio muy elevadas. Estos aceros inoxidables cuentan con similares propiedades mecánicas que los aceros al carbono pero un comportamiento muy mejorado frente a la corrosión, especialmente frente a cloruros. Dentro de los aceros inoxidables, los del tipo dúplex tienen ...

  12. Transformaciones Microestructurales en Soldaduras Disímiles de Acero Inoxidable Austenítico con Acero Inoxidable Ferrítico

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    Sara María Aguilar-Sierra

    2015-03-01

    Full Text Available En este trabajo se estudian los fenómenos metalúrgicos que ocurren en la soldadura SMAW de un acero inoxidable ferrítico AISI 430 con un acero inoxidable austenítico AISI 316L. Para el estudio se utilizaron dos tipos de electrodos: austenítico AWS E309L y dúplex AWS E2209-16, ambos con un diámetro de 3,2 mm. Las uniones soldadas se realizaron con un solo pase y se variaron simultáneamente la corriente y la velocidad de soldadura; las condiciones fueron 49 A y 2,4 mm.s–1como valores bajos y 107 A y 4,3 mm.s–1como valores altos. Se evaluó la influencia del tipo de electrodo y de los parámetros de soldadura en la evolución microestructural de las zonas afectadas por el calor y de las zonas de fusión, encontrando diferencias en la morfología y cantidad de ferrita delta para todas las condiciones estudiadas. Se evidenció crecimiento y refinación de grano ferrítico y formación de martensita en la zona afectada por el calor del metal base ferrítico. Se evaluó también la resistencia a la tensión hallando similitudes en todas las soldaduras.

  13. Tecnología para la obtención de polvos microporosos de acero inoxidable

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    Martínez, M.

    2001-10-01

    Full Text Available En el trabajo se trata el desarrollo de la tecnología de obtención de polvos microporosos de acero inoxidable mediante atomización y recocido de descarburación. La esencia del proceso consiste en recarburar el metal en estado líquido y, posteriormente, descarburar el polvo en estado sólido mediante recocido en hidrógeno o amoniaco disociado. Con esta tecnología se logra la formación de una microporosidad interna en la partícula, que aligera el material y mejora los procesos de conformación, ya que aumenta la deformación que puede experimentar una partícula. A su vez, se reduce el costo de producción y los gastos de inversión, para asimilar la tecnología. Además, se exponen los resultados del estudio cinético acerca de la descarburación y la caracterización del polvo de acero inoxidable obtenido.

    En el trabajo se trata el desarrollo de la tecnología de obtención de polvos microporosos de acero inoxidable mediante atomización y recocido de descarburación. La esencia del proceso consiste en recarburar el metal en estado líquido y, posteriormente, descarburar el polvo en estado sólido mediante recocido en hidrógeno o amoniaco disociado. Con esta tecnología se logra la formación de una microporosidad interna en la partícula, que aligera el material y mejora los procesos de conformación, ya que aumenta la deformación que puede experimentar una partícula. A su vez, se reduce el costo de producción y los gastos de inversión, para asimilar la tecnología. Además, se exponen los resultados del estudio cinético acerca de la descarburación y la caracterización del polvo de acero inoxidable obtenido.

  14. Estudio de la corrosión producida en aceros inoxidables 304 en procesos de soldadura

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    G. Terán

    2004-01-01

    Full Text Available En este trabajo de investigación se analizan las probetas de aceros inoxidables 304 que después de haber sido soldadas mediante los procesos de soldadura SMAW, GMAW y GTAW, se sometieron a un ambiente corrosivo propio de las condiciones de trabajo. Se estudió la microestructura del cordón de soldadura utilizando microscopía electrónica de barrido (SEM, la interfase entre el material base y el de aporte se estudió utilizando un microscopio óptico y analizador de imágenes.

  15. Análisis económico de la utilización de armaduras de acero inoxidable en estructuras de hormigón

    OpenAIRE

    Medina Sanchez, Eduardo; Cobo Escamilla, Alfonso; Martínez Bastidas, David

    2012-01-01

    La utilización de armaduras de acero inoxidable, de los tipos austeníticos y dúplex, con el objetivo de prolongar la vida útil de las estructuras de hormigón, es una alternativa que está recibiendo cada vez más consideración. Los aceros inoxidables son aleaciones fundamentalmente de cromo y níquel, con muy alta resistencia a la corrosión, especialmente frente a cloruros. El elevado coste del níquel y sus grandes fluctuaciones en el mercado, han favorecido la aparición de nuevos aceros inoxida...

  16. Comportamiento Tribológico de Aceros Inoxidables para Cubertería Tribologic Behavior of Stainless Steels for Cutlery

    OpenAIRE

    José D.B de Mello; Paulo S. de S Bálsamo

    2006-01-01

    Se estudió el comportamiento tribológico de los aceros inoxidables utilizados en cubertería. Se sometieron aceros martensíticos y ferríticos con diferentes contenidos de carbono y cromo a ensayos con micro-abrasión y desgaste por deslizamiento alternado. A pesar de que la composición química haya afectado considerablemente la micro estructura y dureza de las aleaciones, el comportamiento en la abrasión y en el coeficiente de fricción no fueron afectados por estos factores. La velocidad de des...

  17. Comportamiento electroquímico de un acero inoxidable AISI 430 implantado con cerio

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    Abreu, C. M.

    2002-10-01

    Full Text Available Chemical treatment in solutions containing cerium compounds has been widely used for prevention of localized corrosion in aluminium alloys (pitting corrosion as well as in stainless steels (crevice corrosion. Ionic implantation presents several advantages for stainless steels. The present paper is devoted to study the effect of cerium implantation on the properties of passive films formed on an AISI 430 stainless steel in alkaline medium. The electrochemical study is performed by cyclic voltammetry and EIS. The chemical characterisation of the oxides film developed is performed by XPS, and the morphological study corresponds to SEM examination. The results show that cerium implantation hinders magnetite formation as well as chromium oxidation processes.

    En los últimos años, se ha extendido el uso de disoluciones de sales de cerio como tratamiento para mejorar la resistencia localizada de las aleaciones de aluminio y para incrementar la resistencia a la corrosión en resquicio de diversos aceros inoxidables. En el caso de estos últimos, la adición de cerio mediante implantación iónica supone notables ventajas con respecto a otros tratamientos. En este artículo se investiga el efecto que ejerce la implantación de cerio sobre la película pasivante de un acero inoxidable ferrítico AISI 430. Para ello, se analiza el comportamiento electroquímico en medio básico mediante la utilización de voltametría cíclica y espectroscopia de impedancia electroquímica. La caracterización química de la película de óxidos formada se realiza mediante XPS, y el estudio morfológico mediante SEM. Los resultados muestran una importante inhibición en la formación de magnetita, así como una reducción en el proceso de oxidación que experimenta el cromo en el acero implantado con cerio.

  18. Influencia de los tratamientos térmicos en la deformación en frío de los aceros inoxidables dúplex

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    Fargas, G.

    2004-06-01

    Full Text Available The purpose of this paper is to study the compression behavior of a duplex stainless steel after several annealing conditions, in order to simulate the response during cold rolling in the industrial process. For each studied condition, stress-strain curves present serrations in the flow zone due to austenite and ferrite twinning and the austenite phase transformation to martensite. At the same time, it is shown that sigma phase increases the strength and diminish the cold deformation capacity of the steel.

    Se realizó un estudio del comportamiento a compresión de un acero inoxidable dúplex sometido a distintos tratamientos térmicos de recocido, con el fin de simular su respuesta durante la laminación en frío que tiene lugar en el proceso industrial. Para todas las condiciones estudiadas, las curvas esfuerzo-deformación presentan inestabilidades en la zona plástica, provocadas por el maclado de ambas fases y la transformación de la austenita a martensita. Al mismo tiempo, puede observarse cómo la presencia de fase sigma endurece el acero y limita su capacidad de deformación.

  19. Efectos gammágenos del cobre en los aceros inoxidables 18Cr8Ni

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    Botella, J.

    1997-10-01

    Full Text Available From a series of 22 typical 18Cr8Ni stainless steel 40 kg ingots, with copper variable concentrations from 0.6 to 3.0 weight %, δ-ferrite is measured with a ferrite-meter device, calculating a nickel equivalent of 0.27 for copper. Some differences between the 8-ferrite and that on calculated by DeLong -excluding the copper γ-gene action- have been found because of different solidification and cooling regimes in ingot and weld cases.

    A partir de una serie de 22 lingotes de 40 kg de aceros inoxidables típicos 18Cr8Ni, con concentraciones variables de cobre entre 0,6 y 3,0 % en masa, se mide la ferrita δ mediante un medidor de ferrita y se deduce para el cobre un equivalente en níquel de 0,27, a la vez que se establecen ciertas diferencias entre los contenidos de ferrita δ medida y la deducida según DeLong -excluida la acción gammágena del cobre- por el hecho de solidificar en lingotes en vez de la típica solidificación de soldaduras.

  20. Influencia del material de aporte en la resistencia a corrosión por picadura en uniones soldadas de un acero inoxidable dúplex 2205

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    Múnez, C. J.

    2007-08-01

    Full Text Available In this work, it has been studied the pitting corrosion resistance of welding duplex stainless steel 2205. Unions were made by GMAW process with different fillers: duplex ER 2209 and two austenitic (ER 316LSi and ER 308LSi. The microstructure obtained with the duplex ER 2209 filler is similar to the duplex 2205 base material, but the unions produced with the austenitic fillers cause a decrease of the phases relation a/g. To evaluate the influence of the filler on the weld, the pitting corrosion resistance was determined by electrochemical critical pitting temperature test (TCP and the mechanical properties by the hardness. The phases imbalance produced for the dissimilar fillers bring out a variation of the pitting corrosion resistance and the mechanical properties.

    En este trabajo se ha estudiado la resistencia a la corrosión localizada por picadura, de soldaduras realizadas sobre un acero inoxidable dúplex 2205. Se hicieron uniones mediante el proceso GMAW, utilizando como material de aporte un hilo dúplex ER 2209 y dos austeníticos ER 316LSi y ER 308LSi. Metalúrgicamente, se observa como para el hilo ER 2209 las microestructuras que se obtienen son similares a la del dúplex 2205, mientras que en las uniones con hilo austenítico, pueden verse microestructuras muy diferentes en las que la relación de fases a/g disminuye. Al evaluar la resistencia a la corrosión por picadura, mediante la Temperatura Crítica de Picadura (TCP, se comprobó como el desequilibrio entre las fases, generado por el aporte, provoca la variación en la resistencia a la corrosión localizada por picadura. También, se estudió la variación en las propiedades mecánicas del material mediante ensayos de dureza.

  1. “ESTUDIO DEL COMPORTAMIENTO DE LOS ACEROS INOXIDABLES AUSTENITICOS 316 Y 316L, EN LA ZONA AFECTADA TERMICAMENTE, UNIDO POR SOLDADURA MIG, CON APLICACION DE INTERACCION ELECTROMAGNETICA DE BAJA INTENSIDAD”

    OpenAIRE

    Estrella García, Salvador

    2012-01-01

    En el presente capítulo, se presenta un contenido breve acerca del tema a estudiar, es decir, de la influencia de la interacción de dos campos magnéticos de baja intensidad durante el proceso de soldadura MIG, en los aceros inoxidables austeníticos 316 y 316L, así como también los principales problemas que presentan dichos aceros inoxidables y de una manera simplificada el resumen de los objetivos planteados y la forma en que se desarrollarán. Los aceros inoxidables, son ino...

  2. Desarrollo de un modelo predictivo de la degradación de lacas colaminadas sobre aceros inoxidables

    OpenAIRE

    Peña de la Mora, Eduardo

    2007-01-01

    En ese trabajo anterior se desarrollaron dos modelos acelerados de prueba que predicen la degradación de lacas con base de dos componentes de poliuretano aplicados sobre acero inoxidable 304 del tipo austenítico. Sin embargo, dichos modelos son de tipo particular. Es decir, específicos para las características particulares de las lacas estudiadas. En síntesis, no se cuenta ni con un procedimiento de prueba general, ni con un modelo general de pruebas aceleradas que permita predecir el envejec...

  3. Caracterización y propiedades mecánicas a alta temperatura de un acero inoxidable dúplex

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    Jiménez, J. A.

    1998-05-01

    Full Text Available The microstructure and mechanical behavior at high temperature of a thermomechanical processed duplex stainless steel have been studied. Recrystalization of the material takes place during heating to test temperature, and a microstructure consisting of islands of austenitic grains of about 10-15 μm in size included in a more or less continuous matrix of ferrite is observed. Tensile tests at temperatures above 1,000°C and at low strain rates show a stress exponent of about 2 and elongations to failure up to 290 %. These values suggest that deformation is controlled by a grain boundary sliding mechanism, which causes a decrease in the size of the islands during deformation. Finally, an activation energy for plastic deformation of 167 kJ/mol was observed that was related to the activation energy for grain boundary diffusion of iron.

    Se ha estudiado la microestructura y el comportamiento mecánico a alta temperatura de un acero inoxidable dúplex procesado termomecánicamente. Durante el calentamiento a la temperatura de ensayo, el material recristaliza y se obtiene una microestructura de granos austeníticos de tamaños comprendidos entre 10 y 15 μm agrupados en islas incluidas en una matriz más o menos continua de ferrita. Ensayos de tracción a temperaturas superiores a 1.000°C y bajas velocidades de deformación muestran un exponente de la tensión igual a 2 y alargamientos a rotura de hasta 290 %. Estos valores permiten asociar el mecanismo de deformación al deslizamiento de fronteras de grano, el cual determina la desaparición progresiva de las islas de granos austeníticos durante la deformación. Finalmente, se encontró un valor de 167 kJ/mol para la energía de activación de la deformación plástica, la cual se relacionó con la energía de autodifusión del hierro a lo largo de las fronteras de grano.

  4. Comportamiento Tribológico de Aceros Inoxidables para Cubertería Tribologic Behavior of Stainless Steels for Cutlery

    Directory of Open Access Journals (Sweden)

    José D.B de Mello

    2006-01-01

    Full Text Available Se estudió el comportamiento tribológico de los aceros inoxidables utilizados en cubertería. Se sometieron aceros martensíticos y ferríticos con diferentes contenidos de carbono y cromo a ensayos con micro-abrasión y desgaste por deslizamiento alternado. A pesar de que la composición química haya afectado considerablemente la micro estructura y dureza de las aleaciones, el comportamiento en la abrasión y en el coeficiente de fricción no fueron afectados por estos factores. La velocidad de desgaste por deslizamiento crece con el potencial de contacto, sugiriendo que el desgaste por deslizamiento de estos aceros se asocia con la formación de una capa protectora de óxidos.A study was made of the tribologic behavior of stainless steel used in cutlery. Abrasive and sliding wear tests were carried out on martensitic and ferritic stainless steels which had different contents of carbon and chromium. Although the chemical composition and heat treatment considerably modified the microstructure and hardness of the steels, these treatments had no significant effect on abrasion resistance and the friction coefficient. The sliding wear rate grows with the contact potential, suggesting that sliding wear in these steels is associated with the formation of protective oxide coatings

  5. Tratamiento térmico del acero inoxidable ferrítico AISI 430L sinterizado en atmósfera de N2-H2

    Directory of Open Access Journals (Sweden)

    Ruiz-Prieto, J. M.

    2005-12-01

    Full Text Available In this Work the influence of sintering AISI 430L stainless steel in N2-H2 atmosphere on its properties and microstructure have been studied. The presence of nitrogen in the sintering atmosphere leads to complex nitrides formation the AISI 430L sintered steel microstructure. A subsequent heat treatment was applied to modify this microstructure in order to improve the mechanical properties and corrosion resistance of these ferritic stainless steels.Los aceros inoxidables ferríticos, son aceros que contienen esencialmente cromo (12-30 % junto con níquel y molibdeno en cantidades que, en general, no sobrepasan el 1 % y, en ocasiones, se les adicionan otros elementos como son el aluminio, silicio, titanio o niobio. En el presente trabajo de investigación se ha evaluado la influencia del nitrógeno presente en la atmósfera de sinterización sobre la microestructura y propiedades del acero inoxidable ferrítico AISI 430L. Además, se ha realizado un tratamiento térmico posterior de hipertemple y maduración con el objeto de incrementar las propiedades mecánicas y a corrosión de este acero inoxidable, mediante la modificación microestructural de los nitruros complejos de hierro y cromo precipitados durante la etapa de sinterización.

  6. Efecto de la biopelícula en la corrosión de aceros inoxidables

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    Bethencourt, M.

    2010-02-01

    Full Text Available In this work, the influence of the biofilms in the corrosion process of different alloys of stainless steel was studied in two sampling points in a wastewater treatment plant during 4 years. The physicochemical microenvironment within the biofilms was characterized through O2, H2S and pH microelectrodes. Corrosion rates were quantified from the number, diameter and depth of pits. The results show a remarkable development of the biofilm and a significantly greater number of pits in the grit removal channel than in the sludge recirculation channel. Based on the characteristics of the water phase and microelectrode measurements, our results suggest that biofilms induced corrosion throughout 3 mechanisms: creation of differential aeration cells, areas with different pH and areas having high sulphide production which may react with metal ions.

    En este trabajo se ha estudiado la influencia de las biopelículas en los procesos de corrosión de diferentes aleaciones de acero inoxidable, situadas durante 4 años en dos puntos de una estación depuradora de aguas residuales. Se caracterizó el microambiente físico-químico en el interior de las biopelículas mediante microelectrodos de O2, H2S y pH, y se cuantificaron las tasas de corrosión a partir del número, diámetro y profundidad de picadura. Los resultados obtenidos muestran un desarrollo más notable de las biopelículas y un número de picaduras significativamente mayor en el canal de salida de desbastes que en el canal de recirculación de fangos. Con base en las características del agua sobrenadante y en las medidas realizadas con microelectrodos, se sugiere que la biopelícula induce la corrosión a través de tres posibles mecanismos: creación de celdas de aireación diferencial, zonas con diferente pH y zonas con elevada producción de sulfuro capaz de reaccionar con iones metálicos.

  7. Evaluation of structural behaviour and corrosion resistant of austenitic AISI 304 and duplex AISI 2304 stainless steel reinforcements embedded in ordinary Portland cement mortars; Evaluacion del comportamiento estructural y de resistencia a la corrosion de armaduras de acero inoxidable austenitico AISI 304 y duplex AISI 2304 embebidas en morteros de cemento Portland

    Energy Technology Data Exchange (ETDEWEB)

    Medina, E.; Cobo, A.; Bastidas, D. M.

    2012-07-01

    The mechanical and structural behaviour of two stainless steels reinforcements, with grades austenitic EN 1.4301 (AISI 304) and duplex EN 1.4362 (AISI 2304) have been studied, and compared with the conventional carbon steel B500SD rebar. The study was conducted at three levels: at rebar level, at section level and at structural element level. The different mechanical properties of stainless steel directly influence the behaviour at section level and structural element level. The study of the corrosion behaviour of the two stainless steels has been performed by electrochemical measurements, monitoring the corrosion potential and the lineal polarization resistance (LPR), of reinforcements embedded in ordinary Portland cement (OPC) mortar specimens contaminated with different amount of chloride over one year time exposure. Both stainless steels specimens embedded in OPC mortar remain in the passive state for all the chloride concentration range studied after one year exposure. (Author) 26 refs.

  8. Evaluación del grado de sensibilización en el acero inoxidable AISI

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    González, O.

    2003-12-01

    Full Text Available Austenitic stainless steel, when heat-treated at 550-850 °C, became susceptible to intergranular corrosion in acids. This phenomenon, know as sensitization, it is result from the precipitation of chrome carbides in the grain boundary, making these areas less resistant to corrosion. Two different electrochemical reactivation tests are compared with a destructive test and related to the classification of its respective microstructures. It was established a quantitative methodology to evaluate the degree of sensitization in AISI 304 and also to compare the correspondence of the results with the data of the automatic and portable EPR device for non-destructive field measurement of the degree of sensitization. The used electrochemical techniques were the EPR (Electrochemical Potentiokinetic Reactivation or single loop test and the PRP (Pasivation Reactivation Potentiokinetic or double loop test. The destructive test used was boiling, 120 h ferric sulfate-50 % sulfuric acid, according to the standard practices ASTM A-262 practices B. The classifications of each structures were according to the standard practices ASTM A-262 practices B.

    El acero inoxidable austenítico, cuando se calienta en un rango de temperatura entre 550 y 850 °C es susceptible a corrosión intergranular en ácidos. Este fenómeno, conocido como sensibilización, es resultado de la precipitación de carburos de cromo en el límite de grano, haciendo esas áreas menos resistentes a la corrosión. Se comparan dos pruebas diferentes de reactivación electroquímica con una prueba destructiva, relacionándolas con su respectiva microestructura. Se estableció una metodología cuantitativa para evaluar el grado de sensibilización del acero AISI 304 y se comparó con los datos generados de una herramienta no destructiva de campo, automática y portátil, para medir el grado de sensibilización. Las técnicas electroquímicas usadas fueron: la EPR (Reactivación electroqu

  9. Estudio de la susceptibilidad de un acero inoxidable dúplex del tipo 22Cr5NiMoN al dañado por hidrógeno en condiciones estáticas (HIC) y bajo carga (SSC)

    OpenAIRE

    Gutiérrez de Saiz-Solabarría, S.; San Juan, J. M.; Valea, A.

    1998-01-01

    The behavior to hydrogen damage caused by corrosion in a H2S medium is studied in a molded ferrite- austenite (52-48 %) duplex stainless steel 22Cr5NiMoN type (UNS-J9.22.05) under both, static (damaging mechanism called Hydrogen Induced Cracking (HIC)) and sustained load (damaging mechanism called Sulfide Stress Cracking (SSC)), conditions.

    Se estudia el comportamiento de un mismo acero moldeado inoxidable dúplex austeno-ferrítico (48-52 %) del tipo 2...

  10. Formación de microporosidad interna en polvos de acero inoxidable: cinética y mecanismo

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    Martínez, M.

    2002-06-01

    Full Text Available The internal microporosity of stainless steel powders is obtained by a technology developed in the Metallurgical Research Center (CIME in collaboration with ISPETP, which consists of carbon enrichment of alloy during the fusion process, and after powder atomization a subsequent decarburization annealing. The internal microporosity, which can reach up to 10 volume percent of the steel particle, reduces powder density and improves powder compressibility, while costs for technology installation are also reduced. In this paper the technology for obtaining the microporosity, the mathematical models of the process, and the structural transformations undergone by stainless steel powder are shown. It is concluded that for carbon contents lower than 0.05% internal microporosity tends to disappear.

    El Centro de Investigaciones Metalúrgicas (CIME de La Habana, en colaboración con el Instituto Superior Pedagógico para la Educación Técnica Profesional (ISPETP, ha desarrollado una tecnología para la obtención de los polvos de acero inoxidable con microporosidad interna. La tecnología consiste en enriquecer la aleación con carbono durante la fusión y, una vez atomizado el polvo, someterlo a un recocido de descarburación. La microporosidad interna, que puede alcanzar hasta un 10 % en volumen de la partícula, reduce la densidad de los polvos y mejora su compresibilidad, al tiempo que reduce los costes de instalación. El presente trabajo muestra la tecnología de obtención de la microporosidad, los modelos matemáticos del proceso y las transformaciones estructurales que sufre el polvo de acero inoxidable. Se concluye que la microporosidad tiende a desaparecer para contenidos de carbono menores de 0,05 %.

  11. Influencia de la adición de cobre y de bronce sobre las propiedades de los aceros inoxidables austeníticos sinterizados

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    Velasco, F.

    1997-04-01

    Full Text Available The effect that, on AISI 316L and 304L stainless steels alloyed with copper and bronze in different percentages up to a maximun of 20 % wt, produce both the alloying content and the sintering temperature over physical and mechanical properties and over the microstructure of sintered stainless steels are studied. Alloying with copper and bronze improves the density of sintered steels at the two sintering temperatures used. Copper and bronze promote liquid phase sintering (transitory or permanent, that activates sintering process. Tensile strength of stainless steel is highly improved for higher alloying contents. Moreover, tensile strength presents greater values alloying with bronze than with copper.

    Partiendo de los aceros inoxidables AISI 316L y 304L a los que se añadió cobre y bronce en diferentes porcentajes hasta el 20 % en peso, se estudia el efecto que la cantidad de aleante y la temperatura de sinterización tienen sobre las propiedades físicas y mecánicas y sobre la microestructura de los aceros inoxidables sinterizados. La aleación con cobre y con bronce aumenta la densidad de los aceros sinterizados para las dos temperaturas de sinterización utilizadas. El cobre y el bronce provocan la aparición de fase líquida (transitoria o permanente que activa el proceso de sinterización. La resistencia a la tracción del acero inoxidable experimenta un fuerte incremento para los contenidos más elevados de aleante. Además, la resistencia a la tracción alcanza mayores valores para la aleación con bronce que con cobre.

  12. Evaluación del comportamiento estructural y de resistencia a la corrosión de armaduras de acero inoxidable austenítico AISI 304 y dúplex AISI 2304 embebidas en morteros de cemento Pórtland

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    Medina, E.

    2012-12-01

    Full Text Available The mechanical and structural behaviour of two stainless steels reinforcements, with grades austenitic EN 1.4301 (AISI 304 and duplex EN 1.4362 (AISI 2304 have been studied, and compared with the conventional carbon steel B500SD rebar. The study was conducted at three levels: at rebar level, at section level and at structural element level. The different mechanical properties of stainless steel directly influence the behaviour at section level and structural element level. The study of the corrosion behaviour of the two stainless steels has been performed by electrochemical measurements, monitoring the corrosion potential and the lineal polarization resistance (LPR, of reinforcements embedded in ordinary Portland cement (OPC mortar specimens contaminated with different amount of chloride over one year time exposure. Both stainless steels specimens embedded in OPC mortar remain in the passive state for all the chloride concentration range studied after one year exposure.

    Se ha evaluado el comportamiento mecánico y estructural de dos aceros inoxidables corrugados, el austenítico EN 1.4301 (AISI 304 y el dúplex EN 1.4362 (AISI 2304, y se han comparado con el tradicional acero al carbono B500SD. El estudio se ha realizado en tres niveles: a nivel de barra, de sección y de pieza. Las diferentes características mecánicas de los aceros inoxidables condicionan el comportamiento a nivel de sección y de pieza estructural. El estudio del comportamiento frente a la corrosión de los dos aceros inoxidables se ha realizado mediante mediciones electroquímicas monitorizando el potencial de corrosión y la resistencia de polarización de armaduras embebidas en probetas de mortero contaminado con diferentes concentraciones de cloruros durante un tiempo de exposición de un año. Ambos aceros inoxidables permanecen en estado pasivo en las probetas para todos los contenidos de cloruros.

  13. Influencia de la temperatura en las propiedades a tracción de un acero inoxidable superdúplex

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    Gironès, A.

    2001-04-01

    Full Text Available Tensile tests, at temperatures ranging between 275 and 475 °C were performed in a superduplex stainless steel EN 1.4410. The dependence of yield stress and ultimate tensile strength on temperature indicates the existence of dynamic strain aging (DSA. In order to evaluate the influence of strain rate on this phenomenon, tests were conducted at two different strain rates, both at 325 °C, temperature at which DSA is maximum for this material. The results show that the flow stress has an inverse strain rate sensitivity which confirms the existence of DSA in the steel under study.

    Un acero inoxidable superduplex tipo EN 1.4410 se ensayó a tracción en el rango de temperaturas de 275 a 475 °C. La evolución, en función de la temperatura, de los valores de límite elástico y resistencia máxima indica la existencia de un fenómeno de envejecimiento por deformación (Dynamic Strain Aging, DSA. Para evaluar la influencia de la velocidad de deformación sobre dicho comportamiento se realizaron ensayos de tracción a dos velocidades diferentes, ambos a la temperatura de 325 °C, para la cual se había registrado la máxima manifestación de DSA. Dichos ensayos reflejaron una sensibilidad inversa a la velocidad de deformación lo que confirma la presencia de DSA en el acero bifásico estudiado.

  14. Formación de maclas durante el enfriamiento en aceros inoxidables superferríticos envejecidos

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    Salán, M. N.

    2005-12-01

    Full Text Available Superferritic stainless steels show a BCC structure free of austenite at any temperature. Intermediate ageing temperatures, close to 475 °C, induce a-chromium content modulation and only after long periods of time, it is possible to detect chromium rich α' phase, which is responsible for embrittlement (475 °C embrittlement. In this work, ageing thermal treatments at intermediate temperatures in the superferritic stainless steel DIN 1.4575, have allowed to relate the associated hardness increase with time and temperature by means of a relationship that is compatible with a thermally activated process. After quenching from ageing temperature, twinning formation has been observed, and the extent of twinning is proportional to the increase in hardness, showing in this way that twinning density is proportional to embrittlement level.

    Los aceros inoxidables superferríticos se caracterizan por su estructura cúbica centrada, libre de austenita a cualquier temperatura. Sometidos a temperaturas intermedias, próximas a 475 °C, revelan una modulación del contenido en Cr de la red. Después de tiempos prolongados se forma fase α', fragilizante y rica en cromo, fenómeno conocido como fragilización a 475 °C. En este trabajo, los tratamientos de envejecimiento realizados a temperaturas intermedias para un superferrítico DIN 1.4575 han permitido relacionar el incremento de dureza asociado a éstos con el tiempo de tratamiento, mediante una expresión coherente con un proceso térmicamente activado. Por otra parte, se ha detectado la presencia de maclas en el acero envejecido y templado en agua, siendo proporcional su densidad al grado de endurecimiento provocado por el tratamiento.

  15. “IDENTIFICACIÓN DE LA CORROSIÓN EN LOS ALAMBRES DE NIQUEL TITANIO Y ACERO INOXIDABLE Y LA PRESENCIA DE BACTERIAS ASOCIADAS EN UNA MUESTRA DE ARCOS UTILIZADOS EN PACIENTES DE LA CLÍNICA DE ORTODONCIA”.

    OpenAIRE

    Vargas Morales, Karla Odette

    2012-01-01

    El propósito de este trabajo de investigación fue identificar la presencia de corrosión en alambres de Níquel Titanio y Acero Inoxidable, así como presencia de bacterias asociadas en los mismos colocados en boca durante 4 meses en pacientes de la clínica de ortodoncia de la Universidad Michoacana de San Nicolás Hidalgo. En el tamaño de la muestra del presente estudio se utilizaron diez arcos: cinco de níquel titanio termoactivados y cinco de acero inoxidable. Los siguientes ...

  16. Influencia de la composición y el conformado en el comportamiento frente a la corrosión de los corrugados de acero inoxidable

    OpenAIRE

    Álvarez Arboleda, Sandra Milena

    2014-01-01

    En la presente Tesis Doctoral se evalúa el comportamiento frente a la corrosión de barras corrugadas de aceros inoxidables (que pueden ser utilizadas como refuerzo en las partes más expuestas de las estructuras de hormigón) y se analizan en profundidad diversos factores que pueden influir en su durabilidad. El estudio de la influencia de la composición química de las barras ha demostrado el gran interés de los nuevos grados 2001 y el 2304 (dúplex de baja aleación), que ofrecen excelentes resu...

  17. Comportamiento frente a la corrosión de nuevos tipos de armaduras de acero inoxidable para estructuras de hormigón armado

    OpenAIRE

    Blanco Rodríguez, Gema

    2009-01-01

    En la presente Tesis Doctoral se ha realizado un profundo estudio sobre el comportamiento frente a la corrosión de nuevos tipos de armaduras de acero inoxidable para su empleo en estructuras de hormigón armado. Las estructuras de hormigón armado suelen presentar graves problemas de corrosión en medios con cloruros o cuando el hormigón se carbonata. Las alternativas tradicionales para aumentar su durabilidad (protección catódica, galvanizados, resinas epoxi, adición de inhibidores, etc.) han d...

  18. Estudio comparativo de la cavidad de acceso radicular en conductos curvos con limas de níquel-titanio y taladros de acero inoxidable

    OpenAIRE

    Oncins Rodríguez, J.; Pumarola Suñé, José; Canalda Sahli, Carlos

    2005-01-01

    El propósito de este estudio fue comparar la cantidad de dentina radicular removida y evaluar el mantenimiento de la forma del conducto tras la instrumentación de los dos tercios coronarios radiculares, utilizando instrumentos de acero inoxidable (taladros de Gates Glidden) y de níqueltitanio (limas GT Flare y limas Orifice Shaper). Un total de 42 dientes humanos extraídos con conductos radiculares curvos fueron divididos en tres grupos. Los conductos se instrumentaron mecánicamente usando ta...

  19. Influencia de la microestructura en el comportamiento a fatiga de aceros inoxidables austeníticos con alto contenido en molibdeno

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    Oñoro, J.

    2006-02-01

    Full Text Available Austenitic stainless steels with molybdenum present high mechanical properties and corrosion resistance to aggressive environments. These steels have been used to tank and vessel components for high corrosive liquids as phosphoric, nitric and sulphuric acids. These materials with low carbon and nitrogen addition have been proposed candidates as structural materials for the international thermonuclear experimental reactor (ITER in-vessel components. Molybdenum addition in austenitic stainless steel improves mechanical and corrosion properties, but with it can produce the presence of nitrogen microstructure modifications by presence or precipitation of second phases. This paper summarises the fatigue and corrosion fatigue behaviour of two 317LN stainless steels with different microstructure. Fully austenitic steel microstructure show better fatigue, corrosion fatigue resistance and better ductility than austenitic steel with delta ferrite microstructure, mainly at low stresses.

    Los aceros inoxidables austeníticos con elevados contenidos en molibdeno presentan alta resistencia mecánica y resistencia a los medios corrosivos. Se utilizan en la construcción de depósitos y recipientes para el almacenamiento y transporte de líquidos altamente corrosivos, tales como ácido fosfórico, nítrico o sulfúrico. Estos materiales con bajo carbono y adiciones de nitrógeno han sido propuestos como candidatos para materiales estructurales en la fabricación de la vasija del reactor experimental termonuclear internacional (ITER. La adición de molibdeno mejora las propiedades frente a la corrosión de los aceros inoxidables austeníticos. Sin embargo, este aumento del contenido en molibdeno, junto con la presencia de nitrógeno, puede producir modificaciones microestructurales, por la aparición de fases precipitadas o segundas fases. En este trabajo, se analiza el comportamiento la fatiga y corrosión-fatiga de dos aceros inoxidables austen

  20. Efecto del boro en la sinterización de un acero inoxidable ferrítico

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    Cabral-Miramontes, J. A.

    2008-12-01

    Full Text Available This work studies the effect of boron on the density of a 409Nb ferritic stainless steel obtained by powder metallurg during the process of sintering. The purpose of adding boron is to promote the formation of a liquid phase during sintering at temperatures below 1200 °C. The boron contents varied from 0.0 to 1.5%wt. Specimens were compacted at 700MPa, and sintering was made at 1075 and 1150 ºC during 60 minutes under a hydrogen atmosphere, using a heating rate of 20 ºC/min. Density values were determined by the Archimedes method, and the samples were analyzed using scanning electron microscopy. This work shows the dependence of the steel density and morphology of the microestructure as a function of boron content and the temperature of sintering.

    En este trabajo se analiza el efecto del boro sobre la densidad del acero inoxidable ferrítico 409Nb en el proceso de sinterización. La finalidad de adicionar boro es promover la formación de una fase líquida durante la sinterización, a una temperatura por debajo de 1.200 °C. Las adiciones de boro variaron entre 0,0 y 1,5 % en peso. Las muestras se compactaron a 700 MPa y las sinterizaciones se realizaron a 1.075 y 1.150 ºC, durante 60 min en una atmósfera de hidrógeno, calentando a una velocidad de 20 ºC/min. La densidad se determinó por el método de Arquímedes y las muestras se analizaron en el microscopio electrónico de barrido. Este trabajo muestra la dependencia de la densidad del acero y morfología de la microestructura, en función del contenido de boro y la temperatura de sinterización.

  1. Detección de la corrosión por picadura en aceros inoxidables empleando ultrasonidos

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    Rodríguez, Cristina

    2014-03-01

    Full Text Available Passive metallic systems are able to develop in a spontaneous way a protective layer on the metallic surface that offers excellent corrosion resistance since really in a physical barrier for the reaction with the environment. However, some factors can break locally this layer, promoting one of the most insidious attack, pitting corrosion, which produces local chemical conditions that favouring the corrosive process causing defects in the material, as externals and internals ones, with a random distribution on the metal surface. In this work, ultrasounds non destructive technique has been employed using as variable the maximum amplitude of the backwall echo in order to detect this type of attack. The material employed is an austenitic stainless steel AISI 304, wherein appear several defectology distributions as superficial such as depths simulating pits.Los sistemas pasivables, capaces de desarrollar una capa protectora, delgada, adherente y continua sobre el substrato metálico, presentan excelente resistencia a la corrosión ya que dicha capa se produce instantáneamente al reaccionar con el medio. Ahora bien, en determinadas circunstancias, esa capa se puede romper localmente, dando lugar a uno de los ataques más insidiosos que se conocen, corrosión por picadura, que producen unas condiciones químicas locales que aceleran el proceso corrosivo provocando defectos en el material, tanto externos como internos, con una distribución aleatoria en la superficie metálica. En este trabajo se ha planteado el empleo de técnicas de ensayos no destructivas mediante ultrasonidos para detectar este tipo de ataque en un acero inoxidable austenítico AISI 304, con distinta distribución superficial de defectología y profundidades de ataque, que simulan picaduras, tomando como variable fundamental de la onda ultrasónica la amplitud máxima del eco de fondo.

  2. Soldadura TIG de los aceros inoxidables dúplex del tipo 22-05 (Uranus 45N y Avesta. Estudio de la microestructura y de las propiedades mecánicas

    Directory of Open Access Journals (Sweden)

    Gómez de Salazar, J. M.

    1998-05-01

    Full Text Available TIG welding of two different duplex stainless steels is carried out. Arc-discharge on base-material plates by means of the TIG technique without filler metal and varying the energetic conditions (E.N.A. has been performed, A comparative study concerning the microstructural evolution as well as mechanical properties is carried out, The relation between hardness profiles, the microstructural variations and the ferrita δ concentration is established. Further, the above mentioned properties are related to the E.N.A. for each welded joint.

    Se estudia la soldadura TIG de dos aceros inoxidables dúplex. Para ello, se ha descargado un arco sobre las chapas de material base mediante la técnica TIG, sin aportación de material y variando las E.N.A. Se realiza un estudio comparativo de la evolución microestructural, así como de las propiedades mecánicas. Se establece la relación entre los perfiles de dureza obtenidos y la variación microestructural y de la concentración de ferrita δ, así como estas propiedades con el E.N.A, de cada cordón.

  3. Aceros inoxidables de nuevo diseño resistentes a la corrosión localizada

    OpenAIRE

    Otero, E.; Botella, J.; Botana, J.; Matres, V.; Merello, R.

    2005-01-01

    A new material, usually, is a classic material with small modifications. The modifications provide new and/or superior properties to the material, making it competitive. The development of a new austenitic stainless steel based on the modified AISI 304 is described in the present work. This new steel shows a pitting corrosion resistance similar, or even better, than AISI 316. The behaviour of a stainless duplex steel with a low content in Ni is also described here. Its pitting corrosion resis...

  4. Evaluación electroquímica de soldaduras en tubos capilares de acero inoxidable

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    Javier E. Rodríguez-Yáñez

    2014-02-01

    Full Text Available La recuperación de capilares de acero 316L utilizados en pozos geotérmicos neutros, por medio de soldadura orbital autógena, se evalúa desde el punto de vista de su resistencia a la corrosión en las condiciones de utilización, mediante técnicas electroquímicas básicas. En el pretratamiento se encuentra que es más conveniente realizar un decapado químico previo a la soldadura por 5 minutos. Mientras que posteriormente a la soldadura, la aplicación de tratamiento térmico de reducción de tensiones no se justifica desde el punto de vista de la resistencia a la corrosión. También se plantea la comparación de los capilares soldados respecto a capilares nuevos y usados, teniendo los capilares soldados un comportamiento intermedio entre ambos.

  5. Vida a la fatiga de juntas soldadas del acero inoxidable AISI 316L obtenidas mediante el proceso GMAW

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    Puchi-Cabrera, E. S.

    2007-06-01

    Full Text Available An investigation has been conducted in order to determine the effect of both the metallic transfer mode (pulsed arc or short circuit and the O2 content in the Ar/O2 gas mixture, of the gas-metal arc welding process (GMAW, on the fatigue life under uniaxial conditions of welded joints of 316L stainless steel. It has been concluded that the mixture of the protective gases employed in the process could have an important influence on the fatigue life of the welded joints of such steel in two different ways. Firstly, through the modification of the radius of curvature at the joint between the welding toe and the base metal and, secondly, through a more pronounced degree of oxidation of the alloying elements induced by a higher O2 content in the mixture. As far as the metallic transfer mode is concerned, it has been determined that the welded joints obtained under a pulsed arc mode show a greater fatigue life in comparison with the joints obtained under short circuit for both gas mixtures.

    Se ha llevado a cabo una investigación con la finalidad de determinar el efecto, tanto del modo de transferencia metálica (arco pulsado o cortocircuito como del contenido de O2 en la mezcla de gases protectores Ar/O2, del proceso de soldadura a tope mediante arco metálico con protección gaseosa (GMAW, sobre la vida a la fatiga en condiciones uniaxiales de juntas soldadas del acero inoxidable AISI 316L. Dicho trabajo ha permitido concluir que la composición de la mezcla de gases protectores del proceso GMAW pudiera tener una influencia importante en la vida a la fatiga de las juntas soldadas de dicho material, a través de dos formas distintas: primero, mediante la modificación del radio de curvatura entre la raíz del cordón de soldadura y el metal base y, en segundo lugar, a través del mayor grado de oxidación de los elementos de aleación. En cuanto al modo de transferencia metálica, se determinó que las juntas soldadas mediante arco pulsado

  6. Estudio de la influencia de la microestructura sobre la deformabilidad en caliente de un acero inoxidable dúplex

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    Iza-Mendia, A.

    1998-05-01

    Full Text Available The complexity of the hot deformation behaviour of the ferrite and austenite in a duplex structure is increased as compared with that of single phase ferritic or austenitic steels. Important factors are: the spatial phase distribution with respect to the direction of the imposed deformation, the codeformation of both phases having considerably different mechanical properties, and the nature of the interface between austenite and ferrite. In the present study, the influence of these factors on the crack formation during the hot deformation is analyzed.

    El comportamiento frente al conformado en caliente de la ferrita y de la austenita, en una estructura dúplex, es muy diferente al que presentan ambas fases por separado en los aceros monofásicos austeníticos o ferríticos. A ello contribuyen, entre otros, la distribución espacial de las fases con respecto a la deformación impuesta, la codeformación de dos fases, con propiedades mecánicas muy diferentes, y la naturaleza de la intercara. En el presente trabajo se analiza la influencia de estos factores en la formación de daño bajo condiciones de deformación en caliente.

  7. Comportamiento Frente a la Corrosión en Ambiente Marino de Acero Galvanizado y Acero Galvanizado Pintado (Duplex Corrosion Behaviour of Galvanized and Coated Galvanized Steel (Duplex in Marine Environment

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    R.M. Vera

    2005-01-01

    Full Text Available En este estudio se evaluó el comportamiento frente a la corrosión en medio marino de acero galvanizado y acero galvanizado pintado (Duplex haciendo uso de ensayos electroquímicos y acelerados de laboratorio. Las medidas electroquímicas consideraron potencial de corrosión a circuito abierto, curvas de polarización y polarización potenciostática en cloruro de sodio 0.1M. Los ensayos acelerados se realizaron en cámara de niebla salina y con el método Cebelcor. El grado de ataque del material se observó por microscopia electrónica de barrido. Los resultados muestran que el sistema Duplex presenta un mejor comportamiento frente la corrosión en medio de cloruros que el acero galvanizado, aumentando su durabilidad en el tiempo.This study evaluated the resistence to corrosion of galvanized and painted galvanized (Duplex steel in a marine environment using electrochemical and accelerated laboratory essays. The electrochemical measurements included open circuit potential, polarization curves, and potentiostatic polarization in 0.1M sodium chloride. The accelerated essays were carried out in a saline fog chamber and also using the Cebelcor method. The degree of corrosion attack of the material was observed by scanning electronic microscopy. The results show that the Duplex system presents a better behaviour against corrosion in chloride media than galvanized steel, increasing its useful life.

  8. Recubrimientos de aluminio-silicio realizados por deposición química de vapor en lecho fluidizado sobre el acero inoxidable AISI 316

    OpenAIRE

    José Luddey Marulanda Arevalo; Francisco Javier Pérez Trujillo; Aduljay Remolina Millán

    2013-01-01

    Los recubrimientos de aluminio-silicio fueron depositados sobre el acero inoxidable AISI 316 mediante deposición química de vapor en lecho fluidizado (CVD-FBR), en el rango de temperaturas de 540 a 560 ºC, utilizando un lecho formado por 2,5 g de silicio y 7,5 g de aluminio en polvo, y 90 g de lecho inerte (Alúmina), el cual se hizo fluidizar con Ar. Como gases activadores se usó una mezcla de HCl/H2, en relaciones de 1/10 a 1/16. Además, se varió el tiempo de deposición de los recubrimientos...

  9. Efecto de los ciclos térmicos sobre la ZAT de una soldadura multipasos de un acero inoxidable superdúplex SAF 2507 Effect of thermal cycles on the HAZ of a stainless steel multipass weld of superduplex SAF 2507

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    D. Villalobos

    2010-09-01

    Full Text Available Los ciclos térmicos de una soldadura multipasos que experimenta un acero inoxidable superdúplex SAF 2507, pueden promover la precipitación de fases secundarias reduciendo significativamente las propiedades mecánicas y la resistencia a la corrosión. Debido a su aplicación en la industria petroquímica, el estudio de las aleaciones superdúplex es de suma importancia para predecir su comportamiento en servicio cuando están involucrados procesos de soldadura por arco eléctrico. En este trabajo, se estudia el cambio microestructural de la zona afectada térmicamente correspondiente al primer cordón depositado de una unión multipasos de acero inoxidable superdúplex SAF 2507 mediante el proceso GTAW y bajo tres temperaturas de interpasos. Los resultados muestran que la temperatura de interpasos tiene una influencia sobre la precipitación de fase sigma en la zona afectada térmicamente del primer cordón depositado.Thermal cycles experienced by a superduplex stainless steel SAF 2507 when is welded, can promote the precipitation of secondary phases which decrease the mechanical properties as well as the corrosion resistance. Due to the application of the duplex alloys in the petrochemical industry, the study of these alloys has become very important in order to predict its service behavior. The aim of this work is to study the microstructural changes in the superduplex stainless steel weld joint after applying the GTAW process under three interpass temperatures after the deposition of every single pass. The results showed that slow cooling rates promoted by the deposition of the subsecuent passes and the higher interpass temperature, promote the precipitation of sigma phase in the HAZ while rapid cooling rates promoted by the lower interpass temperature do not promote the sigma phase precipitation.

  10. Formación de fase sigma en uniones soldadas de acero inoxidable súper dúplex fundido

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    Garin, J. L.

    2011-08-01

    Full Text Available This paper decribes the microstructural characteristics of weldments of cast super duplex stainless steel (J93404, being subjected to annealing processes to induce formation of sigma-phase at high temperatures. The influence of heating time at 1073 K, 1123 K and 1173 K upon precipitation of sigma in the heat affected zone, base metal and fusion zone of the weldments was analyzed. The experimental results revealed the formation of this intermetallic compound throughout decomposition of the ferritic phase into austenite and sigma. At earlier stages of the transformation the phase rapidly nucleates and growth along the ferrite-austenite grain boundaries, and then massively advances towards the bulk of the ferritic zone with greater effectiveness as temperature increases. The formation of sigma-phase in all weldments resembles the Johnson-Mehl-Avrami’s mechanism stated for nucleation and growth.

    El presente trabajo describe las características microestructurales de uniones soldadas de acero súper dúplex fundido (J93404, al ser sometidas a procesos de recocido para inducir la formación de fase sigma a altas temperaturas. Se analizó la influencia del tiempo de calentamiento a 1.073 K, 1.123 K y 1.173 K sobre la precipitación de fase sigma en la zona afectada térmicamente, metal base y zona de fusión de los conjuntos soldados. Los resultados experimentales evidenciaron la formación de este compuesto intermetálico por descomposición de la fase ferrítica en austenita y sigma. Al comienzo de la transformación la fase nuclea y crece rápidamente en los bordes de grano austenita-ferrita, extendiéndose luego masivamente hacia el seno de la zona ferrítica, con mayor efectividad en términos del aumento de la temperatura de proceso. La formación de sigma en todas las uniones soldadas obedece a un mecanismo de nucleación y crecimiento del tipo Jonson-Mehl-Avrami.

  11. Estudio de la influencia microbiológica en la corrosión de latones (UNS C68700, UNS C443 y acero inoxidable AISI 316;

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    Ohanian, Mauricio

    2014-06-01

    Full Text Available Microorganisms may play an important role in the corrosion process and generate conditions which affect the rate and/or the mechanism of deterioration. They become visible by the formation of biofilms: clusters of microorganisms and extracellular polymers. These biofilms affect not only the durability of the material, but also reduce the heat transfer. The present work studied the growth of aerobic and anaerobic heterotrophic microorganisms and sulfate reducing bacteria on aluminum brass (UNS C68700, admiralty brass (UNS C443 and stainless steel AISI 316 in exposure experiments held in the Bay of Montevideo (Uruguay. The influence of the biofilm growth on the corrosion behavior was studied by electrochemical techniques: polarization curves and Electrochemical Impedance Spectroscopy (EIS. The selection of the most suitable material for the exposure conditions is discussed and hypotheses of the corrosion mechanism are presented. Although stainless steel AISI 316 presented the lowest corrosion rate it showed localized deterioration.Los microorganismos influyen de manera significativa en el proceso corrosivo y generan condiciones que afectan la velocidad y/o el mecanismo de deterioro. Su presencia se manifiesta por la formación de bio-películas: conglomerados de bacterias y polímeros extracelulares. Dichas bio-películas afectan la durabilidad del material, la velocidad de flujo y la transferencia de calor. En el presente trabajo se evalúa el crecimiento de microorganismos heterótrofos aerobios, heterótrofos anaerobios y bacterias sulfato-reductoras sobre latón aluminio (UNS C68700, latón almirantazgo (UNS C443 y acero inoxidable AISI 316. Asimismo, se estudia la influencia del crecimiento de la bio-película sobre el comportamiento corrosivo mediante técnicas electroquímicas: curvas de polarización y espectroscopia de impedancia electroquímica. Las exposiciones se realizan en la Bahía de Montevideo, estuario del Río de la Plata

  12. CATALIZADOR ESTRUCTURADO DE Pt/Al2O3 SOBRE UNA ESPUMA DE ACERO INOXIDABLE (AISI 314 PARA LA OXIDACIÓN DE CO

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    Juan P. Bortolozzi

    2011-01-01

    Full Text Available Se obtuvo un catalizador estructurado por recubrimiento de Pt/Al2O3 sobre las paredes de una espuma de acero inoxidable AISI 314. Para estabilizar térmicamente e incrementar la rugosidad de la superficie de la espuma original se realizó un tratamiento a 900°C por 2 h. El soporte, Al2O3, y el metal activo, Pt, se incorporaron por inmersión. Las técnicas de caracterización aplicadas, XRD, LRS y SEM-EDX, permiten concluir que el tratamiento térmico previo indujo la formación de óxido de cromo y de las espinelas Mn1+xCr2-xO4-x y FeCr2O4 como fases principales en las paredes del sustrato. El espesor de la capa formada es cercano a 1 μm y los cristales producidos tienen forma octaédrica. El cubrimiento de alúmina presentó en general una apariencia homogénea, sin interacción con los óxidos formados durante el tratamiento. El Pt se distribuyó de manera uniforme, resultando un catalizador muy activo para la reacción test elegida: oxidación de monóxido de carbono.

  13. Estudio de impedancia de la corrosión del acero inoxidable AISI 316L en las regiones pasiva y de picadura

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    Polo Sanz, José Luis

    1999-12-01

    Full Text Available Impedance measurements were performed on an AISI 316L stainless steel immersed in a 5% NaCl solution at room temperature. Some samples were polarized up to the passive and pitting regions, respectively. The Nyquist plots in the rest potential and in the passive region show high impedance with capacitive behaviour. The impedance diagram in the pitting region shows three loops: a capacitive loop at high frequencies, a loop with inductive effects at intermediate frequencies, and a second capacitive response at low frequencies. To validate the impedance data Kramers-Kronig relations were applied in the pitting región.

    Se estudia la corrosión del acero inoxidable AISI 316L en solución de NaCl al 5% y a temperatura ambiente, utilizándose probetas polarizadas hasta las regiones pasiva y de picadura. Se obtuvieron diagramas de impedancia en el potencial de corrosión y en esas dos regiones. Los diagramas de impedancia en el potencial de corrosión y en la región pasiva muestran comportamiento capacitivo. En la región de picadura los diagramas de impedancia presentan tres bucles capacitivos: un bucle capacitivo a altas frecuencias, un bucle con efectos inductivos a frecuencias intermedias y un segundo bucle capacitivo a bajas frecuencias. Se aplicaron las transformadas de Kramers-Kronig a los resultados de impedancia obtenidos en la región de picadura.

  14. Passivation of duplex stainless steel in solutions simulating chloride-contaminated concrete

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    Takenouti, H.

    2007-12-01

    Full Text Available Most studies published to date on the corrosion behaviour of stainless reinforcing steel are based on austenitic steel. The market presence of corrugated duplex steel is growing, however. The present study compared passivity in 2205 type duplex and 304 type austenitic stainless steel. Polarization tests in chloride-containing Ca(OH2 solutions confirmed the exceptional performance of duplex steels. X-ray photoelectronic spectroscopy (XPS showed that the passive layer generated on duplex stainless steel in media simulating concrete pore solutions had a higher Cr content than the layer formed on steel in contact with the air. The XPS results also revealed that in duplex steel the form adopted by the passive layer Fe oxides was Fe3O4 in the solutions simulating concrete, rather than Fe2O3, as in duplex steel exposed to air. Electrochemical impedance spectroscopy (EIS can be used to monitor the transformations taking place in the passive layer and analyze the factors involved.La mayoría de los estudios publicados hasta el momento sobre el comportamiento frente a la corrosión de armaduras de acero inoxidable se basan en aceros austeníticos. Sin embargo, la presencia en el mercado de aceros corrugados dúplex es cada vez más importante. En este trabajo se analiza la pasividad de un acero inoxidable dúplex tipo 2205 en comparación con la de un inoxidable austenítico tipo 304. Los ensayos de polarización en disoluciones de Ca(OH2 con cloruros confirman el excepcional comportamiento de los aceros dúplex. La espectroscopía fotoelectrónica de rayos X (XPS informa de que la capa pasiva generada en aceros inoxidables dúplex en medios que simulan la disolución de los poros del hormigón posee mayor contenido en óxidos de Cr que la formada en aire. También se puede deducir de los resultados de XPS que los óxidos de Fe de la capa pasiva de los aceros dúplex se encuentran en forma de Fe3O4 en las disoluciones que simulan el hormigón en vez de en

  15. Some pitfalls in welding of duplex stainless steels Algumas armadilhas na soldagem de aços inoxidáveis duplex

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    Demian J. Kotecki

    2010-12-01

    Full Text Available Duplex stainless steels (DSS, including super duplex stainless steels {SDSS} have proven to be very useful engineering materials, albeit with somewhat different welding requirements than those of the more familiar austenitic stainless steels. Despite a generally good track record in welding of duplex stainless steels, certain pitfalls have been encountered with enough frequency that they deserve review. Inappropriate base metal specification often leads to unsuitable heat affected zone (HAZ properties. Autogenous fusion zones are also of concern. This issue centers around nitrogen limits. The most frequently encountered is applying the UNS S31803 composition for 2205 DSS, instead of the S32205 composition. Inappropriate welding heat input arises most frequently with SDSS. While 0.5 to 1.5 kJ/mm is a normal heat input recommendation for SDSS, either a root pass or many small beads towards the low end of this heat input range tends to result in precipitation and/or secondary austenite formation in weld metal subjected to repeated thermal cycles from multiple weld passes. Inappropriate PWHT occurs when the enhanced nickel filler metals (typically 9% Ni are used. DSS are not normally given PWHT, but extensive forming of heads, for example, or repair welding of castings, may require a postweld anneal. Specifications such as ASTM A790 and A890 call for annealing at 1040ºC minimum, and the fabricator tends to use temperatures close to that minimum. However, the enhanced nickel filler metals require higher temperatures to dissolve sigma phase that forms during heating to the annealing temperature.Aços inoxidáveis duplex (AID, incluindo os aços super duplex, AISD provaram ser materiais de engenharia muito úteis, embora com requerimentos de soldagem em alguma medida diferentes daqueles dos aços inoxidáveis austeníticos mais usuais. Apesar do histórico geralmente bom dos aços inoxidáveis duplex quanto a soldagem, algumas dificuldades têm sido

  16. Corrosión de aceros inoxidables martensíticos 13CrNiMo de bajo contenido de carbono en las industrias de gas y petróleo

    OpenAIRE

    Méndez, Claudia Marcela

    2013-01-01

    Los aceros inoxidables 13CrNiMo con bajo contenido de carbono, surgen como alternativa para el reemplazo de materiales más caros en el uso como sistemas de transporte de fluidos de las industrias de gas y petróleo, con concentraciones importantes de cloruros, pCO2, pH2S y temperatura elevadas. El bajo contenido en carbono permite salvar algunos problemas vinculados a la operación de soldadura. Con el fin de obtener una alta tenacidad, se realizan tratamientos térmicos de precalentamiento y de...

  17. Evaluación de la resistencia a la corrosión de recubrimientos de ZrOxNy sobre acero inoxidable y/o silicio mediante técnicas electroquímicas

    OpenAIRE

    Cubillos González, Gloria Ivonne

    2013-01-01

    Se hicieron crecer películas de oxinitruro de zirconio ZrOxNy sobre tres sustratos diferentes: acero inoxidable, Si (100) y vidrio, empleando tres técnicas distintas: spray pirólisis-nitruración (UPS-N), sputtering con radiofrecuencia (RF) y sputtering DC con magnetrón desbalanceado. Para cada una de ellas se optimizó las condiciones de depósito y se estudió la influencia de las mismas en las características estructurales y morfológicas del recubrimiento. Adicionalmente, se realizó la evaluac...

  18. Estudio de corrosión galvánica en pares latón/acero inoxidable y latón/fundición de hierro

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    Ohanian, M.

    2011-08-01

    Full Text Available Corrosion attack in heat exchanger systems is a topic of main interest for the maintenance in each industrial plant. These are multigalvanic systems with particular geometric and fluidodynamic complexity. Corrosive damages include zinc selective dealeation in copper alloys. In order to explain zinc dealeation attack, this paper deals with laboratory scale testing, characterization and interactions between two copper and zinc alloys (Yellow brass –UNS C268– and Admiralty brass –UNS C443– compared to AISI 316 stainless steel and cast iron. The tests were performed at 20 °C in 1.5 % NaCl and 1.5 % Na2SO4 solutions, pH 8 and each material was characterized by potentiodynamic sweeps. The couples are analyzed by studying transient galvanic currents. We conclude about the cause of the analyzed pathology, brass protection potential ranges and its coupling compatibility with other metals.

    El ataque por corrosión en los sistemas intercambiadores de calor constituye un problema para el mantenimiento de cualquier planta industrial. Se trata de sistemas multigalvánicos con particular complejidad geométrica y fluidodinámica. Las patologías corrosivas incluyen el fenómeno de dealeación selectiva de cinc en las aleaciones de cobre. A fin de explicar un caso particular de ataque por decinficación (deterioro en placa de intercambiador de calor de tubos de inoxidable, el presente trabajo aborda en ensayos a escala de laboratorio, la caracterización e interacciones entre dos aleaciones de cobre y cinc, (Yellow brass –UNS C268– y Admiralty brass –UNS C443–, respecto a acero inoxidable AISI 316 y fundición gris de hierro. Los ensayos se realizan a 20 °C en disoluciones de NaCl 1,5 % y Na2SO4 1,5 % y pH 8. Se caracterizan electroquímicamente las aleaciones y materiales involucrados mediante barridos potenciodinámicos. Los pares galvánicos formados se analizan mediante el

  19. Decapado de un acero inoxidable austenítico mediante mezclas ecológicas basadas en H2O2 - H2SO4 - iones F-

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    Narváez, L.

    2013-04-01

    Full Text Available This study reports the pickling of 316L stainless steel using mixtures of hydrogen peroxide (H2O2, sulphuric acid (H2SO4 and fluoride ions as hydrofluoric acid (HF, sodium fluoride (NaF and potassium fluoride (KF. The decomposition of H2O2 in the mixtures was assessed at different temperatures 25 °C to 60 °C, with ferric ion contents from 0 to 40 g/l. According to the results obtained, were established the optimal condition pickling at 20 g/l of ferric ions, 25 °C and p-toluensulphonic acid as stabilizer of H2O2. The HF pickling mixture was the only capable to remove totally the oxide layer from the 316L stainless steel after 300 s. The fluoride salts pickling mixtures only remove partially the oxide layer (20 to 40 % aprox. after 300 s. When the pickling time was increased until 1200 s, the removal percentages were around to 80 %.En este estudio se presenta el decapado del acero inoxidable austenítico 316L utilizando mezclas de peróxido de hidrógeno (H2O2/ácido sulfúrico (H2SO4/iones fluoruro; los iones fluoruro provienen del ácido fluorhídrico (HF, fluoruro de sodio (NaF y fluoruro de potasio (KF. La estabilidad del H2O2 fue valorada modificando las concentraciones del ión férrico de 0 a 40 g/l y las temperaturas de 25 °C a 60 °C en las mezclas decapantes. Se establecieron las condiciones óptimas de decapado utilizando 20 g/l de iones férrico a 25 °C empleando el ácido p-toluensulfónico como estabilizante del H2O2. La mezcla que contenía HF fue la única capaz de eliminar completamente los óxidos superficiales del acero a tiempos de 300 s. Las mezclas a base de sales fluoradas eliminaron parcialmente los óxidos (20 y 40 % aprox. en 300 s. Al incrementar el tiempo de decapado hasta 1200 s se obtuvieron porcentajes de eliminación alrededor de un 80 %.

  20. Decapado del acero inoxidable AISI 316L utilizando una mezcla ecológica de H2O2-H2SO4-HF

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    Gómez, P. P.

    2005-12-01

    Full Text Available This study reports the pickling of austenitic AISI 316L stainless steel (SS using a mixture of hydrogen peroxide (H2O2, sulphuric acid (H2SO4 and hydrofluoric acid (HF at pH 2.0. The stability of H2O2 was also studied using different concentrations of ferric ion from 0 to 40 g/l and temperature from 25 to 60 °C. The pickling rate at 50 °C in the presence and absence of 40 g/l ferric ion was 2.6 and 0.2 mg/dm2 day (mdd, respectively. p-Toluene sulphonic acid was used as stabilizer of H2O2.En la presente investigación se estudia el decapado del acero inoxidable AISI 316L utilizando una mezcla de agua oxigenada (H2O2 y los ácidos sulfúrico (H2SO4 y fluorhídrico (HF a pH 2,0. La estabilidad de la mezcla H2O2-H2SO4-HF se ha ensayado variando el contenido de iones férrico de O a 40 g/l y la temperatura de 25 a 60 °C. La velocidad de decapado a 50 °C ha sido de 2,6 y 0,2 mg/dm2 día (mdd, en ausencia y presencia de 40 g/l de iones férrico, respectivamente. Se ha utilizado el ácido p-toluen sulfónico como estabilizante del H2O2.

  1. Recubrimientos de aluminio-silicio realizados por deposición química de vapor en lecho fluidizado sobre el acero inoxidable AISI 316

    Directory of Open Access Journals (Sweden)

    José Luddey Marulanda Arevalo

    2013-12-01

    Full Text Available Los recubrimientos de aluminio-silicio fueron depositados sobre el acero inoxidable AISI 316 mediante deposición química de vapor en lecho fluidizado (CVD-FBR, en el rango de temperaturas de 540 a 560 ºC, utilizando un lecho formado por 2,5 g de silicio y 7,5 g de aluminio en polvo, y 90 g de lecho inerte (Alúmina, el cual se hizo fluidizar con Ar. Como gases activadores se usó una mezcla de HCl/H2, en relaciones de 1/10 a 1/16. Además, se varió el tiempo de deposición de los recubrimientos de 45 minutos a 1.5 horas, con una relación en volumen de 50% de gases activos y 50% de gases neutros. Se realizó una simulación termodinámica con la ayuda del programa informático Thermocalc, para obtener información de la posible composición y cantidad de material depositado, para las condiciones seleccionadas. En los recubrimientos se encuentran FeAl2Si, Fe2Al5 y FeAl2. Los recubrimientos aluminio-silicio fueron tratados térmicamente, para mejorar sus propiedades mecánicas y su comportamiento frente a la oxidación, por la interdifusión de los elementos de aleación, ya que el tratamiento térmico hace que el aluminio difunda hacia el substrato, y el hierro difunda hacia la superficie del recubrimiento, logrando la transformación de los compuestos anteriores en FeAl, Al2FeSi, Cr3Si, AlCrFe y AlFeNi.

  2. Recuperación de ácidos y metales en baños agotados del decapado de aceros inoxidables

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    Frías, C.

    1998-05-01

    Full Text Available During the pickling of stainless steels around 300.000 m3/year of effluents from spent baths are produced in Europe. The usual treatment of these effluents by neutralisation and slurry disposal gives important disadvantages which are necessary to solve. A new process is being developed, called PIBARE, which shows a good future market in base of a preliminary technical-economical study for a plant of 10.000 m m3/year, where a pay-back period of two years is obtained. Furthermore, other environmental advantages are produced, as free and complex acids recycling and metals recovery as commercial by-products or recycled alloys. This article shows a general review of PIBARE project and the results obtained in the laboratory step which is been developed at the moment.

    En la operación del decapado de los aceros inoxidables se producen anualmente en Europa unos 300.000 m3/año de efluentes de baños agotados. El tratamiento normal de estos efluentes mediante neutralización y depósito de los lodos generados presenta graves inconvenientes que requieren ser subsanados, para lo cual se ha comenzado a desarrollar un nuevo proceso denominado proceso PIBARE, que presenta una gran potencialidad comercial basado en el análisis técnico-económico preliminar para una planta de 10.000 m3/año, donde se obtiene un "pay back period" de unos dos años, con otras ventajas medioambientales, ya que se reciclarían los ácidos libres y complejos y se recuperarían los metales como subproductos comerciales o aleaciones reciclables. Se presenta una visión general del proyecto PIBARE y los resultados obtenidos en la etapa de laboratorio que se desarrolla actualmente.

  3. Separación selectiva de hierro y cromo de las lejías agotadas del decapado de acero inoxidable

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    Gálvez, J. L.

    2005-12-01

    Full Text Available Stainless steel spent pickling baths are very complex solutions of metals and acids (HNO3 and HF and are a very important environmental concern. Several processes have been developed for acid recovery (free and bounded acid with techniques like acid retardation, solvent extraction, evaporation and dialysis diffusion. In these processes, metallic content is precipitated and treated for its disposal. We have developed a process that permits the separation of metals by means of a selective precipitation, induced by adding free fluoride. Iron (Fe and chromium (Cr precipitate as pentafluorides and nitrogennickel (Ni remains in solution. After this stage, complex fluorides can be hydrolized with alkali to give iron and chromium hydroxides, releasing fluoride in solution

    Los baños ácidos agotados del decapado de acero inoxidable son disoluciones muy complejas debido al alto contenido de metales y ácidos (HNO3 y HF, por lo que constituyen un grave problema medioambiental. Existen tratamientos comerciales para la recuperación del ácido (libre o complejado que se basan en técnicas de retardo ácido, extracción con disolventes, evaporación o membranas. En estos procesos el contenido metálico es precipitado y tratado como un residuo. El grupo de investigación formado por los autores del presente trabajo ha desarrollado un procedimiento que permite el aprovechamiento de dichos metales mediante su recuperación selectiva con una técnica de precipitación modificada inducida por fluoruro libre. Se consigue la precipitación de hierro (Fe y cromo (Cr como pentafluoruros (pH 3-4,5 dejando el níquel en disolución. Posteriormente, los fluoruros complejos son hidrolizados con álcali dando lugar a hidróxidos de hierro y cromo, mientras que el fluoruro es redisuelto.

  4. Influencia de la composición química, del tratamiento térmico y del acabado superficial en el bioensuciamiento de aceros inoxidables austeníticos

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    Sarró, M.

    2004-02-01

    Full Text Available The main objective of this study was to analyse the biofouling processes in three kinds of stainless steels used normally in industry (UNS S30400, UNS S30403 and UNS S31600, with different surface treatments after grinding and polishing. The study was developed using two microscopy techniques. Scanning Electron Microscopy (SEM was used to evaluate the microorganisms distribution in the materials, and Epifluorescence Microscopy was used to evaluate the viability of cells in the biofilm. The results revealed the influence of the material, heat treatment, surface treatment and roughness in the biofouling processes in the stainless steel assays.

    El objetivo de este estudio es analizar el comportamiento frente al bioensuciamiento de tres aceros inoxidables austeníticos, utilizados habitualmente en la industria (UNS S30400, UNS S30403, UNS S31600, con diferentes tratamientos térmicos y acabados superficiales de lijado y pulido. Para ello, se utilizaron diferentes técnicas de microscopía. Por microscopía electrónica de barrido se evaluó la distribución de los microorganismos en la superficie del material, y por microscopía de epifluorescencia se analizó la viabilidad de los mismos. Los resultados obtenidos revelan una influencia del material, del tratamiento térmico, del acabado superficial y de la rugosidad en el bioensuciamiento de los aceros inoxidables austeníticos.

  5. Estudio de la susceptibilidad de un acero inoxidable dúplex del tipo 22Cr5NiMoN al dañado por hidrógeno en condiciones estáticas (HIC y bajo carga (SSC

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    Gutiérrez de Saiz-Solabarría, S.

    1998-05-01

    Full Text Available The behavior to hydrogen damage caused by corrosion in a H2S medium is studied in a molded ferrite- austenite (52-48 % duplex stainless steel 22Cr5NiMoN type (UNS-J9.22.05 under both, static (damaging mechanism called Hydrogen Induced Cracking (HIC and sustained load (damaging mechanism called Sulfide Stress Cracking (SSC, conditions.

    Se estudia el comportamiento de un mismo acero moldeado inoxidable dúplex austeno-ferrítico (48-52 % del tipo 22Cr5NiMoN (UNS-J9.22.05 frente al dañado por hidrógeno generado por corrosión en medio H2S, tanto en condiciones estáticas, mecanismo de dañado conocido como HIC (Hydrogen Induced Cracking, como bajo carga de tracción, mecanismo de dañado conocido como SSC (Sulfide Stress Cracking.

  6. Evolución microestructural de un acero inoxidable superdúplex bajo ciclos térmicos de corta duración Microstructural evolution of a superduplex stainless steel under short duration thermal cycles

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    Ivan Mendoza Bravo

    2010-09-01

    Full Text Available Este trabajo investiga el efecto de los ciclos térmicos sobre la microestructura de un acero inoxidable superdúplex específicamente sobre la formación de fase sigma. Los ciclos térmicos examinados son similares a los que se producen en la zona afectada térmicamente del acero inoxidable cuando se aplica el proceso de soldadura GTAW. Las temperaturas y tiempo de permanencia para el ciclo térmico se determinan usando un modelo de distribución de temperatura típico. La aplicación de los ciclos térmicos permite conocer la evolución microestructural del acero en el rango de 475ºC a 1100ºC con un tiempo corto de calentamiento y determinar la temperatura de formación y disolución de la fase sigma, pasando por su temperatura de máxima formación. Se examina la formación preferencial y la composición química de la fase sigma.This work investigates the effect of thermal cycling on the microstructure of a stainless steel superduplex, specifically on the sigma phase formation. The examined thermal cycles are similar to those produced in the heat affected zone of stainless steel when applying GTAW welding process. The temperatures and residence time for the cycle was determined using a typical thermal model of temperature distribution. The application of thermal cycles shows the microstructural evolution of steel in the range of 475ºC to 1100ºC with a short heating time and determines the temperature of formation and disolution of the sigma phase, and its maximum temperature of formation. The formation mechanism and chemical composition of the sigma phase is also examined.

  7. Efecto del nitrógeno en la atmósfera de sinterización del acero inoxidable ferrítico AISI430L P/M

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    Corpas, F. A.

    2005-04-01

    Full Text Available In this paper, we have studied the nitrogen effects different sintering atmospheres (nitrogen-hydrogen, and dissociate ammonia on ferritic stainless steels (430L, fabricated by powder metallurgy process. We have carried out a study of the physical (density, porosity and dimensional variation and mechanical properties (hardness, tensile strength, and lengthening of the ferritic stainless steels sintered in the afore-mentioned atmospheres, as well as of their behaviour in pitting corrosion. We have studied, also the microstructure of the steels, which depends on the atmosphere used for sintering

    En el presente artículo, se ha estudiado el efecto del nitrógeno presente en las diferentes atmósferas de sinterización (nitrógeno-hidrógeno y amoniaco disociado en los aceros inoxidables ferríticos (430L, fabricados mediante procedimientos pulvimetalúrgicos. Por lo cual, se ha tomado como referencia la sinterización en vacío. Se han estudiado las propiedades físicas (densidad, porosidad y variación dimensional y las propiedades mecánicas (dureza, resistencia a la tracción y alargamiento de los aceros inoxidables ferríticos sinterizados en las diferentes atmósferas, así como su comportamiento a la corrosión por picaduras. Del mismo modo, se ha estudiado la microestructura de los aceros dependiendo de la atmósfera utilizada en la sinterización

  8. Ensayos de rozamiento plano sobre aceros inoxidables austeníticos con diferente acabado superficial. Determinación de las condiciones de adhesión en el rozamiento

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    Coello, J.

    2008-12-01

    Full Text Available The main purpose of this work is to evaluate the tribological behaviour of austenic stainless steels AISI 304 with bright annealed surface finishing (BA (ASTM a 240; AISI 304 DDQ and AISI 316 with bright surface finishing (B. The assays have been carried out in flat faced dies system with mineral oil of 200 cts viscosity, S2Mo grease and in dry conditions.. The relationship between friction coefficient and pressure and velocity has been established for the mineral oil as lubricant. In these conditions, a strong adhesive tendency has been found in boundary lubrication regime. The results obtained here, show us that S2Mo grease leads to lowest values for the friction coefficient. A minor adhesive behaviour tendency for AISI 316 steel, harder than 304 grades, has been found. A relevant plowing phenomena has been observed for the more critical friction conditions tried out. A surface hardener is produced as a consequence of that.

    El objetivo de este trabajo es determinar el comportamiento tribológico de los aceros inoxidables austeníticos 304 con acabado brillante BA (ASTM A 240, 304 DDQ y 316 con acabado mate 2B, en sistemas de contacto plano, con el fin de simular el rozamiento en la zona del flanco en los procesos de embutición de acero inoxidable. Para ello, se ha estudiado la influencia del acabado superficial del acero, la velocidad de deslizamiento y la presión normal sobre el coeficiente de rozamiento, utilizando un ensayo de fricción con matrices planas. Los ensayos se han realizado con aceite mineral de 200 cst, grasa de bisulfuro de molibdeno y en seco. En presencia de aceite, se ha establecido una correlación de m con la velocidad de deslizamiento y la presión de contacto con comportamiento fuertemente adhesivo en las condiciones de lubricación límite consideradas. Los resultados obtenidos muestran que la grasa de bisulfuro de molibdeno disminuye en un 50 % los valores del coeficiente de rozamiento

  9. Análisis experimental del desgaste entre UHMWPE y acero inoxidable 316l empleados en la manufactura de prótesis coxofemorales

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    Ricardo Gustavo Rodríguez Cañizo

    2010-10-01

    Full Text Available Título en inglés: Experimental wear analysis of UHMWPE and stainless 316l used in the manufacturing of coxofemoral prosthesis. Resumen La causa más común de falla en prótesis coxofemorales es el aflojamiento entre los componentes que conforman el sistema, de manera específica la copa acetabular y la cabeza femoral. En esta investigación se presenta un análisis tribológico del desgaste en los componentes mencionados, ya que cuando las superficies en contacto se desgastan, la funcionalidad mecánica del sistema se compromete, debido al cambio de geometría de los mismos, dando como resultado un juego mecánico entre la copa y la cabeza. Los materiales considerados en este estudio son el polietileno de ultra elevado peso molecular (UHMWPE, por sus siglas en inglés para la copa acetabular, y acero inoxidable 316L para la cabeza femoral. Esta combinación de materiales representa hoy en día la recomendación más usual por parte de los cirujanos para pacientes de la tercera edad. La tasa anual de desgaste se determinó de manera experimental y se cuantificó la cantidad de material desprendido durante el contacto. Se establecieron las condiciones de carga de forma analítica, considerando las que actúan sobre la cabeza femoral a lo largo del área de desgaste durante la marcha humana. Posteriormente, se realizó el análisis experimental de desgaste utilizando una máquina tribológica de configuración perno-sobre-disco (pin-on-disk, diseñada de manera específica para este estudio. Las pruebas para determinar la pérdida volumétrica de los componentes se realizaron bajo tres condiciones de operación: en seco, lubricada con agua destilada y lubricada con suero bovino. El marco experimental considerado consistió en pernos de UHMWPE sobre discos de acero inoxidable 316L simulando el desgaste equivalente a diez años de uso de la prótesis. Finalmente, de los resultados obtenidos se puede establecer que el desgaste y la cantidad de part

  10. Low temperature plasma carburizing of AISI 316L austenitic stainless steel and AISI F51 duplex stainless steel Cementação sob plasma à baixa temperatura do aço inoxidável austenítico AISI 316L e do aço inoxidável duplex AISI F51

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    Carlos Eduardo Pinedo

    2013-06-01

    Full Text Available In this work an austenitic AISI 316L and a duplex AISI F51 (EN 1.4462 stainless steel were DC-Plasma carburized at 480ºC, using CH4 as carbon carrier gas. For the austenitic AISI 316L stainless steel, low temperature plasma carburizing induced a strong carbon supersaturation in the austenitic lattice and the formation of carbon expanded austenite (γC without any precipitation of carbides. The hardness of the carburized AISI 316L steel reached a maximum of 1000 HV due to ∼13 at% carbon supersaturation and expansion of the FCC lattice. For the duplex stainless steel AISI F51, the austenitic grains transformed to carbon expanded austenite (γC, the ferritic grains transformed to carbon expanded ferrite (αC and M23C6 type carbides precipitated in the nitrided case. Hardness of the carburized case of the F51 duplex steel reached 1600 HV due to the combined effects of austenite and ferrite lattice expansion with a fine and dispersed precipitation of M23C6 carbides.O aço inoxidável austenítico AISI 316L e o aço inoxidável duplex AISI F51 (EN 1.4462 foram cementados sob plasma-DC na temperatura de 480ºC, utilizando-se CH4 como gás de arraste. A cementação sob plasma à baixa temperatura conduziu a uma elevada supersaturação do reticulado cristalino em carbono com a formação de austenita expandida(γC, sem a precipitação de carbonetos. A dureza do aço 316L, após a cementação, atingiu um valor máximo de 1000 HV, devido à supersaturação de ∼ 13 at% de carbono e à expansão do reticulado cristalino CFC. Para o aço inoxidável duplex AISI F51, os grãos de austenita se transformaram em austenita expandida pelo carbono e os grãos de ferrita se transformaram para ferrita expandida com a precipitação de carbonetos do tipo M23C6, na camada cementada. A dureza da camada cementada, no aço F51, atingiu 1600HV, devido ao efeito combinado da expansão dos reticulados cristalinos da austenita e da ferrita com a precipitação fina e

  11. Modificación de las propiedades superficiales de aceros inoxidables Dúplex mediante recubrimientos por láser

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    Amigo, V.

    2004-12-01

    Full Text Available Laser cladding is one of the most promissing techniques to restore damaged surfaces and achieve properties similar to those of the base metal. In this work, duplex stainless steels have been cladded by a nickel alloy under different processing conditions. The influence of the beam speed and defocusing variables has been evaluated in the microstructure both of the cladding and heat affected zone, HAZ. These results have been correlated to mechanical properties by means of microhardness measurements from cladding area to base metal through the interface. This technique has shown to be very appropriate to obtain controlled mechanical properties as they are determined by the solidification microstructure, originated by the transfer of mass and heat in the system.

    La posibilidad de restaurar superficies y, con ello, las propiedades de las mismas mediante el recubrimiento por láser de polvos constituye uno de los mayores intereses en las investigaciones actuales. En este trabajo se ha obtenido un recubrimiento de una aleación base níquel, mediante el tratamiento láser de polvos elementales para diferentes condiciones de procesado. Se ha evaluado la influencia de las variables de proceso, velocidad del láser y desenfoque del haz láser en la microestructura de los recubrimientos y con ello en las propiedades finales de los mismos, así como en la transición de estas a través de la interfase y la zona afectada por el calor, ZAC, evaluada mediante perfiles de microdureza. La obtención de recubrimientos a partir de polvos resulta muy adecuada, en este caso, al obtener unas propiedades mecánicas que están determinadas por la microestructura de solidificación, originada por la transferencia de masa y calor en el sistema.

  12. Soldabilidad del acero inoxidable austenitico

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    Pedro Pablo Torres-Medina

    2002-01-01

    Full Text Available This work involves welding stainless steel AISI 321H applying technical specifications according to welding standards, know the properties and phenomena that occur in the base metal and select the appropriate input material to ensure good quality of the process.

  13. Aplicación del ensayo miniatura de embutido para la evaluación de la tenacidad a temperaturas criogénicas de aceros inoxidables austeníticos envejecidos isotérmicamente

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    Saucedo-Muñoz, M. L.

    2003-10-01

    Full Text Available Two types of austenitic stainless steels JJl and JNl were isothermally aged at temperatures from 873 to 1173 K for 10 to 1000 min in order to study the microstructural evolution and its effect on fracture toughness at cryogenic temperatures. The Charpy V-Notch (CVN and Small-Punch (SPTesting methods were conducted at 77 K to evaluate the toughness of both solution treated and aged specimens. The fracture energy at 77 K determined for both methods showed a significant decrease with aging time for both steels. A linear correlation between the fracture energies of both methods was found. The intergranular precipitation of carbides and nitrides was responsible for the fracture toughness deterioration. The scanning electron microscope fractographs showed an intergranular brittle fracture and its fraction also increased with aging time and temperature. The presence of a more abundant intergranular precipitation resulted in a more rapid decrease in fracture toughness with aging time in JNl steel due to its higher content of C and N, compared to that of JJl steel.

    Dos tipos de aceros inoxidables austeníticos, JJl y JNl, se envejecieron isotérmicamente a temperaturas entre 873 y 1.173 K por tiempos de 10 a 1.000 min, para estudiar la evolución microestructural y su efecto sobre la tenacidad a la fractura a temperaturas criogénicas. Los métodos de ensayo de impacto Charpy y el ensayo miniatura de embutido se llevaron a cabo a 77 K para evaluar la tenacidad de las muestras tratadas térmicamente. La energía de fractura determinada por ambos métodos mostró una disminución con el tiempo de envejecido para ambos aceros. Se encontró una relación lineal entre ambos valores de energía. La precipitación intergranular de carburos y nitruros fue la responsable de la pérdida de la tenacidad en las muestras envejecidas. La fractografía indicó que la fractura intergranular se incrementa con la temperatura y el tiempo de envejecido. La presencia

  14. Influência da temperatura interpasse nas propriedades do aço inoxidável duplex durante a soldagem pelo processo a arco submerso

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    Tatiana Resende Alvarez

    2014-06-01

    Full Text Available Os aços inoxidáveis duplex (AID são materiais que apresentam elevada resistência à corrosão com altos valores de resistência mecânica motivando sua utilização em diversos componentes de processo na indústria offshore. No entanto, existem grandes desafios na soldagem destes materiais em termos de produtividade e qualidade da junta produzida, tendo em vista sua ampla utilização desde componentes de pequenas espessuras, tais como umbilicais, até de grandes espessuras, como tubulações de linhas de injeção de água salgada. No que concerne a tubulações de espessuras pequenas é empregado satisfatoriamente o processo de soldagem Gas Tungsten Arc Welding (GTAW conhecido como TIG. No que diz a respeito a tubulações de paredes espessas foi implementado, recentemente, o processo automático de soldagem por arco submerso (SAW na linha de pré-montagem de tubulações, aumentando consideravelmente a produtividade das juntas produzidas. No entanto, existe uma grande demanda de tempo para a realização de um novo passe de solda, em virtude da máxima temperatura interpasse exigida ser inferior a 150ºC. Portanto, o presente trabalho apresenta os resultados da caracterização e avaliação da resistência à corrosão de uma junta soldada correspondente a uma tubulação de aço inoxidável duplex (AID UNS S31803 de 21,4 mm de espessura de parede soldada pelos processos de soldagem MIG (GMAW na raiz e arco submerso (SAW no enchimento e acabamento, empregando-se temperaturas interpasses entre 150 e 290ºC. Os resultados da caracterização das propriedades mecânicas, composição química e resistência à corrosão em diversas regiões da junta soldada foram comparadas com os obtidos para o metal de base (MB da tubulação, assim como com os valores mínimos exigidos pelas normas de projeto. Deste modo, o presente trabalho permite avaliar a influência da temperatura interpasse nas propriedades da junta em decorrência de um poss

  15. Efecto de la modificación superficial de alambres delgados de acero inoxidable AISI 302 mediante plasma electrolítico sobre sus propiedades mecánicas

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    Gallegos, A.

    2012-12-01

    Full Text Available In this work different tests using electrolytic plasma (EP on thin wires of stainless steel AISI 302 in an inert solution were performed. Tensile tests were carried out in order to measure changes in the mechanical strength of the samples; moreover, both the morphological and microstructural changes also were evaluated. It was found that after 10 s of the application of EP, the samples surface was uniformly covered by nodules-like and craters similar to those found in the melting and cooling periods of EP. The results show a significant surface grain refinement, leading to crystalline arrangements with sizes less than 200 nm and also an increase in the samples tensile strength of at least 57 % respect to steel base.

    En este trabajo se realizaron ensayos de aplicación de plasma electrolítico (PE sobre alambres delgados de acero inoxidable AISI 302 en una solución inerte. Las probetas se sometieron a ensayos de tracción, con el fin de medir cambios en su resistencia mecánica; adicionalmente fueron evaluadas en sus cambios morfológicos y microestructurales. Se encontró que después de 10 s de aplicación de PE, la superficie de las probetas estaba uniformemente cubierta por nódulos y cráteres propios del ciclo de fusión y enfriamiento del PE; se evidenció un significativo afinamiento del grano superficial, llegando a ordenamientos cristalinos de tamaño menor a 200 nm y también se observó que la capa superficial afectada presentó un incremento de la resistencia a la tracción de al menos un 57 % respecto al acero base.

  16. Efecto de las condiciones de corte de un láser de Nd:YAG sobre la estructura y microcomposición de la superficie de aceros inoxidables

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    Ramírez, A.

    1998-04-01

    Full Text Available A study is presented of the effect of laser parameters (time distribution, spatial distribution and speed on both the finishing quality of austenitic stainless steel and its microstructure. An Nd-YAG laser with nitrogen as protection gas has been used. The samples were studied by SEM, metallography and microprobe analysis. At 500 Hz and 10 % of the spatial distribution, any increase of the time distribution produces higher power; this effect allows working at higher speed. Quality increases with the cutting speed. The laser cutting of 304 stainless steel using speeds higher than 200 mm/min and power lower than 1,000 W and a nitrogen flow of 18 bar of pressure do not produce significative changes in the structure.

    Se presenta un estudio de la influencia de los parámetros de procesado láser (distribución temporal, distribución espacial y velocidad en la calidad de acabado y microestructura de aceros inoxidables austeníticos. Se ha utilizado un láser Nd:YAG con nitrógeno como gas de protección, analizándose los resultados mediante SEM, microsonda electrónica y análisis metalográfico. Para una distribución espacial fija (10 %, y una frecuencia de 500 Hz, el aumento de la distribución temporal produce mayor potencia, lo que permite trabajar a velocidades más altas. La calidad del acabado aumenta al hacerlo la velocidad de corte. El corte de acero 304 con láser a velocidades superiores a 0,0033 m/s y potencias inferiores a 1.000 W usando nitrógeno a 18 bar no produce modificaciones apreciables en la estructura.

  17. Simulación del efecto de la irradiación mediante el trabajado en frío y los tratamientos térmicos en dos aceros inoxidables austeníticos

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    de Diego, G.

    1998-10-01

    Full Text Available In the present study, annealed type 304 SS was cold worked and heat treated to simúlate irradiation hardening, ductility loss and grain boundary segregation. Constant Extension Rate Tensile (CERT tests were conducted to reproduce Irradiation Assisted Stress Corrosion Cracking (IASCC in BWR (Boiling Water Reactor environment.

    En este trabajo se simulan los efectos que produce la irradiación, pérdida de ductilidad y segregación de impurezas en borde de grano, mediante trabajado en frío y posterior tratamiento térmico, para aceros inoxidables austeníticos AISI 304. Mediante ensayos de velocidad de extensión constante y en medios similares a los de los reactores de agua en ebullición se intenta relacionar la susceptibilidad a la corrosión bajo tensión con la susceptibilidad a la corrosión asistida por irradiación.

  18. Caracterización mecánica de recubrimientos de aluminio por CVD-FBR sobre aceros inoxidables y resistencia a la oxidación en vapor de agua

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    Diego Pérez-Muñoz

    2015-09-01

    Full Text Available Los recubrimientos de aluminio depositados sobre el acero inoxidable austenítico AISI 317 por Deposición Química de Vapor en Lecho Fluidizado (CVD-FBR presentan a altas temperaturas una reducción de la velocidad de corrosión de más de 80 veces. Se realizó la caracterización mecánica de los recubrimientos por medio de microdureza, nanoindentación, para conocer cómo se vieron afectas las propiedades mecánicas (en especial la dureza y el módulo de Young del recubrimiento y del sustrato luego de ser sometidos a la oxidación a alta temperatura. También se hicieron análisis por medio de Microscopia Electrónica de Barrido (MEB, para observar los cambios microestructurales, y de Microscopia de Fuerza Atómica (MFA, para observar cómo varía la topografía y el gradiente de rugosidad en función de la distancia recorrida por la punta del cantiléver durante los barridos.

  19. Influencia del material de aporte en la resistencia a corrosión por picadura en uniones soldadas de un acero inoxidable dúplex 2205

    OpenAIRE

    Múnez, C. J.; Utrilla, M. V.; UreÑa, A.; Otero, E.

    2007-01-01

    In this work, it has been studied the pitting corrosion resistance of welding duplex stainless steel 2205. Unions were made by GMAW process with different fillers: duplex ER 2209 and two austenitic (ER 316LSi and ER 308LSi). The microstructure obtained with the duplex ER 2209 filler is similar to the duplex 2205 base material, but the unions produced with the austenitic fillers cause a decrease of the phases relation a/g. To evaluate the influence of the filler on the weld, the pitting corros...

  20. “MEDICION DE PARAMETROS GENERADORES DE ESFUERZOS RESIDUALES DURANTE EL PROCESO DE SOLDADURA DE ACERO INOXIDABLE AUSTENITICO AISI 304L”.

    OpenAIRE

    García López, Christian Jesus

    2012-01-01

    En la actualidad los procesos de soldadura por arco eléctrico se han convertido en la técnica por excelencia para la unión del acero y sus aleaciones. Se puede mencionar que la importancia de la soldadura, es tal, que sin ella no serían posibles muchos de los productos y servicios que cotidianamente son consumidos o requeridos por las sociedades contemporáneas actuales. Cada vez con mayor longitud y diámetro se instalan líneas de tubería para la distribución y conducción de tod...

  1. Desarrollo de un modelo matemático de diferencias finitas para el análisis del campo de temperaturas en la soldadura por arco de chapas finas de acero inoxidable

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    Miguel, V.

    2010-12-01

    Full Text Available This work develops a finite difference method to evaluate the temperature field in the heat affected zone in butt welding applied to AISI 304 stainless steel thin sheet by GTAWprocess. A computer program has been developed and implemented by Visual Basic for Applications (VBA in MS-Excel spreadsheet. The results that are obtained using the numerical application foresee the thermal behaviour of arc welding processes. An experimental methodology has been developed to validate the mathematical model that allows to measure the temperature in several points close to the weld bead. The methodology is applied to a stainless steel sheet with a thickness lower than 3 mm, although may be used for other steels and welding processes as MIG/MAG and SMAW. The data which has been obtained from the experimental procedure have been used to validate the results that have been calculated by the finite differences numerical method. The mathematical model adjustment has been carried out taking into account the experimental results. The differences found between the experimental and theoretical approaches are due to the convection and radiation heat losses, which have not been considered in the simulation model.With this simple model, the designer will be able to calculate the thermal cycles that take place in the process as well as to predict the temperature field in the proximity of the weld bead.

    En este trabajo se desarrolla un método de diferencias finitas para calcular el campo de temperaturas en la zona afectada por el calor en la soldadura de dos chapas de acero inoxidable AISI 304, soldadas mediante el procedimiento GTAW. Se ha desarrollado un programa informático implementado en libros de cálculo MS-Excel con Visual Basic para Aplicaciones (VBA. Los experimentos modelizados a través de la aplicación numérica predicen el comportamiento térmico de un procedimiento de soldadura. Para la validación del modelo matemático se ha desarrollado un

  2. Efecto de la velocidad y ángulo de impacto en la resistencia a corrosión - erosión de aceros inoxidables recubiertos con TiN

    Directory of Open Access Journals (Sweden)

    José Ricardo Cano Rodas

    2004-01-01

    Full Text Available Fueron estudiados los mecanismos de degradación superficial en aceros inoxidables austenítico AISI 304 y martensítico AISI 420, con y sin recubrimiento cerámico de TiN, aplicado mediante técnica de deposición física de vapor PVD por arco pulsado, sometidos a erosión (solución de agua destilada con 30% en peso de partículas de sílice, corrosión (solución ½ M H2SO4 + 3.5% NaCl y efectos sinérgicos corrosión - erosión. Fue construido un dispositivo para realizar los ensayos descritos con la posibilidad de variar la velocidad y el ángulo medio de impacto de las partículas sobre la superficie de las muestras. Marcas características fueron observadas en las superficies desgastadas, siendo la condición de ángulo rasante la de mayor efecto nocivo tanto para las superficies desnudas como para las recubiertas con TiN. El nivel de deterioro superficial aumentó con la velocidad de impacto, al tiempo que se evidenció la importancia de la adherencia de las películas protectoras al substrato para la obtención de una buena resistencia a corrosiónerosión. La sinergia corrosión-erosión presentó, en algunas ocasiones, un efecto positivo para la superficie, ya que el impacto de las partículas duras causó intensa deformación plástica pero no consiguió remover material de la superficie.

  3. Relaciones cuantitativas entre los contenidos de azufre y de sulfuros en los aceros inoxidables tipo AISI 303: influencia de la composición química de los sulfuros

    Directory of Open Access Journals (Sweden)

    Botella, J.

    1999-06-01

    Full Text Available The work has been done with ten AISI 303 stainless steel rods which have similar chemical compositions, except for sulphur which varies between 0.25 and 0.36%. These steels are studied by Scanning Electron Microscopy (SEM and Energy Dispersive X-Ray Spectrometry (EDX. The sulphides are chemically microanalysed and the occupied volume determined by automatic image analysis. It can be inferred that the chemical composition of sulphides in AISI 303 steels is variable to some extent even though the steel chemistry is almost invariable. This could mean that solidification conditions and thermomechanical transformations are able to affect resulting in variations of sulphide compositions. Quantitative relations between sulphur and sulphide contents are established and the influence of sulphide chemical compositions on those relations is studied. The experimental results are compared with those obtained from theoretical calculations. A good approach is obtained when the difference between chemical compositions of real sulphides and the theoretical one, MnS, is taken into account.

    Se trabaja con una serie de diez redondos de aceros inoxidables tipo AISI 303 de composiciones químicas prácticamente iguales a excepción del azufre que varía entre 0,25 y 0,36%. Se examinan los aceros mediante Microscopía Electrónica de Barrido (MEB y Espectrometría de Dispersión de Energías de Rayos X (EDX acoplada al MEB, analizándose químicamente los sulfuros y determinando, mediante análisis automático de imágenes, los volúmenes ocupados por los sulfuros. Parece deducible que la composición química de los sulfuros en el AISI 303 puede ser discretamente variable aún siendo prácticamente invariable la composición química del acero. Ello podría significar que las condiciones de solidificación y las transformaciones termomecánicas pueden influir, dando como resultado variaciones en la composición química de los sulfuros. Se establecen

  4. Análisis del Comportamiento Mecánico de Recargues de Inoxidable Sobre Acero de Baja Aleación en Reactores de Proceso Analysis of Mechanical Behavior of Cladding of Stainless Steel over Low Alloyed Steel in Process Reactors

    Directory of Open Access Journals (Sweden)

    B.Y. Moratilla

    2005-01-01

    Full Text Available Se realiza un estudio simple de tensiones considerando dos materiales, acero inoxidable y acero de baja aleación. El estudio es motivado porque en la industria petroquímica es práctica habitual, para reducir costes de materiales, utilizar recargues de inoxidable sobre una pared de acero de baja aleación para la construcción de la pared de reactores. Se determina el coeficiente de dilatación térmica y su evolución a lo largo del espesor de la zona afectada térmicamente, usando una probeta extraída durante la construcción de un reactor. Luego se aplican los resultados obtenidos a un modelo de la pared del reactor usando el método de los elementos finitos. Los resultados muestran que el uso del recargue está científica y tecnológicamente justificado.A simple study of tensions was carried out on stainless steel and low alloyed steel. The reason for the study was that a typical practice in the petrochemical industry for materials cost reduction is the use of layers of stainless steel cladding over low alloy steel in the construction of reactor walls. The coefficient of thermal dilatation and its' evolution throughout the thickness of the thermally affected zone was determined using a test sample obtained during the construction of a reactor. Later, the results obtained were applied to a model of the reactor wall using the finite element method. The results suggested that the use of the cladding was scientifically and technologically justified.

  5. Efecto del nitrógeno y la corriente media pulsada de soldadura en la formación de grietas de solidificación en aceros inoxidables AI5I 316L

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    Trevisan, R. E.

    2002-08-01

    Full Text Available An analysis of the influence of nitrogen concentration in the weld zone and the pulsed mean welding current in the solidification crack formation is presented in this paper. The AISI 316L austenitic stainless steel was employed as the metal base. The welding was done using CC+ pulsed flux cored arc welding process and AWS E316LT-1 wire type. The tests were conducted using CO2 shielding gas with four different nitrogen levels (0, 5, 10 and 15 % in order to induce different nitrogen weld metal concentrations. The pulsed mean welding current was varied in three levels and the Transvarestraint tangential strain test was fixed of 5 %. The results showed that the solidification cracking decreased as the pulsed mean welding current increase. It was also verified that an increase of the weld zone nitrogen level was associated with a decrease in both the total length of solidification crack and the amount of δ ferrite.

    En este trabajo se expone un análisis de la influencia de la concentración de nitrógeno y de la corriente media pulsada de soldadura en la formación de grietas de solidificación. Como metal base se usó el acero inoxidable austenítico AISI 316L. Las soldaduras se realizaron con el proceso de almbre tubular con pulsación del arco en CC+ y metal de aporte del tipo AWS E316LT-1. Se usó CO2 como gas de protección, añadiéndole cuatro diferentes porcentajes de nitrógeno 0, 5, 10 y 15 %, para inducir diferentes concentraciones de este elemento en la zona fundida. La corriente media de pulso se varió en tres niveles. La deformación tangencial de las probetas se mantuvo constante en 5 %, empleando el ensayo Transvarestraint. Los resultados indican que la longitud total de las grietas de solidificación es inversamente proporcional al aumento de la corriente media de pulso, comprobándose, además, que el incremento del nivel de nitrógeno en la zona fundida provocó una disminución en las grietas de

  6. Efecto de la adición de cobre y estaño en el comportamiento a la corrosión por picadura del acero inoxidable AISI 304

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    Pardo, A.

    2004-10-01

    Full Text Available The influence of copper and tin addition on the pitting corrosion resistance of AISI 304 stainless steel in 3.5 % NaCl at 20 °C has been studied using potenciodinamic and cyclic polarization. From that study the effect of alloying elements (Cu and Sn in the corrosion, pitting and repassivation potentials were determined. The effect of copper and tin on the critical pitting temperature (CPT was determined by icon-time-temperature curves. The influence of these alloying elements in FeCl3 under ASTM G48-00 norm was also studied. The addition of copper favours the nucleation of pits. The addition of tin slightly improves the corrosion resistance. The synergic effect of Cu-Sn was positive at low concentrations.

    Se estudia la influencia de la adición de cobre y estaño en la resistencia a la corrosión por picadura del acero inoxidable AISI 304, en 3,5 % NaCl a 20 °C mediante medidas potenciodinámicas de polarización cíclica, con el fin de determinar el efecto de la adición de aleantes (cobre y estaño en los potenciales de corrosión, picadura y repasivación. Se ha determinado el efecto del cobre y estaño en la temperatura crítica de picadura mediante el trazado de curvas icon-tiempo. Asimismo se estudió la influencia de estos aleantes en FeCl3, según norma ASTM 048-00. La adición de cobre favorece la nucleación de picaduras. La adición de estaño presenta una tendencia a mejorar la resistencia a la corrosión. El efecto sinérgico Cu-Sn es positivo en bajas concentraciones.

  7. Estudio de corrosión bajo tensión en los aceros inoxidables 17-4PH y 17-7PH en presencia de NaCl y NaOH (20 % a 90 °C

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    Gaona-Tiburcio, Citlalli

    2000-04-01

    Full Text Available One of the problems that affects to the electric industry is the not programmed stoppages in the power plants, due to the failure of any main component: boiler, turbine and generator. In the turbine, the combined action of a corrosive agent (humid polluted vapor and a mechanical effort generally will result in Stress Corrosion Cracking (SCC. In this work the SCC susceptibility of the precipitation hardening stainless steels 17-4PH and 17- 7PH, thoroughly used in steam turbine blades of power stations is analyzed. The specimens were tested in the presence of NaCl and NaOH (20 % to 90 °C and different pH. The CERT test (Constant Extension Rate Test was used, at 10-6 s-1 supplementing it with electrochemical noise; the aim was to identify the conditions of maximum susceptibility and the performance of the studied materials. The fractographic analysis revealed ductile and brittle fracture. Intergranular crackings, characteristic of the anodic dissolution mechanism of the material was observed. Nevertheless, the main mechanism responsible the failure was hydrogen embrittlement.

    Uno de los problemas que afecta a la industria eléctrica es el de los paros no programados en las plantas generadoras de electricidad, debidos al fallo de algún componente principal: caldera, turbina y generador. En la turbina, la acción combinada de un agente corrosivo (vapor húmedo contaminado y un esfuerzo mecánico, generalmente provocará corrosión bajo tensión (CBT. En este trabajo se analiza la susceptibilidad a la CBT de los aceros inoxidables, endurecibles por precipitación, 17-4PH y 17-7PH, ampliamente usados en alabes de turbina de vapor de centrales termoeléctricas. Las muestras se ensayaron en presencia de NaCl y NaOH (20 % a 90 °C, y distintos valores de pH. Se empleó el ensayo CERT (Constant Extensión Rate Test, a velocidades de 10-6 s-1, complementándolo con ruido electroquímico, buscando

  8. Estudo da soldagem de tubos de aço inoxidável duplex e superduplex na posição 5G Study of the welding of duplex and superduplex stainless steel pipes in the 5G position

    OpenAIRE

    Pedro Ivo Guimarães de Vasconcellos; Ruben Rosenthal; Ronaldo Pinheiro da Rocha Paranhos

    2010-01-01

    Os aços inoxidáveis duplex e superduplex possuem uma microestrutura austeno-ferrítica com fração média de cada fase de cerca 50%. A microestrutura duplex é responsável pelas excelentes propriedades mecânicas, especialmente o limite de escoamento e a tenacidade, e pela elevada resistência a corrosão por pites e sob tensão em meios contendo cloretos. A soldagem destes aços é frequentemente uma operação crítica. Neste trabalho, um tubo de superduplex SAF 2207 foi soldado pelo processo TIG (GTAW)...

  9. Avaliação da soldagem multipasse de chapas espessas de aços inoxidáveis lean duplex UNS S32304 soldadas pelos processos SMAW, GMAW e FCAW: parte 1: propriedades mecânicas Evaluation of multipass welding of thick lean duplex stainless steel UNS S32304 plates welded by SMAW, GMAW and FCAW: part 1: Mechanical Properties

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    Ronaldo Cardoso Junior

    2012-12-01

    Full Text Available Os aços inoxidáveis duplex (AID vêm se apresentando como uma excelente alternativa para aplicações em que alta resistência à corrosão e alta resistência mecânica são requeridas. Contudo, os AID, incluindo os aços inoxidáveis lean duplex, apresentam soldabilidade inferior em relação aos aços inoxidáveis austeníticos. Nesse sentido, esse trabalho tem como objetivo a avaliação da soldagem multipasse de chapas 22 mm de espessura da liga inoxidável lean duplex UNS S32304, utilizando-se os processo SMAW, GMAW e FCAW e consumíveis com dois tipos de composição química, 22%Cr9%Ni3%Mo e 23%Cr7%Ni, totalizando seis experimentos. Foram empregados chanfros em V com 60º e suporte cerâmico para soldagem do passe de raiz, sendo que o aporte térmico foi mantido praticamente constante em 1,6 kJ.mm-1. Determinou-se os tempos de soldagem e a seqüência de passes, objetivando uma análise de produtividade, em seguida as juntas soldadas foram submetidas à END por raios x. Foram extraídos corpos de prova para ensaios de tração, dobramento, Charpy a -30 ºC e microdureza. A produtividade dos processos semi-automáticos se mostrou pelo menos 63 % maior que a do processo SMAW, enquanto o processo FCAW se mostrou de 6 a 18% mais rápido que o GMAW. Foram encontradas descontinuidades (porosidade consideradas aceitáveis segundo ASME B31.3 em alguns dos experimentos, que não influenciaram negativamente os resultados mecânicos, os quais se apresentaram acima requerimento do metal de base e especificado por normas de fabricação.The duplex stainless steels (DSS's have been placed as an excellent alternative for applications where high corrosion resistance and high mechanical strength are required. However, DSS's, including the lean duplex, present lower weldability than the austenitic stainless steels. Thus, this study aims to evaluate the multipass welding of 22 mm plates of lean duplex stainless steel alloy UNS S32304, using the process

  10. Análisis de la deformabilidad del acero inoxidable AISI 304 DDQ en condiciones multiaxiales de embutición. Evaluación de la influencia de la acritud inicial

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    Ferrer, C.

    2010-10-01

    ón-compresión biaxial existentes en la zona del ala de un proceso de embutición profunda. El material estudiado es acero inoxidable AISI 304 con calidad de embutición. También se establece la influencia existente para estados de acritud inicial diferentes, laminación y tracción biaxial. Los resultados obtenidos permiten establecer la validez del ensayo realizado desde el punto de vista de la deformación que impone al material. También, se demuestra el efecto predominante de la acritud inicial del material frente al provocado en condiciones multiaxiales de embutición y se establece la variación del coeficiente de anisotropía del material con la deformación de embutición para la dirección coincidente con la de laminación del material.

  11. Caracterización mediante la técnica EBSD de la deformación de chapa de acero inoxidable AISI 304 DDQ bajo tensiones multiaxiales típicas de la embutición

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    Coello, J.

    2009-10-01

    Full Text Available The main aim of this work is to evaluate AISI 304 DDQ stainless steel behaviour under deep drawing deformation condition, that is, pure shear deformation in which material suffers a typical deformation under tension-biaxial compression stresses system. The microestructural evolution has been investigated by optical microscopy and by EBSD technique. The success of the EBSD analysis has been established for the deformation conditions experimented here. It has been determined the rolling direction and the equivalent strain influence on the crystallographic orientation maps, misorientation diagrams and poles figures. The results let the authors say the low angle misorientations corresponding to 0, 45 and 90° rolling directions have an inverse correlation with the material anisotropy. Initial prestraining has been considered also and the analysis of this aspects lead to establish that the increment of the intragranular misorientations with the strain depends on the initial state of the steel; this increment is observed to be minor for samples with initial prestraining. High angle misorientation analysis (>15° indicates that the grain boundaries character distributions depends on the deformation.

    El objetivo de este trabajo es evaluar el comportamiento del acero inoxidable AISI 304 DDQ durante un proceso de deformación típico del conformado de chapa por embutición, tracción-compresión biaxial (T-CC, determinando la evolución microestructural mediante microscopía óptica y EBSD. Se ha establecido la validez del análisis efectuado por EBSD para las condiciones de deformación consideradas en este trabajo. Se ha analizado la influencia de la dirección de laminación y de la deformación equivalente sobre los mapas de orientación cristalina, diagramas de desorientación y figuras de polos inversa, determinando que las desorientaciones de ángulo bajo obtenidas en muestras deformadas a 0°, 45°, y 90° respecto a la dirección de

  12. Estudo dos efeitos da restrição na microestrutura, microdureza e tenacidade em juntas soldadas em aço inoxidável duplex Study of restriction effects on mMicrostructure, microhardness and toughness in welded joints of duplex stainless steel

    OpenAIRE

    Everton Barbosa Nunes; Marcelo Ferreira Motta; Hamilton Ferreira Gomes de Abreu; Jesualdo Pereira Farias; Hélio Cordeiro de Miranda; Francisco Necy Alves Junior

    2011-01-01

    Os aços inoxidáveis duplex (AID) apresentam em sua microestrutura ferrita e austenita, de modo a aliar boas propriedades mecânicas e resistência à corrosão. Estes materiais possuem grande aplicação na indústria petroquímica, sendo o UNS S31803 um dos mais conhecidos. Existem poucos trabalhos referentes ao estudo da influência da restrição na soldagem da junta na formação de Widmanstätten. Logo, este trabalho tem como objetivo analisar a influência da restrição no balanceamento de fases, na mo...

  13. Development of UNS S 32760 super-duplex stainless steel produced in large diameter rolled bars Desenvolvimento do aço inoxidável super-duplex UNS S 32760 produzido em barras laminadas de grande diâmetro

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    Celso Antonio Barbosa

    2013-06-01

    Full Text Available Nowadays super-duplex stainless is an important material for the Oil and Gas industries, especially for off-shore production. In deep water exploitation the reliability of production system is very important. Corrosion resistance for pitting of the high alloyed duplex stainless steels with high Mo and N content has to be achieved even in large diameters bars. Therefore, the present work deals with an improved super-duplex stainless steel for the production of large diameter rolled 6bars up to 152.40 mm (6 inches. Among the main improvements, the corrosion resistance evaluated both by the chemical method according to the ASTM G-48 method, as well as electrochemical methods, was achieved. During the production of such large dimensions, the precipitation of inter-metallics and nitrides after cooling from high temperatures was studied by changing the chemical composition using Thermo-Calc and evaluating the new proposed chemical compositions. Several alloy compositions were laboratory scale cast, and the austenite/ferrite balance as well as PREN pitting resistance equivalent number content was correlated to the microstructure and the corrosion properties obtained. It was thus possible to determine the ideal chemical composition and define the new processing parameters to produce the UNS S32760 grade (4501 according to the Norsok standard. The new material properties produced in a production full scale heat are also presented.Os aços inoxidáveis superduplex, atualmente, são materiais importantes para a indústria de óleo e gás, especialmente para produção off-shore. Em águas profundas, a confiabilidade do sistema de produção é muito importante. A resistência à corrosão dos aços inoxidáveis duplex de alta liga com alto teor de Mo e N, especialmente em relação à corrosão por pite, tem de ser alcançada, até mesmo em barras com grandes diâmetros. Portanto o presente trabalho trata de um aço inoxidável superduplex com propriedades

  14. Evaluación del comportamiento mecánico, estructural y frente a la corrosión, de una nueva armadura de acero inoxidable dúplex bajo en níquel

    OpenAIRE

    Medina Sanchez, Eduardo

    2012-01-01

    La durabilidad de las estructuras de hormigón armado no es ilimitada, en especial en determinados ambientes. El ingreso de agentes agresivos en el hormigón, fundamentalmente dióxido de carbono e iones cloruros, rebasando el espesor del recubrimiento y alcanzando las armaduras, reducen el alto pH del hormigón hasta alcanzar un umbral crítico, por debajo del cual, el acero queda despasivado. Posteriormente, si existe el suficiente aporte de humedad y oxígeno, el acero se corroe, lo que supone d...

  15. Estudo da soldagem de tubos de aço inoxidável duplex e superduplex na posição 5G Study of the welding of duplex and superduplex stainless steel pipes in the 5G position

    Directory of Open Access Journals (Sweden)

    Pedro Ivo Guimarães de Vasconcellos

    2010-09-01

    Full Text Available Os aços inoxidáveis duplex e superduplex possuem uma microestrutura austeno-ferrítica com fração média de cada fase de cerca 50%. A microestrutura duplex é responsável pelas excelentes propriedades mecânicas, especialmente o limite de escoamento e a tenacidade, e pela elevada resistência a corrosão por pites e sob tensão em meios contendo cloretos. A soldagem destes aços é frequentemente uma operação crítica. Neste trabalho, um tubo de superduplex SAF 2207 foi soldado pelo processo TIG (GTAW no passe de raiz e eletrodo revestido (SMAW nos passes de enchimento, e um tubo de duplex SAF 2205 foi todo soldado pelo processo GTAW. A microestrutura do metal base, zona afetada termicamente (ZTA e metal de solda foi caracterizada e quantificada. As propriedades de tenacidade, resistência a corrosão e composição química foram avaliadas e correlacionadas. Os valores de tenacidade ao impacto Charpy-V foram considerados adequados. Não foi observada a precipitação de intermetálicos, carbonetos e nitretos. O melhor resultado no teste de corrosão da junta soldada de aço inox superduplex, comparado ao duplex, foi atribuído ao baixo teor de ferrita delta na solda e ZTA, e composição química da solda enriquecida em Cr, Mo, W e N.The duplex and superduplex stainless steels have an austenitic-ferritic microstructure with an average fraction of each phase of approximately 50%. This duplex microstructure is responsible for the excellent mechanical properties, specially the yield strength and toughness, and for the improved pitting and stress corrosion cracking resistance in chloride environments. Welding of these steels is often a critical operation. In this work, a superduplex stainless steel SAF 2507 pipe was welded by the GTAW process in the root pass and by SMAW process on filler passes, and one pipe of duplex SAF 2205 was entirely welded by the GTAW process. The microstructure of the base metal, heat affected zone (HAZ and weld

  16. Microstructure evaluation of UNS S32205 duplex stainless steel friction stir welds Avaliação microestrutural de juntas soldadas por atrito com pino não-consumível do aço inoxidável duplex UNS S32205

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    Tiago F. A. Santos

    2013-06-01

    Full Text Available UNS S32205 duplex stainless steel welds were performed by friction stir welding (FSW. Advancing and retreating sides showed distinct characteristics in the welded joint. The advancing side shows the strongest grain refinement which is corroborated by microhardness measurements. The microstructure characterization was carried out by optical, scanning and transmission electron microscopy. The thermomechanically affected zone displays austenite islands deformed in a ferrite matrix. The stir zone (SZ showed a fine recrystallized microstructure providing an outstanding increase of hardness associated with better corrosion performance. Transmission electron microscopy and corrosion tests have corroborated the absence of intermetallic phases on welded joints.Juntas soldadas por atrito com pino foram obtidas para o aço inoxidável duplex UNS S32205. Os lados de avanço e retrocesso da junta soldada evidenciaram diferentes características microestruturais, o lado de avanço apresentou um maior grau de refinamento de grãos, principal mecanismo de aumento de dureza. A caracterização microestrutural foi realizada através de microscopia ótica, eletrônica de varredura e de transmissão. A zona termomecanicamente afetada apresentou ilhas de austenita deformadas em matriz ferrítica. A zona misturada apresentou uma microestrutura fina completamente recristalizada, permitindo um impressionante aumento de dureza, na junta soldada associado a uma melhoria na resistência à corrosão. Avaliações por microscopia eletrônica de transmissão e ensaios de corrosão corroboraram para a ausência de fases secundárias deletérias na junta soldada.

  17. Estudio in vitro de la citotoxicidad y genotoxicidad de los productos liberados del acero inoxidable 316L con recubrimientos cerámicos bioactivos Cytotoxic and genotoxic study of in Vitro released products of stainless Steel 316l with bioactive ceramic Coatings

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    María Elena Márquez Fernández

    2007-03-01

    Full Text Available El acero inoxidable AISI 316L es el biomaterial mas utilizado para la fabricación de implantes temporales, pero presenta limitaciones para implantes permanentes debido a la liberación de iones metálicos hacia los tejidos circundantes, produciendo especies reactivas de oxígeno (ERO y daño en ADN, factores que aumentan el riesgo de aparición de tumores locales y fallas mecánicas del implante. Una estrategia utilizada para disminuir la liberación de iones es la modificación superficial de los implantes metálicos por medio de recubrimientos inorgánicos, cerámicos o vítreos, aplicados por el método sol-gel, el cual presenta una serie de ventajas comparativas con otras técnicas de deposición, como buena adherencia, aplicación sencilla, mínimos problemas de secado, bajas temperaturas de densificación y posibilidad de agregar partículas y/o grupos orgánicos que mejoran la adherencia celular al implante aumentando su biocompatibilidad. En el presente trabajo se evaluaron los efectos citotóxico por medio de la técnica MTT, y genotóxico por electroforesis en gel de células individuales (Ensayo Cometa, sobre células de la línea celular CHO, de los productos liberados en medio MEM por el acero inoxidable 316L sin recubrir, recubierto con una monocapa de vidrio de sílice (MC, o con doble capa que contiene partículas bioactivas de hidroxiapatita (HA, vidrio (V o vitrocerámico (VC, después de un periodo de 30 días. Los resultados muestran que a los 30 días de envejecimiento en medio MEM no se encuentra ningún efecto citotóxico, pero se encontró efecto genotóxico en las probetas de A y MC que no representa un peligro inminente a sistemas celulares. The stainless steel AISI 316L is the must used biomaterial for the making of temporal prosthesis, but it presents severe limitations for permanent implants due to the generation and migration of metallic ions to the surrounding peripheral tissues, which produces oxygen reactive

  18. Characterization of gold and nickel coating on AISI 304 stainless steel for use in the fabrication of current collector plates for fuel cells; Caracterizacion de recubrimientos de oro y niquel realizados sobre acero inoxidable AISI 304 para su empleo en la fabricacion de placas colectoras de corriente para celdas de combustible

    Energy Technology Data Exchange (ETDEWEB)

    Flores Hernandez, J. Roberto [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)] e-mail: jrflores@iie.org.mx; Aguilar Gama, M. Tulio [UNAM. Facultad de Quimica, Mexico D.F. (Mexico); Cano Castillo, Ulises; Albarran, Lorena [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico); Olvera, J. Carlos; Orozco, German [CIDETEQ, Pedro Escobedo, Queretaro (Mexico)

    2009-09-15

    Among the different components that compose fuel cell technology (MEA, bipolar plates, seals, etc.) current collector plates play an important role in the good performance of fuel cells, since they collect all of the current generated and distribute it to the external circuit. Therefore, the most important properties that the current collector plates should have are excellent conductivity and good resistance to the corrosive conditions present in the fuel cell. This document presents results obtained during the nickel and gold electrodeposition process on AISI 304 stainless steel and the morphology and thickness of each coating, their adhesion, hardness and conductivity values. Finally, results obtained during some of the electrochemical tests performed on the coatings are shown. [Spanish] De los diferentes componentes que integran la tecnologia de celdas de combustible (MEA's, placas bipolares, sellos, etc.), las placas colectoras de corriente tienen un importante rol en el buen desempeno de la celdas de combustibles, ya que en estas placas se colecta toda la corriente generada y se distribuye al circuito externo. Debido a esto, las propiedades mas importantes que deben tener las placas colectaras de corriente son: excelente conductividad y buena resistencia a las condiciones corrosivas presentes en la celda de combustible. En este documento se presentan los resultados obtenidos en el proceso de electrodeposicion de niquel y oro sobre acero inoxidable AISI 304, asi como la morfologia y el espesor de cada recubrimiento, sus valores de adherencia, dureza y conductividad. Finalmente se muestran tambien los resultados obtenidos de algunas pruebas electroquimicas a los que fueron sometidos los recubrimientos.

  19. Characterization of the hot cracking resistance using the Essential Work of Fracture (EWF: application to duplex stainless steels Caracterização da resistência ao trincamento a quente com base nos trabalhos esssenciais de mecânica da fratura: aplicação aos aços inoxidáveis duplex

    Directory of Open Access Journals (Sweden)

    Guilhem Martin

    2013-06-01

    Full Text Available Duplex stainless steels (DSS involve two ductile phases, i.e. ferrite and austenite, with a proportion of each phase around 50%. The main advantage in comparison with other austenitic and ferritic stainless steels is the excellent combination of high strength and corrosion resistance together with good formability and weldability. Unfortunately, DSS present in general a poor hot workability. Standard hot ductility tests like hot tensile or hot torsion tests are always helpful to compare the fracture resistance of two very ductile materials. A new method based on the essential work of fracture (EWF concept has been used in order to determine the hot cracking resistance. The EWF concept was introduced to address ductile fracture based on the entire load-displacement response up to the complete fracture of a specimen and not from the initiation measurements such as in classical fracture mechanics concepts. The aim of the method consists in separating, based on dimensional considerations, the work performed within the plastic zone from the total work of fracture in order to provide an estimate of the work spent per unit area within the fracture process zone to break the material. This method proved to be very well adapted to high temperature cracking. Two different duplex stainless steels have been characterized by the essential work of fracture method. Examination of the fracture micrographs and profiles match the EWF results. This method turns out to be a discriminating tool for quantifying hot cracking and to generate a physically relevant fracture index to guide the optimization of microstructures towards successful forming operations.Aços inoxidáveis duplex (AID envolvem duas fases dúcteis, isto é, ferrita e austenita, com uma proporção de cada fase de cerca de 50%. A principal vantagem, em comparação com outros austeníticos e aços inoxidáveis ferríticos, é a excelente combinação de alta resistência mecânica e resistência

  20. Caracterização e avaliação da resistência à corrosão na soldagem de tubulação de aço inoxidável duplex UNS S31803 pelo processo a arco submerso Characterization and evaluation of corrosion resistance of welded joint of duplex stainless steel pipe UNS S31803 by submerged arc process

    OpenAIRE

    Juan Manuel Pardal; Guttemberg C. de Souza; Sérgio Souto Maior Tavares; Maria da P. Cindra Fonseca; Miguel L. Ribeiro Ferreira; Leandro M. Martins; Omar A. Samra Filho

    2011-01-01

    O presente trabalho apresenta os resultados da caracterização e avaliação da resistência à corrosão de uma junta soldada correspondente a uma tubulação de aço inoxidável duplex (AID) UNS S31803 de 35 mm de espessura de parede soldada pelos processos de soldagem TIG (GTAW) na raiz e arco submerso (SAW) no enchimento e acabamento. Foram empregados como consumíveis de soldagem metais de adição de liga 25Cr-9Ni-4Mo (% em peso). Os resultados da caracterização das propriedades mecânicas, composiçã...

  1. Avaliação da proporção de fases em juntas soldadas de tubulações de aço inoxidável duplex mediante aplicação de ensaios não destrutivos Evaluation of phases proportions in welded joints of duplex stainless steel by non-destructive testing

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    Guttemberg Chagas de Souza

    2013-06-01

    Full Text Available Os aços inoxidáveis Duplex (AID aliam uma excelente resistência à corrosão com elevada resistência mecânica devido à fina microestrutura bifásica composta por quantidades similares de ferrita (δ e austenita (γ. Portanto, estas ligas são utilizados em tubulações e equipamentos industriais onde se requer elevada relação resistência/peso, especialmente em empreendimentos de construção e montagem off-shore. Entretanto, as condições operacionais, na soldagem de campo, podem promover um significativo desbalanço microestrutural destas fases, resultando em decréscimo das propriedades mencionadas. A inspeção com o ferritoscópio é uma avaliação normalmente utilizada nestas atividades. Durante a avaliação com esta técnica pode ocorrer a rejeição da junta soldada quando o metal de solda se encontra com valores de ferrita fora das faixas estabelecidas pelas especificações de projeto. Assim, torna-se importante a análise destas juntas, com outras técnicas complementares, tal como a utilização das réplicas metalográficas. Este fato motivou a avaliação da proporção de fases em spools de AID de espessuras relativamente finas, soldados no campo, comparando-se as técnicas não destrutivas descritas. Os resultados denotam valores semelhantes, contudo o resultado pode ser influenciado pela forma e condições superficiais da junta soldada.Duplex stainless steels are high strength and corrosion resistant alloys, whose properties are devoted to the fine microstructure composed by similar amounts of ferrite and austenite and also to the high concentrations of Cr, Mo and N in solid solution. Not for coincidence, duplex steels are extensively used in chemical and petrochemical industries. However, welding operations conditions can promote the unbalance of the ferrite/austenite proportions mainly in the welding metal, with decrease of the properties mentioned. For this reason, non destructive measurements of ferrite content

  2. Welding of stainless and nickel based materials in the chemical industry. Consumables and procedures. Soldadura de aceros inoxidables y de materiales de base niquel en la industria quimica. Consumibles y procedimientos

    Energy Technology Data Exchange (ETDEWEB)

    Stromberg, J.; Budgifvars, S. (The ESA Grouo, Geoteborg (Sweden))

    1994-01-01

    In the chemical and petrochemical process industry a large range of various stainless and nickel based materials are used to meet high demands on corrosion resistance for optimum service performance. These materials include standard stainless steels, duplex and super duplex steels, super austenitic steels and nickel based alloys. Many components are being welded in the construction stage or may later on have to be repaired by welding. The design of components also often calls for joining or cladding of dissimilar materials to optimize the use of the material properties and for economical reasons to reduce the amount of expensive materials. Consumables and procedures have been developed to give weld metals to match the corrosion and strength requirements of the materials. There is a wide selection of MM electrodes with different coatings available and new types of stainless flux cored wires are being introduced. Especially for cladding of large surfaces the submerged arc strip cladding process offer high productivity solutions. (Author) 6 ref.

  3. Low temperature plasma carburizing of AISI 316L austenitic stainless steel and AISI F51 duplex stainless steel Cementação sob plasma à baixa temperatura do aço inoxidável austenítico AISI 316L e do aço inoxidável duplex AISI F51

    OpenAIRE

    Carlos Eduardo Pinedo; André Paulo Tschiptschin

    2013-01-01

    In this work an austenitic AISI 316L and a duplex AISI F51 (EN 1.4462) stainless steel were DC-Plasma carburized at 480ºC, using CH4 as carbon carrier gas. For the austenitic AISI 316L stainless steel, low temperature plasma carburizing induced a strong carbon supersaturation in the austenitic lattice and the formation of carbon expanded austenite (γC) without any precipitation of carbides. The hardness of the carburized AISI 316L steel reached a maximum of 1000 HV due to ∼13 at% c...

  4. INFLUENCIA DE LA NITRURACIÓN POR PLASMA SOBRE EL COMPORTAMIENTO A LA CORROSIÓN Y LA ADHESIÓN DE RECUBRIMIENTOS DLC SOBRE ACERO INOXIDABLE AISI 420

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    Jorge N. Pecina

    2016-01-01

    Full Text Available En este trabajo se estudió el comportamiento a la corrosió n y la adhesión de dos rec ubrimientos DLC (“Diamond Like Carbon ” , “Soft” y “Hard”, depositados por PACVD (“Plasma Assisted Chemical Vapour Deposition” sobre acero AISI 420, templado y revenido y /o nitrurado por plasma . Se analizaron por espectroscopía Raman y midió dureza en superficie. Se observó la microestructura por OM y SEM. Se realizaron pruebas de adhesión con indentación Rockwell C . S e practicaron ensayos de Niebla Salina e inmersión en HCl . Los DLC “ Soft ” presentaron una dureza de 5 00 HV y un espesor de 2 0 μm , mientras que los “ Hard ” tuvieron 1400 HV y 2 ,5 μm. Ambos recubrimientos presentaron bajo coeficiente de fricción y buena adhesión sobre el sustrato nitrurado . También presentaron buena resistencia a la corrosión atmosférica. En HCl el DLC retardó la degradación que se presentó rápidamente en las muestras sin recubrir.

  5. Estudio de la susceptibilidad de un acero inoxidable austenítico estabilizado con niobio al dañado por tensocorrosión en medio H2S (SSC y corrosión intergranular (IGC en otros medios agresivos

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    Gutiérrez de Saiz-Solabarría, S.

    1998-05-01

    Full Text Available Behavior to hydrogen damage caused by stress corrosion in a H2S medium (SSC and to intergranular corrosion (IGC in different mediums, such as oxalic acid (C2H2O4-2H20, iron sulphate-50 % sulfuric acid [Fe2(SO43-50 % H2SO4], nitric acid (HNO3, copper sulphate-16 % sulfuric acid (CuSO4-5H2O-16 % H2SO4 and cooper sulphate-50 % sulfuric acid (CuSO4-5H2O-50 % H2SO4, is studied in an AISI 347 austenitic stainless steel stabilized with 0.61 mass % Nb and hot rolled to a seamless pipe with 273.1 mm in diameter and 18.2 mm in thickness.

    Se estudia el comportamiento de un acero inoxidable austenítico del tipo AISI 347 estabilizado con un 0,61 % en masa de Nb, laminado en caliente para producir una tubería sin soldadura de 273,1 mm de diámetro y 18,2 mm de espesor, frente al dañado por hidrógeno generado por tensocorrosión en medio H2S (SSC y frente a la corrosión intergranular (IGC en diferentes medios agresivos tales como ácido oxálico (C2H2O4∙2H2O, sulfato de hierro-50% ácido sulfúrico [Fe2 (SO43-50 % H2SO4], ácido nítrico (HNO3, sulfato de cobre-16% ácido sulfúrico (CuSO4-5H2O-16 % H2SO4 y sulfato de cobre-50 % ácido sulfúrico (CuSO4-5H2O-50 % H2SO4, respectivamente.

  6. Estudo dos efeitos da restrição na microestrutura, microdureza e tenacidade em juntas soldadas em aço inoxidável duplex Study of restriction effects on mMicrostructure, microhardness and toughness in welded joints of duplex stainless steel

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    Everton Barbosa Nunes

    2011-06-01

    Full Text Available Os aços inoxidáveis duplex (AID apresentam em sua microestrutura ferrita e austenita, de modo a aliar boas propriedades mecânicas e resistência à corrosão. Estes materiais possuem grande aplicação na indústria petroquímica, sendo o UNS S31803 um dos mais conhecidos. Existem poucos trabalhos referentes ao estudo da influência da restrição na soldagem da junta na formação de Widmanstätten. Logo, este trabalho tem como objetivo analisar a influência da restrição no balanceamento de fases, na morfologia da austenita, na microdureza e na tenacidade da Zona Afetada pelo Calor (ZAC e da Zona Fundida (ZF. Foram realizadas soldagens em juntas tipo V utilizando eletrodo revestido AWS E2209-17com dois níveis de energia: 15 kJ/cm e 20 kJ/cm, com e sem restrição. De maneira geral, houve maior quantidade de ferrita nos passes de acabamento em relação aos passes de enchimento e de raiz. Foram observadas maiores quantidades de Widmanstätten nas condições soldadas com restrição. A ZAC apresentou uma microestrutura mais grosseira nos passes de acabamento. No entanto, não foram observadas diferenças significativas nas microestruturas quando comparadas as condições com e sem restrição. As condições que apresentaram maior quantidade de Widmanstätten obtiveram menores níveis de microdureza. Não foram observadas diferenças na energia absorvida na ZAC e ZF.Duplex stainless steels present ferrite and austenite in their microstructure in order to join good mechanical properties and corrosion resistance. These materials are very used in petrochemical industry, being the DSS UNS S31803 one of the most commercially known. There were not much published literature to study the influence of the precipitation of Widmanstätten austenite in joins with some restriction. This work has as objective to analyze the influence of the restriction in the phase balance of austenite and ferrite, in the morphology of the austenite, in the

  7. Influencia de los elementos residuales cobre, estaño, fósforo y arsénico en el agrietamiento de la superficie del acero inoxidable 18-8 durante la compresión a altas temperaturas

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    Botella, J.

    1998-05-01

    Full Text Available The effect of certain different concentrations of Cu, Sn, P and As on the surface cracking of 18-8 austenitic stainless steel hot compressed specimens has been studied, at 1,123 and 1,273 K, in an oxidizing atmosphere (air. A procedure for determining surface cracking has been established, and the cracking factor obtained in this way is correlated with the chemical composition of the materials at both temperatures. The cracking factors obtained at 1,273 K have been compared with the reduction of area drops obtained by hot tension tests at the same temperature.

    Esta investigación aborda el estudio del efecto de concentraciones variables de cobre, estaño, fósforo y arsénico en el agrietamiento de la superficie de un acero 18-8, sometido a ensayos de compresión, a 1.123 y 1.273 K, en atmósfera oxidante (aire. Se desarrolla un procedimiento de cuantificación del grado de agrietamiento y se relaciona cada índice de agrietamiento así obtenido, a las distintas temperaturas, con la composición química" de los materiales. Los índices de agrietamiento correspondientes a los materiales comprimidos a 1.273 K se comparan con los valores de pérdida de reducción de área obtenidos mediante ensayos de tracción a la misma temperatura.

  8. Evaluación de la fuerza de doblado y de fricción en el conformado de chapa de acero inoxidable AISI 304 DDQ mediante ensayos de doblado en condiciones multiaxiales de embutición

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    Coello, J.

    2012-08-01

    Full Text Available Die radius is a critical area from the viewpoint of friction in forming processes. Moreover the sheet, that has been previously deformed in flange area, suffers bending and unbending stresses. Then, die-sheet contact in die radius must be especially considered in order to guarantee the suitable lubrication conditions. In the present work, a test method is carried out for evaluating an AISI 304 DDQ steel under similar conditions to those existing in the die radius area and that, usually, are not really reproduced in traditional bending under tensions tests. Deformation under pure shear condition, the bending and the radius angle have been established as variables of the tests. Results allow to obtain the apparent pressure sheet-bending tool, that increases with bending angle and decreases with tool radius. This last variable is the most significant while the bending angle has lesser influence. Although experimental results present some concordances with values obtained by analytical methods, some corrections must be considered in them in order to improve the theoretical values.

    El radio de entrada a la matriz se considera una de las zonas críticas en los procesos de conformado de chapa mediante embutición profunda. El análisis de la fuerza de fricción y de doblado existentes resulta importante para predecir el comportamiento de la chapa en dicha zona, así como para garantizar una lubricación adecuada a las condiciones de procesado. En el presente trabajo, se aplica un método de ensayo que evalúa las acciones en el proceso de doblado del acero AISI 304 DDQ bajo condiciones similares a las que sufre el material en los procesos de embutición y que no son reproducidas por los clásicos ensayos de doblado bajo tensión. Se establecen como variables la deformación experimentada previamente por el material en condiciones típicas de cortante puro, “pure shear”, el ángulo de doblado y el radio de doblado. Los resultados obtenidos

  9. Caracterização e avaliação da resistência à corrosão na soldagem de tubulação de aço inoxidável duplex UNS S31803 pelo processo a arco submerso Characterization and evaluation of corrosion resistance of welded joint of duplex stainless steel pipe UNS S31803 by submerged arc process

    Directory of Open Access Journals (Sweden)

    Juan Manuel Pardal

    2011-12-01

    Full Text Available O presente trabalho apresenta os resultados da caracterização e avaliação da resistência à corrosão de uma junta soldada correspondente a uma tubulação de aço inoxidável duplex (AID UNS S31803 de 35 mm de espessura de parede soldada pelos processos de soldagem TIG (GTAW na raiz e arco submerso (SAW no enchimento e acabamento. Foram empregados como consumíveis de soldagem metais de adição de liga 25Cr-9Ni-4Mo (% em peso. Os resultados da caracterização das propriedades mecânicas, composição química e resistência à corrosão em diversas regiões da junta soldada foram comparados com os obtidos para o metal de base da tubulação, assim como com os valores mínimos exigidos pelas normas de projeto. Os resultados obtidos demonstram claramente a possibilidade da implementação do processo SAW na pré fabricação de tubulações de paredes espessas de AID, tendo em vista os resultados das propriedades analisadas e a grande demanda na construção e montagem de tubulações desta família de aço inoxidáveis na indústria offshore.This work presents the mechanical properties, microstructural and corrosion resistance evaluation of a welded joint of duplex stainless steel (DSS pipe with 35 mm wall thickness. The joint was welded by gas tungsten arc welding (GTAW process in the root passes and submerged arc welding (SAW in the filling and cap passes using filler metals with composition 25Cr-9Ni-4Mo (%wt.. The results of mechanical properties, chemical composition and corrosion resistance characterization in different regions of the welded joint were compared to the base metal and to the specifications required by the standards applied in the project. The main focus of this work was to show the successful utilization of SAW process in the welding of thick wall pipes of DSS. The application of high productivity process such as SAW has a crescent demand in offshore industry.

  10. Recubrimiento de Stellite 6 sobre acero inoxidable realizado con láser de CO2 para válvulas de escape de motores diesel

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    Cadenas, M.

    2002-12-01

    Full Text Available To reduce the recovery or the replacement costs of diesel engine exhaust valves, they are manufactured with an economic base material, and a coating which is deposited on the seat valve in order to reach high hardness and good impact, corrosion and high temperature wear resistance (>550 °C and without lubrication. In this work, appropriate laser cladding parameters have been determined to obtain Stellite 6 coatings over AISI 304 steel (as plane test specimens and SAE EV8 steel (as valves substrates. One and two superimposed tracks were deposited on the seat valves, and modifying the laser power as a function of the rotated angle at the beginning and the end of the circular tracks, pores and cracks have been minimized and the thickness of the track were made uniform. Hardness, dilution and final microstructure of the different coatings have been analysed. A 10 % dilution and 550 HV in the tracks over plane test specimens was observed, while valves with one track showed 25 % and 430 HV respectively. With two superimposed tracks the hardness was up to 470 HV in the upper track.

    Para abaratar el coste de recuperación o sustitución de válvulas de escape en motores diesel, estas se fabrican con un material base económico, recubriéndose el asiento de la válvula con otro material al que se exigirá elevada dureza y buena resistencia al impacto, a la corrosión y al desgaste erosivo en caliente (>550 °C y sin lubricación. Partiendo de esta idea, en el presente trabajo se han determinado los parámetros adecuados para realizar, mediante la técnica de plaqueado láser, un recubrimiento con Stellite 6, sobre sustratos de acero AISI 304 (probetas planas y SAE EV8 (válvulas reales. Sobre las válvulas, se depositaron uno y dos cordones superpuestos, se minimizó la presencia de poros y grietas, modificando el grado de solape inicial y final de los cordones circulares y la potencia en función del ángulo girado. Así, se

  11. Influência da energia de soldagem na microestrutura e na microdureza de revestimentos de aço inoxidável duplex Influence of the heat input on the microstructure and microhardness of weld overlay of duplex stainless steel

    Directory of Open Access Journals (Sweden)

    Everton Barbosa Nunes

    2012-06-01

    Full Text Available Aços inoxidáveis duplex (AID são caracterizados por apresentar interessante boas propriedades mecânicas e resistência à corrosão, possuindo um vasto campo de aplicação na indústria química e petroquímica. Geralmente, os reparos dos equipamentos ou estruturas são realizados por soldagem, sendo importante a seleção de parâmetros. É de suma importância a obtenção do teor adequado de ferrita no metal de solda, sendo que a variação da energia de soldagem pode influenciar de forma direta no percentual de ferrita. Logo, o objetivo deste trabalho é avaliar a influência da variação da energia de soldagem na microestrutura e na microdureza do metal de solda do AID. Foram realizadas soldagens de revestimento com sobreposição de duas camadas sobre o aço estrutural ASTM A516 Gr.60, utilizando eletrodo revestido AWS E2209-17. Três níveis de energia (15, 20 e 24 kJ/cm foram empregados, variando-se a corrente e a velocidade de soldagem. Foi verificado que para os níveis de energia empregados não houve diferença significativa no percentual de ferrita, porém o primeiro cordão depositado apresentou maior teor de austenita em relação aos demais cordões. De forma geral, foi verificado que o primeiro cordão depositado obteve níveis maiores de microdureza. Todas as condições apresentaram microdurezas abaixo do valor crítico.Duplex stainless steels (DSS are characterized by the presentation of an interesting combination of good mechanical properties and corrosion resistance, having a wide application in chemical and petrochemical industry. Generally, the manufacture and repair of any industrial equipment involve welding operations, even though it is very important to evaluate the influence of welding parameters. It is very important to obtain appropriate ferrite content in the weld metal, so that the variation of heat input can influence on the ferrite content directly. Therefore, the aim this work is to evaluate the

  12. Methodology for calculating the thickness free of sigma phase in duplex stainless steels large section parts during hiperquenching; Metodologia para el calculo de espesores limite libres de fase sigma durante el hipertemple en piezas de aceros duplex de gran seccion

    Energy Technology Data Exchange (ETDEWEB)

    Jimbert, P.; Guraya, T.; Torregary, A.; Bravo, P.

    2013-06-01

    To achieve the mechanical properties and corrosion resistance desired by duplex stainless steels used by the petrochemical and nuclear industry, parts are subjected to a hiperquenching heat treatment from about 1050 degree centigrade. This avoids the risk of intermetallic precipitation which drastically reduces the properties of these materials. However with increasing depth to which the deposits are present, the thicknesses for such pipes have been increased, resulting in higher levels of demand on all its manufacturing process, including the heat treatment. To avoid the precipitation of intermetallic phases such as sigma phase it is necessary to know the cooling profile in the center of the work piece and for this purpose to know the value of the Surface Heat Transfer Coefficient (h) is essential. This coefficient changes during the hiperquenching and its value is determined experimentally as it depends on several process parameters. Studies reveal that its value is stabilized within a few seconds. We can then assume that to know the cooling profile in the center of large sections it is only necessary to know the stabilized value of h. However, all the studies found in the literature are referred to diameters smaller than 100 mm. This paper has developed a methodology to predict the precipitation of intermetallic phases in duplex stainless steel parts with large thicknesses in industrial facilities from the calculation of h. This methodology allows us to calculate the cooling profiles without wasting any work piece using one or more sensorized patterns with thermocouples and a subsequent simulation with ANSYS. (Author)

  13. Evaluación del springback mediante ensayos de doblado bajo tensión en condiciones de multiaxialidad típicas de los procesos de embutición profunda. Aplicación a chapa de acero inoxidable AISI 304 DDQ

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    Miguel, V.

    2013-06-01

    Full Text Available In this paper, a methodology has been developed for evaluating the springback of AISI 304 DDQ stainless steel sheet based on a bending under tension test. The main difference of the methodology herein carried out is that tests are made under the multiaxial stresses state that take place in deep drawing processes. This affects to the level of stress value in the test and to the hardening state of the sheet. Springback evaluation has been done in two different areas. Bending area has been evaluated from elastic recovery ratio defined as the ratio between the bending radius after and before bending. Bending and unbending extreme has been studied from the measured curvature radius in this area and taking into account the geometric equivalence of the test with the drawing cups process. Results found allow to state that drawing ratio or deformation ratio have a negligible influence on the springback into the range of values experimented here. Bending radius has hardly influence as well while bending angle is the most significant variable. The results obtained are compared to those measured in deep-drawn cups, finding a great agreement.En este trabajo se presenta una metodología para evaluar la recuperación elástica o springback de chapa de acero inoxidable AISI 304 DDQ basada en la realización de ensayos bajo tensión. A diferencia de los estudios existentes en la literatura, los ensayos realizados son efectuados en condiciones multiaxiales típicas de los procesos de embutición de chapa. Esto afecta fundamentalmente a las tensiones involucradas en el proceso así como al estado de endurecimiento que experimenta el material. La evaluación del springback se ha efectuado en dos áreas diferentes. En la zona de doblado se ha evaluado a partir del factor de recuperación definido como la razón entre el radio de doblado y el radio con el que queda finalmente el material. La zona de doblado y desdoblado se ha evaluado en base a la inversa del radio

  14. Estudo do processo de fabricação de tubos flexíveis de aço inoxidável duplex UNS 32304 utilizados na indústria de petróleo e gás Study of the manufacturing process of UNS 32304 flexible pipes for the oil and gas industry

    Directory of Open Access Journals (Sweden)

    Ida Paula Gusmão de Oliveira

    2013-03-01

    Full Text Available A principal característica dos aços inoxidáveis duplex é o equilíbrio entre as fases austenita e ferrita, que garantem ao material melhores índices de resistências à corrosão e mecânica. No entanto, durante o processo de soldagem, ocorrem modificações estruturais, principalmente no balanço destas fases. Este desbalanceamento, em função dos níveis de solicitações mecânicas, pode levar tais regiões soldadas ao colapso. No intuito de minimizar o desequilíbrio das fases na região soldada, diversas técnicas são utilizadas, tais como inserção de metal de adição com elementos austenitizantes, uso de gás de proteção com nitrogênio ou, em outros casos, controle pós soldagem. Buscou-se identificar o verdadeiro efeito dos parâmetros de soldagem e do tratamento térmico especificado pela literatura em situações de campo. Através de uma avaliação temporal, observando uma linha de produção de tubulação flexível de aço inoxidável duplex UNS 32304 durante três anos, utilizando-se de procedimentos convencionais de soldagem com e sem a utilização de tratamento térmico foram observadas as falhas por fratura na zona termicamente afetada (ZTA. Foi utilizado um indutor localizado para o tratamento térmico, gerando um intenso fluxo de calor que promoveu temperaturas da ordem de 1000 ºC a altíssimas taxas de subida e descida, conforme estabelecem algumas literaturas.The main characteristic of duplex stainless steels is the balance between ferrite and austenite phases, wich ensures to such material the best levels of corrosion and mechanical resistance. However, during the welding process, structural modifications occur, especially with regard to the balance of these phases. This imbalance, depending on the levels of mechanical stress, may lead welded regions to collapse. In order to minimize the imbalance of the phases in the welded steel, several techniques are used, such as the insertion of filler metal with

  15. Dynamics characterization of microstructural changes in bars of duplex steels SAF 2205 using the information dimension; Caracterizacion dinamica de los cambios microestructurales en barras de aceros duplex SAF 2205 utilizando la dimension de informacion

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez, E.; Suarez, K.; Amorer, L.; Silva, J.

    2014-04-01

    This study evaluates the ultrasonic signals behavior of a duplex stainless steel SAF 2205 (UNS S31803) after aging treatments at 875 and 950 degree centigrade. The first treatment promotes the precipitation of the sigma phase and the second, its dissolution. The microstructural evaluation was carried out by optical microscopy. The results showed an increase of the sigma phase fraction and the secondary austenite with the time of aging treatment at 875 degree centigrade. On the other hand, increasing the time of treatment at 950 degree centigrade promotes a reduction of the sigma phase and the corresponding increase of the ferrite phase fraction. The study proposed to evaluate in the dynamical system field the influence of microstructural phases in the signals behavior and their dependence on the energy losses occurring in system during heat treatment, by deterministic chaos theory. To accomplish characterization, algorithm employs the representation of dynamic phase space and the information dimension estimate. The results show a higher correlation between the information dimension and the attenuation coefficient in comparison with the phase fractions. However, the efficiency of this type of study will depend on the frequency selected for the evaluation of the material. (Author)

  16. Stress corrosion (Astm G30-90 standard) in 08x18H10T stainless steel of nuclear fuel storage pool in WWER reactors; Corrosion bajo esfuerzo (Norma ASTM G30-90) en acero inoxidable 08x18H10T de piscinas de almacenamiento de combustible nuclear en reactores V.V.E.R

    Energy Technology Data Exchange (ETDEWEB)

    Herrera, V.; Zamora R, L. [Centro de Estudios Aplicados al Desarrollo Nuclear (Cuba)

    1997-07-01

    At the water storage of the irradiated nuclear fuel has been an important factor in its management. The actual pools have its walls covered with inoxidable steel and heat exchangers to dissipate the residual heat from fuel. It is essential to control the water purity to eliminate those conditions which aid to the corrosion process in fuel and at related components. The steel used in this research was obtained from an austenitic inoxidizable steel standardized with titanium 08x18H10T (Type 321) similar to one of the two steel coatings used to cover walls and the pools floor. the test consisted in the specimen deformation through an U ply according to the Astm G30-90 standard. The exposition of the deformed specimen it was realized in simulated conditions to the chemical regime used in pools. (Author)

  17. Microstructure evaluation of UNS S32205 duplex stainless steel friction stir welds Avaliação microestrutural de juntas soldadas por atrito com pino não-consumível do aço inoxidável duplex UNS S32205

    OpenAIRE

    Tiago F. A. Santos; Ricardo R. Marinho; Marcelo T. P. Paes; Antonio J. Ramirez

    2013-01-01

    UNS S32205 duplex stainless steel welds were performed by friction stir welding (FSW). Advancing and retreating sides showed distinct characteristics in the welded joint. The advancing side shows the strongest grain refinement which is corroborated by microhardness measurements. The microstructure characterization was carried out by optical, scanning and transmission electron microscopy. The thermomechanically affected zone displays austenite islands deformed in a ferrite matrix. The stir zon...

  18. Characterization of the hot cracking resistance using the Essential Work of Fracture (EWF): application to duplex stainless steels Caracterização da resistência ao trincamento a quente com base nos trabalhos esssenciais de mecânica da fratura: aplicação aos aços inoxidáveis duplex

    OpenAIRE

    Guilhem Martin; Muriel Veron; Yves Brechet; Bechir Chehab; Richard Fourmentin; Jean-Denis Mithieux; Sampath Kumar Yerra; Laurent Delannay; Thomas Pardoen

    2013-01-01

    Duplex stainless steels (DSS) involve two ductile phases, i.e. ferrite and austenite, with a proportion of each phase around 50%. The main advantage in comparison with other austenitic and ferritic stainless steels is the excellent combination of high strength and corrosion resistance together with good formability and weldability. Unfortunately, DSS present in general a poor hot workability. Standard hot ductility tests like hot tensile or hot torsion tests are always helpful to compare the ...

  19. Aceros aluminotérmicos. Nuevas aplicaciones

    Directory of Open Access Journals (Sweden)

    Duart Blay, J. M.

    2004-02-01

    . Particular aplicación o interés presentan en la tecnología de los ferrocarriles para la obtención del carril continuo, prácticamente implantado en todo el mundo y en soldaduras cable de cobre-carril de acero empleadas en las señalizaciones para control de tráfico. En este trabajo se aportan las bases termodinámicas de la aluminotermia del hierro y su aplicación a la soldadura compleja de cruzamientos, juntas de dilatación y desvíos en FF.CC, que combinan aceros Hadfield, aceros inoxidables y aceros perlíticos de diferentes propiedades mecánicas. Las uniones deben ser compactas, resistentes y duras en los niveles que se citan en el trabajo, según requisitos exigidos por la circulación en líneas de alta velocidad (350 km/h., actualmente en construcción en España, pero que resultan generalizables a otro tipo de líneas menos exigentes y a ferrocarriles mineros.

  20. Estudo comparativo entre os aços inoxidáveis dúplex e os inoxidáveis AISI 304L/316L

    Directory of Open Access Journals (Sweden)

    Marcelo Senatore

    2007-03-01

    Full Text Available Os aços inoxidáveis dúplex ferríticos-austeníticos fazem parte de uma classe de materiais com microestrutura bifásica, composta por uma matriz ferrítica e ilhas de austenita, com frações volumétricas aproximadamente iguais dessas fases. Essa classe de materiais é caracterizada por apresentar interessante combinação de elevadas propriedades mecânicas e de resistência à corrosão e, por isso, é considerada bastante versátil. Os aços inoxidáveis dúplex são, freqüentemente, utilizados nas indústrias química e petroquímica, de papel e celulose, siderúrgicas, alimentícias e de geração de energia. O presente trabalho estabelece um comparativo entre as propriedades físicas, mecânicas e de resistência à corrosão dos aços inoxidáveis duplex e os tradicionais aços inoxidáveis austeníticos AISI 304L e 316L, largamente utilizados na indústria brasileira. Resultados de ensaios laboratoriais e dados relevantes de experiências práticas desses materiais também são apresentados.Ferritic-austenitic duplex stainless steels are part of a class of material having a two-phase microestructure, comprised of a ferritic matrix and austenitic islands, with the volumetric fractions approximately the same in these phases. This class of material is characterized by the presentation of an interesting combination of high mechanical properties and corrosion resistance and is therefore considered quite versatile. The duplex stainless steels are often used in the chemical, petrochemical, pulp & paper and food industries, as well as in steel foundaries and energy power plants. This paper shows a comparison between the physical, mechanical and corrosion resistance properties of duplex stainless steels and the traditional austenitic stainless steels 304L and 316L, largely used in the Brazilian industry. Results of laboratory tests and relevant data on practical experiments on these materials are also presented.

  1. Evaluación del comportamiento estructural y de resistencia a la corrosión de armaduras de acero inoxidable austenítico AISI 304 y dúplex AISI 2304 embebidas en morteros de cemento Pórtland

    OpenAIRE

    Medina, E.; Cobo, A.; Bastidas, D. M.

    2012-01-01

    The mechanical and structural behaviour of two stainless steels reinforcements, with grades austenitic EN 1.4301 (AISI 304) and duplex EN 1.4362 (AISI 2304) have been studied, and compared with the conventional carbon steel B500SD rebar. The study was conducted at three levels: at rebar level, at section level and at structural element level. The different mechanical properties of stainless steel directly influence the behaviour at section level and structural element level. The study of the ...

  2. Comportamiento termomecánico de aceros AISI 304

    Directory of Open Access Journals (Sweden)

    El Wahabi, M.

    2001-04-01

    Full Text Available The hot deformation behaviour of three AISI 304 (H, L and HP austenitic stainless steel with different carbon contents has been studied. An analysis of the parameters describing their hot flow curves was carried out. No heavy effect of the carbon content was found on most of the latter parameters. However, the work hardening and dynamic recovery behaviour showed clear differences depending on the given alloy, especially at high temperatures and low strain rates where the high carbon steel displayed larger work hardening and dynamic recovery rates than the other steels. The high purity steel (interstitial free displayed the lower stress levels as its hardening rate was slower than in the other two steels.

    Se llevó a cabo un estudio del comportamiento termomecánico de tres aceros inoxidables austeníticos tipo AISI 304 (H, L y HP con diferentes contenido en carbono, mediante la determinación de los parámetros que describen las etapas de deformación en caliente. No se notó un fuerte efecto del carbono en dichos parámetros, excepto en los que describen los procesos de endurecimiento y de restauración dinámica que muestran una cierta dependencia con la composición química, especialmente a bajos valores del parámetro de Zener-Hollomon, donde el acero de alto carbono (304H endurece y restaura más rápido que el de bajo carbono (304L, alcanzándose valores de tensión de pico similares en ambos casos. El material de alta pureza (libre de intersticiales toma valores de tensión de pico más bajos que los otros aceros, endureciendo más lentamente y con una velocidad de restauración similar a la del 304H.

  3. Magnolias de acero (1989)

    OpenAIRE

    Galache Montero, Aurora

    2009-01-01

    [ES] Magnolias de Acero (1989) acerca a los espectadores al lado humano de la enfermedad. Los pone en contacto con la capacidad de lucha de algunos enfermos por llevar una vida normal ante un proceso crónico ni las repercusiones negativas sobre su salud. La protagonista, que padece una diabetes, se esfuerza por vivir una vida sin limitaciones batallando constante con las barreras que su enfermedad le va poniendo constantemente, anteponiendo siempre su felicidad a las consecuencias fatales que...

  4. Duplex ultrasound

    Science.gov (United States)

    Vascular ultrasound; Peripheral vascular ultrasound ... A duplex ultrasound combines traditional ultrasound with Doppler ultrasound . Traditional ultrasound uses sound waves that bounce off blood vessels to create ...

  5. Evaluación de diferentes aceros para la evolución de hidrógeno en KOH

    Directory of Open Access Journals (Sweden)

    Falk Michel Julke

    2014-05-01

    Full Text Available Se estudió el comportamiento electroquímico de los diferentes tipos de aceros comerciales de bajo costo (A36, 430 y 304 como electrodos para la obtención de hidrógeno. El propósito de este trabajo fue estudiar la evolución de hidrógeno, para lo cual se utilizaron técnicas electroquímicas como cronoamperometría y curvas voltamperométricas, en diferentes concentraciones de KOH (5% y 25% m/m. El acero inoxidable 304 en una concentración de 25%m/m tuvo el mejor desempeño, pues en estas condiciones el inicio de liberación de hidrógeno disminuyó y presentó el menor requerimiento de potencial para su uso como placa bipolar.

  6. un acero importado

    Directory of Open Access Journals (Sweden)

    Wilson A. Hormaza R.

    2007-01-01

    Full Text Available Este trabajo busca determinar las causas que llevaron al deterioro superficial de un conjunto de láminas y bobinas importadas de acero. Lo anterior implica precisar el tipo de deterioro de los componentes, es decir, si este se presentó durante el transporte marítimo o durante el almacenamiento. Los ensayos realizados fueron: análisis visual, análisis de espectrofotometría de infrarrojo y comparativo de los cristales de Cloruro de Sodio (NaCl, análisis de la morfología de la superficie deteriorada a través de microscopia óptica, análisis químico, metalografía y dureza. Los análisis determinaron la presencia de cristales de NaCl, los cuales, al disociarse, generan iones de Cl- (Cloruros y Na+ (Sodio, responsables del proceso de corrosión, indicándose, así la presencia de un ambiente marino

  7. Phosphate coating on stainless steel 304 sensitized;Recubrimiento fosfatado sobre acero inoxidable 304 sensibilizado

    Energy Technology Data Exchange (ETDEWEB)

    Cruz V, J. P. [IPN, Centro de Investigacion en Ciencia Aplicada y Tecnologia Avanzada, Unidad Altamira, Km. 14.5 Carretera Tampico-Puerto Industrial Altamira, 89600 Altamira, Tamaulipas (Mexico); Vite T, J. [ININ, Carretera Mexico-Toluca s/n, Ocoyoacac 52750, Estado de Mexico (Mexico); Castillo S, M.; Vite T, M., E-mail: jpcruz@ipn.m [IPN, Escuela Superior de Ingenieria Mecanica y Electrica, Seccion de Estudios de Posgrado e Investigacion, Unidad Profesional -Adolfo Lopez Mateos-, Zacatenco, 07738 Mexico, D. F. (Mexico)

    2009-07-01

    The stainless steel 304 can be sensitized when welding processes are applied, that causes the precipitation of chromium carbide in the grain limits, being promoted in this way the formation of galvanic cells and consequently the corrosion process. Using a phosphate coating is possible to retard the physiochemical damages that can to happen in the corrosion process. The stainless steel 304 substrate sensitized it is phosphate to base of Zn-Mn, in a immersion cell very hot. During the process was considered optimization values, for the characterization equipment of X-rays diffraction and scanning electron microscopy was used. The XRD technique confirmed the presence of the phases of manganese phosphate, zinc phosphate, as well as the phase of the stainless steel 304. When increasing the temperature from 60 to 90 C in the immersion process a homogeneous coating is obtained. (Author)

  8. Efecto de las sales fundidas en la termofluencia del acero inoxidable tipo 304

    Directory of Open Access Journals (Sweden)

    González-Rodríguez, G.

    1995-06-01

    Full Text Available Problems caused by both hot corrosion and creep type-damage occurring on superheater and reheater tubes of power plants using heavy oil as fuel shorten their design lives. The acceleration of hot corrosion attack of boilers is caused by the presence of fuel ash deposits containing mainly vanadium, sodium and sulphur, in the form of Na2SO4 y V2O5 and V2O5 which form low melting point compounds. In addition to this, the tubes are exposed to the action of both high stresses and high temperatures, producing the so called creep damage. In this work, creep rupture tests were carried out in the temperature range of 620 to 660 °C in static air and in corrosive environments. The corrosive environments included 100 % Na2SO4, 100 % V2O5 and a 80 % V2O5 + 20 % Na2SO4 mixture.

    Los problemas causados tanto por la corrosión por sales fundidas, así como por la termofluencia en los tubos de los sobrecalentadores y recalentadores de una planta de potencia que usa combustibles fósiles, reducen su vida prevista en diseño. La aceleración de la corrosión por sales fundidas es causada por la presencia de cenizas que contienen principalmente vanadio, sodio y azufre en la forma de Na2SO4 y V2O5, los cuales forman mezclas con eutécticos de bajo punto de fusión. Adicionalmente, los tubos están expuestos a la acción de altos esfuerzos y altas temperaturas, lo cual propicia la termofluencia del material. En este trabajo, se han realizado ensayos de termofluencia hasta la rotura en aire y en ambientes corrosivos en el rango de temperaturas de 620 a 660 °C. Los ambientes corrosivos fueron 100 % Na2SO4, 100 % V2O5, y una mezcla 20 % Na2SO4-80 % V2O5.

  9. Caracterización microestructural de uniones soldadas de acero AISI 316L en tuberías

    Directory of Open Access Journals (Sweden)

    Tomás H. Fernández-Columbié

    2016-03-01

    Full Text Available Se analizó el comportamiento microestructural de uniones soldadas de acero AISI 316L empleado en la fabricación de tuberías, las cuales se ven afectadas por agrietamiento en el cordón de soldadura. Se emplearon electrodos revestidos de acero inoxidables de los tipos E 309–16; 310–16 y E 316L–16, según norma de la AWS, los que fueron evaluados por su depósito en uniones a tope preparadas con biseles en V, soldadas por un solo lado del material de la tubería, así como la selección y preparación de muestra en zonas donde la tubería presenta daños mecánicos, fisuras y corrosión severa con pérdida del espesor de pared crítica para soportar las presiones de trabajo. Se caracterizó la microestructura de la zona fundida y la zona de influencia térmica de cada cordón luego de realizado el proceso de soldadura. Se concluye que la soldadura con electrodos del tipo E 309-16 y del tipo E 316-16 no son recomendables debido a que se obtiene una microestructura sensible al agrietamiento.

  10. ESTUDIO DE LA UNIÓN SOLDADA DISÍMIL DE UN ACERO INOXIDABLE SUPERDÚPLEX SAF 2507 CON UN ACERO HSLA API X-52.

    OpenAIRE

    Mendoza Bravo, Ivan

    2012-01-01

    Las uniones soldadas disímiles (USD) han sido utilizadas en la industria química, petroquímica y en la conducción de hidrocarburos como una alternativa para solucionar problemas de corrosión o pérdida de propiedades mecánicas que experimenta un componente o sección de un equipo. Actualmente, la Industria Petrolera Nacional presenta problemas con una sección del ducto ascendente que se encuentra en la zona de marea y oleajes, por lo que está expuesta a medios salinos. Este ducto...

  11. Estudo do mecanismo de corrosão por pites em água do mar de aços inoxidáveis supermartensíticos microligados com Nb e Ti Study of pitting corrosion mechanism of supermartensitic stainless steels microalloyed with Nb and ti in sea water

    OpenAIRE

    Carlos Alberto Picon; Frederico Augusto Pires Fernandes; Germano Tremiliosi-Filho; Cesar Augusto D. Rodrigues; Luiz Carlos Casteletti

    2010-01-01

    Os aços inoxidáveis supermartensíticos (SMSS) são usados em ambientes agressivos devido à sua boa soldabilidade, boas propriedades mecânicas em temperaturas elevadas e superior resistência à corrosão sob tensão. Aplicações na exploração de petróleo demandam superior combinação de propriedades e os aços inoxidáveis duplex e superduplex têm sido aplicados nessa área, a despeito de seus custos elevados. Os SMSS consistem numa alternativa técnica e econômica ao uso daqueles aços. Nesse trabalho, ...

  12. Pitting corrosion detection in stainless steels using ultrasounds; Deteccion de la corrosion por picadura en aceros inoxidables empleando ultrasonidos

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez, C.; Biezma, M. V.

    2014-04-01

    Passive metallic systems are able to develop in a spontaneous way a protective layer on the metallic surface that offers excellent corrosion resistance since really in a physical barrier for the reaction with the environment. However, some factors can break locally this layer, promoting one of the most insidious attack, pitting corrosion, which produces local chemical conditions that favouring the corrosive process causing defects in the material, as externals and internals ones, with a random distribution on the metal surface. In this work, ultrasounds non destructive technique has been employed using as variable the maximum amplitude of the back wall echo in order to detect this type of attack. The material employed is an austenitic stainless steel AISI 304, wherein appear several defectology distributions as superficial such as depths simulating pits. (Author)

  13. Comportamiento a la corrosión del acero 316L sinterizado con distinto grado de porosidad

    Directory of Open Access Journals (Sweden)

    Soria, L.

    1998-05-01

    Full Text Available AISI 316L sintered samples, with porosities ranging from 9 to 40 %, and without alloying losses at the surface, have been prepared. Those samples, along with conventional (rolled steel samples, have been subjected to electrochemical and immersion corrosion tests. According to porosity size quantitative measurements, before and after corrosion tests, two corrosion mechanisms, general and pitting, are proposed depending on the initial porosity.

    A partir de polvos de acero inoxidable AISI 316L, se han preparado muestras con distinto grado de porosidad, entre el 9 y el 40 %, asegurando que la superficie externa no resulta alterada durante el procesado pulvimetalúrgico. Junto a muestras de chapa laminada de la misma composición, han sido sometidas a ensayos de inmersión y a ensayos electroquímicos de corrosión. Estudios cuantitativos de la evolución de la porosidad superficial, antes y después de los ensayos, permiten plantear diversas hipótesis acerca de los mecanismos de corrosión actuantes en función de la porosidad de las piezas.

  14. DEFORMACIÓN ELÁSTICA RESIDUAL EN LÁMINAS DE ACERO AISI 304 RECUBIERTAS CON UNA PELÍCULA DE NITRURO DE TITANIO DEPOSITADA POR PVD-MAGNETRON SPUTTERING

    Directory of Open Access Journals (Sweden)

    H. A. COLORADO

    2009-01-01

    Full Text Available Se realizó una caracterización mediante difracción de rayos x (DRX en láminas de acero inoxidable AISI 304 recubierto con una capa de nitruro de titanio de 3 um de espesor, obtenida mediante deposición física de vapor (PVD-MAGNETRON SPUTTERING a una temperatura de 200 °C. se tomaron imágenes de microscopía electrónica de barrido (MEB, microscopía óptica (MO y microscopía de fuerza atómica (MFA para caracterizar el sustrato, la capa y la zona cercana a la intercara. adicionalmente se determinó la deformación elástica residual asociada con el ensanchamiento de los picos de DRX.

  15. Comportamiento del desgaste del flanco en el torneado en seco de alta velocidad del acero AISI 316L//Flank wear behavior in the dry high‐speed turning of AISI 316L stainless steel

    Directory of Open Access Journals (Sweden)

    Yoandrys Morales-Tamayo

    2013-09-01

    Full Text Available El presente estudio experimental se centra en investigar los efectos de los parámetros corte en el desgaste de flanco con dos insertos recubiertos durante el torneado de acabado en seco a altas velocidades del acero inoxidable AISI 316L. Los efectos de los parámetros de corte fueron determinados utilizando un análisis de varianza y de regresión simple. Como principal resultado se obtuvo el efectosignificativo del avance y del tiempo de maquinado en el desgaste del flanco. El inserto de tres capas no sobrepasó el criterio de fin de vida del desgaste, mientras que el inserto de una capa sufrió un desgaste catastrófico para la mayor velocidad de corte. El desgaste del flanco tuvo mejor comportamiento para el avance de 0,08 mm/rev en todas las velocidades empleadas en este estudio.Palabras claves: torneado de alta velocidad, desgaste de flanco, acero inoxidable AISI 316L, estudio experimental, análisis de varianza y regresión.______________________________________________________________________________AbstractThe current experimental study is focused on investigating the effects of cutting parameters on flank wear in two coated carbide inserts during dry high speed finish turning of AISI 316L stainless steel. The effects of cutting parameters were determinate using analysis of variance and simple regression. As a main resulta significant effect of cutting feed and the machining time on flank wear was found. The three coating layers insert did not exceed the criterion of end of life of wear while the insert with one layer suffered a catastrophic wear at the highest cutting speed. The flank wear showed the best performance for the cuttingfeed of 0,08 mm/rev at all the speeds used in the study.Key words: high speed turning; flank wear; AISI 316L stainless steel, experimental study; analysis of variance and regression.

  16. Duplex tab exhaust nozzle

    Science.gov (United States)

    Gutmark, Ephraim Jeff (Inventor); Martens, Steven (nmn) (Inventor)

    2012-01-01

    An exhaust nozzle includes a conical duct terminating in an annular outlet. A row of vortex generating duplex tabs are mounted in the outlet. The tabs have compound radial and circumferential aft inclination inside the outlet for generating streamwise vortices for attenuating exhaust noise while reducing performance loss.

  17. 76 FR 67253 - Requested Administrative Waiver of the Coastwise Trade Laws: Vessel ACERO AZUL; Invitation for...

    Science.gov (United States)

    2011-10-31

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF TRANSPORTATION Maritime Administration Requested Administrative Waiver of the Coastwise Trade Laws: Vessel ACERO AZUL... the vessel ACERO AZUL is: INTENDED COMMERCIAL USE OF VESSEL: ``Passenger for hire.'' GEOGRAPHIC...

  18. Algunas observaciones sobre la sinterización del acero austenítico 316L en atmósfera de argón

    Directory of Open Access Journals (Sweden)

    Gómez, F.

    1998-05-01

    Full Text Available PM high speed steels are prone to higher corrosion rates due to residual porosity as well as chromium depletion of the matrix during sintering AISI 316L powders have been cold compacted (100-1,000 MPa and sintered (1,000-1,250°C, 15-240 min under several argon containing or vacuum atmospheres. Better densification rates can be achieved as sintering time or temperature increase in the presence of argon. No surface oxidation has been observed with the use of low pressure argon atmospheres, as long as samples are protected in a stainless steel partially sealed container.

    La utilización de acero inoxidable pulvimetalúrgico está limitada, entre otras razones, por la presencia de porosidad que pueda favorecer procesos corrosivos, así como a posibles pérdidas de cromo en la matriz durante los procesos de sinterización. Se han realizado experiencias de procesado de polvos de acero 316L con distintas presiones de compactación (100-1.000 MPa, temperaturas de sinterización (1.100-1.250°C, tiempos de sinterización (15-240 min y en distintas atmósferas de sinterización, de argón y vacío. Se obtiene una mejor densificación con elevada temperatura y tiempos de sinterización en atmósferas de argón a baja presión. En dicha atmósfera, no se produce oxidación superficial aislando parcialmente las muestras del flujo directo del argón.

  19. Estudo comparativo entre os aços inoxidáveis dúplex e os inoxidáveis AISI 304L/316L

    OpenAIRE

    Marcelo Senatore; Leandro Finzetto; Eduardo Perea

    2007-01-01

    Os aços inoxidáveis dúplex ferríticos-austeníticos fazem parte de uma classe de materiais com microestrutura bifásica, composta por uma matriz ferrítica e ilhas de austenita, com frações volumétricas aproximadamente iguais dessas fases. Essa classe de materiais é caracterizada por apresentar interessante combinação de elevadas propriedades mecânicas e de resistência à corrosão e, por isso, é considerada bastante versátil. Os aços inoxidáveis dúplex são, freqüentemente, utilizados nas indústri...

  20. Achieving single channel, full duplex wireless communication

    KAUST Repository

    Choi, Jung Il

    2010-01-01

    This paper discusses the design of a single channel full-duplex wireless transceiver. The design uses a combination of RF and baseband techniques to achieve full-duplexing with minimal effect on link reliability. Experiments on real nodes show the full-duplex prototype achieves median performance that is within 8% of an ideal full-duplexing system. This paper presents Antenna Cancellation, a novel technique for self-interference cancellation. In conjunction with existing RF interference cancellation and digital baseband interference cancellation, antenna cancellation achieves the amount of self-interference cancellation required for full-duplex operation. The paper also discusses potential MAC and network gains with full-duplexing. It suggests ways in which a full-duplex system can solve some important problems with existing wireless systems including hidden terminals, loss of throughput due to congestion, and large end-to-end delays. Copyright 2010 ACM.

  1. INFLUENCIA DE LAS INCLUSIONES DE AZUFRE EN LA FATIGA DE UN ACERO AL MEDIO CARBÓN.

    OpenAIRE

    Banderas Morales, Juan Joel

    2012-01-01

    La fabricación de acero puro es un proceso trabajoso y caro. Las propiedades mecánicas del acero, en particular la solidez, son considerablemente más altas que las del hierro puro. Uno de los problemas del acero es la presencia de inclusiones (sulfuros) en el producto final, que disminuyen las propiedades mecánicas del acero y el control de las inclusiones no-metálicas, que precipitan en fases aisladas durante la solidificación del acero líquido como productos de reacción, form...

  2. “CARACTERIZACIÓN Y SOLDABILIDAD DE UN ACERO AVANZADO DE ALTA RESISTENCIA MICROALEADO CON BORO.”

    OpenAIRE

    Alatorre Torres, Norma

    2012-01-01

    L os aceros micro-aleados, como es el caso de los Aceros Avanzados de Alta Resistencia (AHSS), presentan ventajas en relación a los aceros estructurales al carbón y de baja aleación, respecto al costo y a la mejora en propiedades mecánicas (límites elásticos hasta cuatro veces superiores a los aceros laminados tradicionales), que se obtienen mediante un tratamiento termo-mecánico controlado. Este hecho se ve reflejado en el aumento en la demanda de este acero (entre 10 y 15%...

  3. Analysis of the passive layer developed on stainless steels implanted with chromium; Analisis de las peliculas pasivas generadas en aceros inoxidables implantados con cromo

    Energy Technology Data Exchange (ETDEWEB)

    Abreu, C. M.; Cristobal, M. J.; Novoa, X. R.; Pena, G.; Perez, M. C.

    2004-07-01

    This work studies the effect of chromium implantation on the development of passive layers generated electrochemically in alkaline medium over two stainless steels. The XPS analyses show that the layers generated on the implanted steels present less thickness together with similar composition compared to the unimplanted steels layers. However, SEM micrographs show that the layers grown on implanted steels present more defects and less adherence that the films on unimplanted steels. These changes together with the results obtained by Cyclic Voltammetry suggest an oxide structure modification, lattice structure or crystallinity state. (Author) 6 refs.

  4. Structure and properties of the Stainless steel AISI 316 nitrided with microwave plasma; Estructura y propiedades del acero inoxidable AISI 316 nitrurado con plasmas de microondas

    Energy Technology Data Exchange (ETDEWEB)

    Becerril R, F

    1999-07-01

    In this work were presented the results obtained by nitridation on stainless steel AISI 316 using a plasma generated through a microwave discharge with an external magnetic field using several moistures hydrogen / nitrogen to form a plasma. The purpose of nitridation was to increase the surface hardness of stainless steel through a phase formation knew as {gamma}N which has been reported that produces such effect without affect the corrosion resistance proper of this material. (Author)

  5. Internal microporosity formation in stainless steel powders: kinetics and mechanism; Formacion de microporosidad interna en polvos de acero inoxidable: cinetica y mecanismo

    Energy Technology Data Exchange (ETDEWEB)

    Martinez, M.; Suwardijo, W.; Garcia, L.; Formoso, A.; Cores, A.

    2002-07-01

    The internal microporosity of stainless steel powders is obtained by a technology developed in the Metallurgical Research Center (CIME) in collaboration with ISPETP, which consists of carbon enrichment of alloy during the fusion process, and after powder atomization a subsequent decarburization annealing. The internal microporosity , which can reach up to 10 volume percent of the steel particle, reduces powder density and improves powder compressibility, while costs for technology installation are also reduced. In this paper the technology for obtaining the microporosity, the mathematical models of the process, and the structural transformations undergone by stainless steel powder are shown. It is concluded that for carbon contents lower than 0.05% internal microporosity tends to disappear. (Author) 17 refs.

  6. Comparación entre los diagramas TTS obtenidos mediante los ensayos normalizados Huey y Strauss modificado para el acero inoxidable AISI 304

    Directory of Open Access Journals (Sweden)

    Otero, E.

    1996-04-01

    Full Text Available This work presents a comparison of Temperature-Time-Sensitization TTS diagrams obtained by Huey and modified Strauss standard, for detecting susceptibility to intergranular attack. The difference between these tests is the use of a strong or a slightly smooth oxidizing electrolyte. The diagrams obtained are different and if a sample tested by modified Strauss is sensitized, then it will be sensitized in the Huey test, but the contrary is not always true. This difference is because a sensitized sample has to have a continuous band lacking in chromium along the grain boundary in order to be sensitized in the modified Strauss test. This condition is not necessary in the Huey test.

    Se comparan los diagramas Temperatura-Tiempo-Sensibilización TTS, obtenidos mediante los ensayos normalizados de corrosión intergranular Huey y Strauss modificado, que, respectivamente, utilizan electrólitos fuerte y suavemente oxidantes, mostrándose que los diagramas obtenidos son diferentes. Si una muestra evaluada mediante el ensayo Strauss modificado se encuentra sensibilizada, entonces lo estará también en el ensayo Huey, pero no necesariamente ocurrirá lo contrario; esta diferencia se asocia a la necesidad de la existencia de una zona continua empobrecida en cromo a lo largo del límite de grano para que el material se sensibilice con respecto al ensayo Strauss modificado, condición innecesaria para el caso del ensayo Huey.

  7. Waste water treatment of slaughterhouse through water treatment plants of stainless steel; Tratamiento de aguas residuales de mataderos mediante depuradoras compactas modulares de acero inoxidable

    Energy Technology Data Exchange (ETDEWEB)

    BaNales Sirvent, P.

    1997-06-01

    The object of this project was to develop an integral waste water treatment concept, based on compact module made of stainless steel, with a combination that allows to get performances according to given requirements stablished in the Community Directive 91/271/CEE (1991). The industrial pilot tests have been made in a slaughterhouse with a capacity of 20 tons per day. (Author)

  8. Effect of boron on sintering of a ferritic stainless steel; Efecto del boro en la sinterizacion de un acero inoxidable ferritico

    Energy Technology Data Exchange (ETDEWEB)

    Cabral-Miramontes, J. A.; Barceinas-Sanchez, J. D. O.; Velez-Jacobo, L.; Martinez-Villafane, A.; Chacon-Nava, J. G.

    2008-07-01

    This work studies the effect of boron on the density of a 409Nb ferritic stainless steel obtained by powder metallurgy during the process of sintering. The purpose of adding boron is to promote the formation of a liquid phase during sintering at temperatures below 120 degree centigrade . The boron contents varied from 0.0 to 1.5%wt. Specimens were compacted at 700MPa, and sintering was made at 1075 and 1150 degree centigrade during 60 minutes under a hydrogen atmosphere, using a heating rate of 20 degree centigrade/min. Density values were determined by the Archimedes method, and the samples were analysed using scanning electron microscopy. This work shows the dependence of the steel density and morphology of the microstructure as a function of boron content and the temperature of sintering. (Author) 29 refs.

  9. Estudio de la unión soldada disímil de un acero inoxidable superdúplex SAF 2507 con un HSLA API X-52

    OpenAIRE

    Mendoza Bravo, Iván

    2011-01-01

    Las uniones soldadas disímiles (USD) han sido utilizadas en la industria química, petroquímica y en la conducción de hidrocarburos como una alternativa para solucionar problemas de corrosión o pérdida de propiedades mecánicas que experimenta un componente o sección de un equipo.

  10. Study of the neutronic activation of the stainless steel in a nuclear reactor; Estudios de la activacion neutronica del acero inoxidable en un reactor nuclear

    Energy Technology Data Exchange (ETDEWEB)

    Lazaro Roche, I.; Rodenas Diago, J.; Marques, J. G.

    2013-07-01

    During operation of a nuclear reactor, various components can be activated by neutron reactions. The activity thus generated produces a dose that is a potential risk to workers and environment. Was simulated using the MCNP and CINDER'90 such activation codes on a piece of steel and the values obtained compared with experimental measurements. The equivalence of both methods is verified to calculate neutron activation and evolution of the dose rate with the cooling time.

  11. Influencia de la microestructura en el comportamiento a fatiga de aceros inoxidables austeníticos con alto contenido en molibdeno

    OpenAIRE

    Oñoro, J.; Gamboa, R.; Ranninger, C.

    2006-01-01

    Austenitic stainless steels with molybdenum present high mechanical properties and corrosion resistance to aggressive environments. These steels have been used to tank and vessel components for high corrosive liquids as phosphoric, nitric and sulphuric acids. These materials with low carbon and nitrogen addition have been proposed candidates as structural materials for the international thermonuclear experimental reactor (ITER) in-vessel components. Molybdenum addition in austenitic stainless...

  12. Oxidación cíclica de un acero refractario AISI 310 a alta temperatura en atmósferas con contenidos de oxígeno variables

    Directory of Open Access Journals (Sweden)

    Higuera-Hidalgo, V.

    2005-06-01

    Full Text Available High temperature oxidation tests of an AISI 310 stainless steel was performed in two different environments: in an standard atmosphere (21 % oxygen at 704, 800, 884 and 1,000 °C and in the typical environment of a gas turbine and vapor generator of a combined-cycle electric generation unit (10 % oxygen at 800 and 1,000 °C. The oxidation kinetics was determined by means of the measurement of the weight gain per unit surface of the specimen and also determining the thickness of the oxide layer. Comparable results have been obtained using both methodologies and the effect of the oxygen content along with the other experimental differences were determined observing the oxidation kinetics in both environments. The cyclic oxidation of AISI 310 deteriorates at temperatures higher than 1,000 °C.

    Se ha llevado a cabo un estudio experimental sobre la oxidación a altas temperaturas de un acero inoxidable refractario AISI 310, en dos ambientes diferentes: en una atmósfera convencional (21 % de O2, a 704, 800, 884 y 1.000 °C y en un ambiente simulativo de una turbina de gas y del generador de vapor de uña central eléctrica de ciclo combinado (10-11 % de O2, a 800 y 1.000 °C. La cinética de la oxidación del material se ha determinado a partir, tanto de la ganancia de peso por unidad de superficie experimentada por las probetas objeto de ensayo como por la determinación de los espesores de las capas de óxido formados. Se han obtenido resultados comparables con ambas metodologías y se ha puesto de manifiesto el efecto del contenido de oxígeno y de las demás diferencias experimentales a partir de la comparación de las cinéticas de oxidación del acero en los dos medios oxidantes analizados. La oxidación del acero AISI 310 en situaciones térmicas cíclicas empieza ya a ser importante a partir de una temperatura de 1.000 °C.

  13. Effects of low temperature aging on the mechanical properties and corrosion resistance of duplex and lean duplex stainless steels UNS S32205 and UNS S32304 Efeitos de envelhecimentos em baixas temperaturas nas propriedades mecânicas e resistência à corrosão dos aços duplex e lean duplex UNS S32205 e UNS S32304

    Directory of Open Access Journals (Sweden)

    Francis Gabriel Wasserman

    2013-06-01

    Full Text Available Duplex stainless steels (DSS with austenite-ferrite microstructure are high strength and corrosion resistant steels frequently used as pipes and accessories in chemical/petrochemical on/and off-shore industries. Low temperature heat treatments (400-475ºC may increase the hardness and wear resistance of duplex steels, due to a spinodal decomposition reaction of the ferrite, whose small particles α' precipitate in the matrix. In this work, several heat treatments at 400ºC and 475ºC with short duration (Os aços inoxidáveis duplex (AID com microestrutura austeno-ferrítica são aços de alta resistência mecânica, sendo utilizados em tubos e componentes nas indústrias química e petroquímica. Tratamentos térmicos em baixas temperaturas (400-475ºC podem aumentar a dureza e a resistência ao desgaste, devido à reação de decomposição espinoidal da ferrita, quando finas partículas de α' se precipitam na matriz. Nesse trabalho, diversos tratamentos térmicos de curta duração a 400ºC e 475ºC foram realizados nos aços UNS S32304 e UNS S32205. A cinética de precipitação foi estudada por meio de medidas de dureza. Ensaios de tração foram realizados em algumas condições para se avaliar o efeito do envelhecimento na ductilidade dos dois aços. O endurecimento do aço UNS S32205 é mais pronunciado do que o do aço UNS S32304, embora ambos os aços apresentem um ganho considerável de resistência com tratamentos térmicos de curta duração. Amostras de aço duplex tratadas a 475ºC por 4 h e 8 h não apresentaram qualquer prejuízo na resistência à corrosão nos ensaios de polarização cíclica e temperatura crítica de pites em meio contendo NaCl.

  14. Efeito da chuva ácida em aços inoxidáveis coloridos

    Directory of Open Access Journals (Sweden)

    Célia Regina de Oliveira Loureiro

    2007-03-01

    Full Text Available Em função da crescente demanda de utilização do aço inoxidável, na arquitetura, como material de revestimento externo e, considerando a preocupação dos órgãos de controle ambiental com a poluição no meio urbano, foram avaliados os efeitos da chuva ácida nas condições superficiais do aço inoxidável colorido e na lixiviação de cromo para o ambiente. Para esse estudo, foram realizados, em laboratório, ensaios de imersão de chapas de aço inoxidável colorido e natural em solução simulada de chuva ácida, sendo avaliados a liberação de cromo para a solução e a alteração da aparência superficial das amostras em tempos de exposição de 1, 3, 7, 14 e 28 dias. Nas amostras de aço inoxidável, com e sem coloração, foram medidos a cor e o brilho e, para soluções ácidas remanescentes, foram realizadas análises de cromo total e cromo hexavalente. Os resultados obtidos mostraram que, independente do tempo de contato do aço inoxidável colorido com a solução de chuva ácida, houve preservação da aparência do material, sem alteração das condições superficiais, e o teor de cromo hexavalente na solução se apresentou em níveis muito inferiores aos estabelecidos pelo Conselho de Política Ambiental de Minas Gerais - COPAM.Considering the increase of stainless steel application for exteriors in architecture and governmental environment protection policies, the effect of acid rain exposure on the surface appearance and chromium release of colored stainless steel and uncolored substrate was investigated. Laboratory experiments were conducted by immersing stainless steel samples in an artificial acid rain solution for 1, 3, 7, 14 and 28 days exposure. The surface appearance of the samples was evaluated by color and brightness measurements and chromium release by chemical analysis of total and hexavalent chromium. The obtained results have shown that the surface appearance of the stainless steel was preserved and the

  15. Corrosion behavior of duplex coatings

    Directory of Open Access Journals (Sweden)

    K. Raghu Ram Mohan Reddy

    2016-07-01

    Full Text Available The titanium alloys are used in defense, aerospace, automobile, chemical plants and biomedical applications due to their very high strength and lightweight properties. However, corrosion is a life-limiting factor when Ti alloys are exposed to different chemical environments at high temperatures. In the present paper, duplex NiCrAlY/WC–Co coating is coated onto Ti6Al4V substrate to investigate the corrosion behavior of both coated samples and the substrate. The duplex coating was performed with NiCrAlY as the intermediate coat of 200 μm thickness deposited by HVOF process and WC–Co ceramic top coat with varying thicknesses of 250 μm, 350 μm and 450 μm deposited by DS process. Potentiodynamic polarization tests were employed to investigate the corrosion performance of duplex coated samples and substrate in Ringer’s solution at 37 °C and pH value was set to 5.7. Finally the results reveal that 350 μm thick coated samples showed highest corrosion resistance compared to 250 μm thick samples as well as bare substrate. However, the 450 μm thick coated sample showed poor corrosion resistance compared to the substrate. The scale formed on the samples upon corrosion was characterized by using SEM analysis to understand the degree of corrosion behavior.

  16. Integridad estructural de vigas roblonadas de acero estructural antiguo

    OpenAIRE

    Moreno Revilla, Jesús

    2005-01-01

    Son numerosas las estructuras construidas con hierro pudelado o acero forjado durante el siglo XIX y principios del XX que todavía permanecen en uso. Las cargas actuales y los daños existentes hacen necesarias evaluaciones de integridad estructural para extender su vida útil, adaptar su uso y establecer programas de vigilancia y mantenimiento. Los análisis de este tipo realizados hasta ahora son recientes y consideran que el componente dañado de un elemento estructural roblonada no interaccio...

  17. Influence of Mo alloying on pitting corrosion of stainless steels used as concrete reinforcement Influência do Mo na corrosão por pites de aços inoxidáveis utilizados como reforço de concreto armado

    Directory of Open Access Journals (Sweden)

    Thiago J. Mesquita

    2013-06-01

    concreto. Além de evitar a corrosão dos reforços de aço, em ambientes alcalinos altamente agressivos, o uso de aços inoxidáveis é cada vez mais popular em construções costeiras e marinhas. Embora amplamente utilizado como um elemento que aumenta a resistência à corrosão, em ambientes ácidos, a influência do Mo, sobre as propriedades de corrosão por pites dos aços inoxidáveis, não é muito clara em meios alcalinos. O entendimento do mecanismo do Mo, na resistência à corrosão, nessas condições, é, portanto, de grande importância, sobretudo para a nova classe de aços inoxidáveis "lean duplex". Esses aços contêm um baixo teor de Ni e de Mo, mas apresentam um bom equilíbrio entre as propriedades exigidas, nessas aplicações, e propiciam um bom custo final do material. Nesse trabalho, mostra-se o efeito da adição de Mo sobre as propriedades de corrosão por pites de aços austeníticos, ferríticos e duplex. Os resultados serão discutidos com relação às diferentes famílias de aços inoxidáveis em diferentes meios agressivos, principalmente em uma solução sintética contendo cloretos e carbonatos. Essa solução reproduz o ambiente real de poros de concreto contaminado (pH 10, com íons carbonato e cloreto.

  18. Duplex Direct Data Distribution System

    Science.gov (United States)

    Greenfield, Israel (Technical Monitor)

    2001-01-01

    The NASA Glenn Research Center (GRC) is developing and demonstrating communications and network technologies that are helping to enable the near-Earth space Internet. GRC envisions several service categories. The first of these categories is direct data distribution or D3 (pronounced "D-cubed"). Commercially provided D3 will make it possible to download a data set from a spacecraft, like the International Space Station. as easily as one can extract a file from a remote server today, using a file transfer protocol. In a second category, NASA spacecraft will make use of commercial satellite communication (SATCOM) systems. Some of those services will come from purchasing time on unused transponders that cover landmasses. While it is likely there will be gaps in service coverage, Internet services should be available using these systems. This report addresses alternative methods of implementing a full duplex enhancement of the GRC developed experimental Ka-Band Direct Data Distribution (D3) space-to-ground communication link. The resulting duplex version is called the Duplex Direct Data Distribution (D4) system. The D4 system is intended to provide high-data-rate commercial direct or internet-based communications service between the NASA spacecraft in low earth orbit (LEO) and the respective principal investigators associated with these spacecraft. Candidate commercial services were assessed regarding their near-term potential to meet NASA requirements. Candidates included Ka-band and V-band geostationary orbit and non-geostationary orbit satellite relay services and direct downlink ("LEO teleport") services. End-to-end systems concepts were examined and characterized in terms of alternative link layer architectures. Alternatives included a Direct Link, a Relay Link, a Hybrid Link, and a Dual Mode Link. The direct link assessment examined sample ground terminal placements and antenna angle issues. The SATCOM-based alternatives examined existing or proposed commercial

  19. Ecuaciones constitutivas de la fluencia en caliente de aceros microaleados

    Directory of Open Access Journals (Sweden)

    Cabrera, J. M.

    1998-05-01

    Full Text Available Over centuries, the hot forming has been employed to provide shape to metáis. Nowadays, the deformation at high temperatures gives also the required final mechanical properties. From this point of view, the obtention of a constitutive equation describing the hot flow behaviour of microalloyed steels in particular is a very important task. The main difficulty in modelling the high temperature flow arises from the simultaneity of two opposite phenomena, namely, work hardening and dynamic softening due to recovery and recrystallization. In this is work a review of constitutive equations (including the effect of the chemical composition describing the flow behaviour of microalloyed steels deformed under high temperature conditions.

    Durante siglos el conformado en caliente se ha utilizado para proporcionar a los metales la forma deseada. Hoy en día la deformación en caliente no sólo genera la geometría deseada sino las características mecánicas requeridas. Así, la obtención de una ecuación constitutiva para la fluencia en caliente de un acero en particular, es una tarea ineludible para efectuar simulaciones por ordenador de procesos industriales. La complicación de la modelización de la fluencia a alta temperatura proviene de la simultaneidad de dos fenómenos contrapuestos durante la deformación, a saber, endurecimiento por deformación y ablandamiento por recuperación de la estructura. Este último a su vez puede constar de restauración y recristalización dinámicas. En este trabajo se revisan y plantean las ecuaciones constitutivas que describen las curvas de fluencia bajo condiciones de deformación en caliente, y se presenta una aplicación de las mismas a aceros microaleados.

  20. Avaliação do atrito produzido por braquetes cerâmicos e de aço inoxidável, quando combinados com fios de aço inoxidável Evaluation of friction produced by ceramic and stainless steel brackets, combined with stainless steel wires

    Directory of Open Access Journals (Sweden)

    Paulo Eduardo Bággio

    2007-02-01

    Full Text Available OBJETIVO: no presente trabalho, comparou-se o atrito produzido por braquetes cerâmicos policristalinos e de aço inoxidável, quando combinados com fios de aço inoxidável, durante a execução de mecânica de deslize. METODOLOGIA: com essa finalidade desenvolveram-se um simulador e metodologia apropriados. RESULTADOS E CONCLUSÕES: os coeficientes de atrito verificados na combinação braquete cerâmico/fio de aço inoxidável foram superiores aos da combinação braquete de aço inoxidável/fio de aço inoxidável. Assim sendo, a execução de mecânica de deslize é facilitada quando são utilizados braquetes de aço inoxidável com fios de aço inoxidável.AIM: to compare the friction produced by ceramic and stainless steel brackets, when combinated with stainless steel wire, during the execution of sliding mechanics. METHODS: a simulator and and appropriate methodology were developed. RESULTS AND CONCLUSIONS: the combination of ceramic bracket with stainless steel wire produced more friction than the stainless steel bracket combinated to stainless steel wire. In conclusion, the execution of sliding mechanics is facilitated when used stainless steel bracket combinated with stainless steel wire.

  1. Screening of Modified RNA duplexes

    DEFF Research Database (Denmark)

    Schyth, Brian Dall; Bramsen, Jesper Bertram; Kjems, Jørgen;

    Because of sequence specific gene targeting activity siRNAs are regarded as promising active compounds in gene medicine. But one serious problem with delivering siRNAs as treatment is the now well-established non-specific activities of some RNA duplexes. Cellular reactions towards double stranded...... RNAs include the 2´-5´ oligoadenylate synthetase system, the protein kinase R, RIG-I and Toll-like receptor activated pathways all resulting in antiviral defence mechanism. We have previously shown that antiviral innate immune reactions against double stranded RNAs could be detected in vivo as partial...... protection against a fish pathogenic virus. This protection corresponded with an interferon response in the fish. Here we use this fish model to screen siRNAs containing various chemical modifications of the RNA backbone for their antiviral activity, the overall aim being identification of an siRNA form...

  2. Duplex steam reformer: alternate catalyst

    International Nuclear Information System (INIS)

    The manufacturing feasibility of a duplex steam reformer tube for potential use in a high temperature gas cooled reactor has been successfully demonstrated. This technique consists of explosively expanding the inner tube into the outer tube. To successfully achieve the desired 0 to 3 mil radial gap between the tubes it is necessary to perform the expansion in two steps with an intermediate anneal. A catalyst design that would have replaced the conventional Raschig rings with a metal supported catalyst has been evaluated and it has been concluded that further development and testing are needed before fabrication of a full scale prototype is warranted. Consequently, the immediate efforts are directed towards reevaluating the incentives for developing a catalyst and the probability of successfully developing a catalyst that could be used for steam reforming

  3. A comparison of tensile, fracture and fatigue mechanical behaviour of structural reinforcing bars made with different steels

    Directory of Open Access Journals (Sweden)

    Rodríguez, C.

    2013-09-01

    Full Text Available The use of austenitic stainless steels as rebar is an option increasingly used in reinforced concrete structures exposed to aggressive environments and especially those that have to work in marine environments. The same is true for duplex stainless steel rebars, although nowadays they have a lower use, mainly due to the fact that their inclusion in the reinforced concrete standards was delayed 10 years compared to austenitic stainless steel ones, and consequently their in-service behavior is not as well known. A study of the mechanical properties, including fracture toughness, fatigue behaviour and corrosion resistance in saline alkaline environments of austenitic (AISI 304LN and 316LN and duplex (D2205 stainless steel reinforcing bars was performed in this work. Bars made on a high ductility carbon steel (B500SD that are normally used to reinforce concrete were also characterized and used as a comparison. Stainless steel reinforcing bars show mechanical properties at least similar but usually higher than one of the best carbon steel re-bars (B500SD, along with a significantly higher ductility and, of course, much better corrosion behaviour in saline alkaline environments.El uso de aceros inoxidables austeníticos como armaduras de refuerzo es una opción cada vez más utilizada en estructuras de hormigón armado expuestas a ambientes agresivos y especialmente en las que han de trabajar en ambientes marinos. Lo mismo cabe decir de las armaduras de acero inoxidable dúplex, si bien su uso es menor, debido sobre todo a que su inclusión en la normativa aplicable al armado de hormigón se retrasó 10 años con respecto a los inoxidables austeníticos y, consecuentemente, su comportamiento en servicio es menos conocido. En este trabajo se analiza el comportamiento mecánico, incluyendo fractura y fatiga, así como la resistencia a la corrosión en medios que simulan un hormigón contaminado de cloruros, de armaduras fabricadas tanto con

  4. Análisis de falla en cable de acero Análisis de falla en cable de acero

    Directory of Open Access Journals (Sweden)

    E. A. Ossa

    2005-12-01

    Full Text Available Este artículo describe el análisis de falla realizado en dos muestras de cables de acero que sufrieron falla súbita bajo condiciones de carga de trabajo normales. La falla fue causada por una carga menor a la capacidad nominal. Luego de inspección óptica se evidenció que la falla fue ocasionada por fatiga del material de uno de los cables.This paper describes the failure analysis of two wire ropes fractured during normal working conditions. The failure was caused by a load well below the nominal maximum resistance of the ropes. Optical microscopy indicated fatigue failure of one of the cables.

  5. Practical, real-time, full duplex wireless

    KAUST Repository

    Jain, Mayank

    2011-01-01

    This paper presents a full duplex radio design using signal inversion and adaptive cancellation. Signal inversion uses a simple design based on a balanced/unbalanced (Balun) transformer. This new design, unlike prior work, supports wideband and high power systems. In theory, this new design has no limitation on bandwidth or power. In practice, we find that the signal inversion technique alone can cancel at least 45dB across a 40MHz bandwidth. Further, combining signal inversion cancellation with cancellation in the digital domain can reduce self-interference by up to 73dB for a 10MHz OFDM signal. This paper also presents a full duplex medium access control (MAC) design and evaluates it using a testbed of 5 prototype full duplex nodes. Full duplex reduces packet losses due to hidden terminals by up to 88%. Full duplex also mitigates unfair channel allocation in AP-based networks, increasing fairness from 0.85 to 0.98 while improving downlink throughput by 110% and uplink throughput by 15%. These experimental results show that a re- design of the wireless network stack to exploit full duplex capability can result in significant improvements in network performance. © 2011 ACM.

  6. Avaliação do atrito produzido por braquetes cerâmicos e de aço inoxidável, quando combinados com fios de aço inoxidável Evaluation of friction produced by ceramic and stainless steel brackets, combined with stainless steel wires

    OpenAIRE

    Paulo Eduardo Bággio; Carlos de Souza Telles; João Baptista Domiciano

    2007-01-01

    OBJETIVO: no presente trabalho, comparou-se o atrito produzido por braquetes cerâmicos policristalinos e de aço inoxidável, quando combinados com fios de aço inoxidável, durante a execução de mecânica de deslize. METODOLOGIA: com essa finalidade desenvolveram-se um simulador e metodologia apropriados. RESULTADOS E CONCLUSÕES: os coeficientes de atrito verificados na combinação braquete cerâmico/fio de aço inoxidável foram superiores aos da combinação braquete de aço inoxidável/fio de aço inox...

  7. Tratamiento térmico de acero cubano // Thermal treatment of cuban steel

    OpenAIRE

    N. Caballero Stevens; H. Cabrera Araujo

    2001-01-01

    En este trabajo se muestran algunos de los resultados obtenidos durante la investigación de un nuevo acero cubano que sepretende destinar a la fabricación de elementos de corte para máquinas combinadas cortadoras de caña de azúcar,herramientas de mano y otras piezas de gran responsabilidad que requieren elevada dureza para su trabajo. En el trabajo sepresentan los aspectos principales que relacionan la composición química, microestructura y dureza de este acero. Seestablecen experimentalmente...

  8. Estudio de la corrosión del acero embebido en concreto aas sometido a cloruros

    OpenAIRE

    ROBINSON TORRES GÓMEZ; WILLIAM APERADOR; ENRIQUE VERA; RUBY MEJÍA DE GUTIÉRREZ; CÉSAR ORTIZ

    2011-01-01

    Se presenta un estudio sobre el comportamiento frente a la corrosión de barras de acero de refuerzo de un concreto de escoria activado alcalinamente. La escoria de alto horno fue activada mediante el uso de silicato sódico al 5% obteniéndose un material con buenas propiedades cementantes. Las probetas de concreto fueron fabricadas a partir de este cemento, después de mezclar con los agregados fueron reforzadas con barras de acero sismo-resistente ASTM-A706. Las probetas de concreto reforzado ...

  9. Estudio del efecto de los elementos microaleantes en un acero HSLA

    OpenAIRE

    Illescas Fernández, Silvia

    2007-01-01

    El presente Proyecto Final de Carera tiene como objeto de estudio un acero HSLA que es aquel que contiene cantidades no superiores a l0.15% de elementos de microaleación(V, Nb,TiyAl).Estos elementos generan un afino de grano y endurecimiento del material por lo que se consiguen elevados límites elásticos sin necesidad de añadir grandes cantidades de elementos aleantes, y por lo tanto sin un elevado coste addicional. Por ejemplo, respecto a un acero estructural, gracias a la pequeña cantidad d...

  10. Desarrollo de nuevos aceros sinterizados de alta resistencia aleados mecánicamente con Nb

    OpenAIRE

    Fuentes Pacheco, María Luz

    2012-01-01

    En aceros estructurales, la reducción del tamaño de grano es el único mecanismo que permite un aumento significativo tanto de la resistencia como de la tenacidad del material. Este criterio ha sido utilizado con éxito en los aceros microaleados, en los que la acción conjunta de tratamientos termomecánicos con la incorporación en la composición de pequeñas cantidades de elementos de microaleación conduce a una microestructura muy fina que proporciona una excelente combinación de propiedades. L...

  11. Comportamiento a fractura de dos aceros de ultraalto contenido en carbono

    Directory of Open Access Journals (Sweden)

    Fernández-Vicente, A.

    2001-04-01

    Full Text Available Two ultrahigh carbon steels containing 1.3 and 1.5 pet carbon have been tested for their plane-strain (Chevron-notch fracture toughness using Barker tests. The microstructure of these two materials consisted of fine carbides dispersed in a ferrite matrix. Fracture toughness of UHC-1.3 C was twice that of UHC-1.5 C. This result can be readily explained by means of the difference in size of the carbide particles found in each microstructure. The crack growth mechanism consisted of ductile tearing at the notch tip region followed by nucleation of a brittle crack at carbides. Crack propagation in the UHC-1.3 C specimen occurred unstably and smooth crack growth behavior was observed in UHC-1.5 C. The difference in crack growth behavior was attributed to the elastic energy stored in the grips, which was higher for the UHC-1.3 C test than for the UHC-1.5 C test.

    Se ha analizado la tenacidad a la fractura de dos aceros de ultraalto contenido en carbono, UAC, conteniendo 1,3% C y 1,5% C, los cuales poseían una microestructura de carburos esferoidales finos en una matriz de ferrita. Se ha empleado el ensayo Barker para determinar el comportamiento a fractura. La tenacidad obtenida en el acero UAC-1,3 C fue doble que la del acero UAC-1,5 C. Esto se explica a partir del tamaño de los carburos presentes en cada microestructura. El mecanismo de fractura en ambos aceros consiste, inicialmente, en desgarramiento dúctil de la zona de la punta de la entalla seguido de propagación frágil de una grieta nucleada en los carburos. La propagación de la grieta en el acero UAC-1,5 C se produjo de manera estable, mientras que en el acero UAC-1,3 C la grieta se propagó catastróficamente. La diferencia de comportamientos en el crecimiento de la grieta se atribuye a la mayor energía elástica acumulada por la mordaza para el acero UAC-1,3 C que para el acero UAC-1,5 C.

  12. ESTUDIO DEL DESGASTE EROSIVO POR CAVITACIÓN DE UN ACERO AUSTENÍTICO DE ALTO NITRÓGENO APOYADO EN EL USO DE LA DIFRACCIÓN DE ELECTRONES RETROPROYECTADOS-EBSD ASSESSMENT OF CAVITATION-EROSION WEAR OF A HIGH NITROGEN AUSTENITIC STAINLESS STEEL FROM ELECTRON BACKSCATTERING DIFFRACTION-EBSD

    Directory of Open Access Journals (Sweden)

    Dairo Hernán Mesa Grajales

    2010-08-01

    Full Text Available Muestras de acero inoxidable con estructura austenítica y contenido aproximado de nitrógeno de 0,9% en peso en solución sólida fueron sometidas a ensayos de cavitación vibratoria en agua destilada, con el fin de estudiar la evolución del desgaste erosivo por cavitación (EC a escala del tamaño de grano (mesoescala. Las muestras fueron obtenidas por medio de nitruración gaseosa a alta temperatura (HTGN del acero inoxidable dúplex UNS S31803, las cuales fueron caracterizadas por difracción de electrones retroproyectados (EBSD, a fin de obtener información de la orientación cristalina de los granos en la superficie a ser cavitada. La técnica de microscopía electrónica de barrido (SEM, fue usada para acompañar el proceso de desgaste para diferentes tiempos de ensayo. Como resultados de los ensayos de cavitación se determinó la pérdida de masa y se hizo un estudio secuencial de la apariencia superficial de las muestras para determinar los mecanismos de desgaste operantes en cada etapa. Los resultados fueron analizados a la luz de la caracterización cristalográfica previa. Para propósitos de comparación, fue usado el acero austenítico convencional UNS S30403. A partir de los resultados se observó que tanto la nucleación del daño como su evolución se dan de forma heterogénea a escala del tamaño de grano, resultado atribuido a la anisotropía en la deformación plástica. El carácter heterogéneo del daño por cavitación fue atribuido principalmente a las características de los límites de grano y a la microtextura dentro de los granos.Stainless steel samples with 100% austenitic microstructure and alloyed with 0.9 wt-% of nitrogen in solid solution were tested under vibratory cavitation experiments in distilled water to study the cavitation-erosion wear (EC at grain size level (mesoscale. Fully austenitic samples were obtained by high temperature gas nitriding (HTGN a commercially available dúplex stainless steel, UNS

  13. Measuring secondary phases in duplex stainless steels

    Science.gov (United States)

    Calliari, I.; Brunelli, K.; Dabalà, M.; Ramous, E.

    2009-01-01

    The use of duplex stainless steels is limited by their susceptibility to the formation of dangerous intermetallic phases resulting in detrimental effects on impact toughness and corrosion resistance. This precipitation and the quantitative determinations of the phases have received considerable attention and different precipitation sequences (σ phase, χ phase, and carbides) have been suggested. This study investigates the phase transformation during continuous cooling and isothermal treatments in commercial duplex stainless steel grades and the effects on alloy properties, and compares the most common techniques of analysis.

  14. COMPARACION TECNICO-FINANCIERA DEL ACERO ESTRUCTURAL Y EL HORMIGON ARMADO

    Directory of Open Access Journals (Sweden)

    MIGUEL DAVID ROJAS LOPEZ

    2008-01-01

    Full Text Available Este trabajo presenta un análisis comparativo de las propiedades operativas, estéticas, mecánicas, económicas y financieras de los sistemas constructivos en acero estructural y hormigón armado, con el fin de establecer criterios de escogencia para la construcción en Colombia.

  15. Investigation of corrosion resistance property of cold deformed (bended) duplex and super duplex stainless steel tubes

    OpenAIRE

    Dotel, Utsav Raj

    2014-01-01

    Cold deformation (bending) of stainless steel tubes is one of the efficient and cost effective methods to gain the required shapes of the tube that can be useful for different practical applications. Different mechanical properties can change after the plastic deformation of the material. The purpose of this study is to investigate the corrosion (basically pitting) resistant property of cold deformed Duplex and Super Duplex materials namely UNS S32205 and UNS S32750 respectively. The bended t...

  16. Ultra-short silicon MMI duplexer

    Science.gov (United States)

    Yi, Huaxiang; Huang, Yawen; Wang, Xingjun; Zhou, Zhiping

    2012-11-01

    The fiber-to-the-home (FTTH) systems are growing fast these days, where two different wavelengths are used for upstream and downstream traffic, typically 1310nm and 1490nm. The duplexers are the key elements to separate these wavelengths into different path in central offices (CO) and optical network unit (ONU) in passive optical network (PON). Multimode interference (MMI) has some benefits to be a duplexer including large fabrication tolerance, low-temperature dependence, and low-polarization dependence, but its size is too large to integrate in conventional case. Based on the silicon photonics platform, ultra-short silicon MMI duplexer was demonstrated to separate the 1310nm and 1490nm lights. By studying the theory of self-image phenomena in MMI, the first order images are adopted in order to keep the device short. A cascaded MMI structure was investigated to implement the wavelength splitting, where both the light of 1310nm and 1490nm was input from the same port, and the 1490nm light was coupling cross the first MMI and output at the cross-port in the device while the 1310nm light was coupling through the first and second MMI and output at the bar-port in the device. The experiment was carried on with the SOI wafer of 340nm top silicon. The cascaded MMI was investigated to fold the length of the duplexer as short as 117μm with the extinct ratio over 10dB.

  17. Duplex stainless steels for osteosynthesis devices.

    Science.gov (United States)

    Cigada, A; Rondelli, G; Vicentini, B; Giacomazzi, M; Roos, A

    1989-09-01

    The austenitic stainless steels used today for the manufacture of osteosynthesis devices are sensitive to crevice corrosion. In this study the corrosion properties of some duplex stainless steels were evaluated and compared to traditional austenitic stainless steels. According to our results the following ranking was established: 23Cr-4Ni less than AISI 316L less than ASTM F138 less than 22Cr-5Ni-3Mo less than 27Cr-31Ni-3.5Mo less than 25Cr-7Ni-4Mo-N. In particular the results showed that the high-performance 25Cr-7Ni-4Mo-N duplex stainless steel, with high molybdenum and nitrogen contents, can be considered not susceptible to crevice corrosion in the human body. The duplex stainless steels have also better mechanical properties at the same degree of cold working compared with austenitic stainless steels. Hence the 25Cr-7Ni-4Mo-N duplex stainless steel can be considered a convenient substitute of ASTM F138 for orthopedic and osteosynthesis devices. PMID:2777835

  18. Initial oxidation of duplex stainless steel 2205

    Energy Technology Data Exchange (ETDEWEB)

    Donik, E.; Kocijan, A.; Jenko, M. [Institute of metals and technology, Ljubljana (Slovenia)

    2009-07-01

    Due to superior mechanical and corrosion properties of duplex stainless steels which result in weight reduction of the constructions, thus contributing to the decreases in total costs and also due to the large and versatile usage of the alloy, duplex stainless steel is gradually displacing stainless steels of the AISI 300 series. Pickling of duplex stainless steel has proven to be much more difficult than that of standard austenitic grade (AISI 300 series). There is no complete agreement in the literature on scale (high temperature oxidation) dissolution mechanism in neutral pickling solutions. During annealing, duplex stainless steel is heated in annealing furnace up to 1050 C and is kept at this temperature for some time to soften the metal in order to release the work hardening induced by hot and cold rolling. The elimination of surface defects by forming the oxide scale is required to improve the corrosion resistance. Three different techniques were used to produce thin oxide layers on polished and sputter cleaned duplex stainless steel samples. They were exposed to 10{sup -5} mb pure oxygen inside the vacuum chamber, exposed to ambient conditions for 24 hours and plasma oxidized. Oxide layers thus produced were analysed using XPS depth profiling for determination of the oxide layer's composition with depth. It was found that all techniques produce oxide layer with different traces of metallic components and with chromium oxide maximum concentration shifted towards the oxide layer - bulk metal interface. Depletion of Cr in bulk immediately below the interface was also observed. Simplified ARXPS procedure was used to corroborate thickness estimates for thinnest oxide layers. (authors)

  19. Aceros de baja aleación y alto rendimiento

    Directory of Open Access Journals (Sweden)

    Campos, M.

    2008-02-01

    Full Text Available A highly demanding automobile market requires an intensification of the efforts on increasing the performance and reducing costs of sintered steels, in order to stay in such a competitive market. Final properties of sintered parts and their cost depend on two main factors, density and the alloying system. The growing interest for Cr and Mn as alloying elements is due to both price, more suitable than Mo, and the excellent level of properties which are achieved in assintered parts as well as after the heat treatments. In this work, the possible techniques which lead to an enhancement of density are discussed, such as warm and high velocity compaction, or high temperature sintering; moreover it is important to study the synergy between the proposed techniques which may be compatible.

    Las nuevas demandas en el sector del automóvil están haciendo que se intensifiquen los esfuerzos en aumentar las prestaciones y reducir los costes de los aceros sinterizados, para poder mantenerse en este mercado tan competitivo. Las propiedades finales de los componentes sinterizados y su coste dependen de dos factores principales, la densidad y el sistema de aleación. El creciente interés por el cromo y el manganeso como elementos de aleación se debe tanto al precio, más ventajoso que, por ejemplo, el molibdeno, como al nivel excelente de propiedades que se pueden conseguir tanto en estado sinterizado como después de los tratamientos térmicos. En este trabajo, se discuten además las posibles técnicas que conducen a una mejora de la densidad del componente, como la compactación de polvos precalentados, la compactación por propagación de ondas de impacto, o la sinterización a alta temperatura; además, es importante estudiar los efectos sinérgicos entre las técnicas propuestas que sean compatibles.

  20. Aplicação da norma astm A923-Prática a para identificação de fases intermetálicas em junta soldada de aço inoxidável superduplex UNS 32750 ASTM A923-Practice A application to identify intermetallic phases in a UNS S32750 superduplex welded joint

    Directory of Open Access Journals (Sweden)

    Sérgio Duarte Brandi

    2010-03-01

    Full Text Available Os aços inoxidáveis duplex e superduplex apresentam propriedades superiores aos aços inoxidáveis convencionais. Essa superioridade é baseada na composição química e em uma microestrutura balanceada (aproximadamente 50% de ferrita. Durante a soldagem podem ocorrer alterações, tanto na composição química, como na fração volumétrica das fases presentes, que podem gerar a presença de fases intermetálicas, que alteram as propriedades originais desses aços. O objetivo deste trabalho é de aplicar a norma ASTM A923-Prática A para verificar a presença de fases intermetálicas na junta soldada de aço inoxidável superduplex UNS 32750. Foram soldados tubos de UNS 32750 com diâmetros externos de 18 e 44 mm e espessura de 1,5 mm. O processo utilizado foi o TIG orbital, com adição de 25Cr-10Ni-4Mo e diâmetro de 0,8 mm. O metal de base e as juntas soldadas foram caracterizados tanto em microscopia óptica como em microscopia eletrônica de varredura. Os resultados mostraram que não houve a precipitação de fases intermetálicas detectadas pela norma ASTM A923, porém na ZAC dos dois tubos estudados apareceram pequenas regiões com precipitação de nitretos de cromo, que também podem alterar as propriedades das juntas soldadas.Duplex and superduplex stainless steels present superior mechanical and corrosion properties when compared to usual stainless steels. This superiority is based on chemical composition when in a balanced microstructure (approximately 50% of ferrite. During welding, changes may occur in both, the chemical composition and volume fraction of phases in the material, which may generate the presence of intermetallic phases and, as a consequence, modify the mechanical and corrosion properties of this group of stainless steels. The objective of this work is to apply ASTM A923- Practice A to verify the presence of intermetallic phases in welded joints of UNS 32750 su-perduplex stainless steel. Tubes of UNS 32750, with

  1. Renal duplex Doppler ultrasound findings in diabetics

    International Nuclear Information System (INIS)

    The correlation between clinical-laboratory findings and renal duplex Doppler ultrasound findings was studied in 45 patients with diabetes mellitus to see the role of duplex Doppler ultrasound in the detection of diabetic nephropathy. The resistive indices in patients with elevated serum creatinine, BUN, proteinuria, and systolic blood pressure levels were statistically significantly higher than those in patients with normal levels (p<0.05). Also resistive indics in patients with retinopathy were higher than that in patients without retinopathy (p<0.05). But the ultrasound morphologic changes of kidney such as renal length, cortical eye-catching, and corticomedullarycontrast were not well correlated with clinical-laboratory data and resistive index. The resistive index of the kidney in conjunction with clinical-laboratory data in diabetics may be helpful in the evaluation of diabetic nephropathy

  2. Cyclic deformation of duplex stainless steels

    OpenAIRE

    Mateo García, Antonio Manuel; Gironés, Ana

    2011-01-01

    Duplex stainless steels configure a family of metallic alloys that combined elevated mechanical properties with improved corrosion resistance when compared to standard austenitic grades. This excellent combination of properties leads to their use under many different applications, particularly in the fields of chemical, petrochemical, pulp and paper industries. Moreover, these applications usually involve cyclic loading, and consequently the study of fatigue properties has a great significanc...

  3. A Duplex Stainless Steel for Chloride Environments

    Science.gov (United States)

    Sridhar, N.; Kolts, J.; Flasche, L. H.

    1985-03-01

    This paper examines the effects of microstructural changes on the corrosion, stress corrosion cracking and corrosion fatigue resistance of a duplex stainless steel to chloride environments. The microstructural changes can be precipitation of phases such as sigma and carbides, or changes in the distribution of austenite and ferrite. The former can be important in hot forming operations while the latter is important in welding. The methods of minimizing these deleterious effects can sometimes be different from those used for austenitic stainless steel.

  4. Thermal ageing of duplex stainless steels

    International Nuclear Information System (INIS)

    The evolution of the mechanical properties of Mobearing anf Mo-free cast duplex stainless steels, induced by long term ageing in the range 300-400 deg C, has been studied in relation with the evolution of their microstructure. The unmixing of the ferritic Fe-Cr-Ni, solid solution by three-dimensional (sponge-like) spinodal decomposition and the precipitation of intermetallic G-phase particles are the main characteristics of this microstructural evolution

  5. Fracture toughness properties of duplex stainless steels

    OpenAIRE

    Sieurin, Henrik

    2006-01-01

    Good toughness properties in base and weld material enable the use of duplex stainless steels (DSS) in critical applications. DSS offer high strength compared to common austenitic stainless steels. The high strength can be utilized to reduce the wall thickness and accordingly accomplish reduction of cost, welding time and transportation weight, contributing to ecological and energy savings. Although DSS have been used successfully in many applications the last decades, the full utilisation in...

  6. Hot workability of duplex stainless steels

    OpenAIRE

    Martin, Guilhem

    2011-01-01

    The Duplex Stainless Steels (DSS) are defined as a family of stainless steels consisting of a two-phase microstructure involving δ-ferrite and γ-austenite. Exceptional combinations of strength and toughness together with good corrosion resistance under critical working conditions designate DSS a suitable alternative to conventional austenitic stainless steels. Unfortunately, the relatively poor hot workability of these alloys makes the industrial processing of flat products particularly criti...

  7. Full duplex communication using visible light

    CERN Document Server

    Yang, Yongchao; Li, Yuanhang; Gao, Xumin; Yuan, Jialei; Zhu, Hongbo; Wang, Yongjin

    2016-01-01

    In this work, we propose, fabricate and characterize a full duplex communication system using visible light on a single chip. Both the suspended p-n junction InGaN/GaN multiple quantum well (MQW) devices and the suspended waveguides are obtained on a GaN-on-silicon platform by wafer-level processing. Two suspended p-n junction InGaN/GaN MQW devices that can both emit and detect light simultaneously are connected using suspended waveguides to form an in-plane visible light communication (VLC) system. The light that is emitted from one suspended p-n junction InGaN/GaN MQW device can induce a current in the device located at the other end of the waveguide via in-plane light coupling, thus leading to full duplex communication using visible light. This proof-of-concept in-plane VLC system paves the way towards the implementation of a full duplex communications system operating at the same frequency using visible light on a single chip.

  8. Interpretation of peripheral venous duplex testing.

    Science.gov (United States)

    Barleben, Andrew; Bandyk, Dennis F

    2013-01-01

    Venous duplex ultrasound and plethysmography are used to evaluate patients for suspected deep venous thrombosis (DVT) or venous insufficiency symptoms. Testing can provide clinicians with detailed information on location, extent, and severity of venous conditions before and after treatment. Duplex ultrasound can image the venous system from the vena cava to the peripheral veins, including veins of the calf musculature, and is the recommended technique to diagnose DVT. Accurate interpretation of venous testing requires an understanding of venous hemodynamics, including normal flow phasicity with cardiac and respiratory motion and the changes produced by acute DVT. Duplex scanning provides a roadmap of vein anatomy similar to contrast venography and essential hemodynamic information about the presence of proximal obstruction, vein valve function, and perforator vein reflux. Indications for testing include the diagnosis of acute/chronic DVT and evaluation of patients with venous insufficiency manifested as edema, varicose veins, or ambulatory venous hypertension. Venous plethysmography, an indirect physiologic test, can be used to estimate severity of obstructive or reflux venous pathophysiology and document improvement in venous hemodynamics after intervention. Using criteria based on ultrasound imaging and physiologic testing, venous conditions producing a swollen or painful limb can be accurately determined and aid in appropriate treatment selection. PMID:24636608

  9. Development of a lean duplex stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Liljas, M.; Johansson, P.; Liu Hui-Ping; Olsson, C.O.A. [Avesta Research Centre, Avesta (Sweden). Outokumpu Stainless

    2008-06-15

    The classic series of duplex stainless steels shows very high corrosion resistance and can be used for very demanding applications. A new lean duplex steel, LDX 2101 {sup registered} (EN 1.4162, UNS S32101), has been developed with corrosion resistance on a par with standard austenitic grades. Application areas include: structural components, chemical industry, tanks and containers. The steel was designed to have equal amounts of ferrite and austenite in annealed condition and with an austenite that is stable against strain-induced martensite. Thanks to its high nitrogen content, the steel has a fast austenite reformation when subjected to thermal cycling, e.g. welding. Unlike conventional duplex grades, the formation of intermetallic phase is very sluggish, although precipitation of nitrides and carbides has a certain impact on material properties after exposure in the temperature range 600 to 800 C. The precipitation behaviour after different isothermal treatments is described and its influence on different product properties is shown. A good agreement was found between impact toughness and corrosion resistance for a wide range of thermal treatments. (orig.)

  10. Development of oxide dispersion strengthened 2205 duplex stainless steel composite

    OpenAIRE

    Oladayo OLANIRAN; Peter Apata OLUBAMBI; Benjamin Omotayo ADEWUYI; Joseph Ajibade OMOTOYINBO; Ayodeji Ebenezar AFOLABI; Davies FOLORUNSO; Adekunle ADEGBOLA; Emanuel IGBAFEN

    2015-01-01

    Composites of duplex stainless steel were produced by oxide dispersion strengthening with comparatively improved mechanical properties by hot press sintering of partially stabilized Zirconia (PSZ, 3% yttria, mole fraction) dispersion in 2205 duplex stainless steels. Ceramic oxide was added as reinforcement, while chromium (Cr) and Nickel (Ni) were incorporated to maintain the austenitic/ferritic phase balance of the duplex stainless steel. The powders and sintered were characterized in detail...

  11. Thermodynamics of RNA duplexes modified with unlocked nucleic acid nucleotides

    OpenAIRE

    Pasternak, Anna; Wengel, Jesper

    2010-01-01

    Thermodynamics provides insights into the influence of modified nucleotide residues on stability of nucleic acids and is crucial for designing duplexes with given properties. In this article, we introduce detailed thermodynamic analysis of RNA duplexes modified with unlocked nucleic acid (UNA) nucleotide residues. We investigate UNA single substitutions as well as model mismatch and dangling end effects. UNA residues placed in a central position makes RNA duplex structure less favourable by 4...

  12. Estimación del Esfuerzo de Fluencia de Soldaduras de Aceros Microaleados

    OpenAIRE

    Edgar López Martínez; Octavio Vázquez Gómez; Bernardo Fabián Campillo Illanes

    2014-01-01

    Se diseñó una red neuronal artificial (RNA) para estimar el esfuerzo de fluencia en función de la composición química y dureza de aceros microaleados de alta resistencia (HSLA) y aceros de alta resistencia (HSS). La información necesaria para la RNA se obtuvo mediante la búsqueda en la literatura para construir una base de datos. El diseñó de la RNA fue del tipo perceptón multicapa con una regla de aprendizaje de propagación hacia atrás y función de transferencia sigmoidal, variando el número...

  13. Reflexión sobre la industria del acero en el mercado globalizado

    Directory of Open Access Journals (Sweden)

    Luis Felipe Camacho Carvajal

    2011-06-01

    Full Text Available El propósito de este ensayo es hacer un seguimiento a la evolución de la producción de acero en elmundo. Se evidencia que el resultado de la estrategia de adquisiciones y fusiones de poderosas empresas del sector siderúrgico a nivelmundial, llevó a que China pasara de ser un país netamente importador a ser exportador de materia prima de la cadena siderúrgica, alimentando una nueva etapa de crecimiento y desarrollo de esta cadena. El análisis de las cifras de acero en Suramérica referidas a producción, flujos de comercio y consumo aparente sugiere que la región no demanda lo que produce.

  14. Tratamiento térmico de acero cubano // Thermal treatment of cuban steel

    Directory of Open Access Journals (Sweden)

    N. Caballero Stevens

    2001-01-01

    Full Text Available En este trabajo se muestran algunos de los resultados obtenidos durante la investigación de un nuevo acero cubano que sepretende destinar a la fabricación de elementos de corte para máquinas combinadas cortadoras de caña de azúcar,herramientas de mano y otras piezas de gran responsabilidad que requieren elevada dureza para su trabajo. En el trabajo sepresentan los aspectos principales que relacionan la composición química, microestructura y dureza de este acero. Seestablecen experimentalmente las temperaturas de los puntos críticos para definir los regímenes de tratamiento térmico. Seincluye el comportamiento de las propiedades de dureza ante diferentes regímenes de tratamiento térmico.Palabras claves: Acero, recocido, temple, revenido, martensita, dureza________________________________________________________________________________AbstractIn this article are shown some of the results obtained during the investigation of a new cuban steel that it is going to beused in the manufacture of blades for cane cutting machines, hand tools and other part of great responsibility that requirehigh hardness for the job.In the article are presented the principles aspects of quimical composition, microstructure and hardness of this steel. Thereare stablished experimentally the temperature of the critic points in order to determine the regimes of the thermal treatment.The behavior of the properties of hardness is included at different regimes of thermal treatment.Key words: Steel, thermal treatment, quenching, tempering, hardness.

  15. ESTUDIO DE LA CORROSIÓN DEL ACERO EMBEBIDO EN CONCRETO AAS SOMETIDO A CLORUROS

    Directory of Open Access Journals (Sweden)

    ROBINSON TORRES GÓMEZ

    2010-01-01

    Full Text Available Se presenta un estudio sobre el comportamiento frente a la corrosión de barras de acero de refuerzo de un concreto de escoria activado alcalinamente. La escoria de alto horno fue activada mediante el uso de silicato sódico al 5% obteniéndose un material con buenas propiedades cementantes. Las probetas de concreto fueron fabricadas a partir de este cemento, después de mezclar con los agregados fueron reforzadas con barras de acero sismoresistente ASTMA706. Las probetas de concreto reforzado estuvieron sometidas en ambientes contaminados con iones cloruro para simular condiciones marinas. La evaluación electroquímica se realizo aplicando las técnicas de resistencia a la polarización lineal (LPR y espectroscopia de impedancia electroquímica (EIS. Se logra determinar el comportamiento de la capa pasiva del acero y electroquímico del metal cuando está inmerso en estos materiales cerámicos novedosos.

  16. AUMENTO EN LA RESISTENCIA A LA CORROSIÓN DE UN ACERO T91 ALUMINIZADO

    Directory of Open Access Journals (Sweden)

    LUZ S. QUINTERO

    2011-01-01

    Full Text Available El acero ferrítico T91 ha sido ampliamente utilizado en plantas de generación de energía eléctrica, calderas y plantas nucleares. Sin embargo, su resistencia a la oxidación se ve gravemente afectada a temperaturas superiores a los 600ºC. En esta investigación se empleó la técnica de cementación empacada para aluminizar un acero T91 y se encontraron las condiciones óptimas para la formación de un recubrimiento libre de porosidad y con espesor uniforme (300 micras. Se evaluó la capa de óxido formada luego de una exposición a 800ºC en atmósfera de aire. La caracterización del recubrimiento y de la capa de óxido (Al2O3 se llevó a cabo empleando un microscopio electrónico de barrido (SEM, Espectroscopia de Rayos X (EDX y mapping. Se comprobó una buena resistencia a la oxidación del acero T91 aluminizado, debido a la formación de una fina capa continua de óxido de aluminio de aproximadamente 6 micras de espesor luego de una exposición de 7 días.

  17. Influencia sobre los tratamientos térmicos del contenido de aluminio de aceros no aleados

    Directory of Open Access Journals (Sweden)

    Carreras, L.

    1999-08-01

    Full Text Available The main purpose of this article is to determine the optimal level of aluminum content in plain steels to have the optimal mechanical properties by means of surface heat treatments. Various plain steels with different aluminium content have been studied. The importance of treatment temperature is analyzed. The influence of other factors, like nitrogen content or the homogenous distribution of particles, is evaluated. It is concluded that the aluminum composition of plain steels that are subjected to heat treatments should not exceed 0.02 %.

    El objetivo de este trabajo es determinar el intervalo óptimo de contenidos de aluminio en aceros no aleados para los que se consiguen las propiedades mecánicas óptimas mediante tratamientos térmicos de superficie. Se estudian diferentes coladas de acero en las que varía el contenido de aluminio y las temperaturas de tratamiento. Se evalúa la importancia de otros factores tales como el contenido de nitrógeno y la homogeneidad en la distribución de partículas endurecedoras. Se llega a la conclusión de que los aceros no aleados destinados a tratamientos térmicos no deben tener un contenido de aluminio superior al 0,02 %.

  18. Diseño de nuevos aceros bainíticos.

    Directory of Open Access Journals (Sweden)

    Caballero, F. G.

    2002-02-01

    Full Text Available Mixed microstructures consisting of fine plates of upper bainitic ferrite separated by thin films of stable retained austenite have seen many applications in recent years because of their impressive combination of strength and toughness. There may also be some martensite present in the microstructure, but its formation can be controlled increasing the stability of the retained austenite. On the other hand, carbides are avoided by the judicious use of silicon as an alloying element. The aim of the present work was to see how far these concepts can be extended in order to achieve the highest ever combination of strength and toughness in bulk-samples subjected to continuous cooling transformation. Three alloys were proposed and manufactured, and the results of metallographic characterisation and mechanical tests have shown that the designed steels have the highest ever combination of strength and toughness for bainitic microstructures, matching even the maraging steels which are at least thirty times more expensive. The experimental results confirm the alloy design procedures.

    En los últimos años se han diseñado aceros con microestmcturas formadas por placas de ferrita bainítica superior y finas regiones de austenita retenida que, por su excelente combinación de propiedades de resistencia y tenacidad, han sido empleados para numerosas aplicaciones. Aunque en estas microestructuras puede haber algo de martensita, su formación puede controlarse aumentando la estabilidad de la austenita retenida. Por otra parte, la presencia de carburos en la bainita, causa de importantes disminuciones de tenacidad en los aceros bainíticos convencionales, se evita gracias al uso del silicio como elemento de aleación. El objetivo de este trabajo es estudiar la posibilidad de optimizar la citada combinación de propiedades, generalmente antagónicas, en muestras masivas para aplicación industrial sujetas a transformaciones por enfriamiento continuo. Para

  19. Ductilidad en caliente y mecanismos de fractura de un acero de construcción

    Directory of Open Access Journals (Sweden)

    Calvo, J.

    2006-02-01

    Full Text Available The hot ductility of a structural steel produced from scrap recycling has been studied to determine the origin of the transverse cracks in the corners that appeared in some billets. Samples extracted both from a billet with transverse cracks and from a billet with no external damage were tested. To evaluate the influence of residual elements and inclusions, the steel was compared to another one impurity free. Reduction in area of the samples tensile tested to the fracture was taken as a measure of the hot ductility The tests were carried out at temperatures ranging from 1000ºC to 650ºC and at a strain rate of 1·10- 3 s-1. The fracture surfaces of the tested samples were observed by scanning electron microscopy in order to determine the embrittling mechanisms that could be acting. The steel with residuals and impurities exhibited lower ductility values for a wider temperature range than the clean steel. The embrittling mechanisms also changed as compared to the impurity free steel.

    Se evaluó la ductilidad en caliente de un acero de construcción procedente del reciclaje de chatarra con el fin de determinar el origen de las grietas transversales que aparecen en las esquinas de algunas palanquillas. Para ello, se extrajeron probetas de dos palanquillas de una misma calidad de acero. Una de las palanquillas había presentado agrietamiento transversal al ser colada y, la otra, no. Para conocer la influencia de los elementos residuales e inclusiones en la ductilidad en caliente, otro acero, con la misma composición pero sin impurezas, se fabricó en laboratorio y fue sometido al mismo análisis que los aceros comerciales. La ductilidad en caliente se midió como la reducción del área de las probetas ensayadas a tracción hasta la rotura. Las condiciones a las que se realizaron los ensayos fueron temperaturas de 1.000 a 650 ºC y a una velocidad de deformación de 1·10-3 s-1. Las superficies de fractura de las probetas ensayadas se

  20. Duplex tube steam reformer development program

    International Nuclear Information System (INIS)

    Work done in partial fulfillment of Task 7 of the Duplex Steam Reformer Development Program is described. The DSR concept acts as a double barrier between a process heat high temperature reactor plant (PNP) and a closed loop chemical heat pipe (CHP) for the long distance transport of chemical energy to a remote industrial user. The current state of the DSR design is described as well as related systems and equipment. The PNP concept presented is based upon work currently underway in the Federal Republic of Germany

  1. Fatigue properties of duplex stainless steel

    OpenAIRE

    Turrel, Benjamin; Luna Garcia, Jordi; Andraschko, Stephan

    2009-01-01

    PFC presentat a Oslo University College The aim of the project is to study fatigue properties of duplex stainless steel used for a bridge. The samples had to be tested and the results have to be compared with the theory, studied before. Six specimens have been broken by tensile fatigue testing machine in order to get more knowledge about the lifetime and the behavior under dynamic stress and not only for welded parts. Out of this new knowledge a new fatigue curve for this ma...

  2. Scintigraphic features of duplex kidneys on DMSA renal cortical scans.

    Science.gov (United States)

    Kwatra, Neha; Shalaby-Rana, Eglal; Majd, Massoud

    2013-09-01

    The spectrum of manifestations of duplex kidneys on (99m)Tc-dimercaptosuccinic acid (DMSA) renal cortical scans and correlating findings on other imaging modalities are presented. Relevant embryology of the duplex systems and technical aspects of DMSA scintigraphy are reviewed.

  3. RF Self-Interference cancellation for Full-Duplex

    NARCIS (Netherlands)

    Liempd, van B.; Debaillie, B.; Craninckx, J.; Lavin, C.; Palacios, C.; Malotaux, S.; Long, J.R.; Broek, van den J.D.; Klumperink, E.A.M.

    2014-01-01

    This paper proposes two RF self-interference cancellation techniques. Their small form-factor enables full-duplex communication links for small-to-medium size portable devices and hence promotes the adoption of full-duplex in mass-market applications and next-generation standards, e.g. IEEE802.11 an

  4. Structural Properties of G,T-Parallel Duplexes

    Directory of Open Access Journals (Sweden)

    Anna Aviñó

    2010-01-01

    Full Text Available The structure of G,T-parallel-stranded duplexes of DNA carrying similar amounts of adenine and guanine residues is studied by means of molecular dynamics (MD simulations and UV- and CD spectroscopies. In addition the impact of the substitution of adenine by 8-aminoadenine and guanine by 8-aminoguanine is analyzed. The presence of 8-aminoadenine and 8-aminoguanine stabilizes the parallel duplex structure. Binding of these oligonucleotides to their target polypyrimidine sequences to form the corresponding G,T-parallel triplex was not observed. Instead, when unmodified parallel-stranded duplexes were mixed with their polypyrimidine target, an interstrand Watson-Crick duplex was formed. As predicted by theoretical calculations parallel-stranded duplexes carrying 8-aminopurines did not bind to their target. The preference for the parallel-duplex over the Watson-Crick antiparallel duplex is attributed to the strong stabilization of the parallel duplex produced by the 8-aminopurines. Theoretical studies show that the isomorphism of the triads is crucial for the stability of the parallel triplex.

  5. Efecto de la Nitruración a Plasma en el Endurecimiento por Precipitación del Acero 15-5 PH Plasma Nitriding Effect on Precipitation Hardening of 15-5 PH Steel

    Directory of Open Access Journals (Sweden)

    A. Moreno

    2005-01-01

    Full Text Available Acero inoxidable endurecible por precipitación, 15-5 PH, fue sometido a un ciclo térmico de tratamiento combinando el envejecimiento y la nitruración por plasma en un mismo ciclo. Se aplicaron diversos ciclos térmicos cuyo principal objetivo fue verificar la evolución de la dureza del núcleo del material y de la superficie conforme la condición de tratamiento. En todos los ciclos térmicos ocurrió el endurecimiento del núcleo por precipitación y de la superficie por la formación de una capa nitrurada. La variable tiempo fue mantenida en 2 horas y la atmósfera utilizada fue 25% de Nitrógeno, 75% Hidrógeno. La dureza superficial y del núcleo fueron evaluadas a través de ensayos Vickers HV 10. El perfil de dureza de la capa nitrurada fue evaluado a través de ensayos de microdureza Vickers con carga 50g. Se concluyó en este trabajo que el tratamiento de endurecimiento por precipitación y el endurecimiento superficial por nitruración a plasma pueden ser realizados de forma conjunta.Stainless steel precipitation hardening was evaluated by the thermal treatment for precipitation combined with plasma nitriting surface hardening treatment of 15-5 PH steel. Several thermal treatments were applied to study the core and surface hardness evolution during the treatment process. The core hardness was improved by the precipitation and the surface as well as by the nitrided layer for all the conditions used. For all the samples the same time (2 hours was used and the same nitriding gas mixture (25% Nitrogen and 75% Hydrogen was employed. Metalographic analysis, Vickers HV10, and microVickers test 50g were used to study the behavior of the steel. The results show that the precipitation hardening and plasma nitriding can be done using the same cycle to improve core and surface hardening.

  6. Análisis térmico de soldadura GTAW sobre placa de acero AISI 316L empleando el método de elementos finitos GTAW welding thermal analysis on AISI 316L steel plate using the finite elements method

    Directory of Open Access Journals (Sweden)

    Juan A. Pozo-Morejón

    2011-09-01

    Full Text Available En el presente trabajo se realiza la modelación térmica de soldadura GTAW sobre placa de acero inoxidable AISI 316L. Se analizan los aspectos teóricos más relevantes a considerar durante la ejecución de un análisis de este tipo. En la simulación se emplea un software de análisis por elementos finitos de uso general y se enriquece una metodología, previamente desarrollada, para la modelación en 3D no lineal transitoria del proceso de soldeo. En dicha metodología se implementa una subrutina en lenguaje APDL, programada con el modelo volumétrico de fuente calor de doble elipsoide, en un sistema de coordenadas cartesiano. Se analiza la influencia del paso de tiempo seleccionado sobre los resultados de la simulación. Finalmente se valida la metodología enriquecida, en base a la correlación de los resultados del modelo respecto a los resultados experimentales.In the present work, thermal modeling of GTAW welding on AISI 316L stainless steel plate is presented. More relevant theoretical aspects to be considered during the implementation of an analysis of this type are discussed. For the simulation a general purpose finite element analysis software has been used. A previously developed methodology for 3D nonlinear transient modeling of welding process has also been improved. In this methodology a subroutine in APDL language is implemented, programmed with the double ellipsoid volumetric heat source model, in a Cartesian coordinated system. The influence of the selected time step on the simulation results is analyzed. The good correlation obtained among the results calculated by means of the model and the experimental data validates this improved methodology.

  7. Corrosion behavior of 2205 duplex stainless steel.

    Science.gov (United States)

    Platt, J A; Guzman, A; Zuccari, A; Thornburg, D W; Rhodes, B F; Oshida, Y; Moore, B K

    1997-07-01

    The corrosion of 2205 duplex stainless steel was compared with that of AISI type 316L stainless steel. The 2205 stainless steel is a potential orthodontic bracket material with low nickel content (4 to 6 wt%), whereas the 316L stainless steel (nickel content: 10 to 14 wt%) is a currently used bracket material. Both stainless steels were subjected to electrochemical and immersion (crevice) corrosion tests in 37 degrees C, 0.9 wt% sodium chloride solution. Electrochemical testing indicates that 2205 has a longer passivation range than 316L. The corrosion rate of 2205 was 0.416 MPY (milli-inch per year), whereas 316L exhibited 0.647 MPY. When 2205 was coupled to 316L with equal surface area ratio, the corrosion rate of 2205 reduced to 0.260 MPY, indicating that 316L stainless steel behaved like a sacrificial anode. When 316L is coupled with NiTi, TMA, or stainless steel arch wire and was subjected to the immersion corrosion test, it was found that 316L suffered from crevice corrosion. On the other hand, 2205 stainless steel did not show any localized crevice corrosion, although the surface of 2205 was covered with corrosion products, formed when coupled to NiTi and stainless steel wires. This study indicates that considering corrosion resistance, 2205 duplex stainless steel is an improved alternative to 316L for orthodontic bracket fabrication when used in conjunction with titanium, its alloys, or stainless steel arch wires. PMID:9228844

  8. Recubrimientos de aluminio-silicio sobre acero inoxidable austenítico AISI 304 Y 317 por deposición química de vapor en lecho fluidizado

    Directory of Open Access Journals (Sweden)

    José Luddey Marulanda Arevalo

    2014-07-01

    Full Text Available Aluminum-silicon coatings were deposited onto stainless steels AISI 304 and AISI 317. The deposition was performed at 540°C with a ratio of active gases HCl/H2 of 1/15.3; argon was used as a carrier gas. The bed of the FBR-CVD process consisted of 2.5 g aluminum powder, 7.5 g silicon powder and 90 g alumina. After the coatings were deposited, each sample was given a heat treatment to improve its mechanical properties and oxidation behavior by diffusing the alloying elements. Thermodynamic simulation was performed with Thermo-Calc software to investigate the composition of the deposited material. The coated and uncoated specimens were exposed to temperatures of 750ºC in an atmosphere where the vapor was transported to the samples using a flow of N2 of 40 ml/min and 100% water vapor (H2O. The coated specimens gained little weight during the thousand hours of exposure and will thus guard against a corrosive attack compared to the uncoated substrates. In addition, the coated stainless steels show an oxidation rate with a logarithmic trend while the uncoated steel oxidation rate showed a linear trend.

  9. Ionic implantation by plasma in titanium and stainless steels used in prosthesis and medical instruments; Implantacion ionica por plasma en titanio y aceros inoxidables usados en protesis e instrumental medico

    Energy Technology Data Exchange (ETDEWEB)

    Munoz C, A. E. [ININ, 52750 La Marquesa, Estado de Mexico (Mexico)

    2008-07-01

    A study of a process known as plasma immersion ion implantation (PIII) of nitrogen at low voltages (< 4 kV) into three kind of samples: 1) austenitic stainless AISI 316-L steel plates, 2) ferritic stainless AISI 434 steel-based dentistry drills and 3) commercially pure titanium (CPTi) disks. On the case of CPTi the study was conducted in nitrogen- oxygen calibrated mixtures: 90% N-10% O, 80% N-20% O, 70% N-30% O and in 99.5% pure oxygen and 99.9% pure nitrogen. The PIII process was carried out by using a direct current plasma source controlled both in voltage and current, a negative voltage pulse modulator, a stainless AISI 304 steel vacuum chamber and a rod of the same material, horizontally located in the upper region of the chamber, which plays the role of anode in the plasma discharge. The purpose of the nitriding is forming a relatively thick layer on the surface of the steel specimens in order to enhance their both microhardness and general corrosion performances, desirable in medical applications. This layer contains interstitial nitrogen atoms ({approx}24% at.) which gives place to a deformed lattice (expanded phase) of the steel. Vickers microhardness and potentiodynamic tests (the latter in agreement to the norm ASTM G-61-89) confirm an increase of microhardness up to three times and a decrease of general corrosion rate in one order of magnitude. The nitriding of de dentistry drills is aimed at inhibiting the pitting corrosion produced by the asepsis process which results in pit nucleations, their propagation and consequent fractures when being under cyclic stress (fatigue). Scanning electron microscope micrographs reveal the risks involved in surpassing the critical treatment simple temperature of 450 C as the PIII process itself induces pitting. On its part, cyclic (ASTM G-61) potentiodynamic tests indicate an excellent pitting corrosion resistance of the samples treated under 450 C. In turn, the treatment of CPTi was meant to develop oxidized and/or nitrided replacement layers of high biocompatibility in the form of rutile phase titanium oxide, which favours the bony-integration, along with enhanced wear resistance layers of improved microhardness. The superficial treatments of titanium largely succeed in these purposes both as for microhardness and for most parameters of the biological environment corrosion (simulated in a Hanks solution), surpassing the performance of conventional prosthetic metals, as reported in the current literature, including the Co-Cr-Mo alloy as to its wear resistance. (Author)

  10. Characterization of welding of AISI 304l stainless steel similar to the core encircling of a BWR reactor; Caracterizacion de soldaduras de acero inoxidable AISI 304L similares a las de la envolvente del nucleo de un reactor BWR

    Energy Technology Data Exchange (ETDEWEB)

    Gachuz M, M.E.; Palacios P, F.; Robles P, E.F. [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)

    2003-07-01

    Plates of austenitic stainless steel AISI 304l of 0.0381 m thickness were welded by means of the SMAW process according to that recommended in the Section 9 of the ASME Code, so that it was reproduced the welding process used to assemble the encircling of the core of a BWR/5 reactor similar to that of the Laguna Verde Nucleo electric plant, there being generated the necessary documentation for the qualification of the one welding procedure and of the welder. They were characterized so much the one base metal, as the welding cord by means of metallographic techniques, scanning electron microscopy, X-ray diffraction, mechanical essays and fracture mechanics. From the obtained results it highlights the presence of an area affected by the heat of up to 1.5 mm of wide and a value of fracture tenacity (J{sub IC}) to ambient temperature for the base metal of 528 KJ/m{sup 2}, which is diminished by the presence of the welding and by the increment in the temperature of the one essay. Also it was carried out an fractographic analysis of the fracture zone generated by the tenacity essays, what evidence a ductile fracture. The experimental values of resistance and tenacity are important for the study of the structural integrity of the encircling one of the core. (Author)

  11. Microstructure influence on fatigue behaviour of austenitic stainless steels with high molybdenum content; Influencia de la microestructura en el comportamiento a fatiga de aceros inoxidables austeniticos con alto contenido en molibdeno

    Energy Technology Data Exchange (ETDEWEB)

    Onoro, J.; Gamboa, R.; Ranninger, C.

    2006-07-01

    Austenitic stainless steels with molybdenum present high mechanical properties and corrosion resistance to aggressive environments. These steels have been used to tank and vessel components for high liquids as phosphoric, nitric and sulphuric acids. These materials with low carbon and nitrogen addition have been proposed candidates as structural materials for the international thermonuclear experimental reactor (ITER) in-vessel components. Molybdenum addition in austenitic stainless steel improves mechanical and corrosion properties, but with it can produce the presence of nitrogen microstructure modifications by presence or precipitation of second phases. This paper summarises the fatigue and corrosion fatigue behaviour of two 317LN stainless steels with different microstructure. Fully austenitic steel microstructure show better fatigue, corrosion fatigue resistance and better ductility than austenitic steel with delta ferrite microstructure, mainly at low stresses. (Author)

  12. Characterization of stainless steel through Scanning Electron Microscopy, nitrided in the process of implantation of immersed ions in plasma; Caracterizacion de acero inoxidable mediante Microscopia Electronica de Barrido nitrurado en el proceso de implantacion de iones inmersos en plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Moreno S, H

    2003-07-01

    The present project carries out the investigation of the nitridation of the austenitic stainless steel schedule 304, applying the novel technology of installation of nitrogen ions in immersed materials in plasma (Plll), by means of which they modify those properties of the surface of the steel. The obtained results by means of tests of Vickers microhardness, shows that the hardness was increment from 266 to 740 HV (microhardness units). It was determined by means of scanning electron microscopy, the one semiquantitative chemical analysis of the elements that constitute the austenitic stainless steel schedule 304; the obtained results, show to the nitrogen like an element of their composition in the pieces where carried out to end the PIII technology. The parameters of the plasma with which carried out the technology Plll, were monitored and determined by means of electric probes, and with which it was determined that the density of particles is stable in the interval of 1x10{sup -1} at 3x10{sup -1}Torr, and it is where better results of hardness were obtained. That reported in this work, they are the first results obtained when applying the technology Plll in Mexico, and with base in these, it is even necessary to investigate and to deepen until to dominate the process and to be in possibilities of proposing it to be carried out and exploited in an industrial way. (Author)

  13. T.I.G. Welding of stainless steel. Numerical modelling for temperatures calculation in the Haz; Soldadura T.I.G. de acero inoxidable. Modelo numerico para el calculo de temperaturas en la ZAT

    Energy Technology Data Exchange (ETDEWEB)

    Martinez-Conesa, E. J.; Estrems-Amestoy, M.; Miguel-Eguia, V.; Garrido-Hernandez, A.; Guillen-Martinez, J. A.

    2010-07-01

    In this work, a numerical method for calculating the temperature field into the heat affected zone for butt welded joints is presented. The method has been developed for sheet welding and takes into account a bidimensional heat flow. It has built a computer program by MS-Excel books and Visual Basic for Applications (VBA). The model has been applied to the TIG process of AISI 304 stainless steel 2mm thickness sheet. The welding process has been considered without input materials. The numerical method may be used to help the designers to predict the temperature distribution in welded joints. (Author) 12 refs.

  14. A galvanic corrosion study of brass/stainless steel and brass/cast iron couples; Estudio de corrosion galvanica en pares laton/acero inoxidable y laton/fundicion de hierro

    Energy Technology Data Exchange (ETDEWEB)

    Ohanian, M.; Diaz, V.; Corengia, M.; Zinola, C. F.

    2011-07-01

    Corrosion attack in heat exchanger systems is a topic of main interest for the maintenance in each industrial plant. These are multi galvanic systems with particular geometric and fluidodynamic complexity. Corrosive damages include zinc selective dealeation in copper alloys. In order to explain zinc dealeation attack, this paper deals with laboratory scale testing, characterization and interactions between two copper and zinc alloys (Yellow brass UNS C268 and Admiralty brass UNS C443) compared to AISI 316 stainless steel and cast iron. The tests were performed at 20 degree centigrade in 1.5 % NaCl and 1.5 % Na{sub 2}SO{sub 4} solutions, pH 8 and each material was characterized by potentiodynamic sweeps. The couples are analyzed by studying transient galvanic currents. We conclude about the cause of the analyzed pathology, brass protection potential ranges and its coupling compatibility with other metals. (Author) 33 refs.

  15. Study of cyclic oxidation for stainless steels AISI 309 T 253 M A, with low additions of cerium; Estudio de la oxidacion ciclica de los aceros inoxidables AISI 309 T 253 MA, con pequenas adiciones de Cerio

    Energy Technology Data Exchange (ETDEWEB)

    Velazquez F, G.L.; Martinez, M.; Ruiz, A. [Universidad Nacional Experimental Politecnica (UNEXPO) - Vicerrectorado de Puerto Ordaz, Centro de Estudios de Corrosion. Puerto Ordaz. venezuela (Venezuela)

    1998-12-31

    It has been detected that the addition of small amounts (<1%) of the so called `reactive elements` such as Cerium to Fe-Cr alloys that was utilized in oxidating environment at high temperatures improving its resistance to oxidation under isothermal and cyclic conditions. In this work, it was evaluated the behavior under cyclic oxidation conditions for an austenitic stainless steel at chromium-nickel (253MA) with cerium addition, and comparing it with the AISI 310S austenitic stainless steel. The cyclic oxidation essays consist of five cycles by 24 hours each one, following of a cooling in air until ambient temperature from the temperatures of 850, 900 and 950 Centigrade, registering the gain mass of the specimen at end of each cycle. In order to this were prepared samples with dimensions of 20 mm. x 10 mm. x 1 mm. Later to the oxidation essays was evaluated the morphology of the corrosion products layer by scanning electron microscopy. The present phases were identified by X-ray diffraction and by chemical microanalysis by Dispersive energy (EDAX). The results obtained show that the steel with cerium addition, presents a higher adherence and resistance to the spalling noting that the cerium promotes the casting anchor of the oxides layer to matrix and by reducing the grain size of the layer improving its plasticity. Additionally the cerium promotes the preferential oxidation of the forming elements of protective layers like the chromium. (Author)

  16. Effects of surface modification of thin wires of AISI 302 stainless steel by electrolytic plasma on its mechanical properties; Efecto de la modificacion superficial de alambres delgados de acero inoxidable AISI 302 mediante plasma electrolitico sobre sus propiedades mecanicas

    Energy Technology Data Exchange (ETDEWEB)

    Gallego, A.; Camurri, C.; Carrasco, C.; Soldera, F.

    2012-07-01

    In this work different tests using electrolytic plasma (EP) on thin wires of stainless steel AISI 302 in an inert solution were performed. Tensile tests were carried out in order to measure changes in the mechanical strength of the samples; moreover, both the morphological and microstructural changes also were evaluated. It was found that after 10 s of the application of EP, the samples surface was uniformly covered by nodules-like and craters similar to those found in the melting and cooling periods of EP. The results show a significant surface grain refinement, leading to crystalline arrangements with sizes less than 200 nm and also an increase in the samples tensile strength of at least 57 % respect to steel base. (Author) 14 refs.

  17. Influence of copper and tin addition on pitting corrosion behaviour of AISI 304 Strainless Steel; Efecto de la adicion de cobre y estano en el comportamiento a la corrosion por picadura de acero inoxidable AISI 304

    Energy Technology Data Exchange (ETDEWEB)

    Pardo, A.; Merino, M. C.; Botella, J.; Matres, V.; Viejo, F.; Carboneras, M.; Arrabal, R.

    2004-07-01

    The influence of copper and tin addition on the pitting corrosion resistance of AISI 304 stainless steel in 3.5% NaCl at 20 degree centigree has been studied using potenciodinamic and cyclic polarization. From that study the effect of alloying elements (Cu and Sn) in the corrosion, pitting and re passivation potentials were determined. The effect of copper and tin on the critical pitting temperature (CPT) was determined by i{sub c}orr-time-temperature curves. The influence of these alloying elements in FeCl{sub 3} under ASTM G48-00 norm was also studied. The addition of copper favours the nucleation of pits. The addition of tin slightly improves the corrosion resistance. The synergic effect of Cu-Sn was positive at low concentrations. (Author) 10 refs.

  18. Aplicación del ensayo miniatura de embutido para la evaluación de la tenacidad a temperaturas criogénicas de aceros inoxidables austeníticos envejecidos isotérmicamente

    OpenAIRE

    Saucedo-Muñoz, M. L.; Komazaki, S. I.; T. Hashida; Shoji, T; López-Hirata, V. M.

    2003-01-01

    Two types of austenitic stainless steels JJl and JNl were isothermally aged at temperatures from 873 to 1173 K for 10 to 1000 min in order to study the microstructural evolution and its effect on fracture toughness at cryogenic temperatures. The Charpy V-Notch (CVN) and Small-Punch (SP)Testing methods were conducted at 77 K to evaluate the toughness of both solution treated and aged specimens. The fracture energy at 77 K determined for both methods showed a significant decrease with aging tim...

  19. Crack propagation in stainless steel AISI 304L in Hydrogen Chemistry conditions (HWC); Propagacion de Grietas en Acero Inoxidable AISI 304L en Condiciones de Quimica de Hidrogeno (HWC)

    Energy Technology Data Exchange (ETDEWEB)

    Diaz S, A.; Fuentes C, P.; Merino C, F. [ININ, Carretera Mexico -Toluca s/n, La Marquesa, Ocoyoacac, Mexico (Mexico); Castano M, V. [Instituto de Fisica Aplicada, UNAM, Km 15.5 Carretera Queretaro-San Luis Potosi, Juriquilla, Queretaro (Mexico)]. e-mail: ads@nuclear.inin.mx

    2006-07-01

    Velocities of crack growth in samples type CT pre cracking of stainless steel AISI 304l solder and sensitized thermally its were obtained by the Rising Displacement method or of growing displacement. It was used a recirculation circuit that simulates the operation conditions of a BWR type reactor (temperature of 280 C and a pressure of 8 MPa) with the chemistry modified by the addition of hydrogen with and without the addition of impurities of a powerful oxidizer like the Cu{sup +} ion. In each essay stayed a displacement velocity was constant of 1x10{sup -9} m/s, making a continuous pursuit of the advance of the crack by the electric potential drop technique. Contrary to the idea of mitigation of the crack propagation velocity by effect of the addition of the hydrogen in the system, the values of the growth velocities obtained by this methodology went similar to the opposing ones under normal operation conditions. To the finish of the rehearsal one carries out the fractographic analysis of the propagation surfaces, which showed cracks growth in trans and intergranular way, evidencing the complexity of the regulator mechanisms of the IGSCC like in mitigation conditions as the alternative Hydrogen Chemistry. (Author)

  20. Desarrollo y caracterización de recubrimientos MCrAlY obtenidos mediante técnicas láser para aplicaciones de barrera térmica en aceros inoxidables

    OpenAIRE

    PEREIRA FALCON, JUAN CARLOS

    2015-01-01

    [EN] The coaxial laser cladding process is an excellent tool to obtain quality coatings, achieving complete melting and deposition of alloys with high melting point on complex 3D surfaces. In this work we have studied the coaxial laser cladding parameters for MCrAlY coatings (where M = Ni, Co, Fe or combinations of these), commonly used as bond coats in thermal barrier systems, among them: NiCoCrAlYTa, NiCoCrAlY, NiCrAlY and CoNiCrAlY; selecting the laser parameters that allow to obtain over...

  1. Propagation of crevices in stainless steel AISI304L in conditions of hydrogen chemistry (HWC); Propagacion de grietas en acero inoxidable AISI304L en condiciones de quimica de hidrogeno (HWC)

    Energy Technology Data Exchange (ETDEWEB)

    Diaz S, A.; Fuentes C, P.; Merino C, F. [ININ, 52750 Ocoyoacac, Estado de Mexico (Mexico); Castano M, V. [IFA-UNAM, Juriquilla, Queretaro (Mexico)]. e-mail: ads@nuclear.inin.mx

    2006-07-01

    Crevice growth velocities in samples of AISI 304L stainless steel thermally welded and sensitized were obtained by the Rising displacement method or of growing displacement. It was used a recirculation circuit in where the operation conditions of a BWR type reactor were simulated (temperature of 288 C and a pressure of 8 MPa) with the chemistry modified by the addition of hydrogen with and without the addition of impurities of a powerful oxidizer like the Cu{sup ++} ion. CT pre cracked specimens were used and each rehearsal stayed to one constant displacement velocity of 1 x 10{sup -9} m/s (3.6 {mu}m/hr), making a continuous pursuit of the advance of the crack by the electric potential drop technique. To the end of the rehearsal it was carried out the fractographic analysis of the propagation surfaces. The values of the growth velocities obtained by this methodology went similar to the opposing ones under normal conditions of operation; while the fractographic analysis show the cracks propagation in trans and intergranular ways, evidencing the complexity of the regulator mechanisms of the one IGSCC even under controlled ambient conditions or with mitigation methodologies like the alternative hydrogen chemistry. (Author)

  2. Effect of biofilm in the corrosion of austenitic stainless steels in wastewater treatment plants; Efecto de la biopelicula en la corrosion de aceros inoxidables austeniticos en estaciones depuradoras de aguas residuales

    Energy Technology Data Exchange (ETDEWEB)

    Bethencourt, M.; Garcia de Lomas, J.; Corzo, A.; Villahermosa, D.; Matres, V.

    2010-07-01

    In this work, the influence of the biofilm in the corrosion process of different alloys of stainless steel was studied in two sampling points in a wastewater treatment plant during 4 years. The physicochemical microenvironment within the biofilm was characterized through O{sub 2}, H{sub 2}S and pH microelectrodes. Corrosion rates were quantified from the number, diameter and depth of pits. The results show a remarkable development of the biofilm and a significantly greater number of pits in the grit removal channel than in the sludge recirculation channel. Based on the characteristics of the water phase and microelectrode measurements, our results suggest that biofilm induced corrosion throughout 3 mechanisms: creation of differential aeration cells, areas with different pH and areas having high sulphide production which may react with metal ions. (Author) 54 refs.

  3. Applications of the essay at slow deformation velocity in pipes of stainless steel AISI-304; Aplicaciones del ensayo a velocidad de deformacion lenta en tuberias de acero inoxidable AISI-304

    Energy Technology Data Exchange (ETDEWEB)

    Zamora R, L.; Mora R, T. De la [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)

    2004-07-01

    Nowadays is carried out research related with the degradation mechanisms of structures, systems and/or components in the nuclear power plants, since many of the involved processes are those responsible for the dependability of these, of the integrity of the components and of the aspects of safety. The purpose of this work, was to determine the grade of susceptibility to the corrosion of a pipe of Austenitic stainless steel AISI 304, in a solution of Na CI (3.5%) to the temperatures of 60 and 90 C, in two different thermal treatments - 1. - Sensitive 650 C by 4 hours and cooled in water. 2. Solubilized to 1050 C by 1 hour and cooled in water.

  4. Caracterizaci\\'on de austenita expandida generada por cementaci\\'on i\\'onica de aceros inoxidables. Estudio de la estabilidad frente a la irradiaci\\'on con haces de iones ligeros energ\\'eticos

    CERN Document Server

    Molleja, Javier García

    2014-01-01

    This thesis was focused on the surface modification with plasma discharge. Austenitic AISI 316L stainless steel sample was carburised under different experimental conditions and mechanical properties have been studied (thickness, lattice parameter, elemental composition, hardness, wear resistance and corrosion resistance). After that, steel substrates have been nitrided or carburised in order to analyse their stability under ion bombardment using a plasma focus device. Helium and deuterium were the gases used in 0, 1, 5, and 10 discharges. Optical and X-ray characterisations were used. Finally, using magnetron sputtering nitrided/carburised samples were coated with an AlN thin film in order to study their stability under long treatments at high temperatures.

  5. Estudio de corrosión bajo tensión en los aceros inoxidables 17-4PH y 17-7PH en presencia de NaCl y NaOH (20 %) a 90 °C

    OpenAIRE

    Gaona-Tiburcio, Citlalli; Almeraya-Calderón, Facundo; Martínez-Villafañe, Alberto

    2000-01-01

    One of the problems that affects to the electric industry is the not programmed stoppages in the power plants, due to the failure of any main component: boiler, turbine and generator. In the turbine, the combined action of a corrosive agent (humid polluted vapor) and a mechanical effort generally will result in Stress Corrosion Cracking (SCC). In this work the SCC susceptibility of the precipitation hardening stainless steels 17-4PH and 17- 7PH, thoroughly used in steam turbine blades of powe...

  6. Fatigue life of AISI 316L stainless steel welded joints, obtained by GMAW; Vida a la fatiga de juntas soldadas del acero inoxidable AISI 316L obtenidas mediante el proceso GMAW

    Energy Technology Data Exchange (ETDEWEB)

    Puchi-Cabrera, E. S.; Saya-Gamboa, R. A.; Barbera-Sosa, J. G. la; Staia, M. H.; Ignoto-Cardinale, V.; Berrios-Ortiz, J. A.; Mesmacque, G.

    2007-07-01

    An investigation has been conducted in order to determine the effect of both the metallic transfer mode (pulsed arc or short circuit) and the O{sub 2} content in the Ar/O{sub 2} gas mixture, of the gas-metal arc welding process (GMAW), on the fatigue life under uniaxial conditions of welded joints of 316L stainless. it has been concluded that the mixture of the protective gases employed in the process could have an important influence on the fatigue life of the welded joints of such steel in two different ways. firstly, through the modification of the radius of curvature at the joint between the welding tow and the base metal and, secondly, through a more pronounced degree of oxidation of the alloying elements induced by a higher O{sub 2} content in the mixture. As far as the metallic transfer mode is concerned, it has been determined that the welded joints obtained under a pulsed arc mode show a greater fatigue life in comparison with the joints obtained under short circuit for both gas mixtures. (Author) 25 refs.

  7. Microbiologically influenced corrosion evaluation on brass (UNS C68700, UNS C443) and AISI 316 stainless steel; Estudio de la influencia microbiologica en la corrosion de latones (UNS C68700, UNS C443) y acero inoxidable AISI 316

    Energy Technology Data Exchange (ETDEWEB)

    Ohanian, M.; Diaz, V.; Corengia, M.; Russi, P.; Pianzzola, M. J.; Menes, R. J.

    2014-10-01

    Microorganisms may play an important role in the corrosion process and generate conditions which affect the rate and/or the mechanism of deterioration. They become visible by the formation of bio films: clusters of microorganisms and extracellular polymers. These bio films affect not only the durability of the material, but also reduce the heat transfer. The present work studied the growth of aerobic and anaerobic heterotrophic microorganisms and sulfate reducing bacteria on aluminum brass (Uns C.a.), admiralty brass (Uns C.a.) and stainless steel Asi 316 in exposure experiments held in the Bay of Montevideo (Uruguay). The influence of the biofilm growth on the corrosion behavior was studied by electrochemical techniques: polarization curves and Electrochemical Impedance Spectroscopy (Ei). The selection of the most suitable material for the exposure conditions is discussed and hypotheses of the corrosion mechanism are presented. Although stainless steel Asi 316 presented the lowest corrosion rate it showed localized deterioration. (Author)

  8. Buffer management in wireless full-duplex systems

    KAUST Repository

    Bouacida, Nader

    2015-10-19

    Wireless full-duplex radios can simultaneously transmit and receive using the same frequency. In theory, this can double the throughput. In fact, there is only little work addressing aspects other than throughput gains in full-duplex systems. Over-buffering in today\\'s networks or the so-called “bufferbloat” phenomenon creates excessive end-to-end delays resulting in network performance degradation. Our analysis shows that full-duplex systems may suffer from high latency caused by bloated buffers. In this paper, we address the problem of buffer management in full-duplex networks by using Wireless Queue Management (WQM), which is an active queue management technique for wireless networks. Our solution is based on Relay Full-Duplex MAC (RFD-MAC), an asynchronous media access control protocol designed for relay full-duplexing. We compare the performance of WQM in full-duplex environment to Drop Tail mechanism over various scenarios. Our solution reduces the end-to-end delay by two orders of magnitude while achieving similar throughput in most of the cases.

  9. El acero que nunca se fundió. Una reseña sobre Stalin

    Directory of Open Access Journals (Sweden)

    Iñaki Oneca Agurruza

    2004-02-01

    Full Text Available Era el 5 de marzo de 1953 cuando murió el fetiche, el gurú, el símbolo. Stalin significa “acero”, y precisamente una de las cosas que se reprochó al joven revolucionario, tras la adopción de este apodo, era que el acero era duro pero también frío. Así iniciamos esta breve nota sobre la figura de uno de los personajes clave del siglo XX.

  10. Corrosión en láminas y bobinas de un acero importado

    OpenAIRE

    Wilson A. Hormaza R.

    2007-01-01

    Este trabajo busca determinar las causas que llevaron al deterioro superficial de un conjunto de láminas y bobinas importadas de acero. Lo anterior implica precisar el tipo de deterioro de los componentes, es decir, si este se presentó durante el transporte marítimo o durante el almacenamiento. Los ensayos realizados fueron: análisis visual, análisis de espectrofotometría de infrarrojo y comparativo de los cristales de Cloruro de Sodio (NaCl), análisis de la morfología de la su...

  11. Aplicación de criterios de conformabilidad en productos planos de aceros de alta resistencia

    OpenAIRE

    Gutiérrez Castillo, Joan David

    2012-01-01

    La conformabilidad de chapas metálicas suele evaluarse mediante los diagramas FLD (Forming Limit Diagrams), que informan sobre el límite de conformado de un material representado por la curva FLC (Forming Limit Curve). Estos diagramas y curvas han sido empleados durante años para estudiar la conformabilidad de un material y como criterio de fallo en la simulación por elementos finitos del conformado de componentes estructurales. La aparición de nuevos aceros con mayores prestaciones, como ...

  12. The formation of adjacent triplex-duplex domainsin DNA.

    OpenAIRE

    Nam, K. H.; Abhiraman, S; Wartell, R M

    1999-01-01

    The ability of single-stranded DNA oligomers to form adjacent triplex and duplex domains with two DNA structural motifs was examined. Helix-coil transition curves and a gel mobility shift assay were used to characterize the interaction of single-stranded oligomers 12-20 nt in length with a DNA hairpin and with a DNA duplex that has a dangling end. The 12 nt on the 5'-ends of the oligomers could form a triplex structure with the 12 bp stem of the hairpin or the duplex portion of the DNA with a...

  13. Streamlined analysis of duplex sequencing data with Du Novo.

    Science.gov (United States)

    Stoler, Nicholas; Arbeithuber, Barbara; Guiblet, Wilfried; Makova, Kateryna D; Nekrutenko, Anton

    2016-01-01

    Duplex sequencing was originally developed to detect rare nucleotide polymorphisms normally obscured by the noise of high-throughput sequencing. Here we describe a new, streamlined, reference-free approach for the analysis of duplex sequencing data. We show the approach performs well on simulated data and precisely reproduces previously published results and apply it to a newly produced dataset, enabling us to type low-frequency variants in human mitochondrial DNA. Finally, we provide all necessary tools as stand-alone components as well as integrate them into the Galaxy platform. All analyses performed in this manuscript can be repeated exactly as described at http://usegalaxy.org/duplex . PMID:27566673

  14. Investigation of the Hot Plasticity of Duplex Stainless Steel

    Institute of Scientific and Technical Information of China (English)

    LIN Gang; ZHANG Zhi-xia; SONG Hong-wei; TONG Jun; ZHOU Can-dong

    2008-01-01

    Hot plasticity of a nitrogen alloyed 25Cr-7Ni-4 Mo duplex stainless steel was investigated.The results indicate that thc main factors affecting the hot plasticity of duplex stainless steel are listed as follows:coalescent force of phase interface,microstructure,and the phase ratio and difference between the mechanicsl propertms of ferrite and austenite.The heat treatment and sulphur contents have a notable effect on the hot plasticity.The reasonable heat treatrnents and the irlcreased interfacial coalescent force will effectively enhance the hot plasticity of duplex stainless steel.

  15. Corrosion behavior of sensitized duplex stainless steel.

    Science.gov (United States)

    Torres, F J; Panyayong, W; Rogers, W; Velasquez-Plata, D; Oshida, Y; Moore, B K

    1998-01-01

    The present work investigates the corrosion behavior of 2205 duplex stainless steel in 0.9% NaCl solution after various heat-treatments, and compares it to that of 316L austenitic stainless steel. Both stainless steels were heat-treated at 500, 650, and 800 degrees C in air for 1 h, followed by furnace cooling. Each heat-treated sample was examined for their microstructures and Vickers micro-hardness, and subjected to the X-ray diffraction for the phase identification. Using potentiostatic polarization method, each heat-treated sample was corrosion-tested in 37 degrees C 0.9% NaCl solution to estimate its corrosion rate. It was found that simulated sensitization showed an adverse influence on both steels, indicating that corrosion rates increased by increasing the sensitization temperatures. PMID:9713683

  16. MICROSCOPIC CORROSION STUDIES OF DUPLEX STAINLESS STEELS

    Institute of Scientific and Technical Information of China (English)

    C.Leygraf; J.Pan; M.Femenia

    2004-01-01

    Electrochemical scanning tunneling microscopy and scanning electrochemical microscopy have been used for in situ monitoring of localized corrosion processes of different Duplex stainless steels (DSS) in acidic chloride solutions. The techniques allow imaging of local dissolution events with micrometer resolution, as opposed to conventional electrochemical techniques, which only give an overall view of the corrosion behavior. In addition, combined scanning Kelvin probe force microscopy and magnetic force microscopy were used for mapping the Volta potential variation over the surface of DSSs. A significant difference in Volta potential between the austenite and ferrite phases suggests galvanic interaction between the phases. A compositional gradient appears within 2 micrometers across the phase boundary, as seen with scanning Auger microscopy (SAM). In all, the studies suggest that higher alloyed DSS exhibit a more homogeneous dissolution behavior than lower alloyed DSS, due to higher and more similar corrosion resistance of the two phases, and enhanced resistance of the ferrite/austenite phase boundary regions.

  17. Estudio del comportamiento a fluencia en caliente de un acero avanzado de alta resistencia de bajo contenido en carbono NiCrVCu microaleado con boro

    OpenAIRE

    González Sala, Sara

    2009-01-01

    Una de las líneas de investigación prioritarias en el contexto internacional es el desarrollo de aceros avanzados de alta resistencia (AHSS) con excelentes propiedades de resistencia y tenacidad para aplicaciones en la industria automotriz, naval, aeronáutica y de generación de energía, que permitan disminuir el peso de los componentes y sustituyan aceros tradicionales de contenidos mayores de carbono. Los aceros AHSS microaleados al boro, debido a sus cualidades, tecnología de...

  18. Estudio y modelización de la recristalización estática de aceros ferríticos laminados en frío

    OpenAIRE

    Cock, Tommy de

    2008-01-01

    Los aceros ferríticos de última generación para chapa de atumóvil están diseñados para alcanzar, o incluso mejorar, las propiedades de tenacidad y resistencia de los aceros actuales pero con un menor espesor de chapa. Para ello, estos aceros siguen una ruta de procesado larga y compleja, que incluye una laminación austenítica y/o ferrítica en caliente, una posterior laminación en frío para alcanzar los espesores de chapa requeridos, un recocido a temperaturas inferiores a Ac1, un laminado en...

  19. Análisis comparativo de la calidad del acero de refuerzo distribuido en Boyacá

    Directory of Open Access Journals (Sweden)

    Jimmy Vergara Silva, Óscar Javier Gutiérrez Junco

    2011-05-01

    Full Text Available Presenta  los  resultados  del  análisis  comparativo  de barras de acero de refuerzo, según las exigencias de la Norma Técnica Colombiana NTC 2289 [1], realizado a cinco marcas diferentes distribuidas para la industria de  la  construcción  en  Boyacá.  Inicialmente  se caracterizaron  las barras de  acero mediante  ensayos, para  determinar  su  composición  química  y  sus propiedades físicas y mecánicas; las características de la fractura del acero de refuerzo se observaron con el microscopio  electrónico  de  barrido  (MEB. Adicionalmente,  se  analizaron  muestras  conmicroscopio óptico, con  técnicas de espectrometría paraobservar y determinar las características del metal base de  las probetas. Los resultados  indican que la calidad del acero de refuerzo distribuido en Boyacá cumple en un alto  porcentaje con las exigencias sismo-resistentes para construcción; sin embargo, es importante que los constructores realicen control de calidad.

  20. Thermoacoustic Duplex Technology for Cooling and Powering a Venus Lander

    Science.gov (United States)

    Walker, A. R.; Haberbusch, M. S.; Sasson, J.

    2015-04-01

    A Thermoacoustic Stirling Heat Engine (TASHE) is directly coupled to a Pulse Tube Refrigerator (PTR) in a duplex configuration, providing simultaneous cooling and electrical power, thereby suiting the needs of a long-lived Venus lander.

  1. Heat treatment and characterization of duplex 1010 and 1020 steels

    Energy Technology Data Exchange (ETDEWEB)

    Young, M.J.

    1977-11-01

    An investigation concerning the heat treatment of duplex ferritic-martensitic 1010 and 1020 steels has been carried out. Tensile and impact properties of intermediately quenched and continuously annealed specimens have been characterized and microstructural correlations established. The rule for two phase mixtures may be used as a fairly good approximation of the mechanical behavior of the duplex system, and improved correlations are possible with suitable modifications for the size, shape and distribution of the second phase. The property differentials between the duplex 1010 and 1020 at equal volume fractions of martensite are due mainly to the higher carbon content (hence, higher strength) of the 1020 martensite. Important metallurgical variables include subgrain formation, retained austenite, transformation twinning and martensite fraction. Of these, the volume fraction of martensite appears to be the most influential in controlling the strength, ductility and impact properties of the duplex systems studied.

  2. Development of oxide dispersion strengthened 2205 duplex stainless steel composite

    Directory of Open Access Journals (Sweden)

    Oladayo OLANIRAN

    2015-05-01

    Full Text Available Composites of duplex stainless steel were produced by oxide dispersion strengthening with comparatively improved mechanical properties by hot press sintering of partially stabilized Zirconia (PSZ, 3% yttria, mole fraction dispersion in 2205 duplex stainless steels. Ceramic oxide was added as reinforcement, while chromium (Cr and Nickel (Ni were incorporated to maintain the austenitic/ferritic phase balance of the duplex stainless steel. The powders and sintered were characterized in detail using scanning electron microscopy (SEM and X-ray diffraction (XRD. The microstructural evolution and phase formation during oxide dispersion strengthening of duplex stainless steel composites were investigated. The influence of composition variation of the reinforcements on the microstructural and corrosion behaviour in simulated mine water of the composites were investigated. In this manuscript, it was established that composition has great influence on the structure/properties relationship of the composites developed.

  3. EXPERIMENTAL RESEARCH OF THE DUPLEX STAINLESS STEEL WELDS IN SHIPBUILDING

    OpenAIRE

    Juraga, Ivan; Stojanović, Ivan; Ljubenkov, Boris

    2014-01-01

    Duplex stainless steel is used in shipbuilding increasingly because of its good mechanical properties and marked corrosion resistance. This steel has a two phase structure (austenite-ferrite) which is sensitive on heat input during welding because of the possible ferritisation appearance, that is, increase in ferrite content in the area of heat effected zone (HAZ) which can lead to loss of mechanical and corrosion properties. Work with duplex stainless steel requires special attention in ever...

  4. Properties of duplex stainless steels made by powder metallurgy

    OpenAIRE

    M. Rosso; M. Actis Grande; Z. Brytan; L.A. Dobrzański

    2007-01-01

    Purpose: of this paper was to examine the mechanical properties of duplex stainless steels.Design/methodology/approach: In presented study duplex stainless steels were obtained through powder metallurgy starting from austenitic, martensitic base powders by controlled addition of alloying elements, such as Cr, Ni, Mo and Cu. In the studies behind the preparation of mixes, Schaeffler’s diagram was taken into consideration. Prepared mixes have been sintered in a vacuu...

  5. Probing the duplex stainless steel phases via magnetic force microscopy

    Science.gov (United States)

    Gheno, S. M.; Santos, F. S.; Kuri, S. E.

    2008-03-01

    Duplex stainless steels are austenitic-ferritic alloys used in many applications, thanks to their excellent mechanical properties and high corrosion resistance. In this work, chemical analyses, x-ray diffraction, and magnetic force microscopy (MFM) were employed to characterize the solution annealed and aged duplex stainless steel. The samples exhibited no changes in lattice parameters and the MFM technique proved successful in clearly imaging the magnetic domain structure of the ferrite phase.

  6. Corrosion resistance properties of sintered duplex stainless steel

    OpenAIRE

    L.A. Dobrzański; Z. Brytan; M. Actis Grande; M. Rosso

    2006-01-01

    Purpose: of this paper was to examine the corrosion resistance of duplex stainless steels using electrochemical methods in 1M NaCl solution. The influence of powder mixes preparation and cooling cycle after sintering on corrosion properties was evaluated.Design/methodology/approach: In presented study duplex stainless steels were obtained through powder metallurgy starting from austenitic, martensitic base powders by controlled addition of alloying elements, such as Cr, Ni, Mo and Cu. In the ...

  7. Transferencia de calor en la colada continua de aceros. I parte. El molde

    Directory of Open Access Journals (Sweden)

    Cicutti, C.

    1997-10-01

    Full Text Available The continuous casting mold plays the important role of receiving the liquid steel and allowing an uniform and defect free solidified skin to be developed. In this work, the different heat transfer mechanisms which are present from the liquid steel to the mold cooling water are reviewed. The effect of operating variables on heat extraction and the relationship between global and distributed heat flux are also analyzed.

    El molde de colada continua cumple la importante función de recibir el acero líquido y permitir que se desarrolle una capa solidificada uniforme y libre de defectos. En este trabajo se revisan los distintos mecanismos implicados en el proceso de transferencia de calor, desde el acero líquido hasta el agua de refrigeración del molde. Se analiza también el efecto de las distintas variables de funcionamiento en la extracción calórica producida y la relación entre el flujo global de calor y su distribución a lo largo del molde.

  8. Mejora de la calidad del acero obtenido por colada continua mediante influencias electrofísicas

    Directory of Open Access Journals (Sweden)

    Shklyar, V.

    1998-12-01

    Full Text Available Laboratory tests with tin smelted in a crucible and industrial tests with crude steel poured in moulds had been carried out. These metals were subjected to electrophysical influences. As a result of the applied electric field, it is observed in tin that during the solidification, the crystalization temperature and the solidification time are changed. Crystal growth in the electric field direction and an increase of the fracture limit in the steel ingot are observed.

    Se han realizado ensayos de laboratorio con estaño fundido en crisol y a escala industrial con acero líquido vertidos en moldes, sometiendo estos metales a influencias electrofísicas. Como resultado del campo aplicado, en el estaño se observa que durante la solidificación varía la temperatura de cristalización y el tiempo de solidificación. En el lingote de acero se observa un crecimiento de los cristales en dirección del campo eléctrico y un aumento del límite de rotura.

  9. EFFECT OF INTERMETALLIC PHASES ON CORROSION BEHAVIOR AND MECHANICAL PROPERTIES OF DUPLEX STAINLESS STEEL AND SUPER-DUPLEX STAINLESS STEEL

    OpenAIRE

    Prabhu Paulraj; Rajnish Garg

    2015-01-01

    Duplex Stainless Steels (DSS) and Super Duplex Stainless Steel (SDSS) have excellent integration of mechanical and corrosion properties. However, the formation of intermetallic phases is a major problem in their usage. The mechanical and corrosion properties are deteriorated due to the presence of intermetallic phases. These phases are induced during welding, prolonged exposure to high temperatures, and improper heat treatments. The main emphasis of this review article is on intermetallic pha...

  10. Phase Transformations in Cast Duplex Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Yoon-Jun Kim

    2004-12-19

    Duplex stainless steels (DSS) constitute both ferrite and austenite as a matrix. Such a microstructure confers a high corrosion resistance with favorable mechanical properties. However, intermetallic phases such as {sigma} and {chi} can also form during casting or high-temperature processing and can degrade the properties of the DSS. This research was initiated to develop time-temperature-transformation (TTT) and continuous-cooling-transformation (CCT) diagrams of two types of cast duplex stainless steels, CD3MN (Fe-22Cr-5Ni-Mo-N) and CD3MWCuN (Fe-25Cr-7Ni-Mo-W-Cu-N), in order to understand the time and temperature ranges for intermetallic phase formation. The alloys were heat treated isothermally or under controlled cooling conditions and then characterized using conventional metallographic methods that included tint etching, and also using electron microscopy (SEM, TEM) and wavelength dispersive spectroscopy (WDS). The kinetics of intermetallic-phase ({sigma} + {chi}) formation were analyzed using the Johnson-Mehl-Avrami (MA) equation in the case of isothermal transformations and a modified form of this equation in the case of continuous cooling transformations. The rate of intermetallic-phase formation was found to be much faster in CD3MWCuN than CD3MN due mainly to differences in the major alloying contents such as Cr, Ni and Mo. To examine in more detail the effects of these elements of the phase stabilities; a series of eight steel castings was designed with the Cr, Ni and Mo contents systematically varied with respect to the nominal composition of CD3MN. The effects of varying the contents of alloying additions on the formation of intermetallic phases were also studied computationally using the commercial thermodynamic software package, Thermo-Calc. In general, {sigma} was stabilized with increasing Cr addition and {chi} by increasing Mo addition. However, a delicate balance among Ni and other minor elements such as N and Si also exists. Phase equilibria in

  11. Phase transformations in cast duplex stainless steels

    Science.gov (United States)

    Kim, Yoon-Jun

    Duplex stainless steels (DSS) constitute both ferrite and austenite as a matrix. Such a microstructure confers a high corrosion resistance with favorable mechanical properties. However, intermetallic phases such as sigma (sigma) and chi (chi) can also form during casting or high-temperature processing and can degrade the properties of the DSS. This research was initiated to develop time-temperature-transformation (TTT) and continuous-cooling-transformation (CCT) diagrams of two types of cast duplex stainless steels, CD3MN (Fe-22Cr-5Ni-Mo-N) and CD3MWCuN (Fe-25Cr-7Ni-Mo-W-Cu-N), in order to understand the time and temperature ranges for intermetallic phase formation. The alloys were heat treated isothermally or under controlled cooling conditions and then characterized using conventional metallographic methods that included tint etching, and also using electron microscopy (SEM, TEM) and wavelength dispersive spectroscopy (WDS). The kinetics of intermetallic-phase (sigma + chi) formation were analyzed using the Johnson-Mehl-Avrami (JMA) equation in the case of isothermal transformations and a modified form of this equation in the case of continuous cooling transformations. The rate of intermetallic-phase formation was found to be much faster in CD3MWCuN than CD3MN due mainly to differences in the major alloying contents such as Cr, Ni and Mo. To examine in more detail the effects of these elements of the phase stabilities, a series of eight steel castings was designed with the Cr, Ni and Mo contents systematically varied with respect to the nominal composition of CD3MN. The effects of varying the contents of alloying additions on the formation of intermetallic phases were also studied computationally using the commercial thermodynamic software package, Thermo-Calc. In general, a was stabilized with increasing Cr addition and chi by increasing Mo addition. However, a delicate balance among Ni and other minor elements such as N and Si also exists. Phase equilibria in

  12. ES and H-compatible lubrication for duplex bearings

    Energy Technology Data Exchange (ETDEWEB)

    Steinhoff, R.G.

    1997-10-01

    Two ES and H-compatible lubricants (environment, safety, and health) for duplex bearing applications and one hybrid material duplex bearing were evaluated and compared against duplex bearings with trichlorotrifluoroethane (Freon) deposition of low molecular weight polytetrafluoroethylene (PTFE) bearing lubricant extracted from Vydax{trademark}. Vydax is a product manufactured by DuPont consisting of various molecular weights of PTFE suspended in trichlorotrifluoroethane (Freon), which is an ozone-depleting solvent. Vydax has been used as a bearing lubricant in strong link mechanisms since 1974. Hybrid duplex bearings with silicon nitride balls and molded glass-nylon-Teflon retainers, duplex bearings lubricated with sputtered MoS{sub 2} on races and retainers, and duplex bearings lubricated with electrophoretic deposited MoS{sub 2} were evaluated. Bearings with electrophoretic deposited MoS{sub 2} performed as well as bearings with Freon deposition of PTFE from Freon-based Vydax. Hybrid bearings with silicon nitride balls performed worse than bearings lubricated with Vydax, but their performance would still be acceptable for most applications. Bearings lubricated with sputtered MoS{sub 2} on the races and retainers had varying amounts of film on the bearings. This affected the performance of the bearings. Bearings with a uniform coating performed to acceptable levels, but bearings with no visible MoS{sub 2} on the races and retainers did not perform as well as bearings with the other coatings. Unless process controls are incorporated in the sputtering process or the bearings are screened, they do not appear to be acceptable for duplex bearing applications.

  13. Comportamiento en frío y en caliente de aceros con bajo contenido de carbono obtenidos a través de procesos de laminación controlada

    OpenAIRE

    Quintana Hernández, María José

    2013-01-01

    Los aceros con bajo contenido de carbono microaleados con Ti y Nb fabricados en la planta de Arcelor Mittal en Asturias, España usando el método avanzado de control termomecánico para laminación (ATMCRP) de aceros se pueden dividir en dos rubros: aceros de fase dual (enfriados con agua) y aceros HSLA (cuando el enfriamiento se realiza más lentamente). Dentro de las ventajas de este proceso se encuentran las propiedades mecánicas que permiten su aplicación industrial y el bajo costo en compara...

  14. Corrosión bajo tensión de aceros eutectoides con trefilado progresivo

    Directory of Open Access Journals (Sweden)

    Ovejero, E.

    1998-05-01

    Full Text Available The consequences of the microstructural evolution in an eutectoid steel that has undergone a cold drawing process are studied. This manufacturing technique produces changes in the steel microstructure: a progressive orientation and slenderising of the pearlite colonies and an orientation and packing of the pearlite lamellae, thus reducing the interlamellar spacing. In addition, the experimental results of the stress corrosion cracking tests show that cold drawing produces resistant anisotropy in the steel and thus the stress corrosion cracking resistance is a directional property which seems to depend on the orientation of the microstructure in relation to the cold drawing direction. As a consequence, a transversal crack tends to change its propagation direction approaching the wire axis and a crack growth in mode I evolves to a mixed mode propagation.

    Se estudian las consecuencias de la evolución microestructural en un acero eutectoide que ha sufrido un proceso de trefilado progresivo. Esta técnica de fabricación origina una serie de cambios en la microestructura del acero: una orientación progresiva y un estiramiento de las colonias de perlita y una orientación y densificación de las láminas de perlita, reduciendo así el espaciado interlaminar. Por otra parte, los resultados experimentales de los ensayos de corrosión bajo tensión demuestran que el trefilado produce anisotropía resistente en el acero, y así la resistencia a la corrosión bajo tensión es una propiedad direccional que parece depender de la orientación de la microestuctura con respecto a la dirección del trefilado. Como consecuencia, una fisura transversal tiende a cambiar su dirección de propagación para aproximarse a la del eje del alambre, y un crecimiento en modo I evoluciona hacia una propagación en modo mixto.

  15. Mecanismos de fractura a alta temperatura en aceros eléctricos no-orientados

    Directory of Open Access Journals (Sweden)

    García-Sánchez, E. O.

    2007-08-01

    Full Text Available In this research work the effect of deformation temperature on the hot ductility of non-oriented electrical steels (0.6 % Si-0.3 Al % was studied using high temperature tensile tests. The specimens were machined from two thin slabs (50 mm thickness produced by CSP process (Compact Strip Process, one of them using 100 % sponge iron and the other using 67 % scrap and 33 % sponge iron. The tensile tests were carried out at constant strain rate (5×1010–4 s–1, and a temperature range from 850 to 1,200 °C. The results showed that the ductility decreased with the increment in the temperature until approximately 1,000 °C. At higher temperatures, a ductility recovery was observed only in the steel fabricated without scrap. Scanning Electron Microscopy on fracture surfaces showed that the loss of ductility is associated with intergranular cracking promoted by the austenitic transformation and AlN grain boundaries precipitation.

    Se investigó el efecto de la temperatura de deformación sobre la ductilidad de aceros eléctricos de grano no-orientado (0,6 % Si-0,3 % Al mediante ensayos de tracción uniaxial. Las probetas se obtuvieron de planchones delgados (50 mm de espesor tipo CSP (Continuous Strip Processing fabricados a partir de 100 % hierro esponja y una mezcla de 67 % chatarra y 33 % de hierro esponja. El rango de temperatura de estudio fue de 850 a 1.200 °C y los ensayos se llevaron a cabo a una velocidad de deformación constante de 5×10–4 s–1. Los resultados experimentales demostraron que la ductilidad (% RA disminuye con el aumento en la temperatura hasta un mínimo a ~1.000 °C. A temperaturas mayores, la ductilidad del acero fabricado a partir de 100 % hierro esponja se recupera. Este efecto no fue observado en el acero fabricado a partir de chatarra. La caracterización de las superficies de fractura mediante microscopía electrónica de barrido demostró que la pérdida de

  16. Efectos del tratamiento térmico en la fractura de aceros

    Directory of Open Access Journals (Sweden)

    Héctor Hernández A.

    2011-01-01

    Full Text Available No obstante de los avances logrados en otros tipos de aleaciones, los aceros se siguen utilizando en forma extensiva en la construcción de elementos estructurales, porque con una adecuada selección y tratamiento técnico, los aceros permiten obtener una conveniente combinación de propiedades mecánicas ante unas exigencias específicas de servicio. La fractura en elementos de máquinas frecuentemente se encuentra asociada a una discontinuidad, la cual provoca una concentración de esfuerzo, lo que puede originar sitios de iniciación de una falla por fractura. La carga límite de fractura es afectada por parámetros geométricos, naturaleza y tipo de carga y propiedades mecánicas del material. La mayoría de fallas por fractura de elementos de máquinas son fallas por fatiga; por lo general una fractura por fatiga tiene lugar por una progresiva generación y crecimiento de grietas hasta obtenerse una condición crítica de fractura súbita de la sección residual resistente. Frecuentemente en una fractura por fatiga se observan marcas de playa, las cuales son evidencias de la posición del frente de grietas antes que se alcance la condición de fractura súbita final. En este trabajo se muestra como el tratamiento térmico de temple y revenido de los aceros afecta el esfuerzo límite de falla por fractura para carga de tracción estática y carga de fatiga uniaxial con la presencia de una entalla severa. También se estudia el efecto del tratamiento térmico en la tenacidad de fractura, propiedad que cuantifica la resistencia al crecimiento súbito de una grieta bajo carga estática.

  17. Comparative study in the induced corrosion by sulfate reducing microorganisms, in a stainless steel 304L sensitized and a carbon steel API X65; Estudio comparativo de la corrosion inducida por microorganismos sulfatorreductores, en un acero inoxidable 304L sensibilizado y un acero al carbono API X65

    Energy Technology Data Exchange (ETDEWEB)

    Diaz S, A.; Gonzalez F, E.; Arganis J, C.; Luna C, P.; Carapia M, L. [ININ, Carretera Mexico-Toluca Km. 36.5, 52045 Estado de Mexico (Mexico)]. e-mail: ads@nuclear.inin.mx

    2004-07-01

    In spite of the operational experience related with the presence of the phenomenon of microbiological corrosion (MIC) in industrial components, it was not but until the decade of the 80 s when the nuclear industry recognized its influence in some systems of Nuclear Generating Power plants. At the moment, diverse studies that have tried to explain the generation mechanism of this phenomenon exist; however, they are even important queries that to solve, especially those related with the particularities of the affected metallic substrates. Presently work, the electrochemical behavior of samples of stainless steel AISI 304L sensitized is evaluated and the carbon steel APIX65, before the action of sulfate reducing microorganisms low the same experimental conditions; found that for the APIX65 the presence of this type of bacteria promoted the formation of a stable biofilm that allowed the maintenance of the microorganisms that damaged the material in isolated places where stings were generated; while in the AISI 304L, it was not detected damage associated to the inoculated media. The techniques of Resistance to the Polarization and Tafel Extrapolation, allowed the calculation of the speed of uniform corrosion, parameter that doesn't seem to be influenced by the presence of the microorganisms; while that noise electrochemical it distinguished in real time, the effect of the sulfate reducing in the steel APIX65. (Author)

  18. EBR-II Superheater Duplex Tube Examination

    International Nuclear Information System (INIS)

    After 30 years of operation, the Experimental Breeder Reactor II (EBR-II) Superheater 710 at Argonne National Laboratory-West (now Idaho National Laboratory) was decommissioned. As part of its post-service examination, four duplex tube sections were removed and Charpy impact testing was performed to characterize the crack arresting ability of nickel-bonded tube interfaces. Scanning electron microscopy (SEM) examination was also performed to characterize and identify changes in bond material microstructure. From room temperature to 400 degrees C, all samples demonstrated ductility and crack-stopping ability similar to that exhibited by beginning-of-life samples. However, at low temperature (-5 degrees C), samples removed from the lower region of the superheater (near the sodium inlet) failed while those from the upper region (near the sodium outlet) did not. SEM analysis revealed that all the tube-tube interfaces showed evidence of iron diffusion into the nickel braze, which resulted in the formation of a multiphase diffusion structure. Yet, significant void formation was only observed in the bond layer of the tubes removed from the lower region. This may be due to a change in the crystal microstructure of one of the phases within the bond layer that occurs in the 350 to 450 degrees C temperature range, which results in a lower density and the formation of porosity. Apparently, only the samples from the higher temperature region were exposed to this transition temperature, and the resulting large voids that developed acted as stress concentrators that led to low-temperature embrittlement and failure of the Charpy impact specimens

  19. Comportamiento del acero de baja aleación SA-508 y del acero al carbono A-410b en las condiciones de operación y parada del circuito primario de los reactores de agua ligera tipo PWR

    Directory of Open Access Journals (Sweden)

    García-Redondo, María del Sol

    2000-04-01

    Full Text Available The corrosion rate of low alloy steel SA-508 and carbon steel A-410b in simulated operation and shutdown conditions of pressurized water reactor has been determined. Moreover potentiodynamic polarization curves and galvanic effect through coupling of AISI-304 have been carried out under shutdown simulated condition.

    En este trabajo se ha determinado la cinética de corrosión del acero de baja aleación SA-508 y del acero al carbono A-410b en condiciones que simulan la operación y la parada de los reactores de agua ligera a presión. También se han realizado curvas de polarización potenciodinámica y se ha estudiado el acoplamiento galvánico con AISI-304 en condiciones de parada de los reactores de agua ligera a presión.

  20. Agitación electromagnética en la colada continua de acero

    Directory of Open Access Journals (Sweden)

    Álvarez de Toledo, G.

    1995-02-01

    Full Text Available The electromagnetic stirring of steel in the machines for the continuous casting process has improved the internal quality of the cast product. Experimental work with stirrers situated at different positions of continuous casting machines of billets has been carried out. The in-mould stirrer is the one that produces a major modification of the billet internal structure, and also the biggest decrease of the central segregation. An in-mould electromagnetic coil has been developed which allows the use of high stirring power without producing an undesirable movement of the liquid steel in the meniscus zone, therefore no mould powders entrapments are produced. It has been developed a method for determining the optimum electric frequency of the stirrer.

    La instalación de agitadores electromagnéticos en las máquinas de colada continua del acero ha mejorado notablemente la calidad interna del producto colado. En este trabajo se describen los ensayos efectuados con bobinas agitadoras situadas en diferentes lugares en máquinas de colada continua de palanquilla. Se ha puesto de manifiesto que la bobina situada en el molde, al comienzo del proceso de solidificación, es la que produce una mayor modificación de la estructura de solidificación junto con una disminución de la segregación central de la palanquilla. Se ha diseñado una bobina para el molde que permite utilizar altas potencias de agitación sin que el movimiento del acero líquido, a la altura del menisco, produzca atrapes de los polvos de colada. Por otro lado, se ha encontrado un método por el que se puede calcular la frecuencia eléctrica óptima de trabajo de la bobina situada en el molde.

  1. Mejora de la tenacidad de un acero de ultraalto contenido en carbono nnediante unión por laminación con un acero al cromo y molibdeno

    Directory of Open Access Journals (Sweden)

    Pozuelo, M.

    2005-12-01

    Full Text Available Laminated composite materials containing five layers of ultrahigh carbon steel, 1.35%C, and five layers of a Cr-Mo steel were processed by roll bonding. The rolling procedure improves the bonding of layers and refines the microstructure, diminishing grain size and removing the pearlitic zones. Charpy impact tests were carried out to evaluate the impact properties. Toughness of the laminated composite was highly improved respect to the ultrahigh carbon steel. Moreover, it was double than that of the Cr-Mo steel in the arrester orientation. These results reveal the important role of the interfaces in the mechanical properties of the composite materials.

    Se procesaron mediante unión por laminación, dos materiales compuestos laminados de 10 capas: cinco capas de un acero de ultraalto contenido en carbono con 1,35 % C, alternadas con otras cinco de un acero al cromo y molibdeno. La laminación en caliente consolida la unión entre las capas y afina la microestructura, reduciendo el tamaño de grano y eliminando las zonas de perlita presentes inicialmente. Se realizaron ensayos de impacto Charpy para evaluar su resistencia al impacto. El material compuesto laminado mejoró sustancialmente la tenacidad del acero de ultraalto carbono, además de duplicar la resiliencia del acero al cromo y molibdeno en la orientación "en serie". Estos resultados ponen de manifiesto la importancia de las intercaras en las propiedades mecánicas de los materiales compuestos.

  2. Metodología para el cálculo de espesores límite libres de fase sigma durante el hipertemple en piezas de aceros dúplex de gran sección

    Directory of Open Access Journals (Sweden)

    Jimbert, P.

    2013-04-01

    Full Text Available To achieve the mechanical properties and corrosion resistance desired by duplex stainless steels used by the petrochemical and nuclear industry, parts are subjected to a hiperquenching heat treatment from about 1050 °C. This avoids the risk of intermetallic precipitation which drastically reduces the properties of these materials. However with increasing depth to which the deposits are present, the thicknesses for such pipes have been increased, resulting in higher levels of demand on all its manufacturing process, including the heat treatment. To avoid the precipitation of intermetallic phases such as sigma phase it is necessary to know the cooling profile in the center of the workpiece and for this purpose to know the value of the Surface Heat Transfer Coefficient (h is essential. This coefficient changes during the hiperquenching and its value is determined experimentally as it depends on several process parameters. Studies reveal that its value is stabilized within a few seconds. We can then assume that to know the cooling profile in the center of large sections it is only necessary to know the stabilized value of h. However, all the studies found in the literature are referred to diameters smaller than 100 mm. This paper has developed a methodology to predict the precipitation of intermetallic phases in duplex stainless steel parts with large thicknesses in industrial facilities from the calculation of h. This methodology allows us to calculate the cooling profiles without wasting any workpiece using one or more sensorized patterns with thermocouples and a subsequent simulation with ANSYS.Para conseguir las propiedades mecánicas y de corrosión deseadas en los aceros dúplex utilizados por la industria petro-química y nuclear se les somete a un tratamiento de hipertemple desde unos 1.050 °C. Con ello se evita el riesgo de aparición de precipitados intermetálicos que reducen drásticamente las propiedades de estos materiales. Sin

  3. In vivo behavior of a high performance duplex stainless steel.

    Science.gov (United States)

    Cigada, A; De Santis, G; Gatti, A M; Roos, A; Zaffe, D

    1993-01-01

    An in vivo investigation of a new high molybdenum and nitrogen duplex stainless steel (25Cr--7Ni--4Mo--0.3N) has been performed. Cylindrical pins and specially developed devices, to test in static conditions the in vivo localized corrosion resistance, made of this new duplex steel and of a common austenitic stainless steel were implanted in rabbit's femurs for 6 and 12 months. After sacrifice, SEM observations and EDS microanalyses to detect metallic ion release were carried out on the femur sections surrounding the pins. Morphologic observations with stereoscope and SEM were performed on the metallic surfaces of the special devices in order to detect the presence of localized corrosion. Both ion release and localized corrosion were observed for the specimens made of austenitic stainless steel, but not for those made of 25Cr--7Ni--4Mo--0.3N duplex stainless steel. PMID:10148344

  4. Sarcomatoid carcinoma of the renal pelvis in duplex kidney

    Institute of Scientific and Technical Information of China (English)

    CHEN Ge-ming; CHEN Shan-wen; XIA Dan; LI Jun; YAN Sheng; JIN Bai-ye

    2011-01-01

    Sarcomatoid transitional cell carcinoma of the renal pelvis is a rare neoplasm with only 14 well-illustrated examples reported previously. Duplex kidney is the most common congenital abnormality of the urinary tract, with an incidence of around 2%. Neoplasia of the renal pelvis in duplex kidney is rare. We reported a case whose sarcomatoid carcinoma originated from the upper portion of the duplicated renal pelvis with hydronephrosis, and total nephroureterectomy with bladder cuff excision surgery of both renal units was carried out. Because of the rare nature of renal pelvic sarcomatoid carcinoma and its apparent lack of response to adjuvant therapy, it is essential to do early diagnosis and early radical surgery to improve survival. It is important to stress the need for frequent and diligent monitoring or treating complex duplex kidney with hydronephrosis of either moiety in case of a risk of having neoplasias.

  5. Análise microestrutural e tenacidade ao impacto da ZAC do aço inoxidável ferrítico com 11%Cr

    Directory of Open Access Journals (Sweden)

    Temístocles de Sousa Luz

    2013-09-01

    Full Text Available O aço inoxidável ferrítico possibilita, em função de suas características, o uso em diversos campos da engenharia. Dentre esses é possível citar a industria do petróleo e gás, de celulose açucareira, de transporte, entre outras. Atualmente, o desenvolvimento de novas ligas para a substituição dos aços ao carbono no que se refere ao setor de transporte de carga, levou muitos fabricantes a adotarem a liga ferrítica com base de cromo entre 11% e 12%, implementando a tal situação, uma maior vida util. A utilização dessa nova classe de aço inoxidável ferrítico gera uma demanda no que tange à pesquisas das soldas desses aços. Neste trabalho, buscou-se analisar a região soldada de um aço inoxidável ferrítico experimental contendo 11% de cromo, realizando para tal um estudo de sua microestrutura, e tenacidade ao impacto do metal de base e da zona afetada pelo calor (ZAC. A avaliação mostrou bons resultados nas propriedades mecânicas medidas nas duas regiões analisadas. Entretanto, verificou-se uma perda acentuada da tenacidade ao impacto na ZAC em relação ao metal de base.

  6. THE INFLUENCE OF POSTHEAT TREATMENT ON FERRITE REDISTRIBUTION IN DUPLEX STEELS ELECTRON BEAM WELDS

    OpenAIRE

    Zita Iždinská; František Kolenič

    2009-01-01

    The duplex stainless steel is two-phase steel with the structure composed of austenite and ferrite with optimum austenite/ferrite proportion 50%. At present, classical arc processes for welding duplex steels are generally regarded as acceptable. On the other hand electron and laser beam welding is up to now considered less suitable for welding duplex steels. The submitted work presents the results of testing various thermal conditions at welding duplex stainless steel with electron beam. It w...

  7. Passivation of duplex stainless steel in solutions simulating chloride-contaminated concrete

    OpenAIRE

    Takenouti, H.; Soriano, L; Palacín, S.; Gutiérrez, A.; Velasco, F.; Blanco, G; Bautista, A.

    2007-01-01

    Most studies published to date on the corrosion behaviour of stainless reinforcing steel are based on austenitic steel. The market presence of corrugated duplex steel is growing, however. The present study compared passivity in 2205 type duplex and 304 type austenitic stainless steel. Polarization tests in chloride-containing Ca(OH)2 solutions confirmed the exceptional performance of duplex steels. X-ray photoelectronic spectroscopy (XPS) showed that the passive layer generated on duplex stai...

  8. Consideraciones teórico prácticas acerca de la soldadura de los aceros al carbono

    Directory of Open Access Journals (Sweden)

    Osmundo Héctor Rodríguez Pérez

    2006-01-01

    Full Text Available Se analizan los tres tipos de aceros al carbono y su clasificación desde el punto de vista de su soldabilidad. Se pueden observar los aspectos físico - químicos en la zona fundida, zona de transición y zona afectada por el calor. Existen varios aspectos en la tecnología de la soldadura de los aceros al carbono, tales como: preparación de los bordes, limpieza superficial, posición relativa de las piezas, precalentamiento, selección del material de aporte, deposición de los cordones, postcalentamiento, tratamiento térmico posterior y el control de la calidad de las uniones soldadas a tomar en cuenta para realizar la soldadura.

  9. Properties of duplex stainless steels made by powder metallurgy

    Directory of Open Access Journals (Sweden)

    M. Rosso

    2007-04-01

    Full Text Available Purpose: of this paper was to examine the mechanical properties of duplex stainless steels.Design/methodology/approach: In presented study duplex stainless steels were obtained through powder metallurgy starting from austenitic, martensitic base powders by controlled addition of alloying elements, such as Cr, Ni, Mo and Cu. In the studies behind the preparation of mixes, Schaeffler’s diagram was taken into consideration. Prepared mixes have been sintered in a vacuum furnace with argon backfilling at 1260°C for 1 h. After sintering: rapid cooling have been applied in argon atmosphere. Produced duplex stainless steels have been studied by scanning and optical microscopy. Mechanical properties such as tensile strength, impact energy, hardness and wear rate were evaluated.Findings: According to achieved results, it was affirmed that applied sintering method as well as powder mixes preparation allows for manufacturing the sintered duplex steels with good mechanical properties which depends on austenite/ferrite ratio in the microstructure and elements partitioning between phases. The additions of alloying elements powders (promoting formation ferritic and austenitic phase to master alloy powder, makes possible the formation of structure and properties of sintered duplex stainless steels. Sintered duplex steels obtained starting from austenitic and ferritic powders with admixture of elemental powders achieve lower mechanical properties when compared to composition obtained by mixing ferritic and austenitic powder in equal amounts.Research limitations/implications: According to the powders characteristic, the applied fast cooling rate seems to be a good compromise for mechanical properties and microstructures, nevertheless further tests should be carried out in order to examine different cooling rates.Originality/value: The use of elemental powders added to a stainless steel base showed its potentialities, in terms of fair compressibility and final

  10. On the Potential of Full Duplex Performance in 5G Ultra-Dense Small Cell Networks

    DEFF Research Database (Denmark)

    Gatnau, Marta; Fleischer, Marko; Berardinelli, Gilberto;

    2016-01-01

    Full duplex allows a device to transmit and receive simultaneously in the same frequency band, theoretically doubling the throughput compared to traditional half duplex systems. However, several limitations restrict the promised full duplex gain: non-ideal self-interference cancellation, increase...

  11. Corrosion induced by cathodic hydrogen in 2205 duplex stainless steel

    Science.gov (United States)

    Michalska, J.

    2011-05-01

    In this work new results about the influence of cathodic hydrogen on passivity and corrosion resistance of 2205 duplex stainless steel are described. The results were discussed by taking into account hydrogen charged samples and without hydrogen. The corrosion resistance to pitting was qualified with the polarization curves. The conclusion is that, hydrogen deteriorated the passive film stability and corrosion resistance to pitting of 2205 duplex stainless steel. The presence of hydrogen in passive films increases corrosion current density and decreases the potential of the film breakdown. It was also found that degree of susceptibility to hydrogen action was dependent on the hydrogen charging conditions.

  12. Corrosion induced by cathodic hydrogen in 2205 duplex stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Michalska, J, E-mail: joanna.k.michalska@polsl.pl [Department of Materials Science, Silesian University of Technology, Krasinskiego 8, 40-019 Katowice (Poland)

    2011-05-15

    In this work new results about the influence of cathodic hydrogen on passivity and corrosion resistance of 2205 duplex stainless steel are described. The results were discussed by taking into account hydrogen charged samples and without hydrogen. The corrosion resistance to pitting was qualified with the polarization curves. The conclusion is that, hydrogen deteriorated the passive film stability and corrosion resistance to pitting of 2205 duplex stainless steel. The presence of hydrogen in passive films increases corrosion current density and decreases the potential of the film breakdown. It was also found that degree of susceptibility to hydrogen action was dependent on the hydrogen charging conditions.

  13. Renal cell carcinoma arising in ipsilateral duplex system.

    Science.gov (United States)

    Mohan, Harsh; Kundu, Reetu; Dalal, Usha

    2014-09-01

    Congenital anomalies of the kidney and urinary tract are common and include a wide anatomic spectrum. Duplex systems are one of the more common renal anomalies, with the majority being asymptomatic. Little is known about the molecular pathogenesis of these anomalies; however, certain causative genes have been implicated. The finding of renal cell carcinoma arising in a kidney with the duplication of pelvicalyceal system and ureters, as in the present case, is uncommon. The association between a duplex system and renal cell carcinoma may be more than a coincidence, requiring a deeper insight and further elucidation. PMID:26328175

  14. Comparison of simulated and measured quantities of a duplex reactor

    Energy Technology Data Exchange (ETDEWEB)

    Koskela, M.; Kajava, M. [ABB Marine, Helsinki (Finland)

    1997-12-31

    The purpose of this article is to illustrate the use of an analog simulator as a design tool when designing new power electric equipment. The purpose of simulation is to predict the functionality of electrical equipment to be constructed. Duplex reactor is an electromagnetic device designed to reduce voltage harmonics and short circuit currents in the ship electrical network. In this report a comparison between simulated and measured electrical quantities of a duplex reactor has been made. The purpose of the measurements was to show the correct functioning of the reactor. The simulation results and the measured waveforms corresponds well to each other. (orig.) 4 refs.

  15. Evaluation of the thermal ageing of duplex stainless steels

    International Nuclear Information System (INIS)

    Three methods have been investigated to follow up the thermal ageing of duplex stainless steels: microhardness tests, instrumented ultramicrohardness tests and Small Angle Neutron Scattering (SANS) techniques. The values measured with these methods have been correlated with pertinent parameters of the metallurgical ageing phenomenon determined by Atom-Probe. These methods seem to be sensitive and reproducible enough to detect and follow up the ageing of duplex stainless steels. They can be applied on small samples (chips) drawn from in-service components. (authors). 10 refs., 9 figs., 3 tabs

  16. A Standard Duplex Fiber Optic Receptacle/Connector: Requirements And Test Methods

    Science.gov (United States)

    Barrett, Mike; Khalil, Ragai

    1988-12-01

    The concept for using a duplex connector for the Fiber Distributed Data Interface (FDDI) was formalized in late 1983. The duplex requirements were driven by both the token ring topology and by the need to simplify connectivity between stations. Though most users speak in terms of a duplex connector or Medium Interface Connector (MIC), the FDDI Physical Medium Dependent (PMD) document only defines the physical parameters for a duplex receptacle. The receptacle is the boundary between the station and the cable plant of an FDDI network and hence the only location at which station conformance can be verified. The duplex connector or plug is therefore part of the FDDI cable plant.

  17. Tratamiento térmico con láser de cuchillas de acero para uso agrícola

    Directory of Open Access Journals (Sweden)

    Muñiz, G.

    2003-12-01

    Full Text Available The present paper focuses on the laser surface treatment of mild steels with different %wt of carbon to be used as cutting blades in agricultural applications. The results are discussed in function of the metallographic study, hardness profiles, wear resistance and corrosion testing. Special attention is paid to the results of the results obtained with the experimental steel with carbon 0.33 %wt because it is a new promising material specifically developed to be applied in such agricultural uses. Metallographic studies showed three well defined regions: the laser treated zone, where solid state phase transformation occurs, the heat affected zone (HAZ with partial transformations and finally the bulk metal with the original microstructure. Surface hardness was in all cases higher than the base steel in a depth range 600 μm. Wear resistance is notably improved with laser heat treatment while no detrimental effects were induced in their specific corrosion resistance.

    En el presente trabajo se muestran los resultados obtenidos en el temple superficial mediante láser, sobre aceros con distintos contenidos en carbono susceptibles de empleo en la producción de cuchillas de corte para aplicaciones agrícolas. Se comparan los resultados de los distintos aceros en función de su estudio metalográfico, perfiles de dureza y ensayos de resistencia al desgaste y a la corrosión. Destacan los resultados obtenidos con el acero de 0,33 % de carbono, por tratarse de un acero experimental de producción reciente para su empleo en cuchillas de uso agrícola. Tras el estudio metalográfico, se aprecia, en la capa superficial del metal tratado, la existencia de tres zonas bien definidas: la zona tratada en la que ocurren las transformaciones de fase típicas del temple, una zona de transición, que podemos considerar como la zona afectada térmicamente (ZAT, con transformaciones parciales y, por último, el metal base con su microestructura de origen. Las

  18. Increased Y-chromosome detection by SRY duplexing

    DEFF Research Database (Denmark)

    Hansen, Morten Høgh; Clausen, Frederik Banch; Dziegiel, Morten Hanefeld

    2012-01-01

    Determining fetal sex noninvasively is dependent of a robust assay. We designed a novel SRY assay and combined it with a SRY assay from literature forming a duplex assay with the same fluorescent dye to increase detection of Y-chromosome at low cell-free fetal DNA or chimeric DNA concentrations....

  19. Optimisation of welding procedures for duplex and superduplex stainless steels

    International Nuclear Information System (INIS)

    Austenitic stainless steels are increasingly being replaced by duplex grades that can offer similar corrosion resistance with far higher strength. This increased strength makes it possible to reduce material consumption whilst also decreasing transport and construction costs. Although established welding methods used for austenitic steels can be used for duplex steels, modification of the procedures can lead to improved results. This paper reviews the welding of duplex stainless steel and examines precautions that may be required. The advantages and disadvantages of different welding methods are highlighted and some high productivity solutions are presented. The application of a more efficient process with a high deposition rate (e.g. flux- cored arc welding) can decrease labour costs. Further close control of heat input and interpass temperature can result in more favourable microstructures and final properties. Although welding adversely affects the corrosion resistance of austenitic and duplex stainless steels, particularly the pitting resistance, relative to the parent material, this problem can be minimised by proper backing gas protection and subsequent pickling.

  20. Hydrogen embrittlement of super duplex stainless steel in acid solution

    Energy Technology Data Exchange (ETDEWEB)

    Elhoud, A.M.; Renton, N.C.; Deans, W.F. [University of Aberdeen, School of Engineering, Aberdeen, AB24 3UE (United Kingdom)

    2010-06-15

    Super duplex stainless steel (SDSS) is a good choice of material when resistance to harsh environments is needed. Despite the material's excellent corrosion resistance and high strength, a number of in-service failures have been recorded. The root cause of these failures was environmentally induced cracking initiated at manufacturing and in-service metallurgical defects. In this study the hydrogen embrittlement of pre-strained super duplex stainless steel specimens was investigated after 48 h cathodic charging in 0.1 M H{sub 2}SO{sub 4}. The metallurgical changes that resulted from four levels of cold work (4, 8, 12, and 16% plastic strain) were considered and their effect on the embrittlement of the SDSS alloy was investigated. After hydrogen charging, the specimens were pulled immediately to failure and the mechanical properties evaluated. The obtaining fracture morphology was investigated using low and high magnification microscopy. Experimental results indicated that charging the super duplex stainless steel alloy with hydrogen caused varying degrees of embrittlement depending on cold work level. Increasing cold work resulted in a reduction of the elongation to failure. Microscopic investigation confirmed the significant effect of cold work on the hydrogen embrittlement susceptibility of the super duplex stainless steel alloy investigated. (author)

  1. Corrosion behavior of duplex stainless steel in sulphuric acid

    International Nuclear Information System (INIS)

    Duplex stainless steels are alloyed and processed to develop microstructure of roughly equal amounts of ferrite and austenite. Duplex stainless steel constitute a new class of materials because they have balanced amounts of ferrite and austenite. Since they have high content of chromium and molybdenum present, thus they have good corrosion resistance. Their corrosion resistance is double to that of annealed austenitic stainless steels with regard to pitting, crevice corrosion, sulphide stress corrosion, and chloride stress corrosion environments. The corrosion behavior of duplex stainless steel in various concentrations of sulphuric acid was studied. The reactions were carried out by placing the steel specimen in a beaker containing a known concentration of sulphuric acid at room temperature for a definite period. Pits were initiated in duplex stainless steel specimen and the propagation of pits depends upon the concentration of the acid solution in which the sample is in contact. The weight loss for definite period of time were measured and corrosion rates were calculated in millimetres per year. The corrosion rates increases with an increase in acid concentration at room temperature. A comparison of the results obtained from various concentrations of sulphuric acid with the same concentrations of nitric acid is also discussed. (author)

  2. Analysis of full-duplex relay networks with opportunistic scheduling

    Directory of Open Access Journals (Sweden)

    Lei Shao

    2015-05-01

    Full Text Available This Letter addresses a two-hop decode-and-forward relay system with full-duplex relaying and opportunistic scheduling. Exact expressions for outage probability, average capacity and symbol error rate are presented in an independent identically distributed Rayleigh fading environment. Numerical and simulated results show the validity of the analytical results.

  3. Duplex numbers, diffusion systems, and generalized quantum mechanics

    OpenAIRE

    KOCIK, Jerzy

    2012-01-01

    We show that the relation between the Schr\\"odinger equation and diffusion processes has an algebraic nature and can be revealed via the structure of "duplex numbers." This helps one to clarify that quantum mechanics cannot be reduced to diffusion theory. Also, a generalized version of quantum mechanics where $\\C$ is replaced by a normed algebra with a unit is proposed.

  4. Técnicas para revelar el borde de grano austenítico en aceros microaleados

    Directory of Open Access Journals (Sweden)

    García de Andrés, Carlos

    2001-08-01

    Full Text Available The prior austenite grain size (PAGS exerts an important influence on the microstructures forged by continuous cooling in the steel and on their mechanical properties. Since microalloyed steels have received considerable attention in the last years and enormous difficulties have been repetitively to reveal the austenite grain boundaries in these steels, this work analyzes the different techniques effective in that sense, which enable thus an accurate determination of the PAGS. This paper presents results obtained applying different conventional techniques such us chemical etching of quenched microstructures, the application of thermal cycles that enable the formation of phases around the prior austenite grain boundaries or oxidation etching which reveals the austenite grain boundaries by the preferential accumulation of oxides. Finally, an innovative and effective technique to reveal the prior austenite grain boundaries is presented. This technique is based on the preferential transfer of matter from the grain boundaries to the surrounding austenite by complicated mechanisms such as evaporation-condensation and volume and surface diffusion of atoms.

    El tamaño de grano austenítico (TGA tiene una gran influencia sobre la microestructura final y sobre las propiedades mecánicas de los productos obtenidos por transformación anisotérmica del acero. Debido a la considerable atención que se está prestando a los aceros microaleados en los últimos años y a las dificultades que se encuentran en muchos casos para poder revelar los bordes de grano austenítico de estos aceros, en este trabajo se han analizado las técnicas que lo hacen posible, permitiendo así la determinación fiable del TGA. En este sentido, se presentan los resultados obtenidos al aplicar aislada y combinadamente distintas técnicas tradicionales, como el ataque químico de microestructuras obtenidas directamente por temple, la aplicación de diferentes tipos de ciclos t

  5. Ion Mobility Spectrometry Reveals Duplex DNA Dissociation Intermediates

    Science.gov (United States)

    Burmistrova, Anastasia; Gabelica, Valérie; Duwez, Anne-Sophie; De Pauw, Edwin

    2013-11-01

    Electrospray ionization (ESI) soft desolvation is widely used to investigate fragile species such as nucleic acids. Tandem mass spectrometry (MS/MS) gives access to the gas phase energetics of the intermolecular interactions in the absence of solvent, by following the dissociation of mass-selected ions. Ion mobility mass spectrometry (IMS) provides indications on the tridimensional oligonucleotide structure by attributing a collision cross section (CCS) to the studied ion. Electrosprayed duplexes longer than eight bases pairs retain their helical structure in a solvent-free environment. However, the question of conformational changes under activation in MS/MS studies remains open. The objective of this study is to probe binding energetics and characterize the unfolding steps occurring prior to oligonucleotide duplex dissociation. Comparing the evolution of CCS with collision energy and breakdown curves, we characterize dissociation pathways involved in CID-activated DNA duplex separation into single strands, and we demonstrate here the existence of stable dissociation intermediates. At fixed duplex length, dissociation pathways were found to depend on the percentage of GC base pairs and on their position in the duplex. Our results show that pure GC sequences undergo a gradual compaction until reaching the dissociation intermediate: A-helix. Mixed AT-GC sequences were found to present at least two conformers: a classic B-helix and an extended structure where the GC tract is a B-helix and the AT tract(s) fray. The dissociation in single strands takes place from both conformers when the AT base pairs are enclosed between two GC tracts or only from the extended conformer when the AT tract is situated at the end(s) of the sequence.

  6. Free energy estimation of short DNA duplex hybridizations

    Directory of Open Access Journals (Sweden)

    Leger Serge

    2010-02-01

    Full Text Available Abstract Background Estimation of DNA duplex hybridization free energy is widely used for predicting cross-hybridizations in DNA computing and microarray experiments. A number of software programs based on different methods and parametrizations are available for the theoretical estimation of duplex free energies. However, significant differences in free energy values are sometimes observed among estimations obtained with various methods, thus being difficult to decide what value is the accurate one. Results We present in this study a quantitative comparison of the similarities and differences among four published DNA/DNA duplex free energy calculation methods and an extended Nearest-Neighbour Model for perfect matches based on triplet interactions. The comparison was performed on a benchmark data set with 695 pairs of short oligos that we collected and manually curated from 29 publications. Sequence lengths range from 4 to 30 nucleotides and span a large GC-content percentage range. For perfect matches, we propose an extension of the Nearest-Neighbour Model that matches or exceeds the performance of the existing ones, both in terms of correlations and root mean squared errors. The proposed model was trained on experimental data with temperature, sodium and sequence concentration characteristics that span a wide range of values, thus conferring the model a higher power of generalization when used for free energy estimations of DNA duplexes under non-standard experimental conditions. Conclusions Based on our preliminary results, we conclude that no statistically significant differences exist among free energy approximations obtained with 4 publicly available and widely used programs, when benchmarked against a collection of 695 pairs of short oligos collected and curated by the authors of this work based on 29 publications. The extended Nearest-Neighbour Model based on triplet interactions presented in this work is capable of performing accurate

  7. DMT of Multi-hop Cooperative Networks - Part II: Half-Duplex Networks with Full-Duplex Performance

    CERN Document Server

    Sreeram, K; Kumar, P Vijay

    2008-01-01

    We consider single-source single-sink (ss-ss) multi-hop relay networks, with slow-fading links and single-antenna half-duplex relay nodes. In a companion paper, we established some basic results which laid the foundation for the results presented here. In the present paper, we consider two families of networks of half-duplex networks. KPP networks may be viewed as the union of K node-disjoint parallel relaying paths. Generalizations of these networks include KPP(I) networks, which permit interference between paths and KPP(D) networks, which possess a direct link between source and sink. We characterize the DMT of these families of networks completely and show that they can achieve the cut-set bound, thus proving that full-duplex performance can be obtained even in the presence of the half-duplex constraint. We then consider layered networks, and prove that a linear DMT between maximum diversity and maximum multiplexing gain is achievable. All protocols in this paper are explicit and use only amplify-and-forwa...

  8. Reciclado de los residuos siderúrgicos de fabricación de acero. Nueva alternativa

    Directory of Open Access Journals (Sweden)

    Fernández López, Miguel

    2001-08-01

    Full Text Available A brief description of a new process for recycling hot electric steelmaking wastes of high iron oxides content, from ministeel mills that produce common and special steels is made. The new process is designed to get the best treatment cost for the residues recycling. It is based in the application of the principles of technologies experienced in ministeel industries. This is possible because the following improvements are obtained: a obtention of a commercial product of high zinc oxide content; b avoidance of new toxic wastes; c use of low cost process energy; d increase of metallic yield in the residues; and e treatment of residues in the mill ("in situ", or from other ministeel mill ("off site". Previous technologies precedents of the new process, are given and a comparative study between the new recycling process and the same recycling process without heating pretreatment using the same furnace is made. Electric steel making wasts. Recycling

    Se presenta una breve descripción de un nuevo procedimiento de reciclado de residuos, de alto contenido en óxidos de hierro, generados en miniacerías fabricantes de acero por hornos eléctricos de arco (común y especial, dentro y/o fuera de las instalaciones del generador (“in situ” y ''off site''. El procedimiento pretende, la reducción de los costes de reciclado de dichos residuos, respecto a procedimientos actuales, al incluir las siguientes mejoras: a obtención de un producto comercializable rico en ZnO; b ausencia de residuos tóxicos necesitados de tratamiento; c utilización de energía de proceso de bajo coste, en sustitución parcial de energía eléctrica; d aumento de la recuperación de metales en los residuos; y e versatilidad para poder reciclar los residuos ”in situ'' u ''off site", según procedan de una o de varias miniacerías, respectivamente. Se describen los fundamentos y sus precedentes tecnológicos, así como un breve an

  9. EFECTO DEL PRECALENTAMIENTO Y LA SEVERIDAD DE TEMPLE SOBRE LA RESISTENCIA AL DESGASTE ADHESIVO DEL ACERO AUSTENÍTICO AL MANGANESO

    Directory of Open Access Journals (Sweden)

    OSCAR FABIÁN HIGUERA COBOS

    2010-01-01

    Full Text Available En este trabajo de investigación se estudió el efecto del precalentamiento y la severidad de temple sobre la resistencia al desgaste adhesivo del acero austenítico al manganeso ASTM A 128 grado C. El material se sometió a ciclos térmicos de temple y revenido con y sin precalentamiento con el fin de evaluar su influencia sobre la resistencia al desgaste. Posteriormente el material fue sometido a prueba según norma ASTM G83 y se determinó que el acero Austenítico al manganeso, es un material que presenta una microestructura metaestable en condiciones estables y no debe ser sometido a tratamiento térmico de revenido a altas temperaturas debido que favorece la descomposición de esta a ferrita (fase blanda de los acero y por ende disminuye su resistencia al desgaste.

  10. Full-Duplex Communications in Large-Scale Cellular Networks

    KAUST Repository

    AlAmmouri, Ahmad

    2016-04-01

    In-band full-duplex (FD) communications have been optimistically promoted to improve the spectrum utilization and efficiency. However, the penetration of FD communications to the cellular networks domain is challenging due to the imposed uplink/downlink interference. This thesis presents a tractable framework, based on stochastic geometry, to study FD communications in multi-tier cellular networks. Particularly, we assess the FD communications effect on the network performance and quantify the associated gains. The study proves the vulnerability of the uplink to the downlink interference and shows that the improved FD rate gains harvested in the downlink (up to 97%) comes at the expense of a significant degradation in the uplink rate (up to 94%). Therefore, we propose a novel fine-grained duplexing scheme, denoted as α-duplex scheme, which allows a partial overlap between the uplink and the downlink frequency bands. We derive the required conditions to harvest rate gains from the α-duplex scheme and show its superiority to both the FD and half-duplex (HD) schemes. In particular, we show that the α-duplex scheme provides a simultaneous improvement of 28% for the downlink rate and 56% for the uplink rate. We also show that the amount of the overlap can be optimized based on the network design objective. Moreover, backward compatibility is an essential ingredient for the success of new technologies. In the context of in-band FD communication, FD base stations (BSs) should support HD users\\' equipment (UEs) without sacrificing the foreseen FD gains. The results show that FD-UEs are not necessarily required to harvest rate gains from FD-BSs. In particular, the results show that adding FD-UEs to FD-BSs offers a maximum of 5% rate gain over FD-BSs and HD-UEs case, which is a marginal gain compared to the burden required to implement FD transceivers at the UEs\\' side. To this end, we shed light on practical scenarios where HD-UEs operation with FD-BSs outperforms the

  11. Transferencia de calor en la colada continua de aceros. II parte. Enfriamiento secundario

    Directory of Open Access Journals (Sweden)

    Cicutti, C.

    1997-12-01

    Full Text Available Once the strand leaves the mold, the solidification of steel progresses due to the heat extracted in the secondary cooling zone of the continuous casting machine. In this zone, heat is extracted mainly by: the incidence of water from sprays, radiation to surroundings contact with rolls and run out water accumulated between rolls and strand. In this work, all these mechanisms are evaluated and, when it is possible, they are quantified. Methods which are usually employed to measure solidification profiles in the continuous casting machine are also reviewed. Finally, the incidence of secondary cooling on the quality of cast products is discussed.

    La solidificación del acero iniciada en el molde continúa en la zona de enfriamiento secundario de la máquina donde el calor es extraído, principalmente por la incidencia del agua de los rociadores, la radiación al medio ambiente, el contacto con los rodillos y el agua acumulada en ellos. En este trabajo se revisa cada uno de estos mecanismos determinando, en los casos en que es posible, valores cuantitativos de los mismos. Además, se analizan los distintos métodos empleados para medir el avance del espesor solidificado en la máquina de colada continua. Por último, se discute la incidencia del enfriamiento secundario en la calidad final de los productos colados.

  12. Aplicabilidad de un concreto de escoria activada alcalinamente como material protector del acero de refuerzo

    Directory of Open Access Journals (Sweden)

    Robinson de Jesús Torres Gómez, William A. Aperador Ch., Enrique Vera López,Rubi Mejía de Gutiérrez

    2011-05-01

    Full Text Available Se presentan los resultados del análisis electroquímico de las  barras  de  acero  embebidas  en  un  concreto  no convencional usado internacionalmente para reparación de estructuras. Este concreto utiliza materiales de desecho de otros procesos; en este caso específico se empleó escoria siderúrgica de  la empresa Acerías Paz del Río S.A. Se estudio el comportamiento frente a la corrosión generada por  los iones cloruro, con el uso de la técnica de resistencia lineal a la polarización LPR y pulso galvanostático GPT. Simultáneamente, se compararon los resultados con otras probetas  fabricadas  con  cemento  Portland  tipo  I.  Se realizaron mediciones con  intervalos de veinte días durante nueve  meses  y  finalmente  se  establecieron  las características protectoras del concreto.

  13. Diseño de una unidad de proceso para el tratamiento superficial (cromado y niquelado) de piezas de acero para automoción

    OpenAIRE

    2012-01-01

    El proyecto se centra en la desmineralización continua de aguas residuales de lavado para su posterior reutilización en baños de tratamiento superficial de piezas de acero para automoción. Concretamente se centra en tratar un número máximo de 300000 piezas anuales, 75 piezas diarias. Tratando un volumen máximo de 16 m3/h de agua residual procedente de los baños de tratamiento superficial de piezas de acero.

  14. Tensile properties of duplex UNS S32205 and lean duplex UNS S32304 steels and the influence of short duration 475 ºC aging

    Directory of Open Access Journals (Sweden)

    Sérgio Souto Maior Tavares

    2012-12-01

    Full Text Available Duplex stainless steels are high strength and corrosion resistant steels extensively used in the petrochemical and chemical industries. The aging at 475 ºC for long periods of time provokes embrittlement and deterioration of corrosion resistance. However, short duration aging at 475 ºC may be used as heat treatment to improve mechanical resistance with small decrease in the other properties. In this work the flow stress curves of lean duplex UNS S32304 and duplex UNS S32205 steels were modeled with Hollomon's equation and work hardening exponents (n were determined. The analyses were conducted in specimens annealed and heat treated at 475 ºC for short periods of time. The aging at 475 ºC for 4 hours, 8 hours and 12 hours promoted significant hardening with small decrease of ductility. The work hardening exponents of both steels were compared, being higher in the duplex steel than in the lean duplex grade.

  15. Weld oxide formation on lean duplex stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Westin, E.M. [Outokumpu Stainless, Avesta Research Centre, P.O. Box 74, SE-774 22 Avesta (Sweden)], E-mail: elin.westin@outokumpu.com; Olsson, C.-O.A. [Outokumpu Stainless, Avesta Research Centre, P.O. Box 74, SE-774 22 Avesta (Sweden); Hertzman, S. [Outokumpu Stainless Research Foundation, Brinellvaegen 23, SE-100 44 Stockholm (Sweden)

    2008-09-15

    Weld oxides have a strong influence on corrosion resistance, but have hitherto only been studied to a limited extent for duplex stainless steels. X-ray photoelectron spectroscopy (XPS) has here been used to study heat tint formed on gas tungsten arc (GTA) welds on the commercial duplex grades LDX 2101 (EN 1.4162/UNS S32101) and 2304 (EN 1.4362/UNS S32304) welded with and without nitrogen additions to the shielding gas. The process of heat tint formation is discussed in terms of transport phenomena to explain the effect of atmosphere, temperature and composition. The oxides formed were found to be enriched in manganese and corrosion testing shows that nitrogen has a strong influence on the weld oxide. A mechanism is proposed including evaporation from the weld pool and subsequent redeposition.

  16. Comments on process of duplex coatings on aluminum alloys

    Institute of Scientific and Technical Information of China (English)

    Samir H.A.; QIAN Han-cheng(钱翰城); XIA Bo-cai(夏伯才); WU Shi-ming(吴仕明)

    2004-01-01

    Despite the great achievements made in improvement of wear resistance properties of aluminum alloys,their applications in heavy surface load-bearing are limited. Single coating is insufficient to produce the desired combination of surface properties. These problems can be solved through the duplex coatings. The aim of the present study is to overview the research advances on processes of duplex coatings on aluminum alloys combined with micro plasma oxidation process and with other modern processes such as physical vapour deposition and plasma assisted chemical vapour deposition and also to evaluate the performance of micro plasma oxidation coatings in improving the load-bearing, friction and wear resistance properties of aluminum alloys in comparison with other coatings. Wherein, a more detailed presentation of the processes and their performances and disadvantages are given as well.

  17. Listen and talk full-duplex cognitive radio networks

    CERN Document Server

    Liao, Yun; Han, Zhu

    2016-01-01

    This brief focuses on the use of full-duplex radio in cognitive radio networks, presenting a novel spectrum sharing protocol that allows the secondary users to simultaneously sense and access the vacant spectrum. This protocol, called “Listen-and-talk” (LAT), is evaluated by both mathematical analysis and computer simulations in comparison with other existing protocols, including the listen-before-talk protocol. In addition to LAT-based signal processing and resource allocation, the brief discusses techniques such as spectrum sensing and dynamic spectrum access. The brief proposes LAT as a suitable access scheme for cognitive radio networks, which can support the quality-of-service requirements of these high priority applications. Fundamental theories and key techniques of cognitive radio networks are also covered. Listen and Talk: Full-duplex Cognitive Radio Networks is designed for researchers, developers, and professionals involved in cognitive radio networks. Advanced-level students studying signal pr...

  18. Functional surfaces on duplex stainless steel by lasercladding; Funktionale Oberflaechen auf Duplex-Stahl durch Laserfeinbeschichten

    Energy Technology Data Exchange (ETDEWEB)

    Dwars, A. [KSB Aktiengesellschaft, Pegnitz (Germany); Emmel, A. [FH-Amberg, Weiden (Germany)

    2008-08-15

    The product-lubricated axial and radial bearings installed in multistage high-pressure pumps inevitably encounter severe mixed friction conditions as the pumps start and stop. This leads to extremely high tribological loads on the bearing components, compounded by the effects of a highly corrosive pumped fluid. The present paper describes a laser cladding process which produces near-net-shape coatings of new, highly corrosion and wear resistant functional layers which can be deposited directly on high-alloy stainless steels without requiring additional buffer layers and without affecting the mechanical properties and corrosion resistance of the substrate. The results cover the solidification behaviour of the coatings as well as the microstructure resulting from various heat treatment conditions. In addition, the technological properties of the coatings and the resulting composites are discussed. The coating systems are tested as to their corrosion resistance and tribological characterization in a pump-specific tribological system. (Abstract Copyright [2008], Wiley Periodicals, Inc.) [German] Waehrend der An- und Abfahrvorgaenge mehrstufiger Hochdruckpumpen durchlaufen mediumgeschmierte Axial- und Radiallager unweigerlich einen stark ausgepraegten Mischreibungsbereich. Dies fuehrt zu einer extrem hohen tribologischen Belastung der Lagerkomponenten bei gleichzeitig hoher korrosiver Belastung durch das Foerdermedium. Der vorliegende Beitrag beschreibt einen Laserbeschichtungsprozess zur Erzeugung von hoch korrosions- und verschleissfesten sowie gleichzeitig tribologisch geeigneten Funktionsschichten, die ohne zusaetzliche Pufferung direkt auf hochlegierten Duplex-Staehlen aufgebracht werden koennen, ohne die Eigenschaften des Grundmaterials zu verschlechtern. Die dargestellten Ergebnisse umfassen sowohl das Erstarrungsverhalten der erzeugten Schichten, als auch die Grenzflaechen- und Gefuegeausbildung der entstehenden Werkstoffverbunde in Abhaengigkeit der moeglichen

  19. Rapid commutation duplexer with phase-related outputs

    Science.gov (United States)

    Roveda, R.; Cattarin, G.; Digregorio, C.; Parrucci, U.

    Design criteria and the realization of an X-band waveguide rapid commutation duplexer, in production, are presented. By means of a digital TTL command it is capable of operating in three different conditions: all the power is conveyed to a single output; the poweer is equally divided between two in-phase outputs; and it is equally divided between two counter-phase outputs. In a monopulse radar this permits the electronic scanning of the antenna beam.

  20. Modeling and optimization of turning duplex stainless steels

    OpenAIRE

    Ali, Rastee Dalshad

    2015-01-01

    In the present dissertation, machining investigations into duplex stainless steels are performed under different and systematically well-structured modeling and optimization frameworks. Focusing on the main objective of finding optimum machining process parameters and com-prehensively applying the statistical design of experiments to design the experiments, the study tackles the challenge of integrating modeling and optimization algorithms using six different approaches. Firstly, sets of non-...

  1. Herpes zoster duplex bilateralis in an immunocompetent host

    Directory of Open Access Journals (Sweden)

    Pratik Gahalaut

    2012-01-01

    Full Text Available Varicella zoster virus causes both chicken pox and herpes zoster. The phenomenon of herpes zoster occurring concurrently in two non-contiguous dermatomes involving different halves of the body is termed herpes zoster duplex bilateralis (HZDB. Few cases, reported in the literature, were seen in either an immunosuppressed host or in the older age group. Here we present a case of HZDB in an immunocompetent host, probably the first in India.

  2. Herpes zoster duplex bilateralis in an immunocompetent host

    OpenAIRE

    Pratik Gahalaut; Sandhya Chauhan

    2012-01-01

    Varicella zoster virus causes both chicken pox and herpes zoster. The phenomenon of herpes zoster occurring concurrently in two non-contiguous dermatomes involving different halves of the body is termed herpes zoster duplex bilateralis (HZDB). Few cases, reported in the literature, were seen in either an immunosuppressed host or in the older age group. Here we present a case of HZDB in an immunocompetent host, probably the first in India.

  3. Herpes zoster duplex bilateralis in an immunocompetent host.

    Science.gov (United States)

    Gahalaut, Pratik; Chauhan, Sandhya

    2012-01-01

    Varicella zoster virus causes both chicken pox and herpes zoster. The phenomenon of herpes zoster occurring concurrently in two non-contiguous dermatomes involving different halves of the body is termed herpes zoster duplex bilateralis (HZDB). Few cases, reported in the literature, were seen in either an immunosuppressed host or in the older age group. Here we present a case of HZDB in an immunocompetent host, probably the first in India. PMID:23130258

  4. Thermal fatigue of austenitic and duplex stainless steels

    OpenAIRE

    Virkkunen, Iikka

    2001-01-01

    Thermal fatigue behavior of AISI 304L, AISI 316, AISI 321, and AISI 347 austenitic stainless steels as well as 3RE60 and ACX-100 duplex stainless steels was studied. Test samples were subjected to cyclic thermal transients in the temperature range 20 - 600°C. The resulting thermal strains were analyzed with measurements and numerical calculations. The evolution of thermal fatigue damage was monitored with periodic residual stress measurements and replica-assisted microscopy. The elastic strai...

  5. Hyperbaric welding of duplex stainless steel pipelines offshore.

    OpenAIRE

    Farrell, J.

    1996-01-01

    Three duplex stainless steels (Avesta 2205, Sandvik SAF2507 and Zeron 100) were successfully welded automatically at a range of pressures from 1 to 32bar. The gas tungsten arc (GTA) welding process was chosen as it allows a high degree of control to be exercised during welding. Initial autogenous bead on plate welds established the effects of pressure on the welding process and allowed the process parameters to be determined for subsequent experiments. Analysis of the eff...

  6. Utilización del mineral de manganeso (pirolusita) en la producción de aceros al carbono

    OpenAIRE

    Aerles Batista-Cabrera; Efraín Navas-Medina

    2003-01-01

    Los métodos tradicionales de producción de acero utilizan el ferromanganeso para obtener el porcentaje de Mn en la marca establecida según la norma cubana, pero este compuesto es altamente costoso. Se ensayó, en la producción del Ac 35, sustituir el ferromanganeso por el mineral pirolusita (MnO2) con el fin de reducir los costos. Se evaluaron dos variantes de sustitución: la primera consiste en añadir el mineral con virutas de aluminio y coque (o residuos de electrodos) sobre la escoria del m...

  7. Conformado por vía coloidal de recubrimientos en la cara interna de un tubo de acero

    OpenAIRE

    Ferrari, B.; Moreno Botella, Rodrigo María; Rodríguez Galicia, J. L.; Rojas, E.

    2004-01-01

    [ES] El desarrollo de las tecnologías de fabricación de recubrimientos presenta importantes limitaciones relativas a los espesores de las capas fabricadas y a la geometría de los substratos a recubrir. En este trabajo se proponen dos procesos de conformado coloidal de revestimientos cerámicos y metálicos en la cara interna de un tubo de acero. El revestimiento cerámico (CaCO3) se ha conformado por deposición electroforética (EPD). Para ello se han preparado suspensiones estables de C...

  8. Análisis de placas planas de fibrocemento en sección mixta con perfiles de acero

    OpenAIRE

    Mariscal Jiménez, Juan Gabriel

    2001-01-01

    La presente investigación tiene como objetivo principal analizar el comportamiento general de las láminas planas de fibrocemento actuando en sección mixta con perfiles de acero. Este trabajo se divide en tres fases : Una preliminar que involucra una modelación completa por elementos finitos de diferentes sistemas de lámina y perfil metálico conectados, una segunda en la que se generan modelos equivalentes a los anteriores para ser ensayados en el laboratorio y poder comparar resultados, y una...

  9. Duplex-Selective Ruthenium-based DNA Intercalators

    Science.gov (United States)

    Shade, Chad M.; Kennedy, Robert D.; Rouge, Jessica L.; Rosen, Mari S.; Wang, Mary X.; Seo, Soyoung E.; Clingerman, Daniel J.

    2016-01-01

    We report the design and synthesis of small molecules that exhibit enhanced luminescence in the presence of duplex rather than single-stranded DNA. The local environment presented by a well-known [Ru(dipyrido[2,3-a:3',2'-c]phenazine)L2]2+-based DNA intercalator was modified by functionalizing the bipyridine ligands with esters and carboxylic acids. By systematically varying the number and charge of the pendant groups, it was determined that decreasing the electrostatic interaction between the intercalator and the anionic DNA backbone reduced single-strand interactions and translated to better duplex specificity. In studying this class of complexes, a single RuII complex emerged that selectively luminesces in the presence of duplex DNA with little to no background from interacting with single stranded DNA. This complex shows promise as a new dye capable of selectively staining double versus single-stranded DNA in gel electrophoresis, which cannot be done with conventional SYBR dyes. PMID:26119581

  10. Development and test evaluation of duplex steam reformer tube

    International Nuclear Information System (INIS)

    For HTR applications involving a steam reformer (SR), it is uncertain whether an intermediate heat exchanger (IHX) is required. There are several system configurations that could be developed for the application of nuclear heat using the steam reformer reaction. The considerations (advantages vs. disadvantages) for each of the system configurations are summarized. The approach that technically and economically appears to be the most attractive, in studies conducted by General Electric, combines the SR process heat exchanger and the IHX in a single component using a duplex tube. A central question concerning the duplex tube concept is whether the design would provide adequate leak monitoring capability and significant reduction in tritium and hydrogen diffusion, while introducing only a small increase in overall temperature difference from the helium to the process gas. A cooperative GE-KFA effort was undertaken to develop, fabricate, test, and evaluate a duplex steam reformer tube. GE was responsible for the development and fabrication of the tube, and KFA was responsible for testing the tube in the EVA I facility at Juelich. Both GE and KFA are evaluating the thermochemical and metallurgical test data. Actual fabrication of the tube was performed by Foster-Wheeler in accordance with the GE design. This paper reviews the highlights of the fabrication development and preliminary evaluation of the test data

  11. EFFECT OF INTERMETALLIC PHASES ON CORROSION BEHAVIOR AND MECHANICAL PROPERTIES OF DUPLEX STAINLESS STEEL AND SUPER-DUPLEX STAINLESS STEEL

    Directory of Open Access Journals (Sweden)

    Prabhu Paulraj

    2015-08-01

    Full Text Available Duplex Stainless Steels (DSS and Super Duplex Stainless Steel (SDSS have excellent integration of mechanical and corrosion properties. However, the formation of intermetallic phases is a major problem in their usage. The mechanical and corrosion properties are deteriorated due to the presence of intermetallic phases. These phases are induced during welding, prolonged exposure to high temperatures, and improper heat treatments. The main emphasis of this review article is on intermetallic phases and their effects on corrosion and mechanical properties. First the effect of various alloying elements on DSS and SDSS has been discussed followed by formation of various intermetallic phases. The intermetallic phases affect impact toughness and corrosion resistance significantly. Their deleterious effect on weldments has also been reviewed.

  12. Characterization of duplex stainless steel weld metals obtained by hybrid plasma-gas metal arc welding

    OpenAIRE

    Koray Yurtisik; Suha Tirkes; Igor Dykhno; C. Hakan Gur; Riza Gurbuz

    2013-01-01

    Despite its high efficiency, autogenous keyhole welding is not well-accepted for duplex stainless steels because it causes excessive ferrite in as-welded duplex microstructure, which leads to a degradation in toughness and corrosion properties of the material. Combining the deep penetration characteristics of plasma arc welding in keyhole mode and metal deposition capability of gas metal arc welding, hybrid plasma - gas metal arc welding process has considered for providing a proper duplex mi...

  13. Microstructure and properties of welds in the lean duplex stainless steel LDX 2101

    OpenAIRE

    Westin, Elin M.

    2010-01-01

    Duplex stainless steels can be very attractive alternatives to austenitic grades due to their almost double strength at equal pitting corrosion resistance. When welding, the duplex alloys normally require addition of filler metal, while the commodity austenitic grades can often be welded autogenously. Over-alloyed consumables are used to counteract segregation of important alloying elements and to balance the two phases, ferrite and austenite, in the duplex weld metal. This work focuses on th...

  14. Probing the Transcription Mechanisms of Reovirus Cores with Molecules That Alter RNA Duplex Stability▿

    OpenAIRE

    Demidenko, Alexander A.; Nibert, Max L.

    2009-01-01

    The mammalian reovirus (MRV) genome comprises 10 double-stranded RNA (dsRNA) segments, packaged along with transcriptase complexes inside each core particle. Effects of four small molecules on transcription by MRV cores were studied for this report, chosen for their known capacities to alter RNA duplex stability. Spermidine and spermine, which enhance duplex stability, inhibited transcription, whereas dimethyl sulfoxide and trimethylglycine, which attenuate duplex stability, stimulated transc...

  15. Unzipping Kinetics of Duplex DNA Containing Oxidized Lesions in an α-Hemolysin Nanopore

    OpenAIRE

    Jin, Qian; Fleming, Aaron M.; Burrows, Cynthia J.; White, Henry S.

    2012-01-01

    The unzipping kinetics for lesion-containing DNA duplexes was studied in an α-hemolysin (α-HL) nanopore. The lesion of focus was the guanine two-electron oxidation product, 8-oxo-7,8-dihydroguanine (OG), and its further oxidation products, the hydantoins guanidinohydantoin (Gh) and spiroiminodihydantoin (Sp). The voltage-driven unzipping of individual duplex DNA molecules with symmetrical overhangs was carried out by pulling one strand of the duplex through the α-HL channel using an electrica...

  16. ATP hydrolysis is required for DEAD-box protein recycling but not for duplex unwinding

    OpenAIRE

    Liu, Fei; Putnam, Andrea; Jankowsky, Eckhard

    2008-01-01

    DEAD-box proteins, the largest helicase family, catalyze ATP-dependent remodeling of RNA–protein complexes and the unwinding of RNA duplexes. Because DEAD-box proteins hydrolyze ATP in an RNA-dependent fashion, the energy provided by ATP hydrolysis is commonly assumed to drive the energetically unfavorable duplex unwinding. Here, we show efficient unwinding of stable duplexes by several DEAD-box proteins in the presence of the nonhydrolyzable ATP analog ADP-beryllium fluoride. Another ATP ana...

  17. Influencia del Calor Aportado y Metal de Aporte Sobre las Propiedades Mecánicas y la Microestructura de Juntas Soldadas por FCAW de Acero Microaleado de Alta Resistencia

    OpenAIRE

    César Marconi; María José Castillo; Leonardo Boccanera; Mabel Ramini

    2015-01-01

    ResumenActualmente, los aceros microaleados son ampliamente utilizados en reemplazo de los aceros al C y C-Mn por sus ventajas en cuanto a propiedades mecánicas, resistencia a la corrosión y soldabilidad, permitiendo una reducción de peso de los vehículos y estructuras sin detrimento de su resistencia. Cuando estos aceros son soldados, el ciclo térmico de la soldadura provoca cambios microestructurales que modifican sus propiedades originales. El calor aportado (HI: heat input) es una de las ...

  18. Characterization of microstructure and texture across dissimilar super duplex/austenitic stainless steel weldment joint by super duplex filler metal

    Energy Technology Data Exchange (ETDEWEB)

    Eghlimi, Abbas, E-mail: a.eghlimi@ma.iut.ac.ir [Department of Materials Engineering, Isfahan University of Technology, Isfahan 84156-83111 (Iran, Islamic Republic of); Shamanian, Morteza [Department of Materials Engineering, Isfahan University of Technology, Isfahan 84156-83111 (Iran, Islamic Republic of); Eskandarian, Masoomeh [Department of Materials Engineering, Shiraz University, Shiraz 71348-51154 (Iran, Islamic Republic of); Zabolian, Azam [Department of Natural Resources, Isfahan University of Technology, Isfahan 84156-83111 (Iran, Islamic Republic of); Szpunar, Jerzy A. [Department of Mechanical Engineering, University of Saskatchewan, Saskatoon SK S7N 5A9 (Canada)

    2015-08-15

    In the present paper, microstructural changes across an as-welded dissimilar austenitic/duplex stainless steel couple welded by a super duplex stainless steel filler metal using gas tungsten arc welding process is characterized with optical microscopy and electron back-scattered diffraction techniques. Accordingly, variations of microstructure, texture, and grain boundary character distribution of base metals, heat affected zones, and weld metal were investigated. The results showed that the weld metal, which was composed of Widmanstätten austenite side-plates and allotriomorphic grain boundary austenite morphologies, had the weakest texture and was dominated by low angle boundaries. The welding process increased the ferrite content but decreased the texture intensity at the heat affected zone of the super duplex stainless steel base metal. In addition, through partial ferritization, it changed the morphology of elongated grains of the rolled microstructure to twinned partially transformed austenite plateaus scattered between ferrite textured colonies. However, the texture of the austenitic stainless steel heat affected zone was strengthened via encouraging recrystallization and formation of annealing twins. At both interfaces, an increase in the special character coincident site lattice boundaries of the primary phase as well as a strong texture with <100> orientation, mainly of Goss component, was observed. - Graphical abstract: Display Omitted - Highlights: • Weld metal showed local orientation at microscale but random texture at macroscale. • Intensification of <100> orientated grains was observed adjacent to the fusion lines. • The austenite texture was weaker than that of the ferrite in all duplex regions. • Welding caused twinned partially transformed austenites to form at SDSS HAZ. • At both interfaces, the ratio of special CSL boundaries of the primary phase increased.

  19. Residual stresses and fatigue in a duplex stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Johansson, Johan

    1999-05-01

    Duplex stainless steels, consisting of approximately equal amounts of austenite and ferrite, often combine the best features of austenitic and ferritic stainless steels. They generally have good mechanical properties, including high strength and ductility, and the corrosion resistance is often better than conventional austenitic grades. This has lead to a growing use of duplex stainless steels as a material in mechanically loaded constructions. However, detailed knowledge regarding its mechanical properties and deformation mechanisms are still lacking. In this thesis special emphasis has been placed on the residual stresses and their influence on mechanical behaviour of duplex stainless steels. Due to the difference in coefficient of thermal expansion between the two phases, tensile microstresses are found in the austenitic phase and balancing compressive microstresses in the ferritic phase. The first part of this thesis is a literature survey, which will give an introduction to duplex stainless steels and review the fatigue properties of duplex stainless steels and the influence of residual stresses in two-phase material. The second part concerns the evolution of the residual stress state during uniaxial loading. Initial residual stresses were found to be almost two times higher in the transverse direction compared to the rolling direction. During loading the absolute value of the microstresses increased in the macroscopic elastic regime but started to decrease with increasing load in the macroscopic plastic regime. A significant increase of the microstresses was also found to occur during unloading. Finite element simulations also show stress variation within one phase and a strong influence of both the elastic and plastic anisotropy of the individual phases on the simulated stress state. In the third part, the load sharing between the phases during cyclic loading is studied. X-ray diffraction stress analysis and transmission electron microscopy show that even if

  20. Residual stresses and fatigue in a duplex stainless steel

    International Nuclear Information System (INIS)

    Duplex stainless steels, consisting of approximately equal amounts of austenite and ferrite, often combine the best features of austenitic and ferritic stainless steels. They generally have good mechanical properties, including high strength and ductility, and the corrosion resistance is often better than conventional austenitic grades. This has lead to a growing use of duplex stainless steels as a material in mechanically loaded constructions. However, detailed knowledge regarding its mechanical properties and deformation mechanisms are still lacking. In this thesis special emphasis has been placed on the residual stresses and their influence on mechanical behaviour of duplex stainless steels. Due to the difference in coefficient of thermal expansion between the two phases, tensile microstresses are found in the austenitic phase and balancing compressive microstresses in the ferritic phase. The first part of this thesis is a literature survey, which will give an introduction to duplex stainless steels and review the fatigue properties of duplex stainless steels and the influence of residual stresses in two-phase material. The second part concerns the evolution of the residual stress state during uniaxial loading. Initial residual stresses were found to be almost two times higher in the transverse direction compared to the rolling direction. During loading the absolute value of the microstresses increased in the macroscopic elastic regime but started to decrease with increasing load in the macroscopic plastic regime. A significant increase of the microstresses was also found to occur during unloading. Finite element simulations also show stress variation within one phase and a strong influence of both the elastic and plastic anisotropy of the individual phases on the simulated stress state. In the third part, the load sharing between the phases during cyclic loading is studied. X-ray diffraction stress analysis and transmission electron microscopy show that even if

  1. Effect of ultrafine grain on tensile behaviour and corrosion resistance of the duplex stainless steel.

    Science.gov (United States)

    Jinlong, Lv; Tongxiang, Liang; Chen, Wang; Limin, Dong

    2016-05-01

    The ultrafine grained 2205 duplex stainless steel was obtained by cold rolling and annealing. The tensile properties were investigated at room temperature. Comparing with coarse grained stainless steel, ultrafine grained sample showed higher strength and plasticity. In addition, grain size changed deformation orientation. The strain induced α'-martensite was observed in coarse grained 2205 duplex stainless steel with large strain. However, the grain refinement inhibited the transformation of α'-martensite;nevertheless, more deformation twins improved the strength and plasticity of ultrafine grained 2205 duplex stainless steel. In addition, the grain refinement improved corrosion resistance of the 2205 duplex stainless steel in sodium chloride solution. PMID:26952459

  2. Effect of ultrafine grain on tensile behaviour and corrosion resistance of the duplex stainless steel.

    Science.gov (United States)

    Jinlong, Lv; Tongxiang, Liang; Chen, Wang; Limin, Dong

    2016-05-01

    The ultrafine grained 2205 duplex stainless steel was obtained by cold rolling and annealing. The tensile properties were investigated at room temperature. Comparing with coarse grained stainless steel, ultrafine grained sample showed higher strength and plasticity. In addition, grain size changed deformation orientation. The strain induced α'-martensite was observed in coarse grained 2205 duplex stainless steel with large strain. However, the grain refinement inhibited the transformation of α'-martensite;nevertheless, more deformation twins improved the strength and plasticity of ultrafine grained 2205 duplex stainless steel. In addition, the grain refinement improved corrosion resistance of the 2205 duplex stainless steel in sodium chloride solution.

  3. Influencia del nitruro de aluminio en el crecimiento anormal de grano de aceros microaleados

    Directory of Open Access Journals (Sweden)

    Cabrera, J. M.

    1995-02-01

    Full Text Available After a brief review about concepts and theories involved in control of grain growth by second phase particles, an experimental study of a medium carbon microalloyed steel with two levels of AIN is carried out. A system to study the grain size distributions in order to detect the abnormal grain growth is proposed. Results permit to plot a map of abnormal grain growth-time-temperature. The abnormal grain growth is derived to be due to the AIN dissolution by correlating the above maps with the theoretical volume fraction of precipitates. The importance and effect of the heating rate is also shown: high heating rates can produce a transient oversaturation that can lead to abnormal growing during the dissolution.

    Tras una breve revisión de los conceptos y teorías involucradas en el control del crecimiento de grano por partículas de segunda fase, se efectúa un estudio del mismo en un acero microaleado con contenido medio de carbono con dos niveles de nitruro de aluminio. Se propone un sistema de estudio de las distribuciones de tamaño de grano tendente a poder detectar la presencia de crecimiento anormal de grano. De este modo, se construyen mapas de crecimiento anormal-tiempo-temperatura que, correlacionados con las teóricas fracciones de volumen de los precipitados presentes, permiten comprobar que la disolución del nitruro de aluminio es la responsable fundamental de la aparición del crecimiento anormal de grano. También se muestra el efecto e importancia de la velocidad de calentamiento, ya que altas velocidades pueden producir una sobresaturación transitoria de precipitados que, al disolverse, pueden dar lugar a crecimiento de grano anormal.

  4. Recubrimientos de (ti,aln sobre acero aisi 4140 por sputtering reactivo

    Directory of Open Access Journals (Sweden)

    DANNA GARCIA

    2007-01-01

    Full Text Available Empleando la técnica de Pulverización catódica con radiofrecuencia y magnetrón (Magnetron Sputtering RF, se prepararon películas de (Ti,AlN sobre sustratos de acero AISI 4140. Se utilizó un blanco formado con polvos metálicos de Ti y Al, con composición nominal 60% Ti y 40% Al (porcentaje en átomos y una razón de presiones parciales de nitrógeno - argón, PN2/PAr de 0,1 aproximadamente; la temperatura del sustrato se varió entre 260 y 330 ºC y el tiempo de deposición entre 2 y 4,5 horas para obtener películas con diferentes espesores. La composición química de las películas se determinó mediante la técnica de energía dispersada de rayos X (EDX, y su topografía mediante microscopía de fuerza atómica (AFM. Igualmente se midió micro dureza, y se determinó su comportamiento electroquímico mediante espectroscopia de impedancia electroquímica EIS y ensayos TAFEL. Las películas obtenidas presentaron granos globulares, uniformes y de pequeño diámetro, con características electroquímicas de protección al sustrato frente a procesos de corrosión.

  5. Microbiological corrosion in low carbon steels; Corrosion microbiologica en aceros de bajo carbono

    Energy Technology Data Exchange (ETDEWEB)

    Medina-Custodio, O; Ortiz-Prado, A; Jacobo-Armendariz, V. H; Schouwenaars-Franssens, R [Universidad Nacional Autonoma de Mexico, Mexico, D.F. (Mexico)]. E-mail: medina_1979@yahoo.com; armandoo@servidor.unam.mx; vjacobo@dgapa.unam.mx; raf_schouweenaars@yahoo.com

    2009-01-15

    The Microbiologically Induced Corrosion affects several industries, such as oil industry where it is estimated that 20% to 30% pipes failures are related with microorganism. The chemical reactions generate ions transfer, this validate the use of electrochemical technique for its analysis. Coupons submerged in a nutritional medium with presence and absence of three different microorganisms during two periods, 48 hours and 28 days were studied. Polarization resistance (Rp) and Electrochemical Impedance Spectroscopy (EIS) techniques were applied to determine the corrosively of the systems. The results show a greater corrosive effect of abiotic systems, this indicates a microorganisms protection effect to the metal, opposite to the first hypothesis. This result was ratified observing surface coupons by using Scanning Electron Microscopy (SEM) technique. A possible mechanism based on Evans - Tafel graph is proposed to explain inhibitor microorganism effect. [Spanish] La corrosion microbiologica es un tipo comun de deterioro que afecta diversas industrias, una de ellas es la petrolera en la que se estiman que el 20% o 30% de fallas en las tuberias de trasporte de hidrocarburos es favorecida por microorganismos. Las reacciones quimicas que sustentan estos, generan transferencia de iones, lo que justifica el empleo de tecnicas electroquimicas para su analisis. En este trabajo, se estudiaron probetas de acero de bajo carbono SAE 1018, sumergidas en un medio nutritivo rico en cloruros en presencia y ausencia de tres diferentes cargas microbianas, en tiempos de exposicion de 48 horas y 28 dias. Se realizaron ensayos de resistencia a la polarizacion (Rp) y espectroscopia de impedancia electroquimica (EIS) para determinar el efecto corrosivo de los diferentes sistemas. Los resultados muestran que el medio abiotico causa el mayor efecto corrosivo, lo que indica un efecto protector de los microorganismos al metal contradiciendo la hipotesis inicialmente propuesta. La observacion

  6. Precisiones sobre la corrosión del acero en contacto con hormigón

    Directory of Open Access Journals (Sweden)

    Andrade, C.

    1982-09-01

    Full Text Available In this paper, we emphasize that now it is possible to use some electrochemical non-destructive techniques for measuring the corrosion rate of the metals. Also, it is possible to use the gravimetric determinations if the appropriate instrumentation is not available. The simple visual observation is a good complementary technique but it must not be used alone because of its subjectivity. Also, we stress some aspects, such as the influence of the alkalinity and the humidity, about the corrosion, that the bare and galvanized steel, can suffer in contact with construction materials. We analyze mainly, the influence of the type of cement on the risk of corrosion of both kinds of metals.

    En los presentes comentarios se insiste en que, para evaluar la velocidad de corrosión de los metales, en la actualidad se pueden utilizar técnicas electroquímicas no destructivas que permiten seguir la evolución del proceso diariamente, o bien, en el caso de no contar con los aparatos apropiados, se puede acudir a una determinación gravimétrica de la pérdida de metal. La simple observación visual es una valiosa indicación complementaria de las técnicas antes mencionadas, pero no debe utilizarse como técnica de medida única por la subjetividad que conlleva. También se precisan algunos aspectos sobre la corrosión que el acero desnudo y el galvanizado pueden sufrir por estar en contacto con materiales de construcción, como son la influencia de la alcalinidad y de la humedad del medio y, fundamentalmente, se analiza la influencia que puede ejercer el tipo de cemento en el riesgo de corrosión de ambas clases de metales.

  7. Influencia de la microestructura en la fractura de aceros microaleados de forja

    Directory of Open Access Journals (Sweden)

    Romero, J. L.

    1996-06-01

    Full Text Available The influence of thermomechanical treatments, first carried out at laboratory and afterwards on an industrial scale on the mechanical properties of microalloyed forging steels is analysed. The influence of hot working conditions and the cooling rate after hot working on both the strength and the toughness is analysed. Optimization of the thermomechanical treatments parameters has been carried out at laboratory and the optimized schedules have been carried out industrially. The actual experimental results of mechanical properties have been rationalized in terms of the microstructure developed during the different thermomechanical treatments. After slow cooling of steel bars hot rolled at low temperature (below 850 °C, the ferrite-pearlite is much refined and the toughness improved. Alternatively, accelerated cooling after hot working at high temperature produces a microstructure of acicular ferrite with improved toughness.

    Se analiza la influencia de los tratamientos termomecánicos, en primer lugar, llevados a cabo en laboratorio y, posteriormente, en un proceso industrial, sobre las propiedades mecánicas de aceros microaleados de forja. Se han variado las temperaturas de forja y las velocidades de enfriamiento tras la misma y se ha estudiado su influencia sobre la resistencia y la tenacidad. La optimización de los tratamientos termomecánicos se ha realizado a nivel de laboratorio, probándose posteriormente las secuencias optimizadas a escala industrial. Las propiedades mecánicas se pueden explicar en términos de las microestructuras obtenidas en los diversos tratamientos termomecánicos. Así, microestructuras gruesas, obtenidas por enfriamientos lentos tras la deformación a elevadas temperaturas, muestran un comportamiento frágil. Se pueden obtener buenos valores de tenacidad, manteniendo la resistencia por afino de la microestructura, bien deformando el material a menores temperaturas de forja (ferrita+perlita finas o

  8. GEL DE ALOE-VERA COMO POTENCIAL INHIBIDOR DE LA CORROSIÓN DEL ACERO DE REFUERZO ESTRUCTURAL

    Directory of Open Access Journals (Sweden)

    Héctor Herrera-Hernández

    2015-01-01

    Full Text Available En el presente trabajo se estudiaelectroquímicamente un GELextracto de las hojas de ALOE VERAcomo un posible inhibidor de la corrosión del acero de refuerzo estructuraldel concreto.Los estudiosde corrosiónse llevaron a cabo en 1M de HCl y utilizando la técnica de espectroscopia de impedancia electroquímica (EISse evaluó la resistencia a la corrosión en presencia y ausencia del GEL.Los diagramas de impedancia mostraronque la adición en diferentes proporcionesdel GELinhibe notablemente el proceso de la corrosión del acero inmerso en la solución ácida. También se determinó que las moléculas del GEL obedecena un mecanismo de fisisorciónsobre la superficie del metal de acuerdo con el modelo de isoterma de Langmuircon unG°adsde alrededor de 14.17 kJ/mol. El GEL se clasificócomo un inhibidor orgánico del tipo mixto.

  9. Caracterización de los aceros sinterizados obtenidos a partir de polvos prealeados Fe-1,5% Mo

    Directory of Open Access Journals (Sweden)

    Torralba, J. M.

    1995-02-01

    Full Text Available Sintered molybdenum-, copper-, nickel- alloyed steels, have been studied through the influence of the Chemical composition on different mechanical and physical properties. In all the studied steels, a constant percentage of carbon has been used, as well Fe-Mo prealloyed powders, with a 1,5% Mo content. Selected sintering conditions were close to those used in the P/M industry, potential consumer of the studied steels.

    Se estudian los aceros aleados sinterizados con molibdeno, cobre, níquel y grafito, a partir de la influencia de su composición sobre distintas propiedades mecánicas y físicas. En todos los aceros, se utilizó una composición de carbono constante, así como polvos prealeados de Fe-Mo, con 1,5% Mo. Las condiciones de sinterización elegidas han sido las más próximas a las utilizadas en la industria pulvimetalúrgica, que es el usuario potencial de los materiales estudiados.

  10. Procesos de conversión de acero y efecto de variables en convertidores tipo L.B.E.

    Directory of Open Access Journals (Sweden)

    Blanco, C.

    1995-10-01

    Full Text Available In order to determine control equations based on qualitative and quantitative changes of the raw materials, an analysis of the efficiency of the steel production process was carried out in converters under specified operation conditions. Empirical equations to obtain the final composition of the steel as a function of the additives, the initial concentrations of the hot metal and the blowing oxygen patterns are established. The resulting relationships depend on the considered variables and therefore could be used to determine operational strategies in order to obtain steels of a certain quality.

    Se analiza la eficacia de los procesos de transformación en convertidores en condiciones de trabajo determinadas, para deducir relaciones aplicables al control basadas en la modificación de cantidades y composiciones de las materias primas. Se plantean ecuaciones empíricas para determinar la composición final del acero como función de los aditivos y de las concentraciones iniciales del arrabio tratado, así como el patrón de soplado de oxígeno. Las relaciones obtenidas establecen las dependencias entre cada una de las variables consideradas y, por tanto, permiten determinar estrategias de operación para obtener aceros con unas calidades finales dadas.

  11. Tensile properties of duplex UNS S32205 and lean duplex UNS S32304 steels and the influence of short duration 475 ºC aging

    OpenAIRE

    Sérgio Souto Maior Tavares; Juan Manuel Pardal; Hamilton Ferreira Gomes de Abreu; Cristiana dos Santos Nunes; Manoel Ribeiro da Silva

    2012-01-01

    Duplex stainless steels are high strength and corrosion resistant steels extensively used in the petrochemical and chemical industries. The aging at 475 ºC for long periods of time provokes embrittlement and deterioration of corrosion resistance. However, short duration aging at 475 ºC may be used as heat treatment to improve mechanical resistance with small decrease in the other properties. In this work the flow stress curves of lean duplex UNS S32304 and duplex UNS S32205 steels were modele...

  12. "Estudio tribologico de aceros para moldes. Aplicacion al moldeo por inyeccion de polibutilentereftalato reforzado con fibra de vidrio"

    Science.gov (United States)

    Martinez Mateo, Isidoro Jose

    fabricacion del molde, tienen una gran influencia sobre su comportamiento en servicio a lo largo de la vida util del molde. En la primera parte del presente estudio, a partir de ensayos punzon sobre disco, se ha determinado la relacion entre la resistencia al desgaste y la dureza de aceros para moldes obtenidos a partir de bloques de gran espesor, estudiando los principales mecanismos de desgaste que tienen lugar. A continuacion, con el fin de determinar el dano superficial que sufren los aceros para moldes en condiciones reales de inyeccion, se han estudiado distintos tipos de aceros utilizados comercialmente en moldes de inyeccion de polimeros y materiales compuestos, seleccionando las condiciones de operacion para determinar la variacion de la rugosidad superficial del acero en funcion del material inyectado, del numero de operaciones sucesivas de inyeccion y de la orientacion del flujo de inyeccion, mediante tecnicas de perfilometria optica y microscopia electronica de barrido. Ademas del dano superficial sufrido por el acero con el numero de piezas inyectadas, tambien se ha determinado la evolucion de la rugosidad superficial de los materiales inyectados, polibutilentereftalato (PBT) puro y materiales compuestos derivados de PBT por adicion de un 20 o un 50% en peso de fibra de vidrio. En el caso de las piezas inyectadas, se ha caracterizado su microestructura en funcion del flujo de inyeccion y de la densidad de fibra, se han determinado sus propiedades termicas y dinamico-mecanicas, asi como la variacion de la rugosidad superficial de las piezas inyectadas con el numero de operaciones de inyeccion y con la geometria de las distintas secciones de las piezas. Finalmente, se ha evaluado la resistencia a la abrasion de PBT reforzado con un 50% de fibra, en funcion del numero de piezas inyectadas y de la direccion de rayado con respecto a la orientacion del flujo de inyeccion.

  13. Force-Induced Rupture of a DNA Duplex: From Fundamentals to Force Sensors.

    Science.gov (United States)

    Mosayebi, Majid; Louis, Ard A; Doye, Jonathan P K; Ouldridge, Thomas E

    2015-12-22

    The rupture of double-stranded DNA under stress is a key process in biophysics and nanotechnology. In this article, we consider the shear-induced rupture of short DNA duplexes, a system that has been given new importance by recently designed force sensors and nanotechnological devices. We argue that rupture must be understood as an activated process, where the duplex state is metastable and the strands will separate in a finite time that depends on the duplex length and the force applied. Thus, the critical shearing force required to rupture a duplex depends strongly on the time scale of observation. We use simple models of DNA to show that this approach naturally captures the observed dependence of the force required to rupture a duplex within a given time on duplex length. In particular, this critical force is zero for the shortest duplexes, before rising sharply and then plateauing in the long length limit. The prevailing approach, based on identifying when the presence of each additional base pair within the duplex is thermodynamically unfavorable rather than allowing for metastability, does not predict a time-scale-dependent critical force and does not naturally incorporate a critical force of zero for the shortest duplexes. We demonstrate that our findings have important consequences for the behavior of a new force-sensing nanodevice, which operates in a mixed mode that interpolates between shearing and unzipping. At a fixed time scale and duplex length, the critical force exhibits a sigmoidal dependence on the fraction of the duplex that is subject to shearing.

  14. Hemimethylated duplex DNAs prepared from 5-azacytidine-treated cells.

    OpenAIRE

    Jones, P A; Taylor, S M

    1981-01-01

    Duplex heavy-light (HL) DNAs synthesized in the presence of brdUrd and methylation inhibitors were separated from bulk cellular DNA by CsCl density gradient centrifugation and analysed for 5-methylcytosine (5mC) contents by HPLC. DNAs synthesized in the presence of 5 mM ethionine or 2 mg/ml cycloleucine were not detectably hypomethylated, was undermethylated with respect to control DNA. The heavy, or H-strand, in which up to 5% of the cytosine residues were replaced by intact 5-azacytosine, w...

  15. Corrosion resistance properties of sintered duplex stainless steel

    Directory of Open Access Journals (Sweden)

    L.A. Dobrzański

    2006-09-01

    Full Text Available Purpose: of this paper was to examine the corrosion resistance of duplex stainless steels using electrochemical methods in 1M NaCl solution. The influence of powder mixes preparation and cooling cycle after sintering on corrosion properties was evaluated.Design/methodology/approach: In presented study duplex stainless steels were obtained through powder metallurgy starting from austenitic, martensitic base powders by controlled addition of alloying elements, such as Cr, Ni, Mo and Cu. In the studies behind the preparation of mixes, Schaeffler’s diagram was taken into consideration. Prepared mixes have been compacted at 800 MPa and sintered in a vacuum furnace with argon backfilling at 1260°C for 1 h. After sintering two different cooling cycles were applied: rapid cooling with an average cooling rate of 245 °C/min and slow cooling of 5 °C/min in argon atmosphere. Produced duplex stainless steels have been studied by scanning and optical microscopy and EDS chemical analysis of microstructure components. Corrosion properties have been studied through electrochemical methods in 1M NaCl water solutionFindings: According to achieved results, it was affirmed that applied sintering method as well as powder mixes preparation allows for manufacturing the sintered duplex steels with good corrosion properties which depends on austenite/ferrite ratio in the microstructure and elements partitioning between phases. Corrosion resistance of sintered stainless steels is strictly connected with the density and the pore morphology present in the microstructure too. The highest resistance to pitting corrosion in 1M NaCl solution was achieved for composition with approximate balance of ferrite and austenite in the microstructure.Research limitations/implications: According to the powders characteristic, the applied fast cooling rate seems to be a good compromise for corrosion properties and microstructures, nevertheless further tests should be carried out in

  16. Reliability Capacity of Half-Duplex Channels with Strict Deadlines

    DEFF Research Database (Denmark)

    Costa, Rui; Roetter, Daniel Enrique Lucani; Vinhoza, Tiago;

    2015-01-01

    A fundamental characterization of a half-duplex wireless system with packet losses under traffic with hard deadlines is instrumental to understanding and developing efficient, coding aware policies for real-time applications. We set forth the concept of reliability capacity with a limited number...... and in terms of its advantages towards the mean number of packets that can be transmitted reliably. Optimal schemes for leveraging feedback are presented and the results show that a judicious use of even a single feedback packet can have a significant impact on the mean performance....

  17. Microstructures of duplex (beta + gamma) silver-tin alloys.

    Science.gov (United States)

    Abbott, J R; Miller, D R; Netherway, D J

    1985-05-01

    The microstructures of (beta + gamma) silver-tin alloys are especially influenced by both homogenization temperature and subsequent heat treatment. When the alloy is cooled from homogenization temperatures above approximately 200 degrees C, lenticular regions of the ordered orthorhombic gamma phase precipitate from within the disordered h.c.p. beta phase on three structurally equivalent planes, (1210), (1120), and (2110), to form a Widmanstatten structure. When the duplex alloys were homogenized at temperatures below approximately 200 degrees C, where the beta/(beta + gamma) phase boundary is vertical, these structures were not observed. PMID:3858310

  18. Technology of Welding Joints Mixed with Duplex Steel

    OpenAIRE

    Słania J.; Krawczyk R.; Masłoń D.

    2016-01-01

    Results of the examinations of sample plates of mixed joints with the duplex steel were discussed. Examinations were taken on the sample plates of mixed joints of sheet plates type P355NL1 and X2CrNiMoN22-5-3 welded by the flux-cored wire DW-329A by the Kobelco company of the following category T 22 9 3 NL RC/M3 in the gas shroud M21 (Ar+18%CO2) (plate no.1), and nickel covered electrodes E Ni 6082 by the Böhler company (plate no. 2). Results of the side bend test of welded joint, transverse ...

  19. Deformation in thrust-ramp anticlines and duplexes: implications for geometry and porosity

    Energy Technology Data Exchange (ETDEWEB)

    Groshong, R.H. Jr.; Usdansky, S.I.

    1986-05-01

    A computerized kinematic model of thrust-ramp anticline geometry allows workers to predict the zones of greatest deformation in ramp anticlines and fault duplexes. The model assumes a constant cross-section area, symmetrical fold hinges, and slip in the hanging wall parallel to the ramp and forelimb. Assuming that the collapse of original porosity or the generation of secondary fracture porosity is proportional to deformation, the model can be used to predict porosity changes. Deformation in a single ramp anticline is greatest in the forelimb and backlimb, and may be absent in the crest. A duplex structure results from comparatively closely spaced thrusts that have a common upper detachment horizon. Relatively wide spacing between the duplex faults yields a bumpy roofed duplex as in the central Appalachians. Forelimbs may be deformed twice and should show greater porosity modification. Relatively close spacing between ramp-and-flat thrusts can produce a listric-fault, snakehead anticline geometry because younger faults deform the preexisting thrust slices. The resulting geometry is here called a snakehead duplex and appears to be fairly common, as in the Jumpingpound field in the Canadian Rockies. Each thrust slice within the duplex is deformed six times or more, providing the maximum opportunity for deformation-related porosity changes. Maximum fracture porosity should occur in thrusts having listric-fan or snakehead duplex geometry. Structures involving duplexes generally should be better than isolated ramp anticlines.

  20. Contrast Free Duplex-Assisted EVAR in Patients with Chronic Renal Insufficiency

    OpenAIRE

    Krasznai, Attila G; Sigterman, Tim A.; Bouwman, Lee H.

    2014-01-01

    Renal insufficiency and allergy for iodinated contrast are the main contra-indications for Endovascular Aortic Repair (EVAR). Various techniques have been used to minimize utilization of contrast in order to prevent contrast induced nephropathy. EVAR can be performed without nephrotoxic contrast, using additional duplex-guidance. This report describes three cases of duplex-assisted EVAR in patients with chronic renal insufficiency.

  1. Importance of diastolic velocities in the detection of celiac and mesenteric artery disease by duplex ultrasound

    DEFF Research Database (Denmark)

    Perko, M J; Just, S; Schroeder, T V

    1997-01-01

    To assess the predictive value of ultrasound duplex scanning in the detection of superior mesenteric artery (SMA) and celiac artery (CA) occlusive disease.......To assess the predictive value of ultrasound duplex scanning in the detection of superior mesenteric artery (SMA) and celiac artery (CA) occlusive disease....

  2. Duplex ultrasound scanning of peripheral arterial disease of the lower limb

    DEFF Research Database (Denmark)

    Eiberg, Jonas Peter; Rasmussen, John Bøje Grønvall; Hansen, Marc Allan;

    2010-01-01

    To assess the reliability and applicability of duplex ultrasound scanning (DUS) of lower limb arteries, compared with digital subtraction angiography (DSA), in patients with peripheral arterial disease (PAD).......To assess the reliability and applicability of duplex ultrasound scanning (DUS) of lower limb arteries, compared with digital subtraction angiography (DSA), in patients with peripheral arterial disease (PAD)....

  3. Optimization of welding variables for duplex stainless steel by GTAW and SMAW

    International Nuclear Information System (INIS)

    The main problems faced during the welding of duplex stainless steels are cleanliness and slag inclusions. In the present work the methods to eliminate these problems were studied during the welding of duplex stainless steel by Gas Tungsten Arc Welding (GTAW) and Shielded Metal Arc Welding (SMAW). Since the duplex stainless steel is an expensive material, the initial experiments for optimization of welding variables were. carried out on low carbon steel (CS) plates with duplex consumables. Welding of butt groove joints on CS plates was carried with various sets of welding variables i.e. current, voltage and arc energy using duplex consumables. The. radiographic inspection, micro-structural observations and hardness testing of the welds suggested the welding variables that will produce a sound weld on CS plate. These optimized variables were then used for the welding of edge groove joint and T -joint on duplex stainless steel by GTAW and SMAW processes. The hardness and micro-structural study of the joints produced on duplex stainless steel by GTAW and SMAW with duplex consumables were also studied. No slag inclusions and porosity were observed in the microstructure of these weldments and their properties were found similar to the parent metal. (author)

  4. Throughput Analysis of Full Duplex Communication with Asymmetric Traffic in Small Cell Systems

    DEFF Research Database (Denmark)

    Mahmood, Nurul Huda; Berardinelli, Gilberto; Mogensen, Preben Elgaard;

    2015-01-01

    in this contribution using network analysis tools from stochastic geometry. The analytical findings are further confirmed through computer-based Monte-Carlo simulations. Asymmetric downlink/uplink traffic pattern and the increased network interference stemming from full duplex transmissions are found to limit its......Full duplex communication promises a 100% throughput gain by enabling simultaneous transmission and reception. However, such simultaneous communication leads to a corresponding increase in the network interference. In addition, full duplex communication can only be exploited when traffic...... is available in both uplink and downlink directions; while, cellular network traffic tend to be downlink heavy in practice. The potential throughput gains of full duplex communication over conventional half duplex transmission in a small cell network with asymmetric traffic conditions are investigated...

  5. Evaluation of Microstructure and Mechanical Properties in Dissimilar Austenitic/Super Duplex Stainless Steel Joint

    Science.gov (United States)

    Rahmani, Mehdi; Eghlimi, Abbas; Shamanian, Morteza

    2014-10-01

    To study the effect of chemical composition on microstructural features and mechanical properties of dissimilar joints between super duplex and austenitic stainless steels, welding was attempted by gas tungsten arc welding process with a super duplex (ER2594) and an austenitic (ER309LMo) stainless steel filler metal. While the austenitic weld metal had vermicular delta ferrite within austenitic matrix, super duplex stainless steel was mainly comprised of allotriomorphic grain boundary and Widmanstätten side plate austenite morphologies in the ferrite matrix. Also the heat-affected zone of austenitic base metal comprised of large austenite grains with little amounts of ferrite, whereas a coarse-grained ferritic region was observed in the heat-affected zone of super duplex base metal. Although both welded joints showed acceptable mechanical properties, the hardness and impact strength of the weld metal produced using super duplex filler metal were found to be better than that obtained by austenitic filler metal.

  6. Physical-Layer Security of a Buffer-Aided Full-Duplex Relaying System

    KAUST Repository

    El Shafie, Ahmed

    2016-07-07

    This letter proposes a novel hybrid half-/full-duplex relaying scheme to enhance the relay channel security. A source node (Alice) communicates with her destination node (Bob) in the presence of a buffer-aided full-duplex relay node (Rooney) and a potential eavesdropper (Eve). Rooney adopts two different relaying, namely randomize-and-forward and decode-andforward relaying strategies, to improve the security of the legitimate system. In the first relaying strategy, Rooney uses a codebook different from that used at Alice. In the second relaying strategy, Rooney and Alice use the same codebooks. In addition, Rooney switches between half-duplex and full-duplex modes to further enhance the security of the legitimate system. The numerical results demonstrate that our proposed scheme achieves a significant average secrecy end-to-end throughput improvement relative to the conventional bufferless full-duplex relaying scheme.

  7. Sequence-selective targeting of duplex DNA by peptide nucleic acids

    DEFF Research Database (Denmark)

    Nielsen, Peter E

    2010-01-01

    Sequence-selective gene targeting constitutes an attractive drug-discovery approach for genetic therapy, with the aim of reducing or enhancing the activity of specific genes at the transcriptional level, or as part of a methodology for targeted gene repair. The pseudopeptide DNA mimic peptide...... nucleic acid (PNA) can recognize duplex DNA with high sequence specificity and affinity in triplex, duplex and double-duplex invasive modes or non-invasive triplex modes. Novel PNA modification has improved the affinity for DNA recognition via duplex invasion, double-duplex invasion and triplex...... recognition considerably. Such modifications have also resulted in new approaches to targeted gene repair and sequence-selective double-strand cleavage of genomic DNA....

  8. Inyección de mineral de manganeso en acero líquido

    Directory of Open Access Journals (Sweden)

    Vargas-Ramírez, M.

    2003-04-01

    Full Text Available A theoretical and experimental analysis is carried out to estimate the rate of MnO reduction when manganese ore is injected into liquid steel with three carbon contents, 0.5, 1.0 and 2.0 mass % at 1600 °C. It is assumed that there are two reaction zones along the flux injection operation: a transitory reaction between the rising particles and the bulk metal, and the permanent reaction between the metal and the top slag. The experiments were carried out in an open 10 kg induction furnace using A1203 refractory. The results show that the transitory reaction plays a more important role in the powder injection process than the permanent reaction. The reduction of MnO with silicon is more important when the basicity of the slag is high; this is because the aSi02 decreases as the slag basicity is increased. However, when the slag basicity is low and the initial carbon content in steel is high the reduction of MnO with silicon becomes less efficient, although silicon still remains better reducing agent than carbon.

    En este trabajo se realiza un estudio, teórico y experimental, para determinar la velocidad de reducción de MnO inyectado dentro de acero líquido con contenidos de carbono de 0,5, 1,0 y 2,0 % masa, a 1.600 °C. El modelo considera que se establecen dos zonas de reacción: la transitoria, que se produce entre las partículas inyectadas y el metal líquido, y la permanente, que tiene lugar en la interfase entre el metal y la escoria. Los experimentos se llevaron a cabo en un horno de inducción de 10 kg de capacidad con refractario de alta alúmina. Los resultados muestran que la reacción transitoria produce una mayor reducción de MnO que la reacción permanente. La reducción de MnO con silicio es más importante cuando la basicidad de la escoria es elevada debido a que se disminuye la aSi02. Para una basicidad baja y un alto contenido de carbono en el baño, la eficiencia de la reducción de MnO con silicio disminuye, aunque el

  9. Influencia de diferentes tratamientos termoquímicos en aceros sinterizados base molibdeno

    Directory of Open Access Journals (Sweden)

    Candela, N.

    2001-04-01

    Full Text Available Prealloyed steel powders with different amount of Mo-Cu-Ni-C were compacted at 700 MPa and sintered at 1120 °C in 95 % N2-5 % H2. After sinterizing, these materials were treated by carburizing. For materials characterization radial crushing strength were preformed, density was calculated and a complete study of fracture surfaces was carried out using scanning electron microscopy. The results of radial crushing strength show that resistance after carburizing is higher than in sintered materials. The fracture surfaces give an idea of materials briteless and the treatment depth. In sintered materials, a dúctil surface was observed, with the characteristic dimples. The fracture surfaces after different treatments show britelessnes in the outer zone, while inside appears a mix of dúctil and briteles fracture.

    Polvos prealeados de aceros con diferentes contenidos de Mo-Cu-Ni -C se compactaron a 700 MPa y se sinterizaron a 1.120 °C en atmósfera de 95 % N2-5 % H2. Después de la sinterización, los materiales se trataron termoquímicamente para su cementación (proceso endogas. Para la caracterización de todos los materiales se realizaron ensayos de compresión del tipo radial crushing strength, se calculó la densidad y se hizo un completo estudio de las superficies de fracturas a través de microscopía electrónica de barrido. Los resultados de resistencia a compresión muestran, después de la cementación, valores superiores a los encontrados en el estado sintetizado. La superficie de fractura da idea de la fragilidad del material y de la profundidad del tratamiento. En estado sintetizado, se observa una superficie de fractura totalmente dúctil, donde aparecen las características cavidades. Las superficies de fractura, tras distintos tipos de cementación, reflejan un comportamiento frágil en el exterior, mientras que el interior aparece una mezcla de fractura dúctil con frágil.

  10. Modelización del proceso de austenización de un acero eutectoide

    Directory of Open Access Journals (Sweden)

    Caballero, F. G.

    2001-10-01

    Full Text Available A model describing the pearlite-to-austenite transformation during continuous heating in an eutectoid steel has been developed. In that model, Avrami equation has been successfully applied to calculate the austenite volume fraction formed under non-isothermal conditions. The influence of parameters such as interlamellar spacing and edge length of pearlite colonies and heating rate on the austenite formation kinetics has been experimentally studied and considered in the modelling. It has been found that the kinetics of austenite formation is slower the coarser the initial pearlite microstructure and the higher the heating rate. Moreover, both start and finish temperatures of the transformation slightly increase as heating rate does, but finish temperatures are more sensitive to that parameter. A good agreement (accuracy higher than 90% in square correlation factor between experimental and predicted values has been found.

    En este trabajo se ha desarrollado un modelo matemático para el cálculo de la cinética de formación de austenita a partir de perlita en un acero eutectoide en condiciones de calentamiento continuo. En dicho modelo, se ha aplicado, con éxito, la ecuación de Avrami para calcular la fracción de volumen de la austenita formada en condiciones no isotérmicas. La influencia de parámetros tales como el espaciado interlaminar, la longitud de borde de colonia de perlita y la velocidad de calentamiento sobre la cinética de formación de austenita, ha sido estudiada experimentalmente y considerada en la modelización. Se ha comprobado que la cinética de formación de austenita es más lenta cuanto más grosera es la perlita inicial y más alta es la velocidad de calentamiento. Asimismo, las temperaturas de inicio y final de la transformación aumentan ligeramente con la velocidad de calentamiento, aunque las temperaturas finales son más sensibles a este parámetro. Los resultados experimentales para la fracción de volumen

  11. Endurecimiento superficial de aceros y fundiciones mediante láser de Nd: YAG

    Directory of Open Access Journals (Sweden)

    Sagaró, R.

    2001-10-01

    Full Text Available This work relates with heat treatment by laser of metallic surfaces. The hardening of steels AISI 1045, W1, W112 and flake and nodular cast irons was carried out using a Nd: YAG laser. Operation parameters of laser like beam power (P and traverse speed of the laser Spot (V are closely related to the depth of hardening. The authors present some analyses on metallographic studies. In all cases Vickers microhardness valves of about 500-900 HV (three or four times higher than original substrates. Relations between microhardness and depth of hardening are presented for the processed materials. Experimental results showed that the scan speed increase produces a decrease on depth of hardening as reported by others researchers. On the other hand, the samples with higher carbon content show lower hardenining depth. In addition, tribological tests were carried out. These tests show wear resistance when compared with conventional heat treatment. The frictional coefficient decrease in the samples with laser surface treatment.

    En el trabajo se presentan los resultados del tratamiento térmico superficial, con técnica láser, de superficies metálicas. Con el empleo de un láser de Nd:YAG se procedió al endurecimiento superficial de los aceros AISI 1045, W1, W112 y fundiciones de tipo laminar y nodular. Se presentan los resultados del tratamiento térmico superficial atendiendo al parámetro velocidad de barrido del haz de láser (V. De igual forma se estudian las microestructuras metalográficas obtenidas. En todos los casos, se obtienen valores de microdureza Vickers que oscilan entre los 500-900 HV (incrementos de tres-cuatro veces respecto al material base. Los resultados obtenidos permiten afirmar que, en todos los casos estudiados, el incremento de la velocidad de barrido provocó una disminución de la profundidad de la capa endurecida, en correspondencia con otros resultados expuestos en la literatura especializada. Las experiencias del

  12. Evaluación del coeficiente de endurecimiento del acero AISI 1045 deformado por rodillo

    Directory of Open Access Journals (Sweden)

    D. Alcántara

    2011-12-01

    Full Text Available El objetivo del trabajo es determinar el comportamiento del coeficiente de endurecimiento n por la ecuación de Hollomon en muestras cilíndricas de acero AISI 1045, las cuales, después de ser deformadas, se sometieron a ensayos de tracción. Se utiliza un diseño de experimento donde se tienen en cuenta las variables número de revolución (n con 27, 54 y 110 rev/min, fuerza de compresión (P de 500, 1 500 y   2 500 N y avance (S de 0,075; 0,125 y 0,25 mm/rev. Finalmente, aplicando el método de regresión se obtuvo un coeficiente de endurecimiento, el cual se aproxima a la linealidad cuando restringimos el cálculo a rangos de deformación elevados. Este coeficiente de endurecimiento se aplica en la ecuación de Hollomon para determinar el nuevo valor de tensión de fluencia y aplicarlo para el cálculo del trabajo mínimo a realizar en un proceso de deformación en frío empleando rodillo simple.   Palabras clave: Deformación Plástica; tensión; deformación; endurecimiento.The objective of the work is to determine the behavior of the hardening coefficient n by the equation of Hollomon, in cylindrical samples of steel AISI 1045, those which, after the deformed, were subjected to traction rehearsals. He used an experiment design where are kept in mind the revolution number (n with 27, 54 and 110 rev/min, it compression forces (P of 500, 1 500 and 2 500 N and feed (S of 0.075; 0.125 and 0.25 mm/rev. Finally, applying the regression method a hardening coefficient was obtained, which approaches to the linearity when restrict the calculation to high ranges of deformation. This hardening coefficient is applied in the equation of Hollomon for determine the new value of flow tension and to apply in the calculation of the minimum work to carry out in a cold process of deformation using simple roller.   Keywords: Plastic deformation; stress; deformation; hardening.

  13. Caracterización microestructural, micromecánica y tribológica de aceros dual phase de alta resistencia sometidos a procesos de perfilado en frío (Microstructural, micromechanical and trobological characterización of high strength dual phase steels subjected to cold roll forming processes)

    OpenAIRE

    Ruiz Andrés, Meritxell

    2012-01-01

    El sector de la automoción ha impulsado numerosos desarrollos en el campo de los materiales, específicamente aceros, para disminuir el peso en sus estructuras y, por tanto, el consumo de combustible y las emisiones de CO2 a la atmósfera. Uno de estos nuevos aceros que ha despertado mayor interés es el acero dual-phase, perteneciente a la familia de aceros avanzados de alta resistencia (AHSS, Advanced High Strength Steels), debido a su composición de ferrita y martensita la cual otorga a este ...

  14. Fabrication of Duplex Coated U-Mo-Ti Atomized Powder

    Energy Technology Data Exchange (ETDEWEB)

    Nam, Ji Min; Kim, Woo Jeong; Lee, Kyu Hong [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of); Ryu, Ho Jin [Korea Advanced Institue of Science and Technology, Daejeon (Korea, Republic of)

    2013-10-15

    The results of an annealing test showed that the coating layers inhibit the formation of interaction layers. The results of duplex coating showed that nitride coating layers inhibit the formation of other coating layers. High-density U-Mo alloys are regarded as promising candidates for advanced research reactor fuel as they have shown stable irradiation performance when compared to other uranium alloys and compounds. However, interaction layer formation between the U-Mo alloys and Al matrix degrades the irradiation performance of U-Mo dispersion fuel. Therefore, the addition of Ti in U-Mo alloys, the addition of Si in a Al matrix, and silicide or nitride coating on the surface of U-Mo particles have been proposed to inhibit the interaction layer growth. In this study, U-Mo-Ti alloy powder was produced using a centrifugal atomization method. In addition, nitride and silicide duplex coating layers were fabricated on the surface of the U-Mo-Ti particles. The coated powders were characterized by using X-ray diffraction, SEM, and EDX. Silicide and nitride single coating layers were fabricated on the surface of U-7wt%Mo-1wt%Ti alloys with a thickness of about 10.20 micrometers.

  15. Duplex Identification of Staphylococcus aureus by Aptamer and Gold Nanoparticles.

    Science.gov (United States)

    Chang, Tianjun; Wang, Libo; Zhao, Kexu; Ge, Yu; He, Meng; Li, Gang

    2016-06-01

    Staphylococcus aureus is the top common pathogen causing infections and food poisoning. Identification of S. aureus is crucial for the disease diagnosis and regulation of food hygiene. Herein, we report an aptamer-AuNPs based method for duplex identification of S. aureus. Using AuNPs as an indicator, SA23, an aptamer against S. aureus, can well identify its target from Escherichia coli, Listeria monocytogenes and Pseudomonas aeruginosa. Furthermore, we find citrate-coated AuNPs can strongly bind to S. aureus, but not bind to Salmonella enterica and Proteus mirabilis, which leads to different color changes in salt solution. This colorimetric response is capable of distinguishing S. aureus from S. enteritidis and P. mirabilis. Thus, using the aptasensor and AuNPs together, S. aureus can be accurately identified from the common pathogens. This duplex identification system is a promising platform for simple visual identification of S. aureus. Additionally, in the aptasensing process, bacteria are incubated with aptamers and then be removed before the aptamers adding to AuNPs, which may avoid the interactions between bacteria and AuNPs. This strategy can be potentially applied in principle to detect other cells by AuNPs-based aptasensors. PMID:27427591

  16. Thermal Aging Phenomena in Cast Duplex Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Byun, Thak Sang; Yang, Ying; Overman, Nicole R.; Busby, Jeremy T.

    2016-02-28

    Cast stainless steels (CASSs) have been extensively used for the large components of light water reactor (LWR) power plants such as primary coolant piping and pump casing. The thermal embrittlement of CASS components is one of the most serious concerns related to the extended-term operation of nuclear power plants. Many past researches have concluded that the formation of Cr–rich α'-phase by Spinodal decomposition of δ-ferrite phase is the primary mechanism for the thermal embrittlement. Cracking mechanism in the thermally-embrittled duplex stainless steels consists of the formation of cleavage at ferrite and its propagation via separation of ferrite-austenite interphase. This article intends to provide an introductory overview on the thermal aging phenomena in LWR relevant conditions. Firstly, the thermal aging effect on toughness is discussed in terms of the cause of embrittlement and influential parameters. An approximate analysis of thermal reaction using Arrhenius equation was carried out to scope the aging temperatures for the accelerated aging experiments to simulate the 60 and 80 years of services. Further, equilibrium precipitation calculation was performed for model CASS alloys using the CALPHAD program and the results are used to describe the precipitation behaviors in duplex stainless steels. These results are also to be used to guide an on-going research aiming to provide knowledge-based conclusive prediction for the integrity of the CASS components of LWR power plants during the service life extended up to and beyond 60 years.

  17. Thermal Aging Phenomena in Cast Duplex Stainless Steels

    Science.gov (United States)

    Byun, T. S.; Yang, Y.; Overman, N. R.; Busby, J. T.

    2016-02-01

    Cast stainless steels (CASSs) have been extensively used for the large components of light water reactor (LWR) power plants such as primary coolant piping and pump casing. The thermal embrittlement of CASS components is one of the most serious concerns related to the extended-term operation of nuclear power plants. Many past researches have concluded that the formation of Cr-rich α'-phase by Spinodal decomposition of δ-ferrite phase is the primary mechanism for the thermal embrittlement. Cracking mechanism in the thermally-embrittled duplex stainless steels consists of the formation of cleavage at ferrite and its propagation via separation of ferrite-austenite interphase. This article intends to provide an introductory overview on the thermal aging phenomena in LWR-relevant conditions. Firstly, the thermal aging effect on toughness is discussed in terms of the cause of embrittlement and influential parameters. An approximate analysis of thermal reaction using Arrhenius equation was carried out to scope the aging temperatures for the accelerated aging experiments to simulate the 60 and 80 years of services. Further, an equilibrium precipitation calculation was performed for model CASS alloys using the CALPHAD program, and the results are used to describe the precipitation behaviors in duplex stainless steels. These results are also to be used to guide an on-going research aiming to provide knowledge-based conclusive prediction for the integrity of the CASS components of LWR power plants during the service life extended up to and beyond 60 years.

  18. Thermal treatment effects on laser surface remelting duplex stainless steel

    Science.gov (United States)

    do Nascimento, Alex M.; Ierardi, Maria Clara F.; Aparecida Pinto, M.; Tavares, Sérgio S. M.

    2008-10-01

    In this paper the microstructural changes and effects on corrosion resistance of duplex stainless steels UNS S32304 and UNS S32205, commonly used by the petroleum industry, were studied, following the execution of laser surface remelting (LSM) and post-thermal treatments (TT). In this way, data was obtained, which could then be compared with the starting condition of the alloys. In order to analyze the corrosion behaviour of the alloys in the as-received conditions, treated with laser and after post-thermal treatments, cyclic polarization tests were carried out. A solution of 3.5% NaCl (artificial sea water) was used, as duplex stainless steels are regularly used by the petroleum industry in offshore locations. The results obtained showed that when laser surface treated, due to rapid resolidification, the alloys became almost ferritic, and since the level of nitrogen in the composition of both alloys is superior to their solubility limit in ferrite, a precipitation of Cr2N (chromium nitrides) occurred in the ferritic matrix, causing loss of corrosion resistance, thus resulting in an increase in surface hardness. However, after the post-thermal treatment the alloys corrosion resistance was restored to values close to those of the as-received condition.

  19. Duplex Identification of Staphylococcus aureus by Aptamer and Gold Nanoparticles.

    Science.gov (United States)

    Chang, Tianjun; Wang, Libo; Zhao, Kexu; Ge, Yu; He, Meng; Li, Gang

    2016-06-01

    Staphylococcus aureus is the top common pathogen causing infections and food poisoning. Identification of S. aureus is crucial for the disease diagnosis and regulation of food hygiene. Herein, we report an aptamer-AuNPs based method for duplex identification of S. aureus. Using AuNPs as an indicator, SA23, an aptamer against S. aureus, can well identify its target from Escherichia coli, Listeria monocytogenes and Pseudomonas aeruginosa. Furthermore, we find citrate-coated AuNPs can strongly bind to S. aureus, but not bind to Salmonella enterica and Proteus mirabilis, which leads to different color changes in salt solution. This colorimetric response is capable of distinguishing S. aureus from S. enteritidis and P. mirabilis. Thus, using the aptasensor and AuNPs together, S. aureus can be accurately identified from the common pathogens. This duplex identification system is a promising platform for simple visual identification of S. aureus. Additionally, in the aptasensing process, bacteria are incubated with aptamers and then be removed before the aptamers adding to AuNPs, which may avoid the interactions between bacteria and AuNPs. This strategy can be potentially applied in principle to detect other cells by AuNPs-based aptasensors.

  20. Resonance energy transfer in DNA duplexes labeled with localized dyes.

    Science.gov (United States)

    Cunningham, Paul D; Khachatrian, Ani; Buckhout-White, Susan; Deschamps, Jeffrey R; Goldman, Ellen R; Medintz, Igor L; Melinger, Joseph S

    2014-12-18

    The growing maturity of DNA-based architectures has raised considerable interest in applying them to create photoactive light harvesting and sensing devices. Toward optimizing efficiency in such structures, resonant energy transfer was systematically examined in a series of dye-labeled DNA duplexes where donor-acceptor separation was incrementally changed from 0 to 16 base pairs. Cyanine dyes were localized on the DNA using double phosphoramidite attachment chemistry. Steady state spectroscopy, single-pair fluorescence, time-resolved fluorescence, and ultrafast two-color pump-probe methods were utilized to examine the energy transfer processes. Energy transfer rates were found to be more sensitive to the distance between the Cy3 donor and Cy5 acceptor dye molecules than efficiency measurements. Picosecond energy transfer and near-unity efficiencies were observed for the closest separations. Comparison between our measurements and the predictions of Förster theory based on structural modeling of the dye-labeled DNA duplex suggest that the double phosphoramidite linkage leads to a distribution of intercalated and nonintercalated dye orientations. Deviations from the predictions of Förster theory point to a failure of the point dipole approximation for separations of less than 10 base pairs. Interactions between the dyes that alter their optical properties and violate the weak-coupling assumption of Förster theory were observed for separations of less than four base pairs, suggesting the removal of nucleobases causes DNA deformation and leads to enhanced dye-dye interaction. PMID:25397906

  1. Long term thermal aging of cast duplex stainless steels

    International Nuclear Information System (INIS)

    Cast duplex stainless steels of CF8M and CF8 are used in major components because of their superior characteristics, such as corrosion resistance, weldability and so on. But, these stainless steels are known to have tendency of thermal aging embrittlement after long term service. Therefore, mechanical properties and metallurgical structure were investigated using materials aged at 290--400 C up to 30,000 hours. As the results show, effects of thermal aging on mechanical properties and metallurgical behavior were identified. In addition, prediction method for Charpy absorbed energy and fracture toughness was established. The following results have been obtained: (1) it was recognized that Charpy absorbed energy and fracture toughness tend to decrease and the tensile strength tend to increase with the increasing aging time; (2) it was confirmed that thermal aging embrittlement was caused by the phase separation in ferrite from the test results of APFIM; (3) in the degradation prediction model development the prediction model was applied to the material test data, including materials aged for 30,000 hours. As the results, the degradation prediction formulas for CVRT, CVHT, JIC and J6 were obtained. The toughness of cast duplex stainless steels during service could be estimated from chemical composition using this method

  2. Long term thermal aging of cast duplex stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, Isao; Koyama, Masakuni [Japan Power Engineering and Inspection Corp., Tokyo (Japan); Kawaguchi, Seiichi [Mitsubishi Heavy Industries, Ltd., Takasago (Japan); Mimaki, Hidehito [Mitsubishi Heavy Industries, Ltd., Kobe (Japan); Akiyama, Mamoru; Mishima, Yoshitsugu [Univ. of Tokyo (Japan); Okubo, Tadatsune [Sophia Univ., Tokyo (Japan); Mager, T.R.

    1996-09-01

    Cast duplex stainless steels of CF8M and CF8 are used in major components because of their superior characteristics, such as corrosion resistance, weldability and so on. But, these stainless steels are known to have tendency of thermal aging embrittlement after long term service. Therefore, mechanical properties and metallurgical structure were investigated using materials aged at 290--400 C up to 30,000 hours. As the results show, effects of thermal aging on mechanical properties and metallurgical behavior were identified. In addition, prediction method for Charpy absorbed energy and fracture toughness was established. The following results have been obtained: (1) it was recognized that Charpy absorbed energy and fracture toughness tend to decrease and the tensile strength tend to increase with the increasing aging time; (2) it was confirmed that thermal aging embrittlement was caused by the phase separation in ferrite from the test results of APFIM; (3) in the degradation prediction model development the prediction model was applied to the material test data, including materials aged for 30,000 hours. As the results, the degradation prediction formulas for CVRT, CVHT, J{sub IC} and J{sub 6} were obtained. The toughness of cast duplex stainless steels during service could be estimated from chemical composition using this method.

  3. Stress corrosion cracking of duplex stainless steels in caustic solutions

    Science.gov (United States)

    Bhattacharya, Ananya

    Duplex stainless steels (DSS) with roughly equal amount of austenite and ferrite phases are being used in industries such as petrochemical, nuclear, pulp and paper mills, de-salination plants, marine environments, and others. However, many DSS grades have been reported to undergo corrosion and stress corrosion cracking in some aggressive environments such as chlorides and sulfide-containing caustic solutions. Although stress corrosion cracking of duplex stainless steels in chloride solution has been investigated and well documented in the literature but the SCC mechanisms for DSS in caustic solutions were not known. Microstructural changes during fabrication processes affect the overall SCC susceptibility of these steels in caustic solutions. Other environmental factors, like pH of the solution, temperature, and resulting electrochemical potential also influence the SCC susceptibility of duplex stainless steels. In this study, the role of material and environmental parameters on corrosion and stress corrosion cracking of duplex stainless steels in caustic solutions were investigated. Changes in the DSS microstructure by different annealing and aging treatments were characterized in terms of changes in the ratio of austenite and ferrite phases, phase morphology and intermetallic precipitation using optical micrography, SEM, EDS, XRD, nano-indentation and microhardness methods. These samples were then tested for general and localized corrosion susceptibility and SCC to understand the underlying mechanisms of crack initiation and propagation in DSS in the above-mentioned environments. Results showed that the austenite phase in the DSS is more susceptible to crack initiation and propagation in caustic solutions, which is different from that in the low pH chloride environment where the ferrite phase is the more susceptible phase. This study also showed that microstructural changes in duplex stainless steels due to different heat treatments could affect their SCC

  4. Variación del módulo de Young con el tratamiento térmico en aceros al carbono hipoeutectoides

    Directory of Open Access Journals (Sweden)

    Roca, A.

    2005-12-01

    Full Text Available In previous papers, several hipoeutectoide carbon steels in quenched condition showed values of Young's modulus inferior to values corresponding to tempered condition. In all cases, Young's modulus was measured by ultrasound techniques. In fact, modulus of C22E steel (EN 10083 increases from 209 GPa (quenched condition up to 211 GPa (tempered to 650 °C; for C45E steel, modulus increases from 199 GPa to 211 GPa (tempered to 500 °C, and for C55E steel Young's modulus varies from 202 GPa to 209 GPa for tempered steel to 650 °C. The present work focuses on the microstructural characterization of these steels at different heat conditions using reflection optical microscopy and also scanning electronic microscopy and the authors propose an explanation of the modulus variation using the behaviour of the dislocations array and their interaction with solute atoms and other dislocations present in steel.En trabajos anteriores se ha constatado que varios aceros al carbono hipoeutectoides, en estado de temple, presentan valores del módulo de Young inferiores a los correspondientes en estado de revenido. En todos los casos la determinación se ha realizado mediante ultrasonidos. En concreto, para el acero C22E (EN 10083, el módulo se incrementa ligeramente desde 209 GPa (material templado hasta 211 GPa (revenido a 650 °C, para el acero C45E el módulo aumenta desde 199 GPa hasta 211 GPa (revenido a 500 °C y para el acero C55E el módulo varía desde 202 GPa hasta 209 GPa para el acero revenido a 650 °C. El presente trabajo se centra en la caracterización estructural de los tres aceros mencionados a los distintos estados de tratamiento térmico, utilizando las técnicas de microscopía óptica de reflexión y microscopía electrónica de barrido, y se propone una explicación de la variación del módulo a partir del comportamiento de las dislocaciones y su interacción con átomos de soluto y con otras dislocaciones.

  5. S-N Curves of high resistance steels in the gigacyclic regime; Curvas S-N de aceros de alta resistencia dentro del regimen gigaciclico

    Energy Technology Data Exchange (ETDEWEB)

    Marinez G, I [Conservatoire National des Arts et Metiers-Institut des Technologies et des Materiaux Avances (CNAM-ITMA), Paris (France); Dominguez A, G [Instituto Tecnologico de Celaya, Guanajuato (Mexico); Bathias, C [Conservatoire National des Arts et Metiers-Institut des Technologies et des Materiaux Avances (CNAM-ITMA), Paris (France)

    2004-04-15

    In this paper, the fatigue behavior of high strength steel used for mechanical parts has been investigated in the gigacycle fatigue regime. An experimental study has been carried out with both: R = 0.1 (perlitic-ferritic steel) and R = -1 (perlitic-ferritic steel, bainitic steel, martensitic steels) loads, at a high frequency of 20 khz up to 1010 cycles, to determine the S-N curves when fatigue life is more than 107 cycles. Comparison of experimental results at frequencies of 20 khz and 30 Hz with R = -1, shows that the S-N curve has a good agreement between 105 and 107 cycles for the high strength steels, Furthermore, fracture surface observations are made by SEM; the transition of crack initiation site is described. The generalization of gigacycle fatigue behavior is analyzed. More often initiation of fatigue crack at 109 cycles is a bulk phenomenon with an important effect of stress concentration due to mineral inclusions or perlitic platelets. Thus, the Murakami model is efficient when we can measure the defects associated with fracture, but it can not take into account the microstructure effect related to platelets phenomenon. [Spanish] En este trabajo se investigo el comportamiento en fatiga gigaciclica de varios aceros de alta resistencia utilizados en la industria automotriz. El estudio experimental se llevo a cabo utilizando dos diferentes valores de carga: R = 0.1 (acero perlitoferritico) y R = -1 (acero perlito-ferritico, acero bainitico, aceros martensiticos), a una frecuencia de ensayo de 20 kHz y hasta 1010 ciclos, para determinar las curvas S-N arriba de 107 ciclos. La comparacion de resultados experimentales obtenidos utilizando frecuencias de ensayo de 20 kHz y 30 Hz con la relacion de carga R = - 1, muestran la continuidad de las curvas S-N entre 105 y 107 ciclos para estos aceros de alta resistencia. Por otro lado, observaciones de la superficie de fractura se efectuaron utilizando el microscopio electronico de barrido; se describe la transicion

  6. Avaliação do coeficiente de atrito de braquetes metálicos e estéticos com fios de aço inoxidável e beta-titânio Evaluation of the friction coefficient of metal and esthetic brackets with stainless steel and beta-titanium wires

    OpenAIRE

    Cristine Pritsch Braga; Guilherme Drumond Vanzin; Ernani Menezes Marchioro; João Carlos P. Beck

    2004-01-01

    Um fator importante que define a eficácia dos aparelhos ortodônticos fixos é o atrito existente entre as superfícies de fios e braquetes. Assim, este estudo teve como objetivo investigar o coeficiente de atrito estático entre fios de aço inoxidável e beta-titânio (TP Orthodontics) e braquetes de aço inoxidável (Dynalock® - Unitek), braquetes estéticos com slot de aço inoxidável (Clarity® - Unitek) e estéticos convencionais (Allure® - GAC). Para tanto, construiu-se um equipament...

  7. A força de atrito em braquetes plásticos e de aço inoxidável com a utilização de quatro diferentes tipos de amarração Frictional forces in stainless steel and plastic brackets using four types of wire ligation

    OpenAIRE

    Vanessa Nínia Correia Lima; Maria Elisa Rodrigues Coimbra; Carla D'Agostini Derech; Antônio Carlos de Oliveira Ruellas

    2010-01-01

    OBJETIVO: a finalidade deste estudo in vitro foi avaliar e comparar a resistência friccional em braquetes de aço inoxidável e de policarbonato compósito amarrados com fio metálico e elastômeros. MÉTODOS: foram utilizados quatro braquetes de aço inoxidável e quatro de policarbonato compósito (PC) para pré-molares levados à máquina universal de ensaio mecânico para a tração de um segmento de fio de aço inoxidável 0,019" x 0,025" na velocidade de 0,5mm/min, com 8mm de deslocamento total. A forma...

  8. Tratamientos térmicos de los aceros sinterizados obtenidos a partir de polvos prealeados Fe-1,5% Mo

    Directory of Open Access Journals (Sweden)

    Torralba, J. M.

    1995-04-01

    Full Text Available The influence of several heat treatments on the mechanical and physical properties of three different sintered Ni-Cu-Mo alloyed steels are evaluated. The heat treatments carried out were quenching and tempering at different temperatures. The raw material studied was a Fe-Mo prealloyed powder with an 1.5% Mo content.

    Se estudia la influencia que distintos estados de tratamiento térmico ejercen sobre las propiedades mecánicas y físicas de tres aceros aleados con cobre, níquel y molibdeno sinterizados. Los tratamientos térmicos realizados consisten en temple y revenido a distintas temperaturas. El material de partida utilizado para conseguir la aleación de molibdeno ha sido un polvo prealeado de Fe-1,5% Mo.

  9. Preparation and property of duplex Ni-B-TiO2/Ni nano-composite coatings

    Science.gov (United States)

    Wang, Shu-Jen; Wang, Yuxin; Shu, Xin; Tay, Seeleng; Gao, Wei; Shakoor, R. A.; Kahraman, Ramazan

    2015-03-01

    The duplex Nickel-Boron-Titania/Nickel (Ni-B-TiO2/Ni) coatings were deposited on mild steel by using two baths with Ni as the inner layer. TiO2 nanoparticles were incorporated into the Ni-B coatings as the outer layer by using solid particle mixing method. The microstructure, morphology and corrosion resistance of the duplex Ni-B-TiO2/Ni nanocomposite coatings were systemically investigated. The results show that the duplex interface was uniform and the adhesion between two layers was very good. The microhardness of duplex Ni-B-TiO2/Ni coating was much higher than the Ni coating due to the outer layer of Ni-B-TiO2 coating. The corrosion resistance of the duplex Ni-B-TiO2/Ni coating was also significantly improved comparing with single Ni-B coating. The Ni-B-10 g/L TiO2/Ni coating was found to have the best corrosion resistance among these duplex coatings. This type of duplex Ni-B-TiO2/Ni coating, with high hardness and good corrosion resistance properties, should be able to find broad applications under adverse environmental conditions.

  10. Hybridization accompanying FRET event in labeled natural nucleoside-unnatural nucleoside containing chimeric DNA duplexes.

    Science.gov (United States)

    Bag, Subhendu Sekhar; Das, Suman K; Pradhan, Manoj Kumar; Jana, Subhashis

    2016-09-01

    Förster resonance energy transfer (FRET) is a highly efficient strategy in illuminating the structures, structural changes and dynamics of DNA, proteins and other biomolecules and thus is being widely utilized in studying such phenomena, in designing molecular/biomolecular probes for monitoring the hybridization event of two single stranded DNA to form duplex, in gene detection and in many other sensory applications in chemistry, biology and material sciences. Moreover, FRET can give information about the positional status of chromophores within the associated biomolecules with much more accuracy than other methods can yield. Toward this end, we want to report here the ability of fluorescent unnatural nucleoside, triazolylphenanthrene ((TPhen)BDo) to show FRET interaction upon hybridization with fluorescently labeled natural nucleosides, (Per)U or (OxoPy)U or (Per)U, forming two stable chimeric DNA duplexes. The pairing selectivity and the thermal duplex stability of the chimeric duplexes are higher than any of the duplexes with natural nucleoside formed. The hybridization results in a Förster resonance energy transfer (FRET) from donor triazolylphenanthrene of (TPhen)BDo to acceptor oxopyrene of (OxoPy)U and/or to perylene chromophore of (Per)U, respectively, in two chimeric DNA duplexes. Therefore, we have established the FRET process in two chimeric DNA duplexes wherein a fluorescently labeled natural nucleoside ((OxoPy)U or (Per)U) paired against an unnatural nucleoside ((TPhen)BDo) without sacrificing the duplex stability and B-DNA conformation. The hybridization accompanying FRET event in these classes of interacting fluorophores is new. Moreover, there is no report of such designed system of chimeric DNA duplex. Our observed phenomenon and the design can potentially be exploited in designing more of such efficient FRET pairs for useful application in the detection and analysis of biomolecular interactions and in material science application.

  11. ESTUDIO DE LA IDONEIDAD DEL ENSAYO MINIATURA DE PUNZONADO PARA LA CARACTERIZACION MECANICA DE LOS ACEROS Y DE SUS UNIONES SOLDADAS

    Directory of Open Access Journals (Sweden)

    C. RODRÍGUEZ C.

    2012-01-01

    Full Text Available Los ensayos small punch (SPT permiten estimar propiedades mecánicas de los aceros, empleando una cantidad de material muy pequeña, lo que los hace especialmente interesantes en el análisis de componentes en servicio o zonas demasiado pequeñas para extraer probetas normalizadas. Existen diversas propuestas para estimar propiedades tales como el límite elástico, la resistencia a la tracción, el alargamiento a rotura o la tenacidad a fractura, si bien es cierto que existe una gran controversia sobre las mismas. El presente trabajo analiza varias de estas propuestas, aplicándolas a una amplia gama de aceros, con diferentes microestructuras y características mecánicas.

  12. Detection of Hepatitis B Virus DNA by Duplex Scorpion Primer-based PCR Assay

    Institute of Scientific and Technical Information of China (English)

    KONG De-Ming孔德明; SHEN Han-Xi沈含熙; MI Huai-Feng宓怀风

    2004-01-01

    The application of a new fiuorogenic probe-based PCR assay (PCR duplex scorpion primer assay) to the detection of Hepatitis B virus (HBV) DNA in human sera was described. Duplex scorpion primer is a modified variant of duplex Amplifluor, and the incorporation of a PCR stopper between probe and primer sequences improve the detection specificity and sensitivity. Combined with PCR amplification, this probe can give unambiguous positive results for the reactions initiated with more than 20 HBV molecules. In addition, the particular unimolecular probing mechanism of this probe makes the use of short target-specific probe sequence possible, which will render this probe applicable in some specific systems.

  13. The stability of triplex DNA is affected by the stability of the underlying duplex

    OpenAIRE

    Rusling, David A.; Rachwal, Phillip A.; Brown, Tom; Fox, Keith R.

    2009-01-01

    Abstract We have studied the formation of DNA triple helices in different sequence contexts and show that, for the most stable triplexes, their apparent stability is affected by the stability of the underlying duplex. For a 14-mer parallel triplex-forming oligonucleotide (generating C+.GC and T.AT triplets) at pH 5.0 the Tm is more than 10?C lower with an intermolecular 14-mer duplex target, than it is with an intramolecular duplex, or one which is flanked by 6 GC base pairs at eit...

  14. GRINDING OF HARDENED STEELS USING OPTIMIZED COOLING RECTIFICADO DE ACEROS ENDURECIDOS USANDO REFRIGERACIÓN OPTIMIZADA

    Directory of Open Access Journals (Sweden)

    Manoel Cléber de Sampaio Alves

    2008-06-01

    medio. Para ello, al proceso de rectificación está intrínseco el reciclaje del fluido de corte, que se destaca por su costo. A través de la variación de la velocidad de avance en el proceso de rectificación cilíndrica externa del acero ABNT D6, racionalizando la aplicación de dos fluidos de corte y usando una muela superabrasiva de CBN (nitruro de boro cúbico con ligante vitrificado, se evaluaron los parámetros de salida fuerza tangencial de corte, rugosidad, circularidad, desgaste de la herramienta, la tensión residual y la integridad superficial a través de la microscopia electrónica de barrido (SEM de las piezas de prueba. Con el análisis del desempeño fluido, muela y velocidad de inmersión se encontró las mejores condiciones de fabricación propiciando la disminución del volumen de fluido de corte, disminución del tiempo de fabricación sin perjudicar los parámetros geométricos, dimensionales, el acabado superficial y la integridad superficial de los componentes.

  15. Optimización de fases líquidas para la sinterización de aceros: efecto en la microestructura y comportamiento dimensional

    OpenAIRE

    Bernardo Quejido, Elena

    2014-01-01

    Desde que aparecieron los primeros componentes pulvimetalúrgicos base hierro a principios de la década de los cuarenta, la industria de los aceros sinterizados ha pasado de proporcionar componentes de baja fiabilidad y propiedades mecánicas muy limitadas, a fabricar componentes de altas prestaciones y elevada robustez dimensional, que cubren un amplio espectro de aplicaciones y requerimientos. Las mejoras introducidas en los sistemas de aleación y las rutas de procesado han ...

  16. Technology of Welding Joints Mixed with Duplex Steel

    Directory of Open Access Journals (Sweden)

    Słania J.

    2016-03-01

    Full Text Available Results of the examinations of sample plates of mixed joints with the duplex steel were discussed. Examinations were taken on the sample plates of mixed joints of sheet plates type P355NL1 and X2CrNiMoN22-5-3 welded by the flux-cored wire DW-329A by the Kobelco company of the following category T 22 9 3 NL RC/M3 in the gas shroud M21 (Ar+18%CO2 (plate no.1, and nickel covered electrodes E Ni 6082 by the Böhler company (plate no. 2. Results of the side bend test of welded joint, transverse tensile test, stretching of the weld metal, impact strength, micro and macroscopic metallographic examinations, and measurements of the delta ferrite content were presented.

  17. Electromagnetic non-destructive technique for duplex stainless steel characterization

    Science.gov (United States)

    Rocha, João Vicente; Camerini, Cesar; Pereira, Gabriela

    2016-02-01

    Duplex stainless steel (DSS) is a two-phase (ferrite and austenite) material, which exhibits an attractive combination of mechanical properties and high corrosion resistance, being commonly employed for equipment of petrochemical plants, refining units and oil & gas platforms. The best properties of DSS are achieved when the phases are in equal proportions. However, exposition to high temperatures (e.g. welding process) may entail undesired consequences, such as deleterious phases precipitation (e.g. sigma, chi) and different proportion of the original phases, impairing dramatically the mechanical and corrosion properties of the material. A detailed study of the magnetic behavior of DSS microstructure with different ferrite austenite ratios and deleterious phases content was accomplished. The non destructive method evaluates the electromagnetic properties changes in the material and is capable to identify the presence of deleterious phases into DSS microstructure.

  18. Isothermal DNA amplification strategies for duplex microorganism detection.

    Science.gov (United States)

    Santiago-Felipe, Sara; Tortajada-Genaro, Luis Antonio; Morais, Sergi; Puchades, Rosa; Maquieira, Ángel

    2015-05-01

    A valid solution for micro-analytical systems is the selection of a compatible amplification reaction with a simple, highly-integrated efficient design that allows the detection of multiple genomic targets. Two approaches under isothermal conditions are presented: recombinase polymerase amplification (RPA) and multiple displacement amplification (MDA). Both methods were applied to a duplex assay specific for Salmonella spp. and Cronobacter spp., with excellent amplification yields (0.2-8.6 · 10(8) fold). The proposed approaches were successfully compared to conventional PCR and tested for the milk sample analysis as a microarray format on a compact disc (support and driver). Satisfactory results were obtained in terms of resistance to inhibition, selectivity, sensitivity (10(1)-10(2)CFU/mL) and reproducibility (below 12.5%). The methods studied are efficient and cost-effective, with a high potential to automate microorganisms detection by integrated analytical systems working at a constant low temperature.

  19. XPS study of duplex stainless steel oxidized by oxygen atoms

    Energy Technology Data Exchange (ETDEWEB)

    Donik, Crtomir [Institute of Metals and Technology, Lepi pot 11, SI-1000 Ljubljana (Slovenia)], E-mail: crtomir.donik@imt.si; Kocijan, Aleksandra [Institute of Metals and Technology, Lepi pot 11, SI-1000 Ljubljana (Slovenia); Grant, John T. [Research Institute, University of Dayton, 300 College Park, Dayton OH 45469-0051 (United States); Jenko, Monika [Institute of Metals and Technology, Lepi pot 11, SI-1000 Ljubljana (Slovenia); Drenik, Aleksander [Jozef Stefan Institute, Jamova cesta 39, 1000 Ljubljana (Slovenia); Pihlar, Boris [Faculty of Chemistry and Chemical Technology, Askerceva 5, SI-1000 Ljubljana (Slovenia)

    2009-04-15

    Surface oxidation of the duplex stainless steel DSS alloy 2205 was studied by X-ray photoelectron spectroscopy (XPS) and SEM imaging. The experiments were performed on the alloy after controlled oxidation with oxygen atoms created in an inductively coupled plasma. Experiments were performed at temperatures from room temperature up to 700 deg. C. Compositions of the modified oxidized surfaces were obtained from XPS survey scans, and the chemistries of selected elements from higher energy resolution scans of appropriate peaks. The morphologies of the surfaces were obtained using field emission scanning electron microscopy at different magnifications, up to 10,000x. Different Fe/Cr/Mn oxidized layers and different oxide thicknesses were observed and correlated with temperature.

  20. Hydrogen effects in duplex stainless steel welded joints - electrochemical studies

    Science.gov (United States)

    Michalska, J.; Łabanowski, J.; Ćwiek, J.

    2012-05-01

    In this work results on the influence of hydrogen on passivity and corrosion resistance of 2205 duplex stainless steel (DSS) welded joints are described. The results were discussed by taking into account three different areas on the welded joint: weld metal (WM), heat-affected zone (HAZ) and parent metal. The corrosion resistance was qualified with the polarization curves registered in a synthetic sea water. The conclusion is that, hydrogen may seriously deteriorate the passive film stability and corrosion resistance to pitting of 2205 DSS welded joints. The presence of hydrogen in passive films increases corrosion current density and decreases the potential of the film breakdown. It was also found that degree of susceptibility to hydrogen degradation was dependent on the hydrogen charging conditions. WM region has been revealed as the most sensitive to hydrogen action.

  1. Modern high strength QT, TM and duplex-stainless steels

    International Nuclear Information System (INIS)

    Pressure vessels are commonly manufactured with normalised steel grades with a yield strength up to 355 MPa or with austenitic stainless steels when corrosion as to be considered. From three decades, modern steels with higher mechanical properties - up to yield strength of 960 Mpa - are available and largely used for other applications where weight saving is of major importance as per off-shore, bridges, cranes, shipbuilding, line pipes.. The paper presents these modern steel's families - TMCP (Thermo Mechanically Controlled Process), QT (Quenched and Tempered) and Duplex (austeno-ferritic) stainless - in comparison with the normalised and austenitic steel grades. The following aspects are presented: the main mechanical properties (tensile and Charpy) as per the requirements of the standards for pressure equipment; some examples of use of these modern steels in the industry are given; the limitations of the forming conditions are considered; the weldability aspects and welds properties are developed; the interest of the PWHT (Post Weld Heat Treatment) is discussed. (orig.)

  2. The diffusion of chromium in a duplex alloy steel

    International Nuclear Information System (INIS)

    Diffusion of chromium in a duplex stainless steel containing approximately 8% ferrite has been investigated in the temperature range 600 to 10000C using the standard serial sectioning technique. The resulting concentration profiles exhibited up to four distinct regions. The two main regions are attributed to volume diffusion in the austenite and ferrite phases, the other zones being due to short circuiting paths. Volume diffusion in the austenite phase is in good agreement with chromium diffusion in Type 316 steel. The chromium diffusion coefficient in the ferrite phase of approximate composition 25 wt % Cr, 5 wt % Ni is given by: Dsub(α) = (6.0(+11,-3)) x 10-6 exp - ((212+-5)/RT) m2s-1 the activation energy being expressed in kJ.mol-1. Little evidence was found for enhanced chromium diffusion along austenite/ferrite interface boundaries. (author)

  3. Implementation of real-time duplex synthetic aperture ultrasonography

    DEFF Research Database (Denmark)

    Hemmsen, Martin Christian; Larsen, Lee; Kjeldsen, Thomas;

    2015-01-01

    in the TCP/IP protocol. Benchmarking of real-time imaging showed a total processing time of 25.7 ms (39 frames/s) which is less than the acquisition time (29.4 ms). In conclusion, the proposed implementation demonstrates that both B-mode and CFM can be executed in-time for real-time ultrasound imaging......This paper presents a real-time duplex synthetic aperture imaging system, implemented on a commercially available tablet. This includes real-time wireless reception of ultrasound signals and GPU processing for B-mode and Color Flow Imaging (CFM). The objective of the work is to investigate...... the implementation complexity and processing demands. The image processing is performed using the principle of Synthetic Aperture Sequential Beamforming (SASB) and the flow estimator is implemented using the cross-correlation estimator. Results are evaluated using a HTC Nexus 9 tablet and a BK Medical BK3000...

  4. Duplex Doppler ultrasound study of the temporomandibular joint.

    Science.gov (United States)

    Stagnitti, A; Marini, A; Impara, L; Drudi, F M; Lo Mele, L; Lillo Odoardi, G

    2012-06-01

    Sommario INTRODUZIONE: La fisiologia articolare dell’articolazione temporo-mandibolare (ATM) può essere esaminata sia dal punto di vista clinico che strumentale. La diagnostica per immagini ha da tempo contribuito con la risonanza magnetica (RM) e anche con la radiografia (Rx) e la tomografia computerizzata (TC) all’analisi della morfologia dei capi articolari e della cinetica condilare. L’esame duplex-ecodoppler è una metodica di largo impiego nello studio delle strutture in movimento in particolar modo a livello delle strutture del sistema vascolare. MATERIALI E METODI: È stata utilizzata un’apparecchiatura Toshiba APLIO SSA-770A, con l’uso di tecnica duplex-ecodoppler multi display, che consente la visualizzazione contemporanea dell’immagine ecografica e dei segnali Doppler utilizzando una sonda lineare del tipo phased array con cristalli trasduttori funzionanti ad una frequenza fondamentale di 6 MHz per gli spettri Doppler pulsati e 7.5 MHz per l’imaging ecografico. Sono stati esaminati nel Dipartimento di Scienze Radiologiche, Oncologiche e Anatomo-patologiche dell’Università “Sapienza” di Roma, 30 pazienti del reparto di Ortognatodonzia dell’Istituto di Odontoiatria della stessa Università. RISULTATI: Nei pazienti normali si è ottenuta un’alternanza regolare degli spettri Doppler, mentre nei soggetti con disfunzioni del complesso condilo-meniscale, si è persa la regolarità della sommatoria degli spettri di Fourier, con altezze incostanti in relazione a spostamenti irregolari del complesso condilo-meniscale. CONCLUSIONI: L’esame ecodoppler si è dimostrato, in tutti i pazienti, capace di discriminare quelli normali dai patologici e tra questi ultimi ha permesso di identificare gli aspetti più significativi delle patologie disfunzionali.

  5. Estudio para la optimización de la composición de un HACFRA (hormigón autocompactante reforzado con fibras de acero estructural

    Directory of Open Access Journals (Sweden)

    Orbe, A.

    2015-03-01

    Full Text Available The interest of HACFRA (self compacting concrete reinforced with steel fibers, is the combination of the residual strength increase and cracking decrease compared to plain concrete by the introduction of steel fibers in the mass with the advantages of the self-compacting. The paper presents an analysis of the influence of different components of the HACRFA and provides their selection, refered to the granular skeleton and to different steel fiber types and amount, in order to obtain an optimization of its features and structural behavior.El interés de un HACFRA (Hormigón autocompactante reforzado con fibras de acero, radica en la combinación del incremento de capacidad resistente con respecto al hormigón y disminución de la fisuración, aportada por la introducción de fibras de acero, con las ventajas de la puesta en obra que supone la autocompactación. El artículo analiza la influencia de los diferentes componentes que integran el HACRFA, proponiendo una selección de los mismos, referidos tanto al esqueleto granular como a los diferentes tipos y densidades de fibras de acero, en base a la obtención de sus características y de un comportamiento estructural optimizado.

  6. Transcranial duplex doppler ultrasonography in dogs with hydrocephalus Ultrassonografia duplex Doppler transcraniana em cães com hidrocefalia

    Directory of Open Access Journals (Sweden)

    C.F. Carvalho

    2010-02-01

    Full Text Available Transcranial duplex Doppler ultrasound was performed in 32 conscious dogs presenting ventriculomegaly detected in B-mode, obtaining measures of lateral ventricles and resistance parameters of main cerebral arteries before and after 30 days of clinical treatment. The animals were distributed divided in two groups: group 1, dogs that presented remission or decrease of the neurological signs of the disease after clinical therapy; and group 2, dogs that displayed worsening of the neurological signs or clinical stability. The data were all presented in tables and were submitted to paired t test and to logistic regression models to evaluate the influence of the RI reduction on both groups. There was no significant influence of the variables in the B-mode. After the treatment, the mean resistive index (RI was significantly lower for the group that presented clinical improvement. There was no significant difference of the mean RI reduction for the same artery when the right and left sides were compared. It could be concluded that transcranial duplex Doppler ultrasound is a method of cerebral hemodynamic assessment able to monitor more precisely the treatment of hydrocephalus in dogs and verify the responses.Foi realizada a ultrassonografia duplex Doppler transcraniana em 32 cães, conscientes, que apresentavam ventriculomegalia previamente detectada ao exame modo-B, para obter as medidas dos ventrículos laterais e os parâmetros de resistência das artérias cerebrais antes e depois de 30 dias de tratamento clínico. Os animais foram distribuídos em dois grupos: 1 - formado por cães que apresentaram remissão ou diminuição dos sinais clínicos após tratamento; 2 - por cães que apresentaram piora dos sinais neurológicos ou estabilidade do quadro clínico. Todos os dados foram dispostos em tabelas e submetidos ao teste t pareado e a modelos de regressão logística para avaliar a influência da redução do índice de resistividade (IR. Não foi

  7. Sequence-specific protection of duplex DNA against restriction and methylation enzymes by pseudocomplementary PNAs

    DEFF Research Database (Denmark)

    Izvolsky, K I; Demidov, V V; Nielsen, P E;

    2000-01-01

    and sequence-specific complexes with duplex DNA in a very salt-dependent manner. In accord with a strand-invasion mode of complex formation, the pcPNA binding proceeds much faster with supercoiled than with linear plasmids. The double-duplex invasion complexes selectively shield specific DNA sites from Bcl......A new generation of PNAs, so-called pseudocomplementary PNAs (pcPNAs), which are able to target the designated sites on duplex DNA with mixed sequence of purines and pyrimidines via double-duplex invasion mode, has recently been introduced. It has been demonstrated that appropriate pairs...... of decameric pcPNAs block an access of RNA polymerase to the corresponding promoter. Here, we show that this type of PNAs protects selected DNA sites containing all four nucleobases from the action of restriction enzymes and DNA methyltransferases. We have found that pcPNAs as short as octamers form stable...

  8. Corrosion Behavior of Austenitic and Duplex Stainless Steels in Lithium Bromide

    Directory of Open Access Journals (Sweden)

    Ayo Samuel AFOLABI

    2009-07-01

    Full Text Available The corrosion behavior of austenitic and duplex stainless steels in various concentrations of lithium, bromide solution was investigated by using the conventional weight loss measurement method. The results obtained show that corrosion of these steels occurred due to the aggressive bromide ion in the medium. Duplex stainless steel shows a greater resistance to corrosion than austenitic stainless steel in the medium. This was attributed to equal volume proportion of ferrite and austenite in the structure of duplex stainless steel coupled with higher content of chromium in its composition. Both steels produced electrochemical noise at increased concentrations of lithium bromide due to continuous film breakdown and repair caused by reduction in medium concentration by the alkaline corrosion product while surface passivity observed in duplex stainless steel is attributed to film stability on this steel.

  9. Phase transformations evaluation on a UNS S31803 duplex stainless steel based on nondestructive testing

    Energy Technology Data Exchange (ETDEWEB)

    Macedo Silva, Edgard de, E-mail: edgard@cefetpb.edu.br [Centro federal de Educacao Tecnologica da Paraiba (CEFET PB), Area da Industria, Avenida 1o de Maio, 720 - 58015-430 - Joao Pessoa/PB (Brazil); Costa de Albuquerque, Victor Hugo, E-mail: victor.albuquerque@fe.up.pt [Universidade Federal da Paraiba (UFPB), Departamento de Engenharia Mecanica (DEM), Cidade Universitaria, S/N - 58059-900 - Joao Pessoa/PB (Brazil); Pereira Leite, Josinaldo, E-mail: josinaldo@ct.ufpb.br [Universidade Federal da Paraiba (UFPB), Departamento de Engenharia Mecanica (DEM), Cidade Universitaria, S/N - 58059-900 - Joao Pessoa/PB (Brazil); Gomes Varela, Antonio Carlos, E-mail: varela@cefetpb.edu.br [Universidade Federal da Paraiba (UFPB), Departamento de Engenharia Mecanica (DEM), Cidade Universitaria, S/N - 58059-900 - Joao Pessoa/PB (Brazil); Pinho de Moura, Elineudo, E-mail: elineudo@pq.cnpq.br [Universidade Federal do Ceara (UFC), Departamento de Engenharia Metalurgica e de Materiais, Campus do Pici, Bloco 715, 60455-760 - Fortaleza/CE (Brazil); Tavares, Joao Manuel R.S., E-mail: tavares@fe.up.pt [Faculdade de Engenharia da Universidade do Porto (FEUP), Departamento de Engenharia Mecanica e Gestao Industrial (DEMEGI)/Instituto de Engenharia Mecanica e Gestao Industrial - INEGI, Rua Dr. Roberto Frias, s/n, 4200-465 Porto (Portugal)

    2009-08-15

    Duplex stainless steel presents special mechanical properties such as, for example, mechanical and corrosion strength, becoming competitive in relation to the other types of stainless steel. One of the great problems of duplex stainless steel microstructural changes study is related to embrittlement above 300 deg. C, with the precipitation of the {alpha}' phase occurring over the ferritic microstructure. Aiming to characterise embrittlement of duplex stainless steel, hardening kinetics, from 425 to 475 deg. C, was analysed through the speed of sound, Charpy impact energy, X-ray diffraction, hardness and microscopy parameters. The presence of two hardening stages, detected through the speed of sound, was observed, one being of brittle characteristic and the other ductile. Moreover, the speed of sound showed a direct correlation with the material's hardness. Thus, it is concluded that the speed of sound is a promising nondestructive parameter to follow-up embrittlement in duplex stainless steel.

  10. Two-flux transfer matrix model for predicting the reflectance and transmittance of duplex halftone prints.

    Science.gov (United States)

    Mazauric, Serge; Hébert, Mathieu; Simonot, Lionel; Fournel, Thierry

    2014-12-01

    We introduce a model allowing convenient calculation of the spectral reflectance and transmittance of duplex prints. It is based on flux transfer matrices and enables retrieving classical Kubelka-Munk formulas, as well as extended formulas for nonsymmetric layers. By making different assumptions on the flux transfers, we obtain two predictive models for the duplex halftone prints: the "duplex Clapper-Yule model," which is an extension of the classical Clapper-Yule model, and the "duplex primary reflectance-transmittance model." The two models can be calibrated from either reflectance or transmittance measurements; only the second model can be calibrated from both measurements, thus giving optimal accuracy for both reflectance and transmittance predictions. The conceptual differences between the two models are deeply analyzed, as well as their advantages and drawbacks in terms of calibration. According to the test carried out in this study with paper printed in inkjet, their predictive performances are good provided appropriate calibration options are selected.

  11. On the Potential of Full Duplex Communication in 5G Small Cell Networks

    DEFF Research Database (Denmark)

    Mahmood, Nurul Huda; Berardinelli, Gilberto; Tavares, Fernando Menezes Leitão;

    2015-01-01

    Full duplex communication promises a 100% throughput gain by doubling the number of simultaneous transmissions. In a multi-cell scenario, increasing the number of simultaneous transmissions correspondingly increases the number of interference streams observed at a particular receiver. As such......, the potential throughput gain may not be 100% as promised. In this study, we evaluate the performance of full duplex communication in a dense small cell scenario as targeted by future 5th Generation (5G) radio access technology under the ideal assumptions of a full buffer, always active traffic model...... and perfect self interference cancellation. Advanced interference suppression/cancellation receivers are featured as well. Full duplex communication is found to provide about 30-40% mean throughput gain over half duplex transmissions for indoor scenarios, which provides an indication of the maximum throughput...

  12. Electrochemical Investigation of Interaction between a Bifunctional Probe and GG Mismatch Duplex.

    Science.gov (United States)

    Li, Jiao; He, Hanping; Peng, Xiaoqian; Huang, Min; Zhang, Xiuhua; Wang, Shengfu

    2015-01-01

    A bifunctional probe (FecNC), containing a recognition part and an electrochemical active center, was applied to electrochemical detection of GG mismatch duplexes. The preparation of gold electrodes modified by mismatch and complementatry duplexes was characterized by electrochemical impedance spectroscopy (EIS) and optimized for better detection in terms of self-assembly time, hybridization time, and incubation time. The interaction between FecNC and DNA duplexes modified on the surface of a gold electrode was explored by square wave voltammetry (SWV) and EIS. The results showed that the DNA duplexes with GG mismatch on the surface of a gold electrode was easily detected by the largest electrochemical signal of the bifunctional probe because of its selective binding to GG mismatches. The bifunctional probe could offer a simple, effective electrochemical detection of GG mismatches, and theoretical bases for development of electrochemical biosensors. Further, the method would be favorable for diagnosis of genetic diseases.

  13. Can Full Duplex reduce the discovery time in D2D Communication?

    DEFF Research Database (Denmark)

    Gatnau, Marta; Berardinelli, Gilberto; Mahmood, Nurul Huda;

    2016-01-01

    Device-to-device (D2D) communication is considered as one of the key technologies to support new types of services, such as public safety and proximity-based applications. D2D communication requires a discovery phase, i.e., the node awareness procedure prior to the communication phase. Conventional...... half duplex transmission may not be sufficient to provide fast discovery and cope with the strict latency targets of future 5G services. On the other hand, in-band full duplex, by allowing simultaneous transmission and reception, may complete the discovery phase faster. In this paper, the potential of...... full duplex in providing fast discovery for the next 5th generation (5G) system supporting D2D communication is investigated. A design for such system is presented and evaluated via simulations, showing that full duplex can accelerate the discovery phase by supporting a higher transmission probability...

  14. The influence of sintering time on the properties of PM duplex stainless steel

    OpenAIRE

    Z. Brytan; L.A. Dobrzański; M. Actis Grande; M. Rosso

    2009-01-01

    Purpose: The purpose of this paper is to analyse the effect of sintering time on the pore morphology, microstructural changes, tensile properties and corrosion resistance of vacuum sintered duplex stainless steel.Design/methodology/approach: In presented study PM duplex stainless steels were obtained through mixing base ferritic stainless steel powder with controlled addition of elemental alloying powders and then sintered in a vacuum furnace with argon backfilling at 1250°C for different tim...

  15. Management of multiple type Ⅱ endoleaks detected by duplex ultrasound after endovascular abdominal aneurysm repair

    Institute of Scientific and Technical Information of China (English)

    GUO Da-qiao; LI Wei-miao; JIANG Jun-hao; SHI Zhen-yu; WANG Yu-qi; FU Wei-guo

    2012-01-01

    We reported a case of multiple type Ⅱ endoleaks detected by duplex ultrasound after endovascular abdominal aneurysm repair.The patient was undergoing warfarin therapy.Duplex ultrasound was applied as the sole surveillance method during follow-up and provided the concerned information for reintervention.The endoleaks were successfully repaired by coil embolization of the collaterals from the internal iliac artery feeding the fourth lumbar artery.

  16. Minor Groove Binding between Norfloxacin and DNA Duplexes in Solution: A Molecular Dynamics Study

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    Molecular dynamics were used to investigate the interaction between norfloxacin and DNA duplex. The results showed that norfloxacin was situated in the minor groove of DNA,binding to the TCGA region of d [ATATCGATAT] 2. Specific hydrogen bonds were formed between norfloxacin and guanine base of DNA during the 2 ns MD, which may be the reason for the preferentiality of quinolone antibacterial towards the guanine base of DNA duplex.

  17. Effect of Deleterious Phases on Corrosion Resistance of Duplex Stainless Steel (2205)

    OpenAIRE

    AbdulKadar M. Godil; Hitesh A. Narsia; M. N. Patel; Mr. Paresh U. Haribhakti

    2013-01-01

    Duplex stainless steel is a Ferritic(BCC)-Austenitic(FCC) steel, covers the advantages of both Austenitic and Ferritic Stainless steels. They having good mechanical and corrosion resistance properties are widely used in many industries like chemical plants, refineries for critical equipments such as pressure vessels, heatexchangers, water heaters. Major problem occurs with duplex steels when they are worked or heated above about temperature of 280°C. Detrimental phases like Sigma, Chi, Laves ...

  18. Behaviour and design of cold-formed lean duplex stainless steel members

    OpenAIRE

    Huang, Yun'er; 黃韵兒

    2013-01-01

    Cold-formed stainless steel sections have been increasingly used in architectural and structural applications. Yet the high price of stainless steel limits the application to construction projects. The lean duplex stainless steel (EN 1.4162) offers an opportunity for stainless steels to be used more widely due to its competitive in price, good mechanical properties and corrosion resistance. The lean duplex stainless steel is a relatively new material, and research on this material is limited....

  19. Influence of sintering parameters on the properties of duplex stainless steel

    OpenAIRE

    L.A. Dobrzański; Z. Brytan; M. Actis Grande; M. Rosso

    2007-01-01

    Purpose: of this paper was to examine the influence of sintering parameters like time, temperature, atmosphereand gas pressure under cooling stage on the mechanical properties of duplex stainless steels.Design/methodology/approach: In presented study duplex stainless steels were obtained through powdermetallurgy starting from austenitic, martensitic base powders by controlled addition of alloying elements,such as Cr, Ni, Mo and Cu. In the studies behind the preparation of mixes, Schaeffler’s ...

  20. Corrosion Behavior of Austenitic and Duplex Stainless Steels in Lithium Bromide

    OpenAIRE

    Ayo Samuel AFOLABI; Alaneme, K.K.; Samson Oluwaseyi BADA

    2009-01-01

    The corrosion behavior of austenitic and duplex stainless steels in various concentrations of lithium, bromide solution was investigated by using the conventional weight loss measurement method. The results obtained show that corrosion of these steels occurred due to the aggressive bromide ion in the medium. Duplex stainless steel shows a greater resistance to corrosion than austenitic stainless steel in the medium. This was attributed to equal volume proportion of ferrite and austenite in th...

  1. Effect of Microstructure on Mechanical Properties and Corrosion Resistance of 2205 Duplex Stainless Steel

    OpenAIRE

    Łabanowski Jerzy; Świerczyńska Aleksandra; Topolska Santina

    2015-01-01

    This paper presents results of the research on impact of microstructure of austenitic-ferritic steel of duplex type on its mechanical properties and susceptibility to stress corrosion cracking. As showed, improper processing technologies more and more often used in shipbuilding industry for plates and other half-finished products made of duplex steel may cause significant lowering their properties, which frequently makes their replacing necessary. Results of the tests on stress corrosion unde...

  2. OBSERVATIONS OF STRESS CORROSION CRACKING BEHAVIOUR IN SUPER DUPLEX STAINLESS STEEL

    OpenAIRE

    Al-Rabie, Mohammed

    2011-01-01

    The new generation of highly alloyed super duplex stainless steels such as Zeron 100 are preferable materials for industrial applications demanding high strength, toughness and superior corrosion resistance, especially against stress corrosion cracking (SCC). SCC is an environmentally assisted failure mechanism that occurs due to exposure to an aggressive environment while under a tensile stress. The mechanism by which SCC of duplex stainless steel is expected to suffer depends on the combina...

  3. Corrosion resistance of sintered duplex stainless steel evaluated by electrochemical method

    OpenAIRE

    L.A. Dobrzański; Z. Brytan; M. Actis Grande; M. Rosso

    2006-01-01

    Purpose: Purpose of this paper was to examine the corrosion resistance of duplex stainless steels using electrochemical methods in 1M NaCl solution. The influence of powder mixes preparation and cooling cycle after sintering on corrosion properties was evaluated.Design/methodology/approach: In presented study duplex stainless steels were obtained through powder metallurgy starting from austenitic, martensitic base powders by controlled addition of alloying elements. In the studies behind the ...

  4. Recognition of RNA duplexes by chemically modified triplex-forming oligonucleotides

    OpenAIRE

    Zhou, Yuan; Kierzek, Elzbieta; Loo, Zi Ping; Antonio, Meraldo; Yau, Yin Hoe; Chuah, York Wieo; Geifman-Shochat, Susana; Kierzek, Ryszard; Chen, Gang

    2013-01-01

    Triplex is emerging as an important RNA tertiary structure motif, in which consecutive non-canonical base pairs form between a duplex and a third strand. RNA duplex region is also often functionally important site for protein binding. Thus, triplex-forming oligonucleotides (TFOs) may be developed to regulate various biological functions involving RNA, such as viral ribosomal frameshifting and reverse transcription. How chemical modification in TFOs affects RNA triplex stability, however, is n...

  5. Microarray Detection of Duplex and Triplex DNA Binders with DNA-Modified Gold Nanoparticles

    OpenAIRE

    Lytton-Jean, Abigail K. R.; Han, Min Su; Mirkin, Chad A.

    2007-01-01

    We have designed a chip-based assay, using microarray technology, for determining the relative binding affinities of duplex and triplex DNA binders. This assay combines the high discrimination capabilities afforded by DNA-modified Au nanoparticles with the high-throughput capabilities of DNA microarrays. The detection and screening of duplex DNA binders are important because these molecules, in many cases, are potential anticancer agents as well as toxins. Triplex DNA binders are also promisi...

  6. Matrix-assisted laser desorption/ionization mass spectrometry of immobilized duplex DNA probes.

    OpenAIRE

    Tang, K; Fu, D.; Kötter, S; Cotter, R J; Cantor, C R; Köster, H

    1995-01-01

    Matrix-assisted laser desorption/ionization (MALDI) time-of-flight (TOF) mass spectrometry was used to analyze short DNA duplex probes with one strand immobilized on solid supports (straptavidin-coated magnetic beads or controlled pore glass beads). Only the non-immobilized strand could be detected. Partial denaturation was found when the duplex probes were mixed with 3-hydroxypicolinic acid, ammonium citrate matrix. The strategy has several applications, such as fast DNA sequence analysis an...

  7. Random Linear Network Coding for Time-Division Duplexing: Queueing Analysis

    OpenAIRE

    Lucani, Daniel E.; Médard, Muriel; Stojanovic, Milica

    2009-01-01

    We study the performance of random linear network coding for time division duplexing channels with Poisson arrivals. We model the system as a bulk-service queue with variable bulk size. A full characterization for random linear network coding is provided for time division duplexing channels [1] by means of the moment generating function. We present numerical results for the mean number of packets in the queue and consider the effect of the range of allowable bulk sizes. We show that there exi...

  8. On Achievable Rate Regions for Half-Duplex Causal Cognitive Radio Channels

    OpenAIRE

    Chatterjee, Debdeep; Wong, Tan F.; Oyman, Ozgur

    2010-01-01

    Coding for the causal cognitive radio channel, with the cognitive source subjected to a half-duplex constraint, is studied. A discrete memoryless channel model incorporating the half-duplex constraint is presented, and a new achievable rate region is derived for this channel. It is proved that this rate region contains the previously known causal achievable rate region of \\cite{Devroye06} for Gaussian channels.

  9. Influence Of Heat Treatment On Duplex Stainless Steel To Study The Material Properties

    OpenAIRE

    Jithin M; Anees Abdul Hameed; Ben Jose; Anush Jacob

    2015-01-01

    Abstract The various heat treatment processes are annealing normalizing hardening tempering spheroidising surface hardening flame and induction hardening nitriding cyaniding carbonitriding carburizing etc Heat treatment on duplex stainless steel is to improve ductility toughness strength hardness and to relieve internal stress developed in the material. Here basically the experiment of hardness test impact test wear test and compression is done to get idea about heat treated duplex stainless ...

  10. The fracture mechanisms in duplex stainless steels at sub-zero temperatures

    OpenAIRE

    Pilhagen, Johan

    2013-01-01

    The aim of the thesis was to study the susceptibility for brittle failures and the fracture process of duplex stainless steels at sub-zero temperatures (°C). In the first part of the thesis plates of hot-rolled duplex stainless steel with various thicknesses were used to study the influence of delamination (also known as splits) on the fracture toughness. The methods used were impact and fracture toughness testing. Light optical microscopy and scanning electron microscopy were used to investi...

  11. Corrosion behaviour of new duplex stainless steel reinforcements embedded in chloride contaminated concrete

    OpenAIRE

    Medina Sanchez, Eduardo; Cobo Escamilla, Alfonso; Martínez Bastidas, David

    2011-01-01

    The use of reinforcing stainless steels (SS) in concrete have proved to be one of the most effective methods to guarantee the passivity of reinforced concrete structures exposed to chloride contaminated environment. The present research studies the corrosion behaviour of a new duplex SS reinforcements with low nickel content (LND) (more economicaly compatible) is compared with the conventional austenitic AISI 304 SS and duplex AISI 2304 SS. Corrosion behaviour of ribbed SS reinforcement...

  12. In-Band α-Duplex Scheme for Cellular Networks: A Stochastic Geometry Approach

    KAUST Repository

    Alammouri, Ahmad

    2016-07-13

    In-band full-duplex (FD) communications have been optimistically promoted to improve the spectrum utilization and efficiency. However, the penetration of FD communications to the cellular networks domain is challenging due to the imposed uplink/downlink interference. This paper presents a tractable framework, based on stochastic geometry, to study FD communications in cellular networks. Particularly, we assess the FD communications effect on the network performance and quantify the associated gains. The study proves the vulnerability of the uplink to the downlink interference and shows that FD rate gains harvested in the downlink (up to 97%) come at the expense of a significant degradation in the uplink rate (up to 94%). Therefore, we propose a novel fine-grained duplexing scheme, denoted as -duplex scheme, which allows a partial overlap between the uplink and the downlink frequency bands. We derive the required conditions to harvest rate gains from the -duplex scheme and show its superiority to both the FD and half-duplex (HD) schemes. In particular, we show that the -duplex scheme provides a simultaneous improvement of 28% for the downlink rate and 56% for the uplink rate. Finally, we show that the amount of the overlap can be optimized based on the network design objective.

  13. Is carotid duplex scanning sufficient as the sole investigation prior to carotid endarterectomy?

    Science.gov (United States)

    Collins, P; McKay, I; Rajagoplan, S; Bachoo, P; Robb, O; Brittenden, J

    2005-11-01

    Carotid endarterectomy (CEA) is the accepted treatment for certain patients who have had, or who are at risk of having, a stroke if they have a significant narrowing of the internal carotid artery. Rapid and accurate classification of the degree of stenosis is important as the benefit of surgery is highly dependent on this. The aim of this study was to assess whether the addition of angiography to duplex scanning resulted in a change in patient management in a unit where duplex scanning was used as the sole imaging investigation prior to CEA. The study population consisted of 64 patients with significant internal carotid artery stenosis on duplex scanning who were suitable for, and wished to be considered for, CEA. All patients underwent an angiogram. In this study 9 (14%) patients did not proceed to surgery on the basis of angiography and in a further 11 (17%) patients insufficient views of the distal vessel were obtained on duplex scanning. Three of these patients had extensive disease which excluded surgery. One patient experienced a transient ischaemic attack (TIA) at the time of angiography. In conclusion, this audit has highlighted the limitations in performing duplex scanning alone, and the costs that this can incur on the patient who may undergo an unnecessary operation. We cannot recommend duplex scanning as the sole investigation prior to CEA. There is need to evaluate the role of additional non-invasive carotid imaging such as magnetic resonance angiography or CT angiography in the assessment of these patients. PMID:16249605

  14. Effect of stress and strain on corrosion resistance of duplex stainless steel

    International Nuclear Information System (INIS)

    The interplay of the mechanical and electrochemical phenomena has been a subject of active research. In this paper, corrosion resistance studies about SAF2205 and SAF2507 duplex stainless steel were carried out under elastic stress applied (100 MPa, 300 MPa, 500 MPa) and pre-strain (5%, 10%, 15%) in 3.5% NaCl and 2 mol/L HCl solution. Potentiodynamic anodic polarization study revealed that corrosion resistance of SAF2205 duplex stainless steel decreases slightly with increasing of elastic stress level and noticeably with increasing of pre-strained level. Scanning electron microscopy investigation on surface of the electrochemical tested SAF2205 duplex stainless steel samples indicated that pitting is always located in austenite grains when pre-strain level is below 5% (including different elastic stress level) and located on intersection of ferrite and austenite grain when pre-strain level is above 5%. For SAF2507 duplex stainless steel, elastic stress and pre-strain have no effect on general corrosion and pitting corrosion. Based on deformation mechanism of duplex structure and the relationship of mechanical load and corrosion potential, Pitting corrosion behavior of duplex stainless steel is explained and discussed

  15. Corrosión por depósitos salinos de los aceros SA213-T22 y SA213-TP347H en presencia de una mezcla 80%V2O5-20%Na2SO4-20%Na2SO4

    Directory of Open Access Journals (Sweden)

    Romero, M. A.

    1998-02-01

    soporte de acero inoxidable. La atmósfera empleada fue aire; un termopar tipo K cubierto con tubo de cuarzo se introdujo en la sal fundida para controlar la temperatura del medio. En la mezcla fundida se evaluaron dos materiales: SA213-T22 y SA213-TP347H. Los valores de la velocidad de corrosión obtenidos empleando técnicas electroquímicas están entre de 0,58-7,14 mm/año (22,9-281 mpy. La velocidad de corrosión se incrementa con el tiempo.

  16. Tratamiento térmico superficial del acero U8 mediante láser de Nd:YAG

    Directory of Open Access Journals (Sweden)

    Ceballos-Ruano, J. S.

    1998-04-01

    Full Text Available The feasibility of laser surface hardening of U8 steel using a Nd:YAG continuous wave laser has been shown in this work. With the present trade literature reviewed and the experimental procedure we developed an outline of the process parameters determination methodology. It is found that in spite of the limitations and over-simplification of the experiment, an average explanation of the observed phenomena can be made to illustrate the parameters operation limits. The operation limits of the three principal parameters when hardening U8 steel are described, and it is shown that the depth of hardening is closed correlated with the incident power on the specimen (P, the diameter of the laser beam (d and the scan velocity by P√dν . The experiment was arranged statistically and the surface hardness of U8 steel can be increased to values above 500 HV in a deep of 0.15 mm.

    Utilizando un láser continuo de Nd: YAG se procedió al endurecimiento superficial del acero U8. Se expone la metodología empleada en el trabajo para la determinación de los parámetros del proceso sobre la base de la documentación existente y a las pruebas realizadas. Se logra explicar el fenómeno observado para ilustrar los limites de operación de los parámetros del proceso a pesar de las limitaciones y simplificaciones realizadas. Se muestra que en el proceso de endurecimiento térmico superficial del acero U8 la profundidad endurecida está estrechamente vinculada con la potencia incidente (P en la zona de interacción, el diámetro del haz (d y la velocidad de barrido del haz del láser (ν sobre la probeta por la relación P√dν. El experimento fue diseñado estadísticamente y permitió obtener durezas superiores a los 500 HV en espesores de 0,15 mm.

  17. Corrosión atmosférica del acero en interiores. Sus particularidades en el clima tropical de Cuba

    Directory of Open Access Journals (Sweden)

    Corvo, F.

    2008-04-01

    propuesta de Norma ISO para estas condiciones, exponiéndose la clasificación de esta agresividad para el acero, la cual se encuentra en los mayores niveles establecidos. Se propone un modelo del desarrollo de la corrosión con el tiempo de exposición, teniendo en consideración algunos contaminantes atmosféricos. El modelo se ajusta, aceptablemente, a los datos experimentales. Se observa que el polvo depositado es un factor importante en el proceso de corrosión del acero en interiores.

  18. Ultrasensitive Detection of RNA and DNA Viruses Simultaneously Using Duplex UNDP-PCR Assay.

    Directory of Open Access Journals (Sweden)

    Yong Huang

    Full Text Available Mixed infection of multiple viruses is common in modern intensive pig rearing. However, there are no methods available to detect DNA and RNA viruses in the same reaction system in preclinical level. In this study, we aimed to develop a duplex ultrasensitive nanoparticle DNA probe-based PCR assay (duplex UNDP-PCR that was able to simultaneously detect DNA and RNA viruses in the same reaction system. PCV2 and TGEV are selected as representatives of the two different types of viruses. PCV2 DNA and TGEV RNA were simultaneously released from the serum sample by boiling with lysis buffer, then magnetic beads and gold nanoparticles coated with single and/or duplex specific probes for TGEV and PCV2 were added to form a sandwich-like complex with nucleic acids released from viruses. After magnetic separation, DNA barcodes specific for PCV2 and TGEV were eluted using DTT and characterized by specific PCR assay for specific DNA barcodes subsequently. The duplex UNDP-PCR showed similar sensitivity as that of single UNDP-PCR and was able to detect 20 copies each of PCV2 and TGEV in the serum, showing approximately 250-fold more sensitivity than conventional duplex PCR/RT-PCR assays. No cross-reaction was observed with other viruses. The positive detection rate of single MMPs- and duplex MMPs-based duplex UNDP-PCR was identical, with 29.6% for PCV2, 9.3% for TGEV and 3.7% for PCV2 and TGEV mixed infection. This duplex UNDP-PCR assay could detect TGEV (RNA virus and PCV2 (DNA virus from large-scale serum samples simultaneously without the need for DNA/RNA extraction, purification and reverse transcription of RNA, and showed a significantly increased positive detection rate for PCV2 (29% and TGEV (11.7% preclinical infection than conventional duplex PCR/RT-PCR. Therefore, the established duplex UNDP-PCR is a rapid and economical detection method, exhibiting high sensitivity, specificity and reproducibility.

  19. Eddy current techniques for super duplex stainless steel characterization

    Science.gov (United States)

    Camerini, C.; Sacramento, R.; Areiza, M. C.; Rocha, A.; Santos, R.; Rebello, J. M.; Pereira, G.

    2015-08-01

    Super duplex stainless steel (SDSS) is a two-phase material where the microstructure consists of grains of ferrite (δ) and austenite (γ). SDSS exhibit an attractive combination of properties, such as: strength, toughness and stress corrosion cracking resistance. Nevertheless, SDSS attain these properties after a controlled solution heat treatment, leading to a similar volumetric fraction of δ and γ. Any further heat treatment, welding operation for example, can change the balance of the original phases, or may also lead to precipitation of a deleterious phase, such as sigma (σ). For these situations, the material corrosion resistance is severely impaired. In the present study, several SDSS samples with low σ phase content and non-balanced microstructure were intentionally obtained by thermally treating SDSS specimens. Electromagnetic techniques, conventional Eddy Current Testing (ECT) and Saturated Low Frequency Eddy Current (SLOFEC), were employed to characterize the SDSS samples. The results showed that ECT and SLOFEC are reliable techniques to evaluate σ phase presence in SDSS and can provide an estimation of the δ content.

  20. Kinetics of sigma phase formation in a Duplex Stainless Steel

    Directory of Open Access Journals (Sweden)

    Rodrigo Magnabosco

    2009-09-01

    Full Text Available This work determines the kinetics of sigma phase formation in UNS S31803 Duplex Stainless Steel (DSS, describing the phase transformations that occur in isothermal aging between 700 and 900 ºC for time periods up to 1032 hours, allowing the determination of the Time-Temperature-Precipitation (TTP diagram for sigma phase and proposing a model to predict the kinetics of sigma phase formation using a Johnson-Mehl-Avrami (JMA type expression. The higher kinetics of sigma phase formation occurs at 850 ºC. However, isothermal aging between 700 and 900 ºC for time periods up to 1032 hours are not sufficient to the establishment of thermodynamic equilibrium. Activation energy for both nucleation and growth of sigma phase is determined (185 kJ.mol-1 and its value is equivalent to the activation energy for Cr diffusion in ferrite, indicating that diffusion of Cr is probably the major thermally activated process involved in sigma phase formation. The determined JMA type expression presents good fit with experimental data between 700 and 850 ºC.

  1. Eddy current techniques for super duplex stainless steel characterization

    Energy Technology Data Exchange (ETDEWEB)

    Camerini, C., E-mail: cgcamerini@metalmat.ufrj.br [Laboratory of Non-Destructive Testing, Corrosion and Welding, Department of Metallurgical and Materials Engineering, Federal University of Rio de Janeiro (Brazil); Sacramento, R.; Areiza, M.C.; Rocha, A. [Laboratory of Non-Destructive Testing, Corrosion and Welding, Department of Metallurgical and Materials Engineering, Federal University of Rio de Janeiro (Brazil); Santos, R. [PETROBRAS R& D Center, Rio de Janeiro (Brazil); Rebello, J.M.; Pereira, G. [Laboratory of Non-Destructive Testing, Corrosion and Welding, Department of Metallurgical and Materials Engineering, Federal University of Rio de Janeiro (Brazil)

    2015-08-15

    Super duplex stainless steel (SDSS) is a two-phase material where the microstructure consists of grains of ferrite (δ) and austenite (γ). SDSS exhibit an attractive combination of properties, such as: strength, toughness and stress corrosion cracking resistance. Nevertheless, SDSS attain these properties after a controlled solution heat treatment, leading to a similar volumetric fraction of δ and γ. Any further heat treatment, welding operation for example, can change the balance of the original phases, or may also lead to precipitation of a deleterious phase, such as sigma (σ). For these situations, the material corrosion resistance is severely impaired. In the present study, several SDSS samples with low σ phase content and non-balanced microstructure were intentionally obtained by thermally treating SDSS specimens. Electromagnetic techniques, conventional Eddy Current Testing (ECT) and Saturated Low Frequency Eddy Current (SLOFEC), were employed to characterize the SDSS samples. The results showed that ECT and SLOFEC are reliable techniques to evaluate σ phase presence in SDSS and can provide an estimation of the δ content. - Highlights: • Sigma phase precipitation, even for low amounts, dramatically affects SDSS properties. • SDSS samples were thermally treated and carefully characterized by X-Ray Diffraction. • NDT techniques detected low amounts of sigma phase in SDSS microstructure.

  2. Beamforming Based Full-Duplex for Millimeter-Wave Communication

    Science.gov (United States)

    Liu, Xiao; Xiao, Zhenyu; Bai, Lin; Choi, Jinho; Xia, Pengfei; Xia, Xiang-Gen

    2016-01-01

    In this paper, we study beamforming based full-duplex (FD) systems in millimeter-wave (mmWave) communications. A joint transmission and reception (Tx/Rx) beamforming problem is formulated to maximize the achievable rate by mitigating self-interference (SI). Since the optimal solution is difficult to find due to the non-convexity of the objective function, suboptimal schemes are proposed in this paper. A low-complexity algorithm, which iteratively maximizes signal power while suppressing SI, is proposed and its convergence is proven. Moreover, two closed-form solutions, which do not require iterations, are also derived under minimum-mean-square-error (MMSE), zero-forcing (ZF), and maximum-ratio transmission (MRT) criteria. Performance evaluations show that the proposed iterative scheme converges fast (within only two iterations on average) and approaches an upper-bound performance, while the two closed-form solutions also achieve appealing performances, although there are noticeable differences from the upper bound depending on channel conditions. Interestingly, these three schemes show different robustness against the geometry of Tx/Rx antenna arrays and channel estimation errors. PMID:27455256

  3. Transperitoneal laparoscopic heminephrectomy in duplex kidneys: a one centre experience

    Directory of Open Access Journals (Sweden)

    Mehdi Abedinzadeh

    2012-02-01

    Full Text Available Purpose: The standard treatment for a duplex kidney with poorly functioning upper pole moiety is ipsilateral upper pole heminephrectomy. This procedure is usually performed by open surgery, but with recent developments in techniques of uro-laparoscopy, it can be done with it, safely. In this study we evaluated the results and safety of laparoscopic heminephrectomy in our consecutive cases.Materials and Methods: From February 2001 to May 2007 fourteen unilateral laparoscopic heminephrectomy were performed in our center. Patients' characteristics, presenting symptoms, operative time, and blood loss, early and late complications were all collected retrospectively. Using pre-operative ultrasonography, intravenous pyelography (IVP and CT scanning, unilateral upper pole hydronephrosis was detected in all cases. By DMSA isotope scan hypofunctioning of ipsilateral moieties was detected in all cases.Results: Mean operative time was 203±80 minutes. No major intra-operative or early complications were identified. Mean hospital stay was 4.1 days. On mean follow-up of 32 months no disturbing symptoms or episodes of urinary tract infections (UTIs were detected. Atrophic kidney was detected in one case in post-operative IVP.Conclusion: Laparoscopic heminephrectomy is a valuable minimal invasive procedure that can be performed safely in experienced hands without any important complication. Perfect renal pedicles vascular system manipulation is important for the preservation of renal function post-operatively.

  4. Beamforming Based Full-Duplex for Millimeter-Wave Communication.

    Science.gov (United States)

    Liu, Xiao; Xiao, Zhenyu; Bai, Lin; Choi, Jinho; Xia, Pengfei; Xia, Xiang-Gen

    2016-01-01

    In this paper, we study beamforming based full-duplex (FD) systems in millimeter-wave (mmWave) communications. A joint transmission and reception (Tx/Rx) beamforming problem is formulated to maximize the achievable rate by mitigating self-interference (SI). Since the optimal solution is difficult to find due to the non-convexity of the objective function, suboptimal schemes are proposed in this paper. A low-complexity algorithm, which iteratively maximizes signal power while suppressing SI, is proposed and its convergence is proven. Moreover, two closed-form solutions, which do not require iterations, are also derived under minimum-mean-square-error (MMSE), zero-forcing (ZF), and maximum-ratio transmission (MRT) criteria. Performance evaluations show that the proposed iterative scheme converges fast (within only two iterations on average) and approaches an upper-bound performance, while the two closed-form solutions also achieve appealing performances, although there are noticeable differences from the upper bound depending on channel conditions. Interestingly, these three schemes show different robustness against the geometry of Tx/Rx antenna arrays and channel estimation errors.

  5. Beamforming Based Full-Duplex for Millimeter-Wave Communication.

    Science.gov (United States)

    Liu, Xiao; Xiao, Zhenyu; Bai, Lin; Choi, Jinho; Xia, Pengfei; Xia, Xiang-Gen

    2016-01-01

    In this paper, we study beamforming based full-duplex (FD) systems in millimeter-wave (mmWave) communications. A joint transmission and reception (Tx/Rx) beamforming problem is formulated to maximize the achievable rate by mitigating self-interference (SI). Since the optimal solution is difficult to find due to the non-convexity of the objective function, suboptimal schemes are proposed in this paper. A low-complexity algorithm, which iteratively maximizes signal power while suppressing SI, is proposed and its convergence is proven. Moreover, two closed-form solutions, which do not require iterations, are also derived under minimum-mean-square-error (MMSE), zero-forcing (ZF), and maximum-ratio transmission (MRT) criteria. Performance evaluations show that the proposed iterative scheme converges fast (within only two iterations on average) and approaches an upper-bound performance, while the two closed-form solutions also achieve appealing performances, although there are noticeable differences from the upper bound depending on channel conditions. Interestingly, these three schemes show different robustness against the geometry of Tx/Rx antenna arrays and channel estimation errors. PMID:27455256

  6. Aging of cast duplex stainless steels in LWR systems

    International Nuclear Information System (INIS)

    A program is being conducted to investigate the significance of in-service embrittlement of cast duplex stainless steels under light-water reactor operating conditions. The existing data are evaluated to determine the expected embrittlement of cast components during the operating lifetime of reactors and to define the objectives and scope of the investigation. This presentation describes the status of the program. Data for the metallurgical characterization of the various cast stainless steels used in the investigation are presented. Charpy impact tests on short-term aged material indicate that CF-3 stainless steels are less susceptible to embrittlement than CF-8 or CF-8M stainless steels. Microstructural characterization of cast stainless steels that were obtained from Georg Fischer Co. and aged for up to 70,000 h at 300, 350, and 4000C reveals the formation of four different types of precipitates that are not α'. Embrittlement of the ferrite phase is primarily due to pinning of the dislocations by two of these precipitates, designated as Type M and Type X. The ferrite phase is embrittled after approx. 8 y at 3000C and shows cleavage fracture. Examination of the fracture surfaces of the impact-test specimens indicates that the toughness of the long-term aged material is determined by the austenite phase. 8 figures, 3 tables

  7. Fracture toughness of a welded super duplex stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Pilhagen, Johan, E-mail: pilhagen@kth.se [Department of Materials Science and Engineering, KTH Royal Institute of Technology, Stockholm (Sweden); Sieurin, Henrik [Scania CV AB, Södertälje (Sweden); Sandström, Rolf [Department of Materials Science and Engineering, KTH Royal Institute of Technology, Stockholm (Sweden)

    2014-06-01

    Fracture toughness testing was conducted on standard single-edge notched bend bar specimens of base and weld metal. The material was the SAF 2906 super duplex stainless steel. The aim was to evaluate the susceptibility for brittle failure at sub-zero temperatures for the base and weld metal. The base metal was tested between −103 and −60 °C and was evaluated according to the crack-tip opening displacement method. The fracture event at and below −80 °C can be described as ductile until critical cleavage initiation occurs, which caused unstable failure of the specimen. The welding method used was submerged arc welding with a 7 wt% nickel filler metal. The welded specimens were post-weld heat treated (PWHT) at 1100 °C for 20 min and then quenched. Energy-dispersive X-ray spectroscopy analysis showed that during PWHT substitutional element partitioning occurred which resulted in decreased nickel content in the ferrite. The PWHT weld metal specimens were tested at −72 °C. The fracture sequence was critical cleavage fracture initiation after minor crack-tip blunting and ductile fracture.

  8. Fracture toughness of a welded super duplex stainless steel

    International Nuclear Information System (INIS)

    Fracture toughness testing was conducted on standard single-edge notched bend bar specimens of base and weld metal. The material was the SAF 2906 super duplex stainless steel. The aim was to evaluate the susceptibility for brittle failure at sub-zero temperatures for the base and weld metal. The base metal was tested between −103 and −60 °C and was evaluated according to the crack-tip opening displacement method. The fracture event at and below −80 °C can be described as ductile until critical cleavage initiation occurs, which caused unstable failure of the specimen. The welding method used was submerged arc welding with a 7 wt% nickel filler metal. The welded specimens were post-weld heat treated (PWHT) at 1100 °C for 20 min and then quenched. Energy-dispersive X-ray spectroscopy analysis showed that during PWHT substitutional element partitioning occurred which resulted in decreased nickel content in the ferrite. The PWHT weld metal specimens were tested at −72 °C. The fracture sequence was critical cleavage fracture initiation after minor crack-tip blunting and ductile fracture

  9. Beamforming Based Full-Duplex for Millimeter-Wave Communication

    Directory of Open Access Journals (Sweden)

    Xiao Liu

    2016-07-01

    Full Text Available In this paper, we study beamforming based full-duplex (FD systems in millimeter-wave (mmWave communications. A joint transmission and reception (Tx/Rx beamforming problem is formulated to maximize the achievable rate by mitigating self-interference (SI. Since the optimal solution is difficult to find due to the non-convexity of the objective function, suboptimal schemes are proposed in this paper. A low-complexity algorithm, which iteratively maximizes signal power while suppressing SI, is proposed and its convergence is proven. Moreover, two closed-form solutions, which do not require iterations, are also derived under minimum-mean-square-error (MMSE, zero-forcing (ZF, and maximum-ratio transmission (MRT criteria. Performance evaluations show that the proposed iterative scheme converges fast (within only two iterations on average and approaches an upper-bound performance, while the two closed-form solutions also achieve appealing performances, although there are noticeable differences from the upper bound depending on channel conditions. Interestingly, these three schemes show different robustness against the geometry of Tx/Rx antenna arrays and channel estimation errors.

  10. Hot Forging of Nitrogen Alloyed Duplex Stainless Steels

    Institute of Scientific and Technical Information of China (English)

    P.Chandramohan; S.S. Mohamed Nazirudeen; S.S. Ramakrishnan

    2007-01-01

    Duplex stainless steels are gaining global importance because of the need for a high strength corrosion resistant material. Three compositions of this group were selected with three different nitrogen contents viz, 0.15 wt pct (alloy 1), 0.23 wt pct (alloy 2) and 0.32 wt pct (alloy 3). The steels were melted in a high frequency induction furnace and hot forged to various reductions from 16% to 62%. In this work, the effect of hot forging on the ferrite content, hardness, yield strength, impact strength and grain orientation (texture) were studied. Fracture analysis on all the forged specimens using SEM reveals that a size reduction of 48% results in maximum ductility and impact strength as well as minimal ferrite content and grain size. Thus the mechanical properties are found to have a direct correlation to ferrite content and grain size. The highest impact strength was observed in specimens with the smallest grain size, which was observed in specimens forged to 48% reduction in size.

  11. Hepatic venous pressure gradients measured by duplex ultrasound

    International Nuclear Information System (INIS)

    AIMS: The hepatic venous pressure gradient is a major prognostic factor in portal hypertension but its measurement is complex and requires invasive angiography. This study investigated the relationship between the hepatic venous pressure gradient and a number of Doppler measurements, including the arterial acceleration index. METHOD: We measured the hepatic venous pressure gradient in 50 fasting patients at hepatic venography. Immediately afterwards, a duplex sonographic examination of the liver was performed at which multiple measurements and indices of the venous and arterial hepatic vasculature were made. RESULTS: Hepatic arterial acceleration was correlated directly with the hepatic venous pressure gradient (r = 0.83, P -2 provided a positive predictive value of 95%, a sensitivity of 65% and a specificity of 95% for detecting patients with severe portal hypertension (hepatic venous pressure gradient > 12 mmHg). A correlation between the hepatic venous pressure gradient and the congestion index of the portal vein velocity (r = 0.45,P = 0.01) and portal vein velocity (r = 0.40,P = 0.044), was also noted. CONCLUSION: Measuring the hepatic arterial acceleration index may help in the non-invasive evaluation of portal hypertension. Tasu, J.-P. et al. (2002)

  12. Potential of duplex fuel in prebreeder, breeder, and power reactor designs: tests and analyses (AWBA Development Program)

    International Nuclear Information System (INIS)

    Dual region fuel pellets, called duplex pellets, are comprised of an outer annular region of relatively high uranium fuel enrichment and a center pellet of fertile material with no enrichment. UO2 and ThO2 are the fissile and fertile materials of interest. Both prebreeders and breeders are discussed as are the performance advantages of duplex pellets over solid pellets in these two pressurized water reactor types. Advantages of duplex pellets for commercial reactor fuel rods are also discussed. Both irradiation test data and analytical results are used in comparisons. Manufacturing of duplex fuel is discussed

  13. Compositionally modulated CGDS + MAO duplex coatings for corrosion protection of AZ91 magnesium alloy

    International Nuclear Information System (INIS)

    Highlights: •First of its kind attempt was made to duplex radically different viz., CGDS-MAO techniques. •AZ91 Mg alloy having an Al top coat was subjected to MAO process for obtaining duplex coatings. •Duplex coatings exhibit compositionally graded phase distribution across their thickness. •Corrosion current density is reduced by 1 to 2 orders of magnitude compared to the bare substrate. •Polarization resistance of duplex coating is about 14 times higher than the plain MAO coating. -- Abstract: The micro arc oxidation (MAO) technology is being increasingly recognized as a non-traditional and novel approach for enhancing the corrosion and wear protection of Al, Ti, Mg and their alloys. Since the MAO coatings formed on Mg in general tend to be porous, several methods of duplexing the MAO with other conventional and non-conventional techniques is gaining popularity for enhancing the corrosion protection of Mg and its alloys. The Cold Gas Dynamic Spray (CGDS) technique was employed for the first time as a pre-MAO treatment to deposit Al on AZ91 Mg alloy. The Mg alloy having an Al top coat was subsequently subjected to MAO process for obtaining duplex coating. The coating morphology was studied by employing scanning electron microscopy (SEM), the elemental concentration and their distribution across the coating thickness was evaluated using energy dispersive spectroscopy (EDS) coupled with SEM. The coating is not only duplex in terms of combining two diverse and altogether different methods namely CGDS and MAO, but also by virtue of the elemental distribution across the coating thickness exhibiting a compositionally graded nature. The potentiodynamic polarization studies conducted in 3.5 wt.% NaCl solution revealed that the overall corrosion current density is reduced by 1 to 2 orders of magnitude compared to the bare magnesium substrate

  14. Effect of microstructure on impact toughness of duplex and superduplex stainless steels

    Directory of Open Access Journals (Sweden)

    S. Topolska

    2009-10-01

    Full Text Available Purpose: of this paper is to study the effect of heat treatments and resulting changes in microstructure on mechanical properties, mainly impact toughness, of commercial 2205 duplex stainless steel and higher alloy superduplex 2507 grade.Design/methodology/approach: Both steels were submitted to ageing treatments in the temperature range of 500-900 °C with exposure time periods 6 minutes, 1 hour and 10 hours. Light microscope examinations, hardness measurements and impact toughness tests were performed in order to reveal microstructure and changes in mechanical properties.Findings: Obtained results confirm that high temperature service of duplex stainless steels should be avoided. Precipitations of secondary phases (mainly σ phase strongly deteriorate mechanical properties of steels but some amounts of these phases could be acceptable in the microstructure depending upon the application of the steel.Research limitations/implications: Presence of secondary phases in duplex stainless steel microstructure can be very harmful for its corrosion resistance. This phenomenon is not considered in this study.Practical implications: The accidents during exploitation and errors in processing of duplex stainless steels can result in undesired temperature growth over 500°C. Such events brings question whether the steel can be still exploited or not. The aim of present study is to reveal the effect of thermal cycles on structural changes and mechanical properties of duplex stainless steel and establish the highest acceptable time-temperature conditions for safe operation of the steel.Originality/value: Information available in literature does not clearly indicate what amount of secondary phases existing in duplex stainless steel microstructure can be acceptable. The current study shows that duplex 2205 steel affected by thermal cycles and containing about 10% of sigma phase still exhibit acceptable mechanical properties.

  15. Effect of Deleterious Phases on Corrosion Resistance of Duplex Stainless Steel (2205

    Directory of Open Access Journals (Sweden)

    AbdulKadar M. Godil

    2013-07-01

    Full Text Available Duplex stainless steel is a Ferritic(BCC-Austenitic(FCC steel, covers the advantages of both Austenitic and Ferritic Stainless steels. They having good mechanical and corrosion resistance properties are widely used in many industries like chemical plants, refineries for critical equipments such as pressure vessels, heatexchangers, water heaters. Major problem occurs with duplex steels when they are worked or heated above about temperature of 280°C. Detrimental phases like Sigma, Chi, Laves and Alpha prime form when the Duplex steels are treated above this temperature and they retard the properties of Duplex stainless steels. They also cause embrittlement above temperature of 475°C called “475°C embrittlement”. During welding of duplex steels, Secondary austenite also forms, which is also one of the harmful phases in duplex steels. Among all of these phases, Sigma (σ is extremely harmful to the corrosion resistance of steel. Due to these limitations duplexgrades are not used above certain temperature ranges. In this experimental work a plate of duplex grade 2205 in hot worked condition was procured from TCR Advanced Engineering Pvt. Ltd., GIDC, Vadodara. Initially chemical composition of the plate was checked with emission spectrometer, tensile test and hardness tests werecarried out for comparing with the standard data. As there was no Sigma phase detected when tested with ASTM 930 in the received sample, Sigma phase was intentionally produced by giving heat treatment in the range of 700-850°C. Sigma phases were quantified with ASTM 930 practice A, by electrolytic etching with 40% NaOH. The effect of Sigma phase on corrosion resistance was measured by ASTM G48. The pitting corrosion resistance was evaluated in terms of average pit depth and overall corrosion rate.

  16. Síntesis y caracterización de recubrimientos de tin, tic y ticn sobre acero aisi 4340

    Directory of Open Access Journals (Sweden)

    Héctor E. Jaramillo Suárez

    2004-01-01

    Full Text Available En este trabajo se crecieron películas de TiN, TiC y TiCN sobre aceros AISI 4340, con el objeto de comparar los resultados estructurales, morfológicos y mecánicos al crecerlos sobre un mismo substrato. Se utilizó un láser pulsado Nd: YAG con energía de 500mJ, longitud de onda de 1064 nm y tasa de repetición de 10 Hz. Mediante microscopia de Fuerza Atómica AFM, se observó que los recubrimientos presentan alta homogeneidad y tamaño de grano fino. Por Microscopía Electrónica de Barrido se determinó presencia de microgotas en los recubrimientos. Se aplicó prueba de tensión para determinar la adhesión de las películas; aplicando cargas máximas de 60 Kgf, los recubrimientos no mostraron señales de desprendimiento del substrato. A todos los recubrimientos se les sometió a prueba de dureza Rockwell C, con el fin de determinar la resistencia a la fractura, indicando que estos recubrimientos son aptos para diferentes aplicaciones en la industria.

  17. Comparación de la corrosividad atmosférica del acero al carbono en Colombia y Cuba

    Directory of Open Access Journals (Sweden)

    Delgado Lastra, Juan

    2001-06-01

    Full Text Available Samples of structural carbon steel were exposed to the atmosphere in a number of sites in Colombia and Cuba for periods of 2, 3, 6, 12 and 24 months. Corrosion rate was determined by mass loss measurements, and cause-effect relationship to exposure time and pollutants (deposited chloride and sulfur oxides were calculated. Analysis let to adjust models by the multiple regression method. Also, comparison of atmospheric corrosion rates between Colombia and Cuba were done using covariance analysis.

    Se expusieron a la atmósfera probetas de aceros estructurales de bajo contenido de carbono, en varios sitios de Colombia y Cuba, que se retiraron a intervalos de 2, 3, 6, 12, 18 y 24 meses. Se determinó la corrosión por pérdida de masa y se buscaron relaciones de causalidad con el tiempo de exposición y las cantidades de cloruro y óxidos de azufre depositados. El análisis permitió ajustar modelos de regresión múltiple y también, a través de variables dicótomas, realizar la comparación de la corrosión atmosférica entre Colombia y Cuba, mediante análisis de covarianza.

  18. Estudio y restauración del sable en acero de Damasco de Mehemet Alí

    Directory of Open Access Journals (Sweden)

    Moyano, A.

    2001-12-01

    Full Text Available The present manuscript is about study and restoration of a sabre, which belonged to Mehemet Ali. The work has been adopted a scientific and a historical approach. Scientific one has revealed the secrets of Damascus steel, so admired by the power of their swords as well as by the beauty of their beautiful markings, and damascene works. Techniques such as Optical Microscopy, Scanning Electron Microscopy (SEM, ICP Mass and Ultrasonic have been used in order to achieve this scientific research. Historical approach has carried out a work about the contribution of Mehemet Ali, especially to Egypt in the 18th and 19th centuries.

    El presente artículo trata sobre el estudio y restauración del sable perteneciente a Mehemet Alí. Este trabajo se ha realizado bajo dos enfoques diferentes: científico e histórico. El primero, en donde se han desvelado los secretos internos de este maravilloso y genuino acero de Damasco, tan admirado por el poder de sus espadas como por la belleza de las aguas y damasquinados presentes en las mismas. Para ello nos hemos ayudado de técnicas como la Microscopía Óptica, Microscopía Electrónica de Barrido (MEB, ICP Masas y Ultrasonidos. Bajo el segundo enfoque, se ha realizado un seguimiento histórico de Mehemet Alí, y su contribución al Egipto de los siglos XVIII y XIX.

  19. Estudio comparativo de la normativa existente para la evalución del grado y velocidad de corrosión en aceros para la construcción

    OpenAIRE

    Querol Martí, Marc

    2011-01-01

    La corrosión es una reacción química entre un material y su entorno que provoca su deterioro y el de sus propiedades. Por este motivo la evaluación del grado y la velocidad de corrosión es un aspecto de vital importancia para determinar la vida útil de los aceros en construcción, así como para el establecimiento de las condiciones de uso de aceros y de elementos constructivos compuestos en los que participan materiales mecánicos. Existen varios métodos normativos para la deter...

  20. Estudio de la Cinética de Precipitación Inducida Mediante la Determinación de los Diagramas Precipitación-Tiempo-Temperatura (PTT) en Aceros Microaleados

    OpenAIRE

    Medina, Sebastián F.

    1995-01-01

    [ES]Se describe un método desarrollado en el CENIM que permite estudiar la cinética de la precipitación inducida por la deformación en aceros microaleados. Mediante ensayos de torsión, se ha determinado la fracción recristalizada estáticamente de tres aceros microaleados con niobio, vanadio y titanio, respectivamente, a diferentes temperaturas y deformaciones. Cuando la precipitación comienza, la fracción recristalizada se desvía de la ecuación de Avrami y esto permite conocer el instante en ...

  1. Empleo de la cáscara de arroz en la fundición de piezas de acero al carbono//Using of rice husk in the carbon steel casting parts process

    OpenAIRE

    Juan Carlos Cruz-Pérez; Jesús Eduardo González-Ruiz; Lorenzo Perdomo-González; Pantaleón Rodríguez-González

    2012-01-01

    Los materiales auxiliares desempeñan un papel importante en el aumento de la eficiencia tecnológica del proceso de fundición de piezas de acero al carbono. En este artículo se exponen los primeros resultados del empleo de la cáscara de arroz como material termoaislante en la obtención de piezas fundidas de acero al carbono. En los experimentos se evaluó la influencia  de seis combinaciones de las variables espesor de pared del casquillo y capa de cobertura. En la confección de los casquillos ...

  2. Mechanism of hairpin-duplex conversion for the HIV-1 dimerization initiation site.

    Science.gov (United States)

    Bernacchi, Serena; Ennifar, Eric; Tóth, Katalin; Walter, Philippe; Langowski, Jörg; Dumas, Philippe

    2005-12-01

    We have used the dimerization initiation site of HIV-1 genomic RNA as a model to investigate hairpin-duplex interconversion with a combination of fluorescence, UV melting, gel electrophoresis, and x-ray crystallographic techniques. Fluorescence studies with molecular beacons and crystallization experiments with 23-nucleotide dimerization initiation site fragments showed that the ratio of hairpin to duplex formed after annealing in water essentially depends on RNA concentration and not on cooling kinetics. With natural sequences allowing to form the most stable duplex, and thus also the loop-loop complex (or "kissing complex"), concentrations as low as 3 mum in strands are necessary to obtain a majority of the hairpin form. With a mutated sequence preventing kissing complex formation, a majority of hairpins was even obtained at 80 mum in strands. However, this did not prevent an efficient conversion from hairpin to duplex in the presence of salts. Kinetic considerations are in favor of duplex formation from intermediates involving hairpins engaged in cruciform dimers rather than from free strands. The very first step of formation of such a cruciform intermediate could be trapped in a crystal structure. This mechanism might be significant for the dynamics of small RNAs beyond the strict field of HIV-1. PMID:16169845

  3. Recognition of base pair inversions in duplex by chimeric (alpha,beta) triplex-forming oligonucleotides.

    Science.gov (United States)

    Timofeev, Edward N; Goryaeva, Baira V; Florentiev, Vladimir L

    2006-10-01

    DNA recognition by triplex-forming oligonucleotides (TFOs) is usually limited by homopurine-homopyrimidine sequence in duplexes. Modifications of the third strand may overcome this limitation. Chimeric alpha-beta TFOs are expected to form triplex DNA upon binding to non-regular sequence duplexes. In the present study we describe binding properties of chimeric alpha-beta oligodeoxynucleotides in the respect to short DNA duplexes with one, three, and five base pair inversions. Non-natural chimeric TFO's contained alpha-thymidine residues inside (GT) or (GA) core sequences. Modified residues were addressed to AT/TA inversions in duplexes. It was found in the non-denaturing gel-electrophoresis experiments that single or five adjacent base pair inversions in duplexes may be recognized by chimeric alpha-beta TFO's at 10 degrees C and pH 7.8. Three dispersed base pair inversions in the double stranded DNA prevented triplex formation by either (GT) or (GA) chimeras. Estimation of thermal stability of chimeric alpha-beta triplexes showed decrease in T(m) values as compared with unmodified complexes. PMID:16928141

  4. Comparison of nanostructure and duplex PVD coatings deposited onto hot work tool steel substrate

    Directory of Open Access Journals (Sweden)

    L.A. Dobrzański

    2010-07-01

    Full Text Available Purpose: The aim of the paper was the investigation of the structure and the mechanical properties of the duplex TiN/(Ti,AlN coating and the nanostructure TiAlN coating deposited by PVD technology onto hot work tool steel substrate.Design/methodology/approach: The surfaces’ topography and the structure of the PVD coatings were observed on the scanning electron microscopy. Diffraction and thin film structure were tested with the use of the transmission electron microscopy. The microhardness tests were made on the dynamic ultra-microhardness tester. Tests of the coatings’ adhesion to the substrate material were made using the scratch test.Findings: The duplex and nanostructure coatings demonstrate high hardness and very good adhesion. The critical load LC2 (coating delamination lies within the range 80-85 N, depending on the coating type. It was found out that the duplex TiN/(Ti,AlN coating show the best adhesion to the substrate material.Practical implications: The very good mechanical properties of the duplex and nanostructure PVD coatings make them suitable in industrial applications.Originality/value: The investigation results will provide useful information to applying the duplex and nanostructure PVD coatings for the improvement of mechanical properties of the hot work tool steels. The very hard and antiwear PVD coatings deposited onto hot work tool steel substrates are needed.

  5. Characterization of duplex stainless steel weld metals obtained by hybrid plasma-gas metal arc welding

    Directory of Open Access Journals (Sweden)

    Koray Yurtisik

    2013-09-01

    Full Text Available Despite its high efficiency, autogenous keyhole welding is not well-accepted for duplex stainless steels because it causes excessive ferrite in as-welded duplex microstructure, which leads to a degradation in toughness and corrosion properties of the material. Combining the deep penetration characteristics of plasma arc welding in keyhole mode and metal deposition capability of gas metal arc welding, hybrid plasma - gas metal arc welding process has considered for providing a proper duplex microstructure without compromising the welding efficiency. 11.1 mm-thick standard duplex stainless steel plates were joined in a single-pass using this novel technique. Same plates were also subjected to conventional gas metal arc and plasma arc welding processes, providing benchmarks for the investigation of the weldability of the material. In the first place, the hybrid welding process enabled us to achieve less heat input compared to gas metal arc welding. Consequently, the precipitation of secondary phases, which are known to be detrimental to the toughness and corrosion resistance of duplex stainless steels, was significantly suppressed in both fusion and heat affected zones. Secondly, contrary to other keyhole techniques, proper cooling time and weld metal chemistry were achieved during the process, facilitating sufficient reconstructive transformation of austenite in the ferrite phase.

  6. Heat treatment temperature influence on ASTM A890 GR 6A super duplex stainless steel microstructure

    International Nuclear Information System (INIS)

    Duplex and super duplex stainless steels are ferrous alloys with up to 26% chromium, 8% nickel, 5% molybdenum and 0.3% nitrogen, which are largely used in applications in media containing ions from the halogen family, mainly the chloride ion (Cl-). The emergence of this material aimed at substituting Copper-Nickel alloys (Cupro-Nickel) that despite presenting good corrosion resistance, has mechanical properties quite inferior to steel properties. The metallurgy of duplex and super duplex stainless steel is complex due to high sensitiveness to sigma phase precipitation that becomes apparent, due to the temperatures they are exposed on cooling from solidification as well as from heat treatment processes. The objective of this study was to verify the influence of heat treating temperatures on the microstructure and hardness of ASTM A890/A890M Gr 6A super duplex stainless steel type. Microstructure control is of extreme importance for castings, as the chemical composition and cooling during solidification inevitably provide conditions for precipitation of sigma phase. Higher hardness in these materials is directly associated to high sigma phase concentration in the microstructure, precipitated in the ferrite/austenite interface. While heat treatment temperature during solution treatment increases, the sigma phase content in the microstructure decreases and consequently, the material hardness diminishes. When the sigma phase was completely dissolved by the heat treatment, the material hardness was influenced only due to ferrite and austenite contents in the microstructure

  7. Localization of duplex thrust-ramps by buckling: analog and numerical modelling

    Science.gov (United States)

    Liu, Shumin; Dixon, John M.

    1995-06-01

    Duplex structures in natural fold-thrust belts occur over a wide range of geometric scales. Duplex thrust ramps exhibit a regular spacing linearly related to the thickness of strata involved in the duplex. We suggest that buckling instability in layered systems can produce local stress concentrations which localize thrust ramps with regular spacing. This mechanism is demonstrated through analog (centrifuge) and numerical (finite element) modelling. Centrifuge models containing finely-laminated multilayers composed of plasticine and silicone putty (simulating rocks such as limestone and shale) are compressed from one edge; folds propagate from hinterland to foreland. As shortening continues, the lowest competent unit is thrust into a blind duplex structure by breakthrusting. The duplex develops by serial nucleation of faults from hinterland to foreland; the ramp locations are inherited from the initial buckling instability. Finite-element models based on the analog models and their natural prototypes demonstrate that stress concentrations develop in fore-limbs of anticlines within competent stratigraphie units. Models containing thrust discontinuities (at sites of calculated stress concentration) display additional stress concentrations in the forelimbs of unfaulted folds closer to the foreland. The locus of stress concentration thus propagates towards the foreland, consistent with foreland thrust propagation in nature. The location and regular spacing of ramps are inherited from early (possibly even incipient) buckle folds.

  8. Producción de aceros al carbono en hornos de arco eléctrico en condiciones de mineral de manganeso.

    Directory of Open Access Journals (Sweden)

    E. E. Navas Medina

    2007-05-01

    Full Text Available El presente trabajo constituye una segunda etapa de investigación relacionada con la producción de acero en hornos de arco eléctrico con revestimiento básico en condiciones de utilización de mineral de manganeso como sustituto del ferro-manganeso. En la investigación se caracteriza el acero producido utilizando el mineral de manganeso en dos variantes tecnológicas diferentes y se determinan parámetros importantes, tales como la estructura del acero obtenido, la influencia de la composición química y la temperatura en la reducción del Mn. Adicionalmente, se determina la composición química de la escoria, su basicidad e influencia en el aprovechamiento del Mn del mineral, así como, lo que significa la sustitución del FeMn en la problemática medioambiental. This present work constitutes the second stage of investigation in relation with the steel production by means of electric arc furnaces in the condition of use of manganese ores as a substitute of the ferromanganese. In the investigation, the steel manufactured is analyzed the manganese ore in two different technological variants and some important parameters are determined such as: the chemical composition's structure of the steel, the influence of temperature in the reduction of Mn. Moreover, an analysis of the chemical composition of the slag and the influence in the environmental is realized.

  9. Origen y endurecimiento por dispersión de carbonitruros en un acero comercial microaleado al niobio y laminado en caliente

    Directory of Open Access Journals (Sweden)

    Valencia, E.

    1998-12-01

    Full Text Available Throughout this work, a study on niobium carbonitrides formation and its hardening effect in a commercial hot strip microalloyed steel is presented. Optic and electron micrographs were obtained while mechanical tests and indirect models allow to predict samples yield strength, taking into account the steel composition and its structural characteristics. The results showed an extended precipitation on austenite boundary cells during the last thermomechanical processing stages, which probably achieved a considerable contribution to the hardening by dispersion in the material studied. Otherwise, no evidence of precipitation in ferrite by means of transmission electron microscopy (TEM was observed. A poor interphase precipitation was detected in about 10 per cent of the total observed zones with no appreciated contribution to the steel hardness.

    Se presenta un estudio sobre el origen de los carbonitruros de niobio y su efecto en el endurecimiento de un acero comercial microaleado y laminado en caliente. Para tal fin se utilizaron micrografías ópticas y electrónicas; así como también ensayos mecánicos y modelos indirectos que permitieron predecir el límite elástico teniendo en cuenta la composición del acero y sus características estructurales. Los resultados mostraron una extensa precipitación en la austenita durante las últimas fases del proceso de laminación siendo ésta responsable del principal aporte al endurecimiento por dispersión en el material investigado. No hubo evidencias de precipitación en la ferrita por observaciones al microscopio electrónico de transmisión y sólo una escasa precipitación interfásica fue detectada en un 10 % de las zonas observadas sin una apreciable contribución al endurecimiento del acero.

  10. Study on thermal aging mechanism of cast duplex stainless steel

    International Nuclear Information System (INIS)

    Cast duplex stainless steel is used for reactor coolant piping in pressurized water reactors. However, its toughness is reduced by aging after long time operation. R and D on non-destructive techniques for evaluating the level of aging during in-service inspections has been carried out. A practical technique to evaluate accuracy has not, however, been developed yet. This is because the relationship between microstructural changes and mechanical property changes has not been clearly identified. The aim of this study is to clarify the relationship between the microstructural and mechanical property changes due to aging by examining the process of generation of precipitates. The specimens used in this study were SCS 14 A centrifuged cast stainless steel with three different ferrite content types of 8, 15 and 23%. They were aged at temperatures of 350degC and 400degC for up to 10,000 hours. The mechanical properties were investigated with Charpy impact testing and Vickers hardness testing, and microstructural changes studied with a transmission electron microscope, atom probe analysis and Moessbauer spectroscopy. As a result, the Charpy impact value of the specimen with larger ferrite content decreased the most. The hardness of the austenite phase remained almost unchanged while the hardness of the ferrite phase significantly increased. The ferrite hardness increase and the phase decomposition rate were almost the same among the three specimens with different ferrite contents. G phase precipitation was observed for the ferrite materials of 15% and 23% after the long period of thermal aging. In conclusion, the thermal aging degradation can be evaluated by detecting the ferrite phase decomposition rate, the ferrite content and the G phase precipitation. (author)

  11. Full-Duplex Digital Communication on a Single Laser Beam

    Science.gov (United States)

    Hazzard, D. A.; MacCannell, J. A.; Lee, G.; Selves, E. R.; Moore, D.; Payne, J. A.; Garrett, C. D.; Dahlstrom, N.; Shay, T. M.

    2006-01-01

    A proposed free-space optical communication system would operate in a full-duplex mode, using a single constant-power laser beam for transmission and reception of binary signals at both ends of the free-space optical path. The system was conceived for two-way data communication between a ground station and a spacecraft in a low orbit around the Earth. It has been estimated that in this application, a data rate of 10 kb/s could be achieved at a ground-station-to-spacecraft distance of 320 km, using a laser power of only 100 mW. The basic system concept is also applicable to terrestrial free-space optical communications. The system (see figure) would include a diode laser at one end of the link (originally, the ground station) and a liquid-crystal- based retroreflecting modulator at the other end of the link (originally, the spacecraft). At the laser end, the beam to be transmitted would be made to pass through a quarter-wave plate, which would convert its linear polarization to right circular polarization. For transmission of data from the laser end to the retroreflector end, the laser beam would be modulated with subcarrier phase-shift keying (SC-PSK). The transmitted beam would then pass through an aperture- sharing element (ASE) - basically, a mirror with a hole in it, used to separate the paths of the transmitted and received light beams. The transmitted beam would continue outward through a telescope (which, in the original application, would be equipped with a spacecraft-tracking system) that would launch the transmitted beam along the free-space optical path to the retroreflector end.

  12. Simulación de la precipitación de inclusiones en diferentes etapas del procesamiento del acero líquido

    Directory of Open Access Journals (Sweden)

    Carreño, V.

    1998-05-01

    Full Text Available Steelmaking processes are continuously improved in order to attend the increasing requirements of the cleanness of the liquid metal. At the refining stages, as deoxidation and desulphuration, the formation of inclusions of oxides and sulphides is promoted, which on the other hand, are the most frequent inclusions. In this work a mathematical simulator of the precipitation and chemical composition of non-metallic inclusions at different steps of the steelmaking process is presented. To this purpose, it is assumed that inclusions formed by reoxidation can be simulated by increasing arbitrarily the oxygen levels consumed by the residual elements (aluminium, calcium, etc. and starting the chemical reaction with less powerful deoxidants (silicium and manganese. Accordingly, different operative conditions can be simulated. Numerical predictions are compared with experimental results of industrial trials, as well as results included in the bibliography.

    Los procesos de fabricación de acero se mejoran constantemente en respuesta a las demandas del consumidor que exige un mayor control de limpieza del metal líquido en las diversas etapas de su elaboración. En las etapas de refinación, como son desoxidación y desulfuración, se promueve la formación de inclusiones de óxidos y sulfuros, que por otra parte son las más frecuentes en el acero líquido. En este trabajo se presenta un simulador matemático que predice la precipitación y composición de las inclusiones no metálicas que se encuentran en el acero líquido en diferentes etapas de su procesamiento, asumiendo que las inclusiones formadas por reoxidación también se pueden simular al incrementar arbitrariamente los niveles de oxígeno que deberán consumir los elementos residuales altamente oxidables (Al, Ca, y empezar la reacción con los desoxidantes menores (Si y Mn. De esta manera se simulan diferentes condiciones de operación. Las predicciones numéricas se comparan con los

  13. Estudio del comportamiento termo-mecánico de un acero microaleado de medio carbono durante un proceso de conformado en caliente usando una red neuronal artificial

    Directory of Open Access Journals (Sweden)

    Alcelay, Ignacio

    2016-06-01

    Full Text Available The thermo-mechanical behavior of medium carbon microalloyed steel has been analyzed by an Artificial Neural Network (ANN. The flow curves for training the ANN have been obtained from the hot compression tests, carried out over a temperature range varying from 900 to 1150 °C and at different true strain rates ranging from 10-4 to 10 s-1. It has been found that the ANN model developed in this study is capable to predict accurately and efficiently the flow behavior of the studied steel and there is a good agreement between the experimental results and the ANN results. To analyze the formability of the studied steel, processing maps have been constructed on the basis of the Dynamic Materials Model (DMM, using the ANN values of the flow stress. The study of maps reveals the different domains of the flow behavior of the studied steel and shows the great similarity between the experimental results and the theoretical results, so the use of the ANN can constitute an interesting alternative for design and study of hot forming processes.El comportamiento termo-mecánico de un acero microaleado de medio carbono ha sido analizado mediante una Red Neuronal Artificial (RNA. Las curvas de fluencia para el entrenamiento de la RNA han sido obtenidas mediante ensayos de compresión en caliente que se efectuaron a temperaturas que oscilaron entre 1150 °C y 900 °C a incrementos de 50 °C, y en un intervalo de velocidades de deformación que varió entre 10-4 y 10 s-1. Se ha podido comprobar que el modelo de RNA, desarrollado en el presente trabajo, es capaz de predecir con exactitud y eficiencia el comportamiento de fluencia en caliente del acero estudiado y existe un buen acuerdo entre los resultados experimentales y los resultados de la RNA. Para analizar la conformabilidad del acero microaleado se han construido mapas de procesado basados en el modelo dinámico de materiales (DMM usando los valores de la tensión de fluencia obtenidos mediante la RNA. El

  14. Influencia de la ductilidad de las armaduras de acero en el comportamiento y la seguridad de losas de hormigón armado

    Directory of Open Access Journals (Sweden)

    Ortega, H.

    1999-10-01

    Full Text Available This work is based on the results and basic conclusions of author's doctoral thesis, directed by Professor José Calavera. On the one hand, a new form to measure the ductility of those steels used like reinforcement of concrete, is proposed, in order to be compared and classified in accordance with this one. On the other hand it has been studied the results of the tests on 12 continuous slabs of two equal spans, reinforced with four different steel types chosen so that, in the more requested section the steel will reach, in first place, its collapse (situation in the 2 domain, A pivot. The reinforcement to allow the mentioned extent, is provided with same nominal resistance steels and same diameter, but with - different ductility. The results of this experimental study, reveals the importance of the steel ductility concerning the behaviour and real security of the structure in front of the collapse, and furnish a group of conclusions and proposals concerning this interesting subject.

    Este trabajo se basa en los resultados y conclusiones básicas de la tesis doctoral del autor, dirigida por el Profesor D. José Calavera. Se propone, por un lado, una forma de medir mediante un único parámetro la ductilidad de los aceros utilizados como armaduras para hormigón armado, de forma que se puedan comparar y clasificar con arreglo al mismo. Por otro, se estudian los resultados de los ensayos sobre 12 losas continuas de dos vanos, de sección maciza, armadas con cuatro cuantías diferentes elegidas de forma que, en la sección más solicitada, sea el acero el que alcance, en primer lugar, su agotamiento (situación en el dominio 2, pivote A . El armado para conseguir las citadas cuantías se realiza con aceros de la misma resistencia nominal y del mismo diámetro, pero con distinta ductilidad. Los resultados de este estudio experimental, ponen de manifiesto la importancia de la ductilidad del acero en relación con el comportamiento, as

  15. Fisuración inducida por hidrógeno de aceros soldables microaleados: caracterización y modelo de comportamiento

    OpenAIRE

    Álvarez Laso, José Alberto

    2011-01-01

    RESUMEN: Las condiciones ambientales de trabajo de los aceros estructurales y de conducciones en instalaciones energéticas y petrolíferas han puesto en evidencia la necesidad de encontrar una metodología de caracterización de su resistencia a la fisuración, tanto en régimen de dominio elástico como elastoplástico. Este trabajo recoge una metodología experimental y analítica adecuada para ser aplicada a los procesos de fisuración estudiados sobre probetas y estructuras, en particular a aquéllo...

  16. Caracterización de uniones soldadas GMAW a solape en chapas finas de acero DX53D + Z100MB mediante ultrasonidos

    OpenAIRE

    Larráyoz Izcara, María

    2014-01-01

    En el sector de la automoci on, una de las t ecnicas de uni on para la construcci on de carrocer as basadas en acero m as extendida es la soldadura, tanto por resistencia como por arco el ectrico protegido (GMAW, por sus siglas en ingl es). Uno de los aspectos m as importantes para el control de las soldaduras es la detecci on de la falta de fusi on y/o penetraci on y la estimaci on de la profundidad de penetraci on as como la anchura de la zona fusionada. De forma general, la ...

  17. Efecto del volumen de metal cortado y de la velocidad de corte en el desgaste de la herramienta durante el torneado de alta velocidad del acero AISI 1045

    OpenAIRE

    Luis W. Hernández González; Roberto Pérez Rodríguez; Luminita Dumitrescu; Patricia C. Zambrano Robledo; Martha P. Guerrero Mata

    2011-01-01

    En este trabajo se aborda el estudio experimental del efecto del volumen de metal cortado y de la velocidad de corte en el desgaste del flanco de dos insertos de carburos recubiertos y un cermet, durante el torneado de acabado en seco del acero AISI 1045 a velocidades de corte moderada, intermedia y alta. Los resultados fueron comparados utilizando la dimensión volumétrica de la vida útil de la herramienta, el análisis de varianza y el análisis de regresión lineal para describir la relación e...

  18. Procedimientos y análisis END y ED de soldaduras a tope SMAW, MAG y TIG, de acero al carbono F-114 para construcción

    OpenAIRE

    CLIMENT BALBASTRE, JUAN JOSÉ

    2011-01-01

    Trabajo científico técnico.El objeto del proyecto es la comparación entre tres chapas. Cada una de las chapas tiene un procedimiento de soldadura diferente: Chapa 1. Método SMAW. Chapa 2. Método MAG. Chapa 3. Método TIG. Una vez estas han sido soldadas, se procederá mediante ensayos no destructivos y ensayos destructivos a descubrir las características de estas. Al final de la realización de todos estos ensayos, se concluirá con la elección de la soldadura más apropiada para este acero. La...

  19. Variación del módulo de Young en el acero C45E (norma EN 10083 tratado térmicamente

    Directory of Open Access Journals (Sweden)

    Fonseca, I.

    2002-08-01

    Full Text Available The parameters hardness, yield strength, ultimate tensile strength, toughness and Young's modulus of carbon steel C45E, EN 10083 (AISI 1045 annealed, quenched and tempered at various temperatures have been determined. Young's modulus has also been measured from ultrasonic techniques and also from the tension test; elastic deformation has been determined by the electric gaugue method. A metallographic study by scanning electron microscopy has also been carried out to confirm the results of the thermal treatment. Hardness, yield strength and ultimate tensile strength increases as it is with the thermal treatment. In addition Young=s modulus increases from 199-200 GPa (quenched state to 211-212 GPa (tempered 500 °C, 1 h.. The annealed steel presents a Young's modulus of 206-207 GPa. A good agreement between Young's modulus values obtained by ultrasonic measurements and by tension test has been observed. This behaviour has been correlated with the distribution of dislocations in the material under the various states.

    Se han determinado distintas propiedades mecánicas del acero C45E según norma EN10083 (AISI 1045 reconocido, templado y revenido a distintas temperaturas. Las propiedades mecánicas analizadas han sido: dureza, límite elástico convecional, resistencia a la tracción, resiliencia y módulo de Young. Esta última propiedad se determinó por ultrasonidos y a partir de curvas tensión-deformación midiendo ésta mediante extensometría eléctrica.En todos los casos se ha comprobado la bondad del tratamiento aplicado madiante observaciones metalográficas por microscopía eléctronica de barrido. Los valores de dureza, límite elástico convecional y resistencia a la tracción presentan las variaciones esperadas después de los distintos tratamientos térmicos aplicados. Sorprendentemente, el módulo de Young se incrementa desde valores de 199-200 GPa para el acero templado hasta 211-212 GPa para el acero templado y revenido a

  20. Efecto sobre la resistencia mecanica y las discontinuidades en la soldadura a tope por destello (FBW) durante la fabricación de aros para ruedas de acero

    OpenAIRE

    Acosta Echeverria, Miguel Arturo

    2015-01-01

    En este estudio, se aplicó el proceso de soldadura a tope por destello (FBW) a algunas láminas de acero HSLA microaleado de la especificación SPFH 590 con un espesor de 2,3 mm; se realizaron varias probetas cambiando algunos parámetros del proceso de soldadura con el fin de investigar los efectos de estos cambios. Las partes soldadas y las zonas afectadas por el calor (HAZ) fueron revisadas por medio de inspección visual por un operario de soldadura entrenado, también se realizaro...

  1. Does Dopplersignal enhancement with Levovist improve the diagnostic confidence of duplex scanning of the iliac arteries?--(A pilot study with correlation to intravascular ultrasound)

    DEFF Research Database (Denmark)

    Vogt, K C; Jensen, F; Schroeder, T V

    1998-01-01

    To evaluate whether echo-enhancement with Levovist improves the diagnostic confidence of duplex scanning of the iliac arteries.......To evaluate whether echo-enhancement with Levovist improves the diagnostic confidence of duplex scanning of the iliac arteries....

  2. Caracterización dinámica de los cambios microestructurales en barras de aceros dúplex SAF 2205 utilizando la dimensión de información

    Directory of Open Access Journals (Sweden)

    Rodríguez, Edda

    2014-03-01

    Full Text Available This study evaluates the ultrasonic signals behavior of a duplex stainless steel SAF 2205 (UNS S31803 after aging treatments at 875 and 950 °C. The first treatment promotes the precipitation of the sigma phase and the second, its dissolution. The microstructural evaluation was carried out by optical microscopy. The results showed an increase of the sigma phase fraction and the secondary austenite with the time of aging treatment at 875 °C. On the other hand, increasing the time of treatment at 950 °C promotes a reduction of the sigma phase and the corresponding increase of the ferrite phase fraction. The study proposed to evaluate in the dynamical system field the influence of microstructural phases in the signals behavior and their dependence on the energy losses occurring in system during heat treatment, by deterministic chaos theory. To accomplish characterization, algorithm employs the representation of dynamic phase space and the information dimension estimate. The results show a higher correlation between the information dimension and the attenuation coefficient in comparison with the phase fractions. However, the efficiency of this type of study will depend on the frequency selected for the evaluation of the material.En el presente estudio se evalúa el comportamiento dinámico de las señales ultrasónicas de muestras de acero dúplex SAF 2205 (UNS31803, sometidos a tratamientos de envejecimiento a 875 y 950 °C. En el primer tratamiento se promueve la precipitación de la fase sigma y en el segundo su disolución. Los resultados obtenidos por microscopía óptica indican que la cantidad relativa de la fase sigma aumenta progresivamente con el tiempo de envejecimiento a 875 °C, observándose la transformación de la fase ferrita en fase sigma y en austenita secundaria. Por otra parte, a medida que se aumenta el tiempo de tratamiento a 950 °C, se observa una reducción del porcentaje de fase sigma y un aumento de la fase ferr

  3. Throughput maximization for buffer-aided hybrid half-/full-duplex relaying with self-interference

    KAUST Repository

    Khafagy, Mohammad Galal

    2015-06-01

    In this work, we consider a two-hop cooperative setting where a source communicates with a destination through an intermediate relay node with a buffer. Unlike the existing body of work on buffer-aided half-duplex relaying, we consider a hybrid half-/full-duplex relaying scenario with loopback interference in the full-duplex mode. Depending on the channel outage and buffer states that are assumed available at the transmitters, the source and relay may either transmit simultaneously or revert to orthogonal transmission. Specifically, a joint source/relay scheduling and relaying mode selection mechanism is proposed to maximize the end-to-end throughput. The throughput maximization problem is converted to a linear program where the exact global optimal solution is efficiently obtained via standard convex/linear numerical optimization tools. Finally, the theoretical findings are corroborated with event-based simulations to provide the necessary performance validation.

  4. The influence of aging on the intergranular corrosion of 22 chromium-5 nickel duplex stainless steel

    International Nuclear Information System (INIS)

    Duplex stainless steels are widely used in severe corrosion environments because of their good corrosion performance. This paper deals with the influence of aging treatments on the intergranular corrosion (IGC) resistance of a commercial duplex stainless steel, SAF 2205. Duplex stainless steel was given aging treatments in the range 773-1173 K for time periods ranging from 6 min to 100 h. Optical microscopy and XRD was carried out on the aged stainless steels for the microstructural study. The aged samples were evaluated for the IGC susceptibility with the ASTM standard practices. Potentiodynamic cyclic polarization studies were also carried out to investigate the influence of aging treatments on the passivity breakdown. The results indicate that the sigma phase gets precipitated and is responsible for grain boundary attack. (author)

  5. Interference alignment for degrees of freedom improvement in 3-relay half-duplex systems

    KAUST Repository

    Park, Seongho

    2011-12-01

    In a half-duplex relaying, the capacity pre-log factor is a major drawback in spectral efficiency. This paper proposes a linear precoding scheme and an alternate relaying protocol in a dual-hop half-duplex system where three relays help the communication between the source and the destination. In our proposed scheme, we consider a phase incoherent method in relays in which the source alternately transmits message signals to the different relays. In addition, we propose a linear interference alignment scheme which can eliminate the inter-relay interference resulted from the phase incoherence of relaying. Based on our analysis of degrees of freedom and our simulation results, we show that our proposed scheme achieves additional degrees of freedom compared to the conventional half-duplex relaying. © 2011 IEEE.

  6. Alternate transmission relaying based on interference alignment in 3-relay half-duplex MIMO systems

    KAUST Repository

    Park, Seongho

    2012-09-01

    In a half-duplex relaying, the capacity pre-log factor 1/2 is a major drawback in spectral efficiency. This paper proposes a linear precoding/decoding scheme and an alternate relaying protocol in a dual-hop half-duplex system where three relays help the communication between the source and the destination. In our proposed scheme, we consider a phase incoherent method in relays in which the source alternately transmits message signals to the different relays. In addition, we propose a linear interference alignment scheme which can suppress the inter-relay interference resulting from the phase incoherence of relaying. Based on our analysis of degrees of freedom and our simulation results, we show that our proposed scheme achieves additional degrees of freedom compared to the conventional half-duplex relaying. © 2012 IEEE.

  7. Mixer-Duplexer-Antenna Leaky-Wave System Based on Periodic Space-Time Modulation

    CERN Document Server

    Taravati, Sajjad

    2016-01-01

    We present a mixer-duplexer-antenna leaky-wave system based on periodic space-time modulation. This system operates as a full transceiver, where the upconversion and downconversion mixing operations are accomplished via space-time transitions, the duplexing operation is induced by the nonreciprocal nature of the structure, and the radiation operation is provided by the leaky-wave nature of the wave. A rigorous electromagnetic solution is derived for the dispersion relation and field distributions. The system is implemented in the form of a spatio-temporally modulated microstrip leaky-wave structure incorporating an array of sub-wavelengthly spaced varactors modulated by a harmonic wave. In addition to the overall mixer-duplexer-antenna operation, frequency beam scanning at fixed input frequency is demonstrated as one of the interesting features of the system. A prototype is realized and demonstrated by full-wave and experimental results.

  8. In-Band Full-Duplex Communications for Cellular Networks with Partial Uplink/Downlink Overlap

    KAUST Repository

    Alammouri, Ahmad Mohammad Abdel-Karim

    2015-12-06

    In-band full-duplex (FD) communications have been optimistically promoted to improve the spectrum utilization in cellular networks. However, the explicit impact of spatial interference, imposed by FD communications, on uplink and downlink transmissions has been overlooked in the literature. This paper presents an extensive study of the explicit effect of FD communications on the uplink and downlink performances. For the sake of rigorous analysis, we develop a tractable framework based on stochastic geometry toolset. The developed model accounts for uplink truncated channel inversion power control in FD cellular networks. The study shows that FD communications improve the downlink throughput at the expense of significant degradation in the uplink throughput. Therefore, we propose a novel fine-grained duplexing scheme, denoted as α-duplex scheme, which allows a partial overlap between uplink and downlink frequency bands. To this end, we show that the amount of the overlap can be optimized via adjusting α to achieve a certain design objective.

  9. Sequential and spatial organization of metal complexes inside a peptide duplex.

    Science.gov (United States)

    Yamada, Yasuyuki; Kubota, Takayuki; Nishio, Motoki; Tanaka, Kentaro

    2014-04-30

    To generate integrated organized molecular properties, multiple molecular components are required to be assembled into the molecular system with sequential and spatial accuracy in accordance with the design of the molecular assembly. Herein, we present a novel programmable synthesis of a cofacially stacked porphyrin array via repetitive construction of a peptide duplex. We designed and synthesized a novel porphyrin having two artificial amino acid moieties at the trans meso-positions. The amino acid moieties can be connected with another porphyrin unit by repetitive doubly coupling reactions to afford the peptide duplex bridged by the porphyrins. In the duplex, the porphyrin units are stacked cofacially, and the efficient electronic communication among the arrayed porphyrin units was characterized by split redox waves in the cyclic voltammograms. We also demonstrated the three different square-planar metal ions, namely Cu(2+), Ni(2+), and Pd(2+), were arranged inside the ladder-type porphyrin array in a programmable fashion. PMID:24735178

  10. Design of duplex low carbon steels for improved strenght--weight applications

    Energy Technology Data Exchange (ETDEWEB)

    Koo, J.Y.; Thomas, G.

    1978-03-01

    Design principles for improved mechanical properties of Duplex Ferrite-Martensite (DFM) steels have been evaluated in order to obtain desirable microstructural characteristics which in turn result in desirable mechanical properties. A DFM alloy, of composition Fe/2 percent Si/0.1 percent C, has been developed according to the design criteria. This 2 percent Si DFM steel showed high strength and good formability, and its tensile properties are superior to a series of Cr and Mn containing DFM steels, and to some selective commercial HSLA steels including Van 80. Over the range of 15 to 80 percent martensite the ''composite'' rule for two phase mixtures appears to hold as a fairly good approximation of the tensile behavior of the duplex systems investigated. The effect of the property variations of the individual constituents, and duplex structure-property relations are also presented.

  11. Fluorescence studies on the interaction of ethidium bromide with duplex, triplex and quadruplex DNA structures

    Institute of Scientific and Technical Information of China (English)

    孙雪光; 曹恩华; 何裕建; 秦静芬

    1999-01-01

    Under different conditions, oligonucleotides can form several alternative DNA structures such as duplex, triplex and quadruplex. All these structures can interact with ethidium bromide (EB) and make its fluorescence intensity change. The fluorescence spectra and other related parameters provided by static fluorescence techniques showed that the interaction mechanisms between EB and these structures were not always the same. Among them, B type duplex and triplex DNA adopt an intercalative mode when binding to the EB, which has a relatively high efficiency of energy transfer and the fluorescence of EB cannot be quenched easily. While for the parallel duplex DNA, the interaction mode is an outside binding in which energy transfer can hardly happen and its fluorescence intensity as well as Stern-Volmer constant is almost the same to the free EB. For the quadruplex, the binding mechanism to EB is more complex. Results from the energy transfer and quenching studies indicate that the two interaction modes note

  12. Dwell-Time Distribution, Long Pausing and Arrest of Single-Ribosome Translation through the mRNA Duplex

    Directory of Open Access Journals (Sweden)

    Ping Xie

    2015-10-01

    Full Text Available Proteins in the cell are synthesized by a ribosome translating the genetic information encoded on the single-stranded messenger RNA (mRNA. It has been shown that the ribosome can also translate through the duplex region of the mRNA by unwinding the duplex. Here, based on our proposed model of the ribosome translation through the mRNA duplex we study theoretically the distribution of dwell times of the ribosome translation through the mRNA duplex under the effect of a pulling force externally applied to the ends of the mRNA to unzip the duplex. We provide quantitative explanations of the available single molecule experimental data on the distribution of dwell times with both short and long durations, on rescuing of the long paused ribosomes by raising the pulling force to unzip the duplex, on translational arrests induced by the mRNA duplex and Shine-Dalgarno(SD-like sequence in the mRNA. The functional consequences of the pauses or arrests caused by the mRNA duplex and the SD sequence are discussed and compared with those obtained from other types of pausing, such as those induced by “hungry” codons or interactions of specific sequences in the nascent chain with the ribosomal exit tunnel.

  13. Duplex and Triplex Formation of Mixed Pyrimidine Oligonucleotides with Stacking of Phenyl-triazole Moieties in the Major Groove

    DEFF Research Database (Denmark)

    Andersen, Nicolai Krog; Døssing, Holger; Jensen, Frank;

    2011-01-01

    nucleosides, improved duplex formation with a complementary RNA and improved triplex formation with a complementary DNA duplex were observed. The improvement is due to π-π stacking of the phenyl-triazole moieties in the major groove. The strongest stacking and most pronounced positive influence on thermal...

  14. Structural, Dynamical, and Electronic Transport Properties of Modified DNA Duplexes Containing Size-Expanded Nucleobases

    Energy Technology Data Exchange (ETDEWEB)

    Fuentes-Cabrera, Miguel A [ORNL; Orozco, Modesto [Institut de Recerca Biomedica, Parc Cientific de Barcelona, Barcelona, Spain; Luque, Javier [Universitat de Barcelona; Sumpter, Bobby G [ORNL; Blas, Jose [Universidad de Castilla-La Mancha; Ordejon, Pablo J [ORNL; Huertas, Oscar [Universitat de Barcelona; Tabares, Carolina [Universitat de Barcelona

    2011-01-01

    Among the distinct strategies proposed to expand the genetic alphabet, sizeexpanded nucleobases are promising for the development of modified DNA duplexes with improved biotechnological properties. In particular, duplexes built up by replacing canonical bases with the corresponding benzo-fused counterparts could be valuable as molecular nanowires. In this context, this study reports the results of classical molecular dynamics simulations carried out to examine the structural and dynamical features of size-expanded DNAs, including both hybrid duplexes containing mixed pairs of natural and benzo-fused bases (xDNA) and pure size-expanded (xxDNA) duplexes. Furthermore, the electronic structure of both natural and size-expanded duplexes is examined by means of density functional computations. The results confirm that the structural and flexibility properties of the canonical DNA are globally little affected by the presence of benzo-fused bases. Themost relevant differences are found in the enhanced size of the grooves, and the reduction in the twist. However, the analysis also reveals subtle structural effects related to the nature and sequence of benzo-fused bases in the duplex. On the other hand, electronic structure calculations performed for xxDNAs confirm the reduction in the HOMOLUMO gap predicted from the analysis of the natural bases and their size-expanded counterparts, which suggests that pure size-expanded DNAs can be good conductors. A more complex situation is found for xDNAs, where fluctuations in the electrostatic interaction between base pairs exerts a decisive influence on the modulation of the energy gap.

  15. Characterizing the bending and flexibility induced by bulges in DNA duplexes

    Science.gov (United States)

    Schreck, John S.; Ouldridge, Thomas E.; Romano, Flavio; Louis, Ard A.; Doye, Jonathan P. K.

    2015-04-01

    Advances in DNA nanotechnology have stimulated the search for simple motifs that can be used to control the properties of DNA nanostructures. One such motif, which has been used extensively in structures such as polyhedral cages, two-dimensional arrays, and ribbons, is a bulged duplex, that is, two helical segments that connect at a bulge loop. We use a coarse-grained model of DNA to characterize such bulged duplexes. We find that this motif can adopt structures belonging to two main classes: one where the stacking of the helices at the center of the system is preserved, the geometry is roughly straight, and the bulge is on one side of the duplex and the other where the stacking at the center is broken, thus allowing this junction to act as a hinge and increasing flexibility. Small loops favor states where stacking at the center of the duplex is preserved, with loop bases either flipped out or incorporated into the duplex. Duplexes with longer loops show more of a tendency to unstack at the bulge and adopt an open structure. The unstacking probability, however, is highest for loops of intermediate lengths, when the rigidity of single-stranded DNA is significant and the loop resists compression. The properties of this basic structural motif clearly correlate with the structural behavior of certain nano-scale objects, where the enhanced flexibility associated with larger bulges has been used to tune the self-assembly product as well as the detailed geometry of the resulting nanostructures. We further demonstrate the role of bulges in determining the structure of a "Z-tile," a basic building block for nanostructures.

  16. Recognition of RNA duplexes by chemically modified triplex-forming oligonucleotides.

    Science.gov (United States)

    Zhou, Yuan; Kierzek, Elzbieta; Loo, Zi Ping; Antonio, Meraldo; Yau, Yin Hoe; Chuah, York Wieo; Geifman-Shochat, Susana; Kierzek, Ryszard; Chen, Gang

    2013-07-01

    Triplex is emerging as an important RNA tertiary structure motif, in which consecutive non-canonical base pairs form between a duplex and a third strand. RNA duplex region is also often functionally important site for protein binding. Thus, triplex-forming oligonucleotides (TFOs) may be developed to regulate various biological functions involving RNA, such as viral ribosomal frameshifting and reverse transcription. How chemical modification in TFOs affects RNA triplex stability, however, is not well understood. Here, we incorporated locked nucleic acid, 2-thio U- and 2'-O methyl-modified residues in a series of all pyrimidine RNA TFOs, and we studied the binding to two RNA hairpin structures. The 12-base-triple major-groove pyrimidine-purine-pyrimidine triplex structures form between the duplex regions of RNA/DNA hairpins and the complementary RNA TFOs. Ultraviolet-absorbance-detected thermal melting studies reveal that the locked nucleic acid and 2-thio U modifications in TFOs strongly enhance triplex formation with both parental RNA and DNA duplex regions. In addition, we found that incorporation of 2'-O methyl-modified residues in a TFO destabilizes and stabilizes triplex formation with RNA and DNA duplex regions, respectively. The (de)stabilization of RNA triplex formation may be facilitated through modulation of van der Waals contact, base stacking, hydrogen bonding, backbone pre-organization, geometric compatibility and/or dehydration energy. Better understanding of the molecular determinants of RNA triplex structure stability lays the foundation for designing and discovering novel sequence-specific duplex-binding ligands as diagnostic and therapeutic agents targeting RNA. PMID:23658228

  17. Creep-rupture-test on the stainless steel X6crni1811 (Din 1.494.8) in the frame of the Extrapolation-Program. (Part III); Ensayos de fluencia lenta en el acero inoxidable X6 Cr Ni 1811 (1.4948) en el marco del Programa Extrapolacion

    Energy Technology Data Exchange (ETDEWEB)

    Solano, R.; Schirra, M.; Rivas, M. de la; Barroso, S.; Seith, B.

    1982-07-01

    The austenitic stainless steel X6crni1811 (Din 1.4948) used as a structure material for the German Fast Breeder Reactor SNR 300 was creep tested in a temperature range of 550-650 degree centigree material condition as well as welded material condition. The main point of this program (Extrapolation-Program) lies in the knowledge of the creep-rupture-strength and creep-behaviour up to 3 x 10{sup 4} hours higher temperatures in order to extrapolated up to {>=}10{sup 5} hours for operating temperatures. In order to study the stress dependency of the minimum creep rate additional tests were carried out of 550 degree centigree - 750 degree centigree. The present report describes the state in the running program with test-times of 23.000 hours and results from tests up to 55.000 hours belonging to other parallel programs are taken into account. Besides the creep-rupture behaviour it is also made a study of ductility between 550 and 750 degree centigree. Extensive metallographic examinations have been made to study the fracture behaviour and changes in structure. (Author)

  18. Zirconium oxide deposits (ZrO{sub 2}) and titanium oxide (TiO{sub 2}) on 304l stainless steel; Depositos de oxido de circonio (ZrO{sub 2}) y oxido de titanio (TiO{sub 2}) sobre acero inoxidable 304L

    Energy Technology Data Exchange (ETDEWEB)

    Davila N, M. L.

    2015-07-01

    This research project aims to carry out the surface and electrochemical characterization to obtain the optimum conditions of the hydrothermal deposits of zirconium oxide ZrO{sub 2} (baddeleyite) and titanium oxide TiO{sub 2} (anatase and rutile phases) on 304l stainless steel, simulating an inhibiting protective layer. 304l steel specimens were cut, pre-oxidized in water at a temperature of 288 degrees Celsius and 8 MPa, similar to those of a typical BWR conditions. From the titanium oxide anatase crystalline phase, the rutile phase was obtained by a heat treatment at 1000 degrees Celsius. The Sigma-Aldrich pre-oxidized powders and steel 304l were characterized using techniques of X-ray diffraction, scanning electron microscopy, X-ray dispersive energy, chemical mapping and Raman spectrometry. The pre-oxidized steel has two oxide layers, an inner layer with nano metric crystals and another outer of larger crystals to 1μm, with the formation of hematite and magnetite, this predominating. The surface that contacted the sample holder has larger crystals. Hydrothermal deposits were carry out from suspensions of 10, 100 and 1000 ppm, of the crystal phases of anatase, rutile and baddeleyite, on the pre-oxidized steel at a temperature of 150 degrees Celsius for 2 and 7 days, samples were analyzed by X-ray diffraction, scanning electron microscopy, X-ray dispersive energy, Raman spectrometry and Tafel polarization. The suspension to 1000 ppm for 7 days coated surface most; the baddeleyite deposit is noticed more homogeneous than anatase and rutile. The deposit is favored when hematite and magnetite crystals are larger. The chemical mapping on deposits show that even after being immersed in water to 288 degrees Celsius during 30 days, the deposits are still present although a loss is observed. A reference electrode was assembled to conduct electrochemical tests of Tafel able to withstand a temperature of 288 degrees Celsius and pressure of 8 MPa. The baddeleyite deposit presented the electrochemical corrosion potential versus standard electrode of hydrogen (ECP{sub EEH}) more negative, between -35 and -79 mV{sub EEH}), is indicating that it has the greatest capacity to mitigate the stress corrosion, this at a temperature of 288 degrees Celsius. However at a lower temperature, between 250 and 150 degrees Celsius the rutile coating is having a negative ECP{sub EEH} between -100 and -150 mV{sub EEH}. The cathodic slopes of Tafel curves show that deposits are fulfilling their inhibitor functions. In some cases the anodic part of Tafel curve has a section where the potential remains constant while varying the current, suggesting the formation of oxides. (Author)

  19. Characterization by EBSD technique of AISI 304 DDQ stainless steel sheet deformed under typical deep drawing multiaxial stress system; Caracterizacion mediante la tecnica EBSD de la defromacion de chapa de acero inoxidable AISI 304 DDQ bajo tensiones multiaxiales tipicas de la embuticion

    Energy Technology Data Exchange (ETDEWEB)

    Coello, J.; Miguel, V.; Calatayud, A.; Ferrer, C.; Martinez, A.

    2009-07-01

    The main aim of this work to evaluate AISI 304 DDQ stainless steel behaviour under deep drawing deformation condition, that is pure shear deformation in which materials suffers a typical deformation under tension-biaxial compression stresses system. The microstructural evolution has been investigated by optical microscopy and by EBSD technique. The success of the EBSD analysis has been established for the deformation conditions experimented here. It has been determined the rolling direction and the equivalent strain influence on the crystallographic orientation maps, misorientation diagrams and poles figures. The results let the authors say the low angle misorientation corresponding to 0,45 and 90 degree centigrade rolling directions have an inverse correlation with the material anisotropy. Initial pre-straining has been considered also and the analysis of this aspects lead to establish that the increment of the intragranular misorientation with the strain depends on the initial state a of the steel; this increment is observed to be minor for samples with initial prestraining. High angle misorientation analysis (>15 degree centigrade) indicates that the grain boundaries character distributions depends on the deformation. (Author) 20 refs.

  20. Deformability analysis of the AISI 304 DDQ stainless steel under deep drawing multiaxial condition. Evaluation of the initial strain influence; Analisis de la deformabilidad del acero inoxidable AISI 304 DDQ en condiciones multiaxiales de embuticion. Evaluacion de la influencia de la acritud inicial

    Energy Technology Data Exchange (ETDEWEB)

    Coello, J.; Miguel, V.; Calatayud, A.; Martinez, A.; Ferrer, C.

    2010-07-01

    The deep drawing formability of a material is established as a function of standard indexes, as strength coefficient and anisotropy coefficient. But these indexes are determined in different conditions to those that take place in the forming process. The simulative assays do not separate the actions due to the different variables that work in the process, as for example, the rolling direction. In the present work a test that uses a wedge shape die is considered in order to obtain the strength and anisotropy coefficients as a function of rolling direction. This way, the assays are carried out under a tensile-biaxial compression stress state similar to that one taking place in the flange zone in deep drawing. The experimented material is a deep drawing quality stainless steel AISI 304. The influence of initial strengthened states, rolling and uniaxial tensile on the steel behaviour are also studied. The results permits the authors establish the validity of the assay from the point of view of the strains produced in the sheet. The initial strain has a higher effect on the material than that one obtained from the tensile-biaxial of the state than the tensile-biaxial compression causes. The anisotropy coefficient changes with the strain for the sheet rolling direction. (Author).

  1. A mathematical approach based on finite differences method for analyzing the temperature field in arc welding of stainless steel thin sheets; Desarrollo de un modelo matematico de diferencias finitas para el analisis del campo de temperaturas en la soldadura por arco de chapas finas de acero inoxidable

    Energy Technology Data Exchange (ETDEWEB)

    Martinez-Conesa, E.J.; Estrems, M.; Miguel, V.

    2010-07-01

    This work develops a finite difference method to evaluate the temperature field in the heat affected zone in butt welding applied to AISI 304 stainless steel thin sheet by GTAW process. A computer program has been developed and implemented by Visual Basic for Applications (VBA) in MS-Excel spreadsheet. The results that are obtained using the numerical application foresee the thermal behaviour of arc welding processes. An experimental methodology has been developed to validate the mathematical model that allows to measure the temperature in several points close to the weld bead. The methodology is applied to a stainless steel sheet with a thickness lower than 3 mm, although may be used for other steels and welding processes as MIG/MAG and SMAW. The data which has been obtained from the experimental procedure have been used to validate the results that have been calculated by the finite differences numerical method. The mathematical model adjustment has been carried out taking into account the experimental results. The differences found between the experimental and theoretical approaches are due to the convection and radiation heat losses, which have not been considered in the simulation model.With this simple model, the designer will be able to calculate the thermal cycles that take place in the process as well as to predict the temperature field in the proximity of the weld bead. (Author). 18 refs.

  2. Friction and bending forces evaluation of AISI 304 DDQ steel sheet forming by bending tests under deep-drawing multiaxial stresses; Evaluacion de la fuerza de doblado y de friccion en el conformado de chapa de acero inoxidable AISI 304 DDQ mediante ensayos de doblado en condiciones multiaxiales de embuticion

    Energy Technology Data Exchange (ETDEWEB)

    Coello, J.; Miguel, V.; Ferrer, C.; Calatayud, A.; Martinez, A.

    2012-11-01

    Die radius is a critical area from the viewpoint of friction in forming processes. Moreover the sheet, that has been previously deformed in flange area, suffers bending and unbending stresses. Then, die-sheet contact in die radius must be especially considered in order to guarantee the suitable lubrication conditions. In the present work, a test method is carried out for evaluating an AISI 304 DDQ steel under similar conditions to those existing in the die radius area and that, usually, are not really reproduced in traditional bending under tensions tests. Deformation under pure shear condition, the bending and the radius angle have been established as variables of the tests. Results allow to obtain the apparent pressure sheet-bending tool, that increases with bending angle and decreases with tool radius. This last variable is the most significant while the bending angle has lesser influence. Although experimental results present some concordances with values obtained by analytical methods, some corrections must be considered in them in order to improve the theoretical values. (Author) 18 refs.

  3. Solubility of Oxygen in Liquid Sodium and the Interpretation of Predictions for the Corrosion Rate of Stainless Steels in Liquid Sodium; Solubilidad del oxigeno en sodio liquido e interpretacion de predicciones de la velocidad de corrosion de los aceros inoxidables en sodio liquido

    Energy Technology Data Exchange (ETDEWEB)

    Claxton, K. T.

    1979-07-01

    A statistical analysis of all oxygen in sodium solubility data has been made. The results indicate a real difference. between levels of oxygen reported by UK und US workers. Analysis using sub-sets of culled data to derive a compromise solubility function are considered less than adequate. It is considered preferable and more realistic to distinguish data sub-sets by the analytical technique employed. The vacuum distillation method yields results differing amongst them selves by up to a factor of five at cold trap temperatures of relevance to fast reactor operation. The vanadium wire and electrochemical cell techniques give the lowest solubility values. (Author) 51 refs.

  4. Superficial and electrochemical study of stainless steel 304l with an inhibitory protective coating (TiO{sub 2} and ZrO{sub 2}); Estudio superficial y electroquimico de acero inoxidable 304L con una capa protectora inhibidora (TiO{sub 2} y ZrO{sub 2})

    Energy Technology Data Exchange (ETDEWEB)

    Davila N, M. L.; Contreras R, A.; Arganis J, C. R., E-mail: aida.contreras@inin.gob.mx [ININ, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico)

    2014-10-15

    The degradation mechanisms in the boiling water reactors (BWR) have been an alert focus for owners, especially the cracking by stress corrosion cracking (SCC), therefore different techniques have been studied to inhibit this problem inside which is the water injection of hydrogen feeding (HWC, Hydrogen Water Chemistry), together with the noble metals injection (NMCA, Nobel Metal Chemical Addition) and the ceramic materials injection that form an inhibitory protective coating (Ipc). In this work the Ipc was simulated, for which were carried out hydro-thermals deposits starting from suspensions of 1000 ppm of zirconium oxide in its crystalline phase baddeleyite and titanium oxides in its anatase and rutile phases, on test tubes of stainless steel 304l previously rusty under simulated conditions of pressure and temperature of a BWR (288 C and 8 MPa). The superficial characterization was realized by scanning electron microscopy, energy-dispersive of X-ray and X-ray diffraction. The capacity to mitigate the corrosion was studied with the electrochemical technique of Tafel polarization (288 C and 8 MPa). The steel presents the formation of two oxide coatings formed by magnetite and hematite. The baddeleyite presents a deposit more thick and homogeneous it also presents the most negative electrochemical potential of corrosion, what indicates that it has the bigger capacity to mitigate the SCC. (Author)

  5. Behavior to the fracture of an AISI 304 stainless steel sensitized in BWR reactor conditions (288 degrees Centigrade and 80 Kg/cm{sup 2}); Comportamiento a la fractura de un acero inoxidable AISI 304 sensibilizado en condiciones de reactor BWR (288 grados Centigrados y 80 Kg/cm{sup 2})

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez C, R.; Diaz S, A.; Garcia R, R.; Aguilar T, A.; Gachuz M, M.; Arganis J, C.; Merino C, J. [Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, 11801 Mexico D.F. (Mexico)

    1999-07-01

    It is a knew fact that ductility of a lot of structural alloys can be deteriorated by the environment effect which are exposed, and that their consequent embrittlement can put in doubt the safety of their functioning; such is the case of austenitic stainless steels used in internal components of the BWR type reactors which not only is subjected to the effect combined of the aggressive environment which surround it (pressure, temperature, corrosion potential, conductivity medium, local state of efforts, etc.), but also to the action of present neutron radiation, manifesting microstructural changes which are reflected in the augmentation of its susceptibility to the intergranular cracking, phenomena generally known as IASCC ''Irradiation Assisted Stress Corrosion Cracking''. Once appeared the cracking in the material, the useful life of a component is limited by the rapidity to growth of these cracking, making necessary evaluations which can to predict its behavior, therefore the present work shows the preliminary results for determining the behavior to the fracture of an AISI 304 stainless steel sensitized, in a dynamic recirculation circuit which allows to simulate the operation conditions of a BWR reactor (288 Centigrade and 80 kg/cm{sup 2}). (Author)

  6. Spring back evaluation by bending under tension tests in conditions of multiaxial stresses corresponding to deep drawing processes. Application to AISI 304 DDQ stainless steel sheet; Evaluacion del springback mediante ensayos de doblado bajo tension en condiciones de multiaxialidad tipicas de los procesos de embuticion profunda. Aplicacion a chapa de acero inoxidable AISI 304 DDQ

    Energy Technology Data Exchange (ETDEWEB)

    Miguel, V.; Coello, J.; Martinez, A.; Calatayud, A.

    2013-09-01

    In this paper, a methodology has been developed for evaluating the spring back of AISI 304 DDQ stainless steel sheet based on a bending under tension test. The main difference of the methodology herein carried out is that tests are made under the multiaxial stresses state that take place in deep drawing processes. This affects to the level of stress value in the test and to the hardening state of the sheet. Springback evaluation has been done in two different areas. Bending area has been evaluated from elastic recovery ratio defined as the ratio between the bending radius after and before bending. Bending and unbending extreme has been studied from the measured curvature radius in this area and taking into account the geometric equivalence of the test with the drawing cups process. Results found allow to state that drawing ratio or deformation ratio have a negligible influence on the springback into the range of values experimented here. Bending radius has hardly influence as well while bending angle is the most significant variable. The results obtained are compared to those measured in deep-drawn cups, finding a great agreement. (Author)

  7. Stainless steel pickling using ecologies friendly mixtures composed of H{sub 2}O{sub 2} - H{sub 2}SO{sub 4} - F{sup -} ions; Decapado de un acero inoxidable austenitico mediante mezclas ecologicas basadas en H{sub 2}O{sub 2} - H{sub 2}SO{sub 4} - iones F{sup -}

    Energy Technology Data Exchange (ETDEWEB)

    Narvaez, L.; Miranda, J. M.; Ronquillo, A.

    2013-06-01

    This study reports the pickling of 316L stainless steel using mixtures of hydrogen peroxide (H{sub 2}O{sub 2}), sulphuric acid (H{sub 2}SO{sub 4}) and fluoride ions as hydrofluoric acid (HF), sodium fluoride (NaF) and potassium fluoride (KF). The decomposition of H{sub 2}O{sub 2} in the mixtures was assessed at different temperatures 25 degree centigrade to 60 degree centigrade, with ferric ion contents from 0 to 40 g/l. According to the results obtained, were established the optimal condition pickling at 20 g/l of ferric ions, 25 degree centigrade and p-toluen sulphonic acid as stabilizer of H{sub 2}O{sub 2}. The HF pickling mixture was the only capable to remove totally the oxide layer from the 316L stainless steel after 300 s. The fluoride salts pickling mixtures only remove partially the oxide layer (20 to 40 % aprox.) after 300 s. When the pickling time was increased until 1200 s, the removal percentages were around to 80 %. (Author)

  8. Design and Synthesis of a Highly Stable Six-hydrogen-bonded Self-assembly Yellowish Green Electroluminescent Molecular Duplex

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    This paper describes the design, synthesis and characterization of a hydrogen-bonded molecular duplex with 1,8-naphthalimide fluorescent pendants. The two oligoamide molecular strands, with complementary hydrogen bond sequences of DDADAA and AADADD, caa form an ultra stable self-assembly duplex. Its molecular structure was confirmed by 1H NMR and ESI-MS, and its photoluminescence properties were determined. The resulting duplex exhibited a dramatically enhanced photoluminescence (PL) quantum efficiency of 63.7% compared to the corresponding 1,8-naphthalimide segment (32.4%), suggesting that the formation of the duplex with larger molecular weight could successfully inhibit the quenching of the fluorescent pendant.This novel duplex is a prospective candidate for new electroluminescent emitter.

  9. Use of a gray level co-occurrence matrix to characterize duplex stainless steel phases microstructure

    OpenAIRE

    L. Zortea; F. R. Renzetti

    2011-01-01

    Duplex stainless steels are widely used in industry. This is due to their higher strength compared to austenitic steels and to their higher toughness than ferritic steels. They also have good weldability and high resistance to stress corrosion cracking.These steels are characterized by two-phase microstructures composed by almost the same level of ferrite and austenite.Duplex steel 2205 samples evaluated are: as received, cold rolled (33%) and heat-treated at 800°C for 10 hours.A metallograph...

  10. Ferrite and austenite phase identification in duplex stainless steel using SPM techniques

    Science.gov (United States)

    Guo, L. Q.; Lin, M. C.; Qiao, L. J.; Volinsky, Alex A.

    2013-12-01

    It can be challenging to properly identify the phases in electro-polished duplex stainless steel using optical microscopy or other characterization techniques. This letter describes magnetic force microscopy to properly identify the phases in electropolished duplex stainless steel. The results are also confirmed with the current sensing atomic force and scanning Kelvin probe force microscopy. The difference in topography heights between the ferrite and austenite phases is attributed to the different etching rates during electropolishing, although these phases have different mechanical properties. The current in the austenite is much higher compared with the ferrite, thus current sensing atomic force microscopy can also be used to properly identify the phases.

  11. Problems in repair-welding of duplex-treated tool steels

    Directory of Open Access Journals (Sweden)

    T. Muhič

    2009-01-01

    Full Text Available The present paper addresses problems in laser welding of die-cast tools used for aluminum pressure die-castings and plastic moulds. To extend life cycle of tools various surface improvements are used. These surface improvements significantly reduce weldability of the material. This paper presents development of defects in repair welding of duplex-treated tool steel. The procedure is aimed at reduction of defects by the newly developed repair laser welding techniques. Effects of different repair welding process parameters and techniques are considered. A microstructural analysis is conducted to detect defect formation and reveal the best laser welding method for duplex-treated tools.

  12. Impact of Transport Control Protocol on Full Duplex Performance in 5G Networks

    DEFF Research Database (Denmark)

    Gatnau, Marta; Berardinelli, Gilberto; Mahmood, Nurul Huda;

    2016-01-01

    Full duplex (FD) communication has attracted the attention of the industry and the academia as an important feature in the design of the future 5th generation (5G) wireless communication system. Such technology allows a device to simultaneously transmit and receive in the same frequency band......, with the potential of providing higher throughput and lower latency compared to traditional half duplex (HD) systems. In this paper, the interaction between Transport Control Protocol (TCP) and FD in 5G ultra-dense small cell networks is studied. TCP is a well-known transport layer protocol for providing reliability...

  13. Microstructural and Tribological Characterization of Duplex Coatings with Additional Ion Bombardment

    Institute of Scientific and Technical Information of China (English)

    B.Skorie; D.Kakas; M.akita

    2004-01-01

    A duplex surface treatment involves the sequential application of two surface technologies to produce a surface composition with combined properties. A typical duplex process involves plasma nitriding and the PVD coating treatment of steels. In the paper are presented characteristics of hard coatings, type TiN, produced by classic technology PVD (physical vapour deposition) and IBAD (ion beam assisted deposition). Subsequent ion implantation was provided with N5+ ions. The dependence of friction coefficient was investigated by means of tribometer (pin-on-ring). The sliding pair was TiN thin coating on steel pin combined with steel ring without coating. The ring was produced from hardenable steel.

  14. Microstructural and Tribological Characterization of Duplex Coatings with Additional Ion Bombardment

    Institute of Scientific and Technical Information of China (English)

    B.(S)kori(c); D.Kaka(s); M.Rakita

    2004-01-01

    A duplex surface treatment involves the sequential application of two surface technologies to produce a surface composition with combined properties. A typical duplex process involves plasma nitriding and the PVD coating treatment of steels. In the paper are presented characteristics of hard coatings, type TiN, produced by classic technology PVD (physical vapour deposition) and IBAD (ion beam assisted deposition). Subsequent ion implantation was provided with N5+ions. The dependence of friction coefficient was investigated by means of tribometer (pin-on-ring). The sliding pair was TiN thin coating on steel pin combined with steel ring without coating. The ring was produced from hardenable steel.

  15. Influence Of Heat Treatment On Duplex Stainless Steel To Study The Material Properties

    Directory of Open Access Journals (Sweden)

    Jithin M

    2015-02-01

    Full Text Available Abstract The various heat treatment processes are annealing normalizing hardening tempering spheroidising surface hardening flame and induction hardening nitriding cyaniding carbonitriding carburizing etc Heat treatment on duplex stainless steel is to improve ductility toughness strength hardness and to relieve internal stress developed in the material. Here basically the experiment of hardness test impact test wear test and compression is done to get idea about heat treated duplex stainless steel which has extensive uses in all industries and scientific research and development fields.

  16. Effects of low temperature aging on the mechanical properties and corrosion resistance of duplex and lean duplex stainless steels UNS S32205 and UNS S32304 Efeitos de envelhecimentos em baixas temperaturas nas propriedades mecânicas e resistência à corrosão dos aços duplex e lean duplex UNS S32205 e UNS S32304

    OpenAIRE

    Francis Gabriel Wasserman; Sergio Souto Maior Tavares; Juan Manuel Pardal; Fernando Benedicto Mainier; Ricardo Augusto Faria; Cristiana dos Santos Nunes

    2013-01-01

    Duplex stainless steels (DSS) with austenite-ferrite microstructure are high strength and corrosion resistant steels frequently used as pipes and accessories in chemical/petrochemical on/and off-shore industries. Low temperature heat treatments (400-475ºC) may increase the hardness and wear resistance of duplex steels, due to a spinodal decomposition reaction of the ferrite, whose small particles α' precipitate in the matrix. In this work, several heat treatments at 400ºC and 475ºC with ...

  17. Caracterización mediante HRTEM de un acero AISI4140 nitrurado por postdescarga micro-ondas

    Directory of Open Access Journals (Sweden)

    Béjar-Gómez, L.

    2005-12-01

    Full Text Available An analysis of the nitrides formed in an AISI 4140 steel nitrided by postdischarge microwave nitriding treatment was carried out by high resolution transmission electron microscopy (HRTEM, fast Fourier transform (FFT and nanoanalysis. The steel samples were nitrided below of the eutectoid transformation point (590 °C, after nitriding the samples were cooling slowly inside in the reactor whit an argon atmosphere. The analysis were carried out in a FEG-TEM PHILIPS TECNAI F20 at 200 Kv. The results showed the morphology and size of the nitrides ε-Fe2-3N and γ’-Fe4N, which had coherency whit the matrix. By other hand the following crystallographic relations were determined: (110 Fe-α ║ (1001 ε-Fe2-3N ║ (110 γ’-Fe4N and [1-1 0]Fe-α ║ [1 0-1 0] ε-Fe2-3N ║ [0 1 1] Fe4N.

    Un análisis de las fases de nitruros formados en un acero AISI 4140, nitrurado mediante condiciones de postdescarga micro-ondas, se llevó a cabo por microscopía electrónica de transmisión de alta resolución (HRTEM, rápida transformada de Fourier (FFT y nanoanálisis. Las muestras de acero fueron nitruradas por debajo del punto de transformación eutectoide (590 °C; después del tratamiento de nitruración las piezas fueron enfriadas lentamente dentro del reactor con una atmósfera de argón. Los análisis se realizaron en un microscopio Philips con cañón de emisión de campo Tecnai F20 a 200 Kv (PHILIPS FEG-TEM TECNAI F20. Los resultados mostraron la morfología y tamaño de los nitruros de hierro ε-Fe2-3N y γ’-Fe4N, los cuáles mostraron coherencia con la matriz. Además, se obtuvo la siguiente relación de coherencia entre precipitados y matriz: (110 Fe-α ║ (1001 ε-Fe2-3N ║ (110 γ’-Fe4N y [1-1 0]Fe-α ║ [1 0-1 0] ε-Fe2-3N ║ [0 1 1] Fe4N.

  18. Mecanismos de corrosión e inhibición electroquímica del acero galvanorrecocido

    Directory of Open Access Journals (Sweden)

    Arenas, M. A.

    2006-06-01

    Full Text Available The corrosion mechanism of galvannealed in 0,6 M NaCl has been evaluated by means of electrochemical impedance spectroscopy (EIS. After 48 hours and for longer immersion time, up to 1 month, in sodium chloride, the system is controlled by a diffusion process at finite layer. Moreover, the effectiveness of cerium salts as inhibitor added in the electrolyte has been studied. Inhibition percentages of about 85% for 500 and 1000 ppm at 24 hours have been found. On the hand, changes in the corrosion mechanism due to the cerium presence were shown.

    Se ha estudiado el mecanismo de corrosión de un acero galvanorrecocido, en 0,6 M de cloruro sódico, mediante espectroscopia de impedancia electroquímica. Los resultados revelan que el sistema, para tiempos mayores de 48 h de inmersión y hasta 1 mes en NaCl, está controlado por un proceso de difusión en capa finita. A su vez, se ha estudiado la efectividad de sales de cerio como inhibidor añadido en el medio agresivo, obteniéndose porcentajes de inhibición del 85% para concentraciones de 500 y 1.000 ppm a las 24 h de exposición. Además, los espectros de impedancia electroquímica revelan un cambio en el mecanismo de corrosión del galvanorrecocido por la adición del cerio en el medio.

  19. A corrosão do aço inoxidável austenítico 304 em biodiesel The corrosion of austenitic 304 stainless steel in biodiesel

    Directory of Open Access Journals (Sweden)

    André Lazarin Gallina

    2010-03-01

    Full Text Available As distribuidoras de combustíveis utilizam containers de aço inoxidável para o armazenamento de biocombustíveis, entretanto, na literatura, há poucos relatos sobre os aspectos corrosivos desse aço em biodiesel. O objetivo desse trabalho é estudar o comportamento corrosivo do aço inoxidável austenítico 304 na presença de biodiesel, não lavado e lavado com soluções aquosas de ácido cítrico, oxálico, acético e ascórbico 0,01 mol L-1e comparar com os resultados obtidos para o cobre (ASTM D130. Empregaram-se técnicas como: espectrometria de absorção atômica (EAA e microscopia óptica (MO. Os resultados de EAA mostraram uma baixa taxa de corrosão para o aço inoxidável, os elementos de liga estudados foram Cr, Ni e Fe, a maior taxa observada foi para o cromo, 1,78 ppm/dia em biodiesel não lavado ou lavado. As MO do aço 304, quando comparados com as do cobre, comprovaram a baixa taxa de corrosão para o sistema aço 304/biodiesel, entretanto comprovaram que, tanto o aço 304, quanto o cobre, sofrem corrosão em amostras de biodiesel.Fuel distribution uses 304 stainless steel containers for the storage of biofuels, however, there are few reports in the literature about the corrosive aspects this steel in biodiesel. The objective of this research is to study the corrosive behavior of 304 austenitic stainless steel in the presence of biodiesel, unwashed and washed, with aqueous solutions of citric, oxalic, acetic and ascorbic acids 0,01 mol L-1, and compare with results obtained for the copper (ASTM D130. The employedtechniques were: atomic absorption spectrometry (AAS and optical microscopy (OM. The results of EAA showed a low rate of corrosion for the stainless steel, the alloys elements studied were Cr, Ni and Fe, the highest rate was observed for the chrome, 1.78 ppm / day in biodiesel with or without washing. The OM of the 304 steel, when compared with that of copper, has a low corrosion rate in the 304 steel

  20. Caracterización de aceros dual-phase obtenidos por laminación en caliente

    Directory of Open Access Journals (Sweden)

    Houbaert, Y.

    2011-02-01

    Full Text Available Samples were obtained from C-Mn-Si steel available in the market. Through a hot rolling and coiling process, it was possible to obtain Dual-Phase steel with microstructural and mechanical properties in the theoretical range typical of this material. The thermomechanical process consisted of a strong reduction by multiples pass of hot rolling at temperatures above Ar3, controlled-cooling the sheets during 5 s (at a rate of 20 °C/s in the equilibrium range α+γ. Temperature Ar3 measured by differential scanning calorimetry was 890 °C. Quenching was then carried out in the coiling temperatures range (500-675 °C, cooling the samples in accordance to an established curve that corresponds to the actual cooling curve of a coil. The microstructural characterization of the samples obtained was carried out by optical microscopy, scanning electron microscopy and atomic force microscopy. Additionally, texture measurements were carried out by X-ray diffraction in order to study the resulting orientations due to the finishing rolling temperature and coiling temperature, determining the influence on these parameters of the different texture components. The microstructural results were complemented with the normal and planar anisotropy indexes measured in according to the ASTM E-517 standard. The intensities of the different texture components were correlated with the values of anisotropy indexes, finding that it is possible to obtain only a slightly enhancement in the normal anisotropy index through an appropriate combination of finish rolling and coiling temperatures.

    Se tomaron muestras de acero al C-Mn-Si disponible en el mercado y mediante un proceso de laminación en caliente y bobinado, se obtuvo acero Dual Phase con microestructura y propiedades mecánicas dentro del rango teórico esperado de este material. El proceso termomecánico consistió en producir una fuerte reducción a temperaturas mayores a Ar3