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Sample records for absorption fine structure

  1. X-ray absorption fine structure (XAFS) studies of cobalt silicide thin films

    Energy Technology Data Exchange (ETDEWEB)

    Naftel, S.J.; Coulthard, I.; Hu, Y.; Sham, T.K.; Zinke-Allmang, M. [Univ. of Western Ontario, London, Ontario (Canada)

    1998-12-31

    Cobalt silicide thin films, prepared on Si(100) wafers, have been studied by X-ray absorption near edge structures (XANES) at the Si K-, L{sub 2,3}- and Co K-edges utilizing both total electron (TEY) and fluorescence yield (FLY) detection as well as extended X-ray absorption fine structure (EXAFS) at the Co K-edge. Samples made using DC sputter deposition on clean Si surfaces and MBE were studied along with a bulk CoSi{sub 2} sample. XANES and EXAFS provide information about the electronic structure and morphology of the films. It was found that the films studied have essentially the same structure as bulk CoSi{sub 2}. Both the spectroscopy and materials characterization aspects of XAFS (X-ray absorption fine structures) are discussed.

  2. Extended X-ray absorption fine structure investigation of nitrogen stabilized expanded austenite

    DEFF Research Database (Denmark)

    Oddershede, Jette; Christiansen, Thomas; Ståhl, Kenny;

    2010-01-01

    As-delivered austenitic stainless steel and nitrogen stabilized expanded austenite, both fully nitrided and denitrided (in H2), were investigated with Cr, Fe and Ni extended X-ray absorption fine structure. The data shows pronounced short-range ordering of Cr and N. For the denitrided specimen...

  3. Ab initio self-consistent x-ray absorption fine structure analysis for metalloproteins.

    Science.gov (United States)

    Dimakis, Nicholas; Bunker, Grant

    2006-12-01

    X-ray absorption fine structure is a powerful tool for probing the structures of metals in proteins in both crystalline and noncrystalline environments. Until recently, a fundamental problem in biological XAFS has been that ad hoc assumptions must be made concerning the vibrational properties of the amino acid residues that are coordinated to the metal to fit the data. Here, an automatic procedure for accurate structural determination of active sites of metalloproteins is presented. It is based on direct multiple-scattering simulation of experimental X-ray absorption fine structure spectra combining electron multiple scattering calculations with density functional theory calculations of vibrational modes of amino acid residues and the genetic algorithm differential evolution to determine a global minimum in the space of fitting parameters. Structure determination of the metalloprotein active site is obtained through a self-consistent iterative procedure with only minimal initial information.

  4. The 16th International Conference on X-ray Absorption Fine Structure (XAFS16)

    Science.gov (United States)

    Grunwaldt, J.-D.; Hagelstein, M.; Rothe, J.

    2016-05-01

    This preface of the proceedings volume of the 16th International Conference on X- ray Absorption Fine Structure (XAFS16) gives a glance on the five days of cutting-edge X-ray science which were held in Karlsruhe, Germany, August 23 - 28, 2015. In addition, several satellite meetings took place in Hamburg, Berlin and Stuttgart, a Sino-German workshop, three data analysis tutorials as well as special symposia on industrial catalysis and XFELs were held at the conference venue.

  5. Photoconductivity measurement of polymers by x-ray absorption fine structure

    Institute of Scientific and Technical Information of China (English)

    1999-01-01

    Photoconductivity spectra measurement of polymers at x-ray energies around the Zn and Co K edges,shows obvious x-ray absorption fine structure oscillations.The photoconductivity spectra obtained for gapped and sandwiched electrode geometric samples,indicate that the shape of photoconductivity spectrum depends on the electrode configuration of the samples.The thickness of the conduction layer can be estimated from the photoconductivity spectrum.

  6. Solution spectroelectrochemical cell for in situ X-ray absorption fine structure

    Energy Technology Data Exchange (ETDEWEB)

    Antonio, M.R.; Soderholm, L. [Argonne National Lab., IL (United States). Chemistry Div.; Song, I. [Case Western Reserve Univ., Cleveland, OH (United States)

    1995-06-12

    A purpose-built spectroelectrochemical cell for in situ fluorescence XAFS (X-ray Absorption Fine Structure) measurements of bulk solution species during constant-potential electrolysis is described. The cell performance was demonstrated by the collection of europium L{sub 3}-edge XANES (X-ray Absorption Near Edge Structure) throughout the course of electrolysis of an aqueous solution of EuCl{sub 3}{center_dot}6H{sub 2}O in 1 M H{sub 2}SO{sub 4}. The europium L{sub 3}-edge resonances reported here for the Eu{sup III} and Eu{sup II} ions demonstrate that their 2p{sub 3/2} {yields} 5d electronic transition probabilities are not the same.

  7. A new analysis of fine-structure constant measurements and modelling errors from quasar absorption lines

    CERN Document Server

    Wilczynska, Michael R; King, Julian A; Murphy, Michael T; Bainbridge, Matthew B; Flambaum, Victor V

    2015-01-01

    We present an analysis of 23 absorption systems along the lines of sight towards 18 quasars in the redshift range of $0.4 \\leq z_{abs} \\leq 2.3$ observed on the Very Large Telescope (VLT) using the Ultraviolet and Visual Echelle Spectrograph (UVES). Considering both statistical and systematic error contributions we find a robust estimate of the weighted mean deviation of the fine-structure constant from its current, laboratory value of $\\Delta\\alpha/\\alpha=\\left(0.22\\pm0.23\\right)\\times10^{-5}$, consistent with the dipole variation reported in Webb et al. and King et al. This paper also examines modelling methodologies and systematic effects. In particular we focus on the consequences of fitting quasar absorption systems with too few absorbing components and of selectively fitting only the stronger components in an absorption complex. We show that using insufficient continuum regions around an absorption complex causes a significant increase in the scatter of a sample of $\\Delta\\alpha/\\alpha$ measurements, th...

  8. Possible evidence for a variable fine structure constant from QSO absorption lines motivations, analysis and results

    CERN Document Server

    Murphy, M T; Flambaum, V V; Dzuba, V A; Churchill, C W; Prochaska, J X; Barrow, John D; Wolfe, A M

    2001-01-01

    An experimental search for variation in the fundamental coupling constants is strongly motivated by modern high-energy physics theories. Comparison of quasar absorption line spectra with laboratory spectra provides a sensitive probe for variability of the fine structure constant, alpha, over cosmological time-scales. We have previously developed and applied a new method providing an order of magnitude gain in precision over previous optical astrophysical constraints. Here we extend that work by including new quasar spectra of damped Lyman-alpha absorption systems. We also re-analyse our previous lower redshift data and confirm our initial results. The constraints on alpha come from simultaneous fitting of absorption lines of subsets of the following species: Mg I, Mg II, Al II, Al III, Si II, Cr II, Fe II, Ni II and Zn II. We present a detailed description of our methods and results based on an analysis of 49 quasar absorption systems (towards 28 QSOs) covering the redshift range 0.5 < z < 3.5. There is...

  9. The coefficient of bond thermal expansion measured by extended x-ray absorption fine structure.

    Science.gov (United States)

    Fornasini, P; Grisenti, R

    2014-10-28

    The bond thermal expansion is in principle different from the lattice expansion and can be measured by correlation sensitive probes such as extended x-ray absorption fine structure (EXAFS) and diffuse scattering. The temperature dependence of the coefficient α(bond)(T) of bond thermal expansion has been obtained from EXAFS for CdTe and for Cu. A coefficient α(tens)(T) of negative expansion due to tension effects has been calculated from the comparison of bond and lattice expansions. Negative lattice expansion is present in temperature intervals where α(bond) prevails over α(tens); this real-space approach is complementary but not equivalent to the Grüneisen theory. The relevance of taking into account the asymmetry of the nearest-neighbours distribution of distances in order to get reliable bond expansion values and the physical meaning of the third cumulant are thoroughly discussed.

  10. Possible evidence for a variable fine structure constant from QSO absorption lines systematic errors

    CERN Document Server

    Murphy, M T; Flambaum, V V; Churchill, C W; Prochaska, J X

    2001-01-01

    Comparison of quasar absorption spectra with laboratory spectra allow us to probe possible variations in the fundamental constants over cosmological time-scales. In a companion paper we present an analysis of Keck/HIRES spectra and report possible evidence suggesting that the fine structure constant, alpha, may have been smaller in the past: da/a = (-0.72 +/- 0.18) * 10^{-5} over the redshift range 0.5 < z < 3.5. In this paper we describe a comprehensive investigation into possible systematic effects. Most of these do not significantly influence our results. When we correct for those which do produce a significant systematic effect in the data, the deviation of da/a from zero becomes more significant. We are lead increasingly to the interpretation that alpha was slightly smaller in the past.

  11. FDMX: extended X-ray absorption fine structure calculations using the finite difference method.

    Science.gov (United States)

    Bourke, Jay D; Chantler, Christopher T; Joly, Yves

    2016-03-01

    A new theoretical approach and computational package, FDMX, for general calculations of X-ray absorption fine structure (XAFS) over an extended energy range within a full-potential model is presented. The final-state photoelectron wavefunction is calculated over an energy-dependent spatial mesh, allowing for a complete representation of all scattering paths. The electronic potentials and corresponding wavefunctions are subject to constraints based on physicality and self-consistency, allowing for accurate absorption cross sections in the near-edge region, while higher-energy results are enabled by the implementation of effective Debye-Waller damping and new implementations of second-order lifetime broadening. These include inelastic photoelectron scattering and, for the first time, plasmon excitation coupling. This is the first full-potential package available that can calculate accurate XAFS spectra across a complete energy range within a single framework and without fitted parameters. Example spectra are provided for elemental Sn, rutile TiO2 and the FeO6 octahedron.

  12. Near-Edge X-ray Absorption Fine Structure Spectroscopy of Diamondoid Thiol Monolayers on Gold

    Energy Technology Data Exchange (ETDEWEB)

    Willey, T M; Fabbri, J; Lee, J I; Schreiner, P; Fokin, A A; Tkachenko, B A; Fokina, N A; Dahl, J; Carlson, B; Vance, A L; Yang, W; Terminello, L J; van Buuren, T; Melosh, N

    2007-11-27

    Diamondoids, hydrocarbon molecules with cubic-diamond-cage structures, have unique properties with potential value for nanotechnology. The availability and ability to selectively functionalize this special class of nanodiamond materials opens new possibilities for surface-modification, for high-efficiency field emitters in molecular electronics, as seed crystals for diamond growth, or as robust mechanical coatings. The properties of self-assembled monolayers (SAMs) of diamondoids are thus of fundamental interest for a variety of emerging applications. This paper presents the effects of thiol substitution position and polymantane order on diamondoid SAMs on gold using near-edge X-ray absorption fine structure spectroscopy (NEXAFS) and X-ray photoelectron spectroscopy (XPS). A framework to determine both molecular tilt and twist through NEXAFS is presented and reveals highly ordered diamondoid SAMs, with the molecular orientation controlled by the thiol location. C 1s and S 2p binding energies are lower in adamantane thiol than alkane thiols on gold by 0.67 {+-} 0.05 eV and 0.16 {+-} 0.04 eV respectively. These binding energies vary with diamondoid monolayer structure and thiol substitution position, consistent with different amounts of steric strain and electronic interaction with the substrate. This work demonstrates control over the assembly, in particular the orientational and electronic structure, providing a flexible design of surface properties with this exciting new class of diamond clusters.

  13. Molecular characterization of brominated persistent pollutants using extended X-ray absorption fine structure (EXAFS) spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Bergknut, Magnus; Skyllberg, Ulf [Swedish University of Agricultural Sciences (SLU), Department of Forest Ecology and Management, Umeaa (Sweden); Persson, Per [Umeaa University, Department of Chemistry, Umeaa (Sweden)

    2008-02-15

    X-ray absorption fine structure (EXAFS) spectroscopy spectra were collected for three brominated persistent pollutants: 6-bromo-2,4,5-trichlorophenol (BrTriClP), pentabromophenol (PentaBrP) and 3,3',5,5'-tetrabromobisphenol A (TBBA). The substances were selected to be symmetrical (BrTriClP and TBBA) or asymmetrical (PentaBrP) with respect to the atomic Br positions and to differ in the number of bromine and other halide atoms, as well as their relative positions. The asymmetrical PentaBrP was modelled with special detail as not all bromine atoms have identical coordination environments. The studied substances displayed unique EXAFS spectra, which could be used to determine the molecular structure in fair detail. We conclude that EXAFS spectroscopy is a suitable technique for molecular characterization of the comparatively complex molecules within the class of compounds of brominated organic persistent pollutants. A detailed understanding of the EXAFS spectra of the pure compounds opens up possibilities to study the interactions with soil and sediment matrices by means of EXAFS spectroscopy. (orig.)

  14. Sorption mechanisms of zinc to calcium silicate hydrate: X-ray absorption fine structure (XAFS) investigation.

    Science.gov (United States)

    Ziegler, F; Scheidegger, A M; Johnson, C A; Dähn, R; Wieland, E

    2001-04-01

    In this study, X-ray absorption fine structure (XAFS) spectroscopy has been used to further elucidate the binding mechanisms of Zn(II) to calcium silicate hydrate (C-S-H), the quantitatively most important cement mineral. Such knowledge is essential for the assessment of the longterm behavior of cement-stabilized waste materials. XAFS spectra of the Zn(II) equilibrated with C-S-H(I) for up to 28 days are best modeled by tetrahedral coordination of Zn(II) by four O atoms in the first atomic shell. Beyond the first coordination shell, data analysis of more highly concentrated samples suggests the presence of two distinct Zn distances and possibly the presence of an Si shell. On the basis of the comparison with a set of reference compounds, this coordination environment can be reasonably related to the structure of hemimorphite, a naturally occurring zinc silicate, and/or the presence of gamma-Zn(OH)2. At the lowest Zn uptake, the above fitting approach failed and data could be described best with a Zn-Si and a Zn-Ca shell. Previous work has been able to show that Zn(II) diffuses into the C-S-H(I) particles and does not form discrete precipitates, so the findings appear to confirm the incorporation of Zn(II) in the interlayer of C-S-H(I).

  15. Extended x-ray absorption fine structure investigation of annealed carbon expanded austenite

    DEFF Research Database (Denmark)

    Oddershede, Jette; Christiansen, Thomas L.; Somers, Marcel A. J.;

    2012-01-01

    Carbon expanded austenite synthesized through carburizing of austenitic stainless steel powder at 380°C was annealed at 470°C and investigated with extended X-ray absorption fine structure (EXAFS) and synchrotron powder diffraction (SPD). SPD showed that the samples consisted of carbon expanded...... austenite and Hägg carbide, Ξ-M5C2. EXAFS showed that the Cr atoms were mainly present in environments similar to the carbides Hägg Ξ-M5C2 and M23C6. The environments of the Fe and Ni atoms were concluded to be largely metallic austenite. Light optical micrograph of stainless steel AISI 316 gas......-carburized in a temperature regime around 470°C. The surface zone is converted into carbon expanded austenite; the high interstitial content of carbon dissolved in the surface results in highly favorable materials properties. In the present article the local atomic environment of (annealed) carbon expanded austenite...

  16. A surface extended X-ray absorption fine structure study of tellurium adsorbed onto Si(100)

    Science.gov (United States)

    Burgess, S. R.; Cowie, B. C. C.; Wilks, S. P.; Dunstan, P. R.; Dunscombe, C. J.; Williams, R. H.

    1996-09-01

    The adsorption of tellurium on Si(100) has been studied using surface extended X-ray adsorption fine structure (SEXAFS) and X-ray standing wave spectroscopy (XSW). This particular system is of interest due to its potential applicability in the surfactant aided growth of CdHgTeCdTeSi(100) based infra-red detectors. The Te/Si(100) structure was generated by depositing a thick layer (˜ 100 Å) of CdTe onto a clean Si (2 × 1) double domain surface, and annealing the sample to 350°C. This resulted is a ˜ 1 ML Te terminated surface where the (2 × 1) reconstruction was lost in favour of a (1 × 1) symmetry. X-ray absorption of the Te L 3 edge ( E = 4341 eV), with a photon energy range of 4440-4700 eV, was probed using a total yield detection scheme. The SEXAFS results indicated that the Te atoms sat in 2-fold bridge sites directly above a fourth layer Si atom. The corresponding bond length was measured to be 2.52 ± 0.05 Å. The XSW measurements of the (400) reflection gave a coherent position of 1.63 ± 0.03 Å and a coherent fraction of 0.65. This is consistent with the breaking of the SiSi dimers and thus could be an example of the phenomena of adsorbate-induced dereconstruction of the surface. These results are compared with those of Bennet et al. who examined a similar system using soft X-ray photoemission (SXPS) and the STM study of Yoshikawa et al.

  17. Determining Orientational Structure of Diamondoid Thiols Attached to Silver Using Near Edge X-ray Absorption Fine Structure Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Willey, T M; Lee, J I; Fabbri, J D; Wang, D; Nielsen, M; Randel, J C; Schreiner, P R; Fokin, A A; Tkachenko, B A; Fokina, N A; Dahl, J P; Carlson, R K; Terminello, L J; Melosh, N A; van Buuren, T

    2008-10-07

    Near-edge x-ray absorption fine structure spectroscopy (NEXAFS) is a powerful tool for determination of molecular orientation in self-assembled monolayers and other surface-attached molecules. A general framework for using NEXAFS to simultaneously determine molecular tilt and twist of rigid molecules attached to surfaces is presented. This framework is applied to self-assembled monolayers of higher diamondoid, hydrocarbon molecules with cubic-diamond-cage structures. Diamondoid monolayers chemisorbed on metal substrates are known to exhibit interesting electronic and surface properties. This work compares molecular orientation in monolayers prepared on silver substrates using two different thiol positional isomers of [121]tetramantane, and thiols derived from two different pentamantane structural isomers, [1212]pentamantane and [1(2,3)4]pentamantane. The observed differences in monolayer structure demonstrate the utility and limitations of NEXAFS spectroscopy and the framework. The results also demonstrate the ability to control diamondoid assembly, in particular the molecular orientational structure, providing a flexible platform for the modification of surface properties with this exciting new class of nanodiamond materials.

  18. Extended x-ray absorption fine structure studies of the atomic structure of nanoparticles in different metallic matrices.

    Science.gov (United States)

    Baker, S H; Roy, M; Gurman, S J; Binns, C

    2009-05-06

    It has been appreciated for some time that the novel properties of particles in the size range 1-10 nm are potentially exploitable in a range of applications. In order to ultimately produce commercial devices containing nanosized particles, it is necessary to develop controllable means of incorporating them into macroscopic samples. One way of doing this is to embed the nanoparticles in a matrix of a different material, by co-deposition for example, to form a nanocomposite film. The atomic structure of the embedded particles can be strongly influenced by the matrix. Since some of the key properties of materials, including magnetism, strongly depend on atomic structure, the ability to determine atomic structure in embedded nanoparticles is very important. This review focuses on nanoparticles, in particular magnetic nanoparticles, embedded in different metal matrices. Extended x-ray absorption fine structure (EXAFS) provides an excellent means of probing atomic structure in nanocomposite materials, and an overview of this technique is given. Its application in probing catalytic metal clusters is described briefly, before giving an account of the use of EXAFS in determining atomic structure in magnetic nanocomposite films. In particular, we focus on cluster-assembled films comprised of Fe and Co nanosized particles embedded in various metal matrices, and show how the crystal structure of the particles can be changed by appropriate choice of the matrix material. The work discussed here demonstrates that combining the results of structural and magnetic measurements, as well as theoretical calculations, can play a significant part in tailoring the properties of new magnetic cluster-assembled materials.

  19. Near Edge X-Ray Absorption Fine Structure Spectroscopy with X-Ray Free-Electron Lasers

    Energy Technology Data Exchange (ETDEWEB)

    Bernstein, D.P.; Acremann, Y.; Scherz, A.; Burkhardt, M.; Stohr, J.; /SLAC; Beye, M.; Schlotter, W.F.; Beeck, T.; Sorgenfrei, F.; Pietzsch, A.; Wurth, W.; Fohlisch, A.; /Hamburg U.

    2009-12-11

    We demonstrate the feasibility of Near Edge X-ray Absorption Fine Structure (NEXAFS) spectroscopy on solids by means of femtosecond soft x-ray pulses from a free-electron laser (FEL). Our experiments, carried out at the Free-Electron Laser at Hamburg (FLASH), used a special sample geometry, spectrographic energy dispersion, single shot position-sensitive detection and a data normalization procedure that eliminates the severe fluctuations of the incident intensity in space and photon energy. As an example we recorded the {sup 3}D{sub 1} N{sub 4,5}-edge absorption resonance of La{sup 3+}-ions in LaMnO{sub 3}. Our study opens the door for x-ray absorption measurements on future x-ray FEL facilities.

  20. X-ray absorption fine structure analysis of the local environment of zinc in dentine treated with zinc compounds.

    Science.gov (United States)

    Takatsuka, Tsutomu; Hirano, Junko; Matsumoto, Hitoshi; Honma, Tetsuo

    2005-04-01

    It has been reported that zinc oxide (ZnO) inhibits dentine demineralization. By using the X-ray absorption fine structure (XAFS) technique, our aims in this study were to provide information about the local environment of zinc atoms in dentine that had been treated with zinc compounds. We measured the Zn K-edge X-ray absorption near-edge structure (XANES) and the extended X-ray absorption fine structure (EXAFS) of dentine specimens treated with zinc chloride or ZnO. In XAFS analyses, the spectra of dentine specimens treated with ZnO (D-ZO) or with zinc chloride (D-ZC) were similar and obviously different from the reference ZnO spectrum. This suggests that most of the zinc atoms detected in D-ZO are not derived from particles of ZnO. The spectra of D-ZO and D-ZC were similar to the spectrum of the synthetic, zinc-containing hydroxyapatite, but were not similar to that of zinc in ZnCl2-treated collagen. The results of this study suggest that most of the zinc atoms detected were attached to hydroxyapatite and not to collagen.

  1. Photoluminescence and extended X-ray absorption fine structure studies on cadmium telluride material

    Science.gov (United States)

    Liu, Xiangxin

    The direct-band-gap semiconductor CdTe is an important material for fabricating high efficiency, polycrystalline thin-film solar cells in a heterojunction configuration. The outstanding physical properties of this material such as its good band-gap match to the solar spectrum, ease of fabrication of stoichiometric films, and easy grain boundary passivation make it an important candidate for large area, thin-film solar cells. However, there are several poorly understood processing steps that are commonly utilized in cell fabrication. One of these is a CdCl2 treatment near 400°C in the presence of oxygen, which can improve the cell efficiency a factor of two or more. Another factor is the role of copper in cell performance. In high performance CdS/CdTe thin-film solar cells, copper is usually included in the fabrication of low-resistance back contacts to obtain heavy p-type doping of the absorber CdTe at the contact. However, most of the copper is not electrically active. For example, secondary ion mass spectroscopy (SIMS) on typical CdTe cells has shown Cu concentrations of 1019 atoms/cm3 and even higher, although capacitance-voltage (C-V) measurements indicate typical ionized acceptor levels on the order of 1014/cm 3. Thus, there is great interest in the location and role of this inactive copper in CdTe photovoltaic (PV) devices. In this thesis, I will describe results obtained on magnetron-sputtered CdTe films that were diffused with copper following the procedure used for creating a cell back contact. Extended X-ray Absorption Fine Structure (EXAFS) measurements identified the chemical environment of the majority of the copper and show major differences depending on whether the CdTe film has been treated with chloride prior to the Cu diffusion. The EXAFS data indicate that the Cu chemistry is strongly affected by the chloride treatments---predominantly Cu2Te when Cu was diffused into the as-deposited CdTe film, but a Cu2O environment when Cu was diffused after

  2. Time-variability of the fine-structure constant expected from the Oklo constraint and the QSO absorption lines

    CERN Document Server

    Fujii, Y

    2003-01-01

    The data from the QSO absorption lines indicating a nonzero time-variability of the fine-structure constant has been re-analyzed on the basis of a "damped-oscillator" fit, as motivated by the same type of behavior of a scalar field, dilaton, which mimics a cosmological constant to understand the accelerating universe. We find nearly as good fit to the latest data as the simple weighted mean. In this way, we offer a way to fit the more stringent result from the Oklo phenomenon, as well.

  3. Time-variability of the fine-structure constant expected from the Oklo constraint and the QSO absorption lines

    Science.gov (United States)

    Fujii, Yasunori

    2003-10-01

    The data from the QSO absorption lines indicating a nonzero time-variability of the fine-structure constant has been re-analyzed on the basis of a ``damped-oscillator'' fit, as motivated by the same type of behavior of a scalar field, dilaton, which mimics a cosmological constant to understand the accelerating universe. We find nearly as good fit to the latest data as the simple weighted mean. In this way, we offer a way to fit the more stringent result from the Oklo phenomenon, as well.

  4. PREFACE: The 15th International Conference on X-ray Absorption Fine Structure (XAFS15)

    Science.gov (United States)

    Wu, Z. Y.

    2013-04-01

    The 15th International Conference on X-ray Absorption Fine Structure (XAFS15) was held on 22-28 July 2012 in Beijing, P. R. China. About 340 scientists from 34 countries attended this important international event. Main hall Figure 1. Main hall of XAFS15. The rapidly increasing application of XAFS to the study of a large variety of materials and the operation of the new SR source led to the first meeting of XAFS users in 1981 in England. Following that a further 14 International Conferences have been held. Comparing a breakdown of attendees according to their national origin, it is clear that participation is spreading to include attendees from more and more countries every year. The strategy of development in China of science and education is increasing quickly thanks to the large investment in scientific and technological research and infrastructure. There are three Synchrotron Radiation facilities in mainland China, Hefei Light Source (HLS) in the National Natural Science Foundation of China (NSRL), Beijing Synchrotron Radiation Facility (BSRF) in the Institute of High Energy Physics, and Shanghai Synchrotron Radiation Facility (SSRF) in the Shanghai Institute of Applied Physics. More than 10000 users and over 5000 proposals run at these facilities. Among them, many teams from the USA, Japan, German, Italy, Russia, and other countries. More than 3000 manuscript were published in SCI journals, including (incomplete) Science (7), Nature (10), Nature Series (7), PNAS (3), JACS (12), Angew. Chem. Int. Ed. (15), Nano Lett. (2), etc. In XAFS15, the participants contributed 18 plenary invited talks, 16 parallel invited talks, 136 oral presentations, 12 special talks, and 219 poster presentations. Wide communication was promoted in the conference halls, the classical banquet restaurant, and the Great Wall. Parallel hallCommunicationPoster room Figure 2. Parallel hallFigure 3. CommunicationFigure 4. Poster room This volume contains 136 invited and contributed papers

  5. Silver structure environments in ion-exchanged silicate glasses studied by X-ray absorption fine structure.

    Science.gov (United States)

    Yang, X C; Li, W J; Dubiel, M; Huang, W H; Yano, T

    2009-02-01

    X-ray absorption fine structure (XAFS) technique was used to analyze structural geometry of Ag atoms introduced into soda-lime silicate glass and soda aluminosilicate glass by ion-exchange method. The results show that Ag+ ion in soda aluminosilicate glass takes a coordination number of 1.6 with a Ag-O distance of 2.20 A when the ion-exchange ratio x is smaller than 0.47 and of 2.28 A when x is larger than 0.47. The introduced Ag+ ions are stabilized at the non-bridge oxygen (NBO) sites when x is lower than 0.47. The Na+ ions in AlO4 (O4 represents the bridging oxygen) sites are exchanged by Ag+ ions after all Na+ in NBO sites are replaced. The disorder of Ag-O coordination increases gradually with increasing x from 0.24 to 0.47 in soda aluminosilicate glass and increases dramatically when x is larger than 0.47. Ag+ ions takes a coordination number of 1.6 in the ion-exchanged soda-lime silicate glass and of 1.3 after subsequently thermal treatment with the same Ag-O distance of 2.14 A. Debye-Waller factor (DWF) of Ag-O coordination in soda aluminosilicate glass is higher than that in soda-lime silicate glass. Small Ag cluster has a reduced interatomic distance and a larger DWF. Ag nanoparticle in sample Ag-7 is in a state of tensile stress.

  6. Interpretation of the pre-edge X-ray absorption fine structures in MnO

    Institute of Scientific and Technical Information of China (English)

    LI Shu-Jun; HU Rong; HU Tian-Dou; XIE Ya-Ning; ZHANG Jing; TAO Ye; WU Zi-Yu

    2003-01-01

    The weak pre-edge features in the Mn K-edge X-ray absorption near-edge structure (XANES) spectrumof manganese monoxide (MnO) were investigated by comparing experimental data with dipolar and quadrupolarcross-section calculations in the framework of multiple-scattering theory. We assign the first pre-edge feature to a di-rect quadrupolar transition from Is core state to 3d molecular orbitals of the central atom, e.g., the lowest in energy,due to the more effective attraction of the core hole. The second peak in this region arises unambiguously from thehybridization between p-orbitals of the central atom with higher-shell metal octahedral orbitals.

  7. X-ray absorption fine structure spectroscopic determination of plutonium speciation at the Rocky Flats environmental technology

    Energy Technology Data Exchange (ETDEWEB)

    Lezama-pacheco, Juan S [Los Alamos National Laboratory; Conradson, Steven D [Los Alamos National Laboratory; Clark, David L [Los Alamos National Laboratory

    2008-01-01

    X-ray Absorption Fine Structure spectroscopy was used to probe the speciation of the ppm level Pu in thirteen soil and concrete samples from the Rocky Flats Environmental Technology Site in support of the site remediation effort that has been successfully completed since these measurements. In addition to X-ray Absorption Near Edge Spectra, two of the samples yielded Extended X-ray Absorption Fine Structure spectra that could be analyzed by curve-fits. Most of these spectra exhibited features consistent with PU(IV), and more specificaJly, PuO{sub 2+x}-type speciation. Two were ambiguous, possibly indicating that Pu that was originally present in a different form was transforming into PuO{sub 2+x}, and one was interpreted as demonstrating the presence of an unusual Pu(VI) compound, consistent with its source being spills from a PUREX purification line onto a concrete floor and the resultant extreme conditions. These experimental results therefore validated models that predicted that insoluble PuO{sub 2+x} would be the most stable form of Pu in equilibrium with air and water even when the source terms were most likely Pu metal with organic compounds or a Pu fire. A corollary of these models' predictions and other in situ observations is therefore that the minimal transport of Pu that occurred on the site was via the resuspension and mobilization of colloidal particles. Under these conditions, the small amounts of diffusely distributed Pu that were left on the site after its remediation pose only a negligible hazard.

  8. Quick extended x-ray absorption fine structure instrument with millisecond time scale, optimized for in situ applications.

    Science.gov (United States)

    Khalid, S; Caliebe, W; Siddons, P; So, I; Clay, B; Lenhard, T; Hanson, J; Wang, Q; Frenkel, A I; Marinkovic, N; Hould, N; Ginder-Vogel, M; Landrot, G L; Sparks, D L; Ganjoo, A

    2010-01-01

    In order to learn about in situ structural changes in materials at subseconds time scale, we have further refined the techniques of quick extended x-ray absorption fine structure (QEXAFS) and quick x-ray absorption near edge structure (XANES) spectroscopies at beamline X18B at the National Synchrotron Light Source. The channel cut Si (111) monochromator oscillation is driven through a tangential arm at 5 Hz, using a cam, dc motor, pulley, and belt system. The rubber belt between the motor and the cam damps the mechanical noise. EXAFS scan taken in 100 ms is comparable to standard data. The angle and the angular range of the monochromator can be changed to collect a full EXAFS or XANES spectrum in the energy range 4.7-40.0 KeV. The data are recorded in ascending and descending order of energy, on the fly, without any loss of beam time. The QEXAFS mechanical system is outside the vacuum system, and therefore changing the mode of operation from conventional to QEXAFS takes only a few minutes. This instrument allows the acquisition of time resolved data in a variety of systems relevant to electrochemical, photochemical, catalytic, materials, and environmental sciences.

  9. Extended x-ray absorption fine structure spectroscopy in Co{sub 0.013}NbSe{sub 2}.

    Energy Technology Data Exchange (ETDEWEB)

    Weber, F.; Castellan, J.-P.; Rosenkranz, S.; Osborn, R.; Rosenmann, D.; Iavarone, M.; Materials Science Division

    2010-01-01

    We present a study of the local environment of the Co atom in single crystalline Co{sub x}NbSe{sub 2}, x = 0.013, via Extended X-ray Absorption Fine Structure (EXAFS) measurements at the Co K-edge (7.7 keV) at various temperatures. Co intercalation quickly suppresses superconductivity and the charge-density wave (CDW) present in pure NbSe{sub 2}. In order to study the effect of impurities on superconducting and CDW states one has to verify the random distribution of the intercalated atoms in contrast to possible clustering which could lead to additional, e.g. magnetic, interactions in the case of Co intercalation. Our measurements show that the Co atoms are indeed randomly distributed in Co{sub 0.013}NbSe{sub 2}.

  10. Extended X-ray Absorption Fine Structure spectroscopy in Co{sub 0.013}NbSe{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Weber, F; Castellan, J-P; Rosenkranz, S; Osborn, R; Rosenmann, D; Iavarone, M, E-mail: fweber@anl.go [Materials Science Division, Argonne National Laboratory, Argonne, Illinois (United States)

    2010-01-15

    We present a study of the local environment of the Co atom in single crystalline Co{sub x}NbSe{sub 2}, x = 0.013, via Extended X-ray Absorption Fine Structure (EXAFS) measurements at the Co K-edge (7.7 keV) at various temperatures. Co intercalation quickly suppresses superconductivity and the charge-density wave (CDW) present in pure NbSe{sub 2}. In order to study the effect of impurities on superconducting and CDW states one has to verify the random distribution of the intercalated atoms in contrast to possible clustering which could lead to additional, e.g. magnetic, interactions in the case of Co intercalation. Our measurements show that the Co atoms are indeed randomly distributed in Co{sub 0.013}NbSe{sub 2}.

  11. Zinc cysteine active sites of metalloproteins: a density functional theory and x-ray absorption fine structure study.

    Science.gov (United States)

    Dimakis, Nicholas; Farooqi, Mohammed Junaid; Garza, Emily Sofia; Bunker, Grant

    2008-03-21

    Density functional theory (DFT) and x-ray absorption fine structure (XAFS) spectroscopy are complementary tools for the biophysical study of active sites in metalloproteins. DFT is used to compute XAFS multiple scattering Debye Waller factors, which are then employed in genetic algorithm-based fitting process to obtain a global fit to the XAFS in the space of fitting parameters. Zn-Cys sites, which serve important functions as transcriptional switches in Zn finger proteins and matrix metalloproteinases, previously have proven intractable by this method; here these limitations are removed. In this work we evaluate optimal DFT nonlocal functionals and basis sets for determining optimal geometries and vibrational densities of states of mixed ligation Zn(His)(4-n)(Cys)(n) sites. Theoretical results are compared to experimental XAFS measurements and Raman spectra from the literature and tabulated for use.

  12. Zinc cysteine active sites of metalloproteins: A density functional theory and x-ray absorption fine structure study

    Science.gov (United States)

    Dimakis, Nicholas; Farooqi, Mohammed Junaid; Garza, Emily Sofia; Bunker, Grant

    2008-03-01

    Density functional theory (DFT) and x-ray absorption fine structure (XAFS) spectroscopy are complementary tools for the biophysical study of active sites in metalloproteins. DFT is used to compute XAFS multiple scattering Debye Waller factors, which are then employed in genetic algorithm-based fitting process to obtain a global fit to the XAFS in the space of fitting parameters. Zn-Cys sites, which serve important functions as transcriptional switches in Zn finger proteins and matrix metalloproteinases, previously have proven intractable by this method; here these limitations are removed. In this work we evaluate optimal DFT nonlocal functionals and basis sets for determining optimal geometries and vibrational densities of states of mixed ligation Zn(His)4-n(Cys)n sites. Theoretical results are compared to experimental XAFS measurements and Raman spectra from the literature and tabulated for use.

  13. Near-edge X-ray absorption fine structure spectroscopy-assisted purification of single-walled carbon nanotubes

    Energy Technology Data Exchange (ETDEWEB)

    Yan Dongwei [Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080 (China); Zhong Jun [Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Wang Chunru [Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080 (China)], E-mail: crwang@iccas.ac.cn; Wu Ziyu [Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)], E-mail: wuzy@ihep.ac.cn

    2007-07-15

    Single-walled carbon nanotubes were produced by the conventional arc discharge method, and purified with a two-step treatment. First, the raw soot containing single-walled carbon nanotubes was burned up at ca. 350 deg. C in air to remove amorphous carbon, and then it was treated by strong acidic solvents to remove metal catalysts. Near-edge X-ray absorption fine structure spectroscopy was applied to analyze the defects on single-walled carbon nanotubes in whole purification process, so the experimental conditions can be optimized, and finally high-purity single-walled carbon nanotubes were obtained as revealed by various spectroscopic characterizations such as scanning electron microscopy, transmission electron microscopy, thermogravimetric analysis, and Raman spectroscopy.

  14. Artificial intelligence applied to the automatic analysis of absorption spectra. Objective measurement of the fine structure constant

    CERN Document Server

    Bainbridge, Matthew B

    2016-01-01

    A new and fully-automated method is presented for the analysis of high-resolution absorption spectra (GVPFIT). The method has broad application but here we apply it specifically to the problem of measuring the fine structure constant at high redshift. For this we need objectivity and reproducibility. GVPFIT is also motivated by the importance of obtaining a large statistical sample of measurements of $\\Delta\\alpha/\\alpha$. Interactive analyses are both time consuming and complex and automation makes obtaining a large sample feasible. Three numerical methods are unified into one artificial intelligence process: a genetic algorithm that emulates the Darwinian processes of reproduction, mutation and selection, non-linear least-squares with parameter constraints (VPFIT), and Bayesian model averaging. In contrast to previous methodologies, which relied on a particular solution as being the most likely model, GVPFIT plus Bayesian model averaging derives results from a large set of models, and helps overcome systema...

  15. X-ray absorption fine structure and X-ray excited optical luminescence studies of II-VI semiconducting nanostructures

    Science.gov (United States)

    Murphy, Michael Wayne

    2010-06-01

    Various II-VI semiconducting nanomaterials such as ZnO-ZnS nanoribbons (NRs), CdSxSe1-x nanostructures, ZnS:Mn NRs, ZnS:Mn,Eu nanoprsims (NPs), ZnO:Mn nanopowders, and ZnO:Co nanopowders were synthesized for study. These materials were characterized by techniques such as scanning electron microscopy, transmission electron microscopy, element dispersive X-ray spectroscopy, selected area electron diffraction, and X-ray diffraction. The electronic and optical properties of these nanomaterials were studied by X-ray absorption fine structure (XAFS) spectroscopy and X-ray excited optical luminescence (XEOL) techniques, using tuneable soft X-rays from a synchrotron light source. The complementary nature ofthe XAFS and XEOL techniques give site, element and chemical specific measurements which allow a better understanding of the interplay and role of each element in the system. Chemical vapour deposition (CVD) of ZnS powder in a limited oxygen environment resulted in side-by-side biaxial ZnO-ZnS NR heterostructures. The resulting NRs contained distinct wurtzite ZnS and wurtzite ZnO components with widths of 10--100 nm and 20 --500 nm, respectively and a uniform interface region of 5-15 nm. XAFS and XEOL measurements revealed the luminescence of ZnO-ZnS NRs is from the ZnO component. The luminescence of CdSxSe1-x nanostructures is shown to be dependent on the S to Se ratio, with the band-gap emission being tunable between that of pure CdS and CdSe. Excitation of the CdSxSe 1-x nanostructures by X-ray in XEOL has revealed new de-excitation channels which show a defect emission band not seen by laser excitation. CVD of Mn2+ doped ZnS results in nanostructures with luminescence dominated by the yellow Mn2+ emission due to energy transfer from the ZnS host to the Mn dopant sites. The addition of EuCl3 to the reactants in the CVD process results in a change in morphology from NR to NP. Zn1-xMnxO and Zn1-xCOxO nanopowders were prepared by sol-gel methods at dopant concentrations

  16. Precise limits on cosmological variability of the fine-structure constant with zinc and chromium quasar absorption lines

    CERN Document Server

    Murphy, Michael T; Prochaska, J Xavier

    2016-01-01

    The strongest transitions of Zn and CrII are the most sensitive to relative variations in the fine-structure constant ($\\Delta\\alpha/\\alpha$) among the transitions commonly observed in quasar absorption spectra. They also lie within just 40 \\AA\\ of each other (rest frame), so they are resistant to the main systematic error affecting most previous measurements of $\\Delta\\alpha/\\alpha$: long-range distortions of the wavelength calibration. While Zn and CrII absorption is normally very weak in quasar spectra, we obtained high signal-to-noise, high-resolution echelle spectra from the Keck and Very Large Telescopes of 9 rare systems where it is strong enough to constrain $\\Delta\\alpha/\\alpha$ from these species alone. These provide 12 independent measurements (3 quasars were observed with both telescopes) at redshifts 1.0--2.4, 11 of which pass stringent reliability criteria. These 11 are all consistent with $\\Delta\\alpha/\\alpha=0$ within their individual uncertainties of 3.5--13 parts per million (ppm), with a we...

  17. High-precision limit on variation in the fine-structure constant from a single quasar absorption system

    CERN Document Server

    Kotuš, Srđan M; Carswell, Robert F

    2016-01-01

    The brightest southern quasar above redshift $z=1$, HE 0515$-$4414, with its strong intervening metal absorption-line system at $z_{abs}=1.1508$, provides a unique opportunity to precisely measure or limit relative variations in the fine-structure constant ($\\Delta\\alpha/\\alpha$). A variation of just $\\sim$3 parts per million (ppm) would produce detectable velocity shifts between its many strong metal transitions. Using new and archival observations from the Ultraviolet and Visual Echelle Spectrograph (UVES) we obtain an extremely high signal-to-noise ratio spectrum (peaking at S/N $\\approx250$ pix$^{-1}$). This provides the most precise measurement of $\\Delta\\alpha/\\alpha$ from a single absorption system to date, $\\Delta\\alpha/\\alpha=-1.42\\pm0.55_{\\rm stat}\\pm0.65_{\\rm sys}$ ppm, comparable with the precision from previous, large samples of $\\sim$150 absorbers. The largest systematic error in all (but one) previous similar measurements, including the large samples, was long-range distortions in the wavelengt...

  18. Near-edge x-ray absorption fine structure measurements using a laboratory-scale XUV source

    Science.gov (United States)

    Peth, Christian; Barkusky, Frank; Mann, Klaus

    2008-05-01

    We present a compact setup for near-edge x-ray absorption spectroscopy at the carbon K-edge based on a laser-driven plasma source. To generate the required broad-band emission in the spectral range of the 'water window' (λ = 2.2-4.4 nm) a krypton gas puff target was used. The table-top setup consisting basically of the laser-plasma source and a flat-field spectrometer can be used for near-edge x-ray absorption fine structure experiments in transmission as well as reflection under grazing incidence conditions (ReflEXAFS). The latter method offers the advantage that thin film preparation is not necessary and that the surface sensitivity is strongly enhanced. The results obtained for thin polymer films show good agreement with synchrotron data. Furthermore, we use the ReflEXAFS method to investigate changes in the chemical composition of PMMA induced by extreme ultraviolet (EUV) radiation. The spectra indicate a loss of the carbonyl functional group upon irradiation as well as crosslinking effects at high EUV radiation doses.

  19. Sulfur X-ray absorption fine structure in porous Li–S cathode films measured under argon atmospheric conditions

    Energy Technology Data Exchange (ETDEWEB)

    Müller, Matthias, E-mail: matthias.mueller@ptb.de [Physikalisch-Technische Bundesanstalt, Abbestr. 2-12, 10587 Berlin (Germany); Choudhury, Soumyadip [Leibniz-Institut für Polymerforschung, Hohe Strasse 6, 01069 Dresden (Germany); Technische Universität Dresden, Physical Chemistry of Polymeric Materials ,01062 Dresden (Germany); Gruber, Katharina [VARTA Micro Innovation GmbH, Stremayrgasse 9, 8010 Graz (Austria); Cruz, Valene B. [Universität Ulm, Institut für Elektrochemie, 89069 Ulm (Germany); Helmholtz-Institut Ulm (HIU), 89069 Ulm (Germany); Fuchsbichler, Bernd [VARTA Micro Innovation GmbH, Stremayrgasse 9, 8010 Graz (Austria); Jacob, Timo [Universität Ulm, Institut für Elektrochemie, 89069 Ulm (Germany); Helmholtz-Institut Ulm (HIU), 89069 Ulm (Germany); Koller, Stefan [VARTA Micro Innovation GmbH, Stremayrgasse 9, 8010 Graz (Austria); Stamm, Manfred [Leibniz-Institut für Polymerforschung, Hohe Strasse 6, 01069 Dresden (Germany); Technische Universität Dresden, Physical Chemistry of Polymeric Materials ,01062 Dresden (Germany); Ionov, Leonid [Leibniz-Institut für Polymerforschung, Hohe Strasse 6, 01069 Dresden (Germany); Beckhoff, Burkhard [Physikalisch-Technische Bundesanstalt, Abbestr. 2-12, 10587 Berlin (Germany)

    2014-04-01

    In this paper we present the first results for the characterization of highly porous cathode materials with pore sizes below 1 μm for Lithium Sulfur (Li–S) batteries by Near Edge X-ray Absorption Fine Structure (NEXAFS) spectroscopy. A novel cathode material of porous carbon films fabricated with colloidal array templates has been investigated. In addition, an electrochemical characterization has been performed aiming on an improved correlation of physical and chemical parameters with the electrochemical performance. The performed NEXAFS measurements of cathode materials allowed for a chemical speciation of the sulfur content inside the cathode material. The aim of the presented investigation was to evaluate the potential of the NEXAFS technique to characterize sulfur in novel battery material. The long term goal for the characterization of the battery materials is the sensitive identification of undesired side reactions, such as the polysulfide shuttle, which takes place during charging and discharging of the battery. The main drawback associated with the investigation of these materials is the fact that NEXAFS measurements can usually only be performed ex situ due to the limited in situ instrumentation being available. For Li–S batteries this problem is more pronounced because of the low photon energies needed to study the sulfur K absorption edge at 2472 eV. We employed 1 μm thick Si{sub 3}N{sub 4} windows to construct sealed argon cells for NEXAFS measurements under ultra high vacuum (UHV) conditions as a first step towards in situ measurements. The cells keep the sample under argon atmosphere at any time and the X-ray beam passes mainly through vacuum which enables the detection of the low energy X-ray emission of sulfur. Using these argon cells we found indications for the presence of lithium polysulfides in the cathode films whereas the correlations to the offline electrochemical results remain somewhat ambiguous. As a consequence of these findings one

  20. Non-patchy strategy for inter-atomic distances from Extended X-ray Absorption Fine Structure

    Science.gov (United States)

    Xu, Gu; Li, Guifang; LI, Xianya; Liang, Yi; Feng, Zhechuan

    2017-01-01

    Extended X-ray Absorption Fine Structure (EXAFS) has been one of the few structural probes available for crystalline, non-crystalline and even highly disordered specimens. However, the data analysis involves a patchy and tinkering process, including back-and-forth fitting and filtering, leading to ambiguous answers sometimes. Here we try to resolve this long standing problem, to extract the inter-atomic distances from the experimental data by a single step minimization, in order to replace the tedious and tinkering process. The new strategy is built firmly by the mathematical logic, and made straightforward and undeniable. The finding demonstrates that it is possible to break off from the traditional patchy model fitting, and to remove the logical confusion of a priori prediction of the structure to be matched with experimental data, making it a much more powerful technique than the existing methods. The new method is expected to benefit EXAFS users covering all disciplines. Also, it is anticipated that the current work to be the motivation and inspiration to the further efforts. PMID:28181529

  1. Non-patchy strategy for inter-atomic distances from Extended X-ray Absorption Fine Structure

    Science.gov (United States)

    Xu, Gu; Li, Guifang; Li, Xianya; Liang, Yi; Feng, Zhechuan

    2017-02-01

    Extended X-ray Absorption Fine Structure (EXAFS) has been one of the few structural probes available for crystalline, non-crystalline and even highly disordered specimens. However, the data analysis involves a patchy and tinkering process, including back-and-forth fitting and filtering, leading to ambiguous answers sometimes. Here we try to resolve this long standing problem, to extract the inter-atomic distances from the experimental data by a single step minimization, in order to replace the tedious and tinkering process. The new strategy is built firmly by the mathematical logic, and made straightforward and undeniable. The finding demonstrates that it is possible to break off from the traditional patchy model fitting, and to remove the logical confusion of a priori prediction of the structure to be matched with experimental data, making it a much more powerful technique than the existing methods. The new method is expected to benefit EXAFS users covering all disciplines. Also, it is anticipated that the current work to be the motivation and inspiration to the further efforts.

  2. Near-edge X-ray absorption fine-structure spectroscopy of naphthalene diimide-thiophene co-polymers

    Energy Technology Data Exchange (ETDEWEB)

    Gann, Eliot; McNeill, Christopher R., E-mail: christopher.mcneill@monash.edu [Department of Materials Engineering, Monash University, Wellington Road, Clayton, Victoria 3800 (Australia); Szumilo, Monika; Sirringhaus, Henning [Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE (United Kingdom); Sommer, Michael [Institute of Macromolecular Chemistry, University of Freiburg, Stefan-Meier-Str. 31, 79104 Freiburg (Germany); Maniam, Subashani; Langford, Steven J. [School of Chemistry, Monash University, Wellington Road, Clayton, Victoria 3800 (Australia); Thomsen, Lars [Australian Synchrotron, 800 Blackburn Road, Clayton, Victoria 3168 (Australia)

    2014-04-28

    Near-edge X-ray absorption fine-structure (NEXAFS) spectroscopy is an important tool for probing the structure of conjugated polymer films used in organic electronic devices. High-performance conjugated polymers are often donor-acceptor co-polymers which feature a repeat unit with multiple functional groups. To facilitate better application of NEXAFS spectroscopy to the study of such materials, improved understanding of the observed NEXAFS spectral features is required. In order to examine how the NEXAFS spectrum of a donor-acceptor co-polymer relates to the properties of the sub-units, a series of naphthalene diimide-thiophene-based co-polymers have been studied where the nature and length of the donor co-monomer has been systematically varied. The spectra of these materials are compared with that of a thiophene homopolymer and naphthalene diimide monomer enabling peak assignment and the influence of inter-unit electronic coupling to be assessed. We find that while it is possible to attribute peaks within the π* manifold as arising primarily due to the naphthalene diimide or thiophene sub-units, very similar dichroism of these peaks is observed indicating that it may not be possible to separately probe the molecular orientation of the separate sub-units with carbon K-edge NEXAFS spectroscopy.

  3. The structure of liquid semiconductors, superionic conductors and glasses by neutron scattering, X-ray diffraction and extended X-ray absorption fine structure

    CERN Document Server

    Buchanan, P

    2001-01-01

    NDIS technique alone. The structure of liquid FeTe sub 2 was determined at the total structure factor level using neutron diffraction in order to estimate the effect of chalcogenide ion size on the structure. The results demonstrate the feasibility of the additional structural determination techniques for disordered materials made possible through the development of third generation X-ray synchrotron sources. A study of the applicability of modern X-ray and neutron scattering techniques to the study of the structure of liquid semiconductors and glasses has been made. The results demonstrate how neutron scattering with isotopic substitution (NDIS), anomalous X-ray scattering and Extended X-ray Absorption Fine Structure (EXAFS) can be successfully used to elucidate the structure of materials that cannot be studied by NDIS alone. The local coordination structure of Ag sub 2 Se in its room temperature, superionic and liquid phases has been determined using the EXAFS technique. This EXAFS data have been combined w...

  4. Precise limits on cosmological variability of the fine-structure constant with zinc and chromium quasar absorption lines

    Science.gov (United States)

    Murphy, Michael T.; Malec, Adrian L.; Prochaska, J. Xavier

    2016-09-01

    The strongest transitions of Zn and Cr II are the most sensitive to relative variations in the fine-structure constant (Δα/α) among the transitions commonly observed in quasar absorption spectra. They also lie within just 40 Å of each other (rest frame), so they are resistant to the main systematic error affecting most previous measurements of Δα/α: long-range distortions of the wavelength calibration. While Zn and Cr II absorption is normally very weak in quasar spectra, we obtained high signal-to-noise, high-resolution echelle spectra from the Keck and Very Large Telescopes of nine rare systems where it is strong enough to constrain Δα/α from these species alone. These provide 12 independent measurements (three quasars were observed with both telescopes) at redshifts 1.0-2.4, 11 of which pass stringent reliability criteria. These 11 are all consistent with Δα/α = 0 within their individual uncertainties of 3.5-13 parts per million (ppm), with a weighted mean Δα/α = 0.4 ± 1.4stat ± 0.9sys ppm (1σ statistical and systematic uncertainties), indicating no significant cosmological variations in α. This is the first statistical sample of absorbers that is resistant to long-range calibration distortions (at the <1 ppm level), with a precision comparable to previous large samples of ˜150 (distortion-affected) absorbers. Our systematic error budget is instead dominated by much shorter range distortions repeated across echelle orders of individual spectra.

  5. High-precision limit on variation in the fine-structure constant from a single quasar absorption system

    Science.gov (United States)

    Kotuš, S. M.; Murphy, M. T.; Carswell, R. F.

    2017-01-01

    The brightest southern quasar above redshift z = 1, HE 0515-4414, with its strong intervening metal absorption line system at zabs = 1.1508, provides a unique opportunity to precisely measure or limit relative variations in the fine-structure constant (Δα/α). A variation of just ˜3 parts per million (ppm) would produce detectable velocity shifts between its many strong metal transitions. Using new and archival observations from the Ultraviolet and Visual Echelle Spectrograph (UVES), we obtain an extremely high signal-to-noise ratio spectrum (peaking at S/N ≈ 250 pix-1). This provides the most precise measurement of Δα/α from a single absorption system to date, Δα/α = -1.42 ± 0.55stat ± 0.65sys ppm, comparable with the precision from previous, large samples of ˜150 absorbers. The largest systematic error in all (but one) previous similar measurements, including the large samples, was long-range distortions in the wavelength calibration. These would add an ˜2 ppm systematic error to our measurement and up to ˜10 ppm to other measurements using Mg and Fe transitions. However, we corrected the UVES spectra using well-calibrated spectra of the same quasar from the High Accuracy Radial velocity Planet Searcher, leaving a residual 0.59 ppm systematic uncertainty, the largest contribution to our total systematic error. A similar approach, using short observations on future well-calibrated spectrographs to correct existing high S/N spectra, would efficiently enable a large sample of reliable Δα/α measurements. The high-S/N UVES spectrum also provides insights into analysis difficulties, detector artefacts and systematic errors likely to arise from 25-40-m telescopes.

  6. The forms of trace metals in an Illinois basin coal by x-ray absorption fine structure spectroscopy

    Science.gov (United States)

    Chou, I.-Ming; Bruinius, J.A.; Lytle, J.M.; Ruch, R.R.; Huggins, Frank E.; Huffman, G.P.; Ho, K.K.

    1997-01-01

    Utilities burning Illinois coals currently do not consider trace elements in their flue gas emissions. After the US EPA completes an investigation on trace elements, however, this may change and flue gas emission standards may be established. The mode of occurrence of a trace element may determine its cleanability and Hue gas emission potential. X-ray Absorption Fine Structure (XAFS) is a spectroscopic technique that can differentiate the mode of occurrence of an element, even at the low concentrations that trace elements are found in coal. This is principally accomplished by comparing the XAFS spectra of a coal to a database of reference sample spectra. This study evaluated the technique as a potential tool to examine six trace elements in an Illinois #6 coal. For the elements As and Zn, the present database provides a definitive interpretation on their mode of occurrence. For the elements Ti, V, Cr, and Mn the database of XAFS spectra of trace elements in coal was still too limited to allow a definitive interpretation. The data obtained on these elements, however, was sufficient to rule out several of the mineralogical possibilities that have been suggested previously. The results indicate that XAFS is a promising technique for the study of trace elements in coal.

  7. Fine structure of the CCl3 UV absorption spectrum and CCl3 kinetics

    DEFF Research Database (Denmark)

    Ellermann, T.

    1992-01-01

    The UV gas-phase spectrum of CCl3 was recorded in the range 220-300 nm using pulse radiolysis of CHCl3/SF6 or CCl4/Ar gas mixtures. The UV spectrum exhibits a pronounced vibrational fine structure which is assigned to transition into the (C2A1'(3s)) Rydberg state. The vibronic progression has...... a band origin around 250 nm and the spacing of 569 +/- 63 cm-1 is ascribed to excitation of the out-of-plane bending mode. The absorption cross section with a maximum of sigma = (1.02 +/- 0.16) x 10(-17) cm2 molecule-1 at 224.80 +/- 0.16 nm was determined relative to sigma(CH3) and sigma(CH3O2). The rate...... constants for CCl3 + CCl3 + M --> C2Cl6 + M and CCl3 + Cl + M --> CCl4 + M are (5.9 +/- 1.3) x 10(-12) and (6.5 +/- 1.4) x 10(-11) cm3 molecule-1 s-1, respectively, at 298 +/- 2 K and 1 atm total pressure....

  8. Pressure-Dependent Anharmonic Correlated Einstein Model Extended X-ray Absorption Fine Structure Debye-Waller Factors

    Science.gov (United States)

    Van Hung, Nguyen

    2014-02-01

    A pressure-dependent anharmonic correlated Einstein model is derived for extended X-ray absorption fine structure (EXAFS) Debye-Waller factors (DWFs), which are presented in terms of cumulant expansion up to the third order. The model is based on quantum thermodynamic perturbation theory and includes anharmonic effects based on empirical potentials. Explicit analytical expressions of the pressure-dependent changes in the interatomic distance, anharmonic effective potential, thermodynamic parameters, first, second, and third EXAFS cumulants, and thermal expansion coefficient have been derived. This model avoids the use of extensive full lattice dynamical calculations, yet provides good and reasonable agreement of numerical results for Cu with experimental results of X-ray diffraction (XRD) analysis and pressure-dependent EXAFS. Significant pressure effects are shown by the decrease in the pressure-induced changes in the interatomic distance, EXAFS cumulants and thermal expansion coefficient, as well as by the increase in the pressure-induced changes in the interatomic effective potential, effective spring constant, correlated Einstein frequency, and temperature.

  9. In situ X-ray absorption fine structure studies on the structure of nickel phosphide catalyst supported on K-USY

    CERN Document Server

    Kawai, T; Suzuki, S

    2003-01-01

    Local structure around Ni in a nickel phosphide catalyst supported on K-USY was investigated by an situ X-ray absorption fine structure (XAFS) method during the reduction process of the catalyst and the hydrodesulfurization (HDS) reaction of thiophene. In the passivated sample, Ni phosphide was partially oxidized but after the reduction, 1.1 nm diameter Ni sub 2 P particles were formed with Ni-P and Ni-Ni distances at 0.218 and 0.261 nm, respectively, corresponding to those of bulk Ni sub 2 P. In situ XAFS cleary revealed that the Ni sub 2 P structure was stable under reaction conditions and was an active structure for the HDS process.

  10. Artificial intelligence applied to the automatic analysis of absorption spectra. Objective measurement of the fine structure constant

    Science.gov (United States)

    Bainbridge, Matthew B.; Webb, John K.

    2017-01-01

    A new and automated method is presented for the analysis of high-resolution absorption spectra. Three established numerical methods are unified into one `artificial intelligence' process: a genetic algorithm (Genetic Voigt Profile FIT, gvpfit); non-linear least-squares with parameter constraints (vpfit); and Bayesian model averaging (BMA). The method has broad application but here we apply it specifically to the problem of measuring the fine structure constant at high redshift. For this we need objectivity and reproducibility. gvpfit is also motivated by the importance of obtaining a large statistical sample of measurements of Δα/α. Interactive analyses are both time consuming and complex and automation makes obtaining a large sample feasible. In contrast to previous methodologies, we use BMA to derive results using a large set of models and show that this procedure is more robust than a human picking a single preferred model since BMA avoids the systematic uncertainties associated with model choice. Numerical simulations provide stringent tests of the whole process and we show using both real and simulated spectra that the unified automated fitting procedure out-performs a human interactive analysis. The method should be invaluable in the context of future instrumentation like ESPRESSO on the VLT and indeed future ELTs. We apply the method to the zabs = 1.8389 absorber towards the zem = 2.145 quasar J110325-264515. The derived constraint of Δα/α = 3.3 ± 2.9 × 10-6 is consistent with no variation and also consistent with the tentative spatial variation reported in Webb et al. and King et al.

  11. Artificial intelligence applied to the automatic analysis of absorption spectra. Objective measurement of the fine structure constant.

    Science.gov (United States)

    Bainbridge, Matthew B.; Webb, John K.

    2017-01-01

    A new and automated method is presented for the analysis of high-resolution absorption spectra. Three established numerical methods are unified into one "artificial intelligence" process: a genetic algorithm (GVPFIT); non-linear least-squares with parameter constraints (VPFIT); and Bayesian Model Averaging (BMA). The method has broad application but here we apply it specifically to the problem of measuring the fine structure constant at high redshift. For this we need objectivity and reproducibility. GVPFIT is also motivated by the importance of obtaining a large statistical sample of measurements of Δα/α. Interactive analyses are both time consuming and complex and automation makes obtaining a large sample feasible. In contrast to previous methodologies, we use BMA to derive results using a large set of models and show that this procedure is more robust than a human picking a single preferred model since BMA avoids the systematic uncertainties associated with model choice. Numerical simulations provide stringent tests of the whole process and we show using both real and simulated spectra that the unified automated fitting procedure out-performs a human interactive analysis. The method should be invaluable in the context of future instrumentation like ESPRESSO on the VLT and indeed future ELTs. We apply the method to the zabs = 1.8389 absorber towards the zem = 2.145 quasar J110325-264515. The derived constraint of Δα/α = 3.3 ± 2.9 × 10-6 is consistent with no variation and also consistent with the tentative spatial variation reported in Webb et al. (2011) and King et al. (2012).

  12. Applications of x ray absorption fine structure to the in situ study of the effect of cobalt in nickel hydrous oxide electrodes for fuel cells and rechargeable batteries

    Science.gov (United States)

    Kim, Sunghyun; Tryk, Donald A.; Scherson, Daniel A.; Antonio, Mark R.

    1993-01-01

    Electronic and structural aspects of composite nickel-cobalt hydrous oxides have been examined in alkaline solutions using in situ X-ray absorption fine structure (XAFS). The results obtained have indicated that cobalt in this material is present as cobaltic ions regardless of the oxidation state of nickel in the lattice. Furthermore, careful analysis of the Co K-edge Extended X-ray absorption fine structure data reveals that the co-electrodeposition procedure generates a single phase, mixed metal hydrous oxide, in which cobaltic ions occupy nickel sites in the NiO2 sheet-like layers and not two intermixed phases each consisting of a single metal hydrous oxide.

  13. High resolution spectrometer for extended x-ray absorption fine structure measurements in the 6 keV to 15 keV energy range

    Science.gov (United States)

    Seely, J. F.; Hudson, L. T.; Henins, Albert; Feldman, U.

    2016-11-01

    A Cauchois transmission-crystal spectrometer has been developed with high crystal resolving power in the 6 keV-15 keV energy range and sufficient sensitivity to record single-shot spectra from the Lawrence Livermore National Laboratory (LLNL) Titan laser and other comparable or more energetic lasers. The spectrometer capabilities were tested by recording the W L transitions from a laboratory source and the extended x-ray absorption fine structure (EXAFS) spectrum through a Cu foil.

  14. Cyclic voltammetry and near edge X-ray absorption fine structure spectroscopy at the Ag L3-edge on electrochemical halogenation of Ag layers on Au(111)

    Science.gov (United States)

    Endo, Osamu; Nakamura, Masashi

    2011-05-01

    One to three layers of Ag grown on a Au(111) electrode were studied by cyclic voltammetry in chloride and bromide solutions and by ex-situ near-edge X-ray absorption fine structure spectroscopy at the Ag L3-edge (Ag L3-NEXAFS). The one and two layers obtained by underpotential deposition exhibited reduced intensity at the absorption edge in the Ag L3-NEXAFS spectra, which suggests the gain of d-electrons in these layers. The cyclic voltammograms and the Ag L3-NEXAFS spectra indicate that the second and third layers of Ag halogenated at positive potentials, whereas the first layer remained in metallic form.

  15. Extended x-ray--absorption fine structure of small Cu and Ni clusters: Binding-energy and bond-length changes with cluster size

    Energy Technology Data Exchange (ETDEWEB)

    Apai, G.; Hamilton, J.F.; Stohr, J.; Thompson, A.

    1979-07-09

    Extended x-ray--absorption fine-structure measurements have been made on metal clusters of Cu and Ni which were formed by vapor deposition on amorphous carbon substrates. Small clusters of both elements show a substantial contraction of the nearest-neighbor metal-metal distance and an increase in binding energy for the onset of the K absorption edge. The results are explained by the increasing surface-to-volume ratio as the cluster size decreases resulting in a more free-atom--like configuration of the metal atoms.

  16. Coupled-cluster response theory for near-edge x-ray-absorption fine structure of atoms and molecules

    DEFF Research Database (Denmark)

    Coriani, Sonia; Christiansen, Ove; Fransson, Thomas;

    2012-01-01

    triple corrected excitation energies CCSDR(3). This work is a first step toward the extension of these theoretical electronic structure methods of well-established high accuracy in UV-vis absorption spectroscopies to applications concerned with x-ray radiation. From the imaginary part of the linear...... response function, the near K-edge x-ray absorption spectra of neon, water, and carbon monoxide are determined and compared with experiment. Results at the CCSD level show relative peak intensities in good agreement with experiment with discrepancies in transition energies due to incomplete treatment...

  17. Iron (III)-silica interactions in aqueous solution: insights from X.-ray absorption fine structure spectroscopy

    Science.gov (United States)

    Pokrovski, Gleb S.; Schott, Jacques; Farges, François; Hazemann, Jean-Louis

    2003-10-01

    The influence of aqueous silica on the hydrolysis of iron(III) nitrate and chloride salts in dilute aqueous solutions ( mFe ˜ 0.01 mol/kg) was studied at ambient temperature using X-ray absorption fine structure (XAFS) spectroscopy at the Fe K-edge. Results show that in Si-free iron nitrate and chloride solutions at acid pH (pH hydroxide complexes form via Fe-(O/OH)-Fe bonds. In these polymers, the first atomic shell of iron represents a distorted octahedron with six O/OH groups and Fe-O distances ranging from 1.92 to 2.07 Å. The Fe octahedra are linked together by their edges (Fe-Fe distance 2.92-3.12 Å) and corners (Fe-Fe distance ˜3.47 ± 0.03 Å). The Fe-Fe coordination numbers ( Nedge = 1-2; Ncorner = 0.5-0.7) are consistent with the dominant presence of iron dimers, trimers and tetramers at pH 2.5 to 2.9, and of higher-polymerized species at pH > 3. At pH > 2.5 in the presence of aqueous silica, important changes in Fe(III) hydrolysis are detected. In 0.05- m Si solutions (pH ˜ 2.7-3.0), the corner linkages between Fe octahedra in the polymeric complexes disappear, and the Fe-Fe distances corresponding to the edge linkages slightly increase (Fe-Fe edge ˜ 3.12-3.14 Å). The presence of 1 to 2 silicons at 3.18 ± 0.03 Å is detected in the second atomic shell around iron. At basic pH (˜12.7), similar structural changes are observed for the iron second shell. The Fe-Si and Fe-Fe distances and coordination numbers derived in this study are consistent with (1) Fe-Si complex stoichiometries Fe 2Si 1-2 and Fe 3Si 2-3 at pH silicon tetrahedra linked to two neighboring Fe octahedra via corners. At higher Si concentration (0.16 m, polymerized silica solution) and pH ˜ 3, the signal of the Fe second shell vanishes indicating the destruction of the Fe-Fe bonds and the formation of different Fe-Si linkages. Moreover, ˜20 mol.% of Fe is found to be tetrahedrally coordinated with oxygens in the first coordination shell ( RFe-O = 1.84 Å). This new finding implies

  18. Na-induced bonding and bond-length changes for CO on Pt(111): A near-edge x-ray-absorption fine-structure study

    Energy Technology Data Exchange (ETDEWEB)

    Sette, F.; Stoehr, J.; Kollin, E.B.; Dwyer, D.J.; Gland, J.L.; Robbins, J.L.; Johnson, A.L.

    1985-03-04

    Near-edge x-ray absorption fine-structure studies above the C and O K edges for CO on Pt(111) reveal a 4-eV shift of the sigma shape resonance when Na(0.2 monolayer) is coabsorbed. This allows determination of a Na-induced (0.12 +- 0.03)-A expansion of the C-O bond. Na does not affect the vertical molecular orientation on the surface. Reduction and broadening of the 1s..-->..2..pi..( resonance and the CO bond lengthening in the presence of Na signifies substantially increased metal to CO backbonding.

  19. Application of x-ray absorption fine structure (XAFS) to local-order analysis in Fe-Cr maghemite-like materials

    Energy Technology Data Exchange (ETDEWEB)

    Montero-Cabrera, M. E., E-mail: elena.montero@cimav.edu.mx; Fuentes-Cobas, L. E.; Macías-Ríos, E. [Centro de Investigación en Materiales Avanzados, Chihuahua, 31136, México (Mexico); Fuentes-Montero, M. E. [Universidad Autónoma de Chihuahua, Chihuahua, 31000, México (Mexico)

    2015-07-23

    The maghemite-like oxide system γ-Fe{sub 2-x}Cr{sub x}O{sub 3} (x=0.75, 1 and 1.25) was studied by X-ray absorption fine structure (XAFS) and by synchrotron radiation X-ray diffraction (XRD). Measurements were performed at the Stanford Synchrotron Radiation Lightsource at room temperature, at beamlines 2-1, 2-3 and 4-3. High-resolution XRD patterns were processed by means of the Rietveld method. In cases of atoms being neighbors in the Periodic Table, the order/disorder degree of the considered solutions is indiscernible by “normal” (absence of “anomalous scattering”) diffraction experiments. Thus, maghemite-like materials were investigated by XAFS in both Fe and Cr K-edges to clarify, via short-range structure characterization, the local ordering of the investigated system. Athena and Artemis graphic user interfaces for IFEFFIT and FEFF8.4 codes were employed for XAFS spectra interpretation. Pre-edge decomposition and theoretical modeling of X-ray absorption near edge structure (XANES) transitions were performed. By analysis of the Cr K-edge XANES, it has been confirmed that Cr is located in an octahedral environment. Fitting of the extended X-ray absorption fine structure (EXAFS) spectra was performed under the consideration that the central atom of Fe is allowed to occupy octa- and tetrahedral positions, while Cr occupies only octahedral ones. Coordination number of neighboring atoms, interatomic distances and their quadratic deviation average were determined for x=1, by fitting simultaneously the EXAFS spectra of both Fe and Cr K-edges. The results of fitting the experimental spectra with theoretical standards showed that the cation vacancies tend to follow a regular pattern within the structure of the iron-chromium maghemite (FeCrO{sub 3})

  20. Thermal and magnetic anomalies of α-iron: an exploration by extended x-ray absorption fine structure spectroscopy and synchrotron x-ray diffraction

    Science.gov (United States)

    Boccato, Silvia; Sanson, Andrea; Kantor, Innokenty; Mathon, Olivier; Dyadkin, Vadim; Chernyshov, Dmitry; Carnera, Alberto; Pascarelli, Sakura

    2016-09-01

    The local structure and dynamics of α-iron have been investigated by extended x-ray absorption fine structure (EXAFS) spectroscopy and x-ray diffraction (XRD) in order to shed light on some thermal and magnetic anomalies observed in the last decades. The quantitative EXAFS analysis of the first two coordination shells reveals a peculiar local vibrational dynamics of α-iron: the second neighbor distance exhibits anharmonicity and vibrational anisotropy larger than the first neighbor distance. We search for possible distortions of the bcc structure to justify the unexplained magnetostriction anomalies of α-iron and provide a value for the maximum dislocation of the central Fe atom. No thermal anomalies have been detected from the current XRD data. On the contrary, an intriguing thermal anomaly at about 150 K, ascribed to a stiffening of the Fe-Fe bonds, was found by EXAFS.

  1. An X-ray Absorption Fine Structure study of Au adsorbed onto the non-metabolizing cells of two soil bacterial species

    Energy Technology Data Exchange (ETDEWEB)

    Song, Zhen; Kenney, Janice P.L.; Fein, Jeremy B.; Bunker, Bruce A. (Notre)

    2015-02-09

    Gram-positive and Gram-negative bacterial cells can remove Au from Au(III)-chloride solutions, and the extent of removal is strongly pH dependent. In order to determine the removal mechanisms, X-ray Absorption Fine Structure (XAFS) spectroscopy experiments were conducted on non-metabolizing biomass of Bacillus subtilis and Pseudomonas putida with fixed Au(III) concentrations over a range of bacterial concentrations and pH values. X-ray Absorption Near Edge Structure (XANES) and Extended X-ray Absorption Fine Structure (EXAFS) data on both bacterial species indicate that more than 90% of the Au atoms on the bacterial cell walls were reduced to Au(I). In contrast to what has been observed for Au(III) interaction with metabolizing bacterial cells, no Au(0) or Au-Au nearest neighbors were observed in our experimental systems. All of the removed Au was present as adsorbed bacterial surface complexes. For both species, the XAFS data suggest that although Au-chloride-hydroxide aqueous complexes dominate the speciation of Au in solution, Au on the bacterial cell wall is characterized predominantly by binding of Au atoms to sulfhydryl functional groups and amine and/or carboxyl functional groups, and the relative importance of the sulfhydryl groups increases with increasing pH and with decreasing Au loading. The XAFS data for both microorganism species suggest that adsorption is the first step in the formation of Au nanoparticles by bacteria, and the results enhance our ability to account for the behavior of Au in bacteria-bearing geologic systems.

  2. Local structure of Fe-doped In{sub 2}O{sub 3} films investigated by X-ray absorption fine structure spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    An, Yukai; Wang, Shiqi; Feng, Deqiang; Liu, Jiwen [Key Laboratory of Display Materials and Photoelectric Devices, Ministry of Education, Tianjin (China); Tianjin Key Laboratory for Photoelectric Materials and Devices, Tianjin (China); Tianjin University of Technology, School of Material Science and Engineering, Tianjin (China); Wu, Zhonghua [Chinese Academy of Sciences, Beijing Synchrotron Radiation Facility (BSRF), Institute of High Energy Physics, Beijing (China)

    2014-06-15

    (In{sub 1-x}Fe{sub x}){sub 2}O{sub 3} (x = 0.07, 0.09, 0.16, 0.22, 0.31) films were deposited on Si(100) substrates by RF-magnetron sputtering technique. The influence of Fe doping on the local structure of films was investigated by X-ray absorption spectroscopy (XAS) at Fe K-edge and L-edge. For the (In{sub 1-x}Fe{sub x}){sub 2}O{sub 3} films with x = 0.07, 0.09 and 0.16, Fe ions dissolve into In{sub 2}O{sub 3} and substitute for In{sup 3+} sites with a mixed-valence state (Fe{sup 2+}/Fe{sup 3+}) of Fe ions. However, a secondary phase of Fe metal clusters is formed in the (In{sub 1-x}Fe{sub x}){sub 2}O{sub 3} films with x = 0.22 and 0.31. The qualitative analyses of Fe-K edge extended X-ray absorption fine structure (EXAFS) reveal that the Fe-O bond length shortens and the corresponding Debye-Waller factor (α{sup 2}) increases with the increase of Fe concentration, indicating the relaxation of oxygen environment of Fe ions upon substitution. The anomalously large structural disorder and very short Fe-O distance are also observed in the films with high Fe concentration. Linear combination fittings at Fe L-edge further confirm the coexistence of Fe{sup 2+} and Fe{sup 3+} with a ratio of ∝3:2 (Fe{sup 2+}: Fe{sup 3+}) for the (In{sub 1-x}Fe{sub x}){sub 2}O{sub 3} film with x = 0.16. However, a significant fraction (∝40 at%) of the Fe metal clusters is found in the (In{sub 1-x}Fe{sub x}){sub 2}O{sub 3} film with x = 0.31. (orig.)

  3. Portable ultrahigh-vacuum sample storage system for polarization-dependent total-reflection fluorescence x-ray absorption fine structure spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Watanabe, Yoshihide, E-mail: e0827@mosk.tytlabs.co.jp; Nishimura, Yusaku F.; Suzuki, Ryo; Beniya, Atsushi; Isomura, Noritake [Toyota Central R& D Labs., Inc., Yokomichi 41-1, Nagakute, Aichi 480-1192 (Japan); Uehara, Hiromitsu; Asakura, Kiyotaka; Takakusagi, Satoru [Catalysis Research Center, Hokkaido University, Kita 21-10, Sapporo, Hokkaido 001-0021 (Japan); Nimura, Tomoyuki [AVC Co., Ltd., Inada 1450-6, Hitachinaka, Ibaraki 312-0061 (Japan)

    2016-03-15

    A portable ultrahigh-vacuum sample storage system was designed and built to investigate the detailed geometric structures of mass-selected metal clusters on oxide substrates by polarization-dependent total-reflection fluorescence x-ray absorption fine structure spectroscopy (PTRF-XAFS). This ultrahigh-vacuum (UHV) sample storage system provides the handover of samples between two different sample manipulating systems. The sample storage system is adaptable for public transportation, facilitating experiments using air-sensitive samples in synchrotron radiation or other quantum beam facilities. The samples were transferred by the developed portable UHV transfer system via a public transportation at a distance over 400 km. The performance of the transfer system was demonstrated by a successful PTRF-XAFS study of Pt{sub 4} clusters deposited on a TiO{sub 2}(110) surface.

  4. Extended x-ray absorption fine structure measurements on radio frequency magnetron sputtered HfO2 thin films deposited with different oxygen partial pressures.

    Science.gov (United States)

    Maidul Haque, S; Nayak, C; Bhattacharyya, Dibyendu; Jha, S N; Sahoo, N K

    2016-03-20

    Two sets of HfO2 thin film have been deposited by the radio frequency magnetron sputtering technique at various oxygen partial pressures, one set without any substrate bias and another set with a 50 W pulsed dc substrate bias. The films have been characterized by extended x-ray absorption fine structure (EXAFS) measurements at the Hf L3 edge, and the structural information obtained from analysis of the EXAFS data has been used to explain the macroscopic behavior of the refractive index obtained from spectroscopic ellipsometry measurements. It has been observed that the variation of refractive index with oxygen partial pressure depends on the Hf-Hf bond length for the set of films deposited without substrate bias, while for the other set of films deposited with pulsed dc substrate bias, it depends on the oxygen coordination of the nearest neighbor shell surrounding Hf sites.

  5. Composition analysis of a polymer electrolyte membrane fuel cell microporous layer using scanning transmission X-ray microscopy and near edge X-ray absorption fine structure analysis

    Science.gov (United States)

    George, Michael G.; Wang, Jian; Banerjee, Rupak; Bazylak, Aimy

    2016-03-01

    The novel application of scanning transmission X-ray microscopy (STXM) to the microporous layer (MPL) of a polymer electrolyte membrane fuel cell is investigated. A spatially resolved chemical component distribution map is obtained for the MPL of a commercially available SGL 25 BC sample. This is achieved with near edge X-ray absorption fine structure spectroscopic analysis. Prior to analysis the sample is embedded in non-reactive epoxy and ultra-microtomed to a thickness of 100 nm. Polytetrafluoroethylene (PTFE), carbon particle agglomerates, and supporting epoxy resin distributions are identified and reconstructed for a scanning area of 6 μm × 6 μm. It is observed that the spatial distribution of PTFE is strongly correlated to the carbon particle agglomerations. Additionally, agglomerate structures of PTFE are identified, possibly indicating the presence of a unique mesostructure in the MPL. STXM analysis is presented as a useful technique for the investigation of chemical species distributions in the MPL.

  6. The fate of silver ions in the photochemical synthesis of gold nanorods: an extended X-ray absorption fine structure analysis.

    Science.gov (United States)

    Giannici, Francesco; Placido, Tiziana; Curri, Maria Lucia; Striccoli, Marinella; Agostiano, Angela; Comparelli, Roberto

    2009-12-14

    Water-soluble gold nanorods (Au NRs) were synthesized using a silver-ion mediated photochemical route under UV irradiation. Extended X-ray Absorption Fine Structure (EXAFS) measurements on the Ag K-edge were performed on samples obtained at different Ag/Au ratios and at increasing irradiation times in order to investigate the fate of silver ions during the growth of Au NRs. EXAFS measurements allowed to probe the chemical state and the local environment of silver in the final product. Experimental data suggest that Ag atoms are placed on top of the Au particles as metallic Ag(0), while no significant contribution to the EXAFS spectra comes from AgBr or other Ag(+) based species. The reported results strongly support the deposition of Ag(0) islands on the (110) surfaces of the Au particles, thus driving the anisotropic growth via the (111) surfaces.

  7. Study of Synchrotron Radiation Near-Edge X-Ray Absorption Fine-Structure of Amorphous Hydrogenated Carbon Films at Various Thicknesses

    Directory of Open Access Journals (Sweden)

    Sarayut Tunmee

    2015-01-01

    Full Text Available The compositions and bonding states of the amorphous hydrogenated carbon films at various thicknesses were evaluated via near-edge X-ray absorption fine-structure (NEXAFS and elastic recoil detection analysis combined with Rutherford backscattering spectrometry. The absolute carbon sp2 contents were determined to decrease to 65% from 73%, while the hydrogen contents increase from 26 to 33 at.% as the film thickness increases. In addition, as the film thickness increases, the π⁎ (C=C, σ⁎ (C–H, σ⁎ (C=C, and σ⁎ (C≡C bonding states were found to increase, whereas the π⁎ (C≡C and σ⁎ (C–C bonding states were observed to decrease in the NEXAFS spectra. Consequently, the film thickness is a key factor to evaluate the composition and bonding state of the films.

  8. Particle Formation from Pulsed Laser Irradiation of SootAggregates studied with scanning mobility particle sizer, transmissionelectron microscope and near-edge x-ray absorption fine structure.

    Energy Technology Data Exchange (ETDEWEB)

    Michelsen, Hope A.; Tivanski, Alexei V.; Gilles, Mary K.; vanPoppel, Laura H.; Dansson, Mark A.; Buseck, Peter R.; Buseck, Peter R.

    2007-02-20

    We investigated the physical and chemical changes induced in soot aggregates exposed to laser radiation using a scanning mobility particle sizer, a transmission electron microscope, and a scanning transmission x-ray microscope to perform near-edge x-ray absorption fine structure spectroscopy. Laser-induced nanoparticle production was observed at fluences above 0.12 J/cm(2) at 532 nm and 0.22 J/cm(2) at 1064 nm. Our results indicate that new particle formation proceeds via (1) vaporization of small carbon clusters by thermal or photolytic mechanisms, followed by homogeneous nucleation, (2) heterogeneous nucleation of vaporized carbon clusters onto material ablated from primary particles, or (3) both processes.

  9. Near-edge X-ray absorption fine structure study of disordering in Gd2(Ti1-yZry)2O7 pyrochlores.

    Science.gov (United States)

    Nachimuthu, Ponnusamy; Thevuthasan, Suntharampillai; Adams, Evan M; Weber, William J; Begg, Bruce D; Mun, Bongjin S; Shuh, David K; Lindle, Dennis W; Gullikson, Eric M; Perera, Rupert C C

    2005-02-01

    Disorder in Gd2(Ti(1-y)Zry)2O7 pyrochlores, for y = 0.0-1.0, is investigated by Ti 2p and O 1s near-edge X-ray absorption fine structure spectroscopy. Ti(4+) ions are found to occupy octahedral sites in Gd2Ti2O7 with a tetragonal distortion induced by vacant oxygen sites. As Zr substitutes for Ti, the tetragonal distortion decreases, and Zr coordination increases from 6 to 8. The migration of oxygen ions from 48f or 8b sites to vacant 8a sites compensate for the increased Zr coordination, thereby reducing the number of vacant 8a sites, which further reduces the tetragonal distortion and introduces more disorder around Ti. This is evidence for simultaneous cation disorder with anion migration.

  10. Study of atomic clusters in neutron irradiated reactor pressure vessel surveillance samples by extended X-ray absorption fine structure spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Cammelli, S. [LWV, NES, Paul Scherrer Institute, 5232 Villigen PSI (Switzerland); Fachbereich C - Physik, Bergische Universitaet Wuppertal, Gauss-Str. 20, 42097 Wuppertal (Germany)], E-mail: Sebastiano.cammelli@psi.ch; Degueldre, C.; Kuri, G.; Bertsch, J. [LWV, NES, Paul Scherrer Institute, 5232 Villigen PSI (Switzerland); Luetzenkirchen-Hecht, D.; Frahm, R. [Fachbereich C - Physik, Bergische Universitaet Wuppertal, Gauss-Str. 20, 42097 Wuppertal (Germany)

    2009-03-31

    Copper and nickel impurities in nuclear reactor pressure vessel (RPV) steel can form nano-clusters, which have a strong impact on the ductile-brittle transition temperature of the material. Thus, for control purposes and simulation of long irradiation times, surveillance samples are submitted to enhanced neutron irradiation. In this work, surveillance samples from a Swiss nuclear power plant were investigated by extended X-ray absorption fine structure spectroscopy (EXAFS). The density of Cu and Ni atoms determined in the first and second shells around the absorber is affected by the irradiation and temperature. The comparison of the EXAFS data at Cu and Ni K-edges shows that these elements reside in arrangements similar to bcc Fe. However, the EXAFS analysis reveals local irradiation damage in the form of vacancy fractions, which can be determined with a precision of {approx}5%. There are indications that the formation of Cu and Ni clusters differs significantly.

  11. X-ray absorption fine structure analysis of molybdenum added to BaTiO3-based ceramics used for multilayer ceramic capacitors

    Science.gov (United States)

    Ogata, Yoichiro; Shimura, Tetsuo; Ryu, Minoru; Iwazaki, Yoshiki

    2017-04-01

    The effect of slight molybdenum doping of perovskite-type BaTiO3-based ceramics on the reliability of a multilayer ceramic capacitor (MLCC) and on the valence state of molybdenum in the BaTiO3-based ceramics has been investigated by highly accelerated lifetime tests and X-ray absorption fine structure analysis. The molybdenum added to the BaTiO3-based ceramics is located at Ti sites and improves the highly accelerated lifetime and lowers the initial dielectric resistivity in MLCCs. Through sintering in a reducing atmosphere, which is an important process in the fabrication of BaTiO3-based MLCCs, the oxidation state of the molybdenum added could be adjusted from +6 to a value close to +4.

  12. Multiple-Scattering Approaches to Near-Edge X-Ray Absorption Fine Structure of N2O/Cu(100)

    Institute of Scientific and Technical Information of China (English)

    WU Tai-Quan; TANG Jing-Chang; SHEN Shao-Lai; CAO Song; LI Hai-Yang

    2004-01-01

    @@ The nitrogen 1 s near-edge x-ray absorption fine structure (NEXAFS) spectra of the N2 O adsorbed on the Cu(100) surface have been studied by multiple-scattering cluster (MSC) and self-consistent field DV-Xα methods. It is shown that the N2O molecule is adsorbed on the hollow site with the adsorption height h = 3.0±0.1 A. The MSC calculation confirmed by a DV-Xα analysis has revealed the physical cause of the weak feature in the NEXAFS spectra mentioned above, which originates from the 1s core electrons of the centre and terminal nitrogen atoms transiting into the unoccupied σ* orbital of the N2O molecule.

  13. Communication: Near edge x-ray absorption fine structure spectroscopy of aqueous adenosine triphosphate at the carbon and nitrogen K-edges.

    Science.gov (United States)

    Kelly, Daniel N; Schwartz, Craig P; Uejio, Janel S; Duffin, Andrew M; England, Alice H; Saykally, Richard J

    2010-09-14

    Near edge x-ray absorption fine structure (NEXAFS) spectroscopy at the nitrogen and carbon K-edges was used to study the hydration of adenosine triphosphate in liquid microjets. The total electron yield spectra were recorded as a function of concentration, pH, and the presence of sodium, magnesium, and copper ions (Na(+)/Mg(2+)/Cu(2+)). Significant spectral changes were observed upon protonation of the adenine ring, but not under conditions that promote π-stacking, such as high concentration or presence of Mg(2+), indicating that NEXAFS is insensitive to the phenomenon. Intramolecular inner-sphere association of Cu(2+) did create observable broadening of the nitrogen spectrum, whereas outer-sphere association with Mg(2+) did not.

  14. Multiple-Scattering of Near-Edge x-ray Absorption Fine Structure of Sulphur-Passivated InP(100) Surface

    Institute of Scientific and Technical Information of China (English)

    曹松; 唐景昌; 沈少来; 陈更生; 马丹

    2003-01-01

    We use the multiple-scattering cluster method to calculate the sulphur 1s near-edge x-ray absorption fine structure (NEXAFS) of S-passivated InP(100) surface. The physical origins of the resonances in the NEXAFS have been unveiled. It is shown that the most important resonance is attributed to the photoelectron scattering between the central sulphur and the nearest indium atoms. The studies show that two S-S dimers with the bond lengths of 2.05 A and 3.05 A coexist in the surface, meanwhile the bridge and antibridge site adsorption of single S could not be ruled out. We support the scanning tunnelling microscopy result that the S-passivated InP(100) surface exhibits significant disorder.

  15. Near-edge X-ray absorption fine structure studies of Cr{sub 1−x}M{sub x}N coatings

    Energy Technology Data Exchange (ETDEWEB)

    Mahbubur Rahman, M. [School of Engineering and Information Technology, Murdoch University, Murdoch, WA 6150 (Australia); Department of Physics, Jahangirnagar University, Savar, Dhaka 1342 (Bangladesh); Duan, Alex [School of Chemistry, The University of Melbourne, Parkville, VIC 3010 (Australia); Jiang, Zhong-Tao, E-mail: Z.Jiang@murdoch.edu.au [School of Engineering and Information Technology, Murdoch University, Murdoch, WA 6150 (Australia); Xie, Zonghan [School of Mechanical Engineering, University of Adelaide, SA 5005 (Australia); School of Engineering, Edith Cowan University, WA 6027 (Australia); Wu, Alex [School of Chemistry, The University of Melbourne, Parkville, VIC 3010 (Australia); Amri, Amun [Department of Chemical Engineering, Riau University, Pekanbaru (Indonesia); Cowie, Bruce [Australian Synchrotron, 800 Blackburn Rd., Clayton, VIC 3168 (Australia); Yin, Chun-Yang [Chemical and Analytical Sciences, Murdoch University, Murdoch, WA 6150 (Australia)

    2013-11-25

    Highlights: •Al or Si is doped on CrN and AlN coatings using magnetron sputtering system. •NEXAFS analysis is conducted to measure the Al and Si K-edges, and chromium L-edge. •Structural evolution of CrN matrix with addition of Al or Si element is investigated. -- Abstract: Cr{sub 1−x}M{sub x}N coatings, with doping concentrations (Si or Al) varying from 14.3 to 28.5 at.%, were prepared on AISI M2 tool steel substrates using a TEER UDP 650/4 closed field unbalanced magnetron sputtering system. Near-edge X-ray absorption fine structure (NEXAFS) characterization was carried out to measure the aluminum and silicon K-edges, as well as chromium L-edge, in the coatings. Two soft X-ray techniques, Auger electron yield (AEY) and total fluorescence yield (TFY), were employed to investigate the surface and inner structural properties of the materials in order to understand the structural evolution of CrN matrix with addition of Al (or Si) elements. Investigations on the local bonding states and grain boundaries of the coatings, using NEXAFS technique, provide significant information which facilitates understanding of the local electronic structure of the atoms and shed light on the origins of the high mechanical strength and oxidation resistance of these technologically important coatings.

  16. In situ La, Ce, and Nd L-edge X-ray absorption fine structure study of an intermetallic metal hydride electrode in an operating alkaline battery

    Energy Technology Data Exchange (ETDEWEB)

    Tryk, D.A.; Bae, I.T.; Scherson, D. [Case Western Reserve Univ., Cleveland, OH (United States). Dept. of Chemistry; Antonio, M.R. [Argonne National Lab., IL (United States). Chemistry Division; Jordan, G.W.; Huston, E.L. [Energizer Power Systems, Gainesville, FL (United States)

    1995-05-01

    The X-ray absorption fine structure of a technologically important MmL{sub 5} intermetallic compound (Mm = La{sub 0.52}Ce{sub 0.34}Nd{sub 0.10}Pr{sub 0.04}, L{sub 5} Ni{sub 3.5}Ca{sub 0.8}Mn{sub 0.3}Al{sub 0.4}) in the form of a hydrogen storage cathode was recorded in situ in the region 5440-6290 eV using an electrochemical cell which is essentially a fully functioning alkaline battery. Significant differences were observed in the X-ray absorption near edge structure (XANES) of all of the absorption edges (La, Ce, and Nd) between the uncharged and fully charged states. In particular, a clear increase in the intensity of the La and Nd L{sub III}-edge resonances (due to 2P{sub 3/2} {r_arrow} 5d electronic transitions) was found upon charging the cell. This phenomenon was attributed to an increase in the density of empty d-like states near the Fermi level following hydrogen injection into the lattice. Furthermore, the behavior of the Ca L{sub II,III}-edges of this battery material upon charging was nearly the same as that observed for the gas phase hydrogenation of the Ce{sub 2}Fe{sub 17} and Ce{sub 2}Fe{sub 14}B intermetallics reported in the literature.

  17. Characterization of DPOAE fine structure

    DEFF Research Database (Denmark)

    Reuter, Karen; Hammershøi, Dorte

    2005-01-01

    , and has recently been demonstrated to exist in low level equal-loudness contours. The character of the DPOAE fine structure depends on several parameters, i.e., level, frequencies, and frequency of the two primaries, but also level and character of the noise floor. The prevalence and character of the fine......The distortion product otoacoustic emission (DPOAE) fine structure is revealed, when measuring DPOAE with a very fine frequency resolution. It is characterized by consistent maxima and minima with notches of up to 20 dB depth. The fine structure is known also from absolute hearing thresholds...... structures are highly individual, and till now no standardized method has been suggested for a consistent categorization. In the present paper a method developed for the categorization of fine structures is presented. The method has been used in two previous studies on the prevalence of fine structures, 1...

  18. Extended X-ray absorption fine structure studies of impulsive-type hardening in the heavily Be-doped ZnSe ternaries

    Energy Technology Data Exchange (ETDEWEB)

    Khan, Shabina; Singh, Pankaja [Barkatullah University, Bhopal (India); Mazher, Javed [Addis Ababa University, Addis Ababa (Ethiopia)

    2014-02-15

    Inherently soft zinc-selenides have been hardened through beryllium doping. High-quality stoichiometric ternaries of Be{sub x}Zn{sub 1-x}Se have been synthesized by using the Bridgeman technique. State-of-art X-ray absorption spectroscopy is performed by varying the concentration of the cationic dopant, Be, from 6% to 55% in the host ZnSe. Extended X-ray absorption fine structure analyses are carried out to study the next-neighbor and next nearest neighbor atomic positions, nature of the substitutional doping, extent of bond length homogeneity, the presence of involuntary contrast among path distances, and the crossover from a soft to a hard character of the ternary with increasing Be concentration. Our results indicate the presence of a non-regular impulsive hardening in the ternary with a disparity at the lower and the higher Be-doping levels, which are discussed vis-a-vis self-accommodation of substitutional dopants in the host lattice.

  19. Extended X-ray absorption fine structure (EXAFS) investigations of Ti bonding environment in sputter-deposited nanocomposite TiBC/a-C thin films

    Energy Technology Data Exchange (ETDEWEB)

    Endrino, J L; Gago, R; Jimenez, I [Instituto de Ciencias de Materiales de Madrid, Consejo Superior de Investigaciones Cientificas, Campus de Cantoblanco, E-28049 Madrid (Spain); Abad, M D; Sanchez-Lopez, J C [Instituto de Ciencia de Materiales de Sevilla, CSIC-Universidad de Sevilla, Avda. Americo Vespucio 49, 41092 Sevilla (Spain); Horwat, D, E-mail: jlendrino@icmm.csic.es [Institut Jean Lamour, Departement CP2S, Nancy Universite, Ecole des Mines, CS14234 Parc de Saurupt, 54042 Nancy Cedex (France)

    2010-06-15

    In this study, we have successfully used the extended X-ray absorption fine structure (EXAFS) technique at the Ti-K edge to extract the local structure in a set of nanocomposite TiBC/a-C coatings deposited by a combined d.c.-pulsed and r.f.-magnetron sputtering deposition process. The sequence of Fourier transform spectra in the deposited films shows that there is an increase in the number of Ti-C bonds in the films of higher carbon content in parallel with the increment of the total carbon content. In addition, Ti-K EXAFS spectra indicate that in all the deposited TiBC/a-C films, first-shell neighbours are in a nearer structural arrangement than the one expected for a bulk hexagonal TiB2, which could be due to the formation of mixed Ti-B-C compound in a structural unit similar to the one found in h-TiB{sub 2}.

  20. The Core/Shell Structure of CdSe/ZnS Quantum Dots Characterized by X-Ray Absorption Fine Spectroscopy

    Directory of Open Access Journals (Sweden)

    Huijing Wei

    2015-01-01

    Full Text Available Understanding the chemical and physical properties of core/shell nanocrystal quantum dots (QDs is key for their use in light-emission applications. In this paper, a single-step injection-free scalable synthetic method is applied to prepare high-quality core/shell QDs with emission wavelengths of 544 nm, 601 nm, and 634 nm. X-ray absorption fine structure spectra are used to determine the core/shell structure of CdSe/ZnS quantum dots. Moreover, theoretical XANES spectra calculated by FEFF.8.20 are used to determine the structure of Se and S compounds. The QD samples displayed nearly spherical shapes with diameters of approximately 3.4 ± 0.5 nm (634 nm, 4.5 ± 0.4 nm (601 nm, and 5.5 ± 0.5 nm (544 nm. With XANES results and MS calculations, it is indicated that sphalerite ZnS capped with organic sulfur ligands should be the shell structure. Wurtzite CdSe is the main core structure with a Cd-Se bond length of 2.3 Å without phase shift. This means that different emission wavelengths are only due to the crystal size with single-step injection-free synthesis. Therefore, single-step injection-free synthesis could generate a nearly ideal core/shell structure of CdSe/ZnS QDs capped with an organic sulfur ligand.

  1. Local vibrational dynamics of hematite (α-Fe{sub 2}O{sub 3}) studied by extended x-ray absorption fine structure and molecular dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Sanson, A., E-mail: andrea.sanson@unipd.it [Dipartimento di Fisica e Astronomia - Università di Padova, Padova (Italy); Mathon, O.; Pascarelli, S. [ESRF - European Synchrotron Radiation Facility, Grenoble (France)

    2014-06-14

    The local vibrational dynamics of hematite (α-Fe{sub 2}O{sub 3}) has been investigated by temperature-dependent extended x-ray absorption fine structure spectroscopy and molecular dynamics simulations. The local dynamics of both the short and long nearest-neighbor Fe–O distances has been singled out, i.e., their local thermal expansion and the parallel and perpendicular mean-square relative atomic displacements have been determined, obtaining a partial agreement with molecular dynamics. No evidence of the Morin transition has been observed. More importantly, the strong anisotropy of relative thermal vibrations found for the short Fe–O distance has been related to its negative thermal expansion. The differences between the local dynamics of short and long Fe–O distances are discussed in terms of projection and correlation of atomic motion. As a result, we can conclude that the short Fe–O bond is stiffer to stretching and softer to bending than the long Fe–O bond.

  2. PRELIMINARY IN-SITU X-RAY ABSORPTION FINE STRUCTURE EXAMINATION OF PT/C AND PTCO/C CATHODE CATALYSTS IN AN OPERATIONAL POLYMER ELECTROLYTE FUEL CELL

    Energy Technology Data Exchange (ETDEWEB)

    Phelan, B.T.; Myers, D.J.; Smith, M.C.

    2009-01-01

    State-of-the-art polymer electrolyte fuel cells require a conditioning period to reach optimized cell performance. There is insuffi cient understanding about the behavior of catalysts during this period, especially with regard to the changing environment of the cathode electrocatalyst, which is typically Pt nanoparticles supported on high surface area Vulcan XC-72 carbon (Pt/C). The purpose of this research was to record preliminary observations of the changing environment during the conditioning phase using X-Ray Absorption Fine Structure (XAFS) spectroscopy. XAFS was recorded for a Pt/C cathode at the Pt L3-edge and a PtCo/C cathode at both the Pt L3-edge and Co K-edge. Using precision machined graphite cell-blocks, both transmission and fl uorescence data were recorded at Sector 12-BM-B of Argonne National Laboratory’s Advanced Photon Source. The fl uorescence and transmission edge steps allow for a working description of the changing electrocatalyst environment, especially water concentration, at the anode and cathode as functions of operating parameters. These features are discussed in the context of how future analysis may correlate with potential, current and changing apparent thickness of the membrane electrode assembly through loss of catalyst materials (anode, cathode, carbon support). Such direct knowledge of the effect of the conditioning protocol on the electrocatalyst may lead to better catalyst design. In turn, this may lead to minimizing, or even eliminating, the conditioning period.

  3. Transmission electron microscopic and X-ray absorption fine structure spectroscopic investigation of U repartition and speciation after accumulation in renal cells

    Energy Technology Data Exchange (ETDEWEB)

    Carriere, M.; Milgram, S.; Thiebault, C.; Avoscan, L.; Gouget, B. [CEA Saclay, Lab Pierre Sue, CEA-CNRS, F-91191 Gif sur Yvette, (France); Proux, O. [Univ Joseph Fourier, CNRS, Lab Geophys Interne et Tectonophys, F-38400 Saint Martin d' Heres, (France)

    2008-07-01

    After environmental contamination, U accumulates in the kidneys and in bones, where it causes visible damage. Recent in vitro data prove that the occurrence of citrate increases U bioavailability without changing its speciation. Two hypotheses can explain the role of citrate: it either modifies the U intracellular metabolization pathway, or it acts on the transport of U through cell membrane. To understand which mechanisms lead to increased bioavailability, we studied the speciation of U after accumulation in NRK-52E kidney cells. U speciation was first identified in various exposure media, containing citrate or not, in which U was supplied as U carbonate. The influence of serum proteins was analyzed in order to detect the formation of macromolecular complexes of U. Transmission electron microscopy (TEM) was employed to follow the evolution of the U species distribution among precipitated and soluble forms. Finally, extended X-ray absorption fine structure spectroscopy (EXAFS) enabled the precipitates observed to be identified as U-phosphate. It also demonstrated that the intracellular soluble form of U is U carbonate. These results suggest that citrate does not change U metabolization but rather plays a role in the intracellular accumulation pathway. U speciation inside cells was directly and clearly identified for the first time. These results elucidate the role of U speciation in terms of its bioavailability and consequent health effects. (authors)

  4. Near-Edge X-Ray Absorption Fine Structure of Ultrananocrystalline Diamond/Hydrogenated Amorphous Carbon Films Prepared by Pulsed Laser Deposition

    Directory of Open Access Journals (Sweden)

    Shinya Ohmagari

    2009-01-01

    Full Text Available The atomic bonding configuration of ultrananocrystalline diamond (UNCD/hydrogenated amorphous carbon (a-C:H films prepared by pulsed laser ablation of graphite in a hydrogen atmosphere was examined by near-edge X-ray absorption fine structure spectroscopy. The measured spectra were decomposed with simple component spectra, and they were analyzed in detail. As compared to the a-C:H films deposited at room substrate-temperature, the UNCD/a-C:H and nonhydrogenated amorphous carbon (a-C films deposited at a substrate-temperature of 550∘C exhibited enhanced ∗ and ∗C≡C peaks. At the elevated substrate-temperature, the ∗ and ∗C≡C bonds formation is enhanced while the ∗C–H and ∗C–C bonds formation is suppressed. The UNCD/a-C:H film showed a larger ∗C–C peak than the a-C film deposited at the same elevated substrate-temperature in vacuum. We believe that the intense ∗C–C peak is evidently responsible for UNCD crystallites existence in the film.

  5. Nearest-neighbor nitrogen and oxygen distances in the iron(II)-DNA complex studied by extended X-ray absorption fine structure.

    Science.gov (United States)

    Bertoncini, Clelia R A; Meneghini, Rogerio; Tolentino, Helio

    2010-11-01

    In mammalian cells, DNA-bound Fe(II) reacts with H₂O₂ producing the highly reactive hydroxyl radical (OH) in situ. Since ·OH attacks nearby DNA residue generating oxidative DNA damage, many questions have arisen regarding iron-DNA complex formations and their implication in pre-malignant mutations and aging. In this work, a solid sample of Fe(II)-DNA complex containing one Fe(II) per 10 nucleotides was analyzed from extended X-ray absorption fine structure (EXAFS) spectra collected in a synchrotron radiation light source. Best fitting parameters of the EXAFS signal for the first two shells provide evidence of five oxygen atoms at 1.99 ± 0.02 Å and one nitrogen atom at 2.20 ± 0.02 Å in the inner coordination sphere of the Fe(II)-DNA complex. Considering that both purine base moieties bearing nitrogen atoms are prone to chelate iron, these results are consistent with the previously observed lower levels of DNA damage in cytosine nucleotides relative to adenine and guanine sites in cells under more physiological conditions of Fe(II) Fenton reaction.

  6. Near-edge X-ray absorption fine structure (NEXAFS) spectroscopy for mapping nano-scale distribution of organic carbon forms in soil: Application to black carbon particles

    Science.gov (United States)

    Lehmann, Johannes; Liang, Biqing; Solomon, Dawit; Lerotic, Mirna; LuizãO, Flavio; Kinyangi, James; SchäFer, Thorsten; Wirick, Sue; Jacobsen, Chris

    2005-03-01

    Small-scale heterogeneity of organic carbon (C) forms in soils is poorly quantified since appropriate analytical techniques were not available up to now. Specifically, tools for the identification of functional groups on the surface of micrometer-sized black C particles were not available up to now. Scanning Transmission X-ray Microscopy (STXM) using synchrotron radiation was used in conjunction with Near-Edge X-ray Absorption Fine Structure (NEXAFS) spectroscopy to investigate nano-scale distribution (50-nm resolution) of C forms in black C particles and compared to synchrotron-based FTIR spectroscopy. A new embedding technique was developed that did not build on a C-based embedding medium and did not pose the risk of heat damage to the sample. Elemental sulfur (S) was melted to 220°C until it polymerized and quenched with liquid N2 to obtain a very viscous plastic S in which the black C could be embedded until it hardened to a noncrystalline state and was ultrasectioned. Principal component and cluster analysis followed by singular value decomposition was able to resolve distinct areas in a black carbon particle. The core of the studied biomass-derived black C particles was highly aromatic even after thousands of years of exposure in soil and resembled the spectral characteristics of fresh charcoal. Surrounding this core and on the surface of the black C particle, however, much larger proportions of carboxylic and phenolic C forms were identified that were spatially and structurally distinct from the core of the particle. Cluster analysis provided evidence for both oxidation of the black C particle itself as well as adsorption of non-black C. NEXAFS spectroscopy has great potential to allow new insight into black C properties with important implications for biogeochemical cycles such as mineralization of black C in soils and sediments, and adsorption of C, nutrients, and pollutants as well as transport in the geosphere, hydrosphere, and atmosphere.

  7. Communication: Coordination structure of bromide ions associated with hexyltrimethylammonium cations at liquid/liquid interfaces under potentiostatic control as studied by total-reflection X-ray absorption fine structure.

    Science.gov (United States)

    Nagatani, Hirohisa; Harada, Makoto; Tanida, Hajime; Sakae, Hiroki; Imura, Hisanori

    2014-03-14

    Total-reflection X-ray absorption fine structure (TR-XAFS) technique was applied for the first time to an interface between two immiscible electrolyte solutions under potentiostatic control. The hydration structure of bromide ions was investigated at polarized 2-octanone/water interfaces. TR-XAFS spectra at Br K-edge measured in the presence of hexyltrimethylammonium bromide (C6TAB) were slightly modified depending on the Galvani potential difference (Δ(o)(w)φ). The extended X-ray absorption fine structure analysis exposed hydration structure changes of bromide ions at the polarized interface. The coordination structure of bromide ions at the interface could be analyzed as compared with bromide ions dissolved in aqueous solution and Br(-)-exchanged resin having quaternary ammonium groups. The results indicated that bromide ions were associated with C6TA(+) at the polarized interface. The relative contribution of ion association form of bromide ions with quaternary ammonium groups was enhanced at a potential close to the ion transfer of C6TA(+), where the interfacial concentration of C6TA(+) is increased as a function of Δ(o)(w)φ.

  8. Characterization of Functionalized Self-Assembled Monolayers and Surface-Attached Interlocking Molecules Using Near-Edge X-ray Absorption Fine Structure Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Willey, Trevor M. [Univ. of California, Davis, CA (United States)

    2004-04-01

    Quantitative knowledge of the fundamental structure and substrate binding, as well as the direct measurement of conformational changes, are essential to the development of self-assembled monolayers (SAMs) and surface-attached interlocking molecules, catenanes and rotaxanes. These monolayers are vital to development of nano-mechanical, molecular electronic, and biological/chemical sensor applications. This dissertation investigates properties of functionalized SAMs in sulfur-gold based adsorbed molecular monolayers using quantitative spectroscopic techniques including near-edge x-ray absorption fine structure spectroscopy (NEXAFS) and x-ray photoelectron spectroscopy (XPS). The stability of the gold-thiolate interface is addressed. A simple model SAM consisting of dodecanethiol adsorbed on Au(111) degrades significantly in less than 24 hours under ambient laboratory air. S 2p and O 1s XPS show the gold-bound thiolates oxidize to sulfinates and sulfonates. A reduction of organic material on the surface and a decrease in order are observed as the layer degrades. The effect of the carboxyl vs. carboxylate functionalization on SAM structure is investigated. Carboxyl-terminated layers consisting of long alkyl-chain thiols vs. thioctic acid with short, sterically separated, alkyl groups are compared and contrasted. NEXAFS shows a conformational change, or chemical switchability, with carboxyl groups tilted over and carboxylate endgroups more upright. Surface-attached loops and simple surface-attached rotaxanes are quantitatively characterized, and preparation conditions that lead to desired films are outlined. A dithiol is often insufficient to form a molecular species bound at each end to the substrate, while a structurally related disulfide-containing polymer yields surface-attached loops. Similarly, spectroscopic techniques show the successful production of a simple, surface-attached rotaxane that requires a ''molecular riveting'' step to hold the

  9. Apparatus for In Situ X-Ray Absorption Fine Structure Studies on Catalytic Systems in the Energy Range 1000 eV

    NARCIS (Netherlands)

    Koningsberger, D.C.; Eerden, A.M.J. van der; Bokhoven, J.A. van; Smith, A.D.

    2000-01-01

    A new apparatus for in situ x-ray absoprtion fine structure measurements in the medium energy range of 1000–3500 eV has been developed. Measurements can be performed in a gaseous environment (max. pressure 1 bar) at temperatures ranging from 80 to 750 K. Pre-treatments can be performed at 5 bar and

  10. Surface complexation and precipitate geometry for aqueous Zn(II) sorption on ferrihydrite I: X-ray absorption extended fine structure spectroscopy analysis

    Science.gov (United States)

    Waychunas, G.A.; Fuller, C.C.; Davis, J.A.

    2002-01-01

    "Two-line" ferrihydrite samples precipitated and then exposed to a range of aqueous Zn solutions (10-5 to 10-3 M), and also coprecipitated in similar Zn solutions (pH 6.5), have been examined by Zn and Fe K-edge X-ray absorption spectroscopy. Typical Zn complexes on the surface have Zn-O distances of 1.97(0.2) A?? and coordination numbers of about 4.0(0.5), consistent with tetrahedral oxygen coordination. This contrasts with Zn-O distances of 2.11(.02) A?? and coordination numbers of 6 to 7 in the aqueous Zn solutions used in sample preparation. X-ray absorption extended fine structure spectroscopy (EXAFS) fits to the second shell of cation neighbors indicate as many as 4 Zn-Fe neighbors at 3.44(.04) A?? in coprecipitated samples, and about two Zn-Fe neighbors at the same distance in adsorption samples. In both sets of samples, the fitted coordination number of second shell cations decreases as sorption density increases, indicating changes in the number and type of available complexing sites or the onset of competitive precipitation processes. Comparison of our results with the possible geometries for surface complexes and precipitates suggests that the Zn sorption complexes are inner sphere and at lowest adsorption densities are bidentate, sharing apical oxygens with adjacent edge-sharing Fe(O,OH)6 octahedra. Coprecipitation samples have complexes with similar geometry, but these are polydentate, sharing apices with more than two adjacent edge-sharing Fe(O,OH)6 polyhedra. The results are inconsistent with Zn entering the ferrihydrite structure (i.e., solid solution formation) or formation of other Zn-Fe precipitates. The fitted Zn-Fe coordination numbers drop with increasing Zn density with a minimum of about 0.8(.2) at Zn/(Zn + Fe) of 0.08 or more. This change appears to be attributable to the onset of precipitation of zinc hydroxide polymers with mainly tetrahedral Zn coordination. At the highest loadings studied, the nature of the complexes changes further

  11. Correlation of O (1s) and Fe (2p) near edge x-ray absorption fine structure spectra and electrical conductivity of La1-xSrxFe0.75Ni0.25O3-δ

    Science.gov (United States)

    Erat, Selma; Braun, Artur; Ovalle, Alejandro; Piamonteze, Cinthia; Liu, Zhi; Graule, Thomas; Gauckler, Ludwig J.

    2009-10-01

    A-site substitution of La3+ by Sr2+ in polaron conducting ABO3-type perovskite La1-xSrxFe0.75Ni0.25O3-δ causes oxidation of Fe3+ toward Fe4+ and formation of conducting electron holes, as evidenced by Fe (2p) and O (1s) near edge x-ray absorption fine structure spectra. Hole doping is reflected by linear variation of the prepeak ratio eg(↑)/[t2g(↓)+eg(↓)] of oxygen spectra, along with increased conductivity. The significant increase in conductivity due to NiO doping in La1-xSrxFeO3-δ is caused by increased overlap between Fe (3d) and O (2p) and charge transfer from the O (2p) to the Ni (3d) states, as concluded from near edge x-ray absorption fine structure spectra and ligand field multiplet calculations.

  12. Antimony(III) complexing with O-bearing organic ligands in aqueous solution: An X-ray absorption fine structure spectroscopy and solubility study

    Science.gov (United States)

    Tella, Marie; Pokrovski, Gleb S.

    2009-01-01

    The stability and structure of aqueous complexes formed by trivalent antimony (Sb III) with carboxylic acids (acetic, adipic, malonic, lactic, oxalic, tartaric, and citric acid), phenols (catechol), and amino acids (glycine) having O- and N-functional groups (carboxyl, alcoholic hydroxyl, phenolic hydroxyl and amine) typical of natural organic matter, were determined at 20 and 60 °C from solubility and X-ray absorption fine structure (XAFS) spectroscopy measurements. In organic-free aqueous solutions and in the presence of acetic, adipic, malonic acids and glycine, both spectroscopic and solubility data are consistent with the dominant formation of Sb III hydroxide species, Sb(OH)3-nn+,Sb(OH)30andSb(OH)4-, at strongly acid, acid-to-neutral and basic pH, respectively, demonstrating negligible complexing with mono-functional organic ligands (acetic) or those having non adjacent carboxylic groups (adipic, malonic). In contrast, in the presence of poly-functional carboxylic and hydroxy-carboxylic acids and catechol, Sb III forms stable 1:1 and 1:2 complexes with the studied organic ligands over a wide pH range typical of natural waters (3 cycle. Stability constants for these species, generated from Sb 2O 3 (rhomb.) solubility experiments, were used to model Sb complexing with natural humic acids possessing the same functional groups as those investigated in this study. Our predictions show that in an aqueous solution of pH between 2 and 10, containing 1 μg/L of Sb and 5 mg/L of dissolved organic carbon (DOC), up to 35% of total dissolved Sb binds to aqueous organic matter via carboxylic and hydroxy-carboxylic groups. This amount of complexed Sb for typical natural DOC concentrations is in agreement with that estimated from dialysis experiments performed with commercial humic acid in our work and those available in the literature for a range of standardized IHSS humic acids. Our results imply that a significant part of Sb is likely to be bound with humic acids via

  13. Extended X-ray absorption fine structure studies of Zn2Fe2 hybrid hemoglobins: absence of heme bond length changes in half-ligated species.

    Science.gov (United States)

    Simolo, K; Korszun, Z R; Stucky, G; Moffat, K; McLendon, G; Bunker, G

    1986-07-01

    Metal hybrid hemoglobins, in which Zn(II) replaces Fe(II), have been structurally characterized by extended X-ray absorption structure (EXAFS) studies. Since Zn and Fe have very different K absorption edge energies, the structures of the ligated (Fe) and unligated (Zn) sites could be examined independently within a single molecule that mimics an intermediate ligation state. The observed EXAFS spectra and associated structural parameters are compared among the ligand free (alpha Zn)2(beta Zn)2, half-ligated (alpha FeCO)2(beta Zn)2 and (alpha Zn)2(beta FeCO)2, and fully ligated (alpha FeCO)2(beta FeCO)2 systems.

  14. Surface atomic structures of Fe2O3 nanoparticles coated with cetyltrimethyl ammonium bromide and sodium dodecyl benzene sulphonate:an extended x-ray absorption fine-structure study

    Institute of Scientific and Technical Information of China (English)

    1999-01-01

    Fe2O3 nanoparticles coated with sodium dodecyl benzene sulphonate(DBS)or cetyltrimethyl ammonium bromide(CTAB) were prepared by using a microemulsion method in the system water/toluene.The nanoparticles were characterized by means of transmission electron microscopy and average particle sizes of 5.0nm and 6.0nm were found for DBS-modified and CTAB-modified nanoparticles respectively.The local atomic structures of these iron(Ⅲ) oxide nanoparticles were probed by using the extended x-ray absorption fine-structure technique.Fe K absorption spectra were collected at beam line 4W1B of Beijing Synchrotron Radiation Facility.A structureal model was proposed for describing their atomic structures.The Fe-O bond length at the surface of DBS-coated Fe2O3 nanoparticles was found to be similar to that in bulk Fe2O3.but there was about 0.04A expansion for the CTAB-coated Fe2O3 nanoparticles.On the basis of the model proposed in this paper,the thicknesses of the surface layers were estimated to be 0.5nm and 0.7nm.respectively,for the DBS-coated and CTAB-coated Fe2O3 nanoparticles.The anharmonicity of the atomic vibration and the asymmetry of atom-pair distribution were found to be larger at the surface of the nanoparticles than in the bulk material,while the Debye-Waller factors are almost the same for the surface and the core parts of the nanoparticles.It can be concluded that the atomic structure of the nanoparticle surface is ordered.but the atom-pari distribution is asymmetric.

  15. Local structures of mechanically alloyed Fe100—xCux solid soulutions studied by X—ray absorption fine structure

    Institute of Scientific and Technical Information of China (English)

    WenshengYan; YuzhiLi; 等

    2001-01-01

    The local structures of the immiscible Fe100-xCux alloys(x=0,10,20,40,60,80and100)produced by mechanical alloying have been investigated by XAFS.For the Fe100-xCux(x≥40) solid solutions,the local structures around Fe atoms change from bcc structure to fcc one and the Cu atoms maintain the original coordination geometry after milling for 160 hours.On the contrary,the local structures around Cu atoms in both of Fe80Cu20 and Fe90 Cu10 alloys appear a transition from fcc to bcc structure.We found that the Debye-waller factor σof fcc Fe-Cu phase is larger than that of bcc F-Cu phase,and the σ(0.099A°)around Fe atoms is larger than that (0.089A°) of Cu in the Fe100-xCux(x≥40)solid solutions,This suggests that the mechanically alloyed Fe100-xCux supersaturated solid solution is not a homogeneous alloy,and consists of Fe-rich and Cu-rich regions for various compositions.A possible mechanism for bcc-to-fcc and fcc-to-bcc changes in Fe100-xCux solid solutions is discussed in relation to the interdiffusion and transition induced by the ball milling.

  16. In-Plane Structure of Underpotentially Deposited Copper on Gold (111) Determined by Surface EXAFS (Extended X-Ray Absorption Fine Structure).

    Science.gov (United States)

    1988-01-28

    D-Al 263 INN-PLANE STRUCTURE OF UNDERPOTENTIALLY DEPOSITED COPPER /. ON GOLD (Iii) DET (U) PUERTO RICO UNIV RIO PIEDRAS DEPT OF PHVS I CS 0 R...051-0776 TECHNICAL REPORT #33 In-Plane Structure of Underpotentially Deposited Copper on Gold (111) Determined by Surface EXAFS by O.R. Melroy*, M.G...Strueture of Underpotentially Deposited Copper on Gold ( 11) determincd hv Surface EXAFS 0. R. Melroy*, N1. G. Samant, G. L. Borges. and J. G. Gordon

  17. Structural Analysis of the Mn(IV)/Fe(III) Cofactor of Chlamydia Trachomatis Ribonucleotide Reductase By Extended X-Ray Absorption Fine Structure Spectroscopy And Density Functional Theory Calculations

    Energy Technology Data Exchange (ETDEWEB)

    Younker, J.M.; Krest, C.M.; Jiang, W.; Krebs, C.; Bollinger, J.M.Jr.; Green, M.T.

    2009-05-28

    The class Ic ribonucleotide reductase from Chlamydia trachomatis (C{bar A}) uses a stable Mn(lV)/ Fe(lll) cofactor to initiate nucleotide reduction by a free-radical mechanism. Extended X-ray absorption fine structure (EXAFS) spectroscopy and density functional theory (DFT) calculations are used to postulate a structure for this cofactor. Fe and Mn K-edge EXAFS data yield an intermetallic distance of -2.92 {angstrom}. The Mn data also suggest the presence of a short 1.74 {angstrom} Mn-O bond. These metrics are compared to the results of DFT calculations on 12 cofactor models derived from the crystal structure of the inactive Fe2(lll/ III) form of the protein. Models are differentiated by the protonation states of their bridging and terminal OH{sub x} ligands as well as the location of the Mn(lV) ion (site 1 or 2). The models that agree best with experimental observation feature a{mu}-1, 3-carboxylate bridge (E120), terminal solvent (H{sub 2}O/OH) to site 1, one {mu}-O bridge, and one {mu}-OH bridge. The site-placement of the metal ions cannot be discerned from the available data.

  18. The Fe-heme structure of met-indoleamine 2,3-dioxygenase-2 determined by X-ray absorption fine structure

    Energy Technology Data Exchange (ETDEWEB)

    Aitken, Jade B. [School of Chemistry, The University of Sydney, NSW 2006 (Australia); Australian Synchrotron, Clayton, Victoria 3168 (Australia); Institute of Materials Structure Science, KEK, Tsukuba, Ibaraki 305-0801 (Japan); Austin, Christopher J.D. [School of Chemistry, The University of Sydney, NSW 2006 (Australia); Department of Pathology and Bosch Institute, The University of Sydney, Camperdown, NSW 2006 (Australia); Hunt, Nicholas H.; Ball, Helen J. [Department of Pathology and Bosch Institute, The University of Sydney, Camperdown, NSW 2006 (Australia); Lay, Peter A., E-mail: peter.lay@sydney.edu.au [School of Chemistry, The University of Sydney, NSW 2006 (Australia)

    2014-07-18

    Highlights: • IDO2 is a newly discovered tryptophan metabolising enzyme with a role in immunity. • IDO2’s active site contains a heme moiety for tryptophan binding and catabolism. • EXAFS/XANES analysis provides the first data of an IDO2 Fe-heme environment. • IDO2 Fe-heme exists as a low spin bis(His) form at 10 K; mixed spin-state at RT. - Abstract: Multiple-scattering (MS) analysis of EXAFS data on met-indoleamine 2,3-dioxygenase-2 (IDO2) and analysis of XANES have provided the first direct structural information about the axial donor ligands of the iron center for this recently discovered protein. At 10 K, it exists in a low-spin bis(His) form with Fe–N{sub p}(av) = 1.97 Å, the Fe–N{sub Im} bond lengths of 2.11 Å and 2.05 Å, which is in equilibrium with a high-spin form at room temperature. The bond distances in the low-spin form are consistent with other low-spin hemeproteins, as is the XANES spectrum, which is closer to that of the low-spin met-Lb than that of the high-spin met-Mb. The potential physiological role of this spin equilibrium is discussed.

  19. Probing cation antisite disorder in Gd2 Ti2 O7 pyrochlore by site-specific near-edge x-ray-absorption fine structure and x-ray photoelectron spectroscopy

    Science.gov (United States)

    Nachimuthu, P.; Thevuthasan, S.; Engelhard, M. H.; Weber, W. J.; Shuh, D. K.; Hamdan, N. M.; Mun, B. S.; Adams, E. M.; McCready, D. E.; Shutthanandan, V.; Lindle, D. W.; Balakrishnan, G.; Paul, D. M.; Gullikson, E. M.; Perera, R. C. C.; Lian, J.; Wang, L. M.; Ewing, R. C.

    2004-09-01

    Disorder in Gd2Ti2O7 is investigated by near-edge x-ray-absorption fine structure (NEXAFS) and x-ray photoelectron spectroscopy (XPS). NEXAFS shows Ti4+ ions occupy octahedral sites with a tetragonal distortion induced by vacant oxygen sites. O1s XPS spectra obtained with a charge neutralization system from Gd2Ti2O7(100) and the Gd2Ti2O7 pyrochlore used by Chen [Phys. Rev. Lett. 88, 105901 (2002)], both yielded a single peak, unlike the previous result on the latter that found two peaks. The current results give no evidence for an anisotropic distribution of Ti and O. The extra features reported in the aforementioned communication resulted from charging effects and incomplete surface cleaning. Thus, a result confirming the direct observation of simultaneous cation-anion antisite disordering and lending credence to the split vacancy model has been clarified.

  20. Structural characterization of Bi{sub 2}Te{sub 3} and Sb{sub 2}Te{sub 3} as a function of temperature using neutron powder diffraction and extended X-ray absorption fine structure techniques

    Energy Technology Data Exchange (ETDEWEB)

    Mansour, A. N. [Naval Surface Warfare Center, Carderock Division, West Bethesda, Maryland 20817 (United States); Wong-Ng, W. [Materials Measurement Science Division National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States); Huang, Q. [Center for Neutron Research National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States); Tang, W. [Zhejiang Sci-Tech University, Hangzhou, Zhejiang 310018 (China); Thompson, A.; Sharp, J. [Marlow Industries, Inc Dallas, Texas 75238 (United States)

    2014-08-28

    The structure of Bi{sub 2}Te{sub 3} (Seebeck coefficient Standard Reference Material (SRM™ 3451)) and the related phase Sb{sub 2}Te{sub 3} have been characterized as a function of temperature using the neutron powder diffraction (NPD) and the extended X-ray absorption fine structure (EXAFS) techniques. The neutron structural studies were carried out from 20 K to 300 K for Bi{sub 2}Te{sub 3} and from 10 K to 298 K for Sb{sub 2}Te{sub 3}. The EXAFS technique for studying the local structure of the two compounds was conducted from 19 K to 298 K. Bi{sub 2}Te{sub 3} and Sb{sub 2}Te{sub 3} are isostructural, with a space group of R3{sup ¯}m. The structure consists of repeated quintuple layers of atoms, Te2-M-Te1-M-Te2 (where M = Bi or Sb) stacking along the c-axis of the unit cell. EXAFS was used to examine the bond distances and static and thermal disorders for the first three shells of Bi{sub 2}Te{sub 3} and Sb{sub 2}Te{sub 3} as a function of temperature. The temperature dependencies of thermal disorders were analyzed using the Debye and Einstein models for lattice vibrations. The Debye and Einstein temperatures for the first two shells of Bi{sub 2}Te{sub 3} are similar to those of Sb{sub 2}Te{sub 3} within the uncertainty in the data. However, the Debye and Einstein temperatures for the third shell of Bi-Bi are significantly lower than those of the third shell of Sb-Sb. The Einstein temperature for the third shell is consistent with a soft phonon mode in both Bi{sub 2}Te{sub 3} and Sb{sub 2}Te{sub 3}. The lower Einstein temperature of Bi-Bi relative to Sb-Sb is consistent with the lower value of thermal conductivity of Bi{sub 2}Te{sub 3} relative to Sb{sub 2}Te{sub 3}.

  1. Two-channel opto-acoustic diode laser spectrometer and fine structure of methane absorption spectra in 6070-6180 cm-1 region.

    Science.gov (United States)

    Kapitanov, V A; Ponomarev, Yu N; Tyryshkin, I S; Rostov, A P

    2007-04-01

    We describe the hardware and software of the high-sensitive two-channel opto-acoustic spectrometer with a near infrared diode laser. A semiconductor TEC-100 laser with outer resonator generates a continuous single-frequency radiation in the range of 6040-6300 cm-1 with spectral resolution better that 10 MHz. The newly designed model of photo-acoustic cells in the form of a ring type resonator was used in the spectrometer, and the system allows the measurement of a weak absorption coefficient equal to 1.4x10(-7) cm-1 Hz-1/2 with a laser radiation power of 0.003 W. The methane absorption spectra within a range of 6080-6180 cm-1 were measured with a spectral resolution of 10 MHz and the signal to noise ratio more than 10(3). Six hundred absorption lines were recorded, which is twice as many as in HITRAN-2004. The accurate measurements of the half-width and shift of methane unresolved triplet R3 of 2nu3 band permit us to determine values of the broadening and shift coefficients for CH4-air, CH4-N2, and CH4-SF6 mixtures.

  2. Fine structure constant variation or space-time anisotropy?

    CERN Document Server

    Chang, Zhe; Li, Xin

    2011-01-01

    Recent observations on quasar absorption spectra supply evidences for variation of fine structure constant $\\alpha$. In this paper, we propose another interpretation of the observational data on quasar absorption spectra: a scenario with space-time inhomogeneity and anisotropy but uniform fine structure constant. Maybe the space-time is characterized by Finsler geometry instead of Riemann one. Finsler geometry admits less symmetries than Riemann geometry does. We investigate the Finslerian geodesic equations in Randers space-time (a special Finsler space-time). It is found that the cosmological redshift in this space-time is deviated from the one in general relativity. The modification term to redshift could be generally revealed as a monopole plus dipole function about space-time locations and directions. We suggest that this modification corresponds to the observed spatial monopole and Australian Dipole in quasar absorption spectra.

  3. Near-edge x-ray absorption fine-structure study of ion-beam-induced phase transformation in Gd2(Ti1-yZry)2O7

    Science.gov (United States)

    Nachimuthu, P.; Thevuthasan, S.; Shutthanandan, V.; Adams, E. M.; Weber, W. J.; Begg, B. D.; Shuh, D. K.; Lindle, D. W.; Gullikson, E. M.; Perera, R. C. C.

    2005-02-01

    The structural and electronic properties of Gd2(Ti1-yZry)2O7 (y =0-1) pyrochlores following a 2.0-MeV Au2+ ion-beam irradiation (˜5.0×1014Au2+/cm2) have been investigated by Ti2p and O1s near-edge x-ray absorption fine structure (NEXAFS). The irradiation of Gd2(Ti1-yZry)2O7 leads to the phase transformation from the ordered pyrochlore structure (Fd3m) to the defect fluorite structure (Fm3m) regardless of Zr concentration. Irradiated Gd2(Ti1-yZry)2O7 with y ⩽0.5 are amorphous, although significant short-range order is present. Contrasting to this behavior, compositions with y ⩾0.75 retain crystallinity in the defect fluorite structure following irradiation. The local structures of Zr4+ in the irradiated Gd2(Ti1-yZry)2O7 with y ⩾0.75 determined by NEXAFS are the same as in the cubic fluorite-structured yttria-stabilized zirconia (Y -ZrO2), thereby providing conclusive evidence for the phase transformation. The TiO6 octahedra present in Gd2(Ti1-yZry)2O7 are completely modified by ion-beam irradiation to TiOx polyhedra, and the Ti coordination is increased to eight with longer Ti -O bond distances. The similarity between cation sites and the degree of disorder in Gd2Zr2O7 facilitate the rearrangement and relaxation of Gd, Zr, and O ions/defects. This inhibits amorphization during the ion-beam-induced phase transition to the radiation-resistant defect fluorite structure, which is in contrast to the ordered Gd2Ti2O7.

  4. Experimental study of germanium adsorption on goethite and germanium coprecipitation with iron hydroxide: X-ray absorption fine structure and macroscopic characterization

    Science.gov (United States)

    Pokrovsky, O. S.; Pokrovski, G. S.; Schott, J.; Galy, A.

    2006-07-01

    Adsorption of germanium on goethite was studied at 25 °C in batch reactors as a function of pH (1-12), germanium concentration in solution (10 -7 to 0.002 M) and solid/solution ratio (1.8-17 g/L). The maximal surface site density determined via Ge adsorption experiments at pH from 6 to 10 is equal to 2.5 ± 0.1 μmol/m 2. The percentage of adsorbed Ge increases with pH at pH Model (SCM) which implies a constant capacitance of the electric double layer and postulates the presence of two Ge complexes, >FeO-Ge(OH)30 and >FeO-GeO(OH)2-, at the goethite-solution interface. Coprecipitation of Ge with iron oxy(hydr)oxides formed during Fe(II) oxidation by atmospheric oxygen or by Fe(III) hydrolysis in neutral solutions led to high Ge incorporations in solid with maximal Ge/Fe molar ratio close to 0.5. The molar Ge/Fe ratio in precipitated solid is proportional to that in the initial solution according to the equation (Ge/Fe) solid = k × (Ge/Fe) solution with 0.7 ⩽ k ⩽ 1.0. The structure of adsorbed and coprecipitated Ge complexes was further characterized using XAFS spectroscopy. In agreement with previous data on oxyanions adsorption on goethite, bi-dentate bi-nuclear surface complexes composed of tetrahedrally coordinated Ge attached to the corners of two adjacent Fe octahedra represent the dominant contribution to the EXAFS signal. Coprecipitated samples with Ge/Fe molar ratios >0.1, and samples not aged in solution (hydroxide at Ge/Fe molar ratio ⩽0.0001. These conditions are likely to be met in many superficial aquatic environments at the contact of anoxic groundwaters with surficial oxygenated solutions. Adsorption and coprecipitation of Ge with solid Fe oxy(hydr)oxides and organo-mineral colloids and its consequence for Ge/Si fractionation and Ge geochemical cycle are discussed.

  5. Cosmological Constant, Fine Structure Constant and Beyond

    CERN Document Server

    Wei, Hao; Li, Hong-Yu; Xue, Dong-Ze

    2016-01-01

    In this work, we consider the cosmological constant model $\\Lambda\\propto\\alpha^{-6}$, which is well motivated from three independent approaches. As is well known, the evidence of varying fine structure constant $\\alpha$ was found in 1998. If $\\Lambda\\propto\\alpha^{-6}$ is right, it means that the cosmological constant $\\Lambda$ should be also varying. In this work, we try to develop a suitable framework to model this varying cosmological constant $\\Lambda\\propto\\alpha^{-6}$, in which we view it from an interacting vacuum energy perspective. We propose two types of models to describe the evolutions of $\\Lambda$ and $\\alpha$. Then, we consider the observational constraints on these models, by using the 293 $\\Delta\\alpha/\\alpha$ data from the absorption systems in the spectra of distant quasars, and the data of type Ia supernovae (SNIa), cosmic microwave background (CMB), baryon acoustic oscillation (BAO). We find that the model parameters can be tightly constrained to the narrow ranges of ${\\cal O}(10^{-5})$ t...

  6. X-ray absorption fine structure evidence for amorphous zinc sulfide as a major zinc species in suspended matter from the Seine River downstream of Paris, Ile-de-France, France.

    Science.gov (United States)

    Priadi, Cindy; Le Pape, Pierre; Morin, Guillaume; Ayrault, Sophie; Maillot, Fabien; Juillot, Farid; Hochreutener, Rebecca; Llorens, Isabelle; Testemale, Denis; Proux, Olivier; Brown, Gordon E

    2012-04-01

    Zinc is one of the most widespread trace metals (TMs) in Earth surface environments and is the most concentrated TM in the downstream section of the Seine River (France) due to significant anthropogenic input from the Paris conurbation. In order to better identify the sources and cycling processes of Zn in this River basin, we investigated seasonal and spatial variations of Zn speciation in suspended particulate matter (SPM) in the oxic water column of the Seine River from upstream to downstream of Paris using synchrotron-based extend X-ray absorption fine structure (EXAFS) spectroscopy at the Zn K-edge. First-neighbor contributions to the EXAFS were analyzed in SPM samples, dried and stored under a dry nitrogen atmosphere or under an ambient oxygenated atmosphere. We found a sulfur first coordination environment around Zn (in the form of amorphous zinc sulfide) in the raw SPM samples stored under dry nitrogen vs an oxygen first coordination environment around Zn in the samples stored in an oxygenated atmosphere. These findings are supported by scanning electron microscopy and energy dispersive X-ray spectrometry observations. Linear combination fitting of the EXAFS data for SPM samples, using a large set of EXAFS spectra of Zn model compounds, indicates dramatic changes in the Zn speciation from upstream to downstream of Paris, with amorphous ZnS particles becoming dominant dowstream. In contrast, Zn species associated with calcite (either adsorbed or incorporated in the structure) are dominant upstream. Other Zn species representing about half of the Zn pool in the SPM consist of Zn-sorbed on iron oxyhydroxides (ferrihydrite and goethite) and, to a lesser extent, Zn-Al layered double hydroxides, Zn incorporated in dioctahedral layers of clay minerals and Zn sorbed to amorphous silica. Our results highlight the importance of preserving the oxidation state in TM speciation studies when sampling suspended matter, even in an oxic water column.

  7. Experimental and Theoretical Analysis of Sound Absorption Properties of Finely Perforated Wooden Panels

    Directory of Open Access Journals (Sweden)

    Boqi Song

    2016-11-01

    Full Text Available Perforated wooden panels are typically utilized as a resonant sound absorbing material in indoor noise control. In this paper, the absorption properties of wooden panels perforated with tiny holes of 1–3 mm diameter were studied both experimentally and theoretically. The Maa-MPP (micro perforated panels model and the Maa-Flex model were applied to predict the absorption regularities of finely perforated wooden panels. A relative impedance comparison and full-factorial experiments were carried out to verify the feasibility of the theoretical models. The results showed that the Maa-Flex model obtained good agreement with measured results. Control experiments and measurements of dynamic mechanical properties were carried out to investigate the influence of the wood characteristics. In this study, absorption properties were enhanced by sound-induced vibration. The relationship between the dynamic mechanical properties and the panel mass-spring vibration absorption was revealed. While the absorption effects of wood porous structure were not found, they were demonstrated theoretically by using acoustic wave propagation in a simplified circular pipe with a suddenly changed cross-section model. This work provides experimental and theoretical guidance for perforation parameter design.

  8. Invited article: The fast readout low noise camera as a versatile x-ray detector for time resolved dispersive extended x-ray absorption fine structure and diffraction studies of dynamic problems in materials science, chemistry, and catalysis

    Science.gov (United States)

    Labiche, Jean-Claude; Mathon, Olivier; Pascarelli, Sakura; Newton, Mark A.; Ferre, Gemma Guilera; Curfs, Caroline; Vaughan, Gavin; Homs, Alejandro; Carreiras, David Fernandez

    2007-09-01

    Originally conceived and developed at the European Synchrotron Radiation Facility (ESRF) as an "area" detector for rapid x-ray imaging studies, the fast readout low noise (FReLoN) detector of the ESRF [J.-C. Labiche, ESRF Newsletter 25, 41 (1996)] has been demonstrated to be a highly versatile and unique detector. Charge coupled device (CCD) cameras at present available on the public market offer either a high dynamic range or a high readout speed. A compromise between signal dynamic range and readout speed is always sought. The parameters of the commercial cameras can sometimes be tuned, in order to better fulfill the needs of specific experiments, but in general these cameras have a poor duty cycle (i.e., the signal integration time is much smaller than the readout time). In order to address scientific problems such as time resolved experiments at the ESRF, a FReLoN camera has been developed by the Instrument Support Group at ESRF. This camera is a low noise CCD camera that combines high dynamic range, high readout speed, accuracy, and improved duty cycle in a single image. In this paper, we show its application in a quasi-one-dimensional sense to dynamic problems in materials science, catalysis, and chemistry that require data acquisition on a time scale of milliseconds or a few tens of milliseconds. It is demonstrated that in this mode the FReLoN can be applied equally to the investigation of rapid changes in long range order (via diffraction) and local order (via energy dispersive extended x-ray absorption fine structure) and in situations of x-ray hardness and flux beyond the capacity of other detectors.

  9. Effect of Iron(II) on Arsenic Sequestration by δ-MnO2: Desorption Studies Using Stirred-Flow Experiments and X-Ray Absorption Fine-Structure Spectroscopy.

    Science.gov (United States)

    Wu, Yun; Li, Wei; Sparks, Donald L

    2015-11-17

    Arsenic (As) mobility in the environment is greatly affected by its oxidation state and the degree to which it is sorbed on metal oxide surfaces. Manganese (Mn) and iron (Fe) oxides are ubiquitous solids in terrestrial systems and have high sorptive capacities for many trace metals, including As. Although numerous studies have studied the effects of As adsorption and desorption onto Fe and Mn oxides individually, the fate of As within mixed systems representative of natural environments has not been resolved. In this research, As(III) was initially reacted with a poorly crystalline phyllomanganate (δ-MnO2) in the presence of Fe(II) prior to desorption. This initial reaction resulted in the sorption of both As(III) and As(V) on mixed Fe/Mn-oxides surfaces. A desorption study was carried out using two environmentally significant ions, phosphate (PO4(3-)) and calcium (Ca(2+)). Both a stirred-flow technique and X-ray absorption fine-structure spectroscopy (XAFS) analysis were used to investigate As desorption behavior. Results showed that when As(III)/Fe(II) = 1:1 in the initial reaction, only As(V) was desorbed, agreeing with a previous study showing that As(III) is not associated with the Fe/Mn-oxides. When As(III)/Fe(II) = 1:10 in the initial reaction, both As(III) and As(V) can be desorbed from the Fe/Mn-oxide surface, and more As(III) is desorbed than As(V). Neither of the desorbents used in this study completely removed As(III) or As(V) from the Fe/Mn-oxides surface. However, the As desorption fraction decreases with increasing Fe(II) concentration in the initial reactions.

  10. Extended x-ray absorption fine structure study of incorporation of Bi and Pb atoms into the crystal structure of Ba{sub 4.5}Nd{sub 9}Ti{sub 18}O{sub 54}

    Energy Technology Data Exchange (ETDEWEB)

    Valant, M.; Arcon, I.; Suvorov, D.; Kodre, A. [Jozef Stefan Institute, Jamova 39, 1000 Ljubljana, University of Ljubljana (Slovenia); Negas, T. [Trans-Tech Inc., Adamstown, Maryland 21702 (United States); Frahm, R. [Hambruger Synchrotronstrahlungslabor at Deutsches Elektronen Synchrotron DESY, Hamburg (Germany)

    1997-03-01

    In extended x-ray aborption fine structure (EXAFS) study of local environment of Bi{sup 3+} and Pb{sup 2+} ions incorporated in Ba{sub 4.5}Nd{sub 9}Ti{sub 18}O{sub 54} actual sites of Bi- and Pb-incorporated are determined. Evidences are given that dopant ions are not distributed randomly on all theoretically possible sites: Bi{sup 3+} selectively enters one out of three posible channels, corresponding to the sites x=0.9484, y=0.2500, z=0.2939, and/or x=0.0455, y=0.2500, z=0.6928 previously occupied by Nd{sup 3+}, while Pb{sup 2+} selectively enters site x=0.4940, y=0.2500, z=0.4993 previously shared by Ba{sup 2+} and Nd{sup 3+}. {copyright} {ital 1997 Materials Research Society.}

  11. The fine structure of the ionosphere

    DEFF Research Database (Denmark)

    D'Angelo, N.; Michelsen, Poul

    1967-01-01

    We consider in this note the excitation of ion-acoustic waves by vertical gradients of density in the ionosphere. The conclusion is reached that the fine structure of the ionosphere is probably affected by the resulting instability, as comparison with observations seems to indicate. Recently, Liu...

  12. Fine structure of the exciton electroabsorption in semiconductor superlattices

    Science.gov (United States)

    Monozon, B. S.; Schmelcher, P.

    2017-02-01

    Wannier-Mott excitons in a semiconductor layered superlattice (SL) are investigated analytically for the case that the period of the superlattice is much smaller than the 2D exciton Bohr radius. Additionally we assume the presence of a longitudinal external static electric field directed parallel to the SL axis. The exciton states and the optical absorption coefficient are derived in the tight-binding and adiabatic approximations. Strong and weak electric fields providing spatially localized and extended electron and hole states, respectively, are studied. The dependencies of the exciton states and the exciton absorption spectrum on the SL parameters and the electric field strength are presented in an explicit form. We focus on the fine structure of the ground quasi-2D exciton level formed by the series of closely spaced energy levels adjacent from the high frequencies. These levels are related to the adiabatically slow relative exciton longitudinal motion governed by the potential formed by the in-plane exciton state. It is shown that the external electric fields compress the fine structure energy levels, decrease the intensities of the corresponding optical peaks and increase the exciton binding energy. A possible experimental study of the fine structure of the exciton electroabsorption is discussed.

  13. Combined time-resolved laser fluorescence spectroscopy and extended X-ray absorption fine structure spectroscopy study on the complexation of trivalent actinides with chloride at T = 25-200 °C.

    Science.gov (United States)

    Skerencak-Frech, Andrej; Fröhlich, Daniel R; Rothe, Jörg; Dardenne, Kathy; Panak, Petra J

    2014-01-21

    The complexation of trivalent actinides (An(III)) with chloride is studied in the temperature range from 25 to 200 °C by spectroscopic methods. Time-resolved laser fluorescence spectroscopy (TRLFS) is applied to determine the thermodynamic data of Cm(III)-Cl(-) complexes, while extended X-ray absorption fine structure spectroscopy (EXAFS) is used to determine the structural data of the respective Am(III) complexes. The experiments are performed in a custom-built high-temperature cell which is modified for the respective spectroscopic technique. The TRLFS results show that at 25 °C the speciation is dominated mainly by the Cm(3+) aquo ion. Only a minor fraction of the CmCl(2+) complex is present in solution. As the temperature increases, the fraction of this species decreases further. Simultaneously, the fraction of the CmCl2(+) complex increases strongly with the temperature. Also, the CmCl3 complex is formed to a minor extent at T > 160 °C. The conditional stability constant log β'2 is determined as a function of the temperature and extrapolated to zero ionic strength with the specific ion interaction theory approach. The log β°2(T) values increase by more than 3 orders of magnitude in the studied temperature range. The temperature dependency of log β°2 is fitted by the extended van't Hoff equation to determine ΔrH°m, ΔrS°m, and ΔrC°p,m. The EXAFS results support these findings. The results confirm the absence of americium(III) chloride complexes at T = 25 and 90 °C ([Am(III)] = 10(-3) m, [Cl(-)] = 3.0 m), and the spectra are described by 9-10 oxygen atoms at a distance of 2.44-2.48 Å. At T = 200 °C two chloride ligands are present in the inner coordination sphere of Am(III) at a distance of 2.78 Å.

  14. The O2-Evolving Complex of Photosystem II: Recent Insights from Quantum Mechanics/Molecular Mechanics (QM/MM), Extended X-ray Absorption Fine Structure (EXAFS), and Femtosecond X-ray Crystallography Data.

    Science.gov (United States)

    Askerka, Mikhail; Brudvig, Gary W; Batista, Victor S

    2017-01-17

    Efficient photoelectrochemical water oxidation may open a way to produce energy from renewable solar power. In biology, generation of fuel due to water oxidation happens efficiently on an immense scale during the light reactions of photosynthesis. To oxidize water, photosynthetic organisms have evolved a highly conserved protein complex, Photosystem II. Within that complex, water oxidation happens at the CaMn4O5 inorganic catalytic cluster, the so-called oxygen-evolving complex (OEC), which cycles through storage "S" states as it accumulates oxidizing equivalents and produces molecular oxygen. In recent years, there has been significant progress in understanding the OEC as it evolves through the catalytic cycle. Studies have combined conventional and femtosecond X-ray crystallography with extended X-ray absorption fine structure (EXAFS) and quantum mechanics/molecular mechanics (QM/MM) methods and have addressed changes in protonation states of μ-oxo bridges and the coordination of substrate water through the analysis of ammonia binding as a chemical analog of water. These advances are thought to be critical to understanding the catalytic cycle since protonation states regulate the relative stability of different redox states and the geometry of the OEC. Therefore, establishing the mechanism for substrate water binding and the nature of protonation/redox state transitions in the OEC is essential for understanding the catalytic cycle of O2 evolution. The structure of the dark-stable S1 state has been a target for X-ray crystallography for the past 15 years. However, traditional X-ray crystallography has been hampered by radiation-induced reduction of the OEC. Very recently, a revolutionary X-ray free electron laser (XFEL) technique was applied to PSII to reveal atomic positions at 1.95 Å without radiation damage, which brought us closer than ever to establishing the ultimate structure of the OEC in the S1 state. However, the atom positions in this crystal

  15. On a time varying fine structure constant

    CERN Document Server

    Berman, M S; Berman, Marcelo S.; Trevisan, Luis A.

    2001-01-01

    By employing Dirac LNH, and a further generalization by Berman (GLNH), we estimate how should vary the total number of nucleons, the energy density, Newton Gravitational constant, the cosmological constant, the magnetic permeability and electric permitivity, of the Universe,in order to account for the experimentally observed time variation of the fine structure constant. As a bonus,we find an acceptable value for the deceleration parameter of the present Universe, compatible with the Supernovae observations.

  16. Extended X-ray absorption fine structure studies of Zn/sub 2/Fe/sub 2/ hybrid hemoglobins: absence of heme bond length changes in half-ligated species

    Energy Technology Data Exchange (ETDEWEB)

    Simolo, K.; Korszun, Z.R.; Stucky, G.; Moffat, K.; McLendon, G.

    1986-07-01

    Metal hybrid hemoglobins, in which Zn(II) replaces Fe(II), have been structurally characterized by extended X-ray absorption structure (EAFS) studies. Since Zn and Fe have very different K absorption edge energies, the structures of the ligated (Fe) and unligated (Zn) sites could be examined independently within a single molecule that mimics an intermediate ligation state. The observed EXAFS spectra and associated structural parameters are compared among the ligand free (..cap alpha..Zn)/sub 2/(..beta..Zn)/sub 2/, half-ligated (..cap alpha..FeCO)/sub 2/(..beta..Zn)/sub 2/ and (..cap alpha..Zn)/sub 2/(..beta..FeCO)/sub 2/, and fully ligated (..cap alpha..FeCO)/sub 2/(..beta..FeCO)/sub 2/ systems.

  17. Variation of the fine structure constant

    CERN Document Server

    Lipovka, Anton A

    2016-01-01

    In present paper we evaluate the fine structure constant variation which should take place as the Universe is expanded and its curvature is changed adiabatically. This changing of the fine structure constant is attributed to the energy lost by physical system (consist of baryonic component and electromagnetic field) due to expansion of our Universe. Obtained ratio (d alpha)/alpha = 1. 10{-18} (per second) is only five times smaller than actually reported experimental limit on this value. For this reason this variation can probably be measured within a couple of years. To argue the correctness of our approach we calculate the Planck constant as adiabatic invariant of electromagnetic field, from geometry of our Universe in the framework of the pseudo- Riemannian geometry. Finally we discuss the double clock experiment based on Al+ and Hg+ clocks carried out by T. Rosenband et al. (Science 2008). We show that in this particular case there is an error in method and this way the fine structure constant variation c...

  18. Microwave non-resonant absorption in fine cobalt ferrite particles

    Energy Technology Data Exchange (ETDEWEB)

    Mata-Zamora, M.E. [Depto. Investigacion Aplicada, Centro de Ciencias Aplicadas y Desarrollo Tecnologico, Universidad Nacional Autonoma de Mexico, 04510 (Mexico)]. E-mail: memzamora@yahoo.com.mx; Montiel, H. [Depto. Investigacion Aplicada, Centro de Ciencias Aplicadas y Desarrollo Tecnologico, Universidad Nacional Autonoma de Mexico, 04510 (Mexico); Alvarez, G. [Depto. Metalicos y Ceramicos, Instituto de Investigaciones en Materiales, Universidad Nacional Autonoma de Mexico, 04510 (Mexico); Saniger, J.M. [Depto. Investigacion Aplicada, Centro de Ciencias Aplicadas y Desarrollo Tecnologico, Universidad Nacional Autonoma de Mexico, 04510 (Mexico); Zamorano, R. [Escuela Superior de Fisica y Matematicas, IPN, 07738 (Mexico); Valenzuela, R. [Depto. Metalicos y Ceramicos, Instituto de Investigaciones en Materiales, Universidad Nacional Autonoma de Mexico, 04510 (Mexico)

    2007-09-15

    Cobalt ferrite particles of average crystallite size of 11 nm were obtained by a sol-gel process at 400 deg. C . The powders were annealed at temperatures of 500, 600, 700 and 800 deg. C in air. Derivative microwave power absorption (dP/dH) measurements were carried out as a function of magnetic field (H {sub DC}) at X band (9.4 GHz), in the field range -80-796 kA/m for all annealed temperatures. In order to compare the response of saturation magnetization measurements with high frequency measurements, we calculated the areas inside both the magnetization (A {sub M}) and the absorption hysteresis loops (A {sub LFS}). The dependence of these areas as a function of crystallite size is remarkably similar in both experiments.

  19. Further Evidence for Cosmological Evolution of the Fine Structure Constant

    CERN Document Server

    Webb, J K; Flambaum, V V; Dzuba, V A; Barrow, John D; Churchill, C W; Prochaska, J X; Wolfe, A M

    2001-01-01

    We summarise the results of a search for time variability of the fine structure constant, alpha, using absorption systems in the spectra of distant quasars. Three large optical datasets and two 21cm/mm absorption systems provide four independent samples, spanning approximately 23% to 87% of the age of the universe. Each sample yields a negative Delta(alpha)/alpha (smaller alpha in the past) and the whole optical sample shows a 4-sigma deviation: Delta(alpha)/alpha = -0.72 +/- 0.18 x 10^{-5} over the redshift range 0.5 < z < 3.5. A comprehensive search for systematic effects reveals none which can explain our results. The only potentially significant systematic effects push Delta(alpha)/alpha towards positive values, i.e. our results would become more significant were we to correct for them.

  20. Identifying barriers to charge-carriers in the bulk and surface regions of Cu2ZnSnS4 nanocrystal films by x-ray absorption fine structures (XAFSs)

    Science.gov (United States)

    Turnbull, Matthew J.; Vaccarello, Daniel; Yiu, Yun Mui; Sham, Tsun-Kong; Ding, Zhifeng

    2016-11-01

    Solar cell performance is most affected by the quality of the light absorber layer. For thin-film devices, this becomes a two-fold problem of maintaining a low-cost design with well-ordered nanocrystal (NC) structure. The use of Cu2ZnSnS4 (CZTS) NCs as the light absorber films forms an ideal low-cost design, but the quaternary structure makes it difficult to maintain a well-ordered layer without the use of high-temperature treatments. There is little understanding of how CZTS NC structures affect the photoconversion efficiency, the charge-carriers, and therefore the performance of the device manufactured from it. To examine these relationships, the measured photoresponse from the photo-generation of charge-carrier electron-hole pairs was compared against the crystal structure, as short-range and long-range crystal orders for the films. The photoresponse simplifies the electronic properties into three basic steps that can be associated with changes in energy levels within the band structure. These changes result in the formation of barriers to charge-carrier flow. The extent of these barriers was determined using synchrotron-based X-ray absorbance fine structure to probe the individual metal centers in the film, and comparing these to molecular simulations of the ideal extended x-ray absorbance fine structure scattering. This allowed for the quantification of bond lengths, and thus an interpretation of the distortions in the crystal lattice. The various characteristics of the photoresponse were then correlated to the crystallographic order and used to gain physical insight into barriers to charge-carriers in the bulk and surface regions of CZTS films.

  1. The fine structure constant and habitable planets

    DEFF Research Database (Denmark)

    Sandora, McCullen

    2016-01-01

    © 2016 IOP Publishing Ltd and Sissa Medialab srl .We use the existence of habitable planets to impose anthropic requirements on the fine structure constant, α. To this effect, we present two considerations that restrict its value to be very near the one observed. The first, that the end product...... of stellar fusion is iron and not one of its neighboring elements, restricts α-1 to be 145± 50. The second, that radiogenic heat in the Earth's interior remains adequately productive for billions of years, restricts it to be 145±9. A connection with the grand unified theory window is discussed, effectively...

  2. The Fine Structure Constant and Habitable Planets

    CERN Document Server

    Sandora, McCullen

    2016-01-01

    We use the existence of habitable planets to impose anthropic requirements on the fine structure constant, $\\alpha$. To this effect, we present two considerations that restrict its value to be very near the one observed. The first, that the end product of stellar fusion is iron and not one of its neighboring elements, restricts $\\alpha^{-1}$ to be $145\\pm 50$. The second, that radiogenic heat in the Earth's interior remains adequately productive for billions of years, restricts it to be $145\\pm9$. A connection with the grand unified theory window is discussed, effectively providing a route to probe ultra-high energy physics with upcoming advances in planetary science.

  3. The fine structure constant and habitable planets

    Science.gov (United States)

    Sandora, McCullen

    2016-08-01

    We use the existence of habitable planets to impose anthropic requirements on the fine structure constant, α. To this effect, we present two considerations that restrict its value to be very near the one observed. The first, that the end product of stellar fusion is iron and not one of its neighboring elements, restricts α-1 to be 145± 50. The second, that radiogenic heat in the Earth's interior remains adequately productive for billions of years, restricts it to be 145±9. A connection with the grand unified theory window is discussed, effectively providing a route to probe ultra-high energy physics with upcoming advances in planetary science.

  4. Molecular Eigensolution Symmetry Analysis and Fine Structure

    Directory of Open Access Journals (Sweden)

    William G. Harter

    2013-01-01

    Full Text Available Spectra of high-symmetry molecules contain fine and superfine level cluster structure related to J-tunneling between hills and valleys on rovibronic energy surfaces (RES. Such graphic visualizations help disentangle multi-level dynamics, selection rules, and state mixing effects including widespread violation of nuclear spin symmetry species. A review of RES analysis compares it to that of potential energy surfaces (PES used in Born-Oppenheimer approximations. Both take advantage of adiabatic coupling in order to visualize Hamiltonian eigensolutions. RES of symmetric and D2 asymmetric top rank-2-tensor Hamiltonians are compared with Oh spherical top rank-4-tensor fine-structure clusters of 6-fold and 8-fold tunneling multiplets. Then extreme 12-fold and 24-fold multiplets are analyzed by RES plots of higher rank tensor Hamiltonians. Such extreme clustering is rare in fundamental bands but prevalent in hot bands, and analysis of its superfine structure requires more efficient labeling and a more powerful group theory. This is introduced using elementary examples involving two groups of order-6 (C6 and D3~C3v, then applied to families of Oh clusters in SF6 spectra and to extreme clusters.

  5. Magnetic Tension of Sunspot Fine Structures

    CERN Document Server

    Venkatakrishnan, P

    2010-01-01

    The equilibrium structure of sunspots depends critically on its magnetic topology and is dominated by magnetic forces. Tension force is one component of the Lorentz force which balances the gradient of magnetic pressure in force-free configurations. We employ the tension term of the Lorentz force to clarify the structure of sunspot features like penumbral filaments, umbral light bridges and outer penumbral fine structures. We compute vertical component of tension term of Lorentz force over two active regions namely NOAA AR 10933 and NOAA AR 10930 observed on 05 January 2007 and 12 December 2006 respectively. The former is a simple while latter is a complex active region with highly sheared polarity inversion line (PIL). The vector magnetograms used are obtained from Hinode(SOT/SP). We find an inhomogeneous distribution of tension with both positive and negative signs in various features of the sunspots. The existence of positive tension at locations of lower field strength and higher inclination is compatible...

  6. Time Variation of the Fine Structure Constant Driven by Quintessence

    CERN Document Server

    Anchordoqui, L A; Anchordoqui, Luis; Goldberg, Haim

    2003-01-01

    There are indications from the study of quasar absorption spectra that the fine structure constant $\\alpha$ may have been measurably smaller for redshifts $z>2.$ Analyses of other data ($^{149}$Sm fission rate for the Oklo natural reactor, variation of $^{187}$Re $\\beta$-decay rate in meteorite studies, atomic clock measurements) which probe variations of $\\alpha$ in the more recent past imply much smaller deviations from its present value. In this work we tie the variation of $\\alpha$ to the evolution of the quintessence field proposed by Albrecht and Skordis, and show that agreement with all these data, as well as consistency with WMAP observations, can be achieved for a range of parameters. Some definite predictions follow for upcoming space missions searching for violations of the equivalence principle.

  7. Time variation of the fine structure constant driven by quintessence

    Science.gov (United States)

    Anchordoqui, Luis; Goldberg, Haim

    2003-10-01

    There are indications from the study of quasar absorption spectra that the fine structure constant α may have been measurably smaller for redshifts z>2. Analyses of other data (149Sm fission rate for the Oklo natural reactor, variation of 187Re β-decay rate in meteorite studies, atomic clock measurements) which probe variations of α in the more recent past imply much smaller deviations from its present value. In this work we tie the variation of α to the evolution of the quintessence field proposed by Albrecht and Skordis, and show that agreement with all these data, as well as consistency with Wilkinson Microwave Anisotropy Probe observations, can be achieved for a range of parameters. Some definite predictions follow for upcoming space missions searching for violations of the equivalence principle.

  8. Implications of a Time-Varying Fine Structure Constant

    CERN Document Server

    Alfonso-Faus, A

    2002-01-01

    Much work has been done after the possibility of a fine structure constant being time-varying. It has been taken as an indication of a time-varying speed of light. Here we prove that this is not the case. We prove that the speed of light may or may not vary with time, independently of the fine structure constant being constant or not. Time variations of the speed of light, if present, have to be derived by some other means and not from the fine structure constant. No implications based on the possible variations of the fine structure constant can be imposed on the speed of light.

  9. Cell fine structure and function - Past and present

    Science.gov (United States)

    Fernandez-Moran, H.

    1970-01-01

    Electron microscopic studies of nerve membrane fine structure, discussing cell membrane multienzyme and macromolecular energy and information transduction, protein synthesis and nucleic acids interrelations

  10. Fine structure of charge exchange lines observed in laboratory plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Ida, K.; Nishimura, S. [National Inst. for Fusion Science, Nagoya (Japan); Kondo, K.

    1997-01-01

    The influence of the fine structure of charge exchange lines appears only at the plasma edge or in the recombining phase where the ion temperature is low enough. The observed spectra in Li III and C VI are consistent with the sum of fine-structure components populated by statistical weights (assuming complete l-mixing) not by direct charge exchange cross sections. Some discrepancy was observed in the intensity ratio of fine-structure components between the observation and calculation for C VI in the recombining phase. The fine-structure of charge exchange lines gives an apparent Doppler shift in plasma rotation velocity measurement using charge exchange spectroscopy. (author)

  11. An Einstein-Cartan Fine Structure Constant Definition

    Directory of Open Access Journals (Sweden)

    Stone R. A. Jr.

    2010-01-01

    Full Text Available The fine structure constant definition given in Stone R.A. Jr. Progress in Physics, 2010, v.1, 11-13 is compared to an Einstein-Cartan fine structure constant definition. It is shown that the Einstein-Cartan definition produces the correct pure theory value, just not the measure value. To produce the measured value, the pure theory Einstein-Cartan fine structure constant requires only the new variables and spin coupling of the fine structure constant definition in [1].

  12. Fine velocity structures collisional dissipation in plasmas

    Science.gov (United States)

    Pezzi, Oreste; Valentini, Francesco; Veltri, Pierluigi

    2016-04-01

    In a weakly collisional plasma, such as the solar wind, collisions are usually considered far too weak to produce any significant effect on the plasma dynamics [1]. However, the estimation of collisionality is often based on the restrictive assumption that the particle velocity distribution function (VDF) shape is close to Maxwellian [2]. On the other hand, in situ spacecraft measurements in the solar wind [3], as well as kinetic numerical experiments [4], indicate that marked non-Maxwellian features develop in the three-dimensional VDFs, (temperature anisotropies, generation of particle beams, ring-like modulations etc.) as a result of the kinetic turbulent cascade of energy towards short spatial scales. Therefore, since collisional effects are proportional to the velocity gradients of the VDF, the collisionless hypothesis may fail locally in velocity space. Here, the existence of several characteristic times during the collisional relaxation of fine velocity structures is investigated by means of Eulerian numerical simulations of a spatially homogeneous force-free weakly collisional plasma. The effect of smoothing out velocity gradients on the evolution of global quantities, such as temperature and entropy, is discussed, suggesting that plasma collisionality can increase locally due to the velocity space deformation of the particle velocity distribution. In particular, by means of Eulerian simulations of collisional relaxation of a spatially homogeneous force-free plasma, in which collisions among particles of the same species are modeled through the complete Landau operator, we show that the system entropy growth occurs over several time scales, inversely proportional to the steepness of the velocity gradients in the VDF. We report clear evidences that fine velocity structures are dissipated by collisions in a time much shorter than global non-Maxwellian features, like, for example, temperature anisotropies. Moreover we indicate that, if small-scale structures

  13. The Fine Structure Lines of Hydrogen in HII Regions

    CERN Document Server

    Dennison, B; Minter, A H; Dennison, Brian; Minter, Anthony H.

    2005-01-01

    The 2s_{1/2} state of hydrogen is metastable and overpopulated in HII regions. In addition, the 2p states may be pumped by ambient Lyman-alpha radiation. Fine structure transitions between these states may be observable in HII regions at 1.1 GHz (2s_{1/2}-2p_{1/2}) and/or 9.9 GHz (2s_{1/2}-2p_{3/2}), although the details of absorption versus emission are determined by the relative populations of the 2s and 2p states. The n=2 level populations are solved with a parameterization that allows for Lyman-alpha pumping of the 2p states. The density of Lyman-alpha photons is set by their creation rate, easily determined from the recombination rate, and their removal rate. Here we suggest that the dominant removal mechanism of Lyman-alpha radiation in HII regions is absorption by dust. This circumvents the need to solve the Lyman-alpha transfer problem, and provides an upper limit to the rate at which the 2p states are populated by Lyman-alpha photons. In virtually all cases of interest, the 2p states are predominantl...

  14. Search for Possible Variation of the Fine Structure Constant

    OpenAIRE

    2003-01-01

    Determination of the fine structure constant alpha and search for its possible variation are considered. We focus on a role of the fine structure constant in modern physics and discuss precision tests of quantum electrodynamics. Different methods of a search for possible variations of fundamental constants are compared and those related to optical measurements are considered in detail.

  15. An extended anomalous fine structure of X-ray quasi-Bragg diffuse scattering from multilayers

    CERN Document Server

    Chernov, V A; Mytnichenko, S V

    2001-01-01

    An X-ray quasi-Bragg diffuse scattering anomalous fine structure technique was probed near the absorption Ni K-edge to study the interfacial structure of the Ni/C multilayer deposited by the laser ablation. Like other combinations of the EXAFS and diffraction techniques, this method has a spatial selectivity and was shown qualitatively to provide atomic structural information from the mixed interfacial layers. The possibilities and advantages of this technique are discussed.

  16. Structure of Liquid Aluminum and Hydrogen Absorption

    Institute of Scientific and Technical Information of China (English)

    LIU Yang; DAI Yongbing; WANG Jun; SHU Da; SUN Baode

    2011-01-01

    The hydrogen content in aluminum melts at different temperature was detected. The structure in aluminum melts was investigated by molecular dynamics simulation. The first peak position of pair correlation function, atomic coordination number and viscosity of aluminum melts were calculated and they changed abnormally in the same temperature range. The mechanism of hydrogen absorption has been discussed. From molecular dynamics calculations, the interdependence between melt structural properties and hydrogen absorption were obtained.

  17. Fine-Structured Plasma Flows in Prominences

    Science.gov (United States)

    Panasenco, O.; Velli, M.; Landi, S.

    2008-12-01

    Plasmas in prominences (filaments against the disk) exhibit a very wide spectrum of different kind of motions. Here we analyze the plasma motions inside prominences observed by Hinode/SOT during 2006-2007 with focus on two spectacular examples from 25 April 2007 in Halpha line and 30 November 2006 in CaH line and then carry out some simulations of the possible dynamics. Most filaments are composed of fine threads of similar dimensions rooted in the chromosphere/photosphere. Recent observations of counter-streaming motions together with oscillations along the threads provide strong evidence that the threads are field aligned. To more correctly interpret the nature of observed downward flows of dense and cool plasma as well as the upward dark flows of less dense plasma, we take into account the geometry of the prominence structures and the viewing angle. The dark upflows exhibit turbulent patterns such as vortex formation and shedding that are consistent with the motions predicted by instabilities of the interchange type. Sometimes an appearance of dark motions is generated by dark voids opened in the prominence sheet after initiation of nearby downflow streams, implying mass drainage in the downflows. Based on 304 A observations, there is more filament mass in prominences than is visible in either the Halpha or CaH lines. The source of the downward moving plasma may be located either higher above the visible upper edge of the prominence or on the far end of the prominence spine. The bright downward motions of the more cool and dense plasma may be partly due to the counter-streaming motion along the magnetic fields lines and also to the presence of Rayleigh-Taylor type or ballooning/interchange instabilities in the upper regions of the prominence. Transverse motions of filament threads caused by magnetic instabilities constantly provide the conditions for reconnection in the low part of the corona and the chromosphere. We suggest that the combination of flows along

  18. A five dimensional model of varying effective gravitational and fine structure constants

    Science.gov (United States)

    Mbelek, J. P.; Lachièze-Rey, M.

    2003-01-01

    We explore the possibility that the reported time variation of the fine structure constant alpha is due to a coupling between electromagnetism and gravitation. We predict such a coupling from a very simple effective theory of physical interactions, under the form of an improved version of the Kaluza-Klein theory. We show that it precisely leads to a variation of the effective fine structure constant with cosmic conditions, and thus with cosmic time. The comparison with the recent data from distant quasars absorption line spectra gives a good agreement; moreover, this may reconcile the claimed results on alpha with the upper limit from the Oklo naturel Uranium fission reactor.

  19. Fine Structure of Solar Acoustic Oscillations Due to Rotation

    Science.gov (United States)

    Goode, P. R.; Dziembowski, W.

    1984-01-01

    The nature of the fine structure of high order, low degree five minute period solar oscillations following from various postulated forms of spherical rotation is predicted. The first and second order effects of rotation are included.

  20. Re/Os Constraint on the Time Variability of the Fine-Structure Constant

    Science.gov (United States)

    Fujii, Yasunori; Iwamoto, Akira

    2003-12-01

    We argue that the accuracy by which the isochron parameters of the decay 187Re→187Os are determined by dating iron meteorites may constrain the possible time dependence of the decay rate and hence of the fine-structure constant α, not directly but only in a model-dependent manner. From this point of view, some of the attempts to analyze the Oklo constraint and the results of the quasistellar-object absorption lines are reexamined.

  1. Re/Os constraint on the time-variability of the fine-structure constant

    CERN Document Server

    Fujii, Y; Fujii, Yasunori; Iwamoto, Akira

    2003-01-01

    We argue that the accuracy by which the isochron parameters of the decay $^{187}{\\rm Re}\\to ^{187}{\\rm Os}$ are determined by dating iron meteorites may not directly constrain the possible time-dependence of the decay rate and hence of the fine-structure constant $\\alpha$. From this point of view, some of the attempts to analyze the Oklo constraint and the results of the QSO absorption lines are re-examined.

  2. New Constraints on Spatial Variations of the Fine Structure Constant from Clusters of Galaxies

    Directory of Open Access Journals (Sweden)

    Ivan De Martino

    2016-12-01

    Full Text Available We have constrained the spatial variation of the fine structure constant using multi-frequency measurements of the thermal Sunyaev-Zeldovich effect of 618 X-ray selected clusters. Although our results are not competitive with the ones from quasar absorption lines, we improved by a factor 10 and ∼2.5 previous results from Cosmic Microwave Background power spectrum and from galaxy clusters, respectively.

  3. Thin structured rigid body for acoustic absorption

    Science.gov (United States)

    Starkey, T. A.; Smith, J. D.; Hibbins, A. P.; Sambles, J. R.; Rance, H. J.

    2017-01-01

    We present a thin acoustic metamaterial absorber, comprised of only rigid metal and air, that gives rise to near unity absorption of airborne sound on resonance. This simple, easily fabricated, robust structure comprising a perforated metal plate separated from a rigid wall by a deeply subwavelength channel of air is an ideal candidate for a sound absorbing panel. The strong absorption in the system is attributed to the thermo-viscous losses arising from a sound wave guided between the plate and the wall, defining the subwavelength channel.

  4. Effects of cellular fine structure on scattered light pattern.

    Science.gov (United States)

    Liu, Caigen; Capjack, Clarence E

    2006-06-01

    Biological cells are complex in both morphological and biochemical structure. The effects of cellular fine structure on light scattered from cells are studied by employing a three-dimensional code named AETHER which solves the full set of Maxwell equations by using the finite-difference time-domain method. It is shown that changes in cellular fine structure can cause significant changes in the scattered light pattern over particular scattering angles. These changes potentially provide the possibility for distinguishability of cellular intrastructures. The effects that features of different intrastructure have on scattered light are discussed from the viewpoint of diagnosing cellular fine structure. Finally, we discuss scattered light patterns for lymphocyte-like cells and basophil-like cells.

  5. Determination of lead in fine particulates by slurry sampling electrothermal atomic absorption spectrometry.

    Science.gov (United States)

    Yu, J C; Ho, K F; Lee, S C

    2001-01-02

    A simple method for determining lead in fine particulates (PM2.5) by using electrothermal atomic absorption spectrometry (ETAAS) has been developed. Particulates collected on Nuclepore filter by using a dichotomous sampler were suspended in diluted nitric acid after ultrasonic agitation. The dislodging efficiency is nearly 100% after agitation for 5 min. In order to study the suspension behavior of PM2.5 in solvents, a Brookhaven ZetaPlus Particle Size Analyzer was used to determine the particle size distribution and suspension behavior of air particulates in the solvent. The pre-digestion and modification effect of nitric acid would be discussed. Palladium was added as a chemical modifier and the temperature program of ETAAS was changed in order to improve the recovery. The slurry was introduced directly into a graphite tube for atomization. The metal content in the sample was determined by the standard addition method. In addition, a conventional acid digestion procedure was applied to verify the efficiency of the slurry sampling method. It offers a quick and efficient alternative method for heavy metal characterization in fine particulates.

  6. Adding diffuse reflectance infrared Fourier transform spectroscopy capability to extended x-ray-absorption fine structure in a new cell to study solid catalysts in combination with a modulation approach

    Energy Technology Data Exchange (ETDEWEB)

    Chiarello, Gian Luca [Dipartimento di Chimica, Università degli Studi di Milano, Via C. Golgi 19, I-20133 Milano, Italy and Empa, Swiss Federal Laboratories for Materials Science and Technology, Lab. for Solid State Chemistry and Catalysis, Ueberlandstrasse 129, CH-8600 Dübendorf (Switzerland); Nachtegaal, Maarten; Marchionni, Valentina; Quaroni, Luca; Ferri, Davide, E-mail: davide.ferri@psi.ch [Paul Scherrer Institut, CH-5232 Villigen PSI (Switzerland)

    2014-07-15

    We describe a novel cell used to combine in situ transmission X-ray absorption spectroscopy (XAS) with diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) in a single experiment. The novelty of the cell design compared to current examples is that both radiations are passed through an X-ray and IR transparent window in direct contact with the sample. This innovative geometry also offers a wide surface for IR collection. In order to avoid interference from the crystalline IR transparent materials (e.g., CaF{sub 2}, MgF{sub 2}, diamond) a 500 μm carbon filled hole is laser drilled in the center of a CaF{sub 2} window. The cell is designed to represent a plug flow reactor, has reduced dead volume in order to allow for fast exchange of gases and is therefore suitable for experiments under fast transients, e.g., according to the concentration modulation approach. High quality time-resolved XAS and DRIFTS data of a 2 wt.% Pt/Al{sub 2}O{sub 3} catalyst are obtained in concentration modulation experiments where CO (or H{sub 2}) pulses are alternated to O{sub 2} pulses at 150 °C. We show that additional information can be obtained on the Pt redox dynamic under working conditions thanks to the improved sensitivity given by the modulation approach followed by Phase Sensitive Detection (PSD) analysis. It is anticipated that the design of the novel cell is likely suitable for a number of other in situ spectroscopic and diffraction methods.

  7. A new method to determine the density and water absorption of fine recycled aggregates

    Directory of Open Access Journals (Sweden)

    Fernando Rodrigues

    2013-01-01

    Full Text Available The construction industry keeps on demanding huge quantities of natural resources, mainly minerals for mortars and concrete production. The depletion of many quarries and environmental concerns about reducing the dumping of construction and demolition waste in quarries have led to an increase in the procuring and use of recycled aggregates from this type of waste. If they are to be incorporated in concrete and mortars it is essential to know their properties to guarantee the adequate performance of the end products, in both mechanical and durability-related terms. Existing regulated tests were developed for natural aggregates, however, and several problems arise when they are applied to recycled aggregates, especially fine recycled aggregates (FRA. This paper describes the main problems encountered with these tests and proposes an alternative method to determine the density and water absorption of FRA that removes them. The use of sodium hexametaphosphate solutions in the water absorption test has proven to improve its efficiency, minimizing cohesion between particles and helping to release entrained air.

  8. Intestinal absorption of specific structured triacylglycerols

    DEFF Research Database (Denmark)

    Mu, Huiling; Høy, Carl-Erik

    2001-01-01

    To clarify the intestinal absorption pathway of medium-chain fatty acids from MMM-type structured triaclyglycerols containing both medium- and long-chain fatty acids, we studied the lymphatic transport of 1,3-dioctanoyl-2-linoleoyl-sn- glycerol (8:0/18:2/8:0), 1,3-didecanoyl-2-linoleoyl...... and activated into CoA, and reacylated into triacylglycerols in the enterocyte, The hydrolysis of MLM-type STAG is predominantly partial hydrolysis, whereas part of the STAG can also be hydrolyzed to free glycerol and free fatty acids. - Mu, H., and CE. Hoy. Intestinal absorption of specific structured......-sn-glycerol (10:0/18:2/10:0), and 1,3-didodecanoyl-2-linoleoyl-sn-glycerol (12:0/18:2/12:0) in a rat model. Safflower oil was used in the absorption study in order to compare the absorption of medium- chain fatty acids and long-chain fatty acids, The triacylglycerol species of lymph Lipids were separated...

  9. Helium 23P Fine Structure Measurement in a Discharge Cell

    Science.gov (United States)

    Zelevinsky, T.; Farkas, D.; Gabrielse, G.

    2005-12-01

    A precise measurement of helium 23P fine structure was carried out in a discharge cell using Doppler-free laser spectroscopy. It is the only known experiment to directly measure all three fine structure intervals at a 1 kHz level of accuracy. The 23P1 - 23P2 interval value agrees with other experiments but disagrees with theoretical predictions of two-electron QED. When this disagreement is resolved, the 23P0 - 23P1 interval measurement reported here will allow a determination of the fine structure constant to 14 parts in 109, surpassing the precision of the well known QED-independent quantum Hall effect and Josephson effect determinations. The discharge cell is shown to be advantageous in the study and correction of systematic frequency shifts related to light pressure, and the use of the cell ensures that the possible systematic errors are substantially different from those reported in other experiments.

  10. Fine structure of fields in 2D photonic crystal waveguides

    DEFF Research Database (Denmark)

    Lavrinenko, Andrei; Volkov, V. S.; Bozhevolnyi, S. I.

    2006-01-01

    We resolve fine structure of fields in a single-row missing photonic crystal waveguide by finite-difference time-domain modelling and SNOM measurements. Both linear dispersion and slow-light regimes in proximity of the cutoff are addressed in the analysis.......We resolve fine structure of fields in a single-row missing photonic crystal waveguide by finite-difference time-domain modelling and SNOM measurements. Both linear dispersion and slow-light regimes in proximity of the cutoff are addressed in the analysis....

  11. Theory of the fine structure of auroral kilometric radiation

    Science.gov (United States)

    Grabbe, C. L.

    1982-01-01

    Recent data from ISEE 1 show auroral kilometric radiation (AKR) with finely separated bands in frequency. The observation that the AKR fine structure frequency separation is about equal to the ion cyclotron frequency at the AKR source is strong evidence for the interaction of AKR and electrostatic ion cyclotron (EIC) waves in the source, as proposed by Grabbe et al. (1980) to explain the origin of AKR. It is pointed out that no other wave of frequency close to the band separation is known to exist in the auroral source region. The fine structure observed in the source region AKR is the first evidence for EIC waves in the lower source region (3000 - 5000 km attitude), as required in the theory of Grabbe et al.

  12. FINE STRUCTURE OF RAT INTRAFUSAL MUSCLE FIBERS

    Science.gov (United States)

    Ovalle, William K.

    1972-01-01

    An ultrastructural study has been undertaken on the equatorial (sensory) region of the rat muscle spindle. Two kinds of intrafusal muscle fibers, a nuclear bag fiber and a nuclear chain fiber, have been identified in this region on the basis of fiber diameter, nuclear disposition, and M-band appearance. The large-diameter nuclear bag fiber contains an aggregation of tightly packed vesicular nuclei, while the small-diameter nuclear chain fiber contains a single row of elongated, well-separated nuclei. Both muscle fibers contain an attenuated peripheral cylinder of myofilaments surrounding a central core of sarcoplasm. Elements of the sarcotubular system, dilatations of the sarcoplasmic reticulum, and the presence of other sarcoplasmic organelles and inclusions are considerably more abundant in the nuclear chain fiber than in the nuclear bag fiber. Leptomeric organelles and membrane-bounded sarcoplasmic granules are present in both intrafusal fiber types and may be situated between the myofibrils or in intimate association with the sarcolemma. The functional significance of some of these structural findings is discussed. PMID:4257999

  13. Fine structure of plastids during androgenesis in Hordeum vulgare L.

    OpenAIRE

    Fortunat Młodzianowski; Krystyna Idzikowska

    2014-01-01

    The fine structure of plastids was studied in the course of androgenesis in in the pollen of Hordeum vulgare L. It was found that these organelles occur in all stages of androgenesis. Their structure was simple and was frequently manifested on the cross section only by the presence of the envelope and matrix of different degree of density. Single thylakoids, nucleoid-like regions and starch grains were, however, also noted. The structure of plastids in embryoids formed from microspores of bar...

  14. The Fine Structure of Equity-Index Option Dynamics

    DEFF Research Database (Denmark)

    Andersen, Torben G.; Bondarenko, Oleg; Todorov, Viktor;

    We analyze the high-frequency dynamics of S&P 500 equity-index option prices by constructing an assortment of implied volatility measures. This allows us to infer the underlying fine structure behind the innovations in the latent state variables driving the movements of the volatility surface. In...

  15. Binding energy and fine structure of the He- ion

    Institute of Scientific and Technical Information of China (English)

    ZHUO; Lin; ZHU; Jing-jing; GOU; Bing-cong

    2007-01-01

    The variational method using a multiconfiguration wavefunction is carried out on the core-excited state 1s2s2p 4P0 for helium negative ion, including mass polarization and relativistic corrections. Binding energy and fine structure are reported. The results are compared with other theoretical and experimental date in the literature.

  16. Distortion product otoacoustic emission fine structure of symphony orchestra musicians

    DEFF Research Database (Denmark)

    Reuter, Karen; Hammershøi, Dorte

    2006-01-01

    losses than pure-tone audiometry. The distortion product otoacoustic emission (DPOAE) fine structure is obtained when the ear is stiumulated by dual tone stimuli using a high frequency resolution. It is characterized by quasi-periodic variations across frequency, as it can be observed in the hearing...

  17. Distortion product otoacoustic emission fine structure of symphony orchestra musicians

    DEFF Research Database (Denmark)

    Reuter, Karen; Hammershøi, Dorte

    losses than puretone audiometry. The distortion product otoacoustic emission (DPOAE) fine structure is obtained when the ear is stimulated by dual tone stimuli using a high frequency resolution. It is characterized by quasi-periodic variations across frequency, as it can be observed in the hearing...

  18. Mathematical description of SO/sub 2/ absorption in an aqueous suspension of finely powdered limestone

    Energy Technology Data Exchange (ETDEWEB)

    Biba, V.; Hrncir, J.; Vejvoda, J.

    1978-01-01

    A mathematical model has been proposed that characterizes the course of SO/sub 2/ absorption in a bubble reactor filled by a suspension of finely powdered limestone. The agreement between the experimental results and the calculated course of the output SO/sub 2/ concentration shows that the model represents a useful basis for the description of the studied process. However, as the model has been so far verified only on one sample at a single temperature and for only one grain composition, the results obtained can be considered only as the first step in the modelling of the process. Experiments performed under different condition of temperature, grain composition and with different types of limestone, and/or some further additions to the reaction scheme involved (e.g., the dissociation of carbonates) are needed to make the model more accurate. The results so far obtained represent thus a contribution to the approximation of the fundamental theory of processes that take place in the wet limestone technology of desulphurization of combustion gases.

  19. Coherent perfect absorption in photonic structures

    CERN Document Server

    Baldacci, Lorenzo; Tredicucci, Alessandro

    2016-01-01

    The ability to drive a system with an external input is a fundamental aspect of light-matter interaction. The coherent perfect absorption (CPA) phenomenon extends to the general multibeam interference phenomenology the well known critical coupling concepts. This interferometric control of absorption can be employed to reach full delivery of optical energy to nanoscale systems such as plasmonic nanoparticles, and multi-port interference can be used to enhance the absorption of a nanoscale device when it is embedded in a strongly scattering system, with potential applications to nanoscale sensing. Here we review the two-port CPA in reference to photonic structures which can resonantly couple to the external fields. A revised two-port theory of CPA is illustrated, which relies on the Scattering Matrix formalism and is valid for all linear two-port systems with reciprocity. Through a semiclassical approach, treating two-port critical coupling conditions in a non-perturbative regime, it is demonstrated that the st...

  20. Precision Measurements: Testing the Time Variation of the Fine Structure Constant

    Science.gov (United States)

    Lamoreaux, Steve

    2004-05-01

    Often, precision measurements from diverse fields can be used to learn new facts about the universe. The usual definition of "precision" is based on improvements over previous measurements. A review of the present state of knowledge regarding the possible time variation of the fine structure constant α will be presented; "precise" data from natural phenomena, which include an apparent shift in the red-shift-scaled fine structure in the absorption spectra of quasar light, and the isotopic abundances in the fission products of a prehistoric natural reactor in Oklo, Gabon. Prospects to improve the accuracy for the constancy of α with laboratory experiments will be discussed. Our two experimental investigations currently being developed are based on optical spectroscopy of trapped ions and on radiofrequency spectroscopy of an atomic dysprosium beam. A sensitivity of dotα/α≈ 10-18/yr is anticipated. Because this accuracy exceeds that by which the second is defined, these measurements will necessarily be differential.

  1. A five dimensional model of varying effective gravitational and fine structure constants

    CERN Document Server

    Mbelek, J P

    2003-01-01

    We explore the possibility that the reported time variation of the fine structure constant $\\alpha$ is due to a coupling between electromagnetism and gravitation. We consider the coupling predicted by a very simple {\\sl effective} theory of physical interactions, under the form of an improved version of the Kaluza-Klein theory. We show that it is precisely expressed by a variation of the effective fine structure constant with cosmic conditions, and thus with cosmic time. We compare the predicted variation with the recent data from distant quasars absorption line spectra: we find a good agreement, which moreover reconcile the claimed results on $\\alpha$ with the upper limit from the Oklo naturel Uranium fission reactor.

  2. How Strongly does Dating Meteorites Constrain the Time-Dependence of the Fine-Structure Constant?

    Science.gov (United States)

    Fujii, Yasunori; Iwamoto, Akira

    We review our argument on the nature of the so-called meteorite constraint on the possible time-dependence of the fine-structure constant, emphasizing that dating meteorites at the present time is different in principle from searching directly for the traces in the past, as in the Oklo phenomenon and the QSO absorption lines. In the related literature, we still find some arguments not necessarily consistent with this difference to be taken properly into account. It does not immediately follow that any model-dependent approaches are useless in practice, though we cannot help suspecting that dating meteorites is no match for the Oklo and the QSO in probing the time-variability of the fine-structure constant, at this moment. Some of the relevance to the QSO data particularly in terms of the scalar field will be discussed.

  3. Constraints on field theoretical models for variation of the fine structure constant

    Science.gov (United States)

    Steinhardt, Charles L.

    2005-02-01

    Recent theoretical ideas and observational claims suggest that the fine structure constant α may be variable. We examine a spectrum of models in which α is a function of a scalar field. Specifically, we consider three scenarios: oscillating α, monotonic time variation of α, and time-independent α that is spatially varying. We examine the constraints imposed upon these theories by cosmological observations, particle detector experiments, and “fifth force” experiments. These constraints are very strong on models involving oscillation but cannot compete with bounds from the Oklo subnuclear reactor on models with monotonic timelike variation of α. One particular model with spatial variation is consistent with all current experimental and observational measurements, including those from two seemingly conflicting measurements of the fine structure constant using the many multiplet method on absorption lines.

  4. How strongly does dating meteorites constrain the time-dependence of the fine-structure constant?

    CERN Document Server

    Fujii, Y; Fujii, Yasunori; Iwamoto, Akira

    2005-01-01

    We review our argument on the nature of the so-called meteorite constraint on the possible time-dependence of the fine-structure constant, emphasizing that dating meteorites at the present time is different in principle from searching directly for the traces in the past, as in the Oklo phenomenon and the QSO absorption lines. In the related literature, we still find some arguments not necessarily consistent with this difference to be taken properly into account. This does not imply that any of the model-dependent approaches are useless in practice, though we cannot help guessing that dating meteorites is no match for the Oklo and the QSO in probing time-dependence of the fine-structure constant, at this moment. Some of the relevance to the QSO data particularly in terms of the scalar field will be discussed.

  5. The local structure and optical absorption characteristic investigation on Fe doped TiO2 nanoparticles

    CERN Document Server

    Zhao, Tianxing; Huang, Junheng; He, Jinfu; Liu, Qinghua; Pan, Zhiyun; Wu, Ziyu

    2014-01-01

    The local structures and optical absorption characteristic of Fe doped TiO2 nanoparticles synthesized by the sol-gel method were characterized by X-ray Diffraction (XRD), X-ray absorption fine structure spectroscopy (XAFS) and UV-Vis absorption spectroscopy (UV-Vis). XRD patterns show that all Fe-doped TiO2 samples have the characteristic anatase structure. Accurate Fe and Ti K-edge EXAFS analysis further reveal that all Fe atoms replace Ti atoms in the anatase lattice. The analysis of UV-Vis data shows a red shift to the visible range. According to the above results, we claim that substitutional Fe atoms lead to the formation of structural defects and new intermediate energy levels appear, narrowing the band gap and extending the optical absorption edge towards the visible region.

  6. Investigation of fine and complex vortex circulation structures

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    The formation and evolution of fine and complicated vortex circulation structures were investigated using a two-dimensional quasi-geostrophic barotropic model simulation.We find that the highly localized asymmetric and complex configuration of energy transfer flux between large-and small-scale components is caused by the nonlinear interaction between a large-scale vortex with an initial axi-symmetric flow and four beta meso-scale vortices.The complex structure is characterized by a fine pattern,which contains seven closed systems with spatial scales of less than 100 km,embedded in a positive flux wave train and a negative wave train,respectively.The average wind speed decreased with time in the positive flux region,but was nearly unchanged in the negative flux region.This pattern reveals the evolutionary asymmetry and localization of wind speed of the major vortex.The track of the major vortex center has a trend toward the center of the negative flux center,indicating that there is a certain relation between the complex structure of the energy transfer flux and the motion of the major vortex center.These results imply that the formation and evolution of the fine and complex structure should be attributed to the nonlinear interaction between the vortices at different spatial scales.

  7. Metallicity Diagnostics with Infrared Fine-Structure Lines

    CERN Document Server

    Nagao, Tohru; Marconi, Alessandro; Matsuhara, Hideo

    2010-01-01

    Although measuring the gas metallicity in galaxies at various redshifts is crucial to constrain galaxy evolutionary scenarios, only rest-frame optical emission lines have been generally used to measure the metallicity. This has prevented us to accurately measure the metallicity of dust-obscured galaxies, and accordingly to understand the chemical evolution of dusty populations, such as ultraluminous infrared galaxies. Here we propose diagnostics of the gas metallicity based on infrared fine structure emission lines, which are nearly unaffected by dust extinction even the most obscured systems. Specifically, we focus on fine-structure lines arising mostly from HII regions, not in photo-dissociation regions, to minimize the dependence and uncertainties of the metallicity diagnostics from various physical parameters. Based on photoionization models, we show that the emission-line flux ratio of ([OIII]51.80+[OIII]88.33)/[NIII]57.21 is an excellent tracer of the gas metallicity. The individual line ratios [OIII]51...

  8. Simple Model with Time-Varying Fine-Structure ``Constant''

    Science.gov (United States)

    Berman, M. S.

    2009-10-01

    Extending the original version written in colaboration with L.A. Trevisan, we study the generalisation of Dirac's LNH, so that time-variation of the fine-structure constant, due to varying electrical and magnetic permittivities is included along with other variations (cosmological and gravitational ``constants''), etc. We consider the present Universe, and also an inflationary scenario. Rotation of the Universe is a given possibility in this model.

  9. Possible Cosmological Implications of Time Varying Fine Structure Constant

    CERN Document Server

    Berman, M S; Berman, Marcelo S.; Trevisan, Luis A.

    2001-01-01

    We make use of Dirac LNH and results for a time varying fine structure constant in order to derive possible laws of variation for speed of light, the number of nucleons in the Universe, energy density and gravitational constant. By comparing with experimental bounds on G variation, we find that the deceleration paramenter of the present Universe is negative. This is coherent with recent Supernovae observations.

  10. Oklo Constraint on the Time-Variabilityof the Fine-Structure Constant

    Science.gov (United States)

    Fujii, Yasunori

    The Oklo phenomenon, natural fission reactors which had taken place in Gabon about 2 billion years ago, provides one of the most stringent constraints on the possible time-variability of the fine-structure constant . We first review briefly what it is and how reliable it is in constraining . We then compare the result with a more recent result on the nonzero change of obtained from the observation of the QSO absorption lines. We suggest a possible way to make these results consistent with each other in terms of the behavior of a scalar field which is expected to be responsible for the acceleration of the universe.

  11. Study of the inner structure of fine coal filter cake

    Energy Technology Data Exchange (ETDEWEB)

    Shi Chang-sheng; Xie Guang-yuan; Zhang Yue-qiu [China University of Mining & Technology, Xuzhou (China). School of Environmental Sciences and Spatial Informatics

    2006-07-01

    The dewatering of fine coal in coal processing is very important. Based on the theories of dewatering, the inner structure of the filter cake was analyzed using the scanning-electron microscope. The porosity, the maximal diameter of voids and the average area of voids were analyzed in detail. Genuine causes influencing final moisture of the cake were identified. The results show that the porosity of the filter cake increased from 3.87 % to 15.46 % with the increasing of size of fine coal from 0.045 mm to 0.5 mm, and the average area of the void increased from 2.14{mu}m{sup 2} to 8.24 {mu}m{sup 2}. 8 refs., 8 figs., 5 tabs.

  12. Fine-Scale Filamentary Structure in Coronal Streamers

    Science.gov (United States)

    Woo, Richard; Armstrong, John W.; Bird, Michael K.; Paetzold, Martin

    1995-01-01

    Doppler scintillation measurements of a coronal streamer lasting several solar rotations have been conducted by Ulysses in 1991 over a heliocentric distance range of 14-77 R(sub 0). By showing that the solar corona is filamentary, and that Doppler frequency is the radio counterpart of white-light eclipse pictures processed to enhance spatial gradients, it is demonstrated that Doppler scintillation measurements provide the high spatial resolution that has long eluded white-light coronagraph measurements. The region of enhanced scintillation, spanning an angular extent of 1.8 deg in heliographic longitude, coincides with the radially expanding streamer stalk and represents filamentary structure with scale sizes at least as small as 340 km (0.5 sec) when extrapolated to the Sun. Within the stalk of the streamer, the fine-scale structure corresponding to scale sizes in the range of 20-340 km at the Sun and associated with closed magnetic fields amounts to a few percent of the mean density, while outside the stalk, the fine-scale structure associated with open fields is an order of magnitude lower. Clustering of filamentary structure that takes place within the stalk of the streamer is suggestive of multiple current sheets. Comparison with ISEE 3 in situ plasma measurements shows that significant evolution resulting from dynamic interaction with increasing heliocentric distance takes place by the time streamers reach Earth orbit.

  13. The fine structure line deficit in S 140

    CERN Document Server

    Ossenkopf, Volker; Okada, Yoko; Mookerjea, Bhaswati; van der Tak, Floris F S; Simon, Robert; Pütz, Patrick; Güsten, Rolf

    2015-01-01

    We try to understand the gas heating and cooling in the S 140 star forming region by spatially and spectrally resolving the distribution of the main cooling lines with GREAT/SOFIA. We mapped the fine structure lines of [OI] (63 {\\mu}m) and [CII] (158 {\\mu}m) and the rotational transitions of CO 13-12 and 16-15 with GREAT/SOFIA and analyzed the spatial and velocity structure to assign the emission to individual heating sources. We measure the optical depth of the [CII] line and perform radiative transfer computations for all observed transitions. By comparing the line intensities with the far-infrared continuum we can assess the total cooling budget and measure the gas heating efficiency. The main emission of fine structure lines in S 140 stems from a 8.3'' region close to the infrared source IRS 2 that is not prominent at any other wavelength. It can be explained by a photon-dominated region (PDR) structure around the embedded cluster if we assume that the [OI] line intensity is reduced by a factor seven due ...

  14. Topological Quantization in Units of the Fine Structure Constant

    Energy Technology Data Exchange (ETDEWEB)

    Maciejko, Joseph; /Stanford U., Phys. Dept. /Stanford U., Materials Sci. Dept. /SLAC; Qi, Xiao-Liang; /Station Q, UCSB /Stanford U., Phys. Dept. /Stanford U., Materials Sci. Dept. /SLAC; Drew, H.Dennis; /Maryland U.; Zhang, Shou-Cheng; /Stanford U., Phys. Dept. /Stanford U., Materials Sci. Dept. /SLAC

    2011-11-11

    Fundamental topological phenomena in condensed matter physics are associated with a quantized electromagnetic response in units of fundamental constants. Recently, it has been predicted theoretically that the time-reversal invariant topological insulator in three dimensions exhibits a topological magnetoelectric effect quantized in units of the fine structure constant {alpha} = e{sup 2}/{h_bar}c. In this Letter, we propose an optical experiment to directly measure this topological quantization phenomenon, independent of material details. Our proposal also provides a way to measure the half-quantized Hall conductances on the two surfaces of the topological insulator independently of each other.

  15. Urban, Forest, and Agricultural AIS Data: Fine Spectral Structure

    Science.gov (United States)

    Vanderbilt, V. C.

    1985-01-01

    Spectra acquired by the Airborne Imaging Spectrometer (AIS) near Lafayette, IN, Ely, MN, and over the Stanford University campus, CA were analyzed for fine spectral structure using two techniques: the ratio of radiance of a ground target to the radiance of a standard and also the correlation coefficient of radiances at adjacent wavelengths. The results show ramp like features in the ratios. These features are due to the biochemical composition of the leaf and to the optical scattering properties of its cuticle. The size and shape of the ramps vary with ground cover.

  16. Fine-structure constant constraints on Bekenstein-type models

    CERN Document Server

    Leal, P M M; Ventura, L B

    2014-01-01

    Astrophysical tests of the stability of dimensionless fundamental couplings, such as the fine-structure constant $\\alpha$, are an area of much increased recent activity, following some indications of possible spacetime variations at the few parts per million level. Here we obtain updated constraints on the Bekenstein-Sandvik-Barrow-Magueijo model, which is arguably the simplest model allowing for $\\alpha$ variations. Recent accurate spectroscopic measurements allow us to improve previous constraints by about an order of magnitude. We briefly comment on the dependence of the results on the data sample, as well as on the improvements expected from future facilities.

  17. Emission wavelength tuning of fluorescence by fine structural control of optical metamaterials with Fano resonance

    Science.gov (United States)

    Moritake, Y.; Kanamori, Y.; Hane, K.

    2016-09-01

    We demonstrated fine emission wavelength tuning of quantum dot (QD) fluorescence by fine structural control of optical metamaterials with Fano resonance. An asymmetric-double-bar (ADB), which was composed of only two bars with slightly different bar lengths, was used to obtain Fano resonance in the optical region. By changing the short bar length of ADB structures with high dimensional accuracy in the order of 10 nm, resonant wavelengths of Fano resonance were controlled from 1296 to 1416 nm. Fluorescence of QDs embedded in a polymer layer on ADB metamaterials were modified due to coupling to Fano resonance and fine tuning from 1350 to 1376 nm was observed. Wavelength tuning of modified fluorescence was reproduced by analysis using absorption peaks of Fano resonance. Tuning range of modified fluorescence became narrow, which was interpreted by a simple Gaussian model and resulted from comparable FWHM in QD fluorescence and Fano resonant peaks. The results will help the design and fabrication of metamaterial devices with fluorophores such as light sources and biomarkers.

  18. Emission wavelength tuning of fluorescence by fine structural control of optical metamaterials with Fano resonance.

    Science.gov (United States)

    Moritake, Y; Kanamori, Y; Hane, K

    2016-09-13

    We demonstrated fine emission wavelength tuning of quantum dot (QD) fluorescence by fine structural control of optical metamaterials with Fano resonance. An asymmetric-double-bar (ADB), which was composed of only two bars with slightly different bar lengths, was used to obtain Fano resonance in the optical region. By changing the short bar length of ADB structures with high dimensional accuracy in the order of 10 nm, resonant wavelengths of Fano resonance were controlled from 1296 to 1416 nm. Fluorescence of QDs embedded in a polymer layer on ADB metamaterials were modified due to coupling to Fano resonance and fine tuning from 1350 to 1376 nm was observed. Wavelength tuning of modified fluorescence was reproduced by analysis using absorption peaks of Fano resonance. Tuning range of modified fluorescence became narrow, which was interpreted by a simple Gaussian model and resulted from comparable FWHM in QD fluorescence and Fano resonant peaks. The results will help the design and fabrication of metamaterial devices with fluorophores such as light sources and biomarkers.

  19. Thermal stability analysis of the fine structure of solar prominences

    Science.gov (United States)

    Demoulin, Pascal; Malherbe, Jean-Marie; Schmieder, Brigitte; Raadu, Mickael A.

    1986-01-01

    The linear thermal stability of a 2D periodic structure (alternatively hot and cold) in a uniform magnetic field is analyzed. The energy equation includes wave heating (assumed proportional to density), radiative cooling and both conduction parallel and orthogonal to magnetic lines. The equilibrium is perturbed at constant gas pressure. With parallel conduction only, it is found to be unstable when the length scale 1// is greater than 45 Mn. In that case, orthogonal conduction becomes important and stabilizes the structure when the length scale is smaller than 5 km. On the other hand, when the length scale is greater than 5 km, the thermal equilibrium is unstable, and the corresponding time scale is about 10,000 s: this result may be compared to observations showing that the lifetime of the fine structure of solar prominences is about one hour; consequently, our computations suggest that the size of the unresolved threads could be of the order of 10 km only.

  20. Fine structure of plastids during androgenesis in Hordeum vulgare L.

    Directory of Open Access Journals (Sweden)

    Fortunat Młodzianowski

    2014-01-01

    Full Text Available The fine structure of plastids was studied in the course of androgenesis in in the pollen of Hordeum vulgare L. It was found that these organelles occur in all stages of androgenesis. Their structure was simple and was frequently manifested on the cross section only by the presence of the envelope and matrix of different degree of density. Single thylakoids, nucleoid-like regions and starch grains were, however, also noted. The structure of plastids in embryoids formed from microspores of barley was compared with embryos developed from fertilized egg cell, and we did not found any fundamental differences between them. However, only plastid ribosomes were difficult to identify on ultrathin sections in embryoids and in the embryos.

  1. `Fingerprint' Fine Structure in the Solar Decametric Radio Spectrum Solar Physics

    Science.gov (United States)

    Zlotnik, E. Y.; Zaitsev, V. V.; Melnik, V. N.; Konovalenko, A. A.; Dorovskyy, V. V.

    2015-07-01

    We study a unique fine structure in the dynamic spectrum of the solar radio emission discovered by the UTR-2 radio telescope (Kharkiv, Ukraine) in the frequency band of 20 - 30 MHz. The structure was observed against the background of a broadband type IV radio burst and consisted of parallel drifting narrow bands of enhanced emission and absorption on the background emission. The observed structure differs from the widely known zebra pattern at meter and decimeter wavelengths by the opposite directions of the frequency drift within a single stripe at a given time. We show that the observed properties can be understood in the framework of the radiation mechanism by virtue of the double plasma resonance effect in a nonuniform coronal magnetic trap. We propose a source model providing the observed frequency drift of the stripes.

  2. Herschel Galactic plane survey of [NII] fine structure emission

    CERN Document Server

    Goldsmith, Paul F; Langer, William D; Pineda, Jorge L

    2015-01-01

    We present the first large scale high angular resolution survey of ionized nitrogen in the Galactic Plane through emission of its two fine structure transitions ([NII]) at 122 $\\mu$m and 205 $\\mu$m. The observations were largely obtained with the PACS instrument onboard the Herschel Space Observatory. The lines-of-sight were in the Galactic plane, following those of the Herschel OTKP project GOT C+. Both lines are reliably detected at the 10$^{-8}$ - 10$^{-7}$ $W$m$^{-2}$sr$^{-1}$ level over the range -60$^{o}$ $\\leq$ $l$ $\\leq$ 60$^{o}$. The $rms$ of the intensity among the 25 PACS spaxels of a given pointing is typically less than one third of the mean intensity, showing that the emission is extended. [NII] is produced in gas in which hydrogen is ionized, and collisional excitation is by electrons. The ratio of the two fine structure transitions provides a direct measurement of the electron density, yielding $n(e)$ largely in the range 10 to 50 cm$^{-3}$ with an average value of 29 cm$^{-3}$ and N$^+$ colum...

  3. QED Based Calculation of the Fine Structure Constant

    Energy Technology Data Exchange (ETDEWEB)

    Lestone, John Paul [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-10-13

    Quantum electrodynamics is complex and its associated mathematics can appear overwhelming for those not trained in this field. Here, semi-classical approaches are used to obtain a more intuitive feel for what causes electrostatics, and the anomalous magnetic moment of the electron. These intuitive arguments lead to a possible answer to the question of the nature of charge. Virtual photons, with a reduced wavelength of λ, are assumed to interact with isolated electrons with a cross section of πλ2. This interaction is assumed to generate time-reversed virtual photons that are capable of seeking out and interacting with other electrons. This exchange of virtual photons between particles is assumed to generate and define the strength of electromagnetism. With the inclusion of near-field effects the model presented here gives a fine structure constant of ~1/137 and an anomalous magnetic moment of the electron of ~0.00116. These calculations support the possibility that near-field corrections are the key to understanding the numerical value of the dimensionless fine structure constant.

  4. Black Holes and Quantum Theory: The Fine Structure Constant Connection

    Directory of Open Access Journals (Sweden)

    Cahill R. T.

    2006-10-01

    Full Text Available The new dynamical theory of space is further confirmed by showing that the effective “black hole” masses M BH in 19 spherical star systems, from globular clusters to galaxies, with masses M , satisfy the prediction that M BH = α 2 M , where α is the fine structure constant. As well the necessary and unique generalisations of the Schr ̈ odinger and Dirac equations permit the first derivation of gravity from a deeper theory, showing that gravity is a quantum effect of quantum matter interacting with the dynamical space. As well the necessary generalisation of Maxwell’s equations displays the observed light bending effects. Finally it is shown from the generalised Dirac equation where the spacetime mathematical formalism, and the accompanying geodesic prescription for matter trajectories, comes from. The new theory of space is non-local and we see many parallels between this and quantum theory, in addition to the fine structure constant manifesting in both, so supporting the argument that space is a quantum foam system, as implied by the deeper information-theoretic theory known as Process Physics. The spatial dynamics also provides an explanation for the “dark matter” effect and as well the non-locality of the dynamics provides a mechanism for generating the uniformity of the universe, so explaining the cosmological horizon problem.

  5. Solar Radio Bursts with Spectral Fine Structures in Preflares

    CERN Document Server

    Zhang, Yin; Karlický, Marian; Mészárosová, Hana; Huang, Jing; Tan, Chengming; Simões, Paulo

    2014-01-01

    A good observation of preflare activities is important for us to understand the origin and triggering mechanism of solar flares, and to predict the occurrence of solar flares. This work presents the characteristics of microwave spectral fine structures as preflare activities of four solar flares observed by Ond\\v{r}ejov radio spectrograph in the frequency range of 0.8--2.0 GHz. We found that these microwave bursts which occurred 1--4 minutes before the onset of flares have spectral fine structures with relatively weak intensities and very short timescales. They include microwave quasi-periodic pulsations (QPP) with very short period of 0.1-0.3 s and dot bursts with millisecond timescales and narrow frequency bandwidths. Accompanying these microwave bursts, there are filament motions, plasma ejection or loop brightening on the EUV imaging observations and non-thermal hard X-ray emission enhancements observed by RHESSI. These facts may reveal certain independent non-thermal energy releasing processes and partic...

  6. Effect of fine solid particles on absorption rate of gaseous CO2

    Institute of Scientific and Technical Information of China (English)

    Sumin LU; Youguang MA; Shuhua SHEN; Chunying ZHU

    2008-01-01

    The influence of the properties of solid particles in slurry on the absorption of CO2 in the slurry was inves-tigated in a stirred thermostatic reactor. The absorption experiments were carried out in three different slurries con-sisting of water, cyclohexane and soybean oil, respectively, and three kinds of solid particles (active carbon, active alu-mina and silica gel) were incorporated into each of the above mentioned slurries separately. The experimental results show that the active carbon particles could enhance the absorption rate of gaseous CO2 in the aqueous slurry, while in the cyclohexane slurry, active carbon particles indi-cated no the absorption enhancement effect. However, it was observed that the active alumina and silica gel particles could enhance the absorption rate of CO2 in the cyclohex-ane slurry. These phenomena indicate that the solid part-icles, which could enhance the gaseous CO2 absorption rate, should possess two properties simultaneously, i.e. they rejected the solvent and had higher adsorption capacity for the solute. The experimental results also show that, as for those solid particles which could enhance the gas absorption rate, the enhancement increased quickly with the increase of solid concentration in slurry at first, and then reached a constant value gradually. It was also found that the enhancement factor was related to the coverage fraction of solid particles on the gas-liquid interface, and due to the reduction of surface fraction with increasing stirred speed, the enhancement factor decreased.

  7. Composite Sandwich Structures for Shock Mitigation and Energy Absorption

    Science.gov (United States)

    2016-06-28

    June 29, 2016 Grant Title: Composite Sandwich Structures for Shock Mitigation and Energy Absorption Grant Number: NOOO 14-11-1-0485 Principal...NUMBER Composite Sandwich Structures for Shock Mitigation and Energy Absorption Sb. GRANT NUMBER N00014-11 -1-0485 Sc. PROGRAM ELEMENT NUMBER 6...foam cores offered greater blast resistance and energy absorption than the heavier and stronger foam cores. This was found to be the case even on an

  8. Surface structure of CdSe Nanorods revealed by combined X-rayabsorption fine structure measurements and ab-initio calculations

    Energy Technology Data Exchange (ETDEWEB)

    Aruguete, Deborah A.; Marcus, Matthew A.; Li, Liang-shi; Williamson, Andrew; Fakra, Sirine; Gygi, Francois; Galli, Giulia; Alivisatos, A. Paul

    2006-01-27

    We report orientation-specific, surface-sensitive structural characterization of colloidal CdSe nanorods with extended X-ray absorption fine structure spectroscopy and ab-initio density functional theory calculations. Our measurements of crystallographically-aligned CdSe nanorods show that they have reconstructed Cd-rich surfaces. They exhibit orientation-dependent changes in interatomic distances which are qualitatively reproduced by our calculations. These calculations reveal that the measured interatomic distance anisotropy originates from the nanorod surface.

  9. TEM and HREM study on the fine structure and the interfacial structure of bainite

    Institute of Scientific and Technical Information of China (English)

    李凤照; 敖青; 顾英妮; 姜江; 孙东升; 戴吉岩; 彭红樱

    1996-01-01

    The fine structure of bainite,the morphology and distribution of carbide in steels and the morphology of bainite in Cu-Zn-Al alloys have been investigated with TEM.The interfacial structure ledges and interfacial crystal lattice images of Cu-Zn-Al alloys have also been investigated with HREM.The addition of alloying microelements can fine the structure of bainitic ferrite markedly.The bainitic ferrite is composed of subunits or subchunks.The carbides differ in morphologies and are distributed in between laths,inside the plates and on the boundaries of subunits.There are abundant fine structures in bainitic ferrite.In the primary bainite of Cu-Zn-Al alloy there are interfacial structure ledges,the height of which is about 3 -40 nm,equal to 15-200 atomic layers.The phase transformation mechanism of bainite is discussed.

  10. Atomic Clocks and Variations of the FIne Structure Constant

    Science.gov (United States)

    Prestage, John D.; Tjoelker, Robert L.; Maleki, Lute

    1995-01-01

    We describe a new test for possible variations of the fine structure constant alpha by comparisons of rates between clocks based on hyperfine transitions in alkali atoms with different atomic number Z. H-maser, Cs, and Hg(+) clocks have a different dependence on alpha via relativistic contributions of order (Z-alpha)(sup 2). Recent H-maser vs Hg(+) clock comparison data improve laboratory limits on a time variation by 100-fold to give dot-alpha less than or equal to 3.7 x 10(exp -14)/yr. Future laser cooled clocks (Be(+), Rb, Cs, Hg(+), etc.), when compared, will yield the most sensitive of all tests for dot-alpha/alpha.

  11. Nonlinear Electrodynamics Analysis Of The Fine Structure Constant

    Science.gov (United States)

    Mbelek, Jean Paul

    2010-10-01

    It has been claimed that during the late time history of our universe, the fine structure constant, α, has been increasing [1],[2]. However, other teams has claimed a discordant result [3],[4]. Also, the current precision of laboratory tests is not sufficient to either comfort or reject any of these astronomical observations. Here we suggest that a nonlinear electrodynamics (NLED) interaction of photons with the weak local background magnetic fields of a gas cloud absorber can reconcile the null result of refs.[3] and [4] with the negative variation found by refs. [2] and [1] and also to find a bridge with the positive variation found later by Levshakov et al.. [5]-[7]. Moreover, NLED photon propagation in a vacuum permeated by a background magnetic field is actually in full agreement with constraints from Oklo natural reactor data.

  12. Varying Fine-Structure Constant and the Cosmological Constant Problem

    CERN Document Server

    Fujii, Y

    2003-01-01

    We start with a brief account of the latest analysis of the Oklo phenomenon providing the still most stringent constraint on time-variability of the fine- structure constant $\\alpha$. Comparing this with the recent result from the measurement of distant QSO's appears to indicate a non-uniform time-dependence, which we argue to be related to another recent finding of the accelerating universe. This view is implemented in terms of the scalar-tensor theory, applied specifically to the small but nonzero cosmological constant. Our detailed calculation shows that these two phenomena can be understood in terms of a common origin, a particular behavior of the scalar field, dilaton. We also sketch how this theoretical approach makes it appropriate to revisit non- Newtonian gravity featuring small violation of Weak Equivalence Principle at medium distances.

  13. Varying Fine-Structure Constant and the Cosmological Constant Problem

    Science.gov (United States)

    Fujii, Yasunori

    We start with a brief account of the latest analysis of the Oklo phenomenon providing the still most stringent constraint on time variability of the fine-structure constant α. Comparing this with the recent result from the measurement of distant QSO's appears to indicate a non-uniform time-dependence, which we argue to be related to another recent finding of the accelerating universe. This view is implemented in terms of the scalar-tensor theory, applied specifically to the small but nonzero cosmological constant. Our detailed calculation shows that these two phenomena can be understood in terms of a common origin, a particular behavior of the scalar field, dilaton. We also sketch how this theoretical approach makes it appropriate to revisit non-Newtonian gravity featuring small violation of Weak Equivalence Principle at medium distances.

  14. Varying Fine Structure Constant and Black Hole Physics

    CERN Document Server

    Das, S; Das, Saurya; Kunstatter, Gabor

    2003-01-01

    Recent astrophysical observations suggest that the fine structure constant $\\alpha=e^2/\\hbar c$ may be slowly increasing with time. This may be due to an increase of $e$ or a decrease of $c$, or both. In this article, we argue from model independent considerations that this variation should be considered adiabatic. Then, we examine in detail the consequences of such an adiabatic variation in the context of a specific model of quantized charged black holes. We find that the second law of black hole thermodynamics is obeyed, regardless of the origin of the variation, and that interesting constraints arise on the charge and mass of black holes. Finally, we estimate the work done on a black hole of mass $M$ due to the $\\alpha$ variation.

  15. Measurement of the Running of the Fine-Structure Constant

    CERN Document Server

    Acciarri, M; Adriani, O; Aguilar-Benítez, M; Alcaraz, J; Alemanni, G; Allaby, James V; Aloisio, A; Alviggi, M G; Ambrosi, G; Anderhub, H; Andreev, V P; Angelescu, T; Anselmo, F; Arefev, A; Azemoon, T; Aziz, T; Bagnaia, P; Baksay, L; Balandras, A; Ball, R C; Banerjee, S; Banerjee, Sw; Barczyk, A; Barillère, R; Barone, L; Bartalini, P; Basile, M; Battiston, R; Bay, A; Becattini, F; Becker, U; Behner, F; Bellucci, L; Berdugo, J; Berges, P; Bertucci, B; Betev, B L; Bhattacharya, S; Biasini, M; Biland, A; Blaising, J J; Blyth, S C; Bobbink, Gerjan J; Böhm, A; Boldizsar, L; Borgia, B; Bourilkov, D; Bourquin, Maurice; Braccini, S; Branson, J G; Brigljevic, V; Brochu, F; Buffini, A; Buijs, A; Burger, J D; Burger, W J; Button, A M; Cai, X D; Campanelli, M; Capell, M; Cara Romeo, G; Carlino, G; Cartacci, A M; Casaus, J; Castellini, G; Cavallari, F; Cavallo, N; Cecchi, C; Cerrada-Canales, M; Cesaroni, F; Chamizo-Llatas, M; Chang, Y H; Chaturvedi, U K; Chemarin, M; Chen, A; Chen, G; Chen, G M; Chen, H F; Chen, H S; Chiefari, G; Cifarelli, Luisa; Cindolo, F; Civinini, C; Clare, I; Clare, R; Coignet, G; Colijn, A P; Colino, N; Costantini, S; Cotorobai, F; Cozzoni, B; de la Cruz, B; Csilling, Akos; Cucciarelli, S; Dai, T S; van Dalen, J A; D'Alessandro, R; De Asmundis, R; Déglon, P L; Degré, A; Deiters, K; Della Volpe, D; Denes, P; De Notaristefani, F; De Salvo, A; Diemoz, M; Van Dierendonck, D N; Di Lodovico, F; Dionisi, C; Dittmar, Michael; Dominguez, A; Doria, A; Dova, M T; Duchesneau, D; Dufournaud, D; Duinker, P; Durán, I; El-Mamouni, H; Engler, A; Eppling, F J; Erné, F C; Extermann, Pierre; Fabre, M; Faccini, R; Falagán, M A; Falciano, S; Favara, A; Fay, J; Fedin, O; Felcini, Marta; Ferguson, T; Ferroni, F; Fesefeldt, H S; Fiandrini, E; Field, J H; Filthaut, Frank; Fisher, P H; Fisk, I; Forconi, G; Fredj, L; Freudenreich, Klaus; Furetta, C; Galaktionov, Yu; Ganguli, S N; García-Abia, P; Gataullin, M; Gau, S S; Gentile, S; Gheordanescu, N; Giagu, S; Gong, Z F; Grenier, G; Grimm, O; Grünewald, M W; Guida, M; van Gulik, R; Gupta, V K; Gurtu, A; Gutay, L J; Haas, D; Hasan, A; Hatzifotiadou, D; Hebbeker, T; Hervé, A; Hidas, P; Hirschfelder, J; Hirstius, A; Hofer, H; Holzner, G; Hoorani, H; Hou, S R; Iashvili, I; Jin, B N; Jones, L W; de Jong, P; Josa-Mutuberria, I; Khan, R A; Kaur, M; Kienzle-Focacci, M N; Kim, D; Kim, D H; Kim, J K; Kim, S C; Kirkby, Jasper; Kiss, D; Kittel, E W; Klimentov, A; König, A C; Kopp, A; Koutsenko, V F; Kräber, M H; Krämer, R W; Krenz, W; Krüger, A; Kunin, A; Ladrón de Guevara, P; Laktineh, I; Landi, G; Lassila-Perini, K M; Lebeau, M; Lebedev, A; Lebrun, P; Lecomte, P; Lecoq, P; Le Coultre, P; Lee, H J; Le Goff, J M; Leiste, R; Leonardi, E; Levchenko, P M; Li Chuan; Likhoded, S A; Lin, C H; Lin, W T; Linde, Frank L; Lista, L; Liu, Z A; Lohmann, W; Longo, E; Lü, Y S; Lübelsmeyer, K; Luci, C; Luckey, D; Lugnier, L; Luminari, L; Lustermann, W; Ma Wen Gan; Maity, M; Malgeri, L; Malinin, A; Maña, C; Mangeol, D J J; Marchesini, P A; Marian, G; Martin, J P; Marzano, F; Massaro, G G G; Mazumdar, K; McNeil, R R; Mele, S; Merola, L; Meschini, M; Metzger, W J; Von der Mey, M; Mihul, A; Milcent, H; Mirabelli, G; Mnich, J; Mohanty, G B; Molnár, P; Monteleoni, B; Moulik, T; Muanza, G S; Muheim, F; Muijs, A J M; Musy, M; Napolitano, M; Nessi-Tedaldi, F; Newman, H; Niessen, T; Nisati, A; Nowak, H; Oh, Yu D; Organtini, G; Oulianov, A; Palomares, C; Pandoulas, D; Paoletti, S; Paolucci, P; Paramatti, R; Park, H K; Park, I H; Pascale, G; Passaleva, G; Patricelli, S; Paul, T; Pauluzzi, M; Paus, C; Pauss, Felicitas; Pedace, M; Pensotti, S; Perret-Gallix, D; Petersen, B; Piccolo, D; Pierella, F; Pieri, M; Piroué, P A; Pistolesi, E; Plyaskin, V; Pohl, M; Pozhidaev, V; Postema, H; Pothier, J; Produit, N; Prokofev, D; Prokofiev, D O; Quartieri, J; Rahal-Callot, G; Rahaman, M A; Raics, P; Raja, N; Ramelli, R; Rancoita, P G; Raspereza, A V; Raven, G; Razis, P A; Ren, D; Rescigno, M; Reucroft, S; Van Rhee, T; Riemann, S; Riles, K; Robohm, A; Rodin, J; Roe, B P; Romero, L; Rosca, A; Rosier-Lees, S; Rubio, Juan Antonio; Ruschmeier, D; Rykaczewski, H; Saremi, S; Sarkar, S; Salicio, J; Sánchez, E; Sanders, M P; Sarakinos, M E; Schäfer, C; Shchegelskii, V; Schmidt-Kärst, S; Schmitz, D; Schopper, Herwig Franz; Schotanus, D J; Schwering, G; Sciacca, C; Sciarrino, D; Seganti, A; Servoli, L; Shevchenko, S; Shivarov, N; Shoutko, V; Shumilov, E; Shvorob, A V; Siedenburg, T; Son, D; Smith, B; Spillantini, P; Steuer, M; Stickland, D P; Stone, A; Stone, H; Stoyanov, B; Strässner, A; Sudhakar, K; Sultanov, G G; Sun, L Z; Suter, H; Swain, J D; Szillási, Z; Sztaricskai, T; Tang, X W; Tauscher, Ludwig; Taylor, L; Timmermans, C; Ting, Samuel C C; Ting, S M; Tonwar, S C; Tóth, J; Tully, C; Tung, K L; Uchida, Y; Ulbricht, J; Valente, E; Vesztergombi, G; Vetlitskii, I; Vicinanza, D; Viertel, Gert M; Villa, S; Vivargent, M; Vlachos, S; Vodopyanov, I; Vogel, H; Vogt, H; Vorobev, I; Vorobyov, A A; Vorvolakos, A; Wadhwa, M; Wallraff, W; Wang, M; Wang, X L; Wang, Z M; Weber, A; Weber, M; Wienemann, P; Wilkens, H; Wu, S X; Wynhoff, S; Xia, L; Xu, Z Z; Yang, B Z; Yang, C G; Yang, H J; Yang, M; Ye, J B; Yeh, S C; Zalite, A; Zalite, Yu; Zhang, Z P; Zhu, G Y; Zhu, R Y; Zichichi, A; Zilizi, G; Zöller, M

    2000-01-01

    Small-angle Bhabha scattering data recorded at the Z resonance and large-angleBhabha scattering data recorded at $\\sqrt{s} = 189$ \\textrm{Ge\\kern -0.1em V} bythe L3 detector at LEP are used to measure the running of the effective fine-structure constant for spacelike momentum transfers. The results are\\begin{eqnarray*} \\alpha^{-1}(-2.1 \\mathrm{Ge\\kern -0.1em V}^{2}) - \\alpha^{-1}(-6.25 \\mathrm{Ge\\kern -0.1em V}^{2}) & = & 0.78 \\pm 0.26 \\\\ \\alpha^{-1}(-12.25 \\mathrm{Ge\\kern -0.1em V}^{2}) - \\alpha^{-1}(-3434 \\mathrm{Ge\\kern -0.1em V}^{2}) & = & 3.80 \\pm 1.29, \\\\\\end{eqnarray*}in agreement with theoretical predictions.

  16. HERSCHEL GALACTIC PLANE SURVEY OF [N ii] FINE STRUCTURE EMISSION

    Energy Technology Data Exchange (ETDEWEB)

    Goldsmith, Paul F.; Yıldız, Umut A.; Langer, William D.; Pineda, Jorge L., E-mail: Paul.F.Goldsmith@jpl.nasa.gov [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109 (United States)

    2015-12-01

    We present the first large-scale high angular resolution survey of ionized nitrogen in the Galactic Plane through emission of its two fine structure transitions ([N ii]) at 122 and 205 μm. The observations were largely obtained with the PACS instrument onboard the Herschel Space Observatory. The lines of sight were in the Galactic plane, following those of the Herschel OTKP project GOT C+. Both lines are reliably detected at the 10{sup −8}–10{sup −7} Wm{sup −2} sr{sup −1} level over the range –60° ≤ l ≤ 60°. The rms of the intensity among the 25 PACS spaxels of a given pointing is typically less than one third of the mean intensity, showing that the emission is extended. [N ii] is produced in gas in which hydrogen is ionized, and collisional excitation is by electrons. The ratio of the two fine structure transitions provides a direct measurement of the electron density, yielding n(e) largely in the range 10–50 cm{sup −3} with an average value of 29 cm{sup −3} and N{sup +} column densities 10{sup 16}–10{sup 17} cm{sup −2}. [N ii] emission is highly correlated with that of [C ii], and we calculate that between 1/3 and 1/2 of the [C ii] emission is associated with the ionized gas. The relatively high electron densities indicate that the source of the [N ii] emission is not the warm ionized medium (WIM), which has electron densities more than 100 times smaller. Possible origins of the observed [N ii] include the ionized surfaces of dense atomic and molecular clouds, the extended low-density envelopes of H ii regions, and low-filling factor high-density fluctuations of the WIM.

  17. A heterogeneity test for fine-scale genetic structure.

    Science.gov (United States)

    Smouse, Peter E; Peakall, Rod; Gonzales, Eva

    2008-07-01

    For organisms with limited vagility and/or occupying patchy habitats, we often encounter nonrandom patterns of genetic affinity over relatively small spatial scales, labelled fine-scale genetic structure. Both the extent and decay rate of that pattern can be expected to depend on numerous interesting demographic, ecological, historical, and mating system factors, and it would be useful to be able to compare different situations. There is, however, no heterogeneity test currently available for fine-scale genetic structure that would provide us with any guidance on whether the differences we encounter are statistically credible. Here, we develop a general nonparametric heterogeneity test, elaborating on standard autocorrelation methods for pairs of individuals. We first develop a 'pooled within-population' correlogram, where the distance classes (lags) can be defined as functions of distance. Using that pooled correlogram as our null-hypothesis reference frame, we then develop a heterogeneity test of the autocorrelations among different populations, lag-by-lag. From these single-lag tests, we construct an analogous test of heterogeneity for multilag correlograms. We illustrate with a pair of biological examples, one involving the Australian bush rat, the other involving toadshade trillium. The Australian bush rat has limited vagility, and sometimes occupies patchy habitat. We show that the autocorrelation pattern diverges somewhat between continuous and patchy habitat types. For toadshade trillium, clonal replication in Piedmont populations substantially increases autocorrelation for short lags, but clonal replication is less pronounced in mountain populations. Removal of clonal replicates reduces the autocorrelation for short lags and reverses the sign of the difference between mountain and Piedmont correlograms.

  18. Thermally detected optical absorption in sophisticated nitride structures

    Energy Technology Data Exchange (ETDEWEB)

    Vasson, A.; Leymarie, J. [LASMEA-UMR 6602 CNRS-UBP, 63177 Aubiere Cedex (France); Shubina, T.V. [Ioffe Physico-Technical Institute, RAS, St. Petersburg 194021 (Russian Federation)

    2005-02-01

    The thermally detected optical absorption (TDOA) is applied to elucidate peculiarities of absorption in nitride structures of unusual morphology like GaN nanocolumns or InN layers with various imperfections. A study of GaN structures permits us to establish position of an absorption edge in TDOA spectra. We demonstrate that the absorption edge is different in GaN regions of opposite polarities. In InN with metallic In inclusions, this technique enable separation of InN interband absorption and extinction related to the Mie resonances, if the latter are below the principal absorption edge. (copyright 2005 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  19. Optimal design of porous structures for the fastest liquid absorption.

    Science.gov (United States)

    Shou, Dahua; Ye, Lin; Fan, Jintu; Fu, Kunkun

    2014-01-14

    Porous materials engineered for rapid liquid absorption are useful in many applications, including oil recovery, spacecraft life-support systems, moisture management fabrics, medical wound dressings, and microfluidic devices. Dynamic absorption in capillary tubes and porous media is driven by the capillary pressure, which is inversely proportional to the pore size. On the other hand, the permeability of porous materials scales with the square of the pore size. The dynamic competition between these two superimposed mechanisms for liquid absorption through a heterogeneous porous structure may lead to an overall minimum absorption time. In this work, we explore liquid absorption in two different heterogeneous porous structures [three-dimensional (3D) circular tubes and porous layers], which are composed of two sections with variations in radius/porosity and height. The absorption time to fill the voids of porous constructs is expressed as a function of radius/porosity and height of local sections, and the absorption process does not follow the classic Washburn's law. Under given height and void volume, these two-section structures with a negative gradient of radius/porosity against the absorption direction are shown to have faster absorption rates than control samples with uniform radius/porosity. In particular, optimal structural parameters, including radius/porosity and height, are found that account for the minimum absorption time. The liquid absorption in the optimized porous structure is up to 38% faster than in a control sample. The results obtained can be used a priori for the design of porous structures with excellent liquid management property in various fields.

  20. Absorption enhancement and total absorption in a graphene-waveguide hybrid structure

    Science.gov (United States)

    Guo, Jun; Wu, Leiming; Dai, Xiaoyu; Xiang, Yuanjiang; Fan, Dianyuan

    2017-02-01

    We propose a graphene/planar waveguide hybrid structure, and demonstrate total absorption in the visible wavelength range by means of attenuated total reflectance. The excitation of planar waveguide mode, which has strong near field enhancement and increased light interaction length with graphene, plays a vital role in total absorption. We analyze the origin and physical insight of total absorption theoretically by using an approximated reflectance, and show how to design such hybrid structure numerically. Utilizing the tunability of doped graphene, we discuss the possible application in optical modulators. We also achieve broadband absorption enhancement in near-IR range by cascading multiple graphene-waveguide hybrid structures. We believe our results will be useful not only for potential applications in optical devices, but also for studying other two-dimension materials.

  1. Absorption enhancement and total absorption in a graphene-waveguide hybrid structure

    Directory of Open Access Journals (Sweden)

    Jun Guo

    2017-02-01

    Full Text Available We propose a graphene/planar waveguide hybrid structure, and demonstrate total absorption in the visible wavelength range by means of attenuated total reflectance. The excitation of planar waveguide mode, which has strong near field enhancement and increased light interaction length with graphene, plays a vital role in total absorption. We analyze the origin and physical insight of total absorption theoretically by using an approximated reflectance, and show how to design such hybrid structure numerically. Utilizing the tunability of doped graphene, we discuss the possible application in optical modulators. We also achieve broadband absorption enhancement in near-IR range by cascading multiple graphene-waveguide hybrid structures. We believe our results will be useful not only for potential applications in optical devices, but also for studying other two-dimension materials.

  2. COLLISIONAL EXCITATION OF THE [C II] FINE STRUCTURE TRANSITION IN INTERSTELLAR CLOUDS

    Energy Technology Data Exchange (ETDEWEB)

    Goldsmith, Paul F.; Langer, William D.; Pineda, Jorge L.; Velusamy, T., E-mail: Paul.F.Goldsmith@jpl.nasa.gov [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109 (United States)

    2012-11-15

    We analyze the collisional excitation of the 158 {mu}m (1900.5 GHz) fine structure transition of ionized carbon in terms of line intensities produced by simple cloud models. The single C{sup +} fine structure transition is a very important coolant of the atomic interstellar medium (ISM) and of photon-dominated regions in which carbon is partially or completely in ionized form. The [C II] line is widely used as a tracer of star formation in the Milky Way and other galaxies. Excitation of the [C II] fine structure transition can be via collisions with hydrogen molecules, atoms, and electrons. Analysis of [C II] observations is complicated by the fact that it is difficult to determine the optical depth of the line. We discuss the excitation of the [C II] line, deriving analytic results for several limiting cases and carry out numerical solutions using a large velocity gradient model for a more inclusive analysis. For antenna temperatures up to 1/3 of the brightness temperature of the gas kinetic temperature, the antenna temperature is linearly proportional to the column density of C{sup +} irrespective of the optical depth of the transition. This is appropriately referred to as the effectively optically thin approximation. We review the critical densities for excitation of the [C II] line by various collision partners, briefly analyze C{sup +} absorption, and conclude with a discussion of C{sup +} cooling and how the considerations for line intensities affect the behavior of this important coolant of the ISM.

  3. Neon Fine-Structure Line Emission By X-ray Irradiated Protoplanetary Disks

    CERN Document Server

    Glassgold, A E; Igea, J; Glassgold, Alfred E.; Najita, Joan R.; Igea, Javier

    2006-01-01

    Using a thermal-chemical model for the generic T-Tauri disk of D'Alessio et al. (1999), we estimate the strength of the fine-structure emission lines of NeII and NeIII at 12.81 and 15.55 microns that arise from the warm atmosphere of the disk exposed to hard stellar X-rays. The Ne ions are produced by the absorption of keV X-rays from the K shell of neutral Ne, followed by the Auger ejection of several additional electrons. The recombination cascade of the Ne ions is slow because of weak charge transfer with atomic hydrogen in the case of Ne2+ and by essentially no charge transfer for Ne+. For a distance of 140pc, the 12.81 micron line of Ne II has a flux of 1e-14 erg/cm2s, which should be observable with the Spitzer Infrared Spectrometer and suitable ground based instrumentation. The detection of these fine-structure lines would clearly demonstrate the effects of X-rays on the physical and chemical properties of the disks of young stellar objects and provide a diagnostic of the warm gas in protoplanetary dis...

  4. Constraints on a possible variation of the fine structure constant from galaxy cluster data

    CERN Document Server

    Holanda, R F L; Alcaniz, J S; G., I E Sanchez; Busti, V C

    2015-01-01

    We propose a new method to probe a possible time evolution of the fine structure constant $\\alpha$ from X-ray and Sunyaev-Zeldovich measurements of the gas mass fraction ($f_{gas}$) in galaxy clusters. Taking into account a direct relation between variations of $\\alpha$ and violations of the distance-duality relation, we discuss constraints on $\\alpha$ for a class of dilaton runaway models. Although not yet competitive with bounds from high-$z$ quasar absorption systems, our constraints, considering a sample of 29 measurements of $f_{gas}$, in the redshift interval $0.14 < z < 0.89$, provide an independent estimate of $\\alpha$ variation at low and intermediate redshifts. Furthermore, current and planned surveys will provide a larger amount of data and thus allow to improve the limits on $\\alpha$ variation obtained in the present analysis.

  5. Constraints on a possible variation of the fine structure constant from galaxy cluster data

    Science.gov (United States)

    Holanda, R. F. L.; Landau, S. J.; Alcaniz, J. S.; Sánchez G., I. E.; Busti, V. C.

    2016-05-01

    We propose a new method to probe a possible time evolution of the fine structure constant α from X-ray and Sunyaev-Zel'dovich measurements of the gas mass fraction (fgas) in galaxy clusters. Taking into account a direct relation between variations of α and violations of the distance-duality relation, we discuss constraints on α for a class of dilaton runaway models. Although not yet competitive with bounds from high-z quasar absorption systems, our constraints, considering a sample of 29 measurements of fgas, in the redshift interval 0.14 intermediate redshifts. Furthermore, current and planned surveys will provide a larger amount of data and thus allow to improve the limits on α variation obtained in the present analysis.

  6. Galaxy clusters, type Ia supernovae and the fine structure constant

    CERN Document Server

    Holanda, R F L; Colaço, L R; Alcaniz, J S; Landau, S J

    2016-01-01

    As is well known, measurements of the Sunyaev-Zeldovich effect can be combined with observations of the X-ray surface brightness of galaxy clusters to estimate the angular diameter distance to these structures. In this paper, we show that this technique depends on the fine structure constant, $\\alpha$. Therefore, if $\\alpha$ is a time-dependent quantity, e.g., $\\alpha=\\alpha_0 \\phi(z)$, where $\\phi$ is a function of redshift, we argue that current data do not provide the real angular diameter distance, $D_{\\rm{A}}(z)$, to the cluster but instead $D_A^{data}(z) = \\phi(z)^2 D_{\\rm{A}}(z)$. We use this result to derive constraints on a possible variation of $\\alpha$ for a class of dilaton runaway models considering a sample of 25 measurements of $D_A^{data}(z)$ in redshift range $0.023 < z < 0.784$ and estimates of $D_{\\rm{A}}(z)$ from current type Ia supernovae observations. We find no significant indication of variation of $\\alpha$ with the present data.

  7. Fine structure behaviour of VVER-1000 RPV materials under irradiation

    Science.gov (United States)

    Gurovich, B. A.; Kuleshova, E. A.; Shtrombakh, Ya. I.; Erak, D. Yu.; Chernobaeva, A. A.; Zabusov, O. O.

    2009-06-01

    Changes in the fine structure and mechanical properties of the base metal (BM) and weld metal (WM) of VVER-1000 pressure vessels during accumulation of neutron dose in the range of fluences ˜(3.2-15) × 10 23 m -2 ( E > 0.5 MeV) at 290 °C are studied using methods of transmission electron microscopy, fractographic analysis, and Auger electron spectroscopy. A correlation was found between the changes of mechanical properties and the micro- and nano-structures of the studied steels. Accumulation of neutron dose considerably raises the strength characteristics and transition temperature of VVER-1000 pressure vessel steels. The rate of changes in the mechanical properties of the weld metal is significantly higher than that of the base metal. The slower growth of strength characteristics and transition temperature shift of the base metal under irradiation as compared with the weld metal is due to the slower growth of the density of radiation defects and radiation-induced precipitates. The level of intergranular embrittlement under irradiation in the weld metal is not higher then in the base metal in spite of the higher content of nickel.

  8. Fine structure in the cluster decay of radium isotopes

    Energy Technology Data Exchange (ETDEWEB)

    Santhosh, K P [School of Pure and Applied Physics, Kannur University, Payyanur Campus, Payyanur 670 327 (India)], E-mail: kpsanthosh@eth.net

    2010-01-15

    Half-life times for {sup 14}C cluster emission from various radium isotopes are computed taking interacting potential as the sum of Coulomb and proximity potentials. The half-life time values are compared with experimental data and with the values reported by Poenaru et al using the analytical super-asymmetric fission model (ASAFM). The lowest half-life time for {sup 222}Ra stresses the role of the doubly magic {sup 208}Pb daughter in the exotic decay process. It is found that neutron excess in the parent nucleus slows down the exotic decay process. The high hindrance factor (HF) of the {sup 14}C branch to the ground state (9/2{sup +}) and the low HF to the first excited state (11/2{sup +}) of the {sup 209}Pb daughter are in good agreement with the experimental result. The fine structure from {sup 223}Ra gives direct evidence of the presence of a spherical component in the deformed parent nucleus.

  9. Hymenolepis nana: the fine structure of the embryonic envelopes.

    Science.gov (United States)

    Fairweather, I; Threadgold, L T

    1981-06-01

    The fine structure of the envelopes surrounding hatched and unhatched oncospheres of Hymenolepis nana has been investigated by transmission and scanning electron microscopy (SEM), together with light microscope histochemical observations of JB-4 embedded material. The oncosphere is surrounded by 3 layers--the capsule, the outer envelope and the inner envelope, the latter giving rise to the embryophore and the 'oncospheral membrane'. An additional layer--the polar filament layer--lies between the 'oncospheral membrane' and the oncosphere. Shell material is deposited on the capsule as a thin layer. It is secreted by the outer envelope, which degenerates once shell formation is complete. The uterus may also contribute to shell formation. The embryophore forms a thin incomplete and peripheral layer within the inner envelope. In the basal region of this envelope, partial development of an 'oncospheral membrane' takes place, but it does not become detached as a separate layer. The polar filaments, which are characteristic of the oncosphere of H. nana, are derived from the epithelial covering of the oncosphere itself, which delaminates to form a separate polar filament layer. The filaments arise from knob-like projections at opposite poles of this layer. The design of the embryonic envelopes in H. nana show a number of modifications from the basic cyclophyllidean pattern, and these can be related to the demands of its 'direct' life-cycle.

  10. Fine-structure constant: Is it really a constant?

    Science.gov (United States)

    Bekenstein, Jacob D.

    1982-03-01

    It is often claimed that the fine-structure "constant" α is shown to be strictly constant in time by a variety of astronomical and geophysical results. These constrain its fractional rate of change α˙α to at least some orders of magnitude below the Hubble rate H0. We argue that the conclusion is not as straightforward as claimed since there are good physical reasons to expect α˙α<

  11. Bumblebee Homing: The Fine Structure of Head Turning Movements.

    Directory of Open Access Journals (Sweden)

    Norbert Boeddeker

    Full Text Available Changes in flight direction in flying insects are largely due to roll, yaw and pitch rotations of their body. Head orientation is stabilized for most of the time by counter rotation. Here, we use high-speed video to analyse head- and body-movements of the bumblebee Bombus terrestris while approaching and departing from a food source located between three landmarks in an indoor flight-arena. The flight paths consist of almost straight flight segments that are interspersed with rapid turns. These short and fast yaw turns ("saccades" are usually accompanied by even faster head yaw turns that change gaze direction. Since a large part of image rotation is thereby reduced to brief instants of time, this behavioural pattern facilitates depth perception from visual motion parallax during the intersaccadic intervals. The detailed analysis of the fine structure of the bees' head turning movements shows that the time course of single head saccades is very stereotypical. We find a consistent relationship between the duration, peak velocity and amplitude of saccadic head movements, which in its main characteristics resembles the so-called "saccadic main sequence" in humans. The fact that bumblebee head saccades are highly stereotyped as in humans, may hint at a common principle, where fast and precise motor control is used to reliably reduce the time during which the retinal images moves.

  12. Fine structure of Pn velocity beneath Sichuan-Yunnan region

    Institute of Scientific and Technical Information of China (English)

    黄金莉; 宋晓东; 汪素云

    2003-01-01

    We use 23298 Pn arrival-time data from Chinese national and provincial earthquake bulletins to invert fine structure of Pn velocity and anisotropy at the top of the mantle beneath the Sichuan-Yunnan and its adjacent region. The results suggest that the Pn velocity in this region shows significant lateral variation; the Pn velocity varies from 7.7 to 8.3 km/s. The Pn-velocity variation correlates well with the tectonic activity and heat flow of the region. Low Pn velocity is observed in southwest Yunnan , Tengchong volcano area, and the Panxi tectonic area. These areas have very active seismicity and tectonic activity with high surface heat flow. On the other hand, high Pn velocity is observed in some stable regions, such as the central region of the Yangtze Platform; the most pronounced high velocity area is located in the Sichuan Basin, south of Chengdu. Pn anisotropy shows a complex pattern of regional deformation. The Pn fast direction shows a prominent clockwise rotation pattern from east of the Tibetan block to the Sichuan-Yunnan diamond block to southwest Yunnan, which may be related to southeastward escape of the Tibetan Plateau material due to the collision of the Indian Plate to the Eurasia Plate. Thus there appears to be strong correlation between the crustal deformation and the upper mantle structure in the region. The delay times of events and stations show that the crust thickness decreases from the Tibetan Plateau to eastern China, which is consistent with the results from deep seismic sounding.

  13. Enhancement of CO2 Absorption under Taylor Flow in the Presence of Fine Particles

    Institute of Scientific and Technical Information of China (English)

    CAI Wangfeng; ZHANG Jiao; ZHANG Xubin; WANG Yan; QI Xiangjuan

    2013-01-01

    The physical absorption of CO2 in water containing different types of particles was studied in a microchannel operated under Taylor flow.The maximum enhancement factors of 1.43-2.15 were measured for activated carbon(AcC)particles.The analysis shows that the enhancement effect can be attributed to the shuttle mechanism.Considering the separate contributions of mass transfer from bubble cap and liquid film,a heterogeneous enhancement model is developed.According to this model,the enhancement factors ECap,EFilm and Eov are mainly determined by mass transfer coefficient KL(KLCap and KL Film),adsorptive capacity of particles m,and coverage fraction of particles at gas-liquid interface ζ.With,both effects of particle-to-interface adhesion and apparent viscosity included,the model predicts the enhancement effect of AcC particles reasonably well.

  14. METHODS OF RECEIVING OF FINE-GRAINED STRUCTURE OF CASTINGS AT CRYSTALLIZATION

    Directory of Open Access Journals (Sweden)

    N. K. Tolochko

    2012-01-01

    Full Text Available The article deals with methods for fine-grained structure of ingots during crystallization depending on the used foundry technologies. It is shown that by using modern scientific and technological advances may improve the traditional and the development of new casting processes, providing production of cast parts with over fine-grained structure and enhanced properties.

  15. Does over-exposure modify the fine structure of distortion product otoacoustic emissions?

    DEFF Research Database (Denmark)

    Reuter, Karen; Hammershøi, Dorte

    2008-01-01

    It is investigated, whether the pattern of distortion product otoacoustic emission (DPOAE) fine structure (quasi-periodic variations across frequency) is altered by an acoustical over-exposure. DPOAE fine structures are determined in 16 normal-hearing humans using a high frequency-resolution and ......It is investigated, whether the pattern of distortion product otoacoustic emission (DPOAE) fine structure (quasi-periodic variations across frequency) is altered by an acoustical over-exposure. DPOAE fine structures are determined in 16 normal-hearing humans using a high frequency...... within 20 minutes. The DPOAE fine structure pattern is analyzed by an automatic classification algorithm, which determines ripple center frequency, ripple spacing, ripple height and ripple prevalence. For some individuals, an alteration of some of the parameters could be observed after the exposure, i...

  16. Fine structure of high-power microwave-induced resistance oscillations

    Science.gov (United States)

    Shi, Q.; Zudov, M. A.; Dmitriev, I. A.; Baldwin, K. Â. W.; Pfeiffer, L. Â. N.; West, K. Â. W.

    2017-01-01

    We report on observation of a fine structure of microwave-induced resistance oscillations in an ultraclean two-dimensional electron gas. This fine structure is manifested by multiple secondary sharp extrema, residing beside the primary ones, which emerge at high radiation power. Theoretical considerations reveal that this fine structure originates from multiphoton-assisted scattering off short-range impurities. Unique properties of the fine structure allow us to access all experimental parameters, including microwave power, and to separate different contributions to photoresistance. Furthermore, we show that the fine structure offers a convenient means to quantitatively assess the correlation properties of the disorder potential in high-quality systems, allowing separation of short- and long-range disorder contributions to the electron mobility.

  17. Size-resolved measurements of brown carbon and estimates of their contribution to ambient fine particle light absorption based on water and methanol extracts

    Science.gov (United States)

    Liu, J.; Bergin, M.; Guo, H.; King, L.; Kotra, N.; Edgerton, E.; Weber, R. J.

    2013-07-01

    Light absorbing organic carbon, often termed brown carbon, has the potential to significantly contribute to the visible light absorption budget, particularly at shorter wavelengths. Currently, the relative contributions of particulate brown carbon to light absorption, as well as the sources of brown carbon are poorly understood. With this in mind field measurements were made at both urban (Atlanta), and rural (Yorkville) sites in Georgia. Measurements in Atlanta were made at both a central site and a road side site adjacent to a main highway near the city center. Fine particle brown carbon optical absorption is estimated based on Mie calculations using direct size resolved measurements of chromophores in filter extracts. Size-resolved atmospheric aerosol samples were collected using a cascade impactor and analyzed for water-soluble organic carbon (WSOC), organic and elemental carbon (OC and EC), and solution light absorption spectra of water and methanol extracts. Methanol extracts were more light-absorbing than water extracts for all size ranges and wavelengths. Absorption refractive indices of the organic extracts were calculated from solution measurements for a range of wavelengths and used with Mie theory to predict the light absorption by fine particles comprised of these components, under the assumption that brown carbon and other aerosol components were externally mixed. For all three sites, chromophores were predominately in the accumulation mode with an aerodynamic mean diameter of 0.5 μm, an optically effective size range resulting in predicted particle light absorption being a factor of 2 higher than bulk solution absorption. Fine particle absorption was also measured with a Multi-Angle Absorption Photometer (MAAP) and seven-wavelength Aethalometer. Scattering-corrected aethalometer and MAAP absorption were in good agreement at 670 nm and Mie-estimated absorption based on size-resolved EC data were within 30% of these optical instruments. When applied

  18. Size-resolved measurements of brown carbon and estimates of their contribution to ambient fine particle light absorption based on water and methanol extracts

    Directory of Open Access Journals (Sweden)

    J. Liu

    2013-07-01

    Full Text Available Light absorbing organic carbon, often termed brown carbon, has the potential to significantly contribute to the visible light absorption budget, particularly at shorter wavelengths. Currently, the relative contributions of particulate brown carbon to light absorption, as well as the sources of brown carbon are poorly understood. With this in mind field measurements were made at both urban (Atlanta, and rural (Yorkville sites in Georgia. Measurements in Atlanta were made at both a central site and a road side site adjacent to a main highway near the city center. Fine particle brown carbon optical absorption is estimated based on Mie calculations using direct size resolved measurements of chromophores in filter extracts. Size-resolved atmospheric aerosol samples were collected using a cascade impactor and analyzed for water-soluble organic carbon (WSOC, organic and elemental carbon (OC and EC, and solution light absorption spectra of water and methanol extracts. Methanol extracts were more light-absorbing than water extracts for all size ranges and wavelengths. Absorption refractive indices of the organic extracts were calculated from solution measurements for a range of wavelengths and used with Mie theory to predict the light absorption by fine particles comprised of these components, under the assumption that brown carbon and other aerosol components were externally mixed. For all three sites, chromophores were predominately in the accumulation mode with an aerodynamic mean diameter of 0.5 μm, an optically effective size range resulting in predicted particle light absorption being a factor of 2 higher than bulk solution absorption. Fine particle absorption was also measured with a Multi-Angle Absorption Photometer (MAAP and seven-wavelength Aethalometer. Scattering-corrected aethalometer and MAAP absorption were in good agreement at 670 nm and Mie-estimated absorption based on size-resolved EC data were within 30% of these optical instruments

  19. Transient Intersubband Optical Absorption in Double Quantum Well Structure

    Institute of Scientific and Technical Information of China (English)

    WU Bin-He

    2005-01-01

    The microscopic equations of motion including many-body effects are derived to study the intersubband polarization in the double quantum well structure induced by an ultrafast pumping infrared light. Based on the selfconsistent field theory, the transient probe absorption coefficient is calculated. These calculations are beyond the previous steady-state assumption. Transient probe absorption spectra are calculated under different pumping intensity and various pump probe delay.

  20. Astronomical constraints on the cosmic evolution of the fine structure constant and possible quantum dimensions

    NARCIS (Netherlands)

    Carilli, CL; Menten, KM; Stocke, JT; Perlman, E; Vermeulen, R; Briggs, F; de Bruyn, AG; Conway, J; Moore, CP

    2000-01-01

    We present measurements of absorption by the 21 cm hyperfine transition of neutral hydrogen toward radio sources at substantial look-back times. These data are used in combination with observations of rotational transitions of common interstellar molecules to set limits on the evolution of the fine

  1. Interstellar dust grain composition from high-resolution X-ray absorption edge structure

    Science.gov (United States)

    Corrales, Lia

    2016-06-01

    X-ray light is sufficient to excite electrons from n=1 (K-shell) and n=2 (L-shell) energy levels of neutral interstellar metals, causing a sharp increase in the absorption cross-section. Near the ionization energy, the shape of the photoelectric absorption edge depends strongly on whether the atom is isolated or bound in molecules or minerals (dust). With high resolution X-ray spectroscopy, we can directly measure the state of metals and the mineral composition of dust in the interstellar medium. In addition, the scattering contribution to the X-ray extinction cross-section can be used to gauge grain size, shape, and filling factor. In order to fully take advantage of major advances in high resolution X-ray spectroscopy, lab measurements of X-ray absorption fine structure (XAFS) from suspected interstellar minerals are required. Optical constants derived from the absorption measurements can be used with Mie scattering or anomalous diffraction theory in order to model the full extinction cross-sections from the interstellar medium. Much like quasar spectra are used to probe other intergalactic gas, absorption spectroscopy of Galactic X-ray binaries and bright stars will yield key insights to the mineralogy and evolution of dust grains in the Milky Way.

  2. Fine Resolution Termohaline Structure Of The Yuctatan Coastal Sea

    Science.gov (United States)

    Marino-Tapia, I.; Enriquez-Ortiz, C.; Capurro, L.; Euan-Avila, J.

    2007-05-01

    In the Yucatan peninsula there are a variety processes that drastically affect the thermohaline structure of the coastal seas. Some of these include hyperhaline lagoons that export salt to the ocean, upwelling events that propagate to the coast, persistent submarine groundwater discharges, and very high evaporation rates caused by the intense solar radiation. On July 2006 a fine resolution oceanographic campaign was performed on the Yucatan coast to study the detailed structure of thermohaline processes and currents from the shore to the 10 m isobath. A total of sixty nine transects that cover the entire northern stretch of the Yucatan coast were made. The transects extend seven kilometers in the offshore direction and have an alongshore spacing of 5 km. The temperature and salinity characteristics of the water column were monitored with a SEABIRD SBE 19 CTD performing profiles every 500 m along each transect. Ocean currents were measures along the same transect using a 1.5 MHz Acoustic Doppler Profiler (Sontek). The results clearly show the effects of coastal lagoons on the adjoining sea, with net salt export associated with hyperhaline lagoons (e.g. Ria Lagartos) or more estuarine influence of lagoons such as Celestun, where groundwater discharges play the role of rivers on the estuary. An assessment of this influence on the coastal ocean will be presented. It is well known the meteor impact at the end of the Cretacic era at Chicxulub, Yucatan, generated a crater with multiple rings which is evident from horizontal gravity gradients of the Yucatan mainland, and that associated with the outer ring there is a high concentration of cenotes (sinkholes) (Pope et al. 1991; Hildebrand, et al. 1995). It has also been shown that groundwater flows along this cenote ring towards the ocean, and the zones where the ring intersects the coast (Celestun and Dzilam Bravo) have impressive geologic features known as `submarine water springs' where freshwater springs as a fountain

  3. Simple surface structure determination from Fourier transforms of angle-resolved photoemission extended fine structure

    Energy Technology Data Exchange (ETDEWEB)

    Zheng, Y. [Pennsylvania State Univ., University Park, PA (United States)]|[Lawrence Berkeley Lab., CA (United States); Shirley, D.A. [Pennsylvania State Univ., University Park, PA (United States)

    1995-02-01

    The authors show by Fourier analyses of experimental data, with no further treatment, that the positions of all the strong peaks in Fourier transforms of angle-resolved photoemission extended fine structure (ARPEFS) from adsorbed surfaces can be explicitly predicted from a trial structure with an accuracy of about {+-} 0.3 {angstrom} based on a single-scattering cluster model together with the concept of a strong backscattering cone, and without any additional analysis. This characteristic of ARPEFS Fourier transforms can be developed as a simple method for determining the structures of adsorbed surfaces to an accuracy of about {+-} 0.1 {angstrom}.

  4. Dynamic energy absorption characteristics of hollow microlattice structures

    Energy Technology Data Exchange (ETDEWEB)

    Liu, YL; Schaedler, TA; Chen, X

    2014-10-01

    Hollow microlattice structures are promising candidates for advanced energy absorption and their characteristics under dynamic crushing are explored. The energy absorption can be significantly enhanced by inertial stabilization, shock wave effect and strain rate hardening effect. In this paper we combine theoretical analysis and comprehensive finite element method simulation to decouple the three effects, and then obtain a simple model to predict the overall dynamic effects of hollow microlattice structures. Inertial stabilization originates from the suppression of sudden crushing of the microlattice and its contribution scales with the crushing speed, v. Shock wave effect comes from the discontinuity across the plastic shock wave front during dynamic loading and its contribution scales with e. The strain rate effect increases the effective yield strength upon dynamic deformation and increases the energy absorption density. A mechanism map is established that illustrates the dominance of these three dynamic effects at a range of crushing speeds. Compared with quasi-static loading, the energy absorption capacity a dynamic loading of 250 m/s can be enhanced by an order of magnitude. The study may shed useful insight on designing and optimizing the energy absorption performance of hollow microlattice structures under various dynamic loads. (C) 2014 Elsevier Ltd. All rights reserved.

  5. EU Structural Funds Absorption in Romania: Obstacles and Issues

    Directory of Open Access Journals (Sweden)

    GHEORGHE ZAMAN

    2011-06-01

    Full Text Available Romania’s absorption capacity of EU structural and cohesion funds is based on the degree of implementation of Sectoral Operational Programmes (SOP 2007-2013 within SOP Environment and plays a central role in view of its complex relationships (horizontal and vertical with other SOPs.The present paper analyses the absorption capacity of SOPs in Romania, paying a special attention to SOP Environment, which can be considered an important tool for improving eco-efficiency standards and greening the economic growth. The research is focusing on cases and factors of weak absorption of Structural Funds in Romania under the current economic crisis circumstances as well as on some ways of improving the situation in the future.

  6. Absorption-reduced waveguide structure for efficient terahertz generation

    Energy Technology Data Exchange (ETDEWEB)

    Pálfalvi, L., E-mail: palfalvi@fizika.ttk.pte.hu [Institute of Physics, University of Pécs, Ifjúság ú. 6, 7624 Pécs (Hungary); Fülöp, J. A. [MTA-PTE High-Field Terahertz Research Group, Ifjúság ú. 6, 7624 Pécs (Hungary); Szentágothai Research Centre, University of Pécs, Ifjúság ú. 20, 7624 Pécs (Hungary); Hebling, J. [Institute of Physics, University of Pécs, Ifjúság ú. 6, 7624 Pécs (Hungary); MTA-PTE High-Field Terahertz Research Group, Ifjúság ú. 6, 7624 Pécs (Hungary); Szentágothai Research Centre, University of Pécs, Ifjúság ú. 20, 7624 Pécs (Hungary)

    2015-12-07

    An absorption-reduced planar waveguide structure is proposed for increasing the efficiency of terahertz (THz) pulse generation by optical rectification of femtosecond laser pulses with tilted-pulse-front in highly nonlinear materials with large absorption coefficient. The structure functions as waveguide both for the optical pump and the generated THz radiation. Most of the THz power propagates inside the cladding with low THz absorption, thereby reducing losses and leading to the enhancement of the THz generation efficiency by up to more than one order of magnitude, as compared with a bulk medium. Such a source can be suitable for highly efficient THz pulse generation pumped by low-energy (nJ-μJ) pulses at high (MHz) repetition rates delivered by compact fiber lasers.

  7. Theoretical Study of Relativistic Retardation Effects: the Abnormal Fine Structure of O Ⅱ

    Institute of Scientific and Technical Information of China (English)

    CHEN Shao-Hao; HAN Xiao-Ying; WANG Xiao-Lu; LI Ji

    2007-01-01

    Using multi-configuration Dirac-Fock and relativistic configuration interaction methods with high-order corrections, we report our precise calculation results of the fine-structure energy levels of the ground-state configuration of OⅡ(1s22s22p3). Our calculated fine-structure splittings of 2D3/2,5/2 and 2P1/2,3/2 are abnormal. We elucidate that the transverse (Breit) interaction, i.e. relativistic retardation effect, plays an important role for the abnormal fine-structure splittings. Our calculation results are in good agreement with experimental measurements.

  8. An observation of further splitting of the new fine-structure in magneto-optical spectra of CuO

    Science.gov (United States)

    Masumi, Taizo; Imanaka, Yasutaka; Takehana, Kanji; Yamaguchi, Hiroyuki; Kido, Giyuu

    2001-04-01

    Regarding CuO first in 1998 (Masumi et al., J. Phys. Soc. Japan 67 (1998) 67), we reported an observation of the new fine structures near the optical absorption edge below 90 K. They consist of two sharp peaks A and B at EA=1.57511 eV and EB=1.58097 eV, respectively, at T=7 K. Two peaks emerge only below 90 K and their integrated intensity remarkably grows below 90 and 60 K. Here, we have started a magneto-optical study to seek further natures of these fine structures in the absorption edge of CuO by applying high magnetic fields up to B=25 T with a resolution of δE=1.24 meV, Δ ν=1 cm -1. Peaks A and B exhibit rather little variations up to 10 T. Above 12 T, however, there starts to emerge a potential splitting in the peak A, whereas peak B simply indicates a broadening. Finally, we clearly recognize new finer structures due to splitting in peak A at B=25 T. These results reveal a possibility of an existence of further peculiar magnetic characters in CuO even at lower temperature side besides the antiferromagnetic transitions at TN1=213 K and TN2=230 K.

  9. Fine Structure of Starch-Clay Composites as Biopolymers

    Science.gov (United States)

    Midsol 50 wheat starch and 5% Cloisite clay with or without the addition of glycerin were used to prepare biopolymers in a twin-screw extruder. Early trials of sectioning the unembedded biopolymer resulted in the immediate absorption of water and subsequent dissolution of the sample due to the the ...

  10. STRUCTURAL FUNDS ABSORPTION GROWTH BY IMPROVING THEIR MANAGEMENT

    Directory of Open Access Journals (Sweden)

    Pautu Sorina

    2012-12-01

    Full Text Available Grant project management is now a trend in the institutions of various types in Romania due to the opportunities offered by the EU through structural Instruments. Absorbing European funds is a challenge for Romania. The Managing Authority for Structural Instruments, together with the subordinated institutions present deficiencies in their coordination and implementation, the effect being a slow process of absorption of structural and cohesion funds. Taking action to enhance absorption of Structural and Cohesion Funds was done later; some measures are neither effective nor efficient. One of the major problems in implementing the Structural Funds is the continuous change of their national legislation. Therefore it is necessary to take measures to increase the absorption of structural funds and also the national adoption of a stable legal framework applicable to Structural Funds, guides of the applicant and clearly established project calls, without any latest changes, creating a transparent system of project proposals assessment and results communication of assessments to their beneficiaries, the payments required by the reimbursement requests within 45 days specified in the contract and not just their validation, terms compliance in approval notifications and addenda to the contract funding, proper training of the personnel from the intermediate organizations and linking information provided by their staff.

  11. Optimization of extraordinary optical absorption in plasmonic and dielectric structures

    DEFF Research Database (Denmark)

    Dühring, Maria Bayard; Sigmund, Ole

    2013-01-01

    Extraordinary optical absorption (EOA) can be obtained by plasmonic surface structuring. However, studies that compare the performance of these plasmonic devices with similar structured dielectric devices are rarely found in the literature. In this work we show different methods to enhance the EOA...... silicon layer for certain optical wavelengths compared to metal strips. It is then demonstrated that by topology optimization it is possible to generate nonintuitive surface designs that perform even better than the simple strip designs for both silicon and metals. These results indicate that in general...... by optimizing the geometry of the surface structuring for both plasmonic and dielectric devices, and the optimized performances are compared. Two different problem types with periodic structures are considered. The first case shows that strips of silicon on a surface can increase the absorption in an underlying...

  12. Effects of fine structure of absorption sp ectrum and spin-singlet on zero-field-splitting parameters for BaCrSi4O10 and AgGaSe2:Cr2+%BaCrSi4O10与AgGaSe2:Cr2+吸收光谱的精细结构及自旋单态对零场分裂参量的影响∗

    Institute of Scientific and Technical Information of China (English)

    谭晓明; 赵刚; 张迪

    2016-01-01

    The compounds doped with or containing Cr2+ ions are extensively used as optoelectronic and nonlinear optical materials, because they have special optical, magnetic and electric properties. These properties are very closely related to the absorption spectra and zero-field-splitting. The studies of the absorption spectra and zero-field-splitting are very important for realizing the doped microscopic mechanism and understanding the interaction between impurity ions and host crystals, and they may be useful to material designers. The concept of the standard basis adapted to the double group chain is adopted in the strong-field scheme by the crystal field theory. This concept emphasizes the standardization of the basis of the whole 3d4 configuration space including all spin states. Thus, the basis functions can be constructed according to each irreducible representation of the double group and each basis function has a certain expression. Each standard basis adapted to the double group chain can be built from the former by a linear transformation, which forms a basis chain. Thus, the complete energy matrix including spin singlet is constructed for Cr2+ ion in tetragonal symmetry environment in the strong-field-representation by the crystal field theory. The fine structures of absorption spectra and the spin-singlet contributions to zero-field-splitting parameters for BaCrSi4O10 and AgGaSe2:Cr2+ are studied by diagonalizing the complete energy matrix. The fine structures for the two systems and the zero-field-splitting parameters for BaCrSi4O10 are given theoretically for the first time. The fine structures are assigned by the irreducible representation of the group. The results show that the spin-singlet contribution to D is negligible, but the contributions to a and F are important. The contributions arise from the interaction of the spin quintuplets with both spin triplets and spin singlets via spin-orbit coupling. However, the selection rule of spin-orbit coupling

  13. Estimate on the deceleration parameter in a Universe with variable fine structure constant

    CERN Document Server

    Berman, M S; Berman, Marcelo S.; Trevisan, Luis A.

    2001-01-01

    We determine a cosmological model that include a positive acceleration of the Universe and a time decreasing fine structure constant. The present day deceleration parameter is estimated by us, according to our model and the available experimental data .

  14. Size-resolved measurements of brown carbon in water and methanol extracts and estimates of their contribution to ambient fine-particle light absorption

    Science.gov (United States)

    Liu, J.; Bergin, M.; Guo, H.; King, L.; Kotra, N.; Edgerton, E.; Weber, R. J.

    2013-12-01

    Light absorbing organic carbon, often called brown carbon, has the potential to significantly contribute to the visible light-absorption budget, particularly at shorter wavelengths. Currently, the relative contributions of particulate brown carbon to light absorption, as well as the sources of brown carbon, are poorly understood. With this in mind size-resolved direct measurements of brown carbon were made at both urban (Atlanta), and rural (Yorkville) sites in Georgia. Measurements in Atlanta were made at both a representative urban site and a road-side site adjacent to a main highway. Fine particle absorption was measured with a multi-angle absorption photometer (MAAP) and seven-wavelength Aethalometer, and brown carbon absorption was estimated based on Mie calculations using direct size-resolved measurements of chromophores in solvents. Size-resolved samples were collected using a cascade impactor and analyzed for water-soluble organic carbon (WSOC), organic and elemental carbon (OC and EC), and solution light-absorption spectra of water and methanol extracts. Methanol extracts were more light-absorbing than water extracts for all size ranges and wavelengths. Absorption refractive indices of the organic extracts were calculated from solution measurements for a range of wavelengths and used with Mie theory to predict the light absorption by fine particles comprised of these components, under the assumption that brown carbon and other aerosol components were externally mixed. For all three sites, chromophores were predominately in the accumulation mode with an aerodynamic mean diameter of 0.5 μm, an optically effective size range resulting in predicted particle light absorption being a factor of 2 higher than bulk solution absorption. Mie-predicted brown carbon absorption at 350 nm contributed a significant fraction (20 to 40%) relative to total light absorption, with the highest contributions at the rural site where organic to elemental carbon ratios were

  15. Non-linear electrodynamics and the variation of the fine structure constant

    Science.gov (United States)

    Mbelek, Jean Paul; Mosquera Cuesta, Herman J.

    2008-09-01

    It has been claimed that during the late-time history of our Universe, the fine structure constant of electromagnetism, α, has been increasing. The conclusion is achieved after looking at the separation between lines of ions like CIV, MgII, SiII, FeII, among others in the absorption spectra of very distant quasars, and comparing them with their counterparts obtained in the laboratory. However, in the meantime, other teams have claimed either a null result or a decreasing α with respect to the cosmic time. Also, the current precision of laboratory tests does not allow one to either comfort or reject any of these astronomical observations. Here, we suggest that as photons are the sidereal messengers, a non-linear electrodynamics (NLED) description of the interaction of photons with the weak local background magnetic fields of a gas cloud absorber around the emitting quasar can reconcile the Chand et al. and Levshakov et al. findings with the negative variation found by Murphy et al. and Webb et al., and also to find a bridge with the positive variation argued more recently by Levshakov et al. We also show that NLED photon propagation in a vacuum permeated by a background magnetic field presents a full agreement with constraints from Oklo natural reactor data. Finally, we show that NLED may render a null result only in a narrow range of the local background magnetic field which should be the case of both the claims by Chand et al. and by Srianand et al.

  16. Accelerating universe and the time-dependent fine-structure constant

    Science.gov (United States)

    Fujii, Yasunori

    2010-11-01

    I start with assuming a gravitational scalar field as the dark-energy supposed to be responsible for the accelerating universe. Also from the point of view of unification, a scalar field implies a time-variability of certain “constants” in Nature. In this context I once derived a relation for the time-variability of the fine-structure constant α: Δα/α =ζ Ƶ(α/π) Δσ, where ζ and Ƶ are the constants of the order one, while σ on the right-hand side is the scalar field in action in the accelerating universe. I use the reduced Planckian units with c=ℏ =MP(=(8π G)-1/2)=1. I then compared the dynamics of the accelerating universe, on one hand, and Δα/α derived from the analyses of QSO absorption lines, Oklo phenomenon, also different atomic clocks in the laboratories, on the other hand. I am here going to discuss the theoretical background of the relation, based on the scalar-tensor theory invented first by Jordan in 1955.

  17. Cosmological variation of the fine structure constant from an ultralight scalar field: The effects of mass

    Science.gov (United States)

    Gardner, Carl L.

    2003-08-01

    Cosmological variation of the fine structure constant α due to the evolution of a spatially homogeneous ultralight scalar field (m˜H0) during the matter and Λ dominated eras is analyzed. Agreement of Δα/α with the value suggested by recent observations of quasar absorption lines is obtained by adjusting a single parameter, the coupling of the scalar field to matter. Asymptotically α(t) in this model goes to a constant value α¯≈α0 in the early radiation and the late Λ dominated eras. The coupling of the scalar field to (nonrelativistic) matter drives α slightly away from α¯ in the epochs when the density of matter is important. Simultaneous agreement with the more restrictive bounds on the variation |Δα/α| from the Oklo natural fission reactor and from meteorite samples can be achieved if the mass of the scalar field is on the order of 0.5 0.6 HΛ, where HΛ=Ω1/2ΛH0. Depending on the scalar field mass, α may be slightly smaller or larger than α0 at the times of big bang nucleosynthesis, the emission of the cosmic microwave background, the formation of early solar system meteorites, and the Oklo reactor. The effects on the evolution of α due to nonzero mass for the scalar field are emphasized. An order of magnitude improvement in the laboratory technique could lead to a detection of (α˙/α)0.

  18. Time variation of the fine structure constant α from realistic models of Oklo reactors.

    Science.gov (United States)

    Gould, C. R.; Sharapov, E. I.; Lamoreaux, S. K.

    2006-11-01

    The topic of whether the fundamental constants of nature vary with time has been a subject of great interest since Dirac originally proposed the possibility that GN˜1/tuniverse. Recent observations of absorption spectra lines from distant quasars appeared to indicate a possible increase in the fine structure constant α over ten billion years. Contrarily, analyses of the time evolution of α from Oklo natural nuclear reactor data have yielded inconsistent results, some indicating a decrease over two billion years while others indicated no change. We have used known Oklo reactor epithermal spectral indices as criteria for selecting realistic reactor models. Reactors RZ2 and RZ10 were modeled with MCNP and the resulting neutron spectra were used to calculate the change in the ^149Sm capture cross section as a function of a possible shift in the energy of the 97.3-meV resonance. Our study resolves the contradictory situation with previous Oklo α-results. Our suggested 2 σ bound on a possible time variation of α over two billion years is stringent: -0.11 <=δαα <=0.24, in units of 10-7, but model dependent in that it assumes only α has varied over time.

  19. Fine structure and development of the collar enamel in gars ,Lepisosteus oculatus ,Actinopterygii

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The fine structure of collar enamel and the cells constituting the enamel organ during amelogenesis in Lepisosteus oculatus was observed by light,scanning electron and transmission electron microscopy.In the enamel,slender crystals were arranged perpendicular to the surface and the stripes that were parallel to the surface were observed,suggesting that the enamel in Lepisosteus shares common morphological features with that in sarcopterygian fish and amphibians.Ameloblasts containing developed Golgi apparatus,rough endoplasmic reticulum (rER) and secretory granules were found in the secretory stage.In the maturation stage,a ruffled border was not seen at the distal end of the ameloblasts,while many mitochondria and lysosome-like granules were obvious in the distal cytoplasm.The enamel organ consisted of the outer dental epithelial cells,stratum reticulum cells and ameloblasts,but there was no stratum intermedium.It is likely that the ameloblasts have less absorptive function in comparison with the inner dental epithelial cells facing cap enameloid.

  20. Fine structure of the malpighian tubule in Aedes aegypti

    Energy Technology Data Exchange (ETDEWEB)

    Mathew, G.; Rai, K.S.

    1976-07-01

    The malpighian tubule in Aedes aegypti adults is formed by 2 cell types: the principal cell which forms the great bulk of the tubule, and the stellate cell interspersed singly along the tubule. Both cell types possess ultrastructural features characteristic of cells engaged in ion balance and osmoregulation. These include extensive basal infolding and the differentiation of an apical brush border of microvilli. The central area of the cytoplasm of the principal cell is highly vacuolated while in the stellate cell it is finely granular lacking vacuoles. The microvilli in the principal cells enclose elongated, dense mitochondria whereas the stellate cell microvilli lack mitochondria. Excretory granules of an as yet unknown chemical nature accumulate in the principal cell cytoplasm after a blood meal.

  1. Triple-layer Absorptive Structures for Shock Wave Blast Protection

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Triple-layer absorptive structure is designed to reinforce a missile silo against shock wave blasts. An energy-absorbing layer and a cushion layer overlay the circular silo cover made of reinforced concrete. The dynamic stress analysis is performed by ABAQUS/Explicit. The mesoscopic structure of the energy absorbing layer is designed as an assembly of ductile tubes containing crushable cellular ceramics. Combined mesoscopic and macroscopic simulations indicate that the structure can enhance the survivability of a missile silo against blast waves.

  2. Fine-tuning structural RNA alignments in the twilight zone

    Directory of Open Access Journals (Sweden)

    Schirmer Stefanie

    2010-04-01

    Full Text Available Abstract Background A widely used method to find conserved secondary structure in RNA is to first construct a multiple sequence alignment, and then fold the alignment, optimizing a score based on thermodynamics and covariance. This method works best around 75% sequence similarity. However, in a "twilight zone" below 55% similarity, the sequence alignment tends to obscure the covariance signal used in the second phase. Therefore, while the overall shape of the consensus structure may still be found, the degree of conservation cannot be estimated reliably. Results Based on a combination of available methods, we present a method named planACstar for improving structure conservation in structural alignments in the twilight zone. After constructing a consensus structure by alignment folding, planACstar abandons the original sequence alignment, refolds the sequences individually, but consistent with the consensus, aligns the structures, irrespective of sequence, by a pure structure alignment method, and derives an improved sequence alignment from the alignment of structures, to be re-submitted to alignment folding, etc.. This circle may be iterated as long as structural conservation improves, but normally, one step suffices. Conclusions Employing the tools ClustalW, RNAalifold, and RNAforester, we find that for sequences with 30-55% sequence identity, structural conservation can be improved by 10% on average, with a large variation, measured in terms of RNAalifold's own criterion, the structure conservation index.

  3. Metalloprotein active site structure determination: synergy between X-ray absorption spectroscopy and X-ray crystallography.

    Science.gov (United States)

    Cotelesage, Julien J H; Pushie, M Jake; Grochulski, Pawel; Pickering, Ingrid J; George, Graham N

    2012-10-01

    Structures of metalloprotein active sites derived from X-ray crystallography frequently contain chemical anomalies such as unexpected atomic geometries or elongated bond-lengths. Such anomalies are expected from the known errors inherent in macromolecular crystallography (ca. 0.1-0.2Å) and from the lack of appropriate restraints for metal sites which are often without precedent in the small molecule structure literature. Here we review the potential of X-ray absorption spectroscopy to provide information and perspective which could aid in improving the accuracy of metalloprotein crystal structure solutions. We also review the potential problem areas in analysis of the extended X-ray absorption fine structure (EXAFS) and discuss the use of density functional theory as another possible source of geometrical restraints for crystal structure analysis of metalloprotein active sites.

  4. Fine- and hyperfine-structure effects in molecular photoionization: I. General theory and direct photoionization

    CERN Document Server

    Germann, Matthias

    2016-01-01

    We develop a model for predicting fine- and hyperfine intensities in the direct photoionization of molecules based on the separability of electron and nuclear spin states from vibrational-electronic states. Using spherical tensor algebra, we derive highly symmetrized forms of the squared photoionization dipole matrix elements from which which we derive the salient selection and propensity rules for fine- and hyperfine resolved photoionizing transitions. Our theoretical results are validated by the analysis of the fine-structure resolved photoelectron spectrum of O$_2$ (reported by H. Palm and F. Merkt, Phys. Rev. Lett. 81, 1385 (1998)) and are used for predicting hyperfine populations of molecular ions produced by photoionization.

  5. An Action-Based Fine-Grained Access Control Mechanism for Structured Documents and Its Application

    Directory of Open Access Journals (Sweden)

    Mang Su

    2014-01-01

    Full Text Available This paper presents an action-based fine-grained access control mechanism for structured documents. Firstly, we define a describing model for structured documents and analyze the application scenarios. The describing model could support the permission management on chapters, pages, sections, words, and pictures of structured documents. Secondly, based on the action-based access control (ABAC model, we propose a fine-grained control protocol for structured documents by introducing temporal state and environmental state. The protocol covering different stages from document creation, to permission specification and usage control are given by using the Z-notation. Finally, we give the implementation of our mechanism and make the comparisons between the existing methods and our mechanism. The result shows that our mechanism could provide the better solution of fine-grained access control for structured documents in complicated networks. Moreover, it is more flexible and practical.

  6. Sound absorption by subwavelength membrane structures: A geometric perspective

    Science.gov (United States)

    Yang, Min; Li, Yong; Meng, Chong; Fu, Caixing; Mei, Jun; Yang, Zhiyu; Sheng, Ping

    2015-12-01

    Decorated membranes comprising a thin layer of elastic film with small rigid platelets fixed on top have been found to be efficient absorbers of low-frequency sound. In this work we consider the problem of sound absorption from a perspective aimed at deriving upper bounds under different scenarios, i.e., whether the sound is incident from one side only or from both sides, and whether there is a reflecting surface on the back side of the membrane. By considering the negligible thickness of the membrane, usually on the order of a fraction of one millimeter, we derive a relation showing that the sum of the incoming sound waves' (complex) pressure amplitudes, averaged over the area of the membrane, must be equal to that of the outgoing waves. By using this relation, and without going to any details of the wave solutions, it is shown that the maximum absorption achievable from one-sided incidence is 50%, while the maximum absorption with a back-reflecting surface can reach 100%. The latter was attained by the hybridized resonances. All the results are shown to be in excellent agreement with the experiments. This generalized perspective, when used together with the Green function's formalism, can be useful in gaining insights into the constraints on what are achievable in scatterings and absorption by thin film structures and delineating them.

  7. Solvation structure of the halides from x-ray absorption spectroscopy

    Science.gov (United States)

    Antalek, Matthew; Pace, Elisabetta; Hedman, Britt; Hodgson, Keith O.; Chillemi, Giovanni; Benfatto, Maurizio; Sarangi, Ritimukta; Frank, Patrick

    2016-07-01

    Three-dimensional models for the aqueous solvation structures of chloride, bromide, and iodide are reported. K-edge extended X-ray absorption fine structure (EXAFS) and Minuit X-ray absorption near edge (MXAN) analyses found well-defined single shell solvation spheres for bromide and iodide. However, dissolved chloride proved structurally distinct, with two solvation shells needed to explain its strikingly different X-ray absorption near edge structure (XANES) spectrum. Final solvation models were as follows: iodide, 8 water molecules at 3.60 ± 0.13 Å and bromide, 8 water molecules at 3.40 ± 0.14 Å, while chloride solvation included 7 water molecules at 3.15 ± 0.10 Å, and a second shell of 7 water molecules at 4.14 ± 0.30 Å. Each of the three derived solvation shells is approximately uniformly disposed about the halides, with no global asymmetry. Time-dependent density functional theory calculations simulating the chloride XANES spectra following from alternative solvation spheres revealed surprising sensitivity of the electronic state to 6-, 7-, or 8-coordination, implying a strongly bounded phase space for the correct structure during an MXAN fit. MXAN analysis further showed that the asymmetric solvation predicted from molecular dynamics simulations using halide polarization can play no significant part in bulk solvation. Classical molecular dynamics used to explore chloride solvation found a 7-water solvation shell at 3.12 (-0.04/+0.3) Å, supporting the experimental result. These experiments provide the first fully three-dimensional structures presenting to atomic resolution the aqueous solvation spheres of the larger halide ions.

  8. Insight into the structure of Pd/ZrO2 during the total oxidation of methane using combined in situ XRD, X.-ray absorption and Raman spectroscopy

    DEFF Research Database (Denmark)

    Grunwaldt, Jan-Dierk; van Vegten, Niels; Baiker, Alfons;

    2009-01-01

    The structure of palladium during the total combustion of methane has been studied by a combination of the complementary in situ techniques X-ray absorption spectroscopy, Raman spectroscopy and X-ray diffraction. The study demonstrates that finely dispersed and oxidized palladium is most active f...

  9. Structure- and dose-absorption relationships of coffee polyphenols.

    Science.gov (United States)

    Erk, Thomas; Hauser, Johanna; Williamson, Gary; Renouf, Mathieu; Steiling, Heike; Dionisi, Fabiola; Richling, Elke

    2014-01-01

    Chlorogenic acids (CGAs) from coffee have biological effects related to human health. Thus, specific data on their bioavailability in the upper gastrointestinal tract are of high interest, since some molecules are absorbed here and so are not metabolized by colonic microflora. Up to now, no data on structure-absorption relationships for CGAs have been published, despite this being the most consumed group of polyphenols in the western diet. To address this gap, we performed ex vivo absorption experiments with pig jejunal mucosa using the Ussing chamber model (a model simulating the mucosa and its luminal/apical side). The main coffee polyphenols, caffeoylquinic acid (CQA), feruloylquinic acid (FQA), caffeic acid (CA), dicaffeoylquinic acid (diCQA), and D-(-)-quinic acid (QA), were incubated in individual experiments equivalent to gut lumen physiologically achievable concentrations (0.2-3.5 mM). Identification and quantification were performed with HPLC-diode array detection and HPLC-MS/MS. Additionally, the presence of ABC-efflux transporters was determined by Western blot analysis. The percentages of initially applied CGAs that were absorbed through the jejunal pig mucosa were, in increasing order: diCQA, trace; CQA, ≈ 1%; CA, ≈ 1.5%; FQA, ≈ 2%; and QA, ≈ 4%. No differences were observed within the CGA subgroups. Dose-absorption experiments with 5-CQA suggested a passive diffusion (nonsaturable absorption and a linear dose-flux relationship) and its secretion was affected by NaN3 , indicating an active efflux. The ABC-efflux transporters MDR 1 and MRP 2 were identified in pig jejunal mucosa for the first time. We conclude that active efflux plays a significant role in CGA bioavailability and, further, that the mechanism of CGA absorption in the jejunum is governed by their physicochemical properties.

  10. Paschen-Back effect involving atomic fine and hyperfine structure states

    Science.gov (United States)

    Sowmya, K.; Nagendra, K. N.; Sampoorna, M.; Stenflo, J. O.

    2015-10-01

    The linear polarization in spectral lines produced by coherent scattering is significantly modified by the quantum interference between the atomic states in the presence of a magnetic field. When magnetic fields produce a splitting which is of the order of or greater than the fine or hyperfine structure splittings, we enter the Paschen-Back effect (PBE) regime, in which the magnetic field dependence of the Zeeman splittings and transition amplitudes becomes non-linear. In general, PBE occurs for sufficiently strong fields when the fine structure states are involved and for weak fields in the case of hyperfine structure states. In this work, we apply the recently developed theory of PBE in the atomic fine and hyperfine structure states including the effects of partial frequency redistribution to the case of Li i 6708 Å doublet. We explore the signatures of PBE in a single scattering event and their applicability to the solar magnetic field diagnostics.

  11. Fine structure in a strong magnetic field: Paschen-Back effect reconsidered in Rydberg atoms

    Science.gov (United States)

    Liu, Wenyu; Gu, Sihong; Li, Baiwen

    1996-05-01

    Using a kind of potential model wave function for alkali metal atoms, we nonperturbatively study the effect of fine structure on the Rydberg spectra of Cs atom in a strong magnetic field. Our numerical results reveal spectral structure dramatically different from the well-established Paschen-Back effect, and we argue that the fine structure of the Rydberg Cs atom cannot be neglected even in a magnetic field as strong as several teslas. We also give an error estimate of our results and a word on possible experimental verification.

  12. Excitonic fine structure of elongated InAs/InP quantum dots

    Science.gov (United States)

    Zieliński, M.

    2013-10-01

    The bright exciton splitting in nanosystems and its origins are of primary importance for quantum-dot-based entangled-photon-pair generation. In this paper, I investigate excitonic energies and fine structure for million-atom InAs/InP quantum dots using many-body theory in conjunction with the empirical tight-binding method. Whereas the phenomenological theories relate the fine-structure splitting to quantum-dot-shape asymmetry, using an atomistic approach I demonstrate that for certain elongated quantum-dot shapes the bright exciton splitting can be significantly reduced. I demonstrate that strain effects play an essential role as the main contribution to the bright exciton splitting in InAs/InP quantum dots and observe highly reduced fine-structure splitting for high-symmetry quantum dots without wetting layer. I report the “intrinsic” fine-structure splitting, due to the underlying crystal lattice, to be generally significantly larger than the values predicted by the empirical pseudopotential calculations. Finally, I study excitonic properties of alloyed InAsP quantum dots and demonstrate that alloying effects can significantly reduce fine-structure splitting even in significantly elongated quantum dots.

  13. Impaired perception of temporal fine structure and musical timbre in cochlear implant users.

    Science.gov (United States)

    Heng, Joseph; Cantarero, Gabriela; Elhilali, Mounya; Limb, Charles J

    2011-10-01

    Cochlear implant (CI) users demonstrate severe limitations in perceiving musical timbre, a psychoacoustic feature of sound responsible for 'tone color' and one's ability to identify a musical instrument. The reasons for this limitation remain poorly understood. In this study, we sought to examine the relative contributions of temporal envelope and fine structure for timbre judgments, in light of the fact that speech processing strategies employed by CI systems typically employ envelope extraction algorithms. We synthesized "instrumental chimeras" that systematically combined variable amounts of envelope and fine structure in 25% increments from two different source instruments with either sustained or percussive envelopes. CI users and normal hearing (NH) subjects were presented with 150 chimeras and asked to determine which instrument the chimera more closely resembled in a single-interval two-alternative forced choice task. By combining instruments with similar and dissimilar envelopes, we controlled the valence of envelope for timbre identification and compensated for envelope reconstruction from fine structure information. Our results show that NH subjects utilize envelope and fine structure interchangeably, whereas CI subjects demonstrate overwhelming reliance on temporal envelope. When chimeras were created from dissimilar envelope instrument pairs, NH subjects utilized a combination of envelope (p = 0.008) and fine structure information (p = 0.009) to make timbre judgments. In contrast, CI users utilized envelope information almost exclusively to make timbre judgments (p timbre judgments (p musical timbre in CI users.

  14. Different Structures of PVA Nanofibrous Membrane for Sound Absorption Application

    Directory of Open Access Journals (Sweden)

    Jana Mohrova

    2012-01-01

    Full Text Available The thin nanofibrous layer has different properties in the field of sound absorption in comparison with porous fibrous material which works on a principle of friction of air particles in contact with walls of pores. In case of the thin nanofibrous layer, which represents a sound absorber here, the energy of sonic waves is absorbed by the principle of membrane resonance. The structure of the membrane can play an important role in the process of converting the sonic energy to a different energy type. The vibration system acts differently depending on the presence of smooth fibers in the structure, amount of partly merged fibers, or structure of polymer foil as extreme. Polyvinyl alcohol (PVA was used as a polymer because of its good water solubility. It is possible to influence the structure of nanofibrous layer during the production process thanks to this property of polyvinyl alcohol.

  15. The fine-grained phase-space structure of cold dark matter haloes

    NARCIS (Netherlands)

    Vogelsberger, Mark; White, Simon D. M.; Helmi, Amina; Springel, Volker

    2008-01-01

    We present a new and completely general technique for calculating the fine-grained phase-pace structure of dark matter (DM) throughout the Galactic halo. Our goal is to understand this structure on the scales relevant for direct and indirect detection experiments. Our method is based on evaluating t

  16. Distortion product otoacoustic emission fine structure as an early hearing loss predictor

    DEFF Research Database (Denmark)

    Reuter, Karen; Hammershøi, Dorte

    2006-01-01

    Otoacoustic emissions (OAEs) are a promising method to monitor early noise-induced hearing losses. When distortion product otoacoustic emissions (DPOAEs) are obtained with a high-frequency resolution, a ripple structure across frequency can be seen, called DPOAE fine structure. In this study DPOA...

  17. A simulation for gravity fine structure recovery from high-low GRAVSAT SST data

    Science.gov (United States)

    Estes, R. H.; Lancaster, E. R.

    1976-01-01

    Covariance error analysis techniques were applied to investigate estimation strategies for the high-low SST mission for accurate local recovery of gravitational fine structure, considering the aliasing effects of unsolved for parameters. Surface density blocks of 5 deg x 5 deg and 2 1/2 deg x 2 1/2 deg resolution were utilized to represent the high order geopotential with the drag-free GRAVSAT configured in a nearly circular polar orbit at 250 km. altitude. GEOPAUSE and geosynchronous satellites were considered as high relay spacecraft. It is demonstrated that knowledge of gravitational fine structure can be significantly improved at 5 deg x 5 deg resolution using SST data from a high-low configuration with reasonably accurate orbits for the low GRAVSAT. The gravity fine structure recoverability of the high-low SST mission is compared with the low-low configuration and shown to be superior.

  18. Fine structure of Plasmodium gallinaceum in embryonic and neonate chicks.

    Science.gov (United States)

    Lushbaugh, W B; McGhee, R B; Singh, S D

    1976-02-01

    The erythrocytic stages of Plasmdoium gallinaceum in chicken embryos injected with parasited blood either from a syringe-passaged infection in chickens or from a chicken infected with sporozoites were characterized by abnormal structure. Particularly evident were large, unstained vacuoles within the cytoplasm; these occurred with greatest frequency in schizonts. The presence of myelin bodies within these vacuoles was revealed by transmission electron microscopy; abnormal cytokinesis and aberrant merozoites provided additional evidence of the parasite's inability to develop naturally within the milieu of the embryonic erythrocytes. Fifty-five passages were necessary to restore normal structure of the parasites in embryos, while only 5 passages were required for such restoration in neonate chicks. The probable adaptation of the parasite to the proportions of hemoglobin of the adult chicken may be responsible for the abnormal growth in the immature host.

  19. Fine structure of sprites and proposed global observations

    DEFF Research Database (Denmark)

    Mende, S.B; Frey, H.U.; Rairden, R.l.

    2002-01-01

    In order to understand sprite processes we, have to explain the phenomena from spatial scales of a few meters to the scale of thunderstorm cells. The intricate small-scale vertical structuring of sprites or the so called beads are particularly difficult to understand. From a two-station triangula......In order to understand sprite processes we, have to explain the phenomena from spatial scales of a few meters to the scale of thunderstorm cells. The intricate small-scale vertical structuring of sprites or the so called beads are particularly difficult to understand. From a two-station...... structures of columniform sprites (C sprites) consisted of slant directed, nearly vertically aligned columns of intense pinpoint like beads. The distance of the sprites from the observer was measured and the altitude and vertical spacing of the beads were estimated. The distribution of beads showed...... that the most frequently observed bead spacing is between 0.6 and I km. The vertical and horizontal size of the bright luminous beads was about 80 m or less. The bead spacing showed a trend to increase with altitude and the e folding distance or attitude "scale-height" of bead spacing was found to be 20...

  20. Fine structure characterization of zero-valent iron nanoparticles for decontamination of nitrites and nitrates in wastewater and groundwater

    Directory of Open Access Journals (Sweden)

    Kuen-Song Lin et al

    2008-01-01

    Full Text Available The main objectives of the present study were to investigate the chemical reduction of nitrate or nitrite species by zero-valent iron nanoparticle (ZVIN in aqueous solution and related reaction kinetics or mechanisms using fine structure characterization. This work also exemplifies the utilization of field emission-scanning electron microscope (FE–SEM, transmission electron microscopy (TEM, and x-ray diffraction (XRD to reveal the speciation and possible reaction pathway in a very complex adsorption and redox reaction process. Experimentally, ZVIN of this study was prepared by sodium borohydride reduction method at room temperature and ambient pressure. The morphology of as-synthesized ZVIN shows that the nearly ball and ultrafine particles ranged of 20–50 nm were observed with FE–SEM or TEM analysis. The kinetic model of nitrites or nitrates reductive reaction by ZVIN is proposed as a pseudo first-order kinetic equation. The nitrite and nitrate removal efficiencies using ZVIN were found 65–83% and 51–68%, respectively, based on three different initial concentrations. Based on the XRD pattern analyses, it is found that the quantitative relationship between nitrite and Fe(III or Fe(II is similar to the one between nitrate and Fe(III in the ZVIN study. The possible reason is due to the faster nitrite reduction by ZVIN. In fact, the occurrence of the relative faster nitrite reductive reaction suggested that the passivation of the ZVIN have a significant contribution to iron corrosion. The extended x-ray absorption fine structure (EXAFS or x-ray absorption near edge structure (XANES spectra show that the nitrites or nitrates reduce to N2 or NH3 while oxidizing the ZVIN to Fe2O3 or Fe3O4 electrochemically. It is also very clear that decontamination of nitrate or nitrite species in groundwater via the in-situ remediation with a ZVIN permeable reactive barrier would be environmentally attractive.

  1. Distortion product otoacoustic emission fine-structure: An insight into the ear asymmetries

    Directory of Open Access Journals (Sweden)

    Bhamini Sharma

    2014-01-01

    Full Text Available Context: Use of distortion product otoacoustic emission (DPOAE as a measure of hearing sensitivity is common in clinical practice. However, use of a more informative DPOAE fine-structure has been limited due to non-reliability of DPOAE fine-structure. Aim: The current study was aimed at testing the interaural differences between the DPOAE fine-structure across three age groups. Settings and Design: Acoustically treated room with a calibrated dual channel audiometer (Orbiter 922 along with TDH-39 headphones and B-71 bone vibrator. GSI Tympstar was used for tympanometry and acoustic reflex measurements while ′ILO V6′ OAE analyzer was used for recording of DPOAE and DPOAE fine-structure. Material and Methods : A total of 98 subjects with normal peripheral hearing sensitivity were tested for DPOAE fine-structure. The three age groups consisted of young (8-18 years; n = 50, middle aged (30-40 years; n = 30, and elderly (50-60 years; n = 18. DPOAE fine-structure was studied at 8 points per octave on a total of 25 frequencies from 1000 to 8000 Hz. Statistical Analysis Used: Repeated measure analysis of variance. Results: There was a significant difference (P < 0.05 in the amplitudes at frequencies between 2000 and 3000 Hz. This was evident irrespective of the age groups. There was also a decrease in DPOAE amplitude in elderly group. Conclusions: Interaural asymmetry can be attributed as a reason to these findings and it occurred mostly in the speech perception frequencies. Reduced amplitude of DPAOE in the elderly group can be attributed to presbycusis.

  2. Fine structure of the pygmy dipole resonance in (136)Xe.

    Science.gov (United States)

    Savran, D; Fritzsche, M; Hasper, J; Lindenberg, K; Müller, S; Ponomarev, V Yu; Sonnabend, K; Zilges, A

    2008-06-13

    The photoresponse of the semimagic N=82 nucleus (136)Xe was measured up to the neutron separation energy S(n) using the (gamma, gamma') reaction. A concentration of strong dipole excitations is observed well below S(n) showing a fragmented resonancelike structure. Microscopic calculations in the quasiparticle phonon model including complex configurations of up to three phonons agree well with the experimental data in the total integrated strength, in the shape and the fragmentation of the resonance, which allows us to draw conclusions on the damping mechanism of the pygmy dipole resonance.

  3. Precision Measurement of the Three 23PJ Helium Fine Structure Intervals

    Science.gov (United States)

    Zelevinsky, T.; Farkas, D.; Gabrielse, G.

    2005-11-01

    The three 23P fine structure intervals of He4 are measured at an improved accuracy that is sufficient to test two-electron QED theory and to determine the fine structure constant α to 14 parts in 109. The more accurate determination of α, to a precision higher than attained with the quantum Hall and Josephson effects, awaits the reconciliation of two inconsistent theoretical calculations now being compared term by term. A low pressure helium discharge presents experimental uncertainties quite different than for earlier measurements and allows direct measurements of light pressure shifts.

  4. Fine structure of defects in radial nematic droplets

    Science.gov (United States)

    Mkaddem; Gartland

    2000-11-01

    We investigate the structure of defects in nematic liquid crystals confined in spherical droplets and subject to radial strong anchoring. Equilibrium configurations of the order-parameter tensor field in a Landau-de Gennes free energy are numerically modeled using a finite-element package. Within the class of axially symmetric fields, we find three distinct solutions: the familiar radial hedgehog, the small ring (or loop) disclination predicted by Penzenstadler and Trebin, and a solution that consists of a short disclination line segment along the rotational symmetry axis terminating in isotropic end points. Phase and bifurcation diagrams are constructed to illustrate how the three competing configurations are related. They confirm that the transition from the hedgehog to the ring structure is first order. The third configuration is metastable (in our symmetry class) and forms an alternate solution branch bifurcating off the radial hedgehog branch at the temperature below which the hedgehog ceases to be metastable. Dependence on temperature, droplet size, and elastic constants is investigated, and comparisons with other studies are made.

  5. The fine structure of the Acanthamoeba polyphaga cyst wall.

    Science.gov (United States)

    Lemgruber, Leandro; Lupetti, Pietro; De Souza, Wanderley; Vommaro, Rossiane C; da Rocha-Azevedo, Bruno

    2010-04-01

    Members of the genus Acanthamoeba are present in diverse environments, from freshwater to soil, and also in humans, causing serious brain and corneal infections. Their life cycle presents two stages: the dividing trophozoite and the quiescent cyst. The structures of these life stages have been studied for many years, and structural data have been used for taxonomy. The ultrastructural work on Acanthamoeba cysts was carried out previously by routine transmission electron microscopy (TEM), a process that requires the use of chemical fixation, a procedure that can cause serious artifacts in the ultrastructure of the studied material. In order to prevent fixation artifacts, we processed Acanthamoeba polyphaga cysts by ultrarapid freezing, followed by freeze-fracturing and deep-etching, in order to obtain a 3D visualization of the arrangements of the cyst wall. The exocyst presented an irregular surface, with vesicles located within or near this layer. The endocyst, instead, showed a biphasic arrangement with a more compact district in its innermost part, and a more loosened outer layer. For this reason, it was difficult to distinguish the filaments present in the intercyst space from those forming the endocyst. Surprisingly, the intercyst space was thinner when compared with samples processed by conventional TEM, evidencing the possible damage consequent to the use of chemical fixation.

  6. Arbitrarily thin metamaterial structure for perfect absorption and giant magnification

    DEFF Research Database (Denmark)

    Jin, Yi; Xiao, Sanshui; Mortensen, N. Asger

    2011-01-01

    In our common understanding, for strong absorption or amplification in a slab structure, the desire of reducing the slab thickness seems contradictory to the condition of small loss or gain. In this paper, this common understanding is challenged. It is shown that an arbitrarily thin metamaterial...... layer can perfectly absorb or giantly amplify an incident plane wave at a critical angle when the real parts of the permittivity and permeability of the metamaterial are zero while the absolute imaginary parts can be arbitrarily small. The metamaterial layer needs a totally reflective substrate...

  7. Fine structure of flare ribbons and evolution of electric currents

    CERN Document Server

    Sharykin, I N

    2014-01-01

    Emission of solar flares across the electromagnetic spectrum is often observed in the form of two expanding ribbons. The standard flare model explains the flare ribbons as footpoints of magnetic arcades, emitting due to interaction of energetic particles with the chromospheric plasma. However, the physics of this interaction and properties of the accelerated particles are still unknown. We present results of multiwavelength observations of C2.1 flare of August 15, 2013, observed with New Solar Telescope (NST) of Big Bear Solar Observatory, Solar Dynamics Observatory (SDO), GOES and FERMI spacecraft. The observations reveal previously unresolved sub-arcsecond structure of the flare ribbons in regions of strong magnetic field consisting from numerous small-scale bright knots. We observe red-blue asymmetry of H alpha flare ribbons with a width as small as 100 km. We discuss the relationship between the ribbons and vertical electric currents estimated from vector magnetograms, and show that Joule heating can be r...

  8. Fine structure in the ionospheric D-region

    Science.gov (United States)

    Thrane, E. V.; Grandal, B.; Fla, T.; Brekke, A.

    1981-07-01

    The 'partial reflection' method developed by Gardner and Pawsey (1953) turned out to be a useful tool for studies of the ionospheric D-region. A comparison is conducted of the observations of weak radio echoes from the ionospheric D-region, with model computations of radio wave scattering. The model computations are based on volume scattering from irregular ionospheric structures measured in situ in a sounding rocket. The experimental data were obtained from a rocket-borne electrostatic ion-current probe combined with simultaneous recordings of partial reflections. It is found that the intensity and height variation of partial reflections measured during the rocket flight are consistent with volume scattering from the ionospheric irregularities measured by the electrostatic probe in the rocket. The power spectra of ion density fluctuations derived from the rocket data indicate that these fluctuations are caused by turbulence in the neutral air. It is, therefore, concluded that such turbulence is an important source of partial reflections.

  9. Improved community structure detection using a modified fine tuning strategy

    CERN Document Server

    Sun, Yudong; Josic, Kresimir; Bassler, Kevin E

    2009-01-01

    The community structure of a complex network can be determined by finding the partitioning of its nodes that maximizes modularity. Many of the proposed algorithms for doing this work by recursively bisecting the network. We show that this unduely constrains their results, leading to a bias in the size of the communities they find and limiting their effectivness. To solve this problem, we propose adding a step to the existing algorithms that does not increase the order of their computational complexity. We show that, if this step is combined with a commonly used method, the identified constraint and resulting bias are removed, and its ability to find the optimal partitioning is improved. The effectiveness of this combined algorithm is also demonstrated by using it on real-world example networks. For a number of these examples, it achieves the best results of any known algorithm.

  10. The fine structure of endothelium of large arteries.

    Science.gov (United States)

    BUCK, R C

    1958-03-25

    Endothelium of large arteries from several species was studied in thin sections with the electron microscope. Before sacrifice, some animals received an intravenous injection of colloidal thorium dioxide which was visualized in the sections. Surface replicas were prepared by carbon evaporation on either frozen-dried endothelium or on endothelium dried by sublimation of naphthalene with which the tissue had been impregnated. Cell boundaries, stained with silver, were observed in sections and also from the surface by stripping off the inner part of the endothelium. In addition to the usual cytoplasmic organelles, the endothelial cells showed certain characteristic features, namely, large invaginated pockets communicating with the arterial lumen, numerous much smaller vesicular structures immediately under the plasma membrane and apparently also communicating with the lumen, and inclusions, into which injected thorium particles were incorporated. Intercellular boundaries appeared as regular double membranes in thin sections, and they were outlined by a double row of silver granules after silver staining. No evidence was obtained of permeation of intracellular spaces by colloidal thorium.

  11. Fine-scaled human genetic structure revealed by SNP microarrays.

    Science.gov (United States)

    Xing, Jinchuan; Watkins, W Scott; Witherspoon, David J; Zhang, Yuhua; Guthery, Stephen L; Thara, Rangaswamy; Mowry, Bryan J; Bulayeva, Kazima; Weiss, Robert B; Jorde, Lynn B

    2009-05-01

    We report an analysis of more than 240,000 loci genotyped using the Affymetrix SNP microarray in 554 individuals from 27 worldwide populations in Africa, Asia, and Europe. To provide a more extensive and complete sampling of human genetic variation, we have included caste and tribal samples from two states in South India, Daghestanis from eastern Europe, and the Iban from Malaysia. Consistent with observations made by Charles Darwin, our results highlight shared variation among human populations and demonstrate that much genetic variation is geographically continuous. At the same time, principal components analyses reveal discernible genetic differentiation among almost all identified populations in our sample, and in most cases, individuals can be clearly assigned to defined populations on the basis of SNP genotypes. All individuals are accurately classified into continental groups using a model-based clustering algorithm, but between closely related populations, genetic and self-classifications conflict for some individuals. The 250K data permitted high-level resolution of genetic variation among Indian caste and tribal populations and between highland and lowland Daghestani populations. In particular, upper-caste individuals from Tamil Nadu and Andhra Pradesh form one defined group, lower-caste individuals from these two states form another, and the tribal Irula samples form a third. Our results emphasize the correlation of genetic and geographic distances and highlight other elements, including social factors that have contributed to population structure.

  12. Romania's road to Euro zone. From structural balance to structural balance corrected for absorption

    Directory of Open Access Journals (Sweden)

    Aura-Gabriela SOCOL

    2013-02-01

    Full Text Available The sovereign-debt crisis in the European Union has determined the necessity to reform the signal indicators for the analysis of the public finances' sustainability. In this context, many of the developing/emerging countries consider that the informational value provided by the structural budget balance indicator is insufficient, especially during the periods characterized by absorption. The present study suggests the transition from classical structural budget balance (CAB in the structural balance corrected for absorption (CAAB and supports the use of an improved indicator of the structural budget balance with a superior informational relevance for the macro-economic policies decision makers. Based on the economic literature we will demonstrate that the structural budget balance indicator should be improved, in order to also take into consideration the deviation of the current account balance from its sustainable level, particularly in the stage of the economic cycle characterized by high absorption.

  13. Fine structure of bat deep posterior lingual glands (von Ebner's)

    Science.gov (United States)

    Azzali, G; Gatti, R; Bucci, G; Orlandini, G

    1989-10-01

    We studied the morphology and ultrastructure of the bat (Pipistrellus k.k. and Rhinolophus f.e.) deep posterior lingual glands (Ebner's glands) during hibernation, summer and after stimulation with pilocarpine. Ebner's glands are formed by serous tubulo-alveolar adenomeres and by an excretory system organized in intercalated ducts, long excretory ducts and a main excretory duct. The latter opens in the vallum which surrounds the circumvallate papillae and in the groove of the foliate papillae. The secretory cells, which lack basal folds, show abundant and dense granules (PAS+, Alcian blue -), microvilli (scarce during hibernation), a Golgi apparatus (well developed during summer and after stimulation with pilocarpine), a large nucleus and RER cisternae stacked at the basal pole. Centrioles, lipid droplets, heterogeneous bodies (in content and density, probably lipofuscin bodies), lysosomal multivesicular bodies and large, dense granules with a microcrystalline structure were also encountered. The lateral membranes of adjacent cells are joined by desmosomes; their interdigitations are neither numerous nor prominent during summer. Microfilaments, often gathered in small bundles, lie in the lateral, peripheral cytoplasm without any relation with desmosomes. In summer and particularly after stimulation with pilocarpine, the apical pole of the secretory cells is characterized by many long microvilli, pedunculated hyaloplasmic protrusions and secretory granules. During hibernation the lumen is filled with secretory material. Myoepithelial cells are arranged among secretory cells or between them and the basal lamina. The short intercalated ducts show similarities with the analogous ducts of the parotid gland. Striated ducts are absent. Excretory ducts are endowed with: a) an inner layer of cuboidal cells characterized by poorly developed cytoplasmic organelles, rare dense granules and a few small microvilli; b) an outer layer of basal cells lying on the basal lamina

  14. Quantum and classical optics of dispersive and absorptive structured media

    Science.gov (United States)

    Bhat, Navin Andrew Rama

    This thesis presents a Hamiltonian formulation of the electromagnetic fields in structured (inhomogeneous) media of arbitrary dimensionality, with arbitrary material dispersion and absorption consistent with causality. The method is based on an identification of the photonic component of the polariton modes of the system. Although the medium degrees of freedom are introduced in an oscillator model, only the macroscopic response of the medium appears in the derived eigenvalue equation for the polaritons. For both the discrete transparent-regime spectrum and the continuous absorptive-regime spectrum, standard codes for photonic modes in nonabsorptive systems can easily be leveraged to calculate polariton modes. Two applications of the theory are presented: pulse propagation and spontaneous parametric down-conversion (SPDC). In the propagation study, the dynamics of the nonfluctuating part of a classical-like pulse are expressed in terms of a Schrodinger equation for a polariton effective field. The complex propagation parameters of that equation can be obtained from the same generalized dispersion surfaces typically used while neglecting absorption, without incurring additional computational complexity. As an example I characterize optical pulse propagation in an Au/MgF 2 metallodielectric stack, using the empirical response function, and elucidate the various roles of Bragg scattering, interband absorption and field expulsion. Further, I derive the Beer coefficient in causal structured media. The SPDC calculation is rigorous, captures the full 3D physics, and properly incorporates linear dispersion. I obtain an expression for the down-converted state, quantify pair-production properties, and characterize the scaling behavior of the SPDC energy. Dispersion affects the normalization of the polariton modes, and calculations of the down-conversion efficiency that neglect this can be off by 100% or more for common media regardless of geometry if the pump is near the band

  15. Comment on ``Interpretation of the fine structure in the 14C radioactive decay of 223'

    Science.gov (United States)

    Hussonnois, M.; Le Du, J. F.; Brillard, L.; Ardisson, G.

    1991-12-01

    Priority of our interpretation of the fine structure in the 14C radioactive decay of 223Ra is asserted. It seems that the deformation parameter values, used in the framework of ARM to interpret properties of both 223Ra ground and excited states, partly allow for the qualitative interpretation of the experimental hindrance factors to the 209Pb states.

  16. The plasma processes of some solar radio burst and their fine structures on the time

    Science.gov (United States)

    Ning, Z.-J.; Lu, Q.-K.; Fu, Q.-J.; Yan, Y.

    2003-04-01

    We present three special solar radio bursts or fine structures on the frequency band of 1.00-7.60Ghz. Firstly, we study the type III burst pair, which was recorded by spectrometer 1.00-2.00GHz at National Astronomical Observatory of China on Jan. 05, 1994. A plausible model might be thought that this event could be the observational evidence of two electron beams traveling bi-directions simultanuously due to the acceleration of magnetic reconnection in the corona. Secondly, a fine structure of microwave type IV bursts is microwave type M-burst on May 03 1999. Partial N-burst, which is a fine structure of solar III-V bursts recorded on August 251999 by both separated spectrometers 4.50-7.50 GHz at Purple Mountain observatory and 5.20-7.60GHz at NAO respectively, is the third phenomenon studied here. As the N-burst documented before, the last two fine structures are thought to the new observational evidences of electron beam reflected by magnetic mirror in the corona.

  17. Landscape relatedness: detecting contemporary fine-scale spatial structure in wild populations

    DEFF Research Database (Denmark)

    Norman, Anita J; Strønen, Astrid Vik; Fuglstad, Geir-Arne;

    2017-01-01

    Context Methods for detecting contemporary, fine-scale population genetic structure in continuous populations are scarce. Yet such methods are vital for ecological and conservation studies, particularly under a changing landscape. Objectives Here we present a novel, spatially explicit method that...

  18. Simulations of fine structures on the zero field steps of Josephson tunnel junctions

    DEFF Research Database (Denmark)

    Scheuermann, M.; Chi, C. C.; Pedersen, Niels Falsig;

    1986-01-01

    are generated by the interaction of the bias current with the fluxon at the junction edges. On the first zero field step, the voltages of successive fine structures are given by Vn=[h-bar]/2e(2omegap/n), where n is an even integer. Applied Physics Letters is copyrighted by The American Institute of Physics....

  19. MULTIPLET FINE-STRUCTURE IN THE PHOTOEMISSION OF THE GADOLINIUM AND TERBIUM 5P LEVELS

    NARCIS (Netherlands)

    THOLE, BT; WANG, XD; HARMON, BN; LI, DQ; DOWBEN, PA

    1993-01-01

    Fine structure is observed in the photoemission of the gadolinium and terbium 5p levels. The 5p levels are split into multiplets due to spin-orbit splitting and to Coulomb and exchange interactions with the f shell. The calculated theoretical spectra are in good agreement with the experimental resul

  20. Application of X-ray Absorption Spectroscopy to the study of nuclear structural materials

    Science.gov (United States)

    Liu, Shanshan

    One of key technologies for the next generation nuclear systems are advanced materials, including high temperature structural materials, fast neutron resistance core materials and so on. Local structure determination in these systems, which often are crystallographically intractable, is critical to gaining an understanding of their properties. In this thesis, X-ray Absorption Spectroscopy (XAS), including Extended X-ray Absorption Fine Structure (EXAFS) and X-ray Absorption Near Edge Structure (XANES), is used to examine the geometric and electronic structure of nuclear structural materials under varying conditions. The thesis is divided into two main sections. The first examines the structural analysis of nanostructured ferritic alloys (NFA) which are dispersion strengthened by an ultra high density of Y-Ti-O enriched nano-features, resulting in remarkable high temperature creep strength and radiation damage resistance. Titanium and Yttrium K-edge XAS shows commercial alloys MA957 and J12YWT more closely resemble the as received Fe-14Cr-3W-0.4Ti (wt. %) powders, and mechanically alloyed (MA) powders with 0.25Y2O3 (wt. %). It shows that a significant fraction of substitutional Ti remains dissolved in the (BCC) ferrite matrix. In contrast, annealed powders and hot isostatic press (HIP) consolidated alloys show high temperature heat treatments shift the Y and Ti to more oxidized states that are consistent with combinations of Y2Ti2O7 and, especially, TiO. The second section describes corrosion studies of Pb with 316L stainless steel, molybdenum and spinet (MgAl2O4) at high temperature by XAS. The corrosion of fuel cladding and structural materials by liquid lead at elevated temperatures is an issue that must be considered when designing advanced nuclear systems and high-power spallation neutron targets. The results of ex-situ studies show that a Mo substrate retained a smooth and less corroded surface than 316L stainless steel sample at elevated temperature. In

  1. Topological map of the Hofstadter butterfly: Fine structure of Chern numbers and Van Hove singularities

    Energy Technology Data Exchange (ETDEWEB)

    Naumis, Gerardo G., E-mail: naumis@fisica.unam.mx [Departamento de Física–Química, Instituto de Física, Universidad Nacional Autónoma de México (UNAM), Apartado Postal 20-364, 01000 México, Distrito Federal (Mexico); Department of Physics and Astronomy, George Mason University, Fairfax, VA 22030 (United States); Escuela Superior de Física y Matemáticas, ESIA-Zacatenco, Instituto Politécnico Nacional, México D.F. (Mexico)

    2016-04-29

    The Hofstadter butterfly is a quantum fractal with a highly complex nested set of gaps, where each gap represents a quantum Hall state whose quantized conductivity is characterized by topological invariants known as the Chern numbers. Here we obtain simple rules to determine the Chern numbers at all scales in the butterfly fractal and lay out a very detailed topological map of the butterfly by using a method used to describe quasicrystals: the cut and projection method. Our study reveals the existence of a set of critical points that separates orderly patterns of both positive and negative Cherns that appear as a fine structure in the butterfly. This fine structure can be understood as a small tilting of the projection subspace in the cut and projection method and by using a Chern meeting formula. Finally, we prove that the critical points are identified with the Van Hove singularities that exist at every band center in the butterfly landscape. - Highlights: • Use a higher dimensional approach to build a topological map of the Hofstadter butterfly. • There is a fine structure of Chern numbers around each rational flux. • Van Hove singularities are limiting points for topological sequences of the fine flux.

  2. Considering distortion product otoacoustic emission fine structure in measurements of the medial olivocochlear reflex.

    Science.gov (United States)

    Abdala, Carolina; Mishra, Srikanta K; Williams, Tracy L

    2009-03-01

    In humans, when the medial olivocochlear (MOC) pathway is activated by noise in the opposite ear, changes in distortion product otoacoustic emission (DPOAE) level, i.e., the MOC reflex, can be recorded in the test ear. Recent evidence suggests that DPOAE frequency influences the direction (suppression/enhancement) of the reflex. In this study, DPOAEs were recorded at fine frequency intervals from 500 to 2500 Hz, with and without contralateral acoustic stimulation (CAS) in a group of 15 adults. The MOC reflex was calculated only at DPOAE frequencies corresponding to peaks in the fine structure. Additionally, inverse fast-Fourier transform was conducted to evaluate MOC effects on individual DPOAE components. Results show the following: (1) When considering peaks only, the mean MOC reflex was -2.05 dB and 97% of observations reflected suppression, (2) CAS reduced distortion characteristic frequency component levels more than overlap component levels, and (3) CAS produced an upward shift in fine structure peak frequency. Results indicate that when the MOC reflex is recorded at DPOAE frequencies corresponding to fine structure maxima (i.e., when DPOAE components are constructive and in phase), suppression is reliably observed and level enhancement, which probably reflects component mixing in the ear canal rather than strength of the MOC reflex, is eliminated.

  3. Determining the velocity fine structure by a laser anemometer with fixed orientation

    Energy Technology Data Exchange (ETDEWEB)

    Kristensen, Leif; Kirkegaard, P.; Mikkelsen, Torben

    2011-02-15

    We have studied the velocity structure functions and spectra which can be determined by a CW-laser anemometer and a (pulsed) lidar anemometer. We have found useful theoretical expressions for both types of anemometers and compared their filtering of the along-beam turbulent velocity. The purpose has been to establish a basis for remote determining of turbulence fine-structure in terms of the rate of dissipation of specific kinetic energy in the atmospheric boundary layer. (Author)

  4. HRTS observations of the fine structure and dynamics of the solar chromosphere and transition zone

    Science.gov (United States)

    Dere, K. P.

    1983-01-01

    Arc-second UV observations of the Sun by the NRL High Resolution Telescope and Spectrograph (HRTS) have led to the discovery of dynamic fine structures such as 400 km/s coronal jets and chromospheric jets (spicules) and have provided new information about the structure and dynamics of the transition zone. These observations are reviewed and their relevance to the origin of the solar wind is discussed.

  5. Scattering pulse of label free fine structure cells to determine the size scale of scattering structures

    Science.gov (United States)

    Zhang, Lu; Chen, Xingyu; Zhang, Zhenxi; Chen, Wei; Zhao, Hong; Zhao, Xin; Li, Kaixing; Yuan, Li

    2016-04-01

    Scattering pulse is sensitive to the morphology and components of each single label-free cell. The most direct detection result, label free cell's scattering pulse is studied in this paper as a novel trait to recognize large malignant cells from small normal cells. A set of intrinsic scattering pulse calculation method is figured out, which combines both hydraulic focusing theory and small particle's scattering principle. Based on the scattering detection angle ranges of widely used flow cytometry, the scattering pulses formed by cell scattering energy in forward scattering angle 2°-5° and side scattering angle 80°-110° are discussed. Combining the analysis of cell's illuminating light energy, the peak, area, and full width at half maximum (FWHM) of label free cells' scattering pulses for fine structure cells with diameter 1-20 μm are studied to extract the interrelations of scattering pulse's features and cell's morphology. The theoretical and experimental results show that cell's diameter and FWHM of its scattering pulse agree with approximate linear distribution; the peak and area of scattering pulse do not always increase with cell's diameter becoming larger, but when cell's diameter is less than about 16 μm the monotone increasing relation of scattering pulse peak or area with cell's diameter can be obtained. This relationship between the features of scattering pulse and cell's size is potentially a useful but very simple criterion to distinguishing malignant and normal cells by their sizes and morphologies in label free cells clinical examinations.

  6. Les structures fines de l'\\'{e}lectromagn\\'{e}tisme classique et de la relativit\\'{e} restreinte (The fine structures of Classical Electromagnetism and Special Relativity)

    CERN Document Server

    Pierseaux, Y; Pierseaux, Yves; Rousseaux, Germain

    2006-01-01

    One of us (Y.P.) has shown the existence of a longitudinal component in the propagation of light waves on the basis of the kinematics underlying Poincar\\'{e}'s ellipse. We show how this statement agrees with the electromagnetic theory. We recall that the second of us supports the existence of a "fine structure" of Electromagnetism that is, the co-existence of two theories, one based on the fields (Heaviside-Hertz) and the other on the potentials (Riemann-Lorenz). The existence of two different kinematics (the "fine structure" of Special Relativity : Einstein or Poincar\\'{e}) corresponds to these two formulations of Classical Electromagnetism. With this goal in mind, we prove the relativistic covariance of the Helmholtz decomposition of the vector potential. This one translates into a generalized compensation for all directions of propagation, on the basis of the tangent to Poincar\\'{e}'s ellipse, between the scalar potential and the longitudinal component of the vector potential. The adoption by Poincar\\'{e} ...

  7. STRUCTURE STUDIES OF PLATINOTHIONEINS BY USING EXTENDED X—RAY ASSORPTION FINE STRUCTURE SPECTROSCOPY

    Institute of Scientific and Technical Information of China (English)

    BenggangXiang; TiandouHu; 等

    1999-01-01

    The metal binding sites in the two Pt containing metallothioneins (Pt-MT and Pt14MT) were examined by means of Pt(II) L3-edge extended X-ray absorption rine structure(EXAFS) spectroscopy.Comparisons between the phase and amplitude functions derived from the isolated shells to those of Pt…Pt.Pt-S and Pt-N model components showed that each platinum in Pt7MT was coordinated by four sulfur atoms at a distance of 2.31±0.01 A.Analysis of the outer shell data of platinum atom in Pt7MT indicated backscattering platinum atom at approximate 4.29A.Strkingly different structural parameters had been obtained for the Pt14MT species.fitting of the first shell revealed that each platinum was coordinated by two sulfurs at the distance of 2.3-±0.02A and two nitrogens at 2.02±0.02A.The results of the work provided the detailed information concerning the local environments of the coordinated Pt(II) in these two platinothioneins.

  8. Fine Structure Zonal Flow Excitation by Beta-induced Alfven Eigenmode

    CERN Document Server

    Qiu, Zhiyong; Zonca, Fulvio

    2016-01-01

    Nonlinear excitation of low frequency zonal structure (LFZS) by beta-induced Alfven eigenmode (BAE) is investigated using nonlinear gyrokinetic theory. It is found that electrostatic zonal flow (ZF), rather than zonal current, is preferentially excited by finite amplitude BAE. In addition to the well-known meso-scale radial envelope structure, ZF is also found to exhibit fine radial structure due to the localization of BAE with respect to mode rational surfaces. Specifically, the zonal electric field has an even mode structure at the rational surface where radial envelope peaks.

  9. Exciton fine structure splitting in InP quantum dots in GaInP.

    Science.gov (United States)

    Ellström, C; Seifert, W; Pryor, C; Samuelson, L; Pistol, M-E

    2007-07-25

    We have investigated the electronic structure of excitons in InP quantum dots in GaInP. The exciton is theoretically expected to have four states. Two of the states are allowed to optically decay to the ground (vacuum) state in the dipole approximation. We see these two lines in photoluminescence (PL) experiments and find that the splitting between the lines (the fine structure splitting) is 150(± 30) µeV. The lines were perpendicularly polarized. We verified that the lines arise from neutral excitons by using correlation spectroscopy. The theoretical calculations show that the polarization of the emission lines are along and perpendicular to the major axis of elongated dots. The fine structure splitting depends on the degree of elongation of the dots and is close to zero for dots of cylindrical symmetry, despite the influence of the piezoelectric polarization, which is included in the calculation.

  10. The fine structure of Garnia gonadati and its association with the host cell.

    Science.gov (United States)

    Diniz, J A; Silva, E O; Lainson, R; de Souza, W

    2000-12-01

    Most of the studies on the fine structure of protozoa of the Apicomplexa group have been carried out with members of the ToxoPlasma, Eimeria, and Plasmodium genera. In the present study we analyzed the fine structure of Garnia gonadoti parasitizing the red blood cells of the Amazonian reptile Gonatodes humeralis (Reptilia; Lacertilia). Transmission electron microscopy of thin sections showed that G. gonadoti presented all structures characteristic of the group, including the apicoplast. However, four special features were observed: (1) absence of the hemozoin (malarial) pigment; (2) a group of microtubules associated with the mitochondrion; (3) a vacuole containing electron-dense material, which resembled the acidocalcisome described in trypanosomatids; and (4) a special array of the host-cell endoplasmic reticulum around the parasitophorous vacuole.

  11. Temporal integration near threshold fine structure - The role of cochlear processing

    DEFF Research Database (Denmark)

    Epp, Bastian; Mauermann, Manfred; Verhey, Jesko L.

    structure, but lack a decrease of thresholds with increased pulse duration. The model was extended by including a temporal integrator which introduces a low-pass behavior of the data with different slopes of the predicted threshold curves, producing good agreement with the data. On the basis of the model......The hearing thresholds of normal hearing listeners often show quasi-periodic variations when measured with a high frequency resolution. This hearing threshold fine structure is related to other frequency specific variations in the perception of sound such as loudness and amplitude modulated tones...... at low intensities. The detection threshold of a pulsed tone also depends not only on the pulse duration, but also on the position of its frequency within threshold fine structure. The present study investigates if psychoacoustical data on detection of a pulsed tone can be explained with a nonlinear...

  12. Electronic fine structure and recombination dynamics in single InAs quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Seguin, R.

    2008-01-28

    In the work at hand single InAs/GaAs quantum dots (QDs) are examined via cathodoluminescence spectroscopy. A thorough analysis of the spectra leads to an unambiguous assignment of the lines to the decay of specific excitonic complexes. A special aspect of the Coulomb interaction, the exchange interaction, gives rise to a fine structure in the initial and final states of an excitonic decay. This leads to a fine structure in the emission spectra that again is unique for every excitonic complex. The exchange interaction is discussed in great detail in this work.QDs of different sizes are investigated and the influence on the electronic properties is monitored. Additionally, the structure is modified ex situ by a thermal annealing process. The changes of the spectra under different annealing temperatures are traced. Finally, recombination dynamics of different excitonic complexes are examined by performing time-resolved cathodoluminescence spectroscopy. (orig.)

  13. Complete study of excitonic fine-structure splitting in GaN/AlN quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Hoenig, Gerald; Winkelnkemper, Momme; Schliwa, Andrei; Hoffmann, Axel; Bimberg, Dieter [Institut fuer Festkoerperphysik, Technische Universitaet Berlin (Germany); Kindel, Christian [Institut fuer Festkoerperphysik, Technische Universitaet Berlin (Germany); Research Center for Advanced Science and Technology, University of Tokyo (Japan); Kako, Satoshi [Institute for Nano Quantum Information Electronics, University of Tokyo (Japan); Kawano, Takeshi; Oishi, Hiroaki [Research Center for Advanced Science and Technology, University of Tokyo (Japan); Arakawa, Yasuhiko [Research Center for Advanced Science and Technology, University of Tokyo (Japan); Institute for Nano Quantum Information Electronics, University of Tokyo (Japan); Institute of Industrial Science, University of Tokyo, Komaba, Meguro, Tokyo (Japan)

    2010-07-01

    A detailed understanding of the excitonic fine structure in quantum dots (QDs) is indispensable for their use in quantum cryptography devices. While the fine structure in As-based QDs has been studied extensively, there is a lack of such investigations for N-based QDs, which might operate at room temperature. We present the first complete study of excitonic fine-structure splitting (FSS) in GaN/AlN QDs. Our experimental studies reveal a huge FSS of up to 7 meV with a strong dependence on the emission energy inverse to that in As-based QDs. Our theoretical studies, performed with a configuration-interaction method based on realistic 8-band-k.p Hartree-Fock states, confirm the experimental results and identify the origin of FSS as lattice strain induced. Based on our results it is possible to induce a strain gradient (by micro mechanic techniques or structuring methods), which will reduce the FSS to zero for the emission of entangled photon pairs.

  14. Automatic detection and extraction of ultra-fine bright structure observed with new vacuum solar telescope

    Science.gov (United States)

    Deng, Linhua

    2017-02-01

    Solar magnetic structures exhibit a wealth of different spatial and temporal scales. Presently, solar magnetic element is believed to be the ultra-fine magnetic structure in the lower solar atmospheric layer, and the diffraction limit of the largest-aperture solar telescope (New Vacuum Solar Telescope; NVST) of China is close to the spatial scale of magnetic element. This implies that modern solar observations have entered the era of high resolution better than 0.2 arc-second. Since the year of 2011, the NVST have successfully established and obtained huge observational data. Moreover, the ultra-fine magnetic structure rooted in the dark inter-graunlar lanes can be easily resolved. Studies on the observational characteristics and physical mechanism of magnetic bright points is one of the most important aspects in the field of solar physics, so it is very important to determine the statistical and physical parameters of magnetic bright points with the feature extraction techniques and numerical analysis approaches. For identifying such ultra-fine magnetic structure, an automatically and effectively detection algorithm, employed the Laplacian transform and the morphological dilation technique, is proposed and examined. Then, the statistical parameters such as the typical diameter, the area distribution, the eccentricity, and the intensity contrast are obtained. And finally, the scientific meaning for investigating the physical parameters of magnetic bright points are discussed, especially for understanding the physical processes of solar magnetic energy transferred from the photosphere to the corona.

  15. Analysis of microscopic pore structures of rocks before and after water absorption

    Institute of Scientific and Technical Information of China (English)

    Li Dejian; Wang Guilian; Han Liqiang; Liu Peiyu; He Manchao; Yang Guoxing; Tai Qimin; Chen Cheng

    2011-01-01

    Hydrophilic characteristics of rocks are affected by their microscopic pore structures, which clearly change after water absorption. Water absorption tests and scanning electron microscopic (SEM) experiments on rock samples, located at a site in Tibet, China, were carried out. Changes of rock pore structures before and after water absorption were studied with the distribution of pore sizes and fractal characteristics of pores. The results show that surface porosities, fractal dimensions of pores and the complexity of pore structures increased because the number of new small pores produced increased or the original macropore flow channels were expanded after rocks absorbed water. There were points of inflection on their water absorption curves. After water absorption of other rocks, surface porosities and fractal dimensions of pores and complexity of pore structures decreased as the original pore flow channels became filled. Water absorption curves did not change. Surface porosity and the pore fractal dimensions of rocks have good linear relationships before and after water absorption.

  16. Fine-structure-resolved laser-photodetachment electron spectroscopy of In{sup {minus}}

    Energy Technology Data Exchange (ETDEWEB)

    Williams, W.W.; Carpenter, D.L.; Covington, A.M.; Thompson, J.S. [Department of Physics and Chemical Physics Program, University of Nevada, Reno, Nevada, 89557-0058 (United States); Kvale, T.J. [Department of Physics and Astronomy, University of Toledo, Toledo, Ohio, 43606-3390 (United States); Seely, D.G. [Department of Physics, Albion College, Albion, Michigan, 49224 (United States)

    1998-11-01

    The electron affinity of indium has been measured using the laser-photodetachment electron spectroscopy technique. Fine-structure-resolved photoelectron kinetic energy spectra of In{sup {minus}} were analyzed and the electron affinity of In({sup 2}P{sub 1/2}) was determined to be 0.404{plus_minus}0.009 eV. The fine-structure splittings in the ground state of In{sup {minus}}({sup 3}P{sub 0,1,2}) were determined to be 0.076{plus_minus}0.009 eV (J=0{r_arrow}J=1) and 0.175{plus_minus}0.009 eV (J=0{r_arrow}J=2). This measurement is compared to several recent calculations of the electron affinity of indium. {copyright} {ital 1998} {ital The American Physical Society}

  17. Origin of fine structure of the giant dipole resonance in sd-shell nuclei

    CERN Document Server

    Fearick, R W; Matsubara, H; von Neumann-Cosel, P; Richter, A; Roth, R; Tamii, A

    2014-01-01

    A set of high resolution zero-degree inelastic proton scattering data on 24Mg, 28Si, 32S, and 40Ca provides new insight into the long-standing puzzle of the origin of fragmentation of the Giant Dipole Resonance (GDR) in sd-shell nuclei. Understanding is provided by state-of-the-art theoretical Random Phase Approximation (RPA) calculatios for deformed nuclei using for the first time a realistic nucleon-nucleon interaction derived from the Argonne V18 potential with the unitary correlation operator method and supplemented by a phenomenological three-nucleon contact interaction. A wavelet analysis allows to extract significant scales both in the data and calculations characterizing the fine structure of the GDR. The fair agreement supports that the fine structure arises from ground-state deformation driven by alpha clustering.

  18. Fine structural analysis of the stinger in venom apparatus of the scorpion Euscorpius mingrelicus (Scorpiones: Euscorpiidae

    Directory of Open Access Journals (Sweden)

    N Yigit

    2010-01-01

    Full Text Available In this study, the morphology, histology and fine structure of the stinger, a part of the venom apparatus of Euscorpius mingrelicus (Kessler, 1874 (Scorpiones: Euscorpiidae were studied by light microscopy and transmission electron microscopy (TEM. The stinger, located at the end section of the telson, is sickle-shaped. The venom is ejected through a pair of venom pores on its subterminal portion. Both venom ducts extend along the stinger without contact with each other since they are separated by connective tissue cells. The stinger cuticle is composed of two layers. Additionally, there are many pore canals and some hemolymph vessels in the cuticle. This work constitutes the first histological and fine structure study on Euscorpius mingrelicus stinger.

  19. Topological map of the Hofstadter butterfly: Fine structure of Chern numbers and Van Hove singularities

    Science.gov (United States)

    Naumis, Gerardo G.

    2016-04-01

    The Hofstadter butterfly is a quantum fractal with a highly complex nested set of gaps, where each gap represents a quantum Hall state whose quantized conductivity is characterized by topological invariants known as the Chern numbers. Here we obtain simple rules to determine the Chern numbers at all scales in the butterfly fractal and lay out a very detailed topological map of the butterfly by using a method used to describe quasicrystals: the cut and projection method. Our study reveals the existence of a set of critical points that separates orderly patterns of both positive and negative Cherns that appear as a fine structure in the butterfly. This fine structure can be understood as a small tilting of the projection subspace in the cut and projection method and by using a Chern meeting formula. Finally, we prove that the critical points are identified with the Van Hove singularities that exist at every band center in the butterfly landscape.

  20. Solar Cycle Fine Structure and Surface Rotation from Ca II K-Line Time Series Data

    Science.gov (United States)

    Scargle, Jeff; Keil, Steve; Worden, Pete

    2011-01-01

    Analysis of three and a half decades of data from the NSO/AFRL/Sac Peak K-line monitoring program yields evidence for four components to the variation: (a) the solar cycle, with considerable fine structure and a quasi-periodicity of 122.4 days; (b) a stochastic process, faster than (a) and largely independent of it, (c) a quasi-periodic signal due to rotational modulation, and of course (d) observational errors (shown to be quite small). Correlation and power spectrum analyses elucidate periodic and aperiodic variation of these chromospheric parameters. Time-frequency analysis is especially useful for extracting information about differential rotation, and in particular elucidates the connection between its behavior and fine structure of the solar cycle on approximately one-year time scales. These results further suggest that similar analyses will be useful at detecting and characterizing differential rotation in stars from stellar light-curves such as those being produced at NASA's Kepler observatory.

  1. Quasar absorption spectra and the structure of the universe

    Energy Technology Data Exchange (ETDEWEB)

    Doroshkevich, A.G.

    1984-03-01

    Analysis of the spacing between absorption-line systems in quasar spectra and comparison against deep optical survey data for the separation between superclusters of galaxies indicates that the absorption originates in the superclusters. Supported by analogous data on the absorbing gas in the galactic and Magellanic Cloud halos, this inference sharpens theoretical conclusions as to the properties of superclusters. The problem of the unidentified quasar absorption lines is discussed.

  2. Atomic oxygen fine-structure splittings with tunable far-infrared spectroscopy

    Science.gov (United States)

    Zink, Lyndon R.; Evenson, Kenneth M.; Matsushima, Fusakazu; Nelis, Thomas; Robinson, Ruth L.

    1991-01-01

    Fine-structure splittings of atomic oxygen (O-16) in the ground state have been accurately measured using a tunable far-infrared spectrometer. The 3P0-3pl splitting is 2,060,069.09 (10) MHz, and the 3Pl-3P2 splitting is 4,744,777.49 (16) MHz. These frequencies are important for measuring atomic oxygen concentration in earth's atmosphere and the interstellar medium.

  3. Time variation of the fine structure constant in the early universe and the Bekenstein model

    CERN Document Server

    Mosquera, Mercedes E; Landau, Susana J; Vucetich, Hector

    2007-01-01

    We use observational primordial abundances of $\\De$, $\\Het$, $\\He$ and $\\Li$, recent data from the Cosmic Microwave Background and the 2dFGRS power spectrum, to put limits on the variation of the fine structure constant in the early universe. Furthermore, we use these constraints together with other astronomical and geophysical bounds from the late universe to test Bekenstein's model for the variation of $\\alpha$. The model is not able to fit all observational and experimental data.

  4. Fine Structure of Hydrogen Bond in Cholic Acid Revealed by 2DIR Spectroscopy

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Based on cryogenic FT-IR spectroscopic studies of hydrogen bonds in cholic acid, two-dimensional FT-IR spectroscopy was applied to enhance our understanding of the hydrogen bonds of cholic acid. Fine spectral structures were revealed by asynchronous 2D FT-IR spectra. The co-relationship among various bands was discussed according to the synchronous 2D FT-IR spectrum.

  5. Energies, fine structures and transition wavelengths of the core-excited states in Be * ions

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The fine structures of doubly excited resonances of lithium-like beryllium are calculated using the saddle-point and saddle-point complex-rotation methods. A restricted variational method is used to obtain a more accurate value for the nonrelativistic energy. Relativistic and mass polarization corrections to the resonance energy are included. Transition wavelengths are also calculated and compared with other theories and experimental results.

  6. Cosmological implications in electrodynamics due to variations of the fine structure constant

    CERN Document Server

    Martínez-Ledesma, J L

    2002-01-01

    Astronomical observations are strongly suggesting that the fine structure constant varies cosmologically. We present an analysis on the consequences that this variations might induce on the electromagnetic field as a whole. We show that under this circumstances the electrodynamics in vacuum of the universe are described by two fields, the ``standard'' Maxwell's field and a new scalar field. We provide a generalized Lorentz force which can be used to test our results experimentally.

  7. Helium induced fine structure in the electronic spectra of anthracene derivatives doped into superfluid helium nanodroplets

    Energy Technology Data Exchange (ETDEWEB)

    Pentlehner, D.; Slenczka, A., E-mail: alkwin.slenczka@chemie.uni-regensburg.de [Institut für Physikalische und Theoretische Chemie, Universität Regensburg, 93040 Regensburg (Germany)

    2015-01-07

    Electronic spectra of organic molecules doped into superfluid helium nanodroplets show characteristic features induced by the helium environment. Besides a solvent induced shift of the electronic transition frequency, in many cases, a spectral fine structure can be resolved for electronic and vibronic transitions which goes beyond the expected feature of a zero phonon line accompanied by a phonon wing as known from matrix isolation spectroscopy. The spectral shape of the zero phonon line and the helium induced phonon wing depends strongly on the dopant species. Phonon wings, for example, are reported ranging from single or multiple sharp transitions to broad (Δν > 100 cm{sup −1}) diffuse signals. Despite the large number of example spectra in the literature, a quantitative understanding of the helium induced fine structure of the zero phonon line and the phonon wing is missing. Our approach is a systematic investigation of related molecular compounds, which may help to shed light on this key feature of microsolvation in superfluid helium droplets. This paper is part of a comparative study of the helium induced fine structure observed in electronic spectra of anthracene derivatives with particular emphasis on a spectrally sharp multiplet splitting at the electronic origin. In addition to previously discussed species, 9-cyanoanthracene and 9-chloroanthracene will be presented in this study for the first time.

  8. Strong limit on the spatial and temporal variations of the fine-structure constant

    Science.gov (United States)

    Le, T. D.

    2016-10-01

    Observed spectra of quasars provide a powerful tool to test the possible spatial and temporal variations of the fine-structure constant α = e 2/ћc over the history of the Universe. It is demonstrated that high sensitivity to the variation of α can be obtained from a comparison of the spectra of quasars and laboratories. We reported a new constraint on the variation of the fine-structure constant based on the analysis of the optical spectra of the fine-structure transitions in [NeIII], [NeV], [OIII], [OI] and [SII] multiplets from 14 Seyfert 1.5 galaxies. The weighted mean value of the α-variation derived from our analysis over the redshift range 0.035 < z < 0.281 Δα/α= (4.50 +/- 5.53) \\times 10-5. This result presents strong limit improvements on the constraint on Δα/α compared to the published in the literature

  9. Fine-scale Structures of Flux Ropes Tracked by Erupting Material

    CERN Document Server

    Li, Ting

    2013-01-01

    We present the Solar Dynamics Observatory observations of two flux ropes respectively tracked out by material from a surge and a failed filament eruption on 2012 July 29 and August 04. For the first event, the interaction between the erupting surge and a loop-shaped filament in the east seems to "peel off" the filament and add bright mass into the flux rope body. The second event is associated with a C-class flare that occurs several minutes before the filament activation. The two flux ropes are respectively composed of 85$\\pm$12 and 102$\\pm$15 fine-scale structures, with an average width of about 1$\\arcsec$.6. Our observations show that two extreme ends of the flux rope are rooted in the opposite polarity fields and each end is composed of multiple footpoints (FPs) of the fine-scale structures. The FPs of the fine-scale structures are located at network magnetic fields, with magnetic fluxes from 5.6$\\times10^{18}$ Mx to 8.6$\\times10^{19}$ Mx. Moreover, almost half of the FPs show converging motion of smaller...

  10. Structural studies of molecular and metallic overlayers using angle- resolved photoemission extended fine structure

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Z.

    1992-10-01

    Angle-resolved photoemission extended fine structure (ARPEFS) was used to study molecular and metallic overlayers on metal surfaces through analysis of p2mg(2[times]1)CO/Ni(110) and the p(2[times]2)K/Ni(111) adsorption. For the dense p2mg(2[times]1)CO/Ni(110) surface layer, photoemission intensities from C 1s level were measured in three directions at photoelectron kinetic energies 60-400 eV. Using multiple-scattering spherical-wave (MSSW) modeling, it was found that CO molecules are adsorbed on short-bridge sites, with adjacent CO along the [110] direction displaced alternatively in opposite directions towards the [001] azimuths to form a zigzag chain geometry. The tilt angle is 16[plus minus]2[degree] from the surface normal for the direction linking the C atom and the center of the Ni bridge. The carbon C-Ni interatomic distance was determined to be 1.94[plus minus]0.02[Angstrom]. The first- to second-layer spacing of Ni is 1.27[plus minus]0.04[Angstrom], up from 1.10[Angstrom] for the clean Ni(110) surface, but close to the 1.25[Angstrom] Ni interlayer spacing in the bulk. The C-O bond length and tilt angle were varied within small ranges (1.10--1.20[Angstrom] and 15--23[degrees]) in our MSSW simulations. Best agreement between experiment and simulations was achieved at 1.16[Angstrom] and 19[degrees]. This yields an O-O distance of 2.95[Angstrom] for the two nearest CO molecules, (van der Waals' radius [approximately] 1.5 [Angstrom] for oxygen). Two different partial-wave phase-shifts were used in MSSW, and structural results from both are in very good agreement. For the p(2[times]2)K/Ni(111) overlayer, ARPEFS [chi](k) curves from K 1s level measured along [111] and [771] at 130K showed that the K atoms are preferentially adsorbed on the atop sites, in agreement with a LEED study of the same system.

  11. Structural studies of molecular and metallic overlayers using angle- resolved photoemission extended fine structure

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Z.

    1992-10-01

    Angle-resolved photoemission extended fine structure (ARPEFS) was used to study molecular and metallic overlayers on metal surfaces through analysis of p2mg(2{times}1)CO/Ni(110) and the p(2{times}2)K/Ni(111) adsorption. For the dense p2mg(2{times}1)CO/Ni(110) surface layer, photoemission intensities from C 1s level were measured in three directions at photoelectron kinetic energies 60-400 eV. Using multiple-scattering spherical-wave (MSSW) modeling, it was found that CO molecules are adsorbed on short-bridge sites, with adjacent CO along the [110] direction displaced alternatively in opposite directions towards the [001] azimuths to form a zigzag chain geometry. The tilt angle is 16{plus_minus}2{degree} from the surface normal for the direction linking the C atom and the center of the Ni bridge. The carbon C-Ni interatomic distance was determined to be 1.94{plus_minus}0.02{Angstrom}. The first- to second-layer spacing of Ni is 1.27{plus_minus}0.04{Angstrom}, up from 1.10{Angstrom} for the clean Ni(110) surface, but close to the 1.25{Angstrom} Ni interlayer spacing in the bulk. The C-O bond length and tilt angle were varied within small ranges (1.10--1.20{Angstrom} and 15--23{degrees}) in our MSSW simulations. Best agreement between experiment and simulations was achieved at 1.16{Angstrom} and 19{degrees}. This yields an O-O distance of 2.95{Angstrom} for the two nearest CO molecules, (van der Waals` radius {approximately} 1.5 {Angstrom} for oxygen). Two different partial-wave phase-shifts were used in MSSW, and structural results from both are in very good agreement. For the p(2{times}2)K/Ni(111) overlayer, ARPEFS {chi}(k) curves from K 1s level measured along [111] and [771] at 130K showed that the K atoms are preferentially adsorbed on the atop sites, in agreement with a LEED study of the same system.

  12. Bloch oscillations of ultracold atoms and measurement of the fine structure constant; Oscillations de Bloch d'atomes ultrafroids et mesure de la constante de structure fine

    Energy Technology Data Exchange (ETDEWEB)

    Clade, P

    2005-10-15

    From a measurement of the recoil velocity of an atom absorbing a photon, it is possible to deduce a determination of the ratio h/m between the Planck constant and the mass of the atoms and then to deduce a value of the fine structure constant alpha. To do this measurement, we use the technique of Bloch oscillations, which allows us to transfer a large number of recoils to atoms. A velocity sensor, based on velocity selective Raman transition, enables us to measure the momentum transferred to the atoms. A measurement with a statistical uncertainty of 4.4 10{sup -9}, in conjunction with a careful study of systematic effects (5 10{sup -9}), has led us to a determination of alpha with an uncertainty of 6.7 10{sup -9}: {alpha}{sup -1}(Rb) = 137.03599878 (91). This uncertainty is similar to the uncertainty of the best determinations of alpha based on atom interferometry. (author)

  13. Fine-Scale Structure of the Moho From Receiver Functions: Effects of a Deforming Crust

    Science.gov (United States)

    Zandt, G.; Gilbert, H.; Ozacar, A.; Owens, T. J.

    2004-12-01

    Andrija Mohorovicic, a Croatian seismologist, is credited with the first estimation in 1906 of crustal thickness using the critically refracted phase Pn. The crust-mantle boundary has become commonly known as the Moho and its depth, structure, formation, and evolution remains an important research topic in seismology, petrology, and tectonics. Other seismic phases sensitive to Moho depth and structure are the converted phases Ps and Sp, and the associated 2p1s and 1p2s reverberation phases that are isolated in receiver function waveforms. With sufficient station coverage, multiple receiver functions can be migrated and stacked into cross-sections of the crust. Crustal cross-sections from tectonically active regions reveal dramatic variations in amplitude and frequency content of Moho phases that we associate with fine-scale structure, and possibly anisotropy at the crust-mantle boundary. The Moho amplitude or "brightness" is a measure of the crust-mantle impedance contrast, thickness and structure within the crust-mantle boundary, and effects of scattering from 3D structure. Processes directly related to these Moho structures include crustal thickening, crustal extension, crustal flow, delamination or convective removal, and eclogitization. Therefore, the fine-scale seismological structure of the Moho is an important constraint in regional tectonic reconstructions. Examples of receiver function crustal images and their tectonic implications from the western US, South American Andes, and the Tibetan plateau will be reviewed.

  14. Quad-plane stereoscopic PIV for fine-scale structure measurements in turbulence

    Science.gov (United States)

    Naka, Y.; Tomita, K.; Shimura, M.; Fukushima, N.; Tanahashi, M.; Miyauchi, T.

    2016-05-01

    The fine-scale structure in turbulence is investigated by quad-plane stereoscopic particle image velocimetry (QPSPIV). The quad-plane consists of two each of different polarizations and wavelengths, and it provides three velocity components at four independent parallel planes. Measurements have been undertaken in the developed region of a turbulent round jet with a spatial resolution sufficient to capture the small-scale structures. The advantage of the QPSPIV is presented in terms of the spectral response in the evaluation of the out-of-plane velocity gradient. The full velocity gradient tensor is computed with a fourth-order finite difference scheme in the out-of-plane direction as well as the in-plane directions. The turbulence quantities, such as the vorticity components, the energy dissipation rate and the second and third invariants of the velocity gradient tensor, are computed according to their faithful definitions. The coherent fine-scale eddies are extracted from the present QPSPIV data. The probability density functions of the diameter and the maximum azimuthal velocity of the extracted eddies exhibit their peak at approximately 8η and 1.5u_k, respectively, where η and u_k are the Kolmogorov length and velocity. These values agree well with the data in the literature. The phase-averaged distributions of turbulence quantities around the coherent fine-scale eddy indicate an apparent elliptic feature around the axis. Furthermore, the state of the strain rate exerting the eddy is quantified from the phase-averaged distributions of eigenvalues of the strain rate tensor and the alignment of the corresponding eigenvectors against the axis. The present study gives a solid experimental support of the coherent fine-scale structures in turbulence, and the technique can be applied to various flow fields and to the higher Reynolds number condition.

  15. RESEARCH ON TRANSFER OF LIQUID WATER ABSORPTION OF KNITTED STRUCTURES FOR SOCKS DESTINATION

    Directory of Open Access Journals (Sweden)

    VLAD Dorin

    2016-05-01

    Full Text Available For to adjust the heat, body removes heat. Depending on physical effort, it gives more or less moisture. Moisture removed from the body should be taken from the skin and directed outwards through clothing. This can be due to moisture absorption ability, and because of the capillary effect. This study is a part of a very extensive work on the influence of characteristics and raw materials, knitted structure and density on comfort properties of socks. If a high level of perspiration, moisture liquid, it is important that it be removed as quickly from skin and clothing led outside. From here can evaporate into the environment. This is achieved through the capillary effect of fabrics that may effectively transport moisture. Storage capacity and moisture transfer of a textile depends on the composition and structure. In laboratory conditions, methods for assessing the behavior of textiles against moisture is applied differentially depending on the state humidity: vapor or liquid. With this method of determining the capacity of absorbing water by capillary action, samples have dimensions of 200/200 mm and at one end is immersed in water. The samples knit were made in two versions of the fineness machine.

  16. Pulsed EM Field Response of a Thin, High-Contrast, Finely Layered Structure With Dielectric and Conductive Properties

    NARCIS (Netherlands)

    De Hoop, A.T.; Jiang, L.

    2009-01-01

    The response of a thin, high-contrast, finely layered structure with dielectric and conductive properties to an incident, pulsed, electromagnetic field is investigated theoretically. The fine layering causes the standard spatial discretization techniques to solve Maxwell's equations numerically to b

  17. Tailoring the exciton fine structure of cadmium selenide nanocrystals with shape anisotropy and magnetic field.

    Science.gov (United States)

    Sinito, Chiara; Fernée, Mark J; Goupalov, Serguei V; Mulvaney, Paul; Tamarat, Philippe; Lounis, Brahim

    2014-11-25

    We use nominally spheroidal CdSe nanocrystals with a zinc blende crystal structure to study how shape perturbations lift the energy degeneracies of the band-edge exciton. Nanocrystals with a low degree of symmetry exhibit splitting of both upper and lower bright state degeneracies due to valence band mixing combined with the isotropic exchange interaction, allowing active control of the level splitting with a magnetic field. Asymmetry-induced splitting of the bright states is used to reveal the entire 8-state band-edge fine structure, enabling complete comparison with band-edge exciton models.

  18. Electronic and lattice structures in SmFeAsO1-xFx probed by x-ray absorption spectroscopy

    Science.gov (United States)

    Zhang, C. J.; Oyanagi, H.; Sun, Z. H.; Kamihara, Y.; Hosono, H.

    2010-03-01

    Local lattice and electronic structures in the Fe-As layer of SmFeAsO1-xFx superconductors were studied by x-ray absorption spectroscopy, the FeK -edge and the AsK -edge extended x-ray absorption fine-structure, and x-ray absorption near-edge-structure experiments, respectively. Temperature-dependent local lattice distortions were observed in the Fe-As bond mean-square relative displacement of the superconducting samples. A strong coupling of the carrier-induced local lattice distortion (polaron) to the superconducting transition temperature in the oxypnictide superconductors is indicated. The near-edge spectra showed systematic temperature-dependent energy shifts, which indicate an intralayer electron redistribution from Fed states to Asp states due to orbital-selective band filling at low temperatures.

  19. X-ray Absorption Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Yano, Junko; Yachandra, Vittal K.

    2009-07-09

    This review gives a brief description of the theory and application of X-ray absorption spectroscopy, both X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS), especially, pertaining to photosynthesis. The advantages and limitations of the methods are discussed. Recent advances in extended EXAFS and polarized EXAFS using oriented membranes and single crystals are explained. Developments in theory in understanding the XANES spectra are described. The application of X-ray absorption spectroscopy to the study of the Mn4Ca cluster in Photosystem II is presented.

  20. Speciation of arsenic in pyrite by micro-X-ray absorption fine- structure spectroscopy (XAFS)

    Energy Technology Data Exchange (ETDEWEB)

    Paktunc, D. (CCM)

    2008-09-30

    Pyrite (FeS2) often contains variable levels of arsenic, regardless of the environment of formation. Arsenian pyrite has been reported in coals, sediments and ore deposits. Arsenian pyrite having As concentrations of up to 10 wt % in sedimentary rocks (Kolker et al. 1997), about 10 wt% in gold deposits (Fleet et al. 1993), 12 wt % in a refractory gold ore (Paktunc et al. 2006) and 20 wt % in a Carlin-type gold deposit in Nevada (Reich et al. 2005) have been reported. Arsenian pyrite is the carrier of gold in hydrothermal Carlin-type gold deposits, and gold concentrations of up to 0.9 wt % have been reported (Reich et al. 2005; Paktunc et al. 2006). In general, high Au concentrations correlate with As-rich zones in pyrite (Paktunc et al. 2006). Pyrite often ends up in mining and metallurgical wastes as an unwanted mineral and consititutes one of the primary sources of As in the wastes. Arsenic can be readily released to the environment due to rapid oxidative dissolution of host pyrite under atmospheric conditions. Pyrite is also the primary source of arsenic in emissions and dust resulting from combustion of bituminous coals. Despite the importance of arsenian pyrite as a primary source of anthropogenic arsenic in the environment and its economic significance as the primary carrier of gold in Carlin-type gold deposits, our understanding of the nature of arsenic in pyrite is limited. There are few papers dealing with the mode of occurrence of arsenic by bulk XAFS in a limited number of pyrite-bearing samples. The present study documents the analysis of pyrite particles displaying different morphologies and a range of arsenic and gold concentrations to determine the nature and speciation of arsenic.

  1. Electronic structure and optical properties of CdS{sub x}Se{sub 1−x} solid solution nanostructures from X-ray absorption near edge structure, X-ray excited optical luminescence, and density functional theory investigations

    Energy Technology Data Exchange (ETDEWEB)

    Murphy, M. W. [DESY (Deutsches Elektronen-Synchrotron), FS-PEX, Notkestrasse 85, 22607 Hamburg (Germany); Yiu, Y. M., E-mail: yyiu@uwo.ca; Sham, T. K. [Department of Chemistry, University of Western Ontario, London, ON N6A5B7 (Canada); Ward, M. J. [Cornell High Energy Synchrotron Source (CHESS), Cornell University, Ithaca, NY 14853 (United States); Liu, L. [Institute of Functional Nano and Soft Materials (FUNSOM) and Soochow University-Western University Center for Synchrotron Radiation Research, Soochow University, Suzhou, Jiangsu, 215123 (China); Hu, Y. [Canadian Light Source, University of Saskatchewan, Saskatoon, SK S7N2V3 (Canada); Zapien, J. A. [Center Of Super-Diamond and Advanced Films (COSDAF) and Department of Physics and Materials Science, City University of Hong Kong, Hong Kong SAR (China); Liu, Yingkai [Institute of Physics and Electronic Information, Yunnan Normal University, Kunming, Yunnan, 650500 (China)

    2014-11-21

    The electronic structure and optical properties of a series of iso-electronic and iso-structural CdS{sub x}Se{sub 1−x} solid solution nanostructures have been investigated using X-ray absorption near edge structure, extended X-ray absorption fine structure, and X-ray excited optical luminescence at various absorption edges of Cd, S, and Se. It is found that the system exhibits compositions, with variable local structure in-between that of CdS and CdSe accompanied by tunable optical band gap between that of CdS and CdSe. Theoretical calculation using density functional theory has been carried out to elucidate the observations. It is also found that luminescence induced by X-ray excitation shows new optical channels not observed previously with laser excitation. The implications of these observations are discussed.

  2. Experimental demonstration of broadband absorption enhancement in partially aperiodic silicon nanohole structures

    CERN Document Server

    Lin, Chenxi; Povinelli, Michelle L

    2013-01-01

    We report the design, fabrication, and optical absorption measurement of silicon membranes patterned with partially aperiodic nanohole structures. We demonstrate excellent agreement between measurement and simulations. We optimize a partially aperiodic structure using a random walk algorithm and demonstrate an experimental broadband absorption of 4.9 times that of a periodic array.

  3. Fine structure in the {alpha}-decay of odd-even nuclei

    Energy Technology Data Exchange (ETDEWEB)

    Santhosh, K.P., E-mail: drkpsanthosh@gmail.com [School of Pure and Applied Physics, Kannur University, Payyanur Campus, Payyanur 670 327 (India); Joseph, Jayesh George; Priyanka, B. [School of Pure and Applied Physics, Kannur University, Payyanur Campus, Payyanur 670 327 (India)

    2012-03-01

    Systematic study on {alpha}-decay fine structure is presented for the first time in the case of odd-even nuclei in the range 83 Less-Than-Or-Slanted-Equal-To Z Less-Than-Or-Slanted-Equal-To 101. The model used for the study is the recently proposed Coulomb and proximity potential model for deformed nuclei (CPPMDN), which employs deformed Coulomb potential, deformed two term proximity potential and centrifugal potential. The computed partial half-lives, total half-lives and branching ratios are compared with experimental data and are in good agreement. The standard deviation of partial half-life is 1.08 and that for branching ratio is 1.21. Our formalism is also successful in predicting angular momentum hindered and structure hindered transitions. The present study reveals that CPPMDN is successful in explaining alpha-decay from ground and isomeric state; and alpha fine structure of even-even, even-odd and odd-even nuclei. Our study relights that the differences in the parent and daughter surfaces or the changes in the deformation parameters as well as the shell structure of the parent and daughter nuclei, influences the alpha decay probability.

  4. Lack of sex-biased dispersal promotes fine-scale genetic structure in alpine ungulates

    Science.gov (United States)

    Roffler, Gretchen H.; Talbot, Sandra L.; Luikart, Gordon; Sage, George K.; Pilgrim, Kristy L.; Adams, Layne G.; Schwartz, Michael K.

    2014-01-01

    Identifying patterns of fine-scale genetic structure in natural populations can advance understanding of critical ecological processes such as dispersal and gene flow across heterogeneous landscapes. Alpine ungulates generally exhibit high levels of genetic structure due to female philopatry and patchy configuration of mountain habitats. We assessed the spatial scale of genetic structure and the amount of gene flow in 301 Dall’s sheep (Ovis dalli dalli) at the landscape level using 15 nuclear microsatellites and 473 base pairs of the mitochondrial (mtDNA) control region. Dall’s sheep exhibited significant genetic structure within contiguous mountain ranges, but mtDNA structure occurred at a broader geographic scale than nuclear DNA within the study area, and mtDNA structure for other North American mountain sheep populations. No evidence of male-mediated gene flow or greater philopatry of females was observed; there was little difference between markers with different modes of inheritance (pairwise nuclear DNA F ST = 0.004–0.325; mtDNA F ST = 0.009–0.544), and males were no more likely than females to be recent immigrants. Historical patterns based on mtDNA indicate separate northern and southern lineages and a pattern of expansion following regional glacial retreat. Boundaries of genetic clusters aligned geographically with prominent mountain ranges, icefields, and major river valleys based on Bayesian and hierarchical modeling of microsatellite and mtDNA data. Our results suggest that fine-scale genetic structure in Dall’s sheep is influenced by limited dispersal, and structure may be weaker in populations occurring near ancestral levels of density and distribution in continuous habitats compared to other alpine ungulates that have experienced declines and marked habitat fragmentation.

  5. Indirect estimation of absorption properties for fine aerosol particles using AATSR observations: a case study of wildfires in Russia in 2010

    Science.gov (United States)

    Rodriguez, E.; Kolmonen, P.; Virtanen, T. H.; Sogacheva, L.; Sundstrom, A.-M.; de Leeuw, G.

    2015-08-01

    The Advanced Along-Track Scanning Radiometer (AATSR) on board the ENVISAT satellite is used to study aerosol properties. The retrieval of aerosol properties from satellite data is based on the optimized fit of simulated and measured reflectances at the top of the atmosphere (TOA). The simulations are made using a radiative transfer model with a variety of representative aerosol properties. The retrieval process utilizes a combination of four aerosol components, each of which is defined by their (lognormal) size distribution and a complex refractive index: a weakly and a strongly absorbing fine-mode component, coarse mode sea salt aerosol and coarse mode desert dust aerosol). These components are externally mixed to provide the aerosol model which in turn is used to calculate the aerosol optical depth (AOD). In the AATSR aerosol retrieval algorithm, the mixing of these components is decided by minimizing the error function given by the sum of the differences between measured and calculated path radiances at 3-4 wavelengths, where the path radiances are varied by varying the aerosol component mixing ratios. The continuous variation of the fine-mode components allows for the continuous variation of the fine-mode aerosol absorption. Assuming that the correct aerosol model (i.e. the correct mixing fractions of the four components) is selected during the retrieval process, also other aerosol properties could be computed such as the single scattering albedo (SSA). Implications of this assumption regarding the ratio of the weakly/strongly absorbing fine-mode fraction are investigated in this paper by evaluating the validity of the SSA thus obtained. The SSA is indirectly estimated for aerosol plumes with moderate-to-high AOD resulting from wildfires in Russia in the summer of 2010. Together with the AOD, the SSA provides the aerosol absorbing optical depth (AAOD). The results are compared with AERONET data, i.e. AOD level 2.0 and SSA and AAOD inversion products. The RMSE

  6. INFLUENCE OF FINE-DISPERSED BORON CARBIDE ON THE STRUCTURE AND CHARACTERISTICS OF IRON-BORON ALLOY

    Directory of Open Access Journals (Sweden)

    N. F. Nevar

    2010-01-01

    Full Text Available The influence of boron carbide as fine-dispersed material input into the melt on structure morphology, founding, technological and exploitation characterisstics of cast iron-boron material is shown.

  7. Fine Structure in the Mm-Wavelength Spectra of the Active Region

    Science.gov (United States)

    Sawant, H. S.; Cecatto, J. R.

    1990-11-01

    RESUMEN. Faltan observaciones solares espectrosc6picas en la longitud de onda milimetrica. Hay sugerencias de que se puede superponer una fi na estructura en frecuencia a la componente-S de la regi6n solar activa, asi como a la componente del brote en las longitudes de onda milimetri- cas. Se ha desarrollado un receptor de alta sensibilidad de pasos de frecuencia que opera en el intervalo de 23-18 GHz con una resoluci6n de 1 GHz y resoluci6n de tiempo variable entre 1.2 y 96 sec, usando la an- tena de Itapetinga de 13.7-m para estudiar la estructura fina en frecuencia y tiempo. Discutimos el espectro en longitud de onda-mm en re- giones activas y su evoluci6n en el tiempo. El estudio de Ia evoluci6n en el tiempo de la regi6n activa en AR 5569 observada el 29 de junio de 1989, sugiere la existencia de estructuras finas como funci6n deltiempo. ABSTRACT. There is a lack of mm-wavelength spectroscopic solar observations. There are suggestions that a fine structure in frequency may be superimposed on the S-component of solar active region as well as on the burst component at inm-wavelengths. To study fine structure in frequency and time, a high sensitivity step frequency receiver operating in the frequency range 23-18 GHz with frequency resolution of 1 GHz and variable time resolution 1.2 to 96 sec, using 13.7 m diameter Itapetinga radome covered antenna, has been developed. Here, we discuss mm-wavelength spectra of active regions and their time evolution. Study of time evolution of an active region AR 5569 observed on 29th June, 1989 suggests existence of fine structures as a function of time. ( Ck : SUN-ACTIVITY - SUN-RADIO RADIATION

  8. Boron carbide: Consistency of components, lattice parameters, fine structure and chemical composition makes the complex structure reasonable

    Science.gov (United States)

    Werheit, Helmut

    2016-10-01

    The complex, highly distorted structure of boron carbide is composed of B12 and B11C icosahedra and CBC, CBB and B□B linear elements, whose concentration depends on the chemical composition each. These concentrations are shown to be consistent with lattice parameters, fine structure data and chemical composition. The respective impacts on lattice parameters are estimated and discussed. Considering the contributions of the different structural components to the energy of the overall structure makes the structure and its variation within the homogeneity range reasonable; in particular that of B4.3C representing the carbon-rich limit of the homogeneity range. Replacing in B4.3C virtually the B□B components by CBC yields the hypothetical moderately distorted B4.0C (structure formula (B11C)CBC). The reduction of lattice parameters related is compatible with recently reported uncommonly prepared single crystals, whose compositions deviate from B4.3C.

  9. The fine structure of muscle attachments in a spider (Latrodectus mactans, Fabr.).

    Science.gov (United States)

    Smith, D S; Järlfors, U; Russell, F E

    1969-01-01

    The fine structure of a spider myo-apodeme junction is described, and discussed in terms of other arthropod muscle attachments. This is contrasted with the situation in the venom gland, equipped with muscle fibers that control expulsion of the secreted material. The latter involves a cell-free collagenous matrix, lying between the muscle cells and the sheath of the gland. As in other arthropods, skeletal fibers are attached to the apodeme cuticle via specialized epidermal cells, containing oriented microtubules. Interdigitations between these cells and muscle, basally, and cuticle, apically, are described. Extracellular tonofibrillae described elsewhere are inconspicuous in the apodeme cuticle.

  10. Variation of the fine-structure constant from the de Sitter invariant special relativity

    Institute of Scientific and Technical Information of China (English)

    CHEN Shao-Xia; XIAO Neng-Chao; YAN Mu-Lin

    2008-01-01

    We discuss the variation of the fine-structure constant,α.There are obvious discrepancies among the results of α-variation from recent Quasi-stellar observation experiments and from the Oklo uranium mine analysis.We use dS Sitter invariant Special Relativity (SRc,R) and Dirac large number hypothesis to discuss this puzzle,and present a possible solution to the disagreement.By means of the observational data and the discussions presented in this paper,we estimate the radius of the Universe in SRc,R which is about ~2(√5)×1011l.y.

  11. Evolution of the fine-structure constant in runaway dilaton models

    Directory of Open Access Journals (Sweden)

    C.J.A.P. Martins

    2015-04-01

    Full Text Available We study the detailed evolution of the fine-structure constant α in the string-inspired runaway dilaton class of models of Damour, Piazza and Veneziano. We provide constraints on this scenario using the most recent α measurements and discuss ways to distinguish it from alternative models for varying α. For model parameters which saturate bounds from current observations, the redshift drift signal can differ considerably from that of the canonical ΛCDM paradigm at high redshifts. Measurements of this signal by the forthcoming European Extremely Large Telescope (E-ELT, together with more sensitive α measurements, will thus dramatically constrain these scenarios.

  12. X-ray reflection anomalous fine structure analysis of the stability of permalloy/copper multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Luo, G.M.; Mai, Z.H.; Hase, T.P.A. E-mail: t.p.a.hase@dur.ac.uk; Fulthorpe, B.D.; Tanner, B.K.; Marrows, C.H.; Hickey, B.J

    2001-05-01

    We report the application of reflection anomalous fine structure analysis to the study of the changes in the layer density and local environment in sputtered permalloy/copper multilayers. By fitting the smoothly varying component of the plot of multilayer Bragg peak intensity versus incident X-ray energy, we find a strained permalloy layer at the permalloy/copper but not the copper/permalloy interface. The density difference between copper and strained permalloy layers increases on annealing at 275 deg. C and from the oscillatory component of the spectrum, we show that it is the nearest-neighbour distance around the Ni atoms which decreases.

  13. Evolution of the fine-structure constant in runaway dilaton models

    Energy Technology Data Exchange (ETDEWEB)

    Martins, C.J.A.P., E-mail: Carlos.Martins@astro.up.pt [Centro de Astrofísica, Universidade do Porto, Rua das Estrelas, 4150-762 Porto (Portugal); Instituto de Astrofísica e Ciências do Espaço, CAUP, Rua das Estrelas, 4150-762 Porto (Portugal); Vielzeuf, P.E., E-mail: pvielzeuf@ifae.es [Institut de Física d' Altes Energies, Universitat Autònoma de Barcelona, E-08193 Bellaterra (Barcelona) (Spain); Martinelli, M., E-mail: martinelli@thphys.uni-heidelberg.de [Institute for Theoretical Physics, University of Heidelberg, Philosophenweg 16, 69120, Heidelberg (Germany); Calabrese, E., E-mail: erminia.calabrese@astro.ox.ac.uk [Sub-department of Astrophysics, University of Oxford, Keble Road, Oxford OX1 3RH (United Kingdom); Pandolfi, S., E-mail: stefania@dark-cosmology.dk [Dark Cosmology Centre, Niels Bohr Institute, University of Copenhagen, Juliane Maries Vej 30, DK-2100 Copenhagen (Denmark)

    2015-04-09

    We study the detailed evolution of the fine-structure constant α in the string-inspired runaway dilaton class of models of Damour, Piazza and Veneziano. We provide constraints on this scenario using the most recent α measurements and discuss ways to distinguish it from alternative models for varying α. For model parameters which saturate bounds from current observations, the redshift drift signal can differ considerably from that of the canonical ΛCDM paradigm at high redshifts. Measurements of this signal by the forthcoming European Extremely Large Telescope (E-ELT), together with more sensitive α measurements, will thus dramatically constrain these scenarios.

  14. Morphology, fine structure, biochemistry, and function of the spermatic ducts in marine fish.

    Science.gov (United States)

    Lahnsteiner, Franz

    2003-10-01

    The spermatic ducts and the testicular efferent ducts were investigated in different marine teleost fish species (Diplodus sargus, Mullus barbatus, Thalassoma pavo, Trachinus draco, Uranuscopus scaber, Sparisoma cretense, Synodon saurus). From the morphological, histological, fine structural and biochemical investigations it appeared that the testicular main ducts and spermatic ducts of the investigated marine fish have the following functions: storage of spermatozoa, monosacharide synthesis for nutrition of spermatozoa, synthesis of steroid glucuronides, synthesis of seminal plasma proteins, formation of a ionic gradient in the seminal fluid and phagocytotic activity. Species-specific differences were only found in the morphology of the gonads and in the histology of the spermatic duct epithelium.

  15. Effect of heat treatment on the fine structure and properties of a niobium-base superalloy

    Science.gov (United States)

    Shaboldo, O. P.; Vitorskii, Ya. M.; Sagaradze, V. V.; Volkova, E. G.

    2016-12-01

    The effect of conditions of heat treatment on the microstructure and mechanical characteristics of an LN-1 alloy (Nb-10W-5Mo-1.5Zr-0.15C), which is used to produce high-temperature springs, has been studied. The temperature conditions of annealing of the alloy have been chosen, under which the fairly high ductility needed for the subsequent deformation of the alloy is achieved. Structural examinations have revealed the formation of fine niobium-zirconium carbides in the matrix in the course of the thermomechanical strengthening of the alloy, which involves preannealing.

  16. Ground-based and spaceborn observations of the type II burst with developed fine structure

    Science.gov (United States)

    Dorovskyy, V.; Melnik, V.; Konovalenko, A.; Brazhenko, A.; Rucker, H.; Stanislavskyy, A.; Panchenko, M.

    2012-09-01

    The combination of two huge ground-based radio telescopes (UTR-2 and URAN-2) operated in decameter wavelengths with three spatially separated spacecrafts (SOHO, STEREO-A and STEREO-B) equipped with white light coronagraphs, UV telescopes and decameter-hectometer band radio telescopes created a unique opportunity to investigate the high energy solar transients, such as CMEs and their manifestations in radio bands - type II bursts. In this paper we made detailed analysis of the powerful and complex event occurred on 7 June 2011 consisted of Halo-CME and type II burst with rich fine structure.

  17. A Note on Transfinite M Theory and the Fine Structure Constant

    CERN Document Server

    Castro, C

    2001-01-01

    In this short note, using notions from $p$-Adic QFT and $p$-branes, we derive the transfinite M $theoretical$ corrections $(\\alpha_M)^{-1} = 100 + 61 \\phi$ to El Naschie's inverse fine structure constant value $(\\alpha_{HS})^{-1}= 100 + 60\\phi$ which was based on a transfinite Heterotic string theory ormalism . $\\phi$ is the Golden Mean $0.6180339...$. Our results are consistent with recent Astrophysical observations of he Boomerang and Maxima experiments, with previous results based on the four dimensional gravitational conformal anomaly calculations and with an enhanced hierarchy of the number of lines on Del Pezzo surfaces.

  18. Tuning Photoluminescence Energy and Fine Structure Splitting in Single Quantum Dots by Uniaxial Stress

    Institute of Scientific and Technical Information of China (English)

    DOU Xiu-Ming; SUN Bao-Quan; WANG Bao-Rui; MA Shan-Shan; ZHOU Rong; HUANG She-Song; NI Hai-Qiao; NIU Zhi-Chuan

    2008-01-01

    @@ We report a photoluminescence (PL) energy red-shift of single quantum dots(QDs)by applying an in-plane compressive uniaxial stress along the[110]direction at a liquid nitrogen temperature.Uniaxial stress has an effect not only on the confinement potential in the growth direction which results in the PL shift,but also on the cylindrical symmetry of QDs which can be reflected by the change of the full width at half maximum of PL peak.This implies that uniaxial stress has an important role in tuning PL energy and fine structure splitting of QDs.

  19. The fine structure levels for ground states of negative ions of nitrogen and phosphorus

    Directory of Open Access Journals (Sweden)

    Leyla Özdemir

    2013-01-01

    Full Text Available The fine structure levels for negative ions (anions of nitrogen and phosphorus have been investigated using multiconfiguration Hartree-Fock method within the framework of Breit-Pauli Hamiltonian (MCHF+BP. Nitrogen and phosphorus have half-filled outer shell in ground state 1s22s22p3 4S and 1s22s22p33s23p3 4S, respectively. It has been stated in most works that the negative ion of nitrogen is instable whereas the negative ion of phosphorus is stable. The results obtained have been compared with other works.

  20. Time Variation of the Fine Structure Constant in the Spacetime of a Cosmic Domain Wall

    Science.gov (United States)

    Campanelli, L.; Cea, P.; Tedesco, L.

    The gravitational field produced by a domain wall acts as a medium with spacetime-dependent permittivity ɛ. Therefore, the fine structure constant α=e2/4πɛ will be a time-dependent function at fixed position. The most stringent constraint on the time-variation of α comes from the natural reactor Oklo and gives |˙ α /α | < few × 10-17 yr-1. This limit constrains the tension of a cosmic domain wall to be less than σ ≲ 10-2 MeV3, and then represents the most severe limit on the energy density of a cosmic wall stretching our Universe.

  1. Time Variation of the Fine Structure Constant in the Spacetime of a Domain Wall

    CERN Document Server

    Campanelli, L; Tedesco, L

    2005-01-01

    The gravitational field produced by a domain wall acts as a medium with spacetime-dependent permittivity \\epsilon. Therefore, the fine structure constant \\alpha = e^2/4 \\pi \\epsilon will be a time-dependent function at fixed position. The most stringent constraint on the time-variation of \\alpha comes from the natural reactor Oklo and gives |\\dot{\\alpha}/\\alpha| < few 10^{-17} yr^{-1}. This limit constrains the tension of a cosmic domain wall to be less than \\sigma \\lesssim 10^{-2} MeV^3, and then represents the most severe limit on the energy density of a cosmic wall stretching our Universe.

  2. Evolution of the fine-structure constant in runaway dilaton models

    CERN Document Server

    Martins, C J A P; Martinelli, M; Calabrese, E; Pandolfi, S

    2015-01-01

    We study the detailed evolution of the fine-structure constant $\\alpha$ in the string-inspired runaway dilaton class of models of Damour, Piazza and Veneziano. We provide constraints on this scenario using the most recent $\\alpha$ measurements and discuss ways to distinguish it from alternative models for varying $\\alpha$. For model parameters which saturate bounds from current observations, the redshift drift signal can differ considerably from that of the canonical $\\Lambda$CDM paradigm at high redshifts. Measurements of this signal by the forthcoming European Extremely Large Telescope (E-ELT), together with more sensitive $\\alpha$ measurements, will thus dramatically constrain these scenarios.

  3. Calculation of the fine structure of the level in Rydberg state of lithium

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    The level shift and level formula of lithium atom in Rydberg states are achieved by means of the calculation of polarization of the atomic core (including the contribution of dipole moment, quadrupole moment and octupole moment);meanwhile, the effect of relativity theory, the orbital angular momentum L and the spin angular momentum S coupling (LS coupling), and high order correction of the effective potential are considered. The some fine structures (N=5~12,L=4~9,J=L±1/2) and the corresponding level intervals in Rydberg states can be calculated by the above-mentioned level formula and compared with correlated experimental data.

  4. Anisotropic Beam Model for the Spectral Observations of Radio Burst Fine Structures on 1998 April 15

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    A fine structure consisting of three almost equidistant frequency bands was observed in the high frequency part of a solar burst on 1998 April 15 by the spectrometer of Beijing Astronomical Observatory in the range 2.6-3.8 GHz. A model for this event based on beam-anisotropic instability in the solar corona is presented. Longitudinal plasma waves are excited at cyclotron resonance and then transformed into radio emission at their second harmonic. The model is in accordance with the observations if we suppose a magnetic field strength in the region of emission generation of about 200 G.

  5. Oklo Constraint on the Time-Variability of the Fine-Structure Constant

    CERN Document Server

    Fujii, Y

    2003-01-01

    The Oklo phenomenon, natural fission reactors which had taken place in Gabon about 2 billion years ago, porvides one of the most stringent constraints on the possible time-variability of the fine-structure constant $\\alpha$. We first review briefly what it is and how reliable it is in constraining $\\alpha$. We then compare the result with a more recent result on the nonzero change of $\\alpha$ obtained from the observation of the QSO absoorption lines. We suggest a possible way to make these results consistent with each other in terms of the behavior of a scalar field which is expected to be responsible for the accelaration of the universe.

  6. Time Evolution of the Fine Structure Constant in a Two-Field Quintessence Model

    CERN Document Server

    Bento, M C; Santos, N M C

    2004-01-01

    We examine the variation of the fine structure constant in the context of a two-field quintessence model. We find that, for solutions that lead to a transient late period of accelerated expansion, it is possible to fit the data arising from quasar spectra and comply with the bounds on the variation of $\\alpha$ from the Oklo reactor, meteorite analysis, atomic clock measurements, Cosmic Microwave Background Radiation and Big Bang Nucleosynthesis. That is more difficult if we consider solutions corresponding to a late period of permanent accelerated expansion.

  7. Time evolution of the fine structure constant in a two-field quintessence model

    Science.gov (United States)

    Bento, M. C.; Bertolami, O.; Santos, N. M.

    2004-11-01

    We examine the variation of the fine structure constant in the context of a two-field quintessence model. We find that, for solutions that lead to a transient late period of accelerated expansion, it is possible to fit the data arising from quasar spectra and comply with the bounds on the variation of α from the Oklo reactor, meteorite analysis, atomic clock measurements, cosmic microwave background radiation, and big bang nucleosynthesis. That is more difficult if we consider solutions corresponding to a late period of permanent accelerated expansion.

  8. Enhanced laboratory sensitivity to variation of the fine-structure constant using highly charged ions.

    Science.gov (United States)

    Berengut, J C; Dzuba, V A; Flambaum, V V

    2010-09-17

    We study atomic systems that are in the frequency range of optical atomic clocks and have enhanced sensitivity to potential time variation of the fine-structure constant α. The high sensitivity is due to coherent contributions from three factors: high nuclear charge Z, high ionization degree, and significant differences in the configuration composition of the states involved. Configuration crossing keeps the frequencies in the optical range despite the large ionization energies. We discuss a few promising examples that have the largest α sensitivities seen in atomic systems.

  9. Prospect of China's Auroral Fine-structure Imaging System (CAFIS) at Zhongshan station in Antarctica

    Institute of Scientific and Technical Information of China (English)

    LIU Shun-lin; HAN De-sheng; HU Hong-qiao; HUANG De-hong; ZHANG Bei-chen; YANG Hui-gen

    2008-01-01

    A new auroral imaging system is reported which is planned to be deployed at Zhongshan Station in Antarctica in the end of 2009. The system will focus on study of optical auroras in small scales and be called China' s Auroral Fine-structure Imaging System (CAFIS). The project of CAFIS is carried out by support of 'the tenth five-year plan for capacity building' of China. CAFIS will be a powerful groundbased platform for aurora observational experiments. Composing and advantages of CAFIS are introduced in this brief report. Some potential study topics involved CAFIS are also considered.

  10. Fine structure in the {\\alpha}-decay of odd-even nuclei

    CERN Document Server

    Santhosh, K P; Priyanka, B

    2012-01-01

    Systematic study on {\\alpha}-decay fine structure is presented for the first time in the case of odd-even nuclei in the range 83 \\leq Z \\leq 101. The model used for the study is the recently proposed Coulomb and proximity potential model for deformed nuclei (CPPMDN), which employs deformed Coulomb potential, deformed two term proximity potential and centrifugal potential. The computed partial half lives, total half lives and branching ratios are compared with experimental data and are in good agreement. The standard deviation of partial half-life is 1.08 and that for branching ratio is 1.21. Our formalism is also successful in predicting angular momentum hindered and structure hindered transitions. The present study reveals that CPPMDN is a unified theory which is successful in explaining alpha decay from ground and isomeric state; and alpha fine structure of even-even, even-odd and odd-even nuclei. Our study relights that the differences in the parent and daughter surfaces or the changes in the deformation p...

  11. Fine and Superfine Structure of the Decameter-Hectometer Type II Burst on 7 June 2011

    Science.gov (United States)

    Dorovskyy, V. V.; Melnik, V. N.; Konovalenko, A. A.; Brazhenko, A. I.; Panchenko, M.; Poedts, S.; Mykhaylov, V. A.

    2015-07-01

    The characteristics of a type II burst with a herringbone structure observed both with ground-based radio telescopes (UTR-2 and URAN-2) and space-borne spectrometers (STEREO-A and B) are discussed. The burst was recorded on 7 June 2011 in the frequency band 3 - 33 MHz. It was characterized by extremely rich fine structure. Statistical analysis of more than 300 herringbone sub-bursts constituting the burst was performed separately for the positively (reverse) and negatively (forward) drifting sub-bursts. The sense and the degree of circular polarization of the herringbone sub-bursts were measured in a wide frequency band (16 - 32 MHz). A second-order fine frequency structure of the herringbone sub-bursts was observed and studied for the first time. Using STEREO/COR1 and SOHO/LASCO-C2 images, we determined the direction and radial speed of the coronal mass ejection responsible for the studied type II burst. The possible location of the type II burst source on the flank of the shock was found.

  12. Microwave burst with fine spectral structures in a solar flare on 2011 August 9

    CERN Document Server

    Tan, Baolin; Liu, Yuying; 10.1051/eas/1255035

    2012-01-01

    On August 9, 2011, there was an X6.9 flare event occurred near the west limb of solar disk. From the observation obtained by the spectrometer of the Chinese Solar Broadband Radio Spectrometer in Huairou (SBRS/Huairou) around the flare, we find that this powerful flare has only a short-duration microwave burst of about only 5 minutes, and during the short-duration microwave burst, there are several kinds of fine structures on the spectrogram. These fine structures include very short-period pulsations, millisecond spike bursts, and type III bursts. The most interesting is that almost all of the pulses of very short-period pulsation (VSP) are structured by clusters of millisecond timescales of spike bursts or type III bursts. And there exists three different kinds of frequency drift rates in the VSP: the frequency drift rates with absolute value of about 55 - 130 MHz s^{-1} in the pulse groups, the frequency drift rates with absolute value of about 2.91 - 16.9 GHz s^{-1} on each individual pulse, and the frequen...

  13. He I vector magnetic field maps of a sunspot and its superpenumbral fine-structure

    CERN Document Server

    Schad, T A; Lin, H; Tritschler, A

    2015-01-01

    Advanced inversions of high-resolution spectropolarimetric observations of the He I triplet at 1083 nm are used to generate unique maps of the chromospheric magnetic field vector across a sunspot and its superpenumbral canopy. The observations were acquired by the Facility Infrared Spectropolarimeter (FIRS) at the Dunn Solar Telescope (DST) on 29 January 2012. Multiple atmospheric models are employed in the inversions, as superpenumbral Stokes profiles are dominated by atomic-level polarization while sunspot profiles are Zeeman-dominated but also exhibit signatures perhaps induced by symmetry breaking effects of the radiation field incident on the chromospheric material. We derive the equilibrium magnetic structure of a sunspot in the chromosphere, and further show that the superpenumbral magnetic field does not appear finely structured, unlike the observed intensity structure. This suggests fibrils are not concentrations of magnetic flux but rather distinguished by individualized thermalization. We also dire...

  14. The fine-grained phase-space structure of Cold Dark Matter halos

    CERN Document Server

    Vogelsberger, Mark; Helmi, Amina; Springel, Volker

    2007-01-01

    We present a new and completely general technique for calculating the fine-grained phase-space structure of dark matter throughout the Galactic halo. Our goal is to understand this structure on the scales relevant for direct and indirect detection experiments. Our method is based on evaluating the geodesic deviation equation along the trajectories of individual DM particles. It requires no assumptions about the symmetry or stationarity of the halo formation process. In this paper we study general static potentials which exhibit more complex behaviour than the separable potentials studied previously. For ellipsoidal logarithmic potentials with a core, phase mixing is sensitive to the resonance structure, as indicated by the number of independent orbital frequencies. Regions of chaotic mixing can be identified by the very rapid decrease in the real space density of the associated dark matter streams. We also study the evolution of stream density in ellipsoidal NFW halos with radially varying isopotential shape,...

  15. Hemicellulose fine structure is affected differently during ripening of tomato lines with contrasted texture.

    Science.gov (United States)

    Lahaye, Marc; Quemener, Bernard; Causse, Mathilde; Seymour, Graham B

    2012-11-01

    The impact of genetic and fruit ripening on hemicelluloses fine structure was studied in twelve near isogenic lines of tomato fruits harboring firmness QTL. The sugar composition and the MALDI-TOF MS oligosaccharides profile after glucanase hydrolysis of the cell walls were determined from all green and red fruits pericarp tissue. MS profiles showed two major series of oligomers attributed to xyloglucan (XG) and glucomannan (GM) with minor peaks for xylan and ions attributed to galacto-oligomers. The oligosaccharides MS intensity varied significantly with the fruit genetic and ripening status. Correlations between MS intensity indicated structural regulations of both XG and GM structures with genetics and ripening. These results point to a region on the tomato chromosome 9 controlling cell wall galactose metabolism.

  16. Gaussian Beam Tunneling through a Gyrotropic-Nihility Finely-Stratified Structure

    CERN Document Server

    Tuz, Vladimir R

    2014-01-01

    The three-dimensional Gaussian beam transmission through a ferrite-semiconductor finely-stratified structure being under an action of an external static magnetic field in the Faraday geometry is considered. The beam field is represented by an angular continuous spectrum of plane waves. In the long-wavelength limit, the studied structure is described as a gyroelectromagnetic medium defined by the effective permittivity and effective permeability tensors. The investigations are carried out in the frequency band where the real parts of the on-diagonal elements of both effective permittivity and effective permeability tensors are close to zero while the off-diagonal ones are non-zero. In this frequency band the studied structure is referred to a gyrotropic-nihility medium. It is found out that a Gaussian beam keeps its parameters unchanged (beam width and shape) when passing through the layer of such a medium except of a portion of the absorbed energy.

  17. Relativistic energy, fine structure and hyperfine structure of the low-lying excited states for Be-like system

    Institute of Scientific and Technical Information of China (English)

    Zhang Meng; Gou Bing-Cong

    2005-01-01

    Variational calculations are carried out with a multiconfiguration-interaction wavefunction on the 1s22p2p 1De and 1s22p3p 3pe states to obtain the energies including the mass polarization and relativistic corrections for the beryllium isoelectronic sequence (Z=4-10). The oscillator strengths, transition rates and wavelengths are also calculated. Our results are compared with other theoretical and experimental data in the literatures. The fine structure and hyperfine structure of 1s22p3p 3pe state are also explored.

  18. On the Evidence for Cosmic Variation of the Fine Structure Constant: A Bayesian Reanalysis of the Quasar Dataset

    CERN Document Server

    Cameron, Ewan

    2012-01-01

    We review the evidence behind recent claims of spatial variation in the fine structure constant deriving from observations on ground-based telescopes of ionic absorption lines in the light from distant quasars. To this end we expand upon previous non-Bayesian analyses limited by the assumptions of a strictly Normal and unbiased form for the "unexplained errors" of the benchmark quasar dataset. Through nested importance sampling and the method of power posteriors we evaluate and compare marginal likelihoods (or Bayes factors) for three competing hypotheses-(i) the strict null (no cosmic variation), (ii) the monopole null (a constant Earth-to-quasar offset only), and (iii) the monopole+dipole hypothesis (featuring a cosmic variation manifest to the Earth-bound observer as a North-South divergence)-under various alternative error terms. Our analysis reveals significant support for a skeptical interpretation in which the apparent dipole effect is driven solely by systematic errors of opposing sign inherent in mea...

  19. Cosmological Variation of the Fine Structure Constant from an Ultra-Light Scalar Field: The Effects of Mass

    CERN Document Server

    Gardner, C L

    2003-01-01

    Cosmological variation of the fine structure constant $\\alpha$ due to the evolution of a spatially homogeneous ultra-light scalar field ($m \\sim H_0$) during the matter and $\\Lambda$ dominated eras is analyzed. Agreement of $\\Delta \\alpha/\\alpha$ with the value suggested by recent observations of quasar absorption lines is obtained by adjusting a single parameter, the coupling of the scalar field to matter. Asymptotically $\\alpha(t)$ in this model goes to a constant value $\\bar{\\alpha} \\approx \\alpha_0$ in the early radiation and the late $\\Lambda$ dominated eras. The coupling of the scalar field to (nonrelativistic) matter drives $\\alpha$ slightly away from $\\bar{\\alpha}$ in the epochs when the density of matter is important. Simultaneous agreement with the more restrictive bounds on the variation $|\\Delta \\alpha/\\alpha|$ from the Oklo natural fission reactor and from meteorite samples can be achieved if the mass of the scalar field is on the order of 0.5--0.6 $\\bar{H}$, where $\\bar{H} = \\Omega_\\Lambda^{1/2}...

  20. Fine structure of Tibetan kefir grains and their yeast distribution, diversity, and shift.

    Directory of Open Access Journals (Sweden)

    Man Lu

    Full Text Available Tibetan kefir grains (TKGs, a kind of natural starter for fermented milk in Tibet, China, host various microorganisms of lactic acid bacteria, yeasts, and occasionally acetic acid bacteria in a polysaccharide/protein matrix. In the present study, the fine structure of TKGs was studied to shed light on this unusual symbiosis with stereomicroscopy and thin sections. The results reveal that TKGs consist of numerous small grain units, which are characterized by a hollow globular structure with a diameter between 2.0 and 9.0 mm and a wall thickness of approximately 200 µm. A polyhedron-like net structure, formed mainly by the bacteria, was observed in the wall of the grain units, which has not been reported previously to our knowledge. Towards the inside of the grain unit, the polyhedron-like net structures became gradually larger in diameter and fewer in number. Such fine structures may play a crucial role in the stability of the grains. Subsequently, the distribution, diversity, and shift of yeasts in TKGs were investigated based on thin section, scanning electron microscopy, cloning and sequencing of D1/D2 of the 26S rRNA gene, real-time quantitative PCR, and in situ hybridization with specific fluorescence-labeled oligonucleotide probes. These show that (i yeasts appear to localize on the outer surface of the grains and grow normally together to form colonies embedded in the bacterial community; (ii the diversity of yeasts is relatively low on genus level with three dominant species--Saccharomyces cerevisiae, Kluyveromyces marxianus, and Yarrowia lipolytica; (iii S. cerevisiae is the stable predominant yeast species, while the composition of Kluyveromyces and Yarrowia are subject to change over time. Our results indicate that TKGs are relatively stable in structure, and culture conditions to some extent shape the microbial community and interaction in kefir grains. These findings pave the way for further study of the specific symbiotic

  1. Coupling Fine-Scale Root and Canopy Structure Using Ground-Based Remote Sensing

    Directory of Open Access Journals (Sweden)

    Brady S. Hardiman

    2017-02-01

    Full Text Available Ecosystem physical structure, defined by the quantity and spatial distribution of biomass, influences a range of ecosystem functions. Remote sensing tools permit the non-destructive characterization of canopy and root features, potentially providing opportunities to link above- and belowground structure at fine spatial resolution in functionally meaningful ways. To test this possibility, we employed ground-based portable canopy LiDAR (PCL and ground penetrating radar (GPR along co-located transects in forested sites spanning multiple stages of ecosystem development and, consequently, of structural complexity. We examined canopy and root structural data for coherence (i.e., correlation in the frequency of spatial variation at multiple spatial scales ≤10 m within each site using wavelet analysis. Forest sites varied substantially in vertical canopy and root structure, with leaf area index and root mass more becoming even vertically as forests aged. In all sites, above- and belowground structure, characterized as mean maximum canopy height and root mass, exhibited significant coherence at a scale of 3.5–4 m, and results suggest that the scale of coherence may increase with stand age. Our findings demonstrate that canopy and root structure are linked at characteristic spatial scales, which provides the basis to optimize scales of observation. Our study highlights the potential, and limitations, for fusing LiDAR and radar technologies to quantitatively couple above- and belowground ecosystem structure.

  2. Oscillatory behavior of chromospheric fine structures in a network and a semi-active regions

    CERN Document Server

    Bostanci, Z F; Al, N

    2014-01-01

    In the present work, we study the periodicities of oscillations in dark fine structures using observations of a network and a semi-active region close to the solar disk center. We simultaneously obtained spatially high resolution time series of white light images and narrow band images in the H$\\alpha$ line using the 2D G\\"ottingen spectrometer, which were based on two Fabry-Perot interferometers and mounted in the VTT/Observatorio del Teide/Tenerife. During the observations, the H$\\alpha$ line was scanned at 18 wavelength positions with steps of 125 m\\AA. We computed series of Doppler and intensity images by subtraction and addition of the H$\\alpha$ $\\pm$ 0.3 \\AA\\ and $\\pm$ 0.7 \\AA\\ pairs, sampling the upper chromosphere and the upper photosphere, respectively. Then we obtained power, coherence and phase difference spectra by performing a wavelet analysis to the Doppler fluctuations. Here, we present comparative results of oscillatory properties of dark fine structures seen in a network and a semi-active reg...

  3. The variation of the fine-structure constant from disformal couplings

    Science.gov (United States)

    van de Bruck, Carsten; Mifsud, Jurgen; Nunes, Nelson J.

    2015-12-01

    We study a theory in which the electromagnetic field is disformally coupled to a scalar field, in addition to a usual non-minimal electromagnetic coupling. We show that disformal couplings modify the expression for the fine-structure constant, α. As a result, the theory we consider can explain the non-zero reported variation in the evolution of α by purely considering disformal couplings. We also find that if matter and photons are coupled in the same way to the scalar field, disformal couplings itself do not lead to a variation of the fine-structure constant. A number of scenarios are discussed consistent with the current astrophysical, geochemical, laboratory and the cosmic microwave background radiation constraints on the cosmological evolution of α. The models presented are also consistent with the current type Ia supernovae constraints on the effective dark energy equation of state. We find that the Oklo bound in particular puts strong constraints on the model parameters. From our numerical results, we find that the introduction of a non-minimal electromagnetic coupling enhances the cosmological variation in α. Better constrained data is expected to be reported by ALMA and with the forthcoming generation of high-resolution ultra-stable spectrographs such as PEPSI, ESPRESSO, and ELT-HIRES. Furthermore, an expected increase in the sensitivity of molecular and nuclear clocks will put a more stringent constraint on the theory.

  4. Constraining spatial variations of the fine structure constant using clusters of galaxies and Planck data

    CERN Document Server

    de Martino, I; Ebeling, H; Kocevski, D

    2016-01-01

    We propose an improved methodology to constrain spatial variations of the fine structure constant using clusters of galaxies. We use the {\\it Planck} 2013 data to measure the thermal Sunyaev-Zeldovich effect at the location of 618 X-ray selected clusters. We then use a Monte Carlo Markov Chain algorithm to obtain the temperature of the Cosmic Microwave Background at the location of each galaxy cluster. When fitting three different phenomenological parameterizations allowing for monopole and dipole amplitudes in the value of the fine structure constant we improve the results of earlier analysis involving clusters and CMB power spectrum, and we also found that the best-fit direction of a hypothetical dipole is compatible with the direction of other known anomalies. Although the constraining power of our current datasets do not allow us to test the indications of a dipole obtained though high-resolution optical/UV spectroscopy, our results do highlight that clusters of galaxies will be a very powerful tool to pr...

  5. Sensitivity to temporal fine structure and hearing-aid outcomes in older adults

    Directory of Open Access Journals (Sweden)

    Elvira ePerez Vallejos

    2014-02-01

    Full Text Available Objective: to investigate the effect of sensitivity to temporal fine structure on subjective measures of hearing aid outcome.Design: Prior to receiving hearing aids, participants completed a test to assess sensitivity to temporal fine structure (TFS, the Glasgow Hearing Aid Benefit Profile (GHABP, and the Speech, Spatial and Qualities of hearing (SSQ-A. Follow-up appointments, comprised the GHABP, the SSQ-B , and the International Outcome Inventory for Hearing Aid Outcomes (IOI-HA.Study sample: 75 adults were recruited from direct referral clinics. Results: Two thirds of participants were found to have good sensitivity to TFS; listeners with good sensitivity to TFS rated their hearing abilities higher at pre-fitting (SSQ-A than those with poor sensitivity to TFS. At follow-up, participants with good sensitivity to TFS showed a small improvement on SSQ-B over listeners with poor sensitivity to TFS. Conclusions: The clinical identification of a patient’s ability to process TFS information at an early stage in the treatment pathway could prove useful in managing expectations about hearing aid outcomes.

  6. Retinular fine structure in compound eyes of diurnal and nocturnal sphingid moths.

    Science.gov (United States)

    Eguchi, E

    1982-01-01

    Retinular fine structure has been compared in the superposition compound eyes of three sphingid moths, one nocturnal, Cechenena, and two diurnal, Cephonodes and Macroglossum. Cechenena and Cephonodes have tiered retinas with three kinds of retinular cells: two distal, six regular and one basal. The distal retinular cells in Cechenena are special in having a complex partially intracellular rhabdomere not present in Cephonodes. Macroglossum lacks the distal retinular cell. In Cephonodes a unique rhabdom type, formed by the six regular retinular cells in the middle region of the retinula, is divided into three separate longitudinal plates arranged closely parallel to one another. Their constituent microvilli are consequently all nearly unidirectional. The ratio of rhabdom volume to retinular cell volume in the two diurnal sphingids is 10-27%; this is about the same as that (25%) of skipper butterflies, but significantly smaller than in the nocturnal Cechenena (60%). In the diurnal sphingids retinular cell membranes show elongate meandering profiles with septate junctions between adjacent retinular cells. From the comparative fine structure of their eyes the diurnal sphingids and the skippers would appear to be phylogenetically closely related.

  7. The Fine-Structure of the Net-Circular Polarization in a Sunspot Penumbra

    CERN Document Server

    Tritschler, A; Schlichenmaier, R; Hagenaar, H J

    2007-01-01

    We present novel evidence for a fine structure observed in the net-circular polarization (NCP) of a sunspot penumbra based on spectropolarimetric measurements utilizing the Zeeman sensitive FeI 630.2 nm line. For the first time we detect a filamentary organized fine structure of the NCP on spatial scales that are similar to the inhomogeneities found in the penumbral flow field. We also observe an additional property of the visible NCP, a zero-crossing of the NCP in the outer parts of the center-side penumbra, which has not been recognized before. In order to interprete the observations we solve the radiative transfer equations for polarized light in a model penumbra with embedded magnetic flux tubes. We demonstrate that the observed zero-crossing of the NCP can be explained by an increased magnetic field strength inside magnetic flux tubes in the outer penumbra combined with a decreased magnetic field strength in the background field. Our results strongly support the concept of the uncombed penumbra.

  8. On the fine structure of the sunspot penumbrae. II. The nature of the Evershed flow

    CERN Document Server

    Borrero, J M; Solanki, S K; Collados, M

    2005-01-01

    We investigate the fine structure of the sunspot penumbra by means of a model that allows for a flux tube in horizontal pressure balance with the magnetic background atmosphere in which it is embedded. We apply this model to spectropolarimetric observations of two neutral iron lines at 1.56 $\\mu$m and invert several radial cuts in the penumbra of the same sunspot at two different heliocentric angles. In the inner part of the penumbra we find hot flux tubes that are somewhat inclined to the horizontal. They become gradually more horizontal and cooler with increasing radial distance. This is accompanied by an increase in the velocity of the plasma and a decrease of the gas pressure difference between flux tube and the background component. At large radial distances the flow speed exceeds the critical speed and evidence is found for the formation of a shock front. These results are in good agreement with simulations of the penumbral fine structure and provide strong support for the siphon flow as the physical me...

  9. The variation of the fine-structure constant from disformal couplings

    CERN Document Server

    van de Bruck, Carsten; Nunes, Nelson J

    2015-01-01

    We study a theory in which the electromagnetic field is disformally coupled to a scalar field, in addition to a usual non-minimal electromagnetic coupling. We show that disformal couplings modify the expression for the fine-structure constant, alpha. As a result, the theory we consider can explain the non-zero reported variation in the evolution of alpha by purely considering disformal couplings. We also find that if matter and photons are coupled in the same way to the scalar field, disformal couplings itself do not lead to a variation of the fine-structure constant. A number of scenarios are discussed consistent with the current astrophysical, geochemical, laboratory and the cosmic microwave background radiation constraints on the cosmological evolution of alpha. The models presented are also consistent with the current type Ia supernovae constraints on the effective dark energy equation of state. We find that the Oklo bound in particular puts strong constraints on the model parameters. From our numerical r...

  10. Fine- and hyperfine structure investigations of even configuration system of atomic terbium

    Science.gov (United States)

    Stefanska, D.; Elantkowska, M.; Ruczkowski, J.; Furmann, B.

    2017-03-01

    In this work a parametric study of the fine structure (fs) and the hyperfine structure (hfs) for the even-parity configurations of atomic terbium (Tb I) is presented, based in considerable part on the new experimental results. Measurements on 134 spectral lines were performed by laser induced fluorescence (LIF) in a hollow cathode discharge lamp; on this basis, the hyperfine structure constants A and B were determined for 52 even-parity levels belonging to the configurations 4f85d6s2, 4f85d26s or 4f96s6p; in all the cases those levels were involved in the transitions investigated as the lower levels. For 40 levels the hfs was examined for the first time, and for the remaining 12 levels the new measurements supplement our earlier results. As a by-product, also preliminary values of the hfs constants for 84 odd-parity levels were determined (the investigations of the odd-parity levels system in the terbium atom are still in progress). This huge amount of new experimental data, supplemented by our earlier published results, were considered for the fine and hyperfine structure analysis. A multi-configuration fit of 7 configurations was performed, taking into account second-order of perturbation theory, including the effects of closed shell-open shell excitations. Predicted values of the level energies, as well as of magnetic dipole and electric quadrupole hyperfine structure constants A and B, are quoted in cases when no experimental values are available. By combining our experimental data with our own semi-empirical procedure it was possible to identify correctly the lower and upper level of the line 544.1440 nm measured by Childs with the use of the atomic-beam laser-rf double-resonance technique (Childs, J Opt Soc Am B 9;1992:191-6).

  11. Fine-scale population genetic structure in a fission-fusion society.

    Science.gov (United States)

    Archie, Elizabeth A; Maldonado, Jésus E; Hollister-Smith, Julie A; Poole, Joyce H; Moss, Cynthia J; Fleischer, Robert C; Alberts, Susan C

    2008-06-01

    Nonrandom patterns of mating and dispersal create fine-scale genetic structure in natural populations - especially of social mammals - with important evolutionary and conservation genetic consequences. Such structure is well-characterized for typical mammalian societies; that is, societies where social group composition is stable, dispersal is male-biased, and males form permanent breeding associations in just one or a few social groups over the course of their lives. However, genetic structure is not well understood for social mammals that differ from this pattern, including elephants. In elephant societies, social groups fission and fuse, and males never form permanent breeding associations with female groups. Here, we combine 33 years of behavioural observations with genetic information for 545 African elephants (Loxodonta africana), to investigate how mating and dispersal behaviours structure genetic variation between social groups and across age classes. We found that, like most social mammals, female matrilocality in elephants creates co-ancestry within core social groups and significant genetic differentiation between groups (Phi(ST) = 0.058). However, unlike typical social mammals, male elephants do not bias reproduction towards a limited subset of social groups, and instead breed randomly across the population. As a result, reproductively dominant males mediate gene flow between core groups, which creates cohorts of similar-aged paternal relatives across the population. Because poaching tends to eliminate the oldest elephants from populations, illegal hunting and poaching are likely to erode fine-scale genetic structure. We discuss our results and their evolutionary and conservation genetic implications in the context of other social mammals.

  12. Fine structure in the cosmic ray spectrum: Further analysis and the next step

    CERN Document Server

    Erlykin, A D

    2011-01-01

    An analysis is made of the fine structure in the cosmic ray energy spectrum: new facets of present observations and their interpretation and the next step. It is argued that less than about 10% of the intensity of the helium `peak' at the knee at $\\simeq 5PeV$ is due to just a few sources (SNR) other than the single source. The apparent concavity in the rigidity spectra of protons and helium nuclei which have maximum curvature at about 200 GV is confirmed by a joint analysis of the PAMELA, CREAM and ATIC experiments. The spectra of heavier nuclei also show remarkable structure in the form of `ankles' at several hundred GeV/nucleon. Possible mechanisms are discussed. The search for `pulsar peaks' has not yet proved successful.

  13. THE FINE STRUCTURE OF STALKED BACTERIA BELONGING TO THE FAMILY CAULOBACTERACEAE.

    Science.gov (United States)

    STOVEPOINDEXTER, J L; COHEN-BAZIRE, G

    1964-12-01

    The fine structure of a series of stalked bacteria belonging to the genera Caulobacter and Asticcacaulis has been examined in thin sections. The cell wall has the multilayered structure typical of many Gram-negative bacteria, and continues without interruption throughout the length of the stalk. The core of the stalk, continuous with the cytoplasmic region of the cell, is enclosed in an extension of the cell membrane, and contains a system of internal membranes: it is devoid of ribosomes and nucleoplasm. A membranous organelle occupies the juncture of stalk and cell, separating the ribosomal region from the core of the stalk. Typical mesosomes also occur in the cell, being particularly frequent at the plane of division. The secreted holdfast is located at the tip of the stalk in Caulobacter, and at the pole of the cell adjacent to the stalk in Asticcacaulis.

  14. Systematics of fine structure in the α decay of deformed odd-mass nuclei

    Science.gov (United States)

    Ren, Zhongzhou; Ni, Dongdong

    2014-12-01

    We present a detailed analysis of the a-decay fine structure in 32 deformed odd-mass nuclei from Z = 93 to Z = 102. The α-decay half-lives are systematically calculated within the multichannel cluster model (MCCM), which turns out to well reproduce the experimental data and show the neutron deformed shell structure. The branching ratios for various daughter states are investigated in the MCCM and in the WKB barrier penetration approach, respectively. It is found that the MCCM results agree well with the experimental data, while the WKB results have relatively large deviations from the experimental data for the α transitions to the high-lying members of the rotational band.

  15. Fine structure in the cosmic ray spectrum: Further analysis and the next step

    Science.gov (United States)

    Erlykin, A. D.; Wolfendale, A. W.

    2012-01-01

    An analysis is made of the fine structure in the cosmic ray energy spectrum: new facets of present observations and their interpretation and the next step. It is argued that less than about 10% of the intensity of the helium 'peak' at the knee at ≈5 PeV is due to just a few sources (SNR) other than the single source. The apparent concavity in the rigidity spectra of protons and helium nuclei which have maximum curvature at about 200 GV is confirmed by a joint analysis of the PAMELA, CREAM and ATIC experiments. The spectra of heavier nuclei also show remarkable structure in the form of 'ankles' at several hundred GeV/nucleon. Possible mechanisms are discussed. The search for 'pulsar peaks' has not yet proved successful.

  16. Breed locally, disperse globally: fine-scale genetic structure despite landscape-scale panmixia in a fire-specialist.

    Directory of Open Access Journals (Sweden)

    Jennifer C Pierson

    Full Text Available An exciting advance in the understanding of metapopulation dynamics has been the investigation of how populations respond to ephemeral patches that go 'extinct' during the lifetime of an individual. Previous research has shown that this scenario leads to genetic homogenization across large spatial scales. However, little is known about fine-scale genetic structuring or how this changes over time in ephemeral patches. We predicted that species that specialize on ephemeral habitats will delay dispersal to exploit natal habitat patches while resources are plentiful and thus display fine-scale structure. To investigate this idea, we evaluated the effect of frequent colonization of ephemeral habitats on the fine-scale genetic structure of a fire specialist, the black-backed woodpecker (Picoides arcticus and found a pattern of fine-scale genetic structure. We then tested for differences in spatial structure between sexes and detected a pattern consistent with male-biased dispersal. We also detected a temporal increase in relatedness among individuals within newly burned forest patches. Our results indicate that specialist species that outlive their ephemeral patches can accrue significant fine-scale spatial structure that does not necessarily affect spatial structure at larger scales. This highlights the importance of both spatial and temporal scale considerations in both sampling and data interpretation of molecular genetic results.

  17. Breed locally, disperse globally: fine-scale genetic structure despite landscape-scale panmixia in a fire-specialist.

    Science.gov (United States)

    Pierson, Jennifer C; Allendorf, Fred W; Drapeau, Pierre; Schwartz, Michael K

    2013-01-01

    An exciting advance in the understanding of metapopulation dynamics has been the investigation of how populations respond to ephemeral patches that go 'extinct' during the lifetime of an individual. Previous research has shown that this scenario leads to genetic homogenization across large spatial scales. However, little is known about fine-scale genetic structuring or how this changes over time in ephemeral patches. We predicted that species that specialize on ephemeral habitats will delay dispersal to exploit natal habitat patches while resources are plentiful and thus display fine-scale structure. To investigate this idea, we evaluated the effect of frequent colonization of ephemeral habitats on the fine-scale genetic structure of a fire specialist, the black-backed woodpecker (Picoides arcticus) and found a pattern of fine-scale genetic structure. We then tested for differences in spatial structure between sexes and detected a pattern consistent with male-biased dispersal. We also detected a temporal increase in relatedness among individuals within newly burned forest patches. Our results indicate that specialist species that outlive their ephemeral patches can accrue significant fine-scale spatial structure that does not necessarily affect spatial structure at larger scales. This highlights the importance of both spatial and temporal scale considerations in both sampling and data interpretation of molecular genetic results.

  18. Fine spectral structures in Jovian decametric radio emission observed by ground-based radio telescope.

    Science.gov (United States)

    Panchenko, M.; Brazhenko, A. I.; Shaposhnikov, V. E.; Konovalenko, A. A.; Rucker, H. O.

    2014-04-01

    Jupiter with the largest planetary magnetosphere in the solar system emits intense coherent non-thermal radio emission in a wide frequency range. This emission is a result of a complicated interaction between the dynamic Jovian magnetosphere and energetic particles supplying the free energy from planetary rotation and the interaction between Jupiter and the Galilean moons. Decametric radio emission (DAM) is the strongest component of Jovian radiation observed in a frequency range from few MHz up to 40 MHz. This emission is generated via cyclotron maser mechanism in sources located along Jovian magnetic field lines. Depending on the time scales the Jovian DAMexhibits different complex spectral structures. We present the observations of the Jovian decametric radio emission using the large ground-based radio telescope URAN- 2 (Poltava, Ukraine) operated in the decametric frequency range. This telescope is one of the largest low frequency telescopes in Europe equipped with high performance digital radio spectrometers. The antenna array of URAN-2 consists of 512 crossed dipoles with an effective area of 28 000m2 and beam pattern size of 3.5 x 7 deg. (at 25 MHz). The instrument enables continuous observations of the Jovian radio during long period of times. Jovian DAM was observed continuously since Sep. 2012 (depending on Jupiter visibility) with relatively high time-frequency resolution (4 kHz - 100ms) in the broad frequency range (8-32MHz). We have detected a big amount of the fine spectral structures in the dynamic spectra of DAM such as trains of S-bursts, quasi-continuous narrowband emission, narrow-band splitting events and zebra stripe-like patterns. We analyzed mainly the fine structures associated with non-Io controlled DAM. We discuss how the observed narrowband structures which most probably are related to the propagation of the decametric radiation in the Jupiter's ionosphere can be used to study the plasma parameters in the inner Jovian magnetosphere.

  19. Microsatellite analyses reveal fine-scale genetic structure in grey mouse lemurs (Microcebus murinus).

    Science.gov (United States)

    Fredsted, T; Pertoldi, C; Schierup, M H; Kappeler, P M

    2005-07-01

    Information on genetic structure can be used to complement direct inferences on social systems and behaviour. We studied the genetic structure of the solitary grey mouse lemur (Microcebus murinus), a small, nocturnal primate endemic to western Madagascar, with the aim of getting further insight on its breeding structure. Tissue samples from 167 grey mouse lemurs in an area covering 12.3 km2 in Kirindy Forest were obtained from trapping. The capture data indicated a noncontinuous distribution of individuals in the study area. Using 10 microsatellite markers, significant genetic differentiation in the study area was demonstrated and dispersal was found to be significantly male biased. Furthermore, we observed an overall excess of homozygotes in the total population (F(IT) = 0.131), which we interpret as caused by fine-scale structure with breeding occurring in small units. Evidence for a clumped distribution of identical homozygotes was found, supporting the notion that dispersal distance for breeding was shorter than that for foraging, i.e. the breeding neighbourhood size is smaller than the foraging neighbourhood size. In conclusion, we found a more complex population structure than what has been previously reported in studies performed on smaller spatial scales. The noncontinuous distribution of individuals and the effects of social variables on the genetic structure have implications for the interpretation of social organization and the planning of conservation activities that may apply to other solitary and endangered mammals as well.

  20. Outlier SNP markers reveal fine-scale genetic structuring across European hake populations (Merluccius merluccius).

    Science.gov (United States)

    Milano, Ilaria; Babbucci, Massimiliano; Cariani, Alessia; Atanassova, Miroslava; Bekkevold, Dorte; Carvalho, Gary R; Espiñeira, Montserrat; Fiorentino, Fabio; Garofalo, Germana; Geffen, Audrey J; Hansen, Jakob H; Helyar, Sarah J; Nielsen, Einar E; Ogden, Rob; Patarnello, Tomaso; Stagioni, Marco; Tinti, Fausto; Bargelloni, Luca

    2014-01-01

    Shallow population structure is generally reported for most marine fish and explained as a consequence of high dispersal, connectivity and large population size. Targeted gene analyses and more recently genome-wide studies have challenged such view, suggesting that adaptive divergence might occur even when neutral markers provide genetic homogeneity across populations. Here, 381 SNPs located in transcribed regions were used to assess large- and fine-scale population structure in the European hake (Merluccius merluccius), a widely distributed demersal species of high priority for the European fishery. Analysis of 850 individuals from 19 locations across the entire distribution range showed evidence for several outlier loci, with significantly higher resolving power. While 299 putatively neutral SNPs confirmed the genetic break between basins (F(CT) = 0.016) and weak differentiation within basins, outlier loci revealed a dramatic divergence between Atlantic and Mediterranean populations (F(CT) range 0.275-0.705) and fine-scale significant population structure. Outlier loci separated North Sea and Northern Portugal populations from all other Atlantic samples and revealed a strong differentiation among Western, Central and Eastern Mediterranean geographical samples. Significant correlation of allele frequencies at outlier loci with seawater surface temperature and salinity supported the hypothesis that populations might be adapted to local conditions. Such evidence highlights the importance of integrating information from neutral and adaptive evolutionary patterns towards a better assessment of genetic diversity. Accordingly, the generated outlier SNP data could be used for tackling illegal practices in hake fishing and commercialization as well as to develop explicit spatial models for defining management units and stock boundaries.

  1. Fine Structure ENA Sources Beyond the Termination Shock: Observational Constraints and Detection Limits

    Science.gov (United States)

    Demajistre, R.; Janzen, P. H.; Allegrini, F.; Dayeh, M. A.; McComas, D. J.; Schwadron, N.

    2015-12-01

    High spatial resolution maps from the IBEX mission (McComas et al, Science, 2009) suggest the presence of "fine structure" in the signal from beyond the termination shock. That is, areas of enhanced ENA emission that span less than a degree in the IBEX sky map. If confirmed, this would suggest very concentrated areas of emission from sources with scales of a few AU embedded in the outer heliosphere (or proportionally larger if they are located beyond the heliopause). This, in turn, would require the presence of unanticipated structures (plasma or neutral) beyond the termination shock for which the physics is poorly defined. It is therefore crucial to confirm the presence of these structures through careful analysis, or to establish the detection limits if the data taken to date is not sufficient for such a confirmation. In this work, we use 5 years worth of IBEX data to examine the statistical significance of these enhancements. We examine correlations in time, ENA energy and coincidence type for evidence of these small-scale spatial structures. Then, using the known spatial response of the IBEX instrument, establish the conditions under which such structure, if present, would be detectable. This detection threshold analysis is fully applicable future measurements, such as those planned for IMAP.

  2. Fine structure of the mineralized teeth of the chiton Acanthopleura echinata (Mollusca: Polyplacophora).

    Science.gov (United States)

    Wealthall, Rosamund J; Brooker, Lesley R; Macey, David J; Griffin, Brendan J

    2005-08-01

    The major lateral teeth of the chiton Acanthopleura echinata are composite structures composed of three distinct mineral zones: a posterior layer of magnetite; a thin band of lepidocrocite just anterior to this; and apatite throughout the core and anterior regions of the cusp. Biomineralization in these teeth is a matrix-mediated process, in which the minerals are deposited around fibers, with the different biominerals described as occupying architecturally discrete compartments. In this study, a range of scanning electron microscopes was utilized to undertake a detailed in situ investigation of the fine structure of the major lateral teeth. The arrangement of the organic and biomineral components of the tooth is similar throughout the three zones, having no discrete borders between them, and with crystallites of each mineral phase extending into the adjacent mineral zone. Along the posterior surface of the tooth, the organic fibers are arranged in a series of fine parallel lines, but just within the periphery their appearance takes on a "fish scale"-like pattern, reflective of the cross section of a series of units that are overlaid, and offset from each other, in adjacent rows. The units are approximately 2 microm wide and 0.6 microm thick and comprise biomineral plates separated by organic fibers. Two types of subunits make up each "fish scale": one is elongate and curved and forms a trough, in which the other, rod-like unit, is nestled. Adjacent rod and trough units are aligned into large sheets that define the fracture plane of the tooth. The alignment of the plates of rod-trough units is complex and exhibits extreme spatial variation within the tooth cusp. Close to the posterior surface the plates are essentially horizontal and lie in a lateromedial plane, while anteriorly they are almost vertical and lie in the posteroanterior plane. An understanding of the fine structure of the mineralized teeth of chitons, and of the relationship between the organic and

  3. Local atomic structure investigation of AlFeCuCrMgx (0.5, 1, 1.7) high entropy alloys: X-ray absorption spectroscopy study

    Science.gov (United States)

    Maulik, Ornov; Patra, N.; Bhattacharyya, D.; Jha, S. N.; Kumar, Vinod

    2017-02-01

    The present paper reports local atomic structure investigation of novel AlFeCuCrMgx (x=0.5, 1, 1.7) high entropy alloys (HEAs) produced by mechanical alloying using Fe, Cr and Cu K-edge X-ray absorption near edge spectroscopy (XANES) and extended x-ray absorption fine structure (EXAFS) spectroscopy. XANES spectra measured at Fe and Cr K-edges resemble that of the respective pure metal foils, while the spectrum measured at Cu K-edge manifests the presence of some other phases in the as-milled alloys. The radial distribution functions (RDFs) obtained from Fourier transformation of EXAFS spectra support the formation of disordered BCC structure.

  4. The Young Modulus of Black Strings and the Fine Structure of Blackfolds

    CERN Document Server

    Armas, Jay; Harmark, Troels; Obers, Niels A

    2011-01-01

    We explore corrections in the blackfold approach, which is a worldvolume theory capturing the dynamics of thin black branes. The corrections probe the fine structure of the branes, going beyond the approximation in which they are infinitely thin, and account for the dipole moment of worldvolume stress-energy as well as the internal spin degrees of freedom. We show that the dipole correction is induced elastically by bending a black brane. We argue that the long-wavelength transport coefficient capturing this response is a relativistic generalization of the Young modulus of elastic materials and we compute it analytically. Using this we draw predictions for black rings in dimensions greater than six. Furthermore, we employ our corrected blackfold equations to various multi-spinning black hole configurations in the blackfold limit, finding perfect agreement with known analytic solutions.

  5. Impact of heavy hole-light hole coupling on the exciton fine structure in quantum dots

    Science.gov (United States)

    Tsitsishvili, E.

    2017-03-01

    We present analytical results which describe the properties of the exciton ground state in a single semiconductor quantum dot (QD). Calculations are performed within the Luttinger-Kohn and Bir-Pikus Hamiltonian theory. We show in an explicit form that an interplay of the exchange interaction and the heavy hole-light hole coupling, which is due to the in-plane asymmetries of the dot shape and the strain distribution, plays an essential role. For both the bright and dark exciton, this combined effect leads to a dependence of the fine structure splitting and polarizations on the main anisotropy axis direction relative to the dot orientation. Basing on the obtained analytical expressions, we discuss some special cases in details.

  6. Optimal Design for Nonperiodic Fine Grating Structure Controlled by Proximity Correction with Electron-Beam Lithography

    Science.gov (United States)

    Okano, Masato; Hirai, Yoshihiko; Kikuta, Hisao

    2007-02-01

    We describe a method for designing nonperiodic fine grating structures such as a small F-number diffractive cylindrical lens, to be fabricated by direct-writing electron-beam lithography. The design is based on a resist development simulator for estimating a proximity effect of electron dose and the finite difference time domain (FDTD) method for simulating an electromagnetic field. The surface profile and electron dose distribution are simultaneously optimized to obtain the high diffraction efficiency. For the design of a diffractive lens of 50 μm width and 25 μm focal length, the calculated diffraction efficiency is 49% for 650-nm-wavelength light, which is slightly lower than that of a diffractive lens profile optimized by electromagnetic analysis without restrictions on fabrication limits.

  7. Half-lives and fine structure for the α decay of deformed even-even nuclei

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    The α-decay properties of well-deformed even-even nuclei are systematically calculated within the multichannel cluster model (MCCM). Instead of working in the WKB framework, the quasibound solution to the coupled Schro¨dinger equation is presented with outgoing wave boundary conditions, and the coupling potential is taken into full account in terms of the general quantum theories. The calculated α-decay half-lives are found to agree well with the experimental data with a mean factor of less than 2. The fine structure observed in α decay is also well reproduced by the four-channel microscopic calculation. Very strikingly, the MCCM can give relatively precise descriptions of the branching ratio to excited 4+ states, which is often overestimated in the usual WKB calculations. We expect it to be a significant development of theoretical models toward quantitative descriptions of α transitions to high-spin daughter states.

  8. Half-lives and fine structure for the α decay of deformed even-even nuclei

    Science.gov (United States)

    Ni, DongDong; Ren, ZhongZhou

    2011-08-01

    The α-decay properties of well-deformed even-even nuclei are systematically calculated within the multichannel cluster model (MCCM). Instead of working in the WKB framework, the quasibound solution to the coupled Schrödinger equation is presented with outgoing wave boundary conditions, and the coupling potential is taken into full account in terms of the general quantum theories. The calculated α-decay half-lives are found to agree well with the experimental data with a mean factor of less than 2. The fine structure observed in α decay is also well reproduced by the four-channel microscopic calculation. Very strikingly, the MCCM can give relatively precise descriptions of the branching ratio to excited 4+ states, which is often overestimated in the usual WKB calculations. We expect it to be a significant development of theoretical models toward quantitative descriptions of α transitions to high-spin daughter states.

  9. Theoretical description of fine structure in the α decay of heavy odd-odd nuclei

    Science.gov (United States)

    Ni, Dongdong; Ren, Zhongzhou

    2013-02-01

    The newly developed multichannel cluster model (MCCM), based on the coupled-channel Schrödinger equation with outgoing wave boundary conditions, is extended to study the α-decay fine structure in heavy odd-odd nuclei. Calculations are performed for the α transitions to favored rotational bands where the unpaired nucleons remain unchanged. The simple WKB barrier penetration formula is also used to evaluate the branching ratios for various daughter states. It is found that the WKB formula seems to overestimate the branching ratios for the second and third members of the favored rotational band, while the MCCM gives a precise description of them without any adjustable parameters. Moreover, the experimental total α-decay half-lives are well reproduced within the MCCM.

  10. Fine structure and immunocytochemistry of a new chemosensory system in the Chiton larva (Mollusca: Polyplacophora)

    DEFF Research Database (Denmark)

    Haszprunar, Gerhard; Friedrich, Stefan; Wanninger, Andreas;

    2002-01-01

    Combined electron microscopy and immunocytochemistry of the larvae of several polyplacophoran species (Chiton olivaceus, Lepidochitona aff. corrugata, Mopalia muscosa) revealed a sensory system new to science, a so-called "ampullary system." The cells of the "ampullary system" are arranged in four...... symmetrically situated pairs lying dorsolaterally and ventrolaterally in the pretrochal part of the trochophore-like larva and they send axons into the cerebral commissure. They are lost at metamorphosis. The fine structure of these cells strongly resembles that of so-called "ampullary cells" known from various...... sensory organs of other molluscs, such as the apical complex of gastropod and bivalve larvae, osphradia of vetigastropods, and olfactory organs of cephalopods, and nuchal organs of certain polychaetes. The ampullary cells and their nerves are densely stained by anti-FMRF-amide fluorescence dyes, whereas...

  11. Representations of U(2∞ and the Value of the Fine Structure Constant

    Directory of Open Access Journals (Sweden)

    William H. Klink

    2005-12-01

    Full Text Available A relativistic quantum mechanics is formulated in which all of the interactions are in the four-momentum operator and Lorentz transformations are kinematic. Interactions are introduced through vertices, which are bilinear in fermion and antifermion creation and annihilation operators, and linear in boson creation and annihilation operators. The fermion-antifermion operators generate a unitary Lie algebra, whose representations are fixed by a first order Casimir operator (corresponding to baryon number or charge. Eigenvectors and eigenvalues of the four-momentum operator are analyzed and exact solutions in the strong coupling limit are sketched. A simple model shows how the fine structure constant might be determined for the QED vertex.

  12. New determination of the fine structure constant and test of the quantum electrodynamics.

    Science.gov (United States)

    Bouchendira, Rym; Cladé, Pierre; Guellati-Khélifa, Saïda; Nez, François; Biraben, François

    2011-02-25

    We report a new measurement of the ratio h/m(Rb) between the Planck constant and the mass of (87)Rb atom. A new value of the fine structure constant is deduced, α(-1)=137.035999037(91) with a relative uncertainty of 6.6×10(-10). Using this determination, we obtain a theoretical value of the electron anomaly a(e)=0.00115965218113(84), which is in agreement with the experimental measurement of Gabrielse [a(e)=0.00115965218073(28)]. The comparison of these values provides the most stringent test of the QED. Moreover, the precision is large enough to verify for the first time the muonic and hadronic contributions to this anomaly.

  13. Fine-structural changes in the midgut of old Drosophila melanogaster

    Science.gov (United States)

    Anton-Erxleben, F.; Miquel, J.; Philpott, D. E.

    1983-01-01

    Senescent fine-structural changes in the midgut of Drosophila melanogaster are investigated. A large number of midgut mitochondria in old flies exhibit nodular cristae and a tubular system located perpendicular to the normal cristae orientation. Anterior intestinal cells show a senescent accumulation of age pigment, either with a surrounding two-unit membrane or without any membrane. The predominant localization of enlarged mitochondria and pigment in the luminal gut region may be related to the polarized metabolism of the intestinal cells. Findings concur with previous observations of dense-body accumulations and support the theory that mitochondria are involved in the aging of fixed post-mitotic cells. Demonstrated by statistical analyses is that mitochondrial size increase is related to mitochondrial variation increase.

  14. Dust-cloud structures behind a shock wave moving over a deposited layer of fine particles

    Institute of Scientific and Technical Information of China (English)

    WANG Boyi; XIONG Yi; CHEN Qian; A.N. OSIPTSOV

    2005-01-01

    The present paper investigates dispersed-phase flow structures of a dust cloud induced by a normal shock wave moving at a constant speed over a flat surface deposited with fine particles. In the shock-fitted coordinates, the general equations of dusty-gas boundary layer flows are formulated within the framework of a multi-fluid model and parametric numerical studies of the carrier- and dispersedphase flow fields are performed. The problem associated with crossing particle trajectories and the formation of local particle accumulation regions are solved by using the full Lagrangian method for the dispersed phase. The basic features of the near-wall two-phase flow under consideration including the role of Saffman force in the particle entrainment and the development of discontinuities or singularities in the particle density profiles are discussed. The effects associated with account of the non-uniformity of particle size and the finiteness of the particle Knudsen numbers are studied in detail.

  15. Fine structure of inelastic electron scattering cross-section spectra for MN

    Science.gov (United States)

    Parshin, A. S.; Igumenov, A. Yu; Mikhlin, Yu L.; Pchelyakov, O. P.; Zhigalov, V. S.

    2016-04-01

    The comparative analysis of the reflection electron energy loss spectra and the inelastic electron scattering cross-section spectra for Mn was carried out. It is shown that inelastic electron scattering cross-section spectra have certain advantages in the study of the interaction of electrons with the substance as compared to the electron energy loss spectra. The inelastic electron scattering cross section spectra fine structure was analysed by fitting the experimental spectra using the 3 parameters Lorentzian-type formula of Tougaard. This method was used for the quantitative analysis of the contributions of various loss processes in the inelastic electron scattering cross section spectra, determination of the loss peaks energies and origin.

  16. The variation of the fine structure constant: an update of statistical analysis with recent data

    CERN Document Server

    Kraiselburd, Lucila; Simeone, Claudio

    2013-01-01

    We analyze different astronomical data of the variation in the fine structure constant obtained with KECK and VLT to check their consistency. We test consistency using the Student test and confidence intervals. We split the data sets in smaller intervals and group them by i) redshift and ii) angular position. Another statistical analysis is proposed considering phenomenological models for the variation in \\alpha\\ . Results show consistency for reduced intervals for each pair of data sets considered and suggest that the variation in \\alpha\\ is important at higher redshifts.Even though the "dipole model" proposed by Webb et al. seems to be the most accurate phenomenological model, the statistical analyses indicates that the variation in \\alpha\\ might be depending both on redshift and angular position.

  17. The variation of the fine structure constant: testing the dipole model with thermonuclear supernovae

    CERN Document Server

    Kraiselburd, Lucila; Negrelli, Carolina; Berro, Enrique García

    2014-01-01

    The large-number hypothesis conjectures that fundamental constants may vary. Accordingly, the spacetime variation of fundamental constants has been an active subject of research for decades. Recently, using data obtained with large telescopes a phenomenological model in which the fine structure constant might vary spatially has been proposed. We test whether this hypothetical spatial variation of {\\alpha}, which follows a dipole law, is compatible with the data of distant thermonuclear supernovae. Unlike previous works, in our calculations we consider not only the variation of the luminosity distance when a varying {\\alpha} is adopted, but we also take into account the variation of the peak luminosity of Type Ia supernovae resulting from a variation of {\\alpha}. This is done using an empirical relation for the peak bolometric magnitude of thermonuclear supernovae that correctly reproduces the results of detailed numerical simulations. We find that there is no significant difference between the several phenome...

  18. Study on Fine Structure of Gas Atomized LaNi5-based Alloys

    Institute of Scientific and Technical Information of China (English)

    Hai JING; Hong GUO; Shuguang ZHANG; Zili MA; Shaoming ZHANG

    2003-01-01

    The fine structure of hydrogen storage alloy powders MINi4.3-xCoxMn0.4Al0.3(x=0.75, 0.45, 0.10; MI: La-rich mischmetal) prepared by rapidly solidifying gas atomization was investigated using a Rietveld analysis method. Two setsof CaCu5-type crystal constants were observed in the studied alloys and one set was larger than the other. Withdecreasing powder radius the solidification rate of powder increased, and so did the percentage of a particle partwith larger crystal constants. The reason why there were two sets of crystal constants might be the difference ofsolidification rate between the outside and inside of a particle.

  19. The tardigrade cuticle. I. Fine structure and the distribution of lipids.

    Science.gov (United States)

    Wright, J C

    1988-01-01

    Fine structure and lipid distribution are studied in cuticles of five tardigrade species using TEM and SEM. Double osmication using partitioning methods reveals a substantial lipid component in the intracuticle and in irregular granular regions within the procuticle. These results are substantiated by the loss of osmiophily following lipid extraction with chloroform and methanol. Other lipid components are revealed by osmication following unmasking of lipo-protein complexes with thymol. These occur in the outer epicuticle and in the trilaminar layer lying between the epi- and intracuticles. Anhydrous fixation of dehydrated tardigrades (tuns) reveals dense, superficial masses of osmiophilic material, apparently concentrated lumps of the surface mucopolysaccharide ('flocculent coat'). However, cryo-SEMs of tuns reveal similar dense aggregations which apparently exude from pores (not visible) and are removed by chloroform. These results suggest extruded lipids since the flocculent coat is unaffected by chloroform; likely functions of such lipids are discussed.

  20. Constraints on the time variation of the fine structure constant by the 5-year WMAP data

    CERN Document Server

    Nakashima, Masahiro; Yokoyama, Jun'ichi

    2008-01-01

    The constraints on the time variation of the fine structure constant at recombination epoch relative to its present value, $\\Delta\\alpha/\\alpha \\equiv (\\alpha_{\\mathrm{rec}} - \\alpha_{\\mathrm{now}})/\\alpha_{\\mathrm{now}}$, are obtained from the analysis of the 5-year WMAP cosmic microwave background data. As a result of Markov-Chain Monte-Carlo analysis, it is found that, contrary to the analysis based on the previous WMAP data, the mean value of $\\Delta\\alpha/\\alpha=-0.0009$ does not change significantly whether we use the Hubble Space Telescope (HST) measurement of the Hubble parameter as a prior or not. The resultant 95% confidence ranges of $\\Delta\\alpha/\\alpha$ are $-0.028 < \\Delta\\alpha/\\alpha < 0.026$ with HST prior and $-0.050 < \\Delta\\alpha/\\alpha < 0.042$ without HST prior.

  1. High resolution telescope and spectrograph observations of solar fine structure in the 1600 A region

    Science.gov (United States)

    Cook, J. W.; Brueckner, G. E.; Bartoe, J.-D. F.

    1983-01-01

    High spatial resolution spectroheliograms of the 1600 A region obtained during the HRTS rocket flight of 1978 February 13 are presented. The morphology, fine structure, and temporal behavior of emission bright points (BPs) in active and quiet regions are illustrated. In quiet regions, network elements persist as morphological units, although individual BPs may vary in intensity while usually lasting the flight duration. In cell centers, the BPs are highly variable on a 1 minute time scale. BPs in plages remain more constant in brightness over the observing sequence. BPs cover less than 4 percent of the quiet surface. The lifetime and degree of packing of BPs vary with the local strength of the magnetic field.

  2. Variation of the fine-structure constant from the de Sitter invariant special relativity

    Science.gov (United States)

    Chen, Shao-Xia; Xiao, Neng-Chao; Yan, Mu-Lin

    2008-08-01

    We discuss the variation of the fine-structure constant, α. There are obvious discrepancies among the results of α-variation from recent Quasi-stellar observation experiments and from the Oklo uranium mine analysis. We use dS Sitter invariant Special Relativity (Script SScript Rc,R) and Dirac large number hypothesis to discuss this puzzle, and present a possible solution to the disagreement. By means of the observational data and the discussions presented in this paper, we estimate the radius of the Universe in Script SScript Rc,R which is about ~2√5×1011l.y. Supported by National Natural Science Foundation of China (90403021) and PhD Program Funds of Education Ministry of China (20020358040)

  3. 3-Space In-Flow Theory of Gravity: Boreholes, Blackholes and the Fine Structure Constant

    CERN Document Server

    Cahill, R T

    2006-01-01

    A theory of 3-space explains the phenomenon of gravity as arising from the time-dependence and inhomogeneity of the differential flow of this 3-space. The emergent theory of gravity has two gravitational constants: G - Newton's constant, and a dimensionless constant - alpha. Various experiments and astronomical observations have shown that alpha is the fine structure constant 1/137. Here we analyse the Greenland Ice Shelf and Nevada Test Site borehole g anomalies, and confirm with increased precision this value of alpha. This and other successful tests of this theory of gravity, including the supermassive black holes in globular clusters and galaxies, and the `dark-matter' effect in spiral galaxies, demonstrates the validity of this theory of gravity. This success implies that Newtonian gravity was fundamentally flawed from the beginning.

  4. The fine structure splitting of the level of lithium in Rydberg states

    Institute of Scientific and Technical Information of China (English)

    胡先权; 胡文江; 孔春阳

    2002-01-01

    The Hamiltonian of the four-body problem for a lithium atom is expanded in series. The level shift and levelformula of a lithium atom in Rydberg states are achieved by means of the calculation of polarization of the atomic core(including the contribution of dipole, quadrupole and octupole components). We also consider the effect of relativitytheory, the orbital angular momentum L and the spin angular momentum S coupling scheme (LS coupling) and high-order correction of the effective potential to the level shift. The fine structure splitting (N=5-12, L=4-9, J=L±l/2)and level intervals in B ydberg states have been calculated by the above-mentioned formula and compared with recentexperimental data.

  5. Theory of the Lamb shift and Fine Structure in $\\boldsymbol{(\\mu{}^{4}\\mathrm{He})^{+}}$

    CERN Document Server

    Diepold, Marc; Franke, Beatrice; Antognini, Aldo; Kottmann, Franz; Pohl, Randolf

    2016-01-01

    An up to date review of the theoretical contributions to the $2S\\rightarrow{}2P$ Lamb shift and the fine structure of the $2P$-state in the $(\\mu^4\\mathrm{He})^+$ ion is given. This summary will serve as the basis for the extraction of the alpha particle charge radius from the muonic helium Lamb shift measurements at the Paul Scherrer Institute Switzerland. Individual theoretical contributions needed for a charge radius extraction were compared and compiled into a consistent summary using the already established framework we used for muonic hydrogen and deuterium. The influence of the alpha particle charge distribution on the elastic two-photon exchange is studied to rule out possible model dependencies of the energy levels on the electric form factor of the nucleus.

  6. Engineering quantum dots for electrical control of the fine structure splitting

    Science.gov (United States)

    Pooley, M. A.; Bennett, A. J.; Farrer, I.; Ritchie, D. A.; Shields, A. J.

    2013-07-01

    We have studied the variation in fine-structure splitting (FSS) under application of vertical electric field in a range of quantum dots grown by different methods. In each sample, we confirm that this energy splitting changes linearly over the field range we can access. We conclude that this linear tuning is a general feature of self-assembled quantum dots, observed under different growth conditions, emission wavelengths, and in different material systems. Statistical measurements of characteristic parameters such as emission energy, Stark shift, and FSS tuning are presented which may provide a guide for future attempts to increase the yield of quantum dots that can be tuned to a minimal value of FSS with vertical electric field.

  7. Relations between frequency selectivity, temporal fine-structure processing, and speech reception in impaired hearing

    DEFF Research Database (Denmark)

    Strelcyk, Olaf; Dau, Torsten

    2009-01-01

    and binaural TFS-processing deficits in the HI listeners, no relation was found between TFS processing and frequency selectivity. The effect of noise on TFS processing was not larger for the HI listeners than for the NH listeners. Finally, TFS-processing performance was correlated with speech reception......Frequency selectivity, temporal fine-structure (TFS) processing, and speech reception were assessed for six normal-hearing (NH) listeners, ten sensorineurally hearing-impaired (HI) listeners with similar high-frequency losses, and two listeners with an obscure dysfunction (OD). TFS processing...... was investigated at low frequencies in regions of normal hearing, through measurements of binaural masked detection, tone lateralization, and monaural frequency modulation (FM) detection. Lateralization and FM detection thresholds were measured in quiet and in background noise. Speech reception thresholds were...

  8. Fine-structure processing, frequency selectivity and speech perception in hearing-impaired listeners

    DEFF Research Database (Denmark)

    Strelcyk, Olaf; Dau, Torsten

    2008-01-01

    Hearing-impaired people often experience great difficulty with speech communication when background noise is present, even if reduced audibility has been compensated for. Other impairment factors must be involved. In order to minimize confounding effects, the subjects participating in this study...... consisted of groups with homogeneous, symmetric audiograms. The perceptual listening experiments assessed the intelligibility of full-spectrum as well as low-pass filtered speech in the presence of stationary and fluctuating interferers, the individual's frequency selectivity and the integrity of temporal...... modulation were obtained. In addition, these binaural and monaural thresholds were measured in a stationary background noise in order to assess the persistence of the fine-structure processing to interfering noise. Apart from elevated speech reception thresholds, the hearing impaired listeners showed poorer...

  9. Fine structures in Fe3Al alloy layer of a new hot dip aluminized steel

    Indian Academy of Sciences (India)

    Li Yajiang; Wang Juan; Zhang Yonglan; X Holly

    2002-12-01

    The fine structure in the Fe–Al alloy layer of a new hot dip aluminized steel (HDA) was examined by means of X-ray diffractometry (XRD), electron diffraction technique, etc. The test results indicated that the Fe–Al alloy layer of the new aluminized steel mainly composed of Fe3Al, FeAl and -Fe (Al) solid solution. There was no brittle phase containing higher aluminum content, such as FeAl3 (59.18% Al) and Fe2Al7 (62.93% Al). The tiny cracks and embrittlement, formerly caused by these brittle phases in the conventional aluminum-coated steel, were effectively eliminated. There was no microscopic defect (such as tiny cracks, pores or loose layer) in the coating. This is favourable to resist high temperature oxidation and corrosion of the aluminized steel.

  10. Electron-Vibration Structure of Absorption Spectra of Resazurine

    Directory of Open Access Journals (Sweden)

    T.N. Sakun

    2011-01-01

    Full Text Available In the work the experimental and theoretical investigation of the spectral characteristics of a resazurin molecule are carried out. Comparison of results of experimental and theoretical researches has allowed showing, that the spectrum of absorption in the visible region is formed by quantum transitions between electronic states of the molecule, and also by the electron-vibration interaction. In the work the method of reception of theoretical results with the control of molecule symmetry is offered. It has allowed to receive the completely coordinated theoretical and experimental results both by position and by size of the extinction factor and to find out the nature of all quantum transitions and oscillatory frequencies. It is shown, that strips of absorption in the visible region of the spectrum are formed at participation of the totally symmetrical vibrations of the molecule among which the greatest participation stand out vibrations with frequencies in the region of 478 cm – 1, 1467 cm – 1, and also by group of oscillatory frequencies in the region of 1800-2000 cm – 1 which were less than found theoretically for the basic state of the molecule because the degree of loosening of the bonds that responsible for specified vibrations, increases at excitation of the molecule.

  11. Properties and Modeling of Unresolved Fine Structure Loops Observed by IRIS

    CERN Document Server

    Brooks, David H; Warren, Harry P

    2016-01-01

    Recent observations from the Interface Region Imaging Spectrograph (IRIS) have discovered a new class of numerous low-lying dynamic loop structures, and it has been argued that they are the long-postulated unresolved fine structures (UFS) that dominate the emission of the solar transition region. In this letter, we combine IRIS measurements of the properties of a sample of 108 UFS (intensities, lengths, widths, lifetimes) with 1-D non-equilibrium ionization simulations using the HYDRAD hydrodynamic model to examine whether the UFS are now truly spatially resolved in the sense of being individual structures rather than composed of multiple magnetic threads. We find that a simulation of an impulsively heated single strand can reproduce most of the observed properties suggesting that the UFS may be resolved, and the distribution of UFS widths implies that they are structured on a spatial scale of 133km on average. Spatial scales of a few hundred km appear to be typical for a range of chromospheric and coronal st...

  12. Fine strand-like structure in the solar corona from MHD transverse oscillations

    CERN Document Server

    Antolin, P; Van Doorsselaere, T

    2014-01-01

    Current analytical and numerical modelling suggest the existence of ubiquitous thin current sheets in the corona that could explain the observed heating requirements. On the other hand, new high resolution observations of the corona indicate that its magnetic field may tend to organise itself in fine strand-like structures of few hundred kilometres widths. The link between small structure in models and the observed widths of strand-like structure several orders of magnitude larger is still not clear. A popular theoretical scenario is the nanoflare model, in which each strand is the product of an ensemble of heating events. Here, we suggest an alternative mechanism for strand generation. Through forward modelling of 3D MHD simulations we show that small amplitude transverse MHD waves can lead in a few periods time to strand-like structure in loops in EUV intensity images. Our model is based on previous numerical work showing that transverse MHD oscillations can lead to Kelvin-Helmholtz instabilities that defor...

  13. Fine structures and dynamics in auroral initial brightening at substorm onsets

    Directory of Open Access Journals (Sweden)

    K. Sakaguchi

    2009-02-01

    Full Text Available We show four auroral initial brightening events at substorm onsets focusing on fine structures and their longitudinal dynamics, which were observed by all-sky TV cameras (30-Hz sampling on January 2008, in Canada. For two initial brightenings started in the field of views of the cameras, we found that they started at longitudinal segments with a size of less than ~30–60 km. One brightening expanded with wavy structures and the other expanded as a straight arc. Although the two events had different structures, both brightening auroras expanded with an average speed of ~20 km/s in the first 10 s, and ~10 km/s in the following 10 s. The other two events show that brightening auroras developed with periodic structures, with longitudinal wavelengths of ~100–200 km. Assuming that the brightening auroras are mapped to the physical processes occurring in the plasma sheet, we found that the scale size (30–60 km and the expanding speed (20 km/s of brightening auroras correspond to the order of ion gyro radii (~500–1400 km and Alfvén speed or fast ion-flow speed (~400 km/s, respectively, in the plasma sheet.

  14. Spectral fine structure of the atomic ground states based on full relativistic theory

    Institute of Scientific and Technical Information of China (English)

    Zhenghe Zhu; Yongjian Tang

    2011-01-01

    @@ We focus on the full relativistic quantum mechanical calculations from boron to fluorine atoms with electronic configuration of 1s22s22pn (n = 1, 2, 3, 4, and 5), where 1s22s2 is the closed shell and 2pn is the open shell. Their active electrons in the open shell occupy all the six spinors as far as possible.Therefore, we suggest a new rule called "maximum probability" for the full symmetry group relativistic theory. Furthermore, the spectral fine structure of the atomic ground states based on the full relativistic theory and their intervals of L-S splitting are all reasonable. It is impossible to calculate the L-S splitting through non-relativistic quantum mechanics. The relativistic effect of atomic mass is increased significantly by about 12 folds from boron atom to fluorine atom.%We focus on the full relativistic quantum mechanical calculations from boron to fluorine atoms with electronic configuration of 1s22s22pn (n = 1, 2, 3, 4, and 5), where 1s22s2 is the closed shell and 2pn is the open shell. Their active electrons in the open shell occupy all the six spinors as far as possible.Therefore, we suggest a new rule called "maximum probability" for the full symmetry group relativistic theory. Furthermore, the spectral fine structure of the atomic ground states based on the full relativistic theory and their intervals of L-S splitting are all reasonable. It is impossible to calculate the L-S splitting through non-relativistic quantum mechanics. The relativistic effect of atomic mass is increased significantly by about 12 folds from boron atom to fluorine atom.

  15. On the Visibility of Prominence Fine Structures at Radio Millimeter Wavelengths

    Science.gov (United States)

    Heinzel, P.; Berlicki, A.; Bárta, M.; Karlický, M.; Rudawy, P.

    2015-07-01

    Prominence temperatures have so far mainly been determined by analyzing spectral line shapes, which is difficult when the spectral lines are optically thick. The radio spectra in the millimeter range offer a unique possibility to measure the kinetic temperature. However, studies in the past used data with insufficient spatial resolution to resolve the prominence fine structures. The aim of this article is to predict the visibility of prominence fine structures in the submillimeter/millimeter (SMM) domain, to estimate their brightness temperatures at various wavelengths, and to demonstrate the feasibility and usefulness of future high-resolution radio observations of solar prominences with ALMA ( Atacama Large Millimeter-submillimeter Array). Our novel approach is the conversion of H coronagraphic images into microwave spectral images. We show that the spatial variations of the prominence brightness both in the H line and in the SMM domain predominantly depend on the line-of-sight emission measure of the cool plasma, which we derive from the integrated intensities of the observed H line. This relation also offers a new possibility to determine the SMM optical thickness from simultaneous H observations with high resolution. We also describe how we determine the prominence kinetic temperature from SMM spectral images. Finally, we apply the ALMA image-processing software Common Astronomy Software Applications (CASA) to our simulated images to assess what ALMA would detect at a resolution level that is similar to the coronagraphic H images used in this study. Our results can thus help in preparations of first ALMA prominence observations in the frame of science and technical verification tests.

  16. Experimental fine-structure branching ratios for Na-rare-gas optical collisions

    Energy Technology Data Exchange (ETDEWEB)

    Havey, M.D.; Delahanty, F.T.; Vahala, L.L.; Copeland, G.E.

    1986-10-01

    Experimental ratios for branching into the fine-structure levels of the Na 3p multiplet, as a consequence of an optical collision with He, Ne, Ar, Kr, or Xe, are reported. The process studied is Na(3s /sup 2/S/sub 1/2/)+scrR+nh..nu -->..Na(3p /sup 2/P/sub j/)+scrR+(n-1)h..nu.., where scrR represents a rare-gas atom and where the laser frequency ..nu.. is tuned in the wings of the Na resonance transitions. The branching ratios are defined as I(D1)/I(D2) where I(D1) and I(D2) are measured intensities of the atomic Na D1 and D2 lines. The ratios are determined for detunings ranging from about 650 cm/sup -1/ in the blue wing to 170 cm/sup -1/ in the red wing of the Na 3p multiplet. The branching is found to be strongly detuning dependent in the vicinity of the NaAr, NaKr, and NaXe near-red-wing satellites. The blue-wing branching ratios show a detuning-dependent approach to a recoil, or sudden statistical, limit of 0.5, irrespective of the rare gas. Fine-structure changing cross sections have also been measured for resonant excitation of the Na 3p /sup 2/P/sub j/ state; the results are consistent with cross sections obtained from wing excitation.

  17. A study of fine structure of diffuse aurora with ALIS-FAST measurements

    Directory of Open Access Journals (Sweden)

    T. Sergienko

    2008-10-01

    Full Text Available We present results of an investigation of the fine structure of the night sector diffuse auroral zone, observed simultaneously with optical instruments (ALIS from the ground and the FAST electron spectrometer from space 16 February 1997. Both the optical and particle data show that the diffuse auroral zone consisted of two regions. The equatorward part of the diffuse aurora was occupied by a pattern of regular, parallel auroral stripes. The auroral stripes were significantly brighter than the background luminosity, had widths of approximately 5 km and moved southward with a velocity of about 100 m/s. The second region, located between the region with auroral stripes and the discrete auroral arcs to the north, was filled with weak and almost homogeneous luminosity, against which short-lived auroral rays and small patches appeared chaotically. From analysis of the electron differential fluxes corresponding to the different regions of the diffuse aurora and based on existing theories of the scattering process we conclude the following: Strong pitch angle diffusion by electron cyclotron harmonic waves (ECH of plasma sheet electrons in the energy range from a few hundred eV to 3–4 keV was responsible for the electron precipitation, that produced the background luminosity within the whole diffuse zone. The fine structure, represented by the auroral stripes, was created by precipitation of electrons above 3–4 keV as a result of pitch angle diffusion into the loss cone by whistler mode waves. A so called "internal gravity wave" (Safargaleev and Maltsev, 1986 may explain the formation of the regular spatial pattern formed by the auroral stripes in the equatorward part of the diffuse auroral zone.

  18. A study of fine structure of diffuse aurora with ALIS-FAST measurements

    Science.gov (United States)

    Sergienko, T.; Sandahl, I.; Gustavsson, B.; Andersson, L.; Brändström, U.; . Steen, Ã.

    2008-10-01

    We present results of an investigation of the fine structure of the night sector diffuse auroral zone, observed simultaneously with optical instruments (ALIS) from the ground and the FAST electron spectrometer from space 16 February 1997. Both the optical and particle data show that the diffuse auroral zone consisted of two regions. The equatorward part of the diffuse aurora was occupied by a pattern of regular, parallel auroral stripes. The auroral stripes were significantly brighter than the background luminosity, had widths of approximately 5 km and moved southward with a velocity of about 100 m/s. The second region, located between the region with auroral stripes and the discrete auroral arcs to the north, was filled with weak and almost homogeneous luminosity, against which short-lived auroral rays and small patches appeared chaotically. From analysis of the electron differential fluxes corresponding to the different regions of the diffuse aurora and based on existing theories of the scattering process we conclude the following: Strong pitch angle diffusion by electron cyclotron harmonic waves (ECH) of plasma sheet electrons in the energy range from a few hundred eV to 3 4 keV was responsible for the electron precipitation, that produced the background luminosity within the whole diffuse zone. The fine structure, represented by the auroral stripes, was created by precipitation of electrons above 3 4 keV as a result of pitch angle diffusion into the loss cone by whistler mode waves. A so called "internal gravity wave" (Safargaleev and Maltsev, 1986) may explain the formation of the regular spatial pattern formed by the auroral stripes in the equatorward part of the diffuse auroral zone.

  19. New algorithm improves fine structure of the barley consensus SNP map

    Directory of Open Access Journals (Sweden)

    Endelman Jeffrey B

    2011-08-01

    Full Text Available Abstract Background The need to integrate information from multiple linkage maps is a long-standing problem in genetics. One way to visualize the complex ordinal relationships is with a directed graph, where each vertex in the graph is a bin of markers. When there are no ordering conflicts between the linkage maps, the result is a directed acyclic graph, or DAG, which can then be linearized to produce a consensus map. Results New algorithms for the simplification and linearization of consensus graphs have been implemented as a package for the R computing environment called DAGGER. The simplified consensus graphs produced by DAGGER exactly capture the ordinal relationships present in a series of linkage maps. Using either linear or quadratic programming, DAGGER generates a consensus map with minimum error relative to the linkage maps while remaining ordinally consistent with them. Both linearization methods produce consensus maps that are compressed relative to the mean of the linkage maps. After rescaling, however, the consensus maps had higher accuracy (and higher marker density than the individual linkage maps in genetic simulations. When applied to four barley linkage maps genotyped at nearly 3000 SNP markers, DAGGER produced a consensus map with improved fine structure compared to the existing barley consensus SNP map. The root-mean-squared error between the linkage maps and the DAGGER map was 0.82 cM per marker interval compared to 2.28 cM for the existing consensus map. Examination of the barley hardness locus at the 5HS telomere, for which there is a physical map, confirmed that the DAGGER output was more accurate for fine structure analysis. Conclusions The R package DAGGER is an effective, freely available resource for integrating the information from a set of consistent linkage maps.

  20. [Fine structural study of keratinization of the filiform papillae in the tongue in humans].

    Science.gov (United States)

    Placková, A; Skach, M

    1975-01-01

    The fine structure of the keratinization of the papilla filiformis of the human tongue was described for the first time; Two biopsies of normal tongue tissue were fixed in 2,5% phosphate-buffered glutaraldehyde, postfixed in 1% osmiumtetroxyde, embedded in Durcopan und contrasted ultrathin sections were examined by electron microscopes JEM 7A and 100B. The findings show a highly configurated epithel-connective tissue border with basal lamina and irregular hemidesmosomes. The epithelial structure of the interpapillary area is identical with the fine structure of the human buccal mucosa, which was classified as non-keratinized or incompletely keratinized. Accordingly, a stratum granulosum is missing. After loss of nucleus and organelles, surface cells become flattened, parallel to the surface of the tongue and have a fine fibrillar cytoplasm. The papilla filiformis is formed by cell growth along the secondary connective tissue papillae and consequently tube-like epithelial structures appear. In the papillary area basal and stratum spinosum cells show epidermal structural features. A difference from epidermal and other oral epithelial cells becomes apparent for the first time in the stratum granulosum by the appearance of a great number of round, small, electron-dense KHG, surrounded by ribosomes. The KHG are not associated with tonofilaments. In the area of the walls of the tubes 1...3 mum large, electron-dense structures are formed by fusion of several KHG. With further differentiation these large KHG disintegrate into bulky or granular masses, filling the cell cytoplasm and thus mask the tonofilaments. The cells at the borders of the tubes show a great structural variability. After the disintegration of nucleus and organelles, the cytoplasm is formed by randomly oriented filaments of different packing or by fiber-bundles. Yet the interfibrilla embedding substance, typical of orthokeratinization is mostly lackingmin some cells of the tubeborders, masses of

  1. Active region fine structure observed at 0.08 arcsec resolution

    CERN Document Server

    Schlichenmaier, R; Hoch, S; Soltau, D; Berkefeld, T; Schmidt, D; Schmidt, W; Denker, C; Balthasar, H; Hofmann, A; Strassmeier, K G; Staude, J; Feller, A; Lagg, A; Solanki, S K; Collados, M; Sigwarth, M; Volkmer, R; Waldmann, T; Kneer, F; Nicklas, H; Sobotka, M

    2016-01-01

    The various mechanisms of magneto-convective energy transport determines the structure of sunspots and active regions. We characterise the appearance of light bridges and other fine structure details and elaborate on their magneto-convective nature. We present speckle-reconstructed images taken with the broad band imager at the 1.5 m GREGOR telescope in the 486nm and 589nm bands. We estimate the spatial resolution from the noise characteristics of the image bursts and obtain 0.08" at 589nm. We describe structure details in individual best images as well as the temporal evolution of selected features. We find branched dark lanes extending along thin (~1") light bridges in sunspots at various heliocentric angles. In thick (~2") light bridges the branches are disconnected from the central lane and have a `Y' shape with a bright grain toward the umbra. The images reveal that light bridges exist on varying intensity levels and that their small-scale features evolve on time scales of minutes. Faint light bridges sh...

  2. Fine fragmentation distribution from structural reactive material casings under explosive loading

    Science.gov (United States)

    Wilson, William; Zhang, Fan; Kim, Kibong

    2015-06-01

    Structural reactive material (SRM) can be used for explosive casings to provide additional blast energy. SRM fragments can react either promptly or after impact with nearby structure. Better understanding of fine fragment distributions from SRM casings is important for optimization of initiation and reaction of the SRM fragments. Key to this is knowledge of the initial fragmentation character before it has been altered by early reaction or by subsequent impact with surrounding structure. The study must be conducted beyond critical charge diameter to minimize effects of the expansion wave on fragment sizes. The collection and analysis of fragment distribution down to 40 micron size from thick SRM casings are therefore investigated in a 1.18 m diameter, 2.1 m3 closed cylindrical chamber filled with artificially-made pure snow packed to density 0.35 g/cm3. The snow quenches early reaction of SRM fragments and soft-catches the fragments before impact with the chamber walls. A 100 g cylindrical C-4 explosive charge is used, packed in a 3.3 cm inner diameter SRM casing, with length-to-diameter ratio of L/d = 2, and casing-to-explosive mass ratio of M/C = 1.75. Three types of SRM are investigated, including a baseline of Aluminum 6061 for comparison. The cased charge is suspended in an argon filled cavity, 20 cm in diameter and 40 cm long, within the snow filed chamber.

  3. Fine structure and functional comments of mouthparts in Platypus cylindrus (Col., Curculionidae: Platypodinae).

    Science.gov (United States)

    Belhoucine, Latifa; Bouhraoua, Rachid T; Prats, Eva; Pulade-Villar, Juli

    2013-02-01

    Oak pinhole borer, Platypus cylindrus is seen in recent years as one of the biggest enemies directly involved in the observed decline of cork oak in Mediterranean forests with all the economic implications. As an ambrosia beetle, it has developed its effective drilling mouthpart enough to make tunnels in hardwood of the tree. The fine structural aspects of the mouthpart using the field emission scanning electron microscopy are analyzed about 23 adults collected in galleries of infested cork oak trees (Quercus suber) in a littoral forest of northwest Algeria. These adults are preserved in alcohol 70%, cleaned and coated with gold. The mouthparts of this beetle consist commonly of a labrum, a pair of mandibles, a pair of maxillae and the labium but with adapted structure to excavate galleries in the hardwood. In this role is also involved the first pair of legs. The function that present the different structures related to the construction of the tunnels is discussed. Both of maxillary and labial palpi direct the food to the mouth and hold it while the mandibles chew the food. The distal ends of these palpi are flattened and have shovel-like setae. Females have larger maxillary palpi than males and this is related to the particular biology of each sex.

  4. X-ray absorption near-edge structure and valence state of Mn in (Ga,Mn)N

    Science.gov (United States)

    Titov, A.; Biquard, X.; Halley, D.; Kuroda, S.; Bellet-Amalric, E.; Mariette, H.; Cibert, J.; Merad, A. E.; Merad, G.; Kanoun, M. B.; Kulatov, E.; Uspenskii, Yu. A.

    2005-09-01

    The band structure of the diluted magnetic semiconductor (Ga,Mn)N, and the x-ray absorption near-edge structure (XANES) at the K edge of Mn, were calculated using the linearized augmented plane wave method. The calculated K-edge spectra fit well with experimental data obtained on samples of Ga1-xMnxN with a wide range of Mn content, from x=0.3% to 5.7%. These samples were grown by molecular beam epitaxy. X-ray diffraction measurements and extended x-ray absorption fine structure studies were used to confirm the wurtzite structure of the samples, the absence of any secondary phase, and the substitutional position of Mn in the gallium sublattice of GaN. The shape of the measured XANES spectra does not depend on the Mn content, implying the same valence state and local atomic structure around the Mn atom in all samples. The comparison between the measured spectra and the results of the ab initio calculation offers a clear interpretation of the preedge structure: It is mainly due to dipolar transitions, with a single peak in the case of Mn2+ and an additional peak for Mn3+ . Such a behavior of the XANES preedge of Mn2+ was confirmed experimentally on (Ga,Mn)As and (Zn,Mn)Te. We conclude that the valence state of Mn in wurtzite (Ga,Mn)N is 3+ , a conclusion which is also supported by infrared optical transmission and magnetization data obtained on the same samples.

  5. Noise Abatement and Internal Vibrational Absorption in Potential Structural Materials

    Science.gov (United States)

    1976-09-01

    ial disclosed a fully austenitic ( fcc ) structure and the high damp- ing characteristic of the rod was regenerated. A second demonstration of the ease...20 w/o Fe) could be readily formed in the fcc structure (as demonstrated above) and then aged to high strength by ordering the bcc phase. In fact

  6. Study on the improved structure of dye-sensitized solar cells for enhancing light absorption

    Institute of Scientific and Technical Information of China (English)

    LIU Yong; SHEN Hui; DENG Youjun

    2007-01-01

    The absorption coefncients of N719 or N3 dyes at the longer wavelength region (>600 nm)are not enough to catch photons efficiently,but the solar spectrum has a large photon flux in the wavelength region between 500 and 1,000 nm,so it is desirable to enhance the absorption of light by the dye-sensitized solar cells(DSSC)to achieve higher efficiencies.To solve this problem,an improved structure Of DSSC for enhancing light absorption is introduced in this paper, and I-V characteristics of DSSC are measured to illustrate the enhancement of the light absorption and efficiency.As a result,the improved DSSC exhibits higher light absorption and solar-to-electric conversion efficiency than traditional DSSC.

  7. Mechanism of resonant perfect optical absorption in dielectric film supporting metallic grating structures.

    Science.gov (United States)

    Chen, Xiumei; Yan, Xiaopeng; Li, Ping; Mou, Yongni; Wang, Wenqiang; Guan, Zhiqiang; Xu, Hongxing

    2016-08-22

    The mechanism of resonant perfect optical absorbers is quantitatively revealed by the coupled mode method for the air/grating/dielectric film/air four region system. The sufficient and necessary conditions of the perfect optical absorption are derived from the interface scattering coefficients analyses. The coupling of the Fabry-Perot modes in the grating slits and non-zero order quasi waveguide modes in the dielectric film play a key role for the perfect optical absorption when the light is incident from the grating side. The analytical sufficient and necessary conditions of the perfect optical absorption provide an efficient tool towards geometry design for the perfect optical absorption at the specific wavelengths. The advantages of a widely tunable perfect optical absorption wavelength, a high Q factor and the confined energy loss on metal surfaces make the air/grating/film/air structures promising for applications in sensing, modulation and detection.

  8. Model for the fine structure of zero field steps in long Josephson tunnel junctions and its comparison with experiment

    DEFF Research Database (Denmark)

    Barbara, Paola; Monaco, R.; Ustinov, A. V.

    1996-01-01

    The single fluxon dynamics in the resonant regime has been investigated on high-quality low-loss Nb/Al–AlOx/Nb window Josephson tunnel junctions. A new model accounting for the fine structure of zero field steps in linear junctions is proposed. Depending on the fluxon velocity and on the junction...... simulations, and experiments. The presence of the idle region has been proved to play a determinant role for the occurrence of the fine structure. ©1996 American Institute of Physics....

  9. Cluster model calculation of N near K-edge energy-loss fine structures in hexagonal GaN crystal

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    A cluster model is used to calculate electron energy-loss fine structures in crystal. The multiple-scattering self-consistent-field method is employed in the calculation. Our theoretical results of N near K-edge energy loss fine structures in hexagonal GaN crystal are in good agreement with the experimental spectra. Future possible experiments in energy-filtered transmission electron microscopy (EFTEM) are discussed and proposed because our theoretical work can provide clear assignments for transmitted electrons with different energy losses.

  10. Interesting Features of n2D Rydberg Series Fine-Structure Splittings along the Sodium-Like Isoelectronic Sequence

    Institute of Scientific and Technical Information of China (English)

    WANG Xiao-Lu; LIU Ling-Tao; GAO Xiang; SHEN Chun; LI Jia-Ming

    2008-01-01

    @@ Using a simplified multi-configuration Dirac-Fock (SMCDF) scheme based on the multi-configuration Dirac-Fock (MCDF) theory, we study the systematic variations of the fine-structure splittings of n2 D3/2,5/2 Rydberg series along the sodium-like isoelectronic sequence, i.e.the fine-structure orderings vary with increasing atomic number Z.The competition between the spin-orbit interactions and the exchange interactions due to relativistic effects of the nd orbital wavefunctions well explain such variations.Furthermore, the effect of Breit interactions which plays the secondary role is studied.

  11. Theoretical Study of Interesting Fine-Structure Splittings for 23P0,1,2 States along Helium Isoelectronic Sequence

    Institute of Scientific and Technical Information of China (English)

    QING Bo; CHEN Shao-Hao; GAO Xiang; LI Jia-Ming

    2008-01-01

    Using the multi-configuration Dirac-Fock method including the Breit interactions and QED corrections, we calculate the fine-structure energy levels of the 23P,0,1,2 states along the helium isoelectronic sequence with atomic number up to Z=36, where LS-coupling is appropriate. Our calculation results agree with the experimental results within about 1%. We elucidate the mechanism of the interesting fine-structure splittings for the 23P,0,1,2 states along the helium isoelectronic sequence, I. E. The competitions between the spin-orbit interactions and the Breit interactions which represent the relativistic retardation effect of electromagnetic interactions.

  12. Observation of the fine structure for rovibronic spectral lines in visible part of emission spectra of $D_2$

    CERN Document Server

    Lavrov, B P; Zhukov, A S

    2011-01-01

    For the first time the fine structure of rovibronic spectral lines in visible part of emission spectra of $D_2$ molecule has been observed. Observed splitting in visible doublets is about 0.2 cm$^{-1}$ in good accordance with previous observations in the infrared part of the spectrum ($a^3\\Sigma_g^+ \\to c^3\\Pi_u$ electronic transition) by means of FTIR and laser spectroscopy. Relative intensities of the fine structure components are in agreement with our calculations of adiabatic line strengths for Hund's case "b" coupling scheme.

  13. Regulation of the demographic structure in isomorphic biphasic life cycles at the spatial fine scale.

    Directory of Open Access Journals (Sweden)

    Vasco Manuel Nobre de Carvalho da Silva Vieira

    Full Text Available Isomorphic biphasic algal life cycles often occur in the environment at ploidy abundance ratios (Haploid:Diploid different from 1. Its spatial variability occurs within populations related to intertidal height and hydrodynamic stress, possibly reflecting the niche partitioning driven by their diverging adaptation to the environment argued necessary for their prevalence (evolutionary stability. Demographic models based in matrix algebra were developed to investigate which vital rates may efficiently generate an H:D variability at a fine spatial resolution. It was also taken into account time variation and type of life strategy. Ploidy dissimilarities in fecundity rates set an H:D spatial structure miss-fitting the ploidy fitness ratio. The same happened with ploidy dissimilarities in ramet growth whenever reproductive output dominated the population demography. Only through ploidy dissimilarities in looping rates (stasis, breakage and clonal growth did the life cycle respond to a spatially heterogeneous environment efficiently creating a niche partition. Marginal locations were more sensitive than central locations. Related results have been obtained experimentally and numerically for widely different life cycles from the plant and animal kingdoms. Spore dispersal smoothed the effects of ploidy dissimilarities in fertility and enhanced the effects of ploidy dissimilarities looping rates. Ploidy dissimilarities in spore dispersal could also create the necessary niche partition, both over the space and time dimensions, even in spatial homogeneous environments and without the need for conditional differentiation of the ramets. Fine scale spatial variability may be the key for the prevalence of isomorphic biphasic life cycles, which has been neglected so far.

  14. Unresolved Fine-scale Structure in Solar Coronal Loop-tops

    Science.gov (United States)

    Scullion, E.; Rouppe van der Voort, L.; Wedemeyer, S.; Antolin, P.

    2014-12-01

    New and advanced space-based observing facilities continue to lower the resolution limit and detect solar coronal loops in greater detail. We continue to discover even finer substructures within coronal loop cross-sections, in order to understand the nature of the solar corona. Here, we push this lower limit further to search for the finest coronal loop substructures, through taking advantage of the resolving power of the Swedish 1 m Solar Telescope/CRisp Imaging Spectro-Polarimeter (CRISP), together with co-observations from the Solar Dynamics Observatory/Atmospheric Image Assembly (AIA). High-resolution imaging of the chromospheric Hα 656.28 nm spectral line core and wings can, under certain circumstances, allow one to deduce the topology of the local magnetic environment of the solar atmosphere where its observed. Here, we study post-flare coronal loops, which become filled with evaporated chromosphere that rapidly condenses into chromospheric clumps of plasma (detectable in Hα) known as a coronal rain, to investigate their fine-scale structure. We identify, through analysis of three data sets, large-scale catastrophic cooling in coronal loop-tops and the existence of multi-thermal, multi-stranded substructures. Many cool strands even extend fully intact from loop-top to footpoint. We discover that coronal loop fine-scale strands can appear bunched with as many as eight parallel strands within an AIA coronal loop cross-section. The strand number density versus cross-sectional width distribution, as detected by CRISP within AIA-defined coronal loops, most likely peaks at well below 100 km, and currently, 69% of the substructure strands are statistically unresolved in AIA coronal loops.

  15. Structure and properties of advanced fine grained steels produced using novel thermal treatments

    OpenAIRE

    Vuorinen, Esa

    2012-01-01

    Fine grained advanced steels exhibit favourable mechanical properties for applications requiring high strength, ductility and impact toughness. These properties result from a microstructure containing a fine distribution of several phases including ferrite, austenite, martensite and bainite. The bainite phase is in the form of fine lamellas of ferrite and carbon-enriched austenite which due to proper control of the chemical composition is lacking the nanometre scaled carbides associated with ...

  16. Rotational and Fine Structure of Pseudo-Jahn Molecules with C_1 Symmetry

    Science.gov (United States)

    Liu, Jinjun

    2016-06-01

    It has been found in our previous works that rotational and fine-structure analysis of spectra involving nearly degenerate electronic states may aid in interpretation and analysis of the vibronic structure, specifically in the case of pseudo-Jahn-Teller (pJT) molecules with C_s symmetry. The spectral analysis of pJT derivatives (isopropoxy and cyclohexoxy of a prototypical JT molecule (the methoxy radical) allowed for quantitative determination of various contributions to the energy separation between the nearly degenerate electronic states, including the relativistic spin-orbit (SO) effect, the electrostatic interaction, and their zero-point energy difference. These states are coupled by SO and Coriolis interactions, which can also be determined accurately in rotational and fine structure analysis. Most recently, the spectroscopic model for rotational analysis of pJT molecules has been extended for analysis of molecules with C_1 symmetry, i.e., no symmetry. This model includes the six independently determinable components of the spin-rotation (SR) tensor and the three components of the SO and Coriolis interactions. It has been employed to simulate and fit high-resolution laser-induced fluorescence (LIF) spectra of jet-cooled alkoxy radicals with C_1 symmetry, including the 2-hexoxy and the 2-pentoxy radicals, as well as previously recorded LIF spectrum of the trans-conformer (defined by its OCCC dihedral angle) of the 2-butoxy radical. Although the LIF spectra can be reproduced by using either the SR constants or SO and Coriolis constants, the latter simulation offers results that are physically more meaningful whereas the SR constants have to be regarded as effective constants. Furthermore, we will review the SO and Coriolis constants of alkoxy radicals that have been investigated, starting from the well-studied methoxy radical (CH_3O). J. Liu, D. Melnik, and T. A. Miller, J. Chem. Phys. 139, 094308 (2013) J. Liu and T. A. Miller, J. Phys. Chem. A 118, 11871

  17. Fine structure of Langmuir waves observed upstream of the bow shock at Venus

    Science.gov (United States)

    Hospodarsky, G. B.; Gurnett, D. A.; Kurth, W. S.; Kivelson, M. G.; Strangeway, R. J.; Bolton, S. J.

    1994-01-01

    Highly structured Langmuir waves, also known as electron plasma oscillations, have been observed in the foreshock of Venus using the plasma wave experiment on the Galileo spacecraft during the gravity assist flyby on February 10, 1990. The Galileo wideband sampling system provides digital electric field waveform measurements at sampling rates up to 201,600 samples per second, much higher than any previous instrument of this type. The main Langmuir wave emission band occurs near the local electron plasma frequency, which was approximately 43 kHz. The Langmuir waves are observed to shift above and below the plasma frequency, sometimes by as much as 20 kHz. The shifts in frequency are closely correlated with the downstream distance from the tangent field line, implying that the shifts are controlled by the electron beam velocity. Considerable fine structure is also evident, with timescales as short as 0.15 ms, corresponding to spatial scales of a few tens of Debye lengths. The frequency spectrum often consists of beat-type waveforms, with beat frequencies ranging from 0.2 to 7 kHz, and in a few cases, isolated wave packets. The peak electric field strengths are approximately 1 mV/m. These field strengths are too small for strongly nonlinear processes to be important. The beat-type waveforms are suggestive of a parametric decay process.

  18. Fine-Scale Human Population Structure in Southern Africa Reflects Ecogeographic Boundaries.

    Science.gov (United States)

    Uren, Caitlin; Kim, Minju; Martin, Alicia R; Bobo, Dean; Gignoux, Christopher R; van Helden, Paul D; Möller, Marlo; Hoal, Eileen G; Henn, Brenna M

    2016-09-01

    Recent genetic studies have established that the KhoeSan populations of southern Africa are distinct from all other African populations and have remained largely isolated during human prehistory until ∼2000 years ago. Dozens of different KhoeSan groups exist, belonging to three different language families, but very little is known about their population history. We examine new genome-wide polymorphism data and whole mitochondrial genomes for >100 South Africans from the ≠Khomani San and Nama populations of the Northern Cape, analyzed in conjunction with 19 additional southern African populations. Our analyses reveal fine-scale population structure in and around the Kalahari Desert. Surprisingly, this structure does not always correspond to linguistic or subsistence categories as previously suggested, but rather reflects the role of geographic barriers and the ecology of the greater Kalahari Basin. Regardless of subsistence strategy, the indigenous Khoe-speaking Nama pastoralists and the N|u-speaking ≠Khomani (formerly hunter-gatherers) share ancestry with other Khoe-speaking forager populations that form a rim around the Kalahari Desert. We reconstruct earlier migration patterns and estimate that the southern Kalahari populations were among the last to experience gene flow from Bantu speakers, ∼14 generations ago. We conclude that local adoption of pastoralism, at least by the Nama, appears to have been primarily a cultural process with limited genetic impact from eastern Africa.

  19. Retinal pigment epithelial fine structure in the red-tailed hawk (Buto jamaicensis).

    Science.gov (United States)

    Braekevelt, C R

    1992-03-01

    As part of a comparative morphological study, the fine structure of the retinal epithelium (RPE), choriocapillaris and Bruch's membrane (complexus basalis) has been studied by electron microscopy in the red-tailed hawk (Buteo jamaicensis). In this species the RPE consists of a single layer of low cuboidal cells which display numerous basal (scleral) infoldings and extensive apical (vitreal) processes which interdigitate with photoreceptor outer segments. These epithelial cells are joined laterally by a series of basally located tight junctions. Internally SER is the most abundant cell organelle while only small amounts of RER are present. Polysomes are however abundant as are mitochondria. The RPE cell nucleus is large and vesicular. Melanosomes are mainly located in the apical processes of the RPE cells in light-adaptation. Myeloid bodies are large and numerous in light-adaptation and often show ribosomes on their outer border. Bruch's membrane (complexus basalis) shows the typical pentalaminate structure noted in most vertebrates but with only a poorly defined central elastic layer. The endothelium of the choriocapillaris is very thin facing the RPE but is only moderately fenestrated. The choriocapillaris in this species is unusual however in that many of the fenestrae show a double-layered diaphragm.

  20. Fine scale mapping of the structure and composition of the Elkhorn Slough (California, USA) tidal plume

    Science.gov (United States)

    Fischer, Andrew M.; Ryan, John P.; Rienecker, Erich V.

    2017-01-01

    Fine scale mapping of the structure and composition of a tidal ebb plume from a highly modified coastal lagoon (Elkhorn Slough, California, USA) was conducted by combining in situ, observational data sets from surface underway mapping, autonomous underwater vehicle (AUV) profiles, drifter tracking and the analysis of plume structure indices. The results reveal a 6-m-deep, jet-like, sediment laden plume extending one km offshore at low tide, which becomes entrained in the prevailing nearshore circulation. The plume that exits the slough is significantly different from the water that enters the slough. The rapidly evolving discharge plume is associated with elevated and highly correlated (r = 0.93) concentrations of dissolved organic matter and nitrate. While dissolved constituents remain in the shallow plume and are transported northward with the prevailing current, sediment may settle quickly through the water column and can be transported southwestward with the littoral currents. This study illustrates the applications of AUVs, when coupled with additional datasets, for generating higher resolution observational snapshots of dynamic and ephemeral tidal plumes. The results provide unique perspective on small-scale dynamics of an estuarine plume and its influence on coastal ecology.

  1. Electronic fine structure in the nickel carbide superconductor Th2NiC2

    Science.gov (United States)

    Quan, Y.; Pickett, W. E.

    2013-07-01

    The recently reported nickel carbide superconductor body centered tetragonal I4/mmm Th2NiC2 with Tc=8.5 K increasing to 11.2 K upon alloying Th with Sc is found to have very fine structure in its electronic spectrum, according to density functional based first-principles calculations. The filled Ni 3d band complex is hybridized with C 2p and Th character to and through the Fermi level (EF), and a sharply structured density of states arises only when spin-orbit coupling is included, which splits a zone-center degeneracy, leaving a very flat band edge lying at the Fermi level. The flat part of the band corresponds to an effective mass mz*→∞ with large and negative mx*=my*. Although the region over which the effective mass characterization applies is less than 1% of the zone volume, it supplies on the order of half the states at (or just above) the Fermi level. The observed increase of Tc by hole doping is accounted for if the reference as-synthesized sample is minutely hole doped, which decreases the Fermi level density of states and will provide some stabilization. In this scenario, electron doping will increase the Fermi level density of states and the superconducting critical temperature. Vibrational properties are presented, and enough coupling to the C-Ni-C stretch mode at 70 meV is obtained to imply that superconductivity is electron-phonon mediated.

  2. The morphology and fine structure of the giant interneurons of the wood cricket Nemobius sylvestris.

    Science.gov (United States)

    Insausti, T C; Lazzari, C R; Casas, J

    2011-02-01

    The structural and ultrastructural characteristics of giant interneurons in the terminal abdominal ganglion of the cricket Nemobius sylvestris were investigated by means of cobalt and fluorescent dye backfilling and transmission electron microscopy. The projections of the 8 eight pairs of the biggest ascending interneurons (giant interneurons) are described in detail. The somata of all interneurons analyzed are located contralateral to their axons, which project to the posterior region of the terminal ganglion and arborise in the cercal glomerulus. Neuron 7-1a is an exception, because its arborisation is restricted to the anterior region of the ganglion. The fine structure of giant interneurons shows typical features of highly active cells. We observed striking indentations in the perineural layer, enabling the somata of the giant interneurons to be very close to the haemolymph. The cercal glomerulus exhibits a high diversity of synaptic contacts (i.e. axo-dendritic, axo-axonic, dendro-axonic, and dendro-dendritic), as well as areas of tight junctions. Electrical synapses seem to be present, as well as mixed synapses. The anatomical organization of the giant interneurons is finally discussed in terms of functional implications and on a comparative basis.

  3. Mineralogical properties and internal structures of individual fine particles of Saharan dust

    Science.gov (United States)

    Jeong, Gi Young; Park, Mi Yeon; Kandler, Konrad; Nousiainen, Timo; Kemppinen, Osku

    2016-10-01

    Mineral dust interacts with incoming/outgoing radiation, gases, other aerosols, and clouds. The assessment of its optical and chemical impacts requires knowledge of the physical and chemical properties of bulk dust and single particles. Despite the existence of a large body of data from field measurements and laboratory analyses, the internal properties of single dust particles have not been defined precisely. Here, we report on the mineralogical organization and internal structures of individual fine ( common particle type was clay-rich agglomerate, dominated by illite-smectite series clay minerals with subordinate kaolinite. Submicron grains of iron (hydr)oxides (goethite and hematite) were commonly dispersed through the clay-rich particles. The median total volume of the iron (hydr)oxide grains included in the dust particles was estimated to be about 1.5 % vol. The average iron content of clay minerals, assuming 14 wt % H2O, was determined to be 5.0 wt %. Coarse mineral cores, several micrometers in size, were coated with thin layers of clay-rich agglomerate. Overall, the dust particles were roughly ellipsoidal, with an average axial ratio of 1.4 : 1.0 : 0.5. The mineralogical and structural properties of single Saharan dust particles provide a basis for the modeling of dust radiative properties. Major iron-bearing minerals, such as illite-smectite series clay minerals and iron (hydr)oxides, were commonly submicron- to nano-sized, possibly enhancing their biogeochemical availability to remote marine ecosystems lacking micronutrients.

  4. Fine Structure of Glycosaminoglycans from Fresh and Decellularized Porcine Cardiac Valves and Pericardium

    Directory of Open Access Journals (Sweden)

    Antonio Cigliano

    2012-01-01

    Full Text Available Cardiac valves are dynamic structures, exhibiting a highly specialized architecture consisting of cells and extracellular matrix with a relevant proteoglycan and glycosaminoglycan content, collagen and elastic fibers. Biological valve substitutes are obtained from xenogenic cardiac and pericardial tissues. To overcome the limits of such non viable substitutes, tissue engineering approaches emerged to create cell repopulated decellularized scaffolds. This study was performed to determine the glycosaminoglycans content, distribution, and disaccharides composition in porcine aortic and pulmonary valves and in pericardium before and after a detergent-based decellularization procedure. The fine structural characteristics of galactosaminoglycans chondroitin sulfate and dermatan sulfate were examined by FACE. Furthermore, the mechanical properties of decellularized pericardium and its propensity to be repopulated by in vitro seeded fibroblasts were investigated. Results show that galactosaminoglycans and hyaluronan are differently distributed between pericardium and valves and within heart valves themselves before and after decellularization. The distribution of glycosaminoglycans is also dependent from the vascular district and topographic localization. The decellularization protocol adopted resulted in a relevant but not selective depletion of galactosaminoglycans. As a whole, data suggest that both decellularized porcine heart valves and bovine pericardium represent promising materials bearing the potential for future development of tissue engineered heart valve scaffolds.

  5. Benthic biofilm structure controls the deposition-resuspension dynamics of fine clay particles

    Science.gov (United States)

    Hunter, W. R.; Roche, K. R.; Drummond, J. D.; Boano, F.; Packman, A. I.; Battin, T. J.

    2015-12-01

    In fluvial ecosystems the alternation of deposition and resuspension of particles represents an important pathway for the downstream translocation of microbes and organic matter. Such particles can originate from algae and microbes, the spontaneous auto-aggregation of organic macromolecules (e.g., "river sown"), terrestrial detritus (traditionally classified as "particulate organic matter"), and erosive mineral and organo-mineral particles. The transport and retention of particles in headwater streams is associated with biofilms, which are surface-attached microbial communities. Whilst biofilm-particle interactions have been studied in bulk, a mechanistic understanding of these processes is lacking. Parallel macroscale/microscale observations are required to unravel the complex feedbacks between biofilm structure, coverage and the dynamics of deposition and resuspension. We used recirculating flume mesocosms to test how changes in biofilm structure affected the deposition and resuspension of clay-sized (< 10 μm) particles. Biofilms were grown in replicate 3-m-long recirculating flumes over variable lengths of time (0, 14, 21, 28, and 35) days. Fixed doses of fluorescent clay-sized particles were introduced to each flume and their deposition was traced over 30 minutes. A flood event was then simulated via a step increase in flowrate to quantify particle resuspension. 3D Optical Coherence Tomography was used to determine roughness, areal coverage and height of biofilms in each flume. From these measurements we characterised particle deposition and resuspension rates, using continuous time random walk modelling techniques, which we then tested as responses to changes in biofilm coverage and structure under both base-flow and flood-flow scenarios. Our results suggest that biofilm structural complexity is a primary control upon the retention and downstream transport of fine particles in stream mesocosms.

  6. Segmentation and Enhancement of Latent Fingerprints: A Coarse to Fine Ridge Structure Dictionary.

    Science.gov (United States)

    Cao, Kai; Liu, Eryun; Jain, Anil K

    2014-09-01

    Latent fingerprint matching has played a critical role in identifying suspects and criminals. However, compared to rolled and plain fingerprint matching, latent identification accuracy is significantly lower due to complex background noise, poor ridge quality and overlapping structured noise in latent images. Accordingly, manual markup of various features (e.g., region of interest, singular points and minutiae) is typically necessary to extract reliable features from latents. To reduce this markup cost and to improve the consistency in feature markup, fully automatic and highly accurate ("lights-out" capability) latent matching algorithms are needed. In this paper, a dictionary-based approach is proposed for automatic latent segmentation and enhancement towards the goal of achieving "lights-out" latent identification systems. Given a latent fingerprint image, a total variation (TV) decomposition model with L1 fidelity regularization is used to remove piecewise-smooth background noise. The texture component image obtained from the decomposition of latent image is divided into overlapping patches. Ridge structure dictionary, which is learnt from a set of high quality ridge patches, is then used to restore ridge structure in these latent patches. The ridge quality of a patch, which is used for latent segmentation, is defined as the structural similarity between the patch and its reconstruction. Orientation and frequency fields, which are used for latent enhancement, are then extracted from the reconstructed patch. To balance robustness and accuracy, a coarse to fine strategy is proposed. Experimental results on two latent fingerprint databases (i.e., NIST SD27 and WVU DB) show that the proposed algorithm outperforms the state-of-the-art segmentation and enhancement algorithms and boosts the performance of a state-of-the-art commercial latent matcher.

  7. Enhanced absorption of graphene strips with a multilayer subwavelength grating structure

    Energy Technology Data Exchange (ETDEWEB)

    Hu, Jin-Hua; Huang, Yong-Qing, E-mail: yqhuang@bupt.edu.cn; Duan, Xiao-Feng; Wang, Qi; Zhang, Xia; Wang, Jun; Ren, Xiao-Min [State Key Laboratory of Information Photonics and Optical Communications, Institute of Information Photonics and Optical Communications, Beijing University of Posts and Telecommunications, Beijing 100876 (China)

    2014-12-01

    The optical absorption of graphene strips covered on a multilayer subwavelength grating (MSG) surface is theoretically investigated. The absorption of graphene strips with MSG is enhanced in the wavelength range of 1500 nm to 1600 nm by critical coupling, which is associated with the combined effects of a guided resonance of MSG and its photonic band gap effect. The critical coupling of the graphene strips can be controlled by adjusting the incident angle without changing the structural parameters of MSG. The absorption of graphene strips can also be tuned by varying key parameters, such as grating period, strip width, and incident angle.

  8. Comparison of Intestinal Absorption and Disposition of Structurally Similar Bioactive Flavones in Radix Scutellariae

    OpenAIRE

    Li, Chenrui; Li ZHANG; Zhou, Limin; Wo, Siu Kwan; LIN, GE; Zuo, Zhong

    2011-01-01

    Radix Scutellariae is a commonly used herbal medicine. Baicalein, wogonin, and oroxylin A are three major bioactive flavones in Radix Scutellariae and share similar chemical structures. The intestinal absorption and disposition of baicalein have been systematically investigated by our group before. In this study, the intestinal absorption and disposition of wogonin and oroxylin A were further explored and compared with the profiles of baicalein to find potential structure–activity relationshi...

  9. Changes in the Fine Structure of Stochastic Distributions as a Consequence of Space-Time Fluctuations

    Directory of Open Access Journals (Sweden)

    Shnoll S. E.

    2006-04-01

    Full Text Available This is a survey of the fine structure stochastic distributions in measurements obtained by me over 50 years. It is shown: (1 The forms of the histograms obtained at each geographic point (at each given moment of time are similar with high probability, even if we register phenomena of completely different nature --- from biochemical reactions to the noise in a gravitational antenna, or alpha-decay. (2 The forms of the histograms change with time. The iterations of the same form have the periods of the stellar day (1.436 min, the solar day (1.440 min, the calendar year (365 solar days, and the sidereal year (365 solar days plus 6 hours and 9 min. (3 At the same instants of the local time, at different geographic points, the forms of the histograms are the same, with high probability. (4 The forms of the histograms depend on the locations of the Moon and the Sun with respect to the horizon. (5 All the facts are proof of the dependance of the form of the histograms on the location of the measured objects with respect to stars, the Sun, and the Moon. (6 At the instants of New Moon and the maxima of solar eclipses there are specific forms of the histograms. (7 It is probable that the observed correlations are not connected to flow power changes (the changes of the gravity force --- we did not find the appropriate periods in changes in histogram form. (8 A sharp anisotropy of space was discovered, registered by alpha-decay detectors armed with collimators. Observations at 54 North (the collimator was pointed at the Pole Star showed no day-long periods, as was also the case for observations at 82 North, near the Pole. Histograms obtained by observations with an Easterly-directed collimator were determined every 718 minutes (half stellar day and with observations using a Westerly-directed collimator. (9 Collimators rotating counter-clockwise, in parallel with the celestial equator, gave the probability of changes in histograms as the number of the

  10. Periodicity extraction in the anuran auditory nerve. II: Phase and temporal fine structure.

    Science.gov (United States)

    Simmons, A M; Reese, G; Ferragamo, M

    1993-06-01

    Discharge patterns of single eighth nerve fibers in the bullfrog, Rana catesbeiana, were analyzed in response to signals consisting of multiple harmonics of a common, low-amplitude fundamental frequency. The signals were chosen to reflect the frequency and amplitude spectrum of the bullfrog's species-specific advertisement call. The phase spectrum of the signals was manipulated to produce envelopes that varied in their shapes from impulselike (sharp) to noiselike (flattened). Peripheral responses to these signals were analyzed by computing the autocorrelation functions of the spike trains and their power spectra, as well as by constructing period histograms over the time intervals of the low-frequency harmonics. In response to a phase aligned signal with an impulsive envelope, most fibers, regardless of their characteristic frequencies or place of origin within the inner ear, synchronize to the fundamental frequency of the signal. The temporal patterns of fiber discharge to these stimuli are not typically captured by that stimulus harmonic closet to the fiber characteristic frequency, as would be expected from a spectral coding mechanism for periodicity extraction, but instead directly reflect the periodicity of the stimulus envelope. Changing the phase relations between the individual harmonics constituting the signal produces changes in temporal discharge patterns of some fibers by shifting predominant synchronization away from the fundamental frequency to the low-frequency spectral peak in the complex stimuli. The proportion of fibers whose firing is captured by the fundamental frequency decreases as the waveform envelope becomes less impulselike. Fiber characteristic frequency is not highly correlated with the harmonic number to which synchronization is strongest. The higher-harmonic spectral fine structure of the signals is not reflected in fiber temporal response, regardless of the shape of the stimulus envelope, even for those harmonics within the range of

  11. Changes in the Fine Structure of Stochastic Distributions as a Consequence of Space-Time Fluctuations

    Directory of Open Access Journals (Sweden)

    Shnoll S. E.

    2006-04-01

    Full Text Available This is a survey of the fine structure stochastic distributions in measurements obtained by me over 50 years. It is shown: (1 The forms of the histograms obtained at each geographic point (at each given moment of time are similar with high probability, even if we register phenomena of completely different nature — from biochemical reactions to the noise in a gravitational antenna, or α-decay. (2 The forms of the histograms change with time. The iterations of the same form have the periods of the stellar day (1.436 min, the solar day (1.440 min, the calendar year (365 solar days, and the sidereal year (365 solar days plus 6 hours and 9 min. (3 At the same instants of the local time, at different geographic points, the forms of the histograms are the same, with high probability. (4 The forms of the histograms depend on the locations of the Moon and the Sun with respect to the horizon. (5 All the facts are proof of the dependance of the form of the histograms on the location of the measured objects with respect to stars, the Sun, and the Moon. (6 At the instants of New Moon and the maxima of solar eclipses there are specific forms of the histograms. (7 It is probable that the observed correlations are not connected to flow power changes (the changes of the gravity force — we did not find the appropriate periods in changes in histogram form. (8 A sharp anisotropy of space was discovered, registered by α-decay detectors armed with collimators. Observations at 54◦ North (the collimator was pointed at the Pole Star showed no day-long periods, as was also the case for observations at 82◦ North, near the Pole. Histograms obtained by observations with an Easterly-directed collimator were determined every 718 minutes (half stellar day and with observations using a Westerly-directed collimator. (9 Collimators rotating counter-clockwise, in parallel with the celestial equator, gave the probability of changes in histograms as the number of the

  12. The Effect of Heat on Structural Characteristics and Water Absorption Behavior of Agave Fibers

    Science.gov (United States)

    Saikia, Dip

    2008-04-01

    The structural characteristics and water absorptions behavior agave fibers were investigated over a range of temperature by using XRD, IR, TG and gravimetric methods. Three distinct thermal processes were observed during heating the fiber in the temperature range 310-760 K in air, oxygen and nitrogen invariably. The cellulose structures of the fibers were unaffected on heating up to 450 K. The samples showed thermal decomposition processes beyond 500 K. Fibers displayed a two-stage diffusion behavior. The structural parameters and kinetic of water absorption of the fibers at specific temperatures were analyzed.

  13. Water absorption characteristics and structural properties of rice for sake brewing.

    Science.gov (United States)

    Mizuma, Tomochika; Kiyokawa, Yoshifumi; Wakai, Yoshinori

    2008-09-01

    This study investigated the water absorption curve characteristics and structural properties of rice used for sake brewing. The parameter values in the water absorption rate equation were calculated using experimental data. Differences between sample parameters for rice used for sake brewing and typical rice were confirmed. The water absorption curve for rice suitable for sake brewing showed a quantitatively sharper turn in the S-shaped water absorption curve than that of typical rice. Structural characteristics, including specific volume, grain density, and powdered density of polished rice, were measured by a liquid substitution method using a Gay-Lussac pycnometer. In addition, we calculated internal porosity from whole grain and powdered grain densities. These results showed that a decrease in internal porosity resulted from invasion of water into the rice grain, and that a decrease in the grain density affected expansion during the water absorption process. A characteristic S-shape water absorption curve for rice suitable for sake brewing was related to the existence of an invisible Shinpaku-like structure.

  14. Syntheses and absorption-structure relationships of some new photosensitizer cyanine dyes

    Indian Academy of Sciences (India)

    H A Shindy; A I M Koraiem

    2002-04-01

    New biheterocyclic compound was synthesized as starting material to prepare new photosensitizers mono-, tri-, substituted tri-, azadimethine and mixed cyanine dyes. Absorption-structure relationship of the synthesized cyanine dyes were determined by studying their electronic spectral behaviour in ethanol. The structure of the compounds were identified by elemental analysis, IR and 1H NMR spectral data.

  15. Micro-X-ray absorption near edge structure spectroscopy investigations of baroque tin-amalgam mirrors at BESSY using a capillary focusing system

    Energy Technology Data Exchange (ETDEWEB)

    Bartoll, J. [Stiftung Preussische Schloesser und Gaerten, Postfach 601462, 14414 Potsdam (Germany); Roehrs, S. [Technische Universitaet Berlin, Institut fuer Chemie, Strasse des 17. Juni 135, 10623 Berlin (Germany); Erko, A. [Berliner Elektronenspeicherring-Gesellschaft fuer Synchrotronstrahlung (BESSY) mbH, Albert-Einstein Str. 15, 12489 Berlin (Germany)]. E-mail: erko@bessy.de; Firsov, A. [Berliner Elektronenspeicherring-Gesellschaft fuer Synchrotronstrahlung (BESSY) mbH, Albert-Einstein Str. 15, 12489 Berlin (Germany); Bjeoumikhov, A. [IfG-Institut fuer Geraetebau GmbH Rudower Chaussee, 29-31, 12489 Berlin (Germany); Langhoff, N. [IfG-Institut fuer Geraetebau GmbH Rudower Chaussee, 29-31, 12489 Berlin (Germany)

    2004-10-08

    An elliptically shaped glass monocapillary with a spatial resolution of 5 {mu}m has been used for the fine focusing of the pre-focused X-ray beam produced by the graded-crystal monochromator beamline, KMC-2. The flux density gain of 50 was experimentally measured. The microprobe has been used in the energy range of 3.5-15 keV. Micro-X-ray fluorescence analysis ({mu}XFA) and micro-X-ray absorption near edge structure spectroscopy ({mu}XANES) measurements on test samples and investigations of baroque tin-amalgam mirrors were done.

  16. Micro-X-ray absorption near edge structure spectroscopy investigations of baroque tin-amalgam mirrors at BESSY using a capillary focusing system

    Science.gov (United States)

    Bartoll, J.; Röhrs, S.; Erko, A.; Firsov, A.; Bjeoumikhov, A.; Langhoff, N.

    2004-10-01

    An elliptically shaped glass monocapillary with a spatial resolution of 5 μm has been used for the fine focusing of the pre-focused X-ray beam produced by the graded-crystal monochromator beamline, KMC-2. The flux density gain of 50 was experimentally measured. The microprobe has been used in the energy range of 3.5-15 keV. Micro-X-ray fluorescence analysis (μXFA) and micro-X-ray absorption near edge structure spectroscopy (μXANES) measurements on test samples and investigations of baroque tin-amalgam mirrors were done.

  17. A New Catalogue of Fine Structures Superimposed on Solar Microwave Bursts

    Institute of Scientific and Technical Information of China (English)

    Qi-Jun Fu; Yi-Hua Yan; Yu-Ying Liu; Min Wang; Shu-Juan Wang

    2004-01-01

    The 2.6-3.8 GHz, 4.5-7.5 GHz, 5.2-7.6 GHz and 0.7-1.5 GHz component spectrometers of Solar Broadband Radio Spectrometer (SBRS) started routine observations, respectively, in late August 1996, August 1999, August 1999, and June 2000. They just managed to catch the coming 23rd solar active maximum. Consequently, a large amount of microwave burst data with high temporal and high spectral resolution and high sensitivity were obtained. A variety of fine structures (FS)superimposed on microwave bursts have been found. Some of them are known, such as microwave type Ⅲ bursts, microwave spike emission, but these were observed with more detail; some are new. Reported for the first time here are microwave type U bursts with similar spectral morphology to those in decimetric and metric wavelengths, and with outstanding characteristics such as very short durations(tens to hundreds ms), narrow bandwidths, higher frequency drift rates and higher degrees of polarization. Type N and type M bursts were also observed. Detailed zebra pattern and fiber bursts at the high frequency were found. Drifting pulsation structure (DPS) phenomena closely associated with CME are considered to manifest the initial phase of the CME, and quasi-periodic pulsation with periods of tens ms have been recorded. Microwave "patches", unlike those reported previously, were observed with very short durations (about 300 ms), very high flux densities (up to 1000 sfu), very high polarization (about 100% RCP), extremely narrow bandwidths(about 5%), and very high spectral indexes. These cannot be interpreted with the gyrosynchrotron process. A superfine structure in the form of microwave FS (ZPS,type U), consisting of microwave millisecond spike emission (MMS), was also found.

  18. Fine-scale spatial genetic structure in the frankincense tree Boswellia papyrifera (Del.) Hochst. and implications for conservation

    NARCIS (Netherlands)

    Bekele, Addisalem; Duminil, J.; Wouters, D.; Bongers, F.; Smulders, M.J.M.

    2016-01-01

    The fine-scale genetic structure and how it varies between generations depends on the spatial scale of gene dispersal and other fundamental aspects of species’ biology, such as the mating system. Such knowledge is crucial for the design of genetic conservation strategies. This is particularly rel

  19. Properties of the prominence magnetic field and plasma distributions as obtained from 3D whole-prominence fine structure modeling

    Science.gov (United States)

    Gunár, S.; Mackay, D. H.

    2016-07-01

    Aims: We analyze distributions of the magnetic field strength and prominence plasma (temperature, pressure, plasma β, and mass) using the 3D whole-prominence fine structure model. Methods: The model combines a 3D magnetic field configuration of an entire prominence, obtained from non-linear force-free field simulations, with a detailed semi-empirically derived description of the prominence plasma. The plasma is located in magnetic dips in hydrostatic equilibrium and is distributed along multiple fine structures within the 3D magnetic model. Results: We show that in the modeled prominence, the variations of the magnetic field strength and its orientation are insignificant on scales comparable to the smallest dimensions of the observed prominence fine structures. We also show the ability of the 3D whole-prominence fine structure model to reveal the distribution of the prominence plasma with respect to its temperature within the prominence volume. This provides new insights into the composition of the prominence-corona transition region. We further demonstrate that the values of the plasma β are small throughout the majority of the modeled prominences when realistic photospheric magnetic flux distributions and prominence plasma parameters are assumed. While this is generally true, we also find that in the region with the deepest magnetic dips, the plasma β may increase towards unity. Finally, we show that the mass of the modeled prominence plasma is in good agreement with the mass of observed non-eruptive prominences.

  20. Impact energy analysis of quenched and tempered fine grain structural steel specimens after weld thermal cycle simulation

    Directory of Open Access Journals (Sweden)

    M. Dunđer

    2014-10-01

    Full Text Available The paper presents impact energy results of thermal cycle simulated specimens of quenched and tempered fine grain structural steel S960QL. These results are obtained by examining notched Charpy specimens. Upon performed metallographic analysis and measured hardness, total impact energy is separated into ductile and brittle components.

  1. Fine structure of the entanglement entropy in the O(2) model

    Science.gov (United States)

    Yang, Li-Ping; Liu, Yuzhi; Zou, Haiyuan; Xie, Z. Y.; Meurice, Y.

    2016-01-01

    We compare two calculations of the particle density in the superfluid phase of the O(2) model with a chemical potential μ in 1+1 dimensions. The first relies on exact blocking formulas from the Tensor Renormalization Group (TRG) formulation of the transfer matrix. The second is a worm algorithm. We show that the particle number distributions obtained with the two methods agree well. We use the TRG method to calculate the thermal entropy and the entanglement entropy. We describe the particle density, the two entropies and the topology of the world lines as we increase μ to go across the superfluid phase between the first two Mott insulating phases. For a sufficiently large temporal size, this process reveals an interesting fine structure: the average particle number and the winding number of most of the world lines in the Euclidean time direction increase by one unit at a time. At each step, the thermal entropy develops a peak and the entanglement entropy increases until we reach half-filling and then decreases in a way that approximately mirrors the ascent. This suggests an approximate fermionic picture.

  2. Constraining the Variation in Fine-Structure Constant Using SDSS DR8 QSO Spectra

    CERN Document Server

    Rahmani, H; Srianand, R

    2013-01-01

    We report a robust constrain on the possible variation of fine-structure constant, alpha = e^2/(hbar*c), obtained using O III 4959,5007, nebular emission lines from QSOs. We find Delta-alpha/alpha=-(2.1 +/- 1.6) x 10^(-5) based on a well selected sample of 2347 QSOs from Sloan Digital Sky Survey Data Release 8 with 0.02 < z < 0.74. Our result is consistent with a non-varying alpha at a level of 2 x 10^(-5) over approximately 7 Gyr. This is the largest sample of extragalactic objects yet used to constrain the variation of alpha. While this constraint is not as stringent as those determined using many-multiplet method it is free from various systematic effects. A factor of ~ 4 improvement in Delta-alpha/alpha achieved here compared to the previous study (Bahcall et al. 2004) is just consistent with what is expected based on a factor of 14 times bigger sample used here. This suggests that errors are mainly dominated by the statistical uncertainty. We also find the ratio of transition probabilities correspo...

  3. Strain-tuning of the excitonic fine structure splitting in semiconductor quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Plumhof, Johannes D.; Ding, Fei; Herklotz, Andreas; Doerr, Kathrin; Rastelli, Armando; Schmidt, Oliver G. [IFW Dresden, Helmholtzstr. 20, D-01069 Dresden (Germany); Krapek, Vlastimil; Klenovsky, Petr [Institute of Condensed Matter Physics, Masaryk University, Kotlarska 2, 61137 Brno (Czech Republic); Joens, Klaus D.; Hafenbrak, Robert; Michler, Peter [Institut fuer Halbleiteroptik und Funktionelle Grenzflaechen, University of Stuttgart, Allmandring 3, 70569 Stuttgart (Germany)

    2011-07-01

    For the creation of polarization entangled photon pairs from semiconductor quantum dots (QDs) it is important to decrease the fine structure splitting (FSS) of the neutral exciton to energies comparable to the emission linewidth. We employ a piezoelectric actuator (PMN-PT) to manipulate the excitonic emission of GaAs/AlGaAs as well as InGaAs/GaAs QDs embedded in {approx}200 nm thick (Al)GaAs membranes. By attaching the membranes on the PMN-PT we can apply anisotropic strain to the nanostructures. Polarization resolved {mu}-photoluminescence spectroscopy is used to estimate the excitonic FSS as well as the orientation of the linear polarization of the emitted light. The strain makes it possible to manipulate the FSS in a range of 70 {mu} eV. We also observe rotations of up to 70 of the linear polarization of the light emitted by neutral excitons. These effects can be explained as an strain-induced anticrossing of the bright excitonic states.

  4. Upper Chromospheric Magnetic Field of a Sunspot Penumbra: Observations of Fine Structure

    CERN Document Server

    Joshi, J; Solanki, S K; Feller, A; Collados, M; Suárez, D Orozco; Schlichenmaier, R; Franz, M; Balthasar, H; Denker, C; Berkefeld, T; Hofmann, A; Kiess, C; Nicklas, H; Yabar, A Pastor; Rezaei, R; Schmidt, D; Schmidt, W; Sobotka, M; Soltau, D; Staude, J; Strassmeier, K G; Volkmer, R; von der Lühe, O; Waldmann, T

    2016-01-01

    The fine-structure of magnetic field of a sunspot penumbra in the upper chromosphere is to be explored and compared to that in the photosphere. High spatial resolution spectropolarimetric observations were recorded with the 1.5-meter GREGOR telescope using the GREGOR Infrared Spectrograph (GRIS). The observed spectral domain includes the upper chromospheric He I triplet at 1083.0 nm and the photospheric Si I 1082.7 nm and Ca I 1083.3 nm spectral lines. The upper chromospheric magnetic field is obtained by inverting the He I triplet assuming a Milne-Eddington type model atmosphere. A height dependent inversion was applied to the Si I 1082.7 nm and Ca I 1083.3 nm lines to obtain the photospheric magnetic field. We find that the inclination of the magnetic field shows variations in the azimuthal direction both in the photosphere, but also in the upper chromosphere. The chromospheric variations remarkably well coincide with the variations in the inclination of the photospheric field and resemble the well-known sp...

  5. Helical motions of fine-structure prominence threads observed by Hinode and IRIS

    CERN Document Server

    Okamoto, Takenori J; Tsuneta, Saku

    2016-01-01

    Fine-structure dynamics in solar prominences holds critical clues to understanding their physical nature of significant space-weather implications. We report evidence of rotational motions of horizontal helical threads in two active-region prominences observed by the \\emph{Hinode} and/or \\emph{IRIS} satellites at high resolution. In the first event, we found transverse motions of brightening threads at speeds up to 55~km~s$^{-1}$ seen in the plane of the sky. Such motions appeared as sinusoidal space--time trajectories with a typical period of $\\sim$390~s, which is consistent with plane-of-sky projections of rotational motions. Phase delays at different locations suggest propagation of twists along the threads at phase speeds of 90--270~km~s$^{-1}$. At least 15 episodes of such motions occurred in two days, none associated with any eruption. For these episodes, the plane-of-sky speed is linearly correlated with the vertical travel distance, suggestive of a constant angular speed. In the second event, we found...

  6. All-Optical dc Nanotesla Magnetometry Using Silicon Vacancy Fine Structure in Isotopically Purified Silicon Carbide

    Science.gov (United States)

    Simin, D.; Soltamov, V. A.; Poshakinskiy, A. V.; Anisimov, A. N.; Babunts, R. A.; Tolmachev, D. O.; Mokhov, E. N.; Trupke, M.; Tarasenko, S. A.; Sperlich, A.; Baranov, P. G.; Dyakonov, V.; Astakhov, G. V.

    2016-07-01

    We uncover the fine structure of a silicon vacancy in isotopically purified silicon carbide (4H-28SiC) and reveal not yet considered terms in the spin Hamiltonian, originated from the trigonal pyramidal symmetry of this spin-3 /2 color center. These terms give rise to additional spin transitions, which would be otherwise forbidden, and lead to a level anticrossing in an external magnetic field. We observe a sharp variation of the photoluminescence intensity in the vicinity of this level anticrossing, which can be used for a purely all-optical sensing of the magnetic field. We achieve dc magnetic field sensitivity better than 100 nT /√{Hz } within a volume of 3 ×10-7m m3 at room temperature and demonstrate that this contactless method is robust at high temperatures up to at least 500 K. As our approach does not require application of radio-frequency fields, it is scalable to much larger volumes. For an optimized light-trapping waveguide of 3 mm3 , the projection noise limit is below 100 fT /√{Hz } .

  7. The Potamophylax nigricornis group (Trichoptera, Limnephilidae: resolution of phylogenetic species by fine structure analysis

    Directory of Open Access Journals (Sweden)

    Oláh, J.

    2013-11-01

    Full Text Available Applying the phylogenetic species concept and the sexual selection theory we have reviewed some natal aspects of incipient species and their accelerated evolution. How can we recognise early stages of divergence? Which selection pressures are at work during speciation? Which pathways accelerate the speed of speciation? Which kinds of trait variabilities makes difficult to find initial split criteria? Elaborating the principles of Fine Structure Analysis (FSA and the morphological Initial Split Criteria (ISP it was discovered that the European spring dwelling caddisfly Potamophylax nigricornis doesn’tbelong to a single species. It represents an entire species group with seventeen peripatric species evolving on the southernperipheries of the distributional area. Four new species subgroups have been erected: Potamophylax nigricornis new species subgroup, P. elegantulus new species subgroup, P. horgos new species subgroup, P. simas new species subgroup. Eleven new species have been described: Potamophylax apados sp. nov., P. fules sp. nov., P. fureses sp. nov., P. hasas sp. novov., P. horgos sp. nov., P. kethas sp. nov., P. lemezes sp. nov., P. peremes sp. nov., P. simas sp. nov., P. tuskes sp. nov., P. ureges sp. nov. One Potamophylax sp. nov. has been differentiated and three new species status have been documented:Potamophylax elegantulus (Klapálek stat. n., P. mista (Navás stat. nov., P. testaceus (Zetterstedt stat. nov.

  8. Preferred Compression Speed for Speech and Music and Its Relationship to Sensitivity to Temporal Fine Structure

    Science.gov (United States)

    Sęk, Aleksander

    2016-01-01

    Multichannel amplitude compression is widely used in hearing aids. The preferred compression speed varies across individuals. Moore (2008) suggested that reduced sensitivity to temporal fine structure (TFS) may be associated with preference for slow compression. This idea was tested using a simulated hearing aid. It was also assessed whether preferences for compression speed depend on the type of stimulus: speech or music. Twenty-two hearing-impaired subjects were tested, and the stimulated hearing aid was fitted individually using the CAM2A method. On each trial, a given segment of speech or music was presented twice. One segment was processed with fast compression and the other with slow compression, and the order was balanced across trials. The subject indicated which segment was preferred and by how much. On average, slow compression was preferred over fast compression, more so for music, but there were distinct individual differences, which were highly correlated for speech and music. Sensitivity to TFS was assessed using the difference limen for frequency at 2000 Hz and by two measures of sensitivity to interaural phase at low frequencies. The results for the difference limens for frequency, but not the measures of sensitivity to interaural phase, supported the suggestion that preference for compression speed is affected by sensitivity to TFS. PMID:27604778

  9. Variation of the fine structure constant and the electron mass at early Universe

    CERN Document Server

    Scóccola, Claudia G

    2009-01-01

    In this thesis, we focus on the study of the variation of the electron mass $m_e$, and the fine structure constant $\\alpha$, at different cosmic times. We analyze the details of the recombination physics, including helium recombination, in order to find the dependences of the physical quantities on the fundamental constants. Using up-to-date CMB data, and the final 2dFGRS power spectrum, we set limits to the possible variation of the constants at recombination. We analyze the variation of $\\alpha$ and $m_e$ independently, and the case in which both variations are allowed, fitting also a set of cosmological parameters. We find a fenomenological relationship between the variation of $\\alpha$ and the variation of $m_e$, between decoupling and present time. We analyze the Barrow-Magueijo fenomenological model, which propose a variation in the electron mass induced by changes in a space-time scalar field. We present improved solutions and we estimate the model parameters using bounds on the variation of the electr...

  10. Detectability of temporal changes in fine structures near the inner core boundary beneath the eastern hemisphere

    Science.gov (United States)

    Yu, Wen-che

    2016-04-01

    The inner core boundary (ICB), where melting and solidification of the core occur, plays a crucial role in the dynamics of the Earth's interior. To probe temporal changes near the ICB beneath the eastern hemisphere, I analyze differential times of PKiKP (dt(PKiKP)), double differential times of PKiKP-PKPdf, and PKiKP coda waves from repeating earthquakes in the Southwest Pacific subduction zones. Most PKiKP differential times are within ±30 ms, comparable to inherent travel time uncertainties due to inter-event separations, and suggest no systematic changes as a function of calendar time. Double differential times measured between PKiKP codas and PKiKP main phases show promising temporal changes, with absolute values of time shifts of >50 ms for some observations. However, there are discrepancies among results from different seismographs in the same calendar time window. Negligible changes in PKiKP times, combined with changes in PKiKP coda wave times on 5 year timescales, favor a smooth inner core boundary with fine-scale structures present in the upper inner core. Differential times of PKiKP can be interpreted in the context of either melting based on translational convection, or growth based on thermochemical mantle-inner core coupling. Small dt(PKiKP) values with inherent uncertainties do not have sufficient resolution to distinguish the resultant longitudinal (melting) and latitudinal (growth) dependencies predicted on the basis of the two models on 5 year timescales.

  11. Excitonic fine structure and binding energies of excitonic complexes in single InAs quantum dashes

    Science.gov (United States)

    Mrowiński, P.; Zieliński, M.; Świderski, M.; Misiewicz, J.; Somers, A.; Reithmaier, J. P.; Höfling, S.; Sek, G.

    2016-09-01

    The fundamental electronic and optical properties of elongated InAs nanostructures embedded in quaternary InGaAlAs barrier are investigated by means of high-resolution optical spectroscopy and many-body atomistic tight-binding theory. These wire-like shaped, self-assembled nanostructures are known as quantum dashes and are typically formed during the molecular beam epitaxial growth on InP substrates. In this paper, we study properties of excitonic complexes confined in quantum dashes emitting in a broad spectral range from below 1.2 to 1.55 μm. We find peculiar trends for the biexciton and negative trion binding energies, with pronounced trion binding in smaller size quantum dashes. These experimental findings are then compared and qualitatively explained by atomistic theory. The theoretical analysis shows a fundamental role of correlation effects for the absolute values of excitonic binding energies. Eventually, we determine the bright exciton fine structure splitting (FSS), where both the experiment and theory predict a broad distribution of the splitting varying from below 50 to almost 180 μeV. We identify several key factors determining the FSS values in such nanostructures, including quantum dash size variation and composition fluctuations.

  12. Discovery of Finely Structured Dynamic Solar Corona Observed in the Hi-C Telescope

    Science.gov (United States)

    Winebarger, A.; Cirtain, J.; Golub, L.; DeLuca, E.; Savage, S.; Alexander, C.; Schuler, T.

    2014-01-01

    In the summer of 2012, the High-resolution Coronal Imager (Hi-C) flew aboard a NASA sounding rocket and collected the highest spatial resolution images ever obtained of the solar corona. One of the goals of the Hi-C flight was to characterize the substructure of the solar corona. We therefore examine how the intensity scales from AIA resolution to Hi-C resolution. For each low-resolution pixel, we calculate the standard deviation in the contributing high-resolution pixel intensities and compare that to the expected standard deviation calculated from the noise. If these numbers are approximately equal, the corona can be assumed to be smoothly varying, i.e. have no evidence of substructure in the Hi-C image to within Hi-C's ability to measure it given its throughput and readout noise. A standard deviation much larger than the noise value indicates the presence of substructure. We calculate these values for each low-resolution pixel for each frame of the Hi-C data. On average, 70 percent of the pixels in each Hi-C image show no evidence of substructure. The locations where substructure is prevalent is in the moss regions and in regions of sheared magnetic field. We also find that the level of substructure varies significantly over the roughly 160 s of the Hi-C data analyzed here. This result indicates that the finely structured corona is concentrated in regions of heating and is highly time dependent.

  13. Formation of galaxies in {\\Lambda}CDM cosmologies. I. The fine structure of disc galaxies

    CERN Document Server

    Doménech-Moral, Mariola; Domínguez-Tenreiro, Rosa; Serna, Arturo

    2012-01-01

    We present a detailed analysis of the global and fine structure of four middle-mass disc galaxies obtained from simulations in a $\\Lambda$CDM scenario. These objects have photometric D/T ratios in good agreement with those observed for late-type spirals, as well as kinematic properties in agreement with the observational Tully-Fisher relation. We identify the different dynamical components at z=0 on the basis of both orbital parameters and the binding energy of stars in the galaxy. In this way, we recognize a slowly rotating centrally concentrated spheroid, and two disc components supported by rotation: a thin disc with stars in nearly circular orbits, and a thick disc with orbital parameters transitional between the thin disc and the spheroid. The spheroidal component is composed mainly by old, metal-poor and {\\alpha}-enhanced stars. The distribution of metals in this component shows, however, a clear bimodality with a low-metallicity peak, which could be related to a classical bulge, and a high-metallicity ...

  14. Restricted gene flow and fine-scale population structuring in tool using New Caledonian crows

    Science.gov (United States)

    Rutz, C.; Ryder, T. B.; Fleischer, R. C.

    2012-04-01

    New Caledonian crows Corvus moneduloides are the most prolific avian tool users. It has been suggested that some aspects of their complex tool use behaviour are under the influence of cultural processes, involving the social transmission—and perhaps even progressive refinement—of tool designs. Using microsatellite and mt-haplotype profiling of crows from three distinct habitats (dry forest, farmland and beachside habitat), we show that New Caledonian crow populations can exhibit significant fine-scale genetic structuring. Our finding that some sites of genetic and/or cultural isolation of crow groups. Restricted movement of birds between local populations at such small spatial scales, especially across habitat boundaries, illustrates how specific tool designs could be preserved over time, and how tool technologies of different crow groups could diverge due to drift and local selection pressures. Young New Caledonian crows have an unusually long juvenile dependency period, during which they acquire complex tool-related foraging skills. We suggest that the resulting delayed natal dispersal drives population-divergence patterns in this species. Our work provides essential context for future studies that examine the genetic makeup of crow populations across larger geographic areas, including localities with suspected cultural differences in crow tool technologies.

  15. Fine structure of Delia platura (Meigen) (Diptera: Anthomyiidae) revealed by scanning electron microscopy.

    Science.gov (United States)

    Wang, Qi-Ke; Yang, Yan-Zhi; Liu, Mei-Qin; Zhang, Dong

    2014-08-01

    Delia platura (Meigen) is a phytophagous fly that can cause significant crop losses. To obtain a better understanding of the external morphology of this species, adult D. platura is studied using scanning electron microscopy. Organs or structures that are important for taxonomy, such as the compound eyes, spiracles, pulvilli, wings, and genitalia are highlighted to complement previous description based on light microscope. Mesothoracic and metathoracic spiracles of D. platura that provide efficiency in preventing entrance of fine materials or dust into the tracheal system are morphologically different. In addition, the elongate-oval pulvillus is densely covered with tenent setae with spoon-like tip, which can increase the number of contact points for attachment to a surface. Four types of sensilla are observed on the male genitalia of D. platura including: trichoid sensilla, chaetic sensilla, three subtypes of campaniform sensilla, and basiconic sensilla. Long bristles and microtrichiae are observed on the female genitalia of D. platura. The possible function of sensilla located in the genitalia of D. platura is discussed. Microsc. Res. Tech. 77:619-630, 2014. © 2014 Wiley Periodicals, Inc.

  16. Fine structure of the landers fault zone: segmentation and the rupture process.

    Science.gov (United States)

    Li, Y G; Aki, K; Vidale, J E; Lee, W H; Marone, C J

    1994-07-15

    Observations and modeling of 3- to 6-hertz seismic shear waves trapped within the fault zone of the 1992 Landers earthquake series allow the fine structure and continuity of the zone to be evaluated. The fault, to a depth of at least 12 kilometers, is marked by a zone 100 to 200 meters wide where shear velocity is reduced by 30 to 50 percent. This zone forms a seismic waveguide that extends along the southern 30 kilometers of the Landers rupture surface and ends at the fault bend about 18 kilometers north of the main shock epicenter. Another fault plane waveguide, disconnected from the first, exists along the northern rupture surface. These observations, in conjunction with surface slip, detailed seismicity patterns, and the progression of rupture along the fault, suggest that several simple rupture planes were involved in the Landers earthquake and that the inferred rupture front hesitated or slowed at the location where the rupture jumped from one to the next plane. Reduction in rupture velocity can tentatively be attributed to fault plane complexity, and variations in moment release can be attributed to variations in available energy.

  17. The Oklo bound on the time variation of the fine-structure constant revisited

    CERN Document Server

    Damour, Thibault Marie Alban Guillaume; Damour, Thibault; Dyson, Freeman

    1996-01-01

    It has been pointed out by Shlyakhter that data from the natural fission reactors which operated about two billion years ago at Oklo (Gabon) had the potential of providing an extremely tight bound on the variability of the fine-structure constant alpha. We revisit the derivation of such a bound by: (i) reanalyzing a large selection of published rare-earth data from Oklo, (ii) critically taking into account the very large uncertainty of the temperature at which the reactors operated, and (iii) connecting in a new way (using isotope shift measurements) the Oklo-derived constraint on a possible shift of thermal neutron-capture resonances with a bound on the time variation of alpha. Our final (95% C.L.) results are: -0.9 \\times 10^{-7} <(alpha^{Oklo} - alpha^{now})/alpha <1.2\\times 10^{-7} and -6.7 \\times 10^{-17} {yr}^{-1} < {\\dot alpha}^{averaged}/alpha <5.0\\times10^{-17} {yr}^{-1}.

  18. Bound on the variation in the fine structure constant implied by Oklo data

    CERN Document Server

    Hamdan, Leila

    2015-01-01

    Dynamical models of dark energy can imply that the fine structure constant $\\alpha$ varies over cosmological time scales. Data on shifts in resonance energies $E_r$ from the Oklo natural fission reactor have been used to place restrictive bounds on the change in $\\alpha$ over the last 1.8 billion years. We review the uncertainties in these analyses, focussing on corrections to the standard estimate of $k_\\alpha\\!=\\!\\alpha\\,dE_r/d\\alpha$ due to Damour and Dyson. Guided, in part, by the best practice for assessing systematic errors in theoretical estimates spelt out by Dobaczewski et al. [in J. Phys. G: Nucl. Part. Phys. 41, 074001 (2014)], we compute these corrections in a variety of models tuned to reproduce existing nuclear data. Although the net correction is uncertain to within a factor of 2 or 3, it constitutes at most no more than 25% of the Damour-Dyson estimate of $k_\\alpha$. Making similar allowances for the uncertainties in the modeling of the operation of the Oklo reactors, we conclude that the rela...

  19. Dynamic magnetization models for soft ferromagnetic materials with coarse and fine domain structures

    Energy Technology Data Exchange (ETDEWEB)

    Zirka, S.E., E-mail: zirka@email.dp.ua [Department of Physics and Technology, Dnepropetrovsk National University, Gagarin 72, 49050 Dnepropetrovsk (Ukraine); Moroz, Y.I. [Department of Physics and Technology, Dnepropetrovsk National University, Gagarin 72, 49050 Dnepropetrovsk (Ukraine); Steentjes, S.; Hameyer, K. [Institute of Electrical Machines, RWTH Aachen University, Schinkelstr. 4, 52056 Aachen (Germany); Chwastek, K. [Faculty of Electrical Engineering, Czestochowa University of Technology, al. AK 17, 42-201 Czestochowa (Poland); Zurek, S. [Megger Instruments Ltd., Archcliffe Road, Dover, Kent, CT17 9EN (United Kingdom); Harrison, R.G. [Department of Electronics, Carleton University, Ottawa, Canada K1S 5B6 (Canada)

    2015-11-15

    We consider dynamic models, both numerical and analytical, that reproduce the magnetization field H(B) and the energy loss in ferromagnetic sheet materials with different domain structures. Conventional non-oriented (NO) and grain-oriented (GO) electrical steels are chosen as typical representatives of fine-domain and coarse-domain materials. The commonly-accepted loss separation procedures in these materials are critically analyzed. The use of a well-known simplified (“classical”) expression for the eddy-current loss is identified as the primary source of mistaken evaluations of excess loss in NO steel, in which the loss components can only be evaluated using the Maxwell (penetration) equation. The situation is quite different in GO steel, in which the loss separation is uncertain, but the total dynamic loss is several times higher than that explained by any version (numerical or analytical) of the classical approach. To illustrate the uncertainty of the loss separation in GO steel, we show that the magnetization field, and thus the total loss, in this material can be represented with equal accuracy using either the existing three-component approach or our proposed two-component technique, which makes no distinction between classical eddy-current and excess fields and losses. - Highlights: • Critical analysis of a ferromagnetic-material loss-separation principle. • This is to warn materials-science engineers about the inaccuracies resulting from this principle. • A transient model having a single dynamic component is proposed.

  20. Fine-grained parallelism accelerating for RNA secondary structure prediction with pseudoknots based on FPGA.

    Science.gov (United States)

    Xia, Fei; Jin, Guoqing

    2014-06-01

    PKNOTS is a most famous benchmark program and has been widely used to predict RNA secondary structure including pseudoknots. It adopts the standard four-dimensional (4D) dynamic programming (DP) method and is the basis of many variants and improved algorithms. Unfortunately, the O(N(6)) computing requirements and complicated data dependency greatly limits the usefulness of PKNOTS package with the explosion in gene database size. In this paper, we present a fine-grained parallel PKNOTS package and prototype system for accelerating RNA folding application based on FPGA chip. We adopted a series of storage optimization strategies to resolve the "Memory Wall" problem. We aggressively exploit parallel computing strategies to improve computational efficiency. We also propose several methods that collectively reduce the storage requirements for FPGA on-chip memory. To the best of our knowledge, our design is the first FPGA implementation for accelerating 4D DP problem for RNA folding application including pseudoknots. The experimental results show a factor of more than 50x average speedup over the PKNOTS-1.08 software running on a PC platform with Intel Core2 Q9400 Quad CPU for input RNA sequences. However, the power consumption of our FPGA accelerator is only about 50% of the general-purpose micro-processors.

  1. ;Long-hissler; fine structure within auroral hiss: A review and synthesis

    Science.gov (United States)

    Kim, Howard F.; LaBelle, James; Spasojević, Maria

    2017-04-01

    One of the most prominent fine-structures of auroral hiss is the ;long-hissler;, defined here as a dispersed feature embedded within broadband auroral hiss emissions in the frequency range 1-40 kHz and lasting longer than 0.3 s. While theory is limited, there is evidence that hisslers can be used in remote sensing of density characteristics at altitudes of thousands of km. By applying an automatic threshold algorithm to VLF data collected at South Pole 2230-0130 UT daily during June-August 2014, 22 h of auroral hiss are identified on 49 of 93 days analyzed, for an occurrence rate of 9.7% during the applicable MLT interval. From manual inspection of these intervals, 414 groups (trains) of long hisslers are identified on 34 of the 49 days on which hiss occurred. Median lower (upper) frequency bounds of these features are 8 (22) kHz, median frequency-time slope is -10 kHz/s, and median hissler repetition time within a train (hissler period) is 1.2 s. Hissler period and frequency-time slope are inversely related. Data from previous studies are reviewed to provide a comprehensive description of the phenomenon. Contrary to some previous studies, subsequent long hissler features are found to commonly overlap in time, and no evidence is found for an inverse relationship between hissler train duration and geomagnetic activity.

  2. Radio Fiber Fine Structure During the Solar Flare on July 14,2000

    Institute of Scientific and Technical Information of China (English)

    钟晓春; 王蜀娟

    2004-01-01

    On July 14, 2000, a type IV solar radio burst was observed at 10:43-11:00 UT with the 1-2 GHz digital spectrometer of National Astronomical Observatories of China (NAOC). Many fiber fine structures superposed on the type IV burst were detected in the same interval. A theoretical interpretation for the fibers is performed based upon a model of magnetic-mirror loop configuration in the solar corona. In this model, the source of the fiber emission is considered as the ducting of whistler solitons within the magnetic-mirror loop. A quantitative estimation using the observed data indicats that the magnetic field strength of the radio source is about 1.451×10-2≤B0≤2.734×10-2 T, and that a fiber is composed of 4×1015 solitons occupying a volume of about 1.2×108 km3. For the duct through which the whistler solitons passed within the magnetic-mirror loop, its diameter and the length are worked out, namely, d≈120 km and Δr≈104 km, respectively.

  3. Propagation of whistler waves driven by fine structured ion beams in the magnetotail

    Science.gov (United States)

    Burinskaya, T.; Schriver, D.; Ashour-Abdalla, M.

    1994-01-01

    In a previous paper, which examined the propagation of low-frequency whistler waves generated by ion beams in the Earth's plasma sheet boundary layer (PSBL), it was found that whistler waves driven in the PSBL are focused toward the central plasma sheet due to the global magnetotail inhomogeneities; this finding may help explain the observations of magnetic noise bursts in the tail (Burinskaya et al., 1993). In this paper the same phenomenon is examined, but this time a much more realistic model is used for the ion beam in the PSBL. While the PSBL has been modeled as a solid, homogeneous ion beams with a width of one Earth radius, observations and theoretical considerations have shown that PSBL ion beams actually have a decreasing velocity profile toward the plasma sheet and that the density of the beams within the PSBL can vary locally. We consider again the propagation and generation of electromagnetic waves but in the presence of fine structured ion beams in the PSBL. Our results show that whistler waves, generated quasi-parallel to the background magnetic field, can be trapped locally within small spatial regions where the ion beam density is enhanced compared to the density of the adjacent PSBL region. Wave spectra and nonlinear saturation mechanisms are discussed.

  4. Polyphenols from Bee Pollen: Structure, Absorption, Metabolism and Biological Activity

    Directory of Open Access Journals (Sweden)

    Anna Rzepecka-Stojko

    2015-12-01

    Full Text Available Bee pollen constitutes a natural source of antioxidants such as phenolic acids and flavonoids, which are responsible for its biological activity. Research has indicated the correlation between dietary polyphenols and cardioprotective, hepatoprotective, anti-inflammatory, antibacterial, anticancerogenic, immunostimulating, antianaemic effects, as well as their beneficial influence on osseous tissue. The beneficial effects of bee pollen on health result from the presence of phenolic acids and flavonoids which possess anti-inflammatory properties, phytosterol and linolenic acid which play an anticancerogenic role, and polysaccharides which stimulate immunological activity. Polyphenols are absorbed in the alimentary tract, metabolised by CYP450 enzymes, and excreted with urine and faeces. Flavonoids and phenolic acids are characterised by high antioxidative potential, which is closely related to their chemical structure. The high antioxidant potential of phenolic acids is due to the presence and location of hydroxyl groups, a carboxyl group in the immediate vicinity of ortho-diphenolic substituents, and the ethylene group between the phenyl ring and the carboxyl group. As regards flavonoids, essential structural elements are hydroxyl groups at the C5 and C7 positions in the A ring, and at the C3′ and C4′ positions in the B ring, and a hydroxyl group at the C3 position in the C ring. Furthermore, both, the double bond between C2 and C3, and a ketone group at the C4 position in the C ring enhance the antioxidative potential of these compounds. Polyphenols have an ideal chemical structure for scavenging free radicals and for creating chelates with metal ions, which makes them effective antioxidants in vivo.

  5. Polyphenols from Bee Pollen: Structure, Absorption, Metabolism and Biological Activity.

    Science.gov (United States)

    Rzepecka-Stojko, Anna; Stojko, Jerzy; Kurek-Górecka, Anna; Górecki, Michał; Kabała-Dzik, Agata; Kubina, Robert; Moździerz, Aleksandra; Buszman, Ewa

    2015-12-04

    Bee pollen constitutes a natural source of antioxidants such as phenolic acids and flavonoids, which are responsible for its biological activity. Research has indicated the correlation between dietary polyphenols and cardioprotective, hepatoprotective, anti-inflammatory, antibacterial, anticancerogenic, immunostimulating, antianaemic effects, as well as their beneficial influence on osseous tissue. The beneficial effects of bee pollen on health result from the presence of phenolic acids and flavonoids which possess anti-inflammatory properties, phytosterol and linolenic acid which play an anticancerogenic role, and polysaccharides which stimulate immunological activity. Polyphenols are absorbed in the alimentary tract, metabolised by CYP450 enzymes, and excreted with urine and faeces. Flavonoids and phenolic acids are characterised by high antioxidative potential, which is closely related to their chemical structure. The high antioxidant potential of phenolic acids is due to the presence and location of hydroxyl groups, a carboxyl group in the immediate vicinity of ortho-diphenolic substituents, and the ethylene group between the phenyl ring and the carboxyl group. As regards flavonoids, essential structural elements are hydroxyl groups at the C5 and C7 positions in the A ring, and at the C3' and C4' positions in the B ring, and a hydroxyl group at the C3 position in the C ring. Furthermore, both, the double bond between C2 and C3, and a ketone group at the C4 position in the C ring enhance the antioxidative potential of these compounds. Polyphenols have an ideal chemical structure for scavenging free radicals and for creating chelates with metal ions, which makes them effective antioxidants in vivo.

  6. Acoustic contributions of a sound absorbing blanket placed in a double panel structure: Absorption Versus Transmission

    CERN Document Server

    Doutres, Olivier; 10.1121/1.3458845

    2010-01-01

    The objective of this paper is to propose a simple tool to estimate the absorption vs. transmission loss contributions of a multilayered blanket unbounded in a double panel structure and thus guide its optimization. The normal incidence airborne sound transmission loss of the double panel structure, without structure-borne connections, is written in terms of three main contributions; (i) sound transmission loss of the panels, (ii) sound transmission loss of the blanket and (iii) sound absorption due to multiple reflections inside the cavity. The method is applied to four different blankets frequently used in automotive and aeronautic applications: a non-symmetric multilayer made of a screen in sandwich between two porous layers and three symmetric porous layers having different pore geometries. It is shown that the absorption behavior of the blanket controls the acoustic behavior of the treatment at low and medium frequencies and its transmission loss at high frequencies. Acoustic treatment having poor sound ...

  7. Graphene-sandwiched silicon structures for greatly enhanced unpolarized light absorption

    Science.gov (United States)

    Shi, Kaifeng; Haque, Riaz R.; Mao, Ling-Feng; Lu, Zhaolin

    2015-03-01

    Based on the attenuated total reflection configuration, a multi-layer graphene (MLG) sandwiched silicon structure is proposed for greatly enhancing light absorption over a broad spectral range (1000-2000 nm). At specific incident angles, the electric field in the sandwiched graphene can be simultaneously enhanced for both transverse electric (TE) and transverse magnetic (TM) polarized light. Numerical analysis and finite-difference time-domain simulation demonstrate over 80% and 70% light absorption for TE- and TM-polarized light, respectively. Owing to the unique optical properties of graphene, the absorption of any photon by graphene may give rise to an electron-hole pair. Thus, the greatly enhanced absorption of unpolarized, broadband light may find significant applications in future photovoltaic devices. However, the excess energy carried by the electron-hole pair can dissipate within a sub-picosecond due to the ultra-fast intraband carrier relaxation, which is the challenge for photovoltaic application and will also be discussed.

  8. Symmetry Breaking and Fine Structure Splitting in Zincblende Quantum Dots: Atomistic Simulations of Long-Range Strain and Piezoelectric Field

    Science.gov (United States)

    Ahmed, Shaikh; Usman, Muhammad; Heitzinger, Clemens; Rahman, Rajib; Schliwa, Andrei; Klimeck, Gerhard

    2007-04-01

    Electrons and holes captured in self-assembled quantum dots (QDs) are subject to symmetry breaking that cannot be represented in with continuum material representations. Atomistic calculations reveal symmetry lowering due to effects of strain and piezo-electric fields. These effects are fundamentally based on the crystal topology in the quantum dots. This work studies these two competing effects and demonstrates the fine structure splitting that has been demonstrated experimentally can be attributed to the underlying atomistic structure of the quantum dots.

  9. Identification of sources of lead in the atmosphere by chemical speciation using X-ray absorption near-edge structure (XANES) spectroscopy.

    Science.gov (United States)

    Sakata, Kohei; Sakaguchi, Aya; Tanimizu, Masaharu; Takaku, Yuichi; Yokoyama, Yuka; Takahashi, Yoshio

    2014-02-01

    Sources of Pb pollution in the local atmosphere together with Pb species, major ions, and heavy metal concentrations in a size-fractionated aerosol sample from Higashi-Hiroshima (Japan) have been determined by X-ray absorption near-edge structure (XANES) spectroscopy, ion chromatography, and ICP-MS/AES, respectively. About 80% of total Pb was concentrated in fine aerosol particles. Lead species in the coarse aerosol particles were PbC2O4, 2PbCO3 Pb(OH)2, and Pb(NO3)2, whereas Pb species in the fine aerosol particles were PbC2O4, PbSO4, and Pb(NO3)2. Chemical speciation and abundance data suggested that the source of Pb in the fine aerosol particles was different from that of the coarse ones. The dominant sources of Pb in the fine aerosol particles were judged to be fly ash from a municipal solid waste incinerator and heavy oil combustion. For the coarse aerosol particles, road dust was considered to be the main Pb source. In addition to Pb species, elemental concentrations in the aerosols were also determined. The results suggested that Pb species in size-fractionated aerosols can be used to identify the origin of aerosol particles in the atmosphere as an alternative to Pb isotope ratio measurement.

  10. Analysis of Absorption Characteristics of Conductor-Grounded Lossy Dielectric Periodic Structures by Oblique Incidence

    Institute of Scientific and Technical Information of China (English)

    YANG Li; XU Shanjia

    2001-01-01

    The absorption characteristics oflossy dielectric periodic structures by an oblique in-cidence are analyzed using a method, which combinesthe Multimode Network Theory with the RigorousMode Matching Method. The periodic structures areconductor-grounded and can have arbitrary grooveprofiles. Extensive numerical results are given in thepaper to provide the theoretical predictions for a novelapplication of lossy dielectric periodic structure as thecover of the stealth.

  11. A unified description for dipoles of the fine-structure constant and SnIa Hubble diagram in Finslerian universe

    Energy Technology Data Exchange (ETDEWEB)

    Li, Xin [Chongqing University, Department of Physics, Chongqing (China); Chinese Academy of Sciences, State Key Laboratory Theoretical Physics, Institute of Theoretical Physics, Beijing (China); Lin, Hai-Nan [Chinese Academy of Sciences, Institute of High Energy Physics, Beijing (China); Wang, Sai [Chinese Academy of Sciences, State Key Laboratory Theoretical Physics, Institute of Theoretical Physics, Beijing (China); Chang, Zhe [Chinese Academy of Sciences, Institute of High Energy Physics, Beijing (China); Chinese Academy of Sciences, State Key Laboratory Theoretical Physics, Institute of Theoretical Physics, Beijing (China)

    2015-05-15

    We propose a Finsler spacetime scenario of the anisotropic universe. The Finslerian universe requires both the fine-structure constant and the accelerating cosmic expansion to have a dipole structure and the directions of these two dipoles to be the same. Our numerical results show that the dipole direction of the SnIa Hubble diagram locates at (l,b) = (314.6 {sup circle} ± 20.3 {sup circle},-11.5 {sup circle} ± 12.1 {sup circle}) with magnitude B = (-3.60 ± 1.66) x 10{sup -2}. The dipole direction of the fine-structure constant locates at (l,b) = (333.2 {sup circle} ± 8.8 {sup circle},-12.7 {sup circle} ± 6.3 {sup circle}) with magnitude B = (0.97 ± 0.21) x 10{sup -5}. The angular separation between the two dipole directions is about 18.2 {sup circle}. (orig.)

  12. A unified description for dipoles of the fine-structure constant and SnIa Hubble diagram in Finslerian universe

    CERN Document Server

    Li, Xin; Wang, Sai; Chang, Zhe

    2015-01-01

    We propose a Finsler spacetime scenario of the anisotropic universe. The Finslerian universe requires both the fine-structure constant and accelerating cosmic expansion have dipole structure, and the directions of these two dipoles are the same. Our numerical results show that the dipole direction of SnIa Hubble diagram locates at $(l,b)=(314.6^\\circ\\pm20.3^\\circ,-11.5^\\circ\\pm12.1^\\circ)$ with magnitude $B=(-3.60\\pm1.66)\\times10^{-2}$. And the dipole direction of the fine-structure constant locates at $(l,b)=(333.2^\\circ\\pm8.8^\\circ,-12.7^\\circ\\pm6.3^\\circ)$ with magnitude $B=(0.97\\pm0.21)\\times10^{-5}$. The angular separation between the two dipole directions is about $18.2^\\circ$.

  13. Modeling of 1—D Lossy Fine Structures Using Transformed—Space Non—Uniform PSTD

    Institute of Scientific and Technical Information of China (English)

    LIQingliang; CHENYinchao

    2003-01-01

    Although the advantages of the pseu-dospectral time domain (PSTD) has been validated in di-verse applications of electromagnetic problems based on a uniform grid, it faces a difficulty when an electromagnetic structure involves highly conductivity due to the Gibbs phenomena. In addition, its efficiency will be greatly re-duced in solving a problem with fine structure, since a denser grid is needed. In this paper, we apply a newly de-veloped transformed-space non-uniform grid PSTD tech-nique (TSNU-PSTD) to handle an application with very fine structure. By using a quadratic interpolation, we transform an non-unlform grid into a uniform one, and then we simply implement the conventional PSTD by only utilizing the standard fast Fourier transform (FFT) to de-rive PSTD update equations.

  14. Quiescent Prominences in the Era of ALMA: Simulated Observations Using the 3D Whole-prominence Fine Structure Model

    Science.gov (United States)

    Gunár, Stanislav; Heinzel, Petr; Mackay, Duncan H.; Anzer, Ulrich

    2016-12-01

    We use the detailed 3D whole-prominence fine structure model to produce the first simulated high-resolution ALMA observations of a modeled quiescent solar prominence. The maps of synthetic brightness temperature and optical thickness shown in the present paper are produced using a visualization method for synthesis of the submillimeter/millimeter radio continua. We have obtained the simulated observations of both the prominence at the limb and the filament on the disk at wavelengths covering a broad range that encompasses the full potential of ALMA. We demonstrate here extent to which the small-scale and large-scale prominence and filament structures will be visible in the ALMA observations spanning both the optically thin and thick regimes. We analyze the relationship between the brightness and kinetic temperature of the prominence plasma. We also illustrate the opportunities ALMA will provide for studying the thermal structure of the prominence plasma from the cores of the cool prominence fine structure to the prominence-corona transition region. In addition, we show that detailed 3D modeling of entire prominences with their numerous fine structures will be important for the correct interpretation of future ALMA observations of prominences.

  15. Flaring loop parameters estimated from solar decimeter type U-like and type J-like fine structures

    Science.gov (United States)

    Fernandes, Francisco C. R.; Dutra, José Augusto S. S.; Cunha da Silva, Rafael D.; Sawant, Hanumant S.

    2012-06-01

    This work presents the analysis of five fine structures in the solar radio emission, observed between June 2000 and October 2001 by the Brazilian Solar Spectroscope (BSS), in the decimeter frequency band of 950-2500 MHz. Based on their morphological characteristics identified in the dynamic spectra, the fine structures had been classified as type U-like or type J-like bursts. Such emissions are variants of the type III bursts. They support the hypothesis of generation by plasma emission mechanism, from interaction of electron beams accelerated during solar flares, propagating along closed magnetic structures, within the trapped plasma of the solar corona. The spectral and temporal characteristics of the five fine structures had been obtained from the dynamic spectra and the parameters of the agent and the emitting source have been determined, assuming both fundamental and harmonic emissions. The analysis revealed the flux density of the structures is less than 20-80 s.f.u. For assumption of harmonic emission, the interval of values for the source parameters estimated are: the loop size is (0.3-5.1) × 1010 cm; the electron beam velocity is in the range of 0.16-0.53 c; the temperature of coronal loop top is of the order of (0.25-1.55) × 107 K; and the low limit for the magnetic field is of 7-26 G. These results are in agreement with previous determinations reported in the literature.

  16. The role of fine-scale anatomical structure in the dynamics of reentry in computational models of the rabbit ventricles.

    Science.gov (United States)

    Bishop, Martin J; Plank, Gernot

    2012-09-15

    Fine-scale anatomical structures in the heart may play an important role in sustaining cardiac arrhythmias. However, the extent of this role and how it may differ between species are not fully understood. In this study we used computational modelling to assess the impact of anatomy upon arrhythmia maintenance in the rabbit ventricles. Specifically, we quantified the dynamics of excitation wavefronts during episodes of simulated tachyarrhythmias and fibrillatory arrhythmias, defined as being respectively characterised by relatively low and high spatio-temporal disorganisation.Two computational models were used: a highly anatomically detailed MR-derived rabbit ventricular model (representing vasculature, endocardial structures) and a simplified equivalent model, constructed from the same MR-data but lacking such fine-scale anatomical features. During tachyarrhythmias, anatomically complex and simplified models showed very similar dynamics; however, during fibrillatory arrhythmias, as activation wavelength decreased, the presence of fine-scale anatomical details appeared to marginally increase disorganisation of wavefronts during arrhythmias in the complex model. Although a small amount of clustering of reentrant rotor centres (filaments) around endocardial structures was witnessed in follow-up analysis (which slightly increased during fibrillation as rotor size decreased), this was significantly less than previously reported in large animals. Importantly, no anchoring of reentrant rotors was visibly identifiable in arrhythmia movies. These differences between tachy- and fibrillatory arrhythmias suggest that the relative size of reentrant rotors with respect to anatomical obstacles governs the influence of fine-scale anatomy in the maintenance of ventricular arrhythmias in the rabbit. In conclusion, our simulations suggest that fine-scale anatomical features play little apparent role in the maintenance of tachyarrhythmias in the rabbit ventricles and, contrary to

  17. DISCOVERY OF FINELY STRUCTURED DYNAMIC SOLAR CORONA OBSERVED IN THE Hi-C TELESCOPE

    Energy Technology Data Exchange (ETDEWEB)

    Winebarger, Amy R.; Cirtain, Jonathan; Savage, Sabrina; Alexander, Caroline [NASA Marshall Space Flight Center, ZP 13, Huntsville, AL 35812 (United States); Golub, Leon; DeLuca, Edward [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Schuler, Timothy, E-mail: amy.r.winebarger@nasa.gov [State University of New York College at Buffalo, 1300 Elmwood Avenue, Buffalo, NY 14222 (United States)

    2014-05-20

    In the Summer of 2012, the High-resolution Coronal Imager (Hi-C) flew on board a NASA sounding rocket and collected the highest spatial resolution images ever obtained of the solar corona. One of the goals of the Hi-C flight was to characterize the substructure of the solar corona. We therefore examine how the intensity scales from AIA resolution to Hi-C resolution. For each low-resolution pixel, we calculate the standard deviation in the contributing high-resolution pixel intensities and compare that to the expected standard deviation calculated from the noise. If these numbers are approximately equal, the corona can be assumed to be smoothly varying, i.e., have no evidence of substructure in the Hi-C image to within Hi-C's ability to measure it given its throughput and readout noise. A standard deviation much larger than the noise value indicates the presence of substructure. We calculate these values for each low-resolution pixel for each frame of the Hi-C data. On average, 70% of the pixels in each Hi-C image show no evidence of substructure. The locations where substructure is prevalent is in the moss regions and in regions of sheared magnetic field. We also find that the level of substructure varies significantly over the roughly 160 s of the Hi-C data analyzed here. This result indicates that the finely structured corona is concentrated in regions of heating and is highly time dependent.

  18. Acoustic contributions of a sound absorbing blanket placed in a double panel structure: absorption versus transmission.

    Science.gov (United States)

    Doutres, Olivier; Atalla, Noureddine

    2010-08-01

    The objective of this paper is to propose a simple tool to estimate the absorption vs. transmission loss contributions of a multilayered blanket unbounded in a double panel structure and thus guide its optimization. The normal incidence airborne sound transmission loss of the double panel structure, without structure-borne connections, is written in terms of three main contributions; (i) sound transmission loss of the panels, (ii) sound transmission loss of the blanket and (iii) sound absorption due to multiple reflections inside the cavity. The method is applied to four different blankets frequently used in automotive and aeronautic applications: a non-symmetric multilayer made of a screen in sandwich between two porous layers and three symmetric porous layers having different pore geometries. It is shown that the absorption behavior of the blanket controls the acoustic behavior of the treatment at low and medium frequencies and its transmission loss at high frequencies. Acoustic treatment having poor sound absorption behavior can affect the performance of the double panel structure.

  19. Dual-Band Perfect Absorption by Breaking the Symmetry of Metamaterial Structure

    Science.gov (United States)

    Hai, Le Dinh; Qui, Vu Dinh; Dinh, Tiep Hong; Hai, Pham; Giang, Trinh Thị; Cuong, Tran Manh; Tung, Bui Son; Lam, Vu Dinh

    2017-02-01

    Since the first proposal of Landy et al. (Phys Rev Lett 100:207402, 2008), the metamaterial perfect absorber (MPA) has rapidly become one of the most crucial research trends. Recently, dual-band, multi-band and broadband MPA have been highly desirable in electronic applications. In this paper, we demonstrate and evaluate a MPA structure which can generate dual-band absorption operating at the microwave frequency by breaking the symmetry of structure. There is an agreement between simulation and experimental results. The results can be explained by using the equivalent LC circuit and the electric field distribution of this structure. In addition, various structures with different symmetry configurations were studied to gain greater insight into the absorption.

  20. Rate Constants for Fine-structure Excitations in O–H Collisions with Error Bars Obtained by Machine Learning

    Science.gov (United States)

    Vieira, Daniel; Krems, Roman V.

    2017-02-01

    We present an approach using a combination of coupled channel scattering calculations with a machine-learning technique based on Gaussian Process regression to determine the sensitivity of the rate constants for non-adiabatic transitions in inelastic atomic collisions to variations of the underlying adiabatic interaction potentials. Using this approach, we improve the previous computations of the rate constants for the fine-structure transitions in collisions of O({}3{P}j) with atomic H. We compute the error bars of the rate constants corresponding to 20% variations of the ab initio potentials and show that this method can be used to determine which of the individual adiabatic potentials are more or less important for the outcome of different fine-structure changing collisions.