Energy Technology Data Exchange (ETDEWEB)

The evaluated data testing for Si, Zr, Nb and Fe materials has been performed through the analyses of the neutron leakage spectrum from spherical assemblies measured in integral benchmark experiments with (d,t) and Cf fission neutron sources. Intercomparisons of the calculated from BROND-2, ENDF/B-6 and JENDL-3 data files with experimental results are presented.

Science.gov (United States)

... Accession Number : ADD336001. Title : Development of a FeCoNb Alloy to be used in Eddy Current Probes for Testing Ferromagnetic Tubes,. ...

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AZ31 and experimental ZMA611 alloys were strip cast into 2 mm thick strips. The as-cast AZ31 alloy strip consists of columnar dendrites. On the other hand, as-cast ZMA611 alloy strip shows equiaxed dendritic structure through the thickness of strip. These alloys were subjected to various thermomechanical treatments and their tensile properties were evaluated. Strip cast AZ31 alloy in H24 condition has equivalent yield and tensile strengths with similar ductility compared to commercial ingot cast AZ31-H24 alloy, indicating that strip casting is a viable process for the fabrication of Mg alloy strips. The ZMA611 alloy has a large volume fraction of fine dispersoid particles in the microstructure, resulting from the beneficial effect of strip casting on microstructural refinement. It has been shown that the ZMA611 ...

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Magnesium alloys are being increasingly utilized in a variety of fields as an alternative material to organic materials and aluminum alloys, owing to excellent properties. Those include low density, and excellent damping properties. When compared to organic materials, furthermore, Mg alloy excels at recyclability, heat radiation, and electromagnetic-shielding. Though most of magnesium alloy products are manufactured through die-casting and thixo-molding at present, the demand for the expanding of magnesium wrought alloy market is increasing. Taking full advantage of a drawing technique and applying it to the conventional extruded pipe, we have developed a new type of magnesium alloy pipe. The strength of the developed pipe is significantly higher than that of the conventional one, either extruded or die-casting. Some of ...

Science.gov (United States)

A number of alloys of zirconium have been investigated as part of a program aimed at improving the high-temperature tensile and creep strength of zirconium. These alloys include aluminum, beryllium, lead, magnesium, molybdenum, niobium, tantalum, tin, titanium, tungsten, vanadium, and zinc, binary and ternary alloys. The data indicate that aluminum, lead, molybdenum niobium, tin, titanium, tungsten, and vanadium can be used successfully to harden zirconium, and that aluminum, tin, titanium, and vanadium are particularly effective in maintaining the strength of zirconium at elevated temperatures.

International Nuclear Information System (INIS)

A new high strength titanium alloy has been developed primarily intended for fastener applications. While Ti-6Al-4V is used extensively as a fastener alloy in the aerospace industry, its shear strength allowable is limited to 655 MPa (95 ksi). For higher shear strength requirements, various steels or nickel-based alloys are used (up to 860 MPa (125 ksi)), but with the attendant density penalty. This new alloy is intended to provide the 860 MPa shear strength at roughly a 40% weight savings. After screening various alloy systems, the optimum chemistry has been selected as follows: Ti-6.0V-6.2Mo-5.7Fe-3Al. In light of its 125 ksi shear strength goal, the alloy has been designated TIMETAL reg-sign 125.

Science.gov (United States)

Probabilistic sensitivities using the score function method are developed for a lifing analysis of an alpha + beta titanium alloy in a round bar under axial fatigue load. Sensitivities with respect to the statistical inputs of the crack initiation size (a...

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The time-temperature-precipitation diagrams and the resulting time-temperature-sensitization diagrams have been established and are presented for today's current nickel-chromium-molybdenum alloys C-4, C-276, 22 and the recently developed alloy 59. Compared to those materials alloy 625 behaves differently due to its high niobium content. In addition, also the precipitation and sensitization of alloy G-3 has been established. Under the materials considered alloy C-276 has the strongest tendency to precipitate the intermetallics Mu and P together with the carbide M{sub 6}C at intermediate temperatures, followed by the alloys 22 and 59. The tendency to sensitization in the sense of the 50{mu}m (2 mils) intercrystalline penetration criterion when exposed to the ASTM G-28, method A test solution is greatest with alloy ...

International Nuclear Information System (INIS)

Recent advances made in the area of amorphous and nanocrystalline alloys exhibiting high saturation inductions are reviewed. A new chemical composition was identified that achieves a saturation induction of 1.64 T in an iron-based amorphous alloy. This alloy, when used in electrical transformers, shows a much improved performance over the existing amorphous alloy. Nanocrystalline FeCoCuNbSiB alloys are found to have saturation induction levels reaching 1.7 T. These materials are suited for use in sensors and inductors carrying large currents. Some of these nanocrystalline alloys show a BH squareness ratio exceeding 90%, which can be utilized in pulse power devices. Recent developments in the applications of these materials are also pointed out.

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The distribution of graphite particles in graphite containing copper alloy was further improved very significantly using several procedures and technological modifications. The developed techniques attacked the graphite distribution problem in two ways. Realizing that clustering of very fine (5um) graphite particles is one of the two major problems, a pretreatment process has been developed using aluminum powders to deagglomerate graphite particles. Along with this, a two-stage stirring technique was used to first incorporate and then to distribute uniformly the deagglomerated particles in the melt. During this year, based on these developments, several components were cast to evaluate the castability of Cu alloy-graphite melts. In addition, machinability tests were done to clearly established that addition of graphite particles improve the machinability of copper MMC ...

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Describes performance of excavator teeth manufactured with a new hard alloy. The alloy was developed by the Donetskii Politeknicheskii Institute. Its composition consists of a high-chromium steel with a larger amount of titanium than serial alloy, and a nitrogen additive. Trial tests of new alloy teeth were carried out in the Severnyi and Vershinskii coal surface mines. The teeth were attached to EhRP, EhPG and EhR bucket wheel excavators. Abrasive wear of 129 experimental teeth and 134 serial teeth was compared for different excavation conditions. Test results are tabulated; advantages of the new experimental teeth are listed. 3 refs.

International Nuclear Information System (INIS)

Existing applications of Alloy 800 are summarized, with particular reference to its use in various types of reactor. The need for a co-ordinated research and development programme is stressed, and the variables to be explored are outlined. The papers relating to the problem of corrosion and cracking in water and steam are considered. the strength and ductility of Alloy 800 is considered. Finally, sections of the summary deal with the use of Alloy 800 for (a) sodium cooled fast reactor boiler tubes; (b) the high temperature gas cooled reactor; and (c) PWR steam generator tubes. (U.K.).

International Nuclear Information System (INIS)

Superplasticity in Ti alloys has been widely investigated in the past and superplastic forming of aerospace components has thus been developed over the last two decades. The Ti alloy most studied in this framework is undoubtedly the Ti-6Al-4V (wt %) alloy, for which maximum elongations are obtained in the temperature range [880-900C]. The development of the superplastic properties has been demonstrated to be in close relation with quite similar volume fractions of the #alpha# and #beta# phases, the #beta# transus temperature for this alloy ranging from 980-1000 C. Attempts have been carried out to reduce the temperature of superplastic forming of Ti-6Al-4V by the addition of elements like Fe, Co, or Ni. Such an introduction of alloying elements indeed results in a decrease of the optimum forming temperature to values as low as 820 C. This ...

International Nuclear Information System (INIS)

In response to European operating experience regarding Alloy 800 steam generator (SG) tube cracking, New Brunswick Power Nuclear (NBPN) recognized two important shortcomings in the industry SG technical support framework. First, information exchange networks between utilities with Alloy 800 SG tubing should be strengthened. Second and more importantly, there is a need for consistent industry guidance for Alloy 800 SG tubing degradation management, supported by clear technical bases. It is NBPN's perspective that this guidance can be improved immediately using the extensive amount of laboratory and field data that is available for Alloys 600, 690, and 800, and EPRI methodology developed to predict the performance of Alloy 690. NBPN has initiated the development of a performance-based inspection plan. This effort is based on demonstrated ...

International Nuclear Information System (INIS)

It is shown that bending tests on microsamples can be used to study the conditions in which hydrogen brittleness develops. In such tests hydrogen brittleness develops in the VTI5 alloy within the temperature range +5 to -20"0C. The tendency of VTI5 to develop hydrogen brittleness is enhanced with bending in salt water. (author).

Energy Technology Data Exchange (ETDEWEB)

The effect of concentration on the corrosion behavior of Mg-based alloy AZ91D was investigated in ethylene glycol-water solutions using electrochemical techniques i.e. potentiodynamic polarization, electrochemical impedance measurements (EIS) and surface examination via scanning electron microscope (SEM) technique. This can provide a basis for developing new coolants for magnesium alloy engine blocks. Corrosion behavior of AZ91D alloy by coolant is important in the automotive industry. It was found that the corrosion rate of AZ91D alloy decreased with increasing concentration of ethylene glycol. For AZ91D alloy in chloride >0.05 M or fluoride <0.05 M containing 30% ethylene glycol solution, they are more corrosive than the blank (30% ethylene glycol-70% water). However, at concentrations <0.05 for chloride or >0.05 M for fluoride ...

International Nuclear Information System (INIS)

The microstructures of so called high temperature alloys, which have been developed for service temperatures up to 800"0C, are not necessarily stable at higher temperatures. The mobility of alloying elements is very high in FeCrNi alloys at 950 "0C e.g. iron, chromium or nickel can diffuse up to 0.1 mm distance in one year, which is about a grain diameter. Interstitials like carbon or nitrogen show a four orders of magnitude higher diffusivity than the alloying elements. In addition, the carbon solubility in this type of alloy is reported to be very low. Therefore the alloys are supersaturated with carbon after heat treatment above 1100 "0C and water quenching although the absolute carbon content is very low. At service temperatures around 800"0C the solubility of carbon is still about one order of magnitude lower than at heat treatment ...

International Nuclear Information System (INIS)

The weldability and high temperature strength properties of tungsten-inert-gas (TIG) weldments of Hastelloy alloy XR were investigated by using two different heats of filler metals; the first (HXRF1) was designed on the basis of multiple regression analysis; the second (HXRF2) was the reference material. Bend tests, the FISCO cracking test and optical metallography were used to evaluate weldability. Tensile and creep tests were performed at 900deg C to evaluate high temperature strength properties. The results of weldability tests for both alloys showed good performance. The tensile properties of the weldments were remarkably improved in particular with respect to high temperature ductility. The creep rupture strength in the weldments made with alloy-designed HXRF1 was much higher than those of the Hastelloy alloy XR-II base metal with a higher B content. Furthermore, the creep properties were stable ...

Energy Technology Data Exchange (ETDEWEB)

Mg-3%Al-1%Zn (AZ31) alloy was subjected to ECAE processing at 523 and 573 K. Microstructure observation and texture analysis were carried out using optical microscope and SEM-EBSD technique in order to investigate the process of microstructural changes including texture development during ECAE processing. Grain refinement during ECAE processing is enhanced by dynamic continuous recrystallization. The texture of the ECAE-processed AZ31 alloy specimens change with ECAE processing temperature, and the textural changes relate to deformation mechanisms that change with ECAE processing temperature. (orig.)

Energy Technology Data Exchange (ETDEWEB)

FeSi{sub 6}/graphite composite was prepared by mechanical ball milling. The FeSi{sub 6} alloy particles consist of an electrochemically active silicon phase and inactive phases FeSi{sub 2}, distributed uniformly in the graphite matrix. The composite anode offers a large reversible capacity (about 800 mAh g{sup -1}) and good cycleability, due to the buffering effect of the inactive FeSi{sub 2} phase and graphite layers on the volumetric changes of Si phase during lithium-Si alloying reaction. Since FeSi{sub 6} alloy is a low-cost industrial material, this alloy compound provides a possible alternative for development of high capacity lithium-ion batteries. (author)

Energy Technology Data Exchange (ETDEWEB)

An extensive R and D program on the development of the joining technologies between armour (beryllium, tungsten and carbon fibre composites)/copper alloys heat sink and copper alloys/ stainless steel has been carried out by ITER Home Teams. A brief review of this R and D program is presented in this paper. Based on the results, reference technologies for use in ITER have been selected and recommended for further development. (author)

Energy Technology Data Exchange (ETDEWEB)

The development of structural barriers for nuclear waste packages involves selection of candidate materials, their screening by mechanical and corrosion testing, rigorous accelerated testing, and evaluation and comparison with other package elements. This document presents results from work conducted on titanium and ferrous alloys.

International Nuclear Information System (INIS)

An alloy of composition Ti-4.4 wt.% Ta-1.9 wt.% Nb is being developed as a structural material for corrosion applications, as titanium and its alloys possess excellent corrosion resistance in many oxidizing media. The primary physical metallurgy database for the Ti-4.4 wt.% Ta-1.9 wt.% Nb alloy is being presented for the first time. Determination of the #beta# transus, M_s temperature and classification of the alloy have been carried out, employing a variety of microscopy techniques, X-ray diffraction (XRD), micro-hardness and differential scanning calorimetry (DSC). The #beta# transition temperature or #beta# transus determined using different experimental techniques was found to agree very well with evaluations based on empirical calculations. Based on chemistry and observed room temperature microstructure, the alloy has been classified as an #alpha# + #beta# ...

Energy Technology Data Exchange (ETDEWEB)

An Fe-19Cr-8Al-0.5Hf alloy has been roll bonded to Alloy 800 to form a protective clad material suitable for use in coal conversion atmospheres. The commercial producibility of both the Fe-19Cr-8Al-0.5Hf alloy and the clad composite has been demonstrated. The clad composite has been shown to exhibit resistance to sulfidation in high sulfur, coal gasification atmospheres low Btu for 2000 hrs at 1800/sup 0/F (1255K). The FeCrAlHf alloy must be preoxidized in the absence of sulfur to form fully protective alumina scales on all surfaces. Useful life of the composite at temperatures of 1400 to 2000/sup 0/F (1033 to 1366K) is governed by reactions at the FeCrAlHf clad alloy 800 interface. The rate of interdiffusion decreases with increasing Ni content and a high Ni alloy such as RA333 appears to be a better substrate than Alloy 800 for a FeCrAlHf ...

International Nuclear Information System (INIS)

Magnetic properties of a recently developed Fe-based amorphous alloy with a high saturation induction of 1.65 T are reviewed. The increased saturation induction is fully utilized in transformers with reduced magnetic losses, physical sizes and audible noises, minimizing some of the drawbacks of amorphous metal-based transformers based on a currently available amorphous alloy. Impacts of this on the worldwide energy savings and reduction of greenhouse gas emissions are discussed. A recent effort in achieving a saturation induction beyond 1.65 T in nanocrystalline alloys is mentioned.

International Nuclear Information System (INIS)

In a program to develop a metastable beta alloy with improved fracture toughness, it was found that the tensile ductility of the alloy Ti-8 Mo-4.5 Cr-2.5 Al was strongly dependent on both processing history and annealing temperature. Evaluation of the microfracture mode of tensile samples by scanning electron microscope and metallographic techniques showed that the presence of a continuous grain boundary alpha is the most significant parameter controlling the ductility and is highly detrimental. It is concluded that, for optimum processing, the material must be worked prior to aging to avoid this grain boundary phase.

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Extrusion and subsequent heat treatment of the alloys investigated can lead to reasonable room temperature ductilities and very high strengths being developed compared to the cast + HlPed material. In Ti-45Al-10Nb reasonably room temperature fracture toughness was developed which did not depend on extrusion temperature. For the alloy Ti-48Al-2Cr-0.2C a previously developed solution and ageing heat treatment did not increase the high temperature strength properties when compared to the 'annealed' condition. (orig.)

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A new technique has been developed for improving corrosion resistance on magnesium alloys. Specimens of AZ31 magnesium alloy were dipped into molten salt of NaBF{sub 4} at 723 K for various times, and then cooled, rinsed with water, and dried in air. Corrosion resistance in the surface treated specimens was evaluated by salt immersion test using 1% NaCl solution as a time for occurring filiform corrosion. On an un-treated AZ31 alloy, the time for starting the filiform corrosion was about 1.2 ks, while on the surface treated specimen, the time was prolonged into about 1300 ks. Moreover, the surface treated specimen showed corrosion resistance in low pH solutions, such as 1% HNO{sub 3} and HCl solutions. (orig.)

Energy Technology Data Exchange (ETDEWEB)

The chemical composition and the semiconducting properties of passive films formed on nickel based alloy (Alloy 600) in acidic sulphate solution, pH 2.0 at room temperature were studied using Auger analysis, voltammetric techniques and the Mott-Schottky approach. The results obtained revealed that the presence of both chromium and mixed nickel-iron oxides in the films leads to the development of a p-n heterojunction, which controls their electronic structure, similarly manner to the case of stainless steels and Alloy 600 in borate buffer solution. This behavior has been interpreted as representing of an oxide system, which has a duplex character, with an inner p-type semiconducting region, mainly formed by chromium oxide and an outer n-type semiconducting region, containing iron oxide. It could also be observed that the nickel oxide present in the films acts as a barrier layer conferring improved ...

International Nuclear Information System (INIS)

Alloy 800 has been used by Siemens since 1968 and is now used by KWU for U-tubed steam generators in PWR's. The particular grade of alloy 800 that is used is within the ASTM-Specification B 163, but there have been modifications in composition to improve the corrosion resistance. First the permitted upper limit of carbon was reduced to 0.04% and was then further reduced to 0.03% and a stabilisation ratio of Ti : C >= 12 and Ti : C + N >= 8 was specified. The minimum permitted chromium and nickel levels were increased to 20% and 32% respectively. The maximum permitted levels of other elements or impurities were reduced. At the final fabrication stage peening with glass beads on the outer surface was specified to introduce a compressive stress to depth greater than that allowed for production flaws. An account is given of the behaviour of the alloy in service in four power plants already in operation, and future ...

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We have been developing an innovative Steam Generator concept of Fast Breeder Reactors by using liquid-liquid direct contact heat transfer. In this concept, the SG shell is filled with a molten alloys, which is heated by primary sodium. Water is fed into the high temperature molten alloy, and evaporates by direct contact heating. In order to obtain the fundamental information to discuss the heat transfer mechanisms of the direct contact between the water and the alloy, this phenomenon was visualized by real-time neutron radiography. JRR-3M real-time thermal neutron radiography in Japan Atomic Energy Research Institute was used. Followings are main results. (1) The vigorous evaporation occurs in the molten alloy. This phenomena is different from the known phenomenon such as the evaporation of refrigerant R-113 in the water. (2) The evaporation in the bubble has finished in a moment ...

International Nuclear Information System (INIS)

The service conditions for high-temperature heat-exchangers with helium coolant of HTGRs and requirements imposed on materials for their production are discussed. The choice of nickel-base alloys with solid-solution hardening for long-term service at high temperatures is grounded. Results of study on properties and structure of types Ni-25Cr-5W-5Mo and Ni-20Cr-20W alloy in the temperature range of 900 deg. - 1,000 deg. C are given. The ageing of Ni-25Cr-5W-5Mo alloy at 900 deg. - 950 deg. C results in decreased corrosion-mechanical properties and is caused by the change of structural metal stability. Alloy with 20% tungsten retains a high stability of both structure and properties after prolonged exposure in helium at above temperatures. The alloy has also increased resistance to delayed fracture and low-cycle fatigue at high temperatures. The developed ...

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The present paper describes the development of ultra-fine grains on the surface of AZ31 alloys caused by hydrogenation and dehydrogenation treatment, so-called HDDR process. Upon hydrogenation process, disproportionation reaction occurred in forming of MgH{sub 2}, Mg{sub 0.42}Al{sub 0.58}, and Al phases. In the following desorption process, the three phases were re-solved into the AZ31 alloy. As a result of the HDDR phenomena, the grain size of AZ31 alloy powders was reduced down to about 100 nm after the heat treatment at 350 C under a hydrogen pressure of 7 MPa for 24 h. The grain size tended to be increased with increasing process temperatures. In addition, the HDDR process was also applied to AZ31 alloy plates. By the HDDR process at 450 C, the grain size was reduced to less than 500 nm, where hydrogenated layer thickness was limited to be in the range of about 20 {mu}m from the ...

International Nuclear Information System (INIS)

As the first step for development of the corrosion resistant superheater tube materials of 500 C, 100 ata used in high efficient waste-to-energy plants, field corrosion tests of six conventional alloys were carried out at metal temperatures of 450 C and 550 C for 700 and 3,000 hours in four typical Japanese waste incineration plants. The test results indicate that austenitic alloys containing approximately 80 wt% [Cr+Ni] show excellent corrosion resistance. When the corrosive environment is severe, intergranular corrosion of 40#approx#200 microm depth occurs in stainless steel and high alloyed materials. It is confirmed quantitatively that corrosion behavior is influenced by environmental corrosion factors such as Cl concentration and thickness of deposits on tube surface, metal temperature, and flue gas temperature. The excellent corrosion resistance of high [Cr+Ni+Mo] alloys such ...

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As part of a coordinated program, AECL is developing a set of tools to aid with the prediction and management of steam generator performance. Although stress corrosion cracking (of Alloy 800) has not been detected in any operating steam generator, for life management it is necessary to develop mechanistic models to predict the conditions under which stress corrosion cracking is plausible. Therefore, constant extension rate tests were carried out for Alloy 800 under various steam generator crevice chemistry conditions at applied potentials. These tests were designed to evaluate the stress corrosion cracking susceptibility of Alloy 800 under CANDU( steam generator operating conditions. Based on the experimental results, the recommended electrochemical corrosion potential/pH zone for Alloy 800 determined by electrochemical polarization measurements was verified ...

International Nuclear Information System (INIS)

An experimental approach has been performed to ascertain the effectiveness of semi-solid strip casting using a horizontal twin roll caster. The demand for light-weight products with high strength has grown recently due to the rapid development of automobile and aircraft technology. One key to such development has been utilization of magnesium alloys, which can potentially reduce the total product weight. However, the problems of utilizing magnesium alloys are still mainly related to high manufacturing cost. One of the solutions to this problem is to develop magnesium casting-rolling technology in order to produce magnesium sheet products at competitive cost for commercial applications. In this experiment, magnesium alloy AZ31B was used to ascertain the effectiveness of semi-solid roll strip casting for producing magnesium alloy sheets. The ...

International Nuclear Information System (INIS)

The paper provides a brief description of the fuel characterization for Fast Breeder Test Reactor (FBTR) and Prototype Fast Breeder Reactor (PFBR). The development and characterization of mechanical properties of Alloy D9 clad and wrapper tubes are discussed. The problems associated with fusion welding of Alloy D9 are outlined. Non-destructive characterization of cladding tubes by optimum encircling eddy current probes, on-line and off-line neural network methods is presented. Both the on-line and off-line neural network methods could readily detect and size defects specified by the designers

Science.gov (United States)

TIMETAL LCB was introduced more than 10 years ago targeting automotive suspension spring applications. The alloy development aim was to use a low-cost formulation by selecting less expensive raw materials than typical beta titanium alloys. Following the first successful application of TIMETAL LCB suspension springs to series production vehicles, the 2000 Volkswagen Lupo FSI, the springs have been used for Ferrari Challenge Stradale since 2003. The most recent development effort was focused on the generation of metallurgical and mechanical service data for the alloy, and the implementation of efficient low cost processing of coils. This paper will introduce various properties of TIMETAL LCB products that can be useful in the design and the consideration of spring applications. Recent progress in the processing of TIMETAL LCB will also be introduced and discussed.

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Water model experiments were conducted to develop a two-stage stirring method for obtaining higher yields and a more uniform distribution of graphite particles in copper alloys. This was followed by several melts for synthesis of copper-graphite alloys in which Ti was used as a wetting agent to improve the wettability of graphite in the copper melt. In the first stage, a vortex method was employed to facilitate the addition of graphite particles into the copper melt. In the second stage, a specially designed stirrer was used for uniform particle distribution while avoiding the formation of vortex in the melt. The two-stage stirring was found to considerably improve the recovery of graphite, over those obtained with the prior practice of single-stage stirring and resulting in a more uniform particle distribution. In addition, graphite recoveries increased with increasing Ti content in the range investigated. Floatation, ...

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Excimer laser processing enables both thermally-driven transformations and the incorporation of solutes into the surface of materials through melting and diffusional mixing. We have examined the effect of excimer laser processing on the microstructure and surface mechanical properties of titanium alloys. Changes in the surface hardness due to laser processing were studied using a Nanoindenter [trademark]. Alloying experiments using both mixing of evaporated surface layers of boron and laser gas alloying in air and in nitrogen all result in changes in the surface hardness of the material. Alloying with boron results in an amorphous surface which is somewhat harder than the as polished surface. Laser processing in air and pure nitrogen results in incorporation of oxygen and nitrogen and the development of fine ([approximately] 50 nm) precipitates of TiO and TiN respectively. ...

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Machines and structures, such as automobiles are usually subjected to biaxial or three-axial stresses instead of uniaxial stress. However, research on a fatigue failure under multi-axial stress has not been fully presented because such experiments are difficult. To solve this problem, we developed the servo biaxial fatigue-testing machine. In this research, we performed the biaxial fatigue tests of a magnesium alloy in order to clarify the effects from different heat treatments. Magnesium alloy is the lightest in weight among metal materials for structural use. The fatigue characteristics of a magnesium alloy are indispensable in order to create the design which ensures the reliability and the safety of the vehicles especially in long-distance run. The main conclusions are summarized as follows; (1) The mechanical property of magnesium alloy AZ31B falls by heat treatment at low ...

Science.gov (United States)

Multiple treatment of engineering surfaces can provide improved surface properties that cannot be obtained by a single surface treatment. Consequently, this study investigates the effects of laser melting on the microstructures of plasma nitrided Ti-6Al-4V alloy. The study consists of two parts. In the first part, governing equations pertinent to the laser melting process are developed, and temperature variation across the melted zone is predicted. In the second, an experiment is conducted to nitride the surface of the alloy through plasma nitriding process and to melt the plasma nitrided and the untreated alloy surfaces with a CO2 laser beam. The resulting metallurgical changes are examined using x-ray diffraction (XRD), bdenergy-dispersive spectrometry (EDS), and scanning electron microscopy (SEM) techniques. It is shown that three distinct nitride layers are formed in the vicinity of the ...

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The wear behaviour of metallic material is influenced by the friction force, which in turn, is governed by the hardness and oxidation kinetics of the mating surface. In view of this, present investigation is undertaken to find the influence of mating surface on the high temperature wear of 253 MA alloy. This alloy is developed for high temperature application. In this work 253 MA alloy is made to slide against two different types of counter face material, namely 100Cr6 steel and PM 1000 alloy, at five different temperatures. 100Cr6 steel gets soften with increase of temperature whereas PM 1000 alloy retains its strength even at high temperature. The friction coefficient and the thickness loss of 253 MA alloy is measured and compared against both variety of mating surfaces as function of temperatures. The morphology of the worn surfaces and ...

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This report presents the results of cladding technology development under the Coal-Fired Combined Cycle DOE Project for the period July 1976 through June 1978. Sub-task 3.1, Clad Alloy Development, involved the selection, fabrication and burner rig evaluation of advanced clad alloy compositions diffusion-bonded to IN-738. Testing was conducted for up to 5800 hours at 1600/sup 0/F in a simulated PFB environment. Metallographic evaluation showed Co-base cladding alloys PFB-5PM and PFB-6PM (aluminided) and Fe-base alloy GE-2541 to be the most corrosion resistant. The formability and fabricability of sheet material was significantly improved for these alloys by utilizing powder metallurgy techniques. Sub-task 3.2, Clad Process Development, encompassed processing activities to evaluate sheet alloy ...

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Passive films formed on stainless steels in a borate buffer solution (pH 9.2) have been investigated by capacitance measurements and photoelectrochemistry. The study was carried out on films formed on AISI type 304 and 316 stainless steels and high purity alloys with differing chromium, nickel, and molybdenum contents. Complementary research by Auger analysis shows that the passive films are composed essentially of an inner chromium region in contact with the metallic substrate and an outer iron oxide region developed at the film/electrolyte interface. The semiconducting properties of the passive films are determined by those of the constituent chromium and iron oxides which are of p-type and n-type, respectively. Thus the influence of the alloying elements on the semiconducting properties of the passive films is explained by changes in the electronic structure of each of these two oxide regions.

International Nuclear Information System (INIS)

Minor addition of B to the Ti-6Al-4V alloy reduces the prior #beta# grain size by more than an order of magnitude. TiB formed in-situ in the process has been noted to decorate the grain boundaries. This microstructural modification influences the mechanical behavior of the Ti-6Al-4V alloy significantly. In this paper, an overview of our current research on tensile properties, fracture toughness as well as notched and un-notched fatigue properties of Ti-6Al-4V-xB with x varying between 0.0 to 0.55 wt.% is presented. A quantitative relationship between the microstructural length scales and the various mechanical properties have been developed. Moreover, the effect of the presence of hard and brittle TiB has also been studied.

International Nuclear Information System (INIS)

Alloy 800 was developed in 1949 by The International Nickel Company, Inc. The basic composition, nominally 32wt.%Ni, 20.5wt.%Cr and 46wt.%Fe, was designed to provide a stable, fully austenitic structure and to impart high strength combined with resistance to oxidation, carburization and corrosion in a wide variety of aggressive industrial environments at elevated temperatures. In the short span of twenty-five years, alloy 800 has earned a unique position in the family of heat- and corrosion-resistant materials. Established uses include a wide range of applications in the industrial heating field, in the petro-chemical industry, in domestic appliances and in food processing equipment. The good performance of alloy 800 in these applications has led to its use as boiler tube material both in fossil-fired plants and in HTGR and PWR nuclear power systems. Recently, it was specified for a PHW CANDU reactor ...

International Nuclear Information System (INIS)

The post (neutron) -irradiation high-temperature tensile and creep-rupture properties, deformation and fracture characteristics of austenitic alloys, particularly solution annealed Type 316 steel, are surveyed and correlated with the damage structures developed as a function of irradiation temperature (and dose). The mechanisms proposed to explain the irradiation-induced changes in properties and behaviour are summarised. The factors responsible for the observed differences in the post-irradiation and 'in-reactor' creep-rupture properties and behaviour of an austenitic steel are discussed in terms of the helium gas and stress driven growth of small intergranular bubbles and the atom plating associated with their growth and coalescence. (author).

International Nuclear Information System (INIS)

Repassivation resulting from the bared metal surface is a critical process for judging whether or not material suffers from corroding or immunizing. Nickel based alloys with high chromium content were developed to increase the corrosion resistant to sulphur compounds. Active humps resulting from active dissolution of nickel were obtained by creating the bared metal surfaces in thiosulphate solutions. The lower the Cr content the higher is the dissolution rate. The passive films formed on the bared metal surface were examined by ac impedance. Results suggest the formation of multi-layers oxide which were affected by active dissolution reactions during repassivation. (author).

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Some hypo-stoichiometric Zr-based Laves phase alloys were prepared and studied from a viewpoint of discharge capacity for electrochemical application. After careful alloy design of ZrMn{sub 2}-based hydrogen storage alloys through changing their stoichiometry while substituting or adding some alloying elements, the Zr(Mn{sub 0.2}V{sub 0.2}Ni{sub 0.6}){sub 1.8} alloy reveals relatively good properties with regard to hydrogen storage capacity, hydrogen equilibrium pressure and electrochemical discharge capacity. In order to improve the discharge capacity and rate-capability, Zr is partially replaced by Ti. The discharge capacity of Zr{sub 1-x}Ti{sub x}(Mn{sub 0.2}V{sub 0.2}Ni{sub 0.6}){sub 1.8} (x=0.0, 0.2, 0.3, 0.4, 0.6) alloy electrodes at 30 C reaches a maximum value and decreases as the Ti fraction increases. In view of electrochemical and thermodynamic ...

Energy Technology Data Exchange (ETDEWEB)

Dynamic development of new grain boundaries was studied in compression of a magnesium alloy AZ31 with initial grain sizes (D{sub 0}) of 22 {mu}m and 90 {mu}m at a temperature of 673 K. Kink bands are evolved near corrugated grain boundaries and in grain interiors at low strains accompanied with new fine grains. Kink bands are developed often perpendicular to the basal plane. The boundary misorientation of kink band as well as the volume fraction of new grains increases rapidly with increasing strain and approaches a saturation value in high strain. New fine grains are developed faster with decrease in the D{sub 0}. It is concluded that new grain evolution is controlled by a deformation-induced continuous reaction, i.e. continuous dynamic recrystallization (DRX). (orig.)

Energy Technology Data Exchange (ETDEWEB)

Two austenitic steels, 316 Stainless Steel and Alloy 800, have been examined under conditions of both isothermal low cycle fatigue (LCF) and thermomechanical fatigue (TMF). The TMF tests were conducted between 649 and 360/sup 0/C with a carefully controlled triangular waveform. The LCF tests were performed at 649/sup 0/C and both kinds of tests were subjected to a strain range of 0.5%. TMF shortened life to 40% for 316 Stainless Steel and to 5% for Alloy 800. The microstructural evolution occurring in both alloys has been examined and we conclude these do not play a role in the life shortening caused by TMF. The TMF does produce asymmetric hysteresis loops with large tensile peak stresses in tests where the maximum temperature corresponded with the peak compressive stress. The influence of TMF on fatigue crack growth rates has been measured and it was found that TMF accelerated crack growth in Alloy 800 ...

Energy Technology Data Exchange (ETDEWEB)

Magnesium alloys have replaced resins as a material for the components of electronic products such as cell phone and notebook personal computer mainly, because of their lightness and rigidity. Thin walls, a complicated shape, and high appearance quality are all needed in the external parts. Die-casting and injection molding are the main method of manufacturing magnesium alloy parts. The optimal cast conditions and mold design have been investigated in order that a few defects such as surface cracks and mold cavities in casting parts would be reduced. Instead of cast, plastic forming technologies such as warm drawing and hot forging have been developed to form thinner walls and less defects. Plastic formability of magnesium alloy in hot working is dependent on a grain size of material. The material with fine grains has advantage of being formed at high strain rate. The characteristics of forming ...

Energy Technology Data Exchange (ETDEWEB)

Increase usage of magnesium components in the portable electronics industries has propelled considerable research interest on the development of magnesium forging. There have been some studies done in the area of sheet metal forming and forging of axis-symmetrical parts of magnesium alloys but there are very little work done on the plane strain backward extrusion of magnesium alloy. This paper deals with the analysis of plane strain extrusion of magnesium alloy, AZ31, using numerical modeling at different extrusion conditions of temperatures and friction coefficients. A commercially available finite element package, ANSYS/LSDYNA, was used in the finite element analysis. FE simulated results, material deformation, punch force and stress/strain distributions, were compared with actual experimental data. From the numerical analysis, a decrease in forging temperature from 300 C to 250 C will lead to a ...

Energy Technology Data Exchange (ETDEWEB)

When a metallic alloy is quenched into a miscibility gap, a mixture of two phases develops, whose domain structure then coarsens because of the interfacial energy between the two phases. This spatial arrangement of the domains and the rate at which they evolve may be strongly influenced by elastic interactions. In a recent paper, the authors described a method for simulating the effect of anisotropic elastic interactions in a two-dimensional Ising model of a cubic alloy, using Kawasaki dynamics with the elastic interactions represented by a long-range two-body interaction potential. Here they present the results of such simulations at various temperatures, alloy compositions and misfits (by misfit they mean the difference in size between the two kinds of atom), exhibiting snapshots both of the microscopic configurations (corresponding to experimental measurements using transmission electron microscopy) ...

Science.gov (United States)

The authors develop a procedure for the determination of the Al, Ti, V, Cu, Mn, Mo, and W content of nickel-base alloys by neutron activation analysis. An M-10 microtron with a beryllium target in a paraffin microtron (with a beryllium target) in a paraffin moderator served as the neutron source. In order to evaluate the procedure for quantitative analysis, the authors determined the contents of the above elements in five reference standards, the bulk density of which was 2.94-4.17 g/cm/sup 3/. The difference in the self-absorption of the gammaquanta was assessed by determining the number of gamma-quanta with energies in the range 60-1332 keV that had passed through the RS N4 and N8 which showed the greatest difference in their composition. The results of the determination are presented. The proposed procedure is simple and rapid and can be used to determine the alloying components of nickel-based ...

Energy Technology Data Exchange (ETDEWEB)

The effect of alloying Sn, Pb, As, Sb and P on the dezincification of commercial brass 60Cu-39Zn-1Pb has been investigated in 1% CuCl{sub 2} solution by immersion studies and electrochemical measurements. Specimens with a smooth surface finish exhibited more resistance to dezincification. Appreciable inhibitive effect on dezincification was observed for the 55Cu-40Zn-3Pb-2Sn brass composition. The galvanic coupling of lead phase with the matrix accelerated corrosion. To improve the dezincification resistance of the Sn containing brass, As, Sb and P were added at two different levels (0.05% and 0.1%). Brass of composition 48.95Cu-45Zn-5Pb-1Sn-0.05As was more resistant indicating the synergistic effect of Sn and As. The effect of 0.05 and 0.1% of arsenic addition with various concentrations of zinc was also studied. The alloy of composition 57.90Cu-40Zn-2Pb-0.1As showed better corrosion resistance than the alloy containing 1% ...

Energy Technology Data Exchange (ETDEWEB)

In this work, an attempt was made to develop a novel type of wear-resistant composite employing a TiNi alloy matrix reinforced by hard particles. Titanium carbide was chosen as the reinforcing phase because of its high hardness and TiNi alloy as the matrix due to its pseudoelasticity and good toughness. TiC particles may sustain external load, while the TiNi matrix may accommodate deformation, absorb impact energy and retain the hard particles. Such a combination is expected to lead to an enhanced wear resistance, compared to TiNi alloy. As a matter of fact, some efforts were previously made to develop TiNi-matrix composite reinforced by ceramic particles. However, the emphasis of those studies was put on effects of the reinforcing particles on the phase transformation behavior, shape memory effect and some mechanical properties of the composite; no attempt was made to explore the ...

International Science & Technology Center (ISTC)

The New Titanium Alloys With Increased Mechanical Properties and Corrosion Resistance for Medical Instruments and their Coatings

CERN Document Server

Metals and alloy - Atmospheric corrosion testing

Energy Technology Data Exchange (ETDEWEB)

A-15 compounds are extremely brittle and difficult to process for practical applications. A novel processing technique was developed to greatly improve the mechanical and superconducting properties of A-15 alloys. The new processing technique can be described as follows: (1) to select compounds that can form the A-15 phase (the selected A-15 compounds in this research were Ti3Nb6Mo3Si4 and Nb99.5-(x + y)AlxSiyB0.5 alloys); (2) to rapidly solidify them into the amorphous state; (3) to anneal the quenched amorphous products into ultra fine-grained single A-15 phase. The extreme grain refinement greatly improved the flexibility and the critical current density of the alloys. The melt spinning technique was used to rapidly solidify Ti3Nb6Mo3Si4 and Nb99.5-(x + y)AlxSiyB0.5 alloys. Ti3Nb6Mo3Si4 alloys were relatively easily formed into the amorphous state. Nb3Al ...

International Nuclear Information System (INIS)

The development of the microstructure on aging of an (#alpha# + #beta#) type titanium alloy containing 6Al-1.6Zr-3.3Mo-0.3Si (VT9) (in weight percent) has been studied. The #beta#-transus temperature of this alloy is approximately 1243 K. Solution treatment in the #beta#-phase field of the alloy followed by quenching in water at room temperature resulted in the formation of a single-phase martensite structure. The martensitic structure was confirmed to be orthorhombic (#alpha# double-prime) using X-ray diffraction. The water-quenched (WQ) specimens were subjected to aging treatments at temperatures of 823, 873, and 973 K for various lengths of time. Aging at 823 K for times between 24 and 100 hours did not bring about any noticeable change in the microstructure. Aging at 823 K for 200 and 300 hours resulted in the heterogeneous precipitation of s_2 silicide particles and thin films of #beta# sandwiched ...

International Nuclear Information System (INIS)

The effect of phosphorus on the corrosion resistance of Al-bronzes is studied in detail in this work. A literature review showed that there are a lot of things known about the microstructure and the mechanical properties of Al-bronzes. In spite of their corrosion resistance the corrosion properties and the structure of the protective oxide films of Al-bronzes were seldom a matter of interest. Systematic studies of the influence of different alloying elements on the oxide film and the corrosion properties are rare. Therefore, it is not possible to predict the corrosion resistance of Al-bronzes, made by alloying particular elements. The high corrosion resistance of the new alloy CuAl_2_0P_1 was the reason to investigate the influence of phosphorus on the corrosion properties of Al-bronzes in more detail. A systematic study of the microstructure and the corrosion properties of Cu, CuP_x, CuAl_2_0 and CuAl_2_0P_x offers an ...

International Nuclear Information System (INIS)

Ti-10V-2Fe-3Al is high strength, metastable beta titanium alloy developed by the Timet Division, Titanium Metals Corporation of America for enhanced forgeability and excellent mechanical property combinations, including deep hardening characteristics. Ti-10-2-3 has been the subject of intense thermomechanical processing (TMP) development and reduction to commercial practice for the full range of open die, closed-die and precision forged products utilized in aerospace and other applications. With commercially proven TMP, Ti-10-2-3 forgings provide a range of strength-fracture toughness combinations from 180 Ksi (1,240 MPa) minimum U.T.S. to 140 Ksi (965 MPa) minimum U.T.S with commensurate fracture toughness. With optimal TMP and these strength-toughness combinations, Ti-10-2-3 forgings are found provide superior smooth and notched fatigue properties critical to aerospace applications over incumbent alpha-beta ...

Energy Technology Data Exchange (ETDEWEB)

Four subprojects were completed: development and evaluation of die coatings, accelerated die life characterization of die materials, evaluation of fluid flow and solidification modeling programs, selection and characterization of Al-based die casting alloys, and influence of die materials and coatings on die casting quality.

Energy Technology Data Exchange (ETDEWEB)

Primary dendrite spacings and side-branch coarsening kinetics were examined in specimens of the single-crystal multicomponent commercial superalloy PWA-1480, which were directionally solidified in a psoitive thermal gradient. The experimentally observed dependence of primary dendrite spacings and side-branch coarsening kinetics on growth rate and thermal gradient were in agreement with the behavior predicted by analytical models developed for binary alloys. (orig.).

Energy Technology Data Exchange (ETDEWEB)

In case of airplane engine, technical development like increase of temperature at the turbine entrance or high speed rotation with a purpose of thrust up, and reduction of structural part single substance mass or reduction of number of parts in order to achieve lightness and so forth, has been promoted in order to improve the performance that is evaluated by thrust weight ratio (thrust/weight). Accordingly, research and development of high heat resistance, high strength, lightness and so forth of each material of the parts are in demand. As a representative material corresponding to such demand, L10 type {nu}-TiAl intermetallic compound which is light and has improved high temperature strength properties is paid attention and its development is promotes. The authors were successful for the first time in the world to manufacture composite material with CVD type SiC fiber that was difficult so far by using TiAl-Cr ...

Energy Technology Data Exchange (ETDEWEB)

The texture influence on tensile tests of AZ31, one of the common Mg alloys, has been studied. Starting material was a rectangular extruded bar, which has a strong texture. Due to the preparation of three tensile samples with 0 , 45 , 90 to the extrusion direction, the initial bar texture influences differently on the mechanical behaviour under tensile load. This results in a variation of the yield strength (90 MPa and 175 MPa) the ultimate tensile strength (250 MPa - 278 MPa) and the final texture. Experimental texture analysis was completed by texture simulations using the VPSC-model (visco plastic self-consistent). The good agreement between experimental and simulated pole figures allows the determination of the activated deformation modes related to the initial texture. (orig.)

Energy Technology Data Exchange (ETDEWEB)

The purpose of this study is to evaluate the synergistic effect of helium and hydrogen on Fe-Cr ferritic model alloys, to provide basic understanding concerning development of fusion reactor components. Single, dual and triple ion-beams consisting of Fe{sup 3+}, He{sup +} and H{sup +} were used for irradiation, at temperatures 470-600 deg. C and dose to 50 dpa at 1 {mu}m. The dual beam irradiation with He enhanced cavity nucleation extensively to swelling of about 0.4%, whereas the dual beam irradiation with H did not significantly affect the microstructure. In the case of triple ion irradiation, the synergistic effect of He and H was confirmed clearly; relative large void formation and enhanced swelling to almost 5%. The synergistic effect suggests that the role of H is important for void growth and dislocation bias.

International Nuclear Information System (INIS)

In order to improve the reliability of PWR steam generators, we have performed research to improve the tubing material and tube-support-plate configuration, based on our wide operating experience, and have developed and verified Alloy TT690 as the optimum tubing material and the BEC (Broached Egg Crate) type tube-support design. In the research, we have studied the metallurgical mechanism of the alloy to improve its corrosion resistance, evaluated corrosion susceptible region quantitatively, estimated the actual environment in a steam generator and confirmed the reliability by a model boiler test over a long period. It has been verified that the steam generator with the latest design has higher reliability with respect to the corrosion resistance of tubes. (author).

International Nuclear Information System (INIS)

AM-SC1 is a heat treatable magnesium alloy that has been specifically developed to achieve the elevated temperature strength and creep properties necessary for engine block applications. This paper describes the interrelationship between the microstructure and the mechanical properties of AM-SC1. The compressive and tensile strengths are relatively insensitive to temperature up to and including 450 K and the tensile yield behaviour deviates from a standard Hall-Petch relationship at grain sizes below 200 ?m. The microstructural features contributing to the creep resistance are both inter- and intra-granular in nature and are on length scales from nanometers to micrometers. The creep behaviour at 423 K and 450 K is diffusion controlled, with any contribution from the grain boundaries being negligible.

International Nuclear Information System (INIS)

Up to 90% of the life time of cyclically loaded components is determined by short crack initiation and propagation. This stage of the fatigue damage process is strongly influenced by microstructural features, e.g. grain boundaries and crystallographic grain orientation. Therefore LEFM can not be applied in a reasonable manner explaining the demand for a mechanism-related modelling method. The present study deals with mechanical testing and microstructural examinations applied to the relatively new #beta#-titanium alloy LCB. The results are used as data base to develop a new short crack model that is based on the model of Navarro and de los Rios. By using various techniques such as electron back-scattered diffraction and finite-element calculations the origin of crack initiation is revealed and the characteristics of crack propagation is determined. (orig.)

Energy Technology Data Exchange (ETDEWEB)

Stress corrosion cracking tests in constant extension rate tensile (CERT) and constant load tensile (CLT) tests were conducted on Ni-xCr- 9Fe-yC in Ar, water, and a LiOH-boric acid solution. Cr and C improve the resistance of Ni-base alloys to IG cracking in both Ar and water at 360C. Since creep plays a role in IG cracking, one possible explanation for the role of the environment involves its effect on the creep. Experiments were conducted on the role of C in the deformation behavior and failure mode of Ni-16Cr-9Fe. Constant load experiments were conducted on Ni-16Cr-9Fe to determine if the CLT test is more aggressive than CERT. The electron backscattering technique in a SEM is being developed in order to extend the IG cracking studies to grain sizes typical of commercial alloys, 20-30 microns.

Energy Technology Data Exchange (ETDEWEB)

Pitting behavior of alloy 800 was investigated as a function of temperature and prefilming in high-temperature water. The behavior was characterized in terms of pitting potential (U{sub p}) and pit density (n{sub p}). U{sub p} decreased with increasing temperature and chloride activity. Prefilming of test coupons over a period between 100 h and 5,000 h in ammoniated water at 300 C had no apparent influence on U{sub p} at room temperature, 180 C, and 300 C. However, the number of pits in prefilmed coupons was much higher than in coupons covered with an air passive layer. The effect of prefilming on pit nucleation was investigated in detail with regard to a model and test methods developed by Bianchi, et al. Density of pits in prefilmed coupons was at least 1 order of magnitude higher than in air passive coupons. Maximum pit density was measured after a prefilming period of 100 h. The effect was discussed in terms of Bianchi`s model and in terms ...

Energy Technology Data Exchange (ETDEWEB)

The tensile and compressive properties as well as LCF and HCF performance of the extruded magnesium alloys AZ31 and AZ80 were determined in extrusion (L) and long-transverse (T) directions. Owing to marked crystallographic textures, both alloys showed pronounced directional mechanical properties in monotonic as well as cyclic loading with strength values in L-direction being significantly superior to those in T-direction. Thermomechanical treatments such as pressing, swaging and rolling were found to increase yield stresses and HCF strengths and to alter the directionality in properties due to textural modifications. To further improve HCF strengths, mechanical surface treatments such as shot peening, roller-burnishing and deep rolling were utilized. The results indicate marked improvements provided that suitable process parameters are used. The improvement of the HCF strengths is explained by the process-induced changes in near-surface ...

International Nuclear Information System (INIS)

Past elastic-plastic fracture studies for leak-before-break (LBB) assessment of low alloy steel pipings have been focused mostly on the behavior of base metals and their weld metals. In contrast, the heat-affected zone (HAZ) of a welded pipe has not been studied in detail primarily because the size of the HAZ is too small to make specimens for mechanical properties measurements. In this study, microstructural analyses, microhardness tests, tensile tests and J-R tests have been conducted as a function of distance from a fusion line and temperature for HAZ materials of SA106Gr.C low alloy piping steels. For the ferrite-pearlite steels such as SA106Gr.C, the HAZ specimens showed a higher yield strength and fracture toughness compared with those of its base metal. These characteristics, despite of grain coarsening, can be explained by cleaner microstructures of HAZ materials with a finer morphology of carbides compared with pearlitic-ferritic base ...

Energy Technology Data Exchange (ETDEWEB)

An accelerated crucible rotation (ACR) technique was applied to the Bridgman (B) directional solidification of Al-Cu hypoeutectic and eutectic alloys. For Al-4.5% Cu hypoeutectic alloys. The development of dendrites was prevented and the cellular spacing was reduced by forced convection in the ACR-B process. For the Al-CuAl{sub 2} eutectic alloy, maximum rotation rates of 100, 200, 300 and 400 rpm were adopted, and the growth rate R was varied between 5 and 60 {mu}m/s. The results show that the periodic structure related to the crucible rotation periods occurs when the Reynold's number Re > 500, and that the average eutectic spacing decreases with the increase of Re. It is found that the convection increases the temperature gradient in front of the liquid/solid interface and reduces the depth of the concave interface, depending on Re and R. The convection also changes the solute ...

Science.gov (United States)

... MOLYBDENUM ALLOY GUN BARREL LINERS o0 in ... NEW POWDER TECHNOLOGIES FOR MOLYBDENUM ALLOY GUN BARREL LINERS ...

International Nuclear Information System (INIS)

... filters molybdenum alloys production sulfuric acid alloys chemical reactions ...

Energy Technology Data Exchange (ETDEWEB)

An experimental technique has been developed to examine the interaction between deformation and the exposure of certain high temperature structural alloys to oxidizing molten salt environments. The experimental program involved performing a series of long-term tensile tests over a wide range of strain rates. Fracture strain reduction in area and ultimate strength (UTS) were monitored as parameters indicative of an alloy's susceptibility to environmental degradation. For Incoloy Alloy 800 tested at 600/sup 0/C in the salt medium and at initial strain rates between 2 x 10/sup -7/ sec/sup -1/ and 1 x 10/sup -5/ sec/sup -/1 no appreciable loss of ductility, as measured by reduction in area, was observed relative to control specimens tested in air at the same temperature and strain rates. Similarly, fracture strain and UTS were essentially unaffected by exposure to the oxidizing environment. The ...

Energy Technology Data Exchange (ETDEWEB)

To achieve sufficient thermodynamic efficiency, space nuclear power systems must operate above 1000/sup 0/C. A quantitative evaluation of the existing mechanical properties data for the refractory alloys relevant to space nuclear power systems design lifetimes up to seven years at temperatures up to 1400/sup 0/C is being conducted. The most important properties for space nuclear power systems are long-term high-temperature (>1000/sup 0/C) creep strength and ductility, low-temperature (<400/sup 0/C) fracture toughness (including ductile-to-brittle transition temperature, (DBTT)), and ductility at high strain rates; of special concern are the above properties for weldments of refractory alloys, composition, applied stress, test temperature, test environment (e.g., vacuum, lithium), and thermomechanical treatment (TMT) history. Currently being evaluated are, in order of ascending mp, selected alloys of niobium (e.g., ...

Energy Technology Data Exchange (ETDEWEB)

This paper reviews different helium-cooled first wall and blanket designs; and compares the selection of structural materials. The authors found that the solid breeder, SiC-composite material option generates the lowest amount of induced radioactivity and afterheat and has the highest temperature capability. When combined with the direct cycle gas turbine system, it has the potential to be the most economical fusion system and can compete with advanced fission reactors. When compared to martensitic steel and V-alloy, SiC-composite is the least developed of these three structural materials, a focused development effort will be needed. Fundamental research has begun in addressing the issues of optimized composite materials, irradiation effects, leak tightness and low activation braze materials. Development of helium-cooled high heat flux components and further development of the ...

Science.gov (United States)

The paper deals with the modeling and the development of a numerical procedure for the analysis of shape-memory alloy (SMA) elements in order to predict the main features of SMA devices. A 3D SMA model in the framework of small strain theory is developed starting from the thermo-mechanical model proposed by Souza et al. (Eur J Mech A/Solids 17:789-806, 1998) and modified by Auricchio and Petrini (Int J Numer Methods Eng 55:1255-1284, 2002). The aim of this paper is to propose some more modifications to the original model, to derive its consistent 1D formulation, to clarify the mechanical meaning of the material parameters governing the constitutive model. A robust time integration algorithm is developed in the framework of the finite element method and a new beam finite element is proposed. Some numerical applications and a comparison with experimental data available in literature are carried out in ...

International Nuclear Information System (INIS)

The microstructural development and grain-coarsening behavior of WC-Co alloys, with and without a VC additive, were investigated. The primary goal was to determine the mechanism through which VC acts as a grain-growth inhibitor. The study involved long-time sintering experiments (1 to 100 hours) on fully dense material, nascent stage sintering (90 to 1,320 seconds) starting with the green compact, and surrogate liquid phase experiments to characterize the WC powder prior to sintering. Quantitative microstructural analysis using intercept length distributions was performed for the long-term sintering. The nascent stage experiments involved the measurement of the specific surface area (S_v) of each type of interface separately allowing the determination of the contribution of each developing entity to the overall microstructural evolution. The VC addition has been found to enhance the breakup of multigrained particles in the ...

Energy Technology Data Exchange (ETDEWEB)

A two-year demonstration run of a 500 C/100kgf/cm{sup 2}{center_dot}g high-efficiency waste-to-energy pilot plant has been started from February 1998; this plant represents as the final stage of the NEDO project of development of a high-efficiency waste-to-energy plant. Alloy 625 (SB444) and 310 HCbN tubings were selected for the 3rd and 2nd superheater of the pilot plant, respectively, and ten kinds of conventional and new solid-wall tubings, weld overlayed tubings, composite tubings, and cermet spray coated tubings were tested. By means of 6000-hour field corrosion test in three typical domestic plants, material life and corrosion environment for superheater tubings installed in the pilot plant were evaluated. Also, the effect of alloying elements Cr, Ni, Mo, corrosion rate law, etc. were investigated in detail. Furthermore, the design conception and basic performance of the pilot plant regarding pollution control and ...

Energy Technology Data Exchange (ETDEWEB)

NO abstract prepared.

CERN Document Server

Metals and alloys : atmospheric corrosion testing : General requirements for field tests

Science.gov (United States)

... Title : Effect of Yttrium on the Microstructure of Titanium Alloys,. ... The yttrium was added in the melting stage as an oxide or in the elemental form. ...

International Nuclear Information System (INIS)

The importance that must be attached to the phenomenon of stress corrosion cracking of austenitic alloys is emphasized. The relation between chemical composition of various alloys and their sensitivity to cracking is shown with particular reference to the behaviour of Alloy 800. The different effects of alkaline anc chloride environments are discussed. Studies are reported of the general corrosion of Alloy 800 and other alloys in an environment representative of the primary coolant of PWR reactors; and of the behaviour of various alloys (including Alloy 800) in the conditions envisaged for their use for steam generators with superheat up to about 550 deg.C. (U.K.).

Energy Technology Data Exchange (ETDEWEB)

Low-cost titanium alloy components are getting increasing attention in aerospace applications. Cost reductions are possible in the alloys themselves and in the production techniques. The former aspect is less promising as titanium alloys are costly to produce. Of course, there are some new developments like the (alpha plus beta) alloy Ti-6 Al-2 Fe-0.2 Si (TIMETAL 62S) and the beta-alloy Ti-6.8 Mo-4.5 Fe-1.5 Al (TIMETAL LCB), in which low-cost iron replaces costly beta alloying elements like vanadium or molybdenum, but these will be used mainly on the mass production markets, e.g. motor car construction. In consequence, optimisation of production methods is the more promising option. Near net shape processes will reduce the production cost and improve the fly-to-buy ratio. Some of these production processes are explained. [Deutsch] Die ...

British Library Electronic Table of Contents (United Kingdom)

All the recent DEMO design studies for helium cooled divertors utilize tungsten materials and alloys, mainly due to their high temperature strength, good thermal conductivity, low erosion, and comparably low activation under neutron irradiation. The long-term objective of the EFDA fusion materials programme is to develop structural as well as armor materials in combination with the necessary production and fabrication technologies for future divertor concepts. The programmatic roadmap is structured into four engineering research lines which comprise fabrication process development, structural material development, armor material optimization, and irradiation performance testing, which are complemented by a fundamental research programme on "Materials Science and Modeling". This paper prese...

International Nuclear Information System (INIS)

To suit the needs of development for manufacture VLSI, we started to investigate liquid metal ion sources (LMIS) and focused ion beam (FIB) in 1984. Many kinds of emitters viz. neddle type, co-axial type and capillary type of Ga and Au LMIS and three kinds of eutectic alloys LMIS (Au-Si, Au-Si-Be, Pd-Ni-Si-Be-B) have been tested. A program which can calculate focused ion guns has been written. Four kinds of foused ion guns have been operated, a fine beam with diametic 0.1 #mu#m is obtained. Using the FIB a scanning ion microscope has been constructed. Some tests of etching and self-developing of nitrocellulose are described. (author).

International Nuclear Information System (INIS)

A model has been developed in the recent past to predict fatigue crack growth (FCG) behaviour in the Paris-regime of various steels by employing low cycle fatigue (LCF) properties. The model forms its basis on the assumption that the cyclic damage process immediately ahead of a crack-tip, restricted in a small zone termed as process zone, is identical to those experienced in the LCF loading of a smooth specimen. Within the process zone, fatigue damage has been assumed in terms of product of stress and plastic strain which is analogous to the plastic strain energy density of the smooth specimen under fatigue loading. In this paper the model developed by Kujawski and Ellyin has been used to predict the FCG behaviour of an #alpha#-#beta# titanium alloy in the Paris-regime by employing the experimentally obtained LCF properties. The FCG behaviour thus theoretically predicted was compared with the experimentally determined FCG ...

Energy Technology Data Exchange (ETDEWEB)

The need for a hydrogen economy is driven by increasing fuel prices, depleting oil reserves and uncertainty over supplies, and concerns about global warming and environmental pollution. Alternative methods to portable energy sources such as fossil fuels are being developed that are more efficient and carbon-emission-neutral. A prospective method is to produce hydrogen as an energy carrier. This paper presented a study on the degradation of materials under conditions of the sulphur-iodine (SI) thermochemical cycle. The paper provided background information on the study and presented a schematic of the SI cycle. A literature review was presented along with materials selected, such as refractory metals, reactive metals, superalloys, glassy metals, ceramics, cermets, polymers, composites, and coatings. The experimental method was then described. A capsule method was developed to rapidly quantify the decomposition rate of the candidate materials ...

International Nuclear Information System (INIS)

Due to the well-establish corrosion problems of Alloy 600 as a steam-generator material and the subsequent focus on thermally treated (TT) Alloy 690 and Alloy 800 as alternative materials, a systematic analysis of the corrosion behavior of these two latter alloys is warranted. Corrosion test results for Alloys 690 TT and 800 were collected and organized in the form of corrosion mode diagrams. Selected data for mill annealed (MA) Alloy 600 were also included for reference. The corrosion mode diagrams correlate the modes of corrosion degradation observed in tests as functions of the environment pH and electrochemical potential (ECP). The diagrams confirm that Alloys 690TT shows some susceptibility in caustic environments, and Alloy 800 shows susceptibility in both caustic and highly acidic environments. (authors). 6 figs., ...

International Nuclear Information System (INIS)

Mixed microstructures have been studied in low- carbon microalloyed steels suitable for automotive applications, after continuous cooling from the hot-rolled condition. Microstructural features such as polygonal ferrite, bainitic and acicular ferrite and microphase constituent are identified using transmission electron microscopy. The influence of these mixed structures on the tensile strength, impact toughness and fracture behaviour is examined. It is found that improvements in impact toughness as compared with microalloyed medium- carbon ferrite/pearlite steels can be achieved from these predominantly acicular structures developed by controlling alloy composition and continuous cooling of these lower carbon steels. (orig.).

Energy Technology Data Exchange (ETDEWEB)

As part of our effort to develop a semicontinuous PuO/sub 2/ reduction process, we are investigating promising materials for containing a 900/sup 0/C molten CaCl/sub 2/ . CaO chlorination reaction. We want the material to contain this reaction and to be reusable. We tested candidate materials in a simulated salt (no plutonium) using anhydrous HCl as the chlorinating agent. Data are presented on the performance of 36 metals and alloys, 9 ceramics, and 3 coatings.

Science.gov (United States)

The cupola furnace is used to melt scrap steel, pig iron, foundry returns, and alloying additives to a prescribed tapping chemistry and temperature for iron casting applications. The melting process within the cupola is highly complex and not well quantified. The American Foundrymen's Society is developing a mathematical model to aid in the understanding of these processes. This model is reaching maturity, and has been successful in estimating a number of melting parameters. This paper details the results of efforts to verify the model in a controlled system, equipped wit the appropriate sensors, for model verification. The work was performed on a research-scale cupola furnace located at the Department of Energy's Albany Research Center.

Energy Technology Data Exchange (ETDEWEB)

Low operating power and short cycle life are 2 of the main draw-backs of zinc-air batteries, despite the fact that various attempts have been made to develop improved zinc (Zn) anodes. This study investigated the performance of a Zn anode with a substantial addition of aluminium (Al). Rolled sheets of Zn-Al alloys of varying amounts of Zn and Al were used to prepare the anodes. Results of the study showed that the cells had higher open circuit voltages (OCV) values as well as a higher specific anode capacity. It was observed that specific anode capacity increased with higher current loading. The Zn{sub 59}Al{sub 41} and Zn{sub 67}Al{sub 33} sheets showed the highest performance with high OCV values of between 1540 and 1560 mV, as well as the largest specific anode capacity of 750-800 mAh per g at a discharge current of 200 mA. The 2-phase structure of the Zn-Al sheets was considered to be useful in reducing anode-passivation, and increasing ...

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A necessary condition for crevice corrosion is that a crevice former create a sufficiently tight, restricted geometry on the metal surface to support the development of critical crevice chemistry. Crevice corrosion is affected by the crevice geometry (tightness) and the properties of the crevice former. The objective of this study is to determine the effect of the crevice former material on the evolution of localized corrosion-damage. A standard crevice corrosion test method is modified by (a) the use of ceramic, metal or polymer materials as the crevice former and (b) the variation of size and shape of the crevice. This study focuses on the post initiation stage of crevice corrosion and addresses factors that may limit the initiation of localized corrosion and also slow or stop the continued propagation of corrosion. Controlled crevice corrosion tests are performed under aggressive, accelerated conditions on Ni-Cr-Mo alloy C-22 and other ...

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This paper summarizes the results of a long-term research project by SKBV which aimed to find ways of increasing spiral chute capacity while minimizing particle degradation, and also to extend the life of chute linings. Spiral chutes have been redesigned in such a way that chute speeds are considerably slower. The most wear-resistant and economic material for the inlet area was found to be slabs of tempered alloy cast steel, and for normal chute sections, cast basalt plates. Vertical rom bunkers can now be lined with thin cladding sections of GRC. Staple pit spiral chutes have been considerably improved in respect to wear and abrasion by the use of toughened steel as the chute lining material. Several of the innovations developed during the course of the research project are in use in West German mines and some have also been introduced abroad. (In German)

International Nuclear Information System (INIS)

Consideration is given to the process of the formation of a titanium sponge alloyed with niobium or tantalum, in the joint metallic reduction of titanium, niobium and tantanum chlorides. A percentage composition of the phases observed and the structure of the alloyed sponge have been studied. It is shown that after one remelting operation of the alloyed sponge the alloys of titanium with niobium and tantalum have a uniform component distribution. At the stage of chloride reduction there appear solid solutions based on titanium and an alloying component. The stage of vacuum separation of the reaction mass is associated with a mutual dissolution of the primary phases and the formation of the solid solutions of the alloyed titanium sponge, which, by their composition, are close to the desired alloy composition. The principal features of the ...

International Nuclear Information System (INIS)

The following methods of quartz ceramics alloying were considered: alloying of initial quartz glass; introduction of alloying additive into water slip of quartz glass; porous materials impregnation with salt aqueous solutions and subsequent salt thermal decomposition with formation of stable oxides in pores of ceramics. Oxygen free compounds BN, SiB_4, SiC, Si_3N_4, REM oxides and transition metal oxides were used as alloying additives. Main properties of the materials and compositions obtained are presented.

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The processing characteristics, tensile properties, and oxidation response of two Nb-Ti-Al-Cr alloys were investigated. One creep tests at 650{degrees}C and 172 MPa was conducted on the base alloy which contained 40Nb-40-Ti-10Al-10Cr. A second alloy was modified with 0.11 at. % carbon and 0.07 at. % yttrium. Alloys were arc melted in a chamber backfilled with argon, drop cast into a water-cooled copper mold, and cold rolled to obtain a 0.8-mm sheet. The sheet was annealed at 1100{degrees}C for 0.5 h. Longitudinal tensile specimens and oxidation specimens were obtained for both the base alloy and the modified alloy. Tensile properties were obtained for the base alloy at room temperature, 400, 600, 700, 800, 900, and 1000{degrees}C, and for the modified alloy at room temperature, 400, 600, 700, and 800{degrees}C. Oxidation ...

International Nuclear Information System (INIS)

Investigated are the characteristics of high-temperature plastic deformation the velocity sensitivity of flow stresses, deformation curves, flow stresses, deformation before rupture - as well as the structure of beryllium alloys containing nickel (0.5-4 %), yttrium (0.5-2 %) and aluminium (38 %). The alloys containing nickel (2%) and yttrium (0.5 %) are superplastic, however, deformation before fracture of the alloys is lower than that of the unalloyed beryllium. The singularities of high-temperature plastic flow of the alloys and the causes of deterioration of their plasticity are determined.

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Since 1991, secondary side cracking has become a major concern in EDF steam generators. At 350 C, IGSCC of Alloy 600 was found in pure NaOH solutions from 4 to 500 g/l, with a maximum at 100 g/l. From the present results and available data, IGSCC of Alloy 690 occurred in pure NaOH solutions from 40 to 500 g/l, but the greatest sensitivity was observed at 100 g/l. TG/IGSCC of Alloy 800 became more severe with increasing NaOH solutions, from 10 to 500 g/l. On the whole, the ranking for SCC-resistance was Alloy 600 < Alloy 800 < Alloy 690. A significant improvement was still obtained with 690TT with intergranular carbides (industrial tubes) and perhaps with Alloy 800 NG (nuclear grade), but both alloys cracked at the highest stresses. IGSCC susceptibility of Alloy 600 MA was higher for the tubes ...

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One of the main requirements to use Be as a candidate for plasma facing component in ITER is providing a reliable joint between Be and Cu-alloy heat sink structure. In this work authors present the results of recent activity on this way. To create Be/CuCrZr joints the unique fast e-beam brazing technology was developed in Russia. The numbers of Be/CuCrZr mock-ups were manufactured in Efremov Institute by fast e-beam brazing using Cu-Sn-In-Ni brazing alloy. These mock-ups were tested by Sandia Laboratory at the EBTS electron beam facility. The goals of the tests were to define the allowable dimensions of the armour tiles for the heat loads of more than 10 MW/m{sup 2}, to find the limit of bond strength for the Be/CuCrZr joint and response to heat loads and to estimate the life time of the brazed tiles by thermo-cyclic testing. The screening and thermal fatigue results are presented. With the aim to check the applicability of ...

International Nuclear Information System (INIS)

In 1998, in the frame of the ITER EDA phase, an European R and D Programme for the Blanket Design was implemented for developing and selecting the materials and the relevant fabrication procedures for manufacturing the shielding modules of the ITER Primary Wall. The fabrication of several Beryllium armored small scale mock-ups, reproducing representative portions of a Primary Wall panels, was also launched (Fusion Technol. (1998) 195). Further experimental activities were also programmed for investigating the thermal-mechanical behavior of these mock-ups at high heat flux and under thermal fatigue tests. In 2001, the ITER European Home Team decided to assign to ENEA a contract for the thermal fatigue testing of six mock-ups aiming at verifying the reliability of the Beryllium/Dispersion Strengthened Copper alloy/Stainless Steel and Beryllium/Precipitation hardened Copper alloy/Stainless Steel joints manufactured by solid ...

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Nitrogen ion implantation improves the wear resistance of Ti-6Al-4V alloys by forming a hard TiN superficial passivation layer. However, the thickness of the layer formed by traditional ion implantation is typically 100-200 nm and may not be adequate for many industrial applications. We propose to use radio-frequency (RF) plasma nitriding and nitrogen plasma immersion ion implantation (PIII) to increase the layer thickness. By using a newly designed inductively coupled RF plasma source and applying a series of negative high voltage pulses to the Ti-6Al-4V samples. RF plasma nitriding and nitrogen PIII can be achieved. Our process yields a substantially thicker modified layer exhibiting more superior wear resistance characteristics, as demonstrated by data from micro-hardness testing, pin-on-disc wear testing, scanning electron microscopy (SEM), as well as Auger electron spectroscopy (AES). The performance of our newly developed inductively ...

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The deformation behavior and structure changes of magnesium alloy AZ31 were studied in compression at temperatures ranging from 523 K to 673 K and at a strain rate of 3 x 10{sup -3} s{sup -1}. They depend sensitively on deformation temperature. At high temperatures, grain fragmentation takes place due to frequent formation of kink bands initially at corrugated grain boundaries and then in grain interiors, followed by full development of new grains in high strain. At lower temperatures, in contrast, twinning takes place in rather coarse grains and kink bands are formed mainly in finer original ones in low strain. It is concluded that new grain evolution can be controlled by a deformation-induced continuous reaction resulting in grain fragmentation by kink bands, i.e. continuous dynamic recrystallization (cDRX). The latter is discussed comparing with conventional, i.e. discontinuous, DRX. (orig.)

International Nuclear Information System (INIS)

Much research has been done to estimate the residual stress on a dissimilar metal weld. There are many methods to estimate the weld residual stress and FEM (Finite Element Method) is generally used due to the advantage of the parametric study. And the X-ray method and a Hole Drilling technique for an experimental method are also usually used. The aim of this paper is to develop the appropriate FEM model to estimate the residual stresses of the dissimilar overlay weld pipe. For this, firstly, the specimen of the dissimilar overlay weld pipe was manufactured. The SA 508 Gr3 nozzle, the SA 182 safe end and SA376 pipe were welded by the Alloy 182. And the overlay weld by the Alloy 52M was performed. The residual stress of this specimen was measured by using the Neutron Diffraction device in the HANARO (High-flux Advanced Neutron Application ReactOr) research reactor, KAERI (Korea Atomic Energy Research Institute). Secondly, FEM ...

British Library Electronic Table of Contents (United Kingdom)

In the present study, new light weight nano-composites (AZ31B-3.3Al2O3-Cu) based on magnesium alloy AZ31B are developed using disintegrated melt deposition technique. Microstructural characterization studies revealed grain refinement and significant increase in amount of second phases as a result of increasing presence of copper. All the samples exhibited minimal porosity and good matrix-second phase interfacial integrity. The results also showed that addition of both nano-Al2O3 and Cu led to a simultaneous improvement in 0.2% yield compressive strength (0.2%YCS), ultimate compressive strength (UCS) and work of fracture (WoF) of the AZ31B magnesium alloy while failure strain was marginally affected. The results of this study clearly illustrate the capability of AZ31B-Al2O3-Cu formulations ...

International Nuclear Information System (INIS)

Alloy HT-9 is being used for both duct and cladding applications in advanced liquid-metal reactor (LMR) experiments. This tempered martensitic steel was selected for use as an LMR core component material primarily because of its excellent resistance to radiation-induced swelling. Experiments conducted in the Fast Flux Test Facility (FFTF) at 410 degree C and exposures in the range of 150 to 175 displacements per atom (dpa) have shown that Ht-9 exhibits only a 0.2 to 0.3% increase in volume. Cold-worked austenitic steels exhibit volumetric increases of 20 to 30% at 410 degree C, Alloy HT-9 is being used for a series of fuel pin experiments in the FFTF, and these tests have achieved a burnup of 175 MWd/kg metal and a fluence of 25 x 10"2"2 n/cm"2 (E > 0.1 MeV) without fuel pin breach. The high confidence placed in HT-9 is based on a wide series of in- and ex-reactor experiments. Test results for these experiments are summarized in this paper.

International Nuclear Information System (INIS)

During 17 years since the start of operation of the first commercial LWR in Japan, many LWRs have experienced various corrosion damages, but the causes of them were clarified, and the counter-measures were executed effectively in actual plants, as the results, the cause of corrosion damage decreased remarkably, and now, the high rate of operation has become to be maintained. In this paper, the major cases of corrosion damage experienced in LWRs in Japan and foreign countries, the causes of them and the countermeasures, the problems of hereafter and so on are described. The corrosion damage of metallic materials in the environment of LWRs occurs in the parts in contact with high temperature, high pressure water and steam, such as stainless steel piping in the primary cooling system of BWRs, and nickel alloy heating tubes of steam generators, carbon steel feed water piping and zirconium alloy fuel cladding tubes in PWRs. Recently, accompanying ...

Energy Technology Data Exchange (ETDEWEB)

Three model boilers, manufactured to simulate full-size tube sheet crevices, were tested with various secondary side environments. The first was faulted with organics representative of the decomposition of humic acid. The second was faulted with sodium carbonate and sodium hydroxide, while the third was faulted with sodium sulfate and sodium hydroxide. Each model contained seven tubes, which included Alloy 600 in the mill-annealed (MA) and thermally-treated (TT) conditions and Alloy 690 in the thermally-treated condition. Two models contained Alloy 800 tubes in the mill-annealed condition and one had Alloy 800 in the mill-annealed/cold-worked/glass-bead-peened condition. Two different sizes of tubesheet crevices were used in all model boilers. In the organics-faulted boiler, tubes of Alloy 600MA, Alloy 690TT and Alloy 800MA experienced no ...

International Nuclear Information System (INIS)

The methods of surface modification of Ti-Zr alloy by laser treatment are considered. Characteristics of laser modification without- and with surface melting and with melting in different gaseous environments and with nickel microalloying are presented. Maximum depth, hardness and corrosion resistance are observed under nickel laser alloying.

International Nuclear Information System (INIS)

Corrosion testings of model alloys, corresponding by chemical composition to simple and complex-alloyed #gamma#- and #gamma#'-phases of nickel heat-resistant alloys are conducted in sodium sulfate and chloride melts. It is ascertained that heat resistant nickel alloys containing over 50 % of hardening #gamma#'-phase, are subject to disastrous sulfide corrosion (SC). Resistance against SC alloys containing below 50 % of #gamma#'-phase is determined by the resistance of #gamma#-solid solution. 10 refs., 3 figs., 2 tabs.

Science.gov (United States)

... alloys--Lanthanum-- Magnesium--Magnasium &11oy8--Hagn*31Uft compounds--Manxganese--Manganes. alloys-- Mercury ...

Science.gov (United States)

Hilled Bend Spechene of an Alpha-Beta Titanium Alloy. Ti-6M14V. ..... The all beta titanium alloy was nllled from both sides; only the edges were taped. ...

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The nickel-rich superalloys Alloy 600 and Alloy 800 have been corroded in mildly alkaline deuterated aqueous conditions typical of secondary coolant circuits in a nuclear power station. The oxide films and substrates of these alloys have been analysed by imaging SIMS depth profiling, which makes it possible to describe elemental distribution in all three dimensions. The measurement of the distribution of the secondary ions NiO[sup -], FeO[sup -] and CrO[sup -] appears useful for detailing the behaviour of nickel, iron and chromium within oxidized phases. The measurement of D[sup -] distribution outlines the extent of oxide hydration. For Alloy 800, evidence of sodium migration into the grain boundaries of the alloy substrate is found. For Alloy 600, no grain boundary sodium ingress can be identified under comparable corrosion conditions. (author).

Energy Technology Data Exchange (ETDEWEB)

The resistance to pitting of a Fe-17%Cr alloy in Cl[sup [minus

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Welded Ni-base alloys and Alloy 800 were exposed under metal dusting conditions at 600 C and 650 C for up to 6000 hours. Alloy 800 was attacked very strongly already in the first days and Alloy 600 also rather soon and widespread, on both materials attack started mainly in the heat affected zone. Several surface states of Alloy 600: brushed, ground, sand-blasted and pickled were tried only grinding caused a modest delay and decrease of metal dusting attack. Generally the attack was less widespread but deeper at 650 C than at 600 C, also for Alloy 601 and 602. The latter alloys show minor, mainly local attack, but especially the welds are affected. TIG welding led to better resistance than hand-welding. (Abstract Copyright [2003], Wiley Periodicals, Inc.)

Science.gov (United States)

... CLOSURE DURING HOT WORKING OF AN ALPHA/BETA TITANIUM ALLOY (PREPRINT) ... HOT WORKING OF AN ALPHA/BETA TITANIUM ALLOY ...

Science.gov (United States)

... Title : DUCTILITY RATIO OF AGED BETA TITANIUM ALLOY. Corporate Author : NEW YORK UNIV NY SCHOOL OF ENGINEERING AND SCIENCE. ...

International Nuclear Information System (INIS)

Stemming from their unique combination of elevated strength, low density, and good overall corrosion resistance, beta titanium alloys have become attractive candidate materials for critical, high-stress, components in corrosive services. An overview of the comparative corrosion resistance of beta alloys to conventional alpha and alpha/beta titanium alloys in common industrial and aerospace service environments generally reveals attractive behavior depending on the environment and alloy composition and, in some cases, alloy condition. Expanded performance windows are especially noted for the molybdenum-rich beta alloys, particularly in regard to resisting reducing acids, stress corrosion, and high temperature localized chloride attack, along with hydrogen and oxidation resistance. Where applicable, implications of this enhanced corrosion performance on current ...

International Nuclear Information System (INIS)

A processing technique for A-15 compounds which has improved mechanical and superconducting properties has been developed. This technique consists of rapid solidification of the alloy by the chill block spinning machine (CBSM) to form amorphous ribbons and by subsequent annealing crystallizes the stable or metastable fine grain flexible A-15 structure. The CBSM has been modified so that all the processing parameters could be controlled and optimized for each alloy composition. By the improved CBSM it was possible to form amorphous Nb_3Si, Nb_3Ge and Nb_3(AlSi) ribbons with more than 80% reproducible rate. Critical current density measurements are limited by contact resistance. A Cu plating technique was introduced in this research that made the contact resistance three orders of magnitude lower than that obtained by other methods. This plated coating also gave an additional mechanical support to the sample and acted as a ...

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Magnetothermal measurements up to 1600 K have been made on alloys in the ternary Ni-Mn-Sb system with a constant ratio Mn/Sb=1/1, to which belong the two ferromagnetic Heusler phases Ni/sub 2/MnSb with L2/sub 1/ structure and NiMnSb with C1/sub b/ structure. The susceptibility-temperature curves show the constitution of the vertical section. At high temperatures the susceptibilities obey a Curie-Weiss law. In the solid state the effective magneton number decreases with increasing Mn concentration from 4.9 (Ni/sub 2/MnSb) to 3.8 (NiMnSb). Simultaneously, on the transition from Ni/sub 2/MnSb to NiMnSb there is a strong increase of the susceptibility and of the Curie temperature from 292 to 686 K. In the heterogeneous range between 10 and 20 at.% Mn another phase part appears which is ferromagnetic at room temperature. By a heat treatment it undergoes a distinct development. In the liquid phase, the alloys can be characterized ...

International Nuclear Information System (INIS)

Basic studies of the oxidation resistance of Fe-Cr binary and Fe-Cr-Ni ternary alloys in pure oxygen have shown that the excellent corrosion resistance of Alloy 800 is explicable in terms of the low defect concentrations and diffusion rates in the oxide forming on alloys of this composition in sufficiently oxidising environments. The performance of Alloy 800 in environments of particular importance to nuclear power generation is briefly reviewed to determine to what extent ideas derived from the basic studies of Fe-Cr-Ni ternary alloys are borne out in practice. The good corrosion resistance of Alloy 800 in steam and CO_2 and, to some extent, in molten salt environments is in agreement with the behaviour of ternary alloys in oxygen. Minor aliovalent alloying additions are only expected to have a significant effect on the ...

International Nuclear Information System (INIS)

At 650"0C, the low-cycle fatigue life was essentially the same for the two alloys on the basis of strain amplitude, but Alloy 800H had a longer life on the basis of stress amplitude. A 500"0C, Alloy 800 and 800H exhibited longer fatigue lifetime than at 650"0C, with Alloy 800 exhibiting a 2-3 times longer life than Alloy 800H when compared on the basis of plastic strain range, whereas the difference was less pronounced when compared on the basis of stress amplitude. When a creep effect was introduced either by way of a hold time or a reduced frequency, Alloy 800 exhibited a greater reduction in life than did Alloy 800H. The dislocation structure changed from planar to cellular with increase in strain range, and extensive precipitation of M_2_3C_6 was noted within the grains for Alloy 800H and along grain boundaries for ...

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To clarify the acidic and alkaline Intergranular Stress Corrosion Cracking (IGSCC) mechanism of thermally treated alloy 690 (alloy 690 TT) and shot peened alloy 800 (alloy 800 SP), C-ring tests were conducted in deaerated HCl solutions and in deaerated NaOH solutions at 350degC, compared with the acidic and the alkaline IGSCC susceptibilities of mill-annealed alloy 600 (alloy 600 MA), full-sensitized one (alloy 600 FS) and thermally treated one (alloy 600 TT). Grain boundary characteristics, such as chromium depleted zone and chromium carbide precipitation, were examined using modified Huey test and Transmission Electron Microscopy. Potential-pH diagram for Ni, Cr, Fe-H{sub 2}O system at 350degC was constructed and the solubilities of NiO, Cr{sub 2}O{sub 3} and Fe{sub 3}O{sub 4} were also calculated to evaluate the ...

British Library Electronic Table of Contents (United Kingdom)

The Wendelstein 7-X (W7-X) modular stellarator is under construction at the Max-Planck-Institut fur Plasmaphysik in Greifswald, Germany. The W7-X magnet system contains 70 coils made up from helium cooled superconducting cables in aluminium alloy (EN AW-6063) jackets. Several hundred connections of the jacket to the cable joints are made by aluminium-to-aluminium welds. Due to geometrical and thermal boundary conditions these welds cannot be accomplished free from defects. Microscopic analyses of the welds show that a variety of small flaws such as cracks and pores develop during welding. The welds have thus to be dimensioned accordingly, and appropriate weld qualification, investigation and testing has to be done in order not to jeopardise the structural integrity and leak tightness. The ...

CERN Document Server

The development of a replacement to the conventional film based X-ray imaging technique is required for many reasons. One possible route for this is the use of a large area film of a suitable semiconductor overlaid on an amorphous silicon readout array. A suitable semiconductor exists in cadmium telluride and its tertiary alloy cadmium zinc telluride. In this thesis the spectroscopic characteristics of commercially available CZT X- and gamma-radiation detectors are established. The electronic, optical, electro-optic, structural and compositional properties of these detectors are then investigated. The attained data is used to infer a greater understanding for the carrier transport in a CZT radiation detector following the interaction of a high energy photon. Following this a method used to fabricate large area films of CdTe on a commercial scale is described. This is cathodic electrodeposition from an aqueous electrolyte. The theory and ...

International Nuclear Information System (INIS)

This paper addresses known limitations and constraints in eddy current nondestructive testing. Incomplete appreciation for eddy current limitations is believed to have contributed to both under-utilization and misapplication of the technique. Neither situation need arise if known limitations are recognized. Some, such as the skin depth effect, are inherent to electromagnetic test methods and define the role of eddy current testing. Others can be overcome with available technology such as surface probes to find circumferential cracks in tubes and magnetic saturation of ferromagnetic alloys to eliminate permeability effects. The variables responsible for limitations in eddy current testing are discussed and where alternative approaches exist, these are presented. Areas with potential for further research and development are also identified.

International Nuclear Information System (INIS)

Peculiarities of Kurchatov Institute WWR-2 and TR research reactors spent fuel treating and transportation for radiochemical processing are stated. Spent fuels were performed as fuel assemblies of different forms and containing similar fuel elements: EhK-10 with 10% enrichment UO2-Mg fuel kernels or S-36 with 36% enrichment U-Al alloys. Spent fuel storage conditions are described. Features of developed procedures for identification of fuel assemblies by type of fuel elements are given. Transport package TUK-19 for loading and transportation of spent fuel for processing was chosen. Details of spent fuel loading in TUK-19 that is conducted by personnel under protective sheet of water in special reclaim volume are described

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Advances in nuclear reactor technology and the use of gas-cooled fast reactors require the development of new materials that can operate at the higher temperatures expected in these systems. These include refractory alloys base on Nb, Zr, Ta, Mo, W, and Re; ceramics and composites such as those based on silicon carbide (SiCf-SiC); carbon-carbon composites; and advanced coatings. Besides the ability to handle higher expected temperatures, effective heat transfer between reactor componets is necessary for improved efficiency. Improving thermal conductivity of the materials used in nuclear fuels and other temperature critical components can lower the center-line fuel temperature and thereby enhance durability and reduce the risk of premature failure.

Energy Technology Data Exchange (ETDEWEB)

The present conference discusses plasma-assisted surface coating/modification processes, the applications to date of ion nitriding, the effects of nitrogen on metal surfaces, ion nitriding mechanisms in Cr, Al and Cr + Al-containing 1040 steel, ion nitriding of Al and its alloys, life enhancement for forging dies, novel anode plasma nitriding developments, and a comparative study of the pulsed and dc ion-nitriding behavior in specimens with blind holes. Also discussed are the influence of heating method on ion nitriding, surface hardening of marage steels by ion nitriding without core hardness reduction, plasma nitriding of nodular cast iron sput gears, NbN composites for superconductors, the carburization of tungsten in a glow discharge methane plasma, economic considerations concerning plasma nitriding, and the corrosion properties obtained by ion nitriding.

International Nuclear Information System (INIS)

Intergranular corrosion (IGC) resistance of types 304LN and 316LN stainless steels (SS) thermally aged at 823, 873, and 923 K for various durations was assessed by ASTM A262 practice A test (electrolytic etch test) and electrochemical potentiodynamic reactivation (EPR) test. The results indicated that the type 316LN SS has significantly improved IGC resistance compared to 304LN SS. Based on the results of these tests, time-temperature-sensitization (TTS) diagrams were developed for both alloys. The secondary precipitates formed during thermal aging treatments were electrochemically extracted and analyzed by X-ray diffraction (XRD) to determine the types of precipitates formed during the aging treatments. The results indicated that the precipitates were mostly of M_2_3C_6 carbides.

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Super light and high performance Mg{sub 2}Si/Mg composites, which had excellent mechanical properties, were developed via the combination of solid-state synthesis and hot extrusion process. In this study, cold compacting (CP) and repeated plastic working (RPW) were firstly carried out for the mixture of Mg-Si powders, and the refinement of both Mg grains and dispersoids. Each specimen was evaluated by observation of microstructure and tensile test. As a result, it was understood that Mg{sub 2}Si dispersoids were refined and dispersed into Mg matrix, and were flowed along extrusion direction. And their mechanical properties were higher than the conventional die casting alloys. Also the effect of RPW as the improvement of properties and the decrease of synthesis temperature were confirmed. (orig.)

British Library Electronic Table of Contents (United Kingdom)

The grain morphology developed during solidification of an Al-4.5% Cu alloy is represented generally by columnar or equiaxed dendrites. Twinned feathery grains are found in the structure formed under certain heat and flow conditions during solidification. In this work, these conditions were achieved during solidification in a cavity under forced flow. Feathery grain formation is studied by means of fluid dynamics simulations with solidification included and by experiments. In order to determine the crystallographic orientation of feathery grains, electron backscattered diffraction measurements were performed. The growth features of feathery grains were analyzed by observations made normal and parallel to the growth direction. Some correlations between twinned feathery morphology, flow and ...

International Nuclear Information System (INIS)

The evolution of intergranular lattice strains in a textured, forged bar (Bar) sample of the #alpha# - #beta# titanium alloy Ti-6Al-4V has been characterised using in situ X-ray diffraction. A two-phase elastic-plastic self-consistent (EPSC) model has been developed to rationalise the results. Of the orientations analysed, it is found that the #left brace#2 0 0#right brace# #beta# orientation is the most compliant and that load partitions to this orientation during plasticity. The results from the bar material have then been used to predict the response of unidirectionally rolled plate (UD) Ti-6Al-4V. It is predicted that the residual lattice strains in the #left brace#101-bar0#right brace# and #left brace#112-bar0#right brace# orientations will be significantly higher in the UD material.

Science.gov (United States)

Development of a shear and leach complex for UO/sub 2/-SS clad fuel was continued with major emphasis on the operation of a rotary drum leacher. Flooding data for nozzle plate pulse columns at high A/O ratios are reported. Engineering tests of dissolution of Zr--6% U alloy with HF in molten salt demonstrated a dissolution rate of 0.8 to 1.5 mg/cm/sup 2//min. Subsequent fluorination with 100% F/sub 2/ proceeded at half times of 40 to 135 min. The results of a high level waste calcination (run R-72) made with formaldehyde treated simulated Purex waste are reported. (auth)

Energy Technology Data Exchange (ETDEWEB)

This paper describes an approach to the reliability engineering in aerospace technology. To promote development, configuration management (clarifies the base line of technology), reliability management, quality control, safety management, progress management, and cost management are very important. The following example related to reliability was contained for the development of an N-1 rocket in Japan. A timer and amplifier that are old-fashioned but have actual results were supplied from abroad. The induction system that was purchased from abroad contained faulty components in quality control. The improvement in reliability has priority and the first-stage tank was changed to a home-made aluminum alloy that is superior in stress-resistant corrosiveness. An H-II rocket was completely developed in Japan by self-technology. The number of faults to be generated in the H-II rocket decreases as compared with ...

Science.gov (United States)

A strategic partnership was formed among the American Foundrymen`s Society and the Federal government to develop and transfer the technology needed by the US foundry industry to: increase energy efficiency of cupola melting; improve recovery of carbon, silicon, and manganese through reduced oxidation losses; and improve productivity due to more uniform and predictable iron compositions. An effective mathematical model of the cupola offers a solution to the complex and interactive chemical and heat transfer processes to melt cast iron. The transient changes in charge size, charge composition, blast rate, and coke rate are used to optimize operation to improve melting rates, minimize oxidation losses of valuable alloying elements (C, Si, and Mn), and maintain iron composition. Despite these challenges, the cupola produces iron at a lower cost, and have better environmental controls than other melting process with 70% of domestic liquid iron ...

Science.gov (United States)

The threshold stress itensities for stress corrosion crack propagation in beta titanium alloy 38-6-44, Ti-3Al-8V-6Cr-4Mo-4Zr, has been determined in salt water and methanolic solutions. The alloy was immune to stress corrosion cracking in aqueous sodium c...

Science.gov (United States)

This paper reports Palladium alloy compositions investigated for suitability as a nonreactive material for the processing of ceramic superconductors. Barium-based superconductors were tested on Pd-Au and Pd-Ag alloys for reactivity. Bismuth-based superconductors were tested on a Pd-Ag alloy. The least reactive was found to be 70% Pd-30% Ag for the barium-based high-temperature superconductors (HTSC), whereas 30% Pd-70% Ag was found to be least reactive for bismuth-based HTSC.

Energy Technology Data Exchange (ETDEWEB)

The surface properties of copper-refractory metal (CU-RF) alloy bodies are modified by heat treatments which cause the refractory metal to form a coating on the exterior surfaces of the alloy body. The alloys have a copper matrix with particles or dendrites of the refractory metal dispersed therein, which may be niobium, vanadium, tantalum, chromium, molybdenum, or tungsten. The surface properties of the bodies are changed from those of copper to that of the refractory metal.

KoreaScience (Korea)

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KoreaScience (Korea)

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International Nuclear Information System (INIS)

General corrosion behavior of ALLOY 800 in high temperature water was studied in relation to its surface film structure. The surface film formed in water was found to decrease the corrosion rate of ALLOY 800. This film is composed of Ni ferrite, and can be obtained by oxidation in air or steam. Based on these results, air or steam oxidation treatment to inhibit Ni and Co release of ALLOY 800 into high temperature water is proposed. (author).

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KoreaScience (Korea)

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International Nuclear Information System (INIS)

This paper describes a process for the direct production of a superconductive niobium-titanium alloy during reduction of niobium pentoxide. It comprises: mixing at least one of titanium metal powder and titanium dioxide powder with niobium pentoxide powder and aluminum powder; heating the resulting mixture to form a niobium-titanium alloy and a slag consisting essentially of aluminum oxide; and separating the alloy and the slag.

International Nuclear Information System (INIS)

In this paper a study is made of the structure and mechanical properties of the #beta# alloy system Ti-Mo-Zr-Sn (the composition of which is equivalent to the #beta# III alloy used abroad) containing different amounts of carbon. Study of the #beta#-titanium alloy containing 0.1% C revealed the presence of particles of titanium carbide. Separation of the titanium carbide promotes a reduction in impact strength, an increased tendency toward cold shortness, and poorer workability. (author).

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In a work studying the corrosion and tarnishing properties of a variety of copper alloys, the alloy Cu-A110-Sn5 was found to show an excellent corrosion resistance in neutral solutions, where copper and most conventional Cu alloys are covered by thick nonprotective surface layers. The passive films formed on this alloy were characterized with electrochemical and photoelectrochemical methods. The pH dependence of the passivation and of the photocurrent behavior of the Cu-A110-Sn5 alloy clearly indicates that the passivity of this alloy in neutral solutions is due to a formation of passive film enriched with aluminum oxide. At corrosion potential a strong increase in the corrosion resistance with time is due to a gradual enrichment of the surface with aluminum oxide. This can be seen in the photocurrent spectra which change from cooper-type to aluminum-type with ...

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It is hypothesized that the good performance of Alloy 800 in steam generator service is due to its relative immunity to two distinct mechanisms of stress corrosion cracking; the argument also applies to intergranular corrosion. One mechanism operates in the high-nickel region (Alloy 600 and nearby model alloys) and is due to internal intergranular oxidation. The other operates in the low-nickel (stainless steel) region and is due to de-alloying of Fe and/or Cr. This latter mechanism may, under special conditions, operate in high-Ni, high-Cr alloys such as 690. Some essential features of the de-alloying mechanism are demonstrated using strong caustic solutions, and the prospect of extending this approach to dilute high-temperature environments is discussed. (author)

British Library Electronic Table of Contents (United Kingdom)

Statement of problem. The popularity of base metal alloys has considerably increased in recent years because of their superior mechanical properties as well as the high cost of noble alloys. However, there is disagreement about their effect on the opaque porcelain color and the color differences among base metal alloys. Purpose. The purpose of this in vitro study was to determine and compare the influence of various commercially available base metal alloys (excluding titanium-based systems) on the resulting color of opaque porcelain with the use of a colorimetric device. Material and methods. Fourteen different types of Ni-Cr and 3 different types of Co-Cr porcelain bonding alloys were selected with a Au-Pd alloy (V-Delta SF) as the control group for colorimetric measurements and determina...

International Nuclear Information System (INIS)

The threshold stress intensities for stress corrosion crack propagation in beta titanium alloy 38-6-44, Ti3Al-8V-6Cr-4Mo-4Zr, has been determined in salt water and methanolic solutions. The alloy was immune to stress corrosion cracking (SCC) in aqueous sodium chloride solutions (marine atmosphere). However, in methanolic solutions, the alloy was very susceptible to SCC. This marked susceptibility in methanolic solutions can be mitigated by the addition of an inhibitor: sodium nitrate. Crack extension in the alloy was transgranular and failure occurred by brittle quasi-cleavage in methanolic solutions.

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By the methods of microstructural and electron-microscopic analyses by the tension test and impact test studied is the effect of quenching conditions on structure and mechanical properties of the TS6 titanium-#beta# alloy. It is shown that low temperature quenching from 700 deg C, recommended earlier for analogous VT15 titanium alloy, leads to appearence of intercrystalline fracture and to sharp decrease of impact strength of the TS6 alloy. Established are optimum conditions for quenching of half-finished products and articles of the TS6 alloy depending on their subsequent working or operation.

International Nuclear Information System (INIS)

Cr_2O_3 scales are found to form on Alloy 800 and a similar pure ternary alloy in air, and 1 and 50 atm. helium containing oxidizing impurities typical of those in an SGHTR. The strong temperature dependence and neglibible helium overpressure dependence indicate that gas transport through the scales is not rate controlling. Surface oxidation rates are therefore controlled by solid state diffusion and the low oxygen partial pressure dependence of the oxidation rate in Alloy 800 is ascribed to the presence of extrinsic defects in the Cr_3O_3 (due to doping by alloying elements) or to the presence of short circuit diffusion paths. (Auth.).

International Nuclear Information System (INIS)

The creep crack growth properties of two versions of Alloy 800 have been compared at 500 and 600"0C in the Grade II condition in tests up to 10"4 hours duration. The two alloys were a low carbon alloy containing (wt.%) 0.024 C, 0.5 Ti, 0.3 Al (Alloy B) and a higher carbon alloy containing (wt.%) 0.038 C, 0.2-0.3 Ti, 0.2-3.0 Al (Alloy J). At 600"0C, Alloy B attained maximum age hardening in 10"2 hours, whereas J did not harden significantly in time up to 10"4 hours. Both alloys age hardened at 550"0C with Alloy J hardening more rapidly than B. The creep displacements and displacement rates in small compact tension specimens at 600"0C were smaller than Alloy B than in Alloy J. However, failure times were shorter in Alloy B because of lower ...

International Nuclear Information System (INIS)

In order to investigate the role of amorphous SiO2 particles in corrosion and wear resistance of Ni-based metal matrix composite alloying layer, the amorphous nano-SiO2 particles reinforced Ni-based composite alloying layer has been prepared by double glow plasma alloying on AISI 316L stainless steel surface, where Ni/amorphous nano-SiO2 was firstly predeposited by brush plating. The composition and microstructure of the nano-SiO2 particles reinforced Ni-based composite alloying layer were analyzed by using SEM, TEM and XRD. The results indicated that the composite alloying layer consisted of ?-phase and amorphous nano-SiO2 particles, and under alloying temperature (1000 deg. C) condition, the nano-SiO2 particles were uniformly distributed in the alloying layer and still kept the amorphous structure. The corrosion resistance of composite ...

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The purpose of our research program is to understand the influence of elastic misfit strain and applied stress on the development of microstructure in two-phase coherent alloys. The long-term goal of our research is to identify those material parameters that promote microstructural stability in multiphase systems at elevated temperatures. Our efforts since the last progress report in February 1991 have been twofold. First, we have continued performing coarsening simulations of elastically and diffusionally interacting particles in an infinite matrix. In addition, we have been performing simulations of unstressed systems during coarsening. Secondly, we have begun to develop an experimental component to the research that would allow a careful comparison between theory, computer simulations and experiment. We have continued to focus our computer simulations of stressed systems on elastically homogeneous and isotropic systems ...

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(Al{sub y}Ga{sub 1{minus}y}){sup 1{minus}x}In{sub x}P semiconductor alloys lattice-matched to GaAs are widely used in visible optoelectronic devices. One of the most recent developments in this area is the AlGaInP-based red vertical cavity surface emitting laser (VCSEL). These lasers, which employ AlGaInP active regions and AlGaAs distributed Bragg reflectors (DBRs), have demonstrated continuous-wave (CW) lasing over the 630--690 nm region of the spectrum. Applications for these lasers include plastic fiber data communications, laser printing and bar code scanning. In this paper, the authors present an overview of recent developments in the processing and performance of AlGaInP based VCSELs. This overview will include a review of the general heterostructure designs that have been employed, as well as the performance of lasers fabricated by both ion implantation and selective oxidation.

International Nuclear Information System (INIS)

In order to effectively recover uranium, rotation speed of solid cathode was examined, and effect of uranium concentration and current density on electrodeposition were confirmed. And the potentiostatic and galvanostatic electrorefining experiments were conducted. Element used in the experiments were Zr, Nd, La chlorides. The reduction potentials of chlorides metals on liquid Cd cathode were measured by cyclic voltammetry experiments. The electrowinning experiments were performed in order to recover small amounts of uranium in salt. Experimental set-up for the batch type reductive extraction experiments were developed and installed. On the base of experimental results of batch type, multi-stage extraction equipment was set-up, and optimum number of stage and recover yield were measured. In the oxidative extraction study is examine selective separation behavior of the rare earth metals from alloy composed of actinide and lanthanide metals to ...

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A series of cyclic strain controlled tests have been carried out at 600/sup 0/C on three high temperature austenitic iron-based alloys, AISI type 316 stainless steel, Alloy 800 H and Sandvik 253 MA. The tests were carried out under constant total strain control using a constant strain rate of 0.005 s/sup -1/. By considering the changes in modulus throughout the life of each specimen it was found that damage evolution could be successfully predicted as a function of plastic strain range despite the fact that each alloy had been chosen because of a different stress response at 600/sup 0/C. Although each alloy accumulated fatigue damage in a similar manner the longer lives of Sandvik 253 MA and Alloy 800 H at a given total strain range were due to a smaller plastic strain component and a reduced stage I crack propagation rate. In the 253 MA alloy, slip was ...

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The Control Rod Drive(CRD) nozzles for PWR nuclear power plants(NPP) house the control rod drives. The number of nozzle penetrations range from the mid-30's to over 100 in each reactor head. The integrity of CRD nozzles is very important, because the primary pressure boundary is established with the J-groove weld joining the nozzle to the head clad surface. The Alloy 600 PWSC CRD nozzle leaks discovered in the fall of 2000 and spring of 2001 in several US plants. Therefore the NRC has recommended a more proactive effort by US utilities to inspect similarly susceptible nozzles in all US plants. The primary safety concern is circumferential cracks that can permit the nozzles to separate from the head at high velocity and produce a large-break leak in the reactor vessel. A secondary concern is head leakage from any through-wall cracks in the nozzle or J-groove weld area. Numerous inspection and repair tools have been developed to address ...

British Library Electronic Table of Contents (United Kingdom)

Gas nitridation has shown excellent promise to form dense, electrically conductive and corrosion-resistant Cr-nitride surface layers on Ni-Cr base alloys for use as proton exchange membrane fuel cell (PEMFC) bipolar plates. Due to the high cost of nickel, Fe-base bipolar plate alloys are needed to meet the cost targets for many PEMFC applications. Unfortunately, nitridation of Fe-base stainless steel alloys typically leads to internal Cr-nitride precipitation rather than the desired protective surface nitride layer formation, due to the high permeability of nitrogen in these alloys. This paper reports the finding that it is possible to form a continuous, protective Cr-nitride (CrN and Cr2N) surface layer through nitridation of Fe-base stainless steel alloys. The key to form a protective Cr...

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In this work, we have investigated the capability of different bimetallic nanoparticle alloy combinations to be used in fibre optic sensors based on the technique of surface plasmon resonance. The metals considered for this analysis are silver, gold, copper and aluminium. The performance of the sensor with different bimetallic nanoparticle alloy combinations is evaluated and compared numerically. The performance is analysed in terms of three parameters: sensitivity, signal-to-noise ratio (SNR) and operating range for the sensing layer refractive index values. On the basis of the comparison and some logistic criteria, the best possible bimetallic alloy combinations along with a requisite alloy composition ratio are predicted. The bimetallic nanoparticle alloy combination is capable of simultaneously providing larger values of sensitivity, SNR and operating range, which is not ...

International Nuclear Information System (INIS)

Nano indentation analysis and transmission electron microscopy observation were performed to investigate a microstructural evolution and its influence on the hardening behavior in Fe-Cr alloys after an irradiation with 8 MeV Fe4+ ions at room temperature. Nano indentation analysis shows that an irradiation induced hardening is generated more considerably in the Fe-15Cr alloy than in the Fe-5Cr alloy by the ion irradiation. TEM observation reveals a significant population of the a0 dislocation loops in the Fe-15Cr alloy and an agglomeration of the 1/2a0 dislocation loops in the Fe-5Cr alloy. The results indicate that the a0 dislocation loops will act as stronger obstacles to a dislocation motion than 1/2a0 dislocation loops.

International Nuclear Information System (INIS)

Resistance of Alloy 800 as a PWR S/G tube material to IGC/IGSCC and Ni, Co release into water was evaluated as compared with Alloys 600 and 690. The study to improve the resistance to IGSCC and general corrosion was also made, including the effects of shot-peening on the distribution of the residual stress of the U-bent tubes and the susceptibility to SCC, the stabilizing elements on IGC/IGSCC, and prior oxidation on general corrosion. From the results, shot-peened Alloy 800 was estimated to be the most reliable S/G tube material among the high nickel alloys tested. In addition, the Alloy 800 tube would obtain further reliability in IGSCC and general corrosion resistance by the combined addition of Ti, and Nb, and the prior oxidation of the inner tube surface, respectively.

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