WorldWideScience

Sample records for absorptivity optical

  1. Cavity-enhanced absorption for optical refrigeration

    CERN Document Server

    Seletskiy, Denis V; Sheik-Bahae, Mansoor

    2009-01-01

    A 20-fold increase over the single path optical absorption is demonstrated with a low loss medium placed in a resonant cavity. This has been applied to laser cooling of Yb:ZBLAN glass resulting in 90% absorption of the incident pump light. A coupled-cavity scheme to achieve active optical impedance matching is analyzed.

  2. Resonant Optical Absorption in Semiconductor Quantum Wells

    Institute of Scientific and Technical Information of China (English)

    YU Li-Yuan; CAO Jun-Cheng

    2004-01-01

    @@ We have calculated the intraband photon absorption coefficients of hot two-dimensional electrons interacting with polar-optical phonon modes in quantum wells. The dependence of the photon absorption coefficients on the photon wavelength λ is obtained both by using the quantum mechanical theory and by the balance-equation theory. It is found that the photon absorption spectrum displays a local resonant maximum, corresponding to LO energy, and the absorption peak vanishes with increasing the electronic temperature.

  3. Electric modulation of optical absorption in nanowires

    Science.gov (United States)

    Sakr, M. R.

    2016-11-01

    We have calculated the effect of an external electric field on the intersubband optical absorption of a nanowire subjected to a perpendicular magnetic field and Rashba effect. The absorption peaks due to optical transitions that are forbidden in the absence of the intersubband coupling experience strong amplitude modulation. This effect is quadratic in electric fields applied along the direction of quantum confinement or perpendicularly to tune the Rashba parameter. The electric field also induces frequency modulation in the associated spectrum. On the other hand, transitions that are normally allowed show, to a large extent, a parallel band effect, and accordingly they are responsible for strong optical absorption.

  4. Geometrical interpretation of optical absorption

    Energy Technology Data Exchange (ETDEWEB)

    Monzon, J. J.; Barriuso, A. G.; Sanchez-Soto, L. L. [Departamento de Optica, Facultad de Fisica, Universidad Complutense, E-28040 Madrid (Spain); Montesinos-Amilibia, J. M. [Departamento de Geometria y Topologia, Facultad de Matematicas, Universidad Complutense, E-28040 Madrid (Spain)

    2011-08-15

    We reinterpret the transfer matrix for an absorbing system in very simple geometrical terms. In appropriate variables, the system appears as performing a Lorentz transformation in a (1 + 3)-dimensional space. Using homogeneous coordinates, we map that action on the unit sphere, which is at the realm of the Klein model of hyperbolic geometry. The effects of absorption appear then as a loxodromic transformation, that is, a rhumb line crossing all the meridians at the same angle.

  5. Optical absorption spectra of Ag-11 isomers

    DEFF Research Database (Denmark)

    Martinez, Jose Ignacio; Fernandez, E. M.

    2009-01-01

    The optical absorption spectra of the three most; stable structural isomers of the Ag-11 cluster were calculated using the time-dependent, density functional theory within the Casida formalism. The slightly different, spectra, of the isomers may permit the identification of the ground-stale confi......The optical absorption spectra of the three most; stable structural isomers of the Ag-11 cluster were calculated using the time-dependent, density functional theory within the Casida formalism. The slightly different, spectra, of the isomers may permit the identification of the ground...

  6. Calculated optical absorption of different perovskite phases

    DEFF Research Database (Denmark)

    Castelli, Ivano Eligio; Thygesen, Kristian Sommer; Jacobsen, Karsten Wedel

    2015-01-01

    We present calculations of the optical properties of a set of around 80 oxides, oxynitrides, and organometal halide cubic and layered perovskites (Ruddlesden-Popper and Dion-Jacobson phases) with a bandgap in the visible part of the solar spectrum. The calculations show that for different classes...... of perovskites the solar light absorption efficiency varies greatly depending not only on bandgap size and character (direct/indirect) but also on the dipole matrix elements. The oxides exhibit generally a fairly weak absorption efficiency due to indirect bandgaps while the most efficient absorbers are found...... in the classes of oxynitride and organometal halide perovskites with strong direct transitions....

  7. Universal Zero Conductivity Condition for Optical Absorption

    CERN Document Server

    Guo, Yu; Jacob, Zubin

    2016-01-01

    Harnessing information and energy from light within a nanoscale mode volume is a fundamental challenge for nanophotonic applications ranging from solar photovoltaics to single photon detectors. Here, we show the existence of a universal condition in materials that sheds light on fundamental limits of electromagnetic to matter energy conversion (transduction). We show that the upper limit of absorption rate (transduction rate) in any nanoscale absorber converting light to matter degrees of freedom is revealed by the zero of optical conductivity at complex frequencies ($\\sigma(\\omega^\\prime + i\\omega^{\\prime\\prime})= 0$). We trace the origin of this universal zero conductivity condition to causality requirements on any passive linear response function and propose an experiment of absorption resonances using plasmonic nanoparticles to experimentally verify this universal zero conductivity condition. Our work is widely applicable to linear systems across the electromagnetic spectrum and allows for systematic opti...

  8. NOVEL SPECTRUM ABSORPTION OPTICAL FIBER METHANE SENSOR

    Institute of Scientific and Technical Information of China (English)

    Wang Shutao; Che Rensheng

    2005-01-01

    Based on spectrum principle and analyzing the infrared absorption spectrum of methane, a kind of optical fiber methane gas sensor and its system are developed. DFBLD(Distributed feedback laser diode) in 1 300 nm waveband is used as illuminant and phase-detecting technology is used to carry out harmonic wave detecting the concentration of methane. The sensitivity can arrive at 10-5.Experiments results show that the performance targets of the sensor such as sensitivity can basically satisfy the requests of methane detection.

  9. Stochastic approach to phonon-assisted optical absorption

    OpenAIRE

    Zacharias, Marios; Patrick, Christopher E.; Giustino, Feliciano

    2015-01-01

    We develop a first-principles theory of phonon-assisted optical absorption in semiconductors and insulators which incorporates the temperature dependence of the electronic structure. We show that the Hall-Bardeen-Blatt theory of indirect optical absorption and the Allen-Heine theory of temperature-dependent band structures can be derived from the present formalism by retaining only one-phonon processes. We demonstrate this method by calculating the optical absorption coefficient of silicon us...

  10. Quantitative photoacoustic microscopy of optical absorption coefficients from acoustic spectra in the optical diffusive regime

    OpenAIRE

    Guo, Zijian; Favazza, Christopher; Garcia-Uribe, Alejandro; Lihong V. Wang

    2012-01-01

    Photoacoustic (PA) microscopy (PAM) can image optical absorption contrast with ultrasonic spatial resolution in the optical diffusive regime. Conventionally, accurate quantification in PAM requires knowledge of the optical fluence attenuation, acoustic pressure attenuation, and detection bandwidth. We circumvent this requirement by quantifying the optical absorption coefficients from the acoustic spectra of PA signals acquired at multiple optical wavelengths. With the acoustic spectral method...

  11. Effect of idler absorption in pulsed optical parametric oscillators.

    Science.gov (United States)

    Rustad, Gunnar; Arisholm, Gunnar; Farsund, Øystein

    2011-01-31

    Absorption at the idler wavelength in an optical parametric oscillator (OPO) is often considered detrimental. We show through simulations that pulsed OPOs with significant idler absorption can perform better than OPOs with low idler absorption both in terms of conversion efficiency and beam quality. The main reason for this is reduced back conversion. We also show how the beam quality depends on the beam width and pump pulse length, and present scaling relations to use the example simulations for other pulsed nanosecond OPOs.

  12. Single metal nanoparticle absorption spectroscopy and optical characterization

    Science.gov (United States)

    Muskens, O. L.; Del Fatti, N.; Vallée, F.; Huntzinger, J. R.; Billaud, P.; Broyer, M.

    2006-02-01

    Optical absorption spectra of small single metal nanoparticles are measured using a far-field technique combining a spatial modulation microscope with a broadband light source. Quantitative determination of the spectral and polarization dependencies of the absorption cross section of individual gold nanoparticles permits precise determination of their geometrical properties in excellent agreement with transmission electron microscopy measurements.

  13. Quantitative photoacoustic microscopy of optical absorption coefficients from acoustic spectra in the optical diffusive regime.

    Science.gov (United States)

    Guo, Zijian; Favazza, Christopher; Garcia-Uribe, Alejandro; Wang, Lihong V

    2012-06-01

    Photoacoustic (PA) microscopy (PAM) can image optical absorption contrast with ultrasonic spatial resolution in the optical diffusive regime. Conventionally, accurate quantification in PAM requires knowledge of the optical fluence attenuation, acoustic pressure attenuation, and detection bandwidth. We circumvent this requirement by quantifying the optical absorption coefficients from the acoustic spectra of PA signals acquired at multiple optical wavelengths. With the acoustic spectral method, the absorption coefficients of an oxygenated bovine blood phantom at 560, 565, 570, and 575 nm were quantified with errors of acoustic spectral method provides greater quantification accuracy in the optical diffusive regime. The limitations of the acoustic spectral method was also discussed.

  14. Weak absorption test and defect analysis of optical coatings

    Institute of Scientific and Technical Information of China (English)

    HE Hong-bo; LI Xia; FAN Shu-hai; ZHAO Yuan-an; SHAO Jian-da; FAN Zheng-xiu

    2005-01-01

    Surface thermal lensing technique was developed into a high-sensitive apparatus for weak absorption test and defect analysis of optical coatings. A continuous-wave 1 064 nm Nd:YAG laser and a He-Ne laser were employed as pump source and probe source, respectively. Low noise photoelectrical components and a lock-in amplifier were used for photo-thermal deformation signal detection. In order to improve sensitivity, the apparatus configuration was optimized by choosing appropriate parameters, including pump beam spot size, chopper frequency, detection distance, waist radius and position of probe beam. Coating samples were mounted on a x-y stage. Different procedures, such as single spot, linear scan and 2-dimension area scan, could be performed manually or automatically. Various optical coatings were prepared by both electron beam evaporation and ion beam sputtering deposition. High sensitivity was obtained and low to 1×10-7 weak absorption was tested in low-loss coating samples. For the sensitivity extreme of the system, 1×10-8 absorption was reason out to be measured by surface thermal lensing technique. Very small standard deviation was achieved for the reproducibility evaluation. Moreover, a spatial resolution of 25 micron was proved according to the area scan which traced out the profile of photo-thermal defects inside optical coatings. The system was employed in the analyses of optical absorption, absorption uniformity and defect characterization, and revealed the relationship between laser-induced damage and absorption of optical coatings.

  15. Exploring the origin of high optical absorption in conjugated polymers

    KAUST Repository

    Vezie, Michelle S.

    2016-05-16

    The specific optical absorption of an organic semiconductor is critical to the performance of organic optoelectronic devices. For example, higher light-harvesting efficiency can lead to higher photocurrent in solar cells that are limited by sub-optimal electrical transport. Here, we compare over 40 conjugated polymers, and find that many different chemical structures share an apparent maximum in their extinction coefficients. However, a diketopyrrolopyrrole-thienothiophene copolymer shows remarkably high optical absorption at relatively low photon energies. By investigating its backbone structure and conformation with measurements and quantum chemical calculations, we find that the high optical absorption can be explained by the high persistence length of the polymer. Accordingly, we demonstrate high absorption in other polymers with high theoretical persistence length. Visible light harvesting may be enhanced in other conjugated polymers through judicious design of the structure.

  16. Stochastic Approach to Phonon-Assisted Optical Absorption

    Science.gov (United States)

    Zacharias, Marios; Patrick, Christopher E.; Giustino, Feliciano

    2015-10-01

    We develop a first-principles theory of phonon-assisted optical absorption in semiconductors and insulators which incorporates the temperature dependence of the electronic structure. We show that the Hall-Bardeen-Blatt theory of indirect optical absorption and the Allen-Heine theory of temperature-dependent band structures can be derived from the present formalism by retaining only one-phonon processes. We demonstrate this method by calculating the optical absorption coefficient of silicon using an importance sampling Monte Carlo scheme, and we obtain temperature-dependent line shapes and band gaps in good agreement with experiment. The present approach opens the way to predictive calculations of the optical properties of solids at finite temperature.

  17. Thermally detected optical absorption in sophisticated nitride structures

    Energy Technology Data Exchange (ETDEWEB)

    Vasson, A.; Leymarie, J. [LASMEA-UMR 6602 CNRS-UBP, 63177 Aubiere Cedex (France); Shubina, T.V. [Ioffe Physico-Technical Institute, RAS, St. Petersburg 194021 (Russian Federation)

    2005-02-01

    The thermally detected optical absorption (TDOA) is applied to elucidate peculiarities of absorption in nitride structures of unusual morphology like GaN nanocolumns or InN layers with various imperfections. A study of GaN structures permits us to establish position of an absorption edge in TDOA spectra. We demonstrate that the absorption edge is different in GaN regions of opposite polarities. In InN with metallic In inclusions, this technique enable separation of InN interband absorption and extinction related to the Mie resonances, if the latter are below the principal absorption edge. (copyright 2005 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  18. Nonlinear optical absorption of photosynthetic pigment molecules in leaves.

    Science.gov (United States)

    Ye, Zi-Piao

    2012-04-01

    A mathematical formulation of the relationship between optical absorption coefficient of photosynthetic pigment molecules and light intensity was developed. It showed that physical parameters of photosynthetic pigment molecule (i.e., light absorption cross-section of photosynthetic pigment molecule, its average lifetime in the excited state, total photosynthetic pigment molecules, the statistical weight, or degeneracy of energy level of photosynthetic pigment molecules in the ground state and in the excited state) influenced on both the light absorption coefficient and effective light absorption cross-section of photosynthetic pigment molecules. Moreover, it also showed that both the light absorption coefficient and effective light absorption cross-section of photosynthetic pigment molecules were not constant, they decreased nonlinearly with light intensity increasing. The occupation numbers of photosynthetic pigment molecules in the excited states increased nonlinearly with light intensity increasing.

  19. Tunable optical absorption in silicene molecules

    KAUST Repository

    Mokkath, Junais Habeeb

    2016-07-13

    Two-dimensional materials with a tunable band gap that covers a wide range of the solar spectrum hold great promise for sunlight harvesting. For this reason, we investigate the structural, electronic, and optical properties of silicene molecules using time dependent density functional theory. We address the influence of the molecular size, buckling, and charge state as well as that of a dielectric environment. Unlike planar graphene molecules, silicene molecules prefer to form low-buckled structures with strong visible to ultraviolet optical response. We also identify molecular plasmons.

  20. Luminescence and optical absorption determination in porous silicon

    Energy Technology Data Exchange (ETDEWEB)

    Nogal, U.; Calderon, A.; Marin, E.; Rojas T, J. B.; Juarez, A. G., E-mail: u_nogal@hotmail.com [IPN, Centro de Investigacion en Ciencia Aplicada y Tecnologia Avanzada, Calz. Legaria No. 694, Col. Irrigacion, 11500 Mexico D. F. (Mexico)

    2012-10-15

    We applied the photoacoustic spectroscopy technique in order to obtain the optical absorption spectrum in porous silicon samples prepared by electrochemical anodic etching on n-type, phosphorous doped, (100)-oriented crystal-line silicon wafer with thickness of 300 {mu}m and 1-5 {omega}cm resistivity. The porous layers were prepared with etching times of 13, 20, 30, 40 and 60 minutes. Also, we realized a comparison among the optical absorption spectrum with the photoluminescence and photo reflectance ones, both obtained at room temperature. Our results show that the absorption spectrum of the samples of porous silicon depends notably of the etching time an it consist of two distinguishable absorption bands, one in the Vis region and the other one in the UV region. (Author)

  1. Defects and the optical absorption in nanocrystalline ZnO

    Energy Technology Data Exchange (ETDEWEB)

    Dutta, Sreetama [Department of Physics, University of Calcutta, 92 Acharya Prafulla Chandra Road, Kolkata 700 009 (India); Chattopadhyay, Sanjay [Department of Physics, Taki Government College, Taki 743429 (India); Sutradhar, Manas [Department of Chemistry, University of Calcutta, 92 Acharya Prafulla Chandra Road, Kolkata 700 009 (India); Sarkar, Anindya [Department of Physics, Bangabasi Morning College, 19 Rajkumar Chakraborty Sarani, Kolkata 700 009 (India); Chakrabarti, Mahuya [Variable Energy Cyclotron Centre, 1/AF, Bidhannagar, Kolkata 700 064 (India); Sanyal, Dirtha [Variable Energy Cyclotron Centre, 1/AF, Bidhannagar, Kolkata 700 064 (India); Jana, Debnarayan [Department of Physics, University of Calcutta, 92 Acharya Prafulla Chandra Road, Kolkata 700 009 (India)

    2007-06-13

    The correlation between the structural and optical properties of mechanically milled high purity ZnO powder is reported in the present work. Reduction of average grain size and enhancement of strain as a result of milling have been estimated from the broadening of x-ray powder diffraction patterns. After milling, the optical bandgap, revealed from absorption spectroscopy, has been red-shifted and the width of the localized states, calculated from the analysis of the Urbach tail below the absorption edge, has been extended more and more into the bandgap. Moreover, the band tailing parameter is seen to vary exponentially with the inverse of the grain size. Finally, the positron annihilation technique has been employed to identify the nature of defects present (or generated due to milling) in the system and thereby to correlate the defect mediated modification of optical absorption in ZnO.

  2. Study on Optical Absorption Behavior of Dyestuff in Fabric

    Institute of Scientific and Technical Information of China (English)

    YANG Hong-ying; ZHU Su-kang; ZUO Lei; ZHU Ping-ping; PAN Ning

    2008-01-01

    Fabric is a kind of turbid materials with strong light scattering,to which the Kubelka-Munk theory can be applied to describe it optical behavior.In this paper,the light absorption coefficients of dyestuff in fabrics are obtained by test and calculation thnmgh a special method proposed by the authors.Then the optical behaviours of dyestuff in fabric are studied.Results show that,the absorption coeffident of dye in fabric is non-scalable and exponential to dye concentrafion in fabric which is totally different from that of the dye in transparent medm like water.

  3. Differential optical absorption spectrometer for measurement of tropospheric pollutants.

    Science.gov (United States)

    Evangelisti, F; Baroncelli, A; Bonasoni, P; Giovanelli, G; Ravegnani, F

    1995-05-20

    Our institute has recently developed a differential optical absorption spectrometry system called the gas analyzer spectrometer correlating optical absorption differences (GASCOAD), which features as a detector a linear image sensor that uses an artificial light source for long-path tropospheric-pollution monitoring. The GASCOAD, its method of eliminating interference from background sky light, and subsequent spectral analysis are reported and discussed. The spectrometer was used from 7 to 22 February 1993 in Milan, a heavily polluted metropolitan area, to measure the concentrations of SO(2), NO(2), O(3), and HNO(2) averaged over a 1.7-km horizontal light path. The findings are reported and briefly discussed.

  4. Semiconductor optical modulator by using electron depleting absorption control

    OpenAIRE

    Yamada, Minoru; Noda, Kazuhiro; Kuwamura, Yuji; Nakanishi, Hirohumi; Imai, Kiyohumi

    1992-01-01

    Operation of a newly proposed semiconductor optical modulator based on absorption control by electron depletion around a p-n junction is demonstrated, forming preliminary structures of waveguide-type as well as panel-type (or surface-illuminated type) devices. The optical absorption is occurred at the intrinsic energy levels in the band structure not at the extended state into the band-gap. Performance of 35 dB on-off extinction ratio for 4 V variation of the applied voltage was obtained in a...

  5. Silver Nanoparticles with Broad Multiband Linear Optical Absorption

    KAUST Repository

    Bakr, Osman M.

    2009-07-06

    A simple one-pot method produces silver nanoparticles coated with aryl thiols that show intense, broad nonplasmonic optical properties. The synthesis works with many aryl-thiol capping ligands, including water-soluble 4-mercaptobenzoic acid. The nanoparticles produced show linear absorption that is broader, stronger, and more structured than most conventional organic and inorganic dyes.

  6. Two-Photon-Absorption Scheme for Optical Beam Tracking

    Science.gov (United States)

    Ortiz, Gerardo G.; Farr, William H.

    2011-01-01

    A new optical beam tracking approach for free-space optical communication links using two-photon absorption (TPA) in a high-bandgap detector material was demonstrated. This tracking scheme is part of the canonical architecture described in the preceding article. TPA is used to track a long-wavelength transmit laser while direct absorption on the same sensor simultaneously tracks a shorter-wavelength beacon. The TPA responsivity was measured for silicon using a PIN photodiode at a laser beacon wavelength of 1,550 nm. As expected, the responsivity shows a linear dependence with incident power level. The responsivity slope is 4.5 x 10(exp -7) A/W2. Also, optical beam spots from the 1,550-nm laser beacon were characterized on commercial charge coupled device (CCD) and complementary metal-oxide semiconductor (CMOS) imagers with as little as 13.7 microWatts of optical power (see figure). This new tracker technology offers an innovative solution to reduce system complexity, improve transmit/receive isolation, improve optical efficiency, improve signal-to-noise ratio (SNR), and reduce cost for free-space optical communications transceivers.

  7. Optical absorption of hyperbolic metamaterial with stochastic surfaces

    DEFF Research Database (Denmark)

    Liu, Jingjing; Naik, Gururaj V.; Ishii, Satoshi;

    2014-01-01

    We investigate the absorption properties of planar hyperbolic metamaterials (HMMs) consisting of metal-dielectric multilayers, which support propagating plane waves with anomalously large wavevectors and high photonic-density-of-states over a broad bandwidth. An interface formed by depositing ind...... of stochastically perturbed HMM compared to that of metal. (C) 2014 Optical Society of America...... indium-tin-oxide nanoparticles on an HMM surface scatters light into the high-k propagating modes of the metamaterial and reduces reflection. We compare the reflection and absorption from an HMM with the nanoparticle cover layer versus those of a metal film with the same thickness also covered...

  8. Optical absorption analysis and optimization of gold nanoshells.

    Science.gov (United States)

    Tuersun, Paerhatijiang; Han, Xiang'e

    2013-02-20

    Gold nanoshells, consisting of a nanoscale dielectric core coated with an ultrathin gold shell, have wide biomedical applications due to their strong optical absorption properties. Gold nanoshells with high absorption efficiencies can help to improve these applications. We investigate the effects of the core material, surrounding medium, core radius, and shell thickness on the absorption spectra of gold nanoshells by using the light-scattering theory of a coated sphere. Our results show that the position and intensity of the absorption peak can be tuned over a wide range by manipulating the above-mentioned parameters. We also obtain the optimal absorption efficiencies and structures of hollow gold nanoshells and gold-coated SiO(2) nanoshells embedded in water at wavelengths of 800, 820, and 1064 nm. The results show that hollow gold nanoshells possess the maximum absorption efficiency (5.42) at a wavelength of 800 nm; the corresponding shell thickness and core radius are 4.8 and 38.9 nm, respectively. They can be used as the ideal photothermal conversation particles for biomedical applications.

  9. Remark on: the neutron spherical optical-model absorption.

    Energy Technology Data Exchange (ETDEWEB)

    Smith, A. B.; Nuclear Engineering Division

    2007-06-30

    The energy-dependent behavior of the absorption term of the spherical neutron optical potential for doubly magic {sup 208}Pb and the neighboring {sup 209}Bi is examined. These considerations suggest a phenomenological model that results in an intuitively attractive energy dependence of the imaginary potential that provides a good description of the observed neutron cross sections and that is qualitatively consistent with theoretical concepts. At the same time it provides an alternative to some of the arbitrary assumptions involved in many conventional optical-model interpretations reported in the literature and reduces the number of the parameters of the model.

  10. Optical Absorption Spectroscopy for Gas Analysis in Biomass Gasification

    DEFF Research Database (Denmark)

    Grosch, Helge

    the concentration of the mentioned compounds. However, continuous measurements of different species directly in the gas (in-situ) and at the same time are scarce. In this work, the basis of optical in-situ analysis with ultraviolet and infrared spectroscopy was build to determine the concentration of the most...... important gas species of the low-temperature circulating fluidized bed gasifier. At first, a special gas cell,the hot gas flow cell (HGC), was build up and veried. In this custom-made gas cell, the optical properties, the so-called absorption cross-sections, of the most important sulfur and aromatic...

  11. Optimization of extraordinary optical absorption in plasmonic and dielectric structures

    DEFF Research Database (Denmark)

    Dühring, Maria Bayard; Sigmund, Ole

    2013-01-01

    Extraordinary optical absorption (EOA) can be obtained by plasmonic surface structuring. However, studies that compare the performance of these plasmonic devices with similar structured dielectric devices are rarely found in the literature. In this work we show different methods to enhance the EOA...... silicon layer for certain optical wavelengths compared to metal strips. It is then demonstrated that by topology optimization it is possible to generate nonintuitive surface designs that perform even better than the simple strip designs for both silicon and metals. These results indicate that in general...... by optimizing the geometry of the surface structuring for both plasmonic and dielectric devices, and the optimized performances are compared. Two different problem types with periodic structures are considered. The first case shows that strips of silicon on a surface can increase the absorption in an underlying...

  12. Segregation during crystal growth from melt and absorption cross section determination by optical absorption method

    Institute of Scientific and Technical Information of China (English)

    ZHANG QingLi; YIN ShaoTang; SUN DunLu; WAN SongMing

    2008-01-01

    Segregation during crystal growth from melt under two conditions is studied by using crystal mass, which can be measured easily, as an independent variable, and a method to determine the effective segregation coefficient and absorption cross section of optical dopant is given. When the segregated solute disperses into the whole or just a part of melt homogenously, the concentration Cs in solid interface will change by different formulas. If the crystal growth interface is conical and segregated solute disperses into melt in total or part, the solute concentration at r=2/3R, where r is the distance from the growth cross section center and R the crystal radius, is independent on the shape of the crystal growth interface, and its variation at r=2/3R can be regarded as the result from crystal growth in flat interface. With Cs variation formula in solid and absorption cross section σ for optical dopant, the absorption coefficients along the crystal growth direction can be calculated, and the corresponding experimental value can be obtained through the crystal optical absorption spectra. By minimizing the half sum, whose independent variables are k, △W or σ, of the difference square between the calculated and experimental absorp-tion coefficients from one or more absorption peaks along the crystal growth di-rection, k and σ, or k and △W, can be determined at the same time through the Levenberg-Marquardt iteration method. Finally, the effective segregation coefficient k, △W and absorption cross sections of Nd:GGG were determined, the results fitted by two formula gave more closed effective segregation coefficient, and the value △W also indicates that the segregated dopant had nearly dispersed into the whole melt. Experimental results show that the method to determine effective segregation coefficient k, △W and absorption cross sections σ is convenient and reliable, and the two segregation formulas can describe the segregation during the crystal growth from

  13. Segregation during crystal growth from melt and absorption cross section determination by optical absorption method

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Segregation during crystal growth from melt under two conditions is studied by using crystal mass,which can be measured easily,as an independent variable,and a method to determine the effective segregation coefficient and absorption cross section of optical dopant is given.When the segregated solute disperses into the whole or just a part of melt homogenously,the concentration CS in solid interface will change by different formulas.If the crystal growth interface is conical and segregated solute disperses into melt in total or part,the solute concentration at r=2/3R,where r is the distance from the growth cross section center and R the crystal radius,is independent on the shape of the crystal growth interface,and its variation at r=2/3R can be regarded as the result from crystal growth in flat interface.With CS variation formula in solid and absorption cross section σ for optical dopant,the absorption coefficients along the crystal growth direction can be calculated,and the corresponding experimental value can be obtained through the crystal optical absorption spectra.By minimizing the half sum,whose independent variables are k,ΔW or σ,of the difference square between the calculated and experimental absorp-tion coefficients from one or more absorption peaks along the crystal growth di-rection,k and σ,or k and ΔW,can be determined at the same time through the Levenberg-Marquardt iteration method.Finally,the effective segregation coefficient k,ΔW and absorption cross sections of Nd:GGG were determined,the results fitted by two formula gave more closed effective segregation coefficient,and the value ΔW also indicates that the segregated dopant had nearly dispersed into the whole melt.Experimental results show that the method to determine effective segregation coefficient k,ΔW and absorption cross sections σ is convenient and reliable,and the two segregation formulas can describe the segregation during the crystal growth from melt relatively commendably.

  14. Optical microresonators as single-particle absorption spectrometers

    Science.gov (United States)

    Heylman, Kevin D.; Thakkar, Niket; Horak, Erik H.; Quillin, Steven C.; Cherqui, Charles; Knapper, Kassandra A.; Masiello, David J.; Goldsmith, Randall H.

    2016-12-01

    Optical measurements of nanoscale objects offer major insights into fundamental biological, material and photonic properties. In absorption spectroscopy, sensitivity limits applications at the nanoscale. Here, we present a new single-particle double-modulation photothermal absorption spectroscopy method that employs on-chip optical whispering-gallery-mode (WGM) microresonators as ultrasensitive thermometers. Optical excitation of a nanoscale object on the microresonator produces increased local temperatures that are proportional to the absorption cross-section of the object. We resolve photothermal shifts in the resonance frequency of the microresonator that are smaller than 100 Hz, orders of magnitude smaller than previous WGM sensing schemes. The application of our new technique to single gold nanorods reveals a dense array of sharp Fano resonances arising from the coupling between the localized surface plasmon of the gold nanorod and the WGMs of the resonator, allowing for the exploration of plasmonic-photonic hybridization. In terms of the wider applicability, our approach adds label-free spectroscopic identification to microresonator-based detection schemes.

  15. Optical absorption and scattering spectroscopies of single nano-objects.

    Science.gov (United States)

    Crut, Aurélien; Maioli, Paolo; Del Fatti, Natalia; Vallée, Fabrice

    2014-06-07

    Developments of optical detection and spectroscopy methods for single nano-objects are key advances for applications and fundamental understanding of the novel properties exhibited by nanosize systems. These methods are reviewed, focusing on far-field optical approaches based on light absorption and elastic scattering. The principles of the main linear and nonlinear methods are described and experimental results are illustrated in the case of metal nanoparticles, stressing the key role played by the object environment, such as the presence of a substrate, bound surface molecules or other nano-objects. Special attention is devoted to quantitative methods and correlation of the measured optical spectra of a nano-object with its morphology, characterized either optically or by electron microscopy, as this permits precise comparison with theoretical models. Application of these methods to optical detection and spectroscopy for single semiconductor nanowires and carbon nanotubes is also presented. Extension to ultrafast nonlinear extinction or scattering spectroscopies of single nano-objects is finally discussed in the context of investigation of their nonlinear optical response and their electronic, acoustic and thermal properties.

  16. TL, EPR and optical absorption in natural grossular crystal

    Energy Technology Data Exchange (ETDEWEB)

    Yauri, J.M. [Institute of Physics, University of Sao Paulo, Rua do Matao, Travessa R, 187, CEP 05508-900, Sao Paulo (Brazil); Department of Physics, University of San Agustin, Av. Independencia S/N, Arequipa (Peru); Cano, N.F. [Institute of Physics, University of Sao Paulo, Rua do Matao, Travessa R, 187, CEP 05508-900, Sao Paulo (Brazil)], E-mail: nilocano@dfn.if.usp.br; Watanabe, S. [Institute of Physics, University of Sao Paulo, Rua do Matao, Travessa R, 187, CEP 05508-900, Sao Paulo (Brazil)

    2008-10-15

    Grossular is one of six members of silicate Garnet group. Two samples GI and GII have been investigated concerning their luminescence thermally stimulated (TL). EPR and optical absorption and the measurements were carried out to find out whether or not same point defects are responsible for all three properties. Although X-rays diffraction analysis has shown that both GI and GII have practically the same crystal structure of a standard grossular crystal, they presented different behavior in many aspects. The TL glow curve shape, TL response to radiation dose, the effect of annealing at high temperatures before irradiation, the dependence of UV bleaching parameters on peak temperature, all of them differ going from GI to GII. The EPR signals around g=2.0 as well as at g=4.3 and 6.0 have much larger intensity in GI than in GII. Very high temperature (>800 deg. C) annealing causes large increase in the bulk background absorption in GI, however, only very little in GII. In the cases of EPR and optical absorption, the difference in their behavior can be attributed to Fe{sup 3+} ions; however, in the TL case one cannot and the cause was not found as yet.

  17. Optical Absorption Spectra of Hydrous Wadsleyite to 32 GPa

    Science.gov (United States)

    Thomas, S.; Goncharov, A. F.; Jacobsen, S. D.; Bina, C. R.; Frost, D. J.

    2009-05-01

    Optical absorption spectra of high-pressure minerals can be used as indirect tools to calculate radiative conductivity of the Earth's interior [e.g., 1]. Recent high-pressure studies show that e.g. ringwoodite, γ-(Mg,Fe)2SiO4, does not become opaque in the near infrared and visible region, as previously assumed, but remains transparent to 21.5 GPa [2]. Therefore, it has been concluded that radiative heat transfer does not necessarily become blocked at high pressures of the mantle and ferromagnesian minerals actually could contribute to the heat flow in the Earth's interior [2]. In this study we use gem-quality single-crystals of hydrous Fe-bearing wadsleyite, β-(Mg,Fe)2SiO4, that were synthesized at 18 GPa and 1400 °C in a multianvil apparatus. Crystals were analyzed by Mössbauer and Raman spectroscopy, electron microprobe analysis and single-crystal X-ray diffraction. For absorption measurements a double-polished 50 μm sized single-crystal of wadsleyite was loaded in a diamond-anvil cell with neon as pressure medium. Optical absorption spectra were recorded at ambient conditions as well as up to 32 GPa from 400 to 50000 cm-1. At ambient pressure the absorption spectrum reveals two broad bands at - 10000 cm-1 and -15000 cm-1, and an absorption edge in the visible-ultraviolet range. With increasing pressure the absorption spectrum changes, both bands continuously shift to higher frequencies as has been observed for ringwoodite [2], but is contrary to earlier presumptions for wadsleyite [3]. Here, we will discuss band assignment along with the influence of iron, compare our results to previous absorption studies of mantle materials [2], and analyze possible implications for radiative conductivity of the transition zone. References: [1] Goncharov et al. (2008), McGraw Yearbook Sci. Tech., 242-245. [2] Keppler & Smyth (2005), Am. Mineral., 90 1209-1212. [3] Ross (1997), Phys. Chem. Earth, 22 113-118.

  18. Optical absorption and emission of nitrogen-doped silicon nanocrystals.

    Science.gov (United States)

    Pi, Xiaodong; Chen, Xiaobo; Ma, Yeshi; Yang, Deren

    2011-11-01

    Silicon nanocrystals (Si NCs) may be both unintentionally and intentionally doped with nitrogen (N) during their synthesis and processing. Since the importance of Si NCs largely originates from their remarkable optical properties, it is critical to understand the effect of N doping on the optical behavior of Si NCs. On the basis of theoretical calculations, we show that the doping of Si NCs with N most likely leads to the formation of paired interstitial N at the NC surface, which causes both the optical absorption and emission of Si NCs to redshift. But these redshifts are smaller than those induced by doubly bonded O at the NC surface. It is found that high radiative recombination rates can be reliably obtained for Si NCs with paired interstitial N at the NC surface. The current results not only help to understand the optical behavior of Si NCs synthesized and processed in N-containing environments, but also inspire intentional N doping as an additional means to control the optical properties of Si NCs.

  19. Optical absorption in commercial single mode optical fibres for the LHC machine

    CERN Document Server

    Wijnands, T J; Kuhnhenn, J; Hoeffgen, S K; Weinand, U; TS

    2007-01-01

    The optical absorption of light at 1310 nm and 1550 nm in various commercially available Single Mode (SM) fibres samples has been studied. The absorption was measured as a function of dose, dose rate, temperature and light power. The samples were irradiated with gamma rays from a 60Co source and exposed to a complex radiation field from high energy physics. One fibre sample with an F-doped core exhibits extreme low absorption of light at 1310 nm during irradiation up to doses of at least 100 kGy.

  20. Imaging photothermal microscopy for absorption measurements of optical coatings

    Institute of Scientific and Technical Information of China (English)

    Chunxian Tao; Yuanan Zhao; Hongbo He; Dawei Li; Jianda Shao; Zhengxiu Fan

    2009-01-01

    @@ For absorption measurement of large-aperture optical coatings, a novel method of imaging photothermal microscopy based on image lock-in technique is presented.Detailed theoretical analysis and numerical calculation are made based on the image photothermal technique.The feasibility of this imaging method is proved through the coincidence between the theoretical results of single spot method and multi-channel method.The measuring speed of this imaging method can be increased hundreds of times compared with that of the raster scanning.This technique can expand the applications of photothermal technique.

  1. Correlated theory of linear optical absorption of octacene and nonacene

    Science.gov (United States)

    Chakraborty, Himanshu; Shukla, Alok

    2013-08-01

    The technological importance of higher acenes has led to resurgence of interest in synthesizing higher acenes such as octacene, nonacene etc. Recently, Tönshoff and Bettinger [2010 Angew. Chem. Int. Ed. 49 4125] have synthesized octacene and nonacene. Motivated by their work, we have performed large-scale calculations of linear optical absorption of octacene and nonacene. Methodology adopted in our work is based upon Pariser-Parr-Pople model (PPP) Hamiltonian, along with large-scale multi-reference singles-doubles configuration interaction (MRSDCI) approach.

  2. Enhanced optical absorption and electric field resonance in diabolo metal bar optical antennas.

    Science.gov (United States)

    Pan, Zeyu; Guo, Junpeng

    2013-12-30

    Resonance behaviors of the fundamental resonance mode of diabolo metal bar optical antennas are investigated by using finite-difference time-domain (FDTD) numerical simulations and a dipole oscillator model. It is found that as the waist of the diabolo metal bar optical antenna is reduced, optical energy absorption cross section and near field enhancement at resonance increase significantly. Also reduction of the diabolo waist width causes red-shift of the resonant wavelengths in the spectra of absorption cross-section, scattering cross-section, and the near electric field. A dipole oscillator model including the self-inductance force is used to fit the FDTD numerical simulation results. The dipole oscillator model characterizes well the resonance behaviors of narrow waist diabolo metal bar optical antennas.

  3. All-optical reservoir computer based on saturation of absorption.

    Science.gov (United States)

    Dejonckheere, Antoine; Duport, François; Smerieri, Anteo; Fang, Li; Oudar, Jean-Louis; Haelterman, Marc; Massar, Serge

    2014-05-05

    Reservoir computing is a new bio-inspired computation paradigm. It exploits a dynamical system driven by a time-dependent input to carry out computation. For efficient information processing, only a few parameters of the reservoir needs to be tuned, which makes it a promising framework for hardware implementation. Recently, electronic, opto-electronic and all-optical experimental reservoir computers were reported. In those implementations, the nonlinear response of the reservoir is provided by active devices such as optoelectronic modulators or optical amplifiers. By contrast, we propose here the first reservoir computer based on a fully passive nonlinearity, namely the saturable absorption of a semiconductor mirror. Our experimental setup constitutes an important step towards the development of ultrafast low-consumption analog computers.

  4. Mathematical Model of Fiber Optic Temperature Sensor Based on Optic Absorption and Experiment Testing

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    On the basis of analysis on the temperature monitoring methods for high voltage devices, a new type of fiber optic sensor structure with reference channel is given. And the operation principle of fiber optic sensor is analysed at large based on the absorption of semiconductor chip. The mathematical model of both devices and the whole system are also given. It is proved by the experiment that this mathematical model is reliable.

  5. Absorption of optical power in an S-20 photocathode

    CERN Document Server

    Harmer, S W

    2003-01-01

    By considering a monochromatic plane wave obliquely incident upon a planar layer of S-20 photocathode material, deposited upon a non-absorbing glass substrate, the distribution of optical power absorbed within the layer can be resolved. This is important to the question of photocathode efficiency, as the absorbed light excites photoelectrons within the photocathode which then may pass from the photocathode into the vacuum of the photomultiplier tube and be collected and multiplied. The calculation uses the measured complex permittivity of an extended red S-20 photocathode in the wavelength range, 375-900 nm. The results show that thin film effects are important within the photocathode, as they give rise to interesting power absorption profiles. This information is invaluable in predicting optimum photocathode thickness for wavelength selective applications. Electromagnetic waves that are obliquely incident upon the photocathode are also considered in both transverse electric and transverse magnetic polarizati...

  6. Optical re-injection in cavity-enhanced absorption spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Leen, J. Brian, E-mail: b.leen@lgrinc.com; O’Keefe, Anthony [Los Gatos Research, 67 E. Evelyn Avenue, Suite 3, Mountain View, California 94041 (United States)

    2014-09-15

    Non-mode-matched cavity-enhanced absorption spectrometry (e.g., cavity ringdown spectroscopy and integrated cavity output spectroscopy) is commonly used for the ultrasensitive detection of trace gases. These techniques are attractive for their simplicity and robustness, but their performance may be limited by the reflection of light from the front mirror and the resulting low optical transmission. Although this low transmitted power can sometimes be overcome with higher power lasers and lower noise detectors (e.g., in the near-infrared), many regimes exist where the available light intensity or photodetector sensitivity limits instrument performance (e.g., in the mid-infrared). In this article, we describe a method of repeatedly re-injecting light reflected off the front mirror of the optical cavity to boost the cavity's circulating power and deliver more light to the photodetector and thus increase the signal-to-noise ratio of the absorption measurement. We model and experimentally demonstrate the method's performance using off-axis cavity ringdown spectroscopy (OA-CRDS) with a broadly tunable external cavity quantum cascade laser. The power coupled through the cavity to the detector is increased by a factor of 22.5. The cavity loss is measured with a precision of 2 × 10{sup −10} cm{sup −1}/√(Hz;) an increase of 12 times over the standard off-axis configuration without reinjection and comparable to the best reported sensitivities in the mid-infrared. Finally, the re-injected CRDS system is used to measure the spectrum of several volatile organic compounds, demonstrating the improved ability to resolve weakly absorbing spectroscopic features.

  7. Optical re-injection in cavity-enhanced absorption spectroscopy.

    Science.gov (United States)

    Leen, J Brian; O'Keefe, Anthony

    2014-09-01

    Non-mode-matched cavity-enhanced absorption spectrometry (e.g., cavity ringdown spectroscopy and integrated cavity output spectroscopy) is commonly used for the ultrasensitive detection of trace gases. These techniques are attractive for their simplicity and robustness, but their performance may be limited by the reflection of light from the front mirror and the resulting low optical transmission. Although this low transmitted power can sometimes be overcome with higher power lasers and lower noise detectors (e.g., in the near-infrared), many regimes exist where the available light intensity or photodetector sensitivity limits instrument performance (e.g., in the mid-infrared). In this article, we describe a method of repeatedly re-injecting light reflected off the front mirror of the optical cavity to boost the cavity's circulating power and deliver more light to the photodetector and thus increase the signal-to-noise ratio of the absorption measurement. We model and experimentally demonstrate the method's performance using off-axis cavity ringdown spectroscopy (OA-CRDS) with a broadly tunable external cavity quantum cascade laser. The power coupled through the cavity to the detector is increased by a factor of 22.5. The cavity loss is measured with a precision of 2 × 10(-10) cm(-1)/√Hz; an increase of 12 times over the standard off-axis configuration without reinjection and comparable to the best reported sensitivities in the mid-infrared. Finally, the re-injected CRDS system is used to measure the spectrum of several volatile organic compounds, demonstrating the improved ability to resolve weakly absorbing spectroscopic features.

  8. Nanofluid optical property characterization: towards efficient direct absorption solar collectors

    Directory of Open Access Journals (Sweden)

    Otanicar Todd

    2011-01-01

    Full Text Available Abstract Suspensions of nanoparticles (i.e., particles with diameters < 100 nm in liquids, termed nanofluids, show remarkable thermal and optical property changes from the base liquid at low particle loadings. Recent studies also indicate that selected nanofluids may improve the efficiency of direct absorption solar thermal collectors. To determine the effectiveness of nanofluids in solar applications, their ability to convert light energy to thermal energy must be known. That is, their absorption of the solar spectrum must be established. Accordingly, this study compares model predictions to spectroscopic measurements of extinction coefficients over wavelengths that are important for solar energy (0.25 to 2.5 μm. A simple addition of the base fluid and nanoparticle extinction coefficients is applied as an approximation of the effective nanofluid extinction coefficient. Comparisons with measured extinction coefficients reveal that the approximation works well with water-based nanofluids containing graphite nanoparticles but less well with metallic nanoparticles and/or oil-based fluids. For the materials used in this study, over 95% of incoming sunlight can be absorbed (in a nanofluid thickness ≥10 cm with extremely low nanoparticle volume fractions - less than 1 × 10-5, or 10 parts per million. Thus, nanofluids could be used to absorb sunlight with a negligible amount of viscosity and/or density (read: pumping power increase.

  9. Nanofluid optical property characterization: towards efficient direct absorption solar collectors

    Science.gov (United States)

    Taylor, Robert A.; Phelan, Patrick E.; Otanicar, Todd P.; Adrian, Ronald; Prasher, Ravi

    2011-12-01

    Suspensions of nanoparticles (i.e., particles with diameters nanofluids, show remarkable thermal and optical property changes from the base liquid at low particle loadings. Recent studies also indicate that selected nanofluids may improve the efficiency of direct absorption solar thermal collectors. To determine the effectiveness of nanofluids in solar applications, their ability to convert light energy to thermal energy must be known. That is, their absorption of the solar spectrum must be established. Accordingly, this study compares model predictions to spectroscopic measurements of extinction coefficients over wavelengths that are important for solar energy (0.25 to 2.5 μm). A simple addition of the base fluid and nanoparticle extinction coefficients is applied as an approximation of the effective nanofluid extinction coefficient. Comparisons with measured extinction coefficients reveal that the approximation works well with water-based nanofluids containing graphite nanoparticles but less well with metallic nanoparticles and/or oil-based fluids. For the materials used in this study, over 95% of incoming sunlight can be absorbed (in a nanofluid thickness ≥10 cm) with extremely low nanoparticle volume fractions - less than 1 × 10-5, or 10 parts per million. Thus, nanofluids could be used to absorb sunlight with a negligible amount of viscosity and/or density (read: pumping power) increase.

  10. Nanofluid optical property characterization: towards efficient direct absorption solar collectors.

    Science.gov (United States)

    Taylor, Robert A; Phelan, Patrick E; Otanicar, Todd P; Adrian, Ronald; Prasher, Ravi

    2011-03-15

    Suspensions of nanoparticles (i.e., particles with diameters nanofluids, show remarkable thermal and optical property changes from the base liquid at low particle loadings. Recent studies also indicate that selected nanofluids may improve the efficiency of direct absorption solar thermal collectors. To determine the effectiveness of nanofluids in solar applications, their ability to convert light energy to thermal energy must be known. That is, their absorption of the solar spectrum must be established. Accordingly, this study compares model predictions to spectroscopic measurements of extinction coefficients over wavelengths that are important for solar energy (0.25 to 2.5 μm). A simple addition of the base fluid and nanoparticle extinction coefficients is applied as an approximation of the effective nanofluid extinction coefficient. Comparisons with measured extinction coefficients reveal that the approximation works well with water-based nanofluids containing graphite nanoparticles but less well with metallic nanoparticles and/or oil-based fluids. For the materials used in this study, over 95% of incoming sunlight can be absorbed (in a nanofluid thickness ≥10 cm) with extremely low nanoparticle volume fractions - less than 1 × 10-5, or 10 parts per million. Thus, nanofluids could be used to absorb sunlight with a negligible amount of viscosity and/or density (read: pumping power) increase.

  11. Quantum and classical optics of dispersive and absorptive structured media

    Science.gov (United States)

    Bhat, Navin Andrew Rama

    This thesis presents a Hamiltonian formulation of the electromagnetic fields in structured (inhomogeneous) media of arbitrary dimensionality, with arbitrary material dispersion and absorption consistent with causality. The method is based on an identification of the photonic component of the polariton modes of the system. Although the medium degrees of freedom are introduced in an oscillator model, only the macroscopic response of the medium appears in the derived eigenvalue equation for the polaritons. For both the discrete transparent-regime spectrum and the continuous absorptive-regime spectrum, standard codes for photonic modes in nonabsorptive systems can easily be leveraged to calculate polariton modes. Two applications of the theory are presented: pulse propagation and spontaneous parametric down-conversion (SPDC). In the propagation study, the dynamics of the nonfluctuating part of a classical-like pulse are expressed in terms of a Schrodinger equation for a polariton effective field. The complex propagation parameters of that equation can be obtained from the same generalized dispersion surfaces typically used while neglecting absorption, without incurring additional computational complexity. As an example I characterize optical pulse propagation in an Au/MgF 2 metallodielectric stack, using the empirical response function, and elucidate the various roles of Bragg scattering, interband absorption and field expulsion. Further, I derive the Beer coefficient in causal structured media. The SPDC calculation is rigorous, captures the full 3D physics, and properly incorporates linear dispersion. I obtain an expression for the down-converted state, quantify pair-production properties, and characterize the scaling behavior of the SPDC energy. Dispersion affects the normalization of the polariton modes, and calculations of the down-conversion efficiency that neglect this can be off by 100% or more for common media regardless of geometry if the pump is near the band

  12. Mechanism of resonant perfect optical absorption in dielectric film supporting metallic grating structures.

    Science.gov (United States)

    Chen, Xiumei; Yan, Xiaopeng; Li, Ping; Mou, Yongni; Wang, Wenqiang; Guan, Zhiqiang; Xu, Hongxing

    2016-08-22

    The mechanism of resonant perfect optical absorbers is quantitatively revealed by the coupled mode method for the air/grating/dielectric film/air four region system. The sufficient and necessary conditions of the perfect optical absorption are derived from the interface scattering coefficients analyses. The coupling of the Fabry-Perot modes in the grating slits and non-zero order quasi waveguide modes in the dielectric film play a key role for the perfect optical absorption when the light is incident from the grating side. The analytical sufficient and necessary conditions of the perfect optical absorption provide an efficient tool towards geometry design for the perfect optical absorption at the specific wavelengths. The advantages of a widely tunable perfect optical absorption wavelength, a high Q factor and the confined energy loss on metal surfaces make the air/grating/film/air structures promising for applications in sensing, modulation and detection.

  13. Resonant optical absorption and defect control in Ta3N5 photoanodes

    NARCIS (Netherlands)

    Dabirian, A.; Van de Krol, R.

    2013-01-01

    In this study, we explore resonance-enhanced optical absorption in Ta3N5 photoanodes for water splitting. By using a reflecting Pt back-contact and appropriate Ta3N5 film thickness, the resonance frequency can be tuned to energies just above the bandgap, where the optical absorption is normally weak

  14. Effects of Electron-Phonon Interaction on Linear and Nonlinear Optical Absorption in Cylindrical Quantum Wires

    Institute of Scientific and Technical Information of China (English)

    YU You-Bin

    2008-01-01

    The electron-phonon interaction influences on linear and nonlinear optical absorption in cylindrical quantum wires (CQW) with an infinite confining potential are investigated. The optical absorption coefficients are obtained by using the compact-density-matrix approach and iterative method, and the numerical results are presented for GaAs CQW. The results show that the electron-phonon interaction makes a distinct influence on optical absorption in CQW. The electron-phonon interaction on the wave functions of electron dominates the values of absorption coefficients and the correction of the electron-phonon effect on the energies of the electron makes the absorption peaks blue shift and become wider. Moreover, the electron-phonon interaction influence on optical absorption with an infinite confining potential is different from that with a finite confining potential.

  15. UV optical absorption spectra analysis of beryl crystals from Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Isotani, Sadao, E-mail: sisotani@if.usp.b [Instituto de Fisica da Universidade de Sao Paulo, Cidade Universitaria, Sao Paulo (Brazil); Regina Blak, Ana; Watanabe, Shigueo [Instituto de Fisica da Universidade de Sao Paulo, Cidade Universitaria, Sao Paulo (Brazil)

    2010-03-15

    The spectral decomposition analysis was applied to the optical absorption spectra of green and colorless beryl crystals from the Brazilian Eastern Pegmatitic province in the natural state, submitted to heat treatment and irradiated with UV light. The attributions of the lines were made taking into account highly accurate quantum mechanical calculations. The deconvolution of the green beryl spectra revealed four lines, two of them around 12,000 cm{sup -1} (1.5 eV) and two of them around 34,000 cm{sup -1} (4.2 eV) attributed to Fe{sup 2+} and Fe{sup 3+}, respectively. The deconvolution of the colorless beryl spectra without any treatment, after heating and for the same heat treatment followed by UV light irradiation revealed five lines. The analysis of ratio relations showed that the lines at 36,400 cm{sup -1} (4.5 eV) and 41,400 cm{sup -1} (5.1 eV) belongs to a single defect attributed to a silicon dangling bond defect (=Si:). Discussions and comparison with reported defects in quartz have supported the allocation of the lines at 61,000 cm{sup -1} (7.6 eV) and 43,800 cm{sup -1} (5.4 eV) to diamagnetic oxygen vacancy defect (ident toSi-Siident to) and unrelaxed (ident toSi...Siident to) defect, respectively. Finally, the line at 39,100 cm{sup -1} (4.8 eV), quite polarized along the c-axis, was attributed to a (Fe{sup 2+}OH{sup -}) defect in the structural channels.

  16. Tuning optical and three photon absorption properties in graphene oxide-polyvinyl alcohol free standing films

    Science.gov (United States)

    Karthikeyan, B.; Udayabhaskar, R.; Hariharan, S.

    2016-07-01

    We report the optical and nonlinear optical properties of graphene oxide (GO)-polyvinyl alcohol (PVA) free standing films. The composite polymer films were prepared in ex-situ method. The variation in optical absorption spectra and optical constants with the amount of GO loading was noteworthy from the optical absorption spectroscopic studies. Nonlinear optical studies done at 532 nm using 5 ns laser pulses show three photon absorption like behaviour. Both steady state and time resolved fluorescence studies reveal that the GO was functioning as a pathway for the decay of fluorescence from PVA. This is attributed to the energy level modifications of GO through hydroxyl groups with PVA. Raman spectroscopy also supports the interaction between GO and PVA ions through OH radicals.

  17. Optical absorption of charged excitons in semiconducting carbon nanotubes

    DEFF Research Database (Denmark)

    Rønnow, Troels Frimodt; Pedersen, Thomas Garm; Cornean, Horia

    2012-01-01

    In this article we examine the absorption coefficient of charged excitons in carbon nanotubes. We investigate the temperature and damping dependence of the absorption spectra. We show that the trion peak in the spectrum is asymmetric for temperatures greater than approximately 1 K whereas the abs...

  18. Microstructural and Optical Absorption Properties of Cu-MgF2 Nanoparticle Cermet Film

    Institute of Scientific and Technical Information of China (English)

    孙兆奇; 孙大明; 阮图南

    2002-01-01

    We examine the microstructural and optical absorption spectra of 10-30 vol% Cu-MgF2 nanoparticle cermet films prepared by co-evaporation in vacuum. The results show that the Cu-MgF2 cermet films are mainly composed of the amorphous MgF2 matrix with embedded fcc Cu nanoparticles of average size 12-24 nm. The results also show that the optical absorption of the films decreases as the wavelength increases in the range of 200-800nm. The surface plasmon resonance absorption peaks of Cu nanoparticles in 10, 20 and 30 vo1% Cu-MgF2 films appear at 578, 588 and 606nm, respectively. The interband transition absorption of Cu starts from 590nm downwards.Based on the Maxwell-Garnett theory, the experimental optical absorption properties of the films have been quantitatively evaluated.

  19. Optical Absorption of Poly(thiophene vinylene) Conjugated Polymers. Experiment and First Principle Theory

    CERN Document Server

    Gavrilenko, A V; Bonner, C E; Sun, S -S; Zhang, C; Gavrilenko, V I

    2008-01-01

    Optical absorption spectra of poly(thiophene vinylene) (PTV) conjugated polymers have been studied at room temperature in the spectral range of 450 to 800 nm. A dominant peak located at 577 nm and a prominent shoulder at 619 nm are observed. Another shoulder located at 685 nm is observed at high concentration and after additional treatment (heat, sonification) only. Equilibrium atomic geometries and optical absorption of PTV conjugated polymers have also been studied by first principles density functional theory (DFT). For PTV in solvent, the theoretical calculations predict two equilibrium geometries with different interchain distances. By comparative analysis of the experimental and theoretical data, it is demonstrated that the new measured long-wavelength optical absorption shoulder is consistent with new optical absorption peak predicted for most energetically favorable PTV phase in the solvent. This shoulder is interpreted as a direct indication of increased interchain interaction in the solvent which ha...

  20. Multi-spectral optical absorption in substrate-free nanowire arrays

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Junpeng; Chia, Andrew; Boulanger, Jonathan; LaPierre, Ray, E-mail: lapierr@mcmaster.ca [Department of Engineering Physics, McMaster University, 1280 Main St. West, Hamilton, Ontario L8S 4L7 (Canada); Dhindsa, Navneet; Khodadad, Iman; Saini, Simarjeet [Department of Electrical and Computer Engineering, University of Waterloo, 200 University Ave West, Waterloo, Ontario N2L 3G1 (Canada); Waterloo Institute of Nanotechnology, University of Waterloo, 200 University Ave West, Waterloo, Ontario N2L 3G1 (Canada)

    2014-09-22

    A method is presented of fabricating gallium arsenide (GaAs) nanowire arrays of controlled diameter and period by reactive ion etching of a GaAs substrate containing an indium gallium arsenide (InGaP) etch stop layer, allowing the precise nanowire length to be controlled. The substrate is subsequently removed by selective etching, using the same InGaP etch stop layer, to create a substrate-free GaAs nanowire array. The optical absorptance of the nanowire array was then directly measured without absorption from a substrate. We directly observe absorptance spectra that can be tuned by the nanowire diameter, as explained with rigorous coupled wave analysis. These results illustrate strong optical absorption suitable for nanowire-based solar cells and multi-spectral absorption for wavelength discriminating photodetectors. The solar-weighted absorptance above the bandgap of GaAs was 94% for a nanowire surface coverage of only 15%.

  1. Discrepancy between ambient annealing and H{sup +} implantation in optical absorption of ZnO

    Energy Technology Data Exchange (ETDEWEB)

    Lv, Jinpeng, E-mail: hitljp@gmail.com [College of Astronautics, Nanjing University of Aeronautics and Astronautics, Nanjing, Jiangsu (China); Li, Chundong [School of Materials Science and Engineering, Harbin Institute of Technology, Harbin, Heilongjiang (China)

    2016-05-15

    The discrepancy between sub-bandgap absorption in ZnO induced by thermal annealing and H{sup +} implantation is investigated in this study for the first time. Results indicate that nonreductive annealing-induced optical absorption is independent of annealing ambient, and can be assigned to V{sub O}, whereas the absorption centers caused by H{sup +} implantation and H{sub 2} annealing are primarily associated with V{sub O} and ionized Zn{sub i}.

  2. Optical absorption and Faraday rotation in spin doped Cd1-xHgxSe : Mn crystals

    NARCIS (Netherlands)

    Savchuk, AI; Paranchich, SY; Paranchich, LD; Romanyuk, OS; Andriychuk, MD; Nikitin, PI; Tomlinson, RD; Hill, AE; Pilkington, RD

    1998-01-01

    Optical absorption spectra and the Faraday effect in crystals of Cd1-xHgxSe : Mn have been studied. The studied samples have been characterized abrupt absorption edge and transparency region with high transmission coefficient. The measured values of Verdet constant were considerably larger than in I

  3. Unified theory of electron-phonon renormalization and phonon-assisted optical absorption.

    Science.gov (United States)

    Patrick, Christopher E; Giustino, Feliciano

    2014-09-10

    We present a theory of electronic excitation energies and optical absorption spectra which incorporates energy-level renormalization and phonon-assisted optical absorption within a unified framework. Using time-independent perturbation theory we show how the standard approaches for studying vibronic effects in molecules and those for addressing electron-phonon interactions in solids correspond to slightly different choices for the non-interacting Hamiltonian. Our present approach naturally leads to the Allen-Heine theory of temperature-dependent energy levels, the Franck-Condon principle, the Herzberg-Teller effect and to phonon-assisted optical absorption in indirect band gap materials. In addition, our theory predicts sub-gap phonon-assisted optical absorption in direct gap materials, as well as an exponential edge which we tentatively assign to the Urbach tail. We also consider a semiclassical approach to the calculation of optical absorption spectra which simultaneously captures energy-level renormalization and phonon-assisted transitions and is especially suited to first-principles electronic structure calculations. We demonstrate this approach by calculating the phonon-assisted optical absorption spectrum of bulk silicon.

  4. Temperature-dependent optical absorption of SrTiO{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Kok, Dirk J.; Irmscher, Klaus; Naumann, Martin; Guguschev, Christo; Galazka, Zbigniew; Uecker, Reinhard [Leibniz Institute for Crystal Growth, Berlin (Germany)

    2015-09-15

    The optical absorption edge and near infrared absorption of SrTiO{sub 3} were measured at temperatures from 4 to 1703 K. The absorption edge decreases from 3.25 eV at 4 K to 1.8 eV at 1703 K and is extrapolated to approximately 1.2 eV at the melting point (2350 K). The transmission in the near IR decreases rapidly above 1400 K because of free carrier absorption and is about 50% of the room temperature value at 1673 K. The free carriers are generated by thermal excitation of electrons over the band gap and the formation of charged vacancies. The observed temperature-dependent infrared absorption can be well reproduced by a calculation based on simple models for the intrinsic free carrier concentration and the free carrier absorption coefficient. The measured red shift of the optical absorption edge and the rising free carrier absorption strongly narrow the spectral range of transmission and impede radiative heat transport through the crystal. These effects have to be considered in high temperature applications of SrTiO{sub 3}-based devices, as the number of free carriers rises considerably, and in bulk crystal growth to avoid growth instabilities. Temperature dependent optical absorption edge of SrTiO{sub 3}, measured, fitted, and extrapolated to the melting point. (copyright 2015 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  5. Transient Intersubband Optical Absorption in Double Quantum Well Structure

    Institute of Scientific and Technical Information of China (English)

    WU Bin-He

    2005-01-01

    The microscopic equations of motion including many-body effects are derived to study the intersubband polarization in the double quantum well structure induced by an ultrafast pumping infrared light. Based on the selfconsistent field theory, the transient probe absorption coefficient is calculated. These calculations are beyond the previous steady-state assumption. Transient probe absorption spectra are calculated under different pumping intensity and various pump probe delay.

  6. Optical pumping effect in absorption imaging of F=1 atomic gases

    CERN Document Server

    Kim, Sooshin; Noh, Heung-Ryoul; Shin, Y

    2016-01-01

    We report our study of the optical pumping effect in absorption imaging of $^{23}$Na atoms in the $F=1$ hyperfine spin states. Solving a set of rate equations for the spin populations under a probe beam, we obtain an analytic expression for the optical signal of the $F=1$ absorption imaging. Furthermore, we verify the result by measuring the absorption spectra of $^{23}$Na Bose-Einstein condensates prepared in various spin states with different probe beam pulse durations. The analytic result can be used in quantitative analysis of $F=1$ spinor condensate imaging and readily applied to other alkali atoms with $I=3/2$ nuclear spin such as $^{87}$Rb.

  7. Near IR two photon absorption of cyanines dyes: application to optical power limiting at telecommunication wavelengths

    Science.gov (United States)

    Bouit, Pierre-Antoine; Wetzel, Guillaume; Feneyrou, Patrick; Bretonnière, Yann; Kamada, Kenji; Maury, Olivier; Andraud, Chantal

    2008-02-01

    The design and synthesis of symmetrical and unsymmetrical heptamethine cyanines is reported. These chromophores present significant two-photon cross section in the 1400-1600 nm spectral range. In addition, they display optical power limiting (OPL) properties. OPL curves were interpreted on the basis of two-photon absorption (2PA) followed by excited state absorption (ESA). Finally, these molecules present several relevant properties (nonlinear absorption properties, two-step gram scale synthesis, high solubility, good thermal stability), which could lead to numerous practical applications in material science (solid state optical limiting, signal processing) or in biology (imaging).

  8. Optical label switching in telecommunication using semiconductor lasers, amplifiers and electro-absorption modulators

    DEFF Research Database (Denmark)

    Chi, Nan; Christiansen, Lotte Jin; Jeppesen, Palle;

    2004-01-01

    We demonstrate all-optical label encoding and updating for an orthogonally labeled signal in combined IM/FSK modulation format utilizing semiconductor lasers, semiconductor optical amplifiers and electro-absorption modulators. Complete functionality of a network node including two-hop transmissio...

  9. Edge-promoting reconstruction of absorption and diffusivity in optical tomography

    DEFF Research Database (Denmark)

    Hannukainen, A.; Harhanen, Lauri Oskari; Hyvönen, N.;

    2015-01-01

    In optical tomography a physical body is illuminated with near-infrared light and the resulting outward photon flux is measured at the object boundary. The goal is to reconstruct internal optical properties of the body, such as absorption and diffusivity. In this work, it is assumed that the imaged...

  10. Investigation on optical absorption properties of ion irradiated single walled carbon nanotubes

    Energy Technology Data Exchange (ETDEWEB)

    Vishalli,, E-mail: vishalli-2008@yahoo.com; Dharamvir, Keya, E-mail: keya@pu.ac.in [Department of Physics, Panjab University, Chandigarh (India); Kaur, Ramneek; Raina, K. K. [Materials Research Laboratory, School of Physics and Materials Science, Thapar University, Patiala (India); Avasthi, D. K. [Materials Science Group, Inter University Accelerator Centre, ArunaAsaf Ali Marg, NewDelhi (India); Jeet, Kiran [Electron Microscopy and Nanoscience laboratory, Punjab Agriculture University, Ludhiana (India)

    2015-08-28

    In the present study change in the optical absorption properties of single walled carbon nanotubes (SWCNTs) under nickel ion (60 MeV) irradiation at various fluences has been investigated. Langmuir Blodgett technique is used to deposit SWCNT thin film of uniform thickness. AFM analysis shows a network of interconnected bundles of nanotubes. UV-Vis-NIR absorption spectra indicate that the sample mainly contain SWCNTs of semiconducting nature. It has been found in absorption spectra that there is decrease in the intensity of the characteristic SWCNT peaks with increase in fluence. At fluence value 1×10{sup 14} ions/cm{sup 2} there is almost complete suppression of the characteristic SWCNTs peaks.The decrease in the optical absorption with increase in fluence is due to the increase in the disorder in the system which leads to the decrease in optically active states.

  11. Correction of optical absorption and scattering variations in Laser Speckle Rheology measurements.

    Science.gov (United States)

    Hajjarian, Zeinab; Nadkarni, Seemantini K

    2014-03-24

    Laser Speckle Rheology (LSR) is an optical technique to evaluate the viscoelastic properties by analyzing the temporal fluctuations of backscattered speckle patterns. Variations of optical absorption and reduced scattering coefficients further modulate speckle fluctuations, posing a critical challenge for quantitative evaluation of viscoelasticity. We compare and contrast two different approaches applicable for correcting and isolating the collective influence of absorption and scattering, to accurately measure mechanical properties. Our results indicate that the numerical approach of Monte-Carlo ray tracing (MCRT) reliably compensates for any arbitrary optical variations. When scattering dominates absorption, yet absorption is non-negligible, diffusing wave spectroscopy (DWS) formalisms perform similar to MCRT, superseding other analytical compensation approaches such as Telegrapher equation. The computational convenience of DWS greatly simplifies the extraction of viscoelastic properties from LSR measurements in a number of chemical, industrial, and biomedical applications.

  12. Optical absorption of sodium copper chlorophyllin thin films in UV-vis-NIR region.

    Science.gov (United States)

    Farag, A A M

    2006-11-01

    The optical absorption studies of sodium copper chlorophyllin thin films (SCC), prepared by spray pyrolysis, in the UV-vis-NIR region was reported for the first time. Several new discrete transitions are observed in the UV-vis region of the spectra in addition to a strong continuum component in the IR region. The spectra of the infrared absorption allow characterization of vibration modes for the powder and thin films of SCC. The absorption spectrum recorded in the UV-vis region showed different absorption bands, namely the Soret (B) in the region 340-450 nm and Q-band in the region 600-700 nm and other band labeled N in the 240-320 region. Some important spectral parameters namely optical absorption coefficient (alpha), molar extinction coefficient (epsilon(molar)), oscillator strength (f), electric dipole strength (q(2)) and absorption half bandwidth (Deltalambda) of the principle optical transitions were evaluated. The analysis of the absorption coefficient in the absorption region revealed direct transitions and the energy gap was estimated as 1.63 eV. Discussion of the obtained results and their comparison with the previous published data are also given.

  13. Enhancement of broadband optical absorption in photovoltaic devices by band-edge effect of photonic crystals.

    Science.gov (United States)

    Tanaka, Yoshinori; Kawamoto, Yosuke; Fujita, Masayuki; Noda, Susumu

    2013-08-26

    We numerically investigate broadband optical absorption enhancement in thin, 400-nm thick microcrystalline silicon (µc-Si) photovoltaic devices by photonic crystals (PCs). We realize absorption enhancement by coupling the light from the free space to the large area resonant modes at the photonic band-edge induced by the photonic crystals. We show that multiple photonic band-edge modes can be produced by higher order modes in the vertical direction of the Si photovoltaic layer, which can enhance the absorption on multiple wavelengths. Moreover, we reveal that the photonic superlattice structure can produce more photonic band-edge modes that lead to further optical absorption. The absorption average in wavelengths of 500-1000 nm weighted to the solar spectrum (AM 1.5) increases almost twice: from 33% without photonic crystal to 58% with a 4 × 4 period superlattice photonic crystal; our result outperforms the Lambertian textured structure.

  14. Intensity-Dependent Optical Nonlinear Absorption and Refraction of Gold Nanorods

    Institute of Scientific and Technical Information of China (English)

    GONG Hong-Mei; ZHOU zhang-Kai; XIAO Si; SONG Hao; SU xiong-Rui; LI Min; WANG Qu-Quan

    2007-01-01

    Au nanorods dispersed in aqueous solution were prepared with the electrochemical method.The absorption spectrum shows two absorption peaks corresponding to the perpendicular and transverse surface plasma resonance absorption of the nanorods.The third-order optical nonlinear properties are investigated by Z-scans.The signs of the nonlinear absorption coefficient and refractive index are reversed as the intensity of incident laser increases,which is due to the shape change of the gold nanoparticles melted by the intense laser pulses.

  15. Optical Absorption of Impurities and Defects in SemiconductingCrystals 1. Hydrogen-like Centres

    CERN Document Server

    Pajot, Bernard

    2010-01-01

    Absorption spectroscopy provides information on the chemical nature, atomic structure and concentration of hydrogen-like centers, to which belong most of the dopants of semiconductors and insulators. In this book, an introduction to the bulk optical properties of these materials and to the properties of hydrogen-like centers is first provided, followed by a description of set-ups used in absorption spectroscopy. The results of the calculations of the energy levels of these centres by effective-mass theory are exposed. Detailed absorption data on specific classes of centres are compared with theory, and atomic structures are deduced from absorption measurements under external perturbations.

  16. Optical absorption and fluorescence studies on imidazolium ionic liquids comprising the bis(trifluoromethanesulphonyl)imide anion

    Indian Academy of Sciences (India)

    Aniruddha Paul; Anunay Samanta

    2006-07-01

    Optical absorption and fluorescence behaviour of two rigorously purified imidazolium ionic liquids, 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide and 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide are studied in the neat condition and in solution. Non-negligible absorption in the UV region with a long tail extending into the visible region is the main feature of the absorption. Excitation wavelength-dependent two-component fluorescence characterizes the emission behaviour of these liquids. That ion association gives rise to the long absorption tail and shifting fluorescence maximum, which appears to be common to most of the imidazolium ionic liquids, is evident from the effect of the conventional solvents.

  17. Microstructure and optical absorption of Au-MgF2 nanoparticle cermet films

    Institute of Scientific and Technical Information of China (English)

    Sun Zhao-Qi; Cai Qi; Song Xue-Ping

    2006-01-01

    The microstructure and optical absorption of Au-MgF2 nanoparticle cermet films with different Au contents are studied.The microstructural analysis shows that the films are mainly composed of the amorphous MgF2 matrix with embedded fcc Au nanoparticles with a mean size of 9.8-21.4nm.Spectral analysis suggests that the surface plasma resonance (SPR) absorption peak of Au particles appears at λ=492-537nm.With increasing Au content,absorption peak intensity increases,profile narrows and location redshifts.Theoretical absorption spectra are calculated based on Maxwell-Garnett theory and compared with experimental spectra.

  18. Effects of polarization and absorption on laser induced optical breakdown threshold for skin rejuvenation

    Science.gov (United States)

    Varghese, Babu; Bonito, Valentina; Turco, Simona; Verhagen, Rieko

    2016-03-01

    Laser induced optical breakdown (LIOB) is a non-linear absorption process leading to plasma formation at locations where the threshold irradiance for breakdown is surpassed. In this paper we experimentally demonstrate the influence of polarization and absorption on laser induced breakdown threshold in transparent, absorbing and scattering phantoms made from water suspensions of polystyrene microspheres. We demonstrate that radially polarized light yields a lower irradiance threshold for creating optical breakdown compared to linearly polarized light. We also demonstrate that the thermal initiation pathway used for generating seed electrons results in a lower irradiance threshold compared to multiphoton initiation pathway used for optical breakdown.

  19. Population Dynamics and the Optical Absorption in Hybrid Metal Nanoparticle - Semiconductor Quantum dot Nanosystem

    CERN Document Server

    Kim, Nam-Chol; Ko, Myong-Chol; So, Guang Hyok; Kim, Il-Guang

    2015-01-01

    We studied theoretically the population dynamics and the absorption spectrum of hybrid nanosystem consisted of a matal nanoparticle (MNP) and a semiconductor quantum dot(SQD). We investigated the exciton-plasmon coupling effects on the population dynamics and the absorption properties of the nanostructure. Our results show that the nonlinear optical response of the hybrid nanosystem can be greatly enhanced or depressed due to the exciton-plasmon couplings. The results obtained here may have the potential applications of nanoscale optical devices such as optical switches and quantum devices such as a single photon transistor.

  20. Generating Nanostructures with Multiphoton Absorption Polymerization using Optical Trap Assisted Nanopatterning

    Science.gov (United States)

    Tsai, Yu-Cheng; Leitz, Karl-Heinz; Fardel, Romain; Schmidt, Michael; Arnold, Craig B.

    The need to generate sub 100 nm features is of interest for a variety of applications including optics, optoelectronics, and plasmonics. To address this requirement, several advanced optical lithography techniques have been developed based on either multiphoton absorption polymerization or near-field effects. In this paper, we combine strengths from multiphoton absorption and near field using optical trap assisted nanopatterning (OTAN). A Gaussian beam is used to position a microsphere in a polymer precursor fluid near a substrate. An ultrafast laser is focused by that microsphere to induce multiphoton polymerization in the near field, leading additive direct-write nanoscale processing.

  1. Design of differential optical absorption spectroscopy long-path telescopes based on fiber optics.

    Science.gov (United States)

    Merten, André; Tschritter, Jens; Platt, Ulrich

    2011-02-10

    We present a new design principle of telescopes for use in the spectral investigation of the atmosphere and the detection of atmospheric trace gases with the long-path differential optical absorption spectroscopy (DOAS) technique. A combination of emitting and receiving fibers in a single bundle replaces the commonly used coaxial-Newton-type combination of receiving and transmitting telescope. This very simplified setup offers a higher light throughput and simpler adjustment and allows smaller instruments, which are easier to handle and more portable. The higher transmittance was verified by ray-tracing calculations, which result in a theoretical factor threefold improvement in signal intensity compared with the old setup. In practice, due to the easier alignment and higher stability, up to factor of 10 higher signal intensities were found. In addition, the use of a fiber optic light source provides a better spectral characterization of the light source, which results in a lower detection limit for trace gases studied with this instrument. This new design will greatly enhance the usability and the range of applications of active DOAS instruments.

  2. Optical signal processing using electro-absorption modulators

    DEFF Research Database (Denmark)

    Mørk, Jesper; Romstad, Francis Pascal; Højfeldt, Sune;

    2003-01-01

    Reverse-biased semiconductor waveguides are efficient saturable absorbers and have a number of promising all-optical signal processing applications. Results on ultrafast modulator dynamics as well as demonstrations and investigations of wavelength conversion and regeneration are presented....

  3. In situ optical absorption mercury continuous emission monitor.

    Science.gov (United States)

    Thiebaud, Jérôme; Thomson, Murray J; Mani, Reza; Morrow, William H; Morris, Eric A; Jia, Charles Q

    2009-12-15

    This paper reports the development of an in situ continuous emission monitor (CEM) for measuring elemental mercury (Hg(0)) concentration in the exhaust stream of coal-fired power plants. The instrument is based on the ultraviolet atomic absorption of a mercury lamp emission line by elemental mercury and a light-emitting diode (LED) background correction system. This approach allows an in situ measurement since the absorption of other species such as SO(2) can be removed to monitor the Hg(0) contribution only. Proof of concept was established through a laboratory-based investigation, and a limit of detection, [Hg(0)](min), of 2 microg/m(3) was measured for a 1-min averaged sample and an absorption path length of 49 cm. [Hg(0)](min) is anticipated to be better than 0.2 microg/m(3) across a 7 m diameter stack. Finally, the apparatus was field-tested in a 230 MW coal-fired power plant. The operability of the measurement in real conditions was demonstrated, leading to the first Hg(0) concentration values recorded by the in situ CEM. Comparison with an accepted standard method is required for validation.

  4. The local structure and optical absorption characteristic investigation on Fe doped TiO2 nanoparticles

    CERN Document Server

    Zhao, Tianxing; Huang, Junheng; He, Jinfu; Liu, Qinghua; Pan, Zhiyun; Wu, Ziyu

    2014-01-01

    The local structures and optical absorption characteristic of Fe doped TiO2 nanoparticles synthesized by the sol-gel method were characterized by X-ray Diffraction (XRD), X-ray absorption fine structure spectroscopy (XAFS) and UV-Vis absorption spectroscopy (UV-Vis). XRD patterns show that all Fe-doped TiO2 samples have the characteristic anatase structure. Accurate Fe and Ti K-edge EXAFS analysis further reveal that all Fe atoms replace Ti atoms in the anatase lattice. The analysis of UV-Vis data shows a red shift to the visible range. According to the above results, we claim that substitutional Fe atoms lead to the formation of structural defects and new intermediate energy levels appear, narrowing the band gap and extending the optical absorption edge towards the visible region.

  5. Confined optical-phonon-assisted cyclotron resonance in quantum wells via two-photon absorption process

    Science.gov (United States)

    Phuc, Huynh Vinh; Hien, Nguyen Dinh; Dinh, Le; Phong, Tran Cong

    2016-06-01

    The effect of confined phonons on the phonon-assisted cyclotron resonance (PACR) via both one and two photon absorption processes in a quantum well is theoretically studied. We consider cases when electrons are scattered by confined optical phonons described by the Fuchs-Kliewer slab, Ridley's guided, and Huang-Zhu models. The analytical expression of the magneto-optical absorption coefficient (MOAC) is obtained by relating it to the transition probability for the absorption of photons. It predicts resonant peaks caused by transitions between Landau levels and electric subband accompanied by confined phonons emission in the absorption spectrum. The MOAC and the full-width at half-maximum (FWHM) for the intra- and inter-subband transitions are given as functions of the magnetic field, temperature, and quantum well width. In narrow quantum wells, the phonon confinement becomes more important and should be taken into account in studying FWHM.

  6. Enhanced light absorption in graphene via a liquid-crystalline optical diode

    Science.gov (United States)

    Pantazi, Aikaterini Iria; Yannopapas, Vassilios

    2016-09-01

    We demonstrate theoretically that light absorption in graphene can be boosted via a light-trapping mechanism based on a liquid-crystalline optical diode. The optical diode consists of twisted-nematic and nematic liquid-crystalline slabs. In particular, we show that, using a proper optical-diode setup, the absorption in a single graphene layer can be enhanced by a factor of four. By varying the pitch of the twisted-nematic liquid-crystalline slabs comprising the diode, one can tune the operating spectral region of the diode and thus enhance the absorption of graphene within a desired spectral window. Our calculations are based on Berreman's 4×4 method which treats anisotropic, isotropic and/ or inhomogeneous layered systems on equal footing.

  7. Mass specific optical absorption coefficients of mineral dust components measured by a multi wavelength photoacoustic spectrometer

    Directory of Open Access Journals (Sweden)

    N. Utry

    2014-09-01

    Full Text Available Mass specific optical absorption coefficients of various mineral dust components including silicate clays (illite, kaolin and bentonite, oxides (quartz, hematite and rutile, and carbonate (limestone were determined at wavelengths of 1064, 532, 355 and 266 nm. These values were calculated from aerosol optical absorption coefficients measured by a multi-wavelength photoacoustic (PA instrument, the mass concentration and the number size distribution of the generated aerosol samples as well as the size transfer functions of the measuring instruments. These results are expected to have considerable importance in global radiative forcing calculations. They can also serve as reference for validating calculated wavelength dependent imaginary parts (κ of complex refractive indices which up to now have been typically deduced from bulk phase measurements by using indirect measurement methods. Accordingly, the presented comparison of the measured and calculated aerosol optical absorption spectra revealed the strong need for standardized sample preparation and measurement methodology in case of bulk phase measurements.

  8. Recent Progress Towards Quantum Dot Solar Cells with Enhanced Optical Absorption

    OpenAIRE

    Zheng, Zerui; Ji, Haining; Yu, Peng; Wang, Zhiming

    2016-01-01

    Quantum dot solar cells, as a promising candidate for the next generation solar cell technology, have received tremendous attention in the last 10 years. Some recent developments in epitaxy growth and device structures have opened up new avenues for practical quantum dot solar cells. Unfortunately, the performance of quantum dot solar cells is often plagued by marginal photon absorption. In this review, we focus on the recent progress made in enhancing optical absorption in quantum dot solar ...

  9. Embedded insulated metallic nanopatterns for enhanced optical absorption and photovoltaics

    Science.gov (United States)

    Ye, Fan; Burns, Michael J.; Naughton, Michael J.

    2012-02-01

    Recently, we have shown embedded metallic nanopatterns (EMN) in ultrathin PV films to be candidates for high efficiency thin-film solar cells, owing to prominent metamaterial/plasmonic-enhanced light trapping, as compared to unpatterned, surface- or bottom-patterned [1]. We also showed that hot electron effects emerge in ultrathin a-Si-based solar cells [2]. The EMN in the semiconductor layer, however, can also serve as a source of recombination for photogenerated electrons and holes, leading to decreased current. Here, we propose the idea of an embedded insulated metallic nanopattern (EIMN) to efficiently avoid the recombination effect while maintaining high light absorption in an ultrathin film format in which hot electron physics can contribute. Simulations show that an EIMN with a 10 nm layer of dielectric insulation provides essentially the same absorption as its EMN counterpart. Measurements on several EMN structures will be presented. This EIMN architecture may provide a practical route to high efficiency, hot electron solar cell technology using ultrathin films.[1]F. Ye, M.J. Burns, M.J. Naughton, Proc. SPIE 8111, 811103 (2011).[2]K. Kempa, M.J. Naughton, Z.F. Ren, A. Herczynski, T. Kirkpatrick, J. Rybczynski, Y. Gao, Appl. Phys. Lett. 95, 233121(2009)

  10. Charge-transfer optical absorption mechanism of DNA:Ag-nanocluster complexes

    Science.gov (United States)

    Longuinhos, R.; Lúcio, A. D.; Chacham, H.; Alexandre, S. S.

    2016-05-01

    Optical properties of DNA:Ag-nanoclusters complexes have been successfully applied experimentally in Chemistry, Physics, and Biology. Nevertheless, the mechanisms behind their optical activity remain unresolved. In this work, we present a time-dependent density functional study of optical absorption in DNA:Ag4. In all 23 different complexes investigated, we obtain new absorption peaks in the visible region that are not found in either the isolated Ag4 or isolated DNA base pairs. Absorption from red to green are predominantly of charge-transfer character, from the Ag4 to the DNA fragment, while absorption in the blue-violet range are mostly associated to electronic transitions of a mixed character, involving either DNA-Ag4 hybrid orbitals or intracluster orbitals. We also investigate the role of exchange-correlation functionals in the calculated optical spectra. Significant differences are observed between the calculations using the PBE functional (without exact exchange) and the CAM-B3LYP functional (which partly includes exact exchange). Specifically, we observe a tendency of charge-transfer excitations to involve purines bases, and the PBE spectra error is more pronounced in the complexes where the Ag cluster is bound to the purines. Finally, our results also highlight the importance of adding both the complementary base pair and the sugar-phosphate backbone in order to properly characterize the absorption spectrum of DNA:Ag complexes.

  11. Monitoring Mechanical Motion of Carbon Nanotube based Nanomotor by Optical Absorption Spectrum

    CERN Document Server

    Wang, Baomin; Wang, Zhan; Wang, Yong; Liu, Kaihui

    2016-01-01

    The optical absorption spectrums of nanomotors made from double-wall carbon nanotubes have been calculated with the time-dependent density functional based tight binding method. When the outer short tube of the nanomotor moves along or rotates around the inner long tube, the peaks in the spectrum will gradually evolve and may shift periodically, the amplitude of which can be as large as hundreds of meV. We show that the features and behaviors of the optical absorption spectrum could be used to monitor the mechanical motions of the double-wall carbon nanotube based nanomotor.

  12. Two- and three-dimensional models for analysis of optical absorption in tungsten disulphide single crystals

    Indian Academy of Sciences (India)

    Dhairya A Dholakia; G K Solanki; S G Patel; M K Agarwal

    2001-06-01

    The optical energy gaps of WS2 single crystal were determined from the analysis of the absorption spectrum near the fundamental absorption edge at room temperature using light parallel to -axis incident normally on the basal plane. On the basis of two- and three-dimensional models it was found that both direct and indirect band transitions took place in WS2 and the indirect transition was of the allowed type. The optical energy gaps corresponding to both transitions were determined and the phonon energies associated with the indirect transitions estimated. The implications of the results have been discussed.

  13. Polyethylene laser welding based on optical absorption variations

    Science.gov (United States)

    Galtieri, G.; Visco, A.; Nocita, D.; Torrisi, L.; Ceccio, G.; Scolaro, C.

    2016-04-01

    Polymeric materials, both pure and containing nanostructures, can be prepared as thin sheets in order to produce joints with an interface between an optically transparent sheet and an optically absorbent substrate to be welded by infrared pulsed laser irradiation. The Laser Transmission Welding (LTW) technique has been successfully applied in order to join two or more thermoplastic polymeric sheets that must have a similar chemical composition. In this research work, polymeric joints of Ultra High Molecular Weight Polyethylene sheets were realized, characterized and welded. Some polymer sheets were doped, at different concentrations, with carbon nano-particles absorbent the laser radiation. A pulsed laser operating in the wavelength region 532 nm with intensity of the order of 109 Watt/cm2 was employed to be transmitted by the transparent polymer and to be absorbed by the carbon enriched surface. At the interface of the two polymers the released energy induces melting, that is assisted by pressure, producing a fast and resistant welding zone. Mechanical and optical characterizations and surface analyses are presented and discussed.

  14. Optical Absorption of Sol-Gel Derived ZnO/TiO2 Nanocomposite Films

    Institute of Scientific and Technical Information of China (English)

    袁志好; 唐成春; 范守善

    2001-01-01

    ZnO/TiO2 nanocomposite films on quartz substrates were prepared by the sol-gel method, and the corresponding optical absorption properties were investigated. In the ultraviolet region, it was found that the position of fundamental absorption edge partially depends on the composition of the ZnO/TiO2 films, and shifts toward a shorter wavelength with the increasing content of ZnO in the films. Moreover, a blueshift of the absorption edge resulted from a quantum size effect and the quantum confinement effect was observed in the ZnO/TiO2 system.

  15. Absorption spectroscopy of cold caesium atoms confined in a magneto-optical trap

    Institute of Scientific and Technical Information of China (English)

    Yan Shu-Bin; Liu Tao; Geng Tao; Zhang Tian-Cai; Peng Kun-Chi; Wang Jun-Min

    2004-01-01

    Absorption spectra of cold caesium atoms confined in a magneto-optical trap are measured around D2 line at 852nm with a weak probe beam. Absorption reduction dip due to electromagnetically induced transparency (EIT)effect induced by the cooling/trapping field in a V-type three-level system and a gain peak near the cycling transition are clearly observed. Several mechanisms mixed with EIT effect in a normal V-type three-level system are briefly discussed. A simple theoretical analysis based on a dressed-state model is presented for interpretation of the absorption spectra.

  16. Effect of Sb2O3-doped on optical absorption of ZnO thin film

    Institute of Scientific and Technical Information of China (English)

    CHANG Chun-rong; LI Zi-quan; XU Yun-yun

    2006-01-01

    Sb2O3 doped ZnO thin film was prepared by RF magnetron sputtering technique.The influence of Sb2O3 on the structure and the optical absorption of ZnO thin film was studied by XPS,XRD apparatuses and UV-Vis spectrophotometer.The results show that doped Sb2O3 has affected atomic and electronic structures,growth modes of crystal grains and optical absorption of ZnO.The element Sb exists in many forms in the film including transpositional atoms and compounds such as Sb2O3,Zn7Sb2O14 etc.ZnO crystal grains grow in mixing directions.The lattice relaxation and the content of second phases increase when more Sb is doped.The UVA absorption of doped ZnO thin film increases obviously.The ultraviolet absorption peak narrows,absorption intensity increases,the absorption margin becomes steep and moves to shorter wavelength of about 5 nm,and the visible absorption increases in some sort.

  17. Optical absorption enhancement of CdTe nanostructures by low-energy nitrogen ion bombardment

    Science.gov (United States)

    Akbarnejad, E.; Ghoranneviss, M.; Mohajerzadeh, S.; Hantehzadeh, M. R.; Asl Soleimani, E.

    2016-02-01

    In this paper we present the fabrication of cadmium telluride (CdTe) nanostructures by means of RF magnetron sputtering followed by low-energy ion implantation and post-thermal treatment. We have thoroughly studied the structural, optical, and morphological properties of these nanostructures. The effects of nitrogen ion bombardment on the structural parameters of CdTe nanostructures such as crystal size, microstrain, and dislocation density have been examined. From x-ray diffractometer (XRD) analysis it could be deduced that N+ ion fluence and annealing treatment helps to form (3 0 0) orientation in the crystalline structure of cadmium-telluride films. Fluctuations in optical properties like the optical band gap and absorption coefficient as a function of N+ ion fluences have been observed. The annealing of the sample irradiated by a dose of 1018 ions cm-2 has led to great enhancement in the optical absorption over a wide range of wavelengths with a thickness of 250 nm. The enhanced absorption is significantly higher than the observed value in the original CdTe layer with a thickness of 3 μm. Surface properties such as structure, grain size and roughness are noticeably affected by varying the nitrogen fluences. It is speculated that nitrogen bombardment and post-annealing treatment results in a smaller optical band gap, which in turn leads to higher absorption. Nitrogen bombardment is found to be a promising method to increase efficiency of thin film solar cells.

  18. Thermally Induced Nonlinear Optical Absorption in Metamaterial Perfect Absorbers

    CERN Document Server

    Guddala, Sriram; Ramakrishna, S Anantha

    2015-01-01

    A metamaterial perfect absorber consisting of a tri-layer (Al/ZnS/Al) metal-dielectric-metal system with top aluminium nano-disks is fabricated by laser-interference lithography and lift-off processing. The metamaterial absorber had peak resonant absorbance at 1090 nm and showed nonlinear absorption for 600ps laser pulses at 1064 nm wavelength. A nonlinear saturation of reflectance was measured to be dependent on the average laser power incident and not the peak laser intensity. The nonlinear behaviour is shown to arise from the heating due to the absorbed radiation and photo-thermal changes in the dielectric properties of aluminium. The metamaterial absorber is seen to be damage resistant at large laser intensities of 25 MW/cm2.

  19. Hybrid Microfluidic Platform for Multifactorial Analysis Based on Electrical Impedance, Refractometry, Optical Absorption and Fluorescence

    Directory of Open Access Journals (Sweden)

    Fábio M. Pereira

    2016-10-01

    Full Text Available This paper describes the development of a novel microfluidic platform for multifactorial analysis integrating four label-free detection methods: electrical impedance, refractometry, optical absorption and fluorescence. We present the rationale for the design and the details of the microfabrication of this multifactorial hybrid microfluidic chip. The structure of the platform consists of a three-dimensionally patterned polydimethylsiloxane top part attached to a bottom SU-8 epoxy-based negative photoresist part, where microelectrodes and optical fibers are incorporated to enable impedance and optical analysis. As a proof of concept, the chip functions have been tested and explored, enabling a diversity of applications: (i impedance-based identification of the size of micro beads, as well as counting and distinguishing of erythrocytes by their volume or membrane properties; (ii simultaneous determination of the refractive index and optical absorption properties of solutions; and (iii fluorescence-based bead counting.

  20. Optical absorption and refraction index change of a confined exciton in a spherical quantum dot nanostructure

    Science.gov (United States)

    Mathan Kumar, K.; John Peter, A.; Lee, C. W.

    2011-12-01

    Electronic energies of an exciton confined in a strained Zn1- x Cd x Se/ZnSe quantum dot have been computed as a function of dot radius with various Cd content. Calculations have been performed using Bessel function as an orthonormal basis for different confinement potentials of barrier height considering the internal electric field induced by the spontaneous and piezoelectric polarizations. The optical absorption coefficients and the refractive index changes between the ground state ( L = 0) and the first excited state ( L = 1) are investigated. It is found that the optical properties in the strained ZnCdSe/ZnSe quantum dot are strongly affected by the confinement potentials and the dot radii. The intensity of the total absorption spectra increases for the transition between higher levels. The obtained optical nonlinearity brings out the fact that it should be considered in calculating the optical properties in low dimensional semiconductors especially in quantum dots.

  1. Effect of Sn on the optical band gap determined using absorption spectrum fitting method

    Energy Technology Data Exchange (ETDEWEB)

    Heera, Pawan, E-mail: sramanb70@mailcity.com [Department of Physics, Himachal Pradesh University, Shimla, INDIA, 171005 (India); Govt. College Amb, Himachal Pradesh, INDIA,177203 (India); Kumar, Anup, E-mail: kumar.anup.sml@gmail.com [Department of Physics, Himachal Pradesh University, Shimla, INDIA, 171005 (India); Physics Department, Govt. College, Kullu, H. P., INDIA, 175101 (India); Sharma, Raman, E-mail: pawanheera@yahoo.com [Department of Physics, Himachal Pradesh University, Shimla, INDIA, 171005 (India)

    2015-05-15

    We report the preparation and the optical studies on tellurium rich glasses thin films. The thin films of Se{sub 30}Te{sub 70-x} Sn{sub x} system for x= 0, 1.5, 2.5 and 4.5 glassy alloys prepared by melt quenching technique are deposited on the glass substrate using vacuum thermal evaporation technique. The analysis of absorption spectra in the spectral range 400nm–4000 nm at room temperature obtained from UV-VIS-NIR spectrophotometer [Perkin Elmer Lamda-750] helps us in the optical characterization of the thin films under study. The absorption spectrum fitting method is applied by using the Tauc’s model for estimating the optical band gap and the width of the band tail of the thin films. The optical band gap is calculated and is found to decrease with the Sn content.

  2. Intraband optical absorption in a single quantum ring: Hydrostatic pressure and intense laser field effects

    Science.gov (United States)

    Barseghyan, M. G.

    2016-11-01

    The intraband optical absorption in GaAs/Ga0.7Al0.3As two-dimensional single quantum ring is investigated. Considering the combined effects of hydrostatic pressure and intense laser field the energy of the ground and few excited states has been found using the effective mass approximation and exact diagonalization technique. The energies of these states and the corresponding threshold energy of the intraband optical transitions are examined as a function of hydrostatic pressure for the different values of the laser field parameter. We also investigated the dependencies of the intraband optical absorption coefficient as a function of incident photon energy for different values of hydrostatic pressure and laser field parameter. It is found that the effects of hydrostatic pressure and intense laser field lead to redshift and blueshift of the intraband optical spectrum respectively.

  3. The origin of enhanced optical absorption in solar cells with metal nanoparticles embedded in the active layer

    KAUST Repository

    Lee, Jung-Yong

    2010-04-29

    We analyze the enhancement in optical absorption of an absorbing medium when spherical metal nanoparticles are embedded in it. Our analysis uses generalized Mie theory to calculate the absorbed optical power as a function of the distance from the metal nanoparticle. This analysis is used to evaluate the potential of enhancing optical absorption in thin-film solar cells by embedding spherical metal nanoparticles. We consider the trade-off between maximizing overall optical absorption and ensuring that a large fraction of the incident optical power is dissipated in the absorbing host medium rather than in the metal nanoparticle. We show that enhanced optical absorption results from strong scattering by the metal nanoparticle which locally enhances the optical electric fields. We also discuss the effect of a thin dielectric encapsulation of the metal nanoparticles. ©2010 Optical Society of America.

  4. Optical absorption analysis of quaternary molybdate- and tungstate-ordered double perovskites

    Energy Technology Data Exchange (ETDEWEB)

    Tablero, C., E-mail: ctablero@etsit.upm.es

    2015-08-05

    Highlights: • These compounds present a high optical absorption. • The absorption coefficients using different DFT + U alternatives have been compared. • The absorption coefficients have been split into different contributions. • The maximum efficiency is near the maximum efficiency for multiple-gap solar cells. - Abstract: Quaternary-ordered double perovskite A{sub 2}MM′O{sub 6} (M = Mo,W) semiconductors are a group of materials with a variety of photocatalytic and optoelectronic applications. An analysis focused on the optoelectronic properties is carried out using first-principles density-functional theory with several U orbital-dependent one-electron potentials applied to different orbital subspaces. The structural non-equivalence of the atoms resulting from the symmetry has been taken in account. In order to analyze optical absorption in these materials deeply, the absorption coefficients have been split into inter- and intra-non-equivalent species contributions. The results indicate that the effect of the A and M′ atoms on the optical properties are minimal whereas the largest contribution comes from the non-equivalent O atoms to M transitions.

  5. Aerosol absorption measurement with a sinusoidal phase modulating fiber optic photo thermal interferometer

    Science.gov (United States)

    Li, Shuwang; Shao, Shiyong; Mei, Haiping; Rao, Ruizhong

    2016-10-01

    Aerosol light absorption plays an important role in the earth's atmosphere direct and semi-direct radiate forcing, simultaneously, it also has a huge influence on the visibility impairment and laser engineering application. Although various methods have been developed for measuring aerosol light absorption, huge challenge still remains in precision, accuracy and temporal resolution. The main reason is that, as a part of aerosol light extinction, aerosol light absorption always generates synchronously with aerosol light scattering, and unfortunately aerosol light scattering is much stronger in most cases. Here, a novel photo-thermal interferometry is proposed only for aerosol absorption measurement without disturbance from aerosol scattering. The photo-thermal interferometry consists of a sinusoidal phase-modulating single mode fiber-optic interferometer. The thermal dissipation, caused by aerosol energy from photo-thermal conversion when irritated by pump laser through interferometer, is detected. This approach is completely insensitive to aerosol scattering, and the single mode fiber-optic interferometer is compact, low-cost and insensitive to the polarization shading. The theory of this technique is illustrated, followed by the basic structure of the sinusoidal phase-modulating fiber-optic interferometer and demodulation algorithms. Qualitative and quantitative analysis results show that the new photo-thermal interference is a potential approach for aerosol absorption detection and environmental pollution detection.

  6. Tunable spin and valley dependent magneto-optical absorption in molybdenum disulfide quantum dots

    Science.gov (United States)

    Qu, Fanyao; Dias, A. C.; Fu, Jiyong; Villegas-Lelovsky, L.; Azevedo, David L.

    2017-01-01

    Photonic quantum computer, quantum communication, quantum metrology and quantum optical technologies rely on the single-photon source (SPS). However, the SPS with valley-polarization remains elusive and the tunability of magneto-optical transition frequency and emission/absorption intensity is restricted, in spite of being highly in demand for valleytronic applications. Here we report a new class of SPSs based on carriers spatially localized in two-dimensional monolayer transition metal dichalcogenide quantum dots (QDs). We demonstrate that the photons are absorbed (or emitted) in the QDs with distinct energy but definite valley-polarization. The spin-coupled valley-polarization is invariant under either spatial or magnetic quantum quantization. However, the magneto-optical absorption peaks undergo a blue shift as the quantization is enhanced. Moreover, the absorption spectrum pattern changes considerably with a variation of Fermi energy. This together with the controllability of absorption spectrum by spatial and magnetic quantizations, offers the possibility of tuning the magneto-optical properties at will, subject to the robust spin-coupled valley polarization. PMID:28112197

  7. Influence of refractive index and solar concentration on optical power absorption in slabs

    Science.gov (United States)

    Williams, M. D.

    1988-01-01

    The optical power absorbed by a slab at the focus of a parabolic dish concentrator is calculated. The calculations are plotted versus maximum angle of incidence of irradiation (which corresponds to solar concentration) with absorption coefficient as a parameter for several different indices of refraction that represent real materials.

  8. Optical properties of black carbon aggregates with non-absorptive coating

    Science.gov (United States)

    Liu, Chao; Li, Ji; Yin, Yan; Zhu, Bin; Feng, Qian

    2017-01-01

    This study develops an idealized model to account for the effects of non-absorptive coating on the optical properties of black carbon (BC) aggregates. The classic fractal aggregate is applied to represent realistic BC particles, and the coating is assumed to be spherical. To accelerate the single-scattering simulation, BC monomers that were overlapped with coating sphere (not those completely inside the coating) are slightly moved to avoid overlapping. The multiple-sphere T-matrix method (MSTM) becomes applicable to calculate the optical properties of inhomogeneous particles with any coating amount, and is generally two orders of magnitude faster than the discrete-dipole approximation for particles we considered. Furthermore, the simple spherical coating is found to have similar effects on the optical properties to those based on more complicated coating structure. With the simple particle model and the efficient MSTM, it becomes possible to consider the influence of coating with much more details. The non-absorptive coating of BC aggregates can significantly enhance BC extinction and absorption, which is consistent with previous studies. The absorption of coated aggregates can be over two times stronger than that of BC particles without coating. Besides the coating volume, the relative position between the mass centers of BC aggregate and coating also plays an important role on the optical properties, and should obviously be considered in further studies.

  9. Electro-Optical Multichannel Spectrometer for Transient Resonance Raman and Absorption Spectroscopy

    DEFF Research Database (Denmark)

    Hansen, Karina Benthin; Wilbrandt, Robert Walter; Pagsberg, Palle Bjørn

    1979-01-01

    An optical multichannel system is described, used for time‐dependent absorption measurements in the gas phase and the liquid phase and for resonance Raman spectroscopy of short‐lived transient species in the liquid phase in pulse radiolysis. It consists of either an image converter streak unit or...

  10. Optical absorption and luminescence in neutron-irradiated, silica-based fibers

    Energy Technology Data Exchange (ETDEWEB)

    Cooke, D.W.; Farnum, E.H.; Clinard, F.W. [Los Alamos National Lab., CA (United States)] [and others

    1995-04-01

    The objectives of this work are to assess the effects of thermal annealing and photobleaching on the optical absorption of neutron-irradiated, silica fibers of the type proposed for use in ITER diagnostics, and to measure x-ray induced luminescence of unirradiated (virgin) and neutron-irradiated fibers.

  11. Calculation of optical absorption and resonance Raman correlators using time-dependent recursion relationships

    DEFF Research Database (Denmark)

    Svendsen, Christian; Mortensen, O. Sonnich; Henriksen, Niels Engholm

    1996-01-01

    Time-dependent recursion relationships are derived for optical absorption and resonance Raman correlators in the multidimensional harmonic case using a second-quantization formalism. Furthermore, a procedure is given for the calculation of correlators involving a general analytic coordinate depen...... dependence of the transition dipole moment....

  12. Tunable spin and valley dependent magneto-optical absorption in molybdenum disulfide quantum dots

    Science.gov (United States)

    Qu, Fanyao; Dias, A. C.; Fu, Jiyong; Villegas-Lelovsky, L.; Azevedo, David L.

    2017-01-01

    Photonic quantum computer, quantum communication, quantum metrology and quantum optical technologies rely on the single-photon source (SPS). However, the SPS with valley-polarization remains elusive and the tunability of magneto-optical transition frequency and emission/absorption intensity is restricted, in spite of being highly in demand for valleytronic applications. Here we report a new class of SPSs based on carriers spatially localized in two-dimensional monolayer transition metal dichalcogenide quantum dots (QDs). We demonstrate that the photons are absorbed (or emitted) in the QDs with distinct energy but definite valley-polarization. The spin-coupled valley-polarization is invariant under either spatial or magnetic quantum quantization. However, the magneto-optical absorption peaks undergo a blue shift as the quantization is enhanced. Moreover, the absorption spectrum pattern changes considerably with a variation of Fermi energy. This together with the controllability of absorption spectrum by spatial and magnetic quantizations, offers the possibility of tuning the magneto-optical properties at will, subject to the robust spin-coupled valley polarization.

  13. Electromagnetically induced absorption and transparency in an optical-rf two-photon coupling configuration

    Energy Technology Data Exchange (ETDEWEB)

    Fu Guangsheng [College of Physical Science and Technology, Hebei University, Baoding 071002 (China); Li Xiaoli [College of Physical Science and Technology, Hebei University, Baoding 071002 (China)], E-mail: xiaolixiaoli001@yahoo.com.cn; Zhuang Zhonghong; Zhang Lianshui; Yang Lijun; Li Xiaowei; Han Li [College of Physical Science and Technology, Hebei University, Baoding 071002 (China); Manson, Neil B.; Wei Changjiang [Laser Physics Center, Research School of Physical Sciences and Engineering, Australian Nation University, Canberra, ACT 0200 (Australia)

    2008-01-07

    We study electromagnetically induced absorption (EIA) and transparency (EIT) in an optical-rf two-photon coupling configuration. It is shown that the interference effect due to interacting dark resonances results in an EIA for a resonant two-photon coupling and this EIA is observed to evolve into an EIT when there is a detuning in the two-photon coupling.

  14. Optical pumping effect in absorption imaging of F =1 atomic gases

    Science.gov (United States)

    Kim, Sooshin; Seo, Sang Won; Noh, Heung-Ryoul; Shin, Y.

    2016-08-01

    We report our study of the optical pumping effect in absorption imaging of 23Na atoms in the F =1 hyperfine spin states. Solving a set of rate equations for the spin populations in the presence of a probe beam, we obtain an analytic expression for the optical signal of the F =1 absorption imaging. Furthermore, we verify the result by measuring the absorption spectra of 23Na Bose-Einstein condensates prepared in various spin states with different probe-beam pulse durations. The analytic result can be used in the quantitative analysis of F =1 spinor condensate imaging and readily applied to other alkali-metal atoms with I =3 /2 nuclear spin such as 87Rb.

  15. Theory of edge-state optical absorption in two-dimensional transition metal dichalcogenide flakes

    Science.gov (United States)

    Trushin, Maxim; Kelleher, Edmund J. R.; Hasan, Tawfique

    2016-10-01

    We develop an analytical model to describe sub-band-gap optical absorption in two-dimensional semiconducting transition metal dichalcogenide (s-TMD) nanoflakes. The material system represents an array of few-layer molybdenum disulfide crystals, randomly orientated in a polymer matrix. We propose that optical absorption involves direct transitions between electronic edge states and bulk bands, depends strongly on the carrier population, and is saturable with sufficient fluence. For excitation energies above half the band gap, the excess energy is absorbed by the edge-state electrons, elevating their effective temperature. Our analytical expressions for the linear and nonlinear absorption could prove useful tools in the design of practical photonic devices based on s-TMDs.

  16. Optical investigations and absorption coefficient determination of InGaN/GaN quantum wells

    Energy Technology Data Exchange (ETDEWEB)

    Kvietkova, J.; Siozade, L.; Disseix, P.; Vasson, A.; Leymarie, J. [Clermont-Ferrand-2 Univ., 63 - Aubiere (France). CNRS, LASMEA, UMR 6602; Damilano, B.; Grandjean, N.; Massies, J. [CNRS, CRHEAS, Sophia Antipolis, Valbonne (France)

    2002-03-16

    Thermally detected optical absorption (TDOA) and photoluminescence experiments were carried out on InGaN/GaN multi-quantum well (MQW) structures grown by molecular beam epitaxy on (0001) sapphire substrates. The absorption coefficient of the QW was extracted by modelling the TDOA lineshape. These experimental findings are confronted with the theoretical optical density evaluated within envelope function calculations of transition energies and oscillator strengths, including the electric field effects. The results show a relative agreement obtained by using a smaller value of the electric field than it has been predicted theoretically. However, other effects must be included in our model in order to achieve a realistic description of the absorption process in this sophisticated system. (orig.)

  17. Role of transfer of coherence in the enhanced absorption Hanle effect with two optical fields

    Energy Technology Data Exchange (ETDEWEB)

    Ram, Nibedita; Anupriya, J; Pattabiraman, M; Vijayan, C, E-mail: pattu@physics.iitm.ac.i [Department of Physics, Indian Institute of Technology, Madras, Chennai 600036 (India)

    2009-09-14

    The enhanced absorption Hanle effect has been studied for a closed transition J{sub g} = 2 -> J{sub e} = 3 with a transverse magnetic field in the presence of a coupling optical field. From an analysis of the individual probe and coupling field absorption profiles, it is shown that the Hanle electromagnetically induced absorption is governed by the transfer of {Delta}m = +-2 and {Delta}m = +-1 Zeeman coherences from the excited state to the ground state via spontaneous emission. The individual coherence contributions are governed by the intensity ratio of the optical fields. We show by computation and experiment that the magnetic field dependence of the forward scattered intensity can be used to distinguish the transfer of coherence contributions to the Hanle profile.

  18. Diffuse optical characterization of collagen absorption from 500 to 1700 nm

    Science.gov (United States)

    Sekar, Sanathana Konugolu Venkata; Bargigia, Ilaria; Mora, Alberto Dalla; Taroni, Paola; Ruggeri, Alessandro; Tosi, Alberto; Pifferi, Antonio; Farina, Andrea

    2017-01-01

    Reduction in scattering, high absorption, and spectral features of tissue constituents above 1000 nm could help in gaining higher spatial resolution, penetration depth, and specificity for in vivo studies, opening possibilities of near-infrared diffuse optics in tissue diagnosis. We present the characterization of collagen absorption over a broadband range (500 to 1700 nm) and compare it with spectra presented in the literature. Measurements were performed using a time-domain diffuse optical technique. The spectrum was extracted by carefully accounting for various spectral distortion effects, due to sample and system properties. The contribution of several tissue constituents (water, lipid, collagen, oxy, and deoxy-hemoglobin) to the absorption properties of a collagen-rich in vivo bone location, such as radius distal in the 500- to 1700-nm wavelength region, is also discussed, suggesting bone diagnostics as a potential area of interest.

  19. Optical absorption of neutron-irradiated silica fibers

    Energy Technology Data Exchange (ETDEWEB)

    Cooke, D.W.; Farnum, E.H.; Bennett, B.L. [Los Alamos National Lab., NM (United States)

    1996-10-01

    Induced-loss spectra of silica-based optical fibers exposed to high (10{sup 23} n-m{sup {minus}2}) and low (10{sup 21} n-m{sup {minus}2}) fluences of neutrons at the Los Alamos Spallation Radiation Effects Facility (LASREF) have been measured. Two types of fibers consisting of a pure fused silica core with fluorine-doped ({approximately}4 mole %) cladding were obtained from Fiberguide Industries and used in the as-received condition. Anhydroguide{trademark} and superguide{trademark} fibers contained less than 1 ppm, and 600 to 800 ppm of OH, respectively. The data suggest that presently available silica fibers can be used in plasma diagnostics, but the choice and suitability depends upon the spectral region of interest. Low-OH content fibers can be used for diagnostic purposes in the interval {approximately}800 to 1400 mn if the exposure is to high-fluence neutrons. For low-fluence neutron exposures, the low-OH content fibers are best suited for use in the interval {approximately}800 to 2000 nm, and the high-OH content fibers are the choice for the interval {approximately}400 to 800 nm.

  20. Long Wavelength Plasmonic Absorption Enhancement in Silicon Using Optical Lithography Compatible Core-Shell-Type Nanowires

    Directory of Open Access Journals (Sweden)

    Mohammed Shahriar Sabuktagin

    2014-01-01

    Full Text Available Plasmonic properties of rectangular core-shell type nanowires embedded in thin film silicon solar cell structure were characterized using FDTD simulations. Plasmon resonance of these nanowires showed tunability from  nm. However this absorption was significantly smaller than the Ohmic loss in the silver shell due to very low near-bandgap absorption properties of silicon. Prospect of improving enhanced absorption in silicon to Ohmic loss ratio by utilizing dual capability of these nanowires in boosting impurity photovoltaic effect and efficient extraction of the photogenerated carriers was discussed. Our results indicate that high volume fabrication capacity of optical lithography techniques can be utilized for plasmonic absorption enhancement in thin film silicon solar cells over the entire long wavelength range of solar radiation.

  1. Optical Absorption Measurements on Nitrogen-doped 6H-SiC Single Crystals

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    6H-SiC bulk crystals have been prepared by sublimation method in an inductively heated growth reactor. The effect of nitrogen doping on absorption for 6H-SiC was investigated. The absorption measurement based on optical method is a non-destructive and non-contact method. The band-gap narrowing with higher doping concentration was observed.For n-type doping below band-gap absorption band at 623 nm for 6H-SiC was observed. The peak intensity of the absorption band increased with increasing charge carrier concentration obtained from Hall measurements. It is also found that the nitrogen doping level decreased in the radial direction and it was the highest at the beginning of growth.

  2. Linear and nonlinear optical absorption coefficients of two-electron spherical quantum dot with parabolic potential

    Science.gov (United States)

    Çakır, Bekir; Yakar, Yusuf; Özmen, Ayhan

    2015-02-01

    Linear and nonlinear absorption coefficients of two-electron spherical quantum dot (QD) with parabolic potential are investigated in this paper. Wave functions and energy eigenvalues of the 1s2, 1s1p, 1s1d and 1s1f electronic states have been computed by using an optimization approach, which is a combination of Quantum Genetic Algorithm (QGA) and Hartree-Fock Roothaan (HFR) method. It is found that the strength of S→P transition is stronger than P→D and D→F transitions. Also the peak positions and amplitudes of the absorption coefficients are sensitive to the electron spin. It should be noted that the peak positions and amplitudes of absorption coefficients are strongly dependent on the parabolic potential. Additionally, dot radius, impurity charge, incident optical intensity and relaxation time have a great influence on the linear and nonlinear absorption coefficients.

  3. Linear and nonlinear optical absorption coefficients of two-electron spherical quantum dot with parabolic potential

    Energy Technology Data Exchange (ETDEWEB)

    Çakır, Bekir, E-mail: bcakir@selcuk.edu.tr [Physics Department, Faculty of Science, Selcuk University, Campus 42075, Konya (Turkey); Yakar, Yusuf, E-mail: yuyakar@yahoo.com [Physics Department, Faculty of Arts and Science, Aksaray University, Campus 68100, Aksaray (Turkey); Özmen, Ayhan [Physics Department, Faculty of Science, Selcuk University, Campus 42075, Konya (Turkey)

    2015-02-01

    Linear and nonlinear absorption coefficients of two-electron spherical quantum dot (QD) with parabolic potential are investigated in this paper. Wave functions and energy eigenvalues of the 1s{sup 2}, 1s1p, 1s1d and 1s1f electronic states have been computed by using an optimization approach, which is a combination of Quantum Genetic Algorithm (QGA) and Hartree–Fock Roothaan (HFR) method. It is found that the strength of S→P transition is stronger than P→D and D→F transitions. Also the peak positions and amplitudes of the absorption coefficients are sensitive to the electron spin. It should be noted that the peak positions and amplitudes of absorption coefficients are strongly dependent on the parabolic potential. Additionally, dot radius, impurity charge, incident optical intensity and relaxation time have a great influence on the linear and nonlinear absorption coefficients.

  4. All-optical switching in a symmetric three-waveguide coupler with phase-mismatched absorptive central waveguide.

    Science.gov (United States)

    Chen, Yijing; Ho, Seng-Tiong; Krishnamurthy, Vivek

    2013-12-20

    All-optical switching operation based on manipulation of absorption in a three-waveguide directional coupler is theoretically investigated. The proposed structure consists of one absorptive central waveguide and two identical passive side waveguides. Optically induced absorption change in the central waveguide effectively controls the coupling of light between the two side waveguides, leading to optical switching action. The proposed architecture alleviates the fabrication challenges and waveguide index matching conditions that limit previous demonstrations of similar switching schemes based on a two-waveguide directional coupler. The proposed device accommodates large modal index difference between absorptive and passive waveguides without compromising the switching extinction ratio.

  5. Characteristic features of optical absorption for Gd2O3 and NiO nanoparticles

    Science.gov (United States)

    Zatsepin, A. F.; Kuznetsova, Yu. A.; Rychkov, V. N.; Sokolov, V. I.

    2017-03-01

    The technical approach to determination of the structural and optical parameters of oxides with reduced dimensionality based on optical absorption measurements is described by example of gadolinium and nickel oxides. It was established that the temperature behavior of fundamental absorption edge for oxide nanoparticles is similar with the bulk materials with crystal structure. At the same time, the energy characteristics (band gap and effective phonon energies) for low-dimensional oxides are found to be significantly different from their bulk counterparts. The presented methodological method to obtain of qualitative and quantitative correlations of structural and optical characteristics provides novel reliable knowledge of nanoscaled 3d and 4f-metal oxide materials that is useful for development of their practical applications.

  6. Dual beam light profile microscopy: a new technique for optical absorption depth profilometry.

    Science.gov (United States)

    Power, J F; Fu, S W

    2004-02-01

    Light profile microscopy (LPM) is a recently developed technique of optical inspection that is used to record micrometer-scale images of thin-film cross-sections on a direct basis. In single beam mode, LPM provides image contrast based on luminescence, elastic, and/or inelastic scatter. However, LPM may also be used to depth profile the optical absorption coefficient of a thin film based on a method of dual beam irradiation presented in this work. The method uses a pair of collimated laser beams to consecutively irradiate a film from two opposing directions along the depth axis. An average profile of the beam's light intensity variation through the material is recovered for each direction and used to compute a depth-dependent differential absorbance profile. This latter quantity is shown from theory to be related to the film's depth-dependent optical absorption coefficient through a simple linear model that may be inverted by standard methods of numerical linear algebra. The inverse problem is relatively well posed, showing good immunity to data errors. This profilometry method is experimentally applied to a set of well-characterized materials with known absorption properties over a scale of tens of micrometers, and the reconstructed absorption profiles were found to be highly consistent with the reference data.

  7. Influence of TiO2 nanostructures on the optical absorption of organic-inorganic perovskite

    Science.gov (United States)

    Liu, Zongyi; Ye, Mao; Ostrowski, Michel; Yi, Ya Sha

    2016-04-01

    This work aims to reveal the strong influence of TiO2 nanostructures on the light absorption property of TiO2 and perovskite mixture. Three TiO2 nanostructures, i.e., nanoparticles (S1), ultrapure nanorods (S2), and ultrasmall nanorods (S3), were studied: S1 was selected as a baseline; S2 and S3 were synthesized from S1 by using modified hydrothermal processes. Mesoporous TiO2 thin films were spin-coated from solutions containing these TiO2 nanorods and nanoparticles (S1 as baseline). Organic-inorganic hybrid perovskite CH3NH3PbI3 was then incorporated into these mesoporous TiO2 thin films. Optical absorption results showed that the perovskite mixture with ultrasmall TiO2 nanostructures (S3) has significantly higher optical absorption coefficient. Finite-difference time domain models were built based on three distinct nanostructures of TiO2 and CH3NH3PbI3 mixtures fabricated (S1 to S3) to understand their optical absorption properties. Our work is promising to fabricate TiO2 nanostructures, as a backbone structure, for a series of applications including photovoltaics and photodetection.

  8. Breaking inversion symmetry induces excitonic peak in optical absorption of topological semimetal

    Science.gov (United States)

    Dadsetani, Mehrdad; Ebrahimian, Ali

    2017-01-01

    In this work we present ab initio study on linear optical properties of Dirac and Weyl semimetals and tried to find the consequences of inversion symmetry breaking in the optical properties of topological semimetal. The real and imaginary part of dielectric function in addition to energy loss spectra of topological semimetal with and without inversion symmetry have been calculated within Random phase approximation (RPA) then the electron-hole interaction is included by solving the Bethe-Salpeter Equation (BSE) for the electron-hole Green's function. We find that the lack of inversion symmetry and spin-orbit interaction increases the density of states at Fermi level, giving rise to excitonic peak in optical absorption of topological semimetal. It is remarkable that the excitonic effects in high energy range of the spectrum are stronger than in the lower one. To explore the breaking of inversion symmetry related optical properties, we have investigated the optical properties of Dirac semimetals Na3Bi and BaPt and compared them to corresponding ones in Weyl semimetals NbP and Na3Bi0.75Sb0.25. Our calculations show that NbP, which lacks inversion symmetry, has high energy exciton at 10 and 10.8 eV. In contrast with Na3Bi, electron-hole interactions give rise to several weak peaks at different energy in the optical absorption of Na3Bi0.75Sb0.25 while its red shift is less pronounced.

  9. Recent Progress Towards Quantum Dot Solar Cells with Enhanced Optical Absorption

    Science.gov (United States)

    Zheng, Zerui; Ji, Haining; Yu, Peng; Wang, Zhiming

    2016-05-01

    Quantum dot solar cells, as a promising candidate for the next generation solar cell technology, have received tremendous attention in the last 10 years. Some recent developments in epitaxy growth and device structures have opened up new avenues for practical quantum dot solar cells. Unfortunately, the performance of quantum dot solar cells is often plagued by marginal photon absorption. In this review, we focus on the recent progress made in enhancing optical absorption in quantum dot solar cells, including optimization of quantum dot growth, improving the solar cells structure, and engineering light trapping techniques.

  10. Absorption spectroscopy measurements in optically dense explosive fireballs using a modeless broadband dye laser.

    Science.gov (United States)

    Glumac, Nick

    2009-09-01

    A modeless broadband dye laser is applied to probe inside optically dense fireballs generated by high explosives using single-shot, high resolution absorption spectroscopy. Despite attenuation of the main beam by 98%, high signal-to-noise ratio absorption spectra of Al, Ti, and AlO are readily obtained at resolutions of 0.007 nm, and luminosity from the fireball is strongly rejected. Detection limits for atomic species are less than 200 ppb. The method offers good time resolution of chemistry within the fireball, and scaling laws suggest that this technique should be valid in explosives tests at least up to the gram scale.

  11. Recent Progress Towards Quantum Dot Solar Cells with Enhanced Optical Absorption.

    Science.gov (United States)

    Zheng, Zerui; Ji, Haining; Yu, Peng; Wang, Zhiming

    2016-12-01

    Quantum dot solar cells, as a promising candidate for the next generation solar cell technology, have received tremendous attention in the last 10 years. Some recent developments in epitaxy growth and device structures have opened up new avenues for practical quantum dot solar cells. Unfortunately, the performance of quantum dot solar cells is often plagued by marginal photon absorption. In this review, we focus on the recent progress made in enhancing optical absorption in quantum dot solar cells, including optimization of quantum dot growth, improving the solar cells structure, and engineering light trapping techniques.

  12. Matrix formalism for light propagation and absorption in thick textured optical sheets.

    Science.gov (United States)

    Eisenlohr, Johannes; Tucher, Nico; Höhn, Oliver; Hauser, Hubert; Peters, Marius; Kiefel, Peter; Goldschmidt, Jan Christoph; Bläsi, Benedikt

    2015-06-01

    In this paper, we introduce a simulation formalism for determining the Optical Properties of Textured Optical Sheets (OPTOS). Our matrix-based method allows for the computationally-efficient calculation of non-coherent light propagation and absorption in thick textured sheets, especially solar cells, featuring different textures on front and rear side that may operate in different optical regimes. Within the simulated system, the angular power distribution is represented by a vector. This light distribution is modified by interaction with the surfaces of the textured sheets, which are described by redistribution matrices. These matrices can be calculated for each individual surface texture with the most appropriate technique. Depending on the feature size of the texture, for example, either ray- or wave-optical methods can be used. The comparison of the simulated absorption in a sheet of silicon for a variety of surface textures, both with the results from other simulation techniques and experimentally measured data, shows very good agreement. To demonstrate the versatility of this newly-developed approach, the absorption in silicon sheets with a large-scale structure (V-grooves) at the front side and a small-scale structure (diffraction grating) at the rear side is calculated. Moreover, with minimal computational effort, a thickness parameter variation is performed.

  13. Optical absorption in asymmetric double quantum wells driven by two intense terahertz fields

    Institute of Scientific and Technical Information of China (English)

    Wu Hong-Wei; Mi Xian-Wu

    2013-01-01

    Optical absorption is investigated for asymmetric double quantum wells driven by a resonant terahertz field and a varied terahertz field,both polarized along the growth direction.Rich nonlinear dynamics of the replica peak and the Autler-Townes splitting of various dressed states are systematically studied in undoped asymmetric double quantum wells by taking account of multiple factors,such as the frequency of the varied terahertz field and the strength of the resonant terahertz field.Each electron subband splits into two dressed states when the resonant terahertz field is applied in the absence of the varied terahertz field,the optical absorption spectrum shows the first-order Autler-Townes splitting of the electron subbands.When a varied terahertz field is added into the resonant system,the replica peak and the second-order Autler-Townes splitting of the dressed states near the band edge respectively emerge when the varied terahertz field is non-resonant and resonant with these dressed states.Wben the strength of the resonant terahertz field is increased,the first-order Autler-Townes double peaks and the replica peak in the optical absorption spectrum shift with the shifts of the dressed states.The presented results have potential applications in electro-optical devices.

  14. Effects of {gamma} and neutron irradiation on the optical absorption of pure silica core single-mode optical fibres from Nufern

    Energy Technology Data Exchange (ETDEWEB)

    Calderon, A. [Instituto de Fisica de Cantabria, CSIC-University of Cantabria, Santander (Spain); Martinez-Rivero, C. [Instituto de Fisica de Cantabria, CSIC-University of Cantabria, Santander (Spain); Matorras, F. [Instituto de Fisica de Cantabria, CSIC-University of Cantabria, Santander (Spain); Rodrigo, T. [Instituto de Fisica de Cantabria, CSIC-University of Cantabria, Santander (Spain); Sobron, M. [Instituto de Fisica de Cantabria, CSIC-University of Cantabria, Santander (Spain); Vila, I. [Instituto de Fisica de Cantabria, CSIC-University of Cantabria, Santander (Spain); Virto, A.L. [Instituto de Fisica de Cantabria, CSIC-University of Cantabria, Santander (Spain); Alberdi, J. [CIEMAT, Particle Physics, Avda. Complutense 22, 28040, Madrid (Spain); Arce, P. [CIEMAT, Particle Physics, Avda. Complutense 22, 28040, Madrid (Spain); Barcala, J.M. [CIEMAT, Particle Physics, Avda. Complutense 22, 28040, Madrid (Spain); Calvo, E. [CIEMAT, Particle Physics, Avda. Complutense 22, 28040, Madrid (Spain); Ferrando, A. [CIEMAT, Particle Physics, Avda. Complutense 22, 28040, Madrid (Spain)]. E-mail: Antonio.Ferrando@ciemat.es; Josa, M.I. [CIEMAT, Particle Physics, Avda. Complutense 22, 28040, Madrid (Spain); Luque, J.M. [CIEMAT, Particle Physics, Avda. Complutense 22, 28040, Madrid (Spain); Molinero, A. [CIEMAT, Particle Physics, Avda. Complutense 22, 28040, Madrid (Spain); Navarrete, J. [CIEMAT, Particle Physics, Avda. Complutense 22, 28040, Madrid (Spain); Oller, J.C. [CIEMAT, Particle Physics, Avda. Complutense 22, 28040, Madrid (Spain); Valdivieso, P. [CIEMAT, Particle Physics, Avda. Complutense 22, 28040, Madrid (Spain); Yuste, C. [CIEMAT, Particle Physics, Avda. Complutense 22, 28040, Madrid (Spain); Fenyvesi, A. [Institute of Nuclear Research, ATOMKI, Debrecen (Hungary); Molnar, J. [Institute of Nuclear Research, ATOMKI, Debrecen (Hungary)

    2006-09-15

    A measurement of the optical absorption, induced by photon irradiation up to a dose of 0.9 MGy, in Nufern silica core single-mode optical fibres is presented. In addition, the fibres were irradiated with neutrons, up to a total fluence of 2x10{sup 14} cm{sup -2} and the induced optical absorption was evaluated for four different wavelengths: 630, 670, 681 and 785 nm.

  15. Localized modes in optics of photonic liquid crystals with local anisotropy of absorption

    Science.gov (United States)

    Belyakov, V. A.; Semenov, S. V.

    2016-05-01

    The localized optical modes in spiral photonic liquid crystals are theoretically studied for the certainty at the example of chiral liquid crystals (CLCs) for the case of CLC with an anisotropic local absorption. The model adopted here (absence of dielectric interfaces in the structures under investigation) makes it possible to get rid of mixing of polarizations on the surfaces of the CLC layer and of the defect structure and to reduce the corresponding equations to only the equations for light with polarization diffracting in the CLC. The dispersion equations determining connection of the edge mode (EM) and defect mode (DM) frequencies with the CLC layer parameters (anisotropy of local absorption, CLC order parameter) and other parameters of the DMS are obtained. Analytic expressions for the transmission and reflection coefficients of CLC layer and DMS for the case of CLC with an anisotropic local absorption are presented and analyzed. It is shown that the CLC layers with locally anisotropic absorption reduce the EM and DM lifetimes (and increase the lasing threshold) in the way different from the case of CLC with an isotropic local absorption. Due to the Borrmann effect revealing of which is different at the opposite stop-band edges in the case of CLC layers with an anisotropic local absorption the EM life-times for the EM frequencies at the opposite stop-bands edges may be significantly different. The options of experimental observations of the theoretically revealed phenomena are briefly discussed.

  16. Nonlinear Optical Absorption of Organic Molecules for Applications in Optical Devices

    OpenAIRE

    Boni, Leonardo De; Daniel S. Correa; Mendonca, Cleber R.

    2010-01-01

    This chapter aimed to describe the resonant nonlinear optical properties of four important organic molecules: Chlorophyll A, Indocyanine Green, Ytterbium Bisphthalocyanine and Cytochrome C, which are materials that present interesting optical nonlinearities for applications in optical devices. It was shown that Chlorophyll A solution exhibits a RSA process for Q-switched and mode-locked laser pulses, with an intersystem-crossing time relatively fast and a triplet state cross section value twi...

  17. Management of light absorption in extraordinary optical transmission based ultra-thin-film tandem solar cells

    Science.gov (United States)

    Mashooq, Kishwar; Talukder, Muhammad Anisuzzaman

    2016-05-01

    Although ultra-thin-film solar cells can be attractive in reducing the cost, they suffer from low absorption as the thickness of the active layer is usually much smaller than the wavelength of incident light. Different nano-photonic techniques, including plasmonic structures, are being explored to increase the light absorption in ultra-thin-film solar cells. More than one layer of active materials with different energy bandgaps can be used in tandem to increase the light absorption as well. However, due to different amount of light absorption in different active layers, photo-generated currents in different active layers will not be the same. The current mismatch between the tandem layers makes them ineffective in increasing the efficiency. In this work, we investigate the light absorption properties of tandem solar cells with two ultra-thin active layers working as two subcells and a metal layer with periodically perforated holes in-between the two subcells. While the metal layer helps to overcome the current mismatch, the periodic holes increase the absorption of incident light by helping extraordinary optical transmission of the incident light from the top to the bottom subcell, and by coupling the incident light to plasmonic and photonic modes within ultra-thin active layers. We extensively study the effects of the geometry of holes in the intermediate metal layer on the light absorption properties of tandem solar cells with ultra-thin active layers. We also study how different metals in the intermediate layer affect the light absorption; how the geometry of holes in the intermediate layer affects the absorption when the active layer materials are changed; and how the intermediate metal layer affects the collection of photo-generated electron-hole pairs at the terminals. We find that in a solar cell with 6,6-phenyl C61-butyric acid methyl ester top subcell and copper indium gallium selenide bottom subcell, if the periodic holes in the metal layer are square or

  18. Complete optical absorption of ultrashort pulses by plasmons in nanostructured graphene (Conference Presentation)

    Science.gov (United States)

    Martínez Saavedra, José Ramón; Cerullo, Giulio; Pruneri, Valerio; Wall, Simon; García de Abajo, Javier

    2016-10-01

    The peculiar electronic structure of graphene results in a large optoelectronic response that holds great potential for technology. For example, this material exhibits a nearly constant absorption 2.3% over a broad spectral range [1], which can be electrically modulated in the mid-IR by injecting attainable densities of charge carriers. When doped, graphene can sustain plasmons that radically modify its optical response, enabling complete optical absorption for suitably designed patterns [2]. Graphene nanoribbons constitute one of the simplest geometrical patterns that one can produce. They have been extensively studied and their plasmons accurately explained with simple models [3]. When heated to a large electronic temperature, graphene behaves nearly as if is was highly doped, also giving rise to plasmon modes [4]. In this work, we study the possibility of using ultrashort light pulses together with the natural electronic relaxation mechanisms in graphene nanoribbons as a way to tune their optical response. We first discuss the optically induced plasmons of individual nanoribbons when illuminated with ultrashort pulses and then analyze the evolution of the plasmon frequency as a function of the delay between pump and probe. We study the redshift of these plasmons with increasing delay due to electron relaxation. We also investigate the optical response of the ribbon exposed to a train of optical pulses. We further discuss ribbon arrays illuminated from the substrate under total internal reflection conditions, for which we predict complete absorption for a suitable choice of geometrical and illumination parameters. References [1] F. H. L. Koppens, D. E. Chang, and F. J. García de Abajo, Nano Letters 11, 3370-3377 (2011) [2] S. Thongrattanasiri, F. H. L. Koppens, and F. J. García de Abajo, Phys. Rev. Lett. 108, 047401 (2012) [3] I. Silveiro, J. M. Plaza Ortega, and F. J. García de Abajo, Light: Science and Applications 4, e241 (2015) [4] F. J. García de Abajo

  19. Short optical pulse generation at 40 GHz with a bulk electro-absorption modulator packaged device

    Science.gov (United States)

    Langlois, Patrick; Moore, Ronald; Prosyk, Kelvin; O'Keefe, Sean; Oosterom, Jill A.; Betty, Ian; Foster, Robert; Greenspan, Jonathan; Singh, Priti

    2003-12-01

    Short optical pulse generation at 40GHz and 1540nm wavelength is achieved using fully packaged bulk quaternary electro-absorption modulator modules. Experimental results obtained with broadband and narrowband optimized packaged modules are presented and compared against empirical model predictions. Pulse duty cycle, extinction ratio and chirp are studied as a function of sinusoidal drive voltage and detuning between operating wavelength and modulator absorption band edge. Design rules and performance trade-offs are discussed. Low-chirp pulses with a FWHM of ~12ps and sub-4ps at a rate of 40GHz are demonstrated. Optical time-domain demultiplexing of a 40GHz to a 10GHz pulse train is also demonstrated with better than 20dB extinction ratio.

  20. Optical Absorption Spectra and Intraband Dynamics in Terahertz-Driven Semiconductor Superlattice

    Institute of Scientific and Technical Information of China (English)

    MI Xian-Wu

    2004-01-01

    @@ We have theoretically investigated the optical absorption spectrum and intraband dynamics by subjecting a superlattice to both a terahertz (THz)-frequency driving field and an optical pulse by using an excitonic basis.In the presence of a THz dc field, the satellite structures in the absorption spectra are presented. The satellite structure is a result from the THz nonlinear dynamics of Wannier-Stark ladder excitons. On the other hand, the coherent intraband polarization is investigated. We find that the excitonic Bloch oscillation is driven by the THz field and yields an intraband polarization that continues to oscillate at times much longer than the intraband dephasing time. The temporal evolution of the slowly varying components of the intraband polarization is dependent on the THz frequency.

  1. First principles electron-correlated calculations of optical absorption in magnesium clusters

    CERN Document Server

    Shinde, Ravindra

    2015-01-01

    In this paper we report the calculations of linear optical absorption spectra of various isomers of magnesium clusters Mg$_{n}$ (n=2--5) involving valence transitions, performed using the large-scale all-electron configuration interaction (CI) methodology. First, geometries of several low-lying isomers of each cluster were optimized at the coupled-cluster singles doubles (CCSD) level of theory. These geometries were subsequently employed to perform ground and excited state calculations on these systems using the multi-reference singles-doubles configuration-interaction (MRSDCI) approach, which includes electron correlation effects at a sophisticated level. Resultant CI wave functions were used to compute the optical absorption spectra within the electric-dipole approximation. Our results on magnesium dimer (Mg$_{2}$) isomer are in excellent agreement with the experiments as far as oscillator strengths, and excitation energies are concerned. Owing to a better description of electron-correlation effects, these ...

  2. Optical absorption properties of Ag/SiO sub 2 composite films induced by gamma irradiation

    CERN Document Server

    Pan, A L; Yang, Z P; Liu, F X; Ding, Z J; Qian, Y T

    2003-01-01

    Mesoporous SiO sub 2 composite films with small Ag particles or clusters dispersed in them were prepared by a new method: first the matrix SiO sub 2 films were prepared by the sol-gel process combined with the dip-coating technique; then they were soaked in AgNO sub 3 solutions; this was followed by irradiation with gamma-rays at room temperature and ambient pressure. The structure of these films was examined by high-resolution transmission electron microscopy, and their optical absorption spectra were examined. It has been shown that the Ag particles grown within the porous SiO sub 2 films are very small and are highly dispersed. On increasing the soaking concentration and subjecting the samples to an additional annealing, a different peak-shift effect for the surface plasmon resonance was observed in the optical absorption measurement. Possible mechanisms of this behaviour are discussed in this paper.

  3. Optical Absorption and Electric Resistivity of an l-Cysteine Film

    Science.gov (United States)

    Kamada, Masao; Hideshima, Takuya; Azuma, Junpei; Yamamoto, Isamu; Imamura, Masaki; Takahashi, Kazutoshi

    2016-12-01

    The optical and electric properties of an l-cysteine film have been investigated to understand its applicability to bioelectronics. The fundamental absorption is the allowed transition having the threshold at 5.8 eV and the absorption is due to the charge-transfer type transition from sulfur-3sp to oxygen-2p and/or carbon-2p states, while absorptions more than 9 eV can be explained with intra-atomic transitions in the functional groups. The electric resistivity is 2.0 × 104 Ω m at room temperature and increases as the sample temperature decreases. The results indicate that the l-cysteine film is a p-type semiconductor showing the hole conduction caused by the sulfur-3sp occupied states and unknown impurity or defect states as acceptors. The electron affinity of the l-cysteine film is derived as ≦-0.3 eV.

  4. Investigation of Third Order Optical Nonlinearity and Reverse Saturable Absorption of Octa-alkoxy Metallophthalocyanines

    Science.gov (United States)

    Sanghadasa, Mohan; Shin, In-Seek; Barr, Thomas A.; Clark, Ronald D.; Guo, Huai-Song; Martinez, Angela; Penn, Benjamin G.

    1998-01-01

    In recent years, there has been a growing interest in the development of passive optical power limiters for the protection of the human eye and solid-state sensors from damage caused by energetic light pulses and also for other switching applications. One of the key issues involved is the search for appropriate materials that show effective reverse saturable absorption. Phthalocyanines seem to be good candidates for such applications because of their higher third order nonlinearity and the unique electronic absorption characteristics. A series of 1,4,8,11,15, 18,22,25-octa-alkoxy metallophthalocyanines containing various central metal atoms such as zinc, copper, palladium, cobalt and nickel were characterized for their third order nonlinearity and for their nonlinear absorptive properties to evaluate their suitability to function as reverse saturable absorbers.

  5. Optical absorption of small copper clusters in neon: Cu(n), (n = 1-9).

    Science.gov (United States)

    Lecoultre, S; Rydlo, A; Félix, C; Buttet, J; Gilb, S; Harbich, W

    2011-02-21

    We present optical absorption spectra in the UV-visible range (1.6 eV neon matrix at 7 K. The atom and the dimer have already been measured in neon matrices, while the absorption spectra for sizes between Cu(3) and Cu(9) are entirely (n = 6-9) or in great part new. They show a higher complexity and a larger number of transitions distributed over the whole energy range compared to similar sizes of silver clusters. The experimental spectra are compared to the time dependent density functional theory (TD-DFT) implemented in the TURBOMOLE package. The analysis indicates that for energies larger than 3 eV the transitions are mainly issued from d-type states; however, the TD-DFT scheme does not reproduce well the detailed structure of the absorption spectra. Below 3 eV the agreement for transitions issued from s-type states is better.

  6. Optical absorption enhancement in slanted silicon nanocone hole arrays for solar photovoltaics

    Science.gov (United States)

    Zhang, Shu-Yuan; Liu, Wen; Li, Zhao-Feng; Liu, Min; Liu, Yu-Sheng; Wang, Xiao-Dong; Yang, Fu-Hua

    2016-10-01

    We investigate slanted silicon nanocone hole arrays as light absorbing structures for solar photovoltaics via simulation. With only 1-μm equivalent thickness, a maximum short-circuit current density of 34.9 mA/cm2 is obtained. Moreover, by adding an Ag mirror under the whole structure, a short-circuit current density of 37.9 mA/cm2 is attained. It is understood that the optical absorption enhancement mainly results from three aspects. First, the silicon nanocone holes provide a highly efficient antireflection effect. Second, after breaking the geometric symmetry, the slanted silicon nanocone hole supports more resonant absorption modes than vertical structures. Third, the Fabry-Perot resonance enhances the light absorption after adding an Ag mirror. Project supported by the National Natural Science Foundation of China (Grant Nos. 61274066, 61474115, and 61504138) and the National High Technology Research and Development Program of China (Grant No. 2014AA032602).

  7. Solar absorptance degradation of optical solar reflector radiators on the Spacenet satellites

    Science.gov (United States)

    Naegeli, Charles R.

    1992-01-01

    Telemetry data are presented for two communications hybrid satellites, Spacenet I and Spacenet II, collected to determine the long-term temperature trend and associated solar absorptance degradation of the optical solar reflectors (OSRs). A thermal model was used to calculate the thermal sensitivity of various OSR components to changes in the solar absorptance and to determine absolute values of solar absorptance. The separation of the data into sunlit and nonsunlit periods made it possible to confirm the hypothesis that degradation occurs under the catalytic activity of direct sunlight on the spacecraft contaminants. The differences found between the degradation rates for Spacenet-I and Spacenet-II satellites and between the present results and published reports on other satellites are considered to be related to variations in the volume of spacecraft contaminants.

  8. Two-Photon Absorption and Optical Power Limiting Based on New Organic Dyes

    Institute of Scientific and Technical Information of China (English)

    周广勇; 王东; 邵宗书; 蒋民华; 雷虹

    2001-01-01

    Two new organic dye samples J and L with a large two-photon absorption (TPA) cross section have been reported.The linear absorption spectra show that there is no linear absorption at the wavelength from 650 to 1200 nm.The molecular TPA cross section was measured to be as high as 2.59×10-47 cm4.s and 2.98×10-47 cm4.s at 1064 nm for samples J and L, respectively. The input-output curves indicate that there is a clear optical power limiting behaviour when the input intensity is higher than 0.4 GW/cm2. Furthermore, the basic theory of the TPA process has been discussed.

  9. INVERSE COMPUTATION OF OPTICAL-ABSORPTION COEFFICIENT IN INHOMOGENEOUS MATERIAL WITH VARIED THERMAL CONDUCTIVITY

    Institute of Scientific and Technical Information of China (English)

    ZhuJianxin

    2002-01-01

    In this paper,for an inhomogeneous material in which the thermal conductivity varies as a function of depth,an efficient treatment is proposed to inversely calculate the depth distribution of optical-absorption coefficient by the surface temperature of the material. It is demonstrated that the results of inverse computation by that method are more similar to the experimental ones measured by some destructive method. Thus ,the treatment is more feasible to nondestructively estimate the distribution.

  10. Optical absorption and fluorescence properties of $Er^{3+}$ in sodium borate glass

    OpenAIRE

    Ratnakaram, YC; J.Lakshmi; Chakradhar, RPS

    2005-01-01

    Spectroscopic properties of $Er^{3+}$ ions in sodium borate glass have been studied. The indirect and direct optical band gaps $(E_{opt})$ and energy level parameters (Racah $(E^{1}, E^{2} and E^{3})$, spin-orbit $(\\xi_{4f})$ and configurational interaction (\\alpha)) are evaluated. Spectral intensities for various absorption bands of $Er^{3+}$ doped sodium borate glass are calculated. Using Judd-Ofelt intensity parameters $(\\Omega_{2},\\Omega_{4}, \\Omega_{6})$, radiative transition probabiliti...

  11. Self-absorption influence on the optical spectroscopy of zinc oxide laser produced plasma

    Energy Technology Data Exchange (ETDEWEB)

    De Posada, E; Arronte, M A; Ponce, L; Rodriguez, E; Flores, T [Centro de Investigacion en Ciencia Aplicada y TecnologIa Avanzada-Unidad Altamira, Tamaulipas (Mexico); Lunney, J G, E-mail: edeposada@ipn.mx [School of Physics, Trinity College Dublin (Ireland)

    2011-01-01

    Optical spectroscopy is used to study the laser ablation process of ZnO targets. It is demonstrated that even if Partial Local Thermal Equilibrium is present, self absorption process leads to a decrease of recorded lines emission intensities and have to be taken into account to obtain correct values of such parameters. It is presented a method that combines results of both Langmuir probe technique and Anisimov model to obtain correct values of plasma parameters.

  12. Characterizing trace metal impurities in optical waveguide materials using x-ray absorption

    Energy Technology Data Exchange (ETDEWEB)

    Citrin, P.H.; Northrup, P.A.; Atkins, R.M.; Niu, L.; Marcus, M.A.; Jacobson, D.C. [Lucent Technologies, Murray Hill, NJ (United States). Bell Labs.; Glodis, P.F. [Lucent Technologies, Norcross, GA (United States). Bell Labs.

    1998-12-31

    X-ray absorption measurements are described for identifying metal impurities in silica preforms, the rod-like starting materials from which hair-like optical fibers are drawn. The results demonstrate the effectiveness of this approach as a non-destructive, quantitative, element-selective, position-sensitive, and chemical-state-specific means for characterizing transition metals in the concentration regime of parts per billion.

  13. Towards quantitative tissue absorption imaging by combining photoacoustics and acousto-optics

    CERN Document Server

    Daoudi, Khalid

    2012-01-01

    We propose a strategy for quantitative photoacoustic mapping of chromophore concentrations that can be performed purely experimentally. We exploit the possibility of acousto-optic modulation using focused ultrasound, and the principle that photons follow trajectories through a turbid medium in two directions with equal probability. A theory is presented that expresses the local absorption coefficient inside a medium in terms of noninvasively measured quantities and experimental parameters. Proof of the validity of the theory is given with Monte Carlo simulations.

  14. Nonlinear optical properties of laser synthesized Pt nanoparticles: saturable and reverse saturable absorption

    Science.gov (United States)

    Chehrghani, A.; Torkamany, M. J.

    2014-01-01

    In this paper, the spectral and nonlinear optical properties of a colloidal solution of platinum nanoparticles (Pt NPs) in water are presented. The Pt NPs were prepared by laser ablation of a Pt metallic target in distilled water using a 1064 nm high frequency Nd:YAG laser. The intensity-dependent nonlinear optical absorption and nonlinear refraction behaviors of the sample exposed to the 532 nm nanosecond laser pulses were investigated by applying the Z-scan technique. The saturated nonlinear absorption coefficient 5.4 × 10-7 cm W-1 was obtained in a saturation intensity of 1.8 × 107 W cm-2. The saturable absorption response of the Pt NPs was switched to the reverse saturable absorption in the higher laser intensities. The nonlinear refractive index that has a negative value was increased from -3.5 × 10-13 cm2 W-1 up to -15 × 10-13 cm2 W-1 by increasing the laser intensity.

  15. Tunable Diode Laser Atomic Absorption Spectroscopy for Detection of Potassium under Optically Thick Conditions.

    Science.gov (United States)

    Qu, Zhechao; Steinvall, Erik; Ghorbani, Ramin; Schmidt, Florian M

    2016-04-05

    Potassium (K) is an important element related to ash and fine-particle formation in biomass combustion processes. In situ measurements of gaseous atomic potassium, K(g), using robust optical absorption techniques can provide valuable insight into the K chemistry. However, for typical parts per billion K(g) concentrations in biomass flames and reactor gases, the product of atomic line strength and absorption path length can give rise to such high absorbance that the sample becomes opaque around the transition line center. We present a tunable diode laser atomic absorption spectroscopy (TDLAAS) methodology that enables accurate, calibration-free species quantification even under optically thick conditions, given that Beer-Lambert's law is valid. Analyte concentration and collisional line shape broadening are simultaneously determined by a least-squares fit of simulated to measured absorption profiles. Method validation measurements of K(g) concentrations in saturated potassium hydroxide vapor in the temperature range 950-1200 K showed excellent agreement with equilibrium calculations, and a dynamic range from 40 pptv cm to 40 ppmv cm. The applicability of the compact TDLAAS sensor is demonstrated by real-time detection of K(g) concentrations close to biomass pellets during atmospheric combustion in a laboratory reactor.

  16. Initial Results of Optical Vortex Laser Absorption Spectroscopy in the HYPER-I Device

    Science.gov (United States)

    Yoshimura, Shinji; Asai, Shoma; Aramaki, Mitsutoshi; Terasaka, Kenichiro; Ozawa, Naoya; Tanaka, Masayoshi; Morisaki, Tomohiro

    2015-11-01

    Optical vortex beams have a potential to make a new Doppler measurement, because not only parallel but perpendicular movement of atoms against the beam axis causes the Doppler shift of their resonant absorption frequency. As the first step of a proof-of-principle experiment, we have performed the optical vortex laser absorption spectroscopy for metastable argon neutrals in an ECR plasma produced in the HYPER-I device at the National Institute for Fusion Science, Japan. An external cavity diode laser (TOPTICA, DL100) of which center wavelength was 696.735 nm in vacuum was used for the light source. The Hermite-Gaussian (HG) beam was converted into the Laguerre-Gaussian (LG) beam (optical vortex) by a computer-generated hologram displayed on the spatial light modulator (Hamamatsu, LCOS-SLM X10468-07). In order to make fast neutral flow across the LG beam, a high speed solenoid valve system was installed on the HYPER-I device. Initial results including the comparison of absorption spectra for HG and LG beams will be presented. This study was supported by NINS young scientists collaboration program for cross-disciplinary study, NIFS collaboration research program (NIFS13KOAP026), and JSPS KAKENHI grant number 15K05365.

  17. Electron Spin Resonance and optical absorption spectroscopic studies of manganese centers in aluminium lead borate glasses

    Science.gov (United States)

    SivaRamaiah, G.; LakshmanaRao, J.

    2012-12-01

    Electron Spin Resonance (ESR) and optical absorption studies of 5Al2O3 + 75H3BO3 + (20-x)PbO + xMnSO4 (where x = 0.5, 1,1.5 and 2 mol% of MnSO4) glasses at room temperature have been studied. The ESR spectrum of all the glasses exhibits resonance signals with effective isotropic g values at ≈2.0, 3.3 and 4.3. The ESR resonance signal at isotropic g ≈ 2.0 has been attributed to Mn2+ centers in an octahedral symmetry. The ESR resonance signals at isotropic g ≈ 3.3 and 4.3 have been attributed to the rhombic symmetry of the Mn2+ ions. The zero-field splitting parameter (zfs) has been calculated from the intensities of the allowed hyperfine lines. The optical absorption spectrum exhibits an intense band in the visible region and it has been attributed to 5Eg → 5T2g transition of Mn3+centers in an octahedral environment. The optical band gap and the Urbach energies have been calculated from the ultraviolet absorption edges.

  18. X-RAY ABSORPTION SPECTROSCOPY OF YB3+-DOPED OPTICAL FIBERS

    Energy Technology Data Exchange (ETDEWEB)

    Citron, Robert; Kropf, A.J.

    2008-01-01

    Optical fibers doped with Ytterbium-3+ have become increasingly common in fiber lasers and amplifiers. Yb-doped fibers provide the capability to produce high power and short pulses at specific wavelengths, resulting in highly effective gain media. However, little is known about the local structure, distribution, and chemical coordination of Yb3+ in the fibers. This information is necessary to improve the manufacturing process and optical qualities of the fibers. Five fibers doped with Yb3+ were studied using Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy and X-ray Absorption Near Edge Spectroscopy (XANES), in addition to Yb3+ mapping. The Yb3+ distribution in each fiber core was mapped with 2D and 1D intensity scans, which measured X-ray fluorescence over the scan areas. Two of the five fibers examined showed highly irregular Yb3+ distributions in the core center. In four of the five fibers Yb3+ was detected outside of the given fiber core dimensions, suggesting possible Yb3+ diffusion from the core, manufacturing error, or both. X-ray absorption spectroscopy (XAS) analysis has so far proven inconclusive, but did show that the fibers had differing EXAFS spectra. The Yb3+ distribution mapping proved highly useful, but additional modeling and examination of fiber preforms must be conducted to improve XAS analysis, which has been shown to have great potential for the study of similar optical fi bers.

  19. Dielectric core-shell optical antennas for strong solar absorption enhancement.

    Science.gov (United States)

    Yu, Yiling; Ferry, Vivian E; Alivisatos, A Paul; Cao, Linyou

    2012-07-11

    We demonstrate a new light trapping technique that exploits dielectric core-shell optical antennas to strongly enhance solar absorption. This approach can allow the thickness of active materials in solar cells lowered by almost 1 order of magnitude without scarifying solar absorption capability. For example, it can enable a 70 nm thick hydrogenated amorphous silicon (a-Si:H) thin film to absorb 90% of incident solar radiation above the bandgap, which would otherwise require a thickness of 400 nm in typical antireflective coated thin films. This strong enhancement arises from a controlled optical antenna effect in patterned core-shell nanostructures that consist of absorbing semiconductors and nonabsorbing dielectric materials. This core-shell optical antenna benefits from a multiplication of enhancements contributed by leaky mode resonances (LMRs) in the semiconductor part and antireflection effects in the dielectric part. We investigate the fundamental mechanism for this enhancement multiplication and demonstrate that the size ratio of the semiconductor and the dielectric parts in the core-shell structure is key for optimizing the enhancement. By enabling strong solar absorption enhancement, this approach holds promise for cost reduction and efficiency improvement of solar conversion devices, including solar cells and solar-to-fuel systems. It can generally apply to a wide range of inorganic and organic active materials. This dielectric core-shell antenna can also find applications in other photonic devices such as photodetectors, sensors, and solid-state lighting diodes.

  20. Doubling absorption in nanowire solar cells with dielectric shell optical antennas.

    Science.gov (United States)

    Kim, Sun-Kyung; Zhang, Xing; Hill, David J; Song, Kyung-Deok; Park, Jin-Sung; Park, Hong-Gyu; Cahoon, James F

    2015-01-14

    Semiconductor nanowires (NWs) often exhibit efficient, broadband light absorption despite their relatively small size. This characteristic originates from the subwavelength dimensions and high refractive indices of the NWs, which cause a light-trapping optical antenna effect. As a result, NWs could enable high-efficiency but low-cost solar cells using small volumes of expensive semiconductor material. Nevertheless, the extent to which the antenna effect can be leveraged in devices will largely determine the economic viability of NW-based solar cells. Here, we demonstrate a simple, low-cost, and scalable route to dramatically enhance the optical antenna effect in NW photovoltaic devices by coating the wires with conformal dielectric shells. Scattering and absorption measurements on Si NWs coated with shells of SiN(x) or SiO(x) exhibit a broadband enhancement of light absorption by ∼ 50-200% and light scattering by ∼ 200-1000%. The increased light-matter interaction leads to a ∼ 80% increase in short-circuit current density in Si photovoltaic devices under 1 sun illumination. Optical simulations reproduce the experimental results and indicate the dielectric-shell effect to be a general phenomenon for groups IV, II-VI, and III-V semiconductor NWs in both lateral and vertical orientations, providing a simple route to approximately double the efficiency of NW-based solar cells.

  1. Three-dimensional printed optical phantoms with customized absorption and scattering properties.

    Science.gov (United States)

    Diep, Phuong; Pannem, Sanjana; Sweer, Jordan; Lo, Justine; Snyder, Michael; Stueber, Gabriella; Zhao, Yanyu; Tabassum, Syeda; Istfan, Raeef; Wu, Junjie; Erramilli, Shyamsunder; Roblyer, Darren

    2015-11-01

    Three-dimensional (3D) printing offers the promise of fabricating optical phantoms with arbitrary geometry, but commercially available thermoplastics provide only a small range of physiologically relevant absorption (µa) and reduced scattering (µs`) values. Here we demonstrate customizable acrylonitrile butadiene styrene (ABS) filaments for dual extrusion 3D printing of tissue mimicking optical phantoms. µa and µs` values were adjusted by incorporating nigrosin and titanium dioxide (TiO2) in the filament extrusion process. A wide range of physiologically relevant optical properties was demonstrated with an average repeatability within 11.5% for µa and 7.71% for µs`. Additionally, a mouse-simulating phantom, which mimicked both the geometry and optical properties of a hairless mouse with an implanted xenograft tumor, was printed using dual extrusion methods. 3D printed tumor optical properties matched the live tumor with less than 3% error at a wavelength of 659 nm. 3D printing with user defined optical properties may provide a viable method for durable optically diffusive phantoms for instrument characterization and calibration.

  2. Block matching 3D random noise filtering for absorption optical projection tomography

    Energy Technology Data Exchange (ETDEWEB)

    Fumene Feruglio, P; Vinegoni, C; Weissleder, R [Center for Systems Biology, Massachusetts General Hospital, Harvard Medical School, 185 Cambridge Street, Boston, MA 02114 (United States); Gros, J [Department of Genetics, Harvard Medical School, 77 Avenue Louis Pasteur, Boston MA 02115 (United States); Sbarbati, A, E-mail: cvinegoni@mgh.harvard.ed [Department of Morphological and Biomedical Sciences, University of Verona, Strada Le Grazie 8, 37134 Verona (Italy)

    2010-09-21

    Absorption and emission optical projection tomography (OPT), alternatively referred to as optical computed tomography (optical-CT) and optical-emission computed tomography (optical-ECT), are recently developed three-dimensional imaging techniques with value for developmental biology and ex vivo gene expression studies. The techniques' principles are similar to the ones used for x-ray computed tomography and are based on the approximation of negligible light scattering in optically cleared samples. The optical clearing is achieved by a chemical procedure which aims at substituting the cellular fluids within the sample with a cell membranes' index matching solution. Once cleared the sample presents very low scattering and is then illuminated with a light collimated beam whose intensity is captured in transillumination mode by a CCD camera. Different projection images of the sample are subsequently obtained over a 360{sup 0} full rotation, and a standard backprojection algorithm can be used in a similar fashion as for x-ray tomography in order to obtain absorption maps. Because not all biological samples present significant absorption contrast, it is not always possible to obtain projections with a good signal-to-noise ratio, a condition necessary to achieve high-quality tomographic reconstructions. Such is the case for example, for early stage's embryos. In this work we demonstrate how, through the use of a random noise removal algorithm, the image quality of the reconstructions can be considerably improved even when the noise is strongly present in the acquired projections. Specifically, we implemented a block matching 3D (BM3D) filter applying it separately on each acquired transillumination projection before performing a complete three-dimensional tomographical reconstruction. To test the efficiency of the adopted filtering scheme, a phantom and a real biological sample were processed. In both cases, the BM3D filter led to a signal-to-noise ratio

  3. Optical hydrogen absorption consistent with a thin bow shock leading the hot Jupiter HD 189733b

    CERN Document Server

    Cauley, P Wilson; Jensen, Adam G; Barman, Travis; Endl, Michael; Cochran, William D

    2015-01-01

    Bow shocks are ubiquitous astrophysical phenomena resulting from the supersonic passage of an object through a gas. Recently, pre-transit absorption in UV metal transitions of the hot Jupiter exoplanets HD 189733b and WASP12-b have been interpreted as being caused by material compressed in a planetary bow shock. Here we present a robust detection of a time-resolved pre-transit, as well as in-transit, absorption signature around the hot Jupiter exoplanet HD 189733b using high spectral resolution observations of several hydrogen Balmer lines. The line shape of the pre-transit feature and the shape of the time series absorption provide the strongest constraints on the morphology and physical characteristics of extended structures around an exoplanet. The in-transit measurements confirm the previous exospheric H-alpha detection although the absorption depth measured here is ~50% lower. The pre-transit absorption feature occurs 125 minutes before the predicted optical transit, a projected linear distance from the ...

  4. Gas detection techniques with fiber optical spectrum absorption at near-IR wavelength

    Science.gov (United States)

    Liu, Tiegen; Liu, Kun; Jiang, Junfeng; Peng, Gangding; Wang, Yan; Jia, Dagong; Zhang, Hongxia; Jing, Wencai; Zhang, Yimo

    2010-04-01

    Detection of pollution gas is important in environmental and pollution monitoring, which can be used widely in mining and petrochemical industry. Fiber optical spectrum absorption (FOSA) at near-IR wavelength is widely used in gas detection due to its essential advantages. It has attracted considerable attention, and there are several types and methods in FOSA. Wavelength modulation technique (WMT) is one of them, which will improve the gas detection sensitivity dramatically. This technique can be realized by detecting the intensity of the second-harmonic component signal. Intra-cavity laser spectroscopy (ICLS) is another alternative technique for high sensitivity absorption measurement. With an absorber directly placed within the laser cavity, a short absorption cell can be transformed into a high sensitivity system. But the practical sensitivity is obviously less than the theoretical value. The authors did some works in these fields and have obtained some remarkable progress. With broad reflectors instead of FBG as mirror of the cavity and wavelength sweep technique (WST), several absorption spectra of detected gas can be collected. And the detection sensitivity can be enhanced sharply by averaging the results of each spectrum, with acetylene sensitivity less than 100 ppm . When ICLS is used combined with WST and WMT, the detection sensitivity of acetylene can be enhanced further. The sensitivity is less than 75 ppm. By using FBGs as wavelength references, the absorption wavelength of the detected gas is obtained, which can be used to realize gas recognition. The system is capable of accessing into fiber intelligent sensing network.

  5. Calibration-free absolute quantification of optical absorption coefficients using acoustic spectra in 3D photoacoustic microscopy of biological tissue.

    Science.gov (United States)

    Guo, Zijian; Hu, Song; Wang, Lihong V

    2010-06-15

    Optical absorption is closely associated with many physiological important parameters, such as the concentration and oxygen saturation of hemoglobin, and it can be used to quantify the concentrations of nonfluorescent molecules. We propose a method to use acoustic spectra of photoacoustic signals to quantify the absolute optical absorption. This method is self-calibrating and thus insensitive to variations in the optical fluence. Factors such as system bandwidth and acoustic attenuation can affect the quantification but can be canceled by dividing the acoustic spectra measured at two optical wavelengths. Using optical-resolution photoacoustic microscopy, we quantified the absolute optical absorption of black ink samples with various concentrations. We also quantified both the concentration and oxygen saturation of hemoglobin in a live mouse in absolute units.

  6. Optical sensor instrumentation using absorption- and fluorescence-based capillary waveguide optrodes

    Science.gov (United States)

    Weigl, Bernhard H.; Draxler, Sonja; Kieslinger, Dietmar; Lehmann, H.; Trettnak, Wolfgang; Wolfbeis, Otto S.; Lippitsch, Max E.

    1995-09-01

    An analytical instrument comprising absorption- and fluorescence-based capillary waveguide optrodes (CWOs) is described. Glass capillaries with a chemically sensitive coating on the inner surface are used for optical chemical sensing in gaseous and liquid samples. In case of absorption-based CWOs, light from a LED is coupled into and out of the capillary under a defined angle via a rigid waveguide and an immersion coupler. The coated glass capillary forms an inhomogeneous waveguide, in which the light is guided in both the glass and the coating. The portion of the light which is absorbed in the chemically sensitive coating is proportional to a chemcial concentration or activity. This principle is demonstrated with a pCO2-sensitive inner coating. Typical relative light intensity signal changes with this type of optical interrogation are 98%, with an active capillary length of 10 mm. For fluorescence- based CWOs, the excitation light from an LED is coupled diffusely into the glass capillary and the optical sensor layer. A major portion of the excited fluorescence light is then collected within the coated capillary, and guided to the photodiode, which is located on the distal end of the capillary waveguide. Hereby, the excitation light is separated very efficiently from the fluorescent light. As an example, a CWO for pO2 is described. By applying this optical geometry, it was possible to utilize fluorescence decay time of the sensor layer as the transducer signal even when using solid state components (LEDs and photodiodes).

  7. Far-field optical imaging with subdiffraction resolution enabled by nonlinear saturation absorption

    Science.gov (United States)

    Ding, Chenliang; Wei, Jingsong

    2016-01-01

    The resolution of far-field optical imaging is required to improve beyond the Abbe limit to the subdiffraction or even the nanoscale. In this work, inspired by scanning electronic microscopy (SEM) imaging, in which carbon (or Au) thin films are usually required to be coated on the sample surface before imaging to remove the charging effect while imaging by electrons. We propose a saturation-absorption-induced far-field super-resolution optical imaging method (SAI-SRIM). In the SAI-SRIM, the carbon (or Au) layers in SEM imaging are replaced by nonlinear-saturation-absorption (NSA) thin films, which are directly coated onto the sample surfaces using advanced thin film deposition techniques. The surface fluctuant morphologies are replicated to the NSA thin films, accordingly. The coated sample surfaces are then imaged using conventional laser scanning microscopy. Consequently, the imaging resolution is greatly improved, and subdiffraction-resolved optical images are obtained theoretically and experimentally. The SAI-SRIM provides an effective and easy way to achieve far-field super-resolution optical imaging for sample surfaces with geometric fluctuant morphology characteristics.

  8. Coherent absorption of light by graphene and other optically conducting surfaces in realistic on-substrate configurations

    Directory of Open Access Journals (Sweden)

    S. Zanotto

    2017-01-01

    Full Text Available Analytical formulas are derived describing the coherent absorption of light from a realistic multilayer structure composed by an optically conducting surface on a supporting substrate. The model predicts two fundamental results. First, the absorption regime named coherent perfect transparency theoretically can always be reached. Second, the optical conductance of the surface can be extrapolated from absorption experimental data even when the substrate thickness is unknown. The theoretical predictions are experimentally verified by analyzing a multilayer graphene structure grown on a silicon carbide substrate. The graphene thickness estimated through the coherent absorption technique resulted in good agreement with the values obtained by two other spectroscopic techniques. Thanks to the high spatial resolution that can be reached and high sensitivity to the probed structure thickness, coherent absorption spectroscopy represents an accurate and non-destructive diagnostic method for the spatial mapping of the optical properties of two-dimensional materials and of metasurfaces on a wafer scale.

  9. Modified optical absorption of molecules on metallic nanoparticles at sub-monolayer coverage

    CERN Document Server

    Darby, Brendan L; Meyer, Matthias; Pantoja, Andres E; Ru, Eric C Le

    2015-01-01

    Enhanced optical absorption of molecules in the vicinity of metallic nanostructures is key to a number of surface-enhanced spectroscopies and of great general interest to the fields of plasmonics and nano-optics. Yet, experimental access to this absorbance has long proven elusive. We here present direct measurements of the intrinsic absorbance of dye-molecules adsorbed onto silver nanospheres, and crucially, at sub-monolayer concentrations where dye--dye interactions become negligible. With a large detuning from the plasmon resonance, distinct shifts and broadening of the molecular resonances reveal the intrinsic properties of the dye in contact with the metal colloid, in contrast to the often studied strong-coupling regime where the optical properties of the dye-molecules cannot be isolated. The observation of these shifts together with the ability to routinely measure them has broad implications in the interpretation of experiments involving resonant molecules on metallic surfaces, such as surface-enhanced ...

  10. Linear and Nonlinear Optical Absorptions of a Hydrogenic Donor in a Quantum Dot Under a Magnetic Field

    Institute of Scientific and Technical Information of China (English)

    XIE Wen-Fang

    2009-01-01

    The linear and nonlinear optical properties of a hydrogenic donor in a disc-like parabolic quantum dot in the presence of an external magnetic field are studied. The calculations were performed within the effective mass approximation, using the matrix diagonalization method and the compact density-matrix approach. The linear and nonlinear optical absorption coefficients between the ground (L = 0) and the first excited state (L = 1) have been examined based on the computed energies and wave functions. We find that the linear, nonlinear third-order, and total optical absorption coefficients are strongly affected by the confinement strength of QDs, the external magnetic field, and the incident optical intensity.

  11. The effect of metal nano particle on optical absorption coefficient of multi-layer spherical quantum dot

    Energy Technology Data Exchange (ETDEWEB)

    Zamani, N., E-mail: n.zamani@sutech.ac.ir [Department of Physics, College of Science, Shiraz University, Shiraz 71454 (Iran, Islamic Republic of); Keshavarz, A., E-mail: keshavarz@sutech.ac.ir [Department of Physics, Shiraz University of Technology, Shiraz 71555-313 (Iran, Islamic Republic of); Nadgaran, H., E-mail: nadgaran@susc.ac.ir [Department of Physics, College of Science, Shiraz University, Shiraz 71454 (Iran, Islamic Republic of)

    2016-06-01

    In this paper, we investigate the optical absorption coefficient of hybrid structure consisting of metal nano particle (MNP) coupled to multi-layer spherical quantum dot (MSQD). Energy eigenvalues and eigenfunctions of Schrödinger equation in this structure are obtained by using numerical solution (by the fourth-order Runge–Kutta method). The effect of MNP in the vicinity of MSQD is calculated by considering local field theory. Then the variation of optical absorption coefficient hybrid structure is calculated. The results show that the presence of MNP near MSQD enhances the optical absorption coefficient. Also, by changing the distance between MNP and MSQD and radius of MNP, variation of optical absorption coefficient and refractive index changes are introduced.

  12. The effect of metal nano particle on optical absorption coefficient of multi-layer spherical quantum dot

    Science.gov (United States)

    Zamani, N.; Keshavarz, A.; Nadgaran, H.

    2016-06-01

    In this paper, we investigate the optical absorption coefficient of hybrid structure consisting of metal nano particle (MNP) coupled to multi-layer spherical quantum dot (MSQD). Energy eigenvalues and eigenfunctions of Schrödinger equation in this structure are obtained by using numerical solution (by the fourth-order Runge-Kutta method). The effect of MNP in the vicinity of MSQD is calculated by considering local field theory. Then the variation of optical absorption coefficient hybrid structure is calculated. The results show that the presence of MNP near MSQD enhances the optical absorption coefficient. Also, by changing the distance between MNP and MSQD and radius of MNP, variation of optical absorption coefficient and refractive index changes are introduced.

  13. Band gap shift and the optical nonlinear absorption of sputtered ZnO-TiO2 films.

    Science.gov (United States)

    Han, Yi-Bo; Han, Jun-Bo; Hao, Zhong-Hua

    2011-06-01

    ZnO-TiO2 composite films with different Zn/Ti atomic ratios were prepared with radio frequency reactive sputtering method. The Zn percentage composition (f(Zn)) dependent optical band gap and optical nonlinear absorption were investigated using the transmittance spectrum and the Z-scan technique, respectively. The results showed that composite films with f(Zn) in the range of 23.5%-88.3% are poor crystallized and their optical properties are anomalous which exhibit adjustable optical band gap and large optical nonlinear absorption. The optical absorption edge shifted to the blue wavelength direction with the increasing of f(Zn) and reached the minimum value of 285 nm for the sample with f(Zn) = 70.5%, which has the largest direct band gap of 4.30 eV. Further increasing of f(Zn) resulted in the red-shift of the optical absorption edge. The maximum optical nonlinear absorption coefficient of 1.5 x 10(3) cm/GW was also obtained for the same sample with f(Zn) = 70.5%, which is more than 40 times larger than those of pure TiO2 and ZnO films.

  14. The Application of Atomic Absorption Spectroscopy and Optical Microscopy to the Characterization of Sized Airborne Particulate in Dayton, Ohio.

    Science.gov (United States)

    1978-01-01

    PERIOD COVERED " AneT Appication of Atomic Absorption Spectroscopy ’ and Optical Microscopy to the Characterization of THESIS/DISSERTATION 4 Sized...1978 U I HEREBY REC04MEND THAT THE THESIS PREPARED ’NDER MY SUPERVISION BY Lorelei Ann Krebs ENTITLED The Application of Atomic Absorption Spectroscopy and...acid and diluted with distilled water in a 25 milliliter volumetric flask. Atomic absorption . spectroscopy was used to analyze the solutions for

  15. Infrared Fel Measurements of Power Limiting by 2-Photon Absorption in Insb and Optical Pulse Length Measurements

    NARCIS (Netherlands)

    Jaroszynski, D. A.; Ortega, J. M.; Prazeres, R.; Glotin, F.; Murdin, B. N.; Merveille, C.; Kar, A. K.; Kimmitt, M. F.; Pidgeon, C. R.

    1993-01-01

    We have performed the first optical experiment using the laser output of the CLIO free electron laser. In a transmission experiment we have observed strong power limiting at wavelengths longer than the absorption edge at 7.5 mum associated with induced free carrier absorption produced by direct inte

  16. VO 2+ ions in zinc lead borate glasses studied by EPR and optical absorption techniques

    Science.gov (United States)

    Prakash, P. Giri; Rao, J. Lakshmana

    2005-09-01

    Electron paramagnetic resonance (EPR) and optical absorption spectra of vanadyl ions in zinc lead borate (ZnO-PbO-B 2O 3) glass system have been studied. EPR spectra of all the glass samples exhibit resonance signals characteristic of VO 2+ ions. The values of spin-Hamiltonian parameters indicate that the VO 2+ ions in zinc lead borate glasses were present in octahedral sites with tetragonal compression and belong to C 4V symmetry. The spin-Hamiltonian parameters g and A are found to be independent of V 2O 5 content and temperature but changing with ZnO content. The decrease in Δ g∥/Δ g⊥ value with increase in ZnO content indicates that the symmetry around VO 2+ ions is more octahedral. The decrease in intensity of EPR signal above 10 mol% of V 2O 5 is attributed to a fall in the ratio of the number of V 4+ ions ( N4) to the number of V 5+ ions ( N5). The number of spins ( N) participating in resonance was calculated as a function of temperature for VO 2+ doped zinc lead borate glass sample and the activation energy was calculated. From the EPR data, the paramagnetic susceptibility was calculated at various temperatures and the Curie constant was evaluated from the 1/ χ- T graph. The optical absorption spectra show single absorption band due to VO 2+ ions in tetragonally distorted octahedral sites.

  17. Sedimentation field flow fractionation and optical absorption spectroscopy for a quantitative size characterization of silver nanoparticles.

    Science.gov (United States)

    Contado, Catia; Argazzi, Roberto; Amendola, Vincenzo

    2016-11-04

    Many advanced industrial and biomedical applications that use silver nanoparticles (AgNPs), require that particles are not only nano-sized, but also well dispersed, not aggregated and not agglomerated. This study presents two methods able to give rapidly sizes of monodispersed AgNPs suspensions in the dimensional range of 20-100nm. The first method, based on the application of Mie's theory, determines the particle sizes from the values of the surface plasmon resonance wavelength (SPRMAX), read from the optical absorption spectra, recorded between 190nm and 800nm. The computed sizes were compared with those determined by transmission electron microscopy (TEM) and dynamic light scattering (DLS) and resulted in agreement with the nominal values in a range between 13% (for 20nm NPs) and 1% (for 100nm NPs), The second method is based on the masterly combination of the Sedimentation Field Flow Fractionation (SdFFF - now sold as Centrifugal FFF-CFFF) and the Optical Absorption Spectroscopy (OAS) techniques to accomplish sizes and quantitative particle size distributions for monodispersed, non-aggregated AgNPs suspensions. The SdFFF separation abilities, well exploited to size NPs, greatly benefits from the application of Mie's theory to the UV-vis signal elaboration, producing quantitative mass-based particle size distributions, from which trusted number-sized particle size distributions can be derived. The silver mass distributions were verified and supported by detecting off-line the Ag concentration with the graphite furnace atomic absorption spectrometry (GF-AAS).

  18. Semiperiodicity versus periodicity for ultra broadband optical absorption in thin-film solar cells

    Science.gov (United States)

    Jalali, Mandana; Nadgaran, Hamid; Erni, Daniel

    2016-07-01

    We propose the use of one-dimensional semiperiodic front and back gratings based on Thue-Morse, Fibonacci, and Rudin-Shapiro (RS) binary sequences as promising photon management techniques for enhancing ultra-broadband optical absorption in thin-film solar cells. The semiperiodicity allows an aggregate light in-coupling into the active layer within the range of the solar spectrum that is less weak compared to an inherently broadband random grating, but has a much larger bandwidth than the strong in-coupling via a periodic grating configuration. The proper design procedure proposed here deviates from a canonical double grating synthesis as it adheres to an ultra-broadband design where the spectrally integrated absorption in the active material is the proper subject to optimization, leaving the grating perturbations just a measure to perturb and mold the trapped light field in the active layer accordingly. It is shown that by using a well-defined RS double grating in a 400-nm thick crystalline silicon solar cell, a 110.2% enhancement of the spectrally integrated optical absorption can be achieved relative to the reference case without grating.

  19. Optical torque on a magneto-dielectric Rayleigh absorptive sphere by a vector Bessel (vortex) beam

    Science.gov (United States)

    Li, Renxian; Yang, Ruiping; Ding, Chunying; Mitri, F. G.

    2017-04-01

    The optical torque exerted on an absorptive megneto-dielectric sphere by an axicon-generated vector Bessel (vortex) beam with selected polarizations is investigated in the framework of the dipole approximation. The total optical torque is expressed as the sum of orbital and spin torques. The axial orbital torque component is calculated from the z-component of the cross-product of the vector position r and the optical force exerted on the sphere F. Depending on the beam characteristics (such as the half-cone angle and polarization type) and the physical properties of the sphere, it is shown here that the axial orbital torque vanishes before reversing sign, indicating a counter-intuitive orbital motion in opposite handedness of the angular momentum carried by the incident waves. Moreover, analytical formulas for the spin torque, which is divided into spin torques induced by electric and magnetic dipoles, are derived. The corresponding components of both the optical spin and orbital torques are numerically calculated, and the effects of polarization, the order of the beam, and half-cone angle are discussed in detail. The left-handed (i.e., negative) optical torque is discussed, and the conditions for generating optical spin and orbital torque sign reversal are numerically investigated. The transverse optical spin torque has a vortex-like character, whose direction depends on the polarization, the half-cone angle, and the order of the beam. Numerical results also show that the vortex direction depends on the radial position of the particle in the transverse plane. This means that a sphere may rotate with different directions when it moves radially. Potential applications are in particle manipulation and rotation, single beam optical tweezers, and other emergent technologies using vector Bessel beams on a small magneto-dielectric (nano) particle.

  20. The analysis of time-resolved optical waveguide absorption spectroscopy based on positive matrix factorization.

    Science.gov (United States)

    Liu, Ping; Li, Zhu; Li, Bo; Shi, Guolong; Li, Minqiang; Yu, Daoyang; Liu, Jinhuai

    2013-08-01

    Time-resolved optical waveguide absorption spectroscopy (OWAS) makes use of an evanescent field to detect the polarized absorption spectra of sub-monomolecular adlayers. This technique is suitable for the investigation of kinetics at the solid/liquid interface of dyes, pigments, fluorescent molecules, quantum dots, metallic nanoparticles, and proteins with chromophores. In this work, we demonstrate the application of positive matrix factorization (PMF) to analyze time-resolved OWAS for the first time. Meanwhile, PCA is researched to compare with PMF. The absorption/desorption kinetics of Rhodamine 6G (R6G) onto a hydrophilic glass surface and the dynamic process of Meisenheimer complex between Cysteine and TNT are selected as samples to verify experimental system and analytical methods. The results are shown that time-resolved OWAS can well record the absorption/desorption of R6G onto a hydrophilic glass surface and the dynamic formation process of Meisenheimer complexes. The feature of OWAS extracted by PMF is dynamic and consistent with the results analyzed by the traditional function of time/wavelength-absorbance. Moreover, PMF prevents the negative factors from occurring, avoids contradicting physical reality, and makes factors more easily interpretable. Therefore, we believe that PMF will provide a valuable analysis route to allow processing of increasingly large and complex data sets.

  1. Nonlinear absorption and optical limiting in Duran glass induced by 800 nm femtosecond laser pulses

    Energy Technology Data Exchange (ETDEWEB)

    Jamshidi-Ghaleh, Kazem [Department of Physics, Azerbaijan University of Tarbiat Moallem, Tabriz (Iran, Islamic Republic of); Mansour, Nastaran [Department of Physics, Shahi Beheshti University, Tehran (Iran, Islamic Republic of)

    2007-01-21

    Nonlinear absorption of Duran glass by irradiation of a focused 200 fs pulsed laser were investigated using the z-scan technique at 800 nm. Optical limiting behaviour in this glass has also been measured. The limiting threshold was measured to 33 {mu}J pulse energy (peak intensity of 2.4 x 10{sup 12} W cm{sup -2}) in this sample. The decrease in transmitted intensity is around 75% compared with the theoretical linear transmission for incident pulses pulse energies 320 {mu}J (peak intensity of 5 x 10{sup 12} W cm{sup -2}). A comparison of the theoretical analyses with the experimental results shows that three-photon absorption and three-photon generated free-carrier absorption within the glasses are the main mechanisms for the observed nonlinear response. The values of the three-photon absorption coefficient and the photo-generated free-carrier cross section are measured as {gamma} = 2 x 10{sup -24}cm{sup 3} W{sup -2} and {sigma} = 1.2 x 10{sup -18} cm{sup 2}, respectively.

  2. ANISOTROPY OF OPTICAL ABSORPTION INTENSITY IN Tm3+ DOPED YVO4 CRYSTALS

    Institute of Scientific and Technical Information of China (English)

    LIN XIU-HUA; JIANG BING-XI

    2000-01-01

    Seven absorption group-bands (1D2, 1G4, 3F2, 3F3, 3H4, 3H5, 3F4) of Tm3+ in YVO4 single crystals have been observed in the orientation absorption spectra recorded in the spectral range from 200 to 4000 nm at 300K.The integrated absorption cross section for each group-band was accurately evaluated. On the assumption that the anisotropy of this uni-axial crystal is small, the Judd-Ofelt theory was extended for the calculation of 4f-4f transition intensities of Tm3+ in YVO4. Two sets of phenomenological intensity parameters were derived from a least-squares-fit procedure. For c-axis cut sample we have Ω2=10.18 (10-20cm2), Ω4=1.96 (10-20cm2), Ω6=0.75 (10-20cm2). For a-axis cut sample we have Ω2 = 8.20 (10-20cm2), Ω4 = 2.47 (10-20cm2), Ω6 = 0.91 (10-20cm2). The anisotropy of the optical absorption intensities of Tm3+:YVO4 was theoretically analyzed in detail.

  3. Dependence of Brillouin frequency shift on water absorption ratio in polymer optical fibers

    Science.gov (United States)

    Minakawa, Kazunari; Koike, Kotaro; Hayashi, Neisei; Koike, Yasuhiro; Mizuno, Yosuke; Nakamura, Kentaro

    2016-06-01

    We studied the dependence of the Brillouin frequency shift (BFS) on the water-absorption ratio in poly(methyl methacrylate)-based polymer optical fibers (POFs) to clarify the effect of the humidity on POF-based Brillouin sensors. The BFS, deduced indirectly using an ultrasonic pulse-echo technique, decreased monotonically as the water absorption ratio increased, mainly because of the decrease in the Young's modulus. For the same water absorption ratio, the BFS change was larger at a higher temperature. The maximal BFS changes (absolute values) at 40, 60, and 80 °C were 158, 285, and 510 MHz, respectively (corresponding to the temperature changes of ˜9 °C, ˜16 °C, and ˜30 °C). Thus, some countermeasure against the humidity is indispensable in implementing strain/temperature sensors based on Brillouin scattering in POFs, especially at a higher temperature. On the other hand, Brillouin-based distributed humidity sensors might be developed by exploiting the BFS dependence on water absorption in POFs.

  4. In vivo photothermal optical coherence tomography for non-invasive imaging of endogenous absorption agents.

    Science.gov (United States)

    Makita, Shuichi; Yasuno, Yoshiaki

    2015-05-01

    In vivo photothermal optical coherence tomography (OCT) is demonstrated for cross-sectional imaging of endogenous absorption agents. In order to compromise the sensitivity, imaging speed, and sample motion immunity, a new photothermal detection scheme and phase processing method are developed. Phase-resolved swept-source OCT and fiber-pigtailed laser diode (providing excitation at 406 nm) are combined to construct a high-sensitivity photothermal OCT system. OCT probe and excitation beam coaxially illuminate and are focused on tissues. The photothermal excitation and detection procedure is designed to obtain high efficiency of photothermal effect measurement. The principle and method of depth-resolved cross-sectional imaging of absorption agents with photothermal OCT has been derived. The phase-resolved thermal expansion detection algorithm without motion artifact enables in vivo detection of photothermal effect. Phantom imaging with a blood phantom and in vivo human skin imaging are conducted. A phantom with guinea-pig blood as absorber has been scanned by the photothermal OCT system to prove the concept of cross-sectional absorption agent imaging. An in vivo human skin measurement is also performed with endogenous absorption agents.

  5. Nonlinear absorption and optical damage threshold of carbon-based nanostructured material embedded in a protein

    Science.gov (United States)

    Janulewicz, K. A.; Hapiddin, A.; Joseph, D.; Geckeler, K. E.; Sung, J. H.; Nickles, P. V.

    2014-12-01

    Physical processes in laser-matter interaction used to be determined by generation of fast electrons resulting from efficient conversion of the absorbed laser radiation. Composite materials offer the possibility to control the absorption by choice of the host material and dopants. Reported here strong absorption of ultrashort laser pulse in a composite carbon-based nanomaterial including single-walled carbon nanotubes (SWCNTs) or multilayer graphene was measured in the intensity range between 1012 and 1016 W cm-2. A protein (lysozyme) was used as the host. The maximum absorption of femtosecond laser pulse has reached 92-96 %. The optical damage thresholds of the coatings were registered at an intensity of (1.1 ± 0.5) × 1013 W cm-2 for the embedded SWCNTs and at (3.4 ± 0.3) × 1013 W cm-2 for the embedded graphene. Encapsulated variant of the dispersed nanomaterial was investigated as well. It was found that supernatant protein in the coating material tends to dominate the absorption process, independently of the embedded nanomaterial. The opposite was observed for the encapsulated material.

  6. Linear and nonlinear optical absorption characterization of natural laccaic acid dye

    Science.gov (United States)

    Zongo, S.; Dhlamini, M. S.; Kerasidou, A. P.; Beukes, P.; Sahraoui, B.; Maaza, M.

    2015-09-01

    We report on the optical performances of laccaic acid dye in solution at different concentrations and dye-poly(methyl methacrylate) composite thin films. The linear spectral characteristics including optical constants, i.e. refractive index ( n) and extinction coefficient ( k), were carried out in a comprehensive way through absorbance, fluorescence and ellipsometric studies. The nonlinear optical parameters such as nonlinear absorption coefficient β eff (or β 2), the imaginary third-order susceptibility (Im[ χ (3)]) and the imaginary part of second-order hyperpolarizability ( γ) of the samples were evaluated using the open-aperture Z-scan technique with a laser pulse duration of 10 ns at 532 nm wavelength. The corresponding numerical values of these parameters were of 10-10, 10-11 and 10-32 order, respectively. Two-photon absorption was revealed to be the main driving physical mechanism in the nonlinear response. This suggests that laccaic acid dye can be a potential candidate for NLO materials application.

  7. Spectral interferometric microscopy reveals absorption by individual optical nanoantennas from extinction phase.

    Science.gov (United States)

    Gennaro, Sylvain D; Sonnefraud, Yannick; Verellen, Niels; Van Dorpe, Pol; Moshchalkov, Victor V; Maier, Stefan A; Oulton, Rupert F

    2014-04-30

    Optical antennas transform light from freely propagating waves into highly localized excitations that interact strongly with matter. Unlike their radio frequency counterparts, optical antennas are nanoscopic and high frequency, making amplitude and phase measurements challenging and leaving some information hidden. Here we report a novel spectral interferometric microscopy technique to expose the amplitude and phase response of individual optical antennas across an octave of the visible to near-infrared spectrum. Although it is a far-field technique, we show that knowledge of the extinction phase allows quantitative estimation of nanoantenna absorption, which is a near-field quantity. To verify our method we characterize gold ring-disk dimers exhibiting Fano interference. Our results reveal that Fano interference only cancels a bright mode's scattering, leaving residual extinction dominated by absorption. Spectral interference microscopy has the potential for real-time and single-shot phase and amplitude investigations of isolated quantum and classical antennas with applications across the physical and life sciences.

  8. Optical absorption in transparent PDMS materials applied for multimode waveguides fabrication

    Science.gov (United States)

    Cai, D. K.; Neyer, A.; Kuckuk, R.; Heise, H. M.

    2008-03-01

    The optical properties of transparent PDMS polymer materials, which can be integrated into general printed circuit board (PCB) for data communication, are of great interest due to the substantial market expectations for the near future. For the present paper, it was found that the absorption loss in polydimethylsiloxane (PDMS) is mainly caused by the vibrational overtone and combination bands of the CH 3-groups of the polymer in the spectral datacom region of 600-900 nm. Based on observed positions of fundamental, overtone and combination bands of the methyl-group, as recorded within the mid- and near-infrared spectra, anharmonicity constants and normal vibration frequencies were determined. Thus, an empirical equation for estimating the wavelengths with the most significant intrinsic absorption loss due to the corresponding band positions was formulated, which was found to agree well with the experimental data. In addition, PDMS multimode waveguides were fabricated and the respective optical insertion loss was measured at 850 nm, which is commercially used for optical datacom transmission and finally the thermal stability of PDMS multimode waveguides was verified as well.

  9. Effect of radiation-induced color centers absorption in optical fibers on fiber optic gyroscope for space application

    Science.gov (United States)

    Jin, Jing; Li, Ya; Zhang, Zu-Chen; Wu, Chun-Xiao; Song, Ning-Fang

    2016-08-01

    The effects of color centers’ absorption on fibers and interferometric fiber optical gyroscopes (IFOGs) are studied in the paper. The irradiation induced attenuation (RIA) spectra of three types of polarization-maintaining fibers (PMFs), i.e., P-doped, Ge-doped, and pure silica, irradiated at 100 Gy and 1000 Gy are measured in a wavelength range from 1100 nm to 1600 nm and decomposed according to the Gaussian model. The relationship of the color centers absorption intensity with radiation dose is investigated based on a power model. Furthermore, the effects of all color centers’ absorption on RIA and mean wavelength shifts (MWS) at 1300 nm and 1550 nm are discussed respectively. Finally, the random walk coefficient (RWC) degradation induced from RIA and the scale factor error induced by MWS of the IFOG are simulated and tested at a wavelength of 1300 nm. This research will contribute to the applications of the fibers in radiation environments. Project supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry, China.

  10. Nonlinear optical absorption and stimulated Mie scattering in metallic nanoparticle suspensions

    Science.gov (United States)

    He, Guang S.; Law, Wing-Cheung; Baev, Alexander; Liu, Sha; Swihart, Mark T.; Prasad, Paras N.

    2013-01-01

    The nonlinear optical properties of four metallic (Au-, Au/Ag-, Ag-, and Pt-) nanoparticle suspensions in toluene have been studied in both femtosecond and nanosecond regimes. Nonlinear transmission measurements in the femtosecond laser regime revealed two-photon absorption (2PA) induced nonlinear attenuation, while in the nanosecond laser regime a stronger nonlinear attenuation is due to both 2PA and 2PA-induced excited-state absorption. In the nanosecond regime, at input pump laser intensities above a certain threshold value, a new type of stimulated (Mie) scattering has been observed. Being essentially different from all other well known molecular (Raman, Brillouin) stimulated scattering effects, the newly observed stimulated Mie scattering from the metallic nanoparticles exhibits the features of no frequency shift and low pump threshold requirement. A physical model of induced Bragg grating initiated by the backward Mie scattering from metallic nanoparticles is proposed to explain the gain mechanism of the observed stimulated scattering effect.

  11. Design of Optical Metamaterial Mirror with Metallic Nanoparticles for Broadband Light Absorption in Graphene Optoelectronic Devices

    CERN Document Server

    Lee, Seungwoo

    2015-01-01

    A general metallic mirror (i.e., a flat metallic surface) has been a popular optical component that can contribute broadband light absorption to thin-film optoelectronic devices; nonetheless, such electric mirror with a reversal of reflection phase inevitably causes the problem of minimized electric field near at the mirror surface (maximized electric field at one quarter of wavelength from mirror). This problem becomes more elucidated, when the deep-subwavelength-scaled two-dimensional (2D) material (e.g., graphene and molybdenum disulfide) is implemented into optoelectronic device as an active channel layer. The purpose of this work was to conceive the idea for using a charge storage layer (spherical Au nanoparticles (AuNPs), embedded into dielectric matrix) of the floating-gate graphene photodetector as a magnetic mirror, which allows the device to harness the increase in broadband light absorption. In particular, we systematically examined whether the versatile assembly of spherical AuNP monolayer within ...

  12. Optical Absorption and Electron Injection of 4-(Cyanomethylbenzoic Acid Based Dyes: A DFT Study

    Directory of Open Access Journals (Sweden)

    Yuehua Zhang

    2015-01-01

    Full Text Available Density functional theory (DFT and time-dependent density functional theory (TDDFT calculations were carried out to study the ground state geometries, electronic structures, and absorption spectra of 4-(cyanomethylbenzoic acid based dyes (AG1 and AG2 used for dye-sensitized solar cells (DSSCs. The excited states properties and the thermodynamical parameters of electron injection were studied. The results showed that (a two dyes have uncoplanar structures along the donor unit and conjugated bridge space, (b two sensitizers exhibited intense absorption in the UV-Vis region, and (c the excited state oxidation potential was higher than the conduction band edge of TiO2 photoanode. As a result, a solar cell based on the 4-(cyanomethylbenzoic acid based dyes exhibited well photovoltaic performance. Furthermore, nine dyes were designed on the basis of AG1 and AG2 to improve optical response and electron injection.

  13. Edge physics of the quantum spin Hall insulator from a quantum dot excited by optical absorption.

    Science.gov (United States)

    Vasseur, Romain; Moore, Joel E

    2014-04-11

    The gapless edge modes of the quantum spin Hall insulator form a helical liquid in which the direction of motion along the edge is determined by the spin orientation of the electrons. In order to probe the Luttinger liquid physics of these edge states and their interaction with a magnetic (Kondo) impurity, we consider a setup where the helical liquid is tunnel coupled to a semiconductor quantum dot that is excited by optical absorption, thereby inducing an effective quantum quench of the tunneling. At low energy, the absorption spectrum is dominated by a power-law singularity. The corresponding exponent is directly related to the interaction strength (Luttinger parameter) and can be computed exactly using boundary conformal field theory thanks to the unique nature of the quantum spin Hall edge.

  14. Enhanced optical absorption by Ag nanoparticles in a thin film Si solar cell

    Institute of Scientific and Technical Information of China (English)

    Chen Feng-Xiang; Wang Li-Sheng; Xu Wen-Ying

    2013-01-01

    Thin film solar cells have the potential to significantly reduce the cost of photovoltaics.Light trapping is crucial to such a thin film silicon solar cell because of a low absorption coefficient due to its indirect band gap.In this paper,we investigate the suitability of surface plasmon resonance Ag nanoparticles for enhancing optical absorption in the thin film solar cell.For evaluating the transmittance capability of Ag nanoparticles and the conventional antireflection film,an enhanced transmittance factor is introduced.We find that under the solar spectrum AM1.5,the transmittance of Ag nanoparticles with radius over 160 nm is equivalent to that of conventional textured antireflection film,and its effect is better than that of the planar antireflection film.The influence of the surrounding medium is also discussed.

  15. Anormalous Optical Absorption in Porous Al_2O3 Host Matrix---Nano-Oxide Particle Nanocomposites

    Science.gov (United States)

    Zhang, Lide; Zhang, Biao; Mo, Chimei

    1996-03-01

    Porous Al_2O3 host matrix---nano-γ-Fe_2O3 particle composites (porous nanocomposite) were prepared by pyrolysis of Fe(NO_3)_39H_2O in porous nano- Al_2O3 matrix at 250^0C. Comparing with simple nanocomposites formed by mixing nano-γ-Fe_2O3 and compacting at room temperature, followed by annealing at 250^0C, the following anomalous optical behaviors were observed: for porous nanocomposite containing 5% Fe_2O_3, the aborption edge shifts obviously from 827nm to 543nm, and with increasing dopping amount of Fe_2O3 from 5% to 70%, blue shift phenomina decreases. Namely, the absorption edge moves from 543nm to 710nm. The mechanism of shift of the absorption edge is discussed.

  16. Optical Parameters and Absorption of Azo Dye and Its Metal-Substituted Compound Thin Films

    Institute of Scientific and Technical Information of China (English)

    魏斌; 吴谊群; 顾冬红; 干福熹

    2003-01-01

    We determine the complex refractive indices N ( N = n - ik), dielectric constants ε(ε = ε1 - iε2), and absorption coefficients α of a new azo dye [2-(6-methyl-2-benzothiazolyazo)-5-diethylaminophenol(MBADP)]-doped polymer and its nickel- and zinc-substituted compounds(Ni-MBADP and Zn-MBADP) spin-coated thin films from a scanning ellipsometer in the wavelength 400-700 nm region. Metal chelation strongly (about one times) enhances the optical and dielectric parameters at the peaks and results in a large bathochromic shift (50-60nm) of absorption band. Bathochromic shift of Ni-MBADP is about 10nm larger than that of Zn-MBADP due to different spatial configurations formed in the metal-azo complexes.

  17. Optical absorption in a disk-shaped quantum dot in the presence of an impurity

    Science.gov (United States)

    Mikhail, I. F. I.; Shafee, A. M.

    2017-02-01

    The linear and third order nonlinear optical absorption coefficients have been calculated in a two dimensional disk quantum dot. The confinement potential has been taken to be a combination of a parabolic and inverse squared part. The study has been performed in the presence of a perpendicular static magnetic field and a central or off-central impurity. The resulting Schrödinger equation has been solved by applying the variational method. It has been found that the presence of impurity causes a huge increase in the square of the transition matrix and in the absorption coefficients, in particular in the third order coefficient. Moreover, the asymmetry which results in the case of off-central impurity has been dealt with carefully by taking into consideration the transition matrices which vanish in other cases.

  18. Optical absorption and fluorescence properties of Er3+ in sodium borate glass

    Indian Academy of Sciences (India)

    Y C Ratnakaram; J Lakshmi; R P S Chakradhar

    2005-08-01

    Spectroscopic properties of Er3+ ions in sodium borate glass have been studied. The indirect and direct optical band gaps (opt) and energy level parameters (Racah (1, 2 and 3), spin-orbit (4f) and configurational interaction ()) are evaluated. Spectral intensities for various absorption bands of Er3+ doped sodium borate glass are calculated. Using Judd–Ofelt intensity parameters (2, 4, 6), radiative transition probabilities (), branching ratios () and integrated absorption cross sections ( ) are reported for certain transitions. The radiative lifetimes (R) for different excited states are estimated. From the fluorescence spectra, the emission cross section (p) for the transition, ${}^{4}I_{13/2} \\rightarrow {}^{4}I_{15/2}$ is reported.

  19. Intranight optical variability of radio-loud broad absorption line quasars

    CERN Document Server

    Joshi, Ravi

    2012-01-01

    We present the results of an optical photometric monitoring program of 10 extremely radio loud broad absorption line quasars (RL-BALQSOs) with radio-loudness parameter, R, greater than 100 and magnitude g_i < 19. Over an observing run of about 3.5-6.5 hour we found a clear detection of variability for one of our 10 radio-loud BALQSOs with the INOV duty cycle of 5.1 per cent, while on including the probable variable cases, a higher duty cycle of 35.1 per cent is found; which are very similar to the duty cycle of radio quiet broad absorption line quasars (RQ-BALQSOs). This low duty cycle of clear variability per cent in radio-loud sub-class of BALQSOs can be understood under the premise where BALs outflow may arise from large variety of viewing angles from the jet axis or perhaps being closer to the disc plane.

  20. On the relation of optical obscuration and X-ray absorption in Seyfert galaxies

    CERN Document Server

    Burtscher, L; Gracia-Carpio, J; Koss, M J; Lin, M -Y; Lutz, D; Nandra, P; Netzer, H; de Xivry, G Orban; Ricci, C; Rosario, D J; Veilleux, S; Contursi, A; Genzel, R; Schnorr-Mueller, A; Sternberg, A; Sturm, E; Tacconi, L J

    2016-01-01

    The optical classification of a Seyfert galaxy and whether it is considered X-ray absorbed are often used interchangeably. But there are many borderline cases and also numerous examples where the optical and X-ray classifications appear to be in conflict. In this article we re-visit the relation between optical obscuration and X-ray absorption in AGNs. We make use of our "dust color" method (Burtscher et al. 2015) to derive the optical obscuration A_V and consistently estimated X-ray absorbing columns using 0.3--150 keV spectral energy distributions. We also take into account the variable nature of the neutral gas column N_H and derive the Seyfert sub-classes of all our objects in a consistent way. We show in a sample of 25 local, hard-X-ray detected Seyfert galaxies (log L_X / (erg/s) ~ 41.5 - 43.5) that there can actually be a good agreement between optical and X-ray classification. If Seyfert types 1.8 and 1.9 are considered unobscured, the threshold between X-ray unabsorbed and absorbed should be chosen a...

  1. Probing iron spin state by optical absorption in laser-heated diamond anvil cell

    Science.gov (United States)

    Lobanov, S.; Goncharov, A. F.; Holtgrewe, N.; Lin, J. F.

    2015-12-01

    Pressure-induced spin-pairing transitions in iron-bearing minerals have been in the focus of geophysical studies1. Modern consensus is that iron spin state in the lower mantle is a complex function of crystal structure, composition, pressure, and temperature. Discontinuities in physical properties of lower mantle minerals have been revealed over the spin transition pressure range, but at room temperature. In this work, we have used a supercontinuum laser source and an intensified CCD camera to probe optical properties of siderite, FeCO3, and post-perovskite, Mg0.9Fe0.1SiO3, across the spin transition in laser-heated diamond anvil cell. Synchronously gating the CCD with the supercontinuum pulses (Fig. 1A) allowed diminishing thermal background to ~8.3*10-4. Utilizing the experimental setup we infer the spin state of ferrous iron in siderite at high pressure and temperature conditions (Fig. 1B). Similar behavior is observed for low spin ferric iron in post-perovskite at 130 GPa indicating that all iron in post-perovskite is high spin at lower mantle conditions. Also, our experimental setup holds promise for measuring radiative thermal conductivity of mantle minerals at relevant mantle conditions. Figure 1. (A) Timing of the optical absorption measurements at high temperature. (B) High temperature siderite absorption spectra at 45 GPa. Before heating and quenched after 1300 K spectra are shown in light and dark blue, respectively. Green and red curves are absorption spectra at 1200 K and 1300 K, respectively. Spectra shown in black represent room temperature absorption data on HS (43 GPa) and LS (45.5 GPa) siderite after Lobanov et al., 2015, shown for comparison.

  2. A robust optical parametric oscillator and receiver telescope for differential absorption lidar of greenhouse gases

    Science.gov (United States)

    Robinson, Iain; Jack, James W.; Rae, Cameron F.; Moncrieff, John B.

    2015-10-01

    We report the development of a differential absorption lidar instrument (DIAL) designed and built specifically for the measurement of anthropogenic greenhouse gases in the atmosphere. The DIAL is integrated into a commercial astronomical telescope to provide high-quality receiver optics and enable automated scanning for three-dimensional lidar acquisition. The instrument is portable and can be set up within a few hours in the field. The laser source is a pulsed optical parametric oscillator (OPO) which outputs light at a wavelength tunable near 1.6 μm. This wavelength region, which is also used in telecommunications devices, provides access to absorption lines in both carbon dioxide at 1573 nm and methane at 1646 nm. To achieve the critical temperature stability required for a laserbased field instrument the four-mirror OPO cavity is machined from a single aluminium block. A piezoactuator adjusts the cavity length to achieve resonance and this is maintained over temperature changes through the use of a feedback loop. The laser output is continuously monitored with pyroelectric detectors and a custom-built wavemeter. The OPO is injection seeded by a temperature-stabilized distributed feedback laser diode (DFB-LD) with a wavelength locked to the absorption line centre (on-line) using a gas cell containing pure carbon dioxide. A second DFB-LD is tuned to a nearby wavelength (off-line) to provide the reference required for differential absorption measurements. A similar system has been designed and built to provide the injection seeding wavelengths for methane. The system integrates the DFB-LDs, drivers, locking electronics, gas cell and balanced photodetectors. The results of test measurements of carbon dioxide are presented and the development of the system is discussed, including the adaptation required for the measurement of methane.

  3. Enhanced nonlinear optical absorption and optical limiting properties of superparamagnetic spinel zinc ferrite decorated reduced graphene oxide nanostructures

    Science.gov (United States)

    Saravanan, M.; T. C., Sabari Girisun

    2017-01-01

    Nonlinear absorption and optical limiting properties of ZnFe2O4-rGO magnetic nanostructures was investigated by the Z-scan technique using Q-switched Nd:YAG laser (5 ns, 532 nm, 10 Hz) as an excitation source. Excited state absorption was the dominant process responsible for the observed nonlinearity in ZnFe2O4 decorated rGO which arises due to photo-generated charge carriers in the conduction band of zinc ferrite and increases in defects at the surface of rGO due to the incorporation of ZnFe2O4. The magnitude of the nonlinear absorption co-efficient was found to be in the order of 10-10 m/W. A noteworthy enhancement in the third-order NLO properties in ZnFe2O4-(15 wt%) rGO with those of individual counter parts and well known graphene composites was reported. Role of induced defects states (sp3) arising from the functionalization of rGO in the enhancement of NLO response was explained through Raman studies. Earlier incorporation and distribution of ZnFe2O4 upon GO through one-step hydrothermal method was analyzed by XRD and FTIR. Formation of (nanospheres/nanospindles) ZnFe2O4 along with reduction of graphene oxide was confirmed through TEM analysis. VSM studies showed zinc ferrite decorated rGO posseses superparamagnetic behavior. The tuning of nonlinear optical and magnetic behavior with variation in the content of spinel ferrites upon reduced graphene oxide provides an easy way to attain tunable properties which are exceedingly required in both optoelectronics and photothermal therapy applications.

  4. Optical absorption of CdSe quantum dots on electrodes with different morphology

    Directory of Open Access Journals (Sweden)

    Witoon Yindeesuk

    2013-10-01

    Full Text Available We have studied the optical absorption of CdSe quantum dots (QDs adsorbed on inverse opal TiO2 (IO-TiO2 and nanoparticulate TiO2 (NP-TiO2 electrodes using photoacoustic (PA measurements. The CdSe QDs were grown directly on IO-TiO2 and NP-TiO2 electrodes by a successive ionic layer adsorption and reaction (SILAR method with different numbers of cycles. The average diameter of the QDs was estimated by applying an effective mass approximation to the PA spectra. The increasing size of the QDs with increasing number of cycles was confirmed by a redshift in the optical absorption spectrum. The average diameter of the CdSe QDs on the IO-TiO2 electrodes was similar to that on the NP-TiO2 ones, indicating that growth is independent of morphology. However, there were more CdSe QDs on the NP-TiO2 electrodes than on the IO-TiO2 ones, indicating that there were different amounts of active sites on each type of electrode. In addition, the Urbach parameter of the exponential optical absorption tail was also estimated from the PA spectrum. The Urbach parameter of CdSe QDs on IO-TiO2 electrodes was higher than that on NP-TiO2 ones, indicating that CdSe QDs on IO-TiO2 electrodes are more disordered states than those on NP-TiO2 electrodes. The Urbach parameter decreases in both cases with the increase of SILAR cycles, and it tended to move toward a constant value.

  5. A structure preserving Lanczos algorithm for computing the optical absorption spectrum

    CERN Document Server

    Shao, Meiyue; Lin, Lin; Yang, Chao; Deslippe, Jack; Louie, Steven G

    2016-01-01

    We present a new structure preserving Lanczos algorithm for approximating the optical absorption spectrum in the context of solving full Bethe--Salpeter equation without Tamm--Dancoff approximation. The new algorithm is based on a structure preserving Lanczos procedure, which exploits the special block structure of Bethe--Salpeter Hamiltonian matrices. A recently developed technique of generalized averaged Gauss quadrature is incorporated to accelerate the convergence. We also establish the connection between our structure preserving Lanczos procedure with several existing Lanczos procedures developed in different contexts. Numerical examples are presented to demonstrate the effectiveness of our Lanczos algorithm.

  6. A relation between electromagnetically induced absorption resonances and nonlinear magneto-optics in Lambda-systems

    CERN Document Server

    Budker, D

    2003-01-01

    Recent work on Lambda-resonances in alkali metal vapors (E. Mikhailov, I. Novikova, Yu. V. Rostovtsev, and G. R. Welch, quant-ph/0309171, and references therein) has revealed a novel type of electromagnetically induced absorption resonance that occurs in three-level systems under specific conditions normally associated with electromagnetically induced transparency. In this note, we show that these resonances have a direct analog in nonlinear magneto-optics, and support this conclusion with a calculation for a J=1->J'=0 system interacting with a single nearly circularly polarized light field in the presence of a weak longitudinal magnetic field.

  7. Sign reversal of Hanle electromagnetically induced absorption with orthogonal circularly polarized optical fields

    Energy Technology Data Exchange (ETDEWEB)

    Ram, Nibedita; Pattabiraman, M, E-mail: pattu@physics.iitm.ac.i [Department of Physics, Indian Institute of Technology Madras, Chennai 600036 (India)

    2010-12-28

    We study by computation and experiment an electromagnetically induced absorption resonance in the Hanle configuration with a transverse magnetic field on a closed F{sub g} {yields} F{sub e} = F{sub g}+1 transition with co-propagating orthogonal circularly polarized probe and coupling optical fields. At high coupling field intensities, the Hanle resonance changes sign due to a shift in atomic population from Zeeman sublevels associated with a probe field cyclic transition to sublevels associated with a coupling field cyclic transition at zero magnetic field. We also show that a similar sign reversal does not occur for {pi}-polarized and {sigma}-polarized coupling fields.

  8. ESR and optical absorption studies of gamma- and electron-irradiated sugar crystals

    Energy Technology Data Exchange (ETDEWEB)

    Flores, J.C.; Cabrera, B.E.; Calderon, T.; Munoz, P.E.; Adem, E.; Hernandez, A.J.; Boldu, J.L.; Ovalle M.P.; Murrieta, S.H. E-mail: murrieta@fenix.ifisicacu.unam.mx

    2000-05-15

    Electron spin resonance (ESR) studies of the free radicals induced in gamma- or electron-irradiated sugar crystals were performed. The number of radicals increases linearly, pointing out that this material can be used as a dosimeter. The optical absorption studies show the presence of several distinctive bands in the infrared and UV region, whose intensity changes with the irradiation dose. An interpretation of these results in terms of the formation of free radicals and possible crosslinking along the sugar molecular chains is presented.

  9. Structural control of nonlinear optical absorption and refraction in dense metal nanoparticle arrays.

    Science.gov (United States)

    Kohlgraf-Owens, Dana C; Kik, Pieter G

    2009-08-17

    The linear and nonlinear optical properties of a composite containing interacting spherical silver nanoparticles embedded in a dielectric host are studied as a function of interparticle separation using three dimensional frequency domain simulations. It is shown that for a fixed amount of metal, the effective third-order nonlinear susceptibility of the composite chi((3))(omega) can be significantly enhanced with respect to the linear optical properties, due to a combination of resonant surface plasmon excitation and local field redistribution. It is shown that this geometry-dependent susceptibility enhancement can lead to an improved figure of merit for nonlinear absorption. Enhancement factors for the nonlinear susceptibility of the composite are calculated, and the complex nature of the enhancement factors is discussed.

  10. Plasmon enhanced broadband optical absorption in ultrathin silicon nanobowl array for photoactive devices applications

    Science.gov (United States)

    Sun, Rui-Nan; Peng, Kui-Qing; Hu, Bo; Hu, Ya; Zhang, Fu-Qiang; Lee, Shuit-Tong

    2015-07-01

    Both photonic and plasmonic nanostructures are key optical components of photoactive devices for light harvesting, enabling solar cells with significant thickness reduction, and light detectors capable of detecting photons with sub-band gap energies. In this work, we study the plasmon enhanced broadband light absorption and electrical properties of silicon nanobowl (SiNB) arrays. The SiNB-metal photonic-plasmonic nanostructure-based devices exhibited superior light-harvesting ability across a wide range of wavelengths up to the infrared regime well below the band edge of Si due to effective optical coupling between the SiNB array and incident sunlight, as well as electric field intensity enhancement around metal nanoparticles due to localized surface plasmon resonance. The photonic-plasmonic nanostructure is expected to result in infrared-light detectors and high-efficiency solar cells by extending light-harvesting to infrared frequencies.

  11. Bound states in optical absorption of semiconductor quantum wells containing a two-dimensional electron Gas

    Science.gov (United States)

    Huard; Cox; Saminadayar; Arnoult; Tatarenko

    2000-01-01

    The dependence of the optical absorption spectrum of a semiconductor quantum well on two-dimensional electron concentration n(e) is studied using CdTe samples. The trion peak (X-) seen at low n(e) evolves smoothly into the Fermi edge singularity at high n(e). The exciton peak (X) moves off to high energy, weakens, and disappears. The X,X- splitting is linear in n(e) and closely equal to the Fermi energy plus the trion binding energy. For Cd0.998Mn0.002Te quantum wells in a magnetic field, the X,X- splitting reflects unequal Fermi energies for M = +/-1/2 electrons. The data are explained by Hawrylak's theory of the many-body optical response including spin effects.

  12. Two-photon Absorption and Nonlinear Optical Properties of A New Organic Dye DEASPI

    Institute of Scientific and Technical Information of China (English)

    Guangyong ZHOU; Xiaomei WANG; Dong WANG; Chun WANG; Xian ZHAO; Zongshu SHAO; Minhua JIANG

    2001-01-01

    A new organic dye trans-4- [p-(N,N-diethylamino) styryl ]-N-methylpyridinium iodide (abbreviatedas DEASPI thereafter) with large two-photon absorption (TPA) cross section and excellent upconverted lasing properties was synthesized. The melting point and decompound point were measured to be 230℃ and 264.7℃ respectively. The molecular TPA cross section was meaThe linear and nonlinear optical properties of this dye were systematically studied. The highest net upconversion efficiency from the absorbed pump energy to the output upconverted lasing energy is as high as 18.6% at the pump energy of 2.17 mJ from a mode-locked Nd:YAG ps laser.The nonlinear transmittance at the wavelengths from 720 to 1100 nm was measured. The dye solution also shows a clear optical power limiting effect.

  13. Extending differential optical absorption spectroscopy for limb measurements in the UV

    Science.gov (United States)

    Puä·Ä«Te, J.; Kühl, S.; Deutschmann, T.; Platt, U.; Wagner, T.

    2010-05-01

    Methods of UV/VIS absorption spectroscopy to determine the constituents in the Earth's atmosphere from measurements of scattered light are often based on the Beer-Lambert law, like e.g. Differential Optical Absorption Spectroscopy (DOAS). While the Beer-Lambert law is strictly valid for a single light path only, the relation between the optical depth and the concentration of any absorber can be approximated as linear also for scattered light observations at a single wavelength if the absorption is weak. If the light path distribution is approximated not to vary with wavelength, also linearity between the optical depth and the product of the cross-section and the concentration of an absorber can be assumed. These assumptions are widely made for DOAS applications for scattered light observations. For medium and strong absorption of scattered light (e.g. along very long light-paths like in limb geometry) the relation between the optical depth and the concentration of an absorber is no longer linear. In addition, for broad wavelength intervals the differences in the travelled light-paths at different wavelengths become important, especially in the UV, where the probability for scattering increases strongly with decreasing wavelength. However, the DOAS method can be extended to cases with medium to strong absorptions and for broader wavelength intervals by the so called air mass factor modified (or extended) DOAS and the weighting function modified DOAS. These approaches take into account the wavelength dependency of the slant column densities (SCDs), but also require a priori knowledge for the air mass factor or the weighting function from radiative transfer modelling. We describe an approach that considers the fitting results obtained from DOAS, the SCDs, as a function of wavelength and vertical optical depth and expands this function into a Taylor series of both quantities. The Taylor coefficients are then applied as additional fitting parameters in the DOAS analysis

  14. Extending differential optical absorption spectroscopy for limb measurements in the UV

    Directory of Open Access Journals (Sweden)

    J. Puķīte

    2010-05-01

    Full Text Available Methods of UV/VIS absorption spectroscopy to determine the constituents in the Earth's atmosphere from measurements of scattered light are often based on the Beer-Lambert law, like e.g. Differential Optical Absorption Spectroscopy (DOAS. While the Beer-Lambert law is strictly valid for a single light path only, the relation between the optical depth and the concentration of any absorber can be approximated as linear also for scattered light observations at a single wavelength if the absorption is weak. If the light path distribution is approximated not to vary with wavelength, also linearity between the optical depth and the product of the cross-section and the concentration of an absorber can be assumed. These assumptions are widely made for DOAS applications for scattered light observations.

    For medium and strong absorption of scattered light (e.g. along very long light-paths like in limb geometry the relation between the optical depth and the concentration of an absorber is no longer linear. In addition, for broad wavelength intervals the differences in the travelled light-paths at different wavelengths become important, especially in the UV, where the probability for scattering increases strongly with decreasing wavelength.

    However, the DOAS method can be extended to cases with medium to strong absorptions and for broader wavelength intervals by the so called air mass factor modified (or extended DOAS and the weighting function modified DOAS. These approaches take into account the wavelength dependency of the slant column densities (SCDs, but also require a priori knowledge for the air mass factor or the weighting function from radiative transfer modelling.

    We describe an approach that considers the fitting results obtained from DOAS, the SCDs, as a function of wavelength and vertical optical depth and expands this function into a Taylor series of both quantities. The Taylor coefficients are then applied as

  15. First-principles calculation of optical absorption spectra in conjugated polymers: Role of electron-hole interaction

    Energy Technology Data Exchange (ETDEWEB)

    Rohlfing, Michael; Tiago, M.L.; Louie, Steven G.

    2000-03-20

    Experimental and theoretical studies have shown that excitonic effects play an important role in the optical properties of conjugated polymers. The optical absorption spectrum of trans-polyacetylene, for example, can be understood as completely dominated by the formation of exciton bound states. We review a recently developed first-principles method for computing the excitonic effects and optical spectrum, with no adjustable parameters. This theory is used to study the absorption spectrum of two conjugated polymers: trans-polyacetylene and poly-phenylene-vinylene(PPV).

  16. Functionally graded poly(dimethylsiloxane)/silver nanocomposites with tailored broadband optical absorption

    Energy Technology Data Exchange (ETDEWEB)

    Nikolaou, P.; Mina, C.; Constantinou, M.; Koutsokeras, L.E.; Constantinides, G. [Research Unit for Nanostructured Materials Systems, Department of Mechanical Engineering and Materials Science and Engineering, PO Box 50329, 3603 Limassol (Cyprus); Lidorikis, E.; Avgeropoulos, A. [Department of Materials Science and Engineering, University of Ioannina, 45110 Ioannina (Greece); Kelires, P.C. [Research Unit for Nanostructured Materials Systems, Department of Mechanical Engineering and Materials Science and Engineering, PO Box 50329, 3603 Limassol (Cyprus); Patsalas, P., E-mail: ppats@physics.auth.gr [Physics Department, Aristotle University of Thessaloniki, Thessaloniki 54124 (Greece)

    2015-04-30

    In this work, we produce functionally graded nanocomposites consisting of silver (Ag) plasmonic nanoparticles (PNPs) supported in a poly(dimethylsiloxane) (PDMS) matrix. PDMS was selected due to its high optical transparency, nontoxicity and ease of use. The Ag PNPs were formed by annealing sputtered Ag ultra-thin films and were subsequently capped by a spin-coated PDMS layer. We investigate the factors that affect their plasmonic behavior, such as the PNP size, the annealing conditions and the surrounding environment. In order to achieve broadband absorption, we developed PDMS/Ag(PNPs) multilayers with graded PNP size. Thus, we demonstrate the significance of the stacking sequence of various plasmonic layers sandwiched between PDMS layers and its potential for tailoring the plasmonic response of multilayer structure. As a demonstration of this approach, we deposited a specially designed multilayer structure, whose optical extinction resembles the solar emission spectrum. - Highlights: • Elastomers are combined with plasmonic nanoparticles. • The plasmonic effects in stratified media are identified. • Broadband absorption similar to solar emission is achieved.

  17. Synthesis, XRD, TEM, EPR, and Optical Absorption Spectral Studies of CuZnO2 Nanocompound

    Directory of Open Access Journals (Sweden)

    T. Ravindra Reddy

    2014-01-01

    Full Text Available Synthesis of nano CuZnO2 compound is carried out by thermal decomposition method. The crystalline phase of the material is characterized by XRD. The calculated unit cell constants are a=3.1 Å and c=3.4786 Å and are of tetragonal structure. The unit cell constants are different from wurtzite (hexagonal which indicate that a nanocompound is formed. Further TEM images reveal that the metal ion is in tetragonal structure with oxygen ligands. The prepared CuZnO2 is then characterized for crystallite size analysis by employing transmission electron microscopy (TEM. The size is found to be 100 nm. Uniform bright rings are noticed in the TEM picture suggesting that the nanocrystals have preferential instead of random orientations. The selected-area electron diffraction (SAED pattern clearly indicates the formation of CuO-ZnO nanocompound. The nature of bonding is studied by electron paramagnetic resonance (EPR. The covalency character is about 0.74 and thus the compound is electrically less conductive. Optical absorption spectral studies suggest that Cu(II is placed in tetragonal elongation crystal field. The spin-orbit coupling constant, λ, is calculated using the EPR and optical absorption spectral results suggest some covalent bond between metal and ligand. Near infrared (NIR spectra are due to hydroxyl and water fundamentals.

  18. Optical Absorption and Photo-Thermal Conversion Properties of CuO/H2O Nanofluids.

    Science.gov (United States)

    Wang, Liangang; Wu, Mingyan; Wu, Daxiong; Zhang, Canying; Zhu, Qunzhi; Zhu, Haitao

    2015-04-01

    Stable CuO/H2O nanofluids were synthesized in a wet chemical method. Optical absorption property of CuO/H2O nanofluids was investigated with hemispheric transmission spectrum in the wavelength range from 200 nm to 2500 nm. Photo-thermal conversion property of the CuO/H2O nanofluids was studied with an evaluation system equipped with an AUT-FSL semiconductor/solid state laser. The results indicate that CuO/H2O nanofluids have strong absorption in visible light region where water has little absorption. Under the irradiation of laser beam with a wavelength of 635 nm and a power of 0.015 W, the temperature of CuO/H2O nanofluids with 1.0% mass fraction increased by 5.6 °C within 40 seconds. Furthermore, the temperature elevation of CuO/H2O nanofluids was proved to increase with increasing mass fractions. On the contrast, water showed little temperature elevation under the identical conditions. The present work shows that the CuO/H2O nanofluids have high potential in the application as working fluids for solar utilization purpose.

  19. Calculation of optical and K pre-edge absorption spectra for ferrous iron of distorted sites in oxide crystals

    Science.gov (United States)

    Vercamer, Vincent; Hunault, Myrtille O. J. Y.; Lelong, Gérald; Haverkort, Maurits W.; Calas, Georges; Arai, Yusuke; Hijiya, Hiroyuki; Paulatto, Lorenzo; Brouder, Christian; Arrio, Marie-Anne; Juhin, Amélie

    2016-12-01

    Advanced semiempirical calculations have been performed to compute simultaneously optical absorption and K pre-edge x-ray absorption spectra of Fe2 + in four distinct site symmetries found in minerals. The four symmetries, i.e., a distorted octahedron, a distorted tetrahedron, a square planar site, and a trigonal bipyramidal site, are representative of the Fe2 + sites found in crystals and glasses. A particular attention has been paid to the definition of the p -d hybridization Hamiltonian which occurs for noncentrosymmetric symmetries in order to account for electric dipole transitions. For the different sites under study, an excellent agreement between calculations and experiments was found for both optical and x-ray absorption spectra, in particular in terms of relative intensities and energy positions of electronic transitions. To our knowledge, these are the first calculations of optical absorption spectra on Fe2 + placed in such diverse site symmetries, including centrosymmetric sites. The proposed theoretical model should help to interpret the features of both the optical absorption and the K pre-edge absorption spectra of 3 d transition metal ions and to go beyond the usual fingerprint interpretation.

  20. Structural, thermal and optical absorption features of heavy metal oxides doped tellurite rich glasses

    Science.gov (United States)

    Kaky, Kawa M.; Lakshminarayana, G.; Baki, S. O.; Kityk, I. V.; Taufiq-Yap, Y. H.; Mahdi, M. A.

    In order to improve tellurite glass stability to be applicable for optical fiber amplifier applications, glasses with the composition of (70 - x)TeO2. (10)ZnO. (10)WO3. (5)Na2O. (5)TiO2. (x)Bi2O3 (x = 1, 2, 3, 4, and 5 mol%) have been produced and characterized using the related methods. Structural properties were investigated using X-ray diffraction (XRD) which confirms the non-crystalline structure and scanning electron microscopy (SEM) micrographs also confirm the XRD results. The energy dispersive X-ray (EDX) analysis profiles show that all the mentioned elements are present in the prepared glasses. Following the IR spectra, all the tellurium bonds such as stretching vibrations of TeO4 tbp and TeO3/TeO3+1 unit are revealed. Raman spectra confirm the presence of different functional groups, actually, it shows bands mainly in four spectral regions: R1 (65-150) cm-1, R2 (280-550) cm-1, R3 (880-950) cm-1 and R4 (916-926) cm-1 and the identified bands are assigned to respective molecular groups. The thermal study was carried out using Differential scanning calorimetry (DSC) which indicates good thermal stability of the synthesized glasses with increasing Bi concentration. From the optical absorption spectra, we evaluated cut-off edge wavelengths and found increasing cutoff wavelength with an increase in Bi2O3 concentration. In the UV-Visible region, optical band gap energy and allowed transitions were investigated using three methods; direct, indirect, and absorption spectrum fitting (ASF), and band gaps from indirect and ASF were matched.

  1. Extending differential optical absorption spectroscopy for limb measurements in the UV

    Directory of Open Access Journals (Sweden)

    J. Puķīte

    2009-11-01

    Full Text Available Methods of UV/VIS absorption spectroscopy to determine the constituents in the Earth's atmosphere from measurements of scattered light are often based on the Beer-Lambert law, like e.g. Differential Optical Absorption Spectroscopy (DOAS. Therefore they are strictly valid for weak absorptions and narrow wavelength intervals (strictly only for monochromatic radiation. For medium and strong absorption (e.g. along very long light-paths like in limb geometry the relation between the optical depth and the concentration of an absorber is not linear anymore. As well, for large wavelength intervals the wavelength dependent differences in the travelled light-paths become important, especially in the UV, where the probability for scattering increases strongly with decreasing wavelength.

    However, by taking into account these dependencies, the applicability of the DOAS method can be extended also to cases with medium to strong absorptions and for broader wavelength intervals.

    Common approaches for this correction are the so called air mass factor modified (or extended DOAS and the weighting function modified DOAS. These approaches take into account the wavelength dependency of the slant column densities (SCDs, but also require a-priori knowledge for the air mass factor or the weighting function calculation by radiative transfer modelling.

    We describe an approach that considers the fitting results obtained from DOAS, the SCDs, as a function of wavelength and vertical optical depth and expands this function into a Taylor series of both quantities. The Taylor coefficients are then applied as additional fitting parameters in the DOAS analysis. Thus the variability of the SCD in the fit window is determined by the retrieval itself.

    This new approach gives a description of the SCD that is as close to reality as desired (depending on the order of the Taylor expansion, and is independent from any assumptions or a-priori knowledge

  2. Noise-driven optical absorption coefficients of impurity doped quantum dots

    Science.gov (United States)

    Ganguly, Jayanta; Saha, Surajit; Pal, Suvajit; Ghosh, Manas

    2016-01-01

    We make an extensive investigation of linear, third-order nonlinear, and total optical absorption coefficients (ACs) of impurity doped quantum dots (QDs) in presence and absence of noise. The noise invoked in the present study is a Gaussian white noise. The quantum dot is doped with repulsive Gaussian impurity. Noise has been introduced to the system additively and multiplicatively. A perpendicular magnetic field acts as a source of confinement and a static external electric field has been applied. The AC profiles have been studied as a function of incident photon energy when several important parameters such as optical intensity, electric field strength, magnetic field strength, confinement energy, dopant location, relaxation time, Al concentration, dopant potential, and noise strength take on different values. In addition, the role of mode of application of noise (additive/multiplicative) on the AC profiles has also been analyzed meticulously. The AC profiles often consist of a number of interesting observations such as one photon resonance enhancement, shift of AC peak position, variation of AC peak intensity, and bleaching of AC peak. However, presence of noise alters the features of AC profiles and leads to some interesting manifestations. Multiplicative noise brings about more complexity in the AC profiles than its additive counterpart. The observations indeed illuminate several useful aspects in the study of linear and nonlinear optical properties of doped QD systems, specially in presence of noise. The findings are expected to be quite relevant from a technological perspective.

  3. Optical absorption of (Ag-Au133(SCH352 bimetallic monolayer-protected clusters

    Directory of Open Access Journals (Sweden)

    Alessandro Fortunelli

    2016-10-01

    Full Text Available The evolution of the optical absorption spectrum of bimetallic Ag-Au monolayer-protected clusters (MPC obtained by progressively doping Ag into the experimentally known structure of Au133(SR52 was predicted via rigorous time-dependent density-functional theory (TDDFT calculations. In addition to monometallic Au133(SR52 and Ag133(SR52 species, 5 different (Ag-Au133(SR52 homotops were considered with varying Ag content and site positioning, and their electronic structure and optical response were analyzed in terms of Projected Density Of States (PDOS, the induced or transition electron density, and Transition Component Maps (TCM at selected excitation energies. It was found that Ag doping led to the effects rather different from those encountered in bare metal clusters. And it was also observed that Ag doping could produce structured spectral features, especially in the 3–4 eV range but also in the optical region if Ag atoms were located in the sub-staple region, as rationalized by the accompanying electronic analysis. Additionally, Au doping into the staples of Ag-rich MPC also gave rise to a more homogeneous induced electron density. These findings show the great sensitivity of the electronic response of MPC nanoalloy systems to the exact location of the alloying sites.

  4. Optical limiting of niobic tellurite glass induced by self-trapped exciton absorption of the AgCl nanocrystal dopant

    Institute of Scientific and Technical Information of China (English)

    ZHAO ZhenYu; LIN Jian; JIA TianQin; SUN ZhenRong; WANG ZuGeng

    2009-01-01

    Nioblc tellurite glass doped by silver chloride nanocrystal was prepared with the melting-quenching and heat treatment method, and the self-trapped exciton absorption band of the silver chloride nanocrystal was observed at 532 nm in the UV-visible absorption spectrum. The glass structure chara-cteristics were investigated by Raman spectroscopy, and the mechanism of self-trapped exciton was analyzed by Jahn-Teller model. Its optical limiting was measured with 532 nm picosecond laser pulses, and the corresponding nonlinear absorption coefficient was measured with open-aperture Z-scan. The experimental results showed that optical limiting at 532 nm was attributed to free carrier absorption between the self-trapped state and the continuum band.

  5. Redox ratio and optical absorption of polyvalent ions in industrial glasses

    Indian Academy of Sciences (India)

    W Thiemsorn; K Keowkamnerd; P Suwannathada; H Hessenkemper; S Phanichaphant

    2007-10-01

    The changes in glass structure and redox ratio, (reduced ion to oxidized ion) of Mn2+–Mn3+, Cu+–Cu2+, Cr3+–Cr6+, Ni2+–Ni3+ and Co2+–Co3+ couples and optical absorption due to Mn3+, Cu2+, Cr3+, Ni2+ and Co2+ ions in industrial soda–lime–silica glass were investigated as a function of Na2O concentration in the range 11–19 mol%. With increasing Na2O concentration in the experimental glasses, the basicity, expressed as calculated basicity, cal, increased. 29Si NMR and X-ray diffraction were used to investigate the structural change in glasses. The NMR spectra showed high non-bridging oxygens (NBOs) when the basicity of glass was increased. The results were interpreted to be due to the tetrahedral networks; 4 species were depolymerized by replacing the bridging oxygens (BOs) with NBOs to 3 species. These results confirmed the shift of broadening peaks of XRD patterns. The redox reactions of the Mn2+–Mn3+, Cu+–Cu2+ and Cr3+–Cr6+ couples shifted more toward their oxidized ions due to the oxygen partial pressure, (2), during melting and the oxide ion activity, O2–, increased with increasing glass basicity. These changes caused the redox ratio of these ion couples to decrease. The Ni2+–Ni3+ and Co2+–Co3+ couples were assumed to be present only in the Ni2+ and Co2+ ions in these glasses, respectively. The optical absorption bands due to Mn3+, Cu2+, Cr3+, Ni2+ and Co2+ ions were also investigated. Their spectra occurred at constant wavelengths with different optical densities or intensities as a function of glass basicity. The increase in the intensities of the absorption bands of these absorbing ions, except for Cr3+ ion, at the maximum wavelength, depends not only on the ion concentration but also on the increase of polarizability of oxide (–II) species, oxide(–II), surrounding the ions. This value affected directly the extinction coefficients of the ions, ion. The increase of ion caused the colour of glasses appearing in high intensity. In

  6. Investigation on an evanescent wave fiber-optic absorption sensor based on fiber loop cavity ring-down spectroscopy

    Science.gov (United States)

    Jiang, Meng; Zhang, Weigang; Zhang, Qi; Liu, Yaping; Liu, Bo

    2010-01-01

    An improved ring-down measurement principle for optical waveguides is presented. Fiber loop ring-down spectroscopy allows for measurement of minute optical losses in high-finesse fiber-optic cavities and immunity to the fluctuation of laser source. The evanescent wave absorption losses dependent on the absorption and the refractive index of ambient solution have been theoretically analyzed. The complex refractive index is introduced into our model and extinction coefficient can be calculated accurately through finite element analysis by setting the boundaries of the fiber and the ambient conditions. Using this method, the refractive index of environment can be taken into consideration. Our principle is validated by the highly-sensitive measurement of evanescent wave absorption loss. By chemically processing the surface of sensing segment along an extending ring-down cavity, the concentration of small volume Diethyl Sulphoxide solution where the etched fiber immersed into has been successfully measured and discussed.

  7. Transient optical response of ultrafast nonequilibrium excited metals: Effects of electron-electron contribution to collisional absorption

    CERN Document Server

    Colombier, Jean-Philippe; Audouard, Eric; Stoian, Razvan

    2008-01-01

    Approaching energy coupling in laser-irradiated metals, we point out the role of electron-electron collision as an efficient control factor for ultrafast optical absorption. The high degree of laser-induced electron-ion nonequilibrium drives a complex absorption pattern with consequences on the transient optical properties. Consequently, high electronic temperatures determine largely the collision frequency and establish a transition between absorptive regimes in solid and plasma phases. In particular, taking into account umklapp electron-electron collisions, we performed hydrodynamic simulations of the laser-matter interaction to calculate laser energy deposition during the electron-ion nonequilibrium stage and subsequent matter transformation phases. We observe strong correlations between optical and thermodynamic properties according to the experimental situations. A suitable connection between solid and plasma regimes is chosen in accordance with models that describe the behavior in extreme, asymptotic re...

  8. Simultaneous high crystallinity and sub-bandgap optical absorptance in hyperdoped black silicon using nanosecond laser annealing

    Energy Technology Data Exchange (ETDEWEB)

    Franta, Benjamin, E-mail: bafranta@gmail.com; Pastor, David; Gandhi, Hemi H.; Aziz, Michael J.; Mazur, Eric [School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts 02138 (United States); Rekemeyer, Paul H.; Gradečak, Silvija [Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)

    2015-12-14

    Hyperdoped black silicon fabricated with femtosecond laser irradiation has attracted interest for applications in infrared photodetectors and intermediate band photovoltaics due to its sub-bandgap optical absorptance and light-trapping surface. However, hyperdoped black silicon typically has an amorphous and polyphasic polycrystalline surface that can interfere with carrier transport, electrical rectification, and intermediate band formation. Past studies have used thermal annealing to obtain high crystallinity in hyperdoped black silicon, but thermal annealing causes a deactivation of the sub-bandgap optical absorptance. In this study, nanosecond laser annealing is used to obtain high crystallinity and remove pressure-induced phases in hyperdoped black silicon while maintaining high sub-bandgap optical absorptance and a light-trapping surface morphology. Furthermore, it is shown that nanosecond laser annealing reactivates the sub-bandgap optical absorptance of hyperdoped black silicon after deactivation by thermal annealing. Thermal annealing and nanosecond laser annealing can be combined in sequence to fabricate hyperdoped black silicon that simultaneously shows high crystallinity, high above-bandgap and sub-bandgap absorptance, and a rectifying electrical homojunction. Such nanosecond laser annealing could potentially be applied to non-equilibrium material systems beyond hyperdoped black silicon.

  9. Morphology Control and Optical Absorption Properties of Ag Nanoparticles by Ion Implantation

    Institute of Scientific and Technical Information of China (English)

    G.X. Cai; F. Ren; X.H. Xiao; L.X. Fan; X.D. Zhou; C.Z. Jiang

    2009-01-01

    Ion implantation is a powerful method for fabricating nanoparticles in dielectric. For the actual application of nanoparticle composites, a careful control of nanoparticles has to be achieved. In this letter, the size, distribution and morphology of Ag nanoparticles are controlled by controlling the ion current density, ion implantation sequence and ion irradiation dose. Single layer Ag nanoparticles are formed by Ag~+ ion implantation at current density of 2.5 μA/cm~2. By Ag and Cu ions sequential implantation, the size of single layer Ag nanoparticles increases. While, by Cu and Ag ions sequential implantation, uniform Ag nanoparticles with wide distribution are formed. The morphology of Ag nanoparticles changes to hollow and sandwiched nanoparticles by Cu~+ ion irradiation to doses of 3×10~(16) and 5×10~(16) ions/cm~2. The optical absorption properties of Ag nanoparticles are also tailored by these ways.

  10. Formation and Optical Absorption of Photo-reduced Gold Nanoparticles Inside Pores of Mesoporous Silica

    Institute of Scientific and Technical Information of China (English)

    SHI Hua-Zhong; YAO Bao-Dian; ZHANG Li-De; BI Hui-Juan; CAI Wei-Ping; WU Yu-Cheng

    2000-01-01

    Mesoporous silica with gold nanoparticles inside its pores was synthesized by soaking and photo-reduction method. This new material was characterized by transmission electron microscopy, x-ray photoelectron spectroscopy and Brunauer-Emmett-Teller techniques. The results showed that gold nanoparticles were isolated from each other and uniformly dispersed inside the pores of silica, most of which were less than 4 nm in diameter. It was found that in optical absorption spectrum, surface plasma resonance peak of nanosized gold particles assumed a significant redshift (about 55nm) with respect to that predicted by Mie theory. This can be explained in terms of interface interaction (boundary coupling) between gold particles and pore walls of porous silica.

  11. High precision measurement of formaldehyde in air with differential optical absorption spectroscopy

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The formaldehyde (HCHO) measurement is described by differential optical absorption spectroscopy (DOAS) technique and the data processing method is discussed in detail, including the selection of retrieval wavelength band, the removing of interfering structures, the steps of data processing and the spectrum dealing with nonlinear method. The HCHO concentration retrieved in different wavelength bands were compared, including relative error, repeatability and detection limit. As a result, the band from 314 to 332 nm was most suitable for the retrieval of HCHO. With these methods, high measurement precision of 1.9% was obtained and the detection limit of HCHO is less than 1.5 ppb. In addition, high linear relativity 0.9999 is achieved by measuring five different concentrations of HCHO with this system.

  12. Three-photon absorption in optical parametric oscillators based on OP-GaAs

    Science.gov (United States)

    Heckl, Oliver H.; Bjork, Bryce J.; Winkler, Georg; Bryan Changala, P.; Spaun, Ben; Porat, Gil; Bui, Thinh Q.; Lee, Kevin F.; Jiang, Jie; Fermann, Martin E.; Schunemann, Peter G.; Ye, Jun

    2016-11-01

    We report on the first singly-resonant (SR), synchronously pumped optical parametric oscillator (OPO) based on orientation-patterned gallium arsenide (OP-GaAs). Together with a doubly resonant (DR) degenerate OPO based on the same OP-GaAs material, the output spectra cover 3 to 6 ${\\mu}$m within ~3 dB of relative power. The DR-OPO has the highest output power reported to date from a femtosecond, synchronously pumped OPO based on OP-GaAs. We discovered strong three photon absorption with a coefficient of 0.35 ${\\pm}$ 0.06 cm${^3}$/GW${^2}$ for our OP-GaAs sample, which limits the output power of these OPOs as mid-IR light sources. We present a detailed study of the three photon loss on the performance of both the SR and DR-OPOs, and compare them to those without this loss mechanism.

  13. Three Photon Absorption in Optical Parametric Oscillators Based on OP-GaAs

    CERN Document Server

    Heckl, Oliver H; Winkler, Georg; Changala, P Bryan; Spaun, Ben; Porat, 1 Gil; Bui, Thinh Q; Lee, Kevin F; Jiang, Jie; Fermann, Martin; Schunemann, Peter G; Ye, Jun

    2016-01-01

    We report on the first singly-resonant (SR), synchronously pumped optical parametric oscillator (OPO) based on orientation-patterned gallium arsenide (OP-GaAs). Together with a doubly resonant (DR) degenerate OPO based on the same OP-GaAs material, the output spectra cover 3 to 6 ${\\mu}$m within ~3 dB of relative power. The DR-OPO has the highest output power reported to date from a femtosecond, synchronously pumped OPO based on OP-GaAs. We discovered strong three photon absorption with a coefficient of 0.35 ${\\pm}$ 0.06 cm${^3}$/GW${^2}$ for our OP-GaAs sample, which limits the output power of these OPOs as mid-IR light sources. We present a detailed study of the three photon loss on the performance of both the SR and DR-OPOs, and compare them to those without this loss mechanism.

  14. Optical absorption enhancement in a hybrid system photonic crystal - thin substrate for photovoltaic applications.

    Science.gov (United States)

    Buencuerpo, Jeronimo; Munioz-Camuniez, Luis E; Dotor, Maria L; Postigo, Pablo A

    2012-07-02

    A hybrid approach for light trapping using photonic crystal nanostructures (nanorods, nanopillars or nanoholes) on top of an ultra thin film as a substrate is presented. The combination of a nanopatterned layer with a thin substrate shows an enhanced optical absorption than equivalent films without patterning and can compete in performance with nanostructured systems without a substrate. The designs are tested in four relevant materials: amorphous silicon (a-Si), crystalline silicon (Si), gallium arsenide (GaAs) and indium phosphide (InP). A consistent enhancement is observed for all of the materials when using a thin hybrid system (300 nm) even compared to the non patterned thin film with an anti-reflective coating (ARC). A realistic solar cell structure composed of a hybrid system with a layer of indium tin oxide (ITO) an ARC and a back metal layer is performed, showing an 18% of improvement for the nanostructured device.

  15. The Optical Absorption Coefficient of Maize Grains Investigated by Photoacoustic Spectroscopy

    Science.gov (United States)

    Rodríguez-Páez, C. L.; Carballo-Carballo, A.; Rico-Molina, R.; Hernández-Aguilar, C.; Domínguez-Pacheco, A.; Cruz-Orea, A.; Moreno-Martínez, E.

    2017-01-01

    In the maize and tortilla industry, it is important to characterize the color of maize ( Zea mays L.) grain, as it is one of the attributes that directly affect the quality of the tortillas consumed by the population. For this reason, the availability of alternative techniques for assessing and improving the quality of grain is valued. Photoacoustic spectroscopy has proven to be a useful tool for characterizing maize grain. So, the objective of the present study was to determine the optical absorption coefficient β of the maize grain used to make tortillas from two regions of Mexico: (a) Valles Altos, 2012-2013 production cycle and (b) Guasave, Sinaloa, 2013-2014 production cycle. Traditional reflectance measurements, physical characteristics of the grain and nutrient content were also calculated. The experimental results show different characteristics for maize grains.

  16. Parameterization of light absorption by components of seawater in optically complex coastal waters of the Crimea Peninsula (Black Sea).

    Science.gov (United States)

    Dmitriev, Egor V; Khomenko, Georges; Chami, Malik; Sokolov, Anton A; Churilova, Tatyana Y; Korotaev, Gennady K

    2009-03-01

    The absorption of sunlight by oceanic constituents significantly contributes to the spectral distribution of the water-leaving radiance. Here it is shown that current parameterizations of absorption coefficients do not apply to the optically complex waters of the Crimea Peninsula. Based on in situ measurements, parameterizations of phytoplankton, nonalgal, and total particulate absorption coefficients are proposed. Their performance is evaluated using a log-log regression combined with a low-pass filter and the nonlinear least-square method. Statistical significance of the estimated parameters is verified using the bootstrap method. The parameterizations are relevant for chlorophyll a concentrations ranging from 0.45 up to 2 mg/m(3).

  17. Electron spin resonance and optical absorption spectroscopic studies of Cu{sup 2+} ions in aluminium lead borate glasses

    Energy Technology Data Exchange (ETDEWEB)

    SivaRamaiah, G., E-mail: gsivaram7@yahoo.co.in [Department of Physics, Government College for Men, Kadapa 516004 (India); LakshmanaRao, J., E-mail: jlrao46@yahoo.co.in [Department of Physics, Sri Venkateswara University, Tirupati 517502 (India)

    2013-02-25

    Highlights: Black-Right-Pointing-Pointer It is for the first time to study optical absorption and EPR in these glasses. Black-Right-Pointing-Pointer The thermal properties are new and interesting in this glass system. Black-Right-Pointing-Pointer It is for the first time to report three optical bands for Cu{sup 2+} in oxide glasses. Black-Right-Pointing-Pointer The interesting optical results are due to excellent sample preparation. - Abstract: Electron Spin Resonance and optical absorption spectral studies of Cu{sup 2+} ions in 5 Al{sub 2}O{sub 3} + 75 B{sub 2}O{sub 3} + (20-z) PbO + z CuO (where z = 0.1-1.5 mol.% of CuO) glasses have been reported. The EPR spectra of all the glasses show resonance signals characteristic of Cu{sup 2+} ions at both room and low temperatures. The number of spins and Gibbs energy were calculated at different concentrations and temperatures. From the plot of the ratio of logarithmic number of spins and absolute temperature and the reciprocal of absolute temperature, the entropy and enthalpy have been evaluated. The optical absorption spectra of all the glasses exhibit three bands and these bands have been assigned to {sup 2}B{sub 1g} {yields} {sup 2}E{sub g}, {sup 2}B{sub 1g} {yields} {sup 2}B{sub 2g}, and {sup 2}B{sub 1g} {yields} {sup 2}A{sub 1g} transitions in the decreasing order of energy. It is for the first time to observe three optical absorption bands for Cu{sup 2+} ions in oxide glasses. Such type of results is due to excellent sample preparation. From the EPR and optical absorption spectroscopies data, the molecular orbital coefficients have been evaluated.

  18. Optical absorption, photoluminescence and structural analysis of CdS quantum dots in weak confinement

    Science.gov (United States)

    Mishra, Rakesh K.; Vedeshwar, A. G.; Tandon, R. P.

    2014-02-01

    The diffusion-controlled growth of CdS quantum dots (QDs) dispersed in a silicate glass matrix was investigated. It was found that the size of CdS QDs can be controlled by either heat treatment at various temperatures for a fixed duration or varying times at a constant temperature. Pastel yellow colored glass samples were obtained due to the presence of CdS petite crystals. X-ray diffraction (XRD) was used for determining the average dot size which varied from 3.8 to 30 nm. The typical quantum confinement effect was clearly observed from the blue shift measured in the optical absorption edge with decreasing dot size in the absorption spectroscopy. The band gap of CdS QDs ranges from 2.41 to 2.82 eV. Measured photoluminescence (PL) at an excitation wavelength of 350 nm showed the red shift of emission wavelength with increasing thermal treatment time and temperature in agreement with the increasing dot sizes. The half-width of PL spectra seems to indicate qualitatively the size distribution of dots and is consistent with the treatment parameters.

  19. The INTEGRAL/IBIS AGN catalogue I: X-ray absorption properties versus optical classification

    CERN Document Server

    Malizia, A; Bazzano, A; Bird, A J; Masetti, N; Panessa, F; Stephen, J B; Ubertini, P

    2012-01-01

    In this work we present the most comprehensive INTEGRAL AGN sample which lists 272 objects. Here we mainly use this sample to study the absorption properties of active galaxies, to probe new AGN classes and to test the AGN unification scheme. We find that half (48%) of the sample is absorbed while the fraction of Compton thick AGN is small (~7%). In line with our previous analysis, we have however shown that when the bias towards heavily absorbed objects which are lost if weak and at large distance is removed, as it is possible in the local Universe, the above fractions increase to become 80% and 17%. We also find that absorption is a function of source luminosity, which implies some evolution in the obscuration properties of AGN. Few peculiar classes, so far poorly studied in the hard X-ray band, have been detected and studied for the first time such as 5 XBONG, 5 type 2 QSOs and 11 LINERs. In terms of optical classification, our sample contains 57% of type 1 and 43% of type 2 AGN; this subdivision is simila...

  20. Ellipsometric analysis and optical absorption characterization of gallium phosphide nanoparticulate thin film

    Institute of Scientific and Technical Information of China (English)

    Zhang Qi-Xian; Wei Wen-Sheng; Ruan Fang-Ping

    2011-01-01

    Gallium phosphide (GaP)nanoparticulate thin films were easily fabricated by colloidal suspension deposition via GaP nanoparticles dispersed in N,N-dimethylformamide. The microstructure of the film was performed by x-ray diffraction, high resolution transmission electron microscopy and field emission scanning electron microscopy. The film was further investigated by spectroscopic ellipsometry.After the model GaP+void|Si02 was built and an effective medium approximation was adopted, the values of the refractive index n and the extinction coefficient k were calculated for the energy range of 0.75 eV-4.0 eV using the dispersion formula in DeltaPsi2 software. The absorption coefficient of the film was calculated from its k and its energy gaps were further estimated according to the Tauc equation, which were further verified by its fluorescence spectrum measurement. The structure and optical absorption properties of the nanoparticulate films are promising for their potential applications in hybrid solar cells.

  1. Optical limiting effect in a two-photon absorption dye doped solid matrix

    Science.gov (United States)

    He, Guang S.; Bhawalkar, Jayant D.; Zhao, Chan F.; Prasad, Paras N.

    1995-10-01

    We recently reported a new lasing dye, trans-4-[p-(N-ethyl-N-hydroxylethylamino)styryl]-N-methylpyridinium tetraphenylborate (ASPT), which has also been shown to possess a strong two-photon absorption (TPA) and subsequent frequency upconversion fluorescence behavior when excited with near infrared laser radiation. Based on the TPA mechanism, a highly efficient optical limiting performance has been demonstrated in a 2 cm long ASPT-doped epoxy rod pumped with 1.06 μm Q-switched laser pulses at 50-250 MW/cm2 intensity levels. The measured nonlinear absorption coefficient reached 6 cm/GW for the tested sample of dopant concentration d0=4×10-3 M/L. The molecular TPA cross section of ASPT in the epoxy matrix is estimated as σ2=2.5×10-18 cm4/GW or σ2'=4.7×10-46 cm4/photon/s, respectively. Two-photon pumped cavity lasing is also observed in an ASPT-doped polymer rod.

  2. Magnetometry with nitrogen-vacancy ensembles in diamond based on infrared absorption in a doubly resonant optical cavity

    CERN Document Server

    Dumeige, Yannick; Jacques, Vincent; Treussart, François; Roch, Jean-François; Debuisschert, Thierry; Acosta, Victor; Jarmola, Andrey; Jensen, Kasper; Kehayias, Pauli; Budker, Dmitry

    2013-01-01

    We propose to use an optical cavity to enhance the sensitivity of magnetometers relying on the detection of the spin state of high-density nitrogen-vacancy ensembles in diamond using infrared optical absorption. The role of the cavity is to obtain a contrast in the absorption-detected magnetic resonance approaching unity at room temperature. We project an increase in the photon shot-noise limited sensitivity of two orders of magnitude in comparison with a single-pass approach. Optical losses can limit the enhancement to one order of magnitude which could still enable room temperature operation. Finally, the optical cavity also allows to use smaller pumping power when it is designed to be resonant at both the pump and the signal wavelength.

  3. Assessment of the performance of a compact concentric spectrometer system for Atmospheric Differential Optical Absorption Spectroscopy

    Directory of Open Access Journals (Sweden)

    C. Whyte

    2009-12-01

    Full Text Available A breadboard demonstrator of a novel UV/VIS grating spectrometer has been developed based upon a concentric arrangement of a spherical meniscus lens, concave spherical mirror and curved diffraction grating suitable for a range of atmospheric remote sensing applications from the ground or space. The spectrometer is compact and provides high optical efficiency and performance benefits over traditional instruments. The concentric design is capable of handling high relative apertures, owing to spherical aberration and comma being near zero at all surfaces. The design also provides correction for transverse chromatic aberration and distortion, in addition to correcting for the distortion called "smile", the curvature of the slit image formed at each wavelength. These properties render this design capable of superior spectral and spatial performance with size and weight budgets significantly lower than standard configurations. This form of spectrometer design offers the potential for exceptionally compact instrument for differential optical absorption spectroscopy (DOAS applications from LEO, GEO, HAP or ground-based platforms. The breadboard demonstrator has been shown to offer high throughput and a stable Gaussian line shape with a spectral range from 300 to 450 nm at 0.5 nm resolution, suitable for a number of typical DOAS applications.

  4. Assessment of the performance of a compact concentric spectrometer system for Atmospheric Differential Optical Absorption Spectroscopy

    Directory of Open Access Journals (Sweden)

    C. Whyte

    2009-08-01

    Full Text Available A breadboard demonstrator of a novel UV/VIS grating spectrometer for atmospheric research has been developed based upon a concentric arrangement of a spherical meniscus lens, concave spherical mirror and curved diffraction grating suitable for a range of remote sensing applications from the ground or space. The spectrometer is compact and provides high optical efficiency and performance benefits over traditional instruments. The concentric design is capable of handling high relative apertures, owing to spherical aberration and coma being near zero at all surfaces. The design also provides correction for transverse chromatic aberration and distortion, in addition to correcting for the distortion called "smile", the curvature of the slit image formed at each wavelength. These properties render this design capable of superior spectral and spatial performance with size and weight budgets significantly lower than standard configurations. This form of spectrometer design offers the potential for an exceptionally compact instrument for differential optical absorption spectroscopy (DOAS applications particularly from space (LEO, GEO orbits and from HAPs or ground-based platforms. The breadboard demonstrator has been shown to offer high throughput and a stable Gaussian line shape with a spectral range from 300 to 450 nm at better than 0.5 nm resolution, suitable for a number of typical DOAS applications.

  5. A low-cost portable fibre-optic spectrometer for atmospheric absorption studies

    Directory of Open Access Journals (Sweden)

    J. Bailey

    2013-01-01

    Full Text Available A compact and portable solar absorption spectrometer based on fibre-optic Fabry–Perot technology has been built and tested. The instrument weighs only 4.2 kg and operates from 5 W of power from internal batteries. It provides spectroscopy over the range from 5980–6580 cm−1 (1.52–1.67 μm at a resolution of 0.16 cm−1. The input to the spectrometer is via single-mode optical fibre from a solar tracking system. Spectral scanning is carried out with a piezoelectrically scanned fibre Fabry–Perot tunable filter. Software has been developed to calibrate the spectra in wavelength and relative flux. The signal to noise ratio in solar spectra is about 700 for a spectrum scanned at 200 milliseconds per spectral point. The techniques used should be capable of being adapted to a range of wavelengths and to higher or lower resolutions.

  6. Electron Paramagnetic Resonance and Optical Absorption Studies on Copper Ions in Mixed Alkali Cadmium Phosphate Glasses

    Institute of Scientific and Technical Information of China (English)

    G.Giridhar; M.Rangacharyulu; R.V.S.S.N.Ravikumar; P.Sambasiva Rao

    2009-01-01

    Electron paramagnetic resonance (EPR) and optical absorption studies were carried out at room temperature on copper doped mixed alkali cadmium phosphate (LiNaCdP) glasses to understand the nature and symmetry of dopant. Three samples with varying concentrations of alkali ions have been prepared. The spin Hamiltonian parameters obtained from room temperature EPR spectra are: g||=2.437, g⊥=2.096, A||=117×10-4 cm-1, A⊥=26×10-4 cm-1 for LiNaCdP1, g||=2.441, g⊥=2.088, A||=121×10-4 cm-1, A⊥=25×10-4 cm-1 for LiNaCdP2 and g||=2.433, g⊥=2.096, A||=125×10-4 cm-1, A⊥=32×10-4 cm-1 for LiNaCdP3. These EPR results indicate that the dopant Cu2+ ion enters the glass matrix into a tetragonally elongated octahedral site. The bonding parameters evaluated by correlating optical and EPR data suggest that bonding between the central metal ion and ligands is partially covalent. The mixed alkali effect in cadmium phosphate glasses was reported.

  7. Optical absorption spectrum and electronic structure of multiferroic hexagonal YMnO3 compound

    Science.gov (United States)

    Lima, A. F.; Lalic, M. V.

    2017-02-01

    Optical absorption (OA) spectrum and electronic structure of the hexagonal YMnO3 compound have been investigated by employment of the first-principles calculations based on density functional theory. The calculations were performed upon the ferroelectric structure of the YMnO3, by testing various approximations of the exchange-correlation effects between the Mn d-electrons and considering two types of magnetic ordering of the Mn sub-lattice: (1) collinear anti-ferromagnetic order of the G-type and (2) non-collinear antiferromagnetic order that correspond to magnetic space group P63. The results demonstrate that satisfactory agreement between the theoretical and the experimental OA spectrum can be achieved only if both non-collinear anti-ferromagnetic order of the Mn spins and strong correlations between the Mn d-electrons are taken into account. The latter is found to be best described by effective Hubbard parameter Ueff = 2.55 eV. The principal features of the OA spectrum are interpreted in terms of calculated electronic structure. It is found that the most important, threshold 1.6 eV OA peak is generated by electron transitions from strongly hybridized occupied Mn d- and its neighboring in-plane O p-states to unoccupied Mn d-states. It is also concluded that the electronic gap (calculated as ∼1.1 eV) should be smaller than the optical one (∼1.6 eV).

  8. Characterization of ion-assisted induced absorption in A-Si thin-films used for multivariate optical computing

    Science.gov (United States)

    Nayak, Aditya B.; Price, James M.; Dai, Bin; Perkins, David; Chen, Ding Ding; Jones, Christopher M.

    2015-06-01

    Multivariate optical computing (MOC), an optical sensing technique for analog calculation, allows direct and robust measurement of chemical and physical properties of complex fluid samples in high-pressure/high-temperature (HP/HT) downhole environments. The core of this MOC technology is the integrated computational element (ICE), an optical element with a wavelength-dependent transmission spectrum designed to allow the detector to respond sensitively and specifically to the analytes of interest. A key differentiator of this technology is it uses all of the information present in the broadband optical spectrum to determine the proportion of the analyte present in a complex fluid mixture. The detection methodology is photometric in nature; therefore, this technology does not require a spectrometer to measure and record a spectrum or a computer to perform calculations on the recorded optical spectrum. The integrated computational element is a thin-film optical element with a specific optical response function designed for each analyte. The optical response function is achieved by fabricating alternating layers of high-index (a-Si) and low-index (SiO2) thin films onto a transparent substrate (BK7 glass) using traditional thin-film manufacturing processes (e.g., ion-assisted e-beam vacuum deposition). A proprietary software and process are used to control the thickness and material properties, including the optical constants of the materials during deposition to achieve the desired optical response function. The ion-assisted deposition is useful for controlling the densification of the film, stoichiometry, and material optical constants as well as to achieve high deposition growth rates and moisture-stable films. However, the ion-source can induce undesirable absorption in the film; and subsequently, modify the optical constants of the material during the ramp-up and stabilization period of the e-gun and ion-source, respectively. This paper characterizes the unwanted

  9. Spectral studies of ocean water with space-borne sensor SCIAMACHY using Differential Optical Absorption Spectroscopy (DOAS

    Directory of Open Access Journals (Sweden)

    M. Vountas

    2007-09-01

    Full Text Available Methods enabling the retrieval of oceanic parameter from the space borne instrumentation Scanning Imaging Absorption Spectrometer for Atmospheric ChartographY (SCIAMACHY using Differential Optical Absorption Spectroscopy (DOAS are presented. SCIAMACHY onboard ENVISAT measures back scattered solar radiation at a spectral resolution (0.2 to 1.5 nm. The DOAS method was used for the first time to fit modelled Vibrational Raman Scattering (VRS in liquid water and in situ measured phytoplankton absorption reference spectra to optical depths measured by SCIAMACHY. Spectral structures of VRS and phytoplankton absorption were clearly found in these optical depths. Both fitting approaches lead to consistent results. DOAS fits correlate with estimates of chlorophyll concentrations: low fit factors for VRS retrievals correspond to large chlorophyll concentrations and vice versa; large fit factors for phytoplankton absorption correspond with high chlorophyll concentrations and vice versa. From these results a simple retrieval technique taking advantage of both measurements is shown. First maps of global chlorophyll concentrations were compared to the corresponding MODIS measurements with very promising results. In addition, results from this study will be used to improve atmospheric trace gas DOAS-retrievals from visible wavelengths by including these oceanographic signatures.

  10. Two instruments based on differential optical absorption spectroscopy (DOAS) to measure accurate ammonia concentrations in the atmosphere

    NARCIS (Netherlands)

    Volten, H.; Bergwerff, J.B.; Haaima, M.; Lolkema, D.E.; Berkhout, A.J.C.; Hoff, G.R.; Potma, C.J.M.; Wichink Kruit, R.J.; Pul, van W.A.J.; Swart, D.P.J.

    2012-01-01

    We present two Differential Optical Absorption Spectroscopy (DOAS) instruments built at RIVM: the RIVM DOAS and the miniDOAS. Both instruments provide virtually interference-free measurements of NH3 concentrations in the atmosphere, since they measure over an open path, without suffering from inlet

  11. Electric field effects on the intersubband optical absorptions and refractive index in double-electron quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Lu Liangliang; Xie Wenfang, E-mail: lll516946435@126.com [Department of Physics, College of Physics and Electronic Engineering, Guangzhou University, Guangzhou 510006 (China)

    2011-08-01

    The linear and nonlinear optical properties such as optical absorption and refractive index change associated with intersubband transitions in a two-electron quantum dot (QD) in the presence of an external electric field have been investigated theoretically by using the perturbation method. The exchange force, which is a strictly quantum mechanical phenomenon, has also been considered. Numerical results on typical GaAs/AlGaAs materials show that an increase of the electric field decreases the oscillator strengths, the peak positions of absorption coefficients as well as the refractive index changes. Additionally, an increase of the confinement frequency (dot size) increases (decreases) the absorption coefficients but does not significantly affect the refractive index changes. It is also observed that the intensity of the illumination and the relaxation time have drastic effects on nonlinear optical properties. Finally, we note that the optical absorption coefficients and refractive index changes of two electrons are about five times higher than that of a one-electron QD.

  12. Poynting vector in transfer-matrix formalism for the calculation of light absorption profile in stratified isotropic optical media.

    Science.gov (United States)

    Deparis, Olivier

    2011-10-15

    In spite of the fact that solutions to Maxwell's equations in stratified isotropic optical media are well known, it appears that an explicit expression of the Poynting vector flux spatial evolution inside such a medium has not been derived so far. Based on exact electromagnetic field solutions in the transfer-matrix formalism, I derive such an expression and show that, due to the presence of counterpropagating waves in the medium, an additional contribution to the flux appears that exists only in optically absorbing layers and arises from the interference between these waves. Based on this theory, the concept of incremental absorption is introduced for the calculation of the light absorption profile along the stratification direction. As an illustration of this concept, absorption profiles in a Si-based thin-film tandem solar cell are predicted at typical wavelengths.

  13. Donor impurity-related intraband optical absorption in a single quantum ring: Hydrostatic pressure and intense laser field effects

    Science.gov (United States)

    Barseghyan, M. G.

    2016-10-01

    The simultaneous influence of hydrostatic pressure and intense laser field on hydrogenic donor impurity states and intraband optical absorption has been investigated in GaAs/Ga_{1-tilde{x}}Al_{tilde{x}}As quantum ring. The one-electron energy spectrum and wave functions have been found using the effective mass approximation and exact diagonalization technique. The intraband absorption coefficient is calculated for different values of the hydrostatic pressure, intense laser field parameter and different locations of hydrogenic donor impurity. The simultaneous influence of hydrostatic pressure and intense laser field shows that while the increment of the first one leads only to the blueshift of the absorption spectrum, the augmentation of the second one makes the redshift. In addition, both blueshift and redshift of the spectrum have been obtained with the changes of impurity location. The obtained theoretical results indicate good controlling means of the optical spectrum of ring-like structures by the combined influence of the considered factors.

  14. Third-order nonlinear optical properties of spin-coating films containing benzo[α]phenoxazinium: from reverse saturated to saturated absorptions

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Fei [College of Chemistry, Chemical Engineering and Material Science, Soochow University, 199 Ren' Ai Road, Suzhou 215123 (China); Fang, Yu [School of Physical Science and Technology, Soochow University, 1 Shizi Street, Suzhou 215006 (China); Sun, Ru; Guo, Xiao-Zhi [College of Chemistry, Chemical Engineering and Material Science, Soochow University, 199 Ren' Ai Road, Suzhou 215123 (China); Song, Ying-Lin [School of Physical Science and Technology, Soochow University, 1 Shizi Street, Suzhou 215006 (China); Ge, Jian-Feng, E-mail: ge_jianfeng@hotmail.com [College of Chemistry, Chemical Engineering and Material Science, Soochow University, 199 Ren' Ai Road, Suzhou 215123 (China); Jiangsu Key Laboratory of Medical Optics, Suzhou Institute of Biomedical Engineering and Technology, Chinese Academy of Sciences, Suzhou 215163 (China)

    2015-08-31

    The optical films based on poly(4-vinylphenol) and benzo[α]phenoxazinium dye with a long alkyl chain were obtained by spin-coating, and their optical properties are reported in this paper. UV–vis absorptions of the optical films showed that the absorption maxima were shifted about 40 nm by the influence of dye aggregation with increasing dye ratio. The third-order nonlinear optical properties of films were tested by Z-scan technique with a picosecond laser beam at 532 nm. The third-order nonlinear optical susceptibilities and second hyperpolarizabilities were up to 10{sup −10} and 10{sup −32} esu respectively. Meanwhile, the third-order nonlinear absorptions transformed from reverse saturated absorptions to saturated absorptions with increasing ratios of dye in doped films. The result of aggregation induced adjustable third-order nonlinear absorption can be confirmed from their TEM images. - Highlights: • Benzo[α]phenoxazinium containing optical films with poly(4-vinylphenol). • Optical property was influenced by dye aggregation. • The third-order nonlinear absorptions transformed from reverse saturated absorptions to saturated absorptions with increasing ratios of dye.

  15. Quantum-Confined and Enhanced Optical Absorption of Colloidal PbS Quantum Dots at Wavelengths with Expected Bulk Behavior.

    Science.gov (United States)

    Debellis, Doriana; Gigli, Giuseppe; Ten Brinck, Stephanie; Infante, Ivan; Giansante, Carlo

    2017-02-08

    Nowadays it is well-accepted to attribute bulk-like optical absorption properties to colloidal PbS quantum dots (QDs) at wavelengths above 400 nm. This assumption permits to describe PbS QD light absorption by using bulk optical constants and to determine QD concentration in colloidal solutions from simple spectrophotometric measurements. Here we demonstrate that PbS QDs experience the quantum confinement regime across the entire near UV-vis-NIR spectral range, therefore also between 350 and 400 nm already proposed to be sufficiently far above the band gap to suppress quantum confinement. This effect is particularly relevant for small PbS QDs (with diameter of ≤4 nm) leading to absorption coefficients that largely differ from bulk values (up to ∼40% less). As a result of the broadband quantum confinement and of the high surface-to-volume ratio peculiar of nanocrystals, suitable surface chemical modification of PbS QDs is exploited to achieve a marked, size-dependent enhancement of the absorption coefficients compared to bulk values (up to ∼250%). We provide empirical relations to determine the absorption coefficients at 400 nm of as-synthesized and ligand-exchanged PbS QDs, accounting for the broadband quantum confinement and suggesting a heuristic approach to qualitatively predict the ligand effects on the optical absorption properties of PbS QDs. Our findings go beyond formalisms derived from Maxwell Garnett effective medium theory to describe QD optical properties and permit to spectrophotometrically calculate the concentration of PbS QD solutions avoiding underestimation due to deviations from the bulk. In perspective, we envisage the use of extended π-conjugated ligands bearing electronically active substituents to enhance light-harvesting in QD solids and suggest the inadequacy of the representation of ligands at the QD surface as mere electric dipoles.

  16. Excited state assisted three-photon absorption based optical limiting in nanocrystalline Cu2Se and FeSe2

    Science.gov (United States)

    Anand, Benoy; Molli, Muralikrishna; Aditha, Saikiran; Mimani Rattan, Tanu; Siva Sankara Sai, S.; Kamisetti, Venkataramaniah

    2013-09-01

    Transition metal selenides (FeSe2 and Cu2Se) are synthesized by the hydrothermal co-reduction method. XRD results revealed the crystalline nature of their single phase and the elemental compositions are obtained using EDS. TEM images of the as-prepared samples show the formation of nanorods of 10-20 nm diameter in case of iron selenide and nanoparticles of 10-35 nm diameter in case of copper selenide. The energy bandgap values are calculated using tauc plots obtained from UV-Visible absorption spectra. The open aperture Z-scan measurements carried out using 5 ns pulses at 532 nm revealed that the samples showed excellent optical limiting behavior owing to strong nonlinear absorption (NLA). Through numerical simulations, the mechanism of NLA is found to be effective three-photon absorption which has significant contribution from excited state absorption.

  17. Optical characterization of the nematic lyotropic chromonic liquid crystals: light absorption, birefringence, and scalar order parameter.

    Science.gov (United States)

    Nastishin, Yu A; Liu, H; Schneider, T; Nazarenko, V; Vasyuta, R; Shiyanovskii, S V; Lavrentovich, O D

    2005-10-01

    We report on the optical properties of the nematic (N) phase formed by lyotropic chromonic liquid crystals (LCLCs) in well aligned planar samples. LCLCs belong to a broad class of materials formed by one-dimensional molecular self-assembly and are similar to other systems such as "living polymers" and "wormlike micelles." We study three water soluble LCLC forming materials: disodium chromoglycate, a derivative of indanthrone called Blue 27, and a derivative of perylene called Violet 20. The individual molecules have a planklike shape and assemble into rodlike aggregates that form the phase once the concentration exceeds about 0.1 M. The uniform surface alignment of the N phase is achieved by buffed polyimide layers. According to the light absorption anisotropy data, the molecular planes are on average perpendicular to the aggregate axes and thus to the nematic director. We determined the birefringence of these materials in the N and biphasic N-isotropic (I) regions and found it to be negative and significantly lower in the absolute value as compared to the birefringence of typical thermotropic low-molecular-weight nematic materials. In the absorbing materials Blue 27 and Violet 20, the wavelength dependence of birefringence is nonmonotonic because of the effect of anomalous dispersion near the absorption bands. We describe positive and negative tactoids formed as the nuclei of the new phase in the biphasic N-I region (which is wide in all three materials studied). Finally, we determined the scalar order parameter of the phase of Blue 27 and found it to be relatively high, in the range 0.72-0.79, which puts the finding into the domain of general validity of the Onsager model. However, the observed temperature dependence of the scalar order parameter points to the importance of factors not accounted for in the athermal Onsager model, such as interaggregate interactions and the temperature dependence of the aggregate length.

  18. Optical Absorption of Impurities and Defects in Semiconducting Crystals Electronic Absorption of Deep Centres and Vibrational Spectra

    CERN Document Server

    Pajot, Bernard

    2013-01-01

    This book outlines, with the help of several specific examples, the important role played by absorption spectroscopy in the investigation of deep-level centers introduced in semiconductors and insulators like diamond, silicon, germanium and gallium arsenide by high-energy irradiation, residual impurities, and defects produced during crystal growth. It also describes the crucial role played by vibrational spectroscopy to determine the atomic structure and symmetry of complexes associated with light impurities like hydrogen, carbon, nitrogen and oxygen, and as a tool for quantitative analysis of these elements in the materials.

  19. Physical and optical absorption studies of Fe3+ - ions doped lithium borate glasses containing certain alkaline earths

    Science.gov (United States)

    Bhogi, Ashok; Kumar, R. Vijaya; Kistaiah, P.

    2016-05-01

    Iron ion doped lithium borate glasses with the composition 15RO-25Li2O-59B2O3-1Fe2O3 (where R= Ca, Sr and Ba) have been prepared by the conventional melt quenching technique and characterized to investigate the physical and optical properties using XRD, density, molar volume and UV-Visible spectroscopy. The optical absorption spectra exhibit a band at around 460 nm which is assigned to 6A1g(S) → 4Eg (G) of Fe3+ ions with distorted octahedral symmetry. From ultraviolet absorption edges, the optical band gap and Urbach energies have been evaluated. The effect of alkaline earths on these properties is discussed.

  20. Metastable argon atom density in complex argon/acetylene plasmas determined by means of optical absorption and emission spectroscopy

    Science.gov (United States)

    Sushkov, Vladimir; Herrendorf, Ann-Pierra; Hippler, Rainer

    2016-10-01

    Optical emission and absorption spectroscopy has been utilized to investigate the instability of acetylene-containing dusty plasmas induced by growing nano-particles. The density of Ar(1s5) metastable atoms was derived by two methods: tunable diode laser absorption spectroscopy and with the help of the branching ratio method of emitted spectral lines. Results of the two techniques agree well with each other. The density of Ar(1s3) metastable atoms was also measured by means of optical emission spectroscopy. The observed growth instability leads to pronounced temporal variations of the metastable and other excited state densities. An analysis of optical line ratios provides evidence for a depletion of free electrons during the growth cycle but no indication for electron temperature variations.

  1. Optical absorption, Mössbauer, and FTIR spectroscopic studies of two blue bazzites

    Science.gov (United States)

    Taran, Michail N.; Dyar, M. Darby; Khomenko, Vladimir M.; Boesenberg, Joseph S.

    2017-02-01

    Two samples of bazzite, a very rare Sc analog of beryl, from Tørdal, Telemark, Norway and Kent, Central Kazakhstan were studied by electron microprobe, optical absorption, and Mössbauer spectroscopies; the latter sample was also studied by FTIR. Electron microprobe results show that the Norway bazzite is composed of two bazzites with slightly different FeO contents, viz. 5.66 and 5.43 wt%. The Kazakhstan sample consists of several varieties of bazzite displaying strong differences in iron, manganese, magnesium, and aluminum contents (in wt%): FeO from 2.02 to 6.73, MnO from 0.89 to 2.98, MgO from 0.37 to 1.86, and Al2O3 from 0.30 to 1.30. Mössbauer spectroscopy shows different degrees of iron oxidation. The Norway bazzite is completely Fe2+, while the Kazakhstan sample contains roughly equivalent Fe3+ and Fe2+ accommodated in the octahedral site. The difference in iron oxidation causes strong variations in the intensity of the broad optical absorption band around 13,850 cm-1, which is assigned to Fe2+ → Fe3+ IVCT; as a result, there are strong differences in the intensity of blue color. Dichroism (E||c ≫ E⊥c) is much stronger in the Kazakhstan sample than in the Norway one. Intensities of the electronic spin-allowed bands of [6]Fe2+ at 8900 and 10,400 cm-1 are somewhat higher in the latter than in the former. FTIR spectra of the sample from Kent show the presence of only water type II molecules with the H-H vector perpendicular to the c-axis, in contrast to more typical beryls that always show at least weak minor bands of H2O I. This result shows that trapped water molecules in structural channels of studied bazzite occupy only sites next to or between six-membered rings centered by Na atoms. Definite structure can be observed in the vicinities of ν2 and ν3 peaks. Peaks at 1621 and 3663 cm-1 are assigned to "doubly coordinated" H2O (IId), whereas maximums at 1633 and 3643 cm-1 likely represent "singly coordinated" H2O (IIs). Interpretation of the third

  2. Optical absorption coefficients in GaN/Al(Ga)N double inverse parabolic quantum wells under static external electric field

    Science.gov (United States)

    El Kadadra, A.; Fellaoui, K.; Abouelaoualim, D.; Oueriagli, A.

    2016-09-01

    In this work, we have investigated theoretically the effects of applied electric field on the linear and nonlinear optical properties in a GaN/AlxGa1-xN double inverse parabolic quantum well for different Al concentrations at the well center. Our calculations are based on the potential morphing method in the effective mass approximation. The systematic theoretical investigation contains results with all possible combinations of the involved parameters, such as quantum well width, quantum barrier width, Al concentration at each well center and magnitude of the external electric field. Our results show that the electric fields strengths, the parameter of nanostructure and incident optical intensity have a great effect on the optical characteristics of these nanostructures. Thus, the absorption coefficients which can be suitable for great performance optical modulators and multiple infrared optical device applications can be easily obtained by tuning the external electric field value and the Al concentration at the well center.

  3. A time-resolved single-pass technique for measuring optical absorption coefficients of window materials under 100 GPa shock pressures.

    Science.gov (United States)

    Li, Jun; Zhou, Xianming; Li, Jiabo

    2008-12-01

    An experimental method was developed to perform time-resolved, single-pass optical absorption measurements and to determine absorption coefficients of window materials under strong shock compression up to approximately 200 GPa. Experimental details are described of (i) a configuration to generate an in situ dynamic, bright, optical source and (ii) a sample assembly with a lithium fluoride plate to essentially eliminate heat transfer from the hot radiator into the specimen and to maintain a constant optical source within the duration of the experiment. Examples of measurements of optical absorption coefficients of several initially transparent single crystal materials at high shock pressures are presented.

  4. HST hot Jupiter Transmission Spectral Survey: A detection of Na and strong optical absorption in HAT-P-1b

    CERN Document Server

    Nikolov, N; Pont, F; Burrows, A S; Fortney, J J; Ballester, G E; Evans, T M; Huitson, C M; Wakeford, H R; Wilson, P A; Aigrain, S; Deming, D; Gibson, N P; Henry, G W; Knutson, H; Etangs, A Lecavelier des; Showman, A P; Vidal-Madjar, A; Zahnle, K

    2013-01-01

    We present an optical to near-infrared transmission spectrum of the hot Jupiter HAT-P-1b, based on HST observations, covering the spectral regime from 0.29 to 1.027{\\mu}m with STIS, which is coupled with a recent WFC3 transit (1.087 to 1.687{\\mu}m). We derive refined physical parameters of the HAT-P-1 system, including an improved orbital ephemeris. The transmission spectrum shows a strong absorption signature shortward of 0.55{\\mu}m, with a strong blueward slope into the near-ultraviolet. We detect atmospheric sodium absorption at a 3.3{\\sigma} significance level, but find no evidence for the potassium feature. The red data implies a marginally flat spectrum with a tentative absorption enhancement at wavelength longer than ~0.85{\\mu}m. The STIS and WFC3 spectra differ significantly in absolute radius level (4.3 +/- 1.6 pressure scale heights), implying strong optical absorption in the atmosphere of HAT-P-1b. The optical to near-infrared difference cannot be explained by stellar activity, as simulta- neous st...

  5. Effects of crossed electric and magnetic fields on the interband optical absorption spectra of variably spaced semiconductor superlattices

    Science.gov (United States)

    Zuleta, J. N.; Reyes-Gómez, E.

    2016-05-01

    The interband optical absorption spectra of a GaAs-Ga1-xAlxAs variably spaced semiconductor superlattice under crossed in-plane magnetic and growth-direction applied electric fields are theoretically investigated. The electronic structure, transition strengths and interband absorption coefficients are analyzed within the weak and strong magnetic-field regimes. A dramatic quenching of the absorption coefficient is observed, in the weak magnetic-field regime, as the applied electric field is increased, in good agreement with previous experimental measurements performed in a similar system under growth-direction applied electric fields. A decrease of the resonant tunneling in the superlattice is also theoretically obtained in the strong magnetic-field regime. Moreover, in this case, we found an interband absorption coefficient weakly dependent on the applied electric field. Present theoretical results suggest that an in-plane magnetic field may be used to tune the optical properties of variably spaced semiconductor superlattices, with possible future applications in solar cells and magneto-optical devices.

  6. Reverse saturable absorption studies in polymerized indole - Effect of polymerization in the phenomenal enhancement of third order optical nonlinearity

    Science.gov (United States)

    Jayakrishnan, K.; Joseph, Antony; Bhattathiripad, Jayakrishnan; Ramesan, M. T.; Chandrasekharan, K.; Siji Narendran, N. K.

    2016-04-01

    We report our results on the identification of large order enhancement in nonlinear optical coefficients of polymerized indole and its comparative study with reference to its monomer counterpart. Indole monomer shows virtually little third order effects whereas its polymerized version exhibits phenomenal increase in its third order nonlinear optical parameters such as nonlinear refractive index and nonlinear absorption. Open aperture Z-scan trace of polyindole done with Q-switched Nd:YAG laser source (532 nm, 7 ns), shows β value as high as 89 cm/GW at a beam energy of 0.83 GW/cm2. Closed aperture Z-scan done at identical energies reveals nonlinear refractive index of the order of -3.55 × 10-17 m2/W. Band gap measurement of polyindole was done with UV-Vis absorption spectra and compared with that of Indole. FTIR spectra of the monomer and polymerized versions were recorded and relevant bond formations were confirmed from the characteristic peaks. Photo luminescent spectra were investigated to know the emission features of both molecules. Beam energy (I0) versus nonlinear absorption coefficient (β) plot indicates reverse saturable type of absorption behaviour in polyindole molecules. Degenerate Four Wave Mixing (DFWM) plot of polyindole reveals quite a cubic dependence between probe and phase conjugate signal and the resulting χ(3) is comparable with Z-scan results. Optical limiting efficiency of polyindole is comparable with certain derivatives of porphyrins, phthalocyanines and graphene oxides.

  7. Noninvasive monitoring of glucose concentration using differential absorption low-coherence interferometry based on rapid scanning optical delay line

    Energy Technology Data Exchange (ETDEWEB)

    Zhou Yong; Zeng Nan; He Yonghong, E-mail: heyh@sz.tsinghua.edu.cn [Laboratory of Optical Imaging and Sensing, Graduate School at Shenzhen, Tsinghua University, Shenzhen, 518055 (China)

    2011-01-01

    A non-invasive method of detecting glucose concentration using differential absorption low-coherence interferometry (DALCI) based on rapid scanning optical delay line is presented. Two light sources, one centered within (1625 nm) a glucose absorption band, while the other outside (1310 nm) the glucose absorption band, are used in the experiment. The low-coherence interferometry (LCI) is employed to obtain the signals back-reflecting from the iris which carries the messages of material concentration in anterior chamber. Using rapid scanning optical delay line (RSOD) as the reference arm, we can detect the signals in a very short time. Therefore the glucose concentration can be monitored in real-time, which is very important for the detection in vivo. In our experiments, the cornea and aqueous humor can be treated as nearly non-scattering substance. The difference in the absorption coefficient is much larger than the difference in the scattering coefficient, so the influence of scattering can be neglected. By subtracting the algorithmic low-coherence interference signals of the two wavelengths, the absorption coefficient can be calculated which is proportional to glucose concentration. To reduce the speckle noise, a 30 variation of signals were used before the final calculation of the glucose concentration. The improvements of our experiment are also discussed in the article. The method has a potential application for noninvasive detection of glucose concentration in vivo and in real-time.

  8. Optical absorption and fluorescent behaviour of titanium ions in silicate glasses

    Indian Academy of Sciences (India)

    Manoj Kumar; Aman Uniyal; A P S Chauhan; S P Singh

    2003-04-01

    Titanium in normal melting conditions in air atmosphere present as Ti4+ ion in basic silicate glasses exhibited an ultra-violet cut-off in silicate glasses, viz. soda–magnesia–silica, soda–magnesia–lime–silica and soda–lime–silica glasses. This indicates that Ti4+ ion can be a good replacement for Ce4+ ion in producing UV-absorbing silicate glasses for commercial applications. The wavelength maxima at which the infinite absorption takes place in glasses was found to be around 310 nm against Ti-free blank glass in UV-region. The mechanism of electronic transition from O2- ligands to Ti4+ ion was suggested as L $\\rightarrow$ M charge transfer. The low energy tails of the ultra-violet cut-off were found to obey Urbach’s rule in the optical range 360–500 nm. The fluorescence spectra of these glasses were also studied and based on the radiative fluorescent properties it was suggested that the soda–lime–silica glass containing Ti4+ ion with greater emission crosssection would emit a better fluorescence than the corresponding soda–magnesia–lime–silica and soda–magnesia–silica glasses. The shift of emission wavelengths maxima towards longer wavelength in titania introduced silicate glasses was observed on replacement of MgO by CaO which may be attributed due to an increase in basicity of the glass system.

  9. Optical absorption and fluorescence properties of Er3+/Yb3+ codoped lead bismuth alumina borate glasses

    Science.gov (United States)

    Goud, K. Krishna Murthy; Reddy, M. Chandra Shekhar; Rao, B. Appa

    2014-04-01

    Lead bismuth alumina borate glasses codoped with Er3+/Yb3+ were prepared by melt quenching technique. Optical absorption, FTIR and photoluminescence spectra of these glasses have been studied. Judd-Ofelt theory has been applied to to the f ↔ f transitions for evaluating Ω2, Ω4 and Ω6 parameters. Radiative properties like branching ratio βr and the radiative life time τR have been determined on the basis of Judd-Ofelt theory. Upconversion emissions have been observed under 980nm laser excitation at room temperature. Green and red up-conversion emissions are centered at 530, 550 and 656 nm corresponding to 2H11/2→4I15/2, 4S3/2→4I15/2 and 4F9/2→4I15/2 transitions of Er3+ respectively. The results obtained are discussed quantitatively based on the energy transfer between Yb3+ and Er3+.

  10. Oxygen Absorption in Free-Standing Porous Silicon: A Structural, Optical and Kinetic Analysis

    Directory of Open Access Journals (Sweden)

    Cisneros Rodolfo

    2010-01-01

    Full Text Available Abstract Porous silicon (PSi is a nanostructured material possessing a huge surface area per unit volume. In consequence, the adsorption and diffusion of oxygen in PSi are particularly important phenomena and frequently cause significant changes in its properties. In this paper, we study the thermal oxidation of p+-type free-standing PSi fabricated by anodic electrochemical etching. These free-standing samples were characterized by nitrogen adsorption, thermogravimetry, atomic force microscopy and powder X-ray diffraction. The results show a structural phase transition from crystalline silicon to a combination of cristobalite and quartz, passing through amorphous silicon and amorphous silicon-oxide structures, when the thermal oxidation temperature increases from 400 to 900 °C. Moreover, we observe some evidence of a sinterization at 400 °C and an optimal oxygen-absorption temperature about 700 °C. Finally, the UV/Visible spectrophotometry reveals a red and a blue shift of the optical transmittance spectra for samples with oxidation temperatures lower and higher than 700 °C, respectively.

  11. EPR and optical absorption studies of Cu 2+ doped bis (glycinato) Mg (II) monohydrate single crystals

    Science.gov (United States)

    Dwivedi, Prashant; kripal, Ram

    2010-02-01

    Electron paramagnetic resonance (EPR) study of Cu 2+ doped bis (glycinato) Mg (II) monohydrate single crystals is carried out at room temperature. Copper enters the lattice substitutionally and is trapped at two magnetically inequivalent sites. The observed spectra are fitted to a spin-Hamiltonian of rhombic symmetry with the following values of the parameters: Cu 2+ (I), gx = 2.1577 ± 0.0002, gy = 2.2018 ± 0.0002, gz = 2.3259 ± 0.0002, Ax = (87 ± 2) × 10 -4 cm -1, Ay = (107 ± 2) × 10 -4 cm -1, Az = (141 ± 2) × 10 -4 cm -1; Cu 2+ (II), gx = 2.1108 ± 0.0002, gy = 2.1622 ± 0.0002, gz = 2.2971 ± 0.0002, Ax = (69 ± 2) × 10 -4 cm -1, Ay = (117 ± 2) × 10 -4 cm -1and Az = (134 ± 2) × 10 -4 cm -1. The ground state wave function of the Cu 2+ ion in this lattice is evaluated to be predominantly | x2 - y2lbond2 . The g-factor anisotropy is also calculated and compared with the experimental value. With the help of the optical absorption study, the nature of bonding in the complex is discussed.

  12. Optical absorption and near infrared emission properties of Nd 3+ ions in alkali lead tellurofluoroborate glasses

    Science.gov (United States)

    Saleem, S. A.; Jamalaiah, B. C.; Kumar, J. Suresh; Babu, A. Mohan; Moorthy, L. Rama; Jayasimhadri, M.; Jang, Kiwan; Lee, Ho Sueb; Yi, Soung Soo; Jeong, Jung Hyun

    2009-12-01

    Nd 3+ doped H 3BO 3-PbO-TeO 2-RF (R = Li, Na and K) glasses were prepared through melt quenching technique. Optical absorption and near infrared (NIR) fluorescence spectra were recorded at room temperature. The spectral intensities were analyzed in terms of the Judd-Ofelt (J-O) parameters ( Ω λ = 2, 4, 6). The covalency effect of Nd-O bond on the J-O parameters was estimated from the relative absorbance ratio (R) between 4I 9/2 → 4F 7/2 and 4I 9/2 → 4S 3/2 transitions. The effect of Nd-O covalency on the Ω4 and Ω6 intensity parameters as well as on the spontaneous emission probabilities ( AR) was discussed. Lomheim and Shazer hybrid method was applied to determine the fluorescence branching ratios ( βR) of each emission transition from the 4F 3/2 metastable level to its lower lying levels. The evaluated total radiative transition probabilities ( AT), stimulated emission cross-sections ( σe) and gain bandwidth parameters ( σe × Δ λP) were compared with the earlier reports.

  13. Exploring the Origin and Fate of the Magellanic Stream with Ultraviolet and Optical Absorption

    CERN Document Server

    Fox, Andrew J; Smoker, Jonathan V; Richter, Philipp; Savage, Blair D; Sembach, Kenneth R

    2010-01-01

    (Abridged) We present an analysis of ionization and metal enrichment in the Magellanic Stream (MS), the nearest gaseous tidal stream, using HST/STIS and FUSE ultraviolet spectroscopy of two background AGN, NGC 7469 and Mrk 335. For NGC 7469, we include optical spectroscopy from VLT/UVES. In both sightlines the MS is detected in low-ion and high-ion absorption. Toward NGC 7469, we measure a MS oxygen abundance [O/H]_MS=[OI/HI]=-1.00+/-0.05(stat)+/-0.08(syst), supporting the view that the Stream originates in the SMC rather than the LMC. We use CLOUDY to model the low-ion phase of the Stream as a photoionized plasma using the observed Si III/Si II and C III/C II ratios. Toward Mrk 335 this yields an ionization parameter log U between -3.45 and -3.15 and a gas density log (n_H/cm^-3) between -2.51 and -2.21. Toward NGC 7469 we derive sub-solar abundance ratios for [Si/O], [Fe/O], and [Al/O], indicating the presence of dust in the MS. The high-ion column densities are too large to be explained by photoionization,...

  14. Evaluating the Impact of Smoke Particle Absorption on Passive Satellite Cloud Optical Depth Retrievals

    Science.gov (United States)

    Alfaro-Contreras, R.; Zhang, J.; Reid, J. S.; Campbell, J. R.

    2013-12-01

    Absorbing aerosol particles, when lifted above clouds, can perturb top-of-atmosphere radiation radiances measured by passive satellite sensors through the absorption of reflected solar energy. This scenario, if not properly screened, impacts cloud physical retrievals, like cloud optical depth (COD), conducted using radiances/channels in the visible spectrum. We describe observations of smoke particle presence above cloud off the southwest coast of Africa, using spatially and temporally collocated Aqua Moderate Resolution Imaging Spectroradiometer (AQUA MODIS), Ozone Monitoring Instrument (OMI) and Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) measurements. Results from this study indicate that above cloud aerosol episodes happen rather frequent in the smoke outflow region during the Northern Hemisphere summer where above cloud aerosol plumes introduce a significant bias to MODIS COD retrievals in the visible spectrum. This suggests that individual COD retrievals as well as COD climatology from MODIS can be affected over the smoke outflow region by above cloud aerosol contamination and thus showing the need to account for the presence of above cloud absorbing aerosols in the MODIS visible COD retrievals.

  15. Energy distribution of precipitating electrons estimated from optical and cosmic noise absorption measurements

    Directory of Open Access Journals (Sweden)

    H. Mori

    2004-04-01

    Full Text Available This study is a statistical analysis on energy distribution of precipitating electrons, based on CNA (cosmic noise absorption data obtained from the 256-element imaging riometer in Poker Flat, Alaska (65.11° N, 147.42° W, and optical data measured with an MSP (Meridian Scanning Photometer over 79 days during the winter periods from 1996 to 1998. On the assumption that energy distributions of precipitating electrons represent Maxwellian distributions, CNA is estimated based on the observation data of auroral 427.8-nm and 630.0-nm emissions, as well as the average atmospheric model, and compared with the actual observation data. Although the observation data have a broad distribution, they show systematically larger CNA than the model estimate. CNA determination using kappa or double Maxwellian distributions, instead of Maxwellian distributions, better explains the distribution of observed CNA data. Kappa distributions represent a typical energy distribution of electrons in the plasma sheet of the magnetosphere, the source region of precipitating electrons. Pure kappas are more likely during quiet times – and quiet times are more likely than active times. This result suggests that the energy distribution of precipitating electrons reflects the energy distribution of electrons in the plasma sheet.

    Key words. Ionosphere (auroral ionosphere; particle precipitation; polar ionosphere

  16. Detection of gastrointestinal cancer by elastic scattering and absorption spectroscopies with the Los Alamos Optical Biopsy System

    Energy Technology Data Exchange (ETDEWEB)

    Mourant, J.R.; Boyer, J.; Johnson, T.M.; Lacey, J.; Bigio, I.J. [Los Alamos National Lab., NM (United States); Bohorfoush, A. [Wisconsin Medical School, Milwaukee, WI (United States). Dept. of Gastroenterology; Mellow, M. [Univ. of Oklahoma Medical School, Oklahoma City, OK (United States). Dept. of Gastroenterology

    1995-03-01

    The Los Alamos National Laboratory has continued the development of the Optical Biopsy System (OBS) for noninvasive, real-time in situ diagnosis of tissue pathologies. In proceedings of earlier SPIE conferences we reported on clinical measurements in the bladder, and we report here on recent results of clinical tests in the gastrointestinal tract. With the OBS, tissue pathologies are detected/diagnosed using spectral measurements of the elastic optical transport properties (scattering and absorption) of the tissue over a wide range of wavelengths. The use of elastic scattering as the key to optical tissue diagnostics in the OBS is based on the fact that many tissue pathologies, including a majority of cancer forms, exhibit significant architectural changes at the cellular and sub-cellular level. Since the cellular components that cause elastic scattering have dimensions typically on the order of visible to near-IR wavelengths, the elastic (Mie) scattering properties will be wavelength dependent. Thus, morphology and size changes can be expected to cause significant changes m an optical signature that is derived from the wavelength-dependence of elastic scattering. Additionally, the optical geometry of the OBS beneficially enhances its sensitivity for measuring absorption bands. The OBS employs a small fiber-optic probe that is amenable to use with any endoscope or catheter, or to direct surface examination, as well as interstitial needle insertion. Data acquistion/display time is <1 second.

  17. Optical Absorption Property and Photo-catalytic Activity of Tin Dioxide-doped Titanium Dioxides

    Institute of Scientific and Technical Information of China (English)

    LI,Huai-Xiang; XIA,Rong-Hua; JIANG,Zheng-Wei; CHEN,Shan-Shan; CHEN,De-Zhan

    2008-01-01

    SnO2-doped TiO2 films and composite oxide powders have been prepared by a sol-gel method. Ti(OC4H9)4 and SnCl4·5H2O were used as precursors and C2H5OH was used as solvent. The optical absorption measurements indicate that the composite oxide SnO2-TiO2 thin films exhibit smaller optical energy band gaps than pure TiO2 thin films and the optical energy band gap decreases as calcining temperature increases. X-ray diffraction was used to characterize the phase transition for the composite oxide powders at different calcining temperatures. Aanatase phase is the main crystal structure in both pure TiO2 and Sn0.05Ti0.95O2 samples if calcining temperature is below 500℃. The rutile phase has appeared and coexisted with the anatase crystal phase for both pure TiO2 and Sn0.05Ti0.95O2 composite oxides when calcining was at 600℃ . Transmission electron microscopy analysis shows a smaller grain size in Sn0.05Ti0.95O2 powders than TiO2 powders calcined at 600℃. When calcining temperature is 700℃ , there is only rutile phase in Sn0.05Ti0.95O2 samples, but there are still two crystal phases, anatase and rutile, coexisting in the pure TiO2 samples. Assuming the grain growth obeys the first order kinetics, Arrhenius empirical relation has been used to estimate the activation energy of 47.486 and 33.103 kJ·mol-1 for the grain growth of TiO2 and Sn0.05Ti0.95O2, respectively. The photo-catalytic activity of the powder samples has been examined by measuring the degradation of methylene blue solution under ultra-violet irradiation. Two effective factors of photo-catalytic activity namely, the content of SnO2 in the TiO2 samples and the calcining temperature, have been optimized based on the photo-catalytic degradation of methylene blue solution.

  18. Theoretical Studies on the Third-order Nonlinear Optical Properties and Two-photon Absorption of Stilbene Derivatives

    Institute of Scientific and Technical Information of China (English)

    REN, Ai-Min(任爱民); FENG, Ji-Kang(封继康); LIU, Xiao-Juan(刘孝娟)

    2004-01-01

    Different types of stilbene derivatives (D-π-D, A-π-A, D-π-A) were investigated with AM1, and specially, equilibrium geometries of symmetrical stilbene derivatives (D-π-D) were studied using of PM3. With the same method INDO/CI, the UV-vis spectra were explored and the position and strength of the two-photon absorption were predicated by Sum-Over-States expression. The relationships of the structures, spectra and nonlinear optical properties have been examined. The influence of various substituents on two photon absorption cross-sections was discussed micromechanically.

  19. Optical imaging of absorption and distribution of RITC-SiO2 nanoparticles after oral administration

    Directory of Open Access Journals (Sweden)

    Lee CM

    2014-12-01

    Full Text Available Chang-Moon Lee,1 Tai Kyoung Lee,2–5 Dae-Ik Kim,1,6 Yu-Ri Kim,7 Meyoung-Kon Kim,7 Hwan-Jeong Jeong,2–5 Myung-Hee Sohn,2–5 Seok Tae Lim2–5 1Department of Biomedical Engineering, Chonnam National University, Yeosu, Jeollanam-Do, Republic of Korea; 2Department of Nuclear Medicine, Chonbuk National University Medical School and Hospital, Jeonju, Jeollabuk-Do, Republic of Korea; 3Cyclotron Research Center, Chonbuk National University Medical School and Hospital, Jeonju, Jeollabuk-Do, Republic of Korea; 4Biomedical Research Institute, Chonbuk National University Medical School and Hospital, Jeonju, Jeollabuk-Do, Republic of Korea; 5Molecular Imaging and Therapeutic Medicine Research Center, Chonbuk National University Medical School and Hospital, Jeonju, Jeollabuk-Do, Republic of Korea; 6School of Electrical, Electronic Communication, and Computer Engineering, Chonnam National University, Yeosu, Jeollanam-Do, Republic of Korea; 7Department of Biochemistry and Molecular Biology, Korea University Medical School and College, Seounbuk-Gu, Seoul, Republic of Korea Purpose: In this study, we investigated the absorption and distribution of rhodamine B isothiocyanate (RITC-incorporated silica oxide nanoparticles(SiNPs (RITC-SiNPs after oral exposure, by conducting optical imaging, with a focus on tracking the movement of RITC-SiNPs of different particle size and surface charge. Methods: RITC-SiNPs (20 or 100 nm; positively or negatively charged were used to avoid the dissociation of a fluorescent dye from nanoparticles via spontaneous or enzyme-catalyzed reactions in vivo. The changes in the nanoparticle sizes and shapes were investigated in an HCl solution for 6 hours. RITC-SiNPs were orally administered to healthy nude mice at a dose of 100 mg/kg. Optical imaging studies were performed at 2, 4, and 6 hours after oral administration. The mice were sacrificed at 2, 4, 6, and 10 hours post-administration, and ex vivo imaging studies were performed

  20. Effects of ternary mixed crystal and size on intersubband optical absorption in wurtzite InGaN/GaN core-shell nanowires

    Science.gov (United States)

    Liu, W. H.; Yang, S.; Feng, H. M.; Yang, L.; Qu, Y.; Ban, S. L.

    2015-07-01

    Based on the density matrix approach, the effects of ternary mixed crystal and size on intersubband optical absorption coefficients in InxGa1-xN/GaN core-shell nanowires (CSNWs) are investigated. The results show that the optical absorption can be modulated by In component x and the size of CSNWs, since the variation of electron states in these systems. It is found that photonic frequencies of resonant absorption and the absorption coefficient increase obviously when x increases or the radius of InGaN core reduces, while the half-width of the coefficient decreases as its peak becomes higher and sharper. A saturation phenomenon of optical absorption is also found when the incident light intensity exceeds a certain value. The theoretical results are expected to be helpful to develop CSNW optic devices.

  1. Gradient-based quantitative reconstruction of optical absorption and scattering coefficients in ultrasound-modulated optical tomography: first harmonic measurement type

    CERN Document Server

    Powell, Samuel; Leung, Terence S

    2014-01-01

    Ultrasound-modulated optical tomography is an emerging biomedical imaging modality which uses the spatially localised acoustically-driven modulation of coherent light as a probe of the structure and optical properties of biological tissues. In this work we pose the inverse problem of simultaneously recovering the optical absorption and scattering coefficients in a given domain from measurement of the power-spectral density of the optical field modulated to the acoustic frequency. As part of this exposition we provide an overview of forward modelling techniques, and derive an efficient linearised diffusion-style model. To ameliorate the computational burden and memory requirements of a traditional Newton-based optimisation approach, we develop an adjoint-assisted gradient based method. We validate our reconstruction in two- and three-dimensions using simulated measurements with 1% proportional Gaussian noise, and demonstrate the successful recovery of the parameters to within +/-5% of their true values when th...

  2. Structure-Related Optical Fingerprints in the Absorption Spectra of Colloidal Quantum Dots: Random Alloy vs. Core/Shell Systems

    CERN Document Server

    Mourad, Daniel

    2016-01-01

    We argue that the experimentally easily accessible optical absorption spectrum can often be used to distinguish between a random alloy phase and a stoichiometrically equivalent core/shell realization of ensembles of monodisperse colloidal semiconductor quantum dots without the need for more advanced structural characterization tools. Our proof-of-concept is performed by conceptually straightforward exact-disorder tight-binding calculations. The underlying stochastical tight-binding scheme only parametrizes bulk band structure properties and does not employ additional free parameters to calculate the optical absorption spectrum, which is an easily accessible experimental property. The method is applied to selected realizations of type-I Cd(Se,S) and type-II (Zn,Cd)(Se,S) alloyed quantum dots with an underlying zincblende crystal structure and the corresponding core/shell counterparts.

  3. Optical absorption properties of electron bubbles and experiments on monitoring individual electron bubbles in liquid helium

    Science.gov (United States)

    Guo, Wei

    When a free electron is injected into liquid helium, it forms a microscopic bubble essentially free of helium atoms, which is referred to as an electron bubble. It represents a fine example of a quantum-mechanical particle confined in a potential well. In this dissertation, we describe our studies on bubble properties, especially the optical absorption properties of ground state electron bubbles and experiments on imaging individual electron bubbles in liquid helium. We studied the effect of zero-point and thermal fluctuations on the shape of ground state electron bubbles in liquid helium. The results are used to determine the line shape for the 1S to 1P optical transition. The calculated line shape is in very good agreement with the experimental measurements of Grimes and Adams. For 1S to 2P transition, the obtained transition line width agrees well with the measured data of Zipfel over a range of pressure up to 15 bars. Fluctuations in the bubble shape also make other "unallowed" transitions possible. The transition cross-sections from the 1S state to the 1D and 2D states are calculated with magnitude approximately two orders smaller than that of the 1S to 1P and 2P transitions. In our electron bubble imaging experiments, a planar ultrasonic transducer was used to generate strong sound wave pulse in liquid helium. The sound pulse passed through the liquid so as to produce a transient negative pressure over a large volume (˜ 1 cm3). An electron bubble that was passed by the sound pulse exploded for a fraction of a microsecond and grew to have a radius of around 10 microns. While the bubble had this large size it was illuminated with a flash lamp and its position was recorded. In this way, we can determine its position. Through the application of a series of sound pulses, we can then take images along the track of individual electrons. The motion of individual electron bubbles has been successfully monitored. Interesting bubble tracks that may relate to electrons

  4. Protein dynamics in an intermediate state of myoglobin: optical absorption, resonance Raman spectroscopy, and x-ray structure analysis.

    OpenAIRE

    N. Engler; Ostermann, A; Gassmann, A.; Lamb, D C; Prusakov, V E; J. Schott; Schweitzer-Stenner, R; Parak, F. G.

    2000-01-01

    A metastable state of myoglobin is produced by reduction of metmyoglobin at low temperatures. This is done either by irradiation with x-rays at 80 K or by electron transfer from photoexcited tris(2, 2'-bipyridine)-ruthenium(II) at 20 K. At temperatures above 150 K, the conformational transition toward the equilibrium deoxymyoglobin is observed. X-ray crystallography, Raman spectroscopy, and temperature-dependent optical absorption spectroscopy show that the metastable state has a six-ligated ...

  5. Electrical conductivity, ionic conductivity, optical absorption, and gas separation properties of ionically conductive polymer membranes embedded with Si microwire arrays

    OpenAIRE

    Spurgeon, Joshua M.; Walter, Michael G.; Zhou, Junfeng; Kohl, Paul A.; Lewis, Nathan S.

    2011-01-01

    The optical absorption, ionic conductivity, electronic conductivity, and gas separation properties have been evaluated for flexible composite films of ionically conductive polymers that contain partially embedded arrays of ordered, crystalline, p-type Si microwires. The cation exchange ionomer Nafion, and a recently developed anion exchange ionomer, poly(arylene ether sulfone) that contains quaternary ammonium groups (QAPSF), produced composite microwire array/ionomer membrane films that were...

  6. Annealing-induced optical and sub-band-gap absorption parameters of Sn-doped CdSe thin films

    Science.gov (United States)

    Kaur, Jagdish; Tripathi, S. K.

    2016-01-01

    Thin films of Sn-doped CdSe were prepared by thermal evaporation onto glass substrates in an argon gas atmosphere and annealed at different temperatures. Structural evaluation of the films was carried out using X-ray diffraction and their stoichiometry studied by energy-dispersive X-ray analysis. The films exhibit a preferred orientation along the hexagonal direction of CdSe. The optical transmittance of the films shows a red shift of the absorption edge with annealing. The fundamental absorption edge corresponds to a direct energy gap with a temperature coefficient of 3.34 × 10-3 eV K-1. The refractive index, optical conductivity and real and imaginary parts of the dielectric constants were found to increase after annealing. The sub-band gap absorption coefficient was evaluated using the constant photocurrent method. It varies exponentially with photon energy. The Urbach energy, the density of defect states, and the steepness of the density of localized states were evaluated from the sub-band-gap absorption.

  7. Mapping the Optical Absorption of a Substrate-Transferred Crystalline AlGaAs Coating at 1.5um

    CERN Document Server

    Steinlechner, Jessica; Bell, Angus; Cole, Garrett; Hough, Jim; Penn, Steven; Rowan, Sheila; Steinlechner, Sebastian

    2014-01-01

    The sensitivity of 2nd and 3rd generations of interferometric gravitational wave detectors will be limited by thermal noise of the test-mass mirrors and highly reflective coatings. Recently developed crystalline coatings show a promising thermal noise reduction compared to presently used amorphous coatings. However, stringent requirements apply to the optical properties of the coatings as well. We have mapped the optical absorption of a crystalline AlGaAs coating which is optimized for high reflectivity for a wavelength of 1064nm. The absorption was measured at 1550nm where the coating stack transmits approximately 70% of the laser light. The measured absorption was lower than (30.2 +/- 11.1)ppm which is equivalent to (3.6 +/- 1.3)ppm for a coating stack that is highly reflective at 1530nm. While this is a very promising low absorption result for alternative low--loss coating materials, further work will be necessary to reach the requirements of <1ppm for future gravitational wave detectors.

  8. Understanding the shrinkage of optical absorption edges of nanostructured Cd-Zn sulphide films for photothermal applications

    Science.gov (United States)

    Hossain, Md. Sohrab; Kabir, Humayun; Rahman, M. Mahbubur; Hasan, Kamrul; Bashar, Muhammad Shahriar; Rahman, Mashudur; Gafur, Md. Abdul; Islam, Shariful; Amri, Amun; Jiang, Zhong-Tao; Altarawneh, Mohammednoor; Dlugogorski, Bogdan Z.

    2017-01-01

    In this article Cd-Zn sulphide thin films deposited onto soda lime glass substrates via chemical bath deposition (CBD) technique were investigated for photovoltaic applications. The synthesized films were investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM), and ultraviolet visible (UV-vis) spectroscopic methodologies. A higher degree of crystallinity of the films was attained with the increase of film thicknesses. SEM micrographs exhibited a partial crystalline structure with a particulate appearance surrounded by the amorphous grain boundaries. The optical absorbance and absorption coefficient of the films were also enhanced significantly with the increase in film thicknesses. Optical band-gap analysis indicated a monotonic decrease in direct and indirect band-gaps with the increase of thicknesses of the films. The presence of direct and indirect transitional energies due to the exponential falling edges of the absorption curves may either be due to the lack of long-range order or to the existence of defects in the films. The declination of the optical absorption edges was also confirmed via Urbach energy and steepness parameters studies.

  9. Optical absorption and small-polaron hopping in oxygen deficient and lithium-ion-intercalated amorphous titanium oxide films

    Science.gov (United States)

    Triana, C. A.; Granqvist, C. G.; Niklasson, G. A.

    2016-01-01

    Optical absorption in oxygen-deficient and Li+-ion inserted titanium oxide films was studied in the framework of small-polaron hopping. Non-stoichiometric TiOy films with 1.68 ≤ y ≤ 2.00 were deposited by reactive DC magnetron sputtering and were subjected to electrochemical intercalation of Li+-ions and charge-balancing electrons to obtain LixTiOy films with 0.12 ≤ x ≤ 0.34. Dispersion analysis was applied to calculate the complex dielectric function ɛ(ℏω) ≡ ɛ1(ℏω) + i ɛ2(ℏω) from numerical inversion of optical transmittance and reflectance spectra; a superposition of Tauc-Lorentz and Lorentz oscillator models was used for this purpose. Data on ɛ2(ℏω) were employed to calculate the optical conductivity and fit this property to a small-polaron model for disordered systems with strong electron-phonon interaction and involving transitions near the Fermi level. The introduction of oxygen vacancies and/or Li+ insertion yielded band gap widening by ˜0.20-0.35 eV, and both processes induced similar low-energy optical absorption. The small-polaron-based analysis indicated increases in the Fermi level by ˜0.15-0.3 eV for sub-stoichiometric and/or Li+-inserted films. This suggests the existence of polaronic Ti3+ states in the lower part of the conduction band arising from transfer of electrons from oxygen vacancies and/or inserted Li+ species. The present article is a sequel to an earlier paper on oxygen-deficient and/or Li+-inserted amorphous WOy thin films and forms part of a comprehensive investigation of optical absorption in amorphous transition metal oxides with different valence states of the metallic ions.

  10. Excitations, optical absorption spectra, and optical excitonic gaps of heterofullerenes: I. C60, C59N+ and C48N12

    Energy Technology Data Exchange (ETDEWEB)

    Xie, R; Bryant, G W; Sun, G; C.Nicklaus, M; Heringer, D; Frauenheim, T; Manaa, M R; Smith, Jr., V H; Araki, Y; Ito, O

    2003-10-02

    Low-energy excitations and optical absorption spectrum of C{sub 60} are computed by using time-dependent (TD) Hartree-Fock (HF), TD-density functional theory (TD-DFT), TD-DFT-based tight-binding (TD-DFT-TB) and a semiempirical ZINDO method. A detailed comparison of experiment and theory for the excitation energies, optical gap and absorption spectrum of C{sub 60} is presented. It is found that electron correlations and collective effects of exciton pairs play important roles in assigning accurately the spectral features of C{sub 60} and the TD-DFT method with non-hybrid functionals or a local spin density approximation leads to more accurate excitation energies than with hybrid functionals. The level of agreement between theory and experiment for C{sub 60} justifies similar calculations of the excitations and optical absorption spectrum of a monomeric azafullerene cation C{sub 59}N{sup +} exhibits distinguishing spectral features different from C{sub 60}: (1) the first singlet is dipole-allowed and the optical gap is redshifted by 1.44 eV; (2) several weaker absorption maxima occur in the visible region; (3) the transient triplet-triplet absorption at 1.60 eV (775 nm) is much broader and the decay of the triplet state is much faster. The calculated spectra of C{sub 59}N{sup +} characterize and explain well our measured ultraviolet-visible (UV-vis) and transient absorption spectra of the carborane anion salt [C{sub 59}N][Ag(CB{sub 11}H{sub 6}Cl{sub 6}){sub 2}]. For the most stable isomer of C{sub 48}N{sub 12}, we predict that the first singlet is dipole-allowed, the optical gap is redshifted by 1.22 eV relative to that of C{sub 60}, and optical absorption maxima occur at 585, 528, 443, 363, 340, 314 and 303 nm. We point out that the characterization of the UV-vis and transient absorption spectra of C{sub 48}N{sub 12} isomers is helpful in distinguishing the isomer structures required for applications in molecular electronics. For C{sub 59}N{sup +} and C{sub 48}N

  11. THEORY OF PHONON-ASSISTED MULTIMAGNON OPTICAL-ABSORPTION AND BIMAGNON STATES IN QUANTUM ANTIFERROMAGNETS

    NARCIS (Netherlands)

    Lorenzana, J.; Sawatzky, G.A

    1995-01-01

    We calculate the effective charge for multimagnon infrared absorption assisted by phonons in a perovskitelike antiferromagnet and we compute the spectra for two-magnon absorption using interacting spin-wave theory. The full set of equations for the interacting two-magnon problem is presented in the

  12. An organic dye-polymer (phenol red-poly (vinyl alcohol)) composite architecture towards tunable -optical and -saturable absorption characteristics

    Science.gov (United States)

    Sreedhar, Sreeja; Illyaskutty, Navas; Sreedhanya, S.; Philip, Reji; Muneera, C. I.

    2016-05-01

    Herein, we demonstrate that blending an organic dye (guest/filler), with a vinyl polymer (host template), is an inexpensive and simple approach for the fabrication of multifunctional photonic materials which could display an enhancement in the desirable properties of the constituent materials and, at the same time provide novel synergistic properties for the guest-host system. A new guest-host nanocomposite system comprising Phenol Red dye and poly (vinyl alcohol) as guest and host template, respectively, which exhibits tunable optical characteristics and saturable absorption behavior, is introduced. The dependence of local electronic environment provided by the polymer template and the interactions of the polymer molecules with the encapsulated guest molecules on the observed optical/nonlinear absorption behavior is discussed. An understanding of the tunability of the optical/ photophysical processes, with respect to the filler content, as discussed herein could help in the design of improved optical materials for several photonic device applications like organic light emitting diodes and saturable absorbers.

  13. Photoluminescence and Optical Absorption of Pure NanocrystallineTiO2 Anatase and Rutile at Room Temperature

    Directory of Open Access Journals (Sweden)

    L. Kernazhitsky

    2013-10-01

    Full Text Available The optical absorption and photoluminescence of nanocrystalline TiO2 samples of anatase and rutile were investigated at room temperature. Nanocrystalline TiO2 samples were synthesized in the form of pure anatase or rutile and studied by X-ray diffraction, X-ray fluorescence, Raman spectroscopy, optical absorption and photoluminescence (PL. PL was studied at room temperature when excited by intense UV (3.68 eV by a nitrogen laser. For the first time for nanocrystalline TiO2 a features in the high-resolution PL spectra, including the exciton band and interband transitions were registered. It is concluded that the processes of absorption and emission of light near the edge of the forbidden zone occur with the participation of the same electronic transitions. PL bands, including the peaks at 2.71-2.81 eV in the anatase and rutile arise due to exciton recombination in the TiO2 lattice oxygen vacancies. The exciton peak at 2.91 eV is attributed to the recombination of self-trapped excitons in anatase or to the free exciton in rutile, respectively. PL bands within 3.0-3.3 eV attributed to indirect and direct allowed transitions due to electron-hole recombination. PL bands at 3.03 eV and 3.26 eV, attributed to the emission of free excitons near the fundamental absorption edge of rutile and anatase, respectively. The influence of TiO2 crystal structure and calcination temperature of the samples on the PL spectra and optical absorbtion is discussed.

  14. A theoretical analysis of the optical absorption properties in one-dimensional InAs/GaAs quantum dot superlattices

    Energy Technology Data Exchange (ETDEWEB)

    Kotani, Teruhisa, E-mail: kotani.teruhisa@sharp.co.jp [Advanced Technology Research Laboratories, Sharp Corporation, 2613-1 Ichinomoto-cho, Tenri, Nara 632-8567 (Japan); Institute for Nanoelectronics, Technische Universität München, Arcisstr. 21, 80333 Munich (Germany); Birner, Stefan [Institute for Nanoelectronics, Technische Universität München, Arcisstr. 21, 80333 Munich (Germany); Walter Schottky Institute, Technische Universität München, Am Coulombwall 4, 85748 Garching (Germany); Lugli, Paolo [Institute for Nanoelectronics, Technische Universität München, Arcisstr. 21, 80333 Munich (Germany); Hamaguchi, Chihiro [Advanced Technology Research Laboratories, Sharp Corporation, 2613-1 Ichinomoto-cho, Tenri, Nara 632-8567 (Japan)

    2014-04-14

    We present theoretical investigations of miniband structures and optical properties of InAs/GaAs one-dimensional quantum dot superlattices (1D-QDSLs). The calculation is based on the multi-band k·p theory, including the conduction and valence band mixing effects, the strain effect, and the piezoelectric effect; all three effects have periodic boundary conditions. We find that both the electronic and optical properties of the 1D-QDSLs show unique states which are different from those of well known single quantum dots (QDs) or quantum wires. We predict that the optical absorption spectra of the 1D-QDSLs strongly depend on the inter-dot spacing because of the inter-dot carrier coupling and changing strain states, which strongly influence the conduction and valence band potentials. The inter-miniband transitions form the absorption bands. Those absorption bands can be tuned from almost continuous (closely stacked QD case) to spike-like shape (almost isolated QD case) by changing the inter-dot spacing. The polarization of the lowest absorption peak for the 1D-QDSLs changes from being parallel to the stacking direction to being perpendicular to the stacking direction as the inter-dot spacing increases. In the case of closely stacked QDs, in-plane anisotropy, especially [110] and [11{sup ¯}0] directions also depend on the inter-dot spacing. Our findings and predictions will provide an additional degree of freedom for the design of QD-based optoelectronic devices.

  15. Optical absorption and DFT calculations in L-aspartic acid anhydrous crystals: Charge carrier effective masses point to semiconducting behavior

    Science.gov (United States)

    Silva, A. M.; Silva, B. P.; Sales, F. A. M.; Freire, V. N.; Moreira, E.; Fulco, U. L.; Albuquerque, E. L.; Maia, F. F., Jr.; Caetano, E. W. S.

    2012-11-01

    Density functional theory (DFT) computations within the local-density approximation and generalized gradient approximation in pure form and with dispersion correction (GGA+D) were carried out to investigate the structural, electronic, and optical properties of L-aspartic acid anhydrous crystals. The electronic (band structure and density of states) and optical absorption properties were used to interpret the light absorption measurements we have performed in L-aspartic acid anhydrous crystalline powder at room temperature. We show the important role of the layered spatial disposition of L-aspartic acid molecules in anhydrous L-aspartic crystals to explain the observed electronic and optical properties. There is good agreement between the GGA+D calculated and experimental lattice parameters, with (Δa, Δb, Δc) deviations of (0.029,-0.023,-0.024) (units in Å). Mulliken [J. Chem. Phys.JCPSA60021-960610.1063/1.1740588 23, 1833 (1955)] and Hirshfeld [Theor. Chim. ActaTCHAAM0040-574410.1007/BF00549096 44, 129 (1977)] population analyses were also performed to assess the degree of charge polarization in the zwitterion state of the L-aspartic acid molecules in the DFT converged crystal. The lowest-energy optical absorption peaks related to transitions between the top of the valence band and the bottom of the conduction band involve O 2p valence states and C 1p and O 2p conduction states, with the carboxyl and COOH lateral chain group contributing significantly to the energy band gap. Among the calculated band gaps, the lowest GGA+D (4.49-eV) gap is smaller than the experimental estimate of 5.02 eV, as obtained by optical absorption. Such a wide-band-gap energy together with the small carrier effective masses estimated from band curvatures allows us to suggest that an L-aspartic acid anhydrous crystal can behave as a wide-gap semiconductor. A comparison of effective masses among directions parallel and perpendicular to the L-aspartic molecules layers reveals that charge

  16. Direction dependence of the magneto-optical absorption in nanowires with Rashba interaction

    Energy Technology Data Exchange (ETDEWEB)

    Sakr, M.R., E-mail: msakr@alexu.edu.eg

    2016-09-16

    We study the directional dependence of the absorption spectrum of ballistic nanowires in the presence of gate-controlled Rashba spin–orbit interaction and an in-plane magnetic field. In the weak Rashba regime, our analytical and numerical results show that the absorption peaks associated with the first and third intersubband transitions exhibit frequency shifts and strong amplitude modulations as the direction of the magnetic field changes. If the field is parallel to the nanowire axis, these peaks disappear and the resonance frequencies of the whole absorption spectrum are given merely in terms of the Zeeman splitting and the energy scale characterizing the confinement potential. The second transition has an absorption peak that suffers an opposite frequency shift with amplitude that is largely direction independent. The amplitude modulation and frequency shift of the absorption spectrum is periodic in the angle that the magnetic field makes with the nanowire axis. - Highlights: • Absorption spectrum of the nanowire is calculated in the weak Rashba regime. • First and third absorption peaks show amplitude and frequency modulation. • They disappear if the magnetic field is along the wire axis, forbidden transitions. • The second transition peak shows frequency shift with minor amplitude modulation. • The frequency and amplitude modulations are periodic in the direction of the field.

  17. Effect of heat treatment on absorption and fluorescence properties of PbS-doped silica optical fibre

    Science.gov (United States)

    Qin, Fu; Dong, Yanhua; Wen, Jianxiang; Pang, Fufei; Luo, Yanhua; Peng, Gang-Ding; Chen, Zhenyi; Wang, Tingyun

    2017-02-01

    The effect of heat treatment on the optical properties of a PbS-doped silica optical fibre was investigated. The experimental results showed that the absorption peak of the fibre red shifted from 1032 to 1133 nm when the heat treatment temperatures were carried out at 900, 950, 1000, and 1100 °C for 1 h, respectively. At the same time, when the heat treatment at 900 °C was carried out for 2, 5, 10, 20, and 40 h, the absorption spectra of the fibre showed a red shift from 1074 to 1143 nm. In addition, the intensity of the absorption peak increased from 0.258 to 1.384 dB/m and the full width at half maximum (FWHM) became narrower (from 130 to 50 nm) as the heat treatment proceeded. Moreover, the photoluminescence (PL) intensity in the wavelength range of 1100-1500 nm decreased with an increase in the heat treatment temperature. The theoretical analysis, using an effective mass method, showed that the effective band gap energy and average size of the lead sulphide (PbS) quantum dots (QDs) in the silica fibre core varied from 1.199 to 1.083 eV and from 4.28 to 4.81 nm, respectively. The results indicate that the size of the PbS QDs present in the silica fibre core could be controlled by a proper heat treatment, which is of great interest in optical fibre amplifiers and other fibre optic devices.

  18. Shock tube measurements of the optical absorption of triatomic carbon, C3

    Science.gov (United States)

    Jones, J. J.

    1977-01-01

    The spectral absorption of C3 has been measured in a shock tube using a test gas mixture of acetylene diluted with argon. The absorption of a pulsed xenon light source was measured by means of eight photomultiplier channels to a spectrograph and an accompanying drum camera. The postshock test gas temperature and pressure were varied over the range 3300-4300 K and 0.36 to 2.13 atmospheres, respectively. The results showed appreciable absorption from C3 for the wavelength range 300 to 540 nanometers. The computed electronic oscillator strength varied from 0.12 to 0.06 as a function of temperature.

  19. Quantification and parametrization of non-linearity effects by higher-order sensitivity terms in scattered light differential optical absorption spectroscopy

    OpenAIRE

    J. Puķīte; T. Wagner

    2016-01-01

    We address the application of differential optical absorption spectroscopy (DOAS) of scattered light observations in the presence of strong absorbers (in particular ozone), for which the absorption optical depth is a non-linear function of the trace gas concentration. This is the case because Beer–Lambert law generally does not hold for scattered light measurements due to many light paths contributing to the measurement. While in many cases linear approximation can be made, ...

  20. Using Observations of Deep Convective Systems to Constrain Atmospheric Column Absorption of Solar Radiation in the Optically Thick Limit

    Science.gov (United States)

    Dong, Xiquan; Wielicki, Bruce A.; Xi, Baike; Hu, Yongxiang; Mace, Gerald G.; Benson, Sally; Rose, Fred; Kato, Seiji; Charlock, Thomas; Minnis, Patrick

    2008-01-01

    Atmospheric column absorption of solar radiation A(sub col) is a fundamental part of the Earth's energy cycle but is an extremely difficult quantity to measure directly. To investigate A(sub col), we have collocated satellite-surface observations for the optically thick Deep Convective Systems (DCS) at the Department of Energy Atmosphere Radiation Measurement (ARM) Tropical Western Pacific (TWP) and Southern Great Plains (SGP) sites during the period of March 2000 December 2004. The surface data were averaged over a 2-h interval centered at the time of the satellite overpass, and the satellite data were averaged within a 1 deg X 1 deg area centered on the ARM sites. In the DCS, cloud particle size is important for top-of-atmosphere (TOA) albedo and A(sub col) although the surface absorption is independent of cloud particle size. In this study, we find that the A(sub col) in the tropics is approximately 0.011 more than that in the middle latitudes. This difference, however, disappears, i.e., the A(sub col) values at both regions converge to the same value (approximately 0.27 of the total incoming solar radiation) in the optically thick limit (tau greater than 80). Comparing the observations with the NASA Langley modified Fu_Liou 2-stream radiative transfer model for optically thick cases, the difference between observed and model-calculated surface absorption, on average, is less than 0.01, but the model-calculated TOA albedo and A(sub col) differ by 0.01 to 0.04, depending primarily on the cloud particle size observation used. The model versus observation discrepancies found are smaller than many previous studies and are just within the estimated error bounds. We did not find evidence for a large cloud absorption anomaly for the optically thick limit of extensive ice cloud layers. A more modest cloud absorption difference of 0.01 to 0.04 cannot yet be ruled out. The remaining uncertainty could be reduced with additional cases, and by reducing the current

  1. On the intrinsic optical absorptions by tetrathiafulvalene radical cations and isomers

    DEFF Research Database (Denmark)

    Kirketerp, Maj-Britt Suhr; Leal, Leonardo Andrés Espinosa; Varsano, Daniele;

    2011-01-01

    Gas-phase action spectroscopy shows unambiguously that the low-energy absorptions by tetramethylthiotetrathiafulvalene and tetrathianaphthalene cations in solution phase are due to monomers and not π-dimers....

  2. Optical registration of transformer oil absorption processes in electrical pressboard nano-capillaries

    Science.gov (United States)

    Rogalski, Przemysław

    2016-12-01

    The paper presents designed and built measurement system for measuring electrical pressboard oil absorption speed. During measurements the test bench allows for automatic record of oil level, time, temperature, humidity and atmospheric pressure. Measurements of Nytro Taurus oil, produced by Nynas company, absorption by pressboard, produced by Weidman company, were made. It has been observed, that the absorption of oil takes place in three stages, duration of which are respectively τ1≍0,66 h, τ2≍109 h and τ3≍524 h. It was established that the time required to complete the oil absorption process takes more than 46 days. This means that at least as much time should take oil impregnation process of pressboard samples made for electrical measurements.

  3. Magneto-optical absorption in semiconducting spherical quantum dots: Influence of the dot-size, confining potential, and magnetic field

    Energy Technology Data Exchange (ETDEWEB)

    Kushwaha, Manvir S. [Department of Physics and Astronomy, Rice University, P.O. Box 1892, Houston, TX 77251 (United States)

    2014-12-15

    Semiconducting quantum dots – more fancifully dubbed artificial atoms – are quasi-zero dimensional, tiny, man-made systems with charge carriers completely confined in all three dimensions. The scientific quest behind the synthesis of quantum dots is to create and control future electronic and optical nanostructures engineered through tailoring size, shape, and composition. The complete confinement – or the lack of any degree of freedom for the electrons (and/or holes) – in quantum dots limits the exploration of spatially localized elementary excitations such as plasmons to direct rather than reciprocal space. Here we embark on a thorough investigation of the magneto-optical absorption in semiconducting spherical quantum dots characterized by a confining harmonic potential and an applied magnetic field in the symmetric gauge. This is done within the framework of Bohm-Pines’ random-phase approximation that enables us to derive and discuss the full Dyson equation that takes proper account of the Coulomb interactions. As an application of our theoretical strategy, we compute various single-particle and many-particle phenomena such as the Fock-Darwin spectrum; Fermi energy; magneto-optical transitions; probability distribution; and the magneto-optical absorption in the quantum dots. It is observed that the role of an applied magnetic field on the absorption spectrum is comparable to that of a confining potential. Increasing (decreasing) the strength of the magnetic field or the confining potential is found to be analogous to shrinking (expanding) the size of the quantum dots: resulting into a blue (red) shift in the absorption spectrum. The Fermi energy diminishes with both increasing magnetic-field and dot-size; and exhibits saw-tooth-like oscillations at large values of field or dot-size. Unlike laterally confined quantum dots, both (upper and lower) magneto-optical transitions survive even in the extreme instances. However, the intra-Landau level

  4. Magneto-optical absorption in semiconducting spherical quantum dots: Influence of the dot-size, confining potential, and magnetic field

    Directory of Open Access Journals (Sweden)

    Manvir S. Kushwaha

    2014-12-01

    Full Text Available Semiconducting quantum dots – more fancifully dubbed artificial atoms – are quasi-zero dimensional, tiny, man-made systems with charge carriers completely confined in all three dimensions. The scientific quest behind the synthesis of quantum dots is to create and control future electronic and optical nanostructures engineered through tailoring size, shape, and composition. The complete confinement – or the lack of any degree of freedom for the electrons (and/or holes – in quantum dots limits the exploration of spatially localized elementary excitations such as plasmons to direct rather than reciprocal space. Here we embark on a thorough investigation of the magneto-optical absorption in semiconducting spherical quantum dots characterized by a confining harmonic potential and an applied magnetic field in the symmetric gauge. This is done within the framework of Bohm-Pines’ random-phase approximation that enables us to derive and discuss the full Dyson equation that takes proper account of the Coulomb interactions. As an application of our theoretical strategy, we compute various single-particle and many-particle phenomena such as the Fock-Darwin spectrum; Fermi energy; magneto-optical transitions; probability distribution; and the magneto-optical absorption in the quantum dots. It is observed that the role of an applied magnetic field on the absorption spectrum is comparable to that of a confining potential. Increasing (decreasing the strength of the magnetic field or the confining potential is found to be analogous to shrinking (expanding the size of the quantum dots: resulting into a blue (red shift in the absorption spectrum. The Fermi energy diminishes with both increasing magnetic-field and dot-size; and exhibits saw-tooth-like oscillations at large values of field or dot-size. Unlike laterally confined quantum dots, both (upper and lower magneto-optical transitions survive even in the extreme instances. However, the intra

  5. Absorption-free optical pumping spin control with the quantum Zeno effect

    CERN Document Server

    Nakanishi, T; Kitano, M

    2002-01-01

    We show that atomic spin motion can be controlled by circularly polarized light without light absorption in the strong pumping limit. In this limit, the pumping light, which drives the empty spin state, destroys the Zeeman coherence effectively and freezes the coherent transition via the quantum Zeno effect. It is verified experimentally that the amount of light absorption decreases asymptotically to zero as the incident light intensity is increased.

  6. Optical Absorption Spectra and Excitons of Dye-Substrate Interfaces: Catechol on TiO2(110).

    Science.gov (United States)

    Mowbray, Duncan John; Migani, Annapaola

    2016-06-14

    Optimizing the photovoltaic efficiency of dye-sensitized solar cells (DSSC) based on staggered gap heterojunctions requires a detailed understanding of sub-band gap transitions in the visible from the dye directly to the substrate's conduction band (CB) (type-II DSSCs). Here, we calculate the optical absorption spectra and spatial distribution of bright excitons in the visible region for a prototypical DSSC, catechol on rutile TiO2(110), as a function of coverage and deprotonation of the OH anchoring groups. This is accomplished by solving the Bethe-Salpeter equation (BSE) based on hybrid range-separated exchange and correlation functional (HSE06) density functional theory (DFT) calculations. Such a treatment is necessary to accurately describe the interfacial level alignment and the weakly bound charge transfer transitions that are the dominant absorption mechanism in type-II DSSCs. Our HSE06 BSE spectra agree semiquantitatively with spectra measured for catechol on anatase TiO2 nanoparticles. Our results suggest deprotonation of catechol's OH anchoring groups, while being nearly isoenergetic at high coverages, shifts the onset of the absorption spectra to lower energies, with a concomitant increase in photovoltaic efficiency. Further, the most relevant bright excitons in the visible region are rather intense charge transfer transitions with the electron and hole spatially separated in both the [110] and [001] directions. Such detailed information on the absorption spectra and excitons is only accessible via periodic models of the combined dye-substrate interface.

  7. Satellite monitoring of different vegetation types by differential optical absorption spectroscopy (DOAS in the red spectral range

    Directory of Open Access Journals (Sweden)

    T. Wagner

    2007-01-01

    Full Text Available A new method for the satellite remote sensing of different types of vegetation and ocean colour is presented. In contrast to existing algorithms relying on the strong change of the reflectivity in the red and near infrared spectral region, our method analyses weak narrow-band (few nm reflectance structures (i.e. "fingerprint" structures of vegetation in the red spectral range. It is based on differential optical absorption spectroscopy (DOAS, which is usually applied for the analysis of atmospheric trace gas absorptions. Since the spectra of atmospheric absorption and vegetation reflectance are simultaneously included in the analysis, the effects of atmospheric absorptions are automatically corrected (in contrast to other algorithms. The inclusion of the vegetation spectra also significantly improves the results of the trace gas retrieval. The global maps of the results illustrate the seasonal cycles of different vegetation types. In addition to the vegetation distribution on land, they also show patterns of biological activity in the oceans. Our results indicate that improved sets of vegetation spectra might lead to more accurate and more specific identification of vegetation type in the future.

  8. Optical diffusion property of cerumen from ear canal and correlation to metal content measured by synchrotron x-ray absorption

    Science.gov (United States)

    Holden, Todd; Dehipawala, Sumudu; Cheung, E.; Golebiewska, U.; Schneider, P.; Tremberger, G., Jr.; Kokkinos, D.; Lieberman, D.; Dehipawala, Sunil; Cheung, T.

    2012-03-01

    Human (and other mammals) would secrete cerumen (ear wax) to protect the skin of the ear canal against pathogens and insects. The studies of biodiversity of pathogen in human include intestine microbe colony, belly button microbe colony, etc. Metals such as zinc and iron are essentials to bio-molecular pathways and would be related to the underlying pathogen vitality. This project studies the biodiversity of cerumen via its metal content and aims to develop an optical probe for metal content characterization. The optical diffusion mean free path and absorption of human cerumen samples dissolved in solvent have been measured in standard transmission measurements. EXFAS and XANES have been measured at Brookhaven Synchrotron Light Source for the determination of metal contents, presumably embedded within microbes/insects/skin cells. The results show that a calibration procedure can be used to correlate the optical diffusion parameters to the metal content, thus expanding the diagnostic of cerumen in the study of human pathogen biodiversity without the regular use of a synchrotron light source. Although biodiversity measurements would not be seriously affected by dead microbes and absorption based method would do well, the scattering mean free path method would have potential to further study the cell based scattering centers (dead or live) via the information embedded in the speckle pattern in the deep-Fresnel zone.

  9. Chiral monolithic absorbent constructed by optically active helical-substituted polyacetylene and graphene oxide: preparation and chiral absorption capacity.

    Science.gov (United States)

    Li, Weifei; Wang, Bo; Yang, Wantai; Deng, Jianping

    2015-02-01

    Chiral monolithic absorbent is successfully constructed for the first time by using optically active helical-substituted polyacetylene and graphene oxide (GO). The preparative strategy is facile and straightforward, in which chiral-substituted acetylene monomer (Ma), cross-linker (Mb), and alkynylated GO (Mc) undergo copolymerization to form the desired monolithic absorbent in quantitative yield. The resulting monoliths are characterized by circular dichroism, UV-vis absorption, scanning electron microscopy (SEM), FT-IR, Raman, energy-dispersive spectrometer (EDS), X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET), XPS, and thermogravimetric analysis (TGA) techniques. The polymer chains derived from Ma form chiral helical structures and thus provide optical activity to the monoliths, while GO sheets contribute to the formation of porous structures. The porous structure enables the monolithic absorbents to demonstrate a large swelling ratio in organic solvents, and more remarkably, the helical polymer chains provide optical activity and further enantio-differentiating absorption ability. The present study establishes an efficient and versatile methodology for preparing novel functional materials, in particular monolithic chiral materials based on substituted polyacetylene and GO.

  10. Determination and analysis of optical constants for Ga{sub 2}Se{sub 3} films near absorption edge

    Energy Technology Data Exchange (ETDEWEB)

    Afifi, M.A.; Bekheet, A.E.; El-Shair, H.T.; Zedan, I.T

    2003-01-01

    Ga{sub 2}Se{sub 3} has been prepared in bulk and thin film forms. The composition of films has been checked using energy dispersive X-ray spectroscopy technique. X-ray diffraction measurements have shown that Ga{sub 2}Se{sub 3} films evaporated at room temperature substrates were amorphous. The transmittance (T) of Ga{sub 2}Se{sub 3} thin films has been measured over the wavelength range (400-900 nm). The optical constants, the refractive index (n) and the absorption index (k) have been determined from the analysis of the transmittance data. Analysis of the refractive index (n) yields the values of the long wavelength dielectric constant ({epsilon}{sub {infinity}}), the average oscillator wavelength ({lambda}{sub o}), average oscillator strength (S{sub o}), average oscillator energy E{sub o}, the refractive index dispersion parameter (E{sub o}/S{sub o}) and the dispersion energy (E{sub d}). Analysis of absorption index (k) yields both direct and indirect allowed transitions with optical energy gaps of 2.65 and 2.056 eV, respectively. The effect of annealing at different temperatures on optical constants is also investigated.

  11. Comparison of key absorption and optical properties between pure and transported anthropogenic dust over East and Central Asia

    Science.gov (United States)

    Bi, Jianrong; Huang, Jianping; Holben, Brent; Zhang, Guolong

    2016-12-01

    Asian dust particulate is one of the primary aerosol constituents in the Earth-atmosphere system that exerts profound influences on environmental quality, human health, the marine biogeochemical cycle, and Earth's climate. To date, the absorptive capacity of dust aerosol generated from the Asian desert region is still an open question. In this article, we compile columnar key absorption and optical properties of mineral dust over East and Central Asian areas by utilizing the multiyear quality-assured datasets observed at 13 sites of the Aerosol Robotic Network (AERONET). We identify two types of Asian dust according to threshold criteria from previously published literature. (1) The particles with high aerosol optical depth at 440 nm (AOD440 ≥ 0.4) and a low Ångström wavelength exponent at 440-870 nm (α TOA), at the surface (SFC), and in the atmospheric layer (ATM) for Asian PDU (α < 0.2) and TDU (0.2 < α < 0.6) computed in this study, are a factor of 2 smaller than the results of Optical Properties of Aerosols and Clouds (OPAC) mineral-accumulated (mineral-acc.) and mineral-transported (mineral-tran.) modes. Therefore, we are convinced that our results hold promise for updating and improving accuracies of Asian dust characteristics in present-day remote sensing applications and regional or global climate models.

  12. Optical absorption enhancement in 40 nm ultrathin film silicon solar cells assisted by photonic and plasmonic modes

    Science.gov (United States)

    Saravanan, S.; Dubey, R. S.

    2016-10-01

    Presently, energy problems and environmental issues have attracted the scientific community for the development of cost-effective and high-performance solar cells. Thin film solar cells are cheaper but weak light absorption in longer wavelength has demanded an efficient light trapping scheme for the better harvesting of solar radiation to a maximum possibility. In this paper, we numerically explore the design efforts of an ultrathin film silicon solar cell, integrated with top dielectric and bottom metal gratings. The proposed design is influenced by the localized surface plasmon modes, surface plasmon polariton and optical resonances which leads to the optimal harvesting of sunlight within 40 nm thick absorbing layer. The optimized design of solar cell shows enhanced light absorption with cell efficiency ∼25% at normal transverse magnetic polarization condition. Our design approach assisted by photonic and plasmonic modes is promising for the realization of new generation, low-cost ultrathin film solar cells.

  13. Ultraviolet absorption spectroscopy in optically dense fireballs using broadband second-harmonic generation of a pulsed modeless dye laser.

    Science.gov (United States)

    Soo, Michael; Glumac, Nick

    2014-01-01

    Broadband frequency doubling of a modeless dye laser pulse is used to enable single-shot absorption spectroscopy in the ultraviolet for optically dense, energetic-materials fireball applications. Band widths of approximately 1-3 nm are generated in the 226 and 268 nm regions using a doubling crystal. Strong focusing of the fundamental beam onto the crystal is found to be sufficient to achieve 1-5% conversion efficiency with a pulse intensity sufficient to saturate the array detector even after 75% attenuation through the fireball. The technique is demonstrated with nitric oxide (NO) absorption in a gas cell and is then used to perform the first detection and temperature fitting of aluminum monofluoride (AlF) and magnesium monofluoride (MgF) in a fireball environment.

  14. Detection of HO2 in an atmospheric pressure plasma jet using optical feedback cavity-enhanced absorption spectroscopy

    Science.gov (United States)

    Gianella, Michele; Reuter, Stephan; Lawry Aguila, Ana; Ritchie, Grant A. D.; van Helden, Jean-Pierre H.

    2016-11-01

    Cold non-equilibrium atmospheric pressure plasma jets are increasingly applied in material processing and plasma medicine. However, their small dimensions make diagnosing the fluxes of generated species a challenge. Here we report on the detection of the hydroperoxyl radical, HO2, in the effluent of a plasma jet by the use of optical feedback cavity-enhanced absorption spectroscopy. The spectrometer has a minimum detectable absorption coefficient {α }\\min of 2.25× {10}-10 cm-1 with a 100 second acquisition, equivalent to 5.5× {10}12 {{cm}}-3 of HO2 (under ideal conditions). Concentrations in the range of (3.1-7.8) × 1013 cm-3 were inferred in the 4 mm wide effluent of the plasma jet.

  15. The characterization of low energy molecular hydrogen ion—induced defects in synthetic diamond by optical absorption

    Institute of Scientific and Technical Information of China (English)

    MaZhong-Quan; AokiY; 等

    1998-01-01

    The results of optical absorption analysis of the synthetic diamonds(type Ib) which were implanted with 40 keV molecular hydrogen ions at doses of 1015-1017H/cm2(at 100K),showed that the increase of optical density(OD) of modified layer(-140nm) in UV-VIS region was dependent upon the damage level caused by ion implantation process.The range of relative optical band gap(Er.opt) around 2.0eV suggested that an amorphous carbon network structure like a-C film,which probably contains some localized subtetrabedral-coordinated clusters embedded in the fourflod(sp3) sites.was tentatively found in this layer,basing on the optical gap of carbon materials.The evolution of Er,opt with ion fluence indicated that no more hydrogenated carbon compositions were produced in as -implanted samples,while the increase of Er,opt with annealing temperature was very similar to that of hydrogen content dependence of Eopt in hydrogenately amorphous carbon(a-C:H):In addition the optical inhomogeneity of type Ib diamond has been revealed by a 2-dimension topograph in transmission mode at λ=430nm。

  16. Determination of Optical Constants of Polystyrene Films from IR Reflection-Absorption Spectra

    Directory of Open Access Journals (Sweden)

    Simion Jitian

    2010-09-01

    Full Text Available Determination of The transmittance values measured in IR reflectionabsorption (RA spectra were used to determine the optical constants of dielectric films laid on solid substrates. In order to obtain the optical constants of polystyrene films laid on steel we used dispersion analysis. In this case, the optical constants are obtained from IR spectrum recorded at a single incidence angle. The use of dispersion analysis offers the advantage of processing a large volume of data.

  17. Absorption-induced Optical Tuning of Silicon Photonic Structures Clad with Nematic Liquid Crystals

    Science.gov (United States)

    2013-03-01

    integrating them with other chip-scale photonic elements, challenges in coupling to the input and output of a typical optical fiber , and the presence of...implemented for both the photo-alignment and voltage alignment samples to aid in the coupling from an optical fiber to the on-chip waveguide. The...sample with the input beam and imaging optics . The transmission spectrum was measured with a tunable Agilent 8163B telecom -grade laser (1470- to 1570

  18. Thermoluminescence, optical absorption, photoluminescence, FT-IR and XRD studies on L-arginine doped orthophosphoric acid

    Energy Technology Data Exchange (ETDEWEB)

    Saradha, K. [Department of Physics, Selvamm Arts and Science College, Namakkal-637002, TN (India); Bangaru, S., E-mail: ssbangaru@yahoo.co.in [Department of Physics, Arignar Anna Government Arts College, Namakkal-637002, TN (India); Muralidharan, G. [Department of Physics, Gandhigram Rural University, Gandhigram-624302, TN (India)

    2013-10-15

    A paper report on the thermoluminescence (TL) optical absorption, photoluminescence (PL), single crystal XRD studies on L-arginine doped orthophosphoric acid confirm that a crystal belongs to the orthorhombic system with space group p2{sub 1}2{sub 1}2{sub 1}. The lattice of most of these crystals forming the composite, in spite of whatever the phase it belongs to, it is spatially coherent to each other with in the crystalline bulk. The functional groups present in the crystal confirms that using FT-IR technique optical absorbance shows meagre absorption from the entire visible region. The TL glow curve of L-arginine doped orthophosphoric acid sample marked a prominent peak at 125, 254 and 303 °C along with small peak at around 218 °C. Correlation with changes in optical absorption suggest that a peak at 125 °C to be related to process involving Z{sub 1} center. The peak follows first order kinetics with an activation energy of 0.033 eV and a frequency factor of 7.45×10{sup 2} and FWHM 61 nm. -- Highlights: • L-Arginine doped orthophosphoric acid has not been adequately studied. • A defect centre formed in L-arginine doped orthophosphoric acid system is assigned to F and Z{sub 1} centres. • The glow peaks are found to obey first order kinetics. • The Lattice parameter a=10.89 Å, b=7.91 Å, C=7.34 Å are in good agreement with the reported values. • The formation of a characteristic F- and centered at 520 nm is found. Such a detailed study and obtained results.

  19. Near-infrared diode laser based spectroscopic detection of ammonia: a comparative study of photoacoustic and direct optical absorption methods

    Science.gov (United States)

    Bozoki, Zoltan; Mohacsi, Arpad; Szabo, Gabor; Bor, Zsolt; Erdelyi, Miklos; Chen, Weidong; Tittel, Frank K.

    2002-01-01

    A photoacoustic spectroscopic (PAS) and a direct optical absorption spectroscopic (OAS) gas sensor, both using continuous-wave room-temperature diode lasers operating at 1531.8 nm, were compared on the basis of ammonia detection. Excellent linear correlation between the detector signals of the two systems was found. Although the physical properties and the mode of operation of both sensors were significantly different, their performances were found to be remarkably similar, with a sub-ppm level minimum detectable concentration of ammonia and a fast response time in the range of a few minutes.

  20. Effect of Silver Addition on the Ethanol-Sensing Properties of Indium Oxide Nanoparticle Layers: Optical Absorption Study

    Directory of Open Access Journals (Sweden)

    Vidya Nand Singh

    2007-01-01

    Full Text Available In2O3 and In2O3:Ag nanoparticle layers have been deposited using a two-step method consisting of chemical capping and dip coating techniques. The result of optical absorption analysis of In2O3:Ag samples shows the presence of Ag2O and Ag in air-annealed and vacuum-annealed samples, respectively. These results have been correlated with the gas sensing properties of these layers towards ethanol and support the proposed mechanism that increase in sensor response on Ag addition is due to the conversion of Ag2O to Ag in the presence of ethanol.

  1. Measurements of Nighttime Nitrate Radical Concentrations in the Atmosphere by Long-Path Differential Optical Absorption Spectroscopy

    Institute of Scientific and Technical Information of China (English)

    LI Suwen; LIU Wenqing; XIE Pinhua; LI Ang; QIN Min; DOU Ke

    2007-01-01

    The long-path differential optical absorption spectroscopy (LP-DOAS) technique was developed to measure nighttime atmospheric nitrate radical (NO3) concentrations. An optimized retrieval method, resulting in a small residual structure and low detection limits, was developed to retrieve NOs. The time series of the NO3 concentration were collected from 17 to 24 March, 2006, where a nighttime average value of 15.8 ppt was observed. The interfering factors and errors are also discussed. These results indicate that the DOAS technique provides an essential tool for the quantification of NO3 concentration and in the study of its effects upon nighttime chemistry.

  2. Luminescence and optical absorption studies of submicro-dimensional cerium ortho- and metaphosphates doped with Eu{sup 3+} ions

    Energy Technology Data Exchange (ETDEWEB)

    Matraszek, A. [Department of Inorganic Chemistry, Faculty of Engineering and Economics, Wroclaw University of Economics, 118/120 Komandorska str., 53-345 Wroclaw (Poland); Macalik, L. [Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 1410, 50-950 Wroclaw (Poland); Szczygiel, I. [Department of Inorganic Chemistry, Faculty of Engineering and Economics, Wroclaw University of Economics, 118/120 Komandorska str., 53-345 Wroclaw (Poland); Godlewska, P. [Department of Bioorganic Chemistry, Faculty of Engineering and Economics, Wroclaw University of Economics, 118/120 Komandorska str., 53-345 Wroclaw (Poland); Solarz, P. [Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 1410, 50-950 Wroclaw (Poland); Hanuza, J. [Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 1410, 50-950 Wroclaw (Poland)], E-mail: j.hanuza@int.pan.wroc.pl

    2008-02-28

    Pechini method has been applied for synthesis of the phosphates in the submicro-state. Dimensions of the obtained grains by this method fall into the 100-1000 nm range. The following samples have been synthesised: stoichiometric orthophosphate Na{sub 3}Ce(PO{sub 4}){sub 2} and metaphosphate NaCe(PO{sub 3}){sub 4} both doped with 2 and 5% of Eu{sup 3+}. Optical absorption and emission studies have been performed to characterise the properties and structure of the compounds studied. The electronic characteristics of the Ce{sup 3+} and Eu{sup 3+} ions in these materials have been discussed.

  3. The manifestation of optical centers in UV-Vis absorption and luminescence spectra of white blood human cells

    Science.gov (United States)

    Terent'yeva, Yu G.; Yashchuk, V. M.; Zaika, L. A.; Snitserova, O. M.; Losytsky, M. Yu

    2016-12-01

    A white blood human cells spectral investigation is presented. The aim of this series of experiments was to obtain and analyze the absorption and luminescence (fluorescence and phosphorescence) spectra at room temperature and at 78 K of newly isolated white blood human cells and their organelles. As a result the optical centers and possible biochemical components that form the studied spectra where identified. Also the differences between the spectra of abnormal cells (B-cell chronic lymphocytic leukemia BCLL) and normal ones were studied for the whole cells and individual organelles.

  4. A Scanning Multi-Axis Differential Optical Absorption Spectroscopy System for Measurement of Tropospheric NO2 in Beijing

    Institute of Scientific and Technical Information of China (English)

    LI Ang; XIE Pin-Hua; LIU Cheng; LIU Jian-Guo; LIU Wen-Qing

    2007-01-01

    A scanning multi-axis differential optical absorption spectroscopy (DOAS) system is developed for monitoring tropospheric NO2 abundance. Measurements at different viewing angles near the horizon can be performed sequentially with one telescope collecting scattered sunlight reflected by a moving mirror. Tropospheric NO2 diurnal variations can be derived from slant column densities (SCDs) of different elevation angles. The result from a field campaign in Beijing in summer of 2005 reveals potential possibility for the monitoring of tropospheric NO2 by multi-axis DOAS technique.

  5. Optical absorption measurements and quantum-chemical simulations of optical properties of novel fluoro derivatives of pyrazoloquinoline

    Science.gov (United States)

    Brik, M. G.; Kuznik, W.; Gondek, E.; Kityk, I. V.; Uchacz, T.; Szlachcic, P.; Jarosz, B.; Plucinski, K. J.

    2010-05-01

    The results of experimental research and quantum-chemical simulations of the absorption spectra of 1-(4-fluorophenyl)-3,4-diphenyl, 3-(4-fluorophenyl)-1,4-diphenyl, and 4-(4-fluorophenyl)-1,3-diphenyl-pyrazolo[3,4- b] quinoline are presented. Although the fluorine atom is located on different phenyl rings in these molecules, the absorption spectra do not differ significantly. Semi-empirical AM1, PM3 and RM1 methods, as well as ab initio ADF code-based calculations were used to optimize geometry, calculate the infrared and visible spectra of the afore mentioned compounds and analyze the molecular orbitals schemes. The results of calculations are in good agreement with the experimental data. It was also demonstrated that the positions of the fluorescence maxima depend significantly on the solvent (contrary to the absorption spectra), in which the molecules are embedded, which allows for manipulating with fluorescence properties of the synthesized molecules by changing the solvent.

  6. Tuning optical absorption and photoexcited recombination dynamics in La1-xSrxFeO3-δ through A-site substitution and oxygen vacancies

    Science.gov (United States)

    Smolin, Sergey; Scafetta, Mark; Choquette, Amber; Sfeir, Matthew; Baxter, Jason; May, Steven

    We study optical absorption and recombination dynamics in La1-xSrxFeO3-δ thin films, uncovering the effects of tuning nominal Fe valence via A-site substitution and oxygen stoichiometry. Variable angle spectroscopic ellipsometry was used to measure static optical properties, revealing a linear increase in absorption coefficient at 1.25 eV and a red-shifting of the optical absorption edge with increasing Sr fraction. The absorption spectra can be similarly tuned through the introduction of oxygen vacancies, indicating the critical role that nominal Fe valence plays in optical absorption. Dynamic optoelectronic properties were studied with ultrafast transient reflectance spectroscopy, revealing similar nanosecond photoexcited carrier lifetimes for oxygen deficient and stoichiometric films with the same nominal Fe valence. These results demonstrate that while the static optical absorption is strongly dependent on Fe valence tuned through cation or anion stoichiometry, oxygen vacancies do not appear to play a significantly detrimental role in the recombination kinetics. Nsf: ECCS-1201957, MRI DMR-0922929, MRI DMR-1040166. This research used resources of the Center for Functional Nanomaterials, which is a U.S. DOE Office of Science Facility, at Brookhaven National Laboratory under Contract No. DE-SC0012704.

  7. Direction reversal of the optical spin torque on a Rayleigh absorptive sphere in vector Bessel polarized beams

    Science.gov (United States)

    Yang, Ruiping; Li, Renxian; Qin, Shitong; Ding, Chunying; Mitri, F. G.

    2017-02-01

    The effect of polarization on the optical spin torque (OST) exerted on an absorptive Rayleigh dielectric sphere by a vector Bessel beam is investigated using the dipole approximation method, with particular emphasis on the polarization of the plane wave component forming the beam. On the basis of the mathematical descriptions for the electric fields, which are derived using the angular spectrum decomposition method in plane waves, analytical formulas of the OST are established. The OSTs are numerically calculated, and the effects of polarization, beam-order, and half-cone angle are discussed in detail. Numerical results show that by choosing an appropriate polarization, order and half-cone angle, the transverse OST will manifest vortex-like behaviors, and the sphere will experience negative axial OSTs, i.e. OST sign reversal. Important applications in particle manipulation, rotation and handling using optical Bessel polarized beams would benefit from the results of the present investigation.

  8. Optical absorption spectra as a useful tool to find parameters of deep impurity centers in semiconductors.

    Science.gov (United States)

    Makhniy, Viktor P; Horley, Paul P; Kinzerskaya, Oksana V; Stets, Elena V

    2014-04-01

    We analyze physical models accounting for deep-level conduction band transitions to describe impurity absorption spectra in tetrahedral-structured semiconductors. The investigations were carried out for ZnSe crystals doped with transition metals (Ti, V, Cr, Mn, Fe, Co, Ni) from a vapor phase. It was shown that the impurities provide acceptor centers with ground state energy offset by 0.3-0.6 eV from the edge of the conduction band, forming long-wave bands in the absorption spectra of the materials studied.

  9. Synthesis,structure and nonlinear optical properties of two novel two-photon absorption chromophores

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    Two triphenylamine-based derivatives that can be used as two-photon absorption chromophore,tris{4-[4-(3-trifluoromethyl-3-oxopanoyl)]phenyl}amine (1) and tris{4-[4-(3-phenyl-3-oxopanoyl)] phenyl} amine (2) were successfully synthesized and fully characterized by elemental analysis,IR,1H NMR and MS. The single crystal X-ray diffraction analysis showed that the molecules possess D-(π-A)3 structures. One-and two-photon absorption and fluorescence in various solvents were experimentally investigated. A data recording experiment proved the potential application of these chromophores.

  10. Measurement of small light absorption in microparticles by means of optically induced rotation

    DEFF Research Database (Denmark)

    Angelsky, O. V.; Bekshaev, A. Ya; Maksimyak, P. P.;

    2015-01-01

    The absorption parameters of micro-particles have been associated with the induced spin exerted upon the particle, when embedded in a circularly polarized coherent field. The induced rotational speed is theoretically analyzed, showing the influence of the beam parameters, the parameters of the pa......The absorption parameters of micro-particles have been associated with the induced spin exerted upon the particle, when embedded in a circularly polarized coherent field. The induced rotational speed is theoretically analyzed, showing the influence of the beam parameters, the parameters...

  11. Tunable emission and excited state absorption induced optical limiting in Tb2(MoO4)3: Sm3+/Eu3+ nanophosphors

    Science.gov (United States)

    Mani, Kamal P.; Sreekanth, Perumbilavil; Vimal, G.; Biju, P. R.; Unnikrishnan, N. V.; Ittyachen, M. A.; Philip, Reji; Joseph, Cyriac

    2016-12-01

    Photoluminescence properties and optical limiting behavior of pure and Sm3+/Eu3+ doped Tb2(MoO4)3 nanophosphors are investigated. The prepared nanophosphors exhibit excellent emission when excited by UV light. Color-tunable emissions in Tb2-xSmx(MoO4)3 and Tb2-xEux(MoO4)3 are realized by employing different excitation wavelengths or by controlling the doping concentration of Sm3+ and Eu3+. Luminescence quantum yield and CIE chromatic coordinates of the prepared phosphors were also presented. Optical limiting properties of the samples are investigated by open aperture Z-scan technique using 5 ns laser pulses at 532 nm. Numerical fitting of the measured Z-scan data to the relevant nonlinear transmission equations reveals that the nonlinear absorption is arising from strong excited state absorption, along with weak absorption saturation and it is found that the optical nonlinearity of Tb2(MoO4)3 increases with Sm3+/Eu3+doping. Parameters such as saturation fluence, excited state absorption cross section and ground state absorption cross section of the samples have been determined numerically, from which the figure of merit for nonlinear absorption is calculated. The excited state absorption cross-section of the samples is found to be one order of magnitude higher than that of the ground state absorption cross-section, indicating strong reverse saturable absorption. These results indicate that Sm3+/Eu3+ doped Tb2(MoO4)3 nanophosphors are efficient media for UV/n-UV pumped LEDs, and are also potential candidates for designing efficient optical limiting devices for the protection of human eyes and sensitive optical detectors from harmful laser radiation.

  12. Apparent PS II absorption cross-section and estimation of mean PAR in optically thin and dense suspensions of Chlorella.

    Science.gov (United States)

    Klughammer, Christof; Schreiber, Ulrich

    2015-01-01

    Theoretical prediction of effective mean PAR in optically dense samples is complicated by various optical effects, including light scattering and reflections. Direct information on the mean rate of photon absorption by PS II is provided by the kinetics of the fluorescence rise induced upon onset of strong actinic illumination (O-I1 rise). A recently introduced kinetic multi-color PAM fluorometer was applied to study the relationship between initial slope and cell density in the relatively simple model system of suspensions of Chlorella. Use of a curve fitting routine was made which was originally developed for assessment of the wavelength-dependent absorption cross-section of PS II, σ II(λ), in dilute suspensions. The model underlying analysis of the O-I1 rise kinetics is outlined and data on the relationship between fitted values of σ II(λ) and PAR in dilute samples are presented. With increasing cell density, lowering of apparent cross-section, (λ), with respect to σ II(λ), relates to a decrease of effective mean PAR, (λ), relative to incident PAR(λ). When ML and AL are applied in the same direction, the decline of (λ)/σ II(λ) with increasing optical density is less steep than that of the theoretically predicted (λ)/PAR(λ). It approaches a value of 0.5 when the same colors of ML and AL are used, in agreement with theory. These observations open the way for estimating mean PAR in optically dense samples via measurements of (λ)/σ II(λ)).

  13. Optical detection of potassium chloride vapor using collinear photofragmentation and atomic absorption spectroscopy.

    Science.gov (United States)

    Sorvajärvi, Tapio; Saarela, Jaakko; Toivonen, Juha

    2012-10-01

    A sensitive and selective optical technique to detect potassium chloride (KCl) vapor is introduced. The technique is based on the photofragmentation of KCl molecules, using a pulsed UV laser, and optical probing of the temporarily increased amount of potassium atoms with a near-infrared laser. The two laser beams are aligned to go through the sample volume along the same optical path. The performance of the technique is demonstrated by detecting KCl concentrations from 25 ppb to 30 ppm in a temperature-controlled cell.

  14. Coherent perfect absorption mediated enhancement and optical bistability in phase conjugation

    CERN Document Server

    Reddy, K Nireekshan; Gupta, S Dutta

    2016-01-01

    We study phase conjugation in a nonlinear composite slab when the counter propagating pump waves are completely absorbed by means of coherent perfect absorption. Under the undepleted pump approximation the coupling constant and the phase conjugated reflectivity are shown to undergo a substantial increase and multivalued response. The effect can be used for efficient switching of the phase conjugated reflectivity in photonic circuits.

  15. Enhancing optical absorption of metal–organic frameworks for improved visible light photocatalysis

    NARCIS (Netherlands)

    Nasalevich, M.A.; Goesten, M.G.; Savenije, T.J.; Kapteijn, F.; Gascon, J.

    2013-01-01

    NH2-MIL-125(Ti) has been post-synthetically functionalized with dye-like molecular fragments. The new material (methyl red-MIL- 125(Ti)) exhibits improved light absorption over a wide range of the visible spectrum, and shows enhanced photocatalytic oxidation activity under visible light illumination

  16. Optical-to-X-ray emission in low-absorption AGN: results from the Swift-BAT 9-month catalogue

    Science.gov (United States)

    Vasudevan, R. V.; Mushotzky, R. F.; Winter, L. M.; Fabian, A. C.

    2009-11-01

    We present simultaneous optical-to-X-ray spectral energy distributions (SEDs) from Swift's X-ray and UV-optical telescopes (XRTs and UVOTs) for a well-selected sample of 26 low-redshift (z extinction from the resultant nuclear SEDs. Black hole mass estimates are determined from the host galaxy Two-Micron All-Sky Survey K-band bulge luminosity. Accretion rates determined from our SEDs are on average low (Eddington ratios λEdd extinction. Significant dust reddening is found in some objects despite the selection of low NH objects, emphasizing the complex relationship between these two types of absorption. We do not find a correlation of the optical-to-X-ray spectral index with the Eddington ratio, regardless of the optical reference wavelength chosen for defining the spectral index. An anticorrelation of bolometric correction with black hole mass may reinforce `cosmic downsizing' scenarios, since the higher bolometric corrections at low mass would boost accretion rates in local, lower mass black holes. We also perform a basic analysis of the UVOT-derived host galaxy colours for our sample and find hosts cluster near the `green valley' of the colour-magnitude diagram, but better quality images are needed for a more definitive analysis. The low accretion rates and bolometric corrections found for this representative low-redshift sample are of particular importance for studies of AGN accretion history.

  17. The optical absorption of gamma irradiated and heat-treated natural quartz

    Directory of Open Access Journals (Sweden)

    Eduardo Henrique Martins Nunes

    2005-09-01

    Full Text Available Quartz with aluminum as impurity absorbs energy from ionizing radiation and modifies its color. Colorless quartz becomes smoky or dark smoky (morion quartz when exposed to gamma rays. By heat-treatment, smoky quartz may become successively greenish, yellowish, or brownish as the irradiation dose increases. Natural, colorless quartz is routinely colored by irradiation with gamma rays and heat-treatment for jewelry production. The color formation in natural quartz through this procedure is explained based on EPR, UV-VIS, and IR studies of irradiated and irradiated and heat-treated samples. Smoky quartz shows absorption bands in the visible region and a strong EPR signal. After heat-treatment it shows absorption bands in the near UV region with extensions into the visible region and a weak EPR signal. The intensity of the absorption bands is proportional to the irradiation dose. These changes of color are explained by the model of Itoh, Stoneham, and Stoneham. [AlSi O4 /h+]0 centers are produced by irradiation, causing the EPR signal and the absorption bands in the visible region. [AlSi O4]- centers are created from [AlSi O4 /h+]0 centers by heat-treatment. They cannot cause an EPR signal and have absorption bands in the near UV region with extensions into the visible region. The highest concentration of [AlSi O4]- centers occurs when the charge compensators have medium mobility. Lithium should give the best condition for color formation. Sodium (low mobility and hydrogen (high mobility should make smoky quartz colorless after heat-treatment.

  18. Optical and structural properties of plasma-treated Cordyceps bassiana spores as studied by circular dichroism, absorption, and fluorescence spectroscopy

    Science.gov (United States)

    Lee, Geon Joon; Sim, Geon Bo; Choi, Eun Ha; Kwon, Young-Wan; Kim, Jun Young; Jang, Siun; Kim, Seong Hwan

    2015-01-01

    To understand the killing mechanism of fungal spores by plasma treatment, the optical, structural, and biological properties of the insect pathogenic fungus Cordyceps bassiana spores were studied. A nonthermal atmospheric-pressure plasma jet (APPJ) was used to treat the spores in aqueous solution. Optical emission spectra of the APPJ acquired in air indicated emission peaks corresponding to hydroxyl radicals and atomic oxygen. When the APPJ entered the aqueous solution, additional reactive species were derived from the interaction of plasma radicals with the aqueous solution. Fluorescence and absorption spectroscopy confirmed the generation of hydroxyl radicals and hydrogen peroxide in the plasma-activated water (PAW). Spore counting showed that plasma treatment significantly reduced spore viability. Absorption spectroscopy, circular dichroism (CD) spectroscopy, and agarose gel electrophoresis of the DNA extracted from plasma-treated spores showed a reduction in spore DNA content. The magnitude of the dip in the CD spectrum was lower in the plasma-treated spores than in the control, indicating that plasma treatment causes structural modifications and/or damage to cellular components. Tryptophan fluorescence intensity was lower in the plasma-treated spores than in the control, suggesting that plasma treatment modified cell wall proteins. Changes in spore viability and DNA content were attributed to structural modification of the cell wall by reactive species coming from the APPJ and the PAW. Our results provided evidence that the plasma radicals and the derived reactive species play critical roles in fungal spore inactivation.

  19. Optical and structural properties of plasma-treated Cordyceps bassiana spores as studied by circular dichroism, absorption, and fluorescence spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Geon Joon, E-mail: gjlee@kw.ac.kr; Sim, Geon Bo; Choi, Eun Ha [Plasma Bioscience Research Center/Department of Electrical and Biological Physics, Kwangwoon University, Seoul 139-701 (Korea, Republic of); Kwon, Young-Wan [KU-KIST Graduate School of Converging Science and Technology, Korea University, Seoul 136-701 (Korea, Republic of); Kim, Jun Young; Jang, Siun; Kim, Seong Hwan, E-mail: piceae@naver.com [Department of Microbiology and Institute of Basic Sciences, Dankook University, Cheonan 330-714 (Korea, Republic of)

    2015-01-14

    To understand the killing mechanism of fungal spores by plasma treatment, the optical, structural, and biological properties of the insect pathogenic fungus Cordyceps bassiana spores were studied. A nonthermal atmospheric-pressure plasma jet (APPJ) was used to treat the spores in aqueous solution. Optical emission spectra of the APPJ acquired in air indicated emission peaks corresponding to hydroxyl radicals and atomic oxygen. When the APPJ entered the aqueous solution, additional reactive species were derived from the interaction of plasma radicals with the aqueous solution. Fluorescence and absorption spectroscopy confirmed the generation of hydroxyl radicals and hydrogen peroxide in the plasma-activated water (PAW). Spore counting showed that plasma treatment significantly reduced spore viability. Absorption spectroscopy, circular dichroism (CD) spectroscopy, and agarose gel electrophoresis of the DNA extracted from plasma-treated spores showed a reduction in spore DNA content. The magnitude of the dip in the CD spectrum was lower in the plasma-treated spores than in the control, indicating that plasma treatment causes structural modifications and/or damage to cellular components. Tryptophan fluorescence intensity was lower in the plasma-treated spores than in the control, suggesting that plasma treatment modified cell wall proteins. Changes in spore viability and DNA content were attributed to structural modification of the cell wall by reactive species coming from the APPJ and the PAW. Our results provided evidence that the plasma radicals and the derived reactive species play critical roles in fungal spore inactivation.

  20. Determination of blue-light-induced infrared absorption based on mode-matching efficiency in an optical parametric oscillator

    Science.gov (United States)

    Wang, Yajun; Yang, Wenhai; Li, Zhixiu; Zheng, Yaohui

    2017-02-01

    Non-classical squeezed states of light at a compatible atomic wavelength have a potential application in quantum information protocols for quantum states delaying or storaging. An optical parametric oscillator (OPO) with periodically poled potassium titanyl phosphate (PPKTP) is the most effective method for generating this squeezed state. However, it is a challege for the nonlinear interaction in PPKTP crystal at the D1 line of rubidium atomic, due to a strong blue-light-induced infrared absorption (BLIIRA). In this paper, we report an indirect measurement method for the BLIIRA through measuring the mode-matching efficiency in an optical parametric oscillator. In contrast to previous works, our method is not limited by the absolute power variation induced from the change of frequency conversion loss and the impedance matching originated from the change of absorption loss. Therefore, the measurement process is performed at the phase-matching condition. The measured results show that BLIIRA coefficient is quadratic dependence of blue light intensity below 1 kW per square centimeter in our PPKTP device, which will provide important basis for optimizing squeezed state generation at 795 nm.

  1. Kramers-Kronig analysis of molecular evanescent-wave absorption spectra obtained by multimode step-index optical fibers.

    Science.gov (United States)

    Potyrailo, R A; Ruddy, V P; Hieftje, G M

    1996-07-20

    Spectral distortions that arise in evanescent-wave absorption spectra obtained with multimode step-index optical fibers are analyzed both theoretically and experimentally. Theoretical analysis is performed by the application of Kramers-Kronig relations to the real and the imaginary parts of the complex refractive index of an absorbing external medium. It is demonstrated that even when the extinction coefficient of the external medium is small, anomalous dispersion of that medium in the vicinity of an absorption band must be considered. Deviations from Beer's law, band distortions, and shifts in peak position are quantified theoretically as a function of the refractive index and the extinction coefficient of the external medium; the effect of bandwidth for both Lorentzian and Gaussian bands is also evaluated. Numerical simulations are performed for two types of sensing sections in commonly used plastic-clad silica optical fibers. These sensors include an unclad fiber in contact with a lower-index absorbing liquid and a fiber with the original cladding modified with an absorbing species. The numerical results compare favorably with those found experimentally with these types of sensing sections.

  2. Optical absorption and scattering properties of bulk porcine muscle phantoms from interstitial radiance measurements in 650-900 nm range

    Science.gov (United States)

    Grabtchak, Serge; Montgomery, Logan G.; Whelan, William M.

    2014-05-01

    We demonstrated the application of relative radiance-based continuous wave (cw) measurements for recovering absorption and scattering properties (the effective attenuation coefficient, the diffusion coefficient, the absorption coefficient and the reduced scattering coefficient) of bulk porcine muscle phantoms in the 650-900 nm spectral range. Both the side-firing fiber (the detector) and the fiber with a spherical diffuser at the end (the source) were inserted interstitially at predetermined locations in the phantom. The porcine phantoms were prostate-shaped with ˜4 cm in diameter and ˜3 cm thickness and made from porcine loin or tenderloin muscles. The described method was previously validated using the diffusion approximation on simulated and experimental radiance data obtained for homogenous Intralipid-1% liquid phantom. The approach required performing measurements in two locations in the tissue with different distances to the source. Measurements were performed on 21 porcine phantoms. Spectral dependences of the effective attenuation and absorption coefficients for the loin phantom deviated from corresponding dependences for the tenderloin phantom for wavelengths tissues and organs for interstitial optical interrogation.

  3. Initial investigation of the wavelength dependence of optical properties measured with a new multi-pass aerosol extinction differential optical absorption spectrometer (AE-DOAS

    Directory of Open Access Journals (Sweden)

    R. T. Chartier

    2011-10-01

    Full Text Available Atmospheric aerosols directly affect climate by scattering and absorbing radiation. The magnitude of the impact is dependent upon the wavelength of light, but is often estimated near 550 nm. When light scattering and absorption by aerosols is approximated, the wavelength dependence of the refractive index for specific components is lost. As a result, climate models would have inherent uncertainties for aerosol contributions to radiative forcing when considering the entire solar spectrum. An aerosol extinction differential optical absorption spectrometer has been developed to directly measure aerosol extinction at mid-ultraviolet to near infrared wavelengths. The instrument consists of a spectrometer coupled to a closed White-type multi-pass gas cell with an adjustable path length of up to approximately 20 m. Laboratory measurements of various gases are compared with known absorption cross sections. Additionally, the extinction of monodisperse samples of polystyrene latex spheres are measured and compared to Mie theory generated with refractive index values from the literature to validate the new instrument. The polystyrene experiments also emphasize the ability of the new instrument to retrieve the wavelength dependent refractive index, especially in the ultraviolet wavelength regions where variability is expected. The spectrometer will be a significant advancement for determining wavelength dependent complex refractive indices in future laboratory studies as well as provide the ability to monitor ambient aerosol light extinction.

  4. Initial investigation of the wavelength dependence of optical properties measured with a new multi-pass Aerosol Extinction Differential Optical Absorption Spectrometer (AE-DOAS

    Directory of Open Access Journals (Sweden)

    R. T. Chartier

    2012-04-01

    Full Text Available Atmospheric aerosols directly affect climate by scattering and absorbing radiation. The magnitude of the impact is dependent upon the wavelength of light, but is often estimated near 550 nm. When light scattering and absorption by aerosols is approximated, the wavelength dependence of the refractive index for specific components is lost. As a result, climate models would have inherent uncertainties for aerosol contributions to radiative forcing when considering the entire solar spectrum. An aerosol extinction differential optical absorption spectrometer has been developed to directly measure aerosol extinction at mid-ultraviolet to near infrared wavelengths. The instrument consists of a spectrometer coupled to a closed White-type multi-pass gas cell with an adjustable path length of up to approximately 20 m. Laboratory measurements of various gases are compared with known absorption cross sections. Additionally, the extinction of monodisperse samples of polystyrene latex spheres are measured and compared to Mie theory generated with refractive index values from the literature to validate the new instrument. The polystyrene experiments also emphasize the ability of the new instrument to retrieve the wavelength dependent refractive index, especially in the ultraviolet wavelength regions where variability is expected. The spectrometer will be a significant advancement for determining wavelength dependent complex refractive indices in future laboratory studies as well as provide the ability to monitor ambient aerosol light extinction.

  5. L-Asparagine crystals with wide gap semiconductor features: optical absorption measurements and density functional theory computations.

    Science.gov (United States)

    Zanatta, G; Gottfried, C; Silva, A M; Caetano, E W S; Sales, F A M; Freire, V N

    2014-03-28

    Results of optical absorption measurements are presented together with calculated structural, electronic, and optical properties for the anhydrous monoclinic L-asparagine crystal. Density functional theory (DFT) within the generalized gradient approximation (GGA) including dispersion effects (TS, Grimme) was employed to perform the calculations. The optical absorption measurements revealed that the anhydrous monoclinic L-asparagine crystal is a wide band gap material with 4.95 eV main gap energy. DFT-GGA+TS simulations, on the other hand, produced structural parameters in very good agreement with X-ray data. The lattice parameter differences Δa, Δb, Δc between theory and experiment were as small as 0.020, 0.051, and 0.022 Å, respectively. The calculated band gap energy is smaller than the experimental data by about 15%, with a 4.23 eV indirect band gap corresponding to Z → Γ and Z → β transitions. Three other indirect band gaps of 4.30 eV, 4.32 eV, and 4.36 eV are assigned to α3 → Γ, α1 → Γ, and α2 → Γ transitions, respectively. Δ-sol computations, on the other hand, predict a main band gap of 5.00 eV, just 50 meV above the experimental value. Electronic wavefunctions mainly originating from O 2p-carboxyl, C 2p-side chain, and C 2p-carboxyl orbitals contribute most significantly to the highest valence and lowest conduction energy bands, respectively. By varying the lattice parameters from their converged equilibrium values, we show that the unit cell is less stiff along the b direction than for the a and c directions. Effective mass calculations suggest that hole transport behavior is more anisotropic than electron transport, but the mass values allow for some charge mobility except along a direction perpendicular to the molecular layers of L-asparagine which form the crystal, so anhydrous monoclinic L-asparagine crystals could behave as wide gap semiconductors. Finally, the calculations point to a high degree of optical

  6. L-asparagine crystals with wide gap semiconductor features: Optical absorption measurements and density functional theory computations

    Energy Technology Data Exchange (ETDEWEB)

    Zanatta, G.; Gottfried, C. [Departamento de Bioquímica, Universidade Federal do Rio Grande do Sul, 90035-003 Porto Alegre-RS (Brazil); Silva, A. M. [Universidade Estadual do Piauí, 64260-000 Piripiri-Pi (Brazil); Caetano, E. W. S., E-mail: ewcaetano@gmail.com [Instituto de Educação, Ciência e Tecnologia do Ceará, 60040-531 Fortaleza-CE (Brazil); Sales, F. A. M.; Freire, V. N. [Departamento de Física, Universidade Federal do Ceará, Caixa Postal 6030, 60455-760 Fortaleza-CE (Brazil)

    2014-03-28

    Results of optical absorption measurements are presented together with calculated structural, electronic, and optical properties for the anhydrous monoclinic L-asparagine crystal. Density functional theory (DFT) within the generalized gradient approximation (GGA) including dispersion effects (TS, Grimme) was employed to perform the calculations. The optical absorption measurements revealed that the anhydrous monoclinic L-asparagine crystal is a wide band gap material with 4.95 eV main gap energy. DFT-GGA+TS simulations, on the other hand, produced structural parameters in very good agreement with X-ray data. The lattice parameter differences Δa, Δb, Δc between theory and experiment were as small as 0.020, 0.051, and 0.022 Å, respectively. The calculated band gap energy is smaller than the experimental data by about 15%, with a 4.23 eV indirect band gap corresponding to Z → Γ and Z → β transitions. Three other indirect band gaps of 4.30 eV, 4.32 eV, and 4.36 eV are assigned to α3 → Γ, α1 → Γ, and α2 → Γ transitions, respectively. Δ-sol computations, on the other hand, predict a main band gap of 5.00 eV, just 50 meV above the experimental value. Electronic wavefunctions mainly originating from O 2p–carboxyl, C 2p–side chain, and C 2p–carboxyl orbitals contribute most significantly to the highest valence and lowest conduction energy bands, respectively. By varying the lattice parameters from their converged equilibrium values, we show that the unit cell is less stiff along the b direction than for the a and c directions. Effective mass calculations suggest that hole transport behavior is more anisotropic than electron transport, but the mass values allow for some charge mobility except along a direction perpendicular to the molecular layers of L-asparagine which form the crystal, so anhydrous monoclinic L-asparagine crystals could behave as wide gap semiconductors. Finally, the calculations point to a high degree of optical

  7. Optical absorption, induced bleaching, and photoluminescence of CdSe nanoplatelets grown in cadmium octanoate matrix

    Science.gov (United States)

    Lyashchova, Alina; Dmytruk, Andriy; Dmitruk, Igor; Klimusheva, Gertruda; Mirnaya, Tetyana; Asaula, Vitaliy

    2014-02-01

    CdSe nanoparticles (NPs) are chemically synthesized in thermotropic ionic liquid crystalline (LC) phase of cadmium octanoate that was used as a nanoreactor. The nanocomposite samples are obtained by the rapid cooling of the LC phase to room temperature. Observed doublet structure in absorption spectra of the nanocomposites is characteristic for the two-dimensional CdSe nanoplatelets (NPLs). The thicknesses of the CdSe NPLs are 1.6, 1.9 and 2.3 nm as determined from the absorption spectra, and correspond to 4, 5 and 6 CdSe monolayers, respectively. Induced simultaneous bleaching of the doublet components observed under femtosecond laser excitation, as well as photoluminescence spectra and their kinetics are found compatible with the model of excitons with heavy- and light-hole valence bands confined in nanoplatelets.

  8. Synthesis of ZnO nanorods and their optical absorption in visible-light region

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Single crystalline ZnO nanorods were prepared by the hydrothermal method with synthesized ZnCl2.4Zn(OH)2as the precursor. Morphologies of the nanorods were controlled by various reaction conditions with cetyltrimethylammonium bromide (CTAB) as the modifying agent. The nanorods were characterized by XRD, TEM, UV-Vis spectra, and IR spectra. The microstructure of holes in nanosize was observed on the surface of the nanorods. The UV-Vis spectra indicate that the as-prepared ZnO nanorods have absorption of visible-light as well as ultraviolet-light. Therefore, these nanorods may be good candidates for visible-light photocatalysis materials from the viewpoint of practical applications. The reason for visible-light absorption was discussed in this article.

  9. Demonstration of the Applicability of Novel Photoacoustic Aerosol Monitor for Optical Absorption Coefficient Determination. Laboratory and Field Test.

    Science.gov (United States)

    Ajtai, T.; Schnaiter, M.; Linke, C.; Vragel, M.; Filep, Á.; Fődi, L.; Motika, G.; Bozóki, Z.; Szabó, G.

    2009-04-01

    Despite of its importance, the possibilities to determine the direct radiative forcing by atmospheric aerosols is very limited due to lack of the reliable on-line instruments. Therefore there is an increasing concern for novel methods promising more accurate and reliable results in this field. The accuracy and reliability of the available on-line instruments like SP2 (Single Particle Soot Photometer), MAAP (Multi Angle Absorption Photometer), are limited by the weakness of the spectral resolution or the sampling artefact of filter matrix during the light attenuation measurement on the deposited filter. These methods neither suitable for direct determination of the light absorption by aerosols nor dispose the capability of the source apportionment. In this work we present a novel photoacoustic based instrument for direct light absorption measurements in the atmosphere and demonstrate the suitability of that both in laboratory and field circumstances. We have developed a novel Multi Wavelength PhotoAcoustic System (WaSul-MuWaPas) based on the diode laser pumped, high repetition rate, Q-switched Nd:YAG laser and its frequency converted harmonics for direct determination of light absorption by aerosols. This instrument has designed to make in situ measurements at four different wavelengths simultaneously from the NIR to the UV wavelength range (1064nm, 532nm, 355nm, 266nm). The Wasul-MuWaPas measures directly the optical absorption coefficient on airborne particles, not belong to the integrated plate type technique (filter-free operation), operating at wide wavelength range (source apportionment possibilities), due to the possibilities of the wavelength independent cell constant determination the measurement method is absolute. Because of these the Wasul-MuWaPas system may become one of the best candidate for absorption measurements of various atmospheric aerosols such as black carbon, mineral dust, and secondary organic and inorganic aerosols as well as for source

  10. Electronic absorption spectra and nonlinear optical properties of CO2 molecular aggregates: A quantum chemical study

    Indian Academy of Sciences (India)

    Tarun K Mandal; Sudipta Dutta; Swapan K Pati

    2009-09-01

    We have investigated the structural aspects of several carbon dioxide molecular aggregates and their spectroscopic and nonlinear optical properties within the quantum chemical theory framework. We find that, although the single carbon dioxide molecule prefers to be in a linear geometry, the puckering of angles occur in oligomers because of the intermolecular interactions. The resulting dipole moments reflect in the electronic excitation spectra of the molecular assemblies. The observation of significant nonlinear optical properties suggests the potential application of the dense carbon dioxide phases in opto-electronic devices.

  11. Modeling of absorption and scattering properties of core -shell nanoparticles for application as nanoantenna in optical domain

    Science.gov (United States)

    Devi, Jutika; Saikia, Rashmi; Datta, Pranayee

    2016-10-01

    The present paper describes the study of core-shell nanoparticles for application as nanoantenna in the optical domain. To obtain the absorption and extinction efficiencies as well as the angular distribution of the far field radiation pattern and the resonance wavelengths for these metal-dielectric, dielectric-metal and metal-metal core-shell nanoparticles in optical domain, we have used Finite Element Method based COMSOL Multiphysics Software and Mie Theory. From the comparative study of the extinction efficiencies of core-shell nanoparticles of different materials, it is found that for silica - gold core - shell nanoparticles, the resonant wavelength is greater than that of the gold - silver, silver-gold and gold-silica core - shell nanoparticles and also the radiation pattern of the silica-gold core-shell nanoparticle is the most suitable one from the point of view of directivity. The dielectric functions of the core and shell material as well as of the embedded matrix are extremely important and plays a very major role to tune the directivity and resonance wavelength. Such highly controllable parameters of the dielectric - metal core - shell nanoparticles make them suitable for efficient coupling of optical radiation into nanoscale structures for a broad range of applications in the field of communications.

  12. Optical Absorption and Scattering Properties of Normal and Defective Pickling Cucumbers for 700-1000 nm

    Science.gov (United States)

    Internal defect in pickling cucumbers can cause bloater damage during brining, which lowers the quality of final pickled products and results in economic loss for the pickle industry. Hence it is important to have an effective optical inspection system for detection and segregation of defective pick...

  13. Testing of Cerex Open-Path Ultraviolet Differential Optical Absorption Spectroscopy Systems for Fenceline Monitoring Applications

    Science.gov (United States)

    Development of cost-effective, time-resolved fenceline measurement methods that facilitate improved emissions mitigation strategies is of growing interest to both industry and regulators. Ground-based optical remote sensing (ORS) is a well-known class of technical approaches use...

  14. Testing of Cerex Open-Path Ultraviolet Differential Optical Absorption Spectroscopy System for Fenceline Monitoring Applications

    Science.gov (United States)

    Development of cost-effective, time-resolved fenceline measurement methods that facilitate improved emissions mitigation strategies is of growing interest to both industry and regulators. Ground-based optical remote sensing (ORS) is a well-known class of technical approaches use...

  15. Effect of Molar Concentration on Optical Absorption Spectra of ZnS:Mn Nanoparticles

    Directory of Open Access Journals (Sweden)

    Ravi Sharma

    2010-01-01

    Full Text Available The present paper reports the synthesis and characterization of luminescent nanocrystals of manganese doped zinc sulphide. Nanocrystals of zinc sulphide were prepared by chemical precipitation method using the solution of zinc chloride, sodium sulphide, manganese chloride and mercaptoethanol was used as the capping agent. It was found that change in the molar concentration changes the particle size. The particle size of such nanocrystals was measured using XRD pattern and it is found to be in between 3 nm – 5 nm. The blue-shift in absorption spectra was found with reducing size of the nanoparticles

  16. Linear and nonlinear intra-conduction band optical absorption in (In,Ga)N/GaN spherical QD under hydrostatic pressure

    Science.gov (United States)

    El Ghazi, Haddou; Jorio, Anouar; Zorkani, Izeddine

    2014-11-01

    Linear, third-order nonlinear and total optical absorption coefficients of intra-conduction band 1s-1p transition with hydrogenic shallow-donor impurity in wurtzite (In,Ga)N/GaN spherical quantum dot are reported. Hydrostatic pressure effect is investigated within the framework of single band effective-mass approximation using a combination of Quantum Genetic Algorithm (QGA) and Hartree-Fock-Roothaan (HFR) method. The results show that the pressure has a great influence on optical absorption coefficients of QDs. A blue-shift of the resonant peak is observed while the maximum of the amplitude of optical absorption coefficients decreases under hydrostatic pressure effect. A good agreement is shown compared with results of the finding.

  17. Electronic structure and optical properties of CdS{sub x}Se{sub 1−x} solid solution nanostructures from X-ray absorption near edge structure, X-ray excited optical luminescence, and density functional theory investigations

    Energy Technology Data Exchange (ETDEWEB)

    Murphy, M. W. [DESY (Deutsches Elektronen-Synchrotron), FS-PEX, Notkestrasse 85, 22607 Hamburg (Germany); Yiu, Y. M., E-mail: yyiu@uwo.ca; Sham, T. K. [Department of Chemistry, University of Western Ontario, London, ON N6A5B7 (Canada); Ward, M. J. [Cornell High Energy Synchrotron Source (CHESS), Cornell University, Ithaca, NY 14853 (United States); Liu, L. [Institute of Functional Nano and Soft Materials (FUNSOM) and Soochow University-Western University Center for Synchrotron Radiation Research, Soochow University, Suzhou, Jiangsu, 215123 (China); Hu, Y. [Canadian Light Source, University of Saskatchewan, Saskatoon, SK S7N2V3 (Canada); Zapien, J. A. [Center Of Super-Diamond and Advanced Films (COSDAF) and Department of Physics and Materials Science, City University of Hong Kong, Hong Kong SAR (China); Liu, Yingkai [Institute of Physics and Electronic Information, Yunnan Normal University, Kunming, Yunnan, 650500 (China)

    2014-11-21

    The electronic structure and optical properties of a series of iso-electronic and iso-structural CdS{sub x}Se{sub 1−x} solid solution nanostructures have been investigated using X-ray absorption near edge structure, extended X-ray absorption fine structure, and X-ray excited optical luminescence at various absorption edges of Cd, S, and Se. It is found that the system exhibits compositions, with variable local structure in-between that of CdS and CdSe accompanied by tunable optical band gap between that of CdS and CdSe. Theoretical calculation using density functional theory has been carried out to elucidate the observations. It is also found that luminescence induced by X-ray excitation shows new optical channels not observed previously with laser excitation. The implications of these observations are discussed.

  18. Changes in the optical absorption induced by sequential exposition to short- and long-wavelength radiation in the BTO:Al crystal

    Science.gov (United States)

    Shandarov, S. M.; Dyu, V. G.; Kisteneva, M. G.; Khudyakova, E. S.; Smirnov, S. V.; Akrestina, A. S.; Kargin, Yu F.

    2017-02-01

    Modifications of the spectral dependences of the optical absorption induced in the Bi12TiO20:Al crystal as a result of sequential exposition to cw laser radiation first with the wavelength λ g = 532 nm and then with the longer wavelength λ l,n = 588, 633, 655, 658, 663, 700, 780, 871, or 1064 nm are investigated. We revealed that after the short-wavelength exposition to radiation with λg = 532 nm, the optical absorption in the crystal increases, and in the range 470–1000 nm, yields the spectrum whose form is independent of a prehistory. The subsequent exposition to longer-wavelength radiation leads to bleaching of the crystal in the examined spectral range. A maximum diminishing of the optical absorption in the crystal is observed upon exposure to radiation with the wavelength λ l,5 = 663 nm. To describe the experimentally observed reversible changes in the optical absorption spectrum in the Bi12TiO20:Al we use the impurity absorption model that takes into account the photoinduced transitions between two metastable states of a deep defect center leading to the change of its position in the crystal lattice under conditions of strong lattice relaxation.

  19. Study of nonlinear optical absorption properties of V{sub 2}O{sub 5} nanoparticles in the femtosecond excitation regime

    Energy Technology Data Exchange (ETDEWEB)

    Molli, Muralikrishna; Bhat Kademane, Abhijit; Pradhan, Prabin; Sai Muthukumar, V. [Sri Sathya Sai Institute of Higher Learning, Department of Physics, Puttaparthi, Andhra Pradesh (India)

    2016-08-15

    In this work, we report for the first time, the nonlinear optical absorption properties of vanadium pentoxide (V{sub 2}O{sub 5}) nanoparticles in the femtosecond excitation regime. V{sub 2}O{sub 5} nanoparticles were synthesized through solution combustion technique. The as-synthesized samples were further characterized using XRD, FESEM, EDAX, TEM and UV-visible spectroscopy. X-ray diffraction results revealed the crystalline nature of the nanoparticles. Electron microscopy studies showed the size of the nanoparticles to be ∝200 nm. Open-aperture z-scan technique was employed to study the nonlinear optical absorption behavior of the synthesized samples using a 100-fs laser pulses at 800 nm from a regeneratively amplified Ti: sapphire laser. The mechanism of nonlinear absorption was found to be a three-photon absorption process which was explained using the density of states of V{sub 2}O{sub 5} obtained using density functional theory. These nanoparticles exhibit strong intensity-dependent nonlinear optical absorption and hence could be considered for optical-power-limiting applications. (orig.)

  20. X-ray absorption fine structure and X-ray excited optical luminescence studies of II-VI semiconducting nanostructures

    Science.gov (United States)

    Murphy, Michael Wayne

    2010-06-01

    Various II-VI semiconducting nanomaterials such as ZnO-ZnS nanoribbons (NRs), CdSxSe1-x nanostructures, ZnS:Mn NRs, ZnS:Mn,Eu nanoprsims (NPs), ZnO:Mn nanopowders, and ZnO:Co nanopowders were synthesized for study. These materials were characterized by techniques such as scanning electron microscopy, transmission electron microscopy, element dispersive X-ray spectroscopy, selected area electron diffraction, and X-ray diffraction. The electronic and optical properties of these nanomaterials were studied by X-ray absorption fine structure (XAFS) spectroscopy and X-ray excited optical luminescence (XEOL) techniques, using tuneable soft X-rays from a synchrotron light source. The complementary nature ofthe XAFS and XEOL techniques give site, element and chemical specific measurements which allow a better understanding of the interplay and role of each element in the system. Chemical vapour deposition (CVD) of ZnS powder in a limited oxygen environment resulted in side-by-side biaxial ZnO-ZnS NR heterostructures. The resulting NRs contained distinct wurtzite ZnS and wurtzite ZnO components with widths of 10--100 nm and 20 --500 nm, respectively and a uniform interface region of 5-15 nm. XAFS and XEOL measurements revealed the luminescence of ZnO-ZnS NRs is from the ZnO component. The luminescence of CdSxSe1-x nanostructures is shown to be dependent on the S to Se ratio, with the band-gap emission being tunable between that of pure CdS and CdSe. Excitation of the CdSxSe 1-x nanostructures by X-ray in XEOL has revealed new de-excitation channels which show a defect emission band not seen by laser excitation. CVD of Mn2+ doped ZnS results in nanostructures with luminescence dominated by the yellow Mn2+ emission due to energy transfer from the ZnS host to the Mn dopant sites. The addition of EuCl3 to the reactants in the CVD process results in a change in morphology from NR to NP. Zn1-xMnxO and Zn1-xCOxO nanopowders were prepared by sol-gel methods at dopant concentrations

  1. Inverted Ultrathin Organic Solar Cells with a Quasi-Grating Structure for Efficient Carrier Collection and Dip-less Visible Optical Absorption

    Science.gov (United States)

    in, Sungjun; Park, Namkyoo

    2016-02-01

    We propose a metallic-particle-based two-dimensional quasi-grating structure for application to an organic solar cell. With the use of oblate spheroidal nanoparticles in contact with an anode of inverted, ultrathin organic solar cells (OSCs), the quasi-grating structure offers strong hybridization between localized surface plasmons and plasmonic gap modes leading to broadband (300~800 nm) and uniform (average ~90%) optical absorption spectra. Both strong optical enhancement in extreme confinement within the active layer (90 nm) and improved hole collection are thus realized. A coupled optical-electrical multi-physics optimization shows a large (~33%) enhancement in the optical absorption (corresponding to an absorption efficiency of ~47%, AM1.5G weighted, visible) when compared to a control OSC without the quasi-grating structure. That translates into a significant electrical performance gain of ~22% in short circuit current and ~15% in the power conversion efficiency (PCE), leading to an energy conversion efficiency (~6%) which is comparable to that of optically-thick inverted OSCs (3–7%). Detailed analysis on the influences of mode hybridization to optical field distributions, exciton generation rate, charge carrier collection efficiency and electrical conversion efficiency is provided, to offer an integrated understanding on the coupled optical-electrical optimization of ultrathin OSCs.

  2. Inverted Ultrathin Organic Solar Cells with a Quasi-Grating Structure for Efficient Carrier Collection and Dip-less Visible Optical Absorption.

    Science.gov (United States)

    In, Sungjun; Park, Namkyoo

    2016-02-23

    We propose a metallic-particle-based two-dimensional quasi-grating structure for application to an organic solar cell. With the use of oblate spheroidal nanoparticles in contact with an anode of inverted, ultrathin organic solar cells (OSCs), the quasi-grating structure offers strong hybridization between localized surface plasmons and plasmonic gap modes leading to broadband (300~800 nm) and uniform (average ~90%) optical absorption spectra. Both strong optical enhancement in extreme confinement within the active layer (90 nm) and improved hole collection are thus realized. A coupled optical-electrical multi-physics optimization shows a large (~33%) enhancement in the optical absorption (corresponding to an absorption efficiency of ~47%, AM1.5G weighted, visible) when compared to a control OSC without the quasi-grating structure. That translates into a significant electrical performance gain of ~22% in short circuit current and ~15% in the power conversion efficiency (PCE), leading to an energy conversion efficiency (~6%) which is comparable to that of optically-thick inverted OSCs (3-7%). Detailed analysis on the influences of mode hybridization to optical field distributions, exciton generation rate, charge carrier collection efficiency and electrical conversion efficiency is provided, to offer an integrated understanding on the coupled optical-electrical optimization of ultrathin OSCs.

  3. Exchanging Ohmic Losses in Metamaterial Absorbers with Useful Optical Absorption for Photovoltaics

    CERN Document Server

    Vora, Ankit; Pala, Nezih; Kulkarni, Anand; Pearce, Joshua M; Güney, Durdu Ö

    2014-01-01

    Using metamaterial absorbers, we have shown that metallic layers in the absorbers do not necessarily constitute undesired resistive heating problem for photovoltaics. Tailoring the geometric skin depth of metals and employing the natural bulk absorbance characteristics of the semiconductors in those absorbers can enable the exchange of undesired resistive losses with the useful optical absorbance in the active semiconductors. Thus, Ohmic loss dominated metamaterial absorbers can be converted into photovoltaic near-perfect absorbers with the advantage of harvesting the full potential of light management offered by the metamaterial absorbers. Based on experimental permittivity data for indium gallium nitride, we have shown that between 75%-95% absorbance can be achieved in the semiconductor layers of the converted metamaterial absorbers. Besides other metamaterial and plasmonic devices, our results may also apply to photodectors and other metal or semiconductor based optical devices where resistive losses and p...

  4. Multibeam long-path differential optical absorption spectroscopy instrument: a device for simultaneous measurements along multiple light paths.

    Science.gov (United States)

    Pundt, Irene; Mettendorf, Kai Uwe

    2005-08-10

    A novel long-path differential optical absorption spectroscopy (DOAS) apparatus for measuring tropospheric trace gases and the first results from its use are presented: We call it the multibeam instrument. It is the first active DOAS device that emits several light beams simultaneously through only one telescope and with only one lamp as a light source, allowing simultaneous measurement along multiple light paths. In contrast to conventional DOAS instruments, several small mirrors are positioned near the lamp, creating multiple virtual light sources that emit one light beam each in one specific direction. The possibility of error due to scattering between the light beams is negligible. The trace-gas detection limits of NO2, SO2, O3, and H2CO are similar to those of the traditional long-path DOAS instrument.

  5. Optical control of cardiac cell excitability based on two-photon infrared absorption of AzoTAB

    CERN Document Server

    Shcherbakov, D; Erofeev, I; Astafiev, A

    2014-01-01

    Recent studies of AzoTAB activity in excitable cell cultures have shown that this substance is able to control excitability depending on isomer, cis or trans, predominating in the cellular membrane. Control of isomerization can be performed noninvasively by UV-visual radiation. At the same time it is well-known that azobenezenes can be effectively transformed from one isomer into another by two-photon absorption. Current work is devoted to the study of trans-AzoTAB two-photon transformation in aqueous solution and inside primal neonatal contractive rat cardiomyocytes. In accordance with results obtained Azo-TAB can be used as a probe for two-photon optical control of cardiac excitability.

  6. Spatially resolved measurements of nitrogen dioxide in an urban environment using concurrent multi-axis differential optical absorption spectroscopy

    Directory of Open Access Journals (Sweden)

    R. J. Leigh

    2006-12-01

    Full Text Available A novel system using the technique of concurrent multi-axis differential optical absorption spectroscopy system has been developed and applied to the measurement of nitrogen dioxide in an urban environment. Using five fixed telescopes, slant columns of nitrogen dioxide, ozone, water vapour, and the oxygen dimer, O4, are simultaneously retrieved in five vertically separated viewing directions. The application of this remote sensing technique in the urban environment is explored. Through, the application of several simplifying assumptions a tropospheric concentration of NO2 is derived and compared with an urban background in-situ chemiluminescence detector. The remote sensing and in-situ techniques show good agreement. Owing to the high time resolution of the measurements, the ability to image and quantify plumes within the urban environment is demonstrated. The CMAX-DOAS measurements provide a useful measure of overall NO2 concentrations on a city-wide scale.

  7. Extremely asymmetric diffraction as a method of determining magneto-optical constants for X-rays near absorption edges

    Energy Technology Data Exchange (ETDEWEB)

    Andreeva, M. A., E-mail: Mandreeva1@yandex.ru [Moscow State University (Russian Federation); Repchenko, Yu. L., E-mail: kent160@mail.ru [Voronezh State University (Russian Federation); Smekhova, A. G. [Moscow State University (Russian Federation); Dumesnil, K. [University of Lorraine, Institut Jean Lamour (UMR CNRS 7198) (France); Wilhelm, F.; Rogalev, A. [European Synchrotron Radiation Facility (France)

    2015-06-15

    The spectral dependence of the Bragg peak position under conditions of extremely asymmetric diffraction has been analyzed in the kinematical and dynamical approximations of the diffraction theory. Simulations have been performed for the L{sub 3} absorption edge of yttrium in a single-crystal YFe{sub 2} film; they have shown that the magneto-optical constants (or, equivalently, the dispersion corrections to the atomic scattering factor) for hard X-rays can be determined from this dependence. Comparison with the experimental data obtained for a Nb(4 nm)/YFe{sub 2}(40 nm〈110〉)/Fe(1.5 nm)/Nb(50 nm)/sapphire sample at the European Synchrotron Radiation Facility has been made.

  8. Bandgap widening in thermochromic Mg-doped VO{sub 2} thin films: Quantitative data based on optical absorption

    Energy Technology Data Exchange (ETDEWEB)

    Li, Shu-Yi; Niklasson, Gunnar A.; Granqvist, Claes G. [Department of Engineering Sciences, The Ångström Laboratory, Uppsala University, P.O. Box 534, SE-75121 Uppsala (Sweden); Mlyuka, Nuru R. [Department of Engineering Sciences, The Ångström Laboratory, Uppsala University, P.O. Box 534, SE-75121 Uppsala (Sweden); Department of Physics, University of Dar es Salaam, P.O. Box 35063, Dar es Salaam (Tanzania, United Republic of); Primetzhofer, Daniel; Possnert, Göran [Department of Physics and Astronomy, The Ångström Laboratory, Uppsala University, P.O. Box 516, SE-75120 Uppsala (Sweden); Hallén, Anders [KTH-ICT, Royal Institute of Technology, Electrum 229, SE-164 40 Kista-Stockholm (Sweden)

    2013-10-14

    Thermochromic Mg-doped VO{sub 2} films were deposited by reactive direct current magnetron sputtering onto heated glass and carbon substrates. Elemental compositions were inferred from Rutherford backscattering. Optical bandgaps were obtained from spectral transmittance and reflectance measurements—from both the film side and the back side of the samples—and ensuing determination of absorption coefficients. The bandgap of Mg-doped films was found to increase by 3.9 ± 0.5 eV per unit of atom ratio Mg/(Mg + V) for 0 < Mg/(Mg + V) < 0.21. The presence of ∼0.45 at. % Si enhanced the bandgap even more.

  9. Optical reading of field-effect transistors by phase-space absorption quenching in a single InGaAs quantum well conducting channel

    Science.gov (United States)

    Chemla, D. S.; Bar-Joseph, I.; Klingshirn, C.; Miller, D. A. B.; Kuo, J. M.

    1987-03-01

    Absorption switching in a semiconductor quantum well by electrically varying the charge density in the quantum well conducting channel of a selectively doped heterostructure transistor is reported for the first time. The phase-space absorption quenching (PAQ) is observed at room temperature in an InGaAs/InAlAs grown on InP FET, and it shows large absorption coefficient changes with relatively broad spectral bandwidth. This PAQ is large enough to be used for direct optical determination of the logic state of the FET.

  10. Optical absorption red and blue shifts in ZnFe{sub 2}O{sub 4} nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Kislov, N. [Clean Energy Research Center, College of Engineering, University of South Florida, 4202 East Fowler Avenue, Tampa, FL 33620 (United States)], E-mail: nikolai@eng.usf.edu; Srinivasan, S.S. [Clean Energy Research Center, College of Engineering, University of South Florida, 4202 East Fowler Avenue, Tampa, FL 33620 (United States)], E-mail: sesha@eng.usf.edu; Emirov, Yu. [Nanomaterials and Nanomanufacturing Research Center, College of Engineering, University of South Florida, 4202 East Fowler Avenue, Tampa, FL 33620 (United States); Stefanakos, E.K. [Clean Energy Research Center, College of Engineering, University of South Florida, 4202 East Fowler Avenue, Tampa, FL 33620 (United States)

    2008-09-25

    Nanoparticles of zinc ferrite (ZnFe{sub 2}O{sub 4}) prepared by both wet- and dry-high-energy ball milling (HEBM), have been investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), high resolution transmission electron microscopy (HRTEM), atomic force microscopy (AFM), surface area and pore size distribution (BET) and wavelength-dependent diffuse reflectance and scattering turned into absorption coefficient estimation using the Kubelka-Munk theory. It was found that after 72 h of HEBM, the particle size was decreased from 220 nm for the initial material to 16.5 nm and 9.4 nm for the wet- and dry-milled samples, respectively. The optical absorption analysis revealed that the energy gap is increased (blue shift) for wet-milled and decreased ('anomalous' red shift) for dry-milled samples of ZnFe{sub 2}O{sub 4} as the particle size decreased. The likely origins for the phenomena, namely the blue and red shifts as large as 0.45 eV and 0.14 eV, respectively, are proposed and discussed, and the effects are quantitatively estimated.

  11. Optical Absorption Measurement at 1550 nm on a Highly-Reflective Si/SiO$_2$ Coating Stack

    CERN Document Server

    Steinlechner, Jessica; Schnabel, Roman

    2014-01-01

    Future laser-interferometric gravitational wave detectors (GWDs) will potentially employ test mass mirrors from crystalline silicon and a laser wavelength of $1550\\,\\rm{nm}$, which corresponds to a photon energy below the silicon bandgap. Silicon might also be an attractive high-refractive index material for the dielectric mirror coatings. Films of amorphous silicon (a-Si), however, have been found to be significantly more absorptive at $1550\\,\\rm{nm}$ than crystalline silicon (c-Si). Here, we investigate the optical absorption of a Si/SiO$_2$ dielectric coating produced with the ion plating technique. The ion plating technique is distinct from the standard state-of-the-art ion beam sputtering technique since it uses a higher processing temperature of about 250$^\\circ$C, higher particle energies, and generally results in higher refractive indices of the deposited films. Our coating stack was fabricated for a reflectivity of $R=99.95\\,\\%$ for s-polarized light at $1550\\,\\rm{nm}$ and for an angle of incidence o...

  12. Study of optical absorption and photoluminescence of quantum dots of CdS formed in borosilicate glass matrix

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, Jitender; Verma, A; Pandey, P K; Bhatnagar, P K; Mathur, P C [Department of Electronic Science, University of Delhi South Campus, Benito Juarez Road, New Delhi-110021 (India); Liu, W; Tang, S H [Department of Physics, National University of Singapore, 119243 (Singapore)], E-mail: jitender_does@yahoo.co.in

    2009-06-15

    Optical absorption and photoluminescence (PL) measurements have been made on the quantum dots (QDs) of CdS grown in a borosilicate glass matrix using a two-step annealing technique. The absorption measurements, made in the energy range of 1.3-3.2 eV, indicate the presence of nonradiative trap centers located in the forbidden gap at an energy level near 1.5 eV. The origin of these traps is attributed to the impurities present in the glass matrix. The PL measurements have been made at an excitation energy of 2.75 eV and it is concluded that the origin of PL is not due to either direct recombination of electrons and holes or deep traps, but that it is the shallow traps which are responsible for the observed PL. The shallow traps are attributed to sulfur vacancies formed at the glass-QD interface. The reason for the observed decrease in PL peak intensity with the increase of annealing time is due to the decrease of surface to volume ratio for QDs of higher size.

  13. Optical absorption and photoluminescence properties of ZnO/PMMA nanocomposite films

    Energy Technology Data Exchange (ETDEWEB)

    Kulyk, B; Kapustianyk, V [Department of Physics, Scientific and Educational Center ' Fractal' , Scientific-Technical and Educational Center of Low Temperature Studies, Ivan Franko National University of L' viv, 50 Dragomanova Str., L' viv (Ukraine); Krupka, O [Department of Chemistry, Kyiv Taras Shevchenko National University, 60 Volodymyrska Str., Kyiv (Ukraine); Sahraoui, B, E-mail: bohdan_kulyk@yahoo.com [Department of Physics, University of Angers, 2 Lavoisier Av., Angers (France)

    2011-04-01

    The ZnO nanocrystals (ZnO NCs) with particle size, less than 100 nm, have been blended with polymethylmethacrylate (PMMA) by solution mixing to prepare PMMA/ZnO nanocomposite films. The structure of ZnO/PMMA nanocomposite films was characterized using X-ray diffractometry. The prepared nanocomposite films are highly transparent and a clear excitonic peak is observed in their absorption spectra. Measurements of temperature evolution of the photoluminescence (PL) spectra show intensive UV emission peak corresponding to the donor-bound excitons with binding energy of 51 meV and green emission band related to the intrinsic defects in ZnO. The temperature evolution of the emission peaks energy position, intensity and integral intensity in ZnO/PMMA nanocomposite films were examined.

  14. Optical Absorption and Visible Photoluminescence from Thin Films of Silicon Phthalocyanine Derivatives

    Directory of Open Access Journals (Sweden)

    Arturo Rodríguez Gómez

    2014-09-01

    Full Text Available The interest of microelectronics industry in new organic compounds for the manufacture of luminescent devices has increased substantially in the last decade. In this paper, we carried out a study of the usage feasibility of three organic bidentate ligands (2,6-dihydroxyanthraquinone, anthraflavic acid and potassium derivative salt of anthraflavic acid for the synthesis of an organic semiconductor based in silicon phthalocyanines (SiPcs. We report the visible photoluminescence (PL at room temperature obtained from thermal-evaporated thin films of these new materials. The surface morphology of these films was analyzed by atomic force microscopy (AFM and scanning electron microscopy (SEM. AFM indicated that the thermal evaporation technique is an excellent resource in order to obtain low thin film roughness when depositing these kinds of compounds. Fourier transform infrared spectroscopy (FTIR spectroscopy was employed to investigate possible changes in the intra-molecular bonds and to identify any evidence of crystallinity in the powder compounds and in the thin films after their deposition. FTIR showed that there was not any important change in the samples after the thermal deposition. The absorption coefficient (α in the absorption region reveals non-direct transitions. Furthermore, the PL of all the investigated samples were observed with the naked eye in a bright background and also measured by a spectrofluorometer. The normalized PL spectra showed a Stokes shift ≈ 0.6 eV in two of our three samples, and no PL emission in the last one. Those results indicate that the Vis PL comes from a recombination of charge carriers between conduction band and valence band preceded by a non-radiative relaxation in the conduction band tails.

  15. Intense Photoluminescence and Movement of OpticalAbsorption Edge in Alumina Aerogels

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Alumina aerogels with high porosity of nanometer size were prepared from Al, n-butanol andethyl acetoacetate by the sol-gel route and the N2 supercritical extraction drying technique.Optical experiment results showed that for alumina aerogels after annealing at 500℃ for 4 h pneintense blue emission band appeared in the wavelength range of 400 to 800 nm, and the opticalabsorption edge moved from 8.0 eV of coarse grain Al2O3 to 3~5 eV and with increasing theannealing temperature, this luminescence band presented blue shifts. The reasons of these newoptical properties are discussed in detail.

  16. Absorption spectroscopy of single red blood cells in the presence of mechanical deformations induced by optical traps

    Science.gov (United States)

    Wojdyla, Michal; Raj, Saurabh; Petrov, Dmitri

    2012-09-01

    The electronic properties of single human red blood cells under mechanical deformations were investigated using a combination of dual beam optical tweezers and UV-vis absorption spectroscopy. The mechanical deformations were induced by two near-infrared optical traps with different trapping powers and trap configurations. The deformations were applied in two ways: locally, due to the mechanical forces around the traps, and by stretching the cell by moving the traps in opposite directions. In the presence of local deformations, the single cell undergoes a transition from an oxygenated state to a partially deoxygenated state. This process was found to be reversible and strongly power-dependent. Stretching the cell caused an opposite effect, indicating that the electronic response of the whole cell is dominated by the local interaction with the trapping beams. Results are discussed considering light-induced local heating, the Stark effect, and biochemical alterations due to mechanical forces, and are compared with reports of previous Raman spectroscopy studies. The information gained by the analysis of a single red blood cell's electronic response facilitates the understanding of fundamental physiological processes and sheds further light on the cell's mechanochemistry. This information may offer new opportunities for the diagnosis and treatment of blood diseases.

  17. Donor impurity-related optical absorption coefficients and refractive index changes in a rectangular GaAs quantum dot in the presence of electric field

    Science.gov (United States)

    Sheng, Wang; Yun, Kang; Xianli, Li

    2016-11-01

    Within the quasi-one-dimensional effective potential model and effective mass approximation, we obtain the wavefunctions and energy eigenvalues of the ground (j = 1) and first 2 excited states (j = 2 and 3) of a donor impurity in a rectangular GaAs quantum dot in the presence of electric field. The donor impurity-related linear and nonlinear optical absorption as well as refractive index changes for the transitions j = 1-2 and j = 2-3 are investigated. The results show that the impurity position, incident optical intensity and electric field play important roles in the optical absorption coefficients and refractive index changes. We find that the impurity effect induces the blueshift for j = 1-2 and redshift for j = 3-2 in the absence of the electric field, but it leads to redshift for j = 1-2 and blueshift for j = 3-2 in the existence of the field. Also, the optical coefficient for the higher energy transitions j = 2-3 is insensitive to variation of impurity positions, while that for the low energy transition j = 1-2 depends significantly on the positions of impurity. In addition, the saturation and splitting phenomenon of the optical absorption are observed as the incident optical intensity increases. Project supported by the Science and Technology Project of Education Department of Heilongjiang Province of China (No. 12541070).

  18. 双量子阱中的子带光吸收%Intersubband Optical Absorption in Double Quantum Wells

    Institute of Scientific and Technical Information of China (English)

    邓永晴; 郭康贤; 于凤梅; 俞友宾; 王瑞强

    2005-01-01

    Recently, much attention has been focus on the investigation of the electroabsorption in the GaAs/AlGaAs quantum wells (QW's) because of its possibility of designing new types of electro-optic modulators. Much optical properties of the single QW's with different potential has been and being investigated experimently and theoriticaly with different methods. In these few years, the double quantum wells (DQWs) became the focus of the research. In this paper, by using the density matrix formalism and iterated method, the first-and the third-order intersubband optical absorption of double quantum well with infinit boundary was investigated theoretically. Thereafter, a typical GaAs/AlGaAs DQWs is presented to get the results. The results show that the peak absorption varies with the width of the intermediate potential barrier. And it also shows that the absorption decrease as the incident optical intensity increasing.%由于微制造技术的不断发展,如液相外延(LPE),气相外延(VPE),金属有机化学气相沉积(MOCVD)以及分子束外延技术(MBE)等先进的材料生长技术方法也日趋完善,从而使得各种低维半导体量子器件(如半导体、超晶格、量子阱、量子线和量子点等)制造日趋成熟.由于这些低维半导体量子器件具有很强的非线性光效应,而且随着材料、外形、尺寸等的不同,非线性光效应也有很大的差别,更由于其可能存在的广泛的应用前景,所以近年来,一直是人们研究的重点.近来,由于人们相信,利用GaAs/AlGaAs量子阱有可能制造出一些新型的光学仪器,如光开关、光限幅器、光调制器等,所以,对不同势形的GaAs/AlGaAs量子阱的非线性光学特性一直吸引着人们进行理论和实验的研究.而在最近几年,对双量子阱的研究也成为了人们的研究重点.通过密度矩阵和迭代的方法,得到双量子阱中的第一、第三阶子带光吸收表达式,我们将用一个典型的GaAs/AlGaAs双

  19. Development And Optical Absorption Properties Of A Laser Induced Plasma During CO2-Laser Processing

    Science.gov (United States)

    Beyer, E.; Bakowsky, L.; Loosen, P.; Poprawe, R.; Herziger, G.

    1984-03-01

    Laser material processing is accompanied by a laser induced plasma in front of the target surface as soon as the laser radiation exceeds a certain critical intensity. For cw CO2-laser machining of metal targets the threshold for plasma onset is about 106 W/cm2. Critical condition for plasma generation at this intensity level is to reach evaporation temperature at the target's surface. At intensity levels exceeding 106 W/cm2 the laser light is interacting with the laser induced plasma and then the plasma in turn interacts with the target. The absorptivity is no longer constant, but increases with increasing intensity of the incident radiation, so that the total amount of power coupled to the target is increasing. This holds up to intensity levels of 2'10 Wicm2. Then the plasma begins to withdraw from the target surface, thus interrupting plasma-target interaction so that the laser power is no longer coupled into the target completely. The results of laser welding (welding depth) in the intensity level of 106 W/cm2 are governed by the product of incident intensity times focus radius, so that welding results are a measure to determine focus radius and laser intensity.

  20. Optical absorption spectra of the uranium (4+) ion in the thorium germanate matrix

    CERN Document Server

    Gajek, Z; Antic-Fidancev, E

    1997-01-01

    Visible and infrared absorption measurements on the U sup 4 sup + ion in tetragonal zircon-type matrix beta-ThGeO sub 4 are reported and analysed in terms of the standard parametrization scheme. The observed 17 main peaks and a number of less intense lines have been assigned and fitted to most of the 32 allowed electric dipole transitions with the root mean square error equal to 65 cm sup - sup 1. The free-ion parameters obtained for the model Hamiltonian, zeta 5f = 1809 cm sup - sup 1 , F sup 2 =43 065 cm sup - sup 1 , F sup 4 =38 977 cm sup - sup 1 and F sup 6 =24 391 cm sup - sup 1 , as well as the corresponding crystal-field parameters, B sub 0 sup 2 =-1790 cm sup - sup 1 , B sub 0 sup 4 =1200 cm sup - sup 1 , B sub 4 sup 4 =3260 cm sup - sup 1 , B sub 0 sup 6 =-3170 cm sup - sup 1 and B sub 4 sup 6 =990 cm sup - sup 1 , agree fairly well with the initial theoretical estimations. The results are discussed in relation to the previous spectroscopic study on the scheelite-type matrix UGeO sub 4. (author)

  1. Optical Absorptions of Oxygenated Carbon Chain Cations in the Gas Phase

    Science.gov (United States)

    Hardy, F.-X.; Rice, C. A.; Chakraborty, A.; Fulara, J.; Maier, J. P.

    2016-06-01

    The gas-phase electronic spectra of linear OC4O+ and a planar C6H2O+ isomer were obtained at a rotational temperature of ≈10 K. Absorption measurements in a 6 K neon matrix were followed by gas-phase observations in a cryogenic radiofrequency ion trap. The origin bands of the 1{}2{{{\\Pi }}}u ≤ftarrow X{}2{{{\\Pi }}}g transition of OC4O+ and the 1{}2A{}2 ≤ftarrow X{}2B1 of HCCC(CO)CCH+ lie at 417.31 ± 0.01 nm and 523.49 ± 0.01 nm, respectively. These constitute the first electronic spectra of oxygenated carbon chain cations studied under conditions that are relevant to the diffuse interstellar bands (DIBs), as both have a visible transition. The recent analysis of the 579.5 nm DIB indicates that small carriers, five to seven heavy atoms, continue to be possible candidates (Huang & Oka 2015). Astronomical implications are discussed regarding this kind of oxygenated molecules.

  2. Cationic cyanine dyes: impact of symmetry-breaking on optical absorption and third-order polarizabilities.

    Science.gov (United States)

    Yesudas, Kada

    2013-11-28

    A systematic study is carried out to find the exact crossover point from symmetric to asymmetric configurations (symmetry-breaking) in a series of cationic cyanine dyes. Hybrid density functional with varying exact-exchange admixture has been used to understand the impact of HF exchange both in the gas phase and in the presence of dielectric medium. This approach provides a basis for understanding the electronic structure and photophysical properties of cyanine dyes. The crossover points predicted using this method are in good agreement with the experiment. The SAC-CI method is used to evaluate the lowest S0 → S1 transition energies in the gas phase. These transitions are preferably dominated by the promotion of an electron from HOMO → LUMO. The average static third-order polarizabilities, [γ], are obtained within the three-state model approximation. The analysis showed that for symmetric cyanines, the calculated [γ] values are large and negative, mainly originated from the large S0 → S1 transition moments and small S0 → S1 transition energies. For asymmetric cyanines, the [γ] values are positive and mainly originate from the large change in the ground and first excited state dipole moments. However, both configurations do not include contributions from the two-photon absorption. Further, the localization of charge densities in the HOMO and LUMO indicates that the symmetric and asymmetric cyanines act as promising materials for molecular wires and molecular switches which are fundamental building blocks for molecular electronic devices.

  3. Design of atmospheric composition monitor based on ultraviolet optical absorption technology

    Institute of Scientific and Technical Information of China (English)

    LI Wen-jun

    2011-01-01

    An open path atmospheric composition monitor is designed based on ultraviolet differential absorption technology.Dark current correction and diode response correction are used to improve the detection limit and Savitzky-Golay filter is used to improve the measurement accuracy.The experimental results show that the designed system has the ability to measure NO and NO2 in real time with reasonable accuracy.The detection limit of the system is about 0.25 ppm for NO and 0.28 ppm for NOr When the concentration level of the target gases is below 100 ppm,the system has good linearity and high measurement accuracy,i.e.,the measurement accuracy is about 2% for NO and about 4% for NO2.The detection limit of dark current can be improved by about 5 to 10 ppb,and the correction of diode response can improve the detection limit by around 30 ppb.Moving window average can improve the detection limit at low concentration levels but will generate more errors at higher concentration leveis.Generally,the designed system meets the requirement of measuring multi-species air pollutants in real time and accurately.

  4. Quantification and parametrization of non-linearity effects by higher-order sensitivity terms in scattered light differential optical absorption spectroscopy

    Science.gov (United States)

    Puķīte, Jānis; Wagner, Thomas

    2016-05-01

    We address the application of differential optical absorption spectroscopy (DOAS) of scattered light observations in the presence of strong absorbers (in particular ozone), for which the absorption optical depth is a non-linear function of the trace gas concentration. This is the case because Beer-Lambert law generally does not hold for scattered light measurements due to many light paths contributing to the measurement. While in many cases linear approximation can be made, for scenarios with strong absorptions non-linear effects cannot always be neglected. This is especially the case for observation geometries, for which the light contributing to the measurement is crossing the atmosphere under spatially well-separated paths differing strongly in length and location, like in limb geometry. In these cases, often full retrieval algorithms are applied to address the non-linearities, requiring iterative forward modelling of absorption spectra involving time-consuming wavelength-by-wavelength radiative transfer modelling. In this study, we propose to describe the non-linear effects by additional sensitivity parameters that can be used e.g. to build up a lookup table. Together with widely used box air mass factors (effective light paths) describing the linear response to the increase in the trace gas amount, the higher-order sensitivity parameters eliminate the need for repeating the radiative transfer modelling when modifying the absorption scenario even in the presence of a strong absorption background. While the higher-order absorption structures can be described as separate fit parameters in the spectral analysis (so-called DOAS fit), in practice their quantitative evaluation requires good measurement quality (typically better than that available from current measurements). Therefore, we introduce an iterative retrieval algorithm correcting for the higher-order absorption structures not yet considered in the DOAS fit as well as the absorption dependence on

  5. Measurement of uranium concentration by molecular absorption spectrophotometry by means optical fibers; Medicion continua de concentracion de uranio por espectrofotometria de absorcion molecular mediante fibras opticas

    Energy Technology Data Exchange (ETDEWEB)

    Gauna, Alberto C.; Pascale, Ariel A. [Comision Nacional de Energia Atomica, Buenos Aires (Argentina). Centro Atomico Ezeiza. Agencia Minipost

    1996-07-01

    An on-line method for measuring the concentration of uranium in uranyl nitrate-nitric acid aqueous solutions is described. The method is based on molecular absorption spectrophotometry with transmission of light by means of optical fibers. It is ideally suited for control and processes development applications. (author)

  6. Infrared Optical Absorption in Low-spin Fe2+-doped SrTiO3

    Energy Technology Data Exchange (ETDEWEB)

    Comes, Ryan B.; Kaspar, Tiffany C.; Heald, Steve M.; Bowden, Mark E.; Chambers, Scott A.

    2016-01-06

    Band gap engineering in SrTiO3 and related titanate perovskites has long been explored due to the intriguing properties of the materials for photocatalysis and photovoltaic applications. A popular approach in the materials chemistry community is to substitutionally dope aliovalent transition metal ions onto the B site in the lattice to alter the valence band. However, in such a scheme there is limited control over the dopant valence, and compensating defects often form. Here we demonstrate a novel technique to controllably synthesize Fe2+- and Fe3+-doped SrTiO3 thin films without formation of compensating defects by co-doping with La3+ ions on the A site. We stabilize Fe2+-doped films by doping with two La ions for every Fe dopant, and find that the Fe ions exhibit a low-spin electronic configuration, producing optical transitions in the near infrared regime and degenerate doping. The novel electronic states observed here offer a new avenue for band gap engineering in perovskites for photocatalytic and photovoltaic applications.

  7. Influence of the ``second gap'' on the optical absorption of transparent conducting oxides

    Science.gov (United States)

    Ha, Viet-Anh; Waroquiers, David; Rignanese, Gian-Marco; Hautier, Geoffroy

    Transparent conducting oxides (TCOs) are critical to many technologies (e.g., thin-film solar cells, flat-panel displays or organic light-emitting diodes). TCOs are heavily doped (n or p-type) oxides that satisfy many design criteria such as high transparency to visible light (i.e., a band gap > 3 eV), high concentration and mobility of carriers (leading to high conductivity), ... In such (highly doped) systems, optical transitions from the conduction band minimum to higher energy bands in n-type or from lower energy bands to the valence band maximum in p-type are possible and can degrade transparency. In fact, it has been claimed that a high energy (> 3eV) for any of these transitions made possible by doping, commonly referred as a high ``second gap'', is a necessary design criterion for high performance TCOs. Here, we study the influence of this second gap on the transparency of doped TCOs by using ab initio calculations within the random phase approximation (RPA) for several well-known p-type and n-type TCOs. Our work highlights how the second gap affects the transparency of doped TCOs, shining light on more accurate design criteria for high performance TCOs.

  8. Electrical conductivity, dielectric properties and optical absorption of organic based nanocrystalline sodium copper chlorophyllin for photodiode application

    Energy Technology Data Exchange (ETDEWEB)

    Farag, A.A.M., E-mail: alaafaragg@yahoo.com [Thin Film Laboratory, Physics Department, Faculty of Education, Ain shams University, PO Box 11757, Roxy, Cairo (Egypt); Mansour, A.M. [Solid State Electronics Laboratory, Physics Department, Physics Division, National Research Center, Dokki, Giza (Egypt); Ammar, A.H. [Thin Film Laboratory, Physics Department, Faculty of Education, Ain shams University, PO Box 11757, Roxy, Cairo (Egypt); Rafea, M. Abdel [Electronic Materials Department, Advanced Technologies and New Materials Institute, City for Scientific Research and Technology Applications, PO Box 21934, New Borg El-Arab City, Alexandria (Egypt); Farid, A.M. [Thin Film Laboratory, Physics Department, Faculty of Education, Ain shams University, PO Box 11757, Roxy, Cairo (Egypt)

    2012-02-05

    applied and the type of the optical transitions responsible for optical absorption was found to be direct allowed transition. Position dependent for SCC thin film photo-detector was studied by using laser diode source.

  9. Differential optical absorption spectroscopy (DOAS and air mass factor concept for a multiply scattering vertically inhomogeneous medium: theoretical consideration

    Directory of Open Access Journals (Sweden)

    V. V. Rozanov

    2010-06-01

    Full Text Available The Differential Optical Absorption Spectroscopy (DOAS technique is widely used to retrieve amounts of atmospheric species from measurements of the direct solar light transmitted through the Earth's atmosphere as well as of the solar light scattered in the atmosphere or reflected from the Earth's surface. For the transmitted direct solar light the theoretical basis of the DOAS technique represented by the Beer-Lambert law is well studied. In contrast, scarcely investigated is the theoretical basis and validity range of the DOAS method for those cases where the contribution of the multiple scattering processes is not negligible. Our study is intended to fill this gap by means of a theoretical investigation of the applicability of the DOAS technique for the retrieval of amounts of atmospheric species from observations of the scattered solar light with a non-negligible contribution of the multiple scattering.

    Starting from the expansion of the intensity logarithm in the functional Taylor series we formulate the general form of the DOAS equation. The thereby introduced variational derivative of the intensity logarithm with respect to the variation of the gaseous absorption coefficient, which is often referred to as the weighting function, is demonstrated to be closely related to the air mass factor. Employing some approximations we show that the general DOAS equation can be rewritten in the form of the weighting function (WFDOAS, the modified (MDOAS, and the standard DOAS equations. For each of these forms a specific equation for the air mass factor follows which, in general, is not suitable for other forms of the DOAS equation. Furthermore, the validity range of the standard DOAS equation is quantitatively investigated using a suggested criterion of a weak absorption.

    The results presented in this study are intended to provide a basis for a better understanding of the applicability range of different forms of the DOAS equation as

  10. Photothermal deflection spectroscopy for the study of thin films and optical coatings: measurements of absorption losses and detection of photoinduced changes

    Science.gov (United States)

    Commandre, Mireille; Roche, Pierre J.; Albrand, Gerard; Pelletier, Emile P.

    1990-08-01

    Photothermal deflection has been used to map the absorption characteristics of thin film optical coatings. Our experimental set-up can give low level absorption coefficient down to 1 ppm, with a spatial resolution limited by the excitating laser beam diameter (100 tim). On single layer films, we can calculate extinction coefficient of the deposited material with a detectivity of a few i07. We present a study of absorption losses in single layer titania films and in TiOWSiO2 Fabry-Perot filters prepared in our laboratory by electron beam evaporation, ion assisted deposition and ion plating. Local variations of absorption on the sample surface can be very large especially in lowly absorbing samples; high absorption sites may be related to local defects responsible for laser damage. Furthermore, we show that some titania films can present photoinduced instabilities. Photothermal deflection spectroscopy is a good way to study absorption evolution under illumination. In Ti02/Si02 Fabry-Perot filters, we have observed that these absorption changes are associated with important drifts of transmission curves. So these instabilities can be explained by a change of the value of the complex index Ii = n - ik. Results lead to the conclusion that stability under illumination is strongly correlated to the deposition technique and also to the deposition conditions: unstable samples are mostly prepared by electron beam evaporation.

  11. Optical absorption characteristics in the assessment of powder phosphor-based x-ray detectors: from nano- to micro-scale.

    Science.gov (United States)

    Liaparinos, P F

    2015-11-21

    X-ray phosphor-based detectors have enormously improved the quality of medical imaging examinations through the optimization of optical diffusion. In recent years, with the development of science and technology in the field of materials, improved powder phosphors require structural and optical properties that contribute to better optical signal propagation. The purpose of this paper was to provide a quantitative and qualitative understanding of the optical absorption characteristics in the assessment of powder phosphor-based detectors (from nano- scale up to micro-scale). Variations on the optical absorption parameters (i.e. the light extinction coefficient [Formula: see text] and the percentage probability of light absorption p%) were evaluated based on Mie calculations examining a wide range of light wavelengths, particle refractive indices and sizes. To model and assess the effects of the aforementioned parameters on optical diffusion, Monte Carlo simulation techniques were employed considering: (i) phosphors of different layer thickness, 100 μm (thin layer) and 300 μm (thick layer), respectively, (ii) light extinction coefficient values, 1, 3 and 6 μm(-1), and (iii) percentage probability of light absorption p% in the range 10(-4)-10(-2). Results showed that the [Formula: see text] coefficient is high for phosphor grains in the submicron scale and for low light wavelengths. At higher wavelengths (above 650 nm), optical quanta follow approximately similar depths until interaction for grain diameter 500 nm and 1 μm. Regarding the variability of the refractive index, high variations of the [Formula: see text] coefficient occurred above 1.6. Furthermore, results derived from Monte Carlo modeling showed that high spatial resolution phosphors can be accomplished by increasing the [Formula: see text] parameter. More specifically, the FWHM was found to decrease (i.e. higher resolution): (i) 4.8% at 100 μm and (ii) 9.5%, at 300 μm layer thickness. This study

  12. "Darker-than-black" PbS quantum dots: enhancing optical absorption of colloidal semiconductor nanocrystals via short conjugated ligands.

    Science.gov (United States)

    Giansante, Carlo; Infante, Ivan; Fabiano, Eduardo; Grisorio, Roberto; Suranna, Gian Paolo; Gigli, Giuseppe

    2015-02-11

    Colloidal quantum dots (QDs) stand among the most attractive light-harvesting materials to be exploited for solution-processed optoelectronic applications. To this aim, quantitative replacement of the bulky electrically insulating ligands at the QD surface coming from the synthetic procedure is mandatory. Here we present a conceptually novel approach to design light-harvesting nanomaterials demonstrating that QD surface modification with suitable short conjugated organic molecules permits us to drastically enhance light absorption of QDs, while preserving good long-term colloidal stability. Indeed, rational design of the pendant and anchoring moieties, which constitute the replacing ligand framework leads to a broadband increase of the optical absorbance larger than 300% for colloidal PbS QDs also at high energies (>3.1 eV), which could not be predicted by using formalisms derived from effective medium theory. We attribute such a drastic absorbance increase to ground-state ligand/QD orbital mixing, as inferred by density functional theory calculations; in addition, our findings suggest that the optical band gap reduction commonly observed for PbS QD solids treated with thiol-terminating ligands can be prevalently ascribed to 3p orbitals localized on anchoring sulfur atoms, which mix with the highest occupied states of the QDs. More broadly, we provide evidence that organic ligands and inorganic cores are inherently electronically coupled materials thus yielding peculiar chemical species (the colloidal QDs themselves), which display arising (opto)electronic properties that cannot be merely described as the sum of those of the ligand and core components.

  13. Plasmonic enhancement of the optical absorption and catalytic efficiency of BiVO₄ photoanodes decorated with Ag@SiO₂ core-shell nanoparticles.

    Science.gov (United States)

    Abdi, Fatwa F; Dabirian, Ali; Dam, Bernard; van de Krol, Roel

    2014-08-07

    Recent progress in the development of bismuth vanadate (BiVO4) photoanodes has firmly established it as a promising material for solar water splitting applications. Performance limitations due to intrinsically poor catalytic activity and slow electron transport have been successfully addressed through the application of water oxidation co-catalysts and novel doping strategies. The next bottleneck to tackle is the modest optical absorption in BiVO4, particularly close to its absorption edge of 2.4 eV. Here, we explore the modification of the BiVO4 surface with Ag@SiO2 core-shell plasmonic nanoparticles. A photocurrent enhancement by a factor of ~2.5 is found under 1 sun illumination (AM1.5). We show that this enhancement consists of two contributions: optical absorption and catalysis. The optical absorption enhancement is induced by the excitation of localized surface plasmon resonances in the Ag nanoparticles, and agrees well with our full-field electromagnetic simulations. Far-field effects (scattering) are found to be dominant, with a smaller contribution from near-field plasmonic enhancement. In addition, a significant catalytic enhancement is observed, which is tentatively attributed to the electrocatalytic activity of the Ag@SiO2 nanoparticles.

  14. Generation and healing behavior of radiation-induced optical absorption in fluoride phosphate glasses: The dependence on UV radiation sources and temperature

    Science.gov (United States)

    Natura, U.; Ehrt, D.

    2001-03-01

    High purity fluoride phosphate (FP) glasses have a large transmission range from the vacuum ultraviolet to the infrared. They are attractive candidates for lens systems in microlithography equipment and excimer laser optics. Fluoride single crystals and vitreous silica are well-known traditional materials for ultraviolet optics. Crystal sizes are limited and glass is better for fabricating optics. For lens systems, a variety of glasses with different refractive indices and dispersion are required. The UV resonance wavelengths of FP glasses with a low content of phosphate using a two-term Sellmeier dispersion formula are comparable with those of silica and fluoride single crystals. It is known, that UV radiation induces the generation of several defect centers leading to additional absorption bands. The investigation of the kinetics of defect generation is very important for the prediction of transmission losses in case of long-time irradiation. To predict the kinetics of defect generation, first the separation of absorption bands is necessary. Experiments were carried out using UV-lamps, the KrF excimer laser (ns- and fs-pulses) and the ArF excimer laser (ns-pulses). The healing behavior of radiation-induced absorption bands was investigated using thermal treatment (temperature-dependence) and bleaching experiments (radiation-dependence). The results of these experiments enable the separation of absorption bands and the prediction of the defect generation depending on the used radiation source. The healing of strong defects at room temperature is postulated to be a diffusion-controlled process.

  15. Effect of size and indium-composition on linear and nonlinear optical absorption of InGaN/GaN lens-shaped quantum dot

    Science.gov (United States)

    Ahmed, S. Jbara; Zulkafli, Othaman; M, A. Saeed

    2016-05-01

    Based on the Schrödinger equation for envelope function in the effective mass approximation, linear and nonlinear optical absorption coefficients in a multi-subband lens quantum dot are investigated. The effects of quantum dot size on the interband and intraband transitions energy are also analyzed. The finite element method is used to calculate the eigenvalues and eigenfunctions. Strain and In-mole-fraction effects are also studied, and the results reveal that with the decrease of the In-mole fraction, the amplitudes of linear and nonlinear absorption coefficients increase. The present computed results show that the absorption coefficients of transitions between the first excited states are stronger than those of the ground states. In addition, it has been found that the quantum dot size affects the amplitudes and peak positions of linear and nonlinear absorption coefficients while the incident optical intensity strongly affects the nonlinear absorption coefficients. Project supported by the Ministry of Higher Education and Scientific Research in Iraq, Ibnu Sina Institute and Physics Department of Universiti Teknologi Malaysia (UTM RUG Vote No. 06-H14).

  16. Optical time of flight studies of lithium plasma in double pulse laser ablation: Evidence of inverse Bremsstrahlung absorption

    Energy Technology Data Exchange (ETDEWEB)

    Sivakumaran, V.; Joshi, H. C.; Singh, R. K.; Kumar, Ajai, E-mail: ajai@ipr.res.in [Institute for Plasma Research, Bhat, Gandhinagar, Gujarat 382428 (India)

    2014-06-15

    The early stage of formation of lithium plasma in a collinear—double pulse laser ablation mode has been studied using optical time of flight (OTOF) spectroscopy as a function of inter-pulse delay time, the distance from the target surface and the fluence of the ablation lasers. The experimental TOF measurements were carried out for lithium neutral (670.8 nm and 610.3 nm), and ionic (548.4 nm and 478.8 nm) lines. These experimental observations have been compared with that for single pulse laser ablation mode. It is found that depending on the fluence and laser pulse shape of the first pre-ablation laser and the second main ablation laser, the plasma plume formation and its characteristic features can be described in terms of plume-plume or laser-plume interaction processes. Moreover, the enhancement in the intensity of Li neutral and ionic lines is observed when the laser-plume interaction is the dominant process. Here, we see the evidence of the role of inverse Bremsstrahlung absorption process in the initial stage of formation of lithium plasma in this case.

  17. Optical absorption and fluorescence properties of Er{sup 3+}/Yb{sup 3+} codoped lead bismuth alumina borate glasses

    Energy Technology Data Exchange (ETDEWEB)

    Goud, K. Krishna Murthy, E-mail: krishnamurthy.phy@gmail.com; Reddy, M. Chandra Shekhar, E-mail: krishnamurthy.phy@gmail.com; Rao, B. Appa, E-mail: krishnamurthy.phy@gmail.com [Dept. of Physics, Osmania University, Hyderabad-500007, Andhra Pradesh (India)

    2014-04-24

    Lead bismuth alumina borate glasses codoped with Er{sup 3+}/Yb{sup 3+} were prepared by melt quenching technique. Optical absorption, FTIR and photoluminescence spectra of these glasses have been studied. Judd-Ofelt theory has been applied to to the f ↔ f transitions for evaluating Ω{sub 2}, Ω{sub 4} and Ω{sub 6} parameters. Radiative properties like branching ratio β{sub r} and the radiative life time τ{sub R} have been determined on the basis of Judd-Ofelt theory. Upconversion emissions have been observed under 980nm laser excitation at room temperature. Green and red up-conversion emissions are centered at 530, 550 and 656 nm corresponding to {sup 2}H{sub 11/2}→{sup 4}I{sub 15/2}, {sup 4}S{sub 3/2}→{sup 4}I{sub 15/2} and {sup 4}F{sub 9/2}→{sup 4}I{sub 15/2} transitions of Er{sup 3+} respectively. The results obtained are discussed quantitatively based on the energy transfer between Yb{sup 3+} and Er{sup 3+}.

  18. The high temperature photoluminescence and optical absorption of undoped ZnO single crystals and thin films

    Energy Technology Data Exchange (ETDEWEB)

    Margueron, Samuel [School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts 02138 (United States); Laboratoire Matériaux Optiques, Photonique et Systèmes, Université de Lorraine, F-57070 Metz Cedex (France); Clarke, David R. [School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts 02138 (United States)

    2014-11-21

    The photoluminescence of undoped ZnO single crystals up to 1350 °C and the optical absorption of stress-relaxed, epitaxial ZnO thin films up to 1100 °C are reported. The photoluminescence intensity and power dependence with illumination flux are related to the crystal growth methods and stabilize after high temperature annealing. The observation of excitonic recombination at very high temperatures requires high illumination flux. It is found that the zero phonon line model reproduces the shift and the band gap narrowing as well as the free excitonic transition up to the cross-over with a defect level at 2.83 eV that occurs at 800 °C. A phenomenological model of the excitonic recombination band shape, taking account exciton-phonon losses and defect levels provides an excellent fit up to 2.2–2.4 eV (1100 °C). At these cross-over temperatures, an energy transfer is observed between the free exciton transition and defect transitions. However, at temperature above 1100 °C, the decrease of the band gap and the increase of thermal radiation, as well as the restrictions of our experimental set-up and particularly the illumination flux of the exciting laser, limit the analysis of the photoluminescence spectra measurements.

  19. Wet/dry film thickness measurement of paint by absorption spectroscopy with acousto-optic tunable filter spectrometer

    Science.gov (United States)

    Sinha, Pranay G.; Xiong, Xiangchun; Jin, Feng; Trivedi, Sudhir; Prasad, Narashima S.

    2005-08-01

    Controlling/monitoring the thickness of applied paint in real time is important to many situations including painting ship and submarine hulls in dry docks for maintaining health of ships and submarines against the harshness of the sea, in automobile and aerospace industries, and in a variety of other industries as a control sensor that plays significant role in product quality, process control, and cost control. Insufficient thickness results to inadequate protection while overspray leads to waste and pollution of the environment. A rugged instrumentation for the real time non-contact accurate measurement of wet and dry paint film thickness measurement will be immensely valuable. As paint is applied with several layers of the same or different type, thickness of each newly sprayed wet layer is of most interest, but measurement on dry paint is also useful. In this study, we use acousto-optic tunable filter-based near infrared spectrometer to obtain the absorption spectrum of layers of paint sprayed on sand blasted steel surface and thus measure the thickness of coating under both wet and dry situations. NIR spectra are obtained from 1100 to 2300 nm on four sample of different thickness of paint up to 127 micron. Partial least squares model built with the spectra shows good correlation with standard error of prediction within ~ 0.7 micron. Results indicate that the spectra also respond to the amount of organic solvent in the wet paint and can be used to monitor the degree of dryness of the paint in real time.

  20. Monitoring of atmospheric nitrogen dioxide by long-path pulsed differential optical absorption spectroscopy using two different light paths.

    Science.gov (United States)

    Kambe, Yasuaki; Yoshii, Yotsumi; Takahashi, Kenshi; Tonokura, Kenichi

    2012-03-01

    Measurements of the local distribution of atmospheric nitrogen dioxide (NO(2)) by long-path pulsed differential optical absorption spectroscopy (LP-PDOAS) in Tokyo during August 2008 are presented. Two LP-PDOAS systems simultaneously measured average NO(2) temporal mixing ratios along two different paths from a single observation point. Two flashing aviation obstruction lights, located 7.0 km north and 6.3 km east from the observation point, were used as light sources, allowing spatiotemporal variations of NO(2) in Tokyo to be inferred. The LP-PDOAS data were compared with ground-based data measured using chemiluminescence. Surface wind data indicated that large inhomogeneities were present in the spatial NO(2) distributions under southerly wind conditions, while northerly wind conditions displayed greater homogeneity between the two systems. The higher correlation in the NO(2) mixing ratio between the two LP-PDOAS systems was observed under northerly wind conditions with a correlation factor R(2) = 0.88. We demonstrated that the combined deployment of two LP-PDOAS systems oriented in different directions provides detailed information on the spatial distribution of NO(2).

  1. EPR and optical absorption studies on Gd{sup 3+} ions in ammonium hydrogen malonate single crystals

    Energy Technology Data Exchange (ETDEWEB)

    Kripal, Ram, E-mail: ram_kripal2001@rediffmail.co [EPR Laboratory, Department of Physics, University of Allahabad, Allahabad 211002 (India); Mishra, Indrajeet, E-mail: indrajeet_mishra47@rediffmail.co [EPR Laboratory, Department of Physics, University of Allahabad, Allahabad 211002 (India); Department of Physics, D.D.U. Government P.G. College, Saidabad, Allahabad (India)

    2010-01-01

    X-Band electron paramagnetic resonance (EPR) studies of Gd{sup 3+} ions in ammonium hydrogen malonate single crystals have been done at room temperature. Detailed EPR analysis indicates the presence of four physically equivalent but magnetically inequivalent sites. The zero-field splitting parameters and g factor are determined. The Gd{sup 3+} ion is in {sup 8}S state; its levels are split by the action of the crystalline electric field of monoclinic symmetry. The optical absorption spectra of Gd{sup 3+} ions in single crystals of ammonium hydrogen malonate are also recorded at room temperature. The energy levels of the 4f{sup 7} configuration are calculated and compared with those observed experimentally. The values of E{sup 1}=5854+-11, E{sup 2}=31+-0.36, E{sup 3}=592+-3.3 and zeta{sub 4f}=1595+-25 cm{sup -1} are found to give the best over-all agreement between experimentally observed and calculated levels.

  2. 1-[4-(methylsulfanyl) phenyl]-3-(4-nitropshenyl) prop-2-en-1-one: A reverse saturable absorption based optical limiter

    Energy Technology Data Exchange (ETDEWEB)

    Raghavendra, Subrayachar, E-mail: raghuphotonics@gmail.com [Department of Studies in Physics, Mangalore University, Mangalore, 574199 (India); Chidankumar, Chandraju Sadolalu [X-ray Crystallography Unit, School of Physics, 11800 USM, Universiti Sains Malaysia Penang (Malaysia); Jayarama, Arasalike [Department of Physics, Sadguru Swami Nithyananda Institute of Technology (SSNIT), Kanhangad, 671315 (India); Dharmaprakash, Sampyady Medappa [Department of Studies in Physics, Mangalore University, Mangalore, 574199 (India)

    2015-01-15

    An organic nonlinear optical material “1-[4-(methylsulfanyl) phenyl]-3-(4-nitrophenyl) prop-2-en-1-one” (4MPNP) has been synthesized by Claisen–Schmidt condensation and crystallized by slow evaporation technique at ambient temperature. The functional groups present in 4MPNP molecule were identified by FTIR spectroscopy. TGA-DSC analysis in the temperature range 30{sup o}C–650 °C showed absence of phase transition before melting point. The crystal structure of 4MPNP was determined using X-ray single crystal diffraction technique. UV–Vis absorption studies were carried out in the wavelength range 190–800 nm. Beyond the cut off wavelength 4MPNP is optically transparent in the entire visible region of the spectrum. Open aperture Z-Scan experimental curve showed that the 4MPNP molecule exhibits minimum transmittance at the focus and maximum nonlinear absorptionat532 nm wavelength. The variation of normalized transmittance with laser power density indicates good optical limiting behavior of the molecule. Nonlinear optical absorption coefficient (β), excited state absorption cross-section (σ{sub ex}) and ground state absorption cross-section (σ{sub g}) are estimated and found to be 4.5 cm/GW, 5.17 × 10{sup −18} cm{sup 2} and 5.68 × 10{sup −21} cm{sup 2} respectively. The values σ{sub ex}>>σ{sub g} indicate that 4MPNP crystal has the property of reverse saturable absorption. The studies recommend that 4MPNPcan be considered as a potential material for third order nonlinear optical device applications such as optical limiters. - Highlights: • Beyond the cut off wavelength 4MPNP is transparent in entire visible region. • Potential material for nonlinear optical device applications such as optical limiters. • TGA curve indicates that 4MPNP is almost stable up to melting point. • Band gap of 4MPNP is found to be 3.06 eV.

  3. Exciton optical absorption coefficients and refractive index changes in a strained InAs/GaAs quantum wire: The effect of the magnetic field

    Energy Technology Data Exchange (ETDEWEB)

    Arunachalam, N. [Department of Physics, Government Higher Secondary School, Saruguvalayapatti, Melur 625109, Madurai (India); John Peter, A., E-mail: a.john.peter@gmail.com [Center for Environmental Studies/Green Energy Center, Department of Environmental Science and Engineering, College of Engineering, Kyung Hee University, Seocheon-dong 1, Giheung-gu, Yongin-Si, Gyeonggi-Do 446-701 (Korea, Republic of); Yoo, Chang Kyoo [Center for Environmental Studies/Green Energy Center, Department of Environmental Science and Engineering, College of Engineering, Kyung Hee University, Seocheon-dong 1, Giheung-gu, Yongin-Si, Gyeonggi-Do 446-701 (Korea, Republic of)

    2012-06-15

    Magnetic field induced exciton binding energy is investigated in a strained InAs/GaAs quantum wire within the framework of single band effective mass approximation. The strain contribution to the potential is determined through deformation potentials. The interband emission energy of strained InAs/GaAs wire is investigated in the influence of magnetic field with the various structural parameters. Magnetic field induced photoionization cross section of the exciton is studied. The total optical absorption and the refractive index changes as a function of normalized photon energy between the ground and the first excited state in the presence of magnetic field are analyzed. The optical absorption coefficients and the refractive index changes strongly depend on the incident optical intensity and the magnetic field. The occurred blueshift of the resonant peak due to the magnetic field will give the information about the variation of two energy levels in the quantum well wire. The optical absorption coefficients and the refractive index changes are strongly dependent on the incident optical intensity and the magnetic field. - Highlights: Black-Right-Pointing-Pointer Magnetic field induced exciton binding energy is investigated in a strained InAs/GaAs quantum wire. Black-Right-Pointing-Pointer The strain contribution to the potential is determined through deformation potentials. Black-Right-Pointing-Pointer The interband emission energy of strained InAs/GaAs wire is investigated with the various structural parameters. Black-Right-Pointing-Pointer Magnetic field induced photoionization cross section of the exciton is studied. Black-Right-Pointing-Pointer The optical properties strongly depend on the incident optical intensity and the magnetic field.

  4. Optical constants of silicon carbide for astrophysical applications. II. Extending optical functions from IR to UV using single-crystal absorption spectra

    CERN Document Server

    Hofmeister, A M; Goncharov, A F; Speck, A K

    2009-01-01

    Laboratory measurements of unpolarized and polarized absorption spectra of various samples and crystal stuctures of silicon carbide (SiC) are presented from 1200--35,000 cm$^{-1}$ ($\\lambda \\sim$ 8--0.28 $\\mu$m) and used to improve the accuracy of optical functions ($n$ and $k$) from the infrared (IR) to the ultraviolet (UV). Comparison with previous $\\lambda \\sim$ 6--20 $\\mu$m thin-film spectra constrains the thickness of the films and verifies that recent IR reflectivity data provide correct values for $k$ in the IR region. We extract $n$ and $k$ needed for radiative transfer models using a new ``difference method'', which utilizes transmission spectra measured from two SiC single-crystals with different thicknesses. This method is ideal for near-IR to visible regions where absorbance and reflectance are low and can be applied to any material. Comparing our results with previous UV measurements of SiC, we distinguish between chemical and structural effects at high frequency. We find that for all spectral re...

  5. Facile synthesis of CuSe nanoparticles and high-quality single-crystal two-dimensional hexagonal nanoplatelets with tunable near-infrared optical absorption

    Science.gov (United States)

    Wu, Yimin; Korolkov, Ilia; Qiao, Xvsheng; Zhang, Xianghua; Wan, Jun; Fan, Xianping

    2016-06-01

    A rapid injection approach is used to synthesize the copper selenide nanoparticles and two-dimensional single crystal nanoplates. This technique excludes the use of toxic or expensive materials, increasing the availability of two-dimensional binary chalcogenide semiconductors. The structure of the nanocrystals has been studied and the possible formation mechanism of the nanoplates has been proposed. The optical absorption showed that the nanoplates demonstrated wide and tuneable absorption band in the visible and near infrared region. These nanoplates could be interesting for converting solar energy and for nanophotonic devices operating in the near infrared.

  6. Aerosol optical absorption by dust and black carbon in Taklimakan Desert, during no-dust and dust-storm conditions

    Institute of Scientific and Technical Information of China (English)

    Hui Lu; Wenshou Wei; Mingzhe Liu; Weidong Gao; Xi Han

    2012-01-01

    Aerosol absorption coefficient σap involves the additive contribution of both black carbon aerosol (BC) and dust aerosol.The linear statistical regression analysis approach introduced by Fialho et al.(2005) is used to estimate the absorption exponents of BC and dust aerosol absorption coefficients,and further to separate the contributions of these two types of aerosols from the total light absorption coefficient measured in the hinterland of Taklimakan Desert in the spring of 2006.Absorption coefficients are measured by means of a 7-wavelength Aethalometer from 1 March to 31 May and from 1 November to 28 December,2006.The absorption exponent of BC absorption coefficient α is estimated as (-0.95 ±0.002) under background weather (supposing the observed absorption coefficient is due only to BC); the estimated absorption exponent of dust aerosol absorption coefficient β during the 6 dust storm periods (strong dust storm) is (-2.55 ± 0.009).Decoupling analysis of the measured light absorption coefficients demonstrates that,on average,the light absorptions caused by dust aerosol and BC make up about 50.5% and 49.5% respectively of the total light absorption at 520 nm; during dust weather process periods (dust storm,floating dust,blowing dust),the contribution of dust aerosol to absorption extinction is 60.6% on average; in the hinterland of desert in spring,dust aerosol is also the major contributor to the total aerosol light absorption,more than that of black carbon aerosol.

  7. Optimization of Optical Absorption of Colloids of SiO2@Au and Fe3O4@Au Nanoparticles with Constraints

    Science.gov (United States)

    Xue, Xiaozheng; Sukhotskiy, Viktor; Furlani, Edward P.

    2016-01-01

    We study the optical response of monodisperse colloids of core-shell plasmonic nanoparticles and introduce a computational approach to optimize absorption for photothermal applications that require dilute colloids of non-interacting particles with a prescribed volume fraction. Since the volume fraction is held constant, the particle concentration is size-dependent. Optimization is achieved by comparing the absorption spectra of colloids as a function of particle size and structure. We demonstrate the approach via application to colloids of core-shell SiO2@Au and Fe3O4@Au nanoparticles with particle sizes that range from 5–100 nm and with the incident wavelength varying from 600–1200 nm. The absorption spectra are predicted using Mie theory and the analysis shows that there is a unique mix of parameters (core radius, shell thickness, wavelength) that maximize absorption, independent of the value of volume fraction. We show that lossy Fe3O4 cores produce a much broader absorption peak with much less sensitivity to variations in particle structure and wavelength than lossless SiO2 cores. This approach can be readily adapted to colloids of nanoparticles with arbitrary materials, shapes and structure using appropriate numerical methods to compute the absorption spectra. As such, it is useful for the rational design of colloids and process variables for a broad range of photothermal applications. PMID:27786279

  8. A new calibration system for lightweight, compact and mobile Cavity-Enhanced Differential Optical Absorption Spectroscopy instruments

    Science.gov (United States)

    Zielcke, Johannes; Horbanski, Martin; Pöhler, Denis; Frieß, Udo; Platt, Ulrich

    2013-04-01

    Absorption Spectroscopy has been employed for several decades now to study the earth's atmosphere. While the focus has been on remote sensing for a long time, lately there has been a renewed interest in in-situ methods, as point measurements allow an easier interpretation for highly inhomogeneous distributions of gases of interest compared to the integration approach of most remote sensing methods. One comparatively new method offering both advantages of in-situ measurements as well as being contactless is open-path Cavity-Enhanced Differential Optical Absorption Spectroscopy (CE-DOAS). Broadband open-path CE-DOAS instruments have been used for ten years now, and in the meantime allow the measurement of numerous atmospheric trace gases (e.g. NO2, NO3, IO, CHOCHO, HCHO). While those instruments were bulky and not very mobile at first, recent developments resulted in relatively lightweight (< 30 kg) instruments with a relatively low power consumption allowing mobile open-path measurements at remote field locations. An important operational issue has been the path length calibration in the field, necessary for the determination of the concentration of measured gases. Until now, often calibration gases were used with different scattering properties than air or known concentrations. However this methods has several major shortcomings, being rather inconvenient and cumbersome in the field with the need for compressed gas cylinders, as well as time consuming, preventing a quick check of the state of the instrument in the field after changing measurement locations. Here we present a new wavelength-resolved method for broadband CE-DOAS path length calibration. A small, custom made ring-down system is employed with a pulsed LED as light source. The wavelength is then resolved by tilting a narrow band interference filter. The system not only allows quick, automated path length calibrations without physical interaction on the instrument, but also saves weight, space and the

  9. Linear and nonlinear optical absorption coefficients and refractive index changes in modulation-doped quantum wells: Effects of the magnetic field and hydrostatic pressure

    Energy Technology Data Exchange (ETDEWEB)

    Nazari, M.; Karimi, M.J., E-mail: karimi@sutech.ac.ir; Keshavarz, A.

    2013-11-01

    In this study, the linear, the third-order nonlinear and total optical absorption coefficients and refractive index changes of a modulation-doped GaAs/Al{sub x}Ga{sub 1−x}As quantum well are investigated numerically. In the effective-mass approximation, the electronic structure of modulation-doped quantum well is calculated by solving the Schrödinger and Poisson equations self-consistently. Optical properties are obtained using the compact density matrix approach. The effects of structure parameters, the applied magnetic field and the hydrostatic pressure on the optical properties of the modulation-doped quantum well are studied. Results show that the resonant peaks shift toward the higher (lower) energies with the increase in the magnetic field (pressure). The magnitude of the resonant peaks of the optical properties decreases with the increasing magnetic field or pressure.

  10. Intense laser field effects on the intersubband optical absorption and refractive index change in the δ -doped GaAs quantum wells

    Science.gov (United States)

    Sari, H.; Yesilgul, U.; Ungan, F.; Sakiroglu, S.; Kasapoglu, E.; Sökmen, I.

    2017-04-01

    In this paper, we have investigated the effects of the non-resonant intense laser field on the electronic and optical properties such as linear, nonlinear and the total optical absorption coefficient and refractive index change for transitions between two lower-lying electronic states in the GaAs-based δ -doped quantum well. Within the effective mass approximation, we calculated the eigenvalues and corresponding eigenfunctions as a function of the intense laser parameter by solving the Schrödinger equation in the laser-dressed confinement potential. The analytical expressions of the linear and third-order non-linear optical absorption coefficients and refractive index changes are obtained by using the compact-density matrix formalism. The obtained results show that the separation between ground and first excited energy levels in the δ -doped quantum well decreases in energy by the increase of the laser field intensity and this effect leads to an optical red-shift in the intersubband transitions. This behavior gives us a new degree of freedom in tunability of different device applications based on the optical transitions.

  11. Linear and nonlinear optical absorption coefficients and refractive index changes associated with intersubband transitions in a quantum disk with flat cylindrical geometry

    Energy Technology Data Exchange (ETDEWEB)

    Gambhir, Monica, E-mail: monica.gambhir@yahoo.com [Department of Physics and Astrophysics, University of Delhi, Delhi 110007 (India); Kumar, Manoj [Department of Physics and Astrophysics, University of Delhi, Delhi 110007 (India); Jha, P.K. [Department of Physics and Astrophysics, University of Delhi, Delhi 110007 (India); Deen Dayal Upadhyaya College, University of Delhi, Delhi 110015 (India); Mohan, Man [Department of Physics and Astrophysics, University of Delhi, Delhi 110007 (India)

    2013-11-15

    The linear and nonlinear optical absorption coefficients and changes in the refractive index in GaAs/AlGaAs quantum disk in the form of a flat cylinder are investigated theoretically in the presence of a static magnetic and a laser field within the framework of the compact-density matrix approach. It is found that the absorption coefficients and the refractive index changes depend not only on the optical wave intensity but also on the strength of the static magnetic field. The intersubband relaxation time, also, has an important influence on the linear and nonlinear optical properties of a quantum disk. -- Highlights: • The study is carried out in a quantum disk having quantum dot geometry. • The linear and non-linear optical properties are studied using density matrix approach. • The study is carried out in the presence of a laser field and a magnetic field. • Influence of incident photon energy and static magnetic field is analyzed. • The optical properties are found to be greatly influenced by the relaxation time.

  12. Damage and deuterium retention in LiAlO 2 single crystals irradiated with deuterium ions using ion-beam techniques and optical absorption measurements

    Science.gov (United States)

    Katsui, H.; Nagata, S.; Tsuchiya, B.; Zhao, M.; Shikama, T.

    2011-10-01

    Ion beam analysis techniques and optical absorption measurements were employed to quantitatively examine the damage and deuterium retention in LiAlO 2 single crystals irradiated with 10 keV D2+. Rutherford backscattering spectrometry in channeling geometry revealed that the lattice atoms were disordered by the incident deuterium ions in the ratio O/Al of 2.5. Elastic recoil detection analysis showed that all the incident deuterium ions were retained near the end of their trajectories with a maximum concentration of 0.7 D/Al at room temperature. The depth profiles of the disordered atoms were nearly identical to those of the retained deuterium atoms. The release of the retained deuterium atoms and the annihilation of the ion-induced color centers, which contributed to an optical absorption band at 5.25 eV, were observed in the same temperature range. A correlation was established between the oxygen vacancies and the retained deuterium atoms.

  13. Exciton-related nonlinear optical absorption and refractive index change in GaAs-Ga{sub 1-x}Al{sub x}As double quantum wells

    Energy Technology Data Exchange (ETDEWEB)

    Miranda, Guillermo L. [Fisica Teorica y Aplicada, Escuela de Ingenieria de Antioquia, A.A. 7516 Medellin (Colombia); Instituto de Fisica, Universidad de Antioquia, AA 1226 Medellin (Colombia); Mora-Ramos, Miguel E., E-mail: memora@uaem.mx [Fisica Teorica y Aplicada, Escuela de Ingenieria de Antioquia, A.A. 7516 Medellin (Colombia); Facultad de Ciencias, Universidad Autonoma del Estado de Morelos, Av. Universidad 1001, C.P. 62209 Cuernavaca, Morelos (Mexico); Instituto de Fisica, Universidad de Antioquia, AA 1226 Medellin (Colombia); Duque, Carlos A. [Instituto de Fisica, Universidad de Antioquia, AA 1226 Medellin (Colombia)

    2013-01-15

    In this work the variations of the exciton-related optical absorption and the change of the refractive index in a GaAs-(Ga,Al)As double quantum well as functions of the geometric parameters of the heterostructure are investigated. The variational method is applied within the framework of the parabolic band and effective mass approximations, in order to obtain the 1s-like exciton energy spectrum. The outcome for the related optical coefficients shows a quenched and redshifted light absorption as a result of the increment in the inner barrier and right-hand well widths, with the possibility of an enhancement of the excitonic contribution to the relative change in the refractive index.

  14. Multipass optical absorption spectroscopy: a fast-scanning laser spectrometer for the in situ determination of atmospheric trace-gas components, in particular OH.

    Science.gov (United States)

    Armerding, W; Spiekermann, M; Walter, J; Comes, F J

    1996-07-20

    The optical design of an absorption spectrometer for in situ measurements of atmospheric trace gases is reported. The light source is a rapidly tuned and power-stabilized dye-ring laser, which is frequency doubled by an intracavity BBO crystal. The second harmonic and the fundamental are used simultaneously for measurement of OH, SO(2), CH(2)O, and naphthalene in the UV and of NO(2) in the visible. The 1.2-km absorption path is folded within a 6-m White-cell-type multiple-reflection system with an open-path setup. The absorption sensitivity of the spectrometer is better than 1 part in 10(-5) under tropospheric conditions (integration time 1 min., signal-to-noise ratio 1).

  15. Concentration distribution of Nd{sup 3+} In Nd:Gd{sub 3}Ga{sub 5}O{sub 12} crystals studied by optical absorption method

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Dunlu; Zhang, Qingli; Wang, Zhaobing; Su, Jing; Gu, Changjiang; Wang, Aihua; Yin, Shaotang [Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, HeFei 230031 (China)

    2005-07-01

    Nd:Gd{sub 3}Ga{sub 5}O{sub 12} crystals with different concentrations of Nd{sup 3+} were grown by Czochralski method, their absorption spectra were measured at room temperature. By using the optical absorption method, the effective distribution coefficient k{sub eff} for Nd{sup 3+} in GGG was fitted to be 0.40{+-}0.01, which is higher than that of Nd{sup 3+} in YAG. The 808nm absorption cross-section was calculated to be 4.0{+-}0.2 x 10{sup -20} cm{sup -2}. The lengthways and radial concentration distribution of Nd{sup 3+} in the crystals were also analyzed and discussed. (copyright 2005 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  16. Organic reversed Saturable absorption Materials for optical Power Limiting%有机反饱和吸收光限幅材料

    Institute of Scientific and Technical Information of China (English)

    王鹏; 张爽; 叶成

    2001-01-01

      An introduction to the mechanism of the reversed saturable absorption for optical power limiting is given, and the recent progresses in developing organic reversed saturable absorbers is reviewed._borders%  本文介绍了反饱和吸收光限幅的基本原理,并就目前广泛关注的有机反饱和吸收材料的研究进展进行了评述。

  17. Effects of pre-irradiation annealing at high temperature on optical absorption and electron paramagnetic resonance of natural pumpellyite mineral

    Energy Technology Data Exchange (ETDEWEB)

    Javier-Ccallata, Henry, E-mail: henrysjc@gmail.com [Escuela de Ingeniería Electrónica y Telecomunicaciones, Universidad Alas Peruanas Filial Arequipa, Urb. D. A. Carrión G-14, J. L. Bustamante y Rivero, Arequipa (Peru); Laboratório de Sistemas Nanoestruturados, Departamento de Física, Universidade Federal de Santa Catarina, Florianópolis, Santa Catarina (Brazil); Filho, Luiz Tomaz [Departamento de Física Nuclear, Instituto de Física, Universidade de São Paulo, Rua do Matão, travessa R, 187, CEP 05508-900 São Paulo, SP (Brazil); Faculdade de Tecnologia e Ciências Exatas, Universidade São Judas Tadeu, Rua Taquari 546, São Paulo, SP (Brazil); Sartorelli, Maria L. [Laboratório de Sistemas Nanoestruturados, Departamento de Física, Universidade Federal de Santa Catarina, Florianópolis, Santa Catarina (Brazil); Watanabe, Shigueo [Departamento de Física Nuclear, Instituto de Física, Universidade de São Paulo, Rua do Matão, travessa R, 187, CEP 05508-900 São Paulo, SP (Brazil)

    2013-09-15

    Highlights: •Natural pumpellyite mineral presents superposition bands around 900 and 1060 nm due Fe{sup 2+}and Fe{sup 3+}. •High temperature annealing influences the EPR and OA spectra. •The behavior of EPR line for 800 and 900 °C can be attributed to forbidden dd transitions due the Fe{sup 3+}. -- Abstract: Natural silicate mineral of pumpellyite, Ca{sub 2}MgAl{sub 2}(SiO{sub 4})(Si{sub 2}O{sub 7})(OH){sub 2}·(H{sub 2}O), point group A2/m, has been studied concerning high temperature annealing and γ-radiation effects on Optical Absorption (OA) and Electron Paramagnetic Resonance (EPR) properties. Chemical analysis revealed that besides Si, Al, Ca and Mg, other oxides i.e., Fe, Mn, Na, K, Ti and P are present in the structure as impurities. OA measurements of natural and annealed pumpellyite revealed several bands in the visible region due to spin forbidden transitions of Fe{sup 2+} and Fe{sup 3+}. The behaviour of bands around 900 and 1060 nm, with pre-annealing and γ radiation dose, indicating a transition Fe{sup 2+} → e{sup −} + Fe{sup 3+}. On the other hand, EPR measurements reveal six lines of Mn{sup 2+}, and satellites due to hyperfine interaction, superimposed on the signal of Fe{sup 3+} around of g = 2. For heat treatment from 800 °C the signal grows significantly and for 900 °C a strong signal of Fe{sup 3+} hides all Mn{sup 2+} lines. The strong growth of this signal indicates that the transitions are due to Fe{sup 3+} dipole–dipole interactions.

  18. Modified thermal-optical analysis using spectral absorption selectivity to distinguish black carbon from pyrolized organic carbon

    Energy Technology Data Exchange (ETDEWEB)

    Hadley, Odelle; Hadley, O.L.; Corrigan, C.E.; Kirchstetter, T.W.

    2008-04-14

    Black carbon (BC), a main component of combustion-generated soot, is a strong absorber of sunlight and contributes to climate change. Measurement methods for BC are uncertain, however. This study presents a method for analyzing the BC mass loading on a quartz fiber filter using a modified thermal-optical analysis method, wherein light transmitted through the sample is measured over a spectral region instead of at a single wavelength as the sample is heated. Evolution of the spectral light transmission signal depends on the relative amounts of light-absorbing BC and char, the latter of which forms when organic carbon in the sample pyrolyzes during heating. Absorption selectivities of BC and char are found to be distinct and are used to apportion the amount of light attenuated by each component in the sample. Light attenuation is converted to mass concentration based on derived mass attenuation efficiencies (MAE) of BC and char. The fraction of attenuation due to each component are scaled by their individual MAE values and added together as the total mass of light absorbing carbon (LAC). An iterative algorithm is used to find the MAE values for both BC and char that provide the best fit to the carbon mass remaining on the filter (derived from direct measurements of thermally evolved CO{sub 2}) at temperatures higher than 480 C. This method was applied to measure the BC concentration in precipitation samples collected from coastal and mountain sites in Northern California. The uncertainty in measured BC concentration of samples that contained a high concentration of organics susceptible to char ranged from 12 to 100 percent, depending on the mass loading of BC on the filter. The lower detection limit for this method was approximately 0.35 {micro}g BC and uncertainty approached 20 percent for BC mass loading greater than 1.0 {micro}g BC.

  19. A new Differential Optical Absorption Spectroscopy instrument to study atmospheric chemistry from a high-altitude unmanned aircraft

    Science.gov (United States)

    Stutz, Jochen; Werner, Bodo; Spolaor, Max; Scalone, Lisa; Festa, James; Tsai, Catalina; Cheung, Ross; Colosimo, Santo F.; Tricoli, Ugo; Raecke, Rasmus; Hossaini, Ryan; Chipperfield, Martyn P.; Feng, Wuhu; Gao, Ru-Shan; Hintsa, Eric J.; Elkins, James W.; Moore, Fred L.; Daube, Bruce; Pittman, Jasna; Wofsy, Steven; Pfeilsticker, Klaus

    2017-03-01

    Observations of atmospheric trace gases in the tropical upper troposphere (UT), tropical tropopause layer (TTL), and lower stratosphere (LS) require dedicated measurement platforms and instrumentation. Here we present a new limb-scanning Differential Optical Absorption Spectroscopy (DOAS) instrument developed for NASA's Global Hawk (GH) unmanned aerial system and deployed during the Airborne Tropical TRopopause EXperiment (ATTREX). The mini-DOAS system is designed for automatic operation under unpressurized and unheated conditions at 14-18 km altitude, collecting scattered sunlight in three wavelength windows: UV (301-387 nm), visible (410-525 nm), and near infrared (900-1700 nm). A telescope scanning unit allows selection of a viewing angle around the limb, as well as real-time correction of the aircraft pitch. Due to the high altitude, solar reference spectra are measured using diffusors and direct sunlight. The DOAS approach allows retrieval of slant column densities (SCDs) of O3, O4, NO2, and BrO with relative errors similar to other aircraft DOAS systems. Radiative transfer considerations show that the retrieval of trace gas mixing ratios from the observed SCD based on O4 observations, the most common approach for DOAS measurements, is inadequate for high-altitude observations. This is due to the frequent presence of low-altitude clouds, which shift the sensitivity of the O4 SCD into the lower atmosphere and make it highly dependent on cloud coverage. A newly developed technique that constrains the radiative transfer by comparing in situ and DOAS O3 observations overcomes this issue. Extensive sensitivity calculations show that the novel O3-scaling technique allows the retrieval of BrO and NO2 mixing ratios at high accuracies of 0.5 and 15 ppt, respectively. The BrO and NO2 mixing ratios and vertical profiles observed during ATTREX thus provide new insights into ozone and halogen chemistry in the UT, TTL, and LS.

  20. Interband optical absorption in wurtzite MgxZn1-xO/ZnO/MgyZn1-yO asymmetric quantum wells

    Science.gov (United States)

    Gu, Z.; Zhu, Z. N.; Wang, M. M.; Wang, Y. Q.; Wang, M. S.; Qu, Y.; Ban, S. L.

    2017-02-01

    Based on Fermi golden rule, the optical absorption induced by interband transition of electrons and holes in wurtzite MgxZn1-xO/ZnO/MgyZn1-yO asymmetric quantum wells at room temperature has been discussed. The built-in electric field (BEF) and Poisson potential are considered to calculate the eigenstates and eigenenergies of electrons and holes. The interband optical absorption coefficients (IOACs) influenced by ternary mixed crystal and size effects as functions of incident photon wavelengths are presented. The results indicate that increasing Mg component in left barrier can enhance the BEF to enforce electrons (holes) close to the left (right) interface, so as to reduce the overlapping of their wave functions. Thus the IOAC peak decreases rapidly and presents a blue shift with the increment of Mg component x. Furthermore, the size effect on IOACs is also discussed. The absorption peak is more sensitive to the change of the well width than the left barrier size. The absorption peak reduces sharply and shows a red shift with the increase of the well width. Our results could provide guidance on experiments and device fabrication.

  1. Nonlinear absorption coefficient and optically detected electrophonon resonance in cylindrical GaAs/AlAs quantum wires with different confined phonon models

    Science.gov (United States)

    Khoa, Doan Quoc; Phuong, Le Thi Thu; Hoi, Bui Dinh

    2017-03-01

    A quantum kinetic equation for electrons interacting with confined phonons is used to investigate the nonlinear absorption of an intense electromagnetic wave by electrons in cylindrical GaAs/AlAs quantum wires. The analytic expression for absorption coefficient is calculated for three models of confined optical phonons: the dielectric continuum (DC), hydrodynamic continuum (HC), and Huang-Zhu (HZ) models. The absorption coefficient depends on the square of the electromagnetic wave amplitude. The electrophonon resonance and optically detected electrophonon resonance (ODEPR) are observed through the absorption spectrum. The full width at half maximum (the line-width) of the ODEPR peaks is obtained by a computational method. The line-width is found to increase with increasing temperature and decrease with increasing the quantum wire radius. In particular, numerical results show that the DC and HZ models lead to a similar behaviour of electron - confined phonon interaction whereas the HC model results in a quite different one, especially at small quantum wire radius. For large quantum wire radii, above mentioned phonon models have equivalent contributions to the ODEPR line-width.

  2. Mass-specific optical absorption coefficients and imaginary part of the complex refractive indices of mineral dust components measured by a multi-wavelength photoacoustic spectrometer

    Science.gov (United States)

    Utry, N.; Ajtai, T.; Pintér, M.; Tombácz, E.; Illés, E.; Bozóki, Z.; Szabó, G.

    2015-01-01

    Mass-specific optical absorption coefficients (MACs) and the imaginary part (κ) of the refractive indices of various mineral dust components including silicate clays (illite, kaolin and bentonite), oxides (quartz, hematite and rutile), and carbonate (limestone) were determined at the wavelengths of 1064, 532, 355 and 266 nm. The MAC values were calculated from aerosol optical absorption coefficients measured by a multi-wavelength photoacoustic (PA) instrument, the mass concentration and the number size distribution of the generated aerosol samples as well as the size transfer functions of the measuring instruments. Values of κ were calculated from the measured and particle-loss-corrected data by using a Mie-theory-based retrieval algorithm. The determined values could be used for comparisons with calculated wavelength-dependent κ values typically deduced from bulk-phase measurements by using indirect measurement methods. Accordingly, the presented comparison of the measured and calculated aerosol optical absorption spectra revealed the strong need for standardized sample preparation and measurement methodology in case of bulk-phase measurements.

  3. Intraband magneto-optical absorption in InAs/GaAs quantum dots: Orbital Zeeman splitting and the Thomas-Reiche-Kuhn sum rule

    Science.gov (United States)

    Zhang, J.-Z.; Galbraith, I.

    2008-05-01

    Using perturbation theory, intraband magneto-optical absorption is calculated for InAs/GaAs truncated pyramidal quantum dots in a magnetic field applied parallel to the growth direction z . The effects of the magnetic field on the electronic states as well as the intraband transitions are systematically studied. Selection rules governing the intraband transitions are discussed based on the symmetry properties of the electronic states. While the broadband z -polarized absorption is almost insensitive to the magnetic field, the orbital Zeeman splitting is the dominant feature in the in-plane polarized spectrum. Strong in-plane polarized magneto-absorption features are located in the far-infrared region, while z -polarized absorption occurs at higher frequencies. This is due to the dot geometry (the base length is much larger than the height) yielding different quantum confinement in the vertical and lateral directions. The Thomas-Reiche-Kuhn sum rule, including the magnetic field effect, is applied together with the selection rules to the absorption spectra. The orbital Zeeman splitting depends on both the dot size and the confining potential—the splitting decreases as the dot size or the confining potential decreases. Our calculated Zeeman splittings are in agreement with experimental data.

  4. Pushing the limits of CMOS optical parametric amplifiers with USRN:Si7N3 above the two-photon absorption edge

    Science.gov (United States)

    Ooi, K. J. A.; Ng, D. K. T.; Wang, T.; Chee, A. K. L.; Ng, S. K.; Wang, Q.; Ang, L. K.; Agarwal, A. M.; Kimerling, L. C.; Tan, D. T. H.

    2017-01-01

    CMOS platforms operating at the telecommunications wavelength either reside within the highly dissipative two-photon regime in silicon-based optical devices, or possess small nonlinearities. Bandgap engineering of non-stoichiometric silicon nitride using state-of-the-art fabrication techniques has led to our development of USRN (ultra-silicon-rich nitride) in the form of Si7N3, that possesses a high Kerr nonlinearity (2.8 × 10−13 cm2 W−1), an order of magnitude larger than that in stoichiometric silicon nitride. Here we experimentally demonstrate high-gain optical parametric amplification using USRN, which is compositionally tailored such that the 1,550 nm wavelength resides above the two-photon absorption edge, while still possessing large nonlinearities. Optical parametric gain of 42.5 dB, as well as cascaded four-wave mixing with gain down to the third idler is observed and attributed to the high photon efficiency achieved through operating above the two-photon absorption edge, representing one of the largest optical parametric gains to date on a CMOS platform. PMID:28051064

  5. Donor impurity-related linear and nonlinear intraband optical absorption coefficients in quantum ring: effects of applied electric field and hydrostatic pressure.

    Science.gov (United States)

    Barseghyan, Manuk G; Restrepo, Ricardo L; Mora-Ramos, Miguel E; Kirakosyan, Albert A; Duque, Carlos A

    2012-09-28

    : The linear and nonlinear intraband optical absorption coefficients in GaAs three-dimensional single quantum rings are investigated. Taking into account the combined effects of hydrostatic pressure and electric field, applied along the growth direction of the heterostructure, the energies of the ground and first excited states of a donor impurity have been found using the effective mass approximation and a variational method. The energies of these states are examined as functions of the dimensions of the structure, electric field, and hydrostatic pressure. We have also investigated the dependencies of the linear, nonlinear, and total optical absorption coefficients as a function of incident photon energy for several configurations of the system. It is found that the variation of distinct sizes of the structure leads to either a redshift and/or a blueshift of the resonant peaks of the intraband optical spectrum. In addition, we have found that the application of an electric field leads to a redshift, whereas the influence of hydrostatic pressure leads to a blueshift (in the case of on-ring-center donor impurity position) of the resonant peaks of the intraband optical spectrum.

  6. Preparation and Optical Absorption Performance of Si Single Quantum Dots and Si/Ge Double Quantum Dots Doped TiO2 Films.

    Science.gov (United States)

    Chen, Lixia; He, Fang; Sun, Zuwen; Zhang, Yan; Li, Fengjiao; Huang, Yuan; Gu, Ruisona

    2015-02-01

    Si single quantum dots (QDs) and Si/Ge double QDs doped TiO2 films were successfully fabricated via layer-by-layer ion beam sputtering assisted by annealing treatment, and their morphology and optical absorption performance were analyzed in this paper. TEM images show that Si QDs and Si/Ge double QDs prepared in the TiO2 matrix are in a uniform size distribution and high density, especially after annealed at 500 °C. XPS results indicate that Si in the TiO2 films mainly exists in the form of elemental Si and SiO2, and Ge is in elemental form. From the optical absorption spectra, the optical response of the TiO2 films is shifted from ultraviolet to visible and near infrared region when they are doped by the QDs, and the Si/Ge double QDs co-doped TiO2 films show better optical response compared with the Si QDs doped TiO2 films, suggesting a hybrid enhanced effect of double QDs.

  7. Measurements of NO2 mixing ratios with topographic target light scattering-differential optical absorption spectroscopy system and comparisons to point monitoring technique

    Institute of Scientific and Technical Information of China (English)

    Wang Yang; Li Ang; Xie Pin-Hua; Zeng Yi; Wang Rui-Bin; Chen Hao; Pei Xian; Liu Jian-Guo; Liu Wen-Qing

    2012-01-01

    A topographic target light scattering-differential optical absorption spectroscopy (ToTaL-DOAS) system is developed for measuring average concentrations along a known optical path and studying surface-near distributions of atmospheric trace gases.The telescope of the ToTaL-DOAS system points to targets which are located at known distances from the measurement device and illuminated by sunlight.Average concentrations with high spatial resolution can be retrieved by receiving sunlight reflected from the targets.A filed measurement of NO2 concentration is performed with the ToTaL-DOAS system in Shijiazhuang in the autumn of 2011.The measurement data are compared with concentrations measured by the point monitoring technique at the same site.The results show that the ToTaL-DOAS system is sensitive to the variation of NO2 concentrations along the optical path.

  8. Stark effect-dependent of impurity-related nonlinear optical absorption of a (In,Ga)N-GaN spherical quantum dot

    Science.gov (United States)

    El Ghazi, Haddou; Zorkani, Izeddine; Jorio, Anouar

    2015-03-01

    The nonlinear intra-conduction band optical properties of a wurtzite (In,Ga)N-GaN spherical quantum dot are investigated. The linear, third-order nonlinear, and total absorption coefficients (ACs) of the 1s-1p transition are computed via a combination of the quantum genetic algorithm (QGA) and the Hartree-Fock-Roothaan (HFR) method. The external applied electric field effect is examined within the single-band effective mass and the one-parabolic-band approximations under a finite potential barrier. It is found that the electric field has a great impact on the optical properties of QDs: (i) a significant redshift of the resonant peak is obtained, (ii) the maximum of the amplitude of the optical total AC decreases nonlinearly, and (iii) the Stark shift increases nonlinearly, tending toward the saturation regime. Compared with findings, good agreement is shown.

  9. Optical Absorption Spectra and Electronic Properties of Symmetric and Asymmetric Squaraine Dyes for Use in DSSC Solar Cells: DFT and TD-DFT Studies

    Directory of Open Access Journals (Sweden)

    Reda M. El-Shishtawy

    2016-04-01

    Full Text Available The electronic absorption spectra, ground-state geometries and electronic structures of symmetric and asymmetric squaraine dyes (SQD1–SQD4 were investigated using density functional theory (DFT and time-dependent (TD-DFT density functional theory at the B3LYP/6-311++G** level. The calculated ground-state geometries reveal pronounced conjugation in these dyes. Long-range corrected time dependent density functionals Perdew, Burke and Ernzerhof (PBE, PBE1PBE (PBE0, and the exchange functional of Tao, Perdew, Staroverov, and Scuseria (TPSSh with 6-311++G** basis set were employed to examine optical absorption properties. In an extensive comparison between the optical data and DFT benchmark calculations, the BEP functional with 6-311++G** basis set was found to be the most appropriate in describing the electronic absorption spectra. The calculated energy values of lowest unoccupied molecular orbitals (LUMO were 3.41, 3.19, 3.38 and 3.23 eV for SQD1, SQD2, SQD3, and SQD4, respectively. These values lie above the LUMO energy (−4.26 eV of the conduction band of TiO2 nanoparticles indicating possible electron injection from the excited dyes to the conduction band of the TiO2 in dye-sensitized solar cells (DSSCs. Also, aromaticity computation for these dyes are in good agreement with the data obtained optically and geometrically with SQD4 as the highest aromatic structure. Based on the optimized molecular geometries, relative positions of the frontier orbitals, and the absorption maxima, we propose that these dyes are suitable components of photovoltaic DSSC devices.

  10. Optical Absorption Spectra and Electronic Properties of Symmetric and Asymmetric Squaraine Dyes for Use in DSSC Solar Cells: DFT and TD-DFT Studies.

    Science.gov (United States)

    El-Shishtawy, Reda M; Elroby, Shaaban A; Asiri, Abdullah M; Müllen, Klaus

    2016-04-01

    The electronic absorption spectra, ground-state geometries and electronic structures of symmetric and asymmetric squaraine dyes (SQD1-SQD4) were investigated using density functional theory (DFT) and time-dependent (TD-DFT) density functional theory at the B3LYP/6-311++G** level. The calculated ground-state geometries reveal pronounced conjugation in these dyes. Long-range corrected time dependent density functionals Perdew, Burke and Ernzerhof (PBE, PBE1PBE (PBE0)), and the exchange functional of Tao, Perdew, Staroverov, and Scuseria (TPSSh) with 6-311++G** basis set were employed to examine optical absorption properties. In an extensive comparison between the optical data and DFT benchmark calculations, the BEP functional with 6-311++G** basis set was found to be the most appropriate in describing the electronic absorption spectra. The calculated energy values of lowest unoccupied molecular orbitals (LUMO) were 3.41, 3.19, 3.38 and 3.23 eV for SQD1, SQD2, SQD3, and SQD4, respectively. These values lie above the LUMO energy (-4.26 eV) of the conduction band of TiO₂ nanoparticles indicating possible electron injection from the excited dyes to the conduction band of the TiO₂ in dye-sensitized solar cells (DSSCs). Also, aromaticity computation for these dyes are in good agreement with the data obtained optically and geometrically with SQD4 as the highest aromatic structure. Based on the optimized molecular geometries, relative positions of the frontier orbitals, and the absorption maxima, we propose that these dyes are suitable components of photovoltaic DSSC devices.

  11. Bio-optical characterization of offshore NW Mediterranean waters: CDOM contribution to the absorption budget and diffuse attenuation of downwelling irradiance

    Science.gov (United States)

    Pérez, Gonzalo L.; Galí, Martí; Royer, Sarah-Jeanne; Sarmento, Hugo; Gasol, Josep M.; Marrasé, Cèlia; Simó, Rafel

    2016-08-01

    We investigated the peculiar bio-optical characteristics of the Mediterranean Sea focusing on the spectral diffuse attenuation coefficient [Kd (λ)] and its relationship with chlorophyll a concentration (Chl a), complemented with measurements of light absorption by chromophoric dissolved organic matter (CDOM) and the optical properties of particulate material. The non-water absorption budget showed that CDOM was the largest contributor in the 300-600 nm range (>60% of the absorption at 443 nm in the euphotic layer), increasing to 80% within the first optical depth (FOD). This translated into CDOM accounting for >50% of KdBio (λ) (the irradiance attenuation coefficient caused by all non-water absorptions) between 320 and 555 nm and throughout both layers (FOD and euphotic). Indeed, we tested three Chl a-based bio-optical models and all three underestimated Kd (λ), evidencing the importance of CDOM beside Chl a to fully account for light attenuation. The Morel & Maritorena (2001) model (M&M 01) underestimated Kd (λ) in the UV and blue spectral regions within the FOD layer, showing lower differences with increasing wavelengths. The Morel et al. (2007a) model (BGS 07) also underestimated Kd (λ) in the FOD layer, yet it performed much better in the 380-555 nm range. In the euphotic layer, the Morel (1988) model (JGR 88) underestimated Kd (λ) showing higher differences at 412 and 443 nm and also performed better at higher wavelengths. Observed euphotic layer depths (Z1%) were 28 m shallower than those predicted with the M&M 01 empirical relationship, further highlighting the role of CDOM in the bio-optical peculiarity of Mediterranean Sea. In situ measurements of the CDOM index (Φ), an indicator of the deviation of the CDOM-Chl a average relationship for Case 1 waters, gave a mean of 5.9 in the FOD, consistent with simultaneous estimates from MODIS (4.8±0.4). The implications of the bio-optical anomaly for ecological and biogeochemical inferences in the

  12. Core-shell interaction and its impact on the optical absorption of pure and doped core-shell CdSe/ZnSe nanoclusters.

    Science.gov (United States)

    Wang, Xinqin; Cui, Yingqi; Yu, Shengping; Zeng, Qun; Yang, Mingli

    2016-04-07

    The structural, electronic, and optical properties of core-shell nanoclusters, (CdSe)(x)@(CdSe)(y) and their Zn-substituted complexes of x = 2-4 and y = 16-28, were studied with density functional theory calculations. The substitution was applied in the cores, the shells, and/or the whole clusters. All these clusters are characterized by their core-shell structures in which the core-shell interaction was found different from those in core or in shell, as reflected by their bondlengths, volumes, and binding energies. Moreover, the core and shell combine together to compose a new cluster with electronic and optical properties different from those of separated individuals, as reflected by their HOMO-LUMO gaps and optical absorptions. With the substitution of Cd by Zn, the structural, electronic, and optical properties of clusters change regularly. The binding energy increases with Zn content, attributed to the strong Zn-Se bonding. For the same core/shell, the structure with a CdSe shell/core has a narrower gap than that with a ZnSe shell/core. The optical absorption spectra also change accordingly with Zn substitution. The peaks blueshift with increasing Zn concentration, accompanying with shape variations in case large number of Cd atoms are substituted. Our calculations reveal the core-shell interaction and its influence on the electronic and optical properties of the core-shell clusters, suggesting a composition-structure-property relationship for the design of core-shell CdSe and ZnSe nanoclusters.

  13. Constraining Black Carbon Aerosol over Asia using OMI Aerosol Absorption Optical Depth and the Adjoint of GEOS-Chem

    Science.gov (United States)

    Zhang, Li; Henze, David K.; Grell, Georg A.; Carmichael. Gregory R.; Bousserez, Nicolas; Zhang, Qiang; Torres, Omar; Ahn, Changwoo; Lu, Zifeng; Cao, Junji; Mao, Yuhao

    2015-01-01

    Accurate estimates of the emissions and distribution of black carbon (BC) in the region referred to here as Southeastern Asia (70degE-l50degE, 11degS-55degN) are critical to studies of the atmospheric environment and climate change. Analysis of modeled BC concentrations compared to in situ observations indicates levels are underestimated over most of Southeast Asia when using any of four different emission inventories. We thus attempt to reduce uncertainties in BC emissions and improve BC model simulations by developing top-down, spatially resolved, estimates of BC emissions through assimilation of OMI observations of aerosol absorption optical depth (AAOD) with the GEOS-Chem model and its adjoint for April and October of 2006. Overwhelming enhancements, up to 500%, in anthropogenic BC emissions are shown after optimization over broad areas of Southeast Asia in April. In October, the optimization of anthropogenic emissions yields a slight reduction (1-5%) over India and parts of southern China, while emissions increase by 10-50% over eastern China. Observational data from in situ measurements and AERONET observations are used to evaluate the BC inversions and assess the bias between OMI and AERONET AAOD. Low biases in BC concentrations are improved or corrected in most eastern and central sites over China after optimization, while the constrained model still underestimates concentrations in Indian sites in both April and October, possibly as a. consequence of low prior emissions. Model resolution errors may contribute up to a factor of 2.5 to the underestimate of surface BC concentrations over northern India. We also compare the optimized results using different anthropogenic emission inventories and discuss the sensitivity of top-down constraints on anthropogenic emissions with respect to biomass burning emissions. In addition, the impacts of brown carbon, the formulation of the observation operator, and different a priori constraints on the optimization are

  14. Intersubband optical absorption between multi energy levels of electrons in InGaN/GaN spherical core-shell quantum dots

    Science.gov (United States)

    Liu, W. H.; Qu, Y.; Ban, S. L.

    2017-02-01

    The intersubband optical absorption between multi energy levels of electrons in InxGa1-xN/GaN spherical core-shell quantum dots (CSQDs) and ternary mixed crystal and size effects have been investigated by using the principle of density matrix. Electronic eigenstates under the effect of built-in electric field (BEF) have been calculated by a finite element method. The results show that optical absorption between intersubbands with main quantum numbers n = 1 and n = 2 are as important as that between ones with n = 1 and different angular quantum numbers when the BEF is taken into account. In consideration of BEF, the saturation of total optical absorption coefficients (ACs) and secondary peaks of refractive index changes (RICs) appear when incident light intensity I surpasses a certain value. For a given I, the maximum ACs and zero RICs positions in InxGa1-xN/GaN CSQDs with a fixed shell size have a blue-shift when x increases or the core InxGa1-xN radius R1 decreases from 5 nm. However, when R1 > 5 nm, ACs and RICs tend to be stable. The results indicate that effective adjustment of ACs and RICs in CSQDs with BEFs by size is in a limited scale range. The saturation of ACs or secondary peaks of RICs appear more likely in CSQDs with smaller x or larger R1. These results are expected to be helpful both in the further theoretical and experimental study on optic devices consisting of CSQDs.

  15. Testing and optical modeling of novel concentrating solar receiver geometries to increase light trapping and effective solar absorptance

    Science.gov (United States)

    Yellowhair, Julius; Ho, Clifford K.; Ortega, Jesus D.; Christian, Joshua M.; Andraka, Charles E.

    2015-09-01

    Concentrating solar power receivers are comprised of panels of tubes arranged in a cylindrical or cubical shape on top of a tower. The tubes contain heat-transfer fluid that absorbs energy from the concentrated sunlight incident on the tubes. To increase the solar absorptance, black paint or a solar selective coating is applied to the surface of the tubes. However, these coatings degrade over time and must be reapplied, which reduces the system performance and increases costs. This paper presents an evaluation of novel receiver shapes and geometries that create a light-trapping effect, thereby increasing the effective solar absorptance and efficiency of the solar receiver. Several prototype shapes were fabricated from Inconel 718 and tested in Sandia's solar furnace at an irradiance of ~30 W/cm2. Photographic methods were used to capture the irradiance distribution on the receiver surfaces. The irradiance profiles were compared to results from raytracing models. The effective solar absorptance was also evaluated using the ray-tracing models. Results showed that relative to a flat plate, the new geometries could increase the effective solar absorptance from 86% to 92% for an intrinsic material absorptance of 86%, and from 60% to 73% for an intrinsic material absorptance of 60%.

  16. Effects of acoustic radiation force and shear waves for absorption and stiffness sensing in ultrasound modulated optical tomography.

    Science.gov (United States)

    Li, Rui; Elson, Daniel S; Dunsby, Chris; Eckersley, Robert; Tang, Meng-Xing

    2011-04-11

    Ultrasound-modulated optical tomography (UOT) combines optical contrast with ultrasound spatial resolution and has great potential for soft tissue functional imaging. One current problem with this technique is the weak optical modulation signal, primarily due to strong optical scattering in diffuse media and minimal acoustically induced modulation. The acoustic radiation force (ARF) can create large particle displacements in tissue and has been shown to be able to improve optical modulation signals. However, shear wave propagation induced by the ARF can be a significant source of nonlocal optical modulation which may reduce UOT spatial resolution and contrast. In this paper, the time evolution of shear waves was examined on tissue mimicking-phantoms exposed to 5 MHz ultrasound and 532 nm optical radiation and measured with a CCD camera. It has been demonstrated that by generating an ARF with an acoustic burst and adjusting both the timing and the exposure time of the CCD measurement, optical contrast and spatial resolution can be improved by ~110% and ~40% respectively when using the ARF rather than 5 MHz ultrasound alone. Furthermore, it has been demonstrated that this technique simultaneously detects both optical and mechanical contrast in the medium and the optical and mechanical contrast can be distinguished by adjusting the CCD exposure time.

  17. Lowest excited states and optical absorption spectra of donor-acceptor copolymers for organic photovoltaics: a new picture emerging from tuned long-range corrected density functionals.

    Science.gov (United States)

    Pandey, Laxman; Doiron, Curtis; Sears, John S; Brédas, Jean-Luc

    2012-11-01

    Polymers with low optical gaps are of importance to the organic photovoltaics community due to their potential for harnessing a large portion of the solar energy spectrum. The combination along their backbones of electron-rich and electron-deficient fragments contributes to the presence of low-lying excited states that are expected to display significant charge-transfer character. While conventional hybrid functionals are known to provide unsatisfactory results for charge-transfer excitations at the time-dependent DFT level, long-range corrected (LRC) functionals have been reported to give improved descriptions in a number of systems. Here, we use such LRC functionals, considering both tuned and default range-separation parameters, to characterize the absorption spectra of low-optical-gap systems of interest. Our results indicate that tuned LRC functionals lead to simulated optical-absorption properties in good agreement with experimental data. Importantly, the lowest-lying excited states (excitons) are shown to present a much more localized nature than initially anticipated.

  18. Anionic or Cationic S-Doping in Bulk Anatase TiO 2 : Insights on Optical Absorption from First Principles Calculations

    KAUST Repository

    Harb, M.

    2013-05-02

    Using first principles calculations, we investigate the structural, electronic, optical, and energetic properties of S-doped anatase TiO2 bulk systems. To ensure accurate band gap predictions, we use the HSE06 exchange correlation functional, and the absorption spectra are obtained with density functional perturbation (DFPT) theory by employing HSE06. Various oxidation states (anionic and cationic) of sulfur are considered depending on the location in bulk TiO2: in interstitial position or in substitution for either oxygen or titanium atoms. Among the explored structures, two anionic and one cationic configurations induce an improved optical absorption response in the visible region as observed experimentally. Moreover, we undertake a thermodynamic analysis as a function of the chemical potential of oxygen and considering three relevant sulfur chemical doping agents (S 2, H2S, and thiourea). It highlights that cationic configurations (S4+ and S6+) are strongly stabilized in a wide range of oxygen chemical potential (including standard conditions), whereas anionic species are stabilized only at very low chemical potential of oxygen. The metastable cationic Ti(1-2x)O2S2x system involving the presence of S4+ species in substitution for Ti 4+, with the formation of SO2 units, should offer the best compromise between the thermodynamic conditions and the expected optical properties. © 2013 American Chemical Society.

  19. Lowest excited states and optical absorption spectra of donor–acceptor copolymers for organic photovoltaics: a new picture emerging from tuned long-range corrected density functionals

    KAUST Repository

    Pandey, Laxman

    2012-01-01

    Polymers with low optical gaps are of importance to the organic photovoltaics community due to their potential for harnessing a large portion of the solar energy spectrum. The combination along their backbones of electron-rich and electron-deficient fragments contributes to the presence of low-lying excited states that are expected to display significant charge-transfer character. While conventional hybrid functionals are known to provide unsatisfactory results for charge-transfer excitations at the time-dependent DFT level, long-range corrected (LRC) functionals have been reported to give improved descriptions in a number of systems. Here, we use such LRC functionals, considering both tuned and default range-separation parameters, to characterize the absorption spectra of low-optical-gap systems of interest. Our results indicate that tuned LRC functionals lead to simulated optical-absorption properties in good agreement with experimental data. Importantly, the lowest-lying excited states (excitons) are shown to present a much more localized nature than initially anticipated. © 2012 the Owner Societies.

  20. Real-Time Analysis of Isoprene in Breath by Using Ultraviolet-Absorption Spectroscopy with a Hollow Optical Fiber Gas Cell.

    Science.gov (United States)

    Iwata, Takuro; Katagiri, Takashi; Matsuura, Yuji

    2016-12-05

    A breath analysis system based on ultraviolet-absorption spectroscopy was developed by using a hollow optical fiber as a gas cell for real-time monitoring of isoprene in breath. The hollow optical fiber functions as an ultra-small-volume gas cell with a long path. The measurement sensitivity of the system was evaluated by using nitric-oxide gas as a gas sample. The evaluation result showed that the developed system, using a laser-driven, high-intensity light source and a 3-m-long, aluminum-coated hollow optical fiber, could successfully measure nitric-oxide gas with a 50 ppb concentration. An absorption spectrum of a breath sample in the wavelength region of around 200-300 nm was measured, and the measured spectrum revealed the main absorbing components in breath as water vapor, isoprene, and ozone converted from oxygen by radiation of ultraviolet light. The concentration of isoprene in breath was estimated by multiple linear regression. The regression analysis results showed that the proposed analysis system enables real-time monitoring of isoprene during the exhaling of breath. Accordingly, it is suitable for measuring the circadian variation of isoprene.

  1. Complexation of lactate with neodymium(III) and europium(III) at variable temperatures: studies by potentiometry, microcalorimetry, optical absorption, and luminescence spectroscopy.

    Science.gov (United States)

    Tian, Guoxin; Martin, Leigh R; Rao, Linfeng

    2010-11-15

    The complexation of neodymium(III) and europium(III) with lactate was studied at variable temperatures by potentiometry, absorption spectrophotometry, luminescence spectroscopy, and microcalorimetry. The stability constants of three successive lactate complexes (ML(2+), ML(2)(+), and ML(3)(aq), where M stands for Nd and Eu and L stands for lactate) at 10, 25, 40, 55, and 70 °C were determined. The enthalpies of complexation at 25 °C were determined by microcalorimetry. Thermodynamic data show that the complexation of trivalent lanthanides (Nd(3+) and Eu(3+)) with lactate is exothermic and the complexation becomes weaker at higher temperatures. Results from optical absorption and luminescence spectroscopy suggest that the complexes are inner-sphere chelate complexes in which the protonated α-hydroxyl group of lactate participates in the complexation.

  2. The effect of temperature and pressure on optical absorption spectra of transition zone minerals - Implications for the radiative conductivity of the Earth's interior

    Science.gov (United States)

    Thomas, S.; Jacobsen, S. D.; Bina, C. R.; Goncharov, A. F.; Frost, D. J.; McCammon, C. A.

    2010-12-01

    Optical absorption spectra of high-pressure minerals can be used as indirect tools to calculate radiative conductivities of the Earth’s interior [e.g., 1]. Recent high-pressure studies imply that e.g. ringwoodite, γ-(Mg,Fe)2SiO4, does not become opaque in the near infrared and visible region, as previously assumed, but remains transparent to 21.5 GPa [2]. Therefore, it has been concluded that radiative heat transfer does not necessarily become blocked at high pressures of the mantle and ferromagnesian minerals actually might contribute to the heat flow in the Earth’s interior [2]. However, experimental results on temperature effects on radiative heat transfer are not available. We studied the effect of both, pressure and temperature, on the optical absorption of hydrous Fe-bearing ringwoodite, γ-(Mg,Fe)2SiO4, and hydrous Fe-bearing wadsleyite, β-(Mg,Fe)2SiO4, which are the main components of the Earth’s transition zone. Gem-quality single-crystals were synthesized at 18 GPa and 1400 °C in a 5000t multianvil apparatus. Crystals were analyzed by Mössbauer and Raman spectroscopy, electron microprobe analysis and single-crystal X-ray diffraction. For optical absorption measurements in the IR - VIS - UV spectral range (400 - 50000 cm-1) 50 µm sized single-crystals of ringwoodite and wadsleyite were double polished to thicknesses of 13 µm and 18 µm, respectively, and loaded in resistively heated diamond-anvil cells with argon as pressure medium. After taking measurements at high pressure and room temperature, ringwoodite was studied at 26 GPa up to 650 °C and wadsleyite spectra were recorded at 16 GPa up to 450 °C. At ambient pressure the absorption spectrum of ringwoodite reveals a crystal field band (Fe2+) at 12075 cm-1, an intervalence charge transfer band (Fe2+ to Fe3+) at 16491 cm-1, and an absorption edge due to ligand-metal charge transfer close to 30000 cm-1. The wadsleyite spectrum is characterized by a similar absorption edge in the VIS-UV range

  3. Grazing-angle fiber-optic fourier transform infrared reflection-absorption spectroscopy for the in situ detection and quantification of two active pharmaceutical ingredients on glass.

    Science.gov (United States)

    Perston, Benjamin B; Hamilton, Michelle L; Williamson, Bryce E; Harland, Peter W; Thomson, Mary A; Melling, Peter J

    2007-02-01

    Fourier transform infrared reflection-absorption spectroscopy has been used with a fiber-optic grazing-angle reflectance probe as a rapid, in situ method for trace surface analysis of acetaminophen and aspirin at loadings of approximately 0-2 microg cm(-2) on glass. Partial least-squares multivariate regression permits the loadings to be quantified, simultaneously, with root-mean-squared errors of prediction of RMSEP approximately 0.1 microg cm(-2) for both compounds. The detection limits are estimated to be LD approximately 0.2 microg cm(-2).

  4. Thermal bleaching of optical absorption and photoluminescence spectra of γ-irradiated CaF_2:Dy:Pb:Na single crystals

    Institute of Scientific and Technical Information of China (English)

    S.M.; Moses; Kennedy

    2010-01-01

    The variation of the optical absorption (OA) and photoluminescence (PL) spectra with temperature was studied on γ-irradiated CaF2:Dy:Pb:Na single crystals. The OA spectrum showed bands around 2.05, 3.20, 3.82 and 6.20 eV which could be attributed to different sodium associated (SA) colour centres (CCs) such as MNa and RA+ . Heating the crystal indicated the annihilation and formation of different SACCs. The excitation spectrum for the characteristic Dy3+ emission at 2.14 eV immediately after irradiation was...

  5. In vivo estimation of pigment composition and optical absorption cross-section by spectroradiometry in four aquatic photosynthetic micro-organisms.

    Science.gov (United States)

    Méléder, Vona; Laviale, Martin; Jesus, Bruno; Mouget, Jean Luc; Lavaud, Johann; Kazemipour, Farzaneh; Launeau, Patrick; Barillé, Laurent

    2013-12-05

    The objective of the present study was to estimate in vivo pigment composition and to retrieve absorption cross-section values, a(∗), of photosynthetic micro-organisms using a non-invasive technique of reflectance spectrometry. To test the methodology, organisms from different taxonomical groups and different pigment composition were used (Spirulina platensis a Cyanophyta, Porphyridium cruentum a Rhodophyta, Dunaliella tertiolecta a Chlorophyta and Entomoneis paludosa a Bacillariophyta) and photoacclimated to two different irradiance levels: 25 μmol photonm(-2)s(-1) (Low Light, LL) and 500 μmol photonm(-2)s(-1) (High Light, HL). Second derivative spectra from reflectance were used to identify pigment in vivo absorption bands that were linked to specific pigments detected by high performance liquid chromatography. Whereas some absorption bands such as those induced by Chlorophyll (Chl) a (416, 440, 625 and around 675 nm) were ubiquous, others were taxonomically specific (e.g. 636 nm for Chl c in E. paludosa) and/or photo-physiological dependent (e.g. 489 nm for zeaxanthin in the HL-acclimated S. platensis). The optical absorption cross-section, a(∗), was retrieved from reflectance data using a radiative transfer model previously developed for microphytobenthos. Despite the cellular Chl a decrease observed from LL to HL (up to 88% for S. platensis), the a(∗) increased, except for P. cruentum. This was attributed to a 'package effect' and to a greater absorption by photoprotective carotenoids that did not contribute to the energy transfer to the core Chl a.

  6. Energy levels and far-infrared optical absorption of impurity doped semiconductor nanorings: Intense laser and electric fields effects

    Science.gov (United States)

    Barseghyan, M. G.

    2016-11-01

    The effects of electron-impurity interaction on energy levels and far-infrared absorption in semiconductor nanoring under the action of intense laser and lateral electric fields have been investigated. Numerical calculations are performed using exact diagonalization technique. It is found that the electron-impurity interaction and external fields change the energy spectrum dramatically, and also have significant influence on the absorption spectrum. Strong dependence on laser field intensity and electric field of lowest energy levels, also supported by the Coulomb interaction with impurity, is clearly revealed.

  7. Investigation of linear optical absorption coefficients in core-shell quantum dot (QD) luminescent solar concentrators (LSCs)

    Science.gov (United States)

    Ebrahimipour, Bahareh Alsadat; Askari, Hassan Ranjbar; Ramezani, Ali Behjat

    2016-09-01

    The interlevel absorption coefficient of CdSe/ZnS and ZnS/CdSe core-shell Quantum Dot (QD) in luminescent solar concentrators (LSCs) is reported. By considering the quantum confinement effects, the wave functions and eigenenergies of electrons in the nonperturebative system consists of a core-shell QD have been numerically calculated under the frame work of effective-mass approximation by solving a three-dimensional Schrӧdinger equation. And then the absorption coefficient is obtained under density matrix approximation considering in the polymer sheets of the concentrator including the core-shell QDs. The effect of the hetero-structure geometry upon the energy spectrum and absorption coefficient associated to interlevel transitions was also considered. The results show that the core-shell QDs can absorb the photons with higher energy in solar spectrum as compared to the inverted core-shell. And with a small shell layer diameter, the core-shell QDs produce larger linear absorption coefficients and consequently higher efficiency values, however it is inversed for inverted core-shell QDs. The work described here gives a detailed insight into the promise of QD-based LSCs and the optoelectronic devices applications.

  8. Dynamics of the one-dimensional Heisenberg model and optical absorption of spinons in cuprate antiferromagnetic chains

    NARCIS (Netherlands)

    Lorenzana, J.; Eder, R

    1997-01-01

    We use numerical and analytical results to construct a simple ansatz for the energy dynamical correlation function of the one-dimensional antiferromagnetic Heisenberg model. This is applied to compute the phonon-assisted absorption spectra of magnetic excitations (spinons) in quasi-one-dimensional s

  9. Intersubband optical absorption coefficients and refractive index changes in a graded quantum well under intense laser field: Effects of hydrostatic pressure, temperature and electric field

    Energy Technology Data Exchange (ETDEWEB)

    Ungan, F., E-mail: fungan@cumhuriyet.edu.tr [Department of Physics, Cumhuriyet University, 58140 Sivas (Turkey); Grupo de Materia Condensade-UdeA, Instituto de Fisica, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín (Colombia); Restrepo, R.L. [Grupo de Materia Condensade-UdeA, Instituto de Fisica, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín (Colombia); Escuela de Ingeniería de Antioquia AA 7516, Medellín (Colombia); Mora-Ramos, M.E. [Grupo de Materia Condensade-UdeA, Instituto de Fisica, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín (Colombia); Facultad de Ciencias, Universidad Autonoma del Estado de Morelos, Ave. Universidad 1001, CP 62209, Cuernavaca, Morelos (Mexico); Morales, A.L.; Duque, C.A. [Grupo de Materia Condensade-UdeA, Instituto de Fisica, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21, Medellín (Colombia)

    2014-02-01

    The effects of hydrostatic pressure, temperature, and electric field on the optical absorption coefficients and refractive index changes associated with intersubband transition in a typical GaAs/Ga{sub 0.7}Al{sub 0.3}As graded quantum well under intense laser field have been investigated theoretically. The electron energy eigenvalues and the corresponding eigenfunctions of the graded quantum well are calculated within the effective mass approximation and envelope wave function approach. The analytical expressions of the optical properties are obtained using the compact density-matrix approach and the iterative method. The numerical results show that the linear and nonlinear optical properties depend strongly on the intense laser field and electric field but weakly on the hydrostatic pressure and temperature. Additionally, it has been found that the electronic and optical properties in a GaAs/Ga{sub 0.7}Al{sub 0.3}As graded quantum well under the intense laser field can be tuned by changing these external inputs. Thus, these results give a new degree of freedom in the devices applications.

  10. Performance evaluation of reflective electro-absorption modulator based optical source using a broadband light seed source for colorless WDM-PON applications.

    Science.gov (United States)

    Kim, Chul Han

    2013-05-20

    The performance of reflective electro-absorption modulator (R-EAM) based optical source has been evaluated for the use in high-capacity wavelength-division multiplexed passive optical networks (WDM-PONs). In our measurements, a broadband light source (BLS) was used as a seeding source for the cost-effective implementation of R-EAM based optical source. At first, a bit-error rate (BER) floor at 10(-6) was observed even in a back-to-back configuration with the BLS seeded R-EAM source. This is mainly because of the excess intensity noise (EIN) within BLS and the signal-to-noise ratio (SNR) degradation induced by a high insertion loss of R-EAM. To mitigate both effects of EIN and SNR degradation, a reflective semiconductor optical amplifier (RSOA) was also used for the implementation of our BLS seeded R-EAM source. Then, we have evaluated the impact of various noises, such as EIN, chromatic dispersion of transmission fiber and in-band crosstalk, on the system's performance using our BLS seeded R-EAM optical source. From the results, we have found that a 3-dB bandwidth of the BLS seeded R-EAM optical source should be wider than ~0.8 nm to achieve an error-free transmission of 1.25 Gb/s signal. We have also confirmed that there was a trade-off between the dispersion- and the in-band crosstalk-induced penalties due to the wide source bandwidth of our BLS seeded R-EAM source, like the cases of BLS seeded RSOA and Fabry-Perot laser diode (FP-LD) sources.

  11. Influence of image charge effect on impurity-related optical absorption coefficients and refractive index changes in a spherical quantum dot

    Science.gov (United States)

    Vartanian, A. L.; Asatryan, A. L.; Vardanyan, L. A.

    2017-03-01

    We have investigated the influence of an image charge effect (ICE) on the energies of the ground and first few excited states of a hydrogen-like impurity in a spherical quantum dot (QD) in the presence of an external electric field. The oscillator strengths of transitions from the 1 s -like state to excited states of 2px and 2pz symmetries are calculated as the functions of the strengths of the confinement potential and the electric field. Also, we have studied the effect of image charges on linear and third-order nonlinear optical absorption coefficients and refractive index changes (RICs). The results show that image charges lead to the decrease of energies for all the hydrogen-like states, to the significant enhancement of the oscillator strengths of transitions between the impurity states, and to comparatively large blue shifts in linear, nonlinear, and total absorption coefficients and refractive index changes. Our results indicate that the total optical characteristics can be controlled by the strength of the confinement and the electric field.

  12. A Novel Algorithm Applied to Common Thermal-Optical Transmission Data for Determining Mass Absorption Cross Sections of Atmospheric Black Carbon: Applications to the Indian Outflow

    Science.gov (United States)

    Andersson, A.; Sheesley, R. J.; Kirillova, E.; Gustafsson, O.

    2010-12-01

    High wintertime concentrations of black carbon aerosols (BCA) over South Asia and the Northern Indian Ocean are thought to have a large impact on the regional climate. Direct absorption of sunlight by BCAs causes heating of the atmosphere and cooling at the surface. To quantify such effects it is important to characterize a number of different properties of the aerosols. Here we present a novel application of the thermal-optical (OCEC) instrument in which the laser beam is used to obtain optical information about the aerosols. In particular, the novel algorithm accounts for non-carbon contributions to the light extinction. Combining these light extinction coefficients with the simultaneously constrained Elemental Carbon (EC) concentrations, the Mass Absorption Cross Section (MAC) is computed. Samples were collected during a continuous 14-month campaign Dec 2008 - Mar 2009 at Sinaghad in Western India and on Hanimaadhoo, the Northernmost Island in the Maldives. This data set suggests that the MAC of the BCAs are variable, sometimes by a factor of 3 compared to the mean. This observation adds to the complexity of calculating the radiative forcing for BCAs, reinforcing previous observations that parameters such as aerosol mixing state and sources need to be taken into account.

  13. Coherent control of optical absorption and the energy transfer pathway of an infrared quantum dot hybridized with a VO2 nanoparticle

    Science.gov (United States)

    Hatef, Ali; Zamani, Naser; Johnston, William

    2017-04-01

    We systematically investigate the optical response of a semiconductor quantum dot (QD) hybridized with a vanadium dioxide nanoparticle (VO2NP) in the infrared (IR) region. The VO2NP features a semiconductor to metal phase change characteristic below and above a critical temperature that leads to an abrupt change in the particle’s optical properties. This feature means that the QD-VO2NP hybrid system can support the coherent coupling of exciton-polaritons and exciton-plasmon polaritons in the semiconductor and metal phases of the VO2NP, respectively. In our calculations, the VO2NP phase transition is modelled with a filling fraction (f), representing the fraction of the VO2NP in the metallic phase. The phase transition is driven by the hybrid system’s interaction with a continuous wave (CW) IR laser field. In this paper, we show how control over the filling fraction results in the enhancement or suppression of the QD’s linear absorption. These variations in the QD absorption is due to dramatic changes in the effective local field experienced by the QD and the non-radiative energy transfer from the QD to the VO2NP. The presented results have the potential to be applied to the design of thermal sensors at the nanoscale.

  14. Dependence of the absorption of pulsed CO2-laser radiation by silane on wavenumber, fluence, pulse duration, temperature, optical path length, and pressure of absorbing and nonabsorbing gases

    Science.gov (United States)

    Bl/aŻejowski, Jerzy; Gruzdiewa, Ludwika; Rulewski, Jacek; Lampe, Frederick W.

    1995-05-01

    The absorption of three lines [P(20), 944.2 cm-1; P(14), 949.2 cm-1; and R(24), 978.5 cm-1] of the pulsed CO2 laser (0001-1000 transition) by SiH4 was measured at various pulse energy, pulse duration, temperature, optical path length, and pressure of the compound and nonabsorbing foreign gases. In addition, low intensity infrared absorption spectrum of silane was compared with high intensity absorption characteristics for all lines of the pulsed CO2 laser. The experimental dependencies show deviations from the phenomenological Beer-Lambert law which can be considered as arising from the high intensity of an incident radiation and collisions of absorbing molecules with surroundings. These effects were included into the expression, being an extended form of the Beer-Lambert law, which reasonably approximates all experimental data. The results, except for extending knowledge on the interaction of a high power laser radiation with matter, can help understanding and planning processes leading to preparation of silicon-containing technologically important materials.

  15. Electronic structure of organometal halide perovskite CH3NH3BiI3 and optical absorption extending to infrared region

    Science.gov (United States)

    Zhu, H. X.; Liu, J.-M.

    2016-11-01

    The electronic structure and optical absorption spectrum of organometal halide perovskite compound CH3NH3BiI3 as a substituting candidate of well-concerned CH3NH3PbI3 not only for environmental friendly consideration are studied using the first principles calculations. It is revealed that a Bi replacement of Pb in CH3NH3PbI3 does not change seriously the band edge structure but the bandgap becomes narrow. Consequently, CH3NH3BiI3 exhibits not only stronger visible light absorption than CH3NH3PbI3 does but more strong absorption in the infrared region, which is however absent in CH3NH3PbI3. It is suggested that CH3NH3BiI3 may be one of even more promising alternatives to CH3NH3PbI3 for spectrum-broad and highly-efficient solar cells.

  16. Broadband optical absorption enhancement of N719 dye in ethanol by gold-silver alloy nanoparticles fabricated under laser ablation technique

    Science.gov (United States)

    Al-Azawi, Mohammed A.; Bidin, Noriah; Abbas, Khaldoon N.; Bououdina, Mohamed; Azzez, Shrook A.

    2016-04-01

    The formation of gold-silver alloy nanoparticles (Au-Ag alloy NPs) by a two-step process with a pulsed Nd:YAG laser without any additives is presented. Mixtures of Au and Ag colloidal suspensions were separately obtained by 1064-nm laser ablation of metallic targets immersed in ethanol. Subsequently, the as-mixed colloidal suspensions were reirradiated by laser-induced heating at the second-harmonic generation (532 nm) for different irradiation periods of time. The absorption spectra and morphology of the colloidal alloys were studied as a function of exposure time to laser irradiation. Transmission electron microscopy revealed the formation of monodispersed spherical nanoparticles with a homogeneous size distribution in all the synthesized samples. UV-vis and photoluminescence spectroscopy measurements were also employed to characterize the changes in the light absorption and emission of N719 dye solution with different concentrations of Au-Ag colloidal alloys, respectively. The localized surface plasmon resonance (LSPR) of Au-Ag alloy NPs enhanced the absorption and fluorescence peak of the dye solution. The mixture of dye molecules with a higher concentration of alloy NPs exhibited an additional coupling of dipole moments with the LSPR, thereby contributing to the improvement of the optical properties of the mixture.

  17. Absorption Coefficient of InGaAs V-shaped Quantum Wires Integrated in Optical Waveguides by MBE Growth

    Science.gov (United States)

    1998-06-01

    Integrated in Optical Waveguides by MBE Growth DISTRIBUTION: Approved for public release, distribution unlimited Availability: Hard copy only. This...coefficient of InGaAs V-shaped quantum wires integrated in optical waveguides by MBE growth F Filipowitzt, C. Gourgont, D. Martint, Y Magnenatt, P. Giaccarit...observation The fabrication of waveguides that contains QWR consists of three process sequences: (i) MBE growth of the lower waveguide cladding and half of the

  18. Linear and nonlinear optical absorption coefficients in GaAs/Ga{sub 1-x}Al{sub x}As concentric double quantum rings: Effects of hydrostatic pressure and aluminum concentration

    Energy Technology Data Exchange (ETDEWEB)

    Baghramyan, H.M. [Department of Solid State Physics, Yerevan State University, Al. Manookian 1, 0025 Yerevan (Armenia); Barseghyan, M.G., E-mail: mbarsegh@ysu.am [Department of Solid State Physics, Yerevan State University, Al. Manookian 1, 0025 Yerevan (Armenia); Kirakosyan, A.A. [Department of Solid State Physics, Yerevan State University, Al. Manookian 1, 0025 Yerevan (Armenia); Restrepo, R.L. [Escuela de Ingenieria de Antioquia, AA 7516 Medellin (Colombia); Duque, C.A. [Instituto de Fisica, Universidad de Antioquia, AA 1226 Medellin (Colombia)

    2013-02-15

    The linear and nonlinear intra-band optical absorption coefficients in GaAs/Ga{sub 1-x}Al{sub x}As two-dimensional concentric double quantum rings are investigated. Taking into account the combined effects of hydrostatic pressure and aluminum concentration the energies of the ground (n=1,l=0) and the first excited state (n=2,l=1) have been found using the effective mass approximation and the transfer matrix formalism. The energies of these states and the corresponding threshold energy of the intra-band optical transitions are examined as a function of hydrostatic pressure and aluminum concentration for different sizes of the structure. We also investigated the dependencies of the linear, nonlinear, and total optical absorption coefficients as functions of the incident photon energy for different values of hydrostatic pressure, aluminum concentration, sizes of the structure, and incident optical intensity. Its is found that the effects of the hydrostatic pressure and the aluminum concentration lead to a shifting of the resonant peaks of the intra-band optical spectrum. - Highlights: Black-Right-Pointing-Pointer Linear and nonlinear intra-band absorption in quantum rings. Black-Right-Pointing-Pointer Threshold energy strongly depends on the hydrostatic pressure. Black-Right-Pointing-Pointer Threshold energy strongly depends on the stoichiometry and sizes of structure. Black-Right-Pointing-Pointer Optical absorption is affected by the incident optical intensity.

  19. Optical properties and chemical composition of aerosol particles at an urban location: An estimation of the aerosol mass scattering and absorption efficiencies

    Science.gov (United States)

    Titos, G.; Foyo-Moreno, I.; Lyamani, H.; Querol, X.; Alastuey, A.; Alados-Arboledas, L.

    2012-02-01

    We investigated aerosol optical properties, mass concentration and chemical composition over a 1 year period (from March 2006 to February 2007) at an urban site in Southern Spain (Granada, 37.18°N, 3.58°W, 680 m above sea level). Light-scattering and absorption measurements were performed using an integrating nephelometer and a MultiAngle Absorption Photometer (MAAP), respectively, with no aerosol size cut-off and without any conditioning of the sampled air. PM10 and PM1 (ambient air levels of atmospheric particulate matter finer than 10 and 1 microns) were collected with two high volume samplers, and the chemical composition was investigated for all samples. Relative humidity (RH) within the nephelometer was below 50% and the weighting of the filters was also at RH of 50%. PM10 and PM1 mass concentrations showed a mean value of 44 ± 19 μg/m3 and 15 ± 7 μg/m3, respectively. The mineral matter was the major constituent of the PM10-1 fraction (contributing more than 58%) whereas organic matter and elemental carbon (OM+EC) contributed the most to the PM1 fraction (around 43%). The absorption coefficient at 550 nm showed a mean value of 24 ± 9 Mm-1 and the scattering coefficient at 550 nm presented a mean value of 61 ± 25 Mm-1, typical of urban areas. Both the scattering and the absorption coefficients exhibited the highest values during winter and the lowest during summer, due to the increase in the anthropogenic contribution and the lower development of the convective mixing layer during winter. A very low mean value of the single scattering albedo of 0.71 ± 0.07 at 550 nm was calculated, suggesting that urban aerosols in this site contain a large fraction of absorbing material. Mass scattering and absorption efficiencies of PM10 particles exhibited larger values during winter and lower during summer, showing a similar trend to PM1 and opposite to PM10-1. This seasonality is therefore influenced by the variations on PM composition. In addition, the mass

  20. The X-ray spectra of optically selected Seyfert 2 galaxies. Are there any Sy2 galaxies with no absorption?

    CERN Document Server

    Pappa, A; Stewart, G C; Zezas, A L

    2001-01-01

    We present an X-ray spectral analysis of a sample of 8 bona-fide Seyfert 2 galaxies, selected on the basis of their high $[OIII]\\lambda5007$ flux, from the Ho et al. (1997) spectroscopic sample of nearby galaxies. We find that, in general, the X-ray spectra of our Seyfert 2 galaxies are complex, with some our objects having spectra different from the 'typical' spectrum of X-ray selected Seyfert 2 galaxies. Two (NGC3147 and NGC4698) show no evidence for intrinsic absorption. We suggest this is due to the fact that when the torus suppresses the intrinsic medium and hard energy flux, underlying emission from the host galaxy, originating in circumnuclear starbursts, and scattering from warm absorbers contributes in these energy bands more significantly. Our asca data alone cannot discriminate whether low absorption objects are Compton-thick AGN with a strong scattered component or lack an obscuring torus. The most striking example of our low absorption Seyfert 2 is NGC4698. Its spectrum could be explained by eith...

  1. Optical Absorption of CdI2 Single Molecule and Clusters Incorporated into Zeolite Na-FAU

    Science.gov (United States)

    Nishida, Koji; Ohnishi, Akimasa; Kitaura, Mamoru; Sasaki, Minoru; Kuriyama, Yasunao

    2009-10-01

    The absorption spectra of CdI2 molecules adsorbed through a vapor phase into zeolite Na-FAU are investigated at liquid nitrogen temperature by changing the loading density Ld of CdI2 per supercage from a dilute condition of 0.1 to a saturated condition of 5.5. The theoretical absorption spectrum of a CdI2 molecule is also derived using the wave functions obtained from a relativistic self-consistent-field discrete-variational Xα calculation. A predominant band is observed at 5.8 eV together with sub-bands at 5.0 and 5.5 eV at Ld = 0.1. The comparison between the experimental and theoretical spectra clarifies that these bands originate from the electronic transitions of an isolated CdI2 molecule. Moreover, it suggests that the CdI2 molecule interacts with zeolite. Another three bands appear at 4.8, 5.3, and 6.0 eV at Ld = 2.0 when Ld increases, which are attributed to a CdI2 two-molecule cluster. The lowest absorption band continuously shifts toward the lower-energy side with an increase in Ld between 2.0 and 5.5. This shift is explained by the quantum size effect on photoexcitation energy.

  2. Thermal annealing and UV irradiation effects on structure, morphology, photoluminescence and optical absorption spectra of EDTA-capped ZnS nanoparticles

    Science.gov (United States)

    Osman, M. A.; Othman, A. A.; El-Said, Waleed A.; Abd-Elrahim, A. G.; Abu-sehly, A. A.

    2016-02-01

    Monodispersed ZnS nanoparticles (NPs) were prepared by the chemical precipitation method. Thermally induced structural, morphological and optical changes have been investigated using x-ray diffraction, high-resolution transmission electron microscopy, optical absorption, photoluminescence (PL), and Fourier transform infrared and Raman spectroscopy. It was found that D increases with increasing annealing temperature (T a). The onset of the ZnS phase transition from cubic to hexagonal structure takes place at 400 °C, while cubic ZnS transforms into hexagonal ZnO via thermal oxidation in air at 600 °C. It is also noted that increasing T a results in the red shift of the optical band gap (E\\text{g}\\text{opt} ) and the thermal bleaching of exciton absorption. The PL spectrum of as-prepared ZnS nanopowder shows UV emission bands at 363 and 395 nm and blue and green emission at 438 and 515 nm, respectively. With increasing T a up to 500 °C, these bands were quenched and red-shifted. In addition, the UV irradiation effects on colloidal ZnS NPs were investigated. UV irradiation at a dose  <13 J cm-2 leads to a decrease in D, the blue shift of E\\text{g}\\text{opt} and the enhancement of PL intensity. This behavior was explained in terms of surface modification by photopolymerization, the formation of a ZnSO4 passivation layer, as well as the reduction of D by photocorrosion. At a UV irradiation dose  <13 J cm-2 both E\\text{g}\\text{opt} and D did not change and PL intensity was quenched, which were caused by the creation of nonradiative surface states by the photodegradation of the capping agent and photopassivated layer. The mechanism of the PL emission process in ZnS NPs was discussed and an energy band diagram was proposed.

  3. General Strategy for Broadband Coherent Perfect Absorption and Multi-wavelength All-optical Switching Based on Epsilon-Near-Zero Multilayer Films

    Science.gov (United States)

    Kim, Tae Young; Badsha, Md. Alamgir; Yoon, Junho; Lee, Seon Young; Jun, Young Chul; Hwangbo, Chang Kwon

    2016-03-01

    We propose a general, easy-to-implement scheme for broadband coherent perfect absorption (CPA) using epsilon-near-zero (ENZ) multilayer films. Specifically, we employ indium tin oxide (ITO) as a tunable ENZ material, and theoretically investigate CPA in the near-infrared region. We first derive general CPA conditions using the scattering matrix and the admittance matching methods. Then, by combining these two methods, we extract analytic expressions for all relevant parameters for CPA. Based on this theoretical framework, we proceed to study ENZ CPA in a single layer ITO film and apply it to all-optical switching. Finally, using an ITO multilayer of different ENZ wavelengths, we implement broadband ENZ CPA structures and investigate multi-wavelength all-optical switching in the technologically important telecommunication window. In our design, the admittance matching diagram was employed to graphically extract not only the structural parameters (the film thicknesses and incident angles), but also the input beam parameters (the irradiance ratio and phase difference between two input beams). We find that the multi-wavelength all-optical switching in our broadband ENZ CPA system can be fully controlled by the phase difference between two input beams. The simple but general design principles and analyses in this work can be widely used in various thin-film devices.

  4. Probing formally forbidden optical transitions in PbSe nanocrystals by time- and energy-resolved transient absorption spectroscopy

    NARCIS (Netherlands)

    Schins, J.M.; Trinh, M.T.; Houtepen, A.J.; Siebbeles, L.D.A.

    2009-01-01

    The first two peaks of the optical extinction spectrum of PbSe nanocrystals in solution have been assigned in the literature to the 1Sh1Se and 1Ph1Pe transitions. In the present work we assign the transitions causing extinction in the energy region between these two lowest-energy peaks. Our femtosec

  5. Physical, thermal, structural and optical absorption studies of vanadyl doped magnesium oxy-chloride bismo-borate glasses

    Directory of Open Access Journals (Sweden)

    M.S. Dahiya

    2015-06-01

    Full Text Available Oxy-chloride bismuth-borate glasses with composition xMgCl2·(30 − xMgO·20Bi2O3·50B2O3 containing 2 mol% doping of V2O5 (x = 12, 15, 20, 25 and 30 are prepared by melt-quenching technique. The structural, thermal and optical behaviors are explained by analyzing the data obtained from density (D, molar volume (Vm, theoretical optical basicity (Λth, differential scanning calorimetry (DSC, FTIR and UV–vis results. A decrease in D and increase in Vm (except for sample MBV3 for which D is maximum on increasing chloride content suggests the formation of non-bridging oxygen atoms. Maximum glass transition temperature (Tg and crystallization temperature (Tx have been observed for sample MBV3. The glass stability (S and stability ratio (S/Tg have been calculated from the values of Tg and Tx and both are having maximum values for sample MBV3. Study of the FTIR spectra in the mid-IR range reveals the presence of both triangular and tetrahedral coordinated boron. The optical studies through UV–vis spectral analysis show non-sharp edge. The optical band gap (Eg is also maximum for sample MBV3.

  6. Enhancement and suppression of surface plasmon resonance in Ag aggregate by optical gain and absorption in surrounding dielectric medium

    CERN Document Server

    Noginov, M A; Bahoura, M; Drachev, V P; Ritzo, B A; Shalaev, V M; Small, C; Zhu, G

    2005-01-01

    We have observed the compensation of loss in metal by gain in interfacing dielectric in the mixture of aggregated silver nanoparticles and rhodamine 6G dye. The demonstrated six-fold enhancement of the Rayleigh scattering is the evidence of the increase of the quality factor of the surface plasmon (SP) resonance. The reported experimental observation paves the road to many practical applications of nanoplasmonics. We have also predicted and experimentally observed a suppression of the surface SP resonance in metallic nanoparticles embedded in a dielectric host with absorption.

  7. Theory of direct and indirect effect of two-photon absorption on nonlinear optical losses in high power semiconductor lasers

    Science.gov (United States)

    Avrutin, E. A.; Ryvkin, B. S.

    2017-01-01

    The effect of the transverse laser structure on two-photon absorption (TPA) related effects in high-power diode lasers is analysed theoretically. The direct effect of TPA is found to depend significantly on the transverse waveguide structure, and predicted to be weaker in broad and asymmetric waveguide designs. The indirect effect of TPA, via carrier generation in the waveguide and free-carrier absorption, is analysed for the case of a symmetric laser waveguide and shown to be strongly dependent on the active layer position. With the active layer near the mode peak, the indirect effect is weaker than the direct effect due to the population of TPA-created carriers being efficiently depleted by their diffusion and capture into the active layer, whereas for the active layer position strongly shifted towards the p-cladding, the indirect effect can become the dominant power limitation at very high currents. It is shown that for optimizing a laser design for pulsed high power operation, both TPA related effects and the inhomogeneous carrier accumulation in the waveguide caused by diffusive current need to be taken into account.

  8. Assessment of the coherent potential approximation for the absorption spectra of a one-dimensional Frenkel exciton system with a Gaussian distribution of fluctuations in the optical transition frequency

    Science.gov (United States)

    Boukahil, A.; Avgin, I.; Huber, D. L.

    2015-01-01

    We investigate the accuracy of the coherent potential approximation (CPA) for the optical absorption spectra of a one-dimensional Frenkel exciton system with nearest-neighbor interactions and a Gaussian distribution of fluctuations in the optical transition frequency (diagonal Gaussian disorder). Our earlier studies have established that the CPA gives highly accurate results for the integral of the density of states of this system. In this paper we compare the CPA results for the normalized optical absorption with the finite-array calculations of Schreiber and Toyozawa and Schreiber for the same model. It is found that the CPA results for the absorption are in good agreement with their findings. It is pointed out that an expansion of the density of states in terms of the eigenstates of the ideal (no disorder) array contains a term proportional to the normalized absorption. Since the density of states is accurately approximated by the CPA, the presence of this term explains the success of the CPA in reproducing the absorption spectra. Our findings support the use of the Gaussian disorder model to interpret the absorption spectra of one and quasi-one dimensional exciton systems.

  9. Modeling optical properties of polymer-solvent complexes: the chloroform influence on the P3HT and N2200 absorption spectra.

    Science.gov (United States)

    Dias Ledo, Rodrigo Maia; Leal, Luciano Almeida; de Brito Silva, Patrick Pascoal; da Cunha, Wiliam Ferreira; de Souza, Leonardo Evaristo; Almeida Fonseca, Antonio Luciano; Ceschin, Artemis Marti; da Silva Filho, Demétrio Antonio; Ribeiro Junior, Luiz Antonio

    2017-02-01

    The optical properties of polymer/solvent systems composed by the polymers P3HT and PolyeraActivInk N2200 under the present of chloroform as solvent are experimentally and theoretically investigated using UV-Vis spectroscopy, molecular dynamics (MD), and density functional theory (DFT) calculations. The study is focused on obtaining the theoretical methodologies that properly describes the experimentally obtained absorption spectra of polymer-solvent complexes. In order to investigate the solvent influence, two different approaches are taken into account: the solvation shell method (SSM) and the polarizable continuum model (PCM). Our findings shown that SSM simulations, which combine MD and DFT calculations, are in good agreement with the experimental data. Moreover, it is obtained that simulations in the framework of PCM do not provide a fair description of the real system. Importantly, these results may pave the way for better descriptions of some optoelectronic properties of interest in polymer/solvent systems. Graphical Abstract ᅟ.

  10. Determination of true optical absorption and scattering coefficient of wooden cell wall substance by time-of-flight near infrared spectroscopy.

    Science.gov (United States)

    Kitamura, Ryunosuke; Inagaki, Tetsuya; Tsuchikawa, Satoru

    2016-02-22

    The true absorption coefficient (μa) and reduced scattering coefficient (μ´s) of the cell wall substance in Douglas fir were determined using time-of-flight near infrared spectroscopy. Samples were saturated with hexane, toluene or quinolone to minimize the multiple reflections of light on the boundary between pore-cell wall substance in wood. μ´s exhibited its minimum value when the wood was saturated with toluene because the refractive index of toluene is close to that of the wood cell wall substance. The optical parameters of the wood cell wall substance calculated were μa = 0.030 mm(-1) and μ´s= 18.4 mm(-1). Monte Carlo simulations using these values were in good agreement with the measured time-resolved transmittance profiles.

  11. Optical absorption and electron spin resonance studies of Cu2+ in Li2O–Na2O–B2O3–As2O3 glasses

    Indian Academy of Sciences (India)

    N Srinivasa Rao; Shashidhar Bale; M Purnima; K Siva Kumar; Syed Rahman

    2005-10-01

    The local structure around Cu2+ ion has been examined by means of electron spin resonance and optical absorption measurements in Li2O–(40 – )Na2O–50B2O3–10As2O3 glasses. The site symmetry around Cu2+ ions is tetragonally distorted octahedral. The ground state of Cu2+ is $d_{x^2–y^2}$. The glass exhibited broad absorption band near infrared region and small absorption band around 548 nm, which was assigned to the ${}^{2}B_{1g} \\rightarrow {}^{2}E_{g}$ transition.

  12. Numerical Optimization of Tunnel-recombination Junction and Optical Absorption Properties of a-Si:H/a-SiGe:H Double-junction Solar Cell

    Institute of Scientific and Technical Information of China (English)

    KE Shaoying; WANG Chong; PAN Tao; WANG Zhaoqing; YANG Jie; YANG Yu

    2015-01-01

    The tunnel-recombination junction (TRJ) and optical absorption properties of a-Si:H/a-SiGe:H dou-ble-junction solar cell were calculated by means of one dimensional simulator named AMPS-1D at the radiation of AM1.5G with a power density of 100 mW/cm2. Since the TRJ is the core component of the tandem solar cell, the optical absorption of the sub-cells and the electronic transport properties at the interface of the sub-cells are affected by the thickness and doping concentration of the TRJ. As a result, the TRJ parameters were optimized. The numerical results indicate that the maximum conversion efficiency (Ef) of 9.862% can be obtained when the thickness and doping con-centration of the TRJ are 10 nm and 5´1019 cm–3, respectively. Based on the analysis of the contour map of short circuit current density, the optimal current matching can be achieved for 130 nm-thick topi-layer and 250 nm-thick bottom i-layer. In addition, four kinds of TRJ structures were also simulated for the comparison purpose. According to the cal-culated resistivity and band structures of the four TRJs, the efficiency of the solar cell withn-typeμc-Si:H layer and p-type a-Si:H layer in TRJ structure is greater than that with other TRJ structures. It is assumed that the effect of the band offset that results in the formation of triangular barrier and backscattering behavior at the edge of the TRJ could be responsible to this phenomenon.

  13. Numerical Optimization of Tunnel-recombination Junction and Optical Absorption Properties of a-Si:H/a-SiGe:H Double-junction Solar Cell

    Institute of Scientific and Technical Information of China (English)

    KE; Shaoying; WANG; Chong; PAN; Tao; WANG; Zhaoqing; YANG; Jie; YANG; Yu

    2015-01-01

    The tunnel-recombination junction(TRJ) and optical absorption properties of a-Si:H/a-Si Ge:H double-junction solar cell were calculated by means of one dimensional simulator named AMPS-1D at the radiation of AM1.5G with a power density of 100 m W/cm2. Since the TRJ is the core component of the tandem solar cell, the optical absorption of the sub-cells and the electronic transport properties at the interface of the sub-cells are affected by the thickness and doping concentration of the TRJ. As a result, the TRJ parameters were optimized. The numerical results indicate that the maximum conversion efficiency(Eff) of 9.862% can be obtained when the thickness and doping concentration of the TRJ are 10 nm and 5*1019 cm–3, respectively. Based on the analysis of the contour map of short circuit current density, the optimal current matching can be achieved for 130 nm-thick top i-layer and 250 nm-thick bottom i-layer. In addition, four kinds of TRJ structures were also simulated for the comparison purpose. According to the calculated resistivity and band structures of the four TRJs, the efficiency of the solar cell with n-type μc-Si:H layer and p-type a-Si:H layer in TRJ structure is greater than that with other TRJ structures. It is assumed that the effect of the band offset that results in the formation of triangular barrier and backscattering behavior at the edge of the TRJ could be responsible to this phenomenon.

  14. Plasmon-enhanced optical absorption and photocurrent in organic bulk heterojunction photovoltaic devices using self-assembled layer of silver nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Yoon, Woo-Jun; Jung, Kyung-Young; Teixeira, Fernando L. [Department of Electrical and Computer Engineering, Ohio State University, Columbus, OH 43210 (United States); Liu, Jiwen; Duraisamy, Thirumalai; Revur, Rao; Sengupta, Suvankar [MetaMateria Partners, 1275 Kinnear Road, Columbus, OH 43212 (United States); Berger, Paul R. [Department of Electrical and Computer Engineering, Ohio State University, Columbus, OH 43210 (United States); Department of Physics, Ohio State University, Columbus, OH 43210 (United States)

    2010-02-15

    Improved optical absorption and photocurrent for polythiophene-fullerene bulk heterojunction photovoltaic devices is demonstrated using a unique self-assembled monolayer of Ag nanoparticles formed from a colloidal solution. With the presence of suitable nanoparticle organic capping groups that inhibit its propensity to agglomerate, the particle-to-particle spacing can be tailored. Transmission electron microscopy reveals the self-assembled Ag nanospheres are highly uniform with an average diameter of {proportional_to}4 nm and controllable particle-to-particle spacing. The localized surface plasmon resonance peak is {proportional_to}465 nm with a narrow full width at half maximum (95 nm). In the spectral range of 350-650 nm, where the organic bulk heterojunction photoactive film absorbs, an enhanced optical absorption is observed due to the increased electric field in the photoactive layer by excited localized surface plasmons within the Ag nanospheres. Under the short-circuit condition, the induced photo-current efficiency (IPCE) measurement demonstrates that the maximum IPCE increased to {proportional_to}51.6% at 500 nm for the experimental devices with the self-assembled layer of Ag nanoparticles, while the IPCE of the reference devices without the plasmon-active Ag nanoparticles is {proportional_to}45.7% at 480 nm. For the experimental devices under air mass 1.5 global filtered illuminations with incident intensity of 100 mW/cm{sup 2}, the increased short-circuit current density is observed due to the enhancement of the photogeneration of excitons near the plasmon resonance of the Ag nanoparticles. (author)

  15. Characterization of penetration depth as a function of optical fiber separation at various absorption and scatter coefficients for a noninvasive metabolic sensor

    Science.gov (United States)

    DeMilo, Charles; Brukilacchio, Thomas; Soller, Babs R.; Soyemi, Olusola

    2004-06-01

    A visible-near IR (500-1,000nm) fiber optic sensor is under development that is intended to non-invasively assess muscle metabolism through the measurement of tissue pH and oxygen partial pressure. These parameters are calculated from the spectra of hemoglobin and myoglobin in muscle. The sensor consists of transmit (illumination) fibers and receive (detection) fibers that are coupled to a spectrometer. Light from the probe must penetrate below the surface of the skin and into a 5-10mm thick layer of muscle. A study was conducted to quantify the relationship between transmit and receive fiber separation and sensor penetration depth below the surface of the skin. A liquid phantom was created to replicate the absorption (μa) and reduced scatter coefficient (μs') profiles typically found in human blood and tissue. The phantom consisted of a solution of Intralipid and India ink in the appropriate concentrations to achieve desired reduced scatter coefficient and absorption profiles. The reduced scatter coefficient of the liquid phantom was achieved to an accuracy of +/-10% compared to previously published data. A fixed illumination fiber and translatable detector fiber were placed in the liquid phantom, and the fiber separation was varied from 3-40mm. Values of μa and μs' varied from 0.03-0.40 cm-1 and 5.0-15.0 cm-1 respectively. Results from the experiment demonstrate a strong correlation between penetration depth and fiber separation. Additionally, it was found that penetration depth was not substantially influenced by absorption and scatter concentration. As signal-to-noise is an important parameter in many non-invasive biomedical applications, the relative signal as a function of fiber separation was determined to follow an exponential relationship.

  16. Energy absorption buildup factors, exposure buildup factors and Kerma for optically stimulated luminescence materials and their tissue equivalence for radiation dosimetry

    Science.gov (United States)

    Singh, Vishwanath P.; Badiger, N. M.

    2014-11-01

    Optically stimulated luminescence (OSL) materials are sensitive dosimetric materials used for precise and accurate dose measurement for low-energy ionizing radiation. Low dose measurement capability with improved sensitivity makes these dosimeters very useful for diagnostic imaging, personnel monitoring and environmental radiation dosimetry. Gamma ray energy absorption buildup factors and exposure build factors were computed for OSL materials using the five-parameter Geometric Progression (G-P) fitting method in the energy range 0.015-15 MeV for penetration depths up to 40 mean free path. The computed energy absorption buildup factor and exposure buildup factor values were studied as a function of penetration depth and incident photon energy. Effective atomic numbers and Kerma relative to air of the selected OSL materials and tissue equivalence were computed and compared with that of water, PMMA and ICRU standard tissues. The buildup factors and kerma relative to air were found dependent upon effective atomic numbers. Buildup factors determined in the present work should be useful in radiation dosimetry, medical diagnostics and therapy, space dosimetry, accident dosimetry and personnel monitoring.

  17. Two-photon absorption, nonlinear optical and UV-vis spectral properties of 2-furanylmethyleneaminoantipyrine, benzylideneaminoantipyrine and cinnamilideneaminoantipyrine

    Energy Technology Data Exchange (ETDEWEB)

    Sun Yuxi, E-mail: yuxisun@163.com [Key Laboratory for Soft Chemistry and Functional Materials of Education Ministry, Nanjing University of Science and Technology, Nanjing 210094 (China) and Key Laboratory of Life-Organic Analysis, School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, Shandong 273165 (China); Hao Qingli; Tang Weihua; Wang Yufeng [Key Laboratory for Soft Chemistry and Functional Materials of Education Ministry, Nanjing University of Science and Technology, Nanjing 210094 (China); Yang Xujie, E-mail: yangx@mail.njust.edu.cn [Key Laboratory for Soft Chemistry and Functional Materials of Education Ministry, Nanjing University of Science and Technology, Nanjing 210094 (China); Lu Lude; Wang Xin [Key Laboratory for Soft Chemistry and Functional Materials of Education Ministry, Nanjing University of Science and Technology, Nanjing 210094 (China)

    2011-09-15

    Highlights: {yields} Three imine-bridged aromatic antipyrine derivatives as photo-responsive materials. {yields} The compounds exhibit two-photon absorption and first-hyperpolarization properties {yields} The compounds have long-range electron transfer characteristics. - Abstract: Organic compounds as functional materials have attracted much keen interest in the past three decades owing to their potential applications in science and technology. Currently, great efforts have been made in looking for suitable photo-responsive materials among the multifarious organic compounds. Herein we reported the photophysical properties of 2-furanylmethylene-aminoantipyrine (FMAAP), benzylideneaminoantipyrine (BIAAP) and cinnamilideneamino-antipyrine (CIAAP) studied by a combined experimental and theoretical investigation. Two-photon absorption measurements give the cross-section values of 1.350 x 10{sup -50} cm{sup 4} s/photon for FMAAP, 1.046 x 10{sup -50} cm{sup 4} s/photon for BIAAP and 2.047 x 10{sup -50} cm{sup 4} s/photon for CIAAP. The calculated first-hyperpolarization values are of 2.303 x 10{sup -30}, 1.257 x 10{sup -29}, 2.889 x 10{sup -29} cm{sup 5}/esu for FMAAP, BIAAP and CIAAP, respectively. UV-vis spectroscopy technique further reveals that the studied compounds display long-range electron transfer characteristics by absorbing light of specific wavelengths of 294.5 nm for FMAAP, 293.2 nm for BIAAP and 303.1 nm for CIAAP. All the results indicate that the studied compounds are promising candidates of functionally photo-responsive materials.

  18. Attenuation from the optical to the extreme ultraviolet by dust associated with broad absorption line quasars: the driving force for outflows

    CERN Document Server

    Gaskell, C Martin; Singh, Japneet

    2016-01-01

    We use mid-IR to UV observations to derive a mean attenuation curve out to the rest-frame extreme ultraviolet (EUV) for "BAL dust" -- the dust causing the additional extinction of active galactic nuclei (AGNs) with broad absorption lines (BALQSOs). In contrast to the normal, relatively flat, mean AGN attenuation curve, BAL dust is well fit by a steeply rising, SMC-like curve. We confirm the shape of the theoretical Weingartner & Draine SMC curve out to 700 \\AA, but the drop in attenuation at still shorter wavelengths is less than predicted. The identical attenuation curve for low-ionization BALQSOs (LoBALs) does not support them being a "break out" phase in the life of AGNs. Although attenuation in the optical due to BAL dust is low ($E(B-V) \\sim 0.03 - 0.05$), the attenuation rises to one magnitude in the EUV because of the steep extinction curve. Here the dust optical depth is at the optimum value for radiative acceleration of dusty gas. Because the spectral energy distribution of AGNs peaks in the EUV ...

  19. 银铜纳米枝晶的生长及光学吸收性质%Growth of Silver - Copper Nanodendrites and Their Optical Absorption

    Institute of Scientific and Technical Information of China (English)

    张金生; 陈福义; 闫晓红; 刘婧; 樊莉红

    2011-01-01

    通过电沉积法制备出了Ag - Cu纳米枝晶,并表征了样品的晶体结构、微观形貌以及光学吸收特性.结果表明:当Ag+:Cu2>1时,制备出银铜纳米单相合金,Ag+:Cu2+< 1/4时,制备出银铜纳米双相合金.当E=-0.2V时,形成单个银铜纳米粒子和粒子团簇,吸收峰位于402 nm处:随着沉积电位的增加,形成纳米枝晶,且光学吸收峰发生蓝移.在不同成分的银铜合金中,当Ag+Cu2+=4:1时,形成银铜纳米枝晶,吸收峰在358 nm处,随着铜元素的增加,枝晶尺寸减小,光学吸收峰红移.结合电结晶理论和经典枝晶生长理论解释了Ag - Cu纳米枝晶的形成机制.%Ag - Cu nanodendrites have been synthesized by the electrodeposition method and their crystal structure, morphology and optical properties of samples were characterized. The results demonstrated that when the molar ratio of the Ag+ to Cu2 is > 1, the sample is present as silver - copper single phase nanoalloy, the molar ratio of the Ag+ to Cu2+ < 1/4, the sample is silver - copper double phase nano-alloy. When the deposition potential is -0.2 V, the Ag - Cu material is present as the isolated nanoparti-cles and particle clusters, the absorption peak is located at about 402 nm. With increasing of the deposition potential, Ag - Cu sample changes into nanodendrites and absorption peak is blue - shifted. For the effects of different ratios of Ag+ to Cu2 + , the sample is present as the silver - copper nanodendrites and the absorption peak is around 358 nm for Ag +: Cu2 + = 4:1. With increasing of the molar ratio of copper, the size of the nanodendrites decreases and the absorption peak has a red shift. The formation mechanism of Ag - Cu nanodendrites was revealed using the electrocrystallization theory and classical dendritic growth theory.

  20. A small shoulder of optical absorption in polycrystalline HfO2 by LDA+U approach

    Science.gov (United States)

    Qin, Liyuan; Li, Jinping; Meng, Songhe; Lu, Hantao; Tohyama, Takami

    2016-10-01

    The dielectric function of the wide-gap optical material HfO2 is investigated by the local density approximation (LDA)+U approach. We focus on the origin of the shoulder-like structure near the edge of the band gap in the imaginary part of the dielectric function, which has been observed on the thin films of monoclinic HfO2. A comparison study on the three polymorphs of hafnia shows that regardless of the underlying crystal structure, the existence of the shoulder is mainly controlled by the value of the shortest length of Hf-O bonds. The proposition is further supported by the numerical simulations of isostatic pressing. A possible implication in high-pressure measurements is suggested accordingly.

  1. Cooperative self-construction and enhanced optical absorption of nanoplates-assembled hierarchical Bi 2WO 6 flowers

    Science.gov (United States)

    Liu, Shengwei; Yu, Jiaguo

    2008-05-01

    Bi 2WO 6 hierarchical multilayered flower-like assemblies are fabricated on a large scale by a simple hydrothermal method in the presence of polymeric poly(sodium 4-styrenesulfonate). Such 3D Bi 2WO 6 assemblies are constructed from orderly arranged 2D layers, which are further composed of a large number of interconnected nanoplates with a mean side length of ca. 50 nm. The bimodal mesopores associated with such hierarchical assembly exhibit peak mesopore size of ca. 4 nm for the voids within a layer, and peak mesopore size of ca. 40 nm corresponding to the interspaces between stacked layers, respectively. The formation process is discussed on the basis of the results of time-dependent experiments, which support a novel 'coupled cooperative assembly and localized ripening' formation mechanism. More interestingly, we have noticed that the collective effect related to such hierarchical assembly induces a significantly enhanced optical absorbance in the UV-visible region. This work may shed some light on the design of complex architectures and exploitation of their potential applications.

  2. Infrared optical absorption in low-spin Fe 2+ -doped SrTiO 3

    Energy Technology Data Exchange (ETDEWEB)

    Comes, Ryan B.; Kaspar, Tiffany C.; Heald, Steve M.; Bowden, Mark E.; Chambers, Scott A.

    2016-01-06

    Band gap engineering in SrTiO3 and related titanate perovskites has long been explored due to the intriguing properties of the materials for photocatalysis and photovoltaic applications. A popular approach in the materials chemistry community is to substitutionally dope aliovalent transition metal ions onto the B site in the lattice to alter the valence band. However, in such a scheme there is limited control over the dopant valence, and compensating defects often form. Here we demonstrate a novel technique to controllably synthesize Fe2+- and Fe3+-doped SrTiO3 thin films without formation of compensating defects by co-doping with La3+ ions on the A site. We stabilize Fe2+-doped films by doping with two La ions for every Fe dopant, and find that the Fe ions exhibit a low-spin electronic configuration, producing optical transitions in the near infrared regime and degenerate doping. The novel electronic states observed here offer a new avenue for band gap engineering in perovskites for photocatalytic and photovoltaic applications.

  3. Donor impurity-related linear and nonlinear optical absorption coefficients in GaAs/Ga{sub 1−x}Al{sub x}As concentric double quantum rings: Effects of geometry, hydrostatic pressure, and aluminum concentration

    Energy Technology Data Exchange (ETDEWEB)

    Baghramyan, H.M.; Barseghyan, M.G.; Kirakosyan, A.A. [Department of Solid State Physics, Yerevan State University, Al. Manookian 1, 0025 Yerevan (Armenia); Restrepo, R.L. [Física Teórica y Aplicada, Escuela de Ingeniería de Antioquia, AA 7516, Medellín (Colombia); Grupo de Materia Condensada-UdeA, Instituto de Física, Facultadde Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21,Medellín (Colombia); Mora-Ramos, M.E. [Grupo de Materia Condensada-UdeA, Instituto de Física, Facultadde Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21,Medellín (Colombia); Facultad de Ciencias, Universidad Autónoma del Estado de Morelos, Av. Universidad 1001, CP 62209, Cuernavaca, Morelos (Mexico); Duque, C.A., E-mail: cduque@fisica.udea.edu.co [Grupo de Materia Condensada-UdeA, Instituto de Física, Facultadde Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No. 52-21,Medellín (Colombia)

    2014-01-15

    The linear and nonlinear optical absorption associated with the transition between 1s and 2s states corresponding to the electron-donor-impurity complex in GaAs/Ga{sub 1−x}Al{sub x}As three-dimensional concentric double quantum rings are investigated. Taking into account the combined effects of hydrostatic pressure and the variation of the aluminum concentration, the energies of the ground and first excited s-like states of a donor impurity in such a system have been calculated using the effective mass approximation and a variational method. The energies of these states and the corresponding threshold energy of the optical transitions are examined as functions of hydrostatic pressure, aluminum concentration, radial impurity position, as well as the geometrical dimensions of the structure. The dependencies of the linear, nonlinear and total optical absorption coefficients as functions of the incident photon energy are investigated for different values of those mentioned parameters. It is found that the influences mentioned above lead to either redshifts or blueshifts of the resonant peaks of the optical absorption spectrum. It is particularly discussed the unusual property exhibited by the third-order nonlinear of becoming positive for photon energies below the resonant transition one. It is shown that this phenomenon is associated with the particular features of the system under study, which determine the values of the electric dipole moment matrix elements. -- Highlights: • Intra-band optical absorption associated to impurity states in double quantum rings. • Combined effects of hydrostatic pressure and aluminum concentration are studied. • The influences mentioned above lead to shifts of resonant peaks. • It is discussed an unusual property exhibited by the third-order nonlinear absorption.

  4. The vertical distribution of BrO and aerosols in the Arctic: Measurements by active and passive differential optical absorption spectroscopy

    Science.gov (United States)

    Frieß, U.; Sihler, H.; Sander, R.; PöHler, D.; Yilmaz, S.; Platt, U.

    2011-07-01

    We present results from multiaxis differential optical absorption spectroscopy (MAX-DOAS) and long-path DOAS (LP-DOAS) measurements performed at the North Slope of Alaska from February to April 2009 as part of the Ocean-Atmosphere-Sea Ice-Snowpack Barrow 2009 campaign. For the first time, vertical profiles of aerosol extinction and BrO in the boundary layer were retrieved simultaneously from MAX-DOAS measurements using the method of optimal estimation. Even at very low visibility, retrieved extinction profiles and aerosol optical thickness are in good agreement with colocated ceilometer and Sun photometer measurements, respectively. BrO surface concentrations measured by MAX-DOAS and LP-DOAS are in very good agreement, and it has been found that useful information on the BrO vertical distribution can be retrieved from MAX-DOAS even in cases when blowing snow strongly reduces visibility. The retrieved BrO and extinction vertical profiles allow for a thorough characterization of the vertical structure of the boundary layer during numerous ozone depletion events observed during Barrow 2009. High BrO concentrations are usually present during the onset of ozone depletion events, and BrO disappears as ozone concentrations approach zero. The finding that elevated BrO concentrations occur mainly in the presence of high extinction near the surface strongly suggests that release of reactive bromine from airborne aerosols and/or ice particles at high wind speed plays an important role. Back trajectory calculations indicate that the particles were transported from the frozen ocean to the measurement site and that the release of reactive bromine from sea ice and/or frost flowers occurs when low temperatures (<250 K) prevail in the regions where reactive bromine is emitted.

  5. Optics

    CERN Document Server

    Fincham, W H A

    2013-01-01

    Optics: Ninth Edition Optics: Ninth Edition covers the work necessary for the specialization in such subjects as ophthalmic optics, optical instruments and lens design. The text includes topics such as the propagation and behavior of light; reflection and refraction - their laws and how different media affect them; lenses - thick and thin, cylindrical and subcylindrical; photometry; dispersion and color; interference; and polarization. Also included are topics such as diffraction and holography; the limitation of beams in optical systems and its effects; and lens systems. The book is recommen

  6. Comparing different light-emitting diodes as light sources for long path differential optical absorption spectroscopy NO2 and SO2 measurements

    Institute of Scientific and Technical Information of China (English)

    Chan Ka-Lok; Mark Wenig; Ling Liu-Yi; Andreas Hartl; Zheng Ni-Na; Gerrit Kuhlmann; Qin Min; Sun You-Wen; Xie Pin-Hua; Liu Wen-Qing

    2012-01-01

    In this paper,we present a comparison of different light-emitting diodes (LEDs) as the light source for long path differential optical absorption spectroscopy (LP-DOAS) atmospheric trace gas measurements.In our study,we use a fiberoptic design,where high power LEDs used as the light source are coupled into the telescope using a Y shape fiber bundle.Two blue and one ultraviolet (UV) LEDs with different emission wavelength ranges are tested for NO2 and SO2 measurements.The detailed description of the instrumental setup,the NO2 and SO2 retrieval procedure,the error analysis,and the preliminary results from the measurements carried out in Science Island,Hefei,Anhui,China are presented.Our first measurement results show that atmospheric NO2 and SO2 have strong temporal variations in that area and that the measurement accuracy is strongly dependent on the visibility conditions.The measured NO2 and SO2 data are compared to the Ozone Monitoring Instrument (OMI) satellite observations.The results show that the OMI NO2 product underestimates the ground level NO2 by 45%,while the OMI SO2 data are highly influenced by clouds and aerosols,which can lead to large biases in the ground level concentrations.During the experiment,the mixing ratios of the atmospheric NO2 and SO2 vary from 8 ppbv to 36 ppbv and from 3 ppbv to 18 ppbv,respectively.

  7. Comparing different light-emitting diodes as light sources for long path differential optical absorption spectroscopy NO2 and SO2 measurements

    Science.gov (United States)

    Chan, Ka-Lok; Ling, Liu-Yi; Andreas, Hartl; Zheng, Ni-Na; Gerrit, Kuhlmann; Qin, Min; Sun, You-Wen; Xie, Pin-Hua; Liu, Wen-Qing; Mark, Wenig

    2012-11-01

    In this paper, we present a comparison of different light-emitting diodes (LEDs) as the light source for long path differential optical absorption spectroscopy (LP-DOAS) atmospheric trace gas measurements. In our study, we use a fiberoptic design, where high power LEDs used as the light source are coupled into the telescope using a Y shape fiber bundle. Two blue and one ultraviolet (UV) LEDs with different emission wavelength ranges are tested for NO2 and SO2 measurements. The detailed description of the instrumental setup, the NO2 and SO2 retrieval procedure, the error analysis, and the preliminary results from the measurements carried out in Science Island, Hefei, Anhui, China are presented. Our first measurement results show that atmospheric NO2 and SO2 have strong temporal variations in that area and that the measurement accuracy is strongly dependent on the visibility conditions. The measured NO2 and SO2 data are compared to the Ozone Monitoring Instrument (OMI) satellite observations. The results show that the OMI NO2 product underestimates the ground level NO2 by 45%, while the OMI SO2 data are highly influenced by clouds and aerosols, which can lead to large biases in the ground level concentrations. During the experiment, the mixing ratios of the atmospheric NO2 and SO2 vary from 8 ppbv to 36 ppbv and from 3 ppbv to 18 ppbv, respectively.

  8. Active Stand-off Detection of Gas Leaks Using a Short Range Hard-target Backscatter Differential Optical Absorption System Based on a Quantum Cascade Laser Transmitter

    Science.gov (United States)

    Diaz, Adrian; Thomas, Benjamin; Castillo, Paulo; Gross, Barry; Moshary, Fred

    2016-06-01

    Fugitive gas emissions from agricultural or industrial plants and gas pipelines are an important environmental concern as they can contribute to the global increase of greenhouse gas concentration. Moreover, they are also a security and safety concern because of possible risk of fire/explosion or toxicity. This study presents gas concentration measurements using a quantum cascade laser open path system (QCLOPS). The system retrieves the pathaveraged concentration of N2O and CH4 by collecting the backscattered light from a scattering target. The gas concentration measurements have a high temporal resolution (68 ms) and are achieved at sufficient range (up to 40 m, ~ 130 feet) with a detection limit of 2.6 ppm CH4 and 0.4 ppm for N2O. Given these characteristics, this system is promising for mobile/multidirectional remote detection and evaluation of gas leaks. The instrument is monostatic with a tunable QCL emitting at ~ 7.7 μm wavelength range. The backscattered radiation is collected by a Newtonian telescope and focused on an infrared light detector. Puffs of N2O and CH4 are released along the optical path to simulate a gas leak. The measured absorption spectrum is obtained using the thermal intra-pulse frequency chirped DFB QCL and is analyzed to obtain path averaged gas concentrations.

  9. Controlled synthesis of alpha-Fe2O3 nanorods and its size-dependent optical absorption, electrochemical, and magnetic properties.

    Science.gov (United States)

    Zeng, Suyuan; Tang, Kaibin; Li, Tanwei

    2007-08-15

    Uniform alpha-Fe(2)O(3) nanorods with diameter of about 30 nm and length up to 500 nm were synthesized by a template-free hydrothermal method and a following calcination of the intermediate product in the air at 500 degrees C for 2 h. By carefully tuning the concentration of the reactants, a series of alpha-Fe(2)O(3) nanorods with gradient in aspect ratios can be obtained. The effect of the solvent was also evaluated. Based on the experimental facts, the formation mechanism of this one-dimensional structure was proposed. The size-dependent properties of the as-obtained alpha-Fe(2)O(3) nanorods were investigated. The optical absorption properties of the samples showed that the band gaps of the samples decreased in the sequence in which the size increased. The electrochemical performance of the samples showed that the discharge capacity decreased as the size of the sample increased, which may result from the high surface area and small size. The magnetic hysteresis measurements taken at 5 K showed that the coercivities of the samples were related to the aspect ratios of the samples, which may result from the larger shape anisotropy. However, the temperature-dependent field cooling magnetization showed that there was no Morin transition in the as-prepared samples, which may result from the surface effect.

  10. Real-time monitoring of benzene, toluene, and p-xylene in a photoreaction chamber with a tunable mid-infrared laser and ultraviolet differential optical absorption spectroscopy.

    Science.gov (United States)

    Parsons, Matthew T; Sydoryk, Ihor; Lim, Alan; McIntyre, Thomas J; Tulip, John; Jäger, Wolfgang; McDonald, Karen

    2011-02-01

    We describe the implementation of a mid-infrared laser-based trace gas sensor with a photoreaction chamber, used for reproducing chemical transformations of benzene, toluene, and p-xylene (BTX) gases that may occur in the atmosphere. The system performance was assessed in the presence of photoreaction products including aerosol particles. A mid-infrared external cavity quantum cascade laser (EC-QCL)-tunable from 9.41-9.88 μm (1012-1063 cm(-1))-was used to monitor gas phase concentrations of BTX simultaneously and in real time during chemical processing of these compounds with hydroxyl radicals in a photoreaction chamber. Results are compared to concurrent measurements using ultraviolet differential optical absorption spectroscopy (UV DOAS). The EC-QCL based system provides quantitation limits of approximately 200, 200, and 600 parts in 10(9) (ppb) for benzene, toluene, and p-xylene, respectively, which represents a significant improvement over our previous work with this laser system. Correspondingly, we observe the best agreement between the EC-QCL measurements and the UV DOAS measurements with benzene, followed by toluene, then p-xylene. Although BTX gas-detection limits are not as low for the EC-QCL system as for UV DOAS, an unidentified by-product of the photoreactions was observed with the EC-QCL, but not with the UV DOAS system.

  11. Cavity Ring Down Absorption of O2 in Air as a Temperature Sensor for an Open and a Cryogenic Optical Cavity.

    Science.gov (United States)

    Nyaupane, Parashu R; Perez-Delgado, Yasnahir; Camejo, David; Wright, Lesley M; Manzanares, Carlos E

    2016-06-30

    The A-band of oxygen has been measured at low resolution at temperatures between 90 K and 373 K using the phase shift cavity ring down (PS-CRD) technique. For temperatures between 90 K and 295 K, the PS-CRD technique presented here involves an optical cavity attached to a cryostat. The static cell and mirrors of the optical cavity are all inside a vacuum chamber at the same temperature of the cryostat. The temperature of the cell can be changed between 77 K and 295 K. For temperatures above 295 K, a hollow glass cylindrical tube without windows has been inserted inside an optical cavity to measure the temperature of air flowing through the tube. The cavity consists of two highly reflective mirrors which are mounted parallel to each other and separated by a distance of 93 cm. In this experiment, air is passed through a heated tube. The temperature of the air flowing through the tube is determined by measuring the intensity of the oxygen absorption as a function of the wavenumber. The A-band of oxygen is measured between 298 K and 373 K, with several air flow rates. To obtain the temperature, the energy of the lower rotational state for seven selected rotational transitions is linearly fitted to a logarithmic function that contains the relative intensity of the rotational transition, the initial and final rotational quantum numbers, and the energy of the transition. Accuracy of the temperature measurement is determined by comparing the calculated temperature from the spectra with the temperature obtained from a calibrated thermocouple inserted at the center of the tube. This flowing air temperature sensor will be used to measure the temperatures of cooling air at the input (cold air) and output (hot air) after cooling the blades of a laboratory gas turbine. The results could contribute to improvements in turbine blade cooling design.

  12. Optics

    CERN Document Server

    Fincham, W H A

    2013-01-01

    Optics: Eighth Edition covers the work necessary for the specialization in such subjects as ophthalmic optics, optical instruments and lens design. The text includes topics such as the propagation and behavior of light; reflection and refraction - their laws and how different media affect them; lenses - thick and thin, cylindrical and subcylindrical; photometry; dispersion and color; interference; and polarization. Also included are topics such as diffraction and holography; the limitation of beams in optical systems and its effects; and lens systems. The book is recommended for engineering st

  13. Differential Photoacoustic Particle Absorption Monitor Project

    Data.gov (United States)

    National Aeronautics and Space Administration — We developed a highly sensitive and compact instrument to directly measure particulate matter (PM) optical absorption. This device is based on differential...

  14. In situ aerosol optics in Reno, NV, USA during and after the summer 2008 California wildfires and the influence of absorbing and non-absorbing organic coatings on spectral light absorption

    Directory of Open Access Journals (Sweden)

    M. Gyawali

    2009-10-01

    Full Text Available Hundreds of wildfires in Northern California were sparked by lightning during the summer of 2008, resulting in downwind smoke for the months of June and July. Comparisons are reported for aerosol optics measurements in Reno, Nevada made during the very smoky month of July and the relatively clean month of August. Photoacoustic instruments equipped with integrating nephelometers were used to measure aerosol light scattering and absorption coefficients at wavelengths of 405 nm and 870 nm, revealing a strong variation of aerosol light absorption with wavelength. Insight on fuels burned is gleaned from comparison of Ångström exponents of absorption (AEA versus single scattering albedo (SSA of the ambient measurements with laboratory biomass smoke measurements for many fuels. Measurements during the month of August, which were largely unaffected by fire smoke, exhibit surprisingly low AEA for aerosol light absorption when the SSA is highest, again likely as a consequence of the underappreciated wavelength dependence of aerosol light absorption by particles coated with non-absorbing organic and inorganic matter. Coated sphere calculations were used to show that AEA as large as 1.6 are possible for wood smoke even with non-absorbing organic coatings on black carbon cores, suggesting care be exercised when diagnosing AEA.

  15. Mixed alkali effect in borate glasses - electron paramagnetic resonance and optical absorption studies in Cu sup 2 sup + doped xNa sub 2 O- (30 - x)K sub 2 O- 70B sub 2 O sub 3 glasses

    CERN Document Server

    Chakradhar, R P S; Rao, J L; Ramakrishna, J

    2003-01-01

    The mixed alkali borate glasses xNa sub 2 O-(30 - x)K sub 2 O-70B sub 2 O sub 3 (5 sup sup 2 B sub 2 sub g) and a weak band on the higher energy side at 22 115 cm sup - sup 1 corresponding to the transition ( sup 2 B sub 1 sub g -> sup 2 E sub g). With x > 5, the higher energy band disappears and the lower energy band shifts slightly to the lower energy side. By correlating the EPR and optical absorption data, the molecular orbital coefficients alpha sup 2 and beta sub 1 sup 2 are evaluated for the different glasses investigated. The values indicate that the in-plane sigma bonding is moderately covalent while the in-plane pi bonding is significantly ionic in nature; these exhibit a minimum with x = 15, showing the MAE. The theoretical values of optical basicity of the glasses have also been evaluated. From optical absorption edges, the optical bandgap energies have been calculated and are found to lie in the range 3.00-3.40 eV. The physical properties of the glasses studied have also been evaluated with respe...

  16. Early in-flight detection of SO2 via Differential Optical Absorption Spectroscopy: A feasible aviation safety measure to prevent potential encounters with volcanic plumes

    Science.gov (United States)

    Vogel, L.; Galle, B.; Kern, C.; Delgado, Granados H.; Conde, V.; Norman, P.; Arellano, S.; Landgren, O.; Lubcke, P.; Alvarez, Nieves J.M.; Cardenas, Gonzales L.; Platt, U.

    2011-01-01

    Volcanic ash constitutes a risk to aviation, mainly due to its ability to cause jet engines to fail. Other risks include the possibility of abrasion of windshields and potentially serious damage to avionic systems. These hazards have been widely recognized 5 since the early 1980s, when volcanic ash provoked several incidents of engine failure in commercial aircraft. In addition to volcanic ash, volcanic gases also pose a threat. Prolonged and/or cumulative exposure to sulphur dioxide (SO2) or sulphuric acid (H2SO4) aerosols potentially affects e.g. windows, air frame and may cause permanent damage to engines. SO2 receives most attention among the gas species commonly found in 10 volcanic plumes because its presence above the lower troposphere is a clear proxy for a volcanic cloud and indicates that fine ash could also be present. Up to now, remote sensing of SO2 via Differential Optical Absorption Spectroscopy (DOAS) in the ultraviolet spectral region has been used to measure volcanic clouds from ground based, airborne and satellite platforms. Attention has been given to vol- 15 canic emission strength, chemistry inside volcanic clouds and measurement procedures were adapted accordingly. Here we present a set of experimental and model results, highlighting the feasibility of DOAS to be used as an airborne early detection system of SO2 in two spatial dimensions. In order to prove our new concept, simultaneous airborne and ground-based measurements of the plume of Popocatepetl volcano, Mexico, were conducted in April 2010. The plume extended at an altitude around 5250 m above sea level and was approached and traversed at the same altitude with several forward looking DOAS systems aboard an airplane. These DOAS systems measured SO2 in the flight direction and at ±40 mrad (2.3◦) angles relative to it in both, horizontal and vertical directions. The approaches started at up to 25 km distance to 25 the plume and SO2 was measured at all times well above the detection

  17. Early in-flight detection of SO2 via Differential Optical Absorption Spectroscopy: a feasible aviation safety measure to prevent potential encounters with volcanic plumes

    Directory of Open Access Journals (Sweden)

    U. Platt

    2011-09-01

    Full Text Available Volcanic ash constitutes a risk to aviation, mainly due to its ability to cause jet engines to fail. Other risks include the possibility of abrasion of windshields and potentially serious damage to avionic systems. These hazards have been widely recognized since the early 1980s, when volcanic ash provoked several incidents of engine failure in commercial aircraft. In addition to volcanic ash, volcanic gases also pose a threat. Prolonged and/or cumulative exposure to sulphur dioxide (SO2 or sulphuric acid (H2SO4 aerosols potentially affects e.g. windows, air frame and may cause permanent damage to engines. SO2 receives most attention among the gas species commonly found in volcanic plumes because its presence above the lower troposphere is a clear proxy for a volcanic cloud and indicates that fine ash could also be present. Up to now, remote sensing of SO2 via Differential Optical Absorption Spectroscopy (DOAS in the ultraviolet spectral region has been used to measure volcanic clouds from ground based, airborne and satellite platforms. Attention has been given to volcanic emission strength, chemistry inside volcanic clouds and measurement procedures were adapted accordingly. Here we present a set of experimental and model results, highlighting the feasibility of DOAS to be used as an airborne early detection system of SO2 in two spatial dimensions. In order to prove our new concept, simultaneous airborne and ground-based measurements of the plume of Popocatépetl volcano, Mexico, were conducted in April 2010. The plume extended at an altitude around 5250 m above sea level and was approached and traversed at the same altitude with several forward looking DOAS systems aboard an airplane. These DOAS systems measured SO2 in the flight direction and at ±40 mrad (2.3° angles relative to it in both, horizontal and vertical directions. The approaches started at up to 25 km distance to the plume and SO2 was measured at all times well above the

  18. nc- Si/a- SiOx:H复合薄膜的结构及光吸收特性%Structure and optical absorption properties of nc- Si/a- SiOx:H composite thin film

    Institute of Scientific and Technical Information of China (English)

    郭震宁; 郭亨群; 王加贤; 张文珍; 李世忱

    2001-01-01

    采用 PECVD技术制备的 a- SiOx:H (0 SiOx:H基质的量子点复合膜( nc- Si/a- SiOx:H)。利用 TEM技术, Raman散射谱和光吸收谱等 , 较系统地研究了该复合膜的膜结构和光吸收特性。实验结果表明:纳米硅嵌埋颗粒呈多晶结构, 颗粒大小随退火温度升高而增大。复合膜光吸收边随纳米硅颗粒尺寸的减小发生了蓝移,表现出 明显的量子限域效应。%Sillicon nanocrystals embedded in a- SiOx:H (0 PECVD technique and high- temperature annealing treatment. Using TEM technique, Raman scattering and photo- absorption measurements, the optical properties of the thin films was investigated as well as their structures. The results show that the structure of nc- Si partical is polycrystalline, and the average diameter of the Si nanocrystals increases with annealing tempereture increasing. Optical absorption pro- perties of this kind of film was studied . Quantum confinement effect is observed clearly.With decreasing nc- Si size, the blue shift of the absorption edge is found.

  19. Optical and FT Infrared Absorption Spectra of 3d Transition Metal Ions Doped in NaF-CaF2-B2O3 Glass and Effects of Gamma Irradiation

    Directory of Open Access Journals (Sweden)

    F. H. A. Elbatal

    2014-01-01

    Full Text Available Combined optical and FTIR spectroscopy has been employed to investigate the undoped NaF-CaF2-B2O3 glass together with samples containing 0.2% dopant of 3d TM ions before and after gamma irradiation. The optical spectrum of the undoped glass reveals strong UV absorption with two peaks which are related to unavoidable trace iron impurity within the raw materials. Upon gamma irradiation, an induced visible broad band centered at 500 nm is resolved and is related to B-O hole center or nonbridging oxygen hole center. TMs-doped samples exhibit characteristic absorption due to each respective TM ion but with faint colors. Gamma irradiation of TMs-doped samples reveals the same induced visible band at 500–510 nm in most samples except CuO and Cr2O3-doped glasses. Infrared absorption spectra reveal characteristic vibrational bands due to triangular and tetrahedral borate groups. The introduction of NaF and CaF2 modifies the borate network forming BO3F tetrahedra. The introduction of 3d TMs as dopants did not make any obvious changes in the FTIR spectra due to their low content (0.2%. Gamma irradiation causes only minor variations in the intensities of the characteristic IR borate bands while the bands at about 1640 cm−1 and 3450 cm−1 reveal distinct growth in most samples.

  20. The effects of the electric and intense laser field on the binding energies of donor impurity states (1s and 2p±) and optical absorption between the related states in an asymmetric parabolic quantum well

    Science.gov (United States)

    Kasapoglu, E.; Sakiroglu, S.; Sökmen, I.; Restrepo, R. L.; Mora-Ramos, M. E.; Duque, C. A.

    2016-10-01

    We have calculated the effects of electric and intense laser fields on the binding energies of the ground and some excited states of conduction electrons coupled to shallow donor impurities as well as the total optical absorption coefficient for transitions between 1s and 2p± electron-impurity states in a asymmetric parabolic GaAs/Ga1-x AlxAs quantum well. The binding energies were obtained using the effective-mass approximation within a variational scheme. Total absorption coefficient (linear and nonlinear absorption coefficient) for the transitions between any two impurity states were calculated from first- and third-order dielectric susceptibilities derived within a perturbation expansion for the density matrix formalism. Our results show that the effects of the electric field, intense laser field, and the impurity location on the binding energy of 1s-impurity state are more pronounced compared with other impurity states. If the well center is changed to be Lc0), the effective well width decreases (increases), and thus we can obtain the red or blue shift in the resonant peak position of the absorption coefficient by changing the intensities of the electric and non-resonant intense laser field as well as dimensions of the well and impurity positions.