Scientific Electronic Library Online (English)

Abstract in english Frontal weapon is the term used to designate the apparatus consisting of frontal gland and associated structures that participate in the chemical defense of termite soldiers. The ultra structure of the frontal gland and the scanning microscopy of the soldier head was investigated in the termite Amiitermes euamignathus Silvestri, 1901.Campaniform sensilla was not observed but there were 80 to100 sensory bristles around the frontal pore. The glandular epithelium shows only (more) class 1 cells according 10 the classification of NOIROT & QUENNEDEY (1974, 1991). The glandular cells are characterized by apical microvilli, a basal labyrinth and a large quantity of smooth endoplasmic reticulum which forms dense zones throughout the cytoplasm. The secretion is concentrated mainly in the basal pole of the cell and consists of large lipid droplets. The secretory epithelium is covered by a thick apical cuticle composed of a thin ...

Energy Technology Data Exchange (ETDEWEB)

A mathematical model was developed to simulate the combustion process of a direct injection diesel engine. The model considers the key features of such a combustion process; namely fuel droplet evaporation, spray formation, mixing, ignition of heterogeneous burning of the fuel. To model mixing, great emphasis was placed on treating both large and small scale aspects of mixing, the model divides the combustion chamber into three distinct regions of air, fuel spray, and a turbulent plume that is formed once ignition occurs. The fuel spray itself is considered to be composed of multiple zones, which in turn are made of cells of equal mass and of different thermodynamic states. Micromixing of the fuel and air cells, within each zone of the jet and the turbulent plume, is then achieved by utilizing the concept of Monte Carlo stochastic coalescence dispersion technique. The frequency of such cell interactions within each ...

Science.gov (United States)

Observational evidence is presented for the nucleation of condensation nuclei (CN) in the clear air adjacent to an isolated, marine, cumulus cloud. Two separate regions of particle nucleation are identified: one located above the cloud top, and the second located downwind of the cloud near the level of the anvil outflow. The regions of high CN concentrations were located in extremely clean marine air, with unactivated aerosol surface area (excluding the nucleation mode) less than 2 sq micrometers/cu cm, air temperature -31 C, and higher relative humidities than the undisturbed environment. Vertical profile measurements downwind of the cloud showed that CN concentrations at the level of the anvil outflow (4.9 km) were 8 times greater than at any other level between the surface and 5.3 km. A conceptual model is formulated in which aerosol particles, sulfur dioxide (SO2), sulfuric acid vapor (H2SO4), dimethyl sulfide (DMS), and ozone (O3) from the boundary layer are ...

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This project is aimed at development of optimum combustion technology with diversified fuels, e.g., naphtha and LCO, for gas turbines and others as power sources for topographical energy supply. The combustion under the microgravity is also investigated using the underground facilities at Japan Microgravity Center. Described herein are the FY 2000 results. For construction of combustion model and simulation, the combustion reactions for various liquid fuels are simplified to calculate ignition delay, adiabatic flame temperature and laminar burning velocity with an error less than about 3%. The microgravity combustion experiments are conducted for spray dispersed into a cylinder, to find flame propagation velocities changing with the vaporization characteristics of liquid fuels, and also to construct the combustion models. The premixed turbulent combustion simulation program is developed using a probability density function and analyzed. Development of new combustion technologies ...

KoreaScience (Korea)

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Science.gov (United States)

In this dissertation, a two-phase, air-droplets, dilute, turbulent, and steady state flow in a horizontal rectangular channel, is modeled and numerically simulated using a modified KIVA-3V code. The deposition of different sizes of droplets on the walls of the channel is also studied. In this model, the interaction effects between the phases (two-way coupling) are considered by source terms in the momentum and energy equations for the continuous phase and by the instantaneous local velocity of the air in the droplet equation of motion, which includes the aerodynamic and gravitational forces. The turbulence is modeled by a k-? model. The interaction effects between the turbulence and the dispersed droplets are also taken into account. The effects of the turbulence on the droplets are modeled by a fluctuating component added to the local air velocity in the ...

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The droplet concentration profile in a liquid film-mist two-phase flow in a developing flow region of a horizontal rectangular channel was analyzed theoretically and experimentally. The effects of the mean settling velocity of droplets v sub(f) and the turbulent diffusion coefficient epsilon sub(p) on the droplet concentration profile were investigated by the theoretical analysis. The calculated results of the droplet concentration profile using the proper values of v sub(f) and epsilon sub(p) agreed with the experimental results.

International Nuclear Information System (INIS)

The entrainment flow rate distribution, the gas velocity profile, and the concentration profile of droplets across the channel cross section in fully developed region of a horizontal rectangular channel of 150 mm width and 50 mm height were measured. The concentration profile of droplets was expressed by a simple equation based on a constant diffusion coefficient model. From this equation the effects of gravity and turbulent diffusion of droplets on the concentration profile were evaluated. The characteristic mean settling velocity of a group of droplets with various diameters was derived, and using this value the mean diffusion coefficient of the group of droplets was obtained. (author).

UK PubMed Central (United Kingdom)

The purpose of the work was to quantitatively characterize temperature effects on the bacterial leaching of sulfide ore material containing several sulfide minerals. The leaching was tested at eight...Full Text Available

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The most important kaolin deposits from Campo Alegre region (S C) were formed by the conjunction of at least one hydrothermal phase followed by many others weathering, supergenic, phases. Possibly deposits formed by only one of these processes exist, but these deposits shall be small and smaller than those mined today. Besides kaolinization, illitization/muscovitization and silicification, hydrothermalism also generated pyritized and propilitized zones, with quartz + chlorite. Together, hipogenic alterations related to kaolin deposits are very similar to alterations of high sulfidation epigenetic volcanogenic gold deposits. Most part of the biggest kaolin mines from the southern part of Campo Alegre Basin are distributed along a 13 Km long and 0,5 Km width bent zone that is parallel to structural alignments that point out the eastern Basin border. This zone was originated by deformation that has ...

Science.gov (United States)

Manganese, Iodine and Sulfide Concentrations and Peroxide to Oxygen Ratio Measured during the U.S. JGOFS Arabian Sea Process Study ...

International Nuclear Information System (INIS)

In the region of annular liquid film-mist flow, the behavior of the droplets formed from the liquid film and the rate of formation are the subjects to be clarified in connection with the forecast of dry-out point, which becomes a problem in the region of high dryness such as reactor cooling system and steam generators. Many researches have been performed on such problem in vertical tubes, but the characteristics in horizontal flow have not yet been sufficiently clarified. This series of research is to clarify various characteristics, such as the velocity of vapor phase, the flow rate distribution of droplets, the formation and adhesion of droplets and the structure of liquid film, in the region of liquid film-mist flow, where liquid film exists on the bottom of a horizontal rectangular channel, and vapor flow is accompanied by droplets. In this study, by the measurement of the flow rate distribution of ...

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Late plagiogranite bodies in the Semail ophiolite have been previously suggested to represent late stage fractionates within an episodic spreading center magma chamber or the roots of seamount chains. Field and lab observations suggest that these late silicic magma chambers represent zones of repeated injection by dikes of intermediate to mafic composition. Multiple generations of intrusion, partial resorption and reintrusion are preserved in the plagiogranite as 1) relict phantom xenoliths, 2) angular xenoliths with quartz-rich margins, 3) deformed fine-grained dikes with distinct chilled margins, and 4) planes of rectangular blocks with cuspate margins or ellipsoids of similar fine grained mafic materials. The blocks and ellipsoids are actually dismembered mafic dikes that chilled by intruding a cooler silicic liquid and were either thermally fractured or pinched out. All of the dikes are hydrothermally altered to assemblages including amph., qtz., epi., preh., ...

International Nuclear Information System (INIS)

Exploration for epithermal Au has been active lately in the Aegean Sea of the eastern Mediterranean Basin, both in the islands of the Quaternary arc and in those of the back-arc region. The purpose of this study was the structural mapping and analysis for a preliminary investigation of possible epithermal gold mineralization, using remotely sensed data and techniques, structural and field data, and geochemical information, for a specific area on the Island of Lesvos. Therefore, Landsat-TM and SPOT-Pan satellite images and the Digital Elevation Model (DEM) of the study area were processed digitally using spatial filtering techniques for the enhancement and recognition of the geologically significant lineaments, as well as algebraic operations with band ratios and Principal Component Analysis (PCA), for the identification of alteration zones. Statistical rose diagrams and a SCHMIDT projection Stereo Net were generated from the lineament maps and the collected field ...

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Precondition for the low-NO operation of gas turbine burners is the generation of as homogeneous as possible a gaseous fuel/air mixture. Such a burner behavior can be achieved by selective adaptation of the flow and injection. A computing model is introduced that calculates the dynamically balanced GASs/droplet flow through numerical solution of the transport equations in a curved orthogonal coordinate system. The feedback reaction of the fuel droplets to the gas phase is considered by source terms and/or sink terms. Test computations were carried out for comparison with analytical solutions from the flow mechanics and validated by comparison with measurement results. Droplet motion and evaporation were checked by means of published experimental results on single droplets. For the validation of the developed computing technique, model tests were carried out with water in place of fuel. It is pointed out ...

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Platinized cadmium sulfide powder suspended in a solution of sodium sulfite produces hydrogen efficiently by visible light. Sulfite ions are oxidized to sulfate and dithionate ions. 4 figures.

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The inhibiting effects of two mineral compounds on corrosion of nickel in phosphoric acid (H[sub 3]PO[sub 4]) polluted by sulfide ions (S[sup 2[minus

British Library Electronic Table of Contents (United Kingdom)

Nanoscale yttrium?barium?copper oxide (Y2BaCuO5, Y211) particles were synthesized using the emulsion method and the solution method. The basic water-in-oil (w/o) emulsion system consisted of n-octane (continuous oil phase), cetyltrimethylammonium bromide (cationic surfactant), butanol (cosurfactant) and water. The composition of the emulsion system was varied and characterized by measuring the conductivity of the solutions and droplet size. The droplet size of emulsion was determined by using the dynamic light scattering method. The water content, cosurfactant content, and surfactant/n-octane ratio affected the droplet size which was in the range of 3?8?nm, and hence the w/o emulsion system was referred to as a nano-emulsion system. A model was used to verify the droplet size. The influenc...

CERN Document Server

Aerial view of the depot zone of Bois des Serves.

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A residue in the production of alumina by the Bayer process is red mud. It contains oxides of Fe and Ti, active as hydrogenation catalyst in sulfided form, and whose catalytic activity can be improved by the activation method proposed by Pratt and Christoverson. The paper describes how the development of its activity and selectivity with reaction time was studied for the hydrogenation of a light fraction of an anthracene oil, and compared with untreated sulfided red mud. Catalyst samples were collected at different reaction times, and their texture, morphology and composition characterized by nitrogen adsorption, SEM and SEM-EDX. The loss of catalytic activity of activated sulfided red mud is slower than for untreated sulfided red mud. The main cause of this decrease in catalytic activity is the loss of surface area and superficial Fe.

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Transonic flows with heat addition due to condensation are important to many technical applications, e.g. to the last stages of large steam turbines, where nucleation and droplet formation become important. Our current research concentrates on the interaction of vortex shedding with condensation in turbines and on rotor/stator interaction in nucleating flows. Both phenomena lead to a significant change of the condensate mass and the droplet radius distribution in the downstream two-phase flow regime. (orig.)

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It is well known that the solubilization of coal can be accelerated by adding sulfur or hydrogen sulfide during direct liquefaction of difficult coals. From the studies of authors on the coal liquefaction under the conditions at rather low temperatures between 300 and 400{degree}C, liquefaction products with high quality can be obtained by suppressing the aromatization of naphthene rings, but it was a problem that the reaction rate is slow. For improving this point, results obtained by changing solvents have been reported. In this study, to accelerate the liquefaction reaction, Illinois No.6 coal was liquefied in tetralin at temperature range from 300 to 400{degree}C by adding a given amount of sulfur or hydrogen sulfide at the initial stage of liquefaction. The addition of sulfur or hydrogen sulfide provided an acceleration effect of liquefaction reaction at temperature range between 300 and 400{degree}C. The addition of ...

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A sensitive and rapid automated method has been developed for the selective analysis of acid extractable sulfide in environmental samples by combining gas dialysis separation techniques with methylene blue detection procedures. Acid extractable sulfide is separated from the sample matrix by the gas dialysis membrane and subsequently trapped in a dilute sodium hydroxide receiving stream. This stream is reacted with N,N-dimethyl-p-phenylenediamine and ferric chloride to produce methylene blue which is then quantitated colorimetrically at 660 nm. For standards and nonturbid environmental samples, there is good agreement between the results obtained by this procedure and the standard methylene blue method. The effect of interferences on the accurate determination of sulfide by both methods was also examined and it was found that cupric ions significantly interfered with sulfide estimation. To obtain ...

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The presence of soluble sulfide in produced water results in problems for the petroleum industry due to its toxicity, odor, corrosive nature, and potential for wellbore plugging. Sulfide oxidation by indigenous nitrate-reducing bacteria (NRB) present in brine collected from wells at the Coleville Unit (CVU) in Saskatchewan, Canada, was investigated. Sulfide oxidation took place readily when nitrate and phosphate were added to brine enrichment cultures, resulting in a decrease in sulfide levels of 99-165 ppm to nondetectable levels (< 3.3 ppm). Produced water collected from a number of producing wells was screened to determine the time required for complete sulfide oxidation, in order to select candidate wells for treatment. Three wells were chosen, based on sulfide removal in 48 hours or less. These wells were treated down the backside of the annulus with a ...

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Small droplets of organic diazides investigated by C.K. Law and coworkers burn in hot gas at 1 atm with rates inversely proportional to the droplet diameter presumably owing to leading chemical reaction proceeds in gas phase. These burning rates are obviously much lower than those obtained by extrapolation of the results measured for the some substances in glass tubes (at pressure of about 10{sup -2}-10{sup -1} atm, and temperature 0-100 deg C) on the burning conditions of the droplets. Kinetic constants estimated using Zel`dovich equation for the burning rate in gas phase and Semenov relation for delay time of the droplets micro-explosion in liquid phase are about the same: E {approx_equal} 0.17 MJ/mol, log{sub 10}k{sub o} {approx_equal} 15(S{sup -1}). In both of the cases the leading chemical reaction is supposed to be of the first order. Landau instability is assumed to be reflected in distortion of ...

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Carbonyl sulfide (COS), a colorless gas, is a side product of industrial procedures sure as coal hydrogenation and gasification. It is structurally related to and is a metabolite of carbon disulfide. COS is metabolized in the body by carbonic anhydrase to hydrogen sulfide (H{sub 2}S), which is thought to be responsible for COS toxicity. No threshold limit value for COS has been established. Results of these studies indicate COS (with an LC{sub 50} of 590 ppm) is slightly less acutely toxic than H{sub 2}S (LC{sub 50} of 440 ppm).

British Library Electronic Table of Contents (United Kingdom)

In the present study the optical properties of co-evaporated indium sulfide thin films are investigated. Before being optically characterized, the composition as well as the crystalline properties of the film have been checked with the help of energy dispersive spectroscopy (EDX) and X-Ray diffraction (XRD) analyses. The optical absorption coefficient ? of this indium sulfide film has been deduced from reflectivity R(?) and transmission T(?) measurements. The fit of the curve representing ?(h?) suggests that the ?-In2S3 has an indirect bandgap of 2.01?eV. Density functional theory (DFT) calculations are performed on this indium sulfide compound, using TB-LMTO code. Through these band structure investigations, an indirect bandgap is predicted as observed experimentally. The top of the valen...

Science.gov (United States)

... say for sure if the signal is coming from hail, lots of graupel, or some other hydrometeor . ... Precipitation forms when cloud droplets or ice particles in clouds grow and .... A landslide is the movement of rock, debris, or earth down a slope. ...

British Library Electronic Table of Contents (United Kingdom)

Due to the low thermal conductivity of ceramics large temperature gradients are present through the powder particles during plasma spray deposition. As a result the particles often impinge at the substrate in a semi-molten form; which in turn substantially affects the final characteristics of the coating being formed. This study is dedicated to the novel modelling development and simulation of a semi-molten droplet impingement. The study examines the impingement process during impact, spreading and solidification of semi-molten zirconia. The simulation provides an insight to the heat transfer process during impact and solidification of a semi-molten powder particle and illustrates the freezing-induced break-up mechanism at the splat periphery.

International Nuclear Information System (INIS)

The process of miniemulsification allows the generation of small, homogeneous, and stable droplets containing monomer or polymer precursors and magnetite which are then transferred by polymer reactions to the final polymer latexes, keeping their particular identity without serious exchange kinetics involved. It is shown that the miniemulsion process can excellently be used for the formulation of polymer-coated magnetic nanoparticles which can further be used for biomedical applications. The use of high shear, appropriate surfactants, and the addition of a hydrophobe in order to suppress the influence of Ostwald ripening are key factors for the formation of the small and stable droplets in miniemulsion and will be discussed. Two different approaches based on miniemulsion processes for the encapsulation of magnetite into polymer particles will be presented in detail.

Energy Technology Data Exchange (ETDEWEB)

This program is concerned with the development of an advanced method for the separation of hydrogen sulfides from coal gas. The process utilizes an electrochemical membrane which removes hydrogen sulfide without cooling the gas and with negligible pressure loss through the separator.

British Library Electronic Table of Contents (United Kingdom)

A web-based decision support tool, zone mapping application for precision farming (ZoneMAP, External Reference Not Shown ), has been developed to automatically determine the optimal number of management zones and delineate them using satellite imagery and field data provided by users. Application rates, such as of fertilizer, can be prescribed for each zone and downloaded in a variety of formats to ensure compatibility with GPS-enabled farming equipment. ZoneMAP is linked to Digital Northern Great Plains, a web-based application which hosts an archive of satellite imagery, as well as high resolution imagery from airborne sensors. Management zones created by ZoneMAP mapped natural variation of the soil organic matter and other nutrients relatively well and were consistent with zone maps cre...

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Metals for potential use in the dissociator and the synthesizer reactors of a distributed solar receiver thermochemical transport loop utilizing SO/sub 3//SO/sub 2//O/sub 2/ molecular chemistry were tested in SO/sub 2//O/sub 2/ mixtures at 500/sup 0/C and 900/sup 0/C, respectively, for times of up to four weeks. They included titanium, aluminum and nickel, and iron-base, nickel-base and cobalt-base superalloys. Weight gain measurements determine the oxidation/sulfidation kinetics. Electron microprobe analysis identifies any possible penetration of oxygen and sulfur into the metal and the formation of internal oxides and sulfides. The most promising candidates as a result of these tests are the cobalt-base superalloys.

British Library Electronic Table of Contents (United Kingdom)

Indium sulfide thin films were deposited onto indium-tin-oxide coated glass substrate by electrochemical deposition from an aqueous solution containing In2 (SO4) 3 and Na2S2O3. The deposition conditions were optimized on the basis of data obtained by scanning electron microscope, Auger electron spectroscopy and optical transmission measurements. Furthermore, the photosensitivity of the films was observed by means of photoelectrochemical measurements, which confirmed that the indium sulfide showed n-type conduction. The X-ray diffraction and Raman studies revealed that the as-grown films were amorphous or nanocrystalline in nature and became polycrystalline In2S3 after annealing.

Energy Technology Data Exchange (ETDEWEB)

The absorption of carbonyl sulfide in aqueous methyldiethanolamine (MDEA) was studied over a range of temperatures and MDEA concentrations. MDEA is commonly used for selective absorption of hydrogen sulfide in the presence of carbon dioxide. However, sulfur in the form of COS may also be present and it is necessary that estimates of absorption rates of this compound be made. The objective of this study is to determine the physiochemical properties needed to predict COS absorption rates in aqueous MDEA. Free gas solubility and the diffusivity of COS in MDEA solutions were measured over the temperature range 15 to 40{sup 0}C for MDEA concentrations up to 30 weight per cent using the nitrous oxide analogy method. Solubilities were measured volumetrically in an equilibrium cell and diffusivities were measured using a laminar liquid jet absorber. The kinetics of the reaction between COS and MDEA were studied by measuring absorption rates in a single ...

Energy Technology Data Exchange (ETDEWEB)

The relationship between the gas to melt ratio (GMR) and the surface temperature of an evolving billet surface in spray forming is investigated numerically. The basis for the analysis is an integrated approach for modelling the entire spray forming process. This model includes the droplet atomization taking thermal coupling into consideration and the deposition of material at the surface of the billet taking geometrical aspects such as shading into account. The coupling between these two models is accomplished by ensuring that the total droplet size distribution of the spray is the summation of ''local'' droplet size distributions along the r-axis of the spray cone. The criterion for a successful process has been a predefined process window characterised by a desired fraction solid range at a certain distance from the atomizer. Inside this process window, the gas and melt flows have been ...

Science.gov (United States)

Thin film solar cells and solar cell testing - photovoltaic cells, radiation damage to cadmium sulfide solar cells, and airplane testing of solar cells

Energy Technology Data Exchange (ETDEWEB)

Correlations between structural aspects of solid materials and their behavior as catalysts are relatively recent. This 20-chapter book focuses on understanding of solid-state mechanisms in heterogeneous catalysis and relationship between catalytic behavior and solid state structure, emphasizing catalysis with oxides, sulfides, and zeolites.

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A process for the recovery of nitrilotriacetic acid values from solutions containing polyvalent metal complexes of nitrilotriacetic and the decomposition products thereof is described, the process being characterized by the addition to such solutions of sufficient strong acid to dissociate the complex under conditions to precipitate the nitrilotriacetic acid.

UK PubMed Central (United Kingdom)

Marine sediments are frequently covered by mats of the filamentous Beggiatoa and other large nitrate-storing bacteria that oxidize hydrogen sulfide using either oxygen or nitrate, which...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Concentration of an amine solution for removal of hydrogen sulfides and carbon dioxide from natural gas, is tested by carbon dioxide absorption measurement in an apparatus allowing complete reaction to give reliable results.

British Library Electronic Table of Contents (United Kingdom)

The influences of maltodextrin (MD) addition and multi-layer formation on the freeze-thaw stability of ?-lactoglobulin (?-Lg)-stabilized oil-in-water beverage emulsions (0.1 wt% corn oil, 0.006 wt% ?-Lg) were investigated. Various beverage emulsions were prepared depending on MD concentration (0?20 wt%), its dextrose equivalent (M150 or M250), and the presence or absence of additional polysaccharides (pectin, alginate, or ?-carrageenan) coatings around the emulsion droplets. All emulsions (?-Lg- and ?-Lg-polysaccharide-coated emulsions) were unstable to experimental freeze-thaw cycling in the absence of MD. In the presence of MD, all emulsions containing M250 had better stability to droplet aggregation than those with M150, regardless of MD concentrations and freeze-thawing. The optimum co...

International Nuclear Information System (INIS)

To develop the advanced subchannel analysis code, the dominant factors that influence the boiling transitional process must be taken into account in the mechanistic constitutive equations based on the flow geometries and the fluid properties. The dominant factors that influence the boiling transitional processes are (1) the gas-liquid re-distribution by cross flow, (2) the liquid film dryout, (3) the two-phase flow regime transition, (4) the droplet deposition, and (5) the spacer-droplet interaction. At first, we indicated the strategy for the development of the constitutive equations for the five dominant factors based on the experimental database by the latest measurement technique and the latest computational fluid dynamics method. Then, the problems of the present constitutive equations and the improvement plan of the constitutive equations were indicated. Finally, the layered structure for the two-phase/three-field subchannel code ...

Energy Technology Data Exchange (ETDEWEB)

This paper describes the safety system and training for personnel on board the floating production storage and offloading (FPSO II) currently working in the Cadlao Field, offshore Palawan in the Philippine Islands. (See Figure 1). The crude oil being produced has wellstream hydrogen sulfide concentrations up to 6000 PPM. Concentrations of hydrogen sulfide at 700 PPM or higher can be immediately dangerous to life and every effort must be made to ensure personnel safety.

Science.gov (United States)

Mild steel samples were studied by chronoamperometry in sodium sulfide (Na[sub 2]S) aqueous solution. Pit nucleation and growth also were monitored by optical microscopy. The influence of variables such as temperature, polarization potential, surface roughness, the presence of electrochemically generated oxide layers, and the simultaneous presence of potassium hydroxide (KOH) was studied. The influence of each parameter on pit shape and growth was reviewed. Different reactions and competitive processes were proposed based on the experimental results.

Energy Technology Data Exchange (ETDEWEB)

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Energy Technology Data Exchange (ETDEWEB)

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Energy Technology Data Exchange (ETDEWEB)

Greenhouse-effect induced climate change repercussions will, via the catchment areas of big rivers, eventually arrive in amplified form at the far downstream coastal zones of the world. In the coastal zone these imported problems will add to the locally exerted climate change effects, while the climate change induced sea-level rise will attack the coastal zone from the other side, both by flooding and by saline groundwater intrusion. These multiple problems will hit the coastal zone, which is already under increasing stress. The combined threats require fast and massive support for national Coastal Zone Management capabilities, which could help to limit the damage and to support planning for sustainable development. Recommendations are presented to facilitate implementation of Coastal Zone Management units in all coastal countries by the year 2000.

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Stable strange quark matter produced in the QCD phase transition in the early universe will trap neutrons and repel protons, thus reducing primordial helium production, Ysub(p). For reasonable values of Ysub(p), the radius of strange droplets must exceed 10/sup 6/ cm if strange matter shall solve the dark-matter problem without spoiling Big Bang helium synthesis. (orig.).

British Library Electronic Table of Contents (United Kingdom)

Tachycardia Detection, ICD, CRT-D Devices, Appropriate and Inappropriate Shock.-Introduction: We evaluated the frequency of appropriate and inappropriate shocks and survival in patients using dual-zone programming versus single-zone programming. Methods and Results: For the ALTITUDE REDUCES study, patients were followed for 1.6 1.1 years. The 12-month incidence of any shock was lower for dual-versus single-zone programmed detection at rates -170 bpm and between 170-200 bpm (P < 0.001). Appropriate shock rates at 1 year were also lower with dual-zone programming in these rate intervals (single zone 9.1%, 5.4%, P < 0.001, dual zone 6.7%, 4.7%, P < 0.02). There were no detectable differences between single- and dual-zone shock incidence at detection rates - 200 bpm (P = 0.14). Inappropriate s...

Energy Technology Data Exchange (ETDEWEB)

Metals for potential use in the dissociator and the synthesizer reactors of a distributed solar receiver thermochemical transport loop utilizing SO/sub 3//SO/sub 2//O/sub 2/ molecular chemistry includes stainless steels and iron-base, nickel-base and cobalt-base superalloys. We tested these alloys in SO/sub 2//O/sub 2/ mixtures and SO/sub 3/ gas at 500/sup 0/C and 900/sup 0/C, respectively, for times of up to four weeks. Weight gain measurements were used to determine the oxidation/sulfidation kinetics and electron microprobe analysis was used to measure penetration of oxygen and sulfur into the metal and to identify the formation of internal oxides and sulfides. Results of these tests showed that the most promising candidates are those containing sufficient quantities of both aluminum and chromium alloying additions to be alumina and chromia formers, such as Kanthal A-1, Nimonic 105 and Cabot 214.

Energy Technology Data Exchange (ETDEWEB)

The coke plant at the Sparrows Point Plant consist of three coke oven batteries and two coal chemical plants. The by-product coke oven gas (COG) consists primarily of hydrogen, methane, carbon monoxide, nitrogen and contaminants consisting of tars, light oils (benzene, toluene, and xylene) hydrogen sulfide, ammonia, water vapor and other hydrocarbons. This raw coke oven gas needs to be cleaned of most of its contaminants before it can be used as a fuel at other operations at the Sparrows Point Plant. In response to environmental concerns, BSC decided to replace much of the existing coke oven gas treatment facilities in the two coal chemical Plants (A and B) with a group of technologies consisting of: Secondary Cooling of the Coke oven Gas; Hydrogen Sulfide Removal; Ammonia Removal; Deacification of Acid Gases Removed; Ammonia Distillation and Destruction; and, Sulfur Recovery. This combination of technologies will replace the existing ammonia ...

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Production of hydrogen sulfide in produced waters due to the activity of sulfate-reducing bacteria (SRB) is a potentially serious problem. The hydrogen sulfide is not only a safety and environmental concern, it also contributes to corrosion, solids formation, a reduction in produced oil and gas values, and limitations on water discharge. Waters produced from seawater-flooded reservoirs typically contain all of the nutrients required to support SRB metabolism. Surface processing facilities provide a favorable environment in which SRB flourish, converting water-borne nutrients into biomass and H{sub 2}S. This paper will present results from a field trial in which a new technology for the biochemical control of SRB metabolism was successfully applied. A slip stream of water downstream of separators on a produced water handling facility was routed through a bioreactor in a side-steam device where microbial growth was allowed to develop fully. This ...

British Library Electronic Table of Contents (United Kingdom)

This paper presents studies carried out on tin-doped indium sulfide films prepared using Chemical Spray Pyrolysis (CSP) technique. Effect of both in-situ and ex-situ doping were analyzed. Ex-situ doping was done by thermal diffusion, which was realized by annealing Sn/In2S3 bilayer films. In-situ doping was accomplished by introducing Sn into the spray solution by using SnCl45H2O. Interestingly, it was noted that by ex-situ doping, conductivity of the sample enhanced considerably without affecting any of the physical properties such as crystallinity or band gap. Analysis also showed that higher percentage of doping resulted in samples with low crystallinity and negative photosensitivity. In-situ doping resulted in amorphous films. In contrast to ex-situ doping, `in- situ doping' resulted i...

British Library Electronic Table of Contents (United Kingdom)

Sulfur mustard (HD) is an alkylating and cytotoxic chemical warfare agent, which inflicts severe skin toxicity and an inflammatory response. Effective medical countermeasures against HD-caused skin toxicity are lacking due to limited knowledge of related mechanisms, which is mainly attributed to the requirement of more applicable and efficient animal skin toxicity models. Using a less toxic analog of HD, chloroethyl ethyl sulfide (CEES), we identified quantifiable inflammatory biomarkers of CEES-induced skin injury in dose- (0.05-2 mg) and time- (3-168 h) response experiments, and developed a CEES-induced skin toxicity SKH-1 hairless mouse model. Topical CEES treatment at high doses caused a significant dose-dependent increase in skin bi-fold thickness indicating edema. Histopathological e...

Energy Technology Data Exchange (ETDEWEB)

Alkanol-amine is used for removing hydrogen sulfide and carbon dioxide from the gas stream. Contaminated amine is the amine which is contaminated by hydrocarbon, organic acid or iron sulfide, etc.. In addition, in the case when an antifoaming agent is excessively added to it or when it is decomposed chemically or thermally, it is considered that it is contaminated. When an amine solution becomes contaminated, several problems concerning operation control occur which would influence the effect of the amine treatment in consequence. By using activated charcoal, it is possible to decrease the additional amount of the antifoaming agent or corrosion inhibitor. This is because activated charcoal removes the decomposed product which causes the foaming phenomenon. In order to derive economical profit sufficiently, an activated charcoal system properly designed is necessary. In this article, the CALGON CLEANAMINE SYSTEM of Calgon Co. is introduced which ...

UK PubMed Central (United Kingdom)

Neuroblasts born in the adult subventricular zone (SVZ) migrate long distances in the rostral migratory stream (RMS) to the olfactory bulbs where they integrate into circuitry as functional interneurons....Full Text Available

Wastenet

KOREA-JAPAN NUCLEAR WEAPON FREE ZONE (KJNWFZ) CONCEPT PAPER ...A Korea-Japan2 Nuclear Weapon Free Zone (hereafter KJNWFZ) is a new concept.Once realized, ...Finally, we outline the key elements of the Korea-Japan NWFZ proposed in this paper, noting

UK PubMed Central (United Kingdom)

The destiny of the mitotically active cells of the subventricular zone (SVZ) in adult rodents is to migrate to the olfactory bulb, where they contribute to the replacement of granular and periglomerular...Full Text Available

International Nuclear Information System (INIS)

Small-angle X-ray scattering method recognised to be very useful in the studies of structural problems of materials in homogeneous in nanoscale. Studies by small-angle X-ray scattering on the Al-Ag alloys are presented. The size distributions of spherical Guinier-Person zones were calculated using Vonk's and Glatter's methods. Small-angle X-ray scattering studies were performed on Al-5.0 at.%Ag alloy containing Guinier-Preson zones in the #eta#-state. For this alloy one can assume that scattering particles are of spherical shape, have uniform electron density and scatter independently. Moreover, the size distributions were calculated for Al-1.6 at.%Ag alloy containing Guinier-Preston zones in #epsilon#-state (scattering particles with not uniform electron density). Both, Vonk's and Glatter's, methods gave similar size distributions. Profiles of size distributions for Guinier-Preston zones in ...

UK PubMed Central (United Kingdom)

A simulation is developed that qualitatively describes the small-zone-gel-filtration behaviour of a reversibly associating protein. The results reflect the dependence of the apparent molecular weight...Full Text Available

International Nuclear Information System (INIS)

German 2003 p. 24 Germany Klemz, G. Moenig, K. Sekaric, J. Stahl,

Wastenet

...Benthic Marine Bioregionalisation of Australia's Exclusive Economic Zone The benthic (sea floor) component of the National Marine Bioregionalisation covers the 80% of Australia's ... Exclusive Economic Zone that lies beyond the continental shelf break. It provides a description of patterns of biological distributions and physical habitats on the seafloor....sea floor) component of the National Marine Bioregionalisation covers the 80% of Australia's Exclusive Economic Zone that lies beyond the continental shelf break. It provides a ... Benthic Marine Bioregionalisation of Australia's Exclusive Economic Zone Change text size Skip to content Marine Bioregional Planning resources Search: About us Contact us You ...

International Nuclear Information System (INIS)

In this review, we demonstrate the developmental appearance, structural features, and reorganization of transient cerebral zones and structures in the human fetal brain using a correlative histological and MRI analysis. The analysis of postmortem aldehyde-fixed specimens (age range: 10 postovulatory weeks to term) revealed that, at 10 postovulatory weeks, the cerebral wall already has a trilaminar appearance and consists of: (1) a ventricular zone of high cell-packing density; (2) an intermediate zone; (3) the cortical plate (in a stage of primary consolidation) with high MRI signal intensity. The anlage of the hippocampus is present as a prominent bulging in the thin limbic telencephalon. The early fetal telencephalon impar also contains the first commissural fibers and fornix bundles in the septal area. The ganglionic eminence is clearly visible as an expanded continuation of the proliferative ventricular ...

Energy Technology Data Exchange (ETDEWEB)

Essential to today's modern refineries and the gasoline production process are fluidized catalytic cracking units. By using a computational fluid dynamics (CFD) code developed at Argonne National Laboratory to simulate the riser, parametric and sensitivity studies were performed to determine the effect of catalyst inlet conditions on the riser hydrodynamics and on the product yields. Simulations were created on the basis of a general riser configuration and operating conditions. The results of this work are indications of riser operating conditions that will maximize specific product yields. The CFD code is a three-dimensional, multiphase, turbulent, reacting flow code with phenomenological models for particle-solid interactions, droplet evaporation, and chemical kinetics. The code has been validated against pressure, particle loading, and product yield measurements. After validation of the code, parametric studies were performed on various parameters such ...

Science.gov (United States)

Critical power at boiling transition is an important factor in a boiling water reactor (BWR) fuel bundle design. Boiling transition under high quality accounts for dryout as the result of the complete disappearance of film flow on a fuel rod. This liquid film vanishing process can be calculated by the liquid film model, which takes into account the evaporation due to heat from the rod surface, liquid film entrainment by steam flow, and liquid droplet deposition. It is known that spacers affect liquid film entrainment and liquid droplet deposition, so the detailed study of spacer effects on hydrodynamic characteristics is necessary for critical power prediction based on the film flow model. Many studies have been conducted to examine spacer effects on liquid film flow. However, most of them are restricted to simple test sections such as a rectangular conduit. There are a few reports on fuel bundle geometry; however the bundle studied was only a ...

Energy Technology Data Exchange (ETDEWEB)

A consistent statistical theory of the crystal-liquid phase transition is developed, being based on a method which takes into account liquidlike fluctuations in crystals and solidlike clusters in liquids. It is shown that degenerate fluidlike droplets have a finite number density at zero temperature, while nondegenerate fluctuations disappear when the temperature goes to zero. The existence of a melting point is proved. This method, which takes into consideration the heterophase fluctuations, provides the possibility of describing metastable states such as a supercooled liquid or an overheated crystal. Conditions for the existence of metastable states are found. The liquid-glass transition can also be described by the method presented here.

Energy Technology Data Exchange (ETDEWEB)

This reports is a literature survey on models and correlations for determining flow pattern that are used to simulate thermal-hydraulics in nuclear reactors. Determination of flow patterns are a basis for obtaining physical values of wall/interfacial friction, wall/interfacial heat transfer, and droplet entrainment/de-entrainment. Not only existing system codes, such as RELAP5-3D, TRAC-M, MARS, TRACE, CATHARE) but also up-to-date researches were reviewed to find models and correlations

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An Eulerian/Langrangian model was developed to study the two-phase flow in a two-dimensional, axisymmetric, direct-injection diesel engine, under motored and firing conditions. The liquid phase was tracked in a Lagrangian sense using discrete droplet packets (DDP). The gaseous phase was solved using an implicit, iterative, finite-difference, scheme of the control volume variety. Gaseous-phase turbulence was modeled using a compressible two-equation k/epsilon model. Turbulence effects on the liquid phase were modeled by superimposing a randomly oriented turbulent eddy velocity proportional to the root of the turbulent kinetic energy, on each packet's mean relative velocity. Droplet-droplet interactions were neglected. The general knowledge obtained during validation studies, was used to simulate the direct-injection two-stroke diesel engine under motored conditions. The simulation showed that by beginning of the injection, (15/sup 0/ ...

Energy Technology Data Exchange (ETDEWEB)

This report summarizes the objectives, background, technical progress, and status of ANL electric vehicle battery R&D tasks for DOE-EHP during the period of January 1 through March 31, 1991. The work is organized into the following six task areas: Project management; battery systems technology; lithium/sulfide batteries; advanced sodium/metal chloride battery; aqueous batteries; and EV Battery performance/life evaluation.

Energy Technology Data Exchange (ETDEWEB)

A multiple metal oxide sorbent supported on a zeolite of substantially silicon oxide is used for the desulfurization of process gas streams, such as from a coal gasifier, at temperatures in the range of about 1200.degree. to about 1600.degree. F. The sorbent is provided by a mixture of copper oxide and manganese oxide and preferably such a mixture with molybdenum oxide. The manganese oxide and the molybdenum are believed to function as promoters for the reaction of hydrogen sulfide with copper oxide. Also, the manganese oxide inhibits the volatilization of the molybdenum oxide at the higher temperatures.

Energy Technology Data Exchange (ETDEWEB)

Reaction kinetics for the displacement of 5-aminoquinoline (5-Aq) and diethyl sulfide (SEt{sub 2}) from cis-[PtPh{sub 2}(CO)(L)] (L = 5-Aq or SEt{sub 2}) by aliphatic amines was measured for a wide array of amines. Reaction products were characterized by IR and NMR spectroscopies and crystalk structures of selected products were reported. Steric effects on the substitutions were discussed.

Energy Technology Data Exchange (ETDEWEB)

It is demonstrated that normal pitting can occur during oxidizing conditions in the repository. It is also concluded that a new theory for pitting corrosion has to be developed, as the present theory is not in accordance with all practical and experimental observations. A special variant of pitting, based on the growth of sulfide whiskers, is suggested to occur during reducing conditions. However, such a mechanism needs to be demonstrated experimentally. A simple calculational model of canister corrosion was developed based on the results of this study. 69 refs, 3 figs.

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The effect of treatment with hydrogen, hydrogen sulfide, and steam on the catalytic properties of NaY zeolites has been studied. A mechanism has been proposed for activation of the zeolites, which explains the appearance of Broensted acid centers on modified samples. The influence of modification temperature and the degree of decationization of the zeolites on the promoting capacity of the latter in the cumene cracking reaction has been studied.

International Nuclear Information System (INIS)

A historical overview of corrosion problems found in power plant condensers and mitigation procedures is presented. The paper is organized according to alloy type and failure mode. Alloys considered are copper-base alloys, stainless steels and titanium. Failure modes discussed include erosion-corrosion, sulfide attack, environmentally assisted cracking, galvanic corrosion, steam condensate corrosion, pitting corrosion, and dealloying. Mitigation procedures discussed include cathodic protection, ferrous ion injection, as well as tube cleaning and layup practices.

International Nuclear Information System (INIS)

A photoacoustic (PA) imaging system based on an ultrasonic Fresnel zone plate (FZP) transducer is developed for the purpose of imaging biological tissue. This FZP transducer has a two-zone negative zone plate piezoelectric material pattern, and an optical fibre is integrated with the transducer on the symmetric axis of the zone plates to deliver laser pulses to the sample. The focal characteristic of the FZP transducer is analysed by theoretical prediction and experimental measurement, and the measured results are in good agreement with the predicted results. The limited-field back-projection deconvolution algorithm combined with the coherence-factor weighting technique is used to reconstruct the optical absorption distribution. The experiments were performed with phantoms and the blood vessels of chicken embryo chorioallantoic membrane. The results demonstrate that PA imaging using the FZP transducer ...

British Library Electronic Table of Contents (United Kingdom)

Pursuant to statement issued by the Government of Vietnam on 12 May 1977, on the territorial sea, the contiguous zone, the exclusive economic zone (EEZ) and the continental shelf of Vietnam, and according to the provisions of the LOS Convention, the EEZ of Vietnam extends principally up to 200NM from the baseline, and the area of EEZ amounts to about one million square km including the Hoang Sa (Paracel) and Truong Sa (Spratly) Islands [The declaration of the Government of Vietnam on the territorial sea, contiguous zone, exclusive economic zone and continental shelf, Hanoi, 1977]. The establishment of EEZ has significantly changed circumstances for the fisheries sector in Vietnam.Recently, even though the adaptation of new techniques and technologies to the fisheries sector has been somewh...

Energy Technology Data Exchange (ETDEWEB)

Anomalous features in Gulf Coast Salt domes exhibit deviations from normally pure salt and vary widely in form from one dome to the next, ranging considerably in length and width. They have affected both conventional and solution mining in several ways. Gas outbursts, insolubles, and potash (especially carnallite) have led to the breakage of tubing in a number of caverns, and caused irregular shapes of many caverns through preferential leaching. Such anomalous features essentially have limited the lateral extent of conventional mining at several salt mines, and led to accidents and even the closing of several other mines. Such anomalous features, are often aligned in anomalous zones, and appear to be related to diapiric processes of salt dome development. Evidence indicates that anomalous zones are found between salt spines, where the differential salt intrusion accumulates other materials: Anhydrite bands which are relatively strong, and ...

International Nuclear Information System (INIS)

In the heat-affected zones (HAZ) of low alloy steels used for nuclear pressure vessel, microstructural changes, such as grain coarsening, carbide precipitation, and martensite formation, generally occur and cause a deterioration of toughness and an increase in sensitivity to brittle fracture. Metallographic analyses of low alloy steel welds reveal significantly different regions in HAZ microstructures. In 2-pass welds, there were seven characteristic regions in the HAZ determined by the peak temperature, to which the region was exposed during the weld thermal cycle: a coarse-grained region, a fine-grained region, an intercritical region, and subcritical region. The coarse-grained region can be categorized into four zones according to the reheating temperature as follows : an unaltered coarse-grained zone (UCGHAZ), a supercritically reheated coarse grained zone (SCRCGHAZ), an intercritically reheated ...

Energy Technology Data Exchange (ETDEWEB)

This presentation described the geology of the Kootenay, Gething, Gates, Brazeau and Coalspur Formations in the potential gas-bearing coal zones of the Alberta Foothills/Mountains. The future potential of this region for coalbed methane (CBM) exploitation was discussed, based on available data from drilling activity and the results of a recent coal desorption and adsorption study in the Val d'Or seam of the Coalspur formation. The gas content of the 5 coal zones was evaluated and compared with previous CBM exploration in the area. For evaluation purposes, the coal zones were divided into shallow and deep coal zones. The potential gas content of the shallow coal zones is approximately 31 Tcf of CBM. This is considered an inferred, initial, in-place, CBM resource estimate based on limited data. The gas content of deep zones is approximately 99 Tcf of ...

Energy Technology Data Exchange (ETDEWEB)

This report describes the geology of the following 5 Alberta Foothills/Mountains coal zones: the Kootenay, Gething, Gates, Brazeau and Coalspur coal zones. The coal areas were assessed for gas content and compared with previous coalbed methane (CBM) exploration in the area. The coal zones can be divided into shallow (less than 1000 m depth) and deep (greater than 1000 m depth) coal zones for evaluation purposes. The potential gas content of the shallow coal zones is approximately 31 Tcf of CBM. This is considered an inferred, initial, in-place, CBM resource estimate based on limited data. The gas content of deep zones is approximately 99 Tcf of in-place CBM gas. Therefore, the total ultimate CBM resource is estimated at 130 Tcf. CBM recovery is not usually attempted due to high drilling costs and low permeability. The only CBM production from the Foothills has ...

Energy Technology Data Exchange (ETDEWEB)

Samples from a burning bituminous coal seam from Coalspur, Alberta, were studied by reflected light microscopy. Two zones - namely oxidation- combustion and distillation - were detected in the seam. Near the surface, the oxidation zone contained chars showing cracks and oxidation rims. The cracks were filled with fluorescing hydrocarbon material formed by thermal cracking of coal macerals. The chars in the deeper part of the oxidation zone had a carbonized matrix and burnt rims. The distillation zone covered most of the coal seam. Chars were mostly in the precarbonization stage, except those immediately below the combustion zone or near the base of the seam. Precarbonized chars contained pyrolytic carbon in some horizons. The distilled chars were formed by heat generated by combustion at the top of the seam and also by heat transfer from an underlying burning seam through an ...

British Library Electronic Table of Contents (United Kingdom)

The contention of this commentary, focused on the vestibulocerebellum (particularly the flocculus), is that the great importance for our understanding of cerebellar organization in terms of climbing fiber zones, begun years ago by Voogd [1969, 2011] and Oscarsson [1969], needs to be matched by coming more to grips with the other fundamental geometrical organization of the cerebellum, the parallel fibers. The central issue is the selection of those parallel fiber signals to be transformed into Purkinje cell activity in the different zones. At present, in comparison to our knowledge of vestibulocerebellar climbing fiber inputs, the deficiencies in our knowledge of the zonal anatomy and physiology of vestibulocerebellar mossy fibers and granule cells are glaring. The recent emphasis on molecu...

Energy Technology Data Exchange (ETDEWEB)

Temperature and concentration profiles of CO in a laminar, axisymmetric, premixed methane-air Bunsen flame are measured using line-of-sight diode laser absorption spectroscopy and computer tomographic (CT) reconstruction. Absorption spectra for P(20) (v=2<-1) and P(27) (v=1<-0) vibrotational transitions of CO were measured at 21 evenly spaced positions over a 1.33 cm span for a 1.3 cm radius flame. CT reconstruction algorithm was based on Fourier convolution. The tomographically reconstructed normalized transmission profiles derived from absorption spectra, in conjunction with a quantum mechanical model for vibrotational behavior of CO, yielded both temperature and concentration profiles. The Bunsen flame had 3 distinct zones: an inner rich-premixed flame zone, an outer non-premixed flame zone and an unburnt core region. The reconstructed temperature profile showed that the core region temperature was close to ambient ...

KoreaScience (Korea)

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International Nuclear Information System (INIS)

Portuguese 1984. p. 146. Brazil Czepielewski, MA Kater, CE Biglieri, EG Escola

Science.gov (United States)

... In a first-of-its-kind operation, Lisnave recently converted Latvian Shipping Company's 20,000 dwt products tanker Dzintari into a full Class 3 ...

British Library Electronic Table of Contents (United Kingdom)

A rapid and cost-effective assessment was required to provide advice to management on the connectivity between juvenile and adult life cycle stages of Baldchin Groper Choerodon rubescens, a labrid endemic to the west coast of Australia, which has high social value, but relatively low commercial fishery importance. To minimise costs we used laser ablation ICP-MS to analyse levels of a small suite of elements (Ca, Mg, Mn, Cu, Zn, Sr, Rb, Ba and Pb) at the margin (adult phase) and core (juvenile phase) of the same otoliths of adult C. rubescens, collected at ten locations in five management zones. The elemental composition of both otolith margins and cores differed significantly among management zones and in some cases among locations within zones. Similarity of the pattern of among-zone elem...

Science.gov (United States)

Satellite Observations of the Southeast Pacific Intertropical Convergence Zone During 1993-1998, Halpern, D.; Hung, C.-W., Journal of Geophysical Research ? ...

International Nuclear Information System (INIS)

Japanese Sep 2009 p. 103-106 Japan Idota, Yasuhiro Inoue, Hiroyuki

International Nuclear Information System (INIS)

... University, Fracture and Reliability Research Institute, Sendai, Miyagi (Japan)

Science.gov (United States)

Rapid administration of stable iodine is essential for the saturation and subsequent protection of the thyroid gland against the potential harm caused by radioiodines. This paper proposes the Dutch risk analysis that uses an atmospheric dispersion model to calculate the size of the zones around nuclear power plants where radiological thyroid doses for children might be sufficiently high to warrant iodine administration. Dose calculations for possible releases from the nuclear power plants of Borssele (The Netherlands), Doel (Belgium) and Emsland (Germany) are based on two scenarios in combination with a 1-y set of authentic, high-resolution meteorological data. The dimensions of the circular zones were defined for each nuclear power plant. In these zones, with a radius up to 50 km, distribution of stable iodine tablets is advised. PMID:20332130

UK PubMed Central (United Kingdom)

Mexico is located in a transition zone between the Nearctic and Neotropical biogeographical regions and contains a rich and unique biodiversity. A total of 496 Bacillus thuringiensis...Full Text Available

Science.gov (United States)

Products of a power plant flue gas desulfurization scrubber are discharged into a pond as sludge consisting of calcite (initial delta13C 3.2-3.8 per thousand), gypsum (initial delta34S 7.6-8.6 per thousand), and aqueous solution. Reducing conditions exist below a boundary that appears to move vertically as a function of changes in pond water level. Under reducing conditions, bacteria partially reduce aqueous sulfate to low-delta34S sulfide, consuming organic carbon and generating low-delta13C bicarbonate. Under oxidizing conditions, sulfide is converted to sulfate, leading to calcite dissolution, gypsum precipitation, and isotopic re-equilibration of remaining calcite with dissolved bicarbonate near the pond surface. The gypsum has delta34S near 6 per thousand, and calcite has delta13C as low as -1.7 per thousand; the changes from initial values correspond to predictions based on isotopic balance and reaction stoichiometry. The pond largely ...

International Nuclear Information System (INIS)

The concept of nanocrystal conversion chemistry, which involves the use of pre-formed nanoparticles as templates for chemical transformation into derivative solids, has emerged as a powerful approach for designing the synthesis of complex nanocrystalline solids. The general strategy exploits established synthetic capabilities in simple nanocrystal systems and uses these nanocrystals as templates that help to define the composition, crystal structure, and morphology of product nanocrystals. This article highlights key examples of 'conversion chemistry' approaches to the synthesis of nanocrystalline solids using a variety of techniques, including galvanic replacement, diffusion, oxidation, and ion exchange. The discussion is organized according to classes of solids, highlighting the diverse target systems that are accessible using similar chemical concepts: metals, oxides, chalcogenides, phosphides, alloys, intermetallic compounds, sulfides, and nitrides. - Graphical ...

Energy Technology Data Exchange (ETDEWEB)

In response to the Clean Coal II solicitation, Bethlehem Steel Corporation (BSC) submitted a proposal to the DOE in May 1988. The proposal submitted by BSC describes a Unique integration of commercial technologies developed by Davy/Still Otto to clean coke oven gas being produced at its Sparrows Point, Maryland steel plant. This innovative coke oven gas cleaning system combines secondary gas cooling with hydrogen sulfide and ammonia removal, hydrogen sulfide and ammonia recovery, ammonia destruction and sulfur recovery to produce a cleaner fuel gas for plant use. The primary environmental benefit associated with employing this innovative coke oven gas cleaning system is realized when the fuel gas is burned within the steel plant. Emissions of sulfur dioxide are reduced by more than 60 percent. The removal, recovery and destruction of ammonia eliminates the disposal problems associated with an unmarketable ammonium sulfate by-product. ...

Energy Technology Data Exchange (ETDEWEB)

The industrial standard process for the purification of natural gas is to remove acid gases, mainly hydrogen sulfide and carbon dioxide, by the absorption and reaction of these gases with alkanolamines. The natural gas industry requires vapor-liquid equilibrium (VLE) data to develop more energy efficient amine mixtures. Some energy reductions have been realized in the past decade by applying such amine systems as hindered amines, methyldiethanolamine (MDEA), and MDEA based amine mixtures. However, the lack of reliable and accurate VLE data impedes the commercial application of these more efficient alkanolamine systems. The first objective of this project is to improve the accuracy of vapor-liquid equilibrium measurements at low hydrogen sulfide concentrations. The second objective is to make VLE measurements for amine mixtures. By improving the accuracy of the VLE data on MDEA and other amines, energy savings can be implemented in the many ...

Energy Technology Data Exchange (ETDEWEB)

The industrial standard process for the purification of natural gas is to remove acid gases, mainly hydrogen sulfide and carbon dioxide, by the absorption and reaction of these gases with alkanolamines. Inadequate data for vapor -- liquid equilibrium (VLE) hinder the industry from converting operations to more energy efficient amine mixtures and conserving energy. Some energy reductions have been realized in the past decade by applying such amine systems as hindered'' amines, methyldiethanolamine (MDEA), and MDEA based amine mixtures. However, the lack of reliable and accurate fundamental VLE data impedes the commercial application of these more efficient alkanolamine systems. The first project objective is to improve the accuracy of vapor -- liquid equilibrium measurements at low hydrogen sulfide concentrations. The second project objective is to measure the VLE for amine mixtures. By improving the accuracy of the VLE ...

Energy Technology Data Exchange (ETDEWEB)

Papers are presented on the development of oxidation- and sulfidation-resistant ferritic alloys; the microstructural stability of sulfidation-resistant FeCrAl stainless steels around 500 C; age hardening in Fe-Mn-Al-C austenitic alloys; the oxidation/corrosion behavior of low-Cr Fe-Cr-Ni alloys containing Zr or Nb; the high temperature oxidation/corrosion of iron-based superalloys; and the role of Mo in the Na/sub 2/SO/sub 4/ induced corrosion of superalloys at high temperature. Topics discussed include the effect of variations of Co content on the cyclic oxidation resistance of selected Ni-base superalloys; high temperature oxidation of Fe based alloys; the morphological development of high temperature oxide scales of Fe-Mn-Al base alloys; and the oxidation of an Fe-Mn-Al-C alloy at 1000 C. Consideration is given to the corrosion properties of Fe-Mn-Al alloys; passive films formed on nonmagnetic Cr-Mn-N stainless steels in chloride containing ...

British Library Electronic Table of Contents (United Kingdom)

Background The 2003 outbreak of severe acute respiratory syndrome (SARS) infected over 8000 people and killed 774. Transmission of SARS occurred through direct and indirect contact and large droplet nuclei. The World Health Organization recommended the use of household disinfectants, which have not been previously tested against SARS coronavirus (SARS-CoV), to disinfect potentially contaminated environmental surfaces. There is a need for a surrogate test system given the limited availability of the SARS-CoV for testing and biosafety requirements necessary to safely handle it. In this study, the antiviral activity of standard household products was assayed against murine hepatitis virus (MHV), as a potential surrogate for SARS-CoV. Methods A surface test method, which involves drying an amo...

Energy Technology Data Exchange (ETDEWEB)

A metal spray apparatus is provided with a supersonic nozzle. Molten metal is injected into a gas stream flowing through the nozzle under pressure. By varying the pressure of the injected metal, the droplet can be made in various selected sizes with each selected size having a high degree of size uniformity. A unique one piece graphite heater provides easily controlled uniformity of temperature in the nozzle and an attached tundish which holds the pressurized molten metal. A unique U-shaped gas heater provides extremely hot inlet gas temperatures to the nozzle. A particularly useful application of the spray apparatus is coating of threads of a fastener with a shape memory alloy. This permits a fastener to be easily inserted and removed but provides for a secure locking of the fastener in high temperature environments.

British Library Electronic Table of Contents (United Kingdom)

Spherical nano-sized YSZ (yttria stabilized ZrO2) powders were successfully synthesized via a reverse microemulsion system. The water droplets in the microemulsion system of yclohexane/water/span85/Triton X-100/hexyl alcohol can act as the nano-reactors which solubilize zirconium oxychloride and ammonia water separately. The minute original reactors are favor to the formation of nano-sized spherical YSZ powders and the dispersibility of the powders can be controlled effectually by adjusting the weight ratio of the LiNO3 molten salt to the precursor. The phase transformation from cubic to monoclinic starts at and 500??C and finally monoclinic and cubic phase with increased crytallinity coexist at 800??C. The effect of LiNO3 molten salt in the formation of YSZ powders was also discussed.

British Library Electronic Table of Contents (United Kingdom)

An experimental investigation on the air/water counter-current two-phase flow in a horizontal rectangular channel connected to an inclined riser has been conducted. This test-section representing a model of the hot leg of a pressurized water reactor is mounted between two separators in a pressurized experimental vessel. The cross-section and length of the horizontal part of the test-section are (0.25mx0.05m) and 2.59m, respectively, whereas the inclination angle of the riser is 50degree. The flow was captured by a high-speed camera in the bended region of the hot leg, delivering a detailed view of the stratified interface as well as of dispersed structures like bubbles and droplets. Countercurrent flow limitation (CCFL), or the onset of flooding, was found by analyzing the water levels mea...

Energy Technology Data Exchange (ETDEWEB)

A classical model is presented for magnetic field-induced Wigner crystallization in electron systems confined within two-dimensional quantum dots. In contrast to other classical models, this one does not treat an electron as a point charge; the electron density is assumed to take a Gaussian form corresponding to the lowest Landau level. Using a Monte Carlo method we have determined the equilibrium configurations as functions of the magnetic field. We have found a classical counterpart of the quantum maximum density droplet (MDD) and studied the breakdown of the MDD into a Wigner molecule as well as the transformations of the Wigner molecule shape induced by the external magnetic field. The phase diagram for the classical Wigner molecules has been presented and its qualitative agreement with previous quantum mechanical calculations has been shown.

Energy Technology Data Exchange (ETDEWEB)

This invention refers to the organic geochemistry and can be used in prospecting for oil and gas. The method includes taking samples of rocks, extracting from them the chloroform bitumoid and its thermal processing. In order to improve the accuracy, the equal quantities of bitumoid taken are exposed to gradual thermal treatment to temperatures exceeding the thresholds of thermal stability of sulfur-containing compounds, in each temperature interval, the content of hydrogen sulfide released in this case is revealed, and by its drastic increase at temperatures corresponding to the temperatures of the productive part of the section, a conclusion is drawn about the epigenetic nature of the bitumoid. The method makes it possible to improve the resolution of the bituminological prospecting for oil and gas.

International Nuclear Information System (INIS)

Corrosion testings of model alloys, corresponding by chemical composition to simple and complex-alloyed #gamma#- and #gamma#'-phases of nickel heat-resistant alloys are conducted in sodium sulfate and chloride melts. It is ascertained that heat resistant nickel alloys containing over 50 % of hardening #gamma#'-phase, are subject to disastrous sulfide corrosion (SC). Resistance against SC alloys containing below 50 % of #gamma#'-phase is determined by the resistance of #gamma#-solid solution. 10 refs., 3 figs., 2 tabs.

Science.gov (United States)

Anaerobic processes have been widely used for the treatment of various high-strength industrial wastewaters. However, application has been limited for the treatment of sulfate-rich industrial wastewaters, such as those from the petrochemical, and mining industries. Wastewaters containing benzoate and sulfate were treated in two upflow anaerobic sludge blanket (UASB) reactors at 34--37 C for 320 d. The sulfate concentration was increased stepwise in Reactor-A up to 7,500 mg/L, and was kept mostly constant at 3,000 mg/L in Reactor-B. Both reactors removed over 98% of organic chemical-oxygen demand (COD) for sulfate up to 6,000 mg/L, despite the fact that the mixed liquor contained up to 769 mg S/L of total sulfides and up to 234 mg S/L of dissolved H{sub 2}S. Sulfate0reducing efficiency decreased with the increase in sulfate concentration, but increased with time at each sulfate concentration. Reactor-B consistently reduced 89% of sulfate. However, both organic COD ...

Energy Technology Data Exchange (ETDEWEB)

Our work is towards mechanistically understanding interactions of unsaturated bacterial biofilms and their extracellular polymeric substances (EPS) with actinide metals and metal surrogates under vadose zone conditions. Because metal contaminants in the vadose zone co-occur with organic pollutants, some of our work has included experiments with organic pollutants.

Energy Technology Data Exchange (ETDEWEB)

Numerical simulations are used to predict the migration of radionuclides from the disposal units at Material Disposal Area G through the vadose zone and into the main aquifer in support of a radiological performance assessment and composite analysis for the site. The calculations are performed with the finite element code, FEHM. The transport of nuclides through the vadose zone is computed using a three-dimensional model that describes the complex mesa top geology of the site. The model incorporates the positions and inventories of thirty-four disposal pits and four shaft fields located at Area G as well as those of proposed future pits and shafts. Only three nuclides, C-14, Tc-99, and I-129, proved to be of concern for the groundwater pathway over a 10,000-year period. The spatial and temporal flux of these three nuclides from the vadose zone is applied as a source term for the three-dimensional saturated ...

International Nuclear Information System (INIS)

Boiling phenomenon is responsible for impurities concentration in the liquid phase and then can involve chemically aggressive conditions. This paper presents the methodology developed by NOVATOME to know the water quality conditions in the boiling zone and under deposits, in order to improve corrosion tests and materials reliability and safety. Calculations show that concentration of chloride and sodium hydroxide for example can reach significant levels which may lead to corrosion risks. (author).

Science.gov (United States)

A new dual focal point electro-optic lens that is switchable to focusing and unfocusing is proposed and successfully demonstrated. This electro-optic lens is constructed by coating transparent fine electrodes in the Fresnel-zone plate onto a PLZT ceramic plate. Its focal length changes from 1.25 m to infinity binary at 515 nm with the external voltage of 210 V. PMID:20725208

Energy Technology Data Exchange (ETDEWEB)

Resistive analogous meters for spatial and time characteristics in ocean agitation are most often used in practical oceanography in coastal zones but are based on bridge circuits determined to have shortcomings in their linearity range. This shortcoming is eliminated in the circuit of an instrument developed in an oceanographic laboratory (IMIO, Vana). Principle and block circuits are indicated, and static calibration curves are presented as are the correlative functions in the frequency spectrums obtained with the help of sea agitation recorded at a fixed point and at a depth of 6 meters.

Energy Technology Data Exchange (ETDEWEB)

Previous models of fault-propagation folding used kink-band geometries to approximate folding in front of propagating thrusts. However, kink-band kinematics cannot replicate the curved fold surfaces and complex strain patterns innatural and experimental fault-propagation folds, which also occur in front of steeper reverse and normal faults. Fault-propagation fold hinges tighten and converge downward, forming a triangular zone of penetrative deformation focused on the tip of the propagating fault. The downward convergence of deformation in fault-propagation folds can be modeled as triangular shear zones. Trishear, here defined as distributed, strain-compatible shear in a triangular (in profile) shear zone, provides an alternate kinematic model for fault-propagation folds. Trishear is analogous to simple shear in a tabular shear zone except that area balance in a triangular shear zone ...

International Nuclear Information System (INIS)

Technique, allowing to investigate straggling zone (full braking) from high-energy charged particles in detail, is described. Experimental results on investigation of efective structure, created in polycrystalline molybdenum (99.97%) within 29 MeV alpha-particles straggling zone for fluences from 3.8x10"1"9 up to 3.7x10"2"1 #alpha#/m"2 by methods of microhardness (H_#mu#, X-ray structural analysis (#DELTA#a/a) and transparent electron microscopy (TEM), are presented. It is determined, that for doses from 3.8x10"2"0 #alpha#/m"2 and higher, at #approx#6 MeV energy, molybdenum ''softening'' is observed, H_#mu# curve within straggling zone is well described by alloyage calculated profile. #DELTA#a/a measurements within straggling zone are well described by damage profile. TEM-investigations have shown the developed defective structure even within molybdenum ''softening'' range.

Science.gov (United States)

We study the emission zone in a single-layer polymer light-emitting diode. The emission zone is found by studying the angular distribution of the electroluminescence. The emission is modeled by accounting for optical interference. We account for birefringence of the anode layer in our model. The active polymer was, however, found to be isotropic. The anode consists of a single-layer of the conducting polymer complex poly(3,4-ethylenedioxythiophene) and poly(styrene sulfonate) (PEDOT-PSS), with enhanced conductivity. As a cathode we use plain aluminum. By using only PEDOT-PSS we avoid having a thin metal layer or indium-tin-oxide as the anode in the path of the escaping light. The active material is a substituted polythiophene with excellent film forming properties. A comparison between the experimental and calculated angular distribution of light emission from a single-layered polymer light-emitting diode was shown to be in good agreement for ...

Energy Technology Data Exchange (ETDEWEB)

During the early years of the INEL, the USGS conducted extensive studies (sitewide drilling program) of the geology and hydrology of the area collecting varied data over the years. The unsaturated zone has not received much attention until recently. The studies that have been done are a result of problems or concerns arising from liquid radioactive waste disposal. The TRA facility has the most information published about its waste disposal activities. The ICPP has less data about the unsaturated zone due to the fact that most waste water disposal has been to a well. Little is known about the effect of waste water disposal at the NRF on the unsaturated zone. Essentially no information was found about waste disposal activities at other facilities, primarily because there does not appear to be any reported problems associated with waste water disposal at these locations. The RWMC has received much attention in the last few ...

Energy Technology Data Exchange (ETDEWEB)

The problem during the continuous idling operation of diesel engine is about the time increase in emission of HC (hydrocarbon which is not burned yet) into the atmosphere. A pilot injector having been developed, the time increase in HC emission was studied in order to ameliorate the combustion during the idling. An engine and spray unit were used with the above developed pilot injector for the experiment. Three types of injector were also used for the comparison purpose. Investigation was made of penetration characteristics of spray on the pump tester in the atmosphere, locally averaged droplet size distribution inside the spray, both droplet size and velocity distributions, and emission characteristics by the mounting test onto the engine. The developed pilot injector was most effective in controlling the HC emission. The time increase in HC emission is attributable to the adhering quantity of carbon. The adhering of carbon is caused by the ...

Energy Technology Data Exchange (ETDEWEB)

The finite-volume based commercial CFD-code Fluent was used to simulate the reacting flow in a heavy fuel oil fired laboratory furnace. Both the standard {kappa}-{epsilon} turbulence model and the Reynolds stress model (RSM) were tested. The combustion model was based on the conserved scalar (mixture fraction) and prescribed probability density function approach. The heavy fuel oil droplet trajectories were predicted by solving the momentum equations for the droplets using the Lagrangian treatment. The soot distribution in the furnace was calculated by solving a transport equation for the soot mass fraction. Simple expressions for the soot formation and oxidation rates were employed. The radiation heat transfer equation was solved using the finite volume method. The formation of thermal NO from molecular nitrogen was modeled according to the extended Zeldovich mechanism. Fuel-based NO was modeled assuming that all the nitrogen in the fuel is ...

International Nuclear Information System (INIS)

In this paper, a phenomenological model of the thermal hydraulics of convective boiling in the post-critical-heat-flux (post-CHF) regime is developed and discussed. The model was implemented in the TRAC-PF1/MOD2 computer code (an advanced best-estimate computer program written for the analysis of pressurized water reactor systems). The model was built around the determination of flow regimes downstream of the quench front. The regimes were determined from the flow-regime map suggested by Ishii and his coworkers. Heat transfer in the transition boiling region was formulated as a position-dependent model. The propagation of the CHF point was strongly dependent on the length of the transition boiling region. Wall-to-fluid film boiling heat transfer was considered to consist of two components: first, a wall-to-vapor convective heat-transfer portion and, second, a wall-to-liquid heat transfer representing near-wall effects. Each contribution was considered separately in each of the inverted ...

Science.gov (United States)

B-cell Chronic Lymphocytic Leukemia; Nodal Marginal Zone B-cell Lymphoma; Recurrent Adult Burkitt Lymphoma; Recurrent Adult Diffuse Large Cell Lymphoma; Recurrent Adult Diffuse Mixed Cell Lymphoma; Recurrent Adult Diffuse Small Cleaved Cell Lymphoma; Recurrent Adult Grade III Lymphomatoid Granulomatosis; Recurrent Adult Immunoblastic Large Cell Lymphoma; Recurrent Adult Lymphoblastic Lymphoma; Recurrent Grade 1 Follicular Lymphoma; Recurrent Grade 2 Follicular Lymphoma; Recurrent Grade 3 Follicular Lymphoma; Recurrent Mantle Cell Lymphoma; Recurrent Marginal Zone Lymphoma; Recurrent Small Lymphocytic Lymphoma; Splenic Marginal Zone Lymphoma; Waldenstrom Macroglobulinemia

Energy Technology Data Exchange (ETDEWEB)

The subscale Varestraint test has been used to determine the relative hot cracking susceptibility of the fusion zone in four commercial heats of alloy 800. Although all four heats were susceptible to cracking, one heat exhibited a significant increase in cracking relative to the other three. Optical metallography revealed that nearly all the cracking was localized along fusion zone grain boundaries. Microprobe analysis of the grain boundaries detected high concentrations of titanium, silicon, and niobium resulting from partitioning during solidification. The fusion zone hot cracking mechanism in alloy 800 involves the complex interaction of titanium, silicon, niobium, and carbon along the solidification boundaries. SEM and Auger analyses of the hot crack fracture surfaces revealed the presence of (Ti, Nb)-rich carbides, suggesting that these particles precipitate from the liquid which solidifies last on the fracture ...

Energy Technology Data Exchange (ETDEWEB)

Competitive bidding for ancillary services (A/S), in addition to bidding for energy, is increasingly recognized as an important part of electricity markets. In this paper, an LP-based approach is presented for solving the multi-product (i.e. energy and A/S products), multi-zone/area physical market dispatch problem. The approach can explicitly represent various constraints, such as reserve requirement constraints, network security limits, and sharing of constrained resource capacity (e.g. maximum unit generation) between energy and reserve. The joint dispatch method, which dispatches energy and reserve market concurrently, is extended to allow inter-zonal reserve trading in multi-zone competitive pool. Numerical examples are included to demonstrate the salient characteristics of the joint dispatch solution.

British Library Electronic Table of Contents (United Kingdom)

The Jaduguda U (?Cu?Fe) deposit in the Singhbhum shear zone has been the most productive uranium deposit in India. Pyrite occurs as disseminated grains or in sulphide stringers and veins in the ore zone. Veins, both concordant and discordant to the pervasive foliation, are mineralogically either simple comprising pyrite ? chalcopyrite or complex comprising pyrite + chalcopyrite + pentlandite + millerite. Nickel-sulphide minerals, though fairly common in concordant veins, are very rare in the discordant veins. Pyrite in Ni-sulphide association is commonly replaced by pentlandite at the grain boundary or along micro-cracks. Based on concentrations of Co and Ni, pyrite is classified as: type-A ? high Co (up to 30800?ppm), no/low Ni; type-B ? moderate Co (up to 16500?ppm) and moderate to high ...

Energy Technology Data Exchange (ETDEWEB)

In the world of pipeline maintenance, there are pigs and there are intelligent pigs. Intelligent pigs, when launched into a pipeline, carry instrumentation onboard which enables them to gather and record information about problems such as denting, corrosion, and cracking. More basic pigs, on the other hand, look after the routine internal maintenance chores such as cleaning and swabbing, or else perform operational duties such as batching different types of product along the line. The harsh environment in which pigs often operate is described. Aside from the mechanical shocks they undergo when passing welds, bends, and other fittings, they may have to contend with hostile conditions such as hydrogen sulfide environments. High pressure is another factor to consider. In crude oil lines, significant paraffin deposits also can cause problems if they affect the sensors ability to maintain good contact with the pipe wall. In spite of these considerations, increasing ...

British Library Electronic Table of Contents (United Kingdom)

The present investigation deals with the synthesis of nanostructured nickel ferrite (NiFe2O4) and their liquid petroleum gas-sensing characteristics. The 15-20nm size nickel ferrite has been synthesized at 700degreeC by a simple molten-salt route using sodium chloride as grain growth inhibitor. These nanoparticles exhibit significantly high response towards liquid petroleum gas (LPG) in comparison with ethanol vapor, hydrogen sulfide, ammonia and hydrogen. The gas response towards various gases at their 200ppm concentrations is investigated at 200-450degreeC. Different characterization techniques have been employed, such as differential thermal analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and high resolution transmission elec...

Energy Technology Data Exchange (ETDEWEB)

This paper investigates steels 12Kh18N10T, 10Kh17N13M2T, 08Kh22N6T, and 08Kh21N6M2T. In corrosion of stainless steels in sulfuric acid solutions, dissolved sulfur dioxide acts as a cathodic depolarizer, capable of being reduced to elemental sulfur or forming sulfides with the metal. Depending on the conditions, this is associated with some increase in potential and greater or lesser increase in corrosion or facilitation of passivation of active steel. After passivation the influence of SO/sub 2/ is negligible. The results of this investigation were used as initial data for developing systems of anodic protection for shell-and-tube heat exchangers for sulfuric acid.

British Library Electronic Table of Contents (United Kingdom)

SBA-15 supported nano-scaled copper oxide was synthesized by impregnation method via ultrasonic-assisted route. The removal test from gas mixture containing 0.1?vol.% hydrogen sulfide was carried out over this material at atmospheric conditions. The effects of the chemical nature of copper oxide and the textural properties of the material on removal capacity were studied. The materials before and after the removal test were analyzed by nitrogen adsorption, X-ray diffraction, Transmission Electron Microscope, X-ray photoelectron Spectroscopy, Fourier Transform Infrared Spectrometer and Inductive Coupled Plasma. The results showed that copper species are located predominantly in mesopore channels, existing as copper oxide nanoparticles. Mesopores are active sites for removal reaction. The ou...

Energy Technology Data Exchange (ETDEWEB)

Discusses results of investigations into catalytic properties of various minerals during hydrogenation of Kansk-Achinsk brown coal with a view to replacing synthetic compositions based on molybdenum. Describes tests and equipment used in hydrogenation of grade B-2 Borodinsk deposit coal in tetralin (hydrogen donor). Various by-products of metallurgical processes and compounds separated from tailings containing mainly iron and sulfur and other metals were used as catalysts. States that: minerals containing iron compounds in the form of pyrites, hematites and magnetites exhibit catalytic properties when used in the hydrogenation of brown coal; pyritic catalysts enrich liquid products with hydrogen while sulfur and nitrogen content remains the same; the yield of malthenes with pyritic catalysts is no lower than with alumocobaltmolybdenum catalysts. 18 refs.

International Nuclear Information System (INIS)

An indoor radioactive survey is being conducted in an Italian district. Preliminary results identified a zone with significant radioactive levels, in which a new specific survey has been planned. In this paper attention is dedicated mainly to radon measurement technique and results.

CERN Document Server

We explored ways of doing spatial search within a relational database: (1) hierarchical triangular mesh (a tessellation of the sphere), (2) a zoned bucketing system, and (3) representing areas as disjunctive-normal form constraints. Each of these approaches has merits. They all allow efficient point-in-region queries. A relational representation for regions allows Boolean operations among them and allows quick tests for point-in-region, regions-containing-point, and region-overlap. The speed of these algorithms is much improved by a zone and multi-scale zone-pyramid scheme. The approach has the virtue that the zone mechanism works well on B-Trees native to all SQL systems and integrates naturally with current query optimizers - rather than requiring a new spatial access method and concomitant query optimizer extensions. Over the last 5 years, we have used these techniques extensively in our work on ...

UK PubMed Central (United Kingdom)

BackgroundWhile the gene flow in some organisms is strongly affected by physical barriers and geographical distance, other highly mobile species are able to overcome such constraints....Full Text Available

Energy Technology Data Exchange (ETDEWEB)

The following subjects are dealt with: physics of indoor air flow, flow in individual rooms, exchange of air and pollution between individual building zones and with the outside world, thermal coupling with the building shell, thermal comfort and air quality, evaluation of the ventilation. figs., tabs., refs.

Energy Technology Data Exchange (ETDEWEB)

Treatment of Japanese pines (P. densiflora and P. thunbergii) with paraquat induced a zone of lightwood. Determinations of turpentine and ether extractives contents in lightwoods showed high levels as compared with those in control woods. (Refs. 5).

Energy Technology Data Exchange (ETDEWEB)

Coded imaging techniques using thick, micro-Fresnel zone plates as coded apertures have been used to image x-ray emissions (2-20 keV) and 3.5 MeV Alpha particle emissions from laser driven micro-implosions. Image resolution in these experiments was 3-8 ..mu..m. Extension of this coded imaging capability to higher energy x-rays (approx. 100 keV) and more penetrating charged particles (e.g. approx. 15 MeV protons) requires the fabrication of very thick (50-200 ..mu..m), high aspect ratio (10:1), gold Fresnel zone plates with narrow linewidths (5-25 ..mu..m) for use as coded aperatures. A reactive ion etch technique in oxygen has been used to produce thick zone plate patterns in polymer films. The polymer patterns serve as electroplating molds for the subsequent fabrication of the free-standing gold zone plate structures.

Energy Technology Data Exchange (ETDEWEB)

A method is proposed for operating bed waters in an oil well by injecting silanes into the near-face zone. It is distinguished by the fact that in order to improve the effectiveness of insulation, the silanes used are silanes of general formula Si /SUB n/ H /SUB 2n-n/ .

Energy Technology Data Exchange (ETDEWEB)

The effects of the plasma nitriding with the formation of compound nitride and diffusion zones and of the boronising with the different ion doses on hydrogen distribution and hydrogen induced deterioration of a surface layer were examined in the case of Armco iron. Electrochemical studies of hydrogen permeation rate, hydrogen vacuum extraction measurements, optical and scanning microscopy, X-ray diffraction and elastic recoil detection analysis (ERDA) were used. Accumulation of entering hydrogen within the various constituent zones of the modified layer inhibits the hydrogen transport into the metal and thus, decreases the mean hydrogen content in the deeper zones and in the core. Hydrogen accumulation within the compact nitride zone causes the expansion of the nitride lattice, nitride phase transformation and deterioration. The ion boronising enhances the hydrogen effects in the plasma nitrided layers. ...

Science.gov (United States)

Field campaigns were conducted in 1981 and 1982/83 on the Dutch coast near Egmond. Measurements were made of surface elevations, water velocities and sediment concentrations in 3 to 8 surf zone locations and 2 to 5 offshore locations simultaneously. A des...

Science.gov (United States)

Sulfur dioxide emissions from an iron ore sintering plant have severely damaged vegetation up to 16 km northeast of the source. Concentric zones of increasing vegetation loss have formed around the point of maximum ground level concentration of the gas. Species diversity, sulfur and heavy metal concentrations in vegetation and soil amount to SO/sub 2/ injury were measured along a transect through the injury zones. Surrounding a central denuded area were zones dominated respectively by tussock-forming hair grass (Deschampsia flexuosa); low-growing shrubs and trailers (Sambucus pubens, Polygonum cilinode); higher-growing shrubs and suckering Populus tremuloides and Betula papyrifera) stunted forest tree species (Populus, Betula, Picea glauca, Abies Balsamea), and finally, normal boreal forest flora. Although SO/sub 2/ injury is continuing in this area, these zones now appear to be maintained primarily by ...

UK PubMed Central (United Kingdom)

An image slicing spectrometer (ISS) for microscopy applications is presented. Its principle is based on the redirecting of image zones by specially organized thin mirrors within a custom fabricated...Full Text Available

Science.gov (United States)

Jun 16, 2011 ... Results indicated that fuel loadings averaged 24.05 Mg ha 1 in 2004–2006. Forest litter decreased from wetter to drier forest life zones. ...

UK PubMed Central (United Kingdom)

In multiple sclerosis (MS), oligodendrocyte and myelin destruction lead to demyelination with subsequent axonal loss. Experimental demyelination in rodents has highlighted the activation of the subventricular...Full Text Available

Science.gov (United States)

Approximately 1.2 million kg of uranium oxide (yellow cake) has been produced from the area surrounding Gunnison, Colorado. Over 99 percent of this has come form the Cochetopa and Marshall Pass districts. Uranium in both districts and many of the other occurrences is associated closely with fault and shear zones which cut brittle host formations (sandstones and dolomites) of Paleozonic and Mesozoic age. Minor uranium occurrences are in pegmatites and shear zones in Precambrian rocks, Cambrian vein material, and sandstones of Tertiary age. In the paper presented, the uranium occurences are described by districts. In addition, possibilities for additional discoveries are discussed. (JMT)

Energy Technology Data Exchange (ETDEWEB)

The present paper is concerned with the prediction method for the motions and tensions of mooring lines on slack-moored floating oceanic architectural building in coastal zone. The motions and the tensions of mooring lines were estimated by the time domain numerical simulation in the present method. The present method includes the nonlinearity of mooring system, slow varying wave drift force. The authors performed a time domain numerical simulation for motions and the tensions of mooring lines on floating barge in two component waves. Also, the results obtained by numerical simulation were compared with the experimental results. The validity of the present method was confirmed.

Energy Technology Data Exchange (ETDEWEB)

A process for the production of transportation fuels from heavy hydrocarbonaceous feedstock is provided comprising a two-stage, close-coupled process, wherein the first stage comprises a hydrothermal zone into which is introduced a mixture comprising a feedstock and metals-impregnated red mud having coke-suppressing and demetalizing activity, and hydrogen; and the second, close-coupled stage comprises a hydrocatalytic zone into which substantially all the effluent from the first stage is directly passed and processed under hydrocatalytic conditions. The preferred metals for impregnation include transition metals, in particular, nickel and molybdenum.

Energy Technology Data Exchange (ETDEWEB)

This work deals with the development of wind maps in the Venezuelan coastal zones (South America). The Navier-Stokes equations for real viscous incompressible flow are discretized via the finite element method and they are applied to a full 3D numerical model. Two regions were analyzed: the Margarita island and the Paraguana peninsula, both of them located in the Caribbean Sea at the North of Venezuela. These regions were modeled by using a three dimensional control volume, discretized through hexaedric eight-noded finite elements. Some wind maps obtained in this research are presented and discussed. (author)

International Nuclear Information System (INIS)

Water repellency en the microstructure super-hydrophobic cured surface is important for research and industrial purposes. This microstructure film can be cured on polyethylene terephthalate PET surface by electron beam (EB) at different irradiation doses 10-100 kGy. The microstructure formulation composed from hydrophobic acrylate oligomer (EB 244) and monomer (SR 440). The irradiation induced cross linking of the prepared microstructure was proved by FTIR spectroscopy and the adhesion force by abrasion test. Some factors affecting the adhesion force of the prepared microstructure film such as oligomer/monomer composition ratio and the thickness of the microstructure cured film were studied. The contact angles (8) were measured on cured surfaces before and after adding the super hydrophobic nanoparticles (Zonyl 9361). The super-hydrophobic cured surface showed the self-cleaning property. The volume of water droplet affected both the observed contact angle and its ...

Science.gov (United States)

Poncirin, flavanone glycoside, isolated from the fruit of Poncirus trifoliata, has anti-bacterial and anti-inflammatory activities. In this study, the effects of poncirin on the differentiation of mesenchymal stem cells were investigated. The C3H10T1/2 mesenchymal stem cells and primary bone marrow mesenchymal stem cells were studied. In the C3H10T1/2 cells, poncirin prevented adipocyte differentiation, as demonstrated by inhibition of cytoplasm lipid droplet accumulation and peroxisome proliferator-activating receptor-? (PPAR-?) and CCAAT-enhancer-binding protein-? (C/EBP-?) mRNA expression. By contrast, poncirin enhanced the expression of the key osteogenic transcription factors, runt-related transcription factor 2 (Runx2) and transcriptional coactivator with PDZ-binding motif (TAZ). Poncirin also enhanced expression of the osteogenic marker genes including alkaline phosphatase (ALP) and osteocalcin (OC). Poncirin increased mineral nodule formation in primary ...

International Nuclear Information System (INIS)

The multidimensional countercurrent two-phase flow regimes that occur in a pressurized-water reactor (PWR) vessel downcomer during the refill phase of a large-break loss-of-coolant accident are studied using a transparent 1/10 scale model of a PWR vessel. The various flow regimes and their distribution in the downcomer have been identified and mapped for a range of air-water flooding experiments. The two-phase flow patterns that are identified in the downcomer included various types of film flows, droplet flows, countercurrent churn flows and cocurrent flows depending on the flooding condition. Through observation of the two-phase flow dynamics it was deduced that the physical mechanisms associated with the flooding processes could be separated into a liquid entrainment process and a film flow reversal process. In addition to the above exercise, the effect of non-uniform injection of water into the downcomer via different combinations of cold leg was studied ...

Energy Technology Data Exchange (ETDEWEB)

A technique was developed that permits fluid flow to be visualized even where the flow is completely shrouded by metal. The technique employs real-time neutron radiography, which is similar to x-ray radiography except a collimated beam of neutrons is used. Various combinations of neutron-opaque tracer materials were tested with neutron-transparent fluid. Neutron opaque tracers, such as solid particles, fluid droplets, and streaklines were imaged through metal walls as they convected in neutron-transparent ambient fluid. Visualization of bubbles/voids were evaluated for possible future applications. Surface-flow patterns were also imaged by using neutron-opaque tufts. These techniques were evaluated for image contrast, resolution, and the ability to accurately track fluid flow fields. The techniques were also modeled to optimize contrast in various flow configurations. Imaging techniques such as real-time video, high speed video, and photographic techniques were ...

International Nuclear Information System (INIS)

Along with the shrinkage of LSI geometries, a higher quality of ultrapure water has been continuously required. Analytical technology for ultrapure water has also progressed before ultrapure water production technology improvements. In this study, we performed optimization of the analytical conditions for the direct analysis of acid droplets, and established an analytical technology for measurements of trace amounts of metallic impurities deposited on a wafer surface by means of Vapor Phase Decomposition (VPD)/Inductively Coupled Plasma Mass Spectrometry (ICP-MS). As a result, analytical technology for metallic elements of the 1x10"8 atoms/cm"2 level on wafer surface has been established. By applying analytical technology to the wafer that has been contacted with ultrapure water, a new evaluation technology for ultrapure water quality by means of wafer surface contamination has been established. We confirmed good correlations between metal contamination of the ...

International Nuclear Information System (INIS)

The major driver to enhance the efficiency of the simple gas turbine cycle has been the increase in process conditions through advancements in materials and cooling methods. Thermodynamic cycle developments or cycle integration are among the possible ways to further enhance performance. The current paper presents the possibilities and advantages from the LOTHECO natural gas-fired combined cycle concept. In the LOTHECO cycle, low-temperature waste heat or solar heat is used for the evaporation of injected water droplets in the compressed air entering the gas turbine's combustion chamber. Following a description of this innovative cycle, its advantages are demonstrated by comparison between different gas turbine power generation systems for small and large-scale applications, including thermodynamic and economic analysis. A commercial gas turbine (ALSTOM GT10C) has been selected and computed with the heat mass balance program ENBIPRO. The results from the energy ...

CERN Document Server

This work investigates the impingement of a liquid microdroplet onto a glass substrate at different temperatures. A finite-element model is applied to simulate the transient fluid dynamics and heat transfer during the process. Results for impingement under both isothermal and non-isothermal conditions are presented for four liquids: isopropanol, water, dielectric fluid (FC-72) and eutectic tin-lead solder (63Sn-37Pb). The objective of the work is to select liquids for a combined numerical and experimental study involving a high resolution, laser-based interfacial temperature measurement to measure interfacial heat transfer during microdroplet deposition. Applications include spray cooling, micro-manufacturing and coating processes, and electronics packaging. The initial droplet diameter and impact velocity are 80 {\\mu}m and 5 m/s, respectively. For isothermal impact, our simulations with water and isopropanol show very good agreement with experiments. The ...

Energy Technology Data Exchange (ETDEWEB)

In this paper, a mathematical model for a counterflow wet cooling tower is derived, which is based on one-dimensional heat and mass balance equations using the measured heat transfer coefficient. The balance equations are solved numerically to predict the temperature change of air and water, as well as the humidity as a function of the cooling tower high. Experimental measurements on two pilot-scale cooling towers were carried out in order to analyze the performance of different cooling tower filling materials. Also, the performance of other cooling tower elements, such as droplet separators and water spray nozzles, was investigated in the pilot experiments. The flow distribution, i.e. the velocity field, upstream to the filling material was predicted using the three-dimensional version of the computational fluid dynamics (CFD) code Fluent/UNS, version 4.2. The calculated flow fields are presented for different distances between the inlet of the air and the filling ...

Energy Technology Data Exchange (ETDEWEB)

The uncertainty associated with the sorption coefficient, or K{sub d} value, is one of the key uncertainties in estimating risk associated with burying low-level nuclear waste in the subsurface. The objective of this study was to measure >648 K{sub d} values and provide a measure of the range and distribution (normal or log-normal) of radionuclide K{sub d} values appropriate for the E-Area disposal site, within the Savannah River Site, near Aiken South Carolina. The 95% confidence level for the mean K{sub d} was twice the mean in the Aquifer Zone (18-30.5 m depth), equal to the mean for the Upper Vadose Zone (3.3-10 m depth), and half the mean for the Lower Vadose Zone (3.10-18 m depth). The distribution of K{sub d} values was log normal in the Upper Vadose Zone and Aquifer Zone, and normal in the Lower Vadose Zone. To our knowledge, this is the first ...

Energy Technology Data Exchange (ETDEWEB)

An Fe-19Cr-8Al-0.5Hf alloy has been roll bonded to Alloy 800 to form a protective clad material suitable for use in coal conversion atmospheres. The commercial producibility of both the Fe-19Cr-8Al-0.5Hf alloy and the clad composite has been demonstrated. The clad composite has been shown to exhibit resistance to sulfidation in high sulfur, coal gasification atmospheres low Btu for 2000 hrs at 1800/sup 0/F (1255K). The FeCrAlHf alloy must be preoxidized in the absence of sulfur to form fully protective alumina scales on all surfaces. Useful life of the composite at temperatures of 1400 to 2000/sup 0/F (1033 to 1366K) is governed by reactions at the FeCrAlHf clad alloy 800 interface. The rate of interdiffusion decreases with increasing Ni content and a high Ni alloy such as RA333 appears to be a better substrate than Alloy 800 for a FeCrAlHf composite. The mechanical properties of the clad composite have been evaluated at both ambient (tensile and bend) and elevated ...

Energy Technology Data Exchange (ETDEWEB)

The novel optical, electronic, and/or magnetic properties of metal and semiconductor nanoparticles have resulted in extensive research on new methods for their preparation. An ideal preparation method would allow the particle size, size distribution, crystallinity, and particle shape to be easily controlled, and would be applicable to a wide variety of material systems. Numerous preparation methods have been reported, each with its inherent advantages and disadvantages; however, an ideal method has yet to emerge. The most widely applied methods for nanoparticle preparation include the sonochemical reduction of organometallic reagents,(1&2) the solvothermal method of Alivisatos,(3) reactions in microemulsions,(4-6) the polyol method (reduction by alcohols),(7-9) and the use of polymer and solgel materials as hosts.(10-13) In addition to these methods, there are a variety of methods that take advantage of the unique properties of a supercritical fluid.(14&15) Through simple ...

Energy Technology Data Exchange (ETDEWEB)

The grey-black mudstones of the Sonehat Formation form part of the Middle Jurassic fill of the Jameson Land Basin in East Greenland. The formation is exposed in the southernmost part of the north south-trending, Mesozoic rift system in East Greenland that was part of the epeiric seaway betaveen East Greenland and Norway. Sedimentological observations of the Sortehat Formation indicate deposition in an offshore marine setting that was typically low energy and periodically oxygen-deficient but was influenced by storm currents on occasion. Detailed palynological studies of the Sortehat Formation have resulted in the definition of theee palynological assemblage zones recognised at four localities, namely Enhjoerningen Dal and Pelion (north Jameson Land), the type section at Sortehat (central Jameson Land) and Albuen at Neill Klinter along Hurry Inlet (south-east Jameson Land). In stratigraphic order, these zones are termed the Botryococcus ...

Energy Technology Data Exchange (ETDEWEB)

The Coastal Zone Sector of the Canadian Climate Impact and Adaptation Research Network (C-CIARN) was established to address concerns regarding climate change in coastal areas. Coastal zones are sensitive to increases in air, sea and ground temperatures as well as to variations in sea level, precipitation, ice thickness, and storm intensity. This report presents the results of a workshop which focused on how coastal communities will be affected by climate induced water level changes, particularly sea-level rise on ocean coasts and decreasing lake levels in the Great Lakes. The workshop addressed issues such as the effects of changing water levels on coastal infrastructure, utilities, community development, and the implications of changing water levels to human safety, cultural resources, tourism, and insurance. The workshop reviewed the current state of understanding on water level fluctuations resulting from climate change. It also identified ...

Energy Technology Data Exchange (ETDEWEB)

Multilayer mirrors for the extreme ultraviolet (EUV) are keyelements for numerous applications of coherent EUV sources such as newtabletop lasers and free-electron lasers. However the field ofapplications is limited by the radiation and thermal stability of themultilayers. Taking into account the growing power of EUV sources thestability of the optics becomes crucial. To overcome this problem it isnecessary to study the degradation of multilayers and try to increasetheir temporal and thermal stability. In this paper we report the resultsof detailed study of structural changes in Sc/Simultilayers when exposedto intense EUV laser pulses. Various types of surface damage such asmelting, boiling, shockwave creation and ablation were observed asirradiation fluencies increase. Cross-sectional TEM study revealed thatthe layer structure was completely destroyed in the upper part ofmultilayer, but still survived below. The layers adjacent tothe substrateremained intact even through the ...

Science.gov (United States)

Marine ecosystems are suffering severe depletion of apex predators worldwide; shark declines are principally due to conservative life-histories and fisheries overexploitation. On coral reefs, sharks are strongly interacting apex predators and play a key role in maintaining healthy reef ecosystems. Despite increasing fishing pressure, reef shark catches are rarely subject to specific limits, with management approaches typically depending upon no-take marine reserves to maintain populations. Here, we reveal that this approach is failing by documenting an ongoing collapse in two of the most abundant reef shark species on the Great Barrier Reef (Australia). We find an order of magnitude fewer sharks on fished reefs compared to no-entry management zones that encompass only 1% of reefs. No-take zones, which are more difficult to enforce than no-entry zones, offer almost no protection for shark populations. Population viability ...

Energy Technology Data Exchange (ETDEWEB)

The impacts of the expected climate change on Finnish lake ecosystems were studied with the biota of the mesohumic Lake Paeaejaervi, southern Finland. Experimental conditions, from small-scale experiments on single species level to a large-scale ecosystem manipulation, were established to simulate directly the future climate and/or loading of nutrients and dissolved organic matter (DOM) from the drainage area. The experimental studies were accomplished by modelling the carbon flow in the pelagic food web as well as the growth of littoral macrophytes. The main hypothese tested were as follows: As a consequence of the climate change (rising temperature and increasing precipitation) the loading of nutrients and dissolved organic matter (DOM) from the drainage area to the lake will increase. In the pelagic zone this will be first reflected i higher productivity of primary producers and bacteria, but will later affect the entire food chain. Increase in atmospheric ...

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Assessment of the oil shale resources in Kentucky has continued with 75 NX cores available where the oil shale crops out or is overlain by relatively thin cover in the area from Estill County westward to Bullitt County. In this 14 county area, the total black shale section thins across the crest of the Cincinnati arch and changes stratigraphically from that characteristic of the Ohio Shale in Estill County to that of the New Albany Shale in Bullitt County. Despite this stratigraphic transition the two high-carbon zones (greater than 8.0% carbon) can be traced across the arch. As the traverse is followed from the east, the intervening low-carbon zones thin such that at the crest of the arch, there are areas where the entire section of black shale contains more than 8% carbon. Then upon leaving the crest the two high-carbon zones separate again with one remaining at the very top of the section and one in the lower part. In ...

Energy Technology Data Exchange (ETDEWEB)

California's pacific coast stretches roughly over 11.5 latitudinal degrees, extending from about 32.5{sup o}N to 44{sup o}N. There is nearly 900nm of California coastline offering superior opportunity for wave energy use. The longitudinal position of the coast shifts eastward at two distinct locations: Punta Gorda just south of Cape Mendecino in the north and Point Conception in the south. The change in longitudinal orientation in southern California also coincides with significant change in California's bathymetry. The tilts in the longitudinal coastal lines at the two points also define California wave zones into three areas: the short coastal line north of Punta Gorda, the long north and middle line between the two points, and the short line of the heavily populated southern coast. The northern and central zones are characterized by high waves of relatively low frequency; the southern coast is characterized by low waves of ...

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The pilot area of the Vyngapour oil field allotted for MIOR tests contains three injection and three producing wells. These wells were treated in summer 1993 and 1994. Before, during, and after MIOR treatments on the pilot area the chemical compounds of injected and formation waters were studied, as well as the amount and species of microorganisms entering the stratum with the injected water and indigenous bacteria presented in bottomhole zones of the wells. The results of monitoring showed that the bottomhole zone of the injection well already had biocenosis of heterotrophic, hydrocarbon-oxidizing, methanogenic, and sulfate-reducing bacteria, which were besides permanently introduced into the reservoir during the usual waterflooding. The nutritious composition activated vital functions of all bacterial species presented in the bottomhole zone of the injection well. The formation waters from producing wells showed the ...

CERN Document Server

The bright star 55 Cancri is known to host five planets, including a transiting super-Earth. The interferometric study presented here yields directly determined values for 55 Cnc's stellar astrophyiscal parameters: $R=0.943 \\pm 0.010 R_{\\odot}$, $T_{\\rm EFF} = 5196 \\pm 24$ K. We use isochrone fitting to determine 55 Cnc's age to be 10.2 $\\pm$ 2.5 Gyr, implying a stellar mass of $0.905 \\pm 0.015 M_{\\odot}$. Our analysis of the location and extent of the system's habitable zone (0.67--1.32 AU) shows that planet f ($M \\sin i = 0.155 M_{Jupiter}$) spends the majority of the duration of its elliptical orbit in the circumstellar habitable zone, where, with moderate greenhouse heating, it could harbor liquid water. Finally, our direct value for 55 Cancri's stellar radius allows for a model-independent calculation of the physical diameter of the transiting super-Earth 55 Cnc e ($\\sim 2.05 \\pm 0.15 R_{\\earth}$), which, depending on the ...

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The NACE MR-01-75 standard imposes a restriction of 22HRC maximum for regions of a pipeline girth weld that are not in direct contact with H[sub 2]S containing environments. TWI have demonstrated in an earlier project for the Pipeline Research Committee (PRC) that it may be permissible to relax this maximum hardness requirement. Such a relaxation, which already exists in the BS4515: 1984 standard, offers potential benefits when applied to the capping pass and heat affected zone of a pipeline girth weld. This report presents additional data to supplement that obtained in a previous PRC project conducted at TWI. Further pipe materials with differing pipe wall thicknesses have been welded, exposed to an internal H[sub 2]S containing environment and examined for sulphide stress corrosion cracking.

International Nuclear Information System (INIS)

During the normal operation of a Nuclear Power Plant (NPP), radioactive releases into the atmosphere will be in small quantities. During major accidental situations, though the probability is extremely small, there may be significant release of radioactivity to the environment through the stack or at ground level. To study the external radiation exposure, if any, to the members of public due to releases during the normal operation of a nuclear power plant (NPP) and also to meet the requirement of emergency preparedness for the NPP site, continuous recording and analysis of environmental dose rate data is essential. This paper presents analysis of the gamma dose rates recorded by the Environmental Dose Logging Systems (EDLS) installed around the site during the last six years in the Emergency Planning Zone (EPZ) of Tarapur Atomic Power Station (TAPS). (author)

International Nuclear Information System (INIS)

In order to evaluate postclosure off-site doses from low-level radioactive waste disposal facilities, a computer code was developed to simulate the radionuclide released from waste form, transport through vadose zone and transport in the saturated zone. This paper describes the methodology used to model these process. The radionuclide released from the waste is calculated using a model based on first order kinetics and the transport through porous media was determined using semi-analytical solution of the mass transport equation, considering the limiting case of unidirectional convective transport with three-dimensional dispersion in an isotropic medium. The results obtained in this work were compared with other codes, showing good agreement. (author)

Energy Technology Data Exchange (ETDEWEB)

With the aim of optimizing the nitriding process, experimental studies of the plasma nitriding of four selected steels were carried out, using a d.c. glow discharge. The process parameters were varied systematically. By means of transmission and scanning electron microscopy and X-ray diffraction, the microstructures, including the thicknesses of the compound zones and the diffusion zones of the nitrided steels, were obtained. Using cross-sectional samples and a micro-Vickers indenter, hardness depth profiles were also obtained. From the time and temperature dependences of the hardness profiles, effective diffusion constants and corresponding activation enthalpies were obtained. Furthermore, in an attempt to shed some light on the atomistic nitriding mechanisms, the glow discharges were studied by measuring energy spectra of the energetic ions hitting the cathode (the steel test specimens). It was shown that an increase of the mean energy of the ...

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Interest in the tribological properties of plasma nitriding has increased substantially over the past years because plasma nitriding provides a high nitride depth and improved hard facing. The present study examines the tribological properties of AISI H11 plasma nitrided, hot-worked steel. Different nitriding temperatures and durations were considered. Characterization of the composite structures was investigated with wear tests, x-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), and microhardness tests. The depth profile of the nitrided zone was measured using the nuclear reaction analysis (NRA) technique. Plasma nitriding affected the microhardness, wear properties, and morphology considerably. Increase in process temperature increased the nitride zone depth.

British Library Electronic Table of Contents (United Kingdom)

Runit Island on Enewetak Atoll was very heavily impacted by the U.S. nuclear testing campaign in the northern Marshall Islands (1946?58). The primary source of contamination on Runit Island was the 1958 Quince safety test where a large quantity of device plutonium (Pu) was scattered over the area near the GZ. A second low-yield device was detonated on the same site 10?days later, further disturbing the soil and leaving behind a very heterogeneous pattern of contamination including milligram-size particles of plutonium. A limited cleanup of the Fig-Quince zone was carried out in 1979. During this period, the effectiveness of the cleanup operations was primarily evaluated on the basis of bulk soil concentration data with little consideration given to the heterogeneity and long-term material-...

International Nuclear Information System (INIS)

The biota of the Mississippi River in an ecological recovery zone near Red Wing, MN was studied before and after start-up of a nuclear plant to acquire baseline data and to estimate changes due to thermal addition. Thermal addition produced significant decreases in primary production in a plant region during summer month periods when water temperatures were near 36C. Extensive fisheries studies and sonar tagging/tracking of S. vitreum were performed. Comparison of fisheries results with other riverine, lake, and pond studies indicated a favorable environment for the success of the fish species studied. Qualitative macroinvertebrate surveys were conducted.

British Library Electronic Table of Contents (United Kingdom)

In energy industries, it is always of difficulty to produce high heat value(HHV) gas continuously using pulverized coal. In this paper, a new type furnace for partitioned alternative gasification using pulverized coal is developed, in which the oxidation and reduction reaction occur alternatively with the dropping of pulverized coal and finally HHV gas could be continuously obtained at the reduction zone exit and low heat value(LHV) gas at the oxidation zone exit. Furthermore, the gasification characteristics and their factors in furnace are numerically simulated under two dimensional model with a self-coded program, based on heat, mass and energy transfer as well as reaction principles. It is found that the producing rate of HHV gas is 1.10Nm3/kg with heat value of 11.72MJ/Nm3, however, t...

British Library Electronic Table of Contents (United Kingdom)

Soufriere Hills Volcano had two periods of repetitive Vulcanian activity in 1997. Each explosion discharged the contents of the upper 0.5-2km of the conduit as pyroclastic flows and fallout: frothy pumices from a deep, gas-rich zone, lava and breadcrust bombs from a degassed lava plug, and dense pumices from a transition zone. Vesicles constitute 1-66vol.% of breadcrust bombs and 24-79% of pumices, all those larger than a few tens of m being interconnected. Small vesicles (few hundreds of m) in pumices are interpreted as pre-dating explosion, implying pre-explosive conduit porosities up to 55%. About a sixth of large vesicles in pumices, and all those in breadcrust bombs, are angular voids formed by syn-explosive fracturing of amphibole phenocrysts. An intermediate-sized vesicle population...

British Library Electronic Table of Contents (United Kingdom)

The integrity of the cables located in the target room is very important in the Fire PSA, because the CDF and CCDP are changed according to the results of a cable integrity that depends on the surrounding gas temperature. The conservative assumptions used in the Fire PSA typically specify that all of the equipment and cables of a room would fail when a fire happens in the room. But the realistic assessment of a fire risk by using a fire simulation tool has become necessary in the Fire PSA as described in the ANS Fire PRA Standard. This paper evaluates the cable integrity of eight pump rooms in the nuclear power plant by using the CFAST zone fire model. The upper layer gas temperature of each room is estimated, and an analysis based on the results of model simulations is used to judge the c...

Energy Technology Data Exchange (ETDEWEB)

A multi-zone computational model in conjunction with some engine tests are used to examine the combustion process of gas fueled diesel engines commonly known as dual fuel engine to provide information about details of the production of exhaust emissions, especially at light load when very lean mixtures are employed. Detailed chemical reaction kinetic simulation is employed for each of these individual combustion zones so as to establish the associated temporal variations in the concentrations of reacting species right to the exhaust stage. The influence of changes in major operating and design parameters such as the concentration of the gaseous fuel in the cylinder charge, intake temperature and the size of the diesel pilot fuel employed on the production of the exhaust emissions are examined. It is demonstrated in general that any measure that tends to increase the size of the combustion regions within the overly lean cylinder charge will ...

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The content and biosynthesis of glycosaminoglycans (GAGs) were studied in pig thigh muscle after acute local {gamma}-irradiation. Seven months following irradiation, the muscular tissue next to the irradiation cone was replaced by severe mutilating fibrosis delimited by an intermediary perifibrotic zone. Results showed a parallel increase of collagen and GAG content in perifibrotic and fibrotic tissues. Sulphated GAGs, heparan sulphate and dermatan sulphate were preferentially accumulated in fibrotic tissue, while the hyaluronic acid content increased only slightly. Synthesis of sulphated GAGs was more elevated in fibrotic tissue than in perifibrotic zone as compared with normal muscle. Seven months after irradiation well-developed fibrotic tissue continued to synthesize and to accumulate extracellular matrix macromolecules. (Author).

British Library Electronic Table of Contents (United Kingdom)

WC-Co hardmetals with gradient structure comprising neither -phase nor grain growth inhibitors were produced for the first time by regulating the WC re-crystallisation and carbon content in their near-surface layer and core. Hardmetals with low Co contents in the surface region were obtained by selective carburisation of the near-surface zone of green articles with the original low carbon content and their consequent liquid-phase sintering. The surface region of such gradient hardmetals has a hardness of up 150 Vickers units higher and fracture toughness significantly superior than those of the core. Gradient hardmetals with high Co contents in the surface region were obtained by selective decarburisation of the near-surface zone of green articles with the original high carbon content and ...

Science.gov (United States)

This report presents the operating results for Run 245 at the Advanced Coal Liquefaction R and D Facility in Wilsonville, Alabama. This run was made in an all-distillate Integrated Two-Stage Liquefaction (ITSL) mode using Illinois 6 coal from the Burning Star mine. The primary run objective was to obtain steady-state ITSL performance by replacing spent HTR reactor catalyst with fresh, sulfided catalyst. Secondary objectives were to maintain an all-distillate (minimum resid production) product slate and to demonstrate the effects of catalyst addition on the net gas production and hydrogen consumption. Run 245 began on 7 November, 1983, and continued through 12 February, 1984. During this period, 179.0 tons of coal was fed in 2045 hours of operation. Eight special product workup material balances were defined, and the results are presented herein. 6 references, 28 figures, 20 tables.

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The Electrochemical Program at Argonne National Laboratory (ANL) provides technical and programmatic support to DOE`s Electric and Hybrid Propulsion Division (DOE-EHP). The goal of DOE-EHP is to advance promising electric-vehicle (EV) propulsion technologies to levels where industry will continue their commercial development and thereby. significantly reduce petroleum consumption in the transportation sector of the economy. In support of this goal, ANL provides research, development, testing/evaluation, post-test analysis, modeling, database management, and technical management of industrial R&D contracts on advanced battery and fuel cell technologies for DOE-EHP. This report summarizes the battery-related activities undertaken during the period of October 1, 1991 through March 31, 1992. In this report, the objective, background, technical progress, and status are described for each task. These tasks are structured into the following task areas: 1.0 Project Management and ...

Energy Technology Data Exchange (ETDEWEB)

The Electrochemical Program at Argonne National Laboratory (ANL) provides technical and programmatic support to DOE's Electric and Hybrid Propulsion Division (DOE-EHP). The goal of DOE-EHP is to advance promising electric-vehicle (EV) propulsion technologies to levels where industry will continue their commercial development and thereby. significantly reduce petroleum consumption in the transportation sector of the economy. In support of this goal, ANL provides research, development, testing/evaluation, post-test analysis, modeling, database management, and technical management of industrial R D contracts on advanced battery and fuel cell technologies for DOE-EHP. This report summarizes the battery-related activities undertaken during the period of October 1, 1991 through March 31, 1992. In this report, the objective, background, technical progress, and status are described for each task. These tasks are structured into the following task areas: 1.0 Project Management and ...

Energy Technology Data Exchange (ETDEWEB)

The Electrochemical Technology Program at Argonne National Laboratory (ANL) provides technical and programmatic support to DOE's Electric and Hybrid Propulsion Division (DOE-EHP). The goal of DOE-EHP is to advance promising electric-vehicle (EV) propulsion technologies to levels where industry will continue their commercial development and thereby significantly reduce petroleum consumption in the transportation sector of the economy. In support of this goal, ANL provides research, development, testing/evaluation, post-test analysis, modeling, database management, and technical management of industrial R D contracts on advanced battery technologies for DOE-EHP. This report summarizes the battery-related activities undertaken during the period of July 1, 1992 through September 30, 1992. In this report, the objective, background, technical progress, and status are described for each task. The work is organized into the following task areas: Project Management and Coordination; ...

International Nuclear Information System (INIS)

Sediment treatment and sediment storage may alter sediment toxicity, and consequently biotic response. Purpose of our study was to combine these three aspects (treatment-toxicity-biotic response) in one integrated approach. We used Acid Volatile Sulfide (AVS) concentrations as a proxy of the disturbance of the sediment. AVS and Simultaneously Extracted Metal (SEM) concentrations were compared to bioassay responses with the freshwater benthic macroinvertebrate Asellus aquaticus. Storage conditions and sediment treatment affected AVS but not SEM levels. AVS can be used as a proxy for sediment disturbance. The best way to pretreat the sediment for use in a bioassay in order to maintain initial AVS conditions was to sample the sediment with an Ekman grab, immediately store it in a jar without headspace, and freeze it as soon as possible. In a survey using seven different sediments, bioassay responses of A. aquaticus were correlated with SEM and AVS characteristics. - ...

Energy Technology Data Exchange (ETDEWEB)

The effects of thiosulfate ion and solution pH on pitting corrosion of Alloy 690 in chloride solution were explored. Potentiodynamic polarization measurements were conducted to evaluate pitting corrosion susceptibility of Alloy 690 in these environments. The results showed that pitting corrosion occurred in the mill-annealed (1050 deg. C/5min) Alloy 690 in 1 wt% NaCl solution but not in 0.1 M Na{sub 2}S{sub 2}O{sub 3} solution. The value of pitting nucleation potential (E{sub np}) determined in 1 wt% NaCl solution (without Na{sub 2}S{sub 2}O{sub 3} ) increased with increasing solution pH value in the range of 2-10. The addition of Na{sub 2}S{sub 2}O{sub 3} to 1 wt% NaCl solution greatly affected the pitting corrosion behavior, which was dependent on concentration. The preformed nickel sulfide surface film due to the presence of Na{sub 2}S{sub 2}O{sub 3} caused Alloy 690 to become more susceptible to pitting corrosion in 1 wt% NaCl solution.

Energy Technology Data Exchange (ETDEWEB)

Metallic components within or immediately adjacent to gasifiers, such as gas distributors, thermowells, transfer lines, and cyclones, are subjected to severe of temperature, pressure, and hostile multicomponent gas environments. Metallic heat exchangers/waste-heat boilers resistant to sulfidation, corrosion. and erosion in low- and medium-Btu gas environments are essential components in large-scale gasification schemes, in both dry ash and slogging type gasifiers. Components, in general. must be resistant to corrosion, erosion, and high-temperature creep. A substantial data base is needed on the mechanical properties of materials exposed to complex gas environments to provide a more viable basis for establishing long-term reliability of components. This work examines high-temperature creep of Alloy 800, a high-chromium alloy widely used in coal conversion systems, after exposure to oxygen and oxygen/sulfur mixed-gas environments over a wide temperature range. In ...

Energy Technology Data Exchange (ETDEWEB)

The NiMo sulfide supported on Ketjen Black (KB) was more effective and yielded lighter oil products containing light fractions with their boiling point below 300{degree}C during the two stage liquefaction combining low temperature and high temperature hydrogenation the conventional NiMo/alumina catalyst and FeS2 catalyst. Although the NiMo/alumina yielded increased oil products during the two stage liquefaction, the lighter oil fractions did not increase and the heavier fractions increased mainly. This suggests that the hydrogenation of aromatic rings and successive cleavage of the rings are necessary for producing the light oil, which is derived from the sufficient hydrogenation of aromatic rings using catalysts. For the two stage reaction with NiMo/KB catalyst, it was considered that sufficient hydrogen was directly transferred to coal molecules at the first stage of the low temperature reaction, which promoted the solubilization of coal and the successive ...

Energy Technology Data Exchange (ETDEWEB)

An advanced process for the separation of hydrogen sulfide (H{sub 2}S) from coal gasification product streams through an electrochemical membrane is being developed. H{sub 2}S is removed from the syn-gas stream, split into hydrogen, which enriches the exiting syn-gas, and sulfur, which is condensed from an inert sweep gas stream. The process allows removal of H{sub 2}S without cooling the gas stream and with negligible pressure loss through the separator. The process is made economically attractive by the lack of need for a Claus process for sulfur recovery. Membrane manufacturing coupled with full-cell experimentation was the primary focus this quarter. A tape-casted zirconia membrane was developed and utilized in one full-cell experiment (run 25); run 24 utilized a fabricated membrane purchased from Zircar Corporation. Results are discussed.

International Nuclear Information System (INIS)

The fundamental optical properties of dysprosium (Dy) doped strontium sulfide bulk samples for various dopant concentrations from 0.1 to 1.0 at.% were investigated by X-ray diffraction (XRD), electron paramagnetic resonance spectroscopy (EPR), room temperature photoluminescence (PL), photoluminescence excitation (PLE) and diffuse reflectance spectroscopy (DRS). Investigations by electron paramagnetic resonance yielded the state of Dy in the sample as Dy3+. An additional ESR line due to F+ center was observed. The PL emission spectrum consisted of several intense lines and a number of weaker ones which were identified as transitions between energy levels of Dy3+. The optimum doping concentration for maximum intensity was found to be 0.25 at.%. Blue shift of the absorption edge energy and red shift of the PLE spectrum were observed with increasing doping concentration. The former is due to Burstein-Moss (BM) effect and the latter is attributed due to the presence of ...

International Nuclear Information System (INIS)

Previous corrosion studies identified the materials Hastelloy C4, Ti 99.8-Pd, and carbon steels as promising for the manufacture of long-lived high-level waste containers that could act as an engineered barrier in a rock-salt repository. Here, the efficiency of the corrosion-resistant concept using surface-welded Hastelloy C4 as corrosion protection of carbon steel containers is compared with the corrosion-allowance concept using unalloyed or low-alloyed steels. The materials are examined in three disposal relevant brines (two rich in MgCl_2, one rich in NaCl) at 150 C. The results indicate that welded Hastelloy C4 is highly resistant to corrosion in the NaCl-rich brine. In the presence of sulfides or MgCl_2-rich brines, however, severe pitting corrosion occurs. The three steels investigated are resistant to pitting corrosion in all brines, and their general corrosion rates imply corrosion allowances acceptable for thick-walled containers. In view of these results, ...

Energy Technology Data Exchange (ETDEWEB)

Acid mine drainage is a serious environmental problem caused by the oxidation of sulfide minerals that releases highly acidic, sulfate, and metals-rich drainage. In this study, alkaline industrial wastes were mixed with acid mine tailings in order to obtain neutral conditions. A series of column leaching tests were performed to evaluate the behavior of reactive mine tailings amended with alkaline-additions under dynamic conditions. Column tests were conducted of oxidized mine tailings combined with cement kiln dust, red mud bauxite, and mixtures of cement kiln dust with red mud bauxite. The pH results show the addition of 10% of alkaline materials permits the maintenance of near neutral conditions. In the presence of 10% alkaline material, the concentration of toxic metals such as Al, Cu, Fe, Zn are significantly reduced as well as the number of viable cells (Thiobacillus ferrooxidans) compared to control samples.