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Sample records for 16mnd5 steel influence

  1. A micro-mechanical analysis and an experimental characterisation of the behavior and the damaging processes of a 16MND5 pressure vessel steel at low temperature; Etude micromecanique et caracterisation experimentale du comportement et de l'endommagement de l'acier de cuve 16MND5 a basses temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Pesci, R

    2004-06-15

    As part of an important experimental and numerical research program launched by Electricite De France on the 16MND5 pressure vessel steel, sequenced and in-situ tensile tests are realized at low temperatures [-196 C;-60 C]. They enable to associate the observation of specimens, the complete cartography of which has been made with a scanning electron microscope (damaging processes, initiation and propagation of microcracks), with the stress states determined by X-ray diffraction, in order to establish relevant criteria. All these measurements enable to supply a two-scale polycrystalline modeling of behavior and damage (Mori-Tanaka/self-consistent) which is developed concurrently with the experimental characterization. This model proves to be a very efficient one, since it correctly reproduces the influence of temperature experimentally defined: the stress state in ferrite remains less important than in bainite (the difference never exceeds 150 MPa), whereas it is much higher in cementite. The heterogeneity of strains and stresses for each crystallographic orientation is well rendered; so is cleavage fracture normal to the {l_brace}100{r_brace} planes in ferrite (planes identified by electron back scattered diffraction during an in-situ tensile test at -150 C), which occurs sooner when temperature decreases, for a constant stress of about 700 MPa in this phase. (author)

  2. Micro-mechanical analysis and modelling of the behavior and brittle fracture of a french 16MND5 steel: role of microstructural heterogeneities; Analyse et modelisation micromecanique du comportement et de la rupture fragile de l'acier 16MND5: prise en compte des heterogeneites microstructurales

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    Mathieu, J.Ph

    2006-10-15

    Reactor Pressure Vessel is the second containment barrier between nuclear fuel and the environment. Electricite de France's reactors are made with french 16MND5 low-alloyed steel (equ. ASTM A508 Cl.3). Various experimental techniques (scanning electron microscopy, X-ray diffraction...) are set up in order to characterize mechanical heterogeneities inside material microstructure during tensile testing at different low temperatures [-150 C;-60 C]. Heterogeneities can be seen as the effect of both 'polycrystalline' and 'composite' microstructural features. Interphase (until 150 MPa in average between ferritic and bainitic macroscopic stress state) and intra-phase (until 100 MPa in average between ferritic orientations) stress variations are highlighted. Modelling involves micro-mechanical description of plastic glide, mean fields models and realistic three-dimensional aggregates, all put together inside a multi-scale approach. Calibration is done on macroscopic stress-strain curves at different low temperatures, and modelling reproduces experimental stress heterogeneities. This modelling allows to apply a local micro-mechanical fracture criterion for crystallographic cleavage. Deterministic computations of time to fracture for different carbides random selection provide a way to express probability of fracture for the elementary volume. Results are in good agreement with hypothesis made by local approach to fracture. Hence, the main difference is that no dependence to loading nor microstructure features is supposed for probability of fracture on the representative volume: this dependence is naturally introduced by modelling. (author)

  3. Numerical modelling of Charpy-V notch test by local approach to fracture. Application to an A508 steel in the ductile-brittle transition range; Modelisation de l'essai Charpy par l'approche locale de la rupture. Application au cas de l'acier 16MND5 dans le domaine de transition

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    Tanguy, B

    2001-07-15

    Ferritic steels present a transition of the rupture mode which goes progressively of a brittle rupture (cleavage) to a ductile rupture when the temperature increases. The following of the difference of the transition temperature of the PWR vessel steel by the establishment of toughness curves makes of the Charpy test an integrating part of the monitoring of the French PWR reactors. In spite of the advantages which are adapted to it in particular its cost, the Charpy test does not allow to obtain directly a variable which characterizes a crack propagation resistance as for instance the toughness used for qualifying the mechanical integrity of a structure. This work deals with the establishment of the through impact strength-toughness in the transition range of the vessel steel: 16MND5 from a non-empirical approach based on the local approach of the rupture. The brittle rupture is described by the Beremin model (1983), which allows to describe the dispersion inherent in this rupture mode. The description of the brittle fissure is carried out by the GTN model (1984) and by the Rousselier model (1986). This last model has been modified in order to obtain a realistic description of the brittle damage in the case of fast solicitations and of local heating. The method proposed to determine the parameters of the damage models depends only of tests on notched specimens and of the inclusion data of the material. The behaviour is described by an original formulation parametrized in temperature which allows to describe all the tests carried out in this study. Before using this methodology, an experimental study of the behaviour and of the rupture modes of the steel 16MND5 has been carried out. From the toughness tests carried out in quasi-static and dynamical conditions, it has been revealed that this steel does not present important unwedging of its toughness curve due to the velocity effect. In the transition range, local heating of about 150 C have been measured in the root

  4. Ferrite content in austenitic stainless steel cladding of nuclear power components%核电设备不锈钢堆焊层的铁素体含量

    Institute of Scientific and Technical Information of China (English)

    左波; 余燕; 张茂龙

    2012-01-01

    The ferrite contents date determined by chemical analysis and by magnetic method was different and the welding procedure parameters and the PWHT (post weld heat treatment) should influence the ferrite contents in the stainless steel cladding of nuclear power plants. In this paper, a series of tests that clad 309L+ 308L on 16MND5 low alloy steel were performed. The results showed that the difference of ferrite contents determined by magnetic method and chemical analysis. The increasing of interpass temperature and welding current led to the decreasing of ferrite contents in the cladding. The PWHT decreased the ferrite contents. Moreover, the rising of PWHT temperature and the expanding of PWHT holding time led to the further deceasing of ferrite contents. The research was significant for the design and manufacture of nuclear components.%针对化学分析法和磁性法测得的核电设备不锈钢堆焊层铁素体含量的差异,以及焊接工艺参数和焊后热处理对铁素体含量的影响规律,采用3种焊接方法在16MND5低合金钢上堆焊309L+308L进行试验研究.结果表明:磁性法和化学分析法得到的铁素体含量数据之间存在一定的差距;道间温度和焊接电流的提高会使铁素体含量降低;焊后热处理会降低铁素体含量,热处理温度提高和热处理时间的延长会使铁素体含量进一步降低.

  5. Characterization of PWR vessel steel tearing under severe accident condition temperatures

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    Matheron, Philippe, E-mail: philippe.matheron@cea.fr [CEA, DEN, DM2S, SEMT, F-91191 Gif-sur-Yvette (France); Chapuliot, Stephane, E-mail: stephane.chapuliot@cea.fr [CEA, DEN, DM2S, SEMT, F-91191 Gif-sur-Yvette (France); Nicolas, Laetitia, E-mail: laetitia.nicolas@cea.fr [CEA, DEN, DM2S, SEMT, F-91191 Gif-sur-Yvette (France); Laboratoire de Mecanique des Structures Industrielles Durables, UMR CNRS-EDF 2832, 1 avenue du General de Gaulle, F-92141 Clamart (France); Koundy, Vincent, E-mail: vincent.koundy@irsn.fr [IRSN-DSR, Service d' evaluation des Accidents Graves et des Rejets radioactifs B.P. 17, 92262 Fontenay-aux-Roses Cedex (France); Caroli, Cataldo, E-mail: cataldo.caroli@irsn.fr [IRSN-DSR, Service d' evaluation des Accidents Graves et des Rejets radioactifs B.P. 17, 92262 Fontenay-aux-Roses Cedex (France)

    2012-01-15

    to different types of rupture behaviour at high temperatures. The experimental programme has been conducted on various French RPV 16MND5 steels for temperatures ranging from 900 Degree-Sign C to 1100 Degree-Sign C. Comparisons between the tests performed on these various 16MND5 steels show that this approach is appropriate to characterize the difference in ductility observed at high temperatures. The aim of this experimental study is also to contribute to the definition of a tearing criterion by identifying, on the basis of CT results, the related material parameters at temperatures representative of the real severe accident conditions. This experimental campaign has been carried out in partnership with IRSN in the framework of a research programme whose purpose is to complete the mechanical properties database of 16MND5 steel and to model tearing failure in French RPV lower head vessels under severe conditions ().

  6. Influence of the steel scrap classes on the liquid steel output molten in electric steel processes

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    K. Janiszewski

    2012-12-01

    Full Text Available Purpose: This is why we have analysed in the paper, using statistical analysing methods, the influence of use in the electric arc furnace charges of steel scrap of different qualities on the index of liquid steel output from a melt.Design/methodology/approach: The used research methodology consists in analytical simulation of variations in mass of liquid steel obtained from melts differing in steel scrap content in the metallic charge and statistical analyses of industrial results acquired from the corresponding process documentation (so called melt cards.Findings: Basing on the analytical and statistical analyses carried out we have determine resulting variations in the liquid steel per melt ratios depending on the content of steel scrap in the metallic charge.Research limitations/implications: The research results obtained can be utilized in each steelmaking facility, which employs the Electric Steelmaking process, in order to “design” the metallic charge compositions, having in view the quality and economic aspects.Practical implications: The research results presented in the paper can be used for steel production of high purity steels.Originality/value: The results presented in this paper are directed to the steelmakers employing the Electric Steelmaking process and constitute the authors’ original study.

  7. Influence of Blowing of Argon on the Cleanness of Steel

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    Pribulová A.

    2012-09-01

    Full Text Available The mechanical properties of steel components are controlled by the chemical composition and mechanical treatment to which the steel is submitted. Non-metallic inclusions have a very high influence on the steel quality but secondary metallurgy enables to reduce their content in the steel. Possibilities of secondary metallurgy are relatively extensive but financial situation in Slovak foundries does not enable to make investments in secondary metallurgy in the near future. Accessible means for influencing of steel quality is injection of an inert gas.

  8. Influence of Blowing of Argon on the Cleanness of Steel

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    A. Pribulová

    2012-09-01

    Full Text Available The mechanical properties of steel components are controlled by the chemical composition and mechanical treatment to which thesteel is submitted. Non-metallic inclusions have a very high influence on the steel quality but secondary metallurgy enables to reduce their content in the steel. Possibilities of secondary metallurgy are relatively extensive but financial situation in Slovak foundries does not enable to make investments in secondary metallurgy in the near future. Accessible means for influencing of steel quality is injection of an inert gas .Main goal of experiments described in the article was verify the influence of blowing of argon into the steel in an electric inductionfurnace on its cleanness. Duration and flow-rate of argon blowing have a very clearly influence on the final content of non-metallicinclusions. Minimum time of argon blowing necessary for reducing of content of non-metallic inclusions in one tonne electric inductionfurnace was more then 6 minutes and recommended argon flow rate was 10 litters per minute.

  9. The Influence of Niobium on SSC Resistance in API Steels

    Energy Technology Data Exchange (ETDEWEB)

    Malina, J.; Malina, M.; Novosel-Radovic, V. [Zagreb Univ., Faculty of Metallurgy (Croatia)

    2004-07-01

    Full text of publication follows: Oil country tubular goods are often exposed to aggressive sour environments in oil wells where H{sub 2}S promotes sulfide stress cracking, SSC. This is one of the most dangerous corrosion phenomena characterized by unpredictable and sudden cracking of steel constructions in service. SSC results in a variety of fracture features having a common relationship to the presence of hydrogen in metal and therefore it belongs to hydrogen embrittlement phenomena, HE. For the production of sulfide stress cracking resistant (SSC) tubing from steels included in Group 3 of API Specification 5CT, in this study two experimental Cr-Mo steels (without niobium and with niobium microalloyed) were tested. The influence of Nb precipitates in pipeline steels on the sensitivity to sulfide stress cracking was examined in laboratory experiments using three point bent beam tests. High mechanical properties were achieved through quenching and tempering procedures. Better corrosion resistance of Nb-containing steel is the consequence of microstructural parameters obtained through strengthening mechanism with microalloying element. Besides the usual mechanical, metallographic, SEM and TEM analyses, as complementary method the X-ray diffraction was used. It was revealed that tetragonality of crystal lattice, dislocation density and residual stresses are in good correlation with Sc-vales from corrosion tests. Nb precipitates (especially niobium carbides) have beneficial influence when producing the steels with low sensitivity to SSC. (authors)

  10. Monitoring Techniques for Microbially Influenced Corrosion of Carbon Steel

    DEFF Research Database (Denmark)

    Hilbert, Lisbeth Rischel

    2000-01-01

    Abstract Monitoring Techniques for Microbially Influenced Corrosion of Carbon Steel Microbially influenced corrosion (MIC) of carbon steel may occur in media with microbiological activity of especially sulphate-reducing bacteria, e.g. on pipelines buried in soil and on marine structures. MIC...... of carbon steel must be monitored on-line in order to provide an efficient protection and control the corrosion. A number of monitoring techniques is industrially used today, and the applicability and reliability of these for monitoring MIC is evaluated. Coupons and ER are recommended as necessary basic...... techniques even though localised corrosion rate cannot be measured. FSM measures general corrosion and detects localised corrosion, but the sensitivity is not high enough for monitoring initiation of pitting and small attacks. Electrochemical techniques as LPR and EIS give distorted data and unreliable...

  11. Monitoring Techniques for Microbially Influenced Corrosion of Carbon Steel

    DEFF Research Database (Denmark)

    Hilbert, Lisbeth Rischel

    2000-01-01

    of carbon steel must be monitored on-line in order to provide an efficient protection and control the corrosion. A number of monitoring techniques is industrially used today, and the applicability and reliability of these for monitoring MIC is evaluated. Coupons and ER are recommended as necessary basic......Abstract Monitoring Techniques for Microbially Influenced Corrosion of Carbon Steel Microbially influenced corrosion (MIC) of carbon steel may occur in media with microbiological activity of especially sulphate-reducing bacteria, e.g. on pipelines buried in soil and on marine structures. MIC...... techniques even though localised corrosion rate cannot be measured. FSM measures general corrosion and detects localised corrosion, but the sensitivity is not high enough for monitoring initiation of pitting and small attacks. Electrochemical techniques as LPR and EIS give distorted data and unreliable...

  12. Monitoring Techniques for Microbially Influenced Corrosion of Carbon Steel

    DEFF Research Database (Denmark)

    Hilbert, Lisbeth Rischel

    2000-01-01

    Microbially influenced corrosion (MIC) of carbon steel may occur in media with microbiological activity of especially sulphate-reducing bacteria, e.g. on pipelines buried in soil and on marine structures. MIC of carbon steel must be monitored on-line in order to provide an efficient protection...... corrosion and detects localised corrosion, but the sensitivity is not high enough for monitoring initiation of pitting and small attacks. Electrochemical techniques as LPR and EIS give distorted data and unreliable corrosion rates, when biofilm and corrosion products cover the steel surface. However, EIS...... and control the corrosion. A number of monitoring techniques is industrially used today, and the applicability and reliability of these for monitoring MIC is evaluated. Coupons and ER are recommended as necessary basic techniques even though localised corrosion rate cannot be measured. FSM measures general...

  13. Monitoring Techniques for Microbially Influenced Corrosion of Carbon Steel

    DEFF Research Database (Denmark)

    Hilbert, Lisbeth Rischel

    2000-01-01

    and control the corrosion. A number of monitoring techniques is industrially used today, and the applicability and reliability of these for monitoring MIC is evaluated. Coupons and ER are recommended as necessary basic techniques even though localised corrosion rate cannot be measured. FSM measures general......Microbially influenced corrosion (MIC) of carbon steel may occur in media with microbiological activity of especially sulphate-reducing bacteria, e.g. on pipelines buried in soil and on marine structures. MIC of carbon steel must be monitored on-line in order to provide an efficient protection...... corrosion and detects localised corrosion, but the sensitivity is not high enough for monitoring initiation of pitting and small attacks. Electrochemical techniques as LPR and EIS give distorted data and unreliable corrosion rates, when biofilm and corrosion products cover the steel surface. However, EIS...

  14. Microbial-Influenced Corrosion of Corten Steel Compared with Carbon Steel and Stainless Steel in Oily Wastewater by Pseudomonas aeruginosa

    Science.gov (United States)

    Mansouri, Hamidreza; Alavi, Seyed Abolhasan; Fotovat, Meysam

    2015-07-01

    The microbial corrosion behavior of three important steels (carbon steel, stainless steel, and Corten steel) was investigated in semi petroleum medium. This work was done in modified nutrient broth (2 g nutrient broth in 1 L oily wastewater) in the presence of Pseudomonas aeruginosa and mixed culture (as a biotic media) and an abiotic medium for 2 weeks. The behavior of corrosion was analyzed by spectrophotometric and electrochemical methods and at the end was confirmed by scanning electron microscopy. The results show that the degree of corrosion of Corten steel in mixed culture, unlike carbon steel and stainless steel, is less than P. aeruginosa inoculated medium because some bacteria affect Corten steel less than other steels. According to the experiments, carbon steel had less resistance than Corten steel and stainless steel. Furthermore, biofilm inhibits separated particles of those steels to spread to the medium; in other words, particles get trapped between biofilm and steel.

  15. Formation mechanism of solute clusters under neutron irradiation in ferritic model alloys and in a reactor pressure vessel steel: clusters of defects; Mecanismes de fragilisation sous irradiation aux neutrons d'alliages modeles ferritiques et d'un acier de cuve: amas de defauts

    Energy Technology Data Exchange (ETDEWEB)

    Meslin-Chiffon, E

    2007-11-15

    The embrittlement of reactor pressure vessel (RPV) under irradiation is partly due to the formation of point defects (PD) and solute clusters. The aim of this work was to gain more insight into the formation mechanisms of solute clusters in low copper ([Cu] = 0.1 wt%) FeCu and FeCuMnNi model alloys, in a copper free FeMnNi model alloy and in a low copper French RPV steel (16MND5). These materials were neutron-irradiated around 300 C in a test reactor. Solute clusters were characterized by tomographic atom probe whereas PD clusters were simulated with a rate theory numerical code calibrated under cascade damage conditions using transmission electron microscopy analysis. The confrontation between experiments and simulation reveals that a heterogeneous irradiation-induced solute precipitation/segregation probably occurs on PD clusters. (author)

  16. Microbiologically Influenced Corrosion of Carbon Steel Exposed to Biodiesel

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    S. Malarvizhi

    2016-01-01

    Full Text Available Environmental concerns over worsening air pollution problems caused by emissions from vehicles and depletion of fossil fuels have forced us to seek fuels such as biodiesel which can supplement petrofuels. Biodiesels have the ability to retain water and provide a conducive environment for microbiologically influenced corrosion (MIC which may cause difficulties during transportation, storage, and their use. This paper analyses the influence of bacteria on the corrosivity of biodiesel obtained from Jatropha curcas on carbon steel using mass loss method. Carbon steel showed the highest corrosion rates in B100 (100% biodiesel both in the presence and in absence of bacteria. The surface analysis of the metal was carried out using SEM.

  17. Anticorrosive Influence of Acetobacter aceti Biofilms on Carbon Steel

    Science.gov (United States)

    France, Danielle Cook

    2016-09-01

    Microbiologically influenced corrosion (MIC) of carbon steel infrastructure is an emerging environmental and cost issue for the ethanol fuel industry, yet its examination lacks rigorous quantification of microbiological parameters that could reveal effective intervention strategies. To quantitatively characterize the effect of cell concentration on MIC of carbon steel, numbers of bacteria exposed to test coupons were systematically controlled to span four orders of magnitude throughout a seven-day test. The bacterium studied, Acetobacter aceti, has been found in ethanol fuel environments and can convert ethanol to the corrosive species acetic acid. A. aceti biofilms formed during the test were qualitatively evaluated with fluorescence microscopy, and steel surfaces were characterized by scanning electron microscopy. During exposure, biofilms developed more quickly, and test reactor pH decreased at a faster rate, when cell exposure was higher. Resulting corrosion rates, however, were inversely proportional to cell exposure, indicating that A. aceti biofilms are able to protect carbon steel surfaces from corrosion. This is a novel demonstration of corrosion inhibition by an acid-producing bacterium that occurs naturally in corrosive environments. Mitigation techniques for MIC that harness the power of microbial communities have the potential to be scalable, inexpensive, and green solutions to industrial problems.

  18. Influence of tempering temperature on mechanical properties of cast steels

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    G. Golański

    2008-12-01

    Full Text Available The paper presents results of research on the influence of tempering temperature on structure and mechanical properties of bainite hardened cast steel: G21CrMoV4 – 6 (L21HMF and G17CrMoV5 – 10 (L17HMF. Investigated cast steels were taken out from internal frames of steam turbines serviced for long time at elevated temperatures. Tempering of the investigated cast steel was carried out within the temperature range of 690 ÷ 730 C (G21CrMoV4 – 6 and 700 ÷ 740 C (G17CrMoV5 – 10. After tempering the cast steels were characterized by a structure of tempered lower bainite with numerous precipitations of carbides. Performed research of mechanical properties has shown that high temperatures of tempering of bainitic structure do not cause decrease of mechanical properties beneath the required minimum.oo It has also been proved that high-temperature tempering (>720 oC ensures high impact energy at the 20% decrease of mechanical properties.

  19. Factors influencing the surface quality of polished tool steels

    Science.gov (United States)

    Rebeggiani, S.; Rosén, B.-G.

    2014-09-01

    Today’s demands on surface quality of moulds for injection moulding of plastic components involve no/low defect contents and roughness levels in the nm-range for high gloss applications. Material properties as well as operating conditions influence the mould finish, and thus the final surface of moulded products. This paper focuses on how particle content and different polishing strategies influence final surface qualities of moulds. Visual estimations of polished tool steel samples were combined with non-contact 3D-surface texture analysis in order to correlate traditional assessments to more quantitative methods, and to be able to analyse the surfaces at nanometre-level. It was found that steels with a lower proportion of particles, like carbides and oxides, gave rise to smoother polished surfaces. In a comparative study of polishers from different polishing shops, it was found that while different surface preparation strategies can lead to similar final roughness, similar preparation techniques can produce high-quality surfaces from different steel grades. However, the non-contact 3D-surface texture analysis showed that not all smooth polished surfaces have desirable functional topographies for injection moulding of glossy plastic components.

  20. Hydrogen influence on the mechanical behaviour of high strength steel

    Energy Technology Data Exchange (ETDEWEB)

    Herenu, Silvina [National Technology Univ. of San Nicolas (Argentina).; National Council of Scientific Research and Technology (Argentina); Armas, Alberto [National Univ. of Rosario (Argentina); Brandaleze, Elena [National Technology Univ. of San Nicolas (Argentina). Metallurgical Dept.; Mansilla, Graciela [National Technology Univ. of San Nicolas (Argentina).

    2010-07-01

    Though numerous studies have been devoted to hydrogen embrittlement in steels, up to date there is not a general agreement about the effect of hydrogen on the mechanical behaviour. The purpose of this paper is to analyze the influence of hydrogen on the mechanical response of high strength steels. Samples were cathodically charged with hydrogen, previous to low cyclic fatigue and tensile tests at room temperature. The presence of hydrogen produces softening effects on the cyclic behaviour and improvements in the fatigue life for low hydrogen contents. The stress-strain curves of tensile tests on pre-charged samples depend on the strain rate imposed. Both tensile and fatigue response could be explained by the hydrogen enhancement of dislocation mobility mechanism. (orig.)

  1. INFLUENCE OF ELECTRIC SPARK ON HARDNESS OF CARBON STEEL

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    I. O. Vakulenko

    2014-03-01

    Full Text Available Purpose. The purpose of work is an estimation of influence of an electric spark treatment on the state of mouldable superficial coverage of carbon steel. Methodology. The steel of fragment of railway wheel rim served as material for research with chemical composition 0.65% С, 0.67% Mn, 0.3% Si, 0.027% P, 0.028% S. Structural researches were conducted with the use of light microscopy and methods of quantitative metallography. The structural state of the probed steel corresponded to the state after hot plastic deformation. The analysis of hardness distribution in the micro volumes of cathode metal was carried out with the use of microhardness tester of type of PMT-3. An electric spark treatment of carbon steel surface was executed with the use of equipment type of EFI-25M. Findings. After electric spark treatment of specimen surface from carbon steel the forming of multi-layered coverage was observed. The analysis of microstructure found out the existence of high-quality distinctions in the internal structure of coverage metal, depending on the probed area. The results obtained in the process are confirmed by the well-known theses, that forming of superficial coverage according to technology of electric spark is determined by the terms of transfer and crystallization of metal. The gradient of structures on the coverage thickness largely depends on development of structural transformation processes similar to the thermal character influence. Originality. As a result of electric spark treatment on the condition of identical metal of anode and cathode, the first formed layer of coverage corresponds to the monophase state according to external signs. In the volume of coverage metal, the appearance of carbide phase particles is accompanied by the decrease of microhardness values. Practical value. Forming of multi-layered superficial coverage during electric spark treatment is accompanied by the origin of structure gradient on a thickness. The effect

  2. Influence of Trace Alloying Elements on Corrosive Resistance of Cast Stainless Steel

    Institute of Scientific and Technical Information of China (English)

    DUAN Han-qiao; YAN Xiang; WEI Bo-kang; LIN Han-tong

    2005-01-01

    The influences of trace alloying elements niobium, vanadium and zirconium on the corrosive resistance of 18-8 type cast stainless steel have been studied in deta() orthogonal design experiments. The results show that zirconium is mainly in the form of compound inclusions, which is unfavorable to promote the corrosive resistance of the cast stainless steel. It can alleviate the disadvantageous influence of carbon addition on corrosive resistance when some elements such as vanadium and niobium exist in the steel, and niobium has a remarkable influence on the intergranular corrosive resistance but unobvious on the pitting corrosion, and vanadium has a slightly favorable influence on the corrosive resistance of the steel.

  3. Influence of remanent magnetization on pitting corrosion in pipeline steel

    Energy Technology Data Exchange (ETDEWEB)

    Espina-Hernandez, J. H. [ESIME Zacatenco, SEPI Electronica Instituto Politecnico Nacional Mexico, D. F. (Mexico); Caleyo, F.; Hallen, J. M. [DIM-ESIQIE, Instituto Politecnico Nacional Mexico D. F. (Mexico); Lopez-Montenegro, A.; Perez-Baruch, E. [Pemex Exploracion y Produccion, Region Sur Villahermosa, Tabasco (Mexico)

    2010-07-01

    Statistical studies performed in Mexico indicate that leakage due to external pitting corrosion is the most likely cause of failure of buried pipelines. When pipelines are inspected with the magnetic flux leakage (MFL) technology, which is routinely used, the magnetization level of every part of the pipeline changes as the MFL tool travels through it. Remanent magnetization stays in the pipeline wall after inspection, at levels that may differ from a point to the next. This paper studies the influence of the magnetic field on pitting corrosion. Experiments were carried out on grade 52 steel under a level of remanent magnetization and other laboratory conditions that imitated the conditions of a pipeline after an MLF inspection. Non-magnetized control samples and magnetized samples were subjected to pitting by immersion in a solution containing chlorine and sulfide ions for seven days, and then inspected with optical microscopy. Results show that the magnetic field in the pipeline wall significantly increases pitting corrosion.

  4. Influence of Simulated Outside-Reactor Irradiation on Anticorrosion Property of Austenitic Stainless Steel

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    The influence of γ-ray irradiation on the properties of inside-reactor stainless steel structures was studied by simulating the working condition of pressurized water reactor (PWR) first circuit and the outside-reactor γ-ray irradiation. The result shows that the simulated outside-reactor irradiation (irradiation dose 4.4 × 104 Gy) has no influence on anticorrosion properties of solutionized SUS304 austenitic stainless steel, including intergranular corrosion (IC) and stress corrosion cracking (SCC). Anticorrosion properties (IC, SCC) of sensitized SUS304 austenitic stainless steel are reduced by simulated outside-reactor irradiation. The longer the sensitizedtime is, the more obvious the influence is.

  5. STUDY OF THE HARDENING TEMPERATURE INFLUENCE ON PROCESSES WHEN TEMPERING CARBON STEEL

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    Ms. Irina L. Polyanskaya

    2016-12-01

    Full Text Available The article presents the research results of carbon steel electrical resistance changes at low tem-pering and determines the effect of temperature on the electrical resistance. The analysis of the results showed that the influence of carbon on the value of the electrical resistance is higher than the influence of the crystal structure defects. The changes of the hardened steel electrical resistance are due to the redistri-bution of carbon.

  6. Calculating Method for Influence of Material Flow on Energy Consumption in Steel Manufacturing Process

    Institute of Scientific and Technical Information of China (English)

    YU Qing-bo; LU Zhong-wu; CAI Jiu-ju

    2007-01-01

    From the viewpoint of systems energy conservation, the influences of material flow on its energy consumption in a steel manufacturing process is an important subject. The quantitative analysis of the relationship between material flow and the energy intensity is useful to save energy in steel industry. Based on the concept of standard material flow diagram, all possible situations of ferric material flow in steel manufacturing process are analyzed. The expressions of the influence of material flow deviated from standard material flow diagram on energy consumption are put forward.

  7. Influence of Heat Treatments on the Corrosion Resistance of Medium -Carbon Steel using Sulfuric Spring Water

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    Ikhlas Basheer

    2013-04-01

    Full Text Available The corrosion is one of the important problems that may be occur to the parts of machinery and equipment after manufactured and when used as a result of exposure to corrosive media. Plain-carbon steel is considered as one of the most common minerals used in industrial applications. Some of heat treatments can have direct effect on the corrosion rate of steel by building up galvanic corrosion cells between its microscopic phases. Therefore, to adopt one of kinds of the plain-carbon steel and the most commonly used in industry to be study subject, that is medium carbon steel and took samples of this steel has been treated thermally in three methods which the normalising, annealing, and hardening .The corrosive media used in the research is Sulfuric Spring, it contains many chemical compounds to show its influence on the corrosion of steel. The weight loss method is used to determine corrosion rate and to compare between the results obtained, show that the greatest corrosion resistance of the annealed steel and the corrosion resistance of the hardened steel is the lowest while the corrosion  resistance of the normalised steel is in-between them.         Calcium carbonate was formed on the metal surface which acts as an isolating layer which decrease corrosion rate with time

  8. Influence of the storage conditions on prestressing steel relaxation losses

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    Suárez, F.

    2012-12-01

    Full Text Available Stress relaxation losses on active reinforcement have significant impact on prestressed concrete structures. This is why relaxation tests are carried out on prestressing steel wires and strands after being manufactured. Then, these materials are coiled and stored for a long-term period, sometimes in excess of one year. The influence of these operations, carried out after manufacturing, is usually neglected. Nevertheless, some manufacturers and contractors have noticed that, sometimes, when relaxation tests are carried out after a long-term storage, the relaxation losses found are higher than those measured immediately after manufacturing. In this work, lab tests are performed to check the influence of the coiling radius and the period of storage on the relaxation test. In addition to this, an analytical model is presented to predict the results of a relaxation test carried out on a wire coiled and stored for a long-term period. This model explains the evolution on the cross-sectional stress profile along the coiling-storing-uncoiling process, as well as the influence of the residual stresses on it.

    La pérdida de tensión por relajación en las armaduras activas afecta de forma importante a las estructuras de hormigón pretensado. Por ello se realizan ensayos de relajación de los alambres y cordones de pretensado tras su fabricación. Después, el material es enrollado y almacenado durante periodos que en ocasiones pueden superar el año de duración. Generalmente se desprecia la influencia que estas operaciones posteriores a la fabricación pueden tener sobre el material. Sin embargo, diversos fabricantes y suministradores han constatado experimentalmente que, en ocasiones, el material almacenado durante un periodo prolongado presenta pérdidas de relajación mayores que inmediatamente tras su fabricación. En este trabajo se realizan ensayos de laboratorio para comprobar la influencia que el radio de enrollamiento y el periodo de

  9. Influence of Characteristics on Bending Strength of Layered Steel Fiber Reinforced Concrete

    Institute of Scientific and Technical Information of China (English)

    DAI Shao-bin; SONG Ming-hai; HUANG Jun

    2005-01-01

    The influence of two main characteristics of steel fiber, the aspect ratio (Df) and volume fraction (pf), on the bending strength of Layered Steel Fiber Reinforced Concrete (LSFRC) is investigated by using orthogonal test. Via the variance analysis on the experimental results and trend analysis on the two characteristics, Df is found significantly related to the bending strength of LSFRC. The influence ratio is 63.3%. The bending strength of LSFRC increases if Df increases, makes better when Df reaches 100. ρf has ordinary influence on the bending strength of LSFRC. The influence ratio is 29.2%. Other characteristics, such as the shape of steel fiber and the mix proportion, have less influence. The best ρf contributing to the bending strength of LSFRC is 1.5 %. If pf is greater than 1.5 %, it has negative influence on the bending strength of LSFRC. So, pf makes a limited contribution to the bending strength of LSFRC.

  10. The role of acetogens in microbial influenced corrosion of steel

    Directory of Open Access Journals (Sweden)

    Jaspreet eMand

    2014-06-01

    Full Text Available Microbially-influenced corrosion (MIC of iron (Fe0 by sulfate reducing bacteria (SRB has been studied extensively. Through a mechanism, that is still poorly understood, electrons or hydrogen (H2 molecules are removed from the metal surface and used as electron donor for sulfate reduction. The resulting ferrous ions precipitate in part with the sulfide produced, forming characteristic black iron sulfide. Hydrogenotrophic methanogens can also contribute to MIC. Incubation of pipeline water samples, containing bicarbonate and some sulfate, in serum bottles with steel coupons and a headspace of 10% (vol/vol CO2 and 90% N2, indicated formation of acetate and methane. Incubation of these samples in serum bottles, containing medium with coupons and bicarbonate but no sulfate, also indicated that formation of acetate preceded the formation of methane. Microbial community analyses of these enrichments indicated the presence of Acetobacterium, as well we of hydrogenotrophic and acetotrophic methanogens. The formation of acetate by homoacetogens, such as Acetobacterium woodii from H2 (or Fe0 and CO2, is potentially important, because acetate is a required carbon source for many SRB growing with H2 and sulfate. A consortium of the SRB Desulfovibrio vulgaris Hildenborough and A. woodii was able to grow in defined medium with H2, CO2 and sulfate, because A. woodii provides the acetate, needed by D. vulgaris under these conditions. Likewise, general corrosion rates of metal coupons incubated with D. vulgaris in the presence of acetate or in the presence of A. woodii were higher than in the absence of acetate or A. woodii, respectively. An extended MIC model capturing these results is presented.

  11. Influence of Manufacturing Processes and Microstructures on the Performance and Manufacturability of Advanced High Strength Steels

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Kyoo Sil; Liu, Wenning N.; Sun, Xin; Khaleel, Mohammad A.

    2009-10-01

    Advanced high strength steels (AHSS) are performance-based steel grades and their global material properties can be achieved with various steel chemistries and manufacturing processes, leading to various microstructures. In this paper, we investigate the influence of supplier variation and resulting microstructure difference on the overall mechanical properties as well as local formability behaviors of advanced high strength steels (AHSS). For this purpose, we first examined the basic material properties and the transformation kinetics of TRansformation Induced Plasticity (TRIP) 800 steels from three different suppliers under different testing temperatures. The experimental results show that there is a significant supplier (i.e., manufacturing process) dependency of the TRIP 800 steel mechanical and microstructure properties. Next, we examined the local formability of two commercial Dual Phase (DP) 980 steels during stamping process. The two commercial DP 980 steels also exhibit noticeably different formability during stamping process in the sense that one of them shows severe tendency for shear fracture. Microstructure-based finite element analyses are carried out next to simulate the localized deformation process with the two DP 980 microstructures, and the results suggest that the possible reason for the difference in formability lies in the morphology of the hard martensite phase in the DP microstructure.

  12. The influence of molybdenum on stress corrosion in Ultra Low Carbon Steels with copper addition

    Directory of Open Access Journals (Sweden)

    M. Mazur

    2010-07-01

    Full Text Available The influence of molybdenum content on the process of stress corrosion of ultra-low carbon structural steels with the addition of copper HSLA (High Strength Low Alloy was analyzed. The study was conducted for steels after heat treatment consisting of quenching andfollowing tempering at 600°C and it was obtained microstructure of the tempered martensite laths with copper precipitates and the phaseLaves Fe2Mo type. It was found strong influence of Laves phase precipitate on the grain boundaries of retained austenite on rate anddevelopment of stress corrosion processes. The lowest corrosion resistance was obtained for W3 steel characterized by high contents ofmolybdenum (2.94% Mo which should be connected with the intensity precipitate processes of Fe2Mo phase. For steels W1 and W2which contents molybdenum equals 1.02% and 1.88%, respectively were obtained similar courses of corrosive cracking.

  13. Influence of Environmental Factors on the Volume Change of Blended Cement Containing Steel Slag

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    In the condition of 20 ℃, 5% sulfate liquor curing, standard tap water curing and 50% RH curing-three different curing environments, the volume change of steel slag blended cement influenced by environmental factors was studied. With steel slag addition 10%, 30%, 50%, from 90 days to 356 days, the relationship of shrinkage and three different curing environments is: dry curing environment>tap water curing environment>sulfate curing environment. But, the sample shrinkage in 28 days has much difference with the curing environment, which has no obvious orderliness. The different effects on blended cement containing steel slag in different environmental factors were analyzed using SEM.

  14. The influence of assist gas on magnetic properties of electrotechnical steel sheets cut with laser

    Science.gov (United States)

    Gaworska-Koniarek, Dominika; Szubzda, Bronisław; Wilczyński, Wiesław; Drosik, Jerzy; Karaś, Kazimierz

    2011-07-01

    The paper presents the influence of assist gas (air and nitrogen) during laser cutting on magnetization, magnetic permeability and loss characteristics of non-oriented electrical steels. The research was made on an non-oriented M330-50A grade electrical steels by means of single sheet tester. In order to enhance the effect of cutting and the same degradation zone on magnetic properties, strips with different width were achieved. Measurements results indicate that application of air as assist gas has more destructive effect on magnetic properties of electrical steels than nitrogen one.

  15. INFLUENCE OF MICROALLOYING BY BORON ON HARDENABILITY OF STEEL

    Directory of Open Access Journals (Sweden)

    E. P. Baradyntseva

    2016-01-01

    Full Text Available The research conducted in laboratory of metallurgical science by which the factors exerting impact on hardenability of steel microalloyed by boron were analysed. The research was made because the implementation of this process in mass production is connected with the certain difficulties. The conducted researches have allowed to draw a conclusion that changing content of various chemical elements, such as nitrogen, boron, the titan and aluminum in steel containing boron, produced by JSC «BSW – Management Company of Holding «BMC» at the stage of preparation of chart flowsheet make it possible to predict terms of hardenability of the final product.

  16. Formation of vivianite during microbiologically influenced corrosion of steels

    Energy Technology Data Exchange (ETDEWEB)

    McNeil, M. [Nuclear Regulatory Commission, Washington, DC (United States); McKay, J. [Univ. of Western Ontario, London (Canada)

    1994-12-31

    Exposure of carbon and HY-80 high strength low alloy (HSLA) steels to anaerobic Postgate cultures containing sulfate reducing bacteria leads to production of mackinawite, Fe{sub 9}S{sub 8} and vivianite, Fe{sub 3}(PO{sub 4}){sub 2}{center_dot}8H{sub 2}O, with minor amounts of other minerals, the vivianite being sometimes accompanied by siderite, FeCO{sub 3}. The vivianite and mackinawite persist on exposure to air or oxygenated water. Green rust is a significant alteration product on some steels. The implications of these findings are discussed in light of present and possible future nuclear waste containers.

  17. Strain path's influence on the elastic behaviour of theTRIP 700 steel

    OpenAIRE

    MENDIGUREN, Joseba; CORTES, Fernando; GALDOS, Lander; Berveiller, Sophie

    2013-01-01

    This paper deals with the analysis of thestrain path's influence on the elastic behaviour of TRIP700 steel; it aims to validate the cyclic testing method to characterise inelastic behaviour of advanced high strength steels (AHSS). Different cyclic tests are done, where the strain path is changed from test to test. Large deformation strain gages are used to determine the inelastic behaviour of the specimens at macro-level. At a lower scale, stress measurements are carried out using the XRD tec...

  18. Electrochemical Behavior of Steel Bar in Electrolytes:Influence ofpH Value and Cations

    Institute of Scientific and Technical Information of China (English)

    PU Qi; JIANG Linhua; CHU Hongqiang; XU Jinxia; XU Yi

    2011-01-01

    Steel bar corrosion on electrolytes and the influence of cation were investigated.Three electrolytes of Ca(OH)2,NaOH and KOH with pH levels of 12.5,11.5,10.5,9.5,8.5 were prepared,meanwhile,the methods of free corrosion potential and electrochemical impedance spectra (EIS) were used to evaluate the influence of cations on the depassivation of the steel bar in electrolytes.The experimental results indicate that the initial corrosion pH value of the steel bar is influenced by the cation in electrolyte and the influence ofK+ in electrolyte is the most remarkable,followed by Na+ and Ca2+.The initial corrosion pH values are 10.5 in KOH electrolyte,9.5 in NaOH electrolyte and lower than 8.5 in Ca(OH)2 electrolyte.

  19. Influence of Ring Stiffeners on a Steel Cylindrical Shell

    Directory of Open Access Journals (Sweden)

    D. Lemák

    2005-01-01

    Full Text Available Shell structures are usually formed from concrete, steel and nowadays also from many others materials. Steel is typically used in the structures of chimneys, reservoirs, silos, pipelines, etc. Unlike concrete shells, steel shells are regularly stiffened with the help of longitudinal and/or ring stiffeners.The authors of this paper investigated steel cylindrical shells and their stiffening with the use of ring stiffeners. The more complete the stiffening, the more closely the shell will act to beam theory, and the calculations will be much easier. However, this would make realization of the structure more expensive and more laborious. The target of the study is to find the limits of ring stiffeners for cylindrical shells. Adequate stiffeners will eliminate semi-bending action of the shells in such way that the shell structures can be analyzed with the use of numerical models of the struts (e.g., by beam theory without significant divergences from reality. Recommendations are made for the design of ring stiffeners, especially for the distances between stiffeners and for their bending stiffness. 

  20. INFLUENCE OF ABNORMAL AUSTENITE GRAIN GRAIN GROWTH IN QUENCHED ABNT 5135 STEEL

    Directory of Open Access Journals (Sweden)

    Camila de Brito Ferreira

    2015-03-01

    Full Text Available Grain size in the steels is a relevant aspect in quenching and tempering heat treatments. It is known that high austenitizing temperature and long time provide an increase in austenitic grain sizes. Likewise, after hardening of low alloy steel, the microstructure consists of martensite and a volume fraction of retained austenite. This paper evaluates the influence of austenite grain size on the volume fraction of retained austenite measured by metallographic analyses and X-ray diffraction. The Mi and Mf temperatures were calculated using an empirical equation and experimentally determined by differential thermal analysis. The mechanical behavior of the steel was evaluated by Vickers microhardness testing. Differently from other results published in the literature that steel hardenability increases with the austenite grain size, it was observed that the increase in austenite grain promotes greater volume fraction of retained austenite after water quenching.

  1. EXPERIMENTAL RESEARCH REGARDING THE INFLUENCE OF CUTTING REGIME ON THE WEAR OF DRILLS AT STEEL PROCESSING

    Directory of Open Access Journals (Sweden)

    Leonard Marius CIUREZU GHERGHE

    2015-05-01

    Full Text Available This paper aims to highlight the influence of cutting regime on the wear drills at steel processing , in particular the processing of stainless steel X17CrNi16-2 SR EN 10088-4 DIN 17440. We are interested in wear of the drill at processing of this type of stainless steel , which has applicability in energy industry given the special characteristics of its. We want a maximum value of 0.2 mm for the wear of the drill, measurement and taking pictures are made using a microscope DigiMicro 2.0 and the software used is MicroCapture. Processing was done on machining center YMC YOUNG TECH 1050, and the tool used was 8 mm drill bit high speed steel.

  2. Hydrogen attack - Influence of hydrogen sulfide. [on carbon steel

    Science.gov (United States)

    Eliezer, D.; Nelson, H. G.

    1978-01-01

    An experimental study is conducted on 12.5-mm-thick SAE 1020 steel (plain carbon steel) plate to assess hydrogen attack at room temperature after specimen exposure at 525 C to hydrogen and a blend of hydrogen sulfide and hydrogen at a pressure of 3.5 MN/sq m for exposure times up to 240 hr. The results are discussed in terms of tensile properties, fissure formation, and surface scales. It is shown that hydrogen attack from a high-purity hydrogen environment is severe, with the formation of numerous methane fissures and bubbles along with a significant reduction in the room-temperature tensile yield and ultimate strengths. However, no hydrogen attack is observed in the hydrogen/hydrogen sulfide blend environment, i.e. no fissure or bubble formation occurred and the room-temperature tensile properties remained unchanged. It is suggested that the observed porous discontinuous scale of FeS acts as a barrier to hydrogen entry, thus reducing its effective equilibrium solubility in the iron lattice. Therefore, hydrogen attack should not occur in pressure-vessel steels used in many coal gasification processes.

  3. Influence of the chemical composition on steel casting performance

    Directory of Open Access Journals (Sweden)

    Roney Eduardo Lino

    2017-01-01

    Full Text Available Improving the quality of steel and the steelmaking process has been a matter of routine for metallurgical engineers and steelmaking companies in a demanding market for quality products at highly competitive price. The chemical and temperature adjustment are made during the secondary refining process, as well as the inclusion modification required to product quality, and also the demand for castability accuracy. Continuous casting process is the most used solidification casting process, in which the flow of pouring liquid metal through the submerged entry nozzle is assured by the correct temperature and the formation of liquid inclusion in the casting temperature. Thermocalc and CEQCSI were the software used in this work to assess the effect of carbon, silicon and sulphur in the castability window of the aluminium vs calcium phase diagrams. They have proved to be highly suitable and effective and the results showed that the chemical elements used directly affected the position of the castability window of carbon steel. An analysis of a 0.2%C billet sample using Scanning Electron Microscopy showed that there is a great heterogeneity of inclusions in aluminium-killed and calcium-treated steel.

  4. Influence of submerged entry nozzle clogging on the behavior of molten steel in continuously cast slab molds

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    The influence of submerged entry nozzle clogging on the behavior of molten steel in continuously cast slab molds was studied using commercial code CFX4.3. The results indicate that clogging at the top part of the nozzle port not only increases the velocity of molten steel, but also enhances the wall shear stress, F number and heat flux. This clogging has the greatest effect on the behavior of molten steel. However, clogging at the top 1/3 of the nozzle only increases the velocity of molten steel and has little influence. Clogging at the bottom of the nozzle almost has no influence.

  5. Influence of silver additions to type 316 stainless steels on bacterial inhibition, mechanical properties, and corrosion resistance

    DEFF Research Database (Denmark)

    Chiang, Wen-Chi; Tseng, I-Sheng; Møller, Per;

    2010-01-01

    techniques. The microstructure of these 316 stainless steels was examined, and the influences of silver additions to 316 stainless steels on bacterial inhibition, mechanical properties, and corrosion resistance were investigated. This study suggested that silver-bearing 316 stainless steels could be used......Bacterial contamination is a major concern in many areas. In this study, silver was added to type 316 stainless steels in order to obtain an expected bacteria inhibiting property to reduce the occurrence of bacterial contamination. Silver-bearing 316 stainless steels were prepared by vacuum melting...

  6. Influence of Rare Earths on Contact Fatigue of Rail Steels

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Rail/wheel contact fatigue of NbRE rail, Nb rail and U74 rail was investigated using contact fatigue tester. Microstructure and morphology as well as microhardness in the fatigue profiles were analyzed by scanning electron microscope and Vickers hardness respectively. The experimental results show that rare earths are able to delay the initiation and the propagation of fatigue cracks and postpone the surface shelling or spalling, even more, to reduce the crack propagation angle and the crack propagation depth in steady state as well as the plastic deformation area, and to improve work-hardening of the rail steel.

  7. Influence of oil and water media on fretting behaviour of AISI 52100 steel rubbing against AISI 1045 steel

    Institute of Scientific and Technical Information of China (English)

    REN Ping-di; CHEN Guang-xiong; ZHU Min-hao; ZHOU Zhong-rong

    2004-01-01

    A series of fretting test were carried out using a DELTA PLINT testing system to study the influence of hydraulic oil and water on fretting behaviour of AISI 52100 steel rubbing against AISI 1045 steel. The test result shows that media hydraulic oil and water have a distinct influence on fretting behaviour of the tested materials. Medium water can lead to shifting of the partial slip regime in the fretting map from a larger displacement amplitude toward a smaller one and enlargement of the mixed slip regime, in comparison with that in ambient atmosphere. While medium hydraulic oil can result in shifting of the partial slip regime from a smaller displacement amplitude toward a larger one. In the gross slip regime, hydraulic oil and water play a positive role as lubrication media. They can clearly decrease the fretting friction coefficient between AISI 52100 and AISI 1045. The test result also demonstrates that this lubrication effect will get better with increasing displacement amplitude and that hydraulic oil is better than water for lubrication. SEM observation of the wear scars displays that the fretting wear mainly results from abrasive wear and delamination of the fretted materials when using these two kinds of substances as lubrication media.

  8. Influence of delta ferrite on mechanical and creep properties of steel P92

    Energy Technology Data Exchange (ETDEWEB)

    Mohyla, Petr [VSB - Technical Univ. of Ostrava (Czech Republic). Faculty of Mechanical Engineering; Kubon, Zdenek [Material and Metallurgical Research Ltd., Ostrava (Czech Republic)

    2010-07-01

    This article presents some new results obtained during research of chromium modified steel P92. This steel is considered the best modified 9-12% Cr steel for the construction of modern power plants with ultra-super-critical steam parameters. High creep rupture strength of steel P92 is characterized by its chemical composition and by microstructure as well. Optimal microstructure of steel P92 is ideally composed of homogeneous martensite and fine dispersion of secondary particles. During the research program one P92 heat with an occurrence of about 20% delta ferrite was produced. The article describes the microstructure of the heat in various modes of heat treatment, as well as the results of mechanical properties tests at room temperature and also creep test results. The results are confronted with properties of other heats that have no delta ferrite. The relevance is on the significant difference while comparing of creep test results. The comparison of results brings conclusions, defining influence of delta ferrite on mechanical and creep properties of P92 steel. (orig.)

  9. Influences of cyclic loading on martensite transformation of TRIP steels

    Science.gov (United States)

    Dan, W. J.; Hu, Z. G.; Zhang, W. G.

    2013-03-01

    While austenite transformation into martensite induces increasing of the crack initiation life and restraining of the growth of fatigue cracks in cyclic-loading processes, TRIP-assisted steels have a better fatigue life than the AHSS (Advance High Strength Steels). As two key parameters in the cyclic loading process, strain amplitude and cyclic frequency are used in a kinetic transformation model to reasonably evaluate the phase transformation from austenite into martensite with the shear-band intersections theory, in which strain amplitude and cyclic frequency are related to the rate of shear-band intersection formation and the driving force of phase transformation. The results revealed that the martensite volume fraction increased and the rate of phase transformation decrease while the number of cycles increased, and the martensite volume fraction was almost constant after the number of cycles was more than 2000 times. Higher strain amplitude promotes martensite transformation and higher cyclic frequency impedes phase transformation, which are interpreted by temperature increment, the driving force of phase transformation and the rate of shearband intersection formation.

  10. Assessment of the Critical Parameters Influencing the Edge Stretchability of Advanced High-Strength Steel Sheet

    Science.gov (United States)

    Pathak, N.; Butcher, C.; Worswick, M.

    2016-11-01

    The edge formability of ferritic-martensitic DP (dual-phase) and ferritic-bainitic CP (complex-phase) steels was evaluated using a hole expansion test for different edge conditions. Hole expansion tests involving the standard conical punch as well as a custom flat punch were performed to investigate formability when the hole is expanded out-of-plane (conical punch) and in-plane using the flat punch. A range of edge conditions were considered, in order to isolate the influence of a range of factors thought to influence edge formability. The results demonstrate that work hardening and void damage at the sheared edge govern formability, while the sheared surface quality plays a minor or secondary role. A comparison of the edge stretching limits of DP and CP steels demonstrates the advantages of a ferritic-bainitic microstructure for forming operations with severe local deformation as in a stretch-flanging operation. A comparison of a traditional DP780 steel with a CP steel of similar strength showed that the edge stretching limit of the CP steel was three times larger than that of the DP780.

  11. Influence of asphalt on fatigue crack monitoring in steel bridge decks using guided waves

    NARCIS (Netherlands)

    Pahlavan, P.L.; De Soares Silva e Melo Mota, M.; Blacquière, G.

    2016-01-01

    Asphalt materials generally exhibit temperature-dependent properties, which can influence the performance of fatigue crack inspection and monitoring systems for bridge deck structures. For a non-intrusive fatigue crack sizing methodology applied to steel decks using ultrasonic guided waves, the effe

  12. Influence of asphalt on fatigue crack monitoring in steel bridge decks using guided waves

    NARCIS (Netherlands)

    Pahlavan, P.L.; De Soares Silva e Melo Mota, M.; Blacquière, G.

    2016-01-01

    Asphalt materials generally exhibit temperature-dependent properties, which can influence the performance of fatigue crack inspection and monitoring systems for bridge deck structures. For a non-intrusive fatigue crack sizing methodology applied to steel decks using ultrasonic guided waves, the

  13. The influence of deformation on the product performance of pre-coated packaging steels

    NARCIS (Netherlands)

    Boelen, B.

    2009-01-01

    Recent developments in various countries have led to the development of new types of polymer coated packaging steel. These materials behave differently in production and end use and are therefore subject of extensive studies. The aim of this research is to understand the influence of deformation of

  14. Influence of the surface finishing on electrochemical corrosion characteristics of AISI 316L stainless steel

    Directory of Open Access Journals (Sweden)

    Sylvia Dundeková

    2015-05-01

    Full Text Available Stainless steels from 316 group are very often and successfully uses for medical applications where the good mechanical and chemical properties in combination with non-toxicity of the material assure its safe and long term usage. Corrosion properties of AISI 361L stainless steel are strongly influenced by surface roughness and treatment of the engineering parts (specimens and testing temperature. Electrochemical characteristics of ground, mechanically polished and passivated AISI 316L stainless steel specimens were examined with the aim to identify the polarization resistance evolution due to the surface roughness decrease. Results obtained on mechanically prepared specimens where only natural oxide layer created due to the exposure of the material to the corrosion environment was protecting the materials were compared to the passivated specimens with artificial oxide layer. Also the influence of temperature and stabilization time before measurement were taken into account when discussing the obtained results. Positive influence of decreasing surface roughness was obtained as well as increase of polarization resistance due to the chemical passivation of the surface. Increase of the testing temperature and short stabilization time of the specimen in the corrosion environment were observed negatively influencing corrosion resistance of AISI 316L stainless steel.

  15. Influence of Plastic Deformation on Low Temperature Surface Hardening of Austenitic Stainless Steel by Gaseous Nitriding

    DEFF Research Database (Denmark)

    Bottoli, Federico; Winther, Grethe; Christiansen, Thomas Lundin;

    2015-01-01

    This article addresses an investigation of the influence of plastic deformation on low temperature surface hardening by gaseous nitriding of two commercial austenitic stainless steels: AISI 304 and EN 1.4369. The materials were plastically deformed to different equivalent strains by uniaxial...

  16. The influence of deformation on the product performance of pre-coated packaging steels

    NARCIS (Netherlands)

    Boelen, B.

    2009-01-01

    Recent developments in various countries have led to the development of new types of polymer coated packaging steel. These materials behave differently in production and end use and are therefore subject of extensive studies. The aim of this research is to understand the influence of deformation of

  17. Influence of Punch Radius in a Nakazima Test for Mild Steel and Aluminium

    NARCIS (Netherlands)

    Fictorie, E.; van den Boogaard, Antonius H.; Atzema, E.H.; Atzema, E.H.

    2010-01-01

    Forming limit curves are usually determined for membrane type deformations. Recently, the influence of simultaneous bending deformation on the forming limits has attracted renewed attention. In this paper, FLCs are determined for a DC06 steel and an AA5051 aluminium alloy by the standard Nakazima

  18. Influence of coolant motion on structure of hardened steel element

    Directory of Open Access Journals (Sweden)

    A. Kulawik

    2008-08-01

    Full Text Available Presented paper is focused on volumetric hardening process using liquid low melting point metal as a coolant. Effect of convective motion of the coolant on material structure after hardening is investigated. Comparison with results obtained for model neglecting motion of liquid is executed. Mathematical and numerical model based on Finite Element Metod is described. Characteristic Based Split (CBS method is used to uncouple velocities and pressure and finally to solve Navier-Stokes equation. Petrov-Galerkin formulation is employed to stabilize convective term in heat transport equation. Phase transformations model is created on the basis of Johnson-Mehl and Avrami laws. Continuous cooling diagram (CTPc for C45 steel is exploited in presented model of phase transformations. Temporary temperatures, phases participation, thermal and structural strains in hardening element and coolant velocities are shown and discussed.

  19. Influence of Partial Replacement of Nickel by Nitrogen on Microstructure and Mechanical Properties of Austenitic Stainless Steel

    Directory of Open Access Journals (Sweden)

    A. Ahmed

    2011-01-01

    Furthermore, the produced forged steels were subjected to solution treatment at different temperatures. The microstructure of produced stainless steels was observed. The X-ray diffractmeter and Mossbauer effect spectroscopy were used to follow the phase change in reference and modified steels after different heat treatment temperatures. The influence of grain-size, soluble, and insoluble nitrogen on tensile strength and hardness was investigated. The major phase in the modified steel has a fcc structure similar to the reference one, but with finer grains and more expanded lattice. The yield strength and hardness of the nitrogen-modified stainless steel are higher than the reference steel. On the other hand, the increase of nitrogen content deteriorates the steel ductility.

  20. Influence of Rare Earth on Property of Low Chromium Semi-Steel

    Institute of Scientific and Technical Information of China (English)

    LIU Jian-hua; XIE Dan-yang; LI Chang-sheng; SHAO Li; ZHANG Rui-jun

    2003-01-01

    The influence of rare earth (RE) content on mechanical properties and abrasion resistance of low chromium semi-steel was studied by means of metallographic examination, scanning electron microscopic examination and mechanical property test. The experiment results show that RE can improve the comprehensive properties, especially in combination with proper heat treatment. The optimum properties of low chromium semi-steel modified by RE of 0.25 % could be obtained by normalization at 950 ℃ for 3 h. The main reason is the change in morphology and distribution of eutectic carbide and the precipitation of granular carbides.

  1. Carbide Type Influence on Tribological Properties of Hard Faced Steel Layer - Part I - Theoretical Considerations

    Directory of Open Access Journals (Sweden)

    V. Lazic

    2010-06-01

    Full Text Available This paper gives a theoretical review of influence of the most important alloying elements on steel, and review of the most important carbide-forming elements and states the conditions which elements should fulfill in order to be considered as carbide-forming. It primarily involves alloying elements which in the iron-carbon system can form simple, complex or special carbides, i.e. phases of interstitial and substitutive type. It also gives a review of carbide types that are formed during either production or reparatory hard facing of steel parts with different types of filler materials.

  2. Influence of heat input on weld bead geometry using duplex stainless steel wire electrode on low alloy steel specimens

    Directory of Open Access Journals (Sweden)

    Ajit Mondal

    2016-12-01

    Full Text Available Gas metal arc welding cladding becomes a popular surfacing technique in many modern industries as it enhances effectively corrosion resistance property and wear resistance property of structural members. Quality of weld cladding may be enhanced by controlling process parameters. If bead formation is found acceptable, cladding is also expected to be good. Weld bead characteristics are often assessed by bead geometry, and it is mainly influenced by heat input. In this paper, duplex stainless steel E2209 T01 is deposited on E250 low alloy steel specimens with 100% CO2 gas as shielding medium with different heats. Weld bead width, height of reinforcement and depth of penetration are measured. Regression analysis is done on the basis of experimental data. Results reveal that within the range of bead-on-plate welding experiments done, parameters of welding geometry are on the whole linearly related with heat input. A condition corresponding to 0.744 kJ/mm heat input is recommended to be used for weld cladding in practice.

  3. INFLUENCE OF COLD ROLLING REDUCTION ON MICROSTRUCTURE AND MECHANICAL PROPERTIES OF TWIP STEEL

    Institute of Scientific and Technical Information of China (English)

    Z.L. Mi; D. Tang; Y.J. Dai; H.Q. Wang; S.S. Li

    2007-01-01

    The influence of cold rolling reduction on microstructure and mechanical properties of the TWIP (ttwinning induced plasticity) steel was investigated. The results indicated that the steel had better comprehensive mechanical properties when cold rolling reduction was about 65.0% and the annealing temperature was 1000℃. The tensile strength of the steel is about 640MPa and the yield strength is higher than 255MPa, while the elongation is above 82%. The microstructure is composed of austenitic matrix and annealing twins at room temperature, at the same time, a significant amount of annealing twins and stacking faults are observed by transmission electron microscopy (TEM). Mechanical twins play a dominant role during deformation, and result in excellent mechanical properties.

  4. Influence of laser power on microstructure of laser metal deposited 17-4 ph stainless steel

    Science.gov (United States)

    Adeyemi, A. A.; Akinlabi, ET; Mahamood, R. M.; Sanusi, K. O.; Pityana, S.; Tlotleng, M.

    2017-08-01

    The influence of laser power on the microstructure of 17-4 PH stainless steel produced by laser metal deposition was investigated. Multiple-trackof 17-4 stainless steel powder was deposited on 316 stainless steel substrate using laser metal deposition, an additive manufacturing process. In this research, laser power was varied between 1.0 kW and 2.6 kW with scanning speed fixed at 1.2 m/s. The powder flow rate and the gas flow rate were also kept constant at values of 5 g/min and 2 l/min respectively. The microstructure was studied under optical microscope and it revealed that the microstructure was dendritic in structure with finer and lesser δ-ferriteat low laser power while the appearance of coarse and more δ-ferriteare seen at higher laser power.

  5. Influence of selected rare earth metals on structural characteristics of 42CrMo4 steel

    Directory of Open Access Journals (Sweden)

    J. Drápala

    2016-10-01

    Full Text Available The influence of rare earth metals (REM addition on solidification structure of the low-carbon 42CrMo4 steel was investigated. Alloys were prepared by means of a centrifugal casting. The addition of cerium, praseodymium or mischmetal in the steel produced greatly improved solidification structure with a suppressed columnar grain zone, finer grain size in the equiaxed grain zone. The additions occurred in the steel bath in the form of REM oxide and/or oxide-sulphide inclusions and as dissolved REM segregated along with other elements at prior grain boundaries and interdendritic spaces. Microstructure (light microscope, SEM/EDX chemical microanalysis, and TOF-SIMS analysis – mapping of elements in the structure of alloys were obtained.

  6. Influence of Vanadium and Cast Temperature on Nitrogen Solubility of Stainless Steel

    Directory of Open Access Journals (Sweden)

    Saeed Ghali

    2014-01-01

    Full Text Available Three stainless steel grades with different vanadium content were produced in open induction furnace. The base chemical composition of investigated stainless steel has contained 18.48–18.75% Cr, 5.17–5.62% Mn, 2.47–2.58% Mo, and 6.39–6.64% Ni. The vanadium contents of the three stainless steel grades were 0.009%, 0.112%, and 0.189%. The proposed stainless steels were casted at temperatures 1753 K and 1833 K. The nitrogen contents were determined for the produced steel grades at every cast temperature. The determined nitrogen contents were compared with those calculated from the developed equation of Grigorenko and Pomarin. The influence of cast temperature and vanadium content on nitrogen solubility was investigated. Interpretation between experimental and calculated nitrogen content was carried out. Increasing vanadium content and decreasing cast temperature were found to have positive significant effect on the nitrogen solubility. There were great deviations between experimental results and those calculated by Grigorenko and Pomarin equation.

  7. Influence of Processing and Heat Treatment on Corrosion Resistance and Properties of High Alloyed Steel Coatings

    Science.gov (United States)

    Hill, Horst; Weber, Sebastian; Raab, Ulrich; Theisen, Werner; Wagner, Lothar

    2012-09-01

    Corrosion and abrasive wear are two important aspects to be considered in numerous engineering applications. Looking at steels, high-chromium high-carbon tool steels are proper and cost-efficient materials. They can either be put into service as bulk materials or used as comparatively thin coatings to protect lower alloyed construction or heat treatable steels from wear and corrosion. In this study, two different corrosion resistant tool steels were used for the production of coatings and bulk material. They were processed by thermal spraying and super solidus liquid phase sintering as both processes can generally be applied to produce coatings on low alloyed substrates. Thermally sprayed (high velocity oxygen fuel) coatings were investigated in the as-processed state, which is the most commonly used condition for technical applications, and after a quenching and tempering treatment. In comparison, sintered steels were analyzed in the quenched and tempered condition only. Significant influence of alloy chemistry, processing route, and heat treatment on tribological properties was found. Experimental investigations were supported by computational thermodynamics aiming at an improvement of tribological and corrosive resistance.

  8. Austenite steel transformations under the influence of fatigue loading

    Directory of Open Access Journals (Sweden)

    D. Skibicki

    2008-10-01

    Full Text Available Behavior of materials and structures in fatigue non-proportional loading conditions, characterized by the principal axes rotation during fatigue cycles, is an important issue because of its impact on fatigue properties. The article presents results of an analysis ofmicrostructural steel X5CrNi18-10, subjected to proportional fatigue loadings: torsion and push-pull, as well as non-proportional ones.Variability of the principal axes positions of non-proportional loadings was obtained by using a loading program with alternately realized torsion and tension-compression blocks. The work includes an analysis of one-phase microstructure and microhardness tests of fatigue samples were carried out. The cyclic loading value accepted for the tests caused an martensite transformation induced by plastic strain and occurrence of slip bands in the grains of austenite. A comparative analysis revealed differences in the transformation intensity, depending on the type of applied loading and on the degree of its non-proportionality.

  9. Microbiologically influenced corrosion (MIC) in stainless steel heat exchanger

    Energy Technology Data Exchange (ETDEWEB)

    Huttunen-Saarivirta, E., E-mail: elina.huttunen-saarivirta@tut.fi [Laboratory of Materials Characterization, Department of Materials Science, Tampere University of Technology, P.O.B. 589, FI-33101 Tampere (Finland); Honkanen, M.; Lepistoe, T.; Kuokkala, V.-T. [Laboratory of Materials Characterization, Department of Materials Science, Tampere University of Technology, P.O.B. 589, FI-33101 Tampere (Finland); Koivisto, L. [Andritz Oy, Recovery and Power Division, P.O. Box 184, FI-78201 Varkaus (Finland); Berg, C.-G. [Andritz Pulp and Paper, Tammasaarenkatu 1, FI-00180 Helsinki (Finland)

    2012-06-15

    Corrosion attack in the form of corrosion product tubercles was observed in an AISI 304 (EN 1.4301) stainless steel heat exchanger only after 36 months of service. Failure analyses revealed that in one of the attacked areas corrosion had penetrated the entire wall thickness of 6.2 mm, but in most of the cases it reached the depth of 2-4 mm. In this paper, we report the results from a thorough microstructural characterization of the corroded heat exchanger carried out with optical microscopy (OM), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), transmission electron microscopy (TEM) and X-ray diffractometry (XRD). Microstructural studies by OM, SEM and XRD revealed a two-phase structure of austenite and ferrite in the bulk material, as well as the preferential attack of the ferrite phase. SEM surface studies disclosed bacteria in and close to the attacked areas. Cross-sectional SEM examinations showed the distribution and composition of corrosion products within and underneath the tubercles. TEM and XRD studies gave information about the amorphous and/or nanocrystalline nature of some of the formed corrosion products. These results are discussed in this paper and, based on them, the main corrosion mechanism for the observed attack is suggested. Further, explanations for the propagation of corrosion along the ferrite phase are presented.

  10. Modelling the influence of steel fibres on the electrical resistivity of cementitious composites

    DEFF Research Database (Denmark)

    Solgaard, Anders Ole Stubbe; Michel, Alexander; Stang, Henrik

    2009-01-01

    work concerns the electrical resistivity of cementitious composites and some of the parameters influencing it in order to get a more thorough understanding of the factors governing the overall resistivity. The basis of the present study is an experimental investigation of the electrical resistivity...... the overall resistivity of the material and thereby the corrosion rate of the embedded reinforcement. To the knowledge of the authors, only preliminary studies have been made on the influence of corrosion of the reinforcement bars from the addition of the electrical conductive steel fibres. Thus the present......One of the governing factors on the corrosion of embedded reinforcement is the electrical resistivity of the concrete. The combination of steel fibres and conventional reinforcement bars has been used in a number of structures. However, the addition of electrical con-ductive fibres might influence...

  11. Influence of Thermal Aging on Material Strength Behavior in Grade 91 Steel

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Hyeong-Yeon; Kim, Woo-Gon [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-10-15

    In this study, the influence of thermal aging on yield strength and ductility for Grade 91 steel has been investigated. Service exposed Gr.91 steel materials sampled from a piping system of an ultra-supercritical plant over 73716 hours were used for material testing. The test results were compared with those of the virgin Gr.91 steel and those data were compared with RCC-MRx data. In this study, thermal aging effect of Gr.91 steel on the strength and ductility has been investigated. It was shown that yield strength has dropped as much as 35.8% over the service exposed duration of 8.4 years while ductility has been improved up to 23%. Since the present design rules of ASME Code and RCC-MRx do not provide concrete strength reduction factors for the thermal aging, it was shown to be necessary based on the findings of the present study to take this thermal aging influence into account in those design codes so that the design outcomes are to be more reliable.

  12. Influence of hydrogen on formability and bendability of DP1180 steel for car body application

    Science.gov (United States)

    Gao, Q.; Han, F.; Wortberg, D.; Bleck, W.; Liewald, M.

    2016-11-01

    In order to reach future light weight targets, it is increasing necessary to use advanced high strength steels with tensile strength 980 MPa or higher in automotive body-inwhite structures. Due to the sensitivity to hydrogen embrittlement and the limited understanding of various aspects of hydrogen embrittlement on processing and function, the wide application of these steels is still limited. In the current work, the influence of hydrogen on the multiaxial forming behavior was investigated by determining the forming limit curve and bending limit curve of DP1180 steel. Hydrogen concentration in the material was modified by cathodic charging. Then Nakajima tests on hydrogen uncharged and pre-charged samples were carried out in order to adjust and study different strain states resulting in the forming limit curve. In the study of bending limit curve, the steel sheets were pre-strained by Marciniak test. Bending load on the uncharged and pre-charged samples was introduced by VDA238-100 bending tests. The experimental results indicated that the presence of hydrogen affected the formability and bendability of DP1180 steel. A clear difference in the influence of hydrogen at different strain states was observed. When formed in a biaxial strain state via the Nakajima test, the material showed the highest degradation in formability. Moreover, the samples with biaxial pre-loading showed more degradation in bendability comparing to those pre-strained in plane strain and uni-axial paths. Fractography by scanning electron microscope gave evidence of hydrogen-induced cleavage fracture on pre-charged Nakajima samples. Thus this investigation improves the understanding of influences of hydrogen on forming processes and provides important evidence for further studies on HE susceptibility of AHSS for the application on car body constructions.

  13. MICROBIOLOGICALLY INFLUENCED CORROSION ON WELD OF STAINLESS STEEL 304L

    Institute of Scientific and Technical Information of China (English)

    1998-01-01

    The influence of welding defects on MIC (microbiologically influenced corrosion) was studied.The open circuit potential (OCP) was measured during MIC test. It was found that OCP shifted to a higher level when the system was inoculated with bacteria and it decreased dramatically when MIC started. Among a series of welding defects golden heat tint was found the most susceptible to MIC. The tubercles over pitting were observed with SEM. Some elements inside of the tubercles were analysed with EDXA. Microbiological analysis of a corroded and a non-corroded sample revealed no significant difference between them with the exception of the number of the manganeseoxidising bacteria.

  14. The factors influencing urinary arsenic excretion and metabolism of workers in steel and iron smelting foundry.

    Science.gov (United States)

    Shuhua, Xi; Qingshan, Sun; Fei, Wang; Shengnan, Liu; Ling, Yan; Lin, Zhang; Yingli, Song; Nan, Yan; Guifan, Sun

    2014-01-01

    In order to evaluate the degree of arsenic (As) exposure and the factors influencing urinary As excretion and metabolism, 192 workers from a steel and iron smelting plant, with different type of work in production such as roller, steel smelting, iron smelting and metallic charge preparation, were recruited. Information about characteristics of each subject was obtained by questionnaire and inorganic As (iAs), monomethylarsonic acid (MMA), dimethylarsinic acid (DMA) in urine were determined. The results showed that steel smelters had significantly higher concentrations of DMA and total As (TAs) than rollers and metallic charge preparation workers, and iron and steel smelters had a higher value of primary methylation index and lower proportion of the iAs (iAs%) than rollers and metallic charge preparation workers. In steel smelters, urinary As level exceeded the biological exposure index (BEI) limit for urinary As of 35 μg/l by 65.52%, and higher than metallic charge preparation workers (35.14%). The individuals consumed seafood in recent 3 days had a higher TAs than the individuals without seafood consumption. Multivariate logistic regression analysis showed that different jobs, taken Chinese medicine of bezoar and seafood consumption in recent 3 days were significantly associated with urinary TAs exceeded BEI limit value 35 μg/l. Our results suggest that workers in steel and iron smelting plant had a lower level of As exposure, and seafood consumption and taking Chinese medicine of bezoar also could increase the risk of urinary TAs exceeded BEI limit value.

  15. Influence of solution annealing on microstructure and mechanical properties of Maraging 300 steel

    Energy Technology Data Exchange (ETDEWEB)

    Lima Filho, Venceslau Xavier; Barros, Isabel Ferreira; Abreu, Hamilton Ferreira Gomes de, E-mail: venceslau@ifce.edu.br [Universidade Federal do Ceara (UFC), Fortaleza, CE (Brazil). Departamento de Engenharia Metalurgica e Materiais. Laboratorio de Caracterizacao de Materiais, Metalurgia Fisica e Grupo de Pesquisa de Transformacao de Fase

    2017-01-15

    Maraging 300 belongs to a family of metallic materials with extremely high mechanical strength and good toughness. Some works have been published about aging temperatures that improve ultimate strength resistance with acceptable toughness levels in this steel family, where the prior austenite grain size obtained by different solution annealing temperature influence in the final mechanical properties. Solution annealing temperatures ranging from 860 °C to 1150 deg C and were kept constant until the aging temperature. These treatments were used in order to investigate their influence on the microstructure and mechanical properties of maraging steel 300, especially with regard to toughness. The characterization of the microstructure was performed by optical microscopy, scanning electron microscope (SEM) and X-ray diffraction (XRD). Mechanical properties were evaluated by Rockwell C hardness and Charpy impact tests. The results showed that there is a temperature range where one can get some improvement in toughness without a large loss of mechanical strength. (author)

  16. Influence of the Inclusion Shape on the Rolling Contact Fatigue Life of Carburized Steels

    Science.gov (United States)

    Neishi, Yutaka; Makino, Taizo; Matsui, Naoki; Matsumoto, Hitoshi; Higashida, Masashi; Ambai, Hidetaka

    2013-05-01

    It has been well known that the flaking failure in rolling contact fatigue (RCF) originates from nonmetallic inclusions in steels, and their apparent size is one of the important factors affecting RCF life. However, the influence of inclusion shape on the RCF life has not been fully clarified. In this study, attention was paid to the influence of the inclusion shape on the RCF life. This was evaluated by using carburized JIS-SCM420 (SAE4320) steels that contained two different shapes of MnS—stringer type and spheroidized type—as inclusions. Sectional observations were made to investigate the relation between the occurrence of shear crack in the subsurface and the shape of MnS. It was found that the RCF life was well correlated with the length of MnS projected to the load axis, and the initiation of shear crack in subsurface was accelerated as the length of MnS increased.

  17. INFLUENCE OF LASER CUTTING ON THE FATIGUE LIMIT OF TWO HIGH STRENGTH STEELS

    OpenAIRE

    Mateo García, Antonio Manuel; Fargas Ribas, Gemma; Calvo Muñoz, Jessica; Roa Rovira, Joan Josep

    2013-01-01

    Laser cutting is widely used in the metal industry, particularly when components of high strength steels sheets are produced. On the other hand, the roughness of cut - edges produced by laser differs from that obt ained by other methods, such as mechanical blank ing, and this fact influence s the fatigue performance. Moreover, thermal effects are another factor to consider. In the present investigation, specimens of two grades of high strength ...

  18. Influence of the microstructure on steel hardening in pulsed plasma nitriding

    OpenAIRE

    Ochoa, EA; Figueroa, CA

    2008-01-01

    The plasma technologies are widely used in metal surface engineering processes. Basically, these treatments improve the mechanical, tribological, and chemical properties of the material such as wear resistance, hardness, fatigue resistance, friction, and corrosion resistance. In this work, a comprehensive study of the influence of the microstructure on hardness of AISI P20 steel treated at different temperatures and times by pulsed plasma nitriding is reported. The processes were done by usin...

  19. Velocity hardening influence on the martensite transformation nature in constructional average alloy steel

    Institute of Scientific and Technical Information of China (English)

    Tsellermaer; V.; V.; Popova; N.; A.; Klimashin; S.; I.; Tihonikova; O.; V.; Konovalov; S.; V.; Kozlov; E.; V.; Gromov; V.; E.

    2005-01-01

    The quantitative study of the hardening velocity influence on the α-phase morphology in 30CrNi3MoVA (0.3% C, 1% Cr,3% Ni, 1% Mo, 1% V) cast average alloy steel after gomogenization (1125℃, 13 h), normalizing (980℃, 10 h) and high tempering (660℃, 10 h. with cooling on air) is the aim of this work.……

  20. Velocity hardening influence on the martensite transformation nature in constructional average alloy steel

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    @@ The quantitative study of the hardening velocity influence on the α-phase morphology in 30CrNi3MoVA (0.3% C, 1% Cr,3% Ni, 1% Mo, 1% V) cast average alloy steel after gomogenization (1125℃, 13 h), normalizing (980℃, 10 h) and high tempering (660℃, 10 h. with cooling on air) is the aim of this work.

  1. Influence of Geometrical Imperfections on Analyses of Door Openings in Tubular Steel Towers for Wind Turbines.

    OpenAIRE

    Tran, Anh Tuan; Veljkovic, Milan, ed. lit.; Rebelo, Carlos; Da Silva, Luís Simões

    2014-01-01

    Towers for wind turbines are very sensitive to geometrical imperfections. Pattern and amplitude of imperfections significantly influence the strength of the towers. Rather limited number of experiments exists on a tubular tower like structure and no experiments are available considering door opening in towers with cylindrical or polygonal cross-section. One of the objectives of the RFCS research project “HIGH STEEL TUBULAR TOWERS FOR WIND TURBINES, HISTIWIN2” was to investigate current practi...

  2. Influence of Organic Inhibitor on Corrosion Resistance of Steel in Simulated Concrete Pore Solution

    OpenAIRE

    Cai, Jingshun S.; C. C. CHEN; Liu, J. Z.; Liu, J. P.

    2014-01-01

    Organic corrosion inhibitor is one of lower cost technologies that limit the deterioration of concrete structures. The influence of a newly prepared organic corrosion inhibitor on the corrosion behavior of carbon steel in simulated concrete pore solution was investigated by polarization curves, electrochemical impedance spectroscopy, and so on. The effect of organic corrosion inhibitors on concrete working performance was also studied. The results show that the corrosion rate decreases with t...

  3. Technical Progress of Domestic Iron & Steel Industry and Its Influence on the Development of Refractories

    Institute of Scientific and Technical Information of China (English)

    XINGShouwei; LIUJiehua

    2001-01-01

    The quick increase of domestic iron and steel output,the great improvement of steel quality and variety,the improtation of advanced equipment and the diminution and elimination of some backward technology and facilities have brought about great influence on the development of refracetories.In order to meet the technical progress of iron and steel industry,domestic refractories industry has,in the last industry,domestic refractories industry has,in the last decades ,concentrated its efforts on the development and production of new Sialon bonded SiC bricks and micropore carbon blocks for giant blast furnaces;new refractories for coke oven and non-coke iron making furnaces;MgO-C bricks for converters and electric conductive refractories for UHP EAF;refractories for slag splashing technology;and the highy technology-intensive refractories for continuous casting facilities.The paper reviews the great change occurred in the industries of iron-and steel-making and refratories during the last decaldes.

  4. Influence of thermal aging on microstructure and mechanical properties of CLAM steel

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Lixin, E-mail: lxhuang@ysu.edu.cn [State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 (China); Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 (China); Hu, Xue; Yang, Chunguang; Yan, Wei [Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 (China); Xiao, Furen [State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 (China); Shan, Yiyin, E-mail: yyshan@imr.ac.cn [Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 (China); Yang, Ke [Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 (China)

    2013-11-15

    In order to investigate the influence of thermal aging on microstructure and mechanical properties of CLAM (China low activation martensitic) steel, a comparison study was made on the as-tempered and the aged steels. The tempered CLAM steels were subjected to aging treatment at 600 °C for 1100 h and 3000 h, and at 650 °C for 1100 h, respectively. The changes of microstructure were characterized by both transmission electron microscope (TEM) and scanning electron microscope (SEM). The mechanical properties were evaluated by Charpy impact, tensile and Vickers hardness tests. The upper shelf energy (USE) of the thermal aged CLAM steel decreased with the extension of aging time, while the yield strength changed slightly. After long-term thermal aging, the MX type precipitates remained stable. The coarsening of M{sub 23}C{sub 6} and the formation of Laves phase were confirmed by scanning/transmission electron microscopes. The Laves phase was the main factor leading to the increase of DBTT.

  5. Influence of thermal aging on microstructure and mechanical properties of CLAM steel

    Science.gov (United States)

    Huang, Lixin; Hu, Xue; Yang, Chunguang; Yan, Wei; Xiao, Furen; Shan, Yiyin; Yang, Ke

    2013-11-01

    In order to investigate the influence of thermal aging on microstructure and mechanical properties of CLAM (China low activation martensitic) steel, a comparison study was made on the as-tempered and the aged steels. The tempered CLAM steels were subjected to aging treatment at 600 °C for 1100 h and 3000 h, and at 650 °C for 1100 h, respectively. The changes of microstructure were characterized by both transmission electron microscope (TEM) and scanning electron microscope (SEM). The mechanical properties were evaluated by Charpy impact, tensile and Vickers hardness tests. The upper shelf energy (USE) of the thermal aged CLAM steel decreased with the extension of aging time, while the yield strength changed slightly. After long-term thermal aging, the MX type precipitates remained stable. The coarsening of M23C6 and the formation of Laves phase were confirmed by scanning/transmission electron microscopes. The Laves phase was the main factor leading to the increase of DBTT.

  6. Influence of austenite grain size on recrystallisation-precipitation interaction in a V-microalloyed steel

    Energy Technology Data Exchange (ETDEWEB)

    Quispe, A. [National University ' Jorge Basadre' , Av. Miraflores s/n, University City, Tacna (Peru)]. E-mail: abqc@unjbg.edu.pe; Medina, S.F. [National Center for Metallurgical Research (CENIM), Av. Gregorio del Amo 8, 28040-Madrid (Spain)]. E-mail: smedina@cenim.csic.es; Gomez, M. [National Center for Metallurgical Research (CENIM), Av. Gregorio del Amo 8, 28040-Madrid (Spain); Chaves, J.I. [National Center for Metallurgical Research (CENIM), Av. Gregorio del Amo 8, 28040-Madrid (Spain)

    2007-02-25

    By means of torsion tests using small specimens, the influence of austenite grain size on strain induced precipitation kinetics has been determined in a vanadium microalloyed steel. Determination of recrystallisation-precipitation-time-temperature (RPTT) diagrams for two austenite grain sizes allows values of the aforementioned magnitudes to be determined. An ample discussion is made of the quantitative influence found and its relation with nucleation and growth mechanisms of precipitates. The results are compared with the quantitative influence exerted by the other variables, reaching the conclusion that the austenite grain size has a notable influence on strain induced precipitation kinetics which should not be underestimated. Finally, the influence of austenite grain size is included in a strain induced precipitation model constructed by the authors of this work and which also takes into account the other aforementioned variables.

  7. The influence of the residual copper on the pipes steel hot plasticity according to environmental requirements

    Directory of Open Access Journals (Sweden)

    Rusănescu C.O.

    2013-01-01

    Full Text Available Considering the importance of gaseous and/or liquid fuels impact on the environment, the resistance of pipelines at hot plastic deformation is important. Therefore, in order to avoid or reduce any adverse impact on the environment, the influence of residual copper on hot deformability of steel pipes was investigated in this paper. The negative copper influence was experimentally proved using torsion deformation at temperatures above 1000o, under the air and argon atmosphere. The samples were heated and then deformed at different temperatures with constant deformation rate. Also, structural analysis of investigated materials was done, using metallographic and SEM analysis.

  8. Influence of Austenitizing Heat Treatment on the Properties of the Tempered Type 410-1Mo Stainless Steel

    Science.gov (United States)

    Mabruri, E.; Syahlan, Z. A.; Sahlan; Prifiharni, S.; Anwar, M. S.; Chandra, S. A.; Romijarso, T. B.; Adjiantoro, B.

    2017-05-01

    The modified 410-1Mo stainless steel has been developed with higher tensile strength and elongation compared to the standard 410 stainless steel. This paper reports the influence of austenitizing temperature on the microstructure, hardness, impact resistance and corrosion resistance of the modified 410-1Mo steel. The steel samples were prepared by a process sequence of induction melting, hot forging, annealing, hardening, and tempering. The microstructure of the tempered steels revealed additional phase of delta ferrite at pre-austenitizing temperatures of 950 to 1050 °C and disappeared at a temperature of 1100 °C. The steels which underwent pre-austenitizing at 1100 °C showed the largest sized lath martensite and the largest amount of retained austenite. The tempered steels maintained hardness at austenitizing temperatures of 950 °C to 1000 °C and showed an increasing hardness at austenitizing temperatures from 1000 to 1100 °C. At a range of austenitizing temperatures, it was investigated that the steels exhibited higher impact resistance at 1050 °C. The tempered steels that were pre-austenitized at 950 °C and 1100 °C showed the lowest pitting potential due to the existence of carbides and coarse-high carbon martensite, respectively.

  9. Influence of initial thermomechanical treatment on high temperature properties of laves phase strengthened ferritic steels

    Energy Technology Data Exchange (ETDEWEB)

    Talik, Michal

    2016-07-01

    The aim of this work was to design 17 wt%Cr Laves phase strengthened HiperFer (High performance Ferrite) steels and evaluate their properties. This class of steel is supposed to be used in Advanced Ultra Super Critical power plants. Such cycles exhibit higher efficiency and are environmentally friendly, but improved materials with high resistance to reside/steam oxidation and sufficient creep strength are required. The work focused on the characterization of creep properties of 17Cr2.5W0.5Nb0.25Si heat resistant steel. Small batches of steels with nominal compositions of 17Cr3W0.5Nb0.25Si and 17Cr3W0.9Nb0.25Si were used to analyze the influence of chemical composition on the precipitation behaviour in comparison to 17Cr2.5W0.5Nb0.25Si steel. Creep strength of HiperFer steels is ensured by ne dispersion of thermodynamically stable Laves phase particles, while maintaining high corrosion resistance by a relatively high chromium content. Design of HiperFer steels was accomplished by thermodynamic modeling (Thermocalc) with the main tasks of elimination of the unwelcome brittle (Fe,Cr)-σ phase and maximization of the content of the strengthening C14 Fe{sub 2}Nb type Laves phase particles. Long term annealing experiments of all HiperFer steels were performed at 650 C in order to evaluate the role of chemical composition and initial thermo-mechanical treatment state on precipitation behaviour. Laves phase particles formed quickly after few hours and the size of precipitates did not change significantly within 1,000 hours. The observed development of Laves phase particles was compared with thermodynamical calculations (TC-Prisma). The creep properties of 17Cr2.5W0.5Nb0.25Si steel in different initial thermo-mechanical treatment states were tested at 650 C. The influence of different cold rolling procedures, and heat treatments was investigated. Increased cold rolling deformation had a positive effect resulting not only from work hardening, but from the acceleration of

  10. Influence of diffusion time on steel-mushy Al-7graphite bonding

    Institute of Scientific and Technical Information of China (English)

    杜云慧; 张鹏; 曾大本; 崔建忠; 巴利民

    2002-01-01

    The bonding of steel plate to Al-7graphite slurry was conducted using casting rolling technique. The influence of diffusion time on interfacial mechanical property and structure of bonding plate was studied. The results show that: under the condition of 510℃ for preheat temperature of steel plate and 32% of solid fraction of Al-7graphite slurry, the relationship between interfacial shear strength S and diffusion time t is S=25.3+4.47t-0.133t2+0.001t3. When diffusion time is 22.5s, the largest interfacial shear strength 69.9MPa is got, and the corresponding interface is made up of Fe-Al compound and Fe-Al solid solution alternatively and in a right proportion.

  11. Influence of isothermal quenching of LAMC CrMnSi cast steel on impact toughness

    Institute of Scientific and Technical Information of China (English)

    JIN Bao-shi; HUANG Zhi-qiu; SHEN Da-dong

    2005-01-01

    The influence of isothermal quenching process of low-alloy and medium carbon (LAMC) CrMnSi cast steel on the impact toughness was investigated. The microstructure and mechanical property of LAMC CrMnSi cast steel were analyzed by the laser optical modulator, the scanning electron microscopy, the energy dispersive spectrometer, the hardness and impact tests. The experimental results show that the dual phases of bainite and residual austenite can be obtained by the severity isothermal quenching, the fractographies of specimens change from quasi-cleavage to dimple at 310 ℃ for 60 min, the impact toughness for specimens at the room temperature isothermally achieves 130 J/cm2, meantime and its hardness is more than 45(HRC).

  12. Influence of Mn Content and Hot Deformation on Transformation Behavior of C-Mn Steels

    Institute of Scientific and Technical Information of China (English)

    LI Long; DING Hua; DU Lin-xiu; WEN Jing-lin; SONG Hong-mei; ZHANG Pi-jun

    2008-01-01

    The hot deformation behaviors and the microstructural evolution of plain C-Mn steels with similar contents of C and Si but different contents of Mn have been investigated by compressive processing using Gleeble-1500 mechanical simulator. Influence of Mn and hot deformation on continuous cooling transformation of steels has been studied. The experimental results showed that deformation in austenite region accelerated transformation process, and the extent is dependent on the hot deformation and cooling conditions. The hot deformation would promote transformation process, but the increase of transformation temperature is dependent on Mn contents. The results have also shown that the effect of deformation on ferrite transformation becomes more obvious with the increase of Mn content at relatively low cooling rate.

  13. Influence of Hot Rolling Conditions on the Mechanical Properties of Hot Rolled TRIP Steel

    Institute of Scientific and Technical Information of China (English)

    LI Zhuang; WU Di

    2008-01-01

    Influence of hot rolling conditions on the mechanical properties of hot rolled TRIP steel was investigated.Thermomechanical control processing(TMCP)was conducted by using a laboratory hot rolling mill,in which three different kinds of finish rolling temperatures were applied.The results show that polygonal ferrite,granular bainite and larger amount of stabilized retained anstenite can be obtained by controlled rolling processes.The finer ferrite grain size is produced through the deformation induced transformation during deformation rather than after deformation,which affects the mechanical properties of hot rolled TRIP steel.Mechanical properties increase with decreasing finish rolling temperature due to the stabilization of retained austenite.Ultimate tensile strength(UTS),total elongation(TEL)and the product of ultimate tensile strength and total elongation(UTS×TEL)reaches optimal values(791 MPa,36% and 28 476 MPa%,respectively)whenthe specimen was hot rolled for 50% reduction at finish rolling temperature of 700℃.

  14. Wide – Ranging Influence of Mischmetal on Properties of GP240GH Cast Steel

    Directory of Open Access Journals (Sweden)

    J. Kasińska

    2012-12-01

    Full Text Available This paper presents influence of rare earth metals (REM on the properties of GP240GH cast carbon steel. The research has beenperformed on successive industrial melts. Each time ca 2000 kg of liquid metal was modified. The rare earth metals were put into the ladle during tapping of heat melt from the furnace. Because of this the amount of sulphur in the cast steel was decreased and the non-metallic inclusion morphology was significantly changed. It was found that non metallic inclusions the cracking mechanism of Charpy specimens and the impact strength were all changed. The following properties were tested: mechanical properties (y, UTS, plastic properties (necking, elongation and impact strength (SCI. In the three-point bend test the KJC stress intensity factor was evaluated.

  15. Wide – Ranging Influence of Mischmetal on Properties of GP240GH Cast Steel

    Directory of Open Access Journals (Sweden)

    Kasińska J.

    2012-12-01

    Full Text Available This paper presents influence of rare earth metals (REM on the properties of GP240GH cast carbon steel. The research has been performed on successive industrial melts. Each time ca 2000 kg of liquid metal was modified. The rare earth metals were put into the ladle during tapping of heat melt from the furnace. Because of this the amount of sulphur in the cast steel was decreased and the non-metallic inclusion morphology was significantly changed. It was found that non metallic inclusions the cracking mechanism of Charpy specimens and the impact strength were all changed. The following properties were tested: mechanical properties (σy, σUTS, plastic properties (necking, elongation and impact strength (SCI. In the three-point bend test the KJC stress intensity factor was evaluated.

  16. THIN-WALLED CROSS SECTION SHAPE INFLUENCE ON STEEL MEMBER RESISTANCE

    Directory of Open Access Journals (Sweden)

    Elżbieta Urbańska-Galewska

    2016-03-01

    Full Text Available This work describes why trending thin-walled technology is achieving popularity in steel construction sector. A purpose of this article is to present the influence of the cold-formed element cross-section shape on an axial compression and a bending moment resistance. The authors have considered four different shapes assuming constant section area and thickness. Calculations were based on three different steel grades taking into account local, distortional and overall buckling. The results are presented in a tabular and a graphical way and clearly confirm that cross-section forming distinctly impact the cold-formed member resistance. The authors choose these cross-sections that work better in compression state and the other (those slender and high that function more efficiently are subjected to bending.

  17. The influence of dew point during annealing on the power loss of electrical steel sheets

    Energy Technology Data Exchange (ETDEWEB)

    Broddefalk, Arvid [Development and Market Research, Cogent Power Ltd., P.O. Box 201, SE-735 23 Surahammar (Sweden)], E-mail: arvid.broddefalk@sura.se; Jenkins, Keith [Development and Market Research, Cogent Power Ltd., P.O. Box 201, SE-735 23 Surahammar (Sweden); Silk, Nick [Corus RD and T, Swinden Technology Centre, Moorgate Rotherham S60 3AR (United Kingdom); Lindenmo, Magnus [Development and Market Research, Cogent Power Ltd., P.O. Box 201, SE-735 23 Surahammar (Sweden)

    2008-10-15

    Decarburization is a necessary part of the processing of electrical steels if their carbon content is above a certain level. The process is usually carried out in a wet hydrogen-nitrogen atmosphere. Having a high dew point has a negative influence on the power loss, though. This is due to oxidation of the steel, which hinders domain wall motion near the surface. In this study, an increase of the power loss was only observed at a fairly high dew point (>20 deg. C). It was also only at these high dew points where a subsurface oxide layer was observed. The surfaces of samples with and without this layer were etched in steps. The magnetic properties of the etched samples corresponded well with the expected behavior based on GDOES profiles of the samples.

  18. Influence of formulated neem seed oil and jatropha curcas seed oil on wire drawing of mild steel and medium carbon steel at elevated temperatures

    Directory of Open Access Journals (Sweden)

    Mamuda Muhammad

    2016-09-01

    Full Text Available So many facets of hot wire drawing process, despite its extensive and long time employment in the industries, still remain unclear, due to want of systematic investigation of the process. This work investigated the influence of formulated neem seed and jatropha seed oil as lubricants, using antimony dialkyl dithiocarbamates (ADTC as an additive, on wire drawing process. The suitability of the bio-based oils in friction and wear control during wire drawing process were investigated, using a four ball tester. Experimental drawing process, using a Tungsten Carbide die and the formulated lubricants was carried out on mild steel and medium carbon steel rod (6 and 8mm diameter respectively at temperatures from 20OC to 750OC, on a drawing bench. The stresses and the temperature distribution profiles along the work-piece were reported. Up to 45% of reductions in area, without wire fracture, achieved on the drawing of the medium carbon steel have equally been reported.

  19. Influence of Alloying Elements Corrosion Resistance of Cold on Mechanical Properties and Rolled C-Mn-Si TRIP Steels

    Institute of Scientific and Technical Information of China (English)

    ZHANG Ling-yun; WU Di; LI Zhuang

    2012-01-01

    The rust layer plays an important role in the corrosion of steel in chlorinated environments. Salt spray, po- tentiodynamic polarization curve and tensile test were conducted in laboratory for the specimens after two-stage heat treatment. The influence of the alloying elements on mechanical properties and corrosion resistance of three kinds of steels was investigated by observing the microstructure and the morphologies of rust layer. The results show that the highest value (29%) of total elongation for steel A is obtained. The mechanical property of the specimen for steel C exhibits best strength ductility balance (21 384 MPa ·%) because of the presence of the multiphase microstructures after a two-stage heat treatment and the addition of the alloying elements. The corrosion products are known to be a complex mixture of Fe3O4 , Fe2O3 and α-FeOOH for steel C. The presence of the alloying elements results in the for mation of compact and dense rust layers in steel B and C. Passive film protects the substrate of TRIP (transformation induced plasticity) steel containing a complex mix of multiphase. Superior corrosion performance is exhibited for steel C with low alloying contents due to the enrichment of alloying elements within the rust layers.

  20. Influence of thermo-mechanical treatment on the tensile properties of a modified 14Cr–15Ni stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Vijayanand, V.D., E-mail: vdvijayanand@igcar.gov.in; Laha, K.; Parameswaran, P.; Nandagopal, M.; Panneer Selvi, S.; Mathew, M.D.

    2014-10-15

    The titanium modified 14Cr–15Ni austenitic stainless steel is used as clad and wrapper material for fast breeder nuclear reactor. Thermo-mechanical treatments consisting of solution annealing at two different temperatures of 1273 and 1373 K followed by cold-work and thermal ageing have been imparted to the steel to tailor its microstructure for enhancing strength. Tensile tests have been carried out on the thermo-mechanically treated steel at nominal strain rate of 1.6 × 10{sup −4} s{sup −1} over a temperature range of 298–1073 K. The yield stress and the ultimate tensile strength of the steel increased with increase in solution treatment temperature and this has been attributed to the fine and higher density of Ti(C,N) precipitate. Tensile flow behaviour of the steel has been analysed using Ludwigson and Voce constitutive equations. The steel heat treated at higher solution temperature exhibited earlier onset of cross slip during tensile deformation. The rate of recovery at higher test temperatures was also influenced by variations in solution heat treatment temperature. In addition, dynamic recrystallization during tensile deformation at higher temperatures was profound for steel solution heat-treated at lower temperature. The differences in flow behaviour and softening mechanisms during tensile testing of the steel after different heat treated conditions have been attributed to the nature of Ti(C,N) precipitation.

  1. Influence of the tempurature and rate conditions of deformation on the mechanical properties of 15Kh5M steel

    Energy Technology Data Exchange (ETDEWEB)

    Muckhin, V.N.; Nikulina, O.A.; Teplova, N.I.; Vatnik, L.E.

    1986-10-01

    This paper studies the influence of temperature and rate conditions of deformation of 15Kh5M steel on its mechanical properties for the purpose of determination of the sensitivity of the steel to deform rate, features of the change in uniform and concentrated plasticity, and the deformation capacity in long operating times, since 15Kh steel is widely used for production of the tubular coils of furnances of catalytic reformers of gasolines, which operate at temperatures up to 873 K and a pressure up to 6 MPa in a dangerously explosive medium.

  2. Study of pitting corrosion in line-pipe steel under the influence of remanent magnetization

    Energy Technology Data Exchange (ETDEWEB)

    Espina-Hernandez, J.H.; Caleyo, F.; Hallen, J.M. [Instituto Politecnico Nacional (IPN), Zacatenco (Mexico)

    2009-07-01

    The influence of remanent magnetization on pitting corrosion in line-pipe steels is studied. Pitting corrosion experiments have been carried out on samples of an API 5L grade 52 steel under a magnetization level of the same order of magnitude of the remanent magnetization in the pipeline wall after in-line inspection based on magnetic flux leakage. The samples were magnetized using rings of the same grade as the investigated steel. Immediately after magnetization, the investigated samples were subjected to pitting by immersing them in a solution containing dissolved Cl{sup -} and SO{sup 2-}{sub 4} and ions. The pitting experiments were conducted during a seven days period. The pit depth distribution and the maximum pit depth in each sample were recorded and used to conduct extreme value analyses of the pitting process in magnetized and non-magnetized control samples. The statistical assessment of the pitting corrosion data collected during this study shows that the magnetic field reduces the average depth of the pit population and also the extreme pit depth values that can be predicted from the maximum values observed in the magnetized samples in comparison with to the non-magnetized control samples. Scanning electron microscopy observations show that the magnetic field alters the pit morphology by increasing the pit mouth opening. (author)

  3. Influence of silicon addition on the mechanical properties and corrosion resistance of low-alloy steel

    Indian Academy of Sciences (India)

    M Hebda; H Dębecka; J Kazior

    2015-12-01

    The addition of silicon to low-alloy steel allows to modify the materials' microstructure and thus to improve their corrosion resistance and mechanical properties. The influence of adding different amounts of silicon on the properties (density, transverse rupture strength, microhardness and corrosion resistance) and microstructure of low-alloy steel was investigated. Samples were prepared via the mechanical alloying process, which is the most useful method to homogeneously introduce silicon to low-alloy steel. Sintering was performed by using the spark plasma sintering (SPS) technique. After the SPS process, half of each of the obtained samples was heat-treated in a vacuum furnace. The results show that high-density materials were achieved, and a homogeneous and fine microstructure was obtained. The investigated compositions containing 1 wt% of silicon had better corrosion resistance than samples with 3 wt% of silicon addition. Furthermore, corrosion resistance as well as the mechanical and plastic properties of the samples with 1 wt% of silicon can be further improved by applying heat treatment.

  4. Study of pitting corrosion in line-pipe steel under the influence of remanent magnetization

    Energy Technology Data Exchange (ETDEWEB)

    Espina-Hernandez, J.H.; Caleyo, F.; Hallen, J.M. [Instituto Politecnico Nacional (IPN), Zacatenco (Mexico)

    2009-07-01

    The influence of remanent magnetization on pitting corrosion in line-pipe steels is studied. Pitting corrosion experiments have been carried out on samples of an API 5L grade 52 steel under a magnetization level of the same order of magnitude of the remanent magnetization in the pipeline wall after in-line inspection based on magnetic flux leakage. The samples were magnetized using rings of the same grade as the investigated steel. Immediately after magnetization, the investigated samples were subjected to pitting by immersing them in a solution containing dissolved Cl{sup -} and SO{sup 2-}{sub 4} and ions. The pitting experiments were conducted during a seven days period. The pit depth distribution and the maximum pit depth in each sample were recorded and used to conduct extreme value analyses of the pitting process in magnetized and non-magnetized control samples. The statistical assessment of the pitting corrosion data collected during this study shows that the magnetic field reduces the average depth of the pit population and also the extreme pit depth values that can be predicted from the maximum values observed in the magnetized samples in comparison with to the non-magnetized control samples. Scanning electron microscopy observations show that the magnetic field alters the pit morphology by increasing the pit mouth opening. (author)

  5. The influence of self-compacting steel fibre reinforced concrete infill on the flexure strength and ductility of masonry walls

    OpenAIRE

    Oliveira, Luiz António Pereira de; Bernardo, Luís Filipe Almeida

    2010-01-01

    This paper presents an experimental study on the influence of longitudinal reinforcement ratio and steel fibre volume in self-compacting concrete infill on the strength and ductility of reinforced masonry walls subjected to flexure. Flexure tests were performed as four-point bending tests on twelve walls. The analysis of the concrete infill contribution to the walls capacity is made considering recent recommendations for steel fibre reinforced concrete design. A ductility...

  6. Influence of heat treatment and KIc/HRc ratio on the dynamic wear properties of coated high speed steel

    Directory of Open Access Journals (Sweden)

    M. Sedlaček

    2017-01-01

    Full Text Available The aim of this work was to determine the impact of various heat treatments on the KIc/HRc ratio and subsequently on the wear properties of coated high-speed steel under dynamic impact loading. The results showed that hardness and improvement in the fracture toughness have significant influence on the adhesion and impact wear properties of the coated high-speed steel.

  7. Influence of the V microaddition on the structure and mechanical properties of 60CrV7 spring steel

    OpenAIRE

    M. Opiela

    2007-01-01

    Purpose: Influence of vanadium microaddition on structure and mechanical properties of the constructionalspring steel was investigated.Design/methodology/approach: Metallography, transmission electron microscope, tensile test, hardnessmeasurements have been used.Findings: Microaddition of V introduced to the steel allows to obtain the fine-grained structure, and gives elasticelements obtaining: apparent elastic limit Rp0.05 over 1800 MPa, proof stress Rp0.2 over 1900 MPa and ultimatetensile s...

  8. Influence of rare earth metals on the nucleation and solidification behavior of iron and 1045 steel

    Science.gov (United States)

    Li, H.; McLean, A.; Rutter, J. W.; Sommerville, I. D.

    1988-06-01

    Two series of experiments have been conducted to determine the influence of rare earth additions on the nucleation and crystallization behavior of pure iron and 1045 steel. In the first series, additions of rare earth suicide or cerium dioxide powder to two-Kg 1045 steel ingots indicated that rare earth suicide can refine the as-cast structure of such ingots. However, if the holding time after rare earth silicide addition is over two minutes, the grain refinement decreases. With cerium dioxide additions, a relatively large columnar zone was obtained. In the second series, the effects of cerium metal or cerium dioxide powder additions on the degree of undercooling obtainable in pure iron and 1045 steel were examined by the lévitation melting method. Surface tension measurements of the levitated droplets were carried out at the same time to investigate the possible effects of surface tension variations on the nucleation and crystallization behavior of the metals. The experimental data show that rare earth inclusions can greatly reduce the degree of undercooling of iron and steel, and that a small amount of dissolved cerium can further reduce the degree of undercooling of levitated droplets. The structure and reaction products obtained with Fe-Ce levitated droplets were examined with both optical and scanning electron microscopy as well as X-ray diffraction analysis. The experimental results clearly indicated that cerium solute redistribution during solidification is the dominant factor in refining the as-cast structure. A nucleation and solidification model for the Fe-Ce levitated droplets has been developed, which can successfully explain the experimental results.

  9. The influence of cobalt on the microstructure and adherence characteristics of enamel on steel sheet

    Directory of Open Access Journals (Sweden)

    Masoud Bodaghi

    2011-12-01

    Full Text Available In this study, the influence of cobalt (Co on the microstructure and adhesion between enamel and steel substrate has been investigated. The result of press test indicated that the adhesion strength was greatly improved by Co inclusion. Scanning electronic microscope (SEMrevealed that the amount of dendrite increases in the interface while its average size decreases. The wavelength dispersive X-ray analysis (WDS identified the existence of Co in the dendrite, which confirms that the Co was closely related to the change of interface morphology and the improvement of adhesion strength. Finally, the reasons for adhesion improvement were discussed.

  10. Influence of Hot Deformation and Subsequent Austempering on the Mechanical Properties of Hot Rolled Multiphase Steel

    Institute of Scientific and Technical Information of China (English)

    Zhuang LI; Di WU

    2006-01-01

    Influence of hot deformation and subsequent austempering on the mechanical properties of hot rolled multiphase steel was investigated. Thermo-mechanical control processing (TMCP) was conducted by using a laboratory hot rolling mill, where three different kinds of finishing rolling reduction, and austemperings with various isothermal holding duration were applied. The results have shown that a multiphase microstructure consisting of polygonal ferrite, granular bainite and larger amount of stabilized retained austenite can be obtained by controlled rolling processes. Mechanical properties increase with increasing the amount of deformation because of the stabilization of retained austenite. Ultimate tensile strength (σb), total elongation (δ)36% and 28476 MPa%, respectively) at optimal processes.

  11. INFLUENCE OF QUANTITATIVE ALLOYING OF TOOL STEELS FOR HOT DEFORMATION ON THE LEVEL OF HARDENING

    Directory of Open Access Journals (Sweden)

    V. N. Fedulov

    2015-01-01

    Full Text Available The influence of complexly experimental tool steels: C (0,4–0,50%, Si (0,6–1,2%, Mn (0,17–0,8%, Cr (0,8–3%, W (0,9– 4%, Mo (0,01–3.5% and V (0,28–1,8% on their ability to hardening due to only high-temperature tempering after induction melting, casting in the ceramic mold and air cooling (without deformation and after the various modes of complete heat treatment cycle

  12. Influence of plastic deformation on low temperature surface hardening of stainless steel by gaseous nitriding

    DEFF Research Database (Denmark)

    Bottoli, Federico; Winther, Grethe; Christiansen, Thomas Lundin

    2015-01-01

    This article addresses an investigation of the influence of plastic deformation on low temperature surface hardening by gaseous nitriding of three commercial austenitic stainless steels: AISI 304, EN 1.4369 and Sandvik Nanoflex® with various degrees of austenite stability. The materials were...... plastically deformed to different equivalent strains by uniaxial tension. Gaseous nitriding of the strained material was performed in ammonia at atmospheric pressure in the temperature range 693-703 K. Microstructural characterization of the as-deformed states and the nitrided case included X-ray diffraction...

  13. Influence of the Soil-Structure Interaction on the Design of Steel-Braced Building Foundation

    Science.gov (United States)

    Azarbakht, Alireza; Ashtiany, Mohsen Ghafory

    2008-07-01

    The modeling and analysis of the superstructure and the foundation for the seismic lateral loads are traditionally done separately. This assumption is an important issue in the design/rehabilitate procedures especially for the short period structures, i.e. steel braced or shear wall systems, which may result to a conservative design. By using more advance procedures, i.e. nonlinear static method, and the incorporation of the soil-structure interaction (SSI), the seismic demand in the lateral resisting system decreases and the design will become more economic. This paper includes an investigation about the influence of the SSI effect on the design of the steel-braced building foundation. The presented example is a three-bay three-storey steel braced frame. Three design methods based on the FEMA 356 guideline and the UBC 97 code are taken in to consideration. The three methods are: (1) linear static analysis based on the UBC 97 code assuming the fixed based condition; (2) linear static analysis based on the FEMA 356 guideline assuming the fixed based condition; and (3) nonlinear static analysis assuming both fixed and flexible based assumptions. The results show that the influence of the SSI on the input demand of the short period building foundations is significant and the foundation design based on the linear static method with the fixed base assumption is so conservative. A simple method is proposed to take the SSI effect in to consideration in the linear static procedure with the fixed base assumption, which is a common method for the engineers. The advantage of this proposed method is the simplicity and the applicability for the engineering purposes.

  14. Influence of Freeze-Thaw Damage on the Steel Corrosion and Bond-Slip Behavior in the Reinforced Concrete

    Directory of Open Access Journals (Sweden)

    Fangzhi Zhu

    2016-01-01

    Full Text Available This paper mainly studies the behavior of steel corrosion in various reinforced concrete under freeze-thaw environment. The influence of thickness of concrete cover is also discussed. Additionally, the bond-slip behavior of the reinforced concrete after suffering the freeze-thaw damage and steel corrosion has also be presented. The results show that the freeze-thaw damage aggravates the steel corrosion in concrete, and the results become more obvious in the concrete after suffering serious freeze-thaw damage. Compared with the ordinary concrete, both air entrained concrete and waterproofing concrete possess better resistance to steel corrosion under the same freeze-thaw environment. Moreover, increasing the thicknesses of concrete cover is also an effective method of improving the resistance to steel corrosion. The bond-slip behavior of reinforced concrete with corroded steel decreases with the increase of freeze-thaw damage, especially for the concrete that suffered high freeze-thaw cycles. Moreover, there exists a good correlation between the parameters of bond-slip and freeze-thaw cycles. The steel corrosion and bond-slip behavior of reinforced concrete should be considered serious under freeze-thaw cycles environment, which significantly impact the durability and safety of concrete structure.

  15. INFLUENCE OF AUSTENITE GRAIN SIZE TO DEVELOPMENT OF DECARBONIZATION IN PRODUCTION OF ROLLED STEEL

    Directory of Open Access Journals (Sweden)

    PARUSOV E. V.

    2016-08-01

    ]. The paper [11] acknowledges the influence of micro-additives of boron on changes in the austenite grain size and accordingly the length of borders in high-carbon steels with austenitizing temperature increase within the range of 900…1 100ºС. The purpose of work is to research the effect of austenite grain size on the decarburization depth in carbon (base steel and boron micro-alloyed steel.

  16. Influence of severe plastic deformation on the structure and properties of ultrahigh carbon steel wire

    Energy Technology Data Exchange (ETDEWEB)

    Leseur, D R; Sherby, O D; Syn, C K

    1999-07-01

    Ultrahigh-carbon steel wire can achieve very high strength after severe plastic deformation, because of the fine, stable substructures produce. Tensile strengths approaching 6000 MPa are predicted for UHCS containing 1.8%C. This paper discusses the microstructural evolution during drawing of UHCS wire, the resulting strength produced and the factors influencing fracture. Drawing produces considerable alignment of the pearlite plates. Dislocation cells develop within the ferrite plates and, with increasing strain, the size normal to the axis ({lambda}) decreases. These dislocation cells resist dynamic recovery during wire drawing and thus extremely fine substructures can be developed ({lambda} < 10 nm). Increasing the carbon content reduces the mean free ferrite path in the as-patented wire and the cell size developed during drawing. For UHCS, the strength varies as {lambda}{sup {minus}5}. Fracture of these steels was found to be a function of carbide size and composition. The influence of processing and composition on achieving high strength in these wires during severe plastic deformation is discussed.

  17. Influence of Rare Earths on Improve Impact Property of Structural Alloy Steel with Extra Low Sulfur and Oxygen

    Institute of Scientific and Technical Information of China (English)

    Guo Feng; Lin Qin

    2007-01-01

    The influence of rare earth lanthanum and cerium on impact property of structural alloy steel with extra low sulfur and oxygen was studied by impact test and microanalysis. The results showed that rare earths increased impact power of the steel when their contents were about 0.005%. Proper addition of rare earths could purify grain boundaries and decrease amount of inclusions, and reduced the possibility of crack growth along grain boundaries and through inclusions. Therefore, such steel could absorb more crack growth energy while it was impacted. However, if the content of rare earths is excessive, the grain boundary would be weakened and brittle-hard phosphates and Fe-RE intermetallic would be formed, which worsened impact toughness of steel.

  18. Influence of reheating and cooling conditions on structure and mechanical properties of C-Mn-Si steel

    Directory of Open Access Journals (Sweden)

    T. Kvačkaj

    2008-07-01

    Full Text Available The paper deals with structure and properties development of AHSS (advance high-strength steel and UHSS (ultra high-strength steel steel grades for various groups of automotive parts. C-Mn-Si type steel properties are evaluated based on the results of laboratory controlled rolling and cooling. The important influence on mechanical and plastic properties, amount of residual austenite (RA and final structural type has, except for cooling rate, also starting temperature of intensive cooling (TIC which follows after hot plastic deformations. If TIC is from interval of 620-760°C the final structure predominantly consists of ferrite with RA. Mostly acicular ferrite with RA, as well as bainite with RA was obtained when TIC was kept in the range of 760-850°C.

  19. The influence of the corrosion product layer generated on the high strength low-alloy steels welded by underwater wet welding with stainless steel electrodes in seawater

    Science.gov (United States)

    Bai, Qiang; Zou, Yan; Kong, Xiangfeng; Gao, Yang; Dong, Sheng; Zhang, Wei

    2017-02-01

    The high strength low-alloy steels are welded by underwater wet welding with stainless steel electrodes. The micro-structural and electrochemical corrosion study of base metal (BM), weld zone (WZ) and heat affected zone (HAZ) are carried out to understand the influence of the corrosion product layer generated on the high strength low-alloy steels welded by underwater wet welding with stainless steel electrodes, methods used including, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and scanning electron microscope (SEM). The results indicate that the WZ acts as a cathode and there is no corrosion product on it throughout the immersion period in seawater. The HAZ and BM acts as anodes. The corrosion rates of the HAZ and BM change with the immersion time increasing. In the initial immersion period, the HAZ has the highest corrosion rate because it has a coarse tempered martensite structure and the BM exhibites a microstructure with very fine grains of ferrite and pearlite. After a period of immersion, the BM has the highest corrosion rate. The reason is that the corrosion product layer on the HAZ is dense and has a better protective property while that on the BM is loose and can not inhibit the diffusion of oxygen.

  20. The Influence of Post Weld Heat Treatment in Alloy 82/182 Dissimilar Metal Weld between Low Alloy Steel and 316L Stainless Steel

    Energy Technology Data Exchange (ETDEWEB)

    Hong, Sunghoon; Hong, Jong-Dae; Jang, Changheui [Korea Advanced Institute of Science and Technology, Daejeon (Korea, Republic of); Lee, Kyoung Soo [KHNP-CRI, Daejeon (Korea, Republic of)

    2014-10-15

    Dissimilar metal welds (DMWs) using an Alloy 82/182 are widely used to join low alloy steel components and stainless steel pipes in pressurized water reactors (PWRs). It has been reported that tensile residual stress would be generated within DMWs during the welding processes. It is thought as main reason for primary water stress corrosion cracking (PWSCC) resulting in deterioration of long-term integrity. The application of post weld heat treatment (PWHT) has been considered to reduce the tensile residual stress after welding process. Meanwhile, the PWHT could affect the changes in microstructure, mechanical properties, and corrosion resistance. Therefore, in this study, the effects of PWHT on the microstructure, mechanical properties and corrosion behaviors of base metals of low alloy steel and stainless steel and welding materials of Alloy 82/182 are evaluated. The influence of PWHT in DMW has been investigated. SA 508 and 316L SS exhibited tempered bainite and austenitic grains with a few residual stringer type ferrite. Grain boundary carbides are not precipitated owing to low carbon and insufficient exposure time in 316L SS. The change of mechanicals properties in base metals is not observed. In case of Alloy 182, after PWHT, grain boundaries are covered with film-like continuous Cr-rich carbides.

  1. Influence of cathodic protection on the lifetime extension of painted steel structures

    Science.gov (United States)

    Yoo, Y. R.; Cho, H. H.; Take, S.; Kim, J. G.; Kim, Y. S.

    2006-06-01

    For corrosion to occur on a coated metal surface, an electrochemical double layer must be established. Hence, the adhesion between the substrate and the coating must be weakened to enable a separate thin layer of water to be formed at the interface from water that has permeated the coating. To prevent the failure of a painted coating, we applied a cathodic protection method. This method has been controversial for a few years because cathodic protection can induce cathodic delamination of the entire surface, especially near the anode, and also because it is not effective on a not-wetted surface from the anode. We therefore evaluated the efficiency of cathodic protection for 700 days in an atmospheric environment and performed surface observation, AC impedance measurements and corrosion tests. In the case of a noncathodic protected painted steel specimen, blisters formed after 100 days and grew in number for the remainder of the test. However, cathodic protection of the painted steel increased the coating resistance and extended the lifetime of the coating. According to our calculation with the BEASY program, the thickness of the water film under a rain condition barely influenced the protection potential. The high voltage of the cathodic protection and the subsequent cathodic delamination caused the paint to peel off near the anode. Hence, the protection voltage should be controlled in accordance with changes to the environmental condition.

  2. Microbial consortium influence upon steel corrosion rate, using polarisation resistance and electrochemical noise techniques

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez Gayosso, M.J.; Zavala Olivares, G.; Ruiz Ordaz, N.; Juarez Ramirez, C.; Garcia Esquivel, R.; Padilla Viveros, A

    2004-10-01

    The microbiologically influenced corrosion (MIC) is a process, which affects the oil industry, particularly the hydrocarbons extraction, transport and storage. MIC evaluation has been normally based upon microbiological tests, and just a few references mention alternating methods, such as the electrochemical techniques, which can be used as criteria for their evaluation. In this work, two different electrochemical laboratory techniques, polarisation resistance and electrochemical noise were used, in order to determine the corrosion behaviour of a microbial consortium, obtained from a gas transporting pipeline, located in the southeast of Mexico. The bacteria population growth was found to be different for sessile and plancktonic microorganisms. Moreover, long incubation times were required to reach the maximum concentration of sessile bacteria. The electrochemical techniques used in this study exhibited a similar tendency on the corrosion rate behaviour with time, and values above 0.3 mm year{sup -1} were observed at the end of the experiments. The experiments were complemented with surface analysis. Scanning electron microscope observation of APIXL52 steel coupons, exposed to the consortium action, revealed bacteria presence, as well as a damaged steel surface. A type of localized corrosion was observed on the metal surface, and it was associated to the bacteria effect.

  3. The influence of the surface finishing on the electrochemical behaviour of austenitic and superaustenitic steels

    Energy Technology Data Exchange (ETDEWEB)

    Barsic, G.; Runje, B.; Alar, Z. [University of Zagreb, Faculty of Mechanical Engineering and Naval Architecture, Zagreb (Croatia); Alar, V.

    2012-08-15

    The influence of surface roughness on the pitting potential and the corrosion potential of the DIN W.Nr. 1.4541 and DIN W.Nr 1.4465 stainless steels were examined using electrochemical techniques. Roughness and electrochemical tests were performed on samples with various surface finishing. Electrochemical studies were conducted in an electrochemical cell where steel electrodes were immersed in 0.1 M NaCl and 0.1 M NaCl + 0.1 M Na{sub 2}SO{sub 4} aqueous solutions. We found for both materials when immersed in 0.1 M NaCl aqueous solution lower pitting potential than in 0.1 M NaCl + 0.1 M Na{sub 2}SO{sub 4}. The results showed that the electrochemical behaviour of the DIN W.Nr. 1.4465 is better than of DIN W.Nr. 1.4541. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  4. Normalizing treatment influence on the forged steel SAE 8620 fracture properties

    Directory of Open Access Journals (Sweden)

    Paulo de Tarso Vida Gomes

    2005-03-01

    Full Text Available In a PWR nuclear power plant, the reactor pressure vessel (RPV contains the fuel assemblies and reactor vessels internals and keeps the coolant at high temperature and high pressure during normal operation. The RPV integrity must be assured all along its useful life to protect the general public against a significant radiation liberation damage. One of the critical issues relative to the VPR structural integrity refers to the pressurized thermal shock (PTS accident evaluation. To better understand the effects of this kind of event, a PTS experiment has been planned using an RPV prototype. The RPV material fracture behavior characterization in the ductile-brittle transition region represents one of the most important aspects of the structural assessment process of RPV's under PTS. This work presents the results of fracture toughness tests carried out to characterize the RPV prototype material behavior. The test data includes Charpy energy curves, T0 reference temperatures for definition of master curves, and fracture surfaces observed in electronic microscope. The results are given for the vessel steel in the "as received" and normalized conditions. This way, the influence of the normalizing treatment on the fracture properties of the steel could be evaluated.

  5. Influence of silicon on the microstructures, mechanical properties and stretch-flangeability of dual phase steels

    Institute of Scientific and Technical Information of China (English)

    Le-yu Zhou; Dan Zhang; Ya-zheng Liu

    2014-01-01

    Uniaxial tension tests and hole-expansion tests were carried out to determine the influence of silicon on the microstructures, me-chanical properties, and stretch-flangeability of conventional dual-phase steels. Compared to 0.03wt%silicon, the addition of 1.08wt%sili-con induced the formation of finer ferrite grains (6.8μm) and a higher carbon content of martensite (Cm≈0.32wt%). As the silicon level in-creased, the initial strain-hardening rate (n value) and the uniform elongation increased, whereas the yield strength, yield ratio, and stretch-flangeability decreased. The microstructures were observed after hole-expansion tests. The results showed that low carbon content martensite (Cm≈ 0.19wt%) can easily deform in coordination with ferrite. The relationship between the mechanical properties and stretch-flangeability indicated that the steel with large post-uniform elongation has good stretch-flangeability due to a closer plastic incom-patibility of the ferrite and martensite phases, which can effectively delay the production and decohesion of microvoids.

  6. Influence of Chemical Composition on Phase Transformation Temperature and Thermal Expansion Coefficient of Hot Work Die Steel

    Institute of Scientific and Technical Information of China (English)

    XIE Hao-jie; WU Xiao-chun; MIN Yong-an

    2008-01-01

    On the basis of the uniform design method,six kinds of martensitie hot work die steels were designed.The phase transformation temperatures including Ac1,Ac3,and M,were measured by DIL805A quenching dilatometer.The influences of the main elements on phase transformation temperatures were analyzed by quadratic stepwise regression analysis,and three corresponding equations were obtained.These equations,in which the interactions of the elements were considered,showed more effectiveness than the traditional ones.In addition,the thermal expansion coefficients of these steels in annealed state and quenched state were also obtained during the tests.The influences of chemical composition and temperature on the thermal expansion coefficient were analyzed;the equations obtained Were verified by using several kinds of steels.The predicted values were in accordance with the results of the experiments.

  7. Influence of chemical bonding of chlorides with aluminates in cement hidratation process on corrosion steel bars in concrete

    Directory of Open Access Journals (Sweden)

    Bikić Farzet H.

    2010-01-01

    Full Text Available The presence of chlorides in concrete is a permanent subject of research because they cause corrosion of steel bars. Chlorides added to the concrete during preparation, as accelerators of the bonding of cement minerals process, enter into reaction with aluminates, creating a phase known as chloroaluminate hydrates. In everyday conditions the product of chemical bonding between chlorides and aluminates is usually monochloridealuminate C3A·CaCl2·Hx, better known as Friedel's salt. In this paper, the influence of chemical bonding of chlorides with aluminates during the process of cement hydration on corrosion of steel bars in concrete was investigated. The process of chlorides bonding with aluminates yielding monochloride aluminate is monitored by XRD analyses. It was found that the amount of chlorides bonding with aluminates increases with an increase of temperature, and as a result, reduces the amount of 'free' chlorides in concrete. Potentiodynamic measurements have shown that increase in temperature of the heat treatment of working electrodes by chlorides leads to a reduction of steel bars corrosion as a result of either the increase of the monochloride-aluminate content or the decrease of free chlorides amount. Chlorides bound in chloroaluminate hydrates do not cause activation of steel bars corrosion in concrete. It was also proven that the increase of free chlorides concentration in the concrete leads to intensification of steel bars corrosion. This additionally approves that free chlorides are only the activators of process of steel bars corrosion in the concrete.

  8. The influence of drawing speed on surface topography of high carbon steel wires

    Directory of Open Access Journals (Sweden)

    M. Suliga

    2017-01-01

    Full Text Available In this work the influence of the drawing speed on surface topography of high carbon steel wires has been assessed. The drawing process of f 5,5 mm wire rod to the final wire of f 1,7 mm was conducted in 12 passes by means of a modern Koch multi-die drawing machine. The drawing speeds in the last passes were: 5, 10, 15, 20 and 25 m/s. For final wires f 1,7 mm the three-dimensional analysis of the wire surface topography investigation was determined. It has been proved that the wire topography in the drawing process is characterized by a random anisotropy and the amount of directing the geometrical structure of the surface depends on the drawing speed.

  9. Influence of water cavitation peening with aeration on fatigue behaviour of SAE1045 steel

    Science.gov (United States)

    Han, B.; Ju, D. Y.; Jia, W. P.

    2007-10-01

    Water cavitation peening (WCP) with aeration is a recent potential method in the surface enhancement techniques. In this method, a ventilation nozzle is adopted to improve the process capability of WCP by increasing the impact pressure, which is induced by the bubble collapse on the surface of components in the similar way as conventional shot peening. In this paper, fatigue tests were conducted on the both-edge-notched flat tensile specimens to assess the influences of WCP on fatigue behaviour of SAE1045 steel. The notched specimens were treated by WCP, and the compressive residual stress distributions in the superficial layer were measured by X-ray diffraction method. The tension-tension ( R = Smin/ Smax = 0.1, f = 10 Hz) fatigue tests and the fracture surfaces observation by scan electron microscopy (SEM) were conducted. The experimental results show that WCP can improve the fatigue life by inducing the residual compressive stress in the superficial layer of mechanical components.

  10. Influence of high deformation on the microstructure of low-carbon steel

    Institute of Scientific and Technical Information of China (English)

    Florin Popa; Ionel Chicina; Dan Frunz; Ioan Nicodim; Dorel Banabic

    2014-01-01

    Low-carbon steel sheets DC04 used in the automotive industry were subjected to cold rolling for thickness reduction from 20%to 89%. The desired thickness was achieved by successive reductions using a rolling mill. The influence of thickness reduction on the micro-structure was studied by scanning electron microscopy. Microstructure evolution was characterized by the distortion of grains and the occur-rence of the oriented grain structure for high cold work. A mechanism of grain restructuring for high cold work was described. The occur-rence of voids was discussed in relation with cold work. The evolution of voids at the grain boundaries and inside the grains was also consid-ered. To characterize the grain size, the Feret diameter was measured and the grain size distribution versus cold work was discussed. The chemical homogeneity of the sample was also analyzed.

  11. Influence of the direction of selective laser sintering on machinability of parts from 316L steel

    Science.gov (United States)

    Alexeev, V. P.; Balyakin, A. V.; Khaimovich, A. I.

    2017-02-01

    This work presents the results of research of the impact of layer-by-layer growing of workpieces made of 316L steel on their machinability. The results of determination of residual stresses and measurement of hardness of the workpieces grown have been demonstrated. A series of experimental studies has been performed in order to determine the cutting force which occurs in the process of machining. The microstructure of the workpieces grown has been examined. It has been shown that the workpieces machined using Selective Laser Melting technology have the microstructure which is a totality of ‘microwelded seams’, which have a significant influence on the behavior of deformation processes in case of machining. The studies have shown that in case of lateral milling of the horizontally grown workpiece, the codirectional microwelded borders prevent any significant deformation of the misalignment which increases the cutting force by up to 10% as compared with milling of the vertically grown workpiece.

  12. Simulating microbiologically influenced corrosion by depositing extracellular biopolymers on mild steel surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Roe, F.L.; Lewandowski, Z.; Funk, T. [Montana State Univ., Bozeman, MT (United States). Center for Biofilm Engineering

    1996-10-01

    Electrochemical properties of corroding mild steel (MS) surfaces were measured in real time using three closely spaced microelectrodes. Dissolved oxygen, pH, and ion currents were mapped simultaneously and noninvasively above a MS coupon partially coated with biopolymer gels. Calcium alginate (Ca-Alg [an extracellular biopolymer containing carboxylate functional groups]) and agarose (one without carboxylate functional groups) were tested. Corrosion occurred at approximately the same rate under the two biopolymer spots on the same coupon. Corrosion rates under these biopolymers were {approx} 4 mpy in a weak saline solution. Results suggested corrosion was not influenced by chemical properties of the biopolymer but possibly was controlled by oxygen reduction in noncoated regions of the coupon (i.e., a differential aeration cell).

  13. Influence of Spot Welding on Welding Fatigue Properties of CR340 Steel Joints

    Institute of Scientific and Technical Information of China (English)

    Rui-bin GOU; Wen-jiao DAN; Wei-gang ZHANG

    2016-01-01

    Total 72 lapped specimens including six different kinds of CR340 steel structures were prepared to study the influence of the spot welding technology on their fatigue characteristics.Fatigue test and group method were em-ployed and performed on each sample to obtain the fatigue experimental data of each structure under four stress lev-els.The results show that the spot welding technology had a notable impact on the fatigue performance of both the shear and tensile joints.It can significantly improve the fatigue strength of the structure,the consistency and repeat-ability of experimental data,as well as the stability and reliability of the structure under dynamic load environment. The shear spot welding structure demonstrates the best fatigue performance which is very important for wide appli-cation in engineering of this method.

  14. The role of iron in SRB influenced corrosion of mild steel

    Energy Technology Data Exchange (ETDEWEB)

    Videla, H.A.; Fernandez Lorenzo de Mele, M. [Univ. of La Plata (Argentina); Swords, C.L. [Univ. of Leeds (United Kingdom). School of Materials; Edyvean, R.G. [Univ. of Sheffield (United Kingdom); Watkins, P.; Beech, I.B. [Univ. of Portsmouth (United Kingdom). Dept. of Chemistry

    1998-12-31

    The growth of anaerobic bacteria such as sulfate reducing bacteria(SRB)produces dramatic changes in the mild steel/solution interface which include variations of the redox potential and pH values, anions and cations concentrations and the composition and structure of inorganic layers, among others. Complex equilibria between different iron compounds are established. These equilibria are markedly altered during bacterial growth. As a first approach to the understanding of the complex scenario at the biofilm/surface interface, electrochemical techniques including different perturbation programs complemented by microscopic observations and chemical analysis of the corrosion products were made in the laboratory. Thus, the aim of this work is to study the influence of pH, sulfide, sulfate, and iron ions concentrations on the electrochemical processes occurring at the interface to achieve a better understanding of the transformations produced during SRB growth.

  15. Influence of sulfide inclusion on ductility and fracture behavior of resulfurized HY-80 steel

    Science.gov (United States)

    Biswas, D. K.; Venkatraman, M.; Narendranath, C. S.; Chatterjee, U. K.

    1992-05-01

    The influence of sulfide inclusions on the ductile fracture process of experimental HY-80 steels having graded sulfur levels from 50 to 500 ppm and heat-treated to different strength levels was studied with respect to mechanical properties, namely, tensile ductility and Charpy impact en-ergy. Sulfide inclusions are found to have deleterious effect on both axisymmetric ductility and Charpy impact properties, whereas the plane strain ductility was found to be less sensitive to sulfide inclusions. The effect of interaction between the inclusion and the matrix and the as-sociated stress strain distribution at the void nucleating sites, which control the fracture process by microvoid coalescence, were discussed in the light of various models to suggest a micro-mechanism of fracture. Other toughness parameters obtained from instrumented impact tests were evaluated and discussed as a function of sulfur content.

  16. Influence of Charge Shape and Orientation on the Response of Steel-Concrete Composite Panels

    Directory of Open Access Journals (Sweden)

    Abraham Christian

    2016-09-01

    Full Text Available Blast design codes usually generalize the shape of the charge as spherical or hemispherical. However, it was found that the blast overpressure of cylindrical charges differ greatly when compared with relevant analytical results generated with the charges assumed to be spherical. The objective is to use fully coupled 3D multi-material arbitrary Lagrangian Eulerian (MMALE modelling technique in LS Dyna software to simulate the cylindrical charge blast loading. Comparison of spherical and cylindrical charge blast simulation was carried out to show the influence on peak overpressure and total impulse. Two steel-concrete composite specimens were subjected to blast testing under cylinder charges for benchmarking against numerical results. It was found that top detonated, vertical cylinder charge could give much higher blast loading compared to horizontal cylinder charge. The MMALE simulation could generate the pressure loading of various charge shape and orientation to be used for predicting the response of the composite panel.

  17. Influence of Laser Peening on Phase Transformation and Corrosion Resistance of AISI 321 steel

    Science.gov (United States)

    Karthik, D.; Swaroop, S.

    2016-07-01

    The objective of this study is to investigate the influence of laser peening without coating (LPwC) on austenitic to martensitic (γ → α') phase transformation and corrosion behavior of austenitic stainless steel AISI 321 in 3.5% NaCl environment. Results indicate that LPwC induces a large compressive residual stresses of nearly -854 MPa and γ → α' phase transformation of about 18% (volume fraction). Microstructures of peened surface confirmed the γ → α' phase transformation and showed no grain refinement. Hardness increased slightly with a case depth of 900 μm. Despite the smaller surface roughness introduced, corrosion resistance improved after peening due to compressive residual stresses.

  18. Evaluation of a biocide effect upon microbiologically influenced corrosion of mild steel

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez Gayosso, M.J.; Zavala Olivares, G.; Garcia Esquivel, R. [Instituto Mexicano del Petroleo, Grupo de Corrosion. Eje Central Lazaro Cardenas 152, Col. San Bartolo Atepehuacan, Mexico, D.F, C.P. 07730 (Mexico); Ruiz Ordaz, N. [Escuela Nacional de Ciencias Biologicas, Instituto Politecnico Nacional. Prolongacion de Carpio y Plan de Ayala, Mexico, D.F, C.P. 11340 (Mexico)

    2005-09-01

    The microbiologically influenced corrosion (MIC) is a very dangerous process, which affects the oil industry. The activity and microorganisms' growth at the pipelines steel cause surface modifications, which can induce a more complex corrosion process. The biocide evaluation for the MIC decrease has been normally based upon microbiological tests, and just a few references mention alternating methods which can be used as criteria for their evaluation. In this work, a commercial biocide was tested, using different electrochemical laboratory techniques, to determine its effect upon a biofilm generating bacteria consortium. Using microbiological techniques, the biocide lethal concentration was determined, and a concentration of 200 ppm was used to kill completely the consortium population in both, plancktonic and sessile parts. The electrochemical techniques: Polarisation Resistance (PR) and Electrochemical Impedance Spectroscopy (EIS), allowed describing the corrosion process associated to the microbial consortium and the biocide effect upon it. (Abstract Copyright [2005], Wiley Periodicals, Inc.)

  19. The influence of texture on phase transformation in metastable austenitic stainless steel

    NARCIS (Netherlands)

    Hilkhuijsen, P.

    2013-01-01

    Metastable austenitic stainless steels are used in many applications, from shavers and kitchen sinks to various applications in the food industry. The diversity in applications of this type of steels is possible due to the many positive properties of the steel. It is not only esthetically pleasing,

  20. Influence of tellurium sulfides` morphology and workability of constructional steel; Wplyw telluru na morfologie siarczkow i skrawalnosc stali konstrukcyjnej

    Energy Technology Data Exchange (ETDEWEB)

    Pytel, S.M.; Kadluczka, A.M. [Instytut Materialoznawstwa i Technologii Metali, Politechnika Krakowska, Cracow (Poland)

    1995-12-31

    The interactions of the tellurium additions on quantitative changes in sulfur geometry as well as the influence of such changes on workability improvement of low-alloyed construction steel have been investigated and discussed. (author). 7 refs, 3 figs, 2 tabs.

  1. Influence of Plastic Deformation on Low-Temperature Surface Hardening of Austenitic Stainless Steel by Gaseous Nitriding

    DEFF Research Database (Denmark)

    Bottoli, Federico; Winther, Grethe; Christiansen, Thomas Lundin

    2015-01-01

    This article addresses an investigation of the influence of plastic deformation on low-temperature surface hardening by gaseous nitriding of two commercial stainless steels: EN 1.4369 and AISI 304. The materials were plastically deformed to several levels of equivalent strain by conventional...

  2. Studing the Influence of Six Main Industrial Losses on Overall Equipment Effectiveness in Cold Rolling Unit of Mobarakeh Steel Complex

    Directory of Open Access Journals (Sweden)

    seyed Akbar Nilipour Tabatabaei

    2011-03-01

    Full Text Available Overall Equipment Effectiveness (OEE is a key indicator and a basis for evaluating the effectiveness of equipments as well as assessing the effectiveness of the Total Productive Maintenance (TPM system. This indicator together with overall equipment performance can be used in production lines such as steel production. The aim of this article is to study the influence of six main industrial losses on the OEE indicator . For this purpose, the OEE has been calculated in the cold rolling production lines of Mobarakeh Steel Complex the gap between production lines and the global industrial standards has been studied the causes of production system inefficiency has been investigated and the effectiveness of TPM system, equipments' bottlenecks and the influence of the main industry losses on OEE have been studied. The findings imply that the influence of the variation of availability and performance rates on OEE is high, while the influence of the variation of quality rate on OEE is not considerable.

  3. Significance and influence of the ambient temperature as a rate factor of steel reinforcement corrosion

    Indian Academy of Sciences (India)

    V Živica

    2002-10-01

    The rate of corrosion of reinforcement being an electrochemical process, undoubtedly is dependent even on the level of the ambient temperature. Therefore, the ambient temperature seems to be an important factor of the corrosion rate and the durability of the reinforced concrete structures in aggressive environment. The present data on the influence and significance of the ambient temperature in the process of corrosion of reinforcement of the reinforced structures are surprisingly limited and poor. It seems that it is supposed to be a simple increase of corrosion rate when the ambient temperature is increased. The lack of information was a motivation for the present study. It was aimed at the experimental research of the influence of the increase of the ambient temperature on the rate of chloride induced corrosion of steel reinforcement. The results obtained show that the influence of the studied factor is more complex showing an acceleration effect till a temperature of 40°C diversified by the inhibition effects with further increase of the ambient temperature.

  4. Influence of incubation temperature on biofilm formation and corrosion of carbon steel by Serratia marcescens

    Science.gov (United States)

    Harimawan, Ardiyan; Devianto, Hary; Kurniawan, Ignatius Chandra; Utomo, Josephine Christine

    2017-01-01

    Microbial induced corrosion (MIC) or biocorrosion is one type of corrosion, directly or indirectly influenced by microbial activities, by forming biofilm and adhering on the metal surface. When forming biofilm, the microorganisms can produce extracellular products which influence the cathodic and anodic reactions on metal surfaces. This will result in electrochemical changes in the interface between the biofilm and the metal surface, leading to corrosion and deterioration of the metal. MIC might be caused by various types of microorganism which leads to different corrosion mechanism and reaction kinetics. Furthermore, this process will also be influenced by various environmental conditions, such as pH and temperature. This research is aimed to determine the effect of incubation temperature on corrosion of carbon steel caused by Serratia marcescens in a mixture solution of synthetic seawater with Luria Bertani medium with a ratio of 4:1. The incubation was performed for 19 days with incubation temperature of 30, 37, and 50°C. The analyses of biofilm were conducted by total plate count (TPC), scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR). Biofilm was found to be evenly growth on the surface and increasing with increasing incubation temperature. It consists of functional group of alcohol, alkane, amine, nitro, sulfate, carboxylic acid, and polysulfide. The analyses of the corrosion were conducted by gravimetric and X-ray diffraction (XRD). Higher incubation temperature was found to increase the corrosion rate. However, the corrosion products were not detected by XRD analysis.

  5. Influence of Low-Alloy Cast Steel Modification on Primary Structure Refinement, Type and Shape of Non-Metallic Inclusions

    Directory of Open Access Journals (Sweden)

    Bartocha D.

    2015-04-01

    Full Text Available In the article there are presented methods and results of investigation which main aim were determination of influence of melting technology (gas extraction, vacuum refining, slag refining and extraction, deoxidation and degassing and type of used modifiers on the type and shape of non-metallic inclusions and the primary structure refining. Low alloy cast steel melted in laboratory conditions, in an inductive furnace was investigated. Additions of FeNb, FeV, FeTi and FeZr modifiers were applied. The contents of oxygen and nitrogen in obtained cast steel were determined.

  6. Crack growth tests on a ferritic reactor pressure vessel steel under the simultaneous influence of simulated BWR coolant and irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Hoffmann, H. [VGB PowerTech e.V., Essen (Germany); Huettner, F. [Hamburgische Electricitaets-Werke AG, Hamburg (Germany); Ilg, U. [EnBW Kraftwerke AG, Philippsburg (Germany); Wachter, O. [E.ON Kernkraft GmbH, Hannover(Germany); Widera, M. [RWE Power AG, Essen (Germany); Brozova, A.; Ernestova, M.; Kysela, J.; Vsolak, R. [Nuclear Research Institute Rez plc (Czech Republic)

    2004-07-01

    Crack growth tests under constant load with initial in-situ cycling were performed on the low alloy reactor pressure vessel (RPV) steel 22 NiMoCr 3 7 (A 508 Cl. 2) with the goal to determine crack growth rates of irradiated and non-irradiated steel under the simultaneous influence of simulated BWR coolant and irradiation. The tests were performed under conditions as near as possible to operational conditions in a commercial BWR reactor. The research results are summarized and are compared with international data. (orig.)

  7. Influence of Al on the fatigue crack growth behavior of Fe–22Mn–(3Al)–0.6C TWIP steels

    Energy Technology Data Exchange (ETDEWEB)

    Ma, Penghui [State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 (China); National Engineering Research Center for Equipment and Technology of Cold Strip Rolling, Yanshan University, Qinhuangdao 066004 (China); Qian, Lihe, E-mail: dlhqian@yahoo.com [State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 (China); National Engineering Research Center for Equipment and Technology of Cold Strip Rolling, Yanshan University, Qinhuangdao 066004 (China); Meng, Jiangying [State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 (China); Liu, Shuai; Zhang, Fucheng [State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 (China); National Engineering Research Center for Equipment and Technology of Cold Strip Rolling, Yanshan University, Qinhuangdao 066004 (China)

    2015-10-01

    The influence of Al on fatigue crack growth (FCG) behavior of the high-Mn austenitic twinning-induced plasticity (TWIP) steel was investigated by conducting FCG tests on Fe–22Mn–0Al–0.6C and Fe–22Mn–3Al–0.6C TWIP steels (hereafter, referred to as 0Al and 3Al TWIP steel, respectively). The FCG tests were performed at stress ratio of 0.1 under the control of stress intensity factor range using three-point bending specimens. Excepting that the traditional two-dimensional (2D) observation methods (optical, scanning and transmission electron microscopes) were used to observe the crack paths, fracture surfaces and microstructure features, a high-resolution synchrotron X-ray computed tomography was also applied to observe the three-dimensional (3-D) crack morphology. The results indicate that the FCG resistance of the 0Al TWIP steel is superior to that of 3Al TWIP steel in the near threshold regime. Observed from the 2D crack paths and 3D crack morphologies, it can be found that the crack surface roughness and crack deflection of the 0Al steel are greater than those of 3Al steel. It is suggested that the degree of roughness-induced crack closure decreases with the addition of Al. And the 0Al steel shows much larger plastic zone sizes ahead of the crack tip than the 3Al steel, suggesting that plasticity-induced crack closure may also play an important role in decreasing the FCG rate in the 0Al steel. By excluding the crack closure effects, the 0Al steel still exhibits a higher effective crack growth threshold value than the 3Al steel; this is considered to be due to the higher planarity of slip in the 0Al steel than in the 3Al steel, and the mechanical twins generated in the 0Al steel reduce the stress concentration at crack tip.

  8. Influence of Rolling Treatment on Interfacial Shear Strength of Steel-mushy Al-7graphite Bonding Plate

    Institute of Scientific and Technical Information of China (English)

    Peng ZHANG; Yunhui DU; Hanwu LIU; Daben ZENG; Jianzhong CUI; Limin BA

    2004-01-01

    At room temperature, the rolling treatment of steel-mushy Al-7graphite bonding plate was carried out under different relative reduction. The influence of rolling on interfacial mechanical property of this bonding plate was studied. The results show that, for steel-mushy Al-7graphite bonding plate which is made up of 1.2 mm in thickness 08Al steel plate and 2.0 mm in thickness Al-7graphite layer, there is a nonlinear relationship between interfacial shear strength of bonding plate and relative reduction of rolling. When relative reduction of rolling is smaller than 2.59%, with the increasing of relative reduction, interfacial shear strength of bonding plate increases gradually. When relative reduction of rolling is bigger than 2.59%, with the increasing of relative reduction, interfacial shear strength of bonding plate decreases continuously. When relative reduction of rolling is 2.59%, the largest interfacial shear strength 77.0 MPa can be obtained.

  9. The influence of the Desulfovibrio desulfuricans 14 ATCC 27774 on the corrosion of mild steel

    Energy Technology Data Exchange (ETDEWEB)

    Feio, M.J. [Portsmouth Univ. (United Kingdom). Microbiology Research Lab.; Rainha, V.; Fonseca, I.T.E. [Lisbon Univ. (Portugal). Dept. de Quimica e Bioquimica; Reis, M.A. [Universidade Nova de Lisboa, Lisbon (Portugal). Faculdade de Ciencias e Tecnologia; Lino, A.R. [Instituto de Tecologia Quimica e Biologica, Qeiras (Portugal)

    2000-10-01

    The involvement of sulphate-reducing bacteria (SRB) in microbially influenced corrosion (MIC) of steel and the serious implications associated with their presence in industrial environments have long been known and extensively described. Desulfovibrio desulfuricans ATCC 27774 is an interesting metabolic case of SRB, as it can use both sulphate and nitrate as respiratory substrates during lactate oxidation. This strain has been extensively studied from both a biochemical and structural point of view but, so far, restricted information is available concerning its role in MIC. This work describes a comparative study of the corrosive aggressivity of ATCC 27774 strain towards mild steel when grown either in lactate/sulphate or lactate/nitrate media. The carbon source and electron acceptor's consumption rates were analysed and the metabolic features were correlated with weight loss measurements and SEM observations. (orig.) [German] Die Beteiligung von sulfatreduzierenden Bakterien (SRB) bei der mikrobiologisch beeinflussten Korrosion (MIC) von Stahl und die Auswirkungen, die mit ihrer Anwesenheit in industriellen Umgebungen verbunden sind, sind seit langem bekannt und ausfuehrlich beschrieben. Desulfovibrio desulfuricans ATCC 27774 ist ein interessanter metabolischer Fall von SRB, da es sowohl Sulfat als auch Nitrat als Respirationssubstrat waehrend der Laktatoxidation nutzen kann. Diese Art ist sowohl vom biochemischen als auch vom strukturellen Standpunkt aus intensiv untersucht worden; bisher gibt es allerdings nur begrenzte Informationen ueber eine Rolle bei MIC. Diese Arbeit beschreibt eine Vergleichsstudie der Korrosivitaet der ATCC 27774 Art (bei Wachstum entweder in Laktat/Sulfat- oder Laktat/Nitrat-Medien) gegenueber unlegiertem Stahl. Die Kohlenstoffquelle und die Elektronenakzeptorverbrauchsrate wurden analysiert und die metabolischen Merkmale wurden mit Massenverlustmessungen und REM-Beobachtungen korreliert. (orig.)

  10. Influence of loading path on formability of 304 stainless steel tubes

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    The loading path affects the metal formability remarkably in tube hydroforming, and it is also one of the research focuses. Recently, some scholars abroad proposed a new fluctuant hydraulic loading method, which can improve the formability of tubes in hydroforming. Related studies have shown that this new loading method can improve the tube formability, the distribution of deformation is more uniform and this is useful for avoiding excessive local thinning. In this paper, tube hydroforming experiments without axial feeding were carried out; the influences of the loading methods on formability of stainless steel tubes were studied. Through the comparison of the experimental results under the condition of monotonous increase loading and fluctuation hydraulic loading, the outside diameter distribution, the thickness distribution and the crack expansion forms of deformation zone all fully prove that the uniformity of the distribution of tube deformation and formability have been increased significantly under the condition of fluctuation loading without axial feeding, the reasons should be distinguished from the fluctuation hydroforming with axial feeding. In order to study the forming mechanism, uniaxial tensile test of tubes similar to fluctuation loading deformation is designed in this paper, namely intermittent tensile test. It is found that intermittent uniaxial stretch can improve the tube elongation at fracture by about 40% and the deformation distribution is more uniform than that through uniaxial tensile test of the stainless steel tube. In the process of intermittent tensile tests, changes of metal microstructures brought by the loading and unloading processes are the main reasons that improve the formability of the tubes.

  11. Influence of loading path on formability of 304 stainless steel tubes

    Institute of Scientific and Technical Information of China (English)

    ZHANG ShiHong; YUAN AnYing; WANG Bin; ZHANG HaiQu; WANG ZhongTang

    2009-01-01

    The loading path affects the metal formability remarkably in tube hydroforming,and it is also one of the research focuses.Recently,some scholars abroad proposed a new fluctuant hydraulic loading method,which can improve the formability of tubes in hydroforming.Related studies have shown that this new loading method can improve the tube formability,the distribution of deformation is more uniform and this is useful for avoiding excessive local thinning.In this paper,tube hydroforming experiments without axial feeding were carried out;the influences of the loading methods on formability of stainless steel tubes were studied.Through the comparison of the experimental results under the condition of monotonous increase loading and fluctuation hydraulic loading,the outside diameter distribution,the thickness distribution and the crack expansion forms of deformation zone all fully prove that the uniformity of the distribution of tube deformation and formability have been increased significantly under the condition of fluctuation loading without axial feeding,the reasons should be distinguished from the fluctuation hydroforming with axial feeding.In order to study the forming mechanism,uniaxial tensile test of tubes similar to fluctuation loading deformation is designed in this paper,namely intermittent tensile test.It is found that intermittent uniaxial stretch can improve the tube elongation at fracture by about 40% and the deformation distribution is more uniform than that through uniaxial tensile test of the stainless steel tube.In the process of intermittent tensile tests,changes of metal microstructures brought by the loading and unloading processes are the main reasons that improve the formability of the tubes.

  12. Yttrium modifying influence on the shape and amount of nonmetallic inclusions in the austenitic high alloy steel

    Directory of Open Access Journals (Sweden)

    Андрій Володимирович Патюпкін

    2016-07-01

    Full Text Available Yttrium influence on the form and amount of non-metallic inclusions in steel 06H23N18M5 was studied. It has been found that yttrium binds oxygen and other elements into heterogeneous compounds, it resulting in the transition of impurities into passive state. Oxide inclusions, sulfide inclusions and globules formed as a result of steel components reactions with oxygen, sulfur and nitrogen dissolved in metal are mostly found in the structure. It was found that by modifying and refining austenitic steels with yttrium service properties of the deposited layer can be adjusted. X-ray diffraction and X-ray spectrum analysis revealed that the modified steel 06H23N18M5 + 0.02% Y has a heterogeneous structure with uniformly distributed inclusions of σ-phase and composite carbides (Fe, Cr, Mo 23C6. It is possible that Y modification resulted in the appearance of chemically resistant intermetallic σ-phase in these steels, for nucleation was facilitated by increasing the number of crystallization centers as dispersed primary yttrium oxy-sulfide compounds

  13. Research on key influence factors of laser overlap welding of automobile body galvanized steel

    Science.gov (United States)

    Chen, Genyu; Mei, Lifang; Zhang, Mingjun; Zhang, Yi; Wang, Zujian

    2013-02-01

    In views of structure characteristics of the auto-body parts, the influences of the beam incident angle and joint gap on the performance of laser overlap welded joints were investigated. The experimental results indicate that there were the critical values of beam incident angle and joint gap during laser overlap welding of galvanized steel. The thickness of sheet and the width of joint had a certain influence on the critical beam incident angle and the limit joint gap. With regard to thicker sheet, the limit joint gap can increase appropriately, but the critical beam incident angle should not be too big. With narrow weld width, the laser beam incident angle can increase appropriately, but the joint gap should not be bigger. Additionally, the critical beam incident angle and the limit joint gap were varied with the thickness of the upper sheet. The tensile-shear tests show that the maximum tensile-shear strength of the joint can be obtained with an optimized beam incident angle and joint gap.

  14. Influence of Martensite Fraction on the Stabilization of Austenite in Austenitic-Martensitic Stainless Steels

    Science.gov (United States)

    Huang, Qiuliang; De Cooman, Bruno C.; Biermann, Horst; Mola, Javad

    2016-05-01

    The influence of martensite fraction ( f α') on the stabilization of austenite was studied by quench interruption below M s temperature of an Fe-13Cr-0.31C (mass pct) stainless steel. The interval between the quench interruption temperature and the secondary martensite start temperature, denoted as θ, was used to quantify the extent of austenite stabilization. In experiments with and without a reheating step subsequent to quench interruption, the variation of θ with f α' showed a transition after transformation of almost half of the austenite. This trend was observed regardless of the solution annealing temperature which influenced the martensite start temperature. The transition in θ was ascribed to a change in the type of martensite nucleation sites from austenite grain and twin boundaries at low f α' to the faults near austenite-martensite (A-M) boundaries at high f α'. At low temperatures, the local carbon enrichment of such boundaries was responsible for the enhanced stabilization at high f α'. At high temperatures, relevant to the quenching and partitioning processing, on the other hand, the pronounced stabilization at high f α' was attributed to the uniform partitioning of the carbon stored at A-M boundaries into the austenite. Reduction in the fault density of austenite served as an auxiliary stabilization mechanism at high temperatures.

  15. Experimental investigation of the influence of Mo contained in stainless steel on Cs chemisorption behavior

    Science.gov (United States)

    Di Lemma, F. G.; Nakajima, K.; Yamashita, S.; Osaka, M.

    2017-02-01

    Chemisorption phenomena can affect fission products (FP) retention in a nuclear reactor vessel during a severe accident (SA). Detailed information on the FP chemisorbed deposits, especially for Cs, are important for a rational decommissioning of the reactor following a SA, as for the Fukushima Daiichi Power Station. Moreover the retention of Cs will influence the source term assessment and thus improved models for this phenomenon are needed in SA codes. This paper describes the influence on Cs chemisorption of molybdenum contained in stainless steel (SS) type 316. In our experiments it was observed that Cs-Mo deposits (CsFe(MoO4)3, Cs2MoO4) were formed together with CsFeSiO4, which is the predominant compound formed by chemisorption. The Cs-Mo deposits were found to revaporize from the SS sample at 1000 °C, and thus could contribute to the source term. On the other hand, CsFeSiO4 will be probably retained in the reactor during a SA due to its stability.

  16. The influence of calcium on technological properties and micropurity of steel castings

    Directory of Open Access Journals (Sweden)

    J. Hampl

    2016-07-01

    Full Text Available The paper analyzes the technological parameters, micro-purity and mechanical properties of castings of steel alloyed with calcium. The effect of calcium on the steel was analyzed on samples taken in the process of casting heavy castings and ingots of the weight of ranging from 40 000 to 60 000 kg. Samples for the determination of the liquidus temperature and the solidus temperature of cast steels were analysed using differential thermal analysis (DTA. The production of low alloyed steel grades was performed on the EAF - ASEA-SKF facilities and the production of highalloyed steels on the EAF - ASEA-SKF - SS-VOD facilities. The purity calcium was added into the steel by the injection of a stuffed profile.

  17. The influence of sintering time on the properties of PM duplex stainless steel

    OpenAIRE

    Z. Brytan; L.A. Dobrzański; M. Actis Grande; Rosso, M.

    2009-01-01

    Purpose: The purpose of this paper is to analyse the effect of sintering time on the pore morphology, microstructural changes, tensile properties and corrosion resistance of vacuum sintered duplex stainless steel.Design/methodology/approach: In presented study PM duplex stainless steels were obtained through mixing base ferritic stainless steel powder with controlled addition of elemental alloying powders and then sintered in a vacuum furnace with argon backfilling at 1250°C for different tim...

  18. Influence of microstructure on the microbial corrosión behaviour of stainless steels

    Directory of Open Access Journals (Sweden)

    Moreno, Diego Alejandro

    2000-08-01

    Full Text Available Several stainless steels (Types UNS S30300, S30400, S30403, S31600, S31603 and S42000 with different microstructural characteristics have been used to study the influence of heat treatments on microbiologically influenced corrosion (MIC. Biocorrosion and accelerated electrochemical testing was performed in various microbiological media. Two species of sulphate-reducing bacteria (SRB have been used in order to ascertain the influence of microstructure. The morphology of corrosion pits produced in both chloride and chloride plus sulphide -SRB metabolites- was inspected by optical and scanning electron microscopy (SEM complemented with energy-dispersive X-ray (EDX analysis. Results have shown different behaviours regarding corrosion resistance in each case studied. Sensitized austenitic stainless steels were more affected by the presence of aggressive anions and pitting potential (Ep values were more cathodic than those of as-received state. A corrosion enhancement is produced by the synergistic action of biogenic sulphides and chloride anions. Pitting corrosion in martensitic stainless Steel Type UNS S42000 was found in a- biocorrosion test. The pitting morphology is correlated to the chemical composition, the microstructure and the electrolyte.

    Se han utilizado aceros inoxidables de los tipos UNS S30300, S30400, S30403, S31600, S31603 y S42000, en diferentes estados microestructurales, para estudiar la influencia de los tratamientos térmicos sobre la corrosión microbiana. Para ello, se han realizado ensayos electroquímicos y ensayos de biocorrosión, en diferentes medios microbiológicos, utilizándose dos especies de bacterias reductoras de sulfatos (SRB. La morfología de las picaduras, producidas en presencia de cloruros y en presencia de cloruros más sulfuros -metabolitos de SRB-, se ha analizado por microscopía óptica y por microscopía electrónica de barrido (SEM complementada con análisis por energía dispersiva de rayos X

  19. Influence of the Magnetic High-speed Steel Cutting Tool on Cutting Capability

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The high-speed steel cutting tool has advantaged i n modern cutting tool for its preferable synthetical performance, especially, in a pplication of complicated cutting tools. Therefore, the study of the high-speed steel cutting tools that occupied half of cutting tools has become an importa nt way of studying on modern cutting technology. The cutting performance of hi gh speed-steel cutting tools will be improved by magnetization treating method. Microstructure of high-speed steel will be changed as a ...

  20. Efficiency of inhibitor for biocorrosion influenced by consortium sulfate reducing bacteria on carbon steel

    Science.gov (United States)

    Mahat, Nur Akma; Othman, Norinsan Kamil; Sahrani, Fathul Karim

    2015-09-01

    The inhibition efficiency of benzalkonium chloride (BKC) in controlling biocorrosion on the carbon steel surfaces has been investigated. The carbon steel coupons were incubated in the presence of consortium SRB (C-SRB) with and without BKC for the difference medium concentration. The corrosion rate and inhibition efficiency have been evaluated by a weight loss method. The morphology of biofilm C-SRB on the steel surfaces were characterized with variable pressure scanning electron microscopy (VPSEM). The results revealed that BKC exhibits a low corrosion rate, minimizing the cell growth and biofilm development on the carbon steel surfaces.

  1. Efficiency of inhibitor for biocorrosion influenced by consortium sulfate reducing bacteria on carbon steel

    Energy Technology Data Exchange (ETDEWEB)

    Mahat, Nur Akma; Othman, Norinsan Kamil [School of Applied Physics, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia); Sahrani, Fathul Karim [School of Environment and Natural Resources Science, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia)

    2015-09-25

    The inhibition efficiency of benzalkonium chloride (BKC) in controlling biocorrosion on the carbon steel surfaces has been investigated. The carbon steel coupons were incubated in the presence of consortium SRB (C-SRB) with and without BKC for the difference medium concentration. The corrosion rate and inhibition efficiency have been evaluated by a weight loss method. The morphology of biofilm C-SRB on the steel surfaces were characterized with variable pressure scanning electron microscopy (VPSEM). The results revealed that BKC exhibits a low corrosion rate, minimizing the cell growth and biofilm development on the carbon steel surfaces.

  2. Influence of Tempering Temperature on Cyclic Viscoplastic Behaviour of 55NiCrMoV7 Steel

    Institute of Scientific and Technical Information of China (English)

    ZHANG Zhan-ping; DELAGNES Denis; BERNHART Gerard

    2004-01-01

    Low cycle fatigue behaviour of a steel 55NiCrMoV7 under four tempered conditions is reported. One special type of total strain controlled isothermal cyclic deformation tests were performed in the temperature range 20℃ to 600℃for the steel tempered 2h at 350℃, 460℃, 560℃ and 600℃. The influence of temperature on cyclic behaviour was investigated. Generally, the cyclic stress response shows an initial exponential softening for the first few cycles, followed by a gradual softening without cyclic softening saturation. At 10-2 strain rate, σmax. △σ/2 decrease with the test temperature for all hardness levels. They decrease linearly with tempering temperature when testing temperature is lower than that of tempering, but rest nearly constant when test temperature is equal to or exceed tempering temperature of steel. Cyclic softening intensity increases with testing temperature from 300℃ to 600℃, but the maximal softening intensity occurs at room temperature. The strain rate influences notably the cyclic behaviour when T≥500℃. The time dependence of cyclic behaviour is closely related to test temperature and the tempering history of the steel.

  3. Influence of dissolved hydrogen on the fatigue crack growth behaviour of AISI 4140 steel

    Science.gov (United States)

    Ramasagara Nagarajan, Varun

    Many metallic structural components come into contact with hydrogen during manufacturing processes or forming operations such as hot stamping of auto body frames and while in service. This interaction of metallic parts with hydrogen can occur due to various reasons such as water molecule dissociation during plating operations, interaction with atmospheric hydrogen due to the moisture present in air during stamping operations or due to prevailing conditions in service (e.g.: acidic or marine environments). Hydrogen, being much smaller in size compared to other metallic elements such as Iron in steels, can enter the material and become dissolved in the matrix. It can lodge itself in interstitials locations of the metal atoms, at vacancies or dislocations in the metallic matrix or at grain boundaries or inclusions (impurities) in the alloy. This dissolved hydrogen can affect the functional life of these structural components leading to catastrophic failures in mission critical applications resulting in loss of lives and structural component. Therefore, it is very important to understand the influence of the dissolved hydrogen on the failure of these structural materials due to cyclic loading (fatigue). For the next generation of hydrogen based fuel cell vehicles and energy systems, it is very crucial to develop structural materials for hydrogen storage and containment which are highly resistant to hydrogen embrittlement. These materials should also be able to provide good long term life in cyclic loading, without undergoing degradation, even when exposed to hydrogen rich environments for extended periods of time. The primary focus of this investigation was to examine the influence of dissolved hydrogen on the fatigue crack growth behaviour of a commercially available high strength medium carbon low alloy (AISI 4140) steel. The secondary objective was to examine the influence of microstructure on the fatigue crack growth behaviour of this material and to determine the

  4. Influence of superplastic deformation on the anisotropy of 03Kh26N6T steel

    Energy Technology Data Exchange (ETDEWEB)

    Akhmed Faud, M.F.; Tsepin, M.A.; Lobach, A.A. [Tabbinskii Metallurgical Institute, Cario (Egypt)]|[Moscow Institute of Steel and Alloys (Russian Federation)] [and others

    1992-03-01

    The rules of change in anisotropy of 03Kh26N6T corrosion-resistant steel with a nonequiaxial fine-grained structure deformed under superplastic conditions were considered and an investigation was made of the change in anisotropy of the plastic properties in connection with the presence of original metallographic nonuniformity of the steel structure. 8 refs., 5 figs.

  5. Influence of surface roughness of stainless steel on microbial adhesion and corrosion resistance

    DEFF Research Database (Denmark)

    Hilbert, Lisbeth Rischel; Bagge-Ravn, Dorthe; Kold, John;

    2003-01-01

    Abstract The aim of this study was to evaluate if hygienic characteristics of stainless steel used in the food industry could be improved by smoothing surface roughness from an Ra of 0.9 to 0.01 ƒÝm. The adherence of Pseudomonas sp., Listeria monocytogenes and Candida lipolytica to stainless steel...

  6. Influence of concrete slabs on lateral torsional buckling of steel beams

    NARCIS (Netherlands)

    Maljaars, J.; Snijder, H.H.; Hoenderkamp, J.C.D.

    2007-01-01

    The use of pre-cast concrete floor slabs in steel framed structures is quite common. In the de-sign of the steel beams, the lateral restraining effect of the pre-cast concrete slab is normally safely neglected. However, the concrete slab will provide some horizontal restraint, even without special p

  7. Influence of austenitizing temperature on apparent morphologies of as-quenched microstructures of steels

    Institute of Scientific and Technical Information of China (English)

    LIU Yue-jun; LI Yi-min; HUANG Bai-yun

    2006-01-01

    The effects of austenitizing temperature on the morphologies and substructures of as-quenched microstructure were investigated by using 13 medium and high carbon steels. The formation reasons of various morphologies of martensite quenched at different austenitizing temperatures were also studied. The results show that the packet martensite in medium and high carbon steels quenched at higher austenitizing temperature is entirely different from that in as-quenched low carbon steels, which is still plate martensite, and not lath martensite. All the change laws of as-quenched microstructures in medium and high carbon steels are identical with an increase in austenitizing temperature, and the austenitizing temperature can merely change the combined morphology of martensitic platelets,but cannot alter the type of product of martensitic transformation in commercial steels.

  8. Influence of deformation on structural-phase state of weld material in St3 steel

    Energy Technology Data Exchange (ETDEWEB)

    Smirnov, Alexander, E-mail: galvas.kem@gmail.ru; Ababkov, Nicolay, E-mail: n.ababkov@rambler.ru; Ozhiganov, Yevgeniy, E-mail: zhigan84@mail.ru [Kuzbass State Technical University, 25-54, Krasnaya Str., 650000, Kemerovo (Russian Federation); LLC “Kuzbass Center of Welding and Control”, 33/2, Lenin Str., 650055, Kemerovo (Russian Federation); Kozlov, Eduard, E-mail: kozlov@tsuab.ru [Kuzbass State Technical University, 25-54, Krasnaya Str., 650000, Kemerovo (Russian Federation); Tomsk State University of Architecture and Building, 2, Solyanaya Sq., 634003, Tomsk (Russian Federation); Popova, Natalya, E-mail: natalya-popova-44@mail.ru [Kuzbass State Technical University, 25-54, Krasnaya Str., 650000, Kemerovo (Russian Federation); Tomsk State University of Architecture and Building, 2, Solyanaya Sq., 634003, Tomsk (Russian Federation); Institute of Strength Physics and Materials Science, SB RAS, 2/4, Akademicheskii Ave., 634021, Tomsk (Russian Federation); Nikonenko, Elena, E-mail: vilatomsk@mail.ru [Kuzbass State Technical University, 25-54, Krasnaya Str., 650000, Kemerovo (Russian Federation); Tomsk State University of Architecture and Building, 2, Solyanaya Sq., 634003, Tomsk (Russian Federation); National Research Tomsk Polytechnic University, 30, Lenin Str., 634050, Tomsk (Russian Federation); Zboykova, Nadezhda, E-mail: tezaurusn@gmail.com; Koneva, Nina, E-mail: koneva@tsuab.ru [Tomsk State University of Architecture and Building, 2, Solyanaya Sq., 634003, Tomsk (Russian Federation)

    2016-01-15

    The structural-phase condition of the weld material subjected to the plastic deformation was investigated using the translucent diffraction electron microscopy method. The investigations were carried out near the joint of the weld and the base metal. The seam was done by the method of manual arc welding without artificial defects. The St3 steel was taken as the welded material. Influence of the plastic deformation on morphology, phase composition, defect structure and its parameters of weld metal was revealed. All investigations were done at the distance of 0.5 mm from the joint of the weld and the base metal at the deformation degrees from 0 to 5% and after destruction of a sample. It was established that deformation of the sample did not lead to qualitative changes in the structure (the structure is still presented by ferrite-pearlite mixture) but changed the quantitative parameters of the structure, namely, with the increase of plastic deformation a part of the pearlite component becomes more and more imperfect. In the beginning it turns into the destroyed pearlite then into ferrite, the volume fraction of pearlite is decreased. The polarization of dislocation structure takes place but it doesn’t lead to the internal stresses that can destroy the sample.

  9. Influence of Light Rare Earth on Toughness of Welded Seam of LAHS Steel

    Institute of Scientific and Technical Information of China (English)

    李慕勤; 马臣; 刘冬梅

    2003-01-01

    The influence mechanism of light rare earth elements, which are transited to the welding seam of low-alloy high strength (LAHS) steel through the covering of the electrode, on the toughness of the welding seam was studied. The experimental results show that proper amount of rare earth elements can desulfurate, dehydrogenate, reduce inclusions and purify the structure of the welding seam. Rare earth element additions have the effect on welding seam and, at the same time, the transformation of side-batten ferrite is resisted while the pin-ferrite structure is promoted. The improvement of the toughness of the welding seam is due to the purifying action of rare earth elements as well as their refining effect on the structure. However, the toughness of the welding seam can decrease when the amount of light rare earth elements are added excessively because the crystal grains become coarser, porosities appear and the inclusions increase as well. The experimental results show that the suitable amount of light rare earth element additions is about 2%.

  10. Influence of the Lubricant Type on the Surface Quality of Steel Parts Obtained by Ironing

    Directory of Open Access Journals (Sweden)

    D. Adamović

    2015-06-01

    Full Text Available If it is needed to achieve a higher strain rate during the ironing process, which is possible without inter-stage annealing, the ironing is performed in succession through multiple dies. During that process, changes of friction conditions occur due to the change of contact conditions (dislodging of lubricants, changes of surface roughness, formation of friction junctions, etc.. In the multistage ironing, after each stage, the completely new conditions on the contact surfaces occur, which will significantly affect the quality of the workpiece surface. Lubricant has a very important role during the steel sheet metal ironing process; to separate the sheet metal surface from the tool and to reduce the friction between the contact surfaces. The influence of tribological conditions in ironing process is extremely important and it was a subject of study among researches in recent years, both in the real processes and on the tribo-models. Investigation of tribological conditions in the real processes is much longer and more expensive, so testing on the tribo-models is more frequent. Experimental research on the original tribo-model presented in this paper was aimed to indicate the changes that occur during multistage ironing, as well as to consider the impact of some factors (tool material, lubricant on die and punch on increase or decrease of the sheet metal surface roughness in ironing stages.

  11. Influence of gas pressure and substrate temperature on PIII nitrocarburizing process of AISI 304 stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Abd El-Rahman, A.M. [Physics Department, Faculty of Science, South Valley University, Sohag Branch, Sohag (Egypt) and Institute of Ion Beam Physics and Material Research, FWII, Forschungszentrum Rossendorf, 01314 Dresden (Germany)]. E-mail: ahmedphys96@hotmail.com; El-Hossary, F.M. [Physics Department, Faculty of Science, South Valley University, Sohag Branch, Sohag (Egypt); Negm, N.Z. [Physics Department, Faculty of Science, South Valley University, Sohag Branch, Sohag (Egypt); Prokert, F. [Institute of Ion Beam Physics and Material Research, FWII, Forschungszentrum Rossendorf, 01314 Dresden (Germany); Richter, E. [Institute of Ion Beam Physics and Material Research, FWII, Forschungszentrum Rossendorf, 01314 Dresden (Germany); Moeller, W. [Institute of Ion Beam Physics and Material Research, FWII, Forschungszentrum Rossendorf, 01314 Dresden (Germany)

    2004-12-01

    Plasma immersion ion implantation (PIII) has been used to modify the surface properties of 304 austenitic stainless steel (AISI). The influence of working gas pressure, 0.2-1.0 Pa, and substrate temperature, 300-500 deg. C, on the microstructure, treating rate, nitrogen/carbon concentration depth profile, and surface microhardness was investigated. A gas composition of 25% C{sub 2}H{sub 2}, 75% N{sub 2}, r.f. plasma power input of 350 W, and a negatively biased potential of 30 kV were fixed during the experiment. The experimental results show that the substrate temperature and the diffusion process of nitrogen and carbon depend on the gas pressure inside the plasma chamber. The thickness of the modified layer has been found to be more than 30 {mu}m for samples were treated in the plasma for 60 min. The results show also that the values of diffusion coefficient and surface microhardness of the treated samples are high to be 3.4 x 10{sup -1} {mu}m{sup 2}/s and 1880 kg/mm{sup 2}, respectively.

  12. Influence of gas pressure and substrate temperature on PIII nitrocarburizing process of AISI 304 stainless steel

    Science.gov (United States)

    Abd El-Rahman, A. M.; El-Hossary, F. M.; Negm, N. Z.; Prokert, F.; Richter, E.; Möller, W.

    2004-12-01

    Plasma immersion ion implantation (PIII) has been used to modify the surface properties of 304 austenitic stainless steel (AISI). The influence of working gas pressure, 0.2-1.0 Pa, and substrate temperature, 300-500 °C, on the microstructure, treating rate, nitrogen/carbon concentration depth profile, and surface microhardness was investigated. A gas composition of 25% C2H2, 75% N2, r.f. plasma power input of 350 W, and a negatively biased potential of 30 kV were fixed during the experiment. The experimental results show that the substrate temperature and the diffusion process of nitrogen and carbon depend on the gas pressure inside the plasma chamber. The thickness of the modified layer has been found to be more than 30 μm for samples were treated in the plasma for 60 min. The results show also that the values of diffusion coefficient and surface microhardness of the treated samples are high to be 3.4 × 10-1 μm2/s and 1880 kg/mm2, respectively.

  13. Influence of dislocation glide on the spinodal decomposition of fatigued duplex stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Herenu, S., E-mail: herenu@ifir-conicet.gov.ar [Instituto de Fisica Rosario, Bv. 27 de Febrero 210 bis, (2000) Rosario, Santa Fe (Argentina); Sennour, M. [MINES ParisTech, Centre des Materiaux - UMR CNRS 7633 - 91003, Evry Cedex (France); Balbi, M.; Alvarez-Armas, I. [Instituto de Fisica Rosario, Bv. 27 de Febrero 210 bis, (2000) Rosario, Santa Fe (Argentina); Thorel, A. [MINES ParisTech, Centre des Materiaux - UMR CNRS 7633 - 91003, Evry Cedex (France); Armas, A.F. [Instituto de Fisica Rosario, Bv. 27 de Febrero 210 bis, (2000) Rosario, Santa Fe (Argentina)

    2011-09-25

    Highlights: {center_dot} Dislocations bands and microbands are developed in {alpha} phase of fatigued aged DSS. {center_dot} Inside these structures, demodulation of spinodal decomposition (SD) were found. {center_dot} This fact could take part in the cyclic softening displayed by DSS S32750. {center_dot} Cyclic tests at 475 deg. C show a saturation stage at the end of fatigue life. {center_dot} This could be explained by the effect of demodulation and creation of SD. - Abstract: The present work is focused on assessing the influence of dislocation movement on spinodal decomposition through scanning transmission electron microscopy (STEM) in combination with energy dispersive X-ray spectroscopy (EDS) analysis in aged duplex stainless steel (DSS) S32750. Dislocation bands and microbands are the prominent dislocation arrangements observed in fatigue tested aged samples. By EDS measurements it was found that the spinodal decomposition was dissolved inside these dislocations structures. Therefore, the mechanism of microband formation developed in the ferritic phase during cycling seems to be responsible for the demodulation of the spinodal decomposition and cyclic softening of the aged DSS.

  14. Influence of deformation behavior, oxydation, and temperature on the long time cyclic stress behavior of high temperature steels

    Science.gov (United States)

    Maile, K.

    1982-01-01

    The influence of different parameters on the creep-fatigue behavior of several steel alloys was investigated. The higher the temperature the lower the crack initiation value. Pauses during the cycle reduce the damage. Oxidation reduces and protective gas increases the lifetime. Prior loading and prior deformation reduce the lifetime. Short annealing slightly affects the cycle stress behavior. The test results do not satisfactorily agree with methods of extrapolation and damage accumulation.

  15. Influence of ion nitriding regime on mechanical properties and fracture mechanism of austenitic steel subjected to different thermomechanical treatments

    Science.gov (United States)

    Moskvina, Valentina; Astafurova, Elena; Ramazanov, Kamil; Melnikov, Eugene; Maier, Galina; Budilov, Vladimir

    2016-11-01

    The effect of thermomechanical treatments and low-temperature ion nitriding on mechanical properties and a fracture mechanism of stable austenitic stainless steel Fe-17Cr-13Ni-1.7Mn-2.7Mo-0.5Si-0.01C (in wt %, 316L-type) was investigated. Irrespective of initial heat treatments of steel and the regime of nitrogen saturation, traditional ion nitriding and nitriding with hollow cathode effect do not influence the stages of plastic flow and strain hardening; instead, they contribute to surface hardening of steel samples and reduce their plastic properties due to formation of a brittle surface layer. Ion nitriding leads to formation of a hardened surface layer with the microhardness of 12 GPa. Formation of a high-defective grain/subgrain structure with high dislocation density contributes to strengthening of steel samples under ion nitriding and formation of a thicker strengthened layer in comparison with fine-crystalline and coarse-crystalline samples.

  16. Research of influence of gas nitriding duration on formation of diffusion layer of steel 20Kh2N4A

    Directory of Open Access Journals (Sweden)

    Kateryna O. Kostyk

    2015-06-01

    Full Text Available The research of the gas nitriding process, which allows to obtain a high surface quality of steel parts and has a wide application in mass production, is relevant. Aim of the research is to study the influence of gas nitriding modes on the structure and properties of alloy steel. The research material in this work is steel 20Kh2N4A. Nitriding of the samples is carried out in a shaft furnace at the temperature of 510…530 °C during 35, 40, 46 and 48 h. It is found that the alloy steel 20Kh2N4A preliminary heat treatment before nitriding provides the hardness of products core to 279...321 HV due to the formation of perlite-sorta structure with carbides of alloying elements. The results show that increasing the duration of nitriding from 35 to 48 hours at 510…530 °С increases the depth of nitrided layer from 0,35 to 0,55 mm with surface hardness up to 648 MPa at the maximum depth of the layer. The results of this research can be used in industry and research works.

  17. Influence of flexural fatigue on chloride threshold value for the corrosion of steels in Ca(OH){sub 2} solutions

    Energy Technology Data Exchange (ETDEWEB)

    Jiang, Linhua, E-mail: hhulhjiang@gmail.com [College of Mechanics and Materials, Hohai University, 1 Xikang Rd., Nanjing, 210098 (China); Hydraulic Engineering Research Center for New Materials and Protection, Jiangsu Province, 1 Xikang Rd., Nanjing, 210098 (China); Liu, Hao; Wang, Yongliang; Zhang, Yan; Song, Zijian; Xu, Jinxia; Jin, Ming; Jiang, Peng; Xu, Yi; Gao, Hailang [College of Mechanics and Materials, Hohai University, 1 Xikang Rd., Nanjing, 210098 (China)

    2015-08-15

    The flexural fatigue was enforced on reinforced concrete beam with stress level of 0.6 and different fatigue life cycles. Steels removed from the beams were soaked in the saturated Ca(OH){sub 2} solution, which was used as a simulated concrete pore solution. The NaCl solution was chosen as the source of chloride ions. The Chloride Threshold Values (CTV) were detected by combining the open-circuit potentials (E{sub corr}) with the corrosion current densities (i{sub corr}), which were obtained by electrochemical impedance spectroscopy (EIS). The changes of microstructure caused by the flexural fatigue were observed by scanning electron microscopy (SEM). The results showed that as the fatigue cycle times increased, the CTV decreased under a certain stress level and range of fatigue life cycles. The grains became finer and cracks appeared on the surface of the steels. While the capacitive arcs under no flexural fatigue decreased gradually with the addition of chloride ions, the ones under flexural fatigue presented no regularity. Cracks at the surface were expanded because of sustaining flexural fatigue, which degenerated the later resistance to chloride ions of the steels. - Highlights: • The influence of flexural fatigue on chloride threshold value was examined. • The chloride threshold values vary with different fatigue life cycles. • The corrosion behavior depends on the surface integrity of the steels.

  18. Influence of carbon content on superplastic behavior in Ti- and B-added Cr-Mo steels

    Energy Technology Data Exchange (ETDEWEB)

    Aramaki, M.; Higashida, K.; Onodera, R. [Kyushu Univ., Fukuoka (Japan). Dept. of Materials Science and Engineering

    1999-05-01

    Superplasticity has been investigated in various ferrous alloys and steels. However, in these materials, especially in hypoeutectoid steels below the A{sub 1} temperature, the relationship between the content of carbon and elongation to failure is not obvious. In the present investigation, the influence of carbon content on superplastic behavior is studied using carbon steels based on Cr-Mo steel. In order to obtain the fine grain structure, a small amount of Ti and B were added and the content of carbon was controlled to be in the range from 0.24 to 0.83 pct. The largest value of elongation to failure was 644 pct, which was obtained for a specimen containing 0.58 pct carbon. The temperature and strain rate at which the maximum value was obtained were 710 C and 5 {times} 10{sup {minus}4} s{sup {minus}1}, respectively. Of all the specimens, this specimen had the minimum grain size. Moreover, the area fraction of carbide took the maximum value at the temperature where the largest elongation value was obtained. These results show that the addition of carbon has an effect on grain refinement by the formation of carbide, but excess amounts of carbon (>0.6 pct) bring about premature failure because of the resulting coarse microstructure and larger carbides.

  19. Return on shares of steel companies under the influence of mergers and acquisitions

    Directory of Open Access Journals (Sweden)

    J. Zuzik

    2015-01-01

    Full Text Available The present article intends to asses returns on shares of the steel companies that were formed based on either merger or acquisition. The analysis included 14 operations in the steel industry. Attention was paid to returns of the companies performing acquisitions, as well as to the returns on shares that presented the acquisition target. The analysis was performed based on the “event study” method, and the analysed event was the announcement or notification of realization of an acquisition. Shares of the target steel companies as well as acquirers are attaining higher returns, but the change was not statistical significant.

  20. THE ELECTROCHEMICAL BEHAVIOR OF OCEANIC MICROBIOLOGICAL INFLUENCED CORROSION ON CARBON STEEL

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The corrosion behavior of carbon steel in the medium of marine microorganisms was investigated by electrochemical impedance spectra, polarization curves, and so on. Experimental results showed that the corrosion potential of carbon steel moved in a negative direction in the unpurified marine microorganism solution, and the polarization style of the cathodic process did not change. The electrochemical impedance spectra showed that the impedance value of the electrode decreased in the medium with bacteria, which indicated that the existence of microorganism could accelerate the corrosion progress of carbon steel.

  1. Influence of Molybdenum Addition on Mechanical Properties of Low Carbon HSLA-100 Steel

    Directory of Open Access Journals (Sweden)

    Bogucki R.

    2014-10-01

    Full Text Available The results of mechanical properties and microstructure observation of low carbon copper bearing steel with high addition of molybdenum are presented in this paper. This steels were characterized by contents of molybdenum in the range from 1% to 3% wt. After the thermo -mechanical processing the steels were subsequently quenched and tempered at different temperatures (500-800 °C for 1h. The changes of mechanical properties as function of tempering temperature were typical for the steel with the copper addition. The sudden drop of impact resistance after tempering from 575 °C to 600 °C was caused probably by precipitates of Laves phase of type Fe2Mo.

  2. Influence of surface texture on the galling characteristics of lean duplex and austenitic stainless steels

    DEFF Research Database (Denmark)

    Wadman, Boel; Eriksen, J.; Olsson, M.;

    2010-01-01

    of sheet materials and lubricants. The strip reduction test, a severe sheet forming tribology test was used to simulate the conditions during ironing. This investigation shows that the risk of galling is highly dependent on the surface texture of the duplex steel. Trials were also performed......Two simulative test methods were used to study galling in sheet forming of two types of stainless steel sheet: austenitic (EN 1.4301) and lean duplex LDX 2101 (EN 1.4162) in different surface conditions. The pin-on-disc test was used to analyse the galling resistance of different combinations...... in an industrial tool used for high volume production of pump components, to compare forming of LDX 2101 and austenitic stainless steel with equal thickness. The forming forces, the geometry and the strains in the sheet material were compared for the same component. It was found that LDX steels can be formed...

  3. Influence of plasma peening on oxidation of H13 hot work steel in water vapor

    Institute of Scientific and Technical Information of China (English)

    MIN Yong-an; XU Xiao; WU Xiao-chun; LI Lin; XU Luo-ping

    2004-01-01

    The surface oxidation films on H13 steel samples, obtained by different oxidation processes were observed by optical microscope. It is shown that the oxidation speed of H13 steel is increased remarkably due to the surface modification of plasma peening. Further researches were made by XRD, SEM and EDS. The activation of H13 surface caused by plasma peening and the subsequent higher oxygen diffusion rate into the steel seem to be the main reasons of higher oxidation speed. The nitride layer, generally formed on the steel surface under plasma nitriding process, can be substituted by oxide in subsequent oxidation process, which can reduce the risk of heat cracking in some hot work applications. Therefore, the plasma nitriding plus oxidation process is a proper choice for some hot work dies, which demands high hardness to avoid indentation as well as high toughness to avoid cracks.

  4. Influence of the Manufacturing Process on Defects in the Galvanized Coating of High Carbon Steel Wires

    National Research Council Canada - National Science Library

    Marcello Gelfi; Luigi Solazzi; Sandro Poli

    2017-01-01

    This study is a detailed failure analysis of galvanized high carbon steel wires, which developed coating cracks during the torsion test performed as a quality control at the end of the manufacturing process...

  5. The influence of nickel-nitrogen ratio on the deformation behaviour of austenitic stainless steels

    CSIR Research Space (South Africa)

    Schmid, OE

    1992-01-01

    Full Text Available This study examines the effect that a partial substitution of nickel with nitrogen has on the deformation behaviour of a metastable austenitic stainless steel, AISI 301. The effect on the tensile deformation behaviour is studied in detail...

  6. Influence of Silica Fume on Corrosion Behaviour of Reinforced Steel in Different Media

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Electrochemical and corrosion behaviour of reinforced steel embedded in cement pastes incorporating differentamounts of silica fume as a partial replacement of cement has been studied in chloride and sulphate solutionsby using different electrochemical techniques. The results indicate that, while steel passivity degree is Iow in thecontrol samples upon soaking in the corrosive media, it has been high in samples incorporating silica fume andincreased with increasing silica fume content. The improvement effect of silica fume may be attributed to the poresolution structure of the cement paste, which limits the mobility of aggressive ions near the surface of the steel. Themechanism of steel corrosion due to chloride and sulphate attack and passivation effect of silica fume are discussed.

  7. Influence of nitrogen alloying on hydrogen embrittlement in AISI 304-type stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Hannula, S.-P.; Hanninen, H.; Tahtinen, S.

    1984-12-01

    Hydrogen embrittlement of AISI 304-type austenitic stainless steels has been studied with special emphasis on the effects of the nitrogen content of the steels. Hydrogen charging was found to degrade the mechanical properties of all the steels studied, as measured by a tensile test. The fracture surfaces of hydrogen charged specimens were brittle cleavage-like whereas the uncharged specimens showed ductile, dimpled fracture. In sensitized materials transgranular cleavage mode of fracture was replaced by an intergranular mode of fracture and the losses of mechanical properties were higher. Nitrogen alloying decreased the hydrogen-induced losses of mechanical properties by increasing the stabilit of austenite. In sensitized steels the stability of austenite and nitrogen content were found to have only a minor effect on hydrogen embrittlement, except when sensitization had caused ..cap alpha..'-martensite transformation at the grain boundaries.

  8. Influence of nitrogen alloying on hydrogen embrittlement in AISI 304-type stainless steels

    Science.gov (United States)

    Hannula, Simo-Pekka; Hänninen, Hannu; Tähtinen, Seppo

    1984-12-01

    Hydrogen embrittlement of AISI 304-type austenitic stainless steels has been studied with special emphasis on the effects of the nitrogen content of the steels. Hydrogen charging was found to degrade the mechanical properties of all the steels studied, as measured by a tensile test. The fracture surfaces of hydrogen charged specimens were brittle cleavage-like whereas the uncharged specimens showed ductile, dimpled fracture. In sensitized materials transgranular cleavage mode of fracture was replaced by an intergranular mode of fracture and the losses of mechanical properties were higher. Nitrogen alloying decreased the hydrogen-induced losses of mechanical properties by increasing the stability of austenite. In sensitized steels the stability of austenite and nitrogen content were found to have only a minor effect on hydrogen embrittlement, except when sensitization had caused α'-martensite transformation at the grain boundaries.

  9. Influence of Unstable Non-equilibrium Liquid Iron Oxide on Clustering of Alumina Particles in Steel

    National Research Council Canada - National Science Library

    Mizoguchi, Toshiaki; Ueshima, Yoshiyuki; Sugiyama, Masaaki; Mizukami, Kazumi

    2013-01-01

    .... It was found that a small amount of liquid FeO could accelerate the clustering of alumina inclusions in aluminum-killed steel because of the strong liquid-capillary negative pressure of liquid FeO...

  10. Parameters influencing the transgranular stress corrosion cracking behaviour of austenitic stainless steels in systems conveying reactor coolant

    Energy Technology Data Exchange (ETDEWEB)

    Kilian, R.; Wesseling, U. [Framatome ANP (Germany); Wachter, O. [E.ON Kernkraft (Germany); Widera, M. [RWE Power (Germany); Brummer, G. [HEW - (Germany); Ilg, U. [EnBW - (Germany)

    2002-07-01

    During replacement of an auxiliary system in the German PWR KKS (NPP Stade) a damage was detected in a valve housing and in the connected piping both made from stabilised austenitic stainless steel. During operation stagnant conditions are present in this area. Based on the failure analysis chloride induced stress corrosion cracking (SCC) was found as the dominating root cause. In the open literature many cases of corrosion observed in the water/steam interface in valve components as well as in adjacent portions of auxiliary circuits made of un-stabilized stainless steels are mentioned. A common feature of the reported cases is that transgranular cracking was found. Extensive laboratory investigations revealed that non-stabilised austenitic stainless steels are also sensitive to transgranular cracking in boric acid solutions particularly in concentrated solutions. Often these solutions are contaminated with chlorides and/or oxygen is present. Taking into account the literature data the question could arise whether the above mentioned cracking may be also caused by boric acid attack. Thus, for stabilised stainless steels laboratory exposure tests at 80 C in saturated aerated boric acid solution and at 300 C in (at 100 C) saturated, oxygen free boric acid solution have been performed. Double-U-bend specimens and wedge loaded 1T-CT specimens made of Ti- and Nb-stabilised austenitic stainless steels were used. The results revealed no evidence of crack initiation and crack growth. Based on the laboratory results and the literature data an attempt is undertaken to separate parameters influencing chloride induced SCC from the effect of boric acid. (authors)

  11. Modelling the influence of age of steel fibre reinforced self : compacting concrete on its compressive behaviour

    OpenAIRE

    Cunha, Vitor M. C. F.; Barros, Joaquim A.O.; Sena-Cruz, José

    2008-01-01

    Documento submetido para revisão pelos pares. A publicar na revista "Materials and Structures Journal". ISSN 1359-5997. Steel fibre reinforced self-compacting concrete (SFRSCC) can combine the benefits of self-consolidating concrete technology with those derived from adding steel fibres to quasi-brittle cement based materials. In a recent applied research project joining pre-casting industry, private and public research institutions, a method was developed to design cost-...

  12. Influences of silicon on the work hardening behavior and hot deformation behavior of Fe–25 wt%Mn–(Si, Al) TWIP steel

    Energy Technology Data Exchange (ETDEWEB)

    Li, Dejun, E-mail: lidejun352@163.com [CNPC Tubular Goods Research Institute, Xi’an 710077 (China); The Key Lab for Petroleum Tubular Goods Engineering, CNPC, Xi’an 710077 (China); Feng, Yaorong; Song, Shengyin; Liu, Qiang; Bai, Qiang [CNPC Tubular Goods Research Institute, Xi’an 710077 (China); The Key Lab for Petroleum Tubular Goods Engineering, CNPC, Xi’an 710077 (China); Ren, Fengzhang [School of Material Science and Engineering, Henan University of Science and Technology, Luoyang 471023 (China); Shangguan, Fengshou [CNPC Tubular Goods Research Institute, Xi’an 710077 (China); The Key Lab for Petroleum Tubular Goods Engineering, CNPC, Xi’an 710077 (China)

    2015-01-05

    Highlights: • Influence of Si on work hardening behavior of Fe–25 wt%Mn TWIP steel was investigated. • Influence of Si on hot deformation behavior of Fe–25 wt%Mn TWIP steel was studied. • Si blocks dislocation glide and favors mechanical twinning in Fe–25 wt%Mn TWIP steel. • The addition of Si increases the hot deformation activation energy of Fe–25 wt%Mn TWIP steel. • The addition of Si retards the nucleation and growth of DRX grains of Fe–25 wt%Mn TWIP steel. - Abstract: The influence of silicon on mechanical properties and hot deformation behavior of austenitic Fe–25 wt%Mn TWIP steel was investigated by means of the comparison research between 25Mn3Al and 25Mn3Si3Al steel. The results show that the 25Mn3Si3Al steel has higher yield strength and higher hardness than that of 25Mn3Al steel because of the solution strengthening caused by Si atoms and possesses higher uniform deformation ability and tensile strength than that of 25Mn3Al steel due to the higher work hardening ability of 25Mn3Si3Al steel. 25Mn3Si3Al steel presents a clear four-stage curve of work hardening rate in course of cold compression. Quite the opposite, the 25Mn3Al steel presents a monotonic decline curve of work hardening rate. The difference of the work hardening behavior between 25Mn3Al and 25Mn3Si3Al steel can be attributed to the decline of stacking fault energy (SFE) caused by the addition of 3 wt% Si. The dislocation glide plays an important role in the plastic deformation of 25Mn3Al steel even though the mechanical twinning is still one of the main deformation mechanisms. The 3 wt% Si added into the 25Mn3Al steel blocks the dislocation glide and promotes the mechanical twinning, and then the dislocation glide characteristics cannot be observed in cold deformed microstructure of 25Mn3Si3Al steel. The hot compression tests reveal that the hot deformation resistance of the 25Mn3Si3Al steel is significantly higher than that of the 25Mn3Al steel due to the solid

  13. Influence of cooling rate on secondary phase precipitation and proeutectoid phase transformation of micro-alloyed steel containing vanadium

    Science.gov (United States)

    Dou, Kun; Meng, Lingtao; Liu, Qing; Liu, Bo; Huang, Yunhua

    2016-05-01

    During continuous casting process of low carbon micro-alloyed steel containing vanadium, the evolution of strand surface microstructure and the precipitation of secondary phase particles (mainly V(C, N)) are significantly influenced by cooling rate. In this paper, influence of cooling rate on the precipitation behavior of proeutectoid α-ferrite at the γ-austenite grain boundary and in the steel matrix are in situ observed and analyzed through high temperature confocal laser scanning microscopy. The relationship between cooling rate and precipitation of V(C, N) from steel continuous casting bloom surface microstructure is further studied by scanning electron microscopy and electron dispersive spectrometer. Relative results have shown the effect of V(C, N) precipitation on α-ferrite phase transformation is mainly revealed in two aspects: (i) Precipitated V(C, N) particles act as inoculant particles to promote proeutectoid ferrite nucleation. (ii) Local carbon concentration along the γ-austenite grain boundaries is decreased with the precipitation of V(C, N), which in turn promotes α-ferrite precipitation.

  14. Influence of the post-weld surface treatment on the corrosion resistance of the duplex stainless steel 1.4062

    Science.gov (United States)

    Rosemann, P.; Müller, C.; Baumann, O.; Modersohn, W.; Halle, T.

    2017-03-01

    The duplex stainless steel 1.4062 (X2CrNiN22-2) is used as alternative material to austenitic stainless steels in the construction industry. The corrosion resistance of welded seams is influenced by the base material, the weld filler material, the welding process and also by the final surface treatment. The scale layer next to the weld seam can be removed by grinding, pickling, electro-polished or blasting depending on the application and the requested corrosion resistance. Blasted surfaces are often used in industrial practice due to the easier and cheaper manufacturing process compared to pickled or electro-polished surfaces. Furthermore blasting with corundum-grain is more effective than blasting with glass-beads which also lower the process costs. In recent years, stainless steel surfaces showed an unusually high susceptibility to pitting corrosion after grinding with corundum. For this reason, it is now also questioned critically whether the corrosion resistance is influenced by the applied blasting agent. This question was specifically investigated by comparing grinded, pickled, corundum-grain- and glass-bead-blasted welding seams. Results of the SEM analyses of the blasting agents and the blasted surfaces will be presented and correlated with the different performed corrosion tests (potential measurement, KorroPad-test and pitting potential) on welding seams with different surface treatments.

  15. Influence of microstructure and elemental partitioning on pitting corrosion resistance of duplex stainless steel welding joints

    Science.gov (United States)

    Zhang, Zhiqiang; Jing, Hongyang; Xu, Lianyong; Han, Yongdian; Zhao, Lei; Zhang, Jianli

    2017-02-01

    The influences of microstructure and elemental partitioning on pitting corrosion resistance of duplex stainless steel joints welded by gas tungsten arc welding (GTAW) and flux-cored arc welding (FCAW) with different shielding gas compositions were studied by optical microscopy, electron backscatter diffraction, scanning electron microscopy, transmission electron microscopy, energy dispersive spectroscopy, electron probe microanalysis, and potentiostatic and potentiodynamic polarization methods The adding 2% N2 in shielding gas facilitated primary austenite formation in GTAW weld metal (WM) and suppressed Cr2N precipitation in GTAW weld root. In the HAZ, the banded microstructure disappeared while the coarse ferrite grains maintained same orientation as the banded ferrite in the BM. In the WM, the ferrite had one single orientation throughout a grain, whereas several families of austenite appeared. The austenite both in BM and WM enriched in Ni and nitro`gen, while Cr and Mo were concentrated in the ferrite and thus no element showed clear dendritic distribution in the WM (ER2209 and E2209T1). In addition, the secondary austenite had higher Ni content but lower Cr and Mo content than the primary austenite. The N2-supplemented shielding gas promoted nitrogen solid-solution in the primary and secondary austenite. Furthermore, the secondary austenite had relatively lower pitting resistance equivalent number (PREN) than the ferrite and primary austenite, thereby resulting in its preferential corrosion. The Cr2N precipitation led to relatively poor resistance to pitting corrosion in three HAZs and pure Ar shielding GTAW weld root. The N2-supplemented shielding gas improved pitting corrosion resistance of GTAW joint by increasing PREN of secondary austenite and suppressing Cr2N precipitation. In addition, the FCAW WM had much poorer resistance to pitting corrosion than the GTAW WM due to many O-Ti-Si-Mn inclusions. In the BM, since the austenite with lower PREN compared

  16. Influence of ph on corrosion control of carbon steel by peroxide injection in sour water

    Energy Technology Data Exchange (ETDEWEB)

    Vieira, Martins Magda; Baptista, Walmar; Joia, Carlos Jose Bandeira de Mello [PROTEMP - PETROBRAS/CENPES, Cidade Universitaria, Quadra 7, Rio de Janeiro, CEP 21949-900 (Brazil); Ponciano, Gomes Jose Antonio da Cunha [Departamento de Engenharia Metalurgica e de Materiais-COPPE/UFRJ, Cidade Universitaria, Rio de Janeiro (Brazil)

    2004-07-01

    Sour hydrogen damage is considered the most important corrosive process in the light-ends recovery section of Fluid Catalytic Cracking Units (FCCU). Corrosion in this condition is due to heavy gas oil that originates great amount of contaminants, such as H{sub 2}S, NH{sub 3} and HCN. Hydrogen absorption is promoted by the presence of free cyanides in the environment. The attenuation of this process requires the use of some inhibitors, such as oxygen, hydrogen peroxide (H{sub 2}O{sub 2}) or commercial polysulfides. The effect of these compounds is to neutralize free cyanides (CN{sup -}) into thio-sulfides (SCN{sup -}). When peroxide injection is selected, cyanide concentration in sour water has been used as key parameter to start the peroxide introduction. However, the importance of pH in this system has been pointed out by many authors. The aim of this work is to investigate the influence of pH when peroxide injection is carried out in less alkaline conditions of sour water. Electrochemical techniques - like anodic polarization and hydrogen permeation tests - and weight loss measurements were used to evaluate the effectiveness of corrosion control of carbon steel. It was concluded that at pH 7.5 peroxide injection can drive to an increment of the corrosion rate. Besides that, it was concluded that hydrogen permeation into the metal is promoted. Both detrimental effects were due to elemental sulfur generation in this pH range. The adoption of pH as a key parameter for peroxide injection is then suggested. (authors)

  17. Influence of heat input on weld bead geometry using duplex stainless steel wire electrode on low alloy steel specimens

    OpenAIRE

    Ajit Mondal; Manas Kumar Saha; Ritesh Hazra; Santanu Das

    2016-01-01

    Gas metal arc welding cladding becomes a popular surfacing technique in many modern industries as it enhances effectively corrosion resistance property and wear resistance property of structural members. Quality of weld cladding may be enhanced by controlling process parameters. If bead formation is found acceptable, cladding is also expected to be good. Weld bead characteristics are often assessed by bead geometry, and it is mainly influenced by heat input. In this paper, duplex stainless st...

  18. The Influence of Nano-Al2O3 Additive on the Adhesion between Epoxy Resin and Steel Substrate

    Institute of Scientific and Technical Information of China (English)

    ZHAILan-lan; LINGGuo-ping

    2004-01-01

    The influence of nano-A1203 additive on the adhesion between epoxy resin and steel substrate has been investigated. The results of tensile testing indicated that the adhesion strength was increased dramatically by addition of Al2O3 nanoparticles in epoxy resin compared with that of the unmodified resin. The highest adhesion strength was obtained with 1 wt% nano-Al2O3 added in epoxy adhesive, more than two times higher than that of the unmodified. Scanning electronic microscope (SEM) revealed that a boundary layer exists between epoxy and steel substrate, energy spectrum analysis indicates there is enrichment of the nano-Al2O3 particle. Those results confirmed that the nano-Al2O3 additive was closely related to the change of interface morphology and the improvement of adhesion strength. The reason for adhesion improvement was also be discussed.

  19. The Influence of Nano-Al2O3 Additive on the Adhesion between Epoxy Resin and Steel Substrate

    Institute of Scientific and Technical Information of China (English)

    ZHAI Lan-lan; LING Guo-ping

    2004-01-01

    The influence of nano-Al2O3 additive on the adhesion between epoxy resin and steel substrate has been investigated. The results of tensile testing indicated that the adhesion strength was increased dramatically by addition of Al2O3 nanoparticles in epoxy resin compared with that of the unmodified resin. The highest adhesion strength was obtained with 1 wt% nano-Al2O3 added in epoxy adhesive, more than two times higher than that of the unmodified. Scanning electronic microscope (SEM) revealed that a boundary layer exists between epoxy and steel substrate, energy spectrum analysis indicates there is enrichment of the nano-Al2O3 particle. Those results confirmed that the nano-Al2O3 additive was closely related to the change of interface morphology and the improvement of adhesion strength. The reason for adhesion improvement was also be discussed.

  20. Influence of structural parameters on the tendency of VVER-1000 reactor pressure vessel steel to temper embrittlement

    Science.gov (United States)

    Gurovich, B.; Kuleshova, E.; Zabusov, O.; Fedotova, S.; Frolov, A.; Saltykov, M.; Maltsev, D.

    2013-04-01

    In this paper the influence of structural parameters on the tendency of steels to reversible temper embrittlement was studied for assessment of performance properties of reactor pressure vessel steels with extended service life. It is shown that the growth of prior austenite grain size leads to an increase of the critical embrittlement temperature in the initial state. An embrittlement heat treatment at the temperature of maximum manifestation of temper embrittlement (480 °C) shifts critical embrittlement temperature to higher values due to the increase of the phosphorus concentration on grain boundaries. There is a correlation between phosphorus concentration on boundaries of primary austenite grains and the share of brittle intergranular fracture (that, in turn, depends on impact test temperature) in the fracture surfaces of the tested Charpy specimens.

  1. Influence of processing parameters on lattice parameters in laser deposited tool alloy steel

    Energy Technology Data Exchange (ETDEWEB)

    Sun, G.F., E-mail: gfsun82@gmail.com [Center for Laser-Aided Intelligent Manufacturing, University of Michigan, Ann Arbor, MI, 48109 (United States); School of Mechanical Engineering, Jiangsu University, Zhenjiang, Jiangsu, 212013 (China); Bhattacharya, S. [Center for Laser-Aided Intelligent Manufacturing, University of Michigan, Ann Arbor, MI, 48109 (United States); Dinda, G.P.; Dasgupta, A. [Center for Advanced Technologies, Focus: Hope, Detroit, MI, 48238 (United States); Mazumder, J. [Center for Laser-Aided Intelligent Manufacturing, University of Michigan, Ann Arbor, MI, 48109 (United States)

    2011-06-15

    Highlights: {yields} Orientation relationships among phases in the DMD are given. {yields} Martensite lattice parameters increased with laser specific energy. {yields} Austenite lattice parameters decreased with laser specific energy. - Abstract: Laser aided direct metal deposition (DMD) has been used to form AISI 4340 steel coating on the AISI 4140 steel substrate. The microstructural property of the DMD coating was analyzed by means of scanning electron microscopy, transmission electron microscopy and X-ray diffractometry. Microhardness of the DMD was measured with a Vickers microhardness tester. Results indicate that DMD can be used to form dense AISI 4340 steel coatings on AISI 4140 steel substrate. The DMD coating is mainly composed of martensite and retained austenite. Consecutive thermal cycles have a remarkable effect on the microstructure of the plan view of the DMD coating and on the corresponding microhardness distribution. Orientation relationships among austenite, martensite and cementite in the DMD coating followed the ones in conventional heat treated steels. As the laser specific energy decreased, cooling rate increased, and martensite peaks broadened and shifted to a lower Bragg's angle. Also martensite lattice parameters increased and austenite lattice parameters decreased due to the above parameter change.

  2. Influence of surface defects on the fatigue crack initiation in pearlitic steel

    Directory of Open Access Journals (Sweden)

    Toribio Jesús

    2014-06-01

    Full Text Available Tensile fatigue tests were performed under load control, with constant stress range Δσ on pearlitic steel wires, from the hot rolled bar to the commercial prestressing steel wire (which has undergone seven cold drawing steps. Results show that fatigue cracks in pearlitic steels initiate at the wire surface starting from small defects, whose size decreases with the drawing process. Fatigue cracks created from defects (initiation phase exhibit a fractographic appearance consisting of ductile microtearing events which can be classified as tearing topography surface or TTS, and exhibit a remarkably lower spacing in the prestressing steel wire than in the hot rolled bar. In addition, some S-N tests were performed in both material forms under a stress range of about half the yield strength. In these tests, the main part of the fatigue life corresponds to the propagation stage in the hot rolled bar whereas such a main part of the life is associated with the initiation stage in the case of the prestressing steel wire.

  3. Influence of femtosecond laser produced nanostructures on biofilm growth on steel

    Science.gov (United States)

    Epperlein, Nadja; Menzel, Friederike; Schwibbert, Karin; Koter, Robert; Bonse, Jörn; Sameith, Janin; Krüger, Jörg; Toepel, Jörg

    2017-10-01

    Biofilm formation poses high risks in multiple industrial and medical settings. However, the robust nature of biofilms makes them also attractive for industrial applications where cell biocatalysts are increasingly in use. Since tailoring material properties that affect bacterial growth or its inhibition is gaining attention, here we focus on the effects of femtosecond laser produced nanostructures on bacterial adhesion. Large area periodic surface structures were generated on steel surfaces using 30-fs laser pulses at 790 nm wavelength. Two types of steel exhibiting a different corrosion resistance were used, i.e., a plain structural steel (corrodible) and a stainless steel (resistant to corrosion). Homogeneous fields of laser-induced periodic surface structures (LIPSS) were realized utilizing laser fluences close to the ablation threshold while scanning the sample under the focused laser beam in a multi-pulse regime. The nanostructures were characterized with optical and scanning electron microscopy. For each type of steel, more than ten identical samples were laser-processed. Subsequently, the samples were subjected to microbial adhesion tests. Bacteria of different shape and adhesion behavior (Escherichia coli and Staphylococcus aureus) were exposed to laser structures and to polished reference surfaces. Our results indicate that E. coli preferentially avoids adhesion to the LIPSS-covered areas, whereas S. aureus favors these areas for colonization.

  4. Influence of Prior Fatigue Cycling on Creep Behavior of Reduced Activation Ferritic-Martensitic Steel

    Science.gov (United States)

    Sarkar, Aritra; Vijayanand, V. D.; Parameswaran, P.; Shankar, Vani; Sandhya, R.; Laha, K.; Mathew, M. D.; Jayakumar, T.; Rajendra Kumar, E.

    2014-06-01

    Creep tests were carried out at 823 K (550 °C) and 210 MPa on Reduced Activation Ferritic-Martensitic (RAFM) steel which was subjected to different extents of prior fatigue exposure at 823 K at a strain amplitude of ±0.6 pct to assess the effect of prior fatigue exposure on creep behavior. Extensive cyclic softening that characterized the fatigue damage was found to be immensely deleterious for creep strength of the tempered martensitic steel. Creep rupture life was reduced to 60 pct of that of the virgin steel when the steel was exposed to as low as 1 pct of fatigue life. However, creep life saturated after fatigue exposure of 40 pct. Increase in minimum creep rate and decrease in creep rupture ductility with a saturating trend were observed with prior fatigue exposures. To substantiate these findings, detailed transmission electron microscopy studies were carried out on the steel. With fatigue exposures, extensive recovery of martensitic-lath structure was distinctly observed which supported the cyclic softening behavior that was introduced due to prior fatigue. Consequently, prior fatigue exposures were considered responsible for decrease in creep ductility and associated reduction in the creep rupture strength.

  5. Extracellular Electron Transfer Is a Bottleneck in the Microbiologically Influenced Corrosion of C1018 Carbon Steel by the Biofilm of Sulfate-Reducing Bacterium Desulfovibrio vulgaris.

    Directory of Open Access Journals (Sweden)

    Huabing Li

    Full Text Available Carbon steels are widely used in the oil and gas industry from downhole tubing to transport trunk lines. Microbes form biofilms, some of which cause the so-called microbiologically influenced corrosion (MIC of carbon steels. MIC by sulfate reducing bacteria (SRB is often a leading cause in MIC failures. Electrogenic SRB sessile cells harvest extracellular electrons from elemental iron oxidation for energy production in their metabolism. A previous study suggested that electron mediators riboflavin and flavin adenine dinucleotide (FAD both accelerated the MIC of 304 stainless steel by the Desulfovibrio vulgaris biofilm that is a corrosive SRB biofilm. Compared with stainless steels, carbon steels are usually far more prone to SRB attacks because SRB biofilms form much denser biofilms on carbon steel surfaces with a sessile cell density that is two orders of magnitude higher. In this work, C1018 carbon steel coupons were used in tests of MIC by D. vulgaris with and without an electron mediator. Experimental weight loss and pit depth data conclusively confirmed that both riboflavin and FAD were able to accelerate D. vulgaris attack against the carbon steel considerably. It has important implications in MIC failure analysis and MIC mitigation in the oil and gas industry.

  6. Influence of Heat Treatment on the Corrosion of Microalloyed Steel in Sodium Chloride Solution

    Directory of Open Access Journals (Sweden)

    Asiful Hossain Seikh

    2013-01-01

    Full Text Available Microalloyed Steels find wide application in car bodies and other engineering parts because of its high strength as well as high ductility. Very fine grained microstructure is the reason behind the combination of strength and ductility. It has been reported that repeated quenching leads to further refining of microstructure. In the present investigation, corrosion resistance property of E34 microalloy steel has been studied in 3.5% NaCl solution in different microstructural conditions such as the as rolled one and three repeated quenched conditions. Weight loss, potentiodynamic polarization method, and electrochemical impedance spectroscopy (EIS techniques have been used. To reveal the corrosion resistance of different treated steels, some significant characterization parameters such as Ecorr, Icorr, Rp, and Rct in linear polarization and EIS curves were analyzed and compared. It is found that with repeated recrystallization grains become finer, and corrosion rate increases suggesting that a compromise has to strike between high mechanical property and corrosion rate.

  7. Influence of helium on impact properties of reduced-activation ferritic/martensitic Cr-steels

    Science.gov (United States)

    Lindau, R.; Möslang, A.; Preininger, D.; Rieth, M.; Röhrig, H. D.

    Instrumented Charpy impact tests of the reduced activation type 8Cr2WVTa steel F82H have been performed after homogeneous implantation of 300 appm helium at 250°C. The results are compared with investigations on mixed spectrum neutron irradiated (HFR Petten) specimens. After neutron irradiation at 250°C to the same low damage dose of 0.2 dpa, the ductile-brittle transition temperature shift (ΔDBTT) amounts to 18°C, whereas a much higher ΔDBTT of 42°C has been measured after helium implantation. These results are compared with other neutron irradiated ferritic/martensitic steels having different boron levels and thus different helium contents. A model is proposed which describes the dynamic brittle fracture of martensitic/ferritic steels by a stress-induced propagation of micro-cracks, taking into account radiation induced hardening as well as helium bubble formation.

  8. Influence of mill scale and rust layer on the corrosion resistance of low-alloy steel in simulated concrete pore solution

    Science.gov (United States)

    Shi, Jin-jie; Ming, Jing

    2017-01-01

    Electrochemical impedance spectroscopy, cyclic potentiodynamic polarization measurements, and scanning electron microscopy in conjunction with energy-dispersive X-ray spectroscopy were used to investigate the influence of mill scale and rust layer on the passivation capability and chloride-induced corrosion behaviors of conventional low-carbon (LC) steel and low-alloy (LA) steel in simulated concrete pore solution. The results show that mill scale exerts different influences on the corrosion resistance of both steels at various electrochemical stages. We propose that the high long-term corrosion resistance of LA steel is mainly achieved through the synergistic effect of a gradually formed compact, adherent and well-distributed Cr-enriched inner rust layer and the physical barrier protection effect of mill scale.

  9. The influence of aluminum and carbon on the abrasion resistance of high manganese steels

    Science.gov (United States)

    Buckholz, Samuel August

    Abrasive wear testing of lightweight, austenitic Fe-Mn-Al-C cast steel has been performed in accordance with ASTM G65 using a dry sand, rubber wheel, abrasion testing apparatus. Testing was conducted on a series of Fe-30Mn-XAl-YC-1Si-0.5Mo chemistries containing aluminum levels from 2.9 to 9.5 wt.% and carbon levels from 0.9 to 1.83 wt.%. Solution treated materials having an austenitic microstructure produced the highest wear resistance. Wear resistance decreased with higher aluminum, lower carbon, and higher hardness after age hardening. In the solution treated condition the wear rate was a strong function of the aluminum to carbon ratio and the wear rate increased with a parabolic dependence on the Al/C ratio, which ranged from 1.8 to 10.2. Examination of the surface wear scar revealed a mechanism of plowing during abrasion testing and this method of material removal is sensitive to work hardening rate. Work hardening behavior was determined from tensile tests and also decreased with increasing Al/C ratio and after aging hardening. The loss of wear resistance is related to short range ordering of Al and C in the solution treated materials and kappa-carbide precipitation in age hardened materials and both contribute to planar slip and lower work hardening rates. A high carbon tool steel (W1) and a bainitic low alloy steel (SAE 8620) were also tested for comparison. A lightweight steel containing 6.5 wt.% Al and 1.2 wt.% C has wear resistance comparable to within 5% of the bainitic SAE 8620 steel forging currently used for the Bradley Fighting Vehicle track shoe and this cast Fe-Mn-Al-C steel, at equivalent tensile properties, would be 10% lighter.

  10. Electron transfer mediators accelerated the microbiologically influence corrosion against carbon steel by nitrate reducing Pseudomonas aeruginosa biofilm.

    Science.gov (United States)

    Jia, Ru; Yang, Dongqing; Xu, Dake; Gu, Tingyue

    2017-12-01

    Electron transfer is a rate-limiting step in microbiologically influenced corrosion (MIC) caused by microbes that utilize extracellular electrons. Cross-cell wall electron transfer is necessary to transport the electrons released from extracellular iron oxidation into the cytoplasm of cells. Electron transfer mediators were found to accelerate the MIC caused by sulfate reducing bacteria. However, there is no publication in the literature showing the effect of electron transfer mediators on MIC caused by nitrate reducing bacteria (NRB). This work demonstrated that the corrosion of anaerobic Pseudomonas aeruginosa (PAO1) grown as a nitrate reducing bacterium biofilm on C1018 carbon steel was enhanced by two electron transfer mediators, riboflavin and flavin adenine dinucleotide (FAD) separately during a 7-day incubation period. The addition of either 10ppm (w/w) (26.6μM) riboflavin or 10ppm (12.7μM) FAD did not increase planktonic cell counts, but they increased the maximum pit depth on carbon steel coupons considerably from 17.5μm to 24.4μm and 25.0μm, respectively. Riboflavin and FAD also increased the specific weight loss of carbon steel from 2.06mg/cm(2) to 2.34mg/cm(2) and 2.61mg/cm(2), respectively. Linear polarization resistance, electrochemical impedance spectroscopy and potentiodynamic polarization curves all corroborated the pitting and weight loss data. Copyright © 2017 Elsevier B.V. All rights reserved.

  11. The Influence of Chemical Composition of Steels on the Numerical Simulation of a Continuesly Cast of Billet

    Directory of Open Access Journals (Sweden)

    František KAVIČKA

    2010-12-01

    Full Text Available The chemical composition of steels has significant influence on the actual concasting process, and on the accuracy of its numerical simulation and optimization. The chemical composition of steel affects the thermophysical properties (heat conductivity, specific heat capacity and density in the solid and liquid states often requires more time than the actual numerical calculation of the temperature fields of a continuously cast steel billet. Therefore, an analysis study of these thermophysical properties was conducted. The order of importance within the actual process and the accuracy of simulation were also determined. The order of significance of the chemical composition on thermophysical properties was determined with respect to the metallurgical length. The analysis was performed by means of a so-called calculation experiment, i.e. by means of the original numerical concasting model developed by the authors of this paper. It is convenient to conduct such an analysis in order to facilitate the simulation of each individual case of concasting, thus enhancing the process of optimization.

  12. Influence of Rare Earth Elements on Microstructure and Mechanical Properties of Cast High-Speed Steel Rolls

    Institute of Scientific and Technical Information of China (English)

    Wang Mingjia; Mu Songmei; Sun Feifei; Wang Yan

    2007-01-01

    The influence of rare earth (RE) elements on the solidification process and eutectic transformation and mechanical properties of the high-V type cast, high-speed steel roll was studied. Test materials with different RE additions were prepared on a horizontal centrifugal casting machine. The solidification process, eutectic structure transformation, carbide morphology, and the elements present, were all investigated by means of differential scanning calorimetry (DSC) and scanning electron microscopy energy dispersive spectrometry (SEM-EDS). The energy produced by crack initiation and crack extension was analyzed using a digital impact test machine. It was found that rare earth elements increased the tensile strength of the steel by inducing crystallization of earlier eutectic γ-Fe during the solidification process, which in turn increased the solidification temperature and thinned the dendritic grains. Rare earth elements with large atomic radius changed the lattice parameters of the MC carbide by forming rare earth carbides. This had the effect of dispersing long-pole MC carbides to provide carbide grains, thereby, reducing the formation of the gross carbide and making more V available, to increase the secondary hardening process and improve the hardness level. The presence of rare earth elements in the steel raised the impact toughness by changing the mechanism of MC carbide formation, thereby increasing the crack initiation energy.

  13. INFLUENCE OF CARBON CONTENT OF MARTENSITE STEELS ON HARDNESS RE-DISTRIBUTION NEAR WORN SURFACE

    Institute of Scientific and Technical Information of China (English)

    Y.P. Ma

    2002-01-01

    After three-body abrasion, the hardness re-distribution near the worn surface has aclose relationship with the carbon content of martensite steel. It is considered thatthere is a competition between the work-hardening and the temper softening, whichresults from deformation and friction heat of material. When the carbon content ofmartensite steel is below about 0.6%, the subsurface hardness distribution of materialis a softened layer sandwiched between two hardened layers, but above 0.6%C, nosoftened region appears on the hardness re-distribution curve.

  14. Influence Of Heat Treatment On Duplex Stainless Steel To Study The Material Properties

    Directory of Open Access Journals (Sweden)

    Jithin M

    2015-02-01

    Full Text Available Abstract The various heat treatment processes are annealing normalizing hardening tempering spheroidising surface hardening flame and induction hardening nitriding cyaniding carbonitriding carburizing etc Heat treatment on duplex stainless steel is to improve ductility toughness strength hardness and to relieve internal stress developed in the material. Here basically the experiment of hardness test impact test wear test and compression is done to get idea about heat treated duplex stainless steel which has extensive uses in all industries and scientific research and development fields.

  15. Influence of initial thermomechanical treatment on high temperature properties of laves phase strengthened ferritic steels

    OpenAIRE

    Talik, Michal

    2016-01-01

    The aim of this work was to design 17 wt%Cr Laves phase strengthened HiperFer (Highperfomrance Ferrite) steels and evaluate their properties. This class of steel is supposed to be used in Advanced Ultra Super Critical power plants. Such cycles exhibit higher eciencyand are environmentally friendly, but improved materials with high resistance to reside/steam oxidation and sucient creep strength are required. The work focused on the characterization of creep properties of 17Cr2.5W0.5Nb0.25Si he...

  16. Influence of Impact Energy on Impact Corrosion-abrasion of High Manganese Steel

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The impact corrosion-abrasion properties and mechanism of high manganese steel were investigated under different impact energies. The result shows that the wearability of the steel decreases with the increase of the impact energy. The dominant failure mechanism at a lower impact energy is the rupture of extrusion edge along root and a slight shallow-layer spalling. It transforms to shallow-layer fatigue flaking along with serious corrosion-abrasion when the impact energy is increased, and finally changes to bulk flaking of hardened layer caused by deep work-hardening and heavy corrosion-abrasion.

  17. Influence of grain size on radiation effects in a low carbon steel

    Energy Technology Data Exchange (ETDEWEB)

    Alsabbagh, Ahmad, E-mail: ahalsabb@ncsu.edu [Department of Nuclear Engineering, North Carolina State University (United States); Valiev, Ruslan Z. [Institute of Physics of Advanced Materials, Ufa State Aviation Technical University (Russian Federation); Murty, K.L. [Department of Nuclear Engineering, North Carolina State University (United States)

    2013-11-15

    Ultra-fine grain (UFG) metals with a relatively large volume of interfaces are expected to be more radiation resistant than conventional metals; grain boundaries act as unsaturable sinks for neutron irradiation induced defects. Effects of neutron irradiation on conventional and ultra-fine grain structured carbon steel are studied using the PULSTAR reactor at NC State University to relatively low fluence (∼1.15 × 10{sup −3} dpa). The low dose irradiation of ultrafine grained carbon steel revealed minute radiation effects in contrast to the observed radiation hardening and reduction of ductility in its conventional grained counterpart.

  18. Low friction slip-rolling contacts. Influences of alternative steels, high performance thin film coatings and lubricants

    Energy Technology Data Exchange (ETDEWEB)

    Scholz, Christian

    2013-02-01

    and NC310YW (Aubert and Duval) as well as CSS-42L (Latrobe Specialty Steel Company), in combination with thin film coatings, even if they compete in the uncoated state, the Hertzian contact pressures could be increased up to P{sub 0max} = 4.2 GPa (F{sub N} = 5,000 N) without any surface failures of coating or substrate. It was shown that selected thin film coatings can minimize the wear rates down to nearly 'zero-wear' in highly stressed contacts [Woy08] [Woy11]. In addition, the studies revealed not only the high potential in slip-rolling resistance, but also a possible friction reduction down to 0.047 by use of uncoated steels with increased toughness. Compared to steels like 100Cr6H and Cronidur 30 this means a reduction in friction of approximately 40% under identical testing conditions. Different test series with newly developed base oil-additive formulations were investigated with specific emphasis on the frictional behavior of selected bio-no-tox EP/AW additives and friction modifiers. Additional influencing factors like the structural and surface conditions of the steels/coatings before and after the tests were analyzed by means of REM, EDX, XRD and TEM.

  19. Fatigue Property of Open-Hole Steel Plates Influenced by Bolted Clamp-up and Hole Fabrication Methods

    Directory of Open Access Journals (Sweden)

    Zhi-Yu Wang

    2016-08-01

    Full Text Available Steel plates with open holes are commonly used in structural assemblies. The fatigue properties of such details are influenced by bolted clamp-up and hole fabrication methods. The fracture surface, stiffness degradation and fatigue life of test specimens are investigated in detail and compared with the contemporary test data. The analysis results show that the presence of draglines greatly influences the fatigue crack initiation at the open-hole cut by laser. The bolted clamp-up condition greatly enhances the stiffness and the fatigue life of the open-hole details. A discussion is also made from a comparison with the referred fatigue life of hole fabrication details, such as the influence of plate thickness and plasma cutting, drilling and oxy-fuel gas cutting, with the details studied herein. This work could enhance the understanding of the fatigue property and design of such details.

  20. Influence of non-metallic inclusions on the strength properties of screws made of 35B2+Cr steel after softening

    OpenAIRE

    Krawczyk, J.; Pawłowski, B

    2012-01-01

    Purpose: This paper presents the results of the research on the influence of non-metallic inclusions on strength properties of 35B2+Cr steel screws.Design/methodology/approach: The investigations were carried out on screws after softening. The investigated steels with different fraction of non-metallic inclusions were delivered by three different suppliers.Findings: It was proved, that in spite of the level of fraction of non-metallic inclusions compatible with the corresponding standards, th...

  1. Influence of the placement of a previously derived ellipse shaped aperture in the starting material on the processing with drawing of the cold rolled sheet steels

    OpenAIRE

    Cvetkov, Slavco; Simeonov, Simeon; Dimitrov, Sasko

    2011-01-01

    In this paper, a research of the impact of the position regarding the main directions of the plane anisotropy of previously derived ellipse shaped aperture (opening) in starting material on the workability of the drawn cold rolled sheet steel is made. This influence is researched using hydraulic drawing of cold rolled sheet steel with previous derived ellipse shaped openings placed in the directions of plane anisotropy. The research aims to show how the position of the previous derived el...

  2. Influence of Portland Cement Class on the Corrosion Rate of Steel Reinforcement in Cement Mortar Caused by Penetrating Chloride and Sulfate from the Environment

    OpenAIRE

    Bikić, F.; Cacan, M.; Rizvanović, M.

    2013-01-01

    The influence of portland cement class on the corrosion rate of steel reinforcement in cement mortar caused by penetrating chloride or sulfate from the environment in already hardened cement mortar is investigated in this paper. Three classes of portland cement have been used for the tests, PC 35, PC 45 and PC 55. Cylindrical samples of cement mortar with steel reinfor- cement in the middle were treated 6 months at room temperature in the follow...

  3. Influence of growth conditions on adhesion of yeast Candida spp. and Pichia spp. to stainless steel surfaces.

    Science.gov (United States)

    Tomičić, Ružica; Raspor, Peter

    2017-08-01

    An understanding of adhesion behavior of Candida and Pichia yeast under different environmental conditions is key to the development of effective preventive measures against biofilm-associated infection. Hence in this study we investigated the impact of growth medium and temperature on Candida and Pichia adherence using stainless steel (AISI 304) discs with different degrees of surface roughness (Ra = 25.20-961.9 nm), material typical for the food processing industry as well as medical devices. The adhesion of the yeast strains to stainless steel surfaces grown in Malt Extract broth (MEB) or YPD broth at three temperatures (7 °C, 37 °C, 43 °C for Candida strains and 7 °C, 27 °C, 32 °C for Pichia strains) was assessed by crystal violet staining. The results showed that the nutrient content of medium significantly influenced the quantity of adhered cells by the tested yeasts. Adhesion of C. albicans and C. glabrata on stainless steel surfaces were significantly higher in MEB, whereas for C. parapsilosis and C. krusei it was YPD broth. In the case with P. pijperi and P. membranifaciens, YPD broth was more effective in promoting adhesion than MEB. On the other hand, our data indicated that temperature is a very important factor which considerably affects the adhesion of these yeast. There was also significant difference in cell adhesion on all types of stainless steel surfaces for all tested yeast. Copyright © 2017 Elsevier Ltd. All rights reserved.

  4. The influence of rapid solidification on the microstructure of the 17Cr–9Ni–3Mo precipitation hardened steel

    Energy Technology Data Exchange (ETDEWEB)

    Ziewiec, Aneta, E-mail: aziewiec@agh.edu.pl [AGH University of Science and Technology, Faculty of Metals Engineering and Industrial Computer Science, Al. A. Mickiewicza 30, 30-059 Kraków (Poland); Tasak, Edmund; Zielińska-Lipiec, Anna [AGH University of Science and Technology, Faculty of Metals Engineering and Industrial Computer Science, Al. A. Mickiewicza 30, 30-059 Kraków (Poland); Ziewiec, Krzysztof [Pedagogical University of Cracow, Institute of Technology, ul. Podchorążych 2, 30-084 Kraków (Poland); Kowalska, Joanna [AGH University of Science and Technology, Faculty of Metals Engineering and Industrial Computer Science, Al. A. Mickiewicza 30, 30-059 Kraków (Poland)

    2014-12-05

    Highlights: • Model of the microstructures formed at different cooling rates was proposed. • Effect of cooling rate on the massive formation of austenite was defined. • Influence of sub-zero treatment on the volume fraction of austenite was shown. - Abstract: The 17Cr–9Ni–3Mo precipitation hardened (PH) steel was processed after re-melting using different cooling rates including copper plate chilling and the melt-spinning. The effect of different cooling rates and the sub-zero treatment on the microstructure of the 17Cr–9Ni–3Mo steel was studied. The microstructure and the phase composition of the steel was investigated using light microscopy (LM), scanning electron microscopy (SEM) and energy dispersive spectrometry (EDS), transmission electron microscopy (TEM), the X-ray diffraction (XRD) and Mössbauer spectroscopy. The results show that the microstructure of 17Cr–9Ni–3Mo steel after rapid solidification consists of austenite and δ-ferrite. The quantity of austenite increases with the increase of cooling rate. Sub-zero treatment of the samples cooled at the rate of 4 × 10{sup 4} K/s and 2 × 10{sup 5} K/s reduces the quantity of austenite as a result of austenite → martensite transformation. For the samples cooled at the rate of 2 × 10{sup 6} K/s the quantity of austenite in the microstructure does not change when compared to the state before and after sub-zero treatment. The model for the formation of microstructures during rapid cooling was proposed.

  5. Influence of state of Nb on recrystallization temperature during annealing in cold-rolled low-carbon steels

    Energy Technology Data Exchange (ETDEWEB)

    Ogawa, Toshio, E-mail: ogawa.m8b.toshio@jp.nssmc.com [Nagoya Works, Nippon Steel and Sumitomo Metal Corporation, 5-3 Tokai-machi, Tokai-shi, Aichi 476-8686 (Japan); Sugiura, Natsuko [Steel Research Laboratories, Nippon Steel and Sumitomo Metal Corporation, 20-1 Shintomi, Futtsu, Chiba 293-8511 (Japan); Maruyama, Naoki; Yoshinaga, Naoki [Kimitsu R and D Laboratories, Nippon Steel and Sumitomo Metal Corporation, 1 Kimitsu, Kimitsu, Chiba 299-1141 (Japan)

    2013-03-01

    The influence of state of Nb on recrystallization temperature during annealing in cold-rolled low-carbon steels was investigated. Two kinds of specimens showing a remarkable difference in recrystallization temperature were prepared. Differences in the features of Nb-containing precipitates larger than 3 nm were rarely observed, whereas differences in precipitates smaller than 3 nm were confirmed by atom-probe field-ion microscopy in each hot-rolled sheet. The difference in the recrystallization temperatures of both specimens probably originates in the state of Nb at the atomic scale before annealing.

  6. Wide – ranging influence of mischmetal on properties of G17CrMo5-5 cast steel

    Directory of Open Access Journals (Sweden)

    J. Kasińska

    2015-01-01

    Full Text Available This paper presents influence of rare earth metals (REM on the mechanical properties, microstructure and morphology of non metallic inclusions as well as the cracking mechanism of G17CrMo5-5 high temperature cast steel. The research has been performed on successive industrial melts. It was found that non metallic inclusions the cracking mechanism of Charpy specimens and the impact strength were all changed. The following properties were tested: mechanical properties (Rm, Re, plastic properties (A, Z, impact strength (SCI and the KJC stress intensity factor.

  7. Influence of Rare Earth Metals on Microstructure and Inclusions Morphology G17CrMo5-5 Cast Steel

    Directory of Open Access Journals (Sweden)

    Kasińska J.

    2014-10-01

    Full Text Available This paper presents influence of rare earth metals (REM on the microstructure and morphology of non-metallic inclusions of G17CrMo5-5 cast carbon steel The research has been performed on successive industrial melts. Each time about 2000 kg of liquid metal was modified. The REM was in the form of mishmetal of the composition 49, 8% Ce, 21, 8% La, 17, 1% Nd, 5, 5% Pr and 5, 35% the rest of REM. Therareearth metals were put into the ladle during tapping of heat melt from the furnace.

  8. Influence of Plastic Deformation on Low Temperature Surface Hardening of Austenitic and Precipitation Hardening Stainless Steels by Gaseous Nitriding

    DEFF Research Database (Denmark)

    Bottoli, Federico; Winther, Grethe; Christiansen, Thomas Lundin

    2015-01-01

    This article addresses an investigation of the influence of plastic deformation on low temperature surface hardening by gaseous nitriding of three commercial austenitic stainless steels: AISI 304, EN 1.4369 and Sandvik Nanoflex® with various degrees of austenite stability. The materials were...... plastically deformed to different equivalent strains by uniaxial tension. Gaseous nitriding of the strained material was performed in ammonia gas at atmospheric pressure at 703 K (430 °C) and 693 K (420 °C) depending on the material. Microstructural characterization of the as-deformed states and the nitrided...

  9. The Influence of the Steel Stairs Under the Seismic Performance Analysis of Steel Frame Structure%地震作用下钢楼梯对钢框架结构抗震性能影响研究

    Institute of Scientific and Technical Information of China (English)

    高乐; 焦培培; 刘玲华

    2016-01-01

    随着钢结构在现代建筑的广泛应用,人们往往忽略了地震作用下钢结构楼梯在钢框架结构体系中的影响。为了探究钢楼梯对钢框架结构抗震性能的影响,本文利用大型有限元分析软件ETABS建立计算模型,选择主要的控制参数结构周期、位移角、底层剪力和楼梯受力作为研究对象。计算分析表明,钢结构楼梯对整体钢框架结构提供了一定的刚度,在地震作用下,应将钢楼梯的“释放效应”理念应用到未来钢结构抗震设计概念中,以此达到抗震性能设计要求。%As the steel structure is widely used in modern tall buildings, we are usually likely to neglect the influence of steel stairs on the aseismatic performance of steel structure. In or-der to detect the influence, this paper has set up a calculation model by ETABS, a mass finite element analysis software, and compared the force of stairs with some main control parameters such as structure period, displacement, angle and bottom shear. The results of analysis show that steel stairs have certain help to the stiffness of steel structure. Under the effect of earth-quakes, the resistance concept of steel stairs should be trans-formed into release effect concept which will be applied into the steel construction of future buildings to meet the need of aseis-matic performance.

  10. Influence of NaCl Deposition on Atmospheric Corrosion of A3 Steel

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Regularity of the initial atmospheric corrosion of A3 steel in the presence of NaCl was investigated. The results showed that NaCl can accelerate the corrosion of A3 steel. Dry mass gain of A3 steel in the presence of NaCl deposition increases with the exposure time, which can be correlated by using exponential decay function. The relationship between dry mass gain and amount of NaCl deposition at a certain exposure time follows a quadratic function. More amount of NaCl deposition will slow down the corrosion rate to some extent after exposure for a certain time. SEM/EDAX was used to characterize the corrosion surface and products. The surfaces of the NaCl treated A3 steel were obviously uneven, and some tiny crevices appear in the corrosion products that could help O2 transmit to the inner layer. The amount of oxygen in atomic percentage in the corrosion products increases with the amount of NaCl deposition.

  11. The influence of endodontic broken stainless steel instruments on the urinary levels of iron.

    Science.gov (United States)

    Saghiri, Mohammad Ali; Asatourian, Armen; Haraji, Afshin; Ramezani, Golam H; Garcia-Godoy, Franklin; Scarbecz, Mark; Sheibani, Nader

    2014-06-01

    Previous studies on the endodontic broken stainless steel instruments have mainly focused on retrieval of specimens. However, the systemic consequences of the retained separated instruments need an investigation. The current study aimed to evaluate the correlation between broken stainless steel instruments inside the root canal space and the urinary level of iron (Fe) in patients. Sixty near-aged and same-gender patients were selected. Thirty patients in the control group had no endodontic treatment in their history, while the other 30 patients in the endodontic group had broken stainless steel instrument. The urine samples were collected in iron-free containers. All specimens were refrigerated for 1 day and then subjected to Fe level measurement by electrothermal atomic absorption spectrometry. Data were analyzed by Kolmogorov-Smirnov and t tests at P  0.05). There was a positive correlation between age and Fe levels of endodontic and control groups. However, the joint effects of age and sex on Fe levels were different for the two groups. The presence of broken stainless steel instruments inside the root canal space did not elevate the level of Fe in the urine of patients. However, this value was positively correlated with the patient age.

  12. Influence of Ni-electrodeposited Pretreatment on Galvanized Coatings of Reactive Steels

    Institute of Scientific and Technical Information of China (English)

    CHE Chunshan; LU Jingtang; KONG Gang; XU Qiaoyu; SUI Runzhou

    2007-01-01

    Four types of steel sheets containing 0.04%, 0.09%, 0.14% and 0.36% Si, respectively, were electrodeposited with a nickel layer of 3 μm in thickness and then galvanized in molten Zn at 450℃ for various periods of time. The formation and growth of intermetallic compound layers on the surface of the samples were investigated by SEM and EDS. The experimental results show that the method of Ni-electrodeposited pretreatment can distinctively restrain the over-growth of the galvanized coatings of reactive steels and get eligible coatings with a proper thickness, bright appearance and strong adherence. EDS results indicate that a series of Ni-Zn intermetallic compounds γ',γ and δ2 are first formed on the surface of the samples. With a prolonged immersion time, the Г2-Fe-Zn-Ni and δ-Fe-Zn are formed accompanied by the gradual disappearance of γ',γ and δ2 layer. After a longer immersion time, the lumpy ζ- Fe-Zn occurs between δ and liquid Zn and the Г-Fe-Zn does between steel substrate and δ. Subsequently, ζ is in the form of a continuous and compact layer. The method of Ni-electrodeposited pretreatment changes the formation of Fe-Zn intermetallic compounds, which delay the growth of lumpy ζ and promote the growth of compact δ. Consequently, the abnormal growth of reactive steels is eliminated.

  13. The influence of tooth preparation and crown manipulation on the mechanical retention of stainless steel crowns.

    Science.gov (United States)

    Rector, J A; Mitchell, R J; Spedding, R H

    1985-01-01

    The belief that close adaptation of the metal margins to tooth surfaces in the undercut areas is the most important retentive feature, was borne out in this study. The type of preparation did not affect the retention of stainless steel crowns.

  14. Influence of Oxides on Microstructures and Mechanical Properties of High-Strength Steel Weld Joint

    Science.gov (United States)

    Cai, Yangchuan; Luo, Zhen; Huang, Zunyue; Zeng, Yida

    2016-11-01

    A comprehensive investigation was conducted into the effect of oxides on penetrations, microstructures and mechanical properties of BS700MC super steel weld bead. Boron oxide changed the penetration of weld bead by changing the Marangoni convection in the weld pool and contracting the welding arc. Chromium oxide only changed the Marangoni convection in the weld pool to increase the penetration of super steel. Thus, the super steel weld bead has higher penetration coated with flux boron oxide than that coated with chromium oxide. In other words, the activating flux TIG (A-TIG) welding with flux boron oxide has less welding heat input than the A-TIG welding with flux chromium oxide. As a result, on the one hand, there existed more fine and homogeneous acicular ferrites in the microstructure of welding heat-affected zone when the super steel was welded by A-TIG with flux boron oxide. Thus, the weld beads have higher value of low-temperature impact toughness. On the other hand, the softening degree of welding heat-affected zone, welded by A-TIG with flux boron oxide, will be decreased for the minimum value of welding heat input.

  15. Influence of Citric Acid on the Metal Release of Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Mazinanian, N.; Wallinder, I. Odnevall; Hedberg, Y. S. [KTH Royal Institute of Technology, School of Chemical Science and Engineering, Department of Chemistry, Division of Surface and Corrosion Science, Stockholm (Sweden)

    2015-08-15

    Knowledge of how metal releases from the stainless steels used in food processing applications and cooking utensils is essential within the framework of human health risk assessment. A new European standard test protocol for testing metal release in food contact materials made from metals and alloys has recently been published by the Council of Europe. The major difference from earlier test protocols is the use of citric acid as the worst-case food simulant. The objectives of this study were to assess the effect of citric acid at acidic, neutral, and alkaline solution pH on the extent of metal release for stainless steel grades AISI 304 and 316, commonly used as food contact materials. Both grades released lower amounts of metals than the specific release limits when they were tested according to test guidelines. The released amounts of metals were assessed by means of graphite furnace atomic absorption spectroscopy, and changes in the outermost surface composition were determined using X-ray photoelectron spectroscopy. The results demonstrate that both the pH and the complexation capacity of the solutions affected the extent of metal release from stainless steel and are discussed from a mechanistic perspective. The outermost surface oxide was significantly enriched in chromium upon exposure to citric acid, indicating rapid passivation by the acid. This study elucidates the effect of several possible mechanisms, including complex ion- and ligand-induced metal release, that govern the process of metal release from stainless steel under passive conditions in solutions that contain citric acid.

  16. Use of Homogeneously-Sized Carbon Steel Ball Bearings to Study Microbially-Influenced Corrosion in Oil Field Samples

    Directory of Open Access Journals (Sweden)

    Gerrit eVoordouw

    2016-03-01

    Full Text Available Microbially-influenced corrosion (MIC contributes to the general corrosion rate (CR, which is typically measured with carbon steel coupons. Here we explore the use of carbon steel ball bearings, referred to as beads (55.0 ± 0.3 mg; Ø = 0.238 cm, for determining CRs. CRs for samples from an oil field in Oceania incubated with beads were determined by the weight loss method, using acid treatment to remove corrosion products. The release of ferrous and ferric iron was also measured and CRs based on weight loss and iron determination were in good agreement. Average CRs were 0.022 mm/yr for 8 produced waters with high numbers (105/ml of acid-producing bacteria (APB, but no sulfate-reducing bacteria (SRB. Average CRs were 0.009 mm/yr for 5 central processing facility (CPF waters, which had no APB or SRB due to weekly biocide treatment and 0.036 mm/yr for 2 CPF tank bottom sludges, which had high numbers of APB (106/ml and SRB (108/ml. Hence, corrosion monitoring with carbon steel beads indicated that biocide treatment of CPF waters decreased the CR, except where biocide did not penetrate. The CR for incubations with 20 ml of a produced water decreased from 0.061 to 0.007 mm/yr when increasing the number of beads from 1 to 40. CRs determined with beads were higher than those with coupons, possibly also due to a higher weight of iron per unit volume used in incubations with coupons. Use of 1 ml syringe columns, containing carbon steel beads and injected with 10 ml/day of SRB-containing medium for 256 days gave a CR of 0.11 mm/yr under flow conditions. The standard deviation of the distribution of residual bead weights, a measure for the unevenness of the corrosion, increased with increasing CR. The most heavily corroded beads showed significant pitting. Hence the use of uniformly sized carbon steel beads offers new opportunities for screening and monitoring of corrosion including determination of the distribution of corrosion rates, which allows

  17. Normal Force Influence on 3D Texture Parameters Characterizing the Friction Couple Steel – PBT + 10 % PTFE

    Directory of Open Access Journals (Sweden)

    C. Georgescu

    2014-03-01

    Full Text Available This study presents the influence of the normal force on the surface quality of the friction couple steel – polybutylene terephthalate (PBT + 10 % polytetrafluoroethylene (PTFE. There were calculated the average values of the amplitude and functional parameters, as obtained from investigating square areas on the wear tracks, with the help of a proposed methodology, for initial and tested surfaces generated on the blocks and on counterpart ring made of rolling bearing steel, for the following test conditions: three normal forces (F = 1 N, F = 2.5 N and F =5 N, three sliding speeds (v = 0.25 m/s, v = 0.50 m/s and v = 0.75 m/s and a sliding distance of L = 7500 m. The conclusion of the research study was that the tested normal force range has an insignificant influence on the surface quality for the tested materials and parameters. This friction couple could be recommended for variable conditions (speed and load in dry regimes.

  18. Influence of Sulfate-Reducing Bacteria on the Corrosion Behavior of High Strength Steel EQ70 under Cathodic Polarization.

    Science.gov (United States)

    Guan, Fang; Zhai, Xiaofan; Duan, Jizhou; Zhang, Meixia; Hou, Baorong

    2016-01-01

    Certain species of sulfate-reducing bacteria (SRB) use cathodes as electron donors for metabolism, and this electron transfer process may influence the proper protection potential choice for structures. The interaction between SRB and polarized electrodes had been the focus of numerous investigations. In this paper, the impact of cathodic protection (CP) on Desulfovibrio caledoniens metabolic activity and its influence on highs trength steel EQ70 were studied by bacterial analyses and electrochemical measurements. The results showed that EQ70 under -0.85 VSCE CP had a higher corrosion rate than that without CP, while EQ70 with -1.05 VSCE had a lower corrosion rate. The enhanced SRB metabolic activity at -0.85 VSCE was most probably caused by the direct electron transfer from the electrode polarized at -0.85 VSCE. This direct electron transfer pathway was unavailable in -1.05 VSCE. In addition, the application of cathodic protection led to the transformation of sulfide rusts into carbonates rusts. These observations have been employed to provide updated recommendations for the optimum CP potential for steel structures in the presence of SRB.

  19. Influence of Sulfate-Reducing Bacteria on the Corrosion Behavior of High Strength Steel EQ70 under Cathodic Polarization

    Science.gov (United States)

    Guan, Fang; Zhai, Xiaofan; Duan, Jizhou; Zhang, Meixia; Hou, Baorong

    2016-01-01

    Certain species of sulfate-reducing bacteria (SRB) use cathodes as electron donors for metabolism, and this electron transfer process may influence the proper protection potential choice for structures. The interaction between SRB and polarized electrodes had been the focus of numerous investigations. In this paper, the impact of cathodic protection (CP) on Desulfovibrio caledoniens metabolic activity and its influence on highs trength steel EQ70 were studied by bacterial analyses and electrochemical measurements. The results showed that EQ70 under -0.85 VSCE CP had a higher corrosion rate than that without CP, while EQ70 with -1.05 VSCE had a lower corrosion rate. The enhanced SRB metabolic activity at -0.85 VSCE was most probably caused by the direct electron transfer from the electrode polarized at -0.85 VSCE. This direct electron transfer pathway was unavailable in -1.05 VSCE. In addition, the application of cathodic protection led to the transformation of sulfide rusts into carbonates rusts. These observations have been employed to provide updated recommendations for the optimum CP potential for steel structures in the presence of SRB. PMID:27603928

  20. Investigation of the Influence Factors on Distortion in Induction-Hardened Steel Shafts Manufactured from Cold-Drawn Rod

    Science.gov (United States)

    Dong, Juan; Epp, Jeremy; Rocha, Alexandre da Silva; Nunes, Rafael Menezes; Zoch, Hans Werner

    2016-02-01

    In this study, the distortion of steel shafts was investigated before and after induction hardening. Several essential influencing factors in the manufacturing process chain regarding cold drawing, cutting method, notches on the shafts, and induction hardening were analyzed by design of experiment (DoE). Further necessary examinations of microstructures, hardness profile, segregation of chemical composition, and residual stress state were conducted for understanding the distortion behavior. The results of the statistical analysis of the DoE showed that the drawing process is the most important factor influencing distortion. The surface hardening depth of induction hardening is the second main factor. The relationship between inhomogeneities in the work pieces and the distortion was finally discussed.

  1. A study of the influence of cutting parameters on micromilling of steel with cubic boron nitride (CBN) tools

    Science.gov (United States)

    Klocke, Fritz; Quito, Fernando; Arntz, Kristian; Souza, Alexandre

    2009-02-01

    It has been concluded in previous studies that Cubic Boron Nitride (CBN) tools have greater wear resistance and superior tool life than other tool materials used in conventional milling, due to chemically stability at high temperatures, high abrasive wear resistance and high degree of hardness; however no research has been conducted about its performance on micro milling. Burr formation has a direct negative effect on product quality and assembly automation in micro milling, therefore adoption of machining strategies and influencing factors were investigated intending to reduce burr formation. This paper also aims at analyzing the interference of cutting parameters on micro milling with CBN tools, such as the influence of cutting speed and feed per tooth on the surface quality and tool life. These outcomes enable us to know which parameters and strategies must be used to achieve better results when micro milling steel with CBN tools.

  2. Analysis of the influence of electrolyte on surface finish in electropolished stainless steel

    Science.gov (United States)

    Hernando, M.; Núñez, P. J.; García, E.; Trujillo, R.

    2012-04-01

    Electropolishing is a surface finishing process of metals and alloys that enhances brilliant surface finishes with low surface roughness values. The most widely used electrolytes for the electropolishing of stainless steel are varying concentrations of phosphoric and sulphuric acid, and occasionally additives such as chromic acid. The objective of this study was to assess the performance of three commonly used industrial electrolytes in terms of the surface finish of electropolished stainless steel AISI 316L. Each electrolyte had varying sulphuric-phosphoric acid combinations with or without chromic acid. The following electropolishing conditions were assessed: current density, bath temperature, electropolishing time, and initial surface texture. The results revealed that adding chromic acid to the electrolyte did not significantly enhance surface finish, and electropolishing ranges were quite similar for all three electrolytes.

  3. Influence of surface chemistry on the hygienic status of industrial stainless steel.

    Science.gov (United States)

    Boulange-Petermann, L; Jullien, C; Dubois, P E; Benezech, T; Faille, C

    2004-02-01

    Coupons of fourteen different stainless steels were investigated in terms of surface chemistry and ease of cleaning. Steel surfaces were exposed to Bacillus cereus spores in static saline solution for 2 h. Surfaces were rinsed and then covered with whole milk and allowed to dry. Surfaces were then cleaned in an experimental flow system that mimics an industrial application. After cleaning, remaining spores were released by sonication, spores cultured and colony forming units determined. Surfaces with higher levels of Fe in the outer surface of the passive film cleaned more easily. There was a relation between the polar component and ease of cleaning. The higher the polar component the more easily the surface cleaned. The cleaning mechanism involves dissolution of Fe enriched hydroxide films on the surface.

  4. Influence of Benzotriazole on Corrosion Inhibition of Mild Steel in Citric Acid Medium

    OpenAIRE

    P. Matheswaran; A. K. Ramasamy

    2010-01-01

    Benzotriazole an organic compounds has been studied as corrosion inhibition for mild steel in 1 N citric acid by weight loss method. The result showed that the corrosion inhibition efficiency of the compound was found to be varying with the temperature and acid concentration. Also it was found that the corrosion inhibition behaviour of benzotriazole is better when the concentration of inhibitor is increased. The kinetic treatment of the results shows first order kinetics.

  5. Influence of filler wire composition on weld microstructures of a 444 ferritic stainless steel grade

    OpenAIRE

    Villaret, Vincent; Deschaux-Beaume, Frédéric; Bordreuil, Cyril; Rouquette, Sébastien; Chovet, Corinne

    2013-01-01

    International audience; Seven compositions of metal cored filler wires for Gas Metal Arc Welding (GMAW), containing the same weight percent of chromium (Cr) and molybdenum (Mo) as 444 steel, but with different titanium (Ti) and niobium (Nb) contents were investigated. Experimental results pointed out that the filler wire Ti content required to be twice time more than the amount expected in the deposited metal. This was due to the low Ti transfer ratio during arc welding. Moreover, Ti increase...

  6. Influence of Brick Walls on the Temperature Distribution in Steel Columns in Fire

    Directory of Open Access Journals (Sweden)

    António J. P. Moura Correia

    2009-01-01

    Full Text Available This paper reports on a study of steel columns embedded in walls in fire. Several fire resistance tests were carried out at the Laboratory of Testing Materials and Structures of the University of Coimbra, in Portugal. The temperatures registered in several points of the experimental models are compared with those obtained in numerical simulations carried out with the SUPERTEMPCALC finite element program. 

  7. Influence of Formazan Derivatives on Corrosion Inhibition of Mild Steel in Hydrochloric Acid Medium

    OpenAIRE

    Venkatesan, P.; Anand, B.; P. Matheswaran

    2009-01-01

    Formazan of benzaldehyde (FB) and formazan of p-dimethyl amino benzaldehyde (FD) were synthesized. These compounds were studied as corrosion inhibitor for mild steel in 1.11 N hydrochloric acid by weight loss method. The result showed that the corrosion inhibition efficiency of these compounds was found to vary with the temperature and acid concentration. Also, it was found that the corrosion inhibition behaviour of FD is greater than that of FB. The kinetic treatment of the results gave firs...

  8. Influence of rare-earth modification on the properties of 18KhN2MFL steel for drill bit roller cutters

    Energy Technology Data Exchange (ETDEWEB)

    Evseev, P.P.; Zhirkin, Y.N.

    1986-03-01

    This paper examines the influence of rare-earth metals on the behavior of nonmetallic inclusions, the physical and mechanical properties, the critical transformation points, and the macrostructure of 18KhN2MFL cast steel used for the production of drill bit roller cutters with a diameter of 295 mm and more. The nonmetallic inclusion investigation results showed that for 18KhN2MFL steel deoxidized with aluminum, two types of inclusions are characteristic: sharp angled alumina inclusions and globular manganese sulfides with hardnesses of 2200 HV and 190 HV, respectively. The wear resistance tests showed that the rare-earth-metal-modified steel possesses higher abrasive wear resistance as compared with the unmodified; the relative wear resistance of such steel increases by 14-23%.

  9. Influence of Mo addition on the tempered properties of 13Cr martensitic stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Jung, Byong Ho; Ahn, Yong Sik [Pukyong National Univ., Busan (Korea, Republic of)

    1998-11-01

    In order to investigate the effect of Mo addition on the mechanical properties of 13Cr-0.2C martensitic stainless steel, tensile test and Charpy V-notch test were performed after tempering at the temperature range of 200{approx}700 .deg. C following austenitizing at 1100 .deg. C. The yield strength and hardness of the steel were increased with the increase of Mo content at all tempering conditions, because Mo causes retardation of precipitation and coarsening of carbides and solid solution strengthening of matrix. Except 500 .deg. C of tempering temperature, the Charpy impact energy was significantly increased with Mo content and showed the highest value at 1.5 wt% addition. The increase of impact energy of the steel containing Mo is thought to be caused by {delta}-ferrite formed in the tempered martensitic matrix. At 500 .deg. C tempering, Charpy impact energy was decreased drastically due to temper embrittlement and it was not possible to prevent it even though Mo was added up to 1.5 wt%.

  10. Influence of Co content on the biocompatibility and bio-corrosion of super ferritic stainless steels

    Science.gov (United States)

    Yoo, Y. R.; Jang, S. G.; Nam, H. S.; Shim, G. T.; Cho, H. H.; Kim, J. G.; Kim, Y. S.

    2008-12-01

    Bio-metals require high corrosion resistance, because their biocompatibility is closely related to this parameter. Bio-metals release metal ions into the human body, leading to deleterious effects. Allergies, dermatitis, and asthma are the predominant systemic effects resulting in the human body. In particular, Ni is one of the most common causes of allergic contact dermatitis. In the present work, we designed new ferritic stainless steels wherein Ni is replaced with Co under consideration of allergic respondes and microstructural stability. This work focuses on the effect of Co content on the biocompatibility and corrosion resistance of high PRE super ferritic stainless steels in bio-solution and acidic chloride solution. In the case of the acidic chloride solution, with increasing Co content in the ferritic stainless steels, passive current density increased and critical pitting temperature (CPT) decreased. Also, in the passive state, AC impedance and repassivation rate were reduced. These results are attributed to the thermodynamic stability of cobalt ions, as indicated in the EpH diagram for a Co-H2O system. However, in the case of bio-solutions, with increasing Co content of the alloys, the passive current density decreased. AC impedance and repassivation rate meanwhile increased in the passive state. This is due to the increased ratios of Cr2O3/Cr(OH)3 and [Metal Oxide]/Metal + Metal Oxide] of the passive film formed in bio-solution.

  11. Microstructure and creep properties of 9-12 % Cr-steels. The influence of Co

    Energy Technology Data Exchange (ETDEWEB)

    Kauffmann, F.; Zies, G.; Maile, K. [Stuttgart Univ. (Germany). MPA; Straub, S. [ALSTOM Power Systems, Mannheim (Germany); Mayer, K.H. [ALSTOM Power System, Nuernberg (Germany)

    2008-07-01

    The martensitic 9-12 wt. % Cr steels currently developed for the application in steam power plants are aimed for service temperatures above 600 C and steam pressures above 250 bar. The creep strength of these steels strongly depends on the microstructure and thereby on the chemical composition. In the present work, a combination of various microscopy techniques is used to study the microstructural changes of creep relevant features like subgrain-size, dislocation density, the chemical composition and crystallographic structure of the occurring precipitates as well as their density and size distribution in dependence of the addition of Co for several steels developed in the frame of the COST programs. These features are then correlated with the creep strength of the materials. The behavior of the alloy CB6 with a high Co content is compared to the low Co containing CB2 and the Co free B0 at 650 C. Similar comparisons are made for the alloy FN2, FN3 and FN 4 at 600 C. (orig.)

  12. The influence of Cr content on the mechanical properties of ODS ferritic steels

    Energy Technology Data Exchange (ETDEWEB)

    Li, Shaofu [School of Materials Science and Engineering, University of Science and Technology Beijing, No. 30 Xueyuan Road, Beijing (China); Korea Atomic Energy Research Institute, Daedeokdaero 989-111, Yuseong gu, Daejeon 305-353 (Korea, Republic of); Zhou, Zhangjian, E-mail: zhouzhj@mater.ustb.edu.cn [School of Materials Science and Engineering, University of Science and Technology Beijing, No. 30 Xueyuan Road, Beijing (China); Jang, Jinsung [Korea Atomic Energy Research Institute, Daedeokdaero 989-111, Yuseong gu, Daejeon 305-353 (Korea, Republic of); Wang, Man [School of Materials Science and Engineering, University of Science and Technology Beijing, No. 30 Xueyuan Road, Beijing (China); Korea Atomic Energy Research Institute, Daedeokdaero 989-111, Yuseong gu, Daejeon 305-353 (Korea, Republic of); Hu, Helong; Sun, Hongying; Zou, Lei; Zhang, Guangming; Zhang, Liwei [School of Materials Science and Engineering, University of Science and Technology Beijing, No. 30 Xueyuan Road, Beijing (China)

    2014-12-15

    The present investigation aimed at researching the mechanical properties of the oxide dispersion strengthened (ODS) ferritic steels with different Cr content, which were fabricated through a consolidation of mechanical alloyed (MA) powders of 0.35 wt.% nano Y{sub 2}O{sub 3} dispersed Fe–12.0Cr–0.5Ti–1.0W (alloy A), Fe–16.0Cr–0.5Ti–1.0W (alloy B), and Fe–18.0Cr–0.5Ti–1.0W (alloy C) alloys (all in wt.%) by hot isostatic pressing (HIP) with 100 MPa pressure at 1150 °C for 3 h. The mechanical properties, including the tensile strength, hardness, and impact fracture toughness were tested by universal testers, while Young’s modulus was determined by ultrasonic wave non-destructive tester. It was found that the relationship between Cr content and the strength of ODS ferritic steels was not a proportional relationship. However, too high a Cr content will cause the precipitation of Cr-enriched segregation phase, which is detrimental to the ductility of ODS ferritic steels.

  13. The influence of Si and P in steels on the galvanizing behavior; Zum Einfluss von Si und P auf das Verzinkungsverhalten von Baustaehlen

    Energy Technology Data Exchange (ETDEWEB)

    Katzung, W. [Inst. fuer Stahlbau, Leipzig (Germany); Rittig, R.

    1997-12-01

    The galvanizing behavior of 40 structural steels in current use was investigated in relation to the complex influence of the Si/P content under conditions that are usual in the hot dip galvanizing industry (440/450/460 C, 5/10/15 min immersion time). The effect of P on the increase of coating thickness on steels with 0.01 to 0.40% Si begins to be perceptible at > 0.020% P. The influence of P increases with decreasing Si content of the steels and decreasing temperature of the melt. In steels with {<=} 0.12% Si, an increased P content causes a shift of the thickness maxima in the temperature range from 440 to 450 C, such as is otherwise typical of steels of 0.12% to 0.28% Si with < 0.020% P. Zinc coatings on steels with the critical P/Si content (0 to 0.20% Si/> 0.020% P) as a rule are more unstable. With increased immersion time at the temperature stated above, floating away of the {zeta} phase into the zinc melt may occur. This could also be observed with Sandelin steels in the most critical Si range (0.07 to 0.10%) with < 0.020% P, with an immersion time of 15 min. It is possible to reduce the thickness of zinc coatings by adding small amounts of Al to the zinc melt (< 0.03%). This effect of Al at a concentration that is below what is required for the known inhibitory action by the formation of an thin Fe{sub 2}Al{sub 5}- or Al-containing {delta}{sub 1} film on the steel surface is attributed to the instability of the {zeta} phase, a proportion of which floats away into the zinc melt. (orig.)

  14. INFLUENCE OF SHOCK VOLTAGE FROM THE ELECTRIC DISCHARGE ON THE FATIGUE ENDURANCE OF CARBON STEEL IN WATER

    Directory of Open Access Journals (Sweden)

    I. O. Vakulenko

    2015-09-01

    Full Text Available Purpose. The research supposes the explanation of influence of stress impulses from an electrical discharge in water on the level of the limited endurance at a cyclic loading of the thermally work-hardened carbon steel. Methodology. Material for research was steel 45 (0,45 % carbon with сoncentration of chemical elements within the limits of steel composition. Specimens for tests are made as plates in 1 thick, width 15 and length 120-180 mm. The structural state of steel corresponded to quenching on a martensite from the normal temperatures of annealing and tempering at 300C, duration of 1 h. Microstructure was investigated with the use of electronic microscopy, the density of dislocations was estimated on the methods of X-ray analysis. Hardness was measured on the method of Rockwell (scale of «C». A cyclic loading was carried out in the conditions of symmetric bend on a tester «Saturn-10» at a temperature +20C. The treatment by shock voltage from the electrical discharge was carried out in water on setting of bath type «Iskra-23», used for cleaning of castings manufactures. Electric impulses were formed at 15-18 kV with energy of 10-12 kJ and amplitude of 1-2 GPа. Findings. As a result of processing pulses of a pressure wave of heat-strengthened steel 45 found the increase of endurance under the cyclic loading corresponds to an increased amount of accumulated dislocations on the fracture surface. The use of Coffin–Manson Equation allowed finding the decrease of deformation per cycle of loading as a result of arising stress from an electrical discharge in water. On the fracture surface (after pulse exposure was found the increased number of dislocations, located in different crystallographic systems, that is a testament to the rather complicated development of dislocation transformations in the structure of steel, which provide an increase of endurance at a fatigue. The increase of the limited endurance became as a result of impulsive

  15. Influence of original microstructure on the transformation behavior and mechanical properties of ultra-high-strength TRIP-aided steel

    Institute of Scientific and Technical Information of China (English)

    Hong-xiang Yin; Ai-min Zhao; Zheng-zhi Zhao; Xiao Li; Shuang-jiao Li; Han-jiang Hu; Wei-guang Xia

    2015-01-01

    The transformation behavior and tensile properties of an ultra-high-strength transformation-induced plasticity (TRIP) steel (0.2C–2.0Si–1.8Mn) were investigated by different heat treatments for automobile applications. The results show that F-TRIP steel, a tradi-tional TRIP steel containing as-cold-rolled ferrite and pearlite as the original microstructure, consists of equiaxed grains of intercritical ferrite surrounded by discrete particles of M/RA and B. In contrast, M-TRIP steel, a modified TRIP-aided steel with martensite as the original mi-crostructure, containing full martensite as the original microstructure is comprised of lath-shaped grains of ferrite separated by lath-shaped martensite/retained austenite and bainite. Most of the austenite in F-TRIP steel is granular, while the austenite in M-TRIP steel is lath-shaped. The volume fraction of the retained austenite as well as its carbon content is lower in F-TRIP steel than in M-TRIP steel, and austenite grains in M-TRIP steel are much finer than those in F-TRIP steel. Therefore, M-TRIP steel was concluded to have a higher austenite stability, re-sulting in a lower transformation rate and consequently contributing to a higher elongation compared to F-TRIP steel. Work hardening be-havior is also discussed for both types of steel.

  16. Influence of Shallow and Deep Cryogenic Treatment on Tribological Behavior of En 19 Steel%Influence of Shallow and Deep Cryogenic Treatment on Tribological Behavior of En 19 Steel

    Institute of Scientific and Technical Information of China (English)

    D Senthilkumar; I Rajendran

    2011-01-01

    The influence of cryogenic treatment on the wear resistance of En 19 steel was studied. Furthermore, a comparative analysis on the effect of Deep Cryogenic Treatment (DCT, 196℃× 24 h), Shallow Cryogenic Treatment (SCT -80℃ × 5 h) and Conventional Heat Treatment (CHT) was done through dry sliding wear testing. The microstructures of CHT, SCT and DCT samples were also examined through scanning electron microscopy. The results indicated that the wear resistance of shallow and deep cryogenically treated samples is higher when compared to that of conventionally treated samples. X-ray diffraction pattern revealed that the transformation of retained austenite into martensite is responsible for the wear resistance improvement.

  17. INFLUENCE OF HOT-REDUCTION PARAMETERS ON THE STEEL AUSTENITE STRUCTURE OF A RAILWAY WHEEL

    Directory of Open Access Journals (Sweden)

    Igor VAKULENKO

    2016-12-01

    Full Text Available The formation of grain structures with boundaries similar to substructures is one of the factors contributing to grain refinement in hot-reduction carbon steel. At the forming of a rim, the slight cooling-down (100-150°С of the surface volumes is sufficient to increase their strength characteristics. After that, an increase in the magnitude of the hot-hardening of metal in the central rim volumes will lead to the formation of a more uniform fine-grain austenite structure over the rim section.

  18. Influence of irradiation on the ductile fracture of a reactor pressure vessel steel

    Science.gov (United States)

    Haušild, Petr; Kytka, Miloš; Karlík, Miroslav; Pešek, Pavel

    2005-05-01

    The mechanical properties of 15Ch2MFA steel were characterised by tensile and instrumented Charpy tests. The fracture surfaces of Charpy specimens broken in the ductile-to-brittle transition temperature range contain a certain proportion of ductile fracture correlated to fracture energy. Measured ductile crack lengths show the same dependence on fracture deflection and/or fracture energy for irradiated and non-irradiated specimens. The decrease of upper shelf energy with increasing neutron fluence could be explained by an increasing amount of shear fracture.

  19. Influence of Formazan Derivatives on Corrosion Inhibition of Mild Steel in Hydrochloric Acid Medium

    Directory of Open Access Journals (Sweden)

    P. Venkatesan

    2009-01-01

    Full Text Available Formazan of benzaldehyde (FB and formazan of p-dimethyl amino benzaldehyde (FD were synthesized. These compounds were studied as corrosion inhibitor for mild steel in 1.11 N hydrochloric acid by weight loss method. The result showed that the corrosion inhibition efficiency of these compounds was found to vary with the temperature and acid concentration. Also, it was found that the corrosion inhibition behaviour of FD is greater than that of FB. The kinetic treatment of the results gave first order kinetics. The relative corrosion inhibition efficiency of these compounds has been explained on the basis of structure dependent - electron donor properties of the inhibitors.

  20. The influence of sodium hypochlorite biocide on the corrosion of carbon steel in reclaimed water used as circulating cooling water

    Energy Technology Data Exchange (ETDEWEB)

    Su, Weina; Tian, Yimei; Peng, Sen, E-mail: pengsen@tju.edu.cn

    2014-10-01

    Highlights: • The changes of polarisation curves and EIS over time were investigated. • Protective layers consist of microorganism metabolites and scale in the presence of microorganisms. • NaClO decreases the corrosion in circulating cooling water, whereas it promotes the corrosion in sterile water. • NaClO kills the microorganisms simultaneously along with the inhibition of corrosion and scaling in circulating cooling water. - Abstract: In this paper, we investigated the influence of sodium hypochlorite (NaClO) biocide on the corrosion of carbon steel in four different conditions during one dosing cycle. The results from the polarisation curve and electrochemical impedance spectroscopy (EIS) indicated that NaClO could affect the activity of microorganisms, leading to corrosion inhibition. The equivalent circuits had two time constants in the presence of biocide, which suggested that an oxide layer of NaClO was formed on the carbon steel surface. Environmental scanning electron microscopy (ESEM) and energy dispersive spectroscopy (EDS) were both employed to demonstrate that NaClO produced a good antibacterial activity, thereby indirectly retarding corrosion while simultaneously inhibiting scaling.

  1. The Influence of Temperature on the Frictional Behavior of Duplex-Coated Die Steel Rubbing Against Forging Brass

    Science.gov (United States)

    Ebrahimzadeh, I.; Ashrafizadeh, F.

    2015-01-01

    Improvement of die life under hot forging of brass alloys is considered vital from both economical and technical points of view. One of the best methods for improving die life is duplex coatings. In this research, the influence of temperature on the tribological behavior of duplex-coated die steel rubbing against forging brass was investigated. The wear tests were performed on a pin-on-disk machine from room temperature to 700 °C; the pins were made in H13 hot work tool steel treated by plasma nitriding and by PVD coatings of TiN-TiAlN-CrAlN. The disks were machined from a two-phase brass alloy too. The results revealed that the friction coefficient of this tribosystem went through a maximum at 550 °C and decreased largely at 700 °C. Furthermore, the formation of Cr2O3 caused the reduction of friction coefficient at 700 °C. PVD coatings proved their wear resistance up to 550 °C, well above the working temperature of the brass forging dies.

  2. Influence of high temperature pre-deformation on the dissolution rate of delta ferrites in martensitic heat-resistant steels

    Science.gov (United States)

    Li, Junru; Liu, Jianjun; Jiang, Bo; Zhang, Chaolei; Liu, Yazheng

    2017-03-01

    The dissolution process of delta ferrites and the influence of high temperature pre-deformation on the dissolution rate of delta ferrites in martensitic heat-resistant steel 10Cr12Ni3Mo2VN were studied by isothermal heating and thermal simulation experiments. The precipitation temperature of delta ferrites in experimental steel is about 1195 °C. M23C6-type carbides incline to precipitate and coarsen at the boundaries of delta ferrites below 930 °C, and can be rapidly dissolved by heating at 1180 °C. The percentage of delta ferrites gradually decreases with heating time. And a Kolmogorov-Johnson-Mehl-Avrami equation was established to describe the dissolution process of delta ferrites at 1180 °C. High temperature pre-deformation can markedly increase the dissolution rate of delta ferrites. Pre-deformation can largely increase the interface area between delta ferrite and matrix and thus increase the unit-time diffusing quantities of alloying elements between delta ferrites and matrix. In addition, high temperature pre-deformation leads to dynamic recrystallization and increases the number of internal grain boundaries in the delta ferrites. This can also greatly increase the diffusing rate of alloying elements. In these cases, the dissolution of delta ferrites can be promoted.

  3. Influence of C, N and Ti concentration on the intergranular corrosion resistance of AISI 316 Ti stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Pardo, A.; Merino, M.C.; Carboneras, M.; Coy, A.E.; Viejo, F.; Arrabal, R.; Munoz, J.A. [Departamento de Ciencia de Materiales, Facultad de Quimica, Universidad Complutense, 28040, Madrid (Spain)

    2004-07-01

    The influence of Ti, C, and N concentration on the intergranular corrosion resistance of AISI 316 Ti stainless steel has been studied. A kinetic study of the corrosion process has been carried out using gravimetric tests according to ASTM A-262 practices B and C (Streicher and Huey, respectively). The TTS diagrams were drawn as a function of alloying elements concentration (C, N and Ti). Materials characterization under several test conditions was carried out using Scanning Electron Microscopy (SEM) analysing microstructural characteristics and the attack microstructure. The chemical resistance of these steels to intergranular test was function of N, C and Ti concentration. High Ti and N concentration favoured the precipitation of TiN during the material manufacture process. N forms TiN very stable, causing the removal of Ti from the matrix and, indirectly, favouring the Cr{sub 23}C{sub 6} precipitation during the sensitization process and increasing the corrosion rate. In order to inhibit the intergranular corrosion in these materials the N and Ti concentrations must be optimised. (authors)

  4. Mutual Influence of Special Components in Baotou Steel Blast Furnace Slag on the Crystallization Behavior of Glass

    Directory of Open Access Journals (Sweden)

    Yici Wang

    2012-01-01

    Full Text Available In the process of glass-ceramics prepared with Baotou steel blast furnace slag, quartz sand, and other raw materials by melting method, the mutual influence of the special components such as CaF2, REXOY, TiO2, K2O, and Na2O in the blast furnace slag on the crystallization behavior of parent glass was investigated using differential thermal analysis (DTA and X-ray diffraction (XRD. The results show that the special components in slag can reduce the crystallization temperature and promote crystallization of glass phase, which belongs to surface crystallization of glass, and they cannot play the role of the nucleating agent; the major crystal phase composed of diopside, diopside containing aluminum and anorthite, is slightly different from the expected main crystal phase of diopside. Therefore, the nucleating agents of proper species and quantity must be added into the raw materials in order to obtain glass-ceramics. The results have important theoretical guidance meaning for realizing industrial production of Baotou steel blast furnace slag glass-ceramics preparation.

  5. Influence of alkali, silicate, and sulfate content of carbonated concrete pore solution on mild steel corrosion behavior

    Energy Technology Data Exchange (ETDEWEB)

    Huet, B. [Schlumberger Carbon Services, Schlumberger Riboud Product Center, Clamart (France); L' Hostis, V. [CEA, DEN, DPC, SCCME, Laboratoire d' Etude du Comportement des Betons et des Argiles, Gif-sur-Yvette, (France); Tricheux, L. [CEBTP-SOLEN, Elancourt, (France); Idrissi, H. [Laboratoire MATEIS UMR CNRS, Equipe RI2S, Department Science et Genie des Materiaux, Villeurbanne, (France)

    2010-02-15

    The increase in the rebar corrosion rate due to the concrete carbonation is the major cause of reinforced concrete degradation. The aim of this study was to investigate the corrosion behavior of mild steel rebars in simulated carbonated concrete solution. For this purpose, thermodynamic calculations, electrochemical techniques, gravimetric measurements, and surface analyses were used. Thermodynamic investigations of the nature of the interstitial solution provides an estimation of the influence of sulfate (SO{sub 4}{sup 2} {sup -}) and alkali (Na{sup +}, K{sup +}) content on carbonate alkalinity of the CO{sub 2}/H{sub 2}O open system (pCO{sub 2} = 0.3 mbar). In this system, calcium-silicate hydrates (C-S-H) remain thermodynamically unstable and amorphous silica controls silicate aqueous content at 100 ppm. Electrochemical results highlight a decrease in the corrosion rate with increasing carbonate alkalinity and the introduction of silicate. The introduction of sulfate at fixed carbonate alkalinity shows a dual effect: at high carbonate alkalinity, the corrosion rate is increased whereas at low carbonate alkalinity, corrosion rate is decreased. Those results are supported by surface analysis. Authors conclude that silicate and sulfate release from cement hydrates and fixation of alkali on carbonated hydrates are key parameters to estimate mild steel corrosion in carbonated concrete. (Abstract Copyright [2010], Wiley Periodicals, Inc.)

  6. Influence of cold deformation and annealing on hydrogen embrittlement of cold hardening bainitic steel for high strength bolts

    Energy Technology Data Exchange (ETDEWEB)

    Hui, Weijun, E-mail: wjhui@bjtu.edu.cn [School of Mechanical, Electronic and Control Engineering, Beijing Jiaotong University, Beijing 100044 (China); Zhang, Yongjian; Zhao, Xiaoli; Shao, Chengwei [School of Mechanical, Electronic and Control Engineering, Beijing Jiaotong University, Beijing 100044 (China); Wang, Kaizhong; Sun, Wei; Yu, Tongren [Technical Center, Maanshan Iron & Steel Co., Ltd., Maanshan 243002, Anhui (China)

    2016-04-26

    The influence of cold drawing and annealing on hydrogen embrittlement (HE) of newly developed cold hardening bainitic steel was investigated by using slow strain rate testing (SSRT) and thermal desorption spectrometry (TDS), for ensuring safety performance of 10.9 class high strength bolts made of this kind of steel against HE under service environments. Hydrogen was introduced into the specimen by electrochemical charging. TDS analysis shows that the hydrogen-charged cold drawn specimen exhibits an additional low-temperature hydrogen desorption peak besides the original high-temperature desorption peak of the as-rolled specimen, causing remarkable increase of absorbed hydrogen content. It is found that cold drawing significantly enhances the susceptibility to HE, which is mainly attributed to remarkable increase of diffusible hydrogen absorption, the occurrence of strain-induced martensite as well as the increase of strength level. Annealing after cold deformation is an effective way to improve HE resistance and this improvement strongly depends on annealing temperature, i.e. HE susceptibility decreases slightly with increasing annealing temperature up to 200 °C and then decreases significantly with further increasing annealing temperature. This phenomenon is explained by the release of hydrogen, the recovery of cold worked microstructure and the decrease of strength with increasing annealing temperature.

  7. Influence of alkali, silicate, and sulfate content of carbonated concrete pore solution on mild steel corrosion behavior

    Energy Technology Data Exchange (ETDEWEB)

    L' Hostis, V. [CEA Saclay, DEN, DPC, SCCME, Lab Etud Comportement Betons and Argiles, F-91191 Gif Sur Yvette (France); Huet, B. [Schlumberger Riboud Prod Ctr, Schlumberger Carbon Serv, F-92142 Clamart (France); Tricheux, L. [CEBTP SOLEN, F-78990 Elancourt (France); Idrissi, H. [CNRS, Lab MATEIS UMR 5510, Equipe RI2S, Dept Sci and Genie Mat, F-69621 Villeurbanne (France)

    2010-07-01

    The increase in the rebar corrosion rate due to the concrete carbonation is the major cause of reinforced concrete degradation. The aim of this study was to investigate the corrosion behavior of mild steel rebars in simulated carbonated concrete solution. For this purpose, thermodynamic calculations, electrochemical techniques, gravimetric measurements, and surface analyses were used. Thermodynamic investigations of the nature of the interstitial solution provides an estimation of the influence of sulfate (SO{sub 4}{sup 2-}) and alkali (Na{sup +}, K{sup +}) content on carbonate alkalinity of the CO{sub 2}/H{sub 2}O open system (pCO{sub 2}=0. 3 mbar). in this system, calcium-silicate hydrates (C-S-H) remain thermodynamically unstable and amorphous silica controls silicate aqueous content at 100 ppm. Electrochemical results highlight a decrease in the corrosion rate with increasing carbonate alkalinity and the introduction of silicate. The introduction of sulfate at fixed carbonate alkalinity shows a dual effect: at high carbonate alkalinity, the corrosion rate is increased whereas at low carbonate alkalinity, corrosion rate is decreased. Those results are supported by surface analysis. Authors conclude that silicate and sulfate release from cement hydrates and fixation of alkali on carbonated hydrates are key parameters to estimate mild steel corrosion in carbonated concrete. (authors)

  8. Research on the Influence of Size Effect for the mechanical Performance of GFRP tube concrete steel tube composite column under axial compression

    Science.gov (United States)

    Li, Wen; Wang, Tong; Na, Yu

    2017-08-01

    FRP tube-concrete-steel tube composite column (DSTC) was a new type of composite structures. The column consists of FRP outer tube and steel tube and concrete. Concrete was filled between FRP outer tube and steel tube. This column has the character of light and high strength and corrosion resistance. In this paper, properties of DSTC axial compression were studied in depth. The properties were studied by two groups DSTC short columns under axial compression performance experiment. The different size of DSTC short columns was importantly considered. According to results of the experiment, we can conclude that with the size of the column increases the ability of it to resist deformation drops. On the other hand, the size effect influences on properties of different concrete strength DSTC was different. The influence of size effect on high concrete strength was less than that of low concrete.

  9. Influence of Hold Time and Stress Ratio on Cyclic Creep Properties Under Controlled Tension Loading Cycles of Grade 91 Steel

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Woo Gon; Park, Jae Young; Jang, Jin Sung [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of); Ekaputra, I Made Wicaksana; Kim, Seon Jin [Pukyong National University, Busan (Korea, Republic of)

    2017-04-15

    Influences of hold time and stress ratio on cyclic creep properties of Grade 91 steel were systemically investigated using a wide range of cyclic creep tests, which were performed with hold times (HTs) of 1 minute, 3 minutes, 5 minutes, 10 minutes, 20 minutes, and 30 minutes and stress ratios (R) of 0.5, 0.8, 0.85, 0.90, and 0.95 under tension loading cycles at 600°C. Under the influence of HT, the rupture time increased to HT = 5 minutes at R = 0.90 and R = 0.95, but there was no influence at R = 0.50, 0.80, and 0.85. The creep rate was constant regardless of an increase in the HT, except for the case of HT = 5 minutes at R = 0.90 and R = 0.95. Under the influence of stress ratio, the rupture time increased with an increase in the stress ratio, but the creep rate decreased. The cyclic creep led to a reduction in the rupture time and an acceleration in the creep rate compared with the case of monotonic creep. Cyclic creep was found to depend dominantly on the stress ratio rather than on the HT. Fracture surfaces displayed transgranular fractures resulting from microvoid coalescence, and the amount of microvoids increased with an increase in the stress ratio. Enhanced coarsening of the precipitates in the cyclic creep test specimens was found under all conditions.

  10. Influence of heat treatment on microstructure and properties of GX12CrMoVNbN9-1 cast steel

    Directory of Open Access Journals (Sweden)

    G. Golański

    2010-07-01

    Full Text Available The paper presents results of research on the influence of multistage heat treatment on microstructure and properties of high-chromiummartensitic GX12CrMoVNbN9 – 1 (GP91 steel. The material under investigation were samples taken out from a test coupon. Heattreatment of GP91 cast steel was performed at the parameters of temperature and time typical of treatment for multi-ton steel casts. The research has proved that in the as-received condition (as-cast state GP91 cast steel was characterized by a coarse grain, martensitic microstructure which provided the required standard mechanical properties. The heat treatment of GP91 cast steel contributed to obtainment of a fine grain microstructure of high tempered martensite with numerous precipitations of carbides of diverse size. The GP91 cast steel structure received through heat treatment made it possible to obtain high plastic properties, particularly impact strength, maintaining strength properties on the level of the required minimum.

  11. Influence of explosive welding parameters on properties of bimetal Ti-carbon steel

    Directory of Open Access Journals (Sweden)

    Prazmowski Mariusz

    2017-01-01

    Full Text Available Explosion welding of metals is a process of great technological significance in terms of modern metal composites manufacturing possibilities Nevertheless, selecting welding parameters is not an easy task. This paper assesses the effect of various values of distance of sheets on the quality of the bond zone in titanium (Ti Gr.1 - carbon steel (P355GH structure. The research was carried out for initial state bonds i.e. immediately following explosion welding. The results of mechanical and structural investigations were presented. In order to determine changes in the value of strengthening, microhardness tests of both the weld and the joined plates were performed. Performed metallographic analysis shows that the standoff distance affects the quality of the bond zone boundary. Smaller distance promotes the formation of waves with lower parameters (of length and height, whereas greater distances allow forming the bond of a more pronounced, repetitive wavy character, however, increasing the quantity of the fusion zone at the same time. Also, the initial distance between the materials to be joined makes for the strengthening in the areas adjacent to bond boundary. The results received allowed to conclude that for the assumed parameters it is possible to obtain Ti -carbon steel bi-metal with properties meeting the standard’s requirements.

  12. Influence of femtosecond laser marking on the corrosion resistance of stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Valette, S. [Universite Jean Monnet, LTSI, 10 rue Barrouin, F42000 Saint Etienne (France)]. E-mail: stephane.valette@ec-lyon.fr; Steyer, P. [INSA de Lyon, LPCI, 20 Av. A. Einstein, F69621 Villeurbanne Cedex (France); Richard, L. [Ecole des Mines de St. Etienne, Centre CIS, 158 cours Fauriel, F42000 Saint Etienne (France); Forest, B. [Ecole des Mines de St. Etienne, Centre CIS, 158 cours Fauriel, F42000 Saint Etienne (France); Donnet, C. [Universite Jean Monnet, LTSI, 10 rue Barrouin, F42000 Saint Etienne (France); Audouard, E. [Universite Jean Monnet, LTSI, 10 rue Barrouin, F42000 Saint Etienne (France)

    2006-04-30

    Marking is of prime importance in the field of biomaterials to allow the identification of surgical tools as well as prostheses. Nowadays, marking is often achieved by means of laser beam, which may modify the characteristics of the treated surfaces. The use of laser devices delivering nanosecond pulses is known to induce dramatic corrosion degradations during sterilization or decontamination processes of the biomaterials. The aim of the present study is to investigate the ability of femtosecond (pulse duration in the 10{sup -15} s range) laser treatments to avoid preferential corrosion processes of the marked areas, in order to extend the durability and the reliability of biomaterials. Experiments have been performed on martensitic Z30C13 and austenitic 316L stainless steels. Electrochemical measurements (cyclic polarization curves) were carried out to determine the passive state of samples before and after engraving, their corrosion rate and their susceptibility to localized corrosion. Further protracted immersion tests were also carried out to evaluate the natural long-term degradation of engraved parts. The electrochemical behavior is then explained on the basis of surface characterizations. Femtosecond laser marking is shown to provide an electrochemical ennoblement. Moreover, the chemical composition is not affected so that the passive character of both stainless steels is maintained, even improved if we consider the susceptibility to localized corrosion.

  13. Influence of isothermal bainitic processing on the mechanical properties and microstructure characterization of TRIP steel

    Institute of Scientific and Technical Information of China (English)

    Haitao Jiang; Hubin Wu; Di Tang; Qiang Liu

    2008-01-01

    The mechanical properties of transformation induced plasticity (TRIP) steel are strongly affected by the conditions of iso-thermal bainitic processing. The multiphase microstructure of TRIP steel under different conditions of isothermal bainitic processing was investigated using OM, SEM, XRD and TEM. The volume fraction of retained anstenite and the carbon content in anstenite were determined quantitatively using X-ray diffraction patterns. The relationship between mechanical properties and isothermal bainitic processing parameters was investigated. The stability of retained anstenite was analyzed by the volume fraction of retained austenite and the carbon content in retained anstenite. The experimental results show that the multiphase microstructure consists of ferrite,bainite and metastable retained austenite. To obtain good mechanical properties, the optimal conditions of isothermal bainitic tem-perature and holding time are 410-430℃ and 180-240 s, respectively. After isothermal bainitic processing under the optimal condi-tions, the corresponding volume fraction of retained anstenite is 5vol%-15vol%, which can provide enough retained austenite and plastic stability for austenite with high carbon content.

  14. Influence of the Manufacturing Process on Defects in the Galvanized Coating of High Carbon Steel Wires

    Directory of Open Access Journals (Sweden)

    Marcello Gelfi

    2017-03-01

    Full Text Available This study is a detailed failure analysis of galvanized high carbon steel wires, which developed coating cracks during the torsion test performed as a quality control at the end of the manufacturing process. Careful visual inspections showed that the cracks are already present in the coating before the torsion test. In order to explain the origin of these cracks, systematic metallographic investigations were performed by means of optical and scanning electron microscope on both the wires and the rods that have been cold drawn to produce the wire. The chemical composition of the galvanized coatings was evaluated by means of energy dispersive spectroscopy. Micro bidimensional X-ray diffraction experiments were also performed to measure the residual stresses in the galvanized coating. The results showed that the failure is related to two main factors: the relatively high content of silicon in the steel and the unsuitable cooling rate of the rods at the exit from the galvanizing bath. The mechanism proposed to explain the origin of the defects was supported by Finite Elements Methods simulations and verified with in-plant tests. The proper countermeasures were then applied and the problem successfully solved.

  15. Influence of the Manufacturing Process on Defects in the Galvanized Coating of High Carbon Steel Wires.

    Science.gov (United States)

    Gelfi, Marcello; Solazzi, Luigi; Poli, Sandro

    2017-03-06

    This study is a detailed failure analysis of galvanized high carbon steel wires, which developed coating cracks during the torsion test performed as a quality control at the end of the manufacturing process. Careful visual inspections showed that the cracks are already present in the coating before the torsion test. In order to explain the origin of these cracks, systematic metallographic investigations were performed by means of optical and scanning electron microscope on both the wires and the rods that have been cold drawn to produce the wire. The chemical composition of the galvanized coatings was evaluated by means of energy dispersive spectroscopy. Micro bidimensional X-ray diffraction experiments were also performed to measure the residual stresses in the galvanized coating. The results showed that the failure is related to two main factors: the relatively high content of silicon in the steel and the unsuitable cooling rate of the rods at the exit from the galvanizing bath. The mechanism proposed to explain the origin of the defects was supported by Finite Elements Methods simulations and verified with in-plant tests. The proper countermeasures were then applied and the problem successfully solved.

  16. Influence of PWHT on Toughness of High Chromium and Nickel Containing Martensitic Stainless Steel Weld Metals

    Science.gov (United States)

    Divya, M.; Das, Chitta Ranjan; Mahadevan, S.; Albert, S. K.; Pandian, R.; Kar, Sujoy Kumar; Bhaduri, A. K.; Jayakumar, T.

    2015-06-01

    Commonly used 12.5Cr-5Ni consumable specified for welding of martensitic stainless steels is compared with newly designed 14.5Cr-5Ni consumable in terms of their suitability for repair welding of 410 and 414 stainless steels by gas tungsten arc welding process. Changes in microstructure and austenite evolution were investigated using optical, scanning electron microscopy, X-ray diffraction techniques and Thermo-Calc studies. Microstructure of as-welded 12.5Cr-5Ni weld metal revealed only lath martensite, whereas as-welded 14.5Cr-5Ni weld metal revealed delta-ferrite, retained austenite, and lath martensite. Toughness value of as-welded 12.5Cr-5Ni weld metal is found to be significantly higher (216 J) than that of the 14.5Cr-5Ni weld metal (15 J). The welds were subjected to different PWHTs: one at 923 K (650 °C) for 1, 2, 4 hours (single-stage PWHT) and another one at 923 K (650 °C)/4 h followed by 873 K (600 °C)/2 h or 873 K (600 °C)/4 h (two-stage heat treatment). Hardness and impact toughness of the weld metals were measured for these weld metals and correlated with the microstructure. The study demonstrates the importance of avoiding formation of delta-ferrite in the weld metal.

  17. Influence of the mechanical fatigue progress on the magnetic properties of electrical steel sheets

    Directory of Open Access Journals (Sweden)

    Karthaus Jan

    2017-06-01

    Full Text Available The purpose of this paper is to study the variation of the magnetic properties of non-oriented electrical steel sheets with the fatigue state during cyclic mechanical loading. The obtained results are central to the design of variable drives such as traction drives in electric vehicles in which varying mechanical loads, e.g. in the rotor core (centrifugal forces, alter the magnetic properties. Specimens of non-oriented electrical steel are subject to a cyclically varying mechanical tensile stress with different stress amplitudes and number of cycles. The specimens are characterised magnetically at different fatigue states for different magnetic flux densities and magnetising frequencies. The measurements show a variation in magnetic properties depending on the number of cycles and stress magnitude which can be explained by changes in the material structure due to a beginning mechanical fatigue process. The studied effect is critical for the estimation of the impact of mechanical material fatigue on the operational behaviour of electrical machines. Particularly in electrical machines with a higher speed where the rotor is stressed by high centrifugal forces, material fatigue occurs and can lead to deterioration of the rotor’s stack lamination.

  18. Influence of High Strength Steel Microstructure on Fatigue Crack Growth Rate

    Directory of Open Access Journals (Sweden)

    Enefola S. Ameh

    2016-07-01

    Full Text Available This study examines the effect of high strength steel microstructure morphology on fatigue crack growth rate (FCGR. To achieve this aim, three different heat treatment methods (normalizing, austempering quenching and tempering were considered and all the steel specimens were initially heated to 9500C austenization temperature for ninety minutes and then processed via the different heat treatment methods before viewing the resultant microstructures under light optical microscope (LOM. Fatigue crack growth rate tests were conducted on the resultant microstructures with compact tension specimens at room temperature as prescribed by American standard testing method E647. Results of FCGR tests showed normalized microstructure has the lowest FCGR (6.2698E-06, followed by quenched and tempered (7.9519E-06, asreceived (8.15E-06 and austempered (9.6667E-06 microstructure considering a low stress intensity factor range. The trend of results showed insignificant effect of microstructure over the Paris regime growth indicating fatigue crack growth rate is not a reliable parameter for correlating rate of crack propagation to microstructure

  19. Influence of carbon content on wear resistance and wear mechanism of Mn13Cr2 and Mn18Cr2 cast steels

    Directory of Open Access Journals (Sweden)

    Ding-shan Lu

    2015-01-01

    Full Text Available By means of impact abrasion tests, micro-hardness tests, and worn surface morphology observation via SEM, a comparison research based upon different impact abrasive wear conditions was conducted in this research to study the influence of different carbon contents (1.25wt.%, 1.35wt.%, and 1.45 wt.% on the wear resistance and wear mechanism of water-quenched Mn13Cr2 and Mn18Cr2 cast steels. The research results show that the wear resistance of the Mn18Cr2 cast steel is superior to that of the Mn13Cr2 cast steel under the condition of the same carbon content and different impact abrasive wear conditions because the Mn18Cr2 cast steel possesses higher worn work hardening capacity as well as a more desirable combination of high hardness and impact toughness than that of the Mn13Cr2 cast steel. When a 4.5 J impact abrasive load is applied, the wear mechanism of both steels is that plastic deformation fatigue spalling and micro-cutting coexist, and the former dominates. When the carbon content is increased, the worn work hardening effect becomes increasingly dramatic, while the wear resistance of both steels decreases, which implies that an increase in impact toughness is beneficial to improving the wear resistance under severe impact abrasive wear conditions. Under the condition of a 1.0 J impact abrasive load, the wear mechanism of both steels is that plastic deformation fatigue spalling and micro-cutting coexist, and the latter plays a leading role. The worn work hardening effect and wear resistance intensify when the carbon content is increased, which implies that a higher hardness can be conducive to better wear resistance under low impact abrasive condition.

  20. Influence of additives on electrodeposition of bright Zn–Ni alloy on mild steel from acid sulphate bath

    Indian Academy of Sciences (India)

    S Shivakumara; U Manohar; Y Arthoba Naik; T V Venkatesha

    2007-10-01

    The influence of a condensation product (CP) of veratraldehyde (VRTD) and -amino benzoic acid (PABA) on Zn–Ni alloy electrodeposited onto mild steel was studied in acidic sulphate solutions. Ethylenediaminetetraaceticacid (EDTA) and cetyltrimethylammoniumbromide (CTAB) were used as complexing and wetting agents, respectively. The effect of bath constituents, pH, current density and temperature on nature of deposit were studied through Hull cell experiments. The bath constituents and operating parameters were optimized. Deposit properties and corrosion resistance were discussed. Throwing power, current efficiency and polarization studies were carried out. SEM photomicrographs of the deposit obtained from optimum bath revealed fine-grained deposit of the alloy in the presence of condensation product and hence modified the morphology of zinc–nickel alloy deposit. IR spectrum of the scrapped deposit showed inclusion of addition agent.

  1. INFLUENCE OF CULTURAL ORIENTATION ON PERCEIVED ORGANIZATIONAL CREATIVITY CLIMATE: AN EXPLORATORY STUDY OF TWO STEEL PLANTS IN MALAYSIA

    Directory of Open Access Journals (Sweden)

    Hazman Shah Abdullah

    2006-01-01

    Full Text Available The study explores the relationship between cultural values and perceptions of the creativity climate. Asian culture is allegedly inimical to creativity and innovation in organizations. High power distance, high femininity, and greater orientation towards collectivity are discordant with the cultural underpinnings of the flatter, fluid, less formal, and networked organization. One hundred and seventy executives and nonexecutives of two steel mills were tested for the value orientation using an adaptation of Hofstede's measures for values and Ekvall's Creativity Climate Questionnaire forassessing the creativity climate of the organization. The executives' perceptions of the creativity climate in the organization were low and coincided only weakly with their value orientation. However, power distance and uncertainty avoidance stood out as the single most influential variable in creativity perceptions. Attention must be paid to the relationship and steps to ameliorate these influences by cultural profiling – a move thatidentify subcultures whose values may be more amenable to innovation and creativity than most.

  2. Influence of the finish rolling temperatures on the microstructure and texture evolution in the ferritic stainless steels

    Institute of Scientific and Technical Information of China (English)

    Fei GAO; Zhen yu LIU; Haitao LIU; Guodong WANG

    2011-01-01

    The influence of the finish rolling temperature on the microstructure and texture evolution of Nb and B micro-alloyed ultra purified Cr17 ferritic stainless steels was investigated.The hot rolled bands were produced by conventional rolling process and the finish rolling at relatively low temperatures or “warm rolling”.The microstructure was observed by optical microscopy,scanning electron microscopy and transmission electron microscopy,and X-ray diffraction was used to characterize the texture evolution processes.The results showed that as compared to conventional hot rolling process,the warm rolling has led to the refined and homogeneous microstruc ture and uniform recrystallization texture along γ-fiber in final sheets,indicating that the finish rolling at relatively low temperatures can be the effective way to improve significantly the formability of final sheets.

  3. The influence of the hardening coolant agent on the properties of hot rolled bars of the steel 42CrMo4

    OpenAIRE

    Stańczyk, M.; T. Figlus

    2014-01-01

    In the work the influence results of two different hardening coolant agents on the basic mechanical proprieties and microstructure of the round hot rolled bars were presented. The bars of 42CrMo4 steel were exposed to analysis, and for those bars in the hardening process, water and modern pro-ecological polymer cooling agents Aqua Quench MK were used.

  4. The influence of pluronic P123 micelles on corrosion behaviour of steel in cement extract and bulk matrix properties of cement paste

    NARCIS (Netherlands)

    Koleva, D.A.; Denkova, A. .G.; Hu, J.; van Breugel, K.

    2012-01-01

    The influence of Pluronic P123 (PEO20-PPO20-PEO70) micelles (of 10 nm size) on the corrosion behaviour of low carbon steel in cement extract (CE) was studied using electrochemical impedance spectroscopy (EIS) and potentio-dynamic polarisation (PDP). Additionally, mercury intrusion porosimetry (MIP)

  5. Influence of formwork surface on the orientation of steel fibres within self-compacting concrete and on the mechanical properties of cast structural elements

    DEFF Research Database (Denmark)

    Svec, Oldrich; Zirgulis, Giedrius; Bolander, John E.;

    2014-01-01

    The influences of formwork surface on the final orientation of steel fibres immersed in self-compacting concrete and on the resulting mechanical response of the cast structural elements are investigated. Experimental observations of fibre orientation within cast slabs, obtained via computed tomog...

  6. The quenching influence on defect structure and far acting stress fields of the 30CrNi3MoVA steel

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    @@ The determination of the quenching influence on defect structure and far acting stress fields of the cast constructional steel 30CrNi3MoVA (0.3%C, 1%Cr, 3%Ni, 1%Mo, 1%V) was the purpose of this work.

  7. The quenching influence on defect structure and far acting stress fields of the 30CrNi3MoVA steel

    Institute of Scientific and Technical Information of China (English)

    Kozlov; E.; V.; Popova; N.; A.; Klimashin; S.; I.; Tsellermaer; V.V.; Konovalov; S.; V.; Gromov; V.; E.

    2005-01-01

    The determination of the quenching influence on defect structure and far acting stress fields of the cast constructional steel 30CrNi3MoVA (0.3%C, 1%Cr, 3%Ni, 1%Mo, 1%V) was the purpose of this work.……

  8. Influence of surface roughness and melt superheat on HDA process to form a tritium permeation barrier on RAFM steel

    Energy Technology Data Exchange (ETDEWEB)

    Purushothaman, J. [B.S. Abdur Rahman University, Chennai 600048 (India); MTD, MMG, IGCAR, Kalpakkam 603102 (India); Ramaseshan, R., E-mail: seshan@igcar.gov.in [TFCS, SND, MSG, IGCAR, Kalpakkam 603102 (India); Albert, S.K. [MTD, MMG, IGCAR, Kalpakkam 603102 (India); Rajendran, R. [B.S. Abdur Rahman University, Chennai 600048 (India); Gowrishankar, N. [IP Rings Ltd., Maraimalainagar, Chennai 603209 (India); Ramasubbu, V. [MTD, MMG, IGCAR, Kalpakkam 603102 (India); Murugesan, S.; Dasgupta, Arup [PMG, MMG, IGCAR, Kalpakkam 603102 (India); Jayakumar, T. [MTD, MMG, IGCAR, Kalpakkam 603102 (India)

    2015-12-15

    Highlights: • Surface modified RAFMS samples were subjected to HDA and thermal oxidation. • Sample modified by SB process showed better coating and interface morphology. • Aluminized samples at 740 °C for 2 min showed Fe{sub 2}Al{sub 9}Si{sub 2} intermetallic phase. • Oxidized samples showed Fe{sub 2}Al{sub 8}Si, Fe{sub 2}Al{sub 3}Si{sub 3} and Fe{sub 3}Al{sub 2}Si{sub 3} intermetallic phases. • A uniform permeation barrier Al{sub 2}O{sub 3} was formed on the coating of oxidized HDA samples. - Abstract: The most optimal candidate material for fabrication of Test Blanket Module (TBM) in the installation of ITER and future fusion reactors is Reduced Activation Ferritic Martensitic (RAFM) steel, yet one of the major challenges that need to be addressed with RAFM is minimizing the loss of tritium in a reactor environment through the formation of tritium permeation barrier. One of the most promising methods for the tritium permeation barrier is through duplex coating with Al{sub 2}O{sub 3}/Fe–Al which is well known to reduce tritium permeation rate by several orders of magnitude. The present work aims to form an alumina layer on RAFM steel by a two-step method, which consists of (i) Hot Dip Aluminizing (HDA) and (ii) conversion of Al into alumina by a subsequent oxidation process. In addition, the influence of surface roughness of the substrate, superheat condition of the Al alloy melt and its composition on microstructural properties of coating before and after oxidation were investigated using OM, SEM–EDS, XRD, indentation micro hardness and scratch test. The experimental results confirmed the formation of alumina layer on RAFM steel after the HDA and oxidation process. Moreover, the surface roughness of the substrate, melt superheat of Al alloy and its composition are found to have a significant influence on the microstructure, thickness, micro-hardness, nature of intermetallic compounds formed and adhesion strength of the coating.

  9. Hydrogen diffusion and effect on degradation in welded microstructures of creep-resistant low-alloyed steels

    Energy Technology Data Exchange (ETDEWEB)

    Rhode, Michael

    2016-04-04

    with the permeation technique at room temperature and at elevated temperature ranges up to 400 C - It was investigated by interpreting the hydrogen effusion behavior with carrier gas hot extraction technique (CGHE). For realistic determination of the hydrogen diffusion coefficients, an improved method was developed encompassing accelerated specimen heating and hydrogen determination via mass spectrometer (MS). Simultaneously, the corresponding temperature dependent trapped and total hydrogen concentrations were determined. The determined experimental results showed increased susceptibility to the hydrogen affected degradation of the HAZ compared to the base material, which is independent of the investigated alloy composition. In particular, the martensitic coarse grain HAZ is the most susceptible microstructure to hydrogen-affected degradation. The results of the tensile tests allowed the definition of consistent microstructure specific failure criteria (envelope curves) versus quantified hydrogen concentrations for the reactor pressure vessel 16MND5 steel (20MnMoNi-5-5) and the creep-resistant T24 steel (7CrMoVTiB10-10). The procedure of quantifying hydrogen concentrations in HAZ microstructures is novel and supports a new method of analysis for hydrogen degradation effects. Further investigations with the T22 steel (10CrMo9-10), as compared to the creep-resistant T24 steel (7CrMoVTiB10-10), confirmed the beneficial effect of Vanadium as an alloying element to improve the resistance to degradation. In general, Mn-Mo-Ni base material grades show a higher resistance compared to Cr-Mo steels that do not include Vanadium alloying. The investigations showed the decreased diffusion coefficient of the HAZ microstructure compared to the base material microstructure. This is caused by the stronger trapping effects that are present which simultaneously increase the hydrogen solubility as well. In general, trapping effects above 100 C are negligible. It is noted that after

  10. Influence of Heat Treatment on Mercury Cavitation Resistance of Surface Hardened 316LN Stainless Steel

    Energy Technology Data Exchange (ETDEWEB)

    Pawel, Steven J [ORNL; Hsu, Julia [Massachusetts Institute of Technology (MIT)

    2010-11-01

    The cavitation-erosion resistance of carburized 316LN stainless steel was significantly degraded but not destroyed by heat treatment in the temperature range 500-800 C. The heat treatments caused rejection of some carbon from the carburized layer into an amorphous film that formed on each specimen surface. Further, the heat treatments encouraged carbide precipitation and reduced hardness within the carburized layer, but the overall change did not reduce surface hardness fully to the level of untreated material. Heat treatments as short as 10 min at 650 C substantially reduced cavitation-erosion resistance in mercury, while heat treatments at 500 and 800 C were found to be somewhat less detrimental. Overall, the results suggest that modest thermal excursions perhaps the result of a weld made at some distance to the carburized material or a brief stress relief treatment will not render the hardened layer completely ineffective but should be avoided to the greatest extent possible.

  11. Influence of localized plasticity on oxidation behaviour of austenitic stainless steels under primary water reactor

    Energy Technology Data Exchange (ETDEWEB)

    Cissé, Sarata [CEA Saclay, DEN/DANS/DMN/SEMI, 91191 Gif-sur-Yvette Cedex (France); Laffont, Lydia, E-mail: lydia.laffont@ensiacet.fr [Institut CARNOT, CIRIMAT-ENSIACET, 4 allée Emile Monso, 31030 Toulouse Cedex 4 (France); Lafont, Marie-Christine [Institut CARNOT, CIRIMAT-ENSIACET, 4 allée Emile Monso, 31030 Toulouse Cedex 4 (France); Tanguy, Benoit [CEA Saclay, DEN/DANS/DMN/SEMI, 91191 Gif-sur-Yvette Cedex (France); Andrieu, Eric [Institut CARNOT, CIRIMAT-ENSIACET, 4 allée Emile Monso, 31030 Toulouse Cedex 4 (France)

    2013-02-15

    The sensitivity of precipitation-strengthened A286 austenitic stainless steel to stress corrosion cracking was studied by means of slow-strain-rate tests. First, alloy cold working by low cycle fatigue (LCF) was investigated. Fatigue tests under plastic strain control were performed at different strain levels (Δε{sub p}/2 = 0.2%, 0.5%, 0.8% and 2%) to establish correlations between stress softening and the deformation microstructure resulting from the LCF tests. Deformed microstructures were identified through TEM investigations. The interaction between oxidation and localized deformation bands was also studied and it resulted that localized deformation bands are not preferential oxide growth channels. The pre-cycling of the alloy did not modify its oxidation behaviour. However, intergranular oxidation in the subsurface under the oxide layer formed after exposure to PWR primary water was shown.

  12. INFLUENCE OF COLD ROLLING TECHNOLOGY ON TEXTURE EVOLUTION OF IF STEEL

    Institute of Scientific and Technical Information of China (English)

    J.X. Li; X.H. Liu; G.D. Wang

    2002-01-01

    Two kinds of cold rolling experiments, single cold rolling and double cold rolling, werecarried out on one titanium stabilized interstitial free (IF) steel that has been warmrolled at ferrite temperature. The main aim was to investigate the evolution of rollingand annealing textures from the well known behavior observed under single cold rollingcondition to the less understood double cold rolling by using orientation distributionfunction (ODF). In the twice cold rolled samples, the annealing texture comprises onlyfirst round of rolling. Accordingly both the once cold rolled sample and the twice coldrolled sample with heavy reduction in the first round of rolling have much complextexture components. They are related to the formation of initial {111} subgrain andthe priority growth of stable {111} nucleus.

  13. Influence of Gas Flow Rate on the Deposition Rate on Stainless Steel 202 Substrates

    Directory of Open Access Journals (Sweden)

    M.A. Chowdhury

    2012-12-01

    Full Text Available Solid thin films have been deposited on stainless steel 202 (SS 202 substrates at different flow rates of natural gas using a hot filament thermal chemical vapor deposition (CVD reactor. In the experiments, the variations of thin film deposition rate with the variation of gas flow rate have been investigated. The effects of gap between activation heater and substrate on the deposition rate have also been observed. Results show that deposition rate on SS 202 increases with the increase in gas flow rate within the observed range. It is also found that deposition rate increases with the decrease in gap between activation heater and substrate. In addition, friction coefficient and wear rate of SS 202 sliding against SS 304 under different sliding velocities are also investigated before and after deposition. The experimental results reveal that improved friction coefficient and wear rate is obtained after deposition than that of before deposition.

  14. Influence of the austenitic stainless steel microstructure on the void swelling under ion irradiation

    Directory of Open Access Journals (Sweden)

    Rouxel Baptiste

    2016-01-01

    Full Text Available To understand the role of different metallurgical parameters on the void formation mechanisms, various austenitic stainless steels were elaborated and irradiated with heavy ions. Two alloys, in several metallurgical conditions (15Cr/15Ni–Ti and 15Cr/25Ni–Ti, were irradiated in the JANNUS-Saclay facility at 600 °C with 2 MeV Fe2+ ions up to 150 dpa. Resulting microstructures were observed by Transmission Electron Microscopy (TEM. Different effects on void swelling are highlighted. Only the pre-aged samples, which were consequently solute and especially titanium depleted, show cavities. The nickel-enriched matrix shows more voids with a smaller size. Finally, the presence of nano-precipitates combined with a dense dislocation network decreases strongly the number of cavities.

  15. Influence of Microstructure on Strength and Ductility in Fully Pearlitic Steels

    Directory of Open Access Journals (Sweden)

    Jesús Toribio

    2016-12-01

    Full Text Available This article deals with the relationship between the microstructure and both strength and ductility in eutectoid pearlitic steel. It is seen how standard mechanical properties and fracture micromechanisms are affected by heat treatment and the resulting microstructure in the material. The yield stress, the ultimate tensile strength and the ductility (measured by means of the reduction in area exhibit a rising trend with the increasing cooling rate (associated with smaller pearlite interlamellar spacing and a lower pearlitic colony size, while the strain for maximum load shows a decreasing tendency with the afore-said rising cooling rate. With regard to the fracture surface, its appearance becomes more brittle for lower cooling rates, so that the fracture process zone exhibits a larger area with observable pearlite lamellae and a lower percentage of microvoids.

  16. The influence of laser re-melting on microstructure and hardness of gas-nitrided steel

    Directory of Open Access Journals (Sweden)

    Panfil Dominika

    2016-12-01

    Full Text Available In this paper, modification of nitrided layer by laser re-melting was presented. The nitriding process has many advantageous properties. Controlled gas nitriding was carried out on 42CrMo4 steel. As a consequence of this process, ε+γ’ compound zone and diffusion zone were produced at the surface. Next, the nitrided layer was laser remelted using TRUMPF TLF 2600 Turbo CO2 laser. Laser tracks were arranged as single tracks with the use of various laser beam powers (P, ranging from 0.39 to 1.04 kW. The effects of laser beam power on the microstructure, dimensions of laser tracks and hardness profiles were analyzed. Laser treatment caused the decomposition of continuous compound zone at the surface and an increase in hardness of previously nitrided layer because of the appearance of martensite in re-melted and heat-affected zones

  17. The Influence of Method of Carburizing and Nitrocarburizing on the Microstructure and Properties of Tool Steels

    Institute of Scientific and Technical Information of China (English)

    Tomasz Babul; Natalia Kucharieva; Aleksander Nakonieczny; Jan Senatorski

    2004-01-01

    The paper presents the results of wear and metallography tests of tool steel grades: ASTM A681, Chl2M and Ch12FS per GOST, AMS 6437E i BS X46Cr13, all surface hardened by the Carbo process (carburizing) and by the NiCar process (nitrocarburizing). The thermo-chemical treatment was conducted in powder pack for a duration of 6 h (carburizing)and for 4 h in the case of nitrocarburizing. Factors investigated were: morphology, depth and microhardness of the cases obtained, their microstructure, as well as phase composition. Wear tests were conducted by the three cylinder-cone method.Wear velocity was 0.58 m/s, unit load was 50 MPa and 400Mpa, wear path was 3470 m. Oil SAE30 was applied at the rate of 30 drops per minute.

  18. INFLUENCE OF COOLING RATE ON THE OCORRENCE OF RETAINED AUSTENITE IN A STEEL FOR WELDING ELECTRODES

    Directory of Open Access Journals (Sweden)

    Helder Carvalho Ferreira

    2015-07-01

    Full Text Available The effect of cooling rate on the occurrence of retained austenite in a low carbon Si-Mn steel, used for welding electrodes, is measured here by combining the sectioning of Jominy test samples with the measurement of retained austenite by X-ray diffraction. It was observed that the amount of retained austenite increases from zero, as the cooling rate is less than 0.8°C/s, and the structure is mostly ferrite, to a maximum of 6%, where the quantity of bainite is also maximum. This information guides the post-rolling cooling cycle when welding grade is been rolled. The hard phases proportionality with the amount of retained austenite allows, then, the use of X-ray diffraction as an end of the line equipment for quality control, and also permits simplification of heat treatment before wire drawing.

  19. Influence of weld structure on cross-weld creep behavior in P23 steel

    Energy Technology Data Exchange (ETDEWEB)

    Allen, D.J.; Degnan, C.C. [E.ON Engineering (United Kingdom); Brett, S.J. [RWE npower (United Kingdom); Buchanan, L.W. [Doosan Babcock (United Kingdom)

    2010-07-01

    A thick section pipe weld in low alloy steel P23 has been characterised by cross-weld creep rupture testing at a range of stresses, together with all-weld-metal and parent material testing, under the auspices of the UK High Temperature Power Plant Forum. The results generally show that the weld metal can be weak when tested in the transverse (cross-weld) orientation, and can fail with limited overall ductility by cracking in the zone of refined weld metal beneath the fusion boundary of the superposed weld bead. However, one specimen showed a much superior performance, which could be understood in terms of its locally more creep resistant weld macrostructure. The implications for P23 performance and weld manufacture are discussed. (orig.)

  20. Influence of notch orientation and temperature on the impact behavior of a dual hardness steel composite

    Energy Technology Data Exchange (ETDEWEB)

    Weber, R.P. [Seção de Engenharia Mecânica e de Materiais/Instituto Militar de Engenharia/ Praça General Tibúrcio, 80, 22290-270 Rio de Janeiro, RJ (Brazil); Chawla, K.K. [Department of Materials Science and Engineering/The University of Alabama at Birmingham/Birmingham, AL 35294 (United States); Miguez Suarez, J.C., E-mail: jmiguez@ime.eb.br [Seção de Engenharia Mecânica e de Materiais/Instituto Militar de Engenharia/ Praça General Tibúrcio, 80, 22290-270 Rio de Janeiro, RJ (Brazil)

    2013-09-15

    The need for materials with good characteristics for critical applications, such as in defense and aerospace, has led to the development of new metallic materials. In the present work the impact fracture behavior of a dual hardness steel composite was studied in two geometries, “crack arrester” and “crack divider”. The composite was produced by forging and rolling followed by treatments of quenching and tempering and then annealing. The composite was characterized by optical microscopy as well as hardness, microhardness, tensile and impact tests. The failure mechanisms in impact at different temperatures were analyzed by scanning electron microscopy. The results showed that the mechanical behavior was significantly affected by the heat treating processes, with higher impact resistance associated with the crack arrester orientation. These results are analyzed in terms of the state of stress at the crack tip.

  1. Tensile Ductility of Nanostructured Bainitic Steels: Influence of Retained Austenite Stability

    Directory of Open Access Journals (Sweden)

    Thomas Sourmail

    2017-01-01

    Full Text Available High silicon (>1.5% steels with different compositions were isothermally transformed to bainite at 220 and 250 °C to produce what is often referred to as nanostructured bainite. Interrupted tensile tests were carried out and the retained austenite was measured as a function of strain. Results were correlated with tensile ductility. The role of retained austenite stability is remarkably underlined as strongly affecting the propensity to brittle failure, but also the tensile ductility. A simple quantitative relationship is proposed that clearly delimitates the different behaviours (brittle/ductile and correlates well with the measured ductility. Conclusions are proposed as to the role of retained austenite fraction and the existence of a threshold value associated with tensile rupture.

  2. The influence of drawing parameters on the properties high-manganese TWIP steel wires

    Directory of Open Access Journals (Sweden)

    Z. Muskalski

    2013-01-01

    Full Text Available The paper presents an experimental analysis of the effect of single draft magnitude in the multi-stage drawing process on the mechanical properties of the wire, and a theoretical process analysis aimed at identifying the causes of the variations in mechanical properties, made using Drawing 2D, a FEM-relying software program of high manganese TWIP steel rolling and stamping processes. It was found that wires drawn with small partial drafts (Gp%=11 % had a larger plasticity reserve, as defined by the R0.2/Rm ratio, as compared with wires drawn with large partial drafts (Gp = 26 %. A drop both in tensile strength Rm and in proof stress R0.2 was also found to occur after a total draft of Gc = 80 % had been exceeded, which was caused by the “strain softening” phenomenon.

  3. Influence of Prior Fatigue Damage on Tensile Properties of 316L(N) Stainless Steel and Modified 9Cr-1Mo Steel

    Science.gov (United States)

    Mariappan, K.; Shankar, Vani; Sandhya, R.; Mathew, M. D.; Bhaduri, A. K.

    2015-02-01

    In the current study, the effect of prior low-cycle fatigue (LCF) damage on the tensile properties of 316L(N) stainless steel (SS) and modified 9Cr-1Mo steel were systematically investigated. The LCF tests were interrupted at 5, 10, 30, and 50 pct of the total fatigue life followed by tensile tests on the same specimens at the same strain rate (3 × 10-3 s-1) and temperatures of 300 K, 823 K, and 873 K (27 °C, 550 °C, and 600 °C). Prior strain cycling at elevated temperatures had remarkable effect on the tensile properties of both cyclically hardening and cyclically softening materials. An exponential relationship between the yield stress and the amount of pre-strain cycles is obtained for both the materials. The initial drastic change in the yield strength values up to 10 pct of fatigue life may be due to the microstructural changes that lead to hardening or softening in 316L(N) SS and modified 9Cr-1Mo steel, respectively. Saturation in the yield strength values beyond 10 pct of fatigue life has practical importance for remnant fatigue life assessment. Evolution of fatigue damage in both the 316L(N) SS and modified 9Cr-1Mo steel was analyzed using the surface replica technique.

  4. Influence of Minor Alloying Elements on Selective Oxidation and Reactive Wetting of CMnSi TRIP Steel during Hot Dip Galvanizing

    Science.gov (United States)

    Cho, Lawrence; Kim, Myung Soo; Kim, Young Ha; De Cooman, Bruno C.

    2014-09-01

    The influence of the addition of minor alloying elements on the selective oxidation and the reactive wetting of CMnSi transformation-induced plasticity (TRIP) steels was studied by means of galvanizing simulator tests. Five TRIP steels containing small alloying additions of Cr, Ni, Ti, Cu, and Sn were investigated. After intercritical annealing (IA) at 1093 K (820 °C) in a N2 + 5 pct H2 gas atmosphere with a dew point of 213 K (-60 °C), two types of oxides were formed on the strip surface: Mn-rich xMnO·SiO2 ( x > 1.5) and Si-rich xMnO·SiO2 ( x formation of the inhibition layer during the hot dip galvanizing. The addition of a small amount of Sn is shown to significantly decrease the density of Zn-coating defects on CMnSi TRIP steels.

  5. Rare earth metals influence on mechanical properties and crack resistance of GP240GH and G17CrMo5-5 cast steels

    Directory of Open Access Journals (Sweden)

    M. Gajewski

    2009-10-01

    Full Text Available This paper presents results of research on modification influence of REM on mechanical properties and crack resistance of GP240GH cast carbon steel and G17CrMo5-5 high-temperature cast steel. The tests have been performed on successive industrial melts. The rare earth metals were put into the ladle during tapping of heat melt from the furnace. Each time ca 2000 kg of liquid metals were modified. Because of this the amount of sulphur in the cast steel was decreased and the non-metallic inclusion morphology was significantly changed. There were tested mechanical properties (Re,Rm, plastic properties (A5,Z and impact strength (KV, and on the basis of the three-point bend test the KJC stress intensity factor was evaluated. It was noticed that the REM modification brings essential increase of impact strength as well as fracture toughness determined by KJC factor.

  6. Influence of oversized elements (Hf, Zr, Ti and Nb) on the thermal stability of vacancies in type 316L stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Yabuuchi, A., E-mail: yabuuchi.atsushi@21c.osakafu-u.ac.jp [Advanced Science Research Center, Japan Atomic Energy Agency, 1233 Watanuki, Takasaki, Gunma 370-1292 (Japan); Maekawa, M.; Kawasuso, A. [Advanced Science Research Center, Japan Atomic Energy Agency, 1233 Watanuki, Takasaki, Gunma 370-1292 (Japan)

    2012-11-15

    To reveal the influence of oversized elements on the thermal stability of vacancies in type 316L stainless steels, vacancy recovery processes were investigated by means of positron annihilation spectroscopy. Although vacancies in additive-free 316L stainless steels were mobile at 300 Degree-Sign C, which is a typical nuclear reactor operating temperature, vacancies in oversized elements doped 316L were stable up to 300-350 Degree-Sign C. This result indicates that oversized elements stabilize vacancies in stainless steels. Stability of vacancies inhibits the radiation-induced grain boundary segregation and may also lead to suppression of high-temperature water stress corrosion cracking that is observed in nuclear materials.

  7. Influence of minimum quantity lubrication parameters on tool wear and surface roughness in milling of forged steel

    Science.gov (United States)

    Yan, Lutao; Yuan, Songmei; Liu, Qiang

    2012-05-01

    The minimum quantity of lubrication (MQL) technique is becoming increasingly more popular due to the safety of environment. Moreover, MQL technique not only leads to economical benefits by way of saving lubricant costs but also presents better machinability. However, the effect of MQL parameters on machining is still not clear, which needs to be overcome. In this paper, the effect of different modes of lubrication, i.e., conventional way using flushing, dry cutting and using the minimum quantity lubrication (MQL) technique on the machinability in end milling of a forged steel (50CrMnMo), is investigated. The influence of MQL parameters on tool wear and surface roughness is also discussed. MQL parameters include nozzle direction in relation to feed direction, nozzle elevation angle, distance from the nozzle tip to the cutting zone, lubricant flow rate and air pressure. The investigation results show that MQL technique lowers the tool wear and surface roughness values compared with that of conventional flood cutting fluid supply and dry cutting conditions. Based on the investigations of chip morphology and color, MQL technique reduces the cutting temperature to some extent. The relative nozzle-feed position at 120°, the angle elevation of 60° and distance from nozzle tip to cutting zone at 20 mm provide the prolonged tool life and reduced surface roughness values. This fact is due to the oil mists can penetrate in the inner zones of the tool edges in a very efficient way. Improvement in tool life and surface finish could be achieved utilizing higher oil flow rate and higher compressed air pressure. Moreover, oil flow rate increased from 43.8 mL/h to 58.4 mL/h leads to a small decrease of flank wear, but it is not very significant. The results obtained in this paper can be used to determine optimal conditions for milling of forged steel under MQL conditions.

  8. The influence of martensite shape, concentration, and phase transformation strain on the deformation behavior of stable dual-phase steels

    Science.gov (United States)

    Bhattacharyya, A.; Sakaki, T.; Weng, G. J.

    1993-02-01

    A continuum model is developed to examine the influence of martensite shape, volume fraction, phase transformation strain, and thermal mismatch on the initial plastic state of the ferrite matrix following phase transformation and on the subsequent stress-strain behavior of the dual-phase steels upon loading. The theory is developed based on a relaxed constraint in the ductile matrix and an energy criterion to define its effective stress. In addition, it also assumes the martensite islands to possess a spheroidal shape and to be randomly oriented and homogenously dispersed in the ferrite matrix. It is found that for a typical water-quenched process from an intercritical temperature of 760 °C, the critical martensite volume fraction needed to induce plastic deformation in the ferrite matrix is very low, typically below 1 pct, regardless of the martensite shape. Thus, when the two-phase system is subjected to an external load, plastic deformation commences immediately, resulting in the widely observed “continuous yielding” behavior in dual-phase steels. The subsequent deformation of the dual-phase system is shown to be rather sensitive to the martensite shape, with the disc-shaped morphology giving rise to a superior overall response (over the spherical type). The stress-strain relations are also dependent upon the magnitude of the prior phase transformation strain. The strength coefficient h and the work-hardening exponent n of the smooth, parabolic-type stress-strain curves of the dual-phase system also increase with increasing martensite content for each selected inclusion shape. Comparison with an exact solution and with one set of experimental data indicates that the theory is generally within a reasonable range of accuracy.

  9. Influence of cooling rate on the structure and mechanical properties of G17CrMoV5 – 10 cast steel

    Directory of Open Access Journals (Sweden)

    G. Golański

    2009-07-01

    Full Text Available The paper presents results of research on the influence of cooling rate on the structure and properties of G17CrMoV5 – 10 (L17HMF cast steel. The material for research was a section taken out from an outer cylinder of a steam turbine body after about 250 000 hours of operation at the temperature of 535°C and pressure 9 MPa. The investigated cast steel was subjected to heat treatment which consisted in cooling at the rates corresponding to the processes, such as: bainitic hardening, normalizing and full annealing. Tempering after the process of cooling from austenitizing temperature was carried out at the temperatures of: 700, 720 and 740°C. Performed research has proved that structures obtained after bainitic hardening and normalizing are characterized by a large strength margin which allows to apply high temperatures of tempering. It has been shown that the cast steel of bainitic structure, with similar mechanical properties as the cast steel of bainitic – ferritic structure, is characterized by almost twice as high impact energy. Full annealing and tempering of the examined cast steel ensures only the required impact strength, with mechanical properties comparable to those after service.

  10. Influence of surfactants on the corrosion inhibition behaviour of 2-aminophenyl-5-mercapto-1-oxa-3,4-diazole (AMOD) on mild steel

    Energy Technology Data Exchange (ETDEWEB)

    Rafiquee, M.Z.A. [Department of Applied Chemistry, Corrosion Research Laboratory, Faculty of Engineering and Technology, Aligarh Muslim University, Aligarh 202002 (India)], E-mail: drrafiquee@gmail.com; Saxena, Nidhi; Khan, Sadaf [Department of Applied Chemistry, Corrosion Research Laboratory, Faculty of Engineering and Technology, Aligarh Muslim University, Aligarh 202002 (India); Quraishi, M.A. [Department of Applied Chemistry, IT-BHU Banaras Hindu University (India)

    2008-02-15

    The corrosion inhibition characteristics of 2-aminophenyl-5-mercapto-1-oxa-3,4-diazole (AMOD) on mild steel in HCl solution have been studied by weight loss studies and potentiodynamic polarization. AMOD is a good corrosion inhibitor in HCl solution and its inhibition efficiency is increased markedly in presence of surfactants (SDS, CTAB, TX-100). TX-100 is found to be most effective among the tested surfactants. Weight loss measurements showed that the inhibition efficiency increased with the increasing surfactant concentration and attained a maximum value around 0.2 mol dm{sup -3}. In presence of surfactant, the adsorption of AMOD on the mild steel surface obeyed Langmuir's adsorption isotherm. The influence of inhibitor concentration, solution temperature, and acid concentration on the corrosion rate of mild steel has also been investigated. The deduced thermodynamic parameters for adsorption reveal a strong interaction between the inhibitor and mild steel surface. The negative values of G{sub ads} indicate the spontaneous adsorption of inhibitors on the mild steel surface. Potentiodynamic polarization studies show that these surfactants are mixed-type inhibitors.

  11. The influence of simultaneous impact of temperature and time on the properties and structure of X10CrWMoVNb9-2 steel

    Directory of Open Access Journals (Sweden)

    J. Dobrzański

    2009-05-01

    Full Text Available Purpose: of this paper is to present the changes of the mechanical properties and structure in material components of the power station boiler after long-lasting annealing made of X10CrWMoVNb9-2 steel.Design/methodology/approach: As a material for examination X10CrWMoVNb9-2 steel was use in the form of a pipe Ф 160 mm and wall thickness 40mm after normalization in 1050-1070°C/1h/air and tempering in 760-780°C/2h/air.Findings: Investigations of mechanical properties and the structure of the steel in initial state confirmed that it fulfills the requirements for that steel in initial state. Long annealing in the temperature close to the exploitation one and the examinations of the hardness and impact strength allow to determinate the influence of long temperature and time acting on the properties and structure of X10CrWMoVNb9-2 steel.Practical implications: The presented method can be used for evaluation and qualification of structural changes in power station boiler components operating in creep conditions.Originality/value: The presented results of changes in the mechanical properties, structure and in the precipitation processes are applied to evaluation the condition of the elements in further industrial service.

  12. Influence of Carbon Content and Rolling Temperature on Rolling Texture in 3 Pct Si Steel

    Science.gov (United States)

    Shingaki, Y.; Takashima, M.; Hayakawa, Y.

    2016-10-01

    Effects of carbon and rolling temperature up to 453 K (180 °C) on rolling texture of 3 pct Si steel at a reduction of 66 pct were investigated using a single crystal with an initial orientation of {110}. With residual-level carbon, uniform slip deformation was observed in the specimen cold rolled at room temperature and most of initial orientation {110} rotated to {111} during the rolling. With carbon addition, the formation of the deformation twins and the shear bands were promoted in the specimen cold rolled at room temperature. Regions with {110} were observed inside the shear bands. Warm-rolled specimen with residual-level carbon had microbands containing tiny {110} regions. Warm-rolled specimen with carbon addition had both the shear bands and the microbands but no deformation twin. Additionally, there were unique band structures with rotated crystal orientation around the rolling direction from initial orientation {110}. These experimental results suggest that the carbon addition inhibits dislocation migration by the increase of the critical resolved shear stress (CRSS) and that the high deformation temperature activates multiple slip systems by the reduction of CRSS and further that the carbon addition and high deformation temperature superimposed bring about the activation of symmetrical {110} slip systems additionally.

  13. Influence of Workpiece Material on Tool Wear Performance and Tribofilm Formation in Machining Hardened Steel

    Directory of Open Access Journals (Sweden)

    Junfeng Yuan

    2016-04-01

    Full Text Available In addition to the bulk properties of a workpiece material, characteristics of the tribofilms formed as a result of workpiece material mass transfer to the friction surface play a significant role in friction control. This is especially true in cutting of hardened materials, where it is very difficult to use liquid based lubricants. To better understand wear performance and the formation of beneficial tribofilms, this study presents an assessment of uncoated mixed alumina ceramic tools (Al2O3+TiC in the turning of two grades of steel, AISI T1 and AISI D2. Both workpiece materials were hardened to 59 HRC then machined under identical cutting conditions. Comprehensive characterization of the resulting wear patterns and the tribofilms formed at the tool/workpiece interface were made using X-ray Photoelectron Spectroscopy and Scanning Electron Microscopy. Metallographic studies on the workpiece material were performed before the machining process and the surface integrity of the machined part was investigated after machining. Tool life was 23% higher when turning D2 than T1. This improvement in cutting tool life and wear behaviour was attributed to a difference in: (1 tribofilm generation on the friction surface and (2 the amount and distribution of carbide phases in the workpiece materials. The results show that wear performance depends both on properties of the workpiece material and characteristics of the tribofilms formed on the friction surface.

  14. Influence of post irradiation annealing on the mechanical properties and defect structure of AISI 304 steel

    Energy Technology Data Exchange (ETDEWEB)

    Van Renterghem, W.; Van Dyck, S. [SCK-CEN, Mol (Belgium); Al Mazouzi, A. [EDF, Site les renardieres, Moret-sur-Loing (France)

    2011-07-01

    The effect of post irradiation annealing on the mechanical properties and the radiation induced defect structure was investigated on stainless steel, of type AISI 304, that was irradiated up to 24 dpa in the decommissioned Chooz A reactor. The material has been investigated both in the as-irradiated state as well as after post irradiation annealing. In the as-irradiated specimen the typical radiation induced defects were found as well as precipitates, most probably (Ni3Si), are present. Martensite phases with a bcc crystal structure were found near the grain boundaries. Annealing at 400 C had almost no effect on the radiation induced defects, but annealing at 500 C resulted in the immediate un-faulting of the Frank loops. As to the mechanical properties, annealing at 400 C did not strongly affect the yield strength and the ductility of the material, although the fraction of intergranular fracture during slow strain rate tensile tests (SSRT), under pressurised water reactor (PWR) condition, was significantly reduced. Annealing at 500 C did reduce the yield strength and restored substantially the ductility and the strain hardening capability of the material. The microstructure investigated by transmission electron microscopy correlates to the mechanical test results. It was found that the observed defect changes after post irradiation annealing provide a reasonable explanation for the observed changes of the mechanical properties obtained from SSRT under PWR chemical conditions. (authors)

  15. Influence of post irradiation annealing on the mechanical properties and defect structure of AISI 304 steel

    Energy Technology Data Exchange (ETDEWEB)

    Van Renterghem, W., E-mail: wvrenter@sckcen.be [SCK-CEN, Nuclear Materials Science, Boeretang 200, 2400 Mol (Belgium); Al Mazouzi, A.; Van Dyck, S. [SCK-CEN, Nuclear Materials Science, Boeretang 200, 2400 Mol (Belgium)

    2011-06-15

    The effect of post irradiation annealing on the mechanical properties and the radiation induced defect structure was investigated on stainless steel, of type AISI 304, that was irradiated up to 24 dpa in the decommissioned Chooz A reactor. The material was investigated both in the as-irradiated state as well as after post irradiation annealing. In the as-irradiated specimen the typical radiation induced defects were found as well as {gamma}'-precipitates (Ni{sub 3}Si). Annealing at 400 deg. C had almost no effect on the radiation induced defects, but annealing at 500 deg. C resulted in the immediate unfaulting of the Frank loops. As to the mechanical properties, annealing at 400 deg. C did not strongly affect the yield strength and the ductility of the material, although the fraction of intergranular fracture during slow strain rate tensile tests under pressurised water reactor conditions, was significantly reduced. Annealing at 500 deg. C did reduce the yield strength and restored substantially the ductility and the strain hardening capability of the material. The microstructure investigated by transmission electron microscopy correlates to the mechanical test results. It was found that the observed defect changes after post irradiation annealing provide a reasonable explanation for the observed changes of the mechanical properties.

  16. Cathodic protection of XL 52 steel under the influence of sulfate reducing bacteria

    Energy Technology Data Exchange (ETDEWEB)

    Esquivel, R. Garcia [Instituto Mexicano del Petroleo, Eje Central Lazaro Cardenas No. 152, Col. San Bartolo Atepehuacan, Mexico, D.F. 07730 (Mexico); Departamento de lngenieria Metalurgica, Facultad de Quimica, Universidad Nacional Autonoma de Mexico, Ciudad Universitaria, 04510 Mexico, D.F. (Mexico); Olivares, G. Zavala; Gayosso, M.J. Hernandez; Trejo, A. Gayosso [Instituto Mexicano del Petroleo, Eje Central Lazaro Cardenas No. 152, Col. San Bartolo Atepehuacan, Mexico, D.F. 07730 (Mexico)

    2011-01-15

    The effect of sulfate reducing bacteria (SRB) upon the cathodic protection of XL 52 steel was determined, in order to identify if the potential value of -0.950 V versus copper/copper sulfate electrode is good enough to protect the metal surface. During the experiments, different operational parameters were monitored: hydrogen sulfide production, iron concentration, electrolyte alkalinity, microorganisms' population, as well as the metal surface damage. At the same time, the corrosion rate was determined using two electrochemical techniques: polarization resistance (PR) and electrochemical impedance spectroscopy (EIS). According to the results, it was observed that the protection potential of -0.950 V versus copper/copper sulfate electrode is not enough to control the microbiologically induced corrosion. This situation is reinforced by the fact that significant iron concentration was found in the electrolyte. The microbiological activity is not affected by the protection potential. On the contrary, the population growth is slightly strengthened. The alkalinity generated by the applied potential did not stop the SRB growth. A type of localized corrosion was developed during the experiments with microorganisms, even when the protection potential was applied to the system. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  17. Influence of yttrium on laser surface alloying organization of 40Cr steel

    Institute of Scientific and Technical Information of China (English)

    WU Anqi; LIU Qibin; QIN Shuijie

    2011-01-01

    In order to improve the performance of the metal rollers,Mo+Y2O3 alloy powders were used to coat uniformly on the surface of 40Cr steel roller substrates for the laser surface alloying treatment by a CO2 laser,The results showed that many good consequences were obtained after adding the rare earth oxide Y2O3.The crystal grains of the alloy layer were significantly refine& The boundary of crystal grains was strengthened.The uniformity and density of the rnicrostructure were increased.The hardness and wearing resistance of the alloy layer were considerably improved.The valence electron structure analysis of the alloy layer was made by the empirical electron theory of solids and molecules (EET).The calculated results demonstrated that Y should be mixed in the first stage and Fe should be in the eighteenth hybrid bands.The analyzed outcomes illustrated that the electron theory of the solid solution shows the strengthening effect on the alloying layer,which has enhanced bond and confirmed the experimental results.

  18. Influence of reverted austenite on the texture and magnetic properties of 350 maraging steel

    Energy Technology Data Exchange (ETDEWEB)

    Abreu, Hamilton F.G., E-mail: hamilton@ufc.br [Universidade Federal do Ceará, Campus do Pici-Bloco 729, CEP 60440-554 Fortaleza, CE (Brazil); Silva, Jean J. [Universidade Federal do Ceará, Campus do Pici-Bloco 729, CEP 60440-554 Fortaleza, CE (Brazil); Silva, Manoel R. [Universidade Federal de Itajubá, Campus Sede Itajubá/IFQ- Instituto de Física e Química, Itajubá, MG (Brazil); Gomes da Silva, Marcelo J., E-mail: mgsilva@ufc.br [Universidade Federal do Ceará, Campus do Pici-Bloco 729, CEP 60440-554 Fortaleza, CE (Brazil)

    2015-11-01

    The aging temperature to improve magnetic properties in Maraging-350 steel (Mar-350) is limited by the onset of austenite reversion. The traditional process of cooling after aging is to remove the piece from the oven and then to air cool it. The purpose of this research was to characterize the reverted austenite and to investigate the effect of cooling below the martensite start temperature (M{sub s}) on the magnetic properties. The Mar350 samples aged at temperatures above 550 °C, and subsequently cooled in liquid nitrogen presented less austenite than samples cooled in air, resulting in higher magnetization saturation and a lower coercive force. A combination of optical microscopy (OM), X-ray diffraction (XRD) and electron backscatter diffraction (EBSD) techniques were used to characterize the presence of reverted austenite. The crystallographic texture of both martensite and reverted austenite were analyzed. The texture of the reverted austenite coincides with the texture of the parent austenite indicating that a phenomenon of texture memory is present. - Highlights: • Cooling maraging samples in liquid nitrogen reduces reverted austenite fraction. • Retained austenite increases coercive force and decreases saturation magnetization. • Reverted and parent austenites have the same crystallographic texture. • Memory effect found during reversion transformation.

  19. Electro-Chemical Behavior of Low Carbon Steel Under H2S Influence

    Science.gov (United States)

    Zaharia, M. G.; Stanciu, S.; Cimpoesu, R.; Nejneru, C.; Savin, C.; Manole, V.; Cimpoeșu, N.

    2017-06-01

    Abstract A commercial low carbon steel material (P265GH) with application at industrial scale for natural gas delivery and transportation systems was analyzed in H2S atmosphere. The article proposed a new experimental cell in order to establish the behavior of the material in sulfur contaminated environment. In most of the industrial processes for gas purification the corrosion rate is speed up by the presence of S (sulfur) especially as ions or species like H2S. The H2S (hydrogen sulfide) is, beside a very toxic compound, a very active element in the acceleration of metallic materials deterioration especially in complex solicitations like pressure and temperature in the same time. For experiments we used a three electrodes cell with Na2SO4 + Na2S solution at pH 3 at room temperature (∼ 25 °C) to realize EIS (electrochemical impedance spectroscopy) and potentio-dynamic polarization experiments. Scanning electron microscopy and X-ray dispersive energy spectroscopy were used to characterize the metallic material surface exposed to experimental environment.

  20. Influence of Carbon Content and Rolling Temperature on Rolling Texture in 3 Pct Si Steel

    Science.gov (United States)

    Shingaki, Y.; Takashima, M.; Hayakawa, Y.

    2017-01-01

    Effects of carbon and rolling temperature up to 453 K (180 °C) on rolling texture of 3 pct Si steel at a reduction of 66 pct were investigated using a single crystal with an initial orientation of {110}. With residual-level carbon, uniform slip deformation was observed in the specimen cold rolled at room temperature and most of initial orientation {110} rotated to {111} during the rolling. With carbon addition, the formation of the deformation twins and the shear bands were promoted in the specimen cold rolled at room temperature. Regions with {110} were observed inside the shear bands. Warm-rolled specimen with residual-level carbon had microbands containing tiny {110} regions. Warm-rolled specimen with carbon addition had both the shear bands and the microbands but no deformation twin. Additionally, there were unique band structures with rotated crystal orientation around the rolling direction from initial orientation {110}. These experimental results suggest that the carbon addition inhibits dislocation migration by the increase of the critical resolved shear stress (CRSS) and that the high deformation temperature activates multiple slip systems by the reduction of CRSS and further that the carbon addition and high deformation temperature superimposed bring about the activation of symmetrical {110} slip systems additionally.

  1. The influence of loading on the corrosion of steel in cracked ordinary Portland cement and high performance concretes

    Science.gov (United States)

    Jaffer, Shahzma Jafferali

    Most studies that have examined chloride-induced corrosion of steel in concrete have focused on sound concrete. However, reinforced concrete is seldom uncracked and very few studies have investigated the influence of cracked concrete on rebar corrosion. Furthermore, the studies that have examined the relationship between cracks and corrosion have focused on unloaded or statically loaded cracks. However, in practice, reinforced concrete structures (e.g. bridges) are often dynamically loaded. Hence, the cracks in such structures open and close which could influence the corrosion of the reinforcing steel. Consequently, the objectives of this project were (i) to examine the effect of different types of loading on the corrosion of reinforcing steel, (ii) the influence of concrete mixture design on the corrosion behaviour and (iii) to provide data that can be used in service-life modelling of cracked reinforced concretes. In this project, cracked reinforced concrete beams made with ordinary Portland cement concrete (OPCC) and high performance concrete (HPC) were subjected to no load, static loading and dynamic loading. They were immersed in salt solution to just above the crack level at their mid-point for two weeks out of every four (wet cycle) and, for the remaining two weeks, were left in ambient laboratory conditions to dry (dry cycle). The wet cycle led to three conditions of exposure for each beam: (i) the non-submerged region, (ii) the sound, submerged region and (iii) the cracked mid-section, which was also immersed in the solution. Linear polarization resistance and galvanostatic pulse techniques were used to monitor the corrosion in the three regions. Potentiodynamic polarization, electrochemical current noise and concrete electrical resistance measurements were also performed. These measurements illustrated that (i) rebar corroded faster at cracks than in sound concrete, (ii) HPC was more protective towards the rebar than OPCC even at cracks and (iii) there

  2. Influences of Thermal Martensites and Grain Orientations on Strain-induced Martensites in High Manganese TRIP/TWIP Steels

    Institute of Scientific and Technical Information of China (English)

    Fayun Lu; Ping Yang; Li Meng; Fenge Cui; Hua Ding

    2011-01-01

    Strain-induced martensites in high manganese TRIP/TWIP steels were investigated in the presence of thermal martensites and under the influence of austenitic grain orientation by X-ray diffraction (XRD), scanning electron microscopy (SEM) and electron backscattered diffraction (EBSD). Before deformation, the morphology of α′-M depended mainly on the number of variants and growing period. Regardless of martensite morphologies and deformation, the Kurdjumov-Sachs (K-S) orientation relationships always maintained. The 6 α′-M variants formed from a plate of ε-M were of 3 pairs of twins with a common axis <110>α′ parallel to the normal of {111}γ habit plane to minimize transformation strain. When α′-M could be formed only by deformation, it nucleated at the intersection of ε-M variants and grew mainly in thick ε-M plates. Thick ε plates promoted significantly the α′-M and weakened the influence of grain orientations. During tension, the transformation in <100>-oriented grains was observed to be slower than that in <111>-oriented grains. Deformation twins promoted ε-M formation slightly and had no apparent effect on α′-M. Deformation increased the number of ε-M variants, but reduced that of α′-M variants.

  3. Influence of Cu alloying on hot ductility of C-Mn-Al and Ti-Nb microalloyed steels

    Directory of Open Access Journals (Sweden)

    Comineli, O.

    2005-12-01

    Full Text Available A beneficial effect of the copper on the hot ductility was observed in Ti-Nb microalloyed steels over the temperature range 800-1,000 °C at the cooling rate of 0.4 °C/s, but no influence at the cooling rate of 4 °C/s. Precipitates containing Nb and Ti were present whose size was coarser in the Cu-bearing grade as cooled at 0.4 °C/s. Cu-bearing precipitates were not found. In the C-Mn-Al steel, no influence of the copper on the hot ductility was recorded, but CuS particles were detected. Two mechanisms are proposed to explain the positive influence of the copper in the microalloyed steel. The first is that the copper atoms in the solid solution affect the activity of the carbon and the nitrogen analogically to the previously observed effect of the silicon, enhancing the precipitation at high temperatures, and another mechanism that the copper atoms can prolong the lifetime of vacancies generated by straining assisting the formation of TiNb-vacancy complexes and thereby coarsening the precipitates.

    Se ha observado un efecto beneficioso del cobre sobre la ductilidad en caliente del acero microaleado al Ti-Nb, en el rango de temperaturas 800-1.000 °C. La influencia fue observada a velocidades de enfriamiento bajas, 0,4 °C/s, mientras que a 4 °C/s no se aprecia. En el acero C-Mn-Al, la influencia de cobre no fue detectada. En el acero microaleado se detectó la presencia de precipidados que contienen niobio y titanio, la dimensión de los cuales es mayor cuando se enfría a 0,4 °C/s. En este acero no se detectó la presencia de precipitados con contenidos de cobre, en contraste con el acero C-Mn-Al, donde sí se observaron partículas de CuS. Se proponen dos mecanismos para explicar la influencia positiva del cobre en aceros microaleados. El primero es el aumento de la actividad de carbono y nitrógeno en austenita debido a presencia de átomos de cobre en solución sólida, con el mismo efecto que el silicio, el cual aumenta la

  4. Influence of sand to coarse aggregate ratio on the interfacial bond strength of steel fibers in concrete for nuclear power plant

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jung Jin, E-mail: jjinslow@nate.com [Department of Civil and Environmental Engineering, SeJong University, 98 Gunja-Dong, Gwangjin-Gu, Seoul 143-747 (Korea, Republic of); Kim, Dong Joo, E-mail: djkim75@sejong.ac.kr [Department of Civil and Environmental Engineering, SeJong University, 98 Gunja-Dong, Gwangjin-Gu, Seoul 143-747 (Korea, Republic of); Kang, Su Tae, E-mail: stkang@daegu.ac.kr [Department of Civil Engineering, Daegu University, 201 Daegudae-ro, Jillyang, Gyeongsan, Gyeongbuk 712-714 (Korea, Republic of); Lee, Jang Hwa, E-mail: jhlee@kict.re.kr [Korea Institute of Construction Technology, 2311 Daewha-Dong, Ilsan-Gu, Goyang-Si, Gyeonggi-Do 411-712 (Korea, Republic of)

    2012-11-15

    Highlights: Black-Right-Pointing-Pointer The final goal is to develop a fiber reinforced concrete for containment buildings. Black-Right-Pointing-Pointer We investigated the effect of S/a on the bond strength of steel fibers. Black-Right-Pointing-Pointer Deformed steel fibers produced much higher interfacial bond strength. Black-Right-Pointing-Pointer As S/a increased, twisted fiber showed a significant enhancement in bond strength. Black-Right-Pointing-Pointer Smooth and hooked fiber showed no clear difference as S/a increased. - Abstract: The interfacial bond strength of three high strength steel fibers (smooth, hooked, and twisted fiber) in concrete of nuclear power plants was investigated to develop fiber reinforced concrete for containment building. Sand to aggregate ratio (S/a) was adjusted to compensate reduction in the workability due to adding fibers; the influence of S/a ratio on the interfacial bond strength was investigated. As the S/a ratio increased from 0.444 to 0.615, the bond strength of twisted steel fiber was significantly improved while smooth and hooked steel fiber showed no clear difference. The different sensitivity according to the S/a ratio results from the different pullout mechanism: twisted steel fiber generates more mechanical interaction during fiber pullout at the interface between fiber and matrix than smooth and hooked fibers. The microscopic observation by scanning electron microscope back-scattered electrons images discovered lower porosity at the interfacial transition zone between fiber and concrete with higher S/a ratio.

  5. Influence of silver additions to type 316 stainless steels on bacterial inhibition, mechanical properties, and corrosion resistance

    DEFF Research Database (Denmark)

    Chiang, Wen-Chi; Tseng, I-Sheng; Møller, Per;

    2010-01-01

    Bacterial contamination is a major concern in many areas. In this study, silver was added to type 316 stainless steels in order to obtain an expected bacteria inhibiting property to reduce the occurrence of bacterial contamination. Silver-bearing 316 stainless steels were prepared by vacuum melti...

  6. Influence of Water Pollution on MIC of Stainless Steel 304L

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The influence of water pollution and welding defects on MIC (microbiologically influenced corrosion) was studied. The open circuit potential (OCP) was measured during MIC test. It was found that OCP shifted to a higher level when the system was inoculated with bacteria while the OCP of those samples in water without bacteria was kept at a low level. The OCP decreased dramatically when MIC started in polluted water. Combination of weld defect-heat tint, polluted water and adding bacteria causes MIC happen at high rate. Some elements inside the tubercle were analyzed with EDXA. The pits and biofilm were observed with SEM. Microbiological analysis revealed the difference of bacteria between corroded and uncorroded samples.

  7. The influence of the heat treatment on delta ferrite transformation in austenitic stainless steel welds

    Directory of Open Access Journals (Sweden)

    B. Mateša

    2012-04-01

    Full Text Available Shielded metal arc (SMAW welded specimens using austenitic consumable materials with different amount of delta-ferrite are annealed in range 650-750 °C through 2-10 hours. Factorial plan 33 with influenced factors regression analyze of measured delta-ferrite values is used. The transformation i.e. decomposition of delta ferrite during annealing was analyzed regarding on weld cracking resistance using metallographic examination and WRC-1992 diagram.

  8. The influence of organic structure and rare earth metal cation on the corrosion efficiency observed on AS1020 steel compared with La(4OHCin3

    Directory of Open Access Journals (Sweden)

    Marianne Seter

    2015-01-01

    Full Text Available Whilst the corrosion protection of steel in aqueous chloride environments by the rare earth inhibitor lanthanum 4-hydroxycinnamate is well known, the influence of the structural variation of the organic component as well as the nature of the metal centre has not previously been addressed. Herein we show that praseodymium 4-hydroxy cinnamate is comparable to its lanthanum counterpart in aqueous solution. On the other hand, cerium 4-hydroxycinnamate and lanthanum 2-hydroxycinnamate show poor corrosion protection performance while lanthanum 3-hydroxycinnamate provides a level of inhibition between these. These differences are shown to be related to the speciation in solution and are postulated to be linked to steric influences which are likely to affect the bonding environment within the rare earth compound itself, as well as its bonding with the steel substrate.

  9. The influence of the structure of the metal load removal from liquid steel in electric arc furnaces

    Science.gov (United States)

    Pǎcurar, Cristina; Hepuť, Teodor; Crisan, Eugen

    2016-06-01

    One of the main technical and economic indicators in the steel industry and steel respectively the development it is the removal of liquid steel. This indicator depends on several factors, namely technology: the structure and the quality metal load, the degree of preparedness of it, and the content of non-metallic material accompanying the unit of drawing up, the technology for the elaboration, etc. research has been taken into account in drawing up steel electric arc furnace type spring EBT (Electric Bottom taping), seeking to load and removing components of liquid steel. Metal load has been composed of eight metal grades, in some cases with great differences in terms of quality. Data obtained were processed in the EXCEL spreadsheet programs and MATLAB, the results obtained being presented both graphically and analytically. On the basis of the results obtained may opt for a load optimal structure metal.

  10. The influence of arc plasma electric and laser treatment on the structure and properties of the high speed steel

    Directory of Open Access Journals (Sweden)

    W. Bochnowski

    2009-07-01

    Full Text Available The examination of the structure, hardness and abrasion resistance of surface layer of high speed steel: HS 2-10-1-8, HS 6-5-2 and HS 10-2-5-8 after arc plasma and laser welding are presented in the paper. They are compared with the properties obtained after conventional hardening. Diode laser of continuous operation and GTAW (Gas Tungsten Arc Welding method were used. As a result of concentrated energy beam treatment applied to a steels surface layer, the structures characteristic of rapid solidification / crystallization process were obtained. The treatment of the steel by arc plasma electric with a single remelted track about 7 mm width does not lead to growth of the mechanical and tribological properties of high speed steels. The growth of microhardness as well as low the coefficient Archard of the high speed steel after remelting on the surface single track about 6 mm width by diode laser using can be obtained.

  11. Analysis of the variation in nanohardness of pearlitic steel: Influence of the interplay between ferrite crystal orientation and cementite morphology

    Energy Technology Data Exchange (ETDEWEB)

    Debehets, Jolien, E-mail: jolien.debehets@mtm.kuleuven.be [Department of Materials Engineering, KU Leuven, University of Leuven, Kasteelpark Arenberg 44 bus 2450, B-3001 Leuven (Belgium); Tacq, Jeroen [Department of Materials Engineering, KU Leuven, University of Leuven, Kasteelpark Arenberg 44 bus 2450, B-3001 Leuven (Belgium); Favache, Audrey; Jacques, Pascal [Institute of Mechanics, Materials and Civil Engineering, Université catholique de Louvain, Place Sainte Barbe 2 L5.02.02, 1348 Louvain-la-Neuve (Belgium); Seo, Jin Won; Verlinden, Bert; Seefeldt, Marc [Department of Materials Engineering, KU Leuven, University of Leuven, Kasteelpark Arenberg 44 bus 2450, B-3001 Leuven (Belgium)

    2014-10-20

    The influence of the relative orientation of the ferrite crystallite lattice and the cementite lamellae on the hardness of pearlitic steel has been investigated by a combination of nanoindentation and electron microscopy (electron back scatter diffraction (EBSD) and scanning electron microscopy (SEM)). Three pearlitic samples, each with a different interlamellar spacing, and one ferritic sample were nanoindented. Although the hardness of the ferritic sample is very similar at different spots on the sample, a large variation in hardness is obtained on each of the pearlitic samples. It has been found that this variation cannot be accounted for solely by the variation in interlamellar spacing and is related to differences in ferrite crystal orientation. As to explain the observed large variation in hardness, the ferrite crystal orientation was considered relative to the cementite lamellae orientation by calculation of the distance dislocations can glide between adjacent lamellae in the slip direction. However, no clear correlation was found for a scaling of this orientation factor with the hardness. Possible interpretations of this discrepancy are suggested.

  12. Influence of process parameters on physical dimensions of AA6063 aluminium alloy coating on mild steel in friction surfacing

    Directory of Open Access Journals (Sweden)

    B. Vijaya Kumar

    2015-09-01

    Full Text Available An attempt is made in the present study to obtain the relationships among process parameters and physical dimensions of AA6063 aluminium alloy coating on IS2062 mild steel obtained through friction surfacing and their impact on strength and ductility of the coating. Factorial experimental design technique was used to investigate and select the parameter combination to achieve a coating with adequate strength and ductility. Spindle speed, axial force and table traverse speed were observed to be the most significant factors on physical dimensions. It was observed that the thickness of the coating decreased as the coating width increased. In addition, the width and thickness of the coatings are higher at low and high torques. At intermediate torque values, when the force is high, the width of the coating is high, and its thickness is thin; and when the force is low, the width and thickness are low. The interaction effect between axial force (F – table traverse speed (Vx and spindle speed (N – table traverse speed (Vx produced an increasing effect on coating width and thickness, but other interactions exhibited decreasing influence. It has also been observed that sound coatings could be obtained in a narrow set of parameter range as the substrate-coating materials are metallurgically incompatible and have a propensity to form brittle intermetallics.

  13. Influence of Postbuild Microstructure on the Electrochemical Behavior of Additively Manufactured 17-4 PH Stainless Steel

    Science.gov (United States)

    Stoudt, M. R.; Ricker, R. E.; Lass, E. A.; Levine, L. E.

    2017-03-01

    The additive manufacturing build process produces a segregated microstructure with significant variations in composition and phases that are uncommon in traditional wrought materials. As such, the relationship between the postbuild microstructure and the corrosion resistance is not well understood. Stainless steel alloy 17-4 precipitation hardened (SS17-4PH) is an industrially relevant alloy for applications requiring high strength and good corrosion resistance. A series of potentiodynamic scans conducted in a deaerated 0.5-mol/L NaCl solution evaluated the influence of these microstructural differences on the pitting behavior of SS17-4. The pitting potentials were found to be higher in the samples of additively processed material than in the samples of the alloy in wrought form. This indicates that the additively processed material is more resistant to localized corrosion and pitting in this environment than is the wrought alloy. The results also suggest that after homogenization, the additively produced SS17-4 could be more resistant to pitting than the wrought SS17-4 is in an actual service environment.

  14. Influence of the electrical sliding speed on friction and wear processes in an electrical contact copper stainless steel

    Science.gov (United States)

    Bouchoucha, A.; Chekroud, S.; Paulmier, D.

    2004-02-01

    Among the various parameters that influence the friction and wear behaviour of a copper-stainless steel couple crossed by an electrical current and in a dry contact is the sliding speed. The tests were carried out under ambient environment and the sliding speed was in the range of 0.2-8 ms -1. The electrical current intensity was varied from 0 to 40 A and held constant during each experiment. The normal load was maintained constant corresponding to an average Hertzian stress of 10 7 Pa. It appears that the friction coefficient and the wear rate increase at first with the speed, reach their maximums, then slowly decrease and tend to constant values. Over the entire range of sliding speeds two types of wear are observed. These latters are essentially mild wear as long as hard debris do not appear at the interface and severe wear when debris consisting of oxides or oxide metal mixture become big enough, they are removed from the surface and have abrasive effect. The results are discussed in terms of observations of wear debris size and composition, wear track study, metallographic study of worn surfaces and friction and electrical contact resistance records.

  15. Influence of Shielding Gas Composition on the Properties of Flux-Cored Arc Welds of Plain Carbon Steel

    Directory of Open Access Journals (Sweden)

    Ramy Gadallah

    2012-01-01

    Full Text Available In this study, the influence of variation in the shielding gas composition on the weld properties of steel ST 37-3 was investigated. Six different shielding gas compositions in addition to pure argon (Ar and pure CO2 were studied in this work using flux cored arc welding (FCAW process. For bead-on-plate (B.O.P specimens pure Ar shielding gas has excellent arc stability; however, with increase of the CO2 percent in the shielding gas compositions, the arc stability becomes noisy (unstable arc especially for pure CO2 . 75% Ar – 25% CO2 shielding gas composition has the optimum deposition rate among other shielding gases for B.O.P. Furthermore, for complete real welded joints, the absorbed energy in the Charpy impact toughness test of weld metal (W.M decreases with increase of the CO2 percent in the shielding gas composition. Additionally, the hardness of W.M decreases with the increase of the CO2 percent in the shielding gas composition.

  16. The Influence of Post-Build Microstructure on the Electrochemical Behavior of Additively Manufactured 17-4 PH Stainless Steel.

    Science.gov (United States)

    Stoudt, M R; Ricker, R E; Lass, E A; Levine, L E

    2017-03-01

    The additive manufacturing (AM) build process produces a segregated microstructure with significant variations in composition and phases that are uncommon in traditional wrought materials. As such, the relationship between the post-build microstructure and the corrosion resistance is not well understood. Stainless steel alloy 17-4PH is an industrially-relevant alloy for applications requiring high-strength and good corrosion resistance. A series of potentiodynamic scans conducted in a deaerated 0.5 mol/L NaCl solution evaluated the influence of these microstructural differences on the pitting behavior of SS17-4. The pitting potentials were found to be higher in the samples of additively-processed material than in samples of the alloy in wrought form. This indicates that the additively-processed material is more resistant to localized corrosion and pitting in this environment than the wrought alloy. The results also suggest that after homogenization, the additively-produced SS17-4 could be more resistant to pitting than wrought SS17-4 in an actual service environment.

  17. Influence of tempered microstructures on the transformation behaviour of cold deformed and intercritically annealed medium carbon low alloy steel

    Directory of Open Access Journals (Sweden)

    Kenneth Kanayo Alaneme

    2010-06-01

    Full Text Available This research is focused on understanding the role of microstructural variables and processing parameters in obtaining optimised dual phase structures in medium carbon low alloy steels. Tempered Martensite structures produced at 300, 500, and 650 °C, were cold rolled to varied degrees ranging from 20 to 80% deformation. Intercritical annealing was then performed at 740, 760, and 780 °C for various time duration ranging from 60 seconds to 60 minutes before quenching in water. The transformation behaviour was studied with the aid of optical microscopy and hardness curves. From the results, it is observed that microstructural condition, deformation, and intercritical temperatures influenced the chronological order of the competing stress relaxation and decomposition phase reactions which interfered with the rate of the expected α → γ transformation. The three unique transformation trends observed are systematically analyzed. It was also observed that the 300 and 500 °C tempered initial microstructures were unsuitable for the production of dual structures with optimized strength characteristics.

  18. Simulation of Drawing of Small Stainless Steel Platinum Medical Tubes—Influence of the Tool Parameters on the Forming Limit

    Science.gov (United States)

    Linardon, Camille; Affagard, Jean-Sébastien; Chagnon, Grégory; Favier, Denis; Gruez, Benoit

    2011-05-01

    Tube cold drawing processes are used to reduce tube diameters and thickness, while pulling them through a conical converging die with or without inner plug. An accurate modelling of the material deformation and friction behaviour is required in order to well describe these processes. The study concerns a stainless steel platinum alloy. The material behaviour is characterised through tensile tests at strain rates as close as possible to the high strain rates reached during the drawing process. The results are fitted with an isotropic temperature-independent Johnson Cook constitutive equation. The modelling of floating plug drawing is performed on a ABAQUS/Explicit model. Friction coefficient is difficult to estimate with mechanical experimental tests, thus an inverse analysis is carried out to fit this parameter thanks to finite element simulation and experimental drawing tests. Drawing force measurements are recorded during the forming process. The Cockroft-Latham criterion is applied to understand the different process parameters influence on tube drawing and its accuracy for drawing process is evaluated.

  19. Influence of rare earth elements on solidification behavior of a high speed steel for roll using differential scanning calorimetry

    Institute of Scientific and Technical Information of China (English)

    WANG Mingjia; CHEN Lei; WANG Zixi; BAO Er

    2011-01-01

    The influence of rare earths (RE) on solidification behavior of a high speed steel for roll was investigated by using differential scanning calorimetry (DSC) in combination of microstructure analysis.It was found that the sequence of solidification was L→γ,L→γ+MC,L→γ+M2C,L→γ+M6C,respectively.The start temperature and the latent heat liberated by unit mass of L→γ and L→γ+MC increased with increase of RE addition,indicating that RE could trigger the crystallization of the primary γ and the MC carbide more effectively.The promoting effect of RE on the heterogeneous nucleation was believed to be an important cause of this effect.Grain refinement,discontinuous network of eutectic carbides and disperse and finer MC were observed in the samples with RE addition,moreover,RES could act as the heterogeneous nucleus of the MC.RE addition was favorable for stable M6C at the expense of the metastable M2C.

  20. Influence of Postbuild Microstructure on the Electrochemical Behavior of Additively Manufactured 17-4 PH Stainless Steel

    Science.gov (United States)

    Stoudt, M. R.; Ricker, R. E.; Lass, E. A.; Levine, L. E.

    2017-01-01

    The additive manufacturing build process produces a segregated microstructure with significant variations in composition and phases that are uncommon in traditional wrought materials. As such, the relationship between the postbuild microstructure and the corrosion resistance is not well understood. Stainless steel alloy 17-4 precipitation hardened (SS17-4PH) is an industrially relevant alloy for applications requiring high strength and good corrosion resistance. A series of potentiodynamic scans conducted in a deaerated 0.5-mol/L NaCl solution evaluated the influence of these microstructural differences on the pitting behavior of SS17-4. The pitting potentials were found to be higher in the samples of additively processed material than in the samples of the alloy in wrought form. This indicates that the additively processed material is more resistant to localized corrosion and pitting in this environment than is the wrought alloy. The results also suggest that after homogenization, the additively produced SS17-4 could be more resistant to pitting than the wrought SS17-4 is in an actual service environment.

  1. Influence of temperature on the oxidation/corrosion process of F82Hmod. martensitic steel in lead-bismuth

    Energy Technology Data Exchange (ETDEWEB)

    Gomez Briceno, D.; Soler Crespo, L.; Martin Munoz, F.J.; Hernandez Arroyo, F

    2002-06-01

    A F82Hmod. martensitic steel has been tested in lead-bismuth under a gas atmosphere with a H{sub 2}/H{sub 2}O equilibrium of 0.3 to examine the influence of temperature on the oxidation/corrosion process. The temperature range studied was 535-550 deg. C, temperatures just below the temperature transformation of magnetite into wustite. The durations of the tests were 500 and 1000 h and the oxygen concentration in lead-bismuth was between 3x10{sup -7} and 4x10{sup -7} wt%. The results point out the existence of a threshold temperature, around 550 deg. C, above which corrosion occurs and the formation of a protective oxide layer is not possible. Two approaches have been considered to explain this behaviour: (a) a kinetic mechanism more than thermodynamic considerations as the driving force of the oxidation/corrosion in lead-bismuth under low oxygen potential, (b) the possible transformation of magnetite into wustite.

  2. Materials Selection Criteria for Nuclear Power Applications: A Decision Algorithm

    Science.gov (United States)

    Rodríguez-Prieto, Álvaro; Camacho, Ana María; Sebastián, Miguel Ángel

    2016-02-01

    An innovative methodology based on stringency levels is proposed in this paper and improves the current selection method for structural materials used in demanding industrial applications. This paper describes a new approach for quantifying the stringency of materials requirements based on a novel deterministic algorithm to prevent potential failures. We have applied the new methodology to different standardized specifications used in pressure vessels design, such as SA-533 Grade B Cl.1, SA-508 Cl.3 (issued by the American Society of Mechanical Engineers), DIN 20MnMoNi55 (issued by the German Institute of Standardization) and 16MND5 (issued by the French Nuclear Commission) specifications and determine the influence of design code selection. This study is based on key scientific publications on the influence of chemical composition on the mechanical behavior of materials, which were not considered when the technological requirements were established in the aforementioned specifications. For this purpose, a new method to quantify the efficacy of each standard has been developed using a deterministic algorithm. The process of assigning relative weights was performed by consulting a panel of experts in materials selection for reactor pressure vessels to provide a more objective methodology; thus, the resulting mathematical calculations for quantitative analysis are greatly simplified. The final results show that steel DIN 20MnMoNi55 is the best material option. Additionally, more recently developed materials such as DIN 20MnMoNi55, 16MND5 and SA-508 Cl.3 exhibit mechanical requirements more stringent than SA-533 Grade B Cl.1. The methodology presented in this paper can be used as a decision tool in selection of materials for a wide range of applications.

  3. The Influence of Calcined Clay Pozzolan, Low-Cao Steel Slag and Granite Dust On the Alkali-Silica Reaction in Concrete

    Directory of Open Access Journals (Sweden)

    James Sarfo-Ansah

    2015-08-01

    Full Text Available The influence of low CaO steel slag, calcined clay and granite dust on the alkali-silica reaction was investigated over a period of 35 days under accelerated curing conditions. The mineral admixtures were used to replace varying portions of high alkali Portland limestone cement up to an admixture content of 25% in order to study their effect on the alkali-silica reaction (ASR. Portland limestone cement used for the study had a total Na2Oeq of 4.32. XRD analysis of hydrated mortar bar samples confirmed the formation of an expansive sodium silica gel in the reference Portland cement mortar bar as the agent responsible for ASR. Stable calcium silicates were formed in the mortar bars containing calcined clay in increasing quantities whilst the presence of the sodium silicate gel decreased.The occurrence of these stable silicates in hydrated samples containing steel slag and granite dust was however minimal, compared to calcined clay cement mortars. The highest expansion was recorded for granite dust mortar bars, reaching a maximum of 25.98% at 35 days. Mortar-bar expansion decreased as calcined clay content in the cement increased;mortar bars with 25% calcined clay were the least expansive recording expansion less than 0.1% at all test ages. Whilst the expansion was reduced by between 42.5% and 107.8% at 14 days with increasing calcined clay content, expansion rather increased between 36.8% and 169.5% at 14 days with increasing granite dust content.Steel slag mortar bars experienced reduction in 14 days expansion between 14.3% - 46.2%.The study confirms that steel slag and calcined clay pozzolan have greater influence on ASR in mortar bars than granite dust and shows that calcined clay and low CaO steel slag could be considered as remedial admixtures for ASR at replacement levels of 25% and 15% respectively.

  4. The influence of the hardening coolant agent on the properties of hot rolled bars of the steel 42CrMo4

    Directory of Open Access Journals (Sweden)

    M. Stańczyk

    2014-10-01

    Full Text Available In the work the influence results of two different hardening coolant agents on the basic mechanical proprieties and microstructure of the round hot rolled bars were presented. The bars of 42CrMo4 steel were exposed to analysis, and for those bars in the hardening process, water and modern pro-ecological polymer cooling agents Aqua Quench MK were used.

  5. The influence of pluronic P123 micelles on corrosion behaviour of steel in cement extract and bulk matrix properties of cement paste

    OpenAIRE

    Koleva, D. A.; Denkova, A. .G.; Hu, J; Breugel, K. van

    2012-01-01

    The influence of Pluronic P123 (PEO20-PPO20-PEO70) micelles (of 10 nm size) on the corrosion behaviour of low carbon steel in cement extract (CE) was studied using electrochemical impedance spectroscopy (EIS) and potentio-dynamic polarisation (PDP). Additionally, mercury intrusion porosimetry (MIP) was emplo ed to derive the impact of admixed micelles on porosity and pore-size distribution of cement paste. The motivation for carrying out this investigation has two main aspects: first, previou...

  6. Influence of nitrogen on the stress corrosion cracking resistance of austenitic stainless steels in chloride environment; Influence de l'azote sur la resistance a la corrosion sous contrainte d'aciers inoxydables austenitiques en milieu chlorure

    Energy Technology Data Exchange (ETDEWEB)

    Teysseyre, S

    2001-11-01

    The aim of this study is to investigate the influence of nitrogen additions on the Stress Corrosion Cracking (SSC) resistance of austenitic stainless steel in chloride environment. The investigation was carried out in two part: first, an experimental investigation with model industrial steels was carried out and secondly, numerical simulations based on the Corrosion Enhanced Plasticity Model were developed. Both slow strain rate tensile tests and constant load test of the different steels in boiling MgCl{sub 2} (153 deg C) at free potential show that, for a given plastic strain rate, nitrogen addition increases the critical stress for crack initiation without influencing the crack propagation rate. We observed that the creep rate under constant load was affected by the nitrogen content. As a consequence, the SCC behaviour (cracks density and propagation rate) depends on the nitrogen content. We thus confirm that the nitrogen content influences the corrosion - deformation interaction mechanisms via its positive contribution to the flow stress. These experimental results are reproduced semi-quantitatively by means of numerical simulations at the scale of crack. - dislocation interactions. The presence of nitrogen is modelled by an increased lattice friction stress, which in turn affects the dynamics of crack tip shielding by dislocation pile-ups. We conclude that nitrogen addition in austenitic stainless steels increases the SC crack initiation stress in proportion of the increased flow stress, without penalty in terms of SC crack propagation rate. (author)

  7. Influence of the Heterogeneous Nucleation Sites on the Kinetics of Intermetallic Phase Formation in Aged Duplex Stainless Steel

    Science.gov (United States)

    Melo, Elis Almeida; Magnabosco, Rodrigo

    2017-09-01

    The aim of this work is to study the influence of the heterogeneous nucleation site quantity, observed in different ferrite and austenite grain size samples, on the phase transformations that result in intermetallic phases in a UNS S31803 duplex stainless steel (DSS). Solution treatment was conducted for 1, 24, 96, or 192 hours at 1373 K (1100 °C) to obtain different ferrite and austenite grain sizes. After solution treatment, isothermal aging treatments for 5, 8, 10, 20, 30, or 60 minutes at 1123 K (850 °C) were performed to verify the influence of different amounts of heterogeneous nucleation sites in the kinetics of intermetallic phase formation. The sample solution treated for 1 hour, with the highest surface area between matrix phases, was the one that presented, after 60 minutes at 1123 K (850 °C), the smaller volume fraction of ferrite (indicative of greater intermetallic phase formation), higher volume of sigma (that was present in coral-like and compact morphologies), and chi phase. It was not possible to identify which was the first nucleated phase, sigma or chi. It was also observed that the phase formation kinetics is higher for the sample solution treated for 1 hour. It was evidenced that, from a certain moment on, the chi phase begins to be consumed due to the sigma phase formation, and the austenite/ferrite interface presents higher S V for all solution treatment times. It was also observed that intermetallic phases form preferably in austenite-ferrite interfaces, although the higher occupation rate occurs at triple junction ferrite-ferrite-ferrite. It was verified that there was no saturation of nucleation sites in any interface type nor triple junction, and the equilibrium after 1 hour of aging at 1123 K (850 °C) was not achieved. It was then concluded that sigma phase formation is possibly controlled by diffusional processes, without saturation of nucleation sites.

  8. INVESTIGATION BY NUMERICAL MODELING OF INFLUENCE OF THE SHAPE OF DEFORMING ZONE OF DIE AT WIRE DRAWING OF STEEL HIGH-CARBON WIRE ON TEMPERATURE AND MODE OF DEFORMATION IN WIRE AND DIE

    Directory of Open Access Journals (Sweden)

    Ju. L. Bobarikin

    2010-01-01

    Full Text Available Investigation by numerical modeling of influence of the form of deforming zone of die at drawing of steel highcarbon wire on temperature and strained-deformed state in wire and die is carried out.

  9. Influence of corrugation shape in steel bars ductility used on reinforced concrete

    Science.gov (United States)

    Hortigón, B.; Nieto, E. J.; Fernández, F.; Hernández, O.

    2012-04-01

    Necking process stress and strain analysis, which is key to determine the plastic flow evolution in finite deformation, has been widely studied and applied to a number of materials based on the theories established by Davidenkov-Spiridnova and Bridgman in the 40's decade. These theories envolve from the study of necking geometry in fracture. In this paper, we develop an exhaustive experimental analysis of the stress and strain field in the necking process, applied to concrete bars and mechanized samples with similar features, in order to compare the results with the ones given by the theories listed above and to look for the corrugation influence in the material's plastic behavior.

  10. Influence of Thermal Homogenization Treatment on Structure and Impact Toughness of H13 ESR Steel

    Institute of Scientific and Technical Information of China (English)

    MA Dang-shen; ZHOU Jian; CHEN Zai-zhi; ZHANG Zhong-kan; CHEN Qi-an; LI De-hui

    2009-01-01

    The as-cast microstrueture of H13 ESR ingot and the influence of high temperature diffusion treatment on the structure and impact toughness have been investigated. The results show that the dendrite arm spacing gradually becomes wide from the surface to the center of ingot, and the large primary carbide particles always exist in interdendritic segregation areas; by means of high temperature diffusion treatment of ingot prior to hot forging, the banded segregation is nearly eliminated, the annealed structure is more uniform and the isotropic properties have been improved remarkably.

  11. Influence of temperature histories during reactor startup periods on microstructural evolution and mechanical properties of austenitic stainless steel irradiated with neutrons

    Science.gov (United States)

    Kasahara, Shigeki; Kitsunai, Yuji; Chimi, Yasuhiro; Chatani, Kazuhiro; Koshiishi, Masato; Nishiyama, Yutaka

    2016-11-01

    This paper addresses influence of two different temperature profiles during startup periods in the Japan Materials Testing Reactor and a boiling water reactor upon microstructural evolution and mechanical properties of austenitic stainless steel irradiated with neutrons to about 1 dpa and 3 dpa. One of the temperature profiles was that the specimens experienced neutron irradiation in both reactors, under which the irradiation temperature transiently increased to 290 °C from room temperature with increasing reactor power during reactor startup periods. Another was that the specimens were pre-heated to about 150 °C prior to the irradiation to suppress the transient temperature increase. Tensile tests at 290 °C and Vickers hardness tests at room temperature were carried out, and their microstructures were observed by FEG-TEM. Difference of the temperature profiles was observed obviously in interstitial cluster formation, in particular, growth of Frank loops. Although influence of neutron irradiation involving transient temperature increase to 290 °C from room temperature on the yield strength and the Vickers hardness is buried in the trend curves of existing data, the influence was also found certainly in increment of in yield strength, existence of modest yield drop, and loss of strain hardening capacity and ductility. As a result, Frank loops, which were observed in austenitic stainless steel irradiated at doses of 1 dpa or more, seemed to have important implications regarding the interpretation of not irradiation hardening, but deformation of the austenitic stainless steel.

  12. Influence of respiratory substrate in carbon steel corrosion by a Sulphate Reducing Prokaryote model organism.

    Science.gov (United States)

    Dall'agnol, Leonardo T; Cordas, Cristina M; Moura, José J G

    2014-06-01

    Sulphate Reducing Prokaryotes (SRP) are an important group of microorganisms involved in biocorrosion processes. Sulphide production is recognized as a fundamental cause of corrosion and nitrate is often used as treatment. The present work analyses the influence of respiratory substrates in the metal, from off-shore installations, SRP influenced corrosion, using Desulfovibrio desulfuricans ATTC 27774 as model organism, since this can switch from sulphate to nitrate. Open Circuit Potential over 6days in different conditions was measured, showing an increase around 200 and 90mV for the different media. Tafel plots were constructed allowing Ecorr and jcorr calculations. For SRP in sulphate and nitrate media Ecorr values of -824 and -728mV, and jcorr values of 2.5 and 3.7μAcm(-2), respectively, were attained indicating that in nitrate, the resultant corrosion rate is larger than in sulphate. Also, it is shown that the equilibrium of sulphide in the solution/gas phases is a key factor to the evolution of corrosion Nitrate prevents pitting but promotes general corrosion and increases the corrosion potential and iron dissolution 40 times when compared to sulphate. Our results demonstrate that nitrate injection strategy in oil fields has to be considered carefully as option to reduce souring and localized corrosion.

  13. Microstructural evolution in warm-rolled and cold-rolled strip cast 6.5 wt% Si steel thin sheets and its influence on magnetic properties

    Science.gov (United States)

    Wang, Xianglong; Liu, Zhenyu; Li, Haoze; Wang, Guodong

    2017-07-01

    6.5 wt% Si steel thin sheets were usually fabricated by warm rolling. In our previous work, 6.5 wt% Si steel thin sheets with good magnetic properties had been successfully fabricated by cold rolling based on strip casting. In the present work, the main purposes were to find out the influences of warm rolling and cold rolling on microstructures and magnetic properties of the thin sheets with the thickness of 0.2 mm, and to confirm which rolling method was more suitable for fabricating 6.5 wt% Si steel thin sheets. The results showed that the cold rolled sheet could obtain good surface quality and flatness, while the warm rolled sheet could not. The intensity of γ-fiber rolling texture (//ND) of cold rolled specimen was weaker than that of the warm rolled specimen, especially for the {1 1 1} component at surface layer and {1 1 1} component at center layer. After the same annealing treatment, the cold rolled specimen, which had higher stored energy and weaker intensity of γ-fiber rolling texture, could obtain smaller recrystallization grain size, weaker intensity of γ-fiber recrystallization texture and stronger intensity of λ-fiber recrystallization texture. Therefore, due to the good surface quality, smaller recrystallization grain size and optimum recrystallization texture, the cold rolled specimen possessed improved magnetic properties, and cold rolling should be more suitable for fabricating 6.5 wt% Si steel thin sheets.

  14. Influence of Z-phase on long-term creep stability of martensitic 9-12% Cr steels

    Energy Technology Data Exchange (ETDEWEB)

    Danielsen, Hilmar K. [Technical Univ. of Denmark, Lyngby (Denmark). Dept. of Mechanical Engineering; Hald, John [DONG Energy A/S (Denmark); Vattenfall (Denmark)

    2010-07-01

    The long-term creep strength of the new generation of martensitic creep resistant 9-12%Cr steels since the well-known steel Grade 91 relies strongly on particle strengthening by fine Mn nitrides based on V and Nb. During long-term high-temperature exposures the Mn nitrides may be replaced by the thermodynamically more stable Z-phases (Cr(V,Nb)N) causing a breakdown in creep strength. Cr contents above 10.5% strongly accelerate Z-phase precipitation, which explains the lack of success for all attempts to develop martensitic creep resistant steels with high Cr content for oxidation protection. However 9%Cr steels do not seem to be affected by the Z-phase. Careful control of the Z-phase precipitation process has led to the design of experimental 12%Cr martensitic steels strengthened by fine Z-phase nitrides based on Nb or Ta. Such steels may again enable the combination of high strength and oxidation resistance in the same alloy. This opens a new pathway for further alloy development of the heat resistant martensitic steels. (orig.)

  15. Influence of the carbon content on the phase composition and mechanical properties of P92-type steel

    Science.gov (United States)

    Dudko, V. A.; Fedoseeva, A. E.; Belyakov, A. N.; Kaibyshev, R. O.

    2015-11-01

    The deformation behavior and the microstructure evolution under the creep of 10Kh9V2MFBR steel (Russian analog of the P92 steel) (in wt %, Fe-8.9% Cr-0.05% Si-0.2% Mn-1.9% W-0.5% Mo-0.25% V-0.07Nb-0.08% N-0.01% B) with the standard (0.1%) and lowered (0.018%) carbon contents have been investigated. After the heat treatment, which included normalizing at 1050°C and tempering at 720-750°C, carbides M 23 C 6 and carbonitrides M(C,N) are formed in the 10Kh9V2MFBR steel, while in the 02Kh9V2MFBR steel (modified P92 steel), carbides M 23 C 6, nitrides M 2N, and carbonitrides M(C,N) as well as δ-ferrite (23%) were found. The measurements of hardness and tensile tests at room and elevated temper-atures did not reveal substantial distinctions in the short-term mechanical properties of both steels. The hardness of steels after tempering was 220 HB. At the same time, the creep characteristics of the steels were found to be different. A decrease in the carbon content leads to an increase in the long-term creep strength and creep limit at 650°C for short-term tests with time-to-fracture shorter than 103 h. The time to fracture of steels with various carbon contents is almost the same in long-term creep tests. Factor responsible for such effect of carbon on the creep strength are discussed.

  16. Microbiologically influenced corrosion of galvanized steel by Desulfovibrio sp. and Desulfosporosinus sp. in the presence of Ag–Cu ions

    Energy Technology Data Exchange (ETDEWEB)

    Ilhan-Sungur, Esra, E-mail: esungur@istanbul.edu.tr [Istanbul University, Faculty of Science, Department of Biology, 34134 Vezneciler, Istanbul (Turkey); Unsal-Istek, Tuba [Istanbul University, Faculty of Science, Department of Biology, 34134 Vezneciler, Istanbul (Turkey); Cansever, Nurhan [Yıldız Technical University, Faculty of Chemistry-Metallurgy, Metallurgical and Materials Engineering Department, 34210 Esenler, Istanbul (Turkey)

    2015-07-15

    The effects of Ag–Cu ions on the microbiologically induced corrosion of galvanized steel in the presence of Desulfovibrio sp. and Desulfosporosinus sp. were investigated. The corrosion behavior of galvanized steel was analyzed by potentiodynamic polarization and electrochemical impedance spectroscopy. The biofilm, corrosion products and Ag–Cu ions on the surfaces were investigated by using scanning electron microscopy, energy dispersive X-ray spectrometry and elemental mapping. The biofilm layer formed by the Desulfovibrio sp. was stable covering the all surface of galvanized steel coupons, while that by Desulfosporosinus sp. was intermittent, highly porous and heterogeneous. It was found that both of the sulfate reducing bacteria species accelerated corrosion of the galvanized steel. However, it was detected that Desulfosporosinus sp. was more corrosive for galvanized steel than Desulfovibrio sp. Scanning electron microscopy images showed that Desulfovibrio sp. and Desulfosporosinus sp. in biofilm clustered into patches on the galvanized steel surface when the culture contained toxic Ag–Cu ions. The ions affected the growth of the sulfate reducing bacteria strains in different ways and hence the corrosion behaviors. It was observed that the Ag–Cu ions affected negatively growth of Desulfosporosinus sp. especially after 24 h of exposure leading to a decrease in the corrosion rate of galvanized steel. However, Desulfovibrio sp. showed more corrosive effect in the presence of the ions according to the ions-free culture. Energy dispersive X-ray spectrometry analysis showed that corrosion products on the surfaces were mainly composed of Zn, S, Na, O and P. - Highlights: • Galvanized steel was corroded by Desulfosporosinus sp. and Desulfovibrio sp. • Desulfosporosinus sp. is more corrosive than Desulfovibrio sp. • The Ag–Cu ions affected corrosion behavior of Desulfosporosinus sp. and Desulfovibrio sp. on galvanized steel.

  17. The influence of drawing speed on structure changes in high carbon steel wires

    Directory of Open Access Journals (Sweden)

    M. Suliga

    2015-01-01

    Full Text Available In the paper the influence of the drawing speed on structure changes has been assessed. The Scanning Electron Microscope investigation confirmed that for wires drawn with high total draft, exceeding 80 %, makes it impossible to clearly assess the impact of drawing technology on structural changes in the drawn wires. Thus, to assess the structural changes necessary to apply quantitative methods. On the basis of examination of the wire structure by measuring of electrical resistance, the structure changes in drawn wires has been determined. It has been shown that the increase of drawing speed, especially above 15 m/s, causes an increase in structure defect, with a decline in platelet orientation of cementite in drawn wires.

  18. Influence of HVOF coating on the HCF of 300M low alloy steel

    Institute of Scientific and Technical Information of China (English)

    DENG; Chun-ming; LIU; Min; ZHOU; Ke-song; SONG; Jin-bing; WU; Chao-qun; KUANG; Min

    2005-01-01

    The ultimate methods for solving the contamination of Cr6+ is to replace the Cr electroplating with other techniques, thermal spray provides one of the best choices among those alternative techniques. The influence of coatings upon the fatigue performance of substrate, however,should be labeled as an important factor at some high level applications. The effects of both coatings manufactured by HVOF and Cr electroplating respectively on the fatigue performance of substrate are investigated in this article. These results show that the fatigue limit strength at P= 50 %of thermal spray coating is 750 MPa in comparing with fatigue limit 726 MPa for substrate, and the fatigue life increase 25%- 150% when comparing with fatigue life of substrate at different stress levels. The fatigue life increases in the stress scope of 750-850 MPa even the area of thermal spray coating is subtracted. Cr eleetroplating coating reduces the fatigue life by 70%- 95% and the fatigue limit is only 600 MPa. Fracture analysis reveals that the main fracture is initiated at the subsurface, which is 0.2-0.5 mm away from substrate surface. The analysis also observes that the crack in the Cr electroplating propagates through the interface and finally into the substrate which hastens the formation of crack origin and the extension of crack in the substrate, however, the crack in the thermal spray coating deflects at the interface, spreads along the interface, as a result,the crack forming in the coatings has no negative influence on the main crack initiator and crack extension in the substrate.

  19. Influence of cerium on hot workability of 00Cr25Ni7Mo4N super duplex stainless steel

    Institute of Scientific and Technical Information of China (English)

    王晓峰; 陈伟庆

    2010-01-01

    The effect of Ce on hot workability of 00Cr25Ni7Mo4N steel melted in vacuum induction furnace was studied by Gleeble thermal simulation machine and scanning electron microscopy(SEM).The results showed that ductility of the steel with Ce addition was increased significantly because of increasing content of austenite,segregation of Ce at grain boundaries and modification of inclusion.The optimum range of Ce content in the steel was 0.030 wt.%-0.047 wt.%,and the optimum value was about 0.047 wt.%.The effect of...

  20. Influence of MgO containing strontium on the structure of ceramic film formed on grain oriented silicon steel surface

    OpenAIRE

    Vasconcelos Daniela C. Leite; Cesar Maria das Graças M.M.; Cunha Marco Antônio da; Vasconcelos Wander L.

    1999-01-01

    The oxide layer formed on the surface of a grain oriented silicon steel was characterized by SEM and EDS. 3% Si steel substrates were coated by two types of slurries: one formed by MgO and water and other formed by MgO, water and SrSO4. The ceramic films were evaluated by SEM, EDS and X-ray diffraction. Depth profiles of Fe, Si and Mg were obtained by GDS. The magnetic core losses (at 1.7 Tesla, 60 Hz) of the coated steel samples were evaluated as well. The use of MgO containing strontium red...

  1. Influence of macrostructure on tensile properties of multipass SAW C-Mn steel deposits

    Science.gov (United States)

    Yongyuth, P.; Ghosh, P. K.; Gupta, P. C.; Patwardhan, A. K.; Prakash, Satya

    1993-06-01

    Blocks of 'all weld' metal were prepared by a multipass submerged arc process, using a C-Mn filler wire, at different welding currents and speeds by keeping the arc voltage constant. The variation in welding parameters was found to alter the macrostructure primarily by influencing its co-axial dendrite content. The chemical composition and hardness of the dendritic and the heat affected regions were affected little by the welding parameters. A dendrite content up to 37%, had no significant effect on the tensile properties. However an increase in it beyond 37% was found to enhance the UTS and YS and reduce percent elongation. The tensile strength was found to be a maximum in the L orientation and a minimum in the S direction. The use of post-weld heat treatment (PWHT) at 873 K caused spheroidization of cementite there by somewhat reducing the hardness and strength. The treatment while not affecting the basic dendritic morphology reduced the observed difference in tensile properties along the L, T and S directions. Implications of the data vis-a-vis industrial applications have been discussed.

  2. The influence of cooling rate on the microstructure of stainless steel alloys

    Energy Technology Data Exchange (ETDEWEB)

    Elmer, J.W.

    1988-09-01

    The emergence of high energy density welding, laser surface modification and rapid solidification as commonly used metallurgical processing techniques has greatly increased the range of cooling rates that can be accessed during the solidification of metals and alloys. The microstructures which develop during these rapid cooling conditions may be significantly different from those which develop during low cooling rate conditions as the result of access to new metastable phases with the additional kinetic limitations that accompany rapid solidification. This investigation explores the influence of cooling rate on a series of seven ternary alloys which span the line of two-fold saturation in the Fe-Ni-Cr system. High speed electron beam surface melting was used to resolidify these alloys at scan speeds up to 5 m/s. The resulting cooling rates were estimated from dendrite arm spacing measurements and were confirmed by heat flow modeling to vary from 7 /times/ 10/sup 0/ /degree/C/s to 8 /times/ 10/sup 6/ /degree/C/s. The microstructures that developed from each solidification condition were examined using optical metallography, electron microprobe analysis, scanning electron microscopy and a vibrating sample magnetometer. These results were used to create diagrams to predict the primary mode of solidification, the ferrite content and the complex microstructural morphologies which develop as a function of interface velocity and composition. 158 refs., 90 figs., 45 tabs.

  3. The influence of the oxygen equivalent in a gas-mixture on the structure and toughness of microalloyed steel weldments

    Directory of Open Access Journals (Sweden)

    RADICA PROKIC-CVETKOVIC

    2006-03-01

    Full Text Available Testings were carried out on two steels. The first was microalloyed with Nb and second with Ti, Nb and V. The impact toughness of weld metals of these steels was evaluated using an instrumented Charpy pendulum. Five different gas mixtures (Ar, CO2, O2 were used to determine the optimal gas shielded metal arc process for both steels. The oxygen equivalent was used as a representative parameter of a mixture to follow, in particularly, its effect on the microstructure, toughness and crack propagation energy of the weld metal. For these investigated steels, the optimum gas mixture was established (5 % CO2, 0.91 % O2, balance Ar, which provided the maximum crack propagation energy, due to the microstructurewhich consisted dominantly of acicular ferrite.

  4. Influence of high pressure hydrogen environment on tensile and fatigue properties of stainless steels at low temperatures

    Science.gov (United States)

    Ogata, T.

    2012-06-01

    Hydrogen environment embrittlement (HEE) of stainless steels in the environment of high pressure and low temperature hydrogen gas was evaluated using a very simple mechanical properties testing procedure. In the method, the high-pressure hydrogen environment is produced just inside the hole in the specimen. In this work, the effects of HEE on fatigue properties for austenitic stainless steels SUS304L and SUS316L were evaluated at 298 and 190 K. The effects of HEE on the tensile properties of higher strength stainless steels, such as strain-hardened 316, SUS630, and other alloys, SUH660 and Alloy 718 were also examined. The less effect of HEE on fatigue properties of SUS316L and tensile properties of strain-hardened 316 were observed compared with SUS304L and other steels at room temperature and 190 K.

  5. INFLUENCE OF FUSION MIXTURE AND ITS TEMPERATURE ON THE VOLUME OF REWORK STEEL OF TYPE St45L

    Directory of Open Access Journals (Sweden)

    I. G. Sapchenko

    2007-01-01

    Full Text Available It is determined that the working out technology will allow to increase the using of wastes, to reduce consumption of liquid steel for production of castings, to eliminate defect at casting and etc.

  6. The Influence of Modes of Deposition of Coatings on the Corrosion Resistance of Welded Joints of Steels in Acidic Media;

    Science.gov (United States)

    Saraev, Yu N.; Bezborodov, V. P.; Selivanov, Y. V.

    2016-08-01

    In this work, effect of welding on corrosion of welded joints of austenitic steel 12KH18N10T. It is shown that the use of pulsed - arc welding steel 12KH18N10T allows you to create a protective coating with dispersed structure with less thermal impact on the zone of the welded joint. Coating is of such structure allows 1.5 to 6 times to reduce the corrosion rate of welded joints of steel 12KH18N10T in active chemical environments. Pulse the process of deposition of coatings on welded joint of steels can be effectively used for the protection against corrosion in the repair of equipment of chemical industry. The results obtained can be recommended for use when welding a protective corrosion - resistant coatings on working surfaces of equipment of chemical productions.

  7. Influence of niobium on the hardening phenomenon and wear in the manganese steel (12% Mn destined for the railway

    Directory of Open Access Journals (Sweden)

    Maouche Hichem

    2014-06-01

    Full Text Available This study relates to the manufacture of austenitic manganese steel for the heart switching crossings of railways in all industrial countries where heavy loads are moved by rail. This steel is characterized by a high surface hardness service yard caused by the phenomenon of hardening. According to the microstructure formed after quenching, the transformation of austenite into martensite during working, determine the operating life. The rate of transformation of austenite into martensite can force a compromise between ductility and wear resistance of the steel in order to withstand large forces without breaking. The objective of this study is to improve the resistance to abrasion and friction to cast state and after heat treatment by the addition of niobium. This study permitted to develop a new shade of manganese steel can be integrated into the production of heart of railway switches with better lifecycle.

  8. Influence of Laser Power on the Microstructure and Mechanical Properties of a Laser Welded-Brazed Mg Alloy/Ni-Coated Steel Dissimilar Joint

    Science.gov (United States)

    Tan, Caiwang; Xiao, Liyuan; Liu, Fuyun; Chen, Bo; Song, Xiaoguo; Li, Liqun; Feng, Jicai

    2017-05-01

    In this work, we describe a method to improve the bonding of an immiscible Mg/steel system using Ni as an interlayer by coating it on the steel surface. Laser welding-brazing of AZ31B Mg alloy to Ni-coated Q235 steel using Mg-based filler was performed in a lap configuration. The influence of laser power on the weld characteristics, including joint appearance, formation of interfacial reaction layers and mechanical properties was investigated. The results indicated that the presence of the Ni-coating promoted the wetting of the liquid filler metal on the steel surface. A thermal gradient along the interface led to the formation of heterogeneous interfacial reaction layers. When using a low laser power of 1600 W, the reaction products were an FeAl phase in the direct laser irradiation zone, an AlNi phase close to the intermediate zone and mixtures of AlNi phase and an (α-Mg + Mg2Ni) eutectic structure near the interface at the seam head zone. For high powers of more than 2000 W, the FeAl phase grew thicker in the direct laser irradiation zone and a new Fe(Ni) transition layer formed at the interface of the intermediate zone and the seam head zone. However, the AlNi phase and (α-Mg + Mg2Ni) eutectic structure were scattered at the Mg seam. All the joints fractured at the fusion zone, indicating that the improved interface was not the weakest joint region. The maximum tensile-shear strength of the Mg/Ni-coated steel joint reached 190 N/mm, and the joint efficiency was 70% with respect to the Mg alloy base metal.

  9. The influence of aluminium, steel and polyurethane shoeing systems and of the unshod hoof on the injury risk of a horse kick. An ex vivo experimental study.

    Science.gov (United States)

    Sprick, Miriam; Fürst, Anton; Baschnagel, Fabio; Michel, Silvain; Piskoty, Gabor; Hartnack, Sonja; Jackson, Michelle A

    2017-08-01

    To evaluate the damage inflicted by an unshod hoof and by the various horseshoe materials (steel, aluminium and polyurethane) on the long bones of horses after a simulated kick. Sixty-four equine radii and tibiae were evaluated using a drop impact test setup. An impactor with a steel, aluminium, polyurethane, or hoof horn head was dropped onto prepared bones. An impactor velocity of 8 m/s was initially used with all four materials and then testing was repeated with a velocity of 12 m/s with the polyurethane and hoof horn heads. The impact process was analysed using a high-speed camera, and physical parameters, including peak contact force and impact duration, were calculated. At 8 m/s, the probability of a fracture was 75% for steel and 81% for aluminium, whereas polyurethane and hoof horn did not damage the bones. At 12 m/s, the probability of a fracture was 25% for polyurethane and 12.5% for hoof horn. The peak contact force and impact duration differed significantly between 'hard materials' (aluminium and steel) and 'soft materials' (polyurethane and hoof horn). The observed bone injuries were similar to those seen in analogous experimental studies carried out previously and comparable to clinical fracture cases suggesting that the simulated kick was realistic. The probability of fracture was significantly higher for steel and aluminium than for polyurethane and hoof horn, which suggests that the horseshoe material has a significant influence on the risk of injury for humans or horses kicked by a horse.

  10. Influences of gaseous environment on low growth-rate fatigue crack propagation in steels. Annual report No. 1, January 1980. Report No. FPL/R/80/1030

    Energy Technology Data Exchange (ETDEWEB)

    Ritchie, R.O.; Suresh, S.; Toplosky, J.

    1980-01-01

    The influence of gaseous environment is examined on fatigue crack propagation behavior in steels. Specifically, a fully martensitic 300-M ultrahigh strength steel and a fully bainitic 2-1/4Cr-1Mo lower strength steel are investigated in environments of ambient temperature moist air and low pressure dehumidified hydrogen and argon gases over a wide range of growth rates from 10/sup -8/ to 10/sup -2/ mm/cycle, with particular emphasis given to behavior near the crack propagation threshold ..delta..K/sub 0/. It is found that two distinct growth rate regimes exist where hydrogen can markedly accelerate crack propagation rates compared to air, (1) at near-threshold levels below (5 x 10/sup -6/ mm/cycle) and (2) at higher growth rates, typically around 10/sup -5/ mm/cycle above a critical maximum stress intensity K/sub max//sup T/. Hydrogen-assisted crack propagation at higher growth rates is attributed to a hydrogen embrittlement mechanism, with K/sub max//sup T/ nominally equal to K/sub Iscc/ (the sustained load stress corrosion threshold) in high strength steels, and far below K/sub Iscc/ in the strain-rate sensitive lower strength steels. Hydrogen-assisted crack propagation at near-threshold levels is attributed to a new mechanism involving fretting-oxide-induced crack closure generated in moist (or oxygenated) environments. The absence of hydrogen embrittlement mechanisms at near-threshold levels is supported by tests showing that ..delta..K/sub 0/ values in dry gaseous argon are similar to ..delta..K/sub 0/ values in hydrogen. The potential ramifications of these results are examined in detail.

  11. Influence of traps on the deuterium behaviour in the low activation martensitic steels F82H and Batman

    Science.gov (United States)

    Serra, E.; Perujo, A.; Benamati, G.

    1997-06-01

    A time dependent permeation method is used to measure the permeability, diffusivity and solubility of deuterium in the low activation martensitic steels F82H and Batman. The measurements cover the temperature range from 373 to 743 K which includes the onset of deuterium trapping effects on diffusivity and solubility. The results are interpreted using a trapping model. The number of trap sites and their average energies for deuterium in F82H and Batman steels are determined.

  12. Influence of traps on the deuterium behaviour in the low activation martensitic steels F82H and Batman

    Energy Technology Data Exchange (ETDEWEB)

    Serra, E. [Commission of the European Communities, Ispra (Italy). Joint Research Centre; Perujo, A. [Commission of the European Communities, Ispra (Italy). Joint Research Centre; Benamati, G. [Associazione ENEA-EURATOM sulla FUSIONE, CR Brasimone, 40032 Camungnano Bologna (Italy)

    1997-06-01

    A time dependent permeation method is used to measure the permeability, diffusivity and solubility of deuterium in the low activation martensitic steels F82H and Batman. The measurements cover the temperature range from 373 to 743 K which includes the onset of deuterium trapping effects on diffusivity and solubility. The results are interpreted using a trapping model. The number of trap sites and their average energies for deuterium in F82H and Batman steels are determined. (orig.).

  13. Deformation induced martensite in an AISI 301LN stainless steel: characterization and influence on pitting corrosion resistance

    OpenAIRE

    Hamilton Ferreira Gomes de Abreu; Sheyla Santana de Carvalho; Pedro de Lima Neto; Ricardo Pires dos Santos; Válder Nogueira Freire; Paulo Maria de Oliveira Silva; Sérgio Souto Maior Tavares

    2007-01-01

    In austenitic stainless steels, plastic deformation can induce martensite formation. The induced martensite is related to the austenite (gamma) instability at temperatures close or below room temperature. The metastability of austenite stainless steels increases with the decreasing of stacking fault energy (SFE). In this work, the deformation induced martensite was analyzed by X ray diffraction, electron back scatter diffraction (EBSD), magnetic methods and atomic force microscope (AFM) in sa...

  14. Influence of niobium on the hardening phenomenon and wear in the manganese steel (12% Mn) destined for the railway

    OpenAIRE

    Maouche Hichem; Hadji Ali; Bouhamla Khedidja

    2014-01-01

    This study relates to the manufacture of austenitic manganese steel for the heart switching crossings of railways in all industrial countries where heavy loads are moved by rail. This steel is characterized by a high surface hardness service yard caused by the phenomenon of hardening. According to the microstructure formed after quenching, the transformation of austenite into martensite during working, determine the operating life. The rate of transformation of austenite into martensite can f...

  15. Influence of the Initial Microstructure on the Heat Treatment Response and Tensile Properties of TRIP-Assisted Steel

    Science.gov (United States)

    Lee, Kyooyoung; Ryu, Joo Hyun; Lee, Sea Woong; Lee, Won Hwi; Kim, Jeong In; Suh, Dong-Woo

    2016-11-01

    Microstructure evolution and mechanical properties were investigated in transformation-induced plasticity (TRIP) steel having a different initial microstructure. Compared with the cold-rolled structure that evolves into a typical microstructure of TRIP steel, the martensitic initial structure produces a more lath-type microstructure as the fraction of retained austenite increases in the initial microstructure. The interlath austenite after heat treatment contributes to improving the tensile properties by the enhanced stability and the refinement of the matrix phase.

  16. Analysis the influence of drawing process parameters on the amount of retained austenite in trip steel wires

    Directory of Open Access Journals (Sweden)

    Z. Muskalski

    2013-01-01

    Full Text Available The paper presents a theoretical analysis of the process of drawing TRIP-effect steel wires involving simulation of the drawing process. The process was run following two variants, with small and large partial drafts for three drawing speeds: 1,11; 0,23 and 0,005 m/s. The investigations carried out allowed a relationship between the amount of retained austenite and strain intensity and strain rate to be established for TRIP steel wires drawn.

  17. Influence of Material Model on Prediction Accuracy of Welding Residual Stress in an Austenitic Stainless Steel Multi-pass Butt-Welded Joint

    Science.gov (United States)

    Deng, Dean; Zhang, Chaohua; Pu, Xiaowei; Liang, Wei

    2017-03-01

    Both experimental method and numerical simulation technology were employed to investigate welding residual stress distribution in a SUS304 steel multi-pass butt-welded joint in the current study. The main objective is to clarify the influence of strain hardening model and the yield strength of weld metal on prediction accuracy of welding residual stress. In the experiment, a SUS304 steel butt-welded joint with 17 passes was fabricated, and the welding residual stresses on both the upper and bottom surfaces of the middle cross section were measured. Meanwhile, based on ABAQUS Code, an advanced computational approach considering different plastic models as well as annealing effect was developed to simulate welding residual stress. In the simulations, the perfect plastic model, the isotropic strain hardening model, the kinematic strain hardening model and the mixed isotropic-kinematic strain hardening model were employed to calculate the welding residual stress distributions in the multi-pass butt-welded joint. In all plastic models with the consideration of strain hardening, the annealing effect was also taken into account. In addition, the influence of the yield strength of weld metal on the simulation result of residual stress was also investigated numerically. The conclusions drawn by this work will be helpful in predicting welding residual stresses of austenitic stainless steel welded structures used in nuclear power plants.

  18. Analysis on the Deflection Angle of Columnar Dendrites of Continuous Casting Steel Billets Under the Influence of Mold Electromagnetic Stirring

    Science.gov (United States)

    Wang, Xincheng; Wang, Shengqian; Zhang, Lifeng; Sridhar, Seetharaman; Conejo, Alberto; Liu, Xuefeng

    2016-11-01

    In the current study, the deflection angle of columnar dendrites on the cross section of steel billets under mold electromagnetic stirring (M-EMS) was observed. A mathematical model was developed to define the effect of M-EMS on fluid flow and then to analyze the relationship between flow velocities and deflection angle. The model was validated using experimental data that was measured with a Tesla meter on magnetic intensity. By coupling the numerical results with the experimental data, it was possible to define a relationship between the velocities of the fluid with the deflection angle of high-carbon steel. The deflection angle of high-carbon steel reached maximum values from 18 to 23 deg for a velocity from 0.35 to 0.40 m/s. The deflection angles of low-carbon steel under different EM parameters were discussed. The deflection angle of low-carbon steel was increased as the magnetic intensity, EM force, and velocity of molten steel increased.

  19. Influence of the pulsed plasma treatment on the corrosion resistance of the low-alloy steel plated by Ni-based alloy

    Science.gov (United States)

    Dzhumaev, P.; Yakushin, V.; Kalin, B.; Polsky, V.; Yurlova, M.

    2016-04-01

    This paper presents investigation results of the influence of high temperature pulsed plasma flows (HTPPF) treatment on the corrosion resistance of low-alloy steel 0.2C-Cr-Mn- Ni-Mo cladded by the rapidly quenched nickel-based alloy. A technique that allows obtaining a defect-free clad layer with a good adhesion to the substrate was developed. It is shown that the preliminary treatment of steel samples by nitrogen plasma flows significantly increases their corrosion resistance in the conditions of intergranular corrosion test in a water solution of sulfuric acid. A change of the corrosion mechanism of the clad layer from intergranular to uniform corrosion was observed as a result of sub-microcrystalline structure formation and homogeneous distribution of alloying elements in the plasma treated surface layer thus leading to the significant increase of the corrosion resistance.

  20. Influence of Surface Modification on Properties of Stainless Steel Used for Implants / Wpływ Modyfikacji Powierzchni Na Właściwości Stali Nierdzewnej Stosowanej Na Implanty

    Directory of Open Access Journals (Sweden)

    Basiaga M.

    2015-12-01

    Full Text Available The aim of the study was assessment of the influence of stainless steel 316 LVM surface modification on its functional properties. The analyzed steel undergone a surface treatment consisting of the following processes: mechanical polishing, chemical passivation and deposition of Al2O3 layers by Atomic Layer Deposition method. The proposed variant of surface treatment will undoubtedly contribute to improving the functional properties of stainless steel intended for implants. In order to assess functional properties of the steel, electrochemical studies, adhesion (scratch test, wetting angle tests and topography of surface (AFM method were performed. The obtained results of the study showed clearly that the proposed by the authors way of surface treatment including: mechanical polishing, chemical passivation and deposition of Al2O3 layer by means of the ALD method effectively improves the corrosion resistance of stainless steel.

  1. Influence of compound deoxidation of steel with Al, Zr, rare earth metals, and Ti on properties of heavy castings

    Directory of Open Access Journals (Sweden)

    J. Senberger

    2012-01-01

    Full Text Available Heavy steel castings deoxidized with aluminium are sometimes brittle intercrystalline failed during their service along primary grain boundaries what is initiated by aluminium nitrides and so called conchoidal fractures are formed. The tendency to forming the conchoidal fractures depends in particular on cooling rate (the casting modulus, aluminium and nitrogen contents in steel. During deoxidation, when manufacturing heavy castings, the elements with high affinity to nitrogen, zirconium or titanium, are added to steel that would decrease nitrogen activity by the bond on stable nitrides. The formation of stable nitrides should reduce the tendency of steel to the formation of conchoidal fractures. Deoxidation was thermodynamically analyzed at presence of the mentioned elements. For particular conditions a probable course of deoxidation was estimated at test castings. The deoxidation course was checked by microanalysis of deoxidation products (inclusions. For service and experimental castings the anticipated composition of inclusions was compared. It has been proved that in heavy castings with high aluminium contents in steel under studied conditions neither the addition of zirconium nor of titanium nor of rare earth metals will prevent the formation of conchoidal fractures.

  2. Influence of steel composition and plastic deformation on the surface properties induced by low temperature thermochemical processing

    DEFF Research Database (Denmark)

    Bottoli, Federico

    “PressPerfect” Project was to create a methodology to predict the performance of high quality stainless steels after forming and finishing treatments. The Ph.D. Project focused on the optimization of low-temperature thermochemical processes on severalstainless steel classes used for the surface treatment of industrial......Low-temperature thermochemical surface hardening by nitriding, carburizing and nitrocarburizing is used to improve the performance of stainless steels with respect to wear, fatigue and corrosion resistance.The dissolution of nitrogen and/or carbon atoms in the materials surface leads...... to the formation of a supersaturated solid solution known as expanded austenite, or S-Phase. Expanded austenite is characterized by high hardness, up to 1400 Vickers, and high compressive stresses in the surface region, which result in improved wear and fatigue resistance of the components. Along...

  3. Can the Point Defect Model Explain the Influence of Temperature and Anion Size on Pitting of Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Blackwood, Daniel J. [National University of Singapore, Singapore (Singapore)

    2015-12-15

    The pitting behaviours of 304L and 316L stainless steels were investigated at 3 °C to 90 °C in 1 M solutions of NaCl, NaBr and NaI by potentiodynamic polarization. The temperature dependences of the pitting potential varied according to the anion, being near linear in bromide but exponential in chloride. As a result, at low temperatures grades 304L and 316L steel are most susceptible to pitting by bromide ions, while at high temperatures both stainless steels were more susceptible to pitting by small chloride anions than the larger bromide and iodide. Thus, increasing temperature appears to favour attack by smaller anions. This paper will attempt to rationalise both of the above findings in terms of the point defect model. Initial findings are that qualitatively this approach can be reasonably successful, but not at the quantitative level, possibly due to insufficient data on the mechanical properties of thin passive films.

  4. Influence of MgO containing strontium on the structure of ceramic film formed on grain oriented silicon steel surface

    Directory of Open Access Journals (Sweden)

    Vasconcelos Daniela C. Leite

    1999-01-01

    Full Text Available The oxide layer formed on the surface of a grain oriented silicon steel was characterized by SEM and EDS. 3% Si steel substrates were coated by two types of slurries: one formed by MgO and water and other formed by MgO, water and SrSO4. The ceramic films were evaluated by SEM, EDS and X-ray diffraction. Depth profiles of Fe, Si and Mg were obtained by GDS. The magnetic core losses (at 1.7 Tesla, 60 Hz of the coated steel samples were evaluated as well. The use of MgO containing strontium reduced the volume fraction of forsterite particles beneath the outermost ceramic layer. It was observed a reduced magnetic core loss with the use of the slurry with MgO containing strontium.

  5. INFLUENCE OF NaC1 DEPOSITION ON ATMOSPHERIC CORROSION OF A3 STEEL IN THE PRESENCE OF SO2

    Institute of Scientific and Technical Information of China (English)

    Q. Qu; C.W. Yan; L. Zhang; Y. Wan; C.N. Cao

    2002-01-01

    The regularities of atmospheric corrosion of A3 steel deposited with different amountof NaCl exposed to the air containing 1ppm SO2 at 80% RH and 25℃ were studied inlaboratory. NaCl can accelerate the corrosion of A3 steel obviously under such con-dition. The relationship between the weight loss of A3 steel and the amount of NaCldeposition can be well described by using a quadratic function. Fourier transform in-frared spectroscopy (FTIR), X-ray diffraction (XRD), Scanning electron microscopyand electron dispersion X-ray analysis (SEM/EDAX) were used to characterize thecorrosion products. In the absence of NaCl, FeSO4 xH2O is the dominant corro-sion products, while Fe3O4, FeSO4@ H2O, β-FeOOH and γ-FeOOH dominate in thepresence of NaCl.

  6. Influence of Alloy Content and Prior Microstructure on Evolution of Secondary Phases in Weldments of 9Cr-Reduced Activation Ferritic-Martensitic Steel

    Science.gov (United States)

    Thomas Paul, V.; Sudha, C.; Saroja, S.

    2015-08-01

    9Cr-Reduced Activation Ferritic-Martensitic steels with 1 and 1.4 wt pct tungsten are materials of choice for the test blanket module in fusion reactors. The steels possess a tempered martensite microstructure with a decoration of inter- and intra-lath carbides, which undergoes extensive modification on application of heat. The change in substructure and precipitation behavior on welding and subsequent thermal exposure has been studied using both experimental and computational techniques. Changes i.e., formation of various phases, their volume fraction, size, and morphology in different regions of the weldment due to prolonged thermal exposure was influenced not only by the time and temperature of exposure but also the prior microstructure. Laves phase of type Fe2W was formed in the high tungsten steel, on aging the weldment at 823 K (550 °C). It formed in the fine-grained heat-affected zone (HAZ) at much shorter durations than in the base metal. The accelerated kinetics has been understood in terms of enhanced precipitation of carbides at lath/grain boundaries during aging and the concomitant depletion of carbon and chromium and enrichment of tungsten in the vicinity of the carbides. Therefore, the fine-grained HAZ in the weldment was identified as a region susceptible for failure during service.

  7. Influence of a doping by Al stainless steel on kinetics and character of interaction with the metallic nuclear fuel

    Science.gov (United States)

    Nikitin, S. N.; Shornikov, D. P.; Tarasov, B. A.; Baranov, V. G.

    2016-04-01

    Metallic nuclear fuel is a perspective kind of fuel for fast reactors. In this paper we conducted a study of the interaction between uranium-molybdenum alloy and ferritic- martensitic steels with additions of aluminum at a temperature of 700 ° C for 25 hours. The rate constants of the interaction layer growth at 700 °C is about 2.8.10-14 m2/s. It is established that doping Al stainless steel leads to decrease in interaction with uranium-molybdenum alloys. The phase composition of the interaction layer is determined.

  8. Influence factors on stress corrosion cracking of P110 tubing steel under CO2 injection well annulus environment

    Institute of Scientific and Technical Information of China (English)

    刘然克; 贾静焕; 杜翠薇; 李晓刚

    2016-01-01

    Stress corrosion cracking (SCC) behavior of P110 tubing steel in simulated CO2 injection well annulus environments was investigated through three-point bent tests, potentiodynamic polarization and EIS measurements. The results demonstrate that SCC of P110 tubing steel could occur in acidulous simulated environment, and the sensitivity of SCC increases with the decrease of pH, as well as increase of sulfide concentration and total environmental pressure. Both anodic dissolution and hydrogen embrittlement make contributions to the SCC. Adequate concentration of corrosion inhibitor can inhibit the occurrence of SCC on account of the inhibition of localized anodic dissolution and cathodic hydrogen evolution.

  9. CHANGE OF CONNECTION BETWEEN MAGNETIC PARAMETERS OF CAST IRON IN COMPARISON WITH STEEL UNDER INFLUENCE OF INTERNAL DEMAGNETIZATION

    Directory of Open Access Journals (Sweden)

    S. G. Sandomirsky

    2014-01-01

    Full Text Available Connection of maximum magnetic permeability µm of cast irons with coercive force Нс and residual magnetism Мr is established in all size of changing of the magnetic characteristics of cast iron. Differences of this connection for steels and cast irons are revealed. Formula for calculation µm of steels by Нс and Мr is corrected for calculation µm of cast irons. As a result of correction the calculation error of cast irons µm is diminished. The results can be used in magnetic structural analysis instead of labor-consuming measurement µm.

  10. The influence of the cutting density on the magnetic properties of non-oriented electrical steels cut through mechanical punching and water jet technologies

    Science.gov (United States)

    Paltanea, V.; Paltanea, G.; Gavrila, H.; Popovici, D.; Jiga, G.

    2017-02-01

    The use of high quality non-oriented electrical steel and of an innovative design for the magnetic cores of the electrical machines are very important, in order to minimize the value of the total energy losses. The energy losses are strongly influenced by the cutting technologies, and the producers of the electrical machines want to minimize the deterioration of the magnetic properties during the manufacturing process. The influence of the cutting density on the magnetic permeability and energy losses was analyzed and one can notice that these magnetic properties are strongly influenced by the cutting technologies. There were tested sheet samples of M400-50A and M700-50A industrial steel grades (thickness of 0.50 mm), cut through mechanical and water jet technologies. All samples have the length equal to 300 mm and the width of 30, 15, 10, 7.5 and 5 mm. The magnetic characterization was performed using a laboratory single strip tester, which can make measurements on samples with an area of 300 × 30 mm2. In order to have the standard width of 30 mm, there were put together side by side 2, 3, 4 and 6 pieces with different widths. The magnetic properties were analyzed at 1000 mT in the frequency range 10 ÷ 400 Hz. It was observed that the processing conditions must be controlled and optimized, in order to maintain a low deterioration of the magnetic properties of the non-oriented steels. In the case of water jet technology an increase of the cutting speed will be useful for the introduction of this method in the large scale manufacturing of the electrical machines.

  11. Solubilization and stabilization Heat treatments influence on the susceptibility to intergranular corrosion in AISI-321 steel. Influencia de los tratamientos termicos de solubilizacion estabilizacion sobre la respuesta a la corrosion integranular del acero AISI-321

    Energy Technology Data Exchange (ETDEWEB)

    Fosca, C.; Salas, R.; Saenz, E.; Otero, E.

    1993-01-01

    The influence of heat treatments on the susceptibility to intergranular corrosion of AISI-321 steel is studied by using the EPR method (Electrochemical Potentiokinetic Reactivation). It is shown that a solubilization treatment at 1.373 K gives the material a better resistance against intergranular attach than higher temperatures treatments. A subsequent stabilization heat treatment at 1.073 K gives the best resistance against this type of corrosion to the studied steel. (Author) 12 refs.

  12. The Influence of Calcined Clay Pozzolan, Low-Cao Steel Slag and Granite Dust On the Alkali-Silica Reaction in Concrete

    OpenAIRE

    James Sarfo-Ansah; Eugene Atiemo

    2015-01-01

    The influence of low CaO steel slag, calcined clay and granite dust on the alkali-silica reaction was investigated over a period of 35 days under accelerated curing conditions. The mineral admixtures were used to replace varying portions of high alkali Portland limestone cement up to an admixture content of 25% in order to study their effect on the alkali-silica reaction (ASR). Portland limestone cement used for the study had a total Na2Oeq of 4.32. XRD analysis of hydrated mortar...

  13. Steel making

    CERN Document Server

    Chakrabarti, A K

    2014-01-01

    "Steel Making" is designed to give students a strong grounding in the theory and state-of-the-art practice of production of steels. This book is primarily focused to meet the needs of undergraduate metallurgical students and candidates for associate membership examinations of professional bodies (AMIIM, AMIE). Besides, for all engineering professionals working in steel plants who need to understand the basic principles of steel making, the text provides a sound introduction to the subject.Beginning with a brief introduction to the historical perspective and current status of steel making together with the reasons for obsolescence of Bessemer converter and open hearth processes, the book moves on to: elaborate the physiochemical principles involved in steel making; explain the operational principles and practices of the modern processes of primary steel making (LD converter, Q-BOP process, and electric furnace process); provide a summary of the developments in secondary refining of steels; discuss principles a...

  14. Influence of Different Surface Treatments of H13 Hot Work Die Steel on Its Thermal Fatigue Behaviors

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Thermal fatigue checking is the general failure of hot work die steels, which is relative with the structures and properties of the steels and the stress alternated during the employment. The Uddeholm test method on thermal fatigue is used to compare the behaviors of different samples, which are treated with plasma nitriding、plasma sulfur-carbon-nitriding、 boronizing or not treated. The results show that the nitriding improves the thermal fatigue property of the tool steel, while the plasma sulfur-carbon-nitriding and the boronizing impair the property. The mechanisms are induced as follows. By increasing the hardness and changing the stress distribution in the surface layer, surface treatment can decrease the plastic deformation and the tensile stress during the cycling. Therefore,the generation and growth of the cracks are restrained. On the other hand, as results of surface treating, in the surface layer the toughness declines and the expanding coefficient ascendes; the latter change caused the strengthening of the tensile and compressive stress during the cycling. Thus the resistance to thermal fatigue is weakened. Whether or not the surface treatment is favor to thermal fatigue of tool steels relies on which factor is dominant.

  15. Steel Spring

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    Tarnished Hebei Iron and Steel Group regains chance to shine A lthough it is too early to tell whether the steel-making sector has emerged [from its gloom, a big divide is openling between China’s large and small producers. While most of the marginal players are still reeling from a market contagion, steel titans like the Shanghai-based Baosteel

  16. Influence of Nitrided Layer on The Properties of Carbon Coatings Produced on X105CrMo17 Steel Under DC Glow-Discharge Conditions

    OpenAIRE

    Borowski, Tomasz; Ossowski, Maciej (OPI); Kowalczyk, Piotr; Maciej DUBEK; Agnieszka BROJANOWSKA; Krzysztof ROŻNIATOWSKI

    2016-01-01

    In most cases, machine components, which come in contact with each other, are made of steel. Common steel types include 100Cr6 and X105CrMo17 are widely used in rolling bearings, which are subjected to high static loads. However, more and more sophisticated structural applications require increasingly better performance from steel. The most popular methods for improving the properties of steel is carburisation or nitriding. Unfortunately, when very high surface properties of steel are require...

  17. The influence of adding corrosion inhibitor and pH on the electrochemical properties of hybrid films applied to galvanised steel

    Directory of Open Access Journals (Sweden)

    Sandra Raquel Kunst

    2012-10-01

    Full Text Available This study was aimed at coating galvanised steel with a hybrid film obtained from a sol consisting of silane precursors 3 - (trimetoxisil-ilpropil methacrylate (TMSPMA and tetraethoxysilane (TEOS. The pH of the hydrolysed-silane solution was 1 and 3. The influence of adding corrosion inhibitor (i.e. 0.01M cerium nitrate was evaluated for all samples. The hybrid films were deposited by dip-coating. The film was characterised scanning electron microscopy (SEM, profilometry, contact angle measurement, potentiodynamic polarisation and electrochemical impedance spectroscopy. The results showed that solution pH influenced hybrid film formation and final surface properties. Additionally, cerium nitrate as corrosion inhibitor addition enhances corrosion resistance of the films.

  18. Influence of the Surface Layer when the CMT Process Is Used for Welding Steel Sheets Treated by Nitrooxidation

    Directory of Open Access Journals (Sweden)

    I. Michalec

    2012-01-01

    Full Text Available Nitrooxidation is a non-conventional surface treatment method that can provide significantly improved mechanical properties as well as corrosion resistance. However, the surface layer is a major problem during the welding process, and welding specialists face many problems regarding the weldability of steel sheets. This paper deals with the properties of a nitrooxidized surface layer, and evaluates ways of welding steel sheets treated by nitrooxidation using a Cold Metal Transfer (CMT process. The limited heat input and the controlled metal transfer, which are considered as the main advantage of the CMT process, have a negative impact on weld joint quality. An excessive amount of porosity is observed,probably due to the high content of nitrogen and oxygen in the surface layer of the material and the fast cooling rate of the weld pool.

  19. The influence of heat treatment on properties of cold rolled alloyed steel and nickel superalloys sheets used in aircraft industry

    Science.gov (United States)

    Zaba, K.; Dul, I.; Puchlerska, S.

    2017-02-01

    Superalloys based on nickel and selected steels are widely used in the aerospace industry, because of their excellent mechanical properties, heat resistance and creep resistance. Metal sheets of these materials are plastically deformed and applied, inter alia, to critical components of aircraft engines. Due to their chemical composition these materials are hardly deformable. There are various methods to improve the formability of these materials, including plastic deformation at an elevated or high temperature, or a suitable heat treatment before forming process. The paper presents results of the metal sheets testing after heat treatment. For the research, sheets of two types of nickel superalloys type Inconel and of three types of steel were chosen. The materials were subjected to multivariate heat treatment at different temperature range and time. After this step, mechanical properties were examined according to the metal sheet rolling direction. The results were compared and the optimal type of pre-trial softening heat treatment for each of the materials was determined.

  20. Influence of / ratio on rate of chloride induced corrosion of steel reinforcement and its dependence on ambient temperature

    Indian Academy of Sciences (India)

    V Živica

    2003-08-01

    The permeability of the embedding cement material for the rate of chloride induced corrosion when the ambient temperature is increased has found a dominant position. The importance of the given permeability in the process is based on the fact that it represents a factor conditioning the possibility of the escaping of the unambiguous reaction partners, oxygen and water vapour, from the system embedding cement material-steel, as the ambient temperature is increased. The resulting effect is a slowing down of the corrosion rate when the / ratio over the value 0.6 and the ambient temperature over the value 40°C are increased. Due to the similarity of the chemism of the corrosion process of steel reinforcement, independent of the action of aggressive species, the found relationships are generally valid, e.g. for the corrosion due to carbonation.

  1. Influence of chemical bonding of chlorides with aluminates in cement hidratation process on corrosion steel bars in concrete

    OpenAIRE

    2010-01-01

    The presence of chlorides in concrete is a permanent subject of research because they cause corrosion of steel bars. Chlorides added to the concrete during preparation, as accelerators of the bonding of cement minerals process, enter into reaction with aluminates, creating a phase known as chloroaluminate hydrates. In everyday conditions the product of chemical bonding between chlorides and aluminates is usually monochloridealuminate C3A·CaCl2·Hx, better known as Friedel's salt. In this paper...

  2. Influence of Temperature on Typical Texture Distribution in Primary Recrystallization Matrix of 3% Si CGO Silicon Steel

    Directory of Open Access Journals (Sweden)

    Zhi-chao Li

    2016-01-01

    Full Text Available OM (optical microscopy and EBSD (electron backscatter diffraction techniques were used to study microstructure and texture distribution during primary recrystallization under different intermediate annealing temperatures in CGO silicon steels. The effect of intermediate annealing temperature on texture distribution in 3% Si electrical steel was analyzed. The results indicate that the microstructure in primary recrystallization matrix of CGO silicon steel is comprised of equiaxed ferrite grains. Mean grain size of primary recrystallization increases with the rising of intermediate annealing temperature. γ-fiber texture is the dominant component in primary recrystallization matrix. With higher intermediate annealing temperature, 111121 texture and 111110 texture increase and 111121 texture is stronger than 111110 texture. Goss texture was observed to be decreased firstly and then increased. The content of high angle grain boundaries in primary recrystallization matrix are affected by intermediate annealing temperature. When intermediate annealing temperature is increased, high angle grain boundaries are increased firstly and then decreased. Misorientation distribution in primary recrystallized matrix is affected by primary recrystallization annealing temperature either. The content of high angle grain boundaries are increased owing to higher primary recrystallization annealing temperature, which can be a benefit to the abnormal growth of Goss grains in secondary recrystallization.

  3. Influence of a Protective Coating Slurry on Enhancing the Descaling Ability and Oxidation Resistance of 9%Nickel Steel

    Institute of Scientific and Technical Information of China (English)

    HE Ying; WEI Lianqi; ZHANG Xiaomeng; ZHOU Xun; WANG Shuhua; SHAN Xin; YE Shufeng

    2014-01-01

    A kind of ceramic slurry was prepared and sprayed onto the surface of 9Ni steel at room temperature. The coating layer will not only reduce the depth of the formed Ni-enriched entanglement at high temperature but also have an excellent ability to resist oxidation of the 9Ni steel. Compared to bare specimen, the depths of the entanglement of the coated 9Ni specimen could be successfully reduced by 74.1%and the oxidation loss be decreased by 62.3% by heating at 1 250 ℃ for 60min. In addition, the coated specimen indicates no trace of oxide pegs. It proves that the coating has outstanding improvement to internal oxidation resistance. Some characterization methods such as metalloscopy, XRD, XPS, SEM and EDX have been used to reveal a possible protective mechanism. The result shows that the coating layer reacts with the iron oxide to form MgFe2O4 on the surface of the coated specimen, which could provide a smaller diffusion coefficient rate of Fe ion. The coating with a low cost and easy implementation is promisingly applicable in the slab-reheating process of the 9Ni steel.

  4. Use of an Electrochemical Split Cell Technique to Evaluate the Influence of Shewanella oneidensis Activities on Corrosion of Carbon Steel.

    Science.gov (United States)

    Miller, Robert Bertram; Sadek, Anwar; Rodriguez, Alvaro; Iannuzzi, Mariano; Giai, Carla; Senko, John M; Monty, Chelsea N

    2016-01-01

    Microbially induced corrosion (MIC) is a complex problem that affects various industries. Several techniques have been developed to monitor corrosion and elucidate corrosion mechanisms, including microbiological processes that induce metal deterioration. We used zero resistance ammetry (ZRA) in a split chamber configuration to evaluate the effects of the facultatively anaerobic Fe(III) reducing bacterium Shewanella oneidensis MR-1 on the corrosion of UNS G10180 carbon steel. We show that activities of S. oneidensis inhibit corrosion of steel with which that organism has direct contact. However, when a carbon steel coupon in contact with S. oneidensis was electrically connected to a second coupon that was free of biofilm (in separate chambers of the split chamber assembly), ZRA-based measurements indicated that current moved from the S. oneidensis-containing chamber to the cell-free chamber. This electron transfer enhanced the O2 reduction reaction on the coupon deployed in the cell free chamber, and consequently, enhanced oxidation and corrosion of that electrode. Our results illustrate a novel mechanism for MIC in cases where metal surfaces are heterogeneously covered by biofilms.

  5. Influence of hydroxyis, carbonates and chiorides ions on the pitting corrosión of steel in concrete

    Directory of Open Access Journals (Sweden)

    Chaussadent, Thierry

    1992-06-01

    Full Text Available The electrochemical process of steel corrosion in concrete are studied by simulating its liquid phase with synthetical solutions in a large range of hydroxyls, carbonates and chlorides ions.The steel specimen is either under or without an electrical polarization. The present analysis has made it possible to define a new relevant parameter, which is the [CΓ]/[AIK] ratio (where AIK is the total alkalinity. It characterizes the conditions of the polarized steel pitting corrosion. Furthermore, the investigation showed out that a polarization at potentials lower than — 700 mVSCE, stops the corrosion processes.

    Los procesos electroquímicos de corrosión de las armaduras de acero del hormigón son estudiados simulando su fase líquida mediante disoluciones sintéticas que cubren playas importantes en iones hidróxilos, carbonates y cloruros. El acero está sometido o no a una polarización eléctrica. Este análisis ha permitido definir un nuevo parámetro significativo, la relación [CΓ]/[AIK] (siendo AIK la alcalinidad total, que caracteriza las condiciones de corrosión por picaduras del acero polarizado. Además, el estudio ha mostrado que una polarización, a un potencial más bajo que — 700 mVSCE impide los mecanismos de corrosión.

  6. Special steel production on common carbon steel production line

    Science.gov (United States)

    Pi, Huachun; Han, Jingtao; Hu, Haiping; Bian, Ruisheng; Kang, Jianjun; Xu, Manlin

    2004-06-01

    The equipment and technology of small bar tandem rolling line of Shijiazhuang Iron & Steel Co. in China has reached the 90's international advanced level in the 20th century, but products on the line are mostly of common carbon steel. Currently there are few steel plants in China to produce 45 steel bars for cold drawing, which is a kind of shortage product. Development of 45 steel for cold drawing has a wide market outlook in China. In this paper, continuous cooling transformation (CCT) curve of 45 steel for cold drawing used for rolling was set out first. According to the CCT curve, we determined some key temperature points such as Ac3 temperature and Ac1 temperature during the cooling procedure and discussed the precipitation microstructure at different cooling rate. Then by studying thermal treatment process of 45 steel bars for cold drawing, the influence of cooling time on microstructure was analyzed and the optimum cooling speed has been found. All results concluded from the above studies are the basis of regulating controlled cooling process of 45 steel bars for cold drawing. Finally, the feasible production process of 45 steel bars for cold drawing on common carbon steel production line combined with the field condition was recommended.

  7. Some peculiarities of corrosion of wheel steel

    Directory of Open Access Journals (Sweden)

    Alexander SHRAMKO

    2009-01-01

    Full Text Available Corrosion mechanism and rate of different chemical composition and structural condition of wheel steel were investigated. It was shown that “white layers”, variation in grain size and banding of wheel steel structure results in corrosion rate. Microstructure of steel from different elements of railway wheels after operation with corrosion was investigated. Wheel steel with addition of vanadium corroded more quickly than steel without vanadium. Non-metallic inclusions are the centre of corrosion nucleation and their influence on corrosion depends on type of inclusion. Mechanism of corrosion of wheel steel corrosion was discussed.

  8. Influence of Cutting Parameters on Chatter and Tool Wear During End Milling of Stainless Steel Conducted on VMC

    Directory of Open Access Journals (Sweden)

    A.K.M.N. AMIN, M. IMRAN AND M. ARIF

    2012-09-01

    Full Text Available Stainless steels are a group of difficult to machine work materials. The difficulty in machining stainless steels is manifested in high contact length and stresses, formation of serrated chips and development of chatter resulting in high tool wear rates and poor machined surface finish. The paper focuses on the performance of TiN coated-carbide inserts in machining stainless steel specimens in end milling operation performed on vertical machining centre (VMC. The performance of the tool is evaluated from the point of view of its wear intensity, mechanism of failure and generation and effect of chatter on tool wear and vice versa. The investigations were aimed at determining the effect of cutting parameters, specifically cutting speed, feed and depth of cut, on chatter amplitude, tool wear rate, mechanism of tool wear and using these data and machined surface roughness values from previous work to come up with recommended values of cutting parameters for semi-finish and finish end milling operation of stainless steel work materials. For recording vibration signals a dual channel portable signal analyzers was used and the signals were analyzed using Pulse Multi-analyzer version 4.2 software. Tool wear was measured using an optical microscope with digital readout capabilities along 3 axes. The tool wear mechanisms were studied under a scanning electron microscope (SEM. Results of the investigation show that acceleration amplitudes generally increase with cutting speed and the magnitude of tool flank wears. It has been also found that an increase in feed and depth of cut leads to higher acceleration amplitudes. The most common wear mechanisms observed during machining of stainless steel are attrition, micro and macro chipping of the tool at lower cutting speeds, and diffusion and mechanical failures due to intensive chatter at higher speeds. It has been also established that stable cutting speeds with relatively low tool wear intensity and

  9. INCREASE STRUCTURAL STRENGTH OF MARGANESE STEEL

    Directory of Open Access Journals (Sweden)

    L. N. Bunina

    2011-04-01

    Full Text Available The manganese steels are widely used in machinery construction. The influence of chemical composition and form of non-metallic inclusions on constructive strength of manganese steels is studied. The dependences between the nature of non-metallic inclusions and properties of steels are given.

  10. Study on influencing factors of Carbon Steel Corrosion in Anhydrous Hydrogen Fluoride Production%AHF生产混合段腐蚀影响因素的研究

    Institute of Scientific and Technical Information of China (English)

    蔡荣秋; 林整

    2011-01-01

    The main factors influencing corrosion of carbon steel are studied by weight loss, linear polarization and polarization curves methods in this study. The results show that the corrosion rate of specimen decreased with reducing temperature and the impurity content. The carbon steel can passivate in some proportion between fluorite and sulfuric acid. The corrosion rate of carbon steel is more serious in the first 4 minutes of reaction.%本文分别采用挂片失重法、线性极化法、极化曲线法研究了反应温度、物料配比、反应时间、萤石中所含杂质等因素对碳钢在萤石-硫酸体系中的腐蚀影响,结果表明:降低反应温度、控制杂质含量在一个较低水平都可以有效的降低碳钢的腐蚀速率;增加物料配比中硫酸的比例,会导致碳钢出现某种程度的钝化;碳钢在萤石-硫酸体系中的腐蚀存在着一个严重腐蚀阶段,在本文的实验条件下,该阶段为物料开始反应的前4分钟。

  11. Tool steels

    DEFF Research Database (Denmark)

    Højerslev, C.

    2001-01-01

    On designing a tool steel, its composition and heat treatment parameters are chosen to provide a hardened and tempered martensitic matrix in which carbides are evenly distributed. In this condition the matrix has an optimum combination of hardness andtoughness, the primary carbides provide...... resistance against abrasive wear and secondary carbides (if any) increase the resistance against plastic deformation. Tool steels are alloyed with carbide forming elements (Typically: vanadium, tungsten, molybdenumand chromium) furthermore some steel types contains cobalt. Addition of alloying elements...

  12. The Influence of Heat Treatment Time and Temperature on the Physical Properties of Assab-Corax Steel

    Directory of Open Access Journals (Sweden)

    A.K. Jahja

    2005-07-01

    Full Text Available X-ray diffraction experiment was carried out on commercial Assab-Corax steel sample. The polished samples are then heated to various temperature for different holding time; 200 oC for 4 hours, 300 oC for 4 hours, 400oC for 6-, 8-, 12- and 16 hours, 500 oC for 4 hours and 600 oC for 4 hours. The refinement of the diffraction intensity was carried out using the Im3m model, and the results show that the Carbon atoms are distributed among the base position in the body centered cubic unit cell at the eight-fold octahedral interstitial sites. Using the refined structural parameters, thermo-physical properties such as Debye temperature and coefficient of thermal expansion are calculated. From the results of the analysis it could be concluded that Debye temperature in Assab-Corrax steels tend to decrease with increasing heat-treatment time but tend to increase with heat treatment temperature. The coefficients of linear expansion also tend to decrease with increasing heat-treatment time and tend to increase with heat treatment temperature. Although the patterns are different, for example when the Debye temperature reaches its peak value for heat treatment time of 8 hours, the coefficient of linear expansion would reach its low point at this time. Therefore, the general finding is that both treatment-temperature and – time are influential to the physical properties of Assab-Corrax steels and x-ray diffraction methods could be utilized in elucidating these important findings.

  13. The Influence of Aluminum Tripolyphosphate on the Protective Behavior of an Acrylic Water-Based Paint Applied to Rusty Steels

    Directory of Open Access Journals (Sweden)

    Dongdong Song

    2015-01-01

    Full Text Available The protective performance, in conditions of total immersion, of an acrylic water-based paint applied to rusty steel, has been studied using electrochemical techniques. There was no rust, blister, crack, or flake that occurred on coating after 500 h immersion. The data obtained have enabled the protective mechanism to be proposed. The specific pigments utilized in the formulation of the paint studied can release phosphates to form a protective layer on metal substrate, which can impede the access of aggressive species to substrate surface. The coatings performed electrochemical activity in the beginning of immersion; then the layer formed and resistance of coating increased.

  14. Experiments on different materials (polyamide, stainless & galvanized steel) influencing geothermal CaCO3 scaling formation: Polymorphs & elemental incorporation

    Science.gov (United States)

    Wedenig, Michael; Dietzel, Martin; Boch, Ronny; Hippler, Dorothee

    2016-04-01

    Thermal water is increasingly used for heat and electric power production providing base-load capable renewable and virtually unlimited geothermal energy. Compared to other energy sources geothermal facilities are less harmful to the environment, i.e. chemically and visually. In order to promote the economic viability of these systems compared to other traditional and renewable energy sources, production hindering processes such as corrosion and scaling of components arising from the typically high salinity thermal waters have to be considered as important economic factors. In this context, using proper materials being in contact with the thermal water is crucial and a playground for further improvements. Aim of the study presented, are basic experiments and observations of scaling and corrosive effects from hydrothermal water interacting with different materials and surfaces (stainless steel, polyamide, galvanized steel) and in particular the nucleation and growth effects of these materials regarding the precipitation of solid carbonate phases. The incorporation of Mg, Sr and Ba cations into the carbonate scalings are investigated as environmental proxy. For this purpose, hydrothermal carbonate precipitating experiments were initialized by mixing NaHCO3 and Ca-Mg-Sr-Ba-chloride solutions at temperatures ranging from 40 to 80 °C in glass reactors hosting artificial substrates of the above mentioned materials. The experiments show a strong dependence of the precipitation behaviour of calcium carbonate polymorphs on the particular material being present. Stainless steel and polyamide seem to restrict aragonite formation, whereas galvanized steel supports aragonite nucleation. Vaterite formation is promoted by polyamide surfaces. Importantly, vaterite is more soluble (less stable) compared to the other anhydrous calcium carbonate polymorphs, i.e. vaterite can be more easily re-dissolved. Thus, the use of polyamide components might reduce the amount and durability of

  15. Influence of Cooling Conditions on a Slab’s Chill Zone Formation During Continuous Casting of Steel

    Directory of Open Access Journals (Sweden)

    Drożdż P.

    2017-06-01

    Full Text Available The cooling conditions of a slab during continuous casting of steel have an impact on the crystalline structure formation. Numerical methods allow real processes to be modelled. Professional computer programs are available on the market, so the results of their simulations allow us to understand the processes that occur during the casting and solidification of the slab. The study attempts to evaluate the impact of the intensity of the secondary cooling on the chilled zone size. The calculations show the differences in the structure of a slab cast with various speeds while maintaining industrial cooling parameters during operation of a continuous casting machine.

  16. Steels in interaction with liquid metals: a review; L'influence des metaux liquides sur les aciers inoxydables

    Energy Technology Data Exchange (ETDEWEB)

    Auger, T. [ECP/MSSMAT, UMR CNRS 8579, Grande voie des vignes, 92290 Chatenay-Malabry, (France)

    2011-07-01

    Liquid metals are envisaged for various nuclear applications ranging from spallation neutron sources to future fission and fusion reactors. A fair amount of current research is dedicated to the investigation of the interaction of steels, the only structural materials compatible at long term with liquid metals such as the eutectic lead-bismuth or sodium. The aging problems for these materials are corrosion, wettability and liquid metal induced embrittlement. This review recalls some of the key factors in the understanding of these problems. (authors)

  17. The specific heat loss combined with the thermoelastic effect for an experimental analysis of the mean stress influence on axial fatigue of stainless steel plain specimens

    Directory of Open Access Journals (Sweden)

    G. Meneghetti

    2014-10-01

    Full Text Available The energy dissipated to the surroundings as heat in a unit volume of material per cycle, Q, was recently proposed by the authors as fatigue damage index and it was successfully applied to correlate fatigue data obtained by carrying out fully reversed stress- and strain-controlled fatigue tests on AISI 304L stainless steel plain and notched specimens. The use of the Q parameter to analyse the experimental results led to the definition of a scatter band having constant slope from the low- to the high-cycle fatigue regime. In this paper the energy approach is extended to analyse the influence of mean stress on the axial fatigue behaviour of unnotched cold drawn AISI 304L stainless steel bars. In view of this, stress controlled fatigue tests on plain specimens at different load ratios R (R=-1; R=0.1; R=0.5 were carried out. A new energy parameter is defined to account for the mean stress effect, which combines the specific heat loss Q and the relative temperature variation due to the thermoelastic effect corresponding to the achievement of the maximum stress level of the stress cycle. The new two-parameter approach was able to rationalise the mean stress effect observed experimentally. It is worth noting that the results found in the present contribution are meant to be specific for the material and testing condition investigated here.

  18. The Influence of Lath, Block and Prior Austenite Grain (PAG Size on the Tensile, Creep and Fatigue Properties of Novel Maraging Steel

    Directory of Open Access Journals (Sweden)

    Thomas Simm

    2017-06-01

    Full Text Available The influence of martensitic microstructure and prior austenite grain (PAG size on the mechanical properties of novel maraging steel was studied. This was achieved by looking at two different martensitic structures with PAG sizes of approximately 40 µm and 80 µm, produced by hot rolling to different reductions. Two ageing heat-treatments were considered: both heat-treatments consisted of austenisation at 960 °C, then aging at 560 °C for 5 h, but while one was rapidly cooled the other was slow cooled and then extended aged at 480 °C for 64 h. It is shown that for the shorter ageing treatment the smaller PAG size resulted in significant improvements in strength (increase of more than 150 MPa, ductility (four times increase, creep life (almost four times increase in creep life and fatigue life (almost doubled. Whereas, the extended aged sample showed similar changes in the fatigue life, elongation and hardness it displayed yet showed no difference in tensile strength and creep. These results display the complexity of microstructural contributions to mechanical properties in maraging steels.

  19. 雪荷载对轻钢结构的影响及提高措施%On influence of snow load on light steel structure and its improvement measures

    Institute of Scientific and Technical Information of China (English)

    诸葛文秀

    2011-01-01

    结合GB 50009-2001建筑结构荷载规范和美国规范相关规定,探讨了雪荷载的取值及其对轻钢结构的影响,提出了提高轻钢结构安全性的具体措施,并以具体项目为例进行了阐述,以期指导今后轻钢结构设计。%Combining with GB 50009-2001 Architectural Structure Loading Regulation and relative rule of American standard,the paper explores the influence of evaluation of snow load and its influence on light steel structure,points out the factual measures for improving the safety of the light steel structure,and illustrates the factual engineering projects,so as to direct the design of future light steel structure.

  20. The Influence of Austenite Grain Size on the Mechanical Properties of Low-Alloy Steel with Boron

    Directory of Open Access Journals (Sweden)

    Beata Białobrzeska

    2017-01-01

    Full Text Available This study forms part of the current research on modern steel groups with higher resistance to abrasive wear. In order to reduce the intensity of wear processes, and also to minimize their impact, the immediate priority seems to be a search for a correlation between the chemical composition and structure of these materials and their properties. In this paper, the correlation between prior austenite grain size, martensite packets and the mechanical properties were researched. The growth of austenite grains is an important factor in the analysis of the microstructure, as the grain size has an effect on the kinetics of phase transformation. The microstructure, however, is closely related to the mechanical properties of the material such as yield strength, tensile strength, elongation and impact strength, as well as morphology of occurred fracture. During the study, the mechanical properties were tested and a tendency to brittle fracture was analysed. The studies show big differences of the analysed parameters depending on the applied heat treatment, which should provide guidance to users to specific applications of this type of steel.

  1. Plasma immersion ion implantation on 15-5PH stainless steel: influence on fatigue strength and wear resistance

    Science.gov (United States)

    Bonora, R.; Cioffi, M. O. H.; Voorwald, H. J. C.

    2017-05-01

    Surface improvement in steels is of great interest for applications in industry. The aim of this investigation is to study the effect of nitrogen ion implantation on the axial fatigue strength and wear resistance of 15-5 PH stainless steel. It is well know that electroplated coatings, which are used to improve abrasive wear and corrosion properties, affects negatively the fatigue strength. It is also important to consider requirements to reduce the use of coated materials with electroplated chromium and cadmium, that produce waste, which is harmful to health and environment. The HVOF (High velocity oxygen fuel) process provides hardness, wear strength and higher fatigue resistance in comparison to electroplated chromium. Plasma immersion ion implantation has been used to enhance the hardness, wear, fatigue and corrosion properties of metals and alloys. In the present research the fatigue life increased twice for 15-5 PH three hours PIII treated in comparison to base material. From the abrasive wear tests a lower pin mass reduction was observed, associated to the superficial treatments. The improvement of fatigue and mechanical performance is attributed to a combination of nitrides phase structure and compressive residual stresses during the PIII treatment.

  2. The influence of chromium on the pearlite-austenite transformation kinetics of the Fe–Cr–C ternary steels

    Energy Technology Data Exchange (ETDEWEB)

    Kong, Lingnan; Liu, Yaohui, E-mail: liuyaohui2005@126.com; Liu, Jia' an; Song, Yulai; Li, Shasha; Zhang, Renhang; Li, Tuanjie; Liang, Yan

    2015-11-05

    The Fe–Cr–C ternary steels containing different contents of Cr were successfully cast and further processed in the lab. Differential scanning calorimetry (DSC), optical microscope (OM), and scanning electron microscope (SEM) were employed to investigate the transformation of the Fe–Cr–C ternary steels from pearlite to austenite. It is found that the values of Ac1 and Ac3 are raised with increase in the content of Cr. In addition, the information on the transformation kinetics was obtained from experiment results and the Johnson-Mehl-Avrami-Kolmogorov model (JMAK). The obtained austenitic transformation kinetic process has been described in three overlapping steps: site saturation nucleation, diffusion-controlled growth, and impingement correction. The pre-exponential factor for diffusion decreases firstly and then increases. The activation energy for diffusion increases with the Cr content. In addition, Cr strongly affects the effective diffusion distance, the austenite nucleation sites, and the carbon activity gradient during the austenitic transformation kinetic process. - Highlights: • The pearlite-austenite transformation kinetics is researched by DSC. • The transformation kinetics is analyzed by experiment results and the JMAK model. • The activation energy and the diffusion coefficient are discussed.

  3. Influence of pre-deformation, sensitization and oxidation in high temperature water on corrosion resistance of AISI 304 stainless steel

    Energy Technology Data Exchange (ETDEWEB)

    Lv, Jinlong, E-mail: ljltsinghua@126.com [Beijing Key Laboratory of Fine Ceramics, Institute of Nuclear and New Energy Technology, Tsinghua University, Zhongguancun Street, Haidian District, Beijing 100084 (China); State Key Lab of New Ceramic and Fine Processing, Tsinghua University, Beijing 100084 (China); Liang, Tongxiang [Beijing Key Laboratory of Fine Ceramics, Institute of Nuclear and New Energy Technology, Tsinghua University, Zhongguancun Street, Haidian District, Beijing 100084 (China); State Key Lab of New Ceramic and Fine Processing, Tsinghua University, Beijing 100084 (China); Luo, Hongyun [Key Laboratory of Aerospace Materials and Performance (Ministry of Education), School of Materials Science and Engineering, Beijing University of Aeronautics and Astronautics, Xueyuan Road 37, Beijing 100191 (China)

    2016-12-01

    Highlights: • The pre-strain accelerated desensitization and sensitization for austenitic stainless steels. • Low temperature sensitization (carbide precipitation) induced α′-martensite. • The sensitization level could affect directly corrosion resistance of the oxide film. - Abstract: The effects of pre-deformation on sensitization of AISI 304 stainless steel were investigated by the double loop electrochemical potentiokinetic reactivation test. The effects of pre-deformation and sensitization on high temperature oxidized film formed in high temperature water were analyzed by a XRD and SEM. The electrochemical impedance spectroscopy at room temperature was used to study corrosion resistance of oxidized film. The point defect density of oxidized film was calculated by Mott–Schottky plots. The results showed that the value of the degree of sensitization first decreased and then slight increased with the increasing of engineering strain. Moreover, low temperature promoted to form sensitization induced “secondary” α′-martensite. The sample with 20% engineering strain had higher impedance value than other samples. The result was supported by further Mott–Schottky experiments. Considering increased α′-martensite with the increasing of strain, the results of the impedance were more consistent with values of the degree of sensitization.

  4. Influence of local mechanical properties of high strength steel from large size forged ingot on ultrasonic wave velocities

    Science.gov (United States)

    Dupont-Marillia, Frederic; Jahazi, Mohamad; Lafreniere, Serge; Belanger, Pierre

    2017-02-01

    In the metallurgical industry, ultrasonic inspection is routinely used for the detection of defects. For the non-destructive inspection of small high strength steel parts, the material can be considered isotropic. However, when the size of the parts under inspection is large, the isotropic material hypothesis does not necessarily hold. The aim of this study is to investigate the effect of the variation in mechanical properties such as grain size, Young's modulus, Poissons ratio, chemical composition on longitudinal and transversal ultrasonic wave velocities. A 2 cm thick slice cut from a 40-ton bainitic steel ingot that was forged and heat treated was divided into 875 parallelepiped samples of 2x4x7 cm3. A metallurgical study has been performed to identify the phase and measure the grain size. Ultrasonic velocity measurements at 2.25 MHz for longitudinal and transversal waves were performed. The original location of the parallelepiped samples in the large forged ingot, and the measured velocities were used to produce an ultrasonic velocity map. Using a local isotropy assumption as well as the local density of the parallelepiped samples calculated from the chemical composition of the ingot provided by a previously published study, Youngs modulus and Poissons ratio were calculated from the longitudinal and transversal wave velocities. Micro-tensile test was used to validate Youngs modulus obtained by the ultrasonic wave velocity and an excellent agreement was observed.

  5. The influence of the arc plasma treatment on the structure and microhardness 100Cr6 bearing steel

    Directory of Open Access Journals (Sweden)

    W. Bochnowski

    2010-04-01

    Full Text Available The effect of arc plasma treatment on structure and microhardness of 100Cr6 steel was investigated. Four different the current intensity has been used to remelting surface of the steel. SEM and LM microscopes have been used to evaluate microstructure of remelted zone (RZ. In the remelting zone (RZ were obtained characteristic for rapid crystallization process the dendritic cell structure. Inside the dendritic cells in dependency to current intensity of arc, the martensite or bainite and retained austenite was observed. On the boundaries of the dendritic cells as a result of segregation of C and Cr the alloyed cementite is formed. The cooling rate of the remelted zone is higher than the cooling rate obtained in the classical heat treatment. The maximum hardness 840 HV0,1 was measured in material after treatment with a smaller current intensity of arc plasma – 60A. Increases of the current intensity of arc plasma from 60 A to 110 A (for fixed speed rate of source lead to increases the depth of the remelted zone from 1,5 to 2,3 mm.

  6. Influence of Cold-Sprayed, Warm-Sprayed, and Plasma-Sprayed Layers Deposition on Fatigue Properties of Steel Specimens

    Science.gov (United States)

    Cizek, J.; Matejkova, M.; Dlouhy, I.; Siska, F.; Kay, C. M.; Karthikeyan, J.; Kuroda, S.; Kovarik, O.; Siegl, J.; Loke, K.; Khor, Khiam Aik

    2015-06-01

    Titanium powder was deposited onto steel specimens using four thermal spray technologies: plasma spray, low-pressure cold spray, portable cold spray, and warm spray. The specimens were then subjected to strain-controlled cyclic bending test in a dedicated in-house built device. The crack propagation was monitored by observing the changes in the resonance frequency of the samples. For each series, the number of cycles corresponding to a pre-defined specimen cross-section damage was used as a performance indicator. It was found that the grit-blasting procedure did not alter the fatigue properties of the steel specimens (1% increase as compared to as-received set), while the deposition of coatings via all four thermal spray technologies significantly increased the measured fatigue lives. The three high-velocity technologies led to an increase of relative lives to 234% (low-pressure cold spray), 210% (portable cold spray), and 355% (warm spray) and the deposition using plasma spray led to an increase of relative lives to 303%. The observed increase of high-velocity technologies (cold and warm spray) could be attributed to a combination of homogeneous fatigue-resistant coatings and induction of peening stresses into the substrates via the impingement of the high-kinetic energy particles. Given the intrinsic character of the plasma jet (low-velocity impact of semi/molten particles) and the mostly ceramic character of the coating (oxides, nitrides), a hypothesis based on non-linear coatings behavior is provided in the paper.

  7. INFLUENCE OF PLASMA NITRIDING ON THE CORROSION BEHAVIOUR AND ADHESION OF DLC COATINGS DEPOSITED ON AISI 420 STAINLESS STEEL

    Directory of Open Access Journals (Sweden)

    Jorge N. Pecina

    2016-06-01

    Full Text Available In this work the corrosion behavior and adhesion of two DLC (“Diamond Like Carbon” films (“Soft” and “Hard” were studied. Both coatings were deposited by PACVD (“Plasma Assisted Chemical Vapour Deposition” on plasma-nitrided and non-nitrided AISI 420 stainless steel. Raman spectroscopy was conducted and surface hardness was measured. The microstructure by OM and SEM, was observed. Adhesion tests were performed with C. Rockwell indentation test. Salt Spray and immersion were performed in HCl. The “Soft” coating was 20 μm thick, the “Hard” film was about 2.5 μm. The hardness was of 500 HV in the “Soft” DLC and 1400 HV in the “Hard” DLC. Both coatings presented low friction coefficient and good adhesion when they were deposited on nitrided steel. Also presented good resistance to atmospheric corrosion. HCl DLC degradation slowed rapidly introduced uncoated samples.

  8. Influence of Carbide Morphology and Microstructure on the Kinetics of Superficial Decarburization of C-Mn Steels

    Science.gov (United States)

    Alvarenga, Henrique Duarte; De Putte, Tom Van; Van Steenberge, Nele; Sietsma, Jilt; Terryn, Herman

    2015-01-01

    Decarburization is an important process during the heat treatment of steels. It can be divided into three separated events: dissolution of carbides, diffusion of carbon through the iron matrix, and surface reactions. The process is very sensitive to temperature. During intercritical annealing, austenite nucleates in the cementite-ferrite interface and grows at the rate determined by the diffusion of carbon in austenite. The presence of a decarburizing atmosphere during annealing guides the carbon diffusion in ferrite toward the surface, generating a flux of carbon from austenite toward ferrite, disturbing the austenite growth. In the presence of pearlite, the ferrite-austenite interface can be assumed to remain static until pearlite is completely dissolved, reducing then the carbon flux in austenite, consequently diminishing the austenite formation rate. At intercritical temperatures, the cementite-free ferrite layer at the surface reaches a greater width due to the combination of the thermodynamic fraction of austenite, dissolution rate of cementite, and the diffusivity of carbon in austenite and ferrite. In this study, an experimental investigation of the effects of the carbide morphology and distribution and the phase transformation in the decarburization kinetics on hypo-eutectoid steels is presented. It is suggested that the change of the dissolution kinetics of the carbides due to its morphology will affect the austenitization kinetics. Thus, the distribution of the carbon in the microstructure may determine the rate of decarburization in combination with the carbon diffusion through the phases or the gas-metal reactions.

  9. The influence of active screen plasma nitriding parameters on corrosion behavior of a low-alloy steel

    Energy Technology Data Exchange (ETDEWEB)

    Ahangarani, Sh., E-mail: ahangarani@irost.i [Department of Advanced Materials and Renewable Energies, Iranian Research Organization for Science and Technology (IROST), P.O. Box 15815-3538, Tehran (Iran, Islamic Republic of); Sabour, A.R. [Department of Materials Engineering, Tarbiat Modarres University, Tehran (Iran, Islamic Republic of); Mahboubi, F. [Department of Mining and Metallurgical Engineering, Amirkabir University of Technology, Tehran (Iran, Islamic Republic of); Shahrabi, T. [Department of Materials Engineering, Tarbiat Modarres University, Tehran (Iran, Islamic Republic of)

    2009-09-18

    This work presents a comparative study of low-alloy steel nitriding for different possible techniques. Active screen plasma nitriding (ASPN) is a successful surface modification method that has many advantages over the conventional DC plasma nitriding (CPN). The corrosion behavior of 30CrNiMo8 low-alloy steel has been examined using anodic polarization tests in 3.5% NaCl solution under varying conditions of ASPN and CPN processes. The process variables included active screen setup parameters, treatment temperature (550 and 580 deg. C), gas mixture (25/75 and 75/25 of N{sub 2}/H{sub 2}) and treatment time (5 and 10 h) in 500 Pa pressure. The structure and phases composition of the compound layer was studied by X-ray diffraction (XRD), microhardness tests, optical microscopy and scanning electron microscopy (SEM). It was observed that ASPN treated samples surface enhanced corrosion resistance while the temperature and/or hole size of screen setup increased.

  10. The influence of nano-Al{sub 2}O{sub 3} additive on the adhesion between enamel and steel substrate

    Energy Technology Data Exchange (ETDEWEB)

    Ling Guoping; He Junhui

    2004-08-15

    The influence of Al{sub 2}O{sub 3} nanoparticles on the adhesion between Sb-Mo, NiO enamels, and steel substrate has been investigated. The results of press test indicated that the adhesion strength was greatly improved by addition of Al{sub 2}O{sub 3} nanoparticles into enamel frit. Scanning electronic microscope (SEM) revealed that the amount of dendrite increases in the interface and meanwhile its average size decreases. The energy dispersive X-ray (EDS) analysis identified the existence of Al in the dendrite, which confirmed that the nano-Al{sub 2}O{sub 3} additives were closely related to the change of interface morphology and the improvement of adhesion strength. The reason for adhesion improvement was discussed as well.

  11. INFLUENCE OF COOLING RATE DURING QUENCHING ON IMPACT TOUGHNESS OF A HOT-WORK TOOL STEEL AT AMBIENT TEMPERATURE AND AT 200 °C

    Directory of Open Access Journals (Sweden)

    Henrik Jesperson

    2013-05-01

    Full Text Available Gross cracking of die-casting dies with inferior toughness sometimes occurs through too low preheating temperature and/or too slow cooling during quenching. This study aimed to clarify the influence of cooling rate on the toughness of the hot-work tool steel grade Uddeholm Vidar Superior at ambient temperature and at 200 °C, a typical preheating temperature for aluminium die-casting dies. Toughness was measured through instrumented Charpy V-notch impact testing. The decrease in energy absorption with increasing cooling time between 800°C and 500°C both at both ambient temperature and 200 °C was pronounced. At ambient temperature, the decrease in total energy was a consequence of a decrease in initiation energy whereas, at 200 °C, the decrease in total energy was due to a decrease in propagation energy.

  12. Steel Planning

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    China releases a new plan for the iron and steel industry centered on industrial upgrades The new 12th Five-Year Plan (2011-15) for China’s iron and steel industry, recently released on the website of the Ministry of Industry and Information

  13. Influence of shielding gas composition on weld profile in pulsed Nd:YAG laser welding of low carbon steel

    Directory of Open Access Journals (Sweden)

    M Jokar

    2014-12-01

    Full Text Available Weld area and weld depth/width ratio can be considered to be of the most important geometrical factors in pulsed laser welding. The effects of carbon dioxide and oxygen additions to the argon shielding gas on the weld properties in pulsed laser welding of low carbon steel is investigated. Presence of carbon dioxide and oxygen up to 10 and 15 percent respectively decreases the weld geometrical factors. But, at higher levels of additions, the weld geometrical factors will increase. It is observed that the plasma plume temperature decreases from 6000K to 5500K with the addition of 15% carbon dioxide but increases to 7700K with 25% carbon dioxide addition. Increase in laser absorption coefficient, laser energy absorption, formation of oxide layer on the work-piece surface, exothermic reactions and their competitive effects can be considered as the competing phenomena involved in such a behavior in the weld profile

  14. Influence of different thermal treatment in sintered steels base molybdenum; Influencia de diferentes tratamientos termoquimicos en aceros sinterizados base molibdeno

    Energy Technology Data Exchange (ETDEWEB)

    Candela, N.; Plaza, R.; Ruiz-Amador, D.; Velasco, F.; Torralba, J. M.

    2001-07-01

    Prealloyed steel powders with different amount of Mo-Cu-Ni-C were compacted at 700 MPa and sintered at 1120 degree centigree in 95% N{sub 2} -5% H{sub 2}. After sinterizing, these materials were treated by carburizing. For materials characterization radial crushing strength were preformed, density was calculated and a complete study of fracture surfaces was carried out using scanning electron microscopy. The results of radial crushing strength show that resistance after carburizing is higher than in sintered materials. The fracture surfaces give an idea of materials briteless and the treatment depth. In sintered materials, a ductil surface was observed, with the characteristic dimples. The fracture surfaces after different treatments show brittleness in the outer zone, while appears a mix of ductil and briteless fracture. (Author) 7 refs.

  15. The influence of lubricant carrier and lubrication conditions on mechanical-technological properties of high carbon steel wires

    Directory of Open Access Journals (Sweden)

    M. Suliga

    2016-10-01

    Full Text Available In this paper the effect of the type of soap powder and lubricant carriers on lubrication conditions in multipass drawing process of high carbon steel wires has been determined. The wire drawing process was conducted in industrial conditions by means of a modern multi-die Koch drawing machine. For wires drawn on borax and phosphate lubricant carriers the mechanical-technological properties have been carried out, in which yield stress, tensile strength, uniform elongation, number of twists and number of bends were assessed. It has been proved that the application of phosphate lubricant carrier and also the rotary die in the first draft in an essential way improve the lubrication condition in high speed multipass drawing process and makes it possible to refine the mechanical properties of wires.

  16. The influence of nanostructured features on bacterial adhesion and bone cell functions on severely shot peened 316L stainless steel.

    Science.gov (United States)

    Bagherifard, Sara; Hickey, Daniel J; de Luca, Alba C; Malheiro, Vera N; Markaki, Athina E; Guagliano, Mario; Webster, Thomas J

    2015-12-01

    Substrate grain structure and topography play major roles in mediating cell and bacteria activities. Severe plastic deformation techniques, known as efficient metal-forming and grain refining processes, provide the treated material with novel mechanical properties and can be adopted to modify nanoscale surface characteristics, possibly affecting interactions with the biological environment. This in vitro study evaluates the capability of severe shot peening, based on severe plastic deformation, to modulate the interactions of nanocrystallized metallic biomaterials with cells and bacteria. The treated 316L stainless steel surfaces were first investigated in terms of surface topography, grain size, hardness, wettability and residual stresses. The effects of the induced surface modifications were then separately studied in terms of cell morphology, adhesion and proliferation of primary human osteoblasts (bone forming cells) as well as the adhesion of multiple bacteria strains, specifically Staphylococcus aureus, Staphylococcus epidermidis, Pseudomonas aeruginosa, and ampicillin-resistant Escherichia coli. The results indicated a significant enhancement in surface work hardening and compressive residual stresses, maintenance of osteoblast adhesion and proliferation as well as a remarkable decrease in the adhesion and growth of gram-positive bacteria (S. aureus and S. epidermidis) compared to non-treated and conventionally shot peened samples. Impressively, the decrease in bacteria adhesion and growth was achieved without the use of antibiotics, for which bacteria can develop a resistance towards anyway. By slightly grinding the surface of severe shot peened samples to remove differences in nanoscale surface roughness, the effects of varying substrate grain size were separated from those of varying surface roughness. The expression of vinculin focal adhesions from osteoblasts was found to be singularly and inversely related to grain size, whereas the attachment of gram

  17. Influence of thermomechanical processing on shear bands formation and magnetic properties of a 3% Si non-oriented electrical steel

    Energy Technology Data Exchange (ETDEWEB)

    Silva Ferreira de Dafe, Sara, E-mail: saradafe@gmail.com [Physics Department, Federal University of Ouro Preto, Campus Universitario, Ouro Preto, MG 35400000 (Brazil); Costa Paolinelli, Sebastiao da [Research Department, ArcelorMittal Inox Brasil, Praca Primeiro de Maio, 9 Timoteo, MG 35180018 (Brazil); Barros Cota, Andre [Physics Department, Federal University of Ouro Preto, Campus Universitario, Ouro Preto, MG 35400000 (Brazil)

    2011-12-15

    The effect of thermomechanical processing on the formation of shear bands and on the magnetic properties of a 3.0 wt% silicon non-oriented steel was investigated by hot rolling samples with different thicknesses at different temperatures, in order to obtain a variation in hot band grain size and cold strain. All the samples were processed in a single-stage cold rolling and finally annealed at 1020 deg. C. It was found that the increase of the hot band grain size decreases the {gamma} fiber volume fraction and increases the {eta} fiber volume fraction after the final annealing. The increase of the cold strain strongly contributed to this result. A good combination of intense generation of shear bands, and proper crystallographic texture, due to higher nucleation of grains with favorable orientations to magnetization in these bands, can be obtained for the samples hot rolled at 1000 and 1120 deg. C and submitted to cold strain of 64.3% and 72.2% respectively. However the best combination of B{sub 50}, W{sub 15/60} and {mu}{sub r} can be obtained by hot rolling the samples at 1000 deg. C to the thickness of 1.4 mm, corresponding to 64.3% of cold strain. - Highlights: > Effect of processing on the magnetic properties of a non-oriented electrical steel. > Shear band generation during cold rolling is essential to reach a favorable texture. > Great magnetic properties obtained by hot rolling at 1000 deg. C and 64.3% cold strain.

  18. Effect of steel composition and slag properties on NMI in clean steel production

    Directory of Open Access Journals (Sweden)

    Elfawakhry Mohamed K

    2016-01-01

    Full Text Available The modern steel plants for clean steel production depend to large extent on the efficiency of the refining processes that applied for the production. Refining processes that applied for low alloy and alloyed steel production include degassing via vacuum or ladle and ladle furnace units. This technique could help in producing homogeneous steel with low gas content and minimum internal defects. In certain grades of steel for tools and penetration and impact resistance uses, non-metallic inclusions (NMI and sulphur content are the key factors for the steel performance and applications. ESR, Electro-salg refining (or remelting, is the technique that can efficiently produce clean steel with minimum content of NMI and sulphur due to the special nature and mechanism of this technique. In this study, the effect of initial chemical composition of steel and slag properties on the efficiency of ESR process in removal of NMI and sulphur from steel are evaluated. Different grades of steels were refined using ESR process. The efficiency of ESR in modifying and enhancing NMI shape, size and counts as well as removal of sulphur in different steel grades was evaluated at different slag composition and physical properties. The effect of chemical composition of steel on the efficiency of ESR process was studied. It was found that ESR process has a great effect in producing clean steel where both viscosity and initial composition of steel have influence on the final NMI status and sulphur content in the produced steel.

  19. Influence of the chemical composition, heat and surface treatment in the biofouling of austenitic stainless steels; Influencia de la composicion quimica, del tratamiento termico y del acabado supreficial en el bioensuciamiento de aceros inoxidables austeniticos

    Energy Technology Data Exchange (ETDEWEB)

    Sarro, M. I.; Aleman, O.; Moreno, D. A.; Roso, M.; Ranninger, C.

    2004-07-01

    The main objective of this study was to analyse the biofouling processes in the kinds of stainless steels used normally in industry (UNS S30400, UNS S30403 and UNS S31600), with different surface treatments after grinding and polishing. The study was developed using two microscopy techniques. Scanning Electron Microscopy (SEM) was used to evaluate the microorganisms distribution in the materials, and Epi fluorescence Microscopy was used to evaluate the viability of cells in the biofilm. The results revealed the influence of the material, heat treatment, surface treatment and roughness in the biofouling processes in the stainless steel assays. (Author) 33 refs.

  20. Rare earth metals influence on morphology of non-metallic inclusions and mechanism of GP240GH and G17CrMo5-5cast steel cracking

    Directory of Open Access Journals (Sweden)

    M. Gajewski

    2009-10-01

    Full Text Available This paper presents results of research carried out in order to specify the influence of the rare earth metals on the morphology of the occuring non-metallic inclusions as well as on the cracking mechanism of GP240GH cast carbon steel and G17CrMo5-5 (0.18%C, 1.2%Cr, 0.53%Mo high temperature cast steel. The tests have been performed on successive industrial melts adding rare earth metals to the ladle during tapping of heat melt from the furnace. It was found that ball-shaped non-metalic inclusions occuring as a result of the rare earth metals influence are heterogenic and they significantly influence the cracking mechanism of Charpy specimens and the impact strength. The morphology of the specimens fracture surface has been substantially changed as a result of the rare earth metals modification. The impact strength of the tested cast carbon steel increased from 100 J/cm2 to ca 155 J/cm2, and the high-temperature cast steel from 30 J/cm2 to ca 100 J/cm2.

  1. The influence of surface microstructure and chemical composition on corrosion behaviour in fuel-grade bio-ethanol of low-alloy steel modified by plasma nitro-carburizing and post-oxidizing

    Science.gov (United States)

    Boniatti, Rosiana; Bandeira, Aline L.; Crespi, Ângela E.; Aguzzoli, Cesar; Baumvol, Israel J. R.; Figueroa, Carlos A.

    2013-09-01

    The interaction of bio-ethanol on steel surfaces modified by plasma-assisted diffusion technologies is studied for the first time. The influence of surface microstructure and chemical composition on corrosion behaviour of AISI 4140 low-alloy steel in fuel-grade bio-ethanol was investigated. The steel surfaces were modified by plasma nitro-carburizing followed plasma oxidizing. X-ray diffraction, scanning electron microscopy, optical microscopy, X-ray dispersive spectroscopy, and glow-discharge optical emission spectroscopy were used to characterize the modified surface before and after immersion tests in bio-ethanol up to 77 days. The main corrosion mechanism is pit formation. The pit density and pit size were measured in order to quantify the corrosion resistance which was found to depend more strongly on microstructure and morphology of the oxide layer than on its thickness. The best corrosion protection was observed for samples post-oxidized at 480 °C and 90 min.

  2. The detection and influence of food soils on microorganisms on stainless steel using scanning electron microscopy and epifluorescence microscopy.

    Science.gov (United States)

    Whitehead, Kathryn A; Smith, Lindsay A; Verran, Joanna

    2010-07-31

    A range of food soils and components (complex [meat extract, fish extract, and cottage cheese extract]; oils [cholesterol, fish oil, and mixed fatty acids]; proteins [bovine serum albumin (BSA), fish peptones, and casein]; and carbohydrates [glycogen, starch, and lactose]) were deposited onto 304 2B finish stainless steel surfaces at different concentrations (10-0.001%). Scanning electron microscopy (SEM) and epifluorescence microscopy were used to visualise the cell and food soil distribution across the surface. Epifluorescence microscopy was also used to quantify the percentage of a field covered by cells or soil. At 10% concentration, most soils, with the exception of BSA and fish peptone were easily visualised using SEM, presenting differences in gross soil morphology and distribution. When soil was stained with acridine orange and visualised by epifluorescence microscopy, the limit of detection of the method varied between soils, but some (meat, cottage cheese and glycogen) were detected at the lowest concentrations used (0.001%). The decrease in soil concentration did not always relate to the surface coverage measurement. When 10% food soil was applied to a surface with Escherichia coli and compared, cell attachment differed depending on the nature of the soil. The highest percentage coverage of cells was observed on surfaces with fish extract and related products (fish peptone and fish oil), followed by carbohydrates, meat extract/meat protein, cottage cheese/casein and the least to the oils (cholesterol and mixed fatty acids). Cells could not be clearly observed in the presence of some food soils using SEM. Findings demonstrate that food soils heterogeneously covered stainless steel surfaces in differing patterns. The pattern and amount of cell attachment was related to food soil type rather than to the amount of food soil detected. This work demonstrates that in the study of conditioning film and cell retention on the hygienic properties of surfaces, SEM

  3. Influence of cold rolling direction on texture, inhibitor and magnetic properties in strip-cast grain-oriented 3% silicon steel

    Science.gov (United States)

    Fang, F.; Lu, X.; Zhang, Y. X.; Wang, Y.; Jiao, H. T.; Cao, G. M.; Yuan, G.; Xu, Y. B.; Misra, R. D. K.; Wang, G. D.

    2017-02-01

    An unconventional cold rolling scheme (inclined rolling at 0°, 30°, 45°, 90° during second-stage cold rolling process) was adopted to process grain-oriented silicon steel based on strip casting process. The influences of inclination angles on microstructure, texture, inhibitor and magnetic properties were studied by a combination of EBSD, XRD and TEM. It was found that the α-fiber texture was weakened and γ-fiber was strengthened in cold rolled sheet with increase in inclination angle. The primary recrystallization sheet exhibited more homogeneous microstructure with relatively strong γ-fiber, medium α-fiber texture, weak λ-fiber texture and Goss component at high inclination angles. Fine and homogeneous inhibitors were obtained after primary annealing with increase in inclination angle from 0° to 90° because of more uniform deformation after inclined rolling. The grain-oriented silicon steel experienced completely secondary recrystallization at various inclination angles after final annealing process, with superior magnetic properties at 0° and 90°. Furthermore, Goss nuclei capable of final secondary recrystallization in strip casting process newly formed both in-grain shear bands and grain boundaries region during second-stage cold rolling and subsequent annealing process, which is different from the well-accepted results that Goss texture originated from the subsurface layer of the hot rolled sheet or during intermediate annealing process. In addition, the Goss texture that nucleated in-grain shear bands was weaker but more accurate as compared to that in grain boundaries region.

  4. Influence and Application of Various Elements to Steel Property in Agricultural Using%农业用钢中各种元素对钢性能的影响及应用

    Institute of Scientific and Technical Information of China (English)

    尤晓东

    2014-01-01

    随着农业机械化的发展,我国农业用钢的需求量逐渐增大,对钢材质量的要求也日益提高。分析钢材中各种微量元素对农业用钢性能的影响,介绍常用农机具及其零部件制造所用钢的型号,为提升国产农机装备质量提供参考。%With the development of agricultural mechanization, the steel demand of agricultural application is increasing rapidly in China, the request to steel quality is also rising. To analyze the influence of various microelements in steel to steel property in agricultural using, to introduce steel types for manufacturing usual agricultural machinery and components, will provide a reference for increasing the quality of domestic agricultural machinery.

  5. Influence of geometrical factors and pressing mould wear on thermal-hydraulic characteristics for steel offset strip fins at low Reynolds number

    Energy Technology Data Exchange (ETDEWEB)

    Guo, Lihua; Qin, Feng; Chen, Jiangping; Chen, Zhijiu [Institute of Refrigeration and Cryogenics Engineering, Shanghai Jiaotong University, 1954 Huashan Road, Shanghai 200030 (China); Zhou, Yimin [Zhejiang Yinlun Machinery Co. Ltd., Zhejiang Province 317200 (China)

    2007-12-15

    Aiming at achieving a more comprehensive understanding of influence factors on thermal-hydraulic characteristics for high-pressure-direction type steel offset strip fins, this paper constructed a single fin core assembly test rig with lubricant oil as work media at low Reynolds number. Six fin schemes were experimentally investigated only varying in fin height and fin wavelength due to mould restrictions. Twenty fin schemes changing in fin width, fin angle, fin thickness and staggered fin wavelength were simulated for supplement, and the geometrical influences in fin performance were put forward. Both Taguchi method and uniform design were introduced to study the contribution of each geometrical factor to fin global thermal-hydraulic performance, verifying that fin wavelength and fin height have the most significant contributions. Based on signal to noise ratio distributions, fin geometries were optimized for 16% elevation of global performance at Reynolds number of 430, then the 'cost-based fin performance' was put forward and compared quantitatively, proving that above optimum fin scheme is also economical. Finally, mould wear influence in fin performance was tested in different wear periods of a vacuum heat-treated Cr12MoV mould pair, then three stages of initial wear, stable wear, and overdrive wear were defined based on pressing times. The influences were analyzed and regulations were deduced relating to mould pressing times and oil Reynolds number. The suggested lifetime for this type of mould pair is 1050 thousand pressing times. The paper intends for fin performance evaluation, optimization, and pressing mould improvement. (author)

  6. Influence of austenitizing temperature on microstructure and mechanical properties of AISI 431 martensitic stainless steel electron beam welds

    Energy Technology Data Exchange (ETDEWEB)

    Rajasekhar, A. [Department of Mechanical Engineering, SVITS, Mahaboob Nagar 509 001 (India)], E-mail: adula.rajasekhar@rediffmail.com; Madhusudhan Reddy, G.; Mohandas, T. [Defence Metallurgical Research Laboratory, Hyderabad 500 058 (India); Murti, V.S.R. [Department of Mechanical Engineering, SVITS, Mahaboob Nagar 509 001 (India)

    2009-05-15

    The relative effects of various austenitizing temperatures on microstructure and mechanical properties of electron beam welds of AISI 431martensitic stainless steel were studied. The post-weld heat treatments consist of austenitizing the weld samples for 1 h at various temperatures, i.e., at 950 deg. C, 1000 deg. C, 1050 deg. C, 1100 deg. C and at 1150 deg. C and air cooling followed by double tempering, i.e., tempering at 670 + 600 deg. C. In the as-welded condition the microstructure contains dendritic structure with ferrite network and retained austenite in a matrix of un-tempered martensite. The prior austenite grain size increased with increase in austenitizing temperature. Parent metal grain size was coarser as compared to grain size in the weld zone in respective conditions. Retained austenite content increased with increase in the austenitizing temperature. Presence of undissolved carbides was observed in welds and parent metal austenitized up to 1000 deg. C and they dissolved at austenitizing temperature {>=} 1050 deg. C. Coarsening of martensite laths was observed after tempering. The martensite laths were coarser in the samples subjected to higher austenitizing temperatures. Optimum mechanical properties, i.e., strength, hardness and toughness were observed when austenitized between 1050 deg. C and 1100 deg. C followed by tempering. Austenitizing at 1150 deg. C and tempering resulted in inferior mechanical properties. The mechanism for the observed trends is discussed in relation to the microstructure, fracture features and mechanical properties.

  7. Influences of carbon and silicon on blister formation in scale surface during high temperature oxidation of carbon steels

    Science.gov (United States)

    Kim, Deuk-Jung; Lee, Jae-Sang; Koo, Yang-Mo

    2017-07-01

    The in-situ blistering phenomena of the scale `surface' was investigated on three carbon steels with respect to carbon and silicon concentrations, such as 0.05 wt%C, 0.2 wt%C, and 0.2 wt%C-0.2 wt%Si. The oxidation and blistering kinetics and blister area fraction during high temperature oxidation were analyzed. The average thickness of the surface scale by oxidation during isothermal holding from 800 to 1200 °C in dry air was observed to decrease when the amount of carbon increased and/or when Si was inserted additionally. Thus, the blistering behavior depended primarily on a change in oxidation temperature ( T ox ) as well as amounts of carbon and silicon in the matrix. It is also revealed that such blister formation would be triggered by growth of internal stress and active generations of CO and/or CO2 gases at the interface between the scale and matrix since carbon would result in an increase in the blister formation by generating CO and/or CO2 gas. In addition, silicon might play an important role in preventing the blister formation at T ox below 900 °C by reducing the thickness of the surface scale whilst silicon might enhance the blister formation by means of the appreciable micro-void formation in the scale layer at T ox higher 900 °C.

  8. Influence of the solution temperature on the corrosion behavior of an austenitic stainless steel in phosphoric acid medium

    Energy Technology Data Exchange (ETDEWEB)

    Ibanez-Ferrandiz, M.V.; Blasco-Tamarit, E.; Garcia-Garcia, D.M.; Garcia-Anton, J. [Valencia Univ. Politecnica, Dept. de Ingenieria Quimica y Nuclear. ETSI Industriales, Valencia (Spain); Guenbour, A.; Bakour, S.; Benckokroun, A. [University Mohammed V-Agdal, Lab. Corrosion-Electrochimie, Faculty of Sciences, Rabat (Morocco)

    2009-07-01

    The objective of the present work is to study the effect of the solution temperature on the corrosion resistance of a highly alloyed austenitic stainless steel (UNS N08031) used as base metal, the welded metal obtained by TIG (Tungsten Inert Gas) welding using a Nickel-base alloy (UNS N06059) as filler metal, and the Heat Affected Zone (HAZ) of the base metal. The materials were tested in 5.5 M phosphoric acid solution at 25 C, 40 C, 60 C and 80 C. Open Circuit Potential tests and potentiodynamic anodic polarization curves have been carried out to obtain information about the electrochemical behavior of the materials. Corrosion potentials and corrosion current densities were obtained from Tafel analysis. The critic potentials and passivation current densities of the studied materials were also analyzed. The galvanic corrosion generated by the electrical contact between the welded metal, the base metal and the HAZ, was estimated from the polarisation diagrams according to the Mixed Potential Theory. The samples were etched to study their microstructure by Optical Microscopy. Results demonstrated that the corrosion potential values shift to more anodic potentials as temperature increases. The corrosion current densities and the passive current densities increased with temperature. Open circuit potential values were located in the passive zone of the potentiodynamic curves, which means that the materials passivated spontaneously. (authors)

  9. Influence of load on sliding tribology of C/C composite with 40Cr steel couple coated by Cr

    Institute of Scientific and Technical Information of China (English)

    GE Yi-cheng; YI Mao-zhong; LI Li-ya

    2007-01-01

    With the 40Cr steel couple coated by Cr, the sliding tribology behavior of two kinds of C/C composites with different matrix was tested using a M2000 wear tester. The results show that with the increasing of load, the friction coefficients of the composite with resin carbon matrix(RC) decrease quickly from 0.156 under 60 N to 0.123 under 150 N, while those of the composite with rough lamination/smooth lamination /resin carbon (RL/SL/RC) change only between 0.122 and 0.101. The wear volume loss of the two composites increases except for under 100 N. The SEM morphology shows that with the increasing of load, the worn surface of the composite with RC becomes more and more integrated while the size of the debris becomes less and less. The Raman spectrum shows that the graphitization on the worn surface of the fibers draws down after 100 N, the graphitization of the boundary between the fiber and the matrix carbon rises up to 150 N, but the graphitization of the matrix carbon draws down all the while. With the increasing of load, the graphitization on the worn surface of all the worn areas becomes closer and closer, which indicates the worn surface of the different component has the similar friction ability. The composites with RL/SL/RC have better tribological characteristic than the composite with RC.

  10. Laser-induced breakdown spectroscopy of major and minor oxides in steel slags: Influence of detection geometry and signal normalization

    Science.gov (United States)

    Ahamer, C. M.; Eschlböck-Fuchs, S.; Kolmhofer, P. J.; Rössler, R.; Huber, N.; Pedarnig, J. D.

    2016-08-01

    Slag from secondary metallurgy in industrial steel production is analyzed by laser-induced breakdown spectroscopy (LIBS). The major oxides CaO, Al2O3, MgO, SiO2, FeO, MnO, and TiO2 are determined by calibration-free LIBS (CF-LIBS) method. For the minor oxide P2O5 calibration curves are established and the limits of detection (LOD) and the root-mean squared errors of prediction (RMSEP) are determined. The optical emission of the laser-induced plasma is measured for different detection geometries and varying sample position relative to the focal plane of the laser beam. LIBS spectra, plasma parameters, and analytical results are very similar for light collection with optical fibres close to the plasma ("direct detection") and at remote position ("collinear detection"). With collinear detection, the CF-LIBS calculated oxide concentrations are insensitive to sample position along the optical axis over wide range. The detection limits and the prediction errors of minor P2O5 depend on the major slag element used for signal normalization. With Mg and Si as internal reference elements the LOD values are 0.31 wt% and 0.07 wt%, respectively. The RMSEP values are lowest for signal normalization to Si. Calculations of the optical emission of ideal plasma support the experimental preference for Si as reference element in the phosphorous calibration.

  11. Influence of loading-rate and steel fibers on the shear strength of ultra high performance concrete

    Directory of Open Access Journals (Sweden)

    Bratislav Lukic

    2015-01-01

    Full Text Available The paper describes quasi-static and dynamic experimental methods used to examine the confined shear strength of an Ultra High Performance Concrete, with and without the presence of steel fibers in the concrete composition. An experimental setup was created to investigate the concrete shear strength under quasi-static loading regime using a hydraulic press Schenk while dynamic shear strength was characterized by subjecting concrete samples to dynamic loading through a modified Split Hopkinson Pressure Bar. Both methods are based on a Punch Through Shear (PTS test with a well-instrumented aluminum passive confinement ring that allows measuring the change of radial stress in the shear ligament throughout the test. Firstly, four equally distributed radial notches have been performed in order to deduce the radial stress by suppressing a self-confinement of the sample peripheral part. However, by analyzing the strain gauge data from the confinement ring, it has been noticed that these were apparently insufficient, especially for fiber-reinforced samples, resulting in subsequently practicing eight radial notches through the sample peripheral part. The results obtained from both procedures are reported and discussed.

  12. Influence of loading-rate and steel fibers on the shear strength of ultra high performance concrete

    Science.gov (United States)

    Bratislav, Lukic; Pascal, Forquin

    2015-09-01

    The paper describes quasi-static and dynamic experimental methods used to examine the confined shear strength of an Ultra High Performance Concrete, with and without the presence of steel fibers in the concrete composition. An experimental setup was created to investigate the concrete shear strength under quasi-static loading regime using a hydraulic press Schenk while dynamic shear strength was characterized by subjecting concrete samples to dynamic loading through a modified Split Hopkinson Pressure Bar. Both methods are based on a Punch Through Shear (PTS) test with a well-instrumented aluminum passive confinement ring that allows measuring the change of radial stress in the shear ligament throughout the test. Firstly, four equally distributed radial notches have been performed in order to deduce the radial stress by suppressing a self-confinement of the sample peripheral part. However, by analyzing the strain gauge data from the confinement ring, it has been noticed that these were apparently insufficient, especially for fiber-reinforced samples, resulting in subsequently practicing eight radial notches through the sample peripheral part. The results obtained from both procedures are reported and discussed.

  13. Influence of electrodeposition parameters on the characteristics of Mn–Co coatings on Crofer 22 APU ferritic stainless steel

    Indian Academy of Sciences (India)

    HADI EBRAHIMIFAR; MORTEZA ZANDRAHIMI

    2017-10-01

    Manganese–cobalt coatings are promising candidates for solid oxide fuel cell (SOFC) interconnection applications because of their high conductivity and good oxidation resistance. In the present study, manganese and cobalt are electrodeposited onCrofer 22APU ferritic stainless steel. The effects of current density, pH, sodium gluconate (NaC$_6$H$_{11}$O$_7$)concentration, cobalt sulphate concentration (CoSO$_4$·7H$_2$O) and deposition duration on the microstructure and cathodic efficiency are characterized by means of scanning electron microscopy, weight gain measurements and energy-dispersive X-ray spectrometry, respectively. Results show that increases in current density and deposition duration lead to decrease in current efficiency and deposition rate. Increasing the pH to 2.5 causes an initial rise of current efficiency and depositionrate, followed by subsequent decline. In addition, the increases in sodium gluconate and cobalt sulphate concentrations inthe electrolyte solution result in an increase in current efficiency and deposition rate. Moreover, the results demonstratethat the variations in the current density, pH, sodium gluconate (NaC$_6$H$_{11}$O$_7$) concentration, cobalt sulphate concentration (CoSO$_4$·7H$_2$O) and duration have a significant effect on grain size, uniformity and the adherence of the coating.

  14. Influence of ageing time on hardness, microstructure and wear behaviour of AISI2507 super duplex stainless steel

    Science.gov (United States)

    Davanageri, Mahesh; Narendranath, S.; Kadoli, Ravikiran

    2017-08-01

    The effect of ageing time on hardness, microstructure and wear behaviour of super duplex stainless AISI 2507 is examined. The material was solution treated at 1050 °C and water quenched, further the ageing has been carried out at 850 °C for 30 min, 60 min and 90 min. The chromium (Cr) and molybdenum (Mo) enriched intermetallic sigma phase (σ) were found to precipitate at the ferrite/austenite interface and within the ferrite region. The concentration of intermetallic sigma phase (σ), which was quantified by a combination of scanning electron microscopy and image analysis, increases with increasing ageing time, leading to significant increase in the hardness. The x-ray diffraction (XRD) and energy dispersive x-ray (EDX) was employed to investigate the element distribution and phase identification. Wear characterstics of the aged super duplex stainless steel were measured by varying normal loads, sliding speeds, sliding distance and compared with solution treated (as-cast) specimens. Scanning electron microscopy was used to assist in analysis of worn out surfaces. The outcomes suggested that the increase in percentage of sigma phase increases hardness and wear resistance in heat-treated specimens compared to solution treated specimens (as-cast).

  15. Trepanning drilling of stainless steel using a high-power Ytterbium-doped fiber ultrafast laser: influence of pulse duration on hole geometry and processing quality

    Science.gov (United States)

    Lopez, John; Dijoux, Mathieu; Devillard, Raphael; Faucon, Marc; Kling, Rainer

    2014-03-01

    Percussion drilling is a well-established technique for several applicative markets such as for aircraft and watch industries. Lamp pumped solid state lasers and more recently fiber lasers, operating in millisecond or nanosecond regimes, are classically used for these applications. However, due to their long pulse duration, these technologies are not suitable for emerging applicative market such as fuel injectors for automotive industry. Only the ultrashort laser technology, combined with special drilling optics like trepanning head, has the potential to fulfill the needs for this new market in terms of processing quality, custom-shape capabilities and short drilling time. Although numerous papers dealing with percussion drilling have been reported in the literature, only few papers are dedicated to trepanning drilling. In this context, we present some results on the influence of pulse duration on gas-assisted laser drilling of stainless steel using a trepanning head and a high power Ytterbium doped fiber ultrafast laser (20W). The influence of pulse energy (7- 64μJ), fluence (3-25 J/cm2), drilling time (1-20s), processing gas pressure and drilling strategy will be discussed as well.

  16. Influence of the Carbo-Chromization Process on the Microstructural, Hardness, and Corrosion Properties of 316L Sintered Stainless Steel

    Science.gov (United States)

    Iorga, Sorin; Cojocaru, Mihai; Chivu, Adriana; Ciuca, Sorin; Burdusel, Mihail; Badica, Petre; Leuvrey, Cédric; Schmerber, Guy; Ulhaq-Bouillet, Corinne; Colis, Silviu

    2014-06-01

    We report on the changes on the microstructural, hardness, and corrosion properties induced by carbo-chromization of 316L stainless steel prepared by Spark Plasma Sintering technique. The thermo-chemical treatments have been performed using pack cementation. The carburizing and chromization were carried out between 1153 K (880 °C)/4 h to 1253 K (980 °C)/12 h and 1223 K (950 °C)/6 h to 1273 K (1000 °C)/12 h in a solid powder mixture of charcoal/BaCO3 and ferrochromium/alumina/NH4Cl, respectively. The obtained layers were investigated using X-ray and electron diffraction, optical and scanning electron microscopies, Vickers micro-hardness, and potentiodynamic measurements. The thickness of the carbo-chromized layer ranges between 300 and 500 μm. Besides the host γ-phase, the layers are mainly constituted of carbides (Fe7C3, Cr23C6, Cr7C3, and Fe3C) and traces of α'-martensite. The average hardness values decrease smoothly from 650 HV at the sample surface down to 200 HV at the center of the sample. The potentiodynamic tests revealed that the carbo-chromized samples have smaller corrosion resistance with respect to the untreated material. For strong chromization regimes, the corrosion rate is increased by a factor of four with respect to that of the untreated material, while the micro-hardness of the layer is three times larger. Such materials are suited to be used in environments where good corrosion resistance and wear properties are required.

  17. Analyses of process parameters influence on the drilling process by using carbide drills for steel St52-3

    Directory of Open Access Journals (Sweden)

    Popan Ioan Alexandru

    2017-01-01

    Full Text Available The influence of cutting parameters on the hole quality made using a new type of carbide drill, RT100 U, has been analysed experimentally and analytically. The drilling process is a common application in industrial environments and it has to be established at high accuracy and short time. The influence of process parameters (cutting speed and feed rate on dimensional accuracy and surface roughness is analysed. The experiment was made by using external cooling and canned cycles (G81. On this experimental study was analysed the effect of feed rate onto the chip shape.

  18. The Influence of the Prestress of Reinforced Steel on the Behaviour of the Flexural Elements of Reinforced Concrete

    Directory of Open Access Journals (Sweden)

    Aidas Jokūbaitis

    2013-12-01

    Full Text Available This article briefly discusses the essence of prestressed concrete,its advantages and disadvantages. The analysis of prestress lossesis done according to different standards. The paper explainspretensioning force and selection of its eccentricity as well asanalyzes the influence of beam cracking according to limitationson concrete tensile and compressive stresses.

  19. Influence of localized deformation on A-286 austenitic stainless steel stress corrosion cracking in PWR primary water; Influence de la localisation de la deformation sur la corrosion sous contrainte de l'acier inoxydable austenitique A-286 en milieu primaire des REP

    Energy Technology Data Exchange (ETDEWEB)

    Savoie, M

    2007-01-15

    Irradiation-assisted stress corrosion cracking (IASCC) of austenitic stainless steels is known to be a critical issue for structural components of nuclear reactor cores. The deformation of irradiated austenitic stainless steels is extremely heterogeneous and localized in deformation bands that may play a significant role in IASCC. In this study, an original approach is proposed to determine the influence of localized deformation on austenitic stainless steels SCC in simulated PWR primary water. The approach consists in (i) performing low cycle fatigue tests on austenitic stainless steel A-286 strengthened by {gamma}' precipitates Ni{sub 3}(Ti,Al) in order to shear and dissolve the precipitates in intense slip bands, leading to a localization of the deformation within and in (ii) assessing the influence of these {gamma}'-free localized deformation bands on A-286 SCC by means of comparative CERT tests performed on specimens with similar yield strength, containing or not {gamma}'-free localized deformation bands. Results show that strain localization significantly promotes A-286 SCC in simulated PWR primary water at 320 and 360 C. Moreover, A-286 is a precipitation-hardening austenitic stainless steel used for applications in light water reactors. The second objective of this work is to gain insights into the influence of heat treatment and metallurgical structure on A-286 SCC susceptibility in PWR primary water. The results obtained demonstrate a strong correlation between yield strength and SCC susceptibility of A-286 in PWR primary water at 320 and 360 C. (author)

  20. Influence of accumulation of heaps of steel slag on the environment: determination of heavy metals content in the soils

    Directory of Open Access Journals (Sweden)

    Javier Garcia-Guinea

    2010-06-01

    Full Text Available The presence of high level of heavy metals involves a human healthy risk that could induce chronic diseases. This work reports on the metal contamination due to heaps of steel-slag accumulated during more than 40 years in allotments and industrial areas in the southern part of Madrid (Spain. Several slag and soil samples were collected in an area of 10 km² and characterized by different conventional (XRD and XRF and no so common methods (ESEM, thermoluminescence and EDS-WDS. The analysis reveal the presence of: (i important amounts of Fe (43%, Mg (26%, Cr (1.1%, Mn (4.6%, S (6.5% in the form of Fe-rich slag phases (wustite, magnetite..., Si and Ca-rich phases (larnite, ghelenite..., Cr (chromite, Mn (bustamite and graphite, (ii traces of some other contaminants such as Cr (7700 ppm, Zn (3500 ppm, Ba (3000 ppm, Pb (700 ppm or Cu (500 ppm on pathway soil samples that come from the steel slag, and (iii Co (13 ppm, Pb (78 ppm and V (54 ppm in farmland soil samples. Although the existing heavy metals content is not appropriate for the current use, the extremely high metal contamination of the surrounding areas is more worrying. The properties of the soil farmlands (pH circa 7, 13% of clay, mainly illite, and 1-4% of organic matter content show suitable conditions for the retention of cationic metals, but further studies on the movilization of these elements have to be performed to determine the possibility of severe human health risks. This sort of study can provide useful information for the politicians regarding the appropriate use of the territory to prevent possible health hazard for the population.A presença de altos niveis de metais pesados envolve riscos à saúde humana e pode induzir doenças crônicas. Este trabalho relata a contaminação metálica causada por pilhas de escória siderúrgica acumulada durante mais de 40 anos em áreas industriais na parte sul de Madrid (Espanha. Amostras de escória e solo foram coletadas em uma área de

  1. The study on the influence of surface cleanness and water soluble salt on corrosion protection of epoxy resin coated carbon steel

    Energy Technology Data Exchange (ETDEWEB)

    Shon, Younng Shon [Pukyong National University, Busan (Korea, Republic of)

    2014-10-15

    The corrosion resistance of epoxy-coated carbon steel was evaluated. The carbon steel surface was subjected to different treatment methods such as steel grit blasting and power tool treatment as well as contamination of water soluble salt. To study the effect of the surface treatments and contamination, the topology of the treated surface was observed by confocal microscopy and a pull-off adhesion test was conducted. The corrosion resistance of the epoxy-coated carbon steel was further examined by electrochemical impedance spectroscopy (EIS) combined with immersion test of 3.5 wt% of NaCl solution. Consequently, the surface contamination by sodium chloride with 16 mg/m{sup 2}, 48 mg/m{sup 2} and 96 mg/m{sup 2} didn't affect the adhesion strength for current epoxy coated carbon steel and blister and rust were not observed on the surface of epoxy coating contaminated by various concentration of sodium chloride after 20 weeks of immersion in 3.5 wt% NaCl aqueous solutions. In addition, the results of EIS test showed that the epoxy-coated carbon steel treated with steel grit blasting and power tool showed similar corrosion protection performance and surface cleanness such as Sa 3 and Sa 2.5 didn't affect the corrosion protectiveness of epoxy coated carbon steel.

  2. Some studies on the influence of stress ratio and test temperature on X-ray fractography observations in C45 steel specimens

    NARCIS (Netherlands)

    Rajanna, K.; Pathiraj, B.; Kolster, B.H.

    1996-01-01

    This paper deals with additional ¿X-ray fractography¿ observations made on C45 steel, subsequent to the earlier work [K. Rajanna, B. Pathiraj and B. H. Kolster, Fatigue fracture surface analysis in C45 steel specimens using X-ray fractography. Engng Fracture Mech. 39, 147¿157 (1991)]. Fatigue crack:

  3. Mathematical Simulation of Heat Transfer in Heterogenous Forest Fuel Layer Influenced by Heated Up to High Temperatures Steel Particle

    Directory of Open Access Journals (Sweden)

    Baranovskiy Nikolay V.

    2014-01-01

    Full Text Available Heterogeneity of forest fuel layer renders the important influence on forest fire occurrence processes. One of sources of the raised temperature on forested territories is metal particles heated up to high temperatures. Such particles can be formed as a result of welding of metals on forested territories. The present paper represents the heat transfer research in forest fuel at the influence of metal particle heated up to high temperatures. The heterogonous forest fuel layer with inclusions of small wooden branches and chips is considered. Such object research is urgent especially at fire forecasting on forest cutting. The technology of mathematical simulation is used. The two-dimensional problem of heat transfer in forest fuel layer structure with wood inclusions is solved.

  4. Tensile properties of duplex UNS S32205 and lean duplex UNS S32304 steels and the influence of short duration 475 ºC aging

    Directory of Open Access Journals (Sweden)

    Sérgio Souto Maior Tavares

    2012-12-01

    Full Text Available Duplex stainless steels are high strength and corrosion resistant steels extensively used in the petrochemical and chemical industries. The aging at 475 ºC for long periods of time provokes embrittlement and deterioration of corrosion resistance. However, short duration aging at 475 ºC may be used as heat treatment to improve mechanical resistance with small decrease in the other properties. In this work the flow stress curves of lean duplex UNS S32304 and duplex UNS S32205 steels were modeled with Hollomon's equation and work hardening exponents (n were determined. The analyses were conducted in specimens annealed and heat treated at 475 ºC for short periods of time. The aging at 475 ºC for 4 hours, 8 hours and 12 hours promoted significant hardening with small decrease of ductility. The work hardening exponents of both steels were compared, being higher in the duplex steel than in the lean duplex grade.

  5. Influence of regenerative heat treatment on structure and properties of G20CrMo2 - 5 (L20HM cast steel

    Directory of Open Access Journals (Sweden)

    G. Golański

    2008-03-01

    Full Text Available Thc papcr prcscnts rcsuSts or rcscarch on thc influence of rcgcncratic hcat treatment on thc structurc and propcrtics [hardncss. impactcncrgy or L2O11M cnst stccl. Invcstipatcd material was taken from outer fmmc of a turbinc which was scrviccd for t 67 424 hours a! thctcmpcrauirc or 535 "C and prcssurc or 12.75 MPa. In psi-operating condition ~hicnv cstigntcd cast steel was cl~aracteri~cbdy low impactcncrpy of II I ant1 hart3ncss of 139HV30. Analysis uF the irlflue~~uuel ;lustcniriz;~ti on pariimctcrs (tcrnpcr;lturc and lime has rcvealcd rhntat thc tcinpcr;~turcr angc o f 895 + 955 "C (i-e. h3 - +I IO + 70 "C.fo r both 3 and 5 hours of holtl timc. rhc ohtaincd grain sizc amounls to 20+ 2511m. I has hccn pmved that tempcred bainitic-rcrri~ica nd remit ic-hainiric-pearlit ic stn~cturco f thc invcstigatcd cast stccl msurcs highimpact cncrgy, i.c. KV > 1001. as well a5 hardncss. i.e. 11Y30. just at thc tcrnpcmturc of OXl "C. 'I'crnpcmliirc or 7110 "C causcs i'~tnhcrincrclrsc of impact cncrgy along with a slight dccrcasc of hardncss. Morcovcr. it has hccn concludd that nppl ying oS under-annealinginstcad or tcmpcring. nflcr standardizalion. guarantees scquircd impact cncrgy of KY r 271.

  6. Laser melting treatment of Ni-P surface alloys on mild steel. Influence of initial coating thickness and laser scanning rate

    Directory of Open Access Journals (Sweden)

    García-Alonso, M. C.

    1997-08-01

    Full Text Available Different thickness Ni-P coatings deposited on mild steel are submitted to laser surface melting at different scanning rates. The microstructure of the alloys is characterized by optical and scanning electron microscopy and microprobe analysis. It is shown that both the initial coating thickness and the laser scanning rate have an influence on the shape, extent and size of the different structures resulting from the solidification process. Thus, when the laser scanning rate increases a progressive refinement of the structure takes place that could even totally block the dendritic growth produced during solidification for a high initial coating thickness.

    Recubrimientos de Ni-P, con distinto espesor, depositados sobre un acero microaleado fueron tratados con láser a diferentes velocidades de barrido. La microestructura, tanto del recubrimiento como del acero base, ha sido caracterizada por microscopía óptica y electrónica y por microanálisis. En el proceso de solidificación se han obtenido distintas estructuras que varían en cuanto a la forma, extensión y tamaño dependiendo del espesor inicial de recubrimiento y de la velocidad de barrido del haz láser. A medida que la velocidad del haz aumenta, se produce un refinamiento progresivo de la microestructura dendrítica y, en casos extremos de alto espesor de recubrimiento y velocidades grandes, este crecimiento dendrítico se bloquea.

  7. Influence of Hardness, Matrix and Carbides in Combination with Nitridation on Abrasive Wear Resistance of X210Cr12 Tool Steel

    Directory of Open Access Journals (Sweden)

    Martin Orečný

    2016-10-01

    Full Text Available Materials used in abrasive wear conditions are usually selected according to their microstructure and hardness, however, other factors such as grain size, matrix saturation, carbides size and morphology are rarely considered. Therefore, the present study deals with the influence of different heat and chemical-heat treatments including their combination on abrasive wear resistance of X210Cr12 tool steel. The effects of material hardness, carbide morphology and microstructure on wear resistance after quenching and nitriding were also investigated. One sample series was quenched after austenitization at 960 °C for 20 min and tempered at 180 °C for 2 h. The second sample series was quenched from 1060 °C austenitization for 20 min and afterwards twice tempered at 530 °C for 1 h. From both the quenched and tempered states, one half of the samples was gas nitrided in NH3 atmosphere for 3 h and then diffusion annealed in N2 atmosphere for 4 h. Abrasion wear tests were performed by sliding the samples on Al2O3 paper. The samples weight loss was considered the main criterion for the wear resistance evaluation. The microstructures, nitrided layers and worn surfaces were observed using SEM microscopy. The highest abrasion wear resistance was obtained for the nitrided samples that were previously quenched from 1060 °C and tempered at 530 °C.

  8. Interaction between recrystallization and strain-induced precipitation in a high Nb- and N-bearing austenitic stainless steel: Influence of the interpass time

    Energy Technology Data Exchange (ETDEWEB)

    Silva, M.B.R., E-mail: marianabdrs@gmail.com [Department of Materials Engineering, UFSCar, Via Washington Luis, Km 235, 13565-905 São Carlos, SP (Brazil); Gallego, J. [Department of Mechanical Engineering, UNESP, Avenida Brasil, 56, 15385-000 Ilha Solteira, SP (Brazil); Cabrera, J.M. [Department of Materials Science and Metallurgical Engineering, Polytechnic University of Catalunya, Avenida Diagonal 647, 08028 Barcelona (Spain); Fundacio CTM Centre Tecnologic, Plaza de la Ciencia 2, 08243 Manresa (Spain); Balancin, O. [Department of Materials Engineering, UFSCar, Via Washington Luis, Km 235, 13565-905 São Carlos, SP (Brazil); Jorge, A.M., E-mail: moreira@dema.ufscar.br [Department of Materials Engineering, UFSCar, Via Washington Luis, Km 235, 13565-905 São Carlos, SP (Brazil)

    2015-06-18

    In this work, we studied the influence of the interpass time (20 and 5 s) on the interaction between recrystallization and strain-induced precipitation occurring during multiple passes' deformations under continuous cooling conditions in a high niobium- and nitrogen-bearing austenitic stainless steel (ISO 5832-9). The correlation between microstructure evolution and hot mechanical properties was performed by physical simulation using hot torsion tests. The microstructure evolution was analyzed by optical microscopy, transmission electron microscopy and electron back scattered diffraction (EBSD). This technique indicated that dynamic recrystallization occurred at the first passes promoting an excellent grain refinement. On the other hand, shorter interpass time (5 s) allowed higher volume fraction of smallest precipitates than larger interpass time (20 s). After soaking, only TiNbN precipitates were found, whereas, Z-phase (CrNbN) and NbN were formed during thermomechanical processing. Particles with sizes between 20 and 50 nm were effective to pin grain boundaries and dislocations.

  9. The influence of Desulfovibrio vulgaris on the efficiency of imidazoline as a corrosion inhibitor on low-carbon steel in seawater

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez-Rodriguez, Carlos A. [Facultad de Quimica UNAM, Ciudad Universitaria, C.P. 04510 Mexico, D.F. (Mexico)], E-mail: gorc74@yahoo.com; Rodriguez-Gomez, Francisco J.; Genesca-Llongueras, Joan [Facultad de Quimica UNAM, Ciudad Universitaria, C.P. 04510 Mexico, D.F. (Mexico)

    2008-12-01

    The action of Desulfovibrio vulgaris (Dv) during a corrosion process has been reported in literature, but the influence of imidazoline in the formation of biofilms is not clear, as well as the effect of bacteria on the efficiency of the corrosion inhibitors. The aim of this work is to determine the behavior of bacteria in the presence of imidazoline. Therefore, the growth of Dv, isolated and characterized from a morphological point of view, was monitored during 21 days, during which synthetic seawater was used as the culture medium, according to the ASTM D665-98 standard. Electrochemical noise (EN) was employed to establish the corrosion type generated by the microorganism on an AISI 1018 steel cylinder. The attack was observed using scanning electron microscopy (SEM). In order to evaluate the efficiency of the corrosion inhibitor, Tafel extrapolation was used; the optimum concentration of the inhibitor was used in the presence of sulphate-reducing bacteria (SRB). In general, two forms of corrosion were observed: localized corrosion (in the LAG phase) and mixed corrosion (in the LOG phase)

  10. 国内废钢行业概况及废钢价格关联因素的量化研究%An overview of domestic scrap steel industry and quantitative research on correlative influencing factors of scrap steel price

    Institute of Scientific and Technical Information of China (English)

    陆明希; 张浩

    2011-01-01

    This paper introduced the scrap steel industry development in our country in the Tenth and Eleventh Five- Year periods, and demonstrated the recycling and supply, as well as consumption of scrap steel. A mathematics model was established about the correlative influencing factors of the scrap steel price to qualify the impact of the factors. This research could be helpful to the scrap steel market analysis.%介绍了“十五”和“十一五”时期国内废钢行业发展概况,重点阐述废铜行业的回收供应以及消耗情况,并对影响废钢价格的因素进行数学建模,对关联程度大小进行量化,对更好地分析废钢市场走势有较好的指导意义。

  11. Precipitates in electrical steels

    Energy Technology Data Exchange (ETDEWEB)

    Jenkins, Keith [Development and Market Research, Cogent Power Limited, Corporation Road, Newport, South Wales NP19 OXT (United Kingdom)], E-mail: keith.jenkins@cogent-power.com; Lindenmo, Magnus [Development and Market Research, Cogent Power Limited, Corporation Road, Newport, South Wales NP19 OXT (United Kingdom)

    2008-10-15

    Precipitates heavily influence the magnetic properties of electrical steels, either as a key controlled requirement as part of the manufacturing process or as an unwanted harmful residual in the final product. In this current work copper-manganese sulphides precipitates are the primary inhibitor species in the conventional grain-oriented (CGO) steels examined and grain boundary pinning is effective at a mean precipitate size of 30-70 nm. The growth of CuMnS has been studied and the results show that a precipitate size above {approx}100 nm allows the onset of secondary recrystallisation in the heating conditions applied. The effect of precipitates on the magnetic properties of both grain-oriented and non-oriented steels in their final product form is then examined. Examples of grain-oriented material still containing large numbers of precipitates clearly show the detrimental effects with increases in total power loss of 40% or more. Loss deterioration by about 20% is also seen in samples of high silicon non-oriented material in which titanium carbo-nitride precipitates have been observed. In this case the precipitates are believed to have formed during cooling after final annealing. Finally a grain-oriented steel with a large number of very small precipitates, which do not seem to have any harmful effect on the magnetic properties, is demonstrated.

  12. Real-time corrosion monitoring of steel influenced by microbial activity (SRB) under controlled seawater injection conditions

    Energy Technology Data Exchange (ETDEWEB)

    Kane, Russell D. [InterCorr International, Inc., 14503 Bammel N. Houston Road, Suite 300, Houston, TX 77019 (United States); Campbell, Scott [Commercial Microbiology Inc., 10400 Westoffice Drive Suite 107, Houston, TX 77042 (United States)

    2004-07-01

    An experimental study of microbiologically influenced corrosion (MIC) was conducted involving online, real-time monitoring of a bio-film loop under controlled conditions simulating oil field water handling and injection. Bio-film growth, MIC and biocide efficacy were monitored using an automated, multi-technique monitoring system including linear polarization resistance, electrochemical noise and harmonic distortion analysis. This data was correlated with conventional off-line methods to differentiate conditions of varying MIC activity in real-time to facilitate quick assessment and operator intervention. (authors)

  13. Effect of weld on design of steel moment-resisting connection reinforced with steel plates

    Institute of Scientific and Technical Information of China (English)

    CHEN Peng; LI Yong

    2005-01-01

    The foreign experimental and FEM research of steel moment-resisting connection reinforced with steel plates are introduced. The effect of weld on the connection design is studied in two ways including weld detail and geometrical detail of steel plates contrast to the reference drawing of connection design in China. The research shows that the weld plays an important role in the design of connections. The welds connecting reinforced plates and beam/ column flange and the plate geometry have direct influence on the performance of the connections reinforced with plates. The study is helpful to the application of design of steel moment-resisting connection with steel plates.

  14. 铝氮比对轿车用渗碳钢晶粒混晶的影响%INFLUENCE OF ALUMINUM-NITROGEN RATE ON MIXEDG RAIN STRU CTURE OF20 MnCr 5 CARBURIZING STEEL FOR CAR

    Institute of Scientific and Technical Information of China (English)

    齐建军; 李绍杰

    2015-01-01

    在转炉长流程生产工艺条件下,研究了铝含量、氮含量和铝氮比对轿车用20MnCr5渗碳钢晶粒度混晶的影响。结果表明,在规定的热处理工艺条件下,20MnCr5渗碳齿轮钢产生混晶的主要原因是钢中氮含量偏低。当20MnCr5钢中铝含量≥00.25%且铝氮比≥3时,可以达到轿车渗碳钢对奥氏体晶粒度的要求。%It is researched the influence of contents of aluminum and nitrogen and their proportion on mixed grain size of 20MnCr5 carburizing steel for cars in long process of converter.The result shows that under the specified heat treatment process, the main reason for mixed grain in 20MnCr5 carburizing gear steel is too low nitrogen content in steel.The demand of car carburizing steel for austenite brain size can be met if the a-luminum content not being lower than 0.025%and aluminum-nitrogen proportoi n notb eing smallert han 3.

  15. Influence of carbon content on superplastic behaviour in Ti and B doped Cr-Mo steels; Ti, B tenka kuromu moribudenko no chososei ni oyobosu tanso gan`yuryo no eikyo

    Energy Technology Data Exchange (ETDEWEB)

    Aramaki, M.; Nakai, O.; Onodera, R.; Higashida, K. [Kyushu University, Fukuoka (Japan). Faculty of Engineering

    1997-12-01

    Superplasticity has been investigated in various ferrous alloys and steels. However, in these materials, especially in the hypoeutectoid steel bellow A1 temperature, the relationship between the content of carbon and elongation to failure is not obvious. In the present investigation, the influence of carbon content on superplastic behaviour is studied using carbon steels based on Cr-Mo steel. In order to obtain the fine grain structure, a small amount of Ti and B were added and the content of carbon was controlled to be in the range of 0.24% to 0.83%. The largest value of elongation to failure was 644% which was obtained by the tensile test of the specimen containing 0.58% carbon. The temperature and strain rate at which the maximum value was obtained were 710degC and 5 times 10{sup -4}s{sup -1}, respectively. Of all the specimens, this. specimen had the minimum grain size. Moreover, the area fraction of carbide took the maximum value at the temperature where the largest elongation value was obtained. These results show that the addition of carbon has an effect on grain refinement by formation of carbide, but excess amounts of carbons (>0.6%) bring about premature failure because of coarse microstructure and larger carbide. 17 refs., 9 figs., 1 tab.

  16. Investigation of influence of structure and TiAl3/TiAlN intermetallic coatings on the corrosion behavior of martensitic steels

    Science.gov (United States)

    Vardanyan, E.; Ramazanov, K.; Yagafarov, I.; Khamzina, A.; Agzamov, R.

    2017-05-01

    The paper considers several approaches to protect martensitic steels with ultrafine-grain (UFG) structure in aggressive environments. Scanning electron microscopy was used to study the microstructure and composition of steel substrates and coatings. The samples were also subjected to corrosion tests. Regularities of corrosion behavior were specified for the UFG steels. The samples were subjected to ion nitriding in a glow discharge and deposition of protective TiAl3/TiAlN coatings in vacuum arc discharge plasma. Corrosion rates were identified for different treatments.

  17. Influence of turbulent flow on the corrosion kinetics of API X52 pipeline steel in aqueous solutions containing H{sub 2}S

    Energy Technology Data Exchange (ETDEWEB)

    Galvan-Martinez, Ricardo; Genesca-Llongueras, Juan [Departamento Ingenieria Metalurgica, Facultad Quimica, Universidad Nacional Autonoma de Mexico, UNAM, Ciudad Universitaria, 04510 Mexico D.F. (Mexico); Mendoza-Flores, Juan; Duran-Romero, Ruben [Corrosion, Instituto Mexicano del Petroleo, Eje Central Lazaro Cardenas 152, 07730 Mexico D.F. (Mexico)

    2004-07-01

    A corrosion process can be influenced by the relative movement between the corroding environment and the metal. This relative movement could increase the heat transfer and the mass transfer of reactants towards and from the surface of the corroding metal, with a consequent increase in the corrosion rate. Also, if solid particles are present, removal of protective films, erosion and wear can occur on the metallic surface. Many industrial processes involve the movement of corrosive liquids in close contact to metallic structures. Therefore, the influence of flow on the corrosion processes is an important issue to be considered in the design and operation of industrial equipment. This influence is complex and many variables are involved. Several observations of flow-accelerated corrosion problems have been documented, particularly in the oil and gas industries, where the combined effect of flow and dissolved gases, such as hydrogen sulphide (H{sub 2}S) and carbon dioxide (CO{sub 2}), is important. Turbulent flow conditions are commonly found in industrial processes. However, few corrosion studies in controlled turbulent flow conditions are available. With the increasing necessity to describe the corrosion of metals in turbulent flow conditions some laboratory hydrodynamic systems have been used with different degrees of success. The use of the rotating cylinder electrode (RCE), as a laboratory hydrodynamic test system, has gained popularity in corrosion studies. This popularity is due to its characteristics, such as, its operation mainly at turbulent flow conditions; its well understood mass transfer properties and its easiness of construction and operation. The aim of the present work is to explore the effect that turbulent flow conditions have on the electrochemical kinetics of steel samples immersed in aqueous environments containing H{sub 2}S. In order to control the turbulent flow conditions in the laboratory, a rotating cylinder electrode (RCE) was used. In

  18. Influence of plastic strain localization on the stress corrosion cracking of austenitic stainless steels; Influence de la localisation de la deformation plastique sur la CSC d'aciers austenitiques inoxydables

    Energy Technology Data Exchange (ETDEWEB)

    Cisse, S.; Tanguy, B. [CEA Saclay, DEN, SEMI, 91 - Gif-sur-Yvette (France); Andrieu, E.; Laffont, L.; Lafont, M.Ch. [Universite de Toulouse. CIRIMAT, UPS/INPT/CNRS, 31 - Toulous (France)

    2010-03-15

    The authors present a research study of the role of strain localization on the irradiation-assisted stress corrosion cracking (IASCC) of vessel steel in PWR-type (pressurized water reactor) environment. They study the interaction between plasticity and intergranular corrosion and/or oxidation mechanisms in austenitic stainless steels with respect to sublayer microstructure transformations. The study is performed on three austenitic stainless grades which have not been sensitized by any specific thermal treatment: the A286 structurally hardened steel, and the 304L and 316L austenitic stainless steels

  19. Influence of Fluoride Content of Artificial Saliva on Metal Release from 17-4 PH Stainless Steel Foam for Dental Implant Applications

    Institute of Scientific and Technical Information of China (English)

    Ilven Mutlu; Enver Oktay

    2013-01-01

    Highly porous 17-4 PH stainless steel foam for implant applications was produced by space holder technique.Metal release and weight loss from 17-4 PH stainless steel foams were investigated in fluoride added artificial saliva environment by static immersion test.An inductively coupled plasma-mass spectrometer was employed to measure the concentrations of various metal ions.Effects of fluoride content of artificial saliva on metal release and weight loss from the steel foams were investigated.Effects of immersion time,pH value and process parameters on the weight loss and metal release were determined.Pore morphology,pore size and mechanical properties of the 17-4 PH stainless steel foams were also characterized.

  20. INFLUENCE OF THE MODERN SYSTEMS OF THE BLAST STEEL-FURNACE ELECTRICAL PARAMETERS CONTROL ON CAPACITY AND TECHNICAL AND ECONOMICAL INDICES OF MELTING

    Directory of Open Access Journals (Sweden)

    D. N. Andrianov

    2006-01-01

    Full Text Available The reduction of time under the current, electric energy rate, electrodes rate at working of arc steel-furnace with new transformer of capacity 95 MBA and with regulating system SIMELT-AC-NEC are noted.

  1. Influence of Nitrided Layer on The Properties of Carbon Coatings Produced on X105CrMo17 Steel Under DC Glow-Discharge Conditions

    Directory of Open Access Journals (Sweden)

    Tomasz BOROWSKI

    2016-09-01

    Full Text Available In most cases, machine components, which come in contact with each other, are made of steel. Common steel types include 100Cr6 and X105CrMo17 are widely used in rolling bearings, which are subjected to high static loads. However, more and more sophisticated structural applications require increasingly better performance from steel. The most popular methods for improving the properties of steel is carburisation or nitriding. Unfortunately, when very high surface properties of steel are required, this treatment may be insufficient. Improvement of tribological properties can be achieved by increasing the hardness of the surface, reducing roughness or reducing the coefficient of friction. The formation of composite layers on steel, consisting of a hard nitride diffusion layer and an external carbon coating with a low coefficient of friction, seems to be a prospect with significant potential. The article describes composite layers produced on X105CrMo17 steel and defines their morphology, surface roughness and their functional properties such as: resistance to friction-induced wear, coefficient of friction and corrosion resistance. The layers have been formed at a temperature of 370°C in successive processes of: nitriding in low-temperature plasma followed by deposition of a carbon coating under DC glow-discharge conditions. An evaluation was also made of the impact of the nitrided layers on the properties and morphology of the carbon coatings formed by comparing them to coatings formed on non-nitrided X105CrMo17 steel substrates. A study of the surface topography, adhesion, resistance to friction-induced wear and corrosion shows the significant importance of the substrate type the carbon coatings are formed on.DOI: http://dx.doi.org/10.5755/j01.ms.22.3.7532

  2. The Influence of Technological Parameters of X70 Stainless Steel Ladle Refining on the Residual Content of Non-Metallic Inclusions

    Directory of Open Access Journals (Sweden)

    Babanin A.

    2015-09-01

    Full Text Available It is demonstrated that during secondary refining at the ladle furnace the carbon content of steel and the residence time of the metal in the ladle exert a significant impact on the residual content of non-metallic inclusions (NMI in steel. Mathematical calculations showed that the dynamic forces have minor effect on the motion of small sized NMI, making it difficult to penetrate deep into the slag.

  3. Influence of stress relief annealing on the microstructure and properties of GX12CrMoVNbN9-1(GP91 cast steel

    Directory of Open Access Journals (Sweden)

    G. Golański

    2011-04-01

    Full Text Available The paper presents an effect of stress relief annealing, applied to casts after the repair by welding, on the microstructure and mechanical properties of quenched and tempered martensitic GX12CrMoVNbN9 – 1 cast steel (called GP91. The test pieces being the subject of research were taken out from a test coupon. Heat treatment of GP91 cast steel was carried out at the parameters of temperature and time appropriate for the treatment of multi-ton steel casts, while stress relief annealing was performed at the temperatures of 730 and 750oC.After quenching and tempering GP91 cast steel was characterized by the microstructure of high-tempered martensite with numerousprecipitations of carbides of diverse size. Mechanical properties of the investigated cast steel after heat treatment fulfilled the standard requirements. Stress relief annealing contributes to the processes of recovery and recrystallization of the matrix as well as the privileged precipitation of M23C6 carbides on grain boundaries. Changes in the microstructure of the examined cast steel cause deterioration in mechanical properties – the higher the temperature of stress relief annealing, the greater the deterioration.

  4. Influence of temperature on the hydrogen evolution reaction on stainless steels in LiBr solution by means of polarization techniques

    Energy Technology Data Exchange (ETDEWEB)

    Guinon Pina, V.; Igual-Munoz, A.; Garcia-Anton, J. [Valencia Univ. Politecnica, Dept. de Ingenieria Quimica y Nuclear. ETSI Industriales, Valencia (Spain)

    2009-07-01

    Lithium Bromide aqueous solutions used as absorbent in refrigeration machines can cause serious corrosion problems which also facilitate the hydrogen evolution reaction (HER) in the cathodic regions. Hydrogen formation is an important problem in the operating conditions of adsorption machines because they operate under low pressure conditions. Hydrogen generation makes pressure to increase and as a consequence efficiency decreases. Duplex Stainless Steels (DSS) are iron-based alloys with a two-phase microstructure: austenite and delta ferrite in approximately similar percentages. DSS find increasing use as an alternative to austenitic stainless steels, particularly where aggressive anions such as bromide are present in high concentrations. The objective of the present work is to study the effect of temperature on the hydrogen evolution reaction (HER) of two different stainless steels, Austenitic and Duplex steels, using different electrochemical techniques: Open Circuit Potential (OCP), potentiodynamic and galvano-static measurements and image digital analysis. The HER was studied in 992 g/l LiBr at three different temperatures (25, 50 and 75 C). The results showed that the electrocatalytic activity for the HER increased with temperature. The energy consumption for hydrogen generation on Austenitic Stainless Steel, UNS N08031, is lower than on Duplex Stainless Steel, EN 1.4462, at the studied temperatures. (authors)

  5. Tempering-Induced Microstructural Changes in the Weld Heat-Affected Zone of 9 to 12 Pct Cr Steels and Their Influence on Sliding Wear

    Science.gov (United States)

    Velkavrh, Igor; Kafexhiu, Fevzi; Klien, Stefan; Diem, Alexander; Podgornik, Bojan

    2017-01-01

    Increasing amount of tribological applications is working under alternating high/low temperature conditions where the material is subjected to temperature fatigue mechanisms such as creep, softening due to annealing, and at the same time must withstand mechanical wear due to sliding contact with pairing bodies. Steam turbine valves, gate valves, valve heads, stems, seats and bushings, and contacting surfaces of the carrier elements are some examples of such applications. The purpose of the present study is to evaluate the potential of X20 and P91 steels as materials for applications operating under combined effect of mechanical wear and alternating high/low temperature conditions. It was focused on how the microstructural changes occurring in the weld zone affect the wear properties of the selected materials. Generally, with longer tempering time and higher tempering temperature, the number of carbide precipitates decreased, while their relative spacing increased. Before tempering, the morphology of the steel matrix (grain size, microstructure homogeneity) governed the wear resistance of both steels, while after tempering wear response was determined by the combination of the number and the size of carbide particles. After tempering, in X20 steel larger number of stable M23C6 carbides was observed as compared with P91 steel, resulting in lower wear rates. It was observed that for both steels, a similar combination of number density and size distribution of carbide particles provided the highest wear resistance.

  6. Influence of the working electrode area on the cavitation-corrosion behaviour of a duplex stainless steel in aqueous LiBr solution

    Energy Technology Data Exchange (ETDEWEB)

    Garcia-Garcia, D.M.; Blasco-Tamarit, E.; Igual-Munoz, A.; Garcia-Anton, J. [Valencia Univ. Politecnica, Dept. de Ingenieria Quimica y Nuclear. ETSI Industriales, Valencia (Spain)

    2009-07-01

    Cavitation erosion can occur in almost all hydrodynamic systems and turbo machines, e.g. pumps, valves, marine propeller and hydraulic turbines. It causes serious material damage. Corrosion problems associated with cavitation can appear on different points in LiBr absorption machines. Many efforts have been made to solve this problem, such as optimizing the design of the flow-handling component and selecting better materials and coatings to resist the cavitation erosion-corrosion. A better understanding of cavitation erosion-corrosion mechanisms is very important for the selection materials and coatings. The objective of the present work was to study the influence of the exposed area of the working electrode on the corrosion behaviour of a duplex stainless steel (EN 1.4462) in a 992 g/l LiBr solution under static conditions (without cavitation) and dynamic conditions (with cavitation) at 25 C. Potentiodynamic cyclic curves were obtained under static and dynamic conditions exposing different areas of the working electrode: 1.6 mm diameter (0.02 cm{sup 2} area ), 4 mm diameter (0.12 cm{sup 2} area), 6 mm diameter (0.28 cm{sup 2} area) and 8 mm diameter (0.5 cm{sup 2} area). The dynamic conditions were generated using an ultrasonic cavitation facility in a three-electrode electrochemical cell. The Potentiodynamic Cyclic curves obtained with and without cavitation have been compared and different tendencies were observed. Cavitation increased the cathodic current density when the exposed area to the solution is large (6 mm and 8 mm diameters). This behaviour was not observed during the tests with smaller electrode areas (1.6 mm and 4 mm diameters). In all cases, cavitation increased the anodic current densities independently of the exposed area to the solution. Besides, cavitation favoured the pitting corrosion, since lower pitting potentials were obtained under cavitation conditions than under static conditions. (authors)

  7. Influence of non-smooth surface on tribological properties of glass fiber-epoxy resin composite sliding against stainless steel under natural seawater lubrication

    Science.gov (United States)

    Wu, Shaofeng; Gao, Dianrong; Liang, Yingna; Chen, Bo

    2015-11-01

    With the development of bionics, the bionic non-smooth surfaces are introduced to the field of tribology. Although non-smooth surface has been studied widely, the studies of non-smooth surface under the natural seawater lubrication are still very fewer, especially experimental research. The influences of smooth and non-smooth surface on the frictional properties of the glass fiber-epoxy resin composite (GF/EPR) coupled with stainless steel 316L are investigated under natural seawater lubrication in this paper. The tested non-smooth surfaces include the surfaces with semi-spherical pits, the conical pits, the cone-cylinder combined pits, the cylindrical pits and through holes. The friction and wear tests are performed using a ring-on-disc test rig under 60 N load and 1000 r/min rotational speed. The tests results show that GF/EPR with bionic non-smooth surface has quite lower friction coefficient and better wear resistance than GF/EPR with smooth surface without pits. The average friction coefficient of GF/EPR with semi-spherical pits is 0.088, which shows the largest reduction is approximately 63.18% of GF/EPR with smooth surface. In addition, the wear debris on the worn surfaces of GF/EPR are observed by a confocal scanning laser microscope. It is shown that the primary wear mechanism is the abrasive wear. The research results provide some design parameters for non-smooth surface, and the experiment results can serve as a beneficial supplement to non-smooth surface study.

  8. Influence of Non-smooth Surface on Tribological Properties of Glass Fiber-epoxy Resin Composite Sliding against Stainless Steel under Natural Seawater Lubrication

    Institute of Scientific and Technical Information of China (English)

    WU Shaofeng; GAO Dianrong; LIANG Yingna; CHEN Bo

    2015-01-01

    With the development of bionics, the bionic non-smooth surfaces are introduced to the field of tribology. Although non-smooth surface has been studied widely, the studies of non-smooth surface under the natural seawater lubrication are still very fewer, especially experimental research. The influences of smooth and non-smooth surface on the frictional properties of the glass fiber-epoxy resin composite (GF/EPR) coupled with stainless steel 316L are investigated under natural seawater lubrication in this paper. The tested non-smooth surfaces include the surfaces with semi-spherical pits, the conical pits, the cone-cylinder combined pits, the cylindrical pits and through holes. The friction and wear tests are performed using a ring-on-disc test rig under 60 N load and 1000 r/min rotational speed. The tests results show that GF/EPR with bionic non-smooth surface has quite lower friction coefficient and better wear resistance than GF/EPR with smooth surface without pits. The average friction coefficient of GF/EPR with semi-spherical pits is 0.088, which shows the largest reduction is approximately 63.18% of GF/EPR with smooth surface. In addition, the wear debris on the worn surfaces of GF/EPR are observed by a confocal scanning laser microscope. It is shown that the primary wear mechanism is the abrasive wear. The research results provide some design parameters for non-smooth surface, and the experiment results can serve as a beneficial supplement to non-smooth surface study.

  9. High Nitrogen Stainless Steel

    Science.gov (United States)

    2011-07-19

    Kiev, 1993. 7. High Nitrogen Steels, edited by M. Kikuchi and Y. Mishima , Vol. 36, No. 7, Iron and Steel Institute of Japan Inernational, Tokyo...the Corrosion of Iron and Steels,” High Nitrogen Steels, edited by M. Kikuchi and Y. Mishima , Vol. 36, No. 7, Iron and Steel Institute of Japan

  10. Microbiologically influenced corrosion evaluation on brass (UNS C68700, UNS C443) and AISI 316 stainless steel; Estudio de la influencia microbiologica en la corrosion de latones (UNS C68700, UNS C443) y acero inoxidable AISI 316

    Energy Technology Data Exchange (ETDEWEB)

    Ohanian, M.; Diaz, V.; Corengia, M.; Russi, P.; Pianzzola, M. J.; Menes, R. J.

    2014-10-01

    Microorganisms may play an important role in the corrosion process and generate conditions which affect the rate and/or the mechanism of deterioration. They become visible by the formation of bio films: clusters of microorganisms and extracellular polymers. These bio films affect not only the durability of the material, but also reduce the heat transfer. The present work studied the growth of aerobic and anaerobic heterotrophic microorganisms and sulfate reducing bacteria on aluminum brass (Uns C.a.), admiralty brass (Uns C.a.) and stainless steel Asi 316 in exposure experiments held in the Bay of Montevideo (Uruguay). The influence of the biofilm growth on the corrosion behavior was studied by electrochemical techniques: polarization curves and Electrochemical Impedance Spectroscopy (Ei). The selection of the most suitable material for the exposure conditions is discussed and hypotheses of the corrosion mechanism are presented. Although stainless steel Asi 316 presented the lowest corrosion rate it showed localized deterioration. (Author)

  11. Influence of plasma nitro carburization on fatigue properties in a 4340 steel with different microstructure; Infuencia da nitrocarbonetacao a plasma nas propriedades de fadiga de um aco 4340 com diferentes microestruturas

    Energy Technology Data Exchange (ETDEWEB)

    Ranieri, A.; Hashimoto, T.M. [UNESP, Guaratingueta, SP (Brazil). Faculdade de Engenharia (FEG); Baggio-Scheid, V.H.; Abdalla, A.J., E-mail: abdalla@ieav.cta.b [Departamento de Ciencia e Tecnologia Aeroespacial (IEAv/DCTA), Sao Jose dos Campos, SP (Brazil). Inst. de Estudos Avancados

    2010-07-01

    Three different routes of heat treatments were applied in samples of 4340 steel in order to modify the microstructures and mechanical properties. After this initial treatment was applied a plasma nitrocarburizing thermochemical treatment in a part of the samples, forming a layer of nitride (Fe{sub 4}N and Fe{sub 3}N{sub 2}) of about 10{mu}m, with high hardness, in order to improve the surface characteristics. The layer and microstructure were characterized with X-ray analysis, optical microscopy, confocal laser scanning and hardness test by microindentation. Tensile and fatigue tests show the influence of microstructure formed on the mechanical properties, the microstructure predominantly bainitic phase showed a better combination of ductility, toughness and fatigue life. After treatment nitrocarburizing was observed the effect of tempering, with a reduction in hardness of substrate and tensile strength. In steel with martensitic microstructure the fatigue life decreases. (author)

  12. The influence of biosurfactant adsorption on the physicochemical behaviour of carbon steel surfaces using contact angle measurements and X-ray photoelectron spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Shubina, V., E-mail: varvara.shubina2014@gmail.com [LUNAM Université, IFSTTAR, MAST, SMC, F-44340 Bouguenais (France); Gaillet, L. [LUNAM Université, IFSTTAR, MAST, SMC, F-44340 Bouguenais (France); Ababou-Girard, S. [Institut de Physique de Rennes, Département Matériaux et Nanosciences, UMR 6251 CNRS, Université Rennes 1, 35000 Rennes-Cedex (France); Gaudefroy, V. [LUNAM Université, IFSTTAR, MAST, SMC, F-44340 Bouguenais (France); Chaussadent, T.; Farças, F. [Université Paris-Est, IFSTTAR, MAST, CPDM, F-77447 Marne-la-Vallée (France); Meylheuc, T. [INRA, UMR1319 Micalis, F-78352 Jouy-en-Josas (France); AgroParisTech, UMR Micalis, F-78352 Jouy-en-Josas (France); Dagbert, C. [2 Chemin de la Grand’côte, 36270 Éguzon-Chantôme (France); Creus, J. [LaSIE, UMR7356, Université de La Rochelle, Pôle Sciences et Technologie, Bâtiment Marie Curie, Avenue Michel Crépeau, 17000 La Rochelle (France)

    2015-10-01

    Highlights: • Surface modifications to carbon steel surfaces due to the adsorption of a biosurfactant derived from Pseudomonas fluorescens bacteria cells were investigated using contact angle measurements (CAM) and X-ray photoelectron spectroscopy (XPS). • CAM allowed to establish an increase of electron-donating properties of steel surface due to the biosurfactant adsorption. • XPS demonstrated that biosurfactant molecules change the stoichiometry of mixted-oxide layer and the new outer layer mostly composed of magnetite. • Thickness and density of adsorbed biosurfactants layers were highlighted using a semiquantitative approach for 3 different concentrations of biomolecules. - Abstract: We investigated modifications to carbon steel surfaces due to the adsorption of a biosurfactant derived from Pseudomonas fluorescens bacteria cells using contact angle measurements (CAM) and X-ray photoelectron spectroscopy (XPS). After conditioning carbon steel in solutions with three different concentrations of biosurfactant molecules: 0.05, 0.3 and 1 g L{sup −1}, the average thickness of the biosurfactant layer on the carbon steel specimens was 7.9 ± 0.3, 12.1 ± 0.5 and 16.4 ± 0.7 Å, respectively. The biosurfactants changed the composition of both the Fe{sup 2+} and Fe{sup 3+} mixed-oxide layer and the outer layer, mostly composed of Fe{sup 3+} associated with magnetite. Contact angle measurements indicate decreased hydrophobic properties after the carbon steel was modified by biosurfactant. It was shown that the carbon steel surface free energy depends on the biosurfactant concentration, due to an acquisition of strong electron-donating properties.

  13. Influence of Vanadium and Boron Additions on the Microstructure, Fracture Toughness, and Abrasion Resistance of Martensite-Carbide Composite Cast Steel

    Directory of Open Access Journals (Sweden)

    Waleed Elghazaly

    2016-01-01

    Full Text Available High chromium cast steel alloys are being used extensively in many industrial services where dry or wet abrasion resistance is required. Such steel castings are demanded for cement, stoneware pipes, and earth moving industries. In this research, five steel heats were prepared in 100 kg and one-ton medium frequency induction furnaces and then sand cast in both Y-block and final impact arm spare parts, respectively. Vanadium (0.5–2.5% and boron (120–150 ppm were added to the 18Cr-1.9C-0.5Mo steel heats to examine their effects on the steel microstructure, mechanical properties especially impact, fracture toughness and abrasion resistance. Changes in the phase transformation after heat treatment were examined using inverted, SEM-EDX microscopy; however, the abrasion resistance was measured in dry basis using the real tonnage of crushed and milled stoneware clay to less than 0.1 mm size distribution.

  14. Influences of Temperature and pH Value on the Corrosion Behaviors of X80 Pipeline Steel in Carbonate/Bicarbonate Buffer Solution

    Institute of Scientific and Technical Information of China (English)

    LI,Jin-Bo; ZUO,Jian-E

    2008-01-01

    The joint effect of temperature and pH value on the corrosion behavior of X80 steel in carbonate/bicarbonate buffer solution was detected by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and Mott-Schottky analysis. The results show that an unstable corrosion film will be formed on the X80 steel surface in low pH value solutions, and a better protective corrosion film can be formed on the X80 steel surface in high pH value solutions. On the whole, the corrosion film resistance and transfer resistance increase with the increment of pH value, and decrease with increase of solution temperature, which indicates that the protective effect of the corrosion film on X80 steel is enhanced with increasing pH value and decreasing the solution temperature. The corrosion film formed on X80 steel surface in carbonate/bicarbonate buffer solution has an n-type semi-conductive character, and the donor density decreases with increasing the pH value, and increases with increasing the solution temperature. The flat-band potential and pH value have a linear relationship with a positive slope.

  15. An investigation of microbial diversity in crude oil & seawater injection systems and microbiologically influenced corrosion (MIC) of linepipe steels under different exposure conditions

    Science.gov (United States)

    AlAbbas, Faisal Mohammed

    During oil and gas operations, pipeline networks are subjected to different corrosion deterioration mechanisms that result from the interaction between the fluid process and the linepipe steel. Among these mechanisms is microbiologically influenced corrosion (MIC) that results from accelerated deterioration caused by different indigenous microorganisms that naturally reside in the hydrocarbon and associated seawater injection systems. The focus of this research is to obtain comprehensive understanding of MIC. This work has explored the most essential elements (identifications, implications and mitigations) required to fully understand MIC. Advanced molecular-based techniques, including sequencing of 16S rRNA genes via 454 pyrosequencing methodologies, were deployed to provide in-depth understanding of the microbial diversity associated with crude oil and seawater injection systems and their relevant impact on MIC. Key microbes including sulfate reducing bacteria (SRB) and iron reducing bacteria (IRB) were cultivated from sour oil well field samples. The microbes' phylotypes were identified in the laboratory to gain more thorough understanding of how they impact microbial corrosion. Electrochemical and advanced surface analytical techniques were used for corrosion evaluations of linepipe carbon steels (API 5L X52 and X80) under different exposure conditions. On the identification front, 454 pyrosequencing of both 16S rRNA genes indicated that the microbial communities in the corrosion products obtained from the sour oil pipeline, sweet crude pipeline and seawater pipeline were dominated by bacteria, though archaeal sequences (predominately Methanobacteriaceae and Methanomicrobiaceae) were also identified in the sweet and sour crude oil samples, respectively. The dominant bacterial phylotypes in the sour crude sample included members of the Thermoanaerobacterales, Synergistales, and Syntrophobacterales. In the sweet crude sample, the dominant phylotypes included

  16. Reactive-inspired ball-milling synthesis of an ODS steel: study of the influence of ball-milling and annealing; Synthese et caracterisation d'un acier ODS prepare par un procede inspiredu broyage reactif: etude de l'influence des conditions de broyage et recuit

    Energy Technology Data Exchange (ETDEWEB)

    Brocq, M.

    2010-10-15

    In the context of the development of new ODS (Oxide Dispersion Strengthened) steels as core materials in future nuclear reactors, we investigated a new process inspired by reactive ball-milling which consists in using YFe{sub 3} andFe{sub 2}O{sub 3} as starting reactants instead of Y{sub 2}O{sub 3} to produce a dispersion of nano-oxides in a steel matrix and the influence of synthesis conditions on the nano-oxide characteristics were studied. For that aim, ODS steels were prepared by ball-milling and then annealed. Multi-scale characterizations were performed after each synthesis step, using notably atom probe tomography and small angle neutron scattering. The process inspired by reactive ball-milling was shown to be efficient for ODS steel synthesis, but it does not modify the nano-oxide characteristics as compared to those of oxides directly incorporated in the matrix by ball-milling. Broadly speaking, the nature of the starting oxygen bearing reactants has no influence on nano-oxide formation. Moreover, we showed that the nucleation of nano-oxides nucleation can start during milling and continues during annealing with a very fast kinetic. The final characteristics of nano-oxides formed in this way can be monitored through ball-milling parameters (intensity, temperature and atmosphere) and annealing parameters (duration and temperature). (author)

  17. Influence of Fouling Assemblage on the Corrosion Behaviour of Mild Steel in the Coastal Waters of The Gulf of Mannar, India

    Institute of Scientific and Technical Information of China (English)

    G. Subramanian; S. Palanichamy

    2013-01-01

    Corrosion behaviour and biofouling characteristics of mild steel in three different coastal locations in the Gulf of Mannar, India have been studied over a period of 24 months. Oyster fouling was predominant at Open sea - Tuticorin, while barnacle fouling was dominant at both Mandapam and Harbour-Tuticorin. The rate of corrosion for 24 months exposure period was highest at Mandapam, where fouling was minimal. The surface of the mild steel was characterized by etchings & crevices beneath the hard foulers attached on it, at all the test locations. The depth of crevice caused by hard foulers was higher at Open sea-Tuticorin followed by Harbour-Tuticorin and Mandapam. The loss in ultimate tensile strength was more in Open sea - Tuticorin than the other two locations. Corrosion behaviour of mild steel is discussed based on the variation in the biofouling assemblage at the three test locations.

  18. Influence of obliquity effect on the ballistic performance of high strength steel plate%倾角效应对高强度钢板抗弹性能的影响

    Institute of Scientific and Technical Information of China (English)

    肖红亮; 李晓源; 时捷; 韩赟; 曹文全; 雍岐龙

    2011-01-01

    选择53式7.62 mm普通弹和53式7.62 mm穿燃弹两种弹型,对不同厚度的高强度马氏体均质钢板和有孔结构钢板进行抗弹性能试验.研究对应不同的弹丸类型和钢板结构时,倾角效应对抗弹性能的影响.结果表明,53普通弹和53穿燃弹冲击时,倾斜角增大,均质钢板抗弹性能均提高.钢板防护53普通弹时的抗弹性能对倾斜角不敏感,而钢板防护53穿燃弹时的抗弹性能对倾斜角敏感.弹丸以跳飞角入射时,钢板防护53普通弹和53穿燃弹的临界厚度基本相当.有孔结构钢板在大角度倾斜抗弹时,抗弹性能较好;在垂直抗弹时,孔结构导致的边缘效应明显降低钢板的抗弹性能.%Ballistic resistance tests were carried out on high-strength martensitic homogeneous steel plates with different thickness and the perforated steel plates, using 53-type ordinary ball and 53-type armor-piercing incendiary. The influence of obliquity effect on the ballistic performance under the different types of bullet and the structure of plates was studied. The results show that with the oblique angle increasing, the ballistic performance of homogeneous steel plates against the 53-type ordinary ball and 53-type armor-piercing incendiary increases. Moreover, ballistic performance against the 53-type ordinary ball is not sensitive to oblique angle, while it is contrary for 53-type armor-piercing incendiary. When the steel plate is impacted at ricochet angle, the critical thickness of plate against 53-type ordinary ball and 53-type armor-piercing incendiary is roughly equal. The perforated steel plate impacted at large oblique angle has preferable ballistic performance; while at normal impact, the ballistic performance of the perforated steel plate deteriorates obviously by edge effect.

  19. 钢弹簧浮置板轨道对车内噪声影响的实测与分析%Measurement and Analysis of Influence of Steel Spring Floating Slab Track on Vehicle Interior Noise

    Institute of Scientific and Technical Information of China (English)

    肖安鑫; 田野

    2012-01-01

    When a train passes through on steel spring floating slab, intermediate and low frequency noises will be generated in its vehicles. Such noises will reduce the traveling comfort. In this paper, the vehicle' s interior noises of floating slab in different tracks are compared and analyzed. The influence of steel spring floating slab track on vehicle' s interior noise is analyzed. The results show that the floating slab track with high damping steel spring can effectively reduce the interior noise.%在列车经过钢弹簧浮置板地段时,车内产生中低频噪声,影响着人们乘车环境舒适性.通过对不同钢弹簧浮置板轨道地段车内噪声的对比测试,分析钢弹簧浮置板轨道对车内噪声的影响,结果表明采用高阻尼钢弹簧浮置板轨道可有效降低车内噪声.

  20. Influence of the heat treatment on the cold deformation od duplex stainless steels; Influencia de los tratamientos termicos en la deformacion en frio de los aceros inoxidables duplex

    Energy Technology Data Exchange (ETDEWEB)

    Fargas, G.; Manero, J. M.; Anglada, M.; Mateo, A.

    2004-07-01

    The purpose of this paper is to study the compression behavior of a duplex stainless steel after several annealing conditions, in order to simulate the response during cold rolling in the industrial process. For each studied condition, stress-strain curves present serrations in the flow zone due to austenite and ferrite twinning and the austenite phase transformation to martensite. At the same time, it is shown that sigma phase increases the strength and diminish the cold deformation capacity of the steel. (Author) 15 refs.