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Sample records for 304l stainless steel

  1. Simulation of Friction Stir Processing in 304L Stainless Steel

    Directory of Open Access Journals (Sweden)

    MilesM.P.

    2016-01-01

    Full Text Available A major dilemma facing the nuclear industry is repair or replacement of stainless steel reactor components that have been exposed to neutron irradiation. When conventional fusion welding is used for weld repair, the high temperatures and thermal stresses inherent in the process enhance the growth of helium bubbles, causing intergranular cracking in the heat-affected zone (HAZ. Friction stir processing (FSP has potential as a weld repair technique for irradiated stainless steel, because it operates at much lower temperatures than fusion welding, and is therefore less likely to cause cracking in the HAZ. Numerical simulation of the FSP process in 304L stainless steel was performed using an Eulerian finite element approach. Model input required flow stresses for the large range of strain rates and temperatures inherent in the FSP process. Temperature predictions in three locations adjacent to the stir zone were accurate to within 4% of experimentally measure values. Prediction of recrystallized grain size at a location about 6mm behind the tool center was less accurate, because the empirical model employed for the prediction did not account for grain growth that occurred after deformation in the experiment was halted.

  2. Weld solidification cracking in 304 to 304L stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Hochanadel, Patrick W [Los Alamos National Laboratory; Lienert, Thomas J [Los Alamos National Laboratory; Martinez, Jesse N [Los Alamos National Laboratory; Martinez, Raymond J [Los Alamos National Laboratory; Johnson, Matthew Q [Los Alamos National Laboratory

    2010-01-01

    A series of annulus welds were made between 304 and 304L stainless steel coaxial tubes using both pulsed laser beam welding (LBW) and pulsed gas tungsten arc welding (GTAW). In this application, a change in process from pulsed LBW to pulsed gas tungsten arc welding was proposed to limit the possibility of weld solidification cracking since weldability diagrams developed for GTAW display a greater range of compositions that are not crack susceptible relative to those developed for pulsed LBW. Contrary to the predictions of the GTAW weldability diagram, cracking was found. This result was rationalized in terms of the more rapid solidification rate of the pulsed gas tungsten arc welds. In addition, for the pulsed LBW conditions, the material compositions were predicted to be, by themselves, 'weldable' according to the pulsed LBW weldability diagram. However, the composition range along the tie line connecting the two compositions passed through the crack susceptible range. Microstructurally, the primary solidification mode (PSM) of the material processed with higher power LBW was determined to be austenite (A), while solidification mode of the materials processed with lower power LBW apparently exhibited a dual PSM of both austenite (A) and ferrite-austenite (FA) within the same weld. The materials processed by pulsed GT A W showed mostly primary austenite solidification, with some regions of either primary austenite-second phase ferrite (AF) solidification or primary ferrite-second phase austenite (FA) solidification. This work demonstrates that variations in crack susceptibility may be realized when welding different heats of 'weldable' materials together, and that slight variations in processing can also contribute to crack susceptibility.

  3. HYDROGEN-ASSISTED FRACTURE IN FORGED TYPE 304L AUSTENITIC STAINLESS STEEL

    Energy Technology Data Exchange (ETDEWEB)

    Switzner, Nathan; Neidt, Ted; Hollenbeck, John; Knutson, J.; Everhart, Wes; Hanlin, R. [University of Missouri-Kansas City; Bergen, R. [Precision Metal Products; Balch, D. K. [Sandia Natl Laboratory

    2012-09-06

    Austenitic stainless steels generally have good resistance to hydrogen-assisted fracture; however, structural designs for high-pressure gaseous hydrogen are constrained by the low strength of this class of material. Forging is used to increase the low strength of austenitic stainless steels, thus improving the efficiency of structural designs. Hydrogen-assisted racture, however, depends on microstructural details associated with manufacturing. In this study, hydrogen-assisted fracture of forged type 304L austenitic stainless steel is investigated. Microstructural variation in multi-step forged 304L was achieved by forging at different rates and temperatures, and by process annealing. High internal hydrogen content in forged type 304L austenitic stainless steel is achieved by thermal precharging in gaseous hydrogen and results in as much as 50% reduction of tensile ductility.

  4. Dynamic compressive response of wrought and additive manufactured 304L stainless steels

    Directory of Open Access Journals (Sweden)

    Nishida Erik

    2015-01-01

    Full Text Available Additive manufacturing (AM technology has been developed to fabricate metal components that include complex prototype fabrication, small lot production, precision repair or feature addition, and tooling. However, the mechanical response of the AM materials is a concern to meet requirements for specific applications. Differences between AM materials as compared to wrought materials might be expected, due to possible differences in porosity (voids, grain size, and residual stress levels. When the AM materials are designed for impact applications, the dynamic mechanical properties in both compression and tension need to be fully characterized and understood for reliable designs. In this study, a 304L stainless steel was manufactured with AM technology. For comparison purposes, both the AM and wrought 304L stainless steels were dynamically characterized in compression Kolsky bar techniques. They dynamic compressive stress-strain curves were obtained and the strain rate effects were determined for both the AM and wrought 304L stainless steels. A comprehensive comparison of dynamic compressive response between the AM and wrought 304L stainless steels was performed. SAND2015-0993 C.

  5. Mitigation of Stress Corrosion Cracking Susceptibility of Machined 304L Stainless Steel Through Laser Peening

    Science.gov (United States)

    Sundar, R.; Ganesh, P.; Kumar, B. Sunil; Gupta, R. K.; Nagpure, D. C.; Kaul, R.; Ranganathan, K.; Bindra, K. S.; Kain, V.; Oak, S. M.; Singh, Bijendra

    2016-09-01

    The paper describes an experimental study aimed at suppressing stress corrosion cracking susceptibility of machined 304L stainless steel specimens through laser shock peening. The study also evaluates a new approach of oblique laser shock peening to suppress stress corrosion cracking susceptibility of internal surface of type 304L stainless steel tube. The results of the study, performed with an indigenously developed 2.5 J/7 ns Nd:YAG laser, demonstrated that laser shock peening effectively suppresses chloride stress corrosion cracking susceptibility of machined surface of type 304L stainless steel. In the investigated range of incident laser power density (3.2-6.4 GW/cm2), machined specimens peened with power density of 4.5 and 6.4 GW/cm2 displayed lower stress corrosion cracking susceptibility considerably than those treated with 3.2 and 3.6 GW/cm2 in boiling magnesium chloride test. Oblique laser shock peening, performed on machined internal surface of a type 304L stainless steel tube (OD = 111 mm; ID = 101 mm), was successful in introducing residual compressive surface stresses which brought about significant suppression of its stress corrosion cracking susceptibility. The technique of oblique laser shock peening, in spite of its inherent limitations on the length of peened region being limited by tube internal diameter and the need for access from both the sides, presents a simplified approach for peening internal surface of small tubular components.

  6. Dynamic Strength of 304L stainless steel under impact

    Science.gov (United States)

    Werdiger, Meir; Bakshi, Lior; Glam, Benny; Pistinner, Shlomi

    2011-06-01

    We use the Asay self consistent technique to analyze the effects of pressure hardening and strain hardening on SS304L. Previously unloading experiment has been used to infer the strength of this material at high pressure, and recently the Johnson-Cook (JC) model has been calibrated at low strain rate. Release and reshock experiments with impact velocity range of 300-1700 m/s were preformed. We used VISAR to extract the particle velocity of the SS304L- LiF window interface. The velocity profile compared to hydrodynamic simulation using JC model. Our unloading experiments have clearly demonstrate that the material yield but does not fail. Thus infer substantial effect of pressure hardening.

  7. Passivity and passivity breakdown of 304L stainless steel in hot and concentrated nitric acid

    International Nuclear Information System (INIS)

    The objective of this study is to characterize the oxidation behavior of 304L stainless steel (SS) in representative conditions of spent nuclear fuel reprocessing, i.e. in hot and concentrated nitric acid. In these conditions the SS electrochemical potential is in the passive domain and its corrosion rate is low. However when the media becomes more aggressive, the potential may be shifted towards the trans-passive domain characterized with a high corrosion rate. Passivity and passivity breakdown in the trans-passive domain are of a major interest for the industry. So as to characterize these phenomenons, this work was undertaken with the following representative conditions: a 304L SS from an industrial sheet was studied, the media was hot and concentrated HNO3, long term tests were performed. First, the surface of an immersed 304L SS was characterized with several complementary techniques from the micro to the nanometer scale. Then oxidation kinetics was studied in the passive and in the trans-passive domain. The oxidation behavior was studied thanks to weight loss determination and surface analysis. Finally, oxidation evolution as a function of the potential was studied from the passive to the trans-passive domain. In particular, this allowed us to obtain the anodic curve of 304L SS in hot and concentrated and to define precisely the 304L SS limits of in such conditions. (author)

  8. Development of Nanocrystalline 304L Stainless Steel by Large Strain Cold Working

    OpenAIRE

    Marina Odnobokova; Andrey Belyakov; Rustam Kaibyshev

    2015-01-01

    The microstructural changes leading to nanocrystalline structure development and the respective tensile properties were studied in a 304L stainless steel subjected to large strain cold rolling at ambient temperature. The cold rolling was accompanied by the development of deformation twinning and martensitic transformation. The latter readily occurred at deformation microshear bands, leading the martensite fraction to approach 0.75 at a total strain of 3. The deformation twinning followed by m...

  9. Impact energy absorption of aluminium foam fitted AISI 304L stainless steel tube

    Energy Technology Data Exchange (ETDEWEB)

    Rajendran, R. [BARC Facilities, Bhabha Atomic Research Centre, Kalpakkam 603 102, Tamilnadu (India)], E-mail: rajurajendr@yahoo.co.in; Prem Sai, K.; Chandrasekar, B. [BARC Facilities, Bhabha Atomic Research Centre, Kalpakkam 603 102, Tamilnadu (India); Gokhale, A. [Defence Metallurgical Research Laboratory, Kanchanbagh, Hyderabad 500 058 (India); Basu, S. [BARC Facilities, Bhabha Atomic Research Centre, Kalpakkam 603 102, Tamilnadu (India)

    2009-05-15

    Closed cell aluminium foam fitted AISI 304L stainless steel tube was investigated for its impact energy absorption characteristics. Quasi-static load-deflection tests were employed to establish the foam-tube interaction factor. Drop experiments were carried out using a free flight drop tower on aluminium foam fitted stainless steel tube to obtain the acceleration-time history of the hammer. Estimated deflections compared well with the experimental values. Adequate force reduction factor indicated that the foam-tube configuration is a potential energy absorber candidate for the nuclear transportation cask.

  10. Comparison of Stress Corrosion Cracking Susceptibility of Laser Machined and Milled 304 L Stainless Steel

    Science.gov (United States)

    Gupta, R. K.; Kumar, Aniruddha; Nagpure, D. C.; Rai, S. K.; Singh, M. K.; Khooha, Ajay; Singh, A. K.; Singh, Amrendra; Tiwari, M. K.; Ganesh, P.; Kaul, R.; Singh, B.

    2016-07-01

    Machining of austenitic stainless steel components is known to introduce significant enhancement in their susceptibility to stress corrosion cracking. The paper compares stress corrosion cracking susceptibility of laser machined 304 L stainless steel specimens with conventionally milled counterpart in chloride environment. With respect to conventionally milled specimens, laser machined specimens displayed more than 12 times longer crack initiation time in accelerated stress corrosion cracking test in boiling magnesium chloride as per ASTM G36. Reduced stress corrosion cracking susceptibility of laser machined surface is attributed to its predominantly ferritic duplex microstructure in which anodic ferrite phase was under compressive stress with respect to cathodic austenite.

  11. Preparation of high-performance ultrafine-grained AISI 304L stainless steel under high temperature and pressure

    Directory of Open Access Journals (Sweden)

    Peng Wang

    2016-08-01

    Full Text Available Bulk ultra-fine grained (UFG AISI 304L stainless steel with excellent mechanical properties was prepared by a high-temperature and high-pressure (HTHP method using nanocrystalline AISI 304L stainless steel powders obtained from ball milling. Samples were sintered in high-pressure conditions using the highest martensite content of AISI 304L stainless steel powders milled for 25 h. Analyses of phase composition and grain size were accomplished by X-ray diffraction and Rietveld refinement. By comparing the reverse martensite transformation under vacuum and HTHP treat, we consider that pressure can effectively promote the change in the process of transformation. Compared with the solid-solution-treated 304L, the hardness and yield strength of the samples sintered under HTHP are considerably higher. This method of preparation of UFG bulk stainless steel may be widely popularised and used to obtain UFG metallic materials with good comprehensive performance.

  12. Corrosion and microstructural aspects of dissimilar joints of titanium and type 304L stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Mudali, U. Kamachi. E-mail: kamachi@igcar.ernet.in; Ananda Rao, B.M.; Shanmugam, K.; Natarajan, R.; Raj, Baldev

    2003-09-01

    To link titanium and zirconium metal based (Ti, Zr-2, Ti-5%Ta, Ti-5%Ta-1.8Nb) dissolver vessels containing highly radioactive and concentrated corrosive nitric acid solution to other nuclear fuel reprocessing plant components made of AISI type 304L stainless steel (SS), high integrity and corrosion resistant dissimilar joints between them are necessary. Fusion welding processes produce secondary precipitates which dissolve in nitric acid, and hence solid-state processes are proposed. In this work, various dissimilar joining processes available for producing titanium-304L SS joints with adequate strength, ductility and corrosion resistance for this critical application are highlighted. Developmental efforts made at IGCAR, Kalpakkam are outlined. The possible methods and the microstructural-metallurgical properties of the joints along with corrosion results obtained with three phase (liquid, vapour, condensate) corrosion testing are discussed. Based on the results, dissimilar joint produced by the explosive joining process was adopted for plant application.

  13. Corrosion and microstructural aspects of dissimilar joints of titanium and type 304L stainless steel

    International Nuclear Information System (INIS)

    To link titanium and zirconium metal based (Ti, Zr-2, Ti-5%Ta, Ti-5%Ta-1.8Nb) dissolver vessels containing highly radioactive and concentrated corrosive nitric acid solution to other nuclear fuel reprocessing plant components made of AISI type 304L stainless steel (SS), high integrity and corrosion resistant dissimilar joints between them are necessary. Fusion welding processes produce secondary precipitates which dissolve in nitric acid, and hence solid-state processes are proposed. In this work, various dissimilar joining processes available for producing titanium-304L SS joints with adequate strength, ductility and corrosion resistance for this critical application are highlighted. Developmental efforts made at IGCAR, Kalpakkam are outlined. The possible methods and the microstructural-metallurgical properties of the joints along with corrosion results obtained with three phase (liquid, vapour, condensate) corrosion testing are discussed. Based on the results, dissimilar joint produced by the explosive joining process was adopted for plant application

  14. Dissimilar Joining of Zircaloy-4 to Type 304L Stainless Steel by Friction Welding Process

    Science.gov (United States)

    Ravi Shankar, A.; Suresh Babu, S.; Ashfaq, Mohammed; Kamachi Mudali, U.; Prasad Rao, K.; Saibaba, N.; Raj, Baldev

    2009-12-01

    Zirconium- and titanium-based dissolver vessels containing highly radioactive and concentrated corrosive nitric acid solution needs to be joined to the rest of fuel reprocessing plant made of AISI type 304L stainless steel (SS), which demands high integrity and corrosion resistant dissimilar joints. Solid-state joining process of friction welding was proposed in the present work to join zircaloy-4 and type 304L SS since fusion welding processes produce brittle intermetallic precipitates at the interface which reduce the mechanical strength as well as the corrosion resistance of the joint. The present study attempts to optimize joining parameters, without and with thin Ta and Ni interlayers that can prevent brittle intermetallic formation. Tensile test, three-point bend test, and microhardness measurements were performed on the joints. Characterization techniques such as optical microscopy, scanning electron microscopy (SEM), and x-ray diffraction (XRD) were employed. A good friction weld joint of zircaloy-4 to 304L SS was achieved with the joint strength (~540 MPa) greater than that of the base of zircaloy-4, without using any interlayer. A bend ductility of 5° was only obtained without using any interlayer. However, XRD patterns indicated the presence of intermetallics in the friction-welded joints without interlayers. Corrosion test carried out on zircaloy-4 to 304L SS friction joint in boiling 11.5 M nitric acid exhibited corrosion rate of 225 μm/year after 240 h. SEM examination of the corroded joint indicated severe intergranular corrosion attack over stainless steel and preferential dissolution at the interface.

  15. Microstructure and corrosion behavior of multipass gas tungsten arc welded 304L stainless steel

    International Nuclear Information System (INIS)

    Highlights: • Multipass gas tungsten arc welding of 304L stainless steel was successfully done. • All welds were austenitic with the presence of a small amount of δ-ferrite. • The morphology of δ-ferrite showed the lathy and skeletal δ-ferrite in the welds. • Hardness and corrosion resistance were improved by multipass welding. • The best joint properties were obtained after three passes welding. - Abstract: The purpose of this study was to discuss the effect of single pass and multipass (double and triple pass) gas tungsten arc welding (GTAW) on microstructure, hardness and corrosion behavior of 304L stainless steel. In this investigation, 308 stainless steel filler metal was used. Microstructures and hardness of the weldments were investigated using optical microscopy, scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-ray diffraction analysis (XRD) and Vickers microhardness (HV0.5). A ferritescope was also used in the non-destructive evaluation to observe the ferrite content on the weldments. Corrosion behavior of weldments in 1 M H2SO4 solution at 25 ± 1 °C was investigated using potentiodynamic polarization and immersion tests. Results indicated that the microstructure of fusion zones exhibited dendritic structure contained lathy and skeletal δ-ferrite. The contents of δ-ferrite in the weld zone increased by increasing the number of passes. Therefore, as the number of passes increased, the hardness and corrosion resistance increased

  16. Corrosion testing of type 304L stainless steel in tuff groundwater environments

    Energy Technology Data Exchange (ETDEWEB)

    Westerman, R.E.; Pitman, S.G.; Haberman, J.H.

    1987-11-01

    The stress-corrosion cracking (SCC) resistance of Type 304L stainless steel (SS) to elevated temperatures in tuff rock and tuff groundwater environments was determined under irradiated and nonirradiated conditions using U-bend specimens and slow-strain-rate tests. The steel was tested both in the solution-annealed condition and after sensitization heat treatments. The material was found to be susceptible to SCC in both the solution-annealed and solution-annealed-and-sensitized conditions when exposed to an irradiated crushed tuff rock environment containing air and water vapor at 90{sup 0}C. A similar exposure at 50{sup 0}C did not result in failure after a 25-month test duration. Specimens of sensitized 304 SS conditioned with a variety of sensitization heat treatments resisted failure during a test of 1-year duration in which a nonirradiated environment of tuff rock and groundwater held at 200{sup 0}C was allowed to boil to dryness on a cyclical basis. All specimens of sensitized 304 SS exposed to this environment failed. Slow-strain-rate studies were performed on 304L, 304, and 316L SS specimens. The 304L SS was tested in J-13 well water at 150{sup 0}C, and the 316L SS at 95{sup 0}C. Neither material showed evidence of SCC in these tests. Sensitized 304 SS did exhibit SCC in J-13 well water in tests conducted at 150{sup 0}C. 12 refs., 27 figs., 13 tabs.

  17. Corrosion testing of type 304L stainless steel in tuff groundwater environments

    International Nuclear Information System (INIS)

    The stress-corrosion cracking (SCC) resistance of Type 304L stainless steel (SS) to elevated temperatures in tuff rock and tuff groundwater environments was determined under irradiated and nonirradiated conditions using U-bend specimens and slow-strain-rate tests. The steel was tested both in the solution-annealed condition and after sensitization heat treatments. The material was found to be susceptible to SCC in both the solution-annealed and solution-annealed-and-sensitized conditions when exposed to an irradiated crushed tuff rock environment containing air and water vapor at 900C. A similar exposure at 500C did not result in failure after a 25-month test duration. Specimens of sensitized 304 SS conditioned with a variety of sensitization heat treatments resisted failure during a test of 1-year duration in which a nonirradiated environment of tuff rock and groundwater held at 2000C was allowed to boil to dryness on a cyclical basis. All specimens of sensitized 304 SS exposed to this environment failed. Slow-strain-rate studies were performed on 304L, 304, and 316L SS specimens. The 304L SS was tested in J-13 well water at 1500C, and the 316L SS at 950C. Neither material showed evidence of SCC in these tests. Sensitized 304 SS did exhibit SCC in J-13 well water in tests conducted at 1500C. 12 refs., 27 figs., 13 tabs

  18. Effect of rare earth oxide additions on oxidation behavior of AISI 304L stainless steel

    Directory of Open Access Journals (Sweden)

    Marina Fuser Pillis

    2006-12-01

    Full Text Available AISI 304L stainless steel powder compacts containing 2 vol% high purity rare earth oxides were prepared by mixing the different powders in a vibratory mill followed by pressing. The compacts thus obtained were sintered in a vacuum furnace and isothermal oxidation measurements were carried out in a muffle furnace, in air, up to 200 hours at 900 °C. The oxidized surfaces were examined in a scanning electron microscope and micro regions of the reaction products were studied using energy dispersive analysis. The addition of rare earth oxides decreased the oxidation rate of the stainless steel. Further evidence of predominant oxygen ion diffusion controlling the overall oxidation process in rare earth containing chromium oxide forming alloys has been observed.

  19. Comparative Shock Response of Additively Manufactured Versus Conventionally Wrought 304L Stainless Steel*

    Science.gov (United States)

    Wise, J. L.; Adams, D. P.; Nishida, E. E.; Song, B.; Maguire, M. C.; Carroll, J.; Reedlunn, B.; Bishop, J. E.

    2015-06-01

    Gas-gun experiments have probed the compression and release behavior of impact-loaded 304L stainless steel specimens machined from additively manufactured (AM) blocks as well as baseline ingot-derived bar stock. The AM technology allows direct fabrication of metal parts. For the present study, a velocity interferometer (VISAR) measured the time-resolved motion of samples subjected to one-dimensional (i.e., uniaxial strain) shock compression to peak stresses ranging from 0.2 to 7.5 GPa. The acquired wave-profile data have been analyzed to determine the comparative Hugoniot Elastic Limit (HEL), Hugoniot equation of state, spall strength, and high-pressure yield strength of the AM and conventional materials. Observed differences in shock loading and unloading characteristics for the two 304L source variants have been correlated to complementary Kolsky bar results for compressive and tensile testing at lower strain rates. The effects of composition, porosity, microstructure (e.g., grain size and morphology), residual stress, and sample axis orientation relative to the additive manufacturing deposition trajectory have been assessed to explain differences between the AM and baseline 304L dynamic mechanical properties. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under Contract DE-AC04-94AL85000.

  20. Repetitive Thermomechanical Processing towards Ultra Fine Grain Structure in 301, 304 and 304L Stainless Steels

    Institute of Scientific and Technical Information of China (English)

    A. Momeni; S.M. Abbasi

    2011-01-01

    Thermomechanical processing as a combination of cold rolling and annealing was performed on austenitic stainless steels 301,304 and 304L. Two cold rolling steps each one up to a reduction of 75% were combined with an intermediate annealing at 800℃ for 20 min. The final annealing was performed at.the same temperature and time. Cold rolling contributed to martensite formation at the expense of metastable austenite in the studied materials. Austenite in 301 was found to be less stable than that in 304 and 304L. Hence, higher strength characteristics in the as-quenched 301 stainless steels were attributed to the higher volume fraction of martensite. Both α'-martensite and ε-martensite were found to form as induced by deformation. However, the intensity of ε-martensite increased as the stability of austenite decreased. Annealing after cold rolling led to the reversion of austenite with an ultra fine grained structure in the order of 0.5-1 μm from the strain induced martensite. The final grain size was found to be an inverse function of the amount of strain induced martensite. The thermomechanical processing considerably improved the strength characteristics while the simultaneous decrease of elongation was rather low.

  1. Chemical interaction between granular B4C and 304L-type stainless steel materials used in BWRs in Japan

    International Nuclear Information System (INIS)

    Chemical reactions between stainless steel and boron carbide were investigated using the materials applied for control rods in BWRs in Japan, specifically 304L-type stainless steel and granular boron carbide. The reaction region consisted of 2–4 layers, in which the significant composition variation of each element was detected, especially for B and C. Assuming that the reaction layer growth obeys the parabolic law, the effective rate constant between 304L-type stainless steel and granular boron carbide was evaluated to be approximately one order of magnitude smaller than the previously reported values for boron carbide pellets or powers. This difference might originate from the loose contact between the stainless steel and the granular boron carbide in the present study. Regarding liquefaction progress, the stainless steel components were selectively dissolved in the melt; consequently, the unreacted boron carbide tended to remain. (author)

  2. Comparison of SCC Behavior of 304L Stainless Steels With and Without Boron Addition in Acidic Chloride Environment

    Science.gov (United States)

    Sivai Bharasi, N.; Pujar, M. G.; Nirmal, S.; Mallika, C.; Kamachi Mudali, U.; Angelo, P. C.

    2016-07-01

    The stress corrosion cracking (SCC) behavior of 304L B4 grade borated stainless steel (SS) as well as 304L SS was investigated by constant load and slow strain rate testing (SSRT) techniques. The microstructure, pitting, and SCC behavior of borated SS in the as-received, sensitized, and solution-annealed conditions were analyzed. Potentiodynamic anodic polarization and double loop electrochemical potentiokinetic reactivation (DLEPR) experiments were carried out to find out pitting corrosion resistance and degree of sensitization (DOS). The number of boride particles (composed of Cr, Fe, and B) were highest for the specimen solution annealed at 1423 K/2 h. Solution-annealing treatment at 1423 K/4 h was found to be beneficial in improving the corrosion resistance of borated 304L SS. Although the borated 304L SS exhibited a higher DOS, it showed improved pitting corrosion resistance compared to 304L SS. Constant load experiments revealed the time to failure to be the highest for the specimen solution annealed at 1423 K/4 h. SCC susceptibility index (Iscc) values obtained from SSRT tests were lower for solution-annealed borated 304L SS compared to the as-received and sensitized conditions. The improved SCC resistance of borated 304L SS was attributed not only to the solution-annealing treatment but also the higher stacking fault energy (SFE) value compared to 304L SS.

  3. Research on General Corrosion Property of 304L and 304NG Stainless Steels in Simulated PWR Primary Water

    Institute of Scientific and Technical Information of China (English)

    PENG; De-quan; HU; Shi-lin; ZHANG; Ping-zhu; WANG; Hui

    2012-01-01

    <正>The general corrosion behaviors of 304L and 304NG grade stainless steels in simulated pressurized water reactor (PWR) primary loop were studied using still autoclave, respectively, the corrosion test lasted for 1 680 hours. The corrosion oxide films were analyzed macroscopically and microscopically. The results are shown in Figs. 1, 2.

  4. Investigation of shot-peened austenitic stainless steel 304L by means of magnetic Barkhausen noise

    International Nuclear Information System (INIS)

    Research highlights: The results and the conclusions drawn in this paper are important for the scientific community and especially for scientist who are looking for method to characterize phase transformations in metallic materials. We show that Barkhausen noise measurements can be successfully used to monitor strain-induced martensite in austenitic stainless steels. - Abstract: Different shot peening conditions were applied to an austenitic stainless steel AISI 304L in order to transform austenite to martensite α' at different depths. Magnetic Barkhausen noise measurements performed on this steel reveal a correlation between the strength of the signal and the depth of the treatment. The combined effect of the volume fraction of martensite and the residual stress in martensite determined using X-ray diffraction analysis were found to be responsible for the evolution of the Barkhausen noise response. Using tensile plastic deformation, the residual stress in martensite was changed, giving rise to a strong increase of the Barkhausen noise activity. This variation was correlated to a modification of the sign and amplitude of the residual stress in the martensite phase. Directional measurements of the Barkhausen noise revealed the anisotropy of the residual stresses induced by the tensile plastic deformation. It is concluded that the Barkhausen noise activity recording could lead to the determination of the residual stresses in martensite induced by shot peening processes.

  5. Investigation of shot-peened austenitic stainless steel 304L by means of magnetic Barkhausen noise

    Energy Technology Data Exchange (ETDEWEB)

    Kleber, X., E-mail: xavier.kleber@insa-lyon.fr [Universite de Lyon, INSA-Lyon, MATEIS CNRS UMR5510, 7 Avenue Jean Capelle, F-69621 Villeurbanne (France); Barroso, S. Pirfo [Universite de Lyon, INSA-Lyon, MATEIS CNRS UMR5510, 7 Avenue Jean Capelle, F-69621 Villeurbanne (France)

    2010-08-20

    Research highlights: The results and the conclusions drawn in this paper are important for the scientific community and especially for scientist who are looking for method to characterize phase transformations in metallic materials. We show that Barkhausen noise measurements can be successfully used to monitor strain-induced martensite in austenitic stainless steels. - Abstract: Different shot peening conditions were applied to an austenitic stainless steel AISI 304L in order to transform austenite to martensite {alpha}' at different depths. Magnetic Barkhausen noise measurements performed on this steel reveal a correlation between the strength of the signal and the depth of the treatment. The combined effect of the volume fraction of martensite and the residual stress in martensite determined using X-ray diffraction analysis were found to be responsible for the evolution of the Barkhausen noise response. Using tensile plastic deformation, the residual stress in martensite was changed, giving rise to a strong increase of the Barkhausen noise activity. This variation was correlated to a modification of the sign and amplitude of the residual stress in the martensite phase. Directional measurements of the Barkhausen noise revealed the anisotropy of the residual stresses induced by the tensile plastic deformation. It is concluded that the Barkhausen noise activity recording could lead to the determination of the residual stresses in martensite induced by shot peening processes.

  6. Electronic structures and nitride formation on ion-implanted AISI 304L austenitic stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Chang, G.S.; Son, J.H.; Kim, S.H.; Chae, K.H.; Whang, C.N. (Yonsei Univ., Seoul (Korea, Republic of). Dept. of Physics); Menthe, E.; Rie, K.-T.; Lee, Y.P.

    1999-02-01

    A N[sub 2][sup +] implantation technique was employed to improve the surface hardness of stainless steel, and the electronic structures and nitride formation of the ion-implanted layer were investigated and compared with those produced using other techniques, including plasma nitriding. AISI 304L austenite stainless steel was irradiated by 80 keV N[sub 2][sup +] with a dosage ranging from 1.0 x 10[sup 16] to 1.0 x 10[sup 18] ions cm[sup -2] at room temperature. The formation of various nitrides was confirmed by X-ray diffraction. The quantitative hardness of the samples was measured by using a Knoop microhardness tester. X-ray photoelectron spectroscopy was also carried out to elucidate the chemical states and electronic structures of the ion-implanted layers. The measurements were repeated after post-annealing at 400 C for 1 h in a high vacuum. Changes in phase, chemical state and electronic structures were observed according to the ion dose and heat treatment. (orig.) 12 refs.

  7. Microstructure and Mechanical Properties of Plasma Arc Brazed AISI 304L Stainless Steel and Galvanized Steel Plates

    Science.gov (United States)

    Jin, Yajuan; Li, Ruifeng; Yu, Zhishui; Wang, Yu

    2016-04-01

    Plasma arc brazing is used to join the AISI 304L stainless steel and galvanized steel plate butt joints with the CuSi3Mn1 filler wire. The effect of parameters on weld surface appearance, interfacial microstructure, and composition distribution in the joint was studied. The microhardness and mechanical tests were conducted to determine the mechanical properties of the welded specimens. The results indicated that good appearance, bead shape, and sufficient metallurgical bonding could be obtained when the brazing process was performed with a wire feeding speed of 0.8 m/min, plasma gas flow rate of 3.0 l/min, welding current of 100 A, and welding speed of 27 cm/min. During plasma arc brazing process, the top corner of the stainless steel and galvanized steel plate were heated and melted, and the melted quantity of stainless steel was much more than that of the galvanized steel due to the thermal conductivity coefficient difference between the dissimilar materials. The microhardness test results shows that the microhardness value gradually increased from the side of the galvanized steel to the stainless steel in the joint, and it is good for improving the mechanical properties of joint. The tensile strength was a little higher than that of the brazing filler, and the fracture position of weld joint was at the base metal of galvanized steel plate.

  8. Mechanical properties of Austenitic Stainless Steel 304L and 316L at elevated temperatures

    Directory of Open Access Journals (Sweden)

    Raghuram Karthik Desu

    2016-01-01

    Full Text Available Austenitic Stainless Steel grade 304L and 316L are very important alloys used in various high temperature applications, which make it important to study their mechanical properties at elevated temperatures. In this work, the mechanical properties such as ultimate tensile strength (UTS, yield strength (YS, % elongation, strain hardening exponent (n and strength coefficient (K are evaluated based on the experimental data obtained from the uniaxial isothermal tensile tests performed at an interval of 50 °C from 50 °C to 650 °C and at three different strain rates (0.0001, 0.001 and 0.01 s−1. Artificial Neural Networks (ANN are trained to predict these mechanical properties. The trained ANN model gives an excellent correlation coefficient and the error values are also significantly low, which represents a good accuracy of the model. The accuracy of the developed ANN model also conforms to the results of mean paired t-test, F-test and Levene's test.

  9. Propagation of crevices in stainless steel AISI304L in conditions of hydrogen chemistry (HWC)

    International Nuclear Information System (INIS)

    Crevice growth velocities in samples of AISI 304L stainless steel thermally welded and sensitized were obtained by the Rising displacement method or of growing displacement. It was used a recirculation circuit in where the operation conditions of a BWR type reactor were simulated (temperature of 288 C and a pressure of 8 MPa) with the chemistry modified by the addition of hydrogen with and without the addition of impurities of a powerful oxidizer like the Cu++ ion. CT pre cracked specimens were used and each rehearsal stayed to one constant displacement velocity of 1 x 10-9 m/s (3.6 μm/hr), making a continuous pursuit of the advance of the crack by the electric potential drop technique. To the end of the rehearsal it was carried out the fractographic analysis of the propagation surfaces. The values of the growth velocities obtained by this methodology went similar to the opposing ones under normal conditions of operation; while the fractographic analysis show the cracks propagation in trans and intergranular ways, evidencing the complexity of the regulator mechanisms of the one IGSCC even under controlled ambient conditions or with mitigation methodologies like the alternative hydrogen chemistry. (Author)

  10. Effect of thermal cycles on heavily cold deformed AISI 304L austenitic stainless steel

    International Nuclear Information System (INIS)

    The solution treated commercial grade AISI 304L austenitic stainless steel plate was heavily cold rolled to 90% of thickness reduction. Cold rolled specimens were annealed at various temperatures by thermal cycles and isothermal annealing. Strain-induced phase transformations and microstructure studies were carried out both in the cold rolled and annealed conditions. The X-ray diffraction and magnetic measurements were used for phase transformation studies. The transmission electron microscope characterisation revealed that the cyclic thermal process resulted in ultrafine grain austenite formation whereas, the isothermal annealing developed coarser grain size microstructure. The different microstructural evolutions by the above two processes largely influenced the development of the recrystallisation texture. The thermal cycling produced a distinct γ-fibre texture while the isothermal annealing resulted in a cube texture component along with the γ-fibre. The γ-fibre texture evolution was attributed to the over critical subgrains or nuclei and {1 0 0} cube texture to the coarser grains of micrometer size.

  11. Development of Nanocrystalline 304L Stainless Steel by Large Strain Cold Working

    Directory of Open Access Journals (Sweden)

    Marina Odnobokova

    2015-04-01

    Full Text Available The microstructural changes leading to nanocrystalline structure development and the respective tensile properties were studied in a 304L stainless steel subjected to large strain cold rolling at ambient temperature. The cold rolling was accompanied by the development of deformation twinning and martensitic transformation. The latter readily occurred at deformation microshear bands, leading the martensite fraction to approach 0.75 at a total strain of 3. The deformation twinning followed by microshear banding and martensitic transformation promoted the development of nanocrystalline structure consisting of a uniform mixture of austenite and martensite grains with their transverse sizes of 120–150 nm. The developed nanocrystallites were characterized by high dislocation density in their interiors of about 3 × 1015 m−2 and 2 × 1015 m−2 in austenite and martensite, respectively. The development of nanocrystalline structures with high internal stresses led to significant strengthening. The yield strength increased from 220 MPa in the original hot forged state to 1600 MPa after cold rolling to a strain of 3.

  12. Martensitic Transformation in Ultrafine-Grained Stainless Steel AISI 304L Under Monotonic and Cyclic Loading

    Directory of Open Access Journals (Sweden)

    Heinz Werner Höppel

    2012-02-01

    Full Text Available The monotonic and cyclic deformation behavior of ultrafine-grained metastable austenitic steel AISI 304L, produced by severe plastic deformation, was investigated. Under monotonic loading, the martensitic phase transformation in the ultrafine-grained state is strongly favored. Under cyclic loading, the martensitic transformation behavior is similar to the coarse-grained condition, but the cyclic stress response is three times larger for the ultrafine-grained condition.

  13. Irradiation creep of SA 304L and CW 316 stainless steels: Mechanical behaviour and microstructural aspects. Part I: Experimental results

    Science.gov (United States)

    Garnier, J.; Bréchet, Y.; Delnondedieu, M.; Pokor, C.; Dubuisson, P.; Renault, A.; Averty, X.; Massoud, J. P.

    2011-06-01

    Solution annealed 304L (SA 304L) and cold work 316 (CW 316) austenitic stainless steel irradiation creep behaviour have been studied thoroughly. Irradiations were carried out in fast breeder reactors BOR-60 (at 330 °C, up to 120 dpa) and EBR-II (at 375 °C, up to 10.5 dpa), and in the OSIRIS mixed spectrum reactor (at 330 °C, up to 9.8 dpa). After an incubation threshold, the irradiation creep of the austenitic stainless steels is linear in stress and in dose. Creep appears to be athermal in this temperature range. A significant difference in the behaviour is measured between the creep of SA 304L and CW 316. In order to study the anisotropy of loop population, which would be the signature of a possible stress induced preferential absorption (SIPA) mechanism for irradiation creep, special attention was given to the measurement of anisotropy of loop distribution between the four families. The anisotropy induced by an applied stress has been shown to be in the range of the statistical scatter in the situation where no stress is applied. TEM microstructural analyses performed on this sample show slight difference between the microstructure of specimens deformed under irradiation and the microstructure of specimens irradiated without stress under the same irradiation conditions.

  14. XPS Analysis of AISI 304L Stainless Steel Surface after Electropolishing

    Directory of Open Access Journals (Sweden)

    Rokosz K.

    2015-03-01

    Full Text Available In the paper, the passive surface layers of AISI 304L after standard (EP50 and very-high-current density electropolishing (EP1000 in a mixture of orthophosphoric and sulfuric acids in a 1:4 ratio, are presented. The main finding of the presented studies is enrichment of the steel surface film in chromium: total chromium to total iron ratio was equal to 6.6 after EP50 and to 2.8 after EP1000; on the other hand, chromium compounds to iron compounds ratio was equal to 10.1 after EP50, and 3.9 after EP1000.

  15. The effect of electrode vertex angle on automatic tungsten-inert-gas welds for stainless steel 304L plates

    International Nuclear Information System (INIS)

    The effect of electrode vertex angle on penetration depth and weld bead width, in automatic tungsten-inert-gas (TIG) dcsp bead-on-plate welding with different currents, has been studied for stainless steel 304L plates 1.5 mm and 8 mm thick. It has been found that for thin plates, wider and deeper welds are obtained when using sharper electrodes while, for thick plates, narrower and deeper welds are produced when blunt electrodes (vertex angle 180 deg) are used. An explanation of the results, based on a literature survey, is included

  16. Corrosion of high Ni-Cr alloys and Type 304L stainless steel in HNO3-HF

    International Nuclear Information System (INIS)

    Nineteen alloys were evaluated as possible materials of construction for steam heating coils, the dissolver vessel, and the off-gas system of proposed facilities to process thorium and uranium fuels. Commercially available alloys were found that are satisfactory for all applications. With thorium fuel, which requires HNO3-HF for dissolution, the best alloy for service at 1300C when complexing agents for fluoride are used is Inconel 690; with no complexing agents at 1300C, Inconel 671 is best. At 950C, six other alloys tested would be adequate: Haynes 25, Ferralium, Inconel 625, Type 304L stainless steel, Incoloy 825, and Haynes 20 (in order of decreasing preference); based on composition, six untested alloys would also be adequate. The ions most effective in reducing fluoride corrosion were the complexing agents Zr4+ and Th4+; Al3+ was less effective. With uranium fuel, modestly priced Type 304L stainless steel is adequate. Corrosion will be most severe in HNO3-HF used occasionally for flushing and in solutions of HNO3 and corrosion products (ferric and dichromate ions). HF corrosion can be minimized by complexing the fluoride ion and by passivation of the steel with strong nitric acid. Corrosion caused by corrosion products can be minimized by operating at lower temperatures

  17. Effects of hydrogen water chemistry on corrosion fatigue behavior of cold-worked 304L stainless steel in simulated BWR coolant environments

    Energy Technology Data Exchange (ETDEWEB)

    Chiang, M.F., E-mail: mfchiang@iner.gov.tw [Institute of Nuclear Energy Research, Division of Nuclear Fuels and Materials, Lungtan, Taoyuan 325, Taiwan (China); Young, M.C.; Huang, J.Y. [Institute of Nuclear Energy Research, Division of Nuclear Fuels and Materials, Lungtan, Taoyuan 325, Taiwan (China)

    2011-04-15

    Corrosion fatigue behavior of stainless steel 304L (SS304L) in a simulated BWR coolant with hydrogen injection was investigated. Hydrogen water chemistry slightly mitigated the corrosion fatigue degradation of the as-received SS304L specimens, but, on the contrary, it slightly increased the corrosion fatigue crack growth rates (CFCGRs) of the cold-worked specimens. All the CFCGR-tested specimens showed similar fracture features, except for the amounts of deposited corrosion debris. The results indicated that decreasing the oxygen concentration of water environment is not an effective measure to suppress the fatigue crack growth rate of cold-worked SS304L. The CFCGRs of the SS304L were determined by an interaction between corrosion, oxide-induced crack closure and cold work in corrosive environments. At a specific level of reduction, cold work could enhance the corrosion fatigue resistance of SS304 both in the air-saturated and HWC coolant environments.

  18. Effects of hydrogen water chemistry on corrosion fatigue behavior of cold-worked 304L stainless steel in simulated BWR coolant environments

    Science.gov (United States)

    Chiang, M. F.; Young, M. C.; Huang, J. Y.

    2011-04-01

    Corrosion fatigue behavior of stainless steel 304L (SS304L) in a simulated BWR coolant with hydrogen injection was investigated. Hydrogen water chemistry slightly mitigated the corrosion fatigue degradation of the as-received SS304L specimens, but, on the contrary, it slightly increased the corrosion fatigue crack growth rates (CFCGRs) of the cold-worked specimens. All the CFCGR-tested specimens showed similar fracture features, except for the amounts of deposited corrosion debris. The results indicated that decreasing the oxygen concentration of water environment is not an effective measure to suppress the fatigue crack growth rate of cold-worked SS304L. The CFCGRs of the SS304L were determined by an interaction between corrosion, oxide-induced crack closure and cold work in corrosive environments. At a specific level of reduction, cold work could enhance the corrosion fatigue resistance of SS304 both in the air-saturated and HWC coolant environments.

  19. The role of martensitic transformation on bimodal grain structure in ultrafine grained AISI 304L stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Sabooni, S., E-mail: s.sabooni@ma.iut.ac.ir [Department of Materials Engineering, Isfahan University of Technology, 84156-83111 Isfahan (Iran, Islamic Republic of); Karimzadeh, F.; Enayati, M.H. [Department of Materials Engineering, Isfahan University of Technology, 84156-83111 Isfahan (Iran, Islamic Republic of); Ngan, A.H.W. [Department of Mechanical Engineering, The University of Hong Kong, Pokfulam Road, Hong Kong (China)

    2015-06-11

    In the present study, metastable AISI 304L austenitic stainless steel samples were subjected to different cold rolling reductions from 70% to 93%, followed by annealing at 700 °C for 300 min to form ultrafine grained (UFG) austenite with different grain structures. Transmission electron microscopy (TEM) and nanoindentation were used to characterize the martensitic transformation, in order to relate it to the bimodal distribution of the austenite grain size after subsequent annealing. The results showed that the martensite morphology changed from lath type in the 60% rolled sample to a mixture of lath and dislocation-cell types in the higher rolling reductions. Calculation of the Gibbs free energy change during the reversion treatment showed that the reversion mechanism is shear controlled at the annealing temperature and so the morphology of the reverted austenite is completely dependent on the morphology of the deformation induced martensite. It was found that the austenite had a bimodal grain size distribution in the 80% rolled and annealed state and this is related to the existence of different types of martensite. Increasing the rolling reduction to 93% followed by annealing caused changing of the grain structure to a monomodal like structure, which was mostly covered with small grains of around 300 nm. The existence of bimodal austenite grain size in the 80% rolled and annealed 304L stainless steel led to the improvement of ductility while maintaining a high tensile strength in comparison with the 93% rolled and annealed sample.

  20. Cladding of aluminum on AISI 304L stainless steel by cold roll bonding: Mechanism, microstructure, and mechanical properties

    Energy Technology Data Exchange (ETDEWEB)

    Akramifard, H.R., E-mail: akrami.1367@ut.ac.ir [School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, P.O. Box 11155-4563, Tehran (Iran, Islamic Republic of); Mirzadeh, H., E-mail: hmirzadeh@ut.ac.ir [School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, P.O. Box 11155-4563, Tehran (Iran, Islamic Republic of); Advanced Metalforming and Thermomechanical Processing Laboratory, School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); Parsa, M.H., E-mail: mhparsa@ut.ac.ir [School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, P.O. Box 11155-4563, Tehran (Iran, Islamic Republic of); Center of Excellence for High Performance Materials, School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); Advanced Metalforming and Thermomechanical Processing Laboratory, School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of)

    2014-09-08

    The AA1050 aluminum alloy and AISI 304L stainless steel sheets were stacked together to fabricate Al/304L/Al clad sheet composites by the cold roll bonding process, which was performed at temperatures of ∼100 and 23 °C to produce austenitic and austenitic–martensitic microstructures in the AISI 304L counterpart, respectively. The peel test results showed that the threshold reduction required to make a suitable bond at room temperature is below 10%, which is significantly lower than the required reduction for cold roll bonding of Al sheets. The tearing of the Al sheet during the peel test signified that the bond strength of the roll bonded sheets by only 38% reduction has reached the strength of Al, which is a key advantage of the developed sheets. The extrusion of Al through the surface cracks and settling inside the 304L surface valleys due to strong affinity between Al and Fe was found to be the bonding mechanism. Subsequently, the interface and tensile behaviors of three-layered clad sheets after soaking at 200–600 °C for 1 h were investigated to characterize the effect of annealing treatment on the formation and thickening of intermetallic compound layer and the resultant mechanical properties. Field emission scanning electron microscopy, X-ray diffraction, and optical microscopy techniques revealed that an intermediate layer composed mainly of Al{sub 13}Fe{sub 4}, FeC and Al{sub 8}SiC{sub 7} forms during annealing at 500–600 °C. A significant drop in tensile stress–strain curves after the maximum point (UTS) was correlated to the interface debonding. It was found that the formation of intermediate layer by post heat treatment deteriorates the bond quality and encourages the debonding process. Moreover, the existence of strain-induced martensite in clad sheets was found to play a key role in the enhancement of tensile strength.

  1. Effect of sensitization on the mechanical properties of type 304 L stainless steel

    International Nuclear Information System (INIS)

    The sensitization is a corrosion cause that it has studied broadly in the austenitic steels; however its relations don't knowed very well, into the sensitization and the steel's mechanical properties. Wherefore, the objectives of this work was to study the mechanical properties, in tension of austenitic steel with different levels of sensitization. The material utilized was a 304 L steel of standard composition AISI. The samples were sensitized at 450, 650 and 850 Centigrade degree, by short expositions, following by a temper in water. After this treatment, the tension test tubes were carried to rupture at low deformation velocity. The sensitization was evaluated by the method of Akashi EPR cyclic polarization. The sensitization distribution was analyzed by optical metallography in color and the fracture surface were studied by sweeping electronic microscopy. The distribution and length of the carbides were the factor that control the mechanic behavior of materials. At 450 Centigrade, the border of the grain its founded free of carbides, also for the longest times of exposition, but the particles are presented as fine precipitates in the grain interior, with this is increased the mechanical properties by the internal interactions of hardness or oldness types. At 650 Centigrade the frontiers show a dense distribution of fine carbides. These precipitates are interacting with the borders grain, increasing lightly the mechanical properties of steel. At 850 Centigrade, were formed discontinued carbides that not affect the mechanical behavior, but whether the fracture; the resistance is reduced and the ductility is increased although to impose the thermic effect of treatment. (Author)

  2. Nanosecond laser surface modification of AISI 304L stainless steel: Influence the beam overlap on pitting corrosion resistance

    Energy Technology Data Exchange (ETDEWEB)

    Pacquentin, Wilfried, E-mail: wilfried.pacquentin@cea.fr [CEA, DEN/DANS/DPC/SEARS/LISL, F-91191 Gif-sur-Yvette (France); Caron, Nadège [CEA, DEN/DANS/DPC/SEARS/LISL, F-91191 Gif-sur-Yvette (France); Oltra, Roland [Laboratoire Interdisciplinaire Carnot de Bourgogne, Université de Bourgogne, UMR CNRS 5209, 21078 Dijon Cedex (France)

    2014-01-01

    Surface modifications of AISI 304L stainless steel by laser surface melting (LSM) were investigated using a nanosecond pulsed laser-fibre doped by ytterbium at different overlaps. The objective was to study the change in the corrosion properties induced by the treatment of the outer-surface of the stainless steel without modification of the bulk material. Different analytical techniques such as scanning electron microscopy (SEM), X-ray diffraction (XRD), and glow discharge optical emission spectrometry (GDOES) were used to characterize the laser-melted surface. The corrosion resistance was evaluated in a chloride solution at room temperature by electrochemical tests. The results showed that the crystallographic structure, the chemical composition, the properties of the induced oxide layer and consequently the pitting corrosion resistance strongly depend on the overlap rate. The most efficient laser parameters led to an increase of the pitting potential by more than 300 mV, corresponding to a quite important improvement of the corrosion resistance. This latter was correlated to chromium enrichment (47 wt.%) at the surface of the stainless steel and the induced absence of martensite and ferrite phases. However, these structural and chemical modifications were not sufficient to explain the change in corrosion behaviour: defects and adhesion of the surface oxide layer must have been taken into consideration.

  3. Effects of Low Temperature on Hydrogen-Assisted Crack Growth in Forged 304L Austenitic Stainless Steel

    Science.gov (United States)

    Jackson, Heather; San Marchi, Chris; Balch, Dorian; Somerday, Brian; Michael, Joseph

    2016-08-01

    The objective of this study was to evaluate effects of low temperature on hydrogen-assisted crack propagation in forged 304L austenitic stainless steel. Fracture initiation toughness and crack-growth resistance curves were measured using fracture mechanics specimens that were thermally precharged with 140 wppm hydrogen and tested at 293 K or 223 K (20 °C or -50 °C). Fracture initiation toughness for hydrogen-precharged forgings decreased by at least 50 to 80 pct relative to non-charged forgings. With hydrogen, low-temperature fracture initiation toughness decreased by 35 to 50 pct relative to room-temperature toughness. Crack growth without hydrogen at both temperatures was microstructure-independent and indistinguishable from blunting, while with hydrogen microcracks formed by growth and coalescence of microvoids. Initiation of microvoids in the presence of hydrogen occurred where localized deformation bands intersected grain boundaries and other deformation bands. Low temperature additionally promoted fracture initiation at annealing twin boundaries in the presence of hydrogen, which competed with deformation band intersections and grain boundaries as sites of microvoid formation and fracture initiation. A common ingredient for fracture initiation was stress concentration that arose from the intersection of deformation bands with these microstructural obstacles. The localized deformation responsible for producing stress concentrations at obstacles was intensified by low temperature and hydrogen. Crack orientation and forging strength were found to have a minor effect on fracture initiation toughness of hydrogen-supersaturated 304L forgings.

  4. Effect of welding process, type of electrode and electrode core diameter on the tensile property of 304L austenitic stainless steel

    Directory of Open Access Journals (Sweden)

    Akinlabi OYETUNJI

    2014-11-01

    Full Text Available The effect of welding process, type of electrode and electrode core diameter on the tensile property of AISI 304L Austenitic Stainless Steel (ASS was studied. The tensile strength property of ASS welded samples was evaluated. Prepared samples of the ASS were welded under these three various variables. Tensile test was then carried out on the welded samples. It was found that the reduction in ultimate tensile strength (UTS of the butt joint samples increases with increase in core diameter of the electrode. Also, the best electrode for welding 304L ASS is 308L stainless steel-core electrode of 3.2 mm core diameter. It is recommended that the findings of this work can be applied in the chemical, food and oil industries where 304L ASS are predominantly used.

  5. Reactor Materials Program: Mechanical properties of irradiated Types 304 and 304L stainless steel weldment components

    International Nuclear Information System (INIS)

    The vessels (reactor tanks) of the Savannah River Site nuclear production reactors constructed in the 1950's are comprised of Type 304 stainless steel with Type 308 stainless steel weld filler. Irradiation exposure to the reactor tank sidewalls through reactor operation has caused a change in the mechanical properties of these materials. A database of as-irradiated mechanical properties for site-specific materials and irradiation conditions has been produced for reactor tank structural analyses and to quantify the effects of radiation-induced materials degradation for evaluating reactor service life. The data has been collected from the SRL Reactor Materials Program (RMP) irradiations and testing of archival stainless steel weldment components and from previous SRL programs to measure properties of irradiated reactor Thermal Shield weldments and reactor tank (R-tank) sidewall material. Irradiation programs of the RMP are designed to quantify mechanical properties at tank operating temperatures following irradiation to present and future tank wall maximum exposure conditions. The exposure conditions are characterized in terms of fast neutron fluence (En > 0.1 MeV) and displacements per atom (dpa)3. Tensile properties, Charpy-V notch toughness, and elastic-plastic fracture toughness were measured for base, weld, and weld heat-affected zone (HAZ) weldment components from archival piping specimens following a Screening Irradiation in the University of Buffalo Reactor (UBR) and following a Full-Term Irradiation in the High Flux Isotope Reactor (HFIR)

  6. Reactor Materials Program: Mechanical properties of irradiated Types 304 and 304L stainless steel weldment components

    Energy Technology Data Exchange (ETDEWEB)

    Sindelar, R.L.; Caskey, G.R. Jr.

    1991-12-01

    The vessels (reactor tanks) of the Savannah River Site nuclear production reactors constructed in the 1950's are comprised of Type 304 stainless steel with Type 308 stainless steel weld filler. Irradiation exposure to the reactor tank sidewalls through reactor operation has caused a change in the mechanical properties of these materials. A database of as-irradiated mechanical properties for site-specific materials and irradiation conditions has been produced for reactor tank structural analyses and to quantify the effects of radiation-induced materials degradation for evaluating reactor service life. The data has been collected from the SRL Reactor Materials Program (RMP) irradiations and testing of archival stainless steel weldment components and from previous SRL programs to measure properties of irradiated reactor Thermal Shield weldments and reactor tank (R-tank) sidewall material. Irradiation programs of the RMP are designed to quantify mechanical properties at tank operating temperatures following irradiation to present and future tank wall maximum exposure conditions. The exposure conditions are characterized in terms of fast neutron fluence (E{sub n} > 0.1 MeV) and displacements per atom (dpa){sup 3}. Tensile properties, Charpy-V notch toughness, and elastic-plastic fracture toughness were measured for base, weld, and weld heat-affected zone (HAZ) weldment components from archival piping specimens following a Screening Irradiation in the University of Buffalo Reactor (UBR) and following a Full-Term Irradiation in the High Flux Isotope Reactor (HFIR).

  7. Reactor Materials Program: Mechanical properties of irradiated Types 304 and 304L stainless steel weldment components

    Energy Technology Data Exchange (ETDEWEB)

    Sindelar, R.L.; Caskey, G.R. Jr.

    1991-12-01

    The vessels (reactor tanks) of the Savannah River Site nuclear production reactors constructed in the 1950`s are comprised of Type 304 stainless steel with Type 308 stainless steel weld filler. Irradiation exposure to the reactor tank sidewalls through reactor operation has caused a change in the mechanical properties of these materials. A database of as-irradiated mechanical properties for site-specific materials and irradiation conditions has been produced for reactor tank structural analyses and to quantify the effects of radiation-induced materials degradation for evaluating reactor service life. The data has been collected from the SRL Reactor Materials Program (RMP) irradiations and testing of archival stainless steel weldment components and from previous SRL programs to measure properties of irradiated reactor Thermal Shield weldments and reactor tank (R-tank) sidewall material. Irradiation programs of the RMP are designed to quantify mechanical properties at tank operating temperatures following irradiation to present and future tank wall maximum exposure conditions. The exposure conditions are characterized in terms of fast neutron fluence (E{sub n} > 0.1 MeV) and displacements per atom (dpa){sup 3}. Tensile properties, Charpy-V notch toughness, and elastic-plastic fracture toughness were measured for base, weld, and weld heat-affected zone (HAZ) weldment components from archival piping specimens following a Screening Irradiation in the University of Buffalo Reactor (UBR) and following a Full-Term Irradiation in the High Flux Isotope Reactor (HFIR).

  8. Standard test method for electrochemical reactivation (EPR) for detecting sensitization of AISI type 304 and 304L stainless steels

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    1994-01-01

    1.1 This test method covers a laboratory procedure for conducting an electrochemical reactivation (EPR) test on AISI Type 304 and 304L (UNS No. S30400 and S30403, respectively) stainless steels. This test method can provide a nondestructive means of quantifying the degree of sensitization in these steels (1, 2, 3). This test method has found wide acceptance in studies of the effects of sensitization on intergranular corrosion and intergranular stress corrosion cracking behavior (see Terminology G15). The EPR technique has been successfully used to evaluate other stainless steels and nickel base alloys (4), but the test conditions and evaluation criteria used were modified in each case from those cited in this test method. 1.2 The values stated in SI units are to be regarded as the standard. The inch-pound units given in parentheses are for information only. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this...

  9. Microelectrochemical investigation of the effect of cathodic polarisation on the corrosion resistance of 304L stainless steel in a 1 M NaCl solution

    OpenAIRE

    Arjmand Gholenji, Farzin; Adriaens, Annemie

    2012-01-01

    304L stainless steel was cathodically polarised in a 1 M sodium chloride solution using a microcapillary electrochemical droplet cell. During the cathodic polarisation the produced hydrogen atoms penetrate into the sample and accumulate at sites of the steel surface. We observed that the pitting potential (E-pit), the anodic current density (I-corr) and the corrosion potential (E-corr) of the polarised steel are strongly influenced by the applied cathodic potential and therefore by the amount...

  10. Martensite phase reversion-induced nano/ ultrafine grained AISI 304L stainless steel with magnificent mechanical properties

    Directory of Open Access Journals (Sweden)

    Mohammad Shirdel

    2015-06-01

    Full Text Available Austenitic stainless steels are extensively used in various applications requiring good corrosion resistance and formability. In the current study, the formation of nano/ ultrafine grained austenitic microstructure in a microalloyed AISI 304L stainless steel was investigated by the advanced thermomechanical process of reversion of strain-induced martensite. For this purpose, samples were subjected to heavy cold rolling to produce a nearly complete martensitic structure. Subsequently, a wide range of annealing temperatures (600 to 800°C and times (1 to 240 min were employed to assess the reversion behavior and to find the best annealing condition for the production of the nano/ultrafine grained austenitic microstructure. Microstructural characterizations have been performed using X-ray diffraction (XRD, scanning electron microscopy (SEM, and magnetic measurement, whereas the mechanical properties were assessed by tensile and hardness tests. After thermomechanical treatment, a very fine austenitic structure was obtained, which was composed of nano sized grains of ~ 85 nm in an ultrafine grained matrix with an average grain size of 480 nm. This microstructure exhibited superior mechanical properties: high tensile strength of about 1280 MPa with a desirable elongation of about 41%, which can pave the way for the application of these sheets in the automotive industry.

  11. On the dynamic strength of 304l stainless steel under impact

    Science.gov (United States)

    Werdiger, Meir; Glam, Benny; Bakshi, Lior; Moshe, Ella; Horovitz, Yossef; Pistinner, Shlomi Levi

    2012-03-01

    Uniaxial strain plane impact (300-1700 m/s), loading and reloading experiments carried out on SS304L are reported. The aim of these experiments was to measure the material strength properties under shock compression. Most of the experiments reported here show a viscous type elastic precursor. The experimental results are compared to numerical simulations performed using a 1D code. The input physics to the simulations are the Steinberg equation of state and Johnson-Cook strength model. This model has been previously calibrated under uniaxial stress conditions in the rangee ɛ =1-5×103 s-1. Our experiments extended the data into the regione ɛ =105 -106 s-1. In spite of this extrapolation, there is a general agreement between simulations and experiments. However, differences in some details still exist.

  12. Evaluation of stress corrosion cracking of irradiated 304L stainless steel in PWR environment using heavy ion irradiation

    Science.gov (United States)

    Gupta, J.; Hure, J.; Tanguy, B.; Laffont, L.; Lafont, M.-C.; Andrieu, E.

    2016-08-01

    IASCC has been a major concern regarding the structural and functional integrity of core internals of PWR's, especially baffle-to-former bolts. Despite numerous studies over the past few decades, additional evaluation of the parameters influencing IASCC is still needed for an accurate understanding and modeling of this phenomenon. In this study, Fe irradiation at 450 °C was used to study the cracking susceptibility of 304 L austenitic stainless steel. After 10 MeV Fe irradiation to 5 dpa, irradiation-induced damage in the microstructure was characterized and quantified along with nano-hardness measurements. After 4% plastic strain in a PWR environment, quantitative information on the degree of strain localization, as determined by slip-line spacing, was obtained using SEM. Fe-irradiated material strained to 4% in a PWR environment exhibited crack initiation sites that were similar to those that occur in neutron- and proton-irradiated materials, which suggests that Fe irradiation may be a representative means for studying IASCC susceptibility. Fe-irradiated material subjected to 4% plastic strain in an inert argon environment did not exhibit any cracking, which suggests that localized deformation is not in itself sufficient for initiating cracking for the irradiation conditions used in this study.

  13. Effect of low temperature on hydrogen-assisted crack propagation in 304L/308L austenitic stainless steel fusion welds

    International Nuclear Information System (INIS)

    Highlights: •Measured crack growth resistance of welds at 223 K with 140 wppm H (gas charged). •H reduced fracture initiation toughness by >59% and altered fracture mode. •223 K altered fracture mode but had no effect on JIC of precharged welds. •At 293 K, microcracks initiate at δ-ferrite, and ferrite governed crack path. •At 223 K, microvoids form at γ deformation band intersections near phase boundaries. -- Abstract: Effects of low temperature on hydrogen-assisted cracking in 304L/308L austenitic stainless steel welds were investigated using elastic–plastic fracture mechanics methods. Thermally precharged hydrogen (140 wppm) decreased fracture toughness and altered fracture mechanisms at 293 and 223 K relative to hydrogen-free welds. At 293 K, hydrogen increased planar deformation in austenite, and microcracking of δ-ferrite governed crack paths. At 223 K, low temperature enabled hydrogen to exacerbate localized deformation, and microvoid formation, at austenite deformation band intersections near phase boundaries, dominated damage initiation; microcracking of ferrite did not contribute to crack growth

  14. Effect of strain-path on stress corrosion cracking of AISI 304L stainless steel in PWR primary environment at 360 deg. C

    Energy Technology Data Exchange (ETDEWEB)

    Couvant, T.; Vaillant, F.; Boursier, JM. [EDF R and D - MMC, Route de Sens, 77818 Moret-sur-Loing (France); Delafosse, D. [Ecole des Mines de St-Etienne, 157 Cours Fauriel, 42023 St-Etienne cedex 2 (France)

    2004-07-01

    Austenitic stainless steels (ASS) are widespread in primary and auxiliary circuits of PWR. Moreover, some components suffer stress corrosion cracking (SCC) under neutron irradiation. This degradation could be the result of the increase of hardness or the modification of chemical composition at the grain boundary by irradiation. In order to avoid complex and costly corrosion facilities, the effects of irradiation on the material are commonly simulated by applying a cold work on non-irradiated material prior to stress corrosion cracking tests. Slow strain rate tests were conducted on an austenitic stainless steel (SS) AISI 304L in PWR environment (360 deg. C). Particular attention was directed towards pre-straining effects on crack growth rate (CGR) and crack growth path (CGP). Results have demonstrated that the susceptibility of 304L to SCC in high-temperature hydrogenated water was enhanced by pre-straining. It seemed that IGSCC was enhanced by complex strain paths. (authors)

  15. Numerical Simulation and Artificial Neural Network Modeling for Predicting Welding-Induced Distortion in Butt-Welded 304L Stainless Steel Plates

    Science.gov (United States)

    Narayanareddy, V. V.; Chandrasekhar, N.; Vasudevan, M.; Muthukumaran, S.; Vasantharaja, P.

    2016-02-01

    In the present study, artificial neural network modeling has been employed for predicting welding-induced angular distortions in autogenous butt-welded 304L stainless steel plates. The input data for the neural network have been obtained from a series of three-dimensional finite element simulations of TIG welding for a wide range of plate dimensions. Thermo-elasto-plastic analysis was carried out for 304L stainless steel plates during autogenous TIG welding employing double ellipsoidal heat source. The simulated thermal cycles were validated by measuring thermal cycles using thermocouples at predetermined positions, and the simulated distortion values were validated by measuring distortion using vertical height gauge for three cases. There was a good agreement between the model predictions and the measured values. Then, a multilayer feed-forward back propagation neural network has been developed using the numerically simulated data. Artificial neural network model developed in the present study predicted the angular distortion accurately.

  16. Effect of welding process, type of electrode and electrode core diameter on the tensile property of 304L austenitic stainless steel

    OpenAIRE

    Akinlabi OYETUNJI; Nwafagu NWIGBOJI

    2014-01-01

    The effect of welding process, type of electrode and electrode core diameter on the tensile property of AISI 304L Austenitic Stainless Steel (ASS) was studied. The tensile strength property of ASS welded samples was evaluated. Prepared samples of the ASS were welded under these three various variables. Tensile test was then carried out on the welded samples. It was found that the reduction in ultimate tensile strength (UTS) of the butt joint samples increases with increase in core diameter of...

  17. Investigation of micro-structure and micro-hardness properties of 304L stainless steel treated in a hot cathode arc discharge plasma

    International Nuclear Information System (INIS)

    We have established a hot cathode arc discharge plasma system, where different stainless steel samples can be treated by monitoring the plasma parameters and nitriding parameters independently. In the present work, a mixture of 70% N2 and 30% H2 gases was fed into the plasma chamber and the treatment time and substrate temperature were optimized for treating 304L Stainless Steel samples. Various physical techniques such as x-ray diffraction, energy dispersive x-ray spectroscopy and micro-vickers hardness tester were employed to determine the structural, surface composition and surface hardness of the treated samples

  18. Investigation of micro-structure and micro-hardness properties of 304L stainless steel treated in a hot cathode arc discharge plasma

    Energy Technology Data Exchange (ETDEWEB)

    Malik, Hitendra K., E-mail: hkmalik@physics.iitd.ac.in [Department of Physics, Indian Institute of Technology Delhi, New Delhi – 110016 (India); Singh, Omveer [Centre for Energy Studies, Indian Institute of Technology Delhi, New Delhi – 110016 (India); Dahiya, Raj P. [Centre for Energy Studies, Indian Institute of Technology Delhi, New Delhi – 110016 (India); Deenbandhu Chhotu Ram University of Science and Technology, Murthal–131039 (India)

    2015-08-28

    We have established a hot cathode arc discharge plasma system, where different stainless steel samples can be treated by monitoring the plasma parameters and nitriding parameters independently. In the present work, a mixture of 70% N{sub 2} and 30% H{sub 2} gases was fed into the plasma chamber and the treatment time and substrate temperature were optimized for treating 304L Stainless Steel samples. Various physical techniques such as x-ray diffraction, energy dispersive x-ray spectroscopy and micro-vickers hardness tester were employed to determine the structural, surface composition and surface hardness of the treated samples.

  19. The role of atomic hydrogen and hydrogen-induced martensites in hydrogen embrittlement of type 304L stainless steel

    Institute of Scientific and Technical Information of China (English)

    潘川; 褚武扬; 李正邦; 梁东图; 宿彦京; 乔利杰

    2002-01-01

    The role of atomic hydrogen and hydrogen-induced martensites in hydrogen embrittlement in slow strain rate tensile tests and hydrogen-induced delayed cracking (HIC) in sustained load tests for type 304 L stainless steel was quantitatively studied.The results indicated that hydrogen-induced martensites formed when hydrogen concentration C0 exceeded 30 ppm,and increased with an increase in C0,i.e.M(vol%)=62-82.5exp(-C0/102).The relative plasticity loss caused by the martensites increased linearly with increasing amount of the martensites,i.e.Iδ(M),%=0.45M(vol %)=27.9-37.1 exp(-C0/102).The plasticity loss caused by atomic hydrogen Iδ(H) increased with an increase in C0 and reached a saturation value Iδ(H)max=40% when C0>100 ppm.Iδ(H) decreased with an increase in strain rate ,i.e.Iδ(H),%=-21.9-9.9,and was zero when ≥c=0.032/s.HIC under sustained load was due to atomic hydrogen,and the threshold stress intensity for HIC decreased linearly with lnC0,i.e.KIH(Mpam1/2)=91.7-10.1 lnC0(ppm).The fracture surface of HIC was dimple if KI was high or/and C0 was low,otherwise it was quasi-cleavage.The boundary line between ductile and brittle fracture surface was KI-54+25exp(-C0/153)=0.``

  20. Environmental effect on cracking of an 304L austenitic stainless steels in PWR primary environment under cyclic loading

    International Nuclear Information System (INIS)

    The present study was undertaken in order to get further insights on cracking mechanisms in a 304L stainless steel. More precisely, a first objective of this study was to evaluate the effect of various cold working conditions on the cyclic stress-strain behavior and the fatigue life in air and in PWR primary environment. In air a prior hardening was found to reduce the fatigue life in the LCF regime but not in primary environment. In both environments, the fatigue limit of the hardened materials was increased after cold working.The second objective addresses the effect of the air and the PWR primary environments on the cracking mechanisms (initiation and propagation) in the annealed material in the LCF regime. More precisely, the kinetics of crack initiation and micro crack propagation were evaluated with a multi scale microscopic approach in air and in primary environment. In PWR primary environment, during the first cycles, preferential oxidation occurs along emerging dissociated dislocation and each cycle generates a new C-rich/Fe-rich oxide layer. Then, during cycling, the microstructure evolves from stacking fault into micro twinning and preferential oxidation occurs by continuous shearing and dissolution of the passive film. Beyond a certain crack depth (≤3 μm), the crack starts to propagate with a direction close to a 90 degrees angle from the surface. The crack continues its propagation by successive generation of shear bands and fatigue striations at each cycle up to failure. The role of corrosion hydrogen on these processes is finally discussed. (author)

  1. Comparative study in the induced corrosion by sulfate reducing microorganisms, in a stainless steel 304L sensitized and a carbon steel API X65

    International Nuclear Information System (INIS)

    In spite of the operational experience related with the presence of the phenomenon of microbiological corrosion (MIC) in industrial components, it was not but until the decade of the 80 s when the nuclear industry recognized its influence in some systems of Nuclear Generating Power plants. At the moment, diverse studies that have tried to explain the generation mechanism of this phenomenon exist; however, they are even important queries that to solve, especially those related with the particularities of the affected metallic substrates. Presently work, the electrochemical behavior of samples of stainless steel AISI 304L sensitized is evaluated and the carbon steel APIX65, before the action of sulfate reducing microorganisms low the same experimental conditions; found that for the APIX65 the presence of this type of bacteria promoted the formation of a stable biofilm that allowed the maintenance of the microorganisms that damaged the material in isolated places where stings were generated; while in the AISI 304L, it was not detected damage associated to the inoculated media. The techniques of Resistance to the Polarization and Tafel Extrapolation, allowed the calculation of the speed of uniform corrosion, parameter that doesn't seem to be influenced by the presence of the microorganisms; while that noise electrochemical it distinguished in real time, the effect of the sulfate reducing in the steel APIX65. (Author)

  2. Solidification Behavior and Weldability of Dissimilar Welds Between a Cr-Free, Ni-Cu Welding Consumable and Type 304L Austenitic Stainless Steel

    Science.gov (United States)

    Sowards, Jeffrey W.; Liang, Dong; Alexandrov, Boian T.; Frankel, Gerald S.; Lippold, John C.

    2012-04-01

    The solidification behavior of a Cr-free welding consumable based on the Ni-Cu system was evaluated in conjunction with Type 304L stainless steel. The weld metal microstructure evolution was evaluated with optical and secondary electron microscopy, energy dispersive spectroscopy, X-ray diffraction, button melting, and thermodynamic (CALPHAD-based) modeling. Solidification partitioning patterns showed that higher dilutions of the filler metal by Type 304L increased segregation of Ti, Cu, and Si to interdendritic regions. Button melting experiments showed a widening of the solidification temperature range with increasing dilution because of the expansion of the austenite solidification range and formation of Ti(C,N) via a eutectic reaction. The model predictions showed good correlation with button melting experiments and were used to evaluate the nature of the Ti(C,N) precipitation reaction. Solidification cracking susceptibility of the weld metal was shown to increase with dilution of 304L stainless steel based on testing conducted with the cast pin tear test. The increase in cracking susceptibility is associated with expansion of the solidification temperature range and the presence of eutectic liquid at the end of solidification that wets solidification grain boundaries.

  3. Acoustic wave propagation in austenitic stainless steel AISI 304L: Application examples

    Energy Technology Data Exchange (ETDEWEB)

    Dahmene, F., E-mail: fethidahmen@yahoo.fr [Laboratoire Roberval Unite Mixte 6066 CNRS, UTC, BP20592, 60205 Compiegne (France)] [Ecole des Mines de Douai, Departement Technologies des Polymeres et Composites and Ingenierie Mecanique, 941 rue Charles Bourseul, BP. 10838, 59508 Douai Cedex (France); Laksimi, A. [Laboratoire Roberval Unite Mixte 6066 CNRS, UTC, BP20592, 60205 Compiegne (France); Hariri, S. [Ecole des Mines de Douai, Departement Technologies des Polymeres et Composites and Ingenierie Mecanique, 941 rue Charles Bourseul, BP. 10838, 59508 Douai Cedex (France); Herve, C.; Jaubert, L.; Cherfaoui, M. [Pole EPI, Equipements sous Pression et Ingenierie d' Instrumentation, CETIM, 52, Avenue Felix-Lauat, BP80067, 60304 Senlis (France); Mouftiez, A. [Ecole des Mines de Douai, Departement Technologies des Polymeres et Composites and Ingenierie Mecanique, 941 rue Charles Bourseul, BP. 10838, 59508 Douai Cedex (France)

    2012-04-15

    Prior to the detection and monitoring by acoustic emission of defects in steel, this paper deals with the use of waveguide that avoids direct contact between the sensor and monitoring structure when working at high temperature. The study of the waveguide effect on elastic wave transmission shows that waveguide deforms the waveform but it does not affect its frequency. Waveguide length does not affect signal magnitude. An experimental example of compact tensile specimen monitoring by acoustic emission is given. The monitoring of the damage at low and high temperature '450 Degree-Sign C' by acoustic emission enables us to identify crack propagation stages and their acoustic signature. - Highlights: Black-Right-Pointing-Pointer This paper deals with the use of waveguide that avoids direct contact between the sensor and monitoring structure when working at high temperature. Black-Right-Pointing-Pointer The objective is the development of nondestructive testing by acoustic emission (AE) of pressure equipment (PE) operating at high temperature. Black-Right-Pointing-Pointer The use of AE in this work has underlined high temperature mechanical behavior in terms of damage and crack propagation.

  4. Effect of prior deformation on the 76-K fracture toughness of AISI 304L and AWS 308L stainless steels

    International Nuclear Information System (INIS)

    AISI 304L and its weld metal, AWS 308L, may undergo a partial transformation to martensite during cryogenic service owing to thermal and mechanical stresses. In this study, the effect of service-induced deformation on the toughness of these materials were determined. Low temperature compressive loading in the laboratory produced larger deformations. Crack initiation toughness, K/sub Ic/(J), and tearing resistance, dJ/da, at 76 K were evaluated as a function of martensite content, a measure of the deformation in these steels. The results showed that the toughness properties of the 304L decrease gradually as the martensite content increases from the 5 to 8% level found in the service condition to the 45% level obtained by compressive loading. The decrease was less than that expected on the basis of the increased flow stress. The toughness properties of the 308L weld metal decreased more sharply with increased martensite content than those of the 304L. The sharp decrease is associated with a degradation of the properties of the delta ferrite rather than that of the austenite

  5. Materials Reliability Program: Environmental Fatigue Testing of Type 304L Stainless Steel U-Bends in Simulated PWR Primary Water (MRP-137)

    Energy Technology Data Exchange (ETDEWEB)

    R.Kilian

    2004-12-01

    Laboratory data generated in the past decade indicate a significant reduction in component fatigue life when reactor water environmental effects are experimentally simulated. However, these laboratory data have not been supported by nuclear power plant component operating experience. In recent comprehensive review of laboratory, component and structural test data performed through the EPRI Materials Reliability Program, flow rate was identified as a critical variable that was generally not considered in laboratory studies but applicable in plant operating environments. Available data for carbon/low-alloy steel piping components suggest that high flow is beneficial regarding the effects of a reactor water environment. Similar information is lacking for stainless steel piping materials. This report documents progress made to date in an extensive testing program underway to evaluate the effects of flow rate on the corrosion fatigue of 304L stainless steel under simulated PWR primary water environmental conditions.

  6. Correlation between Corrosion Potential and Pitting Potential for AISI 304L Austenitic Stainless Steel in 3.5% NaCl Aqueous Solution

    OpenAIRE

    Neusa Alonso-Falleiros; Stephan Wolynec

    2002-01-01

    We investigated the effect of surface finish of two AISI 304L (UNS S30403) stainless steels on the corrosion potential (Ecorr) in 3.5% NaCl aqueous solution and its value was compared with the pitting potential (Ep) value and the type of anodic potentiodynamic curve obtained for determination of Ep in this solution. Five different surface finishes were examined. Ecorr and its standard deviation are strongly affected by the type of surface finish. Moreover, there are evidences of a linear corr...

  7. Oligo-cyclic damage and behaviour of a 304 L austenitic stainless steel according to environment (vacuum, air, PWR primary water) at 300 C

    International Nuclear Information System (INIS)

    Nowadays, for nuclear power plants licensing or operating life extensions, various safety authorities require the consideration of the primary water environment effect on the fatigue life of Pressurized Water Reactor (PWR) components. Thus, this work focused on the study of low cycle fatigue damage kinetics and mechanisms, of a type 304L austenitic stainless steel. Several parameters effects such as temperature, strain rate or strain amplitude were investigated in air as in PWR water. Thanks to targeted in-vacuum tests, the intrinsic influence of these parameters and environments on the fatigue behaviour of the material was studied. It appears that compared with vacuum, air is already an active environment which is responsible for a strong decrease in fatigue lifetime of this steel, especially at 300 C and low strain amplitude. The PWR water coolant environment is more active than air and leads to increased damage kinetics, without any modifications of the initiation sites or propagation modes. Moreover, the decreased fatigue life in PWR water is essentially attributed to an enhancement of both initiation and micropropagation of 'short cracks'. Finally, the deleterious influence of low strain rates on the 304L austenitic stainless steel fatigue lifetime was observed in PWR water environment, in air and also in vacuum without any environmental effects. This intrinsic strain rate effect is attributed to the occurrence of the Dynamic Strain Aging phenomenon which is responsible for a change in deformation modes and for an enhancement of cracks initiation. (author)

  8. Influence of low-temperature nitriding on the strain-induced martensite and laser-quenched austenite in a magnetic encoder made from 304L stainless steel.

    Science.gov (United States)

    Leskovšek, Vojteh; Godec, Matjaž; Kogej, Peter

    2016-08-05

    We have investigated the possibility of producing a magnetic encoder by an innovative process. Instead of turning grooves in the encoder bar for precise positioning, we incorporated the information in 304L stainless steel by transforming the austenite to martensite after bar extrusion in liquid nitrogen and marking it with a laser, which caused a local transformation of martensite back into austenite. 304L has an excellent corrosion resistance, but a low hardness and poor wear resistance, which limits its range of applications. However, nitriding is a very promising way to enhance the mechanical and magnetic properties. After low-temperature nitriding at 400 °C it is clear that both ε- and α'-martensite are present in the deformed microstructure, indicating the simultaneous stress-induced and strain-induced transformations of the austenite. The effects of a laser surface treatment and the consequent appearance of a non-magnetic phase due to the α' → γ transformation were investigated. The EDS maps show a high concentration of nitrogen in the alternating hard surface layers of γN and α'N (expanded austenite and martensite), but no significantly higher concentration of chromium or iron was detected. The high surface hardness of this nitride layer will lead to steels and encoders with better wear and corrosion resistance.

  9. Influence of low-temperature nitriding on the strain-induced martensite and laser-quenched austenite in a magnetic encoder made from 304L stainless steel

    Science.gov (United States)

    Leskovšek, Vojteh; Godec, Matjaž; Kogej, Peter

    2016-08-01

    We have investigated the possibility of producing a magnetic encoder by an innovative process. Instead of turning grooves in the encoder bar for precise positioning, we incorporated the information in 304L stainless steel by transforming the austenite to martensite after bar extrusion in liquid nitrogen and marking it with a laser, which caused a local transformation of martensite back into austenite. 304L has an excellent corrosion resistance, but a low hardness and poor wear resistance, which limits its range of applications. However, nitriding is a very promising way to enhance the mechanical and magnetic properties. After low-temperature nitriding at 400 °C it is clear that both ε- and α‧-martensite are present in the deformed microstructure, indicating the simultaneous stress-induced and strain-induced transformations of the austenite. The effects of a laser surface treatment and the consequent appearance of a non-magnetic phase due to the α‧ → γ transformation were investigated. The EDS maps show a high concentration of nitrogen in the alternating hard surface layers of γN and α‧N (expanded austenite and martensite), but no significantly higher concentration of chromium or iron was detected. The high surface hardness of this nitride layer will lead to steels and encoders with better wear and corrosion resistance.

  10. Characterization of welding of AISI 304l stainless steel similar to the core encircling of a BWR reactor; Caracterizacion de soldaduras de acero inoxidable AISI 304L similares a las de la envolvente del nucleo de un reactor BWR

    Energy Technology Data Exchange (ETDEWEB)

    Gachuz M, M.E.; Palacios P, F.; Robles P, E.F. [ININ, 52045 Ocoyoacac, Estado de Mexico (Mexico)

    2003-07-01

    Plates of austenitic stainless steel AISI 304l of 0.0381 m thickness were welded by means of the SMAW process according to that recommended in the Section 9 of the ASME Code, so that it was reproduced the welding process used to assemble the encircling of the core of a BWR/5 reactor similar to that of the Laguna Verde Nucleo electric plant, there being generated the necessary documentation for the qualification of the one welding procedure and of the welder. They were characterized so much the one base metal, as the welding cord by means of metallographic techniques, scanning electron microscopy, X-ray diffraction, mechanical essays and fracture mechanics. From the obtained results it highlights the presence of an area affected by the heat of up to 1.5 mm of wide and a value of fracture tenacity (J{sub IC}) to ambient temperature for the base metal of 528 KJ/m{sup 2}, which is diminished by the presence of the welding and by the increment in the temperature of the one essay. Also it was carried out an fractographic analysis of the fracture zone generated by the tenacity essays, what evidence a ductile fracture. The experimental values of resistance and tenacity are important for the study of the structural integrity of the encircling one of the core. (Author)

  11. Crack propagation in stainless steel AISI 304L in Hydrogen Chemistry conditions (HWC); Propagacion de Grietas en Acero Inoxidable AISI 304L en Condiciones de Quimica de Hidrogeno (HWC)

    Energy Technology Data Exchange (ETDEWEB)

    Diaz S, A.; Fuentes C, P.; Merino C, F. [ININ, Carretera Mexico -Toluca s/n, La Marquesa, Ocoyoacac, Mexico (Mexico); Castano M, V. [Instituto de Fisica Aplicada, UNAM, Km 15.5 Carretera Queretaro-San Luis Potosi, Juriquilla, Queretaro (Mexico)]. e-mail: ads@nuclear.inin.mx

    2006-07-01

    Velocities of crack growth in samples type CT pre cracking of stainless steel AISI 304l solder and sensitized thermally its were obtained by the Rising Displacement method or of growing displacement. It was used a recirculation circuit that simulates the operation conditions of a BWR type reactor (temperature of 280 C and a pressure of 8 MPa) with the chemistry modified by the addition of hydrogen with and without the addition of impurities of a powerful oxidizer like the Cu{sup +} ion. In each essay stayed a displacement velocity was constant of 1x10{sup -9} m/s, making a continuous pursuit of the advance of the crack by the electric potential drop technique. Contrary to the idea of mitigation of the crack propagation velocity by effect of the addition of the hydrogen in the system, the values of the growth velocities obtained by this methodology went similar to the opposing ones under normal operation conditions. To the finish of the rehearsal one carries out the fractographic analysis of the propagation surfaces, which showed cracks growth in trans and intergranular way, evidencing the complexity of the regulator mechanisms of the IGSCC like in mitigation conditions as the alternative Hydrogen Chemistry. (Author)

  12. Propagation of crevices in stainless steel AISI304L in conditions of hydrogen chemistry (HWC); Propagacion de grietas en acero inoxidable AISI304L en condiciones de quimica de hidrogeno (HWC)

    Energy Technology Data Exchange (ETDEWEB)

    Diaz S, A.; Fuentes C, P.; Merino C, F. [ININ, 52750 Ocoyoacac, Estado de Mexico (Mexico); Castano M, V. [IFA-UNAM, Juriquilla, Queretaro (Mexico)]. e-mail: ads@nuclear.inin.mx

    2006-07-01

    Crevice growth velocities in samples of AISI 304L stainless steel thermally welded and sensitized were obtained by the Rising displacement method or of growing displacement. It was used a recirculation circuit in where the operation conditions of a BWR type reactor were simulated (temperature of 288 C and a pressure of 8 MPa) with the chemistry modified by the addition of hydrogen with and without the addition of impurities of a powerful oxidizer like the Cu{sup ++} ion. CT pre cracked specimens were used and each rehearsal stayed to one constant displacement velocity of 1 x 10{sup -9} m/s (3.6 {mu}m/hr), making a continuous pursuit of the advance of the crack by the electric potential drop technique. To the end of the rehearsal it was carried out the fractographic analysis of the propagation surfaces. The values of the growth velocities obtained by this methodology went similar to the opposing ones under normal conditions of operation; while the fractographic analysis show the cracks propagation in trans and intergranular ways, evidencing the complexity of the regulator mechanisms of the one IGSCC even under controlled ambient conditions or with mitigation methodologies like the alternative hydrogen chemistry. (Author)

  13. Low cycle fatigue: high cycle fatigue damage accumulation in a 304L austenitic stainless steel; Endommagement et cumul de dommage en fatigue dans le domaine de l'endurance limitee d'un acier inoxydable austenitique 304L

    Energy Technology Data Exchange (ETDEWEB)

    Lehericy, Y

    2007-05-15

    The aim of this study was to evaluate the consequences of a Low Cycle Fatigue pre-damage on the subsequent fatigue limit of a 304L stainless steel. The effects of hardening and severe roughness (grinding) have also been investigated. In a first set of tests, the evolution of the surface damage induced by the different LCF pre-cycling was characterized. This has permitted to identify mechanisms and kinetics of damage in the plastic domain for different surface conditions. Then, pre-damaged samples were tested in the High Cycle Fatigue domain in order to establish the fatigue limits associated with each level of pre-damage. Results evidence that, in the case of polished samples, an important number of cycles is required to initiate surface cracks ant then to affect the fatigue limit of the material but, in the case of ground samples, a few number of cycles is sufficient to initiate cracks and to critically decrease the fatigue limit. The fatigue limit of pre-damaged samples can be estimated using the stress intensity factor threshold. Moreover, this detrimental effect of severe surface conditions is enhanced when fatigue tests are performed under a positive mean stress (author)

  14. Correlation between Corrosion Potential and Pitting Potential for AISI 304L Austenitic Stainless Steel in 3.5% NaCl Aqueous Solution

    Directory of Open Access Journals (Sweden)

    Alonso-Falleiros Neusa

    2002-01-01

    Full Text Available We investigated the effect of surface finish of two AISI 304L (UNS S30403 stainless steels on the corrosion potential (Ecorr in 3.5% NaCl aqueous solution and its value was compared with the pitting potential (Ep value and the type of anodic potentiodynamic curve obtained for determination of Ep in this solution. Five different surface finishes were examined. Ecorr and its standard deviation are strongly affected by the type of surface finish. Moreover, there are evidences of a linear correlation between Ecorr and Ep, as well as between the percentage of anodic curves with a well-defined pitting potential and the uncertainty in the determination of Ecorr.

  15. Effects of concentration of sodium chloride solution on the pitting corrosion behavior of AISI 304L austenitic stainless steel

    Directory of Open Access Journals (Sweden)

    Asaduzzaman M.D.

    2011-01-01

    Full Text Available The pitting corrosion behavior of the austenitic stainless steel in aqueous chloride solution was investigated using electrochemical technique. Corrosion potential (Ecorr measurement, potentiodynamic experiments, potential-hold experiments in the passive range, and microscopic examination were used for the evaluation of corrosion characteristics. The experimental parameters were chloride ion concentration, immersion time and anodic-hold potential. Ecorr measurements along with microscopic examinations suggest that in or above 3.5 % NaCl at pH 2 pitting took place on the surface in absence of applied potential after 6 hour immersion. The potentiodynamic experiment reveals that Ecorr and pitting potential (Epit decreased and current density in the passive region increased with the increase of chloride ion concentrations. A linear relationship between Epit and chloride ion concentrations was found in this investigation. The analysis of the results suggests that six chloride ions are involved for the dissolution of iron ion in the pitting corrosion process of austenitic stainless steel.

  16. L2 Milestone 5433: Characterization of Dynamic Behavior of AM and Conventionally Processed Stainless Steel (316L and 304L)

    Energy Technology Data Exchange (ETDEWEB)

    Gray, George Thompson [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Livescu, Veronica [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Rigg, P. A. [Washington State Univ., Pullman, WA (United States). Inst. for Shock Physics; Trujillo, Carl Patrick [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Cady, Carl McElhinney [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Chen, Shuh-Rong [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Carpenter, John S. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Lienert, Thomas J. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Fensin, Saryu Jindal [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Knapp, Cameron M. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Beal, Roberta Ann [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Morrow, Benjamin [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Dippo, Olivia F. [Univ. of California, San Diego, CA (United States); Jones, David Robert [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Martinez, Daniel Tito [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Valdez, James Anthony [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-09-26

    For additive manufacturing (AM) of metallic materials, the certification and qualification paradigm needs to evolve as there currently exists no broadly accepted “ASTM- or DIN-type” additive manufacturing certified process or AM-material produced specifications. Accordingly, design, manufacture, and thereafter implementation and insertion of AM materials to meet engineering applications requires detailed quantification of the constitutive (strength and damage) properties of these evolving materials, across the spectrum of metallic AM methods, in comparison/contrast to conventionally-manufactured metals and alloys. This report summarizes the 316L SS research results and presents initial results of the follow-on study of 304L SS. For the AM-316L SS investigation, cylindrical samples of 316L SS were produced using a LENS MR-7 laser additive manufacturing system from Optomec (Albuquerque, NM) equipped with a 1kW Yb-fiber laser. The microstructure of the AM-316L SS was characterized in both the “as-built” Additively Manufactured state and following a heat-treatment designed to obtain full recrystallization to facilitate comparison with annealed wrought 316L SS. The dynamic shock-loading-induced damage evolution and failure response of all three 316L SS materials was quantified using flyer-plate impact driven spallation experiments at peak stresses of 4.5 and 6.35 GPa. The results of these studies are reported in detail in the first section of the report. Publication of the 316L SS results in an archival journal is planned. Following on from the 316L SS completed work, initial results on a study of AM 304L SS are in progress and presented herein. Preliminary results on the structure/dynamic spallation property behavior of AM-304L SS fabricated using both the directed-energy LENS and an EOS powder-bed AM techniques in comparison to wrought 304L SS is detailed in this Level 2 Milestone report.

  17. Experimental investigation of Tie6Ale4V titanium alloy and 304L stainless steel friction welded with copper interlayer

    Institute of Scientific and Technical Information of China (English)

    R. KUMAR; M. BALASUBRAMANIAN

    2015-01-01

    The basic principle of friction welding is intermetallic bonding at the stage of super plasticity attained with self-generating heat due to friction and finishing at upset pressure. Now the dissimilar metal joints are especially popular in defense, aerospace, automobile, bio-medical, refinery and nuclear engineerings. In friction welding, some special alloys with dual phase are not joined successfully due to poor bonding strength. The alloy surfaces after bonding also have metallurgical changes in the line of interfacing. The reported research work in this area is scanty. Although the sound weld zone of direct bonding between Tie6Ale4V and SS304L was obtained though many trials, the joint was not successful. In this paper, the friction welding characteristics between Tie6Ale4V and SS304L into which pure oxygen free copper (OFC) was introduced as interlayer were investigated. BoxeBehnken design was used to minimize the number of experiments to be performed. The weld joint was analyzed for its mechanical strength. The highest tensile strength between Tie6Ale4V and SS304L between which pure copper was used as insert metal was acquired. Micro-structural analysis and elemental analysis were carried out by EDS, and the formation of intermetallic compound at the interface was identified by XRD analysis.

  18. Experimental investigation of Ti–6Al–4V titanium alloy and 304L stainless steel friction welded with copper interlayer

    Directory of Open Access Journals (Sweden)

    R. Kumar

    2015-03-01

    Full Text Available The basic principle of friction welding is intermetallic bonding at the stage of super plasticity attained with self-generating heat due to friction and finishing at upset pressure. Now the dissimilar metal joints are especially popular in defense, aerospace, automobile, bio-medical, refinery and nuclear engineerings. In friction welding, some special alloys with dual phase are not joined successfully due to poor bonding strength. The alloy surfaces after bonding also have metallurgical changes in the line of interfacing. The reported research work in this area is scanty. Although the sound weld zone of direct bonding between Ti–6Al–4V and SS304L was obtained though many trials, the joint was not successful. In this paper, the friction welding characteristics between Ti–6Al–4V and SS304L into which pure oxygen free copper (OFC was introduced as interlayer were investigated. Box–Behnken design was used to minimize the number of experiments to be performed. The weld joint was analyzed for its mechanical strength. The highest tensile strength between Ti–6Al–4V and SS304L between which pure copper was used as insert metal was acquired. Micro-structural analysis and elemental analysis were carried out by EDS, and the formation of intermetallic compound at the interface was identified by XRD analysis.

  19. Plasma nitriding of AISI 304L and AISI 316L stainless steels: effect of time in the formation of S phase and the chromium nitrides; Nitretacao a plasma dos acos inoxidaveis AISI 304L e AISI 316L: efeito do tempo na formacao da fase S e dos nitretos de cromo

    Energy Technology Data Exchange (ETDEWEB)

    Souza, D.A. de; Barbosa, G.C.; Pinto, F.A.M.; Gontijo, L.C. [Instituto Federal de Educacao, Ciencia e Tecnologia do Espirito Santo - IFES, Vitoria, ES (Brazil); Canal, G.P.; Cunha, A.G., E-mail: disouzam@yahoo.com.br [Universidade Federal do Espirito Santo (UFES), Vitoria, ES (Brazil). Dept. de Fisica

    2009-07-01

    Plasma nitriding can improve hardness and wear resistance of austenitic stainless steels without losses in corrosion resistance. This fact relies on a nitrided layer constituted only by S phase, without chromium nitrides precipitation. In this work, the effect of nitriding time on phases formed on nitrided layer was investigated in two austenitic stainless steels: AISI 304L e AISI 316L. The samples were nitrided at 420 deg C, using a mixture of 60 % N{sub 2} and 40% H{sub 2}, during 5, 7 and 9 hours. It was noted that chromium nitrides were formed on samples of AISI 304L, nitrided for 7 e 9 hours, while all nitrided samples of AISI 316L showed only formation of S phase. The nitrided layers were characterized using optical microscope and x-ray diffraction. (author)

  20. Effect of surface machining and cold working on the ambient temperature chloride stress corrosion cracking susceptibility of AISI 304L stainless steel

    International Nuclear Information System (INIS)

    Effect of plastic deformation induced by cold rolling or surface machining on the susceptibility to chloride-induced stress corrosion cracking at ambient temperature of 304L austenitic stainless steel was investigated in this study. The test material was subjected to three treatments: (a) solution annealed, (b) cold rolled and (c) surface machined to induce different levels of strain/stresses in the material. Subsequently constant strained samples were produced as per ASTM G30 for each condition and these were exposed to 1 M HCl at ambient temperature until cracking occurred. Subsequently the cracked samples were characterized using stereo microscopy, optical microscopy and atomic force microscopy to understand the effect of microstructural changes produced by straining on the susceptibility to stress corrosion cracking at ambient temperature. Strained surface produced by machining accelerated the process of crack initiation resulting in densely distributed shallow surface cracks in a very short period of time as compared to solution annealed and cold worked sample. Crack propagation in cold worked sample was along the slip lines and cracking occurred much earlier than in the solution annealed sample.

  1. Heat transfer and fluid flow during keyhole mode laser welding of tantalum, Ti 6Al 4V, 304L stainless steel and vanadium

    Science.gov (United States)

    Rai, R.; Elmer, J. W.; Palmer, T. A.; Roy, T. Deb

    2007-09-01

    Because of the complexity of several simultaneous physical processes, most heat transfer models of keyhole mode laser welding require some simplifications to make the calculations tractable. The simplifications often limit the applicability of each model to the specific materials systems for which the model is developed. In this work, a rigorous, yet computationally efficient, keyhole model is developed and tested on tantalum, Ti-6Al-4V, 304L stainless steel and vanadium. Unlike previous models, this one combines an existing model to calculate keyhole shape and size with numerical fluid flow and heat transfer calculations in the weld pool. The calculations of the keyhole profile involved a point-by-point heat balance at the keyhole walls considering multiple reflections of the laser beam in the vapour cavity. The equations of conservation of mass, momentum and energy are then solved in three dimensions assuming that the temperatures at the keyhole wall reach the boiling point of the different metals or alloys. A turbulence model based on Prandtl's mixing length hypothesis was used to estimate the effective viscosity and thermal conductivity in the liquid region. The calculated weld cross-sections agreed well with the experimental results for each metal and alloy system examined here. In each case, the weld pool geometry was affected by the thermal diffusivity, absorption coefficient, and the melting and boiling points, among the various physical properties of the alloy. The model was also used to better understand solidification phenomena and calculate the solidification parameters at the trailing edge of the weld pool. These calculations indicate that the solidification structure became less dendritic and coarser with decreasing weld velocities over the range of speeds investigated in this study. Overall, the keyhole weld model provides satisfactory simulations of the weld geometries and solidification sub-structures for diverse engineering metals and alloys.

  2. Comparative study in the induced corrosion by sulfate reducing microorganisms, in a stainless steel 304L sensitized and a carbon steel API X65; Estudio comparativo de la corrosion inducida por microorganismos sulfatorreductores, en un acero inoxidable 304L sensibilizado y un acero al carbono API X65

    Energy Technology Data Exchange (ETDEWEB)

    Diaz S, A.; Gonzalez F, E.; Arganis J, C.; Luna C, P.; Carapia M, L. [ININ, Carretera Mexico-Toluca Km. 36.5, 52045 Estado de Mexico (Mexico)]. e-mail: ads@nuclear.inin.mx

    2004-07-01

    In spite of the operational experience related with the presence of the phenomenon of microbiological corrosion (MIC) in industrial components, it was not but until the decade of the 80 s when the nuclear industry recognized its influence in some systems of Nuclear Generating Power plants. At the moment, diverse studies that have tried to explain the generation mechanism of this phenomenon exist; however, they are even important queries that to solve, especially those related with the particularities of the affected metallic substrates. Presently work, the electrochemical behavior of samples of stainless steel AISI 304L sensitized is evaluated and the carbon steel APIX65, before the action of sulfate reducing microorganisms low the same experimental conditions; found that for the APIX65 the presence of this type of bacteria promoted the formation of a stable biofilm that allowed the maintenance of the microorganisms that damaged the material in isolated places where stings were generated; while in the AISI 304L, it was not detected damage associated to the inoculated media. The techniques of Resistance to the Polarization and Tafel Extrapolation, allowed the calculation of the speed of uniform corrosion, parameter that doesn't seem to be influenced by the presence of the microorganisms; while that noise electrochemical it distinguished in real time, the effect of the sulfate reducing in the steel APIX65. (Author)

  3. THE EFFECT OF SMALL AMOUNTS OF ELEMENTS ON SHAPES OF POTENTIODYNAMIC AND POTENTIOSTATIC CURVES OF AISI 304L AND AISI 316L STAINLESS STEELS IN CHLORIDE MEDIA

    Directory of Open Access Journals (Sweden)

    D. Pulino-Sagradi

    1997-06-01

    Full Text Available Abstract - Samples of high purity grade and commercial purity grade type AISI 304L and AISI 316L steels were studied by the potentiodynamic and potentiostatic techniques in a naturally aerated 3.5% NaCl aqueous solution at a controlled temperature of (23±2°C. The anodic polarization curves of the potentiodynamic technique showed that not always is it possible to determine pitting potential: most of the curves of commercial purity grade steels displayed a smooth curvature in the region where the current density should increase sharply. The density current versus time potentiostatic curves also showed different shapes according to the purity grade steels: for the commercial purity grade steels, the current density showed large oscillations with time (related to unstable pits, whereas for the high purity grade steels, a regular behavior of current density as a function of time was found (related to stable pits

  4. AES depth profiles in Mo-coated 304L stainless steel achieved by RF-magnetron sputtering and influence of Mo on the corrosion in 3.5% NaCl solution

    Energy Technology Data Exchange (ETDEWEB)

    Saidi, D. [Département de métallurgie, Division de Technologie du Combustible, Centre de Recherche Nucléaire de Draria CRND, BP. 43 Draria, Alger (Algeria); Zaid, B., E-mail: zaidbachir@yahoo.com [Département de métallurgie, Division de Technologie du Combustible, Centre de Recherche Nucléaire de Draria CRND, BP. 43 Draria, Alger (Algeria); Souami, N. [Centre de Recherche Nucléaire d’Alger CRNA, 2 Bd. Frantz Fanon, Alger (Algeria); Saoula, N. [Division des Milieux Ionisés et Lasers, Centre de Développement des Technologies Avancées CDTA, Cité du 20 août 1956, Baba Hassan, BP n 17, Alger (Algeria); Siad, M. [Centre de Recherche Nucléaire d’Alger CRNA, 2 Bd. Frantz Fanon, Alger (Algeria); Si Ahmed, A. [Im2np, UMR 7334 CNRS, Aix-Marseille Université, 13397 Marseille Cedex 20 (France); Biberian, J.P. [CINaM, UMR 7525 CNRS, Aix Marseille Université, 13288 Marseille Cedex 9 (France)

    2015-10-05

    Highlights: • Mo coating of 304L stainless steel is achieved via RF-magnetron sputtering. • The AES depth profiles before and after annealing in air (at 973 K) are analyzed. • The corrosions in NaCl solution of bare and Mo-coated samples are compared. • Mo-coated steels exhibit better corrosion behaviors. • The positive action of Mo oxide via its semi-conducting properties is deduced. - Abstract: Molybdenum-coated 304L stainless steel samples, fabricated by RF-magnetron sputtering, are characterized by Auger Electron Spectroscopy (AES) before and after annealing in air at 973 K. The electrochemical parameters of bare and coated materials, in NaCl 3.5% water solution at 298 K, are derived from the potentiodynamic polarization curves. The corrosion current of Mo-coated samples (before and after annealing) is significantly lower than that of its bare counterpart. The information gained from the AES depth profiles leads us to infer that the positive action of molybdenum on the corrosion behavior may be attributed to the changes induced by the semi-conducting properties of Mo oxide in the passive film.

  5. Zirconium oxide deposits (ZrO{sub 2}) and titanium oxide (TiO{sub 2}) on 304l stainless steel; Depositos de oxido de circonio (ZrO{sub 2}) y oxido de titanio (TiO{sub 2}) sobre acero inoxidable 304L

    Energy Technology Data Exchange (ETDEWEB)

    Davila N, M. L.

    2015-07-01

    This research project aims to carry out the surface and electrochemical characterization to obtain the optimum conditions of the hydrothermal deposits of zirconium oxide ZrO{sub 2} (baddeleyite) and titanium oxide TiO{sub 2} (anatase and rutile phases) on 304l stainless steel, simulating an inhibiting protective layer. 304l steel specimens were cut, pre-oxidized in water at a temperature of 288 degrees Celsius and 8 MPa, similar to those of a typical BWR conditions. From the titanium oxide anatase crystalline phase, the rutile phase was obtained by a heat treatment at 1000 degrees Celsius. The Sigma-Aldrich pre-oxidized powders and steel 304l were characterized using techniques of X-ray diffraction, scanning electron microscopy, X-ray dispersive energy, chemical mapping and Raman spectrometry. The pre-oxidized steel has two oxide layers, an inner layer with nano metric crystals and another outer of larger crystals to 1μm, with the formation of hematite and magnetite, this predominating. The surface that contacted the sample holder has larger crystals. Hydrothermal deposits were carry out from suspensions of 10, 100 and 1000 ppm, of the crystal phases of anatase, rutile and baddeleyite, on the pre-oxidized steel at a temperature of 150 degrees Celsius for 2 and 7 days, samples were analyzed by X-ray diffraction, scanning electron microscopy, X-ray dispersive energy, Raman spectrometry and Tafel polarization. The suspension to 1000 ppm for 7 days coated surface most; the baddeleyite deposit is noticed more homogeneous than anatase and rutile. The deposit is favored when hematite and magnetite crystals are larger. The chemical mapping on deposits show that even after being immersed in water to 288 degrees Celsius during 30 days, the deposits are still present although a loss is observed. A reference electrode was assembled to conduct electrochemical tests of Tafel able to withstand a temperature of 288 degrees Celsius and pressure of 8 MPa. The baddeleyite deposit

  6. Ferromagnetic properties of cold rolled AISI 304L steel

    Science.gov (United States)

    Tavares, S. S. M.; da Silva, M. R.; Neto, J. M.; Miraglia, S.; Fruchart, D.

    2002-04-01

    The ferromagnetic properties (coercive force, residual and saturation magnetisation) of a cold rolled AISI 304L stainless steel were measured as function of the applied deformation, using a vibrating sample magnetometer. The martensite volume fraction produced by deformation was calculated through the magnetisation saturation ( σs) value. A maximum amount of martensite (81%) was obtained by applying a true deformation ɛ=2.41 and a heat treatment at 400°C after rolling. The residual induction ( Br) and the squareness (=ratio between residual ( Br) and saturation ( Bs) inductions) increased, while the coercive field ( Hc) decreased with the amount of deformation. The heat treatment at 400°C promotes as well the increase of both Br and Br/ Bs and the decrease of Hc. The magnetic properties obtained in the most severely deformed samples ( Hc=23.08-23.63 kJ/m 3, Br=1.01-1.20 T and Bs=1.12-1.28 T) are comparable to that of some hard and semi-hard alloys used as magnets. The stability of the ferromagnetic martensite ( α') was investigated by thermomagnetic analysis. The starting ( As) and final ( Af) temperatures of the martensite phase ( α') transformation into austenite during heating were determined to As=430-440°C and Af=610-616°C.

  7. Microstructural origins of radiation-induced changes in mechanical properties of 316 L and 304 L austenitic stainless steels irradiated with mixed spectra of high-energy protons and spallation neutrons

    Science.gov (United States)

    Sencer, B. H.; Bond, G. M.; Hamilton, M. L.; Garner, F. A.; Maloy, S. A.; Sommer, W. F.

    2001-07-01

    A number of candidate alloys were exposed to a particle flux and spectrum at Los Alamos Neutron Science Center (LANSCE) that closely match the mixed high-energy proton/neutron spectra expected in accelerator production of tritium (APT) window and blanket applications. Austenitic stainless steels 316 L and 304 L are two of these candidate alloys possessing attractive strength and corrosion resistance for APT applications. This paper describes the dose dependence of the irradiation-induced microstructural evolution of SS 316 L and 304 L in the temperature range 30-60°C and consequent changes in mechanical properties. It was observed that the microstructural evolution during irradiation was essentially identical in the two alloys, a behavior mirrored in their changes in mechanical properties. With one expection, it was possible to correlate all changes in mechanical properties with visible microstructural features. A late-term second abrupt decrease in uniform elongation was not associated with visible microstructure, but is postulated to be a consequence of large levels of retained hydrogen measured in the specimens. In spite of large amounts of both helium and hydrogen retained, approaching 1 at.% at the highest exposures, no visible cavities were formed, indicating that the gas atoms were either in solution or in subresolvable clusters.

  8. Microstructural features of a type 304L stainless steel deformed at 1473 K in the strain rate interval 10[sup [minus]3] s[sup [minus]1] to 10[sup 2] s[sup [minus]1

    Energy Technology Data Exchange (ETDEWEB)

    Sundararaman, D.; Divakar, R.; Raghunathan, V.S. (Indira Gandhi Centre for Atomic Research, Kalpakkam (India))

    1993-05-01

    Deformation processing of materials in continuously being refined by dynamic materials modeling procedures to establish a safe window for the manufacture of engineering components. Microstructure development during the processing and its correlation with the mechanical properties is inevitable for better understanding of the materials. On this basis, microstructural examination of the dynamically processed type 304L austenitic stainless steels has been carried out. The samples that have been deformed at 1,473 K under various strain rates, ranging from 10[sup [minus]2]s[sup [minus]1] to 10[sup 2]s[sup [minus]1], were observed by transmission electron microscopy, to corroborate the energy efficiency of the process. The details of the energy efficiency contours and their implications are reported elsewhere. In this report the authors present some of the unusual microstructural features that, in general, are not desirable for the safe processing of materials.

  9. Thermal fatigue of a 304L austenitic stainless steel: simulation of the initiation and of the propagation of the short cracks in isothermal and aniso-thermal fatigue; Fatigue thermique d'un acier inoxydable austenitique 304L: simulation de l'amorcage et de la croissance des fissures courtes en fatigue isotherme et anisotherme

    Energy Technology Data Exchange (ETDEWEB)

    Haddar, N

    2003-04-01

    The elbow pipes of thermal plants cooling systems are submitted to thermal variations of short range and of variable frequency. These variations bound to temperature changes of the fluids present a risk of cracks and leakages. In order to solve this problem, EDF has started the 'CRECO RNE 808' plan: 'thermal fatigue of 304L austenitic stainless steels' to study experimentally on a volume part, the initiation and the beginning of the propagation of cracks in thermal fatigue on austenitic stainless steels. The aim of this study is more particularly to compare the behaviour and the damage of the material in mechanic-thermal fatigue (cycling in temperature and cycling in deformation) and in isothermal fatigue (the utmost conditions have been determined by EDF for the metal: Tmax = 165 degrees C and Tmin = 90 degrees C; the frequency of the thermal variations can reach a Hertz). A lot of experimental results are given. A model of lifetime is introduced and validated. (O.M.)

  10. Superficial and electrochemical study of stainless steel 304l with an inhibitory protective coating (TiO{sub 2} and ZrO{sub 2}); Estudio superficial y electroquimico de acero inoxidable 304L con una capa protectora inhibidora (TiO{sub 2} y ZrO{sub 2})

    Energy Technology Data Exchange (ETDEWEB)

    Davila N, M. L.; Contreras R, A.; Arganis J, C. R., E-mail: aida.contreras@inin.gob.mx [ININ, Carretera Mexico-Toluca s/n, 52750 Ocoyoacac, Estado de Mexico (Mexico)

    2014-10-15

    The degradation mechanisms in the boiling water reactors (BWR) have been an alert focus for owners, especially the cracking by stress corrosion cracking (SCC), therefore different techniques have been studied to inhibit this problem inside which is the water injection of hydrogen feeding (HWC, Hydrogen Water Chemistry), together with the noble metals injection (NMCA, Nobel Metal Chemical Addition) and the ceramic materials injection that form an inhibitory protective coating (Ipc). In this work the Ipc was simulated, for which were carried out hydro-thermals deposits starting from suspensions of 1000 ppm of zirconium oxide in its crystalline phase baddeleyite and titanium oxides in its anatase and rutile phases, on test tubes of stainless steel 304l previously rusty under simulated conditions of pressure and temperature of a BWR (288 C and 8 MPa). The superficial characterization was realized by scanning electron microscopy, energy-dispersive of X-ray and X-ray diffraction. The capacity to mitigate the corrosion was studied with the electrochemical technique of Tafel polarization (288 C and 8 MPa). The steel presents the formation of two oxide coatings formed by magnetite and hematite. The baddeleyite presents a deposit more thick and homogeneous it also presents the most negative electrochemical potential of corrosion, what indicates that it has the bigger capacity to mitigate the SCC. (Author)

  11. Study of diffusion welding between the zirconium alloy Zy{sub 4} and the stainless steel 304L. Morphology of the interface and nature of the phases formed; Etude du soudage diffusion entre l'alliage de zirconium Zy{sub 4} et l'acier inoxydable 304L. Morphologie de l'interface et nature des phases formees

    Energy Technology Data Exchange (ETDEWEB)

    Taouinet, M. [Centre de Recherche Nucleaire de Draria (CRNA), Alger (Algeria); Lebaili, S. [Universite des Sciences et de la Technologie Houari Boumediene, Lab. de Science et Genie des Materiaux, Faculte de Genie Mecanique et Genie des Procedes, Alger (Algeria); Souami, N. [Centre de Recherche Nucleaire d' Alger (CRNA), Alger (Algeria)

    2009-07-01

    We approach a study on the solid state diffusion bonding between zircaloy (Zy{sub 4}) and stainless steel (304L) for an application in the sector of the nuclear power. The diffusion couples prepared underwent treatments at the temperatures ranging between 850 and 1020 C in a controlled atmosphere and under dynamic pressures. We give a particular attention to the morphology of the interface, formed, and to the determination of the nature of the compounds formed. The observations and chemical analysis are realized by ESEM-EDX and XRD. The quantitative distribution as well as the detailed localization of the basic chemical elements are defined by chemical profiles, and series of images X. The junction of diffusion consists of three zones distinct, formed from a solid solution FeCr({alpha}), rich in Cr in the form of a homogeneous edge, localized in steel side. The two other zones of the center of the Zy{sub 4} side are two phase of type Zr{sub {alpha}}, (FeCr){sub {alpha}}-Zr(Fe, Cr){sub 2} and Zr{sub {alpha}}-Zr{sub 2}(Fe{sub 1-x}Ni{sub x}), 0.15{<=}x{<=}0.25. The detailed results obtained, are a regrouping, between those obtained from the observations and chemical analysis and radio crystallographic. The values of the measured micro-hardnesses give very heterogeneous filiations to the level of the interface. (authors)

  12. Hydrogen-assisted crack propagation in 304L/308L and 21Cr–6Ni–9Mn/308L austenitic stainless steel fusion welds

    International Nuclear Information System (INIS)

    Highlights: ► Measured crack growth resistance of welds with 140 wppm H from gas charging. ► H reduced fracture initiation toughness by over 67% and altered fracture mode. ► With H, microcracks initiate at weld ferrite. Without H, fracture is uniformly ductile. ► With H, localized deformation in austenite creates stress concentrations at ferrite. ► In austenite/ferrite microstructures, JIC decreases with increasing vol.% ferrite. - Abstract: Elastic–plastic fracture mechanics methods were used to characterize hydrogen-assisted crack propagation in two austenitic stainless steel gas tungsten arc (GTA) welds. Thermally precharged hydrogen (140 wppm) degraded fracture initiation toughness and crack growth toughness and altered fracture mechanisms. Fracture initiation toughness in hydrogen-precharged welds represented a reduction of >67% from the estimated toughness of non-charged welds. In hydrogen-precharged welds, microcracks initiated at ferrite, and dendritic microstructure promoted crack propagation along ferrite. Deformation twinning in austenite interacts with ferrite, facilitating microcrack formation. While hydrogen altered fracture mechanisms similarly for both welds, the amount of ferrite governed the severity of hydrogen-assisted crack propagation.

  13. Multi-scale analysis of behavior and fatigue life of 304L stainless under cyclic loading with pre-hardening

    International Nuclear Information System (INIS)

    This study investigates the effects of loading history on the cyclic stress-strain curve and fatigue behavior of 304L stainless steel at room temperature. Tension-compression tests were performed on the same specimen under controlled strain, using several loading sequences of increasing or decreasing amplitude. The results showed that fatigue life is significantly reduced by the previous loading history. A previously developed method for determining the effect of prehardening was evaluated. Microstructural analyses were also performed; the microstructures after pre-loading and their evolution during the fatigue cycles were characterized by TEM. The results of these analyses improve our understanding of the macroscopic properties of 304L stainless steel and can help us identify the causes of failure and lifetime reduction. (author)

  14. Welding of Vanadium, Tantalum, 304L and 21-6-9 Stainless Steels, and Titanium Alloys at Lawrence Livermore National Laboratory using a Fiber Delivered 2.2 kW Diode Pumped CW Nd:YAG Laser

    Energy Technology Data Exchange (ETDEWEB)

    Palmer, T; Elmer, J; Pong, R; Gauthier, M

    2006-06-16

    This report summarizes the results of a series of laser welds made between 2003 and 2005 at Lawrence Livermore National Laboratory (LLNL). The results are a compilation of several, previously unpublished, internal LLNL reports covering the laser welding of vanadium, tantalum, 304L stainless steel, 21-6-9 (Nitronic 40) steel, and Ti-6Al-4V. All the welds were made using a Rofin Sinar DY-022 diode pumped continuous wave Nd:YAG laser. Welds are made at sharp focus on each material at various power levels and travel speeds in order to provide a baseline characterization of the performance of the laser welder. These power levels are based on measurements of the output power of the laser system, as measured by a power meter placed at the end of the optics train. Based on these measurements, it appears that the system displays a loss of approximately 10% as the beam passes through the fiber optic cable and laser optics. Since the beam is delivered to the fixed laser optics through a fiber optic cable, the effects of fiber diameter are also briefly investigated. Because the system utilizes 1:1 focusing optics, the laser spot size at sharp focus generally corresponds to the diameter of the fiber with which the laser is delivered. Differences in the resulting weld penetration in the different materials system are prevalent, with the welds produced on the Nitronic 40 material displaying the highest depths (> 5 mm) and minimal porosity. A Primes focusing diagnostic has also been installed on this laser system and used to characterize the size and power density distribution of the beams as a function of both power and focus position. Further work is planned in which this focusing diagnostic will be used to better understand the effects of changes in beam properties on the resulting weld dimensions in these and other materials systems.

  15. Initiation and growth of thermal fatigue crack networks in an AISI 304 L type austenitic stainless steel (X2 CrNi18-09); Amorcage et propagation de reseaux de fissures de fatigue thermique dans un acier inoxydable austenitique de type X2 CrNi18-09 (AISI 304 L)

    Energy Technology Data Exchange (ETDEWEB)

    Maillot, V

    2004-07-01

    We studied the behaviour of a 304 L type austenitic stainless steel submitted to thermal fatigue. Using the SPLASH equipment of CEA/SRMA we tested parallelepipedal specimens on two sides: the specimens are continuously heated by Joule effect, while two opposites faces are cyclically. cooled by a mixed spray of distilled water and compressed air. This device allows the reproduction and the study of crack networks similar to those observed in nuclear power plants, on the inner side of circuits fatigued by mixed pressurized water flows at different temperatures. The crack initiation and the network constitution at the surface were observed under different thermal conditions (Tmax = 320 deg C, {delta}T between 125 and 200 deg C). The experiment produced a stress gradient in the specimen, and due to this gradient, the in-depth growth of the cracks finally stopped. The obtained crack networks were studied quantitatively by image analysis, and different parameters were studied: at the surface during the cycling, and post mortem by step-by-step layer removal by grinding. The maximal depth obtained experimentally, 2.5 mm, is relatively coherent with the finite element modelling of the SPLASH test, in which compressive stresses appear at a depth of 2 mm. Some of the crack networks obtained by thermal fatigue were also tested in isothermal fatigue crack growth under 4-point bending, at imposed load. The mechanisms of the crack selection, and the appearance of the dominating crack are described. Compared to the propagation of a single crack, the crack networks delay the propagation, depending on the severity of the crack competition for domination. The dominating crack can be at the network periphery, in that case it is not as shielded by its neighbours as a crack located in the center of the network. It can also be a straight crack surrounded by more sinuous neighbours. Indeed, on sinuous cracks, the loading is not the same all along the crack path, leading to some

  16. Fatigue behaviour of 304L steel welded structures: influence of residual stresses and surface mechanical finishing

    International Nuclear Information System (INIS)

    This study focuses on the influence of residual stresses and surface mechanical finishing on lifetime of stainless steel 304L welded structures. Residual stresses are determined on specific specimens of three types: base-metal, as-welded and ground-welded specimens. Each type is submitted to fatigue tests in order to assess the influence of these parameters on the lifetime, and to determine their evolution. The experiments show that an important surface stress concentration is located in the weld root of as-welded structures, which has a negative effect on the fatigue life. The grinding operation generates high-level surface residual stresses but the lifetime is higher thanks to the reduction of the notch effect. The fatigue test results are compared to the nuclear industry best-fit S-N curves. This enables the determination of correction factors related to fatigue test results of polished specimens, and to assess the lifetime of structures. (author)

  17. Resistance Spot Weldability of Dissimilar Materials: BH180-AISI304L Steels and BH180-IFT123 Steels

    Institute of Scientific and Technical Information of China (English)

    Fatih Hayat

    2011-01-01

    In this study, resistance spot weldability of 180 grade bake hardening steel (BH180), 7123 grade interstitial free steel (IF7123) and 304 grade austenitic stainless steel (AISI304L) with each other was investigated. In the joining process, electrode pressure and weld current were kept constant and six different weld time were chosen. Microstructure, microhardness, tensile-shear properties and fracture types of resistance spot welded joints were examined. In order to characterize the metallurgical structure of the welded joint, the microstructural profile was developed, and the relationship between mechanical properties and microstructure was determined. The change of weld time, nugget diameter, the HAZ (heat affected zone) width and the electrode immersion depth were also investigated. Welded joints were examined by SEM (scanning electron microscopy) images of fracture surface. As a result of the experiment, it was determined that with increasing weld time, tensile shear load bearing capacity (TLBC) increased with weld time up to 25 cycle and two types of tearing occurred. It was also determined that while the failure occurred from IF side at the BHIS0+IF7123 joint, it occurred from the BH180 side at the BHIS0+AISI304L joint.

  18. Influence of Size on the Microstructure and Mechanical Properties of an AISI 304L Stainless Steel—A Comparison between Bulk and Fibers

    Directory of Open Access Journals (Sweden)

    Francisco J. Baldenebro-Lopez

    2015-01-01

    Full Text Available In this work, the mechanical properties and microstructural features of an AISI 304L stainless steel in two presentations, bulk and fibers, were systematically studied in order to establish the relationship among microstructure, mechanical properties, manufacturing process and effect on sample size. The microstructure was analyzed by XRD, SEM and TEM techniques. The strength, Young’s modulus and elongation of the samples were determined by tensile tests, while the hardness was measured by Vickers microhardness and nanoindentation tests. The materials have been observed to possess different mechanical and microstructural properties, which are compared and discussed.

  19. Flow lines and microscopic elemental inhomogeneities in austenitic stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Mosley, Jr, W C

    1982-01-01

    Flow lines in mechanically formed austenitic stainless steels are known to influence fracture behavior. Enhancement of flow lines by chemical etching is evidence of elemental inhomogeneity. This paper presents the results of electron microprobe analyses to determine the nature of flow lines in three austenitic stainless steels: 21Cr-6Ni-9Mn, 304L, and 19Ni-18Cr.

  20. Stainless Steel Permeability

    Energy Technology Data Exchange (ETDEWEB)

    Buchenauer, Dean A. [Sandia National Laboratories (SNL-CA), Livermore, CA (United States); Karnesky, Richard A. [Sandia National Laboratories (SNL-CA), Livermore, CA (United States)

    2015-09-01

    An understanding of the behavior of hydrogen isotopes in materials is critical to predicting tritium transport in structural metals (at high pressure), estimating tritium losses during production (fission environment), and predicting in-vessel inventory for future fusion devices (plasma driven permeation). Current models often assume equilibrium diffusivity and solubility for a class of materials (e.g. stainless steels or aluminum alloys), neglecting trapping effects or, at best, considering a single population of trapping sites. Permeation and trapping studies of the particular castings and forgings enable greater confidence and reduced margins in the models. For FY15, we have continued our investigation of the role of ferrite in permeation for steels of interest to GTS, through measurements of the duplex steel 2507. We also initiated an investigation of the permeability in work hardened materials, to follow up on earlier observations of unusual permeability in a particular region of 304L forgings. Samples were prepared and characterized for ferrite content and coated with palladium to prevent oxidation. Issues with the poor reproducibility of measurements at low permeability were overcome, although the techniques in use are tedious. Funding through TPBAR and GTS were secured for a research grade quadrupole mass spectrometer (QMS) and replacement turbo pumps, which should improve the fidelity and throughput of measurements in FY16.

  1. Deep drawing of 304 L Steel Sheet using Vegetable oils as Forming Lubricants

    Science.gov (United States)

    Shashidhara, Y. M.; Jayaram, S. R.

    2012-12-01

    The study involves the evaluation of deep drawing process using two non edible oils, Pongam (Pongammia pinnata) and Jatropha (Jatropha carcass) as metal forming lubricants. Experiments are conducted on 304L steel sheets under the raw and modified oils with suitable punch and die on a hydraulic press of 200 ton capacity. The punch load, draw-in-length and wall thickness distribution for deep drawn cups are observed. The drawn cups are scanned using laser scanning technique and 3D models are generated using modeling package. The wall thickness profiles of cups at different sections (or height) are measured using CAD package. Among the two raw oils, the drawn cups under Jatropha oil, have uniform wall thickness profile compared to Pongam oil. Uneven flow of material and cup rupturing is observed under methyl esters of Pongam and Jatropha oil lubricated conditions. However, the results are observed under epoxidised Jatropha oil with uniform metal flow and wall thicknesses compared to mineral and other versions of vegetable oils.

  2. Mechanisms-based viscoplasticity: Theoretical approach and experimental validation for steel 304L.

    Science.gov (United States)

    Zubelewicz, Aleksander; Oliferuk, Wiera

    2016-01-01

    We propose a mechanisms-based viscoplasticity approach for metals and alloys. First, we derive a stochastic model for thermally-activated motion of dislocations and, then, introduce power-law flow rules. The overall plastic deformation includes local plastic slip events taken with an appropriate weight assigned to each angle of the plane misorientation from the direction of maximum shear stress. As deformation progresses, the material experiences successive reorganizations of the slip systems. The microstructural evolution causes that a portion of energy expended on plastic deformation is dissipated and the rest is stored in the defect structures. We show that the reorganizations are stable in a homogeneously deformed material. The concept is tested for steel 304L, where we reproduce experimentally obtained stress-strain responses, we construct the Frost-Ashby deformation map and predict the rate of the energy storage. The storage is assessed in terms of synchronized measurements of temperature and displacement distributions on the specimen surface during tensile loading. PMID:27026209

  3. Thermal fatigue of austenitic and duplex stainless steels

    OpenAIRE

    Virkkunen, Iikka

    2001-01-01

    Thermal fatigue behavior of AISI 304L, AISI 316, AISI 321, and AISI 347 austenitic stainless steels as well as 3RE60 and ACX-100 duplex stainless steels was studied. Test samples were subjected to cyclic thermal transients in the temperature range 20 - 600°C. The resulting thermal strains were analyzed with measurements and numerical calculations. The evolution of thermal fatigue damage was monitored with periodic residual stress measurements and replica-assisted microscopy. The elastic strai...

  4. Stainless steel recycle FY94 progress report

    International Nuclear Information System (INIS)

    The Materials Technology Section (MTS) of the Savannah River Technology Center (SRTC) was asked to demonstrate the practicality of recycling previously contaminated stainless steel components such as reactor heat exchanger heads, process water piping and slug buckets into 208 liters (55 gallon) drums and 2.8 cubic meter (100 ft3) storage boxes. Radioactively contaminated stainless steel scrap will be sent to several industrial partners where it will be melted, decontaminated/cast into ingots, and rolled into plate and sheet and fabricated into the drums and boxes. As part of this recycle initiative, MTS was requested to demonstrate that radioactively contaminated Type 304L stainless steel could be remelted and cast to meet the applicable ASTM specification for fabrication of drums and boxes. In addition, MTS was requested to develop the technical basis of melt decontamination and establish practicality of using this approach for value added products. The findings presented in this investigation lead to the following conclusions: recycle of 18 wt% Cr-8 wt% Ni alloy can be achieved by melting Type 304 stainless steel in a air vacuum induction furnace; limited melt decontamination of the contaminated stainless steel was achieved, surface contamination was removed by standard decontamination techniques; carbon uptake in the as-cast ingots resulted from the graphite susceptor used in this experiment and is unavoidable with this furnace configuration. A new furnace optimized for melting stainless steel has been installed and is currently being tested for use in this program

  5. Weldability of Stainless Steels

    International Nuclear Information System (INIS)

    It gives an outline of metallographic properties of welding zone of stainless steels, generation and mechanisms of welding crack and decreasing of corrosion resistance of welding zone. It consists of seven chapters such as introduction, some kinds of stainless steels and properties, metallographic properties of welding zone, weld crack, toughness of welding zone, corrosion resistance and summary. The solidification modes of stainless steels, each solidification mode on the cross section of Fe-Cr-Ni alloy phase diagram, each solidification mode of weld stainless steels metal by electron beam welding, segregation state of alloy elements at each solidification mode, Schaeffler diagram, Delong diagram, effects of (P + S) mass content in % and Cr/Ni equivalent on solidification cracking of weld stainless steels metal, solidification crack susceptibility of weld high purity stainless steels metal, effects of trace impurity elements on solidification crack susceptibility of weld high purity stainless steels metal, ductile fracture susceptibility of weld austenitic stainless steels metal, effects of H2 and ferrite content on generation of crack of weld 25Cr-5N duplex stainless steels, effects of O and N content on toughness of weld SUS 447J1 metals, effect of ferrite content on aging toughness of weld austenitic stainless steel metal, corrosion morphology of welding zone of stainless steels, generation mechanism of knife line attack phenomenon, and corrosion potential of some kinds of metals in seawater at room temperature are illustrated. (S.Y.)

  6. Effect of Cold-Rolling on Precipitation Phenomena in Sensitized Type 316L and 340L Austenitic Stainless Steels

    Institute of Scientific and Technical Information of China (English)

    H.Tsubakino; A.Yamamoto; T. Yamada; L.Liu; M.Terasawa; S.Nakahigashi; H.Harada

    2004-01-01

    Precipitation phenomena in Type 316L and 304L stainless steels were studied mainly by transmission electron microscopic (TEM) observations after cold-rolling ranging from 0% (as solution annealed) to 80% reduction in thickness,and then by sensitization treatment. Precipitates were identified by electron diffraction analysis and EDS analysis.Precipitates observed in sensitized 316L stainless steel were sigma and chi phases, whereas carbide and sigma were observed in sensitized 304L stainless steel. Recrystallized grains were formed in 30% cold-rolled and sensitized 304L.However, the tendency toward recrystallization in sensitized 316L was much lower than in 304L. Precipitation of sigma and chi phases was accelerated by cold-rolling and they were observed at grain boundaries in lower cold-rolling; they were also seen, in grain interiors in higher cold-rolling. Higher deformation induced partially recrystallization combined with precipitation, resulting in the formation of heterogeneous microstructures.

  7. Phenomena of the coupling between steel 304L and platinum group metal particles in the environment of the dissolution of burned nuclear fuels

    International Nuclear Information System (INIS)

    This work describes the phenomena of the electrochemical coupling between stainless steel (304L) and platinum group metal particles in the environment of the recycling of burned nuclear fuels. The main goals of this work are to prove the acceleration of the corrosion by these deposits, the comprehension of the mechanisms and the development of a corrosion model. First the corrosion phenomena are evidenced for steel in contact with noble particles (RuO2,xH2O and Ru(0)). Their accelerating effect on the corrosion process is quantified in 8 mol.L-1 HNO3. Second a local approach on the reduction process is performed using Scanning Electrochemical Microscopy (SECM). The reduction reaction is investigated for microelectrodes and for different substrates (Ru, Pt, bare steel and steel with deposit). This approach clearly showed the catalytic effect of the noble particles on the reduction process of nitrate. Most probably the limiting step of the reduction process, the chemical formation of NO2, is catalyzed by these particles. Third a reduction scheme is developed for different materials which can describe the experimental results. Simulation results were in agreement with the experimental results. This demonstrates the validity of the assumptions for the model. Finally a model was developed for the bare steel as well as the covered steel, taking into account the dissolution step. It is shown that the most important parameter, that governs the whole corrosion process is the concentration of N(III) species. It can be concluded that, due to the presence of the deposits, the concentration of these species is higher in the vicinity of the steel substrate. (author)

  8. Warm compacting behavior of stainless steel powders

    Institute of Scientific and Technical Information of China (English)

    肖志瑜; 柯美元; 陈维平; 召明; 李元元

    2004-01-01

    The warm compacting behaviors of four different kinds of stainless steel powders, 304L, 316L, 410L and 430L, were studied. The results show that warm compaction can be applied to stainless steel powders. The green densities and strengths of compacts obtained through warm compaction are generally higher than those obtained through cold compaction. The compacting behaviors in warm compaction and cold compaction are similar.Under the compacting pressure of 700 MPa, the warm compacted densities are 0. 10 - 0.22 g/cm3 higher than the cold compacted ones, and the green strengths are 11.5 %-50 % higher. The optimal warm compacting temperature is 100 - 110 ℃. In the die wall lubricated warm compaction, the optimum internal lubricant content is 0.2%.

  9. Fatigue of stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Solin, J. (VTT Technical Research Centre of Finland, Espoo (Finland))

    2010-05-15

    The 2009b update of ASME III introduces a new set of fatigue design curves. The new curve for austenitic stainless steels is exactly matching with the one endorsed in 2007 by the US NRC for new designs only. This has a notable effect in usage factor calculation at strain amplitudes below 0.5 %. However, experimental results clearly demonstrate that a new air curve would not be needed for the studied stainless steel grades. Our current results suggest arguments for use of stabilized stainless steels in NPP piping components, where high cycle fatigue (epsilon{sub a}<=0.5%) is a concern. (orig.)

  10. The Influence of Surface Processing on Outgassing Measurements of High-Mn Stainless Steel

    Science.gov (United States)

    Fukaya, Masuhiro; Teraoka, Shin-Ichi; Sato, Yoshihiro; Uota, Masahiko; Saito, Yoshio

    An outgassing rate was measured for a stainless steel material of YUS130S, having a high-mangany content (Fe-18Cr-7Ni-11Mn-0.3N), and compared with that for a stainless steel of SUS304L. A surface processing of both electropolished and electrochemical buffing followed by an in-air oxidation was examined in order to investigate the outgas reduction effect in the case of with and without baking. Further, a depth profile of the surface composition was analyzed by glow-discharge emission spectroscopy (GDS). Based on the results, the outgassing rate of YUS130S was 35% lower than that of SUS304L, when electropolished and electrochemical buffing. The oxidation process in air at 723 K in the case of electrochemical buffing showed effect on the outgassing reduction in both YUS130S and SUS304L. The GDS observation shows that, by electropolishing, Cr-Mn-rich and Cr-rich passive films were formed on the YUS130S and SUS304L surface, respectively. By electrochemical buffing, passive films changed to more Fe-rich films. The further process of in-air-oxidation causes a change in oxide films to Fe-Mn-rich and Fe-rich characteristics for YUS130S and SUS304L respectively. The stainless steel with Mn-rich and Cr-poor passive films shows low outgassing rate.

  11. Articles comprising ferritic stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Rakowski, James M.

    2016-06-28

    An article of manufacture comprises a ferritic stainless steel that includes a near-surface region depleted of silicon relative to a remainder of the ferritic stainless steel. The article has a reduced tendency to form an electrically resistive silica layer including silicon derived from the steel when the article is subjected to high temperature oxidizing conditions. The ferritic stainless steel is selected from the group comprising AISI Type 430 stainless steel, AISI Type 439 stainless steel, AISI Type 441 stainless steel, AISI Type 444 stainless steel, and E-BRITE.RTM. alloy, also known as UNS 44627 stainless steel. In certain embodiments, the article of manufacture is a fuel cell interconnect for a solid oxide fuel cell.

  12. Self-organisation of nanoscaled pores in anodic oxide overlayer on stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Martin, F. [CEA de Saclay, DEN, DPC, SCCME, Laboratoire d' Etude de la Corrosion Aqueuse, F-91191 Gif-sur-Yvette (France); Del Frari, D. [CEA de Saclay, DSM, IRAMIS, SPSCI, F-91191 Gif-sur-Yvette (France); Cousty, J. [CEA de Saclay, DSM, IRAMIS, SPSCI, F-91191 Gif-sur-Yvette (France)], E-mail: jacques.cousty@cea.fr; Bataillon, C. [CEA de Saclay, DEN, DPC, SCCME, Laboratoire d' Etude de la Corrosion Aqueuse, F-91191 Gif-sur-Yvette (France)

    2009-04-15

    The nanoscaled morphology of the overlayer covering stainless steels after electropolishing in perchloric acid-based electrolyte was explored mainly by AFM and SEM. Two kinds of stainless steels were tested. For the austenitic one (AISI 304L), a quasi-periodic arrangement of pores in this overlayer has been observed. Depending on the experimental conditions, the distance between neighbouring pores ranged from 20 nm up to 230 nm. This inter-pore distance varied either with the applied voltage or with the current density for a constant voltage. From XPS spectra performed on the nanostructured surfaces, analysis of the energy shifts of Cr and Fe 2p levels showed that the anodic overlayer was enriched in Cr atoms compared to the 304L steel bulk composition. For the austeno-ferritic duplex stainless steel, the electropolished surface exhibited nanoscaled pores, which had grown and self-organised on both phases but with different characteristic dimensions.

  13. Non destructive testing by acoustic signature of damage level in 304L steel samples submitted to rolling, tensile test and thermal annealing treatments

    International Nuclear Information System (INIS)

    The aim of this work is to demonstrate the ability of acoustic signature technique to detect in a non-destructive way mechanical property variations due to damage of the internal material structure for 304L steel samples, provided by EDF company. For this purpose, the velocity and the attenuation of Rayleigh acoustic waves have been measured for rolled, drawn and thermally treated samples. Complementary information provided by echography have also been used to calculate the corresponding variations of the dynamic Young's modulus E

  14. Structure and related corrosion behaviour in 1M H{sub 2}SO{sub 4} of b.c.c. 304L films prepared by ion beam sputtering

    Energy Technology Data Exchange (ETDEWEB)

    Idiri, M.; Boubeker, B. [Faculte des Science, Casablanca (Morocco). Lab. de Controle et d' Analyse des Materiaux; Sabot, R. [Laboratoire d' Etudes des Materiaux en Milieux Agressifs, Universite de La Rochelle, Faculte des Sciences, Avenue Marillac, 17042, La Rochelle (France); Goudeau, P. [Laboratoire de Metallurgie Physique, Universite de Poitiers, UMR 6630 du CNRS, Universite de Poitiers, SP2MI, Bd 3, Teleport 2, B.P; 179, 86960, Futuroscope (France); Dinhut, J.-F.; Grosseau-Poussard, J.-L. [Laboratoire d' Etudes des Materiaux en Milieux Agressifs, Universite de La Rochelle, Faculte des Sciences, Avenue Marillac, 17042, La Rochelle (France)

    1999-12-15

    The corrosion behaviour in a non-deaered 1M H{sub 2}SO{sub 4} solution of 304L stainless steel (SS) in bulk and thin film state was investigated. In the first step, we elaborated based cubic-centred 304L stainless steel thin films onto Si and f.c.c. 304L SS bulk substrates by using a sputter deposition method. Then, the structure and residual macrostress state of the films were studied by X-ray diffraction. It was found that films are in a highly compressive state ({approx}3 GPa). Finally, corrosion tests revealed an improvement in corrosion resistance of the films with respect to the bulk 304L stainless steel. (orig.)

  15. Metal release reduction from stainless steel for LWR

    International Nuclear Information System (INIS)

    Reduction of metal release from structural materials is one of key subjects on reliability in nuclear power plants. This study describes the pre-filming technology to reduce Cr and Co release from TP304L feeder water tube. Reducing content of elements that have long half time from the structural materials is very important for reduction of radioactivity. Stainless steels contain slight amount of Co as contamination. Lower Co in TP304L is obtained during a steel making process using a raw material from a blast furnace to reduce scraps which contains Co contamination. So extra low Co (< 0.02%) is applied to the chemical controlled TP304L for the feeder water tubes. Furthermore, pre-filming was also studied. It was known that metal release increased during early term in operation and reduced with growing oxide film. In high temperature water, Cr2O3 is stable oxide. So Cr2O3 pre-filming for inner surface of the feeder water tube was investigated for the reduction of metal release. TP304L consists of mainly Fe, Cr and Ni. Cr has the lowest oxygen potential than those of them. Cr can be oxidized selectivity by controlling a dew point of atmosphere during a heat treatment. Pre-filming on inner surface of the feeder water tube was performed by the final heat treatment under the controlled dew points in flowing H2 gas. The amount of metal release was measured in water at 488 K by a refreshed type autoclave. The rate of Cr rerelease from the pre-filming tube was two third that from the bare tube without pre-filming. It was considered that pre-filming was effective for the reduction of the metal release from the tube. (author)

  16. Influence of high pressure hydrogen environment on tensile and fatigue properties of stainless steels at low temperatures

    Science.gov (United States)

    Ogata, T.

    2012-06-01

    Hydrogen environment embrittlement (HEE) of stainless steels in the environment of high pressure and low temperature hydrogen gas was evaluated using a very simple mechanical properties testing procedure. In the method, the high-pressure hydrogen environment is produced just inside the hole in the specimen. In this work, the effects of HEE on fatigue properties for austenitic stainless steels SUS304L and SUS316L were evaluated at 298 and 190 K. The effects of HEE on the tensile properties of higher strength stainless steels, such as strain-hardened 316, SUS630, and other alloys, SUH660 and Alloy 718 were also examined. The less effect of HEE on fatigue properties of SUS316L and tensile properties of strain-hardened 316 were observed compared with SUS304L and other steels at room temperature and 190 K.

  17. Attenuation of shock waves in copper and stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Harvey, W.B.

    1986-06-01

    By using shock pins, data were gathered on the trajectories of shock waves in stainless steel (SS-304L) and oxygen-free-high-conductivity copper (OFHC-Cu). Shock pressures were generated in these materials by impacting the appropriate target with thin (approx.1.5 mm) flying plates. The flying plates in these experiments were accelerated to high velocities (approx.4 km/s) by high explosives. Six experiments were conducted, three using SS-304L as the target material and three experiments using OFHC-Cu as the target material. Peak shock pressures generated in the steel experiments were approximately 109, 130, and 147 GPa and in the copper experiments, the peak shock pressures were approximately 111, 132, and 143 GPa. In each experiment, an attenuation of the shock wave by a following release wave was clearly observed. An extensive effort using two characteristic codes (described in this work) to theoretically calculate the attenuation of the shock waves was made. The efficacy of several different constitutive equations to successfully model the experiments was studied by comparing the calculated shock trajectories to the experimental data. Based on such comparisons, the conclusion can be drawn that OFHC-Cu enters a melt phase at about 130 GPa on the principal Hugoniot. There was no sign of phase changes in the stainless-steel experiments. In order to match the observed attenuation of the shock waves in the SS-304L experiments, it was necessary to include strength effects in the calculations. It was found that the values for the parameters in the strength equations were dependent on the equation of state used in the modeling of the experiments. 66 refs., 194 figs., 77 tabs.

  18. Atom probe, AFM, and STM studies on vacuum-fired stainless steels.

    Science.gov (United States)

    Stupnik, A; Frank, P; Leisch, M

    2009-04-01

    The surface morphology of grades 304L and 316LN stainless steels, after low-temperature bake-out process and vacuum annealing, has been studied by atomic force microscopy (AFM) and scanning tunnelling microscopy (STM). The local elemental composition on the surface before and after thermal treatment has been investigated by atom probe (AP) depth profiling measurements. After vacuum annealing, AFM and STM show significant changes in the surface structure and topology. Recrystallization and surface reconstruction is less pronounced on the 316LN stainless steel. AP depth profiling analyses result in noticeable nickel enrichment on the surface of grade 304L samples. Since hydrogen recombination is almost controlled by surface structure and composition, a strong influence on the outgassing behaviour by the particular surface microstructure can be deduced. PMID:19167824

  19. Corrosion behavior of powder metallurgical stainless steels in urban and marine environments

    OpenAIRE

    Bautista, A.; F. Velasco; S. Guzmán; Fuente, Daniel de la; Cayuela, F.; Morcillo, Manuel

    2006-01-01

    This work studies the development of corrosive attack on sintered components manufactured from AISI 316L and AISI 304L powders. The stainless steels were sintered in vacuum and in nitrogen-base atmosphere at 1,120 and 1,250ºC, and their corrosion resistance was then analyzed by electrochemical techniques and by atmospheric corrosion testing (two years) at urban and marine test sites. Images are shown of the morphology of the attack on the surface of the stainless steels and the development...

  20. Corrosion behavior of powder metallurgical stainless steels in urban and marine environments

    OpenAIRE

    Bautista, A.; F. Velasco; S. Guzmán; de la Fuente, D.; Cayuela, F.; Morcillo, M.

    2006-01-01

    This work studies the development of corrosive attack on sintered components manufactured from AISI 316L and AISI 304L powders. The stainless steels were sintered in vacuum and in nitrogen-base atmosphere at 1,120 and 1,250 ºC, and their corrosion resistance was then analyzed by electrochemical techniques and by atmospheric corrosion testing (two years) at urban and marine test sites. Images are shown of the morphology of the attack on the surface of the stainless steels and the development o...

  1. Stainless steel display evaluation

    Science.gov (United States)

    Hopper, Darrel G.; Meyer, Frederick M.; Longo, Sam J.; Trissell, Terry L.

    2007-04-01

    Active matrix organic light emitting diode (AMOLED) technology is one candidate to become a low power alternative in some applications to the currently dominant, active matrix liquid crystal display (AMLCD), technology. Furthermore, fabrication of the AMOLED on stainless steel (SS) foil rather than the traditional glass substrate, while presenting a set of severe technical challenges, opens up the potential for displays that are both lighter and less breakable. Also, transition to an SS foil substrate may enable rollable displays - large when used but small for stowage within gear already worn or carried or installed. Research has been initiated on AMOLED/SS technology and the first 320 x 240 color pixel 4-in. demonstration device has been evaluated in the AFRL Display Test and Evaluation Laboratory. Results of this evaluation are reported along with a research roadmap.

  2. Elaboration et étude de l'oxydation à haute température d'un cermet dense constitué de particules d'acier inoxydable 304L dispersées dans une matrice de zircone yttriée.

    OpenAIRE

    Tarabay, Jinan

    2013-01-01

    Ceramic matrix composite dispersed with metallic particles, called M(p)-CMC(s), are being developed for optimizing several functions of industrial components in severe atmospheres at high temperature.The corrosion of a model M(p)-CMC(s), based on 304L stainless steel and yttrium doped zirconia (304L(p)-ZrO2(s); 40%/60% in volume) is studied and compared with the oxidation behaviour of the stainless steel powders. The oxidation behaviour of the model 304L(p)-ZrO2(s) composite produced by powde...

  3. Weld bonding of stainless steel

    DEFF Research Database (Denmark)

    Santos, I. O.; Zhang, Wenqi; Goncalves, V.M.;

    2004-01-01

    This paper presents a comprehensive theoretical and experimental investigation of the weld bonding process with the purpose of evaluating its relative performance in case of joining stainless steel parts, against alternative solutions based on structural adhesives or conventional spot-welding. Th......This paper presents a comprehensive theoretical and experimental investigation of the weld bonding process with the purpose of evaluating its relative performance in case of joining stainless steel parts, against alternative solutions based on structural adhesives or conventional spot...

  4. Welding Stainless Steels and Refractory Metals Using Diode-Pumped Continuous Wave Nd:YAG Lasers

    Energy Technology Data Exchange (ETDEWEB)

    Palmer, T A; Elmer, J W; Pong, R; Gauthier, M D

    2004-09-27

    This report provides an overview of a series of developmental welding studies performed on a 2.2 kW Rofin Sinar DY-022 Diode Pumped Continuous Wave (CW) Nd:YAG welder at Lawrence Livermore National Laboratory (LLNL). Several materials systems, ranging from refractory metals, such as commercially pure tantalum and vanadium, to austenitic stainless steels, including both 304L and 21-6-9 grades, are examined. Power input and travel speed are systematically varied during the welding of each materials system, and the width, depth, and cross sectional area of the resulting weld fusion zones are measured. These individual studies are undertaken in order to characterize the response of the welder to changes in these welding parameters for a range of materials and to determine the maximum depth of penetration of which this welder is capable in each materials system. The maximum weld depths, which are on the order of 5.4 mm, are observed in the 21-6-9 austenitic stainless steel at the maximum laser power setting (2200 W) and a slow travel speed (6.4 mm/sec). The next highest weld depth is observed in the 304L stainless steel, followed by that observed in the vanadium and, finally, in the tantalum. Porosity, which is attributed to the collapse of the keyhole during welding, is also observed in the welds produced in tantalum, vanadium, and 304L stainless steel. Only the 21-6-9 austenitic stainless steel welds displayed little or no porosity over the range of welding parameters. Comparisons with similar laser welding systems are also made for several of these same materials systems. When compared with the welds produced by these other systems, the LLNL system typically produces welds of an equivalent or slightly higher depth.

  5. Multi-cracking in uniaxial and biaxial fatigue of 304L stainless steel

    International Nuclear Information System (INIS)

    When a mechanical part is subjected to a repeated mechanical stress, it may be damaged after a number of cycles by several cracks initiation and propagation of a main crack. This is the phenomenon of fatigue damage. The thesis deals specifically with possible damage to some components of nuclear plants due to thermal fatigue. Unlike conventional mechanical fatigue damage where a main crack breaks the part, the thermal fatigue damage usually results in the appearance of a surface crack network. Two aspects are discussed in the thesis. The first is the experimental study of fatigue multiple cracking stage also called multi-cracking. Two mechanical test campaigns with multi-cracking detection by digital image correlation were conducted. These campaigns involve uniaxial and equi-biaxial mechanical loads in tension/compression without mean stress. This work allows to monitor and to observe the evolution of different networks of cracks through mechanical solicitations. The second is the numerical simulation of the phenomenon of fatigue damage. Several types of model are used (stochastic, probabilistic, cohesive finite elements). The experimental results have led to identify a multiple crack initiation law in fatigue which is faced with the numerical results. This comparison shows the relevance of the use of an analytical probabilistic model to find statistical results on the density of cracks that can be initiated with thermal and mechanical fatigue loadings. (author)

  6. Influence of Water Pollution on MIC of Stainless Steel 304L

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The influence of water pollution and welding defects on MIC (microbiologically influenced corrosion) was studied. The open circuit potential (OCP) was measured during MIC test. It was found that OCP shifted to a higher level when the system was inoculated with bacteria while the OCP of those samples in water without bacteria was kept at a low level. The OCP decreased dramatically when MIC started in polluted water. Combination of weld defect-heat tint, polluted water and adding bacteria causes MIC happen at high rate. Some elements inside the tubercle were analyzed with EDXA. The pits and biofilm were observed with SEM. Microbiological analysis revealed the difference of bacteria between corroded and uncorroded samples.

  7. Can the Point Defect Model Explain the Influence of Temperature and Anion Size on Pitting of Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Blackwood, Daniel J. [National University of Singapore, Singapore (Singapore)

    2015-12-15

    The pitting behaviours of 304L and 316L stainless steels were investigated at 3 °C to 90 °C in 1 M solutions of NaCl, NaBr and NaI by potentiodynamic polarization. The temperature dependences of the pitting potential varied according to the anion, being near linear in bromide but exponential in chloride. As a result, at low temperatures grades 304L and 316L steel are most susceptible to pitting by bromide ions, while at high temperatures both stainless steels were more susceptible to pitting by small chloride anions than the larger bromide and iodide. Thus, increasing temperature appears to favour attack by smaller anions. This paper will attempt to rationalise both of the above findings in terms of the point defect model. Initial findings are that qualitatively this approach can be reasonably successful, but not at the quantitative level, possibly due to insufficient data on the mechanical properties of thin passive films.

  8. Welding Characteristics of Nitrogen Added Stainless Steels for Nuclear Application

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Y. D. [Pohang Iron and Steel Co., Ltd, Pohang (Korea, Republic of)

    1997-07-01

    Characteristics of properties and manufacturing process was evaluated in development of high strength and corrosion resistant stainless steel. The continuous cast structure of STS 316L was similar to that of STS 304. The most of residual {delta}-ferrite of STS 316L was vermicular type. The residual {delta}-ferrite content increased from the surface towards the center of the slab and after reaching a maximum value at about 50mm distance from surface and steeply decreased towards the center itself. Hot ductility of STS 304L and STS 316L stainless steels containing below 1000 ppm N was appeared to be reasonably good in the range of hot rolling temperature. In case of the steels containing over 1000 ppm N, the hot ductility was decreased rapidly when sulfur content of the steel was above 20 ppm. Therefore, to achieve good hot ductility of the high nitrogen containing steel, reduction of sulfur contents is required as low as possible. The inter granular corrosion resistance and impact toughness of STS 316L were increased with increasing the nitrogen contents. Yield strength and tensile strength of 304 and 316 stainless steels are increased linearly with increasing the nitrogen contents but their elongations are decreased with increasing the nitrogen contents. Therefore, the mechanical properties of these stainless steels could be controlled with variation of nitrogen. The effects of nitrogen on the resistance of stress corrosion cracking (SCC) can be explained by improvement of the load bearing capacity with increasing tensile strength rather than inhibition of trans granular SCC crack generation and propagation. 101 refs., 17 tabs., 105 figs. (author)

  9. Strip casting of stainless steels

    OpenAIRE

    Raabe, D.

    1997-01-01

    FLAT PRODUCTS OF STAINLESS STEELS ARE CONVENTIONALLY MANUFACTURED BY CONTINUOUS CASTING, HOT ROLLING, HOT BAND ANNEALING, PICKLING, COLD ROLLING AND RECRYSTALLISATION. IN THE LAST YEARS STRIP CASTING HAS INCREASINGLY ATTRACTED ATTENTION. IT OFFERS THREE IMPROVEMENTS IN COMPARISON TO THE CONVENTIONAL METHOD.1.) IT ALLOWS TO CAST STEEL SHEETS WITH THE SAME THICKNESS AND WIDTH AS THOSE PRODUCED BY HOT ROLLING. THIS MEANS THAT THE HOT ROLLING PROCESSIS BYPASSED. 2.) THE STRIP CAST STEEL REVEALS A...

  10. HYDROGEN EFFECTS ON THE FRACTURE TOUGHNESS PROPERTIES OF FORGED STAINLESS STEELS

    Energy Technology Data Exchange (ETDEWEB)

    Morgan, M

    2008-03-28

    The effect of hydrogen on the fracture toughness properties of Types 304L, 316L and 21-6-9 forged stainless steels was investigated. Fracture toughness samples were fabricated from forward-extruded forgings. Samples were uniformly saturated with hydrogen after exposure to hydrogen gas at 34 MPa or 69 and 623 K prior to testing. The fracture toughness properties were characterized by measuring the J-R behavior at ambient temperature in air. The results show that the hydrogen-charged steels have fracture toughness values that were about 50-60% of the values measured for the unexposed steels. The reduction in fracture toughness was accompanied by a change in fracture appearance. Both uncharged and hydrogen-charged samples failed by microvoid nucleation and coalescence, but the fracture surfaces of the hydrogen-charged steels had smaller microvoids. Type 316L stainless steel had the highest fracture toughness properties and the greatest resistance to hydrogen degradation.

  11. Cryogenic material properties of stainless steel tube-to-flange welds

    Science.gov (United States)

    Siewert, T. A.; McCowan, C. N.; Vigliotti, D. P.

    The mechanical properties of stainless steel tube-to-flange welds for a cryogenic piping application were measured. A planar specimen was developed to duplicate the constraint, loading and heat-sink properties of the circular joint, while reducing preparation time and cost. Specimens were evaluated containing welds between the tube material (21 Cr-6Ni-9Mn) and the three stainless steels being considered for the flange materials: type 304L, type 316L and 21 Cr-6Ni-9Mn. The mechanical property tests consisted of three phases: simple tensile testing to failure, tensile testing of notched specimens (where the notch simulated fabrication flaws) and fatigue testing of notched specimens for the 4 × 10 4 cycle design life of the structure. The type 316L stainless steel flange produced welds with the best combination of strength and ductility at 295 and 4 K in all three phases of testing.

  12. Preformed posterior stainless steel crowns: an update.

    Science.gov (United States)

    Croll, T P

    1999-02-01

    For almost 50 years, dentists have used stainless steel crowns for primary and permanent posterior teeth. No other type of restoration offers the convenience, low cost, durability, and reliability of such crowns when interim full-coronal coverage is required. Preformed stainless steel crowns have improved over the years. Better luting cements have been developed and different methods of crown manipulation have evolved. This article reviews stainless steel crown procedures for primary and permanent posterior teeth. Step-by-step placement of a primary molar stainless steel crown is documented and permanent molar stainless steel crown restoration is described. A method for repairing a worn-through crown also is reviewed.

  13. Multitechnique characterisation of 304L surface states oxidised at high temperature in steam and air atmospheres

    Science.gov (United States)

    Mamede, Anne-Sophie; Nuns, Nicolas; Cristol, Anne-Lise; Cantrel, Laurent; Souvi, Sidi; Cristol, Sylvain; Paul, Jean-François

    2016-04-01

    In case of a severe accident occurring in a nuclear reactor, surfaces of the reactor coolant system (RCS), made of stainless steel (304L) rich in Cr (>10%) and Ni (8-12%), are oxidised. Fission products (FPs) are released from melt fuel and flow through the RCS. A part of them is deposited onto surfaces either by vapour condensation or by aerosol deposition mechanisms. To be able to understand the nature of interactions between these FPs and the RCS surfaces, a preliminary step is to characterize the RSC surface states in steam and air atmosphere at high temperatures. Pieces of 304L stainless steel have been treated in a flow reactor at two different temperatures (750 °C and 950 °C) for two different exposition times (24 h and 72 h). After surfaces analysing by a unique combination of surface analysis techniques (XPS, ToF-SIMS and LEIS), for 304L, the results show a deep oxide scale with multi layers and the outer layer is composed of chromium and manganese oxides. Oxide profiles differ in air or steam atmosphere. Fe2O3 oxide is observed but in minor proportion and in all cases no nickel is detected near the surface. Results obtained are discussed and compared with the literature data.

  14. Corrosion behavior of 2205 duplex stainless steel.

    Science.gov (United States)

    Platt, J A; Guzman, A; Zuccari, A; Thornburg, D W; Rhodes, B F; Oshida, Y; Moore, B K

    1997-07-01

    The corrosion of 2205 duplex stainless steel was compared with that of AISI type 316L stainless steel. The 2205 stainless steel is a potential orthodontic bracket material with low nickel content (4 to 6 wt%), whereas the 316L stainless steel (nickel content: 10 to 14 wt%) is a currently used bracket material. Both stainless steels were subjected to electrochemical and immersion (crevice) corrosion tests in 37 degrees C, 0.9 wt% sodium chloride solution. Electrochemical testing indicates that 2205 has a longer passivation range than 316L. The corrosion rate of 2205 was 0.416 MPY (milli-inch per year), whereas 316L exhibited 0.647 MPY. When 2205 was coupled to 316L with equal surface area ratio, the corrosion rate of 2205 reduced to 0.260 MPY, indicating that 316L stainless steel behaved like a sacrificial anode. When 316L is coupled with NiTi, TMA, or stainless steel arch wire and was subjected to the immersion corrosion test, it was found that 316L suffered from crevice corrosion. On the other hand, 2205 stainless steel did not show any localized crevice corrosion, although the surface of 2205 was covered with corrosion products, formed when coupled to NiTi and stainless steel wires. This study indicates that considering corrosion resistance, 2205 duplex stainless steel is an improved alternative to 316L for orthodontic bracket fabrication when used in conjunction with titanium, its alloys, or stainless steel arch wires. PMID:9228844

  15. Stainless steel denitriding with slag

    International Nuclear Information System (INIS)

    Calculation and experimental methods were used to investigate the process of titanium nitride formation when alloying chromium nickel stainless steels with titanium. At common concentrations of titanium and nitrogen, titanium nitrides were observed to be precipitated from the melt into slag in amounts of 0.1% and more. The laboratory study of the slag influence of the process of steel refining from titanium nitrides showed that the slag containing calcium, aluminium and magnesium oxides is favourable to the denitriding of steel. In addition, the possibility of direct transition of dissolved nitrogen from the metal into the slag is revealed. 7 refs., 1 fig., 2 tabs

  16. Low temperature thermal aging of austenitic stainless steel welds: Kinetics and effects on mechanical properties

    International Nuclear Information System (INIS)

    Highlights: ► Embrittlement of 304L and 316L welds after aging up to 20,000 h. ► Spinodal decomposition and G-phase precipitation in ferrite at 400 °C. Only spinodal decomposition at 335 and 365 °C. ► Charpy impact, microhardness and tensile tests for evaluation of aging embrittlement and its kinetics determined. - Abstract: Austenitic stainless steel welds in components used in light water reactors are susceptible to thermal aging embrittlement at reactor operating temperature of around 300 °C after a long service life. In this study, low temperature aging embrittlement of types 304L and 316L stainless steel welds with 10% ferrite was investigated on the basis of changes in mechanical properties and microstructure after aging up to 20,000 h at 335, 365 and 400 °C. Spinodal decomposition and G-phase precipitation in the ferrite was observed after aging which lead to embrittlement in the material. In contrast to the small effect on tensile properties, the impact toughness was significantly degraded after aging. Charpy impact test of the aged samples showed decrease in upper-shelf and lower-shelf energy and increase in ductile brittle transition temperature. Large increase in the microhardness of ferrite phase was observed with no change in austenite hardness. The embrittlement in 316L weld was higher compared to 304L weld for similar aging condition. The kinetics of aging embrittlement was established based on Arrhenius relationship. A constant activation energy was determined for 304L weld in the temperature range 335–400 °C, however, 316L weld showed different activation energy values in each temperature range.

  17. Low temperature thermal aging of austenitic stainless steel welds: Kinetics and effects on mechanical properties

    Energy Technology Data Exchange (ETDEWEB)

    Chandra, K., E-mail: kchandra@barc.gov.in [Materials Science Division, Bhabha Atomic Research Centre, Mumbai 400 085 (India); Kain, Vivekanand [Materials Science Division, Bhabha Atomic Research Centre, Mumbai 400 085 (India); Bhutani, Vikas [Punjab Engineering College, Chandigarh 160 012 (India); Raja, V.S. [Indian Institute of Technology, Mumbai 400 076 (India); Tewari, R.; Dey, G.K. [Materials Science Division, Bhabha Atomic Research Centre, Mumbai 400 085 (India); Chakravartty, J.K. [Mechanical Metallurgy Division, Bhabha Atomic Research Centre, Mumbai 400 085 (India)

    2012-02-01

    Highlights: Black-Right-Pointing-Pointer Embrittlement of 304L and 316L welds after aging up to 20,000 h. Black-Right-Pointing-Pointer Spinodal decomposition and G-phase precipitation in ferrite at 400 Degree-Sign C. Only spinodal decomposition at 335 and 365 Degree-Sign C. Black-Right-Pointing-Pointer Charpy impact, microhardness and tensile tests for evaluation of aging embrittlement and its kinetics determined. - Abstract: Austenitic stainless steel welds in components used in light water reactors are susceptible to thermal aging embrittlement at reactor operating temperature of around 300 Degree-Sign C after a long service life. In this study, low temperature aging embrittlement of types 304L and 316L stainless steel welds with 10% ferrite was investigated on the basis of changes in mechanical properties and microstructure after aging up to 20,000 h at 335, 365 and 400 Degree-Sign C. Spinodal decomposition and G-phase precipitation in the ferrite was observed after aging which lead to embrittlement in the material. In contrast to the small effect on tensile properties, the impact toughness was significantly degraded after aging. Charpy impact test of the aged samples showed decrease in upper-shelf and lower-shelf energy and increase in ductile brittle transition temperature. Large increase in the microhardness of ferrite phase was observed with no change in austenite hardness. The embrittlement in 316L weld was higher compared to 304L weld for similar aging condition. The kinetics of aging embrittlement was established based on Arrhenius relationship. A constant activation energy was determined for 304L weld in the temperature range 335-400 Degree-Sign C, however, 316L weld showed different activation energy values in each temperature range.

  18. The deformation response of L-grade stainless steels relative to IGSCC in 288 C water

    International Nuclear Information System (INIS)

    Laboratory testing of L-grade stainless steels in representative boiling water nuclear reactor (BWR) core environments has shown that the intergranular (IG) cracking behavior is sensitive to the composition, corrosion potential and cold work. The objective of this study is to explore the deformation response of L-grade stainless steels to better understand its role on the IGSCC behavior. The deformation response was studied as a function of composition to evaluate the phase stability, susceptibility to sensitization and creep relaxation behaviors. The effect of deformation on 304, 304L, 316L and 316NG materials were evaluated metallographically and as a function of thermal treatment using the double loop electrochemical potentiokinetic reactivation (DL-EPR) technique. Metallographic results show that 304L is most likely to form deformation induced martensite, consistent with calculations. The DL-EPR response of 304L and 316L/NG materials increases significantly upon thermal treatment of cold worked material. These results are being used to determine the combinations of cold work and thermal treatment that promote IGSCC in 288 C high purity water at ∼ +200mVSHE of 304L weld material obtained from an unirradiated nuclear station core shroud. The creep relaxation response of 304, 304L, 316L and 316NG materials were evaluated as a function of the stress intensity in 288 C air using compact tension specimens. The preliminary results suggest that the lower alloyed 304L exhibits more creep strain in the same period of time than higher alloyed 316L/NG and Alloy 600 materials. These results have implications in terms of the slip-oxidation model for crack advance where higher creep rates are expected to promote a higher crack tip strain rate and faster crack growth rates. Future work will study the crack growth rates of 304W316L/316NG in various states of cold work and thermal treatment to evaluate the roles of phase stability, sensitization and creep relaxation on the

  19. Effect of Geobacter sulfurreducens on the microbial corrosion of mild steel, ferritic and austenitic stainless steels

    OpenAIRE

    Mehanna, Maha; Basséguy, Régine; Délia, Marie-Line; Bergel, Alain

    2009-01-01

    The influence of Geobacter sulfurreducens was tested on the anaerobic corrosion of four different steels: mild steel 1145, ferritic steel 403 and austenitic steels 304L and 316L. Within a few hours, the presence of cells induced a free potential (Eoc) ennoblement around +0.3 V on 1145 mild steel, 403 ferritic steel and 304L austenitic steels and slightly less on 316L. The kinetics of Eoc ennoblement depended on the amount of bacteria in the inoculum, but the final potential value depended ess...

  20. The comparison of frictional resistance in titanium, self-ligating stainless steel, and stainless steel brackets using stainless steel and TMA archwires: An in vitro study

    OpenAIRE

    Syed Altaf Khalid; Vadivel Kumar; Prithviraj Jayaram

    2012-01-01

    Aim: The aim of the study was to compare the frictional resistance of titanium, self-ligating stainless steel, and conventional stainless steel brackets, using stainless steel and titanium molybdenum alloy (TMA) archwires. Materials and Methods: We compared the frictional resistance in 0.018 slot and 0.022 slot of the three brackets - titanium, self-ligating stainless steel, and conventional stainless steel - using stainless steel archwires and TMA archwires. An in vitro study of simulated ca...

  1. Microbial corrosion of stainless steel.

    Science.gov (United States)

    Ibars, J R; Moreno, D A; Ranninger, C

    1992-11-01

    Stainless steel, developed because of their greater resistance to corrosion in different aggressive environments, have proved to be affected, however, by various processes and types of corrosion. Some of these types of corrosion, mainly pitting, is activated and developed in the presence of microorganisms, which acting in an isolated or symbiotic way, according to their adaptation to the environment, create a favorable situation for the corrosion of these steel. The microorganisms that are involved, mainly bacteria of both the aerobic and anaerobic type, modify the environment where the stainless steel is found, creating crevices, differential aeration zones or a more aggressive environment with the presence of metabolites. In these circumstances, a local break of the passive and passivating layer is produced, which is proper to these types of steel and impedes the repassivation that is more favorable to corrosion. In the study and research of these types of microbiologically influenced corrosion are found electrochemical techniques, since corrosion is fundamentally an electrochemical process, and microbiological techniques for the identification, culture, and evaluation of the microorganisms involved in the process, as well as in the laboratory or field study of microorganism-metal pairs. Microstructural characterization studies of stainless steel have also been considered important, since it is known that the microstructure of steel can substantially modify their behavior when faced with corrosion. As for surface analysis studies, it is known that corrosion is a process that is generated on and progresses from the surface. The ways of dealing with microbiologically influenced corrosion must necessarily include biocides, which are not always usable or successful, the design of industrial equipment or components that do not favor the adherence of microorganisms, using microstructures in steel less sensitive to corrosion, or protecting the materials. PMID:1492953

  2. Effect of heating rate on sintered series 300 stainless steel

    Directory of Open Access Journals (Sweden)

    Ornmanee Coovattanachai

    2010-05-01

    Full Text Available Stainless steel powders (303L, 304L, 310L and 316L were formed into tensile test bars using the “press and sinter”process. Most processing parameters, except heating rate, were kept constant. During the heating of the experimental specimensfrom 700°C to the sintering temperature of 1300°C, heating rates were varied, e.g., 2.5, 5.0, and 10.0°C/min. Experimentalresults showed that a material heated with a low heating rate tended to have higher sintered density and tensile strength.However, the low heating rate caused grain growth in the sintered material. These results are in contradiction with the improved densification of some ceramics by ultra rapid heating. The reasons for contradiction are as follows. First, the heatingrates employed in this work are not very different. The second is attributed to small thermal gradients generated in thethin metal powder compacts. Because of these reasons, densification of the sintered stainless steels series 300 is controlled by an isothermal condition. The low heating rate allows longer time for atomic diffusion, which is an important sintering factor. This means more atoms move to points of contact between powder particles to form necking and to cause neckinggrowth. This results in better sintering. However, the low heating rate means that the materials are exposed to heat for longertime and thus their grains have a tendency to grow.

  3. Nano-composite stainless steel

    Science.gov (United States)

    Dehoff, Ryan R.; Blue, Craig A.; Peter, William H.; Chen, Wei; Aprigliano, Louis F.

    2015-07-14

    A composite stainless steel composition is composed essentially of, in terms of wt. % ranges: 25 to 28 Cr; 11 to 13 Ni; 7 to 8 W; 3.5 to 4 Mo; 3 to 3.5 B; 2 to 2.5 Mn; 1 to 1.5 Si; 0.3 to 1.7 C; up to 2 O; balance Fe. The composition has an austenitic matrix phase and a particulate, crystalline dispersed phase.

  4. Porosity in millimeter-scale welds of stainless steel : three-dimensional characterization.

    Energy Technology Data Exchange (ETDEWEB)

    Aagesen, Larry K. (University of Michigan, Ann Arbor, MI); Madison, Jonathan D.

    2012-05-01

    A variety of edge joints utilizing a continuous wave Nd:YAG laser have been produced and examined in a 304-L stainless steel to advance fundamental understanding of the linkage between processing and resultant microstructure in high-rate solidification events. Acquisition of three-dimensional reconstructions via micro-computed tomography combined with traditional metallography has allowed for qualitative and quantitative characterization of weld joints in a material system of wide use and broad applicability. The presence, variability and distribution of porosity, has been examined for average values, spatial distributions and morphology and then related back to fundamental processing parameters such as weld speed, weld power and laser focal length.

  5. Reverse Transformation of Deformation-Induced Phases and Associated Changes in the Microstructure of Explosively Clad Ti-5Ta-2Nb and 304L SS

    Science.gov (United States)

    Prasanthi, T. N.; Sudha, C.; Murugesan, S.; Thomas Paul, V.; Saroja, S.

    2015-10-01

    Ti-5Ta-2Nb alloy was joined to 304L austenitic stainless steel by explosive cladding technique. Explosive cladding resulted in the formation of deformation-induced martensite in 304L SS and fcc phase of Ti in the Ti-5Ta-2Nb side of the joint. The stability of these metastable phases was systematically studied using high-temperature X-ray diffraction technique and transmission electron microscopy, which enabled the optimization of the temperature window for post-cladding heat treatments.

  6. Hot workability of duplex stainless steels

    OpenAIRE

    Martin, Guilhem

    2011-01-01

    The Duplex Stainless Steels (DSS) are defined as a family of stainless steels consisting of a two-phase microstructure involving δ-ferrite and γ-austenite. Exceptional combinations of strength and toughness together with good corrosion resistance under critical working conditions designate DSS a suitable alternative to conventional austenitic stainless steels. Unfortunately, the relatively poor hot workability of these alloys makes the industrial processing of flat products particularly criti...

  7. The resistance of austenitic stainless steels to pitting corrosion in simulated BFS/OPC pore waters containing thiosulphate ions

    International Nuclear Information System (INIS)

    Current plans for the disposal of intermediate-level nuclear waste involve the use of austenitic stainless steel drums. The immediate environment seen by both the inner and outer surfaces of these drums will be alkaline, as a consequence of the encasement of both the drum and its contents in concrete. Normally there would be no risk of localized corrosion of the steel in this situation, but a possible complication is introduced by the use of blast-furnace slag (BFS) to decrease the permeability of the concrete. Metal sulphides in the BFS react with air and water to yield thiosulphate ions, which are known to be corrosive towards stainless steels in environments of near-neutral pH. This research was carried out to study the effects of thiosulphate at alkaline pH, simulating the concrete environment. Types 304L and 316L stainless steel have been tested for pitting corrosion resistance in simulated BFS/Ordinary Portland Cement pore waters of pH 10-13, at 20oC and 50oC. The results show that the 316L steel is essentially immune to pitting. The 304L steel shows some pitting at the higher temperature, especially at the higher chloride concentrations, but only at pH values of less than 12, which would require serious deterioration of the cement matrix. (author)

  8. Effect of Hydrogen Charging on the Tensile and Constant Load Properties of an Austenitic Stainless Steel Weldment

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The effect of cathodic hydrogen charging on the tensile and constant load properties was determined for an austenitic stainless steel weldment comprising a 304L steel in the solution treated condition as a base metal and a 308L filler steel as a weld metal. Part of the 304L solution treated steel was separately given additional sensitization treatment to simulate the microstructure that would develop in the heat affected zone. Tests were performed at room temperature on notched round bar specimens. Hydrogen charging resulted in a pronounced embrittlement of the tested materials. This was manifested mainly as a considerable loss in the dluctility of tensile specimens and a decrease in the time to failure and threshold stress of constant load specimens. The 308L weld metal exhibited the highest, and the 304L solution treated steel the lowest, resistance to hydrogen embrittlement. Hydrogen embrittlement was associated with the formation of strain induced martensite as well as a transition from brittle to ductile fracture morphology onwards the centre of the specimens.

  9. Influence of plastic strain localization on the stress corrosion cracking of austenitic stainless steels; Influence de la localisation de la deformation plastique sur la CSC d'aciers austenitiques inoxydables

    Energy Technology Data Exchange (ETDEWEB)

    Cisse, S.; Tanguy, B. [CEA Saclay, DEN, SEMI, 91 - Gif-sur-Yvette (France); Andrieu, E.; Laffont, L.; Lafont, M.Ch. [Universite de Toulouse. CIRIMAT, UPS/INPT/CNRS, 31 - Toulous (France)

    2010-03-15

    The authors present a research study of the role of strain localization on the irradiation-assisted stress corrosion cracking (IASCC) of vessel steel in PWR-type (pressurized water reactor) environment. They study the interaction between plasticity and intergranular corrosion and/or oxidation mechanisms in austenitic stainless steels with respect to sublayer microstructure transformations. The study is performed on three austenitic stainless grades which have not been sensitized by any specific thermal treatment: the A286 structurally hardened steel, and the 304L and 316L austenitic stainless steels

  10. Brazing of stainless steel; Stainless ko no rozuke

    Energy Technology Data Exchange (ETDEWEB)

    Matsu, T.

    1996-04-01

    This paper explains brazing of stainless steel as to its processing materials, brazing materials, brazing methods, and brazing works. When performing brazing at higher than 800{degree}C on a martensite-based stainless steel represented by the 13Cr steel, attention is required on cracking caused by quenching. When a ferrite-based stainless steel represented by the 18Cr steel is heated above 900{degree}C, crystalline particles grow coarser, causing their tenacity and corrosion resistance to decline. High-temperature long-time heating in brazing in a furnace demands cautions. Austenite-based stainless steel represented by the 18Cr-8Ni steel has the best brazing performance. However, since the steel has large thermal expansion coefficient and low thermal conductivity, attention is required on strain and deformation due to heating, and on localized overheating. Deposition hardened stainless steel made of the Cr-Ni alloy steel added with aluminum and titanium has poor wettability in a brazing work, hence pretreatment is required for the purpose of activation. 9 figs., 7 tabs.

  11. Study of the Intercrystalline Corrosion in Pipes of Stainless Steel in a Combined Cycle

    Directory of Open Access Journals (Sweden)

    Raúl Andrés Montejo Serrano

    2014-09-01

    Full Text Available The present work is carried out with the purpose of giving answer to the possible presence ofintercrystalline corrosion and its future consequences in the built tubes of stainless steel 304L anddedicated to the conduction from the water to the boilers of a combined cycle of electricity production.The plant is these in this moments in installation of process investor and assembly and this study wasrequested since during the trial of installation of the pipes of stainless steel that will drive the watertried to the steam generators, they were detected on the part of the operatives some imperfections inthe material, what generated the doubt about the possibility of presence of intercrystalline corrosion orof another type in the pipes. After the realized rehearsals according to international norms and alsousing rehearsals metallography you concludes that the material employee is not sensitive to this typeof corrosion.

  12. Effects of postweld treatments on corrosion of stainless steel weldments in microbial fresh-water systems

    Energy Technology Data Exchange (ETDEWEB)

    Li, P.; Buchanan, R.A.; Lundin, C.D. [Univ. of Tennessee, Knoxville, TN (United States). Dept. of Materials Science and Engineering; Tuthill, A.H. [Tuthill Associates, Inc., Blacksburg, VA (United States); Avery, R.E. [Avery Consulting Associates, Inc., Londonderry, NH (United States); Angell, P. [Center for Environmental Biotechnology, Knoxville, TN (United States); Sachs, D.E. [Arizona Public Service Co., Phoenix, AZ (United States)

    1995-10-01

    Corrosion studies of 304L and 316L stainless steel weldments were conducted in natural and simulated fresh-water systems containing microorganisms. Experimental conditions were chosen to simulate microbiologically influenced corrosion (MIC) conditions in practical applications. Results showed that corrosion, with the formation of nodules, occurred at imposed crevice locations within weldment heat-tint areas. Upon removal of the heat tint, either chemically, electrochemically, or mechanically, corrosion nodules were not formed even under crevice conditions. Follow-up experiments indicated that the stainless steel weldments were less corrosion resistant in the bacterial environments. The results were correlated to the presence of the heat tint, the crevice geometry, the chloride concentration, and the bacterial activities.

  13. 24 h-corrosion tests combined with electrochemical potential measurements of CrNi-steel DIN W.Nr. 1.4306 (AISI Type 304 L) in 7 molar nitric acid containing oxidizing metal ions at 90deg C

    International Nuclear Information System (INIS)

    Corrosion experiments - combined with measurements of the free corrosion potential of the steels under test and the redox potential of the corrosive nitric acid media - have been performed. Three different versions of the austenitic CrNi steel DIN W.Nr. 1.4306 (AISI Type 304 L) in the solution annealed condition were tested at 90deg C during 24 h in nitric acid and nitric acid solutions containing single or combined additions of Fe(III)-, Cr(VI)- and Ce(IV)-ions. The relationship between the rate of metal loss and the free corrosion potential of the corroding steels was confirmed to be an exponential one. Furthermore, it was shown that these short-term tests could reveal within a narrow band of free corrosion potentials (1150-1250 mV) an extent of surface corrosion which is specific for small compositional or microstructural differences of these steels. (orig.)

  14. Interaction between stainless steel and plutonium metal

    Energy Technology Data Exchange (ETDEWEB)

    Dunwoody, John T [Los Alamos National Laboratory; Mason, Richard E [Los Alamos National Laboratory; Freibert, Franz J [Los Alamos National Laboratory; Willson, Stephen P [Los Alamos National Laboratory; Veirs, Douglas K [Los Alamos National Laboratory; Worl, Laura A [Los Alamos National Laboratory; Archuleta, Alonso [Los Alamos National Laboratory; Conger, Donald J [Los Alamos National Laboratory

    2010-01-01

    Long-term storage of excess plutonium is of great concern in the U.S. as well as abroad. The current accepted configuration involves intimate contact between the stored material and an iron-bearing container such as stainless steel. While many safety scenario studies have been conducted and used in the acceptance of stainless steel containers, little information is available on the physical interaction at elevated temperatures between certain forms of stored material and the container itself. The bulk of the safety studies has focused on the ability of a package to keep the primary stainless steel containment below the plutonium-iron eutectic temperature of approximately 410 C. However, the interactions of plutonium metal with stainless steel have been of continuing interest. This paper reports on a scoping study investigating the interaction between stainless steel and plutonium metal in a pseudo diffusion couple at temperatures above the eutectic melt-point.

  15. Stress corrosion cracking of austenitic stainless steel core internal welds.

    Energy Technology Data Exchange (ETDEWEB)

    Chung, H. M.; Park, J.-H.; Ruther, W. E.; Sanecki, J. E.; Strain, R. V.; Zaluzec, N. J.

    1999-04-14

    Microstructural analyses by several advanced metallographic techniques were conducted on austenitic stainless steel mockup and core shroud welds that had cracked in boiling water reactors. Contrary to previous beliefs, heat-affected zones of the cracked Type 304L, as well as 304 SS core shroud welds and mockup shielded-metal-arc welds, were free of grain-boundary carbides, which shows that core shroud failure cannot be explained by classical intergranular stress corrosion cracking. Neither martensite nor delta-ferrite films were present on the grain boundaries. However, as a result of exposure to welding fumes, the heat-affected zones of the core shroud welds were significantly contaminated by oxygen and fluorine, which migrate to grain boundaries. Significant oxygen contamination seems to promote fluorine contamination and suppress thermal sensitization. Results of slow-strain-rate tensile tests also indicate that fluorine exacerbates the susceptibility of irradiated steels to intergranular stress corrosion cracking. These observations, combined with previous reports on the strong influence of weld flux, indicate that oxygen and fluorine contamination and fluorine-catalyzed stress corrosion play a major role in cracking of core shroud welds.

  16. A temperature dependent slip factor based thermal model for friction stir welding of stainless steel

    Indian Academy of Sciences (India)

    M Selvaraj

    2013-12-01

    This paper proposes a new slip factor based three-dimensional thermal model to predict the temperature distribution during friction stir welding of 304L stainless steel plates. The proposed model employs temperature and radius dependent heat source to study the thermal cycle, temperature distribution, power required, the effect of process parameters on heat generation per mm length of the weld and peak temperature during the friction stir welding process. Simulations of friction stir welding process were carried out on 304L stainless steel workpieces for various rotational and welding speeds. The predicted thermal cycle, power required and temperature distributions were found to be in good agreement with the experimental results. The heat generation per mm length of weld and peak temperature were found to be directly proportional to rotational speed and inversely proportional to welding speed. The rate of increase in heat generation per mm length of the weld and peak temperature are found to be higher at lower rotational speeds and lower at higher rotational speed. The heat generation during friction stir welding was found to be 80.8 % at shoulder, 16.1 % at pin side and 3.1 % at the bottom of the pin.

  17. Corrosion behavior of powder metallurgical stainless steels in urban and marine environments

    Directory of Open Access Journals (Sweden)

    Bautista, A.

    2006-06-01

    Full Text Available This work studies the development of corrosive attack on sintered components manufactured from AISI 316L and AISI 304L powders. The stainless steels were sintered in vacuum and in nitrogen-base atmosphere at 1,120 and 1,250 ºC, and their corrosion resistance was then analyzed by electrochemical techniques and by atmospheric corrosion testing (two years at urban and marine test sites. Images are shown of the morphology of the attack on the surface of the stainless steels and the development of this attack in the interior of the material.

    Este trabajo estudia el desarrollo del proceso corrosivo en componentes sinterizados fabricados a partir de polvos de AISI 316L y AISI 304L. Los aceros inoxidables fueron sinterizados en vacío y en atmósfera base nitrógeno a 1.120 y 1.250 ºC y, su resistencia a corrosión se ha analizado mediante técnicas electroquímicas y mediante ensayos de corrosión atmosférica (dos años en ambientes urbano y marino. Se muestran imágenes de la morfología del ataque en la superficie de los aceros inoxidables y del desarrollo de este ataque en el interior del material.

  18. The microstructural, mechanical, and fracture properties of austenitic stainless steel alloyed with gallium

    Science.gov (United States)

    Kolman, D. G.; Bingert, J. F.; Field, R. D.

    2004-11-01

    The mechanical and fracture properties of austenitic stainless steels (SSs) alloyed with gallium require assessment in order to determine the likelihood of premature storage-container failure following Ga uptake. AISI 304 L SS was cast with 1, 3, 6, 9, and 12 wt pct Ga. Increased Ga concentration promoted duplex microstructure formation with the ferritic phase having a nearly identical composition to the austenitic phase. Room-temperature tests indicated that small additions of Ga (less than 3 wt pct) were beneficial to the mechanical behavior of 304 L SS but that 12 wt pct Ga resulted in a 95 pct loss in ductility. Small additions of Ga are beneficial to the cracking resistance of stainless steel. Elastic-plastic fracture mechanics analysis indicated that 3 wt pct Ga alloys showed the greatest resistance to crack initiation and propagation as measured by fatigue crack growth rate, fracture toughness, and tearing modulus. The 12 wt pct Ga alloys were least resistant to crack initiation and propagation and these alloys primarily failed by transgranular cleavage. It is hypothesized that Ga metal embrittlement is partially responsible for increased embrittlement.

  19. Effects of Cold Rolling and Strain-Induced Martensite Formation in a SAF 2205 Duplex Stainless Steel

    Science.gov (United States)

    Breda, Marco; Brunelli, Katya; Grazzi, Francesco; Scherillo, Antonella; Calliari, Irene

    2015-02-01

    Duplex stainless steels (DSSs) are biphasic steels having a ferritic-austenitic microstructure that allows them to combine good mechanical and corrosion-resistance properties. However, these steels are sensitive to microstructural modifications, such as ferrite decomposition at high temperatures and the possibility of strain-induced martensite (SIM) formation from cold-worked austenite, which can significantly alter their interesting features. In the present work, the effects of cold rolling on the developed microstructural features in a cold-rolled SAF 2205 DSS and the onset of martensitic transformation are discussed. The material was deformed at room temperature from 3 to 85 pct thickness reduction, and several characterization techniques (scanning and transmission electron microscopy, X-ray diffraction, hardness measurements, and time-of-flight-neutron diffraction) were employed in order to fully describe the microstructural behavior of the steel. Despite the low stacking fault energy of DSS austenite, which contributed to SIM formation, the steel was found to be more stable than other stainless steel grades, such as AISI 304L. Rolling textures were similar to those pertaining to single-phase materials, but the presence of the biphasic (Duplex) microstructure imposed deformation constraints that affected the developed microstructural features, owing to phases interactions. Moreover, even if an intensification of the strain field in austenite was revealed, retarded SIM transformation kinetics and lower martensite amounts with respect to AISI 304L were observed.

  20. Tensile and Fracture Properties of Circumferentially Notched Tensile Specimens of Stainless Steel Weldments

    International Nuclear Information System (INIS)

    The tensile and fracture properties of different types of austenitic stainless steel weldments were determined using round notched tensile specimens. These included 304L, 316L and 6%Mo super austenitic stainless steels and their weld metals. The triaxial state of stress, the plastic constraint and the plane strain conditions developed ahead of the notch root make notched specimens eligible for the evaluation of fracture toughness. This was achieved through the testing procedure: J-evaluation on tensile test (JETT) using circumferentially notched round bar specimens. The JETT index was taken as a measure of the relevant elastic-plastic fracture toughness of the tested materials. In the case of austenitic stainless steels being too ductile at room temperature the resulted JETT were of relatively higher values than the fracture toughness values determined from the standard fracture mechanics test methods. This could be related to the difference in the stress state ahead of the sharp crack of the standard fracture mechanics specimen and that of the blunt notch of the tensile specimen. The results showed that the 6% Mo weld metal ranked highest while the 316L weld metal ranked lowest regarding JETT fracture toughness values. The deformation mechanisms pertinent to austenitic stainless steels (generation of stacking faults and formation of strain induced martensite) were employed for the interpretation of the experimental results.

  1. Duplex stainless steels for osteosynthesis devices.

    Science.gov (United States)

    Cigada, A; Rondelli, G; Vicentini, B; Giacomazzi, M; Roos, A

    1989-09-01

    The austenitic stainless steels used today for the manufacture of osteosynthesis devices are sensitive to crevice corrosion. In this study the corrosion properties of some duplex stainless steels were evaluated and compared to traditional austenitic stainless steels. According to our results the following ranking was established: 23Cr-4Ni less than AISI 316L less than ASTM F138 less than 22Cr-5Ni-3Mo less than 27Cr-31Ni-3.5Mo less than 25Cr-7Ni-4Mo-N. In particular the results showed that the high-performance 25Cr-7Ni-4Mo-N duplex stainless steel, with high molybdenum and nitrogen contents, can be considered not susceptible to crevice corrosion in the human body. The duplex stainless steels have also better mechanical properties at the same degree of cold working compared with austenitic stainless steels. Hence the 25Cr-7Ni-4Mo-N duplex stainless steel can be considered a convenient substitute of ASTM F138 for orthopedic and osteosynthesis devices. PMID:2777835

  2. Preparation of precursor for stainless steel foam

    Institute of Scientific and Technical Information of China (English)

    ZHOU Xiang-yang; LI Shan-ni; LI Jie; LIU Ye-xiang

    2008-01-01

    The effects of polyurethane sponge pretreatment and slurry compositions on the slurry loading in precursor were discussed, and the,performances of stainless steel foams prepared from precursors with different slurry loadings and different particle sizes of the stainless steel powder were also investigated. The experimental results show that the pretreatment of sponge with alkaline solution is effective to reduce the jam of cells in precursor and ensure the slurry to uniformly distribute in sponge, and it is also an effective method for increasing the slurry loading in precursor; the mass fraction of additive A and solid content in slurry greatly affect the slurry loading in precursor, when they are kept in 9%-13% and 52%-75%, respectively, the stainless steel foam may hold excellent 3D open-cell network structure and uniform muscles; the particle size of the stainless steel powder and the slurry loading in precursor have great effects on the bending strength, apparent density and open porosity of stainless steel foam; when the stainless steel powder with particle size of 44 tan and slurry loading of 0.5 g/cm3 in precursor are used, a stainless steel foam can be obtained, which has open porosity of 81.2%, bending strength of about 51.76 MPa and apparent density of about 1.0 g/cm3.

  3. Recycle of radiologically contaminated austenitic stainless steels

    International Nuclear Information System (INIS)

    The United States Department of Energy owns large quantities of radiologically contaminated austenitic stainless steel which could by recycled for reuse if appropriate release standards were in place. Unfortunately, current policy places the formulation of a release standard for USA industry years, if not decades, away. The Westinghouse Savannah River Company, Idaho National Engineering Laboratory and various university and industrial partners are participating in initiative to recycle previously contaminated austenitic stainless steels into containers for the storage and disposal of radioactive wastes. This paper describes laboratory scale experiments which demonstrated the decontamination and remelt of stainless steel which had been contaminated with radionuclides

  4. Behaviour comparison of various flux cored wires in FCAW on austenitic stainless steel

    International Nuclear Information System (INIS)

    This study deals with the GMAW process evaluation for the orbital butt welding of strong thickness pipings, in order to increase the productivity of these operations (higher deposition rate than in GTAW, process currently used). The main goal of this project is to evaluate the operational feasibility of mechanized orbital welding under gas protection in narrow gap with stainless flux cored wire 308L on stainless steel 304L. The study was composed of two parts with firstly a bibliographical research which has allowed to underline this operation practice, as good with rutile flux cored wire in smooth mode as with metal cored wire in pulsed mode. In the second part, flat and in position welding tests, by unit cords and filling of narrow grooves, made possible to define preliminary welding parameters. (author)

  5. Impact Tensile Testing of Stainless Steels at Various Temperatures

    Energy Technology Data Exchange (ETDEWEB)

    D. K. Morton

    2008-03-01

    Stainless steels are used for the construction of numerous spent nuclear fuel or radioactive material containers that may be subjected to high strains and moderate strain rates during accidental drop events. Mechanical characteristics of these base materials and their welds under dynamic loads in the strain rate range of concern (1 to 300 per second) are not well documented. However, research is being performed at the Idaho National Laboratory to quantify these characteristics. The work presented herein discusses tensile impact testing of dual-marked 304/304L and 316/316L stainless steel material specimens. Both base material and welded material specimens were tested at -20 oF, room temperature, 300 oF, and 600 oF conditions. Utilizing a drop weight impact test machine and 1/4-inch and 1/2-inch thick dog bone-shaped test specimens, a strain rate range of approximately 4 to 40 per second (depending on initial temperature conditions) was achieved. Factors were determined that reflect the amount of increased strain energy the material can absorb due to strain rate effects. Using the factors, elevated true stress-strain curves for these materials at various strain rates and temperatures were generated. By incorporating the strain rate elevated true stress-strain material curves into an inelastic finite element computer program as the defined material input, significant improvement in the accuracy of the computer analyses was attained. However, additional impact testing is necessary to achieve higher strain rates (up to 300 per second) before complete definition of strain rate effects can be made for accidental drop events and other similar energy-limited impulsive loads. This research approach, using impact testing and a total energy analysis methodology to quantify strain rate effects, can be applied to many other materials used in government and industry.

  6. Stainless Steel to Titanium Bimetallic Transitions

    Energy Technology Data Exchange (ETDEWEB)

    Kaluzny, J. A. [Fermilab; Grimm, C. [Fermilab; Passarelli, D. [Fermilab

    2015-01-01

    In order to use stainless steel piping in an LCLS-II (Linac Coherent Light Source Upgrade) cryomodule, stainless steel to titanium bimetallic transitions are needed to connect the stainless steel piping to the titanium cavity helium vessel. Explosion bonded stainless steel to titanium transition pieces and bimetallic transition material samples have been tested. A sample transition tube was subjected to tests and x-ray examinations between tests. Samples of the bonded joint material were impact and tensile tested at room temperature as well as liquid helium temperature. The joint has been used successfully in horizontal tests of LCLS-II cavity helium vessels and is planned to be used in LCLS-II cryomodules. Results of material sample and transition tube tests will be presented.

  7. Hydrogen compatibility handbook for stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Caskey, G.R. Jr.

    1983-06-01

    This handbook compiles data on the effects of hydrogen on the mechanical properties of stainless steels and discusses this data within the context of current understanding of hydrogen compatibility of metals. All of the tabulated data derives from continuing studies of hydrogen effects on materials that have been conducted at the Savannah River Laboratory over the past fifteen years. Supplementary data from other sources are included in the discussion. Austenitic, ferritic, martensitic, and precipitation hardenable stainless steels have been studied. Damage caused by helium generated from decay of tritium is a distinctive effect that occurs in addition to the hydrogen isotopes protium and deuterium. The handbook defines the scope of our current knowledge of hydrogen effects in stainless steels and serves as a guide to selection of stainless steels for service in hydrogen.

  8. Horizontal electron beam welding for stainless steels

    International Nuclear Information System (INIS)

    Stainless steel samples have been realized by local vacuum apparatus for electron beam welding applications to reactor core shell realizations. The best welding parameters have been determined by a systematic study. The welds have been characterized by mechanical tests

  9. A Duplex Stainless Steel for Chloride Environments

    Science.gov (United States)

    Sridhar, N.; Kolts, J.; Flasche, L. H.

    1985-03-01

    This paper examines the effects of microstructural changes on the corrosion, stress corrosion cracking and corrosion fatigue resistance of a duplex stainless steel to chloride environments. The microstructural changes can be precipitation of phases such as sigma and carbides, or changes in the distribution of austenite and ferrite. The former can be important in hot forming operations while the latter is important in welding. The methods of minimizing these deleterious effects can sometimes be different from those used for austenitic stainless steel.

  10. Studies of stainless steel exposed to sandblasting

    OpenAIRE

    Horodek Paweł; Eseev Marat K.; Kobets Andrey G.

    2015-01-01

    The influence of sandblasting on surface and subsurface of stainless steel is investigated using variable energy positron beam (VEP), positron annihilation spectroscopy (PAS), scanning electron microscopy (SEM), and atomic force microscopy (AFM). Samples of stainless steel were blasted using 110 μm particles of Al2O3 under different pressure and time duration. In the case of sandblasting for 90 s, the reduction of positron diffusion length depending on the applied pressure was observed. Sandb...

  11. Fracture toughness properties of duplex stainless steels

    OpenAIRE

    Sieurin, Henrik

    2006-01-01

    Good toughness properties in base and weld material enable the use of duplex stainless steels (DSS) in critical applications. DSS offer high strength compared to common austenitic stainless steels. The high strength can be utilized to reduce the wall thickness and accordingly accomplish reduction of cost, welding time and transportation weight, contributing to ecological and energy savings. Although DSS have been used successfully in many applications the last decades, the full utilisation in...

  12. Phase transformations in welded supermartensitic stainless steels

    OpenAIRE

    Carrouge, Dominique

    2002-01-01

    Supermartensitic stainless steels have recently been introduced in the oil and gas industries to substitute more expensive duplex stainless steels for onshore and offshore tubing applications. Although easily joined by arc welding processes, the service life of the supermartensitic welded joint in corrosive environments relies to a large extent on the behaviour of the heat-affected zone (HAZ). The microstructure of the HAZ in these new materials has, until now, received little ...

  13. Effect of Geobacter sulfurreducens on the microbial corrosion of mild steel, ferritic and austenitic stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Mehanna, Maha [Laboratoire de Genie Chimique, CNRS - Universite de Toulouse, 5 rue Paulin Talabot, BP1301, 31029 Toulouse (France)], E-mail: mum34@psu.edu; Basseguy, Regine; Delia, Marie-Line; Bergel, Alain [Laboratoire de Genie Chimique, CNRS - Universite de Toulouse, 5 rue Paulin Talabot, BP1301, 31029 Toulouse (France)

    2009-11-15

    The influence of Geobacter sulfurreducens was tested on the anaerobic corrosion of four different steels: mild steel 1145, ferritic steel 403 and austenitic steels 304L and 316L. Within a few hours, the presence of cells induced a free potential (E{sub oc}) ennoblement around +0.3 V on 1145 mild steel, 403 ferritic steel and 304L austenitic steels and slightly less on 316L. The kinetics of E{sub oc} ennoblement depended on the amount of bacteria in the inoculum, but the final potential value depended essentially on the nature of the material. This effect was due to the capacity of G. sulfurreducens to create a direct cathodic reaction on steel surfaces, extracting the electrons directly from material. The presence of bacterial cells modified the corrosion features of mild steel and ferritic steel, so that corrosion attacks were gathered in determined zones of the surface. Local corrosion was significantly enhanced on ferritic steel. Potential ennoblement was not sufficient to induce corrosion on austenitic steels. In contrast G. sulfurreducens delayed the occurrence of pitting on 304L steel because of its capability to oxidize acetate at high potential values. The electrochemical behaviour of 304L steel was not affected by the concentration of soluble electron donor (acetate, 1-10 mM) or the amount of planktonic cells; it was directly linked to the biofilm coverage. After polarization pitting curves had been recorded, microscopic observations showed that pits propagated only in the surface zones where cell settlement was the densest. The study evidenced that Geobacter sulfurreducens can control the electrochemical behaviour of steels in complex ways that can lead to severe corrosion. As Geobacteraceae are ubiquitous species in sediments and soils they should now be considered as possible crucial actors in the microbial corrosion of buried equipment.

  14. Effect of Geobacter sulfurreducens on the microbial corrosion of mild steel, ferritic and austenitic stainless steels

    International Nuclear Information System (INIS)

    The influence of Geobacter sulfurreducens was tested on the anaerobic corrosion of four different steels: mild steel 1145, ferritic steel 403 and austenitic steels 304L and 316L. Within a few hours, the presence of cells induced a free potential (Eoc) ennoblement around +0.3 V on 1145 mild steel, 403 ferritic steel and 304L austenitic steels and slightly less on 316L. The kinetics of Eoc ennoblement depended on the amount of bacteria in the inoculum, but the final potential value depended essentially on the nature of the material. This effect was due to the capacity of G. sulfurreducens to create a direct cathodic reaction on steel surfaces, extracting the electrons directly from material. The presence of bacterial cells modified the corrosion features of mild steel and ferritic steel, so that corrosion attacks were gathered in determined zones of the surface. Local corrosion was significantly enhanced on ferritic steel. Potential ennoblement was not sufficient to induce corrosion on austenitic steels. In contrast G. sulfurreducens delayed the occurrence of pitting on 304L steel because of its capability to oxidize acetate at high potential values. The electrochemical behaviour of 304L steel was not affected by the concentration of soluble electron donor (acetate, 1-10 mM) or the amount of planktonic cells; it was directly linked to the biofilm coverage. After polarization pitting curves had been recorded, microscopic observations showed that pits propagated only in the surface zones where cell settlement was the densest. The study evidenced that Geobacter sulfurreducens can control the electrochemical behaviour of steels in complex ways that can lead to severe corrosion. As Geobacteraceae are ubiquitous species in sediments and soils they should now be considered as possible crucial actors in the microbial corrosion of buried equipment.

  15. High Mn austenitic stainless steel

    Science.gov (United States)

    Yamamoto, Yukinori [Oak Ridge, TN; Santella, Michael L [Knoxville, TN; Brady, Michael P [Oak Ridge, TN; Maziasz, Philip J [Oak Ridge, TN; Liu, Chain-tsuan [Knoxville, TN

    2010-07-13

    An austenitic stainless steel alloy includes, in weight percent: >4 to 15 Mn; 8 to 15 Ni; 14 to 16 Cr; 2.4 to 3 Al; 0.4 to 1 total of at least one of Nb and Ta; 0.05 to 0.2 C; 0.01 to 0.02 B; no more than 0.3 of combined Ti+V; up to 3 Mo; up to 3 Co; up to 1W; up to 3 Cu; up to 1 Si; up to 0.05 P; up to 1 total of at least one of Y, La, Ce, Hf, and Zr; less than 0.05 N; and base Fe, wherein the weight percent Fe is greater than the weight percent Ni, and wherein the alloy forms an external continuous scale including alumina, nanometer scale sized particles distributed throughout the microstructure, the particles including at least one of NbC and TaC, and a stable essentially single phase FCC austenitic matrix microstructure that is essentially delta-ferrite-free and essentially BCC-phase-free.

  16. Review on research and application of stainless steel reinforced concrete

    OpenAIRE

    Gu Li; Meng Xian Hong

    2016-01-01

    For ordinary reinforced under corrosion environment corrosion problems and analysis the main factors affecting ordinary steel corrosion, proposed stainless steel bar rust and corrosion resistance advantages, introduce the related properties of the stainless steel reinforced, combined with the research status of domestic and international stainless steel bar, put forward the research and engineering application of stainless steel rebar for the related problems and direction, the prospects and ...

  17. Compatibility of different stainless steels in molten Pb-Bi eutectic at high temperatures

    International Nuclear Information System (INIS)

    Advanced nuclear reactors and the accelerator driven subcritical (ADS) system require the structural materials to be in contact with the molten metals/lead-bismuth eutectic at 400 degC and higher temperatures. One of the primary concerns in using the molten lead-bismuth eutectic (LBE) as a coolant in the primary circuit of these systems is the degradation of structural materials in contact with LBE. An experimental setup has been fabricated to expose the materials in the molten LBE at high temperatures in stagnant condition under inert atmosphere. Samples from five different stainless steels (types 304L, 316L, 403, duplex SS SAF 2205 and super austenitic SS 2RK65) were exposed in this setup at 450 degC for 200h and at 500 degC for 600 and 2100 h under argon atmosphere. A different setup was prepared in which type 316L SS tube in the as-welded condition was exposed in molten LBE at 500 degC for 1200 h in rotating condition. All the samples showed formation of oxide on their surfaces. The thickness and compositional profiles of these oxides analyzed by EPMA confirmed formation of a double layer oxide on type 316L SS. The oxide thickness was highest on SS 403, while it was lowest on 304L and 316L SS. SEM results showed dissolution of materials at the surface in Sandvik 2RK65 and preferential dissolution of austenite phase in duplex SS. None of the stainless steels, except the duplex and the super austenitic stainless steels, showed any localized or selective corrosion. The composition of LBE before and after the exposure tests was analyzed by XRF technique. The result showed presence of Fe, Cr and Ni in the used LBE but these elements were not present in the virgin Pb-Ei alloy. This showed that the corrosion of stainless steels in LBE at temperatures upto 500 degC is due to oxidation and dissolution of alloying elements through the oxide on stainless steels. (author)

  18. Radiation-induced sensitisation of stainless steels

    International Nuclear Information System (INIS)

    The book contains the proceedings of a symposium on radiation-induced sensitization of stainless steels, which took place at Berkeley, United Kingdom, 1986. The purpose of the symposium was to examine the mechanism leading to inter-granular corrosion of 20%Cr/25% Ni/Nb stainless steel cladding of AGR fuel following irradiation. Nine papers are presented, of which three are theoretical, two papers are based upon corrosion studies of 20%Cr/25%Ni/Nb steel, and the remaining are concerned with compositional redistribution and its measurement. (U.K.)

  19. Corrosion behavior of sensitized duplex stainless steel.

    Science.gov (United States)

    Torres, F J; Panyayong, W; Rogers, W; Velasquez-Plata, D; Oshida, Y; Moore, B K

    1998-01-01

    The present work investigates the corrosion behavior of 2205 duplex stainless steel in 0.9% NaCl solution after various heat-treatments, and compares it to that of 316L austenitic stainless steel. Both stainless steels were heat-treated at 500, 650, and 800 degrees C in air for 1 h, followed by furnace cooling. Each heat-treated sample was examined for their microstructures and Vickers micro-hardness, and subjected to the X-ray diffraction for the phase identification. Using potentiostatic polarization method, each heat-treated sample was corrosion-tested in 37 degrees C 0.9% NaCl solution to estimate its corrosion rate. It was found that simulated sensitization showed an adverse influence on both steels, indicating that corrosion rates increased by increasing the sensitization temperatures. PMID:9713683

  20. Corrosion Performance of Rosemary-Extract-Doped TEOS:TMSM Sol-Gel Coatings on 304L Stainless Steel

    OpenAIRE

    M. Nasr-Esfahani; M. Pourriahi; A. Ashrafi; A. Motalebi

    2014-01-01

    Чистые и легированные экстрактом розмарина гибридные наноразмерные пленки были изготовлены с применением золя, синтезированного гидролизом и тетраэтоксисилана в молярном соотношении 1:1, с добавлением экстракта розмарина. Пленки осаждалисьна подложку из нержавеющей стали марки 304Lметодом центрифугирования и выдерживались при комнатной температуре в течение 24 часов, с последующим определением характеристик коррозии. Структура, состав и прочность сцепления (адгезии) гибридных пленок, полученн...

  1. Properties of high-frequency sub-wavelength ripples on stainless steel 304L under ultra short pulse laser irradiation

    NARCIS (Netherlands)

    Mitko, V.S.; Röer, G.R.B.E.; Huis in 't veld, A.J.; Skolski, J.Z.P.; Obona, J.V.; Ocelík, V.; Hosson, J.T.M.de

    2011-01-01

    The paper concentrates on surface texturing on sub-micro meter scale with ultra short laser pulses that has several applications, e.g. changing the hydrophilic/hydrophobic performance, optical or tribological properties of materials. In general, the formations of wavy structures, or ripples on a sur

  2. Properties of High-Frequency Sub-Wavelength Ripples on Stainless Steel 304L under Ultra Short Pulse Laser Irradiation

    NARCIS (Netherlands)

    Mitko, V.S.; Römer, G.R.B.E.; Huis in ‘t Veld, A.J.; Skolski, J.Z.P.; Obona, J.V.; Ocelík, V.; Hosson, J.T.M. De

    2011-01-01

    The paper concentrates on surface texturing on sub-micro meter scale with ultra short laser pulses that has several applications, e.g. changing the hydrophilic/hydrophobic performance, optical or tribological properties of materials. In general, the formations of wavy structures, or ripples on a sur

  3. Ultrasonic stress evaluation through thickness of a stainless steel pressure vessel

    International Nuclear Information System (INIS)

    This paper investigates ultrasonic method in stress measurement through thickness of a pressure vessel. Longitudinal critically refracted (LCR) waves are employed to measure the welding residual stresses in a vessel constructed from austenitic stainless steel 304L. The acoustoelastic constant is measured through a hydro test to keep the pressure vessel intact. Hoop and axial residual stresses are evaluated by using different frequency range of ultrasonic transducers. The welding processes of vessel shell and caps are simulated by a 3D finite element (FE) model which is validated by hole-drilling method. The residual stresses calculated by FE simulation are then compared with those obtained from the ultrasonic measurement while a good agreement is observed. It is demonstrated that the residual stresses through thickness of the stainless steel pressure vessel can be evaluated by combining FE and LCR method (known as FELCR method). - Highlights: • The main goal is ultrasonic evaluation of through thickness stresses. • Welding processes of a stainless steel pressure vessel are modelled by FE. • The hole-drilling method is used to validate the FE results. • Residual stresses are measured by four different series of ultrasonic transducers. • The comparison between ultrasonic and FE results show an acceptable agreement

  4. Aging degradation of cast stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Chopra, O.K.; Chung, H.M.

    1985-10-01

    A program is being conducted to investigate the significance of in-service embrittlement of cast-duplex stainless steels under light-water reactor operating conditions. Data from room-temperature Charpy-impact tests for several heats of cast stainless steel aged up to 10,000 h at 350, 400, and 450/sup 0/C are presented and compared with results from other studies. Microstructures of cast-duplex stainless steels subjected to long-term aging either in the laboratory or in reactor service have been characterized. The results indicate that at least two processes contribute to the low-temperature embrittleent of duplex stainless steels, viz., weakening of the ferrite/austenite phase boundary by carbide precipitation and embrittlement of ferrite matrix by the formation of additional phases such as G-phase, Type X, or the ..cap alpha..' phase. Carbide precipitation has a significant effect on the onset of embrittlement of CF-8 and -8M grades of stainless steels aged at 400 or 450/sup 0/C. The existing correlations do not accurately represent the embrittlement behavior over the temperature range 300 to 450/sup 0/C. 18 refs., 13 figs.

  5. Aging degradation of cast stainless steel

    International Nuclear Information System (INIS)

    A program is being conducted to investigate the significance of in-service embrittlement of cast-duplex stainless steels under light-water reactor operating conditions. Data from room-temperature Charpy-impact tests for several heats of cast stainless steel aged up to 10,000 h at 350, 400, and 4500C are presented and compared with results from other studies. Microstructures of cast-duplex stainless steels subjected to long-term aging either in the laboratory or in reactor service have been characterized. The results indicate that at least two processes contribute to the low-temperature embrittleent of duplex stainless steels, viz., weakening of the ferrite/austenite phase boundary by carbide precipitation and embrittlement of ferrite matrix by the formation of additional phases such as G-phase, Type X, or the α' phase. Carbide precipitation has a significant effect on the onset of embrittlement of CF-8 and -8M grades of stainless steels aged at 400 or 4500C. The existing correlations do not accurately represent the embrittlement behavior over the temperature range 300 to 4500C. 18 refs., 13 figs

  6. Experimental investigation of the residual stresses of 304L tubular welded joints; Caracterisation des contraintes residuelles sur assemblages soudes tubulaires en acier 304L

    Energy Technology Data Exchange (ETDEWEB)

    Monin, L.; Panier, S.; Hariri, S.; Zakrzewski, D. [Ecole des Mines de Douai, 941, rue Charles Bourseul, BP 10838, 59508 DOUAI Cedex (France); Faidi, C. [EDF-SEPTEN, 12-14, avenue Dutrievoz, 69628 VILLEURBANNE (France)

    2007-07-01

    In the nuclear energy industry, the use of components made of austenitic stainless steel is widely spread, because of its specific thermal properties. The assembly of these pressure vessels and piping by welding processes often requires surface mechanical operations. These operations aim at hardening surfaces and lowering roughness. Nevertheless the main effect of these operations is the occurrence of residual stresses which can have positive or negative effects on the fatigue life. In this study, we focus on the evaluation and relaxation of residual stresses level on AISI 304L austenitic stainless steel tubular welded structures. Some of these rings are base metal rings (which stand as reference), the rest presents a longitudinal and symmetrical Y-weld joint, with or without grinding. Surface residual stresses, and their relaxation, were determined by using the X-ray diffraction method. (authors) [French] L'utilisation de composants en acier inoxydable austenitique, aux proprietes thermiques bien specifiques, est tres courante dans le domaine de la production d'energie nucleaire. Les procedes d'assemblage par soudage de ces equipements sous pression requierent des traitements de parachevement mecanique afin d'ameliorer l'etat de surface et modifier l'etat mecanique en introduisant des contraintes residuelles, qui peuvent avoir une influence sur la duree de vie de la structure. Cette etude porte sur la caracterisation et la relaxation des contraintes residuelles, determinees sur des eprouvettes annulaires specifiques en acier inoxydable austenitique de type 304L, a l'etat brut ou avec des soudures, arasees ou non. La methode de determination utilisee est la diffraction des rayons X. La relaxation de ces contraintes au cours d'essais de fatigue est egalement etudiee. (auteurs)

  7. HTPro: Low-temperature Surface Hardening of Stainless Steel

    DEFF Research Database (Denmark)

    Christiansen, Thomas Lundin; Somers, Marcel A. J.

    2013-01-01

    Low-temperature surface hardening of stainless steel provides the required performance properties without affecting corrosion resistance.......Low-temperature surface hardening of stainless steel provides the required performance properties without affecting corrosion resistance....

  8. Low temperature gaseous surface hardening of stainless steel

    DEFF Research Database (Denmark)

    Christiansen, Thomas; Somers, Marcel A. J.

    2010-01-01

    The present contribution gives an overview of some of the technological aspects of low temperature thermochemical treatment of stainless steel. Examples of low temperature gaseous nitriding, carburising and nitrocarburising of stainless steel are presented and discussed. In particular, the...

  9. Low temperature gaseous surface hardening of stainless steel

    DEFF Research Database (Denmark)

    Christiansen, Thomas; Somers, Marcel A. J.

    2011-01-01

    The present contribtion gives an overview of some of the technological aspects of low temperature thermochemical treatment of stainless steel. Examples of low temperature gaseous nitriding, carburising and nitrocarburising of stainless steel are presented and discussed. In particular, the...

  10. Ultrasonic Spectroscopy of Stainless Steel Sandwich Panels

    Science.gov (United States)

    Cosgriff, Laura M.; Lerch, Bradley A.; Hebsur, Mohan G.; Baaklini, George Y.; Ghosn, Louis J.

    2003-01-01

    Enhanced, lightweight material systems, such as 17-4PH stainless steel sandwich panels are being developed for use as fan blades and fan containment material systems for next generation engines. In order to improve the production for these systems, nondestructive evaluation (NDE) techniques, such as ultrasonic spectroscopy, are being utilized to evaluate the brazing quality between the 17-4PH stainless steel face plates and the 17-4PH stainless steel foam core. Based on NDE data, shear tests are performed on sections representing various levels of brazing quality from an initial batch of these sandwich structures. Metallographic characterization of brazing is done to corroborate NDE findings and the observed shear failure mechanisms.

  11. Phosphate coating on stainless steel 304 sensitized

    International Nuclear Information System (INIS)

    The stainless steel 304 can be sensitized when welding processes are applied, that causes the precipitation of chromium carbide in the grain limits, being promoted in this way the formation of galvanic cells and consequently the corrosion process. Using a phosphate coating is possible to retard the physiochemical damages that can to happen in the corrosion process. The stainless steel 304 substrate sensitized it is phosphate to base of Zn-Mn, in a immersion cell very hot. During the process was considered optimization values, for the characterization equipment of X-rays diffraction and scanning electron microscopy was used. The XRD technique confirmed the presence of the phases of manganese phosphate, zinc phosphate, as well as the phase of the stainless steel 304. When increasing the temperature from 60 to 90 C in the immersion process a homogeneous coating is obtained. (Author)

  12. Initial oxidation of duplex stainless steel 2205

    Energy Technology Data Exchange (ETDEWEB)

    Donik, E.; Kocijan, A.; Jenko, M. [Institute of metals and technology, Ljubljana (Slovenia)

    2009-07-01

    Due to superior mechanical and corrosion properties of duplex stainless steels which result in weight reduction of the constructions, thus contributing to the decreases in total costs and also due to the large and versatile usage of the alloy, duplex stainless steel is gradually displacing stainless steels of the AISI 300 series. Pickling of duplex stainless steel has proven to be much more difficult than that of standard austenitic grade (AISI 300 series). There is no complete agreement in the literature on scale (high temperature oxidation) dissolution mechanism in neutral pickling solutions. During annealing, duplex stainless steel is heated in annealing furnace up to 1050 C and is kept at this temperature for some time to soften the metal in order to release the work hardening induced by hot and cold rolling. The elimination of surface defects by forming the oxide scale is required to improve the corrosion resistance. Three different techniques were used to produce thin oxide layers on polished and sputter cleaned duplex stainless steel samples. They were exposed to 10{sup -5} mb pure oxygen inside the vacuum chamber, exposed to ambient conditions for 24 hours and plasma oxidized. Oxide layers thus produced were analysed using XPS depth profiling for determination of the oxide layer's composition with depth. It was found that all techniques produce oxide layer with different traces of metallic components and with chromium oxide maximum concentration shifted towards the oxide layer - bulk metal interface. Depletion of Cr in bulk immediately below the interface was also observed. Simplified ARXPS procedure was used to corroborate thickness estimates for thinnest oxide layers. (authors)

  13. Stainless Steel Microstructure and Mechanical Properties Evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Switzner, Nathan T

    2010-06-01

    A nitrogen strengthened 21-6-9 stainless steel plate was spinformed into hemispherical test shapes. A battery of laboratory tests was used to characterize the hemispheres. The laboratory tests show that near the pole (axis) of a spinformed hemisphere the yield strength is the lowest because this area endures the least “cold-work” strengthening, i.e., the least deformation. The characterization indicated that stress-relief annealing spinformed stainless steel hemispheres does not degrade mechanical properties. Stress-relief annealing reduces residual stresses while maintaining relatively high mechanical properties. Full annealing completely eliminates residual stresses, but reduces yield strength by about 30%.

  14. Measuring secondary phases in duplex stainless steels

    Science.gov (United States)

    Calliari, I.; Brunelli, K.; Dabalà, M.; Ramous, E.

    2009-01-01

    The use of duplex stainless steels is limited by their susceptibility to the formation of dangerous intermetallic phases resulting in detrimental effects on impact toughness and corrosion resistance. This precipitation and the quantitative determinations of the phases have received considerable attention and different precipitation sequences (σ phase, χ phase, and carbides) have been suggested. This study investigates the phase transformation during continuous cooling and isothermal treatments in commercial duplex stainless steel grades and the effects on alloy properties, and compares the most common techniques of analysis.

  15. Embrittlement of austenitic stainless steel welds

    International Nuclear Information System (INIS)

    To prevent hot-cracking, austenitic stainless steel welds generally contain a small percent of delta ferrite. Although ferrite has been found to effectively prevent hot-cracking, it can lead to embrittlement of welds when exposed to elevated temperatures. The aging behavior of type-308 stainless steel weld has been examined over a range of temperatures 475--850 C for times up to 10,000 hrs. Upon aging, and depending on the temperature range, the unstable ferrite may undergo a variety of solid state transformations. These phase changes creep-rupture and Charpy impact properties

  16. 21 CFR 878.4495 - Stainless steel suture.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Stainless steel suture. 878.4495 Section 878.4495...) MEDICAL DEVICES GENERAL AND PLASTIC SURGERY DEVICES Surgical Devices § 878.4495 Stainless steel suture. (a) Identification. A stainless steel suture is a needled or unneedled nonabsorbable surgical suture composed of...

  17. 21 CFR 872.3350 - Gold or stainless steel cusp.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Gold or stainless steel cusp. 872.3350 Section 872...) MEDICAL DEVICES DENTAL DEVICES Prosthetic Devices § 872.3350 Gold or stainless steel cusp. (a) Identification. A gold or stainless steel cusp is a prefabricated device made of austenitic alloys or...

  18. Effects of δ-ferrite and welding structure on high-cycle fatigue properties of austenitic stainless steels weld metals

    International Nuclear Information System (INIS)

    We studied the effects of δ-ferrite and welding structure on high-cycle fatigue properties for austenitic stainless steel weld metals at cryogenic temperatures. SUS304L and SUS316L weld metals contained 0% δ-ferrite (0% material) and 10% δ-ferrite (10% material) were prepared. High-cycle fatigue tests were carried out at 293, 77 and 4 K. The S-N curves of those weld metals shifted towards higher stress levels, i.e., the longer life side, with decreasing test temperature. The ratios of 106-cycles fatigue strength (FS) to tensile strength (TS) of 0% material decreased from 0.8 to 0.45 and those of 10% material decreased between 0.35 to 0.65 with decreasing test temperature. Fatigue crack initiation sites of SUS304L 10% material were almost at blowholes, and those of SUS316L 10% material were at weld pass interface boundaries. On the other hand, those of 0% materials were considered to be due to the interface of the solidification structure. Although δ-ferrite reduces toughness at cryogenic temperatures in austenitic stainless steel weld metals, the effects of δ-ferrite on high-cycle fatigue properties are not significant

  19. Thermal fatigue of austenitic stainless steel: influence of surface conditions through a multi-scale approach

    International Nuclear Information System (INIS)

    Some cases of cracking of 304L austenitic stainless steel components due to thermal fatigue were encountered in particular on the Residual Heat Removal Circuits (RHR) of the Pressurized Water Reactor (PWR). EDF has initiated a R and D program to understand assess the risks of damage on nuclear plant mixing zones. The INTHERPOL test developed at EDF is designed in order to perform pure thermal fatigue test on tubular specimen under mono-frequency thermal load. These tests are carried out under various loadings, surface finish qualities and welding in order to give an account of these parameters on crack initiation. The main topic of this study is the research of a fatigue criterion using a micro:macro modelling approach. The first part of work deals with material characterization (stainless steel 304L) emphasising the specificities of the surface roughness link with a strong hardening gradient. The first results of the characterization on the surface show a strong work-hardening gradient on a 250 microns layer. This gradient does not evolved after thermal cycling. Micro hardness measurements and TEM observations were intensively used to characterize this gradient. The second part is the macroscopic modelling of INTHERPOL tests in order to determine the components of the stress and strain tensors due to thermal cycling. The third part of work is thus to evaluate the effect of surface roughness and hardening gradient using a calculation on a finer scale. This simulation is based on the variation of dislocation density. A goal for the future is the determination of the fatigue criterion mainly based on polycrystalline modelling. Stocked energy or critical plane being available that allows making a sound choice for the criteria. (author)

  20. Nickel-free austenitic stainless steels for medical applications

    Directory of Open Access Journals (Sweden)

    Ke Yang and Yibin Ren

    2010-01-01

    Full Text Available The adverse effects of nickel ions being released into the human body have prompted the development of high-nitrogen nickel-free austenitic stainless steels for medical applications. Nitrogen not only replaces nickel for austenitic structure stability but also much improves steel properties. Here we review the harmful effects associated with nickel in medical stainless steels, the advantages of nitrogen in stainless steels, and emphatically, the development of high-nitrogen nickel-free stainless steels for medical applications. By combining the benefits of stable austenitic structure, high strength and good plasticity, better corrosion and wear resistances, and superior biocompatibility compared to the currently used 316L stainless steel, the newly developed high-nitrogen nickel-free stainless steel is a reliable substitute for the conventional medical stainless steels.

  1. Stainless chromium-nickel steels. Chapter I

    International Nuclear Information System (INIS)

    The chemical composition is tabulated of 90 chromium-nickel stainless steels and alloys given in volume %. The values are also given of the corrosion resistance of the steels and alloys. The tables show data on the surface condition or the methods of material working, types and chemical composition of the medium where corrosion resistance tests were carried out, temperature, pressure, time of tests, corrosion rates, corrosion types, and literature references. A total of 35 references is given. (J.B.)

  2. Weld solidification cracking in 304 to 204L stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Hochanadel, Patrick W [Los Alamos National Laboratory; Lienert, Thomas J [Los Alamos National Laboratory; Martinez, Jesse N [Los Alamos National Laboratory; Johnson, Matthew Q [Los Alamos National Laboratory

    2010-09-15

    A series of annulus welds were made between 304 and 304L stainless steel coaxial tubes using both pulsed laser beam welding (LBW) and pulsed gas tungsten arc welding (GTAW). In this application, a change in process from pulsed LBW to pulsed gas tungsten arc welding was proposed to limit the possibility of weld solidification cracking since weldability diagrams developed for GTAW display a greater range of compositions that are not crack susceptible relative to those developed for pulsed LBW. Contrary to the predictions of the GTAW weldability diagram, cracking was found.This result was rationalized in terms of the more rapid solidification rate of the pulsed gas tungsten arc welds. In addition, for the pulsed LBW conditions, the material compositions were predicted to be, by themselves, 'weldable' according to the pulsed LBW weldability diagram. However, the composition range along the tie line connecting the two compositions passed through the crack susceptible range. Microstructurally, the primary solidification mode (PSM) of the material processed with higher power LBW was determined to be austenite (A), while solidification mode of the materials processed with lower power LBW apparently exhibited a dual PSM of both austenite (A) and ferrite-austenite (FA) within the same weld. The materials processed by pulsed GTAW showed mostly primary austenite solidification, with some regions of either primary austenite-second phase ferrite (AF) solidification or primary ferrite-second phase austenite (FA) solidification. This work demonstrates that variations in crack susceptibility may be realized when welding different heats of 'weldable' materials together, and that slight variations in processing can also contribute to crack susceptibility.

  3. Advances in the research of nitrogen containing stainless steels

    Institute of Scientific and Technical Information of China (English)

    2004-01-01

    The current status of nitrogen containing stainless steels at home and aboard has been introduced. The function and existing forms of nitrogen in the stainless steels, influence of nitrogen on mechanical properties and anti-corrosion properties as well as the application of nitrogen containing cast stainless steels were discussed in this paper. It is clear that nitrogen will be a potential and important alloying element in stainless steels. And Argon Oxygen Decarbonization (AOD) refining can provide an advanced manufacture process for nitrogen containing stainless steels with ultra-low- carbon and high cleanliness.

  4. Sintering and characterization of YAG dispersed ferritic stainless steels

    International Nuclear Information System (INIS)

    The present study investigates the effect of yttrium aluminium garnet (YAG) addition on the densification, mechanical, tribological and corrosion behaviour of ferritic (434L) stainless steels. The composites were sintered at both solid-state (1200 deg. C) and supersolidus (1400 deg. C) sintering conditions. Supersolidus sintering results in superior densification, hardness and corrosion resistance of both straight 434L stainless steel as well as YAG reinforced 434L stainless steels. The addition of YAG to 434L stainless steels at supersolidus sintered conditions improves the strength and wear resistance of 434L stainless steels without significantly degrading the corrosion performance

  5. Stainless steel forgings for nuclear chemical plants

    International Nuclear Information System (INIS)

    This Specification covers detailed requirements for the supply of austenitic stainless steel forgings used in radioactive and corrosive areas within the Nuclear Industry. With the exception of 316S51 the materials specified are all suitable for contact with nitric acid, 316S51 being included as suitable for use in contact with sodium and other alkali metals at elevated temperatures. (author)

  6. CASE-HARDENING OF STAINLESS STEEL

    DEFF Research Database (Denmark)

    2004-01-01

    The invention relates to case-hardening of a stainless steel article by means of gas including carbon and/or nitrogen, whereby carbon and/or nitrogen atoms diffuse through the surface into the article. The method includes activating the surface of the article, applying a top layer on the activated...

  7. Austenitic stainless steels for cryogenic service

    Energy Technology Data Exchange (ETDEWEB)

    Dalder, E.N.C.; Juhas, M.C.

    1985-09-19

    Presently available information on austenitic Fe-Cr-Ni stainless steel plate, welds, and castings for service below 77 K are reviewed with the intent (1) of developing systematic relationships between mechanical properties, composition, microstructure, and processing, and (2) of assessing the adequacy of these data bases in the design, fabrication, and operation of engineering systems at 4 K.

  8. Stabilizing stainless steel components for cryogenic service

    Science.gov (United States)

    Holden, C. F.

    1967-01-01

    Warpage and creep in stainless steel valve components are decreased by a procedure in which components are machined to a semifinish and then cold soaked in a bath of cryogenic liquid. After the treatment they are returned to ambient temperature and machine finished to the final drawing dimensions.

  9. Hydrogen gas embrittlement of selected stainless steels

    International Nuclear Information System (INIS)

    Hydrogen gas embrittlement of selected stainless steels: metastable 18-8, (α+γ) IN 744 and γ' or N-hardened austenites, has been investigated means of the triaxial disk pressure test at various pressure increase rates, at RT or sometimes -500C and +1000C. Test are supplemented with SEM and magnetic phase determination

  10. Ne Implantation Induced Transformation in Stainless Steel

    NARCIS (Netherlands)

    Noordhuis, J.; Hosson, J.Th.M. De

    1990-01-01

    This paper reports a microstructural investigation of the changes induced by Ne implantation in stainless steel of the austenitic type. At a critical dose of 2.3 · 10^17/cm^2 a martensitic phase transformation was observed. In particular, attention has been paid to the effect of the stress held of n

  11. Microbially Influenced Corrosion of Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Yong Deuk; Ryu, Seung Ki; Kim Young Ho [POSCO Techanical Researh Laboratories, Pohang (Korea, Republic of)

    1996-06-25

    Microbially Influenced Corrosion(MIC) is often a significant factor in controlling the long-term performance of most structural materials in industrial applications. This papers cover MIC mechanism and evaluation of stainless steels in soil and sea water environments. Papers also cover detection, monitoring and mitigation of MIC, biocides and treatments. (author). 28 refs., 2 tabs., 5 figs.

  12. Austenitic stainless steels for cryogenic service

    International Nuclear Information System (INIS)

    Presently available information on austenitic Fe-Cr-Ni stainless steel plate, welds, and castings for service below 77 K are reviewed with the intent (1) of developing systematic relationships between mechanical properties, composition, microstructure, and processing, and (2) of assessing the adequacy of these data bases in the design, fabrication, and operation of engineering systems at 4 K

  13. Granulate of stainless steel as compensator material

    NARCIS (Netherlands)

    J.P.C. van Santvoort (J. P C)

    1995-01-01

    textabstractCompensators produced with computer controlled milling devices usually consist of a styrofoam mould, filled with an appropriate material. We investigated granulate of stainless steel as filling material. This cheap, easy to use, clean and re-usable material can be obtained with an averag

  14. Finite Element Modeling and Validation of Residual Stresses in 304 L Girth Welds

    Energy Technology Data Exchange (ETDEWEB)

    Dike, J.J.; Ortega, A.R.; Cadden, C.H.; Rangaswamy, P. Brown, D.

    1998-06-01

    Three dimensional finite element simulations of thermal and mechanical response of a 304 L stainless steel pipe subjected to a circumferential autogenous gas tungsten arc weld were used to predict residual stresses in the pipe. Energy is input into the thermal model using a volumetric heat source. Temperature histories from the thermal analysis are used as loads in the mechanical analyses. In the mechanical analyses, a state variable constitutive model was used to describe the material behavior. The model accounts for strain rate, temperature, and load path histories. The predicted stresses are compared with x-ray diffraction determinations of residual stress in the hoop and circumferential directions on the outside surface of the pipe. Calculated stress profiles fell within the measured data. Reasons for observed scatter in measured stresses are discussed.

  15. Aging degradation of cast stainless steel

    International Nuclear Information System (INIS)

    A program is being conducted to investigate the significance of in-service embrittlement of cast duplex stainless steels under light-water reactor operating conditions. Microstructures of cast materials subjected to long-term aging either in reactor service or in the laboratory have been characterized by TEM, SANS, and APFIM techniques. Two precipitate phases, i.e., the Cr-rich α' and Ni- and Si-rich G phase, have been identified in the ferrite matrix of the aged steels. The results indicate that the low-temperature embrittlement is primarily caused by α' precipitates which form by spinodal decomposition. The relative contribution of G phase to loss of toughness is now known. Microstructural data also indicate that weakening of ferrite/austenite phase boundary by carbide precipitates has a significant effect on the onset and extent of embrittlement of the high-carbon CF-8 and CF-8M grades of stainless steels, particularly after aging at 400 or 4500C. Data from Charpy-impact, tensile, and J-R curve tests for several heats of cast stainless steel aged up to 10,000 h at 350, 400, and 4500C are presented and correlated with the microstructural results. Thermal aging of the steels results in an increase in tensile strength and a decrease in impact energy, J/sub IC/, and tearing modulus. The fracture toughness results show good agreement with the Charpy-impact data. The effects of compositional and metallurgical variables on loss of toughness are discussed

  16. Correlation of the surface composition of degassed 347 stainless steel with thermally desorbed H2 and CO

    International Nuclear Information System (INIS)

    Variations in the surface composition of stainless steel after a 24 h, 250 deg. C bakeout over the temperature range of room temperature to 800 deg. C have been correlated with desorption of H2 and CO. The surface composition of the 347 stainless steel was monitored by Auger electron spectroscopy (AES) and X-ray photoelectron spectroscopy (XPS) and desorption kinetics were determined from temperature desorption spectroscopy (TDS). Non-linear TDS was used to resolve the surface hydrogen from the bulk hydrogen. H2 and CO were observed to desorb from degassed 347 stainless steel by second-order kinetics, i.e., the gases were generated from atoms at the surface. The oxygen exchange from the surface CrxOy, FexOy to the residing carbon in the surface complex appears to control the CO generation. The onset of H2 desorption occurred slightly ahead of the CO, reached a maximum almost simultaneously (∼420 deg. C) and then declined in concert with the AES detected surface C and O. Non-linear TDS applied to large, cylindrical samples of 347 stainless steel showed H2 and CO surface desorption completely resolved from H2 bulk desorption. The steady state hydrogen desorption rate following the bakeout is bulk diffusion limited and was found to be 5.6x10-12 Torr l/(s cm2). Some discussion of the surface complex stress on the aforementioned oxide decomposition with temperature is also presented. Similar experiments on 304L stainless steel gave the same results as were observed on 347 stainless steel

  17. Austenitic stainless steels with cryogenic resistance

    International Nuclear Information System (INIS)

    The most used austenitic stainless steels are alloyed with chromium and nickel and have a reduced carbon content, usually lower than 0.1 % what ensures corresponding properties for processing by plastic deformation at welding, corrosion resistance in aggressive environment and toughness at low temperatures. Steels of this kind alloyed with manganese are also used to reduce the nickel content. By alloying with manganese which is a gammageneous element one ensures the stability of austenites. Being cheaper these steels may be used extensively for components and equipment used in cryogenics field. The best results were obtained with steels of second group, AMnNi, in which the designed chemical composition was achieved, i.e. the partial replacement of nickel by manganese ensured the toughness at cryogenic temperatures. If these steels are supplementary alloyed, their strength properties may increase to the detriment of plasticity and toughness, although the cryogenic character is preserved

  18. Nickel-free austenitic stainless steels for medical applications

    OpenAIRE

    Ke Yang and Yibin Ren

    2010-01-01

    The adverse effects of nickel ions being released into the human body have prompted the development of high-nitrogen nickel-free austenitic stainless steels for medical applications. Nitrogen not only replaces nickel for austenitic structure stability but also much improves steel properties. Here we review the harmful effects associated with nickel in medical stainless steels, the advantages of nitrogen in stainless steels, and emphatically, the development of high-nitrogen nickel-free stainl...

  19. Effects of beam offset on mechanical properties and corrosion resistance of Alloy 690-SUS 304L EBW joints for nuclear power plant

    Science.gov (United States)

    Lin, Yong-Ding; Lee, Hwa-Teng; Kuo, Tsung-Yuan; Jeng, Sheng-Long; Wu, Jia-Lin

    2010-06-01

    The current study investigates the effect of the beam offset (BOF) on the microstructure, mechanical properties, and the corrosion resistance of the fusion zone (FZ) of Alloy 690-SUS 304L stainless steel (SS) dissimilar metal butt joints formed by electron beam welding (EBW). The experimental results showed that as the value of the BOF increased from 0 to 0.30 mm, i.e. the electron beam shifted progressively toward the Alloy 690 base metal (BM), the tensile strength of the FZ fell from 582.1 to 541.2 MPa. However, the modified Huey test results indicated that the interdendritic corrosion resistance of the FZ was significantly enhanced. Pit nucleation potential value ( Enp) was raised from 385 to 1050 mV. An offset of 0.30 mm appears to be the optimal BOF setting when fabricating Alloy 690-SUS 304L SS dissimilar metal butt joints using the EBW technique.

  20. Tensile-property characterization of thermally aged cast stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Michaud, W.F.; Toben, P.T.; Soppet, W.K.; Chopra, O.K. [Argonne National Lab., IL (United States)

    1994-02-01

    The effect of thermal aging on tensile properties of cast stainless steels during service in light water reactors has been evaluated. Tensile data for several experimental and commercial heats of cast stainless steels are presented. Thermal aging increases the tensile strength of these steels. The high-C Mo-bearing CF-8M steels are more susceptible to thermal aging than the Mo-free CF-3 or CF-8 steels. A procedure and correlations are presented for predicting the change in tensile flow and yield stresses and engineering stress-vs.-strain curve of cast stainless steel as a function of time and temperature of service. The tensile properties of aged cast stainless steel are estimated from known material information, i.e., chemical composition and the initial tensile strength of the steel. The correlations described in this report may be used for assessing thermal embrittlement of cast stainless steel components.

  1. 304L无缝钢管二辊斜轧穿孔裂纹的形成原因%Causes of Crack Formation in 304L Seamless Steel Pipe during Double-Roll Cross Piercing Process

    Institute of Scientific and Technical Information of China (English)

    王宝顺; 邵羽; 李三; 赵芳馨; 沈红英; 朱新强

    2013-01-01

    The mechanism of cracking in 304L seamless steel pipe during double-roll cross piercing processing was analyzed by optical microscopy, thermal-calculation ulation software and scanning electron microscopy. The results show that about 3 vol. % S ferrite phase in the billet and the heterogenous deformation of billet during the piercing process were the main causes of cracking. In addition, the difference of deformability between S ferrite phase and y phase caused both the tensile stress and the shear stress at the interface of two phases higher than the fracture strength of billet, which promoted the formation and growth of the cracks.%采用光学显微镜、热力学计算软件、扫描电镜等分析了304L无缝钢管二辊斜轧穿孔工艺中荒管内部产生裂纹的原因.结果表明:穿孔用钢坯中存在3%左右(体积分数)的δ铁素体相,穿孔工艺中不均匀变形是裂纹产生的主要原因;由于δ相和γ相变形能力不一致,在两相界面上产生超过金属断裂强度的拉应力和切应力则促进了裂纹的形成与扩展.

  2. Estimation of the kinetics of martensitic transformation in austenitic stainless steels by conventional and novel approaches

    Energy Technology Data Exchange (ETDEWEB)

    Shirdel, M., E-mail: mshirdel1989@ut.ac.ir [School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, P.O. Box 11155-4563, Tehran (Iran, Islamic Republic of); Mirzadeh, H., E-mail: hmirzadeh@ut.ac.ir [School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, P.O. Box 11155-4563, Tehran (Iran, Islamic Republic of); Advanced Metalforming and Thermomechanical Processing Laboratory, School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); Parsa, M.H., E-mail: mhparsa@ut.ac.ir [School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, P.O. Box 11155-4563, Tehran (Iran, Islamic Republic of); Center of Excellence for High Performance Materials, School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); Advanced Metalforming and Thermomechanical Processing Laboratory, School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of)

    2015-01-29

    A comparative study was carried out on the kinetics of the martensitic transformation in a 304L stainless steel during cold rolling by conventional and novel approaches. The phase analysis based on X-ray diffraction patterns and metallography and also magnetic measurements based on ferritescope readings were utilized to elucidate the kinetics of the martensitic transformation. A straightforward magnetic measurement approach for evaluating the amount of strain-induced martensite in metastable austenitic stainless steels has been introduced in this study. This technique collects the data throughout the bulk of the material to give a realistic estimate of the amount of ferromagnetic martensite. This is an advantage over the surface collecting methods such as ferritescope readings, which overestimates the amount of martensite due to its inhomogeneous distribution through the thickness based on the frictional effects between the rolls and the specimen surface. The proposed approach can be applied in various designs for static/continuous magnetic measurement of bulk materials that is advantageous compared with the conventional vibrating sample magnetometer technique which is useful for static measurement of bulk materials with specific shapes. Moreover, in analogy to ferritescope, the output data of the developed device is directly related to the amount of martensite.

  3. Phase Transformation in Cast Superaustenitic Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Lee Phillips, Nathaniel Steven [Iowa State Univ., Ames, IA (United States)

    2006-01-01

    Superaustenitic stainless steels constitute a group of Fe-based alloys that are compositionally balanced to have a purely austenitic matrix and exhibit favorable pitting and crevice corrosion resistant properties and mechanical strength. However, intermetallic precipitates such as sigma and Laves can form during casting or exposure to high-temperature processing, which degrade the corrosion and mechanical properties of the material. The goal of this study was to accurately characterize the solid-solid phase transformations seen in cast superaustenitic stainless steels. Heat treatments were performed to understand the time and temperature ranges for intermetallic phase formations in alloys CN3MN and CK3MCuN. Microstructures were characterized using scanning electron microscopy (SEM), transmission electron microscopy (TEM), and energy and wavelength dispersive spectroscopy (EDS, WDS). The equilibrium microstructures, composed primarily of sigma and Laves within purely austenitic matrices, showed slow transformation kinetics. Factors that determine the extent of transformation, including diffusion, nucleation, and growth, are discussed.

  4. Plasma spot welding of ferritic stainless steels

    International Nuclear Information System (INIS)

    Plasma spot wedding of ferritic stainless steels studied. The study was focused on welding parameters, plasma and shieldings and the optimum welding equipment. Plasma-spot welded overlap joints on a 0.8 mm thick ferritic stainless steel sheet were subjected to a visual examination and mechanical testing in terms of tension-shear strength. Several macro specimens were prepared Plasma spot welding is suitable to use the same gas as shielding gas and as plasma gas , i. e. a 98% Ar/2% H2 gas mixture. Tension-shear strength of plasma-spot welded joint was compared to that of resistance sport welded joints. It was found that the resistance welded joints withstand a somewhat stronger load than the plasma welded joints due to a large weld sport diameter of the former. Strength of both types of welded joints is approximately the same. (Author) 32 refs

  5. Studies of stainless steel exposed to sandblasting

    Directory of Open Access Journals (Sweden)

    Horodek Paweł

    2015-12-01

    Full Text Available The influence of sandblasting on surface and subsurface of stainless steel is investigated using variable energy positron beam (VEP, positron annihilation spectroscopy (PAS, scanning electron microscopy (SEM, and atomic force microscopy (AFM. Samples of stainless steel were blasted using 110 μm particles of Al2O3 under different pressure and time duration. In the case of sandblasting for 90 s, the reduction of positron diffusion length depending on the applied pressure was observed. Sandblasting during 30 s leads only to the reduction of positron diffusion length to about 60 nm for all samples. Positron lifetimes close to 170 ps measured using positrons emitted directly from the source point to the presence of vacancies on the dislocation lines. SEM and AFM images show that surface roughness depends rather on pressure of sandblasting than time of exposition.

  6. Weldability of Additive Manufactured Stainless Steel

    Science.gov (United States)

    Matilainen, Ville-Pekka; Pekkarinen, Joonas; Salminen, Antti

    Part size in additive manufacturing is limited by the size of building area of AM equipment. Occasionally, larger constructions that AM machines are able to produce, are needed, and this creates demand for welding AM parts together. However there is very little information on welding of additive manufactured stainless steels. The aim of this study was to investigate the weldability aspects of AM material. In this study, comparison of the bead on plate welds between AM parts and sheet metal parts is done. Used material was 316L stainless steel, AM and sheet metal, and parts were welded with laser welding. Weld quality was evaluated visually from macroscopic images. Results show that there are certain differences in the welds in AM parts compared to the welds in sheet metal parts. Differences were found in penetration depths and in type of welding defects. Nevertheless, this study presents that laser welding is suitable process for welding AM parts.

  7. Tritium Depth Profiles in 316 Stainless Steel

    Science.gov (United States)

    Torikai, Yuji; Murata, Daiju; Penzhorn, Ralf-Dieter; Akaishi, Kenya; Watanabe, Kuniaki; Matsuyama, Masao

    To investigate the behavior of hydrogen uptake and release by 316 stainless steel (SS316), as-received and finely polished stainless steel specimens were exposed at 573 K to tritium gas diluted with hydrogen. Then tritium concentration in the exposed specimens was measured as a function of depth using a chemical etching method. All the tritium concentration profiles showed a sharp drop in the range of 10 μm from the top surface up to the bulk. The amount of tritium absorbed into the polished specimens was three times larger than that into the as-received specimen. However, the polishing effects disappeared by exposing to the air for a long time.

  8. State on AISI 304 Stainless Steel

    Directory of Open Access Journals (Sweden)

    A. Fattah-alhosseini

    2011-01-01

    Full Text Available The passivity and protective nature of the passive films are essentially related to ionic and electronic transport processes, which are controlled by the optical and electronic properties of passive films. In this study, the electrochemical behavior of passive films anodically formed on AISI 304 stainless steel in sulfuric acid solution has been examined using electrochemical impedance spectroscopy. AISI 304 in sulphuric acid solution is characterized by high interfacial impedance, thereby illustrating its high corrosion resistance. Results showed that the interfacial impedance and the polarization resistance (pol initially increase with applied potential, within the low potential passive. However, at a sufficiently high potential passive (>0.4 V, the interfacial impedance and the polarization resistance decrease with increasing potential. An electrical equivalent circuit based on the impedance analysis, which describes the behavior of the passive film on stainless steel more satisfactorily than the proposed models, is presented.

  9. Diamond deposition on siliconized stainless steel

    International Nuclear Information System (INIS)

    Silicon diffusion layers in AISI 304 and AISI 316 type stainless steels were investigated as an alternative to surface barrier coatings for diamond film growth. Uniform 2 μm thick silicon rich interlayers were obtained by coating the surface of the steels with silicon and performing diffusion treatments at 800 deg. C. Adherent diamond films with low sp2 carbon content were deposited on the diffused silicon layers by a modified hot filament assisted chemical vapor deposition (HFCVD) method. Characterization of as-siliconized layers and diamond coatings was performed by energy dispersive X-ray analysis, scanning electron microscopy, X-ray diffraction and Raman spectroscopy.

  10. The compatibility of stainless steels with particles and powders of uranium carbide and low-sulphur UCS fuels

    International Nuclear Information System (INIS)

    Slightly hyperstoichiometric (U,Pu)C is a potential nuclear fuel for fast breeder reactors. The excess carbon above the stoichiometric amount results in a higher carbon activity in the fuel, and carbon is transferred to the stainless steel cladding, resulting in embrittlement of the cladding. It is with this problem of carbon transfer from the fuel to the cladding that this thesis is concerned. For practical reasons, UC and not (U,Pu)C was used as the fuel. The theory of decarburisation of carbide fuel and the carburisation of stainless steel, the facilities constructed for the project at the Atomic Energy Board, and the experimental techniques used, including preparation of the fuels, are discussed. The effect of a number of variables of uranium carbide fuel on its compatibility behaviour with stainless steels was investigated, as well as the effect om microstructure and type of stainless steel (304, 304 L and 316) on the rate of carburisation. These studies can be briefly summarised under the following headings: powder-particle size; surface oxidation of uranium carbide; preparation temperature of uranium carbide; low sulfur UCS fuels; uranium sulfide and the microstructure and type of steel. The author concludes that: the effect of surface oxidation and particle size must be taken into account when evaluating out-of-pile tests; the possible effects of surface oxidation must be taken into account when considering vibro-compacted carbide fuels; there is no advantage in replacing a fraction of the carbon atoms by sulphur atoms in slightly hyperstoichiometric carbide fuels, and the type and thermo-mechanical treatment of the stainless steel used as cladding material in a fuel pin is not important as far as the rate of carburisation by the fuel is concerned

  11. Fatigue fracture modes of a stainless steel

    International Nuclear Information System (INIS)

    The influence of strain hardening and martensite phase transformation on the fatigue fracture regions (pulsative tension) of a Stainless Steel type AISI 316 was investigated. This lead to the conclusion that the greater austenite strain hardening level only favours the occurrence of a brittle fracture. Also, in as much as the static induced martensite is concerned, a direct influence on the failure process was not observed, whereas, apparently, the one transformed under cyclic loading has no contribution to the rupture mechanisms. (author)

  12. Pitting corrosion resistant austenite stainless steel

    Science.gov (United States)

    van Rooyen, D.; Bandy, R.

    A pitting corrosion resistant austenite stainless steel comprises 17 to 28 wt. % chromium, 15 to 26 wt. % nickel, 5 to 8 wt. % molybdenum, and 0.3 to 0.5 wt. % nitrogen, the balance being iron, unavoidable impurities, minor additions made in the normal course of melting and casting alloys of this type, and may optionally include up to 10 wt. % of manganese, up to 5 wt. % of silicon, and up to 0.08 wt. % of carbon.

  13. Corrosion Properties of Laser Welded Stainless Steel

    DEFF Research Database (Denmark)

    Weldingh, Jakob; Olsen, Flemmming Ove

    1997-01-01

    In this paper the corrosion properties of laser welded AISI 316L stainless steel are examined. A number of different welds has been performed to test the influence of the weld parameters of the resulting corrosion properties. It has been chosen to use the potential independent critical pitting...... temperature (CPT) test as corrosion test. The following welding parameters are varied: Welding speed, lsser power, focus point position and laser operation mode (CW or pulsed)....

  14. Complex Protection of Vertical Stainless Steel Tanks

    OpenAIRE

    Fakhrislamov Radik Zakievich

    2014-01-01

    The authors consider the problem of fail-safe oil and oil products storage in stainless steel tanks and present the patented tank inner side protection technology. The latter provides process, ecological and fire safety and reducing soil evaporation of oil products, which is a specific problem. The above-mentioned technology includes corrosion protection and heat insulation protection providing increase of cover durability and RVS service life in general. The offered technological protection ...

  15. Cyclic deformation of duplex stainless steels

    OpenAIRE

    Mateo García, Antonio Manuel; Gironés, Ana

    2011-01-01

    Duplex stainless steels configure a family of metallic alloys that combined elevated mechanical properties with improved corrosion resistance when compared to standard austenitic grades. This excellent combination of properties leads to their use under many different applications, particularly in the fields of chemical, petrochemical, pulp and paper industries. Moreover, these applications usually involve cyclic loading, and consequently the study of fatigue properties has a great significanc...

  16. Thermal ageing of duplex stainless steels

    International Nuclear Information System (INIS)

    The evolution of the mechanical properties of Mobearing anf Mo-free cast duplex stainless steels, induced by long term ageing in the range 300-400 deg C, has been studied in relation with the evolution of their microstructure. The unmixing of the ferritic Fe-Cr-Ni, solid solution by three-dimensional (sponge-like) spinodal decomposition and the precipitation of intermetallic G-phase particles are the main characteristics of this microstructural evolution

  17. Study of the experimental parameters associated to the determination of residual macro stresses in stainless steel tubes, through x-ray diffraction method

    International Nuclear Information System (INIS)

    The basic principles related to the determination of residual macro stresses by X-rays diffractometry are present, whereas different techniques associated with the respective experimental errors are discussed. The residual stresses in two 304 L stainless steel tubes were measured using three models of diffractometers, Rigaku SG-8, Jeol JDX-11PA and Rigaku Strainflex. The measured values of stresses as well as the reproducibilities are examined. The suitability of peak location method, by fitting three data points to the parabolic function, is discussed through values of position and intensity obtained by two of the above diffractometers. (author)

  18. Study of the experimental parameters associated to the determination of residual macro stresses in stainless steel tubes through x-rays diffraction method

    International Nuclear Information System (INIS)

    The basic principles related to the determination of residual macro stresses by X-rays diffractometry are present, whereas different techniques associated with the respective experimental errors are discussed. The residual stresses in two 304 L stainless steel tubes were measured using three models of diffractometers, Rigaku SG-8, Jeol JDX-11PA and Rigaku Strainflex. The measured values of stresses as well as the reproducibilities are examined. The suitability of peak location method, by fitting three data points to the parabolic function, is discussed through values of position and intensity obtained by two of the above diffractometers. (author)

  19. SRS stainless steel beneficial reuse program

    Energy Technology Data Exchange (ETDEWEB)

    Boettinger, W.L.

    1997-02-01

    The US Department of Energy`s (DOE) Savannah River Site (SRS) has thousands of tons of stainless steel radioactive scrap metal (RSNI). Much of the metal is volumetrically contaminated. There is no {open_quotes}de minimis{close_quotes} free release level for volumetric material, and therefore no way to recycle the metal into the normal commercial market. If declared waste, the metal would qualify as low level radioactive waste (LLW) and ultimately be dispositioned through shallow land buried at a cost of millions of dollars. The metal however could be recycled in a {open_quotes}controlled release{close_quote} manner, in the form of containers to hold other types of radioactive waste. This form of recycle is generally referred to as {open_quotes}Beneficial Reuse{close_quotes}. Beneficial reuse reduces the amount of disposal space needed and reduces the need for virgin containers which would themselves become contaminated. Stainless steel is particularly suited for long term storage because of its resistance to corrosion. To assess the practicality of stainless steel RSM recycle the SRS Benficial Reuse Program began a demonstration in 1994, funded by the DOE Office of Science and Technology. This paper discusses the experiences gained in this program.

  20. SCC of stainless steel under evaporative conditions

    Energy Technology Data Exchange (ETDEWEB)

    Andersen, H.; Arnvig, P.E.; Wasielewska, W.; Wegrelius, L.; Wolfe, C. [Avesta Sheffield AB, Avesta (Sweden)

    1998-12-31

    Three different test methods have been used to assess the susceptibility of different stainless steel grades to SCC under evaporative and immersed conditions. The methods employed were the drop evaporation test, the wick test and a high temperature, high pressure test simulating a feedwater heater tubing application in power plants. The alloys investigated were commercially produced austenitic and duplex stainless steels varying in chemical composition, plus one copper-nickel alloy. The resistance of austenitic stainless steels towards SCC increased by increasing the content of Ni, Mo and Cr, thus the super austenitic 654SMO{reg_sign} (uns32654) did not show any cracking in any of the three tests. The super austenitic 254SMO{reg_sign} (UNS31254) revealed only slight SCC in the simulated feed water heater tubing application while the equivalent N08367 revealed severe pitting and cracking. The drop evaporation test exhibited the most severe test conditions characterized by thermally induced fatigue effects, sensibility to onset of corrosion and severe acidic conditions generated under deposits on the test specimen. Some factors in stress corrosion cracking tests such as thermal fatigue, diffusion, heat transfer and stress condition, are discussed with regard to their influence on the test results.

  1. Aging degradation of cast stainless steel

    International Nuclear Information System (INIS)

    A program is being conducted to investigate the significance of in-service embrittlement of cast duplex stainless steels under light-water reactor operating conditions. Microstructures of cast materials subjected to long-term aging either in reactor service or in the laboratory have been characterized by TEM, SANS, and APFIM techniques. Two precipitate phases, i.e., the Cr-rich α' phase and the Ni- and Si-rich G phase, have been identified in the ferrite matrix of the aged steels. The results indicate that the low-temperature embrittlement is primarily caused by α' precipitates which form by spinodal decomposition. The relative contribution of the G phase to loss of toughness is now known. Microstructural data also indicate that weakening of the ferrite/austenite phase boundary by carbide precipitates has a significant effect on the onset and extent of embrittlement of the high-carbon CF-8 and CF-8M grades of stainless steels, particularly after aging at 400 or 4500C. Data from Charpy-impact, tensile, and J-R curve tests for several heats of cast stainless steel aged up to 10,000 h at 350, 400, and 4500C are presented and correlated with the microstructural results. Thermal aging of the steels results in an increase in tensile strength and a decrease in impact energy, J/sub IC/, and tearing modulus. The fracture toughness results show good agreement with the Charpy-impact data. The effects of compositional and metallurgical variables on loss of toughness are discussed

  2. Corrosion fatigue of a superduplex stainless steel weldment

    OpenAIRE

    Comer, Anthony John

    2004-01-01

    Superduplex stainless steels have superior mechanical and corrosion properties compared to austenitic stainless steels such as the grade 300 series. This is a result of a microstructure consisting of roughly equal percentages of austenite (y) and ferrite (a) and negligible inclusion content. As a result, super duplex stainless steels are increasingly being used in the offshore oil and gas industries. It is also envisaged that they will find application in the emergent renewable energy sec...

  3. Sinter-hardening process applicable to stainless steels

    OpenAIRE

    M. Rosso; Z. Brytan; L.A. Dobrzański

    2007-01-01

    Purpose: of this paper was to describe sintered duplex stainless steels manufactured in sinter-hardening process and its usability in field of stainless steels.Design/methodology/approach: In presented study duplex stainless steels were obtained through powder metallurgy starting from austenitic, ferritic base powders by controlled addition of alloying elements, such as Cr, Ni, Mo and Cu. In the studies apart from the preparation of mixes, Schaeffler’s diagram was taken into consideration. Pr...

  4. Development of oxide dispersion strengthened 2205 duplex stainless steel composite

    OpenAIRE

    Oladayo OLANIRAN; Peter Apata OLUBAMBI; Benjamin Omotayo ADEWUYI; Joseph Ajibade OMOTOYINBO; Ayodeji Ebenezar AFOLABI; Davies FOLORUNSO; Adekunle ADEGBOLA; Emanuel IGBAFEN

    2015-01-01

    Composites of duplex stainless steel were produced by oxide dispersion strengthening with comparatively improved mechanical properties by hot press sintering of partially stabilized Zirconia (PSZ, 3% yttria, mole fraction) dispersion in 2205 duplex stainless steels. Ceramic oxide was added as reinforcement, while chromium (Cr) and Nickel (Ni) were incorporated to maintain the austenitic/ferritic phase balance of the duplex stainless steel. The powders and sintered were characterized in detail...

  5. Buckling response of ferritic stainless steel columns at elevated temperatures

    OpenAIRE

    Afshan, S; Gardner, L; Baddoo, NR

    2013-01-01

    This paper presents a numerical study on the buckling behaviour of ferritic stainless steel columns in fire. Finite element models were developed and validated against existing test results to predict the elevated temperature non-linear response of ferritic stainless steel columns. A total of nine austenitic and three ferritic stainless steel column tests were replicated using the finite element analysis package ABAQUS. Parametric studies were performed to investigate the effects of variation...

  6. Electrochemical aspects of stainless steel behaviour in biocorrosive environment

    International Nuclear Information System (INIS)

    Electrochemical measurements have been used to evaluate and follow, to understand and control microbial induced corrosion of stainless steels. Results include seawater loop tests and laboratory-based microbiological experiments. With natural flowing seawater, impedance spectroscopy measurements have been used to evaluate and follow biofilms on stainless steel tube-electrodes. With batch cultures of single bacterial strain (Sulphate Reducing Bacteria), open-circuit potential measurements and polarization curves performed on 316 L and 430 Ti stainless steels, have shown that the corrosion behaviour of these stainless steels is mainly dependent on the sulphide content of the culture media

  7. Statistical model of water environment effects on the fatigue behavior of austenitic stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Wilhelm, Paul [AREVA GmbH, Erlangen (Germany); Erlangen-Nuernberg Univ., Erlangen (Germany). Chair of Applied Mechanics; Steinmann, Paul [Erlangen-Nuernberg Univ., Erlangen (Germany). Chair of Applied Mechanics; Rudolph, Juergen [AREVA GmbH, Erlangen (Germany)

    2014-07-01

    Many studies on the effects of elevated temperature environments on the cycle fatigue performance of austenitic stainless steels typically used for boiling and light water reactor components have been performed. The key parameters (e. g. strain rate, and temperature) that influence the fatigue life were identified and the range of these key parameters where environmental effects become pronounced were defined. The two major efforts to characterize environmentally assisted fatigue (EAF) are by Argonne National Laboratory (U. S.) and EFD (Japan). Since each nation considers only domestic fatigue data, the widely applied titanium and niobium stabilized austenitic stainless steels in Germany are not included by any data points in these models. Based on a review of past and current research reports about EAF a database for wrought Types 304, 304L, 316, 316NG, 321, 347, and 348 stainless steels was compiled. Only specimen tests under strain control with a fully reversed uniaxial loading were included. The modified Langer equation was used to develop the room temperature in air curve to the collected data, which serves as the basis for the discussion of the EAF database. Besides the key variables that influence fatigue life in light and boiling water reactor environments additional parameters like, for example, the strain amplitude, which pronounces environmental effects more at low than at high strain amplitudes, can reduce the fatigue life by a factor of about two and should not be neglected in the current fatigue approach. A statistical model is evolved to address EAF in fatigue usage calculation by a fatigue life correction factor (F{sub en}), which is defined as the ratio of life in air at room temperature to that in water at elevated temperature. Compared to the current ANL statistical prediction model, a different functional form is used and additional variables are considered, too.

  8. Complex Protection of Vertical Stainless Steel Tanks

    Directory of Open Access Journals (Sweden)

    Fakhrislamov Radik Zakievich

    2014-03-01

    Full Text Available The authors consider the problem of fail-safe oil and oil products storage in stainless steel tanks and present the patented tank inner side protection technology. The latter provides process, ecological and fire safety and reducing soil evaporation of oil products, which is a specific problem. The above-mentioned technology includes corrosion protection and heat insulation protection providing increase of cover durability and RVS service life in general. The offered technological protection scheme is a collaboration of the author, Steel Paint GmbH firm and JSC “Koksokhimmontazhproyekt”. PU foam unicomponent materials of Steel Paint GmbH firm provide the protection of tank inner side and cover.

  9. Bacterial inhibition of silver-containing stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Chiang, W.C. [Technical Univ. of Denmark, Lyngby (Denmark). Dept. of Mechanical Engineering; Chang, S.M.; Lin, J.D.; Tseng, I.S.; Wu, J.K. [National Taiwan Ocean Univ., Taiwan (China). Inst. of Materials Engineering

    2010-07-01

    In this study, silver (Ag) was added to AlSl 316 austenitic 2205 duplex and 430 ferritic stainless steels as a means of inhibiting bacterial contamination. Three Ag-containing stainless steels were prepared using vacuum melting techniques. The influence of the Ag addition on corrosion resistance, bacterial inhibition, and mechanical properties was investigated. A study of the Ag-containing stainless steel microstructures demonstrated that Ag precipitates as small particles on the steel matrix surface. The precipitates act as anodes in the local action cell in the presence of bacteria. Ag dissolution mechanisms from the Ag precipitates on the Ag-containing stainless steels in the presence of Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) were also discussed. Results of the study suggested that Ag-containing stainless steels may be used in areas where hygiene is a significant concern.

  10. Duplex stainless steels for applications in power plants. Stress corrosion tests in high temperature water containing oxygen and chloride. Duplexa rostfria staal foer kraftverkstillaempningar. Spaenningskorrosionsprovning i syre- och kloridhaltigt hoegtemperaturvatten

    Energy Technology Data Exchange (ETDEWEB)

    Molander, A.

    1987-09-15

    The work presented in this report forms the first experimental part of the project 'Duplex stainless steels for applications in power plants' started to investigate how duplex stainless steels can favourably replace conventional materials in power generating equipment. The corrosion resistance of duplex stainless steels are often better than for austenitic stainless steels, but background documentation for power plant applications is limited. The stress corrosion test presented in this report has been performed in the light of these facts. The test environment was water at 250 deg C with addition of oxygen to a nominal concentration of 10 ppb and sodium chloride to a chloride concentration of 1 000 ppm. Slow strain rate testing and exposure of corrosion coupons were performed. The following materials were tested: Type 439 (ferritic), Sandvik 3RE60, SAF 2304 and SAF 2205 (duplex), and Type 304, Type 304L, Type 316L and Alloy 800 (austenitic stainless alloys). Corrosion coupons from these alloys and the following steels were also included: St 35 (carbon steel), Type 409 and Type 444 (ferritic), and Sanicro 28 (austenitic stainless steel). Alloy 800 and SAF 2205 were not attacked by stress corrosion cracking during these conditions. Concerning general corrosion the duplex and the austenitic materials were superior to the ferritic steels.

  11. Ion nitriding in 316=L stainless steel

    International Nuclear Information System (INIS)

    Ion nitriding is a glow discharge process that is used to induce surface modification in metals. It has been applied to 316-L austenitic stainless steel looking for similar benefits already obtained in other steels. An austenitic stainless steel was selected because is not hardenable by heat treatment and is not easy to nitride by gas nitriding. The samples were plastically deformed to 10, 20, 40, 50 AND 70% of their original thickness in order to obtain bulk hardening and to observe nitrogen penetration dependence on it. The results were: an increase of one to two rockwell hardness number (except in 70% deformed sample because of its thickness); an increase of even several hundreds per cent in microhardness knoop number in nitrided surface. The later surely modifies waste resistance which would be worth to quantify in further studies. Microhardness measured in an internal transversal face to nitrided surface had a gradual diminish in its value with depth. Auger microanalysis showed a higher relative concentration rate CN/CFe near the surface giving evidence of nitrogen presence till 250 microns deep. The color metallography etchant used, produced faster corrosion in nitrited regions. Therefore, corrosion studies have to be done before using ion nitrited 316-L under these chemicals. (Author)

  12. Fatigue properties of duplex stainless steel

    OpenAIRE

    Turrel, Benjamin; Luna Garcia, Jordi; Andraschko, Stephan

    2009-01-01

    PFC presentat a Oslo University College The aim of the project is to study fatigue properties of duplex stainless steel used for a bridge. The samples had to be tested and the results have to be compared with the theory, studied before. Six specimens have been broken by tensile fatigue testing machine in order to get more knowledge about the lifetime and the behavior under dynamic stress and not only for welded parts. Out of this new knowledge a new fatigue curve for this ma...

  13. EXAFS investigation of low temperature nitrided stainless steel

    DEFF Research Database (Denmark)

    Oddershede, Jette; Christiansen, Thomas; Ståhl, Kenny;

    2008-01-01

    Low temperature nitrided stainless steel AISI 316 flakes were investigated with EXAFS and X-ray diffraction analysis. The stainless steel flakes were transformed into a mixture of nitrogen expanded austenite and nitride phases. Two treatments were carried out yielding different overall nitrogen...

  14. Characterization of silane layers on modified stainless steel surfaces and related stainless steel-plastic hybrids

    International Nuclear Information System (INIS)

    The aim of this work was to characterize silane layers on the modified stainless steel surfaces and relate it to the adhesion in the injection-molded thermoplastic urethane-stainless steel hybrids. The silane layers were characterized with scanning electron microscope and transmission electron microscope, allowing the direct quantization of silane layer thickness and its variation. The surface topographies were characterized with atomic force microscope and chemical analyses were performed with X-ray photoelectron spectroscopy. The mechanical strength of the respective stainless steel-thermoplastic urethane hybrids was determined by peel test. Polishing and oxidation treatment of the steel surface improved the silane layer uniformity compared to the industrially pickled surface and increased the adhesion strength of the hybrids, resulting mainly cohesive failure in TPU. XPS analysis indicated that the improved silane bonding to the modified steel surface was due to clean Fe2O3-type surface oxide and stronger interaction with TPU was due to more amino species on the silane layer surface compared to the cleaned, industrially pickled surface. Silane layer thickness affected failure type of the hybrids, with a thick silane layer the hybrids failed mainly in the silane layer and with a thinner layer cohesively in plastic.

  15. Local fracture toughness of stainless steel welds at 4 K by J-evaluation on tensile test

    International Nuclear Information System (INIS)

    Local fracture toughness of top, middle, bottom, and heat-affected zones of weld joints of SUS304L and SUS316L have been evaluated by a new testing procedure of J-evaluation on tensile test (JETT) with circumferentially notched round bar specimen. Delta (δ)-ferrite contents of those welds were changed between 0% and 10%. The tests were carried out at 293, 77, and 4 K. In the case of austenitic stainless steels, being too ductile at room temperature, this test method is effective at low temperatures. Fracture toughness at 4 K obtained by JETT was a little bit higher than that obtained by conventional CT specimens and was lower in weld metals than in base metals and decreased as the content of delta ferrite increased in both 304L and 316L. Scatter in the values of fracture toughness among the locations in weld metals were less than 50% and were considered to be caused by effects of δ-ferrite grains

  16. Operational experience with stainless steel condenser tubes

    International Nuclear Information System (INIS)

    Longitudinal seam welded tubes of stainless austenitic 18/8 CrNi and 18/8/2 CrNiMo steels have proved their worth when used in steam condensers with fresh water recooling. However, in water containing a high level of salt, in particular brackish water and seawater, experience to date has not been satisfactory in the case of these materials. High-alloy austenitic, ferritic and austenitic-ferritic steels developed during the last 10 years, on the other hand, have high pitting potentials and, both in the laboratory and in practice, have proved their suitability as heat-exchanger materials for steam condensers. These materials are easily worked to form welded tubes with a longitudinal seam and are therefore a relatively inexpensive design which ensures both plant safety and availability

  17. The effects of 800 MeV proton irradiation on the corrosion of tungsten, tantalum, stainless steel, and gold

    Energy Technology Data Exchange (ETDEWEB)

    Lillard, R.S.; Butt, D.P.; Kanner, G.; Daemen, L.

    1997-12-01

    Real time electrochemical data were acquired for tungsten, tantalum, stainless steel 304L, and gold targets during proton irradiation at the LANSCE Weapons Neutron Research Facility. The goal of this research was to establish a better understanding of the corrosion properties of materials as a function of proton irradiation and gain insight into the mechanism of the observed phenomena. The following electrochemical observations were made during proton irradiation of W, Ta, SS304, and Au: (1) the open circuit potential of all materials increased with increasing proton fluence; (2) the corrosion rate (at the OCP) of W and SS304 increased with increasing proton fluence; (3) the passive dissolution rate for SS304 and Ta decreased with increasing proton fluence; (4) the anodic dissolution rate for W increased with increasing proton fluence; (5) the pitting potential for SS304 increased with proton fluence, which is an indication that the material is less susceptible to pitting attack during irradiation.

  18. The effects of 800 MeV proton irradiation on the corrosion of tungsten, tantalum, stainless steel, and gold

    International Nuclear Information System (INIS)

    Real time electrochemical data were acquired for tungsten, tantalum, stainless steel 304L, and gold targets during proton irradiation at the LANSCE Weapons Neutron Research Facility. The goal of this research was to establish a better understanding of the corrosion properties of materials as a function of proton irradiation and gain insight into the mechanism of the observed phenomena. The following electrochemical observations were made during proton irradiation of W, Ta, SS304, and Au: (1) the open circuit potential of all materials increased with increasing proton fluence; (2) the corrosion rate (at the OCP) of W and SS304 increased with increasing proton fluence; (3) the passive dissolution rate for SS304 and Ta decreased with increasing proton fluence; (4) the anodic dissolution rate for W increased with increasing proton fluence; (5) the pitting potential for SS304 increased with proton fluence, which is an indication that the material is less susceptible to pitting attack during irradiation

  19. Angle-dependent lubricated tribological properties of stainless steel by femtosecond laser surface texturing

    Science.gov (United States)

    Wang, Zhuo; Li, Yang-Bo; Bai, Feng; Wang, Cheng-Wei; Zhao, Quan-Zhong

    2016-07-01

    Lubricated tribological properties of stainless steel were investigated by femtosecond laser surface texturing. Regular-arranged micro-grooved textures with different spacing and micro-groove inclination angles (between micro-groove path and sliding direction) were produced on AISI 304L steel surfaces by an 800 nm femtosecond laser. The spacing of micro-groove was varied from 25 to 300 μm, and the inclination angles of micro-groove were measured as 90° and 45°. The tribological properties of the smooth and textured surfaces with micro-grooves were investigated by reciprocating ball-on-flat tests against Al2O3 ceramic balls under starved oil lubricated conditions. Results showed that the spacing of micro-grooves significantly affected the tribological property. With the increase of micro-groove spacing, the average friction coefficients and wear rates of textured surfaces initially decreased then increased. The tribological performance also depended on the inclination angles of micro-grooves. Among the investigated patterns, the micro-grooves perpendicular to the sliding direction exhibited the lowest average friction coefficient and wear rate to a certain extent. Femtosecond laser-induced surface texturing may remarkably improve friction and wear properties if the micro-grooves were properly distributed.

  20. The effect of heat treatments and coatings on the outgassing rate of stainless steel chambers

    CERN Document Server

    Mamun, M A; Stutzman, M L; Adderley, P A; Poelker, M

    2014-01-01

    The outgassing rates of four nominally identical 304L stainless steel vacuum chambers were measured to determine the effect of chamber coatings and heat treatments. One chamber was coated with titanium nitride (TiN) and one with amorphous silicon (a-Si) immediately following fabrication. One chamber remained uncoated throughout, and the last chamber was first tested without any coating, and then coated with a-Si following a series of heat treatments. The outgassing rate of each chamber was measured at room temperatures between 15 and 30 {\\deg}C following bakes at temperatures between 90 and 400 {\\deg}C. Measurements for bare steel showed a significant reduction in the outgassing rate by more than a factor of 20 after a 400 {\\deg}C heat treatment (4x10-12 TorrLs-1cm-2 prior to heat treatment, reduced to 1.7x10-13 following heat treatment). The chambers that were coated with a-Si showed minimal change in outgassing rates with heat treatment, though an outgassing rate reduced by heat treatments prior to a-Si coa...

  1. Improvement of the mechanical properties of austenitic stainless steel after plasma nitriding

    Energy Technology Data Exchange (ETDEWEB)

    Menthe, E.; Bulak, A.; Zimmermann, A.; Rie, K.-T. [Technische Univ. Braunschweig (Germany). Inst. fuer Oberflaechentechnik und Plasmatechnische Werkstoffentwicklung; Olfe, J. [Fraunhofer Institut fuer Schicht- und Oberflaechentechnik, Braunschweig (Germany)

    2000-11-01

    In this paper, we report on a series of experiments designed to study the influence of plasma nitriding on the mechanical properties of austenitic stainless steel. Plasma nitriding experiments were conducted on AISI 304L steel in a temperature range of 375-475 C using pulsed-DC plasma with different N{sub 2}-H{sub 2} gas mixtures and treatment times. Firstly the formation and the microstructure of the modified layer will be highlighted followed by the results of hardness measurement, adhesion testing, wear resistance and fatigue life tests. The modified surface was analyzed directly after plasma nitriding as well as using a depth profiling method. The microhardness after plasma nitriding is increased up to 19 GPa, that is a factor of five higher compared to the untreated material (3.3 GPa). The adhesion is examined by Rockwell indentation and scratch test. No delamination of the treated layer could be observed. The wear rate after plasma nitriding is significantly reduced compared to the untreated material. Plasma nitriding produces compressive stress inside the modified layer, which can be easily derived from the bending of thin metal foil, which was treated only on one side. The treatment influences the fatigue life, which can be raised by a factor of 10 at a low stress level (230 MPa). (orig.)

  2. Effect of cold work on low-temperature sensitization behaviour of austenitic stainless steels

    Science.gov (United States)

    Kain, V.; Chandra, K.; Adhe, K. N.; De, P. K.

    2004-09-01

    The effects of cold work and low-temperature sensitization heat treatment of non-sensitized austenitic stainless steels have been investigated and related to the cracking in nuclear power reactors. Types 304, 304L and 304LN developed martensite after 15% cold working. Heat treatment of these cold worked steels at 500 °C led to sensitization of grain boundaries and the matrix and a desensitization effect was seen in 11 days due to fast diffusion rate of chromium in martensite. Types 316L and 316LN did not develop martensite upon cold rolling due to its chemical composition suppressing the martensite transformation (due to deformation) temperature, hence these were not sensitized at 500 °C. The sensitization of the martensite phase was always accompanied by a hump in the reactivation current peak in the double loop electrochemical potentiokinetic reactivation test, thus providing a test to detect such sensitization. It was shown that bending does not produce martensite and therefore, is a better method to simulate weld heat affected zone. Bending and heating at 500 °C for 11 days led to fresh precipitation due to increased retained strain and desensitization of 304LN due to faster diffusion rate of chromium along dislocations. The as received or solution annealed 304 and 304LN with 0.15% nitrogen showed increased sensitization after heat treatment at 500 °C, indicating the presence of carbides/nitrides.

  3. The specific heat loss combined with the thermoelastic effect for an experimental analysis of the mean stress influence on axial fatigue of stainless steel plain specimens

    Directory of Open Access Journals (Sweden)

    G. Meneghetti

    2014-10-01

    Full Text Available The energy dissipated to the surroundings as heat in a unit volume of material per cycle, Q, was recently proposed by the authors as fatigue damage index and it was successfully applied to correlate fatigue data obtained by carrying out fully reversed stress- and strain-controlled fatigue tests on AISI 304L stainless steel plain and notched specimens. The use of the Q parameter to analyse the experimental results led to the definition of a scatter band having constant slope from the low- to the high-cycle fatigue regime. In this paper the energy approach is extended to analyse the influence of mean stress on the axial fatigue behaviour of unnotched cold drawn AISI 304L stainless steel bars. In view of this, stress controlled fatigue tests on plain specimens at different load ratios R (R=-1; R=0.1; R=0.5 were carried out. A new energy parameter is defined to account for the mean stress effect, which combines the specific heat loss Q and the relative temperature variation due to the thermoelastic effect corresponding to the achievement of the maximum stress level of the stress cycle. The new two-parameter approach was able to rationalise the mean stress effect observed experimentally. It is worth noting that the results found in the present contribution are meant to be specific for the material and testing condition investigated here.

  4. Development of a lean duplex stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Liljas, M.; Johansson, P.; Liu Hui-Ping; Olsson, C.O.A. [Avesta Research Centre, Avesta (Sweden). Outokumpu Stainless

    2008-06-15

    The classic series of duplex stainless steels shows very high corrosion resistance and can be used for very demanding applications. A new lean duplex steel, LDX 2101 {sup registered} (EN 1.4162, UNS S32101), has been developed with corrosion resistance on a par with standard austenitic grades. Application areas include: structural components, chemical industry, tanks and containers. The steel was designed to have equal amounts of ferrite and austenite in annealed condition and with an austenite that is stable against strain-induced martensite. Thanks to its high nitrogen content, the steel has a fast austenite reformation when subjected to thermal cycling, e.g. welding. Unlike conventional duplex grades, the formation of intermetallic phase is very sluggish, although precipitation of nitrides and carbides has a certain impact on material properties after exposure in the temperature range 600 to 800 C. The precipitation behaviour after different isothermal treatments is described and its influence on different product properties is shown. A good agreement was found between impact toughness and corrosion resistance for a wide range of thermal treatments. (orig.)

  5. Citric Acid Passivation of Stainless Steel

    Science.gov (United States)

    Yasensky, David; Reali, John; Larson, Chris; Carl, Chad

    2009-01-01

    Passivation is a process for cleaning and providing corrosion protection for stainless steel. Currently, on Kennedy Space Center (KSC), only parts passivated with nitric acid are acceptable for use. KSC disposes of approximately 125gal of concentrated nitric acid per year, and receives many parts from vendors who must also dispose of used nitric acid. Unfortunately, nitric acid presents health and environmental hazards. As a result, several recent industry studies have examined citric acid as an alternative. Implementing a citric acid-based passivation procedure would improve the health and environmental safety aspects of passivation process. However although there is a lack of published studies that conclusively prove citric acid is a technically sound passivation agent. In 2007, NASA's KSC Materials Advisory Working Group requested the evaluation of citric acid in place of nitric acid for passivation of parts at KSC. United Space Alliance Materials & Processes engineers have developed a three-phase test plan to evaluate citric acid as an alternative to nitric acid on three stainless steels commonly used at KSC: UNS S30400, S41000, and S17400. Phases 1 and 2 will produce an optimized citric acid treatment based on results from atmospheric exposure at NASA's Beach Corrosion Facility. Phase 3 will compare the optimized solution(s) with nitric acid treatments. If the results indicate that citric acid passivates as well or better than nitric acid, NASA intends to approve this method for parts used at the Kennedy Space Center.

  6. Carburization of stainless steel furnace tubes

    International Nuclear Information System (INIS)

    Stainless steel containing molybdenum are usually recommended to resist naphtenic acid corrosion in vacuum heaters. In 1993 the original 5Cr-1/2Mo roof tubes of the furnace in a vacuum unit were replaced by stainless steel 316 Ti to minimize tube replacement and increase heater reliability. Unexpectedly, some of the new tubes failed after only three years of service and just one year after undergoing the last inspection. The damage occurred in the form of deep holes and perforations, starting from the outside tube surface on the fireside. Coke build-up occurred due to severe operating conditions, overheating the tubes on the fireside, above 675 Centigrade. Metallographic and Scanning Electron Microscopy (Sem) examination revealed internal and external carburization of the material due to the presence of coke and combustion ashes, respectively. The increase in the skin metal temperature facilitated the diffusion of carbon from these carbon-rich deposits into the low carbon content material (0.023%). Depletion of chromium at the grain boundaries due to the massive formation of chromium carbides, resulted in a severe intergranular corrosion attack by molten salts rich in vanadium and sulfur produced by asphalt burning. Normal operating practice demands the use of steam for the heater tubes to control coke build-up. This practice had been first reduced and then eliminated, during the past two years prior to the failure, because of economic incentives. This paper describes the root cause analysis conducted to account for these premature tube failures. (Author)

  7. Fracture toughness of irradiated stainless steel alloys

    International Nuclear Information System (INIS)

    The postirradiation fracture toughness responses of Types 316 and 304 stainless steel (SS) wrought products, cast CF8 SS and Type 308 SS weld deposit were characterized at 4270C using J/sub R/-curve techniques. Fast-neutron irradiation of these alloys caused an order of magnitude reduction in J/sub c/ and two orders of magnitude reduction in tearing modulus at neutron exposures above 10 dpa, where radiation-induced losses in toughness appeared to saturate. Saturation J/sub c/ values for the wrought materials ranged from 28 to 31 kJ/m2; the weld exhibited a saturation level of 11 kJ/m2. Maximum allowable flaw sizes for highly irradiated stainless steel components stressed to 90% of the unirradiated yield strength are on the order of 3 cm for the wrought material and 1 cm for the weld. Electron fractographic examination revealed that irradiation displacement damage brought about a transition from ductile microvoid coalescence to channel fracture, associated with local separation along planar deformation bands. The lower saturation toughness value for the weld relative to that for the wrought products was attributed to local failure of ferrite particles ahead of the advancing crack which prematurely initiated channel fracture

  8. Embrittlement of austenitic stainless steel welds

    Energy Technology Data Exchange (ETDEWEB)

    David, S.A.; Vitek, J.M. [Oak Ridge National Lab., TN (United States). Metals and Ceramics Div.

    1997-12-31

    The microstructure of type-308 austenitic stainless steel weld metal containing {gamma} and {delta} and ferrite is shown. Typical composition of the weld metal is Cr-20.2, Ni-9.4, Mn-1.7, Si-0.5, C-0.05, N-0.06 and balance Fe (in wt %). Exposure of austenitic stainless steel welds to elevated temperatures can lead to extensive changes in the microstructural features of the weld metal. On exposure to elevated temperatures over a long period of time, a continuous network of M{sub 23}C{sub 6} carbide forms at the austenite/ferrite interface. Upon aging at temperatures between 550--850 C, ferrite in the weld has been found to be unstable and transforms to sigma phase. These changes have been found to influence mechanical behavior of the weld metal, in particular the creep-rupture properties. For aging temperatures below 550 C the ferrite decomposes spinodally into {alpha} and {alpha}{prime} phases. In addition, precipitation of G-phase occurs within the decomposed ferrite. These transformations at temperatures below 550 C lead to embrittlement of the weld metal as revealed by the Charpy impact properties.

  9. Corrosion behaviour of hyper duplex stainless steel in various metallurgical conditions for sea water cooled condensers

    International Nuclear Information System (INIS)

    The sea water cooled condensers have to resist severe corrosion as marine environment is the most corrosive natural environment. Copper alloys are being phased out due to difficulties in water chemistry control and Titanium base alloys are extremely expensive. Austenitic stainless steels (SS) remain prone to localized corrosion in marine environments hence not suitable. These heat exchangers operate at temperatures not exceeding 50 deg C and at very low pressures. The tubes of these heat exchangers are joined to the carbon steel tube sheets by roll expansion or by roll expansion followed by seam welding. These conditions are expected to affect the localized corrosion resistance of the tube in roll joined region due to cold working and in the tube-tube sheet welded joint due to thermal effects of welding. In this study, the localized corrosion behaviour of a Hyper Duplex Stainless Steel (HDSS) has been evaluated, and compared with other materials e.g. types 304L SS, 316L SS, Duplex SS 2205, Titanium grade - 2, and Al Brass. The evaluation is done in three metallurgical conditions (a) as received, (b) cold rolled and (c) welded condition in synthetic sea water at room temperature and at 50 deg C to assess the resistance to crevice, pitting and stress corrosion cracking using standard ASTM exposure and electrochemical techniques. The results provide comparative assessment of these alloys and show their susceptibility in the three metallurgical conditions as encountered in condensers. Hyper-duplex SS has been shown to be highly resistant in sea water for the condenser tubing application. (author)

  10. The Effect of Heat Treatments and Coatings on the Outgassing Rate of Stainless Steel Chambers

    Energy Technology Data Exchange (ETDEWEB)

    Mamum, Md Abdullah A. [Old Dominion Univ., Norfolk, VA (United States); Elmustafa, Abdelmageed A, [Old Dominion Univ., Norfolk, VA (United States); Stutzman, Marcy L. [JLAB, Newport News, VA (United States); Adderley, Philip A. [JLAB, Newport News, VA (United States); Poelker, Matthew [JLAB, Newport News, VA (United States)

    2014-03-01

    The outgassing rates of four nominally identical 304L stainless steel vacuum chambers were measured to determine the effect of chamber coatings and heat treatments. One chamber was coated with titanium nitride (TiN) and one with amorphous silicon (a-Si) immediately following fabrication. One chamber remained uncoated throughout, and the last chamber was first tested without any coating, and then coated with a-Si following a series of heat treatments. The outgassing rate of each chamber was measured at room temperatures between 15 and 30 deg C following bakes at temperatures between 90 and 400 deg C. Measurements for bare steel showed a significant reduction in the outgassing rate by more than a factor of 20 after a 400 deg C heat treatment (3.5 x 10{sup 12} TorrL s{sup -1}cm{sup -2} prior to heat treatment, reduced to 1.7 x 10{ sup -13} TorrL s{sup -1}cm{sup -2} following heat treatment). The chambers that were coated with a-Si showed minimal change in outgassing rates with heat treatment, though an outgassing rate reduced by heat treatments prior to a-Si coating was successfully preserved throughout a series of bakes. The TiN coated chamber exhibited remarkably low outgassing rates, up to four orders of magnitude lower than the uncoated stainless steel. An evaluation of coating composition suggests the presence of elemental titanium which could provide pumping and lead to an artificially low outgassing rate. The outgassing results are discussed in terms of diffusion-limited versus recombination-limited processes.

  11. Contribution to the study of physico-chemical properties of surfaces modified by laser treatment. Application to the enhancement of localized corrosion resistance of stainless steels

    International Nuclear Information System (INIS)

    Metallic materials are more and more used in severe conditions with particularly strong request for improving their behavior in aggressive environment and especially over long periods. The objective of this PhD work is to estimate the potentiality of a laser surface melting treatment on the improvement of the stainless steel 304L corrosion resistance, surface treatments by laser can be revisited on the basis of a recent change in the laser technology. In the frame of this work, a nano-pulsed laser fiber was chosen: it allows the treated surface to be melted for few microns in depth, followed by an ultra-fast solidification occurring with cooling rates up to 1011 K/s. The combination of these processes leads to the elimination of the surface defects, the formation (trapping) of metastable phases, the segregation of chemical elements and the growth of a new oxide layer which properties are governed by the laser parameters. To correlate these latter to the electrochemical reactivity of the surface, the influence of two laser parameters on the physico-chemical properties of the surface was studied: the laser power and the overlap of the laser impacts. To support this approach, the pitting corrosion resistance of the samples was determined by standard electrochemical tests. For specific laser parameters, the pitting potential of a 304L stainless steel was increased by more than 500 mV corresponding to an important enhancement in localized corrosion resistance in chloride environment. The interdependence of the different phenomena resulting from the laser treatment lead to a quite complex prioritization of their role on the sensibility of the 304L. However, it was demonstrated that the nature of the thermal oxide formed during the laser surface melting and the induced defects are first-order parameters for the initiation of pits. (author)

  12. Assessment of thermal embrittlement of cast stainless steels

    International Nuclear Information System (INIS)

    A procedure and correlations are presented for assessing thermal embrittlement and predicting Charpy-impact energy and fracture toughness J-R curve of cast stainless steel components under Light Water Reactor operating conditions from known material information. The ''saturation'' impact strength and fracture toughness of a specific cast stainless steel, i.e., the minimum value that would be achieved for the material after long-term service, is estimated from the chemical composition of the steel. Fracture properties as a function of time and temperature of reactor service are estimated from the kinetics of embrittlement, which are also determined from chemical composition. A common ''predicted lower-bound'' J-R curve for cast stainless steels of unknown chemical composition is also defined for a given grade of steel, ferrite content, and temperature. Examples of estimating fracture toughness of cast stainless steel components during reactor service are presented

  13. EXPERIMENTAL RESEARCH OF THE DUPLEX STAINLESS STEEL WELDS IN SHIPBUILDING

    OpenAIRE

    Juraga, Ivan; Stojanović, Ivan; Ljubenkov, Boris

    2014-01-01

    Duplex stainless steel is used in shipbuilding increasingly because of its good mechanical properties and marked corrosion resistance. This steel has a two phase structure (austenite-ferrite) which is sensitive on heat input during welding because of the possible ferritisation appearance, that is, increase in ferrite content in the area of heat effected zone (HAZ) which can lead to loss of mechanical and corrosion properties. Work with duplex stainless steel requires special attention in ever...

  14. Initiation of stress corrosion cracking in pre-stained austenitic stainless steels exposed to primary water

    International Nuclear Information System (INIS)

    Austenitic stainless steels are widely used in primary circuits of Pressurized Water Reactors (PWR) plants. However, a limited number of cases of Intergranular Stress Corrosion Cracking (IGSCC) has been detected in cold-worked (CW) areas of non-sensitized austenitic stainless steel components in French PWRs. A previous program launched in the early 2000's identified the required conditions for SCC of cold-worked stainless steels. It was found that a high strain hardening coupled with a cyclic loading favoured SCC. The present study aims at better understanding the role of pre-straining on crack initiation and at developing an engineering model for IGSCC initiation of 304L and 316L stainless steels in primary water. Such model will be based on SCC initiation tests on notched (not pre-cracked) specimens under 'trapezoidal' cyclic loading. The effects of pre-straining (tensile versus cold rolling), cold-work level and strain path on the SCC mechanisms are investigated. Experimental results demonstrate the dominating effect of strain path on SCC susceptibility for all pre-straining levels. Initiation can be understood as crack density and crack depth. A global criterion has been proposed to integrate both aspects of initiation. Maps of SCC initiation susceptibility have been proposed. A critical crack depth between 10 and 20 μm has been demonstrated to define transition between slow propagation and fast propagation for rolled materials. For tensile pre-straining, the critical crack depth is in the range 20 - 50 μm. Experimental evidences support the notion of a KISCC threshold, whose value depends on materials, pre-straining ant load applied. The initiation time has been found to depend on the applied loading as a function of (σmaxmax/YV)11,5. The effect of both strain path and surface hardening is indirectly taken into account via the yield stress. In this study, material differences rely on strain path effect on mechanical properties. As a result, a stress high

  15. Nickel-free Stainless Steel for Medical Applications

    Institute of Scientific and Technical Information of China (English)

    Yibin REN; Ke YANG; Bingchun ZHANG; Yaqing WANG; Yong LIANG

    2004-01-01

    BIOSS4 steel is essentially a nickel-free austenitic stainless steel developed by the Institute of Metal Research, Chinese Academy of Sciences, in response to nickel allergy problems associated with nickel-containing stainless steels that are widely used in medical applications. The high nitrogen content of this steel effectively maintains the austenitic stability and also contributes to the high levels of corrosion resistance and strength. BIOSS4 steel possesses a good combination of high strength and toughness, better corrosion resistance, and better blood compatibility, in comparison with the medical 316L stainless steel. Potential applications of BIOSS4 steel can include medical implantation material and orthodontic or orthopedic devices, as well as jewelries and other decorations.

  16. In vivo behavior of a high performance duplex stainless steel.

    Science.gov (United States)

    Cigada, A; De Santis, G; Gatti, A M; Roos, A; Zaffe, D

    1993-01-01

    An in vivo investigation of a new high molybdenum and nitrogen duplex stainless steel (25Cr--7Ni--4Mo--0.3N) has been performed. Cylindrical pins and specially developed devices, to test in static conditions the in vivo localized corrosion resistance, made of this new duplex steel and of a common austenitic stainless steel were implanted in rabbit's femurs for 6 and 12 months. After sacrifice, SEM observations and EDS microanalyses to detect metallic ion release were carried out on the femur sections surrounding the pins. Morphologic observations with stereoscope and SEM were performed on the metallic surfaces of the special devices in order to detect the presence of localized corrosion. Both ion release and localized corrosion were observed for the specimens made of austenitic stainless steel, but not for those made of 25Cr--7Ni--4Mo--0.3N duplex stainless steel. PMID:10148344

  17. Microbial-Influenced Corrosion of Corten Steel Compared with Carbon Steel and Stainless Steel in Oily Wastewater by Pseudomonas aeruginosa

    Science.gov (United States)

    Mansouri, Hamidreza; Alavi, Seyed Abolhasan; Fotovat, Meysam

    2015-07-01

    The microbial corrosion behavior of three important steels (carbon steel, stainless steel, and Corten steel) was investigated in semi petroleum medium. This work was done in modified nutrient broth (2 g nutrient broth in 1 L oily wastewater) in the presence of Pseudomonas aeruginosa and mixed culture (as a biotic media) and an abiotic medium for 2 weeks. The behavior of corrosion was analyzed by spectrophotometric and electrochemical methods and at the end was confirmed by scanning electron microscopy. The results show that the degree of corrosion of Corten steel in mixed culture, unlike carbon steel and stainless steel, is less than P. aeruginosa inoculated medium because some bacteria affect Corten steel less than other steels. According to the experiments, carbon steel had less resistance than Corten steel and stainless steel. Furthermore, biofilm inhibits separated particles of those steels to spread to the medium; in other words, particles get trapped between biofilm and steel.

  18. Compressibility of 304 Stainless Steel Powder Metallurgy Materials Reinforced with 304 Short Stainless Steel Fibers

    Directory of Open Access Journals (Sweden)

    Bibo Yao

    2016-03-01

    Full Text Available Powder metallurgy (P/M technique is usually used for manufacturing porous metal materials. However, some P/M materials are limitedly used in engineering for their performance deficiency. A novel 304 stainless steel P/M material was produced by a solid-state sintering of 304 stainless steel powders and 304 short stainless steel fibers, which were alternately laid in layers according to mass ratio. In this paper, the compressive properties of the P/M materials were characterized by a series of uniaxial compression tests. The effects of fiber content, compaction pressure and high temperature nitriding on compressive properties were investigated. The results indicated that, without nitriding, the samples changed from cuboid to cydariform without damage in the process of compression. The compressive stress was enhanced with increasing fiber content ranging from 0 to 8 wt.%. For compaction pressure from 55 to 75 MPa, greater compaction pressure improved compressive stress. Moreover, high temperature nitriding was able to significantly improve the yield stress, but collapse failure eventually occurred.

  19. A mortality study among mild steel and stainless steel welders.

    Science.gov (United States)

    Moulin, J J; Wild, P; Haguenoer, J M; Faucon, D; De Gaudemaris, R; Mur, J M; Mereau, M; Gary, Y; Toamain, J P; Birembaut, Y

    1993-03-01

    A mortality study was carried out in conjunction with the European mortality study among welders coordinated by the International Agency for Research on Cancer (IARC). The study was aimed at assessing risks for lung cancer in relation to exposure to asbestos, welding fumes containing chromium and nickel, and tobacco smoke. The study included a cohort of 2721 welders and an internal comparison group of 6683 manual workers employed in 13 factories in France. The mortality of the two cohorts was studied from 1975 to 1988 by the historical prospective method. Job histories of welders were traced including welding processes used, metals welded, and proportion of worktime spent in welding. Data on smoking habits were collected from medical records. The observed number of deaths were compared with those expected (standardised mortality ratio (SMR)) based on national rates with adjustments for age, sex, and calendar time. The smoking habits of 87% of the whole study population were known. The distribution of welders and controls according to smoking was not statistically different. The overall mortality was slightly higher for welders (SMR = 1.02, 95% confidence interval (95% CI) 0.89-1.18) than for controls (SMR = 0.91, 95% CI 0.84-0.99). For lung cancer, the SMR was 1.24 (95% CI 0.75-1.94) for welders, whereas the corresponding value was lower for controls (SMR = 0.94, 95% CI 0.68-1.26). The SMR for lung cancer was 1.59 among non-shipyard mild steel welders (95% CI 0.73-3.02). This contrasted with the results for all stainless steel welders (SMR = 0.92, 95% CI 0.19-2.69), and for stainless steel welders predominantly exposed to chromium VI (SMR = 1.03, 95% CI 0.12-3.71). Moreover, SMRs for lung cancer for mild steel welders tended to increase with duration of exposure and time since first exposure, leading to significant excesses for duration > or = 20 years and latency > or = 20 years. Such a pattern was not found for stainless steel welders.

  20. Nitrogen bearing austenitic stainless steels for surgical implants

    Energy Technology Data Exchange (ETDEWEB)

    Tschiptschin, A.P.; Aidar, C.H.; Alonso-Falleiros, N. [Sao Paulo Univ. (Brazil). Escola Politecnica; Neto, F.B. [Instituto de Pesquisas Tecnologicas, Sao Paulo (Brazil)

    1999-07-01

    Nitrogen addition promotes substantial improvements on general and localized corrosion performance of stainless steels. In recent times high nitrogen (up to 0.6 wt%) and Mn bearing super austenitic stainless steel has been studied for medical applications due to its low Ni content, the so called body friendly alloys. 18%Cr, 0.4%N and 15%Mn stainless steels were cast either from electrolytic or commercial master alloys in induction furnace, forged, solubilized at 1423K for 3 hours and water quenched. Delta ferrite and carbide precipitate free structures were observed. (orig.)

  1. Structural Analysis of Cavitation for Different Stainless Steels

    Directory of Open Access Journals (Sweden)

    Mădălina-Elena Mânzână

    2011-09-01

    Full Text Available The cavitation phenomenon is currently approaching all areas of technology and modern industry, where are fluid in motion. In this paper cavitational erosion was conducted on different samples of stainless steels. The cavitation were performed in magnetostrictive vibrating apparatus at Cavitation Laboratory (Polytechnic University of Timisoara. The present paper intends to identify specific structural features in stainless steels. Several investigations were done: macrostructural analysis (Olympus SZX57, scaning electron microscope (Philips SEM and X-ray diffraction (D8 ADVANCE. After quantitative and qualitative investigations structural features were put in evidence on experimental stainless steels.

  2. Investigation of the Hot Plasticity of Duplex Stainless Steel

    Institute of Scientific and Technical Information of China (English)

    LIN Gang; ZHANG Zhi-xia; SONG Hong-wei; TONG Jun; ZHOU Can-dong

    2008-01-01

    Hot plasticity of a nitrogen alloyed 25Cr-7Ni-4 Mo duplex stainless steel was investigated.The results indicate that thc main factors affecting the hot plasticity of duplex stainless steel are listed as follows:coalescent force of phase interface,microstructure,and the phase ratio and difference between the mechanicsl propertms of ferrite and austenite.The heat treatment and sulphur contents have a notable effect on the hot plasticity.The reasonable heat treatrnents and the irlcreased interfacial coalescent force will effectively enhance the hot plasticity of duplex stainless steel.

  3. Magnetic characterisation of duplex stainless steel

    Science.gov (United States)

    Mészáros, I.

    2006-02-01

    Heat treatment-induced microstructural processes were studied by different non-destructive magnetic and mechanical material testing methods in the present work. A commercial SAF 2507 type superduplex stainless steel was investigated. This alloy contains about 40% metastable ferrite which can decompose to a sigma phase and secondary austenite due to heat treatment. All the mechanical, corrosion resistance and magnetic properties are strongly influenced by this microstructural changes. This study had two aims: to understand better the kinetics of the ferrite decomposition process and to study the application possibilities of the applied magnetic measurements. This paper presents an application possibility of the nonlinear harmonics analysis measurement and demonstrates the possibility to find a quantitative correlation between measured harmonics and mechanical properties obtained from destructive tests.

  4. Electrochemical decontamination of Pu contaminated stainless steel

    International Nuclear Information System (INIS)

    Electrochemical decontamination has been demonstrated to be very effective in removing plutonium nitrate contamination (0.5 μg cm-2) on stainless steels. The amount of metal dissolved to achieve a DF of 102 to 103 was 2 to 7 μm depending on the electrolyte used. In unstirred electrolytes 1M HNO3, 1M HNO3/0.1M NaF, 5M HNO3 perform best. Under stirred electrolyte conditions, there is a general marginal fall in effectiveness except for 5M HNO3 where there is a slight improvement. The optimum performance is a compromise between maximizing the electrolyte throwing power and minimizing substrate surface roughening during decontamination. (author)

  5. MOCVD deposition of YSZ on stainless steels

    Science.gov (United States)

    Chevalier, S.; Kilo, M.; Borchardt, G.; Larpin, J. P.

    2003-01-01

    Yttria stabilized zirconia was deposited on stainless steel using the metal-organic chemical vapor deposition (MOCVD) technique, from β-diketonate precursors. The variation of the evaporation temperatures of yttrium and zirconium precursor allowed to control the level of Y within the film. Over the temperature range 125-150 °C, the Y content increased from 2.5 to 17.6 at.%. X-ray diffraction (XRD) analyses evidenced tetragonal phase of zirconia when the Y content was below 8 at.%, and cubic phase for higher concentration. Sputtered neutral mass spectrometry (SNMS) profiles confirmed that the control and stability of Y precursor temperature were of major importance to guarantee the homogeneity of the deposited films.

  6. A stainless steel bracket for orthodontic application.

    Science.gov (United States)

    Oh, Keun-Taek; Choo, Sung-Uk; Kim, Kwang-Mahn; Kim, Kyoung-Nam

    2005-06-01

    Aesthetics has become an essential element when choosing orthodontic fixed appliances. Most metallic brackets used in orthodontic therapy are made from stainless steel (SS) with the appropriate physical properties and good corrosion resistance, and are available as types 304, 316 and 17-4 PH SS. However, localized corrosion of these materials can frequently occur in the oral environment. This study was undertaken to evaluate the accuracy of sizing, microstructure, hardness, corrosion resistance, frictional resistance and cytotoxicity of commercially available Mini-diamond (S17400), Archist (S30403) and experimentally manufactured SR-50A (S32050) brackets. The size accuracy of Mini-diamond was the highest at all locations except for the external horizontal width of the tie wing (P SS brackets. PMID:15947222

  7. MICROSCOPIC CORROSION STUDIES OF DUPLEX STAINLESS STEELS

    Institute of Scientific and Technical Information of China (English)

    C.Leygraf; J.Pan; M.Femenia

    2004-01-01

    Electrochemical scanning tunneling microscopy and scanning electrochemical microscopy have been used for in situ monitoring of localized corrosion processes of different Duplex stainless steels (DSS) in acidic chloride solutions. The techniques allow imaging of local dissolution events with micrometer resolution, as opposed to conventional electrochemical techniques, which only give an overall view of the corrosion behavior. In addition, combined scanning Kelvin probe force microscopy and magnetic force microscopy were used for mapping the Volta potential variation over the surface of DSSs. A significant difference in Volta potential between the austenite and ferrite phases suggests galvanic interaction between the phases. A compositional gradient appears within 2 micrometers across the phase boundary, as seen with scanning Auger microscopy (SAM). In all, the studies suggest that higher alloyed DSS exhibit a more homogeneous dissolution behavior than lower alloyed DSS, due to higher and more similar corrosion resistance of the two phases, and enhanced resistance of the ferrite/austenite phase boundary regions.

  8. Thermal fatigue crack growth in stainless steel

    International Nuclear Information System (INIS)

    A judgment of residual service life of engineering parts exposed to thermal fatigue makes it possible to deal with economic and safety issues in power plants. The aim of this study is to analyze a fatigue crack initiation and propagation in A321 stainless steel bodies subjected to repeated thermal shocks. For this purpose, various methods of crack propagation monitoring were used. The first stage of experiments included mechanical cyclic loading of specimens with the central notch at fixed temperatures ranging from 20 °C to 410 °C. The crack growth rate was only minimally influenced by temperature in this case. Thermal loading of the same specimens with ΔT varying from 150 °C to 340 °C showed very rapid crack initiation in the notches and its asymmetric growth. Metallographic and fractographic analyses of failed specimens were carried out after 1000, 3000 and 6000 thermal cycles. The comparison of the fracture surface micromorphology confirmed the similarity in the mechanism of the thermal and mechanical fatigue crack growth. Stress analysis using the finite element method consisting of transient thermal and mechanical solutions was performed in order to simulate the experiments. Thermal fatigue crack growth assessment was carried out on the basis of the experiments and the computed thermally induced stress intensity factors. This model successfully confirms the discussed analogy of thermal and mechanical stress induced damage. Highlights: ► A fatigue crack initiation and propagation in A321 stainless steel was analyzed. ► Mechanical and thermal experiments were performed, simulated also by FEM. ► Similarity in the mechanism of thermal and mechanical fatigue crack growth found. ► Application of the Paris model for the thermal cycling confirmed.

  9. Behaviour and design of cold-formed lean duplex stainless steel members

    OpenAIRE

    Huang, Yun'er; 黃韵兒

    2013-01-01

    Cold-formed stainless steel sections have been increasingly used in architectural and structural applications. Yet the high price of stainless steel limits the application to construction projects. The lean duplex stainless steel (EN 1.4162) offers an opportunity for stainless steels to be used more widely due to its competitive in price, good mechanical properties and corrosion resistance. The lean duplex stainless steel is a relatively new material, and research on this material is limited....

  10. Effects of Cr2N Precipitation on the Antibacterial Properties of AISI 430 Stainless Steel

    OpenAIRE

    Je-Kang Du; Chih-Yeh Chao; Yu-Ting Jhong; Chung-Hao Wu; Ju-Hui Wu

    2016-01-01

    Based on their mechanical properties and good corrosion resistance, some commercial Ni-Cr stainless steels have been widely applied as biomaterials, including the austenitic 304 stainless steel, the austenitic 316 stainless steel, the duplex 2205 stainless steel, and the ferritic 430 stainless steel. In order to reduce the occurrence of infections resulting from biomaterial implants, instruments, and medical devices, Cu2+ and Ag2+ ions have been added onto biomaterials for increasing the anti...

  11. Stainless steel anodes for alkaline water electrolysis and methods of making

    Science.gov (United States)

    Soloveichik, Grigorii Lev

    2014-01-21

    The corrosion resistance of stainless steel anodes for use in alkaline water electrolysis was increased by immersion of the stainless steel anode into a caustic solution prior to electrolysis. Also disclosed herein are electrolyzers employing the so-treated stainless steel anodes. The pre-treatment process provides a stainless steel anode that has a higher corrosion resistance than an untreated stainless steel anode of the same composition.

  12. Bacterial adhesion on ion-implanted stainless steel surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Q. [Department of Mechanical Engineering, University of Dundee, Dundee DD1 4HN (United Kingdom)]. E-mail: q.zhao@dundee.ac.uk; Liu, Y. [Department of Mechanical Engineering, University of Dundee, Dundee DD1 4HN (United Kingdom); Wang, C. [Department of Mechanical Engineering, University of Dundee, Dundee DD1 4HN (United Kingdom); Wang, S. [Department of Mechanical Engineering, University of Dundee, Dundee DD1 4HN (United Kingdom); Peng, N. [Surrey Ion Beam Centre, University of Surrey, Surrey GU2 7XH (United Kingdom); Jeynes, C. [Surrey Ion Beam Centre, University of Surrey, Surrey GU2 7XH (United Kingdom)

    2007-08-31

    Stainless steel disks were implanted with N{sup +}, O{sup +} and SiF{sub 3} {sup +}, respectively at the Surrey Ion Beam Centre. The surface properties of the implanted surfaces were analyzed, including surface chemical composition, surface topography, surface roughness and surface free energy. Bacterial adhesion of Pseudomonas aeruginosa, Staphylococcus epidermidis and Staphylococcus aureus, which frequently cause medical device-associated infections was evaluated under static condition and laminar flow condition. The effect of contact time, growth media and surface properties of the ion-implanted steels on bacterial adhesion was investigated. The experimental results showed that SiF{sub 3} {sup +}-implanted stainless steel performed much better than N{sup +}-implanted steel, O{sup +}-implanted steel and untreated stainless steel control on reducing bacterial attachment under identical experimental conditions.

  13. Bacterial adhesion on ion-implanted stainless steel surfaces

    International Nuclear Information System (INIS)

    Stainless steel disks were implanted with N+, O+ and SiF3+, respectively at the Surrey Ion Beam Centre. The surface properties of the implanted surfaces were analyzed, including surface chemical composition, surface topography, surface roughness and surface free energy. Bacterial adhesion of Pseudomonas aeruginosa, Staphylococcus epidermidis and Staphylococcus aureus, which frequently cause medical device-associated infections was evaluated under static condition and laminar flow condition. The effect of contact time, growth media and surface properties of the ion-implanted steels on bacterial adhesion was investigated. The experimental results showed that SiF3+-implanted stainless steel performed much better than N+-implanted steel, O+-implanted steel and untreated stainless steel control on reducing bacterial attachment under identical experimental conditions

  14. Bacterial adhesion on ion-implanted stainless steel surfaces

    Science.gov (United States)

    Zhao, Q.; Liu, Y.; Wang, C.; Wang, S.; Peng, N.; Jeynes, C.

    2007-08-01

    Stainless steel disks were implanted with N +, O + and SiF 3+, respectively at the Surrey Ion Beam Centre. The surface properties of the implanted surfaces were analyzed, including surface chemical composition, surface topography, surface roughness and surface free energy. Bacterial adhesion of Pseudomonas aeruginosa, Staphylococcus epidermidis and Staphylococcus aureus, which frequently cause medical device-associated infections was evaluated under static condition and laminar flow condition. The effect of contact time, growth media and surface properties of the ion-implanted steels on bacterial adhesion was investigated. The experimental results showed that SiF 3+-implanted stainless steel performed much better than N +-implanted steel, O +-implanted steel and untreated stainless steel control on reducing bacterial attachment under identical experimental conditions.

  15. Further investigation of the structure and properties of austenitic stainless steel after plasma nitriding

    Energy Technology Data Exchange (ETDEWEB)

    Menthe, E.; Rie, K.-T. [Technische Univ. Braunschweig (Germany). Inst. fuer Oberflaechentechnik und Plasmatechnische Werkstoffentwicklung

    1999-09-01

    A series of plasma nitriding experiments has been conducted on AISI 304L austenitic stainless steel at temperatures ranging from 375 to 475 C using pulsed-DC plasma with different pulse duty cycles, N{sub 2}-H{sub 2} gas mixtures and treatment times. It is shown that a wide range of treatment parameters exist that allow the formation of the S-phase. The formation and growth of this surface layer depend strongly on the treatment parameters, such as nitrogen partial pressure and duty cycle. Within the parameter range investigated, the layer growth appears to be diffusion controlled with an activation energy about 107 kJ/mol. The formation of CrN precipitates during plasma nitriding is not accompanied by the formation of bcc iron, which might be expected due to the loss of free chromium. However, the S-phase transforms into CrN and bcc iron following a heat treatment at 450 C or higher for 25 h. The wear rate after plasma nitriding is greatly reduced compared with the untreated material. (orig.)

  16. Reliability of welded austenitic stainless steel containing base metal delta ferrite

    Energy Technology Data Exchange (ETDEWEB)

    Shalaby, Hamdy M. [Kuwait Institute for Scientific Research (Kuwait)

    2004-07-01

    The paper presents the results of a failure case study carried out on welded 304L stainless steel (SS) pipeline of waste gas header (WGH). The environment inside the WGH was mainly wet steam with hydrocarbons, H{sub 2}S, oxygen, CO{sub 2}, organic acids, and organic chlorides. The outside pipe wall temperature was 91-97 deg C. The failure of the pipe was at the heat-affected zone (HAZ). The study was made on four welded pipeline samples, three of which were in service. The pipe samples were welded using three different techniques that included autogenous gas tungsten arc, shielded metal arc, and flux core arc. The investigation revealed that cracking at HAZ was due to base metal delta ferrite decay accompanied with sigma phase formation due to high heat input during welding. However, the morphology and orientation of the cracks suggested that stress-rupture and stress corrosion cracking had occurred. The presence of base metal delta ferrite made all used welding procedures un-successful. The study concluded that utilization of delta ferrite free austenitic SS should eliminate the problem. (author)

  17. Effect of tritium and decay helium on the fracture toughness properties of stainless steel weldments

    International Nuclear Information System (INIS)

    J-Integral fracture toughness tests were conducted on tritium-exposed-and- aged Types 304L and 21-6-9 stainless steel weldments in order to measure the combined effects of tritium and its decay product, helium-3 on the fracture toughness properties. Initially, weldments have fracture toughness values about three times higher than base-metal values. Delta-ferrite phase in the weld microstructure improved toughness provided no tritium was present in the microstructure. After a tritium-exposure-and-aging treatment that resulted in ∼1400 atomic parts per million (appm) dissolved tritium, both weldments and base metals had their fracture toughness values reduced to about the same level. The tritium effect was greater in weldments (67 % reduction vs. 37% reduction) largely because the ductile discontinuous delta-ferrite phase was embrittled by tritium and decay helium. For both base metals and weldments, fracture toughness values decreased with increasing decay helium content in the range tested (50-800 appm). (authors)

  18. Effects of stop-start features on residual stresses in a multipass austenitic stainless steel weld

    Energy Technology Data Exchange (ETDEWEB)

    Turski, M., E-mail: Mark.Turski@magnesium-elektron.com [School of Materials, University of Manchester, Grosvenor Street, Manchester M1 7HS (United Kingdom); Francis, J.A. [School of Materials, University of Manchester, Grosvenor Street, Manchester M1 7HS (United Kingdom)] [Materials Engineering, Open University, Walton Hall, Milton Keynes MK7 6AA (United Kingdom); Hurrell, P.R. [Rolls-Royce Plc., Raynesway, Derby DE21 7XX (United Kingdom); Bate, S.K. [Serco Technical Services, Birchwood Park, Warrington, Cheshire WA3 6GA (United Kingdom); Hiller, S. [Materials Engineering, Open University, Walton Hall, Milton Keynes MK7 6AA (United Kingdom); Withers, P.J. [School of Materials, University of Manchester, Grosvenor Street, Manchester M1 7HS (United Kingdom)

    2012-01-15

    In this article we describe experiments that characterise and quantify the localised perturbations in residual stress associated with both ramped and abrupt stop-start features in a multipass weld. Residual stress distributions in AISI Grade 304L/308L stainless steel groove-welded specimens, containing weld interruptions that were introduced in a controlled manner, have been characterised using both neutron diffraction and the incremental deep hole drilling method. The extent to which the localised stresses associated with the interruptions were annealed by overlayed passes was also assessed. The results suggest that, regardless of the type of interruption, there can be significant localised increases in residual stress if the stop-start feature is left exposed. If further weld passes are deposited, then the localised increases in stress are likely to persist if the interruption was abrupt, whereas for a ramped interruption they may be dissipated. - Highlights: Black-Right-Pointing-Pointer In this study the residual stress-field surrounding weld interruptions was measured. Black-Right-Pointing-Pointer Localised stresses were found to increase at weld interruptions. Black-Right-Pointing-Pointer Both ramped and abrupt weld interruptions were investigated. Black-Right-Pointing-Pointer After subsequent weld passes, localised stresses persisted for abrupt interruptions. Black-Right-Pointing-Pointer After subsequent weld passes, localised stresses dissipated for ramped interruptions.

  19. Phase Transformations in Cast Duplex Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Yoon-Jun Kim

    2004-12-19

    Duplex stainless steels (DSS) constitute both ferrite and austenite as a matrix. Such a microstructure confers a high corrosion resistance with favorable mechanical properties. However, intermetallic phases such as {sigma} and {chi} can also form during casting or high-temperature processing and can degrade the properties of the DSS. This research was initiated to develop time-temperature-transformation (TTT) and continuous-cooling-transformation (CCT) diagrams of two types of cast duplex stainless steels, CD3MN (Fe-22Cr-5Ni-Mo-N) and CD3MWCuN (Fe-25Cr-7Ni-Mo-W-Cu-N), in order to understand the time and temperature ranges for intermetallic phase formation. The alloys were heat treated isothermally or under controlled cooling conditions and then characterized using conventional metallographic methods that included tint etching, and also using electron microscopy (SEM, TEM) and wavelength dispersive spectroscopy (WDS). The kinetics of intermetallic-phase ({sigma} + {chi}) formation were analyzed using the Johnson-Mehl-Avrami (MA) equation in the case of isothermal transformations and a modified form of this equation in the case of continuous cooling transformations. The rate of intermetallic-phase formation was found to be much faster in CD3MWCuN than CD3MN due mainly to differences in the major alloying contents such as Cr, Ni and Mo. To examine in more detail the effects of these elements of the phase stabilities; a series of eight steel castings was designed with the Cr, Ni and Mo contents systematically varied with respect to the nominal composition of CD3MN. The effects of varying the contents of alloying additions on the formation of intermetallic phases were also studied computationally using the commercial thermodynamic software package, Thermo-Calc. In general, {sigma} was stabilized with increasing Cr addition and {chi} by increasing Mo addition. However, a delicate balance among Ni and other minor elements such as N and Si also exists. Phase equilibria in

  20. Phase transformations in cast duplex stainless steels

    Science.gov (United States)

    Kim, Yoon-Jun

    Duplex stainless steels (DSS) constitute both ferrite and austenite as a matrix. Such a microstructure confers a high corrosion resistance with favorable mechanical properties. However, intermetallic phases such as sigma (sigma) and chi (chi) can also form during casting or high-temperature processing and can degrade the properties of the DSS. This research was initiated to develop time-temperature-transformation (TTT) and continuous-cooling-transformation (CCT) diagrams of two types of cast duplex stainless steels, CD3MN (Fe-22Cr-5Ni-Mo-N) and CD3MWCuN (Fe-25Cr-7Ni-Mo-W-Cu-N), in order to understand the time and temperature ranges for intermetallic phase formation. The alloys were heat treated isothermally or under controlled cooling conditions and then characterized using conventional metallographic methods that included tint etching, and also using electron microscopy (SEM, TEM) and wavelength dispersive spectroscopy (WDS). The kinetics of intermetallic-phase (sigma + chi) formation were analyzed using the Johnson-Mehl-Avrami (JMA) equation in the case of isothermal transformations and a modified form of this equation in the case of continuous cooling transformations. The rate of intermetallic-phase formation was found to be much faster in CD3MWCuN than CD3MN due mainly to differences in the major alloying contents such as Cr, Ni and Mo. To examine in more detail the effects of these elements of the phase stabilities, a series of eight steel castings was designed with the Cr, Ni and Mo contents systematically varied with respect to the nominal composition of CD3MN. The effects of varying the contents of alloying additions on the formation of intermetallic phases were also studied computationally using the commercial thermodynamic software package, Thermo-Calc. In general, a was stabilized with increasing Cr addition and chi by increasing Mo addition. However, a delicate balance among Ni and other minor elements such as N and Si also exists. Phase equilibria in

  1. Eddy sensors for small diameter stainless steel tubes.

    Energy Technology Data Exchange (ETDEWEB)

    Skinner, Jack L.; Morales, Alfredo Martin; Grant, J. Brian; Korellis, Henry James; LaFord, Marianne Elizabeth; Van Blarigan, Benjamin; Andersen, Lisa E.

    2011-08-01

    The goal of this project was to develop non-destructive, minimally disruptive eddy sensors to inspect small diameter stainless steel metal tubes. Modifications to Sandia's Emphasis/EIGER code allowed for the modeling of eddy current bobbin sensors near or around 1/8-inch outer diameter stainless steel tubing. Modeling results indicated that an eddy sensor based on a single axial coil could effectively detect changes in the inner diameter of a stainless steel tubing. Based on the modeling results, sensor coils capable of detecting small changes in the inner diameter of a stainless steel tube were designed, built and tested. The observed sensor response agreed with the results of the modeling and with eddy sensor theory. A separate limited distribution SAND report is being issued demonstrating the application of this sensor.

  2. Controlled dissolution of colossal quantities of nitrogen in stainless steel

    DEFF Research Database (Denmark)

    Christiansen, Thomas; Somers, Marcel A. J.

    2006-01-01

    The solubility of nitrogen in austenitic stainless steel was investigated thermogravimetrically by equilibrating thin foils of AISI 304 and AISI 316 in ammonia/hydrogen gas mixtures. Controlled dissolution of colossal amounts of nitrogen under metastable equilibrium conditions was realized...

  3. Development of oxide dispersion strengthened 2205 duplex stainless steel composite

    Directory of Open Access Journals (Sweden)

    Oladayo OLANIRAN

    2015-05-01

    Full Text Available Composites of duplex stainless steel were produced by oxide dispersion strengthening with comparatively improved mechanical properties by hot press sintering of partially stabilized Zirconia (PSZ, 3% yttria, mole fraction dispersion in 2205 duplex stainless steels. Ceramic oxide was added as reinforcement, while chromium (Cr and Nickel (Ni were incorporated to maintain the austenitic/ferritic phase balance of the duplex stainless steel. The powders and sintered were characterized in detail using scanning electron microscopy (SEM and X-ray diffraction (XRD. The microstructural evolution and phase formation during oxide dispersion strengthening of duplex stainless steel composites were investigated. The influence of composition variation of the reinforcements on the microstructural and corrosion behaviour in simulated mine water of the composites were investigated. In this manuscript, it was established that composition has great influence on the structure/properties relationship of the composites developed.

  4. Stainless steels and special grades for specific applications

    International Nuclear Information System (INIS)

    The development of special steels grades with a composition between stainless steels and nickel alloys for localised corrosion resistance applications (steam condenser, combustion products de-pollution...) are shortly presented by family (austenitic and super-austenitic stainless steels of the URANUS family with or without nitrogen additions, austeno-ferritic steels), with electrochemistry corrosion tests evaluation : in standard medium (30 g/l NaCl + 6% FeCl3) or in real medium. (A.B.). 6 refs., 12 figs., 2 tabs

  5. Fatigue crack growth in metastable austenitic stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Mei, Z.; Chang, G.; Morris, J.W. Jr.

    1988-06-01

    The research reported here is an investigation of the influence of the mechanically induced martensitic transformation on the fatigue crack growth rate in 304-type steels. The alloys 304L and 304LN were used to test the influence of composition, the testing temperatures 298 K and 77 K were used to study the influence of test temperature, and various load ratios (R) were used to determine the influence of the load ratio. It was found that decreasing the mechanical stability of the austenite by changing composition or lowering temperature decreases the fatigue crack growth rate. The R-ratio effect is more subtle. The fatigue crack growth rate increases with increasing R-ratio, even though this change increases the martensite transformation. Transformation-induced crack closure can explain the results in the threshold regime, but cannot explain the R-ratio effect at higher cyclic stress intensities. 26 refs., 6 figs.

  6. Properties of duplex stainless steels made by powder metallurgy

    OpenAIRE

    M. Rosso; M. Actis Grande; Z. Brytan; L.A. Dobrzański

    2007-01-01

    Purpose: of this paper was to examine the mechanical properties of duplex stainless steels.Design/methodology/approach: In presented study duplex stainless steels were obtained through powder metallurgy starting from austenitic, martensitic base powders by controlled addition of alloying elements, such as Cr, Ni, Mo and Cu. In the studies behind the preparation of mixes, Schaeffler’s diagram was taken into consideration. Prepared mixes have been sintered in a vacuu...

  7. Probing the duplex stainless steel phases via magnetic force microscopy

    Science.gov (United States)

    Gheno, S. M.; Santos, F. S.; Kuri, S. E.

    2008-03-01

    Duplex stainless steels are austenitic-ferritic alloys used in many applications, thanks to their excellent mechanical properties and high corrosion resistance. In this work, chemical analyses, x-ray diffraction, and magnetic force microscopy (MFM) were employed to characterize the solution annealed and aged duplex stainless steel. The samples exhibited no changes in lattice parameters and the MFM technique proved successful in clearly imaging the magnetic domain structure of the ferrite phase.

  8. Fatigue curve and stress strain response for stainless steel

    International Nuclear Information System (INIS)

    Applicability of ASME, KTA and RCC-M fatigue design curves for stainless steels is an issue of current debate. Laboratory data have shown environmental effects in coolant waters, but applicability of the proposed new design criteria to current plant components has been questioned. In a Regulatory Guide for new designs, the US NRC endorsed also a new air curve for stainless steels. Aim of the current study is to test applicability of the existing and proposed design criteria

  9. Restorasi Gigi Insisivus Sulung Menggunakan Resin Veneer Mahkota Stainless Steel

    OpenAIRE

    Hilda Shandika P.

    2008-01-01

    Untuk memperbaiki kerusakan gigi yang luas diperlukan restorasi yang tahan lama, retentif, dan estetik. Mahkota stainless steel digunakan untuk merestorasi insisivus sulung yang mengalami karies berat, kelainan bentuk atau akibat trauma. Mahkota ini merupakan restorasi yang kuat, tidak mudah fraktur, dan jarang rusak sampai beberapa tahun selama masih berada di tempatnya. Namun mahkota stainless steel memiliki kekurangan dari segi estetik karena warna peraknya yang mengganggu perhatian pada w...

  10. Corrosion resistance properties of sintered duplex stainless steel

    OpenAIRE

    L.A. Dobrzański; Z. Brytan; M. Actis Grande; M. Rosso

    2006-01-01

    Purpose: of this paper was to examine the corrosion resistance of duplex stainless steels using electrochemical methods in 1M NaCl solution. The influence of powder mixes preparation and cooling cycle after sintering on corrosion properties was evaluated.Design/methodology/approach: In presented study duplex stainless steels were obtained through powder metallurgy starting from austenitic, martensitic base powders by controlled addition of alloying elements, such as Cr, Ni, Mo and Cu. In the ...

  11. Stainless steel reinforcement for durability in concrete structures

    International Nuclear Information System (INIS)

    Stainless steels and concrete are materials which the nuclear industry, more than any other, has given special attention to over the years. It is the intention of this paper to inform congress about developments outside the nuclear industry, in the use of stainless steel as reinforcement (rebar) in concrete structures. It is left to individual engineers within the industry to assess the implications of this information to applications with which they will be familiar. (author)

  12. Strain induced grain boundary migration effects on grain growth of an austenitic stainless steel during static and metadynamic recrystallization

    International Nuclear Information System (INIS)

    Static and metadynamic recrystallization of an AISI 304L austenitic stainless steel was investigated at 1100 °C and 10− 2 s− 1 strain rate. The kinetics of recrystallization was determined through double hit compression tests. Two strain levels were selected for the first compression hit: εf = 0.15 for static recrystallization (SRX) and 0.25 for metadynamic recrystallization (MDRX). Both the as-deformed and the recrystallized microstructures were investigated through optical microscopy and electron back-scattered diffraction (EBSD) technique. During deformation, strain induced grain boundary migration appeared to be significant, producing a square-like grain boundary structure aligned along the directions of the maximum shear stresses in compression. EBSD analysis revealed to be as a fundamental technique that the dislocation density was distributed heterogeneously in the deformed grains. Grain growth driven by surface energy reduction was also investigated, finding that it was too slow to explain the experimental data. Based on microstructural results, it was concluded that saturation of the nucleation sites occurred in the first stages of recrystallization, while grain growth driven by strain induced grain boundary migration (SIGBM) dominated the subsequent stages. - Highlights: • Recrystallization behavior of a stainless steel was investigated at 1100 °C. • EBSD revealed that the dislocation density distribution was heterogeneous during deformation. • Saturation of nucleation sites occurred in the first stages of recrystallization. • Strain induced grain boundary migration (SIGBM) effects were significant. • Grain growth driven by SIGBM dominated the subsequent stages

  13. Employing the Waves to Measure Longitudinal Residual Stresses in Different Depths of a Stainless Steel Welded Plate

    Directory of Open Access Journals (Sweden)

    Yashar Javadi

    2013-01-01

    Full Text Available Ultrasonic stress measurement is based on the acoustoelasticity law which presents the relationship between the stress and acoustic wave velocity in engineering materials. The technique uses longitudinal critically refracted ( waves that travel parallel to the material surface. The wave is a bulk longitudinal wave that propagates within an effective depth underneath the surface while the penetration depth of a wave depends on its frequency. It is possible to measure the residual stress in different depths by employing different frequencies of the waves. This paper evaluates welding residual stresses in different depths of a plate made of austenitic stainless steel (304L. The penetration depths are accurately measured for the waves produced by 1 MHz, 2 MHz, 4 MHz, and 5 MHz transducers. Residual stresses through the thickness of the plate are then evaluated by employing four different series of transducers. It has been concluded that the method is nondestructive, easy and fast, portable, readily available, and low cost and bulk measuring technique which can be accurately employed in through-thickness stress measurement of austenitic stainless steels.

  14. Copper contamination in thin stainless steel sheet

    International Nuclear Information System (INIS)

    The standard welding technique used at Oak Ridge Y-12 Plant for joining thin stainless sheet is the gas tungsten arc (GTA) welding process. One of the reoccurring problems with the sheet welds is surface cracking in the heat-affected zone (HAZ). Metallography shows that the cracks are only about 0.05 mm (0.002 in.) deep which is significant in a 0.25 mm (0.01 in.) thick sheet. Thus, welding requirements do not permit any surfacing cracking as detected by a fluorescent dye penetrant test conducted on every part after welding. Surface cracks have been found in both of the two most common weld designs in the thin sheet fabricated at the Oak Ridge Y-12 Plant. These butt joints are welded between two 0.25 mm thick stainless steel sheets and a tube with eyelet welded to a 25 mm (0.98 in.) thick sheet. The weld between the two sheets is made on a semiautomatic seam welding unit, whereas the tube-to-eyelet-to-sheet welds are done manually. The quality of both welds is very dependent on the welding procedure and the way the parts are placed in the weld fixturing. Metallographic examination has indicated that some welded parts with surface cracking in the weld region had copper particles on the surface, and the question of copper contamination has been raised. With the aid of a scanning electron microscope and an electron microprobe, the existence of copper in an around the surface cracks has been verified. The copper is on the surface of the parts prior to welding in the form of small dust particles

  15. The electrochemistry of 13% chromium stainless steel in oilfield brines

    Energy Technology Data Exchange (ETDEWEB)

    Sidorin, Dmitry; Pletcher, Derek [Department of Chemistry, The University of Southampton, Southampton SO17 1BJ (United Kingdom); Hedges, Bill [BP Trinidad Ltd., P.O. Box 714, Port of Spain (Trinidad and Tobago)

    2005-07-25

    The electrochemistry of a 13% Cr stainless steel (API5CT L80-13Cr) in 3% NaCl containing acetate and either acetic acid or carbon dioxide at 333 K is explored using RDE voltammetry. The reduction of proton, carbonic acid and acetic acid occur simultaneously, immediately negative to the corrosion potential. Acetic acid gives a well formed reduction wave and the current densities increase with the equilibrium concentration of acetic acid in the medium; in the plateau region, the reduction is mass transport controlled. Despite this reduction process, the corrosion resistance and passivation current density are independent of the acetic acid concentration. It is confirmed that the 13% Cr stainless steel is much more resistant to corrosion that X65 carbon steel and, unlike the carbon steel, its rate of corrosion does not vary with acetic acid concentration. The properties of the passivating film appear to dominate the behaviour of the 13% Cr stainless steel. (author)

  16. The electrochemistry of 13% chromium stainless steel in oilfield brines

    International Nuclear Information System (INIS)

    The electrochemistry of a 13% Cr stainless steel (API5CT L80-13Cr) in 3% NaCl containing acetate and either acetic acid or carbon dioxide at 333 K is explored using RDE voltammetry. The reduction of proton, carbonic acid and acetic acid occur simultaneously, immediately negative to the corrosion potential. Acetic acid gives a well formed reduction wave and the current densities increase with the equilibrium concentration of acetic acid in the medium; in the plateau region, the reduction is mass transport controlled. Despite this reduction process, the corrosion resistance and passivation current density are independent of the acetic acid concentration. It is confirmed that the 13% Cr stainless steel is much more resistant to corrosion that X65 carbon steel and, unlike the carbon steel, its rate of corrosion does not vary with acetic acid concentration. The properties of the passivating film appear to dominate the behaviour of the 13% Cr stainless steel

  17. EFFECT OF INTERMETALLIC PHASES ON CORROSION BEHAVIOR AND MECHANICAL PROPERTIES OF DUPLEX STAINLESS STEEL AND SUPER-DUPLEX STAINLESS STEEL

    OpenAIRE

    Prabhu Paulraj; Rajnish Garg

    2015-01-01

    Duplex Stainless Steels (DSS) and Super Duplex Stainless Steel (SDSS) have excellent integration of mechanical and corrosion properties. However, the formation of intermetallic phases is a major problem in their usage. The mechanical and corrosion properties are deteriorated due to the presence of intermetallic phases. These phases are induced during welding, prolonged exposure to high temperatures, and improper heat treatments. The main emphasis of this review article is on intermetallic pha...

  18. Plasma spot welding of ferritic stainless steels

    Directory of Open Access Journals (Sweden)

    Lešnjak, A.

    2002-06-01

    Full Text Available Plasma spot welding of ferritic stainless steels is studied. The study was focused on welding parameters, plasma and shielding gases and the optimum welding equipment. Plasma-spot welded overlap joints on a 0.8 mm thick ferritic stainless steel sheet were subjected to a visual examination and mechanical testing in terms of tension-shear strength. Several macro specimens were prepared. Plasma spot welding is suitable to use the same gas as shielding gas and as plasma gas, i.e., a 98 % Ar/2 % H 2 gas mixture. Tension-shear strength of plasma-spot welded joints was compared to that of resistance-spot welded joints. It was found that the resistance welded joints withstand a somewhat stronger load than the plasma welded joints due to a larger weld spot diameter of the former. Strength of both types of welded joints is approximately the same.

    El artículo describe el proceso de soldeo de aceros inoxidables ferríticos por puntos con plasma. La investigación se centró en el establecimiento de los parámetros óptimos de la soldadura, la definición del gas de plasma y de protección más adecuado, así como del equipo óptimo para la realización de la soldadura. Las uniones de láminas de aceros inoxidables ferríticos de 0,8 mm de espesor, soldadas a solape por puntos con plasma, se inspeccionaron visualmente y se ensayaron mecánicamente mediante el ensayo de cizalladura por tracción. Se realizaron macro pulidos. Los resultados de la investigación demostraron que la solución más adecuada para el soldeo por puntos con plasma es elegir el mismo gas de plasma que de protección. Es decir, una mezcla de 98 % de argón y 2 % de hidrógeno. La resistencia a la cizalladura por tracción de las uniones soldadas por puntos con plasma fue comparada con la resistencia de las uniones soldadas por resistencia por puntos. Se llegó a la conclusión de que las uniones soldadas por resistencia soportan una carga algo mayor que la uniones

  19. Liquid Phase Sintering of Highly Alloyed Stainless Steel

    DEFF Research Database (Denmark)

    Mathiesen, Troels

    1996-01-01

    Liquid phase sintering of stainless steel is usually applied to improve corrosion resistance by obtaining a material without an open pore system. The dense structure normally also give a higher strength when compared to conventional sintered steel. Liquid phase sintrering based on addition...

  20. Fracture toughness of stainless steel welds

    International Nuclear Information System (INIS)

    The effects of temperature, composition and weld-process variations on the fracture toughness behavior for Types 308 and 16-8-2 stainless steel (SS) welds were examined using the multiple-specimen J/sub R/-curve procedure. Fracture characteristics were found to be dependent on temperature and weld process but not on filler material. Gas-tungsten-arc (GTA) welds exhibited the highest fracture toughness, a shielded metal-arc (SMA) weld exhibited an intermediate toughness and submerged-arc (SA) welds yielded the lowest toughness. Minimum-expected fracture properties were defined from lower-bound J/sub c/ and tearing modulus values generated here and in previous studies. Fractographic examination revealed that microvoid coalescence was the operative fracture mechanism for all welds. Second phase particles of manganese silicide were found to be detrimental to the ductile fracture behavior because they separated from the matrix during the initial stages of plastic straining. In SA welds, the high density of inclusions resulting from silicon pickup from the flux promoted premature dimple rupture. The weld produced by the SMA process contained substantially less manganese silicide, while GTA welds contained no silicide inclusions. Delta ferrite particles present in all welds were substantially more resistant to local failure than the silicide phase. In welds containing little or no manganese silicide, delta ferrite particles initiated microvoid coalescence but only after extensive plastic straining

  1. Martensite transformation in antimony implanted stainless steel

    International Nuclear Information System (INIS)

    The authors have used Rutherford backscattering analysis (RBS) and transmission electron microscopy (TEM) and diffraction to investigate austenitic stainless steel crystals implanted at room temperature with 80 keV Sb+ ions to a fluence of 5 x 1020 ions/m2, thus providing implantation with a heavy group V element. RBS channeling spectra from implanted crystals show a damage peak which approaches the height of the random level and therefore indicates a very high degree of disorder in the implanted layers. The distribution of the disorder extends to a depth 3-5 times the depth of the primary radiation damage. The Sb peaks under channeling as well as random conditions are indistinguishable, confirming that substitutionality during implantation is negligible. To establish the nature of the disorder which cannot be assessed from the RBS analysis alone, and in particular to assess whether an amorphous alloy is formed in the implanted layer as indicated from the RBS spectra, samples implanted under similar conditions were investigated in the TEM. Significant extra spots in the patterns can be ascribed to the presence of a radiation induced b.c.c. phase of martensitic origin. The result that a significant amount of martensite can be induced by antimony implantation seems to indicate that the main driving force for the transition is due to damage induced stress concentrations. (Auth.)

  2. Corrosion behavior of duplex stainless steel in sulphuric acid

    International Nuclear Information System (INIS)

    Duplex stainless steels are alloyed and processed to develop microstructure of roughly equal amounts of ferrite and austenite. Duplex stainless steel constitute a new class of materials because they have balanced amounts of ferrite and austenite. Since they have high content of chromium and molybdenum present, thus they have good corrosion resistance. Their corrosion resistance is double to that of annealed austenitic stainless steels with regard to pitting, crevice corrosion, sulphide stress corrosion, and chloride stress corrosion environments. The corrosion behavior of duplex stainless steel in various concentrations of sulphuric acid was studied. The reactions were carried out by placing the steel specimen in a beaker containing a known concentration of sulphuric acid at room temperature for a definite period. Pits were initiated in duplex stainless steel specimen and the propagation of pits depends upon the concentration of the acid solution in which the sample is in contact. The weight loss for definite period of time were measured and corrosion rates were calculated in millimetres per year. The corrosion rates increases with an increase in acid concentration at room temperature. A comparison of the results obtained from various concentrations of sulphuric acid with the same concentrations of nitric acid is also discussed. (author)

  3. Stainless steel tube-based cell cryopreservation containers.

    Science.gov (United States)

    Shih, Wei-Hung; Yu, Zong-Yan; Wu, Wei-Te

    2013-12-01

    This study focused on increasing the freezing rate in cell vitrification cryopreservation by using a cryopreservation container possessing rigid mechanical properties and high heat-transfer efficiency. Applying a fast freezing rate in vitrification cryopreservation causes a rapid temperature change in the cryopreservation container and has a substantial impact on mechanical properties; therefore, a highly rigid cryopreservation container that possesses a fast freezing rate must be developed. To produce a highly rigid cryopreservation container possessing superior heat transfer efficiency, this study applies an electrochemical machining (ECM) method to an ANSI 316L stainless steel tube to treat the surface material by polishing and roughening, thereby increasing the freezing rate and reducing the probability of ice crystal formation. The results indicated that the ECM method provided high-quality surface treatment of the stainless steel tube. This method can reduce internal surface roughness in the stainless steel tube, thereby reducing the probability of ice crystal formation, and increase external surface roughness, consequently raising convection heat-transfer efficiency. In addition, by thinning the stainless steel tube, this method reduces heat capacity and thermal resistance, thereby increasing the freezing rate. The freezing rate (3399 ± 197 °C/min) of a stainless steel tube after interior and exterior polishing and exterior etching by applying ECM compared with the freezing rate (1818 ± 54 °C/min) of an original stainless steel tube was increased by 87%, which also exceeds the freezing rate (2015 ± 49 °C/min) of an original quartz tube that has a 20% lower heat capacity. However, the results indicated that increasing heat-transferring surface areas and reducing heat capacities cannot effectively increase the freezing rate of a stainless steel tube if only one method is applied; instead, both techniques must be implemented concurrently to improve the

  4. Modern high strength QT, TM and duplex-stainless steels

    International Nuclear Information System (INIS)

    Pressure vessels are commonly manufactured with normalised steel grades with a yield strength up to 355 MPa or with austenitic stainless steels when corrosion as to be considered. From three decades, modern steels with higher mechanical properties - up to yield strength of 960 Mpa - are available and largely used for other applications where weight saving is of major importance as per off-shore, bridges, cranes, shipbuilding, line pipes.. The paper presents these modern steel's families - TMCP (Thermo Mechanically Controlled Process), QT (Quenched and Tempered) and Duplex (austeno-ferritic) stainless - in comparison with the normalised and austenitic steel grades. The following aspects are presented: the main mechanical properties (tensile and Charpy) as per the requirements of the standards for pressure equipment; some examples of use of these modern steels in the industry are given; the limitations of the forming conditions are considered; the weldability aspects and welds properties are developed; the interest of the PWHT (Post Weld Heat Treatment) is discussed. (orig.)

  5. 77 FR 28568 - Grant of Authority for Subzone Status; North American Stainless, (Stainless Steel), Ghent, KY

    Science.gov (United States)

    2012-05-15

    ... public comment has been given in the Federal Register (76 FR 66684-66685, 10-27-2011) and the application... Steel), Ghent, KY Pursuant to its authority under the Foreign-Trade Zones Act of June 18, 1934, as... authority to establish a special-purpose subzone at the stainless steel mill of North American...

  6. Experimental study on the emissivity of stainless steel

    International Nuclear Information System (INIS)

    The emissivity of material is a very important parameter for thermal radiative heat transfer. The emissivities of stainless steel 316L and 304 were measured as a fuction of surface temperature and heating time of test section by indirect method using the infrared thermometer. The error range of experiment is within 3∼10% and most of errors were occurred in measuring the surface temperature by thermocouple. The range of temperature for the experiment was 50∼540.deg. C and the emissivities of stainless steel 316L and 304 were increased along with the increase of surface temperature, and the increase rates for two materials were approximately the same and the value was about 1.31x10-4(1/.deg. C). The emissivity of stainless steel 316L with surface roughness 4.1μm was between 0.44 and 0.51, and the emissivity of stainless steel 304 with surface roughness 2.0μm was between 0.32 and 0.38 in this temperature range. The emissivity of stainless steel 304 was gradually increased by a value of 0.03 at 395.deg. C for 266 hours

  7. Aging of cast duplex stainless steels in LWR systems

    International Nuclear Information System (INIS)

    A program is being conducted to investigate the significance of in-service embrittlement of cast duplex stainless steels under light-water reactor operating conditions. The existing data are evaluated to determine the expected embrittlement of cast components during the operating lifetime of reactors and to define the objectives and scope of the investigation. This presentation describes the status of the program. Data for the metallurgical characterization of the various cast stainless steels used in the investigation are presented. Charpy impact tests on short-term aged material indicate that CF-3 stainless steels are less susceptible to embrittlement than CF-8 or CF-8M stainless steels. Microstructural characterization of cast stainless steels that were obtained from Georg Fischer Co. and aged for up to 70,000 h at 300, 350, and 4000C reveals the formation of four different types of precipitates that are not α'. Embrittlement of the ferrite phase is primarily due to pinning of the dislocations by two of these precipitates, designated as Type M and Type X. The ferrite phase is embrittled after approx. 8 y at 3000C and shows cleavage fracture. Examination of the fracture surfaces of the impact-test specimens indicates that the toughness of the long-term aged material is determined by the austenite phase. 8 figures, 3 tables

  8. Compresibility and sinterability of HCx PM steel diluted with stainless steels

    OpenAIRE

    Gordo Elena; Khattab Nermein Hamid; Ruiz-Navas Elisa María

    2003-01-01

    HCx powder metallurgy steel contains in its composition high contents of Cr and C, and significant quantities of alloy elements typical of tool steels (Mo, V, W), to provide the corrosion resistance of stainless steel with wear resistance of tool steels. HCx appears to be a suitable material for applications in aggressive environments, as valve seat inserts in automotive engines. However, this steel presents a low compressibility leading to high production costs. In this work, some results ca...

  9. Operational experience of stainless steels in seawater-cooled systems

    International Nuclear Information System (INIS)

    A study has been made of chiefly Swedish and Finnish operational experience of stainless steel in seawater and brackish water. A report is given on 23 typical cases, behind which in actual fact a considerably larger number of individual practical cases are concealed. The answer to the primary question why a standard steel of type SS 2343 (AISI 316) sometimes, contrary to expectation, remains unattacked by local corrosion is that there is usually spontaneous cathodic protection by other less noble components of carbon steel, cast iron or some copper alloy in direct contact with the stainless steel. The study confirms in other respects the adverse effect of residual oxides after welding and the beneficial of low temperature, high continuous waterflow and periodic cleaning, and of rinsing with fresh water during out-of service periods. It also verifies the additional advantages of the new high-alloy special steels which have begun to be marketed in recent years for seawater applications. (author)

  10. Tensile properties of the modified 13Cr martensitic stainless steels

    Science.gov (United States)

    Mabruri, Efendi; Anwar, Moch. Syaiful; Prifiharni, Siska; Romijarso, Toni B.; Adjiantoro, Bintang

    2016-04-01

    This paper reports the influence of Mo and Ni on the tensile properties of the modified 13Cr martensitic stainless steels in tempered condition. Four steels with different content of Mo and Ni were prepared by induction melting followed by hot forging, quenching and tempering. The experimental results showed that the addition of about 1% and 3% Mo has a beneficial effect to increase both the tensile strength and the elongation of the steels. On the contrary, the addition of about 3% Ni into the martensitic stainless steel results in decreasing of both the tensile strength and the elongation. Among the alloys investigated the 13Cr3Mo type steel exhibited largest tensile strength of 1348 MPa and largest elongation of 12%. The observation on the tensile fractured surfaces by using scanning electron microscope supported these findings.

  11. Thermal Induced Processes in Laminar System of Stainless Steel - Beryllium

    International Nuclear Information System (INIS)

    The paper reports on investigation of the laminar system 'stainless steel 12Cr18Ni10Ti - Be' at thermal treatment. There have been determined sequences of phase transformations along with relative amount of iron-containing phases in the samples subjected to thermal beryllization. It has been revealed that thermal beryllization of stainless steel thin foils results in γ→α transformation and formation of the beryllides NiBe and FeBe2. It has also been revealed that direct γ→α- and reverse α→γ-transformations are accompanied by, correspondingly, formation and decomposition of the beryllide NiBe. It is shown that distribution of the formed phases within sample bulk is defined by local concentration of beryllium. Based on obtained experimental data there is proposed a physical model of phase transformations in stainless steel at thermal beryllization.

  12. Depth distribution of martensite in xenon implanted stainless steels

    International Nuclear Information System (INIS)

    The amount of stress-induced martensite and its distribution in depth in xenon implanted austenitic stainless steel poly- and single crystals have been measured by Rutherford backscattering and channeling analysis, depth selective conversion electron Moessbauer spectroscopy, cross-sectional transmission electron microscopy and x-ray diffraction analysis. In low nickel 17/7, 304 and 316 commercial stainless steels and in 17:13 single crystals the martensitic transformation starts at the surface and develops towards greater depth with increasing xenon fluence. The implanted layer is nearly completely transformed, and the interface between martensite and austenite is rather sharp and well defined. In high nickel 310 commercial stainless steel and 15:19 and 20:19 single crystals, on the other hand, only insignificant amounts of martensite are observed. (orig.)

  13. Highly robust stainless steel tips as microelectrospray emitters.

    Science.gov (United States)

    Ishihama, Yasushi; Katayama, Hiroyuki; Asakawa, Naoki; Oda, Yoshiya

    2002-01-01

    Tapered stainless steel spray tips for sheathless microelectrospray ionization (microESI) have been developed. The fabrication procedure for the tapered stainless steel tips was optimized using an electropolishing technique followed by removal of the burr. Using the tip as the microESI emitter, a stable ESI spray was obtained at a flow rate of 20 nL/min. The sensitivity of the microESI system was almost two orders greater than that of the conventional ion spray system. The tip was highly stable, and was successfully used for over 1000 h. Moreover, these stainless steel tips were suitable for use with sheathless capillary electrophoresis/mass spectrometry (CE/MS) and capillary liquid chromatography/mass spectrometry (LC/MS) for routine analysis in proteomic and pharmaceutical applications. PMID:11968120

  14. Microbially influenced corrosion of stainless steels in nuclear power plants

    Energy Technology Data Exchange (ETDEWEB)

    Sinha, U.P.; Wolfram, J.H.; Rogers, R.D.

    1990-01-01

    This paper reviews the components, causative agents, corrosion sites, and potential failure modes of stainless steel components susceptible to microbially influenced corrosion (MIC). The stainless steel components susceptible to MIC are located in the reactor coolant, emergency, and reactor auxiliary systems, and in many plants, in the feedwater train and condenser. The authors assessed the areas of most high occurrence of corrosion and found the sites most susceptible to MIC to the heat-affected zones in the weldments of sensitized stainless steel. Pitting is the predominant MIC corrosion mechanisms, caused by sulfur reducing bacteria (SRB). Also discussed is the current status of the diagnostic, preventive, and mitigation techniques, including use of improved water chemistry, alternate materials, and improved thermomechanical treatments. 37 refs., 3 figs.

  15. Embrittlement of cast stainless steels in LWR systems

    International Nuclear Information System (INIS)

    Mechanical property data from Charpy-impact and J-R curve tests are presented for several experimental and commercial heats, as well as reactor-aged material of CF-3, CF-8, and CF-8M grades of cast stainless steel. The effects of material variables on the embrittlement of cast stainless steels are evaluated. The chemical composition and ferrite morphology have a strong effect on the extent and kinetics of embrittlement. The data are analyzed to establish the mechanisms of embrittlement. The procedure and correlations for predicting the impact strength and fracture toughness of cast components during reactor service are described. The lower bound values of impact strength and fracture toughness for low-temperature aged cast stainless steel are defined. 13 refs., 13 figs., 3 tabs

  16. Evaluation of Additive Manufacturing for Stainless Steel Components

    Energy Technology Data Exchange (ETDEWEB)

    Peter, William H. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Lou, Xiaoyuan [General Electric (GE), Wilmington, NC (United States); List, III, Frederick Alyious [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Webber, David [General Electric (GE), Wilmington, NC (United States)

    2016-09-01

    This collaboration between Oak Ridge National Laboratory and General Electric Company aimed to evaluate the mechanical properties, microstructure, and porosity of the additively manufactured 316L stainless steel by ORNL’s Renishaw AM250 machine for nuclear application. The program also evaluated the stress corrosion cracking and corrosion fatigue crack growth rate of the same material in high temperature water environments. Results show the properties of this material to be similar to the properties of 316L stainless steel fabricated additively with equipment from other manufacturers with slightly higher porosity. The stress corrosion crack growth rate is similar to that for wrought 316L stainless steel for an oxygenated high temperature water environment and slightly higher for a hydrogenated high temperature water environment. Optimized heat treatment of this material is expected to improve performance in high temperature water environments.

  17. Mechanical properties of duple stainless steels laser joints

    International Nuclear Information System (INIS)

    The welded joints of stainless steels always present problems for the microstructural modifications that occur in the heat affected zone. Particularly, duplex stainless steels present very important changes when the weld pool solidifies forming fundamentally ferritic structures with some austenite in grain boundaries. These microstructural modifications, and those which occur in the HAZ, justify the mechanical properties of the joint and mainly those of plasticity, being all of them influenced by the processing conditions. In this work the influence of the laser welding speed on the tensile behaviour od duplex stainless steel welded joints is presented. The microstructure of the obtained seams and of the heat affected zone will be evaluated by means of optic and scanning electron microscopy. Also, different microhardness profiles have been obtained to evaluate the modifications in the mechanical properties both in the seam and the zone of thermal affection. (Author) 23 refs

  18. Irradiation creep of SA 304L and CW 316 stainless steels: Mechanical behaviour and microstructural aspects. Part II: Numerical simulation and test of SIPA model

    Science.gov (United States)

    Garnier, J.; Bréchet, Y.; Delnondedieu, M.; Renault, A.; Pokor, C.; Dubuisson, P.; Massoud, J.-P.

    2011-06-01

    A cluster dynamic model has been adapted to test the Stress Induced Preferential Absorption of Defect (SIPA) on Frank loops hypothesis concerning irradiation creep, to reproduce quantitatively both microstructure evolution and its stress induced anisotropy and macroscopic creep rate. It is concluded that SIPA on Frank loops model can account for the observed defects structure, but is unable to reproduce quantitatively the creep rate.

  19. Biomaterial Studies on AISI 316L Stainless Steel after Magnetoelectropolishing

    Directory of Open Access Journals (Sweden)

    Massimiliano Filippi

    2009-03-01

    Full Text Available The polarisation characteristics of the electropolishing process in a magnetic field (MEP – magnetoelectropolishing, in comparison with those obtained under standard/conventional process (EP conditions, have been obtained. The occurrence of an EP plateau has been observed in view of the optimization of MEP process. Up-to-date stainless steel surface studies always indicated some amount of free-metal atoms apart from the detected oxides and hydroxides. Such a morphology of the surface film usually affects the thermodynamic stability and corrosion resistance of surface oxide layer and is one of the most important features of stainless steels. With this new MEP process we can improve metal surface properties by making the stainless steel more resistant to halides encountered in a variety of environments. Furthermore, in this paper the stainless steel surface film study results have been presented. The results of the corrosion research carried out by the authors on the behaviour of the most commonly used material - medical grade AISI 316L stainless steel both in Ringer’s body fluid and in aqueous 3% NaCl solution have been investigated and presented earlier elsewhere, though some of these results, concerning the EIS Nyquist plots and polarization curves are also revealed herein. In this paper an attempt to explain this peculiar performance of 316L stainless steel has been undertaken. The SEM studies, Auger electron spectroscopy (AES and X-ray photoelectron spectroscopy (XPS were performed on 316L samples after three treatments: MP – abrasive polishing (800 grit size, EP – conventional electrolytic polishing, and MEP – magnetoelectropolishing. It has been found that the proposed magnetoelectropolishing (MEP process considerably modifies the morphology and the composition of the surface film, thus leading to improved corrosion resistance of the studied 316L SS.

  20. Sinter-hardening process applicable to stainless steels

    Directory of Open Access Journals (Sweden)

    M. Rosso

    2007-10-01

    Full Text Available Purpose: of this paper was to describe sintered duplex stainless steels manufactured in sinter-hardening process and its usability in field of stainless steels.Design/methodology/approach: In presented study duplex stainless steels were obtained through powder metallurgy starting from austenitic, ferritic base powders by controlled addition of alloying elements, such as Cr, Ni, Mo and Cu. In the studies apart from the preparation of mixes, Schaeffler’s diagram was taken into consideration. Prepared mixes have been compacted at 800 MPa and sintered in a vacuum furnace with argon backfilling at temperatures from 1200°C to 1285°C for 0.5, 1 and 2 h. After sintering different cooling cycles were applied using nitrogen under pressure from 0.6 MPa to 0.002 MPa in argon atmosphere. Produced duplex stainless steels have been studied by scanning and optical microscopy and EDS chemical analysis of microstructure components.Findings: Obtained microstructure and mechanical properties of sintered duplex stainless steel strictly depend on the density and the pore morphology present in the microstructure and especially on cooling rate directly from sintering temperature in sinter-hardening process. The lowest cooling rate - applied gas pressure, the mechanical properties and corrosion resistance decrease due to precipitation of sigma phase. Proper bi-physic microstructure was obtained using nitrogen under pressure of 0.6 and 0.2 MPa.Research limitations/implications: Applied fast cooling rate seems to be a good compromise for mechanical properties and obtained microstructures, nevertheless further tests should be carried out in order to examine its influence on corrosion properties.Originality/value: The utilization of sinter-hardening process combined with use of elemental powders added to a stainless steel base powder shows its potentialities in terms of good microstructural homogeneity and especially working with cycles possible to introduce in

  1. Failure of austenitic stainless steel tubes during steam generator operation

    OpenAIRE

    M. Głowacka; J. Łabanowski; S. Topolska

    2012-01-01

    Purpose: of this study is to analyze the causes of premature failure of steam generator coil made of austenitic stainless steel. Special attention is paid to corrosion damage processes within the welded joints.Design/methodology/approach: Examinations were conducted several segments of the coil made of seamless cold-formed pipes Ø 23x2.3 mm, of austenitic stainless steel grade X6CrNiTi18-10 according to EN 10088-1:2007. The working time of the device was 6 months. The reason for the withdrawa...

  2. Fatigue behavior of welded austenitic stainless steel in different environments

    OpenAIRE

    D. S. Yawas; S.Y. Aku; S.O. Aluko

    2014-01-01

    The fatigue behavior of welded austenitic stainless steel in 0.5 M hydrochloric acid and wet steam corrosive media has been investigated. The immersion time in the corrosive media was 30 days to simulate the effect on stainless steel structures/equipment in offshore and food processing applications and thereafter annealing heat treatment was carried out on the samples. The findings from the fatigue tests show that seawater specimens have a lower fatigue stress of 0.5 × 10−5 N/mm2 for the heat...

  3. Impact toughness of tungsten films deposited on martensite stainless steel

    Institute of Scientific and Technical Information of China (English)

    HUANG Ning-kang; YANG Bin; WANG De-zhi

    2005-01-01

    Tungsten films were deposited on stainless steel Charpy specimens by magnetron sputtering followed by electron beam heat treatment. Charpy impact tests and scanning electron microscopy were used to investigate the ductile-brittle transition behavior of the specimens. With decreasing test temperature the fracture mode was transformed from ductile to brittle for both kinds of specimens with and without W films. The data of the crack initiation energy, crack propagation energy, impact absorbing energy, fracture time and deflection as well as the fracture morphologies at test temperature of -70 ℃ show that W films can improve the impact toughness of stainless steel.

  4. Corrosion induced by cathodic hydrogen in 2205 duplex stainless steel

    Science.gov (United States)

    Michalska, J.

    2011-05-01

    In this work new results about the influence of cathodic hydrogen on passivity and corrosion resistance of 2205 duplex stainless steel are described. The results were discussed by taking into account hydrogen charged samples and without hydrogen. The corrosion resistance to pitting was qualified with the polarization curves. The conclusion is that, hydrogen deteriorated the passive film stability and corrosion resistance to pitting of 2205 duplex stainless steel. The presence of hydrogen in passive films increases corrosion current density and decreases the potential of the film breakdown. It was also found that degree of susceptibility to hydrogen action was dependent on the hydrogen charging conditions.

  5. Corrosion induced by cathodic hydrogen in 2205 duplex stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Michalska, J, E-mail: joanna.k.michalska@polsl.pl [Department of Materials Science, Silesian University of Technology, Krasinskiego 8, 40-019 Katowice (Poland)

    2011-05-15

    In this work new results about the influence of cathodic hydrogen on passivity and corrosion resistance of 2205 duplex stainless steel are described. The results were discussed by taking into account hydrogen charged samples and without hydrogen. The corrosion resistance to pitting was qualified with the polarization curves. The conclusion is that, hydrogen deteriorated the passive film stability and corrosion resistance to pitting of 2205 duplex stainless steel. The presence of hydrogen in passive films increases corrosion current density and decreases the potential of the film breakdown. It was also found that degree of susceptibility to hydrogen action was dependent on the hydrogen charging conditions.

  6. Topographical Anisotropy and Wetting of Ground Stainless Steel Surfaces

    Directory of Open Access Journals (Sweden)

    Cornelia Bellmann

    2012-12-01

    Full Text Available Microscopic and physico-chemical methods were used for a comprehensive surface characterization of different mechanically modified stainless steel surfaces. The surfaces were analyzed using high-resolution confocal microscopy, resulting in detailed information about the topographic properties. In addition, static water contact angle measurements were carried out to characterize the surface heterogeneity of the samples. The effect of morphological anisotropy on water contact angle anisotropy was investigated. The correlation between topography and wetting was studied by means of a model of wetting proposed in the present work, that allows quantifying the air volume of the interface water drop-stainless steel surface.

  7. Deformation and rupture of stainless steel under cyclic, torsional creep

    OpenAIRE

    Rees, DWA

    2008-01-01

    Copyright 2008 @ Engineering Integrity Society. Recent results from a long-term, strain-limited, cyclic creep test program upon stainless steel tubes are given. The test conditions employed were: constant temperature 500 °C, shear stress Ƭ = ± 300 MPa and shear strain limits ƴ = ± 4%. It is believed that a cyclic creep behaviour for the material has been revealed that has not been reported before in the literature. That is, the creep curves for stainless steel under repeated, shear stress...

  8. Comparison of antibacterial ability of copper and stainless steel

    Institute of Scientific and Technical Information of China (English)

    GENG Ping; ZHANG Wen; TANG Hui; ZHANG Xinai; JIN Litong; FENG Zhen; WU Zirong

    2007-01-01

    In this paper,the electro-analysis and spectrophotometric analysis methods were used to study the antibacterial ability of copper and stainless steel materials.When Escherichia coli (E.coli) and photo-bacteria were used as samples,the antibacterial effect of stainless steel was very weak,while the percentage of bacteria dying from exposure to metallic copper for 30 min was over 90%.The antibacterial ability of copper has a potential application in the field of disinfection,food packaging and piping of drinking water.

  9. Development status of ultrasonic test techniques for cast stainless steel

    International Nuclear Information System (INIS)

    Ultrasonic testing has been thought to be difficult to apply to cast stainless steel which is used as the material for the main coolant pipes in pressurized water reactors (PWRs). An ultrasonic testing technique using large aperture twin crystal transducers was developed in INSS for application to inspection of the main coolant pipes. The method was evaluated in an application to detect circumferential and axial defects in the cast stainless steel pipes. It was found that (1) the defects could be detected which had a depth that was so small that their evaluation was not required; and (2) depth sizing and length sizing of detected defects were also possible. (author)

  10. Corrosion of 316L stainless steels MAVL wastes containers

    International Nuclear Information System (INIS)

    The long lived and medium activity wastes are conditioned or could be re-conditioned in primary drums of 316L stainless steels. In the framework of wastes storage, these drums will be placed in concrete containers; each containers would contain one or more drums. This document recalls global information on the corrosion of stainless steels, analyzes specific conditions bond to the drums conditioning in concrete containers and the nature of the wastes, and details the consequences on the possible risks of external and internal corrosion of the drums. (A.L.B.)

  11. Intergranular stress corrosion in soldered joints of stainless steel 304

    International Nuclear Information System (INIS)

    The intergranular stress cracking of welded joints of austenitic stainless steel, AISI 304, is a serious problem in BWR type reactors. It is associated with the simultaneous presence of three factors; stress, a critical media and sensibilization (DOS). EPR technique was used in order to verify the sensibilization degree in the base metal, and the zone affected by heat and welding material. The characterization of material was done. The objective of this work is the study of microstructure and the evaluation of EPR technique used for the determination of DOS in a welded plate of austenitic stainless steel AISI 304. (Author)

  12. Ozone decay on stainless steel and sugarcane bagasse surfaces

    Science.gov (United States)

    Souza-Corrêa, Jorge A.; Oliveira, Carlos; Amorim, Jayr

    2013-07-01

    Ozone was generated using dielectric barrier discharges at atmospheric pressure to treat sugarcane bagasse for bioethanol production. It was shown that interaction of ozone molecules with the pretreatment reactor wall (stainless steel) needs to be considered during bagasse oxidation in order to evaluate the pretreatment efficiency. The decomposition coefficients for ozone on both materials were determined to be (3.3 ± 0.2) × 10-8 for stainless steel and (2.0 ± 0.3) × 10-7 for bagasse. The results have indicated that ozone decomposition has occurred more efficiently on the biomass material.

  13. Evaluation of the thermal ageing of duplex stainless steels

    International Nuclear Information System (INIS)

    Three methods have been investigated to follow up the thermal ageing of duplex stainless steels: microhardness tests, instrumented ultramicrohardness tests and Small Angle Neutron Scattering (SANS) techniques. The values measured with these methods have been correlated with pertinent parameters of the metallurgical ageing phenomenon determined by Atom-Probe. These methods seem to be sensitive and reproducible enough to detect and follow up the ageing of duplex stainless steels. They can be applied on small samples (chips) drawn from in-service components. (authors). 10 refs., 9 figs., 3 tabs

  14. Application and development of stainless steel reinforced concrete structure

    Directory of Open Access Journals (Sweden)

    Meng Xian Hong

    2016-01-01

    Full Text Available Now reinforced concrete structure in our country develops very fast, and reinforced concrete structure has been widely applied by various buildings. But with the deepening of the research experts and scholars, they found in some areas where high corrosion of reinforced concrete structure with the increase of service time, the concrete cracks, and led to the internal steel bar corrosion conditions. In the face of these problems, the experts used stainless steel applied to the study of concrete. In this paper, the stainless stell reinforced concrete structure of the application and development status of made briefly.

  15. 78 FR 63517 - Control of Ferrite Content in Stainless Steel Weld Metal

    Science.gov (United States)

    2013-10-24

    ... COMMISSION Control of Ferrite Content in Stainless Steel Weld Metal AGENCY: Nuclear Regulatory Commission... revision to Regulatory Guide (RG) 1.31, ``Control of Ferrite Content in Stainless Steel Weld Metal.'' This... content in stainless steel weld metal. It updates the guide to remove references to outdated standards...

  16. 77 FR 60478 - Control of Ferrite Content in Stainless Steel Weld Metal

    Science.gov (United States)

    2012-10-03

    ... COMMISSION Control of Ferrite Content in Stainless Steel Weld Metal AGENCY: Nuclear Regulatory Commission... Ferrite Content in Stainless Steel Weld Metal.'' This guide describes a method that the NRC staff considers acceptable for controlling ferrite content in stainless steel weld metal. Revision 4 updates...

  17. Accelerated corrosion of stainless steel in thiocyanate-containing solutions

    Energy Technology Data Exchange (ETDEWEB)

    Pistorius, P Chris; Li, Wen

    2012-09-19

    It is known that reduced sulfur compounds (such as thiocyanate and thiosulfate) can accelerate active corrosion of austenitic stainless steel in acid solutions, but before we started this project the mechanism of acceleration was largely unclear. This work combined electrochemical measurements and analysis using scanning electron microscopy (SEM) and X-ray photo-electron spectroscopy (XPS), which provided a comprehensive understanding of the catalytic effect of reduced sulfur species on the active corrosion of stainless steel. Both the behavior of the pure elements and the steel were studied and the work focused on the interaction between the pure elements of the steel, which is the least understood area. Upon completion of this work, several aspects are now much clearer. The main results from this work can be summarized as follows: The presence of low concentrations (around 0.1 mM) of thiocyanate or tetrathionate in dilute sulfuric acid greatly accelerates the anodic dissolution of chromium and nickel, but has an even stronger effect on stainless steels (iron-chromium-nickel alloys). Electrochemical measurements and surface analyses are in agreement with the suggestion that accelerated dissolution really results from suppressed passivation. Even well below the passivation potential, the electrochemical signature of passivation is evident in the electrode impedance; the electrode impedance shows clearly that this pre-passivation is suppressed in the presence of thiocyanate. For the stainless steels, remarkable changes in the morphology of the corroded metal surface and in the surface concentration of chromium support the suggestion that pre-passivation of stainless steels is suppressed because dissolution of chromium is accelerated. Surface analysis confirmed that adsorbed sulfur / sulfide forms on the metal surfaces upon exposure to solutions containing thiocyanate or thiosulfate. For pure nickel, and steels containing nickel (and residual copper), bulk sulfide

  18. Properties of duplex stainless steels made by powder metallurgy

    Directory of Open Access Journals (Sweden)

    M. Rosso

    2007-04-01

    Full Text Available Purpose: of this paper was to examine the mechanical properties of duplex stainless steels.Design/methodology/approach: In presented study duplex stainless steels were obtained through powder metallurgy starting from austenitic, martensitic base powders by controlled addition of alloying elements, such as Cr, Ni, Mo and Cu. In the studies behind the preparation of mixes, Schaeffler’s diagram was taken into consideration. Prepared mixes have been sintered in a vacuum furnace with argon backfilling at 1260°C for 1 h. After sintering: rapid cooling have been applied in argon atmosphere. Produced duplex stainless steels have been studied by scanning and optical microscopy. Mechanical properties such as tensile strength, impact energy, hardness and wear rate were evaluated.Findings: According to achieved results, it was affirmed that applied sintering method as well as powder mixes preparation allows for manufacturing the sintered duplex steels with good mechanical properties which depends on austenite/ferrite ratio in the microstructure and elements partitioning between phases. The additions of alloying elements powders (promoting formation ferritic and austenitic phase to master alloy powder, makes possible the formation of structure and properties of sintered duplex stainless steels. Sintered duplex steels obtained starting from austenitic and ferritic powders with admixture of elemental powders achieve lower mechanical properties when compared to composition obtained by mixing ferritic and austenitic powder in equal amounts.Research limitations/implications: According to the powders characteristic, the applied fast cooling rate seems to be a good compromise for mechanical properties and microstructures, nevertheless further tests should be carried out in order to examine different cooling rates.Originality/value: The use of elemental powders added to a stainless steel base showed its potentialities, in terms of fair compressibility and final

  19. A review of hot cracking in austenitic stainless steel weldments

    International Nuclear Information System (INIS)

    The occurrence of hot cracking in austenitic stainless steel weldments is discussed with respect to its origin and metallurgical contributory factors. Of the three types of hot cracking, namely solidification cracking, liquation and ductility dip cracking, solidification cracking occurs in the interdendritic regions in weld metal while liquation and ductility dip cracking occur intergranularly in the heat-affected zone (HAZ). Segregation of impurity and minor elements such as sulphur, phosphorous, silicon, niobium, boron etc to form low melting eutectic phases has been found to be the major cause of hot cracking. Control of HAZ cracking requires minimisation of impurity elements in the base metal. In stabilized stainless steels containing niobium, higher amounts of delta-ferrite have been found necessary to prevent cracking than in unstabilized compositions. Titanium compounds have been found to cause liquation cracking in maraging steels and titanium containing stainless steels and superalloys. In nitrogen added stainless steels, cracking resistance decreases when the solidification mode changes to primary austenitic due to nitrogen addition. A review of the test methods to evaluate hot cracking behaviour showed that several external restraint and semi-self-restraint tests are available. The finger Test, WRC Fissure Bend Test, the PVR test and the Varestraint Test are described along with typical test results. Hot ductility testing to reveal HAZ cracking tendency during welding is described, which is of particular importance to stabilized stainless steels. Based on the literature, recommendations are made for welding stabilized and nitrogen added steels, indicating areas of further work. (author). 81 refs., 30 figs., 1 tab

  20. Corrosion resistance of stainless steel pipes in soil

    Energy Technology Data Exchange (ETDEWEB)

    Sjoegren, L.; Camitz, G. [Swerea KIMAB AB, Box 55970, SE-102 16 Stockholm (Sweden); Peultier, J.; Jacques, S.; Baudu, V.; Barrau, F.; Chareyre, B. [Industeel and ArcelorMittal R and D, 56 rue Clemenceau, BP19, FR-71201 le Creusot, Cedex (France); Bergquist, A. [Outokumpu Stainless AB, P.O. Box 74, SE-774 22 Avesta (Sweden); Pourbaix, A.; Carpentiers, P. [Belgian Centre for Corrosion Study, Avenue des Petits-Champs 4A, BE 1410 Waterloo (Belgium)

    2011-04-15

    To be able to give safe recommendations concerning the choice of suitable stainless steel grades for pipelines to be buried in various soil environments, a large research programme, including field exposures of test specimens buried in soil in Sweden and in France, has been performed. Resistance against external corrosion of austenitic, super austenitic, lean duplex, duplex and super duplex steel grades in soil has been investigated by laboratory tests and field exposures. The grades included have been screened according to their critical pitting-corrosion temperature and according to their time-to-re-passivation after the passive layer has been destroyed locally by scratching. The field exposures programme, being the core of the investigation, uses large specimens: 2 m pipes and plates, of different grades. The exposure has been performed to reveal effects of aeration cells, deposits or confined areas, welds and burial depth. Additionally, investigations of the tendency of stainless steel to corrode under the influence of alternating current (AC) have been performed, both in the laboratory and in the field. Recommendations for use of stainless steels under different soil conditions are given based on experimental results and on operating experiences of existing stainless steel pipelines in soil. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  1. Electrochemically induced annealing of stainless-steel surfaces

    Science.gov (United States)

    Burstein, G. T.; Hutchings, I. M.; Sasaki, K.

    2000-10-01

    Modification of the surface properties of metals without affecting their bulk properties is of technological interest in demanding applications where surface stability and hardness are important. When austenitic stainless steel is heavily plastically deformed by grinding or rolling, a martensitic phase transformation occurs that causes significant changes in the bulk and surface mechanical properties of the alloy. This martensitic phase can also be generated in stainless-steel surfaces by cathodic charging, as a consequence of lattice strain generated by absorbed hydrogen. Heat treatment of the steel to temperatures of several hundred degrees can result in loss of the martensitic structure, but this alters the bulk properties of the alloy. Here we show that martensitic structures in stainless steel can be removed by appropriate electrochemical treatment in aqueous solutions at much lower temperature than conventional annealing treatments. This electrochemically induced annealing process allows the hardness of cold-worked stainless steels to be maintained, while eliminating the brittle martensitic phase from the surface. Using this approach, we are able to anneal the surface and near-surface regions of specimens that contain rolling-induced martensite throughout their bulk, as well as those containing surface martensite induced by grinding. Although the origin of the electrochemical annealing process still needs further clarification, we expect that this treatment will lead to further development in enhancing the surface properties of metals.

  2. Low Temperature Surface Carburization of Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Collins, Sunniva R; Heuer, Arthur H; Sikka, Vinod K

    2007-12-07

    Low-temperature colossal supersaturation (LTCSS) is a novel surface hardening method for carburization of austenitic stainless steels (SS) without the precipitation of carbides. The formation of carbides is kinetically suppressed, enabling extremely high or colossal carbon supersaturation. As a result, surface carbon concentrations in excess of 12 at. % are routinely achieved. This treatment increases the surface hardness by a factor of four to five, improving resistance to wear, corrosion, and fatigue, with significant retained ductility. LTCSS is a diffusional surface hardening process that provides a uniform and conformal hardened gradient surface with no risk of delamination or peeling. The treatment retains the austenitic phase and is completely non-magnetic. In addition, because parts are treated at low temperature, they do not distort or change dimensions. During this treatment, carbon diffusion proceeds into the metal at temperatures that constrain substitutional diffusion or mobility between the metal alloy elements. Though immobilized and unable to assemble to form carbides, chromium and similar alloying elements nonetheless draw enormous amounts of carbon into their interstitial spaces. The carbon in the interstitial spaces of the alloy crystals makes the surface harder than ever achieved before by more conventional heat treating or diffusion process. The carbon solid solution manifests a Vickers hardness often exceeding 1000 HV (equivalent to 70 HRC). This project objective was to extend the LTCSS treatment to other austenitic alloys, and to quantify improvements in fatigue, corrosion, and wear resistance. Highlights from the research include the following: • Extension of the applicability of the LTCSS process to a broad range of austenitic and duplex grades of steels • Demonstration of LTCSS ability for a variety of different component shapes and sizes • Detailed microstructural characterization of LTCSS-treated samples of 316L and other alloys

  3. Carburisation of stainless steel caused by oil in sodium

    International Nuclear Information System (INIS)

    The primary objectives of this work were to investigate the kinetics of austenitic stainless steel carburisation in sodium caused by oil in sodium, and to measure the corresponding 'sodium carbon activity' (a quantitative measure of sodium steel carburisation potential). For comparative purposes, the steel carburising effects of chemically simpler carbon sources have also been studied. The specific experimental investigations have involved: (i) A study of the kinetics of stainless steel carburisation at 5500C caused by oil in sodium; (ii) A determination of the effective steel carburisation potential (carbon activity) arising from oil ingress, and its persistence with time, and (iii) A comparison of oil and chemically simpler carbon sources, namely graphite and cementite (as carburised iron, Fe-Fe3C), with regard to both kinetics of steel carburisation and sodium carbon activities produced. In all cases, the nature and extent of carburisation has been determined by optical metallography, X-ray and nuclear microprobe analysis. Preliminary studies on the mutual effect of steel surfaces in close proximity have also been conducted. Previous studies on steel carburisation in sodium are outlined, and the present results are discussed in the context of available thermodynamic and kinetic data pertaining to the carbon-steel and carbon-sodium systems. (author)

  4. Precipitated phases and corrosion behavior in the dissimilar alloy 690-SUS 304L joints formed by EBW and GTAW

    International Nuclear Information System (INIS)

    This study investigates the correlation between the microstructure and the corrosion resistance properties of the fusion zone of Alloy 690-SUS 304L stainless steel dissimilar weldments formed by electron beam welding (EBW). The effects of the EBW process are evaluated by comparing the microstructure and corrosion resistance properties of the EBW weldment with those of Alloy 690-SUS 304L weldment formed by gas tungsten arc welding (GTAW). The experimental results reveal that the interdendritic region of the fusion zone of the EBW weldment contains fine TiN precipitates and Cr-Ni rich phases. The TiN precipitates are originated from the Alloy 690 base metal, while the Cr-Ni rich phases, a new formation of precipitates, is precipitated in the region around TiN during solidification. Microscopic analysis of the samples following a modified Huey test indicates that the matrix around TiN precipitate and the Cr-Ni rich phase precipitate provide the preferred sites for corrosion pit initiation. Due to the rapid cooling in the EBW process, relatively fewer and smaller TiN precipitates and Cr-Ni rich phases are formed in the weldment. Consequently, only limited corrosive pitting is observed which indicates better interdendritic corrosion resistance properties in comparison to joints with GTAW process. Furthermore, rapid solidification in the fusion zone results not only the suppression of chromium carbide precipitation but also the chromium depletion at the grain boundaries. As a result, the intergranular corrosion resistance and interdendritic corrosion resistance of the EBW weldment are significantly higher than that of the GTAW weldment. (author)

  5. Process-microstructure-corrosion interrelations for stainless steel

    OpenAIRE

    Lindell, David

    2015-01-01

    Stainless steels were first developed in the early 20th century and have since then emerged as a very diverse class of engineering materials. Along with steels having new combinations of properties, there is a continuous development of new technologies allowing the material to be produced in a faster and more energy effcient manner. A prerequisite for new technologies to be adapted quicklyis a fundamental understanding of the microstructure evolution throughout theprocess chain. The first par...

  6. High density sintered stainless steels with improved properties

    OpenAIRE

    M. Actis Grande; M. Rosso

    2007-01-01

    Purpose: of this paper is the study of the properties of sintered AISI 316L (1.4404 according to EN 10088. Sintered stainless steels occupy a prominent position in the high alloyed steels, however their properties are limited by the presence of porosity. The improvement of quality and performances of products coupled with a reduction of manufacturing costs calls for high compacting pressures, as well as high sintering temperatures. However, the possibility to fill the open porosity of sintere...

  7. Hydrometallurgical removal of zinc from stainless steel flue dusts

    OpenAIRE

    Järvinen, Outi

    2013-01-01

    Stainless steel flue dusts are problematic to the steel industry because of their chemi-cal composition that makes direct recycling and landfilling impossible. Pyrometallur-gical and hydrometallurgical processes have been tested in dust treatment. At the moment, most of the processes that have reached commercialization have been py-rometallurgical. Still, it is thought that hydrometallurgy could offer solutions espe-cially in small scale on-site treatment as it is less energy intensive and re...

  8. Construction of a stainless steel storage tank for phosphoric acid

    OpenAIRE

    Buh, Igor

    2006-01-01

    The main purpose of this thesis was to get acquainted with all necessary procedures for steel storage tank manufacturing and assembly control. The representative storage tank was built from stainless steel and it was designed to hold 750 m3 of phosphoric acid. In the first section all legally mandatory control procedures are described and they are applied to our storage tank in the second section. Welding control is presented, which consists of destructive and non-destructive inspections of t...

  9. Stainless steel weld metal designed to mitigate residual stresses

    OpenAIRE

    Shirzadi, A. A.; Bhadeshia, H. K. D. H.; Karlsson, L.; Withers, P.J.

    2009-01-01

    There have been considerable efforts to create welding consumables which on solid state phase transformation partly compensate for the stresses which develop when a constrained weld cools to ambient temperatures. All of these efforts have focused on structural steels which are ferritic. In the present work, alloy design methods have been used to create a stainless steel welding consumable which solidifies as δ ferrite, transforms almost entirely into austenite which then undergoes martensitic...

  10. Instrumental Neuron Activation Analysis for certification of stainless steel materials

    International Nuclear Information System (INIS)

    The use of Instrumental Neuron Activation Analysis (INAA) may contribute to improve the certification of the materials, especially in the case of minor and trace elements. In presented paper the INAA method of analysis of stainless steel materials has been elaborated. The obtained results were compared with those of common analytical techniques. The presented results show the usefulness of the INAA method for the certification of CRMs for the iron and steel industry

  11. Mechanical properties of low-nickel stainless steel

    Science.gov (United States)

    Montano, J. W.

    1978-01-01

    Demand for improved corrosion-resistant steels, coupled with increased emphasis on conserving strategic metals, has led to development of family of stainless steels in which manganese and nitrogen are substituted for portion of usual nickel content. Advantages are approximately-doubled yield strength in annealed condition, better resistance to stress-corrosion cracking, retention of low magnetic permeability even after severe cold working, excellent strength and ductility at cryogenic temperatures, superior resistance to wear and galling, and excellent high-temperature properties.

  12. Properties of super stainless steels for orthodontic applications.

    Science.gov (United States)

    Oh, Keun-Taek; Kim, Young-Sik; Park, Yong-Soo; Kim, Kyoung-Nam

    2004-05-15

    Orthodontic stainless-steel appliances are considered to be corrosion resistant, but localized corrosion can occur in the oral cavity. This study was undertaken to evaluate the properties of super stainless steels in orthodontic applications. Accordingly, the metallurgical properties, mechanical properties, corrosion resistance, amount of the released nickel, cytotoxicity, and characteristics of the passive film were investigated. Corrosion resistances of the specimens were high and in the following order: super austenitic stainless steel (SR-50A) > super ferritic stainless steel (SFSS) = super duplex stainless steel (SR-6DX) > 316L SS > super martensitic stainless steel (SR-3Mo) in artificial saliva, 37 degrees C. At 500 mV (SCE), current densities of SR-50A, SFSS, SR-6DX, 316L SS, and SR-3Mo were 5.96 microA/cm(2), 20.3 microA/cm(2), 31.9 microA/cm(2), 805 microA/cm(2), and 5.36 mA/cm(2), respectively. Open circuit potentials of SR-50A, 316L SS, SR-6DX, SR-3Mo, and SFSS were - 0.2, - 0.22, - 0.24, - 0.43, and - 0.46 V (SCE), respectively. SR-50A, SFSS, and SR-6DX released below 3 ng/ml nickel for 8 weeks, and increased a little with immersion time, and 316L SS released about 3.5 ng/ml nickel, but SR-3Mo released a large amount of nickel, which increased with immersion time. The study demonstrated that SR-50A, SR-6DX, and SFSS have high corrosion resistance and mild or no cytotoxicity, due to the passive film enhanced by synergistic effect of Mo + N or by high addition effect of Cr + W. All super stainless steels showed very low cytotoxicity regardless of their nickel contents, although SR-3Mo was found to be relatively cytotoxic. From these studies, these steels are considered suitable for orthodontic applications. PMID:15116408

  13. Estudo comparativo entre os aços inoxidáveis dúplex e os inoxidáveis AISI 304L/316L

    Directory of Open Access Journals (Sweden)

    Marcelo Senatore

    2007-03-01

    Full Text Available Os aços inoxidáveis dúplex ferríticos-austeníticos fazem parte de uma classe de materiais com microestrutura bifásica, composta por uma matriz ferrítica e ilhas de austenita, com frações volumétricas aproximadamente iguais dessas fases. Essa classe de materiais é caracterizada por apresentar interessante combinação de elevadas propriedades mecânicas e de resistência à corrosão e, por isso, é considerada bastante versátil. Os aços inoxidáveis dúplex são, freqüentemente, utilizados nas indústrias química e petroquímica, de papel e celulose, siderúrgicas, alimentícias e de geração de energia. O presente trabalho estabelece um comparativo entre as propriedades físicas, mecânicas e de resistência à corrosão dos aços inoxidáveis duplex e os tradicionais aços inoxidáveis austeníticos AISI 304L e 316L, largamente utilizados na indústria brasileira. Resultados de ensaios laboratoriais e dados relevantes de experiências práticas desses materiais também são apresentados.Ferritic-austenitic duplex stainless steels are part of a class of material having a two-phase microestructure, comprised of a ferritic matrix and austenitic islands, with the volumetric fractions approximately the same in these phases. This class of material is characterized by the presentation of an interesting combination of high mechanical properties and corrosion resistance and is therefore considered quite versatile. The duplex stainless steels are often used in the chemical, petrochemical, pulp & paper and food industries, as well as in steel foundaries and energy power plants. This paper shows a comparison between the physical, mechanical and corrosion resistance properties of duplex stainless steels and the traditional austenitic stainless steels 304L and 316L, largely used in the Brazilian industry. Results of laboratory tests and relevant data on practical experiments on these materials are also presented.

  14. Adhesion of food-borne bacteria to stainless steel is reduced by food conditioning films

    DEFF Research Database (Denmark)

    Bernbom, Nete; Ng, Yin; Jorgensen, R.L.;

    2009-01-01

    to stainless steel. Attachment of Pseudomonas fluorescens AH2 to stainless steel coated with water-soluble coatings of animal origin was significantly reduced as compared with noncoated stainless steel or stainless steel coated with laboratory substrate or extracts of plant origin. Coating with animal extracts...... also decreases adhesion of other food-relevant bacteria. The manipulation of adhesion was not attributable to growth inhibitory effects. Chemical analysis revealed that the stainless steels were covered by homogenous layers of adsorbed proteins. The presence of tropomyocin was indicated by appearance...

  15. Effect of ultrafine grain on tensile behaviour and corrosion resistance of the duplex stainless steel.

    Science.gov (United States)

    Jinlong, Lv; Tongxiang, Liang; Chen, Wang; Limin, Dong

    2016-05-01

    The ultrafine grained 2205 duplex stainless steel was obtained by cold rolling and annealing. The tensile properties were investigated at room temperature. Comparing with coarse grained stainless steel, ultrafine grained sample showed higher strength and plasticity. In addition, grain size changed deformation orientation. The strain induced α'-martensite was observed in coarse grained 2205 duplex stainless steel with large strain. However, the grain refinement inhibited the transformation of α'-martensite;nevertheless, more deformation twins improved the strength and plasticity of ultrafine grained 2205 duplex stainless steel. In addition, the grain refinement improved corrosion resistance of the 2205 duplex stainless steel in sodium chloride solution. PMID:26952459

  16. Ionic bombardment of stainless steel by nitrogen and nickel ions immersion

    Institute of Scientific and Technical Information of China (English)

    XIONG Ling; HU Yong-jun; XU jian; MENG Ji-long

    2008-01-01

    A new nitriding process was used to carry out the ionic bombardment, in which nickel ion was introduced. The microstructure, composition and properties of the treated stainless steel were studied by means of scanning electron microscopy(SEM), micro-hardness test and electrochemistry method. The results show that the hardness of the stainless steel is greatly increased after ionic bombardment under nitrogen and nickel ions immersion. Vickers' hardness as high as Hv1268 is obtained. The bombarded stainless steel is of a little reduction in corrosion resistance, as compared with the original stainless steel. However, as compared with the traditional ion-nitriding stainless steel, the corrosion resistance is greatly improved.

  17. Effect of ultrafine grain on tensile behaviour and corrosion resistance of the duplex stainless steel.

    Science.gov (United States)

    Jinlong, Lv; Tongxiang, Liang; Chen, Wang; Limin, Dong

    2016-05-01

    The ultrafine grained 2205 duplex stainless steel was obtained by cold rolling and annealing. The tensile properties were investigated at room temperature. Comparing with coarse grained stainless steel, ultrafine grained sample showed higher strength and plasticity. In addition, grain size changed deformation orientation. The strain induced α'-martensite was observed in coarse grained 2205 duplex stainless steel with large strain. However, the grain refinement inhibited the transformation of α'-martensite;nevertheless, more deformation twins improved the strength and plasticity of ultrafine grained 2205 duplex stainless steel. In addition, the grain refinement improved corrosion resistance of the 2205 duplex stainless steel in sodium chloride solution.

  18. Redemption of asthma pharmaceuticals among stainless steel and mild steel welders

    DEFF Research Database (Denmark)

    Kristiansen, Pernille; Jørgensen, Kristian Tore; Hansen, Johnni;

    2015-01-01

    PURPOSE: The purpose was to examine bronchial asthma according to cumulative exposure to fume particulates conferred by stainless steel and mild steel welding through a proxy of redeemed prescribed asthma pharmaceuticals. METHODS: A Danish national company-based historical cohort of 5,303 male ever...... was estimated by combining questionnaire data on welding work with a welding exposure matrix. The estimated exposure accounted for calendar time, welding intermittence, type of steel, welding methods, local exhaustion and welding in confined spaces. Hazard ratios (HRs) with 95 % confidence intervals (CIs) were...... nonsignificant increased rate of redemption of asthma medicine was observed among high-level exposed stainless steel welders in comparison with low-level exposed welders (HR 1.54, 95 % CI 0.76-3.13). This risk increase was driven by an increase risk among non-smoking stainless steel welders (HR 1.46, 95 % CI 1...

  19. Effect of pulsating water jet peening on stainless steel

    OpenAIRE

    Hlaváček, Petr

    2015-01-01

    Effects of action of pulsating water jet on polished surface of the stainless steel AISI 316L are presented. Surface slip bands appeared after this treatment. In the most severe conditions, microcracks were formed. Hardness measurement showed that the affected layer was thinner than 60 μm. Application of the pulsating water jet has beneficial effect on the fatigue life of the material.

  20. Fatigue behavior of welded austenitic stainless steel in different environments

    Directory of Open Access Journals (Sweden)

    D.S. Yawas

    2014-01-01

    Full Text Available The fatigue behavior of welded austenitic stainless steel in 0.5 M hydrochloric acid and wet steam corrosive media has been investigated. The immersion time in the corrosive media was 30 days to simulate the effect on stainless steel structures/equipment in offshore and food processing applications and thereafter annealing heat treatment was carried out on the samples. The findings from the fatigue tests show that seawater specimens have a lower fatigue stress of 0.5 × 10−5 N/mm2 for the heat treated sample and 0.1 × 10−5 N/mm2 for the unheat-treated sample compared to the corresponding hydrochloric acid and steam samples. The post-welding heat treatment was found to increase the mechanical properties of the austenitic stainless steel especially tensile strength but it reduces the transformation and thermal stresses of the samples. These findings were further corroborated by the microstructural examination of the stainless steel specimen.

  1. Failure Assessment Diagram for Brazed 304 Stainless Steel Joints

    Science.gov (United States)

    Flom, Yory

    2011-01-01

    Interaction equations were proposed earlier to predict failure in Albemet 162 brazed joints. Present study demonstrates that the same interaction equations can be used for lower bound estimate of the failure criterion in 304 stainless steel joints brazed with silver-based filler metals as well as for construction of the Failure Assessment Diagrams (FAD).

  2. Sticking Phenomenon Occurring during Hot Rolling of Ferritic Stainless Steels

    International Nuclear Information System (INIS)

    Sticking phenomenon occurring during hot rolling of two ferritic stainless steels, STS 430J1L and STS 436L, was investigated in this study. A hot rolling simulation test was carried out using a high-temperature wear tester capable of controlling rolling speed, load, and temperature. The simulation test results at 900 .deg. C and 1000 .deg. C revealed that the sticking process proceeded with three stages, i.e., nucleation, growth, and saturation, for the both stainless steels, and that STS 430J1L had a smaller number of sticking nucleation sites than the STS436L because of higher high-temperature hardness, thereby leading to a smaller amount of the sticking. When the test temperature was 1070 .deg. C, the sticking hardly occurred in both stainless steels as Fe-Cr oxide layers were formed on the surface of the rolled materials. These findings suggested that the improvement of high-temperature properties of stainless steels and the appropriate rolling conditions for readily forming oxide layers on the rolled material surface were required in order to prevent or minimize the sticking

  3. Hydrogen embrittlement of super duplex stainless steel in acid solution

    Energy Technology Data Exchange (ETDEWEB)

    Elhoud, A.M.; Renton, N.C.; Deans, W.F. [University of Aberdeen, School of Engineering, Aberdeen, AB24 3UE (United Kingdom)

    2010-06-15

    Super duplex stainless steel (SDSS) is a good choice of material when resistance to harsh environments is needed. Despite the material's excellent corrosion resistance and high strength, a number of in-service failures have been recorded. The root cause of these failures was environmentally induced cracking initiated at manufacturing and in-service metallurgical defects. In this study the hydrogen embrittlement of pre-strained super duplex stainless steel specimens was investigated after 48 h cathodic charging in 0.1 M H{sub 2}SO{sub 4}. The metallurgical changes that resulted from four levels of cold work (4, 8, 12, and 16% plastic strain) were considered and their effect on the embrittlement of the SDSS alloy was investigated. After hydrogen charging, the specimens were pulled immediately to failure and the mechanical properties evaluated. The obtaining fracture morphology was investigated using low and high magnification microscopy. Experimental results indicated that charging the super duplex stainless steel alloy with hydrogen caused varying degrees of embrittlement depending on cold work level. Increasing cold work resulted in a reduction of the elongation to failure. Microscopic investigation confirmed the significant effect of cold work on the hydrogen embrittlement susceptibility of the super duplex stainless steel alloy investigated. (author)

  4. Resistance microwelding of 316L stainless steel wire to block

    DEFF Research Database (Denmark)

    Friis, Kasper Storgaard; Khan, M.I.; Bay, Niels;

    2011-01-01

    The excellent corrosion resistance of low carbon vacuum melted 316 stainless steel coupled with its non-magnetic properties makes it ideal for biomedical applications. The typical joint geometry for microcomponents, such as medical implants, includes joining of fine wire to a larger block. However...

  5. New Stainless Steel Alloys for Low Temperature Surface Hardening?

    DEFF Research Database (Denmark)

    Christiansen, Thomas Lundin; Dahl, Kristian Vinter; Somers, Marcel A. J.

    2015-01-01

    The present contribution showcases the possibility for developing new surface hardenable stainless steels containing strong nitride/carbide forming elements (SNCFE). Nitriding of the commercial alloys, austenitic A286, and ferritic AISI 409 illustrates the beneficial effect of having SNCFE presen...

  6. Solidification cracking in austenitic stainless steel welds

    Indian Academy of Sciences (India)

    V Shankar; T P S Gill; S L Mannan; S Sundaresan

    2003-06-01

    Solidification cracking is a significant problem during the welding of austenitic stainless steels, particularly in fully austenitic and stabilized compositions. Hot cracking in stainless steel welds is caused by low-melting eutectics containing impurities such as S, P and alloy elements such as Ti, Nb. The WRC-92 diagram can be used as a general guide to maintain a desirable solidification mode during welding. Nitrogen has complex effects on weld-metal microstructure and cracking. In stabilized stainless steels, Ti and Nb react with S, N and C to form low-melting eutectics. Nitrogen picked up during welding significantly enhances cracking, which is reduced by minimizing the ratio of Ti or Nb to that of C and N present. The metallurgical propensity to solidification cracking is determined by elemental segregation, which manifests itself as a brittleness temperature range or BTR, that can be determined using the varestraint test. Total crack length (TCL), used extensively in hot cracking assessment, exhibits greater variability due to extraneous factors as compared to BTR. In austenitic stainless steels, segregation plays an overwhelming role in determining cracking susceptibility.

  7. 77 FR 1504 - Stainless Steel Wire Rod From India

    Science.gov (United States)

    2012-01-10

    ... Commission instituted this review on July 1, 2011 (76 FR 38686) and determined on October 4, 2011, that it would conduct an expedited review (76 FR 64105, October 17, 2011). The Commission transmitted its... COMMISSION Stainless Steel Wire Rod From India Determination On the basis of the record \\1\\ developed in...

  8. Alternative to Nitric Acid for Passivation of Stainless Steel Alloys

    Science.gov (United States)

    Lewis, Pattie L.; Kolody, Mark; Curran, Jerry

    2013-01-01

    Corrosion is an extensive problem that affects the Department of Defense (DoD) and National Aeronautics and Space Administration (NASA). The deleterious effects of corrosion result in steep costs, asset downtime affecting mission readiness, and safety risks to personnel. Consequently, it is vital to reduce corrosion costs and risks in a sustainable manner. The DoD and NASA have numerous structures and equipment that are fabricated from stainless steel. The standard practice for protection of stainless steel is a process called passivation. Typical passivation procedures call for the use of nitric acid; however, there are a number of environmental, worker safety, and operational issues associated with its use. Citric acid offers a variety of benefits including increased safety for personnel, reduced environmental impact, and reduced operational cost. DoD and NASA agreed to collaborate to validate citric acid as an acceptable passivating agent for stainless steel. This paper details our investigation of prior work developing the citric acid passivation process, development of the test plan, optimization of the process for specific stainless steel alloys, ongoing and planned testing to elucidate the process' resistance to corrosion in comparison to nitric acid, and preliminary results.

  9. Elaboration of selective solar energy absorbers beginning with stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Aries, L.; Bonino, J.P.; Benavente, R.; Laaouini, A.; Traverse, J.P.

    1981-01-01

    An original simple and cheap method of elaboration of selective surfaces is described. The method involves anodic oxydation of stainless steel in acid solution with addition of sulfides; chemical conversion of the metallic surface is achieved. The selective surfaces exhibit an excellent thermal stability.

  10. Metal release from stainless steel in biological environments: A review.

    Science.gov (United States)

    Hedberg, Yolanda S; Odnevall Wallinder, Inger

    2016-03-01

    Due to its beneficial corrosion resistance, stainless steel is widely used in, e.g., biomedical applications, as surfaces in food contact, and for products intended to come into skin contact. Low levels of metals can be released from the stainless steel surface into solution, even for these highly corrosion resistant alloys. This needs to be considered in risk assessment and management. This review aims to compile the different metal release mechanisms that are relevant for stainless steel when used in different biological settings. These mechanisms include corrosion-induced metal release, dissolution of the surface oxide, friction-induced metal release, and their combinations. The influence of important physicochemical surface properties, different organic species and proteins in solution, and of biofilm formation on corrosion-induced metal release is discussed. Chemical and electrochemical dissolution mechanisms of the surface oxides of stainless steel are presented with a focus on protonation, complexation/ligand-induced dissolution, and reductive dissolution by applying a perspective on surface adsorption of complexing or reducing ligands and proteins. The influence of alloy composition, microstructure, route of manufacture, and surface finish on the metal release process is furthermore discussed as well as the chemical speciation of released metals. Typical metal release patterns are summarized. PMID:26514345

  11. Transformation in Austenitic Stainless Steel Sheet under Different Loading Directions

    NARCIS (Netherlands)

    Boogaard, van den A.H.; Krauer, J.; Hora, P.

    2011-01-01

    The stress-strain relation for austenitic stainless steels is based on 2 main contributions: work hardening and a phase transformation from austenite to martensite. The transformation is highly temperature dependent. In most models for phase transformation from austenite to martensite, the stress tr

  12. Heat treatment method for two-phase stainless steel

    International Nuclear Information System (INIS)

    A two-phase stainless steel the toughness of which is reduced by exposure to a high temperature is kept at from 900degC to 1040degC to be solidified and then quenched. With such procedures, a δ-phase deposited in a ferrite phase can be eliminated to restore the toughness. In the solidification step, the two-phase stainless steel having a plate thickness of 1cm or less is kept for 15mins or more, and is kept for additional 5min on every increase of the thickness of 1cm, and then it is compulsorily cooled with water or air. In the heat treatment comprising such steps, a Cr-depleted layer of the welded portion of the two-phase stainless steel of reduced toughness is eliminated to restore an initial state thereby enabling to maintain the integrity of the welded portion. Since the δ-phase deposited in the ferrite phase can be eliminated by solid-solubilizing the two phase stainless steel of reduced toughness by induction heating, reduced toughness can be restored thereby enabling to keep the integrity. (T.M.)

  13. Towards commercialization of fast gaseous nitrocarburising stainless steel

    DEFF Research Database (Denmark)

    Hummelshøj, Thomas Strabo; Christiansen, Thomas; Somers, Marcel A. J.

    2010-01-01

    A novel method for fast and versatile low temperature nitrocarburising of stainless steel has recently been invented by the present authors. Selected results obtained with this new surface hardening process are presented. It is shown that it is possible to obtain a case thickness of 20 μm on...

  14. Sticking Phenomenon Occurring during Hot Rolling of Ferritic Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Son, Chang Young; Kim, Chang Kyu; Ha, Dae Jin; Lee, Sung Hak [Pohang Univ. of Institute of Science and Technology, Pohang (Korea, Republic of); Lee, Jong Seog; Kim, Kwang Tae; Lee, Yong Deuk [POSCO Technical Research Lab., Gwangyang (Korea, Republic of)

    2007-01-15

    Sticking phenomenon occurring during hot rolling of two ferritic stainless steels, STS 430J1L and STS 436L, was investigated in this study. A hot rolling simulation test was carried out using a high-temperature wear tester capable of controlling rolling speed, load, and temperature. The simulation test results at 900 .deg. C and 1000 .deg. C revealed that the sticking process proceeded with three stages, i.e., nucleation, growth, and saturation, for the both stainless steels, and that STS 430J1L had a smaller number of sticking nucleation sites than the STS436L because of higher high-temperature hardness, thereby leading to a smaller amount of the sticking. When the test temperature was 1070 .deg. C, the sticking hardly occurred in both stainless steels as Fe-Cr oxide layers were formed on the surface of the rolled materials. These findings suggested that the improvement of high-temperature properties of stainless steels and the appropriate rolling conditions for readily forming oxide layers on the rolled material surface were required in order to prevent or minimize the sticking.

  15. Phase formation at bonded vanadium and stainless steel interfaces

    International Nuclear Information System (INIS)

    The interface between vanadium bonded to stainless steel was studies to determine whether a brittle phase formed during three joining operations. Inertia friction welds between V and 21-6-9 stainless steel were examined using TEM. In the as-welded condition, a continuous, polygranular intermetallic layer about 0.25 μm thick was present at the interface. This layer grew to about 50 μm thick during heat treatment at 1000 degrees C for two hours. Analysis of electron diffraction patterns confirmed that this intermetallic was the ω phase. The interface between vanadium and type 304, SANDVIK SAF 2205, and 21-6-9 stainless steel bonded by a co-extrusion process had intermetallic particles at the interface in the as-extruded condition. Heat treatment at 1000 degrees C for two hours caused these particles to grow into continuous layers in all three cases. Based on the appearance, composition and hardness of this interfacial intermetallic, it was also concluded to be ω phase. Bonding V to type 430 stainless steel by co-extrusion caused V-rich carbides to form at the interface due to the higher concentration of C in the type 430 than in the other stainless steels investigated. The carbide particles initially present grew into a continuous layer during a two-hour heat treatment at 1000 degrees C. Co-hipping 21-6-9 stainless steel tubing with V rod resulted in slightly more concentric specimens than the co-extruded ones, but a continuous layer of the ω phase formed during the hipping operation. This brittle layer could initiate failure during subsequent forming operations. The vanadium near the stainless steel interface in the co-extruded and co-hipped tubing in some cases was harder than before heat treatment. It was concluded that this hardening was due to thermal straining during cooling following heat treatment and that thermal strains might present a greater problem than seen here when longer tubes are used in actual applications

  16. Behaviour of cold-formed stainless steel beams at elevated temperatures

    Institute of Scientific and Technical Information of China (English)

    Ju CHEN; Wei-liang JIN

    2008-01-01

    A study of the behaviour of constructional cold-formed stainless steel beams at elevated temperatures was conducted in this paper.An accurate finite element model(FEM)for stainless steel beams was developed using the finite element program ABAQUS.Stainless steel beams having different cross-sections were simulated in this study.The nonlinear FEM was verified against the experimental results.Generally,the developed FEM could accurately simulate the stainless steel beams.Based on the high temperature stainless steel material test results,a parametric study was carried out on stainless steel beams at elevated tem-peratures using the verified FEM.Both high strength stainless steel EN 1.4462 and normal strength stainless steel EN 1.4301 were considered.A total of 42 stainless steel beams were simulated in the parametric study.The effect of temperatures on the behaviour of stainless steel beams was investigated.In addition,a limiting temperature for stainless steel beams was also proposed.

  17. Fatigue Crack Growth Behavior of Gas Metal Arc Welded AISI 409 Grade Ferritic Stainless Steel Joints

    Science.gov (United States)

    Lakshminarayanan, A. K.; Shanmugam, K.; Balasubramanian, V.

    2009-10-01

    The effect of filler metals such as austenitic stainless steel, ferritic stainless steel, and duplex stainless steel on fatigue crack growth behavior of the gas metal arc welded ferritic stainless steel joints was investigated. Rolled plates of 4 mm thickness were used as the base material for preparing single ‘V’ butt welded joints. Center cracked tensile specimens were prepared to evaluate fatigue crack growth behavior. Servo hydraulic controlled fatigue testing machine with a capacity of 100 kN was used to evaluate the fatigue crack growth behavior of the welded joints. From this investigation, it was found that the joints fabricated by duplex stainless steel filler metal showed superior fatigue crack growth resistance compared to the joints fabricated by austenitic and ferritic stainless steel filler metals. Higher yield strength and relatively higher toughness may be the reasons for superior fatigue performance of the joints fabricated by duplex stainless steel filler metal.

  18. Low temperature surface hardening of stainless steel; the role of plastic deformation

    DEFF Research Database (Denmark)

    Bottoli, Federico; Jespersen, Freja Nygaard; Hattel, Jesper Henri;

    2016-01-01

    Thermochemical surface engineering by nitriding of austenitic stainless steel transforms the surface zone into expanded austenite, which improves the wear resistance of the stainless steel while preserving the stainless behavior. As a consequence of the thermochemical surface engineering, huge......: - plastic deformation of metastable austenitic stainless steels leads to the development of strain-induced martensite, which compromises the uniformity and the homogeneity of the expanded austenite zone. - during low temperature surface engineering composition and stress profiles develop. On numerical...

  19. Stress corrosion cracking susceptibility of dissimilar stainless steels welded joints

    OpenAIRE

    J. Łabanowski

    2007-01-01

    Purpose: The aim of the current study is to reveal the influence of welding conditions on structure and stresscorrosion cracking resistance of dissimilar stainless steels butt welded joints.Design/methodology/approach: Butt joints between duplex 2205 and austenitic 316L steels were performedwith the use of submerged arc welding (SAW) method. The plates 15 mm in thickness were welded with heatinput in the range of 1.15 – 3.2 kJ/mm using duplex steel filler metal. Microstructure examinations an...

  20. Optimisation of welding procedures for duplex and superduplex stainless steels

    International Nuclear Information System (INIS)

    Austenitic stainless steels are increasingly being replaced by duplex grades that can offer similar corrosion resistance with far higher strength. This increased strength makes it possible to reduce material consumption whilst also decreasing transport and construction costs. Although established welding methods used for austenitic steels can be used for duplex steels, modification of the procedures can lead to improved results. This paper reviews the welding of duplex stainless steel and examines precautions that may be required. The advantages and disadvantages of different welding methods are highlighted and some high productivity solutions are presented. The application of a more efficient process with a high deposition rate (e.g. flux- cored arc welding) can decrease labour costs. Further close control of heat input and interpass temperature can result in more favourable microstructures and final properties. Although welding adversely affects the corrosion resistance of austenitic and duplex stainless steels, particularly the pitting resistance, relative to the parent material, this problem can be minimised by proper backing gas protection and subsequent pickling.

  1. Irradiation-assisted stress corrosion cracking behavior of austenitic stainless steels applicable to LWR core internals.

    Energy Technology Data Exchange (ETDEWEB)

    Chung, H. M.; Shack, W. J.; Energy Technology

    2006-01-31

    This report summarizes work performed at Argonne National Laboratory on irradiation-assisted stress corrosion cracking (IASCC) of austenitic stainless steels that were irradiated in the Halden reactor in simulation of irradiation-induced degradation of boiling water reactor (BWR) core internal components. Slow-strain-rate tensile tests in BWR-like oxidizing water were conducted on 27 austenitic stainless steel alloys that were irradiated at 288 C in helium to 0.4, 1.3, and 3.0 dpa. Fractographic analysis was conducted to determine the fracture surface morphology. Microchemical analysis by Auger electron spectroscopy was performed on BWR neutron absorber tubes to characterize grain-boundary segregation of important elements under BWR conditions. At 0.4 and 1.4 dpa, transgranular fracture was mixed with intergranular fracture. At 3 dpa, transgranular cracking was negligible, and fracture surface was either dominantly intergranular, as in field-cracked core internals, or dominantly ductile or mixed. This behavior indicates that percent intergranular stress corrosion cracking determined at {approx}3 dpa is a good measure of IASCC susceptibility. At {approx}1.4 dpa, a beneficial effect of a high concentration of Si (0.8-1.5 wt.%) was observed. At {approx}3 dpa, however, such effect was obscured by a deleterious effect of S. Excellent resistance to IASCC was observed up to {approx}3 dpa for eight heats of Types 304, 316, and 348 steel that contain very low concentrations of S. Susceptibility of Types 304 and 316 steels that contain >0.003 wt.% S increased drastically. This indicates that a sulfur related critical phenomenon plays an important role in IASCC. A sulfur content of <0.002 wt.% is the primary material factor necessary to ensure good resistance to IASCC. However, for Types 304L and 316L steel and their high-purity counterparts, a sulfur content of <0.002 wt.% alone is not a sufficient condition to ensure good resistance to IASCC. This is in distinct contrast to

  2. Aging degradation of cast stainless steels: Effects on mechanical properties

    International Nuclear Information System (INIS)

    A program is being conducted to investigate the significance of in-service embrittlement of cast duplex stainless steels under light-water operating conditions. Mechanical property data are presented from Charpy-impact, tensile, and J-R curve tests for several heats of cast stainless steel aged up to 10,000 h at 450, 400, 350, 320, and 2900C. The results indicate that thermal aging increases the tensile strength and decreases the impact energy, J/sub IC/, and tearing modulus of the steels. Also, the ductile-to-brittle transition curve shifts to higher temperatures. The fracture toughness results are consistent with the Charpy-impact data, i.e., the relative reduction in J/sub IC/ is similar to the relative decrease in impact energy. The ferrite content and concentration of C in the steel have a strong effect on the overall process of low-temperature embrittlement. The low-carbon CF-3 steels are the most resistant and Mo-containing CF-8M steels are most susceptible to embrittlement. Weakening of the ferrite/austenite phase boundaries by carbide precipitates has a significant effect on the kinetics and extent of embrittlement of the high-carbon CF-8 and CF-8M steels, particularly after aging at temperatures ≥4000C. The influence of N content and distribution of ferrite on loss of toughness are discussed. The data also indicate that existing correlations do not accurately represent the embrittlement behavior over the temperature range 280 to 4500C, i.e., extrapolation of high-temperature data to reactor temperatures may not be valid for some compositions of cast stainless steel

  3. Strain induced grain boundary migration effects on grain growth of an austenitic stainless steel during static and metadynamic recrystallization

    Energy Technology Data Exchange (ETDEWEB)

    Paggi, A., E-mail: alpaggi@tenaris.com [Tenaris Dalmine R& D, Dalmine S.p.A., Piazza Caduti 6 Luglio 1944 n.1, 24044 Dalmine (Italy); Angella, G.; Donnini, R. [National Research Council (CNR), Institute for Energetics and Interphases (IENI), Via Roberto Cozzi 53, 20125 Milano (Italy)

    2015-09-15

    Static and metadynamic recrystallization of an AISI 304L austenitic stainless steel was investigated at 1100 °C and 10{sup −} {sup 2} s{sup −} {sup 1} strain rate. The kinetics of recrystallization was determined through double hit compression tests. Two strain levels were selected for the first compression hit: ε{sub f} = 0.15 for static recrystallization (SRX) and 0.25 for metadynamic recrystallization (MDRX). Both the as-deformed and the recrystallized microstructures were investigated through optical microscopy and electron back-scattered diffraction (EBSD) technique. During deformation, strain induced grain boundary migration appeared to be significant, producing a square-like grain boundary structure aligned along the directions of the maximum shear stresses in compression. EBSD analysis revealed to be as a fundamental technique that the dislocation density was distributed heterogeneously in the deformed grains. Grain growth driven by surface energy reduction was also investigated, finding that it was too slow to explain the experimental data. Based on microstructural results, it was concluded that saturation of the nucleation sites occurred in the first stages of recrystallization, while grain growth driven by strain induced grain boundary migration (SIGBM) dominated the subsequent stages. - Highlights: • Recrystallization behavior of a stainless steel was investigated at 1100 °C. • EBSD revealed that the dislocation density distribution was heterogeneous during deformation. • Saturation of nucleation sites occurred in the first stages of recrystallization. • Strain induced grain boundary migration (SIGBM) effects were significant. • Grain growth driven by SIGBM dominated the subsequent stages.

  4. Thermal stability of ultrafine-grained austenitic stainless steels

    International Nuclear Information System (INIS)

    Ultrafine-grained 316 and 304 austenitic stainless steel samples have been produced by high pressure torsion. Their microstructure, after deformation and annealing at a temperature in the 350-900 deg. C range, has been characterized using several techniques (transmission electron microscopy, X-ray diffraction, Moessbauer spectroscopy). The average grain size in the ultrafine-grained 316 is about 40 nm while it is larger in the ultrafine-grained 304 due to a smaller deformation. Results show the formation of α'-martensite during deformation in both steels while ε-martensite is formed only in the 304 steel. Annealing at 350 deg. C induces the decrease of α'-martensite content in the 316 steel. The trend is different in the 304 steel, in which the α'-martensite content increases. Recrystallization of grains is observed from 700 deg. C. Moessbauer spectroscopy shows a reduction of the level of solute atoms in α'-martensite during annealing.

  5. 2012 ACCOMPLISHMENTS - TRITIUM AGING STUDIES ON STAINLESS STEELS

    Energy Technology Data Exchange (ETDEWEB)

    Morgan, M.

    2013-01-31

    This report summarizes the research and development accomplishments during FY12 for the tritium effects on materials program. The tritium effects on materials program is designed to measure the long-term effects of tritium and its radioactive decay product, helium-3, on the structural properties of forged stainless steels which are used as the materials of construction for tritium reservoirs. The FY12 R&D accomplishments include: (1) Fabricated and Thermally-Charged 150 Forged Stainless Steel Samples with Tritium for Future Aging Studies; (2) Developed an Experimental Plan for Measuring Cracking Thresholds of Tritium-Charged-and-Aged Steels in High Pressure Hydrogen Gas; (3) Calculated Sample Tritium Contents For Laboratory Inventory Requirements and Environmental Release Estimates; (4) Published report on “Cracking Thresholds and Fracture Toughness Properties of Tritium-Charged-and-Aged Stainless Steels”; and, (5) Published report on “The Effects of Hydrogen, Tritium, and Heat Treatment on the Deformation and Fracture Toughness Properties of Stainless Steels”. These accomplishments are highlighted here and references given to additional reports for more detailed information.

  6. Corrosion Behavior of Austenitic and Duplex Stainless Steels in Lithium Bromide

    OpenAIRE

    Ayo Samuel AFOLABI; Alaneme, K.K.; Samson Oluwaseyi BADA

    2009-01-01

    The corrosion behavior of austenitic and duplex stainless steels in various concentrations of lithium, bromide solution was investigated by using the conventional weight loss measurement method. The results obtained show that corrosion of these steels occurred due to the aggressive bromide ion in the medium. Duplex stainless steel shows a greater resistance to corrosion than austenitic stainless steel in the medium. This was attributed to equal volume proportion of ferrite and austenite in th...

  7. Toughness of welded stainless steels sheets for automotive industry

    Directory of Open Access Journals (Sweden)

    E. Bayraktar

    2011-01-01

    Full Text Available Purpose: In the automotive industry, more and more it is compulsory to develop new grades of stainless steels, such as high resistant Martensitic Stainless Steels (MA-SS and Ferritic Stainless Steels (FSS in order to realise certain or many complex deep drawn pieces. For these grades, resistance spot welding (RSW is the most widespread process used largely for many parts of the car body in the automotive industry. This paper aims to characterise mechanical behaviour (toughness of the different steel grades under dynamic test conditions.Design/methodology/approach: A special crash test device is used in different temperatures and the simulated crash tests are performed at a constant speed of 5.52 m/s.Findings: The specimen is submitted to impact tensile test at different temperatures. According to testing temperature, fracture mode varies: At low temperatures, brittle fracture occurs: due to stress concentration, fracture always occurs in the notched section. At high temperatures, the specimen fails by ductile fracture. Toughness of the steel sheets (base metals, BM or welded parts is well compared at different materials and test conditions.Research limitations/implications: Evaluation of welded thin sheets submitted to the dynamic loading in order to correlate in real service conditions in order to realize a useful correlation between the transition temperature and deep drawability can be used for evaluating of the welding conditions and also of the material characteristics. For detail study, this type of the test needs a standard formulation.Practical implications: This is a new conception of specimen and of the impact/crash machine. It is widely used in automotive industry for practical and economic reason to give rapid answers to designer and also steel makers for ranking the materials.Originality/value: New developed test called impact crash test for evaluating the toughness of thin welded joints (tailored blanks / mechanical assemblies in

  8. Failure of austenitic stainless steel tubes during steam generator operation

    Directory of Open Access Journals (Sweden)

    M. Głowacka

    2012-12-01

    Full Text Available Purpose: of this study is to analyze the causes of premature failure of steam generator coil made of austenitic stainless steel. Special attention is paid to corrosion damage processes within the welded joints.Design/methodology/approach: Examinations were conducted several segments of the coil made of seamless cold-formed pipes Ø 23x2.3 mm, of austenitic stainless steel grade X6CrNiTi18-10 according to EN 10088-1:2007. The working time of the device was 6 months. The reason for the withdrawal of the generator from the operation was leaks in the coil tube caused by corrosion damage. The metallographic investigations were performed with the use of light microscope and scanning electron microscope equipped with the EDX analysis attachment.Findings: Examinations of coil tubes indicated severe corrosion damages as pitting corrosion, stress corrosion cracking, and intergranular corrosion within base material and welded joints. Causes of corrosion was defined as wrong choice of austenitic steel grade, improper welding technology, lack of quality control of water supply and lack of surface treatment of stainless steel pipes.Research limitations/implications: It was not known the quality of water supply of steam generator and this was the reason for some problems in the identification of corrosion processes.Practical implications: Based on the obtained research results and literature studies some recommendations were formulated in order to avoid failures in the application of austenitic steels in the steam generators. These recommendations relate to the selection of materials, processing technology and working environment.Originality/value: Article clearly shows that attempts to increase the life time of evaporator tubes and steam coils by replacing non-alloy or low alloy structural steel by austenitic steel, without regard to restrictions on its use, in practice often fail.

  9. Deformation behavior of open-cell stainless steel foams

    Energy Technology Data Exchange (ETDEWEB)

    Kaya, A.C., E-mail: a.kaya@campus.tu-berlin.de; Fleck, C.

    2014-10-06

    This study presents the deformation and cell collapse behavior of open-cell stainless steel foams. 316L stainless-steel open-cell foams with two porosities (30 and 45 pores per inch, ppi) were produced with the pressureless powder metallurgical method, and tested in quasi-static compression. As a result of the manufacturing technique, 316L stainless steel open-cell foams have a high amount of microporosity. The deformation behavior was investigated on a macroscopic scale by digital image correlation (DIC) evaluation of light micrographs and on the microscopic scale by in situ loading of cells in the scanning electron microscope. The deformation behavior of the metal foams was highly affected by microstructural features, such as closed pores and their distribution throughout the foam specimen. Moreover, the closed pores made a contribution to the plateau stress of the foams through cell face stretching. Strut buckling and bending are the dominant mechanisms in cell collapse. Although there are edge defects on the struts, the struts have an enormous plastic deformation capability. The cell size of the steel foams had no significant effect on the mechanical properties. Due to the inhomogeneities in the microstructure, the measured plateau stresses of the foams showed about 20% scatter at the same relative density.

  10. Field welding of hydraulic turbines made of martensitic stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Akhtar, A.

    1982-06-15

    Field welding of hydraulic turbines made of 13 Cr-Ni martensitic stainless steels was investigated. Two shielded metal arc welding electrodes, one containing 15 Cr-25 Ni and the other with 50% cobalt, were studied with respect to the criteria of weldability, structural integrity and cavitation erosion resistance. The cavitation erosion resistance of the 15 Cr-25 Ni material, evaluated with an ultrasonic vibratory test method, was found to be poor, being comparable to that of mild steel. Although the 50% cobalt alloy possesses excellent cavitation erosion properties, its cost is ca 10 times higher than that of austenitic stainless steels. Under certain welding conditions, the 50% cobalt alloy produces a hard interface with the martensitic stainless steel base material. These interfaces were systematically investigated using microhardness measurement and scanning electron microscopy. The interfaces between the base metal and the weld deposits as well as that between the two weld metals were subjected to measurements of Charpy impact energy, corrosion fatigue tests and an elastoplastic fracture mechanics analysis. It is concluded that the presence of the hard zone is not detrimental to structural integrity. A field welding procedure is proposed on the basis of these findings. The shallow cavitation damaged areas may be repaired with the 50% cobalt containing material. The cheaper 15 Cr-25 Ni material may be used for the filling of deep cavitation damaged areas and for the repair of cracks followed by an overlay of 50% cobalt weld metal. 20 refs., 22 figs., 7 tabs.

  11. High specialty stainless steels and nickel alloys for FGD dampers

    Energy Technology Data Exchange (ETDEWEB)

    Herda, W.R.; Rockel, M.B.; Grossmann, G.K. [Krupp VDM GmbH, Werdohl (Germany); Starke, K. [Mannesmann-Seiffert GmbH, Beckum (Germany)

    1997-08-01

    Because of process design and construction, FGD installations normally have bypass ducts, which necessitates use of dampers. Due to corrosion from acid dew resulting from interaction of hot acidic flue gases and colder outside environments, carbon steel cannot be used as construction material under these specific conditions. In the past, commercial stainless steels have suffered by pitting and crevice corrosion and occasionally failed by stress corrosion cracking. Only high alloy specialty super-austenitic stainless steels with 6.5% Mo should be used and considered for this application. Experience in Germany and Europe has shown that with regard to safety and life cycle cost analysis as well as providing a long time warranty, a new specialty stainless steel, alloy 31--UNS N08031--(31 Ni, 27 Cr, 6.5 Mo, 0.2 N) has proven to be the best and most economical choice. Hundreds of tons in forms of sheet, rod and bar, as well as strip (for damper seals) have been used and installed in many FGD installations throughout Europe. Under extremely corrosive conditions, the new advanced Ni-Cr-Mo alloy 59--UNS N06059--(59 Ni, 23 Cr, 16 Mo) should be used. This paper describes qualification and workability of these alloys as pertains to damper applications. Some case histories are also provided.

  12. Study of irradiation damage structures in austenitic stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Hamada, Shozo [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    1997-08-01

    The irradiation damage microstructures in austenitic stainless steels, which have been proposed to be a candidate of structural materials of a fusion reactor, under ions and neutrons irradiation have been studied. In ion irradiation experiments, cross-sectional observation of the depth distribution of damage formed due to ion irradiation became available. Comparison and discussion between experimental results with TEM and the calculated ones in the depth profiles of irradiation damage microstructures. Further, dual-phase stainless steels, consisted of ferritic/austenitic phases, showed irradiation-induced/enhanced precipitation during ion irradiation. High Flux Isotope Reactor with high neutron fluxes was employed in neutron-irradiation experiments. Swelling of 316 steel showed irradiation temperature dependence and this had strong correlation with phase instability under heavy damage level. Swelling resistance of Ti-modified austenitic stainless steel, which has good swelling resistance, decreased during high damage level. This might be caused by the instability of Ti-carbide particles. The preparation method to reduce higher radioactivity of neutron-irradiated TEM specimen was developed. (author). 176 refs.

  13. Residual stresses and fatigue in a duplex stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Johansson, Johan

    1999-05-01

    Duplex stainless steels, consisting of approximately equal amounts of austenite and ferrite, often combine the best features of austenitic and ferritic stainless steels. They generally have good mechanical properties, including high strength and ductility, and the corrosion resistance is often better than conventional austenitic grades. This has lead to a growing use of duplex stainless steels as a material in mechanically loaded constructions. However, detailed knowledge regarding its mechanical properties and deformation mechanisms are still lacking. In this thesis special emphasis has been placed on the residual stresses and their influence on mechanical behaviour of duplex stainless steels. Due to the difference in coefficient of thermal expansion between the two phases, tensile microstresses are found in the austenitic phase and balancing compressive microstresses in the ferritic phase. The first part of this thesis is a literature survey, which will give an introduction to duplex stainless steels and review the fatigue properties of duplex stainless steels and the influence of residual stresses in two-phase material. The second part concerns the evolution of the residual stress state during uniaxial loading. Initial residual stresses were found to be almost two times higher in the transverse direction compared to the rolling direction. During loading the absolute value of the microstresses increased in the macroscopic elastic regime but started to decrease with increasing load in the macroscopic plastic regime. A significant increase of the microstresses was also found to occur during unloading. Finite element simulations also show stress variation within one phase and a strong influence of both the elastic and plastic anisotropy of the individual phases on the simulated stress state. In the third part, the load sharing between the phases during cyclic loading is studied. X-ray diffraction stress analysis and transmission electron microscopy show that even if

  14. Residual stresses and fatigue in a duplex stainless steel

    International Nuclear Information System (INIS)

    Duplex stainless steels, consisting of approximately equal amounts of austenite and ferrite, often combine the best features of austenitic and ferritic stainless steels. They generally have good mechanical properties, including high strength and ductility, and the corrosion resistance is often better than conventional austenitic grades. This has lead to a growing use of duplex stainless steels as a material in mechanically loaded constructions. However, detailed knowledge regarding its mechanical properties and deformation mechanisms are still lacking. In this thesis special emphasis has been placed on the residual stresses and their influence on mechanical behaviour of duplex stainless steels. Due to the difference in coefficient of thermal expansion between the two phases, tensile microstresses are found in the austenitic phase and balancing compressive microstresses in the ferritic phase. The first part of this thesis is a literature survey, which will give an introduction to duplex stainless steels and review the fatigue properties of duplex stainless steels and the influence of residual stresses in two-phase material. The second part concerns the evolution of the residual stress state during uniaxial loading. Initial residual stresses were found to be almost two times higher in the transverse direction compared to the rolling direction. During loading the absolute value of the microstresses increased in the macroscopic elastic regime but started to decrease with increasing load in the macroscopic plastic regime. A significant increase of the microstresses was also found to occur during unloading. Finite element simulations also show stress variation within one phase and a strong influence of both the elastic and plastic anisotropy of the individual phases on the simulated stress state. In the third part, the load sharing between the phases during cyclic loading is studied. X-ray diffraction stress analysis and transmission electron microscopy show that even if

  15. High density sintered stainless steels with improved properties

    Directory of Open Access Journals (Sweden)

    M. Actis Grande

    2007-04-01

    Full Text Available Purpose: of this paper is the study of the properties of sintered AISI 316L (1.4404 according to EN 10088. Sintered stainless steels occupy a prominent position in the high alloyed steels, however their properties are limited by the presence of porosity. The improvement of quality and performances of products coupled with a reduction of manufacturing costs calls for high compacting pressures, as well as high sintering temperatures. However, the possibility to fill the open porosity of sintered parts by infiltration process with a metal alloy or by the use of reactive sintering techniques can favour the production of stainless steel parts with enhanced mechanical properties and good corrosion resistance. Design/methodology/approach: Sintered AISI 316L (1.4404 according to EN 10088 stainless steel samples have been manufactured using different combinations of compacting pressure and sintering parameters (time, temperature, atmosphere, or a modified composition able to allow reactive sintering process, as well as the contact infiltration with bronze.Findings: The studies have been forwarded towards the statical and dynamic mechanical properties, as well as the corrosion behavior. Lowering the porosity level and increasing the sintering degree, by use of higher compacting pressure or sintering temperature, is of great effectiveness, especially from the point of view of mechanical properties and fatigue endurance.Practical implications: the obtained results demonstrate the benefits of contact infiltration and of reactive sintering techniques to sinter stainless steels components having higher density and better mechanical and corrosion resistance properties than the traditional compositions, compacted at high pressure and sintered at elevated temperature.Originality/value: very promising results have been also obtained with a modified composition able to allow reactive sintering process.

  16. Effect of implantation defects on the corrosion of austenitic stainless steels in pressurized water reactor primary medium

    International Nuclear Information System (INIS)

    Internal parts of pressurized water reactor (PWR) vessels are often made of austenitic stainless steels (304L and 316L). These structural materials are exposed to an oxidizing medium under irradiation and mechanical stresses. Under these conditions, they can suffer damages by IASCC (Irradiation-Assisted Stress Corrosion Cracking). The first step in this cracking phenomenon is the initiation, which implies the breakdown of the passive layer. The nature and the structure of the oxide film formed on these steels are key factors in initiation of IASCC cracks. In this context, the objective of this work is first to better understand the oxidation mechanisms of stainless steels in primary medium and second to study the effects of irradiation induced defects on the oxide film formed on stainless steels in primary medium. Xenon ions and protons, were implanted in 316L-type austenitic stainless steel samples, respectively at an energy of 240 and 230 keV in order to simulate the irradiation defects. Implanted and non-implanted samples were exposed in a corrosion loop at 325 C to an aqueous medium containing 1000 ppm of boron, 2 ppm of lithium and 1,19.10-3 mol.L-1 of dissolved hydrogen. The samples were analyzed by TEM before and after exposure to primary medium in order to characterize both the defects generated by the implantation and the nature, structure, and morphology of the formed oxide. Comparing implanted and non-implanted samples has shown that the nature and the density of defects in the alloy subsurface played an important role on the composition (mainly on the content of Cr and Mo) and on the thickness of the inner layer. The study of the oxidation kinetics by coupling two ion beam analysis techniques (NRA and RBS) has revealed different behavior between the two types of samples: non-implanted and implanted. Tracer experiments (using D and 18O) were conducted to study the growth mechanism of the inner oxide layer and the associated transport mechanisms. The

  17. Microstructure and antibacterial property of stainless steel implanted by Cu ions

    Institute of Scientific and Technical Information of China (English)

    XU Bo-fan; NI Hong-wei; XIONG Ping-yuan; XIONG Juan; DAN Zhi-gang

    2004-01-01

    Copper ions were implanted into AISI 304 austenitic stainless steel by metal vapor vacuum are (MEVVA) with 60 - 100 keV energy and a dose range (0.2 - 5.0) × 1017 cm-2. Then Cu-implanted stainless steel was treated by a special antibacterial treatment. Antibacterial rates of Cu-implanted stainless steel, Cu-implanted stainless steel with special antibacterial treatment and un-implanted stainless steel were obtained by agar plate method. Phase composition in the implanted layer was analyzed by glancing X-ray diffraction (GXRD). Microstructure of antibacterial stainless steel was observed with transmission electron microscopy (TEM), and changes of the bacterium appearance after 24 h antibacterial action on the surface of un-implanted and Cu-implanted stainless steel with antibacterial treatment were observed with bio-TEM respectively. The results show that stainless steel obtains antibacterial property against E. coli when the Cu ions dose approaches to the saturated one. A suitable amount of Cu-rich phase uniformly disperses on the surface of Cu-implanted stainless steel that is treated by the special antibacterial treatment. The Cu-rich phase naked on the surface has a function of damage to pericellular membrane and cell wall,the pericellular membrane is thickened and the karyon degraded, and finally, bacteria die. Cu-rich phase naked on the surface endows stainless steel with best antibacterial property.

  18. Stress corrosion cracking susceptibility of dissimilar stainless steels welded joints

    Directory of Open Access Journals (Sweden)

    J. Łabanowski

    2007-01-01

    Full Text Available Purpose: The aim of the current study is to reveal the influence of welding conditions on structure and stresscorrosion cracking resistance of dissimilar stainless steels butt welded joints.Design/methodology/approach: Butt joints between duplex 2205 and austenitic 316L steels were performedwith the use of submerged arc welding (SAW method. The plates 15 mm in thickness were welded with heatinput in the range of 1.15 – 3.2 kJ/mm using duplex steel filler metal. Microstructure examinations and corrosiontests were carried out. Slow strain rate tests (SSRT were performed in inert (glycerin and aggressive (boiling35% MgCl2 solution environments.Findings: It was shown that place of the lowest resistance to stress corrosion cracking is heat affected zone atduplex steel side of dissimilar joins. That phenomenon was connected with undesirable structure of that zoneconsisted of great amount of coarse ferrite grains and acicular austenite precipitates. High welding inputs do notdeteriorate stress corrosion cracking resistance of welds.Research limitations/implications: High welding heat inputs should enhance the precipitation process ofintermetallic phases in the HAZ. It is necessary to continue the research to determine the relationship betweenwelding parameters, obtained structures, and corrosion resistance of dissimilar stainless steels welded joints.Practical implications: Application of more productive joining process for dissimilar welds like submerged arcwelding instead of currently employed gas metal arc welding (GMAW method will be profitable in terms ofreduction the welding costs.Originality/value: The stress corrosion cracking resistance of dissimilar stainless steel welded joints wasdetermined. The zone of the weaker resistance to stress corrosion cracking was pointed out.

  19. Super austenitic stainless steels - a promising replacement for the currently used type 316L stainless steel as the construction material for flue-gas desulphurization plant

    Energy Technology Data Exchange (ETDEWEB)

    Rajendran, N.; Rajeswari, S. [University of Madras, Madras (India). Dept. of Analytical Chemistry

    1996-12-15

    Potentiodynamic anodic cyclic polarization experiments on type 316L stainless steel and 6Mo super austenitic stainless steels were carried out in simulated flue-gas desulphurization (FGD) environment in order to assess the localized corrosion resistance. The pitting corrosion resistance was higher in the case of the super austenitic stainless steel containing 6Mo and a higher amount of nitrogen. The accelerated leaching study conducted for the alloys showed that the super austenitic stainless steels have a little tendency for leaching of metal ions such as iron, chromium and nickel at different impressed potentials. This may be due to surface segregation of nitrogen as CrN, which would, in turn, enrich a chromium and molybdenum mixed oxide film and thus impede the release of metal ions. The present study indicates that the 6Mo super austenitics can be adopted as a promising replacement for the currently used type 316L stainless steel as the construction material for FGD plants.

  20. Mechanical and physical properties of irradiated type 348 stainless steel

    International Nuclear Information System (INIS)

    A type 348 stainless steel in-pile tube irradiated to a fluence of 3 x 1022 n/cm2, E > 1 MeV (57 dpa), was destructively examined. The service had resulted in a maximum total creep of 1.8% at the high fluence. The metal temperature ranged between 623 and 6520K, hence the thermal creep portion of the total was negligible. Total creep was greater than had been anticipated from creep data for austenitic stainless steels irradiated in other reactors. The objectives of the destructive examination were to determine the service-induced changes of mechanical and physical properties, and to assess the possibility of adverse effects of both these changes and the greater total creep on the prospective service life of other tubes

  1. Interaction between Lubricants Containing Phosphate Ester Additives and Stainless Steels

    Directory of Open Access Journals (Sweden)

    David W. Johnson

    2013-05-01

    Full Text Available One way to improve fuel efficiency in today’s jet aircraft engines is to create an environment for higher operating temperatures and speeds. New and improved lubricants and bearing materials must be developed to remain stable in these elevated operating temperatures. Three lubricants, with varying amounts of tricresyl phosphate added as an anti-wear/extreme pressure additive were tested on two different stainless steels at varying temperatures ranging from 300 °C to 350 °C in vacuum. Significant decomposition of the lubricant base-stocks and the phosphate ester additive did occur in most of the trials resulting in the formation of carboxylic acids and phenols. In these cases a film containing phosphorus was deposited onto the stainless steel substrate.

  2. Investigation of Laser Peening Effects on Hydrogen Charged Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Zaleski, Tania M. [San Jose State Univ., CA (United States)

    2008-10-30

    Hydrogen-rich environments such as fuel cell reactors can exhibit damage caused by hydrogen permeation in the form of corrosion cracking by lowering tensile strength and decreasing material ductility. Coatings and liners have been investigated, but there were few shot-peening or laser peening studies referenced in the literature with respect to preventing hydrogen embrittlement. The surface compressive residual stress induced by laser peening had shown success in preventing stress corrosion cracking (SCC) for stainless steels in power plants. The question arose if the residual stresses induced by laser peening could delay the effects of hydrogen in a material. This study investigated the effect of laser peening on hydrogen penetration into metal alloys. Three areas were studied: laser peening, hydrogenation, and hydrogen detection. This study demonstrated that laser peening does not reduce the hydrogen permeation into a stainless steel surface nor does it prevent hydrogen embrittlement. The effect of laser peening to reduce hydrogen-assisted fatigue was unclear.

  3. COLD ROLLING ORTHODONTIC WIRES OF AUSTENITIC STAINLESS STEEL AISI 304

    Directory of Open Access Journals (Sweden)

    Rodrigo Santos Messner

    2013-03-01

    Full Text Available Austenitic stainless steels wires are widely used in the final stages of orthodontic treatment. The objective of this paper is to study the process of conformation of rectangular wires from round wires commercial austenitic stainless steel AISI 304 by the process of cold rolling. The wire quality is evaluated by means of dimensional analysis, microhardness measurements, tensile strength and fractographic analysis of the wires subjected to tensile tests. Also a study on the application of finite element method to simulate the process, comparing the force and rolling stress obtained in the rolling is done. The simulation results are consistent with those obtained in the actual process and the rolled wires show ductile fracture, tensile strength and dimensional variations appropriate to orthodontic standards. The fracture morphology shows the model cup-cone type besides the high deformation and hardness inherent in the cold rolling process.

  4. Long-Term Underground Corrosion of Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    M. K. Adler Flitton; T. S. Yoder

    2007-03-01

    In 1970, the National Institute of Standards and Technology (NIST) implemented the most ambitious and comprehensive long-term corrosion behavior test to date for stainless steels in soil environments. Over thirty years later, one of the six test sites was targeted to research subsurface contamination and transport processes in the vadose and saturated zones. This research directly applies to environmental management operational corrosion issues and long term stewardship scientific needs for understanding the behavior of waste forms and their near-field contaminant transport of chemical and radiological contaminants at nuclear disposal sites. This paper briefly describes the ongoing research and the corrosion analysis results of the stainless steel plate specimens recovered from the partial recovery of the first test site.

  5. Multilayer modelling of stainless steel with a nanocrystallised superficial layer

    Energy Technology Data Exchange (ETDEWEB)

    Petit, J. [Laboratoire Energetique Mecanique Electromagnetisme (LEME), EA4416, Universite Paris Ouest, 92410 Ville d' Avray (France); Waltz, L., E-mail: laurent.waltz@univ-montp2.fr [Laboratoire de Mecanique et Genie Civil de Montpellier (LMGC), University of Montpellier II, Place Eugene Bataillon, 34000 Montpellier (France); Montay, G.; Retraint, D.; Roos, A.; Francois, M. [Institut Charles Delaunay - LASMIS, UMR CNRS 6279, University of Technology of Troyes, 10010 Troyes (France)

    2012-02-28

    Highlights: Black-Right-Pointing-Pointer SMAT has been used for nanocrystallisation of an austenitic stainless steel. Black-Right-Pointing-Pointer The mechanical response of the nano-phase has been obtained by an indirect method. Black-Right-Pointing-Pointer Minimisation of a stress formulated objective function. Black-Right-Pointing-Pointer The model predicts the strain at which diffuse necking occurs. - Abstract: In order to obtain the macroscopic mechanical response of a 316L stainless steel, nanocrystallised by Surface Mechanical Attrition Treatment (SMAT), a multilayer model is proposed. The constitutive behaviour of each layer is determined from tensile tests or by an inverse method and its thickness is evaluated from Scanning and Transmission Electron Microscopy (SEM and TEM) analyses and local hardness measurements. The consistency of the model is verified by its ability to predict the strain at which diffuse necking occurs.

  6. PITTING CORROSION OF STAINLESS STEEL AT THE VARIOUS SURFACE TREATMENT

    Directory of Open Access Journals (Sweden)

    Viera Zatkalíková

    2011-09-01

    Full Text Available The stainless steel surface treatment is very important with regard to its pitting corrosion susceptibility. An effect of various types surfacing on pitting corrosion resistance of AISI 304stainless steel is investigated in this work. The samples of the tested material are turned, blasted, peened, grinded and a half of them are pickled to achieve higher purity of surfaces and better quality of passive film. Eight types of different finished surfaces are tested by electrochemical and immersion tests to determine corrosion behaviour in conditions where pitting is evoked by controlled potential and second by solution with high redox potential. By this way the effect of mechanical and chemical surface treatment on the resistance to pitting corrosion, character, size and shape of pits are compared in the conditions of different mechanisms of corrosion process.

  7. New hermetic sealing material for vacuum brazing of stainless steels

    Science.gov (United States)

    Hildebrandt, S.; Wiehl, G.; Silze, F.

    2016-03-01

    For vacuum brazing applications such as in vacuum interrupter industry Hermetic Sealing Materials (HSM) with low partial pressure are widely used. AgCu28 dominates the hermetic sealing market, as it has a very good wetting behavior on copper and metallized ceramics. Within recent decades wetting on stainless steel has become more and more important. However, today the silver content of HSMs is more in focus than in the past decades, because it has the biggest impact on the material prices. Umicore Technical Materials has developed a new copper based HSM, CuAg40Ga10. The wettability on stainless steel is significantly improved compared to AgCu28 and the total silver content is reduced by almost 44%. In this article the physical properties of the alloy and its brazed joints will be presented compared to AgCu28.

  8. Mechanical properties and corrosion resistance of dissimilar stainless steel welds

    OpenAIRE

    J. Łabanowski

    2007-01-01

    Purpose: The purpose of this paper is to determine the influence of welding on microstructure, mechanical properties, and stress corrosion cracking resistance of dissimilar stainless steels butt welded joints.Design/methodology/approach: Duplex 2205 and austenitic 316L steels were used. Butt joints of plates 15 mm in thickness were performed with the use of submerged arc welding (SAW) method. The heat input was in the range of 1.15 – 3.2 kJ/mm. Various plates’ edge preparation...

  9. Corrosion Behavior of Austenitic and Duplex Stainless Steels in Lithium Bromide

    Directory of Open Access Journals (Sweden)

    Ayo Samuel AFOLABI

    2009-07-01

    Full Text Available The corrosion behavior of austenitic and duplex stainless steels in various concentrations of lithium, bromide solution was investigated by using the conventional weight loss measurement method. The results obtained show that corrosion of these steels occurred due to the aggressive bromide ion in the medium. Duplex stainless steel shows a greater resistance to corrosion than austenitic stainless steel in the medium. This was attributed to equal volume proportion of ferrite and austenite in the structure of duplex stainless steel coupled with higher content of chromium in its composition. Both steels produced electrochemical noise at increased concentrations of lithium bromide due to continuous film breakdown and repair caused by reduction in medium concentration by the alkaline corrosion product while surface passivity observed in duplex stainless steel is attributed to film stability on this steel.

  10. Modeling of the integrity of machining surfaces: application to the case of 15-5 PH stainless steel finish turning

    International Nuclear Information System (INIS)

    During machining, extreme conditions of pressure, temperature and strain appear in the cutting zone. In this thermo-mechanical context, the link between the cutting conditions (cutting speed, lubrication, feed rate, wear, tool coating...) and the machining surface integrity represents a major scientific target. This PhD study is a part of a global project called MIFSU (Modeling of the Integrity and Fatigue resistance of Machining Surfaces) and it focuses on the finish turning of the 15-5PH (a martensitic stainless steel used for parts of helicopter rotor). Firstly, material behavior has been studied in order to provide data for machining simulations. Stress-free dilatometry tests were conducted to obtain the austenitization kinetics of 15-5PH steel for high heating rates (up to 11,000 degrees C/s). Then, parameters of Leblond metallurgical model have been calibrated. In addition, dynamic compression tests (de/dt ranging from 0.01 to 80/s and e ≥ 1) have been performed to calibrate a strain-rate dependent elasto-plasticity model (for high strains). These tests also helped to highlight the dynamic recrystallization phenomena and their influence on the flow stress of the material. Thus, recrystallization model has also been implemented.In parallel, a numerical model for the prediction of machined surface integrity has been constructed. This model is based on a methodology called 'hybrid' (developed during the PhD thesis of Frederic Valiorgue for the AISI 304L steel). The method consists in replacing tool and chip modeling by equivalent loadings (obtained experimentally). A calibration step of these loadings has been carried out using orthogonal cutting and friction tests (with sensitivity studies of machining forces, friction and heat partition coefficients to cutting parameters variations).Finally, numerical simulations predictions of microstructural changes (austenitization and dynamic recrystallization) and residual stresses have been successfully compared with

  11. Surface nanocrystallization of stainless steel for reduced biofilm adherence.

    Science.gov (United States)

    Yu, Bin; Davis, Elisabeth M; Hodges, Robert S; Irvin, Randall T; Li, D Y

    2008-08-20

    Stainless steel is one of the most common metallic biomedical materials. For medical applications, its resistance to the adherence of biofilms is of importance to the elimination or minimization of bacterial infections. In this study, we demonstrate the effectiveness of a process combining surface nanocrystallization and thermal oxidation (or a recovery heat treatment in air) for reducing the biofilm's adherence to stainless steel. During this treatment, a target surface was sandblasted and the resultant dislocation cells in the surface layer were turned into nanosized grains by a subsequent recovery treatment in air. This process generated a more protective oxide film that blocked the electron exchange or reduced the surface activity more effectively. As a result, the biofilm's adherence to the treated surface was markedly minimized. A synthetic peptide was utilized as a substitute of biofilms to evaluate the adhesion between a treated steel surface and biofilms using an atomic force microscope (AFM) through measuring the adhesive force between the target surface and a peptide-coated AFM tip. It was shown that the adhesive force decreased with a decrease in the grain size of the steel. The corresponding surface electron work function (EWF) of the steel was also measured, which showed a trend of variation in EWF with the grain size, consistent with corresponding changes in the adhesive force. PMID:21730615

  12. Ionic nitriding of high chromium martensitic stainless steels

    International Nuclear Information System (INIS)

    Martensitic stainless steels are used in industrial applications where resistance to corrosion and mechanical resistance are needed simultaneously. These steels are normally used in tempering and annealing condition which gives them hardnesses of 500 and 600 HV (about 54 HRC). Ionic nitriding is an assisted diffusion technique that has recently been successfully applied to harden austenitic stainless steels without reducing their resistance to corrosion. The application with AISI 420 martensitic steels has not given good results yet, because in most cases, it affects their corrosion resistance. This work presents the results of the pulsed nitriding of martensitic steels with a higher chrome content, such as the M340 and M333 Boehler steels and they are compared with the same materials after tempering and annealing, without nitriding. The influence of the variations in the parameters of the process, such as the percentage of active time in the pulsed wave, partial nitrogen pressure, current density and effective tension in the microstructure, hardness and wear and corrosion resistance was studied. The microstructure was studied with an optic microscope; the wear resistance with abrasion tests following ASTM G-65 and corrosion with 100 hour long saline haze tests, in a device built according to ASTM B117. Hardness was found to rise to values of 1000 to 1350 HV in all the steels after ionic nitriding, the modified layers oscillated from 3 to 15 microns. As a result, wear resistance also increased, with differences depending on the microstructure and the thickness of the modified layer. However, corrosion resistance was not good, except in the case of the M333 steel test piece with less hardness and a less thick nitrided layer without a noticeable interphase (au)

  13. Highly alloyed stainless steels for sea water applications

    Energy Technology Data Exchange (ETDEWEB)

    Audouard, J.P.; Verneau, M. [Creusot-Loire Industrie, Le Creusot (France). Research Centre for Materials

    1996-10-01

    Natural sea water is known as a very aggressive environment which generates pitting and crevice corrosion on stainless steels. High chromium grades with sufficient molybdenum and nitrogen additions (PREN > 40) are generally recognized as resistant materials in natural sea water bu the material selection criteria must be improved to take into account the effect of climatic conditions and of biocide treatments which are widely used as anti-fouling agents in sea water circuits. The paper deals with the localized corrosion properties of conventional stainless steels (SS), duplex and superaustenitic alloys. The results of laboratory investigations conducted in more or less oxidizing chloride containing media are discussed. Then, immersion tests carried out in natural sea waters in different climatic conditions are presented and discussed. Finally, the effect of biocide addition on fouling and its consequences on corrosion is investigated. The results are interpreted taking into account the chemical composition of the stainless steels and biofilm criteria. The results showed the Mediterranean Sea to be slightly more aggressive than other European seas but a PREN value higher than 40 is sufficient for stainless steels to withstand localized corrosion in European natural sea waters. A residual chlorine level around 0.3--0.4 ppm was found to be very effective to limit the fouling and to avoid localized corrosion on SS. Nevertheless, due to difficulties in monitoring chlorine addition, PREN values higher than 50 are recommended to withstand localized corrosion in treated sea waters. As an example, the new super-austenitic grade 25Cr-22Ni-5.8Mo-1.5Cu-2W-0.45N with a PRENW value of 54 was found to be perfectly resistant to crevice corrosion with 0.5 ppm free chlorine at ambient temperature.

  14. Adhesive bonding of stainless steel : strength and durability

    OpenAIRE

    Boyes, Robert

    1998-01-01

    Adhesive bonding as an alternative method of joining materials together has many advantages over the more conventional joining methods such as fusion and spot welding, bolting and riveting. For example, adhesives can be used to bond dissimilar materials, adhesive joints have a high stiffness to weight ratio and the stress distribution within the joint is much improved. Stainless steels are commonly used in applications that would clearly benefit from adhesive bonding; architectural cladding, ...

  15. Modeling and optimization of turning duplex stainless steels

    OpenAIRE

    Ali, Rastee Dalshad

    2015-01-01

    In the present dissertation, machining investigations into duplex stainless steels are performed under different and systematically well-structured modeling and optimization frameworks. Focusing on the main objective of finding optimum machining process parameters and com-prehensively applying the statistical design of experiments to design the experiments, the study tackles the challenge of integrating modeling and optimization algorithms using six different approaches. Firstly, sets of non-...

  16. Manifestations of DSA in austenitic stainless steels and inconel alloys

    International Nuclear Information System (INIS)

    The aim of the investigation was to examine and compare different types of DSA (Dynamic Strain Aging) manifestations in AISI 316 austenitic stainless steel (SS) and Inconel 600 and Inconel 690 alloys by means of slow strain rate tensile testing, mechanical loss spectrometry (internal friction) and transmission electron microscopy (TEM). Another aim was to determine differences in the resulting dislocation structures and internal friction response of materials showing and not showing DSA behaviour

  17. Stainless steel: Recovery of properties after exposure to detrimental phases

    OpenAIRE

    Skaare, Andreas

    2015-01-01

    High alloyed stainless steel provides a desirable combination of corrosion resistance and mechanical properties, being a preferred material when ductility, overall strength and resistance to harsh environments are required. High service temperatures where alloy elements, as chromium and molybdenum, are present, is a well-known recipe for the precipitation of detrimental phases in the material. Even a small amount of these precipitations may impair the mechanical and corrosion properties. T...

  18. Hyperbaric welding of duplex stainless steel pipelines offshore.

    OpenAIRE

    Farrell, J.

    1996-01-01

    Three duplex stainless steels (Avesta 2205, Sandvik SAF2507 and Zeron 100) were successfully welded automatically at a range of pressures from 1 to 32bar. The gas tungsten arc (GTA) welding process was chosen as it allows a high degree of control to be exercised during welding. Initial autogenous bead on plate welds established the effects of pressure on the welding process and allowed the process parameters to be determined for subsequent experiments. Analysis of the eff...

  19. Intragranular Chromium Nitride Precipitates in Duplex and Superduplex Stainless Steel

    OpenAIRE

    Iversen, Torunn Hjulstad

    2012-01-01

    Intragranular chromium nitrides is a phenomenon with detrimental effects on material properties in superduplex stainless steels which have not received much attention. Precipitation of nitrides occurs when the ferritic phase becomes supersaturated with nitrogen and there is insufficient time during cooling for diffusion of nitrogen into austenite. Heat treatment was carried out at between 1060◦C and 1160◦C to study the materials susceptibility to nitride precipitation with...

  20. Microstructural Characterization of Low Temperature Gas Nitrided Martensitic Stainless Steel

    DEFF Research Database (Denmark)

    Fernandes, Frederico Augusto Pires; Christiansen, Thomas Lundin; Somers, Marcel A. J.

    2015-01-01

    The present work presents microstructural investigations of the surface zone of low temperature gas nitrided precipitation hardening martensitic stainless steel AISI 630. Grazing incidence X-ray diffraction was applied to investigate the present phases after successive removal of very thin sections...... of the sample surface. The development of epsilon nitride, expanded austenite and expanded martensite resulted from the low temperature nitriding treatments. The microstructural features, hardness and phase composition are discussed with emphasis on the influence of nitriding duration and nitriding potential....

  1. Chromium reduction from slag on electromelting of stainless steel

    International Nuclear Information System (INIS)

    Specific features of chromium reduction from the slag on electromelting of stainless steel type Kh18N10T according to one- or two-slag procedure were studied. It was shown that one-slag melting technology allows double decrease of chromium losses in the form of incompletely reduced oxides. This occurs due to additional chemical reactions between metal and slag on their combined pouring into the ladle. 1 ref.; 3 figs

  2. Increase of chromium utilization in stainless steel melting

    International Nuclear Information System (INIS)

    The processes of deoxidizing when melting stainless 18-10 steels in electric are furnaces by the method of remelting with wastes are investigated. The dependences of amount of reduced chromium on silicon consumption are made more precise. It is shown that it is useful to apply aluminium for deoxidation of acid high-chromium slags. Based on the data on pilot melts the extent to which aluminium can be used as a reducing agent for chromium is estimated. 3 refs., 2 figs

  3. Stabilization of final titanium concentration in stainless steel

    International Nuclear Information System (INIS)

    The technology of combined alloying of stainless steel type 08-12Kh18N10T with 30%-ferrotitanium and metallic spongy titanium is developed and put into practice. This permits to stabilize titanium assimilation at the level of 40-60 % in two-slag melting process and to increase chromium recovering from the slag. Stabilization of titanium assimilation promotes its homogeneous distribution in final metal after electroslag remelting. 2 refs. 3 figs

  4. 75 FR 67689 - Stainless Steel Bar From Brazil: Preliminary Results of Antidumping Duty Administrative Review

    Science.gov (United States)

    2010-11-03

    ... Brazil. See Antidumping Duty Orders: Stainless Steel Bar from Brazil, India and Japan, 60 FR 9661... Steel Bar From Brazil: Preliminary Results of Antidumping Duty Administrative Review, 74 FR 10022 (March... market. \\2\\ These results were unchanged in the final results of review (Stainless Steel Bar From...

  5. 46 CFR 148.04-13 - Ferrous metal borings, shavings, turnings, or cuttings (excluding stainless steel).

    Science.gov (United States)

    2010-10-01

    ... (excluding stainless steel). 148.04-13 Section 148.04-13 Shipping COAST GUARD, DEPARTMENT OF HOMELAND... stainless steel). (a) This section applies to the stowage and transportation in bulk of hazardous materials... steel). However, unmanned barges on which the article is stowed for or transported on a voyage...

  6. Corrosion resistance properties of sintered duplex stainless steel

    Directory of Open Access Journals (Sweden)

    L.A. Dobrzański

    2006-09-01

    Full Text Available Purpose: of this paper was to examine the corrosion resistance of duplex stainless steels using electrochemical methods in 1M NaCl solution. The influence of powder mixes preparation and cooling cycle after sintering on corrosion properties was evaluated.Design/methodology/approach: In presented study duplex stainless steels were obtained through powder metallurgy starting from austenitic, martensitic base powders by controlled addition of alloying elements, such as Cr, Ni, Mo and Cu. In the studies behind the preparation of mixes, Schaeffler’s diagram was taken into consideration. Prepared mixes have been compacted at 800 MPa and sintered in a vacuum furnace with argon backfilling at 1260°C for 1 h. After sintering two different cooling cycles were applied: rapid cooling with an average cooling rate of 245 °C/min and slow cooling of 5 °C/min in argon atmosphere. Produced duplex stainless steels have been studied by scanning and optical microscopy and EDS chemical analysis of microstructure components. Corrosion properties have been studied through electrochemical methods in 1M NaCl water solutionFindings: According to achieved results, it was affirmed that applied sintering method as well as powder mixes preparation allows for manufacturing the sintered duplex steels with good corrosion properties which depends on austenite/ferrite ratio in the microstructure and elements partitioning between phases. Corrosion resistance of sintered stainless steels is strictly connected with the density and the pore morphology present in the microstructure too. The highest resistance to pitting corrosion in 1M NaCl solution was achieved for composition with approximate balance of ferrite and austenite in the microstructure.Research limitations/implications: According to the powders characteristic, the applied fast cooling rate seems to be a good compromise for corrosion properties and microstructures, nevertheless further tests should be carried out in

  7. Material Characterization of Fatigue Specimens made from Meta-stable Austenitic Stainless Steel

    Energy Technology Data Exchange (ETDEWEB)

    Niffenegger, M.; Grosse, M.; Kalkhof, D.; Leber, H. [Paul Scherrer Institut Villigen (Switzerland); Vincent, A.; Pasco, L.; Morin, M. [Insa de Lyon (France)

    2003-07-01

    The main objective of the EU-project CRETE (Contract No.: FIS5-1999-00280) was to assess the capability and the reliability of innovative NDT-inspection techniques for the detection of material degradation, induced by thermal fatigue and neutron irradiation, of metastable austenitic and ferritic low-alloy steel. Several project partners tested aged or irradiated samples, using various techniques (acoustic, magnetic and thermoelectric). However, these indirect methods require a careful interpretation of the measured signal in terms of micro-structural evolutions due to ageing of the material. Therefore the material had to be characterized in its undamaged, as well as in its damaged state. The present report summarises only the material characterization of the fatigue specimens. It is issued simultaneously as an PSI Bericht and the CRETE work package 3 (WP3) report. Each partner according to their own specifications purchased three materials under investigation, namely AISI 347, AISI 321 and AISI 304L. After sending the material to PSI, all fatigue specimens were manufactured by the same Swiss company. Each partner was responsible for his fatigue tests which are documented in the report WP1, written by FANP. In order to characterize the material in its unfatigued as well as in its fatigued state and to consider microstructural changes related to fatigue damage the methods listed below were employed either by PSI or by INSA de Lyon: (1) Inductive Coupled Plasma Emission Photometry (ICP-OES) was applied to determine the chemical composition, (2) Scanning electron microscopy (SEM) for observing cracks, slip bands between grain and twin boundaries, - Ferromaster for measuring the magnetic permeability, (3) Physical Properties Measuring System (PPMS) for measuring magnetization characteristics, (4) Neutron- and advanced X-ray diffraction methods for the quantitative determination of martensite, - Transmission electron microscopy (TEM) for the observation of crystalline

  8. Material Characterization of Fatigue Specimens made from Meta-stable Austenitic Stainless Steel

    International Nuclear Information System (INIS)

    The main objective of the EU-project CRETE (Contract No.: FIS5-1999-00280) was to assess the capability and the reliability of innovative NDT-inspection techniques for the detection of material degradation, induced by thermal fatigue and neutron irradiation, of metastable austenitic and ferritic low-alloy steel. Several project partners tested aged or irradiated samples, using various techniques (acoustic, magnetic and thermoelectric). However, these indirect methods require a careful interpretation of the measured signal in terms of micro-structural evolutions due to ageing of the material. Therefore the material had to be characterized in its undamaged, as well as in its damaged state. The present report summarises only the material characterization of the fatigue specimens. It is issued simultaneously as an PSI Bericht and the CRETE work package 3 (WP3) report. Each partner according to their own specifications purchased three materials under investigation, namely AISI 347, AISI 321 and AISI 304L. After sending the material to PSI, all fatigue specimens were manufactured by the same Swiss company. Each partner was responsible for his fatigue tests which are documented in the report WP1, written by FANP. In order to characterize the material in its unfatigued as well as in its fatigued state and to consider microstructural changes related to fatigue damage the methods listed below were employed either by PSI or by INSA de Lyon: (1) Inductive Coupled Plasma Emission Photometry (ICP-OES) was applied to determine the chemical composition, (2) Scanning electron microscopy (SEM) for observing cracks, slip bands between grain and twin boundaries, - Ferromaster for measuring the magnetic permeability, (3) Physical Properties Measuring System (PPMS) for measuring magnetization characteristics, (4) Neutron- and advanced X-ray diffraction methods for the quantitative determination of martensite, - Transmission electron microscopy (TEM) for the observation of crystalline

  9. Mechanical Properties of Austenitic Stainless Steel Made by Additive Manufacturing.

    Science.gov (United States)

    Luecke, William E; Slotwinski, John A

    2014-01-01

    Using uniaxial tensile and hardness testing, we evaluated the variability and anisotropy of the mechanical properties of an austenitic stainless steel, UNS S17400, manufactured by an additive process, selective laser melting. Like wrought materials, the mechanical properties depend on the orientation introduced by the processing. The recommended stress-relief heat treatment increases the tensile strength, reduces the yield strength, and decreases the extent of the discontinuous yielding. The mechanical properties, assessed by hardness, are very uniform across the build plate, but the stress-relief heat treatment introduced a small non-uniformity that had no correlation to position on the build plate. Analysis of the mechanical property behavior resulted in four conclusions. (1) The within-build and build-to-build tensile properties of the UNS S17400 stainless steel are less repeatable than mature engineering structural alloys, but similar to other structural alloys made by additive manufacturing. (2) The anisotropy of the mechanical properties of the UNS S17400 material of this study is larger than that of mature structural alloys, but is similar to other structural alloys made by additive manufacturing. (3) The tensile mechanical properties of the UNS S17400 material fabricated by selective laser melting are very different from those of wrought, heat-treated 17-4PH stainless steel. (4) The large discontinuous yielding strain in all tests resulted from the formation and propagation of Lüders bands.

  10. Thermo-mechanical behavior of stainless steel knitted structures

    Science.gov (United States)

    Hamdani, Syed Talha Ali; Fernando, Anura; Maqsood, Muhammad

    2016-09-01

    Heating fabric is an advanced textile material that is extensively researched by the industrialists and the scientists alike. Ability to create highly flexible and drapeable heating fabrics has many applications in everyday life. This paper presents a study conducted on the comparison of heatability of knitted fabric made of stainless steel yarn. The purpose of the study is to find a suitable material for protective clothing against cold environments. In the current research the ampacity of stainless steel yarn is observed in order to prevent the overheating of the heating fabrics. The behavior of the knitted structure is studied for different levels of supply voltage. Infrared temperature sensing is used to measure the heat generated from the fabrics in order to measure the temperature of the fabrics without physical contact. It is concluded that interlock structure is one of the most suited structures for knitted heating fabrics. As learnt through this research, fabrics made of stainless steel yarn are capable of producing a higher level of heating compared to that of knitted fabric made using silver coated polymeric yarn at the same supply voltage.

  11. Thermal Aging Phenomena in Cast Duplex Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Byun, Thak Sang; Yang, Ying; Overman, Nicole R.; Busby, Jeremy T.

    2016-02-28

    Cast stainless steels (CASSs) have been extensively used for the large components of light water reactor (LWR) power plants such as primary coolant piping and pump casing. The thermal embrittlement of CASS components is one of the most serious concerns related to the extended-term operation of nuclear power plants. Many past researches have concluded that the formation of Cr–rich α'-phase by Spinodal decomposition of δ-ferrite phase is the primary mechanism for the thermal embrittlement. Cracking mechanism in the thermally-embrittled duplex stainless steels consists of the formation of cleavage at ferrite and its propagation via separation of ferrite-austenite interphase. This article intends to provide an introductory overview on the thermal aging phenomena in LWR relevant conditions. Firstly, the thermal aging effect on toughness is discussed in terms of the cause of embrittlement and influential parameters. An approximate analysis of thermal reaction using Arrhenius equation was carried out to scope the aging temperatures for the accelerated aging experiments to simulate the 60 and 80 years of services. Further, equilibrium precipitation calculation was performed for model CASS alloys using the CALPHAD program and the results are used to describe the precipitation behaviors in duplex stainless steels. These results are also to be used to guide an on-going research aiming to provide knowledge-based conclusive prediction for the integrity of the CASS components of LWR power plants during the service life extended up to and beyond 60 years.

  12. Thermal Aging Phenomena in Cast Duplex Stainless Steels

    Science.gov (United States)

    Byun, T. S.; Yang, Y.; Overman, N. R.; Busby, J. T.

    2016-02-01

    Cast stainless steels (CASSs) have been extensively used for the large components of light water reactor (LWR) power plants such as primary coolant piping and pump casing. The thermal embrittlement of CASS components is one of the most serious concerns related to the extended-term operation of nuclear power plants. Many past researches have concluded that the formation of Cr-rich α'-phase by Spinodal decomposition of δ-ferrite phase is the primary mechanism for the thermal embrittlement. Cracking mechanism in the thermally-embrittled duplex stainless steels consists of the formation of cleavage at ferrite and its propagation via separation of ferrite-austenite interphase. This article intends to provide an introductory overview on the thermal aging phenomena in LWR-relevant conditions. Firstly, the thermal aging effect on toughness is discussed in terms of the cause of embrittlement and influential parameters. An approximate analysis of thermal reaction using Arrhenius equation was carried out to scope the aging temperatures for the accelerated aging experiments to simulate the 60 and 80 years of services. Further, an equilibrium precipitation calculation was performed for model CASS alloys using the CALPHAD program, and the results are used to describe the precipitation behaviors in duplex stainless steels. These results are also to be used to guide an on-going research aiming to provide knowledge-based conclusive prediction for the integrity of the CASS components of LWR power plants during the service life extended up to and beyond 60 years.

  13. Adsorption of ammonia on treated stainless steel and polymer surfaces

    Science.gov (United States)

    Vaittinen, O.; Metsälä, M.; Persijn, S.; Vainio, M.; Halonen, L.

    2014-05-01

    Adsorption of dynamically diluted ammonia at part-per-billion to low part-per-million concentrations in dry nitrogen was studied with treated and non-treated stainless steel and polymer test tubes. The treatments included electropolishing and two types of coatings based on amorphous silicon. Cavity ring-down spectroscopy with an external cavity diode laser operating in the near-infrared wavelength range was used to monitor the adsorption process in real time in continuous-flow conditions to obtain quantitative assessment of the adsorptive properties of the studied surfaces. The investigated polymers were all less adsorptive than any of the treated or non-treated stainless steel surfaces. Some of the commercial coatings reduced the adsorption loss of stainless steel by a factor of ten or more. Polyvinylidene fluoride was found to be superior (less adsorption) to the four other studied polymer coatings. The number of adsorbed ammonia molecules per surface area obtained at different ammonia gas phase concentrations was modeled with Langmuir and Freundlich isotherms. The time behavior of the adsorption-desorption process occurring in the time scale of seconds and minutes was simulated with a simple kinetic model.

  14. [Clinical evaluation of gingival tissue restored with stainless steel crown].

    Science.gov (United States)

    Chao, D D; Tsai, T P; Chen, T C

    1992-12-01

    The use of stainless steel crown for the restoration of primary molars is widely accepted in pediatric dentistry. There has been a concern regarding their effect on the health of the gingival tissue. It is a possibility that the preformed crown may be a contributing cause of gingivitis. This study evaluated one hundred and thirty-seven crowns in forty-five patients who had received pedodontic treatment at Chang Gung Memorial Hospital. The results indicated that the majority of stainless steel crowns had one or more defects, with crown crimping being the most common error. According to what the paired t-test showed, non-ideal crowns indicated that the gingival index was significantly higher than the entire mouth and control teeth. However the supragingival plaque accumulation of these teeth was significant lower than the entire mouth and control teeth. There was only a moderate positive correlation between supragingival plaque and gingivitis. The operator is necessary to adapt the stainless steel crown margin as closely as possible to the tooth and to avoid the mechanical defect of a crown. It minimizes the irritation of gingival tissue and diminishes the bacterial adherence of subgingival plaque, therefore preserving the health of gingival tissue.

  15. Surface interactions of cesium and boric acid with stainless steel

    International Nuclear Information System (INIS)

    In this report, the effects of cesium hydroxide and boric acid on oxidized stainless steel surfaces at high temperatures and near one atmosphere of pressure are investigated. This is the first experimental investigation of this chemical system. The experimental investigations were performed using a mass spectrometer and a mass electrobalance. Surfaces from the different experiments were examined using a scanning electron microscope to identify the presence of deposited species, and electron spectroscopy for chemical analysis to identify the species deposited on the surface. A better understanding of the equilibrium thermodynamics, the kinetics of the steam-accelerated volatilizations, and the release kinetics are gained by these experiments. The release rate is characterized by bulk vaporization/gas-phase mass transfer data. The analysis couples vaporization, deposition, and desorption of the compounds formed by cesium hydroxide and boric acid under conditions similar to what is expected during certain nuclear reactor accidents. This study shows that cesium deposits on an oxidized stainless steel surface at temperatures between 1000 and 1200 Kelvin. Cesium also deposits on stainless steel surfaces coated with boric oxide in the same temperature ranges. The mechanism for cesium deposition onto the oxide layer was found to involve the chemical reaction between cesium and chromate. Some revaporization in the cesium hydroxide-boric acid system was observed. It has been found that under the conditions given, boric acid will react with cesium hydroxide to form cesium metaborate. A model is proposed for this chemical reaction

  16. Crevice Corrosion of 321 Stainless Steel in Sodium Chloride Solutions

    International Nuclear Information System (INIS)

    Electrochemical techniques have been applied to study the crevice corrosion behaviour of stabilized 321 stainless steel in both 0.5, 1 and 2 M sodium chloride solutions at 25 and 80 degree . This type of stainless steel enjoys a good corrosion resistance especially in the heat affected zone (Haz) of welds. In this investigation the crevice corrosion of 321 stainless steel was studied in both bulk solution environments as well as in chloride solutions simulating those formed inside crevices. A metal-to-nonmetal crevice assembly, in which disc type specimens were faced to a PTFE crevice former, is used for bulk solution tests. Crevice-free specimens of solutions formed inside crevices (known as the critical crevice solutions, CCS). Cyclic potentiodynamic technique was used in evaluating the electrochemical corrosion performance of the alloy in bulk (0.5 and 1 M Nacl) environment. This revealed that both chloride ion concentration and temperature have a marked effect on the electrochemical parameters generally used for the evaluation of the crevice corrosion susceptibility. This included the corrosion potential. E corr. The passivity breakdown potential, Eb, and the protection potential, E p

  17. Long term thermal aging of cast duplex stainless steels

    International Nuclear Information System (INIS)

    Cast duplex stainless steels of CF8M and CF8 are used in major components because of their superior characteristics, such as corrosion resistance, weldability and so on. But, these stainless steels are known to have tendency of thermal aging embrittlement after long term service. Therefore, mechanical properties and metallurgical structure were investigated using materials aged at 290--400 C up to 30,000 hours. As the results show, effects of thermal aging on mechanical properties and metallurgical behavior were identified. In addition, prediction method for Charpy absorbed energy and fracture toughness was established. The following results have been obtained: (1) it was recognized that Charpy absorbed energy and fracture toughness tend to decrease and the tensile strength tend to increase with the increasing aging time; (2) it was confirmed that thermal aging embrittlement was caused by the phase separation in ferrite from the test results of APFIM; (3) in the degradation prediction model development the prediction model was applied to the material test data, including materials aged for 30,000 hours. As the results, the degradation prediction formulas for CVRT, CVHT, JIC and J6 were obtained. The toughness of cast duplex stainless steels during service could be estimated from chemical composition using this method

  18. Long term thermal aging of cast duplex stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, Isao; Koyama, Masakuni [Japan Power Engineering and Inspection Corp., Tokyo (Japan); Kawaguchi, Seiichi [Mitsubishi Heavy Industries, Ltd., Takasago (Japan); Mimaki, Hidehito [Mitsubishi Heavy Industries, Ltd., Kobe (Japan); Akiyama, Mamoru; Mishima, Yoshitsugu [Univ. of Tokyo (Japan); Okubo, Tadatsune [Sophia Univ., Tokyo (Japan); Mager, T.R.

    1996-09-01

    Cast duplex stainless steels of CF8M and CF8 are used in major components because of their superior characteristics, such as corrosion resistance, weldability and so on. But, these stainless steels are known to have tendency of thermal aging embrittlement after long term service. Therefore, mechanical properties and metallurgical structure were investigated using materials aged at 290--400 C up to 30,000 hours. As the results show, effects of thermal aging on mechanical properties and metallurgical behavior were identified. In addition, prediction method for Charpy absorbed energy and fracture toughness was established. The following results have been obtained: (1) it was recognized that Charpy absorbed energy and fracture toughness tend to decrease and the tensile strength tend to increase with the increasing aging time; (2) it was confirmed that thermal aging embrittlement was caused by the phase separation in ferrite from the test results of APFIM; (3) in the degradation prediction model development the prediction model was applied to the material test data, including materials aged for 30,000 hours. As the results, the degradation prediction formulas for CVRT, CVHT, J{sub IC} and J{sub 6} were obtained. The toughness of cast duplex stainless steels during service could be estimated from chemical composition using this method.

  19. Passivation of duplex stainless steel in solutions simulating chloride-contaminated concrete

    OpenAIRE

    Takenouti, H.; Soriano, L; Palacín, S.; Gutiérrez, A.; Velasco, F.; Blanco, G; Bautista, A.

    2007-01-01

    Most studies published to date on the corrosion behaviour of stainless reinforcing steel are based on austenitic steel. The market presence of corrugated duplex steel is growing, however. The present study compared passivity in 2205 type duplex and 304 type austenitic stainless steel. Polarization tests in chloride-containing Ca(OH)2 solutions confirmed the exceptional performance of duplex steels. X-ray photoelectronic spectroscopy (XPS) showed that the passive layer generated on duplex stai...

  20. Microbially influenced corrosion of stainless steels; Stainless ko no biseibutsu fushoku ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Kimura, Y.; Misawa, M. [Kansai Electric Power Co. Inc., Osaka (Japan)

    1998-11-30

    It is generally known, though not fully clarified, that stainless steel pipes, particularly those exposed to natural sea water; are susceptible to microbially influenced corrosion (MIC) at welded joints. In an effort to gain a better understanding of the mechanism, factors affecting the MIC behavior in welded stainless steel pipe joints were experimentally investigated. Results of the study indicate there are two major contributing factors to MIC development in the weld region. One is the circumferentially protruding shape effect of the deposited metal, provinding an environment that allows aquatic microorganisms to adhere to the downstream side of the welded bead surface. The other factor is the declining corrosion resistance in the welded joint due to the oxide film formation caused by insufficient shielding during welding. There factors, if combined, produce higher susceptibility to MIC in the weld than in the base metal. (author)

  1. Microstructural characterization in dissimilar friction stir welding between 304 stainless steel and st37 steel

    Energy Technology Data Exchange (ETDEWEB)

    Jafarzadegan, M. [Department of Materials Eng., Tarbiat Modares University, P.O. Box: 14115-143, Tehran (Iran, Islamic Republic of); State Key Laboratory of Advanced Welding Production Technology, School of Materials Science and Eng., Harbin Institute of Technology, P.O. Box: 150001, Harbin (China); Feng, A.H. [State Key Laboratory of Advanced Welding Production Technology, School of Materials Science and Eng., Harbin Institute of Technology, P.O. Box: 150001, Harbin (China); Abdollah-zadeh, A., E-mail: zadeh@modares.ac.ir [Department of Materials Eng., Tarbiat Modares University, P.O. Box: 14115-143, Tehran (Iran, Islamic Republic of); Saeid, T. [Advanced Materials Research Center, Sahand University of Technology, P.O. Box: 51335-1996, Tabriz (Iran, Islamic Republic of); Shen, J. [State Key Laboratory of Advanced Welding Production Technology, School of Materials Science and Eng., Harbin Institute of Technology, P.O. Box: 150001, Harbin (China); Assadi, H. [Department of Materials Eng., Tarbiat Modares University, P.O. Box: 14115-143, Tehran (Iran, Islamic Republic of)

    2012-12-15

    In the present study, 3 mm-thick plates of 304 stainless steel and st37 steel were welded together by friction stir welding at a welding speed of 50 mm/min and tool rotational speed of 400 and 800 rpm. X-ray diffraction test was carried out to study the phases which might be formed in the welds. Metallographic examinations, and tensile and microhardness tests were used to analyze the microstructure and mechanical properties of the joint. Four different zones were found in the weld area except the base metals. In the stir zone of the 304 stainless steel, a refined grain structure with some features of dynamic recrystallization was evidenced. A thermomechanically-affected zone was characterized on the 304 steel side with features of dynamic recovery. In the other side of the stir zone, the hot deformation of the st37 steel in the austenite region produced small austenite grains and these grains transformed to fine ferrite and pearlite and some products of displacive transformations such as Widmanstatten ferrite and martensite by cooling the material after friction stir welding. The heat-affected zone in the st37 steel side showed partially and fully refined microstructures like fusion welding processes. The recrystallization in the 304 steel and the transformations in the st37 steel enhanced the hardness of the weld area and therefore, improved the tensile properties of the joint. - Highlights: Black-Right-Pointing-Pointer FSW produced sound welds between st37 low carbon steel and 304 stainless steel. Black-Right-Pointing-Pointer The SZ of the st37 steel contained some products of allotropic transformation. Black-Right-Pointing-Pointer The material in the SZ of the 304 steel showed features of dynamic recrystallization. Black-Right-Pointing-Pointer The finer microstructure in the SZ increased the hardness and tensile strength.

  2. Microstructure and properties of composite of stainless steel and partially stabilized zirconia

    Institute of Scientific and Technical Information of China (English)

    张文泉; 谢建新; 杨志国; 王从曾

    2003-01-01

    To fabricate the metal-ceramics multi-layer hollow functionally gradient materials(FGMs) that mightmeet the requirement of repeated service and long working time of high temperature burners, such as spacecraft en-gine, the microstructure and properties of composite of stainless steel and partially stabilized zirconia were investiga-ted. Samples of different proportions of stainless steel to partially yttria-stabilized zirconia were fabricated by powderextrusion and sintering method. Shrinkage, relative density, microstructure, micro-Vickers hardness, compressionstrength, bending strength, fractography morphology and electrical resistivity of sintered samples with differentproportions of stainless steel were measured. The results show that threshold of metallic matrix composite(MMC)is approximately equal to 60 % (volume fraction) stainless steel. The samples with 0 to 50% (volume fraction) stain-less steel indicate ceramic brittleness and non cutability, and the samples with 70% to 100% (volume fraction) stain-less steel indicate metallic plasticity and cutability.

  3. EFFECT OF INTERMETALLIC PHASES ON CORROSION BEHAVIOR AND MECHANICAL PROPERTIES OF DUPLEX STAINLESS STEEL AND SUPER-DUPLEX STAINLESS STEEL

    Directory of Open Access Journals (Sweden)

    Prabhu Paulraj

    2015-08-01

    Full Text Available Duplex Stainless Steels (DSS and Super Duplex Stainless Steel (SDSS have excellent integration of mechanical and corrosion properties. However, the formation of intermetallic phases is a major problem in their usage. The mechanical and corrosion properties are deteriorated due to the presence of intermetallic phases. These phases are induced during welding, prolonged exposure to high temperatures, and improper heat treatments. The main emphasis of this review article is on intermetallic phases and their effects on corrosion and mechanical properties. First the effect of various alloying elements on DSS and SDSS has been discussed followed by formation of various intermetallic phases. The intermetallic phases affect impact toughness and corrosion resistance significantly. Their deleterious effect on weldments has also been reviewed.

  4. The influence of sintering time on the properties of PM duplex stainless steel

    OpenAIRE

    Z. Brytan; L.A. Dobrzański; M. Actis Grande; M. Rosso

    2009-01-01

    Purpose: The purpose of this paper is to analyse the effect of sintering time on the pore morphology, microstructural changes, tensile properties and corrosion resistance of vacuum sintered duplex stainless steel.Design/methodology/approach: In presented study PM duplex stainless steels were obtained through mixing base ferritic stainless steel powder with controlled addition of elemental alloying powders and then sintered in a vacuum furnace with argon backfilling at 1250°C for different tim...

  5. Marine microbial fuel cell : use of stainless steel electrodes as anode and cathode materials

    OpenAIRE

    Dumas, Claire; Mollica, Alfonso; Féron, Damien; Basséguy, Régine; Etcheverry, Luc; Bergel, Alain

    2007-01-01

    Numerous biocorrosion studies have stated that biofilms formed in aerobic seawater induce an efficient catalysis of the oxygen reduction on stainless steels. This property was implemented here for the first time in a marine microbial fuel cell (MFC). A prototype was designed with a stainless steel anode embedded in marine sediments coupled to a stainless steel cathode in the overlying seawater. Recording current/potential curves during the progress of the experiment confirmed that the cath...

  6. Microstructure and wear resistance of spray-formed supermartensitic stainless steel

    OpenAIRE

    Guilherme Zepon; Claudio Shyinti Kiminami; Walter José Botta Filho; Claudemiro Bolfarini

    2013-01-01

    Since the early 90's the oil industry has been encouraging the development of corrosion and wear resistant alloys for onshore and offshore pipeline applications. In this context supermartensitic stainless steel was introduced to replace the more expensive duplex stainless steel for tubing applications. Despite the outstanding corrosion resistance of stainless steels, their wear resistance is of concern. Some authors reported obtaining material processed by spray forming, such as ferritic stai...

  7. Influence of hydrogen on corrosion and stress induced cracking of stainless steel

    OpenAIRE

    Kivisäkk, Ulf

    2010-01-01

    Hydrogen is the smallest element in the periodical table. It has been shown in several studies that hydrogen has a large influence on the corrosion and cracking behaviour of stainless steels. Hydrogen is involved in several of the most common cathode reactions during corrosion and can also cause embrittlement in many stainless steels. Some aspects of the effect of hydrogen on corrosion and hydrogen-induced stress cracking, HISC, of stainless steels were studied in this work. These aspects rel...

  8. 77 FR 16207 - Stainless Steel Bar From Brazil, India, Japan, and Spain: Final Results of the Expedited Third...

    Science.gov (United States)

    2012-03-20

    ... Steel Bar From Spain, 60 FR 11656 (March 2, 1995). The Department received a notice of intent to.... Stainless steel bar means articles of stainless steel in straight lengths that have been either hot-rolled... International Trade Administration Stainless Steel Bar From Brazil, India, Japan, and Spain: Final Results...

  9. Tensile behavior of irradiated manganese-stabilized stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Klueh, R.L. [Oak Ridge National Lab., TN (United States)

    1996-10-01

    Tensile tests were conducted on seven experimental, high-manganese austenitic stainless steels after irradiation up to 44 dpa in the FFTF. An Fe-20Mn-12Cr-0.25C base composition was used, to which various combinations of Ti, W, V, B, and P were added to improve strength. Nominal amounts added were 0.1% Ti, 1% W, 0.1% V, 0.005% B, and 0.03% P. Irradiation was carried out at 420, 520, and 600{degrees}C on the steels in the solution-annealed and 20% cold-worked conditions. Tensile tests were conducted at the irradiation temperature. Results were compared with type 316 SS. Neutron irradiation hardened all of the solution-annealed steels at 420, 520, and 600{degrees}C, as measured by the increase in yield stress and ultimate tensile strength. The steel to which all five elements were added to the base composition showed the least amount of hardening. It also showed a smaller loss of ductility (uniform and total elongation) than the other steels. The total and uniform elongations of this steel after irradiation at 420{degrees}C was over four times that of the other manganese-stabilized steels and 316 SS. There was much less difference in strength and ductility at the two higher irradiation temperatures, where there was considerably less hardening, and thus, less loss of ductility. In the cold-worked condition, hardening occured only after irradiation at 420{degrees}C, and there was much less difference in the properties of the steels after irradiation. At the 420{degrees}C irradiation temperature, most of the manganese-stabilized steels maintained more ductility than the 316 SS. After irradiation at 420{degrees}C, the temperature of maximum hardening, the steel to which all five of the elements were added had the best uniform elongation.

  10. Improved corrosion resistance of 316L stainless steel by nanocrystalline and electrochemical nitridation in artificial saliva solution

    Science.gov (United States)

    Lv, Jinlong; Liang, Tongxiang

    2015-12-01

    The fluoride ion in artificial saliva significantly changed semiconductor characteristic of the passive film formed on the surface of 316L stainless steels. The electrochemical results showed that nanocrystalline α‧-martensite improved corrosion resistance of the stainless steel in a typical artificial saliva compared with coarse grained stainless steel. Moreover, comparing with nitrided coarse grained stainless steel, corrosion resistance of the nitrided nanocrystalline stainless steel was also improved significantly, even in artificial saliva solution containing fluoride ion. The present study showed that the cryogenic cold rolling and electrochemical nitridation improved corrosion resistance of 316L stainless steel for the dental application.

  11. Electrochemical and passivation behavior investigation of ferritic stainless steel in simulated concrete pore media.

    Science.gov (United States)

    Luo, Hong; Su, Huaizhi; Dong, Chaofang; Xiao, Kui; Li, Xiaogang

    2015-12-01

    The applications of stainless steel are one of the most reliable solutions in concrete structures to reduce chloride-induced corrosion problems and increase the structures service life, however, due to high prices of nickel, especially in many civil engineering projects, the austenitic stainless steel is replaced by the ferritic stainless steels. Compared with austenite stainless steel, the ferritic stainless steel is known to be extremely resistant of stress corrosion cracking and other properties. The good corrosion resistance of the stainless steel is due to the formation of passive film. While, there is little literature about the electrochemical and passive behavior of ferritic stainless steel in the concrete environments. So, here, we present the several corrosion testing methods, such as the potentiodynamic measurements, EIS and Mott-Schottky approach, and the surface analysis methods like XPS and AES to display the passivation behavior of 430 ferritic stainless steel in alkaline solution with the presence of chloride ions. These research results illustrated a simple and facile approach for studying the electrochemical and passivation behavior of stainless steel in the concrete pore environments. PMID:26501086

  12. NDE of explosion welded copper stainless steel first wall mock-up

    International Nuclear Information System (INIS)

    The study showed that reflection type C-mode scanning acoustic microscope (C-SAM) and internal ultrasonic inspection (IRIS) equipment can be applied for ultrasonic examination of copper stainless steel compound structures of ITER first wall mock-ups. Explosive welding can be applied to manufacture fully bonded copper stainless steel compound plates. However, explosives can be applied only for mechanical tightening of stainless steel cooling tubes within copper plate. If metallurgical bonding between stainless steel tubes and copper plate is required Hot Isostatic Pressing (HIP) method can be applied. (orig.)

  13. Electrochemical and passivation behavior investigation of ferritic stainless steel in simulated concrete pore media.

    Science.gov (United States)

    Luo, Hong; Su, Huaizhi; Dong, Chaofang; Xiao, Kui; Li, Xiaogang

    2015-12-01

    The applications of stainless steel are one of the most reliable solutions in concrete structures to reduce chloride-induced corrosion problems and increase the structures service life, however, due to high prices of nickel, especially in many civil engineering projects, the austenitic stainless steel is replaced by the ferritic stainless steels. Compared with austenite stainless steel, the ferritic stainless steel is known to be extremely resistant of stress corrosion cracking and other properties. The good corrosion resistance of the stainless steel is due to the formation of passive film. While, there is little literature about the electrochemical and passive behavior of ferritic stainless steel in the concrete environments. So, here, we present the several corrosion testing methods, such as the potentiodynamic measurements, EIS and Mott-Schottky approach, and the surface analysis methods like XPS and AES to display the passivation behavior of 430 ferritic stainless steel in alkaline solution with the presence of chloride ions. These research results illustrated a simple and facile approach for studying the electrochemical and passivation behavior of stainless steel in the concrete pore environments.

  14. Nano/ultrafine grained austenitic stainless steel through the formation and reversion of deformation-induced martensite: Mechanisms, microstructures, mechanical properties, and TRIP effect

    Energy Technology Data Exchange (ETDEWEB)

    Shirdel, M., E-mail: mshirdel1989@ut.ac.ir [School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, P.O. Box 11155-4563, Tehran (Iran, Islamic Republic of); Mirzadeh, H., E-mail: hmirzadeh@ut.ac.ir [School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, P.O. Box 11155-4563, Tehran (Iran, Islamic Republic of); Advanced Metalforming and Thermomechanical Processing Laboratory, School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); Parsa, M.H., E-mail: mhparsa@ut.ac.ir [School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, P.O. Box 11155-4563, Tehran (Iran, Islamic Republic of); Center of Excellence for High Performance Materials, School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); Advanced Metalforming and Thermomechanical Processing Laboratory, School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of)

    2015-05-15

    A comprehensive study was carried out on the strain-induced martensitic transformation, its reversion to austenite, the resultant grain refinement, and the enhancement of strength and strain-hardening ability through the transformation-induced plasticity (TRIP) effect in a commercial austenitic 304L stainless steel with emphasis on the mechanisms and the microstructural evolution. A straightforward magnetic measurement device, which is based on the measurement of the saturation magnetization, for evaluating the amount of strain-induced martensite after cold rolling and reversion annealing in metastable austenitic stainless steels was used, which its results were in good consistency with those of the X-ray diffraction (XRD) method. A new parameter called the effective reduction in thickness was introduced, which corresponds to the reasonable upper bound on the obtainable martensite fraction based on the saturation in the martensitic transformation. By means of thermodynamics calculations, the reversion mechanisms were estimated and subsequently validated by experimental results. The signs of thermal martensitic transformation at cooling stage after reversion at 850 °C were found, which was attributed to the rise in the martensite start temperature due to the carbide precipitation. After the reversion treatment, the average grain sizes were around 500 nm and the nanometric grains of the size of ~ 65 nm were also detected. The intense grain refinement led to the enhanced mechanical properties and observation of the change in the work-hardening capacity and TRIP effect behavior. A practical map as a guidance for grain refining and characterizing the stability against grain growth was proposed, which shows the limitation of the reversion mechanism for refinement of grain size. - Graphical abstract: Display Omitted - Highlights: • Nano/ultrafine grained austenitic stainless steel through martensite treatment • A parameter descriptive of a reasonable upper bound on

  15. CO2 laser welding of AISI 321stainless steel

    International Nuclear Information System (INIS)

    CO2 laser welding of AISI 321austenitic stainless steel has been carried out. Bead on plate welds on 2 mm thick steel were performed with 450W CO2 laser at speeds ranging from 200 to 900 mm/min. It was observed that weld depth and width was decreased with increasing the speed at constant laser power. Butt welds on different sheet thickness of 1, 2 and 2.5 mm were performed with laser power of 450 W and at speed 750, 275 and 175 mm/min, respectively. The microstructures of the welded joints and the heat affected zones (HAZ) were examined by optical microscopy and SEM. The austenite/delta ferrite microstructure was reported in the welded zone. The microhardness and tensile strength of the welded joints were measured and found almost similar to base metal due to austenitic nature of steel

  16. Joining dissimilar stainless steels for pressure vessel components

    International Nuclear Information System (INIS)

    A series of studies was carried out to examine the weldability and properties of dissimilar steel joints between martensitic and austenitic stainless steels - F6NM (OCrl3Ni4Mo) and AISI 347, respectively. The weldability tests included weld thermal simulation of the martensitic steel for investigating the influence of weld thermal cycles and post-weld heat treatment (PWHT) on the mechanical properties of the heat-affected zone (HAZ); implant testing for examining the tendency for cold cracking of martensitic steel; rigid restraint testing for determining hot crack susceptibility of the multi-pass dissimilar steel joints. The joints were subjected to various mechanical tests including a tensile test, bending test and impact test at various temperatures, as well as slow strain-rate test for examining the stress corrosion cracking tendency in the simulated environment of a primary circuit of a PWR. Based on the weldability tests, a welding procedure - tungsten inert gas (TIG) welding for root passes with HNiCrMo-2B wire followed by manual metal arc (MMA) welding using coated electrode ENiCrFe-3B - was developed and a PWHT at 600 deg C/2h was recommended. Furthermore, the welding of tube/tube joints between these dissimilar steels is described. (21 refs., 11 figs., 14 tabs.)

  17. The interaction between nitride uranium and stainless steel

    Science.gov (United States)

    Shornikov, D. P.; Nikitin, S. N.; Tarasov, B. A.; Baranov, V. G.; Yurlova, M. S.

    2016-04-01

    Uranium nitride is most popular nuclear fuel for Fast Breeder Reactor New Generation. In-pile experiments at reactor BOR-60 was shown an interaction between nitride fuel and stainless steel in the range of 8-11% burn up (HA). In order to investigate this interaction has been done diffusion tests of 200 h and has been shown that the reaction occurs in the temperature range 1000-1100 ° C. UN interacted with steel in case of high pollution oxygen (1000-2000 ppm). Also has been shown to increase interaction UN with EP-823 steel in the presence of cesium. In this case the interaction layer had a thickness about 2-3 μm. Has been shown minimal interaction with new ODS steel EP-450. The interaction layer had a thickness less then 2 μm. Did not reveal the influence of tellurium and iodine increased interaction. It was show compatibility at 1000 °C between UN and EP-450 ODS steel, chrome steel, alloying aluminium and silicium.

  18. Fabrication of high nitrogen austenitic stainless steels with excellent mechanical and pitting corrosion properties

    Institute of Scientific and Technical Information of China (English)

    Hua-bing Li; Zhou-hua Jiang; Yang Cao; Zu-rui Zhang

    2009-01-01

    18Cr18Mn2Mo0.9N high nitrogen austenitic stainless steel exhibits high strength and good ductility at room temperature. The steel shows typical duc-tile-brittle transition behavior and excellent pitting corrosion resistance properties.

  19. The influence of cold work on the oxidation behaviour of stainless steel

    International Nuclear Information System (INIS)

    In this thesis the study of the interaction of oxygen gas with stainless steel surfaces is described. Thermogravimetry, microscopy and ellipsometry have been used to follow the oxidation in situ, while EDX, AES and XPS have been used to determine the oxide compositions. The aim of this thesis is to reveal the influence on the oxidation behaviour of stainless steel of i) cold work (rolling, drawing, milling, polishing and Ar ion bombardment) ii) the initially formed oxide and iii) the experimental conditions. Two types of stainless steels have been used (AISI 304 (a 18/8 Cr/Ni steel) and Incoloy 800 H (a 20/30 Cr/Ni steel)). (Auth.)

  20. In situ 3D monitoring of corrosion on carbon steel and ferritic stainless steel embedded in cement paste

    KAUST Repository

    Itty, Pierre-Adrien

    2014-06-01

    In a X-ray microcomputed tomography study, active corrosion was induced by galvanostatically corroding steel embedded in cement paste. The results give insight into corrosion product build up, crack formation, leaching of products into the cracks and voids, and differences in morphology of corrosion attack in the case of carbon steel or stainless steel reinforcement. Carbon steel was homogeneously etched away with a homogeneous layer of corrosion products forming at the steel/cement paste interface. For ferritic stainless steel, pits were forming, concentrating the corrosion products locally, which led to more extensive damage on the cement paste cover. © 2014 Elsevier Ltd.

  1. Effect of Deleterious Phases on Corrosion Resistance of Duplex Stainless Steel (2205)

    OpenAIRE

    AbdulKadar M. Godil; Hitesh A. Narsia; M. N. Patel; Mr. Paresh U. Haribhakti

    2013-01-01

    Duplex stainless steel is a Ferritic(BCC)-Austenitic(FCC) steel, covers the advantages of both Austenitic and Ferritic Stainless steels. They having good mechanical and corrosion resistance properties are widely used in many industries like chemical plants, refineries for critical equipments such as pressure vessels, heatexchangers, water heaters. Major problem occurs with duplex steels when they are worked or heated above about temperature of 280°C. Detrimental phases like Sigma, Chi, Laves ...

  2. Threshold Chloride Concentration of Stainless Steels in Simulated Concrete Pore Solution

    OpenAIRE

    Wang, Hailong; Ling, Jiayan; Sun, Xiaoyan

    2016-01-01

    To evaluate whether stainless steel can replace carbon steel as rebar in reinforced concrete structures exposed to aggressive environment, the threshold chloride concentration of carbon steel, austenitic and duplex stainless steels were experimentally studied in this paper. The solutions with pH ranging from 9.5 to 13.6 were used herein to simulate the pore liquids in both alkaline and carbonated concretes. Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) tests we...

  3. Separation by transportation in vapor phase of stainless steels components

    International Nuclear Information System (INIS)

    A procedure for separating cobalt from other constituents of radioactive stainless steel is proposed in order to condition material originating from dismantling of reactor pressure vessels. The procedure is based on the transport in the vapour phase, under the presence of an appropriate carrier gas and a thermal gradient in a sealed device. By calculation, iodine was found to be the most appropriate carrier gas. Tests carried out at 50 mg to 2 g scale in quartz ampoules permitted to determine parameters, i.e. temperature range and gradient, pressure, and the effectiveness. It was shown that steel turnings may be treated efficiently. The procedure achieves well a partition of stainless steel into two metal masses: one containing the bulk of cobalt and radioactivity, the other depleted of cobalt and suitable for recycling. There is few or no secondary waste created, but the costs of the procedure are estimated to be high, i.e. between 100 and 1,000 ECU/kg

  4. Stable phases in aged type 321 stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Bentley, J.; Leitnaker, J.M.

    1978-01-01

    X-ray diffraction and Analytical Electron Microscopy have been used to characterize the precipitate phases present in type 321 stainless steel after 17 years of service at approximately 600/sup 0/C. The morphology, crystallography, and orientation relationships with the matrix of the precipitates have been determined along with the chemical composition of several of the phases. Long-term aging of type 321 stainless steel indicates TiC, not M/sub 23/C/sub 6/, is the stable carbide phase. A theory is developed to explain appearance of M/sub 23/C/sub 6/ at intermediate times. The theory also indicates the means for preventing M/sub 23/C/sub 6/ formation and hence sensitization of the steel to intergranular corrosion. The amount of sigma found correlates well with results from shorter time studies. Ti/sub 4/C/sub 2/S/sub 2/ and a complex phosphide-arsenide were also present.

  5. High-pressure stainless steel active membrane microvalves

    Science.gov (United States)

    Sharma, G.; Svensson, S.; Ogden, S.; Klintberg, L.; Hjort, K.

    2011-07-01

    In this work, high-pressure membrane microvalves have been designed, manufactured and evaluated. The valves were able to withstand back-pressures of 200 bar with a response time of less than 0.6 s. These stainless steel valves, manufactured with back-end batch production, utilize the large volume expansion coupled to the solid-liquid phase transition in paraffin wax. When membrane materials were evaluated, parylene coated stainless steel was found to be the best choice as compared to polydimethylsiloxane and polyimide. Also, the influence of the orifice placement and diameter is included in this work. If the orifice is placed too close to the rim of the membrane, the valve can stay sealed even after turning the power off, and the valve will not open until the pressure in the system is released. The developed steel valves, evaluated for both water and air, provide excellent properties in terms of mechanical stability, ease of fabrication, and low cost. Possible applications include sampling at high pressures, chemical microreactors, high performance liquid chromatography, pneumatics, and hydraulics.

  6. Malfunction analysis of OPGW of stainless steel-unit structure

    Institute of Scientific and Technical Information of China (English)

    李星梅; 张素芳; 王旭锋; 乞建勋

    2008-01-01

    Composite fiber optic overhead ground wire (OPGW) is increasingly applied in China’s overhead transmission lines. The stainless steel structure is adopted by most OPGWs as it is very small and easy to match the existing ground wire. The malfunction of OPGW in Beijing-Shanghai Optical Communication Project was analyzed through the chemical composition method and spectrum semi-quantitative method. The analysis indicates that the cable fault was due to the failure of seepage and irregular holes in the steel pipe of the optical unit. The rain water and the watery air entered into the optical units, and the water in turn became ice when temperature dropped. The occurrence of ice led to the acceleration of attenuation of the fiber. The results show that the rupture of stainless steel tube is mainly due to the instability of welding technique. The malfunction of OPGW is due to the local defects of welding seam because of local stress concentration in the manufacturing process.

  7. Sensitization of Laser-beam Welded Martensitic Stainless Steels

    Science.gov (United States)

    Dahmen, Martin; Rajendran, Kousika Dhasanur; Lindner, Stefan

    Ferritic and martensitic stainless steels are an attractive alternative in vehicle production due to their inherent corrosion resistance. By the opportunity of press hardening, their strength can be increased to up to 2000 MPa, making them competitors for unalloyed ultra-high strength steels. Welding, nevertheless, requires special care, especially when it comes to joining of high strength heat treated materials. With an adopted in-line heat treatment of the welds in as-rolled as well as press hardened condition, materials with sufficient fatigue strength and acceptable structural behavior can be produced. Because of microstructural transformations in the base material such as grain coarsening and forced carbide precipitation, the corrosion resistance of the weld zone may be locally impaired. Typically the material in the heat-affected zone becomes sensitive to intergranular cracking in the form of knife-edge corrosion besides the fusion line. The current study comprises of two text scenarios. By an alternating climate test, general response in a corroding environment is screened. In order to understand the corrosion mechanisms and to localize the sensitive zones, sensitisation tests were undertaken. Furthermore, the applicability of a standard test according to ASTM 763-83 was examined. It was found that the alternative climate test does not reveal any corrosion effects. Testing by the oxalic acid test revealed clearly the effect of welding, weld heat treatment and state of thermal processing. Also application of the standard which originally suited for testing ferritic stainless steels could have been justified.

  8. Cold Spray Repair of Martensitic Stainless Steel Components

    Science.gov (United States)

    Faccoli, M.; Cornacchia, G.; Maestrini, D.; Marconi, G. P.; Roberti, R.

    2014-12-01

    The possibility of using cold spray as repair technique of martensitic stainless steel components was evaluated through laboratory investigations. An austenitic stainless steel feedstock powder was chosen, instead of soft metals powders like nickel, copper, or aluminum, used for repairing components made in light alloy or cast iron. The present study directly compares the microstructure, the residual stresses, and the micro-hardness of repairs obtained by cold spray and by TIG welding, that is commonly used as repair technique in large steel components. XRD and optical metallographic analysis of the repairs showed that cold spray offers some advantages, inducing compressive residual stresses in the repair and avoiding alterations of the interface between repair and base material. For these reasons, a heat treatment after the cold spray repair is not required to restore the base material properties, whereas a post-weld heat treatment is needed after the welding repair. Cold spray repair also exhibits a higher micro-hardness than the welding repair. In addition, the cavitation erosion resistance of a cold spray coating was investigated through ultrasonic cavitation tests, and the samples worn surfaces were observed by scanning electron microscopy.

  9. THE EFFECT OF W ON THE REPASSIVATION BEHAVIOR OF Ni-ADDED STAINLESS STEELS

    Institute of Scientific and Technical Information of China (English)

    J.X. Pan; K. Y. Kim

    2005-01-01

    The effect of W on the repassivation behavior of Ni-added stainless steels was investigated with respect to the repassivation rate and the SCC susceptibility. It was found that more stable passive film was formed on the W-modified stainless steels than that of steels without W-modification, and the repassivation rate was faster for W-modified stainless steels in acidic chloride solution (0.5M H2SO4+3.5% Cl-). In neutral chloride solution (1M MgCl2), there were no significant differences on both passivation properties and the repassivation rates for duplex stainless steels,while W-modified austenite stainless steel showed faster repassivation rate. The SCC tests verified that W-modified Ni-added stainless steels exhibited better SCC resistance than steels without W in chloride solution. Moreover, W-modification in higher Ni-added stainless steels exhibited more remarkable SCC resistance than steels with lower Ni content in chloride solution.

  10. Influence of surface finish on the cleanability of stainless steel.

    Science.gov (United States)

    Frank, J F; Chmielewski, R

    2001-08-01

    Stainless steel for fabricating food processing equipment is available with various surface finishes. The objective of this research was to determine the effect of surface finish on cleanability. Nine samples of stainless steel, type 304, from various manufacturers including no finish (hot rolled and pickled), #4 finish, 2B mechanical polished, and electropolished were tested. Cleanability was assessed by using coupon samples soiled with either cultured milk inoculated with spores of Bacillus stearothermophilus or by growth of a Pseudomonas sp. biofilm. Samples were cleaned by immersion in a turbulent bath of 1.28% sodium hydroxide at 66 degrees C for 3 min followed by a sterile water rinse, neutralizing in 0.1% phosphoric acid for 30 s, rinsing in phosphate buffer, sanitizing in 100 ppm hypochlorite, neutralizing in sodium thiosulfate, and drying. To determine residual milk soil, coupon samples were covered with PM indicator agar and incubated for 25 h at 58 degrees C. Other coupons were subjected to an additional 10 soiling or cleaning cycles, and the residual protein was measured by using epifluorescent microscopy and image analysis. Results indicate that the spore count was more precise for measuring initial cleanability of the finished samples, and the protein residue determination was useful for determining the effect of repeated cleaning. Data on the removal of milk soil suggest that stainless steel should be purchased based on measures of surface defects rather than finish type. Surface defects, as determined using a surface roughness gauge, produced a correlation of 0.82 with spore counts. Data also indicated that biofilm was more difficult to remove than milk-based soil. PMID:11510656

  11. A study on laser welding deformation of 304 stainless steel

    International Nuclear Information System (INIS)

    In heavy industries, 304 austenitic stainless steel is the most popular material which is used for nuclear equipment, chemical vessels, vacuum vessels and so on. On the fabrication, not only a joint quality but also severe dimensional accuracy is required. To keep dimensional accuracy, considerable cost and efforts are requested, because the welding deformation of austenitic stainless steel is deeply depended on the physical properties of material itself. To decrease welding deformation, big jigs or water cooling method are commonly used which lead to the high cost. In general, the fusion welding by high energy density heat source results in less distortion. Today, laser welding technology has grown up to the stage that enables to weld thick plate with small deformation. The researches of welding deformation have been conducted intensively, but they are mainly concerned for arc welding, and studies for laser welding are very few. In this report, the authors will show the test results of deformation behavior in laser welding of 304 stainless steel. Also, they will discuss the deformation behavior comparing to that in arc welding. The main results of this study are as follows. 1. The angular distortion of laser welding can be unified by heat input parameter (Hp) which is used for arc welding deformation. 2. The angular distortion are same under the condition of Hp3 in spite of different welding method, however under the condition of Hp>6-9 J/mm3 the angular distortion is quite different depending on the power density of welding method. 3. Pure angular distortion seemed to complete just after welding, but following longitudinal distortion took place for long period. 4. The critical value of longitudinal distortion can be estimated from heat input parameter. The transverse deformation can be also estimated by heat input parameter. (author)

  12. Aging and Embrittlement of High Fluence Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Was, gary; Jiao, Zhijie; der ven, Anton Van; Bruemmer, Stephen; Edwards, Dan

    2012-12-31

    Irradiation of austenitic stainless steels results in the formation of dislocation loops, stacking fault tetrahedral, Ni-Si clusters and radiation-induced segregation (RIS). Of these features, it is the formation of precipitates which is most likely to impact the mechanical integrity at high dose. Unlike dislocation loops and RIS, precipitates exhibit an incubation period that can extend from 10 to 46 dpa, above which the cluster composition changes and a separate phase, (G-phase) forms. Both neutron and heavy ion irradiation showed that these clusters develop slowly and continue to evolve beyond 100 dpa. Overall, this work shows that the irradiated microstructure features produced by heavy ion irradiation are remarkably comparable in nature to those produced by neutron irradiation at much lower dose rates. The use of a temperature shift to account for the higher damage rate in heavy ion irradiation results in a fairly good match in the dislocation loop microstructure and the precipitate microstructure in austenitic stainless steels. Both irradiations also show segregation of the same elements and in the same directions, but to achieve comparable magnitudes, heavy ion irradiation must be conducted at a much higher temperature than that which produces a match with loops and precipitates. First-principles modeling has confirmed that the formation of Ni-Si precipitates under irradiation is likely caused by supersaturation of solute to defect sinks caused by highly correlated diffusion of Ni and Si. Thus, the formation and evolution of Ni-Si precipitates at high dose in austenitic stainless steels containing Si is inevitable.

  13. Chromium-nickel stainless steel and method of its manufacture

    International Nuclear Information System (INIS)

    The chromium-nickel stainless steel is designed for the production of rolled bands to be welded onto the primary circuit component surfaces. The invention claims the steel composition. Phosphorus content is restricted to an amount of 0.005 to 0.025%, sulfur to 0.001 to 0.012%, oxygen to 0.001 to 0.008% aluminium to 0.005 to 0.05%, and titanium to 0.02 to 0.20%. The steel may also contain 0.01 to 0.15% of cerium, 0.01 to 0.15% of zirconium and 0.0001 to 0.005% of boron while the overall combined content of cerium, zirconium and boron does not exceed 0.25%. The initial material is nonalloyed waste, nickel metal and ferroalloys. The steel is deoxidized with aluminium and its chemical composition is adjusted with an addition of ferrochrome or nickel. The steel is then vacuum processed and after standing, it is cast at a temperature of 1520 to 1580 degC. (J.P.)

  14. Joining dissimilar stainless steels for pressure vessel components

    Science.gov (United States)

    Sun, Zheng; Han, Huai-Yue

    1994-03-01

    A series of studies was carried out to examine the weldability and properties of dissimilar steel joints between martensitic and austenitic stainless steels - F6NM (OCr13Ni4Mo) and AISI 347, respectively. Such joints are important parts in, e.g. the primary circuit of a pressurized water reactor (PWR). This kind of joint requires both good mechanical properties, corrosion resistance and a stable magnetic permeability besides good weldability. The weldability tests included weld thermal simulation of the martensitic steel for investigating the influence of weld thermal cycles and post-weld heat treatment (PWHT) on the mechanical properties of the heat-affected zone (HAZ); implant testing for examining the tendency for cold cracking of martensitic steel; rigid restraint testing for determining hot crack susceptibility of the multi-pass dissimilar steel joints. The joints were subjected to various mechanical tests including a tensile test, bending test and impact test at various temperatures, as well as slow strain-rate test for examining the stress corrosion cracking tendency in the simulated environment of a primary circuit of a PWR. The results of various tests indicated that the quality of the tube/tube joints is satisfactory for meeting all the design requirements.

  15. Thermal stability of ultrafine-grained austenitic stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Etienne, A.; Radiguet, B.; Genevois, C.; Le Breton, J.-M. [Groupe de Physique des Materiaux, Universite et INSA de Rouen, UMR CNRS 6634, BP 12, 76 801 Saint Etienne du Rouvray Cedex (France); Valiev, R. [Institute of Physics of Advanced Materials, Ufa State Aviation Technical University, 12K. Marx Street, 450000 Ufa (Russian Federation); Pareige, P., E-mail: philippe.pareige@univ-rouen.fr [Groupe de Physique des Materiaux, Universite et INSA de Rouen, UMR CNRS 6634, BP 12, 76 801 Saint Etienne du Rouvray Cedex (France)

    2010-08-20

    Ultrafine-grained 316 and 304 austenitic stainless steel samples have been produced by high pressure torsion. Their microstructure, after deformation and annealing at a temperature in the 350-900 deg. C range, has been characterized using several techniques (transmission electron microscopy, X-ray diffraction, Moessbauer spectroscopy). The average grain size in the ultrafine-grained 316 is about 40 nm while it is larger in the ultrafine-grained 304 due to a smaller deformation. Results show the formation of {alpha}'-martensite during deformation in both steels while {epsilon}-martensite is formed only in the 304 steel. Annealing at 350 deg. C induces the decrease of {alpha}'-martensite content in the 316 steel. The trend is different in the 304 steel, in which the {alpha}'-martensite content increases. Recrystallization of grains is observed from 700 deg. C. Moessbauer spectroscopy shows a reduction of the level of solute atoms in {alpha}'-martensite during annealing.

  16. Microbial corrosion in weld zone of stainless steel. Stainless ko yosetsubu no biseibutsu fushoku

    Energy Technology Data Exchange (ETDEWEB)

    Sasaki, E. (National Chemical Laboratory for Industry, Tsukuba (Japan)); Nishimura, M. (Mitsubishi Kakoki Kaisha, Ltd., Tokyo (Japan))

    1992-10-15

    Microbial corrosion may happen wherever water is treated in many kinds of practical metal except titan, such as common steel, copper alloy, stainless steel, and high-nickel alloy. Although microbes causing microbial corrosion are not limited to specified microbes, specially affecting microbes are iron bacteria, iron-oxidizing bacteria, and sulfate-reducing bacteria. mechanism in these microbial corrosion, which is fundamentally caused through formation of oxygen concentration cells and production of metabolites, is complex and different by each microbe. In the case of stainless steel, the corrosion is located mainly in weld zones or heat affected zones, the shape of corrosion is like a pot, and the pattern is a type of pitting corrosion. Microbes are apt to adhere to the surface near weld zones, then oxygen becomes consequently insufficient beneath the surface, where the self-mending capacity of passive films is deprived, resulting in occurrence of pitting corrosion. For protection of microbial corrosion, it is essential to control water so that habitation of microbes is not formed. 9 refs., 3 figs.

  17. Characteristics of residual stresses of water jet peened stainless steel

    International Nuclear Information System (INIS)

    The material of the specimen was austenitic stainless steel, SUS316L. The residual stresses in the specimen was introduced by a water jet peening (WJP). The change in the residual stress with thermal aging at 773K was measured by an X-ray stress measurement. The WJP residual stresses were an equi-biaxial stress state, and the compressive residual stress did not decrease against the thermal aging. To investigate dependence of the residual stress on a lattice plane, the WJP residual stresses were measured using hard synchrotron X-rays. (author)

  18. Thermal aging evaluation of casting stainless steel under BWR environment

    International Nuclear Information System (INIS)

    Effect of thermal aging under BWR condition on material properties of casting stainless steel were evaluated by such as Charpy impact test, using replaced BWR component material. Solution heat treatment was performed to the same material and the material properties were obtained. Comparing each material test results, impact value of thermal aging material was lower than solution heat treatment material. By the results, thermal aging effect on material properties under BWR condition was confirmed. The material properties were compared with model equation using PLM evaluation and conservativeness of model equation was confirmed. (author)

  19. Analysis of ridging in ferritic stainless steel sheet

    Energy Technology Data Exchange (ETDEWEB)

    Wu, P.D. [Novelis Inc., Novelis Global Technology Centre, 945 Princess Street, Kingston, Ont., K7L 5L9 (Canada)]. E-mail: wupeidong@hotmail.com; Jin, H. [Novelis Inc., Novelis Global Technology Centre, 945 Princess Street, Kingston, Ont., K7L 5L9 (Canada); Shi, Y. [Novelis Inc., Novelis Global Technology Centre, 945 Princess Street, Kingston, Ont., K7L 5L9 (Canada); Lloyd, D.J. [Novelis Inc., Novelis Global Technology Centre, 945 Princess Street, Kingston, Ont., K7L 5L9 (Canada)

    2006-05-15

    The finite element method is used to numerically simulate the development of ridging/roping in ferritic stainless steel sheet under stretching. The measured electron backscattered diffraction (EBSD) data (grain orientations and their spatial distributions) are directly incorporated into the finite element model and the constitutive response at an integration point is described by the single crystal plasticity theory. The effects of spatial orientation distribution, imposed deformation path, and inhomogeneous deformation within individual grains on the roping are discussed. It is found that the initial texture and its spatial distribution are the predominant factors for the development of ridging.

  20. Low temperature gaseous nitriding and carburising of stainless steel

    DEFF Research Database (Denmark)

    Christiansen, Thomas; Somers, Marcel A.J.

    2005-01-01

    The response of various austenitic and duplex stainless steel grades to low temperature gaseous nitriding and carburising was investigated. Gaseous nitriding was performed in ammonia/hydrogen mixtures at temperatures ,723 K; gaseous carburising was carried out in carbon monoxide/hydrogen mixtures...... for temperatures (783 K. The case developed by thermochemical treatment was examined using reflected light microscopy, X-ray diffraction analysis and microhardness testing. Both nitriding and carburising led to the development of expanded austenite in the surface adjacent zone, irrespective of the phase...... constitution of the substrate. A two step process, consisting of carburising followed by nitriding, provides great flexibility with regard to adjusting the hardness–depth profile....