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Sample records for 20-l continuously stirred

  1. Continuous-flow stirred-tank reactor 20-L demonstration test: Final report

    Lee, D.D.; Collins, J.L.

    2000-02-01

    One of the proposed methods of removing the cesium, strontium, and transuranics from the radioactive waste storage tanks at Savannah River is the small-tank tetraphenylborate (TPB) precipitation process. A two-reactor-in-series (15-L working volume each) continuous-flow stirred-tank reactor (CSTR) system was designed, constructed, and installed in a hot cell to test the Savannah River process. The system also includes two cross-flow filtration systems to concentrate and wash the slurry produced in the process, which contains the bulk of radioactivity from the supernatant processed through the system. Installation, operational readiness reviews, and system preparation and testing were completed. The first test using the filtration systems, two CSTRs, and the slurry concentration system was conducted over a 61-h period with design removal of Cs, Sr, and U achieved. With the successful completion of Test 1a, the following tests, 1b and 1c, were not required.

  2. Evaluation of the Small-Tank Tetraphenylborate Process Using a Bench-Scale, 20-L Continuous Stirred Tank Reactor System at Oak Ridge National Laboratory: Results of Test 5

    Lee, D.D.

    2001-08-30

    The goal of the Savannah River Salt Waste Processing Program (SPP) is to evaluate the presently available technologies and select the most effective approach for treatment of high-level waste salt solutions currently stored in underground tanks at the U.S. Department of Energy's Savannah River Site in Aiken, South Carolina. One of the three technologies currently being developed for this application is the Small-Tank Tetraphenylborate Process (STTP). This process uses sodium tetraphenylborate (TPB) to precipitate and remove radioactive cesium from the waste and monosodium titanate (MST) to sorb and remove radioactive strontium and actinides. Oak Ridge National Laboratory is demonstrating this process at the 1:4000 scale using a 20-L-capacity continuous-flow stirred-tank reactor (CSTR) system. Since March 1999, five operating campaigns of the 20-L CSTR have been conducted. The ultimate goal is to verify that this process, under certain extremes of operating conditions, can meet the minimum treatment criteria necessary for processing and disposing of the salt waste at the Savannah River Saltstone Facility. The waste acceptance criteria (WAC) for {sup 137}Cs, {sup 90}Sr, and total alpha nuclides are <40 nCi/g, <40 nCi/g, and <18 nCi/g, respectively. However, to allow for changes in process conditions, the SPP is seeking a level of treatment that is about 50% of the WAC. The bounding separation goals for {sup 137}Cs and {sup 90}Sr are to obtain decontamination factors (DFs) of 40,000 (99.998% removal) and 26 (96.15% removal), respectively. (DF is mathematically defined as the concentration of contaminant in the waste feed divided by the concentration of contaminant in the effluent stream.)

  3. Nonequilibrium chemical instabilities in continuous flow stirred tank reactors: The effect of stirring

    Horsthemke, W.; Hannon, L.

    1984-11-01

    We present a stochastic model for stirred chemical reactors. In the limiting case of practical interest, i.e., fast stirring, we solve for the characteristic function in steady state and derive expressions for the stationary moments through a perturbation expansion. Moments are explicitly calculated for a generic model of bistable behavior. We find that stirring decreases the area of the bistable region essentially by changing the point of transition from the high reaction rate state to the low reaction rate state. This is in remarkable agreement with the experimental findings of Roux, et al. Our results indicate that stirring should not be considered simply as an ``enhanced diffusion'' process and that nucleation plays only a minor role in transitions between multiple steady states in a continuous flow stirred tank reactor (CSTR).

  4. Kinetics of propionate conversion in anaerobic continuously stirred tank reactors

    Bangsø Nielsen, Henrik; Mladenovska, Zuzana; Ahring, Birgitte Kiær

    2008-01-01

    The kinetic parameters of anaerobic propionate degradation by biomass from 7 continuously stirred tank reactors differing in temperature, hydraulic retention time and substrate composition were investigated. In substrate-depletion experiments (batch) the maximum propionate degradation rate, A......-m, was estimated. The results demonstrate that the rate of endogenous substrate (propionate) production should be taken into account when estimating kinetic parameters in biomass from manure-based anaerobic reactors....

  5. Adaptive Controller Design for Continuous Stirred Tank Reactor

    K. Prabhu

    2014-09-01

    Full Text Available Continues Stirred Tank Reactor (CSTR is an important issue in chemical process and a wide range of research in the area of chemical engineering. Temperature Control of CSTR has been an issue in the chemical control engineering since it has highly non-linear complex equations. This study presents problem of temperature control of CSTR with the adaptive Controller. The Simulation is done in MATLAB and result shows that adaptive controller is an efficient controller for temperature control of CSTR than PID controller.

  6. Design of Controllers for Continuous Stirred Tank Reactor

    Somasundaram Deepa

    2015-02-01

    Full Text Available The objective of the project is to design various controllers for temperature control in Continuous Stirred Tank Reactor (CSTR systems. Initially Zeigler-Nichols, modified Zeigler-Nichols, Tyreus-Luyben, Shen-Yu and IMC based method of tuned Proportional Integral (PI controller is designed and comparisons are made with Fuzzy Logic Controller. Simulations are carried out and responses are obtained for the above controllers. Maximum peak overshoot, Settling time, Rise time,  ISE, IAE  are chosen as performance index. From the analysis it is found that the Fuzzy Logic Controller  is a promising controller than the conventional controllers.

  7. A cubic autocatalytic reaction in a continuous stirred tank reactor

    Yakubu, Aisha Aliyu; Yatim, Yazariah Mohd [School of Mathematical Sciences, Universiti Sains Malaysia, 11800 USM, Penang Malaysia (Malaysia)

    2015-10-22

    In the present study, the dynamics of the cubic autocatalytic reaction model in a continuous stirred tank reactor with linear autocatalyst decay is studied. This model describes the behavior of two chemicals (reactant and autocatalyst) flowing into the tank reactor. The behavior of the model is studied analytically and numerically. The steady state solutions are obtained for two cases, i.e. with the presence of an autocatalyst and its absence in the inflow. In the case with an autocatalyst, the model has a stable steady state. While in the case without an autocatalyst, the model exhibits three steady states, where one of the steady state is stable, the second is a saddle point while the last is spiral node. The last steady state losses stability through Hopf bifurcation and the location is determined. The physical interpretations of the results are also presented.

  8. Implementation of Neural Control for Continuous Stirred Tank Reactor (CSTR

    Karima M. Putrus

    2011-01-01

    Full Text Available In this paper a dynamic behavior and control of a jacketed continuous stirred tank reactor (CSTR is developed using different control strategies, conventional feedback control (PI and PID, and neural network (NARMA-L2, and NN Predictive control. The dynamic model for CSTR process is described by a first order lag system with dead time.The optimum tuning of control parameters are found by two different methods; Frequency Analysis Curve method (Bode diagram and Process Reaction Curve using the mean of Square Error (MSE method. It is found that the Process Reaction Curve method is better than the Frequency Analysis Curve method and PID feedback controller is better than PI feedback controller. The results show that the artificial neural network is the best method to control the CSTR process and it is better than the conventional method because it has smaller value of mean square error (MSE. MATLAB program is used as a tool of solution for all cases used in the present work.

  9. Center Segregation with Final Electromagnetic Stirring in Billet Continuous Casting Process

    Jiang, Dongbin; Zhu, Miaoyong

    2017-02-01

    With a multiphase solidification model built, the effect of F-EMS parameters on center segregation was investigated in 160 mm × 160 mm billet continuous casting process. In the model, the initial growth of equiaxed grains which could move freely with liquid was treated as slurry, while the coherent equiaxed zone was regarded as porous media. The results show that the stirring velocity is not the main factor influencing center segregation improvement, which is more affected by current intensity and stirring pool width. Because solute transport is controlled by solidification rate as stirring pool width is 73 mm, center segregation declines continuously with current intensity increasing. As liquid pool width decreases to 61 mm and less latent heat needs to dissipate in the later solidification, the center segregation could be improved more obviously by F-EMS. Due to center liquid solute enrichment and liquid phase accumulation in the stirring zone, center segregation turns to rise reversely with higher current intensity and becomes more serious with stirring pool width further decreasing to 43 mm. As the stirring pool width is 25 mm, the positive segregation has already formed and solute could still concentrate with weak stirring, leading to center segregation deterioration. With the optimized current intensity (400 A) and stirring pool width (61 mm) set for continuous mode, center segregation improvement is better than that of alternative mode.

  10. Chaotic behavior in the dynamical system of a continuous stirred tank reactor

    Retzloff, D. G.; Chan, P. C.-H.; Chicone, C.; Offin, D.; Mohamed, R.

    1987-03-01

    The dynamical system describing a continuous stirred tank reactor (CSTR) for the reactions A→B→C and A→C, B→D is considered. A circulating attractor with accompanying circulating orbits is shown to exist when the critical point of the system is unique and unstable. The orbit structure has been numerically found to consist of periodic orbits and chaotic behavior.

  11. Effect of electromagnetic stirring on solidification structure of austenitic stainless steel in horizontal continuous casting

    2007-01-01

    An investigation on the influence of low frequency rotary electromagnetic stirring on solidification structure of austenitic stainless steel in horizontal continuous casting was experimentally conducted and carried out on an industrial trial basis. The results show that application of appropriate electromagnetic stirring parameters can obviously improve the macrostructure of austenitic stainless steel, in which both columnar and equiaxed grains can be greatly refined and shrinkage porosity or cavity zone along centerline can be remarkably decreased due to eliminating intracrystalline and enlarging equiaxed grains zone. The industrial trials verify that the electromagnetic stirring intensity of austenitic stainless steel should be higher than that of plain carbon steel. Electromagnetic stirring has somewhat affected the macrostructure of austenitic stainless steel even if the magnetic flux density of the electromagnetic stirring reaches 90 mT (amplitude reaches 141 mT ) in average at frequency f=3-4Hz, which provides a reference for the optimization of design and process parameters when applying the rotary electromagnetic stirrer

  12. Effect of electromagnetic stirring on solidification structure of austenitic stainless steel in horizontal continuous casting

    ZHOU Shu-cai

    2007-08-01

    Full Text Available An investigation on the influence of low frequency rotary electromagnetic stirring on solidification structure of austenitic stainless steel in horizontal continuous casting was experimentally conducted and carried out on an industrial trial basis. The results show that application of appropriate electromagnetic stirring parameters can obviously improve the macrostructure of austenitic stainless steel, in which both columnar and equiaxed grains can be greatly refined and shrinkage porosity or cavity zone along centerline can be remarkably decreased due to eliminating intracrystalline and enlarging equiaxed grains zone. The industrial trials verify that the electromagnetic stirring intensity of austenitic stainless steel should be higher than that of plain carbon steel. Electromagnetic stirring has somewhat affected the macrostructure of austenitic stainless steel even if the magnetic flux density of the electromagnetic stirring reaches 90 mT (amplitude reaches 141 mT in average at frequency f=3-4Hz, which provides a reference for the optimization of design and process parameters when applying the rotary electromagnetic stirrer.

  13. Selective precipitation of Cu from Zn in a pS controlled continuously stirred tank reactor

    Sampaio, R.M.; Timmers, R.A.; Xu, Y.; Keesman, K.J.; Lens, P.N.L.

    2009-01-01

    Copper was continuously and selectively precipitated with Na2S to concentrations below 0.3 ppb from water containing around 600 ppm of both Cu and Zn in a Continuously Stirred Tank Reactor. The pH was controlled at 3 and the pS at 25 (pS = ¿log(S2¿)) by means of an Ag2S sulfide selective electrode.

  14. Electromagnetic stirring in the continuous casting of steel. Agitacion electromagnetica en la colada continua de acero

    Alvarez de Toledo, G.; Campo, O.; Lainez, E. (Sidenor, Basauri (Spain))

    1995-01-01

    The electromagnetic stirring of steel in the machines for the continuous casting process has improved the internal quality of the cast product. Experimental work with stirrers situated at different positions of continuous casting machines of billets has been carried out. The in-mould stirrer is the one that produces a major modification of the billet internal structure, and also the biggest decrease of the central segregation. An in mould electromagnetic coil has been developed which allows the use of high stirring power without producing an undesirable movement of the liquid steel in the meniscus zone, therefore no mould powders entrapments are produced. It has been developed a method for determining the optimum electric frequency of the stirrer. (Author) 31 refs.

  15. Evaluation of an integrated continuous stirred microbial electrochemical reactor: Wastewater treatment, energy recovery and microbial community.

    Wang, Haiman; Qu, Youpeng; Li, Da; Zhou, Xiangtong; Feng, Yujie

    2015-11-01

    A continuous stirred microbial electrochemical reactor (CSMER) was developed by integrating anaerobic digestion (AD) and microbial electrochemical system (MES). The system was capable of treating high strength artificial wastewater and simultaneously recovering electric and methane energy. Maximum power density of 583±9, 562±7, 533±10 and 572±6 mW m(-2) were obtained by each cell in a four-independent circuit mode operation at an OLR of 12 kg COD m(-3) d(-1). COD removal and energy recovery efficiency were 87.1% and 32.1%, which were 1.6 and 2.5 times higher than that of a continuous stirred tank reactor (CSTR). Larger amount of Deltaproteobacteria (5.3%) and hydrogenotrophic methanogens (47%) can account for the better performance of CSMER, since syntrophic associations among them provided more degradation pathways compared to the CSTR. Results demonstrate the CSMER holds great promise for efficient wastewater treatment and energy recovery.

  16. Bistability in an uncatalyzed bromate oscillator in a continuously fed stirred tank reactor

    Dutt, Arun K.; Müller, S. C.

    1996-01-01

    Uncatalyzed gallic acid oscillating system has been investigated in a continuously fed stirred tank reactor (CSTR). In the [Bromate]0-[Bromide]0 concentration space, a region has been located where a bistability is observed between an oscillatory branch and a flow branch. To our knowledge this is the first evidence of bistability in an uncatalyzed bromate oscillator. Some observations have been explained in terms of the skeleton mechanism proposed in the past.

  17. Continuous production of diatom Entomoneis sp. in mechanically stirred tank and flat-panel airlift photobioreactors.

    Viriyayingsiri, Thunyaporn; Sittplangkoon, Pantaporn; Powtongsook, Sorawit; Nootong, Kasidit

    2016-10-02

    Continuous production of diatom Entomonies sp. was performed in mechanically stirred tank and flat-panel airlift photobioreactors (FPAP). The maximum specific growth rate of diatom from the batch experiment was 0.98 d(-1). A series of dilution rate and macronutrient concentration adjustments were performed in a stirred tank photobioreactor and found that the dilution rate ranged from 0.7 to 0.8 d(-1) and modified F/2 growth media containing nitrate at 3.09 mg N/L, phosphate at 2.24 mg P/L, and silicate at 11.91 mg Si/L yielded the maximum cell number density. Finally, the continuous cultivation of Entomonies sp. was conducted in FPAP using the optimal conditions determined earlier, resulting in the maximum cell number density of 19.69 × 10(4) cells/mL, which was approximately 47 and 73% increase from the result using the stirred tank photobioreactor fed with modified and standard F/2 growth media, respectively.

  18. MODELLING AND CONTROL OF CONTINUOUS STIRRED TANK REACTOR WITH PID CONTROLLER

    Artur Wodołażski

    2016-09-01

    Full Text Available This paper presents a model of dynamics control for continuous stirred tank reactor (CSTR in methanol synthesis in a three-phase system. The reactor simulation was carried out for steady and transient state. Efficiency ratio to achieve maximum performance of the product per reactor unit volume was calculated. Reactor dynamics simulation in closed loop allowed to received data for tuning PID controller (proportional-integral-derivative. The results of the regulation process allow to receive data for optimum reactor production capacity, along with local hot spots eliminations or temperature runaway.

  19. Development of Linearizing Feedback Control with a Variable Structure Observer for Continuous Stirred Tank Reactors

    Bachir Daaou; Abdellah Mansouri; Mohamed Bouhamida; Mohammed Chenafa

    2012-01-01

    This paper deals with the design of an observer-based nonlinear control for continuous stirred tank reactors (CSTR). A variable structure observer is constructed to estimate the whole process state variables. This observer is basically the conventional Luenberger observer with an additional switching term used to guarantee the robustness against modeling errors. The observer is coupled with a nonlinear controller, designed based on input-output linearization for controlling the reactor temperature. The asymptotical stability of the closed-loop system is shown by the Lyapunov stability theorem. Finally, computer simulations are developed for showing the performance of the proposed approach.

  20. A long-lived lunar dynamo driven by continuous mechanical stirring.

    Dwyer, C A; Stevenson, D J; Nimmo, F

    2011-11-09

    Lunar rocks contain a record of an ancient magnetic field that seems to have persisted for more than 400 million years and which has been attributed to a lunar dynamo. Models of conventional dynamos driven by thermal or compositional convection have had difficulty reproducing the existence and apparently long duration of the lunar dynamo. Here we investigate an alternative mechanism of dynamo generation: continuous mechanical stirring arising from the differential motion, due to Earth-driven precession of the lunar spin axis, between the solid silicate mantle and the liquid core beneath. We show that the fluid motions and the power required to drive a dynamo operating continuously for more than one billion years and generating a magnetic field that had an intensity of more than one microtesla 4.2 billion years ago are readily obtained by mechanical stirring. The magnetic field is predicted to decrease with time and to shut off naturally when the Moon recedes far enough from Earth that the dissipated power is insufficient to drive a dynamo; in our nominal model, this occurred at about 48 Earth radii (2.7 billion years ago). Thus, lunar palaeomagnetic measurements may be able to constrain the poorly known early orbital evolution of the Moon. This mechanism may also be applicable to dynamos in other bodies, such as large asteroids.

  1. Biological treatment of phenolic wastewater in an anaerobic continuous stirred tank reactor

    Firozjaee Taghizade Tahere

    2013-01-01

    Full Text Available In the present study, an anaerobic continuous stirred tank reactor (ACSTR with consortium of mixed culture was operated continuously for a period of 110 days. The experiments were performed with three different hydraulic retention times and by varying initial phenol concentrations between 100 to 1000 mg/L. A maximum phenol removal was observed at a hydraulic retention time (HRT of 4 days, with an organic loading rate (OLR of 170.86 mg/L.d. At this condition, phenol removal rate of 89% was achieved. In addition, the chemical oxygen demand (COD removal corresponds to phenol removal. Additional operating parameters such as pH, MLSS and biogas production rate of the effluents were also measured. The present study provides valuable information to design an anaerobic ACSTR reactor for the biodegradation of phenolic wastewater.

  2. Bio-hydrogen production from molasses by anaerobic fermentation in continuous stirred tank reactor

    Han, Wei; Li, Yong-feng; Chen, Hong; Deng, Jie-xuan; Yang, Chuan-ping

    2010-11-01

    A study of bio-hydrogen production was performed in a continuous flow anaerobic fermentation reactor (with an available volume of 5.4 L). The continuous stirred tank reactor (CSTR) for bio-hydrogen production was operated under the organic loading rates (OLR) of 8-32 kg COD/m3 reactor/d (COD: chemical oxygen demand) with molasses as the substrate. The maximum hydrogen production yield of 8.19 L/d was obtained in the reactor with the OLR increased from 8 kg COD/m3 reactor/d to 24 kg COD/m3 d. However, the hydrogen production and volatile fatty acids (VFAs) drastically decreased at an OLR of 32 kg COD/m3 reactor/d. Ethanoi, acetic, butyric and propionic were the main liquid fermentation products with the percentages of 31%, 24%, 20% and 18%, which formed the mixed-type fermentation.

  3. Genetic Algorithm Based PID Controller Tuning Approach for Continuous Stirred Tank Reactor

    A. Jayachitra

    2014-01-01

    Full Text Available Genetic algorithm (GA based PID (proportional integral derivative controller has been proposed for tuning optimized PID parameters in a continuous stirred tank reactor (CSTR process using a weighted combination of objective functions, namely, integral square error (ISE, integral absolute error (IAE, and integrated time absolute error (ITAE. Optimization of PID controller parameters is the key goal in chemical and biochemical industries. PID controllers have narrowed down the operating range of processes with dynamic nonlinearity. In our proposed work, globally optimized PID parameters tend to operate the CSTR process in its entire operating range to overcome the limitations of the linear PID controller. The simulation study reveals that the GA based PID controller tuned with fixed PID parameters provides satisfactory performance in terms of set point tracking and disturbance rejection.

  4. Biohydrogen production from waste bread in a continuous stirred tank reactor: A techno-economic analysis.

    Han, Wei; Hu, Yun Yi; Li, Shi Yi; Li, Fei Fei; Tang, Jun Hong

    2016-12-01

    Biohydrogen production from waste bread in a continuous stirred tank reactor (CSTR) was techno-economically assessed. The treating capacity of the H2-producing plant was assumed to be 2 ton waste bread per day with lifetime of 10years. Aspen Plus was used to simulate the mass and energy balance of the plant. The total capital investment (TCI), total annual production cost (TAPC) and annual revenue of the plant were USD931020, USD299746/year and USD639920/year, respectively. The unit hydrogen production cost was USD1.34/m(3) H2 (or USD14.89/kg H2). The payback period and net present value (NPV) of the plant were 4.8years and USD1266654, respectively. Hydrogen price and operators cost were the most important variables on the NPV. It was concluded that biohydrogen production from waste bread in the CSTR was feasible for practical application.

  5. Performance of continuous stirred tank reactor (CSTR) on fermentative biohydrogen production from melon waste

    Cahyari, K.; Sarto; Syamsiah, S.; Prasetya, A.

    2016-11-01

    This research was meant to investigate performance of continuous stirred tank reactor (CSTR) as bioreactor for producing biohydrogen from melon waste through dark fermentation method. Melon waste are commonly generated from agricultural processing stages i.e. cultivation, post-harvesting, industrial processing, and transportation. It accounted for more than 50% of total harvested fruit. Feedstock of melon waste was fed regularly to CSTR according to organic loading rate at value 1.2 - 3.6 g VS/ (l.d). Optimum condition was achieved at OLR 2.4 g VS/ (l.d) with the highest total gas volume 196 ml STP. Implication of higher OLR value is reduction of total gas volume due to accumulation of acids (pH 4.0), and lower substrate volatile solid removal. In summary, application of this method might valorize melon waste and generates renewable energy sources.

  6. Nonlinear versus Ordinary Adaptive Control of Continuous Stirred-Tank Reactor

    Vojtesek, Jiri; Dostal, Petr

    2015-01-01

    Unfortunately, the major group of the systems in industry has nonlinear behavior and control of such processes with conventional control approaches with fixed parameters causes problems and suboptimal or unstable control results. An adaptive control is one way to how we can cope with nonlinearity of the system. This contribution compares classic adaptive control and its modification with Wiener system. This configuration divides nonlinear controller into the dynamic linear part and the static nonlinear part. The dynamic linear part is constructed with the use of polynomial synthesis together with the pole-placement method and the spectral factorization. The static nonlinear part uses static analysis of the controlled plant for introducing the mathematical nonlinear description of the relation between the controlled output and the change of the control input. Proposed controller is tested by the simulations on the mathematical model of the continuous stirred-tank reactor with cooling in the jacket as a typical nonlinear system. PMID:26346878

  7. Fluid dynamic analysis of a continuous stirred tank reactor for technical optimization of wastewater digestion.

    Hurtado, F J; Kaiser, A S; Zamora, B

    2015-03-15

    Continuous stirred tank reactors (CSTR) are widely used in wastewater treatment plants to reduce the organic matter and microorganism present in sludge by anaerobic digestion. The present study carries out a numerical analysis of the fluid dynamic behaviour of a CSTR in order to optimize the process energetically. The characterization of the sludge flow inside the digester tank, the residence time distribution and the active volume of the reactor under different criteria are determined. The effects of design and power of the mixing system on the active volume of the CSTR are analyzed. The numerical model is solved under non-steady conditions by examining the evolution of the flow during the stop and restart of the mixing system. An intermittent regime of the mixing system, which kept the active volume between 94% and 99%, is achieved. The results obtained can lead to the eventual energy optimization of the mixing system of the CSTR.

  8. Thermodynamics of open nonlinear systems far from equilibrium: The continuously stirred tank reactor

    Yoshida, Nobuo

    1993-11-01

    A thermodynamic analysis is made of a continuously stirred tank reactor (CSTR) which is fed with ideal gases and in which arbitrary types of chemical reactions take place. For stationary states and oscillatory ones in which limit cycles are established, expressions are derived which describe the change of entropy of the reactor contents relative to the feed in terms of explicit quantities, including the rate of entropy production due to the chemical reactions. This entropy change is shown to be always greater than what would be observed in closed systems under comparable circumstances. It is pointed out that this statement is beyond what the second law of thermodynamics can predict. In previous articles, entropy and entropy production have been found to follow certain systematic trends in some specific models based on the CSTR. That work is compared with the present theory.

  9. Anaerobic digestion performance of vinegar residue in continuously stirred tank reactor.

    Li, Lin; Feng, Lu; Zhang, Ruihong; He, Yanfeng; Wang, Wen; Chen, Chang; Liu, Guangqing

    2015-06-01

    Anaerobic digestion (AD) of vinegar residue was investigated in continuously stirred tank reactor (CSTR). The influence of organic loading rate (OLR) and effluent recirculation on AD performance of vinegar residue was tested. Five OLRs, 1.0, 1.5, 2.0, 2.5, and 3.0 g(vs) L(-1) d(-1), were used. The highest volumetric methane productivity of 581.88 mL L(-1) was achieved at OLR of 2.5 g(vs) L(-1) d(-1). Effluent reflux ratio was set as 50%, the results showed that effluent recirculation could effectively neutralize the acidity of vinegar residue, raise the pH of the feedstock, and enhance the buffering capacity of the AD system. Anaerobic digestion of vinegar residue could be a promising way not only for converting this waste into gas energy but also alleviating environmental pollution which might be useful for future industrial application.

  10. Stability criteria and critical runway conditions of propylene glycol manufacture in a continuous stirred tank reactor

    Miguel Ángel Gómez

    2015-08-01

    Full Text Available Here, a new method for the analysis of the steady state and the safety operational conditions of the hydrolysis of propylene oxide with excess of water, in a Continuous Stirred Tank Reactor (CSTR, was developed. For industrial operational typical values, at first, the generated and removed heat balances were examined. Next, the effect of coolant fluid temperature in the critical ignition and extinction temperatures (TCI and TCE, respectively was analyzed. The influence of the heat exchange parameter (hS on coolant and critical temperatures was also studied. Finally, the steady state operation areas were defined. The existence of multiple stable states was recognized when the heat exchange parameter was in the range 6.636 < hS kJ/(min.K < 11.125. Unstable operation area was located between the TCI and TCE values, restricting the reactor operation area to the low stable temperatures.

  11. Immersion and invariance adaptive control of a class of continuous stirred tank reactors

    Gaiyan HONG; Xiangbin LIU; Hongye SU

    2015-01-01

    An immersion and invariance (I&I) manifold based adaptive control algorithm is presented for a class of continuous stirred tank reactors (CSTR) to realize performance-oriented control in this paper. The nonlinear contraction method is combined into the control law design to render the closed-loop CSTR system globally asymptotically stable, firstly. Then, the I&I method is used to form the adaptation law such that the off-the-manifold coordinate (the parameter estimation error) converges to zero using P-monotone property enforced by selecting tuning function in manifold. As a result, the state of the closed-loop CSTR converges to its desired value asymptotically. The simulation is given to illustrate the effectiveness of the presented algorithm.

  12. CFD optimization of continuous stirred-tank (CSTR) reactor for biohydrogen production.

    Ding, Jie; Wang, Xu; Zhou, Xue-Fei; Ren, Nan-Qi; Guo, Wan-Qian

    2010-09-01

    There has been little work on the optimal configuration of biohydrogen production reactors. This paper describes three-dimensional computational fluid dynamics (CFD) simulations of gas-liquid flow in a laboratory-scale continuous stirred-tank reactor used for biohydrogen production. To evaluate the role of hydrodynamics in reactor design and optimize the reactor configuration, an optimized impeller design has been constructed and validated with CFD simulations of the normal and optimized impeller over a range of speeds and the numerical results were also validated by examination of residence time distribution. By integrating the CFD simulation with an ethanol-type fermentation process experiment, it was shown that impellers with different type and speed generated different flow patterns, and hence offered different efficiencies for biohydrogen production. The hydrodynamic behavior of the optimized impeller at speeds between 50 and 70 rev/min is most suited for economical biohydrogen production.

  13. Artificial Neural Networks Based Modeling and Control of Continuous Stirred Tank Reactor

    R. S.M.N. Malar

    2009-01-01

    Full Text Available Continuous Stirred Tank Reactor (CSTR is one of the common reactors in chemical plant. Problem statement: Developing a model incorporating the nonlinear dynamics of the system warrants lot of computation. An efficient control of the product concentration can be achieved only through accurate model. Approach: In this study, attempts were made to alleviate the above mentioned problem using “Artificial Intelligence” (AI techniques. One of the AI techniques namely Artificial Neural Networks (ANN was used to model the CSTR incorporating its non-linear characteristics. Two nonlinear models based control strategies namely internal model control and direct inverse control were designed using the neural networks and applied to the control of isothermal CSTR. Results: The simulation results for the above control schemes with set point tracking were presented. Conclusion: Results indicated that neural networks can learn accurate models and give good non-linear control when model equations are not known.

  14. A mathematical model for multiple hydrogeneration reactions in a continuous stirred three phase slurry reactor with an evaporating solvent

    Janssen, H.J.; Westerterp, K.R.; Vos, J.

    1992-01-01

    An experimental study of the catalytic hydorgenation of 2,4-dinitrotoluene (DNT) in a mini-installation with a continuously operated stirred three-phase slurry reactor and an evaporating solvent is discussed. Some characteristic properties of the reactor system and the influence of the operating par

  15. A new halogen-free chemical oscillator: the reaction between permanganate ion and ninhydrin in a continuously stirred tank reactor

    Treindl, Ľudovít; Nagy, Arpád

    1987-07-01

    The reaction between permanganate ion and ninhydrin in the presence of phosphoric acid in aqueous solution shows sustained oscillations in a continuously stirred tank reactor (CSTR). It exhibits a kinetic bistability between an oscillatory and a stationary state. Our new oscillating system seems to be a second permanganate chemical oscillator, thus broadening the small group of non-halogen-based chemical oscillators.

  16. Analysis of cracking phenomena in continuous casting of 1Cr13 stainless steel billets with final electromagnetic stirring

    Yu Xu; Rong-jun Xu; Zheng-jie Fan; Cheng-bin Li; An-yuan Deng; En-gang Wang

    2016-01-01

    Solidification cracking that occurs during continuous casting of 1Cr13 stainless steel was investigated with and without final elec-tromagnetic stirring (F-EMS). The results show that cracks initiates and propagates along the grain boundaries where the elements of carbon and sulfur are enriched. The final stirrer should be appropriately placed at a location that is 7.5 m away from the meniscus, and the appropri-ate thickness of the liquid core in the stirring zone is 50 mm. As a stirring current of 250 A is imposed, it can promote columnar-equiaxed transition, decrease the secondary dendrite arm spacing, and reduce the segregation of both carbon and sulfur. F-EMS can effectively de-crease the amount of cracks in 1Cr13 stainless steel.

  17. Selective precipitation of Cu from Zn in a pS controlled continuously stirred tank reactor

    Sampaio, R.M.M., E-mail: ricardo.sampaio@wur.nl [Sub-department of Environmental Technology, Wageningen University, ' Biotechnion' , Bomenweg 2, P.O. Box 8129, 6700 EV Wageningen (Netherlands); Timmers, R.A., E-mail: ruud.timmers@wur.nl [Sub-department of Environmental Technology, Wageningen University, ' Biotechnion' , Bomenweg 2, P.O. Box 8129, 6700 EV Wageningen (Netherlands); Xu, Y., E-mail: lucyxyzxyz@hotmail.com [Sub-department of Environmental Technology, Wageningen University, ' Biotechnion' , Bomenweg 2, P.O. Box 8129, 6700 EV Wageningen (Netherlands); Keesman, K.J., E-mail: karel.keesman@wur.nl [Systems and Control Group, Wageningen University, Bornsesteeg 59, 6708 PD Wageningen (Netherlands); Lens, P.N.L., E-mail: piet.lens@wur.nl [Sub-department of Environmental Technology, Wageningen University, ' Biotechnion' , Bomenweg 2, P.O. Box 8129, 6700 EV Wageningen (Netherlands)

    2009-06-15

    Copper was continuously and selectively precipitated with Na{sub 2}S to concentrations below 0.3 ppb from water containing around 600 ppm of both Cu and Zn in a Continuously Stirred Tank Reactor. The pH was controlled at 3 and the pS at 25 (pS = -log(S{sup 2-})) by means of an Ag{sub 2}S sulfide selective electrode. Copper's recovery and purity were about 100%, whereas the total soluble sulfide concentration was below 0.02 ppm. X-ray diffraction (XRD) analysis showed that copper precipitated as hexagonal CuS (covellite). The mode of the particle size distribution (PSD) of the CuS precipitates was around 36 {mu}m. The PSD increased by high pS values and by the presence of Zn. Depending on the turbulence, the CuS precipitates can grow up to 200 {mu}m or fragment in particles smaller than 3 {mu}m in a few seconds. Zn precipitation with Na{sub 2}S at pH 3 and 4, in batch, always lead to Zn concentrations above 1 ppm. Zn precipitated as cubic ZnS (spharelite).

  18. Solidification Structure of Continuous Casting Large Round Billets under Mold Electromagnetic Stirring

    Tao SUN; Feng YUE; Hua-jie WU; Chun GUO; Ying LI; Zhong-cun MA

    2016-01-01

    The solidification structure of a continuous casting large round billet was analyzed by a cellular-automaton-finite-element coupling model using the ProCAST software.The actual and simulated solidification structures were compared under mold electromagnetic stirring (MEMS)conditions (current of 300 A and frequency of 3 Hz).There-after,the solidification structures of the large round billet were investigated under different superheats,casting speeds,and secondary cooling intensities.Finally,the effect of the MEMS current on the solidification structures was obtained under fixed superheat,casting speed,secondary cooling intensity,and MEMS frequency.The model accurately simulated the actual solidification structures of any steel,regardless of its size and the parameters used in the continuous casting process.The ratio of the central equiaxed grain zone was found to increase with decreasing su-perheat,increasing casting speed,decreasing secondary cooling intensity,and increasing MEMS current.The grain size obviously decreased with decreasing superheat and increasing MEMS current but was less sensitive to the casting speed and secondary cooling intensity.

  19. Cassava Stillage Treatment by Thermophilic Anaerobic Continuously Stirred Tank Reactor (CSTR)

    Luo, Gang; Xie, Li; Zou, Zhonghai; Zhou, Qi

    2010-11-01

    This paper assesses the performance of a thermophilic anaerobic Continuously Stirred Tank Reactor (CSTR) in the treatment of cassava stillage under various organic loading rates (OLRs) without suspended solids (SS) separation. The reactor was seeded with mesophilic anaerobic granular sludge, and the OLR increased by increments to 13.80 kg COD/m3/d (HRT 5d) over 80 days. Total COD removal efficiency remained stable at 90%, with biogas production at 18 L/d (60% methane). Increase in the OLR to 19.30 kg COD/m3/d (HRT 3d), however, led to a decrease in TCOD removal efficiency to 79% due to accumulation of suspended solids and incomplete degradation after shortened retention time. Reactor performance subsequently increased after OLR reduction. Alkalinity, VFA and pH levels were not significantly affected by OLR variation, indicating that no additional alkaline or pH adjustment is required. More than half of the SS in the cassava stillage could be digested in the process when HRT was 5 days, which demonstrated the suitability of anaerobic treatment of cassava stillage without SS separation.

  20. [Research on change process of nitrosation granular sludge in continuous stirred-tank reactor].

    Yin, Fang-Fang; Liu, Wen-Ru; Wang, Jian-Fang; Wu, Peng; Shen, Yao-Liang

    2014-11-01

    In order to investigate the effect of different types of reactors on the nitrosation granular sludge, a continuous stirred-tank reactor (CSTR) was studied, using mature nitrosation granular sludge cultivated in sequencing batch reactor (SBR) as seed sludge. Results indicated that the change of reactor type and influent mode could induce part of granules to lose stability with gradual decrease in sludge settling ability during the initial period of operation. However, the flocs in CSTR achieved fast granulation in the following reactor operation. In spite of the changes of particle size distribution, e. g. the decreasing number of granules with diameter larger than 2.5 mm and the increasing number of granules with diameter smaller than 0.3 mm, granular sludge held the absolute predominance of sludge morphology in CSTR during the entire experimental period. Moreover, results showed that the change of reactor type and influent mode didn't affect the nitrite accumulation rate which was still kept at about 85% in effluent. Additionally, the average activity of the sludge in CSTR was stronger than that of the seed sludge, because the newly generated small particles in CSTR had higher specific reactive activity than the larger granules.

  1. Continuous biological waste gas treatment in stirred trickle-bed reactor with discontinuous removal of biomass.

    Laurenzis, A; Heits, H; Wübker, S; Heinze, U; Friedrich, C; Werner, U

    1998-02-20

    A new reactor for biological waste gas treatment was developed to eliminate continuous solvents from waste gases. A trickle-bed reactor was chosen with discontinuous movement of the packed bed and intermittent percolation. The reactor was operated with toluene as the solvent and an optimum average biomass concentration of between 5 and 30 kg dry cell weight per cubic meter packed bed (m3pb). This biomass concentration resulted in a high volumetric degradation rate. Reduction of surplus biomass by stirring and trickling caused a prolonged service life and prevented clogging of the trickle bed and a pressure drop increase. The pressure drop after biomass reduction was almost identical to the theoretical pressure drop as calculated for the irregular packed bed without biomass. The reduction in biomass and intermittent percolation of mineral medium resulted in high volumetric degradation rates of about 100 g of toluene m-3pb h-1 at a load of 150 g of toluene m-3pb h-1. Such a removal rate with a trickle-bed reactor was not reported before.

  2. Bioconversion of Waste Gases into Biofuel via Fermentation in a Continuous Stirred Tank Bioreactor

    Najafpour, G.

    2005-01-01

    Full Text Available Biological hydrogen production was carried out in a continuous stirred tank bioreactor. A photosynthetic bacterium, Rhodospirillum rubrum, was used as biocatalyst to oxidize carbon monoxides in the waste gas generated from biomass in a gasification process. The fresh liquid media was supplied for microbial growth which contained sodium acetate as carbon source at initial concentration of 4 gL-1. The optimum media space velocity or the suitable ratio of liquid flow rate to the reactor volume (F/VL was 0.02 h-1. At the steady state condition, the concentration of acetate was independent of the dilution rate and it was approximately 1.5 gL-1. The average cell dry weight in the fermentation broth was at satisfactory concentration, approximately 3.4 gL-1 with dilution rate at 0.55 mL min-1. The maximum value of KLa and CO conversion were about 58 h-1 and 80%, respectively, with agitation speed at 500 rpm and gas flow rate at 14 mL min-1. At this condition, the maximum yield of hydrogen production was 0.82 mmol H2•mmol-1 CO.

  3. Control of the sulfide (S2-) concentration for optimal zinc removal by sulfide precipitation in a continuously stirred tank reactor

    Veeken, A.H.M.; Akoto, L.; Pol, L.W.H.; Weijma, J.

    2003-01-01

    Precipitation of Zn2+ with S2− was studied at room temperature in a continuously stirred tank reactor of 0.5 l to which solutions of ZnSO4 (800–5800 mg Zn2+/l) and Na2S were supplied. The pH was controlled at 6.5 and S2− concentration in the reactor was controlled at set point values ranging from 3.

  4. The Reduced Rank of Ensemble Kalman Filter to Estimate the Temperature of Non Isothermal Continue Stirred Tank Reactor

    Erna Apriliani; Dieky Adzkiya; Arief Baihaqi

    2011-01-01

    Kalman filter is an algorithm to estimate the state variable of dynamical stochastic system. The square root ensemble Kalman filter is an modification of Kalman filter. The square root ensemble Kalman filter is proposed to keep the computational stability and reduce the computational time. In this paper we study the efficiency of the reduced rank ensemble Kalman filter. We apply this algorithm to the non isothermal continue stirred tank reactor problem. We decompose the covariance of the ense...

  5. Dynamical Analysis of a Continuous Stirred-Tank Reactor with the Formation of Biofilms for Wastewater Treatment

    Karen López Buriticá

    2015-01-01

    Full Text Available This paper analyzes the dynamics of a system that models the formation of biofilms in a continuous stirred-tank reactor (CSTR when it is utilized for wastewater treatment. The growth rate of the microorganisms is modeled using two different kinetics, Monod and Haldane kinetics, with the goal of studying the influence of each in the system. The equilibrium points are identified through a stability analysis, and the bifurcations found are characterized.

  6. The nonequilibrium electromotive force. II. Theory for a continuously stirred tank reactor

    Keizer, Joel

    1987-10-01

    In previous work [J. Keizer, J. Chem. Phys. 82, 2751 (1985)] we used statistical nonequilibrium thermodynamics to predict a non-Nernstian component to the electromotive force (EMF) for half-reactions involving reactants at nonequilibrium steady states. In this paper we present a simple theory for calculating the nonequilibrium component of the EMF based on the elementary transport processes occurring in a continuously stirred tank reactor (CSTR). The calculations utilize the density-density correlation function, which is obtained from the statistical theory of nonequilibrium thermodynamics. This gives rise to an expression for the second partial derivatives of the generalized entropy, or sigma function, which is used to calculate generalized chemical potentials. The generalized chemical potentials are related to the EMF through a generalization of the Nernst equation. The calculations presented here depend on the residence time in the CSTR, reaction rate constants, feed line concentrations in the CSTR, and the diffusion constants of reactants and products. A characteristic diffusion length is used to represent the length scale below which turbulent mixing effects are not important. Calculations with the theory are carried out for several different reaction mechanisms, including A+B⇄C; A+B⇄C, D+E⇄B; A+B⇄2B; and A+B→C+D, A+D→C+E. Values of the nonequilibrium EMF depend on the mechanism as well as all of the transport parameters cited above. For a plausible choice of the diffusion length, corrections to the Nernst formula can be as large as 10-15 mV. Specific calculations for the reaction of Fe2+ with S2O2-8 are shown in the preceding paper to agree with experimental measurements on this system in a CSTR.

  7. Biodegradation of Fresh vs. Oven-Dried Inedible Crop Residue in a Continuously Stirred Tank Reactor

    Crawford, Kamau; Strayer, Richard

    1998-01-01

    The degradation of soluble organics and mineral recovery from fresh and oven-dried biomass were compared in an Intermediate-Scale Aerobic Bioreactor (8 L working volume) to determine if drying crop residue improves performance in a continuously stirred tank reactor (CSTR). The study was conducted in an Intermediate-Scale Aerobic Bioreactor (ISAB) CSTR with dimensions of 390 mm height x 204 mm diameter. The pH in the bioreactor was controlled at 6.0, temperature at 30 C, and aeration at 7.0 L/min. Gases monitored were CO2 evolution and dissolved oxygen. Homogeneously mixed wheat cultures, used either fresh or oven-dried biomass and were leached, then placed in the ISAB for a 4-day degradation period. Studies found that mineral recovery was greater for leached oven-dried crop residue. However, after activity by the mixed microbial communities in the ISAB CSTR, there were little notable differences in the measured mineral recovery and degradation of soluble organic compounds. Degradation of soluble organic compounds was also shown to improve for leached oven-dried crop residue, but after mixing in the CSTR the degradation of the fresh biomass seemed to be slightly greater. Time for the biomass to turn in the CSTR appeared to be one factor for the experimental differences between the fresh and oven-dried biomass. Other factors, although not as defined, were the differing physical structures in the cell walls and varying microbial components of the fresh and oven-dried treatments due to changes in chemical composition after drying of the biomass.

  8. Production of hydrogen in a granular sludge-based anaerobic continuous stirred tank reactor

    Show, Kuan-Yeow [Faculty of Engineering and Science, University of Tunku Abdul Rahman, 53300 Setapak, Kuala Lumpur (Malaysia); Zhang, Zhen-Peng; Tay, Joo-Hwa [School of Civil and Environmental Engineering, Nanyang Technological University, 639798 (Singapore); Institute of Environmental Science and Engineering, Nanyang Technological University, 637723 (Singapore); Tee Liang, David [Institute of Environmental Science and Engineering, Nanyang Technological University, 637723 (Singapore); Lee, Duu-Jong [Department of Chemical Engineering, National Taiwan University, Taipei 10617, Taiwan, RO (China); Jiang, Wen-Ju [Department of Environmental Science and Engineering, Sichuan University, Chengdu 610065 (China)

    2007-12-15

    An investigation on biohydrogen production was conducted in a granular sludge-based continuous stirred tank reactor (CSTR). The reactor performance was assessed at five different glucose concentrations of 2.5, 5, 10, 20 and 40 g/L and four hydraulic retention times (HRTs) of 0.25, 0.5, 1 and 2 h, resulting in the organic loading rates (OLRs) ranged between 2.5 and 20 g-glucose/L h. Carbon flow was traced by analyzing the composition of gaseous and soluble metabolites as well as the cell yield. Butyrate, acetate and ethanol were found to be the major soluble metabolite products in the biochemical synthesis of hydrogen. Carbon balance analysis showed that more than half of the glucose carbon was converted into unidentified soluble products at an OLR of 2.5 g-glucose/L h. It was found that high hydrogen yields corresponded to a sludge loading rate in between 0.6 and 0.8 g-glucose/g-VSS h. Substantial suppression in hydrogen yield was noted as the sludge loading rate fell beyond the optimum range. It is deduced that decreasing the sludge loading rate induced the metabolic shift of biochemical reactions at an OLR of 2.5 g-glucose/L h, which resulted in a substantial reduction in hydrogen yield to 0.36-0.41 mol-H{sub 2}/mol-glucose. Optimal operation conditions for peak hydrogen yield (1.84 mol-H{sub 2}/mol-glucose) and hydrogen production rate (3.26 L/L h) were achieved at an OLR of 20 g-glucose/L h, which corresponded to an HRT of 0.5 h and an influent glucose concentration of 10 g/L. Influence of HRT and substrate concentration on the reactor performance was interrelated and the adverse impact on hydrogen production was noted as substrate concentration was higher than 20 g/L or HRT was shorter than 0.5 h. The experimental study indicated that a higher OLR derived from appropriate HRTs and substrate concentrations was desirable for hydrogen production in such a granule-based CSTR. (author)

  9. Extended continuous-flow stirred-tank reactor (ECSTR) as a simple model of life under thermodynamically open conditions

    Takinoue, Masahiro; Ma, Yue; Mori, Yoshihito; Yoshikawa, Kenichi

    2009-07-01

    A continuous-flow stirred-tank reactor (CSTR) is a vital tool for investigating the nonlinear dynamics of chemical systems. This report proposes an extended CSTR (ECSTR) inspired by active and passive transports through a closed membrane in living systems. In addition to the externally-controlled flow in a conventional CSTR, we introduce passive diffusion through a membrane into the ECSTR. This extension allows us to control the chemical dynamics with a larger parameter-dimension. Numerical analyses show that the ECSTR can expand an oscillatory region in the parameter space and can convert a non-oscillatory chemical system to an oscillatory system.

  10. Cascade degradation of organic matters in brewery wastewater using a continuous stirred microbial electrochemical reactor and analysis of microbial communities

    Wang, Haiman; Qu, Youpeng; Li, Da; Ambuchi, John J.; He, Weihua; Zhou, Xiangtong; Liu, Jia; Feng, Yujie

    2016-01-01

    A continuous stirred microbial electrochemical reactor (CSMER), comprising of a complete mixing zone (CMZ) and microbial electrochemical zone (MEZ), was used for brewery wastewater treatment. The system realized 75.4 ± 5.7% of TCOD and 64.9 ± 4.9% of TSS when fed with brewery wastewater concomitantly achieving an average maximum power density of 304 ± 31 m W m−2. Cascade utilization of organic matters made the CSMER remove a wider range of substrates compared with a continuous stirred tank reactor (CSTR), in which process 79.1 ± 5.6% of soluble protein and 86.6 ± 2.2% of soluble carbohydrates were degraded by anaerobic digestion in the CMZ and short-chain volatile fatty acids were further decomposed and generated current in the MEZ. Co-existence of fermentative bacteria (Clostridium and Bacteroides, 19.7% and 5.0%), acetogenic bacteria (Syntrophobacter, 20.8%), methanogenic archaea (Methanosaeta and Methanobacterium, 40.3% and 38.4%) and exoelectrogens (Geobacter, 12.4%) as well as a clear spatial distribution and syntrophic interaction among them contributed to the cascade degradation process in CSMER. The CSMER shows great promise for practical wastewater treatment application due to high pre-hydrolysis and acidification rate, high energy recovery and low capital cost. PMID:27270788

  11. Cascade degradation of organic matters in brewery wastewater using a continuous stirred microbial electrochemical reactor and analysis of microbial communities.

    Wang, Haiman; Qu, Youpeng; Li, Da; Ambuchi, John J; He, Weihua; Zhou, Xiangtong; Liu, Jia; Feng, Yujie

    2016-06-07

    A continuous stirred microbial electrochemical reactor (CSMER), comprising of a complete mixing zone (CMZ) and microbial electrochemical zone (MEZ), was used for brewery wastewater treatment. The system realized 75.4 ± 5.7% of TCOD and 64.9 ± 4.9% of TSS when fed with brewery wastewater concomitantly achieving an average maximum power density of 304 ± 31 m W m(-2). Cascade utilization of organic matters made the CSMER remove a wider range of substrates compared with a continuous stirred tank reactor (CSTR), in which process 79.1 ± 5.6% of soluble protein and 86.6 ± 2.2% of soluble carbohydrates were degraded by anaerobic digestion in the CMZ and short-chain volatile fatty acids were further decomposed and generated current in the MEZ. Co-existence of fermentative bacteria (Clostridium and Bacteroides, 19.7% and 5.0%), acetogenic bacteria (Syntrophobacter, 20.8%), methanogenic archaea (Methanosaeta and Methanobacterium, 40.3% and 38.4%) and exoelectrogens (Geobacter, 12.4%) as well as a clear spatial distribution and syntrophic interaction among them contributed to the cascade degradation process in CSMER. The CSMER shows great promise for practical wastewater treatment application due to high pre-hydrolysis and acidification rate, high energy recovery and low capital cost.

  12. Evaluation of mass-transfer and kinetic parameters for Rhodospirillum rubrum in a continuous stirred tank reactor

    Klasson, K.T. (Oak Ridge National Lab., TN (United States)); Gupta, A.; Clausen, E.C.; Gaddy, J.L. (Univ. of Arkansas, Fayetteville, AR (United States))

    The photosynthetic bacterium Rhodospirillum rubrum has been evaluated for its ability to produce hydrogen from carbon monoxide and water in a continuous stirred tank reactor according to the water-gas shift reaction. An assessment of mass-transfer parameters and reaction kinetics was made for this sparingly soluble substrate system. Experiments were conducted in a nonsteady-state fashion with continuous liquid and gas flow, which allowed for separation of the mass-transfer and kinetic-limited regions. Based on the data obtained, mass-transfer coefficients for the system were determined, and a mathematical expression for the reaction kinetics was formulated. The results showed that the hydrogen production was inhibited by elevated levels of dissolved carbon monoxide in the liquid. 8 refs., 4 figs., 1 tab.

  13. Linear and Non-linear Multi-Input Multi-Output Model Predictive Control of Continuous Stirred Tank Reactor

    Muayad Al-Qaisy

    2013-04-01

    Full Text Available In this article, multi-input multi-output (MIMO linear model predictive controller (LMPC based on state space model and nonlinear model predictive controller based on neural network (NNMPC are applied on a continuous stirred tank reactor (CSTR. The idea is to have a good control system that will be able to give optimal performance, reject high load disturbance, and track set point change. In order to study the performance of the two model predictive controllers, MIMO Proportional-Integral-Derivative controller (PID strategy is used as benchmark. The LMPC, NNMPC, and PID strategies are used for controlling the residual concentration (CA and reactor temperature (T. NNMPC control shows a superior performance over the LMPC and PID controllers by presenting a smaller overshoot and shorter settling time.

  14. Optimal conditions and operational parameters for conversion of Robusta coffee residues in a continuous stirred tank reactor

    Msambichaka, B.L.; Kivaisi, A.K.; Rubindamayugi, M.S.T. [Univ. of Dar es Salaam, Applied Microbiology Unit (Tanzania, United Republic of)

    1997-12-31

    This experiment studied the possibility of optimizing anaerobic degradation, developing microbial adaptation and establishing long term process stability in a Continuous Stirred Tank Reactor (CSTR) running on Robusta coffee hulls as feed substrate. Decrease in lag phase and increase in methane production rate in batch culture experiment conducted before and after process stabilization of each operational phase in the CSTR clearly suggested that microbial adaptation to increasing coffee percentage composition was attained. Through gradual increase of coffee percentage composition, from 10% coffee, 2% VS, 20 days HRT and a 1 g VS/1/day loading rate to 80% coffee, 4.5% VS, 12 days HRT and a loading rate of 3 g VS/1/day the CSTR system was optimized at a maximum methane yield of 535 ml/g VS. Again it was possible to attain long term process stability at the above mentioned optimal operational parameters for a further 3 month period. (au)

  15. Stochastic resonance in the presence or absence of external signal in the continuous stirred tank reactor system

    Hou, Zhonghuai; Xin, Houwen

    1999-07-01

    A two variable model, which has been proposed to describe a first-order, exothermic, irreversible reaction A→B carried out in a continuous stirred tank reactor (CSTR), is investigated when the control parameter is modulated by random and/or periodic forces. Within the bistable region where a limit cycle and a stable node coexist, stochastic resonance (SR) is observed when both random and periodic modulations are present. In the absence of periodic external signal noise induced coherent oscillations (NICO) appear when the control parameter is randomly modulated near the supercritical Hopf bifurcation point. In addition, the NICO-strength goes through a maximum with the increment of the noise intensity, characteristic for the occurrence of internal signal stochastic resonance (ISSR).

  16. COMPUTER SIMULATION OF CONTINUOUS ELECTROMAGNETIC STIRRING FOR MAKING RHEOLOGIC SEMI-SOLID SLURRY OF ZL112Y ALUMINUM ALLOY

    2008-01-01

    To realize the technology of fabricating the rheologic semi-solid slurry of ZL112Y aluminum alloy via continues electromagnetic stirring process, ANSYS software was used to simulate electromagnetic force field and fluid velocity field in the alloy melt in a crucible tube in three coils. In the first section of the paper, eletromagnetic force field and fluid velocity field caused by single coil were simulated. The result of this simulation gives an average velocity of 3.2 cm/s and it is called critical velocity because a fluid velocity over it will cause a fine and spherical structure of solid primary a in a semi-solid melt. And, from this result, a reasonable temperature of semi-solid of the alloy and an electrical current intensity were established. The electrical current intensity of the result of this simulation corresponded to the current intensity used in a practice experiment, in which the primary a was obviously refined and sphericized. Based on this simulation of single coil electromagnetic stirring, in the second section of the paper, eletromagnetic force field and fluid velocity field caused by three coils were simulated. The result of the simulation shows that, 1) there is a semi-solid zone of 32 mm from bottom of the crucible tube to the upper; 2) the electrical current intensities of three coils of 400 A, 600 A, and 400 A, which were set to top range, middle range and bottom range of the tube, respectively, were the optimum parameters of electromagnetic current intensity under the condition of this investigation; and 3) under effect of these electromagnetic current intensity, the fluid velocities of the melt in the tube were 6.3 cm/s in top range, 3.75 cm/s in middle range, and 3.9 cm/s in bottom range of it, respectively.

  17. Biohydrogen production in a continuous stirred tank bioreactor from synthesis gas by anaerobic photosynthetic bacterium: Rhodopirillum rubrum.

    Younesi, Habibollah; Najafpour, Ghasem; Ku Ismail, Ku Syahidah; Mohamed, Abdul Rahman; Kamaruddin, Azlina Harun

    2008-05-01

    Hydrogen may be considered a potential fuel for the future since it is carbon-free and oxidized to water as a combustion product. Bioconversion of synthesis gas (syngas) to hydrogen was demonstrated in continuous stirred tank bioreactor (CSTBR) utilizing acetate as a carbon source. An anaerobic photosynthetic bacterium, Rhodospirillum rubrum catalyzed water-gas shift reaction which was applied for the bioconversion of syngas to hydrogen. The continuous fermentation of syngas in the bioreactor was continuously operated at various gas flow rates and agitation speeds, for the period of two months. The gas flow rates were varied from 5 to 14 ml/min. The agitation speeds were increasingly altered in the range of 150-500 rpm. The pH and temperature of the bioreactor was set at 6.5 and 30 degrees C. The liquid flow rate was kept constant at 0.65 ml/min for the duration of 60 days. The inlet acetate concentration was fed at 4 g/l into the bioreactor. The hydrogen production rate and yield were 16+/-1.1 mmol g(-1)cell h(-1) and 87+/-2.4% at fixed agitation speed of 500 rpm and syngas flow rate of 14 ml/min, respectively. The mass transfer coefficient (KLa) at this condition was approximately 72.8h(-1). This new approach, using a biocatalyst was considered as an alternative method of conventional Fischer-Tropsch synthetic reactions, which were able to convert syngas into hydrogen.

  18. Molecular weight​/branching distribution modeling of low-​density-​polyethylene accounting for topological scission and combination termination in continuous stirred tank reactor

    Yaghini, N.; Iedema, P.D.

    2014-01-01

    We present a comprehensive model to predict the molecular weight distribution (MWD),(1) and branching distribution of low-density polyethylene (IdPE),(2) for free radical polymerization system in a continuous stirred tank reactor (CSTR).(3) The model accounts for branching, by branching moment or ps

  19. The catalytic hydrogenation of 2,4-dinitrotoluene in a continuous stirred three-phase slurry reactor with an evaporting solvent

    Westerterp, K.R.; Janssen, H.J.; Kwast, van der H.J.

    1992-01-01

    An experimental study of the catalytic hydorgenation of 2,4-dinitrotoluene (DNT) in a mini-installation with a continuously operated stirred three-phase slurry reactor and an evaporating solvent is discussed. Some characteristic properties of the reactor system and the influence of the operating par

  20. Effects of casting speed on microstructure and segregation of electromagnetically stirred Aluminum alloy in continuous casting process

    LEE Dock-Young; KANG Suk-Won; CHO Duck-Ho; KIM Ki-Bae

    2006-01-01

    Recently, a semi-solid metal processing has been acknowledged as a cost-effective technique to be able to manufacture high quality product for the transportation industry.In this study a hypo-eutectic Al alloy was fabricated by means of an electromagnetic stirrer in continuous casting process and the microstructural change during solidification due to a fluid flow by electromagnetic stirring was examined.Due to the forced fluid flow during solidification a dendritic phase of primary α phase of Al alloy was turned into a globular phase, which can make the Al alloy get a thixotropic behavior in the semi-solid region.In order to establish the quantitative relationship between microstructure and the process parameters, the morphology shape, a silicon distribution and a size of primary α phase were observed according to casting speed in continuous casting machine.The primary α phase was turned into the degenerate dendrites approaching a spherical configuration with increasing casting speed.The fine-grained and equiaxed microstructure appeared at higher casting speed.A segregation behavior of Si element was declined with increasing casting speed and a very uniform distribution of Si element was observed on the billet at a casting speed of 600 mm·min-1.A thickness of the solidifying shell of the billet was shortened with increasing the casting speed.

  1. Production of biohythane from food waste via an integrated system of continuously stirred tank and anaerobic fixed bed reactors.

    Yeshanew, Martha M; Frunzo, Luigi; Pirozzi, Francesco; Lens, Piet N L; Esposito, Giovanni

    2016-11-01

    The continuous production of biohythane (mixture of biohydrogen and methane) from food waste using an integrated system of a continuously stirred tank reactor (CSTR) and anaerobic fixed bed reactor (AFBR) was carried out in this study. The system performance was evaluated for an operation period of 200days, by stepwise shortening the hydraulic retention time (HRT). An increasing trend of biohydrogen in the CSTR and methane production rate in the AFBR was observed regardless of the HRT shortening. The highest biohydrogen yield in the CSTR and methane yield in the AFBR were 115.2 (±5.3)L H2/kgVSadded and 334.7 (±18.6)L CH4/kgCODadded, respectively. The AFBR presented a stable operation and excellent performance, indicated by the increased methane production rate at each shortened HRT. Besides, recirculation of the AFBR effluent to the CSTR was effective in providing alkalinity, maintaining the pH in optimal ranges (5.0-5.3) for the hydrogen producing bacteria.

  2. Batch and continuous production of stable dense suspensions of drug nanoparticles in a wet stirred media mill

    Afolabi, Afola we mi

    One way to improve the bioavailability of poorly water-soluble drugs is to reduce particle size of drug crystals down to nanoscale via wet stirred media milling. An increase in total surface area per mass loading of the drug and specific surface area as well as reduced external mass transfer resistance allow a faster dissolution of the poorly-water soluble drug from nanocrystals. To prevent aggregation of nanoparticles, polymers and surfactants are dissolved in water acting as stabilizers via adsorption onto the drug crystals. In the last two decades, ample experimental data were generated in the area of wet stirred media milling for the production of drug nanoparticle suspensions. However, a fundamental scientific/engineering understanding of various aspects of this process is still lacking. These challenges include elucidation of the governing mechanism(s) during nanoparticle formation and physical stabilization of the nanosuspension with the use of polymers and surfactants (formulation parameters), understanding the impact of process parameters in the context of first-principle-based models, and production of truly nanosized drug particles (10-100 nm) with acceptable physical stability and minimal contamination with the media. Recirculation mode of milling operation, where the drug suspension in a holding tank continuously circulates through the stirred media mill, has been commonly used in lab, pilot, and commercial scales. Although the recirculation is continuous, the recirculation operation mode is overall a batch operation, requiring significant number of batches for a large-volume pharmaceutical product. Hence, development and investigation of a truly continuous process should offer significant advantages. To explain the impact of some of the processing parameters, stress intensity and stress number concepts were widely used in literature, which do not account for the effect of suspension viscosity explicitly. The impact of the processing parameters has not

  3. Stabilization of unstable steady states of a continuous stirred tank bioreactor with predator-prey kinetics.

    Tabiś, Bolesław; Skoneczny, Szymon

    2013-07-20

    Nonlinear properties of a bioreactor with a developed microbiological predator-prey food chain are discussed. The presence of the predator microorganism completely changes the position and stability of the stationary states. A wide range of unstable steady states appears, associated with high amplitude oscillations of the state variables. Without automatic control such a system can only operate in transient states, with the yield undergoing periodic changes following the dynamics of the stable limit cycle. Technologically, this is undesirable. It has been shown that the oscillations can be removed by employing continuous P or PI controllers. Moreover, with a PI-controller, the predator can be eliminated from the system.

  4. Dynamic nonlinear feedback for temperature control of continuous stirred reactor with complex behavior

    Pablo A. López Pérez

    2009-08-01

    Full Text Available The main objective of this work is to present an alternative methodology for the design of a class of integral high order slidingmodecontroller applied to a class of continuous chemical reactor with complex behavior for temperature tracking purposes.The proposed design is based on the differential geometry framework, where the named reaching trajectory contains a highorder sliding mode term in order to diminish chattering. Considering that the proposed technique is model based, an observerbaseduncertainty estimator is coupled, which provides robustness against model uncertainties and noisy measurements.Numerical simulations are performed in order to show the capacities of the proposed controller, which is compared with othernonlinear methodologies.

  5. The Reduced Rank of Ensemble Kalman Filter to Estimate the Temperature of Non Isothermal Continue Stirred Tank Reactor

    Erna Apriliani

    2011-01-01

    Full Text Available Kalman filter is an algorithm to estimate the state variable of dynamical stochastic system. The square root ensemble Kalman filter is an modification of Kalman filter. The square root ensemble Kalman filter is proposed to keep the computational stability and reduce the computational time. In this paper we study the efficiency of the reduced rank ensemble Kalman filter. We apply this algorithm to the non isothermal continue stirred tank reactor problem. We decompose the covariance of the ensemble estimation by using the singular value decomposition (the SVD, and then we reduced the rank of the diagonal matrix of those singular values. We make a simulation by using Matlab program. We took some the number of ensemble such as 100, 200 and 500. We compared the computational time and the accuracy between the square root ensemble Kalman filter and the ensemble Kalman filter. The reduced rank ensemble Kalman filter can’t be applied in this problem because the dimension of state variable is too less.

  6. Application of a continuously stirred tank bioreactor (CSTR) for bioremediation of hydrocarbon-rich industrial wastewater effluents

    Gargouri, Boutheina; Karray, Fatma; Mhiri, Najla; Aloui, Fathi [Laboratoire des Bioprocedes Environnementaux, Pole d' Excellence Regional AUF-LBPE, Centre de Biotechnologie de Sfax, Universite de Sfax, BP 1117, 3018 Sfax (Tunisia); Sayadi, Sami, E-mail: sami.sayadi@cbs.rnrt.tn [Laboratoire des Bioprocedes Environnementaux, Pole d' Excellence Regional AUF-LBPE, Centre de Biotechnologie de Sfax, Universite de Sfax, BP 1117, 3018 Sfax (Tunisia)

    2011-05-15

    A continuously stirred tank bioreactor (CSTR) was used to optimize feasible and reliable bioprocess system in order to treat hydrocarbon-rich industrial wastewaters. A successful bioremediation was developed by an efficient acclimatized microbial consortium. After an experimental period of 225 days, the process was shown to be highly efficient in decontaminating the wastewater. The performance of the bioaugmented reactor was demonstrated by the reduction of COD rates up to 95%. The residual total petroleum hydrocarbon (TPH) decreased from 320 mg TPH l{sup -1} to 8 mg TPH l{sup -1}. Analysis using gas chromatography-mass spectrometry (GC-MS) identified 26 hydrocarbons. The use of the mixed cultures demonstrated high degradation performance for hydrocarbons range n-alkanes (C10-C35). Six microbial isolates from the CSTR were characterized and species identification was confirmed by sequencing the 16S rRNA genes. The partial 16S rRNA gene sequences demonstrated that 5 strains were closely related to Aeromonas punctata (Aeromonas caviae), Bacillus cereus, Ochrobactrum intermedium, Stenotrophomonas maltophilia and Rhodococcus sp. The 6th isolate was affiliated to genera Achromobacter. Besides, the treated wastewater could be considered as non toxic according to the phytotoxicity test since the germination index of Lepidium sativum ranged between 57 and 95%. The treatment provided satisfactory results and presents a feasible technology for the treatment of hydrocarbon-rich wastewater from petrochemical industries and petroleum refineries.

  7. Investigation of hydroxyl radical reactions with o-xylene and m-xylene in a continuous stirred tank reactor

    Gery, M.W.; Fox, D.L.; Kamens, R.M.; Stockburger, L.

    1987-04-01

    The gas-phase reactions of hydroxyl radicals with o-xylene and m-xylene were studied in a continuous stirred tank reactor. Gas and aerosol products accounted for 65-85% of the reacted carbon. Approximately 19 and 13% of the original o-xylene and m-xylene oxidation were estimated to have occurred through methyl hydrogen abstraction by OH, primarily leading to methylbenzyl nitrates and tolualdehydes. The remaining mass reacted through the OH addition pathway forming dimethylphenols, nitrodimethylphenols, nitroxylenes, and stable products resulting from reaction of metastable O/sub 2/-OH adducts. For o-xylene, the ratio of the rate constants for formation of nitroxylenes vs. dimethylphenols was estimated to be 5.9 x 10/sup 4/, while the same value for m-xylene was only about 1.0 x 10/sup 4/. The ratios of the dimethylphenol formation rates to the oxygen addition rates were found to be greater than or equal to 0.15 for o-xylene and 0.27 for m-xylene. 44 references, 3 figures, 4 tables.

  8. Biohydrogen and Bioethanol Production from Biodiesel-Based Glycerol by Enterobacter aerogenes in a Continuous Stir Tank Reactor.

    Jitrwung, Rujira; Yargeau, Viviane

    2015-05-11

    Crude glycerol from the biodiesel manufacturing process is being produced in increasing quantities due to the expanding number of biodiesel plants. It has been previously shown that, in batch mode, semi-anaerobic fermentation of crude glycerol by Enterobacter aerogenes can produce biohydrogen and bioethanol simultaneously. The present study demonstrated the possible scaling-up of this process from small batches performed in small bottles to a 3.6-L continuous stir tank reactor (CSTR). Fresh feed rate, liquid recycling, pH, mixing speed, glycerol concentration, and waste recycling were optimized for biohydrogen and bioethanol production. Results confirmed that E. aerogenes uses small amounts of oxygen under semi-anaerobic conditions for growth before using oxygen from decomposable salts, mainly NH4NO3, under anaerobic condition to produce hydrogen and ethanol. The optimal conditions were determined to be 500 rpm, pH 6.4, 18.5 g/L crude glycerol (15 g/L glycerol) and 33% liquid recycling for a fresh feed rate of 0.44 mL/min. Using these optimized conditions, the process ran at a lower media cost than previous studies, was stable after 7 days without further inoculation and resulted in yields of 0.86 mol H2/mol glycerol and 0.75 mol ethanol/mole glycerol.

  9. Biohydrogen and Bioethanol Production from Biodiesel-Based Glycerol by Enterobacter aerogenes in a Continuous Stir Tank Reactor

    Rujira Jitrwung

    2015-05-01

    Full Text Available Crude glycerol from the biodiesel manufacturing process is being produced in increasing quantities due to the expanding number of biodiesel plants. It has been previously shown that, in batch mode, semi-anaerobic fermentation of crude glycerol by Enterobacter aerogenes can produce biohydrogen and bioethanol simultaneously. The present study demonstrated the possible scaling-up of this process from small batches performed in small bottles to a 3.6-L continuous stir tank reactor (CSTR. Fresh feed rate, liquid recycling, pH, mixing speed, glycerol concentration, and waste recycling were optimized for biohydrogen and bioethanol production. Results confirmed that E. aerogenes uses small amounts of oxygen under semi-anaerobic conditions for growth before using oxygen from decomposable salts, mainly NH4NO3, under anaerobic condition to produce hydrogen and ethanol. The optimal conditions were determined to be 500 rpm, pH 6.4, 18.5 g/L crude glycerol (15 g/L glycerol and 33% liquid recycling for a fresh feed rate of 0.44 mL/min. Using these optimized conditions, the process ran at a lower media cost than previous studies, was stable after 7 days without further inoculation and resulted in yields of 0.86 mol H2/mol glycerol and 0.75 mol ethanol/mole glycerol.

  10. Fermentative hydrogen production from beet sugar factory wastewater treatment in a continuous stirred tank reactor using anaerobic mixed consortia

    Gefu ZHU; Chaoxiang LIU; Jianzheng LI; Nanqi REN; Lin LIU; Xu HUANG

    2013-01-01

    A low pH, ethanol-type fermentation process was evaluated for wastewater treatment and bio-hydrogen production from acidic beet sugar factory wastewater in a continuous stirred tank reactor (CSTR) with an effective volume of 9.6 L by anaerobic mixed cultures in this present study. After inoculating with aerobic activated sludge and operating at organic loading rate (OLR) of 12 kgCOD·m-3·d-1, HRT of 8h, and temperature of 35℃ for 28 days, the CSTR achieved stable ethanol-type fermentation. When OLR was further increased to 18 kgCOD·m-3·d-1, on the 53rd day, ethanol-type fermentation dominant microflora was enhanced. The liquid fermentation products, including volatile fatty acids (VFAs) and ethanol, stabilized at 1493mg·L-1 in the bioreactor. Effluent pH, oxidation-reduction potential (ORP), and alkalinity ranged at 4.1-4.5, -250-(-290) mV, and 230-260mgCaCO3·L-1. The specific hydrogen production rate of anaerobic activated sludge was 0.1 L'gMLVSS-1· d-1 and the COD removal efficiency was 45%. The experimental results showed that the CSTR system had good operation stability and microbial activity, which led to high substrate conversion rate and hydrogen production ability.

  11. Quantifying the Reactive Uptake of OH by Organic Aerosols in aContinuous Flow Stirred Tank Reactor

    Che, Dung L.; Smith, Jared D.; Leone, Stephen R.; Ahmed, Musahid; Wilson, Kevin R.

    2009-03-01

    Here we report a new method for measuring the heterogeneous chemistry of submicron organic aerosol particles using a continuous flow stirred tank reactor. This approach is designed to quantify the real time heterogeneous kinetics, using a relative rate method, under conditions of low oxidant concentration and long reaction times that more closely mimic the real atmosphere. A general analytical expression, which couples the aerosol chemistry with the flow dynamics in the chamber is developed and applied to the heterogeneous oxidation of squalane particles by hydroxyl radicals (OH) in the presence of O2. The particle phase reaction is monitored via photoionization aerosol mass spectrometry and yields a reactive uptake coefficient of 0.51+-0.10, using OH concentrations of 1-7x108 molec cdot cm-3 and reaction times of 1.5+-3 hours. This uptake coefficient is larger than that found for the reaction carried out under high OH concentrations (~;;1x1010 molec cdot cm-3) and short reaction times in a flow tube reactor. This difference suggests that oxidant concentration and reaction time are not interchangeable quantities in reactions of organic aerosols with radicals. In general, this approach provides a new way to examine how the chemical aging of organic particles measured at short reaction times and high oxidant concentrations in flow tubes might differ from the long reaction times and low oxidant levels found in the real atmosphere.

  12. A continuous stirred hydrogen-based polyvinyl chloride membrane biofilm reactor for the treatment of nitrate contaminated drinking water.

    Xia, Siqing; Zhang, YanHao; Zhong, FoHua

    2009-12-01

    A continuous stirred hydrogen-based polyvinyl chloride (PVC) membrane biofilm reactor (MBfR) was investigated to remove nitrate from the drinking water. The reactor was operated over 100 days, and the result showed that the average nitrate denitrification rate of 1.2 g NO(3)(-)-N/m(2) d and the total nitrogen (TN) removal of 95.1% were achieved with the influent nitrate concentration of 50 mg NO(3)(-)-N/L and the hydrogen pressure of 0.05 MPa. Under the same conditions, the average rate of hydrogen utilization by biofilm was 0.031 mg H(2)/cm(2) d, which was sufficient to remove 50 mg NO(3)(-)-N/L from the contaminated water with the effluent nitrate and nitrite concentrations below drinking water limit values. The average hydrogen utilization efficiency was achieved as high as 99.5%. Flux analysis demonstrated that, compared to sulfate reduction, nitrate reduction competed more strongly for hydrogen electron, and obtained more electrons in high influent nitrate loading.

  13. Reuse of drinking water treatment residuals in a continuous stirred tank reactor for phosphate removal from urban wastewater.

    Bai, Leilei; Wang, Changhui; Pei, Yuansheng; Zhao, Jinbo

    2014-01-01

    This work proposed a new approach of reusing drinking water treatment residuals (WTR) in a continuous stirred tank reactor (CSTR) to remove phosphate (P) from urban wastewater. The results revealed that the P removal efficiency of the WTR was more than 94% for urban wastewater, in the condition of initial P concentration (P0) of 10 mg L⁻¹, hydraulic retention time (HRT) of 2 h and WTR dosage (M0) of 10 g L⁻¹. The P mass transfer from the bulk to the solid-liquid interface in the CSTR system increased at lower P0, higher M0 and longer HRT. The P adsorption capacity of WTR from urban wastewater was comparable to that of the 201 × 4 resin and unaffected by ions competition. Moreover, WTR had a limited effect on the metals' (Fe, Al, Zn, Cu, Mn and Ni) concentrations of the urban wastewater. Based on the principle of waste recycling, the reuse of WTR in CSTR is a promising alternative technology for P removal from urban wastewater.

  14. Entropy production in a chemical system involving an autocatalytic reaction in an isothermal, continuous stirred tank reactor

    Yoshida, Nobuo

    1990-02-01

    The rate of entropy production due to chemical reaction is calculated for various combinations of parameter values in the cubic autocatalator model in an isothermal, continuous stirred tank reactor (CSTR) proposed by Gray and Scott and by Escher and Ross. Values of the entropy production averaged over periods of limit cycle oscillations are compared with those in coexistent unstable stationary states. It is found that in ranges of the residence time over which there are limit cycles, the entropy production in coexisting stationary states increases as the residence time is shortened, i.e., as the system is removed farther from thermodynamic equilibrium. The average entropy production over a limit cycle is less than that in the corresponding stationary state over wide ranges of parameter values, but not necessarily for the whole oscillatory region. More specifically, the former inequality always prevails in ranges where the entropy production of stationary states is larger, i.e., the residence time is shorter, but in some cases the inequality is reversed in ranges of lower magnitudes of the entropy production.

  15. Application of a continuously stirred tank bioreactor (CSTR) for bioremediation of hydrocarbon-rich industrial wastewater effluents.

    Gargouri, Boutheina; Karray, Fatma; Mhiri, Najla; Aloui, Fathi; Sayadi, Sami

    2011-05-15

    A continuously stirred tank bioreactor (CSTR) was used to optimize feasible and reliable bioprocess system in order to treat hydrocarbon-rich industrial wastewaters. A successful bioremediation was developed by an efficient acclimatized microbial consortium. After an experimental period of 225 days, the process was shown to be highly efficient in decontaminating the wastewater. The performance of the bioaugmented reactor was demonstrated by the reduction of COD rates up to 95%. The residual total petroleum hydrocarbon (TPH) decreased from 320 mg TPH l(-1) to 8 mg TPH l(-1). Analysis using gas chromatography-mass spectrometry (GC-MS) identified 26 hydrocarbons. The use of the mixed cultures demonstrated high degradation performance for hydrocarbons range n-alkanes (C10-C35). Six microbial isolates from the CSTR were characterized and species identification was confirmed by sequencing the 16S rRNA genes. The partial 16S rRNA gene sequences demonstrated that 5 strains were closely related to Aeromonas punctata (Aeromonas caviae), Bacillus cereus, Ochrobactrum intermedium, Stenotrophomonas maltophilia and Rhodococcus sp. The 6th isolate was affiliated to genera Achromobacter. Besides, the treated wastewater could be considered as non toxic according to the phytotoxicity test since the germination index of Lepidium sativum ranged between 57 and 95%. The treatment provided satisfactory results and presents a feasible technology for the treatment of hydrocarbon-rich wastewater from petrochemical industries and petroleum refineries.

  16. Efficient azo dye decolorization in a continuous stirred tank reactor (CSTR) with built-in bioelectrochemical system.

    Cui, Min-Hua; Cui, Dan; Gao, Lei; Cheng, Hao-Yi; Wang, Ai-Jie

    2016-10-01

    A continuous stirred tank reactor with built-in bioelectrochemical system (CSTR-BES) was developed for azo dye Alizarin Yellow R (AYR) containing wastewater treatment. The decolorization efficiency (DE) of the CSTR-BES was 97.04±0.06% for 7h with sludge concentration of 3000mg/L and initial AYR concentration of 100mg/L, which was superior to that of the sole CSTR mode (open circuit: 54.87±4.34%) and the sole BES mode (without sludge addition: 91.37±0.44%). The effects of sludge concentration and sodium acetate (NaAc) concentration on azo dye decolorization were investigated. The highest DE of CSTR-BES for 4h was 87.66±2.93% with sludge concentration of 12,000mg/L, NaAc concentration of 2000mg/L and initial AYR concentration of 100mg/L. The results in this study indicated that CSTR-BES could be a practical strategy for upgrading conventional anaerobic facilities against refractory wastewater treatment.

  17. Effect of organic loading rate on dark fermentative hydrogen production in the continuous stirred tank reactor and continuous mixed immobilized sludge reactor from waste pastry hydrolysate.

    Han, Wei; Hu, Yunyi; Li, Shiyi; Nie, Qiulin; Zhao, Hongting; Tang, Junhong

    2016-12-01

    Waste pastry (6%, w/v) was hydrolyzed by the produced glucoamylase and protease to obtain the glucose (19.8g/L) and free amino nitrogen (179mg/L) solution. Then, the effect of organic loading rate (OLR) (8-40kgCOD/(m(3)d)) on dark fermentative hydrogen production in the continuous stirred tank reactor (CSTR) and continuous mixed immobilized sludge reactor (CMISR) from waste pastry hydrolysate was investigated and compared. The maximum hydrogen production rate of CSTR (277.76mL/(hL)) and CMISR (320.2mL/(hL)) were achieved at OLR of 24kgCOD/(m(3)d) and 32kgCOD/(m(3)d), respectively. Carbon recovery ranged from 75.2-84.1% in the CSTR and CMISR with the balance assumed to be converted to biomass. One gram waste pastry could produce 0.33g (1.83mmol) glucose which could be further converted to 79.24mL (3.54mmol) hydrogen in the CMISR or 91.66mL (4.09mmol) hydrogen in the CSTR. This is the first study which reports dark fermentative hydrogen production from waste pastry.

  18. A Mathematical model for ethanol production by extractive fermentation in a continuous stirred tank fermentor.

    Kollerup, F; Daugulis, A J

    1985-09-01

    Extractive fermentation is a technique that can be used to reduce the effect of end product inhibition through the use of a water-immiscible phase that removes fermentation products in situ. This has the beneficial effect of not only removing inhibitory products as they are formed (thus keeping reaction rates high) but also has the potential for reducing product recovery costs. We have chosen to examine the ethanol fermentation as a model system for end product inhibition and extractive fermentation and have developed a computer model predicting the productivity enhancement possible with this technique together with other key parameters such as extraction efficiency and residual glucose concentration. The model accommodates variable liquid flowrates entering and leaving the system, since it was found that the aqueous outlet flowrate could be up to 35% lower than the inlet flowrate during extractive fermentation of concentrated glucose feeds due to the continuous removal of ethanol from the fermentation broth by solvent extraction. The model predicts a total ethanol productivity of 82.6 g/L h if a glucose feed of 750 g/L is fermented with a solvent having a distribution coefficient of 0.5 at a solvent dilution rate of 5.0 h(-1). This is more than 10 times higher than for a conventional chemostat fermentation of a 250 g/L glucose feed. The model has furthermore illustrated the possible trade-offs that exist between obtaining a high extraction efficiency and a low residual glucose concentration.

  19. Simultaneous removal of selected oxidized contaminants in groundwater using a continuously stirred hydrogen-based membrane biofilm reactor

    Siqing Xia; Jun Liang; Xiaoyin Xu; Shuang Shen

    2013-01-01

    A laboratory trial was conducted for evaluating the capability of a continuously stirred hydrogen-based membrane biofilm reactor to simultaneously reduce nitrate (NO3--N),sulfate (SO42-),bromate (BrO3-),hexavalent chromium (Cr(Ⅵ)) and parachloronitrobenzene (p-CNB).The reactor contained two bundles of hollow fiber membranes functioning as an autotrophic biofilm carrier and hydrogen pipe as well.On the condition that hydrogen was supplied as electron donor and diffused into water through membrane pores,autohydrogenotrophic bacteria were capable of reducing contaminants to forms with lower toxicity.Reduction occurred within 1 day and removal fluxes for NO3--N,SO42-,BrO3-,Cr(Ⅵ),and p-CNB reached 0.641,2.396,0.008,0.016 and 0.031 g/(day.m2),respectively after 112 days of continuous operation.Except for the fact that sulfate was 37% removed under high surface loading,the other four contaminants were reduced by over 95%.The removal flux comparison between phases varying in surface loading and H2 pressure showed that decreasing surface loading or increasing H2 pressure would promote removal flux.Competition for electrons occurred among the five contaminants.Electron-equivalent flux analysis showed that the amount of utilized hydrogen was mainly controlled by NO2--N and SO42-reduction,which accounted for over 99% of the electron flux altogether.It also indicated the electron acceptor order,showing that nitrate was the most prior electron acceptor while sulfate was the second of the five contaminants.

  20. A laboratory and pilot plant scaled continuous stirred reactor separator for the production of ethanol from sugars, corn grits/starch or biomass streams

    Dale, M.C.; Lei, Shuiwang; Zhou, Chongde

    1995-10-01

    An improved bio-reactor has been developed to allow the high speed, continues, low energy conversion of various substrates to ethanol. The Continuous Stirred Reactor Separator (CSRS) incorporates gas stripping of the ethanol using a recalculating gas stream between cascading stirred reactors in series. We have operated a 4 liter lab scale unit, and built and operated a 24,000 liter pilot scale version of the bioreactor. High rates of fermentation are maintained in the reactor stages using a highly flocculent yeast strain. Ethanol is recovered from the stripping gas using a hydrophobic solvent absorber (isothermal), after which the gas is returned to the bioreactor. Ethanol can then be removed from the solvent to recover a highly concentrated ethanol product. We have applied the lab scale CSRS to sugars (glucose/sucrose), molasses, and raw starch with simultaneous saccharification and fermentation of the starch granules (SSF). The pilot scale CSRS has been operated as a cascade reactor using dextrins as a feed. Operating data from both the lab and pilot scale CSRS are presented. Details of how the system might be applied to cellulosics, with some preliminary data are also given.

  1. Analysis on the Deflection Angle of Columnar Dendrites of Continuous Casting Steel Billets Under the Influence of Mold Electromagnetic Stirring

    Wang, Xincheng; Wang, Shengqian; Zhang, Lifeng; Sridhar, Seetharaman; Conejo, Alberto; Liu, Xuefeng

    2016-11-01

    In the current study, the deflection angle of columnar dendrites on the cross section of steel billets under mold electromagnetic stirring (M-EMS) was observed. A mathematical model was developed to define the effect of M-EMS on fluid flow and then to analyze the relationship between flow velocities and deflection angle. The model was validated using experimental data that was measured with a Tesla meter on magnetic intensity. By coupling the numerical results with the experimental data, it was possible to define a relationship between the velocities of the fluid with the deflection angle of high-carbon steel. The deflection angle of high-carbon steel reached maximum values from 18 to 23 deg for a velocity from 0.35 to 0.40 m/s. The deflection angles of low-carbon steel under different EM parameters were discussed. The deflection angle of low-carbon steel was increased as the magnetic intensity, EM force, and velocity of molten steel increased.

  2. 基于MLD模型的CSTR建模和控制%Modeling and Control of a Continuous Stirred Tank Reactor Based on a Mixed Logical Dynamical Model

    杜静静; 宋春跃; 李平

    2007-01-01

    A novel control strategy for a continuous stirred tank reactor (CSTR) system, which has the typical characteristic of strongly pronounced nonlinearity, multiple operating points, and a wide operating range, is initiated from the point of hybrid systems. The proposed scheme makes full use of the modeling power of mixed logical dynamical (MLD) systems to describe the highly nonlinear dynamics and multiple operating points in a unified framework as a hybrid system, and takes advantage of the good control quality of model predictive control (MPC)to design a controller. Thus, this approach avoids oscillation during switching between sub-systems, helps to relieve shaking in transition, and augments the stability robustness of the whole system, and finally achieves optimal (i.e.fast and smooth) transition between operating points. The simulation results demonstrate that the presented approach has a satisfactory performance.

  3. Effect of noise correlation on noise-induced oscillation frequency in the photosensitive Belousov-Zhabotinsky reaction in a continuous stirred tank reactor.

    Simakov, David S A; Pérez-Mercader, Juan

    2013-12-27

    We report on the experimental study of noise-induced oscillations in the photosensitive Ru(bpy)3(2+)-catalyzed Belousov-Zhabotinsky reaction in a continuous stirred tank reactor (CSTR). In the absence of deterministic oscillations and any external periodic forcing, oscillations appear when the system is perturbed by stochastic fluctuations in light irradiation with sufficiently high amplitude in the vicinity of the bifurcation point. The frequency distribution of the noise-induced oscillations is strongly affected by noise correlation. There is a shift of the noise-induced oscillation frequency toward higher frequencies for an intermediate range of the noise correlation exponent, indicating the occurrence of coherence resonance. Our findings indicate that, in principle, noise correlation can be used to direct chemical reactions toward certain behavior.

  4. Coproduction of hydrogen and methane via anaerobic fermentation of cornstalk waste in continuous stirred tank reactor integrated with up-flow anaerobic sludge bed.

    Cheng, Xi-Yu; Li, Qian; Liu, Chun-Zhao

    2012-06-01

    A 10 L continuous stirred tank reactor (CSTR) system was developed for a two-stage hydrogen fermentation process with an integrated alkaline treatment. The maximum hydrogen production rate reached 218.5 mL/L h at a cornstalk concentration of 30 g/L, and the total hydrogen yield and volumetric hydrogen production rate reached 58.0 mL/g-cornstalk and 0.55-0.57 L/L d, respectively. A 10 L up-flow anaerobic sludge bed (UASB) was used for continuous methane fermentation of the effluents obtained from the two-stage hydrogen fermentation. At the optimal organic loading rate of 15.0 g-COD/Ld, the COD removal efficiency and volumetric biogas production rate reached 83.3% and 4.6L/Ld, respectively. Total methane yield reached 200.9 mL/g-cornstalk in anaerobic fermentation with the effluents and alkaline hydrolysate. As a result, the total energy recovery by coproduction of hydrogen and methane with anaerobic fermentation of cornstalk reached 67.1%.

  5. Anaerobic treatment of cassava stillage for hydrogen and methane production in continuously stirred tank reactor (CSTR) under high organic loading rate (OLR)

    Luo, Gang; Xie, Li; Zou, Zhonghai; Wang, Wen; Zhou, Qi [Key Laboratory of Yangtze River Water Environment, Ministry of Education (Tongji University), UNEP-Tongji, Tongji University, Siping Road No. 1239, Shanghai 200092 (China); Shim, Hojae [Department of Civil and Environmental Engineering, Faculty of Science and Technology, University of Macau, Macau SAR 999078 (China)

    2010-11-15

    Anaerobic hydrogen and methane production from cassava stillage in continuously stirred tank reactor (CSTR) were investigated in this study. Results showed that the heat-pretreatment of inoculum did not enhance hydrogen yield compared to raw inoculum under mesophilic condition after continuous operation. However, the hydrogen yield increased from about 14 ml H{sub 2}/gVS under mesophilic condition to 69.6 ml H{sub 2}/gVS under thermophilic condition due to the decrease of propionate concentration and inhibition of homoacetogens. Therefore, temperature was demonstrated to be more important than pretreatment of inoculum to enhance the hydrogen production. Under high organic loading rate (OLR) (>10 gVS/(L.d)), the two-phase thermophilic CSTR for hydrogen and methane production was stable with hydrogen and methane yields of 56.6 mlH{sub 2}/gVS and 249 mlCH{sub 4}/gVS. The one-phase thermophilic CSTR for methane production failed due to the accumulation of both acetate and propionate, leading to the pH lower than 6. Instead of propionate alone, the accumulations of both acetate and propionate were found to be related to the breakdown of methane reactor. (author)

  6. Reactor models for a series of continuous stirred tank reactors with a gas-liquid-solid leaching system: Part I. Surface reaction control

    Papangelakis, V. G.; Demopoulos, G. P.

    1992-12-01

    In this three-part series of articles, comprehensive three-phase steady-state hydrometallurgical reactor models of the continuous stirred tank reactor (CSTR) type are developed and applied to a commercial (pressure oxidation) process. The key features of the developed models are the coupling of both mass and heat balance equations, the description of the nonisothermal performance (autothermal) of a multistage continuous reactor, and the treatment of multimineral feed materials. The model considers only the oxidation reactions, because they mainly affect the thermal balance of the reactor. The stoichiometries and intrinsic kinetics of the heterogeneous leaching reactions, which are established via independent experiments, are the foundation of the developed model. A three-phase (g-l-s) reaction process might be controlled by either surface reaction control, i.e., the rate(s) of the heterogeneous leaching reaction(s), or by gas transfer control, i.e., the rate of transfer of the gaseous reactant into the liquid phase. In the present article (Part I), the case of surface reaction control is treated. The article addresses, in particular, the following topics: (1) it outlines the basic mass and heat balance equations which describe the performance of a multistage leaching reactor; (2) it presents a continuous function to describe the particle size distribution of the feed; and (3) it develops, on the basis of probability theory, number- and mass-particle size density functions which give the size distribution of particle populations reacting according to the surface reaction control-shrinking core model.

  7. Performance comparison of a continuous-flow stirred-tank reactor and an anaerobic sequencing batch reactor for fermentative hydrogen production depending on substrate concentration.

    Kim, S-H; Han, S-K; Shin, H-S

    2005-01-01

    This study was conducted to compare the performance of a continuous-flow stirred-tank reactor (CSTR) and an anaerobic sequencing batch reactor (ASBR) for fermentative hydrogen production at various substrate concentrations. Heat-treated anaerobic sludge was utilized as an inoculum, and hydraulic retention time (HRT) for each reactor was maintained at 12 h. At the influent sucrose concentration of 5 g COD/L, start-up was not successful in both reactors. The CSTR, which was started-up at 10 g COD/L, showed stable hydrogen production at the influent sucrose concentrations of 10-60 g COD/L during 203 days. Hydrogen production was dependent on substrate concentration, resulting in the highest performance at 30 g COD/L. At the lower substrate concentration, the hydrogen yield (based on hexose consumed) decreased with biomass reduction and changes in fermentation products. At the higher substrate concentration, substrate inhibition on biomass growth caused the decrease of carbohydrate degradation and hydrogen yield (based on hexose added). The ASBR showed higher biomass concentration and carbohydrate degradation efficiency than the CSTR, but hydrogen production in the ASBR was less effective than that in the CSTR at all the substrate concentrations.

  8. Hydrolysis-acidogenesis of food waste in solid-liquid-separating continuous stirred tank reactor (SLS-CSTR) for volatile organic acid production.

    Karthikeyan, Obulisamy Parthiba; Selvam, Ammaiyappan; Wong, Jonathan W C

    2016-01-01

    The use of conventional continuous stirred tank reactor (CSTR) can affect the methane (CH4) recovery in a two-stage anaerobic digestion of food waste (FW) due to carbon short circuiting in the hydrolysis-acidogenesis (Hy-Aci) stage. In this research, we have designed and tested a solid-liquid-separating CSTR (SLS-CSTR) for effective Hy-Aci of FW. The working conditions were pH 6 and 9 (SLS-CSTR-1 and -2, respectively); temperature-37°C; agitation-300rpm; and organic loading rate (OLR)-2gVSL(-1)day(-1). The volatile fatty acids (VFA), enzyme activities and bacterial population (by qPCR) were determined as test parameters. Results showed that the Hy-Aci of FW at pH 9 produced ∼35% excess VFA as compared to that at pH 6, with acetic and butyric acids as major precursors, which correlated with the high enzyme activities and low lactic acid bacteria. The design provided efficient solid-liquid separation there by improved the organic acid yields from FW.

  9. Determination of Noncovalent Binding Using a Continuous Stirred Tank Reactor as a Flow Injection Device Coupled to Electrospray Ionization Mass Spectrometry

    Santos, Inês C.; Waybright, Veronica B.; Fan, Hui; Ramirez, Sabra; Mesquita, Raquel B. R.; Rangel, António O. S. S.; Fryčák, Petr; Schug, Kevin A.

    2015-07-01

    Described is a new method based on the concept of controlled band dispersion, achieved by hyphenating flow injection analysis with ESI-MS for noncovalent binding determinations. A continuous stirred tank reactor (CSTR) was used as a FIA device for exponential dilution of an equimolar host-guest solution over time. The data obtained was treated for the noncovalent binding determination using an equimolar binding model. Dissociation constants between vancomycin and Ac-Lys(Ac)-Ala-Ala-OH peptide stereoisomers were determined using both the positive and negative ionization modes. The results obtained for Ac- L-Lys(Ac)- D-Ala- D-Ala (a model for a Gram-positive bacterial cell wall) binding were in reasonable agreement with literature values made by other mass spectrometry binding determination techniques. Also, the developed method allowed the determination of dissociation constants for vancomycin with Ac- L-Lys(Ac)- D-Ala- L-Ala, Ac- L-Lys(Ac)- L-Ala- D-Ala, and Ac- L-Lys(Ac)- L-Ala- L-Ala. Although some differences in measured binding affinities were noted using different ionization modes, the results of each determination were generally consistent. Differences are likely attributable to the influence of a pseudo-physiological ammonium acetate buffer solution on the formation of positively- and negatively-charged ionic complexes.

  10. Comparison of bioleaching of heavy metals from municipal sludge using indigenous sulfur and iron-oxidizing microorganisms: continuous stirred tank reactor studies.

    Pathak, Ashish; Kothari, Richa; Dastidar, M G; Sreekrishnan, T R; Kim, Dong J

    2014-01-01

    A comparative study was undertaken using indigenous sulfur-oxidizing microorganisms and iron-oxidizing microorganisms in separate 12 litre continuous stirred tank reactors (CSTRs) for solubilization of heavy metals from anaerobically digested sewage sludge. The CSTRs were operated at hydraulic retention times (HRTs) ranging from 4 to 10 days using sewage sludge feed having near neutral pH. The pH, oxidation-reduction potential (ORP) and solubilization efficiency of metals were found to be highly dependent on HRT and an increase in HRT led to higher solubilization of metals in both the CSTRs. In both the CSTRs, the CSTR operated with sulfur-oxidizing microorganisms at an HRT of 8 days was found to be optimum in solubilizing 58% Cu, 52% Ni, 72% Zn and 43% Cu from the sludge. The nutrient value, nitrogen and phosphorus of bioleached sludge was also conserved (<20% loss) at 8 days HRT. The metals fractionation study conducted using BCR sequential extraction procedure suggested that most of the metals remaining in the bioleached sludge were in the more stable fractions (F3 and F4) and, therefore, can be safely apply as a fertilizer on land.

  11. Bistability in isothermal photochemical systems: The A ⇆ h nu B --> h nu C reaction in a continuous flow stirred tank reactor

    Laplante, J. P.; Lavabre, D.; Micheau, J. C.

    1988-08-01

    In this paper we present a kinetic analysis of the consecutive photoreaction scheme A⇄hνB→hνC assuming the reaction is carried out in a continuous flow stirred tank reactor (CSTR). The reactor is kept at constant temperature and fed with reactant A at a constant flow rate. A numerical analysis of the model's stationary states reveals a range of constraints for which the system possesses multiple steady states. The observed bistability depends strongly on the rate constant of the B→A reaction k2 . It is typically observed when k2 is much larger than the other rate constants. Our numerical calculations also reveal a marked dependency on parameters such as the molar absorptivities and the irradiation intensity I0 . Interestingly, multiple steady states are only observed for intermediate values of I0 . Analytical approximations are obtained for the stationary states in the limit where the end-product C does not absorb light. These approximations are used to clarify the mechanism responsible for the light-induced instability.

  12. Anaerobic co-digestion of chicken manure and corn stover in batch and continuously stirred tank reactor (CSTR).

    Li, Yeqing; Zhang, Ruihong; He, Yanfeng; Zhang, Chenyu; Liu, Xiaoying; Chen, Chang; Liu, Guangqing

    2014-03-01

    Anaerobic co-digestion of chicken manure and corn stover in batch and CSTR were investigated. The batch co-digestion tests were performed at an initial volatile solid (VS) concentration of 3gVS/L, carbon-to-nitrogen (C/N) ratio of 20, and retention time of 30d. The methane yield was determined to be 281±12mL/gVSadded. Continuous reactor was carried out with feeding concentration of 12% total solids and C/N ratio of 20 at organic loading rates (OLRs) of 1-4gVS/L/d. Results showed that at OLR of 4gVS/L/d, stable and preferable methane yield of 223±7mL/gVSadded was found, which was equal to energy yield (EY) of 8.0±0.3MJ/kgVSadded. Post-digestion of digestate gave extra EY of 1.5-2.6MJ/kgVSadded. Pyrolysis of digestate provided additional EY of 6.1MJ/kgVSadded. Pyrolysis can be a promising technique to reduce biogas residues and to produce valuable gas products simultaneously.

  13. Solidification Structure and Macrosegregation of Billet Continuous Casting Process with Dual Electromagnetic Stirrings in Mold and Final Stage of Solidification: A Numerical Study

    Jiang, D.; Zhu, M.

    2016-12-01

    Coupling macroscale heat transfer and fluid flow with microscale grain nucleation and crystal growth, a mixed columnar-equiaxed solidification model was established to study the SWRT82B steel solidification structure and macrosegregation in 160 mm × 160 mm billet continuous casting with dual electromagnetic stirrings in mold and final stage of solidification (M-EMS and F-EMS). In the model, the phases of liquid, columnar, and equiaxed were treated separately and the initial growing equiaxed phase, which could move freely with liquid, was regarded as slurry. To obtain the equiaxed grains nucleation and columnar front evolution, the unit tracking method and the columnar front tracking model were built. The model was validated by magnetic induction intensity of stirrer, billet surface temperature, and carbon segregation. The equiaxed phase evolution and the solute transport with effect of fluid flow and grains transport were described in this article. The results show that the equiaxed phase ratio will not increase obviously with higher current intensity of M-EMS, while the negative segregation near the strand surface becomes more serious. The negative segregation zone near the billet center and the center positive segregation come into being with the effect of equiaxed grains sedimentation and liquid thermosolutal flow. It is also found that the liquid solute transport in the F-EMS zone becomes the main factor with higher current intensity rather than the solidification rate, and therefore, the final billet center segregation decreases first and then turns to rise with the current intensity. The optimal current intensities of M-EMS and F-EMS proposed for SWRT82B billet continuous casting are 200 and 400 A, respectively.

  14. Solidification Structure and Macrosegregation of Billet Continuous Casting Process with Dual Electromagnetic Stirrings in Mold and Final Stage of Solidification: A Numerical Study

    Jiang, D.; Zhu, M.

    2016-08-01

    Coupling macroscale heat transfer and fluid flow with microscale grain nucleation and crystal growth, a mixed columnar-equiaxed solidification model was established to study the SWRT82B steel solidification structure and macrosegregation in 160 mm × 160 mm billet continuous casting with dual electromagnetic stirrings in mold and final stage of solidification (M-EMS and F-EMS). In the model, the phases of liquid, columnar, and equiaxed were treated separately and the initial growing equiaxed phase, which could move freely with liquid, was regarded as slurry. To obtain the equiaxed grains nucleation and columnar front evolution, the unit tracking method and the columnar front tracking model were built. The model was validated by magnetic induction intensity of stirrer, billet surface temperature, and carbon segregation. The equiaxed phase evolution and the solute transport with effect of fluid flow and grains transport were described in this article. The results show that the equiaxed phase ratio will not increase obviously with higher current intensity of M-EMS, while the negative segregation near the strand surface becomes more serious. The negative segregation zone near the billet center and the center positive segregation come into being with the effect of equiaxed grains sedimentation and liquid thermosolutal flow. It is also found that the liquid solute transport in the F-EMS zone becomes the main factor with higher current intensity rather than the solidification rate, and therefore, the final billet center segregation decreases first and then turns to rise with the current intensity. The optimal current intensities of M-EMS and F-EMS proposed for SWRT82B billet continuous casting are 200 and 400 A, respectively.

  15. Coupling of acrylic dyeing wastewater treatment by heterogeneous Fenton oxidation in a continuous stirred tank reactor with biological degradation in a sequential batch reactor.

    Esteves, Bruno M; Rodrigues, Carmen S D; Boaventura, Rui A R; Maldonado-Hódar, F J; Madeira, Luís M

    2016-01-15

    This work deals with the treatment of a recalcitrant effluent, from the dyeing stage of acrylic fibres, by combination of the heterogeneous Fenton's process in a continuous stirred tank reactor (CSTR) with biological degradation in a sequential batch reactor (SBR). Three different catalysts (a commercial Fe/ZSM-5 zeolite and two distinct Fe-containing activated carbons - ACs - prepared by wet impregnation of iron acetate and iron nitrate) were employed on the Fenton's process, and afterwards a parametric study was carried out to determine the effect of the main operating conditions, namely the hydrogen peroxide feed concentration, temperature and contact time. Under the best operating conditions found, using the activated carbon impregnated with iron nitrate, 62.7% of discolouration and 39.9% of total organic carbon (TOC) reduction were achieved, at steady-state. Furthermore, a considerable increase in the effluent's biodegradability was attained (BOD5:COD ratio increased from <0.001 to 0.27 and SOUR - specific oxygen uptake rate - from <0.2 to 11.1 mg O2/(gVSS·h)), alongside a major decrease in its toxicity (from 92.1 to 94.0% of Vibrio fischeri inhibition down to 6.9-9.9%). This allowed the application of the subsequent biological degradation stage. The combination of the two processes provided a treated effluent that clearly complies with the legislated discharge limits. It was also found that the iron leaching from the three catalysts tested was very small in all runs, a crucial factor for the stability and long-term use of such materials.

  16. Performance and microbial communities of a continuous stirred tank anaerobic reactor treating two-phases olive mill solid wastes at low organic loading rates.

    Rincón, B; Raposo, F; Borja, R; Gonzalez, J M; Portillo, M C; Saiz-Jimenez, C

    2006-02-24

    A study of the performance and microbial communities of a continuous stirred tank reactor (CSTR) treating two-phases olive mill solid wastes (OMSW) was carried out at laboratory-scale. The reactor operated at a mesophilic temperature (35 degrees C) and an influent substrate concentration of 162 g total chemical oxygen demand (COD)L(-1) and 126 g volatile solids (VS)L(-1). The data analyzed in this work corresponded to a range of organic loading rates (OLR) of between 0.75 and 3.00 g CODL(-1)d(-1), getting removal efficiencies in the range of 97.0-95.6%. Methane production rate increased from 0.164 to 0.659 L CH(4)L(reactor)(-1)d(-1) when the OLR increased within the tested range. Methane yield coefficients were 0.225 L CH(4)g(-1) COD removed and 0.290 L CH(4)g(-1) VS removed and were virtually independent of the OLR applied. A molecular characterization of the microbial communities involved in the process was also accomplished. Molecular identification of microbial species was performed by PCR amplification of 16S ribosomal RNA genes, denaturing gradient gel electrophoresis (DGGE), cloning and sequencing. Among the predominant microorganisms in the bioreactor, the Firmicutes (mainly represented by Clostridiales) were the most abundant group, followed by the Chloroflexi and the Gamma-Proteobacteria (Pseudomonas species as the major representative). Other bacterial groups detected in the bioreactor were the Actinobacteria, Bacteroidetes and Deferribacteres. Among the Archaea, the methanogen Methanosaeta concilii was the most representative species.

  17. Photocatalytic inactivation of Flavobacterium and E. coli in water by a continuous stirred tank reactor (CSTR) fed with suspended/immobilised TiO2 medium.

    Cohen-Yaniv, Vered; Narkis, Nava; Armon, Robert

    2008-01-01

    A photocatalytic continuous stirred tank reactor (CSTR) was built at laboratory scale to inactivate two environmental bacteria strains (Flavobacterium and E. coli) in tap water. Several parameters were found to impact reactor efficiency. Bacterial initial concentration is an important factor in inactivation rate. After 30 minutes of irradiation at 10(8)-10(9) CFU mL(-1) starting concentration, a >5 log reduction was achieved while at 10(4)-10(6) CFU mL(-1) only a 2 log reduction was observed. Water hardness and pH have an important influence on the photocatalytic inactivation process. Soft water, with low Ca(+2) and Mg(+2) at low pH approximately 5.3 resulted in increased inactivation of Flavobacterium reaching >6 orders of magnitude reduction. E. coli and Flavobacterium at pH 5 were inactivated by 3 logs more as compared to pH 7 under similar conditions. pH below TiO2 isoelectric point (approximately 5.6) supports better contact between bacteria and anatase particles resulting in superior inactivation. TiO2 powder suspension was compared with immobilised powder in sol-gel coated glass beads in order to exclude the need for particles separation from the treated water. TiO2 suspension was more effective by 3 orders of magnitude when compared to coated glass beads. An interesting observation was found between the two bacterial strains based on their hydrophobicity/hydrophilicity balance. The more hydrophobic Flavobacterium compared to E. coli was inactivated photocatalytically by >3 logs more then E. coli in the first 30 minutes of irradiation interval. The results indicate the importance of the parameters involved in the contact between TiO2 particles and microorganisms that govern the successful inactivation rate in CSTR.

  18. Application of Mold Electromagnetic Stirring in Billet Continuous Casting Machine%结晶器电磁搅拌装置在方坯连铸机的应用

    于本庆

    2012-01-01

    The electromagnetic stirring system is introduced, including the characteristics of the system, working principle and characteristics of inverter power supply cabinet, application and good results in the 8-strand billet continuous casting machine at the steelmaking plant.%介绍了电磁搅拌器的组成特点、逆变电源柜的工作原理特性及其在北营炼钢厂8机8流方坯连铸机应用取得的成效。

  19. Ultrasonic Stir Welding

    Nabors, Sammy

    2015-01-01

    NASA Marshall Space Flight Center (MSFC) developed Ultrasonic Stir Welding (USW) to join large pieces of very high-strength metals such as titanium and Inconel. USW, a solid-state weld process, improves current thermal stir welding processes by adding high-power ultrasonic (HPU) energy at 20 kHz frequency. The addition of ultrasonic energy significantly reduces axial, frictional, and shear forces; increases travel rates; and reduces wear on the stir rod, which results in extended stir rod life. The USW process decouples the heating, stirring, and forging elements found in the friction stir welding process allowing for independent control of each process element and, ultimately, greater process control and repeatability. Because of the independent control of USW process elements, closed-loop temperature control can be integrated into the system so that a constant weld nugget temperature can be maintained during welding.

  20. Aperiodicity resulting from two-cycle coupling in the Belousov-Zhabotinskii reaction. III. Analysis of a model of the effect of spatial inhomogeneities at the input ports of a continuous-flow, stirred tank reactor

    Györgyi, László; Field, Richard J.

    1989-11-01

    Deterministic chaos is a well-established phenomenon in continuous-flow, stirred tank reactor (CSTR) experiments with the oscillatory Belousov-Zhabotinskii (BZ) reaction. However, it has not yet been possible to reproduce the experimentally observed, robust chaos in simulations using realistic models of the homogeneous chemical kinetics of the BZ reaction. That it may be necessary to consider spatial inhomogeneities in modeling the BZ chaos is suggested by the existence of strong stirring effects on the aperiodic behavior and by the difficulty of reproducing chaos under the same conditions in reactors of different physical configuration. Such inhomogeneity might result from a lack of perfect mixing in the CSTR, especially near the inlets, or from diffusion of species at low flow rates from the CSTR reaction mixture into the tips of the inlets. The presence of spatial inhomogeneities allows coupling between essentially independent oscillators, a well-known source of chaos. Such a model using a realistic representation of the BZ kinetics leads to an eight-variable set of ordinary differential equations. Numerical analysis of these equations by continuation methods and by numerical integration shows the existence of broad regions of chaos and various hysteresis effects involving limit cycles, a steady state and/or a strange attractor. Tristability was found in calculations in a narrow flow rate range. The computed behavior appears for parameter values closely related to the values used experimentally to obtain similar phenomena, and the visual similarity of the computed and experimental strange attractors is striking. The experimental routes to chaos, period doubling, intermittency, and secondary Hopf bifurcations are all reproduced in the simulations. The computed and experimental structures of periodic windows observed within chaotic regions also are very similar.

  1. Effects of nitrobenzene concentration and hydraulic retention time on the treatment of nitrobenzene in sequential anaerobic baffled reactor (ABR)/continuously stirred tank reactor (CSTR) system.

    Kuscu, Ozlem Selcuk; Sponza, Delia Teresa

    2009-04-01

    The effects of increasing nitrobenzene (NB) concentrations and hydraulic retention times (HRT) on the treatment of NB were investigated in a sequential anaerobic baffled reactor (ABR)/aerobic completely stirred tank reactor (CSTR) system. In the first step of the study, the maximum COD removal efficiencies were found as 88% and 92% at NB concentrations varying between 30 mg L(-1) and 210 mg L(-1) in ABR. The minimum COD removal efficiency was 79% at a NB concentration of 700 mg L(-1). The removal efficiency of NB was nearly 100% for all NB concentrations in the ABR reactor. The methane gas production and the methane gas percentage remained stable (1500 mL day(-1) and 48-50%, respectively) as the NB concentration was increased from 30 to 210 mg L(-1). In the second step of the study it was found that as the HRT decreased from 10.38 days to 2.5 days the COD removal efficiencies decreased slightly from 94% to 92% in the ABR. For maximum COD and NB removal efficiencies the optimum HRT was found as 2.5 days in the ABR. The total COD removal efficiency was 95% in sequential anaerobic (ABR)/aerobic (CSTR) reactor system at a minimum HRT of 1 day. When the HRT was decreased from 10.38 days to 1 day, the methane percentage decreased from 42% to 29% in an ABR reactor treating 100 mg L(-1) NB. Nitrobenzene was reduced to aniline under anaerobic conditions while aniline was mineralized to catechol with meta cleavage under aerobic conditions.

  2. Friction stir welding tool

    Tolle; Charles R. , Clark; Denis E. , Barnes; Timothy A.

    2008-04-15

    A friction stir welding tool is described and which includes a shank portion; a shoulder portion which is releasably engageable with the shank portion; and a pin which is releasably engageable with the shoulder portion.

  3. Modeling of 1,2-Dichloroethane Biodegradation by Xanthobacter autotrophicus GJ10 under Shock Loading of Other Halogenated Compounds in Continuous Stirred Tank Bioreactor

    Beschkov, V.; Sapundzhiev, Ts.; Torz, M.; Wietzes, P.; Janssen, D. B.

    2008-01-01

    A mathematical model describing the behavior of a continuous culture that degrades 1,2-dichloroethane and receives a shock loading of another compound was developed. The model takes into account possible cell death due to toxicity, growth inhibition and additional growth of cells on the second carbo

  4. Tool For Friction Stir Tack Welding of Aluminum Alloys

    Bjorkman, Gerald W.; Dingler, Johnny W.; Loftus, Zachary

    2003-01-01

    A small friction-stir-welding tool has been developed for use in tack welding of aluminum-alloy workpieces. It is necessary to tack-weld the workpieces in order to hold them together during friction stir welding because (1) in operation, a full-size friction-stir-welding tool exerts a large force that tends to separate the workpieces and (2) clamping the workpieces is not sufficient to resist this force. It is possible to tack the pieces together by gas tungsten arc welding, but the process can be awkward and time-consuming and can cause sufficient damage to necessitate rework. Friction stir tack welding does not entail these disadvantages. In addition, friction stir tack welding can be accomplished by use of the same automated equipment (except for the welding tool) used in subsequent full friction stir welding. The tool for friction stir tack welding resembles the tool for full friction stir welding, but has a narrower shoulder and a shorter pin. The shorter pin generates a smaller workpiece-separating force so that clamping suffices to keep the workpieces together. This tool produces a continuous or intermittent partial-penetration tack weld. The tack weld is subsequently consumed by action of the larger tool used in full friction stir welding tool.

  5. Robust L2-L∞ Control for Continuous Stirred Tank Reactor Based on T-S Model%基于T-S模型的连续搅拌反应釜鲁棒L2-L∞控制

    李艳辉; 冯岩

    2014-01-01

    To realize precise control for CSTR( Continuous Stirring Tank Reactor) systems in actual reactions, a robust L2-L∞ state feedback control problem is studied by using a T-S fuzzy model to approximate the nonlinear object according to reaction characteristics of the CSTR. All reactor temperatures which are easier to be measured can be treated as premise variables in the model, where fewer number of fuzzy rules are employed. The design method of partial controllers is given by applying the PDC ( Parallel Distributed Compensation ) algorithm. A global controller is designed by adopting the LMI ( Linear Matrix Inequality ) technique, and the design of controllers is cast into a convex optimization problem. Simulations are provided to demonstrate the effectiveness of the proposed design scheme, which can be applied to other chemical industrial reactions.%为实现对连续搅拌反应釜( CSTR:Continuous Stirring Tank Reactor)系统在实际反应中的精确控制,根据CSTR反应特点,采用T-S模糊模型逼近非线性对象,研究鲁棒L2-L∞状态反馈控制问题。模型中将更易测量的反应器温度作为前件变量,模糊规则少。应用平行分配补偿算法( PDC:Parallel Distributed Compensation),给出局部控制器的设计方法,并利用线性矩阵不等式( LMI:Linear Matrix Inequality)技术设计全局控制器,在此基础上把控制器的设计转化为一个凸优化的求解问题。最后仿真验证了该方法的有效性,从而可扩展到其他化学工业反应中。

  6. Anaerobic co-digestion of cheese whey and the screened liquid fraction of dairy manure in a single continuously stirred tank reactor process: Limits in co-substrate ratios and organic loading rate.

    Rico, Carlos; Muñoz, Noelia; Rico, José Luis

    2015-01-01

    Mesophilic anaerobic co-digestion of cheese whey and the screened liquid fraction of dairy manure was investigated with the aim of determining the treatment limits in terms of the cheese whey fraction in feed and the organic loading rate. The results of a continuous stirred tank reactor that was operated with a hydraulic retention time of 15.6 days showed that the co-digestion process was possible with a cheese whey fraction as high as 85% in the feed. The efficiency of the process was similar within the range of the 15-85% cheese whey fraction. To study the effect of the increasing loading rate, the HRT was progressively shortened with the 65% cheese whey fraction in the feed. The reactor efficiency dropped as the HRT decreased but enabled a stable operation over 8.7 days of HRT. At these operating conditions, a volumetric methane production rate of 1.37 m(3) CH4 m(-3) d(-1) was achieved.

  7. Inactivating effects of lignin-derived compounds released during lignocellulosic biomass pretreatment on the endo-glucanase catalyzed hydrolysis of carboxymethylcellulose: A study in continuous stirred ultrafiltration-membrane reactor.

    Cantarella, Maria; Mucciante, Claudia; Cantarella, Laura

    2014-03-01

    This study focusses on the reversible/irreversible damage that selected phenolic compounds, released during steam-explosion pretreatment, mandatory for cellulose accessibility, causes on both stability and activity of a commercial cellulase (half-life=173h) during carboxymethyl-cellulose hydrolysis. Long-term experiments performed in continuous stirred UF-membrane bioreactors, operating at steady-state regime, in controlled operational conditions, allowed evaluating the inactivation-constant in the phenol presence (kd1) and after its removal (kd2) from the reactor feed. p-Hydroxybenzoic acid (1 and 2g L(-1)) are the extreme limits in the inactivating effect with enzyme half-lives 99.02 and 14.15h, respectively. The inactivation reversibility was assessed for vanillic acid, p-hydroxybenzoic acid, syringaldehyde, p-coumaric acid, being kd1>kd2. p-Hydroxybenzaldehyde and protocatechuic acid irreversibly affected cellulase stability increasing its inactivation with kd2>kd1. p-Hydroxybenzaldehyde, 1g L(-1), syringaldehyde, and vanillin, at 2gL(-1), had similar kd1÷kd2.

  8. Ce-Zr-La/Al2O3 prepared in a continuous stirred-tank reactor: a highly thermostable support for an efficient Rh-based three-way catalyst.

    Wang, Su-Ning; Lan, Li; Hua, Wei-Bo; Shi, Zhong-Hua; Chen, Yao-Qiang; Gong, Mao-Chu; Zhong, Lin

    2015-12-21

    Two Ce-Zr-La/Al2O3 composite oxides, CZLA-C and CZLA-B, were synthesized using a co-precipitation method in a continuous stirred-tank reactor (CSTR) and a batch reactor (BR), respectively. Two Rh-based three-way catalysts (TWCs), Rh/CZLA-C and Rh/CZLA-B were obtained by a wet-impregnation method using the two composites as the supports. The physicochemical properties of the samples before and after thermal treatment at 1000 °C were characterized by N2 adsorption-desorption, X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), H2-temperature programmed reduction (H2-TPR) and CO chemisorption. The results indicated that CZLA-C shows higher thermal stability than CZLA-B due to a sparsely-agglomerated morphology. Compared with Rh/CZLA-B, Rh/CZLA-C displayed better reducibility and higher thermal stability and exhibited significantly higher activity in the catalytic removal of the simulated gasoline vehicle exhaust emission (NO, CO and C3H8). Our work can provide a facile and economical synthesis route to advanced support materials and catalysts for exhaust emission control.

  9. Hinfinity control for continuous stirred tank reactor based on Takagi-Sugeno fuzzy bilinear models%基于Takagi-Sugeno模糊双线性模型的连续搅拌反应釜H∞控制

    陈珺; 刘飞

    2012-01-01

    This paper is concerned with the H-infinity control for a class of continuous stirred tank reactor (CSTR) systems, in which the nonlinear dynamics are described by TakagiSugeno fuzzy bilinear models. By introducing two free matrix variables, we derive a new sufficient condition, in terms of linear matrix inequalities, of the global stability with a prescribed Hinfinity performance level for the closedloop fuzzy bilinear systems. The controller design method is also given. Simulation results of a CSTR system illustrate the effectiveness of the design method.%本文研究了一类连续搅拌反应釜(CSTR)系统的H∞控制问题.系统中的非线性动态特性可采)用Takagi-Sugeno(T-S)模糊双线性模型进行描述.通过引入两个自由矩阵,给出一个新的保证闭环模糊双线性系统在H∞性能指标下全局渐近稳定的充分条件和控制器设计方法,并且该条件最终可归结为求解一组线性矩阵不等式的可行性问题.CSTR系统的仿真结果表明设计方法的有效性.

  10. Reactor models for a series of continuous stirred tank reactors with a gas-liquid-solid leaching system: Part III. Model application

    Papangelakis, V. G.; Demopoulos, G. P.

    1992-12-01

    A mathematical model developed to describe the steady-state performance of a three-phase leaching reactor is applied to the analysis and simulation of an industrial process: the high-temperature (180 °C to 200 °C) aqueous pressure oxidation (O2-H2SO4) of refractory pyrite-arsenopyrite (FeS2-FeAsS) gold concentrates. The simulation work reported here centers on the analysis of the autothermal operation of a continuous multistage horizontal autoclave. The focus is on the performance of the first autoclave compartment, since its autothermal “initialization” determines the rate of the whole process. The analysis of the whole autoclave is subsequently done on a stage-by-stage basis. The model considers both possible reaction control regimes, that is, reactor operation limited by the rate of the particle dissolution reaction (surface reaction control) or limited by the rate of O2 transfer at the g-1 interface (gas-transfer control). The decision whether the reactor operates under surface reaction control or gas transfer control is based on whether the gas-transfer capacity of the reactor can or cannot satisfy the oxygen demands of the leaching reactions. With the aid of the model, the effects of feed rate, feed preheating, cooling with water injection, slurry recycling, and autoclave configuration are critically evaluated from the standpoint of optimum autoclave performance.

  11. Neural network predictive control of continuous stirred-tank reactor based on Hammerstein-Wiener model%基于Hammerstein-Wiener模型的连续搅拌反应釜神经网络预测控制

    满红; 邵诚

    2011-01-01

    针对化工过程中广泛使用的连续搅拌反应釜(CSTR),提出一种基于神经网络的模型预测控制策略,采用分段最小二乘支持向量机辨识Hammerstein-Wiener模型系数的方法,在此基础上建立线性自回归模式(ARX)结构和高斯径向基神经网络串联的非线性预测控制器.利用BP神经网络训练预测控制输入序列和拟牛顿算法求解非线性预测控制律,从而实现一种基于支持向量机Hammerstein-Wiener辨识模型的非线性神经网络预测控制算法.对CSTR的仿真结果表明,该方法能够更有效地跟踪控制反应物浓度.%A model predictive control strategy based on neural network is presented for a continuous stirred tank reactor (CSTR). A segmentation method was adopted to identify Hammerstein-Wiener model coefficient by least squares support vector machines and then to construct a nonlinear predictive controller which was by a linear optimal component and radial basis function neural networks in series. A nonlinear predictive control algorithm based on least support vector machines Hammerstein-Wiener model was realized by using BP neural network to train predictive input sequences and to solve nonlinear predictive control rules by Quasi-Newton method. The simulation results of CSTR illustrate that this approach is effective tracking and controlling product concentration.

  12. Friction Stir Welding

    Nunes, Arthur C., Jr.

    2008-01-01

    Friction stir welding (FSW) is a solid state welding process invented in 1991 at The Welding Institute in the United Kingdom. A weld is made in the FSW process by translating a rotating pin along a weld seam so as to stir the sides of the seam together. FSW avoids deleterious effects inherent in melting and promises to be an important welding process for any industries where welds of optimal quality are demanded. This article provides an introduction to the FSW process. The chief concern is the physical effect of the tool on the weld metal: how weld seam bonding takes place, what kind of weld structure is generated, potential problems, possible defects for example, and implications for process parameters and tool design. Weld properties are determined by structure, and the structure of friction stir welds is determined by the weld metal flow field in the vicinity of the weld tool. Metal flow in the vicinity of the weld tool is explained through a simple kinematic flow model that decomposes the flow field into three basic component flows: a uniform translation, a rotating solid cylinder, and a ring vortex encircling the tool. The flow components, superposed to construct the flow model, can be related to particular aspects of weld process parameters and tool design; they provide a bridge to an understanding of a complex-at-first-glance weld structure. Torques and forces are also discussed. Some simple mathematical models of structural aspects, torques, and forces are included.

  13. Ozone absorption in a mechanically stirred reactor

    LJILJANA TAKIC; VLADA VELJKOVIC; MIODRAG LAZIC; SRDJAN PEJANOVIC

    2007-01-01

    Ozone absorption in water was investigated in a mechanically stirred reactor, using both the semi-batch and continuous mode of operation. A model for the precise determination of the volumetric mass transfer coefficient in open tanks without the necessity of the measurement the ozone concentration in the outlet gas was developed. It was found that slow ozone reactions in the liquid phase, including the decomposition of ozone, can be regarded as one pseudo-first order reaction. Under the exami...

  14. Continuous stirred tank reactor mechanical modelling and opening virtual simulation system development%连续搅拌反应釜机理建模与开放式虚拟仿真系统开发

    邓晓刚; 于佐军

    2016-01-01

    This paper proposes an opening virtual simulation system design method based on the chemical reactor mechanism model.One common chemical reactor referred to as continuous stirred tank reactor (CSTR) is used as the simulation objective.Firstly,its mathematical models are built using the mechanism analysis technique.Then the process flow diagram is constructed by LabVIEW software and the simulation programs are established using the four-order Runge-Kutta method.With the help of shared variable engine (SVE),the simulation data are deployed to OPC server,which leads to good system open performances.Matlab is used to illustrate the calling procedure of sharing data.This system can simulate the CSTR device characteristics well. Also the openness of simulation helps students to design their own control strategy and provides a platform for the innovative experiment.%以一类常见的化学反应器———连续搅拌反应釜(CSTR)为虚拟仿真对象,提出一种基于化学反应器装置机理模型的开放式虚拟仿真系统开发方法。首先,使用机理分析法建立数学模型;然后,在 LabVIEW 软件中构建工艺流程界面,并基于四阶龙格-库塔法编制虚拟仿真程序;进一步,利用共享变量引擎将虚拟装置数据发布到 OPC Server 中,使虚拟系统具有良好的开放性。以 Matlab 软件为例,说明了共享数据的调用过程。该虚拟仿真系统不但能够较好地模拟 CSTR 的工艺特性,而且其数据的开放性有助于学生自行设计控制方案、自主开展创新性实验研究。

  15. Biogas by semi-continuous anaerobic digestion of food waste.

    Zhang, Cunsheng; Su, Haijia; Wang, Zhenbin; Tan, Tianwei; Qin, Peiyong

    2015-04-01

    The semi-continuous anaerobic digestion of food waste was investigated in 1-L and 20-L continuously stirred tank reactors (CSTRs), to identify the optimum operation condition and the methane production of the semi-continuous anaerobic process. Results from a 1-L digester indicated that the optimum organic loading rate (OLR) for semi-continuous digestion is 8 g VS/L/day. The corresponding methane yield and chemical oxygen demand (COD) reduction were 385 mL/g VS and 80.2 %, respectively. Anaerobic digestion was inhibited at high OLRs (12 and 16 g VS/L/day), due to volatile fatty acid (VFA) accumulation. Results from a 20-L digester indicated that a higher methane yield of 423 mL/g VS was obtained at this larger scale. The analysis showed that the methane production at the optimum OLR fitted well with the determined kinetics equation. An obvious decrease on the methane content was observed at the initial of digestion. The increased metabolization of microbes and the activity decrease of methanogen caused by VFA accumulation explained the lower methane content at the initial of digestion.

  16. Stirring by swimming bodies

    Thiffeault, Jean-Luc, E-mail: jeanluc@math.wisc.ed [Department of Mathematics, University of Wisconsin - Madison, 480 Lincoln Dr., Madison, WI 53706 (United States); Institute for Mathematics and Applications, University of Minnesota - Twin Cities, 207 Church Street S.E., Minneapolis, MN 55455 (United States); Childress, Stephen [Courant Institute of Mathematical Sciences, New York University, 251 Mercer Street, New York, NY 10012 (United States)

    2010-07-26

    We consider the stirring of an inviscid fluid caused by the locomotion of bodies through it. The swimmers are approximated by non-interacting cylinders or spheres moving steadily along straight lines. We find the displacement of fluid particles caused by the nearby passage of a swimmer as a function of an impact parameter. We use this to compute the effective diffusion coefficient from the random walk of a fluid particle under the influence of a distribution of swimming bodies. We compare with the results of simulations. For typical sizes, densities and swimming velocities of schools of krill, the effective diffusivity in this model is five times the thermal diffusivity. However, we estimate that viscosity increases this value by two orders of magnitude.

  17. Research on Change Process of Nitrosation Granular Sludge in Continuous Stirred-Tank Reactor%CSTR 中亚硝化颗粒污泥的变化过程研究

    阴方芳; 刘文如; 王建芳; 吴鹏; 沈耀良

    2014-01-01

    在连续全混反应器(CSTR)中接种 SBR 培养成熟的亚硝化颗粒污泥,考察反应器构型对亚硝化颗粒污泥生长和运行的影响特性.结果表明,反应器构型和进水模式变化初期部分颗粒污泥解体,污泥平均沉速下降;但随着反应器的进一步运行, CSTR 中实现了亚硝化絮体污泥的快速颗粒化过程;整个研究过程中,虽颗粒粒径分布存较大变化,如粒径>2.5 mm 颗粒的减少和粒径《0.3 mm 颗粒的增加,但颗粒态污泥始终是 CSTR 中占优势的污泥形态.另外,研究表明反应器构型和进水模式的改变对出水中亚硝酸盐累积率(保持在85%左右)无显著影响,并且新生的小粒径颗粒污泥比大粒径颗粒具有更高的比反应活性,此 CSTR 中污泥的平均活性亦高于接种污泥平均活性.%In order to investigate the effect of different types of reactors on the nitrosation granular sludge, a continuous stirred-tank reactor (CSTR) was studied, using mature nitrosation granular sludge cultivated in sequencing batch reactor (SBR) as seed sludge. Results indicated that the change of reactor type and influent mode could induce part of granules to lose stability with gradual decrease in sludge settling ability during the initial period of operation. However, the flocs in CSTR achieved fast granulation in the following reactor operation. In spite of the changes of particle size distribution, e. g. the decreasing number of granules with diameter larger than 2. 5 mm and the increasing number of granules with diameter smaller than 0. 3 mm, granular sludge held the absolute predominance of sludge morphology in CSTR during the entire experimental period. Moreover, results showed that the change of reactor type and influent mode didn't affect the nitrite accumulation rate which was still kept at about 85% in effluent. Additionally, the average activity of the sludge in CSTR was stronger than that of the seed sludge, because

  18. 微生物燃料电池耦合连续搅拌反应系统(CSTR)低温下处理“糖蜜-电镀”废水%Microbial fuel cell with continuous stirred reactor system (CSTR) for continuous flow Processing of “Molasses-Electroplating”wastewater at low temperatures

    谢静怡; 李永峰; 孙彩玉; 秦必达

    2015-01-01

    为提高传统微生物燃料电池( MFC)在低温条件下的效率,实现实验装置放大化.本实验将连续搅拌反应系统( CSTR)与双极室微生物燃料电池系统相结合,连续流处理糖蜜废水,并间接回收金属单质,处理模拟电镀废水,考察系统的产电性能和废水处理效果.结果表明,当系统稳定运行后,最高电压及功率密度分别可达到340 mV和58.65 mW·m-2.20 d后,系统COD去除率明显增加,最高COD去除率可达到81%.实验运行10 d后,银离子开始析出,最高去除率可达到90%左右.%In order to improve the efficiency of traditional microbial fuel cells ( MFC ) at low temperatures, and scale up the experimental device amplification, this experiment combined a continuous stirred reactor with a two chamber microbial fuel cell to continuously process molasses wastewater and simulated electroplating wastewater, indirectly recovered metals, and investigated electricity production and wastewater treatment effect. The results from the experiment showed that the highest voltage output of 340 mV and the maximum power density of 58. 65 mW·m-2 were obtained under a stable operating condition. In addition,COD removal rate reached its highest value (81%)after 20 d, and the maximum removal rate(90%) for Ag+ was recorded after 10 d.

  19. Stirring and mixing effects on oscillations and inhomogeneities in the minimal bromate oscillator

    Dutt, A. K.; Menzinger, M.

    1999-04-01

    Stirring and mixing effects on the oscillations and inhomogeneities in the bromate-bromide-cerous system (minimal bromate oscillator) have been investigated in a continuously fed stirred tank reactor (CSTR). A movable microelectrode is used to monitor the inhomogeneities inside the CSTR in an oscillating phase. The results are explained in terms of the theory of imperfect mixing.

  20. Phosphorus removal in aerated stirred tank reactor

    Ghigliazza, R.; Lodi, A.; Rovatti, M. [Inst. of Chemical and Process Engineering ``G.B. Bonino``, Univ. of Genoa (Italy)

    1999-03-01

    The possibility to obtain biological phosphorus removal in strictly aerobic conditions has been investigated. Experiments, carried out in a continuous stirred tank reactor (CSTR), show the feasibility to obtain phosphorus removal without the anaerobic phase. Reactor performance in terms of phosphorus abatement kept always higher then 65% depending on adopted sludge retention time (SRT). In fact increasing SRT from 5 days to 8 days phosphorus removal and reactor performance increase but overcoming this SRT value a decreasing in reactor efficiency was recorded. (orig.) With 6 figs., 3 tabs., 18 refs.

  1. Friction Stir Spot Welding of Advanced High Strength Steels

    Santella, M. L.; Hovanski, Yuri; Grant, Glenn J.; Carpenter, Joseph A.; Warren, C. D.; Smith, Mark T.

    2008-12-28

    Experiments are continuing to evaluate the feasibility of friction stir spot welding advanced high-strength steels including, DP780, martensitic hot-stamp boron steel, and TRIP steels. Spot weld lap-shear strengths can exceed those required by industry standards such as AWS D8.1.

  2. Stirring-induced bifurcation driven by the chaotic regime in the Belousov—Zhabotinsky reaction in a CSTR

    Strizhak, Peter E.

    1995-09-01

    The stirring-induced bifurcation at low stirring rate S 0 = 23 rpm of the reaction volume has been observed for the chaotic regime in the Belousov—Zhabotinsky oscillating chemical reaction (malonic acidbromatecerium(III)sulfuric acid) in a continuously stirred tank reactor in premixing mode. This bifurcation is characterized by a stepwise growth of the macroscopic spatial concentration gradients that is shown by the use of the time dependencies of the potential difference between two platinum electrodes.

  3. 用数值模拟方法分析混合和导流筒对搅拌槽中沉淀硫酸钡的影响%Computational Fluid Dynamics Approach to the Effect of Mixing and Draft Tube on the Precipitation of Barium Sulfate in a Continuous Stirred Tank

    王正; 毛在砂; 杨超; 沈湘黔

    2006-01-01

    The effect of mixing on the precipitation of barium sulfate in a continuous stirred tank is simulated numerically with different feeding location, feed concentration, impeller speed and residence time through solving the standard momentum and mass transport equations in combination with the moment equations for crystal population balance. The numerical method was validated with the literature data. The simulation results including the distribution of the local supersaturation ratio distribution in the precipitator, mean crystal size and coefficient of variation under different operating conditions compared well with experimental data in the literature. The effect of the presence of a draft tube on precipitation were also investigated, and it is suggested that the installation of a draft tube increased the mean crystal size, in general agreement with experimental work in the literature.

  4. Modelling of baffled stirred tanks

    Ahlstedt, H.; Lahtinen, M. [Tampere Univ. of Technology (Finland). Energy and Process Engineering

    1996-12-31

    The three-dimensional flow field of a baffled stirred tank has been calculated using four different turbulence models. The tank is driven by a Rushton-type impeller. The boundary condition for the impeller region has been given as a source term or by calculating the impeller using the sliding mesh technique. Calculated values have been compared with measured data. (author)

  5. New Tool Creates a Big Stir

    2001-01-01

    A new self-adjusting, retractable pin tool for friction stir welding is now used in the manufacturing of components for NASA Space Shuttles. Friction stir welding is a process that makes straight-line welds without bringing the parent material to a liquid state. This is accomplished through high-speed rotation, which generates frictional heat between the welding tool and the piece being welded. This heat causes the material to soften to the point of plasticity without allowing it to melt. The plasticized material is then transferred from the front edge of the welding tool to the trail edge, where it joins the pieces being welded. However, a major flaw of this method is its reliance on a single-piece pin tool. The weld is left unfinished and a hole remains where the pin was inserted. The hole must be covered with a rivet in order to preserve the integrity of the weld. The NASA-developed pin tool, however, eliminates the need for this finishing step, as its retraction allows continuous rewelding at lesser depths, until the hole is completely closed. With this NASA technology, welding of higher strength alloys, as well as non-planer and variable thickness structures can be achieved.

  6. Research on Electromagnetic Stirring Technology for 20CrMnTi Gear Steel Continuous Casting Process%齿轮钢20CrMnTi连铸电磁搅拌工艺研究

    刘建; 彭振宇

    2011-01-01

    The segregation of alloying element of gear steel 20CrMnTi has significant influence on the machining accuracy of gear. The macro segregation law of C、Mn and Cr in 20CrMnTi billets that were produced with different MEMS process was studied with the method of original position statistic distribution analysis(OPA). 2-D and 3-D distribution figures of alloying elements were obtained, and the quantitative description of the homogeneity of material was figured out. The results showed that when other conditions were not changed, the degree of segregation was the least when the current of the mould electromagnetic stirring was 400 A, and with the frequency of 2.5 Hz.%为改善齿轮钢材质量,采用原住统计分布分析、钻点取样化学成分分析等方法,研究了改变连铸结晶器搅拌工艺所生产的20CrMnTi钢连铸坯中C、Mn、Cr等合金元素的分布情况,得到了表示合金元素分布的二维、三维分布图,以及可定量表征材料均匀度的统计偏析度,从而对连铸生产工艺参数进行优化.结果表明,在其它生产工艺参数稳定的情况下,结晶器电磁搅拌电流为400 A,频率为2.5 Hz时,生产的连铸坯合全元素偏析程度最小.

  7. Læremiddelevaluering af web 2.0 læremidler

    Falkesgaard Slot, Marie; Gissel, Stig Toke

    2014-01-01

    Kapitlet etablerer og afprøver et analyseapparat, der bidrager til at højne kvaliteten af de valg, som foretages af web 2.0-læremidler i danskfaget. I kapitlet fokuseres der på læremiddel evaluering af nogle af de funktioner, som typisk tilskrives web 2.0-værktøjerne, ligesom der gives eksempler på...

  8. The new 2.0 l TDI {sup registered} to fulfill American emission standards in Volkswagens new Passat; Der neue 2,0l TDI {sup registered} zur Erfuellung der amerikanischen Emissionsgesetze in Volkswagens neuem Passat

    Kahrstedt, Joern; Dorenkamp, Richard; Kuiken, Sander; Greiner, Michael; Kuehne, Ingo; Nigro, Giampaolo; Duesterdiek, Thorsten; Veldeten, Burkhard; Thoem, Norbert [Volkswagen AG, Wolfsburg (Germany)

    2011-07-01

    Volkswagen introduced the all-new Passat in 2011 at the Detroit Motor Show in the USA. It is a new midsize sedan designed exclusively for the American market and will be built at a completely new plant in Chattanooga, Tennessee. The second-generation 2.0l TDI {sup registered} engine familiar from Europe was extensively modified and further developed for the new Passat, in order to comply with the American BIN5/ULEV emission limits. For this purpose the engine's untreated emissions had to be lowered and, in combination with exhaust emission control by selective catalytic reduction (SCR), compliance with the emission limits throughout the car's operating life ensured. An effective measure for lowering the engine's untreated emissions has proved to be the low-pressure EGR system (LP EGR) [1] introduced on the first-generation 2.0l TDI {sup registered} BIN5 engine. In the course of ongoing development of the LP EGR system, work continued on reducing pressure losses in the system, and charge-air cooling was converted from air to water cooling. Water-cooled charge-air cooling enables intake pipe temperature control independent of ambient temperature, and due to the elimination of throttling and the associated reduction in volume improves road dynamics. Systematic elimination of throttling restrictions in the gas system, combined with improved turbocharging, led to a significant drop in fuel consumption and optimal road performance. As a means of stabilizing untreated emissions in the engine, cylinder-pressure control of combustion was carried-over from the first-generation 2.0l TDI BIN5 engine. Thanks to the closed-loop control of the indicated mean pressure and the centre of combustion with the pressure sensor integrated into the glow-plug, it was possible to minimize the influences of fluctuating fuel quality and component tolerances. The exhaust system was completely revised in order to achieve maximum NOX conversion in the SCR catalytic converter. The

  9. Pulsed ultrasonic stir welding system

    Ding, R. Jeffrey (Inventor)

    2013-01-01

    An ultrasonic stir welding system includes a welding head assembly having a plate and a rod passing through the plate. The rod is rotatable about a longitudinal axis thereof. During a welding operation, ultrasonic pulses are applied to the rod as it rotates about its longitudinal axis. The ultrasonic pulses are applied in such a way that they propagate parallel to the longitudinal axis of the rod.

  10. Flexible Friction Stir Joining Technology

    Feng, Zhili [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Lim, Yong Chae [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Mahoney, Murray [MegaStir Technologies LLC, Orem, UT (United States); Sanderson, Samuel [MegaStir Technologies LLC, Orem, UT (United States); Larsen, Steve [MegaStir Technologies LLC, Orem, UT (United States); Steel, Russel [MegaStir Technologies LLC, Orem, UT (United States); Fleck, Dale [MegaStir Technologies LLC, Orem, UT (United States); Fairchild, Doug P [ExxonMobil, Upstream Research Company (URC), Houston, TX (United States); Wasson, Andrew J [ExxonMobil, Upstream Research Company (URC), Houston, TX (United States); Babb, Jon [MegaStir Technologies LLC, Orem, UT (United States); Higgins, Paul [MegaStir Technologies LLC, Orem, UT (United States)

    2015-07-23

    Reported herein is the final report on a U.S. Department of Energy (DOE) Advanced Manufacturing Office (AMO) project with industry cost-share that was jointly carried out by Oak Ridge National Laboratory (ORNL), ExxonMobil Upstream Research Company (ExxonMobil), and MegaStir Technologies (MegaStir). The project was aimed to advance the state of the art of friction stir welding (FSW) technology, a highly energy-efficient solid-state joining process, for field deployable, on-site fabrications of large, complex and thick-sectioned structures of high-performance and high-temperature materials. The technology innovations developed herein attempted to address two fundamental shortcomings of FSW: 1) the inability for on-site welding and 2) the inability to weld thick section steels, both of which have impeded widespread use of FSW in manufacturing. Through this work, major advance has been made toward transforming FSW technology from a “specialty” process to a mainstream materials joining technology to realize its pervasive energy, environmental, and economic benefits across industry.

  11. Microstructure and Properties of Joint Interface of Semisolid Stirring Brazing of Composites

    Huibin Xu; Bofang Zhou; Changhua Du; Quanxiang Luo; Hongyou Chen

    2012-01-01

    Stirring assisted brazing of SiC(p/A356) composites in air was investigated. A stirring was applied on one of the samples to be bonded at 455℃ during brazing. The filler metal was extruded and impacted intensively on the two surfaces of the base materials during stirring. It can be found that oxide film on the surface of the composites can be disrupted and removed through the observation by scanning electron microscopy (SEM). The metallurgical bonds formed between the filler metal and the base materials. However, continuous residual oxide film was found at bottom joint interface, which limited the lift of joint strength. A stirring was applied once more after the samples were continuously heated up to 470 and 500℃, respectively. At this time, residual oxide film after the first of stirring can be broken by once more stirring. The bonds are mainly composed of a new alloy, which have a higher content of aluminum and are free of continuous oxide film, showing higher shear strength of 113 MPa than that of the base materials.

  12. Quality evaluation of Al-5Ti-1B grain refiner produced by continuous casting and extrusion process with electromagnetic stirring%电磁搅拌连续铸挤Al-5Ti-1B合金晶粒细化剂的质量评价

    王顺成; 戚文军; 郑开宏; 李建湘; 宁长维

    2014-01-01

    采用电磁搅拌连续铸挤技术生产Al-5Ti-1B合金晶粒细化剂,研究了Al-5Ti-1B合金的化学成分、显微组织和晶粒细化效果,并与美国KBA、荷兰KBM、英国LSM 公司生产的Al-5Ti-1B合金进行了比较,对电磁搅拌连续铸挤Al-5Ti-1B合金的质量进行了评价.结果表明:电磁搅拌连续铸挤Al-5Ti-1B合金中Ti和B元素含量分别为5.08%和1.02%.Fe ,Si及V杂质元素含量分别为0.11%,0.087%和0.011%;T iA l3相呈块状,平均尺寸为15.7μm ,而T iB2粒子呈颗粒状均匀分布于α-A l基体,平均尺寸为0.74μm ;添加0.2%的A l-5 T i-1B合金,可使纯铝晶粒平均尺寸从2800μm细化到68μm .比较结果表明:电磁搅拌连续铸挤A l-5 T i-1B合金的元素含量更稳定、杂质元素含量更低,T iA l3相和T iB2粒子更细小均匀,对铝晶粒的细化能力更强.%The Al-5Ti-1B grain refiner was produced by continuous casting and extrusion process with elec-tromagnetic stirring .The chemical compositions ,microstructure and grain refining efficiency of Al-5Ti-1B grain refiner were studied and compared with that of Al-5Ti-1B grain refiner produced by KBA ,KBM and LSM .The quality of Al-5Ti-1B grain refiner produced by continuous casting and extrusion process with e-lectromagnetic stirring was evaluated .Results show that the content of alloying elements Ti and B are 5 .08% and 1 .02% ,respectively .T he content of impurity elements Fe ,Si and V are 0 .11% ,0 .087% and 0 .011% ,respectively .The average size of fine TiAl3 phase with square shape is 15 .7 μm .The average size of fine TiB2 particles uniformly distributed in the α-Al is 0 .74 μm .The grains average size of pure Al with adding 0 .2% Al-5Ti-1B grain refiner can be refined from 2800μm to 68μm .The compared results in-dicate that the Al-5Ti-1B grain refiner produced by continuous casting and extrusion process with electro-magnetic stirring have many

  13. Friction Stir Processing of Cast Superalloys Project

    National Aeronautics and Space Administration — This SBIR effort examines the feasibility of an innovative fabrication technology incorporating sand casting and friction stir processing (FSP) for producing...

  14. Peak Stir Zone Temperatures during Friction Stir Processing

    Swaminathan, Srinivasan; Oh-Ishi, Keiichiro; Zhilyaev, Alexander P.; Fuller, Christian B.; London, Blair; Mahoney, Murray W.; McNelley, Terry R.

    2010-03-01

    The stir zone (SZ) temperature cycle was measured during the friction stir processing (FSP) of NiAl bronze plates. The FSP was conducted using a tool design with a smooth concave shoulder and a 12.7-mm step-spiral pin. Temperature sensing was accomplished using sheathed thermocouples embedded in the tool path within the plates, while simultaneous optical pyrometry measurements of surface temperatures were also obtained. Peak SZ temperatures were 990 °C to 1015 °C (0.90 to 0.97 T Melt) and were not affected by preheating to 400 °C, although the dwell time above 900 °C was increased by the preheating. Thermocouple data suggested little variation in peak temperature across the SZ, although thermocouples initially located on the advancing sides and at the centerlines of the tool traverses were displaced to the retreating sides, precluding direct assessment of the temperature variation across the SZ. Microstructure-based estimates of local peak SZ temperatures have been made on these and on other similarly processed materials. Altogether, the peak-temperature determinations from these different measurement techniques are in close agreement.

  15. Studies of stirred jujube yogurt

    郑强强; 薛菊兰; 刘亚丽; 秦婷婷

    2014-01-01

    Jujube is a delicious sweet fruits, with the functions of anti-tumor, anti-cancer, anti-aging, reducing blood pressure, improving immunity and so on [1]. Yogurt is a kind of high nutritional value and special flavor drinks. Its protein is easily digested and absorbed, especial y calcium. In this experiment, dry jujube and fresh milk as the main material to obtain solidified yoghurt. Then researched how the amounts of solidified yoghurt, sugar, jujube slurry to effect the yogurt quality. The results showed that: the best proportion of stirred yogurt: jujube slurry 15%, sugar 4%and yoghurt85%.

  16. Pulsed ultrasonic stir welding method

    Ding, R. Jeffrey (Inventor)

    2013-01-01

    A method of performing ultrasonic stir welding uses a welding head assembly to include a plate and a rod passing through the plate. The rod is rotatable about a longitudinal axis thereof. In the method, the rod is rotated about its longitudinal axis during a welding operation. During the welding operation, a series of on-off ultrasonic pulses are applied to the rod such that they propagate parallel to the rod's longitudinal axis. At least a pulse rate associated with the on-off ultrasonic pulses is controlled.

  17. Effects of mechanical force on grain structures of friction stir welded oxide dispersion strengthened ferritic steel

    Han, Wentuo, E-mail: hanwentuo@hotmail.com [Institute of Advanced Energy, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan); Kimura, Akihiko [Institute of Advanced Energy, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan); Tsuda, Naoto [Graduate School of Energy Science, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan); Serizawa, Hisashi [Joining and Welding Research Institute, Osaka University, Ibaraki, Osaka 567-0047 (Japan); Chen, Dongsheng [Graduate School of Energy Science, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan); Je, Hwanil [Institute of Advanced Energy, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan); Fujii, Hidetoshi [Joining and Welding Research Institute, Osaka University, Ibaraki, Osaka 567-0047 (Japan); Ha, Yoosung [Graduate School of Energy Science, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan); Morisada, Yoshiaki [Joining and Welding Research Institute, Osaka University, Ibaraki, Osaka 567-0047 (Japan); Noto, Hiroyuki [Graduate School of Energy Science, Kyoto University, Gokasho, Uji, Kyoto 611-0011 (Japan)

    2014-12-15

    The weldability of oxide dispersion strengthened (ODS) ferritic steels is a critical obstructive in the development and use of these steels. Friction stir welding has been considered to be a promising way to solve this problem. The main purpose of this work was to reveal the effects of mechanical force on grain structures of friction stir welded ODS ferritic steel. The grain appearances and the misorientation angles of grain boundaries in different welded zones were investigated by the electron backscatter diffraction (EBSD). Results showed that the mechanical force imposed by the stir tool can activate and promote the recrystallization characterized by the transformation of boundaries from LABs to HABs, and contribute to the grain refinement. The type of recrystallization in the stir zone can be classified as the continuous dynamic recrystallization (CDRX)

  18. Wiping Metal Transfer in Friction Stir Welding

    Nunes, Arthur C., Jr.; Whitaker, Ann F. (Technical Monitor)

    2001-01-01

    Much evidence suggests that as the friction stir pin-tool moves along a weld seam the displacement of metal takes place by a wiping action at the surface of a plug of metal that rotates with the tool. The wiping model is explained and some consequences for the friction stir welding process are drawn.

  19. Gimbaled-shoulder friction stir welding tool

    Carter, Robert W. (Inventor); Lawless, Kirby G. (Inventor)

    2010-01-01

    A gimbaled-shoulder friction stir welding tool includes a pin and first and second annular shoulders coupled to the pin. At least one of the annular shoulders is coupled to the pin for gimbaled motion with respect thereto as the tool is rotated by a friction stir welding apparatus.

  20. Friction Stir Welding and Processing

    Hovanski, Yuri; Carsley, John; Clarke, Kester D.; Krajewski, Paul E.

    2015-05-01

    With nearly twenty years of international research and collaboration in friction stir welding (FSW) and processing industrial applications have spread into nearly every feasible market. Currently applications exist in aerospace, railway, automotive, personal computers, technology, marine, cutlery, construction, as well as several other markets. Implementation of FSW has demonstrated diverse opportunities ranging from enabling new materials to reducing the production costs of current welding technologies by enabling condensed packaging solutions for traditional fabrication and assembly. TMS has sponsored focused instruction and communication in this technology area for more than fifteen years, with leadership from the Shaping and Forming Committee, which organizes a biannual symposium each odd year at the annual meeting. A focused publication produced from each of these symposia now comprises eight volumes detailing the primary research and development activities in this area over the last two decades. The articles assembled herein focus on both recent developments and technology reviews of several key markets from international experts in this area.

  1. Self-Reacting Friction Stir Welding for Aluminum Alloy Circumferential Weld Applications

    Bjorkman, Gerry; Cantrell, Mark; Carter, Robert

    2003-01-01

    Friction stir welding is an innovative weld process that continues to grow in use, in the commercial, defense, and space sectors. It produces high quality and high strength welds in aluminum alloys. The process consists of a rotating weld pin tool that plasticizes material through friction. The plasticized material is welded by applying a high weld forge force through the weld pin tool against the material during pin tool rotation. The high weld forge force is reacted against an anvil and a stout tool structure. A variation of friction stir welding currently being evaluated is self-reacting friction stir welding. Self-reacting friction stir welding incorporates two opposing shoulders on the crown and root sides of the weld joint. In self-reacting friction stir welding, the weld forge force is reacted against the crown shoulder portion of the weld pin tool by the root shoulder. This eliminates the need for a stout tooling structure to react the high weld forge force required in the typical friction stir weld process. Therefore, the self-reacting feature reduces tooling requirements and, therefore, process implementation costs. This makes the process attractive for aluminum alloy circumferential weld applications. To evaluate the application of self-reacting friction stir welding for aluminum alloy circumferential welding, a feasibility study was performed. The study consisted of performing a fourteen-foot diameter aluminum alloy circumferential demonstration weld using typical fusion weld tooling. To accomplish the demonstration weld, weld and tack weld development were performed and fourteen-foot diameter rings were fabricated. Weld development consisted of weld pin tool selection and the generation of a process map and envelope. Tack weld development evaluated gas tungsten arc welding and friction stir welding for tack welding rings together for circumferential welding. As a result of the study, a successful circumferential demonstration weld was produced leading

  2. Modeling of material flow in friction stir welding process

    2007-01-01

    This paper presents a 3D numerical model to study the material flow in the friction stir welding process. Results indicate that the material in front of the pin moves upwards due to the extrusion of the pin, and then the upward material rotates with the pin. Behind the rotating tool, the material starts to move downwards and to deposit in the wake. This process is the real cause to make friction stir welding process continuing successfully. The tangent movement of the material takes the main contribution to the flow of the material in friction stir welding process. There exists a swirl on the advancing side and with the increase of the translational velocity the inverse flow of the material on the advancing side becomes faster. The shoulder can increase the velocity of material flow in both radial direction and tangent direction near the top surface. The variations of process parameters do have an effect on the velocity field near the pin, especially in the region in which the material flow is faster.

  3. Recent Developments in Friction Stir Welding of Al-alloys

    Çam, Gürel; Mistikoglu, Selcuk

    2014-06-01

    The diversity and never-ending desire for a better life standard result in a continuous development of the existing manufacturing technologies. In line with these developments in the existing production technologies the demand for more complex products increases, which also stimulates new approaches in production routes of such products, e.g., novel welding procedures. For instance, the friction stir welding (FSW) technology, developed for joining difficult-to-weld Al-alloys, has been implemented by industry in manufacturing of several products. There are also numerous attempts to apply this method to other materials beyond Al-alloys. However, the process has not yet been implemented by industry for joining these materials with the exception of some limited applications. The microstructures and mechanical properties of friction stir welded Al-alloys existing in the open literature will be discussed in detail in this review. The correlations between weld parameters used during FSW and the microstructures evolved in the weld region and thus mechanical properties of the joints produced will be highlighted. However, the modeling studies, material flow, texture formation and developments in tool design are out of the scope of this work as well as the other variants of this technology, such as friction stir spot welding (FSSW).

  4. Nano-Sized Grain Refinement Using Friction Stir Processing

    2013-03-01

    friction stir weld is a very fine grain microstructure produced as a result of dynamic recrystallization. The friction stir ... Friction Stir Processing, Magnesium, Nano-size grains Abstract A key characteristic of a friction stir weld is a very fine grain microstructure...state process developed on the basis of the friction stir welding (FSW) technique invented by The Welding Institute (TWI) in 1991 [2]. During

  5. pH对发酵系统的产甲烷活性抑制及产氢强化%Enhancement of the fermentative hydrogen production in a continuous-flow stirred tank reactor by decreasing pH to inhibit methanogenesis

    李建政; 苏晓煜; 昌盛; 张立国; 于泽

    2012-01-01

    To develop a feasible method for inhibiting methanogenesis while enhancing fermentative hydrogen production in anaerobic organic wastewater fermentation process, a continuous - flow stirred tank reactor (CSTR) a methane production feature was introduced and used as the base-line condition. The CSTR was op- erated at (35 ± 1 )℃ with an influent COD 7 000 mg/L and a hydraulic retention time (HRT) 8 h throughout the performance test. When the pH in the CSTR decreased from 6. 5 - 7.2 to 6. 0 - 6. 5, the methane yield decreased remarkably and could not be inspected in the biogas at last, while the percentage of hydrogen in bio- gas kept at a low level less than 3 %. When the CSTR operated with a lower pH 4. 0 -5.0, the acidogenesis was further enhanced with a total organic intermediate of 2 052 rag/L, dominated by ethanol and acetic acid, indicating a typical ethanol-type fermentation established in the CSTR. During the ethanol-type fermentation process, a biogas yield of 26 L/d was obtained with a hydrogen percentage about 45%. The specific hydrogen producing rate of the anaerobic activated sludge reached at 1.67 L/( g · d) averagely. Key words: organic wastewater; methanogenesis; fermentative hydrogen production; pH adjustment; continu- ous-flow stirred tank reactor (CSTR)%为抑制厌氧发酵系统的产甲烷活性,强化其发酵产氢性能,采用逐级降低pH的调控方法,探讨连续流搅拌槽式反应器(CSTR)从具有显著甲烷发酵特征的厌氧发酵系统向发酵产氢系统转变的运行特征.在进水COD7000mg/L、水力停留时间(HRT)8h条件下,发酵体系在pH由6.5~7.2降低到6.0~6.5时,虽然发酵气中的甲烷体积分数逐渐减少乃至消失,但氢气体积分数一直在3%以下;当pH下降到4.0~5.0时,系统中的产酸发酵作用得到了进一步强化,挥发性发酵产物总量平均为2052mg/L,呈现为典型的乙醇型发酵

  6. Torque Control of Friction Stir Welding Project

    National Aeronautics and Space Administration — Longhurst Engineering, PLC and Vanderbilt University propose the innovation of torque control of friction stir welding (FSW) as a replacement to force control of...

  7. Friction Stir Processing of Cast Superalloys Project

    National Aeronautics and Space Administration — This SBIR Phase I effort examines the feasibility of an innovative fabrication technology incorporating sand casting and friction stir processing (FSP) for producing...

  8. Robust Nonlinear Control of Continuous Stirred Tank Reactors

    1998-01-01

    1IntroductionRobustcontrolofuncertainsystemsisacentralissueincontroltheory.Inthepastfewyearsmuchinteresthasbeendevotedtothede...

  9. Gimballed Shoulders for Friction Stir Welding

    Carter, Robert; Lawless, Kirby

    2008-01-01

    In a proposed improvement of tooling for friction stir welding, gimballed shoulders would supplant shoulders that, heretofore, have been fixedly aligned with pins. The proposal is especially relevant to self-reacting friction stir welding. Some definitions of terms, recapitulated from related prior NASA Tech Briefs articles, are prerequisite to a meaningful description of the proposed improvement. In friction stir welding, one uses a tool that includes (1) a rotating shoulder on top (or front) of the workpiece and (2) a pin that rotates with the shoulder and protrudes from the shoulder into the depth of the workpiece. In conventional friction stir welding, the main axial force exerted by the tool on the workpiece is reacted through a ridged backing anvil under (behind) the workpiece. When conventional friction stir welding is augmented with an auto-adjustable pin-tool (APT) capability, the depth of penetration of the pin into the workpiece is varied in real time by a position- or forcecontrol system that extends or retracts the pin as needed to obtain the desired effect. In self-reacting (also known as self-reacted) friction stir welding as practiced heretofore, there are two shoulders: one on top (or front) and one on the bottom (or back) of the workpiece. In this case, a threaded shaft protrudes from the tip of the pin to beyond the back surface of the workpiece. The back shoulder is held axially in place against tension by a nut on the threaded shaft. Both shoulders rotate with the pin and remain aligned coaxially with the pin. The main axial force exerted on the workpiece by the tool and front shoulder is reacted through the back shoulder and the threaded shaft into the friction-stir-welding machine head, so that a backing anvil is no longer needed. A key transmits torque between the bottom shoulder and the threaded shaft, so that the bottom shoulder rotates with the shaft. This concludes the prerequisite definitions of terms.

  10. Deterministic Chaos in Open Well-stirred Bray-Liebhafsky Reaction System

    Kolar-Anić, Ljiljana; Vukojević, Vladana; Pejić, Nataša; Grozdić, Tomislav; Anić, Slobodan

    2004-12-01

    Dynamics of the Bray-Liebhafsky (BL) oscillatory reaction is analyzed in a Continuously-fed well-Stirred Thank Reactor (CSTR). Deterministic chaos is found under different conditions, when temperature and acidity are chosen as control parameters. Dynamic patterns observed in real experiments are also numerically simulated.

  11. Stirring effects and bistability in the iodate-arsenous acid reaction: Premixed vs segregated flows

    Hannon, L.; Horsthemke, W.

    1987-01-01

    Using a coalescence-dispersion model of the continuous flow-stirred tank reactor (CSTR), we study the effect of premixed vs nonpremixed reactant flows on chemical bistability. The region of bistability is smaller for segregated feed streams than for a fully premixed feed stream. The transition from flow branch to thermodynamic branch is particularly sensitive to the feed stream configuration.

  12. Friction Stir Spot Welding of DP780 and Hot-Stamp Boron Steels

    Santella, Michael L.; Frederick, Alan; Hovanski, Yuri; Grant, Glenn J.

    2008-05-16

    Friction stir spot welds were made in two high-strength steels: DP780, and a hot-stamp-boron steel with tensile strength of 1500 MPa. The spot welds were made at either 800 or 1600 rpm using either of two polycrystalline boron nitride tools. One stir tool, BN77, had the relatively common pin-tool shape. The second tool, BN46, had a convex rather than a concave shoulder profile and a much wider and shorter pin. The tools were plunged to preprogrammed depths either at a continuous rate (1-step schedule) or in two segments consisting of a relatively high rate followed by a slower rate. In all cases, the welds were completed in 4s. The range of lap-shear values were compared to values required for resistance spot welds on the same steels. The minimum value of 10.3 kN was exceeded for friction stir spot welding of DP780 using a 2-step schedule and either the BN77- or the BN46-type stir tool. The respective minimum value of 12 kN was also exceeded for the HSB steel using the 2-step process and the BN46 stir tool.

  13. Mitigating Abnormal Grain Growth for Friction Stir Welded Al-Li 2195 Spun Formed Domes

    Chen, Po-Shou; Russell, Carolyn

    2012-01-01

    Formability and abnormal grain growth (AGG) are the two major issues that have been encountered for Al alloy spun formed dome development using friction stir welded blanks. Material properties that have significant influence on the formability include forming range and strain hardening exponent. In this study, tensile tests were performed for two 2195 friction stir weld parameter sets at 400 F to study the effects of post weld anneal on the forming range and strain hardening exponent. It was found that the formability can be enhanced by applying a newly developed post weld anneal to heat treat the friction stir welded panels. This new post weld anneal leads to a higher forming range and much improved strain hardening exponent. AGG in the weld nugget is known to cause a significant reduction of ductility and fracture toughness. This study also investigated how AGG may be influenced by the heating rate to the solution heat treatment temperature. After post-weld annealing, friction stir welds were strained to 15% and 39% by compression at 400 F before they were subjected to SHT at 950 F for 1 hour. Salt bath SHT is very effective in reducing the grain size as it helps arrest the onset of AGG and promote normal recrystallization and grain growth. However, heat treating a 18 ft dome using a salt bath is not practical. Efforts are continuing at Marshall Space Flight Center to identify the welding parameters and heat treating parameters that can help mitigate the AGG in the friction stir welds.

  14. Acclimation of Methane-fermenting Anaerobic Flocs in a Continuous Flow Stirred Tank Reactor for Treating Beet-sugar Processing Wastewater%制糖废水CSTR甲烷发酵系统的污泥驯化与运行特征

    李建政; 叶菁菁; 王卫娜; 马超; 昌盛

    2008-01-01

    与厌氧颗粒污泥相比,絮状悬浮活性污泥具有传质界面大、速度快的突出优点,但要形成具有完整甲烷发酵过程的微生物生态系统则比较困难.采用连续搅拌槽式反应器(Continuous flow Stirred-Tank Reactor,CSTR),探讨了制糖废水厌氧生物处理系统的絮状污泥驯化与运行特征.研究表明,以有机废水好氧处理工艺的剩余污泥为种泥,在接种量MLVSS为8.52g/L,温度为(35±1)℃,COD浓度为4000mg/L,HRT为18 h,系统pH值保持在6.5~7.5等条件下,CSTR可在84d左右形成具有完整甲烷发酵过程的絮状是浮厌氧活性污泥系统.CSTR甲烷发酵系统对负荷冲击表现出了良好的调节能力,在有机负荷从5.3 kg COD/(m3·d)提高到9.33 kg COD/(m3·d)时,反应系统可在16d内重新达到稳定运行状态,其出水COD可稳定在1100mg/L左右,COD去除率和产气量平均为84%和38L/d,发酵气中的CO2和CH4含量分别为41%和48%.

  15. Microstructures of AZ91D alloy solidified during electromagnetic stirring

    MAO Wei-min; ZHEN Zi-sheng; CHEN Hong-tao

    2005-01-01

    With the help of an electromagnetic stirring device self-made and alloy melt quenching technology,the effect of electromagnetic stirring parameters on the microstructures of semi-solid AZ91D alloy was mainly studied at the stirring frequency of 200 Hz.The experimental results show that when the stirring power rises,the primary α-Mg rosettes in the semi-solid melt will bear stronger man-made temperature fluctuation and the root remelting effect of the dendritic arms is promoted so that the spherical primary α-Mg grains become much more and rounder.If the stirring frequency is 200 Hz,the ideal semi-solid microstructure of AZ91D magnesium alloy can be obtained when the stirring power is increased to 6.0 kW.If the stirring frequency is 200 Hz and the stirring power is 6.0 kW,it is found that the lower cooling rate is favorable for the spherical primary α-Mg grains to be developed during the electromagnetic stirring stage.If the AZ91D magnesium alloy billet prepared during electromagnetic stirring at the stirring frequency of 200 Hz and the stirring power of 6.0 kW is reheated to the solidus and liquidus temperature region,the primary α-Mg grain's shape will get more spherical,so it is very advantageous to the semi-solid thixoforming process.

  16. Friction Stir Welding of Aluminum Alloys

    FU Zhi-hong; HE Di-qiu; WANG Hong

    2004-01-01

    Friction stir welding(FSW), a new solid-state welding technology invited in the early 1990s,enables us weld aluminum alloys and titanium alloys etc. The processing of FSW, the microstructure in FSW alloysand the factors influencing weld quality are introduced. The complex factors affecting the properties are researched.

  17. Stirring the Ashes of Public Discourse.

    Marinara, Martha

    Sylvia Plath's confessional poem, "Lady Lazarus" can be used to illustrate a connection between autobiography and social critique. "You poke and stir" among the institutions that form social relations--the educational system, the court system, the economic system--to find individuals whose lives, whose joys and pains, and struggles for survival…

  18. Ferrous friction stir weld physical simulation

    Norton, Seth Jason

    2006-04-01

    Traditional fusion welding processes have several drawbacks associated with the melting and solidification of metal. Weld defects associated with the solidification of molten metal may act as initiation sites for cracks. Segregation of alloying elements during solidification may cause local changes in resistance to corrosion. The high amount of heat required to produce the molten metal in the weld can produce distortion from the intended position on cooling. The heat from the electric arc commonly used to melt metal in fusion welds may also produce metal fumes which are a potential health hazard. Friction stir welding is one application which has the potential to make full thickness welds in a single pass, while eliminating fume, reducing distortion, and eliminating solidification defects. Currently the friction stir welding process is used in the aerospace industry on aluminum alloys. Interest in the process by industries which rely on iron and its alloys for structural material is increasing. While friction stir welding has been shown to be feasible with iron alloys, the understanding of friction stir welding process effects on these materials is in its infancy. This project was aimed to better that understanding by developing a procedure for physical simulation of friction stir welding. Friction stir weld material tracer experiments utilizing stainless steel markers were conducted with plates of ingot iron and HSLA-65. Markers of 0.0625" diameter 308 stainless steel worked well for tracing the end position of material moved by the friction stir welding tool. The markers did not produce measurable increases in the loading of the tool in the direction of travel. Markers composed of 0.25" diameter 304 stainless steel did not perform as well as the smaller markers and produced increased loads on the friction stir welding tool. The smaller markers showed that material is moved in a curved path around the tool and deposited behind the tool. Material near the surface

  19. Friction Stir Welding of Shipbuilding Steel with Primer

    José Azevedo

    2016-03-01

    Full Text Available Abstract Friction Stir Welding has proven its merits for welding of aluminium alloys and is focused in expanding its material database to steel and titanium and also to assess new joint configurations. The use of welded structures in shipbuilding industry has a long tradition and continuously seeks for innovation in terms of materials and processes maintaining, or even, reducing costs. Several studies have been performed in the past years on FSW of steel. However, just recently were reported defect-free welds, free of martensite with stable parameters in steel without Primer. FSW of steel with primer has not been addressed. This work aims to fulfil a knowledge gap related to the use of friction stir for welding shipbuilding steel by analysing the effect of welding parameters on the metallurgical characteristics and mechanical properties of welds obtained with an innovative FSW tool in joining steel plates with a primer. Welds were performed in 4mm thick GL-A36 steel plates painted with a zinc based primer followed by a detailed microscopic, chemical and mechanical analysis. The results that matching fatigue properties are obtained using this technique, in FSW of shipbuilding steel with Primer.

  20. Effect of a stirring process in an isothermal titration microcalorimeter

    Socorro, F.; Nuez, I. de la; Alvarez, L.; Rodriguez de Rivera, M

    2004-10-01

    In this paper, it is analysed the way in which the thermodynamic results obtained in an isothermal titration microcalorimeter, with continuous injection of a liquid and a variable mass are affected. Two aspects are presented, the first one refers to a variation in the baseline that takes place when the liquid mass is increased in the laboratory cell, this variation is due to the change in the thermal coupling between the stirrer and its contact with the thermostat. The second aspect is the analysis of the effect of the stirring process and the injection velocity on the homogenization of the remaining mixture in the laboratory cell. The aim of the study of these two previous aspects is to increase the accuracy of the thermodynamic measures carried out. The variation of the baseline affects in a percentage from 1 to 2% of the total energy developed. It is also shown the necessity of a stirring process according to the injection velocity in order to obtain a homogeneous mixture at every instant. This fact allows to carry out a deconvolution of the calorimetric signal and to obtain directly the power developed in the mixture process in terms of the amount of mixed substance [Meas. Sci. Technol. 1 (1990) pp. 1285-1290; J. Thermal Analysis 41 (1994) pp. 1385-1392].

  1. Friction Stir Lap Welding: material flow, joint structure and strength

    Z.W. Chen

    2012-12-01

    Full Text Available Friction stir welding has been studied intensively in recent years due to its importance in industrial applications. The majority of these studies have been based on butt joint configuration and friction stir lap welding (FSLW has received considerably less attention. Joining with lap joint configuration is also widely used in automotive and aerospace industries and thus FSLW has increasingly been the focus of FS research effort recently. number of thermomechancal and metallurgical aspects of FSLW have been studied in our laboratory. In this paper, features of hooking formed during FSLW of Al-to-Al and Mg-to-Mg will first be quantified. Not only the size measured in the vertical direction but hook continuity and hooking direction have been found highly FS condition dependent. These features will be explained taking into account the effects of the two material flows which are speed dependent and alloy deformation behaviour dependent. Strength values of the welds will be presented and how strength is affected by hook features and by alloy dependent local deformation behaviours will be explained. In the last part of the paper, experimental results of FSLW of Al-to-steel will be presented to briefly explain how joint interface microstructures affect the fracturing process during mechanical testing and thus the strength. From the results, tool positioning as a mean for achieving maximum weld strength can be suggested.

  2. Guidelines for Friction Stir Welding

    2011-03-29

    in a large void at the termination point of the weld, the effects the exit hole will have on structural integrity must be considered. The...3.6 Cavity. A void -type discontinuity within a solid-state weld. See Figure 3.4. 3.7 Complex weld joint. A continuous weld...except as affected by corner radii. 3.61 Underfill . A depression resulting when the weld face is below the adjacent parent material surface. See

  3. 升流式厌氧污泥床和连续流搅拌槽式反应器的废水处理效能及产甲烷菌群组成的对比分析%Comparative Analysis of the Efficiency and the Methanogens Composition in Upflow Anaerobic Sludge Blanket and Continuous Stirred-Tank Reactor

    张立国; 李建政; 班巧英; 许一平

    2012-01-01

    分别运行升流式厌氧污泥床(UASB)反应器和连续流搅拌槽式反应器(CSTR)并使其达到稳定运行状态,在有机负荷率(OLR)均为6.0kg·m-3·d-1的条件下,对比分析了二者在稳定期的运行特性和产甲烷菌群的组成.结果表明,UASB的化学需氧量(COD)去除率为95%,显著高于CSTR的COD去除率(84%).然而,CSTR系统中的活性污泥的比产甲烷速率(315L·kg-1·d-1)和比COD去除率(0.85kg·kg-1·d-1)则显著高于UASB的260L·kg-1·d-1和0.67kg·kg-1·d-1.采用聚合酶链式反应-变性梯度凝胶电泳(PCR-DGGE)指纹分析技术对系统稳定期的活性污泥进行分析的结果表明,UASB系统的优势产甲烷菌为Methanosaeta concilii 和 Methanospirillum hungatei,而CSTR系统中的优势产甲烷菌为Methanosarcina mazeii和Methanobacterium formicicum.污泥微生物群落组成及其代谢特征的不同是造成厌氧处理系统效能差异的内在原因.UASB和CSTR在COD去除效能和污泥比活性方面各有所长,在实际应用中,须根据废水水质和预期处理程度合理选用.%The efficiency and the methanogens composition in an Upflow Anaerobic Sludge Blanket (UASB) reactor and a Continuous Stirred-Tank Reactor (CSTR) are investigated after achieving steady states at the same Organic Loading Rate (OLR) of 6.0kg· m-3 · d-1. The results show that the average removal rate of COD reaches 95% in the UASB, significantly higher than 84% of the CSTR. However, the specific methane production rate and the specific COD removal rate of the activated sludge are SlSL·kg-1·d-1 and 0.85kg·kg-1·d-1, respectively, in the CSTR, notably higher than those of the UASB of 260L·kg-1·d-1 and 0.67kg· kg-1·d-1, respectively. The analysis of the methanogens composition of the activated sludge by polymerase chain reaction-denaturing gradient gel electrophoresis (PCR-DGGE) indicates that Methanosaeta concilii and Methanospirillum hungatei are the dominant methanogens in the UASB, while

  4. Friction stir processing on carbon steel

    Tarasov, Sergei Yu., E-mail: tsy@ispms.ru [Institute of Strength Physics and Materials Science SB RAS, Tomsk, 634055, Russia and National Research Tomsk Polytechnic University, Tomsk, 634050 (Russian Federation); Melnikov, Alexander G., E-mail: melnikov-ag@tpu.ru [National Research Tomsk Polytechnic University, Tomsk, 634050 (Russian Federation); Rubtsov, Valery E., E-mail: rvy@ispms.ru [Institute of Strength Physics and Materials Science SB RAS, Tomsk, 634055 (Russian Federation)

    2014-11-14

    Friction stir processing of medium carbon steel samples has been carried out using a milling machine and tools made of cemented tungsten carbide. Samples have been machined from 40 and 40X steels. The tools have been made in the shape of 5×5×1.5 mm and 3×3×1.5 mm tetrahedrons. The microstructure of stirred zone has been obtained using the smaller tool and consists of fine recrystallized 2-3 μm grains, whereas the larger tool has produced the 'onion-like' structures comprising hard quenched 'white' 500-600 MPa layers with 300-350 MPa interlayers of bainite needles. The mean values of wear intensity obtained after measuring the wear scar width were 0.02 mm/m and 0.001 mm/m for non-processed and processed samples, respectively.

  5. Joining dissimilar materials using Friction Stir scribe technique

    Upadhyay, Piyush; Hovanski, Yuri; Jana, Saumyadeep; Fifield, Leonard S.

    2016-10-03

    The ability to effectively join materials with vastly different melting points like Aluminum-Steel, Polymer composites - metals has been one of the road blocks in realizing multi-material components for light weighting efforts. Friction stir scribe (FSS) technique is a promising method that produces continuous overlap joint between materials with vastly different melting regimes and high temperature flow characteristics. FSS uses an offset cutting tool at the tip of the FSW pin to create an insitu mechanical interlock between material interfaces. With investments from Vehicle Technology office, US DOE and several automotive manufacturers and suppliers PNNL is developing the FSS process and has demonstrated viability of joining several material combinations. Details of welding trails, unique challenges and mitigation strategies in different material combinations will be discussed. Joint characterization including mechanical tests and joint performances will also be presented.

  6. Welding defects at friction stir welding

    P. Podržaj

    2015-04-01

    Full Text Available The paper presents an overview of different types of defects at friction stir welding. In order to explain the reasons for their occurrence a short theoretical background of the process is given first. The main emphasis is on the parameters that influence the process. An energy supply based division of defects into three disjoint groups was used. The occurring defects are demonstrated on various materials.

  7. Thermal modelling of friction stir welding

    Schmidt, Henrik Nikolaj Blicher; Hattel, Jesper Henri

    2008-01-01

    The objective of the present work is to present the basic elements of the thermal modelling of friction stir welding as well as to clarify some of the uncertainties in the literature regarding the different contributions to the heat generation. Some results from a new thermal pseudomechanical model...... in which the temperature-dependent yield stress of the weld material controls the heat generation are also presented....

  8. Ultrasonic stir welding process and apparatus

    Ding, R. Jeffrey (Inventor)

    2009-01-01

    An ultrasonic stir welding device provides a method and apparatus for elevating the temperature of a work piece utilizing at least one ultrasonic heater. Instead of relying on a rotating shoulder to provide heat to a workpiece an ultrasonic heater is utilized to provide ultrasonic energy to the workpiece. A rotating pin driven by a motor assembly performs the weld on the workpiece. A handheld version can be constructed as well as a fixedly mounted embodiment.

  9. Enhancement of the performance of an anaerobic sequencing batch reactor treating low-strength wastewater through implementation of a variable stirring rate program

    Rodrigues, J.A.D.; Pinto, A.G.; Ratusznei, S.M.; Gedraite, R. [Instituto Maua de Tecnologia (IMT), Sao Caetano do Sul, SP (Brazil). Escola de Engenharia. Dept. de Engenharia Quimica e de Alimentos]. E-mail: rodrigues@maua.br; Zaiat, M. [Sao Paulo Univ., Sao Carlos, SP (Brazil). Escola de Engenharia. Dept. de Hidraulica e Saneamento

    2004-09-01

    This work focuses on enhancement of the performance of an anaerobic sequencing batch reactor with a six-vertical-blade-disk-turbine impeller, containing granulated biomass treating low-strength synthetic wastewater, through a study of the feasibility of implementing a variable stirring rate program. The reactor was operated at 30 deg C and a six-hour cycle was used to treat approximately 2.0 L of the synthetic substrate with a chemical oxygen demand (COD) of nearly 500 mg/L. Two different stirring rate program were implemented: a constant rate of 50 rpm and a variable rate consisting of 75 rpm for one hour, 50 rpm for four hours and 25 rpm for 0.5 hour. The last 0.5 hour of the cycle was used for the settling step. In both cases, a very short start-up period and unfiltered and filtered substrate removal efficiencies of 81% and 88%, respectively, were attained. However, use of the variable stirring rate enhanced efficiency of the reactor dynamics without impairing biomass morphology, thus resulting in a reduction in the total cycle time and a possible decrease in energy consumption. Additionally, a simplified model of the anaerobic metabolic activity, using apparent kinetic parameters, was proposed as a consecutive first-order kinetic model with substrate and total volatile acid residual concentrations in order to analyze how the variable stirring rate affects reactor performance. (author)

  10. Numerical simulation of friction stir welding

    Mijajlović Miroslav

    2014-01-01

    Full Text Available Friction stir welding is a solid-state welding technique that utilizes thermo-mechanical influence of the rotating welding tool on parent material resulting with monolith joint-weld. On the contact of welding tool and parent material, significant stirring and deformation of parent material appears, and during this process mechanical energy is partially transformed into heat. The paper describes the software for the numerical simulation of friction stir welding developed at Mechanical Engineering Faculty, University of Nis. Numerical solution for estimation of welding plates temperature is estimated using finite difference method-explicit scheme with adaptive grid, considering influence of temperature on material's conductivity, contact conditions between welding tool and parent material, material flow around welding tool etc. The calculated results are in good agreement with the experimental results. [Projekat Ministarstva nauke Republike Srbije, br. TR35034: The research of modern non-conventional technologies application in manufacturing companies with the aim of increase efficiency of use, product quality, reduce of costs and save energy and materials

  11. Electrochemical Studies of Passive Film Formation and Corrosion of Friction Stir Processed Nickel Aluminum Bronze

    2011-06-01

    friction stir welding (FSW) but is used for the purpose of refining...mechanical properties [11]. C. FRICTION STIR WELDING AND PROCESSING Friction Stir Processing (FSP) is derived from Friction Stir Welding (FSW) which was...Temple-Smith, and C. Dawes, Friction - stir butt welding , GB Patent No. 9125978.8, International patent application No. PCT/GB92/02203, 1991. [4

  12. Analysis and Comparison of Friction Stir Welding and Laser Assisted Friction Stir Welding of Aluminum Alloy

    Sabina Luisa Campanelli; Giuseppe Casalino; Caterina Casavola; Vincenzo Moramarco

    2013-01-01

    Friction Stir Welding (FSW) is a solid-state joining process; i.e., no melting occurs. The welding process is promoted by the rotation and translation of an axis-symmetric non-consumable tool along the weld centerline. Thus, the FSW process is performed at much lower temperatures than conventional fusion welding, nevertheless it has some disadvantages. Laser Assisted Friction Stir Welding (LAFSW) is a combination in which the FSW is the dominant welding process and the laser pre-heats the we...

  13. Friction Stir Weld Failure Mechanisms in Aluminum-Armor Structures Under Ballistic Impact Loading Conditions

    2013-01-01

    Sheet) Continuation for Block 13 ARO Report Number Friction Stir Weld Failure Mechanisms in Alumin Block 13: Supplementary Note © 2013 . Published in...nose, steel jacketed, hard tungsten core (1400 Hv), armor piercing (AP) projectile (Ref 1). As mentioned above, this failure mechanism is often...zones being impacted with blunt, lower hardness projectiles [e.g., 20-mm caliber, 53 g, blunt, chamfered right circular cylindrical steel fragment

  14. Influence of vibrational treatment on thermomechanical response of material under conditions identical to friction stir welding

    Konovalenko, Ivan S., E-mail: ivkon@ispms.tsc.ru [Institute of Strength Physics and Materials Science SB RAS, Tomsk, 634055 (Russian Federation); Konovalenko, Igor S., E-mail: igkon@ispms.tsc.ru; Kolubaev, Evgeniy A., E-mail: eak@ispms.tsc.ru [Institute of Strength Physics and Materials Science SB RAS, Tomsk, 634055 (Russian Federation); National Research Tomsk Polytechnic University, Tomsk, 634050 (Russian Federation); Dmitriev, Andrey I., E-mail: dmitr@ispms.tsc.ru [Institute of Strength Physics and Materials Science SB RAS, Tomsk, 634055 (Russian Federation); National Research Tomsk Polytechnic University, Tomsk, 634050 (Russian Federation); National Research Tomsk State University, Tomsk, 634050 (Russian Federation); Psakhie, Sergey G., E-mail: sp@ms.tsc.ru [Institute of Strength Physics and Materials Science SB RAS, Tomsk, 634055 (Russian Federation); National Research Tomsk State University, Tomsk, 634050 (Russian Federation)

    2015-10-27

    A molecular dynamics model was constructed to describe material loading on the atomic scale by the mode identical to friction stir welding. It was shown that additional vibration applied to the tool during the loading mode provides specified intensity values and continuous thermomechanical action during welding. An increase in additional vibration intensity causes an increase both in the force acting on the workpiece from the rotating tool and in temperature within the welded area.

  15. Influence of vibrational treatment on thermomechanical response of material under conditions identical to friction stir welding

    Konovalenko, Ivan S.; Konovalenko, Igor S.; Dmitriev, Andrey I.; Psakhie, Sergey G.; Kolubaev, Evgeniy A.

    2015-10-01

    A molecular dynamics model was constructed to describe material loading on the atomic scale by the mode identical to friction stir welding. It was shown that additional vibration applied to the tool during the loading mode provides specified intensity values and continuous thermomechanical action during welding. An increase in additional vibration intensity causes an increase both in the force acting on the workpiece from the rotating tool and in temperature within the welded area.

  16. The Effect of Tool Position for Aluminum and Copper at High Rotational Friction Stir Welding

    Recep Çakır; Sare Çelik

    2015-01-01

    Friction Stir Welding (FSW) is a solid state welding process used for welding similar and dissimilar materials. This welding technique allows welding of Aluminum alloys which present difficulties in fusion joining and allows different material couples to be welded continuously. In this study, 1050 aluminum alloy and commercially pure copper to increase heat input were produced at high rotation rate (2440 rev/min) with four different pin position (0-1-1.5-2 mm) and three different weld speeds ...

  17. Tristability in the iodate-As(III) chemical system arising from a model of stirring and mixing effects

    Ganapathisubramanian, N.

    1991-08-01

    The iodate-As(III) system which exhibits bistability in an ideal continuous flow stirred tank reactor (CSTR), exhibits tristability when subjected to the mixing model of Kumpinsky and Epstein [J. Chem. Phys. 82, 53 (1985)]. The cross flow between the major and minor reactors influences the system's lower hysteresis limit more than its upper hysteresis limit.

  18. Automated multisyringe stir bar sorptive extraction using robust montmorillonite/epoxy-coated stir bars.

    Ghani, Milad; Saraji, Mohammad; Maya, Fernando; Cerdà, Víctor

    2016-05-01

    Herein we present a simple, rapid and low cost strategy for the preparation of robust stir bar coatings based on the combination of montmorillonite with epoxy resin. The composite stir bar was implemented in a novel automated multisyringe stir bar sorptive extraction system (MS-SBSE), and applied to the extraction of four chlorophenols (4-chlorophenol, 2,4-dichlorophenol, 2,4,6-trichlorophenol and pentachlorophenol) as model compounds, followed by high performance liquid chromatography-diode array detection. The different experimental parameters of the MS-SBSE, such as sample volume, selection of the desorption solvent, desorption volume, desorption time, sample solution pH, salt effect and extraction time were studied. Under the optimum conditions, the detection limits were between 0.02 and 0.34μgL(-1). Relative standard deviations (RSD) of the method for the analytes at 10μgL(-1) concentration level ranged from 3.5% to 4.1% (as intra-day RSD) and from 3.9% to 4.3% (as inter-day RSD at 50μgL(-1) concentration level). Batch-to-batch reproducibility for three different stir bars was 4.6-5.1%. The enrichment factors were between 30 and 49. In order to investigate the capability of the developed technique for real sample analysis, well water, wastewater and leachates from a solid waste treatment plant were satisfactorily analyzed.

  19. Forming of aluminium alloy friction stir welds

    Bruni, Carlo

    2016-10-01

    The present paper aims at investigating, through analytical models, numerical models and experiments, the effect of the warm deformation phase, realised with an in temperature upsetting, on the weld previously performed by friction stir lap welding on aluminium alloy blanks. The investigation allows to show the deformation zones after upsetting that determine the homogenisation of the weld section. The analytical model allows to relate the friction factor with the upsetting load. The presence on the weld of not elevated friction factor values determines the deformation and localisation levels very useful for the weld. Such methodology allows to improve the weld itself with the forming phase.

  20. Friction stir welding of single crystal aluminium

    Fonda, Richard Warren; Wert, John A.; Reynolds, A.P.

    2007-01-01

    Friction stir welds were prepared in different orientations in an aluminium single crystal. The welds were quenched to preserve the microstructure surrounding the tool and then electron backscattered diffraction was used to reveal the generation of grain boundaries and the evolution...... of crystallographic texture around the tool in each weld. The extent of both dynamic recrystallisation and conventional recrystallisation varied considerably as a function of weld orientation. As the base plate begins to interact with the deformation field surrounding the tool, regions of the single crystal rotate...

  1. Uniform and reproducible stirring in a microbioreactor

    Bolic, Andrijana; Eliasson Lantz, Anna; Rottwitt, Karsten;

    microbioreactor application. In order to address some of these questions, we are currently investigating and developing a microbioreactor platform with a reactor volume up to 1ml, as we believe that this volume is of interest to many industrial applications. It is widely known that stirring plays a very important...... question is which microbioreactor volume is optimal while keeping in mind the final objective – application. Do we need a sample or not? Do we talk about cells in suspension or adhered on some substrate? Final microbioreactor design should thus strongly depend on the final goal of a specific...

  2. Localized Mechanical Properties of Friction Stir Processed Sensitized 5456-H116 Al

    2013-04-01

    stir welding (FSW) but it does not create a joint. Friction stir welding is a solid state joining process where the material is softened such that...small randomly distributed porosity. The volumetric defects are representative of those seen in friction stir processing and friction stir welding ...retreating side on the second pass, are typical defects seen in aluminum friction stir processing and friction stir welding

  3. Certification of a weld produced by friction stir welding

    Obaditch, Chris; Grant, Glenn J

    2013-10-01

    Methods, devices, and systems for providing certification of friction stir welds are disclosed. A sensor is used to collect information related to a friction stir weld. Data from the sensor is compared to threshold values provided by an extrinsic standard setting organizations using a certification engine. The certification engine subsequently produces a report on the certification status of the weld.

  4. Damage Tolerance Behavior of Friction Stir Welds in Aluminum Alloys

    McGill, Preston; Burkholder, Jonathan

    2012-01-01

    Friction stir welding is a solid state welding process used in the fabrication of various aerospace structures. Self-reacting and conventional friction stir welding are variations of the friction stir weld process employed in the fabrication of cryogenic propellant tanks which are classified as pressurized structure in many spaceflight vehicle architectures. In order to address damage tolerance behavior associated with friction stir welds in these safety critical structures, nondestructive inspection and proof testing may be required to screen hardware for mission critical defects. The efficacy of the nondestructive evaluation or the proof test is based on an assessment of the critical flaw size. Test data describing fracture behavior, residual strength capability, and cyclic mission life capability of friction stir welds at ambient and cryogenic temperatures have been generated and will be presented in this paper. Fracture behavior will include fracture toughness and tearing (R-curve) response of the friction stir welds. Residual strength behavior will include an evaluation of the effects of lack of penetration on conventional friction stir welds, the effects of internal defects (wormholes) on self-reacting friction stir welds, and an evaluation of the effects of fatigue cycled surface cracks on both conventional and selfreacting welds. Cyclic mission life capability will demonstrate the effects of surface crack defects on service load cycle capability. The fracture data will be used to evaluate nondestructive inspection and proof test requirements for the welds.

  5. Fluidization of potato starch in a stirred vibrating fluidized bed

    Kuipers, N.J M; Stamhuis, Eize; Beenackers, A.A C M

    1996-01-01

    A novel gas-solid reactor for cohesive C-powders such as potato starch is introduced, designed and characterized, the so-called stirred vibrating fluidized bed. The effects of a sinusoidal vibration of the gas distributor and/or stirring of the bed are investigated. The fluidization index, bed expan

  6. Friction Stir Welding Technology: Adapting NASA's Retractable Pin Tool

    ECT Team, Purdue

    2007-01-01

    In late 1991, The Welding Institute (TWI), a British research and technology organization, invented and patented a welding process named Friction Stir Welding (FSW). Friction Stir Welding is a highly significant advancement in aluminum welding technology that can produce stronger, lighter, and more efficient welds than any previous process.

  7. A Rotating Plug Model of Friction Stir Welding Heat Transfer

    Raghulapadu J. K.; Peddieson, J.; Buchanan, G. R.; Nunes, A. C.

    2006-01-01

    A simplified rotating plug model is employed to study the heat transfer phenomena associated with the fiction stir welding process. An approximate analytical solution is obtained based on this idealized model and used both to demonstrate the qualitative influence of process parameters on predictions and to estimate temperatures produced in typical fiction stir welding situations.

  8. Validation of the revised STI-r method

    Steeneken, H.J.M.; Houtgast, T.

    2002-01-01

    The revised model for the speech transmission index (STIr, Speech Communication 28 (1999) 109), was validated with an independent set of 68 test conditions. For a subset of 18 conditions, including only additive noise and band-pass limiting, it was veri.ed that the STIr provides a good prediction of

  9. Optimizing the stirring strategy for the vibrating intrinsic reverberation chamber

    Serra, Ramiro; Leferink, Frank

    2010-01-01

    This work describes the definition, application and assessment of a factorial plan with the aim of gaining insight on what kind of stirring strategy could work the best in a vibrating intrinsic reverberation chamber. Three different stirring strategies were defined as factors of a factorial analysis

  10. Microstructure Evolution during Friction Stir Spot Welding of TRIP Steel

    Lomholt, Trine Colding; Pantleon, Karen; Somers, Marcel A. J.

    2010-01-01

    In this study, the feasibility of friction stir spot welding of TRIP steel is investigated. In addition to manufacturing successful welds, the present study aims at a fundamental understanding of the mechanisms occurring at the (sub)micron scale during friction stir spot welding. As one of the main...

  11. Effect of Stirring and Seeding on Whey Protein Fibril Formation

    Bolder, S.G.; Sagis, L.M.C.; Venema, P.; Linden, van der E.

    2007-01-01

    The effect of stirring and seeding on the formation of fibrils in whey protein isolate (WPI) solutions was studied. More fibrils of a similar length are formed when WPI is stirred during heating at pH 2 and 80 C compared to samples that were heated at rest. Addition of seeds did not show an addition

  12. Gravitational Stirring in Planetary Debris Disks

    Kenyon, S J; Kenyon, Scott J.; Bromley, Benjamin C.

    2001-01-01

    We describe gravitational stirring models of planetary debris disks using a new multi-annulus planetesimal evolution code. The current code includes gravitational stirring and dynamical friction; future studies will include coagulation, fragmentation, Poynting-Robertson drag, and other physical processes. We use the results of our calculations to investigate the physical conditions required for small bodies in a planetesimal disk to reach the shattering velocity and begin a collisional cascade. Our results demonstrate that disks composed primarily of bodies with a single size will not undergo a collisional cascade which produces small dust grains at 30-150 AU on timescales of 1 Gyr or smaller. Disks with a size distribution of bodies reach conditions necessary for a collisional cascade in 10 Myr to 1 Gyr if the disk is at least as massive as a minimum mass solar nebula and if the disk contains objects with radii of 500 km or larger. The estimated 500 Myr survival time for these disks is close to the median ag...

  13. Simulation of 3D material flow in friction stir welding of AA6061-T6

    Zhang Zhao; Zhang Hongwu

    2008-01-01

    This paper reports the numerical simulation of the 3D material flow in friction stir welding process by using finite element methods based on solid mechanics. It is found that the material flow behind the pin is much faster than that in front of the pin. The material in front of the pin moves upwards and then rotates with the pin due to the effect of the rotating tool. Behind of the pin, the material moves downwards. This process of material movement is the real cause to make the friction stir welding process continuing successfully. With the increase of the translational velocity or the rotational velocity of the pin, the material flow becomes faster.

  14. Effect of stirring and seeding on whey protein fibril formation.

    Bolder, Suzanne G; Sagis, Leonard M C; Venema, Paul; van der Linden, Erik

    2007-07-11

    The effect of stirring and seeding on the formation of fibrils in whey protein isolate (WPI) solutions was studied. More fibrils of a similar length are formed when WPI is stirred during heating at pH 2 and 80 degrees C compared to samples that were heated at rest. Addition of seeds did not show an additional effect compared to samples that were stirred. We propose a model for fibril formation, including an activation, nucleation, growth, and termination step. The activation and nucleation steps are the rate-determining steps. Fibril growth is relatively fast but terminates after prolonged heating. Two processes that possibly induce termination of fibril growth are hydrolysis of nonassembled monomers and inactivation of the growth ends of the fibrils. Stirring may break up immature fibrils, thus producing more active fibrils. Stirring also seems to accelerate the kinetics of fibril formation, resulting in an increase of the number of fibrils formed.

  15. High-Powered, Ultrasonically Assisted Thermal Stir Welding

    Ding, Robert

    2013-01-01

    This method is a solid-state weld process capable of joining metallic alloys without melting. The weld workpieces to be joined by thermal stir welding (TSW) are drawn, by heavy forces, between containment plates past the TSW stir tool that then causes joining of the weld workpiece. TSW is similar to friction stir welding (FSW) in that material is heated into a plastic state (not melted) and stirred using a stir rod. The FSW pin tool is an integrated geometrical structure consisting of a large-diameter shoulder, and a smaller-diameter stir pin protruding from the shoulder. When the pin is plunged into a weld workpiece, the shoulder spins on the surface of the weld workpiece, thus inducing frictional heat into the part. The pin stirs the fraying surfaces of the weld joint, thus joining the weld workpiece into one structure. The shoulder and stir pin of the FSW pin tool must rotate together at a desired rotational speed. The induced frictional energy control and stir pin control of the pin tool cannot be de-coupled. The two work as one integrated unit. TSW, on the other hand, de-couples the heating and stirring of FSW, and allows for independent control of each process element. A uniquely designed induction coil heats the weld workpiece to a desired temperature, and once heated, the part moves into a stir rod whose RPM is also independently controlled. As the weld workpiece moves into the stir rod, the piece is positioned, or sandwiched, between upper and lower containment plates. The plate squeezes together, thus compressing the upper and lower surfaces of the weld workpiece. This compressive force, also called consolidation force, consolidates the plastic material within the weld nugget material as it is being stirred by the stir rod. The stir rod is positioned through the center of the top containment plate and protrudes midway through the opposite lower containment plate where it is mechanically captured. The upper and lower containment plates are separated by a

  16. Production of Forskolin by Axenic Coleus forskohlii Roots Cultivated in Shake Flasks and 20-l Glass Jar Bioreactors*.

    Krombholz, R; Mersinger, R; Kreis, W; Reinhard, E

    1992-08-01

    Root cultures of COLEUS FORSKOHLII Briq. were initiated from primary callus or IBA-treated suspension cultures and maintained on Gamborg's B5 medium containing 1 mg/l IBA. Transformed root cultures were established by infecting surface-sterilized leaves with AGROBACTERIUM RHIZOGENES strain 15834. Transformation was confirmed by mannopine detection. These cultures displayed the typical characteristics of hairy root cultures, with the sole exceptions of slow growth in hormone-free medium and accelerated growth on medium containing phytohormones. All root cultures examined formed forskolin and its derivatives in amounts ranging from 500 to 1300 mg/kg dry weight, corresponding to about 4 to 5 mg/l. During cultivation roots could be cut into small pieces without affecting growth and forskolin production. Scale-ups of the cultivation procedure were performed in 20-l glass jars with a working volume of 10 to 13l. Forskolin production in bioreactors was better than in shake flasks. Levels of almost 14 mg/l could be reached after 21 d of cultivation. As in the shake flask experiments cutting the roots did not affect growth or productivity in a negative way.

  17. Metal Flow in Friction Stir Welding

    Nunes, Arthur C., Jr.

    2006-01-01

    The plastic deformation field in Friction Stir Welding (FSW) is compared to that in metal cutting. A shear surface around the FSW tool analogous to the metal cutting shear plane is identified and comprises the basis of the "rotating plug" flow field model and the "wiping" model of tool interaction with weld metal. Within the context of these models: The FSW shear rate is estimated to be comparable to metal cutting shear rates. The effect of tool geometry on the FSW shear surface is discussed and related to published torque measurements. Various FS W structural features are explained, including a difference in structure of bimetallic welds when alloys on the advancing and retreating sides of the weld seam are exchanged. The joining mechanism and critical parameters of the FSW process are made clear.

  18. Tool Forces Developed During Friction Stir Welding

    Melendez, M.; Tang, W.; Schmidt, C.; McClure, J. C.; Nunes, A. C.; Murr, L. E.

    2003-01-01

    This paper will describe a technique for measuring the various forces and the torque that exist on the Friction Stir Welding pin tool. Results for various plunge depths, weld speeds, rotational speed, and tool configurations will be presented. Welds made on 6061 aluminum with typical welding conditions require a downward force of 2800 lbs. (12.5 kN) a longitudinal force in the direction of motion of 300 lbs (1.33 kN), a transverse force in the omega x v direction of 30 lbs (135 N). Aluminum 2195 under typical weld conditions requires a downward force of 3100 lbs. (1.38 kN), a longitudinal force of 920 lbs. (4.1 kN), and a transverse force of 45 lbs. (200 N) in the omega x v direction.

  19. Thermomechanical Modelling of Friction Stir Welding

    Hattel, Jesper Henri; Schmidt, Henrik Nikolaj Blicher; Tutum, Cem Celal

    2009-01-01

    Friction Stir Welding (FSW) is a fully coupled thermomechanical process and should in general be modelled as such. Basically, there are two major application areas of thermomechanical models in the investigation of the FSW process: i) Analysis of the thermomechanical conditions such as e.g. heat...... generation and local material deformation (often referred to as flow) during the welding process itself. ii) Prediction of the residual stresses that will be present in the joint structure post to welding. While the former in general will call for a fully-coupled thermomechanical procedure, however...... for the FSW process at hand, the heat generation must either be prescribed analytically or based on a fully coupled analysis of the welding process itself. Along this line, a recently proposed thermal-pseudo-mechanical model is presented in which the temperature dependent yield stress of the weld material...

  20. Friction stir welding of copper alloys

    Liu Shuhua; Liu Meng; Wang Deqing; Xu Zhenyue

    2007-01-01

    Copper plates,brass plates and copper/brass plates were friction stir welded with various parameters. Experimental results show that the microstructure of the weld is characterized by its much finer grains as contrasted with the coarse grains of parent materials and the heat-affected zones are very narrow. The microhardness of the copper weld is a little higher than that of parent plate. The microhardness of brass weld is about 25% higher than that of parent material. The tensile strength of copper joints increases with increasing welding speed in the test range. The range of parameters to obtain good welds for copper is much wider than that for brass. When different materials were welded, the position of copper plate before welding affected the quality of FSW joints. If the copper plate was put on the advancing side of weld, the good quality of weld could be got under proper parameters.

  1. Ultrasonically-assisted Thermal Stir Welding System

    Ding, R. Jeffrey (Inventor)

    2014-01-01

    A welding head assembly has a work piece disposed between its containment plates' opposing surfaces with the work piece being maintained in a plastic state thereof at least in a vicinity of the welding head assembly's stir rod as the rod is rotated about its longitudinal axis. The welding head assembly and the work piece experience relative movement there between in a direction perpendicular to the rod's longitudinal axis as the work piece is subjected to a compressive force applied by the containment plates. A first source coupled to the first containment plate applies a first ultrasonic wave thereto such that the first ultrasonic wave propagates parallel to the direction of relative movement. A second source coupled to the second containment plate applies a second ultrasonic wave thereto such that the second ultrasonic wave propagates parallel to the direction of relative movement.propagates parallel to the direction of relative movement.

  2. Horizontal stirring in the global ocean

    Hernández-Carrasco, I; Hernández-García, E; Turiel, A

    2011-01-01

    Horizontal mixing and the distribution of coherent structures in the global ocean are analyzed using Finite-Size Lyapunov Exponents (FSLE), computed for the surface velocity field derived from the Ocean general circulation model For the Earth Simulator (OFES). FSLEs measure horizontal stirring and dispersion; additionally, the transport barriers which organize the oceanic flow can roughly be identified with the ridges of the FSLE field. We have performed a detailed statistical study, particularizing for the behaviour of the two hemispheres and different ocean basins. The computed Probability Distributions Functions (PDFs) of FSLE are broad and asymmetric. Horizontal mixing is generally more active in the northern hemisphere than in the southern one. Nevertheless the Southern Ocean is the most active ocean, and the Pacific the less active one. A striking result is that the main currents can be classified in two 'activity classes': Western Boundary Currents, which have broad PDFs with large FSLE values, and Eas...

  3. In-process discontinuity detection during friction stir welding

    Shrivastava, Amber

    The objective of this work is to develop a method for detecting the creation of discontinuities (e.g., voids) during friction stir welding. Friction stir welding is inherently cost-effective, however, the need for significant weld inspection can make the process cost-prohibitive. A new approach to weld inspection is required -- where an in-situ characterization of weld quality can be obtained, reducing the need for post-process inspection. Friction stir welds with discontinuity and without discontinuity were created. In this work, discontinuities are generated by reducing the friction stir tool rotation frequency and increasing the tool traverse speed in order to create "colder" welds. During the welds, forces are measured. Discontinuity sizes for welds are measured by computerized tomography. The relationship between the force transients and the discontinuity sizes indicate that the force measurement during friction stir welding can be effectively used for detecting discontinuities in friction stir welds. The normalized force transient data and normalized discontinuity size are correlated to develop a criterion for discontinuity detection. Additional welds are performed to validate the discontinuity detection method. The discontinuity sizes estimated by the force measurement based method are in good agreement with the discontinuity sizes measured by computerized tomography. These results show that the force measurement based discontinuity detection model method can be effectively used to detect discontinuities during friction stir welding.

  4. Continuous wok-frying of vegetables:

    Adler-Nissen, Jens

    2007-01-01

    A new process for continuous stir-frying in industrial scale has been developed for producing convenience high-quality vegetables. The understanding of the dynamics of heat and mass transfer during stir-frying is crucial for up-scaling and controlling the process. The effect of different factors...... of loosely bound water from the vegetables allows the products to be frozen and re-heated without drip loss, and it is also an advantage when using them as ingredients in composite foods, such as pâtés. Examples developed by a professional chef indicate that he saved up to half of the cooking time compared...

  5. Applications of Friction Stir Processing during Engraving of Soft Materials

    V. Kočović

    2015-12-01

    Full Text Available Friction stir processing has extensive application in many technological operations. Application area of friction stir processing can be extended to the processing of non-metallic materials, such as wood. The paper examines the friction stir processing contact between a specially designed hard and temperature-resistant rotating tool and workpiece which is made of wood. Interval of speed slip and temperature level under which the combustion occurs and carbonization layer of soft material was determined. The results of the research can be applied in technological process of wood engraving operations which may have significant technological and aesthetic effects.

  6. Friction Stir Spot Welding of Advanced High Strength Steels

    Hovanski, Yuri; Grant, Glenn J.; Santella, M. L.

    2009-11-13

    Friction stir spot welding techniques were developed to successfully join several advanced high strength steels. Two distinct tool materials were evaluated to determine the effect of tool materials on the process parameters and joint properties. Welds were characterized primarily via lap shear, microhardness, and optical microscopy. Friction stir spot welds were compared to the resistance spot welds in similar strength alloys by using the AWS standard for resistance spot welding high strength steels. As further comparison, a primitive cost comparison between the two joining processes was developed, which included an evaluation of the future cost prospects of friction stir spot welding in advanced high strength steels.

  7. A METHOD AND APPARATUS FOR STIR-FRYING

    1999-01-01

    of a mechanically driven stirring means and scraping means in the form of a helix (4), the discrete pieces being stirred such that the orientation of same with respect to the heated surface (14) is altered such that the various surface portions of the discrete pieces are brought into heat conducting contact...... with the heated surface (14), at the same time scraping the heated surface (14) by means of the rim of the helix or by means of special scraping and stirring elements (27) arranged along the rim of the helix such that the entire area of the heated surface contacted by the discrete pieces is scraped mechanically...

  8. Development of Microstructure and Crystallographic Texture in a Double-Sided Friction Stir Welded Microalloyed Steel

    Rahimi, S.; Wynne, B. P.; Baker, T. N.

    2017-01-01

    The evolution of microstructure and crystallographic texture has been investigated in double-sided friction stir welded microalloyed steel, using electron backscatter diffraction (EBSD). The microstructure analyses show that the center of stirred zone reached a temperature between Ac1 and Ac3 during FSW, resulting in a dual-phase austenitic/ ferritic microstructure. The temperatures in the thermo-mechanically affected zone and the overlapped area between the first and second weld pass did not exceed the Ac1. The shear generated by the rotation probe occurs in austenitic/ferritic phase field where the austenite portion of the microstructure is transformed to a bainitic ferrite, on cooling. Analysis of crystallographic textures with regard to shear flow lines generated by the probe tool shows the dominance of simple shear components across the whole weld. The austenite texture at Ac1 - Ac3 is dominated by the B { {1bar{1}2} }stirred zone and the ferrites in the thermo-mechanically affected zones and the overlapped area underwent shear deformation with textures dominated by the D1 { {bar{1}bar{1}2} }weld pass. This is due to continuous dynamic strain-induced recrystallization as a result of simultaneous severe shear deformation and drastic undercooling.

  9. The Effect of Tool Position for Aluminum and Copper at High Rotational Friction Stir Welding

    Recep Çakır

    2015-12-01

    Full Text Available Friction Stir Welding (FSW is a solid state welding process used for welding similar and dissimilar materials. This welding technique allows welding of Aluminum alloys which present difficulties in fusion joining and allows different material couples to be welded continuously. In this study, 1050 aluminum alloy and commercially pure copper to increase heat input were produced at high rotation rate (2440 rev/min with four different pin position (0-1-1.5-2 mm and three different weld speeds (20-30-50 mm/min by friction stir welding. The influence of welding parameters on microstructure and mechanical properties of the joints was investigated. Tensile and bending tests and microhardness measurements were used to determine of mechanical properties. Nugget zone microstructures were investigated by optical microscope and scanning electron microscope (SEM and were analyzed in energy-dispersive X-ray spectroscopy (EDX. Depending on the XRD analysis results intermetallic phase was observed to form in the interfacial region. In the tensile test results, 83.55% weld performance was obtained in the friction stir welding merge of Al-Cu.

  10. A novel milliliter-scale chemostat system for parallel cultivation of microorganisms in stirred-tank bioreactors.

    Schmideder, Andreas; Severin, Timm Steffen; Cremer, Johannes Heinrich; Weuster-Botz, Dirk

    2015-09-20

    A pH-controlled parallel stirred-tank bioreactor system was modified for parallel continuous cultivation on a 10 mL-scale by connecting multichannel peristaltic pumps for feeding and medium removal with micro-pipes (250 μm inner diameter). Parallel chemostat processes with Escherichia coli as an example showed high reproducibility with regard to culture volume and flow rates as well as dry cell weight, dissolved oxygen concentration and pH control at steady states (n=8, coefficient of variation bioreactor on a liter-scale. Thus, parallel and continuously operated stirred-tank bioreactors on a milliliter-scale facilitate timesaving and cost reducing steady state studies with microorganisms. The applied continuous bioreactor system overcomes the drawbacks of existing miniaturized bioreactors, like poor mass transfer and insufficient process control.

  11. Friction stir processing (FSP: refining microstructures and improving properties

    McNelley, T. R.

    2010-12-01

    Full Text Available FSP is reviewed as an allied technology of friction stir welding (FSW and additional considerations such as processing pattern and step over distance are introduced. The application of FSP to continuously cast AA5083 material in the as-cast condition is described and the extent of grain refinement and homogenization of microstructure is documented. The FSP-induced superplastic response of this material is compared to the response of conventionally processed AA5083 and the improved ductility of the FSP material is related to grain refinement and microstructure homogenization.

    Se revisa el procesado por fricción batida (FSP como un aliado tecnológico de la soldadura por fricción batida (FSW y se introducen consideraciones adicionales tales como el patrón de procesado y el paso en función de la distancia. Se describe la aplicación de FSP al material AA5083 por colada continua en la condición de colada y se documenta el grado de afino de grano y homogeneización de la microestructura. La respuesta de superplasticidad inducida por FSP se compara con la respuesta de la aleación AA5083 procesada convencionalmente y la mejora de ductilidad del material FSP se relaciona con el afino de grano y la homogeneización de la microestructura.

  12. Reconstruction of Clear-PEM data with STIR

    Martins, M V; Rodrigues, P; Trindade, A; Oliveira, N; Correia, M; Cordeiro, H; Ferreira, N C; Varela, J; Almeida, P

    2006-01-01

    The Clear-PEM scanner is a device based on planar detectors that is currently under development within the Crystal Clear Collaboration, at CERN. The basis for 3D image reconstruction in Clear-PEM is the software for tomographic image reconstruction (STIR). STIR is an open source object-oriented library that efficiently deals with the 3D positron emission tomography data sets. This library was originally designed for the traditional cylindrical scanners. In order to make its use compatible with planar scanner data, new functionalities were introduced into the library's framework. In this work, Monte Carlo simulations of the Clear-PEM scanner acquisitions were used as input for image reconstruction with the 3D OSEM algorithm available in STIR. The results presented indicate that dual plate PEM data can be accurately reconstructed using the enhanced STIR framework.

  13. Low temperature friction stir welding of P91 steel

    Prasad Rao Kalvala

    2016-08-01

    Full Text Available Bead-on-plate friction stir welds were made on P91 alloy with low and high rotational speeds (100 and 1000 RPM to study their effects on weld microstructural changes and impression creep behavior. Temperatures experienced by the stir zone were recorded at the weld tool tip. Different zones of welds were characterized for their microstructural changes, hardness and creep behavior (by impression creep tests. The results were compared with submerged arc fusion weld. Studies revealed that the stir zone temperature with 100 RPM was well below Ac1 temperature of P91 steel while it was above Ac3 with 1000 RPM. The results suggest that the microstructural degradation in P91 welds can be controlled by low temperature friction stir welding technique.

  14. In-Space Friction Stir Welding Machine Project

    National Aeronautics and Space Administration — Longhurst Engineering, PLC, and Vanderbilt University propose an in-space friction stir welding (FSW) machine for joining complex structural aluminum components. The...

  15. Friction Stir Processing for Efficient Manufacturing

    Mr. Christopher B. Smith; Dr. Oyelayo Ajayi

    2012-01-31

    Friction at contacting surfaces in relative motion is a major source of parasitic energy loss in machine systems and manufacturing processes. Consequently, friction reduction usually translates to efficiency gain and reduction in energy consumption. Furthermore, friction at surfaces eventually leads to wear and failure of the components thereby compromising reliability and durability. In order to reduce friction and wear in tribological components, material surfaces are often hardened by a variety of methods, including conventional heat treatment, laser surface hardening, and thin-film coatings. While these surface treatments are effective when used in conjunction with lubrication to prevent failure, they are all energy intensive and could potentially add significant cost. A new concept for surface hardening of metallic materials and components is Friction Stir Processing (FSP). Compared to the current surface hardening technologies, FSP is more energy efficient has no emission or waste by products and may result in better tribological performance. FSP involves plunging a rotating tool to a predetermined depth (case layer thickness) and translating the FSP tool along the area to be processed. This action of the tool produces heating and severe plastic deformation of the processed area. For steel the temperature is high enough to cause phase transformation, ultimately forming hard martensitic phase. Indeed, FSP has been used for surface modification of several metals and alloys so as to homogenize the microstructure and refine the grain size, both of which led to improved fatigue and corrosion resistance. Based on the effect of FSP on near-surface layer material, it was expected to have beneficial effects on friction and wear performance of metallic materials. However, little or no knowledge existed on the impact of FSP concerning friction and wear performance the subject of the this project and final report. Specifically for steel, which is the most dominant

  16. Mechanism for Self-Reacted Friction Stir Welding

    Venable, Richard; Bucher, Joseph

    2004-01-01

    A mechanism has been designed to apply the loads (the stirring and the resection forces and torques) in self-reacted friction stir welding. This mechanism differs somewhat from mechanisms used in conventional friction stir welding, as described below. The tooling needed to apply the large reaction loads in conventional friction stir welding can be complex. Self-reacted friction stir welding has become popular in the solid-state welding community as a means of reducing the complexity of tooling and to reduce costs. The main problems inherent in self-reacted friction stir welding originate in the high stresses encountered by the pin-and-shoulder assembly that produces the weld. The design of the present mechanism solves the problems. The mechanism includes a redesigned pin-and-shoulder assembly. The welding torque is transmitted into the welding pin by a square pin that fits into a square bushing with set-screws. The opposite or back shoulder is held in place by a Woodruff key and high-strength nut on a threaded shaft. The Woodruff key reacts the torque, while the nut reacts the tensile load on the shaft.

  17. Surface modification of Poly(tetrafluorethylene) magnetic stirring bars with plasma of hexamethyldisiloxane and its applications in the stir bar sorptive extraction technique

    R. Baeza-Marrufo; P. Acereto-Escoffié; C. Carrera-Figueiras; D. Muñoz-Rodriguez; A. Ávila-Ortega; J. A. López-Barrera; J. Morales-Corona; Olayo-González, R.

    2012-01-01

    This paper explores the potential of plasma polymerization to modify the surface of stir bars for its use in Stir Bar Sorptive Extraction (SBSE). The modification of the poly(tetrafluoroethylene) surface of stir bars was done through plasma polymerization of hexamethyldisiloxane (30 min, 110 W and 1.4×10-1 Torr). The coating was characterized by contact angle, Fourier transform infrared spectroscopy, energy dispersive x-ray analysis and scanning electron microscopy. The modified stir bars wer...

  18. Effect of Friction Stir Welding Parameters on the Mechanical and Microstructure Properties of the Al-Cu Butt Joint

    Sare Celik

    2016-05-01

    Full Text Available Friction Stir Welding (FSW is a solid-state welding process used for welding similar and dissimilar materials. FSW is especially suitable to join sheet Al alloys, and this technique allows different material couples to be welded continuously. In this study, 1050 Al alloys and commercially pure Cu were produced at three different tool rotation speeds (630, 1330, 2440 rpm and three different tool traverse speeds (20, 30, 50 mm/min with four different tool position (0, 1, 1.5, 2 mm by friction stir welding. The influence of the welding parameters on the microstructure and mechanical properties of the joints was investigated. Tensile and bending tests and microhardness measurements were used to determine the mechanical properties. The microstructures of the weld zone were investigated by optical microscope and scanning electron microscope (SEM and were analyzed in an energy dispersed spectrometer (EDS. Intermetallic phases were detected based on the X-ray diffraction (XRD analysis results that evaluated the formation of phases in the weld zone. When the welding performance of the friction stir welded butt joints was evaluated, the maximum value obtained was 89.55% with a 1330 rpm tool rotational speed, 20 mm/min traverse speed and a 1 mm tool position configuration. The higher tensile strength is attributed to the dispersion strengthening of the fine Cu particles distributed over the Al material in the stir zone region.

  19. Metal Flow During Friction Stir Welding

    Guerra, M.; Schmidt, C.; McClure, J. C.; Murr, L. E.; Nunes, A. C.; Munafo, Paul M. (Technical Monitor)

    2001-01-01

    The flow of metal during Friction Stir Welding is clarified using a faying surface tracer and a nib frozen in place during welding. It is shown that material is transported by two processes. The first is a wiping of material from the advancing front side of the nib onto a plug of material that rotates and advances with the nib. The material undergoes a helical motion within the plug that both rotates and advances with the plug and descends in the wash of the threads on the nib and rises on the outer part of the plug. After one or more rotations, this material is sloughed off the plug in its wake, primarily on the advancing side. The second process is an entrainment of material from the front retreating side of the nib that fills in between the sloughed off pieces from the advancing side. These two processes produce material with different mechanical properties and the strength of a weld should depend on the relative importance of the processes.

  20. Inspecting Friction Stir Welding using Electromagnetic Probes

    Kinchen, David G.

    2004-01-01

    A report describes the use of advanced electromagnetic probes to measure the dimensions, the spatial distribution of electrical conductivity, and related other properties of friction stir welds (FSWs) between parts made of the same or different aluminum alloy(s). The probes are of the type described in in another Tech Brief. To recapitulate: A probe of this type is essentially an eddy-current probe that includes a primary (driver) winding that meanders and multiple secondary (sensing) windings that meander along the primary winding. Electrical conductivity is commonly used as a measure of heat treatment and tempering of aluminum alloys, but prior to the development of these probes, the inadequate sensitivity and limited accuracy of electrical-conductivity probes precluded such use on FSWs between different aluminum alloys, and the resolution of those probes was inadequate for measurement of FSW dimensions with positions and metallurgical properties. In contrast, the present probes afford adequate accuracy and spatial resolution for the purposes of measuring the dimensions of FSW welds and correlating spatially varying electrical conductivities with metallurgical properties, including surface defects.

  1. The Plunge Phase of Friction Stir Welding

    McClure, John C.

    2005-01-01

    The many advantages of Friction Stir Welding have led to a relatively rapid acceptance in the often conservative welding community. Because the process is so different from traditional fusion welding, with which most investigators are most familiar, there remain many aspects of FSW for which there is no clear consensus. For example, the well known onion rings seen in transverse sections have been variously interpreted as grain size variations, variation in density of second phase particles and parts of the carousel of material rotating with the pin that have been shed from the carousel. Using Orientation Imaging Microscopy, Schneider has recently noted that the onion rings have a different orientation (and hence etch differently) than the surrounding material, and this orientation is consistent with slip plane orientations at the edge of the carousel. Likewise, the forces and torque exerted by the FSW tool on the work piece largely remain unaccounted for. Although these forces are routinely measured by investigators with commercial instrumented welders, they are rarely reported or even qualitatively analyzed. This paper will introduce a model based on a carousel or disk of material that rotates with the tool to estimate the torque and plunge force required to plunge a tool into the work piece. A stationary tool is modeled rather than the moving tool because effects such as thermal transients and metallurgical changes in the sample (primarily aging in aluminum) can be more easily accounted for. It is believed, however, that with some modifications the model should be applicable to a moving tool also.

  2. Magnetic properties of friction stir processed composite

    Das, Shamiparna; Martinez, Nelson Y.; Das, Santanu; Mishra, Rajiv S.; Grant, Glenn J.; Jana, Saumyadeep; Polikarpov, Evgueni

    2016-03-29

    There are many existing inspection systems each with their own advantages and drawbacks. These usually comprise of semi-remote sensors which frequently causes difficulty in reaching complex areas of a component. This study proposes to overcome that difficulty by developing embedded functional composites. Through this route, embedding can be achieved in virtually any component part and can be periodically interrogated by a reading device. The “reinforcement rich” processed areas can then be utilized to record properties like strain, temperature, stress state etc. depending on the reinforcement material. In this work, friction stir processing (FSP) was utilized to fabricate a magnetostrictive composite by embedding galfenol particles into a nonmagnetic aluminum (Al) matrix. It targets to develop a composite that produces strain in a varying magnetic field. Reinforcements were observed to be distributed uniformly in the matrix. Magnetization curves were studied using a vibrating sample magnetometer (VSM). A simple and cheap setup was developed to measure the magnetostrictive strain of the composites. Important factors affecting the magnetic properties were identified and ways to improve the magnetic properties discussed.

  3. Magnetic Properties of Friction Stir Processed Composite

    Das, Shamiparna; Martinez, Nelson Y.; Das, Santanu; Mishra, Rajiv S.; Grant, Glenn J.; Jana, Saumyadeep; Polikarpov, Evgueni

    2016-07-01

    Of the many existing inspection or monitoring systems, each has its own advantages and drawbacks. These systems are usually comprised of semi-remote sensors that frequently cause difficulty in reaching complex areas of a component. This study proposes to overcome that difficulty by developing embedded functional composites, so that embedding can be achieved in virtually any component part and periodically can be interrogated by a reading device. The "reinforcement rich" processed areas can then be used to record properties such as strain, temperature, and stress state, to name a few, depending on the reinforcement material. Friction stir processing was used to fabricate a magnetostrictive composite by embedding galfenol particles into a nonmagnetic aluminum matrix. The aim was to develop a composite that produces strain in response to a varying magnetic field. Reinforcements were distributed uniformly in the matrix. Magnetization curves were studied using a vibrating sample magnetometer. A simple and cost-effective setup was developed to measure the magnetostrictive strain of the composites. Important factors affecting the magnetic properties were identified and the processing route was modified to improve the magnetic response.

  4. Impeller Submergence Depth for Stirred Tanks

    Thiyam T. Devi

    2011-11-01

    Full Text Available Impeller submergence governs the performance of mixing tanks employed in oxygen transfer operation. Present work experimentally investigates the effect of impeller submergence depths on oxygen transfer and corresponding power consumption. It has been found that at higher range of impeller submergence, mixing tanks consume less power and gives higher values of oxygen transfer coefficient. Optimal range of submergence depth is 0.7 to 0.9 times the impeller diameter. Copyright ©2011 BCREC UNDIP. All rights reserved.(Received: 4th March 2011; Revised: 12nd July 2011; Accepted: 14th July 2011[How to Cite: T.T. Devi, A.P. Sinha, M. Thakre, and B. Kumar. (2011. Impeller Submergence Depth for Stirred Tanks. Bulletin of Chemical Reaction Engineering & Catalysis, 6 (2: 123-128. doi:10.9767/bcrec.6.2.826.123-128][How to Link / DOI: http://dx.doi.org/10.9767/bcrec.6.2.826.123-128 || or local: http://ejournal.undip.ac.id/index.php/bcrec/article/view/826] | View in 

  5. Topological optimisation of rod-stirring devices

    Finn, Matthew D

    2011-01-01

    There are many industrial situations where rods are used to stir a fluid, or where rods repeatedly stretch a material such as bread dough or taffy. The goal in these applications is to stretch either material lines (in a fluid) or the material itself (for dough or taffy) as rapidly as possible. The growth rate of material lines is conveniently given by the topological entropy of the rod motion. We discuss the problem of optimising such rod devices from a topological viewpoint. We express rod motions in terms of generators of the braid group, and assign a cost based on the minimum number of generators needed to write the braid. We show that for one cost function -- the topological entropy per generator -- the optimal growth rate is the logarithm of the golden ratio. For a more realistic cost function,involving the topological entropy per operation where rods are allowed to move together, the optimal growth rate is the logarithm of the silver ratio, $1+\\sqrt{2}$. We show how to construct devices that realise th...

  6. Nondestructive Ultrasonic Inspection of Friction Stir Welds

    Tabatabaeipour, M.; Hettler, J.; Delrue, S.; Van Den Abeele, K.

    Friction Stir Welding (FSW) is a relatively new solid-state welding procedure developed at The Welding Institute (TWI-UK) and the technique is widely employed for welding aluminum alloys in various applications. In order to examine the quality of the welds and to detect a variety of welding flaws such as wormholes and root-flaws, it is required to develop a methodical inspection technique that can be used for the identification and localization of such defects. The most prevalent and risky defect in this type of welding is the barely visible root flaw with a length varying from 100-700 μm. Due to the extreme characteristics of the flaw, off-the-shelf ultrasonic weld inspection methods are not always able to readily detect this type of minute defect feature. Here, we propose a novel approach to characterize root flaws using an oblique incident ultrasonic C-scan backscattering analysis. The implementation consists of an immersion ultrasonic testing method in pulse echo (i.e. backscatter) mode with a 3.5 MHz transducer, and makes use of an empirical procedure to engender of a shear wave dominated excitation at the root surface, and to properly gate the received signal for root flaw examination. By scanning the surface above the welded component, a C-scan image displaying the backscatter response from the root surface of the nugget zone can be obtained which allows a simple interpretation of the root flaw status of the weld.

  7. Texture Analyses of Ti/Al2O3 Nanocomposite Produced Using Friction Stir Processing

    Shafiei-Zarghani, Aziz; Kashani-Bozorg, Seyed Farshid; Gerlich, Adrian P.

    2016-11-01

    The texture evolution of Ti/Al2O3 nanocomposite fabricated using friction stir processing (FSP) was investigated at both macroscopic and microscopic levels employing X-ray diffraction and electron backscattering diffraction techniques. The developed textures were compared with ideal shear textures of hexagonal close-packed (hcp) structure, revealing that the fabricated nanocomposite is dominated by the P 1 hcp (fiber { 10bar{1}1} continuous dynamic recrystallization as well as increasing the fraction of high-angle grain boundaries within the developed microstructure.

  8. Continuous lactose fermentation by Clostridium acetobutylicum - Assessment of solventogenic kinetics

    Procentese, Alessandra; Raganati, Francesca; Olivieri, Giuseppe; Russo, Maria Elena; Salatino, Piero; Marzocchella, Antonio

    2015-01-01

    This work reports the results of a series of tests on the specific butanol production rate by Clostridium acetobutylicum continuous cultures. The tests were carried out using lactose as carbon source to mimic cheese-whey. A continuous stirred tank reactor equipped with a microfiltration unit was

  9. Analysis and Comparison of Friction Stir Welding and Laser Assisted Friction Stir Welding of Aluminum Alloy

    Sabina Luisa Campanelli

    2013-12-01

    Full Text Available Friction Stir Welding (FSW is a solid-state joining process; i.e., no melting occurs. The welding process is promoted by the rotation and translation of an axis-symmetric non-consumable tool along the weld centerline. Thus, the FSW process is performed at much lower temperatures than conventional fusion welding, nevertheless it has some disadvantages. Laser Assisted Friction Stir Welding (LAFSW is a combination in which the FSW is the dominant welding process and the laser pre-heats the weld. In this work FSW and LAFSW tests were conducted on 6 mm thick 5754H111 aluminum alloy plates in butt joint configuration. LAFSW is studied firstly to demonstrate the weldability of aluminum alloy using that technique. Secondly, process parameters, such as laser power and temperature gradient are investigated in order to evaluate changes in microstructure, micro-hardness, residual stress, and tensile properties. Once the possibility to achieve sound weld using LAFSW is demonstrated, it will be possible to explore the benefits for tool wear, higher welding speeds, and lower clamping force.

  10. Simulation of fluid flow induced by opposing ac magnetic fields in a continuous casting mold

    Chang, F.C.; Hull, J.R. [Argonne National Lab., IL (United States); Beitelman, L. [J. Mulcahy Enterprises, Whitby, ON (Canada)

    1995-07-01

    A numerical simulation was performed for a novel electromagnetic stirring system employing two rotating magnetic fields. The system controls stirring flow in the meniscus region of a continuous casting mold independently from the stirring induced within the remaining volume of the mold by a main electromagnetic stirrer (M-EMS). This control is achieved by applying to the meniscus region an auxiliary electromagnetic field whose direction of rotation is opposite to that of the main magnetic field produced by the M-EMS. The model computes values and spatial distributions of electromagnetic parameters and fluid flow in the stirred pools of mercury in cylindrical and square geometries. Also predicted are the relationships between electromagnetics and fluid flows pertinent to a dynamic equilibrium of the opposing stirring swirls in the meniscus region. Results of the numerical simulation compared well with measurements obtained from experiments with mercury pools.

  11. Thermal Stir Welding Development at Marshall Space Flight Center

    Ding, Robert J.

    2008-01-01

    Solid state welding processes have become the focus of welding process development at NASA's Marshall Space Flight Center. Unlike fusion weld processes such as tungsten inert gas (TIG), variable polarity plasma arc (VPPA), electron beam (EB), etc., solid state welding processes do not melt the material during welding. The resultant microstructure can be characterized as a dynamically recrystallized morphology much different than the casted, dentritic structure typical of fusion weld processes. The primary benefits of solid state processes over fusion weld processes include superior mechanic properties and the elimination of thermal distortion and residual stresses. These solid state processes attributes have profoundly influenced the direction of advanced welding research and development within the NASA agency. Thermal Stir Welding (TSW) is a new solid state welding process being developed at the Marshall Space Flight Center. Unlike friction stir welding, the heating, stirring and forging elements of the weld process can be decoupled for independent control. An induction coil induces energy into a workpiece to attain a desired plastic temperature. An independently controlled stir rod, captured within non-rotating containment plates, then stirs the plasticized material followed by forging plates/rollers that work the stirred weld joint. The independent control (decoupling) of heating, stirring and forging allows, theoretically, for the precision control of microstructure morphology. The TSW process is being used to evaluate the solid state joining of Haynes 230 for ARES J-2X applications. It is also being developed for 500-in (12.5 mm) thick commercially pure grade 2 titanium for navy applications. Other interests include Inconel 718 and stainless steel. This presentation will provide metallurgical and mechanical property data for these high melting temperature alloys.

  12. A new microfluidic concept for parallel operated milliliter-scale stirred tank bioreactors.

    Gebhardt, Gabi; Hortsch, Ralf; Kaufmann, Klaus; Arnold, Matthias; Weuster-Botz, Dirk

    2011-01-01

    Parallel miniaturized stirred tank bioreactors are an efficient tool for "high-throughput bioprocess design." As most industrial bioprocesses are pH-controlled and/or are operated in a fed-batch mode, an exact scale-down of these reactions with continuous dosing of fluids into the miniaturized bioreactors is highly desirable. Here, we present the development, characterization, and application of a novel concept for a highly integrated microfluidic device for a bioreaction block with 48 parallel milliliter-scale stirred tank reactors (V = 12 mL). The device consists of an autoclavable fluidic section to dispense up to three liquids individually per reactor. The fluidic section contains 144 membrane pumps, which are magnetically driven by a clamped-on actuator section. The micropumps are designed to dose 1.6 μL per pump lift. Each micropump enables a continuous addition of liquid with a flow rate of up to 3 mL h(-1) . Viscous liquids up to a viscosity of 8.2 mPa s (corresponds to a 60% v/v glycerine solution) can be pumped without changes in the flow rates. Thus, nearly all feeding solutions can be delivered, which are commonly used in bioprocesses. The functionality of the first prototype of this microfluidic device was demonstrated by double-sided pH-controlled cultivations of Saccharomyces cerevisiae based on signals of fluorimetric sensors embedded at the bottom of the bioreactors. Furthermore, fed-batch cultivations with constant and exponential feeding profiles were successfully performed. Thus, the presented novel microfluidic device will be a useful tool for parallel and, thus, efficient optimization of controlled fed-batch bioprocesses in small-scale stirred tank bioreactors. This can help to reduce bioprocess development times drastically.

  13. Friction Stir Processing of Particle Reinforced Composite Materials

    Daniel Solomon

    2010-01-01

    Full Text Available The objective of this article is to provide a review of friction stir processing (FSP technology and its application for microstructure modification of particle reinforced composite materials. The main focus of FSP was on aluminum based alloys and composites. Recently, many researchers have investigated this technology for treating other alloys and materials including stainless steels, magnesium, titanium, and copper. It is shown that FSP technology is very effective in microstructure modification of reinforced metal matrix composite materials. FSP has also been used in the processing and structure modification of polymeric composite materials. Compared with other manufacturing processes, friction stir processing has the advantage of reducing distortion and defects in materials. The layout of this paper is as follows. The friction stir processing technology will be presented first. Then, the application of this technology in manufacturing and structure modification of particle reinforced composite materials will be introduced. Future application of friction stir processing in energy field, for example, for vanadium alloy and composites will be discussed. Finally, the challenges for improving friction stir processing technology will be mentioned.

  14. Wet gringing of zeolite in stirred media mill

    Mucsi, G.; Bohács, K.

    2016-04-01

    In the present study the results of systematic experimental series are presented with the specific goal of optimizing the zeolite nanoparticles' production using a wet stirred media mill. The diameter of the grinding media as well as the rotor velocity were varied in the experiments. Particle size distribution and "outer" specific surface area of the ground samples were measured by a laser particle size analyser. Additionally, BET, XRD and FT-IR analyses were performed for the characterization of the "total" specific surface area as well as the crystalline and material structure, respectively. Based on the results of the laboratory experiments it was found that wet stirred media milling provided significant reductions in the particle size of zeolite. Furthermore, the crystallinity of the samples also decreased, so not only the physical but the mineralogical characteristics of zeolite can be controlled by stirred media milling.

  15. Nanoscale magnetic stirring bars for heterogeneous catalysis in microscopic systems.

    Yang, Shuliang; Cao, Changyan; Sun, Yongbin; Huang, Peipei; Wei, Fangfang; Song, Weiguo

    2015-02-23

    Nanometer-sized magnetic stirring bars containing Pd nanoparticles (denoted as Fe3 O4 -NC-PZS-Pd) for heterogeneous catalysis in microscopic system were prepared through a facile two-step process. In the hydrogenation of styrene, Fe3 O4 -NC-PZS-Pd showed an activity similar to that of the commercial Pd/C catalyst, but much better stability. In microscopic catalytic systems, Fe3 O4 -NC-PZS-Pd can effectively stir the reaction solution within microdrops to accelerate mass transfer, and displays far better catalytic activity than the commercial Pd/C for the hydrogenation of methylene blue in an array of microdroplets. These results suggested that the Fe3 O4 -NC-PZS-Pd could be used as nanoscale stirring bars in nanoreactors.

  16. The Effect of Stirring on the Morphology of Birnessite Nanoparticles

    Marcos A. Cheney

    2008-01-01

    Full Text Available The effect of mechanical stirring on the morphology of hexagonal layer-structure birnessite nanoparticles produced from decomposition of KMnO4 in dilute aqueous H2SO4 is investigated, with characterization by X-ray diffraction (XRD, scanning electron microscopy (SEM, transmission electron microscopy (TEM, high-resolution transmission electron microscopy (HRTEM, thermogravimetric analysis (TGA, and N2 adsorption (BET. Mechanical stirring during an initial stage of synthesis is shown to produce black birnessite containing nanofibers, whereas granular particulates of brown birnessite are produced without stirring. This is the first reduction synthesis of black birnessite nanoparticles with dendritic morphology without any use of organic reductant, and suggests that a particular morphology can arise from structural preferences of Mn in acidic conditions rather than particular organic reactants. These results enlighten the possibility of synthesizing nanoparticles with controlled size and morphology.

  17. MICROSTRUCTURAL STUDIES OF FRICTION STIR WELDED AZ31 MAGNESIUM ALLOY

    H.Zhang; S.B.Lin; L.Wu; J.C.Feng

    2004-01-01

    Friction stir welding achieves the weld in solid phase by locally introducing frictional heating and plastic flow arising from rotation of the welding tool, which results in changes in the local microstructure of magnesium alloy. The purpose in the paper is to study the microstructures of friction stir welded AZ3I magnesium alloy. Residual microstructures,including dynamic re-crystallization zone and nugget structures have been systematically investigated utilizing optical microscopy (OM), scanning electric microscopy (SEM),transmission electron microscopy (TEM) with energy dispersive spectroscopy (EDS), X-ray diffraction (XRD) and micro-hardness. AZ31 magnesium alloy has been successfully friction stir welded and exhibits the variations of microstructure including dynamically recrystallized,equaxied grains in the weld nugget. Residual hardness in the nugget was found slightly lower than the parent but not too obvious.

  18. Weld Nugget Temperature Control in Thermal Stir Welding

    Ding, R. Jeffrey (Inventor)

    2014-01-01

    A control system for a thermal stir welding system is provided. The control system includes a sensor and a controller. The sensor is coupled to the welding system's containment plate assembly and generates signals indicative of temperature of a region adjacent and parallel to the welding system's stir rod. The controller is coupled to the sensor and generates at least one control signal using the sensor signals indicative of temperature. The controller is also coupled to the welding system such that at least one of rotational speed of the stir rod, heat supplied by the welding system's induction heater, and feed speed of the welding system's weld material feeder are controlled based on the control signal(s).

  19. A Brief Introduction to the Theory of Friction Stir Welding

    Nunes, Arthur C., Jr.

    2008-01-01

    Friction stir welding (FSW) is a solid state welding process invented in 1991 at The Welding Institute in the United Kingdom. A weld is made in the FSW process by translating a rotating pin along a weld seam so as to stir the sides of the seam together. FSW avoids deleterious effects inherent in melting and is already an important welding process for the aerospace industry, where welds of optimal quality are demanded. The structure of welds determines weld properties. The structure of friction stir welds is determined by the flow field in the weld metal in the vicinity of the weld tool. A simple kinematic model of the FSW flow field developed at Marshall Space Flight Center, which enables the basic features of FSW microstructure to be understood and related to weld process parameters and tool design, is explained.

  20. Process Model for Friction Stir Welding

    Adams, Glynn

    1996-01-01

    Friction stir welding (FSW) is a relatively new process being applied for joining of metal alloys. The process was initially developed by The Welding Institute (TWI) in Cambridge, UK. The FSW process is being investigated at NASA/MSEC as a repair/initial weld procedure for fabrication of the super-light-weight aluminum-lithium shuttle external tank. The FSW investigations at MSFC were conducted on a horizontal mill to produce butt welds of flat plate material. The weldment plates are butted together and fixed to a backing plate on the mill bed. A pin tool is placed into the tool holder of the mill spindle and rotated at approximately 400 rpm. The pin tool is then plunged into the plates such that the center of the probe lies at, one end of the line of contact, between the plates and the shoulder of the pin tool penetrates the top surface of the weldment. The weld is produced by traversing the tool along the line of contact between the plates. A lead angle allows the leading edge of the shoulder to remain above the top surface of the plate. The work presented here is the first attempt at modeling a complex phenomenon. The mechanical aspects of conducting the weld process are easily defined and the process itself is controlled by relatively few input parameters. However, in the region of the weld, plasticizing and forging of the parent material occurs. These are difficult processes to model. The model presented here addresses only variations in the radial dimension outward from the pin tool axis. Examinations of the grain structure of the weld reveal that a considerable amount of material deformation also occurs in the direction parallel to the pin tool axis of rotation, through the material thickness. In addition, measurements of the axial load on the pin tool demonstrate that the forging affect of the pin tool shoulder is an important process phenomenon. Therefore, the model needs to be expanded to account for the deformations through the material thickness and the

  1. Heat Control via Torque Control in Friction Stir Welding

    Venable, Richard; Colligan, Kevin; Knapp, Alan

    2004-01-01

    In a proposed advance in friction stir welding, the torque exerted on the workpiece by the friction stir pin would be measured and controlled in an effort to measure and control the total heat input to the workpiece. The total heat input to the workpiece is an important parameter of any welding process (fusion or friction stir welding). In fusion welding, measurement and control of heat input is a difficult problem. However, in friction stir welding, the basic principle of operation affords the potential of a straightforward solution: Neglecting thermal losses through the pin and the spindle that supports it, the rate of heat input to the workpiece is the product of the torque and the speed of rotation of the friction stir weld pin and, hence, of the spindle. Therefore, if one acquires and suitably processes data on torque and rotation and controls the torque, the rotation, or both, one should be able to control the heat input into the workpiece. In conventional practice in friction stir welding, one uses feedback control of the spindle motor to maintain a constant speed of rotation. According to the proposal, one would not maintain a constant speed of rotation: Instead, one would use feedback control to maintain a constant torque and would measure the speed of rotation while allowing it to vary. The torque exerted on the workpiece would be estimated as the product of (1) the torque-multiplication ratio of the spindle belt and/or gear drive, (2) the force measured by a load cell mechanically coupled to the spindle motor, and (3) the moment arm of the load cell. Hence, the output of the load cell would be used as a feedback signal for controlling the torque (see figure).

  2. Process optimization of friction stir welding based on thermal models

    Larsen, Anders Astrup

    2010-01-01

    This thesis investigates how to apply optimization methods to numerical models of a friction stir welding process. The work is intended as a proof-of-concept using different methods that are applicable to models of high complexity, possibly with high computational cost, and without the possibility...... information of the high-fidelity model. The optimization schemes are applied to stationary thermal models of differing complexity of the friction stir welding process. The optimization problems considered are based on optimizing the temperature field in the workpiece by finding optimal translational speed...

  3. Near Net Manufacturing Using Thin Gage Friction Stir Welding

    Takeshita, Jennifer; Potter, David; Holquin, Michael

    2006-01-01

    Friction Stir Welding (FSW) and near net spin forming of FSW aluminumn blanks were investigated for large-scale pressure vessel applications. With a specific focus on very thin gage 2xxx and 7xxx aluminum alloys, the program concentrated on the following: the criteria used for material selection, a potential manufacturing flow, and the effectiveness and associated risks of near net spin forming. Discussion will include the mechanical properties of the friction stir welds and the parent material from before and after the spin forming process. This effort was performed under a NASA Space Exploration initiative focused on increasing the affordability, reliability and performance of pressure vessels larger than 10 ft. diameter.

  4. Unraveling the Processing Parameters in Friction Stir Welding

    Schneider, Judy; Nunes, Arthur C., Jr.

    2005-01-01

    In friction stir welding (FSW), a rotating threaded pin tool is translated along a weld seam, literally stirring the edges of the seam together. To determine optimal processing parameters for producing a defect free weld, a better understanding of the resulting metal deformation flow path or paths is required. In this study, various markers are used to trace the flow paths of the metal. X-ray radiographs record the segmentation and position of the wire. Several variations in the trajectories can be differentiated within the weld zone.

  5. Numerical optimisation of friction stir welding: review of future challenges

    Tutum, Cem Celal; Hattel, Jesper Henri

    2011-01-01

    During the last decade, the combination of increasingly more advanced numerical simulation software with high computational power has resulted in models for friction stir welding (FSW), which have improved the understanding of the determining physical phenomena behind the process substantially....... This has made optimisation of certain process parameters possible and has in turn led to better performing friction stir welded products, thus contributing to a general increase in the popularity of the process and its applications. However, most of these optimisation studies do not go well beyond manual...

  6. Friction stir weld tools having fine grain structure

    Grant, Glenn J.; Frye, John G.; Kim, Jin Yong; Lavender, Curt A.; Weil, Kenneth Scott

    2016-03-15

    Tools for friction stir welding can be made with fewer process steps, lower cost techniques, and/or lower cost ingredients than other state-of-the-art processes by utilizing improved compositions and processes of fabrication. Furthermore, the tools resulting from the improved compositions and processes of fabrication can exhibit better distribution and homogeneity of chemical constituents, greater strength, and/or increased durability. In one example, a friction stir weld tool includes tungsten and rhenium and is characterized by carbide and oxide dispersoids, by carbide particulates, and by grains that comprise a solid solution of the tungsten and rhenium. The grains do not exceed 10 micrometers in diameter.

  7. Interfacial and Mechanical Behavior of AA5456 Filling Friction-Stir-Welded Lap Joints Using Similar and Dissimilar Pins

    Behmand, Saleh Alaei; Mirsalehi, Seyyed Ehsan; Omidvar, Hamid; Safarkhanian, Mohammad Ali

    2016-10-01

    In this article, filling friction stir welding (FFSW) of the remaining exit holes of AA5456 alloy friction-stir-welded lap joints was studied. For this purpose, the influences of different rotating speeds, holding times, and pin materials, AA5456 and AA2024, on the metallurgical structure and joint strength were investigated. The observations showed that defect-free lap joints are successfully obtainable by this method using similar and dissimilar consumable pins. The results indicated that the higher rotating speed and holding time adversely affect the weld performance. The best result was achieved for 30 seconds holding time, 500 rpm rotating speed, and AA2024 consumable pin. In this condition, a lap shear strength of 10 pct higher than that of the nonfilled joint, equivalent to about 94 pct of the original defect-free FSW joint, was obtained, whereas the GTAW filled joint showed only approximately 87 pct of the continuous FSW joint strength.

  8. Control of fluid flow during Bridgman crystal growth using low-frequency vibrational stirring

    Zawilski, Kevin Thomas

    The goal of this research program was to develop an in depth understanding of a promising new method for stirring crystal growth melts called coupled vibrational stirring (CVS). CVS is a mixing technique that can be used in sealed systems and produces rapid mixing through vortex flows. Under normal operating conditions, CVS uses low-frequency vibrations to move the growth crucible along a circular path, producing a surface wave and convection in the melt. This research focused on the application of CVS to the vertical Bridgman technique. CVS generated flows were directly studied using a physical modeling system containing water/glycerin solutions. Sodium nitrate was chosen as a model growth system because the growth process could be directly observed using a transparent furnace. Lead magnesium niobate-lead titanate (PMNT) was chosen as the third system because of its potential application for high performance solid state transducers and actuators. In this study, the critical parameters for controlling CVS flows in cylindrical Bridgman systems were established. One of the most important results obtained was the dependence of an axial velocity gradient on the vibrational frequency. By changing the frequency, the intensity of fluid flow at a given depth can be easily manipulated. The intensity of CVS flows near the crystal-melt interface was found to be important. When flow intensity near the interface increased during growth, large growth rate fluctuations and significant changes in interface shape were observed. To eliminate such fluctuations, a constant flow rate near the crystal-melt interface was maintained by decreasing the vibrational frequency. A continuous frequency ramp was found to be essential to grow crystals of good quality under strong CVS flows. CVS generated flows were also useful in controlling the shape of the growth interface. In the sodium nitrate system without stirring, high growth rates produced a very concave interface. By adjusting the flow

  9. Friction Stir Welding of Thick Section Aluminum for Military Vehicle Applications

    2012-12-01

    Friction Stir Welding of Thick Section Aluminum for Military Vehicle Applications by Brian Thompson, Kevin Doherty, Craig Niese, Mike Eff...International Symposium on Friction Stir Welding (9ISFSW), Huntsville, AL, 15–17 May 2012. Approved for public release...Aberdeen Proving Ground, MD 21005-5069 ARL-RP-417 December 2012 Friction Stir Welding of Thick Section Aluminum for Military

  10. 21 CFR 133.144 - Granular and stirred curd cheese.

    2010-04-01

    ..., as to promote and regulate the separation of whey and curd. A part of the whey is drained off. The curd is then alternately stirred and drained to prevent matting and to remove whey from curd. The curd... ingredients. The following safe and suitable ingredients may be used: (1) Dairy ingredients. Milk, nonfat...

  11. Cladding of Advanced Al Alloys Employing Friction Stir Welding

    Stelt, van der A.A.; Bor, T.C.; Geijselaers, H.J.M.; Akkerman, R.; Boogaard, van den A.H.

    2013-01-01

    In this paper an advanced solid state cladding process, based on Friction Stir Welding, is presented. The Friction Surface Cladding (FSC) technology enables the deposition of a solid-state coating using filler material on a substrate with good metallurgical bonding. A relatively soft AA1050 filler m

  12. Recent developments in Micro Friction Stir Welding: A review

    Sithole, Keydon; Vasudeva Rao, Veeredhi

    2016-02-01

    The advent of friction stir welding (FSW) in 1991 has been evolutionary in the joining of metals and related materials. Friction stir welding has enabled the joining of metals that could not be joined by other welding processes. Research has shown that dissimilar materials with very different properties, plastics, composites and even wood can be joined by FSW. Recent activities in the application of FSW has seen the development of micro friction stir welding (μFSW), which is the FSW of very thin sections of thickness 1000 μm (1 mm) or less. Micro friction stir welding further extends the applications of FSW to areas such as copper electrical contacts, tailor-welded blanks, wood. Though μFSW is relatively new development significant work has been done to date with interesting research findings being reported. This paper aims to review developments in μFSW to date. The focus of the paper will be on problems peculiar to μFSW due to downscaling to the micro scale and other practical considerations.

  13. The Care Tradition: Beyond "Add Women and Stir."

    Noddings, Nel

    2001-01-01

    Examines problems of curricular inclusion, emphasizing ways of including the interests and contributions of women in social studies curricula. After describing the inadequacy of the "add women and stir" approach to inclusion, the paper discusses the tradition of care long identified with female life, then explores ways to preserve and extend this…

  14. Induced electromagnetic stirring behavior in a resistance spot weld nugget

    2010-01-01

    A multi-physics hybrid numerical model,which couples electric,magnetic,thermal and flow fields,was used to investigate electromagnetic stirring behavior in a resistance spot weld nugget.The differences of two kinds of different excitation inputs,i.e.,a sinusoidal current and its root-mean-square(RMS) value,were studied to examine if they could produce equivalent electromagnetic stirring effects in the weld nugget.Research showed that the two types of current inputs could produce almost identical fluid flow and heat transfer patterns and consistent evolution of flow and thermal fields in the nugget.At the end of the welding cycles,the maximum flow velocity and temperature between the two inputs differed by 11.6% and 0.3%,respectively.Therefore,the RMS current can be assumed to produce an approximately equivalent electromagnetic stirring effect with the sinusoidal current,and can be used in the future research to greatly improve the solution efficiency of the electromagnetic stirring behavior in the resistance spot weld nugget.

  15. Temporarily alloying titanium to facilitate friction stir welding

    Hovanski, Yuri [Washington State Univ., Pullman, WA (United States)

    2009-05-01

    While historically hydrogen has been considered an impurity in titanium, when used as a temporary alloying agent it promotes beneficial changes to material properties that increase the hot-workability of the metal. This technique known as thermohydrogen processing was used to temporarily alloy hydrogen with commercially pure titanium sheet as a means of facilitating the friction stir welding process. Specific alloying parameters were developed to increase the overall hydrogen content of the titanium sheet ranging from commercially pure to 30 atomic percent. Each sheet was evaluated to determine the effect of the hydrogen content on process loads and tool deformation during the plunge phase of the friction stir welding process. Two materials, H-13 tool steel and pure tungsten, were used to fabricate friction stir welding tools that were plunged into each of the thermohydrogen processed titanium sheets. Tool wear was characterized and variations in machine loads were quantified for each tool material and weld metal combination. Thermohydrogen processing was shown to beneficially lower plunge forces and stabilize machine torques at specific hydrogen concentrations. The resulting effects of hydrogen addition to titanium metal undergoing the friction stir welding process are compared with modifications in titanium properties documented in modern literature. Such comparative analysis is used to explain the variance in resulting process loads as a function of the initial hydrogen concentration of the titanium.

  16. Effect of stirring on striae in glass melts

    Jensen, Martin; Yue, Yuanzheng

    2012-01-01

    Chemical striae have often negative effect on the glass properties, and hence, elimination of striae has been a key issue in glass science and technology. To produce highly homogeneous glasses, it is necessary to stir melts during the melting process. To explore the physical origin of the stria e...

  17. Numerical Simulation of Laminar Flow Field in a Stirred Tank

    范茏; 王卫京; 杨超; 毛在砂

    2004-01-01

    Stirred tanks are used extensively in process industry and one of the most commonly used impellers in stirred tanks is the R.ushton disk turbine. Surprisingly few data are available regarding flow and mixing in stirred-tank reactors with Rushton turbine in the laminar regime, in particular the laminar flow in baffled tanks.In this paper, the laminar flow field in a baffled tank stirred by a standard R.ushton turbine is simulated with the improved inner-outer iterative method. The non-inertial coordinate system is used for the impeller region, which is in turn used as the boundary conditions for iteration. It is found that the simulation results are in good agreement with previous experiments. In addition, the flow number and impeller power number calculated from the simulated flow field are in satisfactory agreement with experimental data. This numerical method allows prediction of flow structure requiring no experimental data as the boundary conditions and has the potential of being used to scale-up and design of related process equipment.

  18. Submerged culture of phellinus linteus in a stirred tank fermenter and an airlift fermenter

    Choi, Keun Ho; Lee, Chang Woo [Dept. of Chemical Engineering, Hanbat National University, Taejeon (Korea)

    2000-04-01

    In this study, to choose a suitable bioreactor type for the mass culture of Phellinus linteus mycelium, we cultured phellinus linteus mycelium using a stirred tank fermenter and an airlift fermenter and compared the performances of the two fermenters. The effects of aeration rate and agitation speed on the culture of Phellinus linteus mycelium were also investigated in the ranges of 1-4L/min, 200-300 rpm, respectively. For the Batch submerged culture, the dry weight of mycelium, pH, and dissolved oxygen concentration changed in four steps, respectively. But the periods of same steps were not consistent with each other. With an increase in aeration rate, the final dry weight of mycelium, dissolved oxygen concentration and pH value until the third step of pH change were increased. As the time increased, the concentration of glucose decreased. However, the effects of aeration rate and agitation speed on the variation of glucose concentration were negligible. The maximum final dry weight of mycelium was obtained when agitation speed was 300 rpm. The dissolved oxygen concentration was increased with agitation speed. The dry weight of mycelium and dissolved oxygen concentration in the continuous stirred tank fermenter were larger than them those in the airlift fermenter. 27 refs., 9 figs.

  19. Effect of stirring speed on anaerobic hydrolytic acidification of excess sludge%搅拌速率对剩余污泥厌氧水解酸化的影响研究

    段小睿; 李杨; 苑宏英

    2011-01-01

    搅拌速率大小对污泥中有机质的溶出影响较大.改变不同的机械搅拌速率,对剩余污泥中SCODCr、VFAs等的溶出进行对比研究.结果表明,搅拌越快越利于SCODCr值的生成,搅拌速率为410 ~ 430 r/min时,产生的SCODCr值明显大于较低搅拌速率,但是如此高速的搅拌使污泥处于剧烈搅动状态,可使大气中的氧不断的溶入,污泥产酸效率下降,搅拌速率越大这种影响越明显;当搅拌速率为70 r/min时,试验中采用的3层搅拌器的轴功率约为87.1 W.%The release of organic matters from sludge was greatly affected by stirring speed. Through changing mechanical stirring speed, the release of SCODcr, VFAs and some other matters from excess sludge were compared and studied. The results showed that, high-speed stirring was of benefit to the SCODCr value increase, the SCODCr. Value with stirring speed of 410 - 430 r/min was obviously greater than those with lower stirring speed. However, to stir sludge at such a high speed caused the oxygen in air continuously dissolved into it, and decreased the acid production rate, the higher the stirring speed was, the more obvious the said affection would be; when the stirring speed was 70 r/min, the shaft power of the three-layer stirrer used in the test was about 87.1 W.

  20. Continuous production of glycerol by catalytic high pressure hydrogenolysis of sucrose

    Ling, van Gerrit; Driessen, Alfons J.; Piet, Arie C.; Vlugter, Jozef C.

    1970-01-01

    Several continuous reactor systems have been discussed for the catalytic high pressure hydrogenolysis of sucrose to glycerol. Theoretically and actually, continuous reactors lead to lower glycerol yields than in a batch process. Two continuous stirred tank reactors in cascade constitute a reasonable

  1. Long echo time STIR sequence MRI of optic nerves in optic neuritis

    Onofrj, M. [Dept. of Neurology, State Univ. of Chieti, Ospedale ex-Pediatrico (Italy); Tartaro, A. [Dept. of Radiology, State Univ. of Chieti (Italy); Thomas, A. [Dept. of Neurology, State Univ. of Chieti, Ospedale ex-Pediatrico (Italy); Gambi, D. [Dept. of Neurology, State Univ. of Chieti, Ospedale ex-Pediatrico (Italy); Fulgente, T. [Dept. of Neurology, State Univ. of Chieti, Ospedale ex-Pediatrico (Italy); Delli Pizzi, C. [Dept. of Radiology, State Univ. of Chieti (Italy); Bonomo, L. [Dept. of Radiology, State Univ. of Chieti (Italy)

    1996-01-01

    MRI of the optic nerves was obtained in 13 patients with acute optic neuritis and 13 with a previous optic neuritis (ON), assessed by clinical features, visual fields and visual evoked potentials. Results of the conventional short tau inversion recovery (STIR) sequence obtained with a short echo time (STE-STIR; 22 ms) were compared with those of a long echo time (LTE-STIR: 80 ms) sequence. The conventional STE-STIR sequence revealed lesions in the optic nerves in 78.5% of acute and 58.8% of previous ON. The LTE-STIR sequence showed abnormalities in 92.8% of acutely symptomatic nerves and 94.1% of nerves with previous ON. The optic nerve lesions appeared significantly longer with the LTE-STIR sequence than with the conventional STE-STIR sequences, in both acute and previous ON. (orig.)

  2. Continuous Cultivation of Photosynthetic Bacteria for Fatty Acids Production

    Kim, Dong-Hoon; Lee, Ji-Hye; Hwang, Yuhoon

    2013-01-01

    In the present work, we introduced a novel approach for microbial fatty acids (FA) production. Photosynthetic bacteria, Rhodobacter sphaeroides KD131, were cultivated in a continuous-flow, stirred-tank reactor (CFSTR) at various substrate (lactate) concentrations.At hydraulic retention time (HRT) 4....... sphaeroides was around 35% of dry cell weight, mainly composed of vaccenic acid (C18:1, omega-7)....

  3. Friction stir welding of AZ31 magnesium alloy

    林三宝; 张华; 吴林; 冯吉才; 戴鸿滨

    2003-01-01

    Friction stir welding (FSW) is an new solid-phase joining technology which has more advantages over fusion welding methods in welding of aluminum and other non-ferrous metals. The effects of welding parameters on mechanical properties and microstructure during friction stir welding of AZ31 magnesium alloy were studied in this paper. Microstructures and mechanical properties of the joints were investigated by means of optical microscopy, scanning electric microscopy (SEM), micro-hardness analysis, and tensile test. Experimental results show that the magnesium alloy can be successfully welded by FSW method, and the ultimate tensile strength (UTS) of FSW joint reaches up to 90 percent of base metal. The microstructures of welded joints exhibit the variation from dynamically recrystallized fine grains to greatly deformed grains. Hardness in nugget zone was found lower than the base metal but not too obvious.

  4. Predicting the forming limit of friction stir welded blanks

    Ramulu, Perumalla Janaki; Narayanan, R. Ganesh

    2011-05-01

    Friction stir welded blanks (FSWB) are tailored blanks made by friction stir welding of sheets of different thicknesses and quality. In order to reduce the trial-and-error principles and costs, the computational simulation of stamping processes of FSW blanks is required for which a feasible methodology or theory to evaluate the forming characteristics has to be incorporated. In the present work, the validity of effective strain rate based necking criterion (ESRC) in both original and modified forms to predict the forming limit of FSW blanks made of AA6111, DP590 is analyzed. The FLC thus predicted is compared with FLC from thickness gradient based necking criterion and from literature. It is found from the validation done with literature results that a consistent and accurate forming limit prediction is obtained from modified ESRC when compared to original ESRC. The failure pattern prediction is also agreeing well with the literature results.

  5. FRICTION STIR LAP WELDING OF ALUMINUM - POLYMER USING SCRIBE TECHNOLOGY

    Upadhyay, Piyush; Hovanski, Yuri; Fifield, Leonard S.; Simmons, Kevin L.

    2015-02-16

    Friction Stir Scribe (FSS) technology is a relatively new variant of Friction Stir Welding (FSW) which enables lap joining of dissimilar material with very different melting points and different high temperature flow behaviors. The cutter scribe attached at the tip of FSW tool pin effectively cuts the high melting point material such that a mechanically interlocking feature is created between the dissimilar materials. The geometric shape of this interlocking feature determines the shear strength attained by the lap joint. This work presents first use of scribe technology in joining polymers to aluminum alloy. Details of the several runs of scribe welding performed in lap joining of ~3.175mm thick polymers including HDPE, filled and unfilled Nylon 66 to 2mm thick AA5182 are presented. The effect of scribe geometry and length on weld interlocking features is presented along with lap shear strength evaluations.

  6. Effects of electromagnetic stirring on microstructures of solidified aluminum alloys

    时海芳; 张伟强

    2003-01-01

    Al-20%Cu, Al-33%Cu and Al-7%Si alloys were solidified with electromagnetic stirring(EMS). The fluid flow induced by electromagnetic stirring leads to the increases of the lamellar spacing of Al-CuAl2 and Al-Si eutectics and the secondary dendritic arm spacing. Rod-like eutectic structure plus pro-eutectic α(Al) are observed in Al-Cu eutectic alloy when the agitating voltage is increased over 130 V, and in the hypoeutectic alloys, globular grains of proeutectic α(Al) grains may form when the magnetic field is strong enough. The Si flakes in the Al-Si eutectic are also coarsened by applying forced flow during solidification, which is always related to the depression of their branching in the growth by the forced convection.

  7. CFD simulation of particle suspension in a stirred tank

    Nana Qi; Hu Zhang; Kai Zhang; Gang Xu; Yongping Yang

    2013-01-01

    Particle suspension characteristics are predicted computationally in a stirred tank driven by a Smith turbine.In order to verify the hydrodynamic model and numerical method,the predicted power number and flow pattern are compared with designed values and simulated results from the literature,respectively.The effects of particle density,particle diameter,liquid viscosity and initial solid loading on particle suspension behavior are investigated by using the Eulerian-Eulerian two-fluid model and the standard k-ε turbulence model.The results indicate that solid concentration distribution depends on the flow field in the stirred tank.Higher particle density or larger particle size results in less homogenous distribution of solid particles in the tank.Increasing initial solid loading has an adverse impact on the homogeneous suspension of solid particles in a low-viscosity liquid,whilst more uniform particle distribution is found in a high-viscositv liauid.

  8. Simulation on Gas Injection Refining Process with Mechanical Stirring

    Zhang Ting’an

    2012-12-01

    Full Text Available Basing on the new method of in-situ desulfurization with gas injection and mechanical stirring, the effect of bubble dispersion and disintegration of three type impellers are numerically simulated by commercial CFD software Ansys Fluent 12.0. Numerical simulations of three-dimensional multiphase turbulence in gas injection and mechanical stirring are performed by adopting unsteady SM method coupled with Eulerian multiphase model and two-phase turbulence model. The information of gas-liquid fluid flow, velocity, turbulent kinetic energy and the power consumption are investigated and the results show that the SSB impeller can make bubbles get best dispersion and disintegration,and its power consumption is lower than VB impeller. The disk on the impeller blades can weaken the swirl flow in the upper zone of the impeller. Therefore, the bubble residence time is extended, and the bubble dispersing zone is also increased.

  9. Determination of the decay exponent in mechanically stirred isotropic turbulence

    J. Blair Perot

    2011-06-01

    Full Text Available Direct numerical simulation is used to investigate the decay exponent of isotropic homogeneous turbulence over a range of Reynolds numbers sufficient to display both high and low Re number decay behavior. The initial turbulence is generated by the stirring action of the flow past many small randomly placed cubes. Stirring occurs at 1/30th of the simulation domain size so that the low-wavenumber and large scale behavior of the turbulent spectrum is generated by the fluid and is not imposed. It is shown that the decay exponent in the resulting turbulence matches the theoretical predictions for a k2 low-wavenumber spectrum at both high and low Reynolds numbers. The transition from high Reynolds number behavior to low Reynolds number behavior occurs relatively abruptly at a turbulent Reynolds number of around 250 ( Re λ≈41.

  10. Corrosion of friction stir welded magnesium alloy AM50

    Zeng Rongchang [School of Material Science and Engineering, Chongqing University of Technology, Xingshenglu Rd. 4, Chongqing 400050 (China)], E-mail: rczeng2001@yahoo.com.cn; Chen Jun [School of Material Science and Engineering, Chongqing University of Technology, Xingshenglu Rd. 4, Chongqing 400050 (China); Dietzel, Wolfgang; Zettler, Rudolf; Santos, Jorge F. dos [GKSS-Forschungszentrum Geesthacht GmbH, Max Planck Strasse 1, 21502 Geesthacht (Germany); Lucia Nascimento, M. [Technische Universitaet Berlin, Fachgebiet Werkstofftechnik, Strasse des 17. Juni 135, 10623 Berlin (Germany); Kainer, Karl Ulrich [GKSS-Forschungszentrum Geesthacht GmbH, Max Planck Strasse 1, 21502 Geesthacht (Germany)

    2009-08-15

    The microstructure of a friction stir welded magnesium alloy AM50 was examined by means of optical light microscopy. The chemical composition, particularly the iron content, and morphology of the oxide film were analyzed and discerned via auger electron spectroscopy (AES) and X-ray photoelectron spectroscopy (XPS). Corrosion behaviour of the welds and base materials were investigated by virtue of neutral salt spray tests and potentiodynamic polarization measurements in conventional cells and in a mini cell. The results demonstrate that minor increases in iron concentration as might be speculated to occur as a consequence of tool/work piece interaction during the welding process on the corrosion resistance of the weld can be ignored. The corrosion morphology was predominantly influenced by the distribution of the Mg{sub 17}Al{sub 12} phase. Here, it was also found that the corrosion resistance of the friction stir weld varied in response to changes in the joint microstructure.

  11. MRI of lymphedema using short-TI-IR (STIR)

    Fujii, Koichi; Ishida, Osamu; Mabuchi, Norihisa; Shindou, Hiroshi; Yoshioka, Hiroyasu; Kumano, Machiko; Hamada, Tatsumi; Ohkuma, Moriya (Kinki Univ., Osaka (Japan). School of Medicine)

    1990-01-01

    Thirty four cases with lymphedema of the extremities were examined with MRI at 0.5 tesla. On T1-weighted image, the enlarged subcutaneous tissue and the subcutaneous trabecular structures were seen in all cases. Moreover, the trabecular structures in the enlarged subcutaneous tissue showed low signal intensity on T1-weighted image and high signal intensity on T2-weighted image in all cases. Additionally, in 12 of 15 cases examined by Short-TI-IR (STIR) image, the trabecular structures and fluid collections in the subcutaneous tissue were shown more definitely in high signal intensity than by T2-weighted image. We consider MRI using STIR is to be useful in the evaluation of edematous disease. (author).

  12. Multiaxial fatigue of aluminium friction stir welded joints: preliminary results

    D. G. Hattingh

    2015-07-01

    Full Text Available The aim of the present research is to check the accuracy of the Modified Wöhler Curve Method (MWCM in estimating the fatigue strength of friction stir (FS welded tubular joints of Al 6082-T6 subjected to in-phase and out-of-phase multiaxial fatigue loading. The welded samples being investigated were manufactured by equipping an MTS I-STIR process development system with a retracting tool that was specifically designed and optimised for this purpose. These specimens were tested under proportional and non-proportional tension and torsion, the effect of non-zero mean stresses being also investigated. The validation exercise carried out by using the generated experimental results allowed us to prove that the MWCM (applied in terms of nominal stresses is highly accurate in predicting the fatigue strength of the tested FS welded joints, its usage resulting in estimates falling with the uniaxial and torsional calibration scatter bands.

  13. Structure and properties of stir-cast zinc alloys

    LeHuy, H.; Blain J.; Masounave, J.; Bata, G.L. (Industrial Materials Research Institute, Boucherville, P.Q. (Canada))

    Stir casting (or rheocasting) of ZA-27 zinc alloys was investigated experimentally. By vigorously agitating the alloys during cooling, the dendrites that were forming were fragmented giving a unique structure composed of spherical and rosette shaped particles suspended in the remaining liquid. Under high shear rates ({center dot}{gamma} = 300s{sup {minus}1} or more) the slurries with primary particle concentrations as high as 60% displayed viscosities as low as 20 poises and could easily be casted. The effects of processing variables such as shearing and cooling rates and casting temperatures were studied. Their relative importance on the rheological and microstructural behavior of the stir cast alloys are discussed. Results from viscosity measurements on slurries show that non-dendritical ZA-27 alloys obey a power law fluid model. Finally, results from mechanical and compressive studies carried out on solidified slurries are discussed and compared to conventional casted and wrought alloy properties.

  14. Effect of friction stir welding parameters on defect formation

    Tarasov, S. Yu.; Rubtsov, V. E.; Eliseev, A. A.; Kolubaev, E. A.; Filippov, A. V.; Ivanov, A. N.

    2015-10-01

    Friction stir welding is a perspective method for manufacturing automotive parts, aviation and space technology. One of the major problems is the formation of welding defects and weld around the welding zone. The formation of defect is the main reason failure of the joint. A possible way to obtain defect-free welded joints is the selection of the correct welding parameters. Experimental results describing the effect of friction stir welding process parameters on the defects of welded joints on aluminum alloy AMg5M have been shown. The weld joint defects have been characterized using the non-destructive radioscopic and ultrasound phase array methods. It was shown how the type and size of defects determine the welded joint strength.

  15. Microstructural Evolution During Friction Stir Welding of Mild Steel and Ni-Based Alloy 625

    Fernandez, Johnnatan Rodriguez; Ramirez, Antonio J.

    2017-01-01

    Microstructure evolution during friction stir welding (FSW) of mild steel and Ni-based alloy 625 was studied. Regarding the Ni-based alloy, the welding process led to grain refinement caused by discontinuous and continuous dynamic recrystallization, where bulging of the pre-existing grains and subgrain rotation were the primary mechanisms of recrystallization. In the steel, discontinuous dynamic recrystallization was identified as the recovery process experienced by the austenite. Simple shear textures were observed in the regions affected by the deformation of both materials. Although the allotropic transformation obscured the deformation history, the thermo-mechanically affected zone was identified in the steel by simple shear texture components. A new methodology for the study of texture evolution based on rotations of the slip systems using pole figures is presented as an approximation to describe the texture evolution in FSW.

  16. Microstructural Evolution During Friction Stir Welding of Mild Steel and Ni-Based Alloy 625

    Fernandez, Johnnatan Rodriguez; Ramirez, Antonio J.

    2017-03-01

    Microstructure evolution during friction stir welding (FSW) of mild steel and Ni-based alloy 625 was studied. Regarding the Ni-based alloy, the welding process led to grain refinement caused by discontinuous and continuous dynamic recrystallization, where bulging of the pre-existing grains and subgrain rotation were the primary mechanisms of recrystallization. In the steel, discontinuous dynamic recrystallization was identified as the recovery process experienced by the austenite. Simple shear textures were observed in the regions affected by the deformation of both materials. Although the allotropic transformation obscured the deformation history, the thermo-mechanically affected zone was identified in the steel by simple shear texture components. A new methodology for the study of texture evolution based on rotations of the slip systems using pole figures is presented as an approximation to describe the texture evolution in FSW.

  17. Numerical Simulation of Friction Stir Welding by Natural Element Methods

    Alfaro, I.; Fratini, L.; CUETO, Elias; Chinesta, Francisco

    2009-01-01

    International audience; In this work we address the problem of numerically simulating the Friction Stir Welding process. Due to the special characteristics of this welding method (i.e., high speed of the rotating pin, very large deformations, etc.) finite element methods (FEM) encounter several difficulties. While Lagrangian simulations suffer from mesh distortion, Eulerian or Arbitrary Lagrangian Eulerian (ALE) ones still have difficulties due to the treatment of convective terms, the treatm...

  18. STIR: Novel Electronic States by Gating Strongly Correlated Materials

    2016-03-01

    understood, has long been the foundation for electronic devices. What if we could apply these techniques to a much broader range of materials ? This short...grant aimed at demonstrating such large potential modulations in correlated electron materials using a technique known as electrolyte gating. This...of Papers published in non peer-reviewed journals: Final Report: STIR: Novel Electronic States by Gating Strongly Correlated Materials Report Title

  19. Feasibility of Underwater Friction Stir Welding of HY-80 Steel

    2011-03-01

    control procedures. A single tool of polycrystalline cubic boron nitride (PCBN) in a Tungsten -Rhenium binder was used to conduct three bead-on-plate FSW... Tungsten -Rhenium binder was used to conduct three bead-on-plate FSW traverses, approximately 40 inches in length on 0.25 inch HY-80 steel. The...the processing of nickel aluminum bronze propellers used on Navy ships and submarines. Friction stir welding is accomplished by using a cylindrical

  20. Feasibility of underwater friction stir welding of HY-80 steel

    Stewart, William Chad

    2011-01-01

    Approved for public release; distribution is unlimited. The purpose of this thesis is to determine the feasibility of underwater friction stir welding (FSW) of high-strength; quench and temper low carbon steels that are susceptible to hydrogen-assisted cracking (HAC). The specific benefits of underwater FSW would be weld repairs of ship and submarine control surfaces and hulls without the need for drydocking and extensive environmental control procedures. A single tool of polycrystallin...

  1. Friction stir welding of 5052 aluminum alloy plates

    Yong-Jai KWON; Seong-Beom SHIM; Dong-Hwan PARK

    2009-01-01

    Friction stir welding between 5052 aluminum alloy plates with a thickness of 2 mm was performed. The tool for welding was rotated at speeds ranging from 500 to 3 000 r/min under a constant traverse speed of 100 mm/min. The results show that at all tool rotation speeds, defect-free welds are successfully obtained. Especially at 1 000, 2 000 and 3 000 r/min, the welds exhibit very smooth surface morphologies. At 500, 1 000, and 2 000 r/min, onion ring structure is clearly observed in the friction-stir-welded zone (SZ). In addition, the onion ring structure region becomes wider as the tool rotation speed is increased. The gain size in the SZ is smaller than that in the base metal, and is decreased with a decrease of the tool rotation speed. In all tool rotation speeds, the SZ exhibits higher average hardness than the base metal. Especially at 500 r/min, the average hardness of the SZ reaches a level about 33% greater than that of the base metal. At 500, 1 000 and 2 000 r/min, the tensile strength of the friction stir welded (FSWed) plates is similar to that of the base metal (about 204 Mpa). The elongation of the FSWed plates is lower than that of the base metal (about 22%). However, it is noticeable that the maximum elongation of about 21% is obtained at 1 000 r/min.

  2. Repair welding process of friction stir welding groove defect

    LIU Hui-jie; ZHANG Hui-jie

    2009-01-01

    The groove defect formed in the friction stir welding dramatically deteriorates weld appearances and mechanical properties of the joints owing to its larger size and penetration. Therefore, the friction stir repair welding was utilized to remove such a groove defect, and the focus was placed on the mechanical properties and microstructural characteristics of the repair joints so as to obtain an optimum repair welding process. The experimental results indicate that the groove defect can be removed by friction stir repair welding, and the offset repair welding process is superior to the symmetrical repair welding process. In the symmetrical repair welding process, a large number of fine cavity defects and an obvious aggregation of hard-brittle phase Al2Cu occur, accordingly the mechanical properties of the repair joint are weakened, and the fracture feature of repair joint is partially brittle and partially plastic. A good-quality repair joint can be obtained by the offset repair welding process, and the repair joint is fractured near the interface between the weld nugget zone and thermal-mechanically affected zone.

  3. Friction stir welding characteristics of two aluminum alloys

    刘会杰; 藤井英俊; 前田将克; 野城清

    2003-01-01

    The friction stir welding characteristics of the strain-hardened AA1050-H24 and precipitate-hardened AA2017-T351 aluminum alloys were examined in order to reveal the effects of the alloy properties on the friction stir welding behavior of the base materials. The results show that (1) for AA1050-H24, the weld possesses a smooth surface and clear ripples, there is no elliptical weld nugget in the weld, there is not discernible interface between the stir zone and the thermo-mechanically affected zone(TMAZ), and the internal defect of the weld looks like a long crack and is located in the lower part of the weld; (2) for AA2017-T351, the weld usually possesses a rough surface and visible ripples, the elliptical weld nugget clearly exists in the weld and there is obvious plastic flow and a discernible interface between the nugget and the TMAZ, and the internal defect of the weld is composed of many voids and distributed in the middle part of the weld; (3) the effective ranges of the welding parameters for AA1050-H24 and AA2017-T351 are both narrow, especially for the latter; and (4) the tensile strength efficiencies of the joints for the two typical alloys are similar, i e 79% for AA1050-H24 and 82% for AA2017-T351.

  4. Thermo-Mechanical Processing in Friction Stir Welds

    Schneider, Judy

    2003-01-01

    Friction stir welding is a solid-phase joining, or welding process that was invented in 1991 at The Welding Institute (TWI). The process is potentially capable of joining a wide variety of aluminum alloys that are traditionally difficult to fusion weld. The friction stir welding (FSW) process produces welds by moving a non-consumable rotating pin tool along a seam between work pieces that are firmly clamped to an anvil. At the start of the process, the rotating pin is plunged into the material to a pre-determined load. The required heat is produced by a combination of frictional and deformation heating. The shape of the tool shoulder and supporting anvil promotes a high hydrostatic pressure along the joint line as the tool shears and literally stirs the metal together. To produce a defect free weld, process variables (RPM, transverse speed, and downward force) and tool pin design must be chosen carefully. An accurate model of the material flow during the process is necessary to guide process variable selection. At MSFC a plastic slip line model of the process has been synthesized based on macroscopic images of the resulting weld material. Although this model appears to have captured the main features of the process, material specific interactions are not understood. The objective of the present research was to develop a basic understanding of the evolution of the microstructure to be able to relate it to the deformation process variables of strain, strain rate, and temperature.

  5. Friction Stir Welding of Al 5052 with Al 6061 Alloys

    N. T. Kumbhar

    2012-01-01

    Full Text Available Friction stir welding (FSW, a solid-state joining technique, is being extensively used in similar as well as dissimilar joining of Al, Mg, Cu, Ti, and their alloys. In the present study, friction stir welding of two aluminium alloys—AA6061 and AA5052—was carried out at various combinations of tool rotation speeds and tool traverse speeds. The transverse cross-section of the weld was used for optical as well as electron microscopy observations. The microstructural studies were used to get an indication of the extent of material mixing both at the macro- and microscales. It was observed that, at the interface region, both materials exhibited similar texture despite the nonrigorous mixing of the materials in the nugget. The extent of interdiffusion of alloying elements at the interface was studied using electron probe microanalysis. The tensile testing evaluation of these specimens showed good mechanical properties. The interdiffusion of alloying elements and development of similar orientations in the nugget could have contributed to the better tensile properties of the friction-stir-welded AA5052-AA6061 specimens.

  6. Effects of Friction Stir Welding Speed on AA2195 alloy

    Lee Ho-Sung

    2016-01-01

    Full Text Available The application of friction stir welding (FSW to aerospace has grown rapidly due to the high efficiency and environmental friendly nature of the process. FSW is achieved by plastic flow of frictionally heated material in solid state and offers many advantages of avoiding hot cracking and limiting component distortion. Recently low density, high modulus and high strength AA2195 are used as substitute for conventional aluminum alloys since the weight saving is critical in aerospace applications. One of the problems for this alloy is weld metal porosity formation leading to hot cracking. Combination of FSW and AA2195 provides synergy effect to improve mechanical properties and weight saving of aerospace structure such as cryogenic fuel tanks for launch systems. The objective of this paper is to investigate the effect of friction stir welding speed on mechanical and microstructural properties of AA2195. The friction stir welded materials were joined with four different tool rotation speeds (350~800 rpm and five welding speeds (120~360 mm/min, which are the two prime welding parameters in this process.

  7. Continuous auditing & continuous monitoring : Continuous value?

    van Hillo, Rutger; Weigand, Hans; Espana, S; Ralyte, J; Souveyet, C

    2016-01-01

    Advancements in information technology, new laws and regulations and rapidly changing business conditions have led to a need for more timely and ongoing assurance with effectively working controls. Continuous Auditing (CA) and Continuous Monitoring (CM) technologies have made this possible by obtain

  8. Microstructural Characterization of Friction Stir Welded Aluminum-Steel Joints

    Patterson, Erin E.; Hovanski, Yuri; Field, David P.

    2016-06-01

    This work focuses on the microstructural characterization of aluminum to steel friction stir welded joints. Lap weld configuration coupled with scribe technology used for the weld tool have produced joints of adequate quality, despite the significant differences in hardness and melting temperatures of the alloys. Common to friction stir processes, especially those of dissimilar alloys, are microstructural gradients including grain size, crystallographic texture, and precipitation of intermetallic compounds. Because of the significant influence that intermetallic compound formation has on mechanical and ballistic behavior, the characterization of the specific intermetallic phases and the degree to which they are formed in the weld microstructure is critical to predicting weld performance. This study used electron backscatter diffraction, energy dispersive spectroscopy, scanning electron microscopy, and Vickers micro-hardness indentation to explore and characterize the microstructures of lap friction stir welds between an applique 6061-T6 aluminum armor plate alloy and a RHA homogeneous armor plate steel alloy. Macroscopic defects such as micro-cracks were observed in the cross-sectional samples, and binary intermetallic compound layers were found to exist at the aluminum-steel interfaces of the steel particles stirred into the aluminum weld matrix and across the interfaces of the weld joints. Energy dispersive spectroscopy chemical analysis identified the intermetallic layer as monoclinic Al3Fe. Dramatic decreases in grain size in the thermo-mechanically affected zones and weld zones that evidenced grain refinement through plastic deformation and recrystallization. Crystallographic grain orientation and texture were examined using electron backscatter diffraction. Striated regions in the orientations of the aluminum alloy were determined to be the result of the severe deformation induced by the complex weld tool geometry. Many of the textures observed in the weld

  9. Expression at a 20L scale and purification of the extracellular domain of the Schistosoma mansoni TSP-2 recombinant protein: a vaccine candidate for human intestinal schistosomiasis.

    Curti, Elena; Kwityn, Clifford; Zhan, Bin; Gillespie, Portia; Brelsford, Jill; Deumic, Vehid; Plieskatt, Jordan; Rezende, Wanderson C; Tsao, Eric; Kalampanayil, Bose; Hotez, Peter J; Bottazzi, Maria Elena

    2013-11-01

    A novel recombinant protein vaccine for human schistosomiasis caused by Schistosoma mansoni is under development. The Sm-TSP-2 schistosomiasis vaccine is comprised of a 9 kDa recombinant protein corresponding to the extracellular domain of a unique S. mansoni tetraspanin. Here, we describe the cloning and the expression of the external loop of Sm-TSP-2 recombinant protein secreted by Pichia Pink the process development at 20L scale fermentation, and the two-steps purification, which resulted in a protein recovery yield of 31% and a protein purity of 97%. The developed processes are suitable for the production of purified protein for subsequent formulation and Phase 1 clinical studies.

  10. Design of nonlinear PID controller and nonlinear model predictive controller for a continuous stirred tank reactor.

    Prakash, J; Srinivasan, K

    2009-07-01

    In this paper, the authors have represented the nonlinear system as a family of local linear state space models, local PID controllers have been designed on the basis of linear models, and the weighted sum of the output from the local PID controllers (Nonlinear PID controller) has been used to control the nonlinear process. Further, Nonlinear Model Predictive Controller using the family of local linear state space models (F-NMPC) has been developed. The effectiveness of the proposed control schemes has been demonstrated on a CSTR process, which exhibits dynamic nonlinearity.

  11. Perancangan dan Simulasi MRAC untui Proses Pengendalian Temperatur pada Continuous Stirred Tank Reactor (CSTR

    Amelia Sylvia

    2014-03-01

    Full Text Available Temperatur merupakan salah satu variabel proses dasar yang dikendalikan untuk menjaga suhu cairan di dalam reaktor. Model Reference Adaptive Controller (MRAC dengan MIT rule dipilih untuk mencapai spesifikasi respon yang diinginkan pada CSTR. Beban yang bervariasi berupa debit aliran likuid yang masuk ke dalam reaktor dapat menyebabkan perubahan parameter yang mempengaruhi perubahan temperatur output produk pada CSTR. Sebuah simulasi dilakukan dengan menggunakan MATLAB dan hasilnya dianalisa. Respon plant dapat melakukan adaptasi parameter – parameter kontrolernya cukup baik pada nilai gain adaptasi dengan rentang 0.00000010000 sampai 0.00000000001. Waktu yang dibutuhkan untuk mengatasi beban yang bervariasi berupa debit aliran yang masuk ke dalam reaktor dengan nilai yang maksimal (1.5 m^3/min menghasilkan respon plant lebih cepat 42 detik dari pada debit aliran masuk dengan nilai yang nominal (1 m^3/min 63 detik dan minimal (0.5 m^3/min 75 detik.

  12. Numerical Bifurcation Analysis of Delayed Recycle Stream in a Continuously Stirred Tank Reactor

    Gangadhar, Nalwala Rohitbabu; Balasubramanian, Periyasamy

    2010-10-01

    In this paper, we present the stability analysis of delay differential equations which arise as a result of transportation lag in the CSTR-mechanical separator recycle system. A first order irreversible elementary reaction is considered to model the system and is governed by the delay differential equations. The DDE-BIFTOOL software package is used to analyze the stability of the delay system. The present analysis reveals that the system exhibits delay independent stability for isothermal operation of the CSTR. In the absence of delay, the system is dynamically unstable for non-isothermal operation of the CSTR, and as a result of delay, the system exhibits delay dependent stability.

  13. MULTI-LOOP CONTROL DESIGN IN MULTIVARIABLE (2X2 CONTINUOUS STIRRED TANK REACTOR

    Abdul Wahid

    2015-06-01

    Full Text Available With this study, the design and tuning of multi-loop for multivariable (2x2 CSTR will be made in order to achieve optimum CSTR control performance. This study used Bequette model reactor and MATLAB software and is expected to be able to cope with disturbances in the reactor so that the reactor system is able to stabilize quickly despite the distractions. In this study, the design will be made using multi-loop approach, along with PI controller as the next step. Then, BLT and auto-tune tuning method will be used in PI controller and given disturbances to both of tuning method. The controller performances are then compared. Results of the study are then analyzed for discussions and conclusions. Results from this study have shown that in terms of disturbance rejection, BLT is better than auto-tune based on comparison between both of controller performances. For IAE for the case of temperature, BLT is 30% better than auto-tune, but it is almost the same for the case of concentration. For settling time for the case of concentration, BLT is 30% better than auto-tune, and for the case of temperature, BLT is 18% better than auto-tune. For rise time for the case of concentration and temperature, BLT is 30% better than auto-tune.

  14. Physical Simulation of New Desulphurization Technology Using Pulsed and Rotary Stirring-Injection

    WU Wei; HU Yan-bin; LIU Liu; DING Yong-liang

    2008-01-01

    The contrast experiment of different stirring modes, which includes a new type of stirring-injection with the method of pulse and rotation, and the initial one-way stirring method, is done through physical simulation in the laboratory. The stirring methods of pulse and rotation are of two kinds. One is pulsed and rotary stirrer with positive and opposite directions. The other is pulsed and rotary stirrer with rotation-stop-rotation. The results show that the stirring mode of pulse and rotation has better effects than the one-way stirring method. The specific effects are that the mixing time of the melting bath is apparently shortened, the number of grains involved in the liquid surface is increased, and the residence time of air bubble in water is doubled.

  15. Solid-Liquid Dispersion in a Stirred Tank%固-液搅拌槽的分散性能

    张优; 尹喜祥; 黄雄斌

    2011-01-01

    在直径为0.478 m的立式搅拌槽中,采用高岭土和水为物料,比较了四斜叶、六直叶涡轮等8种桨的固-液分散性能及搅拌功率(P)、桨组合形式对分散性能的影响规律.结果表明,8种桨中分散效果最好的是六直叶涡轮桨和四斜叶桨,分散速率最快的是两叶CBY桨;分散速率与P1.08成正比;分散前期,搅拌功率增加,相对分散效果Y随之提高,当Y达到0.999以上,提高搅拌功率对搅拌效果几乎不起作用;采用分散速率较快(两叶CBY桨)与分散效果较好(四斜叶桨)的双桨组合,更适于连续操作过程.%The solid-liquid dispersion property by eight types of impeller such as four-pitched-blade turbine (PBT), Rushton turbine (RT), etc, and the influences of stirring power and impeller combinations on dispersion property were studied in a vertical stirred tank with diameter of 0.478 m. Kaolin particles were chosen as the particulate material to be dispersed in the water. The experimental results show that PBT and RT have the optimum dispersion performance, while the 2-blade CBY propeller has the shortest dispersion time. The dispersion rate is in the direct ratio of 1.08 to the stirring power. In the beginning period, the relative dispersion performance Y increases with the stirring power, but the stirring power has little influence on the dispersion performance when the relative dispersion performance Y is more than 0.999. The results also reveal that the combination of a bottom 2-blade CBY and an upper PBT has a clear advantage in continuous operation.

  16. Spatial Mechanical Response and Strain Gradient Evolution of Friction Stir Welded Aluminum-2139

    2012-02-01

    Spatial Mechanical Response and Strain Gradient Evolution of Friction Stir Welded Aluminum-2139 by Brian Justusson, Jessica Medintz, Jian...Evolution of Friction Stir Welded Aluminum-2139 Brian Justusson and Jessica Medintz Oak Ridge Institute for Science and Education Jian Yu...and Strain Gradient Evolution of Friction Stir Welded Aluminum-2139 5a. CONTRACT NUMBER ORISE 1120-1120-99 5b. GRANT NUMBER 5c. PROGRAM ELEMENT

  17. Microstructural Investigation and Evaluation of Mechanical Properties in Friction Stir Welded Joints

    2011-08-01

    Properties in Friction Stir Welded Joints BRIAN JUSTUSSON MENTORS: DR. CONSTANTINE FOUNTZOULAS AND DR. CHIAN-FONG YEN U.S. ARMY RESEARCH LABORATORY...2011 4. TITLE AND SUBTITLE Microstructural Investigation And Evaluation Of Mechanical Properties In Friction Stir Welded Joints 5a. CONTRACT NUMBER...of the weldment can be costly and needs to be addressed. Friction Stir Welding (FSW) is a solid-state welding technique, which involves local softening

  18. Semi-solid slurry of AZ91 magnesium alloy prepared by electromagnetic stirring near liquidus temperature

    2007-01-01

    An electromagnetic stirring process near liquidus temperature was designed and demonstrated experimentally to produce semi-solid slurry of AZ91 magnesium alloy, in order to avoid not only contamination from mechanical stirring but also the inflammation of Mg alloy melt at elevated temperature. AZ91 alloy feedstock was isothermally heat treated at 600-610 ℃ for 20 min, and then stirred by electromagnetic field. Globular primary particle characteristic was observed optically in the castings. Mechanical properties were also studied.

  19. Modeling of AA5083 Material-Microstructure Evolution During Butt Friction-Stir Welding

    2010-07-01

    B. Clausen, and K. An, In Situ Neutron Diffraction Measurements of Temperature and Stresses During Friction Stir Welding of 6061 -T6 Aluminium Alloy...Analytical Modelling of Friction Stir Welding, INALCO98: Seventh International Conference on Joints in Aluminium , M.J. Russell and R. Shercliff R, Ed...Fujii, M. Maeda, and K. Nogi, Tensile Fracture Location Characterisation of Friction Stir Welded Joints of Different Aluminium Alloys, J. Mater. Sci

  20. Investigation of the Microstructure of Joints of Aluminum Alloys Produced by Friction Stir Welding

    Kolubaev, E. A.

    2015-02-01

    Special features of the microstructure of joints of aluminum-magnesium and aluminum-copper alloys produced by friction stir welding are analyzed. It is demonstrated that a layered structure with ultradisperse grains is produced by friction stir welding at the center of the weld joint. An analogy is drawn between the microstructures of joints produced by friction stir welding and surface layer produced by sliding friction.

  1. CFD simulation of flow patterns in unbaffled stirred tank with CD-6 impeller

    Devi Tamphasana Thiyam

    2012-01-01

    Full Text Available Understanding the flow in stirred vessels can be useful for a wide number of industrial applications. There is a wealth of numerical simulations of stirring vessels with standard impeller such as Rushton turbine and pitch blade turbine. Here, a CFD study has been performed to observe the spatial variations (angular, axial and radial of hydrodynamics (velocity and turbulence field in unbaffled stirred tank with Concave-bladed Disc turbine (CD-6 impeller. Three speeds (N=296, 638 & 844.6 rpm have been considered for this study. The angular variations of hydrodynamics of stirred tank were found very less as compared to axial and radial variations.

  2. Research on Semi-Solid Microstructure of High-Chrome Cast Iron by Using Electromagnetic Stirring Method%电磁搅拌法制备高铬铸铁半固态组织研究

    高军芳

    2012-01-01

    To research the effect of electromagnetic stirring on the solidification microstructures of high melting point alloy, KmTBCr20Mo2 high-chrome cast iron was treated by electromagnetic stirring method under the different parameters.The results show that the solidification microstructures of high melting point alloy could be improved through electromagnetic stirring of which power and stirring time all have effects on the microstructure.Under the same stirring power, with the increasing of stirring time, the primary phase will continuously change.When the stirring power is high, great changes of the primary phase will occur in a short time.%为了研究电磁搅拌对高熔点合金组织的影响,在不同工艺条件下对KmTBCr20Mo2高铬铸铁进行电磁搅拌.试验结果表明:电磁搅拌可以有效改变高铬铸铁的组织状态,搅拌功率大小、搅拌时间长短对搅拌效果均存在影响,在相同的电磁搅拌功率条件下,随搅拌时间的延长初生相会不断变化,搅拌功率较大时在较短的搅拌时间内就能够使初生相产生较大的变化.

  3. Design strategy and process optimization for reactors with continuous transport of an immobilized enzyme

    Vos, H.J.; Luyben, K.Ch.A.M.; Westerterp, K.R.

    1993-01-01

    In order to operate a process which uses immobilized enzymes at constant conversion and constant capacity, the refreshment of the enzyme must be continuous. In this paper, two reactor types with continuous refreshment of the biocatalyst are discussed: the stirred tank and the multistage fluidized be

  4. Research progress of macromixing in multiphase stirred vessels%多相搅拌槽内宏观混合研究进展

    程荡; 程景才; 雍玉梅; 杨超; 毛在砂

    2011-01-01

    Multiphase stirred reactor is common unit operation equipment in process industry such as chemical industry and metallurgy.Multiphase mixing is of great significance for the design, optimization and scale-up of multiphase stirred reactors.Mixing time is an important parameter for characterizing the macromixing process in stirred reactors.Based on the experiment and numerical simulation, the study on the liquid phase mixing time of multiphase stirred reactor was reviewed; the multiphase stirred reactors were categorized as gas-liquid, solid-liquid,liquid-liquid and gas-liquid-solid systems; and the influences of dispersed phase, type of impeller, rotational speed, baffle plate, etc., on continuous mixing time were analyzed.The correlations of mixing time in multiphase stirred reactors were generalized.Several suggestions were presented for further in-depth research on macromixing in multiphase stirred reactors.%多相搅拌槽反应器广泛应用于化工、冶金等过程工业中,而多相混合状态对于多相搅拌槽反应器的设计、优化和放大具有重要意义.混合时间是表征其宏观混合过程的一个重要参数.文中从实验和数值模拟二方面对多相搅拌槽反应器的液相混合时间研究进行综述,对气液、液固、液液、气液固4种体系的多相搅拌槽进行了分类总结,讨论了分散相、桨型、转速、挡板等因素对连续相混合时间的影响.对多相搅拌槽内估算混合时间的经验关联式进行了归纳,并展望了未来多相搅拌槽内宏观混合研究的发展方向.

  5. Retractable Pin Tools for the Friction Stir Welding Process

    1998-01-01

    Two companies have successfully commercialized a specialized welding tool developed at the Marshall Space Flight Center (MSFC). Friction stir welding uses the high rotational speed of a tool and the resulting frictional heat created from contact to crush, 'stir' together, and forge a bond between two metal alloys. It has had a major drawback, reliance on a single-piece pin tool. The pin is slowly plunged into the joint between two materials to be welded and rotated as high speed. At the end of the weld, the single-piece pin tool is retracted and leaves a 'keyhole,' something which is unacceptable when welding cylindrical objects such as drums, pipes and storage tanks. Another drawback is the requirement for different-length pin tools when welding materials of varying thickness. An engineer at the MSFC helped design an automatic retractable pin tool that uses a computer-controlled motor to automatically retract the pin into the shoulder of the tool at the end of the weld, preventing keyholes. This design allows the pin angle and length to be adjusted for changes in material thickness and results in a smooth hole closure at the end of the weld. Benefits of friction stir welding, using the MSFC retractable pin tool technology, include the following: The ability to weld a wide range of alloys, including previously unweldable and composite materials; provision of twice the fatigue resistance of fusion welds and no keyholes; minimization of material distortion; no creation of hazards such as welding fumes, radiation, high voltage, liquid metals, or arcing; automatic retraction of the pin at the end of the weld; and maintaining full penetration of the pin.

  6. Controlling Force and Depth in Friction Stir Welding

    Adams, Glynn; Loftus, Zachary; McCormac, Nathan; Venable, Richard

    2005-01-01

    Feedback control of the penetration force applied to a pin tool in friction stir welding has been found to be a robust and reliable means for controlling the depth of penetration of the tool. This discovery has made it possible to simplify depth control and to weld with greater repeatability, even on workpieces with long weld joints. Prior to this discovery, depths of penetration in friction stir welding were controlled by hard-tooled roller assemblies or by depth actuators controlled by feedback from such external sensors as linear variable-differential transformers or laser-based devices. These means of control are limited: A hard-tooled roller assembly confines a pin tool to a preset depth that cannot be changed easily during the welding process. A measurement by an external sensor is only an indirect indicative of the depth of penetration, and computations to correlate such a measurement with a depth of penetration are vulnerable to error. The present force-feedback approach exploits the proportionality between the depth and the force of penetration Unlike a depth measurement taken by an external sensor, a force measurement can be direct because it can be taken by a sensor coupled directly to the pin tool. The reading can be processed through a modern electronic servo control system to control an actuator to keep the applied penetration force at the desired level. In comparison with the older depth-control methods described above, this method offers greater sensitivity to plasticizing of the workpiece metal and is less sensitive to process noise, resulting in a more consistent process. In an experiment, a tapered panel was friction stir welded while controlling the force of penetration according to this method. The figure is a plot of measurements taken during the experiment, showing that force was controlled with a variation of 200 lb (890 N), resulting in control of the depth of penetration with a variation of 0.004 in. (0.1 mm).

  7. Analysis of stirring efficiency in reverberation chamber with combined stirring%混响室复合搅拌方式的搅拌效率分析

    刘逸飞; 陈永光; 王庆国; 程二威

    2013-01-01

    In order to evaluate the stirring efficiency in the reverberation chamber under different stirring modes, and improve the accuracy of the measurement, the method for calculating the number of independent samples which is an important indicator is introduced briefly. The frequencies of 200, 500 and 1000 MHz are chosen to evaluate the stirring efficiency of mechanical stirring and frequency stirring. The calculated number of independent samples shows that the stirring efficiency of the two stirring modes is proportional to the operating frequency. In the mechanical stirring mode, the stirring efficiency can be significantly improved when stirrers work at different speed ratios, and the larger stirring bandwidth is chosen, the higher stirring efficiency can be obtained in the frequency stirring mode, but the number of independent samples has an upper limit in the order of hundreds. Thus the combined stirring method based on mechanical stirring and frequency stirring is proposed, and the stirring efficiency is analyzed deeply, also the formula for calculating the independent samples is given. The test results show that the number of independent samples can be drastically increased under the combined stirring mode.%为了评价混响室在不同搅拌方式下的搅拌效率,提高相关测试的精确度,对独立采样数这一重要指标的计算方法做了简单介绍,并在某大型混响室内,对200,500,1000 MHz频点下的机械搅拌与频率搅拌方式的搅拌效率进行了试验分析.结果表明:二者的搅拌效率均与工作频率成正比;在机械搅拌方式下,多个搅拌器在不同转速比下能够显著提高搅拌效率;频率搅拌的搅拌带宽选取越大搅拌效率越高;两种搅拌方式提供的独立采样点数均存在一个上限值.通过分析对比,提出了基于机械搅拌与频率搅拌相结合的复合搅拌方式,并对该方式的搅拌效率进行了重点分析,给出了该方式下独立采样点的计算

  8. Friction Stir Spot Welding of Advanced High Strength Steels

    Hovanski, Yuri; Santella, M. L.; Grant, Glenn J.

    2009-12-28

    Friction stir spot welding was used to join two advanced high-strength steels using polycrystalline cubic boron nitride tooling. Numerous tool designs were employed to study the influence of tool geometry on weld joints produced in both DP780 and a hot-stamp boron steel. Tool designs included conventional, concave shouldered pin tools with several pin configurations; a number of shoulderless designs; and a convex, scrolled shoulder tool. Weld quality was assessed based on lap shear strength, microstructure, microhardness, and bonded area. Mechanical properties were functionally related to bonded area and joint microstructure, demonstrating the necessity to characterize processing windows based on tool geometry.

  9. Micromechanical Simulation of Deformation of Friction Stir Welded Components

    Sidle, B. C.; Dawson, P. R.; Boyce, D. E.

    2004-06-01

    A microstructure-based finite element formulation for the mechanical response of friction stir welded AL-6XN stainless steel is presented. The welding process generates regions of substantial variations in material state and properties that contribute to strong heterogeneities in the mechanical behavior of welded components We modeled the system with a multiscale elastoplastic formulation in which polycrystalline behavior is computed as the integrated responses of constituent crystals. Model validation is made through comparisons to post-test measurements of shape and hardness and to lattice strain measurements from in situ neutron diffraction experiments.

  10. Friction stir welding (FSW of aluminium foam sandwich panels

    M. Bušić

    2016-07-01

    Full Text Available The article focuses on the influence of welding speed and tool tilt angle upon the mechanical properties at the friction stir welding of aluminium foam sandwich panels. Double side welding was used for producing butt welds of aluminium sandwich panels applying insertion of extruded aluminium profile. Such insertion provided lower pressure of the tool upon the aluminium panels, providing also sufficient volume of the material required for the weldment formation. Ultimate tensile strength and flexural strength for three-point bending test have been determined for samples taken from the welded joints. Results have confirmed anticipated effects of independent variables.

  11. Phased array ultrasonic inspection of Friction Stir Weldments

    Lamarre, André; Moles, Michael; Lupien, Vincent

    2000-05-01

    Phased array ultrasonic inspection methods have been developed for the rapid inspection of Friction Stir Weldments (FSW) on Delta rocket cryogenic tanks. A comprehensive review was performed to identify NDE methods that are suitable for the detection of defects in this new welding process. The search included a review of traditional and advanced NDE methods that were capable of demonstrating both the sensitivity and inspection rates required for this examination. This paper will discuss the theory behind phased array techniques, fundamentals of several probe designs for FSW configurations, and the advantages of using phased arrays over conventional NDE methods for this applications.

  12. Hybrid Friction Stir Welding of High-carbon Steel

    Don-Hyun Choi; Seung-Boo Jung; Chang-Yong Lee; Byung-Wook Ahn; Jung-Hyun Choi; Yun-Mo Yeon; Keun Song; Seung-Gab Hong; Won-Bae Lee; Ki-Bong Kang

    2011-01-01

    A high-carbon steel joint, SK5 (0.84 wt% C), was successfully welded by friction stir welding (FSW), both without and with a gas torch, in order to control the cooling rate during welding. After welding, the weld zone comprised gray and black regions, corresponding to microstructural variation: a martensite structure and a duplex structure of ferrite and cementite, respectively. The volume fraction of the martensite structure and the Vickers hardness in the welds were decreased with the using of the gas torch, which was related with the lower cooling rate.

  13. Friction stir welding tool and process for welding dissimilar materials

    Hovanski, Yuri; Grant, Glenn J; Jana, Saumyadeep; Mattlin, Karl F

    2013-05-07

    A friction stir welding tool and process for lap welding dissimilar materials are detailed. The invention includes a cutter scribe that penetrates and extrudes a first material of a lap weld stack to a preselected depth and further cuts a second material to provide a beneficial geometry defined by a plurality of mechanically interlocking features. The tool backfills the interlocking features generating a lap weld across the length of the interface between the dissimilar materials that enhances the shear strength of the lap weld.

  14. Friction Stir Processing of ODS and FM Steels

    Kang, Suk Hoon; Chun, Young Bum; Noh, Sang Hoon; Jang, Jin Sung; Kim, Tae Kyu [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2013-10-15

    In ODS steels, it is well known that uniform nano-oxide dispersoids act as pinning points to obstruct dislocation and grain boundary motion, however, those advantages will be disappeared while the material is subjected to the high temperature of conventional fusion welding. Rotary friction welding, also referred to as friction stir welding (FSW), has shown great promise as a method for welding traditionally difficult to weld materials such as aluminum alloys. This relatively new technology has more recently been applied to higher melting temperature alloys such as steels, nickel-based and titanium alloys. Friction stir processing (FSP) is a method of changing the properties of a metal through intense, localized plastic deformation. FSW is the precursor of the FSP technique. When ideally implemented, this process mixes the material without changing the phase and creates a microstructure with fine, equiaxed grains. This homogeneous grain structure, separated by high-angle boundaries, allows some alloys to take on superplastic properties. In this study, FSW is used as a substitutive welding process between FMS tube and ODS parts. The dimension of tube is 7.0 OD, 0.5 T. During the FSW, dynamic-recrystallized grains are developed; the uniform oxides dispersion is preserved in the metal matrix. The microstructure and microtexture of the material near the stir zone is found to be influenced by the rotational behavior of the tool. The additive effect from FSP on sample surface is considered. Since the mechanical alloying (MA) and FSP commonly apply extreme shear deformation on materials, the dispersion of oxide particle in ODS steels is very active during both processes. Friction stir welding appears to be a very promising technique for the welding of FMS and ODS steels in the form of sheet and tube. FSW could successfully produce defect-free welds on FMS tubes and ODS ring assembly. FSW produces a fine grain structure consisting of ferrite and martensite, and the oxide

  15. Developing Friction Stir Welding Process Model for ICME Application

    Yang, Yu-Ping

    2015-01-01

    A framework for developing a product involving manufacturing processes was developed with integrated computational materials engineering approach. The key component in the framework is a process modeling tool which includes a thermal model, a microstructure model, a thermo-mechanical, and a property model. Using friction stir welding (FSW) process as an example, development of the process modeling tool was introduced in detail. The thermal model and the microstructure model of FSW of steels were validated with the experiment data. The model can predict reasonable temperature and hardness distributions as observed in the experiment. The model was applied to predict residual stress and joint strength of a pipe girth weld.

  16. In-syringe-stirring: A novel approach for magnetic stirring-assisted dispersive liquid–liquid microextraction

    Horstkotte, Burkhard [Department of Analytical Chemistry, Faculty of Pharmacy, Charles University, Heyrovského 1203, CZ-50005 Hradec Králové (Czech Republic); Laboratory of Environmental Analytical Chemistry – LQA2, University of the Balearic Islands, Cra. Valldemossa km 7.5, 07122 Palma de Mallorca (Spain); Suárez, Ruth [Laboratory of Environmental Analytical Chemistry – LQA2, University of the Balearic Islands, Cra. Valldemossa km 7.5, 07122 Palma de Mallorca (Spain); Solich, Petr [Department of Analytical Chemistry, Faculty of Pharmacy, Charles University, Heyrovského 1203, CZ-50005 Hradec Králové (Czech Republic); Cerdà, Víctor, E-mail: victor.cerda@uib.es [Laboratory of Environmental Analytical Chemistry – LQA2, University of the Balearic Islands, Cra. Valldemossa km 7.5, 07122 Palma de Mallorca (Spain)

    2013-07-25

    Graphical abstract: -- Highlights: •We propose a new automatic magnetic stirring assisted dispersive liquid–liquid microextraction. •It allows the extraction of aluminum from seawater and freshwater samples within less than 4 min. •The method was applicable to the natural samples. -- Abstract: For the first time, the use of a magnetic stirrer within the syringe of an automated syringe pump and the resulting possible analytical applications are described. A simple instrumentation following roughly the one from sequential injection analyzer systems is used in combination with an adaptor, which is placed onto the barrel of a glass syringe. Swirling around the longitudinal axis of the syringe and holding two strong neodymium magnets, it causes a rotating magnetic field and serves as driver for a magnetic stirring bar placed inside of the syringe. In a first study it was shown that this approach leads to a sealed but also automatically adaptable reaction vessel, the syringe, in which rapid and homogeneous mixing of sample with the required reagents within short time can be carried out. In a second study in-a-syringe magnetic stirring-assisted dispersive liquid–liquid microextraction (MSA-DLLME) was demonstrated by the application of the analyzer system to fluorimetric determination of aluminum in seawater samples using lumogallion. A linear working range up to 1.1 μmol L{sup −1} and a limit of detection of 6.1 nmol L{sup −1} were found. An average recovery of 106.0% was achieved for coastal seawaters with a reproducibility of 4.4%. The procedure lasted 210 s including syringe cleaning and only 150 μL of hexanol and 4.1 mL of sample were required.

  17. Closed-Loop Control of the Thermal Stir Welding Process to Enable Rapid Process/Part Qualification Project

    National Aeronautics and Space Administration — Thermal Stir Welding (TSW) provides advancement over the more conventional Friction Stir Welding (C-FSW) process because it separates the primary processes variables...

  18. Colosed-Loop Control of the Thermal Stir Welding Process to Enable Rapid Process/Ppart Qualification Project

    National Aeronautics and Space Administration — Thermal Stir Welding (TSW) provides advancement over the more conventional Friction Stir Welding (C-FSW) process because it separates the primary processes variables...

  19. Analysis of the thin layer of Galactic warm ionized gas in the range 20 < l < 30 deg, -1.5 < b < +1.5 deg

    Paladini, R; Davies, R D; Giard, M

    2005-01-01

    We present an analysis of the thin layer of Galactic warm ionized gas at an angular resolution ~ 10'. This is carried out using radio continuum data at 1.4 GHz, 2.7 GHz and 5 GHz in the coordinate region 20 < l < 30 deg, -1.5 < b < +1.5 deg. For this purpose, we evaluate the zero level of the 2.7 and 5 GHz surveys using auxiliary data at 2.3 GHz and 408 MHz. The derived zero level corrections are T_{zero}(2.7 GHz)=0.15 +/- 0.06 K and T_{zero}(5 GHz)=0.1 +/- 0.05 K. We separate the thermal (free-free) and non-thermal (synchrotron) component by means of a spectral analysis performed adopting an antenna temperature spectral index -2.1 for the free-free emission, a realistic spatial distribution of indices for the synchrotron radiation and by fitting, pixel-by-pixel, the Galactic spectral index. We find that at 5 GHz, for |b| = 0 deg, the fraction of thermal emission reaches a maximum value of 82%, while at 1.4 GHz, the corresponding value is 68%. In addition, for the thermal emission, the analysis in...

  20. Multi-Criteria Optimization in Friction Stir Welding Using a Thermal Model with Prescribed Material Flow

    Tutum, Cem Celal; Deb, Kalyanmoy; Hattel, Jesper Henri

    2013-01-01

    Friction stir welding (FSW) is an innovative solid-state joining process providing products with superior mechanical properties. It utilizes a rotating tool being submerged into the joint line and traversed while stirring the two pieces of metal together to form the weld. The temperature distribu...

  1. Direct microscopy of alloy nucleation, solidification and ageing (coarsening) during stir casting

    Smeulders, R. J.; Mischgofsky, F. H.; Frankena, H. J.

    1986-07-01

    The mechanisms governing the slurry rheology and the particle shape and size distribution during the stir casting of low fractions of a solid material (about 1 to 10 vol pct) are investigated experimentally up to high stirring rates (50 per s). Experimental results obtained for a model substance indicate that several mechanisms are effective nearly simultaneously.

  2. Effects of Laser Peening, and Shot Peening, on Friction Stir Welding

    Hatamleh, Omar; Hackel, Lloyd; Rankin, Jon; Truong, Chanh; Walter, Matt

    2006-01-01

    A viewgraph presentation describing the effects of laser peening and shot peening on friction stir welding is shown. The topics include: 1) Background; 2) Friction Stir Welding (FSW); 3) Microstructure; 4) Laser & Shot Peening; 5) Residual Stresses; 6) Tensile Behavior; 7) Fatigue Life & Surface Roughness; 8) Crack Growth; and 9) Benefits.

  3. Fatigue and Damage Tolerance of Friction Stir Welded Joints for Aerospace Applications

    Lemmen, H.J.K.

    2010-01-01

    Friction stir welding is a young welding process with high potential to replace riveted joints in aerospace structures like the fuselage. Friction stir welding is a robust process and capable of welding high strength aluminum alloys. Therefore it can lead to both costs and weight savings. To substit

  4. Strong sensitivity of Southern Ocean carbon uptake and nutrient cycling to wind stirring

    K. B. Rodgers

    2013-09-01

    Full Text Available Here we test the hypothesis that winds have an important role in determining the rate of exchange of CO2 between the atmosphere and ocean through wind stirring over the Southern Ocean. This is tested with a sensitivity study using an ad hoc parameterization of wind stirring in an ocean carbon cycle model. The objective is to identify the way in which perturbations to the vertical density structure of the planetary boundary in the ocean impacts the carbon cycle and ocean biogeochemistry. Wind stirring leads to reduced uptake of CO2 by the Southern Ocean over the period 2000–2006, with differences of order 0.9 Pg C yr−1 over the region south of 45° S. Wind stirring impacts not only the mean carbon uptake, but also the phasing of the seasonal cycle of carbon and other species associated with ocean biogeochemistry. Enhanced wind stirring delays the seasonal onset of stratification, and this has large impacts on both entrainment and the biological pump. It is also found that there is a strong sensitivity of nutrient concentrations exported in Subantarctic Mode Water (SAMW to wind stirring. This finds expression not only locally over the Southern Ocean, but also over larger scales through the impact on advected nutrients. In summary, the large sensitivity identified with the ad hoc wind stirring parameterization offers support for the importance of wind stirring for global ocean biogeochemistry, through its impact over the Southern Ocean.

  5. Gas-solid hydroxyethylation of potato starch in a stirred vibrating fluidized bed reactor

    Kuipers, N.J M; Stamhuis, Eize; Beenackers, A.A C M

    1996-01-01

    A novel reactor for modifying cohesive C-powders such as in the gas-solid hydroxyethylation of semidry potato starch is characterized, the so-called stirred vibrating fluidized bed reactor. Good fluidization characteristics are obtained in this reactor for certain combinations of stirring and vibrat

  6. 7 CFR 58.711 - Cheddar, colby, washed or soaked curd, granular or stirred curd cheese.

    2010-01-01

    ... requirements equivalent to U.S. Standard Grade for Bulk American Cheese for Manufacturing provided the quantity... stirred curd cheese. 58.711 Section 58.711 Agriculture Regulations of the Department of Agriculture... soaked curd, granular or stirred curd cheese. Cheese, used in the manufacture of pasteurized...

  7. Metal Cutting Theory and Friction Stir Welding Tool Design

    Payton, Lewis N.

    2003-01-01

    Friction Stir Welding (FSW) is a relatively new industrial process that was invented at The Weld Institute (TWI, United Kingdom) and patented in 1992 under research funded by in part by the National Aeronautics and Space Administration (NASA). Often quoted advantages of the process include good strength and ductility along with minimization of residual stress and distortion. Less well advertised are the beneficial effects of this solid state welding process in the field of occupational and environmental safety. It produces superior weld products in difficult to weld materials without producing any toxic fumes or solid waste that must be controlled as hazardous waste. In fact, it reduces noise pollution in the workspace as well. In the early days of FSW, most welding was performed on modified machine tools, in particular on milling machines with modified milling cutters. In spite of the obvious milling heritage of the process, the techniques and lessons learned from almost 250 years of successful metalworking with milling machines have not been applied in the field of modern Friction Stir Welding. The goal of the current research was to study currently successful FSW tools and parameterize the process in such a way that the design of new tools for new materials could be accelerated. Along the way, several successful new tooling designs were developed for current issues at the Marshall Space Flight Center with accompanying patent disclosures

  8. JOINING DISSIMILAR MATERIALS USING FRICTION STIR SCRIBE TECHNIQUE

    Upadhyay, Piyush; Hovanski, Yuri; Jana, Saumyadeep; Fifield, Leonard S.

    2016-09-01

    Development of robust and cost effective method of joining dissimilar materials can provide a critical pathway to enable widespread use of multi-material design and components in mainstream industrial applications. The use of multi-material components such as Steel-Aluminum, Aluminum-Polymer allows design engineers to optimize material utilization based on service requirements and often lead weight and cost reductions. However producing an effective joint between materials with vastly different thermal, microstructural and deformation response is highly problematic using conventional joining and /or fastening methods. This is especially challenging in cost sensitive high volume markets that largely rely on low–cost joining solutions. Friction Stir Scribe technology was developed to meet the demands of joining materials with drastically different properties and melting regimes. The process enables joining of light metals like Magnesium and Aluminum to high temperature materials like Steels and Titanium. Additionally viable joints between polymer composites and metal can also be made using this method. This paper will present state of the art, progress made and challenges associated with this innovative derivative of Friction Stir welding in reference to joining dissimilar metals and polymer/metal combinations.

  9. Simulation of Friction Stir Processing in 304L Stainless Steel

    Miles M.P.

    2016-01-01

    Full Text Available A major dilemma facing the nuclear industry is repair or replacement of stainless steel reactor components that have been exposed to neutron irradiation. When conventional fusion welding is used for weld repair, the high temperatures and thermal stresses inherent in the process enhance the growth of helium bubbles, causing intergranular cracking in the heat-affected zone (HAZ. Friction stir processing (FSP has potential as a weld repair technique for irradiated stainless steel, because it operates at much lower temperatures than fusion welding, and is therefore less likely to cause cracking in the HAZ. Numerical simulation of the FSP process in 304L stainless steel was performed using an Eulerian finite element approach. Model input required flow stresses for the large range of strain rates and temperatures inherent in the FSP process. Temperature predictions in three locations adjacent to the stir zone were accurate to within 4% of experimentally measure values. Prediction of recrystallized grain size at a location about 6mm behind the tool center was less accurate, because the empirical model employed for the prediction did not account for grain growth that occurred after deformation in the experiment was halted.

  10. Modified Mathematical Model For Neutralization System In Stirred Tank Reactor

    Ahmmed Saadi Ibrehem

    2011-05-01

    Full Text Available A modified model for the neutralization process of Stirred Tank Reactors (CSTR reactor is presented in this study. The model accounts for the effect of strong acid [HCL] flowrate and strong base [NaOH] flowrate with the ionic concentrations of [Cl-] and [Na+] on the Ph of the system. In this work, the effect of important reactor parameters such as ionic concentrations and acid and base flowrates on the dynamic behavior of the CSTR is investigated and the behavior of mathematical model is compared with the reported models for the McAvoy model and Jutila model. Moreover, the results of the model are compared with the experimental data in terms of pH dynamic study. A good agreement is observed between our model prediction and the actual plant data. © 2011 BCREC UNDIP. All rights reserved(Received: 1st March 2011, Revised: 28th March 2011; Accepted: 7th April 2011[How to Cite: A.S. Ibrehem. (2011. Modified Mathematical Model For Neutralization System In Stirred Tank Reactor. Bulletin of Chemical Reaction Engineering & Catalysis, 6(1: 47-52. doi:10.9767/bcrec.6.1.825.47-52][How to Link / DOI: http://dx.doi.org/10.9767/bcrec.6.1.825.47-52 || or local:  http://ejournal.undip.ac.id/index.php/bcrec/article/view/825 ] | View in 

  11. Mixing Study in an Unbaffled Stirred Precipitator Using LES Modelling

    Murielle Bertrand

    2012-01-01

    Full Text Available This paper describes the CFD modelling of a reactor operating in the nuclear industry using LES approach. The reactor consists of an unbaffled stirred tank reactor in which plutonium precipitation reactions are carried out. The flow generated in such a precipitator is complex and there is very little information available in the literature about unbaffled reactors stirred with magnetic rod. That is why a hydrodynamic modelling has been developed using computational fluid dynamics (CFD in order to get accurate description of mixing phenomena inside the precipitator and therefore to be able to predict the solid particle properties. Due to the strong turbulence anisotropy, the turbulence transport simulation is achieved by a large eddy simulation (LES approach which gives unsteady solutions. The numerical simulations are performed in 3D using the Trio_U code developed at the Commissariat à l'Énergie Atomique. The predictive performances of the modelling are analysed through a mixing phenomena study. Both experimental and numerical studies are performed. This work shows how hydrodynamics inside the reactor can have a noticeable effect on the precipitate properties and how LES modelling is a very effective tool for the process control.

  12. Dynamics of fluid and light intensity in mechanically stirred photobioreactor.

    Zhang, T

    2013-10-10

    Turbulent flows in a single-stage and a two-stage impeller-stirred photobioreactor with a simple geometric configuration were analyzed using computational fluid dynamics. The trajectories of the microorganisms entrained in the flow field were traced by the particle tracking method. By projecting these trajectories onto a radial-axial (r-z) plane with a given azimuth angle, we were able to observe four different dynamics zones: circulation, pure rotation, trap, and slow-motion. Within the pure rotation zone, turbulence can be observed near the edges of the impeller. The light intensity and the light/dark cycles subjected by the microorganisms differ significantly in these zones. These differences can be further changed by providing different incident light illuminations on the reactor surface. The dynamics zones can be altered by modifying the geometric configuration of the reactor and the impeller stirring mechanism. In combination with the utilization of different incident light illuminations, the light intensity dynamics and the light/dark cycles subjected by the microorganisms can be controlled such that an optimal photobioreactor design with a high efficiency of light utilization and a high formation rate of the biochemical products can be realized.

  13. Joining Dissimilar Materials Using Friction Stir Scribe Technique

    Upadhyay, Piyush [Pacific Northwest National Laboratory, Richland 99352, WA e-mail: piyush.upadhyay@pnnl.gov; Hovanski, Yuri [Pacific Northwest National Laboratory, Richland 99352, WA; Jana, Saumyadeep [Pacific Northwest National Laboratory, Richland 99352, WA; Fifield, Leonard S. [Pacific Northwest National Laboratory, Richland 99352, WA

    2016-10-03

    Development of a robust and cost-effective method of joining dissimilar materials could provide a critical pathway to enable widespread use of multi-material designs and components in mainstream industrial applications. The use of multi-material components such as steel-aluminum and aluminum-polymer would allow design engineers to optimize material utilization based on service requirements and could often lead to weight and cost reductions. However, producing an effective joint between materials with vastly different thermal, microstructural, and deformation responses is highly problematic using conventional joining and/or fastening methods. This is especially challenging in cost sensitive, high volume markets that largely rely on low cost joining solutions. Friction stir scribe technology was developed to meet the demands of joining materials with drastically different properties and melting regimes. The process enables joining of light metals like magnesium and aluminum to high temperature materials like steel and titanium. Viable joints between polymer composites and metal can also be made using this method. This paper will present the state of the art, progress made, and challenges associated with this innovative derivative of friction stir welding in reference to joining dissimilar metals and polymer/metal combinations.

  14. The Correlation of Stir Zone Texture Development with Base Metal Texture and Tool-Induced Deformation in Friction Stir Processing of Severely Deformed Aluminum

    Sarkari Khorrami, M.; Kazeminezhad, Mohsen; Miyashita, Y.; Kokabi, A. H.

    2017-01-01

    The texture development during friction stir processing (FSP) of 1050 aluminum severely deformed at the strain magnitude of 2.32 was comprehensively discussed. It was observed that the component bar{B} of the ideal shear texture along with the cube texture was developed in the severely deformed base metal. The effects of base metal texture on the texture development of stir zone, thermo-mechanically affected zone, and heat-affected zone during FSP were examined. Also, the developed texture components in the vicinity of the FSP tool and the stir zone were correlated to the deformation induced by the rotating tool which consisted of pin and shoulder. The observed texture components in the longitudinal section of the stir zone were found coincided with the ideal shear ones, but different from those observed in the severely deformed base metal. It could be responsible for the fact that the material beneath the FSP tool is predominantly deformed and stirred by the shoulder rather than the pin. The independency of texture development in the stir zone from pin-induced deformation was also consistent with the observation associated with the stir zone geometry which was independent of the pin geometry. Microstructural evolutions in the regions located ahead of the FSP tool manifested the incident of static recovery and recrystallization as a result of the stored strain in the severely deformed base metal. These led to the development of almost random texture and the deterioration of base metal texture in this region. This suggested the independency of texture development in the stir zone from the texture of severely deformed base metal.

  15. Numerical simulation of temperature distribution using finite difference equations and estimation of the grain size during friction stir processing

    Arora, H.S. [School of Mechanical, Material and Energy Engineering, Indian Institute of Technology Ropar, Rupnagar, Punjab 140001 (India); Singh, H., E-mail: harpreetsingh@iitrpr.ac.in [School of Mechanical, Material and Energy Engineering, Indian Institute of Technology Ropar, Rupnagar, Punjab 140001 (India); Dhindaw, B.K. [School of Materials and Mineral Resources, Universiti Sains Malaysia, Engineering Campus, Nibong Tebal, Pulau Penang 14300 (Malaysia)

    2012-05-01

    Highlights: Black-Right-Pointing-Pointer Magnesium alloy AE42 was friction stir processed under different cooling conditions. Black-Right-Pointing-Pointer Heat flow model was developed using finite difference heat equations. Black-Right-Pointing-Pointer Generalized MATLAB code was developed for solving heat flow model. Black-Right-Pointing-Pointer Regression equation for estimation of grain size was developed. - Abstract: The present investigation is aimed at developing a heat flow model to simulate temperature history during friction stir processing (FSP). A new approach of developing implicit form of finite difference heat equations solved using MATLAB code was used. A magnesium based alloy AE42 was friction stir processed (FSPed) at different FSP parameters and cooling conditions. Temperature history was continuously recorded in the nugget zone during FSP using data acquisition system and k type thermocouples. The developed code was validated at different FSP parameters and cooling conditions during FSP experimentation. The temperature history at different locations in the nugget zone at different instants of time was further utilized for the estimation of grain growth rate and final average grain size of the FSPed specimen. A regression equation relating the final grain size, maximum temperature during FSP and the cooling rate was developed. The metallurgical characterization was done using optical microscopy, SEM, and FIB-SIM analysis. The simulated temperature profiles and final average grain size were found to be in good agreement with the experimental results. The presence of fine precipitate particles generated in situ in the investigated magnesium alloy also contributed in the evolution of fine grain structure through Zener pining effect at the grain boundaries.

  16. ZnS thin film deposited with chemical bath deposition process directed by different stirring speeds

    Zhang, Y.; Dang, X. Y.; Jin, J.; Yu, T.; Li, B. Z.; He, Q.; Li, F. Y.; Sun, Y.

    2010-09-01

    In this combined film thickness, scanning electron microscopy (SEM), X-ray diffraction and optical properties study, we explore the effects of different stirring speeds on the growth and optical properties of ZnS film deposited by CBD method. From the disclosed changes of thickness of ZnS film, we conclude that film thickness is independent of the stirring speeds in the heterogeneous process (deposition time less than 40 min), but increases with the stirring speeds and/or deposition time increasing in the homogeneous process. Grazing incident X-ray diffraction (GIXRD) and the study of optical properties disclosed that the ZnS films grown with different stirring speeds show partially crystallized film and exhibit good transmittance (70-88% in the visible region), but the stirring speeds cannot give much effects on the structure and optical properties in the homogeneous process.

  17. Fatigue Performance of Friction-Stir-Welded Al-Mg-Sc Alloy

    Zhemchuzhnikova, Daria; Mironov, Sergey; Kaibyshev, Rustam

    2017-01-01

    Fatigue behavior of a friction-stir-welded Al-Mg-Sc alloy was examined in cast and hot-rolled conditions. In both cases, the joints failed in the base material region and therefore the joint efficiency was 100 pct. The specimens machined entirely from the stir zone demonstrated fatigue strength superior to that of the base material in both preprocessed tempers. It was shown that the excellent fatigue performance of friction-stir joints was attributable to the ultra-fine-grained microstructure, the low dislocation density evolved in the stir zone, and the preservation of Al3Sc coherent dispersoids during welding. The formation of such structure hinders the initiation and growth of fatigue microcracks that provides superior fatigue performance of friction-stir welds.

  18. The Effect of Premixed Al-Cu Powder on the Stir Zone in Friction Stir Welding of AA3003-H18

    Abnar, B.; Kazeminezhad, M.; Kokabi, A. H.

    2015-02-01

    In this research, 3-mm-thick AA3003-H18 non-heat-treatable aluminum alloy plates were joined by friction stir welding (FSW). It was performed by adding pure Cu and premixed Cu-Al powders at various rotational speeds of 800, 1000, and 1200 rpm and constant traveling speeds of 100 mm/min. At first, the powder was filled into the gap (0.2 or 0.4 mm) between two aluminum alloy plates, and then the FSW process was performed in two passes. The microstructure, mechanical properties, and formation of intermetallic compounds were investigated in both cases of using pure Cu and premixed Al-Cu powders. The results of using pure Cu and premixed Al-Cu powders were compared in the stir zone at various rotational speeds. The copper particle distribution and formation of Al-Cu intermetallic compounds (Al2Cu and AlCu) in the stir zone were desirable using premixed Al-Cu powder into the gap. The hardness values were significantly increased by formation of Al-Cu intermetallic compounds in the stir zone and it was uniform throughout the stir zone when premixed Al-Cu powder was used. Also, longitudinal tensile strength from the stir zone was higher when premixed Al-Cu powder was used instead of pure Cu powder.

  19. Development of Finite Element Forulations for High-Fidelity Polycrystals and Damage Avoidance in Friction Stir Welding

    2010-07-26

    simulate friction stir welding processes with a focus on computing conditions that lead to the formation and...focused on advancing the technology of friction stir welding (FSW) in shipbuilding. We developed finite element based simulation methods that can help... simulation capability we com- puted the sensitivity of defect formation to a number of variables associated with friction stir welding , including pin

  20. Tool for Two Types of Friction Stir Welding

    Carter, Robert

    2006-01-01

    A tool that would be useable in both conventional and self-reacting friction stir welding (FSW) has been proposed. The tool would embody both a prior tooling concept for self-reacting FSW and an auto-adjustable pin-tool (APT) capability developed previously as an augmentation for conventional FSW. Some definitions of terms are prerequisite to a meaningful description of the proposed tool. In conventional FSW, depicted in Figure 1, one uses a tool that includes (1) a rotating shoulder on top (or front) of the workpiece and (2) a rotating pin that protrudes from the shoulder into the depth of the workpiece. The main axial force exerted by the tool on the workpiece is reacted through a ridged backing anvil under (behind) the workpiece. When conventional FSW is augmented with an APT capability, the depth of penetration of the pin into the workpiece is varied in real time by a position- or force-control system that extends or retracts the pin as needed to obtain the desired effect. In self-reacting (also known as self-reacted) friction stir welding (SR-FSW), there are two rotating shoulders: one on top (or front) and one on the bottom (or back) of the workpiece. In this case, a threaded shaft protrudes from the tip of the pin to beyond the back surface of the workpiece. The back shoulder is held axially in place against tension by a nut on the threaded shaft. The main axial force exerted on the workpiece by the tool and front shoulder is reacted through the back shoulder and the threaded shaft, back into the FSW machine head, so that a backing anvil is no longer needed. A key transmits torque between the bottom shoulder and the threaded shaft, so that the bottom shoulder rotates with the shaft. A tool for SRFSW embodying this concept was reported in "Mechanism for Self-Reacted Friction Stir Welding" (MFS-31914), NASA Tech Briefs, Vol. 28, No. 10 (October 2004), page 53. In its outward appearance, the proposed tool (see Figure 2) would fit the above description of an SR

  1. Physical Simulation of a Duplex Stainless Steel Friction Stir Welding by the Numerical and Experimental Analysis of Hot Torsion Tests

    da Fonseca, Eduardo Bertoni; Santos, Tiago Felipe Abreu; Button, Sergio Tonini; Ramirez, Antonio Jose

    2016-09-01

    Physical simulation of friction stir welding (FSW) by means of hot torsion tests was performed on UNS S32205 duplex stainless steel. A thermomechanical simulator Gleeble 3800® with a custom-built liquid nitrogen cooling system was employed to reproduce the thermal cycle measured during FSW and carry out the torsion tests. Microstructures were compared by means of light optical microscopy and electron backscatter diffraction. True strain and strain rate were calculated by numerical simulation of the torsion tests. Thermomechanically affected zone (TMAZ) was reproduced at peak temperature of 1303 K (1030 °C), rotational speeds of 52.4 rad s-1 (500 rpm) and 74.5 rad s-1 (750 rpm), and 0.5 to 0.75 revolutions, which represent strain rate between 10 and 16 s-1 and true strain between 0.5 and 0.8. Strong grain refinement, similar to the one observed in the stir zone (SZ), was attained at peak temperature of 1403 K (1130 °C), rotational speed of 74.5 rad s-1 (750 rpm), and 1.2 revolution, which represent strain rate of 19 s-1 and true strain of 1.3. Continuous dynamic recrystallization in ferrite and dynamic recrystallization in austenite were observed in the TMAZ simulation. At higher temperature, dynamic recovery of austenite was also observed.

  2. Friction Stir Welding of ODS and RAFM Steels

    Yu, Zhenzhen; Feng, Zhili; Hoelzer, David; Tan, Lizhen; Sokolov, Mikhail A.

    2015-09-01

    Advanced structural materials such as oxide dispersion strengthened steels and reduced-activation ferritic/martensitic steels are desired in fusion reactors as primary candidate materials for first wall and blanket structures, due to their excellent radiation and high-temperature creep resistance. However, their poor fusion weldability has been the major technical challenge limiting practical applications. For this reason, solid-state friction stir welding (FSW) has been considered for such applications. In this work, the effect of FSW parameters on joining similar and dissimilar advanced structural steels was investigated. Scanning electron microscopy and electron backscatter diffraction methods were used to reveal the effects of FSW on grain size, micro-texture distribution, and phase stability. Hardness mapping was performed to evaluate mechanical properties. Post weld heat treatment was also performed to tailor the microstructure in the welds in order to match the weld zone mechanical properties to the base material.

  3. Tool Geometry for Friction Stir Welding—Optimum Shoulder Diameter

    Mehta, M.; Arora, A.; de, A.; Debroy, T.

    2011-09-01

    The most important geometric parameter in the friction stir welding (FSW) tool design is the shoulder diameter, which is currently estimated by trial and error. Here, we report a combined experimental and theoretical investigation on the influence of shoulder diameter on thermal cycles, peak temperatures, power requirements, and torque during FSW of AA7075-T6. An optimum tool shoulder diameter is identified using a three-dimensional, heat transfer and materials flow model. First, the predictive capability of the model is tested by comparing the computed values of peak temperature, spindle power, and torque requirements for various shoulder diameters against the corresponding experimental data. The change in the values of these variables with shoulder diameter is correctly predicted by the model. The model is then used to identify the optimum tool shoulder diameter that facilitates maximal use of the supplied torque in overcoming interfacial sticking. The tool with optimum shoulder diameter is shown to result in acceptable yield strength (YS) and ductility.

  4. Mixing-Structure Relationship in Jet-Stirred Reactors

    Ayass, Wassim W.

    2016-05-26

    In this study, measurements were performed to assess the overall mixing in jet-stirred reactors (JSRs) passively agitated by feed nozzles. The reactor diameter, nozzle shape, and nozzle diameter were varied to determine the effects of these geometrical parameters on mixing. The mixing was studied at ambient conditions using laser absorption spectroscopy to follow the exit concentration of a tracer gas, carbon dioxide, after a step change in its input flow. The results indicate that the use of a JSR of diameter D = 40 mm, having inclined or crossed nozzles of diameter d = 1 mm is recommended for low residence times up to 0.4 sec, while at moderate/high residence times 0.5-5 sec the use of a JSR of D = 56 mm and d = 0.3 mm having crossed nozzles is suggested.

  5. Friction stir welding (FSW process of copper alloys

    M. Miličić

    2016-01-01

    Full Text Available The present paper analyzes the structure of the weld joint of technically pure copper, which is realized using friction stir welding (FSW. The mechanism of thermo-mechanical processes of the FSW method has been identified and a correlation between the weld zone and its microstructure established. Parameters of the FSW welding technology influencing the zone of the seam material and the mechanical properties of the resulting joint were analyzed. The physical joining consists of intense mixing the base material along the joint line in the “doughy” phase. Substantial plastic deformations immediately beneath the frontal surface of tool provide fine-grained structure and a good quality joint. The optimum shape of the tool and the optimum welding regime (pressure force, rotation speed and the traverse speed of the tool in the heat affected zone enable the achievement of the same mechanical properties as those of the basic material, which justifies its use in welding reliable structures.

  6. Micro friction stir welding of copper electrical contacts

    D. Klobčar

    2014-10-01

    Full Text Available The paper presents an analysis of micro friction stir welding (μFSW of electrolytic tough pitch copper (CuETP in a lap and butt joint. Experimental plan was done in order to investigate the influence of tool design and welding parameters on the formation of defect free joints. The experiments were done using universal milling machine where the tool rotation speed varied between 600 and 1 900 rpm, welding speed between 14 and 93 mm/min and tilt angle between 3° and 5°. From the welds samples for analysis of microstructure and samples for tensile tests were prepared. The grain size in the nugget zone was greatly reduced compared to the base metal and the joint tensile strength exceeded the strength of the base metal.

  7. Interfacial Reaction during Friction Stir Welding of Al and Cu

    Genevois, C.; Girard, M.; Huneau, B.; Sauvage, X.; Racineux, G.

    2011-08-01

    Commercially pure copper was joined to a 1050 aluminum alloy by friction stir welding. A specific configuration where the tool pin was fully located in the aluminum plate was chosen. In such a situation, there is no mechanical mixing between the two materials, but frictional heating gives rise to a significant thermally activated interdiffusion at the copper/aluminum interface. This gives rise to the formation of defect-free joints where the bonding is achieved by a very thin intermetallic layer at the Cu/Al interface. Nanoscaled grains within this bonding layer were characterized using transmission electron microscopy (TEM). Two phases were identified, namely, Al2Cu and Al4Cu9 phases. The nucleation and growth of these two phases are discussed and compared to the standard reactive interdiffusion reactions between Cu and Al.

  8. Electrical process tomography: seeing "without eyes" inside stirred vessels

    MANN R.

    2005-01-01

    Body-scanning exploiting 3-D imaging has revolutionised diagnostics and treatment in medicine. Process engineers would like to be similarly able to image chemical process units in 3-D, but without the £multi-million price tag. UMIST and Leeds University have together, through the Virtual Centre for Industrial Process Tomography (http://www. vcipt.org), pioneered several electrical process tomography techniques and used them in a variety of applications. Illustrations are presented to show how electrical resistance tomography (ERT) has been developed for typical stirred vessels widely encountered in batch process manufacturing. The technique is potentially fast and inexpensive and capable of imaging both dynamic and pseudo-stationary processes. Examples from UMIST's two-tonne vessel will be presented for miscible tracer mixing, as well as gas-liquid and solid-liquid mixing.

  9. Microstructure Evolution during Friction Stir Spot Welding of TRIP steel

    Lomholt, Trine Colding

    Transformation Induced Plasticity (TRIP) steels have been developed for automotive applications due to the excellent high strength and formability. The microstructure of TRIP steels is a complex mixture of various microstructural constituents; ferrite, bainite, martensite and retained austenite....... The TRIP effect is activated under the influence of an external load, thereby leading to a martensitic transformation of the retained austenite. This transformation induced plasticity contributes to the excellent mechanical properties of this class of steels and provides high tensile strength without...... and thereby reduced weight of the vehicles. One of the limitations for the wide application of TRIP steel is associated with joining, since so far no method has succeeded in joining TRIP steel, without comprising the steel properties. In this study, the potential of joining TRIP steel with Friction Stir Spot...

  10. Microstructure characterization of Friction Stir Spot Welded TRIP steel

    Lomholt, Trine Colding; Adachi, Yoshitaka; Peterson, Jeremy

    2012-01-01

    Transformation Induced Plasticity (TRIP) steels have not yet been successfully joined by any welding technique. It is desirable to search for a suitable welding technique that opens up for full usability of TRIP steels. In this study, the potential of joining TRIP steel with Friction Stir Spot......-mechanically affected zones (TMAZ), and two heat-affected zones (HAZ). The dual behavior of the microstructure in the zones is related to the two transition temperatures in steel: A1 and A3. In parts of the TMAZ the microstructure contains ultra fine-grained ferrite. This finding parallels the observation in thermo......-mechanically processed steels, where severe deformation at elevated temperatures is used to produce ultra fine-grained microstructures. Several possible transformation mechanisms could in principle explain the development of ultra fine-grained ferrite, e.g. dynamic recrystallization, strain-induced ferrite...

  11. Designing aluminium friction stir welded joints against multiaxial fatigue

    L. Susmel

    2016-07-01

    Full Text Available The present paper investigates the accuracy of the Modified Wöhler Curve Method (MWCM in estimating multiaxial fatigue strength of aluminium friction stir (FS welded joints. Having developed a bespoke joining technology, circumferentially FS welded tubular specimens of Al 6082-T6 were tested under proportional and non-proportional tension and torsion, the effect of non-zero mean stresses being also investigated. The validation exercise carried out using the experimental results have demonstrated that the MWCM applied in terms of nominal stresses, notch stresses, and also the Point Method is accurate in predicting the fatigue lifetime of the tested FS welded joints, with its use resulting in life estimates that fall within the uniaxial and torsional calibration scatter bands.

  12. Stirring with ghost rods in a lid-driven cavity

    Kumar, Pankaj; Chen, Jie; Stremler, Mark

    2009-11-01

    It has shown that passive fluid particles moving on periodic orbits can be used to `stir' a viscous fluid in a two-dimensional lid-driven cavity that exhibits a figure-eight flow pattern (Stremler & Chen 2007). Fluid motion in the vicinity of these particles produces ``ghost rod'' structures that behave like semi-permeable rods in the flow. Since these ghost rods are present due to the system dynamics, perturbations in the boundary conditions lead to variations in the existence and structure of the ghost rods. We discuss these variations and assess the role of ghost rods in mixing over a range of operating conditions for this system. The results suggest that ghost rods can play an important role in mixing for other counter-rotating flows.

  13. Comparison of fatigue property between friction stir and TIG welds

    Xunhong Wang; Kuaishe Wang; Yang Shen; Kai Hu

    2008-01-01

    The alloy 5052 was welded by friction stir welding (FSW) and tungsten inert gas (TIG) welding. The effect of welding processes (FSW and TIG) on the fatigue properties of 5052 aluminum-welded joints was analyzed based on fatigue testing, and the S-N curve of the joints were established. The results show that the fatigue properties of FSW welded joints are better than those of TIG welded joints. The fatigue strength is determined as 65 Mpa under 106 cycling of fatigue life. The microstructure of joints is fine grains and narrow HAZ zone in FSW welds, which inhibit the growth of cracks and produce high fatigue life compared with that of TIG welds. Fracture morphologies also show that the fatigue fracture results from weld defects.

  14. Pin Tool Geometry Effects in Friction Stir Welding

    Querin, J. A.; Rubisoff, H. A.; Schneider, J. A.

    2009-01-01

    In friction stir welding (FSW) there is significant evidence that material can take one of two different flow paths when being displaced from its original position in front of the pin tool to its final position in the wake of the weld. The geometry of the pin tool, along with the process parameters, plays an important role in dictating the path that the material takes. Each flow path will impart a different thermomechanical history on the material, consequently altering the material microstructure and subsequent weld properties. The intention of this research is to isolate the effect that different pin tool attributes have on the flow paths imparted on the FSWed material. Based on published weld tool geometries, a variety of weld tools were fabricated and used to join AA2219. Results from the tensile properties and microstructural characterization will be presented.

  15. Prolegomena to the Study of Friction Stir Welding

    Nunes, Arthur C., Jr.

    2010-01-01

    The literature contains many approaches toward modeling of the friction stir welding (FSW) process with varying treatments of the weld metal properties. It is worthwhile to consider certain fundamental features of the process before attempting to interpret FSW phenomena: Because of the unique character of metal deformation (as opposed to, say, viscous deformation) a velocity "discontinuity" or shear surface occurs in FSW and determines much of the character of the welding mechanism. A shear surface may not always produce a sound bond. Balancing mechanical power input against conduction and convection heat losses yields a relation, a "temperature index", between spindle speed and travel speed to maintain constant weld temperature. But many process features are only weakly dependent upon temperature. Thus, unlike modeling of metal forming processes, it may be that modeling the FSW process independently of the material conditions has some merit.

  16. Modelling the Thermomechanical Conditions in Friction Stir Welding

    Schmidt, Henrik Nikolaj Blich

    Friction Stir Welding is a solid-state welding process invented by TWI in 1991. The FSW process is unique in the sense that joining of un-weldable alloys readily can be made. The thermomechanical conditions present in the workpiece during the welding process are of great interest since...... these control the properties of the weld. In the present work, a set of experimental, analytical and numerical analyses are carried out in order to evaluate the thermomechanical conditions descriptive for welding of aluminium, in this case AA2024-T3, under a specific set of welding parameters. Despite...... these specific data, the developed models can be applied for other alloys and welding parameters as well. A detailed experiment is carried out which constitutes the basis for the development and validation of the numerical and analytical models presented in this work. The contact condition at the tool...

  17. Simulation of MILD combustion using Perfectly Stirred Reactor model

    Chen, Z.

    2016-07-06

    A simple model based on a Perfectly Stirred Reactor (PSR) is proposed for moderate or intense low-oxygen dilution (MILD) combustion. The PSR calculation is performed covering the entire flammability range and the tabulated chemistry approach is used with a presumed joint probability density function (PDF). The jet, in hot and diluted coflow experimental set-up under MILD conditions, is simulated using this reactor model for two oxygen dilution levels. The computed results for mean temperature, major and minor species mass fractions are compared with the experimental data and simulation results obtained recently using a multi-environment transported PDF approach. Overall, a good agreement is observed at three different axial locations for these comparisons despite the over-predicted peak value of CO formation. This suggests that MILD combustion can be effectively modelled by the proposed PSR model with lower computational cost.

  18. Improving heat transfer in stirred tanks cooled by helical coils

    Pedrosa S.M.C.P.

    2003-01-01

    Full Text Available Stirred Tank Reactors are extensively used in chemical industries. When they are used for highly exothermic reactions, jackets or coils are employed for heat removal. Internal coils can be either helical or axial and they considerably affect the flow inside the reactor because they impose an additional resistance to flow circulation. The aim of this work is to show that the design of vessels cooled by helical coils can be further improved. The design of these reactors follows very much the geometry proposed by Oldshue and Gretton (1954, and some minor modifications in the coil arrangements are likely to improve internal circulation inside these vessels mainly in the region between coils and wall of the vessel. Results show a gain in performance when small alterations are made specially in the shape of the coil arrangement.

  19. Metal cutting analogy for establishing Friction Stir Welding process parameters

    Stafford, Sylvester Allen

    A friction stir weld (FSW) is a solid state joining operation whose processing parameters are currently determined by lengthy trial and error methods. To implement FSWing rapidly in various applications will require an approach for predicting process parameters based on the physics of the process. Based on hot working conditions for metals, a kinematic model has been proposed for calculating the shear strain and shear strain rates during the FSW process, validation of the proposed model with direct measuring is difficult however. Since the shear strain and shear strain rates predicted for the FSW process, are similar to those predicted in metal cutting, validation of the FSW algorithms with microstructural studies of metal chips may be possible leading to the ability to predict FSW processing parameters.

  20. Laser-Assisted Stir Welding of 25-mm-Thick HSLA-65 Plate

    Williamson, Keith M.

    2002-12-01

    Laser-assisted stir welding is a hybrid process that combines energy from a laser with functional heating and mechanical energy to join materials in the solid state. The technology is an adaptation of friction stir welding which is particularly suited for joining thick plates. Aluminum plates up to 75 mm thick have been successfully joined using friction stir welding. Since joining occurs in the solid state, stir technology offers the capability for fabricating full penetration joints in thick plates with better mechanical properties and less weld distortion than is possible by fusion processes. Currently friction stir welding is being used in several industries to improve productivity, reduce weight, and increase the strength of welded structures. Examples include: (a) the aircraft/aerospace industry where stir technology is currently being used to fabricate the space shuttle's external tank as well as components of the Delta family of rockets; (b) the shipping industry where container manufacturers are using stir technology to produce lighter containers with more payload capacity; and (c) the oil industry where offshore platform manufactures are using automated stir welding plants to fabricate large panels and structures up to 16 meters long with widths as required. In all these cases, stir technology has been restricted to aluminum alloys; however, stainless and HSLA 65 steels have been recently stir welded with friction as the primary heat source. One of the difficulties in adapting stir welding to steel is tool wear aggravated by the high tool rubbing velocities needed to provide frictional heat input into the material. Early work showed that the tool shoulder reached temperatures above 1000 C and the weld seam behind the tool stayed within this temperature range for up to 25 mm behind the tool. Cross sections of stir welded samples showed that the heat-affected zone is relatively wide and follows the profile of the tool shoulder. Besides minimizing the tool

  1. Effects of cutting intensity and stirring speed on syneresis and curd losses during cheese manufacture.

    Everard, C D; O'Callaghan, D J; Mateo, M J; O'Donnell, C P; Castillo, M; Payne, F A

    2008-07-01

    Recombined whole milk was renneted under constant conditions of pH, temperature, and added calcium, and the gel was cut at a constant firmness. The effects of cutting and stirring on syneresis and curd losses to whey were investigated during cheese making using a factorial design with 3 cutting modes designed to provide 3 different cutting intensity levels (i.e., total cutting revolutions), 3 levels of stirring speed, and 3 replications. These cutting intensities and stirring speeds were selected to give a wide range of curd grain sizes and curd shattering, respectively. Both factors affected curd losses, and correct selection of these factors is important in the cheesemaking industry. Decreased cutting intensity and increased stirring speed significantly increased the losses of fines and fat from the curd to the whey. Cutting intensities and stirring speeds in this study did not show significant effects on curd moisture content over the course of syneresis. Levels of total solids, fines, and fat in whey were shown to change significantly during syneresis. It is believed that larger curd particles resulting from low cutting intensities coupled with faster stirring speeds resulted in a higher degree of curd shattering during stirring, which caused significant curd losses.

  2. Additional merit of coronal STIR imaging for MR imaging of lumbar spine

    Ranjana Gupta

    2015-01-01

    Full Text Available Introduction: Back pain is a common clinical problem and is the frequent complaint for referral of lumbar spine magnetic resonance imaging (MRI. Coronal short tau inversion recovery sequence (STIR can provide diagnostically significant information in small percentage of patients. Materials and Methods: MRI examinations of a total of 350 patients were retrospectively included in the study. MR sequences were evaluated in two settings. One radiologist evaluated sagittal and axial images only, while another radiologist evaluated all sequences, including coronal STIR sequence. After recording the diagnoses, we compared the MRI findings in two subsets of patients to evaluate additional merit of coronal STIR imaging. Results: With addition of coronal STIR imaging, significant findings were observed in 24 subjects (6.8%. Twenty-one of these subjects were considered to be normal on other sequences and in three subjects diagnosis was changed with the addition of coronal STIR. Additional diagnoses on STIR included sacroiliitis, sacroiliac joint degenerative disease, sacral stress/insufficiency fracture/Looser′s zones, muscular sprain and atypical appendicitis. Conclusion: Coronal STIR imaging can provide additional diagnoses in a small percentage of patients presenting for lumbar spine MRI for back pain. Therefore, it should be included in the routine protocol for MR imaging of lumbar spine.

  3. Continuity theory

    Nel, Louis

    2016-01-01

    This book presents a detailed, self-contained theory of continuous mappings. It is mainly addressed to students who have already studied these mappings in the setting of metric spaces, as well as multidimensional differential calculus. The needed background facts about sets, metric spaces and linear algebra are developed in detail, so as to provide a seamless transition between students' previous studies and new material. In view of its many novel features, this book will be of interest also to mature readers who have studied continuous mappings from the subject's classical texts and wish to become acquainted with a new approach. The theory of continuous mappings serves as infrastructure for more specialized mathematical theories like differential equations, integral equations, operator theory, dynamical systems, global analysis, topological groups, topological rings and many more. In light of the centrality of the topic, a book of this kind fits a variety of applications, especially those that contribute to ...

  4. The influence of investigated factors on viscosity of stirred yogurt

    Denin-Đurđević Jelena D.

    2002-01-01

    Full Text Available Skim milk was reconstituted to obtain milk with 8.44% DM, which was standardized with demineralized whey powder (DWP to obtain milk sample A (9.71% DM and milk sample B (10.75% DM. Milk samples were heat treated at 85ºC/20 min and 90ºC/10 min, respectively. Untreated milk was used as control. Milk samples were inoculated with 2.5% of commercial yogurt culture (containing Lactobacillus delbrueckii subsp. bulgaricus and Streptococcus thermophilus in the ratio 1:1 at 43ºC. Samples were incubated until pH 4.6 was reached. Samples were immediately cooled to 4ºC and held at that temperature until analyses. Samples of acid casein gels were stirred after 1, 7 and 14 days of storage. Measurements of viscosity were done with Brookfield DV-E Viscometer. Spindle No 3 at 30 rpm was used for all samples. Duration of fermentation decreased when DWP was used for standardization of milk dry matter content. Yogurt samples produced from milk heat treated at 85ºC/20 min, obtained by stirring of gel 1 day after production had a higher viscosity than sample produced from milk heat treated at 90ºC/10 min. On the other hand, samples produced from milk heat treated at 90ºC/10 min had a greater viscosity after 7 and 14 days of storage, which indicates a greater hydrophilic properties and a more pronounced swelling of casein micelles.

  5. Versatile Friction Stir Welding/Friction Plug Welding System

    Carter, Robert

    2006-01-01

    A proposed system of tooling, machinery, and control equipment would be capable of performing any of several friction stir welding (FSW) and friction plug welding (FPW) operations. These operations would include the following: Basic FSW; FSW with automated manipulation of the length of the pin tool in real time [the so-called auto-adjustable pin-tool (APT) capability]; Self-reacting FSW (SRFSW); SR-FSW with APT capability and/or real-time adjustment of the distance between the front and back shoulders; and Friction plug welding (FPW) [more specifically, friction push plug welding] or friction pull plug welding (FPPW) to close out the keyhole of, or to repair, an FSW or SR-FSW weld. Prior FSW and FPW systems have been capable of performing one or two of these operations, but none has thus far been capable of performing all of them. The proposed system would include a common tool that would have APT capability for both basic FSW and SR-FSW. Such a tool was described in Tool for Two Types of Friction Stir Welding (MFS- 31647-1), NASA Tech Briefs, Vol. 30, No. 10 (October 2006), page 70. Going beyond what was reported in the cited previous article, the common tool could be used in conjunction with a plug welding head to perform FPW or FPPW. Alternatively, the plug welding head could be integrated, along with the common tool, into a FSW head that would be capable of all of the aforementioned FSW and FPW operations. Any FSW or FPW operation could be performed under any combination of position and/or force control.

  6. Ethylene oxidation in a well-stirred reactor

    Marinov, N.M. [Lawrence Livermore National Lab., CA (United States); Malte, P.C. [Washington Univ., Seattle, WA (United States). Dept. of Mechanical Engineering

    1994-10-01

    The detailed ethylene oxidation data set of Thornton, obtained for a well-stirred reactor operated fuel-lean at atmospheric pressure and for temperatures of 1003K to 1253K, is used as a basis for the comparison of chemical kinetic mechanisms reported in the literature and for the development of a new ethylene oxidation mechanism. The mechanisms examined are those of Westbrook and Pitz and Dagaut et al. These mechanisms indicated that unusually large rates for the vinyl decomposition reaction are required to obtain agreement with the Thornton data set. A new ethylene oxidation mechanism is developed in order to overcome some of the drawbacks of the previous mechanisms. The new mechanism closely simulates the overall rate of loss of ethylene, and the concentation of CO, CO{sub 2}, H{sub 2}, CH{sub 2}O, C{sub 2}H{sub 2}, CH{sub 3}OH, CH{sub 4}, and C{sub 2}H{sub 6} measured for the stirred reactor. Predictions by this mechanism are dependent on a new high temperature vinyl oxidation route, C{sub 2}H{sub 3} + O{sub 2} = CH{sub 2}CHO + O with a k{sub C2H3+O2=CH2CHO+O}/k{sub C2H3+O2=CH2O+HCO} branching ratio of 1.20 at 1053K to 2.05 at 1253K. The branching ratio values were dependent upon the extent of fall-off for the C{sub 2}H{sub 3} + O{sub 2} = CH{sub 2}O + HCO reaction.

  7. Ultrasonic-assisted friction stir welding on V95AT1 (7075) aluminum alloy

    Tarasov, S. Yu.; Rubtsov, V. Ye.; Kolubaev, E. A.; Ivanov, A. N.; Fortuna, S. V.; Eliseev, A. A.

    2015-10-01

    Ultrasonic-assisted friction stir butt welding on aluminum alloy V95AT1 (7075) has been carried out. Samples have been characterized using metallography, microhardness and XRD. As shown, ultrasonic treatment during welding provides extra plasticizing of metal and better stirring efficiency. The latter serves for elimination of defects, such as root flaw and grain refining in the stir zone. The stress state in the welded joint is characterized by tensile stress in the direction of the weld seam centerline and compression in the transversal direction. The ultrasonic treatment was shown to increase the compression stress and relieve the tensile one.

  8. Tensile strength on friction stir processed AMg5 (5083) aluminum alloy

    Chumaevsky, A. V.; Eliseev, A. A.; Filippov, A. V.; Rubtsov, V. E.; Tarasov, S. Yu.

    2016-11-01

    The results of the tensile tests carried out both on AMg5 (5083) aluminum alloy samples base and those obtained using friction stir processing technique are reported. The tensile test samples have been prepared from the friction stir processed plates so that their tensile axis was parallel to the processing direction. The maximum tensile strength of the processed samples was 9% higher than of the base metal. The fractographic examination shows the presence of flat areas inherent of the brittle fracture in all three friction processed samples. The load-extension curves show that friction stir processing may suppress the serrated yielding.

  9. Microstructure Evolution during Friction Stir Welding of Mill-Annealed Ti-6Al-4V (Preprint)

    2011-05-01

    AFRL-RX-WP-TP-2011-4300 MICROSTRUCTURE EVOLUTION DURING FRICTION STIR WELDING OF MILL-ANNEALED Ti-6Al-4V (Preprint) A.L. Pilchak...DURING FRICTION STIR WELDING OF MILL-ANNEALED Ti-6Al-4V (Preprint) 5a. CONTRACT NUMBER In-House 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER...Transactions A. Document contains color. 14. ABSTRACT In this study, mill-annealed Ti-6Al-4V plates were successfully friction stir welded over a

  10. Effect of cooling rate on microstructure of friction-stir welded AA1100 aluminum alloy

    Yi, D.; Mironov, S.; Sato, Y. S.; Kokawa, H.

    2016-06-01

    In this work, the microstructural changes occurring during cooling of friction-stir welded aluminum alloy AA1100 were evaluated. To this end, friction-stir welding (FSW) was performed in a wide range of cooling rates of 20-62 K/s and the evolved microstructures were studied by using electron backscatter diffraction. Below 0.6 Tm (Tm being the melting point), the stir zone material was found to experience no significant changes during cooling. At higher FSW temperatures, however, notable changes occurred in the welded material, including grain growth, sharpening of texture, reduction of the fraction of high-angle boundaries and material softening.

  11. Grain refinement of AZ31 magnesium alloy by electromagnetic stirring under effect of grain-refiner

    S Y Gao; Q C Le; Z Q Zhang; J Z Cui

    2012-08-01

    The effects of electromagnetic stirring and Al4C3 grain refiner on the grain refinement of semicontinuously cast AZ31 magnesium alloy were discussed in this investigation. The results indicate that electromagnetic stirring has an effective refining effect on the grain size of AZ31 magnesium alloy under the effect of Al4C3 grain refiner. Electromagnetic stirring can `activate’ the Al4C3 particles, resulting in more heterogeneous nucleation sites for the primary -Mg grains. But, longer holding time can `deactivate’ the Al4C3 particles and poison the grain refining effect.

  12. Analysis of Mixing Characteristics of Batch Stirred Vessels Using the Networks-of-Zones Model

    2002-01-01

    Batch stirred vessels, being devoid of through flow, cannot be assessed by the classical response technique. However, visible inert tracers can be readily observed in a batch or semi-batch stirred vessel. Visible images of the mixing and dispersion of the tracer present a picture in both space and time of the mixing process. Axi-symmetric networks of backmixed zones were used in an image reconstruction approach to analytically characterize the mixing. Computer generated images were compared with experimental results. The qualitative agreement between the observed and calculated images suggests that the analysis of batch stirred reactors can be used to guide operational strategies to control internal concentration fields.

  13. Effects of Fusion Tack Welds on Self-Reacting Friction Stir Welds

    Nunes, A. C., Jr.; Pendleton, M. L.; Brooke, S. A.; Russell, C. K.

    2012-01-01

    In order to know whether fusion tack welds would affect the strength of self-reacting friction stir seam welds in 2195-T87 aluminum alloy, the fracture stresses of 144 tensile test coupons cut from 24 welded panels containing segments of friction stir welds were measured. Each of the panels was welded under unique processing conditions. A measure of the effect of the tack welds for each panel was devised. An analysis of the measures of the tack weld effect supported the hypothesis that fusion tack welds do not affect the strength of self-reacting friction stir welds to a 5% level of confidence.

  14. Optimization of Friction Stir Welding Tool Advance Speed via Monte-Carlo Simulation of the Friction Stir Welding Process

    Kirk A. Fraser

    2014-04-01

    Full Text Available Recognition of the friction stir welding process is growing in the aeronautical and aero-space industries. To make the process more available to the structural fabrication industry (buildings and bridges, being able to model the process to determine the highest speed of advance possible that will not cause unwanted welding defects is desirable. A numerical solution to the transient two-dimensional heat diffusion equation for the friction stir welding process is presented. A non-linear heat generation term based on an arbitrary piecewise linear model of friction as a function of temperature is used. The solution is used to solve for the temperature distribution in the Al 6061-T6 work pieces. The finite difference solution of the non-linear problem is used to perform a Monte-Carlo simulation (MCS. A polynomial response surface (maximum welding temperature as a function of advancing and rotational speed is constructed from the MCS results. The response surface is used to determine the optimum tool speed of advance and rotational speed. The exterior penalty method is used to find the highest speed of advance and the associated rotational speed of the tool for the FSW process considered. We show that good agreement with experimental optimization work is possible with this simplified model. Using our approach an optimal weld pitch of 0.52 mm/rev is obtained for 3.18 mm thick AA6061-T6 plate. Our method provides an estimate of the optimal welding parameters in less than 30 min of calculation time.

  15. Comparison of a production process in a membrane-aerated stirred tank and up to 1000-L airlift bioreactors using BHK-21 cells and chemically defined protein-free medium.

    Hesse, Friedemann; Ebel, Maria; Konisch, Nadine; Sterlinski, Reinhard; Kessler, Wolfgang; Wagner, Roland

    2003-01-01

    The applicability of a protein-free medium for the production of recombinant human interleukin-2 with baby hamster kidney cells in airlift bioreactors was investigated. For this purpose, a BHK-21 cell line, adapted to grow and produce in protein-free SMIF7 medium without forming spheroids in membrane-aerated bubble-free bioreactors, was used as the producer cell line. First, cultivation of the cells was established at a 20-L scale using an internal loop airlift bioreactor system. During the culturing process the medium formulation was optimized according to the specific requirements associated with cultivation of mammalian cells under protein-free conditions in a bubble-aerated system. The effects of the addition of an antifoam agent on growth, viability, productivity, metabolic rates, and release of lactate dehydrogenase were investigated. Although it was possible to establish cultivation and production at a 20-L scale without the use of antifoaming substances, the addition of 0.002% silicon-oil-based antifoaming reagent improved the cultivation system by completely preventing foam formation. This reduced the release of lactate dehydrogenase activity to the level found in bubble-free aerated stirred tank membrane bioreactors and led to a reduction in generation doubling times by about 5 h (17%). Using the optimized medium formulation, cells were cultivated at a 1000-L scale, resulting in a culture performance comparable to the 20-L airlift bioreactor. For comparison, cultivations with protein-containing SMIF7 medium were carried out at 20- and 1000-L scales. The application of protein supplements did not lead to a significant improvement in the cultivation conditions. The results were also compared with experiments performed in a bubble-free aerated stirred tank membrane bioreactor to evaluate the influence of bubbles on the investigated culture parameters. The data implied a higher metabolic activity of the cells in airlift bioreactors with a 150% higher glucose

  16. Growth and biomass production with enhanced {beta}-glucan and dietary fibre contents of Ganoderma australe ATHUM 4345 in a batch-stirred tank bioreactor

    Papaspyridi, Lefki-Maria; Christakopoulos, Paul [BIOtechMASS Unit, Biotechnology Laboratory, School of Chemical Engineering, National Technical University of Athens, Athens (Greece); Katapodis, Petros [BIOtechMASS Unit, Biotechnology Laboratory, School of Chemical Engineering, National Technical University of Athens, Athens (Greece); Biotechnology Laboratory, Department of Biological Applications and Technologies, University of Ioannina, Ioannina (Greece); Gonou-Zagou, Zacharoula; Kapsanaki-Gotsi, Evangelia [Department of Ecology and Systematics, Faculty of Biology, National and Kapodistrian University of Athens, Athens (Greece)

    2011-02-15

    In this study we maximized biomass production by the basidiomycete Ganoderma australe ATHUM 4345, a species of pharmaceutical interest as it is a valuable source of nutraceuticals, including dietary fibers and glucans. We used the Biolog FF MicroPlate to screen 95 different carbon sources for growth monitoring. The pattern of substrate catabolism forms a substrate assimilation fingerprint, which is useful in selecting components for media optimization of maximum biomass production. Response surface methodology, based on the central composite design was applied to explore the optimum concentrations of carbon and nitrogen sources of culture medium in shake flask cultures. When the improved culture medium was tested in a 20-L stirred tank bioreactor, using 13.7 g/L glucose and 30.0 g/L yeast extract, high biomass yields (10.1{+-}0.4 g/L) and productivity of 0.09 g L{sup -1} h{sup -1} were obtained. The yield coefficients for total glucan and dietary fibers on biomass formed were 94.82{+-}6 and 341.15{+-}12.3 mg/g mycelium dry weight, respectively. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  17. Continuation calculus

    Bram Geron

    2013-09-01

    Full Text Available Programs with control are usually modeled using lambda calculus extended with control operators. Instead of modifying lambda calculus, we consider a different model of computation. We introduce continuation calculus, or CC, a deterministic model of computation that is evaluated using only head reduction, and argue that it is suitable for modeling programs with control. It is demonstrated how to define programs, specify them, and prove them correct. This is shown in detail by presenting in CC a list multiplication program that prematurely returns when it encounters a zero. The correctness proof includes termination of the program. In continuation calculus we can model both call-by-name and call-by-value. In addition, call-by-name functions can be applied to call-by-value results, and conversely.

  18. Fluid Flow Behavior of Liquid in Cylindrical Vessels Stirred by One or Two Air Jets

    2000-01-01

    Based on the two-phase model (Eulerian-Eulerian model), the three dimensional fluid flow in water and that liquid steel systems stirred by one or two multiple gas jets are simulated. In the Eulerian-Eulerian two-phase model, the gas and the liquid phase are considered to be two different continuous fluids interacting with each other through the finite inter-phase areas. The exchange between the phases is represented by source terms in conversation equations. Turbulence is assumed to be a property of the liquid phase. A new turbulence modification - model is introduced to consider the bubbles movement contribution to and . The dispersion of phases due to turbulence is represented by introducing a diffusion term in mass conservation equation. The mathematical simulation agrees well with the experiment results. The study results indicate that the distance of two nozzles has big effect on fluid flow behavior in the vessel. Using two gas injection nozzles at the half radii of one diameter of the bottom generates a much better mixing than with one nozzle under the condition of the same total gas flow rate.

  19. Experimental Characterisation and Modelling of Homogeneous Solid Suspension in an Industrial Stirred Tank

    Sébastien Calvo

    2013-01-01

    Full Text Available In this work, we study the conditions needed to reach homogeneous distribution of aluminium salts particles in water inside a torispherical bottom shaped stirred tank of 70 L equipped with a Pfaudler RCI type impeller and three equispaced vertical baffles. The aim of the present study is to develop a CFD model describing the quality of particle distribution in industrial scale tanks. This model, validated with experimental data, is used afterwards to develop scale-up and scale-down correlations to predict the minimum impeller speed needed to reach homogeneous solid distribution Nhs. The commercial CFD software Fluent 14 is used to model the fluid flow and the solid particle distribution in the tank. Sliding Mesh approach is used to take the impeller motion into account. Assuming that the discrete solid phase has no influence on the continuous liquid phase behaviour, the fluid flow dynamics is simulated independently using the well-known k-∊ turbulence model. The liquid-solid mixture behaviour is then described by implementing the Eulerian Mixture model. Computed liquid velocity fields are validated by comparison with PIV measurements. Computed Nhs were found to be in good agreement with experimental measurements. Results from different scales allowed correlating Nhs values to the volumetric power consumption.

  20. Simulated Service and Stress Corrosion Cracking Testing for Friction Stir Welded Spun Formed Domes

    Stewart, Thomas J.; Torres, Pablo D.; Caratus, Andrei A.; Curreri, Peter A.

    2010-01-01

    Simulated service testing (SST) development was required to help qualify a new 2195 aluminum lithium (Al-Li) alloy spin forming dome fabrication process for the National Aeronautics and Space Administration (NASA) Exploration Development Technology Program. The application for the technology is to produce high strength low weight tank components for NASA s next generation launch vehicles. Since plate material is not currently manufactured large enough to fabricate these domes, two plates are joined by means of friction stir welding. The plates are then pre-contour machined to near final thicknesses allowing for a thicker weld land and anticipating the level of stretch induced by the spin forming process. The welded plates are then placed in a spin forming tool and hot stretched using a trace method producing incremental contours. Finally the dome receives a room temperature contour stretch to final dimensions, heat treatment, quenching, and artificial aging to emulate a T-8 condition of temper. Stress corrosion cracking (SCC) tests were also performed by alternate immersion in a sodium chloride (NaCl) solution using the typical double beam assembly and with 4-point loaded specimens and use of bent-beam stress-corrosion test specimens under alternate immersion conditions. In addition, experiments were conducted to determine the threshold stress intensity factor for SCC (K(sub ISCC)) which to our knowledge has not been determined previously for Al-Li 2195 alloy. The successful simulated service and stress corrosion testing helped to provide confidence to continue to Ares 1 scale dome fabrication

  1. Liquation Cracking in Arc and Friction-Stir Welding of Mg-Zn Alloys

    Wagner, Dustin C.; Chai, Xiao; Tang, Xin; Kou, Sindo

    2015-01-01

    As compared to Al alloys, which are known to be susceptible to liquation ( i.e., liquid formation) and liquation-induced cracking, most Mg alloys have a lower eutectic temperature and thus are likely to be even more susceptible. The present study was conducted to study liquation and liquation cracking in Mg alloys during arc welding and friction-stir welding (FSW). Binary Mg-Zn alloys were selected as a model material in view of their very low eutectic temperature of 613 K (340 °C). Mg-Zn alloys with 2, 4, and 6 wt pct of Zn were cast and welded in the as-cast condition by both gas-tungsten arc welding (GTAW) and FSW. A simple test for liquation cracking was developed, which avoided interference by solidification cracking in the nearby fusion zone. Liquation and liquation cracking in GTAW were found to be in the decreasing order of Mg-6Zn, Mg-4Zn, and Mg-2Zn. Liquation cracking occurred in FSW of Mg-6Zn but not Mg-4Zn or Mg-2Zn. Instead of a continuous ribbon-like flash connected to the weld edge, small chips, and powder covered the weld surface of Mg-6Zn. The results from GTAW and FSW were discussed in light of the binary Mg-Zn phase diagram and the curves of temperature vs fraction solid during solidification.

  2. Full-Scale Continuous Mini-Reactor Setup for Heterogeneous Grignard Alkylation of a Pharmaceutical Intermediate

    Pedersen, Michael Jønch; Holm, Thomas; Rahbek, Jesper P.

    2013-01-01

    A reactor setup consisting of two reactors in series has been implemented for a full-scale, heterogeneous Grignard alkylation. Solutions pass from a small filter reactor into a static mixer reactor with multiple side entries, thus combining continuous stirred tank reactor (CSTR) and plug flow rea...

  3. Grain Size Control of Semisolid A356 Alloy Manufactured by Electromagnetic Stirring

    Z Yang; P.K. Seo; C.G.Kang

    2005-01-01

    To investigate the possibility of substituting the mechanical stirring system with electromagnetic stirring (EMS)system for aluminum rheo die-casting, the EMS under the different stirring cooling conditions was carried out. It was found that in the early period of solidification, the dendrite breakages led to a fine primary phase. When dendrites grew coarsely, the effect of ripening on grain size overwhelmed that of dendrite breakage. It was also found that the high cooling rate favored large nucleation rate, and led to a fine primary phase. But high cooling rate also made the growth rate of the dendrite arm, which prevented the dendrite arm from being sheared off. Therefore there were a suitable stirring time and suitable cooling rate to obtain the best rheo die-casting structure. Qualified semisolid A356aluminum alloy was successfully manufactured with short time EMS.

  4. The Analysis of a Vibrator Oil-stirring Phnomenon and Study on a New Structure

    HAN Bing-bing; ZHANG Gong-xue

    2012-01-01

    The deep vibrator is an important equipment of foundation improvement. It works through eccentric masses with high-speed. But the traditional eccentric structure will stir the oil around it, and it will result in the loss of motor power. The paper analyzed the stirring phenomenon, and got the level and specific data of stirring and swirling through fluent software. After principle analysis, a new type of anti-churning eccentric structure was put forward, which can effectively avoid stirring phenomenon. Otherwise, the new structure will also not produce irregular vibration because of swirling, then it can work with a better performance. In addition, the contrast of dynamic performance between a traditional and new structure was carried out in the paper and proved that the new structure has a better working performance. Modeling data in the paper is from surveying and mapping, so the conclusion can be taken as guidance for vibrator designing.

  5. Thermal Performance Evaluation of Friction Stir Welded and Bolted Cold Plates with Al/Cu Interface

    Lakshminarayanan, A. K.; Suresh, M.; Sibi Varshan, M.

    2015-05-01

    An attempt is made to design and fabricate a cold plate with aluminum-copper dissimilar interface joined by friction stir welding. Optimum welding conditions for obtaining sound-quality corner and T joints with an aluminum-copper interface were established. Welded cross sections of the friction stir welded cold plate were analyzed to understand the bonding characteristics. Computational fluid dynamics (CFD) was used to evaluate the fluid-flow characteristics and thermal resistance of friction stir welded cold plate and the resulted are compared with the conventional bolted cold plate configuration. For CFD modeling of a cold plate with a dissimilar interface, a new methodology is proposed. From the CFD analysis and experimental results, it is observed that friction stir welded cold plate offered better thermal performance compared to the bolted cold plate and it is due to the metallurgical bonding at the aluminum-copper interface with the dispersion of copper particles.

  6. Equipment for Solid State Stir Welding of High Temperature Materials Project

    National Aeronautics and Space Administration — Stir welding generates high-quality joints in fabricated structure and is the baseline joining process for most NASA aluminum alloy structures such as cryogenic...

  7. Nonlinear Time Reversal Acoustic Method of Friction Stir Weld Assessment Project

    National Aeronautics and Space Administration — The goal of the project is demonstration of the feasibility of Friction Stir Weld (FSW) assessment by novel Nonlinear Time Reversal Acoustic (TRA) method. Time...

  8. Thermal Stir Welding of High Strength and High Temperature Alloys for Aerospace Applications Project

    National Aeronautics and Space Administration — The Keystone and MSU team propose to demonstrate the feasibility of solid-state joining high strength and temperature alloys utilizing the Thermal Stir Welding...

  9. Improvement of lipase production at different stirring speeds and oxygen levels

    F.O.M. Alonso

    2005-03-01

    Full Text Available Lipase production by a Brazilian wild strain of Yarrowia lipolytica at different stirring speeds and air flow rates was studied. The relationship among lipid consumption, cell growth and lipase production by this microorganism is presented. The most pronounced effect of oxygen on lipase production was determined by stirring speed. Maximum lipase activity was detected in the late stationary phase at 200 rpm and an air flow rate of 1-2 dm³/min (0.8-1.7 vvm when the lipid source had been fully consumed. Higher stirring speeds resulted in mechanical and/or oxidative stress, while lower stirring speeds seemed to limit oxygen levels. An increase in the availability of oxygen at higher air flow rates led to faster lipid uptake and anticipation of enzyme release into the culture medium. The highest lipase production was obtained at 200 rpm and 1 dm³/min (0.8 vvm.

  10. Counterrotating-Shoulder Mechanism for Friction Stir Welding

    Nunes, Arthur C., Jr.

    2007-01-01

    A counterrotating-shoulder mechanism has been proposed as an alternative to the mechanism and fixtures used in conventional friction stir welding. The mechanism would internally react most or all of the forces and torques exerted on the workpiece, making it unnecessary to react the forces and torques through massive external fixtures. In conventional friction stir welding, a rotating pin tool is inserted into, and moved along, a weld seam. As the pin tool moves, it stirs together material from the opposite sides of the seam to form the weld. A large axial plunge force must be exerted upon the workpiece through and by the pin tool and a shoulder attached above the pin tool in order to maintain the pressure necessary for the process. The workpiece is secured on top of an anvil, which supports the workpiece against the axial plunge force and against the torque exerted by the pin tool and shoulder. The anvil and associated fixtures must be made heavy (and, therefore, are expensive) to keep the workpiece stationary. In addition, workpiece geometries must be limited to those that can be accommodated by the fixtures. The predecessor of the proposed counterrotating-shoulder mechanism is a second-generation, self-reacting tool, resembling a bobbin, that makes it possible to dispense with the heavy anvil. This tool consists essentially of a rotating pin tool with opposing shoulders. Although the opposing shoulders maintain the necessary pressure without need to externally apply or react a large plunge force, the torque exerted on the workpiece remains unreacted in the absence of a substantial external fixture. Depending on the RPM and the thickness of the workpiece, the torque can be large. The proposed mechanism (see figure) would include a spindle attached to a pin tool with a lower shoulder. The spindle would be coupled via splines to the upper one of three bevel gears in a differential drive. The middle bevel gear would be the power-input gear and would be coupled to the

  11. A review of using computational fluid dynamic in simulating of friction stir welding and parametric studies

    Hamza, Esam

    2016-01-01

    Friction Stir Welding (FSW) is still gradually evolving where it is newer than most thermomechanical processes and due to its ability to avoid many of the common defects in other welding techniques it has become largely used, particularly for those materials that are soft.[1]\\ud Since the invention of friction stir welding by The Welding Institute (TWI), Cambridge, UK, there have been many attempts to comprehend the physical phenomena that take place during this process. These phenomena can b...

  12. STUDY ON THE TEXTURE OF A FRICTION STIR WELDED Mg-Al-Ca ALLOY

    D.T. Zhang; M. Suzuki; K. Maruyama

    2006-01-01

    Macro-texture of an Mg-Al-Ca alloy prepared by friction stir welding (FSW) was investigated through pole figure measurement and X-ray diffraction (XRD) pattern analysis. It was found that at the top and bottom surfaces of friction stir zone (FSZ), (0002) basal planes of magnesium tend to be arranged parallel to the plate surface. In the cross section of FSZ, no obvious texture had evolved and (0002) basal planes showed a random distribution.

  13. Fluid Dynamic Analysis of Shaken and Mechanically Stirred Reactors by Means of Optical Techniques

    Pieralisi, Irene

    2016-01-01

    This research aims at deepening the knowledge of the hydrodynamics developing within some specific mixing system configurations. In particular, a standard geometry stirred vessel, an unbaffled stirred vessel of unconventional geometry and a shaken bioreactor are studied. Optical techniques (LDA, PIV) are employed in order to obtain detailed information on the mean and turbulent characteristics of the flow developing within the different lab-scale reactors, while subsequent data analysis a...

  14. Composite Aluminum-Copper Sheet Material by Friction Stir Welding and Cold Rolling

    Kahl, S; Osikowicz, W

    2013-01-01

    An aluminum alloy and a pure copper material were butt-joined by friction stir welding and subsequently cold rolled. The cold-rolling operation proved to be very advantageous because small voids present after friction stir welding were closed, the interface area per material thickness was enlarged, a thin intermetallic layer was partitioned, and the joint was strengthened by strain hardening. Tensile test specimens fractured in the heat-affected zone in the aluminum material; tensile strength...

  15. Numerical Simulations of Inclusion Behavior in Gas-Stirred Ladles

    Lou, Wentao; Zhu, Miaoyong

    2013-06-01

    A computation fluid dynamics-population balance model (CFD-PBM) coupled model has been proposed to investigate the bubbly plume flow and inclusion behavior including growth, size distribution, and removal in gas-stirred ladles, and some new and important phenomena and mechanisms were presented. For the bubbly plume flow, a modified k- ɛ model with extra source terms to account for the bubble-induced turbulence was adopted to model the turbulence, and the bubble turbulent dispersion force was taken into account to predict gas volume fraction distribution in the turbulent gas-stirred system. For inclusion behavior, the phenomena of inclusions turbulent random motion, bubbles wake, and slag eye forming on the molten steel surface were considered. In addition, the multiple mechanisms both that promote inclusion growth due to inclusion-inclusion collision caused by turbulent random motion, shear rate in turbulent eddy, and difference inclusion Stokes velocities, and the mechanisms that promote inclusion removal due to bubble-inclusion turbulence random collision, bubble-inclusion turbulent shear collision, bubble-inclusion buoyancy collision, inclusion own floatation near slag-metal interface, bubble wake capture, and wall adhesion were investigated. The importance of different mechanisms and total inclusion removal ratio under different conditions, and the distribution of inclusion number densities in ladle, were discussed and clarified. The results show that at a low gas flow rate, the inclusion growth is mainly attributed to both turbulent shear collision and Stokes collision, which is notably affected by the Stokes collision efficiency, and the inclusion removal is mainly attributed to the bubble-inclusion buoyancy collision and inclusion own floatation near slag-metal interface. At a higher gas flow rate, the inclusions appear as turbulence random motion in bubbly plume zone, and both the inclusion-inclusion and inclusion-bubble turbulent random collisions become

  16. Marine ecosystem dynamics, ocean circulation and horizontal stirring

    Rossi, V.; Tewkai, E.; López, C.; Sudre, J.; Hernández-García, E.; Garcon, V.

    2009-04-01

    The oceanic submeso and mesoscale circulation and its eddies, filaments, meanders play a major role in marine ecosystems dynamics from the lower trophic levels to the marine top predators. We study here the interplay between turbulence in fluid dynamics on these scales and biological activity at different trophic levels using two cases study. The first example focuses on the four eastern boundary upwelling zones, the Canary, Benguela, California and Humboldt upwelling systems which constitute the largest contribution to the world ocean productivity. These areas are spatially heterogeneous, populated with a large variety of mesoscale and sub-mesoscale structures such as filaments, plumes and eddies, which control exchange processes between the shelf and open ocean and play a major role in modulating the biomass, rates and structure of marine ecosystems. We will present here results from a lagrangian approach based on Finite Size Lyapunov Exponents (FSLE) using altimetric and scatterometric data to estimate the spatial and temporal variations in the lateral stirring and mixing of tracers in the upper ocean within the four areas. When investigating links with chlorophyll a concentration as a proxy for biological activity in these upwelling systems, results show that surface horizontal stirring and mixing vary inversely with chlorophyll standing stocks. FSLEs lead to a clear clustering of the systems suggesting that one may use them as integrated and comparative indices for characterizing horizontal dynamical features in all eastern boundary upwellings. Then we investigate the role of submesoscale structures in the Mozambique Channel on the distribution of a top marine predator, the Great Frigatebird. Using similar dynamical concept, the FSLE, we have identified Lagrangian Coherent Structures (LCSs) present in the surface flow in the Channel. By comparing seabirds' satellite positions with LCSs locations, we demonstrate that frigatebirds track precisely these

  17. Friction stir welding of F82H steel for fusion applications

    Noh, Sanghoon; Ando, Masami; Tanigawa, Hiroyasu; Fujii, Hidetoshi; Kimura, Akihiko

    2016-09-01

    In the present study, friction stir welding was employed to join F82H steels and develop a potential joining technique for a reduced activation ferritic/martensitic steel. The microstructures and mechanical properties on the joint region were investigated to evaluate the applicability of friction stir welding. F82H steel sheets were successfully butt-joined with various welding parameters. In welding conditions, 100 rpm and 100 mm/min, the stirred zone represented a comparable hardness distribution with a base metal. Stirred zone induced by 100 rpm reserved uniformly distributed precipitates and very fine ferritic grains, whereas the base metal showed a typical tempered martensite with precipitates on the prior austenite grain boundary and lath boundary. Although the tensile strength was decreased at 550 °C, the stirred zone treated at 100 rpm showed comparable tensile behavior with base metal up to 500 °C. Therefore, friction stir welding is considered a potential welding method to preserve the precipitates of F82H steel.

  18. The erosion performance of cold spray deposited metal matrix composite coatings with subsequent friction stir processing

    Peat, Tom; Galloway, Alexander; Toumpis, Athanasios; McNutt, Philip; Iqbal, Naveed

    2017-02-01

    This study forms an initial investigation into the development of SprayStir, an innovative processing technique for generating erosion resistant surface layers on a chosen substrate material. Tungsten carbide - cobalt chromium, chromium carbide - nickel chromium and aluminium oxide coatings were successfully cold spray deposited on AA5083 grade aluminium. In order to improve the deposition efficiency of the cold spray process, coatings were co-deposited with powdered AA5083 using a twin powder feed system that resulted in thick (>300 μm) composite coatings. The deposited coatings were subsequently friction stir processed to embed the particles in the substrate in order to generate a metal matrix composite (MMC) surface layer. The primary aim of this investigation was to examine the erosion performance of the SprayStirred surfaces and demonstrate the benefits of this novel process as a surface engineering technique. Volumetric analysis of the SprayStirred surfaces highlighted a drop of approx. 40% in the level of material loss when compared with the cold spray deposited coating prior to friction stir processing. Micro-hardness testing revealed that in the case of WC-CoCr reinforced coating, the hardness of the SprayStirred material exhibits an increase of approx. 540% over the unaltered substrate and 120% over the as-deposited composite coating. Microstructural examination demonstrated that the increase in the hardness of the MMC aligns with the improved dispersion of reinforcing particles throughout the aluminium matrix.

  19. Hybrid manufacturing processes for fusion welding and friction stir welding of aerospace grade aluminum alloys

    Gegesky, Megan Alexandra

    Friction stir welding and processing can provide for joints in aerospace grade aluminum alloys that have preferable material properties as compared to fusion welding techniques. Aerospace grade aluminum alloys such as AA2024-T3 and AA7075-T6 are considered non-weldable by traditional fusion welding techniques. Improved mechanical properties over previously used techniques are usually preferable for aerospace applications. Therefore, by combining traditional fusion welding and friction stir processing techniques, it could be plausible to create more difficult geometries in manufactured parts instead of using traditional techniques. While this combination of fusion welding and friction stir processing is not a new technology, its introduction to aerospace grade aluminum alloys as well as non-weldable alloys, is new. This is brought about by a lowered required clamping force required by adding a fusion weld before a friction stir processing technique. The changes in properties associated with joining techniques include: microstructural changes, changes in hardness, tensile strength, and corrosion resistance. This thesis illustrates these changes for the non-weldable AA2024-T351 and AA7075-T651 as well as the weldable alloy AA5052-H32. The microhardness, tensile strength and corrosion resistance of the four processing states: base material, fusion welded material, friction stir welded material, and friction stir processed fusion welded material is studied. The plausibility of this hybrid process for the three different materials is characterized, as well as plausible applications for this joining technique.

  20. Experimental Study on Aqueous Phase Entrainment in a Mixer-settler with Double Stirring Mode

    Wang Shuchan; Zhang Tingan; Zhao Qiuyue; Liu Yan; Wu Qiuyang

    2013-01-01

    The mixer-settler is a core device of solvent extraction for separating rare earth elements. There are some adverse effects like high rare earth accumulation and poor production efifciency during industrial production. Current researches usually focus on changing the structure of the mixer-settler without making a breakthrough towards gravity clariifcation. In this paper, in order to improve the efifciency of clariifcation, a mixer-settler with double stirring mode was designed and manufactured by adding a stirring device in the settler after reducing the volume of the settler. The innovation of this research involves adopting the ultraviolet-visible spectrophotometer to investigate the quantity of aqueous phase entrainment at the settler outlet in order to measure the clariifcation degree. Experimental results show that the clariifcation effect with stirring is better than that without stirring. The clariifcation effect is ameliorated as the stirring speed increases. Generally, the clariifcation effect shows a best condition when the offset distance is 12.5 cm, making the phase entrainment reduced to less than 0.1%. When the clearance over the tank bottom is 7 cm and 10 cm, respectively, the quantity of aqueous phase entrainment is better than the case with a clearance of 4 cm. The results show that the stirring paddle close to the mixed phase zone can better promote the two-phase separation.

  1. Microstructural formation of semi-solid AZ91D alloy stirred by electromagnetic field

    2005-01-01

    With the help of an electromagnetic stirring device, alloy melt quenching and EBSD (electron back scatter diffraction)analysis technology, the microstructure of the semi-solid AZ91D magnesium alloy slurry stirred by rotational electromagnetic field under different stirring power conditions has been studied. The results show that the size of primary α-Mg phase is reduced obviously when the solidifying alloy melt is stirred by rotational electromagnetic field, moreover, the primary α-Mg grains are changed to fine rosette grains or spherical grains which are proved to belong to the different grains in three-dimension by the EBSD analysis technology. The results also show that the stirring power is an important processing parameter in the preparation of the semi-solid AZ91D magnesium alloy slurry. The larger the stirring power, the finer the primary α-Mg grains, the less the rosette primary α-Mg grains, and the more the spherical primary α-Mg grains. Theoretical analysis indicates that a stronger flow motion leads to a more even temperature field and solute field and a stronger man-made temperature fluctuation in the alloy melt so that the specially fine rosette and/or spherical primary α-Mg grains are formed in the semi-solid AZ91D magnesium alloy slurry.

  2. Continuous fermentative hydrogen production in different process conditions

    Nasirian, N. [Islamic Azad Univ., Shoushtar (Iran, Islamic Republic of). Dept. of Agricultural Mechanization; Almassi, M.; Minaee, S. [Islamic Azad Univ., Tehran (Iran, Islamic Republic of). Dept. of Agricultural Mechanization; Widmann, R. [Duisburg-Essen Univ., Essen (Germany). Dept. of Environmental Engineering, Waste and Water

    2010-07-01

    This paper reported on a study in which hydrogen was produced by fermentation of biomass. A continuous process using a non-sterile substrate with a readily available mixed microflora was used on heat treated digested sewage sludge from a wastewater treatment plant. Hydrogen was produced from waste sugar at a pH of 5.2 and a temperature of 37 degrees C. An experimental setup of three 5.5 L working volume continuously stirred tank reactors (CSTR) in different stirring speeds were constructed and operated at 7 different hydraulic retention times (HRTs) and different organic loading rates (OLR). Dissolved organic carbon was examined. The results showed that the stirring speed of 135 rpm had a beneficial effect on hydrogen fermentation. The best performance was obtained in 135 rpm and 8 h of HRT. The amount of gas varied with different OLRs, but could be stabilized on a high level. Methane was not detected when the HRT was less than 16 h. The study identified the reactor in which the highest specific rate of hydrogen production occurred.

  3. Continuous ethanol production under acidic conditions

    1983-09-06

    Gelatinized starch is treated with saccharifying enzymes and immobilized EtOH-producing microorganisms (e.g., Saccharomyces, Candida, Zymomonas) at pH less than or equal to 3.4 to produce EtOH continuously. At this pH, no contamination occurs. Thus, a 25% slurry of cassava powder was heated at 120/sup 0/ for 20 min and mixed with ..cap alpha..-amylase 0.6 and CaCl/sub 2/ 2 g/l. The mixture was stirred at 90/sup 0/ for 30 min, cooled to room temperature, filtered, and the filtrate mixed with 1 g (NH/sub 4/)/sub 2/SO/sub 4/ and adjusted to pH 2.8. A mixture of wine and bakers' yeast (500 g) immobilized on alginate was continuously contacted with the saccharified starch solution to yield 77-90 g EtOH/l.

  4. A study of the friction stir welding process by experimental investigation and numerical simulation

    Long, Tianzhong

    2005-12-01

    In this study, 2-D and 3-D models based on a commercial computational fluid dynamics (CFD) code (FLUENT) and suitable user defined viscosity law are used to capture many of the trends observed in FSW. The fully thermo-mechanically coupled 2 D CFD model can run in a few hours on a PC based system. The low computational cost for 2-D model enables rapid assessment of the effects of various material properties and the criticality of inclusion or exclusion of some property details. The effects of varying material properties and process parameters, on the trends in x-axis forces and potential weld defect formation (via material flow pattern) are studied and compared with the experimental observations. It was found that the minimum x-force that occurs in the median RPM range is strongly influenced by the cutoff temperature in the viscosity law. The bifurcation of material flow in the weld path also occurs when the maximum temperature ahead of the pin surpasses the cutoff temperature. Aluminum alloys AA2219, AA5083, AA6061, and AA7050 were welded using constant welding speed and linearly increased RPM. The grain sizes in the welds were measured and the applied torque and x-force during friction stir welding process were recorded. The correlations of the grain size, the applied torque and x-force were studied using simulation and the experimental methods. The 2D and 3D CFD model simulation results compare well with experimental measurements. Based on the 2D model results, the material's simulated thermo-mechanical history was also studied. The model predicts that the material in the weld region experiences a high temperature after the deformation is complete. This thermo-mechanical history indicates that metallurgical transformations may continue after the end of deformation and that the grain size in the weld cannot be adequately described using a Zener-Holloman parameter approach or by invoking the continuous dynamic recrystallization process.

  5. Extended Beta Regression in R: Shaken, Stirred, Mixed, and Partitioned

    Bettina Grün

    2012-05-01

    Full Text Available Beta regression – an increasingly popular approach for modeling rates and proportions – is extended in various directions: (a bias correction/reduction of the maximum likelihood estimator, (b beta regression tree models by means of recursive partitioning, (c latent class beta regression by means of finite mixture models. All three extensions may be of importance for enhancing the beta regression toolbox in practice to provide more reliable inference and capture both observed and unobserved/latent heterogeneity in the data. Using the analogy of Smithson and Verkuilen (2006, these extensions make beta regression not only “a better lemon squeezer” (compared to classical least squares regression but a full-fledged modern juicer offering lemon-based drinks: shaken and stirred (bias correction and reduction, mixed (finite mixture model, or partitioned (tree model. All three extensions are provided in the R package betareg (at least 2.4-0, building on generic algorithms and implementations for bias correction/reduction, model-based recursive partioning, and finite mixture models, respectively. Specifically, the new functions betatree( and betamix( reuse the object-oriented flexible implementation from the R packages party and flexmix, respectively.

  6. Threshold for creating excitations in a stirred superfluid ring

    Wright, K. C.; Blakestad, R. B.; Lobb, C. J.; Phillips, W. D.; Campbell, G. K.

    2013-12-01

    We have measured the threshold for creating long-lived excitations when a toroidal Bose-Einstein condensate is stirred by a rotating (optical) barrier of variable height. When the barrier height is on the order of or greater than half of the chemical potential, the critical barrier velocity at which we observe a change in the circulation state is much less than the speed for sound to propagate around the ring. In this regime we primarily observe discrete jumps (phase slips) from the noncirculating initial state to a simple, well-defined, persistent current state. For lower barrier heights, the critical barrier velocity at which we observe a change in the circulation state is higher, and approaches the effective sound speed for vanishing barrier height. The response of the condensate in this small-barrier regime is more complex, with vortex cores appearing in the bulk of the condensate. We find that the variation of the excitation threshold with barrier height is in qualitative agreement with the predictions of an effective one-dimensional hydrodynamic model.

  7. A coupled thermo-mechanical model of friction stir welding

    Veljić Darko M.

    2012-01-01

    Full Text Available A coupled thermo-mechanical model was developed to study the temperature fields, the plunge force and the plastic deformations of Al alloy 2024-T351 under different rotating speed: 350, 400 and 450 rpm, during the friction stir welding (FSW process. Three-dimensional FE model has been developed in ABAQUS/Explicit using the arbitrary Lagrangian-Eulerian formulation, the Johnson-Cook material law and the Coulomb’s Law of friction. Numerical results indicate that the maximum temperature in the FSW process is lower than the melting point of the welding material. The temperature filed is approximately symmetrical along the welding line. A lower plastic strain region can be found near the welding tool in the trailing side on the bottom surface. With increasing rotation speed, the low plastic strain region is reduced. When the rotational speed is increased, the plunge force can be reduced. Regions with high equivalent plastic strains are observed which correspond to the nugget and the flow arm.

  8. Manual adjustable probe tool for friction stir welding

    Oelgoetz, Peter A. (Inventor); Ding, Jeff (Inventor)

    2000-01-01

    A friction stir welding tool is provided generally comprising three parts: a rotatable welding tool body (22) that has an outer threaded surface (32) and a probe (24) extending from a distal end of the body, a shoulder (26), which has a threaded inner surface (40) and a bore (36) at a distal end of the shoulder, and a jam nut (28), which has a threaded inner surface (42). The shoulder is threaded onto the tool body such that the probe extends from the shoulder through the bore by a preferred length. The jam nut is then threaded onto the tool body to secure the shoulder. The tool is operatively connected to a drive motor for rotating the tool body. The shoulder may include a knife edge projecting from the distal end (38) thereof adjacent the bore. The knife edge inhibits the weld material from migrating along the probe to intrude inside the shoulder, where it may prevent separation of the tool body and the shoulder when readjustment of the tool is necessary.

  9. EFFECT OF THICKENERS ON THE TEXTURE OF STIRRED YOGURT

    D. GONÇALVEZ

    2009-03-01

    Full Text Available

    The effect of the addition of gelatin and starch on the rheological properties of sweetened plain stirred yogurt was studied by manufacturing six samples: two with gelatin (3000 and 6000 ppm, three with starch (1000, 5000, 10000 ppm and a sample without thickener (control. Rheological characterization of the samples was performed using a coaxial cylinder Haake VT500 viscometer. Yield stress ( and hysteresis were also determined. Syneresis (% was measured by centrifugation at 1100 rpm for 10 minutes. Sensory characterization was performed with a panel of trained sensory assessors, who evaluated the following texture attributes: viscosity, ropiness, creaminess and mouthfeel. All samples showed thixotropic and pseudoplastic behaviour. Since the upward curve did not fit a unique model, it was divided in two regions. The first one fitted Herschel-Bulkley’s model. The addition of gelatine decreased flow behaviour index (n, whereas yield stress significantly increased with the addition of both thickeners. Gelatine was more efficient in reducing syneresis than starch. The addition of thickeners significantly increased all the studied sensory texture attributes. Non-oral and oral parameters were highly correlated witch each other and witch rheological parameters. KEYWORDS: Yogurt; texture; thickeners.

  10. Heat generation during plunge stage in friction stir welding

    Veljić Darko M.

    2013-01-01

    Full Text Available This paper deals with the heat generation in the Al alloy Al2024-T3 plate under different rotating speeds and plunge speeds during the plunge stage of friction stir welding (FSW. A three-dimensional finite element model (FEM is developed in the commercial code ABAQUS/Explicit using the arbitrary Lagrangian-Eulerian formulation, the Johnson-Cook material law and Coulomb’s Law of friction. The heat generation in FSW can be divided into two parts: frictional heat generated by the tool and heat generated by material deformation near the pin and the tool shoulder region. Numerical results obtained in this work indicate a more prominent influence from the friction-generated heat. The slip rate of the tool relative to the workpiece material is related to this portion of heat. The material velocity, on the other hand, is related to the heat generated by plastic deformation. Increasing the plunging speed of the tool decreases the friction-generated heat and increases the amount of deformation-generated heat, while increasing the tool rotating speed has the opposite influence on both heat portions. Numerical results are compared with the experimental ones, in order to validate the numerical model, and a good agreement is obtained.

  11. Stirred batch crystallization of a therapeutic antibody fragment.

    Hebel, Dirk; Huber, Sabine; Stanislawski, Bernd; Hekmat, Dariusch

    2013-07-20

    Technical-scale crystallization of therapeutic proteins may not only allow for a significant cost-reduction in downstream processing, but also enable new applications, e.g., the use of crystal suspensions for subcutaneous drug delivery. In this work, the crystallization of the antigen-binding fragment FabC225 was studied. First, vapor diffusion crystallization conditions from the literature were transferred to 10μL-scale microbatch experiments. A phase diagram was developed in order to identify the crystallization window. The conditions obtained from the microbatch experiments were subsequently transferred to parallelized 5mL-scale stirred-tank crystallizers. This scalable and reproducible agitated crystallization system allowed for an optimization of the crystallization process based on quantitative measurements. The optimized crystallization process resulted in an excellent yield of 99% in less than 2h by increasing the concentration of the crystallization agent ammonium sulfate during the process. The successful scalability of the Fab fragment crystallization process to 100mL-scale crystallizers based on geometric similarity was demonstrated. A favorable crystal size distribution was obtained. Furthermore, a wash step was introduced in order to remove unfavorable low-molecular substances from the crystals.

  12. MOTIONS OF ALLOYING ADDITIONS IN GAS STIRRED LADLES

    S.C. Fan,; B.K. Li; J.C. He

    2001-01-01

    A mathematical model has been developed to analyze the flow patterns and subsurface trajectories of spherical shaped particles (alloy additions) in gas stirring ladles. First,a numerical method to solve fluid flow problems in conjunction with a curvilinear coordinate system is proposed. The internal boundary in flow field, which must be designated in the cylindrical polar coordinate system, can be avoided by using bodyfitted coordinate system (BFC). Consequently, computed flow of molten steel and paths of alloying additions are able to cross smoothly the geometric centerline of cylindrical vessel. Second, motion of particles is calculated in the three-dimensional coordinate system, the modification of parameters, such as the drag coefficient and density in the gas plume region, is examined. When the density of sphere is closer and closer to that of fluid, the path of motion is longer and longer. If the plug is moved off-centered to the half of radius, the path of sphere is prolonged, and the sphere may go through the geometric centerline of vessel, reach the deeper region. The immersed depths increase with increasing entry velocities.``

  13. Process Optimization for Friction-Stir-Welded Martensitic Steel

    Ghosh, M.; Kumar, K.; Mishra, R. S.

    2012-06-01

    Advanced high-strength M190 steel sheets were joined by friction-stir welding under different tool rotational and traversing speeds. The optical microstructure of the joints exhibited complete martensite and partial martensite at the weld nugget depending on the cooling rate during welding. The first heat-affected zone outside of the weld nugget revealed ferrite-pearlite phase aggregate, and the second heat-affected zone showed a tempered martensitic structure. The interplay of process variables in terms of peak temperature and cooling rate was studied to observe their effect on joint efficiency under shear testing. The peak hardness at weld nugget was close to the parent alloy at an intermediate cooling rate of 294 to 313 K/s. The lowest hardness was observed at the first heat-affected zone for all welded joints. Joint efficiency was dependent on relative quantity of ferrite-pearlite at first heat-affected zone. In that respect, the intermediate temperature to the tune of ~1193 K to 1273 K (~920 °C to 1000 °C) at the weld nugget was found to be beneficial for obtaining an adequate quantity of pearlite at the first heat-affected zone to provide joint efficiency of more than 50 pct of that of parent alloy.

  14. Changes of Resistance During Polyelectrolyte-enhanced Stirred Batch Ultrafiltration

    ZHU Xin-Sheng; Kwang-Ho CHOO

    2007-01-01

    The permeation flux or the resistance in the ultrafiltration process is mainly limited by osmotic pressure,and it may originate from various kinds of polymer interactions. However, the real origin of permeation resistance hasn't been clarified yet in the light of polymer solution nature. The removal of nitrate contamination by polyelectrolytes was carried out with stirred batch ultrafiltration. The polyelectrolyte concentrations both in permeate and retentate were analyzed with total organic carbon analyzer and permeate mass was acquired by electronic balance connected with computer. The total resistance was calculated and interpreted based on the osmotic pressures in three concentration regimes. In the dilute region, the resistance was proportional to polymer concentration; in the semidilute region, the resistance depended on polymer concentration in the parabolic relationship; in the highly concentrated solution regime, the osmotic pressure factor (OPF) would dominate the total resistance; and the deviation from OPF control could come from the electrostatic repulsion between the tightly compacted and charged polyelectrolyte particles at extremely concentrated solution regime. It was first found that dilute and semidilute concentration regions can be easily detected by plotting the log-log curves of the polymer concentration versus the ratio of the total resistance to polymer concentration. The new concept OPF was defined and did work well at highly concentrated regime.

  15. Design of Friction Stir Welding Tool for Avoiding Root Flaws

    Shude Ji

    2013-12-01

    Full Text Available In order to improve material flow behavior during friction stir welding and avoid root flaws of weld, a tool with a half-screw pin and a tool with a tapered-flute pin are suggested. The effect of flute geometry in tool pins on material flow velocity is investigated by the software ANSYS FLUENT. Numerical simulation results show that high material flow velocity appears near the rotational tool and material flow velocity rapidly decreases with the increase of distance away from the axis of the tool. Maximum material flow velocity by the tool with the tapered-flute pin appears at the beginning position of flute and the velocity decreases with the increase of flow length in flute. From the view of increasing the flow velocity of material near the bottom of the workpiece or in the middle of workpiece, the tool with the half-screw pin and the tool with the tapered-flute pin are both better than the conventional tool.

  16. Continuous Low Cost Transesterification Process for the Production of Coconut Biodiesel

    Chandra P. Singh

    2010-01-01

    Full Text Available Biodiesel, or alkyl ester, is an alternative renewable, biodegradable, and non-toxic diesel fuel produced by the catalytic transesterification of vegetable oil. Here we characterize a system for continuous transesterification of vegetable oil using five continuous stirring tank reactors (5CSTRs. We tested residence times of 16–43min, stirring speeds of 200–800rpm, a catalyst concentration (KOH of 0.25–1 wt% of oil (in gram, different total flow rates of the oil and MeOH, and on the production performance of the 5 stage continuous reactor for transesterification of vegetable oil. Using a molar ratio of oil:methanol of 1:7 and a reaction temperature of 65 °C, we show that a high stirring speed increased the reaction rate, but an excessive stir speed decreased the reaction rate and conversion to biodiesel. Furthermore, a higher catalyst percentage significantly increased the reaction rate and production capacity. A catalyst percentage of 1 wt% of oil gave the best conversion; 99.04 ± 0.05%. The resulting biodiesel esters were characterized for their physical and fuel properties including density, viscosity, iodine volume, acid volume, cloud point, pure point, gross heat of combustion, and volatility. The purity and conversion of the biodiesel was analyzed by HPLC.

  17. Continuous Cultivation of Photosynthetic Bacteria for Fatty Acids Production

    Kim, Dong-Hoon; Lee, Ji-Hye; Hwang, Yuhoon; Kang, Seoktae; Kim, Mi-Sun

    2013-01-01

    In the present work, we introduced a novel approach for microbial fatty acids (FA) production. Photosynthetic bacteria, Rhodobacter sphaeroides KD131, were cultivated in a continuous-flow, stirred-tank reactor (CFSTR) at various substrate (lactate) concentrations.At hydraulic retention time (HRT) 4 d, cell concentration continuously increased from 0.97 g dcw/L to 2.05 g dcw/L as lactate concentration increased from 30 mM to 60 mM. At 70 mM, however, cell concentration fluctuated with incomple...

  18. Modifications in the AA5083 Johnson-Cook Material Model for Use in Friction Stir Welding Computational Analyses

    2011-12-30

    REPORT Modifications in the AA5083 Johnson-Cook Material Model for Use in Friction Stir Welding Computational Analyses 14. ABSTRACT 16. SECURITY...TERMS AA5083, friction stir welding , Johnson-Cook material model M. Grujicic, B. Pandurangan, C.-F. Yen, B. A. Cheeseman Clemson University Office of...Use in Friction Stir Welding Computational Analyses Report Title ABSTRACT Johnson-Cook strength material model is frequently used in finite-element

  19. Characterization of Residual Stress as a Function of Friction Stir Welding Parameters in ODS Steel MA956

    2013-06-01

    OF RESIDUAL STRESS AS A FUNCTION OF FRICTION STIR WELDING PARAMETERS IN ODS STEEL MA956 by Martin S. Bennett June 2013 Thesis Advisor...characterizes the residual stresses generated by friction stir welding of ODS steel MA956 as a function of heat index. The heat index of a weld is used to...determine relative heat input among different friction stir welding conditions. It depends on a combination of the rotational speed and traverse, or

  20. Stir Friction Welding Used in Ares I Upper Stage Fabrication

    2007-01-01

    Under the goals of the Vision for Space Exploration, Ares I is a chief component of the cost-effective space transportation infrastructure being developed by NASA's Constellation Program. This transportation system will safely and reliably carry human explorers back to the moon, and then onward to Mars and other destinations in the solar system. The Ares I effort includes multiple project element teams at NASA centers and contract organizations around the nation, and is managed by the Exploration Launch Projects Office at NASA's Marshall Space Flight Center (MFSC). ATK Launch Systems near Brigham City, Utah, is the prime contractor for the first stage booster. ATK's subcontractor, United Space Alliance of Houston, is designing, developing and testing the parachutes at its facilities at NASA's Kennedy Space Center in Florida. NASA's Johnson Space Center in Houston hosts the Constellation Program and Orion Crew Capsule Project Office and provides test instrumentation and support personnel. Together, these teams are developing vehicle hardware, evolving proven technologies, and testing components and systems. Their work builds on powerful, reliable space shuttle propulsion elements and nearly a half-century of NASA space flight experience and technological advances. Ares I is an inline, two-stage rocket configuration topped by the Crew Exploration Vehicle, its service module, and a launch abort system. This HD video image depicts friction stir welding used in manufacturing aluminum panels that will fabricate the Ares I upper stage barrel. The aluminum panels are subjected to confidence panel tests during which the bent aluminum is stressed to breaking point and thoroughly examined. The panels are manufactured by AMRO Manufacturing located in El Monte, California. (Highest resolution available)

  1. Deconvoluting the Friction Stir Weld Process for Optimizing Welds

    Schneider, Judy; Nunes, Arthur C.

    2008-01-01

    In the friction stir welding process, the rotating surfaces of the pin and shoulder contact the weld metal and force a rotational flow within the weld metal. Heat, generated by the metal deformation as well as frictional slippage with the contact surface, softens the metal and makes it easier to deform. As in any thermo-mechanical processing of metal, the flow conditions are critical to the quality of the weld. For example, extrusion of metal from under the shoulder of an excessively hot weld may relax local pressure and result in wormhole defects. The trace of the weld joint in the wake of the weld may vary geometrically depending upon the flow streamlines around the tool with some geometry more vulnerable to loss of strength from joint contamination than others. The material flow path around the tool cannot be seen in real time during the weld. By using analytical "tools" based upon the principles of mathematics and physics, a weld model can be created to compute features that can be observed. By comparing the computed observations with actual data, the weld model can be validated or adjusted to get better agreement. Inputs to the model to predict weld structures and properties include: hot working properties ofthe metal, pin tool geometry, travel rate, rotation and plunge force. Since metals record their prior hot working history, the hot working conditions imparted during FSW can be quantified by interpreting the final microstructure. Variations in texture and grain size result from variations in the strain accommodated at a given strain rate and temperature. Microstructural data from a variety of FSWs has been correlated with prior marker studies to contribute to our understanding of the FSW process. Once this stage is reached, the weld modeling process can save significant development costs by reducing costly trial-and-error approaches to obtaining quality welds.

  2. Mixing In Jet-Stirred Reactors With Different Geometries

    Ayass, Wassim W.

    2013-12-01

    This work offers a well-developed understanding of the mixing process inside Jet- Stirred Reactors (JSR’s) with different geometries. Due to the difficulty of manufacturing these JSR’s made in quartz, existing JSR configurations were assessed with certain modifications and optimal operating conditions were suggested for each reactor. The effect of changing the reactor volume, the nozzle diameter and shape on mixing were both studied. Two nozzle geometries were examined in this study, a crossed shape nozzle and an inclined shape nozzle. Overall, six reactor configurations were assessed by conducting tracer experiments - using the state-of-art technologies of high-speed cameras and laser absorption spectroscopy- and Computational Fluid Dynamics (CFD) simulations. The high-speed camera tracer experiment gives unique qualitative information – not present in the literature – about the actual flow field. On the other hand, when using the laser technique, a more quantitative analysis emerges with determining the experimental residence time distribution (RTD) curves of each reactor. Comparing these RTD curves with the ideal curve helped in eliminating two cases. Finally, the CFD simulations predict the RTD curves as well as the mixing levels of the JSR’s operated at different residence times. All of these performed studies suggested the use of an inclined nozzle configuration with a reactor diameter D of 40mm and a nozzle diameter d of 1mm as the optimal choice for low residence time operation. However, for higher residence times, the crossed configuration reactor with D=56mm and d=0.3mm gave a nearly perfect behavior.

  3. Ethylene oxidation chemistry in a well-stirred reactor

    Marinov, N. [Lawrence Livermore National Lab., CA (United States); Malte, P. [Univ. of Washington, Seattle, WA (United States). Dept. of Mechanical Engineering

    1994-09-01

    Ethylene is an important intermediate in the combustion of methane, larger aliphatic hydrocarbons, and aromatics. Detailed fuel-lean C{sub 2}H{sub 4}H{sub 2}O/air well-stirred reactor data by Thornton were used to analyze reported combustion chemistry mechanisms and the development of this study`s ethylene oxidation mechanism. The data set had been obtained for the temperature range 1,003 to 1,253 K and ethylene-oxygen equivalence ratio range 0.086 to 0.103, at atmospheric pressure. Mechanisms were derived from reaction sets of Westbrook and Pitz, and Dagaut, Cathonnet and Boettner. Examination of each reported mechanism indicated unusually large kinetic rates for the vinyl decomposition reaction were used in order to obtain agreement with the Thornton data set. An ethylene oxidation model was developed in order to address the mechanistic problems of the previous models. This study`s mechanism well simulated the overall rate of ethylene oxidation and concentration profiles of CO, CO{sub 2}, H{sub 2}, CH{sub 2}O, C{sub 2}H{sub 2}, CH{sub 3}OH, CH{sub 4}, and C{sub 2}H{sub 6}. Successful predictions by the model were dependent on a new high temperature vinyl oxidation reaction route, C{sub 2}H{sub 3} + O{sub 2} = CH{sub 2}CHO + O with a branching ratio of 1.19--1.21 at 1,053 K to 1.63--2.47 at 1,253 K. The branching ratio values were dependent upon the extent of fall-off for the C{sub 2}H{sub 3} + O{sub 2} = CH{sub 2}O + HCO reaction. 132 refs.

  4. Detailed Microstructural Characterization and Restoration Mechanisms of Duplex and Superduplex Stainless Steel Friction-Stir-Welded Joints

    Santos, T. F. A.; Torres, E. A.; Lippold, J. C.; Ramirez, A. J.

    2016-12-01

    Duplex stainless steels are successfully used in a wide variety of applications in areas such as the food industry, petrochemical installations, and sea water desalination plants, where high corrosion resistance and high mechanical strength are required. However, during fusion welding operations, there can be changes to the favorable microstructure of these materials that compromise their performance. Friction stir welding with a non-consumable pin enables welded joints to be obtained in the solid state, which avoids typical problems associated with solidification of the molten pool, such as segregation of alloying elements and the formation of solidification and liquefaction cracks. In the case of superduplex stainless steels, use of the technique can avoid unbalanced proportions of ferrite and austenite, formation of deleterious second phases, or growth of ferritic grains in the heat-affected zone. Consolidated joints with full penetration were obtained for 6-mm-thick plates of UNS S32101 and S32205 duplex stainless steels, and S32750 and S32760 superduplex steels. The welding heat cycles employed avoided the conditions required for formation of deleterious phases, except in the case of the welded joint of the S32760 steel, where SEM images indicated the formation of secondary phases, as corroborated by decreased mechanical performance. Analysis using EBSD and transmission electron microscopy revealed continuous dynamic recrystallization by the formation of cellular arrays of dislocations in the ferrite and discontinuous dynamic recrystallization in the austenite. Microtexture evaluation indicated the presence of fibers typical of shear in the thermomechanically affected zone. These fibers were not obviously present in the stir zone, probably due to the intensity of microstructural reformulation to which this region was subjected.

  5. Identifiability of sorption parameters in stirred flow-through reactor experiments and their identification with a Bayesian approach.

    Nicoulaud-Gouin, V; Garcia-Sanchez, L; Giacalone, M; Attard, J C; Martin-Garin, A; Bois, F Y

    2016-10-01

    This paper addresses the methodological conditions -particularly experimental design and statistical inference- ensuring the identifiability of sorption parameters from breakthrough curves measured during stirred flow-through reactor experiments also known as continuous flow stirred-tank reactor (CSTR) experiments. The equilibrium-kinetic (EK) sorption model was selected as nonequilibrium parameterization embedding the Kd approach. Parameter identifiability was studied formally on the equations governing outlet concentrations. It was also studied numerically on 6 simulated CSTR experiments on a soil with known equilibrium-kinetic sorption parameters. EK sorption parameters can not be identified from a single breakthrough curve of a CSTR experiment, because Kd,1 and k(-) were diagnosed collinear. For pairs of CSTR experiments, Bayesian inference allowed to select the correct models of sorption and error among sorption alternatives. Bayesian inference was conducted with SAMCAT software (Sensitivity Analysis and Markov Chain simulations Applied to Transfer models) which launched the simulations through the embedded simulation engine GNU-MCSim, and automated their configuration and post-processing. Experimental designs consisting in varying flow rates between experiments reaching equilibrium at contamination stage were found optimal, because they simultaneously gave accurate sorption parameters and predictions. Bayesian results were comparable to maximum likehood method but they avoided convergence problems, the marginal likelihood allowed to compare all models, and credible interval gave directly the uncertainty of sorption parameters θ. Although these findings are limited to the specific conditions studied here, in particular the considered sorption model, the chosen parameter values and error structure, they help in the conception and analysis of future CSTR experiments with radionuclides whose kinetic behaviour is suspected.

  6. Direct Microscopic And Microholographic Observations Of The Solidification Of Particles From Rapidly Stirred Melts

    Smeulders, R. J.; Mischgofsky, F. H.; Frankena, H. J.

    1983-06-01

    A microscopic set-up to observe fast moving solidifying particles during stir casting is described. The set-up consists of a Ruby laser and a frequency doubled Nd3+:YAG laser, a model device of an actual stir casting apparatus filled with a transparent organic alloy, melting at a low temperature and three different recording systems. Using a neopentyl alcohol alloy as a model substance for metal alloys, the crystallization process is studied by direct observation. Pulses from both lasers are used to provide a sufficiently short exposure time to take (simultaneously) holograms, microphotographs and videorecordings of the fast moving (flow rates up to 10 ms-1) small particles with sizes in the order of 10-103 μm. Primarily solidified particles appear to have equiaxed dendritic shapes. The longest diameter of these particles attain a maximum for low stirring rates and high cooling rates. After a period of stirring, some of the dendrite tips grow and transform the particle shapes into more spherical ones. At this stage the morphology of the solidified particles shows a good similarity with stir casted metal alloys.

  7. Experimental studies of parameters affecting the heat generation in friction stir welding process

    Mijajlović Miroslav M.

    2012-01-01

    Full Text Available Heat generation is a complex process of transformation of a specific type of energy into heat. During friction stir welding, one part of mechanical energy delivered to the welding tool is consumed in the welding process, another is used for deformational processes etc., and the rest of the energy is transformed into heat. The analytical procedure for the estimation of heat generated during friction stir welding is very complex because it includes a significant number of variables and parameters, and many of them cannot be fully mathematically explained. Because of that, the analytical model for the estimation of heat generated during friction stir welding defines variables and parameters that dominantly affect heat generation. These parameters are numerous and some of them, e. g. loads, friction coefficient, torque, temperature, are estimated experimentally. Due to the complex geometry of the friction stir welding process and requirements of the measuring equipment, adequate measuring configurations and specific constructional solutions that provide adequate measuring positions are necessary. This paper gives an overview of the process of heat generation during friction stir welding, the most influencing parameters on heat generation, constructional solutions for the measuring equipment needed for these experimental researches and examples of measured values.

  8. Mechanical properties and structure of friction stir welds of rolled Zr-modified AA5083 alloy

    Malopheyev, S.; Mironov, S.; Kaibyshev, R.

    2016-11-01

    Microstructure and mechanical properties of friction stir welds of Zr-modified AA5083 aluminum sheets were studied. The sheets were produced by cold or hot rolling with a total reduction of 80%. In both rolled conditions, the average high angle boundary spacing was 17-18 µm. The density of free dislocations was ˜5.6 × 1013 and ˜3.5 × 1014 m-2 in hot rolled and cold rolled conditions, respectively. The volume fraction of incoherent Al6Mn dispersoids with an average diameter of ˜25 nm was measured to be ˜0.076%. Defect-free welds were produced by double-side friction stir welding (FSW). Friction stir welding led to the formation of fully recrystallized microstructures with the average grain size about 2.5 µm and low dislocation density in the stir zone in both conditions. The average size and volume fraction of Al6Mn particles increased to ˜25 nm and ˜0.1%, respectively. The joint efficiency of the friction stir welds for ultimate tensile strength was found to be 74 and 94% in the cold-rolled and hot-rolled preprocessed material conditions. The relatively low weld strength was attributed to the elimination of dislocation substructure strengthening during FSW.

  9. Physical Simulation of Friction Stir Welding and Processing of Nickel-Base Alloys Using Hot Torsion

    Rule, James R.; Lippold, John C.

    2013-08-01

    The Gleeble hot torsion test was utilized in an attempt to simulate the friction stir-processed microstructure of three Ni-base alloys: Hastelloy X, Alloy 625, and Alloy 718. The simulation temperatures were based on actual thermal cycles measured by embedded thermocouples during friction stir processing of these alloys. Peak process temperatures were determined to be approximately 1423 K (1150 °C) for Hastelloy X and Alloy 625 K and 1373 K (352 °C and 1100 °C) for Alloy 718. The peak temperature and cooling rates were programed into the Gleeble™ 3800 thermo-mechanical simulator to reproduce the stir zone and thermo-mechanically affected zone (TMAZ) microstructures. The TMAZ was successfully simulated using this technique, but the stir zone microstructure could not be accurately reproduced, with hot torsion samples exhibiting larger grain size than actual friction stir processing trials. Shear stress and strain rates as a function of temperature were determined for each material using hot torsion simulation.

  10. The Effect of Rotation Stirring on Macrosegregation in Bi-Sn Alloy

    Zulaida Yeni Muriani

    2017-01-01

    Full Text Available Macrosegregation is a defect that difficult to avoid in a metal alloy made by casting method. Macrosegregation can cause decreasing in mechanical properties of casting products. It will reduce their performance in industrial application. Macrosegregation is convinced occur during solidification time in liquid alloy. In the early solidified, The solids move upward/downward in liquid alloy during solidification are considered to contribute on macrosegregation formation. This movement occur due to the density differences between the solid and the surrounding liquid. This research want to observe the effect of stirring on macrosegregation formation for interfering on the movement of initial solidified solid. Stiring with rotation method is applied in this experiment at certain temperature. The temperature and the rotation speed of stirring are varied to observe the effect of rotation stirring on macrosegregation formation. The mold is covered by insulation jacket and kept the bottom part opened in order to obtain the directionally solidification. The result shows that the rotation stirring can change the macrostructure of casting but in case of composition distribution, the macrosegregation still appear. Increasing the rotation stirring will rise solid crystals up and the macrosegregation become more uniform and the treatment is better if conducting at lower temperature.

  11. Stirring in massive, young debris discs from spatially resolved Herschel images

    Moór, A; Ábrahám, P; Apai, D; Balog, Z; Grady, C; Henning, Th; Juhász, A; Kiss, Cs; Krivov, A V; Pawellek, N; Szabó, Gy M

    2014-01-01

    A significant fraction of main-sequence stars are encircled by dusty debris discs, where the short-lived dust particles are replenished through collisions between planetesimals. Most destructive collisions occur when the orbits of smaller bodies are dynamically stirred up, either by the gravitational effect of locally formed Pluto-sized planetesimals (self-stirring scenario), or via secular perturbation caused by an inner giant planet (planetary stirring). The relative importance of these scenarios in debris systems is unknown. Here we present new Herschel Space Observatory imagery of 11 discs selected from the most massive and extended known debris systems. All discs were found to be extended at far-infrared wavelengths, five of them being resolved for the first time. We evaluated the feasibility of the self-stirring scenario by comparing the measured disc sizes with the predictions of the model calculated for the ages of our targets. We concluded that the self-stirring explanation works for seven discs. How...

  12. Post Process Characterization of Friction Stir Welded Components Project

    National Aeronautics and Space Administration — Luna Innovations Incorporated proposes in this STTR Phase II project to continue development and validation of Luna's amplitude-dependent, nonlinear ultrasonic...

  13. Safety enhancement by transposition of the nitration of toluene from semi-batch reactor to continuous intensified heat exchanger reactor

    Di Miceli Raimondi, Nathalie; Olivier Maget, Nelly; Gabas, Nadine; Cabassud, Michel; GOURDON, Christophe

    2015-01-01

    International audience; The behaviour of a continuous intensified heat exchanger (HEX) reactor in case of process failure is analysed and compared to the behaviour of a semi-continuous reactor. The nitration of toluene is considered as test reaction to identify the main failure scenarios that can lead to thermal runaway in both processes using the HAZOP method.No flow rate of process fluid and utility fluid in the continuous process. No stirring during feeding of the reactor followed by norma...

  14. Process parameters optimization for friction stir welding of RDE-40 aluminium alloy using Taguchi technique

    A.K.LAKSHMINARAYANAN; V.BALASUBRAMANIAN

    2008-01-01

    Taguchi approach was applied to determine the most influential control factors which will yield better tensile strength of the joints of friction stir welded RDE-40 aluminium alloy. In order to evaluate the effect of process parameters such as tool rotational speed, traverse speed and axial force on tensile strength of friction stir welded RDE-40 aluminium alloy, Taguchi parametric design and optimization approach was used. Through the Taguchi parametric design approach, the optimum levels of process parameters were determined. The results indicate that the rotational speed, welding speed and axial force are the significant parameters in deciding the tensile strength of the joint. The predicted optimal value of tensile strength of friction stir welded RDE-40 aluminium alloy is 303 MPa. The results were confirmed by further experiments.

  15. Simulation on solidification of an Al-Ni alloy under electromagnetic stirring

    Sha Minghong

    2012-08-01

    Full Text Available The microstructure of Al-Ni alloy has a significant influence on its performance, while electromagnetic stirring is one of the most effective methods for control of solidification structure of Al alloy. To investigate the effect of electromagnetic stirring on the solidification of the ingot, the solidification of the Al-50Ni alloy in vacuum with electromagnetic stirring was described by numerical simulation in this paper; and a three dimensional mathematical model was established. The electromagnetic field was simulated by ANSYS software and the thermal-flow field was simulated by FLUENT software. The coupling between the electromagnetic field and the thermal-flow field was implemented by user-defined subroutines. It is found that the current intensity has significant influences on the fluid flow and the microstructure of the alloy. The simulation results agree well with the experimental results, and the optimum current intensity under the exprimental conditions is 80 A, while the frequency is 50 Hz.

  16. Temperature comparison of initial, middle and final point of polypropylene friction stir welded

    Kusharjanta, Bambang; Raharjo, Wahyu P.; Triyono

    2016-03-01

    Friction Stir Welding is known as a new solid state joining process. This process is applied in thermoplastic polymers material recently. One of member thermoplastic polymer is polypropylene. Polypropylene sheet 6 mm thick was friction stir welded with a cone cut steel pin. Tool rotation, travelling speed, and plunge depth, as welding parameters were 620 rpm, 7.3 mm/minutes and 0.02 mm respectively. Temperature at the initial, middle, and final point of advance side working piece were measured and compared. Measurement were done by thermocouple and recorded by data acquisition. Based on this research, it is concluded that temperature at the initial, middle and final point of friction stir welding process are different. The highest temperature peak reach at the middle point on the advance side which affects face bending strength.

  17. Effect of Tool Shoulder and Pin Probe Profiles on Friction Stirred Aluminum Welds - a Comparative Study

    H. K. Mohanty; M. M. Mahapatra; P. Kumar; P. Biswas; N. R. Mandal

    2012-01-01

    In marine application,marine grade steel is generally used for haul and superstructures.However,aluminum has also become a good choice due to its lightweight qualities,while rusting of aluminum is minimal compared to steel.In this paper a study on friction stir welding of aluminum alloys was presented.The present investigation deals with the effects of different friction stir welding tool geometries on mechanical strength and the microstructure properties of aluminum alloy welds.Three distinct tool geometries with different types of shoulder and tool probe profiles were used in the investigation according to the design matrix.The effects of each tool shoulder and probe geometry on the weld was evaluated.It was also observed that the friction stir weld tool geometry has a significant effect on the weldment reinforcement,microhardness,and weld strength.

  18. Effect of tool geometry on friction stir spot welding of polypropylene sheets

    M. K. Bilici

    2012-10-01

    Full Text Available The effects of tool geometry and properties on friction stir spot welding properties of polypropylene sheets were studied. Four different tool pin geometries, with varying pin angles, pin lengths, shoulder diameters and shoulder angles were used for friction stir spot welding. All the welding operations were done at the room temperature. Lap-shear tensile tests were carried out to find the weld static strength. Weld cross section appearance observations were also done. From the experiments the effect of tool geometry on friction stir spot weld formation and weld strength were determined. The optimum tool geometry for 4 mm thick polypropylene sheets were determined. The tapered cylindrical pin gave the biggest and the straight cylindrical pin gave the lowest lap-shear fracture load.

  19. Mechanism of removing inclusions from molten aluminum by stirring active molten flux

    周鸣; 李克; 孙宝德; 疏达; 倪红军; 王俊; 张佼

    2003-01-01

    Removal of inclusions from industrial pure molten aluminum(A01) by stirring active molten flux wasstudied. Wettability of nonmetallic inclusions in the molten aluminum was worse than that in active molten flux. Ac-cording to the surface renewal model, the inclusions were easily transferred into molten active flux from fine alumi-num droplets and then reacted chemically when molten aluminum was dispersed into fine aluminum droplets in stir-ring active molten flux. Tensile tests show that tensile strength of purified tensile sample(as-cast) increases by8.59%. SEM photographs show that the fracture cracks of purified tensile sample are homogeneous, and the dim-ples are small and homogeneous. From metallographs and statistic results of Leco analysis software, it is found thatthe quantities and sizes of the inclusions in purified sample are obviously fewer and smaller than in unpurified tensilesample(as-cast).

  20. Annulus electromagnetic stirring for preparing semisolid A357 aluminum alloy slurry

    BAI Yue-long; XU Jun; ZHANG Zhi-feng; SHI Li-kai

    2009-01-01

    The effects of pouring temperature and annulus gap width on the microstructure of the semi-solid A357 aluminum alloy slurry prepared by annulus electromagnetic stirring(AEMS) technology were investigated. The results show that low pouring temperature and narrow annulus gap are advantageous to obtaining the small spherical primary α(Al) phase. The lower the pouring temperature is and the smaller the annulus gap width is, the more uniform, the smaller and the more spherical the microstructure is. The microstructures obtained by the ordinary electromagnetic stirring and AEMS were compared. The results indicate that the primary α(Al) particles are globular, small and distribute homogeneously in the slurry obtained by AEMS. But in the slurry obtained by the ordinary electromagnetic stirring, the primary α(Al) particles are small dendrites in the edge of the slurry and they are large and rosette-like or dendritic in the inner of the slurry.

  1. Numerical Simulation of Linear Electromagnetic Stirring in Secondary Cooling Region of Slab Caster

    HUANG Jun-tao; WANG En-gang; HE Ji-cheng

    2003-01-01

    According to the theory of alternating magnetohydrodynamics and magnetic boundary renewal method, mathematical models were proposed for electromagnetic stirring in secondary cooling region (SEMS) of slab caster. The magnetic fields and flow fields of melt were simulated with SEMS. It′s shown that the electromagnetic forces with inward and sidelong components produced by travel magnetic field at the wide faces of slab make the melt whirling in horizontal section, and the convection of the melt is strengthened obviously there. In addition, magnetic flux density attenuates from the edge to the center of slab, and the profile of the melt velocity along slab thickness in the center of the horizontal section takes a two-opposite-peak configuration. Ultimately, the stirring intensity and features are determined by the electromagnetic parameters, coil arrangement and stirring types.

  2. Finite Element Simulation in Superplastic forming of Friction Stir Welded Aluminium Alloy 6061-T6

    P Ganesh

    2011-09-01

    Full Text Available Superplasticity in materials is the ability of materials to achieve large elongation only under specific conditions of temperature and strain rate. Superplastic Forming (SPF is an important industrial process that has found application in sheet metal forming in the aerospace and automotive industries. Friction Stir Welding (FSW is a solid state joining process that can alter the grain structure of the parent material. FSW process is an effective tool to refine the grain structure of the sheet metal and enhance their Superplasticity. Friction Stir Welding was used to join Superplastic AA 6061-T6 sheets. The Finite Element Simulation was performed for the Superplastic Forming of the Friction Stir Welded joints to evaluate the thinning and formability of AA 6061-T6 for hemispherical shape. The commercially available Finite Element Software ABAQUS was used to execute these simulations.

  3. Experimental Study on Scale-Up of Solid-Liquid Stirred Tank with an Intermig Impeller

    Zhao, Hongliang; Zhao, Xing; Zhang, Lifeng; Yin, Pan

    2017-02-01

    The scale-up of a solid-liquid stirred tank with an Intermig impeller was characterized via experiments. Solid concentration, impeller just-off-bottom speed and power consumption were measured in stirred tanks of different scales. The scale-up criteria for achieving the same effect of solid suspension in small-scale and large-scale vessels were evaluated. The solids distribution improves if the operating conditions are held constant as the tank is scaled-up. The results of impeller just-off-bottom speed gave X = 0.868 in the scale-up relationship ND X = constant. Based on this criterion, the stirring power per unit volume obviously decreased at N = N js, and the power number ( N P) was approximately equal to 0.3 when the solids are uniformly distributed in the vessels.

  4. Microstructural and Mechanical Characteristics of Aluminum Alloy AA5754 Friction Stir Spot Welds

    Mahmoud, T. S.; Khalifa, T. A.

    2014-03-01

    In the present investigation, friction stir spot welding on annealed aluminum alloy AA5754 sheets was performed. The influences of the tool rotational speed and tool stirring (dwell) time on the weld structure and static strength of welds were evaluated. The results revealed that the width of the completely metallurgical-bonded region increases with the increasing tool rotational speed and/or the dwell time up to certain levels. Increasing such parameters beyond these levels slightly reduces the width of the bonding region. The stirred zone exhibited higher microhardness than that of the base material. The tensile-shear force was found to increase with the increasing tool rotational speed and/or dwell time up to a certain level (9s). Higher tool rotational speeds and/or prolonged dwell times slightly reduce(s) the tensile-shear force.

  5. Processing-Microstructure Relationships in Friction Stir Welding of MA956 Oxide Dispersion Strengthened Steel

    Baker, Bradford W.; Menon, E. Sarath K.; McNelley, Terry R.; Brewer, Luke N.; El-Dasher, Bassem; Farmer, Joseph C.; Torres, Sharon G.; Mahoney, Murray W.; Sanderson, Samuel

    2014-12-01

    A comprehensive set of processing-microstructure relationships is presented for friction stir welded oxide dispersion strengthened MA956 steel. Eight rotational speed/traverse speed combinations were used to produce friction stir welds on MA956 plates using a polycrystalline cubic boron nitride tool. Weld conditions with high thermal input produced defect-free, full-penetration welds. Electron backscatter diffraction results showed a significant increase in grain size, a persistent body centered cubic torsional texture in the stir zone, and a sharp transition in grain size across the thermo-mechanically affected zone sensitive to weld parameters. Micro-indentation showed an asymmetric reduction in hardness across a transverse section of the weld. This gradient in hardness was greatly increased with higher heat inputs. The decrease in hardness after welding correlates directly with the increase in grain size and may be explained with a Hall-Petch type relationship.

  6. Mechanical properties of friction stir butt-welded Al-5086 H32 plate

    G. Çam

    2008-10-01

    Full Text Available Purpose: The purpose of the paper is to study Al-5086 H32 plates with a thickness of 3 mm friction stir butt-welded using different welding speeds at a tool rotational speed of 1600 rpm. Design/methodology/approach: The effect of welding speed on the weld performance of the joints was investigated by conducting optical microscopy, microhardness measurements and mechanical tests (i.e. tensile and bend tests. The effect of heat input during friction stir welding on the microstructure, and thus mechanical properties, of cold-rolled Al- 5086 plates was also determined.Findings: The experimental results indicated that the maximum tensile strength of the joints, which is about 75% that of the base plate, was obtained with a traverse speed of 200 mm/min at the tool rotational speed used, e.g. 1600 rpm, and the maximum bending angle of the joints can reach 180º. The maximum ductility performance of the joints was, on the other hand, relatively low, e.g. about 20%. These results are not unexpected due to the loss of the cold-work strengthening in the weld region as a result of the heat input during welding, and thus the confined plasticity within the stirred zone owing to strength undermatching. Higher joint performances can also be achieved by increasing the penetration depth of the stirring probe in butt-friction stir welding of Al-5086 H32 plates.Research limitations/implications: The results suggest that both strength and ductility performances can be increased by optimizing the tool penetration depth.Originality/value: Examination of mechanical properties of friction stir butt-welded Al-5086 H32 plate.

  7. Spindle-shaped nanoscale yolk/shell magnetic stirring bars for heterogeneous catalysis in macro- and microscopic systems.

    Yang, Shuliang; Cao, Changyan; Peng, Li; Huang, Peipei; Sun, Yongbin; Wei, Fang; Song, Weiguo

    2016-01-28

    A new type of spindle-shaped nanoscale yolk/shell magnetic stirring bar containing noble metal nanoparticles was prepared. The as-synthesized Pd-Fe@meso-SiO2 not only showed impressive activity and stability as a heterogeneous catalyst in a macroscopic flask system, but also acted as an efficient nanoscale magnetic stir bar in a microscopic droplet system.

  8. Effect of cryogenic cooling on corrosion of friction stir welded AA7010-T7651

    Jariyaboon, Manthana; Davenport, A. J.; Ambat, Rajan

    2010-01-01

    Purpose - The purpose of this paper is to study how cryogenic CO2 cooling during the welding process affects corrosion behaviour of friction stir welding (FSW) AA7010-T7651. Design/methodology/approach - Friction stir welded AA7010-17651 was produced with a rotation speed of 288 rpm and a travel...... does not show any influence on anodic reactivity of the weld region (both nugget and HAZ) compared to uncooled weld metal. However, the width of the reactive HAZ is reduced after cooling, as compared to the uncooled weld. The cooled welds show higher cathodic reactivity in the nugget region than does...

  9. Numerical Simulation of Gas—Liquid Flow in a Stirred Tank with a Rushton Impeller

    WANGWeijing; MAOZaisha

    2002-01-01

    The gas-liquid flow field in a stirred tank with a Rushton disk turbine,including the impeller region,was numerically simulated using the improved inner-outer iterative procedure.The characteristic features of the strirred tank,such as gas cavity and accumulation of gas at the two sides of wall baffles,can be captured by the simulation.The simulated results agree well with available experimental data.Since the improved inner-outer iterative algorithm demands no empirical formula and experimental data for the impeller region,and the approach seems generally applicable for simulating gas-liquid stirred tanks.

  10. Friction Stir Spot Welding: A Review on Joint Macro- and Microstructure, Property, and Process Modelling

    X. W. Yang

    2014-01-01

    Full Text Available Friction stir spot welding (FSSW is a very useful variant of the conventional friction stir welding (FSW, which shows great potential to be a replacement of single-point joining processes like resistance spot welding and riveting. There have been many reports and some industrial applications about FSSW. Based on the open literatures, the process features and variants, macro- and microstructural characteristics, and mechanical properties of the resultant joints and numerical simulations of the FSSW process were summarized. In addition, some applications of FSSW in aerospace, aviation, and automobile industries were also reviewed. Finally, the current problems and issues that existed in FSSW were indicated.

  11. Effect of Electromagnetic Stirring on the Quality of K417 Superalloy Ingots

    Jin; Wenzhong; Li; Tingju; Yin; Guomao

    2007-01-01

    The effect of electromagnetic stirring on the inner quality of K417 superalloy ingots is studied with EPMA and optical microscope.The results show that while an electromagnetic stirring with 50Hz frequency and 80A current is imposed,the equiax crystals of K417 superalloy ingots can be effectively refined and increased,and the central shrinkage porosity and the dendritic segregation of K417 superalloy ingots are greatly reduced,so the inner quality of K417 superalloy ingots is obviously improved.

  12. Design and Fabrication of a Stir Casting Furnace Set-Up

    Manabhanjan Sahoo

    2015-07-01

    Full Text Available Now-a-days a large variety of heating techniques/furnaces are available. There may be many method for supplying heat to the work but heat is produced either by combustion of fuel or electric resistance heating. Taking into consideration the effect of cost, safety, simplicity and ease of construction we are going for an electrical resistance heating furnace with indirect heating provisions. The stir casting furnace has two main parts that enable to perform all its operations, they are: Furnace Elements and Control Panel. This paper shows the design and fabrication of stir-casting furnace and aluminium melted and casted to form.

  13. Heterotrophic Cultivation of Cyanobacteria: Study of Effect of Exogenous Sources of Organic Carbon, Absolute Amount of Nutrients, and Stirring Speed on Biomass and Lipid Productivity

    Meireles dos Santos, Aline; Vieira, Karem Rodrigues; Basso Sartori, Rafaela; Meireles dos Santos, Alberto; Queiroz, Maria Isabel; Queiroz Zepka, Leila; Jacob-Lopes, Eduardo

    2017-01-01

    The production of bioproducts from cyanobacteria with techno-economic feasibility is a challenge to these biotechnological processes. The choice of low-cost raw materials is of great importance for the overall economy of bioprocesses, as they represent a significant percentage in the final cost of the product. The objective of this work was to study the operational parameters of cultivation (exogenous sources of organic carbon and absolute amount of nutrients) to optimize productivity in bioproducts by Aphanothece microscopica Nägeli, for further evaluation of stirring speed. The experiments were performed in a bubble column bioreactor, operating at 30°C, pH of 7.6, C/N ratio of 20, 100 mg/L of inoculum, continuous aeration of 1 volume of air per volume of culture per minute (VVM), and absence of light. The results indicate that absolute amounts of 5,000/250 using cassava starch resulted in improved system performance, reaching biomass productivity of 36.66 mg/L/h in parallel with lipid productivity of 6.65 mg/L/h. Finally, experiments with variation in stirring speed indicate that 200 rpm resulted in better average rate of substrate consumption (44.01 mg/L/h), in parallel to biomass productivity of 39.27 mg/L/h. However, the increase of stirring speed had a negative effect on lipid productivity of the process. The technological route developed indicates potential to production of biomass and bulk oil, as a result of the capacity of cyanobacteria to adapt their metabolism in varying culture conditions, which provides opportunities to modify, control, and thereby maximize the formation of targeted compounds. PMID:28265559

  14. Friction stir welding - an alternative method for sealing nuclear waste storage canisters

    Andrews, R.E. [TWI Ltd, Cambridge (United Kingdom)

    2004-12-01

    When welding 50 mm thick copper a very high heat input is required to combat the high thermal diffusivity and only the Electron Beam Welding (EBW) process had this capability when this copper canister concept was conceived. Despite the encouraging results achieved using EBW with thick section copper, SKB felt that it would be prudent to assess other joining methods. This assessment concluded that friction welding, could also provide very high quality welds to satisfy the service life requirements of the SKB canister design. A friction welding variant called Friction Stir Welding (FSW) was shown to have the capability of welding 3 mm thick copper sheet with excellent integrity and reproducibility. This later provided sufficient encouragement for SKB to consider the potential of FSW as a method for joining thick section copper, using relatively simple machine tool based technology. It was thought that FSW might provide an alternative or complementary method for welding lids, or bases to canisters. In 1997 an FSW development programme started at TWI, focussed on the feasibility of welding 10 mm thick copper plate. Once this task was successfully completed, work continued to demonstrate that progressively thicker plate, up to 50 mm thick, could be joined. At this stage, with process viability established, a full size experimental FSW canister machine was designed and built. Work with this machine finished in January 2003, when it had been shown that FSW could definitely be used to weld lids to full size canisters. This report summarises the TWI development of FSW for SKB from 1997 to January 2003. It also highlights the important aspects of the process and the project milestones that will help to ensure that SKB has a welding technology that can be used with confidence for production fabrication of copper waste storage canisters in the future. The overall conclusion to this FSW development is that there is no doubt that the FSW process could be used to produce full

  15. Formation of Oxides in the Interior of Friction Stir Welds

    Schneider, Judy; Chen, Po; Nunes, Arthur C., Jr.

    2016-01-01

    In friction stir welding (FSWing) the actual solid state joining takes place between the faying surfaces which form the weld seam. Thus the seam trace is often investigated for clues when the strength of the weld is reduced. Aluminum and its alloys are known to form a native, protective oxide on the surface. If these native surface oxides are not sufficiently broken up during the FSW process, they are reported to remain in the FSW interior and weaken the bond strength. This type of weld defect has been referred to as a lazy "S", lazy "Z", joint line defect, kissing bond, or residual oxide defect. Usually these defects are mitigated by modification of the process parameters, such as increased tool rotation rate, which causes a finer breakup of the native oxide particles. This study proposes that there may be an alternative mechanism for formation of oxides found within the weld nugget. As the oxidation rate increases at elevated temperatures above 400ºC, it may be possible for enhanced oxidation to occur on the interior surfaces during the FSW process from entrained air entering the seam gap. Normally, FSWs of aluminum alloys are made without a purge gas and it is unknown how process parameters and initial fit up could affect a potential air path into the interior during the processing. In addition, variations in FSW parameters, such as the tool rotation, are known to have a strong influence on the FSW temperature which may affect the oxidation rate if internal surfaces are exposed to entrained air. A series of FSWs were made in 3 different thickness panels of AA2219 (0.95, 1.27 and 1.56 cm) at 2 different weld pitches. As the thickness of the panels increased, there was an increased tendency for a gap to form in advance of the weld tool. If sufficient air is able to enter the workpiece gap prior to consolidation, the weld temperature can increase the oxidation rate on the interior surfaces. These oxidation rates would also be accelerated in areas of localized

  16. A Colorful Mixing Experiment in a Stirred Tank Using Non-Newtonian Blue Maize Flour Suspensions

    Trujilo-de Santiago, Grissel; Rojas-de Gante, Cecillia; García-Lara, Silverio; Ballesca´-Estrada, Adriana; Alvarez, Marion Moise´s

    2014-01-01

    A simple experiment designed to study mixing of a material of complex rheology in a stirred tank is described. Non-Newtonian suspensions of blue maize flour that naturally contain anthocyanins have been chosen as a model fluid. These anthocyanins act as a native, wide spectrum pH indicator exhibiting greenish colors in alkaline environments, blue…

  17. Holographic And Microscopic Study Of Morphology And Velocity Distribution Of Solidifying Particles In Rapidly Stirred Melts

    Smeulders, R. J.; Mischgofsky, F. H.; Frankena, H. J...

    1983-12-01

    A technique is described to observe shape development and particle displacements of fast moving solidifying particles during stir casting. The optical set-up consists of a Ruby la-ser (generating pulse pairs), a frequency doubled Nd3+:YAG laser (generating single pulses at a 10 Hz repetition rate), a model device of an actual metal stir casting apparatus filled with a transparent organic alloy and three different recording systems. Double exposure holograms and microphotographs are used to analyse the three- and two-dimensional particle displacements, respectively. Simultaneously recorded videotapes, microphotographs and holograms provide the opportunity to study the shape development at a repetition rate of 10 Hz over periods of 103 seconds in an imaging volume of 3 x 2 x 2 mm3. We found that a NPA-water alloy nucleates initially as equiaxed dendritic particles. After a period of stirring, the dendrite tips become more rounded. Finally the particles obtain the shape of a bunch of grapes. This final state is in good agreement with the morphology of stir casted metal alloys. Further we found that the flow behaviour at the start of the experiment can be decisive for the solidification process. We observed Taylor vortices and measured particle displacements, that occur in the direction of rotation and also along the axis of rotation (although there was no flow pressure excerted in that direction) and in the radial direction, too.

  18. Muscle MRI STIR signal intensity and atrophy are correlated to focal lower limb neuropathy severity

    Deroide, N.; Mambre, L.; Kubis, Nathalie [Service de Physiologie Clinique-Explorations Fonctionnelles, AP-HP, Hopital Lariboisiere, Paris (France); Universite Paris Diderot, Sorbonne Paris Cite France, Paris (France); Bousson, V.; Laredo, J.D. [Universite Paris Diderot, Sorbonne Paris Cite France, Paris (France); Radiologie Osteo-articulaire, AP-HP, Hopital Lariboisiere, Paris (France); Vicaut, E. [Universite Paris Diderot, Sorbonne Paris Cite France, Paris (France); URC, AP-HP, Hopital Lariboisiere, Paris (France)

    2014-09-26

    The objective is to determine if muscle MRI is useful for assessing neuropathy severity. Clinical, MRI and electromyography (EMG) examinations were performed in 17 patients with focal lower limb neuropathies. MRI Short Tau Inversion Recovery (STIR) signal intensity, amyotrophy, and muscle fatty infiltration measured after T1-weighted image acquisition, EMG spontaneous activity (SA), and maximal voluntary contraction (MVC) were graded using semiquantitative scores and quantitative scores for STIR signal intensity and were correlated to the Medical Research Council (MRC) score for testing muscle strength. Within this population, subgroups were selected according to severity (mild versus severe), duration (subacute versus chronic), and topography (distal versus proximal) of the neuropathy. EMG SA and MVC MRI amyotrophy and quantitative scoring of muscle STIR intensity were correlated with the MRC score. Moreover, MRI amyotrophy was significantly increased in severe, chronic, and proximal neuropathies along with fatty infiltration in chronic lesions. Muscle MRI atrophy and quantitative evaluation of signal intensity were correlated to MRC score in our study. Semiquantitative evaluation of muscle STIR signal was sensitive enough for detection of topography of the nerve lesion but was not suitable to assess severity. Muscle MRI could support EMG in chronic and proximal neuropathy, which showed poor sensitivity in these patients. (orig.)

  19. Structure and properties of fixed joints formed by ultrasonic-assisted friction-stir welding

    Fortuna, S. V., E-mail: s-fortuna@ispms.ru; Ivanov, K. V., E-mail: ikv@ispms.ru; Eliseev, A. A., E-mail: alan@ispms.ru [Institute of Strength Physics and Materials ScienceTomsk, 634055 (Russian Federation); Tarasov, S. Yu., E-mail: tsy@ispms.ru; Ivanov, A. N., E-mail: ivan@ispms.ru; Rubtsov, V. E., E-mail: rvy@ispms.ru; Kolubaev, E. A., E-mail: eak@ispms.ru [Institute of Strength Physics and Materials ScienceTomsk, 634055 (Russian Federation); National Research Tomsk Polytechnic University, Tomsk, 634050 (Russian Federation)

    2015-10-27

    This paper deals with structure and properties of aluminum alloy 7475 and its joints obtained by friction stir welding including under ultrasonic action. Microhardness measurements show that ultrasonic action increases strength properties of the joints. Optical and transmission electron microscopy reveals that this effect is related to the precipitation of tertiary coherent S-and T-phase particles.

  20. An analytical model for the heat generation in friction stir welding

    Schmidt, Henrik Nikolaj Blich; Hattel, Jesper; Wert, John

    2004-01-01

    The objective of this work is to establish an analytical model for heat generation by friction stir welding (FSW), based on different assumptions of the contact condition between the rotating tool surface and the weld piece. The material flow and heat generation are characterized by the contact...

  1. Optimum condition by mechanical characteristic evaluation in friction stir welding for 5083-O Al alloy

    Min-Su HAN; Seung-Jun LEE; Jae-Cheul PARK; Seok-Cheol KO; Yong-Bin WOO; Seong-Jong KIM

    2009-01-01

    The mechanical characteristics for friction stir welding (FSW) of 5083-O Al alloy were evaluated. The results show that in FSW at 800 r/min and 124 mm/min, a weld defect is observed at the start point. However, the button shape at the end point is good and the stir zone has a soft appearance. At 267 mm/min, a void occurs at the button. A slight weld defect and rough stir zone are seen both at the start and end points at 342 mm/min. Moreover, at the bottom, a tunnel-type void is observed from an early stage to the end point, and at 1 800 r/min, a weld defect can be found from an early stage to the end point. These defects are rough with imperfect joining due to excessive rotation speed and high physical force. Weld fractures relative to rotational and travel speeds are observed at the stir zone. The optimum FSW conditions are a welding speed of 124 mm/min and a rotational speed of 800 r/min.

  2. Gas Hold-Up in Stirred Tank Reactors in the Presence of Inorganic Electrolytes

    Yawalkar, Archis A.; Heesink, Albertus B.M.; Versteeg, Geert F.; Pangarkar, Vishwas G.

    2002-01-01

    Gas hold-up (εG) in air–aqueous electrolyte solutions in stirred tank reactors (STR) is correlated using a relative gas dispersion parameter, N/Ncd and a surface tension factor (STF), (c/z)(dσ/dc)^2. For electrolyte concentration below transition concentration (ct) a single correlation in the form o

  3. Microstructure of electromagnetic stirred semi-solid AZ91D alloy

    毛卫民; 甄子胜; 陈洪涛; 钟雪友

    2004-01-01

    The microstructures of semi-solid AZ91D alloy stirred by rotationally electromagnetic field were studied.The shape of primary α-Mg phase is dendrite under conventional solidification condition and the primary α-Mg grains are changed to the fine rosette-like or granular grains under electromagnetic stirring condition. If the electromagnetic stirring frequencies are low, there are a large amount of fine rosette-like primary α-Mg grains and the fine rosettelike primary α-Mg grain in two dimensions belongs to a single grain in three dimensions; there are also many spherical primary α-Mg grains, they may belong to a single grain in three dimensions and the orientation differences of the grains between them are very small. If the electromagnetic stirring frequencies are high, a lot of the fine rosette-like primary α-Mg grains disappear and are converted into granular grains, and moreover, most of these granular grains belong to different grains in three dimensions.

  4. Promoting Inquiry-Based Science Instruction: The Validation of the Science Teacher Inquiry Rubric (STIR)

    Bodzin, Alec M.; Beerer, Karen M.

    2003-01-01

    The National Science Education Standards recognize that inquiry-based instruction holds significant promise for developing scientifically literate students. The Science Teacher Inquiry Rubric (STIR) was developed based upon the National Science Education Standards' essential features of inquiry instruction (NRC, 2000). A pilot study using a…

  5. Optimization of Thermal Aspects of Friction Stir Welding – Initial Studies Using a Space Mapping Technique

    Larsen, Anders Astrup; Bendsøe, Martin P.; Schmidt, Henrik Nikolaj Blicher;

    2007-01-01

    The aim of this paper is to optimize a thermal model of a friction stir welding process. The optimization is performed using a space mapping technique in which an analytical model is used along with the FEM model to be optimized. The results are compared to traditional gradient based optimization...

  6. Multiple pass and multiple layer friction stir welding and material enhancement processes

    Feng, Zhili [Knoxville, TN; David, Stan A [Knoxville, TN; Frederick, David Alan [Harriman, TN

    2010-07-27

    Processes for friction stir welding, typically for comparatively thick plate materials using multiple passes and multiple layers of a friction stir welding tool. In some embodiments a first portion of a fabrication preform and a second portion of the fabrication preform are placed adjacent to each other to form a joint, and there may be a groove adjacent the joint. The joint is welded and then, where a groove exists, a filler may be disposed in the groove, and the seams between the filler and the first and second portions of the fabrication preform may be friction stir welded. In some embodiments two portions of a fabrication preform are abutted to form a joint, where the joint may, for example, be a lap joint, a bevel joint or a butt joint. In some embodiments a plurality of passes of a friction stir welding tool may be used, with some passes welding from one side of a fabrication preform and other passes welding from the other side of the fabrication preform.

  7. STUDY OF ELECTROMAGNETIC STIRRING REFINING MICRO- STRUCTURES OF PIPE-LINE STEEL SAW DEPOSITS

    Y. Zhang; B.N. Qian; X.M. Guo

    2002-01-01

    The effects of electromagnetic stirring on the microstructures of pipe-line steel SAWdeposited metal were investigated. The results showed that electromagnetic stirringincreased the number density of inclusions with 0.2-0.6μm in diameter and promotedthe formation and refining of acicular ferrite within austenite grains. The low tem-perature toughness of deposited metal was improved.

  8. A temperature dependent slip factor based thermal model for friction stir welding of stainless steel

    M Selvaraj

    2013-12-01

    This paper proposes a new slip factor based three-dimensional thermal model to predict the temperature distribution during friction stir welding of 304L stainless steel plates. The proposed model employs temperature and radius dependent heat source to study the thermal cycle, temperature distribution, power required, the effect of process parameters on heat generation per mm length of the weld and peak temperature during the friction stir welding process. Simulations of friction stir welding process were carried out on 304L stainless steel workpieces for various rotational and welding speeds. The predicted thermal cycle, power required and temperature distributions were found to be in good agreement with the experimental results. The heat generation per mm length of weld and peak temperature were found to be directly proportional to rotational speed and inversely proportional to welding speed. The rate of increase in heat generation per mm length of the weld and peak temperature are found to be higher at lower rotational speeds and lower at higher rotational speed. The heat generation during friction stir welding was found to be 80.8 % at shoulder, 16.1 % at pin side and 3.1 % at the bottom of the pin.

  9. CFD SIMULATION OF THE HYDRODYNAMICS AND MIXING TIME IN A STIRRED TANK

    AOYI OCHIENG

    2010-12-01

    Full Text Available Hydrodynamics and mixing efficiency in stirred tanks influence power draw and are therefore important for the design of many industrial processes. In the present study, both experimental and simulation methods were employed to determine the flow fields in different mixing tank configurations in a single phase system. Laser Doppler velocimetry (LDV and computational fluid dynamics (CFD techniques were used to determine the flow fields in systems with and without a draft tube. There was reasonable agreement between the simulation and experimental results. It was shown that the use of a draft tube with a Rushton turbine and hydrofoil impeller resulted in a reduction in the homogenization energy by 19.2 and 17.7%, respectively. This indicates that a reduction in the operating cost can be achieved with the use of a draft tube in a stirred tank and there would be a greater cost reduction in a system stirred by the Rushton turbine compared to that stirred by a propeller.

  10. Fatigue Behavior of Friction Stir-Welded Joints Repaired by Grinding

    Vidal, C.; Infante, V.

    2014-04-01

    Fatigue is undoubtedly the most important design criterion in aeronautic structures. Although friction stir-welded joints are characterized by a high mechanical performance, they can enclose some defects, especially in their root. These defects along with the relatively low residual stresses of the friction stir-welding thermomechanical cycle can turn into primary sources of crack initiation. In this context, this article deals with the fatigue behavior of friction stir-welded joints subjected to surface smoothing by grinding improvement technique. The 4-mm-thick aluminum alloy 2024-T351 was used in this study. The fatigue strength of the base material, joints in the as-welded condition, and the sound and defective friction stir-welded joints improved by grinding were investigated in detail. The tests were carried out with a constant amplitude loading and with a stress ratio of R = 0. The fatigue results show that an improvement in fatigue behavior was obtained in the joints repaired by superficial grinding technique. The weld grinding technique is better especially for lower loads and increases the high cycle fatigue strength. The fatigue strength of the improved welded joints was higher than that of the base material.

  11. Microstructure of AA 2024 fixed joints formed by friction stir welding

    Eliseev, A. A.; Kalashnikova, T. A.; Tarasov, S. Yu.; Rubtsov, V. E.; Fortuna, S. V.; Kolubaev, E. A.

    2015-10-01

    Friction stir welded butt joints on 2024T3 alloy have been obtained using different process parameters. The microstructures of all the weld joint zones have been examined and such structural parameters as grain size, particle size and volume content of particles have been determined in order to find correlations with the microhardness of the corresponding zones of the weld.

  12. Role of stirring assist during solvothermal synthesis for preparing single-crystal bismuth telluride hexagonal nanoplates

    Takashiri, Masayuki, E-mail: takashiri@tokai-u.jp [Department of Materials Science, Tokai University, 4-1-1 Kitakaname, Hiratsuka, Kanagawa 259-1292 (Japan); Kai, Shintaro; Wada, Kodai [Department of Materials Science, Tokai University, 4-1-1 Kitakaname, Hiratsuka, Kanagawa 259-1292 (Japan); Takasugi, Soichi [Graduate School of Science and Technology, Tokai University, 4-1-1 Kitakaname, Hiratsuka, Kanagawa 259-1292 (Japan); Tomita, Koji [Department of Chemistry, Tokai University, 4-1-1 Kitakaname, Hiratsuka, Kanagawa 259-1292 (Japan)

    2016-04-15

    We investigated the role of stirring assist during solvothermal synthesis for preparing high quality bismuth telluride (Bi{sub 2}Te{sub 3}) hexagonal nanoplates. We performed a series of experiments that comprised solvothermal synthesis with stirring assist at 500 rpm and without stirring assist. As a result, high purity Bi{sub 2}Te{sub 3} hexagonal nanoplates with uniform morphology and edge length of 400–800 nm were obtained by solvothermal synthesis using stirring assist, whereas intermediate products such as tellurium and tellurium oxide compounds were also produced besides the Bi{sub 2}Te{sub 3} hexagonal nanoplates by solvothermal synthesis without stirring assist. To further study the nanostructure of the nanoplates with stirring assist, we performed high-resolution transmission electron microscopy and selected-area electron diffraction analysis. It was found that the Bi{sub 2}Te{sub 3} hexagonal nanoplates were composed of rhombohedral phases and highly single-crystalline structures. Based on the experimental and analytical results, we propose a possible reaction process and growth mechanism of the Bi{sub 2}Te{sub 3} hexagonal nanoplates. The reaction rate is the key factor to control the shapes of nanostructures. When the reaction rate was sufficient, it proceeded to the final stage, and then Bi{sub 2}Te{sub 3} nanoplates were produced. However, when the reaction rate was insufficient, the entire morphology evolution process was terminated at the intermediate stage, and intermediate products besides Bi{sub 2}Te{sub 3} nanoplates were also produced. - Highlights: • High quality Bi{sub 2}Te{sub 3} hexagonal nanoplates were prepared by solvothermal synthesis. • Role of stirring assist during the solvothermal synthesis were investigated. • Bi{sub 2}Te{sub 3} hexagonal nanoplates with edge length of 400–800 nm were obtained. • Bi{sub 2}Te{sub 3} hexagonal nanoplates were composed of single-crystalline structures. • The reaction rate is the key

  13. Design of an Adaptive PID Neural Controller for Continuous Stirred Tank Reactor based on Particle Swarm Optimization

    Khulood A. Dagher

    2013-12-01

    Full Text Available A particle swarm optimization algorithm and neural network like self-tuning PID controller for CSTR system is presented. The scheme of the discrete-time PID control structure is based on neural network and tuned the parameters of the PID controller by using a particle swarm optimization PSO technique as a simple and fast training algorithm. The proposed method has advantage that it is not necessary to use a combined structure of identification and decision because it used PSO. Simulation results show the effectiveness of the proposed adaptive PID neural control algorithm in terms of minimum tracking error and smoothness control signal obtained for non-linear dynamical CSTR system.

  14. Dynamic bioconversion mathematical modelling and simulation of urban organic waste co-digestion in continuously stirred tank reactor

    Fitamo, Temesgen Mathewos; Boldrin, Alessio; Dorini, G.

    The application of anaerobic digestion (AD) as process technology is increasing worldwide: the production of biogas, a versatile form of renewable energy, from biomass and organic waste materials allows mitigating greenhouse gas emission from the energy and transportation sectors while treating w...

  15. Biogas Upgrading via Hydrogenotrophic Methanogenesis in Two-Stage Continuous Stirred Tank Reactors at Mesophilic and Thermophilic Conditions

    Bassani, Ilaria; Kougias, Panagiotis; Treu, Laura;

    2015-01-01

    to the second one, where H2 was injected. This configuration was tested at both mesophilic and thermophilic conditions. After H2 addition, the produced biogas was upgraded to average CH4 content of 89% in the mesophilic reactor and 85% in the thermophilic. At thermophilic conditions, a higher efficiency of CH4...... production and CO2 conversion was recorded. The consequent increase of pH did not inhibit the process indicating adaptation of microorganisms to higher pH levels. The effects of H2 on the microbial community were studied using high-throughput Illumina random sequences and full-length 16S rRNA genes extracted...

  16. Co-digestion of food and garden waste with mixed sludge from wastewater treatment in continuously stirred tank reactors

    Fitamo, Temesgen Mathewos; Boldrin, Alessio; Boe, Kanokwan

    2016-01-01

    Co-digestions of urban organic waste were conducted to investigate the effect of the mixing ratio between sludge, food waste, grass clippings and green waste at different hydraulic retention times (HRTs). Compared to the digestion of 100% sludge, the methane yield increased by 48% and 35%, when co......-digesting sludge with food waste, grass clippings and garden waste with a corresponding % VS of 10:67.5:15.75:6.75 (R1) and 10:45:31.5:13.5 (R2), respectively. The methane yield remained constant at around 425 and 385 NmL CH4/g VS in R1 and R2, respectively, when the reactors were operated at HRTs of 15, 20 and 30...

  17. Anaerobic digestion of blackwater from vacuum toilets and kitchen refuse in a continuous stirred tank reactor (CSTR).

    Wendland, C; Deegener, S; Behrendt, J; Toshev, P; Otterpohl, R

    2007-01-01

    The objective of this research was mesophilic anaerobic digestion of blackwater from vacuum toilets (BW) and kitchen refuse (KR) in a CSTR within an ecological sanitation system. A detailed investigation of the BW characteristics was carried out. Research on anaerobic digestion was performed with CSTR of 101 volume at HRT of 10, 15 and 20 days. The digestion of BW at 20 days HRT showed stable performance without inhibition effects, in spite of relatively high ammonium concentrations. The removal of total and particulate COD was 61% and 53%, respectively, and the methane yield 10/CH4/cap/day. The addition of kitchen refuse (KR) improved the performance of the CSTR in terms of COD removal efficiency and methane yield. At 20 days HRT the removal of total and particulate COD increased up to 71% and 67%, respectively, and the methane yield to 27/CH4/cap/day. The results at 15 days HRT showed similar performance. At HRT of 10 days, the anaerobic treatment was limited but reached steady state conditions at higher VFA concentrations in the effluent, with a decrease of COD removal of 30 to 33% and of methane yields of 19 to 21%.

  18. Biogas Upgrading via Hydrogenotrophic Methanogenesis in Two-Stage Continuous Stirred Tank Reactors at Mesophilic and Thermophilic Conditions.

    Bassani, Ilaria; Kougias, Panagiotis G; Treu, Laura; Angelidaki, Irini

    2015-10-20

    This study proposes an innovative setup composed by two stage reactors to achieve biogas upgrading coupling the CO2 in the biogas with external H2 and subsequent conversion into CH4 by hydrogenotrophic methanogenesis. In this configuration, the biogas produced in the first reactor was transferred to the second one, where H2 was injected. This configuration was tested at both mesophilic and thermophilic conditions. After H2 addition, the produced biogas was upgraded to average CH4 content of 89% in the mesophilic reactor and 85% in the thermophilic. At thermophilic conditions, a higher efficiency of CH4 production and CO2 conversion was recorded. The consequent increase of pH did not inhibit the process indicating adaptation of microorganisms to higher pH levels. The effects of H2 on the microbial community were studied using high-throughput Illumina random sequences and full-length 16S rRNA genes extracted from the total sequences. The relative abundance of archaeal community markedly increased upon H2 addition with Methanoculleus as dominant genus. The increase of hydrogenotrophic methanogens and syntrophic Desulfovibrio and the decrease of aceticlastic methanogens indicate a H2-mediated shift toward the hydrogenotrophic pathway enhancing biogas upgrading. Moreover, Thermoanaerobacteraceae were likely involved in syntrophic acetate oxidation with hydrogenotrophic methanogens in absence of aceticlastic methanogenesis.

  19. Co-digestion of food and garden waste with mixed sludge from wastewater treatment in continuously stirred tank reactors.

    Fitamo, T; Boldrin, A; Boe, K; Angelidaki, I; Scheutz, C

    2016-04-01

    Co-digestions of urban organic waste were conducted to investigate the effect of the mixing ratio between sludge, food waste, grass clippings and green waste at different hydraulic retention times (HRTs). Compared to the digestion of 100% sludge, the methane yield increased by 48% and 35%, when co-digesting sludge with food waste, grass clippings and garden waste with a corresponding %VS of 10:67.5:15.75:6.75 (R1) and 10:45:31.5:13.5 (R2), respectively. The methane yield remained constant at around 425 and 385 NmL CH4/g VS in R1 and R2, respectively, when the reactors were operated at HRTs of 15, 20 and 30 days. However, the methane yield dropped significantly to 356 (R1) and 315 (R2) NmL CH4/g VS when reducing the HRT to 10 days, indicating that the process was stressed. Since the methane production rate improved significantly with decreasing HRT, the trade-off between yield and productivity was obtained at 15 days HRT.

  20. Operational strategies for thermophilic anaerobic digestion of organic fraction of municipal solid waste in continuously stirred tank reactors

    Angelidaki, Irini; Cui, J.; Chen, X.;

    2006-01-01

    Three operational strategies to reduce inhibition due to ammonia during thermophilic anaerobic digestion of source-sorted organic fraction of municipal solid waste (SS-OFMSW) rich in proteins were investigated. Feed was prepared by diluting SS-OFMSW (ratio of 1:4) with tap water or reactor proces...

  1. Biogas upgrading by injection of hydrogen in a two-stage Continuous Stirred-Tank Reactor system

    Bassani, Ilaria; Kougias, Panagiotis; Treu, Laura;

    An innovative method for biogas upgrading (i.e. CH4 content more than 90%) combines the coupling of H2, which could be produced by water electrolysis using surplus renewable electricity produced from wind mills, with the CO2 of the biogas. CO2 is biologically converted to CH4 by hydrogenotrophic...... methanogens. In this study, a novel serial biogas reactor system is presented, in which the produced biogas from the first stage reactor was introduced in the second stage, where also H2 was injected. The effects of the H2 addition on the process performance and on the microbial community were investigated...

  2. L-glutamic acid production in a continuous stirred tank bioreactor using coimmobilized bio-catalyst using a fluorosensor.

    Prabhu, N; Babu, J Sarat Chandra; Sundaram, S

    2002-01-01

    The production of L-Glutamic acid has been studied using coimmobilized whole cells of pseudomonas reptilivora and micrococcus glutamicus in a two litre Tokyo Rikakikai fermentor using glucose as selected production medium. The process was carried out at an optimum temperature of 32 degree Celsius and a pH of 7.2. The progress of the reaction was recorded using Dr. Ingold fluorosensor. The effect of initial substrate concentration, speed of agitation, volume ofcalcium alginate beads and aeration rate on the yield of glutamic acid has been investigated. It has been found that the acid production increases exponentially with substrate concentration, and mass transfer co-efficient varied linearly with aeration rate. The kinetic parameters also had been estimated.

  3. Chemical characterization and antioxidant activities comparison in fresh, dried, stir-frying and carbonized ginger.

    Li, Yuxin; Hong, Yan; Han, Yanquan; Wang, Yongzhong; Xia, Lunzhu

    2016-02-01

    Ginger (Zingiber officinale Rosc.) is a common dietary adjunct that contributes to the taste and flavor of foods, and is also an important Traditional Chinese medicine (TCM). Different processing methods can produce different processed gingers with dissimilar chemical constituents and pharmacological activities. In this study, an ultra-performance liquid chromatography/quadrupole-time-of-flight mass spectrometry (UPLC/QTOF-MS) was applied to identify the complicated components from fresh, dried, stir-frying and carbonized ginger extracts. All of the 27 compounds were identified from four kinds of ginger samples (fresh, dried, stir-frying and carbonized ginger). Five main constituents (zingerone, 6-gingerol, 8-gingerol, 6-shogaol and 10-gingerol) in these four kinds of ginger sample extracts were simultaneously determined by UPLC-PDA. Meanwhile, the antioxidant effect of fresh, dried, stir-frying and carbonized gingers were evaluated by three assays (2,2-diphenyl-1-picrylhydrazyl (DPPH), 2,2'-azinobis(3-ethylbenzthiazolinesulfonic acid) diammonium salt (ABTS), and ferric reducing antioxidant power (FRAP)). The results demonstrated that antioxidant activity of dried ginger was the highest, for its phenolic contents are 5.2-, 1.1- and 2.4-fold higher than that of fresh, stir-frying and carbonized ginger, respectively, the antioxidant activities' results indicated a similar tendency with phenolic contents: dried ginger>stir-frying ginger>fresh ginger>carbonized ginger. The processing contributed to the decreased concentration of gingerols and the increased levels of shogaols, which reducing the antioxidant effects in pace with processing. This study elucidated the relationship of the heating process with the constituents and antioxidant activity, and provided a guide for choosing different kinds of ginger samples on clinical application.

  4. Influence of Stored Strain on Fabricating of Al/SiC Nanocomposite by Friction Stir Processing

    Khorrami, M. Sarkari; Kazeminezhad, M.; Kokabi, A. H.

    2015-05-01

    In this work, 1050 aluminum (Al) sheets were annealed and severely deformed by 1, 2, and 3 passes of constrained groove pressing process to obtain the various initial stored strain values of 0, 1.16, 2.32, and 3.48, respectively. Friction stir processing (FSP) was then applied using SiC nanoparticles to fabricate Al/SiC nanocomposite with approximately 1.5 vol pct reinforced particles. Microstructural examinations revealed that an increase in the initial stored strain of the base metal led to the formation of finer grain structure after 1 pass of FSP. The finer grain structure occurred in the stir zone where a sufficient amount of nanoparticles with a relatively proper distribution existed. However, the initial stored strain value had a contrary influence in the regions with low volume fraction of nanoparticles. In fact, more stored strain in the base metal provided more driving force for both nucleation and grain growth of newly recrystallized grains at the stir zone. Pinning effect of well-distributed nanoparticles could effectively retard grain growth leading to the formation of very fine grain structure. Also it was observed that the initial stored strain values did not have impressive rule in the microstructural evolutions at the stir zone during the second and third FSP passes signifying that all of the stored energy in the base metal would be released after 1 pass of FSP. The results obtained with microhardness measurement at the stir zone were fairly in agreement with those achieved by the microstructure assessments.

  5. TiB{sub 2} reinforced aluminum based in situ composites fabricated by stir casting

    Chen, Fei [Key Laboratory of Materials Modification by Laser, Ion, and Electron Beams (Ministry of Education), School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024 (China); Chen, Zongning [Laboratory of Special Processing of Raw Materials, Dalian University of Technology, Dalian 116024 (China); Mao, Feng [Key Laboratory of Materials Modification by Laser, Ion, and Electron Beams (Ministry of Education), School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024 (China); Wang, Tongmin, E-mail: tmwang@dlut.edu.cn [Key Laboratory of Materials Modification by Laser, Ion, and Electron Beams (Ministry of Education), School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024 (China); Cao, Zhiqiang, E-mail: caozq@dlut.edu.cn [Laboratory of Special Processing of Raw Materials, Dalian University of Technology, Dalian 116024 (China)

    2015-02-11

    In this study, a new technique involving mechanical stirring at the salts/aluminum interface was developed to fabricate TiB{sub 2} particulate reinforced aluminum based in situ composites with improved particle distribution. Processing parameters in terms of stirring intensity, stirring duration and stirring start time were optimized according to the microstructure and mechanical properties evaluation. The results show that, the first and last 15 min of the entire 60 min holding are of prime importance to the particle distribution of the final composites. When applying 180 rpm (revolutions per minute) stirring at the salts/aluminum interface in these two intervals, a more uniform microstructure can be achieved and the Al-4 wt% TiB{sub 2} composite thus produced exhibits superior mechanical performance. Synchrotron radiation X-ray computed tomography (SR-CT) was used to give a full-scale imaging of the particle distribution. From the SR-CT results, the in situ Al–xTiB{sub 2} composites (x=1, 4 and 7, all in wt%) fabricated by the present technique are characterized by fine and clean TiB{sub 2} particles distributed uniformly throughout the Al matrix. These composites not only have higher yield strength (σ{sub 0.2}) and ultimate tensile strength (UTS), but also exhibit superior ductility, with respect to the Al–TiB{sub 2} composites fabricated by the conventional process. The σ{sub 0.2} and UTS of the Al–7TiB{sub 2} composite in the present work, are 260% and 180% higher than those of the matrix. A combined mechanism was also presented to interpret the improvements in yield strength of the composites as influenced by their microstructures and processing history. The predicted values are in good agreement with the experimental results, strongly supporting the strengthening mechanism we proposed. Fractography reveals that the composites thus fabricated, follow ductile fracture mechanism in spite of the presence of stiff reinforcements.

  6. Protein crystallization in stirred systems--scale-up via the maximum local energy dissipation.

    Smejkal, Benjamin; Helk, Bernhard; Rondeau, Jean-Michel; Anton, Sabine; Wilke, Angelika; Scheyerer, Peter; Fries, Jacqueline; Hekmat, Dariusch; Weuster-Botz, Dirk

    2013-07-01

    Macromolecular bioproducts like therapeutic proteins have usually been crystallized with µL-scale vapor diffusion experiments for structure determination by X-ray diffraction. Little systematic know-how exists for technical-scale protein crystallization in stirred vessels. In this study, the Fab-fragment of the therapeutic antibody Canakinumab was successfully crystallized in a stirred-tank reactor on a 6 mL-scale. A four times faster onset of crystallization of the Fab-fragment was observed compared to the non-agitated 10 µL-scale. Further studies on a liter-scale with lysozyme confirmed this effect. A 10 times faster onset of crystallization was observed in this case at an optimum stirrer speed. Commonly suggested scale-up criteria (i.e., minimum stirrer speed to keep the protein crystals in suspension or constant impeller tip speed) were shown not to be successful. Therefore, the criterion of constant maximum local energy dissipation was applied for scale-up of the stirred crystallization process for the first time. The maximum local energy dissipation was estimated by measuring the drop size distribution of an oil/surfactant/water emulsion in stirred-tank reactors on a 6 mL-, 100 mL-, and 1 L-scale. A comparable crystallization behavior was achieved in all stirred-tank reactors when the maximum local energy dissipation was kept constant for scale-up. A maximum local energy dissipation of 2.2 W kg(-1) was identified to be the optimum for lysozyme crystallization at all scales under study.

  7. Monoterpenoid oxindole alkaloid production by Uncaria tomentosa (Willd) D.C. cell suspension cultures in a stirred tank bioreactor.

    Trejo-Tapia, Gabriela; Cerda-García-Rojas, Carlos M; Rodríguez-Monroy, Mario; Ramos-Valdivia, Ana C

    2005-01-01

    Cell growth, monoterpenoid oxindole alkaloid (MOA) production, and morphological properties of Uncaria tomentosa cell suspension cultures in a 2-L stirred tank bioreactor were investigated. U. tomentosa (cell line green Uth-3) was able to grow in a stirred tank at an impeller tip speed of 95 cm/s (agitation speed of 400 rpm), showing a maximum biomass yield of 11.9 +/- 0.6 g DW/L and a specific growth rate of 0.102 d(-1). U. tomentosa cells growing in a stirred tank achieved maximum volumetric and specific MOA concentration (467.7 +/- 40.0 microg/L, 44.6 +/- 5.2 microg/g DW) at 16 days of culture. MOA chemical profile of cell suspension cultures growing in a stirred tank resembled that of the plant. Depending on culture time, from the total MOA produced, 37-100% was found in the medium in the bioreactor culture. MOA concentration achieved in a stirred tank was up to 10-fold higher than that obtained in Erlenmeyer flasks (agitated at 110 rpm). In a stirred tank, average area of the single cells of U. tomentosa increased up to 4-fold, and elliptical form factor increased from 1.40 to 2.55, indicating enlargement of U. tomentosa single cells. This work presents the first report of U. tomentosa green cell suspension cultures that grow and produce MOA in a stirred tank bioreactor.

  8. Mechanical Properties and Microstructure of Dissimilar Friction Stir Welds of 11Cr-Ferritic/Martensitic Steel to 316 Stainless Steel

    Sato, Yutaka S.; Kokawa, Hiroyuki; Fujii, Hiromichi T.; Yano, Yasuhide; Sekio, Yoshihiro

    2015-12-01

    Dissimilar joints between ferritic and austenitic steels are of interest for selected applications in next generation fast reactors. In this study, dissimilar friction-stir welding of an 11 pct Cr ferritic/martensitic steel to a 316 austenitic stainless steel was attempted and the mechanical properties and microstructure of the resulting welds were examined. Friction-stir welding produces a stir zone without macroscopic weld-defects, but the two dissimilar steels are not intermixed. The two dissimilar steels are interleaved along a sharp zigzagging interface in the stir zone. During small-sized tensile testing of the stir zone, this sharp interface did not act as a fracture site. Furthermore, the microstructure of the stir zone was refined in both the ferritic/martensitic steel and the 316 stainless steel resulting in improved mechanical properties over the adjacent base material regions. This study demonstrates that friction-stir welding can produce welds between dissimilar steels that contain no macroscopic weld-defects and display suitable mechanical properties.

  9. Characterization of a continuous agitated cell reactor for oxygen dependent biocatalysis

    Pedersen, Asbjørn Toftgaard; Teresa de Melo Machado Simoes Carvalho, Ana; Sutherland, Euan

    2017-01-01

    for the ACR was developed. The model consisted of ten tanks-in-series with back-mixing occurring within and between each cell. The back-mixing was a necessary addition to the model in order to explain the observed phenomenon that the ACR behaved as two continuous stirred tank reactors (CSTRs) at low flow...... rates, while it at high flow rates behaved as the expected ten CSTRs in series. The performance of the ACR was evaluated by comparing the steady state conversion at varying residence times with the conversion observed in a stirred batch reactor of comparable size. It was found that the ACR could more......Biocatalytic oxidation reactions employing molecular oxygen as the electron acceptor are difficult to conduct in a continuous flow reactor because of the requirement for high oxygen transfer rates. In this paper, the oxidation of glucose to glucono-1,5-lactone by glucose oxidase was used as a model...

  10. The effect of postprocessing on tensile property and microstructure evolution of friction stir welding aluminum alloy joint

    Hu, Z.L., E-mail: zhilihuhit@163.com [Hubei Key Laboratory of Advanced Technology of Automobile Parts, Wuhan University of Technology, Wuhan 430070 (China); State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); State Key Laboratory of Materials Processing and Die & Mould Technology, Huazhong University of Science and Technology (China); Wang, X.S. [State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China); Pang, Q. [School of Mechanical and Electrical Engineering, Wuhan Donghu University, Wuhan 430070 (China); Huang, F.; Qin, X.P.; Hua, L. [Hubei Key Laboratory of Advanced Technology of Automobile Parts, Wuhan University of Technology, Wuhan 430070 (China)

    2015-01-15

    Friction stir welding is an efficient manufacturing method for joining aluminum alloy and can dramatically reduce grain size conferring excellent plastic deformation properties. Consequently, friction stir welding is used to manufacture tailor welded blanks to optimize weight or performance in the final component. In the study, the microstructural evolution and mechanical properties of friction stir welding joint during plastic forming and subsequent heat treatment were investigated. The microstructural characteristics of the friction stir welding joints were studied by Electron Backscattered Diffraction and Transmission Electron Microscopy. The mechanical properties were evaluated by tensile and microhardness tests. It is found that the tensile and yield strengths of friction stir welding joints are significantly improved after severe plastic deformation due to the grain refinement. Following heat treatment, the strength of the friction stir welding joints significantly decrease due to the obvious abnormal grain growth. Careful attention must be given to the processing route of any friction stir welding joint intended for plastic forming, especially the annealing between forming passes. Severe plastic deforming of the friction stir welding joint leads to a high level of stored energy/dislocation density, which causes the abnormal grain growth during subsequent heat treatment, and consequently reduce the mechanical properties of the friction stir welding joint. - Highlights: • Great changes are observed in the microstructure of FSW joint after postprocessing. • Postprocessing shows great effect on the microstructure stability of FSW joint. • The weld shows more significant decrease in strength than the BM due to the AGG. • Attention must be given to the processing route of FSW joint for plastic forming.

  11. 脱水污泥厌氧发酵搅拌动力需求试验研究%Experimental Study on Power Requirements for Stirring in Dewatered Sludge Anaerobic Digestion

    盛金良; 严敏东; 赵志永; 龚莹

    2012-01-01

    对于含固率较高的脱水污泥厌氧发酵系统,对物料的搅拌是能耗的重要组成部分,而目前对发酵工艺中机械搅拌动力需求的研究几乎没有.研制了一台卧式强制搅拌干式厌氧发酵反应器,对叶片搅拌过程进行受力分析,计算出理论搅拌扭矩,并以此反应器为基础,研究了污水处理厂脱水污泥的搅拌动力需求.具体研究了污泥的含固率、搅拌转速、反应器填充率等因素对搅拌动力需求的影响,发现低转速下,转速对搅拌扭矩影响非常小,而从搅拌动力需求角度考虑,物料填充率在66.7%~85%之间比较合理.同时还对长期连续搅拌状态下污泥所需的搅拌动力的变化做了研究,发现经过搅拌污泥的内摩擦角和粘聚力出现了较大的变化,从而引起搅拌所需动力在短时间内大幅降低.而原污泥兑水使含固率降低、自由水含量增加时,其搅拌动力需求呈指数趋势减小.%Stirring takes an essential part in energy consumption in an anaerobic digestion system of dewatered sludge with high solids, but little relative research about power requirements for stirring has been done. A horizontal continuous stirred tank reactor for high solids anaerobic digestion were built to study the influence of power requirement brought by sludge solids content, stirring speed and reactor fill level. Force analysis of mixing arms were done and theoretical torsion needs for stirring obtained. Experiments results indicated that changing stirring speed has little effect on power requirements, and the fill level kept between 66.7% and 85% is more reasonable from energy point of view. Some studies were done for dynamic change of power requirement in long-term continuous stirring, showing that the power needs for stirring decline rapidly due to the substantial changes in internal friction angle and cohesive force. The torsion requirements decrease exponentially by adding free water into the sludge.

  12. CONTINUOSLY STIRRED TANK REACTOR PARAMETERS THAT AFFECT SLUDGE BATCH 6 SIMULANT PROPERTIES

    Newell, J.; Lambert, D.; Stone, M.; Fernandez, A.

    2010-05-28

    The High Level Radioactive Waste (HLW) Sludge in Savannah River Site (SRS) waste tanks was produced over a period of over 60 years by neutralizing the acidic waste produced in the F and H Separations Canyons with sodium hydroxide. The HLW slurries have been stored at free hydroxide concentrations above 1 M to minimize the corrosion of the carbon steel waste tanks. Sodium nitrite is periodically added as a corrosion inhibitor. The resulting waste has been subjected to supernate evaporation to minimize the volume of the stored waste. In addition, some of the waste tanks experienced high temperatures so some of the waste has been at elevated temperatures. Because the waste is radioactive, the waste is transforming through the decay of shorter lived radioactive species and the radiation damage that the decay releases. The goal of the Savannah River National Laboratory (SRNL) simulant development program is to develop a method to produce a sludge simulant that matches both the chemical and physical characteristics of the HLW without the time, temperature profile, chemical or radiation exposure of that of the real waste. Several different approaches have been taken historically toward preparing simulated waste slurries. All of the approaches used in the past dozen years involve some precipitation of the species using similar chemistry to that which formed the radioactive waste solids in the tank farm. All of the approaches add certain chemical species as commercially available insoluble solid compounds. The number of species introduced in this manner, however, has varied widely. All of the simulant preparation approaches make the simulated aqueous phase by adding the appropriate ratios of various sodium salts. The simulant preparation sequence generally starts with an acidic pH and ends up with a caustic pH (typically in the 10-12 range). The current method for making sludge simulant involves the use of a temperature controlled continuously stirred tank reactor (CSTR

  13. Influence of glucose and stirring in the fermentation process in order to produce anti- Candida metabolites produced by Streptomyces sp.

    Silvia Katrine Silva Escher

    Full Text Available ABSTRACT This study evaluated the influence of glucose and stirring in the fermentation process in order to produce anti-Candida metabolites produced by Streptomyces sp. MPO4 isolated from Amazon soil. The anti-Candida metabolites production was registered after 24 h of fermentation in stirred ISP2 medium, having antifungal inhibition halos between 12.3 mm and 25.3 mm, yielding higher production of anti-Candida agents after 96 h. Stirring was a determining factor for the production of anti-Candida secondary metabolites, since the absence of glucose reflected in the late production of the antifungal starting from Streptomyces sp.

  14. Distribution of SiCp in Al and Al-Cu Alloy Centrifugally Cast with Electromagnetic Stirring

    Weiqiang ZHANG; Haifang SHI; Huameng FU

    2004-01-01

    The SiCp/(Al-Cu) alloy and pure Al matrix composites have been prepared by the centrifugal casting with electromagnetic stirring. There are two particle-depleted zones formed in the samples without electro-magnetic stirring.Electromagnetic stirring may result in a homogeneous distribution of fine SiC particles in the Al-Cu alloy, whereas it has little effect on the segregation in pure Al matrix. The results also show that the particle segregation is influenced by particle size and the coarse particles are more readily segregated than the fine ones.

  15. Combustion of n-heptane in a shock tube and in a stirred reactor: A detailed kinetic modeling study

    Gaffuri, P.; Curran, H.J.; Pitz, W.J.; Westbrook, C.K.

    1995-04-13

    A detailed chemical kinetic reaction mechanism is used to study the oxidation of n-heptane under several classes of conditions. Experimental results from ignition behind reflected shock waves and in a rapid compression machine were used to develop and validate the reaction mechanism at relatively high temperatures, while data from a continuously stirred tank reactor (cstr) were used to refine the low temperature portions of the reaction mechanism. In addition to the detailed kinetic modeling, a global or lumped kinetic mechanism was used to study the same experimental results. The lumped model was able to identify key reactions and reaction paths that were most sensitive in each experimental regime and provide important guidance for the detailed modeling effort. In each set of experiments, a region of negative temperature coefficient (NTC) was observed. Variation in pressure from 5 to 40 bars were found to change the temperature range over which the NTC region occurred. Both the lumped and detailed kinetic models reproduced the measured results in each type of experiments, including the features of the NTC region, and the specific elementary reactions and reaction paths responsible for this behavior were identified and rate expressions for these reactions were determined.

  16. Texture Evolution within the Thermomechanically Affected Zone of an Al-Li Alloy 2195 Friction Stir Weld

    Tayon, Wesley A.; Domack, Marcia S.; Hoffman, Eric K.; Hales, Stephen J.

    2013-11-01

    Friction stir welding (FSW) of Al -Li alloy 2195 plate produces strong texture gradients. The microstructural characteristics evolve from the base plate, through the thermomechanically affected zone (TMAZ), to the weld nugget interface. In the current study, electron backscattered diffraction (EBSD) analyses were employed to quantify the spatial distribution of texture gradients associated with the evolution of texture within the TMAZ. The strong texture of the base plate enabled the texture evolution to be characterized as a function of location. Systematic partitioning of EBSD data relative to the degree of lattice rotation at each point accurately captured the crystallographic transitions across the advancing side TMAZ. Over a large section of this region, the texture evolves as a result of continuous rigid body rotations. The rigid body rotations were correlated with the complex material flow patterns commonly associated with the FSW process and prior observations of shear-related textures. Finally, a correlation between texture and fracture in a subscale tensile specimen is observed, where failure occurs within a visible band of low-Taylor factor grains.

  17. Friction stir welding process and material microstructure evolution modeling in 2000 and 5000 series of aluminum alloy

    Yalavarthy, Harshavardhan

    Interactions between the rotating and advancing pin-shaped tool (terminated at one end with a circular-cylindrical shoulder) with the clamped welding-plates and the associated material and heat transport during a Friction Stir Welding (FSW) process are studied computationally using a fully-coupled thermo-mechanical finite-element analysis. To surmount potential numerical problems associated with extensive mesh distortions/entanglement, an Arbitrary Lagrangian Eulerian (ALE) formulation was used which enabled adaptive re-meshing (to ensure the continuing presence of a high-quality mesh) while allowing full tracking of the material free surfaces. To demonstrate the utility of the present computational approach, the analysis is applied to the cases of same-alloy FSW of two Aluminum-alloy grades: (a) AA5083 (a solid-solution strengthened and strain-hardened/stabilized Al-Mg-Mn alloy); and (b) AA2139 (a precipitation hardened quaternary Al-Cu-Mg-Ag alloy). Both of these alloys are currently being used in military-vehicle hull structural and armor systems. In the case of non-age-hardenable AA5083, the dominant microstructure evolution processes taking place during FSW are extensive plastic deformation and dynamic recrystallization of highly-deformed material subjected to elevated temperatures approaching the melting temperature. To account for the competition between plastic-deformation controlled strengthening and dynamic-recrystallization induced softening phenomena during the FSW process, the original Johnson-Cook strain- and strain-rate hardening and temperature-softening material strength model is modified in the present work using the available recrystallization-kinetics experimental data. In the case of AA2139, in addition to plastic deformation and dynamic recrystallization, precipitates coarsening, over-aging, dissolution and re-precipitation had to be also considered. Limited data available in the open literature pertaining to the kinetics of the aforementioned

  18. Modeling the Effects of Tool Shoulder and Probe Profile Geometries on Friction Stirred Aluminum Welds Using Response Surface Methodology

    H.K.Mohanty; M.M.Mahapatra; P.Kumar; P.Biswas; N.R.Mandal

    2012-01-01

    The present paper discusses the modeling of tool geometry effects on the friction stir aluminum welds using response surface methodology.The friction stir welding tools were designed with different shoulder and tool probe geometries based on a design matrix.The matrix for the tool designing was made for three types of tools,based on three types of probes,with three levels each for defining the shoulder surface type and probe profile geometries.Then,the effects of tool shoulder and probe geometries on friction stirred aluminum welds were experimentally investigated with respect to weld strength,weld cross section area,grain size of weld and grain size of thermo-mechanically affected zone.These effects were modeled using multiple and response surface regression analysis.The response surface regression modeling were found to be appropriate for defining the friction stir weldment characteristics.

  19. Effect of ultrasonic stirring on temperature distribution and grain refinement in Al- 1.65% Si alloy melt

    2007-01-01

    A series of experiments were conducted for Al-1.65%Si (mass fraction) alloy melt to study the formation of grain refining structure with ultrasonic stirring. The cooling curves of ingots with ultrasonic were measured and compared with those without ultrasonic. At the same time, the effect of the time of ultrasonic stirring on solidification structure of ingots was investigated. The influence of ultrasonic on the grain-refining efficiency of ingots was analyzed. In order to well understand the melts behavior under ultrasonic, by using ammonium chloride solution, the simulation experiment was carried out and the temperature distribution in ingot with or without ultrasonic was compared. The results indicate that the ultrasonic reduces the temperature inhomogeneity of melt, i.e.the ultrasonic helps to homogenize the melt temperature. The effect of stirring and heat generation in ingot start to occur with increasing the time of ultrasonic stirring.

  20. Structure and Properties of Thick-Walled Joints of Alloy 1570s Prepared by Friction Stir Welding

    Velichko, O. V.; Ivanov, S. Yu.; Karkhin, V. A.; Lopota, V. A.; Makhin, I. D.

    2016-09-01

    The microstructure and mechanical properties of thick-walled joints of Al - Mg - Sc alloy 1570S, prepared by friction stir welding are studied. Joint microstructural and mechanical inhomogeneity are revealed.