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Sample records for 2-methylpropene

  1. Improved direct production of 2,3-dimethylbutenes and 3,3-dimethylbutene from 2-methylpropene on tungsten hydride based catalysts

    KAUST Repository

    Garron, Anthony

    2012-01-01

    2-Methylpropene in the presence of W-H/Ni 1%-Al 2O 3-(500) is transformed in high selectivity into a mixture of 2,3-dimethylbutenes (2,3-DMBs = DMB-1 and DMB-2) and neohexene. 2,3-DMBs arise from the unfavoured 2-methylpropene self-metathesis reaction whereas the neohexene originates from a cascade reaction: 2-methylpropene dimerisation followed by cross metathesis. © 2012 The Royal Society of Chemistry.

  2. An investigation of the electronic structure of some 3-monosubstituted-2-methylpropenes through computational chemistry and photoelectron spectroscopy

    Science.gov (United States)

    Schuquel, Ivânia T. A.; Ducati, Lucas C.; Custodio, Rogério; Rittner, Roberto; Klapstein, Dieter

    2008-06-01

    The photoelectron (PE) spectra of some 3-monosubstituted 2-methylpropenes H 2C dbnd C(CH 3)CH 2X [X = Cl, Br, I, OH, OMe, OEt, SH, SMe, SEt, N(Me) 2 and N(Et) 2] have been recorded. A preliminary analysis is presented indicating some trends in the ionization potentials associated with application of OVGF method and NBO analysis from MP2/6-31G(d,p) and cc-pVDZ level of theory indicating that the more effective hyperconjugation effect leads to the most stable conformers. The sensitivity of the outermost ionization energies of selected molecules with respect to the level of theory was analyzed. Application of the CASPT2 method with ANO basis set and geometries from MP2 calculations provided results in excellent agreement with the experimental data.

  3. C2-C10 hydrocarbon emissions from a boreal wetland and forest floor

    Directory of Open Access Journals (Sweden)

    H. Hellén

    2006-01-01

    Full Text Available Emissions of various C2-C10 hydrocarbons (VOCs and halogenated hydrocarbons (VHOCs from a boreal wetland and a Scots pine forest floor in south-western Finland were measured by the static chamber technique. Isoprene was the main non-methane hydrocarbon emitted by the wetland, but small emissions of ethene, propane, propene, 1-butene, 2-methylpropene, butane, pentane and hexane were also detected. The isoprene emission from the wetland was observed to follow the commonly-used isoprene emission algorithm. The mean emission potential of isoprene was 224 µg m-2 h-1 for the whole season. This is lower than the emission potentials published earlier; that is probably at least partly due to the cold and cloudy weather during the measurements. No emissions were detected of monoterpenes or halogenated hydrocarbons from the wetland. The highest hydrocarbon emissions from the Scots pine forest floor were measured in spring and autumn. However, only a few measurements were conducted during summer. The main compounds emitted were monoterpenes. Isoprene emissions were negligible. The total monoterpene emission rates varied from zero to 373 µg m-2 h-1. The results indicated that decaying plant litter may be the source for these emissions. Small emissions of chloroform (100-800 ng m-2 h-1, ethene, propane, propene, 2-methylpropene, cis-2-butene, pentane, hexane and heptane were detected. Comparison with Scots pine emissions showed that the forest floor may be an important monoterpene source, especially in spring.

  4. Biogenic Emissions of Light Alkenes from a Coniferous Forest

    Science.gov (United States)

    Rhew, R. C.; Turnipseed, A. A.; Martinez, L.; Shen, S.; De Gouw, J. A.; Warneke, C.; Koss, A.; Lerner, B. M.; Miller, B. R.; Smith, J. N.; Guenther, A. B.

    2014-12-01

    Alkenes are reactive hydrocarbons that play important roles in the photochemical production of tropospheric ozone and in the formation of secondary organic aerosols. The light alkenes (C2-C4) originate from both biogenic and anthropogenic sources and include C2H4 (ethene), C3H6 (propene) and C4H8 (1-butene, 2-butene, 2-methylpropene). Light alkenes are used widely as chemical feedstocks because their double bond makes them versatile for industrial reactions. Their biogenic sources are poorly characterized, with most global emissions estimates relying on laboratory-based studies; net ecosystem emissions have been measured at only one site thus far. Here we report net ecosystem fluxes of light alkenes and isoprene from a semi-arid ponderosa pine forest in the Rocky Mountains of Colorado, USA. Canopy scale fluxes were measured using relaxed eddy accumulation (REA) techniques on the 28-meter NCAR tower in the Manitou Experimental Forest Observatory. Updrafts and downdrafts were determined by sonic anemometry and segregated into 'up' and 'down' reservoirs over the course of an hour. Samples were then measured on two separate automated gas chromatographs (GCs). The first GC measured light hydrocarbons (C2-C6 alkanes and C2-C5 alkenes) by flame ionization detection (FID). The second GC measured halocarbons (methyl chloride, CFC-12, and HCFC-22) by electron capture detection (ECD). Additional air measurements from the top of the tower included hydrocarbons and their oxidation products by Proton Transfer Reaction Mass Spectrometry (PTR-MS). Three field intensives were conducted during the summer of 2014. The REA flux measurements showed that ethene, propene and the butene emissions have significant diurnal cycles, with maximum emissions at midday. The light alkenes contribute significantly to the overall biogenic source of reactive hydrocarbons and have a temporal variability that may be associated with physical and biological parameters. These ecosystem scale measurements

  5. NTP Toxicology and Carcinogenesis Studies of Isobutene (CAS No. 115-11-7) in F344/N Rats and B6C3F1 Mice (Inhalation Studies).

    Science.gov (United States)

    1998-12-01

    was measured in the urine of male and female mice as an indicator of isobutene exposure at 6, 12t 6, 12,and 18 months. The amount of HIBA excreted increased with increasing exposure concentration. However, when HIBA concentration was normalized to isobutene exposure concentration, the relative amount of HIBA excreted decreased with increasing exposure concentration, implying nonlinear kinetics. Pathology Findings: The incidences of hyaline degeneration of the respiratory epithelium in all groups of exposed males and females were significantly greater than those in the chamber control groups. The incidences of hyaline degeneration of the olfactory epithelium in 2,000 and 8,000 ppm mice were greater than those in the chamber controls. GENETIC TOXICOLOGY: Isobutene was not mutagenic in any of four strains of S. typhimurium, with or without S9 metabolic activation, and no increase in the frequency of micronucleated erythrocytes was seen in peripheral blood of male or female mice treated with isobutene by inhalation for 14 weeks. CONCLUSIONS: Under the conditions of these 2-year inhalation studies, there was some evidence of carcinogenic activity of isobutene in male F344/N rats based on an increased incidence of follicular cell carcinoma of the thyroid gland. There was no evidence of carcinogenic activity of isobutene in female F344/N rats or male or female B6C3F1 mice exposed to 500, 2,000, or 8,000 ppm. Exposure to isobutene by inhalation for 2 years resulted in increased incidences and/or severities of nasal lesions including hyaline degeneration of the olfactory epithelium in male and female rats and mice and hyaline degeneration of the respiratory epithelium in male and female mice. Synonyms: Isobutylene, 2-methylpropene, liquified petroleum gas, g-butylene.