Summary on performance study of corrosion resistance of zirconium alloys
International Nuclear Information System (INIS)
Zirconium-base alloys are used primarily as fuel cladding material and other core structure material in water cooled nuclear power reactors. Main research achievements and problems about corrosion of zirconium alloys are reviewed; the present theories and challenge are summarized. In the 1980s, great progress had been made towards correlating alloy composition, microstructure and irradiation with corrosion resistance. In the 1990s, main researches are focused on exploring actual mechanism of corrosion, optimizing both alloy composition and microstructure in order to minimize the fuel cycle costs through burnup optimization.
Reactor fuel cladding tube with excellent corrosion resistance and method of manufacturing the same
International Nuclear Information System (INIS)
The present invention provides a fuel cladding tube having an excellent corrosion resistance and thus a long life, and a suitable manufacturing method therefor. Namely, in the fuel cladding tube, the outer circumference of an inner layer made of a zirconium base alloy is coated with an outer layer made of a metal more corrosion resistant than the zirconium base alloy. Ti or a titanium alloy is suitable for the corrosion resistant metal. In addition, the outer layer can be coated by a method such as vapor deposition or plating, not limited to joining of the inner layer material and the outer layer material. Specifically, a composite material having an inner layer made of a zirconium alloy coated by the outer material made of a titanium alloy is applied with hot fabrication at a temperature within a range of from 500 to 850degC and at a ...
1993-07-14
Electrometallurgical treatment of aluminum-matrix fuels
Energy Technology Data Exchange (ETDEWEB)
The electrometallurgical treatment process described in this paper builds on our experience in treating spent fuel from the Experimental Breeder Reactor (EBR-II). The work is also to some degree, a spin-off from applying electrometallurgical treatment to spent fuel from the Hanford single pass reactors (SPRs) and fuel and flush salt from the Molten Salt Reactor Experiment (MSRE) in treating EBR-II fuel, we recover the actinides from a uranium-zirconium fuel by electrorefining the uranium out of the chopped fuel. With SPR fuel, uranium is electrorefined out of the aluminum cladding. Both of these processes are conducted in a LiCl-KCl molten-salt electrolyte. In the case of the MSRE, which used a fluoride salt-based fuel, uranium in this salt is recovered through a series of ...
1996-08-01
Energy Technology Data Exchange (ETDEWEB)
The desire to increase uranium utilization and to minimize spent fuel storage requirements provides an incentive to extend the average fuel rod discharge burnup to about 70,000MWd/MTU. For these higher burnups data are needed to determine if waterside corrosion of the cladding may be a life-limiting feature of fuel rod design. It is apparent that many factors can influence waterside corrosion, and these need to be better understood in order to minimize corrosion at these higher target burnups. The objective of this report is to review published data relevant to the corrosion of Zircaloy under PWR operating conditions. (author). 100 refs., 4 tabs., 21 figs.
1999-02-01
Zirconium for superior corrosion resistance
International Nuclear Information System (INIS)
Zirconium is a transition element located along with sister elements titanium and hafnium in Group IVB of the periodic table. It is grayish white metal, with a density somewhat less than carbon steel. Zirconium is the ninth most common metallic element in the earth's crust, and is more abundant than zinc, lead, nickel, or even copper. Zirconium is exceptionally resistant to corrosion by many common acids and alkalis. It is resistant to most organic acids, such as formic, acetic, lactic, and oxalic acids. It also has a high resistance to localized forms of corrosion, such as pitting, crevice corrosion, and stress corrosion cracking. Its corrosion resistance is caused by the formation of a dense, tenaciously adherent, chemically inert oxide film on the surface. This oxide film protects the base metal from both chemical and mechanical attack at temperatures up to about 400 C (750 F). This article describes ...
British Library Electronic Table of Contents (United Kingdom)
Flame propagating through zirconium particle cloud in a small-scale vertical rectangle chamber was investigated experimentally. In the experiments, the zirconium quoted 99% purity was used and the diameter of particles was distributed 1?22 ?m. The zirconium dust was dispersed into the chamber by air flow and ignited by an electrode spark. A high-speed video camera was used to record the images of the propagating flame. Micro-thermocouples, schlieren optical system and microscopic lens were used to obtain temperature profiles and flame structure, respectively. Based on the experimental results, flame propagation characteristics and flame structure of zirconium particle cloud were analyzed. The propagation velocity of the flame is quite slow in the initial 14 ms and then accelerates to maxim...
2010-01-01
Evaluation method for corrosion resistance of zirconium alloy
International Nuclear Information System (INIS)
The present invention concerns a method of evaluating corrosion resistance of a zirconium alloy easily and in a short period of time. An anode polarization curve of the zirconium alloy is measured to obtain an anode polarization curve expressed by logarithm. The curve is converted to a potential-current density curve expressed by absolute values. The peak area in the curve of the converted potential-current density is indicated by numerical values. Further, the corrosion resistance of the zirconium alloy is evaluated based on the peak area converted into the numerical values as a reference. This method is based on the finding that the peak area has a close relation with nodular corrosion resistance, and the corrosion resistance can be judged with respect to a specific zircaloy-2. (T.M.).
1993-03-26
Energy Technology Data Exchange (ETDEWEB)
Total hemispherical emittance was measured for the SP-100 reactor fuel cladding alloy (Nb-l% Zr). Based on a standard test method (ASTM C 835-82), experiments were conducted on a reference sample of oxidized stainless steel and then on a sample of actual cladding. The sample is heated in a vacuum by passing DC current through it until reaching equilibrium. Measurements are made of the electrical power dissipated in the sample and of the surface temperature. Using the Stefan-Boltzmann Law and some key assumptions concerning conductive and radiative heat transfer, the measured quantities are used to calculate emittance. Calculated values for unoxidized cladding range from 0.159 +/- 5.35% at 913 K to 0.200 +/- 4.51% at 1091 K. Highest value measured after onset of visible oxidation was 0.339 +/- 3.92% at 1269 K.... SP-100, Reactor, Emittance, Niobium, Fuel cladding, Emissivity.
1992-12-01
Plasma deposition of sealing coatings based on zirconium dioxide
International Nuclear Information System (INIS)
Technology of plasma sputtering, structure and properties of zirconium dioxide coatings were studied. Necessity of void number increase to enhance coating heat-resistance is shown. Optimal powder particle size (20-60 #mu#m) providing optimal coating porosity was determined. Weight part of stabilizating oxide (Y_2O_3) in ZrO_2 for formation in coating of microcracks serving as barriers for macro-cracks propagation was determined.
1992-01-01
Activation calculations using an expanded data base
Energy Technology Data Exchange (ETDEWEB)
Using an expanded nuclear data base, the activation of nitrogen, aluminum, iron, nickel, copper, zirconium, niobium, molybdenum, tungsten, and lead were calculated for the first wall positions of the STARFIRE and MARS conceptual fusion reactors.
1986-04-01
Aspects of the contamination with oxygen in obtaining low enriched uranium fuel
International Nuclear Information System (INIS)
The manufacturing of TRIGA fuel rods with low enriched uranium follows in principle the same route as high-enriched uranium. The high purity of the primary metals (uranium, zirconium and erbium) is important for determining the equilibrium metal-hydrogen phases. The impurities from the metal, on the surface and from hydrogen may have an important influence on the hydriding process. This paper presents the aspects of the fuel contamination with oxygen during the manufacturing process of the low enriched uranium fuel. The continuous control of the oxygen concentration in the working zone ensures avoidance of the accidental contamination. Key words: manufacturing, fuel, oxygen, contamination. (authors)
2009-10-12
Osseointegration of zirconia implants: an SEM observation of the bone-implant interface
UK PubMed Central (United Kingdom)
BackgroundThe successful use of zirconia ceramics in orthopedic surgery led to a demand for dental zirconium-based implant systems. Because of its excellent biomechanical characteristics,...Full Text Available
LITERATURE SURVEY OF THE CORROSION BEHAVIOR OF TANTALUM, ZIRCONIUM, AND TITANIUM
The corrosion behavior of Ta, Ti, and Zr in inorganic acids, bases, chlorides and miscellaneous salts, waters and gases, and organic acids and miscellaneous organic chemicals is summarized. (W.L.H)
1955-02-23
State-of-the-art technology for production of seamless tubes in zirconium and titanium alloys
International Nuclear Information System (INIS)
Zircaloy fabrication plant manufactures all the necessary Zr-2 components like fuel canning tubes, calandria tubes and other rod and sheet products. This plant is having a capacity of producing about 4 lakh nos. of PHWR fuel tubes per annum. These tubes are seamless, thin walled with close dimensional tolerances and stringent mechanical properties. The plant has established all the facilities required to produce these tubes with required quality.
International Nuclear Information System (INIS)
Current trends in nuclear power generation (and particularly in pressurized water reactors) are toward plant life extension and extended fuel burnup. A higher heat generation rate can induce local boiling regimes at the fuel rod surface in the hottest channels of the core, which can strongly modify the chemical environment of the cladding and influence the oxidation rate of zirconium alloys. Tests performed in out-of-pile loops under severe chemical and thermal-hydraulic conditions (nucleate boiling, higher lithium contents compared to PWRs) reveal two important phenomena: an increase of the oxidation rate of Zircaloy-4 cladding materials in 'high' lithiated environments; an enrichment of the chemical additives in the primary water (boron, lithium) at the surface of the cladding under nucleate boiling conditions. The latter phenomenon, also called 'hideout effect', is mainly controlled by some thermal hydraulic parameters ...
1999-12-01
Energy Technology Data Exchange (ETDEWEB)
The incorporation of (a) Cs/Sr as simulated heat-generating isotopes contained in Purex reprocessing waste, (b) simulated actinides, and (c) simulated Purex waste in sodium zirconium phosphate (NZP) has been studied. The samples were prepared by sintering, by hot pressing and by hot isostatic pressing in metal bellows containers. The short-term chemical durability of the phosphate-based material containing Purex waste was within an order of magnitude of that for Synroc-C, as measured by 7-day MCC-1 tests at 90{degrees}C. The dissolution behavior showed evidence of re-precipitation phenomena, even after times as short as 28 days. Potential for improvement of NZP-based ceramics for HLW management is discussed. 19 refs., 4 figs., 3 tabs.
1996-12-31
Comparison of sodium zirconium phosphate and Synroc matrices for immobilization of high-level waste
Energy Technology Data Exchange (ETDEWEB)
The aims of the present work were to investigate possible compatibility between sodium zirconium phosphate (NZP) and Synroc titanate phases, to prepare NZP-based waste forms by hot-pressing rather than sintering, and to investigate the incorporation in NZP of (a) Cs/Sr as simulated heat-generating nuclides; (b) simulated actinides; and (c) simulated Purex waste. The NZP samples were prepared by methods similar to those used for Synroc. The precursor NZP phase was formed from tetrabutyl zirconate Zr(OC{sub 4}H{sub 9}){sub 4}, sodium nitrate, and 85% orthophosphoric acid. Simulated waste nitrate solutions were then mixed with the liquid precursor. After stir drying of the precursor, calcination was carried out at 700{degree}C to remove nitrates and organics.
1996-12-31
The TTT diagrams describing the beta to alpha isothermal transformation have been made by isothermal dilatometry for pure uranium and 21 alloys based on chromium, silicon, molybdenum, iron, aluminium, zirconium. The thermal cycle preceeding the isothermal...
1966-01-01
Introduction to corrosion of bioimplants
British Library Electronic Table of Contents (United Kingdom)
The review provides a general idea about the types of metallic alloys and the pure metals used as implant materials in dental and orthopedic surgery. Their corrosive behavior in both real solutions and various media that model human biological fluids is described. Based on the literature data, it is concluded that multicomponent alloys containing titanium, niobium, zirconium, tungsten, molybdenum, aluminum, and silicon are the most resistant to corrosion. Implants made of different types of stainless steel are preferred when manufacturing orthopedic devices for short-term use.
2011-01-01
Development of zirconium alloys. Part II
A number of alloys of zirconium have been investigated as part of a program aimed at improving the high-temperature tensile and creep strength of zirconium. These alloys include aluminum, beryllium, lead, magnesium, molybdenum, niobium, tantalum, tin, titanium, tungsten, vanadium, and zinc, binary and ternary alloys. The data indicate that aluminum, lead, molybdenum niobium, tin, titanium, tungsten, and vanadium can be used successfully to harden zirconium, and that aluminum, tin, titanium, and vanadium are particularly effective in maintaining the strength of zirconium at elevated temperatures.
1952-01-02
Laser-Based Fuel Cell Manufacturing for Thermal ...
... FLUENT PEM fuel cell toolbox is actually composed of many User Defined Functions that are incorporated into the fuel cell model developed by ...
2005-10-12
Trace metal characterization of the U-Al matrix by atomic spectroscopy
International Nuclear Information System (INIS)
Uranium-aluminum alloys with a significant enrichment of uranium with "2"3"3U or "2"3"5U serve as nuclear fuels in research reactors. The quality assurance of this fuel requires, among other things, precise knowledge that all trace metal constituents that affect neutron economy, fuel integrity, and fuel fabrication process parameters are well within the specification limits. Trace metal characterization of "2"3"5U-Al alloy has been carried out by atomic spectrometry. The trace metal constituents of interest are grouped into common metals (silver, boron, calcium, cadmium, cobalt, chromium, copper, iron, magnesium, manganese, molybdenum, sodium, nickel, lead, silicon, tin, titanium, vanadium, tungsten, and zinc) and lanthanides (cerium, dysprosium, europium, gadolinium, holminium, lutetium, samarium, and terbium). The elements yttrium and zirconium are grouped with the latter in view ...
International Nuclear Information System (INIS)
In one of the first uses of high Tc superconductors in an end-use product, Lake Shore Cryotronics and a Swiss lab have developed a liquid nitrogen level sensor using a high Tc thin film. The probe is manufactured using a seamless stainless steel tube with an yttrium-based zirconium oxide flame-sprayed on the tube. A plasma-sprayed superconductor compound is deposited on top of that. The probe is coated with a sealant that protects the superconducting film from the atmosphere. This manufacturing method has yielded an extremely durable product. Unaffected by ice formation and related mechanical problems, the superconducting level sensor can be kept in the dewar for long periods of time.
Research efforts to produce a {sup 99}Mo-{sup 99m}Tc generator using reactor-produced {sup 99}Mo
Energy Technology Data Exchange (ETDEWEB)
Recognizing the importance of {sup 99m}Tc and {sup 99m}Tc-based radiopharmaceuticals in nuclear medicine, the Philippine Nuclear Research Institute has initiated research on the development of column-type generators for {sup 99m}Tc using {sup 99}Mo in the form of a gel. The use of reactor-produced {sup 99}Mo will reduce the country's dependence on the importation of commercial generators based on fission product molybdenum-99. However, the relatively low specific activity of {sup 99}Mo must be compensated by the high adsorption capacity of the column material for molybdenum. A procedure based on the incorporation of low activity {sup 99}Mo into a zirconium molybdate gel matrix was adopted with reasonable success. Because the properties of the gel vary considerably with conditions of synthesis, the following parameters were carefully controlled: pH, concentration, temperature, order of mixing of ...
2003-03-01
Mechanism of zirconium complexing with biphenyl mono- and biscatecholylazo derivatives
Energy Technology Data Exchange (ETDEWEB)
The complex formation of zirconium with biphenyl mono- and biscatecholyazo derivatives has been studied spectrophotometrically. The composition of the complexes, form and charge of complex-forming zirconium ions have been established. A procedure is suggested for calculation of molar absorptivities and stability constants for each of the complexes formed simultaneously in the system. Possible complex formation schemes have been studied. The data obtained were used to develop a spectrophotometric method of determining zirconium in the presence of large amounts of copper.
1982-05-01
Hydrous oxide activated charcoal
Energy Technology Data Exchange (ETDEWEB)
This patent describes a process for preparing of an ion exchanger, comprising: treating an ionically inert activated charcoal porous support with an aqueous solution of metal oxychloride selected from the group consisting of zirconium and titanium oxychlorides so as to impregnate the pores of the support with the solution; separating the treated support from excess metal oxychloride solution; converting the metal oxychloride to a hydrous metal oxide precipitate in the pores of the support at a pH above 8 and above the pH whereat the hydrous metal oxide and activated charcoal support have opposite zeta potentials and sufficient to hydrolyze the metal oxychloride. It also describes a process for preparing an ion exchanger comprising: treating granulated activated charcoal with a concentrated solution of a metal oxychloride from the group consisting of zirconium and titanium oxychlorides, degassing the mixture; and treating the resultant mixture ...
1987-09-08
Energy Technology Data Exchange (ETDEWEB)
This project of law concerns an additional protocol to the agreement of warranties signed on September 22, 1998 between France, the European atomic energy community and the IAEA. This agreement concerns the declaration of all information relative to the R and D activities linked with the fuel cycle and involving the cooperation with a foreign country non endowed with nuclear weapons. These information include the trade and processing of nuclear and non-nuclear materials and equipments devoted to nuclear reactors (pressure vessels, fuel loading/unloading systems, control rods, force and zirconium tubes, primary coolant pumps, deuterium and heavy water, nuclear-grade graphite), to fuel reprocessing plants, to isotope separation plants (gaseous diffusion, laser enrichment, plasma separation, electromagnetic enrichment), to heavy water and deuterium production plants, and to uranium conversion plants. ...
2002-10-01
International Nuclear Information System (INIS)
In association with periodic inspection of CANDU nuclear power plant components, Canadian Standards Association issued CSA N285.8 in 2005 as technical requirements for in-service evaluation of zirconium alloy pressure tubes in CANDU reactors. This first version, CSA N285.8 involves procedures for, firstly, the evaluation of pressure tube flaws, secondly, the evaluation of pressure tube to calandria tube contact and, thirdly, the assessment of a reactor core, and material properties and derived quantities. The evaluation of pressure tube flaws includes delayed hydride cracking evaluation the procedures of which are stipulated based on the existing delayed hydride cracking models. For example, the evaluation of flaw-tip hydride precipitation during reactor cooldown involves a procedure to calculate the equilibrium hydrogen equivalent concentration in solution at the flaw tip, Htipas follows: Htip=Hfexp[- (VH delta no.)/RT], where Hf is the total ...
2007-05-10
Modification of fuel bundles and associated optimization of fuel handling equipment
Energy Technology Data Exchange (ETDEWEB)
This is a continuation of research that started in July 2007 at the Deep River Science Academy. The research was related to the effects of endplate thickness and misalignment of fuel bundles in the fuel channel on pressure losses of reactor coolant. Based on this research, a new approach to refueling of the CANDU reactor has been developed. It greatly simplifies fuel handling equipment and increases its reliability. It also reduces required staffing, as well as operating and maintenance costs associated with fuel handling. (author)
2008-07-01
Thermal release of volatile fission products from irradiated nuclear fuel
International Nuclear Information System (INIS)
An effective procedure for removing _3H, Xe and Kr from irradiated fuels was demonstrated using Shippingport UO"2 fuel. The release characteristics of _3H, Kr, Xe, and I from irradiated nuclear fuel have been determined as a function of temperature and gaseous environment. Vacuum outgassing and a flowing gas stream have been used to vary the gaseous environment. Vacuum outgassing released about 99% of the _3H and 20% of both Kr and Xe within a 3 h at 1500_0C. Similar results were obtained using a carrier gas of He containing 6% H"2. However, a carrier gas containing only He resulted in the release of approximately 80% of the _3H and 99% of both Kr and Xe. These results indicate that the release of these volatile fission products from irradiated nuclear fuel is a function of the chemical composition of the gaseous environment. The rate of tritium release increased with increasing temperature (1100 to ...
and used to reduce or replace petroleum-based transportation fuel, heating oil or jet fuel). In addition, this rule includes a new regulatory provision establishing a...
2010-09-27
from a military fuel storage facility released about 80,000 gallons of kerosine-based jet fuel. Immediate and extensive recovery measures managed to contain the spill, but...
2011-10-08
from a military fuel storage facility released about 80,000 gallons of kerosine-based jet fuel. Immediate and extensive recovery measures managed to contain the spill, but...
2011-08-27
Bio-fuels for the gas turbine: A review
International Nuclear Information System (INIS)
Due to depletion of fossil fuel, bio-fuels have generated a significant interest as an alternative fuel for the future. The use of bio-fuels to fuel gas turbine seems a viable solution for the problems of decreasing fossil-fuel reserves and environmental concerns. Bio-fuels are alternative fuels, made from renewable sources and having environmental benefit. In recent years, the desire for energy independence, foreseen depletion of nonrenewable fuel resources, fluctuating petroleum fuel costs, the necessity of stimulating agriculture based economy, and the reality of climate change have created an interest in the development of bio-fuels. The application of bio-fuels in automobiles and heating applications is ...
2010-12-01
Energy Technology Data Exchange (ETDEWEB)
The distribution of the alkaline earth elements strontium and barium between the solid phases of phosphates of transition elements of group 4 and chloride melts was studied. The distribution coefficients of strontium and barium were found at T = 700-800/sup 0/C. Phosphates of the type NaM/sub 2//sup (IV)/(PO/sub 4/)/sub 3/, where M/sub (IV)/ represents titanium, zirconium, and hafnium, were used as the solid phases. It was established that there is an enrichment of the precipitates with the distributed components. The distribution coefficient depends on the nature of the solid phase and the temperature. It was suggested that M/sup (II)/ x M/sub 4//sup (IV)/(PO/sub 4/)/sub 6/ is formed in processes of distribution, where M/sup (II)/ represents Sr, Ba.
1987-07-01
Study on the use of zirconium phosphate for radioactive waste treatment
International Nuclear Information System (INIS)
Zirconium phosphate was one of the earliest inorganic ion-exchange suggested for removing strontium and cesium from aqueous nuclear waste. This paper studied ionic exchange to remove Cs-137 and Sr-90 by using different cationic of zirconium phosphate. In this case the parameters studied were the effect of temperature and ion concentration to percent up take and distribution coefficients. It is also conducted the study on column experiments to determine the breakthrough curves for Cs-137 and Sr-90. The result showed the potential of use of zirconium phosphate in radioactive waste treatment. (author)
1998-12-01
Energy Technology Data Exchange (ETDEWEB)
The electrochromatographic behavior of 25 metal ions on zirconium tungstate-impregnated papers is described. Six background electrolytes were used. On the basis of the differential mobilities of metal ions which depend on the ion-exchange properties of zirconium tungstate and the nature of complex formation with the electrolytes, some important binary and ternary separations have been achieved.
1980-03-01
GRAIN REFINEMENT OF PERMANENT MOLD CAST COPPER BASE ALLOYS
Energy Technology Data Exchange (ETDEWEB)
Grain refinement behavior of copper alloys cast in permanent molds was investigated. This is one of the least studied subjects in copper alloy castings. Grain refinement is not widely practiced for leaded copper alloys cast in sand molds. Aluminum bronzes and high strength yellow brasses, cast in sand and permanent molds, were usually fine grained due to the presence of more than 2% iron. Grain refinement of the most common permanent mold casting alloys, leaded yellow brass and its lead-free replacement EnviroBrass III, is not universally accepted due to the perceived problem of hard spots in finished castings and for the same reason these alloys contain very low amounts of iron. The yellow brasses and Cu-Si alloys are gaining popularity in North America due to their low lead content and amenability for permanent mold casting. These alloys are prone to hot tearing in permanent mold casting. Grain refinement is one of the solutions for reducing this problem. However, to use this ...
2004-04-29
Energy Technology Data Exchange (ETDEWEB)
The RECH-1 MTR reactor has been converted from HEU to MEU (45% enrichment) and the decision to a LEU (20% enrichment) conversion was taken some years ago. This LEU conversion decision involved a local fuel development and fabrication based on U{sub 3}Si{sub 2}-Al dispersion fuel, and a fabrication qualification stage that resulted in four fuel elements fully complying with established fabrication standards for this type of fuel. This report-presents relevant points of these four leaders fuel elements fabrication, in particular a fuel plate core homogeneity control development. A summary of the intended in core follow-up studies for the leaders fuel elements is also presented here. (author)
1999-07-01
Energy Technology Data Exchange (ETDEWEB)
Fuel elements used in the ORR whole-core LEU fuel demonstration have been gamma-scanned to determine axial distributions of UZLa and TXCs fission product activities. This data has been analyzed to determine cycle-averaged fuel element powers, residual STVU masses, and burnups of discharged fuel elements. Methods used to analyze the data are discussed and results are presented for the LEU fuel elements. Measured and calculates fuel element powers agree to within 5%, residual STVU masses to within 2%, and burnups to within 3%. These results are somewhat preliminary and await improved burnup calculations and independent calibration data to be based on the destructive analyses of a number of irradiated fuel elements. 4 refs., 7 figs., 3 tabs.
1988-01-01
Corrosion failure and its prevention in light water reactor power plants
Energy Technology Data Exchange (ETDEWEB)
During 17 years since the start of operation of the first commercial LWR in Japan, many LWRs have experienced various corrosion damages, but the causes of them were clarified, and the counter-measures were executed effectively in actual plants, as the results, the cause of corrosion damage decreased remarkably, and now, the high rate of operation has become to be maintained. In this paper, the major cases of corrosion damage experienced in LWRs in Japan and foreign countries, the causes of them and the countermeasures, the problems of hereafter and so on are described. The corrosion damage of metallic materials in the environment of LWRs occurs in the parts in contact with high temperature, high pressure water and steam, such as stainless steel piping in the primary cooling system of BWRs, and nickel alloy heating tubes of steam generators, carbon steel feed water piping and zirconium alloy fuel cladding tubes in PWRs. Recently, accompanying ...
1988-01-01
Corrosion failure and its prevention in light water reactor power plants
International Nuclear Information System (INIS)
During 17 years since the start of operation of the first commercial LWR in Japan, many LWRs have experienced various corrosion damages, but the causes of them were clarified, and the counter-measures were executed effectively in actual plants, as the results, the cause of corrosion damage decreased remarkably, and now, the high rate of operation has become to be maintained. In this paper, the major cases of corrosion damage experienced in LWRs in Japan and foreign countries, the causes of them and the countermeasures, the problems of hereafter and so on are described. The corrosion damage of metallic materials in the environment of LWRs occurs in the parts in contact with high temperature, high pressure water and steam, such as stainless steel piping in the primary cooling system of BWRs, and nickel alloy heating tubes of steam generators, carbon steel feed water piping and zirconium alloy fuel cladding tubes in PWRs. Recently, accompanying ...
Spent Fuel Background Report Volume I
Energy Technology Data Exchange (ETDEWEB)
This report is an overview of current spent nuclear fuel management in the DOE complex. Sources of information include published literature, internal DOE documents, interviews with site personnel, and information provided by individual sites. Much of the specific information on facilities and fuels was provided by the DOE sites in response to the questionnaire for data for spent fuels and facilities data bases. This information is as accurate as is currently available, but is subject to revision pending results of further data calls. Spent fuel is broadly classified into three categories: (a) production fuels, (b) special fuels, and (c) naval fuels. Production fuels, comprising about 80% of the total inventory, are those used at Hanford and Savannah River to produce nuclear materials for defense. ...
1994-03-01
Fast reactor fuel pin performance requirements for off-normal events
International Nuclear Information System (INIS)
HEDL is conducting an experimental transient testing program to evaluate the performance of prototypic Fast Flux Test Facility (FFTF) fuel pins up to the cladding integrity limit. The relationship is described of the HEDL/TREAT transient overpower test program to the confirmation of FFTF fuel pin design bases via the FFTF fuel pin design procedure.
Energy Technology Data Exchange (ETDEWEB)
This fact sheet describes NREL's accomplishments in accurately modeling costs for fuel cell-based combined heat, hydrogen, and power systems. Work was performed by NREL's Hydrogen Technologies and Systems Center.
2010-11-01
CANFLEX-NU fuel licensing status and issues in Korea
International Nuclear Information System (INIS)
The CANFLEX-NU Fuel Design Report (FDR) for Wolsung 1,2,3,4 was submitted for licensing review in July 1996. The FDR contains sections of fuel rod design, fuel bundle design, nuclear design and thermal-hydraulic design. Each section describes the design bases, design methodology and design evaluation results showing that the design bases are met. The CANFLEX-NU fuel design is not finalized yet in Korean licensing point of view. For example, among others, new Xc-BL correlation is needed to be developed, fuel rod gap reduction effect is to be considered in the Critical Heat Flux, more information for power ramp defect of fuel rod especially in the end-cap weld region is needed in the fuel rod design, and enough data are not available in irradiated conditions in the fuel rod and ...
1999-09-26
International Nuclear Information System (INIS)
This paper presents a new methodology to create realistic 3D microstructures of polycrystals. The virtual microstructures are based on statistical data describing the morphological and crystallographic textures of a sample, obtained from an EBSD analysis. In addition, the methodology can reproduce the observed surface on top of the simulated microstructure. This feature allows finite element calculations on these virtual aggregates to be compared to experimental results of mechanical tests. Such a comparison leads to the identification of the mechanical parameters of constitutive laws, such as critical resolved shear stress and strain hardening, using an optimization algorithm. Two materials were simulated in this study: TiAl and grade 702 zirconium. The first one presents twins inside the microstructure and the second one has an anisotropic texture. Based on 2D simulations, the important parameters necessary to describe a ...
International Nuclear Information System (INIS)
The DOE is conducting a comprehensive technical analysis of a flexible-fuel transportation system in the United States -- that is, a system that could easily switch between petroleum and another fuel, depending on price and availability. The DOE Alternative Fuels Assessment is aimed directly at questions of energy security and fuel availability, but covers a wide range of issues. This report examines environmental, health, and safety concerns associated with a switch to alternative- and flexible-fuel vehicles. Three potential alternatives to oil-based fuels in the transportation sector are considered: methanol, compressed natural gas (CNG), and electricity. The objective is to describe and discuss qualitatively potential environmental, health, and safety issues that would accompany widespread use of these three fuels. ...
2004-06-07
A sensitivity study on neutronic properties of DUPIC fuel
Energy Technology Data Exchange (ETDEWEB)
A sensitivity study has been done to determine the composition of DUPIC fuel from the viewpoint of neutronics fuel design. The spent PWR fuel compositions were generated and fissile contents adjusted by blending fresh uranium after mixing two spent PWR fuel assemblies. The {sup 239}Pu and {sup 235}U enrichments of DUPIC fuel were adjusted by controlling the amount of fresh uranium feed and the ratio of slightly enriched and depleted uranium in the feed uranium. Based on the material balance calculation, it is recommended that DUPIC fuel composition be such that spent PWR fuel utilization is more than 90%. A sensitivity study on the temperature reactivity coefficient of DUPIC fuel and shown that it is desirable to increase the {sup 239}Pu and {sup 235}U contents to reduce both the ...
1998-12-31
Evaluation of codisposal viability of MOX (FFTF) DOE-owned fuel: Phase 1 -- Intact mode calculations
Energy Technology Data Exchange (ETDEWEB)
The authors provide the intact criticality information that supports the disposal of spent nuclear fuel (SNF) from the US Department of Energy's (DOE's) Fast Flux Test Facility (FFTF) in the potential Monitored Geologic Repository at Yucca Mountain. FFTF is one of more than 250 forms of DOE-owned SNF. Because of the variety of the DOE SNF, the National Spent Nuclear Fuel Program has designated nine representative fuel groups for disposal criticality analyses based on fuel matrix, primary fissile isotope, and enrichment. The FFTF fuel is representative of the mixed-oxide fuel (MOX) group.
1999-07-01
Development of PC 4 dual-fuel engine
Energy Technology Data Exchange (ETDEWEB)
Recently, utilization of natural gas, which is considered to be one of most important alternative fuels for petroleum, has been marked. As thermal efficiency of dual-fuel engine is higher than those of other prime movers with gaseous fuel, i.e., spark-ignited gas engine or gas turbine, it is possible to construct fuel-economical gas power plants with dual-fuel engines. However, its horsepower has been limited to the rather lower range. In 1984, NKK succeeded in developing large-sized dual-fuel engines based on the Pielstick PC4 diesel engine. The horsepower is 1200 HP/cyl, i.e. 21,600 HP for 18-cyclinder engine.
1985-01-01
Tracing of salicylic acid additive during precipitation of zirconium
International Nuclear Information System (INIS)
This paper presents the results of experimental study carried out to know whether the salicylic acid used as an additive during the precipitation of zirconium using ammonium hydroxide solution goes into the filtrate, remains in the hydrated zirconia or gets distributed between the both under the ambient conditions of precipitation. Keeping its simplicity and amenability to adopt on a routine basis, spectrophotometric method has been chosen for the purpose among the many methods available and the problems associated in determining salicylic acid in the presence of zirconium and the medial measures to circumvent the same have been brought out in detail. (author)
2011-02-22
Pitting corrosion of zirconium and hafnium
Energy Technology Data Exchange (ETDEWEB)
The initiation and inhibition of pitting corrosion on zirconium and hafnium in aqueous solutions have been investigated by potentiodynamic, potentiostatic and galvanostatic measurements at 25/sup 0/C. Effects of Cl/sup -/, Br/sup -/and I/sup -/ have been examined over a range of salt concentrations and pH. All three halide ions cause pitting attack on the two metals, but this may be inhibited by other anions. The results show that hafnium is more easily protected against pitting than is zirconium. The data are treated by the Butler-Volmer equation to yield more information about the mechanisms of the pitting corrosion.
1988-02-01
The emphasis of combustion research efforts at NASA Glenn Research Center (GRC) is on collaborating
2000-01-01
International Nuclear Information System (INIS)
... structure crystal-phase transformations fluorescence fluorescence spectroscopy
2011-02-22
Energy Technology Data Exchange (ETDEWEB)
The US National Energy Policy of 2001 advocated the development of advanced fuel and fuel cycle technologies that are cleaner, more efficient, less waste-intensive, and more proliferation resistant. The need for advanced fuel development is emphasized in on-going DOE-supported programs, e.g., Global Nuclear Energy Initiative (GNEI), Advanced Fuel Cycle Initiative (AFCI), and GEN-IV Technology Development. The Directorates of Energy & Environment (E&E) and Chemistry & Material Sciences (C&MS) at Lawrence Livermore National Laboratory (LLNL) are interested in advanced fuel research and manufacturing using its multi-disciplinary capability and facilities to support a design concept of a small, secure, transportable, and autonomous reactor (SSTAR). The E&E and C&MS Directorates co-sponsored this Laboratory Directed Research & Development ...
2006-02-09
International Nuclear Information System (INIS)
The Joint Convention on the Safety of Spent Fuel management and on the Safety of Radioactive Waste Management is the first legal instrument to directly address the safety of spent fuel and radioactive waste management on a global scale. The Joint Convention entered into force in 2001. This paper describes its process and its main achievements to date. The perspectives to establish of a Global Waste Safety Regime based on the Joint Convention are also discussed. (authors)
A nuclear engine design with {sup 242m}Am as a nuclear fuel
Energy Technology Data Exchange (ETDEWEB)
A preliminary design for a nuclear engine is presented. The engine is based on the nuclear heating of a gas composed of H{sub 2} and {sup 242m}Am as a nuclear fuel. This engine has an initial volume of 0.135 m{sup 3} and at 64 MPa the critical mass is 0.228 kg. The simplicity {sup 242m}Am of the engine design might compensate for the use of rare nuclear fuel, such as {sup 242m}Am.
2000-01-01
Role of the diffuse layer in acidic and alkaline fuel cells
British Library Electronic Table of Contents (United Kingdom)
A numerical model is developed to study electrolyte dependent kinetics in fuel cells. The model is based on the Poisson-Nernst-Planck (PNP) and generalized-Frumkin-Butler-Volmer (gFBV) equations, and is used to understand how the diffuse layer and ionic transport play a role in the performance difference between acidic and alkaline systems. The laminar flow fuel cell (LFFC) is used as the model fuel cell architecture to allow for the appropriate comparison of equivalent acidic and alkaline systems. We study the overall cell performance and individual electrode polarizations of acidic and alkaline fuel cells for both balanced and unbalanced electrode kinetics as well as in the presence of transport limitations. The results predict cell behavior based on electrolyte composition that strongly...
2011-01-01
British Library Electronic Table of Contents (United Kingdom)
A highly efficient integrated energy conversion system is built based on a methane catalytic decomposition reactor (MCDR) together with a direct carbon fuel cell (DCFC) and an internal reforming solid oxide fuel cell (IRSOFC). In the MCDR, methane is decomposed to pure carbon and hydrogen. Carbon is used as the fuel of DCFC to generate power and produce pure carbon dioxide. The hydrogen and unconverted methane are used as the fuel in the IRSOFC. A gas turbine cycle is also used to produce more power output from the thermal energy generated in the IRSOFC. The output performance and efficiency of both the DCFC and IRSOFC are investigated and compared by development of exact models of them. It is found that this system has a unique loading flexibility due to the good high-loading property of ...
2010-01-01
Diesel-fueled solid oxide fuel cell auxiliary power units for heavy-duty vehicles
Energy Technology Data Exchange (ETDEWEB)
This paper explores the potential of solid oxide fuel cells (SOFCS) as 3--10 kW auxiliary power units for trucks and military vehicles operating on diesel fuel. It discusses the requirements and specifications for such units, and the advantages, challenges, and development issues for SOFCS used in this application. Based on system design and analysis, such systems should achieve efficiencies approaching 40% (lower heating value), with a relatively simple system configuration. The major components of such a system are the fuel cell stack, a catalytic autothermal reformer, and a spent gas burner/air preheater. Building an SOFC-based auxiliary power unit is not straightforward, however, and the tasks needed to develop a 3--10 kW brassboard demonstration unit are outlined.
2000-05-15
Solid fuels in chemical-looping combustion using a NiO-based oxygen carrier
Energy Technology Data Exchange (ETDEWEB)
The feasibility of using three different solid fuels in chemical-looping combustion (CLC) has been investigated using NiO as oxygen carrier. A laboratory fluidized-bed reactor system for solid fuel was used, simulating a chemical-looping combustion system by exposing the sample to alternating reducing and oxidizing conditions. In each reducing phase 0.2g of fuel was added to the reactor containing 20g oxygen carrier. The experiments were performed at 970{sup o}C. Compared to previously published results with other oxygen carriers the reactivity of the used Ni-particles was considerably lower for the high-sulphur fuel and higher for the low-sulphur fuel. Much more unconverted CO was released and the fuel conversion was much slower for high-sulphur fuel such as petroleum coke, suggesting that the nickel-based oxygen ...
2009-11-15
Monte-Carlo-based simulation of LWR cores with innovative fuel concepts
International Nuclear Information System (INIS)
High resolution Monte-Carlo simulations show that the neutron spectrum, fuel burnup and fuel temperature feedback effect of a PWR core loaded with Thoria-based fuel (Th/Pu-O_2) do not significantly differ from the MOX fuelled one due to the similar neutronic characteristics of both fertile materials (Th-232, U-238). The core physics of this fuel variant is characterized by an enhanced moderator/void temperature coefficient (by factor 2.4) and high incineration rate for Pu (approx. 60 %). A PWR core loaded with the Molybdenum-based inert matrix fuel (IMF) - in contrast to MOX-, shows a harder spectrum, resulting in small temperature coefficients of reactivity and particularly in a higher fuel depletion rate as well as an enhanced TRU reduction performance. The incineration of Pu amounts to 46 % resulting, in turn, in ...
2009-05-03
Energy Technology Data Exchange (ETDEWEB)
This study presents results from Monte Carlo radiation transport calculations aimed at characterizing a novel methodology being developed to detect partial defects in Pressurized Water Reactor (PWR) spent fuel assemblies (SFAs). The methodology uses a combination of measured neutron and gamma fields inside a spent fuel assembly in an in-situ condition where no movement of the fuel assembly is required. Previous studies performed on single isolated assemblies resulted in a unique base signature that would change when some of the fuel in the assembly is replaced with dummy fuel. These studies indicate that this signature is still valid in the in-situ condition enhancing the prospect of building a practical tool, Partial Defect Detector (PDET), which can be used in the field for partial defect detection.
2008-04-28
Fuel management study for 0.9% CANFLEX-SEU in Wolsung-1
International Nuclear Information System (INIS)
Fuel management simulations have been performed for 0.9% SEU CANFLEX fuel in the Wolsung-1. Based on earlier studies at AECL, the bi-directional, four-bundle-shift fuelling scheme was assumed. Time-averaged simulations resulted in an average discharge burnup of 13.0 MWd/kgU. The derived pin power envelope indicated that the peak linear element rating with CANFLEX fuel is 15% less than that obtained with 0.9% SEU 37-element fuel and there is little power boosting at high burnups. Calculated worths of the reactivity devices are sufficient to provide the control and safety requirements for CANFLEX 0.9% SEU fuel in the Wolsung-1 reactor. (Author).
1993-05-01
A new method for adiabatic flame temperature estimations of hydrocarbon fuels
Energy Technology Data Exchange (ETDEWEB)
This paper presents the application of artificial neural networks to adiabatic flame temperature prediction of hydrocarbon fuels. The investigation was conducted over a wide range of operating conditions in terms of fuel composition, pressure and temperature of reactants, fuel-air equivalence ratio and fuel vapour fraction. Several neural network models for predicting the flame temperature for different applicable fuel ranges were built and examined. The proper preparation of network training data and the appropriate choice of network parameters for achieving better prediction accuracy are discussed. The neural network prediction results were compared with those calculated by a thermodynamic and chemical equilibrium-based computer code - the NASA program CET89. It was shown that trained neural network models can provide the adiabatic flame temperature prediction ...
1999-03-01
Nuclear fuels and their use in atomic reactors: uranium
International Nuclear Information System (INIS)
The reactor fuel cycle based on uranium is described. The various stages in the cycle include mining of uranium ores followed by crushing and grinding, leaching and purification of leach liquor by ion exchange resin process or solvent extraction process, refining of uranium concentrate (yellow cake) by digesting with HNO_3 and then solvent extracting uranyl nitrate with TBP, conversion of uranyl nitrate to uranium hexafluoride, production of uranium metal, uranium enrichment, fabrication of reactor fuel elements and reprocessing of the spent fuel. Chemical reactions wherever they are involved are explained. (M.G.B.).
1978-01-01
A study on compressed biogas and its application to the compression ignition dual-fuel engine
Energy Technology Data Exchange (ETDEWEB)
This paper is based on research on the combustion ignition dual-fuel engine conducted at the Zhejiang Agricultural University. The properties of compressed biogas, its performance characteristics in the compression ignited dual-fuel engine as well as the possibilities and needs for its use are discussed. Using information derived from experimental data compiled by the laboratory, analyses and comparisons have been made between high- and low-pressure biogas used in the compression ignition dual-fuel engine with respect to variation of power and the corresponding characteristic curve of the engine. The economic effects of utilizing compressed biogas are also discussed. (author).
1989-01-01
Energy Technology Data Exchange (ETDEWEB)
Using the PMR method the interaction of zirconium and hafnium tetrachlorides with tri.tet.butylphenyl ester of 1,2- naphthoquinonediazide (2)-5-sulfonic acid is studied. The formation of MCl/sub 4/xNQD complexes is established, the equilibrium constants and thermodynamic parameters of complexing reaction are determined. The presence of rapid ligand exchange, proceeding according to associative mechanism, is detected. The rate constants and activation energies of the exchange reaction are calculated.
1981-11-01
International Nuclear Information System (INIS)
Using the PMR method the interaction of zirconium and hafnium tetrachlorides with tri.tet.butylphenyl ester of 1,2- naphthoquinonediazide (2)-5-sulfonic acid is studied. The formation of MCl_4xNQD complexes is established, the equilibrium constants and thermodynamic parameters of complexing reaction are determined. The presence of rapid ligand exchange, proceeding according to associative mechanism, is detected. The rate constants and activation energies of the exchange reaction are calculated.
International Nuclear Information System (INIS)
A method has been developed for the adsorption of Sc"I"I"I employing inorganic ion exchanger zirconium phosphosilicate by batch method. Effects of various parameters have been evaluated on the percentage adsorption of Sc"I"I"I. Separation of Sc"I"I"I from various other elements is standardized. (author)
1998-03-01
Energy Technology Data Exchange (ETDEWEB)
The kinetics of the reaction of zirconium phosphates with carbon tetrachloride in sodium and potassium chloride melt as well as the effect of temperature, gas flow, solubility and weight of the solid phase of the phosphate, and stirring of the melt on the chlorination rate has been studied. The kinetic parameters of the reaction (rate constants, activation energy, etc.) have been calculated.
1987-07-01
Analysis of titanium and zirconium in red mud with energy dispersive x-ray spectrometry
Energy Technology Data Exchange (ETDEWEB)
An energy dispersive x-ray fluorescence technique was used for the determination of Titanium (Ti) and Zirconium (Zr) in red mud by using a standard addition method. An annular {sup 241}Am source is employed for excitation of K shells of elements. 13 refs., 2 figs., 1 tab.
1996-11-01
A technical review is presented of experiment activities and state of knowledge on air-borne, radiation source terms resulting from explosive sabotage attacks on spent reactor fuel subassemblies in shielded casks. Current assumptions about the behavior of irradiated fuel are largely based on a limited number of experimental results involving unirradiated, depleted uranium dioxide ''surrogate'' fuel. The behavior of irradiated nuclear fuel subjected to explosive conditions could be different from the behavior of the surrogate fuel, depending on the assumptions made by the evaluator. Available data indicate that these potential differences could result in errors, and possible orders-of-magnitude overestimates of aerosol dispersion and potential health effects from sabotage attacks. Furthermore, it is suggested that the current ...
2002-04-01
Spent Fuel Transfer to Dry Storage Using Unattended Monitoring System
Energy Technology Data Exchange (ETDEWEB)
There are 4 CANDU reactors at Wolsung site together with a spent fuel dry storage associated with unit 1. These CANDU reactors, classified as On-Load Reactor (OLR) for Safeguards application, change 16- 24 fuel bundles with fresh fuel in everyday. Especially, the spent fuel bundles are transferred from spent fuel bays to dry storage throughout a year because of the insufficient capacity of spent fuel pond. Safeguards inspectors verify the spent fuel transfer to meet safeguards purposes according to the safeguards criteria by means of inspector's presence during the transfer campaign. For the verification, 60-80 person-days of inspection (PDIs) are needed during approximately 3 months for each unit. In order to reduce the inspection effort and operators' burden, an Unattended Monitoring System (UMS) was designed and ...
2009-05-15
Development of PHWR fuel fabrication in Korea
Energy Technology Data Exchange (ETDEWEB)
Korea Advanced Energy Research Institute (KAERI) started a research project to develop the PHWR (CANDU) nuclear fuel fabrication technology in 1981. Based on the results of the intensive developmental work, several prototype fuel bundles were fabricated and tested in the Hot Test Loop at KAERI continuously in 1983 and 1984. After that, irradiation test and post-irradiation examination were carried out for two KAERI-made fuel bundles at Chalk River Nuclear Laboratories in Canada in 1984. Since the results of in-pile and out-of-pile tests with prototype fuel bundles proved to be satisfactory, 48 additional fuel bundles were loaded in Wolsung reactor (CANDU) in 1984 and 1985, and all of them were discharged without a defect after excellent performance in the power reactor. In 1985, the Korean government decided that KAERI supplies all the fuel ...
1988-01-01
International Nuclear Information System (INIS)
The objective of this report was to evaluate four possible alternative methods of preparing and packaging spent fuel assemblies for geologic disposal against the Reference Process of unmodified spent fuel. The four alternative processes were: (1) End fitting removal, (2) Fission gas venting and resealing, (3) Fuel bundle disassembly and close packing of fuel pins, and (4) Fuel shearing and immobilization. Systems analysis was used to develop a basis of comparison of the alternatives. Conceptual processes and facility layouts were devised for each of the alternatives, based on technology deemed feasible for the purpose. Assessments were made of 15 principal attributes from the technical, operational, safety/risk, and economic considerations related to each of the alternatives, including both the surface packaging and underground repository operations. Specific ...
An evaluation of the alternative transport fuel policies for Turkey
Energy Technology Data Exchange (ETDEWEB)
The search for alternative fuels and new fuel resources is a top priority for Turkey, as is the case in the majority of countries throughout the world. The fuel policies pursued by governmental or civil authorities are of key importance in the success of alternative fuel use, especially for widespread and efficient use. Following the 1973 petroleum crisis, many users in Turkey, especially in transportation sector, searched for alternative fuels and forms of transportation. Gasoline engines were replaced with diesel engines between the mid-1970s and mid-1980s. In addition, natural gas was introduced to the Turkish market for heating in the early 1990s. Liquid petroleum gas was put into use in the mid-1990s, and bio-diesel was introduced into the market for transportation in 2003. However, after long periods of indifference governmental action, guidance and fuel ...
2010-06-15
Energy Technology Data Exchange (ETDEWEB)
Pt-based ternary catalysts have been proposed as electrode materials for low temperature fuel cells. Pt-Ru-based ternary catalysts were tested as anode materials with improved CO tolerance or enhanced activity for methanol or ethanol oxidation. Ternary catalysts based on platinum alloyed with first row transition metals were tested as cathode materials with improved activity for the oxygen reduction. This paper presents an overview of the preparation methods and structural characteristics of these ternary catalysts. (author)
2007-07-31
Energy Technology Data Exchange (ETDEWEB)
Substantial roles of precipitates such as Zr-Fe-Cr type intermetallic compounds on uniform corrosion and hydrogen pickup of zirconium alloys in pure water autoclave tests were investigated from an electrochemical point of view. This paper describes the roles on corrosion. A corrosion test on precipitate-containing and precipitate-free materials made from pure zirconium and a small quantity of iron and chromium, rest potential measurements on an intermetallic compound of Zr(FeCr){sub 2} and zirconium matrix, and a galvanic coupling test of those were performed. Results showed that corrosion behavior of zirconium alloys could be attributed to the electrochemical properties of intermetallic compounds precipitated in each alloy. Namely, the cathodic and anodic polarization characteristics were associated with anodic protection provided by the precipitates on the alloys and the precipitates degradation in ...
2000-07-01
International Nuclear Information System (INIS)
Substantial roles of precipitates such as Zr-Fe-Cr type intermetallic compounds on uniform corrosion and hydrogen pickup of zirconium alloys in pure water autoclave tests were investigated from an electrochemical point of view. This paper describes the roles on corrosion. A corrosion test on precipitate-containing and precipitate-free materials made from pure zirconium and a small quantity of iron and chromium, rest potential measurements on an intermetallic compound of Zr(FeCr)_2 and zirconium matrix, and a galvanic coupling test of those were performed. Results showed that corrosion behavior of zirconium alloys could be attributed to the electrochemical properties of intermetallic compounds precipitated in each alloy. Namely, the cathodic and anodic polarization characteristics were associated with anodic protection provided by the precipitates on the alloys and the precipitates degradation in the ...
2000-07-01
A NEM diffusion code for fuel management and time average core calculation
International Nuclear Information System (INIS)
A computer code based on Nodal expansion method has been developed for solving two groups three dimensional diffusion equation. This code can be used for fuel management and time average core calculation. Explicit Xenon and fuel temperature estimation are also incorporated in this code. TAPP-4 phase-B physics experimental results were analyzed using this code and a code based on FD method. This paper gives the comparison of the observed data and the results obtained with this code and FD code. (author)
2005-11-01
Advanced thermally stable jet fuels: Technical progress report, October 1994--December 1994
There are five tasks within this project on thermally stable coal-based jet fuels. Progress on each of the tasks is described. Task 1, Investigation of the quantitative degradation chemistry of fuels, has 5 subtasks which are described: Literature review on thermal stability of jet fuels; Pyrolytic and catalytic reactions of potential endothermic fuels: cis- and trans-decalin; Use of site specific {sup 13}C-labeling to examine the thermal stressing of 1-phenylhexane: A case study for the determination of reaction kinetics in complex fuel mixtures versus model compound studies; Estimation of critical temperatures of jet fuels; and Surface effects on deposit formation in a flow reactor system. Under Task 2, Investigation of incipient deposition, the subtask reported is Uncertainty analysis on growth and deposition of particles during heating ...
1995-02-01
TRIGA spent fuel bundles safe storage
International Nuclear Information System (INIS)
TRIGA-SSR is a steady state research and material test reactor that has been in operation since 1980. The original TRIGA fuel was HEU (highly enriched uranium) with a U"2"3"5 enrichment of 93 per cent. Almost all TRIGA HEU fuel bundles are now burned-up. Part of the spent fuel was loaded and transferred to US, in a Romania - DOE arrangement. The rest of the TRIGA fuel bundles have to be temporarily stored in the TRIGA facility. As the storage conditions had to be established with caution, neutron and thermal hydraulic evaluations of the storage conditions were required. Some criticality evaluations were made based on the SAR (Safety Analysis Report) data. Fuel constant axial temperature approximation effect is usual for criticality computations. TRIGA-SSR fuel bundle geometry and materials model for SCALE5-CSAS module allows the introduction ...
2007-05-13
International Nuclear Information System (INIS)
This paper examines the attractiveness of material mixtures containing special nuclear materials (SNM) associated with reprocessing and the thorium-based LWR fuel cycle. This paper expands upon the results from earlier studies that examined the attractiveness of SNM associated with the reprocessing of spent light water reactor (LWR) fuel by various reprocessing schemes and the recycle of plutonium as a mixed oxide (MOX) fuel in LWR. This study shows that "2"3"3U that is produced in thorium-based fuel cycles is very attractive for weapons use. Consistent with other studies, these results also show that all fuel cycles examined to date need to be rigorously safeguarded and provided moderate to high levels of physical protection. These studies were performed at the request of the United States Department of Energy (DOE), and are ...
Advanced fuel fabrication for Indian nuclear power programme
International Nuclear Information System (INIS)
Indian Nuclear Power Programme is based on closed nuclear fuel cycle for efficient utilization of its nuclear resources. This strategy also enables waste classification and gives an elegant solution to long-lived waste disposal problem. The three stage nuclear programme envisages mainly pressurized heavy water reactors in the first stage, fast breeder reactors in the second stage and thorium utilization in the third stage. Advanced Fuels in the context of this paper refer to Pu bearing fuels used or proposed to be used in our three stage programme. Fabrication of (U-Pu) Mixed Carbide fuel for FBTR is carried out at Radio Metallurgy Division at Trombay which has also an excellent Characterization facility required for development of all types of advanced Fuels. A (U-Pu) MOX fuel required for Proto-type Fast Breeder Reactor (PFBR-500 MWe) is ...
2010-10-01
Fuel processing equipment for fuel cell plant. Nenryo denchi plant no nenryo shori sochi
Energy Technology Data Exchange (ETDEWEB)
Activated charcoal which is the desulfurizing agent for the fuel cell plant can be used only at the normal temperature, and it must be placed upstream of the fuel gas, increasing the displacement flow of the fuel gas processed in the desulfurizer. In addition, a large quantity of activated charcoal must be filled or the frequency of its exchange must be increased because activated charcoal used at the normal temperature has little sulfur absorbing capacity. This invention is concerned with provision of a desulfurizer in the downstream of the fuel gas compressor of the fuel cell plant to remove sulfur content in the fuel gas by this desulfurizer. As a result, the displacement flow of the processing gas is decreased to increase the processing capacity of the desulfurizing agent. In addition, hydrogen recycling can be eliminated to realize compact arrangement of ...
1993-02-19
International Nuclear Information System (INIS)
Short-lived fission gas release from fuel pellets during irradiation was investigated based on the experimental results of the gas-flow rigs irradiated in the Halden Heavy Water Reactor (HBWR). The release-to-birth (R/B) rates of short-lived fission gas were measured by means of gas-flow measurement during the irradiation experiments. Surface-to-volume (S/V) ratios of fuel pellets and diffusion coefficients of short-lived fission gas release were evaluated from the obtained (R/B) values. The increase of (S/V) ratio agreed well with the point where the fuel temperature exceeded the threshold of 1% fission gas release. This indicates that the interlinkage of fission gas bubbles occurred there. The evaluated diffusion coefficients scattered in the range between 10"-"2"3 and 10"-"1"7 m"2/s, and the effects of fuel type (UO_2 or MOX) were not clearly observed. In addition, it is likely ...
2010-07-31
Specific consumption of liquid biofuels in gasoline fuelled engines
Energy Technology Data Exchange (ETDEWEB)
Oxygenated fuels increase fuel consumption due to their low enthalpy of combustion; however, their high antiknock index renders them suitable for use in engines with a high compression rate, increasing their thermal yield. This study evaluated the performance of biorenewable oxygenated fuels (ethanol and isoamyl alcohol) and partially renewable fuels (ETBE: ethyl tert-butyl ether, TAEE: tert-amyl ethyl ether and di-TAE: di-tert-amyl ether) with high degree of purity and in mixtures with automotive gasoline, based on tests with Otto cycle engines. Among the oxygenated fuels evaluated here, di-TAE was found to present the best characteristics of performance, both individually and in mixtures with gasoline. 40 refs., 5 figs., 2 tabs.
2008-11-15
Specific consumption of liquid biofuels in gasoline fuelled engines
British Library Electronic Table of Contents (United Kingdom)
Oxygenated fuels increase fuel consumption due to their low enthalpy of combustion; however, their high antiknock index renders them suitable for use in engines with a high compression rate, increasing their thermal yield. This study evaluated the performance of biorenewable oxygenated fuels (ethanol and isoamyl alcohol) and partially renewable fuels (ETBE: ethyl tert-butyl ether, TAEE: tert-amyl ethyl ether and di-TAE: di-tert-amyl ether) with high degree of purity and in mixtures with automotive gasoline, based on tests with Otto cycle engines. Among the oxygenated fuels evaluated here, di-TAE was found to present the best characteristics of performance, both individually and in mixtures with gasoline.
2008-01-01
HYFIRE: a tokamak- high-temperature electrolysis system
Energy Technology Data Exchange (ETDEWEB)
Brookhaven National Laboratory is involved in a conceptual design study of a commercial nuclear power system which utilizes high-temperature electrolysis to produce synthetic fuels. The system is called HYFIRE. It includes a tokamak fusion power reactor supplying electrical and thermal energy to an array of electrolytes. The electrolytes produce hydrogen which can be used either directly as a fuel or in the production of hydrocarbons. The purpose of the study is to provide a mechanism for DOE to further assess the commercial potential of fusion using a tokamak reactor to produce synthetic fuel. The HYFIRE design is based on the tokamak commercial power reactor, STARFIRE. STARFIRE uses the deuterium/tritium/lithium fuel cycle. The HYFIRE study assumes the plasma shape and characteristics of STARFIRE study but uses a different blanket design. This study is particularly interested in ...
1980-01-01
Fuel cost analysis of CANDU-PHWR Wolsung Nuclear Power Plant unit 1
International Nuclear Information System (INIS)
Being based on the Segal method, calculation was carried out for the natural uranium nuclear fuel cost with Zircaloy-4 cladding having design parameters of Wolsung Nuclear Power Plant, CANDU-PHWR (Unit 1), currently under construction in Korea aiming at its completion in 1982. An attempt was also made for the sensitivity analysis of each fuel component; i.e., depreciation of fuel manufacturing plant caused by its life time, its load factor, production scale expansion of plant facilities, variations of construction and operating costs of fuel manufacturing plant, fluctuation of interest rates, extent of uranium ore price increases and effect of learning factor. (author).
1977-01-01
Crude oil and finished fuel storage stability: An annotated review
Energy Technology Data Exchange (ETDEWEB)
A state-of-the-art review and assessment of storage effects on crude oil and product quality was undertaken through a literature search by computer accessing several data base sources. Pertinent citations from that literature search are tabulated for the years 1980 to the present. This 1990 revision supplements earlier reviews by Brinkman and others which covered stability publications through 1979 and an update in 1983 by Goetzinger and others that covered the period 1952--1982. For purposes of organization, citations are listed in the current revision chronologically starting with the earliest 1980 publications. The citations have also been divided according to primary subject matter. Consequently 11 sections appear including: alternate fuels, gasoline, distillate fuel, jet fuel, residual fuel, crude oil, biodegradation, analyses, reaction mechanisms, containment, and handling and ...
1991-01-01
Space reactor fuel element testing in upgraded TREAT
Energy Technology Data Exchange (ETDEWEB)
The testing of candidate fuel elements at prototypic operating conditions with respect to temperature, power density, hydrogen coolant flow rate, etc., a crucial component in the development and qualification of nuclear rocket engines based on the Particle Bed Reactor (PBR), NERVA-derivative, and other concepts. Such testing may be performed at existing reactors, or at new facilities. A scoping study has been performed to assess the feasibility of testing PBR based fuel elements at the TREAT reactor. initial results suggest that full-scale PBR, elements could be tested at an average energy deposition of {approximately}60--80 MW-s/L in the current TREAT reactor. If the TREAT reactor was upgraded to include fuel elements with a higher temperature limit, average energy deposition of {approximately}100 MW/L may be achievable.
1993-05-01
Energy Technology Data Exchange (ETDEWEB)
A methane catalytic decomposition reactor-direct carbon fuel cell-internal reforming solid oxide fuel cell (MCDR-DCFC-IRSOFC) energy system is highly efficient for converting the chemical energy of methane into electrical energy. A gas turbine cycle is also used to output more power from the thermal energy generated in the IRSOFC. In part I of this work, models of the fuel cells and the system are proposed and validated. In this part, exergy conservation analysis is carried out based on the developed electrochemical and thermodynamic models. The ratio of the exergy destruction of each unit is examined. The results show that the electrical exergy efficiency of 68.24% is achieved with the system. The possibility of further recovery of the waste heat is discussed and the combined power-heat exergy efficiency is over 80%. (author)
2010-10-01
British Library Electronic Table of Contents (United Kingdom)
A methane catalytic decomposition reactor-direct carbon fuel cell-internal reforming solid oxide fuel cell (MCDR-DCFC-IRSOFC) energy system is highly efficient for converting the chemical energy of methane into electrical energy. A gas turbine cycle is also used to output more power from the thermal energy generated in the IRSOFC. In part I of this work, models of the fuel cells and the system are proposed and validated. In this part, exergy conservation analysis is carried out based on the developed electrochemical and thermodynamic models. The ratio of the exergy destruction of each unit is examined. The results show that the electrical exergy efficiency of 68.24% is achieved with the system. The possibility of further recovery of the waste heat is discussed and the combined power-heat e...
2010-01-01
Energy Technology Data Exchange (ETDEWEB)
In recent years, interest in the development of a polymer electrolyte fuel cell (PEFC) has considerably increased due to its advantages (e.g., high power density) compared with other fuel cell systems, and its potentials to become the power plant for the next generation, nonpolluting automobile engine. For large scale application of fuel cells, low platinum loading electrode structures are necessary. An electrode based on a highly porous carbonized polyacrylonitrile foam material with very low platinum loading ({approximately} 13 {micro}g/cm{sup 2}) was prepared. The performance of this electrode for oxygen reduction was evaluated and compared with bulk platinum and glassy carbon electrodes.
1996-01-01
Energy Technology Data Exchange (ETDEWEB)
Consolidation of spent fuel is under active consideration as the US Department of Energy plans to dispose of spent fuel. During consolidation, the fuel pins are removed from an intact fuel assembly and repackaged into a more compact configuration. After repackaging, approximately 30 kg of residual spent fuel assembly hardware per assembly remains that is also radioactive and requires disposal. Understanding the nature of this secondary waste stream is critical to designing a system that will properly handle, package, store, and dispose of the waste. This report presents a methodology for estimating the radionuclide inventory in irradiated spent fuel hardware. Ratios are developed that allow the use of ORIGEN2 computer code calculations to be applied to regions that are outside the fueled region. The ratios are based on ...
1989-06-01
Long-term optimization of fuel loading pattern using genetic algorithms and simulated annealing
International Nuclear Information System (INIS)
This paper describes Automatic Refueling Planning System (ARPS) for a nuclear power station using Genetic Algorithms (GA) and a Simulated Annealing (SA). ARPS has been developed and verified by applying to the Fugen nuclear power station (NPS), which is a 165MWe, heavy water-moderated, boiling light water-cooled, pressure tube-type reactor developed by JNC utilizing mainly uranium and plutonium mixed oxide (MOX) fuel. Fuel loading patterns have been managed independently in the Fugen NPS since the initial core. A planning of an adequate fuel loading pattern on each operational cycle needs one to two months even for expert core management engineers, for the reason that it has multi-objective optimization and nonlinear problems. In order to achieve the optimum fuel loading pattern and a fuel cost reduction, ARPS has been developed by JNC and CRC Solutions Corporation for the last five ...
2003-04-20
Effects of irradiation on the microstructural evolution and corrosion resistance of zirconium alloys
International Nuclear Information System (INIS)
Zircaloy-2 and Zircaloy-4 tubing materials were irradiated with 1 MeV proton at 350 degrees C to doses of 0.01, 0.1, and 1 dpa respectively. Both microstructure examination and nodular corrosion test (500 degrees C, 1500 psi steam) were performed in order to understand the relationship between the microstructural evolution and the corrosion resistance of these alloys under irradiation. Neutron-irradiated Zircaloy-2 specimens which were obtained from a failed BWR fuel rod cladding were also studied. Specimens of three different neutron fluences were investigated; namely, 2.6x10"2"4, 3.2x10"2"5, 3.8x10"2"5, (E_n#>=#1MeV). The results indicated that the higher the irradiation dose the better the nodular corrosion resistance of both Zircaloy-2 and Zircaloy-4. It is concluded that irradiation-induced precipitate dissolution and irradiation-enhanced diffusion may increase the solute concentration in the matrix and make it distributed more evenly which in turn ...
1991-08-25
Multivariate statistics in the identification of unknown nuclear material
International Nuclear Information System (INIS)
The identification, and hence origin determination, of unknown nuclear material that might be found undeclared away from designated locations in the nuclear fuel cycle, is an important task in the frame of nuclear forensics. Material with forensic importance can be found at the microscopic level as particles in environmental samples indicating possible clandestine production of fissile material, and as bulky samples in the case of illicit trafficking of nuclear material. The objective of this work is to present, at a theoretical level, an isotopic finger-printing methodology which would determine the origin of unknown nuclear material with forensic importance. This is demonstrated for the case when the unknown nuclear material is spent nuclear fuel. The methodology is based on multivariate statistics, such as cluster and factor analysis, complemented by spent fuel isotopic composition simulations using ...
2004-10-25
Energy Technology Data Exchange (ETDEWEB)
A highly efficient integrated energy conversion system is built based on a methane catalytic decomposition reactor (MCDR) together with a direct carbon fuel cell (DCFC) and an internal reforming solid oxide fuel cell (IRSOFC). In the MCDR, methane is decomposed to pure carbon and hydrogen. Carbon is used as the fuel of DCFC to generate power and produce pure carbon dioxide. The hydrogen and unconverted methane are used as the fuel in the IRSOFC. A gas turbine cycle is also used to produce more power output from the thermal energy generated in the IRSOFC. The output performance and efficiency of both the DCFC and IRSOFC are investigated and compared by development of exact models of them. It is found that this system has a unique loading flexibility due to the good high-loading property of DCFC and the good low loading property of IRSOFC. The effects of temperature, pressure, current ...
2010-10-01
Effect of the fabrication process on fatigue performance of U3Si2 fuel plate with sandwich structure
U3Si2 Al fuel plate is one of the dispersion fuel structure materials recently developed and widely used in research reactors. The mechanical properties of this structural material, especially the fatigue performance, are strongly dependent on its fabrication process. To investigate the effects of these processing technologies, the fatigue tests for the different specimens were carried out. The S N curves indicate that the fabrication processing technologies of U3Si2 fuel plate, such as the addition of U3Si2 particles into aluminum powder to form the fuel meat, holding and rolling the processes of meat and cladding of 6061-Al alloy, plays an important role in improving the mechanical properties and fatigue performance of this fuel plate. In addition, some factors that influence the crack initiation and propagation are summarized based on the fatigue images that ...
2005-06-01
Novel Processing of Unique Ceramic-Based Nuclear Materials and Fuels
Energy Technology Data Exchange (ETDEWEB)
Advances in nuclear reactor technology and the use of gas-cooled fast reactors require the development of new materials that can operate at the higher temperatures expected in these systems. These include refractory alloys base on Nb, Zr, Ta, Mo, W, and Re; ceramics and composites such as those based on silicon carbide (SiCf-SiC); carbon-carbon composites; and advanced coatings. Besides the ability to handle higher expected temperatures, effective heat transfer between reactor componets is necessary for improved efficiency. Improving thermal conductivity of the materials used in nuclear fuels and other temperature critical components can lower the center-line fuel temperature and thereby enhance durability and reduce the risk of premature failure.
2008-11-30
The importance of vehicle costs, fuel prices, and fuel efficiency to HEV market success.
Energy Technology Data Exchange (ETDEWEB)
Toyota's introduction of a hybrid electric vehicle (HEV) named ''Prius'' in Japan and Honda's proposed introduction of an HEV in the United States have generated considerable interest in the long-term viability of such fuel-efficient vehicles. A performance and cost projection model developed entirely at Argonne National Laboratory (ANL) is used here to estimate costs. ANL staff developed fuel economy estimates by extending conventional vehicle (CV) modeling done primarily under the National Cooperative Highway Research Program. Together, these estimates are employed to analyze dollar costs vs. benefits of two of many possible HEV technologies. We project incremental costs and fuel savings for a Prius-type low-performance hybrid (14.3 seconds zero to 60 mph acceleration, 260 time) and a higher-performance ''mild'' hybrid vehicle, or ...
1999-12-08
{sup 242m}Am fueled nuclear battery
Energy Technology Data Exchange (ETDEWEB)
A nuclear battery based on the direct energy conversion of the fission products is presented. Such energy conversion is possible by using a nuclear reactor with ultra-thin fuel elements of 0.2 {mu}m of {sup 242m}Am. The amount of nuclear fuel is 376 g and the dimensions of the battery are 2.4x2.4x2.4 m{sup 3} (including the vacuum spacing), with a BeO moderator and Be electrodes. The total power of the reactor is 10.6 MW and the electrical power is 0.652 MW.
2004-10-01
Thermal-hydraulics performance optimization of Candu fuel using Assert subchannel code
Energy Technology Data Exchange (ETDEWEB)
An optimization of fuel bundle geometry using the subchannel code ASSERT is performed in support of Candu fuel design to enhance the thermohydraulics performance. The new bundle design is based on a reference CANFLEX bundle with changes to the centre and inner-ring element diameters and pitch-circle diameters (PCDs) of various element rings. Different methods of varying the PCDs for reaching the optimized geometry are considered in an attempt to minimize the optimization effort. The optimized geometry in the present analysis is the one that maximizes the dryout power and that has simultaneous CHF (critical heat flux) initiation involving more than one subchannel rings. (authors)
2007-07-01
Energy Technology Data Exchange (ETDEWEB)
This report is published in the framework of the 1991 French law for the nuclear waste management. The state of the art reported here concerns the long term evolution of spent fuel in the various environmental conditions corresponding to dry storage and geological disposal: closed system, air and water saturated medium. This review is based on the results of the french PRECCI project (Research Program on Long term Evolution of Spent Nuclear Fuel) and on literature data. (authors)
2005-03-15
R D for the storage, transport, and handling of coal-based fuels
Energy Technology Data Exchange (ETDEWEB)
The product of several advanced physical coal cleaning processes is a dry, ultrafine coal (DUC), in the order of 10 microns mean mass diameter. To utilize this fuel commercially, cost-effective, environmentally safe systems must be provided for the storage, transport, and handling of this finely divided form of fuel. The objective of the project described herein is the development of total logistics systems for DUC, including experimental verification of key features. The systems to be developed will provide for safe, economic, and environmentally protective storage and delivery of DUC for residential, commercial, and industrial uses. 20 figs.
1991-01-01
Energy Technology Data Exchange (ETDEWEB)
We developed the technology of using a waste plastic as fuel in the rotary kiln from reducing the fuel cost and recycling resource point of view. It has established based upon the research of a primary combustion characteristics on waste plastics, the research of the combustion mode of the fuel in the rotary kiln by simulation and the actual examination of kiln. The first rotary kiln equipped with the waste plastic injection system has been operating since 1994, and has achieved a good operating result. (author)
1999-03-01
Breached fuel location in FFTF by delayed neutron monitor triangulation
International Nuclear Information System (INIS)
The purpose of this work was to develop and evaluate a method of locating breached fuel within the Fast Flux Test Facility (FFTF) reactor based on the relative response of the delayed neutron monitors (DNM) located on each of the three primary sodium cooling loops. The primary method of location is the use of tag gas containing unique ratios of the noble gases xenon and krypton. Although the tag gas system works quite well, it is relatively expensive because of the costs of preparing and loading the gas into each fuel pin. Triangulation of DNM signals could potentially decrease tag gas costs while maintaining overall location reliability.
1985-11-10
Regeneration of CO poisoned PEM fuel cells by periodic pulsed oxidation
International Nuclear Information System (INIS)
CO poisoning is a major issue when reformate is used as a fuel in PEM fuel cells. Normally it is necessary to reduce the CO to very low levels (#approx#5 ppm) and CO tolerant catalysts, such as Pt-Ru, are often employed. As an alternative approach, we have studied the use of pulsed oxidation for the regeneration of CO poisoned cells. Results are presented for the regeneration of Pt and Pt-Ru anodes in a PEM fuel cell fed with CO concentrations as high as 10,000 ppm. The results show periodic removal of CO from the catalyst surface by pulsed oxidation can increase the average cell potential and increase overall efficiency. A method for enhancing the performance of a fuel cell stack using a microprocessor-based Fuel Cell Health Manager (FCHM) has been developed. The results of a cost/benefit analysis for the use of a FCHM on a 4 kW residential ...
2004-09-25
Control rod ejection accident analysis for the high burnup fuel in Daya Bay NPS
International Nuclear Information System (INIS)
A lot of recent experimental results show that cladding failure limits to the RCCA ejection accident will be changed because of the impact of the high irradiation on the fuel rod behavior in the reactor. The maximal assembly discharge burnup in Daya Bay unit 1 and 2 will reach up to 52 GMd/tU with 18 month fuel cycle. It is necessary to perform the specific RCCA ejection accident analysis for the high burnup fuel assembly in order to evaluate the maximal enthalpy in the fuel rods. There is no definite design limit of maximal enthalpy for high burnup assembly during the RCCA ejection accident. One could perform the rod ejection accident analysis for the high burnup assemblies and compare the analytical results with the specific experimental results. The RCCA ejection accident analysis for the high burnup assemblies for Daya Bay NPS has been performed based on the conventional ...
2004-10-04
International Nuclear Information System (INIS)
The applicability of the thermal response of an electrically heated simulated rod mostly used in loss-of-coolant-accident (LOCA) experiments to that of a nuclear fuel rod is a concern for the safety evaluation of a reactor. The present analysis describes the characteristics of the thermal response for both electrically heated and nuclear fuel rods during typical reflood conditions for a PWR-LOCA. A model describing the radial temperature field in the rod is developed based on the scheme in HETRAP code by Malang and incorporated into a reflood analysis code, REFLA for that purpose. The calculations applied to the existing reflood tests gave good agreement with experiments, showing the validity of the present model. The analysis has shown that the nuclear fuel rod tends to give a lower clad temperature and a sooner quench time than the electrically heated rod in a typical reflood condition, due to the ...
UK PubMed Central (United Kingdom)
The management of the interim phase of a complete oral rehabilitation in patients with severely worn dentition is often challenging due to the loss of occlusal vertical dimension, loss of tooth structure,...Full Text Available
2009-01-01
British Library Electronic Table of Contents (United Kingdom)
Zirconium and particularly Zr-2.5wt%Nb (Zr2.5Nb) alloy are useful for engineering bearing applications because they can be oxidized in air to form a hard surface ceramic. Oxidized zirconium (OxZr) due to its abrasion resistant ceramic surface and biocompatible substrate alloy has been used as a bearing surface in total joint arthroplasty for several years. OxZr is characterized by hard zirconium oxide (oxide) formed on Zr2.5Nb using one step thermal oxidation carried out in air. Because the oxide is only at the surface, the bulk material behaves like a metal, with high toughness. The oxide, furthermore, exhibits high adhesion to the substrate because of an oxygen-rich diffusion hardened zone (DHZ) interposing between the oxide and the substrate. In this study, we demonstrate a two step pro...
2011-01-01
Laser hardening of titanium-zirconium alloy
International Nuclear Information System (INIS)
The methods of surface modification of Ti-Zr alloy by laser treatment are considered. Characteristics of laser modification without- and with surface melting and with melting in different gaseous environments and with nickel microalloying are presented. Maximum depth, hardness and corrosion resistance are observed under nickel laser alloying.
Slide rings made of an SiC/silicide composite; Gleitringe aus einem SiC/Silicid-Verbundwerkstoff
Energy Technology Data Exchange (ETDEWEB)
The objective of the project was to develop an infiltration material based on SiC that should have improved corrosion resistance and should permit higher operating temperatures. From a variety of tested doping agents, zirconium silicide and molybdenum proved to be the most appropriate agents. The respective infiltration materials permit a combination of advantages of the SSiC with those of the SiSiC. Silicide SiC, analogous to the SiSiC, is almost nonshrinking, and above all is more corrosion-resistant than SiSiC in the alkaline regime, due to the replacement of free silicon by silicide phases. The operating temperature of the molybdenum-base variant is 1600 C. (orig./CB) [Deutsch] Ziel des Vorhabens war die Entwicklung eines Infiltrationswerkstoffes auf SiC-Basis mit verbesserter Korrosionsbestaendigkeit und hoeherer Einsatztemperatur. Aus einer Vielzahl von getesteten Dotierungsmoeglichkeiten kristallisierten sich ...
1997-12-31
Temperature coefficient in D_2O moderated reactor (Wolsung Unit 1)
International Nuclear Information System (INIS)
The temperature coefficient has been investigated on the Wolsung nuclear power reactor, in which fuel is natural uranium dioxide and moderator heavy water. The numerical computations are carried out in terms of changes of the effective neutron multiplication factor with respect to fuel, moderator, and coolant temperatures. Those results are compared with the computed values of temperature coefficient based on the LATREP computer code. (author).
1977-01-01
Energy Technology Data Exchange (ETDEWEB)
Research is presented on oil and gas technologies, advanced systems for fossil fuels, environmental technologies for remediation and waste management, applied energy science on heavy oil and plastics coprocessing, and fossil fuel and hydrocarbon conversion using hydrogen rich plasma.
1997-05-01
Power and ecological aspects of hydrogen and hydrogenous gas usage
International Nuclear Information System (INIS)
General trends of developing hydrogen power engineering and technology in Ukraine are considered. Based on a general level of power consumption and real opportunities for hydrogen production, a conclusion is derived that there are possibilities in the near future to partially replace conventional hydrocarbon fuels by hydrogen. Besides, developed technologies for burning hydrogenous gases and hydrogen-fuel systems when applied to transport installations allow one to improve essentially their power and ecological characteristics. 5 refs.
An outline of the fuelling machine electrical instrumentation and controls
International Nuclear Information System (INIS)
An outline of the instrumentation and control systems associated with fuelling machines is given. The control systems such as hydraulic system, oil hydraulic system, electric control system and the remote control systems have been discussed in detail. The difference between RAPP and MAPP fuel handling control systems has been explained. A computer based system for the Narora fuel handling control system is also discussed. (S.K.K.).
Twenty First Century Space Propulsion Study Addendum
... Fuels", Paper AIAA-91-2451, 27th AIAA/SAE/ASME ... to-surface ballistic missiles than space-based space-to ... an effective hit-to-kill weapon without the ...
1991-06-01
Energy Technology Data Exchange (ETDEWEB)
Based on changes to the fuel pin gas gap composition, pin location and assembly location, revisions to the TDD-IB, Part 2 are provided.
1989-07-14
million for advanced energy projects Thu, Sep 29, 2011 - Project Aims to Bring Bio-based Jet Fuel Production to the Northwest Mon, Sep 12, 2011 - Drive like the wind Thu, Aug 25,...
2011-10-09
Base program on energy-related research. Quarterly report, February 1995--April 1995
Energy Technology Data Exchange (ETDEWEB)
This report describes research performed by the Morgantown Energy Technology Center in the following areas: oil and gas; advanced systems describing a coal solid fuel and an eastern shale oil residue waste program; environmental remediation; and waste management technologies.
1995-06-01
Energy Technology Data Exchange (ETDEWEB)
Chemical looping combustion is a novel technology that can be used to meet the demand on energy production without CO{sub 2} emission. To improve CO{sub 2} capture efficiency in the process of chemical looping combustion of coal, a prototype configuration for chemical looping combustion of coal is made in this study. It comprises a fast fluidized bed as an air reactor, a cyclone, a spout-fluid bed as a fuel reactor and a loop-seal. The loop-seal connects the spout-fluid bed with the fast fluidized bed and is fluidized by steam to prevent the contamination of the flue gas between the two reactors. The performance of chemical looping combustion of coal is experimentally investigated with a NiO/Al{sub 2}O{sub 3} oxygen carrier in a 1 kW{sub th} prototype. The experimental results show that the configuration can minimize the amount of residual char entering into the air reactor from the fuel reactor with the external circulation of oxygen carrier ...
2010-05-15
Energy Technology Data Exchange (ETDEWEB)
This report presents an assessment of the potential energy savings that could accrue from the use of alternative fuels in future transportation engines. Alternative fuels are defined in this study as hydrocarbon fuels which possess characteristics that assure user safety and satisfaction, but require less energy to produce than conventional specification fuels produced from the same resource. In particular, the energy requirements for producing such fuels from domestic coal and oil shale resources are examined from the standpoint of their adaptability to engine types having a high potential for achieving significant efficiency gains over existing transportation engines. Incentives for specific types of engine development are identified in terms of energy savings above those obtainable with current specification fuels. While engine research and development ...
1985-08-01
The development of PHWR fuel fabrication in Korea
International Nuclear Information System (INIS)
Korea Advanced Energy Research Institute (KAERI) started a research project to develop the PHWR (CANDU) nuclear fuel fabrication technology in 1981. Based on the results of the intensive developmental work, several prototype fuel bundles were fabricated and tested in the Hot Test Loop at KAERI continuously in 1983 and 1984. After that, irradiation test and post-irrradiation examination were carried out for two KAERI-made fuel bundles at Chalk River Nuclear Laboratories in Canada in 1984. Since the results of in-pile and out-of-pile tests with prototype fuel bundles proved to be satisfactory, 48 additional fuel bundles were loaded in Wolsung reactor (CANDU) in 1984 and 1985, and all of them were discharged without a defect after excellent performance in the power reactor. In 1985, the Korean government decided that KAERI supplies all the fuel ...
1987-09-07
PNC`s proposal on the Advanced Fuel Recycle concept
Energy Technology Data Exchange (ETDEWEB)
MOX fuel for FBR is allowed to contain impurities within several thousand ppm, which means less than 1000 of decontamination factor (DF) in reprocessing is enough for Pu and U recycle use. The Advanced Fuel Recycle proposed by PNC is on this basis. The concept consists of innovations on both MOX fuel fabrication and aqueous reprocessing technologies based on the Purex process and it is believed that successful optimization of fuel cycle interface condition is the key issue to realize the concept. The lower DF such as 1000 can be easily obtained by the simplified Purex flowsheet which has no purification steps. However, new subject arises in MOX fuel fabrication, that is, fabrication is conducted in the shielding cell using equipment which is maintained remotely. A simplified fabrication technology becomes essential to establish the remote maintenance system and ...
1998-03-01
Interpretation of gamma-scanning data from the ORR demonstration elements
Energy Technology Data Exchange (ETDEWEB)
The HEU and LEU fuel elements used in the ORR whole-core demonstration were gamma-scanned to determine the axial distribution of the {sup 140}La and {sup 137}Cs activities. Analysis of this data is now complete. From the {sup 140}La activity distributions cycle-averaged powers were determined while the {sup 137}Cs data provided a measure of the final {sup 235}U burnup in the fuel elements. A method for calculating correction factors for activity gradients transverse to the fuel element axis is presented and is applied to the first mixed core used in the demonstration during the gradual transition to an all LEU core. Results based on the gamma-scanning of the LEU fuel followers are also presented. Improved burnup calculations against which the experimental results are to be compared are now in progress. 7 refs., 21 figs., 3 tabs.
1989-01-01
Independent power plant using wood waste
Energy Technology Data Exchange (ETDEWEB)
A 1 MWe power plant using waste wood fuel is to be installed at a US Marine Corps base, which will supply all wood from a landfill site. The core energy conversion technology is a down-draft gasifier supplying approximately 150 Btu/scf gas to both spark ignition and diesel dual-fuel engine-generator sets. Features of the plant design include: (1) grinding wood fuel from a wide range of waste resources, (2) specialized screening for fines removal, (3) complete tar and other waste product control without landfill disposal, and (4) use of process heat for bulk fuel drying, gasifier air pre-heating, and wastewater evaporation.
1995-08-01
Energy Technology Data Exchange (ETDEWEB)
Based on the air pollution values typical of brown coal furnaces the paper discusses pollution abatement measures on the part of fuel engineering and flue gas technology. Fuel engineering contributes to air pollution abatement by measures such as stepped air supply, stepped fuel supply and flue gas draw-in. Flue gas technology largely relies on measures such as the SCR method using different catalytic converters, the noncatalytic reduction of nitrogen oxides, the simultaneous separation of sulfur dioxides and nitrogen oxides, and the Denox-Luvo method. The paper concludes with remarks on the RWE brown coal power plant retrofitting scheme planning to have all power plants equipped with adequate denitrification systems until the end of 1989 at the latest. (orig./PW)
1987-05-01
British Library Electronic Table of Contents (United Kingdom)
Gas nitridation has shown excellent promise to form dense, electrically conductive and corrosion-resistant Cr-nitride surface layers on Ni-Cr base alloys for use as proton exchange membrane fuel cell (PEMFC) bipolar plates. Due to the high cost of nickel, Fe-base bipolar plate alloys are needed to meet the cost targets for many PEMFC applications. Unfortunately, nitridation of Fe-base stainless steel alloys typically leads to internal Cr-nitride precipitation rather than the desired protective surface nitride layer formation, due to the high permeability of nitrogen in these alloys. This paper reports the finding that it is possible to form a continuous, protective Cr-nitride (CrN and Cr2N) surface layer through nitridation of Fe-base stainless steel alloys. The key to form a protective Cr...
2007-01-01
Energy Technology Data Exchange (ETDEWEB)
This report for the Swiss Federal Office of Energy (SFOE) presents the overview reports made by SFOE Heads of Program on work done in 2007. Projects reported on in the natural gas-fired fuel cell area include the EU-project REAL-SFOC, the long-term testing of anode-supported SOFC stacks, intermediate-temperature fuel cells based on proton conducting electrolytes, the interdisciplinary ONEBAT project and lifetime-enhancement of SOFC stacks for CHP applications. In the polymer-electrolyte fuel cell (PEFC) area, projects concerning proton-conducting polymer membranes, factors limiting the lifetime of fuel cell membranes, a new highly active oxygen reduction electrode for PEM fuel cell and zinc/air battery applications, the enhancement of PEFC durability and reliability, model-based investigation of PEFC performance, and local gas analysis of PE ...
2008-07-01
Development of QA/QC technology in Korea
International Nuclear Information System (INIS)
KAERI (Korea Advanced Energy Research Institute) has performed research to develop the fabrication technology of CANDU nuclear fuel since 1981. Based on the satisfactory results of in-pile and out-of-pile tests of prototype nuclear fuel and the outstanding performance of 48 KAERI-made nuclear fuels in Wolsung(CANDU) power reactor, Korean government decided KAERI to supply all the nuclear fuels for Wolsung from 1988. In order to guarantee the safety and performance of nuclear fuel manufactured in mass production scale, well-organized quality assurance system and appropriate quality control techniques should be established. To establish the QA system, KAERI reviewed various QA standards and decided to establish QA system based on the 10 CFR 50 Appendix B. Quality control techniques was also revised to fit the mass production even though ...
1986-10-06
Platinum-based ternary catalysts for low temperature fuel cells. Part 2. Electrochemical properties
Energy Technology Data Exchange (ETDEWEB)
The development of high performance electrode materials is currently one of the main activities in the field of the low temperature fuel cells, fuelled with H{sub 2}/CO or low molecular weight alcohols. A promising way to attain higher catalytic performance is to add a third element to the best binary catalysts actually used as anode and cathode materials. In Part I of this review an overview of the preparation and structural characteristics of Pt-based ternary catalysts was presented. This part of the review deals with the electrochemical properties of these catalysts regarding their CO tolerance and electrocatalytic activity for methanol and ethanol oxidation in the case of anode materials, and their activity for oxygen reduction and stability in fuel cell conditions when used as cathode materials. (author)
2007-07-31
Nomographs for predicting crown fire initiation in Aleppo pine (Pinus halepensis Mill.) forests
British Library Electronic Table of Contents (United Kingdom)
Nomographs that calculate the threshold values of surface fire parameters which lead to crown fire initiation were created by linking two separate fire behavior models: Van Wagner?s crown fire ignition criteria and Byram?s surface fire model. The nomographs were also based on the existing surface (fuel load, fuel heat content) and canopy (foliar moisture content, live crown base height) fuel models of Aleppo (Pinus halepensis Mill.) pine forests of Mediterranean Greece. The most important fire parameters for crown fire initiation that are calculated by the nomographs are the critical flame length and the forward spread rate of the surface fire. These parameters are readily observable in the field during fires. The nomographs provide a judicious way to assess whether a crown fire is likely ...
2007-01-01
Model for predicting air-fuel mixing and combustion for direct injection diesel engine
Energy Technology Data Exchange (ETDEWEB)
Based on a multi-zone spray-mixing approach, an air-fuel mixing and combustion model for a Direct Injection Diesel engine is presented. The predictions from the model show very good agreement with the experimental data for various engines under a wide range of operating conditions. Major physical processes are modeled and validated independently. The atomisation process is based on Binary Drop Division concept. Fuel droplets are considered randomly distributed in the spray. A spherico-symmetrical transient drop evaporation model is used for evaporation calculation. A 3-dimensional spray-swirl interaction is modeled on centreline velocity vector/continuum approach. Turbulent mixing is characterised considering all possible available energy sources in DI diesel engines.
1986-01-01
Space effect on liquid film flow in a BWR fuel bundle
Critical power at boiling transition is an important factor in a boiling water reactor (BWR) fuel bundle design. Boiling transition under high quality accounts for dryout as the result of the complete disappearance of film flow on a fuel rod. This liquid film vanishing process can be calculated by the liquid film model, which takes into account the evaporation due to heat from the rod surface, liquid film entrainment by steam flow, and liquid droplet deposition. It is known that spacers affect liquid film entrainment and liquid droplet deposition, so the detailed study of spacer effects on hydrodynamic characteristics is necessary for critical power prediction based on the film flow model. Many studies have been conducted to examine spacer effects on liquid film flow. However, most of them are restricted to simple test sections such as a rectangular conduit. There are a few reports on fuel bundle ...
1991-01-01
Solar thermal production of zinc: Program strategy
Energy Technology Data Exchange (ETDEWEB)
The solar thermal production of zinc is considered for the conversion of solar energy into storable and transportable chemical fuels. The ultimate objective is to develop a technically and economically viable technology that can produce solar zinc. The program strategy for achieving such a goal involves research on two paths: a direct path via the solar thermal splitting of ZnO in the absence of fossil fuels, and an indirect path via the solar carbothermal/CH{sub 4}-thermal reduction of Zn O, with fossil fuels (coke or natural gas) as chemical reducing agents. Both paths make use of concentrated solar energy for high-temperature process heat. The direct path brings us to the complete substitution of fossil fuels with solar fuels for a sustainable energy supply system. The indirect path creates a link between today`s fossil-fuel-based technology and tomorrow`s ...
1999-08-01
The performance of jet fuel with an oxidant mixture containing 70 percent liquid fluorine and 30 percent liquid oxygen by weight was investigated in a 500-pound-thrust engine operating at a chamber pressure of 300 pounds per square inch absolute. A one-oxidant-on-one-fuel skewed-hole impinging-jet injector was evaluated in a chamber of characteristic length equal to 50 inches. A maximum experimental specific impulse of 268 pound-seconds per pound was obtained at 25 percent fuel, which corresponds to 96 percent of the maximum theoretical specific impulse based on frozen composition expansion. The maximum characteristic velocity obtained was 6050 feet per second at 23 percent fuel, or 94 percent of the theoretical maximum. The average thrust coefficient was 1.38 for the 500-pound thrust combustion-chamber nozzle used, which was 99 percent of the theoretical (frozen) maximum. Mixtures ...
1954-01-01
MAN B&W Diesel extends dual-fuel engine range up to 16 MW
Energy Technology Data Exchange (ETDEWEB)
In 1995, MAN B&W Diesel launched a dual-fuel version of the successful L + V (in-line and vee) configurations of the 32/40 diesel engine series, covering a power range between 2.4 and 7.2 MW. In 1996, the company is launching a dual-fuel version of the L + V 48/60 engine series, moving the power range of dual-fuel engines to 16.2 MW. With its new dual fuel type 32/40 DG and 48/60 DG engines, MAN B&W Diesel has designed prime movers offering a high efficiency at low operating costs, while simultaneously meeting the most stringent NO{sub x} emission limits without any exhaust gas after-treatment. These engines are based on the successful HFO-operated four-stroke diesel engines. They offer environment-friendly and, operating at high mean effective pressures, simultaneously cost effective propulsion alternatives, especially if natural gas is used as a fuel. ...
1996-04-01
Fuel cells and electricity companies - new risk management opportunities
International Nuclear Information System (INIS)
'Full text:' Deregulation, distributed generation, combined heat and power, renewables, fuel cells, hydrogen. Power companies are facing a rapidly evolving environment that is testing their ability to effectively deploy capital and earn profits. While recent deregulation trends have shifted the structure of power markets into separating generators from distributors, the improving economic value proposition offered by smaller scale distributed generation technologies - such as fuel cells - would seem to be a conflicting development. In this complex and changing environment, decisions based on the economic reality of the capital markets are likely to prevail. By examining the opportunity to enhance risk management offered by stationary fuel cells, particularly in CHP applications, we provide a context for the issues being discussed in today's sessions focusing on power companies and electric utilities. ...
2004-09-25
Cars and fuels for tomorrow: A comparative assessment
International Nuclear Information System (INIS)
Light duty vehicles, i.e. passenger cars and light trucks, account for approximately half of global transportation energy demand and, thus, a major share of carbon dioxide and other emissions from the transport sector. Energy consumption in the transport sector is expected to grow in the future, especially in developing countries. Cars with alternative powertrains to internal combustion engines (notably battery, hybrid and fuel-cell powertrains), in combination with potentially low carbon electricity or alternative fuels (notably hydrogen and methanol), can reduce energy demand by at least 50%, and carbon dioxide and regulated emissions much further. This article presents a comparative technical and economic assessment of promising future fuel/vehicle combinations. There are several promising technologies but no obvious winners. However, the electric drivetrain is a common denominator in the alternative powertrains and ...
2001-05-01
FFTF ex-vessel flux monitor response due to in-vessel stored fuel
International Nuclear Information System (INIS)
A feature of the Fast Flux Test Facility (FFTF) is that fuel assemblies can be stored within the reactor vessel, either for future use in the core or for temporary storage of spent fuel. Due to the close proximity of fuel assemblies stored in the in-vessel storage (IVS) locations to the ex-vessel flux monitors (EVFMs), neutrons originating in the stored fuel can result in significant contributions to the total EVFM signals. The paper shows EVFM-induced electronic current data during operation at full power for FFTF power cycles 1 through 7. The data were obtained early in each cycle so that signal drift due to core burnup could be ignored. The differences in currents are attributed to differences in cycle-to-cycle core and stored fuel loadings. At the beginning of cycle 1 there were no fuel assemblies stored in IVS. Subsequent to cycle 1, the EVFM currents have ...
1986-06-15
Cask consolidated spent fuel thermal analyses using the COBRA-SFS code
Energy Technology Data Exchange (ETDEWEB)
The COBRA-SFS computer code was used to perform thermal-hydraulic analyses of consolidated spent fuel stored in casks. The ability of the COBRA-SFS code to model consolidated fuel was evaluated by comparing predictions with experimental data obtained from electrically heated rod bundles by Ridihalgh, Eggers, and Associates and Eggers Ridihalgh Partners, Inc. under sponsorship of the Electric Power Research Institute. The calculations agreed with the measured temperatures well within the bounds of experimental error. Based on the evaluation results, best-estimate temperature predictions were performed for consolidated fuel in several cask designs. Results are presented for the REA 2023 BWR cask, the CASTOR-1C BWR cask, and the Concrete Sealed Storage Cask designed for Monitored Retrievable Storage (MRS). The cask simulation results indicate that consolidation of spent fuel results in ...
1986-04-01
International Nuclear Information System (INIS)
A semi-empirical relation which can be used to determine the total attenuation cross sections of samples containing H, C, N and O in the energy range 145-1332 keV has been derived based on the total attenuation cross sections of several sugars, amino acids and fatty acids. The cross sections have been measured by performing transmission experiments in a narrow beam good geometry set-up by employing a high-resolution hyperpure germanium detector at seven energies of biological importance such as 145.4 keV, 279.2 keV, 514 keV, 661.6 keV, 1115.5 keV, 1173.2 keV and 1332.1 keV. The semi-empirical relation can reproduce the experimental values within 1-2%. The total attenuation cross sections of five elements carbon, aluminium, titanium, copper and zirconium measured in the same experimental set-up at the energies mentioned above have been used in a new matrix method to evaluate the effective atomic numbers and the effective electron densities of ...
2006-09-28
Energy Technology Data Exchange (ETDEWEB)
A molybdenum (Mo) adsorbent called PZC (Poly Zirconium Compound) with high efficiency of Mo adsorption has been developed in order to generate {sup 99m}Tc from {sup 99}Mo produced from natural Mo by (n, gamma) method. The {sup 99m}Tc generator using PZC has cleared mostly the technical subjects. By the results of many experiments, cold and hot test with {sup 99}Mo activity from low level (10{sup 5} Bq) to high level (10{sup 10} Bq), it has been confirmed that the PZC method can be practically applied for the (n, gamma) {sup 99}Mo-{sup 99m}Tc generator. From the reasons that PZC has the ability and many merits such as high adsorption capacity (>250 mg-Mo/g-PZC) of Mo, high elution yield (av. 80%) of {sup 99m}Tc, the low breakthrough (<0.05 kBq-{sup 99m}Mo/MBq-{sup 99m}Tc) of {sup 99}Mo and others, the current (n, fission) {sup 99m}Tc generator utilizing {sup 99}Mo produced from enriched uranium will be taken the place by PZC method. In this paper, the ...
2003-03-01
Energy Technology Data Exchange (ETDEWEB)
In this work theoretical investigations are carried out for cooling systems, which are used in fuel cell vehicles. This work focuses mainly on the capability of increasing the heat rejection rate by using new alternative cooling systems and by improving the conventional cooling system. Fuel cell vehicles have a higher demand of heat rejection to the ambient than comparable vehicles with combustion engine. The performance of conventional liquid cooling systems, especially at high loads and high ambient temperatures, is often not sufficient anymore. Hence, cooling systems with improved performance are necessary for fuel cell vehicles. The investigations in this work are based on DaimlerChrysler's ''A-Class'' having a PEM-Fuel Cell system integrated. Specific computational models are developed for radiators and condensers to evaluate the ...
2008-04-01
Global environment problems have become more and more serious in recent years, and reduction of greenhouse gas emission based on Kyoto Protocol adopted at the 3rd conference of the parties of the United nations Framework Convention on Climate Change (COP3); securement of primary energy source and development of clean and renewable energy sources have been pressingly needed in consideration of the predicted depletion of fossil fuel in the future. In this study, we explore the use of a solidified biomass-derived fuel, having the maximum compressive strength of 100MPa and calorific value of 21MJ/kg, in iron-casting or iron-making processes as an alternative fuel to be mixed with coal coke. This study, carried out for internal observation using a quick-freeze technique, observed an actual working cupola furnace under the 20% alternative coal coke operation condition. After quick freeze of the cupola ...
2010-01-01
International Nuclear Information System (INIS)
Environmental and security concerns are stimulating global interest in hydrogen power, renewable energy, and advanced transportation technologies, but no significant movement away from oil and a carbon-based world economy is expected soon. Over the longer-term, however, a transition from fossil fuels to a non-carbon-based economy will likely occur, affecting the type of environment future generations may encounter. Key challenges will face the world's energy industry over the next few decades to ensure a smooth transition-challenges which will require government and industry solutions beginning as early as today. This paper identifies four critical challenges in energy and the choices which will have to be made on how best to confront growing pollution caused by fossil fuels and how to facilitate an eventual revolutionary-like transition to a non-carbon-based global economy.
2006-10-01
Reprocessing of research reactor spent nuclear fuel at the PA ''Mayak''
International Nuclear Information System (INIS)
The first Russian reprocessing facility, known as RT-1 (located at PA-Mayak in Ural region) was started on the radiochemical plant base in 1977. Nowadays RT-1 is the sole operating reprocessing plant in Russia. The main features of RT-1 is its broad spectrum of reprocessing spent nuclear fuels (SNF). The following spent fuel types are reprocessed: -) SNF from PWR reactors (WWER-440) and FB reactor (BN-600); -) SNF of transport ship reactors; -) production reactors SNF; -) research reactor spent nuclear fuel. The world-known technological processes are used at RT-1, but there are the following distinctive features. First, the universality of the three technological lines which allows not only the reprocessing of various SNF kinds, but also to implement the combined reprocessing of some types of them. Secondly, extraction of neptunium during SNF reprocessing which is used to implement its separate storage ...
2007-03-11
Reprocessing of research reactor spent nuclear fuel at the PA 'Mayak'
Energy Technology Data Exchange (ETDEWEB)
The first Russian reprocessing facility, known as RT-1 (located at PA-Mayak in Ural region) was started on the radiochemical plant base in 1977. Nowadays RT-1 is the sole operating reprocessing plant in Russia. The main features of RT-1 is its broad spectrum of reprocessing spent nuclear fuels (SNF). The following spent fuel types are reprocessed: -) SNF from PWR reactors (WWER-440) and FB reactor (BN-600); -) SNF of transport ship reactors; -) production reactors SNF; -) research reactor spent nuclear fuel. The world-known technological processes are used at RT-1, but there are the following distinctive features. First, the universality of the three technological lines which allows not only the reprocessing of various SNF kinds, but also to implement the combined reprocessing of some types of them. Secondly, extraction of neptunium during SNF reprocessing which is used to implement its separate storage ...
2007-07-01
Improvement of fuel performance in the Wolsung Nuclear Power Plant
International Nuclear Information System (INIS)
From the start of commercial operation in 1983 until the end of 1985, the Wolsung Nuclear Power Plant operated for about 800 effective full power days (EFPDs). During this relatively short operational period it experienced various problems but achieved high reliability in operation. Wolsung recorded economical fuel utilization, particularly in 1985, together with a 94.4% plant capacity factor; it also showed successful in-pile test results as part of a fuel localization project. The actual fuelling rate was 16.3 bundles per EFPD in 1985, i.e. a saving of about 11% compared with the design fuelling rate of 18.2 bundles per EFPD. Better fuel performance was achieved because minimum excess reactivity was maintained in the core, characteristics unique to the core were found and the spatial flux distribution was controlled. The average discharge fuel burnup in 1985 was 6993 MW#centre dot#d/t U, which was ...
1986-09-15
Fuel pin fabrication for the FFTF
Energy Technology Data Exchange (ETDEWEB)
Fabrication processes for FFTF fuel pins are described.
1980-01-01
International Nuclear Information System (INIS)
Alloys of zirconium are widely used in various core components of power reactors. Nuclear assemblies require high degree of reliability and integrity for performing in radiation and corrosive atmosphere. The hostile environments of reactor core and inaccessibility for repairs make it mandatory to select only those joining techniques which produce not only superior quality but are also amenable to NDT methods and such other techniques which ensure acceptable performance. The author has worked on various types of welding of zirconium alloys for different applications. Modern techniques in electron beam (EB) welding, resistance welding, GTAW welding and laser welding have been developed for joining Zr alloys components for different types of reactors. Many of these have been standardized and successfully used in production. Several advancements have been made in the welding technologies towards achieving high productivity and increased reliability ...
2002-09-11
Energy Technology Data Exchange (ETDEWEB)
Multi-dimensional modelling of two-phase flow requires accurate constitutive relationships for interfacial parameters such as interfacial heat transfer, void fraction distribution, interfacial area, etc. However, existing diagnostic systems for measurement of two-phase flow parameters have difficulty measuring two or three-dimensional void distributions required for determination of interfacial parameters. In this work, a Real-Time Neutron Radiography (RTNR) system is developed for non-intrusive measurement of two-phase flow parameters in nuclear fuel channels at low thermal neutron fluxes (on the order of 10{sup 6}n/cm{sup 2}-s). This advanced radiation technique has the advantage of measuring two-phase flow in 3 1/2 dimensions (x,{integral}dy,t) where the 1/2 dimension refers to an integrated or averaged space dimension. Pipe flow channels, annulus flow channels, MAPLE-type nuclear fuel flow channels, and CANDU-type nuclear ...
1995-07-01
International Nuclear Information System (INIS)
Multi-dimensional modelling of two-phase flow requires accurate constitutive relationships for interfacial parameters such as interfacial heat transfer, void fraction distribution, interfacial area, etc. However, existing diagnostic systems for measurement of two-phase flow parameters have difficulty measuring two or three-dimensional void distributions required for determination of interfacial parameters. In this work, a Real-Time Neutron Radiography (RTNR) system is developed for non-intrusive measurement of two-phase flow parameters in nuclear fuel channels at low thermal neutron fluxes (on the order of 10"6n/cm"2-s). This advanced radiation technique has the advantage of measuring two-phase flow in 3 1/2 dimensions (x,#integral#dy,t) where the 1/2 dimension refers to an integrated or averaged space dimension. Pipe flow channels, annulus flow channels, MAPLE-type nuclear fuel flow channels, and CANDU-type nuclear fuel ...
1346-01-01
All the Spent Nuclear Wastes to Low and Intermediate Level Wastes: PyroGreen
International Nuclear Information System (INIS)
Spent nuclear wastes are inevitable issues to use nuclear power as a sustainable energy. Therefore, every country has their fuel cycles which are best for their environmental and/or political circumstances for the use of nuclear energy. These days agreements are made that spent nuclear fuels should be recycled to minimize waste volume and its toxicity all around the world. Republic of Korea also has a plan to recycle the spent nuclear fuels by using Gen-IV concept burner reactors and pyro-process plants. Not many options of national nuclear strategies are exist because Korea has too many people for its limited land space. KAERI already has been proposing a national fuel cycle concept called 'KIEP-21' that encompasses all the requirements of the advanced nuclear fuel cycle such as reduction of volume, toxicity, HLW heat load and so on. Authors suggest non-national ...
2009-06-01
Transient performance of FFTF [Fast Flux Test Facility] reference fuel
International Nuclear Information System (INIS)
Fourteen irradiated Fast Flux Test Facility (FFTF) fuel pins were subjected to representative overpower transients in six flowing sodium loop experiments conducted in the TREAT reactor. The transient tests were extended to substantial overpower levels well beyond protected levels, with some tests intentionally run to failure to identify failure thresholds and characteristics. Test variables included transient ramp rate (5, 50, and 100 cents/s) and burnup (2 to 58 MWd/kg). Performance limits and failure characteristics were identified, and cladding strain and fuel melting data were obtained for development and verification of transient analysis codes. The test results demonstrated that FFTF Reference fuel pins are capable of surviving overpower levels well beyond the FFTF secondary Plant Protection System (PPS) trip limit of 1.25 times normal rated power. Based on analytical evaluations to interpolate ...
1986-09-07
International Nuclear Information System (INIS)
To clarify the effects of the principal factors that govern the thermal fragmentation of a molten metallic fuel jet in the course of fuel-coolant interaction, which is important in evaluating the sequence of core disruptive accidents (CDAs) for metallic fuel fast reactors, basic experiments were carried out using molten metallic fuel simulants (copper and silver) and a sodium pool.Fragmentation of a molten metal jet with a solid crust was caused by internal pressure produced by the boiling of sodium, which is locally entrapped inside the jet due to hydrodynamic motion between the jet and the coolant. The superheating and the latent heat of fusion of the jet are the principal factors governing this type of thermal fragmentation. On the other hand, the effect of the initial sodium temperature is regarded as negligible in the case of thermal conditions expected to result in CDAs for practical metallic ...
2005-02-01
International Nuclear Information System (INIS)
The International Project on Innovative Nuclear Reactors and Fuel Cycles (INPRO) was launched in the year 2000, based on a resolution by the IAEA General Conference (GC(44)/RES/21). INPRO intends to help to ensure that nuclear energy is available in the 21st century in a sustainable manner, and seeks to bring together all interested Member States, both technology holders and technology users, to consider, jointly, actions to achieve desired innovations. INPRO is taking care of the specific needs of developing countries. This IAEA publication is part of Phase 1 of INPRO. It intends to provide an overview on history, present situation and future perspectives of nuclear fuel cycle technologies. While this overview focuses on technical issues, nevertheless, the aspects of economics, environment, and safety and proliferation resistance are important background issues for this study. After a brief description about the INPRO ...
1991-01-01
International Nuclear Information System (INIS)
The paper discusses the safety problems connected with the conversion to dense storage of RBMK-1000 spent fuel in reactor cooling pools and independent storage facilities. Recourse to dense storage has been made for a number of reasons, among which are the absence of spent fuel shipments from the nuclear power plant site, prolongation of storage time and a partial change in storage conditions. Increasing the storage density per unit volume of the storage facility and turning to new technical procedures (as against the basic design) call for further investigation of safety problems. The safety assessment of the dense storage mode includes: (1) Selecting a list of initiating events for design basis and unforeseeable accidents; (2) Assessing dense storage safety under normal as well as design basis accident conditions; (3) Safety analysis and development of measures to compensate for unforeseen accidents. Based on the studies ...
1995-08-01
International Nuclear Information System (INIS)
A push for electric vehicles has occurred in the past several decades due to various concerns about air pollution and the contribution of emissions to global climate change. Although electric cars and buses have been the focus of much of electric vehicle development, smaller vehicles are used extensively for transportation and utility purposes in many countries. In order to explore the viability of fuel cell - battery hybrid electric vehicles, empirical fuel cell system data has been incorporated into the NREL's vehicle design and simulation tool, ADVISOR (ADvanced Vehicle SimulatOR), to predict the performance of a low-speed, fuel cell - battery electric vehicle through MATLAB Simulink. The modelling and simulation provide valuable feedback to the design optimization of the fuel cell power system. A sampling based optimization algorithm was used to explore the viability and options ...
2005-06-12
Direct hydrogenation and solvent extraction of coal. [US DOE
Recent fuel cost increases coupled with energy shortages have resulted in an awareness of the need to conserve energy and to expand the United States domestic energy base. Increase in coal conversion and utilization are major objectives of the research and development activities in the US Department of Energy. Several alternate processing schemes are being developed to convert coal to environmentally acceptable liquid fuels. A few of these technologies are approaching the commercialization stage and scale-up is being carried forward on the most promising processes. The various coal liquefaction processes are discussed by dividing them into four general classifications. Processes for converting various types of coal to synthetic liquid fuels are being improved so that clean fuels can be produced commercially. Emphasis is on the production of fuels suitable for ...
1979-09-01
Development of the new MAN B and W 32/40 dual fuel engine
Energy Technology Data Exchange (ETDEWEB)
Based on the tried and proven 32/40 diesel engine MAN B and W Diesel AG has developed a dual fuel gas engine covering a rate from 2.4 to 7.2 MW for stationary application in cogeneration and power stations. This paper reports the salient points of the 32/40 DG development project from the concept phase through to prototype testing. To reach the targets a dual fuel prechamber combustion system was developed using an externally arranged, cylinder individual gas admission for the main combustion chamber and a pilot fuel injection to the prechamber. Due to the high thermal and mechanical load sustaining capability of the strong-built heavy fuel diesel engine, bmep (19.9 bar) and efficiency (42.6%) in excess of the targets were achieved with a more than satisfactory life of components. Moreover, the NO{sub x} limit of 500 mg/m{sup 3} as specified in the German TA Luft was successfully ...
1996-12-31
Energy Technology Data Exchange (ETDEWEB)
In nuclear fuel, in approximately one quarter of the fissions, one of the two formed fission products is gaseous. These are mainly the noble gases xenon and krypton with isotopes of xenon contributing up to 90% of the product gases. These noble fission gases do not combine with other species, and have a low solubility in the normally used uranium oxide matrix. They can be dissolved in the fuel matrix or precipitate in nanometer-sized bubbles within the fuel grain, in micrometer-sized bubbles at the grain boundaries, and a fraction also precipitates in fuel pores, coming from fuel fabrication. A fraction of the gas can also be released into the plenum of the fuel rod. With increasing fission, and therefore burn-up, the ceramic fuel material experiences a transformation of its structure in the 'cooler' rim region of the ...
2008-07-01
Energy Technology Data Exchange (ETDEWEB)
In this study, sensitivity analysis of 100 MWth chemical looping combustion combined cycle (CLC-CC) plant based on fuel cost were performed. By performance analysis, net efficiency of natural gas/syngas fueled CLC-CC plant was 53-54%, corresponding to previous research. We used Chemical Engineering Plant Cost Index and Guthrie method to evaluate plant cost. For syngas fueled CLC-CC plant, the plant cost was higher since lower heating value (LHV) of syngas was lower than that of natural gas and cost of electricity (COE) was also higher since the cost of syngas was higher than that of natural gas. By sensitivity analysis, it was shown that the cost of syngas should be less than 5.3 $/GJ in order to make COE lower than 5.8 c/kWh which was COE of natural gas CLC-CC plant. 15 refs., 2 figs., 5 tabs.
2009-07-01
International Nuclear Information System (INIS)
Determination of americium (Am) is one of the requirements of chemical quality assurance of plutonium (Pu) bearing fuel materials. Though many methods are published for determining Am at picogram to femtogram levels in environmental and biological matrices, yet a few of them are used routinely for Pu based nuclear fuel samples. This paper gives a brief summary of the different analytical methods available and presents results of our experiments on the determination of Am in Pu bearing fuels using gamma spectroscopy. The methods utilizing gamma emissions from "2"4"1Am and Pu isotopes are fast as they do not involve chemical separation of Pu and Am, do not require an accurate knowledge of the efficiency values of the detector systems and are not dependent on the availability of a radiometric standard for "2"4"1Am. In addition, for aged Pu samples containing large amounts of "2"4"1Am, there is no need for ...
2010-11-15
Energy Technology Data Exchange (ETDEWEB)
The conversion of off-peak surplus electricity into peak electricity through an electrolyzer, hydrogen storage, and fuel cell energy storage system was discussed. Development efforts in high pressure alkaline electrolysis and Proton-Exchange Membrane (PEM) fuel cells have improved the near-term viability of these systems. Potential use of wind turbines and other renewable energy-based generation systems, through hydrogen-based energy storage, were discussed as a new supply of surplus electricity. An integrated set of nomographs were presented for providing quick estimates of peak electricity costs derived from an electrolyzer/hydrogen fuel cell system. The nomographs allowed first order cost comparisons of centralized versus distributed hydrogen energy systems considering trade-offs between production economies of scale and hydrogen storage and transport costs. Use of the nomographs ...
1995-06-01
Energy Technology Data Exchange (ETDEWEB)
The structural integrity of the Fuel Test Loop(FTL) in a Korean experimental reactor is evaluated when the FTL, submerged in a water environment, is subjected to a postulated pipe rupture. The analyses are performed under static and dynamic conditions, imposing the thrust force history at each postulated pipe rupture section. Through analysis the following results are found: 1) A double ended guillotine can not be expected based on the toughness of the material, 2) the structural integrity of the chimney surrounding the FTL would not impede the structural integrity by the pipe whip. All analyses are performed by finite element methods.
2000-02-01
Energy Technology Data Exchange (ETDEWEB)
This paper presents fundamental researches based on the electronic structure calculations and X absorption spectroscopy, allowing the knowledge on nuclear fuels at an atomic scale. They bring a better understanding of these material behavior to accurate the macroscopic simulation. The calculation methods, the experimental techniques of validation and the ab initio calculations results are detailed. (A.L.B.)
2000-07-01
This bulletin traces development of high-pressure, coal and tar hydrogenation technology, based on an intensive review of pertinent literature. The bulletin written as part of the Bureau of Mines research program on synthetic liquid fuels covers the history and economics of the process; chemical aspects of hydrogenation of coal, tar, and middle oil; engineering aspects of converting coal and tar to liquid fuels, principally gasoline; and equipment for the process. The literature covered includes documents of United States and British governments, journals, and other publications. Bureau results in the hydrogenation field are also incorporated.
1968-01-01
Energy Technology Data Exchange (ETDEWEB)
Epoxy-resin based neutron shielding material, NS-4-FR, is used for spent fuel transport and/or storage cask. In this paper the outline of thermal aging test performed to evaluate the heating effect on this neutron shielding material, NS-4-FR, is introduced. The test is consisted of two kinds of thermal aging test, one is 'Basic Test' and the other is 'Block Heating Test'. The former is cooperatively performed by ten Japanese Electrical Power Companies, and the latter is done by GESC and NOF Corporation. (authors)
1998-07-01
International Nuclear Information System (INIS)
Epoxy-resin based neutron shielding material, NS-4-FR, is used for spent fuel transport and/or storage cask. In this paper the outline of thermal aging test performed to evaluate the heating effect on this neutron shielding material, NS-4-FR, is introduced. The test is consisted of two kinds of thermal aging test, one is 'Basic Test' and the other is 'Block Heating Test'. The former is cooperatively performed by ten Japanese Electrical Power Companies, and the latter is done by GESC and NOF Corporation. (authors)
1998-05-10
Advances in cotton gin trash energy conversion
Energy Technology Data Exchange (ETDEWEB)
The concept of using agricultural residues, especially cotton gin trash (CGT), as a fuel for a small cogeneration power plant based on fluidized bed gasification (FBG) requires that three problems be solved: (1) ash must be removed from the low calorific value (LCV) gas prior to combustion; (2) the high NO/sub x/ emissions associated with many biomass fuels must be significantly reduced; (3) a systems analyses of engineering/economic feasibility for potential applications must be developed. This paper addresses current research at TAMU pertaining to these problems.
1985-01-01
Treatment feasibility of the radioactive liquid waste originated from MOX fuel characterization
International Nuclear Information System (INIS)
Different types of radioactive liquid waste are being generated at Advanced Fuel Fabrication Facility (AFFF), Tarapur during the quality control analysis of the mixed oxide (MOX) fuel pellets. A laboratory scale study was performed for treatment of such waste. Some of the waste streams originating from U and Pu analysis contain components like sulphate and phosphate which interfere during chemical precipitation of alpha activity from the waste. Various chemical co-precipitation experiments were conducted based on alkaline precipitation. Reductive precipitation using sodium sulphite and Fe(II) was found to be promising and the same was suggested for plant scale treatment. (author)
2011-02-22
The U.S. Liquid Metal Reactor Development Program
International Nuclear Information System (INIS)
This paper discusses how the U.S. Liquid Metal Reactor Development Program has been restructured to carry out R and D on advanced reactor technology. The program gives particular emphasis to improvements to reactor safety. The new directions are based on the technology of the integral fast reactor (IFR). Much of the basis for superior safety performance using IFR technology has been experimentally verified and aggressive programs continue in EBR-II and TREAT. Progress has been made in demonstrating both the metallic fuel and the new electrochemical processes of the IFR. The FFTF facility is converting to metallic fuel; however, FFTF also maintains a considerable U.S. program in oxide fuels. In addition, generic programs are continuing in steam generator testing, materials development, and with international cooperation, aqueous reprocessing.
1988-05-01
British Library Electronic Table of Contents (United Kingdom)
Glass ceramics are commonly used as sealing materials for planar solid oxide fuel cells (SOFCs). The major requirements of stack and module builders for these materials are the stability of the coefficient of thermal expansion (CTE), excellent bonding (sticking) behaviour and the absence of volatile ingredients, which can lead to changes of the material properties and the sealing ability. SCHOTT Electronic Packaging has developed special glasses and glass-ceramics for various solid oxide fuel cell designs and operating temperatures. The glass compositions are based on the system MgO-Al2O3-BaO-SiO2-B2O3. In this study the evaluation of the developed materials was done by high temperature aging tests for up to 1000h, high temperature XRD-studies and Rietveld calculations, combined with scann...
2011-01-01
Road maps on research and development plans for water chemistry of nuclear power systems
International Nuclear Information System (INIS)
Water chemistry of nuclear power plants has played an important role in reduction of personnel doses, structural materials and fuel integrity assurance, and reduction of radioactive wastes production. Further contributions are requested for advanced utilization of the LWR, advanced fuels and aging management of plants. Since water chemistry has an effect on all structure and materials immersed and at the same time affected by them, the optimum control not sticking to specific issues and covering the whole plant is required for these requests. Taking account of roles and activities of the industry, governmental institutes and academia, road maps on research and development plans for water chemistry were compiled into identified eleven items with targets and counter measures taken, such as common basic technologies, dose reduction, SCC mitigation, fuel cans corrosion/hydrogen absorption mitigation, condition ...
2008-05-01
RECENT ACTIVITIES AT THE CENTER FOR SPACE NUCLEAR RESEARCH FOR DEVELOPING NUCLEAR THERMAL ROCKETS
Energy Technology Data Exchange (ETDEWEB)
Nuclear power has been considered for space applications since the 1960s. Between 1955 and 1972 the US built and tested over twenty nuclear reactors/ rocket-engines in the Rover/NERVA programs. However, changes in environmental laws may make the redevelopment of the nuclear rocket more difficult. Recent advances in fuel fabrication and testing options indicate that a nuclear rocket with a fuel form significantly different from NERVA may be needed to ensure public support. The Center for Space Nuclear Research (CSNR) is pursuing development of tungsten based fuels for use in a NTR, for a surface power reactor, and to encapsulate radioisotope power sources. The CSNR Summer Fellows program has investigated the feasibility of several missions enabled by the NTR. The potential mission benefits of a nuclear rocket, historical achievements of the previous programs, and recent investigations into alternatives ...
2001-09-01
British Library Electronic Table of Contents (United Kingdom)
The objective of this study is to analyze the effects of heat loss characterized by a percentage of the fuel's energy, friction and variable specific heats of working fluid on the performance of an air standard Otto cycle with a restriction of maximum cycle temperature. A more realistic and precise relationship between the fuel's chemical energy and the heat leakage that is based on a pair of inequalities is derived through the resulting temperature. The variations in power output and thermal efficiency with compression ratio, and the relations between the power output and the thermal efficiency of the cycle are presented. The results show that the power output as well as the efficiency where maximum power output occurs will increase with increase of the maximum cycle temperature. The temp...
2008-01-01
Clean combustion of solid fuels
International Nuclear Information System (INIS)
A chemical-looping process is proposed for the clean combustion of solid fuels for electric power or heat generation. The process is based on coal gasification with CO_2 to produce CO. The CO then reduces CaSO_4, which is used as an oxygen carrier, in a separate reactor to give CaS and CO_2. A portion of the CO_2 is recycled for the gasification stage and the rest can be sent for sequestration. The CaS is sent to another reactor for oxidation with air and to generate heat or power. The overall thermal effect is the same as direct combustion, but separation of CO_2 and other pollutants, such as sulphur, is achieved. In comparison with conventional chemical-looping combustion of natural gas, much less water is present in the CO_2 product, and hence the loss of heat energy and corrosion of the fuel-reactor system can be reduced.
2008-01-01
International Nuclear Information System (INIS)
The report presents the results of experimental studies conducted to provide a description of the conditions which lead to the occurrence of critical heat flux (CHF), in Combustion Engineering (C-E) fuel assemblies using the C-E standard spacer grid. A CHF correlation is presented which is based on CHF data obtained in tests with electrically heated rod bundles representative of the C-E 14 x 14 and 16 x 16 array fuel assemblies. The results reported are for a uniform axial heat flux distribution. The experiments were conducted in the Medium Pressure Heat Transfer Flow Loop at the Chemical Engineering Research Laboratories at Columbia University.
British Library Electronic Table of Contents (United Kingdom)
The present paper concerns the development of a polymer electrolyte membrane (PEM) fuel cells model in order to analyse the behaviour of the cell varying its operating parameters such as temperature (70-120 ^oC), pressure (1-3 atm), relative humidity (35-100%) and CO content (0-200 ppm) in the feeding gas. The voltage output and the relative current of a generic PEM fuel cell has been predicted through a mathematical method based on semi-empirical correlations derived from the experimental data available in literature. The model has been implemented in a commercial process simulator (AspenPlus) and it has been validated by comparing the obtained results with further experimental data (not utilized for the model development). The comparison has underlined a good agreement with the experimen...
2011-01-01
Remote power systems with advanced storage technologies for Alaskan villages
Energy Technology Data Exchange (ETDEWEB)
Remote Alaskan communities pay economic and environmental penalties for electricity, because they must import diesel as their primary fuel for electric power production, paying heavy transportation costs and potentially causing environmental damage with empty drums, leakage, and spills. For these reasons, remote villages offer a viable niche market where sustainable energy systems based on renewable resources and advanced energy storage technologies can compete favorably on purely economic grounds, while providing environmental benefits. These villages can also serve as a robust proving ground for systematic analysis, study, improvement, and optimization of sustainable energy systems with advanced technologies. This paper presents an analytical optimization of a remote power system for a hypothetical Alaskan village. The analysis considers the potential of generating renewable energy (e.g., wind and solar), along with the possibility of using ...
1997-12-01
Energy Technology Data Exchange (ETDEWEB)
There is renewed interest in the development of natural gas vehicles in response to the challenge to reduce urban air pollution and consumption of petroleum. The natural gas/diesel dual fuel engine is one way to apply natural gas to the conventional diesel engine. Dual fuel engines operating on natural gas and diesel emit less nitrogen oxides, and less carbon soot to the air compared to conventional diesel engines. The problem is that at light loads, fuel efficiency is reduced and emissions of hydrocarbons and carbon monoxide are increased. This thesis focused on control methods for emissions of hydrocarbons and carbon monoxide in the dual fuel engine at light loads. This was done by developing a reverse flow catalytic converter to complement dual fuel engine exhaust characteristics. Experimental measurements and numerical simulations of reverse flow catalytic converters were ...
2000-07-01
International Nuclear Information System (INIS)
The "6"2Zn-"6"2Cu generator system is one of the few which yield a pure positron emitting daughter. The authors have developed a method for the preparation of this generator system following 32 MeV #alpha# particle bombardment of nickel targets. The chemical processing involves two stages: first a hydrous zirconium oxide column is used at pH 4-5 to separate the zinc and copper activities produced in the target nickel, and secondly, a conventional anion exchange column is used to retain the "6"2Zn and remove all copper activities in 2M HCl. This column serves as the "6"2Cu generator which will yield pure "6"2Cu repeatedly, free from "6"2Zn and other impurities, in a mixture of HCl and NaCl. A method is outlined also to obtain a solution of "6"2Zn using the hydrous zirconium oxide (HZO) column. "6"1Cu can be prepared as a by-product in the above procedure, but a method for the preparation of "6"1Cu alone using an 18 MeV #alpha# particle beam on a ...
Interaction of tetravalent plutonium and zirconium with citric acid in nitric acid solutions
The interaction of Pu(IV) and Zr(IV) with citric acid in nitric acid solutions (C/sub HNO/sub 3// greater than 0.1 M) of lithium nitrate was studied by the distribution method in the interval of nitrate ion concentrations from 1 to 6 g-eq/liter. A 40 percent solution of TBP in decane was used as the extraction reagent. It was established that within the range of concentrations studied, complex compounds of plutonium and zirconium are formed: PuHCit/sup 2 +/ and ZrH/sub 2/Cit/sup 3 +/. The concentration equilibrium constants of the reactions of formation of these compounds retain a constant value at constant ionic strength and undergo substantial variation when the total concentration of the nitrate ion in solution is varied. The values of the effective equilibrium constants, calculated considering the change in the activity coefficient of the hydrogen ion, retain a constant value within a wide range of nitrate ion concentrations. It was shown that the effectiveness ...
1975-01-01
Energy Technology Data Exchange (ETDEWEB)
Substantial roles of precipitates such as Zr-Fe-Cr type intermetallic compounds on uniform corrosion and hydrogen pickup of zirconium alloys in pure water autoclave tests were investigated from an electrochemical point of view. In the previous paper, corrosion mechanism was elucidated by the anodic protection-precipitates degradation model. This paper describes the roles on hydrogen pickup. 633 K pure water autoclave test was performed on high purity zirconium, Zr-0.2Fe, Zr-0.2Cr, and Zr-0.1Fe-0.1Cr alloys. Hydrogen analysis after the corrosion test showed that hydrogen pickup ratio of Zr-0.2Fe alloy was about 80%. It was much higher than about 30% of pure Zr and about 10% of both Zr-0.2Cr and Zr-0.1Fe-0.1Cr alloys. Larger hydrogen content was introduced into Zr-0.2Fe alloy than the other ones by the cathodic hydrogen charging under coulombic equivalence. The precipitates at metal-oxide interface could act not only as cathodic sites in the ...
2000-08-01
International Nuclear Information System (INIS)
Substantial roles of precipitates such as Zr-Fe-Cr type intermetallic compounds on uniform corrosion and hydrogen pickup of zirconium alloys in pure water autoclave tests were investigated from an electrochemical point of view. In the previous paper, corrosion mechanism was elucidated by the anodic protection-precipitates degradation model. This paper describes the roles on hydrogen pickup. 633 K pure water autoclave test was performed on high purity zirconium, Zr-0.2Fe, Zr-0.2Cr, and Zr-0.1Fe-0.1Cr alloys. Hydrogen analysis after the corrosion test showed that hydrogen pickup ratio of Zr-0.2Fe alloy was about 80%. It was much higher than about 30% of pure Zr and about 10% of both Zr-0.2Cr and Zr-0.1Fe-0.1Cr alloys. Larger hydrogen content was introduced into Zr-0.2Fe alloy than the other ones by the cathodic hydrogen charging under coulombic equivalence. The precipitates at metal-oxide interface could act not only as cathodic sites in the ...
2000-08-01
Reprocessed uranium fuel fabrication in Japan
International Nuclear Information System (INIS)
Nuclear fuel vendors in Japan are now studying reprocessed uranium (RepU) fuel in order to prepare for full scale utilization in the future. Separate studies are made for PWR and BWR fuel. The study consists of 2 phrases. The purposes of phase-1 are to understand various RepU characteristics in the fuel fabrication process, to analyze the core characteristics by loading RepU assemblies, to solve the problems clarified in the study, and to collect basic data for licensing. In phase-2, the effects of impurities on the fabrication process will be evaluated, and the safety of RepU fuel manufacturing will be confirmed with a RepU fuel fabrication campaign in 1990. The neutronic data will be collected after insertion into power reactors, and the data will be used to verify plant safety for full utilization of RepU in the future. This paper summarizes the phase-1 study ...
1990-12-01
Energy Technology Data Exchange (ETDEWEB)
Flowsheets for the dissolution of aluminum-clad spent nuclear fuel have been proposed using 0.002 M mercuric nitrate catalyst in 5 to 6 M nitric acid. Previous calculations for flammable gas control during the dissolution of spent nuclear fuel have been extended to cover a range of dissolver purge rates from 40 to 55 scfm. A range of dissolver solution volumes from 12000 to 15000 liters were considered for the large H-Canyon dissolver (6.4D). Depending on the purge rate, anywhere from four to six bundles of MURR fuel can be initially charged to the dissolver (6.4D). For successive charges where the dissolver solution already contains 0.002 M mercury catalyst and the dissolved aluminum from five bundles of MURR fuel, five to nine bundles of additional fuel can be charged depending on the purge rate and the dissolver solution volume. Similar calculations have been performed for the ...
2010-07-22
Growth of Cr-Nitrides on commercial Ni-Cr and Fe-Cr base alloys to protect PEMFC bipolar plates
Energy Technology Data Exchange (ETDEWEB)
Nitridation of Cr-bearing alloys can yield low interfacial contact resistance (ICR), electrically conductive and corrosion-resistant CrN or Cr{sub 2}N base surfaces of interest for a range of electrochemical devices, including fuel cells, batteries, and sensors. This paper presents results of exploratory studies of the nitridation of commercially available, high Cr (30-35 wt%) Ni-Cr alloys and a ferritic high Cr (29 wt%) stainless steel for proton exchange membrane fuel cell (PEMFC) bipolar plates. A high degree of corrosion resistance in sulfuric acid solutions designed to simulate bipolar plate conditions and low ICR values were achieved. Oxygen impurities in the nitriding environment were observed to play a significant role in the nitrided surface structures that formed, with detrimental effects for the Ni-Cr base alloys, but beneficial effects for the stainless steel alloy. Positive results from ...
2007-11-15
Growth of Cr-Nitrides on Commercial Ni-Cr and Fe-Cr Base Alloys to Protect PEMFC Bipolar Plates
Energy Technology Data Exchange (ETDEWEB)
Nitridation of Cr-bearing alloys can yield low interfacial contact resistance (ICR), electrically- conductive and corrosion-resistant CrN or Cr2N base surfaces of interest for a range of electrochemical devices, including fuel cells, batteries, and sensors. This paper presents results of exploratory studies of the nitridation of two high Cr (30-35 wt%) commercially available Ni-Cr alloys and a ferritic high Cr (29 wt.%) stainless steel for proton exchange membrane fuel cell (PEMFC) bipolar plates. A high degree of corrosion resistance in sulfuric acid solutions designed to simulate bipolar plate conditions and low ICR values were achieved via nitridation. Oxygen impurities in the nitriding environment were observed to play a significant role in the nitrided surface structures that formed, with detrimental effects for the Ni-Cr base alloys, but beneficial effects for the stainless steel alloy. Results of ...
2007-01-01
49 CFR 130.11 - Communication requirements.
...identified as oil when the shipment document accurately describes the material as: aviation fuel, diesel fuel, fuel oil, gasoline, jet fuel, kerosene, motor fuel, or...
2010-10-01
International Nuclear Information System (INIS)
Greenhouse gas emissions from international maritime transport are exempt from liabilities under the Kyoto Protocol. Research into quantifying these emissions is ongoing, and influences policy proposals to reduce emissions. This paper presents a cargo-based analysis of fuel consumption and greenhouse gas emissions from New Zealand's international maritime transport of goods. Maritime transport moves 99.5% (by mass) of New Zealand's internationally traded products. It is estimated that 73% of visiting vessels' activity can be directly attributed to the movement of goods in and out of New Zealand. A cargo-based methodology was used to estimate that the international maritime transport of New Zealand's imports and exports consumed 2.5 million tonnes (Mt; 2.6 billion litres) of fuel during the year 2007, which generated 7.7 Mt of carbon dioxide (CO_2) emissions. Double-counting of emissions would occur if a ...
2011-03-01
International Nuclear Information System (INIS)
This patent describes the producing of a refractory metal wherein a sponge refractory metal is produced as an intermediate product by the use of magnesium with the incidental production of magnesium chloride, and wherein residual magnesium is separated from the magnesium chloride and from refractory metal to a vacuum distillation step which fractionally distills the magnesium, the magnesium chloride, and the metal sub-chlorides; the steps of: recovering fractionally distilled vapors of magnesium chloride and metal sub-chlorides from a sponge refractory metal; separately condensing the vapors as separately recovered; and recycling the separately recovered magnesium at a purity of at least about 96%.
1990-09-21
Corrosion resistance characteristic of aluminium bronze containing chromium and zirconium
International Nuclear Information System (INIS)
There are reported the results of corrosion resistance investigation of aluminium bronzes, containing about 8 and 10% of aluminium and modifying quantities of zirconium. The tests of corrosion resistance were carried out in synthetic seawater, in 3% NaCl aqueous solution and in 10% H_2SO_4 aqueous solution, with reference to industrial bronze BA93 (CuAl9Fe3). The bronzes were tested in an annealed, hardened, tempered state and after plastic hot working. The conclusion is that corrosion resistance of aluminium bronzes, especially against selective corrosion, depends more on material structure, resulted form heat treatment, than on chemical composition. (author). 6 refs, 8 figs, 6 tabs.
Energy Technology Data Exchange (ETDEWEB)
Simple frameworks have been developed for estimating the utilization potential of: (a) solar photovoltaic (SPV) pumps; (b) windmill pumps; (c) producer gas based dual fuel engine pumps; and (d) biogas based dual fuel engine pumps for irrigation water pumping in India. The approach takes into account factors such as: solar radiation intensity, wind speed, availability of bovine dung and agri-residues, and their alternative uses, ground water requirements for irrigation and its availability, affordability, and propensity of the users to invest in renewable energy devices, etc. SPV pumps are estimated to have the maximum utilization potential in India, followed by windmill pumps. (author)
2007-05-15
British Library Electronic Table of Contents (United Kingdom)
Feasibility of using fixed bed column of conventional ion exchangers/sorbent and chemical precipitation based processes have been examined for the effective removal of the very low levels of 106Ru activity from NH4NO3 effluent generated during wet processing of rejected sintered depleted uranium fuel pellets. Based on the results, a simple process involving precipitation of cobalt sulphide along with ferric hydroxide was selected and further optimization of process variables was carried out. The optimized process has been found to be highly efficient in reducing 106Ru activity down to extremely low levels.
2011-01-01
Growth of Cr-Nitrides on commercial Ni-Cr and Fe-Cr base alloys to protect PEMFC bipolar plates
British Library Electronic Table of Contents (United Kingdom)
Nitridation of Cr-bearing alloys can yield low interfacial contact resistance (ICR), electrically conductive and corrosion-resistant CrN or Cr2N base surfaces of interest for a range of electrochemical devices, including fuel cells, batteries, and sensors. This paper presents results of exploratory studies of the nitridation of commercially available, high Cr (30-35wt%) Ni-Cr alloys and a ferritic high Cr (29wt%) stainless steel for proton exchange membrane fuel cell (PEMFC) bipolar plates. A high degree of corrosion resistance in sulfuric acid solutions designed to simulate bipolar plate conditions and low ICR values were achieved. Oxygen impurities in the nitriding environment were observed to play a significant role in the nitrided surface structures that formed, with detrimental effect...
2007-01-01
A study on the management of spent fuel storage capacity in South Korea
International Nuclear Information System (INIS)
The saturation of South Korea's at-reactor (AR) spent fuel storage pools will create a necessity for additional spent fuel storage capacity. Because the South Korean government has the plan to increase the number of nuclear power plants from 20 units (end of 2005) to 27 units by 2015, the increase of spent nuclear fuel generation will be accelerated. Because there is no clear national plan for spent nuclear fuel storage and disposal, the utility company (Korea Hydraulic Nuclear Power company) is planning to construct a spent fuel storage facility with 11 000 tHM capacity for Pressurised Water Reactor (PWR). This study is intended to predict the maximum allowable periods when the storage facility will be fully occupied with respect to the already fixed re-racking plan of spent fuel storage pools and construction of new nuclear power plants. The result from this ...
2006-06-19
Energy Technology Data Exchange (ETDEWEB)
The State Energy Conservation Office has executed its first Fuel Cell Project which was awarded under a Department of Energy competitive grant process. The Texas LPG Fuel Processor Development and Fuel Cell Demonstration Program is a broad-based public/private partnership led by the Texas State Energy Conservation Office (SECO). Partners include the Alternative Fuels Research and Education Division (AFRED) of the Railroad Commission of Texas; Plug Power, Inc., Latham, NY, UOP/HyRadix, Des Plaines, IL; Southwest Research Institute (SwRI), San Antonio, TX; the Texas Natural Resource Conservation Commission (TNRCC), and the Texas Department of Transportation (TxDOT). The team proposes to mount a development and demonstration program to field-test and evaluate markets for HyRadix?s LPG fuel processor system integrated into Plug Power?s residential-scale ...
2004-07-26
Field performance of a premium heating oil
Energy Technology Data Exchange (ETDEWEB)
As part of our ongoing research to provide quality improvements to heating oil, Mobil Oil together with Santa Fuel, Inc., conducted a field trial to investigate the performance of a new premium heating oil. This premium heating oil contains an additive system designed to minimize sludge related problems in the fuel delivery system of residential home heating systems. The additive used was similar to others reported at this and earlier BNL conferences, but was further developed to enhance its performance in oil heat systems. The premium heating oil was bulk additized and delivered to a subset of the customer base. Fuel related, unscheduled service calls were monitored in this test area, as well as in a similar baseline area that did not receive the premium heating oil. Overall, the premium fuel provided a 45% reduction in the occurrence of fuel related, ...
1996-07-01
Energy Technology Data Exchange (ETDEWEB)
Non-edible filtered high viscous (72 cSt at 40{sup o}C) and high acid value (44 mg KOH/gm) polanga (Calophyllum inophyllum L.) oil based mono esters (biodiesel) produced by triple stage transesterification process and blended with high speed diesel (HSD) were tested for their use as a substitute fuel of diesel in a single cylinder diesel engine. HSD and polanga oil methyl ester (POME) fuel blends (20%, 40%, 60%, 80%, and 100%) were used for conducting the short-term engine performance tests at varying loads (0%, 20%, 40%, 60%, 80%, and 100%). Tests were carried out over entire range of engine operation at varying conditions of speed and load. The brake specific fuel consumption (BSFC) and brake thermal efficiency (BTE) were calculated from the recorded data. The engine performance parameters such as fuel consumption, thermal efficiency, exhaust gas temperature and exhaust emissions ...
2007-02-15
Evaluation of the performance of a dual fuel engine
Energy Technology Data Exchange (ETDEWEB)
Dual fuel operation, in which natural gas is mixed with the diesel engine intake air and ignition is by diesel fuel spray, has the advantage that engine conversion is simple. Under high load it has the same high efficiency as a diesel engine and it can be switched to normal diesel operation for long distance running. Also, NO{sub x} and black smoke emissions can also be reduced. However, the disadvantages are to increase HC and CO emissions, to reduce efficiency under low load, and to emit the large amount of NO{sub x} under high load. Waseda University was commissioned by Tokyo Gas Co., Ltd. to conduct research program involving experimentation ragarding a dual fuel engine. It was then discovered that the most effective means of solving the problems mentioned above is Exhaust Gas Recirculation (EGR) and that the effect can be increased by heating the intake air. An old engine before the current emission standard was ...
1998-12-31
COOLOD, Steady-State Thermal Hydraulics of Research Reactors
International Nuclear Information System (INIS)
1 - Description of program or function: The COOLOD-N2 code provides a capability for the analyses of the steady-state thermal-hydraulics of research reactors. This code is a revised version of the COOLOD-N code, and is applicable not only for research reactors in which plate-type fuel is adopted, but also for research reactors in which rod-type fuel is adopted. In the code, subroutines to calculate temperature distribution in rod-type fuel have been newly added to the COOLOD-N code. The COOLOD-N2 code can calculate fuel temperatures under both forced convection cooling mode and natural convection cooling mode. A 'Heat Transfer package' is used for calculating heat transfer coefficient, DNB heat flux etc. The 'Heat Transfer package' is a subroutine program and is especially developed for research reactors in which plate-type fuel is adopted. In case of rod-type ...
Heavy fuel oil combustion in a cylindrical laboratory furnace: measurements and modeling
Energy Technology Data Exchange (ETDEWEB)
The finite-volume based commercial CFD-code Fluent was used to simulate the reacting flow in a heavy fuel oil fired laboratory furnace. Both the standard {kappa}-{epsilon} turbulence model and the Reynolds stress model (RSM) were tested. The combustion model was based on the conserved scalar (mixture fraction) and prescribed probability density function approach. The heavy fuel oil droplet trajectories were predicted by solving the momentum equations for the droplets using the Lagrangian treatment. The soot distribution in the furnace was calculated by solving a transport equation for the soot mass fraction. Simple expressions for the soot formation and oxidation rates were employed. The radiation heat transfer equation was solved using the finite volume method. The formation of thermal NO from molecular nitrogen was modeled according to the extended Zeldovich mechanism. Fuel-based ...
2005-03-01
Toxicity of radioactive wastes generated from PEACER spent fuel
Energy Technology Data Exchange (ETDEWEB)
Assessment on the back end fuel cycle, in PEACER (Proliferation-resistant Environmental-friendly Accident-tolerant Continuable and Economical Reactor) that was designated as a new transmutation concept, was performed. Recovery system of uranium and TRU for PEACER is based on pyroprocessing. In the assessment of Long-Lived Fission Products (LLFP) wastes, initially {sup 90}Sr and {sup 137}Cs are dominant contributor nuclides until 30 years and especially {sup 90}Sr and {sup 137}Cs have the highest activity and decay heat than other LLFP. In this study, recovery of {sup 90}Sr and {sup 137}Cs is recommended for reducing of wastes loading. The acceptable decontamination factor is investigated by the toxicity of PEACER spent fuel. The acceptable decontamination factor is about 1.02E+05 for the actinides from PEACER spent fuel after 10 years cooling, 4.26E+05 after 100 years cooling, 1.97E+04 after 300 years ...
2003-10-01
Toxicity of radioactive wastes generated from PEACER spent fuel
International Nuclear Information System (INIS)
Assessment on the back end fuel cycle, in PEACER (Proliferation-resistant Environmental-friendly Accident-tolerant Continuable and Economical Reactor) that was designated as a new transmutation concept, was performed. Recovery system of uranium and TRU for PEACER is based on pyroprocessing. In the assessment of Long-Lived Fission Products (LLFP) wastes, initially "9"0Sr and "1"3"7Cs are dominant contributor nuclides until 30 years and especially "9"0Sr and "1"3"7Cs have the highest activity and decay heat than other LLFP. In this study, recovery of "9"0Sr and "1"3"7Cs is recommended for reducing of wastes loading. The acceptable decontamination factor is investigated by the toxicity of PEACER spent fuel. The acceptable decontamination factor is about 1.02E+05 for the actinides from PEACER spent fuel after 10 years cooling, 4.26E+05 after 100 years cooling, 1.97E+04 after 300 years cooling, 9.52E+03 ...
2003-10-01
International Nuclear Information System (INIS)
The second regular inspection of No.2 plant in Sendai Nuclear Power Station was carried out from October 5, 1987 to January 8, 1988. the parallel operation was resumed on December 8, 1987, 65 days after the parallel off. The facilities as the object of inspection were the reactor proper, reactor cooling system, measurement and control system, fuel facilities, radiation control facilities, waste facilities, reactor containment installation, and emergency power generation system. On these facilities as the object of inspection, the appearance, disassembling, leak, function, performance and other inspections were carried out, and abnormality was not found at all. The works related to this regular inspection were accomplished within the range of allowable dose based on the relevant laws. The main reconstruction works carried out during the period of this regular inspection were the change of the degree of enrichment from 3.15 wt.% to 3.4 wt.% for ...
1988-01-01
Energy Technology Data Exchange (ETDEWEB)
The second regular inspection of No.2 plant in Sendai Nuclear Power Station was carried out from October 5, 1987 to January 8, 1988. the parallel operation was resumed on December 8, 1987, 65 days after the parallel off. The facilities as the object of inspection were the reactor proper, reactor cooling system, measurement and control system, fuel facilities, radiation control facilities, waste facilities, reactor containment installation, and emergency power generation system. On these facilities as the object of inspection, the appearance, disassembling, leak, function, performance and other inspections were carried out, and abnormality was not found at all. The works related to this regular inspection were accomplished within the range of allowable dose based on the relevant laws. The main reconstruction works carried out during the period of this regular inspection were the change of the degree of enrichment from 3.15 wt.% to 3.4 wt.% for ...
1988-08-01
Radionuclide release rates from spent fuel for performance assessment modeling
Energy Technology Data Exchange (ETDEWEB)
In a scenario of aqueous transport from a high-level radioactive waste repository, the concentration of radionuclides in water in contact with the waste constitutes the source term for transport models, and as such represents a fundamental component of all performance assessment models. Many laboratory experiments have been done to characterize release rates and understand processes influencing radionuclide release rates from irradiated nuclear fuel. Natural analogues of these waste forms have been studied to obtain information regarding the long-term stability of potential waste forms in complex natural systems. This information from diverse sources must be brought together to develop and defend methods used to define source terms for performance assessment models. In this manuscript examples of measures of radionuclide release rates from spent nuclear fuel or analogues of nuclear fuel are presented. Each example ...
1994-11-01
Oxygen carriers for chemical looping combustion of solid fuels
Energy Technology Data Exchange (ETDEWEB)
A thermal analyzer-differential scanning calorimeter-mass spectrometer (TG-DSC-MS) was used to study oxygen carriers (OC) for their potential use for the application of chemical looping combustion (CLC) to solid fuels. Reaction rates, changes in reaction rates with repeated oxidation-reductions, exothermic heats during oxidation, and the effect of changing reduction gas compositions were studied. Oxidation rates were greater than reduction rates and reaction rates were reproducible through multiple oxidation-reduction cycles except where agglomeration occurred with powders. Iron oxide (Fe{sub 2}O{sub 3} powder) and iron-based catalysts were found suitable for CLC of solid fuels having rapid reduction rates which increased with higher reducing gas concentrations. Fe{sub 2}O{sub 3} powder was used to oxidize a high carbon coal char in an inert gas removing 88% of the carbon from the char. Other properties such as cost and ...
2009-05-15
Under the auspices of the DOE and private industry, considerable progress has been made in: preparation of coal-water fuels; combustion of low-ash coal-based fuel forms; processes to provide deeply-cleaned coal. Developments in advanced beneficiation of coal to meet stringent requirements for low ash and low sulfur can be anticipated to further complicate the problem areas associated with this product. This is attributable to the beneficiated coal being procured in very fine particles with high surface areas, modified surface characteristics, reduced particle size distribution range, and high inherent moisture. Experience in the storage, handling, and transport of highly beneficiated coal has been limited. This is understandable, as quantities of such product are only now becoming available in meaningful quantities. During this reporting period the authors have: developed a suite of empirical tests covering water retention, ...
1993-01-01
Fuel management at the Petten high flux reactor
Energy Technology Data Exchange (ETDEWEB)
Several years ago the shipment of spent fuel of the High Flux Reactor (HFR) at Petten has come to a standstill resulting in an ever growing stock of fuel elements that are labelled 'fully burnt up'. Examination of those elements showed that a reasonably number of them have a relatively high {sup 235}U mass left. A reactor physics analysis showed that the use of such elements in the peripheral core zone allows the loading of four instead of five fresh fuel elements in many cycle cores. For the assessment of safety and performance parameters of HFR cores a new calculational tool is being developed. It is based on AEA Technology's Reactor physics code suite Winfrith Improved Multigroup Scheme (WIMS). NRG produced pre- and post-processing facilities to feed input data into WIMS's 2D transport code CACTUS and to extract relevant parameters from the output. The processing ...
1999-07-01
International Nuclear Information System (INIS)
It is very well known that the CANDU reactor has positive Coolant Void Reactivity (CVR), which is most important criticisms about CANDU. The most recent innovations based on using a thin absorbent Hafnium shell in the central bundle element were successfully been applied to the Advanced CANDU Reactor (ACR) project. The paper's objective is to analyze elementary lattice cell effects in applying such methods to reduce the CVR. Three basic fuel designs in their corresponding geometries were chosen to be compared: the ACR-1000TM, the RU-43 (developed in INR Pitesti) and the standard CANDU fuel. The bundle geometry influence on void effect was also evaluated. The WIMS calculations proved the Hafnium absorber suitability (in the latest 'shell design') to achieve the negative CVR target with great accuracy for the ACR-1000 fuel bundle design than for the other two projects. (authors)
2009-05-27
Evaluation of light-water-moderated, mixed-oxide, hexagonal pitch lattices
International Nuclear Information System (INIS)
The use of previously measured mixed-oxide (MOX) fuel systems as benchmarks can be valuable tool in computational analysis and quality assurance efforts. The Fissile Materials Disposition Program (FMDP) has identified these experiments as potential benchmarks, or standards, for VVER's employing MOX fuel. Standards for the analysis of these benchmark experiments were based on those used in the recent compilation International Handbook of Evaluated Criticality Safety Benchmark Experiments begun in 1992 by the U.S. Department of Energy. The Los Alamos National Laboratory's archives were explored for log-book records of these experiments without success. These experiments were the first to use MOX fuel in light water. Three approach-to-critical experiments were performed using fuel rods at various pitches and different plutonium-oxide concentrations. A parallel program verified the ...
1997-11-16
Drop Test of the Candu Spent Fuel Storage Basket in MACSTOR/KN-400
International Nuclear Information System (INIS)
The MACSTOR/KN-400 of Wolsung power plant in Korea is a dry interim storage facilities. There are 400 long slender cylinders in MACSTOR/KN-400. In one cylinder, ten baskets where Candu spent fuels are loaded are stacked and stored. For this MACSTOR/KN-400 facilities, analyses and tests for the hypothetical accident conditions that might happen during moving and storing baskets into a cylinder were performed. The hypothetical accident conditions to be considered are two cases. One is the case of basket dropping onto the bottom plate of a cylinder. The other is the case of basket dropping onto the other basket top plate stored in the cylinder. For the drop analyses, the case of hanging cylinder and the case of cylinder on the unyielding target surface were considered. Based on the dropping analysis, testing condition was determined as the latter case that is for the cylinder on the target surface. In a basket, 60 dummy fuel ...
2009-06-01
Development of the Regulation Concept for a Fusion Reactor
International Nuclear Information System (INIS)
Fusion energy has been studied in many countries such as U.S., France, Japan, Korea etc. Because it would provide much more energy for a given weight of fuel than any technology currently in use, and the fuel itself (primarily deuterium) exists abundantly in the Earth's ocean. Nuclear fusion reactor uses tritium and deuterium as fuel while nuclear fission reactor uses uranium and plutonium as fuel. Besides, inherent design characteristics and driving condition of nuclear fusion reactor is different from those of nuclear fission reactor. Therefore, we cannot apply the regulation rules of nuclear fission reactor to nuclear fusion reactor without change and thus it is needed to development of the safety regulation concept which reflects the characteristics of nuclear fusion reactor. Safety regulation of nuclear fusion reactor employs deterministic approach until sufficient data are secured. However, ...
2010-10-01
International Nuclear Information System (INIS)
A high-performance power system (HIPPS) is being developed. This system is a coal-fired, combined-cycle plant that will have an efficiency of at least 47 percent, based on the higher heating value of the fuel. The original emissions goal of the project was for NOx and SOx to each be below 0.15 lb/MMBtu. In the Phase 2 RFP this emissions goal was reduced to 0.06 lb/MMBtu. The ultimate goal of HIPPS is to have an all-coal-fueled system, but initial versions of the system are allowed up to 35 percent heat input from natural gas. Foster Wheeler Development Corporation is currently leading a team effort with AlliedSignal, Bechtel, Foster Wheeler Energy Corporation, Research-Cottrell, TRW and Westinghouse. Previous work on the project was also done by General Electric. The HIPPS plant will use a high-Temperature Advanced Furnace (HITAF) to achieve combined-cycle operation with coal as the primary fuel. The ...
1995-07-12
International Nuclear Information System (INIS)
A method for express determination of "2"3"4"-"2"3"8U, "2"3"8"-"2"4"2Pu, "2"4"1"-"2"4"3Am and "2"4"2"-"2"4"4Cm content in fuel 'hot' particles and spent nuclear fuel is offered. The method is based on precision measurement of a sample #alpha# activity followed by estimate of relative contributions of individual nuclides, or groups of radionuclides, to total activity. Segregation in separate fractions of uranium, plutonium, americium and curium was made with the help of ion-exchange chromatography. Results are presented of "2"3"4"U, "2"3"8U, "2"3"8"Pu,"2"3"9"+"2"4"0Pu, "2"4"1Pu, "2"4"2Pu, "2"4"1"Am, "2"4"2"mAm, "2"4"3Am "2"4"2"Cm and "2"4"4Cm definition in 'hot' particles sampled in Chernobyl NPP surroundings, Opportunities to apply this method for identifying radionuclide content of spent nuclear fuel are discussed.
Energy Technology Data Exchange (ETDEWEB)
A sequential port injection, lean-burn, fully electronically-controlled compressed natural gas (CNG)/diesel dual-fuel engine has been developed based on a turbo-charged and inter-cooled direct injection (D.I.) diesel engine. During the optimisation of engine overall performance, the effects of pilot diesel and premixed CNG/air mixture equivalence ratio on emissions (CO, HC, NO{sub x}, soot), knocking, misfire and fuel economy are studied. The rich and lean boundaries of the premixed CNG/air mixture versus engine load are also provided, considering the acceptable values of NO{sub x} and THC emissions, respectively. It is interesting to find that there is a critical amount of pilot diesel for each load and speed point, which proved to be the optimum amount of pilot fuel. Any decrease in the amount of pilot diesel from this optimum amount results in an increase of NO{sub x} emissions, because the premixed ...
2003-07-01
A dynamic model of a locomotive diesel engine and electrohydraulic governor
Energy Technology Data Exchange (ETDEWEB)
As part of a comprehensive simulation of a prototype locomotive propulsion system, a detailed model has been developed which predicts the dynamic response of an experimental 2-stroke, turbocharged and intercooled diesel engine. Engine fueling and brake torque are computed from regression equations derived from an extensive data base. Corrections are applied to the calculated steady-state torque to account for dynamic deviations of in-cylinder trapped air-fuel ratio from the steady-state value. The engine simulation accurately represents the operation of the turbo-charger, which is gear-driven at low turbocharger speeds, and freewheels through an overrunning clutch when exhaust energy accelerates the turbocharger beyond its geared speed. Engine fueling level, ie, rack, is determined from a dynamic simulation of an electrohydraulic governor which responds to the difference between the desired and the ...
1988-01-01
Least cost electricity generation options based on environmental impact abatement
Energy Technology Data Exchange (ETDEWEB)
The power sector in Thailand is the largest contributor to CO{sub 2} emissions. There is high potential to mitigate CO{sub 2} emission via alternative power generating plants. Alternative plants considered in this study include nuclear plants, integrated gasification combined cycle plants, biomass-based plants and supercritical thermal power plants. The biomass-based plants considered here are fueled with four types of biomass; paddy husk, municipal solid waste (MSW), fuel wood and corncob. The methodology for the optimal expansion plan of the power generating system over the planning horizon is based on the least-cost approach. The results from the least-cost planning analyses show that the nuclear alternative has the highest potential to mitigate not only CO{sub 2} but also other airborne emissions. Moreover, the nuclear option is the most effective abatement strategy for CO{sub ...
2003-12-01
Evaluation method for grate combustion (EMGC); Utvaerderingsmetod foer eldning i rostpannor
Energy Technology Data Exchange (ETDEWEB)
The aim with this project sponsored by Energimyndigheten is to develop a method for calculations of grate boilers fueled by bark. This report describes this project, 'Evaluation Method for Grate Combustion' (EMGC). CFD codes is an engineering tool applicable in the area of the over-grate section called the furnace. This part of the boiler is easy to model for an experienced CFD code user and the results are usually quite satisfactory for evaluating the combustion process in general. Various gas phases reactions and related combustion processes over the burning bed can be simulated including air staging, fuel staging and SNCR. However the simulation needs information of amount and properties of the burning bed products, entering the furnace. The simulation of the in-furnace processes without this information is often just a numerical speculation. A predictive mathematical model based on physical and ...
2000-04-01
SOME RECENT DETERMINATIONS OF ATOMIC MASSES IN THE STRONTIUM-ZIRCONIUM REGION
A large double-focusing mass spectrometer was used to obtain new values for the masses of Sr/sup 86/, Sr/sup 88/, and Zr/sup 90/. Mass differences calculated from these values are found to be in better agreement with nuclear transmutation information than were previous mass spectroscopically derived values. (auth)
1960-06-01
Recent process developments at the SOMAIRE uranium mill
International Nuclear Information System (INIS)
This paper reviews the mill flowsheet applied at the SOMAIR (Societe des Mines de l'Air) uranium mill in Niger. It focuses on the yellow cake quality improvements achieved by molybdenum and zirconium elimination through double yellow cake precipitation in tanks at first stage and through size/density control in a fluidized bed precipitator at second stage. Water saving aspects in the plant are also presented. (author)
2000-09-09
Method of altering the permeability of a subterranean formation
The production of water from a subterranean formation is reduced by contacting the formation with a water dispersible hydrophilic organic polymer having a molecular weight greater than 100,000 and containing carboxyl functionality and a crosslinking composition comprising water, a zirconium compound having a value of 4+, an alpha-hydroxy acid and an amine compound.
1985-06-25
Integral testing of the evaluated data files for silicon, zirconium, niobium and iron
Energy Technology Data Exchange (ETDEWEB)
The evaluated data testing for Si, Zr, Nb and Fe materials has been performed through the analyses of the neutron leakage spectrum from spherical assemblies measured in integral benchmark experiments with (d,t) and Cf fission neutron sources. Intercomparisons of the calculated from BROND-2, ENDF/B-6 and JENDL-3 data files with experimental results are presented.
1994-12-31
Hydrogen-induced phase transformations in H-storing alloys of zirconium
Energy Technology Data Exchange (ETDEWEB)
In this work, the ability of a number of Zr-containing intermetallic compounds with the Zr{sub 2}Me stoichiometry, including Zr{sub 2}Fe, Zr{sub 2}Ni, Zr{sub 2}Co and Zr{sub 4}Fe{sub 2}O{sub 0.6}, to participate in the Hydrogenation-Disproportionation-Desorption-Recombination process was investigated, revealing for the first time that the HDDR route can be employed successfully for all these compounds. 24 refs.
1998-07-01
Energy Technology Data Exchange (ETDEWEB)
An austenitic alloy having good thermal stability and resistance to sodium corrosion at 700.degree. C. consists essentially of 35-45% nickel 7.5-14% chromium 0.8-3.2% molybdenum 0.3-1.0% silicon 0.2-1.0% manganese 0-0.1% zirconium 2.0-3.5% titanium 1.0-2.0% aluminum 0.02-0.1% carbon 0-0.01% boron and the balance iron.
1983-01-01
Correlation between electrochemical properties and corrosion resistance of zirconium alloys
International Nuclear Information System (INIS)
The electrochemical behavior of some zirconium alloys including Zry-2 with various #SIGMA#Ai from 2.5 x 10"-"2"0 to 1.2 x 10"-"1"7 (h), modified Zry-2 with iron contents of 0.15, 0.25, and 0.5%, and standard Zry-4 was studied by measuring anodic polarization curves in sulfuric acid solution. The results of these electrochemical tests were compared with those of steam autoclave tests. In Zry-2, the current peak was observed at 1250 mV (versus SCE) on the anodic polarization curve, and this peak area increased with #SIGMA#Ai and with the size of secondary precipitates. Also, this peak was closely correlated with nodular corrosion resistance as expected from the above results. As iron contents in modified Zry-2 increased, the current peak at 1,250 mV decreased and a new peak at 1,900 mV appeared. The former peak disappeared and the latter peak increased further at 0.5% iron. In Zry-4, the current peak was observed at 1,900 mV, but not at 1,250 mV, and this behavior ...
1995-09-11
Glass-ceramic sealants for solid oxide fuel cells: Part I. Physical properties
International Nuclear Information System (INIS)
A family of sealant materials has been developed for use in the solid oxide fuel cell (SOFC) and in other applications in the temperature range of 800 endash 1000 degree C. These materials are based on glasses and glass-ceramics in the SrO endash La_2O_3 endash Al_2O_3 endash B_2O_3 endash SiO_2 system. The coefficients of thermal expansion (CTE) for these materials are in the range of 8 endash 13x10"-"6/degree C, a good match with those of the SOFC components. These sealant materials bond well with the ceramics of the SOFC and, more importantly, form bonds that can be thermally cycled without failure. At the fuel cell operating temperature, the sealants have viscosities in the range of 10"4-10"6 Pa-s, which allow them to tolerate a CTE mismatch of about 20% among the bonded substrates. The gas tightness of a sample seal was demonstrated in a simple zirconia-based oxygen concentration cell. copyright ...
Transportation cost of nuclear off-peak power for hydrogen production based on water electrolysis
International Nuclear Information System (INIS)
The paper describes transportation cost of the nuclear off-peak power for a hydrogen production based on water electrolysis in Japan. The power could be obtainable by substituting hydropower and/or fossil fueled power supplying peak and middle demands with nuclear power. The transportation cost of the off-peak power was evaluated to be 1.42 yen/kWh when an electrolyser receives the off-peak power from a 6kV distribution wire. Marked reduction of the cost was caused by the increase of the capacity factor. (author)
Energy Technology Data Exchange (ETDEWEB)
Coal-water-slurry (CWS) engine tests designed to evaluate a new accumulator-based injection system are described in this paper The new injection system was found to improve CWS burnout considerably at both full and part engine loads. The peak cylinder firing pressure when operating with CWS was no higher than when operating with diesel oil. These data demonstrates the improved engine performance that can be achieved with the accumulator-based injection system.
1989-07-01
Optimization of cleaning timing and load allocation in steam generator management
Energy Technology Data Exchange (ETDEWEB)
A method for cleaning timing optimization in a parallel steam generator system is described. The method is based on the minimization of a suitable objective function, and takes into account the load allocation on steam generators. In order to establish appropriate fouling growth models the mechanism of the particle deposition and removal on heat transfer surfaces is analyzed. The objective function is related to the short time management costs which are based on depreciation of steam generators, fuel costs and the costs of cleaning interventions. The optimization problem is described; a direct one level method is compared with a two level method. Some applications and their results are reported and discussed. (author)
1998-03-01
Energy Technology Data Exchange (ETDEWEB)
The overall goal of the Coal Liquefaction Program of the Office of Coal Technology (OCT) is to develop the scientific and engineering knowledge base with which industry can bring economically competitive and environmentally acceptable advanced technology for manufacturing synthetic liquid fuels from coal into the marketplace when needed. The technical goal of the Coal Liquefaction Program is to seek advanced and innovative improvements over the state-of-the-art processes for coal liquefaction that can utilize all major parts of the US coal resource base. A technology description and discussion of program goals and strategy is provided in this report. 2 figs.
1989-09-01
Energy Technology Data Exchange (ETDEWEB)
Research is presented on oil and gas technologies, advanced systems, soil remediation and remediation of acid mine drainage, applied science research in plastics and petroleum coprocessing, and fossil fuel and hydrocarbon conversion using a hydrogen rich plasmas.
1997-05-01
Korea-IAEA Unattended Safeguards Approach on the Spent Fuel Transfer to Dry Storage in Wolsung NPP
Energy Technology Data Exchange (ETDEWEB)
The field trial of an unattended monitoring system for SF transfer verification ended in June 2005. The system is aiming to improve the safeguards measures applied during SF transfers and reduce inspection effort currently required by the Operator, NNCA and the IAEA. They were reviewed based on its technical performance and other issues in this paper.
2006-07-01
Korea-IAEA Unattended Safeguards Approach on the Spent Fuel Transfer to Dry Storage in Wolsung NPP
International Nuclear Information System (INIS)
The field trial of an unattended monitoring system for SF transfer verification ended in June 2005. The system is aiming to improve the safeguards measures applied during SF transfers and reduce inspection effort currently required by the Operator, NNCA and the IAEA. They were reviewed based on its technical performance and other issues in this paper.
2006-05-25
Government to buy low-cost energy from non-utility sources
Energy Technology Data Exchange (ETDEWEB)
Power generated by manufacturers and third-party suppliers in venture capital projects is available to military and other government users at a cost 10 to 20% lower. Tax benefits and other financial incentives keep suppliers' costs low. Users are required to contract for a minimum amount of energy over a 20- to 30-year period. Military use of these energy projects includes sources based on solar energy, cogeneration, geothermal heat, and refuse-derived fuel. (DCK)
1983-04-04
Evaluation of the SYNTHOIL process. Volume II. Status of development. [47 refs
The Synthoil process for producing heavy desulfurized fuel oil from coal has been under development at Pittsburgh Energy Research Center since 1969. The status of development and technical feasibility of the process are reviewed. This is part of an engineering and economic evaluation based on the conceptual design of a 100,000-bbl/day commercial Synthoil facility. Experimental data are discussed with regard to their adequacy for the formulation of a basis for the process design of such a facility. Potential engineering and equipment problems are analyzed.
1977-06-01
Energy Technology Data Exchange (ETDEWEB)
This retrospective bibliography contains citations concerning economic analysis of the techniques and technology for cogeneration and the effects of government policies and industrial attitudes toward cogeneration. Combined energy systems and combined manufacturing/energy systems which utilize waste heat and waste products as well as traditional fuels are included. (Contains 71 citations, fully indexed and including a table of contents.)
1980-12-01
Direct Energy Conversion: a current awareness bulletin
This current awareness bulletin announces on a semimonthly basis the current worldwide information entered into the Energy Data Base on all aspects of direct energy conversion. Categories include photovoltaic conversion, magnetohydrodynamic generators, electrohydrodynamic generators, thermoelectric generators, thermionic converters, fuel cells, and miscellaneous converters. An abstract is inclluded with each citation. (WHK)
1985-01-15
Computer analysis and control for nondestructive gamma scanning of LMFBR fuel pins
International Nuclear Information System (INIS)
A program to modernize existing computer control and data analysis in a precision gamma-scanning system is described. This involves interfacing a new computer-based multichannel analyzer to existing equipment through a CAMAC system with an intelligent crate controller and writing software for scan control and data reduction. Both hardware and software requirements are discussed. 6 figures.
CAPSULE REPORT: BAHCO FLUE GAS DESULFURIZATION AND PARTICULATE REMOVAL SYSTEM
This capsule report describes a Research-Cottrell/Bahco scrubber module for sulfur dioxide and particulate emission control located at the central heat plant of Rickenbacker Air Force Base. he report also describes flue gas desulfurization technology using any fuel, including hig...
200 Area Interim Storage Area Technical Safety Requirements
Energy Technology Data Exchange (ETDEWEB)
The 200 Area Interim Storage Area Technical Safety Requirements define administrative controls and design features required to ensure safe operation during receipt and storage of canisters containing spent nuclear fuel. This document is based on the 200 Area Interim Storage Area, Annex D, Final Safety Analysis Report which contains information specific to the 200 Area Interim Storage Area.
2000-03-15
Marketers report on oil quality
Energy Technology Data Exchange (ETDEWEB)
The quality of fuel oils is discussed. The problems that the fuel oil marketer must deal with that relate to the quality of the fuel oil are described.
1985-04-01
Liquid hydrocarbon fuel composition
Energy Technology Data Exchange (ETDEWEB)
A fuel composition comprising a liquid hydrocarbon fuel and a detergent amount of the product of reaction between a polyamine and a stearic acid is described.
1983-07-19
Understanding and predicting soot generation in turbulent non-premixed jet flames.
Energy Technology Data Exchange (ETDEWEB)
This report documents the results of a project funded by DoD's Strategic Environmental Research and Development Program (SERDP) on the science behind development of predictive models for soot emission from gas turbine engines. Measurements of soot formation were performed in laminar flat premixed flames and turbulent non-premixed jet flames at 1 atm pressure and in turbulent liquid spray flames under representative conditions for takeoff in a gas turbine engine. The laminar flames and open jet flames used both ethylene and a prevaporized JP-8 surrogate fuel composed of n-dodecane and m-xylene. The pressurized turbulent jet flame measurements used the JP-8 surrogate fuel and compared its combustion and sooting characteristics to a world-average JP-8 fuel sample. The pressurized jet flame measurements demonstrated that the surrogate was representative of JP-8, with a somewhat higher tendency to soot formation. The ...
2010-10-01
Research guidance studies. Quarterly progress report, April--June 1996
The overall objective of this project is to provide research guidance and quantification of research progress in the areas of direct and indirect coal liquefaction, coal/waste coprocessing, refining of coal-derived liquid fuels, and natural gas conversion. Specifically, the work is divided into two subtasks that relate to whether the technology application is direct or indirect. In subtask (a), Direct Coal Liquefaction technology is the subject of the analyses, and in subtask (b), Indirect Liquefaction, technologies will be evaluated in accordance with the priorities of the COR. Mitretek Systems has been developing detailed computer simulation models of direct and indirect coal and natural gas conversion systems for several years. These models are constantly being updated and improved as more data and better cost information becomes available. These models also include detailed refinery models based on bench-scale upgrading data of coal derived ...
1996-12-31
Dual-fuel engine developments at MAN B&W
Energy Technology Data Exchange (ETDEWEB)
MAN B&W in Augsburg, Germany has further developed its dual-fuel line of engines with the 32/40 DG engine family. These engines, with prechamber injection, augment the company`s spark-ignited gas and dual-fuel engines based on its four-stroke diesel engines. MAN B&W`s power range is between 400 and 16200 kW. Based on the well-proven 32/ 40 engine, the 32/40 DG dual-fuel engine was developed mainly for stationary applications in cogeneration plants and power stations, covering an output range from 2.4 to 7.2 MW. The engine line (bore 320 x stroke 400 mm) has a cylinder output of 400 kW at 750 r/min and a bmep of 19.9 bar with a maximum efficiency of 44.4%. The development focused on meeting TA Luft limits for NO{sub x} emissions of less than 500 mg/m{sup 3} NO{sub x}. This level was targeted without catalytic exhaust after treatment (SCR) and retaining high efficiency and ...
1995-10-01
Energy Technology Data Exchange (ETDEWEB)
A general criterion has been suggested for deep geological repositories containing spent fuel - the repositories should impose no greater radiological risk than due to naturally occurring uranium deposits. The following analysis investigates the rationale of that suggestion and determines whether current expectations of spent-fuel repository performance are consistent with such a criterion. In this study, reference spent-fuel repositories were compared to natural uranium-ore deposits. Comparisons were based on intrinsic characteristics, such as radionuclide inventory, depth, proximity to aquifers, and regional distribution, and actual and potential radiological consequences that are now occurring from some ore deposits and that may eventually occur from repositories and other ore deposits. The comparison results show that the repositories are quite comparable to the natural ore deposits and, in some ...
1980-09-01
Safety-technical characteristics of biomass, coal and straw. Final report
Energy Technology Data Exchange (ETDEWEB)
Safety-technical factors related to spontaneous ignition and dust explosions of biomasses were investigated. Parametres of dust explosions and effect of inertisation on the maximum pressure (pmax) and the maximum rate of pressure rise (Kstmax) were studied at elevated initial pressure (1-9 bar). The level of inertisation required to prevent dust explosions totally was determined at different initial pressures. The sensitivity of fuels to spontaneous ignition and the effect of pressure on the sensitivity to and temperature of spontaneous ignition were studied on a pressurised dynamic self-ignition equipment. The effect of inertisation on the self-ignition temperature and alternatives of preventing spontaneous ignition by effective inertisation in the pressure ranges of 1 and 25 bar were investigated. As an example of application, results obtained with the laboratory test equipment were extrapolated to bin sizes used in practice. As a factor contributing to ...
1995-12-31
Energy Technology Data Exchange (ETDEWEB)
The Federal Aviation Administration (FAA) identified 17 accidents that may have resulted from fuel tank explosions on commercial aircraft from 1959 to 2001. Seven events involved JP 4 or JP 4/Jet A mixtures that are no longer used for commercial aircraft fuel. The remaining 10 events involved Jet A or Jet A1 fuels that are in current use by the commercial aircraft industry. Four fuel tank explosions occurred in center wing tanks (CWTs) where on-board appliances can potentially transfer heat to the tank. These tanks are designated as ''Heated Center Wing Tanks'' (HCWT). Since 1996, the FAA has significantly increased the rate at which it has mandated airworthiness directives (ADs) directed at elimination of ignition sources. This effort includes the adoption, in 2001, of Special Federal Aviation Regulation 88 of 14 CFR part 21 (SFAR 88 ...
2007-02-07
Numerical methods for multiphysics, multiphase, and multicomponent models for fuel cells
In this dissertation, we design and analyze efficient numerical methods for obtaining accurate solutions to model problems arising in fuel cells. A basic fuel cell model consists of five principles of conservation, namely, mass, momentum, species, charges (electrons and ions), and thermal energy. Overall, transport equations couple with electrochemical processes through source terms to describe reaction kinetics and electro-osmotic drag in the polymer electrolyte. To model multiphase species transport in the porous media and the gas channel of fuel cells, we consider a multiphase mixture model framework. The diffusivity of the two-phase mixture water conservation equation in this model is nonlinear, discontinuous, and degenerate. To handle this difficulty, we developed efficient and fast nonlinear iterative solvers based on the Kirchhoff transformation and nonlinear Dirichlet-Neumann domain ...
2008-01-01
Energy Technology Data Exchange (ETDEWEB)
This proceedings volume is organized into seven sections that reflect the materials systems and issues of electrochemical materials R and D in batteries, fuel cells, and capacitors. The first three parts are largely devoted to lithium ion rechargeable battery materials since that electrochemical system has received much of the attention from the scientific community. Part 1 discusses cathodes for lithium ion rechargeable batteries as well as various other battery systems. Part 2 deals with electrolytes and cell stability, and Part 3 discusses anode developments, focusing on carbon and metal oxides. Part 4 focuses on another rechargeable system that has received substantial interest, nickel/metal hydride battery materials. The next two parts discuss fuel cells--Part 5 deals with Proton Exchange Membrane (PEM) fuel cells, and Part 6 discusses oxide materials for solid oxide fuel cells. The former has the ...
2000-07-01
International Nuclear Information System (INIS)
For higher U-loading in low-enriched U-10 wt.%Mo fuels, monolithic fuel plate clad in AA6061 is being developed as a part of Reduced Enrichment for Research and Test Reactor (RERTR) program. This paper reports the first characterization results from a monolithic U-10 wt.%Mo fuel plate with a Zr diffusion barrier that was fabricated as part of a plate fabrication campaign for irradiation testing in the Advanced Test Reactor (ATR). Both scanning and transmission electron microscopy (SEM and TEM) were employed for analysis. At the interface between the Zr barrier and U-10 wt.%Mo, going from Zr to U(Mo), UZr_2, #gamma#-UZr, Zr solid-solution and Mo_2Zr phases were observed. The interface between AA6061 cladding and Zr barrier plate consisted of four layers, going from Al to Zr, (Al, Si)_2Zr, (Al, Si)Zr_3 (Al, Si)_3Zr, and AlSi_4Zr_5. Irradiation behavior of these intermetallic phases is discussed based on ...
2010-07-01
Questions and Answers on Changes to the Renewable Fuel Standard...
fuel obligation under the RFS2 program for the production or importation of conventional jet fuel, RINs can be generated for renewable jet fuel. Is that right? A: As described in...
2011-08-18
GHG Inventories & Forecasts: National Inventories and Forecasts...
of different transportation fuels (e.g., gasoline, diesel fuel, aviation gasoline, jet fuel, residual fuel oil). Subsequent calculations are performed to estimate the share...
2011-08-26
Energy Technology Data Exchange (ETDEWEB)
Chapter 2 describes the worldwide increase of primary energy consumption, which is expected in coming decades and results in possible solutions of a decentralised energy supply that is mainly based upon renewable energy carriers and the use of cogeneration systems. Chapter 3 shows the characteristics of decentralised system components that have been investigated in the frame of this research work as well as the resulting model library to depict the operational performance of the individual components and their mutual influence. A detailed dynamic simulation of a complete fuel cell system based on a steam reformer including the concept of local and superordinate control circuits is presented in chapter 4. Chapter 5 includes the integrated concepts for the intelligent and adaptable management of complex decentralised energy systems as well as a description of their implementation. Apart from the applied metaheuristic ...
2007-06-28
International Nuclear Information System (INIS)
A series of separation experiment was performed in order to study a multi-functional spent fuel reprocessing process based on ion-exchange technique. The tertiary pyridine-type anion-exchange resin was used in this experiment and the mixed oxide fuel highly irradiated in the experimental fast reactor ''JOYO'' was used as a reference spent fuel. As the result, "1"0"6Ru + "1"2"5Sb, "1"3"7Cs + "1"5"5Eu + "1"4"4Ce, plutonium, americium and curium could be separated from the irradiated fuel by only three steps of ion-exchange. The decontamination factor of "1"3"7Cs and trivalent lanthanides ("1"5"5Eu, "1"4"4Ce) in the final americium product exceeded 3.9 x 10"4 and 1.0 x 10"5, respectively. The decontamination factor for the mutual separation of "2"4"3Cm and "2"4"1Am was larger than 2.2 x 10"3 for the americium product and, moreover, the content of "1"3"7Cs, trivalent lanthanides and ...
2006-06-01
Energy Technology Data Exchange (ETDEWEB)
The burning characteristics of fuel droplets containing nano and micron-sized aluminum particles were investigated. Particle size, surfactant concentration, and the type of base fluid were varied. In general, nanosuspensions can last much longer than micron suspensions, and ethanol-based fuels were found to achieve much better suspension than n-decane-based fuels. Five distinctive stages (preheating and ignition, classical combustion, microexplosion, surfactant flame, and aluminum droplet flame) were identified for an n-decane/nano-Al droplet, while only the first three stages occurred for an n-decane/micron-Al droplet. For the same solid loading rate and surfactant concentration, the disruption and microexplosion behavior of the micron suspension occurred later with much stronger intensity. The intense droplet fragmentation was accompanied by shell rupture, ...
2011-02-15
Synthetic fuels at Sasol; Les carburants de synthese chez Sasol
Energy Technology Data Exchange (ETDEWEB)
Sasol, a South-African company, has converted coal into synthetic fuels for 40 years; in order to increase by 6 pc its annual production (40 Mt coal are processed), Sasol has launched the Sky High project and intends to replace the ancient Sasol Synthol reactors by Advanced Synthol reactors using conventional fluidized beds instead of circulating fluidized beds. Coal is first gasified under high pressure and high temperature conditions (the Secunda site uses the Fischer-Tropsch conversion process) and is then processed in the reactor through a single phase process using an iron-base catalyst, leading to significant cost reductions.
1998-11-01
International Nuclear Information System (INIS)
Ceramic fuel element is one of the most important items of HTGR technology, and the corrosion resistance of is matrix materials is vital to the operational performance of HTGR. In the paper, based on the oxidation study of the matrix materials, it has been proposed that the corrosion resistance of the matrix materials might be improved through forming carbon -ceramic composite. The experiment results have shown that the corrosion resistance of matrix materials has been improved by addition of SiC superfine powders, and that the matrix materials containing SiC superfine powders and heat-treated at 1600 deg. C had an oxidation rate lower than the general one containing no SiC superfine powder and heat-treated at 1950 deg. C. (author). 5 refs, 8 figs.
1995-01-01
Reduction of statistic error in Mihalczo subcriticality measurement
Energy Technology Data Exchange (ETDEWEB)
The theoretical formula for the statistical error estimation in Mihalczo method was derived, and the dependence of the error were investigated on the facility to be measured and on the parameter in the data analysis. The formula was derived based on the reactor noise theory and the error theory for the frequency analysis, and found that the error depends on such parameters as the prompt neutron decay constant, detector efficiencies, and the frequency bandwidth. Statistical errors estimated with the formula was compared with experimental values and verified to be reasonable. Through parameter surveys, it is found that there is an optimum combination of the parameters to reduce the magnitude of the errors. In the experiment performed in DCA subcriticality measurement facility, it is estimated experimentally that the measurement requires 20 minutes to obtain the statistic error of 1% for the keff 0.9. According to the error theory, this might be reduced to 3 seconds ...
1998-08-01
Range of decontamination factor for near-surface disposal of PEACER wastes
Energy Technology Data Exchange (ETDEWEB)
One of the alternative ideas to solve the spent fuel issues, the partitioning and transmutation (P and T) technology has been developed for decades. Moreover, the concept of LILW production from P and T are proposed by Bowman. A PEACER (Proliferationresistant, Environmental-friendly Accident-tolerant, Continuable and Economical Reactor), based on pyrochemical process and Pb-Bi coolant transmutation reactor, has been conceptually designed to be able to convert all PWR spent fuel into low and intermediate level waste for near-surface disposal. In this study, the acceptance criteria for near-surface disposal facility is derived by the methodology for establishment of acceptance criteria. Then acceptable TRU decontamination factor (DF) and LLFP removal efficiency in order to meet acceptance criteria is evaluated.
2005-07-01
Range of decontamination factor for near-surface disposal of PEACER wastes
International Nuclear Information System (INIS)
One of the alternative ideas to solve the spent fuel issues, the partitioning and transmutation (P and T) technology has been developed for decades. Moreover, the concept of LILW production from P and T are proposed by Bowman. A PEACER (Proliferationresistant, Environmental-friendly Accident-tolerant, Continuable and Economical Reactor), based on pyrochemical process and Pb-Bi coolant transmutation reactor, has been conceptually designed to be able to convert all PWR spent fuel into low and intermediate level waste for near-surface disposal. In this study, the acceptance criteria for near-surface disposal facility is derived by the methodology for establishment of acceptance criteria. Then acceptable TRU decontamination factor (DF) and LLFP removal efficiency in order to meet acceptance criteria is evaluated
2005-05-26
British Library Electronic Table of Contents (United Kingdom)
We present a novel fabrication route yielding Raney-platinum film electrodes intended as glucose oxidation anodes for potentially implantable fuel cells. Fabrication roots on thermal alloying of an extractable metal with bulk platinum at 200^oC for 48h. In contrast to earlier works using carcinogenic nickel, we employ zinc as potentially biocompatible alloying partner. Microstructure analysis indicates that after removal of extractable zinc the porous Raney-platinum film (roughness factor ~2700) consists predominantly of the Pt3Zn phase. Release of zinc during electrode operation can be expected to have no significant effect on physiological normal levels in blood and serum, which promises good biocompatibility. In contrast to previous anodes based on hydrogel-bound catalyst particles the ...
2010-01-01
British Library Electronic Table of Contents (United Kingdom)
This work deals with a new route to modify polymer blend morphology in order to improve the porosity of gas diffusion layers (GDLs) for proton exchange membrane fuel cells (PEMFCs). First, electrically conductive polymer-based blends were carefully formulated using a twin-screw extrusion process. Blend electrical conductivity was ensured by the addition of high specific surface area carbon black and synthetic graphite flakes. Final GDL porosity, in particular its macroporosity, was generated by melt blending polyamide 11 (PA11) matrix with polystyrene (PS) followed by PS extraction with tetrahydrofuran (THF) solvent at room temperature. In order to improve GDL porosity by the optimisation of PS dispersion in the PA11 matrix, PA11/PS blends were compatibilised by the addition of 2 wt.-% of ...
2007-01-01
Performance evaluation of low heat rejection engines
Energy Technology Data Exchange (ETDEWEB)
Improving the performance of the Chinese B135 six-cylinder direct injection turbocharged and turbocompounded Low Heat Rejection Engine (LHRE) was based on experimental and analytical studies. The studies were primarily applied on a B1135 single-cylinder LHR engine and a conventional water-cooled B1135 single-cylinder engine. Performance of the B1135 LHRE was worse than that of the conventional B1135 due to a deterioration in the combustion process of the B1135 LHRE. The combustion process was improved and the fuel injection system was redesigned and applied to the B135 six-cylinder LHRE. The new design improved the performance of the LHRE and better fuel economy was realized by the thermal energy recovered from the exhaust gases by the turbocompounding system.
1994-10-01
Parameter study of the LIFE engine nuclear design
British Library Electronic Table of Contents (United Kingdom)
LLNL is developing the nuclear fusion based Laser Inertial Fusion Energy (LIFE) power plant concept. The baseline design uses a depleted uranium (DU) fission fuel blanket with a flowing molten salt coolant (flibe) that also breeds the tritium needed to sustain the fusion energy source. Indirect drive targets, similar to those that will be demonstrated on the National Ignition Facility (NIF), are ignited at 13Hz providing a 500MW fusion source. The DU is in the form of a uranium oxycarbide kernel in modified TRISO-like fuel particles distributed in a carbon matrix forming 2-cm-diameter pebbles. The thermal power is held at 2000MW by continuously varying the 6Li enrichment in the coolants. There are many options to be considered in the engine design including target yield, U-to-C ratio in th...
2010-01-01
Energy Technology Data Exchange (ETDEWEB)
An emergency shutdown system for high-temperature gas-cooled pebble-bed reactors is proposed in addition to the common absorber rod shutdown system. This system is based on the strongly absorbing effect of small boronated graphite spheres (called KLAK), which trickle in case of emergency by gravity from the top reflector into the reactor core. The inner reflector of the Siemens-Argonaut reactor was substituted by an assembly of spherical Arbeitsgemeinschaft Versuchsreaktor fuel elements, and the shutdown effect was examined by installing well-defined KLAK nests inside this assembly. The purpose was to develop and prove a calculational procedure for determining criticality values for assemblies of large fuel spheres and small absorbing spheres.
1987-09-01
Impedance Spectra of Mixed Conductors: a 2D Study of Ceria
In this paper we develop an analytical framework for the study of electrochemical impedance of mixed ionic and electronic conductors (MIEC). The framework is based on first-principles and it features the coupling of electrochemical reactions, surface transport and bulk transport processes. We utilize this work to analyze two dimensional systems relevant for fuel cell science via finite element method (FEM). Alternate current Impedance Spectroscopy (IS) of a ceria symmetric cell is simulated near equilibrium condition (zero bias) for a wide array of working conditions including variations of temperature and $H_2$ partial pressure on a two dimensional fuel cell sample with patterned metal electrodes. The model shows agreement of IS curves with the experimental literature with the relative error on the impedance being consistently below 2%. Important two-dimensional effects such the effects of thickness decrease and the ...
2009-01-01
Ignition delay as determined in a variable-compression ratio direct-injection diesel engine
Energy Technology Data Exchange (ETDEWEB)
A variable-compression ratio, direct-injection diesel engine (VCR) has been designed and assembled at Southwest Research Institute with the intention of examining the current procedures for rating the ignition quality of diesel fuels and the meaning of ignition delay as an indicator of ignition and combustion quality. Using a slightly modified ASTM D 613 procedure, the engine has been used to rate the ignition quality of 43 different test fuels. The ratings obtained in the VCR engine are compared to the corresponding rating obtained using the standard cetane rating procedure. Some of the problems associated with the standard procedure became apparent during these experiments. The experimental results are discussed in terms of the problems and the advantages of a proposed VCR-based rating procedure.
1987-01-01
British Library Electronic Table of Contents (United Kingdom)
Abstract Dynamic testing of a phosphoric acid-based high temperature PEM fuel cell shows a peculiar phenomenon. A certain current loss is observed after temperature cycling at constant voltage. This loss is incidentally recovered by applying a cell voltage spike to open circuit voltage. Experimental investigations into temperature, cell voltage, and ageing effects show that this phenomenon might occur due to the orientation of the adsorbed phosphate species on the platinum catalyst surface. Along with some supporting literature and experimental results, a hypothesis is presented in order to explain this occurrence. Phosphoric acid adsorption hysteresis on platinum catalyst due to temperature cycling could cause the temporary cell current loss. Electrode potential-dependent molecule symmetr...
2011-01-01
Electrolytic production of hydrogen utilizing photovoltaic cells
Energy Technology Data Exchange (ETDEWEB)
Hydrogen has the potential to serve as both an energy storage means and an energy carrier in renewable energy systems. When renewable energy sources such as solar or wind power are used to produce electrical power, the output can vary depending on weather conditions. By using renewable sources to produce hydrogen, a fuel which can be stored and transported, a reliable and continuously available energy supply with a predictable long-term average output is created. Electrolysis is one method of converting renewable energy into hydrogen fuel. In this experiment we examine the use of an electrolyzer based on polymer-electrolyte membrane technology to separate water into hydrogen and oxygen. The oxygen is vented to the atmosphere and the hydrogen is stored in a small pressure vessel.
1996-10-01
British Library Electronic Table of Contents (United Kingdom)
A dry interim storage facility has been constructed at the Wolsung power plant in Korea. This dry storage facility has seven separated modules. There are 40 long slender cylinders in one module. In one cylinder, ten baskets where sixty CANDU spent fuel bundles are loaded are stacked and stored. For this dry storage facility, analyses and tests for hypothetical accident conditions that might occur while moving and storing the baskets into a cylinder were performed. In a demonstration test, one of test basket models did not satisfy one of the safety-related requirements. Thus, the revised basket designs were generated using a structural evaluation based on finite element analyses and specimen tests. Among these revised designs, one design was chosen as a final revised basket design. The fina...
2011-01-01
Compact Single-Stage Fuel Processor for PEM Fuel Cells. Final report
Energy Technology Data Exchange (ETDEWEB)
Based on observations during the steam reforming of ethanol, the authors conclude that carbon was forming in the steam generator due to the thermal decomposition of ethanol. Since ethanol is being thermally decomposed, they were operating the steam generator at too high of a temperature. The thermal degradation of ethanol was confirmed by using a GC with a flame ionization detector. They observed trace amounts of additional hydrocarbons other than methane in the effluent which we assume maybe ethane and ethylene. We identified the operating conditions that allowed us to steam reform ethanol for an acceptable amount of time. These conditions were a steam temperature of 200 C and a wall temperature of 400 C at the center of the reactor. The calculated ratios of CO{sub 2}/CO indicate that we can lower the potential for carbon deposition from the Boudouard further by reducing the pressure.
2000-01-01
British Library Electronic Table of Contents (United Kingdom)
A one-dimensional, steady-state, two-phase direct methanol fuel cell (DMFC) model is developed to precisely investigate complex physiochemical phenomena inside DMFCs. In this model, two-phase species transport through the porous components of a DMFC is formulated based on Maxwell-Stefan multi-component diffusion equations, while capillary-induced liquid flow in the porous media is described by Darcy's equation. In addition, the model fully accounts for water and methanol crossover through the membrane, which is driven by the effects of electro-osmotic drag, diffusion, and the hydraulic pressure gradient. The developed model is validated against readily available experimental data in the literature. Then, a parametric study is carried out to investigate the effects of the operating temperat...
2010-01-01
British Library Electronic Table of Contents (United Kingdom)
An appropriate mathematical model can help researchers to simulate, evaluate, and control a proton exchange membrane fuel cell (PEMFC) stack system. Because a PEMFC is a nonlinear and strongly coupled system, many assumptions and approximations are considered during modeling. Therefore, some differences are found between model results and the real performance of PEMFCs. To increase the precision of the models so that they can describe better the actual performance, optimization of PEMFC model parameters is essential. In this paper, an artificial bee swarm optimization algorithm, called ABSO, is proposed for optimizing the parameters of a steady-state PEMFC stack model suitable for electrical engineering applications. For studying the usefulness of the proposed algorithm, ABSO-based results...
2011-01-01
Basic Information | Fuel Cells &
...Basic Information | Fuel Cells & Vehicles | US EPA This web page provides basic information on EPA's Fuel Cells & Vehicles web site ...including the chemical composition of fuel cell technology, how it works, descriptions of the various types of fuel cells , their availability and ... background,electrochemical,hydrogen,fuel cell,fuel cell vehicle,fuel reformer,performace,improved fuel economy,increased engine efficiency,lower emissions,zero emissions,availablity,fuel cell types,diagram,Proton ...Exchange Membrane,PEM Basic Information | Fuel Cells & Vehicles | US EPA background,electrochemical,hydrogen,fuel cell,fuel cell vehicle,fuel reformer,performace,improved fuel economy,...
Energy Technology Data Exchange (ETDEWEB)
This paper describes an outline of solid fuel production process from brown coal and the investigation results of its elemental techniques. Dried coal is produced by this process which consists of a dewatering of crushed brown coal in oil-based solvent, a solid and liquid separation of slurry, and a remained oil recovery by heating. This process is characterized by the higher thermal efficiency compared with usual drying and the restraint of spontaneous combustion of product coal. It was revealed that solid fuel with low moisture, low ash, low sulfur, and suppressed spontaneous combustion property can be produced from Australian brown coal through this process. From the comparison between kerosene and fuel oil A, it was confirmed that the oil content during dewatering was smaller and the oil recovery by heating was easier by using a solvent with lower boiling point. It was also confirmed that the ...
1996-10-28
US Department of Energy investments in natural gas R&D: An analysis of the gas industry proposal
Energy Technology Data Exchange (ETDEWEB)
The natural gas industry has proposed an increase in the DOE gas R&D budget from about $100 million to about $250 million per year for each of the next 10 years. The proposal includes four programs: natural gas supplies, fuel cells, natural gas vehicles and stationary combustion systems. This paper is a qualitative assessment of the gas industry proposal and recommends a natural gas R&D strategy for the DOE. The methodology is a conceptual framework based on an analysis of market failures and the energy policy objectives of the DOE`s (1991) National Energy Strategy. This framework would assist the DOE in constructing an R&D portfolio that achieves energy policy objectives. The natural gas supply program is recommended to the extent that it contributes to energy price stability. Stationary combustion programs are supported on grounds of economic efficiency and environmental quality. The fuel cell program is ...
1992-04-13
Energy Technology Data Exchange (ETDEWEB)
Improvements to a small diesel engine turbocharger were made based on data gathered during a previous Army contract. The improved turbocharger was fabricated and tested on a small, four cylinder, 239 CID diesel engine. Engine dynamometer test data revealed a 2 to 9 percent reduction in fuel consumption at all points over the operating envelope. A turbocharger was operated for 1011 hours at speeds between 70000 and 78000 rpm without incident. The ball bearings were in excellent condition at the end of the test. A math model of the engine and turbocharger was generated. The model was used to estimate 13 Mode Federal Diesel Emissions Cycle, the LA4 driving cycle and the application of the variable area turbine nozzle (VATN) turbocharger to a diesel engine driven generator set. A recommendation was made to build a gen set demo unit. A fuel savings of 8 to 10 percent was estimated for a 30KW DED generator set.
1982-04-01
Toxicity of Radioactive Wastes Generated from PEACER in Korea
International Nuclear Information System (INIS)
Assessment on the back end fuel cycle, in PEACER (Proliferation-resistant Environmental-friendly Accident-tolerant Continuable and Economical Reactor) that was designated as a new transmutation concept, was performed. Recovery system of uranium and TRU for PEACER is based on pyro-processing. In the assessment of long-lived fission products (LLFP) wastes, initially "9"0Sr and "1"3"7Cs are dominant contributor nuclides until 30 years and especially "9"0Sr and "1"3"7Cs have the highest activity and decay heat than other LLFP. In this study, recovery of "9"0Sr and "1"3"7Cs is recommended for reducing of wastes loading. The acceptable decontamination factor is investigated by the toxicity of PEACER spent fuel. The acceptable decontamination factor is about 1.02 E+05 for the actinides from PEACER spent fuel after 10 years cooling, 4.26 E+05 after 100 years cooling, 1.97 E+04 after 300 years cooling, 9.52 E+03 ...
2006-06-04
Solar-powered unmanned aerial vehicles
Energy Technology Data Exchange (ETDEWEB)
An analysis was performed to determine the impact of various power system components and mission requirements on the size of solar-powered high altitude long endurance (HALE)-type aircraft. The HALE unmanned aerial vehicle (UAV) has good potential for use in many military and civil applications. The primary power system components considered in this study were photovoltaic (PV) modules for power generation and regenerative fuel cells for energy storage. The impact of relevant component performance on UAV size and capability were considered; including PV module efficiency and mass, power electronics efficiency, and fuel cell specific energy. Mission parameters such as time of year, flight altitude, flight latitude, and payload mass and power were also varied to determine impact on UAV size. The aircraft analysis method used determines the required aircraft wing aspect ratio, wing area, and total mass based on maximum ...
1996-12-31
Renewable regenerative energy systems: Practical integration challenges. Paper no. IGEC-1-093
International Nuclear Information System (INIS)
Interest in renewable energy systems that employ regenerative components to enable intermittent energy sources to service time varying loads is growing. The overall performance of these systems is intimately linked to the choice of the energy storage media and the efficiency of the energy conversion devices. Recent advances in electrolyser and fuel cell technologies may make small-scale hydrogen buffered renewable energy systems a practical reality in the near term. A research team at the University of Victoria - Institute for Integrated Energy Systems (IESVic) is developing a flexible distributed, laboratory-scale energy system called IRENE (Integrated Renewable Energy Experiment). The initial goal of this research is to explore the potential for constructing a regenerative energy system using early commercial and precommercial hydrogen storage and fuel cell energy conversion devices. Once implemented, research efforts will focus on the ...
2005-06-12
Parameter study of the LIFE engine nuclear design
International Nuclear Information System (INIS)
LLNL is developing the nuclear fusion based Laser Inertial Fusion Energy (LIFE) power plant concept. The baseline design uses a depleted uranium (DU) fission fuel blanket with a flowing molten salt coolant (flibe) that also breeds the tritium needed to sustain the fusion energy source. Indirect drive targets, similar to those that will be demonstrated on the National Ignition Facility (NIF), are ignited at #approx#13 Hz providing a 500 MW fusion source. The DU is in the form of a uranium oxycarbide kernel in modified TRISO-like fuel particles distributed in a carbon matrix forming 2-cm-diameter pebbles. The thermal power is held at 2000 MW by continuously varying the "6Li enrichment in the coolants. There are many options to be considered in the engine design including target yield, U-to-C ratio in the fuel, fission blanket thickness, etc. Here we report results of design variations and compare them in ...
2010-09-01
International Nuclear Information System (INIS)
Protonic ceramic membrane fuel cells (PCMFCs) based on proton-conducting electrolytes have attracted much attention because of many advantages, such as low activation energy and high energy efficiency. A stable, easily sintered perovskite oxide BaCe_0_._5Zr_0_._3Y_0_._1_6Zn_0_._0_4O_3_-_#delta# (BCZYZ) as electrolyte for proton-conducting solid oxide fuel cells (SOFCs) with Sm_0_._5Sr_0_._5CoO_3_-_#delta# (SSC) composite cathode is investigated. By fabricating thin membrane BCZYZ electrolyte (#approx#20 #mu#m) synthesized by a modified Pechini method on NiO-BCZYZ anode support, PCMFCs are assembled and tested by selecting SSC perovskite cathode with high mixed ionic and electronic conductivities. An open-circuit potential of 1.015 V, a maximal power density of 528 mW cm"-"2, and a low polarization resistance of the electrodes of 0.15 #OMEGA# cm"2 is achieved at 700 "oC. The results indicate that BCZYZ proton-conducting ...
2010-04-02
Hazard analysis for 300 Area N Reactor Fuel Fabrication and Storage Facilty
Energy Technology Data Exchange (ETDEWEB)
This hazard analysis (HA) has been prepared for the 300 Area N Reactor Fuel Fabrication and Storage Facility (Facility), in compliance with the requirements of Westinghouse Hanford Company (Westinghouse Hanford) controlled manual WHC-CM-4-46, Nonreactor Facility Safety Analysis Manual, and to the direction of WHC-IP-0690, Safety Analysis and Regulation Desk Instructions, (WHC 1992). An HA identifies potentially hazardous conditions in a facility and the associated potential accident scenarios. Unlike the Facility hazard classification documented in WHC-SD-NR-HC-004, Hazard Classification for 300 Area N Reactor Fuel Fabrication and Storage Facility, (Huang 1993), which is based on unmitigated consequences, credit is taken in an HA for administrative controls or engineered safety features planned or in place. The HA is the foundation for the accident analysis. The significant event scenarios identified by this HA will be ...
1994-01-25
Economic evaluation of the solar thermal co-production of zinc, synthesis gas, and hydrogen
Energy Technology Data Exchange (ETDEWEB)
The use of concentrated solar energy for co-producing Zn and synthesis gas from Zn O and natural gas upgrades the calorific value of the initial reactants by 39% and, when compared to the traditional carbothermic reduction of Zn O, has the potential of reducing CO{sub 2} emissions by up to 78%. An economic assessment for an industrial thermochemical plant, 30 to 51 MW solar input, indicates that the cost of solar production of zinc ranges between 89-133 $/t (excluding the cost of Zn O feed and credit for pollution abatement), and thus might be competitive with conventional fossil-fuel-based processes at current fuel prices. The cost of solar H{sub 2}, produced by splitting water with zinc, is estimated to be in the range 0.10-0.14 $/kWh, and it is a favorable long term prospect once the cost of energy will account for the environmental externalities from fossil fuel burning such as the costs for CO{sub 2} mitigation and ...
1999-08-01
Development of two stroke engines with direct injection
Energy Technology Data Exchange (ETDEWEB)
In order to develop modern two-stroke engines with low fuel consumption, respectively with low exhaust emissions, two alternative development areas -- the mixture formation and the scavenging system -- have been correlated. For a satisfying mixture formation without fuel losses by scavenging, the direct injection seems to be one of the best solution for the high speed two-stroke engine of the future. On the other hand the modern development of two-stroke scavenging systems shows a large field of application and improvement methods of cross and loop scavenging. Based on the specific optimization factors of the injection system, respectively of the scavenging system, the aim off this common work of the Universities of Pisa and Zwickau is to correlate both the optimization fields in an advantageous mixture formation process. The principal elements of this correlation are the design of the combustion chamber, the position of ...
1995-12-31
Energy Technology Data Exchange (ETDEWEB)
Solid-state nuclear magnetic resonance (NMR) has been used to explore the nanometer-scale structure of Nafion, the widely used fuel cell membrane, and its composites. We have shown that solid-state NMR can characterize chemical structure and composition, domain size and morphology, internuclear distances, molecular dynamics, etc. The newly-developed water channel model of Nafion has been confirmed, and important characteristic length-scales established. Nafion-based organic and inorganic composites with special properties have also been characterized and their structures elucidated. The morphology of Nafion varies with hydration level, and is reflected in the changes in surface-to-volume (S/V) ratio of the polymer obtained by small-angle X-ray scattering (SAXS). The S/V ratios of different Nafion models have been evaluated numerically. It has been found that only the water channel model gives the measured S/V ratios in the normal hydration ...
2010-03-15
Cd speciation in biomass fly ash particles after size separation by centrifugal SPLITT
Energy Technology Data Exchange (ETDEWEB)
The finest particle size fractions ({le} 25 {mu}m) in four fly ash samples from fluidised bed combustion of three biomass based fuels and a municipal solid waste fuel were size separated using a centrifugal SPLITT fractionation cell. The ashes were separated into different size fractions and the cadmium concentration, partition and speciation in each separated fraction were then investigated in relation to their possible leaching. The fractionation was evaluated by environmental scanning electron microscopy, which also provided indications of the associations between Cd and other main elements on the particles through the use of X-ray fluorescence mapping. The total concentration of Cd in each fraction was determined by AAS analysis which showed different dependence on the ash particle size in the case of biomass or waste fuels. In addition, the speciation of Cd in each fraction, investigated by ...
2002-08-01
Ballard fuel cells and the changing energy landscape
Energy Technology Data Exchange (ETDEWEB)
The numerous challenges facing the North American electric utility industry were discussed. In addition to competition, electric utilities are faced with low demand growth, public pressure to avoid adding transmission and distribution capacity, and strict environmental requirements. In view of these developments, large central generation additions that have been industry norm until recently, do not always make economic sense in the current environment. Instead, smaller, distributed additions to generating capacity is becoming the new norm. Small-scale on-site generating capacity has the added advantage of reducing the need for expensive high-voltage transmission lines. The Ballard generation system described here is a modular, efficient fuel cell-based solution to implementing distributed power concepts. The system is natural gas fueled, with low noise, vibration and emissions. Apart from its other advantages, it provides ...
1997-02-01
Energy Technology Data Exchange (ETDEWEB)
A one-way coupling system between the plant simulator TRAC/BF1-ENTREE and the subchannel code with the improved cross flow model, NASCA, has been developed. Based on a scenario of turbine trip tests in the Peach Bottom Unit 2, the wide and rapid reactivity insertion transient induced by the system pressure rise was calculated. The pin power distribution in hot bundles was re-constructed considering heterogeneity of the fuel bundle. When the neighboring control blade is withdrawn, NASCA predicted that the steady-state bundle exit void distribution was nearly flat with regardless of the pin power distribution. However, void distributions in the middle and lower bundle regions became complicated depending on the pin power and the two-phase flow regime in each subchannel. The pin power distribution rapidly changed according to traveling of control blades. However, influence in the void distribution was delayed and damped due to the ...
2002-11-01
A novel concept for CRIEC-driven subcritical research reactors
Energy Technology Data Exchange (ETDEWEB)
A novel scheme is proposed to drive a low-power subcritical fuel assembly by means of a long Cylindrical Radially-convergent Inertial Electrostatic Confinement (CRIEC) used as a neutron source. The concept is inherently safe in the sense that the fuel assembly remains subcritical at all times. Previous work has been done for the possible implementation of CRIEC as a subcritical assembly driver for power reactors. However, it has been found that the present technology and stage of development of IEC-based neutron sources can not meet the neutron flux requirements to drive a system as big as a power reactor. Nevertheless, smaller systems, such as research and training reactors, could be successfully driven with levels of neutron flux that seem more reasonable to be achieved in the near future by IEC devices. The need for custom-made expensive nuclear fission fuel, as in the case of the TRIGA reactors, is ...
2001-07-01
Plasma Technologies for Fuel Processing
International Science & Technology Center (ISTC)
Plasma Technologies of Solid Fuels Processing for Power Engineering and Metallurgy
International Nuclear Information System (INIS)
... NUCLEAR FUEL CYCLE AND FUEL MATERIALS borophosphate glass
2002-04-17
Energy Technology Data Exchange (ETDEWEB)
This patent describes a gas-diesel dual fuel engine apparatus having a diesel engine, a diesel fuel supply system including a diesel fuel injection pump, a gaseous fuel supply system including gaseous fuel regulating valve, and a governing and controlling device for governing the speed of the engine and controlling the switchover of the operation of the engine between a diesel fuel mode and a gaseous fuel mode.
1986-08-05
Flow deflector for nuclear fuel element assemblies
International Nuclear Information System (INIS)
... coolants departure nucleate boiling fluid flow fluidic control devices fuel
First-generation fuel cell demonstration and commercialization activities
International Nuclear Information System (INIS)
... electric utilities electrochemistry energy storage fuel cells organizational models
Evaluation of corrosion of dissolver for enriched uranium
International Nuclear Information System (INIS)
... FUEL CYCLE AND FUEL MATERIALS MATERIALS SCIENCE chromium-nickel
2007-10-01
Cumulative Jets Interaction with Spent Nuclear Fuel
International Science & Technology Center (ISTC)
Research of Cumulative Jets Interaction with Spent Nuclear Fuel
Towards a higher energy efficiency and lower carbon society the European approach and experience
International Nuclear Information System (INIS)
The use of natural energy sources and their conversion to secondary forms of energy are a crucial base for the development of our society with its continuous change of requirements due to an increase in population and the broadening of the needs in our modern life. As a consequence the consumption of primary energy resources rose drastically worldwide during the last 5 decades in particular in the industrialized regions such as Europe. Parallel in time the increasing awareness of negative effects of fuel dependent pollution on the environment and the introduction of stringent emission control regulations about 3 decades ago initiated extensive development and retrofit activities resulting in the today applied high level state of the art. As an additional challenge the worldwide debate about the potential effects of the emission of the s.c green house gases on the global climate in particular carbon dioxide from the use of predominantly fossil ...
2010-07-26
Energy Technology Data Exchange (ETDEWEB)
Only about 25% of residue accumulating in the Federal Republic of Germany is currently used for the purposes of energy. This residue will be converted into fuel for power stations by the Omega process when the dumping of waste with a calorific value in excess of 5 MJ/kg is prohibited with effect from 2005. This oxygen melting process is suitable for the local use of substitute fuels. Waste is converted into a high-quality synthesis gas with a wide range of uses. The Omega process combines drying, thermal decomposition, gasification and melting of the material used in a single-stage process. This is now technologically possible for the first time by combining a metallurgical cupola furnace with a traditional gas producer. The highly-calorific synthesis gas produced by the Omega process can be used in block heat and power stations or as an industrial fuel gas, instead of natural gas. It is also suitable as a starting material ...
2003-03-01
The effect of liquefied natural gas on pollutant emissions was evaluated experimentally with used and new appliances in the laboratory and with appliances installed in residences, targeting information gaps from previous studies. Burner selection targeted available technologies that are projected to comprise the majority of installed appliances over the next decade. Experiments were conducted on 13 cooktop sets, 12 ovens, 5 broiler burners, 5 storage water heaters, 4 forced air furnaces, 1 wall furnace, and 6 tankless water heaters. Air-free concentrations and fuel-based emission factors were determined for carbon monoxide, nitrogen oxides, nitrogen dioxide, and the number of (predominantly ultrafine) particles over complete burns?including transient effects (device warm-up and intermittent firing of burners) following ignition--and during more stable end-of-burn conditions. Formaldehyde was measured over multi-burn cycles. The baseline fuel ...
2009-12-01
Criticality calculations of the fixed bed nuclear reactor
Energy Technology Data Exchange (ETDEWEB)
The Fixed Bed Nuclear Reactor (FBNR) is a small 40 MWe reactor based on the Pressurized Water Reactor (PWR) technology. FBNR is an integrated primary circuit and simple in design. It has the characteristics of being small, modular, proliferation resistant, inherently safe and passively cooled reactor with reduced adverse environmental impact. It utilizes the fuel designed for high temperature reactors operating in a relatively low temperature of PWR environment The 15 mm diameter spherical fuel elements are made of TRISO type microspheres embedded in graphite and cladded by SiC. The coolant flow transfers them from the fuel chamber into the core and become fixed forming a suspended core. Any accident signal will cut off the power to the coolant pump causing a stop in the flow. This results in making the fuel elements fall out of the reactor core by the force of gravity and return ...
2007-07-01
Analysis of a Fast Spectrum Irradiation Facility in the High Flux Isotope Reactor
Energy Technology Data Exchange (ETDEWEB)
The Global Nuclear Energy Partnership (GNEP) is proposing to develop a sodium-cooled fast-spectrum reactor (SFR) to transmute and consume actinides from discharged nuclear fuel. To meet performance objectives, new and advanced fuels and targets need to be developed. The fuels to be irradiated include metal and oxide mixed actinides (U-Np-Pu-Am-Cm); for the target concept, Am-Cm has been considered. A significant part of the development process is the irradiation of the fuel and cladding in a prototypic fast reactor environment to determine the performance under irradiation. Analysis results are presented in this paper for a fast-neutron irradiation facility design based on the large fast neutron flux available in the High Flux Isotope Reactor (HFIR) at Oak Ridge National Laboratory (ORNL) combined with the use of a strongly-absorbing thermal neutron shield. Several designs were ...
2008-09-01
International Nuclear Information System (INIS)
The Chinese government has enacted policies to promote alternative vehicle fuels (AVFs) and alternative fuel vehicles (AFVs), including city bus fleets. The life cycle (LC), energy savings (ES) and GHG reduction (GR) profiles of AVFs/AFVs are critical to those policy decisions. The well-to-wheels module of the Tsinghua-CA3EM model is employed to investigate actual performance data. Compared with conventional buses, AFVs offer differences in performance in terms of both ES and GR. Only half of the AFVs analyzed demonstrate dual benefits. However, all non-oil/gas pathways can substitute oil/gas with coal. Current policies seek to promote technology improvements and market creation initiatives within the guiding framework of national-level diversification and district-level uniformity. Combined with their actual LC behavior and in keeping with near- and long-term strategies, integrated policies should seek to (1) apply hybrid electric technology ...
2010-01-01
{sup 99m}Tc generator preparation using (n, {gamma}){sup 99}Mo produced ex-natural molybdenum
Energy Technology Data Exchange (ETDEWEB)
Theoretical assessment on the chromatographic {sup 99m}Tc generator preparation using (n, {gamma}) {sup 99}Mo produced ex-natural molybdenum was carried out. The relationship between the neutron flux for MoO{sub 3} target activation, Mo-content or Mo adsorption capacity of column packing material, {sup 99m}Tc pertechnetate concentration and/or {sup 99m}Tc radioactivity of eluate was established. The reasonably lower limit of neutron flux of reactor and Molybdenum content of column packing material were found out to estimate the production of portable chromatographic generators available for nuclear medicine application. The concentration of {sup 99m}Tc pertechnetate eluate of low {sup 99m}Tc concentration using the column elution technique was also evaluate theoretically and conducted successfully in practice. Three options of {sup 99m}Tc generator using Titanium-Molybdate, Zirconium-Molybdate and Zirconium Oxide as generator column-packing ...
2003-03-01
International Nuclear Information System (INIS)
The detailed electronic energy band structure of hexagonal close-packed #alpha#-zirconium, corresponding to the atomic configuration of 4d"25s"2 of its four outermost valence electrons, has been computed by the composite-wave variational version of the augmented-plane-wave(APW) method in conjunction with the X#alpha#(#alpha# = 0.70424) exchange approximation for obtaining the potentials. From these data the electronic density of states and its angular-momentum-decomposed components have been obtained by the Raubenheimer-Gilat method. These quantities are required in order to calculate the electron-phonon interaction parameter (lambda) and the superconducting transition temperature (Tsub(c)) within the framework of the theories of Gaspari and Gyorffy and McMillan. A study of the variation of Tsub(c) with the Coulomb pseudopotential (#mu#*) revealed that #mu#* = 0.1 yields the best agreement between theory and experiment for #alpha#-Zr. Also studied from the energy ...
Spectral dependence of ultrasonic attenuation for hydrided Zr-2.5%Nb Alloy
International Nuclear Information System (INIS)
The cold-worked Zr-2.5%Nb alloy is used as material for the pressure tubes in CANDU nuclear reactors. During the service life in reactor, diffusion of hydrogen and/or deuterium in the pressure tubes wall occur. Below a certain temperature, a stable hydride of zirconium is formed, as a brittle phase which can lead to catastrophic failures. For this reason, it is very important to be able to investigate the hydrogen effect on the micro structural properties of zirconium alloys. In the present paper a non-destructive testing technique is used, known as ultrasonic spectral analysis. When an ultrasonic signal traverses a medium, the frequency components associated with the input signal are altered. By frequency analysing the reflected signals, it is possible to study and compare the material properties. The two major parameters measured in ultrasonic spectroscopy are the attenuation and the velocity of the waves. Attenuation is determined by the ...
2009-10-12
Photoelectrochemistry of disordered passive films
Energy Technology Data Exchange (ETDEWEB)
A theoretical model, which describes subband gap photoexcitation involving localized electronic states, was developed. The escape probability of a charge carrier trapped in a localized state is considered via Poole-Frenkel, direct tunneling, or phonon-assisted tunneling processes, as competing escape mechanisms. Photoelectrochemical experiments were performed on the passive films formed on zirconium and amorphous iron-zirconium alloys and on pure HfO/sub 2/ films and HfO/sub 2/ films implanted with varying concentrations of xenon. These films were found to possess some degree of disorder depending on the substrate, the thickness of the film, and the extent of implantation. The spectral dependence of the photocurrent in all of the films studied is considerably different from what was found for crystalline passive films. The potential dependence of the photocurrent yields Poole-Frenkel behavior. Reverse tunneling processes were also observed at ...
1987-01-01
International Nuclear Information System (INIS)
A zirconium alloy comprising from 0.8 to 1.6wt% of Sn, from 0.17 to 0.25wt% of Fe, from 0.15 to 0.25wt% of Cr and from 0.01 to 0.08wt% of Ni and Si at a concentration of 120ppm or lower as an impurity and the balance of Zr is melted into cast pieces and then subjected to an #beta# annealing. It is controlled so as to satisfy Fe + Cr + Ni #<=# 0.52wt%. Then, rolling and annealing are applied so that the total heat injection amount #SIGMA#A_i to the materials is within a range of from 1 x 10"-"1"9 to 1 x 10"-"1"7. #SIGMA#A_i = #SIGMA#t_i #centre dot# exp(-Q/RT_i), in which t_i represents processing time (hour) at an ith heat treatment step after the #beta# annealing, T_i represents a processing temperature (K) in the step i. Q represents an activating energy, R represents a gas constant, and Q/R 40,000. (I.N.).
1995-08-23
Luminescent determination of zirconium and hafnium with myricetin
International Nuclear Information System (INIS)
Reaction of formation of 3, 5, 7, 3', 4', 5' - hexaoxiflavone - myricetin complexes with zirconium and hafnium ions has been the basis for development of luminescent method of determining these elements. Optimum conditions for complexing have been determined. For Hf they are : 8-9 HCl concentration, maximum fluorescence wave length (lambda fl.)of 520 nm, wave length of exciting light (lambda el) of 436 nm, for Zr lambda fl = 536nm, lambda el = 436 nm. Stable fluorescence establishes after 25 min. for Zr and after 15 min for Hf in the presence of 40% ethanol. Usage of various camouflage agents has permitted to attain high selectivity of the method. Possibility for determination of Zr with myricetin in the presence of a 10-time excess of Hf, Cr, Cu, 50-time excess of Mo and Ti is shown. Sensitivity of Zr determination is 2.0x10 #mu#g"-"2/ml, for Hf it is 9.0x10 #mu#g"-"3 and mineral waters.
International Nuclear Information System (INIS)
Ten different alloys of zirconium have been tested with regard to the effect of irradiation on their mechanical properties and their sensitivity to environmentally induced failure. Two different environments were used: iodine vapour and liquid cesium with an addition of 2% cadmium. The neutron dose was 10"2"1n/cm"2 (E>1MeV) and the irradiation temperature was about 300 degrees C. All alloy additions increased the irradiation hardening. Especially notable was the large effect of titanium and tin on irradiation hardening. A limited amount of transmission electron microscopy was carried out in order to find an explanation to the effects. The testing in different environments showed that there is no clear correlation between environmental sensitivity and yield stress. For materials of similar yield stress an alloyed material tends to be more sensitive to environmental cracking than a material which only contains oxygen as an impurity. There also seems to be an ...
1991-08-25
Energy Technology Data Exchange (ETDEWEB)
This research has two main goals. First, we wanted to introduce optimization tools in the diffusion code DONJON, mostly for fuel management. The second objective is more practical. The optimization capabilities are applied to the fuel management problem for different CANDU reactors at refueling equilibrium state. Two kinds of approaches are considered and implemented in this study to solve optimization problems in the code DONJON. The first methods are based on gradients and on the quasi-linear mathematical programming. The method initially developed in the code OPTEX is implemented as a reference approach for the gradient based methods. However, this approach has a major drawback. Indeed, the starting point has to be a feasible point. Then, several approaches have been developed to be more general and not limited by the initial point choice. Among the different methods we developed, two were found to ...
2006-07-01
International Nuclear Information System (INIS)
Ultra low loading noble metal (0.04-0.12 mg_P_t/cm"2) based electrodes were obtained by direct metallization of non-catalyzed gas diffusion layers via dual ion beam assisted deposition (IBAD) method. Fuel cell performance results reported earlier indicate significant improvements in terms of mass specific power density of 0.297 g_P_t/kW with 250 A thick IBAD deposit (0.04 mg_P_t/cm"2 for a total MEA loading of 0.08 mg_P_t/cm"2) at 0.65 V in contrast to the state of the art power density of 1.18 g_P_t/kW using 1 mg_P_t_(_M_E_A_)/cm"2 at 0.65 V. In this article we report the peroxide radical initiated attack of the membrane electrode assembly utilizing IBAD electrodes in comparison to commercially available E-TEK (now BASF Fuel Cell GmbH) electrodes and find the pathway of membrane degradation as well. A novel segmented fuel cell is used for this purpose to relate membrane degradation to peroxide ...
2009-11-01
Session 6: Redox Behavior of Cerium-Zirconium-Bismuth Mixed Oxides
Energy Technology Data Exchange (ETDEWEB)
The CeO{sub 2}-ZrO{sub 2}-Bi{sub 2}O{sub 3} samples with different bismuth content were prepared in this study. By the doping of Bi{sub 2}O{sub 3} into the lattice, TPR profiles of the CeO{sub 2}-ZrO{sub 2} shifted to lower temperatures and oxygen storage capacity increased remarkably. It is concluded that the reason for such a behavior is probably due to both the formation of oxygen vacancies which enhance the oxygen mobility and the simultaneous reduction of Ce{sup 4+} and Bi{sup 3+} in the mixed oxides. (authors)
2004-07-01
Reaction of hydrogen with ZrNiHsub(x) studying by programmed thermodesorption method
International Nuclear Information System (INIS)
The method of programmed thermodesorption has been used to study the forms of hydrogen adsorption in ZrNiHsub(x) hydride. It is shown that high concentration of the hydrogen, which extracted from hydride in the temperature range of 240-260 deg C results in appearance of ''reverse'' peak. Charge of hydride adsorption properties during its oxidation-reduction treatment is studied. Comparison with spectra of hydrogen thermodesorption from the surface of Ni/ZrO_2 deposited catalyst and zirconium oxide is carried out.
1983-01-01
International Nuclear Information System (INIS)
The description is presented of binary phase diagrams of titanium alloyed with the following elements: silver, aluminium, arsenic, gold, boron, barium, beryllium, bismuth, carbon, calcium, cadmium, cobalt, chromium, copper, iron, gallium, germanium, hydrogen, hafnium, indium, iridium, potassium, lithium, magnesium, manganese, molybdenum, nitrogen, sodium, niobium, nickel, oxygen, osmium, phosphorus, lead, palladium, platinum, plutonium, rhenium, lanthanium, cerium, preseodymium, neodymium, gadolinium, erbium, terbium, thulium, lutetium, rhodium, ruthenium, scandium, silicon, tin, strontium, tantalum, technetium, thorium, uranium, vanadium, tungsten, yttrium, ytterbium, zinc and zirconium.
Energy Technology Data Exchange (ETDEWEB)
The theoretical principles underlying the formation of oxide and, in particular, anodic oxide coatings on metals produced by chemical oxidation, anodizing in solutions, and anodizing in cold plasmas are reviewed. The mechanisms and conditions of anodic oxidation are described, and the structure of anodic oxide coatings on aluminum, magnesium, beryllium, zinc, cadmium, iron, cobalt, nickel, titanium, zirconium, tantalum, and chromium alloys is examined. Attention is also given to various applictins of anodized coatings. 54 references.
1985-01-01
International Nuclear Information System (INIS)
Instrumental neutron activation analysis is used for simultaneously determination of macrocomponents in ferroelectric materials LLZT. Pb, Zr, Ti have been determined by "2"0"3Pb, "8"9Zr and "4"8Sc nuclides created by fast neutron (14.5 MeV) activation. Application of paraffine as neutron moderator and reflector allows to simultaneously determine lanthanum by "1"4"0La nuclide. It has been shown that zirconium, titanium and lanthanum can be determined with the accuracy of #+-#0.1 mas. % and lead - #+-#0.7 mas. %.
Unconventional systems for lunar base power generation and storage
International Nuclear Information System (INIS)
Recent advances in thin film solar photovoltaic converters (PV's) can furnish multimegawatt power levels during lunar daylight periods with only modest mass requirements. The extended duration of lunar night (ca. 354 hr) and the high specific mass of earth-imported energy storage systems (regenerative fuel cells, batteries, etc.) render PV plus import storage power systems non-competitive with nuclear power plants for lunar bases. However, power storage or generation methods which can be constructed using primarily lunar materials, used either alone or with lightweight PV's, can be attractive alternatives to nuclear power. Three separate generic systems which can provide favorable low import mass goals have been identified and studied. These are: gravitational energy generation using lunar soil, thermal energy storage using basalt rock or glass, and electrochemical storage using lunar derived electrodes or fuels. Design, ...
1990-08-12
Quality assurance requirements and description for the Civilian Radioactive Waste Management Program
International Nuclear Information System (INIS)
The Quality Assurance Requirements and Description (QARD) is the principal quality assurance document for the Civilian Radioactive Waste Management Program (Program). It establishes the minimum requirements for the Quality Assurance Program. The QARD contains regulatory requirements and program commitments necessary for the development of an effective quality assurance program. Quality assurance implementing documents must be based on, and consistent with, QARD requirements. The QARD applies to the following: (1) acceptance of spent nuclear fuel and high-level radioactive waste; (2) transport of spent nuclear fuel and high-level radioactive waste; (3) the Monitored Retrievable Storage (MRS) facility through application for an operating license; (4) Mined Geologic Disposal System (MGDS), including the site characterization activities (exploratory studies facility (ESF) and surface based testing), through ...
Energy Technology Data Exchange (ETDEWEB)
For a direct injection diesel engine to exhibit its inherent low-emission characteristics, it is essential to improve control accuracy, in particular under transient operating conditions during which emissions are more noted. A model-based control system is established for exhaust gas recirculation (EGR) and air/fuel ratio, using a diesel-engine/vehicle model established on the CAD control system. Described herein are the results of simulation for optimizing control of transient conditions, and the emission-controlling effects confirmed by the field tests. The tests for verification of the established model have confirmed that there are good agreements between the simulated and observed results in terms of air/fuel ratio changing with EGR ratio, exhaust and intake gas and pressure levels, and vehicle speed. The model will be applicable to assessment of emission characteristics under varying conditions. Simulation of the ...
1997-05-01
Energy Technology Data Exchange (ETDEWEB)
X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM) have been conducted on a new fuel cell electrocatalytic material based on a highly porous carbonized polyacrylonitrile (PAN) microcellular foam with very low platinum loading ({approximately}13 to 23 {micro}g/cm{sup 2}). TEM images of this material clearly show the existence of nanometer size platinum particles which are homogeneously distributed in the highly porous carbonized PAN matrix. An XPS study of Pt-loaded PAN indicates that C 1s, O 1s, and N 1s peaks shift to lower binding energies, compared to virgin PAN. It was concluded that special metal-support interaction exists, through the formation of a charge-transfer complex between platinum and pyridine-type nitrogen atoms of PAN support. This interaction leads to the enhancement of the catalytic activity, and the improvement of the long-time stability of this electrocatalyst.
1997-01-01
The solar energy in Lebanon: an inexhaustible and economical energy
International Nuclear Information System (INIS)
The article describes the energy in Lebanon. In 1995, 97% of the imported energy was based on hydrocarbons. Fuel and gas oil present 66% of the final energy. Air pollution is mainly caused by the transportation sector (vehicles and buses...) which presents 70% of the global atmospheric pollution. Renewable energy such as biomass, fossil energy, hydro-energy, solar energy... are also described. The solar energy was defined as a best solution that preserve health in Lebanon. The different applications of the solar for energy production is discussed: photovoltaic , thermal heating, sanitary hot water, electrical heaters, solar water heaters...In conclusion, solar heaters economize 80% of the annual energy expenses
1997-06-01
Sustainable economic development and the necessity of nuclear power
International Nuclear Information System (INIS)
If trends from the past continue into the future, the major increase in the use of energy will come from the developing nations. If the industrialization of the Third World continues to be based on the burning of fossil fuels, the impact on the global climate from these sources alone will be substantial. Statistical information supporting the above statements is presented. The conclusion is reached that improving the efficiency of energy use is not sufficient to avert climatic changes. The accelerated and worldwide use of nuclear power is essential and, if prudently used, can become, contrary to the recommendations of the Brundtland Commission, the basic energy source fuelling future sustainable developments of the world. (author).
1991-01-01
Resistance of the alloy steel used in the fuel gas desulphurization installations
International Nuclear Information System (INIS)
The results have been presented of DC polarization and exposure investigations of alloy steels used as construction materials in flue gas desulphurization installations. on the base of analysis of composition of investigated steels and results of polarization studies, conditions have been discussed in which the pitting resistance equivalent (PRE) should be used. Among tested steels the significantly highest resistance to pitting corrosion is exhibited by 654SMO steel, classified as the super austenitic grade. (author). 14 refs, 3 figs, 2 tabs.
Energy Technology Data Exchange (ETDEWEB)
The US DOE is calling on the nations' industries and academic institutions to develop a new approach for converting coal into liquid fuels at costs that can be competitive with imported oil. Based on a number of innovations, the department is looking for new approaches that can substantially reduce the cost of liquids from coal, essentially capping the price of imported oil. If successful, the new process will define the next generation of coal liquefaction technology and represent a dramatic improvement over the current state-of-the-art integrated two-stage process. 1 fig.
1989-12-01
Neural network for prediction of superheater fireside corrosion
Energy Technology Data Exchange (ETDEWEB)
Superheater corrosion causes vast annual losses to the power companies. If the corrosion could be reliably predicted, new power plants could be designed accordingly, and knowledge of fuel selection and determination of process conditions could be utilized to minimize superheater corrosion. If relations between inputs and the output are poorly known, conventional models depending on corrosion theories will fail. A prediction model based on a neural network is capable of learning from errors and improving its performance as the amount of data increases. The neural network developed during this study predicts superheater corrosion with 80 % accuracy at early stage of the project. (orig.) 10 refs.
1998-12-31
International Nuclear Information System (INIS)
This study illustrates the way to perform protocols, collect samples, and conduct laboratory analyses in order to characterize the physical properties of wood used in the industrial sector of the Valle de Aburra metropalitan area and the gains obtained by characterizing the properties of the most frequently used woods. In this investigation some of the most important sampling parameters are presented, such as taking samples in piles or accumulations of waste, handling of these samples in the laboratory and others of great importance such as the ignition point. the proposed methodology is based upon some of the international astm coal norms, for the similarity it has with wood and for the lack of information on sampling this type in wood
Input price risk and optimal timing of energy investment: choice between fossil- and biofuels
Energy Technology Data Exchange (ETDEWEB)
We consider energy investment, when a choice has to be made between fossil fuel and biomass fired production technologies. A dynamic model is presented to illustrate the effect of the different degrees of input price uncertainty on the choice of technology and the timing of the investment. It is shown that when the choice of technology is irreversible, it may be optimal to postpone the investment even if it would otherwise be optimal to invest in one or both of the plant types. We provide a numerical example based on cost, estimates of two different power plant types. (author)
2002-05-01
Indirect liquefaction contractors' review meeting: Proceedings
The Eighth Indirect Liquefaction Contractors' Review Meeting was held November 15-17, 1988 at the Pittsburgh Hyatt Hotel. Twenty-eight presentations were made by contractors, invited speakers, and Pittsburgh Energy Technology Center R and D personnel. Six areas of research were covered: synthesis gas conversion to oxygenates; light hydrocarbon gas conversion; slurry reactor hydrodynamics; production, clean-up and conversion to hydrocarbon fuels; Fischer-Tropsch products upgrading; and, synthesis gas bioconversion. The meetings also included a panel discussion on direct methane conversion research. Individual projects are processed separately for the data bases.
1988-01-01
High efficiency USC power plant - present status and future potential
Energy Technology Data Exchange (ETDEWEB)
Increasing demand for energy production with low impact on the environment and minimised fuel consumption can be met with high efficient coal fired power plants with advanced steam parameters. An important key to this improvement is the development of high temperature materials with optimised mechanical strength. Based on the results of more than ten years of development a coal fired power plant with an efficiency above 50 % can now be realised. Future developments focus on materials which enable an efficiency of 52-55 %. (orig.) 25 refs.
1998-12-31
Formation and decay of secondary actinides in water reactor and fast neutron reactors
International Nuclear Information System (INIS)
Actinides other than the main uranium or plutonium isotopes take a growing part in the different stages of the nuclear cycle. For the French nuclear power program based on the development of light water reactors and fast breeders, many evaluations of the secondary actinides build up are made for the both reactor types using mainly the existing reactor codes. The comparison of these foreseen compositions with experimental results allows to perform some adjustments of the neutronic data. The secondary actinide compositions are given for some typical fuels and their consequences on the nuclear cycle are discussed. An hypothetical burning of these wastes in fast reactors has been studied and the main conclusions are reported.
International Nuclear Information System (INIS)
Decision making about possible investment options for energy supply technology is usually based on economic criteria reflecting primarily the unit cost of energy and the return on capital invested. This study attempts to reverse the process. The chosen starting point is a UK investment programme geared towards reliance on conservation, renewable energy systems and the more efficient use of our remaining fossil fuels (through combined heat and power and district heating systems). The number and type of jobs likely to be created is then estimated and compared with the jobs likely to be created by the currently proposed nuclear power programme. (author).
Energy balances of OECD countries 1970/1982
Energy Technology Data Exchange (ETDEWEB)
The present volume provides standardized energy balance sheets expressed in a common unit of tons of oil equivalent for all OECD Countries. It covers the years 1970 to 1982 year by year and includes many revisions and additions to data previously published. The balances in the present volume are based on data published in OECD Energy Statistics 1971-1981 and OECD Energy Statistics 1981-1982. Tables for each OECD Country include production, import, export, consumption by the different industries, transportation, agriculture, residential sector of the different energies: solid fuels, petroleum, gas, nuclear power and hydroelectricity.
1984-01-01
Chandler Slavin | Greener Package
...it only highlights the different feedstocks used in the production of fiber-based packaging materials or fossil-fuel ones; what about the energy required to convert ...feedstock, is unacceptable in trying to quantify the overall burden a specific packaging material has on the environment. As an aside, the point ... Consequentially, it is difficult to speculate on how much packaging material a company diverts from the landfill by switching from one material to another ...without specifying what geographical region said packaging material resides in. In addition, there is a lot of interest in diverting PET thermoforms from ...
Research programs on coal and coal liquefaction are presented. Topics discussed are: coal science, combustion, kinetics, surface science; advanced technology projects in liquefaction; two stage liquefaction and direct liquefaction; catalysts of liquefaction; Fischer-Tropsch synthesis and thermodynamics; alternative fuels utilization; coal preparation; biodegradation; advanced combustion technology; flue gas cleanup; environmental coordination, and technology transfer. Individual projects are processed separately for the data base. (CBS)
1988-02-01
Fuel-cycle cost comparisons with oxide and silicide fuels
Energy Technology Data Exchange (ETDEWEB)
This paper addresses fuel cycle cost comparisons for a generic 10 MW reactor with HEU aluminide fuel and with LEU oxide and silicide fuels in several fuel element geometries. The intention of this study is to provide a consistent assessment of various design options from a cost point of view. Fuel cycle cost benefits could result if a number of reactors were to utilize fuel elements with the same number or different numbers of the same standard fuel plate. Data are presented to quantify these potential cost benefits. This analysis shows that there are a number of fuel element designs using LEU oxide or silicide fuels that have either the same or lower total fuel cycle costs than the HEU design. Use of these fuels with the uranium densities considered requires ...
1982-01-01
System, economy and ecology viewpoints of the Krsko NPP lifetime extension
International Nuclear Information System (INIS)
Krsko NPP plant life extension was analysed and evaluated with respect to system, economy and ecology viewpoints. From the system perspective it was established that also in the extended lifetime the plant will remain in operation as a base load electricity supplier. The systematic review was performed to determine its overall competitiveness against advanced coal, gas and new nuclear units. The analysis considered also hydro and renewable sources. Analysis and evaluations resulted in the conclusion that the Krsko NPP lifetime extension is the most effective alternative for base load production due to small additional capital investments, low fuel costs, no new siting requirements, lowest climate and environmental impact, and reliable and safe operation. (author)
2007-09-10
Mineral-wool industry: opportunities for natural gas technologies. Topical report, January-July 1987
To quantify the opportunities for natural gas and identify technological advances needed to capture such opportunities, the mineral-wool industry was analyzed with respect to the principal companies, their capabilities, and markets. The mineral-wool industry is stable with a slightly declining market. Of its market segments, only commercial acoustic insulation (which is currently dominant) is likely to be affected by growth in the next ten years. The principal process is based on treatment of blast-furnace slags in a cupola furnace using coke as the fuel and reducing agent. Expanded use of gas, as a substitute for coke, would eliminate environmental problems and expand the latitude of suitable raw materials. The study provides insights into the mineral-wool industry and identifies factors that may constitute bases for future usage of natural gas.
1988-05-01
Embodied energy and emergy evaluation of a typical biodiesel production chain in China
British Library Electronic Table of Contents (United Kingdom)
Biodiesel from non-grain feedstock has been considered as one of the proper substitutes for fossil fuels associated with a series of activities emerging in China in order to meet the resource shortage and develop the energy crops. This paper presents an ecological accounting framework based on embodied energy, emergy, and CO2 emission for the whole production chain of biodiesel made from Jatropha curcas L. (JCL) oil. The energy and materials invested in and CO2 emission from the whole process, including cropping, transportation, extraction, and production, are accounted and calculated. Also, EmCO2, the ratio of real CO2 released to the emergy-based sustainability indicator per joule biodiesel, is proposed in this paper to present a new goal function for low-carbon system optimization. Fina...
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
A detailed chemical kinetic reaction mechanism is developed to describe incineration of the chemical warfare nerve agent sarin (GB), based on commonly used principles of bond additivity and hierarchical reaction mechanisms. The mechanism is based on previous kinetic models of organophosphorus compounds such as TMP, DMMP and DIMP that are often used as surrogates to predict incineration of GB. Kinetic models of the three surrogates and GB are then used to predict their consumption in a perfectly stirred reactor fueled by natural gas to simulate incineration of these chemicals. Computed results indicate that DIMP is the only one of these surrogates that adequately describes combustion of GB under comparable conditions. The kinetic pathways responsible for these differences in reactivity are identified and discussed. The most important reaction in GB and DIMP that makes them more reactive than TMP or DMMP is found to be a ...
2001-12-13
A new strategy of counterattacking anti-satellite based on motion camouflage
Motion Camouflage (MC) is illuminated as a novel strategy in counterattacking anti-satellite by way of stealth trajectory scheduling. The dynamics model of MC in space is developed and a quadratic function with three boundary constraints is employed for trajectory determination. Based on the model a scenario is set to run the simulation. The results indicate given the designed acceleration input, the predator will be moved following a prescribed route, which precisely locates the predator between two objects at each time instant. In the last approaching phase, the motion is achieved with a big bumping rate which guarantees the power of this striking. Methods for deriving minimum fuel cost in the fixed approaching duration and the minimum approaching duration in limited acceleration input are proposed and are verified in the simulation. At last, camouflage is recognized as a multi-faceted affair, in which stealth trajectory design is considered ...
2010-08-01
High efficiency power production from biomass and waste
Energy Technology Data Exchange (ETDEWEB)
Two-stage gasification allows power production from biomass and waste with high efficiency. The process involves pyrolysis at about 550C followed by heating of the pyrolysis gas to about 1300C in order to crack hydrocarbons and obtain syngas, a mixture of H2, CO, H2O and CO2. The second stage produces soot as unwanted by-product. Experimental results are reported on the suppression of soot formation in the second stage for two different fuels: beech wood pellets and Rofire pellets, made from rejects of paper recycling. Syngas obtained from these two fuels and from an industrial waste fuel has been cleaned and fed to a commercial SOFC stack for 250 hours in total. The SOFC stack showed comparable performance on real and synthetic syngas and no signs of accelerated degradation in performance over these tests. The experimental results have been used for the design and analysis of a future 25 MWth demonstration plant. As an ...
2008-11-15
Energy Technology Data Exchange (ETDEWEB)
This paper examines the role that carbon dioxide capture and storage technologies could play in reducing greenhouse gas emissions if a significant unconventional fuels industry were to develop within the United States. Specifically, the paper examines the potential emergence of a large scale domestic unconventional fuels industry based on oil shale and coal-to-liquids (CTL) technologies. For both of these domestic heavy hydrocarbon resources, this paper models the growth of domestic production to a capacity of 3 MMB/d by 2050. For the oil shale production case, we model large scale deployment of an in-situ retorting process applied to the Eocene Green River formation of Colorado, Utah, and Wyoming where approximately 75% of the high grade oil shale resources within the United States lies. For the CTL case, we examine a more geographically dispersed coal-based unconventional fuel ...
2008-11-18
A study on an electronically controlled liquefied petroleum gas diesel dual-fuel automobile
Energy Technology Data Exchange (ETDEWEB)
In this paper, the control scheme of a liquefied petroleum gas (LPG)-diesel dual-fuel engine with electronic control is illustrated, the external characteristics and load characteristics of the LPG-diesel dual-fuel engine and the diesel engine are compared and analysed, and the results of automobile road tests are also given. The experimental results show that, compared with diesel, the output performance of dual fuel is not reduced, while smoke emission of dual fuel is significantly reduced, NO{sub x} emission of dual fuel is hardly changed, but HC emission and CO emission of dual fuel are increased and fuel consumption of dual fuel is reduced. (Author)
2005-02-15
Toxicity of Jet A (Aviation Fuel) Selected Aquatic Organisms
... Descriptors : *JET ENGINE FUELS, *AQUATIC ORGANISMS, *AVIATION FUELS, *TOXICITY, HEALTH, SMOKE SCREENS, WIND, WATER ...
1989-03-01
The effects of pilot fuel quality on the ignition delay of gas fueled diesel engines
Energy Technology Data Exchange (ETDEWEB)
The effects of changes in the cetane number of liquid pilot fuels on the ignition delay period in dual fuel engines were investigated experimentally. Various pilot fuel quantities were employed with methane, propane and low heating value gaseous fuel mixtures over a wide range of engine load.the ignition delay variation with increased gaseous fuel admission showed a strong dependence on both the quantity and the quality of the pilot fuel used. It was found that the use of high cetane number pilot liquid fuels permitted smaller pilot quantities to be used satisfactorily. Engine operation on propane and low heating value gaseous fuels improved in comparison with dual fuel engine operation employing common diesel fuels.
1997-07-01
Fuel Cell Technologies Equipment on Environmental Expert
... Fuel Cell Technologies Equipment on Environmental Expert Find and compare a variety of fuel cell technologies equipment on the world's largest environmental industry portal. View ...
Energy Technology Data Exchange (ETDEWEB)
The Electric Power Monthly is prepared by the Survey Management Division; Office of Coal, Nuclear, Electric and Alternate Fuels, Energy Information Administration (EIA), Department of Energy. This publication provides monthly statistics at the national, Census division, and State levels for net generation, fuel consumption, fuel stocks, quantity and quality of fuel, cost of fuel, electricity sales, revenue, and average revenue per kilowatthour of electricity sold. Data on net generation, fuel consumption, fuel stocks, quantity and cost of fuel are also displayed for the North American Electric Reliability Council (NERC) regions. Additionally, statistics by company and plant are published in the EPM on capability of new plants, new generation, fuel consumption, fuel stocks, ...
1992-05-01
Durability of Membrane Electrode Assemblies (MEAs) in PEM Fuel ...
Proton exchange membrane (PEM) fuel cells are energy sources that have the ... for H2 /02 PEM fuel cells because their catalysts have properties suitable for 0 ...
Canadian fuel development program in 1997/98
International Nuclear Information System (INIS)
This paper describes the CANDU fuel development activities in Canada during 1997 through 1998. The activities include those of the Fuel Technology Program sponsored by the CANDU Owners Group. The goal of the Fuel Technology Program is to maintain and improve the reliability, economics and safety of CANDU fuel in operating reactors. These activities, therefore, concentrate on the present designs of 28-element and 37-element fuel bundles. The Canadian fuel development activities also include those of the Advanced Fuel and Fuel Cycle Technology Program at AECL. These activities concentrate on the development of advanced fuel designs and advanced fuel cycles, which among other advantages, can reduce the capital and fuelling costs, maintain operating margins in aging reactors, improve ...
1997-09-21
Alternative fuel trucks case studies: Running line-haul trucks on ethanol
Energy Technology Data Exchange (ETDEWEB)
This bulletin describes case studies of trucks operating on ethanol fuel. Cost, maintenance and repair, as well as fuel economy are discussed.
1996-10-01
Sulfur behavior in chemical looping combustion with NiO/Al{sub 2}O{sub 3} oxygen carrier
Energy Technology Data Exchange (ETDEWEB)
Chemical looping combustion (CLC) is a novel technology where CO{sub 2} is inherently separated during combustion. Due to the existence of sulfur contaminants in the fossil fuels, the gaseous products of sulfur species and the interaction of sulfur contaminants with oxygen carrier are a big concern in the CLC practice. The reactivity of NiO/Al{sub 2}O{sub 3} oxygen carrier reduction with a gas mixture of CO/H{sub 2} and H{sub 2}S is investigated by means of a thermogravimetric analyzer (TGA) and Fourier Transform Infrared spectrum analyzer in this study. An X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and scanning electron microscope (SEM) are used to evaluate the phase characterization of reacted oxygen carrier, and the formation mechanisms of the gaseous products of sulfur species are elucidated in the process of chemical looping combustion with a gaseous fuel containing hydrogen sulfide. The results show that the rate of ...
2010-05-15
Staged direct injection diesel engine
Energy Technology Data Exchange (ETDEWEB)
A diesel engine having staged injection for using lower cetane number fuels than No. 2 diesel fuel. The engine includes a main fuel injector and a pilot fuel injector. Pilot and main fuel may be the same fuel. The pilot injector injects from five to fifteen percent of the total fuel at timings from 20.degree. to 180.degree. BTDC depending upon the quantity of pilot fuel injected, the fuel cetane number and speed and load. The pilot fuel injector is directed toward the centerline of the diesel cylinder and at an angle toward the top of the piston, avoiding the walls of the cylinder. Stratification of the early injected pilot fuel is needed to reduce the fuel-air mixing rate, prevent loss of pilot fuel to quench zones, ...
1985-01-01
Interactions of Jet Fuels with Nitrile O-Rings: Petroleum-Derived versus Synthetic Fuels
Energy Technology Data Exchange (ETDEWEB)
A transition from petroleum~derived jet fuels to blends with Fischer-Tropsch (F~T) fuels, and ultimately fully synthetic hydro-isomerized F-T fuels has raised concern about the fate of plasticizers in nitrile-butadiene rubber a-rings that are contacted by the fuels as this transition occurs. The partitioning of plasticizers and fuel molecules between nitrile a-rings and petroleum-derived, synthetic, and additized-synthetic jet fuels has been measured. Thermal desorption of o-rings soaked in the various jet fuels followed by gas chromatographic analysis with a mass spectrometric detector showed many of the plasticizer and stabilizer compounds were removed from the o-rings regardless of the contact fuel. Fuel molecules were observed to migrate into the o-rings for the petroleum-derived ...
2009-01-01
The analysis of complex fluids such as crude oils, fuels, vegetable oils and mixed waste streams poses significant challenges arising primarily from the multiplicity of components, the different properties of the components (polarity, polarizability, etc.) and matrix properties. We have recently introduced an analytical strategy that simplifies many of these analyses, and provides the added potential of linking compositional information with physical property information. This aspect can be used to facilitate equation of state development for the complex fluids. In addition to chemical characterization, the approach provides the ability to calculate thermodynamic properties for such complex heterogeneous streams. The technique is based on the advanced distillation curve (ADC) metrology, which separates a complex fluid by distillation into fractions that are sampled, and for which thermodynamically consistent temperatures are measured at ...
2009-11-17
Loading pattern optimization cooperatively using two new algorithms - 130
International Nuclear Information System (INIS)
Loading pattern optimization (LPO) for a PWR in nuclear power plant contains three parts: fuel assembly location optimization, burnable poison placement optimization, and used fuel assembly orientation optimization. To solve the former two parts, this paper devises an innovative stochastic evolutionary algorithm-Interval Bound Algorithm (IBA), which can optimize fuel assembly location and burnable poison placement together. IBA just uses the fuel assembly's infinite multiplication factor to get rid of unfavorable patterns and to explore new promising solution space. To solve the last part, this paper applies Estimation of Distribution Algorithms (EDAs), which also belong to evolutionary algorithms. These three parts depend on each other, so it is better not to solve them separately. In order to optimize these parts in a coupled way, we use Symbiotic Co-evolutionary Algorithm (SCA) to incorporate IBA and ...
2010-05-09
Energy Technology Data Exchange (ETDEWEB)
Carbon capture and storage have been receiving increasing interest lately, mainly as an option to reduce CO{sub 2} emissions from the power sector. The concept could be adapted for production of H{sub 2} as well, which would provide a carbon free energy carrier that could be used for example as transportation fuel. In this doctoral thesis, the option to use chemical-looping technologies to produce H{sub 2} from fossil fuels with CO{sub 2} capture is explored. In chemical-looping combustion, direct contact between fuel and combustion air is avoided. Instead, a solid oxygen carrier performs the task of bringing oxygen from the air to the fuel. Thus, the resulting CO{sub 2} and H{sub 2}O are not diluted with N{sub 2}, and pure CO{sub 2} can easily be recovered by cooling and condensation. The heat of reaction is the same as for ordinary combustion. Chemical-looping reforming uses the same basic principles ...
2008-04-15
Energy Technology Data Exchange (ETDEWEB)
Gas nitridation has shown excellent promise to form dense, electrically conductive and corrosion-resistant Cr-nitride surface layers on Ni-Cr base alloys for use as proton exchange membrane fuel cell (PEMFC) bipolar plates. Due to the high cost of nickel, Fe-base bipolar plate alloys are needed to meet the cost targets for many PEMFC applications. Unfortunately, nitridation of Fe-base stainless steel alloys typically leads to internal Cr-nitride precipitation rather than the desired protective surface nitride layer formation, due to the high permeability of nitrogen in these alloys. This paper reports the finding that it is possible to form a continuous, protective Cr-nitride (CrN and Cr{sub 2}N) surface layer through nitridation of Fe-base stainless steel alloys. The key to form a protective Cr-nitride surface layer was found to be the initial formation of oxide during nitridation, ...
2007-01-01
Energy Technology Data Exchange (ETDEWEB)
Gas nitridation has shown excellent promise to form dense, electrically conductive and corrosion-resistant Cr-nitride surface layers on Ni-Cr base alloys for use as proton exchange membrane fuel cell (PEMFC) bipolar plates. Due to the high cost of nickel, Fe-base bipolar plate alloys are needed to meet the cost targets for many PEMFC applications. Unfortunately, nitridation of Fe-base stainless steel alloys typically leads to internal Cr-nitride precipitation rather than the desired protective surface nitride layer formation, due to the high permeability of nitrogen in these alloys. This paper reports the finding that it is possible to form a continuous, protective Cr-nitride (CrN and Cr{sub 2}N) surface layer through nitridation of Fe-base stainless steel alloys. The key to form a protective Cr-nitride surface layer was found to be the initial formation of oxide during nitridation, ...
2007-11-22
Development of wood fuel delivery logistics; Puupolttoaineiden hankintalogistiikan kehittaeminen
Energy Technology Data Exchange (ETDEWEB)
The main aim of the project is to model the energy wood business and total logistics in a certain large region. First, wood utilisation locations inside this area are examined; the most important ones are the wood processing factories, and the heating- and power plants. After that, wood potentials in the forests of the area are evaluated in sub-areas suitable in size and sufficiently detailed for further evaluations. For that purpose, the most valuable source data are forest management plans, up to ten years forward, on which basis the wood fuel potentials can be evaluated following sustainable development. In Finland there are extensive and detailed data bases storing forest information and it is possible to collect necessary data for a data base applicable to our calculations. In logistical sense it is important to know, by which delivery chains the economically best and desired results are achieved. The software ...
1996-12-31
International Nuclear Information System (INIS)
The H-SAPS (Hydrogen Stand-Alone Power System) project, an EU project within the ALTENER programme in the period 2002-2004, was initiated to determine the potential for the introduction of environmentally benign hydrogen technology in what is believed to be a near-term market, namely stand-alone power systems (SAPS). The objective of the project was to examine the technological, political, social and economical factors affecting the emergence of hydrogen technology in the stand-alone power system market today and in the future. The scope of the project was limited to small and medium sized stand-alone power systems, up to a few hundred kilowatts (kW) power rating and based on renewable energy as the primary energy source. The work was divided into five phases: (1) Inception, (2) Data collection and analysis, (3) Market analysis and barrier removal, (4) Dissemination, and (5) Final report. Separate reports were written on these topics, and later summarised this ...
1992-10-01
Energy Technology Data Exchange (ETDEWEB)
This paper extends the analytical procedure described in another paper in these proceedings to analyze a variety of compact and light-weight OSC-designed radioisotope-heated generators. Those generators employed General Purpose Heat Source (GPHS) modules and a converter containing sixteen AMTEC cells of OSC`s revised five-tube design with enhanced cell wall reflectivity described in a companion paper in these proceedings. OSC found that the performance of the generator is primarily a function of the thermal insulation between the outside of the generator`s 16 cells and the inside of its wall. After examining a variety of insulation options, it was found that the generator`s performance is optimized by employing a hybrid insulation system, in which the space between the cells is filled with fibrous Min-K insulation, and the generator walls are lined with tapered (i.e., graded-length) multifoil insulation. The OSC design results in a very compact generator, with eight AMTEC cells on each ...
1997-12-31
Coal-oil mixture as a utility boiler fuel. Volume 2. Coal-oil mixture preparation. Final report
Energy Technology Data Exchange (ETDEWEB)
Atlantic Richfield Company, together with Bechtel Group, Inc. and Combustion Engineering, have conducted a study since August 1979 for the Electric Power Research Institute to: (1) develop guidelines for the electric utility industry to assess the technical and economic applicability of coal-oil mixtures (COM) to existing fossil fuel plants, and (2) assess the market potential and cost of preparation for a commercially produced COM fuel suitable for use by electric utility entities. This report is the compilation of work done for the second task. Results from Task 1 are reported separately. Reported here is a methodology for the estimation of coal-oil mixture pricing. Components included in the pricing estimate are raw materials costs, transportation and manufacturing cost components, with capital recovery treated according to both public (utility) and private financing guidelines. A detailed base case using a specific ...
1982-11-01
Progress of the DUPIC Fuel Compatibility Analysis (IV) - Fuel Performance
International Nuclear Information System (INIS)
This study describes the mechanical compatibility of the direct use of spent pressurized water reactor (PWR) fuel in Canada deuterium uranium (CANDU) reactors (DUPIC) fuel, when it is loaded into a CANDU reactor. The mechanical compatibility can be assessed for the fuel management, primary heat transport system, fuel channel, and the fuel handling system in the reactor core by both the experimental and analytic methods. Because the physical dimensions of the DUPIC fuel bundle adopt the CANDU flexible (CANFLEX) fuel bundle design which has already been demonstrated for a commercial use in CANDU reactors, the experimental compatibility analyses focused on the generation of material property data and the irradiation tests of the DUPIC fuel, which are used for the computational analysis. The intermediate results of the ...
1995-06-04
Dual fuel control of a high speed turbocharged diesel engine
Energy Technology Data Exchange (ETDEWEB)
The modification of a Ford 7600 turbocharged diesel engine to a dual fuel engine using methane as the supplementary fuel has been carried out. The paper describes the preliminary work of dual fuel control. Two systems are examined and their behaviour is presented.
1987-01-01
International Nuclear Information System (INIS)
The LWR fuel performance analysis computer code, FRAPCON-1, are evaluated to investigate the performance of CANDU fuel elements loaded in Wolsung-1 reactor. The FRAPCON-1 models of neutron flux depression in fuel and of fuel-to-cladding heat transfer are modified, and the validity of fission gas release model for CANDU fuel is evaluated. And the heavy water properties are provided in calculating the heat transfer coefficient between cladding and coolant. By using the modified code, FRAPCON-1-CSK, the sensitivity studies are carried out for Wolsung-1 fuel element design parameters. The performance analysis is also performed for Wolsung-1 fuel elements. The calculated results are discussed in terms of LWR fuel design criteria because of unavailability of CANDU fuel design criteria. (Author).
1983-01-01
International Nuclear Information System (INIS)
Peculiarities of Kurchatov Institute WWR-2 and TR research reactors spent fuel treating and transportation for radiochemical processing are stated. Spent fuels were performed as fuel assemblies of different forms and containing similar fuel elements: EhK-10 with 10% enrichment UO2-Mg fuel kernels or S-36 with 36% enrichment U-Al alloys. Spent fuel storage conditions are described. Features of developed procedures for identification of fuel assemblies by type of fuel elements are given. Transport package TUK-19 for loading and transportation of spent fuel for processing was chosen. Details of spent fuel loading in TUK-19 that is conducted by personnel under protective sheet of water in special reclaim volume are described
2009-04-01
On the suitability of alternate fuels for dual fuel engine operation
Energy Technology Data Exchange (ETDEWEB)
A compression ignition engine was operated on dual fuel principle inducting two commercial fuels and four pure hydrocarbon fuels in turn through intake manifold along with air and injecting diesel fuel to initiate the combustion in the conventional manner. The engine was operated at different loads and at each load the quantity of inducted fuel was increased gradually till knocking set in. The engine performance and exhaust pollutant emissions were recorded at different operating conditions. It was observed that the extent of induction and the effect on the performance depend on the properties of the inducted fuel such as volatility, self ignition temperature and oxidation characteristics. The energy release during the cycle was also observed to shift depending on the properties of inducted fuel. With the dual fuel ...
1980-12-01
Low emission fuel engine and method of operating same
Energy Technology Data Exchange (ETDEWEB)
This patent describes a low emission duel fuel engine system. It comprises: a dual fuel engine having a combustion chamber; a fuel oil supply connected to the engine; a fuel gas supply connected to the engine; and means connected between the fuel oil supply and the engine for injecting fuel oil into the engine. The means connected between the engine and fuel oil supply limiting the injection of fuel oil to the combustion chamber to pilot ignition quantities only, wherein the limiting means includes means for limiting the injection of fuel oil such that the exhaust emission of NO{sub x} is at an emission rate of less than 1 GM/PH-HR, whereby the exhaust emission performance of the dual fuel engine is enhanced.
1990-09-11
The Behavior of Water in Jet Fuels and the Clogging of ...
... values and unless special precautions and equipment are used, it would be very difficult to service and maintain operational jet-fuel systems with ...
1950-01-11
Safe Type of Transference for Spent Fuel
International Science & Technology Center (ISTC)
Safe Transference of Spent Fuel Assemblies from Near-Reactor Storage Pools to Long-term "Dry" Storage
Method and apparatus for operation of a dual fuel compression ignition combustion engine
Energy Technology Data Exchange (ETDEWEB)
A dual fuel engine control system for controlling the power output of a dual fuel compression ignition engine. The engine includes mixing means for combining an oxidizer and a primary fuel at a substantially constant ratio of oxidizer to primary fuel. The power output of the engine is controlled through the use of a throttle valve controlling the quantity of combustible mixture delivered to the combustion chamber. The fuel control system minimizes the quantity of ignition fuel required by controlling the quantity of combustible mixture rather than the fuel of air ratio. (author) figs.
1994-03-03
MR-6 Type Fuel Elements Cooling in Natural Convection Conditions after Reactor Shutdown
International Nuclear Information System (INIS)
... Natural convection cooling of the channel type reactor performed with the fuel
1992-08-03
Fuel cycle of reactor SVBR-100
International Nuclear Information System (INIS)
... fast reactors fbr type reactors fuels liquid metal cooled reactors materials nuclear
Fuel Assembly Materials under Dry Storage
International Science & Technology Center (ISTC)
Behavior of Nuclear Reactor Fuel Assembly Materials during Their Long-Term Dry Storage
Analysis of Nuclear and Coal Fueled Total Energy System ...
... ENERGY CONSERVATION, ENERGY CONSUMPTION, ELECTRIC POWER DISTRIBUTION, FOSSIL FUELS, COAL, BRAYTON CYCLE. ...
1977-06-30
US/Japan workshop on global change land disposal of CO{sub 2}
Energy Technology Data Exchange (ETDEWEB)
The general responses proposed to reduce CO{sub 2} emissions to the atmosphere are conservation, improved efficiency and fuel substitution. These are valid options but other alternatives such as CO{sub 2} capture and disposal may be more attractive for specific areas. There are good reasons why the capture and disposal option fits the situation in Western Canada. The first and obvious reason is the importance of hydrocarbon energy to the regional economy. Here the economy is based on the production, utilization and sale of hydrocarbons such as coal, oil and natural gas and we intend to stay in business. Besides meeting the Canadian demand, natural gas from Alberta is used in the US as far away as Boston and Los Angeles. Canadian heavy crude oil serves much of the American Midwest and coal from the Canadian Rocky Mountains is exported to Japan. Although many may consider these hydrocarbon reserves and fossil fuel production ...
1993-12-31
Thermodynamics in a turbocharged direct injection diesel engine
Energy Technology Data Exchange (ETDEWEB)
Software has been developed for the calculation of the thermodynamic cycle and the entropy changes in a turbocharged, direct injection, diesel engine based upon the measured cylinder pressure and a shaft encoder output. Assumptions of homogeneous mixture and equilibrium thermodynamic properties are made for the products of combustion and temporal variation in the fluid thermodynamic state is followed in a quasi-steady manner through a series of adjacent equilibrium states, each separated by finite intervals of one degree crank angle (1degCA). The thermodynamic properties are calculated by either of two equivalent formulations -- equilibrium constant or minimisation of Gibbs free energy, and are expressed in algebraic equations of the partial derivative of internal energy and gas constant with respect to temperature, pressure and equivalence ratio. The effect of the engine operating conditions on the thermodynamic cycle is studied, Results show that the dynamic ...
1998-02-01
The role of clean coal technologies in post-2000 power generation
Energy Technology Data Exchange (ETDEWEB)
A substantial global market for advanced power systems is expected to develop early in the next century for both repowering and new capacity additions, Although natural gas-fueled systems, such as gas turbines, are expected to dominate in the 1990`s, coal-fueled systems are expected to emerge in the 2000`s as systems of choice for base-load capacity because of coal`s lower expected cost. Stringent environmental regulations dictate that all advanced power systems must be clean, economical, and efficient in order to meet both the environmental and economic performance criteria of the future. Recognizing these needs, the DOE strategy is to carry out an effective RD&D program, in partnership with the private sector, to demonstrate these technologies for commercial applications in the next century. These technologies are expected to capture a large portion of the future power generation market. The DOE: expects that, ...
1994-07-01
Energy Technology Data Exchange (ETDEWEB)
This work deals with a new route to modify polymer blend morphology in order to improve the porosity of gas diffusion layers (GDLs) for proton exchange membrane fuel cells (PEMFCs). First, electrically conductive polymer-based blends were carefully formulated using a twin-screw extrusion process. Blend electrical conductivity was ensured by the addition of high specific surface area carbon black and synthetic graphite flakes. Final GDL porosity, in particular its macroporosity, was generated by melt blending polyamide 11 (PA11) matrix with polystyrene (PS) followed by PS extraction with tetrahydrofuran (THF) solvent at room temperature. In order to improve GDL porosity by the optimisation of PS dispersion in the PA11 matrix, PA11/PS blends were compatibilised by the addition of 2 wt.-% of clay. It was observed that both macroporosity and pore size distribution were beneficially modified after blend compatibilisation. Final GDL conductivity of ...
2007-12-15
New technology for the comprehensive utilization of Chinese oil shale resources
Energy Technology Data Exchange (ETDEWEB)
In China, the conventional utilization of oil shale is concentrated mainly on retorting oil shale to produce shale oil and fuel gas, and burning oil shale to generate electricity. The growth of petroleum price, and the development in heavy industry, make these conventional utilization facilities become unavailable on the energy market. In this paper, a new comprehensive utilization system is recommended for the future use of Huadian oil shale, based on the current status of energy and the characteristics of oil shale. The system involves three subsystems: retort subsystem, where coarse oil shale (8-80 mm) is retorted to shale oil, hydrocarbon gases and oil shale semicoke; combustion subsystem, where the mixture fuel of oil-shale semicoke and fine oil shale (0-8 mm) is fed to a circulating fluidized bed (CFB) furnace to burn, in order to generate high-pressure steam which is used to supply heat and generate electricity via a ...
2007-05-15
Energy Technology Data Exchange (ETDEWEB)
The deposition of platinum on various carbon blacks was carried out by forming active functional groups on the surface of the carbon support, and exchanging these active groups with different platinum complexes. Using H{sub 2}PtCl{sub 6} solution, an impregnation rather than an exchange takes place. However, using divalent platinum complexes [Pt(NH{sub 3}){sub 4}]{sup 2+}, a fast exchange takes place which leads to extremely small platinum particles highly dispersed on the surface of carbon black. A comparison of the catalytic activities of platinum supported on various carbon blacks was also carried out. The performances of PEFC (Polymer Electrolyte Fuel Cell) based on the process of the ion exchange are reported. (authors) 3 refs.
1998-01-01
Energy Technology Data Exchange (ETDEWEB)
This paper investigates various usages of natural gas (NG) as an energy source for different hydrogen production technologies. A comparison is made between the different methods of hydrogen production, based on the total amount of natural gas needed to produce a specific quantity of hydrogen, carbon dioxide emissions per mole of hydrogen produced, water requirements per mole of hydrogen produced, and a cost sensitivity analysis that takes into account the fuel cost, carbon dioxide capture cost and a carbon tax. The methods examined are the copper-chlorine (Cu-Cl) thermochemical cycle, steam methane reforming (SMR) and a modified sulfur-iodine (S-I) thermochemical cycle. Also, an integrated Cu-Cl/SMR plant is examined to show the unique advantages of modifying existing SMR plants with new hydrogen production technology. The analysis shows that the thermochemical Cu-Cl cycle out-performs the other conventional methods with respect to ...
2010-08-15
International Nuclear Information System (INIS)
This paper investigates various usages of natural gas (NG) as an energy source for different hydrogen production technologies. A comparison is made between the different methods of hydrogen production, based on the total amount of natural gas needed to produce a specific quantity of hydrogen, carbon dioxide emissions per mole of hydrogen produced, water requirements per mole of hydrogen produced, and a cost sensitivity analysis that takes into account the fuel cost, carbon dioxide capture cost and a carbon tax. The methods examined are the copper-chlorine (Cu-Cl) thermochemical cycle, steam methane reforming (SMR) and a modified sulfur-iodine (S-I) thermochemical cycle. Also, an integrated Cu-Cl/SMR plant is examined to show the unique advantages of modifying existing SMR plants with new hydrogen production technology. The analysis shows that the thermochemical Cu-Cl cycle out-performs the other conventional methods with respect to ...
2010-08-01
Integrated plasma synthesis of efficient catalytic nanostructures for fuel cell electrodes
International Nuclear Information System (INIS)
A single plasma process involving three consecutive steps has been developed for producing high gas flow catalytic nanostructures on the electrodes of proton exchange membrane (PEM) fuel cells (FC). Using a high density helicon radio frequency (13.56 MHz) plasma, nickel is sputtered onto a porous carbon support. Changing the background gas from argon to methane/hydrogen allowed 2 ?m long, 37 nm diameter carbon nanofibres (CNFs) to be grown by diffusion through the nickel clusters in a 'tip growth' mechanism at the relatively low temperature of 400 deg. C. The third step involves plasma sputtering of platinum onto the CNFs, resulting in nanoclusters (3-8 nm) being formed on the periphery of the CNFs. Four FC cathodes were synthesized on carbon paper and PTFE/carbon loaded cloth (known as gas diffusion layer, GDL), both with and without CNFs, with the Pt/CNFs nanostructures grown on PTFE/carbon loaded cloth having the best FC performances. Compared with conventional ...
2007-08-01
Evaluation of Pd-Ag alloys as electrocatalysts for oxygen reduction reaction
Energy Technology Data Exchange (ETDEWEB)
Alkaline fuel cells (AFCs) provide a less corrosive environment and can provide higher electrode reaction kinetics than proton exchange membrane fuel cells (PEMFCs). The alkaline media also allows for the replacement of platinum (Pt) based electrocatalysts with non-Pt electrocatalysts. Studies have shown that palladium (Pd) and silver (Ag) form a homogenous solid solution with a face-centred cubic structure within a large range of temperatures. This study described the results of an oxygen reduction reaction (ORR) on lead-silver (Pd-Ag) alloy electrodes in alkaline media. The reaction was compared with Pd and Ag electrodes. The alloys were synthesized as thin films using a sequential electroless deposition of Pd and Ag on stainless steel discs followed by an annealing procedure in an Ar stream. X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) were used to characterize ...
2010-07-01
Energy Technology Data Exchange (ETDEWEB)
An analysis is given of the problems which can be solved by the use of electric-powered vehicles. A detailed comparison is made of the energy consumption and the air polluting emissions of electric and conventional vehicles, taking into account the energy consumption of the vehicles and the primary energy consumption of electric power generation and automotive fuels production. Also the air pollution, as a result of power generation and fuel production are considered. In chapter 1 an outline is given of the traffic and transportation sector in the Netherlands with special attention to data on the energy consumption and the air pollution of this sector. Based on these data the problems can be formulated for which the application of electric vehicles can be a solution. In chapter three a brief description is given of the technical specifications and characteristics of electric vehicles. Special attention is paid to the ...
1992-09-01
Energy Technology Data Exchange (ETDEWEB)
The geometrical and chemical effects of cerium (Ce) addition to Ni-Cr anode electrode in molten carbonate fuel cells (MCFCs) were investigated by measuring the fractal dimensions and wettability of four types of anode electrode with Ce added up to 5 wt.%. In addition, their cell performances were investigated through a single cell operation test and their results were explained based on the wettability of the anode electrodes. The addition of Ce to the anode electrode increased the fractal dimensions and wettabilities of the electrodes. Despite the even larger electrical resistivity of Ce compared to that of Ni and Cr, the electrical resistances of the Ce-added anode electrodes were slightly increased with increasing level of Ce addition. This might be ascribed to the greater wettability of the Ce-added anode electrode that enhanced the cell performance. Therefore, the greater wettability of the Ce-added anode electrode might compensate for its ...
2007-02-15
Development of HT-9 for liquid-metal reactor components
International Nuclear Information System (INIS)
Alloy HT-9 is being used for both duct and cladding applications in advanced liquid-metal reactor (LMR) experiments. This tempered martensitic steel was selected for use as an LMR core component material primarily because of its excellent resistance to radiation-induced swelling. Experiments conducted in the Fast Flux Test Facility (FFTF) at 410 degree C and exposures in the range of 150 to 175 displacements per atom (dpa) have shown that Ht-9 exhibits only a 0.2 to 0.3% increase in volume. Cold-worked austenitic steels exhibit volumetric increases of 20 to 30% at 410 degree C, Alloy HT-9 is being used for a series of fuel pin experiments in the FFTF, and these tests have achieved a burnup of 175 MWd/kg metal and a fluence of 25 x 10"2"2 n/cm"2 (E > 0.1 MeV) without fuel pin breach. The high confidence placed in HT-9 is based on a wide series of in- and ex-reactor experiments. Test results for these experiments are ...
1989-11-26
Energy Technology Data Exchange (ETDEWEB)
A concept for a fast spectrum irradiation facility has been developed for insertion in the High Flux Isotope Reactor at Oak Ridge National Laboratory. The design is based on the very large fast flux that is available in this reactor combined with the use of a strongly-absorbing thermal neutron shield. The preferred concept from the several considered consists of a three-pin design surrounded by a Eu{sub 2}O{sub 3} thermal neutron shield located in the reactor flux trap. Preliminary analyses showed that this concept can provide a fast flux larger than 1x10{sup 15} n/cm{sup 2}{center_dot}s and a fast-to-thermal flux ratio greater than 300 while having an acceptable impact on the HFIR operation. Additional analyses are necessary to confirm that this design is feasible and meets the requirements for fast fuel irradiation. If the design proves to be suitable, it can provide a relatively low-cost, near-term capability.
2008-03-01
Energy Technology Data Exchange (ETDEWEB)
Concerns over the environment and energy security have recently prompted renewed interest in the U.S. in nuclear energy. Recognizing this, the U.S. Dept. of Energy has launched an initiative to revamp and modernize the role that modeling and simulation plays in the development and operation of nuclear facilities. This Nuclear Energy Advanced Modeling and Simulation (NEAMS) program represents a major investment in the development of new software, with one or more large multi-scale multi-physics capabilities in each of four technical areas associated with the nuclear fuel cycle, as well as additional supporting developments. In conjunction with this, we are designing a software architecture, computational environment, and component framework to integrate the NEAMS technical capabilities and make them more accessible to users. In this report of work very much in progress, we lay out the 'problem' we are addressing, describe the model-driven system ...
2009-11-01
British Library Electronic Table of Contents (United Kingdom)
The main drawback of Ni/YSZ anode supports for solid oxide fuel cell application is their low tolerance to reducing and oxidizing (RedOx) atmosphere changes, owing to the Ni/NiO volume variation. This work describes a structured approach based on design of experiments for optimizing the microstructure for RedOx stability enhancement. A full factorial hypercube design and the response surface methodology are applied with the variables and their variation range defined as: (1) NiO proportion (40-60wt% of the ceramic powders), (2) pore-former proportion (0-30wt% corresponding to 0-64vol.%), (3) NiO particle size (0.5-8mm) and (4) 8YSZ particle size (0.6-9mm). To obtain quadratic response models, 25 different compositions were prepared forming a central composite design. The measured responses...
2011-01-01
Dependence of fast reactor fuel burnup characteristics on nuclear data libraries
International Nuclear Information System (INIS)
In the framework of the development of burnup calculation method for commercial fast reactors, a sensitivity analysis was carried out to clarify the dependence of fuel burnup characteristics on nuclear data libraries (NDLs). The following NDLs were compared: JEF-2.2, ENDF/B-VI Release 5, JENDL-3.2 and JENDL-3.3. The NDL-dependence of material balance for main heavy metal nuclides ("2"3"5U, "2"3"8U, "2"3"9Pu, "2"4"0Pu and "2"4"1Pu) was small, since the number densities at the end of one-cycle burnup did not change over 1 or 2% among the above-mentioned libraries. Relatively large differences were found for minor actinide nuclides, especially for "2"3"6U, "2"3"7Np, "2"4"2"mAm, "2"4"3Am and curium isotopes. The number densities for these nuclides after burning up showed remarkable NDL-dependence over 5% through 50%. A burnup sensitivity analysis system based on the generalized perturbation theory enabled us to find out quantitatively the causative ...
2005-04-01
Degradation of materials under conditions of the sulphur-iodine thermochemical cycle
Energy Technology Data Exchange (ETDEWEB)
The need for a hydrogen economy is driven by increasing fuel prices, depleting oil reserves and uncertainty over supplies, and concerns about global warming and environmental pollution. Alternative methods to portable energy sources such as fossil fuels are being developed that are more efficient and carbon-emission-neutral. A prospective method is to produce hydrogen as an energy carrier. This paper presented a study on the degradation of materials under conditions of the sulphur-iodine (SI) thermochemical cycle. The paper provided background information on the study and presented a schematic of the SI cycle. A literature review was presented along with materials selected, such as refractory metals, reactive metals, superalloys, glassy metals, ceramics, cermets, polymers, composites, and coatings. The experimental method was then described. A capsule method was developed to rapidly quantify the decomposition rate of the candidate materials ...
2009-07-01
Anaerobic digestion and related best management practices : utilizing life cycle assessment
Energy Technology Data Exchange (ETDEWEB)
This paper reported on a life cycle assessment (LCA) study that compared the environmental impacts of business-as-usual manure management with those of a manure management operation incorporating anaerobic digestion with combined heat and power generation. The case study was based on a medium sized dairy farm in northern New York State. The study identified the benefits resulting from the displacement of fossil fuels, and reduction of related emissions. Although anaerobic digestion of dairy manure with energy recovery through biogas combustion is viewed as a positive environmental approach to increase the use of renewable energy, there are potential negative impacts that can counteract the environmental benefits. The negative impacts are associated with emissions of methane and nitrogen species during digestion and after spreading of digester effluent. The environmental impacts and their causes should be evaluated in order to promote best ...
2010-07-01
APEX accelerator cycle for transmutation of long-lived fission wastes
Energy Technology Data Exchange (ETDEWEB)
Based on preliminary studies, some conclusions can be drawn concerning the Accelerator Fuel Enricher and Fission Product Exterminator (APEX). APEX-1 and APEX-2 systems can destroy TU's, /sup 137/Cs, and /sup 90/Sr at acceptable cost and efficiency. The principal difference between APEX-1 and APEX-2 is the in-reactor and in-circuit inventory of /sup 137/Cs and /sup 90/Sr. Stable and low hazard wastes can be disposed of by burial. Accelerator breeders can effectively sustain a fission reactor economy indefinitely. Military waste can be blended into commercial fuel cycle for transmutation. Accelerator and target technologies appear practical and could be developed in a few years. More detailed studies are needed to better define the technical and economic features of the LAFER and APEX cycles, so that comparative assessments can be made between these cycles, as well as with other transmutation and waste disposal ...
1980-01-01
A study on the fuel handling control system in CANDU 6 nuclear power plants
Energy Technology Data Exchange (ETDEWEB)
The Fuel Handling(F/H) System in existing CANDU 6 nuclear power plants was designed in the early 1960`s, utilizing the technology available at that time. The design for the F/H control system has been proven to be excellent in meeting the functional requirements through more than 20 CANDU units in service or under construction. The significant advance in electrical and electronic engineering area in a few decades motivates the design changes to reduce costs for engineering, construction and operation as well as to improve performance, reliability and safety based on the latest technology. This report outlines the current design of the F/H system, especially for the F/H control system, introduces some topics in research and development projects being carried out by AECL or other institutes, and presents several potential design improvement items for the better CANDU system with brief explanation about implementation. 29 figs., 2 tabs., 27 refs. ...
1994-06-01
Probabilistic power generation planning with environmental consideration for Lebanon
International Nuclear Information System (INIS)
Full text.This paper describes a software tool for generation expansion planning based on dynamic programming, probabilistic production simulation, and environmental assessment. The aim is to determine the units needed to expand a given system in order to minimize either the cost or the environmental impact or some weighed function of the two. The problem of generation expansion planning is solved in stages using Tunnel Dynamic Programming (TDP) with Heuristic rules to limit the number of options analyzed. The production costing methodology is based on combining a probabilistic generation model known as the capacity outage table (COT) with the load duration curve (LDC) of the system to deduce a risk model from which the expected energy not supplied (EENS) is estimated. The generation model is built recursively using an efficient numerical convolution procedure and is combined at each step with the LDC to calculate the expected energy produced ...
2000-11-23
New perspectives on renewable energy systems based on hydrogen
International Nuclear Information System (INIS)
Current hydrocarbon-based energy systems, current energy consumption and the push towards the utilization of renewable energy sources, fuelled by global warming and the need to reduce atmospheric pollution are discussed. The consequences of climatic change and the obligation of Annex B countries to reduce their greenhouse gas emissions in terms of the Kyoto Protocols are reviewed. The role that renewable energy sources such as hydrogen, solar and wind energy could play in avoiding the most catastrophic consequences of rapidly growing energy consumption and atmospheric pollution in the face of diminishing conventional fossil fuel resources are examined. The focus is on hydrogen energy as a means of storing and transporting primary energy. Some favorable characteristics of hydrogen is its abundance, the fact that it can be produced utilizing renewable or non-renewable sources, and the further fact that its combustion produces three times more ...
1999-09-27
New era for coal-based electricity generation in the United States
Energy Technology Data Exchange (ETDEWEB)
In 1970, the Federal Power Commission predicted a fall from 46% to 27% in 1990 as a result of predicted increases in the use of nuclear power. Today, the Department of Energy expects coal to supply about 50% of electricity generation in 1990. About one-eighth of the world's annual hard coal production is used to make electricity in the United States. Power stations in the country used more coal in 1979 than was produced in the whole Western Europe that year. These 405,000,000 tons of coal equivalent were burned in 1257 individual utilities with an aggregate capacity of 235,000 megawatts. There are coal-fired power plants in 43 of the 50 states. Four factors will be most important in shaping the future development of coal-based electricity: prices, conservation, environmental regulations, and national security. The price differential between coal and oil has now reached a level where it is much more economic for a United States electric utility to build and ...
1980-01-01
Eielson Air Force Base Operable Unit 2 baseline risk assessment
Energy Technology Data Exchange (ETDEWEB)
Operable Unit 2 at Eielson Air Force Base (AFB) near Fairbanks, is one of several operable units characterized by petroleum, oil, and lubricant contamination, and by the presence of organic products floating at the water table, as a result of Air Force operations since the 1940s. The base is approximately 19,270 acres in size, and comprises the areas for military operations and a residential neighborhood for military dependents. Within Operable Unit 2, there are seven source areas. These source areas were grouped together primarily because of the contaminants released and hence are not necessarily in geographical proximity. Source area ST10 includes a surface water body (Hardfill Lake) next to a fuel spill area. The primary constituents of concern for human health include benzene, toluene, ethylbenzene, and xylenes (BTEX). Monitored data showed these volatile constituents to be present in groundwater wells. The data also ...
1994-10-01
Hydrocarbon fuels having one or more fullerenes therein as identification media
Energy Technology Data Exchange (ETDEWEB)
An improved hydrocarbon fuel is described selected from the group consisting of gasoline, diesel fuel, kerosene, jet fuel, No. 1 heating oil, and No. 2 heating oil containing a detectable amount of one or more fullerene additives therein serving as identification means for said fuel wherein said fullerenes are present in an amount insufficient to alter any of the combustion properties of the fuel.
1993-08-10
Low-Cost Hydrogen Distributed Production System Development
H{sub 2}Gen, with the support of the Department of Energy, successfully designed, built and field-tested two steam methane reformers with 578 kg/day capacity, which has now become a standard commercial product serving customers in the specialty metals and PV manufacturing businesses. We demonstrated that this reformer/PSA system, when combined with compression, storage and dispensing (CSD) equipment could produce hydrogen that is already cost-competitive with gasoline per mile driven in a conventional (non-hybrid) vehicle. We further showed that mass producing this 578 kg/day system in quantities of just 100 units would reduce hydrogen cost per mile approximately 13% below the cost of untaxed gasoline per mile used in a hybrid electric vehicle. If mass produced in quantities of 500 units, hydrogen cost per mile in a FCEV would be 20% below the cost of untaxed gasoline in an HEV in the 2015-2020 time period using EIA fuel cost projections for natural gas and untaxed ...
2011-03-10
Modern concept for ethanol distilleries: maximization of the electricity surplus
Energy Technology Data Exchange (ETDEWEB)
Once again Brazil faces the possibility of an electricity shortage in the near future. The low level of rain and the consequent reduction of hydroelectric reservoirs (hydroelectric energy represents almost 80% the total Brazilian electricity generation) led to the dispatch of thermal plants based on natural gas and/or fuel oil. However, the recent crisis regarding the Bolivian natural gas supply to Brazil increased the risk of a shortage of this energy source. Hence, the uncertainty of the electricity supply scenario is pushing the electricity prices up in the near future. A possible alternative to increase the electricity supply is the maximization of the electricity surplus in sugarcane mills. Back in 1970's and 1980's, cogeneration plants in sugarcane mills were primarily designed to consume all bagasse, and produce steam and electricity to the process. The plants used medium pressure steam boilers (21 bar and 300 deg C) ...
2008-07-01
Energy Technology Data Exchange (ETDEWEB)
The objective of the research was to develop a procurement method for small-diameter pulpwood based on chain-flail delimbing-debarking method. The study consisted of four parts: Development of the chain-flail delimbing-debarking method (based on Peterson Pacific DDC 5000 device); Combined chain-flail delimbing and drum-debarking; Processing and procurement of the chain-flail delimbing chips and; Intensifying of the timber debarking in chain-flail delimbing. The project was coordinated by Metsaeteho, and it was carried out as cooperation between Metsaeteho, the Finnish Forest Research Institute (METLA), VTT Energy, Pertti Szepaniak Oy and Enso-Gutzeit Oy. A calculation model, by which it is possible to determine the costs of pulpwood chips and fuel-rawmaterials formed beside the pulpwood chips while using different kinds of procurement methods and chains, was developed for chain-flail delimbing-debarking-chipping method ...
1996-12-31
Device for energy-saving heating of fuel in the fuel supply for an internal combustion engine
Energy Technology Data Exchange (ETDEWEB)
The invention concerns a device for the energy-saving heating of fuel in the supply pipe to an internal combustion engine to regain energy from the fuel itself, particularly but not exclusively for a Diesel engine. A part of the quantity of heat added to the fuel between the tank and the injection nozzles is given up by excess fuel not to the tank, but to the fuel lifted upstream of the injection pump. The device is characterised by the fact that it has a heat exchanger, which absorbs heat from the fuel at the level of the injection pump or upstream of it, and takes this to the fuel above the injection pump. The heat exchanger is preferably mounted upstream of a filter and close to it. A bridging pipe, which may be integrated in the heat exchanger, permits the heat exchanger to be short-circuited depending on the fuel ...
1981-02-10
International Nuclear Information System (INIS)
The cross section and activity profile of different radioisotopes produced by #alpha#-induced nuclear reaction on natural zirconium, have been obtained by stacked foil activation using 40 MeV #alpha#-particles from Variable Energy Cyclotron (VEC) machine at Calcutta. The activity profile would be used to study the surface loss of zircaloy materials of engineering components by thin layer activation (TLA) technique. Generally, isotopes with suitable #gamma#-rays and long half-lives are the most useful in TLA technique, e.g., "9"2Nb, "9"5"gNb and "9"5Zr. (author). 2 refs., 1 tab.
1995-02-01
Study of even-A zirconium and strontium isotopes with the (d,"6Li) reaction
International Nuclear Information System (INIS)
All stable even-A molybdenum isotopes and sup(90,92)Zr have been investigated with the (d, "6Li) reaction at Esub(d) = 45 MeV to study proton- and neutron-pair correlations. Differential cross sections were measured for states up to Esub(x) = 3 MeV in "8"6Sr, sup(88,92,94,96)Zr and up to 6 MeV in "8"8Sr and "9"0Zr. Particular attention was paid to the comparison of #alpha#-pickup data with two-nucleon pickup data. The population of low-lying 0"+ and 5"- states for two-neutron and four-nucleon pickup reactions was calculated using simple phenomenological wave functions for the initial and final states. The results of these calculations are in satisfactory agreement with the data. (orig.).
Some sensitivities during a LWR severe core-damage sequence
International Nuclear Information System (INIS)
Stable boiloff of core water during a severe LWR accident, that is, boiloff driven only by the decay power generated below the water level, is tractable analytically and is relatively insensitive to axial power distribution. As might be expected, calculated accident event times are sensitive to the fidelity of the decay power model. During later stages of boiloff, heat transfer or transport of energy from above the water level to the residual water can result in an unstable condition during which the boiloff rate increases greatly. The unstable boiloff phenomenon illustrates the highly nonlinear influence of core heat transfer during meltdown and emphasizes the great accuracy requirements which attend the modeling of the accident during periods of enhanced heat transfer when significant zirconium oxidation is possible.
1981-12-04
Microstructure and fracture toughness of hot pressed zirconia-toughened sialon
International Nuclear Information System (INIS)
Zirconia-toughened sialon composites have been fabricated using conventional hot-pressing techniques. The fracture toughness and microstructure were determined for CeO_2- and Y_2O_3-stabilized ZrO_2 additives and also as a function of volume percent ZrO_2. The Yttria system showed a linear increase in fracture toughness with increasing volume fraction zirconia content while the ceria-stabilized system exhibited a peak in fracture toughness at 20 vol% ZrO_2 content. The fracture toughness at 800 C was measured and correlated with the microstructure. High-temperature stability was determined and it was found that the deleterious nitride phases of zirconium could be precluded from the microstructure.
Manufacturing of Austenitic Stainless Steel-Zirconia Composites by Infiltration
British Library Electronic Table of Contents (United Kingdom)
Abstract Within the framework of the CRC 799 -TRIP-Matrix-Composites- at the TU Bergakademie Freiberg new composite materials consisting of TRIP steel and zirconium dioxide ceramics are designed in a powder route and a casting route. To manufacture faultless samples basic investigations of the feeding and infiltration behaviour within macro porous ceramics such as filters were needed. The effects of bottom pouring and top pouring were investigated as well as the effects of different preheating temperatures, contents of phosphorous in the steel and flow trough rates. Bottom pouring corrupts the feeding mainly of filters with high ppi (pores per inch). Top pouring improves the feeding, but generates inhomogeneous infiltration qualities, which can affected and enhanced by a increasing preheat...
2011-01-01
British Library Electronic Table of Contents (United Kingdom)
Spherical nano-sized YSZ (yttria stabilized ZrO2) powders were successfully synthesized via a reverse microemulsion system. The water droplets in the microemulsion system of yclohexane/water/span85/Triton X-100/hexyl alcohol can act as the nano-reactors which solubilize zirconium oxychloride and ammonia water separately. The minute original reactors are favor to the formation of nano-sized spherical YSZ powders and the dispersibility of the powders can be controlled effectually by adjusting the weight ratio of the LiNO3 molten salt to the precursor. The phase transformation from cubic to monoclinic starts at and 500??C and finally monoclinic and cubic phase with increased crytallinity coexist at 800??C. The effect of LiNO3 molten salt in the formation of YSZ powders was also discussed.
2008-01-01
Development of long-life BF3 counters
Energy Technology Data Exchange (ETDEWEB)
In order to improve the well-known short operational life time of BF3 counters, three potential adsorbents for impurity gases (graphite, activated charcoal and a zirconium-aluminum mixture) were introduced into BF3 counters in the form of coating on the aluminum cathode surface. Tests in el fields revealed that a partial coating of activated charcoal provides the best result. The improvement of their operational life in el fields was about three orders of magnitude in terms of tolerable exposure. Many counters with a partial coating of activated charcoal were further tested from the following viewpoints: background noise, vibration and shock, el pulse discrimination, operational life in a neutron field and non-operational in-reactor exposure life. The results were satisfactory for reactor control and protection usage. (author).
1985-02-01
Behavior of Stress-Relaxation phenomena in Zr-1.1Nb-0.05Cu
International Nuclear Information System (INIS)
Zirconium alloys have anisotropic mechanical properties depending on their physical orientations and are widely used as nuclear materials such as cladding tube material. An operation condition of the nuclear reactor requires a high creep resistance, because it is subjected to long period operations, high temperature and high pressure. Generally, it takes a few days or months to do the creep experiment, so it is difficult to get a data in short period. However, there is a way to predict a creep property by using the stress-relaxation in the short term. These studies realized the stress-relaxation through a compressive test of HANA-6 (Zr-1.1Nb-0.05Cu) alloy that was developed by KAERI (Korea Atomic Energy Research Institute), and then predicted the creep property
2010-10-01
Alpha-particle dose distribution effects at the cellular level
International Nuclear Information System (INIS)
Ionizing radiations that differ in number, size, and distribution of energy deposition events might be expected to cause different effects for the same absorbed dose. Furthermore, microdosimetry calculations suggest that large variations in biological effectiveness might be expected for internally deposited alpha-emitting radionuclides for the same absorbed dose, depending upon the specific activity and spatial distribution of the sources in tissue. The study described in this article was designed to demonstrate these phenomena in vitro. Cultured Chinese hamster ovary (CHO-K1 BH4) cells were exposed in vitro to inert, insoluble ceramic microspheres in zirconium dioxide labeled with "2"3"9Pu. The average exit energy of the 5.15 MeV alpha particle was calculated to be 4.3 MeV. Exposure times varied from four to seven hours to achieve the desired dose level.
1985-02-01
Energy Technology Data Exchange (ETDEWEB)
The use of vegetable oils as a fuel in diesel engines causes some problems due to their high viscosity compared with conventional diesel fuel. Various techniques and methods are used to solve the problems resulting from high viscosity. One of these techniques is fuel blending. In this study, a blend of 50% sesame oil and 50% diesel fuel was used as an alternative fuel in a direct injection diesel engine. Engine performance and exhaust emissions were investigated and compared with the ordinary diesel fuel in a diesel engine. The experimental results show that the engine power and torque of the mixture of sesame oil-diesel fuel are close to the values obtained from diesel fuel and the amounts of exhaust emissions are lower than those of diesel fuel. Hence, it is seen that blend of sesame oil and diesel ...
2008-08-15
Turbulent Flame Speed Characteristics Of High-Pressure, Lean Premixed Methane / Air Flames
Energy Technology Data Exchange (ETDEWEB)
High-pressure, lean, premixed methane/air flames are investigated experimentally to determine turbulent flame speeds (s{sub T}). The results are based on the statistical analysis of single-shot OH-PLIF images. The influences of pressure (p = 5 - 14.4 bars) and equivalence ratio ( {phi} 0.43 - 0.56) on the turbulent flame speed are discussed. The analysis reveals that s{sub T} is independent of pressure and it depends strongly on equivalence ratio. The turbulent flame speed at {phi} = 0.56 is about 3 times higher than at {phi} = 0.43 because of the higher integral reaction rate caused by the higher fuel concentration and therefore higher adiabatic flame temperature. (author)
2005-03-01
British Library Electronic Table of Contents (United Kingdom)
The analysis of complex fluids such as crude oils, fuels, vegetable oils and mixed waste streams poses significant challenges arising primarily from the multiplicity of components, the different properties of the components (polarity, polarizability, etc.) and matrix properties. We have recently introduced an analytical strategy that simplifies many of these analyses, and provides the added potential of linking compositional information with physical property information. This aspect can be used to facilitate equation of state development for the complex fluids. In addition to chemical characterization, the approach provides the ability to calculate thermodynamic properties for such complex heterogeneous streams. The technique is based on the advanced distillation curve (ADC) metrology, wh...
2010-01-01
Energy Technology Data Exchange (ETDEWEB)
Based on the enhanced cooperation between Republic of Korea (ROK) and International Atomic Energy Agency (IAEA), IAEA installed new safeguards equipment (Unattended Monitoring System, UMS) at Wolsung unit 2 on January, 2005. The UMS was utilized in parallel with traditional human surveillance during the transfer campaign of Wolsung unit 2 (7 March - 22 July). Installation of UMS at all Wolsung units will be decided on the basis of the result of this test. The transfer campaign with UMS at Wolsung units 2 and 4 was started from September 1, 2006 at the same time. Implementation of UMS to the transfer campaign in Wolsung site will be considerably reduced the IAEA's inspection effort and burden of operator.
2006-07-01
International Nuclear Information System (INIS)
Based on the enhanced cooperation between Republic of Korea (ROK) and International Atomic Energy Agency (IAEA), IAEA installed new safeguards equipment (Unattended Monitoring System, UMS) at Wolsung unit 2 on January, 2005. The UMS was utilized in parallel with traditional human surveillance during the transfer campaign of Wolsung unit 2 (7 March - 22 July). Installation of UMS at all Wolsung units will be decided on the basis of the result of this test. The transfer campaign with UMS at Wolsung units 2 and 4 was started from September 1, 2006 at the same time. Implementation of UMS to the transfer campaign in Wolsung site will be considerably reduced the IAEA's inspection effort and burden of operator.
2006-11-02
Structural material trends in future power plants
Energy Technology Data Exchange (ETDEWEB)
Future power plants will be more fuel efficient, environmentally benign, and economical than current power plants. A high performance power system (HIPPS), based on a coal-fired combined cycle, is currently being developed. The corrosion and temperature-strength properties of currently available metallic materials limit the maximum efficiency of this cycle. Recently, ceramic matrix composites have shown promise in overcoming the design limitations on the future power plants. In particular, the high-temperature, and corrosion and erosion resistant properties of continuous fiber ceramic composites (CFCCs) will allow engineers to design high-temperature heat exchangers, cyclone vortex finder tubes, and other components. Research being performed to evaluate candidate materials for use in future power plants is discussed.
2000-07-01
Status of electric power in the Missouri River Basin
Energy Technology Data Exchange (ETDEWEB)
This third Missouri River Basin Commission report on Status of Electric Power in the Missouri River Basin provides information on the status of electric power generation, future needs, and potentials for meeting these needs. Information for this 1980 update is based upon available published information up to and including December 31, 1979. State and federal members of the Missouri River Basin Commission provided information for sections of the report and on legislative activities. Information is included on the planning and projected costs of hydro, nuclear and fossil-fuel power plants, pumped-storage plants, transmission systems, projected power demands, the environmental, socio-economic-cultural impacts of electric power generation, and regulations affecting energy development. (LCL)
1980-01-01
Spray, combustion, and heat transfer studies in a Ricardo hydra direct-injection diesel engine
Energy Technology Data Exchange (ETDEWEB)
The spray and combustion development in a single-cylinder, direct-injection diesel engine equipped with optical access was examined using a number of complementary techniques. A laser imaging system, based around a pulsed copper-vapour laser synchronised to an intensified CCD camera, was used to obtain images of the four fuel sprays prior to combustion, and to determine the tip penetration of each spray as a function of crankangle. The surface heat flux to the wall of the piston bowl was measured by placing a fast-response thermocouple at the impingement point of one of the sprays, and a two-colour imaging system was used to obtain digital images of the flame temperature and equivalent soot distribution in the cylinder. (author)
1996-12-31
Sensitivity analysis: Interaction of DOE SNF and packaging materials
International Nuclear Information System (INIS)
A sensitivity analysis was conducted to evaluate the technical issues pertaining to possible destructive interactions between spent nuclear fuels (SNFs) and the stainless steel canisters. When issues are identified through such an analysis, they provide the technical basis for answering what if questions and, if needed, for conducting additional analyses, testing, or other efforts to resolve them in order to base the licensing on solid technical grounds. The analysis reported herein systematically assessed the chemical and physical properties and the potential interactions of the materials that comprise typical US Department of Energy (DOE) SNFs and the stainless steel canisters in which they will be stored, transported, and placed in a geologic repository for final disposition. The primary focus in each step of the analysis was to identify any possible phenomena that could potentially compromise the structural integrity of the canisters and to ...
1999-06-06
Requirement of decontamination factor for near-surface disposal of PEACER wastes
International Nuclear Information System (INIS)
A pyrochemical process has been introduced and utilized so that the transmutation of spent PWR fuel in PEACER can produce mainly low and intermediate level waste for near surface disposal. Major radioactive nuclides from PEACER pyroprocessing are composed of TRU and LLFP. In this study, the requirement for the final waste from PEACER is evaluated based on the methodology for establishment of waste acceptance criteria. Also, sensitivity analysis for several input parameters is conducted in order to determine acceptable decontamination factor (DF) and LLFP removal efficiency and to find out input parameter that extremely have an effect on DF. As a result of the study, TRU DF and LLFP removal efficiency have to be achieved more than 1.0E+04 - 1.0E+05 and 96%, respectively. (author)
2005-10-09
British Library Electronic Table of Contents (United Kingdom)
Complex fluids have long posed a significant challenge in our ability to characterize and model fluid properties. Here, we consider complex fluids to be mixtures with many components that can differ significantly in polarity and polarizability. The penultimate complex fluid is crude oil, although many other fluids such as finished fuels are also highly complex. We have recently introduced a measurement strategy that can simplify these efforts and provides the added potential of linking chemical composition (i.e. analytical) information with physical property information. In addition to chemical characterization, the approach provides the ability to calculate thermodynamic and transport properties for such complex heterogeneous streams. The technique is based on the advanced distillation cu...
2010-01-01
Energy Technology Data Exchange (ETDEWEB)
The Riskaudit 7 report has been made by a group of independent experts from Western European countries representing technical organizations specialized in the support of regulatory bodies of those countries. It represents a preliminary estimation of the Ukrainian WWER B 213 and B 320 reactors, based on the example of Rovno NPP, analysed with a Western practice. The first part of the document covers the following aspects of the report: core design and fuel management; pressurized components; electrical supply; instrumentation and control; containment; internal events; site conditions and external events.
1994-07-15
British Library Electronic Table of Contents (United Kingdom)
This study presents new software, called Google Earth-based Optimal HAulage RouTing System (GEOHARTS), to improve the functionality of Google Earth for optimal haulage routing of off-road dump trucks in construction and mining sites. A modified least-cost path algorithm, which is applicable to working areas with both paved and unpaved temporary roads and can consider the effects of terrain relief and curves along a route on the route planning, was proposed and utilized for the software development. GEOHARTS can determine optimal haulage routes between loaders and dumps that ensure the least travel time or fuel consumption of off-road dump trucks and can visualize the results using an embedded 3D render window of Google Earth. The application to the Pasir open-pit coal mine in Indonesia dem...
2011-01-01
International Nuclear Information System (INIS)
A numerical analysis method for melting/solidification phenomena has been developed to evaluate a feasibility of several candidate techniques in the nuclear fuel cycle. Our method is based on the eXtended Finite Element Method (X-FEM) which has been used for moving boundary problems. Key technique of the X-FEM is to incorporate signed distance function into finite element interpolation to represent a discontinuous gradient of the temperature at a moving solid-liquid interface. Construction of the finite element equation, the technique of quadrature and the method to solve the equation are reported here. The numerical solutions of the one-dimensional Stefan problem, solidification in a two-dimensional square corner and melting of pure gallium are compared to the exact solutions or to the experimental data. Through these analyses, validity of the newly developed numerical analysis method has been demonstrated. (author)
2008-06-01
British Library Electronic Table of Contents (United Kingdom)
This paper investigates various usages of natural gas (NG) as an energy source for different hydrogen production technologies. A comparison is made between the different methods of hydrogen production, based on the total amount of natural gas needed to produce a specific quantity of hydrogen, carbon dioxide emissions per mole of hydrogen produced, water requirements per mole of hydrogen produced, and a cost sensitivity analysis that takes into account the fuel cost, carbon dioxide capture cost and a carbon tax. The methods examined are the copper-chlorine (Cu-Cl) thermochemical cycle, steam methane reforming (SMR) and a modified sulfur-iodine (S-I) thermochemical cycle. Also, an integrated Cu-Cl/SMR plant is examined to show the unique advantages of modifying existing SMR plants with new h...
2010-01-01
Improvements on burnup chain model and group cross section library in the SRAC system
Energy Technology Data Exchange (ETDEWEB)
Data and functions of the cell burnup calculation of the SRAC system were revised to improve mainly the accuracy of the burnup calculation of high conversion light water reactors (HCLWRs). New burnup chain models were developed in order to treat fission products (FPs) and actinide nuclides in detail. Group cross section library, SRACLIB-JENDL2, was generated based on JENDL-2 nuclear data file. In generating this library, emphasis was placed on FPs and actinides. Also revised were the data such as the average energy release per fission for various actinides. These improved data were verified by performing the burnup analysis of PWR spent fuels. Some new functions were added to the SRAC system for the convenience to yield macroscopic cross sections used in the core burnup process. (author).
1992-01-01
Improvements in the cost of liquid fuels from direct coal liquefaction
International Nuclear Information System (INIS)
This paper presents an assessment of recent improvements in the technology for direct coal liquefaction on the estimated commercial economics. The basis for the design and cost estimates is a series of studies sponsored by Amoco Corporation and Electric Power Research Institute, which were derived from the highly detailed Breckinridge Project, completed in the early 1980s under DOE sponsorship. The technology, design, and cost estimates reflect the current two-stage liquefaction technology practiced at the Advanced Coal Liquefaction Research facility in Wilsonville, Alabama. Details of the design bases and cost estimates and how they compare with the original Breckinridge study are described. Also examined are effects of feed coal rank, product slate, and the source of hydrogen (natural gas or coal) on the costs. Finally, the ways that projected future improvements in the technology will change the design and lead to lower costs are discussed. 7 refs., 5 figs., 7 ...
Gasification of waste from furniture industries for generation of sustainable energy
Energy Technology Data Exchange (ETDEWEB)
The global interest in renewable energy is attributed to the decline in fossil fuel sources and the need for technical, economic, social and environmental sustainability. This study focused on the new techniques that have been developed for the use of biomass for energy from wood wastes from the forest-based industry. As an energy source, wood waste contributes positively to the environment by reducing environmental problems related to contamination of soil, air and water through improper disposal of waste. Biomass gasification has the advantage of converting biomass into a combustible gas that can be used for heat generation, electricity and synthesis of chemicals. Syngas produced from gasification of eucalyptus residues has significant potential, with an average High Heating Value of 6.60 MJ/m{sup 3}, and regular composition during the process, with predominance of carbon monoxide, followed by hydrogen, carbon dioxide and methane.
2010-07-01
Energy Technology Data Exchange (ETDEWEB)
A new fuel-cell electrocatalyst based on highly porous carbonized polyacrylonitrile (PAN) microcellular foam with platinum particles was prepared recently in this laboratory. Its surface morphology, one of the most important aspects of a practical electrocatalyst, has been examined in terms of fractal theory and methods. The fractal dimension of the platinum particles dispersed in porous carbonized PAN foam was determined by using chronometric and rotating-disk-electrode methods in oxygen-saturated solutions. A fractal dimension smaller than 2 was obtained, which was attributed to the partially active nature of the surface of this electrocatalytic material. This value of fractal dimension is also proposed to be considered as a reaction dimension. A reaction dimension smaller than 2 may indicate that not all of the platinum particle surface is accessible to the incoming oxygen molecules.
1997-05-01
Feasibility of biomass-fuelled steam turbine cogeneration for olive oil pressing plants
Energy Technology Data Exchange (ETDEWEB)
The adoption of a cogenerator integrated system is described. The dry kernel, a woody residue of olive pressing, is produced in very large quantities and could therefore be used in high pressure condensing-extraction team turbines to supply on-site electricity and steam needs. This system is becoming more and more interesting since it produces an excess of electricity which could be sold, e.g. to the electric utility. Such a cogeneration system is discussed in terms of efficiency, capital cost, near-time commercial viability and power-to-fuel costs. The economical analysis is presented for olive press-cake processing plants and can be extrapolated to biomass-based industries having the same characteristics. An energy audit has been carried out on 16 plants. (Author)
1994-01-01
British Library Electronic Table of Contents (United Kingdom)
The molten salt reactor (MSR), which is one of the generation IV reactors, can meet the demand of transmutation and breeding. The thermodynamic properties of the molten salt system like LiF-NaF-BeF2 influence the design and construction of the fuel salt and coolant in the MSR for the new generation. In this paper, the equation of state of the ternary system 15%LiF-58%NaF-27%BeF2, over the temperature range from 873.15 to 1 073.15 K at one atmosphere pressure, is described using a modified Peng-Robinson (PR) equation. The densities of the ternary system and its components are estimated by this equation directly, and compared with the experimental data. Based on the equation of state, the other thermodynamic properties such as the enthalpy, entropy and heat capacity at constant pressure are ...
2007-01-01
Emissions and efficiency from production cooktop burners firing natural gas
Energy Technology Data Exchange (ETDEWEB)
Investigations were conducted on the range of emission rates of NO, NO[sub 2], CO and hydrocarbons, and the thermal efficiencies produced by each burner on three production cookers, supplied by different Australian manufacturers. It was found that the emissions and efficiencies were markedly affected by (1) the thermal input, both with and without a load on the burner, and (2) the load-height to flame-length ratio, with a load on the burner. The effect of hydrocarbon leakage into the secondary/dilution air was investigated, to explain the observed correlation of hydrocarbon emission rate with dilution air flow. The hydrocarbons were found to arise from two sources: -leakage from the stabilisation ports at the base of the burner, which was found to be significant at the higher thermal input; -incomplete combustion of the fuel in the premix, which was the dominant source of hydrocarbons emissions at the lower thermal input. (author)
1994-12-01
International Nuclear Information System (INIS)
A series of cyclic voltammetry, chronoamperometry and electrochemical impedance experiments have been carried out in order to investigate the effect of cathode composition and porosity on the electrochemical characteristics of strontium-doped lanthanum, praseodymium and gadolinium cobaltite cathodes. The impedance responses at different electrode potentials of the half cell and symmetric single cell setups are compared and analyzed by the equivalent circuit modeling method. The deconvolution of impedance spectra for single cell cathode and anode reactions contributions based on the results of simultaneous analysis of half cells and symmetric single cells has been made by differential impedance real part vs. ac frequency plot analysis method. Noticeable influence of cathode chemical composition, meso-porosity and macro-porosity on the electrochemical activity of the oxygen electroreduction has been demonstrated. Seeming activation energy values have been calculated ...
2010-11-01
Electricity generation from rice husk in Indian rice mills: potential and financial viability
Energy Technology Data Exchange (ETDEWEB)
Rice husk generated as a by-product of rice processing is an important energy resource. The availability of this resource in India has been assessed and the technologies for exploitation of its energy potential in rice processing industry discussed. Nomographs have been developed for estimation of the husk required to meet the energy demand of parboiling, drying and milling operations. The unit cost of electricity using rice husk gasifier-based power generation systems has been calculated and its financial feasibility assessed in comparison with utility-supplied and diesel-generated electricity. With the cost and efficiency data assumed here, the unit cost of electricity produced by rice husk gasifier-dual fuel engine-generator system varies between Rs 2/kWh and Rs 7/kWh. (author)
1996-10-01
Electricity generation from rice husk in Indian rice mills: potential and financial viability
Energy Technology Data Exchange (ETDEWEB)
Rice husk generated as a by-product of rice processing is an important energy resource. The availability of this resource in India has been assessed and the technologies for exploitation of its energy potential in the rice processing industry discussed. Nomographs have been developed for estimation of the husk required to meet the energy of parboiling, drying and milling operations. The unit cost of electricity using rice husk gasifier-based power generation systems has been calculated and its financial feasibility assessed in comparison with utility-supplied and diesel-generated electricity. With the cost and efficiency data assumed here, the unit cost of electricity produced by rice husk gasifier-dual fuel engine-generator system varies between Rs 2/kWh and Rs 7/kWh. (35 Rs approximates to SUS 1.). (author)
1998-12-31
Energy Technology Data Exchange (ETDEWEB)
Recently it is strongly required to reduce energy consumption to cope with the global warming. Since energy consumption in commercial and residential sectors are increasing while industrial sector is almost constant in Japan, policies to lead energy conservation in urban areas is quite important. This study aims at investigating the performance of urban energy systems which install combined heat and power (CHP) as a district heating and cooling (DHC) plant and the influence of CHP on the structure of electric power systems of utilities. The behavior of energy technologies and the possibility of energy conservation are evaluated based on an optimization model with respect to total system cost. Sensitivity analysis of population allocation into urban areas indicates that fossil fuel consumption varies in the range of 10--20% compared with conventional systems.
1997-12-31
Direct solar thermal-to-electric energy conversion using thermophotovoltaics
Energy Technology Data Exchange (ETDEWEB)
Thermophotovoltaic energy conversion achieves direct conversion of thermal energy to electricity without the need for complex dynamic machinery operating in one of several possible thermodynamic cycles. This paper presents an analysis of a hybrid solar thermophotovoltaic (STPV) energy conversion system in which a receiver/photovoltaic (PV) array subsystem is powered by either a solar concentrator or a fossil fuel combustion source. The overall TPV system efficiency is calculated using an appropriate selective emitter and a spectrally tuned solar cell designed to achieve maximum conversion efficiency in the narrow band emitted by the selective emitter. Two limiting cases are examined to place upper and lower bounds on system performance. The estimates of system performance are based on actual experimental data from PV cells and selective emitters.
1995-10-01
The economic benefits of supplemental fuel injections depend, in part, on the coke replacement ratio. An assessment of the accuracy with which blast furnace coke rate may be measured and a determination of the key drivers of coke rate uncertainty are offered, to provide guidance for experiments in high-rate gas injection. Using statistical analysis tools, an expression for the measurement error associated with the various terms of blast furnace carbon balance is developed. Coke rate calculations based on the material balance are most sensitive to coke carbon content and to proper tracking of hot metal tapping schedule.
1992-09-01
Development and implementation of methods for determination of the origin of nuclear materials
International Nuclear Information System (INIS)
The determination of the origin of seized nuclear material is important for authorities in the context of the criminal investigation, in order to return the material to its last legal owner and to help preventing any further diversion of material from this source. Origin determination is based on a complex pattern of parameters obtained through analytical measurements. The information required to determine the origin of nuclear materials may be divided into two categories: endogenous information (e.g. age or mode of production of the material) which is self-explanatory; whereas exogenous information (e.g. dimensions, surface roughness, impurities) requires a database to which the parameters can be compared. The Institute for Transuranium Elements has developed methods to determine characteristic parameters like impurities, surface roughness, or microstructural information. Furthermore, a database was set up containing relevant information on reactor ...
2001-10-01
During 1978 the Engineering Board of SRC granted Specially Promoted Program status to the Coal Technology program. This recognized that coal would increase in importance as the cost of liquid and gaseous hydrocarbons rises with the decreasing availability of petroleum related sources. It was, therefore, considered necessary to anticipate and improve, through SRC supported research, the technologies required to win, transport, convert to liquid and gaseous fuels and utilize coal and coal based substances. In view of the interest in the program, and also in the hope of reaching a still wider audience the reports of the two meetings have been combined in this single booklet. The reports indicate specific problems of importance in coal winning and coal conversion but, naturally, do not cover all of the program priorities.
1980-10-01
Benefit analysis and evaluation of pumped-storage plant in Taipower system
Energy Technology Data Exchange (ETDEWEB)
The operation of pumped-storage plants (PSP) is based on the daily load variations of power demand. It performs power generation at peak load times during the day, and pumps water up into the reservoir during the off-peak times at night. In the Taipower system in Taiwan, there are two pumped storage plants with ten units. These had a total installed capacity of 2,602 MW or a 12 percent capacity at the end of 1995. The plants were able to reduce system generation costs and improve reliability. A Pumped-Storage Plant Benefit Analysis (PSPBA) program was established using the principle of economic dispatch in 1985. This paper explains the rules of the program, the analysis results of the past 10 years, and a a cost benefit evaluation. It was found that the advantages of PSP are not only in supplying the power for peak load, but also in decreasing the total fuel cost. 5 figs., 4 refs.
1995-12-31
International Nuclear Information System (INIS)
Nuclear forensic science has become increasingly important for global nuclear security. However, many current laboratory analysis techniques are based on methods developed without the imperative for timely analysis that underlies the post-detonation forensics mission requirements. Current analysis of actinides, fission products, and fuel-specific materials requires time-consuming chemical separation coupled with nuclear counting or mass spectrometry. High-temperature gas-phase separations have been used in the past for the rapid separation of newly created elements/isotopes and as a basis for chemical classification of that element. We are assessing the utility of this method for rapid separation in the gas-phase to accelerate the separations of radioisotopes germane to post-detonation nuclear forensic investigations. The existing state of the art for thermo chromatographic separations, and its applicability to nuclear forensics, will be ...
2011-07-01
Architects and engineers guide to energy conservation in existing buildings
Energy Technology Data Exchange (ETDEWEB)
The manual enhances and simplifies the work of those architects and engineers whose practice includes the analysis and modification of existing buildings to reduce both fuel consumption and operating costs. A review of the principles of energy use and conservation is given. The manual also provides a step-by-step methodology for assessing and improving the year-round energy performance of buildings, as well as a series of forms, charts, and nomographs designed to serve as day-to-day tools in the energy professional's toolbox. After a cost-benefit analysis is prepared for each conservation opportunity, the owner will be able to implement decisions based on projected energy savings and calculate investment costs, operational changes, and payback periods. Each of these considerations is accorded a detailed treatment.
1980-02-01
Energy Technology Data Exchange (ETDEWEB)
A two-phase flow regime map is developed experimentally and theoretically for a vertical hexagonal flow channel with and without a 36-finned rod hexagonal bundle. This type of flow channel is of interest to MAPLE-type nuclear research reactors. The flow regime maps are determined by visual observations and observation of waveforms shown by a capacitance-type void fraction meter. The experimental results show that the inclusion of the finned hexagonal bundle shifts the flow regime transition boundaries toward higher water flow rates. Existing flow regime maps based on pipe flow require slight modifications when applied to the hexagonal flow channel with and without a MAPLE-type finned hexagonal bundle. The proposed theoretical model agrees well with experimental results.
1997-05-01
International Nuclear Information System (INIS)
A two-phase flow regime map is developed experimentally and theoretically for a vertical hexagonal flow channel with and without a 36-finned rod hexagonal bundle. This type of flow channel is of interest to MAPLE-type nuclear research reactors. The flow regime maps are determined by visual observations and observation of waveforms shown by a capacitance-type void fraction meter. The experimental results show that the inclusion of the finned hexagonal bundle shifts the flow regime transition boundaries toward higher water flow rates. Existing flow regime maps based on pipe flow require slight modifications when applied to the hexagonal flow channel with and without a MAPLE-type finned hexagonal bundle. The proposed theoretical model agrees well with experimental results.
1997-01-01
1988 EEI (Edison Electric Institute) power directory
Energy Technology Data Exchange (ETDEWEB)
Generated annually from the Edison Electric Institute's POWER STATISTICS Data Base, the EEI Power Directory provides state-by-state data on all utility-owned steam-electric plants in the US. The 1988 directory contains the following information for approximately 2500 units located at 1000 generating sites around the country: unit age, capacity, fuel type, and operating status. In addition, solid waste disposal methods for fly ash, bottom ash, and sludge are covered for approximately 1500 US coal-fired units. The directory contains a listing of more than 800 environmental managers and key environmental staff at over 300 utilities, with names, addresses, and telephone numbers. Special indices list plants and utility owner-operators.
1988-05-01
Experience of HWR nuclear fuel fabrication technology development in Korea
Energy Technology Data Exchange (ETDEWEB)
Since January, 1981, the project of development of nuclear fuel fabrication technology for Wolsung reactor (CANDU type) was undertaken by KAERI(Korea Advanced Energy Research Institute) and successfully fulfilled with loading 24 fuel bundles made by KAERI in Wolsung reactor in September, 1984. On the basis of this accumulated technology and experience, mass production plan to supply all the nuclear fuels for Wolsung reactor is under way. In this presentation, the Korean experience in the development of the nuclear fuel fabrication technology, safety and performance evaluation of KAERI fuel and the results of irradiation of KAERI fuels in Wolsung reactor will be described.
1985-07-01
Experience of HWR nuclear fuel fabrication technology development in Korea
International Nuclear Information System (INIS)
Since January, 1981, the project of development of nuclear fuel fabrication technology for Wolsung reactor (CANDU type) was undertaken by KAERI(Korea Advanced Energy Research Institute) and successfully fulfilled with loading 24 fuel bundles made by KAERI in Wolsung reactor in September, 1984. On the basis of this accumulated technology and experience, mass production plan to supply all the nuclear fuels for Wolsung reactor is under way. In this presentation, the Korean experience in the development of the nuclear fuel fabrication technology, safety and performance evaluation of KAERI fuel and the results of irradiation of KAERI fuels in Wolsung reactor will be described.
1985-10-29
Energy Technology Data Exchange (ETDEWEB)
The aim of this case study is to analyse the socio-economic effects of forest fuel supply and use chains. Two of the four cases are rural district heating plants. In Perho, the co-operative organisation of forest owners maintains the fuel supply and operates the plant. In Ruukki, the local forestry association supplies forest chips to the plant. These medium-scale plants use small-sized trees from young thinning stands as their main fuel. The trees are felled manually. The other two cases are large power plants. Alholmens Kraft's new power plant in Pietarsaari aim to use 250 000 solid-m3 of forest chips annually. The logging residues are hauled to the plant as bales using traditional timber harvesting equipment or as bulk material. At young thinning stands the trees are harvested using an accumulating feller buncher. The Toppila I and II power plants in the city of Oulu used about 36 000 solid-m3 of forest chips. ...
2003-07-01
Sulfur Management of NOx Adsorber Technology for Diesel Light-Duty Vehicle and Truck Applications
Energy Technology Data Exchange (ETDEWEB)
Sulfur poisoning from engine fuel and lube is one of the most recognizable degradation mechanisms of a NOx adsorber catalyst system for diesel emission reduction. Even with the availability of 15 ppm sulfur diesel fuel, NOx adsorber will be deactivated without an effective sulfur management. Two general pathways are currently being explored for sulfur management: (1) the use of a disposable SOx trap that can be replaced or rejuvenated offline periodically, and (2) the use of diesel fuel injection in the exhaust and high temperature de-sulfation approach to remove the sulfur poisons to recover the NOx trapping efficiency. The major concern of the de-sulfation process is the many prolonged high temperature rich cycles that catalyst will encounter during its useful life. It is shown that NOx adsorber catalyst suffers some loss of its trapping capacity upon high temperature lean-rich exposure. With the use of a disposable SOx ...
2003-10-01
Present status of study on reduced-moderation water reactors
Energy Technology Data Exchange (ETDEWEB)
The Reduced-Moderation Water Reactor (RMWR) is a next generation water-cooled reactor, based on the experienced light water reactor (LWR) technology, aiming at effective utilization of uranium resources, high burn-up and long operation cycle and plutonium multiple recycling. These characteristics can be achieved by the high conversion ratio from {sup 238}U to {sup 239}Pu resulted from the higher neutron energy spectrum in comparison to conventional LWRs. Considering the extension of LWR utilization, Japan Atomic Energy Research Institute (JAERI) started the research on it in 1997 and then started a collaboration in the conceptual design study with the Japan Atomic Power Company (JAPC) in 1998, under technical cooperation with three Japanese reactor vendors. In the core design study of the RMWR, several basic core designs with the high conversion ratio more than 1 and the negative void reactivity coefficient have been proposed, and then, subsequent investigation on ...
2001-09-01
Overall analysis of the cost key factors for the nuclear energy
International Nuclear Information System (INIS)
In 1995, 25,8 % of the world electricity consumption was of nuclear origin, while in the EU this figure is increased up to 50,6 %. In order to maintain and even to increase its share in the electricity generation, Nuclear Energy needs to achieve a good economic performance as a base load source when compared with its competitors, basically coal and gas fired plants. Fossil-fired generation costs have declined over the past ten years, mainly due to lower fossil fuel prices. This factor together with the recently observed tendency of higher discount rates to be applied are challenging the attractiveness of the nuclear energy. Nuclear energy is a capital intensive option. Taken into account extensive standardization programs has been established aiming at cost reductions as well as to increase efficiency of nuclear energy utilization, among their main purposes. Externalities play an important role, as they are already internalized in nuclear ...
1996-10-02
Energy Technology Data Exchange (ETDEWEB)
The dissolution of NiO cathodes during cell operation is a limiting factor to the successful commercialization of molten carbonate fuel cells (MCFCs). Lithium cobalt oxide coating onto the porous nickel electrode has been adopted to modify the conventional MCFC cathode which is believed to increase the stability of the cathodes in the carbonate melt. The material used for surface modification should possess thermodynamic stability in the molten carbonate and also should be electro catalytically active for MCFC reactions. Two approaches have been adopted to get a stable cathode material. First approach is the use of LiNi{sub 0.8}Co{sub 0.2}O{sub 2}, a commercially available lithium battery cathode material and the second is the use of tape cast electrodes prepared from cobalt coated nickel powders. The morphology and the structure of LiNi{sub 0.8}Co{sub 0.2}O{sub 2} and tape cast Co coated nickel powder electrodes were studied using scanning electron microscopy and ...
2002-04-01
NO formation in the burnout region of a partially premixed methane-air flame with upstream heat loss
Energy Technology Data Exchange (ETDEWEB)
Measurements of temperature and NO concentration in laminar, partially premixed methane-air flames stabilized on a ceramic burner in coflow are reported. The NO concentration and temperature were determined by laser-induced fluorescence (LIF) and coherent anti-Stokes Raman scattering (CARS), respectively. Upstream heat loss to the burner was varied by changing the exit velocity of the fuel-air mixture at a constant equivalence ratio of 1,3; this alters the structure of the flame from an axisymmetric Bunsen-type to a strongly stabilized flat flame. To facilitate analysis of the results, a method is derived for separating the effects of dilution from those of chemical reaction based on the relation between the measured temperature and the local mixture fraction, including the effects of upstream heat loss. Using this method, the amount of NO formed during burnout of the hot, fuel-rich combustion products can be ascertained. ...
1999-09-01
Energy Technology Data Exchange (ETDEWEB)
Alter both oil crisis, of 1973 and 1979, a bad effect of the elevated costs and continuously increment of the oil prices was noted, for this reason, the interest for renewable energies sources widely available in developing countries was increased. All over the world, governments have formulated main objectives for energies savings and search for friendly technologies, taking into account the effects related with the environment. The imminent scarcity of fossil fuels has made humanity the rational use of primary energies, as a result of these; new plants with improved technology have been conceived taking into account energy savings and efficiency improvement. In this context, biomass gasification technologies are important, since they consist in techniques of parallel production of electricity and heat from just one fuel. This work consists in the development of a gasifier down draft of 100 kW for an internal combustion engine, which includes ...
2006-07-01
Layered PrBaCo_2O_5_+_#delta# perovskite as a cathode for proton-conducting solid oxide fuel cells
International Nuclear Information System (INIS)
The layered PrBaCo_2O_5_+_#delta# (PBCO) perovskite oxides were synthesized by modified Pechini method and investigated as a cathode material for solid oxide fuel cells (SOFCs) based on a stable and easily sintered perovskite oxide BaCe_0_._5Zr_0_._3Y_0_._1_6Zn_0_._0_4O_3_-_#delta# (BCZYZ) as electrolyte. The fabricated single cell of NiO-BCZYZ/BCZYZ (#approx#20 #mu#m)/PBCO was operated from 550 to 700 "oC with humidified hydrogen (#approx#5% H_2O) as fuel and the static air as oxidant. The BCZYZ perovskite electrolyte was completely dense after sintered at 1250 "oC for 5 h, lower than that without zinc dopant about 150 "oC. A high open-circuit potential of 1.007 V, a peak power density of 361 mW cm"-"2, and a low polarization resistance of the electrodes of 0.12 #OMEGA# cm"2 was achieved at 700 "oC. The ratio of polarization resistance to total cell resistance decreased with the increase of operating temperature, from ...
2010-04-02
International Nuclear Information System (INIS)
The layered GdBa_0_._5Sr_0_._5Co_2O_5_+_#delta# (GBSC) perovskite oxides are synthesized by modified Pechini method and investigated as a novel cathode material for solid oxide fuel cells (SOFCs) based on a stable perovskite oxide BaCe_0_._5Zr_0_._3Y_0_._1_6Zn_0_._0_4O_3_-_#delta# (BCZYZ) as electrolyte. The fabricated single cells of NiO-BCZYZ/BCZYZ (#approx#20 #mu#m)/GBSC (#approx#20 #mu#m) were operated from 550 to 700 "oC with humidified hydrogen (#approx#5% H_2O) as fuel. The BCZYZ perovskite electrolyte was completely dense after sintered at 1250 "oC for 5 h, lower than that without zinc dopant about 150 "oC. An open circuit voltage of 1.009 V and a maximal power density of 0.35 W cm"-"2 were achieved at 700 "oC. The interfacial polarization resistance was as low as 1.46, 0.45, 0.25 and 0.15 #OMEGA# cm"2 at 550, 600, 650 and 700 "oC, respectively. The ratio of polarization resistance to total cell resistance decreased ...
2010-04-30
Foreign wood fuel supply for power generation in the Netherlands. Final report
Energy Technology Data Exchange (ETDEWEB)
In the Netherlands, the interest in biomass for electricity generation has increased, mainly due to environmental reasons. Currently, the Dutch energy sector is investigating technologies which can reduce CO{sub 2} emissions. The growth of biomass and its subsequent utilization for energy purposes circulates recycled atmospheric carbon and has no net discharge of CO{sub 2}. To reduce emissions from coal-fired power plants biomass co-firing options are investigated. After exhaustion of internal supplies of wood wastes and other residues an extra amount of 1.02 Mt{sub 20} would be needed. Two supply options exist: the use of internal energy crops and the import of biomass. Because production of energy crops in the Netherlands is a rather expensive option, biomass procurement and production outside the Netherlands is studied. Two countries were investigated for the possible import of biomass: Estonia and Uruguay. Estonia has short-term opportunities for residue supply and long-term ...
1995-08-01
International Nuclear Information System (INIS)
Proton-conducting solid oxide fuel cells, incorporating BaZr0.1Ce0.7Y0.2O3-? (BZCY) electrolyte, NiO-BZCY anode, and Sm0.5Sr0.5CoO3-?-Ce0.8Sm0.2O2-? (SSC-SDC) cathode, were successfully fabricated by a combined co-pressing and printing technique after a one-step co-firing process at 1100, 1150, or 1200 oC. Scanning electron microscope (SEM) results revealed that the co-firing temperature significantly affected not only the density of the electrolyte membrane but the grain size and porosity of the electrodes. Influences of the co-firing temperature on the electrochemical performances of the single cells were also studied in detail. Using wet hydrogen (2% H2O) as the fuel and static air as the oxidant, the cell co-fired at 1150 oC showed the highest maximum power density (PDmax) of 552 and 370 mW cm-2 at 700 and 650 oC, respectively, while the one co-fired at 1100 oC showed the highest PDmax of 276 and 170 mWcm-2 at 600 and 550 oC, respectively. ...
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
Detailed chemical kinetic reaction mechanisms have been developed to describe the pyrolysis and oxidation of nine n-alkanes larger than n-heptane, including n-octane (n-C{sub 8}H{sub 18}), n-nonane (n-C{sub 9}H{sub 20}), n-decane (n-C{sub 10}H{sub 22}), n-undecane (n-C{sub 11}H{sub 24}), n-dodecane (n-C{sub 12}H{sub 26}), n-tridecane (n-C{sub 13}H{sub 28}), n-tetradecane (n-C{sub 14}H{sub 30}), n-pentadecane (n-C{sub 15}H{sub 32}), and n-hexadecane (n-C{sub 16}H{sub 34}). These mechanisms include both high temperature and low temperature reaction pathways. The mechanisms are based on our previous mechanisms for the primary reference fuels n-heptane and iso-octane, using the reaction class mechanism construction first developed for n-heptane. Individual reaction class rules are as simple as possible in order to focus on the parallelism between all of the n-alkane fuels included in the mechanisms, and these mechanisms will be ...
2008-02-08
Breaking the Biological barriers to Cellulosic Ethanol: A Joint Research Agenda
Energy Technology Data Exchange (ETDEWEB)
A robust fusion of the agricultural, industrial biotechnology, and energy industries can create a new strategic national capability for energy independence and climate protection. In his State of the Union Address (Bush 2006), President George W. Bush outlined the Advanced Energy Initiative, which seeks to reduce our national dependence on imported oil by accelerating the development of domestic, renewable alternatives to gasoline and diesel fuels. The president has set a national goal of developing cleaner, cheaper, and more reliable alternative energy sources to substantially replace oil imports in the coming years. Fuels derived from cellulosic biomass - the fibrous, woody, and generally inedible portions of plant matter - offer one such alternative to conventional energy sources that can dramatically impact national economic growth, national energy security, and environmental goals. Cellulosic biomass is an attractive energy feedstock ...
2006-06-01
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