WorldWideScience
1

Sustainable development at Canadian Electrolytic Zinc -- recent improvements  

Energy Technology Data Exchange (ETDEWEB)

A series of modifications which increased the capacity of Canadian Electrolytic Zinc's Valleyfield plant from 220,000 MT/year to 260,000 MT/year during the last decade is discussed, combined with an an overview of the plant's operations. The modifications included modernisation of the waste disposal methods and facilities, such as a new high-density sludge wastewater treatment process, a new process to remove selenium from weak acid solutions and the jarofix process. Roasting capacity also has been improved by recent investments in new cooling coils, rebricking, oxygen enrichment and process automation. In addition to increases in refining capacity, the improvements also enabled the company to minimize its impact on the environment and the community.

2001-07-01

2

The Bullhouse Project - Phase 2  

Energy Technology Data Exchange (ETDEWEB)

The operation of the Bullhouse Minewater System, used to treat iron-rich minewaters discharged from long-abandoned coal mines, was studied to minimise pollution of the Upper Don river in the UK. Tests were carried out to determine optimal operating conditions. Ochre flocculation with polyacrylamide was efficient in batch tests as the ochre self-flocculated and sedimented in the lagoon without the need for chemical enhancement. The rate of accretion of the pipework in the system was modified by partial dewatering, reshaping and hardening of the deposits during ageing. Samples of ochre recovered from the drying beds and sump deposits were converted to ferric sulphate coagulant by dissolution with sulphuric acid and used with a polyelectrolyte to successfully purify reservoir water and pretreat wastewater. There was considerable local interest in the scheme with educational opportunities for schools and colleges.

2000-12-01

3

Review of Constructed Subsurface Flow vs. Surface Flow Wetlands  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this document is to use existing documentation to review the effectiveness of subsurface flow and surface flow constructed wetlands in treating wastewater and to demonstrate the viability of treating effluent from Savannah River Site outfalls H-02 and H-04 with a subsurface flow constructed wetland to lower copper, lead and zinc concentrations to within National Pollutant Discharge Elimination System (NPDES) Permit limits. Constructed treatment wetlands are engineered systems that have been designed and constructed to use the natural functions of wetlands for wastewater treatment. Constructed wetlands have significantly lower total lifetime costs and often lower capital costs than conventional treatment systems. The two main types of constructed wetlands are surface flow and subsurface flow. In surface flow constructed wetlands, water flows above ground. Subsurface flow constructed wetlands are designed to ...

2004-09-01

6

Effect of sulfate on anaerobic degradation of benzoate in UASB reactors  

Science.gov (United States)

Anaerobic processes have been widely used for the treatment of various high-strength industrial wastewaters. However, application has been limited for the treatment of sulfate-rich industrial wastewaters, such as those from the petrochemical, and mining industries. Wastewaters containing benzoate and sulfate were treated in two upflow anaerobic sludge blanket (UASB) reactors at 34--37 C for 320 d. The sulfate concentration was increased stepwise in Reactor-A up to 7,500 mg/L, and was kept mostly constant at 3,000 mg/L in Reactor-B. Both reactors removed over 98% of organic chemical-oxygen demand (COD) for sulfate up to 6,000 mg/L, despite the fact that the mixed liquor contained up to 769 mg S/L of total sulfides and up to 234 mg S/L of dissolved H{sub 2}S. Sulfate0reducing efficiency decreased with the increase in sulfate concentration, but increased with time at each sulfate concentration. Reactor-B ...

1997-04-01

7

Zn-Al alloy as a new anode-metal of a zinc-air battery  

Energy Technology Data Exchange (ETDEWEB)

Low operating power and short cycle life are 2 of the main draw-backs of zinc-air batteries, despite the fact that various attempts have been made to develop improved zinc (Zn) anodes. This study investigated the performance of a Zn anode with a substantial addition of aluminium (Al). Rolled sheets of Zn-Al alloys of varying amounts of Zn and Al were used to prepare the anodes. Results of the study showed that the cells had higher open circuit voltages (OCV) values as well as a higher specific anode capacity. It was observed that specific anode capacity increased with higher current loading. The Zn{sub 59}Al{sub 41} and Zn{sub 67}Al{sub 33} sheets showed the highest performance with high OCV values of between 1540 and 1560 mV, as well as the largest specific anode capacity of 750-800 mAh per g at a discharge current of 200 mA. The 2-phase structure of the Zn-Al sheets was considered to be useful in reducing anode-passivation, and increasing ...

2006-01-15

8

Zinc electrode and rechargeable zinc-air battery  

Energy Technology Data Exchange (ETDEWEB)

This patent describes an improved zinc electrode for a rechargeable zinc-air battery comprising an outer frame and a porous foam electrode support within the frame which is treated prior to the deposition of zinc thereon to inhibit the formation of zinc dendrites on the external surface thereof. The outer frame is provided with passageways for circulating an alkaline electrolyte through the treated zinc-coated porous foam. A novel rechargeable zinc-air battery system is also disclosed.

1989-06-27

10

Measuring instrument for radiometric monitoring of solids and heavy metals in water  

International Nuclear Information System (INIS)

A combination of measuring instruments, consisting of a Beta-Sedimeter and a radionuclide X-ray fluorescence instrument, is described. With the Beta-Sedimeter the C-14-radiation is measured. Through direct irradiation with photons of a Pu238-source in an ancillary irradiation chamber and energy dispersing measurement of the K- and L-radiation resp. of the excited heavy metals with the aid of a Si(Li)-semiconductor detector and a 4-channel analyzer the heavy metal concentrations of the heavy metals Zn, Cr, Ni and Pb are determined. For the determination of cadmium the indirect excitation with Am-241 and Dy-targets is described. The system produces records and operates fully automatically in a step-by-step mode with a testing cycle of 45 minutes. In connection with the process monitoring of the wastewater from a zinc plating plant during a period of 8 months the concentration of the solid material and of the metals Cr and Zn, which were ...

1979-01-01

11

Waste and dust utilisation in shaft furnaces  

Energy Technology Data Exchange (ETDEWEB)

Wastes and dusts from steel industry, non-ferrous metallurgy and other branches can be utilised e.g. in agglomeration processes (sintering, pelletising or briquetting) and by injection into shaft furnaces. This paper deals with the second way. Combustion and reduction behaviour of iron- and carbon-rich metallurgical dusts and sludges containing lead, zinc and alkali as well as other wastes with and without pulverised coal (PC) has been studied when injecting into shaft furnaces. Following shaft furnaces have been examined: blast furnace, cupola furnace, OxiCup furnace and imperial-smelting furnace. Investigations have been done at laboratory and industrial scale. Some dusts and wastes under certain conditions can be not only reused but can also improve combustion efficiency at the tuyeres as well as furnace performance and productivity.

2005-07-01

12

Improved zinc electrode and rechargeable zinc-air battery  

Energy Technology Data Exchange (ETDEWEB)

The invention comprises an improved rechargeable zinc-air cell/battery having recirculating alkaline electrolyte and a zinc electrode comprising a porous foam support material which carries the active zinc electrode material. 5 figs.

1988-06-21

13

Radionuclide X-ray fluorescence determination of Mn, Fe, Cu, Zn and Pb in wastewaters and sludges from wastewater treatment plants in Bratislava (SR)  

International Nuclear Information System (INIS)

Radiometric X-ray fluorescence analysis was used for the determination of Mn, Fe, Cu, Zn and Pb in wastewater and sludges from three wastewater treatment plants in Bratislava (SR). Metals were determined in wastewaters after preconcentration by 8-hydroxyquinoline and in sludges by drying and pressing to pellets. "2"3"8Pu and "1"0"9Cd was used for excitation of fluorescence radiation. (author).

1997-01-01

18

Effects of livestock wastewater variety and disinfectants on the performance of constructed wetlands in organic matters and nitrogen removal  

British Library Electronic Table of Contents (United Kingdom)

Background, aim and scope Treatment performance of constructed wetlands (CWs) is largely dependent on the characteristics of the wastewater. Although livestock wastewater is readily biodegradable in general, its variety in biodegradability can still be significant in practice. In addition, it is a common practice to periodically use disinfectants in livestock activities for health concerns. Obviously, the residual of the disinfectants in livestock wastewater may have serious inhibitory effect on the microbial activities during wastewater treatment. Thus, the main objective of this study was to examine the variety of livestock wastewater in biodegradability and its effect on the performance of a pilot scale tidal flow CWs (TFCWs) in organic matter and nitrogen removal. Furthermore, investig...

2011-01-01

19

Research and development o zinc-air battery for electric vehicle in USA and Europe; EV yo aen kuki denchi (kaigai no jokyo)  

Energy Technology Data Exchange (ETDEWEB)

This paper describes zinc-air battery for electric vehicle (EV). This battery is composed of air electrode, zinc electrode, and alkali electrolyte. During the discharge, oxygen taken from the air is reduced at the air electrode, and zinc is dissolved at the zinc electrode. The whole reaction is formation of zinc oxide from oxygen and zinc. This is taken out to use as a secondary battery through exchange and regeneration, which is called mechanical charge. For Electric Fuel, discharged products in the zinc electrode from a spent EV are extracted by a vibrating crusher, and are dissolved in KOH to prepare zinc ion electrolyte. Thus, zinc is obtained through the electrolytic refining. Since the regenerated zinc is separated from the electrolytic electrode as a form of dendritic ...

1998-05-05

20

Galvanic primary cell with an alkaline electrolyte and an air electrode. Galvanisches Primaerelement mit alkalischem Elektrolyten und einer Luftelektrode  

Energy Technology Data Exchange (ETDEWEB)

According to the invention, a zinc foil is arranged between the negative electrode of a zinc/air battery (round cell) and the expansion space compensating for the reactive increase in volume of the zinc powder. This zinc foil functioning as a stop diaphragm particularly ensures, from the very onset, that the zinc filling has a density and compactness necessary for good electronic conductance.

1986-11-06

21

Wastewater Treatment Software Solutions on Environmental Expert  

Wastenet

... TOXCHEM+ - Wastewater Predictive Fate by Hydromantis Environmental Software Solutions, Inc. TOXCHEM+ is regarded as the most reliable and ... TOXCHEM+ is EPA-approved for estimating ... »Read more » Contact now / Request quote 0 Comments ...

22

Recovery of energy from the food industry by anaerobic purification of its wastewaters  

Energy Technology Data Exchange (ETDEWEB)

The energy recovery by anaerobic purification of wastewaters from olive oil manufactured is reported. The process efficiency is 82%, and the gas (CH4-CO2) yield is 850 L/kg eliminated BOD.

1980-01-01

23

Effect of Wastewater Treatment Plant Effluent on Microbial Function and Community Structure in the Sediment of a Freshwater Stream with Variable Seasonal Flow?  

UK PubMed Central (United Kingdom)

We investigated the effects of wastewater treatment plant (WWTP) discharge on the ecology of bacterial communities in the sediment of a small, low-gradient stream in South Australia. The quantification...Full Text Available

2008-05-01

26

A new concept in an electrically rechargeable zinc-air alkaline battery. [Porous electrodes  

Energy Technology Data Exchange (ETDEWEB)

This paper describes a new idea for zinc-air battery design. The novel idea is a porous zinc electrode surrounded with a supersaturated zincate solution. 3 figs. (JDH)

1987-10-01

27

Water | Editorial Board  

Wastenet

...Tota-MaharajE-Mail: Interests: water and wastewater treatment, environmental engineering and sustainable systems; sustainable water management; sustainable urban drainage systems (SUDS); combined renewable energy applications with reverse osmosis desalination; microbial fuel cells for bioenergy production and treatment of urban wastewater; solar photocatalytic treatment and disinfection of water/wastewater Dr. Simon Toze CSIRO Land and Water, Queensland Bioscience Precinct - St Lucia, 306 Carmody Road, St Lucia QLD 4067,...

28

Heavy metals in industrial wastewater determined by radionuclide x-ray fluorescence analysis and their effects on Allium cepa root tip cells  

International Nuclear Information System (INIS)

Radionuclide x-ray fluorescence method was used in the determination of Cr, Ni and other heavy metals content in wastewater of an engineering plant taken both before and after chemical treatment. Toxic effects of the wastewaters using Allium cepa root tip cells were tested. (author) 8 refs.; 2 tabs.

1994-05-01

29

Determination of heavy metals in industrial wastewaters and their influence on activated sludge biocenose  

International Nuclear Information System (INIS)

Radionuclide X-ray fluorescence method with a Si/Li semiconductor detector and "2"3"8Pu exciting source was used in the determination of Cr, Fe, Ni, Cu, and Zn content in industrial wastewaters. Simultaneously, the effects of the wastewaters on activated sludge biocenose were evaluated. (author) 6 refs.; 1 fig.; 1 tab.

1994-03-01

30

Optimized Zn-electrode for the rechargeable zinc-air battery  

Energy Technology Data Exchange (ETDEWEB)

For the development of a long-lived electrically rechargeable zinc/air battery, the structure and wettability of pasted zinc electrodes were optimized. Pasted zinc electrodes, having the same nominal capacities but containing 1% to 10% cellulose, were prepared and tested under defined charge and discharge conditions in zinc-oxygen cells. The maximum power as well as the cycle life of these cells were measured. After different times of operation, the porosity and the pore size distribution of the pasted zinc electrodes were measured by means of mercury porosimetry. (author) 4 figs., 1 tab., 6 refs.

1996-06-01

31

Optimized zinc electrode for the rechargeable zinc-air battery  

Energy Technology Data Exchange (ETDEWEB)

For the development of a long-lived, electrically rechargeable zinc-air battery the structure and wettability of pasted zinc electrodes were optimized. Pasted zinc electrodes containing 1 to 10% cellulose, but having almost the same nominal capacities, were prepared and tested in zinc/oxygen cells. The effect of discharge rate on cell voltage and delivered capacity, as well as the maximum power, were measured. Furthermore, cell charge-discharge behaviour and cycle life were examined. After different times of operation, the porosity and the pore size distribution of the pasted zinc electrodes were measured by means of mercury porosimetry. The life cycle and peak power drain capability of the Zn/oxygen battery could be substantially improved by the addition of 10 wt% cellulose to the pasted zinc electrode. (author)

1998-09-01

32

Aluminum-Zinc (Al-Zn) Dust Analyses for Recycling Purposes  

Science.gov (United States)

... Accession Number : ADA547552. Title : Aluminum-Zinc (Al-Zn) Dust Analyses for Recycling Purposes. Descriptive Note : Technical rept. ...

2011-08-01

33

Simultaneous ozonation kinetics of phenolic acids present in wastewaters  

Energy Technology Data Exchange (ETDEWEB)

Among the several chemical processes conducted for the removal of organic matter present in wastewaters coming from some agro-industrial plants (wine distilleries, olive oil mills, etc), the oxidation by ozone has shown a great effectiveness in the destruction of specially refractory pollutants: it is demonstrated that the biodegradability of those wastewaters increases aflcer an ozonation pretreatment. Their great pollutant character is imputed to the presence of some organic compounds, like phenols and polyphenols, which are toxic and inhibit the latter biological treatments. In this research, a competitive kinetic procedure reported by Clurol and Nekouinaini is applied to determine the degradation rate constants by ozone of several phenolic acids which are present in the wastewaters from the olive oil obtaining process. The resulting kinetic expressions for the ozonation reactions are useful for the successful design and ...

1996-12-31

36

Corrosion resistance of zinc coatings on depleted uranium and uranium alloys  

Energy Technology Data Exchange (ETDEWEB)

Simulated atmospheric corrosion studies were performed to determine the corrosion protection provided by galvanized zinc coatings on depleted uranium, U-0.75 Ti alloy, and U-6 Nb alloys. The accelerated ASTM tests consisted of exposing the galvanized samples to aqueous and aqueous chloride environments. The test results showed that anodic protection was provided by the electronegative zinc coatings on uranium and uranium alloys. Treating zinc with chromate conversion coatings also provided more protection.

1985-01-27

37

Zinc-air battery/fuel cell  

Energy Technology Data Exchange (ETDEWEB)

The zinc-air battery/fuel cell is an old technology invented one hundred years ago. However, there is renewed interest in this technology in response to the growing need for clean energy technology. The zinc-air battery/fuel cell is more attractive than similar technologies because its characteristics include high power density, safe operation and storage, and low cost. Zinc-air battery/fuel cells can be made in milliwatts to mega watts to accommodate different applications. The zinc-air battery/fuel cell has four major designs, namely primary, mechanically rechargeable, continuous feed and electrically rechargeable zinc-air battery/fuel cells. Among the different designs, the most common is the air cathode. There are 3 generations of catalysts used in the air cathodes. This paper discussed the different designs of the zinc-air battery/fuel cell, and more ...

2010-07-01

38

Zinc air battery development for electric vehicles. Final report  

Energy Technology Data Exchange (ETDEWEB)

This report summarizes the results of research conducted during the sixteen month continuation of a program to develop rechargeable zinc-air batteries for electric vehicles. The zinc-air technology under development incorporates a metal foam substrate for the zinc electrode, with flow of electrolyte through the foam during battery operation. In this ``soluble`` zinc electrode the zincate discharge product dissolves completely in the electrolyte stream. Cycle testing at Lawrence Berkeley Laboratory, where the electrode was invented, and at MATSI showed that this approach avoids the zinc electrode shape change phenomenon. Further, electrolyte flow has been shown to be necessary to achieve significant cycle life (> 25 cycles) in this open system. Without it, water loss through the oxygen electrode results in high-resistance failure of the cell. The Phase I program, which focused ...

1991-07-01

39

Zinc air battery development for electric vehicles  

Energy Technology Data Exchange (ETDEWEB)

This report summarizes the results of research conducted during the sixteen month continuation of a program to develop rechargeable zinc-air batteries for electric vehicles. The zinc-air technology under development incorporates a metal foam substrate for the zinc electrode, with flow of electrolyte through the foam during battery operation. In this soluble'' zinc electrode the zincate discharge product dissolves completely in the electrolyte stream. Cycle testing at Lawrence Berkeley Laboratory, where the electrode was invented, and at MATSI showed that this approach avoids the zinc electrode shape change phenomenon. Further, electrolyte flow has been shown to be necessary to achieve significant cycle life (> 25 cycles) in this open system. Without it, water loss through the oxygen electrode results in high-resistance failure of the cell. The Phase I program, ...

1991-07-01

40

Metal Coupled Folding of Cys2His2 Zinc-Finger  

CERN Document Server

Zinc-fingers, which widely exist in eukaryotic cell and play crucial roles in life processes, depend on the binding of zinc ion for their proper folding. To computationally study the zinc coupled folding of the zinc-fingers, charge transfer and metal induced protonation/deprotonation effects have to be considered. Here, by attempting to implicitly account for such effects in classical molecular dynamics and performing intensive simulations with explicit solvent for the peptides with and without zinc binding, we investigate the folding of the Cys2His2 type zinc-finger motif and the coupling between the peptide folding and zinc binding. We find that zinc ion not only stabilizes the native structure, but also participates in the whole folding process. It binds to the peptide at early stage of folding, and directs or ...

2008-01-01

41

Regenerative zinc/air and zinc/ferricyanide batteries for stationary power applications  

Energy Technology Data Exchange (ETDEWEB)

The authors report a novel configuration for a zinc-particle, packed-bed anode in which an open structure of high hydraulic permeability is maintained indefinitely in a cell with closely spaced walls by the formation of particle bridges and associated gaps. The configuration minimizes electrolyte pumping costs, allows rapid refueling and partial recharge, and provides for 100% zinc consumption. This approach benefits zinc/air fuel batteries by allowing nearly continuous operation and fuel recycle without commercial infrastructure; it benefits Zn/[Fe(CN){sub 6}]{sup {minus}3} batteries by eliminating shape-change and polarization problems found with planar anodes.

1994-05-01

42

Depleted zinc: Properties, application, production  

Energy Technology Data Exchange (ETDEWEB)

The addition of ZnO, depleted in the Zn-64 isotope, to the water of boiling water nuclear reactors lessens the accumulation of Co-60 on the reactor interior surfaces, reduces radioactive wastes and increases the reactor service-life because of the inhibitory action of zinc on inter-granular stress corrosion cracking. To the same effect depleted zinc in the form of acetate dihydrate is used in pressurized water reactors. Gas centrifuge isotope separation method is applied for production of depleted zinc on the industrial scale. More than 20 years of depleted zinc application history demonstrates its benefits for reduction of NPP personnel radiation exposure and combating construction materials corrosion.

2009-07-15

43

Neutron activation analysis for determination of selected trace elements responsible for immunity in foodstuffs and water in egypt  

International Nuclear Information System (INIS)

Selenium (Se), zinc (Zn), magnesium (Mg), molybdenum (Mo) and vanadium (V) in 28 types of Egyptian common foodstuffs as well as drinking and irrigation water samples were determined using neutron activation analysis (NAA) and atomic absorption spectrometry (AAS). The samples were collected from 74 sites over 13 governorates as well as the Nile river, wells and tap water in the regions of the Nile Delta, Sinai, the east and west desert, and north and south Egypt. These trace elements were chosen according to international references, which show the close relationship of their deficiencies to immunity-related diseases. Calculation values of daily uptake per capita were made with the results of analysis. The results, as calculated per 100 g dry weight, showed that some Egyptian foods are rich in Se including such fish (0.94 #mu#g), sesame (0.88 #mu#g), beef meat (0.48 #mu#g), instant tea (0.42 #mu#g), mushroom (0.34 #mu#g) and eggs (0.3 #mu#g), ...

44

Application of electro-Fenton oxidation for the detoxification of olive mill wastewater phenolic compounds  

Energy Technology Data Exchange (ETDEWEB)

Olive mill effluent (OMW) is an example of a wastewaters containing high concentrations of recalcitrant and toxic compounds which are polyphenolics of different molecular weight. It causes disposal problems because they contain powerful pollutants. Treatment and detoxification of phenolic fraction extracted from olive mill wastewaters as well as a synthetic phenolic mixture was investigated by electro-Fenton method. Results shows that this method is highly efficient in polymerising low molecular mass phenolics and removing a large amount of recalcitrant polyphenolic compounds. This treatment decreased 78% of the toxicity which sustained a good anaerobic post-treatment. (orig.)

2003-07-01

45

Effect of Non-aqueous Solvents on the Rate of Production of Copper Powder from Copper Sulphate Solution by Cementation on Stationary Zinc Sheet and Rotating Zinc Cylinder  

Scientific Electronic Library Online (English)

Abstract in english The rate of copper II/zinc cementation from copper sulphate solutions in the absence and in the presence of methanol (CH3OH) and dimethyl sulphoxide (DMSO) has been studied and the reaction was found to follow first-order kinetics. The influence of several parameters on the course of the reaction, such as cylinder rotation speed, initial concentration of Cu2+ ions, temperature and concentration of organic solvent, was investigated. In the case of CH3OH, rotating zinc cyli (more) nder was used, while in the presence of DMSO stationary zinc sheet and rotating zinc cylinder were used. It was found that (1) the percentage inhibition caused by methanol ranged from 10.70 to 58.38 depending on the concentration of the alcohol used; (2) the rate of cementation in the presence of DMSO using rotating zinc cylinder > the rate of cementation in the presence of DMSO using ...

2004-01-01

46

Use of sanitary sewers as wastewater pre-treatment systems  

Energy Technology Data Exchange (ETDEWEB)

As wastewater travels through a sewer system it undergoes changes in composition. The changes in composition may be caused by chemical, physical and/or biological processes. At present engineers do not take into consideration the impacts of these processes on the wastewater quality when designing wastewater treatment systems. However, the impact of these processes on the chemical oxygen demand, biochemical oxygen demand, nitrogen and phosphorus content of the wastewater can be significant. In the case of the biological processes, microorganisms present in the water as it travels through the sewer system are similar to those found in an activated sludge process. Given that the microorganism population and the hydraulic retention time often resembles that of an activated sludge process, it would seem only reasonable to look further into the possibility of using sewers as wastewater ...

1998-12-31

47

Molecular Characterization of Cryptosporidium Oocysts in Samples of Raw Surface Water and Wastewater  

UK PubMed Central (United Kingdom)

Recent molecular characterizations of Cryptosporidium parasites make it possible to differentiate the human-pathogenic Cryptosporidium parasites from those that do...Full Text Available

2001-03-01

48

Closed Cycle Bleach Kraft Pulp Production; NICE3 Forest Products Project Fact Sheet  

Energy Technology Data Exchange (ETDEWEB)

Fact sheet written for the NICE3 Program on a new chlorine-free process for pulping and bleaching wastewater.

2000-10-30

49

Ashbrook Simon-Hartley Profile on Environmental Expert  

Wastenet

...been a world leader in the design, manufacture and installation of high quality precision-engineered systems for water and wastewater treatment fo Create Free Account ...

50

Ashbrook Simon-Hartley Profile on Environmental Expert  

Wastenet

...been a world leader in the design, manufacture and installation of high quality precision-engineered systems for water and wastewater treatment fo Bulletins Environmental Expert ...

51

Virostatic potential of micro-nano filopodia-like ZnO structures against herpes simplex virus-1.  

Science.gov (United States)

Herpes simplex virus type-1 (HSV-1) entry into target cell is initiated by the ionic interactions between positively charged viral envelop glycoproteins and a negatively charged cell surface heparan sulfate (HS). This first step involves the induction of HS-rich filopodia-like structures on the cell surface that facilitate viral transport during cell entry. Targeting this initial first step in HSV-1 pathogenesis, we generated different zinc oxide (ZnO) micro-nano structures (MNSs) that were capped with multiple nanoscopic spikes mimicking cell induced filopodia. These MNSs were predicted to target the virus to compete for its binding to cellular HS through their partially negatively charged oxygen vacancies on their nanoscopic spikes, to affect viral entry and subsequent spread. Our results demonstrate that the partially negatively charged ZnO-MNSs efficiently trap the virions via a novel virostatic mechanism rendering them unable to enter into ...

2011-08-26

52

Stepped reforming - a new method for recovering energy and hydrogen from biogenic residues; Die Gestufte Reformierung - ein neues Verfahren zur Gewinnung von Energie und Wasserstoff aus biogenen Reststoffen  

Energy Technology Data Exchange (ETDEWEB)

DMT has developed what is called the stepped reforming process. This is an allothermal gasification process which uses hydrogen for a gasification medium. First the biomass is pyrolised by means of a heat transfer material. The escaping gaseous and condensable constituents are hydrogenated, heated in a reforming stage and are made to react to a hydrogen-rich product gas by means of homogeneous gasification. The heat required for this is provided by burning the pyrolysis coke. This makes it possible to dispense with process stages that would involve gasification of solid material and hence require higher pressure levels. The present process also works at ambient pressure. Moreover, stepped reforming promises a number of additional advantages: low-tar product gas containing 60% hydrogen, high cold gas efficiency, no wastewater arisings, robust operating behaviour. This paper outlines the basic ideas that led to the development of stepped ...

2000-07-01

53

Regeneration of zinc anodes for the Electric Fuel{reg_sign} zinc-air refuelable EV battery system  

Energy Technology Data Exchange (ETDEWEB)

The Electric Fuel Limited (EFL) refuelable zinc-air battery system is currently being tested in a number of electric vehicle demonstration projects, the largest of which is a field test of zinc-air postal vans sponsored chiefly by Deutsche Post AG (the German Post Office). The zinc-air battery is not recharged electrically, but rather is refueled through a series of mechanical and electrochemical steps that will require a special infrastructure in commercial application. As part of the German Post Office field test program, Electric Fuel designed and constructed a pilot zinc anode regeneration plant in Bremen, Germany. This plant is capable of servicing up to 100 commercial vans per week, which is adequate for the field test vehicle fleet. This paper will describe the design and operation of each of the areas and devices within the plant.

1997-12-31

54

Development of rechargeable monopolar and bipolar zinc/air batteries  

Energy Technology Data Exchange (ETDEWEB)

For the development of a rechargeable zinc/air battery, La[sub 0.6]Ca[sub 0.4]CoO[sub 3]-catalyzed (perovskite) bifunctional oxygen electrodes and pasted zinc electrodes were prepared and tested in monopolar zinc/air cells. In addition, a bipolar Zn/air stack was tested using reticulated copper foam as substrate for the zinc deposit. The cells were cycled in moderately alkaline ZnO-saturated electrolyte with KF as an electrolyte additive. The maximum power as well as the cycle life of the cells was investigated. The differences in porosity of the zinc electrode before and after the long-term test were analyzed using mercury porosimetry. (author) 8 figs., 13 refs.

1995-01-01

55

Rich Baldwin - NASA  

Science.gov (United States)

Rich Baldwin. Phone : 301-286-3031. Email : Building/Office : 22/163. Mailing Address : NASA/GSFC, Code 921, Greenbelt, MD 20771 ...

56

BALDWIN001  

Science.gov (United States)

Mar 13, 1997 ... Rich Baldwin's data and program files from the workstation Geomag extracted 5/96 FILE DESCRIPTION /BINNER/ /u/baldwin/rich/fortran/binner/ ...

57

Transcriptional repression and developmental functions of the atypical vertebrate GATA protein TRPS1  

UK PubMed Central (United Kingdom)

Known vertebrate GATA proteins contain two zinc fingers and are required in development, whereas invertebrates express a class of essential proteins containing one GATA-type zinc finger. We isolated...Full Text Available

2001-04-02

58

The electric fuel zinc-air battery option  

Energy Technology Data Exchange (ETDEWEB)

With specific energy of more than 200 Wh/kg, the Electric Fuel zinc-air battery delivers as much as eight times the energy of lead-acid traction battery, more than twice the energy of the nearest advanced-battery competitor, and as much energy as a tank of gasoline. (author)

1995-12-31

59

The effects of zinc deficiency on pancreatic carboxypeptidase activity and protein digestion and absorption in the rat  

UK PubMed Central (United Kingdom)

1. Proteolytic enzyme activities were examined in the pancreas of zinc-deficient and control rats. 2. No change was detected in trypsin-plus-chymotrypsin activity. 3. Carboxypeptidase activity was...Full Text Available

1967-03-01

60

Novel structural features in two ZHX homeodomains derived from a systematic study of single and multiple domains  

UK PubMed Central (United Kingdom)

BackgroundZhx1 to 3 (zinc-fingers and homeoboxes) form a set of paralogous genes encoding multi-domain proteins. ZHX proteins consist of two zinc fingers followed...Full Text Available

61

Genome-Wide Transcriptional Response of Chemostat-Cultured Escherichia coli to Zinc  

UK PubMed Central (United Kingdom)

Zinc is an essential trace metal ion for growth, but an excess of Zn is toxic and microorganisms express diverse resistance mechanisms. To understand global bacterial responses to excess Zn, we conducted...Full Text Available

2005-02-01

62

Epigallocatechin-3-gallate affects the growth of LNCaP cells via membrane fluidity and distribution of cellular zinc*  

UK PubMed Central (United Kingdom)

Objective: To evaluate effects of epigallocatechin-3-gallate (EGCG) on the viability, membrane properties, and zinc distribution, with and without the presence of Zn2+, in human prostate...Full Text Available

2009-06-01

63

Effectiveness of zinc protoporphyrin/heme ratio for screening iron deficiency in preschool-aged children  

UK PubMed Central (United Kingdom)

Hemoglobin and zinc protoporphyrin (ZPP) tests are commonly used to screen for iron deficiency, but little research has been done to systematically evaluate the sensitivity and specificity of these...Full Text Available

2011-02-01

64

Cerebrospinal fluid zinc concentrations in febrile convulsions.  

UK PubMed Central (United Kingdom)

Zinc modulates the activity of glutamic acid decarboxylase, the rate limiting enzyme in the synthesis of gamma-aminobutyric acid (GABA), which is a major inhibitory neurotransmitter. Low cerebrospinal...Full Text Available

1995-10-01

65

Analysis of illegitimate genomic integration mediated by zinc-finger nucleases: implications for specificity of targeted gene correction  

UK PubMed Central (United Kingdom)

BackgroundFormation of site specific genomic double strand breaks (DSBs), induced by the expression of a pair of engineered zinc-finger nucleases (ZFNs), dramatically increases the...Full Text Available

66

Radionuclide X-ray fluorescence determination of Cr, Fe, Cu, Zn,and Pb in industrial wastewaters after preconcentration of determined elements  

International Nuclear Information System (INIS)

Radionuclide X-ray fluorescence analysis was used for the determination of Cr, Fe, Cu, Zn and Ph in industrial wastewaters (from surface treatment of metals and glasses) after precipitation of determined elements by 8-hydroxyquinoline. (author).

1997-01-01

67

Pilot scale hybrid processes for olive mill wastewater treatment, energy production and water reuse: comparison between fungal and electro-coagulation pre-treatments  

Energy Technology Data Exchange (ETDEWEB)

Olive oil mill wastewaters (OMW) cause disposal problems because they contain powerful pollutants such as phenolic compounds. Complete biodegradation or removal of these compounds is hardly achieved by a single treatment method. In this work, we investigated 2 integrated technologies for the treatment of the recalcitrant contaminants of OMW, allowing water recovery and reuse for agricultural purposes. (Author)

2009-07-01

68

NAME=\\  

Wastenet

... Biodegradable plastics have the potential to be used in various flushable sanitary product applications such as sanitary towels, colostomy bags and other absorbent products. In addition, effluent from recycling activities must be treated in wastewater treatment plants and may contain biodegradable plastics. Flushable biodegradable plastics can have an adverse impact on wastewater treatment plants due to the very fast throughputs, typically 4 to 8 hours, from the drain to the plant. This length of time is insufficient for many biodegradable plastics to lose their structure. Such plastics can ...

69

Development document for proposed effluent limitations guidelines and standards for the transportation equipment cleaning category  

Energy Technology Data Exchange (ETDEWEB)

Contents of this report are under the following topical sections: Legal Authority; Summary and Scope; Data Collection Activities; Industry Description; Industry Subcategorization; Water Use and Wastewater Characterization; Pollutants Selected for Regulation; Pollution Prevention and Wastewater Treatment Technologies; Development of Control and Treatment Options; Costs of Technology Bases for Regulations; Pollutant Reduction Estimates; Non-Water Quality Impacts; Implementation of Proposed Effluent Limitation Guidelines and Standards; Analytical Methods; and Glossary.

1998-05-01

70

Testing of a refuelable zinc/air bus battery  

Energy Technology Data Exchange (ETDEWEB)

We report tests of a refuelable zinc/air battery of modular, bipolar-cell design, intended for fleet electric busses and vans. The stack consists of twelve 250-cm{sup 2} cells built of two units: (1) a copper-clad glass-reinforced epoxy board supporting anode and cathode current collectors, and (2) polymer frame providing for air- and electrolyte distribution and zinc fuel storage. The stack was refueled in 4 min. by a hydraulic transfer of zinc particles entrained in solution flow.

1995-02-22

73

Diffusion Zink Planting of Steels  

International Science & Technology Center (ISTC)

Research on Diffusion Zinc Cladding of Structural Steels, as Well as Their Mechanical and Corrosion Properties to Replace Their Cyanic Cadmium Plating

74

Development and cycle test of zinc-oxygen cells  

Energy Technology Data Exchange (ETDEWEB)

For the development of a rechargeable zinc/air battery, La{sub 0.6}Ca{sub 0.4}CoO{sub 3}-catalyzed (perovskite) bifunctional oxygen electrodes and pasted zinc electrodes were prepared and tested in monopolar zinc/air cells. The cells were cycled in moderately alkaline electrolyte. The maximum power as well as the cycle life of the cells were investigated. Up to 450 cycles could be reached, and attractive specific energies and powers were obtained. (author) 3 figs., 4 refs.

1995-07-01

76

The recovery of zinc and cadmium following 6.1 MeV alpha particle irradiation at 4.2 K  

International Nuclear Information System (INIS)

The paper reports the recovery of zinc and cadmium following 6.1 MeV alpha particle irradiation at 4.2 K as studied by means of electrical reistivity measurements. Specimens of 10 #mu#m thick have been used in order to obtain a homogeneous defect distribution over the whole thickness of the specimen. The pre-irradiation resistivity ratios were 700 and 750 for cadmium and zinc, respectively. (Auth.).

77

Surprising collectivity in neutron-rich iron isotopes  

International Nuclear Information System (INIS)

... VDPEAZ (Bonn 2010 issue) NUCLEAR PHYSICS AND RADIATION PHYSICS

2010-03-15

80

Nucleosynthesis in early supernova winds III: No significant contribution from neutron-rich pockets  

CERN Document Server

Recent nucleosynthesis calculations of Type II supernovae using advanced neutrino transport determine that the early neutrino winds are proton-rich. However, a fraction of the ejecta emitted at the same time is composed of neutron-rich pockets. In this paper we calculate the nucleosynthesis contribution from the neutron-rich pockets in the hot convective bubbles of a core-collapse supernova and show that they do not contribute significantly to the total nucleosynthesis.

2007-01-01

83

Environmental Pollution Levels of Lead and Zinc in Ishiagu and Uburu Communities of Ebonyi State, Nigeria  

British Library Electronic Table of Contents (United Kingdom)

Water and soil samples from the area were therefore analyzed for their lead and zinc content. Computation of pollution statuses of lead and zinc revealed topsoil lead geoaccumulation indices of ?0.143 and ?0.069 and zinc geoaccumulation indices of 1.168 and 0.713 for Ishiagu and Uburu respectively. The pollution indices were determined to be 0.499 and 0.3564 for soil in Ishiagu and Uburu respectively and also 5.11 and 2.42 for water in Ishiagu and Uburu communities respectively. Water/soil concentration ratio were found to be 0.0018 and 0.0014 for lead in Ishiagu and Uburu respectively. On the other hand, the water/soil concentration ratio for zinc was computed to be 0.001 and 0.0008 for Ishiagu and Uburu respectively. These results seem to suggest that the pollution of the environment by ...

2010-01-01

84

Bond strength of electrochemically-aged arc-sprayed zinc coatings on concrete  

Energy Technology Data Exchange (ETDEWEB)

Research was conducted to determine the effect of electrochemical aging on large area arc-sprayed zinc anodes for cathodic protection of bridges and other reinforced concrete structures. The study focused on the influence of total charge passed and concrete surface preparation on the bonding of the zinc to the concrete. Half of the samples were preheated prior to being arc-sprayed with zinc. The preheated samples had initial bond strengths that were 80% higher than the unheated samples. This difference in bond strength became insignificant after the passage of approximately 200 kC/m{sup 2} (5.2 A-h/ft{sup 2}) and bond strengths for all samples started to decrease after approximately 600 kC/m{sup 2} (15.5 A-h/ft{sup 2}). These changes in bond strength were correlated with observed changes in the permeability of the zinc coating to water, the electrical behavior of the zinc-concrete ...

1996-11-01

85

Biogeochemistry of the compost bioreactor components of a composite acid mine drainage passive remediation system  

International Nuclear Information System (INIS)

The compost bioreactor ('anaerobic cell') components of three composite passive remediation systems constructed to treat acid mine drainage (AMD) at the former Wheal Jane tin mine, Cornwall, UK were studied over a period of 16 months. While there was some amelioration of the preprocessed AMD in each of the three compost bioreactors, as evidenced by pH increase and decrease in metal concentrations, only one of the cells showed effective removal of the two dominant heavy metals (iron and zinc) present. With two of the compost bioreactors, concentrations of soluble (ferrous) iron draining the cells were significantly greater than those entering the reactors, indicating that there was net mobilisation (by reductive dissolution) of colloidal and/or solid-phase ferric iron compounds within the cells. Soluble sulfide was also detected in waters draining all three compost bioreactors which was rapidly oxidised, in contrast to ferrous iron. Oxidation and hydrolysis of iron, ...

2005-02-01

86

Understanding consumption-related sucralose emissions - A conceptual approach combining substance-flow analysis with sampling analysis  

British Library Electronic Table of Contents (United Kingdom)

This paper explores the potential of combining substance-flow modelling with water and wastewater sampling to trace consumption-related substances emitted through the urban wastewater. The method is exemplified on sucralose. Sucralose is a chemical sweetener that is 600 times sweeter than sucrose and has been on the European market since 2004. As a food additive, sucralose has recently increased in usage in a number of foods, such as soft drinks, dairy products, candy and several dietary products. In a field campaign, sucralose concentrations were measured in the inflow and outflow of the local wastewater treatment plant in Linkoping, Sweden, as well as upstream and downstream of the receiving stream and in Lake Roxen. This allows the loads emitted from the city to be estimated. A method c...

2010-01-01

87

TOXCHEM: Predicting the fate of toxics in wastewater treatment plants  

Energy Technology Data Exchange (ETDEWEB)

TOXCHEM is a microcomputer based modelling system for predicting the fate of toxic contaminants in wastewater treatment plants. The package evaluates concentrations of toxics in final effluent and waste sludge, and mass air emissions from municipal or industrial activated sludge wastewater treatment plants. Maximum allowable influent concentrations of toxics required to meet effluent discharge or air emission limits can also be estimated. The package contains a read-only database with treatability parameters for over 100 contaminants, including organic compounds and metals. If effluent or sludge quality limits have been specified, treatment plant owners and operators can use the package to estimate the permissable discharge limits for dischargers to their collection system. A hypothetical example is provided of application of the software to a planning problem involving the start up of a new operation that would discharge 1,4 dichlorobenzene, ...

1991-12-01

88

Remazol Black B removal from aqueous solutions and wastewater using weakly basic anion exchange resins  

British Library Electronic Table of Contents (United Kingdom)

In this study, the use of the weakly basic anion exchange resins of phenol-formaldehyde (Amberlyst A 23), polyacrylate (Amberlite IRA 67) and polystyrene (Lewatit MonoPlus MP 62) matrices for removal of the reactive dye Remazol Black B (RBB) from aqueous solution and wastewater were investigated. RBB sorption on the anion exchangers was a time dependent process. Color reduction percentiles of 75.2, 33.9 and 25.1% in wastewater treatment were found after 216 h of phase contact time with Lewatit MonoPlus MP 62, Amberlyst A 23 and Amberlite IRA 67, respectively. Inorganic salts and anionic surfactant action influenced RBB uptake by the anion exchangers. The amounts of dye retained by the anion exchangers increased with a rise in temperature. The maximum sorption capacities calculated from the...

2011-01-01

89

Fate of volatile organic compounds in wastewater collection systems, volumes IV-VIII  

Energy Technology Data Exchange (ETDEWEB)

This publication compiles five documents on volatile organic compounds (VOCs) in wastewater collection systems. The first is a thesis describing experiments conducted to obtain parameters for determining the significance of biodegradation relative to volatilization as a VOC fate mechanism in sewers. The second is a compilation of three papers from the 1992-94 conferences of the Air & Waste Management Association (AWMA). The papers concern VOC emissions at sewer drop structures and an estimation method for determining VOC emissions from industrial sewers. The third is a compilation of two papers from the AWMA 1992 and 1994 conferences, covering the formation of chloroform from household sources. The fourth is a thesis on post-discharge formation of chloroform in untreated municipal wastewater. The final document is a report detailing the derivation of fate mechanism models in the TOXCHEM model.

1994-12-31

90

Characterization and uncertainty analysis of VOCs emissions from industrial wastewater treatment plants  

British Library Electronic Table of Contents (United Kingdom)

Air toxics from the industrial wastewater treatment plants (IWTPs) impose serious health concerns on its surrounding residential neighborhoods. To address such health concerns, one of the key challenges is to quantify the air emissions from the IWTPs. The objective here is to characterize the air emissions from the IWTPs and quantify its associated uncertainty. An IWTP receiving the wastewaters from an airplane maintenance facility is used for illustration with focus on the quantification of air emissions for benzyl alcohol, phenol, methylene chloride, 2-butanone, and acetone. Two general fate models, i.e., WATER9 and TOXCHEM+V3.0 were used to model the IWTP and quantify the air emissions. Monte Carlo and Bootstrap simulation were used for uncertainty analysis. On average, air emissions fr...

2010-01-01

91

High-Rate Anaerobic Treatment of Wastewater at Low Temperatures  

UK PubMed Central (United Kingdom)

Anaerobic treatment of a volatile fatty acid (VFA) mixture was investigated under psychrophilic (3 to 8°C) conditions in two laboratory-scale expanded granular sludge bed reactor stages in series....Full Text Available

1999-04-01

92

HIGH-RATE DISINFECTION OF COMBINED SEWER OVERFLOW  

Science.gov (United States)

Wet-weather flow (WWF), including combined-sewer overflow (CSO, sanitary-sewer overflow, and stormwater (SW), is a significant contributor of microbial contamination to surface water and ground water. By using effective wastewater or SW disinfection, introduction of pathogen con...

93

Electrochemical treatment of olive oil mill wastewater  

Energy Technology Data Exchange (ETDEWEB)

The possibility of oxidizing at a PbO{sub 2} anode the phenols and polyphenols, present in the olive oil mill wastewater, has been studied as a pre-treatment for the submission of such wastewater to the traditional biological treatments. The results obtained operating at current densities ranging 500 to 2000 A/m{sup 2} show that it is possible to reduce the concentration of the phenolic components, which interfere with the biological treatments, down to low values without decreasing too much the total organic content of the wastewater. [Italian] E' stata studiata la possibilita' di ossidare anodicamente i componenti fenolici delle acque reflue di frantoio, quale pretrattamento delle stesse prima del loro invio ai processi di trattamento biologico. I risultati ottenuti impiegando PbO{sub 2} quale materiale anodico e operando con densita' di corrente comprese tra 500 e 2000 A/m{sup 2} mostrano come ...

2001-04-01

94

Ammonium and Nitrate Uptake by the Floating Plant Landoltia punctata  

UK PubMed Central (United Kingdom)

Background and AimsPlants from the family Lemnaceae are widely used in ecological engineering projects to purify wastewater and eutrophic water bodies. However, the biology of nutrient...Full Text Available

2007-02-01

95

13C-NMR Assessment of the Pattern of Organic Matter Transformation during Domestic Wastewater Treatment by Autothermal Aerobic Digestion (ATAD)  

UK PubMed Central (United Kingdom)

The pattern of biodegradation and the chemical changes occurring in the macromolecular fraction of domestic sludge during autothermal thermophilic aerobic digestion (ATAD) was monitored and characterised...Full Text Available

2009-08-01

96

Wastewater treatment of industrial effluent using activated dolomite adsorption  

Environmental Research Database

SummaryInitial results from the use of activated dolomite from QUESTOR project L1 have proved extremely encouraging in terms of metallic ion (also phosphate, nitrate and dye) removal from wastewater, with capacities in some instances in excess of commercially available activated carbons.This new project involves investigating actual plant effluent in laboratory scale columns and the design of a pilot scale rig for on site trials. The project also involves investigating disposal options and an economic [continued...

2007-01-01

97

The use of treated wastewater for chemlali olive tree irrigation: effects on soil properties, growth and oil quality  

Energy Technology Data Exchange (ETDEWEB)

Olive tree (Olea european L.) cultivation, the major tree crops in Mediterranean countries is being extended to irrigated lands. However, the limited water availability, the severe climatic conditions and the increased need for good water quality for urban and industrial sector uses are leading to the urgent use of less water qualities (brackish water and recycled wastewater) for olive tree irrigation. The aim of this work was to asses the effects of long term irrigation with treated waste water (TWW) on the soil chemical properties, on olive tree growth and on oil quality characteristics. (Author)

2009-07-01

98

Magnetic separation of antibiotics by electrochemical magnetic seeding  

Energy Technology Data Exchange (ETDEWEB)

Magnetic separation of several classes of antibiotics was investigated using electrochemical magnetic seeding. Electrocoagulation with a sacrificial anode followed by addition of magnetite particles was applied for the magnetic seeding of antibiotics. With electrochemical magnetic seeding using an iron anode, tetracycline antibiotics (oxytetracycline, chlortetracycline, doxycycline and tetracycline) and cephalosporin antibiotic (cefdinir) were rapidly removed from synthetic wastewater by magnetic separation using a neodymium magnet. Iron and aluminium anodes were suitable for magnetic seeding of the antibiotics. The results indicated that the ability of antibiotics to form strong complex with iron and aluminium allowed the higher removal by magnetic separation. This method would be appropriate for rapid treatment of antibiotics in wastewater.

2009-03-01

99

Flue gas desulfurization wastewater treatment primer  

Science.gov (United States)

Purge water from a typical wet flue gas desulfurization system contains myriad chemical constituents and heavy metals whose mixture is determined by the fuel source and combustion products as well as the stack gas treatment process. A well-designed water treatment system can tolerate upstream fuel and sorbent arranged in just the right order to produce wastewater acceptable for discharge. This article presents state-of-the-art technologies for treating the waste water that is generated by wet FGD systems. 11 figs., 3 tabs.

2009-03-15

100

Evaluation of wastewater treatment requirements for thermochemical biomass liquefaction  

Science.gov (United States)

Biomass can provide a substantial energy source. Liquids are preferred for use as transportation fuels because of their high energy density and handling ease and safety. Liquid fuel production from biomass can be accomplished by any of several different processes including hydrolysis and fermentation of the carbohydrates to alcohol fuels, thermal gasification and synthesis of alcohol or hydrocarbon fuels, direct extraction of biologically produced hydrocarbons such as seed oils or algae lipids, or direct thermochemical conversion of the biomass to liquids and catalytic upgrading to hydrocarbon fuels. This report discusses direct thermochemical conversion to achieve biomass liquefaction and the requirements for wastewater treatment inherent in such processing. 21 refs.

1992-04-01

101

A mathematical model for simulating shallow solar ponds for treatment of industrial wastewater  

Energy Technology Data Exchange (ETDEWEB)

This paper presents a mathematical model to analyze the solar evaporation in a shallow pond in steady state, when the inlet flow rate, concentration, surface area and solar radiation are given. The simultaneous heat and mass transfer mechanisms are considered for quantifying the amount of evaporated water to the atmosphere and the actual absorbed heat by wastewater is calculated to obtain the bottom temperature of water pond. The heat losses to air by radiation and convection mechanisms are considered and the heat transmission across the water film is evaluated by the forced convection mechanism. 6 refs., 5 figs., 1 tab.

1996-12-31

102

Zinc air battery development for electric vehicles  

Energy Technology Data Exchange (ETDEWEB)

This document reports the progress and accomplishments of a 16 month program to develop a rechargeable zinc-air battery for electric vehicle propulsion, from October 1988 through January 1990. The program was the first stage in the transition of alkaline zinc electrode technology, invented at Lawrence Berkeley Laboratory, to private industry. The LBL invention teaches the use of a copper metal foam substrate for the zinc electrode, in combination with forced convection of electrolyte through the foam during battery operation. Research at LBL showed promise that this approach would avoid shape change (densification and dendrite growth), the primary failure mode of this electrode. The program comprised five tasks; (1) cell design, (2) capacity maximization, (3) cycle testing, (4) materials qualification, and (5) a cost/design study. The cell design contemplates a plate and frame stack, with alternating ...

1990-05-01

103

Report on commissioned business for fiscal 1997. Development of new power storage system for cells and development of technology for distributed power storage (research for a zinc/air cell system for automobiles); 1997 nendo itaku gyomu hokokusho. Shingata denchi denryoku chozo system kaihatsu bunsangata denryoku chozo gijutsu kaihatsu (denki jidoshayo aen kuki denchi system chosa)  

Energy Technology Data Exchange (ETDEWEB)

Concerning the above, it is discussed whether such a system is feasible in Japan. A zinc/air cell system requires some special plants for zinc regeneration, etc. It is necessary to build a zinc refining plant and to install dozens of electrode replacing facilities in an area dozens of kilometers in diameter with the plant at the center. For such a system to be functional, there have to be several tens of thousands of automobile users in a limited area. In Japan, so large a number will not be found anywhere even if the appeal is directed to those in the postal service and electric utilities. There will be no economic success in Japan, different from in Germany. As for the economic comparison between a zinc/air cell system and natural gas system, the two will be equivalent to each other as far as the use of the quick filling stations for the natural gas automobiles remains as it is. When the number in ...

1998-03-01

104

beta- and gamma-decay studies of neutron-rich chromium, manganese, cobalt and nickel isotopes including the new isotopes $^{60}$Cr and $^{60g}$Mn  

CERN Document Server

beta- and gamma-decay studies of neutron-rich chromium, manganese, cobalt and nickel isotopes including the new isotopes $^{60}$Cr and $^{60g}$Mn

1987-01-01

105

Zinc determination in medicinal powders by radionuclide X-ray fluorescence analysis  

International Nuclear Information System (INIS)

X-ray fluorescence analysis was used to determine the zinc content of the ''Perilacin'' powder and the ZnO content of the ''Epiderman-pix'' powder. The characteristic Ksub(#alpha#) line of zinc was excited using a "1"4"7Pm/Mo source (10"7 s"-"1) and the molybdenum Ksub(#alpha#) line (17.47 keV). 4 to 5% Zn and 45 to 49% ZnO were determined with a NaI(Tl) scintillation detector. The radiation intensity was found to decrease with particle size. (M.K.).

1977-01-01

106

Moessbauer spectroscopy study of iron corrosion underneath painting system  

International Nuclear Information System (INIS)

The effect of pigments on the development of corrosion products between the painting system and metal surface when exposed to marine environments has been discussed. The pigments studied were: red mud zinc chromate, zinc chromate, red oxide zinc phosphate, manganese phosphate barium chromate and basic lead silico chromate. Moessbauer spectroscopy revealed that the upper rust layer in all the cases consisted of #gamma#-Fe_2O_3, #gamma#-FeOOH and #alpha#-FeOOH. The lower rust layer immediately in contact with the metal surface consisted of an asymmetrical doublet due to #gamma#-FeOOH. (Auth.).

107

Modeling of an electrically rechargeable alkaline zinc-air battery  

Energy Technology Data Exchange (ETDEWEB)

A numerical model has been developed to simulate the charging and discharge behaviour of an electrically rechargeable alkaline zinc-air battery. Further a galvanostatic experiment including three charge/discharge cycles has been performed. The cell voltages, the Zn electrode potentials versus a Zn reference, and the O{sub 2} electrode potentials versus a Zn reference calculated with the model are in fairly good agreement with the corresponding experimental data. The model is expected to be useful for zinc-air battery design and for analysis of experimental data. (author)

2003-03-01

108

Galvanic element with suspended electrode. Galvanisches Element mit suspendierter Elektrode  

Energy Technology Data Exchange (ETDEWEB)

A zinc/air battery is claimed whose performance is improved by omitting separating elements such as diaphragms etc. The cathode and anode spaces are separated by a collector with holes big enough to permit the electrons to pass freely while restraining the anode material. Further, the active material consists of a spherical care of inert material with a zinc coating. Under the zinc coating, the spherical particles have another thin coating of an electropositive material, e.g. nickel. The cell also contains means for circulating the anode suspension.

1984-08-09

109

The structure of the transitional N=59 nucleus "1"0"1Mo  

International Nuclear Information System (INIS)

... fermions interacting boson model molybdenum 101 neutron-rich isotopes

1987-03-23

110

The Way Ahead: CENTCOM's New Strategy for Theater ...  

Science.gov (United States)

... The CENTCOM AOR encompasses the world's most energy-rich region, with the Arabian Gulf region and Central Asia together ...

2010-05-03

112

Zinc/air battery R and D zinc/air engineering analysis for electrical vehicles: Tasks III, Final report  

Energy Technology Data Exchange (ETDEWEB)

This report is an examination and analysis of the zinc-air system as the motive power source for electric vehicle propulsion. Various versions of the zinc-air system and operating schemes along with their advantages and disadvantages are discussed. Baseline cost calculations are also presented in order to compare the cost effectiveness of each of the systems. The treatise is conceptual in nature and is not based on new experimental work. The information is based on published literature and investigations carried out at ERC in the past. The study also includes recommendations and suggestions in areas that require further research and development work to achieve a smooth transition from the conceptual stage to a practical, viable, and cost effective system.

1986-12-01

113

New developments in the Electric Fuel Ltd. zinc/air system  

Energy Technology Data Exchange (ETDEWEB)

Electric Fuel Ltd. is engaged in the design, development and commercialization of its proprietary zinc/air battery technology for electric vehicles, consumer electronic products and defence applications. To meet the challenging requirements for propelling an all-electric bus, the Vehicle Division sought a unique solution: an all electric battery-battery hybrid propulsion system. The high energy zinc/air battery is coupled with a high-power auxiliary battery. The combined system offers zero emission, high power and long range in an economically viable package. The consumer battery group has developed a high power primary zinc/air cell aimed at cellular phone users, offering extended use, convenience and low cost. (orig.)

1999-07-01

114

Effect of zinc and its form of supply on production and quality of coffee beans  

British Library Electronic Table of Contents (United Kingdom)

Abstract BACKGROUND: In Brazil, the usual forms of zinc (Zn) supply to coffee plants have limitations that compromise the element availability to the plant. This study proposes to test an alternative approach to supplying the nutrient to Coffea arabica L. using trunk implanted zinc tablets. Additionally, the effect of Zn on the production and quality of coffee beans was also evaluated. RESULTS: The highest total coffee bean production was recorded in plants implanted with Zn tablets (TA), while the lowest was recorded in the control treatment, without zinc supply (WZn), reaching a bianual production of 188.2 and 130.1 60-kg bags of processed beans per hectare, respectively. In the treatments where Zn were applied as tablet implantation or as foliage spraying (SZn); the bean size was larger...

2011-01-01

115

Design and fabrication of a micro zinc/air battery  

Energy Technology Data Exchange (ETDEWEB)

Micro-batteries are one of the key components that restrict the application of autonomous Microsystems. However little efforts were made to solve the problem. We have proposed a new planar zinc/air micro-battery, suitable for autonomous microsystem applications. The micro-battery has a layered structure of zinc electrode/alkaline electrolyte/air cathode. A 3D zinc electrode with a high density of posts was designed to obtain a high porosity, hence to offer a best performance. A model of the micro-battery is developed and the device performances were simulated and discussed. A four-mask process was developed to fabricate the prototype micro-batteries. The preliminary testing results showed the micro-batteries is able to deliver a maximum power up to 5 mW, and with an average power of 100 {mu}W at a steady period for up to 2hrs. Fabrication process is still under optimization for further improvement.

2006-04-01

116

Comparative effects of ten dithiocarbamate and thiuram compounds on tissue distribution and excretion of lead in rats  

International Nuclear Information System (INIS)

The dithiocarbamate and thiuram compounds, including disulfiram, were compared for their efficacies in influencing tissue distribution of a trace dose of intravenously injected lead plus "2"0"3Pb in rats. The tested compounds were sodium diethyldithiocarbamate (DEDTC), sodium dimethyldithiocarbamate (DMDTC), tetraethylthiuram disulfide (disulfiram), a complex of zinc and manganese ethylenebisdithiocarbamate (mancozeb), manganese ethylenebisdithiocarbamate (maneb), sodium monomethyldithiocarbamate (metham), zinc propylene bisdithiocarbamate (propineb), tetramethylthiuram disulfide (thiram), zinc ethylenebisdithiocarbamate (zineb), and zinc dimethyldithiocarbamate (ziram). The results of this study show that interactions can occur between lead and DEDTC, DMDTC, disulfiram, metham, thiram, and ziram, resulting in increased levels of lead in brain and probably potentiation of the neurotoxic effects of lead.

117

Acceptability of zinc-fortified, lipid-based nutrient supplements (LNS) prepared for young children in Burkina Faso  

British Library Electronic Table of Contents (United Kingdom)

Abstract Micronutrient deficiencies are a public health concern among young children in low-income countries, and novel strategies are needed to improve the nutritional status of children at risk. One promising approach is the use of lipid-based nutrient supplements (LNS), which can be added to complementary food at the time of consumption. The optimal amount of zinc to include in LNS is uncertain, and concerns have been expressed about possible adverse effects of zinc on sensory characteristics of LNS. We conducted a series of acceptability studies of LNS containing either 0 or 10-mg of zinc per daily 20-g LNS dose among Burkinabe children 9-15 months old and their mothers. These acceptability studies included observations of children's consumption, maternal and child sensory reaction to ...

2011-01-01

118

The Refuelable Zinc-air Battery: Alternative Techniques for Zinc and Electrolyte Regeneration  

Energy Technology Data Exchange (ETDEWEB)

An investigation was conducted into alternative techniques for zinc and electrolyte regeneration and reuse in the refuelable zinc/air battery that was developed by LLNL and previously tested on a moving electric bus using cut wire. Mossy zinc was electrodeposited onto a bipolar array of inclined Ni plates with an energy consumption of 1.8 kWh/kg. Using a H{sub 2}-depolarized anode, zinc was deposited at 0.6 V (0.8 kA/m{sup 2}); the open circuit voltage was 0.45 V. Three types of fuel pellets were tested and compared with results for 0.75 mm cut wire: spheres produced in a spouted bed (UCB); coarse powder produced by gas-atomization (Noranda); and irregular pellets produced by chopping 1-mm plates of compacted zinc fines (Eagle-Picher, Inc.). All three types transported within the cell. The coarse powder fed continuously from hopper to cell, as did the compacted pellets (< ...

2006-01-19

119

Superplastic deformation of nitrogen-rich Ca-#alpha#-sialon ceramics  

International Nuclear Information System (INIS)

Nitrogen-rich Ca-#alpha#-sialon ceramics, prepared with CaH_2 as one of the starting powders, were compressively deformed in spark plasma sintering equipment. Compared with the oxygen-rich Ca-#alpha#-sialons, increasing onset deformation temperatures (about 150 K higher) were observed for nitrogen-rich Ca-#alpha#-sialons deformed at a rate of 2 x 10"-"3 s"-"1. High hardness (H_V_1_0 = 18-20 GPa) and toughness (K_I_C = 4-7 MPa m"1"/"2) were maintained after the deformation. Anisotropic grain growth was found to take place during deformation, resulting in anisotropic microstructures, containing coarse and elongated grains. The observed differences in deformation behaviour and properties between nitrogen-rich and oxygen-rich Ca-#alpha#-sialons are, as indicated by transmission electron microscopy and electron energy loss spectroscopy analysis, attributed to the presence of reduced ...

2008-02-25

120

bring scheme, buy recycled, recycled products, producer responsibility, environment, environmental, household waste, municipal waste, paper recycling  

Wastenet

... Zinc-carbon/air and alkaline-manganese batteries can be reprocessed using a number of different methods, which include smelting and other thermal-metallurgical processes to ... Citron in France - thermal-metallurgical reprocessing primarily of zinc-carbon/air and alkaline-manganese (including older ones containing mercury), but also NiMH, ...

121

Zinc/air technology, December 1993 meeting report  

Energy Technology Data Exchange (ETDEWEB)

A Zinc/Air Battery Review and Strategic Planning Meeting was held in 1993. One outcome of the meeting was recognition of the need for a report on the current status of the technology. This report contains contributions from many of the attendees at the above meeting and expresses their views on where the technology is today and what could/should be done to improve its performance.

1994-10-01

122

Zinc tetraaminophthalocyanine-Fe3O4 nanoparticle composite for laccase immobilization  

UK PubMed Central (United Kingdom)

Zinc tetraaminophthalocyanine-Fe3O4 nanoparticle composites were prepared by organic-inorganic complex technology and characterized. It has been proved that the ZnTAPc dispersed...Full Text Available

2007-12-01

123

The relationship between seminal plasma zinc levels and high molecular weight zinc binding protein and sperm motility in Iraqi infertile men  

International Nuclear Information System (INIS)

To evaluate the relationship between sperm motility and total seminal plasma zinc concentration and high molecular weight zinc bound protein values in infertile Iraqi men. A case-control study was conducted at the Chemistry and Biochemistry Department, College of Medicine, Al-Nahrain University, Baghdad, Iraq between March 2005 to February 2006. The subjects for the study included 60 infertile male patients who were recruited Al-Kadhimiya Teaching Hospital, and Institute of Embryo Research and Infertility Treatment, Baghdad, Iraq. They were categorized according to their seminal parameters to oligozoospermia (n=32), azoospermia (n=22), and asthenozoospermia (n=6). Thirty nine fertile men (age range 31.87 +/- 3.76 years) were selected as controls, whose partners had conceived within the last year before participation with this study, and having normal spermiogram parameters. Seminal plasma zinc concentration and high ...

124

Energy density ten times as high; Energy engineering: Zinc/air battery systems on trial. Dichte verzehnfacht; Energietechnik: Zink-Luft-Batteriesystem im Test  

Energy Technology Data Exchange (ETDEWEB)

Prior to an industrial-scale test of zinc/air batteries at Greven, the TUeV Bayern-Sachsen carried out preliminary tests on behalf of the Deutsche Bundespost. The results were quite promising: The energy density of the new battery is ten times as high as that of conventional lead batteries, and the battery-powered test vehicle had a range of up to 300 km. (orig.)

1994-01-01

125

Battery using a metal particle bed electrode  

Energy Technology Data Exchange (ETDEWEB)

A zinc-air battery in a case including a zinc particle bed supported adjacent the current feeder and diaphragm on a porous support plate which holds the particles but passes electrolyte solution. Electrolyte is recycled through a conduit between the support plate and top of the bed by convective forces created by a density of differential caused by a higher concentration of high density discharge products in the interstices of the bed than in the electrolyte recycle conduit.

1991-01-01

126

Battery using a metal particle bed electrode  

Energy Technology Data Exchange (ETDEWEB)

A zinc-air battery in a case is described including a zinc particle bed supported adjacent the current feeder and diaphragm on a porous support plate which holds the particles but passes electrolyte solution. Electrolyte is recycled through a conduit between the support plate and top of the bed by convective forces created by a density of differential caused by a higher concentration of high density discharge products in the interstices of the bed than in the electrolyte recycle conduit. 7 figures.

1991-04-09

127

Alkaline rechargeable zinc-air battery; Alkalische wiederaufladbare Zink-Luft Batterie  

Energy Technology Data Exchange (ETDEWEB)

Because of its high energy density, compatibility with aqueous electrolytes and the low toxicity of its active materials, the zinc-air battery system is an interesting candidate for electric vehicle applications. The use of O{sub 2} from the air as a reactant requires a partially open cell construction and a technologically challenging air interface. This report describes the research and development program at the Paul Scherrer Institute which finally led to the demonstration of a durable, electrically rechargeable zinc-oxygen battery. In a first phase the research program was focused on the development of bifunctional oxygen diffusion electrodes and pasted zinc electrodes. The current-potential behaviour and the cycle life performance of anodes and cathodes was tested in single electrode measurements (three-electrode arrangements) as well as in complete monopolar zinc-oxygen and ...

1996-11-01

128

#alpha#-particle irradiation damage and stage I recovery in zinc  

International Nuclear Information System (INIS)

Defects are produced in zinc by 6.1 MeV #alpha#-particle irradiation at 4.2 K and the subsequent recovery between 4.2 and 22 K. No evidence is found for free migration of an interstitial in the temperature range investigated. The recovery spectra reveal a series of substages which are ascribed to recombination of close Frenkel pairs. (author).

129

Novel alloys to improve the electrochemical behavior of zinc anodes for zinc/air battery  

Energy Technology Data Exchange (ETDEWEB)

In our continued efforts for improving the performance of zinc anodes for a Zn/air battery, we now report the preparation of three alloys and improved performances of anodes made up with these alloys. The alloys contained zinc, nickel, and indium with different weight percentages and were calcined at two different temperatures. Out of the six alloys, the alloy which has a composition of zinc 90%, nickel 7.5% and Indium 2.5% and fired at 500{sup o}C is found to be the best. In the case of the hydrogen evolution reaction, this alloy had its potential shifted to a more negative potential. As far as the cyclic voltammograms were concerned, the difference between the anodic and cathodic part was minimal when compared with other alloys. Surprisingly, this alloy had reversibility even after 100 cycles of the cyclic voltammogram. This is a clear indication that dendrite formation was reduced to a considerable extent. Images taken ...

2006-10-06

130

Feasibility study of a new zinc-air battery concept using flowing alkaline electrolyte  

Energy Technology Data Exchange (ETDEWEB)

Proof-of-principle experiments are reported for a new concept in electrically rechargeable zinc-air battery. The zinc electrode is a porous flow-thru type using a copper foam metal substrate with zinc deposition onto the foam metal from concentrated zincate electrolyte (as used in zinc-slurry type batteries). The bifunctional air electrode employs low-cost materials, being fabricated entirely from carbon-based precursors and small amounts of nickel and/or cobalt oxide. Corrosion measurements on the graphite materials in the air electrode indicate sufficient corrosion resistance for 8000 h life on charge. A prototype single cell was constructed having 1.5 Ah capacity producing 1.2 V discharge -2.0 charge at the three hour rate and has produced stable voltages for more than 150 cycles. Based on the 1.5 Ah prototype characteristics, design calculations for a 32 kWh battery project an energy density of ...

1986-04-01

131

Phosphorous adsorption and precipitation in a permeable reactive wall: Applications for wastewater disposal systems  

Energy Technology Data Exchange (ETDEWEB)

A permeable reactive mixture has been developed using low cost, readily available materials that is capable of providing effective, long-term phosphorous treatment in areas impacted by on-land wastewater disposal. The reactive mixture creates a geochemical environment suitable for P-attenuation by both adsorption and precipitation reactions. Potential benefits include significant reductions in phosphorous loading to receiving groundwater and surface water systems, and the accumulation of P-mass in a finite and accessible volume of material. The mixture may be applied as a component within surface treatment systems or in subsurface applications such as horizontal or vertical permeable reactive walls. The mixture averaged > 90% treatment efficiency over 3.6 years of continuous-flow laboratory column experiments. The mixture was further evaluated at the pilot-scale to treat municipal wastewater, and the field-scale to treat a well-characterized ...

1997-12-31

132

Evaluating the cytotoxicity of palladium/magnetite nano-catalysts intended for wastewater treatment  

International Nuclear Information System (INIS)

Palladium/magnetite nanoparticulate catalysts were developed for efficient elimination of halogenated organic pollutants from contaminated wastewater. Particle recovery from treated water can be ensured via magnetic separation. However, in worst-case scenarios, this catalyst removal step might fail, leading to particle release into the environment. Therefore, a toxicological study was conducted to investigate the impact of both pure magnetite and palladium/magnetite nanoparticle exposure upon human skin (HaCaT) and human colon (CaCo-2) cell lines and a cell line from rainbow trout gills (RTgill-W1). To quantify cell viability after particle exposure, three endpoints were examined for all tested cell lines. Additionally, the formation of reactive oxygen species was studied for the human cells. The results showed only minor effects of the particles on the tested cell systems and support the assumption that palladium/magnetite nano-catalysts can be implemented for a ...

2010-01-01

133

Development of a Novel Bioelectrochemical Membrane Reactor for Wastewater Treatment.  

Science.gov (United States)

A novel bioelectrochemical membrane reactor (BEMR), which takes advantage of a membrane bioreactor (MBR) and microbial fuel cells (MFC), is developed for wastewater treatment and energy recovery. In this system, stainless steel mesh with biofilm formed on it serves as both the cathode and the filtration material. Oxygen reduction reactions are effectively catalyzed by the microorganisms attached on the mesh. The effluent turbidity from the BEMR system was low during most of the operation period, and the chemical oxygen demand and NH(4)(+)-N removal efficiencies averaged 92.4% and 95.6%, respectively. With an increase in hydraulic retention time and a decrease in loading rate, the system performance was enhanced. In this BEMR process, a maximum power density of 4.35 W/m(3) and a current density of 18.32 A/m(3) were obtained at a hydraulic retention time of 150 min and external resister of 100 ?. The Coulombic efficiency was 8.2%. Though the power density and current ...

2011-10-01

134

Development and application of bio-sensor. Production of ammonia sensor  

Energy Technology Data Exchange (ETDEWEB)

The objectives of this study are to make a biosensor on a trial basis which can instantaneously measure the nitrogen in wastewater, and to develop a wastewater treatment system which is capable of on-line measurement and controlling. The system provides easier operational control relating to such a high efficient treatment as the removal of nitrogen content in wastewater, serving as a solution to the eutrophication problem. It can be applied also to the analysis of fertilizer components for agriculture. Ammonia oxidizing bacteria were immobilized with cellulose acetate film, which is mounted on a diaphragm type oxygen electrode to make a sensor, and its responsibility was studied. The gradient is slow in high concentration but sharp in low concentration, and it seems possible to use it for the measurement for less than 20 ppm nitrogen concentration. The dependence of the sensor including electrodes and activity of bacteria ...

1989-08-01

135

Anaerobic treatment of wastewater from a food-manufacturing plant with a low concentration of organic matter and regeneration of usable pure water  

Energy Technology Data Exchange (ETDEWEB)

Wastewater from a food-manufacturing plant with a low concentration of organic matter was treated at 37 centigrade in an anaerobic fluidized-bed reactor or in an upflow anaerobic sludge blanket. As the influent TOC (total organic carbon) concentration decreased, the TOC removal efficiency in these reactors decreased from 85% to 65%. The concentration of suspended solids in the effluent could be reduced to 20 mg/l, which corresponded to 7% of that in the influent. The effluent from both reactors was treated aerobically in a fixed-bed reactor. The TOC concentration and optical density of effluent from the aerobic treatment were reduced to 5 mg/l and 0.005, respectively. When the effluent treated anaerobically or aerobically was passed over an activated carbon column, the effluent TOC concentration was reduced to 2 to 3 mg/l. The conductivity in raw wastewater was remarkably reduced on an ion-exchange resin column. Ultra-pure water for industrial ...

1994-03-25

136

Anaerobic digestion of olive mill wastewaters  

Energy Technology Data Exchange (ETDEWEB)

Anaerobic treatment of olive oil mill wastewaters (COD up to 220 kg/cubic m) is feasible, and the most promising results were obtained on UASB reactors, both at laboratory and pilot scale (tank capacity 15 litres and 5 cubic m), fed on diluted waste (COD = 13-18 kg/cubic m). Volumetric loading rates ranging from 16-21.5 kg COD/cubic m/day and 70% removal efficiencies were obtained with these digesters. Start-up of UASB reactors fed on olive oil mill waste is a delicate step which still has to be fully controlled and optimized. The best results were obtained by starting with very diluted waste (COD = 5 kg/cubic m). Granulation of the sludge, as achieved in Dutch UASB digesters fed on sugar beet wastewaters, was not obtained, but, even so, the settleability of the sludge was very good. 22 references.

1984-01-01

137

Effects of the insertion of a thick sp"2 buffer layer on the adhesion of cBN-rich film  

International Nuclear Information System (INIS)

A method was proposed and examined to deposit thick cubic boron nitride (cBN)-rich layer of good adhesion to silicon substrate. The method combined (i) the insertion of a thick sp"2 buffer layer, and (ii) the use of an appropriate assist ion beam energy for the growth of the cBN-rich top layer. The sp"2-bonded boron nitride buffer layer was deposited under irradiation of ions with energies in the range of 200-360 eV. The buffer layer was found to contain curled graphitic basal planes, and so was supposed to be relatively deformable, and facilitate the relaxation of stresses in the cBN-rich top layer. The ion assist introduced during the growth of the cBN-rich layer was supposed to both create and annihilate defects, and so resulted in the generation and relaxation of internal stresses. Results showed that the insertion of a 492 nm sp"2 buffer layer, and the use of a beam energy of 450 eV for assisting ...

2004-05-01

138

Waste characterization study for the Kemp's Ridley sea turtle. Technical memo  

Energy Technology Data Exchange (ETDEWEB)

The Kemp's Ridley sea turtle, Lepidochelys kempi, is an endangered species. The National Marine Fisheries Service's Head Start program is part of an international operation to save the turtles from extinction. Under the Head Start program, eggs from the Ridley's only known wild nesting beach at Rancho Nuevo in Mexico are transported to Padre Island on the Texas coast to be hatched. The head start enables the turtles to develop a survival advantage. The principal objective was to develop baseline waste-characterization data required to design a waste-water treatment scheme for the Galveston Head Start facility. As a secondary objective, preliminary testing of some filtration components was undertaken to determine which units were most appropriate for inclusion in a wastewater treatment scheme.

1988-02-01

139

Ozonation kinetics of phenolic acids present in wastewaters from olive oil mills  

Energy Technology Data Exchange (ETDEWEB)

A kinetic study of the degradation by ozone of eight phenolic acids present in wastewaters from olive oil mills has been performed by using a competition kinetic method. The selected phenolic acids are: caffeic, p-coumaric, syringic, vanillic, 3,4,5-trimethoxybenzoic, veratric, p-hydroxy-benzoic, and protocatechuic. The influence of the operating variables (temperature, pH, and ozone partial pressure in the gas stream) is established, and the stoichiometric ratios for the individual direct reactions between ozone and each acid are determined. Once the reaction rate constants are evaluated, they are correlated as a function of temperature and pH into kinetic expressions which are provided for every phenolic acid. The global process occurs in the fast and pseudo-first-order kinetic regime of absorption, a condition required by the competition model to be used.

1997-03-01

140

Environmental implications of coal gasification/liquefaction technologies in Canada  

Energy Technology Data Exchange (ETDEWEB)

This report reviews coal conversion processes which may be introduced in Canada within the next decade if interest in alternate energy technologies continues. A detailed review was conducted on coal liquefaction and gasification projects worldwide including information on individual proprietors, process technologies used, their present status and available environmental data. Further assessment of emissions and wastes emanating from commercial-scale plants was used to determine significant or potentially significant wastestreams connected to the various technologies, particularly wastewater discharges. Emphasis was placed on those technologies that are close to commercialization in Canada, i.e. SASOL II-type liquefaction facility at Hat Creek. Available information on wastewater treatment/reuse is also included in this report.

1983-01-01

141

Dye Removal, Energy Consumption and Operating Cost of Electrocoagulation of Textile Wastewater as a Clean Process  

British Library Electronic Table of Contents (United Kingdom)

Abstract In this research, the efficiency of electrocoagulation treatment process using aluminum electrodes to treat synthetic wastewater containing Reactive Red198 (RR198) was studied. The effects of parameters such as voltage, time of reaction, electrode connection mode, initial dye concentration, electrolyte concentration, and inter electrode distance on dye removal efficiency were investigated. In addition, electrical energy consumption, electrode consumption, and operating cost at optimum condition have been investigated. The results showed that dye and chemical oxygen demand removals were 98.6 and 84%, respectively. Electrode consumption, energy consumption and operating cost were 0.052-kg/m3, 1.303-kWh/m3 and 0.256-US$/m3, respectively. Dye removal kinetic followed first order kinet...

2011-01-01

142

Separation and determination of cadmium and zinc as their thenoyltrifluoroacetone complexes with dibenzo-18-crown-6 by means of synergistic extraction and atomic absorption spectrometry  

Energy Technology Data Exchange (ETDEWEB)

A new method for the separation and determination of trace amounts of cadmium and zinc in water as their thenoyltrifluoroacetone (TTA) complexes with dibenzo-18-crown-6 (DB18C6) in o-dichlorobenzene has been established by means of synergistic extraction and back-extraction combined with atomic absorption spectrometry. The effect of various factors (synergism with TTA and DB18C6, shaking time, composition of the extracted species, and mutual separation etc.) on the extraction and back-extraction of cadmium and zinc has been in- vestigated. When the mixtures were extracted for 4 min at pH 4.9, only zinc was extracted quantitatively, whereas cadmium remained in the aqueous phase. After the phases were separated, cadmium was again extracted quantitatively at pH 7.5. Then, the two phases were each shaken with 0.05-0.1 mol/l HCl in order to back-extract cadmium and zinc from the organic phases; the ions were ...

1997-01-01

143

Paper-based, printed zinc-air battery  

Energy Technology Data Exchange (ETDEWEB)

A flexible battery is printed on paper by screen-printing a zinc/carbon/polymer composite anode on one side of the sheet, polymerising a poly(3,4-ethylenedioxythiophene) (PEDOT) cathode on the other side of the sheet, and applying a lithium chloride electrolyte between the two electrodes. The PEDOT cathode is prepared by inkjet printing a pattern of iron(III)p-toluenesulfonate as a solution in butan-1-ol onto paper, followed by vapour phase polymerisation of the monomer. The electrolyte is prepared as a solution of lithium chloride and lithium hydroxide and also applied by inkjet printing on to paper, where it is absorbed into the sheet cross-section. Measurements on a zinc/carbon-PEDOT/air battery in a similar configuration on a polyethylene naphthalate substrate shows a discharge capacity of up to 1.4 mAh cm{sup -2} for an initial load of 2.5 mg zinc, equivalent to almost 70% of the zinc content of ...

2009-12-01

144

The roles and electrochemical characterizations of activated carbon in zinc air battery cathodes  

Energy Technology Data Exchange (ETDEWEB)

We prepared cathodes with various types of activated carbon and measured the cathodes' electrochemical performance according to the kind of activated carbon. Activated carbon supplies airflow channels and reaction sites in the cathode of zinc air batteries. When we use activated carbon with a high specific surface area as the cathode's catalyst substrate, we expect high electrochemical performance because this type of carbon provides more air flow channels and reaction sites. We focused on investigating the relationship between the cathode's pore structure and its electrochemical characterizations. We also studied the effects of the various activated carbon materials on the zinc air batteries' performance. Increasing the macropores or mesopores in the activated carbon resulted in achieving more power from the battery. (author)

2006-12-01

145

SYNERGISTIC EFFECT OF N,N-BIS(PHOSPHONOMETHYL) GLYCINE AND ZINC IONS IN CORROSION CONTROL OF CARBON STEEL IN COOLING WATER SYSTEMS  

British Library Electronic Table of Contents (United Kingdom)

A protective film has been developed on the surface of carbon steel in low chloride aqueous environment using a synergistic mixture of an environmentally friendly phosphonic acid, N,N-bis(phosphonomethyl) glycine (BPMG), and zinc ions. Impedance studies of the metal/solution interface indicated that the surface film is highly protective against the corrosion of carbon steel in the chosen environment. Potentiodynamic polarization studies showed that the inhibitor is a mixed inhibitor. X-ray photoelectron spectroscopic analysis (XPS) of the film showed the presence of the elements iron, phosphorus, nitrogen, oxygen, carbon, and zinc. Deconvolution spectra of these elements in the surface film showed the presence of oxides/hydroxides of iron(III), Zn(OH)2, and [Zn(II)-BPMG] complex. This infe...

2011-01-01

146

Raney-platinum film electrodes for potentially implantable glucose fuel cells. Part 1: Nickel-free glucose oxidation anodes  

British Library Electronic Table of Contents (United Kingdom)

We present a novel fabrication route yielding Raney-platinum film electrodes intended as glucose oxidation anodes for potentially implantable fuel cells. Fabrication roots on thermal alloying of an extractable metal with bulk platinum at 200^oC for 48h. In contrast to earlier works using carcinogenic nickel, we employ zinc as potentially biocompatible alloying partner. Microstructure analysis indicates that after removal of extractable zinc the porous Raney-platinum film (roughness factor ~2700) consists predominantly of the Pt3Zn phase. Release of zinc during electrode operation can be expected to have no significant effect on physiological normal levels in blood and serum, which promises good biocompatibility. In contrast to previous anodes based on hydrogel-bound catalyst particles the ...

2010-01-01

147

Lead, copper and zinc biosorption from bicomponent systems modelled by empirical Freundlich isotherm  

Energy Technology Data Exchange (ETDEWEB)

The biosorption of lead, copper and zinc ions on Rhizopus arrhizus has been studied for three single-component and two binary systems. The equilibrium data have been analysed using the Freundlich adsorption model. The characteristic parameters for the Freundlich adsorption model have been determined and the competition coefficients for the competitive biosorption of Pb(II)-Cu(II) at pH 4.0 and 5.0, and Pb(II)-Zn(II) at pH 5.0 have been calcualted. For the individual single-component isotherms, lead has the highest biosorption capacity followed by copper, then zinc. The capacity of lead in the two binary systems is always significantly greater than those of the other metal ions, in agreement with the single-component data. Only a partial selectivity for copper ions has been obtained at pH 4.0. (orig.)

2000-07-01

148

Functional domain analysis of glass, a zinc-finger-containing transcription factor in Drosophila.  

Science.gov (United States)

The glass gene is required for proper photo-receptor differentiation during development of the Drosophila eye glass codes for a DNA-binding protein containing five zinc fingers that we show is a transcriptional activator. A comparison of the sequences of the glass genes from two species of Drosophila and a detailed functional domain analysis of the Drosophila melanogaster glass gene reveal that both the DNA-binding domain and the transcriptional-activation domain are highly conserved between the two species. Analysis of the DNA-binding domain of glass indicates that the three carboxyl-terminal zinc fingers alone are necessary and sufficient for DNA binding. We also show that a deletion mutant of glass containing only the DNA-binding domain can behave in a dominant-negative manner both in vivo and in a cell culture assay that measures transcriptional activation. PMID:7604032

1995-07-01

149

Self-similarity in NMR Spectra: An Application in Assessing the Level of Cysteine  

UK PubMed Central (United Kingdom)

High resolution of NMR spectroscopic data of biosamples are a rich source of information on the metabolic response to physiological variation or pathological events. There are many advantages...Full Text Available

2010-01-01

150

Ras history  

UK PubMed Central (United Kingdom)

Although the roots of Ras sprouted from the rich history of retrovirus research, it was the discovery of mutationally activated RAS genes in human cancer in 1982 that stimulated an...Full Text Available

2010-07-01

151

Phylogenetic relationships in Cortinarius, section Calochroi, inferred from nuclear DNA sequences  

UK PubMed Central (United Kingdom)

BackgroundSection Calochroi is one of the most species-rich lineages in the genus Cortinarius (Agaricales, Basidiomycota) and is widely distributed...Full Text Available

152

Mass measurement of neutron-rich isotopes from [sup 51]Ca to [sup 72]Ni  

Energy Technology Data Exchange (ETDEWEB)

The ground state masses of thirty-nine neutron-rich nuclei from [sup 51]Ca to [sup 72]Ni have been measured using the Time-of-Flight Isochronous (TOFI) spectrometer. Eight of these masses have been measured for the first time and thirty-one are remeasurements of neutron-rich nuclei previously reported. Good agreement between these results and a previous TOFI experiment was observed except for the most neutron-rich isotopes of vanadium through iron with the present results being more bound and in better agreement with theory. The low binding energy of [sup 68]Ni, as indicated by an unreasonably low two-neutron separation energy, suggests the presence of a high-lying, long-lived isomeric state in this nucleus. (orig.)

1994-07-01

153

Mass measurement of neutron-rich isotopes from "5"1Ca to "7"2Ni  

International Nuclear Information System (INIS)

The ground state masses of thirty-nine neutron-rich nuclei from "5"1Ca to "7"2Ni have been measured using the Time-of-Flight Isochronous (TOFI) spectrometer. Eight of these masses have been measured for the first time and thirty-one are remeasurements of neutron-rich nuclei previously reported. Good agreement between these results and a previous TOFI experiment was observed except for the most neutron-rich isotopes of vanadium through iron with the present results being more bound and in better agreement with theory. The low binding energy of "6"8Ni, as indicated by an unreasonably low two-neutron separation energy, suggests the presence of a high-lying, long-lived isomeric state in this nucleus. (orig.).

154

Favism, with special reference to Iran*  

UK PubMed Central (United Kingdom)

Fava beans (Vicia fava) are cultivated rather widely in most countries of the Eastern Mediterranean area and provide a cheap but protein-rich food that can be eaten alone, in various...Full Text Available

1969-01-01

155

Characterization of cry Genes in a Mexican Bacillus thuringiensis Strain Collection  

UK PubMed Central (United Kingdom)

Mexico is located in a transition zone between the Nearctic and Neotropical biogeographical regions and contains a rich and unique biodiversity. A total of 496 Bacillus thuringiensis...Full Text Available

1998-12-01

156

Aging measurements of a TMAE-based photon detector for the HERA-B RICH  

CERN Document Server

We report on aging measurements of a photon detector candidate for the HERA-B RICH. The prototype, a proportional wire chamber operated with TMAE, was mounted on an argon filled test-beam RICH and was aged by UV light at rates we expect in HERA-B. We monitored gain and current continuously, and checked the chamber with Cherenkov photons at regular intervals. The number of detected photons/track (projected to 2.75 m C sub 4 F sub 1 sub 0 in HERA-B) dropped from 26 to 11 after two days of aging - well below the 20 required for pi/K separation. Based on these results, HERA-B decided to use multi-anode PMTs as photon detectors in the RICH.

1999-01-01

157

Zinc release from thapsigargin/IP3-sensitive stores in cultured cortical neurons  

UK PubMed Central (United Kingdom)

BackgroundChanges in ionic concentration have a fundamental effect on numerous physiological processes. For example, IP3-gated thapsigargin sensitive intracellular calcium...Full Text Available

158

The Zinc Finger SET Domain Gene Prdm14 Is Overexpressed in Lymphoblastic Lymphomas with Retroviral Insertions at Evi32  

UK PubMed Central (United Kingdom)

BackgroundAKXD recombinant inbred strains of mice have proven to be very useful in the identification of potential oncogenes and tumor suppressors involved in the development of...Full Text Available

159

Targeted plasmid integration into the human genome by an engineered zinc-finger recombinase  

UK PubMed Central (United Kingdom)

The development of new methods for gene addition to mammalian genomes is necessary to overcome the limitations of conventional genetic engineering strategies. Although a variety of DNA-modifying enzymes...Full Text Available

2011-09-01

160

Silver nanoparticle-decorated carbon nanotubes as bifunctional gas-diffusion electrodes for zinc-air batteries  

Energy Technology Data Exchange (ETDEWEB)

Thin, lightweight, and flexible gas-diffusion electrodes (GDEs) based on freestanding entangled networks of single-walled carbon nanotubes (SWNTs) decorated with Ag nanoparticles (AgNPs) are tested as the air-breathing cathode in a zinc-air battery. The SWNT networks provide a highly porous surface for active oxygen absorption and diffusion. The high conductivity of SWNTs coupled with the catalytic activity of AgNPs for oxygen reduction leads to an improvement in the performance of the zinc-air cell. By modulating the pH value and the reaction time, different sizes of AgNPs are decorated uniformly on the SWNTs, as revealed by transmission electron microscopy and powder X-ray diffraction. AgNPs with sizes of 3-5 nm double the capacity and specific energy of a zinc-air battery as compared with bare SWNTs. The simplified, lightweight architecture shows significant advantages over conventional carbon-based GDEs in terms of ...

2010-07-01

161

Sequences homologous to the human x- and y-borne zinc finger protein genes (ZFX/Y) are autosomal in monotreme mannals  

Energy Technology Data Exchange (ETDEWEB)

The human zinc finger protein genes (ZFX/Y) were identified as a result of a systematic search for the testis-determining factor gene on the human Y chromosome. Although they play no direct role in sex determination, they are of particular interest because they are highly conserved among mammals, birds, and amphibians and because, in eutherian mammals at least, they have active alleles on both the X and the Y chromosomes outside the pseudoautosomal region. We used in situ hybridization to localize the homologues of the zinc finger protein gene to chromosome 1 of the Australian echidna and to an equivalent position on chromosomes 1 and 2 of the playtpus. The localization to platypus chromosome 1 was confirmed by Southern analysis of a Chinese hamster [times] platypus cell hybrid retaining most of platypus chromosome 1. This localization is consistent with the cytological homology of chromosome 1 between the two species. The ...

1993-02-01

162

Radionuclide X-ray fluorescence analysis of waste water from the production of citric acid  

Energy Technology Data Exchange (ETDEWEB)

Radionuclide X-ray fluorescence analysis was used for the determination of iron, calcium, potassium, copper, manganese and zinc in waste water from the production process of citric acid.

1982-02-18

163

Radionuclide X-ray fluorescence analysis of waste water from the production of citric acid  

International Nuclear Information System (INIS)

Radionuclide X-ray fluorescence analysis was used for the determination of iron, calcium, potassium, copper, manganese and zinc in waste water from the production process of citric acid. (author).

1982-02-01

164

Osterix Overexpression in Mesenchymal Stem cells Stimulates Healing of Critical-Sized Defects in Murine Calvarial Bone  

UK PubMed Central (United Kingdom)

Osterix (Osx) is a zinc-finger-containing transcription factor that is expressed in osteoblasts of all endochondral and membranous bones. In Osx null ...Full Text Available

2007-10-01

165

Human intronic enhancers control distinct sub-domains of Gli3 expression during mouse CNS and limb development  

UK PubMed Central (United Kingdom)

BackgroundThe zinc-finger transcription factor GLI3 is an important mediator of Sonic hedgehog signaling and crucial for patterning of many aspects of the vertebrate body plan. In...Full Text Available

166

German connections behind EFL's Zn-air  

Energy Technology Data Exchange (ETDEWEB)

This paper describes a new concept in zinc-air battery technology and provides and insight into the role of the German Post Office and its former chairman in its commercial promotion. (UK)

1994-10-01

167

Economic evaluation of the solar carbothermic reduction of ZnO by using a single sensitivity analysis and a Monte-Carlo risk analysis  

Energy Technology Data Exchange (ETDEWEB)

The technical feasibility of the solar carbothermal reduction of ZnO has been successfully demonstrated in a pilot plant. The economics of this process is addressed by means of a single sensitivity analysis and a Monte-Carlo risk analysis. A medium-term and a long-term scenario have been investigated, each for a 5 and a 30 MW{sub th} plant. For a discount rate of 15% the zinc production costs vary between 482 and 245 $/t for the medium-term scenario and between 312 and 146 $/t for the long-term scenario, respectively. These costs do not account for the zinc oxide input material. In addition, a risk analysis was conducted for the 30 MW{sub th} long-term scenario. For each input parameter, a probability distribution was estimated and the probability distribution of the zinc production cost was calculated by means of a Monte-Carlo method. The expected mean zinc production costs vary from 95 $/t for a ...

2007-07-15

168

Corrosion and histopathological studies on anode materials for implantable power sources. [In vivo corrosion studies on anode material  

Science.gov (United States)

The biocompatibility and corrosion resistance of various materials for use as sacrificial anodes in in vivo hybrid fuel cells were studied. Aluminium, zinc, and magnesium alloy AZ31B were studied, and the results are discussed.

1974-01-01

169

Contribution to the radionuclide x-ray fluorescence analysis of human blood and plasma  

International Nuclear Information System (INIS)

A photon-induced x-ray fluorescence method allowing the simultaneous determination of iron, copper, zinc, bromine and rubidium in human blood and blood plasma samples is described. The method is reliable and has a good sensitivity for a wide range of elements. (author).

1986-04-01

170

Citrate Process Flue Gas Desulfurization Demonstration Plant.  

Science.gov (United States)

At the St. Joe Minerals Corp.'s zinc smelter powerplant, an SO2 emission control program evolved into a cooperative program with the Bureau of Mines for installation and initial operation of a citrate process flue gas desulfurization demonstration plant. ...

1983-01-01

171

Cadmium, Lead, and Other Metals in Relation to Semen Quality: Human Evidence for Molybdenum as a Male Reproductive Toxicant  

UK PubMed Central (United Kingdom)

BackgroundEvidence on human semen quality as it relates to exposure to various metals, both essential (e.g., zinc, copper) and nonessential (e.g., cadmium, lead), is inconsistent....Full Text Available

2008-11-01

172

Atmospheric corrosion in Gran Canaria specifically meteorological and pollution conditions.  

Science.gov (United States)

Carbon steel, copper, zinc and aluminium samples were exposed in different sizes with known ambient parameters in Gran Canaria Island and atmospheric corrosion was investigated. Weight-loss measurements used to determine corrosion damage were complemented...

1998-01-01

173

Assessment of battery technologies for electric vehicles  

Energy Technology Data Exchange (ETDEWEB)

This document, Part 2 of Volume 2, provides appendices to this report and includes the following technologies, zinc/air battery; lithium/molybdenum disulfide battery; sodium/sulfur battery; nickel/cadmium battery; nickel/iron battery; iron/oxygen battery and iron/air battery. (FI)

1990-02-01

174

A Novel Nuclear-Localized CCCH-Type Zinc Finger Protein, OsDOS, Is Involved in Delaying Leaf Senescence in Rice1[W  

UK PubMed Central (United Kingdom)

Leaf senescence is a developmentally programmed degeneration process, which is fine tuned by a complex regulatory network for plant fitness. However, molecular regulation of leaf senescence is poorly...Full Text Available

2006-08-01

175

Waste treatment by dialysis. (Latest citations from Pollution abstracts). Published Search  

Energy Technology Data Exchange (ETDEWEB)

The bibliography contains citations concerning the use of dialysis in the treatment of wastewaters. Techniques for the removal of metals, ammonia, waste acids, nitrates, and phosphates are described. Special attention is given to the desalination of liquid wastes. Applications of this technology to the treatment of effluent from the agrochemical, petrochemical, tanning, and electroplating industries are discussed. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

1996-02-01

176

Simultaneous ultraviolet spectrophotometric determination of nitrate and nitrite in water  

Energy Technology Data Exchange (ETDEWEB)

A rapid and accurate method for the direct simultaneous determination of nitrate and nitrite is proposed. The method is applied to the determination of nitrate and nitrite in rainwater and wastewater without preliminary separation. The determinations are performed by a CPA matrix method with ultraviolet spectrophotometric detection. The results obtained are in agreement with those obtained by conventional methods for the determination of nitrate and nitrite.

1991-02-01

177

Siemens provides treatment packages for oil production  

British Library Electronic Table of Contents (United Kingdom)

Modec International Inc has selected Siemens Water Technologies to provide sea-water reverse osmosis (SWRO) systems for several floating, production, storage and offloading (FPSO) vessels that are to be operated in deep-water locations. Siemens is also supplying a wastewater reuse system to one of Brazils largest refineries.

2010-01-01

178

Nitrite removal from marine aquaculture wastewater using electrochemical process  

International Nuclear Information System (INIS)

The hazardous and toxic nature of some of the constituent such as nitrite in the aquaculture wastewater is of major concern. Present study focuses the removal of nitrite from the aquaculture wastewater prior to disposal. Effect of certain operational parameters such as electrode material, current density, initial pH, and electrode spacing on nitrite removal from aquaculture wastewater was elucidated. Better nitrite removal efficiency achieved when nickel used as compared to stainless steel, graphite and aluminum electrodes. Nitrite removal is positively related to the current density however, increase is up to 31.4% when current density increased from 2.5 to 9.3 mA/cm/sup 2/. Further increase in current density does not improve the process efficiency. Removal efficiency of electrochemical process decreased with the increase in initial pH of test solution. However, with the passage of time this difference is diminishing. ...

3183-01-01

179

Inland wetlands legislation and management. (Latest citations from the NTIS data base). Published Search  

Energy Technology Data Exchange (ETDEWEB)

The bibliography contains citations concerning Federal and state laws and management programs for the protection and use of inland wetlands. Utilization of wetlands to control highway runoff and community wastewater is discussed. Wetlands protection programs, restoration projects, resource planning, and wetlands identification methods are cited. References to coastal and salt water wetlands are not included in this bibliography. (Contains 250 citations and includes a subject term index and title list.)

1992-05-01

180

Engineering approaches to ecosystem restoration  

Energy Technology Data Exchange (ETDEWEB)

This proceedings CD ROM contains 127 papers on developing and evaluating engineering approaches to wetlands and river restoration. The latest engineering developments are discussed, providing valuable insights to successful approaches for river restoration, wetlands restoration, watershed management, and constructed wetlands for stormwater and wastewater treatment. Potential solutions to a wide variety of ecosystem concerns in urban, suburban, and coastal environments are presented.

1998-07-01

181

Chapter 11 Aqueous Solutions  

Wastenet

...Chapter 11 Aqueous Solutions Chapter 11 Aqueous Solutions Download the entire chapter (PDF-136k) Drilling to China More water than rivers Saving the aquifer Drying with Xeriscapes Everywhere in the house Rainwater and graywater Creating urban watersheds Wastewater equals ...3851 Powered by Intrcomm Technology's SMC ...

182

Aerosols Equipment in Brazil on Environmental Expert  

Wastenet

... Hale, Markku Kulmala, 373.43 EUR; 225.00 USD; 276.00 GBP... More Journals » MAGAZINES & JOURNALS Environmental Quarterly - 2009 Fall Trinity`s Environmental Quarterly (EQ) magazine co... Industrial Wastewater Responsible for managing your company`s wastes?... ...

183

Zn/gelled 6M KOH/O{sub 2} zinc-air battery  

Energy Technology Data Exchange (ETDEWEB)

The gel electrolyte for the zinc-air cell was prepared by mixing hydroponics gel with a 6M potassium hydroxide aqueous solution. The self-discharge of cells was characterized by measuring the open-circuit voltage. The effect of a discharge rate of 50mA constant current on cell voltage and plateau hour, as well as the voltage-current and current density-power density were measured and analysed. The electrode degradation after discharge cycling was characterized by structural and surface methods. The oxidation of the electrode surface further blocked the utilization of the Zn anode and was identified as a cause for the failure of the cell. (author)

2006-09-13

184

Rechargeable zinc/manganese dioxide cell  

Energy Technology Data Exchange (ETDEWEB)

A rechargeable cell is disclosed which is characterized in the following manner. A positive electrode is formed from a manganese oxide electrode material. This manganese oxide electrode material contains a heavy metal selected from the group comprising lead, bismuth, and mixtures of lead and bismuth. The cell also contains a negative electrode of zinc. A separator is provided between the positive electrode and the negative electrode. An alkaline electrolyte consisting essentially of an alcohol and an alkaline hydroxide is also contained in the rechargeable cell in contact with both the positive electrode and the negative electrode.

1984-05-29

185

Lead oxides-lithium cells  

Science.gov (United States)

The possibility of using lead and lead-bismuth mixed oxides as positive active materials in organic electrolyte lithium cells with a working voltage similar to those of silver zinc cells has been considered. Button cells of SR 44 size have been developed as a test vehicle and studied under various conditions of discharge rate and storage. This paper describes the performance characteristics obtained under these conditions and suggests in conclusion the possible replacement of silver zinc cells by such systems for a large range of low-rate applications on the basis of cost effectiveness.

1979-01-01

186

Full potential linearized augmented plane wave calculations of structural and electronic properties of GeC, SnC and GeSn  

International Nuclear Information System (INIS)

A theoretical study of structural and electronic properties of GeC, SnC and GeSn is presented using the full potential linearized augmented plane wave method. In this approach, the generalized gradient approximation was used for the exchange-correlation potential. Results are given for lattice constant, bulk modulus and its pressure derivative in both zinc-blende and rocksalt structures. Band structure, density of states and band gap pressure coefficients in zinc-blende structure are also given. The results are compared with previous calculations and with experimental measurements.

2003-08-01

187

Evaluation of carbon substrates for bifunctional air electrodes applied in zinc-air-batteries  

Energy Technology Data Exchange (ETDEWEB)

The key component for improving the energy efficiency and cycle life of the electrically rechargeable zinc-air battery is the bifunctional air electrode. The air electrodes described in this paper contained different types of carbon black as the substrate for the perovskite catalyst (La{sub 0.6}Ca{sub 0.4}CoO{sub 3}). Morphological and physical properties of the carbon substrates play an important role in enhancing the activity and stability of the bifunctional air electrode. Current-potential curves and cycle-life tests were applied in order to gather information on the activity and stability of these electrodes. (authors)

2000-07-01

188

Effect of Carbon Dioxide in the Air on Zinc-air Cell  

Energy Technology Data Exchange (ETDEWEB)

The electrolyte was brought into contact with air and potassium carbonate was measured with various contact time in order to check the defect of carbon dioxide in the air on zinc-air cell. The relationship between potassium carbonate concentration in electrolyte and battery capacity was also studied. The potassium carbonate concentration in the electrolyte. The rate of carbon dioxide absorption was mainly affected by the pore size of hydrophobic membrane. Our study showed that adapting the pore of hydrophobic membrane decreased the loss of cell discharge performance due to the presence of carbon dioxide or water vapor in the atmosphere. 7 refs., 12 figs., 1 tab.

1999-04-01

189

Driving-cycle testing for the PSI zinc/air battery  

Energy Technology Data Exchange (ETDEWEB)

This contribution describes our research and development effort towards an electrically rechargeable zinc/air battery which is capable of meeting the demands of a scaled power profile (driving-cycle tests). The power profiles DST (Dynamic Stress Test) and ECE15-L (European Driving Cycle for alkaline Batteries) were applied to our 200 and 50 cm{sup 2} electrically rechargeable Zn/O{sub 2} cells with nominal capacities of 30 and 7.5 Ah, respectively. (authors)

2000-07-01

190

Biosorption process for removing heavy metal ions using water milfoil (Myriophyllum Spicatum) in contaminated water  

Energy Technology Data Exchange (ETDEWEB)

A small scale biomass metal contacting experiment was performed to screen the optimal plant species for biosorption and bioaccumulation of cadmium, zinc, nickel, lead, and copper. Experiments were also conducted to test the ability of the biomass to lower the metal concentrations below the US Environmental Protection Agency surface water discharge criteria. The minimum residual concentration was 0.1 mg/L for zinc, 0.004 mg/L for lead, and about 0.01 mg/L for cadmium, nickel, and lead. Results indicate that water milfoil can be used for bioremoval of metals.

1995-12-31

191

Atmospheric corrosion in Gran Canaria specifically meteorological and pollution conditions  

Energy Technology Data Exchange (ETDEWEB)

Carbon steel, copper, zinc and aluminium samples were exposed in different sizes with known ambient parameters in Gran Canaria Island and atmospheric corrosion was investigated. Weight-loss measurements used to determine corrosion damage were complemented with metallographic and XP S determination in order to characterize the structure and morphology of surface corrosion products. The ambient aggressiveness could be well evaluated from meteorological and pollution data. All atmospheric corrosion and environmental data were statistically processed for establishing general corrosion damage functions for carbon steel, copper, aluminium and zinc in terms of Gran Canaria extreme meteorological and pollution parameters. (Author)

1998-12-31

192

In situ spectroscopic and corrosion studies of ultra-thin gradient plasma polymer layers on zinc  

International Nuclear Information System (INIS)

By means of an audio frequency plasma polymerisation ultra-thin gradient plasma polymer layers were deposited on zinc and zinc-coated iron. The aim was to generate an interfacial polymeric layer which bonds to an oxidised metal as well as to a subsequently applied organic coating and acts as an interfacial barrier layer for ions and water. Surface modifications were done in an in situ plasma cell with infrared reflection absorption spectroscopy (IRRAS). The zinc surface was first activated by an oxygen plasma to provide a freshly oxidised and contamination free oxide surface. The intermediate stages of the surface reactions could be revealed. Carbon dioxide molecules as oxidation products adsorbed on the growing zinc oxide and were desorbed at a later stage. An organosilicon plasma polymer was deposited directly on top of the oxide layer from a hexamethyldisilane (HMDS) plasma. Afterwards a cyclohexene ...

2003-07-15

193

UV photoelectron yield spectroscopy of chalcopyrite structure Cu-In-Se thin films  

International Nuclear Information System (INIS)

Surface-sensitive UV photoelectron yield spectroscopy was employed to study electron acceptor levels at surfaces of chalcopyrite structure Cu-In-Se thin films. Surface Fermi level pinning was observed for Cu-rich films. Shallow acceptor levels ascribable to defects Cu_I_n and V_C_u were observed for near-stoichiometric and In-rich films respectively. (orig.).

194

Spectroscopy of Neutron-Rich Nuclei with the CLARA-PRISMA Setup  

International Nuclear Information System (INIS)

The CLARA-PRISMA setup, composed of an array of 25 Clover detectors placed at the target position of the magnetic spectrometer PRISMA, has recently concluded its campaign to study the structure of moderately neutron-rich nuclei. In this contribution, results obtained in the vicinity of the doubly-magic nucleus "4"8Ca are presented, together with results obtained for the heavy iron isotopes. The perspectives offered by the forthcoming operation of the AGATA Demonstrator Array coupled to PRISMA are also discussed. (author)

2009-03-01

195

Binding the Mammalian High Mobility Group Protein AT-hook 2 to AT-Rich Deoxyoligonucleotides: Enthalpy-Entropy Compensation  

UK PubMed Central (United Kingdom)

HMGA2 is a DNA minor-groove binding protein. We previously demonstrated that HMGA2 binds to AT-rich DNA with very high binding affinity where the binding of HMGA2 to poly(dA-dT)2 is enthalpy-driven...Full Text Available

2009-05-20

196

Autologous Platelet-Rich Plasma Mixed with Purified Fat Graft in Aesthetic Plastic Surgery  

British Library Electronic Table of Contents (United Kingdom)

Platelet-rich plasma (PRP) is a platelet concentrate that has widely been used to accelerate the healing of soft and hard tissues. The preparation of PRP has been described by several authors. Preparation protocols vary from system to system, depending on the concentration of different integrating proteins. The objective of this article is to describe the principal use of PRP mixed with fat grafts in aesthetic plastic surgery.

2009-01-01

197

A microscopic description of neutron-rich lithium isotopes  

International Nuclear Information System (INIS)

A unified calculation of neutron-rich isotopes in lithium is performed using the hyperspherical basis in which the underlying symmetry of each isotope exhibits a simple structure. The variation of the binding energy as a function of mass number is qualitatively reproduced, and the asymptotic of radial distribution of each isotope decreases exponentially. The form factors of the lithium isotopes are calculated and display diffraction minima. 27 refs., 3 figs., 3 tabs.

198

Novel InN growth method under In-rich condition on GaN/Al2O3(0001) templates  

International Nuclear Information System (INIS)

A novel technique is proposed for the growth of an InN film on a GaN/Al2O3(0001) template by radio-frequency plasma-excited molecular beam epitaxy (RF-MBE). The method involves 1) InN growth under an In-rich condition and 2) additional nitrogen radical irradiation after the InN growth under an In-rich condition. Excess In that appeared on the InN surface in the InN growth under an In-rich condition is transformed to InN by the additional nitrogen radical irradiation. The effective V/III ratio is easily controlled by monitoring the intensity in a reflection high-energy electron diffraction (RHEED) pattern. The growth of the InN film by repeating the InN growth under an In-rich condition and the additional nitrogen radical irradiation is also demonstrated. (copyright 2009 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

2009-06-01

199

Shell-model calculations for neutron-rich nuclei in the 0f1p shell  

Energy Technology Data Exchange (ETDEWEB)

A new two-body interaction recently derived for nuclei in the 0f1p shell by fitting two-body matrix elements to 494 energy levels in A=41-66 nuclei, is used to investigate the neutron-rich nuclei in the vicinity of the doubly closed nuclide {sup 48}Ca. This study is of fundamental interest in providing a test for the new effective interaction away from the stability line. Masses and binding energies are calculated for a variety of neutron-rich nuclei and compared with experimental data, where available. In addition level schemes for {sup 50-52}Ca, {sup 51-52}Sc and {sup 51-52}Ti have been calculated and are compared with available experimental data. In general a good correspondence between theory and experiment is found, but some systematic discrepancies are apparent. ((orig.)).

1995-04-17

200

Shell-model calculations for neutron-rich nuclei in the 0f1p shell  

International Nuclear Information System (INIS)

A new two-body interaction recently derived for nuclei in the 0f1p shell by fitting two-body matrix elements to 494 energy levels in A=41-66 nuclei, is used to investigate the neutron-rich nuclei in the vicinity of the doubly closed nuclide "4"8Ca. This study is of fundamental interest in providing a test for the new effective interaction away from the stability line. Masses and binding energies are calculated for a variety of neutron-rich nuclei and compared with experimental data, where available. In addition level schemes for "5"0"-"5"2Ca, "5"1"-"5"2Sc and "5"1"-"5"2Ti have been calculated and are compared with available experimental data. In general a good correspondence between theory and experiment is found, but some systematic discrepancies are apparent. ((orig.)).

201

Shallow-lacustrine sand-rich deltaic depositional cycles and sequence stratigraphy of the Upper Triassic Yanchang Formation, Ordos Basin, China  

British Library Electronic Table of Contents (United Kingdom)

ABSTRACT Shallow-lacustrine delta deposits of the Upper Triassic Yanchang Formation form the most important petroleum reservoir sandstone units in the Ordos Basin, China. Recent hydrocarbon exploration and outcrop studies demonstrated that shallow-lacustrine sand-rich deltas developed extensively along the gentle flanks and central part of the basin. The vertical succession of facies indicates that the Yanchang Formation records the entire lacustrine life cycle of the Late Triassic Ordos Basin. Four third-order transgressive-regressive cycles and two larger shallow-lacustrine deltaic cycles have been recognized. A process-based depositional model, derived in part from the modern Ganjiang delta in Poyang Lake, China, is used to infer the origins of the sand-rich lacustrine delta deposits. S...

2010-01-01

202

On the off-stoichiometric peaking of adiabatic flame temperature  

Energy Technology Data Exchange (ETDEWEB)

The characteristic rich shifting of the maximum adiabatic flame temperature from the stoichiometric value for mixtures of hydrocarbon and air is demonstrated to be caused by product dissociation and hence reduced amount of heat release. Since the extent of dissociation is greater on the lean side as a result of the stoichiometry of dissociated products, the peaking occurs on the rich side. The specific heat per unit mass of the mixture is shown to increase monotonically with increasing fuel concentration, and as such tends to shift the peak toward the lean side. It is further shown that this is the cause for the lean shifting of the adiabatic flame temperature of oxidizer-enriched mixtures of N{sub m}H{sub n} and F{sub 2} and of NH{sub 3} and O{sub 2}, with various amounts of inert dilution, even though their maximum heat release still peaks on the rich side. (author)

2006-06-15

203

New neutron-rich isotopes in the scandium-to-nickel region, produced by fragmentation of a 500 MeV/u {sup 86}Kr beam  

Energy Technology Data Exchange (ETDEWEB)

We have measured production cross-sections of the new neutron-rich isotopes {sup 58}Ti, {sup 61}V, {sup 63}Cr, {sup 66}Mn, {sup 69}Fe, {sup 71}Co and neighbouring isotopes that have been identified as projectile fragments from reactions between a 500 MeV/u {sup 86}Kr beam and a beryllium target. The isotope identification was performed with the zero-degree magnetic spectrometer FRS at GSI, using in addition time-of-flight and energy-loss mesurements. The experimental production cross-sections for the new nuclides and neighbouring isotopes are compared with an empirical parameterization. The resulting prospects for reaching even more neutron-rich isotopes, such as the doubly-magic nuclide {sup 78}Ni, are discussed. (orig.).

1991-10-01

204

Jet plume injection and combustion system for internal combustion engines  

Energy Technology Data Exchange (ETDEWEB)

This invention is comprised of an improved combustion system for an internal combustion engine is disclosed wherein a rich air/fuel mixture is furnished at high pressure to one or more jet plume generator cavities adjacent to a cylinder and then injected through one or more orifices from the cavities into the head space of the cylinder to form one or more turbulent jet plumes in the head space of the cylinder prior to ignition of the rich air/fuel mixture in the cavity of the jet plume generator. The portion of the rich air/fuel mixture remaining in the cavity of the generator is then ignited to provide a secondary jet, comprising incomplete combustion products which are injected into the cylinder to initiate combustion in the already formed turbulent jet plume. Formation of the turbulent jet plume in the head space of the cylinder prior to ignition has been found to yield a higher maximum combustion pressure in the ...

1992-12-31

205

Effect of preparative treatment on the corrosion resistance of duplex stainless steel  

International Nuclear Information System (INIS)

The effect of surface treatment on the characteristics of the passive film on a super duplex stainless steel is addressed. Auger Electron Spectroscopy (AES) has been used to provide in-depth chemical profile analyses of the passivation film. This study showed that the constitution of the film is largely dependent on the electrolytic conditions under which it is produced or to which it is submitted. The passive films formed by polarisation in an alkaline solution (boric-borate solution) consist of two regions, an inner region rich in chromium and an outer region rich in iron, whilst the films produced in acid solution only present the chromium - rich region. The film thickness is also greatly affected by the polarisation conditions. It can vary from ca. 8 monolayers to about 20 monolayers for cathodically and anodically polarised specimens respectively. The microstructure of weldmetal is also discussed. (author)

1999-09-01

206

Responses of aquatic organisms to metal pollution in a lowland river in Flanders: A comparison of diatoms and macroinvertebrates  

International Nuclear Information System (INIS)

The role of macroinvertebrates and diatoms as indicator for metal pollution was investigated by assessing both biota along a metal gradient in the Belgian river the Dommel. Macroinvertebrates and diatoms were sampled in summer and winter and physical-chemical characteristics of the water were measured at four different sample periods and related to sediment characteristics. Although metal concentrations, except cadmium, in the water nowhere exceeded water quality standards, high metal concentrations were measured in the sediment, indicating historical contamination of the Dommel. At the sites that were situated downstream of the pollution source, high levels of conductivity and chloride were measured in the water. Redundancy Analysis (RDA) indicated pH, phosphate and zinc as the significant environmental variables explaining each respectively 7.7%, 11.6% and 22.6% of the macroinvertebrate community composition. Two clusters could be separated, with Gammarus pulex, ...

2008-12-15

207

Preparation of ZnO-Al2O3 Particles in a Premixed Flame  

DEFF Research Database (Denmark)

Zinc oxide (ZnO) and alumina (Al2O3) particles are synthesized by the combustion of their volatilized acetylacetonate precursors in a premixed air-methane flame reactor. The particles are characterized by XRD, transmission electron microscopy, scanning mobility particle sizing and by measurement of the BET specific surface area. Pure (?-)alumina particles appear as dendritic aggregates with average mobile diameter 43-93 nm consisting of partly sintered, crystalline primary particles with diameter 7.1-8.8 nm and specific surface area 184-229 m2/g. Pure zinc oxide yields compact, crystalline particles with diameter 25-40 nm and specific surface area 27-43 m2/g. The crystallite size for both oxides, estimated from the XRD line broadening, is comparable to or slightly smaller than the primary particle diameter. The specific surface area increases and the primary particle size decreases with a decreasing flame temperature and a decreasing precursor ...

2000-01-01

208

Preliminary study on zinc-air battery using zinc regeneration electrolysis with propanol oxidation as a counter electrode reaction  

Energy Technology Data Exchange (ETDEWEB)

A zinc-air battery using zinc regeneration electrolysis with propanol oxidation as a counter electrode reaction is reported in this paper. It possesses functions of both zincate reduction and electrochemical preparation, showing the potential for increasing the electronic energy utilization. Charge/discharge tests and scanning electron microscopy (SEM) micrographs reveal that when a nickel sheet plated with the high-H{sub 2}-overpotential metal, cadmium, was used as the negative substrate electrode, the dendritic formation and hydrogen evolution are suppressed effectively, and granular zinc deposits become larger but relatively dense with the increase of charge time. The performance of batteries is favorable even if the charge time is as long as 5 h at the current density of 20 mA cm{sup -2}. Better discharge performance is achieved using a 'cavity-opening' configuration for the discharge cell rather than ...

2009-03-01

209

Powering future vehicles with the refuelable zinc/air battery  

Energy Technology Data Exchange (ETDEWEB)

A recent road test at LLNL underscored the zinc/air battery`s capacity to give electric vehicles some of the attractive features of gas-driven cars: a 400-km range between refueling, 10-minute refueling, and highway-safe acceleration. Developed at Lawrence Livermore National Laboratory, the battery weights only one-sixth as much as standard lead/acid batteries and occupies one-third the space, yet costs less per mile to operate. What`s more, because the battery is easily refuelable, it promises trouble-free, nearly 24-hour-a-day operation for numerous kinds of electric vehicles, from forklifts to delivery vans and possibly, one day, personal automobiles. The test of a Santa Barbara Municipal Transit bus with a hybrid of zinc/air and lead/acid batteries capped a short development period for the zinc/air battery. The test run indicated the zinc/air battery`s potential savings in vehicle weight from 5.7 to ...

1995-10-01

210

Contaminant assimilation in newly created prairie wetlands  

Energy Technology Data Exchange (ETDEWEB)

Increased use of wetlands for habitat and water quality improvement emphasize the need for further study of abiotic-biotic interactions in these systems. This research examined contaminant assimilation within the water column of two newly created Colorado prairie wetlands (RMA3 and RMA4). To examine the influence of abiotic factors (e.g., alkalinity, suspended solids), ten chronic toxicity tests were performed from December 1991 through November 1993. In the first set of tests, Ceriodaphnia dubia were exposed to water from the two wetlands which was spiked with various concentrations of zinc. These tests suggested that water from RMA4 had higher contaminant assimilative capacity than water from RMA3. Preliminary analysis suggested suspended solids, pH, conductivity, and temperature were important factors affecting neonate production by C. dubia when exposed to zinc-spiked wetland water. To test the importance of suspended solids in contaminant ...

1994-12-31

211

Potential for energy production and use from biogas in Brazil; Potencial de aproveitamento energetico do biogas no Brasil  

Energy Technology Data Exchange (ETDEWEB)

Biogas, produced from anaerobic digestion of organic matter in domestic, industrial and rural wastewaters and residuals, represent an alternative and renewable source of energy, with growing use worldwide. In Brazil, high population and its spatial concentration and expressive agricultural and agricultural-industrial production indicate a substantial potential of biogas production. The results presented in this work show a potential of biogas production of almost 2 billion cubic feet a day of CH{sub 4}. Viability of biogas production and use depends substantially on project scale. Generally, biogas projects are viable from landfills and domestic wastewater treatment for populations higher than 50,000 inhabitants and swine and dairy farms with at least 5,000 and 1,000 animals, respectively. Biogas is also competitive when compared to fossil fuels used in industry and transport. Despite incentive mechanisms for biogas production and use, like ...

2009-12-15

212

Changes in aerobic digester performance with the use of methanol for biological nutrient removal in a full-scale sequencing batch reactor  

Energy Technology Data Exchange (ETDEWEB)

Increasingly, governments enact more stringent regulations governing nitrogen and phosphorus in the discharge effluent of wastewater treatment plants. Scientists know that nitrogen and phosphorus accelerates the eutrophication of lakes and reservoirs and stimulates algal growth. Ammonia has proven to be toxic to aquatic life forms, including fish. Engineers favour Biological Nutrient Removal (BNR) over chemical addition to wastewater treatment. Sequencing Batch Reactors (SBRs), a type of bioreactor requiring less land, provide the anaerobic, anoxic, and aerobic zones necessary for BNR. Methanol was used as an effective external source of carbon for denitrification but lacked research. The authors remedied this situation and some of the results were available. They indicated that the addition of methanol in the SBR increased solids production in the SBR, leading to increased sludge wasting to the aerobic digester. All aspects of the sludge ...

2000-07-01

213

Ceriodaphnia and Chironomus in situ toxicity tests assessing the wastewater treatment efficacy of constructed wetlands  

Energy Technology Data Exchange (ETDEWEB)

In situ toxicity tests were designed for Ceriodaphnia dubia and Chironomus tentans as part of a larger study designed to assess the effectiveness of constructed wetlands for the treatment of wastewater produced by oil production at Suncor OSG. The artificial wetlands were 50m long by 3m wide, with three replicates of the control and the treatment. Each wetland had four sample sites equidistant along its length, creating a gradient of treatment from site A being the most toxic to site D being the least toxic. Each test was conducted twice during the summer of 1994. Both the Ceriodaphnia and Chironomus test cages were a flow through design to allow for maximal exposure to the water within the wetlands. Mortality and reproduction were used as endpoints for Ceriodaphnia, whereas mortality and growth were used as endpoints for the Chironomus test. Test durations were fifteen and ten days respectively. Chironomus had very high mortality along the entire wetlands whereas ...

1995-12-31

214

Biosorption of heavy metals from wastewater by biosolids  

Energy Technology Data Exchange (ETDEWEB)

In a study where the removal of heavy metals from wastewater is the primary aim, the biosorption of heavy metals onto biosolids prepared as Pseudomonas aeruginosa immobilized onto granular activated carbon was investigated in batch and column systems. In the batch system, adsorption equilibriums of heavy metals were reached between 20 and 50 min, and the optimal dosage of biosolids was 0.3 g/L. The biosorption efficiencies were 84, 80, 79, 59 and 42 % for Cr(VI), Ni(II), Cu(II), Zn(II) and Cd(II) ions, respectively. The rate constants of biosorption and pore diffusion of heavy metals were 0.013-0.089 min{sup -1} and 0.026-0.690 min{sup -0.5}. In the column systems, the biosorption efficiencies for all heavy metals increased up to 81-100 %. The affinity of biosorption for various metal ions towards biosolids was decreased in the order: Cr = Ni > Cu > Zn > Cd. (Abstract Copyright [2006], Wiley Periodicals, Inc.)

2006-08-15

215

Air pollutants emissions from waste treatment and disposal facilities.  

Science.gov (United States)

This study examined the atmospheric pollution created by some waste treatment and disposal facilities in the State of Kuwait. Air monitoring was conducted in a municipal wastewater treatment plant, an industrial wastewater treatment plant established in a petroleum refinery, and at a landfill site used for disposal of solid wastes. Such plants were selected as models for waste treatment and disposal facilities in the Arabian Gulf region and elsewhere. Air measurements were made over a period of 6 months and included levels of gaseous emissions as well as concentrations of volatile organic compounds (VOCs). Samples of gas and bioaerosols were collected from ambient air surrounding the treatment facilities. The results obtained from this study have indicated the presence of VOCs and other gaseous pollutants such as methane, ammonia, and hydrogen sulphide in air surrounding the waste treatment and disposal facilities. In some cases the levels ...

2006-01-01

216

Advanced Flue Gas Desulfurization (AFGD) Demonstration Project, A DOE Assessment  

Science.gov (United States)

The AFGD process as demonstrated by Pure Air at the Bailly Station offers a reliable and cost-effective means of achieving a high degree of SO{sub 2} emissions reduction when burning high-sulfur coals. Many innovative features have been successfully incorporated in this process, and it is ready for widespread commercial use. The system uses a single-loop cocurrent scrubbing process with in-situ oxidation to produce wallboard-grade gypsum instead of wet sludge. A novel wastewater evaporation system minimizes effluents. The advanced scrubbing process uses a common absorber to serve multiple boilers, thereby saving on capital through economies of scale. Major results of the project are: (1) SO{sub 2} removal of over 94 percent was achieved over the three-year demonstration period, with a system availability exceeding 99.5 percent; (2) a large, single absorber handled the combined flue gas of boilers generating 528 MWe of power, and no spares were required; (3) direct ...

2001-08-31

217

Wetland treatment of oil and gas well wastewaters. Quarterly technical report, May 25, 1992---August 24, 1992  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this study is to extend the knowledge base for wetland treatment to include processes and substances of particular importance to small, on-site systems receiving oil and gas well waste water. Collection of data on the sorption of heavy metals and the degradation of toxic organics is one of the key tasks. The toxic organics phenolics and anthracene, and chromium and copper have been selected as target adsorbates. An information search was performed on oil refinery waste treatment wetland systems.

1995-11-01

218

Removal of uranium by biosorption  

Energy Technology Data Exchange (ETDEWEB)

The technology developed here will exploit the ability of microorganisms to remove dissolved metals from aqueous solutions. Microbial sorbents for uranium will be immobilized biosorbents will be deployed ex situ within flow-through reactors for the continuous or semicontinuous treatment of recovered wastewaters. The proposed technology will primarily be applied within a pump-and-treat process using immobilized biosorbents for the large-scale, long-term remediation of uranium-laden surface water or groundwater impoundments (environmental restoration). The technology may be equally useful as an ``end-of-pipe`` treatment of process effluents (waste management). Successful operation of this process will achieve immobilization of the targeted waste and accompanying volume reduction.

1993-06-01

219

FCE power plants for renewable biogas project in San Diego  

British Library Electronic Table of Contents (United Kingdom)

FuelCell Energy in Connecticut has sold 4.5 MW worth of power plants to California renewable energy company BioFuels Fuel Cells, part of New Energy Capital and BioFuels Energy. Three molten carbonate fuel cell power plants - a 2.8 MW DFC3000 unit, a 1.4 MW DFC1500 system, and a 300 kW DFC300 unit - will be installed at three locations in the San Diego area, and utilize purified biogas from the Point Loma wastewater treatment plant as their primary fuel source.

2010-01-01

220

Case studies of hazardous-waste treatment to remove volatile organics. Volume 2  

Energy Technology Data Exchange (ETDEWEB)

Case studies are presented for treatment of refinery wastes in a pilot-scale thin-film evaporator, the removal of volatiles from industrial wastewater for two steam strippers, and the removal of semivolatiles from water by steam stripping followed by liquid-phase carbon adsorption. The report provides data on removal efficiency, air emissions, process residuals, treatment costs, and process limitations. Details on sampling and analytical procedures, quality assurance, and process data are contained in the Appendixes (Volume II).

1987-11-01

221

Case studies of hazardous-waste treatment to remove volatile organics. Volume 1  

Energy Technology Data Exchange (ETDEWEB)

Case studies are presented for treatment of refinery wastes in a pilot-scale thin-film evaporator, the removal of volatiles from industrial wastewater for two steam strippers, and the removal of semivolatiles from water by steam stripping followed by liquid-phase carbon adsorption. The report provides data on removal efficiency, air emissions, process residuals, treatment costs, and process limitations. Details on sampling and analytical procedures, quality assurance, and process data are contained in the Appendixes (Volume II).

1987-11-01

222

Studies on the development of mossy zinc electrodeposits from flowing alkaline electrolytes  

Energy Technology Data Exchange (ETDEWEB)

The initiation and characteristics of mossy zinc electrodeposits have been investigated. Batteries with zinc electrodes are candidates for electric vehicle applications; however, this electrode is prone to form non-compact deposits that contribute to capacity loss and battery failure. Moss is deposited when the current density is far from the limiting current. This morphology first appears only after the bulk deposit is approximately 1 {mu}m thick. In this investigation, the effects of flow rate (Re=0--4000), current density (0--50 mA/cm{sup 2}), concentration of the electroactive species (0.25 and 0.5 M), and the concentration of supporting electrolyte (3, 6, and 12 M) on the initiation of moss were examined. The rotating concentric cylinder electrode was employed for most of the experiments; and a flow channel was used to study the development of morphology. After the experiment, the deposit was characterized using microscopic, x-ray ...

1991-07-01

223

Solar thermal production of zinc: Program strategy  

Energy Technology Data Exchange (ETDEWEB)

The solar thermal production of zinc is considered for the conversion of solar energy into storable and transportable chemical fuels. The ultimate objective is to develop a technically and economically viable technology that can produce solar zinc. The program strategy for achieving such a goal involves research on two paths: a direct path via the solar thermal splitting of ZnO in the absence of fossil fuels, and an indirect path via the solar carbothermal/CH{sub 4}-thermal reduction of Zn O, with fossil fuels (coke or natural gas) as chemical reducing agents. Both paths make use of concentrated solar energy for high-temperature process heat. The direct path brings us to the complete substitution of fossil fuels with solar fuels for a sustainable energy supply system. The indirect path creates a link between today`s fossil-fuel-based technology and tomorrow`s solar chemical technology and builds bridges between present and future energy ...

1999-08-01

224

Photocatalytic self-cleaning properties of cellulosic fibers modified by nano-sized zinc oxide  

International Nuclear Information System (INIS)

Nano-sized zinc oxide was synthesized and deposited onto cellulosic fibers using the sol-gel process at ambient temperature. The prepared materials were characterized using several techniques including scanning electron microscopy, transmission electron microscopy, diffuse reflectance spectroscopy, X-ray diffraction and thermogravimetric analysis. X-ray diffraction studies of the ZnO-coated fiber indicate formation of the hexagonal crystal phase which was satisfactory crystallized on the fiber surface. The electron micrographs show formation of zinc oxide nanoparticles within 10-15 nm in size which have been homogeneously dispersed on the fiber surface. The prepared materials show significant photocatalytic self-cleaning activity, which was monitored by diffuse reflectance spectroscopy. The photoactivity was studied upon measuring the photodegradation of methylene blue and eosin yellowish under UV-Vis irradiation. The photocatalytic activity of ...

2011-03-31

225

Noninvasive analysis of skin iron and zinc levels in beta-thalassemia major and intermedia  

Energy Technology Data Exchange (ETDEWEB)

Diagnostic x-ray spectrometry, a method based on x-ray fluorescence analysis, was used for noninvasive determination of iron and zinc in two distinct skin areas, representing predominantly dermal and epidermal tissues, in 56 patients with beta-thalassemia major and intermedia. The mean iron levels in the skin of patients with beta-thalassemia major and intermedia were elevated by greater than 200% and greater than 50%, respectively, compared with control values. The zinc levels of both skin areas examined were within the normal range. The data indicate that the rate and number of blood transfusions, which correlated well with serum ferritin levels (r . 0.8), are not the only factors that determine the amount of iron deposition in the skin (r less than 0.6). Other sources of iron intake contribute to the total iron load in the tissues, particularly in patients who are not given multiple transfusions. The noninvasive quantitation of skin levels ...

1985-01-01

226

Isotope - aided studies of the bioavailability of iron and zinc from human diets consumed in Poland  

International Nuclear Information System (INIS)

The main aims of the study were: 1) the evaluation of iron and zinc status in women of Lodz aged 18-45 years, 2) adaptation of the whole body counter to in vivo measurements absorption of iron given to the gastro-intestinal tract of volunteers and 3) in rat model estimation iron bioavailability from fortified wheat flour combined with products usually consumed in Poland. During five months investigations thirty seven women were examined each one twice in two months interval. Following variables were measured: iron and zinc in blood serum, in public and scalp hair and in food, taste acuity score, serum ferritin, hemoglobin, total iron binding capacity, red blood cells, mean corpuscular concentration and corpuscular volume. Prevalence of iron deficiency and iron deficient anemia were assessed by two models in terms of the depression of serum ferritin and hemoglobin concentrations. 64 refs, 6 figs, 23 tabs.

227

Extraction of copper-, nickel-, zinc- and cadmium complexes with 4-(2-pyridilazo)-resorcin and 2-aminopyridine  

International Nuclear Information System (INIS)

Extraction of copper-, nickel-, zinc- and cadmium complexes with 4-(2 pyridilazo)-resorcin (PAR) is studied in the presence of 2-aminopyridine (Am). Maximum optical densities of the extracts are attained at pH=7.5-8.0; 6.0-7.0; 6.5-7.0 and 7.0-8.0, respectively. The ratio of components in the complexes extractable by chloroform was defined by the method of isomolar series and equilibrium shift. It is established that nickel and copper are extracted to the organic phase as the NiAm(PAR)_2 and CuAmPAR complexes, and, in the case of zinc and cadmium, complexes of different composition are extracted, for example Zn(Am)_2PAR and ZnAm(PAR)_2. The light absorption spectra are studied and molar extinction coefficients of complex extracts are determined at lambdasub(max). It is shown that the general low of light absorption is observed within a sufficiently wide range of concentrations for all the elements.

1984-01-01

228

Economic evaluation of the solar thermal co-production of zinc, synthesis gas, and hydrogen  

Energy Technology Data Exchange (ETDEWEB)

The use of concentrated solar energy for co-producing Zn and synthesis gas from Zn O and natural gas upgrades the calorific value of the initial reactants by 39% and, when compared to the traditional carbothermic reduction of Zn O, has the potential of reducing CO{sub 2} emissions by up to 78%. An economic assessment for an industrial thermochemical plant, 30 to 51 MW solar input, indicates that the cost of solar production of zinc ranges between 89-133 $/t (excluding the cost of Zn O feed and credit for pollution abatement), and thus might be competitive with conventional fossil-fuel-based processes at current fuel prices. The cost of solar H{sub 2}, produced by splitting water with zinc, is estimated to be in the range 0.10-0.14 $/kWh, and it is a favorable long term prospect once the cost of energy will account for the environmental externalities from fossil fuel burning such as the costs for CO{sub 2} mitigation and pollution abatement. ...

1999-08-01

229

Coaxial nanocables of p-type zinc telluride nanowires sheathed with silicon oxide: synthesis, characterization and properties  

International Nuclear Information System (INIS)

Coaxial nanocables with a single-crystalline zinc telluride (ZnTe) nanowire core and an amorphous silicon oxide (SiO_x) shell have been synthesized via a simple one-step chemical vapor deposition (CVD) method on gold-decorated silicon substrates. The single-crystal ZnTe nanowire core is in zinc-blende structure along the [111] direction, while the uniform SiO_x shell fully covers the core with no observable pin-hole or crack. Formation mechanisms of the ZnTe-SiO_x nanocables are discussed. The ZnTe nanowire core shows p-type electrical properties while the SiO_x shell acts as an effective insulating layer. The ZnTe-SiO_x nanocables may have potential applications in nanoscale devices, such as p-type FETs and nanosensors.

2009-11-11

230

Two Proline-Rich Nuclear Localization Signals in the Amino- and Carboxyl-Terminal Regions of the Borna Disease Virus Phosphoprotein  

UK PubMed Central (United Kingdom)

Borna disease virus (BDV) uses a unique strategy of replication and transcription which takes place in the nucleus, unlike other known, nonsegmented, negative-stranded RNA viruses of animal origin....Full Text Available

1998-12-01

231

Transcriptome Profiling of a Toxic Dinoflagellate Reveals a Gene-Rich Protist and a Potential Impact on Gene Expression Due to Bacterial Presence  

UK PubMed Central (United Kingdom)

BackgroundDinoflagellates are unicellular, often photosynthetic protists that play a major role in the dynamics of the Earth's oceans and climate. Sequencing of dinoflagellate nuclear...Full Text Available

232

Three-dimensional culture models of mammary gland  

UK PubMed Central (United Kingdom)

The mammary gland is a complex tissue comprised of a branching network of ducts embedded within an adipocyte-rich stroma. The ductal epithelium is a bi-layer of luminal and myoepithelial cells, the...Full Text Available

2009-04-01

233

The missing graphical user interface for genomics  

UK PubMed Central (United Kingdom)

AbstractThe Galaxy package empowers regular users to perform rich DNA sequence analysis through a much-needed and user-friendly graphical web interface.See research article...Full Text Available

2010-01-01

234

The Surface Water and Ocean Topography (SWOT) - NASA  

Science.gov (United States)

The ratio of particle velocity to translation speed exceeds 1 for 98% of .... The westward movement of the meandering jet and eddy system transports nutrient- rich ...... J. Hydrometeor., 4, 1044-1066. Gedney, N., P. M. Cox, H. Douville, ...

235

Technical approaches for mouse models of human disease  

UK PubMed Central (United Kingdom)

The mouse is the leading organism for disease research. A rich resource of genetic variation occurs naturally in inbred and special strains owing to spontaneous mutations. However, one can also obtain...Full Text Available

2011-05-01

236

Relative potencies for barbiturate binding to the Torpedo acetylcholine receptor.  

UK PubMed Central (United Kingdom)

1. The structural requirements of an allosteric barbiturate binding site on acetylcholine receptor-rich membranes isolated from Torpedo electroplaques have been characterized by the ability of fourteen...Full Text Available

1990-11-01

237

Regression of atherosclerotic lesions by high density lipoprotein plasma fraction in the cholesterol-fed rabbit.  

UK PubMed Central (United Kingdom)

The effects of homologous plasma HDL and VHDL fractions on established atherosclerotic lesions were studied in cholesterol-fed rabbits. Atherosclerosis was induced by feeding the animals a 0.5% cholesterol-rich...Full Text Available

1990-04-01

238

Pharmacology and toxicology of pahayokolide A, a bioactive metabolite from a freshwater species of Lyngbya isolated from the Florida Everglades  

UK PubMed Central (United Kingdom)

The genus of filamentous cyanobacteria, Lyngbya, has been found to be a rich source of bioactive metabolites. However, identification of such compounds from Lyngbya...Full Text Available

2004-12-01

239

Oettinger pushes for stress tests of Europe'  

Wastenet

... Austrian Environment Minister Nikolaus Berlakovich called for such stress tests on Sunday (13 March) to make sure that nuclear power stations were quake-proof following Japan's massive earthquake and tsunami. Austria, a mountainous country rich in geothermal energy, has no NPPs and no plans to develop ...

240

Nuclear data sheets update for A = 101  

Science.gov (United States)

The 1985 evaluation of A = 1-1 (85B1114) has been revised. Experimental information is presented from the neutron-rich {sup 101}Sr to the neutron-deficient {sup 101}In.

1991-06-01

241

Nuclear data sheets update for A = 101  

International Nuclear Information System (INIS)

The 1985 evaluation of A = 1-1 (85B1114) has been revised. Experimental information is presented from the neutron-rich "1"0"1Sr to the neutron-deficient "1"0"1In.

242

Neutron star collisions and the r-process  

Energy Technology Data Exchange (ETDEWEB)

It is shown that a natural consequence of the binary pulsar's evolution is a neutron star collision. Such a collision is expected to eject neutron-rich matter of an r-process character. Taking reasonable estimates for the number of such events over the history of the galaxy, it may be that they account for all of the r-process nuclei.

1982-01-01

243

Inelastic x-ray scattering of dense solid oxygen: Evidence for intermolecular bonding  

UK PubMed Central (United Kingdom)

The detailing of the intermolecular interactions in dense solid oxygen is essential for an understanding of the rich polymorphism and remarkable properties of this element at high pressure. Synchrotron...Full Text Available

2008-08-19

244

If I Had - Signs of Aging Skin  

Medline Plus

... also include a healthy diet that included abundant antioxidants, such as vitamin C, vitamin E, and lycopene. ... exfoliants, the higher-level moisturizers as well as antioxidants as my night product. A very rich moisturizer ...

245

High-energy reaction cross sections of light nuclei  

Energy Technology Data Exchange (ETDEWEB)

The high-energy reaction cross sections of Li and Be isotopes are calculated using a simplified Glauber model and densities constrained by the empirical binding energies. We find excellent agreement with experiment, reproducing the large increase for the most neutron-rich nuclei.

1989-03-01

246

Gaseous fuels and other alternative fuels  

Energy Technology Data Exchange (ETDEWEB)

This book contains papers relating to the 1990 Future Transportation Technology Conference and Exposition. Included are the following papers; Examination of rich mixtures operation of a dual fuel engine, A hybrid natural gas vehicles, Performance analysis of a spark ignited engine with ETBE as a blending agent.

1990-01-01

247

Evaluation of Two Homologous Proline-Rich Proteins of Coccidioides posadasii as Candidate Vaccines against Coccidioidomycosis?  

UK PubMed Central (United Kingdom)

Evaluation of the protective efficacy of recombinant T-cell-reactive proteins of Coccidioides posadasii in a murine model of coccidioidomycosis has led to the discovery of potential...Full Text Available

2007-12-01

248

Effect of rich and high turbulence combustion on emissions and flame behavior in a direct-injection diesel engine; Chokusetsu funshashiki diesel kikan ni okeru haki tokusei to kaen kyodo ni oyobosu kano koranryu nensho no eikyo  

Energy Technology Data Exchange (ETDEWEB)

This study tried to reduce NO{sub x} and particulate emissions simultaneously in a high speed direct-injection diesel engine. Fuel-rich combustion was used to reduce NO{sub x} emission at initial combustion stage and high turbulence combustion was used to reduce particulate emission at diffusion combustion stage. Experiments were carried out to investigate the effects of high squish combustion chambers with small throat on combustion process and exhaust emissions. Results showed that in the high squish combustion chamber, both NO{sub x} and particulate emissions reduced with retarded injection timing. Endoscopic high speed photography was employed to analyze experimental results. In the original combustion chamber at the early combustion stage, the high luminosity flame tended to spread out of the cavity. Fuel-rich mixture burned slowly over the piston crown. In the high squish combustion chamber, flame rotated violently around the bowl. ...

1999-09-25

249

Corrosion of high-level waste packaging materials in disposal relevant brines  

International Nuclear Information System (INIS)

Previous corrosion studies identified the materials Hastelloy C4, Ti 99.8-Pd, and carbon steels as promising for the manufacture of long-lived high-level waste containers that could act as an engineered barrier in a rock-salt repository. Here, the efficiency of the corrosion-resistant concept using surface-welded Hastelloy C4 as corrosion protection of carbon steel containers is compared with the corrosion-allowance concept using unalloyed or low-alloyed steels. The materials are examined in three disposal relevant brines (two rich in MgCl_2, one rich in NaCl) at 150 C. The results indicate that welded Hastelloy C4 is highly resistant to corrosion in the NaCl-rich brine. In the presence of sulfides or MgCl_2-rich brines, however, severe pitting corrosion occurs. The three steels investigated are resistant to pitting corrosion in all brines, and their general corrosion rates imply corrosion allowances ...

250

Complete tree utilization of a fast growing species - eucalyptus hybrid  

Energy Technology Data Exchange (ETDEWEB)

Potential uses of foliage and bark wastes of E. ('Mysore') hybrid in southern India for the production of cineole and oxalic acid respectively are discussed. Only certain strains are cineole-rich and these are being successfully propagated vegetatively at the authors' laboratory.

1981-01-01

251

Collisions with ice-volatile objects: Geological implications  

International Nuclear Information System (INIS)

The collision of the Earth with extra-terrestrial ice-volatile bodies is proposed as a mechanism to produce rapid changes in the geologic record. These bodies would be analogs of the ice satellites found for the Jovian planets and suspected for comets and certain low density bodies in the Asteroid belt. Five generic end-members are postulated: (1) water ice; (2) dry ice: carbon-carbon dioxide rich, (3) oceanic (chloride) ice; (4) sulfur-rich ice; (5) ammonia hydrate-rich ice; and (6) clathrate: methane-rich ice. Due to the volatile nature of these bodies, evidence for their impact with the Earth would be subtle and probably best reflected geochemically or in the fossil record. Actual boloids impacting the Earth may have a variable composition, generally some admixture with water ice. However for discussion purposes, only the effects of a dominant component will be treated. The general geological effects ...

1988-10-20

252

Characterization of Two Unique Cholesterol-Rich Lipid Particles Isolated from Human Atherosclerotic Lesions  

UK PubMed Central (United Kingdom)

The authors' laboratory, using histochemicalmethods, previously identified two types of cholesterol-containing lipid particles in the extracellular spaces of human atherosclerotic lesions, one particle...Full Text Available

1990-01-01

253

Cathepsin B facilitates Autophagy mediated apoptosis in SPARC Overexpressed Primitive Neuroectodermal Tumor cells  

UK PubMed Central (United Kingdom)

Medulloblastoma and neuroblastoma belong to a group of neoplasms designated as primitive neuroectodermal tumors (PNETs). Secreted Protein, Acidic and Rich in Cysteine (SPARC) is a matrix-associated...Full Text Available

2010-10-01

254

Animal Models in Carotenoids Research and Lung Cancer Prevention1  

UK PubMed Central (United Kingdom)

Numerous epidemiological studies have consistently demonstrated that individuals who eat more fruits and vegetables (which are rich in carotenoids) and who have higher serum β-carotene levels...Full Text Available

255

Absorption and diffusion of hydrogen in palladium-silver alloys by density functional theory  

Science.gov (United States)

The vibrational states, absorption energies, and diffusions of H in Pd and Pd1-xAgx(0Pd-Ag alloys should avoid the Ag-rich areas.

2002-11-01

256

Trivalent chromium removal from wastewater using low cost activated carbon derived from agricultural waste material and activated carbon fabric cloth  

International Nuclear Information System (INIS)

An efficient adsorption process is developed for the decontamination of trivalent chromium from tannery effluents. A low cost activated carbon (ATFAC) was prepared from coconut shell fibers (an agricultural waste), characterized and utilized for Cr(III) removal from water/wastewater. A commercially available activated carbon fabric cloth (ACF) was also studied for comparative evaluation. All the equilibrium and kinetic studies were conducted at different temperatures, particle size, pHs, and adsorbent doses in batch mode. The Langmuir and Freundlich isotherm models were applied. The Langmuir model best fit the equilibrium isotherm data. The maximum adsorption capacities of ATFAC and ACF at 25 deg. C are 12.2 and 39.56 mg/g, respectively. Cr(III) adsorption increased with an increase in temperature (10 deg. C: ATFAC-10.97 mg/g, ACF-36.05 mg/g; 40 deg. C: ATFAC-16.10 mg/g, ACF-40.29 mg/g). The kinetic studies were conducted to delineate the effect of temperature, ...

2006-07-31

257

Temperature effects on wastewater nitrate removal in laboratory-scale constructed wetlands  

Energy Technology Data Exchange (ETDEWEB)

Constructed wetlands may be used for removal of high nutrient loads in greenhouse wastewater prior to discharge into the environment. Temperature affects both the physical and biological activities in wetland systems. Since nitrification and denitrification are temperature-dependent processes, effluent nitrate concentrations will fluctuate due to changes in air and wetland temperature. In a cold climate, constructed wetlands can function in a temperature-controlled, greenhouse environment year-round. This work evaluates four temperature treatments on nitrate removal rates in five planted and five unplanted laboratory-scale wetlands. Wetlands were supplied with a nutrient solution similar to the fertigation runoff solution (100 PPM nitrate-N) used in greenhouse crop production. A first-order kinetic model was used to describe experimental nitrate depletion data and to predict nitrate removal rate constants (k) in the wetlands planted with Iris pseudocoras. The ...

1999-02-01

258

Enhanced biosorption of nickel(II) ions by silica-gel-immobilized waste biomass: Biosorption characteristics in batch and dynamic flow mode  

Energy Technology Data Exchange (ETDEWEB)

Batch and dynamic flow biosorption studies were carried out using the waste biomass entrapped in silica-gel matrix for the removal of nickel(II) ions from synthetic solutions and real wastewater. Batch biosorption conditions were examined with respect to initial pH, S/L ratio, contact time, and initial nickel ion concentration. Zeta potential measurements showed that immobilized biosorbent was negatively charged in the pH range of 3.0-8.0. The immobilized biomass was found to possess relatively high biosorption capacity (98.01 mg g{sup -1}), and biosorption equilibrium was established in a short time of operation (5 min). The equilibrium data were followed by Langmuir, Freundlich, and Dubinin-Radushkevich isotherm models. Scanning electron microscope analysis was used to screen the changes on the surface structure of the waste biomass after immobilization and nickel(II) biosorption. Sorbent-sorbate interactions were confirmed by Fourier transform infrared ...

2009-04-30

259

Effect of hydraulic retention time on the biodegradation of complex phenolic mixture from simulated coal wastewater in hybrid UASB reactors  

International Nuclear Information System (INIS)

This study describes the feasibility of anaerobic treatment of complex phenolics mixture from a simulated synthetic coal wastewater using four identical 13.5 L (effective volume) bench scale hybrid up-flow anaerobic sludge blanket (HUASB) (combining UASB + anaerobic filter) reactors at four different hydraulic retention times (HRT) under mesophilic (27 #+-# 5 "oC) conditions. Synthetic coal wastewater with an average chemical oxygen demand (COD) of 2240 mg/L and phenolics concentration of 752 mg/L was used as substrate. The phenolics contained phenol (490 mg/L); m-, o-, p-cresols (123.0, 58.6, 42 mg/L); 2,4-, 2,5-, 3,4- and 3,5-dimethyl phenols (6.3, 6.3, 4.4 and 21.3 mg/L) as major phenolic compounds. The study demonstrated that at optimum HRT, 24 h, and phenolic loading rate of 0.75 g COD/(m"3-d), the phenolics and COD removal efficiency of the reactors were 96% and 86%, respectively. Bio-kinetic models were applied to data obtained from ...

2008-05-01

260

{Beta} decay and isomeric properties of neutron-rich Ca and Sc isotopes.  

Energy Technology Data Exchange (ETDEWEB)

The isomeric and {beta}-decay properties of neutron-rich {sup 53-57}Sc and {sup 53,54}Ca nuclei near neutron number N = 32 are reported, and the low-energy level schemes of {sup 53,54,56}Sc and {sup 53-57}Ti are presented. The low-energy level structures of the {sub 21}Sc isotopes are discussed in terms of the coupling of the valence 1f{sub 7/2} proton to states in the corresponding {sub 20}Ca cores. Implications with respect to the robustness of the N = 32 subshell closure are discussed, as well as the repercussions for a possible N = 34 subshell closure.

2010-07-21

261

Spectroscopy of neutron-rich Fe isotopes populated in the "6"4Ni+"2"3"8U reaction  

International Nuclear Information System (INIS)

The neutron-rich Fe isotopes from A=61 to 66 were studied through multinucleon transfer reactions by bombarding a "2"3"8U target with a 400 MeV "6"4Ni beam. Unambiguous identification of prompt #gamma# rays belonging to each nucleus was achieved using coincidence relationships with the ions detected in a high-acceptance magnetic spectrometer. The new data extend our knowledge of the level structure of Fe isotopes, which is discussed in terms of the systematics of the region and compared with large-scale shell-model calculations.

2007-09-01

262

Effect of yttrium on mechanical properties of 9Cr-2WVTa low active martensite steel  

International Nuclear Information System (INIS)

The effect of the rare earth element, yttrium, on the mechanical properties of 9Cr-2WVTa low active martensite steel for fusion reactor was studied and the metallurgical behavior of yttrium in the steel was primarily analyzed. The results show that it is easy for yttrium to aggregate and form the blocky yttrium rich inclusions in the steel, which can dissever the continuity of the matrix and produce micro-cracks for fracture. The yttrium rich inclusions were distributed along the rolling direction, which made the fracture surface delaminated in the tensile and impact samples, and reduced the mechanical properties of the steel. (authors)

2009-03-01

263

Collectivity at N=40 in neutron-rich "6"4Cr  

International Nuclear Information System (INIS)

"9Be-induced inelastic scattering of "6"2","6"4","6"6Fe and "6"0","6"2","6"4Cr was performed at intermediate beam energies. Excited states in "6"4Cr were measured for the first time. Energies and population patterns of excited states in these neutron-rich Fe and Cr nuclei are compared and interpreted in the framework of large-scale shell-model calculations in different model spaces. Evidence for increased collectivity and for distinct structural changes between the neighboring Fe and Cr isotopic chains near N=40 is presented.

2010-05-01

264

Beta-decay half-lives of new neutron-rich chromium-to-nickel isotopes and their consequences for the astrophysical r-process  

International Nuclear Information System (INIS)

Beta-decay studies of the new neutron-rich isotopes sup(58,59)Cr, "6"3Mn, sup(66,67)Co and "6"9Ni, yielding distinctly shorter half-lives than the corresponding theoretical predictions, are presented. The influence of the short half-lives on the r-process calculations of nuclear abundances is discussed. It is concluded that a significantly higher neutron density than the one obtained from explosive helium burning in supernovae is needed to reproduce the observed abundances around A = 80. (orig.).

265

? decay and isomeric properties of neutron-rich Ca and Sc isotopes  

International Nuclear Information System (INIS)

The isomeric and ?-decay properties of neutron-rich 53-57Sc and 53,54Ca nuclei near neutron number N=32 are reported, and the low-energy level schemes of 53,54,56Sc and 53-57Ti are presented. The low-energy level structures of the 21Sc isotopes are discussed in terms of the coupling of the valence 1f7/2 proton to states in the corresponding 20Ca cores. Implications with respect to the robustness of the N=32 subshell closure are discussed, as well as the repercussions for a possible N=34 subshell closure.

2010-07-01

266

The elevation of blood levels of zinc protoporphyrin in mice following whole body irradiation  

Energy Technology Data Exchange (ETDEWEB)

Elevation of zinc protoporphyrin (ZPP) levels in the blood has served as an indicator of lead poisoning and iron deficiency anemia for many years. We have discovered that sublethal doses of whole body irradiation with x-rays also elevates ZPP 2-3-fold over normal levels. The ZPP level does not begin to increase until days 12-14 postirradiation and peaks between days 18 and 20 before returning to normal levels between days 28 and 35. Increasing the radiation dose delays the onset of the rise in ZPP, but does not affect the magnitude of the elevation. At lethal doses, ZPP elevation is not observed. Neither of the two previously described mechanisms that cause elevations of ZPP, namely iron deficiency and inhibition of ferrochelatase, are responsible for the radiation-induced elevation of ZPP. The elevation of ZPP appears to be correlated with the recovery of the hematopoietic system from radiation injury.

1984-05-01

267

Study of interaction between 7-(6-Br-2-benzthiazolylazo)-8-oxiquinoline-5-sulfonic acid and uranium (6), zinc (2) and manganese (2)  

International Nuclear Information System (INIS)

A new reagent 7-(6-Br-2-henzthiazolilazo)-8-oxyquinoline-5-sulphoacid has been studied spectrophotometrically. Dissociation constants have been determined in 50% acetone (pK_1=2.5 and pK_2=5.9) and 50% dioxane (pK_1=1.7 and pK_2=6.1) as well as molar extinction coefficients of the reagent dissociated form in the same solvents (71.1.10"3 and 72.4.10"3). The conditions have been studied of complexing the reagent with ions of uranium (6), zinc (2), and manganese (2) in 50% dioxane (pH 2.5-4.5) and the properties of the formed complexes.

1977-01-01

268

Structural, optical, photocatalytic and antibacterial activity of zinc oxide and manganese doped zinc oxide nanoparticles  

British Library Electronic Table of Contents (United Kingdom)

Polycrystalline ZnO doped with Mn (5 and 10at%) was prepared by the co-precipitation method. The effect of Mn doping on the photocatalytic, antibacterial activities and the influence of doping concentration on structural, optical properties of nanoparticles were studied. Structural and optical properties of the particles elucidated that the Mn2+ ions have substituted the Zn2+ ions without changing the Wurtzite structure of ZnO. The optical spectra showed a blue shift in the absorbance spectrum with increasing dopant concentration. The photocatalytic activities of ZnO powders were evaluated by measuring the degradation of methylene blue (MB) in water under the UV region. It was found that undoped ZnO bleaches MB much faster than manganese doped ZnO upon its exposure to the U...

2010-01-01

269

Restauration of the Clinton site; Restauration du site Clinton  

Energy Technology Data Exchange (ETDEWEB)

Mining of copper and zinc took place at the Clinton Mine located in the Estrie region of Quebec between 1973 and 1975, during which time 115,000 tons of mineral were treated at the Solbec plant. In this poster presentation, the authors provided the background information pertaining to this mine and described the state in which it was in 1994. The pit was covered with good quality water, with a pH of 7,1 and copper and zinc content ranging between 0,1 and 0,6 mg/l, and iron ranging between 0,2 and 1,8 mg/l. The tailings basin drainage was found to have a pH of between 3,6 and 6,1. A program for the characterization of the site was implemented and the concept for the restauration of the Clinton site was developed and implemented. The work carried out at the site is discussed during this presentation as well as the monitoring taking place. 27 figs.

2000-07-01

270

Production of {sup 62}Zn, {sup 65}Zn and {sup 203}Pb radioisotopes for studying the transport of zinc and lead in plants  

Energy Technology Data Exchange (ETDEWEB)

In the Carpathian Basin, significant percentage of watershed area and floodplains of rivers are utilised agriculturally. Several potential sources of poisonous metal pollution have been identified in these areas. Because of spills from some of them a few severe accidents have happened especially in the watershed area of Tisza River during the last decades. The motivation of our present work was to produce {sup 62,65}Zn and {sup 203}Pb radioisotopes because they can be used especially as tracers for studying the kinetics of uptake, transport and accumulation of zinc and lead by plants under different circumstances. (orig.)

2004-07-01

271

Production of "6"2Zn, "6"5Zn and "2"0"3Pb radioisotopes for studying the transport of zinc and lead in plants  

International Nuclear Information System (INIS)

In the Carpathian Basin, significant percentage of watershed area and floodplains of rivers are utilised agriculturally. Several potential sources of poisonous metal pollution have been identified in these areas. Because of spills from some of them a few severe accidents have happened especially in the watershed area of Tisza River during the last decades. The motivation of our present work was to produce "6"2","6"5Zn and "2"0"3Pb radioisotopes because they can be used especially as tracers for studying the kinetics of uptake, transport and accumulation of zinc and lead by plants under different circumstances. (orig.)

272

Oxygen reduction reaction on electrodeposited zinc oxide electrodes in KCl solution at 70 deg. C  

Energy Technology Data Exchange (ETDEWEB)

The reduction of oxygen was studied in 0.1 M KCl at 70 deg. C using the rotating disk electrode (RDE) technique on platinum and electrodeposited ZnO thin film electrodes deposited on platinum substrates. In the absence of Zn{sup 2+} ions in solution, a Tafel slope of 139 mV dec{sup -1} was obtained, a value close to that measured on bare platinum electrode (133 mV dec{sup -1}) and ascribed to the limitation of the reaction rate by the first electron transfer. The main difference between the noble metal and the oxide electrode was a shift of the curves towards more negative potentials. In the presence of Zn{sup 2+} ions, the current density decreased significantly and the Tafel slope was measured at 282 mV dec{sup -1} showing that the electrode was partially blocked by zinc oxide formation reaction intermediates.

2006-04-01

273

Lipid-soluble metal compounds in a coal gasifier process stream  

Energy Technology Data Exchange (ETDEWEB)

The concentrations of iron, chromium, zinc, and aluminum were measured by atomic absorption spectroscopy in the lipid-soluble fractions of tar from the process stream of an experimental coal gasifier as part of large study on the health risks of coal gasification. Lipid solubility was inferred from octanol/water-partitioning and benzene-solubility tests. The properties of the lipid-soluble metals were compared to reference compounds by Sephadex LH-20 chromatography. The ability of the lipid-soluble metals to remain lipid soluble after treatment with acid and base was also tested. Lipid-soluble iron, chromium, zinc, and aluminum were present at 360, 12, 3, and 1 ppM, respectively, in the gasifier coal tar. The presence of these metals in lipid-soluble form may have important consequences relative to the potential toxicity of the tar if persons are exposed to it.

1982-08-01

274

Leaching of zinc sulfide by Thiobacillus ferrooxidans: Bacterial oxidation of the sulfur product layer increases the rate of zinc sulfide dissolution at high concentrations of ferrous ions  

Energy Technology Data Exchange (ETDEWEB)

This paper reports the results of leaching experiments conducted with and without Thiobacillus ferroxidans at the same conditions in solution. The extent of leaching of ZnS with Bacteria is significantly higher than that without bacteria at high concentrations of ferrous ions. A porous layer of elemental sulfur is present on the surfaces of the chemically leached particles, which no sulfur is present on the surfaces of the bacterially leached particles. The analysis of the data using the shrinking-core model shows that the chemical leaching of ZnS is limited by the diffusion of ferrous ions through the sulfur product layer at high concentrations of ferrous ions. The analysis of the data shows that diffusion through the product layer does not limit the rate of dissolution when bacteria are present. This suggests that the action of T.ferroxidans in oxidizing the sulfur formed on the particle surface is to remove the barrier to diffusion by ferrous ions.

1999-12-01

275

Full size zinc-air battery  

Energy Technology Data Exchange (ETDEWEB)

The Electric Fuel zinc-air battery yielded energy densities from 6.8 to 10.2 times higher than those of the lead-acid batteries. The higher the power and the more difficult the driving cycle, the higher this ratio of energy densities grew. Not only was the Electric Fuel battery capable of extended high-power discharge, the impact of such discharge conditions on energy and driving range was show to be quite small, and was much smaller than the comparable impact on lead-acid traction batteries. At the time of writing this paper, tests are scheduled to continue with the 110-kWh battery in the Mercedes van, and preliminary plans have been made for testing of additional batteries on other vehicle types.

1993-11-01

276

Full potential linearized augmented plane wave calculations of positronic and electronic charge densities of zinc-blende AlN, InN and their alloy Al_0_._5In_0_._5N  

International Nuclear Information System (INIS)

A theoretical study of electron and positron band structures of zinc-blende AlN and InN and their alloy Al_0_._5In_0_._5N is presented using the first-principles full-potential linearized augmented plane-wave method. Equilibrium lattices constants are determined from the total-energy minimization method. The results are compared with previous calculations and with experimental measurement. Electron and positron charge densities are computed as function of position in the unit cell. Detailed plots of distributions are along the direction. The ionicity factors are calculated by means of three different approaches. The calculated results of the positron charge density reflect the high insight for the annihilation effect.

2005-06-01

277

Determination of some minor and trace elements in iron ores by ion exchange chromatography, spectrophotometry and atomic absorption spectrometry  

International Nuclear Information System (INIS)

A method is described for determination of aluminium, cadmium, cobalt, chromium, copper, calcium, magnesium, sodium, potassium, manganese, nickel, lead, strontium, zinc, titanium and vanadium in iron ore. After dissolution, a 1 gram sample of iron ore is applied to a column of AGI-X8 anion exchange resin (chloride form), in 100 ml of 7M HCl. Aluminium, chromium, calcium, magnesium, sodium, potassium, manganese, nickel, lead, strontium, titanium and vanadium are eluted with 7M HCl; iron, copper and cobalt are eluted with 0.5M HCl; cadmium and zinc are eluted with 2M HNO_3. Iron is subsequently removed from copper and cobalt by a solvent extraction with methyl isobutyl ketone. The elements are determined in the eluates by atomic absorption spectrometry, except for titanium and vanadium, which are determined spectrophotometrically.

278

Demonstration of zinc/air fuel battery to enhance the range and mission of fleet electric vehicles: Preliminary results in the refueling of a multicell module  

Energy Technology Data Exchange (ETDEWEB)

We report progress in an effort to develop and demonstrate a refuelable zinc/air battery for fleet electric vehicle applications. A refuelable module consisting of twelve bipolar cells with internal flow system has been refueled at rates of nearly 4 cells per minute refueling time of 10 minutes for a 15 kW, 55 kWh battery. The module is refueled by entrainment of 0.5-mm particles in rapidly flowing electrolyte, which delivers the particles into hoppers above each cell in a parallel-flow hydraulic circuit. The concept of user-recovery is presented as an alternative to centralized service infrastructure during market entry.

1994-08-08

279

Core testing of zinc/air refuelable battery modules  

Energy Technology Data Exchange (ETDEWEB)

We are developing a refuelable zinc/air battery (6-cells) for evaluation under the five USABC `core` test protocols. In the first half of the two year project ($1OOK, FY1997), an advanced refuelable design was developed, fabricated and tested at power levels up to 415 W. Performance matched or exceeded that of earlier multicell systems. A computer program was developed for automated data acquisition and drive cycle simulation. Small mockup cells (80 cm 2) were constructed for rapid testing of components. In the follow-on effort (FY1998, $1OOK) we will make minor advances in system design and fabrication efficiency, and seek to improve cathode performance and life, before delivery of two final units for test at DOE laboratory.

1998-08-20

280

Co-ordinated research programme on isotope-aided studies of the bioavailability of iron and zinc from human diets. Report of the second research co-ordination meeting, Hyderabad, India, 16-20 November 1992  

International Nuclear Information System (INIS)

The Co-ordinated Research Programme (CRP) on ''Isotope-Aided Studies on the Bioavailability of Iron and Zinc from Human Diets'' was initiated by the IAEA in 1990, and presently encompasses participating institutes in 11 countries. A summary of the discussions that took place during thr second Research Co-ordination Meeting held in Hyderabad, India, between 16-20 November 1992, is given in this report together with 12 working papers (progress reports) presented by individual participants. A separate abstract was prepared for each of these papers. Refs, figs and tabs.

1992-11-16

281

Biosorption of Zn(II) by Thiobacillus ferrooxidans  

Energy Technology Data Exchange (ETDEWEB)

There have been a number of studies considering the possibility of removing and recovering heavy metals from diluted solutions. These are due, principally, because of the commercial value of some metals as well as in the environmental impact caused by them. The traditional methods for removing have several disadvantages when metals are present in concentrations lower than 100 mg/l. Biosorption, which uses biological materials as adsorbents, has been considered as an alternative method. In this work, variables like pH and biomass chemical pretreatment have been studied for its effect on the capacity for zinc biosorption by Thiobacillus ferrooxidans. Also, studies to determinate the time for zinc adsorption were carried out. Results indicate that a capacity as high as 82.61 mg of Zn(II)/g of dry biomass can be obtained at a temperature of 25 C and that the biosorption process occurs in a time of 30 min. (orig.)

2000-06-01

282

Ag/C nanoparticles as an cathode catalyst for a zinc-air battery with a flowing alkaline electrolyte  

Energy Technology Data Exchange (ETDEWEB)

The cyclic voltammetry indicated that the oxygen reduction reaction (ORR) proceeded by the four-electron pathway mechanism on larger Ag particles (174 nm), and that the ORR proceeded by the four-electron pathway and the two-electron pathway mechanisms on finer Ag particles (4.1 nm), simultaneously. The kinetics towards ORR was measured at a rotating disk electrode (RDE) with Ag/C electrode. The number of exchanged electrons for the ORR was found to be close to four on larger Ag particles (174 nm) and close to three on finer Ag particles (4.1 nm). The zinc-air battery with Ag/C catalysts (25.9 nm) was fabricated and examined. (author)

2009-09-05

283

A new zinc hydroxide nitrate heterogeneous catalyst for the esterification of free fatty acids and the transesterification of vegetable oils  

British Library Electronic Table of Contents (United Kingdom)

A new heterogeneous catalyst for the esterification of free fatty acids and the transesterification of vegetable oils is reported. The layered compound zinc hydroxide nitrate (Zn5(OH)8(NO3)22H2O) was very effective in the alcoholysis of palm oil and the esterification of lauric acid with m(ethanol), even when hydrated ethanol was used. Over the range of 100-140degreeC, the ester yield was the highest at 140degreeC, while the catalyst concentration had a much greater effect on ester yields than the molar ratio of alcohol to acid did. Total ester contents above 95wt% were obtained in both reactions and 93.2wt% glycerin streams were recovered as a result of methanolysis.

2008-01-01

284

A ZnO nanowire array film with stable highly water-repellent properties  

Energy Technology Data Exchange (ETDEWEB)

Highly water-repellent surfaces have been prepared from arrayed nanowires of zinc oxide (ZnO) by a treatment with stearic acid. The layers are electrochemically deposited on a nanocrystalline seed layer from an oxygenated aqueous zinc chloride solution. An advancing contact angle (CA) as high as 176{sup 0} is obtained with a very small hysteresis {approx}1{sup 0}. These results, supplemented by infrared spectroscopy, show that the stearic acid forms a very well-packed self-assembled monolayer. The CA measurements show a very good stability of the treated surface even when exposed to harsh conditions or long-term ambient illumination.

2007-09-12

285

A 1500-year record of lead, copper, arsenic, cadmium, zinc level in Antarctic seal hairs and sediments  

British Library Electronic Table of Contents (United Kingdom)

To reconstruct the profiles of heavy metal levels in the South Ocean ecosystem of Antarctica, the concentrations of lead (Pb), copper (Cu), arsenic (As), cadmium (Cd), and zinc (Zn) in seal hairs and lake sediments spanning the past 1500?years from Fildes Peninsula of King George Island and in weathering lake sediments from Nelson Island of West Antarctica were determined. The lead contents in the seal hairs and the weathering sediments show a sharp increase since the late 1800s, very likely due to anthropogenic contamination from modern industries. After the 1980s, the Pb content in seal hairs dropped by one-third, apparently due to the reduced usage of leaded gasoline in the Southern Hemisphere. Copper arises mainly from the weathering process, and its level may be substantially affected...

2006-01-01

286

Reduced boron diffusion under interstitial injection in fluorine implanted silicon  

International Nuclear Information System (INIS)

Point defect injection studies are performed to investigate how fluorine implantation influences the diffusion of boron marker layers in both the vacancy-rich and interstitial-rich regions of the fluorine damage profile. A 185 keV, 2.3x10"1"5 cm"-"2 F"+ implant is made into silicon samples containing multiple boron marker layers and rapid thermal annealing is performed at 1000 deg. C for times of 15-120 s. The boron and fluorine profiles are characterized by secondary ion mass spectroscopy and the defect structures by transmission electron microscopy (TEM). Fluorine implanted samples surprisingly show less boron diffusion under interstitial injection than those under inert anneal. This effect is particularly noticeable for boron marker layers located in the interstitial-rich region of the fluorine damage profile and for short anneal times (15 s). TEM images show a band of dislocation loops around the range of the fluorine ...

2007-12-01

287

The separation and determination of trace elements in iron ore  

International Nuclear Information System (INIS)

The separation, concentration, and determination of trace elements in iron ores are described. After the sample has been dissolved, the iron is separated by liquid-liquid extraction with a liquid cation-exchanger, di-(2-ethylhexyl) phosphoric acid. The trace elements aluminium, cadmium, calcium, chromium, cobalt, copper, lead, magnesium, manganese, mercury, potassium, sodium, vanadium, and zinc are determined in the aqueous phase by atomic-absorption spectrophotometry.

2008-05-01

288

The postal service wants to move away from diesel transport. Die Post will sich von ihren Dieseltransportern trennen  

Energy Technology Data Exchange (ETDEWEB)

By the year 2000, the Postal Service aims to reduce its diesel transport by around 15000 vehicles. The advisory service, Detecon, is reviewing alternatives for postal deliveries as part of the ''Post 2000'' initiative. One such system is an electric-powered vehicle with a zinc-air battery from the Israeli firm Electric Fluid Limited (EFL). (orig.)

1994-01-05

289

The effect of phytic acid on the levels of blood glucose and some enzymes of carbohydrate and lipid metabolism.  

Science.gov (United States)

In this study, six groups of rats were fed as follows: Groups 1 and 2 were fed formulated diets supplemented with zinc or without zinc respectively. Groups 3 and 4 were fed formulated diets supplemented with zinc plus phytic acid extracted from sweet potato (Ipomea batatas) or commercial phytic acid respectively. Groups 5 and 6 were fed formulated diets supplemented with phytic acid extract from sweet potato or commercial phytic acid respectively. The animals were fed for three weeks and then sacrificed The activities of key enzymes of carbohydrate and lipid metabolism as well as transaminases in the liver were determined. Blood glucose level was also assessed. Phytic acid extract consumption from sweet potato and commercial phytic acid plus zinc supplement lowered blood glucose levels. There was no significant change in the activity of 6-phosphogluconate dehydrogenase among the groups. Similarly, ...

2005-03-01

290

The combined transduction of copper, zinc-superoxide dismutase and catalase mediated by cell-penetrating peptide, PEP-1, to protect myocardium from ischemia-reperfusion injury  

UK PubMed Central (United Kingdom)

BackgroundOur previous studies indicate that either PEP-1-superoxide dismutase 1 (SOD1) or PEP-1-catalase (CAT) fusion proteins protects myocardium from ischemia-reperfusion-induced...Full Text Available

291

Sorption of gold by activated charcoal from cyan-containing solutions of complex salt composition  

Energy Technology Data Exchange (ETDEWEB)

An evaluation was made of the effectiveness of the action of reagents used for cleaning cyan-containing waste water for conditioning of the overflow of copper concentrate thickners of the Belousovskiy enrichment before sorption extraction of gold by activated charcoal. It was established that conditioning of the overflow by iron sulfates (II), copper and zinc diminshes, and by hypochlorite increases the capacitance of the activated charcoal for gold.

1982-01-01

292

Positive electrode for an alkaline primary air oxygen battery with thickened electrolyte. Positive Elektrode fuer ein alkalisches primaeres Luftsauerstoffelement mit eingedicktem Elektrolyten  

Energy Technology Data Exchange (ETDEWEB)

A cathode of improved discharge characteristics for a zinc-air battery is prepared from mixtures containing gamma-MnO/sub 2/ 33-67 wt%, C 12-40 wt% and KOH 20-28 wt%.

1981-06-19

293

Identification of Thlaspi caerulescens Genes That May Be Involved in Heavy Metal Hyperaccumulation and Tolerance. Characterization of a Novel Heavy Metal Transporting ATPase1  

UK PubMed Central (United Kingdom)

Thlaspi caerulescens is a heavy metal hyperaccumulator plant species that is able to accumulate extremely high levels of zinc (Zn) and cadmium (Cd) in its shoots (30,000 μg...Full Text Available

2004-11-01

294

Final Report: Planetary Instrument Definition and Design Program (PIDDP) Support Project  

Energy Technology Data Exchange (ETDEWEB)

The results of Sandia National Laboratories' participation in the NASA Planetary Definition and Design Program are summarized. Areas reported include the characterization of large area cadmium zinc telluride spectrometers and the application of simulation techniques to the prediction of device performance. Also investigated was the response of mercuric iodide devices in the region from 1 to 100 KeV. A literature study to determine the status or radiation damage measurements in room temperature semiconductor devices is also reported.

1999-03-01

295

Energy storage for hybrid remote power systems  

Energy Technology Data Exchange (ETDEWEB)

Energy storage can be a cost-effective component of hybrid remote power systems. Storage serves the special role of taking advantage of intermittent renewable power sources. Traditionally this role has been played by lead-acid batteries, which have high life-cycle costs and pose special disposal problems. Hydrogen or zinc-air storage technologies can reduce life-cycle costs and environmental impacts. Using projected data for advanced energy storage technologies, LLNL ran an optimization for a hypothetical Arctic community with a reasonable wind resource (average wind speed 8 m/s). These simulations showed the life-cycle annualized cost of the total energy system (electric plus space heating) might be reduced by nearly 40% simply by adding wind power to the diesel system. An additional 20 to 40% of the wind-diesel cost might be saved by adding hydrogen storage or zinc-air fuel cells to the system. Hydrogen produced by electrolysis of water using ...

1998-03-01

296

Development of zirconium alloys. Part II  

Science.gov (United States)

A number of alloys of zirconium have been investigated as part of a program aimed at improving the high-temperature tensile and creep strength of zirconium. These alloys include aluminum, beryllium, lead, magnesium, molybdenum, niobium, tantalum, tin, titanium, tungsten, vanadium, and zinc, binary and ternary alloys. The data indicate that aluminum, lead, molybdenum niobium, tin, titanium, tungsten, and vanadium can be used successfully to harden zirconium, and that aluminum, tin, titanium, and vanadium are particularly effective in maintaining the strength of zirconium at elevated temperatures.

1952-01-02

297

Cadmium down-regulation of kidney Sp1 binding to mouse SGLT1 and SGLT2 gene promoters: Possible reaction of cadmium with the zinc finger domain of Sp1  

UK PubMed Central (United Kingdom)

Cadmium (Cd) exposure causes glucosuria (glucose in the urine). Previously, it was shown that Cd exposure of primary cultures of mouse kidney cells (PMKC) decreased mRNA levels of the glucose...Full Text Available

2010-05-01

298

A novel zinc-air battery for electric vehicles  

Energy Technology Data Exchange (ETDEWEB)

A new type of zinc electrode is matched with new bifunctional air electrodes to produce a zinc-air battery of a novel design. The zinc electrode is a flow-thru type made from copper foam-metal. The air electrode uses corrosion resistant carbon black as a high area support for a highly dispersed spinel oxide electrocatalyst. The battery design employs flowing electrolyte, 12 M KOH saturated or supersaturated with zincate. Single cells as large as 200 cm{sup 2} (1/5 EV design scale) having a capacity of 20 AH have been tested with C/4--C/16 constant current cycling. More extensive and realistic life cycle testing was done with 2 Ah cells, including the Simplified Federal Urban Driving Schedule (SFUDS) cycle. This testing has confirmed that these cells can provide the necessary transient power response required for urban EV applications. The cells achieved an average of 72 SFUDS repetitions (7.2 hrs) per discharge cycle, more ...

1995-07-01

299

Properties of cubic boron nitride films with buffer layer control for stress relaxation using ion-beam-assisted deposition  

Energy Technology Data Exchange (ETDEWEB)

Significant ion irradiation during film growth is required for the formation of cubic boron nitride (cBN) films. Meanwhile, a huge level of intrinsic stress possibly induced by the ion bombardment has been frequently reported to result in cracking and/or lack of adhesion of deposited cBN films. The present work has been performed to investigate the interfacial and/or the buffer layer structures with better matching to the cBN film by relaxation of the film stress using ion-beam-assisted deposition (IBAD). Boron nitride films have been synthesized on Si(100) wafer and tungsten carbide (WC) substrates by depositing boron vapor under simultaneous bombardment with nitrogen ions and nitrogen-argon mixture ions in the energy range of 0.5-10 keV. Cubic BN films with enhanced tribological properties have been explored by inserting a BN layer with various B/N compositions as a controlled buffer at the interface. Significant relaxation of the film stress has been observed for the buffer layer ...

1999-09-01

300

Formation of the Neutron Donor C13 in AGB Stars by Overshoot and Rotation  

CERN Document Server

(abridged) Observations clearly show that low-mass AGB stars can provide a nucleosynthesis site of the s-process. Recent stellar evolution models indicate that radiative burning of C13 between thermal pulses in low-mass AGB stars may indeed provide the needed neutrons. Some mixing between the proton-rich envelope and the carbon-rich core may lead to the production of C13. However, the responsible physical mechanism is not yet unambiguously identified. We present stellar model calculations with overshoot and rotation. Overshoot, with a time-dependent and exponentially decaying efficiency, leads to a partial mixture of protons and C12 during the third dredge-up. According to the depth-dependent ratio of protons and C12, a small C13-pocket forms underneath a N14-rich layer. Overshoot does not allow for any mixing during the interpulse phase. Rotation introduces mixing driven by large angular velocity gradients which form at ...

2000-01-01

301

Wastewater treatment; Abwasserreinigung  

Energy Technology Data Exchange (ETDEWEB)

The methods introduced for the field of cleaning waste water can be classified under various processes. Chemical oxidation is done with ozone, hydrogen peroxide and ultraviolet irradiation with subsequent biological decomposition. Another method is ultra-filtration with recovery of valuable materials or waste water ponds with algae biomass to decompose ammonium compounds, nitrates and phosphates. (EF) [Deutsch] Die auf dem Gebiet der Abwasserreinigung vorgestellten Methoden kann man in verschiedene Verfahren einordnen. Die chemische Oxidation erfolgt mit Ozon, Wasserstoff-Peroxid, UV Bestrahlung und anschliessenden biologischen Abbau. Eine andere Methode ist die Ultrafiltration mit Rueckgewinnung von Wertstoffen oder Abwasserteiche mit Algenbiomasse zum Abbau von Ammoniumverbindungen, Nitraten und Phosphaten. (EF)

1994-11-01

302

U.S. Department of Energy, Nevada Operations Office, Environmental Monitoring Program: Summary data report - first and second calendar quarters 1994  

International Nuclear Information System (INIS)

During the first and second quarters of 1994 air samples were collected and analyzed from 54 air particulate/halogen sampling stations, 10 noble gas sampling stations and 19 tritiated water vapor sampling stations. Surface water samples were collected and analyzed from 12 open water supply reservoirs, 8 natural springs, 2 wastewater containment ponds and 9 sewage lagoons. Groundwater samples were obtained brom 10 potable and 1 non-potable supply wells, and 8 drinking water consumption points. Ambient radiation levels were measured at 193 locations.

1991-10-31

303

The wash-off of dyeings using interstitial water part 1: Initial studies  

British Library Electronic Table of Contents (United Kingdom)

The extent to which a novel wash-off process using polyamide beads removed five different types of dye from three different types of fibre was similar to that achieved using conventional aftertreatments. Whilst bead wash-off and the conventional aftertreatments were of similar duration and temperature, conventional aftertreatment employed a 10:1 or 20:1 liquor ratio whereas bead wash-off used a < 1:1 liquor ratio. As vagrant dye was adsorbed onto the bead material during wash-off, the low amount of wastewater generated contained little residual dye, thereby offering the potential of reduced environmental and cost benefits. Bead wash-off did not impair the fastness of two non-metallised acid dyes on nylon 6,6 to washing at 60 ?C.

2011-01-01

304

Synergies in co-digestion of sludge with olive oil mill effluent  

Energy Technology Data Exchange (ETDEWEB)

A full scale co-digestion system for sludge and Olive oil mill effluent (OME) and a regional sludge management plan has been set-up to solve urgent environmental problems, modifying an existing cold municipal digester, by means of simple and effective technology. Monitoring of the full scale system demonstrated good compatibility between OME and sludge, up to 20% mixture, and high removal of organics compounds. Coagulant compounds present in OME (mainly Fats), promoted aggregation and settling of anaerobic sludge and also its acetoclastic activity, minimizing the load returned to the wastewater treatment line and improving also the activated sludge system. The co-digestion of OME with sludge agreed the project purposes, and produced large quantity of biogas and electric energy.

2004-07-01

305

Submerged microfiltration membrane coupled with alum coagulation/powdered activated carbon adsorption for complete decolorization of reactive dyes  

British Library Electronic Table of Contents (United Kingdom)

Even the presence of very low concentrations of dyes (1mgL-1) in the effluent is highly visible and is considered aesthetically undesirable. It must be removed from wastewater completely. This study systematically evaluates the performance of adsorption (three kinds of powdered activated carbons), coagulation (AlCl36H2O) and membrane (submerged hollow fiber microfiltration) processes individually in treating two kinds of reactive dyes (Orange 16 and Black 5) and then using a hybrid process with combined coagulation-adsorption-membrane treatment system. Adsorption capacity and kinetics of Orange 16 were much higher and faster than those of Black 5. The dye removal efficiency by coagulation was highly dependent on dye concentration and solution pH. The hybrid process performance was far more...

2006-01-01

306

Series of surveys for enteric viruses and indicator organisms in Tokyo Bay after an event of combined sewer overflow.  

Science.gov (United States)

Combined sewer overflows (CSOs) have been recognised as one of the serious sources of pollution to the water environment during rain events, although field surveys to investigate the effect of their magnitude and duration on receiving waters have been very limited. The fates of enteric viruses (norovirus G1, G2, enteroviruses) and coliforms were determined in the wastewater treatment plant on a fine day and on a rainy day. Not all microorganisms were reduced in the primary treatment, but were reduced in the secondary treatment. Occurrences of enteric viruses and levels of coliforms were surveyed in the receiving coastal area after a CSO event, with the profiles of the enteric viruses in the coastal seawater being almost at the same positive ratio for 4 d after the CSO event. PMID:15318519

2004-01-01

307

Removal of reactive dye Brilliant Red HE-3B from aqueous solutions by industrial lignin: Equilibrium and kinetics modeling  

British Library Electronic Table of Contents (United Kingdom)

The lignin, one of the main by-products of the pulp industry, can be used to remove dyes from textile wastewaters. The potential of the lignin for Brilliant Red HE-3B reactive dye removal from aqueous solutions at pH=1.5 was examined by the batch technique as a function of dye concentration, solution temperature and contact time. The Freundlich, Langmuir, Dubinin-Radushkevich and Tempkin adsorption isotherms were used to describe the data of sorption equilibrium and to determine its corresponding isotherm constants. The thermodynamic parameters DG, DH and DS were also determined; the obtained values show that the sorption of reactive dye on lignin is a spontaneous, endothermic and entropy-driven process. The kinetic of reactive dye sorption was analyzed using the pseudo-first order and pse...

2010-01-01

308

Removal of polycyclic aromatic hydrocarbons from aqueous solution using plant residue materials as a biosorbent  

British Library Electronic Table of Contents (United Kingdom)

To elucidate biosorption mechanism and removal efficiency of plant residues as a biosorbent to abate polycyclic aromatic hydrocarbons (PAHs) in wastewater, sorption of PAHs onto wood chips (WC), ryegrass roots (RR), orange peels (OP), bamboo leaves (BL), and pine needles (PN) were investigated. The structural characterization of the biosorbents was analyzed by elemental composition, BET-N2 surface area, and Fourier transform infrared spectroscopy. PAHs sorption to the selected biosorbents were compared and correlated with their structures. Biosorption isotherms fit well with Freundlich equation and the mechanism was dominated by partition process. The magnitude of phenanthrene partition coefficients (Kd) followed the order of PN>BL>OP>RR>WC, ranged from 2484+/-24.24 to 5306+/-92.49L/kg. Ex...

2011-01-01

309

Non-catalytic and catalytic wet air oxidation of pharmaceuticals in ultra-pure and natural waters  

British Library Electronic Table of Contents (United Kingdom)

A wet air oxidation (WAO) process was applied to four selected pharmaceuticals (metoprolol, naproxen, amoxicillin, and phenacetin) individually dissolved in ultra-pure water, varying the temperature and oxygen pressure. Due to the moderate (amoxicillin) or low (metoprolol, naproxen, and phenacetin) efficiency found in the oxidation of these pollutants, a catalytic wet air oxidation (CWAO) process was then tested using a platinum catalyst supported on multi-walled carbon nanotubes (CNT). In this CWAO process, the pharmaceuticals were dissolved together in ultra-pure water and in four natural water matrices-a reservoir water, a groundwater, and two waters from different municipal wastewater treatment plants. On the basis of the measurements of their removals, a discussion is given of the inf...

2011-01-01

310

Kinetics of a reactive dye adsorption onto dolomitic sorbents.  

Science.gov (United States)

A novel wastewater treatment technique has been investigated, for reactive dye removal, in batch kinetic systems. These experimental studies have indicated that charred dolomite has the potential to act as an adsorbent for the removal of Brilliant Red reactive dye from aqueous solution. The effect of initial dye concentration, adsorbent mass:liquid volume ratio, and agitation speed on dye removal have been determined with the experimental data mathematically described using empirical external mass transfer and intra-particle diffusion models. The experimental data show conformity with an adsorption process, with the removal rate heavily dependent on both external mass transfer and intra-particle diffusion. PMID:12691893

2003-05-01

311

Independent power plant using wood waste  

Energy Technology Data Exchange (ETDEWEB)

A 1 MWe power plant using waste wood fuel is to be installed at a US Marine Corps base, which will supply all wood from a landfill site. The core energy conversion technology is a down-draft gasifier supplying approximately 150 Btu/scf gas to both spark ignition and diesel dual-fuel engine-generator sets. Features of the plant design include: (1) grinding wood fuel from a wide range of waste resources, (2) specialized screening for fines removal, (3) complete tar and other waste product control without landfill disposal, and (4) use of process heat for bulk fuel drying, gasifier air pre-heating, and wastewater evaporation.

1995-08-01

312

Economic analysis of effluent limitation guidelines and standards for the centralized waste treatment industry  

Science.gov (United States)

This report estimates the economic and financial effects and the benefits of compliance with the proposed effluent limitations guidelines and standards for the Centralized Waste Treatment (CWT) industry. The Environmental Protection Agency (EPA) has measured these impacts in terms of changes in the profitability of waste treatment operations at CWT facilities, changes in market prices to CWT services, and changes in the quantities of waste management at CWT facilities in six geographic regions. EPA has also examined the impacts on companies owning CWT facilities (including impacts on small entities), on communities in which CWT facilities are located, and on environmental justice. EPA examined the benefits to society of the CWT effluent limitations guidelines and standards by examining cancer and non-cancer health effects of the regulation, recreational benefits, and cost savings to publicly owned treatment works (POTWs) to which indirect-discharging CWT facilities send their ...

1998-12-01

313

Diversity of Dominant Bacterial Taxa in Activated Sludge Promotes Functional Resistance following Toxic Shock Loading  

British Library Electronic Table of Contents (United Kingdom)

Examining the relationship between biodiversity and functional stability (resistance and resilience) of activated sludge bacterial communities following disturbance is an important first step towards developing strategies for the design of robust biological wastewater treatment systems. This study investigates the relationship between functional resistance and biodiversity of dominant bacterial taxa by subjecting activated sludge samples, with different levels of biodiversity, to toxic shock loading with cupric sulfate (Cu[II]), 3,5-dichlorophenol (3,5-DCP), or 4-nitrophenol (4-NP). Respirometric batch experiments were performed to determine the functional resistance of activated sludge bacterial community to the three toxicants. Functional resistance was estimated as the 30?min IC50 or th...

2011-01-01

314

Development document for proposed effluent limitations guidelines and standards for the centralized waste treatment industry. Volumes 1 and 2  

Energy Technology Data Exchange (ETDEWEB)

This document includes the following topics: Background; Data Collection; Scope/Applicability of the Proposed Regulation; Description of the Industry; Industry Subcategorization; Pollutants of Concern for the Centralized Waste Treatment Industry; Pollutants Selected for Regulation; Wastewater Treatment Technologies; Regulatory Options Considered and Selected for Basis of Regulation; Long-Term Averages, Variability Factors, and Limitations and Standards; Cost of Treatment Technologies; Pollutant Loading and Removal Estimates; Non-Water Quality Impacts; Implementation; Analytical Methods and Baseline Values; List of Definitions; List of Acronyms; Appendix A--Pollutant Groups; Appendix B--Listing of Characerization Data From Non-Hazardous Oils Facilities; Appendix C--Listing of Daily Influent and Effluent Measuements; Appendix D--Facility-Specific Compliance Costs; Appendix E--Attachements to Chapter 10; and Appendix F--Listing of Pollutants of Concern and Cas ...

1998-12-01

315

Catalytic applications of red mud, an aluminium industry waste. A review  

Energy Technology Data Exchange (ETDEWEB)

Red mud is a by-product of bauxite processing through Bayer process. The amount of red mud generated depends largely on the type of ore used and the processing. Use of red mud as a catalyst can be a good alternative to the existing commercial catalysts. Its properties such as iron content in form of ferric oxide (Fe{sub 2}O{sub 3}), high surface area, sintering resistance, resistance to poisoning and low cost make it an attractive potential catalyst for many reactions. Besides red mud, ferric ion sludge from wastewater treatment plant has also been studied for its catalytic properties, mainly due to its ferric oxide constituent. This paper reviews the studies on red mud as a catalyst. The catalyst characteristics, reaction mechanisms involved and performance are examined and compared with iron oxide catalyst and commercial catalysts. (author)

2008-05-30

316

Biosorption of heavy metals on fungal biomass  

Energy Technology Data Exchange (ETDEWEB)

A method of using fungi in removing heavy metal from wastewater was discussed. Fungi for this purpose can be obtained inexpensively, and on a constant basis from industrial fermentation processes. The biosorption of lead, cadmium and nickel on fungal stock cultures, was investigated. In these experiments, the fungal stock used was Aspergillus niger and Rhizopus stolonfier. Alkali pre-treatment of the fungal biomass improved the metal biosorptive capacity in comparison to live cells. The effect of alkali treatment, however, varied,showing highest biosorptive capacity for lead and least for nickel. Results showed that metal biosorption of metallic ions increased with an increase in pH from 3.2 to 4.0. Equilibrium times of five hours were observed for the biosorption of lead and cadmium, while the equilibrium time for nickel was three hours. 10 refs., 3 tabs., 7 figs.

1996-09-01

317

Biosorption behavior and mechanism of beryllium from aqueous solution by aerobic granule  

British Library Electronic Table of Contents (United Kingdom)

The treatment of Be-contaminated wastewater has been paid little attention, although beryllium (Be) and its compounds are of high toxicity. In this research, aerobic granule was for the first time introduced to remove Be from aqueous solution. Influencing factors including reaction time, initial Be concentration, pH, biosorbent dosage, and coexistent metal ions (Cd, Cu, and Fe) were investigated in batch experiments. The aerobic granule, characterized by element analysis and CLSM, was abundant in carboxyl, phosphoryl, amine and hydroxyl groups. Potentiometric titration experiment demonstrated that the pH effect on biosorption depended on the surface charge of granule (pHzpc=2.4) and the species of Be (Be^2^+, Be(OH)^+, and Be(OH)2) in solution. The coexistent metal ions would either inhibi...

2011-01-01

318

Base flow hydrology and water quality of an Ozarks spring and associated recharge area, southern Missouri, USA  

British Library Electronic Table of Contents (United Kingdom)

Human activities in the karst Ozark Plateaus can impact water quality of springs where surface water is rapidly transferred to subsurface conduits. Bennett Spring, in southern Missouri, is the fourth largest spring in the state and supports local tourism activities. Questions regarding poorly functioning on-site wastewater systems (OWS) have raised concerns over the long-term water quality of the spring. This study reports the results of a surface water quality monitoring program in the recharge area where monthly samples were collected at base flow to identify potential pollution sources to the spring. Base flow hydrology of the recharge area was highly variable over the study period, which was drier than normal, causing an incomplete sampling record due to no flow conditions at some site...

2011-01-01

319

Advanced Flue Gas Desulfurization (AFGD) Demonstration Project. Technical progress report No. 13, January 1, 1993--March 31, 1993  

Science.gov (United States)

The goal of this project is to demonstrate that, by combining state-of-the-art technology, highly efficient plant operation and maintenance capabilities and by-product gypsum sales, significant reductions of SO{sub 2} emissions can be achieved at approximately one-half the life cycle cost of a conventional Flue Gas Desulfurization (FGD) system. Further, this emission reduction is achieved without generating solid waste and while minimizing liquid wastewater effluent. Basically, this project entails the design, construction and operation of a nominal 600 MWe AFGD facility to remove SO{sub 2} from coal-fired power plant flue gas at the Northern Indiana Public Service Company`s Bailly Generating Station.

1994-08-01

320

3D model for a secondary facultative pond  

British Library Electronic Table of Contents (United Kingdom)

This paper describes a comprehensive model of wastewater treatment in secondary facultative ponds, which combines 3D hydrodynamics with a mechanistic water quality model. The hydrodynamics are based on the Navier-Stokes equation for incompressible fluids under shallow water and Boussinesq assumptions capturing the flow dynamics along length, breadth and depth of the pond. The water quality sub model is based on the Activated Sludge Model (ASM) concept, describing COD and nutrient removal as function of bacterial growth following Monod kinetics, except for Escherichia coli removal, which was modelled as first order decay. The model was implemented in the Delft3D software and was used to evaluate the effect of wind and the addition of baffles on the water flow pattern, temperature profiles i...

2011-01-01

321

Spectroscopy of neutron-rich {sup 59-63}Mn isotopes  

Science.gov (United States)

The neutron-rich Mn isotopes from A=59 to 63 have been studied through multi-nucleon transfer reactions by bombarding a {sup 238}U target with a beam of {sup 70}Zn at an energy of E{sub lab}=460 MeV. Prompt {gamma} rays measured by the CLARA array have been identified unambiguously for each nucleus, using coincidence relationships with ions detected in the high-acceptance magnetic spectrometer PRISMA. The new data extends the knowledge of the low-lying level structure of Mn isotopes, which is discussed in terms of the systematics of the region. Results are compared with large-scale shell-model calculations using different effective interactions and valence spaces.

2008-08-15

322

Spectroscopy of neutron-rich "5"9"-"6"3Mn isotopes  

International Nuclear Information System (INIS)

The neutron-rich Mn isotopes from A=59 to 63 have been studied through multi-nucleon transfer reactions by bombarding a "2"3"8U target with a beam of "7"0Zn at an energy of E_l_a_b=460 MeV. Prompt #gamma# rays measured by the CLARA array have been identified unambiguously for each nucleus, using coincidence relationships with ions detected in the high-acceptance magnetic spectrometer PRISMA. The new data extends the knowledge of the low-lying level structure of Mn isotopes, which is discussed in terms of the systematics of the region. Results are compared with large-scale shell-model calculations using different effective interactions and valence spaces.

2008-08-01

323

Seasonal variations of Zn, Cu, As and Mo in arsenic-rich stream at the Mokrsko gold deposit, Czech Republic  

British Library Electronic Table of Contents (United Kingdom)

Monthly sampling of slightly alkaline arsenic-rich stream in the Mokrsko gold deposit revealed seasonal variations in dissolved Zn, Cu, As and Mo. Concentrations of trace metal cations (Zn, Cu) increased as much as 330 and 178%, respectively, from minimum mean values at autumn to maximum mean values at spring. In contrast, concentrations of trace element oxyanions (As, Mo) revealed opposite seasonal pattern with increase to 189% (As) and 123% (Mo) during summer?autumn, indicating that in-stream biogeochemical process(es) played the main role in controlling the seasonal variations of these trace elements. The trace elements were mainly scavenged by low crystalline Mn oxyhydroxide and Fe oxyhydroxide (ferrihydrite). Results are consistent with sorption and coprecipitation processes controlli...

2011-01-01

324

Occurrences and distributions of branched alkylbenzenes in the Dongsheng sedimentary uranium ore deposits, China  

British Library Electronic Table of Contents (United Kingdom)

A series of branched alkylbenzene ranging from C15 to C19 with several isomers (2?5) at each carbon number were identified in sediments from the Dongsheng sedimentary uranium ore deposits, Ordos Basin, China. The distribution patterns of the branched alkylbenzenes show significant differences in the sample extracts. The branched alkylbenzenes from organic-rich argillites and coals range from C15 to C19 homologues, in which the C17 or C18 dominated. On the other hand, the C19 branched alkylbenzenes dominated in the sandstone/siltstone extracts. The obvious differences of the branched alkylbenzene distributions between the uranium-host sandstones/siltstones and the interbedded barren organic-rich mudstones/coals probably indicate their potential use as biological markers associated with part...

2010-01-01

325

New neutron-rich isotopes in the scandium-to-nickel region, produced by fragmentation of a 500 MeV/u sup 86 Kr beam  

Energy Technology Data Exchange (ETDEWEB)

We have measured production cross-sections of the new neutron-rich isotopes {sup 58}Ti, {sup 61}V, {sup 63}Cr, {sup 66}Mn, {sup 69}Fe, {sup 71}Co and neighbouring isotopes that have been identified as projectile fragments from reactions between a 500 MeV/u {sup 86}Kr beam and a beryllium target. The isotope identification was performed with the zero-degree magnetic spectrometer FRS at GSI, using in addition time-of-flight and energy-loss measurements. The experimental production cross-sections for the new nuclides and neighbouring isotopes are compared with an empirical parametrization. The resulting prospects for reaching even more neutronrich isotopes, such as the doubly-magic nuclide {sup 78}Ni, are discussed. (orig.).

1992-07-01

326

New neutron-rich isotopes in the scandium-to-nickel region, produced by fragmentation of a 500 MeV/u "8"6Kr beam  

International Nuclear Information System (INIS)

We have measured production cross-sections of the new neutron-rich isotopes "5"8Ti, "6"1V, "6"3Cr, "6"6Mn, "6"9Fe, "7"1Co and neighbouring isotopes that have been identified as projectile fragments from reactions between a 500 MeV/u "8"6Kr beam and a beryllium target. The isotope identification was performed with the zero-degree magnetic spectrometer FRS at GSI, using in addition time-of-flight and energy-loss measurements. The experimental production cross-sections for the new nuclides and neighbouring isotopes are compared with an empirical parametrization. The resulting prospects for reaching even more neutronrich isotopes, such as the doubly-magic nuclide "7"8Ni, are discussed. (orig.).

327

LDEF impact craters formed by carbon-rich impactors  

International Nuclear Information System (INIS)

Two small craters (number 74, 119 microns, and number 31, 158 microns in diameter) with depth to diameter ratios of about 0.59 and 0.8, respectively, were found in Al from the Long Duration Exposure Facility (LDEF) experiment tray A11EOOF. Both craters have residues concentrated in the crater bottoms, along the walls, and on top of the overturned rims. Low voltage scanning electron electron microscopy, Auger electron spectroscopy, time of flight secondary ion mass spectroscopy and energy dispersive x-ray spectroscopy were used to obtain high resolution imagery and elemental analysis. Analyses indicate that the impactor for both craters was carbon-rich, as the residues contain mostly C. Silicon, S, and F in low concentrations are present on the Al surface away from the craters and may be, in part, contaminants.

1991-06-01

328

How is Regeneration of Plants after Mowing Affected by Shoot Size in Two Species-Rich Meadows with Different Water Supply?  

British Library Electronic Table of Contents (United Kingdom)

Mowing a meadow is an example of an equalizing process that reduces differences among species by removing aboveground biomass approximately 5?cm above ground. This regular disturbance that affects all plants prevents competitive exclusion of small species and thus allows coexistence of numerous species differing in shoot size. In this paper we search for the mechanism behind this by comparing the shoot biomass of 41 common species in dry and wet species-rich meadows in mown and recently abandoned plots in June (before mowing) and in October. We asked the following questions: i) Do the plants differ in proportion of biomass lost by mowing? ii) Are the mown plants able to compensate for biomass lost by mowing? iii) Is the compensatory ability of mown plants related to their size? iv) Is the ...

2010-01-01

329

Effect of Mo on the composition and electronic properties of the passive films formed on stainless steels at 350 C  

Energy Technology Data Exchange (ETDEWEB)

The effect of Mo addition as an alloying element to stainless steel alloys is investigated by capacitance (Mott Schottky approach), and photoelectrochemistry measurements. Complementary studies were made using Auger electron spectroscopy and X-ray photoelectron spectroscopy. The Mott-Schottky approach and the photoelectrochemical studies showed that the presence of Mo as an alloying element affects the semiconductive properties of the oxide films. The analytical results have shown that the oxide films formed on stainless steels are composed by an external Fe rich region and an inner Cr rich region. No significant amount of Mo was found in the outer layers of the film. The presence of Mo leads to an increase of the chromium content in the inner layers of the film, although without increasing the film thickness. (orig.) 30 refs.

1998-12-31

330

Effect of Mo on the composition and electronic properties of the passive films formed on stainless steels at 350 C  

International Nuclear Information System (INIS)

The effect of Mo addition as an alloying element to stainless steel alloys is investigated by capacitance (Mott Schottky approach), and photoelectrochemistry measurements. Complementary studies were made using Auger electron spectroscopy and X-ray photoelectron spectroscopy. The Mott-Schottky approach and the photoelectrochemical studies showed that the presence of Mo as an alloying element affects the semiconductive properties of the oxide films. The analytical results have shown that the oxide films formed on stainless steels are composed by an external Fe rich region and an inner Cr rich region. No significant amount of Mo was found in the outer layers of the film. The presence of Mo leads to an increase of the chromium content in the inner layers of the film, although without increasing the film thickness. (orig.)

1997-08-25

331

Disordered bcc γ-phase to δ-phase transformation in Zr-rich U-Zr alloy  

British Library Electronic Table of Contents (United Kingdom)

The transformation mechanism of hexagonal delta phase from the disordered bcc gamma phase has not been reported before in the Zr-rich U-Zr alloy system. With the help of X-ray diffraction, transmission electron microscopy (TEM) and high-resolution TEM analyses it was shown that the gamma to delta conversion takes place by the lattice collapse mechanism of omega transformation. It was also ascertained that a higher aging temperature or time promotes the growth of all four variants of the delta phase within a parent gamma grain. In addition, ab initio electronic structure calculations showed that the bcc to hexagonal transformation, involving partial ordering of the parent bcc phase followed by (111) plane collapse, is energetically favorable.

2011-01-01

332

Deposition of amino-rich coatings by RF magnetron sputtering of Nylon: Investigation of their properties related to biomedical applications  

British Library Electronic Table of Contents (United Kingdom)

Amino-rich polymeric coatings are widely used in biomedical applications, since they promote adsorption of diverse biomolecules or facilitate cell growth. As a consequence, there is a growing interest in fabrication of such coatings that is focused predominantly on the optimization of the deposition process in terms of high density of primary amino groups. In addition, the nature of biomedical applications requires also sufficient stability of the films in aqueous environments. This aspect is investigated in this contribution. In particular, the effect of water and phosphate buffer saline on the coatings prepared by RF magnetron sputtering of Nylon 6,6 in Ar/N2 and N2/H2 gas mixtures is evaluated. The samples exposed to liquids are characterized by various diagnostic methods and their prop...

2011-01-01

333

Competing Shapes And Alignments In Neutron-Rich Hf Nuclei  

International Nuclear Information System (INIS)

The talk will focus on spin-dependent competition between oblate and prolate shape minima in the potential energy landscape of "1"8"0Hf (the most neutron-rich stable isotope), mediated via the alignment of valence nucleons. Results of a prompt spectroscopic study, using deep inelastic reactions with Gammasphere and CHICO, bombarding a thin "2"3"2Th target with a "1"8"0Hf beam #approx#25% above the Coulomb barrier, will be presented. Nucleon alignments in both prolate and oblate minima will be discussed, as well as the favoring of oblate collective rotation at high spins, observed through a mixing with gamma vibrations built on the prolate shape.

2008-05-12

334

Are Stars with Planets Polluted?  

CERN Document Server

We compare the metallicities of stars with radial velocity planets to the metallicity of a sample of field dwarfs. We confirm recent work indicating that the stars-with-planet sample as a whole is iron rich. However, the lowest mass stars tend to be iron poor, with several having [Fe/H]0.48) that contributes to but does not explain the mass-metallicity trend in the stars-with-planets sample. We use Monte Carlo models to show that adding an average of 6.5 Earth masses of iron to each star can explain both the mass-metallicity and the age-metallicity relations of the stars-with-planets sample. However, for at least one star, HD 38529, there is good evidence that the bulk metallicity is high. We conclude that the observed metallicities and metallicity trends are the result of the interaction of three effects; accretion of about 6 Earth masses of iron rich material, selection effects, and in some cases, high intrinsic metallicity.

2002-01-01

335

A VUV prism spectrometer for RICH radiator refractometry  

CERN Document Server

A prism spectrometer has been developed to operate in the VUV wavelength range from 120 to 200 nm. It can be used as a pre- disperser in conjunction with a Fabry-Perot based gas refractometer. This instrument has also been used to measure the refractive index of the liquid radiator C/sub 6/F/sub 14/ in various spectral lines. This radiator is used in the RICH detectors of the DELPHI experiment and has been proposed for ALICE, and LHCb experiments. The spectral resolution of the system is improved as the wavelength decreases and the data are consistent with a wavelength accuracy about 0.4 nm at 140 nm. The results for the dispersion curve of the above liquid are presented. (17 refs).

2000-01-01

336

Thermal effect on superhydrophobic performance of stearic acid modified ZnO nanotowers  

Energy Technology Data Exchange (ETDEWEB)

The thermal desorption of stearic acid on superhydrophobic zinc oxide nanotowers has been investigated. The stearic acid passivated zinc oxide nanotowers provide a very high contact angle of {approx}173 {+-} 1.1 deg. with a very low hysteresis of {approx}1.4 {+-} 0.5 deg. due to the presence of a binary structure composed of several nanosteps on each nanotower of height {approx}700 nm that eventually reduces the area of contact between the drop and the nanotowers and trapping more air as revealed by the field emission scanning electron microscopy images. The superhydrophobic performance of these nanotowers, however, declines following annealing at elevated temperatures. Fourier transform infrared spectra show a reduction in the intensity of stearic acid -CH{sub n} peaks at elevated temperatures revealing the cause of the decrease in contact angle and confirming the occurrence of thermal desorption at 184 deg. C. The corresponding activation ...

2008-02-28

337

Role of the presence of transition-metal atoms at the antisites in CrAs, CrSe and VAs zinc-blende compounds  

Energy Technology Data Exchange (ETDEWEB)

In a recent publication [I. Galanakis, K. Ozdog-tilde an, E. Sasiog-tilde lu, B. Aktas, Phys. Rev. B 74 (2006) 140408(R)] we have shown that in the case of CrAs and related transition-metal chalcogenides and pnictides, crystallizing in the zinc-blende structure, the excess of the transition-metal atoms leads to half-metallic ferrimagnetism. The latter property is crucial for spintronic applications with respect to ferromagnets due to the lower stray fields created by these materials. We extend this study to cover the case where the transition-metal atoms sitting at antisites are not identical to the ones in the perfect sites. In Cr-based compounds, the creation of Mn antisites keeps the half-metallic ferrimagnetic character produced also by the Cr antisites. In the case of VAs, Cr and Mn antisites keep the half-metallic character of VAs (contrary to V antisites) due to the larger exchange splitting exhibited by these atoms.

2008-02-15

338

Release of zinc from disposable coils during hemodialysis  

Energy Technology Data Exchange (ETDEWEB)

In a prior study, we demonstrated that certain disposable coils are contaminated with zinc and release substantial quantities of Zn during hemodialysis, producing high post-dialysis plasma Zn concentrations. The present investigation was designed to monitor plasma and dialysis fluid Zn and copper throughout dialysis and to estimate patient Zn and Cu uptake. Venous plasma, arterial plasma and coil chamber fluid were sampled periodically throughout dialysis; trace metal concentrations were determined by flame atomic absorption spectrophotometry. Release of considerable quantities of Zn from the coils into the dialysis fluid, with uptake into the patient's plasma, was found. Approximately one-half of the plasma Zn uptake occurred in the first 45 minutes. Coils from different lots released significantly different quantities of Zn. Patient uptake of Zn ranged from 3.2 mg-23.0 mg, with a mean of 15.0 +- 6.1 mg. Copper release and uptake was low. It is ...

1981-06-01

339

Reduction of CO{sub 2} concentration in a zinc/air battery by absorption in a rotating packed bed  

Energy Technology Data Exchange (ETDEWEB)

The reduction of CO{sub 2} concentration in a gas stream containing 500ppm of CO{sub 2} by a technique combining chemical absorption with Higee (high gravity) was investigated in this study. Using a 2.0L aqueous amine-based solution to treat the feed gas with a flow rate which varied from 12.9 to 20.6Lmin{sup -1}, piperazine (PZ) was found to be more effective than 2-(2-aminoethylamino) ethanol (AEEA) and monoethanolamine (MEA) for reducing the CO{sub 2} concentration to a level below 20ppm. The effects of temperature, rotating speed, amine solution flow rate, and gas flow rate on the removal efficiency of CO{sub 2} were systematically examined. The results indicated that the proposed compact device could effectively reduce CO{sub 2} to a level below 20ppm, as required by a zinc/air battery, for a long period of time using PZ and its mixture with AEEA and MEA as the absorbents. (author)

2006-11-22

340

Properties of ZnO thin films prepared by radio-frequency plasma beam assisted laser ablation  

International Nuclear Information System (INIS)

Zinc oxide thin films were obtained by laser ablation of a Zn target in oxygen reactive atmosphere, the oxygen being supplied either by a standard gas inlet valve or from a radio-frequency (rf) oxygen plasma. Pt-coated silicon and MgO were used as substrates. The influence of the deposition parameters as laser wavelength (266, 355, 1064 nm), laser fluence (1.5-20 J/cm2) and oxygen pressure (1-60 Pa) was studied. The influence of the rf plasma beam addition on the morphological proprieties of zinc oxide films was particularly investigated, simultaneously with several configurations of the direction of the ablation plasma, the rf plasma beam and the substrate. The obtained films, with thicknesses in the range of 50 nm to 1 ?m have been characterized by atomic force microscopy (AFM), X-ray diffraction (XRD), transmission electron microscopy (TEM).

2005-07-15

341

Initial stage of localized corrosion in artificial pits formed with photon rupture on Zn-5 mass% Al alloy-coated steel  

International Nuclear Information System (INIS)

The photon rupture method, by which oxide film and metal are removed by focused pulsed Nd-YAG laser beam irradiation, was applied to form artificial micro-pits in Zn-5 mass% Al alloy-coated steel. The zinc alloy-coated layer was removed by pulsed laser irradiation treatment for about one second in a neutral buffer solution with NaCl. The rest potential transient with the laser treatment was measured. In the early stage of the laser treatment the rest potential of zinc alloy-coated steel changed to the negative direction immediately after every irradiation of a laser pulse and then returned to the previous value. However, after the steel substrate was exposed to the solution, the rest potential moved to the positive direction immediately after every irradiation of a laser pulse and then returned to the previous value. The amplitude and duration of the potential change after the laser irradiation increased with repetition of laser irradiation, ...

2007-05-01

342

Hydrogen evolution and corrosion performance of NiZn coatings  

International Nuclear Information System (INIS)

The hydrogen evolution reaction (HER) was studied on bare brass (B), nickel coated brass (B/Ni), nickel-zinc alloy coated brass (B/NiZn, leached Zn), nickel (under layer)/nickel-zinc alloy coated (top layer) brass electrodes (B/Ni/NiZn, leached Zn) in 1 M NaOH solution using electrolysis, cathodic polarization and electrochemical impedance spectroscopy (EIS) techniques. Long term tests were performed in order to evaluate the electrocatalytic activity and corrosion performance of the prepared electrodes with operation time. The results showed that leached electrodes, especially B/Ni/NiZn electrode, have a smaller overpotential than the others and a good electrocatalytic activity for the HER. Its electrocatalytic activity is also stable over electrolysis time. Contrary to the HER performance, B/NiZn cannot provide an adequate corrosion protection. However, when a thin Ni layer was coated under the NiZn alloy coating (B/Ni/NiZn), a greater ...

2007-02-01

343

Growth and characterisation of electrodeposited ZnO thin films  

Energy Technology Data Exchange (ETDEWEB)

The electrochemical method has been used to deposit zinc oxide (ZnO) thin films from aqueous zinc nitrate solution at 80 deg. C onto fluorine doped tin oxide (FTO) coated glass substrates. ZnO thin films were grown between - 0.900 and - 1.025 V vs Ag/AgCl as established by voltammogram. Characterisation of ZnO films was carried out for both as-deposited and annealed films in order to study the effect of annealing. Structural analysis of the ZnO films was performed using X-ray diffraction, which showed polycrystalline films of hexagonal phase with (002) preferential orientation. Atomic force microscopy was used to study the surface morphology. Optical studies identified the bandgap to be {approx} 3.20 eV and refractive index to 2.35. The photoelectrochemical cell signal indicated that the films had n-type electrical conductivity and current-voltage measurements showed the glass/FTO/ZnO/Au devices exhibit rectifying properties. The thickness of ...

2008-04-30

344

Experimental Evaluation And Simulation Of Multi-pixel Cadmium-zinc-telluride Hard-x-ray Detectors  

CERN Document Server

This dissertation describes the evaluation of many-pixel Cadmium-Zinc-Telluride (CdZnTe) hard-X-ray detectors for future use with the High Energy Replicated Optics (HERO) telescope being developed at Marshall Space Flight Center. The detector requirements for the HERO application are good energy resolution (sufficient to resolve cyclotron features and nuclear lines), spatial resolution of ∼200 μm, minimal charge loss of absorbed X rays, and minimal sensitivity to the background environment. This research concentrates on assessing the suitability of these detectors for the focus of HERO, and includes the development of a simulation of the physics involved in an X-ray-detector interaction, a study of the intrinsic material properties, measurements with prototype detectors such as the energy and spatial resolution, charge loss, and X-ray background reduction through 3-dimensional depth sensing. Two types of detectors were available for evaluation. The ...

2004-01-01

345

Electrochemical power generation apparatus and methods  

Energy Technology Data Exchange (ETDEWEB)

Apparatus and methods are described for generating heat and electricity from the consumption of a variety of aluminum products. The method consists of (A) a reaction chamber containing an aqueous electrolyte solution and adapted for introduction therein of aluminum pieces of various shapes and sizes up to a certain maximum predetermined size and for effecting a chemical reaction between said aqueous electrolyte and said aluminum pieces yielding aluminum hydroxide and an intermediate reactant; (B) means for feeding said aluminum pieces into said reaction chamber in small quantities upon demand; (C) means for removing the heat generated in said chamber as a result of said reaction; (D) means for removing said aluminum hydroxide reaction product; and (E) means for oxidizing said intermediate reactant in an electrochemical cell, thereby generating electrical energy. The intermediate reactant is preferably hydrogen or zinc. The latter may be used in a slurry type ...

1981-03-03

346

Electrochemical power generation  

Energy Technology Data Exchange (ETDEWEB)

Apparatus and methods for generating heat and electricity from the consumption of a variety of aluminum products comprise: (A) a reaction chamber containing an aqueous electrolyte solution and adapted for introduction therein of aluminum pieces of various shapes and sizes up to a certain maximum predetermined size and for effecting a chemical reaction between said aqueous electrolyte and said aluminum pieces yielding aluminum hydroxide and an intermediate reactant; (B) means for feeding said aluminum pieces into said reaction chamber in small quantities upon demand; (C) means for removing the heat generated in said chamber as a result of said reaction; (D) means for removing said aluminum hydroxide reaction product; and (E) means for oxidizing said intermediate reactant in an electrochemical cell, thereby generating electrical energy. The intermediate reactant is preferably hydrogen or zinc. The latter may be used in a slurry type zinc/air ...

1983-01-18

347

Elastic properties and structural studies on some zinc-borate glasses derived from ultrasonic, FT-IR and X-ray techniques  

International Nuclear Information System (INIS)

Glasses in the system (1 - x) [29Na2O- 4Al2O3- 67B2O3]- xZnO (0 ? x ? 35 mol%), have been prepared by the melt quenching technique. Elastic properties, X-ray and FT-IR spectroscopic studies have been employed to study the role of ZnO on the structure of the investigated glass system. Elastic properties and Debye temperature have been investigated using sound wave velocity measurements at 4 MHz at room temperature. The results showed that the density increases and the molar volume decreases while both sound velocities and the determined glass transition temperatures decrease with increase in x. X-ray and infrared spectra of the glasses reveal that the borate network consists of diborate units and is affected by the increase in the concentration of ZnO content. These results are interpreted in terms of the decrease in the N4 values (fraction of tetrahedral coordinated boron atoms), and substitution of longer bond lengths of Zn-O in place of shorter B-O bond. The results indicate that ...

2009-05-05

348

Apparent molar volumes and apparent molar heat capacities of aqueous nickel(II) nitrate, copper(II) nitrate, and zinc(II) nitrate at temperatures from (278.15 to 393.15) K at the pressure 0.35 MPa  

Energy Technology Data Exchange (ETDEWEB)

Apparent molar volumes V{sub phi} and apparent molar heat capacities C{sub p,phi} were determined for aqueous solutions of nickel(II) nitrate, copper(II) nitrate, and zinc(II) nitrate at molalities m=(0.01 to 0.5) mol {center_dot} kg{sup -1}, and at the pressure p=0.35 MPa. Solution densities obtained using a vibrating-tube densimeter at T=(278.15 to 368.15) K were used to calculate V{sub phi} values. Heat capacity measurements obtained with a twin fixed-cell, differential-output, power-compensating, temperature-scanning calorimeter at T=(278.15 to 393.15) K were used to calculate values of C{sub p,phi}. Our results were then fitted to functions of m and T and compared to literature values.

2004-05-01

349

A 1500-year record of lead, copper, arsenic, cadmium, zinc level in Antarctic seal hairs and sediments  

Energy Technology Data Exchange (ETDEWEB)

To reconstruct the profiles of heavy metal levels in the South Ocean ecosystem of Antarctica, the concentrations of lead (Pb), copper (Cu), arsenic (As), cadmium (Cd), and zinc (Zn) in seal hairs and lake sediments spanning the past 1500 years from Fildes Peninsula of King George Island and in weathering lake sediments from Nelson Island of West Antarctica were determined. The lead contents in the seal hairs and the weathering sediments show a sharp increase since the late 1800s, very likely due to anthropogenic contamination from modern industries. After the 1980s, the Pb content in seal hairs dropped by one-third, apparently due to the reduced usage of leaded gasoline in the Southern Hemisphere. Copper arises mainly from the weathering process, and its level may be substantially affected by climatic conditions. The concentrations of Cd, As, and Zn do not show any clear temporal trends.

2006-12-01

350

Toxicity of N-substituted aromatics to acetoclastic methanogenic activity in granular sludge  

Energy Technology Data Exchange (ETDEWEB)

N-substituted aromatics are important priority pollutants entering the environment primarily through anthropogenic activities associated associated with the industrial production of dyes, explosives, pestides, and pharmaceuticals. Anaerobic treatment of wastewaters discharged by these industries could potentially be problematical as a result of the high toxicity of N-substituted aromatics. The objective of this study was to examine the structure-toxicity relationship of N-substituted aromatic compounds to acetoclastic methanogenic bacteria. The toxicity was assayed to serum flasks by measuring methane production in granular sludge. Unacclimated cultures were used to minimize the biotransformation of the toxic organic chemicals during the test. The nature and the degree of the aromatic substitution were observed to have a profound effect on the toxicity of the test compound. Nitroaromatic compounds were, on the average, over 500-fold more toxic than their ...

1995-11-01

351

Microbial characterization of a radionuclide- and metal-contaminated waste site  

Energy Technology Data Exchange (ETDEWEB)

The operation of nuclear processing facilities and defense-related nuclear activities has resulted in contamination of near-surface and deep-subsurface sediments with both radionuclides and metals. The presence of mixed inorganic contaminants may result in undetectable microbial populations or microbial populations that are different from those present in uncontaminated sediments. To determine the impact of mixed radionuclide and metal contaminants on sediment microbial communities, we sampled a processing pond that was used from 1948 to 1975 for the disposal of radioactive and metal-contaminated wastewaters from laboratories and nuclear fuel fabrication facilities on the Hanford Site in Washington State. Because the Hanford Site is located in a semiarid environment with average rainfall of 159 mm/year, the pond dried and a settling basin remained after wastewater input into the pond ceased in 1975. This processing pond basin offered a unique ...

1993-04-01

352

Cd(II), Pb(II) and Zn(II) removal from contaminated water by biosorption using activated sludge biomass  

Energy Technology Data Exchange (ETDEWEB)

Biosorption using activated sludge biomass (ASB) as a potentially sustainable technology for the treatment of wastewater containing different metal ions (Cd(II), Pb(II) and Zn(II)) was investigated. ASB metal uptake clearly competed with protons consumed by microbial biomass compared with control tests with non-activated sludge biomass. Biosorption tests confirmed maximum exchange between metal ions and protons at pH 2.0-4.5. It was revealed by the study that the amount of metal ions released from the biomass increased with biomass sludge concentration. The result showed that maximum absorption of metal ions was observed for Cd(II) at pH 3.5, Pb(II) at pH 4.0, and pH 4.5 for Zn(II) ions. The maximum absorption capacities of ASB for Cd(II), Pb(II) and Zn(II) were determined to be 59.3, 68.5 and 86.5%, respectively. The biosorption of heavy metals was directly proportional to ASB stabilization corresponding to a reduction in heavy metals in the order of ...

2010-02-15

353

Application of 'waste' wood-shaving bottom ash for adsorption of azo reactive dye.  

Science.gov (United States)

The utilization of wood-shaving bottom ash (WBA) for the removal of Red Reactive 141 (RR141), an azo reactive dye, was investigated. WBA/H(2)O and WBA/H(2)SO(4) were made by treating WBA with water and 0.1M H(2)SO(4), respectively, to increase adsorption capacity. Adsorption of RR141 from reactive dye solution (RDS) and reactive dye wastewater (RDW) by WBA/H(2)O and WBA/H(2)SO(4) involved the BET surface area and pore size diameter. Properties of adsorbents, effect of contact time, initial pH of solution, dissolved metals and elution studies indicated that the decolorisation mechanism involved both chemical adsorption and precipitation with calcium ions. In addition, the WBA/H(2)SO(4) surface might contain sulphate-cation complexes that were specific to enhancing dye adsorption from RDW. The adsorption isotherm had a best fit by the Freundlich model. Freundlich parameters showed that WBA/H(2)O used more heterogeneous surface than WBA/H(2)SO(4) and activated carbon ...

2008-04-23

354

Trace metals in tap water from Tehran, Iran  

Energy Technology Data Exchange (ETDEWEB)

A total of 272 tap water samples were collected from 68 homes throughout the city of Tehran. Analysis for cadmium, zinc, lead, copper, arsenic, iron and manganese showed some accumulation of these metals in household piping overnight. However, the concentration of all metals was in the parts per billion (ug/l) range and well below international standards. Heavy metals in Tehran's drinking water therefore, do not pose a significant acute health hazard. 19 references, 2 tables.

1986-01-01

355

The secondary slurry-zinc/air battery  

Energy Technology Data Exchange (ETDEWEB)

The rechargeability of the slurry-Zn/air battery was demonstrated with a practical recharge cell that requires minimal hydraulic and mechanical energy for operation. A dendritic Zn was deposited on a Mg plate substrate from which it was easily, periodically and automatically scraped to regenerate dendritic Zn slurries. Excellent discharge results were obtained with the regenerated dendritic Zn slurry, comparable to those obtained with slurries made with mixtures of Zn powder. The dendritic Zn slurry allowed, however, twice the utilization of Zn. 13 refs., 24 figs., 2 tabs.

1989-07-01

356

Synthesis and characterization of nickel(II), chromium(III), cobalt(II), copper(II), zinc(II), and cadmium(II) complexes with isatin- isonicotinoylhydrazone  

International Nuclear Information System (INIS)

A few metal complexes of isatin-isonicotinoylhydrazone with Ni(II), Cr(III), Co(II), Cu(II), Zn(II) and Cd(II) have been prepared and characterized on the basis of elemental analyses, infrared and electronic spectra as well as "1H NMR spectra, conductivity and magnetic measurements. In view of the results obtained, it has been found that two molecules of isatin-isonicotinoylhydrazone are chelated to the central metal ion as bis-uninegative ONO tridentate ligand forming non-electrolytic octahedral metal complexes. (author)

1997-03-01

357

Structural origin of optical bowing in semiconductor alloys p  

Energy Technology Data Exchange (ETDEWEB)

The principle of conservation and transferability of chemical bonds explains the recent discovery by extended x-ray absorption fine-structure measurements of two unequal anion-cation bond lengths R/sub A/C and R/sub B/C in A/sub x/B/sub 1-x/C zinc-blende semiconductor alloys despite the close adherence of the lattice constant to the average value (Vegard rule). This bond alternation, manifested as a structural distortion to a local chalcopyrite coordination around the anions, explains also most of the observed optical bowing in semiconductor alloys.

1983-08-22

358

Structural origin of optical bowing in semiconductor alloys p  

International Nuclear Information System (INIS)

The principle of conservation and transferability of chemical bonds explains the recent discovery by extended x-ray absorption fine-structure measurements of two unequal anion-cation bond lengths R/sub A/C and R/sub B/C in A/sub x/B/sub 1-x/C zinc-blende semiconductor alloys despite the close adherence of the lattice constant to the average value (Vegard rule). This bond alternation, manifested as a structural distortion to a local chalcopyrite coordination around the anions, explains also most of the observed optical bowing in semiconductor alloys.

359

Relationship between copper speciation and cyanobacterial distribution in harbors and other coastal environments. Final report, 1 July 1993--1 November 1998  

Energy Technology Data Exchange (ETDEWEB)

The long term goal is to determine the ecological importance of specific toxic metals (copper and zinc) in harbors, through an understanding of their chemistry and biological effects at the base of marine food chains. This work provides information on potential problems with Zn and Cu, which may help to foresee problems in the future. Anthropogenic inputs of both metals are increasing; they are derived from diverse sources and are a simple function of population growth in coastal regions.

1998-11-01

360

Progress towards a 20 Ah/12 V zinc/air battery  

Energy Technology Data Exchange (ETDEWEB)

Electrode areas, for the bifunctional O{sub 2}-electrodes and the pasted Zn-electrodes, have been successfully scaled up from 25 cm{sup 2} up to 250 cm{sup 2}. A filter press type cell was used to measure the cycle life of larger electrodes (100 cm{sup 2}). Up to now, more than 100 charge-discharge cycles (900 hours) with these scaled up Zn/O{sub 2}-cells could be demonstrated. (author) 2 figs., 2 refs.

1997-06-01

361

Probable role of trace elements of some medicinal plants in cardio-vascular diseases  

International Nuclear Information System (INIS)

A number of herbal drugs are used in the Unani (Greco-Arab) System of Medicine for cardiovascular diseases. The herbs were analyzed by flame AAS and ICP-AES to determine if their therapeutic actions can be associated with the elements present in them. Cadmium, cobalt, chromium, copper, iron, potassium, magnesium, manganese, sodium, nickel, phosphorus, lead and zinc were some of the elements which play various roles in cardiovascular affections. An effort was made to correlate the role of these elements in cardiac diseases. (Auth.). 2 tabs., 32 refs.

362

Primary explosives  

Energy Technology Data Exchange (ETDEWEB)

The present invention provides a compound of the formula (Cat).sup.+.sub.z[M.sup.++(5-nitro-1H-tetrazolato-N2).sup.-.sub.x(H.sub.2- O).sub.y] where x is 3 or 4, y is 2 or 3, x+y is 6, z is 1 or 2, and M.sup.++ is selected from the group consisting of iron, cobalt, nickel, copper, zinc, chromium, and manganese, and (Cat).sup.+ is selected from the group consisting of ammonium, sodium, potassium, rubidium and cesium. A method of preparing the compound of that formula is also disclosed.

2009-03-03

363

Primary explosives  

Energy Technology Data Exchange (ETDEWEB)

The present invention provides a compound of the formula (Cat).sup.+.sub.z[M.sup.++(5-nitro-1H-tetrazolato-N2).sup.-.sub.x(H.sub.2- O).sub.y] where x is 3 or 4, y is 2 or 3, x+y is 6, z is 1 or 2, and M.sup.++ is selected from the group consisting of iron, cobalt, nickel, copper, zinc, chromium, and manganese, and (Cat).sup.+ is selected from the group consisting of ammonium, sodium, potassium, rubidium and cesium. A method of preparing the compound of that formula is also disclosed.

2011-01-25

364

Phase diagrams  

International Nuclear Information System (INIS)

The description is presented of binary phase diagrams of titanium alloyed with the following elements: silver, aluminium, arsenic, gold, boron, barium, beryllium, bismuth, carbon, calcium, cadmium, cobalt, chromium, copper, iron, gallium, germanium, hydrogen, hafnium, indium, iridium, potassium, lithium, magnesium, manganese, molybdenum, nitrogen, sodium, niobium, nickel, oxygen, osmium, phosphorus, lead, palladium, platinum, plutonium, rhenium, lanthanium, cerium, preseodymium, neodymium, gadolinium, erbium, terbium, thulium, lutetium, rhodium, ruthenium, scandium, silicon, tin, strontium, tantalum, technetium, thorium, uranium, vanadium, tungsten, yttrium, ytterbium, zinc and zirconium.

365

Non-nitro radiation sensitizers  

International Nuclear Information System (INIS)

This short communication aims to update the review of non-nitro radiation sensitizers (Shenoy and Singh 1985) and correct omissions. Work is mentioned and bibliography given for studied of cis-platinum, potassium permanganate, cobalt hexammine, sodium bromide, dimethylsulphoxide, zinc and copper ions, organic nitroxyl free radicals (TAN,TMPN and NPPN + PNAP), halogenated pyrimidines, organic and inorganic iodine containing compounds, diacetyl, acetone and acetophenone, rho-hydrobenzoic acid and its esters, pentobarbitone and secobarbitone, heparin and 9-anilinoacridines, dehydropiandosterone and paraquat. (U.K.).

366

Magnetic properties of glasses from geothite industrial wastes recycling (FeOOH)  

International Nuclear Information System (INIS)

It has been carried out the magnetic properties determination for high iron oxide content glasses series obtained from a geothite red mud waste from the zinc hydrometallurgy and dolomite and glass cullet as main raw materials. It has been determined the magnetic susceptibility and magnetization values for the glasses here investigated. The results suggest that the magnetic behaviour are depending on the glass chemical composition, so that glasses can be differently classified like ferrimagnetic, ferromagnetic, superparamagnetic and paramagnetic. (Author) 6 refs.

367

Long-term monitoring of microleakage of dental cements by radiochemical diffusion  

International Nuclear Information System (INIS)

Radioactive "1"4C sucrose was found to be an ideal marker for microleakage because it did not penetrate tooth tissue, dental cement, or mounting resin. The main finding is that the adhesive cements--the glass-ionomer and polycarboxylate--are significantly more effective at preventing microleakage than are the traditional phosphate cements--silicate and zinc phosphate. The differences can be as high as two orders of magnitude. The adhesive cements provide almost perfect and reliable seals. By contrast, the nonadhesive cements are erratic sealants with most of the restorations leaking.

368

Local Heine-Abarenkov model potential for III-V and II-VI covalent compounds  

Energy Technology Data Exchange (ETDEWEB)

A local Heine-Abarenkov model potential is proposed for zinc blende-type crystals. The potential parameters are determined by satisfying the zero pressure condition and the first zero of the empirical pseudopotential interpolated from band calculations. Two sets of parameters are presented for thirteen tetrahedral compounds such as AlP, AlAs, AlSb, GaP, GaAs, GaSb, InP, InAs, InSb, ZnS, ZnSe, ZnTe, and CdTe.

1983-10-01

369

Electric vehicle getting up speed soon?; Kommt E-Mobil in Fahrt?  

Energy Technology Data Exchange (ETDEWEB)

A novel zinc-air battery might soon enhance the mileage and applications of electric vehicles. The battery named Zoxy battery weighs 80% less than a conventional lead battery, but has an equal amount of energy in store. (orig./CB) [Deutsch] Eine neuartige Zink-Luft-Batterie koennte vor allem dem Elektroauto groessere Reichweiten und neue Einsatzmoeglichkeiten erschliessen. Die sogenannte Zoxy-Batterie ist 80% leichter als eine herkoemmliche Bleibatterie - bei gleichem Energiegehalt. (orig.)

1997-12-31

370

Effects of iodine deficiency on metabolism of metal ions in the rat brain by nuclear analytical techniques  

International Nuclear Information System (INIS)

Iodine deficiency disorders (IDD) are one of most common nutritional deficiencies in the world. The nuclear analytical methods (ENAA, SRXRF and XRF) were employed to study the effect of iodine deficiency on the metal ion changes during the stage of brain development, combined with biochemical methods. The results show that the distributions of iron, copper and zinc varied to different extent in different brain regions and subcellular fractions of the ID rat brains. These distributional changes of trace elements might be associated with the brain damage caused by the iodine deficiency. (author)

2006-09-01

371

Dialysis kinetics of motor oil additives  

Energy Technology Data Exchange (ETDEWEB)

Studies dialysis kinetics of zinc dialkyldithiophosphates, detergent-dispersing agents, alkyl-phenols and base oils. It was established that diffusion kinetics of oil hydrocarbons through membrane of individual compounds and narrow fractions is described by Brinzinger's formula, which is identical to the kinetic reaction formula of the 1st order. It was shown that dialysis can be utilized to determine the content of the ''active substance'' only in sulphonate and alkylsalycilate additives. Increasing temperature from 20 to 40/sup 0/ results in an increased dialysis constant for all studied products by 1.4-1.9 times.

1982-01-01

372

Anodic oxide coatings on metals and anodic protection /2nd revised and enlarged edition/. Anodnye oksidnye pokrytiia na metallakh i anodnaia zashchita /2nd revised and enlarged edition/  

Energy Technology Data Exchange (ETDEWEB)

The theoretical principles underlying the formation of oxide and, in particular, anodic oxide coatings on metals produced by chemical oxidation, anodizing in solutions, and anodizing in cold plasmas are reviewed. The mechanisms and conditions of anodic oxidation are described, and the structure of anodic oxide coatings on aluminum, magnesium, beryllium, zinc, cadmium, iron, cobalt, nickel, titanium, zirconium, tantalum, and chromium alloys is examined. Attention is also given to various applictins of anodized coatings. 54 references.

1985-01-01

373

ASARCO to pay over $59 million for damages and cleanup costs at Denver smelting facility  

Science.gov (United States)

Since 1901, ASARCO, Inc. has owned and operated an 89-acre cadmium-refining smelter in the Globeville neighborhood of north Denver, Colorado. According to complaints filed by EPA and local residents, operations at the smelter have allegedly contaminated the air, ground water, surface water, and soil; contamination from arsenic, cadmium, lead, and zinc has occurred both onsite and offsite. EPA proposed to add the site to the National Priorities List (NPL) in May 1993.

1993-11-01

374

A hierarchical lattice structure and formation mechanism of ZnO nano-tetrapods  

International Nuclear Information System (INIS)

The existence of characteristic longitudinal optical and transverse optical phonons of cubic ZnO in ZnO nano-tetrapods is determined by Raman spectroscopy and first-principles calculations. Stacking sequence change at the boundary of the core and legs is also identified by high-resolution transmission electron microscopy. Based on this experimental and theoretical evidence, we demonstrate that the lattice structure of ZnO nano-tetrapods is hierarchical with a zinc blende core connecting to four wurtzite legs. Furthermore, we establish the atomic configuration and propose a formation mechanism induced by Laplace pressure in the initial growth stage of ZnO nano-tetrapods.

2009-08-12

375

Verification of zinc injection applicability to Japanese BWRs  

Energy Technology Data Exchange (ETDEWEB)

The verification test program on zinc injection applicability to Japanese BWRs was started in 1997. Laboratory tests using high temperature water loops under BWR reactor water conditions are in progress. This paper is an interim report on results obtained so far. Co-58 and Zn-65 were simultaneously used in the Co radioactivity buildup test to evaluate zinc injection suppression effects towards cobalt deposition on pre-oxidized stainless steel. The following results were obtained. The Co deposition was suppressed effectively by Zn injection, even when there was a pre-oxide film. For the test piping that had the pre-oxide film formed under the NWC (normal water chemistry) condition, when soaked under the HWC (hydrogen water chemistry) condition a large amount of Co-58 was taken into a small part of the inner layer. The distribution ratio of Co-58 in the inner layer and outer layer of the oxide film was almost the same for both the pre-oxidized ...

2002-07-01

376

The influence of modified water chemistries on metal oxide films, activity build-up and stress corrosion cracking of structural materials in nuclear power plants  

Energy Technology Data Exchange (ETDEWEB)

The primary coolant oxidises the surfaces of construction materials in nuclear power plants. The properties of the oxide films influence significantly the extent of incorporation of actuated corrosion products into the primary circuit surfaces, which may cause additional occupational doses for the maintenance personnel. The physical and chemical properties of the oxide films play also an important role in different forms of corrosion observed in power plants. This report gives a short overview of the factors influencing activity build-up and corrosion phenomena in nuclear power plants. Furthermore, the most recent modifications in the water chemistry to decrease these risks are discussed. A special focus is put on zinc water chemistry, and a preliminary discussion on the mechanism via which zinc influences activity build-up is presented. Even though the exact mechanisms by which zinc acts are not yet known, it is assumed ...

1999-03-01

377

New electric-vehicle batteries  

Energy Technology Data Exchange (ETDEWEB)

Electric vehicles that can`t reach trolley wires need batteries. In the early 1900`s electric cars disappeared when owners found that replacing the car`s worn-out lead-acid battery costs more than a new gasoline-powered car. Most of today`s electric cars are still propelled by lead-acid batteries. General Motors` Impact, for example, uses starting-lighting-ignition batteries, which deliver lots of power for demonstrations, but have a life of less than 100 deep discharges. Now promising alternative technology has challenged the world-wide lead miners, refiners, and battery makers into forming a consortium that sponsors research into making better lead-acid batteries. Horizon`s new bipolar battery delivered 50 watt-hours per kg (Wh/kg), compared with 20 for ordinary transport-vehicle batteries. The alternatives are delivering from 80 Wh/kg (nickel-metal hydride) up to 200 Wh/kg (zinc-bromine). A Fiat Panda travelled 260 km on a single charge of its ...

1994-12-31

378

Use of boron waste as an additive in red bricks  

International Nuclear Information System (INIS)

In boron mining and processing operations, large amounts of clay containing tailings have to be discarded. Being rich in boron, the tailings do not only cause economical loss but also pose serious environmental problems. Large areas have to be allocated for waste disposal. In order to alleviate this problem, the possibility of using clayey tailings from a borax concentrator in red brick manufacturing was investigated. Up to 30% by weight tailings addition was found to improve the brick quality.

379

Time-resolved measurement of a self-amplified free-electron laser  

International Nuclear Information System (INIS)

We report on a time-resolved measurement of self-amplified spontaneous emission free-electron laser (FEL) pulses. We observed that the spikes in such FEL pulses have an intrinsic positive chirp and the energy chirp in the electron bunch mapped directly into the FEL output. The measurement also provides rich information on the statistics of the FEL pulses.

2003-07-11

380

The Membrane Bound LRR Lipoprotein Slr, and the Cell Wall-Anchored M1 Protein from Streptococcus pyogenes Both Interact with Type I Collagen  

UK PubMed Central (United Kingdom)

Streptococcus pyogenes is an important human pathogen and surface structures allow it to adhere to, colonize and invade the human host. Proteins containing leucine rich repeats (LRR)...Full Text Available

381

Quarterly technical progress report - base program on energy related research. Quarterly report, May 1--July 31, 1994  

Energy Technology Data Exchange (ETDEWEB)

Research is presented on oil and gas technologies, advanced systems, soil remediation and remediation of acid mine drainage, applied science research in plastics and petroleum coprocessing, and fossil fuel and hydrocarbon conversion using a hydrogen rich plasmas.

1997-05-01

382

Quarterly technical progress report - base program on energy related research. Quarterly report, February 1--April 30, 1994  

Energy Technology Data Exchange (ETDEWEB)

Research is presented on oil and gas technologies, advanced systems for fossil fuels, environmental technologies for remediation and waste management, applied energy science on heavy oil and plastics coprocessing, and fossil fuel and hydrocarbon conversion using hydrogen rich plasma.

1997-05-01

383

Proton-Transfer-Reaction Mass Spectrometry as a New Tool for Real Time Analysis of Root-Secreted Volatile Organic Compounds in Arabidopsis1  

UK PubMed Central (United Kingdom)

Plant roots release about 5% to 20% of all photosynthetically-fixed carbon, and as a result create a carbon-rich environment for numerous rhizosphere organisms, including plant pathogens and symbiotic...Full Text Available

2004-05-01

384

Perlinhibin, a Cysteine-, Histidine-, and Arginine-Rich Miniprotein from Abalone (Haliotis laevigata) Nacre, Inhibits In Vitro Calcium Carbonate Crystallization  

UK PubMed Central (United Kingdom)

We have isolated a 4.785 Da protein from the nacreous layer of the sea snail Haliotis laevigata (greenlip abalone) shell after demineralization with acetic acid. The sequence of 41...Full Text Available

2007-08-15

385

P and e identification capabilities CAPRICE  

Energy Technology Data Exchange (ETDEWEB)

The cosmic antiparticle ring imaging Cherenkov experiment (CAPRICE) flew on a stratospheric balloon 8-9 August 1994 over northern Canada and collected data for more than 21 hours with less than 5 g/cm{sup 2} of residual atmosphere. The instrument includes a solid radiator RICH detector and an electromagnetic calorimeter for particle identification in the magnetic spectrometer. Preliminary antiproton and positron identification capabilities are presented.

1995-09-01

386

Oil shale resources of Nova Scotia  

Energy Technology Data Exchange (ETDEWEB)

Oil shale occurrences have been historically reported in the Cape Breton Island, northern mainland and southern mainland areas of Nova Scotia. Twelve of these occurrences were investigated for this study. Rocks from three of the areas gave oil yields of less than 25 litres per tonne (below oil shale grade) while the remainder gave oil yields greater than 25 litres per tonne (above oil shale grade). The rock types of oil shale grade include silicate-rich shale, carbonaceous shale locally transitional to coal, limy shale and petroliferous limestone associated with coal, silicate-rich shale and cannel shale associated with coal and silicate-rich shale, cannel shale and boghead shale associated with coal. The Stellarton Basin represents the province's largest oil shale resource with an estimated 825 x 10{sup 6} tonnes of oil shale and 168 x 10{sup 6} barrels of shale oil in situ. The Antigonish Basin represents the ...

1990-01-01

387

Oil shale in China: resources and utilization  

Energy Technology Data Exchange (ETDEWEB)

China is continuing to extract oil from kerogen shale despite having a crude production capacity of 100 Mt a year. Among the reasons for this policy are the country's rich oil shale resources, comparatively mature extraction techniques, and a comprehensive utilization of the shale that has proved to be economically profitable. China has oil shale deposits of 340 Gt, equivalent to 24.5 Gt of shale oil, to rank fourth in the world after the U.S., Brazil, and the Soviet Union.

1984-05-01

388

NAME=\\  

Wastenet

...the huge volumes of ephemera amassed by the Colonial Office to record the coronation celebrations of 1937 and 1953 to the small illustrated manuscript account of Tobago penned by its governor in 1810, from one of the first European accounts of Ethiopia to be published to Winston Churchillrsquo;s valedictory letter of 1922 to Colonial Office staff, the exhibits provide a snapshot of the riches to be explored within this matchless collection. Explore ...

389

Halflives of rp-Process Waiting Point Nuclei  

Energy Technology Data Exchange (ETDEWEB)

The fragment separator at GSI, Darmstadt, has been used to produce and separate very proton rich nuclei in the {sup 100}Sn region. By fragmentation of a {sup 112}Sn beam at 1 A{center_dot}GeV we produced nuclei along the rp-process path between {sup 77}Y and {sup 98}In. By implanting these ions into a silicon detector stack we were able to determine their halflives. Preliminary data are presented.

1999-12-31

390

Evaluation of potential hydrocarbon sources in lacustrine facies of Newark Supergroup, eastern United States  

Energy Technology Data Exchange (ETDEWEB)

Lacustrine rocks are a significant component of many rift-valley sequences. Comparisons of both active and ancient rift valleys indicate that the lacustrine facies are commonly rich in organic matter and may be important sources for oil. For example, Holocene sediments in Lake Tanganyika and Cretaceous lacustrine rocks in west Africa contain as much as 12% and 20% TOC, respectively. The Newark Supergroup contains abundant lacustrine rocks. The widespread occurrence of black shales, the general similarity to known organically rich rift systems, and a few isolated geochemical analyses have caused some speculation about the potential of the Newark Supergroup to be an effective source of oil and gas. Sufficient geochemical analyses are available from lacustrine rocks in the Newark, Connecticut, and Deep River basins to evaluate their potential as hydrocarbon sources. In general, both the quantity and quality of organic matter in these rocks are ...

1985-02-01

391

Effects of pseudomonas toxin A, diphtheria toxin, and cholera toxin on electrical characteristics of turtle bladder.  

UK PubMed Central (United Kingdom)

Rapidly developing changes in the short-circuiting current (Isc), conductance (G), and potential (PD) of turtle bladders in Na-rich or Na-free media are seen after the mucosal addition, at 10 nM, of...Full Text Available

1979-07-01

392

ESCA-investigations of the passive films formed on austenitic stainless steels in nitric acid  

International Nuclear Information System (INIS)

By means of ESCA the composition and the thickness of passive films formed on austenitic stainless steels were investigated after the attack of nitric acid at various temperatures and acid concentrations. The outermost layers of the oxide film consist of SiO_2, then a layer rich of Cr-oxid follows, containing also some Mo in the four- and sixvalent state. Ni does not contribute to the oxide film. Cr is also enriched in the metal just below the oxide film. (orig.).

1978-01-01

393

Discordant expression and variable numbers of neighboring GGA- and GAA-rich triplet repeats in the 3' untranslated regions of two groups of messenger RNAs encoded by the rat polymeric immunoglobulin receptor gene.  

UK PubMed Central (United Kingdom)

An unusual S1-nuclease sensitive microsatellite (STMS) has been found in the single copy, rat polymeric immunoglobulin receptor gene (PIGR) terminal exon. In Fisher rats, elements within or beyond the...Full Text Available

1995-04-11

394

Deep-sea mystery solved: astonishing larval transformations and extreme sexual dimorphism unite three fish families  

UK PubMed Central (United Kingdom)

The oceanic bathypelagic realm (1000–4000 m) is a nutrient-poor habitat. Most fishes living there have pelagic larvae using the rich waters of the upper 200 m. Morphological...Full Text Available

2009-04-23

395

Calculation of. beta. -decay half-lives with the proton-neutron quasiparticle RPA  

Energy Technology Data Exchange (ETDEWEB)

The ..beta.. decay half-lives of neutron-rich isotopes with Z=24-28 are calculated in the QRPA with a Gamow-Teller residual interaction. For odd-mass and odd-odd systems QRPA phonon correlations are introduced to quasiparticle transitions in first-order perturbation. The calculated half-lives agree very well with the experimental values. For later application of this model to nuclei far from stability, we have examined the dependence of the calculated half-lives on the model parameters.

1988-07-07

396

Calculation of #beta#-decay half-lives with the proton-neutron quasiparticle RPA  

International Nuclear Information System (INIS)

The #beta# decay half-lives of neutron-rich isotopes with Z=24-28 are calculated in the QRPA with a Gamow-Teller residual interaction. For odd-mass and odd-odd systems QRPA phonon correlations are introduced to quasiparticle transitions in first-order perturbation. The calculated half-lives agree very well with the experimental values. For later application of this model to nuclei far from stability, we have examined the dependence of the calculated half-lives on the model parameters. (orig.).

397

B(s) properties at the Tevatron  

Energy Technology Data Exchange (ETDEWEB)

The Tevatron collider at Fermilab provides a very rich environment for the study B{sub s} mesons. In this paper they show a few selected topics from the CDF and D0 collaborations, giving special attention to the B{sub s} Mixing analyses. This note corresponds to the proceedings of the Hadron Collider Physics 2005 conference.

2005-11-01

398

Administration of a Decoction of Sucrose- and Polysaccharide-Rich Radix Astragali (Huang Qi) Ameliorated Insulin Resistance and Fatty Liver but Affected Beta-Cell Function in Type 2 Diabetic Rats  

UK PubMed Central (United Kingdom)

The current investigation attempted to confirm the beneficial actions of a chemically characterized Radix Astragali decoction (AM-W) against type 2 diabetic (T2D) Sprague-Dawley (SD) rats. Using a case/control...Full Text Available

2011-01-01

399

A neutron activation analysis of iridium concentration in Yamato carbonaceous chondrite  

International Nuclear Information System (INIS)

Iridium concentration in extra-terrestrial bodies is an important quantity in relation to Ir-rich geological layers. Ir concentration of a Yamato carbonaceous chondrite (Y-793321) has been measured by a neutron activation method. The measurement yields a value of (0.57#+-#0.06) #mu#g per gramme for the chondrite. 4 refs.; 1 figure.

400

The seeded growth of calcium sulfate dihydrate crystals in NaCl solutions up to 6 m and 90 C  

Energy Technology Data Exchange (ETDEWEB)

The kinetics of calcium sulfate crystal growth is of importance in various fields, such as geochemistry, desalination technology, petroleum industry, and water and wastewater treatment. The seeded crystal growth rate of calcium sulfate dihydrate was measured as a function of supersaturation in NaCl electrolyte solutions from 0 to 6 m at temperatures of 25, 50, 70, and 90 C. The growth followed a second-order parabolic rate law with activation energies greater than 53 kJ/mol which suggested the surface reaction as the rate-limiting step. It was observed that the rate constant and the activation energy are solution composition dependent. The rate constant increases with NaCl concentration up to 3 molal and then begins to fall slightly. The activation energy dropped from 61 kJ/mol in the pure Ca-SO[sub 4]H[sub 2]O system to 53 kJ/mol in 3.0 m NaCl solutions. The electrolyte effect was similar to the crystal solubility behavior in aqueous electrolyte solutions ...

1994-03-15

401

The Oak Ridge Y-12 Plant biological monitoring and abatement program for East Fork Poplar Creek  

Energy Technology Data Exchange (ETDEWEB)

In May 1985, a National Pollutant Discharge Elimination System permit was issued for the Oak Ridge Y-12 Plant, a nuclear weapons components production facility located in Oak Ridge, Tennessee, and operated by Martin Marietta Energy Systems, Inc., for the US Department of Energy. As a condition of the permit, a Biological Monitoring and Abatement Program (BMAP) was developed to demonstrate that the effluent limitations established for the Oak Ridge Y-12 Plant protect the classified uses of the receiving stream (East Fork Poplar Creek), in particular, the growth and propagation of fish and aquatic life, as designated by the Tennessee Department of Health and Environment. A second purpose for the BMAP is to document the ecological effects resulting from implementation of a water pollution control program that will include construction of nine new wastewater treatment facilities over the next 4 years. Because of the complex nature of the effluent discharged to East ...

1989-10-01

402

Test of electron beam technology on Savannah River Laboratory low-activity aqueous waste for destruction of benzene, benzene derivatives, and bacteria  

Energy Technology Data Exchange (ETDEWEB)

High energy radiation was studied as a means for destroying hazardous organic chemical wastes. Tests were conducted at bench scale with a {sup 60}Co source, and at full scale (387 l/min) with a 1.5 MV electron beam source. Bench scale tests for both benzene and phenol included 32 permutations of water quality factors. For some water qualities, as much as 99.99% of benzene or 90% of phenol were removed by 775 krads of {sup 60}Co irradiation. Full scale testing for destruction of benzene in a simulated waste-water mix showed loss of 97% of benzene following an 800 krad dose and 88% following a 500 krad dose. At these loss rates, approximately 5 Mrad of electron beam irradiation is required to reduce concentrations from 100 g/l to drinking water quality (5 {mu}g/l). Since many waste streams are also inhabited by bacterial populations which may affect filtering operations, the effect of irradiation on those populations was also studied. {sup 60}Co and electron beam ...

1993-08-01

403

Study on biosorption kinetics and thermodynamics of uranium by Citrobacter freudii  

Energy Technology Data Exchange (ETDEWEB)

Biosorption has been developed as an effective and economic method to treat wastewater containing low concentrations of metal pollutants. In this study, a bacterium, Citrobacter freudii, was used as a biosorbent to adsorb uranium ions. The thermodynamics and kinetics of this adsorption, as well as its mechanism, were investigated. The results indicated that the biosorption rate could be better described by a pseudo 2nd-order model than a pseudo 1st-order model. The adsorption of U (VI) proceeded very rapidly in the first 30 min and subsequently slowed down continuously for a long period. The biosorption isotherm of uranium by C. freudii could be described well by the Langmuir or Freundlich isotherm, and the latter was better. The thermodynamics parameters, {delta}H{sup o}, {delta}G{sup o}, and {delta}S{sup o} were calculated according to the results of the experiment, which showed this biosorption as being endothermic and spontaneous. The authors investigated the ...

2008-01-15

404

Soil water retention at varying matric potentials following repeated wetting with modestly saline-sodic water and subsequent air drying  

Energy Technology Data Exchange (ETDEWEB)

Coal bed natural gas (CBNG) development in the Powder River (PR) Basin produces modestly saline, highly sodic wastewater. This study assessed impacts of wetting four textural groups (0-11%, 12-22%, 23 -33%, and > 33% clay (g clay/100 g soil) x 100%))with simulated PR or CBNG water on water retention. Soils received the following treatments with each water quality: a single wetting event, five wetting and drying events, or five wetting and drying events followed by leaching with salt-free water. Treated samples were then resaturated with the final treatment water and equilibrated to -10, -33, -100, -500, or -1,500 kPa. At all potentials, soil water retention increased significantly with increasing clay content. Drought-prone soils lost water-holding capacity between saturation and field capacity with repeated wetting and drying, whereas finer textured soils withstood this treatment better and had increased water-retention capacity at lower matric potentials.

2007-07-01

405

Selecting soil amendment materials for removal of phosphorus  

Energy Technology Data Exchange (ETDEWEB)

Phosphorus sorption capacities of several different materials including Merribrook soil (a loamy sand) and some industrial solid wastes (red mud neutralized with gypsum, fly ash, bottom ash and black oxide) were determined in sorption isotherms by Langmuir and Freundlich equations. The materials were characterized by bulk density, particle density, total porosity and particle size distributions. Red mud gypsum possessed the best sorption capacity based on the Langmuir maxima. Alkaline fly ash and Merribrook soil had lower sorption maxima compared to the red mud gypsum. Bottom ash and acidic fly ash had very low sorption capacity at low concentrations. Merribrook soil had the highest hydraulic conductivity. The results suggested that alkaline fly ash may be a promising amendment for coarse sand bed to enhance phosphorus removal. Merribrook soil appears to be suitable for on-site wastewater treatment.

1994-12-31

406

Reducing CSOs and giving the river back to the public: innovative combined sewer overflow control and riverbanks restoration of the St. Charles River in Quebec City.  

Science.gov (United States)

After the construction of its wastewater treatment plants, the City of Quebec began to implement overflow control in wet weather to ultimately meet the effluent discharge objectives, i.e. no more than two overflows per summer season in the St. Lawrence River and no more than four in the St-Charles River. After several years of studies to determine which management strategies would best suit the purpose, and to propose optimum solutions, a first project to implement optimal and predictive management in real time, called "Pilot", came to life in 1999. Construction in phases soon followed and the work was completed in the fall of 2009. As a result, requirements with regard to environmental rejects were met in two sectors, namely the St-Charles River and the Jacques-Cartier Beach, and aquatic recreational activities could resume. Meanwhile, the City also worked at giving back access to the water courses to the public by developing sites at the Jacques-Cartier Beach and ...

2011-01-01

407

Radioactive contamination of fish, shellfish, and waterfowl exposed to Hanford effluents: Annual summaries, 1945--1972. Hanford Environmental Dose Reconstruction Project  

Energy Technology Data Exchange (ETDEWEB)

The objective of the Hanford Environmental Dose Reconstruction Project (HEDR) is to estimate the potential radiation doses received by people living within the sphere of influence of the Hanford Site. A potential critical pathway for human radiation exposure is through the consumption of waterfowl that frequent onsite waste-water ponds or through eating of fish, shellfish, and waterfowl that reside in/on the Columbia River and its tributaries downstream of the reactors. This document summarizes information on fish, shellfish, and waterfowl radiation contamination for samples collected by Hanford monitoring personnel and offsite agencies for the period 1945 to 1972. Specific information includes the types of organisms sampled, the kinds of tissues and organs analyzed, the sampling locations, and the radionuclides reported. Some tissue concentrations are also included. We anticipate that these yearly summaries will be helpful to individuals and organizations ...

1992-07-01

408

Radioactive contamination of fish, shellfish, and waterfowl exposed to Hanford effluents: Annual summaries, 1945--1972  

Energy Technology Data Exchange (ETDEWEB)

The objective of the Hanford Environmental Dose Reconstruction Project (HEDR) is to estimate the potential radiation doses received by people living within the sphere of influence of the Hanford Site. A potential critical pathway for human radiation exposure is through the consumption of waterfowl that frequent onsite waste-water ponds or through eating of fish, shellfish, and waterfowl that reside in/on the Columbia River and its tributaries downstream of the reactors. This document summarizes information on fish, shellfish, and waterfowl radiation contamination for samples collected by Hanford monitoring personnel and offsite agencies for the period 1945 to 1972. Specific information includes the types of organisms sampled, the kinds of tissues and organs analyzed, the sampling locations, and the radionuclides reported. Some tissue concentrations are also included. We anticipate that these yearly summaries will be helpful to individuals and organizations ...

1992-07-01

409

Radioactive contamination of fish, shellfish, and waterfowl exposed to Hanford effluents: Annual summaries, 1945--1972  

International Nuclear Information System (INIS)

The objective of the Hanford Environmental Dose Reconstruction Project (HEDR) is to estimate the potential radiation doses received by people living within the sphere of influence of the Hanford Site. A potential critical pathway for human radiation exposure is through the consumption of waterfowl that frequent onsite waste-water ponds or through eating of fish, shellfish, and waterfowl that reside in/on the Columbia River and its tributaries downstream of the reactors. This document summarizes information on fish, shellfish, and waterfowl radiation contamination for samples collected by Hanford monitoring personnel and offsite agencies for the period 1945 to 1972. Specific information includes the types of organisms sampled, the kinds of tissues and organs analyzed, the sampling locations, and the radionuclides reported. Some tissue concentrations are also included. We anticipate that these yearly summaries will be helpful to individuals and organizations ...

410

Potential biogas scrubbing using a high rate pond  

Energy Technology Data Exchange (ETDEWEB)

The potential to scrub biogas in a high rate pond (HRP) was evaluated using apparatus designed to maximize gas-liquid contact. Experiments compared the removal of carbon dioxide from synthetic biogas by an 'in-pond angled gutter' to that by a simulated 'counter-current pit'. Results showed that the counter current pit has potential for use in biogas scrubbing, with synthetic biogas carbon dioxide composition consistently reduced from 40% to<5%. The in-pond angled gutter was less effective due to bubble coalescence which reduced the total bubble surface surface area available for gas transfer. Measurement of oxygen levels in the scrubbed biogas showed that despite supersaturation of oxygen in the HRP water, there was little transfer to the biogas, so that explosive methane/oxygen mixtures would not be formed. Theoretical calculations indicated that the amount of biogas likely to be formed during anaerobic treatment of municipal ...

2005-07-01

411

Maryland mill will recycle wastepaper, reclaim water  

Energy Technology Data Exchange (ETDEWEB)

A $200 million paper mill being built in Hagerstown, Md., is expected to produce 150,000 bone-dry short tons per year of de-inked, market-grade pulp for writing and printing paper. The 1st Urban Fibers facility, the largest capital project in Hagerstown's history, is slated for completion in the spring. Landegger Recycled Fiber Corp. will operate and maintain the 200,000-square-foot recycling mill and 60,000-square-foot water reclamation plant. The wastepaper recycling mill plans to minimize waste and pollution by: reclaiming 635 tons per day of 100 percent post-consumer mixed office waste from the solid waste stream; saving more than 16 million cubic feet of landfill area per year; conserving the fiber equivalent of 6,700 trees per day; using no chlorine; saving about 2,000 gallons of water and 4,000 kilowatt hours of electricity per ton of throughput, compared to virgin fiber mills; reusing treated wastewater, reducing effluent discharge by 65 percent; ...

1995-02-01

412

Management of industrial solid wastes in Alexandria, Egypt  

Science.gov (United States)

This paper presents a summary of the first phase of the EPA project, which encompasses surveys of residues from industrial sources in Alexandria. Studies to date indicate that wastes from various industries can be recovered economically. Wastes such as tin cans, glass, wastepaper, and food residues from processing of fruits, starch, and beer are examples of reusable industrial wastes in Egypt. The results of experimental studies for reuse of residues from oil refining, starch and yeast processing, and steel pickling are presented. Spent clay from edible oil refining is currently discarded, causing both handling and disposal problems. This clay contains as much as 40% oil; 90% can be recovered by extraction. The recovered oil can be successfully used in soap production, and the spent clay can be reused in oil bleaching. Other examples include starch and yeast wastes, which can be used for animal feed, and spent pickling liquor, which can be used as a coagulant aid for treating paper ...

1983-03-01

413

Liquid waste evaporator operating experience  

Energy Technology Data Exchange (ETDEWEB)

Atomic Energy of Canada Limited (AECL) operates the Waste Treatment Centre (WTC) to treat and immobilize some of the low- level radioactive waste (LLRW) streams at the Chalk River Laboratories (CRL). The WTC at treats low- level radioactive liquid waste by removing the contaminants from the wastewater, concentrating them, and immobilizing them. The fundamental design concept for the WTC is to process the waste streams using forced circulation type liquid waste evaporation (LWE), to solidify the concentrates using thin film evaporator and to discharge the purified effluent into the Ottawa River following verification monitoring. The solidified product drums are stored in existing storage facilities in the CRL. The LWE was installed in the WTC to treat the LLRW. After about four (4) years of design, construction and cold commissioning, the active commissioning of the evaporator process using radioactive waste streams commenced in February 2000. The LWE has overcome ...

2006-07-01

414

Liquid waste evaporator operating experience  

International Nuclear Information System (INIS)

Atomic Energy of Canada Limited (AECL) operates the Waste Treatment Centre (WTC) to treat and immobilize some of the low- level radioactive waste (LLRW) streams at the Chalk River Laboratories (CRL). The WTC at treats low- level radioactive liquid waste by removing the contaminants from the wastewater, concentrating them, and immobilizing them. The fundamental design concept for the WTC is to process the waste streams using forced circulation type liquid waste evaporation (LWE), to solidify the concentrates using thin film evaporator and to discharge the purified effluent into the Ottawa River following verification monitoring. The solidified product drums are stored in existing storage facilities in the CRL. The LWE was installed in the WTC to treat the LLRW. After about four (4) years of design, construction and cold commissioning, the active commissioning of the evaporator process using radioactive waste streams commenced in February 2000. The LWE has overcome ...

2005-05-08

415

Isolation and Identification of Achromobacter sp. DN-06 and Evaluation of Its Pyridine Degradation Kinetics  

British Library Electronic Table of Contents (United Kingdom)

We report the isolation of a new bacterium species (named as DN-06) that degrades pyridine, a model compound containing both carbon and nitrogen, from the aerobic activated sludge in a coking wastewater treatment plant. DN-06 was identified as Achromobacter sp. using 16S rDNA sequence analysis. In batch culture, more than 95% of pyridine (500?mg/L) was degraded within 18?h by DN-06 grown at 35?C and pH?8 with agitation at 170?rpm. Degradation experiments of pyridine at different initial concentrations (50?4,300?mg/L) revealed that pyridine was an inhibitory substrate, and that neither yield coefficient Y nor endogenous decay coefficient K d was a constant. The values of Y and K d were 0.55?0.74 and 0.0032?0.0057?h?1, respectively. Five kinetic models (Haldane, Yano, Aiba, Webb, and Monod) ...

2011-01-01

416

International symposium: concepts for the treatment of wastewater in the rural areas of Europe. Proceedings; Internationales Symposium: Konzepte zur Abwasserbehandlung im laendlichen Raum Europas. Tagungsband  

Energy Technology Data Exchange (ETDEWEB)

In the first part of the symposium, experts reviewed the state of the art of decentralized waste water treatment in Europe. In the second part, exemplary solutions in Poland and the Czech Republic were presented. The final part was dedicated to future concepts and strategies. [German] Im Herbst letzten Jahres hat die Kommunale Umwelt-AktioN U.A.N. in einer Abfolge von drei Abwasserfachsymposien Expertenrunden zum Austausch ueber den aktuellen Stand des Wissens zum Thema dezentrale Abwasserbehandlung veranstaltet. Mit dem Internationalen Symposium 'Konzepte zur Abwasserbehandlung im laendlichen Raum Europas' in Celle hat das Projekt der U.A.N. seinen Abschluss gefunden. Der Konzeption des Projektes entsprechend haben im 1. Teil des Symposiums Experten ueber den Stand der Entwicklung auf dem Sektor der dezentralen Abwasserbehandlung in Deutschland berichtet. Im 2. Teil unserer Fachtagung wurden europaeische Beispiele fuer dezentrale Loesungen aus Polen und Tschechien ...

2000-07-01

417

Innovative coke oven gas cleaning system for retrofit applications. Quarterly environmental monitoring report No. 1, January 1, 1991--June 30, 1991  

Energy Technology Data Exchange (ETDEWEB)

The coke plant at the Sparrows Point Plant consist of three coke oven batteries and two coal chemical plants. The by-product coke oven gas (COG) consists primarily of hydrogen, methane, carbon monoxide, nitrogen and contaminants consisting of tars, light oils (benzene, toluene, and xylene) hydrogen sulfide, ammonia, water vapor and other hydrocarbons. This raw coke oven gas needs to be cleaned of most of its contaminants before it can be used as a fuel at other operations at the Sparrows Point Plant. In response to environmental concerns, BSC decided to replace much of the existing coke oven gas treatment facilities in the two coal chemical Plants (A and B) with a group of technologies consisting of: Secondary Cooling of the Coke oven Gas; Hydrogen Sulfide Removal; Ammonia Removal; Deacification of Acid Gases Removed; Ammonia Distillation and Destruction; and, Sulfur Recovery. This combination of technologies will replace the existing ammonia removal system, the final coolers, hydrogen ...

1992-08-24

418

Innovative coke oven gas cleaning system for retrofit applications  

Energy Technology Data Exchange (ETDEWEB)

The coke plant at the Sparrows Point Plant consist of three coke oven batteries and two coal chemical plants. The by-product coke oven gas (COG) consists primarily of hydrogen, methane, carbon monoxide, nitrogen and contaminants consisting of tars, light oils (benzene, toluene, and xylene) hydrogen sulfide, ammonia, water vapor and other hydrocarbons. This raw coke oven gas needs to be cleaned of most of its contaminants before it can be used as a fuel at other operations at the Sparrows Point Plant. In response to environmental concerns, BSC decided to replace much of the existing coke oven gas treatment facilities in the two coal chemical Plants (A and B) with a group of technologies consisting of: Secondary Cooling of the Coke oven Gas; Hydrogen Sulfide Removal; Ammonia Removal; Deacification of Acid Gases Removed; Ammonia Distillation and Destruction; and, Sulfur Recovery. This combination of technologies will replace the existing ammonia removal system, the final coolers, hydrogen ...

1992-08-24

419

Elimination of organics chemicals in aqueous solutions by gamma radiation processing  

International Nuclear Information System (INIS)

The objective this work was to evaluate the gamma radiation processing for elimination of organic contaminants on industrial wastewater. Standard samples with 17 hydrocarbons (acetophenone, anisole, benzene, chlorobenzene, cyclohexanone, N, N-dimethylaniline, phenol, naphtalene, 1-chloronaphtalene, n-octadecane, p-nitrotoluene, toluene, tetrachloroethane, tetramethylbenzene, n-undecane, m-xylene and o-xylene) was preparated in hexane with total concentration of 1 #mu# g/ #mu# l which was analyzed by gas chromatography. Other sample with the same concentration of these hydrocarbons in acetone was used to contaminate water samples, which were irradiated with gamma radiation from Co-60 between doses 5.0 to 20.0 KGy and dose rate of 1.162 KGy/h. The activity of source was 1470 Ci. Percents destruction of hydrocarbons were: 79.76 % to 5.0 KGy, 85.97 % to 7.5 KGy, 86.24 % to 10.0 KGy, 86.72 % to 12.5 KGy, 88.92 % to 15.0 KGy, 91.74 % to 17.5 KGy and 92.38 % to 20.0 KGy. ...

1992-08-16

420

ELECTROLYTIC MEMBRANE DIALYSIS FOR TREATING WASTEWATER STREAMS  

Energy Technology Data Exchange (ETDEWEB)

This project will determine whether electrolytic dialysis has promise in the separation of charged particles in an aqueous solution. The ability to selectively move ions from one aqueous solution to another through a semipermeable membrane will be studied as a function of emf, amperage, and particle electrical charge. The ions selected for the study are Cl{sup -} and SO{sub 4}{sup 2-}. These ions are of particular interest because of their electrical conduction properties in aqueous solution resulting with their association with the corrosive action of metals. The studies will be performed with commercial membranes on solutions prepared in the laboratory from reagent salts. pH adjustments will be made with dilute reagent acid and base. Specific objectives of the project include testing a selected membrane currently available for electrolytic dialysis, membrane resistance to extreme pH conditions, the effectiveness of separating a mixture of two ions selected on the basis of size, the ...

2000-04-01

421

Development of radioisotope tracer technology  

Energy Technology Data Exchange (ETDEWEB)

The purpose of this study is to develop the radioisotope tracer technology, which can be used in solving industrial and environmental problems and to build a strong tracer group to support the local industries. In relation to the tracer technology in 1999, experiments to estimate the efficiencies of a sludge digester of a waste water treatment plant and a submerged biological reactor of a dye industry were conducted. As a result, the tracer technology for optimization of facilities related to wastewater treatment has been developed and is believed to contribute to improve their operation efficiency. The quantification of the experimental result was attempted to improve the confidence of tracer technology by ECRIN program which basically uses the MCNP simulation principle. Using thin layer activation technique, wear of tappet shim was estimated. Thin layer surface of a tappet shim was irradiated by proton beam and the correlation between the measured activity loss ...

2000-04-01

422

Continuous fermentative hydrogen production in different process conditions  

Energy Technology Data Exchange (ETDEWEB)

This paper reported on a study in which hydrogen was produced by fermentation of biomass. A continuous process using a non-sterile substrate with a readily available mixed microflora was used on heat treated digested sewage sludge from a wastewater treatment plant. Hydrogen was produced from waste sugar at a pH of 5.2 and a temperature of 37 degrees C. An experimental setup of three 5.5 L working volume continuously stirred tank reactors (CSTR) in different stirring speeds were constructed and operated at 7 different hydraulic retention times (HRTs) and different organic loading rates (OLR). Dissolved organic carbon was examined. The results showed that the stirring speed of 135 rpm had a beneficial effect on hydrogen fermentation. The best performance was obtained in 135 rpm and 8 h of HRT. The amount of gas varied with different OLRs, but could be stabilized on a high level. Methane was not detected when the HRT was less than 16 h. The study identified the ...

2010-07-01

423

Coir pith of the green coconut in the decontamination of radioactive aqueous effluent  

International Nuclear Information System (INIS)

Industrial segments as plant of mining, hospitals and university generate considerable volumes of radioactive wastewater containing uranium. The increasing development of the use of the nuclear energy to lead away to an expansion of the sectors of the nuclear fuel cycle, but it leads to security problems and it appears the necessity of control of the removing of uranium and radioactive effluent treatments. Researches evaluate if the technique of the biosorption would promote an alternative process with attractive characteristics of cost-benefit. The residual biomass from agricultural activities has been studied and used as adsorbent of metals and organic composts by low cost, abundance and for being biodegradable. In this work, it is presented the efficiency of the coir pith for the adsorption of ions UO_2"2"+. The coir pith is a by-product of the harvest of the coconut, a renewable natural source. The study was accomplished using the batch techniques. The ...

424

Can we do it?  

International Nuclear Information System (INIS)

One wonders how a facility will cope with the new Clean Air Act Amendments (CAAA). Environmental engineers working in large companies' facilities and in corporate engineering groups already have an idea of how to comply with the regulations for chemical plant equipment leaks. (In fact, the rules will also affect process bins, wastewater, transfer and storage.) But those who work for smaller companies or who have assignments not directly tied to environmental affairs may not have access to the latest thinking on compliance. One of the first challenges in becoming aware of the CAAA regulations is learning the new language, which consists of acronyms, some containing other acronyms. NESHAP, for example, stands for national emissions standards for hazardous air pollutants. Prior to the CAAA, NESHAPs applied to a few specific chemicals, such as benzene. Now the proposed rules establish a HON, a hazardous organic NESHAP. According to David Gustafson, environmental air ...

425

Aquatic macroinvertebrates and water quality in Sandia Canyon  

International Nuclear Information System (INIS)

In 1990, field studies of water quality and stream macroinvertebrate communities were initiated in Sandia Canyon at Los Alamos National Laboratory. The studies were designed to establish baseline data and to determine the effects of routine discharges of industrial and sanitary waste. Water quality measurements were taken and aquatic macroinvertebrates sampled at three permanent stations within the canyon. Two of the three sample stations are located where the stream regularly receives industrial and sanitary waste effluents. These stations exhibited a low diversity of macroinvertebrates and slightly degraded water quality. The last sample station, located approximately 0.4 km (0.25 mi) downstream from the nearest wastewater outfall, appears to be in a zone of recovery where water quality parameters more closely resemble those found in natural streams in the Los Alamos area. A large increase in macroinvertebrate diversity was also observed at the third station. ...

2005-09-01

426

A simple model for strontium breakthrough on zeolite columns  

Science.gov (United States)

The Process Waste Treatment Plant (PWTP) at the Oak Ridge National Laboratory is designed to remove radioactive contaminants, principally {sup 90}Sr, from process wastewater. Planned upgrades to the PWTP will use chabazite zeolite columns. Pilot-scale studies have shown that mass transfer zone lengths increase from 10 to about 30 cm as the superficial velocity increases from 5.5 to 22 cm/min. Calculations with a multicomponent equilibrium model showed that the distribution coefficient for strontium remains essentially constant over the process conditions, suggesting that a simple kinetic model (the Rosen long-bed solution) should adequately represent breakthrough behavior. Using a distribution coefficient of 4.87 L/g predicted by the equilibrium model, good agreement was found between experimental breakthrough curves and those calculated with the Rosen solution. This model allows prediction of bed depths and cycle times necessary to achieve the required ...

1995-04-01

427

Utilization of intestinal triglyceride-rich lipoproteins in mammary gland of cows.  

Science.gov (United States)

Elution profiles of total lipoproteins, apolipoprotein B (apoB) concentrations in lipoproteins, and plasma triglyceride (TG) levels were examined in early-, late-, and non-lactating cows. Additionally, arteriovenous (A-V) differences were also measured to elucidate the uptake of TG and apoB-containing lipoproteins in mammary gland. Non-lactating cows showed three major peaks corresponding to triglyceride-rich lipoprotein (TRL), low density lipoprotein (LDL), and high density lipoprotein (HDL) fraction, whereas both early- and late-lactating cows revealed two peaks corresponding to TRL and HDL. The peak area of TRL in early- and late-lactating cows were significantly (p < 0.05) smaller than that in non-lactating cows. The plasma TG levels and apoB-48 concentrations of TRL in early- and late-lactating cows were also significantly (p < 0.01) lower. Furthermore, early lactating cows showed significantly (p < 0.05) larger A-V differences in both plasma TG and ...

1999-10-01

428

Transient enhanced diffusion of Sb and B due to MeV silicon implants  

Energy Technology Data Exchange (ETDEWEB)

We measure the transient enhanced diffusion of shallow molecular-beam-epitaxy grown marker layers of Sb and B due to deep MeV Si{sup +} ion implants at very high doses ({approx}10{sup 16}cm{sup {minus}2}). We expect the near-surface region of these implants to be vacancy rich, and we observe transient enhanced diffusion of Sb (the classic vacancy diffuser). The large enhancements imply a significant vacancy supersaturation ({approx}700 at 740{degree}C). Double implantation of the high-dose MeV Si followed by a shallow (40 keV) Si implant and annealing produces a greatly reduced number of {l_brace}311{r_brace} defects compared to a 40 keV implant into virgin Si, again consistent with a vacancy-rich region in the near-surface region of an MeV implant. However, the shallow B marker layers also show transient enhanced diffusion for the same MeV implant under similar annealing conditions, implying that an interstitial supersaturation is present at ...

1997-06-01

429

Transient enhanced diffusion of Sb and B due to MeV silicon implants  

International Nuclear Information System (INIS)

We measure the transient enhanced diffusion of shallow molecular-beam-epitaxy grown marker layers of Sb and B due to deep MeV Si"+ ion implants at very high doses (#approx#10"1"6cm"-"2). We expect the near-surface region of these implants to be vacancy rich, and we observe transient enhanced diffusion of Sb (the classic vacancy diffuser). The large enhancements imply a significant vacancy supersaturation (#approx#700 at 740 degree C). Double implantation of the high-dose MeV Si followed by a shallow (40 keV) Si implant and annealing produces a greatly reduced number of #left brace#311#right brace# defects compared to a 40 keV implant into virgin Si, again consistent with a vacancy-rich region in the near-surface region of an MeV implant. However, the shallow B marker layers also show transient enhanced diffusion for the same MeV implant under similar annealing conditions, implying that an interstitial supersaturation is present at the same ...

430

Thermodynamic and transport properties of thoria-urania fuel of Advanced Heavy Water Reactor  

International Nuclear Information System (INIS)

High temperature thermochemistry of thoria-urania fuel for Advanced Heavy Water Reactor was investigated. Oxygen potential development within the matrix and distribution behaviors of the fission products (fps) in different phases were worked out with the help of thermodynamic and transport properties of the fps as well as fission generated oxygen and the detailed balance of the elements. Some of the necessary data for different properties were generated in this laboratory while others were taken from literatures. Noting the behavior of poor transports of gases and volatile species in the thoria rich fuel (thoria-3 mol% urania), the evaluation shows that the fuel will generally bear higher oxygen potential right from early stage of burnup, and Mo will play vital role to buffer the potential through the formation of its oxygen rich chemical states. The problems related to the poor transport and larger retention of fission gases (Xe) and volatiles ...

2010-08-01

431

Surface brightness and effective radius for elliptical galaxies  

International Nuclear Information System (INIS)

Seeing convolved two-dimensional de Vaucouleurs profiles have been fitted to digital images of the brightest elliptical galaxies in two nearby groups of galaxies and three clusters of galaxies with redshifts in the range 0.06 to 0.15. The digital images were created by scanning electronographic plates obtained by the use of several versions of the RGO electronographic camera. The linear relation between effective surface brightness #mu#/sub e/ and the logarithm of the effective radius r/sub e/, first discovered by Kormendy to be valid for nearby elliptical galaxies, is found to be equally valid for the largest and brightest galaxies in rich clusters of galaxies. The apparent universal nature of that relation indicates that the same type of processes might have been involved during the formation of all ellipticals from cD galaxies in clusters to fainter ellipticals in small groups. It is suggested that the (I/sub e/,r/sub e/) relation is not changed by the expected ...

432

Suppression of band crossing in the neutron-rich nuclei {sup 172,173}Yb due to the absence of a static pair field  

Energy Technology Data Exchange (ETDEWEB)

High-spin states in the neutron-rich nuclei {sup 172,173}Yb have been populated in a {sup 170}Er({sup 7}Li,(p,d,t)xn) incomplete-fusion reaction and the emitted {gamma}-radiation was detected with the GASP array. The signature partners of the 7/2{sup +}[633] rotational band of the odd-N {sup 173}Yb isotope have been newly established and were observed up to spin values of (45/2{sup +}) and (43/2{sup +}), respectively. The ground-state band of the even-even nucleus {sup 172}Yb has been observed up to a spin value of (22{sup +}). No band crossings were found in these bands. To explain this observation, it is proposed that the static pair field is absent, considering that the neutron odd-even mass differences reach for these nuclei very small values and that the band crossing is absent in cranked shell modell calculations without pairing. The results indicate, however, that strong dynamic correlations are still present. (orig.)

2005-10-01

433

Remnant of a "Wet" Merger: NGC 34 and Its Young Massive Clusters, Young Stellar Disk, and Strong Gaseous Outflow  

CERN Document Server

This paper presents new images and spectroscopy of NGC 34 (Mrk 938) obtained with the du Pont 2.5-m and Baade 6.5-m telescopes at Las Campanas, plus photometry of an HST archival V image. This Mv = -21.6 galaxy has often been classified as a Seyfert 2, yet recently published infrared spectra suggest a dominant central starburst. We find that the galaxy features a single nucleus, a main spheroid containing a blue central disk, and tidal tails indicative of two former disk galaxies. These galaxies appear to have completed merging. The remnant shows three clear optical signs that the merger was gas-rich ("wet") and accompanied by a starburst: (1) It sports a rich system of young star clusters, of which 87 have absolute magnitudes -10.0 > Mv > -15.4. Five clusters with available spectra have ages in the range 0.1-1.0 Gyr, photometric masses between 2x10^6 and 2x10^7 Msun, and are gravitationally bound young globulars. (2) The blue central ...

2007-01-01

434

Rare-earth-rich tellurides: Gd_4NiTe_2 and Er_5M_2Te_2 (M=Co, Ni)  

International Nuclear Information System (INIS)

Three new rare earth metal-rich compounds, Gd_4NiTe_2, and Er_5M_2Te_2 (M=Ni, Co), were synthesized in direct reactions using R, R_3M, and R_2Te_3 (R=Gd, Er; M=Co, Ni) and single-crystal structures were determined. Gd_4NiTe_2 is orthorhombic and crystallizes in space group Pnma with four formula units per cell. Lattice parameters at 110(2)K are a=15.548(9), b=4.113(2), c=11.7521(15)A. Er_5Ni_2Te_2 and Er_5Co_2Te_2 are isostructural and crystallize in the orthorhombic space group Cmcm with two formula units per cell. Lattice parameters at 110(2)K are a=3.934(1), b=14.811(4), c=14.709(4)A, and a=3.898(1), b=14.920(3), c=14.889(3)A, respectively. Metal-metal bonding correlations were analyzed using the empirical Pauling bond order concept.

2004-11-01

435

Properties of superconducting Cu-rich composites containing V_3Si or V_3Ga  

International Nuclear Information System (INIS)

Superconducting Cu-rich composites containing the A-15 compounds V_3Si or V_3Ga were made by the ''Tsuei'' process (melting into ingots followed by cold working and heat treatment). Superconducting transition temperatures of the composites were measured. X-ray diffraction analyses were performed. Microstructures were studied using both the optical metallograph and the scanning electron microscope. For some composites containing V_3Ga, the critical current densities as functions of transverse magnetic field up to 60 kG, and as functions of temperature from 4.2 to 12"0K were measured. It was found that the Tsuei process does not work for the composites containing V_3Si, but works satisfactorily for V_3Ga; reasons are discussed. Relations between measured properties and various metallurgical factors such as alloy compositions, cross-section reduction ratios, and heat treatment are discussed. The mechanism for the observed superconductivity in the materials is also ...

436

Polyphenol rich botanicals used as food supplements interfere with EphA2-ephrinA1 system  

British Library Electronic Table of Contents (United Kingdom)

The Eph tyrosine kinase receptors and their ephrin ligands play a central role in several human cancers and their deregulated expression or function promotes tumorigenesis, inducing aggressive tumor phenotypes. Green tea extracts (GTE) have been recently found to inhibit Eph-kinase phosphorylation. In order to evaluate the potential contribution of edible and medicinal plants on EphA2-ephrinA1 modulation, 133 commercially available plant extracts used as food supplements, essential and fixed oils were screened with an ELISA-based binding assay. Nine plant extracts, rich of polyphenols, reversibly inhibited binding in a dose-dependent manner (IC"5"0 0.83-24@mg/ml). Functional studies on PC3 prostate adenocarcinoma cells revealed that active extracts antagonized ephrinA1-Fc-induced EphA2-pho...

2011-01-01

437

Performance and emissions of a supercharged dual-fuel engine fueled by hydrogen-rich coke oven gas  

Energy Technology Data Exchange (ETDEWEB)

This study investigated the engine performance and emissions of a supercharged dual-fuel engine fueled by hydrogen-rich coke oven gas and ignited by a pilot amount of diesel fuel. The engine was tested for use as a cogeneration engine, so power output while maintaining a reasonable thermal efficiency was important. Experiments were carried out at a constant pilot injection pressure and pilot quantity for different fuel-air equivalence ratios and at various injection timings without and with exhaust gas recirculation (EGR). The experimental strategy was to optimize the injection timing to maximize engine power at different fuel-air equivalence ratios without knocking and within the limit of the maximum cylinder pressure. The engine was tested first without EGR condition up to the maximum possible fuel-air equivalence ratio of 0.65. A maximum indicated mean effective pressure (IMEP) of 1425 kPa and a thermal efficiency of 39% were obtained. However, the nitrogen ...

2009-12-15

438

On combining surface and bulk passivation of SiN{sub x}:H layers for mc-Si solar cells  

Energy Technology Data Exchange (ETDEWEB)

A route, as followed by ECN, is described for development of SiN{sub x}:H layers deposited by microwave (MW) PECVD, which are suited for surface and bulk passivation of mc-Si solar cells. First research was focussed on surface passivation and this resulted in the development of SiN layers that were Si-rich and where the hydrogen is mainly bonded to silicon atoms. A disadvantage of such Si-rich layers is their large absorption at shorter wavelengths, which make them unsuitable as front side AR coatings. Further, these layers appeared to be less suitable for bulk passivation. The next step therefore was the development of SiN layers for bulk passivation. For good bulk passivation of solar cells by means of a thermal anneal of the SiN layers, we found that SiN layers with high N-H bonding concentrations are required. Fine-tuning of the deposition conditions of these layers, finally resulted in the development of a SiN layer type which combines the ...

2002-05-01

439

Natural gels: crystal-chemistry of short range ordered components in Al, Fe, and Si systems  

Energy Technology Data Exchange (ETDEWEB)

In this review, the most important inorganic natural gels are presented: opal, aluminosilicate (allophanes) and hydrous iron oxides and silicates. It is demonstrated that natural gels are ordered at the atomic scale. In allophanes, Al is distributed between octahedral and tetrahedral sites. The amount of Al increases as Al/Si ratio decreases. Si-rich allophane have a local structure around Al and Si very different of that is known in kaolinite or halloysite. Transformation of Si-rich allophanes to crystallized minerals implies dissolution-recrystallization processes. On the contrary, in iron silicate with Fe/Si = 0.72, Si and Fe environments are close to those found in nontronite. The gel transformation to Fe-smectite may occur by long range ordering during ageing. In ferric silicate gels, the similarity of local structure around Fe in poorly ordered precursors and what is known in crystallized minerals suggests a solid transformation during ...

1997-07-01

440

Measurement of level lifetimes in the ps range and model interpretations for neutron-rich A #approx =# 100 nuclei  

International Nuclear Information System (INIS)

The nuclear structure of A #propor to# 100 nuclei has been studied in the frame of this thesis with a recently developed #beta# - #gamma# - #gamma# triple coincidence fast timing technique and different models such as shell model, hydrodynamic model, Nilsson and particle-rotor models. This technique which allows the measurement of the level lifetimes in the ps range has been applied at JOSEF at the research reactor DIDO of KFA Juelich in studes of the short-lived neutron-rich nuclei in the A #approx =# 100 region. Lifetimes of level in "9"6,"9"8,"1"0"0 ZR, "9"9,"1"0"1-"1"0"4 Nb, "1"0"0-"1"0"5 Mo have been measured, which are in many cases completely new, and otherwise more precise than previously published data. From the lifetimes of the members of rotational bands, the size of the nuclear deformations has been deduced. (orig./HSI).

441

Mass measurements of the proton-rich nuclides {sup 85,86,87}Mo and {sup 87}Tc and their impact on the rp-process  

Energy Technology Data Exchange (ETDEWEB)

The masses of the proton-rich nuclides {sup 85,86,87}Mo and {sup 87}Tc have been measured with the Penning trap mass spectrometer SHIPTRAP at GSI. The measured mass excesses of these nuclei deviate from the values of the Atomic Mass Evaluation 2003 by up to 1.6 MeV, indicating a systematic shift of the mass surface in this region compared to previous measurements. A local mass extrapolation based on the new results has been made for the mass range A=80-95. Measured and extrapolated mass values and the derived separation energies have been compared to theoretical mass models. Taking into account the new mass excess values, rp-process network calculations have been performed. Preliminary results show changes in the final abundances for A=86-92 by up to a factor of 30. Results of measurements and calculations are presented, and the issue of a potential Zr-Nb cycle is addressed.

2010-07-01

442

Mass measurements of the proton-rich nuclides "8"5","8"6","8"7Mo and "8"7Tc and their impact on the rp-process  

International Nuclear Information System (INIS)

The masses of the proton-rich nuclides "8"5","8"6","8"7Mo and "8"7Tc have been measured with the Penning trap mass spectrometer SHIPTRAP at GSI. The measured mass excesses of these nuclei deviate from the values of the Atomic Mass Evaluation 2003 by up to 1.6 MeV, indicating a systematic shift of the mass surface in this region compared to previous measurements. A local mass extrapolation based on the new results has been made for the mass range A=80-95. Measured and extrapolated mass values and the derived separation energies have been compared to theoretical mass models. Taking into account the new mass excess values, rp-process network calculations have been performed. Preliminary results show changes in the final abundances for A=86-92 by up to a factor of 30. Results of measurements and calculations are presented, and the issue of a potential Zr-Nb cycle is addressed.

2010-03-15

443

Magnetic moments of C isotopes studied with antisymmetrized molecular dynamics  

International Nuclear Information System (INIS)

We studied the magnetic dipole moments #mu# of even-odd C isotopes, ranging from proton-rich to neutron-rich nuclei, with antisymmetrized molecular dynamics (AMD). The results are in good agreement with the experimental data. In the "9C ground state the total intrinsic spin of the protons is found to be nonzero (S_p#not =#0), which is unusual in even-odd nuclei. The interesting point is that the spin-orbit force breaks slightly the coupling off of intrinsic spins of the even nucleon group in isospin T=3/2 nuclei. This result is consistent with the newly measured #mu# data that, when combined with "9Li data, indicate an unusual left-angle #sigma# right-angle value larger than unity. A #mu# moment -1.05#mu#_N of "1"7C is theoretically predicted. We also show a good reproduction of E2 transition data. copyright 1996 The American Physical Society.

444

Interfacial reactions between PbO-rich glasses and aluminium composites  

CERN Document Server

565 deg C occurs when dissolution rate exceeds oxidation rate, exposing the fresh Al anode to the glass melt. Under inert atmosphere (at 583 deg C), air oxidation is not possible and galvanic cell redox reactions generate an excessive copper interlayer as the system attempts to sustain the oxide layer at the anode. Similar behaviour is observed in those coatings formed on the alloy using glass C (containing Al sub 2 O sub 3 and Na sub 2 O). In this case, the interfacial reactions involve the PbO of the glass and Pb-rich spherical precipitates are formed in the interfacial region, along side sodium aluminosilicate phases, precipitated from the PbO-depleted glass. The behaviour in both systems indicates that oxygen diffuses through the edge of the glass drop, from the atmosphere, to the substrate/glass interface. Coatings formed on the MMCs in air exhibited a porosity of approx 10%, attributed to the production of CO sub 2 gas through the oxidation of SiC at the ...

2000-01-01

445

Identification of protein phosphorylation sites within Ser/Thr-rich cluster domains using site-directed mutagenesis and hybrid linear quadrupole ion trap Fourier transform ion cyclotron resonance mass spectrometry  

British Library Electronic Table of Contents (United Kingdom)

We describe a method for the analysis of multi-site phosphorylation in serine/threonine (Ser/Thr)-rich protein sequences. Site-specific mutagenesis was used to introduce tryptic cleavage sites in the serine glutamine/threonine glutamine cluster domain (SCD) of the human checkpoint protein kinase (Chk2). The mutant proteins were shown to autophosphorylate on residues that are inducibly phosphorylated when mammalian cells are exposed to ionizing radiation (serine 33/35, serine 516, threonine 68 and threonine 432). Five Ser/Thr clusters within the SCD were flanked by arginine or lysine residues to produce tryptic peptides for nanospray liquid chromatography (nanoLC)/linear quadrupole ion trap Fourier transform ion cyclotron resonance mass spectrometry. Phosphorylation sites were assigned usin...

2007-01-01

446

Hydrogen synthesis via combustion of fuel-rich natural gas/air mixtures at elevated pressure  

Energy Technology Data Exchange (ETDEWEB)

Combustion of extremely fuel-rich ({phi}=4) methane/air mixtures at elevated pressures is investigated as a potential means to generate molecular hydrogen by non-catalytic partial oxidation. This system is investigated both computationally and experimentally. The computations use a perfectly-stirred reactor model and an explicit methane cool-flame mechanism to investigate the effects of reactor parameters on reaction time and product composition. Under adiabatic conditions, such mixtures are predicted to autoignite at low temperatures {approx}700 K for pressures exceeding 8.5 atm. Above 15 atm, conversion to products is complete in roughly 1 s. The dependence of reaction time and hydrogen yield is investigated as a function of inlet temperature, system pressure, and flame equivalence ratio. Actual product yields are measured in a tube reactor facility, and many of the predictions of the model, including long relaxation times to chemical equilibrium and temperatures ...

2005-07-01

447

HD 100453: A Link Between Gas-Rich Protoplanetary Disks and Gas-Poor Debris Disks  

CERN Document Server

HD 100453 has an IR spectral energy distribution (SED) which can be fit with a power-law plus a blackbody. Previous analysis of the SED suggests that the system is a young Herbig Ae star with a gas-rich, flared disk. We reexamine the evolutionary state of the HD 100453 system by refining its age (based on a candidate low-mass companion) and by examining limits on the disk extent, mass accretion rate, and gas content of the disk environment. We confirm that HD 100453B is a common proper motion companion to HD 100453A, with a spectral type of M4.0V - M4.5V, and derive an age of 10 +/- 2 Myr. We find no evidence of mass accretion onto the star. Chandra ACIS-S imagery shows that the Herbig Ae star has L_X/L_Bol and an X-ray spectrum similar to non-accreting Beta Pic Moving Group early F stars. Moreover, the disk lacks the conspicuous Fe II emission and excess FUV continuum seen in spectra of actively accreting Herbig Ae stars, and from the FUV continuum, we find the ...

2009-01-01

448

Growth of single-crystal metastable semiconducting (GaSb)_1/sub -//sub x/Ge/sub x/ films  

International Nuclear Information System (INIS)

Epitaxial metastable (GaSb)/sub 1-x/Ge/sub x/ alloys with compostions across the pseudobinary phase diagram have been grown on (100) GaAs substrates by multitarget rf sputtering. An essential feature allowing the growth of these metastable materials was low-energy ion bombardment of the growing film during deposition to enhance surface diffusion, promote mixing, and preferentially sputter incipient second-phase precipitates. Annealing experiments indicated that the metastable films exhibit good high-temperature stability and that they transform through a continuous series of GaSb-rich and Ge-rich phases in which the solute concentrations decrease until the equilibrium two-phase alloy is obtained. While the calculated free-energy difference between the single-phase metastable and equilibrium states is approx.18 meV, the measured activation barrier for the transformation is approx.3 eV. All films were p-type with room-temperature hole ...

6180-01-01

449

First direct mass measurement of the proton rich nuclides {sup 85,86,87}Mo and {sup 87}Tc  

Energy Technology Data Exchange (ETDEWEB)

The masses of proton rich nuclides in the vicinity of N=Z=43 were measured with the Penning trap mass spectrometer SHIPTRAP at GSI. These nuclei were produced in the fusion-evaporation reaction {sup 36}Ar+{sup 54}Fe at energies of 5.0 and 5.9 MeV/u and separated at the velocity filter SHIP. The data are of astrophysical interest since these nuclei are believed to be a part of the rp and {nu}p process paths. The masses of {sup 85}Mo and {sup 87}Tc were measured for the first time. The masses of another two nuclides, {sup 86,87}Mo, were determined for the first time in a direct mass measurement. For these nuclides the mass excess deviates from values of the 2003 Atomic Mass Evaluation by up to 1.5 MeV, indicating a systematic shift of the mass surface in this region of the nuclear chart. Additionally, the masses of {sup 86}Zr and {sup 85}Nb were measured and found to be in agreement with the values obtained at JYFLTRAP. The experiment as well as preliminary data on ...

2009-07-01

450

First direct mass measurement of the proton rich nuclides "8"5","8"6","8"7Mo and "8"7Tc  

International Nuclear Information System (INIS)

The masses of proton rich nuclides in the vicinity of N=Z=43 were measured with the Penning trap mass spectrometer SHIPTRAP at GSI. These nuclei were produced in the fusion-evaporation reaction "3"6Ar+"5"4Fe at energies of 5.0 and 5.9 MeV/u and separated at the velocity filter SHIP. The data are of astrophysical interest since these nuclei are believed to be a part of the rp and #nu#p process paths. The masses of "8"5Mo and "8"7Tc were measured for the first time. The masses of another two nuclides, "8"6","8"7Mo, were determined for the first time in a direct mass measurement. For these nuclides the mass excess deviates from values of the 2003 Atomic Mass Evaluation by up to 1.5 MeV, indicating a systematic shift of the mass surface in this region of the nuclear chart. Additionally, the masses of "8"6Zr and "8"5Nb were measured and found to be in agreement with the values obtained at JYFLTRAP. The experiment as well as preliminary data on mass values, separation ...

2009-03-16

451

Differential responses of the freshwater wetland species Juncus effusus L. and Caltha palustris L. to iron supply in sulfidic environments  

Energy Technology Data Exchange (ETDEWEB)

Sulfur pollution can lead to serious problems in freshwater wetlands, including phosphorus eutrophication and sulfide toxicity. We tested the effects of anaerobic iron-rich groundwater discharge in fens, simulated by iron injection, on two characteristic species (Juncus effusus and Caltha palustris) in a sulfidic environment. Biomass production of C. palustris roots showed an optimum response to the combined addition of iron and sulfide, with highest values at intermediate concentrations of both substances. Iron deficiency apparently occurred at low iron concentrations, while at high iron concentrations, growth was decreased. For J. effusus, in contrast, no toxic effects were found of both iron and sulfide. This could be explained by larger radial oxygen loss (ROL) of J. effusus and could not be explained by differences in phosphorous concentrations. The results of our experiments confirm that iron-rich groundwater discharge has the potential ...

2007-05-15

452

Characterisation and emissions of single fuel particles under fluidized bed combustor conditions  

Energy Technology Data Exchange (ETDEWEB)

Devolatilization, char combustion and emission characteristics of different single fuel particles were studied under various fluidized bed combustor conditions, in order to develop a classification system which enables prediction of the behaviour of different fuels ranging from fixed carbon rich coals to volatile rich woods and plastics. To investigate formation reaction, the concentration of CO, CO{sub 2}, total hydrocarbons, O{sub 2}, NO and N{sub 2}O were measured continuously. Additionally, temperature histories of the particles were recorded by implanting thermocouples. Devolatilization and char combustion were analysed by an integral and differential method. The integral analysis uses global rates which were compared with the ultimate and proximate analyses and used to classify the fuels. In the differential analysis the single physical and chemical steps viz mass transfer from the bulk gas to the particle surface, mass transfer through ...

1995-12-31

453

Breakfast meal composition influences plasma tryptophan to large neutral amino acid ratios of healthy lean young men  

International Nuclear Information System (INIS)

The effect of a carbohydrate, a 20% protein, or a carbohydrate +0.3% tryptophan TRP breakfast on plasma large neutral amino acid ratio was studied in 6 healthy men. The carbohydrate-rich meal produced shifts in plasma amino acid concentrations such that plasma TRP/LNAA ratios increased from 0.13 to 0.15 (p<0.04) and the protein meal decreased the ratio from 0.14 to 0.11 (p<0.04) after 1 hour. Addition of 0.3% TRP to the carbohydrate-rich meal increased plasma TRP/LNAA ratios more than 2-fold. The TRP containing meal was thus the only one likely to influence brain 5-HT synthesis, although the difference between the plasma TRP/LNAA ratios after carbohydrate and protein breakfasts suggests that the brain may distinguish, by synthesizing more or less 5-HT, the composition of breakfast meals. (Author).

454

Beta-decay studies of neutron-rich Sc-Cr nuclei  

International Nuclear Information System (INIS)

The neutron-rich nuclei"5"7","5"8_2_1Sc,"5"8"-"6"0_2_2Ti,"6"0"-"6"3_2_3V,"6"2"-"6"6_2_4Cr have been produced at Ganil via interactions of a 61.8A MeV "7"6Ge beam with a "5"8Ni target. Beta-decay studies have been performed using combined #beta#- and #gamma#-ray spectroscopy. Half-lives have been determined and #beta#-decay schemes are proposed for "5"8Ti, "6"1V and "6"2Cr. From these studies, new hints for the existence of #beta#-decaying isomers in "6"0V and in "6"2Mn are provided. These results are compared to shell model calculations. The role of the #pi#f_7_/_2- #nu#f_5_/_2 proton-neutron interaction is examined through its influence on the lifetime values. (orig.)

2005-01-01

455

Analysis of exhaust gas visibility in iron ore sintering plant  

Energy Technology Data Exchange (ETDEWEB)

Visible smoke of exhaust gas from iron ore sintering plants spoil the scenery around the works. In this paper, the mechanism of formation of visible smoke is discussed by detailed analysis of the exhaust gas components and dust in the Oita No. 1 sintering plant. The main substance of visible smoke was mist condensing in the air during the cooling of exhaust gas that contained 0.1 ppm of sulfuric acid. Sulfuric acid is considered to raise the dew point and so facilitate mist condensation, and to lower the vaporization of visible mist containing sulfuric acid solution. Dust in the exhaust gas is also considered to act as nucleation sites for mist condensation. This proposed mechanism was confirmed by the test remixing SOx-rich gas with desulfurization gas in the Nagoya No. 3 sintering plant. Long trails of visible smoke were observed by remixing SOx-rich gas with exhaust gas. In conclusion, in order to make exhaust gas invisible, it is not ...

2006-07-01

456

A study on the amount of pilot injection and its effects on rich and lean boundaries of the premixed CNG/air mixture for a CNG/diesel dual-fuel engine  

Energy Technology Data Exchange (ETDEWEB)

A sequential port injection, lean-burn, fully electronically-controlled compressed natural gas (CNG)/diesel dual-fuel engine has been developed based on a turbo-charged and inter-cooled direct injection (D.I.) diesel engine. During the optimisation of engine overall performance, the effects of pilot diesel and premixed CNG/air mixture equivalence ratio on emissions (CO, HC, NO{sub x}, soot), knocking, misfire and fuel economy are studied. The rich and lean boundaries of the premixed CNG/air mixture versus engine load are also provided, considering the acceptable values of NO{sub x} and THC emissions, respectively. It is interesting to find that there is a critical amount of pilot diesel for each load and speed point, which proved to be the optimum amount of pilot fuel. Any decrease in the amount of pilot diesel from this optimum amount results in an increase of NO{sub x} emissions, because the premixed CNG/air mixture must be made richer, otherwise THC emissions ...

2003-07-01

457

The zinc/air battery test of the Deutsche Post AG - first results from practice; Der Zink/Luft-Batterie-Test der Deutschen Post AG - erste Ergebnisse aus der Praxis  

Energy Technology Data Exchange (ETDEWEB)

The Deutsche Post AG is a transport company that with approximately 55,000 vehicles owns one of the biggest fleets in Europe. Being aware of its responsibility in the field of environmental policy it is looking for an alternative solution of an environmentally friendly vehicle drive system that also takes into account economic efficiency. Extensive investigations have led to a new energy storage based on the zinc-air energy system that has been developed and manufactured by the Israeli Company Electric Fuel Ltd. First tests showed an extraordinarily high capacity potential, drive values and ranges, which had been considered as impossible until that point of time. After these tests the Deutsche Post AG decided together with other well-known partners at home and abroad to carry out a territorial test with the zinc-air energy system in order to obtain insight into the day-to-day capability, economic efficiency, environmental friendliness under ...

1997-07-01

458

The effect of oxide inclusions on the kinetics of the austenite to ferrite transformation in low alloy steel weld metal  

Energy Technology Data Exchange (ETDEWEB)

Isothermal transformation kinetics of austenite to acicular ferrite and allotriomorphic ferrite were measured in reheated low alloy steel weld deposits with similar weld compositions and austenite grain size but different inclusion characteristics. Accelerated kinetics of transformation to acicular ferrite were observed in weld metal containing coarser and titanium-rich inclusions. In contrast, kinetics of transformation to allotriomorphic ferrite were not influenced by inclusion characteristics, but, rather, by the austenite grain size and carbon concentration.

1994-09-01

459

Stress corrosion cracking and pitting corrosion relation for zircaloy-4 in chloride-containing hydro-alcoholic media  

International Nuclear Information System (INIS)

A study of stress corrosion cracking susceptibility of Zircaloy-4 in chloride-containing aqueous methanolic media is presented. The influence of water content is investigated in the 5-100 vol. % water range. The dependence of stress corrosion cracking on potential is evidenced. A close correlation is established with pitting susceptibility determined by a statistical analysis of induction times. A correlation with the repassivation potential is observed in the water-rich solutions. In the low water content solutions, two repassivation curves are determined according to the experimental technique. Pit morphology and fractography show a transition from aqueous to organic media. (author).

460

Spectroscopy of light exotic nuclei  

International Nuclear Information System (INIS)

Neutron-rich He-, Li-, and Be-isotopes in the vicinity of the drip-line have been studied by "1"2C- and "1"4C-induced multi-nucleon transfer reactions on "1"0Be and "1"3","1"4C-targets. This study revealed unknown excited states in "8","1"0He, "1"0","1"1Li and in "1"3","1"4Be. Both excitation energies and widths have been measured. In some cases most probable spins and parities could be assigned to the particle-unstable states observed. (orig.).

1996-01-15

461

SP-700 titanium alloy data sheets  

International Nuclear Information System (INIS)

SP-700, an emerging #beta#-rich #alpha#+#beta# titanium alloy, is designed to improve superplastic formability as well as mechanical properties over Ti-6Al-4V alloy. Owing to its fine microstructure and low #beta#-transus temperature, it is superplastic-formable at temperature below 1,073K (800 C) with low flow stress. Remarkable workability of this alloy is also retained in conventional Manufacturing processes. Another advantage of SP-700 is heat treatment response which includes deep hardenability and quick aging kinetics. Corrosion resistance and machinability are equivalent to or better than Ti-6Al-4V alloy.

1993-02-21

462

Recent observations of Cassiopeia A  

International Nuclear Information System (INIS)

During the last few years radio and X-ray astronomers have produced high-resolution imagery of the remnant of Cas A. Since the most recent published optical photographs of Cas A date back to 1975 it seemed worthwhile to present new optical results based on plates obtained with the 5-m Hale telescope in 1976, 1977, and 1980. The major changes that have taken place in Cas A during the last decade are: (1) A broken shell of fast-moving knots has formed along the southern and SW rim of the remnant and (2) A number of blue (oxygen-rich) filaments have developed to the north of the centre of Cas A. (Auth.).

463

Progress report No. 1. Coal liquefaction program quarterly report. April 1 - June 30, 1980  

Energy Technology Data Exchange (ETDEWEB)

British Columbia is rich in resources of coal but is deficient in resources of liquid petroleum. The overall objective of the B.C. Research Coal Liquefaction Program is to provide sufficient technical data to identify and evaluate coal conversion opportunities in the province. In this first quarterly report, liquefaction test systems are discussed and results from the testing of equipment, procedures and analytical methods using coal samples from Sukunka (N.E. coal) and Hat Creek (central interior) are presented. The proposed program to be undertaken over the next four years is outlined.

1980-01-01

464

Persistence of the N=28 shell closure far from stability  

Science.gov (United States)

The masses of 16 neutron-rich nuclei in the mass range from 35 to 45 have been measured using a direct time of flight technique following the fragmentation of a {sup 48}Ca beam at 60 MeV/nucleon. The masses of {sup 35,36}Mg, {sup 38}Al, {sup 39,40}Si, {sup 42,43}P and {sup 43,44}S are reported for the first time. Preliminary analysis shows that the N=28 shell closure persists, even if weakened by the large neutron excess.

1998-12-21

465

Persistence of the N=28 shell closure far from stability  

International Nuclear Information System (INIS)

The masses of 16 neutron-rich nuclei in the mass range from 35 to 45 have been measured using a direct time of flight technique following the fragmentation of a "4"8Ca beam at 60 MeV/nucleon. The masses of "3"5","3"6Mg, "3"8Al, "3"9","4"0Si, "4"2","4"3P and "4"3","4"4S are reported for the first time. Preliminary analysis shows that the N=28 shell closure persists, even if weakened by the large neutron excess.

1998-12-21

466

Operation of a high temperature ion source at the helium-jet on-line isotope separator facility HELIOS  

Energy Technology Data Exchange (ETDEWEB)

The performance of a high temperature ion source coupled to a helium gas-jet transport system for an efficient mass separation of neutron-rich alkaline earth and lanthanide isotopes is reported and the results of overall efficiency measurements using different cluster materials in the gas-jet are given. A fast, microprocessor controlled tape transport system for ..gamma..-spectroscopic studies on short-lived isotopes is described. Some results on the decay of 3.8sub(-s) /sup 152/Pr are presented. (orig.).

1985-02-01

467

Operation of a high temperature ion source at the helium-jet on-line isotope separator facility HELIOS  

Energy Technology Data Exchange (ETDEWEB)

The performance of a high temperature ion source coupled to a helium gas-jet transport system for an efficient mass separation of neutron-rich alkaline earth and lanthanide isotopes is reported and the results of overall efficiency measurements using different cluster materials in the gas-jet are given. A fast, microprocessor controlled tape transport system for ..gamma..-spectroscopic studies on short-lived isotopes is described. Some results on the decay of 3.8sub(-s) /sup 152/Pr are presented.

1985-02-01

468

More Polish coal mines needed  

Science.gov (United States)

The economy of Poland depends to a large extent upon the exploitation of its vast rich coal reserves for which new mines will have to be sunk and existing mines modernized. Two avenues of coal conversion are being followed. Both involve hydrogenation but one is based on solvent extraction of coal and the other on its pyrolysis. At present large scale established methods of chemical treatment are those which involve the production of coke, production of town-gas, production of synthesis gas and partial oxydation. Total weight amounts to 21,000,000 tons.

1977-11-01

469

Mitochondrial DNA variants in Drosophila melanogaster are expressed at the level of the organismal phenotype.  

Science.gov (United States)

A plethora of experimental studies use mtDNA as a marker of demographic processes without questioning the possibility that selection may bias their interpretations. We studied four lines of Drosophila melanogaster that have a standardized nuclear DNA but variable mtDNA. We completed the sequencing of the mitochondrial genomes (excluding the A+T rich region) and compiled the differences. We then assayed male influence on oviposition, starvation resistance, lipid proportion and physical activity. We discuss these results in terms of the known differences between the lines and conclude that naturally occurring mtDNA variants in D. melanogaster are expressed at the level of the organismal phenotype. PMID:21757031

2011-07-05

470

Localization of highly repetitive, species-specific EcoRI elements from 'Lupinus luteus' L  

International Nuclear Information System (INIS)

Using Southern, dot-blot and 'in situ' hybridization, molecular and cytological localization of repetitive 'Lupinus lueteus' DNA sequence was shown. Under CsCl gradient centrifugation conditions CG-rich satellite fraction appeared. Dot-blot hybridization clearly indicated that 1070bp repetitive element being a member of previously described EcoRI fragments family appeared only in the main band. The use of that DNA fragment as an 'in situ' hybridization signal in the euchromatin area. (author). 26 refs, 3 figs.

471

Light elements in massive single and binary stars  

CERN Document Server

We highlight the role of the light elements (Li, Be, B) in the evolution of massive single and binary stars, which is largely restricted to a diagnostic value, and foremost so for the element boron. However, we show that the boron surface abundance in massive early type stars contains key information about their foregoing evolution which is not obtainable otherwise. In particular, it allows to constrain internal mixing processes and potential previous mass transfer event for binary stars (even if the companion has disappeared). It may also help solving the mystery of the slowly rotating nitrogen-rich massive main sequence stars.

2010-01-01

472

Investigation of cause of cracking of high-strength 30HGSNA grade steel subjected to stresses and corrosive agents  

International Nuclear Information System (INIS)

It has been found out that 30HGSNA steel undergo cracking under action of stresses in aqueous solutions containing oxygen, while it show high resistance in deoxidated solutions. The purpose of such phenomena is the existence of sulfur inclusions in steel which are a centers of denting corrosion. That points acting as a stresses concentrators where pH factor decreases including hydrogen formation and its absorption in the metal. That mechanism is the main purpose of brittle steel cracking observed in oxygen rich solutions. (author).

1995-05-17

473

Investigating Biochar: from Source to Sink (Overview - Research)  

Wastenet

...Investigating Biochar: from Source to Sink (Overview - Research) The Sustainable Agriculture Flagship is leading national collaborative research analysing the properties ...and potential of a variety of biochars to improve soil health and sequester carbon. The Sustainable Agriculture Flagship is leading national collaborative research ...analysing the properties and potential of a variety of biochars to improve soil health and sequester carbon. Biochar, sustainable agriculture, soil,...carbon, SAF, pyrolysis, fertiliser, biochar, soil types, greenhouse gas, herbicide, pesticide, bioenergy, soil science, carbon-rich solid, ...

474

Intermediate mass Higgs study at {gamma}{gamma} colliders  

Energy Technology Data Exchange (ETDEWEB)

We present the efficient technique to extract the signal of the intermediate mass Higgs boson from the backgrounds at future {gamma}{gamma} colliders. For a clear Higgs detection, it is important to fit the original electron accelerator energy depending on the Higgs mass, to set the polarization of the photon beams and to apply the efficient b quark tagging method. we demonstrate the extraction of information of Higgs parameters and the new physics from the observable physical quantities. It is clearly shown that a future {gamma}{gamma} collider will have a rich potential for study on the new physics, as well as the Higgs physics. (author).

1995-05-01

475

Intermediate mass Higgs study at #gamma##gamma# colliders  

International Nuclear Information System (INIS)

We present the efficient technique to extract the signal of the intermediate mass Higgs boson from the backgrounds at future #gamma##gamma# colliders. For a clear Higgs detection, it is important to fit the original electron accelerator energy depending on the Higgs mass, to set the polarization of the photon beams and to apply the efficient b quark tagging method. we demonstrate the extraction of information of Higgs parameters and the new physics from the observable physical quantities. It is clearly shown that a future #gamma##gamma# collider will have a rich potential for study on the new physics, as well as the Higgs physics. (author).

1995-05-01

476

Gunshot wounds of abdomen detected at CT. Personal experience in 30 patients; Ferite da arma da fuoco dell'addome studiate con tomografia computerizzata: esperienza personale in 30 casi  

Energy Technology Data Exchange (ETDEWEB)

The paper investigates the yield and the role of the computerized tomography in diagnosing abdominal gunshot wounds, with their rich and varied radiological signs and associated injuries, and subsequently used in the diagnosis. [Italian] Scopo del lavoro e' riportare l'esperienza personale nell'uso della tomografia computerizzata per riconoscere le lesioni da arma da fuoco dell'addome e nelle fasi successive dell'approfondimento diagnostico.

1999-09-01

477

Formation and coarsening of Ga droplets on focused-ion-beam irradiated GaAs surfaces  

International Nuclear Information System (INIS)

We have investigated the formation and coarsening of Ga droplets on focused-ion-beam (FIB) irradiated GaAs surfaces. To separately examine formation and coarsening, Ga droplets were fabricated by Ga"+ FIB irradiation of GaAs substrates with and without pre-patterned holes. We determined the droplet growth rate and size distribution as a function of FIB energy following irradiation. The data suggest a droplet formation mechanism that involves Ga precipitation from a Ga-rich layer, followed by droplet coarsening via a combination of diffusion and Ostwald ripening or coalescence via droplet migration (dynamic coalescence).

2009-10-12

478

Environmental Influence on Passive Films Formed on Alloy 22  

Energy Technology Data Exchange (ETDEWEB)

The passive corrosion rate of Alloy 22 is exceptionally low in a wide range of aqueous solutions, temperatures and electrochemical potentials, Alloy 22 contains approximately 22% chromium (Cr) by weight; thus, it forms a Cr-rich passive film in most environments. Very little is known about the composition, thickness and other properties of this passive film. The aim of this research was to determine the general characteristics of the oxide film that forms on Alloy 22, as a function of solution pH, temperature and applied electrochemical potential.

2002-10-07

479

Effect of discharge voltage on an ion sheath formed at a grid in a multi-dipole discharge plasma  

International Nuclear Information System (INIS)

It is experimentally demonstrated that a relatively strong ion-rich sheath formed at a fixed negative bias of the grid can be changed to a rather weak ion sheath (sheath potential weakly retards electrons) only by increasing the discharge voltage in the system. At sufficiently high negative grid bias, an increase of discharge voltage enhances the ion collection current at the grid. An explanation is put forward in support of this experimental observation. A slight density enhancement with a fall in plasma electron temperature is also observed with the increasing negative grid bias. (authors)

2008-03-01

480

Ecosystem restoration versus reclamation: the value of managing for biodiversity  

Energy Technology Data Exchange (ETDEWEB)

The importance of ecosystem restoration to land reclamation is discussed. If a plant community is to be self sustaining, natural diversity processes provide a useful model for restoration. Biodiversity is important for utilitarian, ecological, and ethical/aesthetic reasons. Issues that must be considered include sampling and management scales, the separate richness of the diverse array of species playing a role in ecosystem productivity and stability, and natural trends in diversity. Ecological restoration comprises two fundamental activities: management for some pre-disturbance level of biodiversity and the combination of species in a manner that is essentially experimental. Endeavours to restore biological diversity are a useful method of experimenting with the factors that control ecosystem structure and function. 21 refs.

1991-06-01

481

Developing with Ext GWT Enterprise RIA Development  

CERN Document Server

Developing in Ext GWT is a fast--paced, practical guide to quickly learning the tasks necessary in building enterprise--class Rich Internet Applications. Based around the exciting new UI library from Ajax leaders Ext JS and the latest GWT release, this book takes the reader through setup, the available widgets, and advanced custom widgets and templates, and concludes with a functional sample client--server application in less than 150 pages. Not your typical beginner's guide to programming, this book provides a rapid approach to becoming effective with leading commercial RIA tools and librarie

2009-01-01

482

Analysis on uranium resource situations and metallogenic potential of Heyuan mineralization belt of Guangdong province  

International Nuclear Information System (INIS)

Heyuan mineralization belt is a structure-magmatic activities belt which is charcterized by strong plastic deformation and shearing. The squeeze (overthrust) structure is formed early. Later stretch produced slide shovel-shaped normal fault which control the red basin and uranium mineralization. Comprehensive study shows that this area is of favorable uranium metallogenic condition due to the rich uranium source and higher degree of geology work, it is a target for the new round resources exploration. (authors)

2008-03-01

483

ZnO nanoparticles enhanced antibacterial activity of ciprofloxacin against Staphylococcus aureus and Escherichia coli  

British Library Electronic Table of Contents (United Kingdom)

Nanoparticle metal oxides offer a wide variety of potential applications in medicine due to the unprecedented advances in nanobiotechnology research. In this work, the effect of zinc oxide (ZnO) nanoparticles prepared by mechano-chemical method on the antibacterial activity of different antibiotics was evaluated using disk diffusion method against Staphylococcus aureus and Escherichia coli. The average size of ZnO nanoparticles was between 20 nm and 45 nm. Although ZnO nanoparticles (500 mg/disk) decreased the antibacterial activity of amoxicillin, penicillin G, and nitrofurantoin in S. aureus, the antibacterial activity of ciprofloxacin increased in the presence of ZnO nanoparticles in both test strains. A total of 27% and 22% increase in inhibition zone areas was observed for ciprofloxac...

2010-01-01

484

Technology base research on the slurry-zinc/air battery system: Final report  

Energy Technology Data Exchange (ETDEWEB)

The slurry-Zn/air battery system has received renewed R and D interest because it does not have the shape-change problems of batteries with Zn-plate electrodes and can sustain higher current densities and specific peak power than other metal-air battery systems. Additional advantages of the slurry-Zn/air battery include safety, low environmental impact, potential low cost, and separation of energy density from power density functions for design purposes. In this work we present results obtained at the individual cell level as a basis to estimate the performance of a secondary slurry-Zn/air battery system. The expected specific energy of such systems has been increased as a result of the use of capacity-extension additives, which has been one of the major thrusts of this work. 8 refs., 20 figs., 5 tabs.

1988-08-01

485

Synthesis and characterization of conducting polymer composite (PAn/TiO{sup 2}) for cathode material in rechargeable battery  

Energy Technology Data Exchange (ETDEWEB)

This paper deals with the preparation and characterization of polyaniline/TiO{sub 2} composite by XRD, UV-VIS spectra, TGA/DTA and FTIR. The composite is used as a cathode material for rechargeable battery comprising of zinc container as the anode, cellulose acetate as the separator and polyvinyl sulfate and carboxy methyl cellulose as the solid polymer electrolytes (SPE). By using the PAn/TiO{sub 2} composite as the cathode material, the cylindrical AA type rechargeable battery was fabricated and the following output was observed. The open circuit voltage (OCV) is 1.4 V and current is 250 mA to 1.0 A, 50 recharge cycles, power density is 350 A h/kg and power efficiency is 70%.

2003-02-01

486

Properties of transition metal-doped zinc chalcogenide crystals for tunable IR laser radiation  

Energy Technology Data Exchange (ETDEWEB)

The spectroscopic properties of Cr{sup 2+}, Co{sup 2+}, and Ni{sup 2+}-doped single crystals of ZnS, ZnSe, and ZnTe have been investigated to understand their potential application as mid-IR tunable solid-state laser media. The spectroscopy indicated divalent Cr was the most favorable candidate for efficient room temperature lasing, and accordingly, a laser-pumped laser demonstration of Cr:ZnS and Cr:ZnSe has been performed. The lasers` output were peaked at {approximately} 2.35 {mu}m and the highest measured slope efficiencies were {approximately} 20% in both cases.

1995-03-17

487

Pilot project ''measurement of efficacy'' - biological monitoring of antimony pollution in the Munich test area using a standardized grass culture  

International Nuclear Information System (INIS)

This pilot project was carried out for the purpose of testing methods for active biological monitoring. It covered a period of three years (until September 1994), including two years of exposure. The measurements served to determine pollutant levels in plants used as animal fodder and dust-borne heavy metal concentrations in different sites and, on this basis, to obtain indirect information on human exposure. Among others, the pilot project investigated the suitability of Italian rye-grass as a biological indicator for aluminium, arsenic, cadmium, cobalt, chromium, copper, iron, mercury, magnesium, manganese, nickel, lead, platinum, antimony, titanium, and zinc. (orig./GL).

488

On stage III and stage IV recovery of zinc after alpha-particle irradiation  

International Nuclear Information System (INIS)

Stage III and stage IV recovery have been investigated resistometrically following 6.1 MeV alpha-particle irradiation at 4.2 K. The activation energy associated with stage III shows a gradual increase from 0.35 +- 0.02 eV to 0.39 +- 0.02 eV. Stage IV (155 to 180 K) is associated with an activation energy of 0.46 +- 0.03 eV. The present results are compared with those obtained after electron and neutron irradiation. The stage III recovery kinetics are interpreted in terms of the Goesele-Seeger theory for interstitial migration in highly anisotropic hexagonal metals. Stage IV is ascribed to monovacancy migration. (author).

489

New highly active oxygen reduction electrode for PEM fuel cell and Zn/air battery applications (NORA). Final report  

Energy Technology Data Exchange (ETDEWEB)

This illustrated final report for the Swiss Federal Office of Energy (SFOE) presents the results of a project concerning a new, highly active oxygen reduction electrode for PEM fuel cell and zinc/air battery applications. The goal of this project was, according to the authors, to increase the efficiency of the oxygen reduction reaction by lowering the activation polarisation through the right choice of catalyst and by lowering the concentration polarisation. In this work, carbon nanotubes are used as support material. The use of these nanotubes grown on perovskites is discussed. Theoretical considerations regarding activation polarisation are discussed and alternatives to the use of platinum are examined. The results of experiments carried out are presented in graphical and tabular form. The paper is completed with a comprehensive list of references.

2008-04-15

490

Near term and future alternative clean vehicle technologies  

Energy Technology Data Exchange (ETDEWEB)

Availability of a natural gas-powered van that meets California`s ultra low emission vehicle requirements and has a 300-km range was reported. A similar van with an electric system giving a range of 240 km was also within sight. Regarding the limitations of electric batteries it was suggested that a super capacitor may allow systems to achieve higher energy densities; a refuelable zinc-air battery could be considered for vehicle use. While the prospect for emissions improvement of gasoline vehicles has clearly improved in recent years, the relative costs of infrastructure, vehicle and fuel for the the alternative fuels compared with gasoline demonstrate the difficulty the alternative fuels have in taking market share from gasoline. For the next decade, gasoline, propane and CNG are expected to be the dominant fuels for vehicles. After that, the leading fuel will be the one that has been most extensively researched and developed during the decade. 17 refs.

1994-12-31

491

National technical report (Matsushita Electric Industrial Company), Vol. 40, No. 4, August 1994. Special issue on batteries  

Energy Technology Data Exchange (ETDEWEB)

Contents: recent trend of battery technologies; alkaline manganese battery with no mercury addition; high capacity zinc-air battery series for hearing aids; characteristics of vanadium-niobium-lithium rechargeable battery; high-energy density lithium-ion rechargeable battery; lithium polymer rechargeable battery: polymer gel electrolyte and electrode; high-capacity ni-cd battery sm120; high-capacity nickel-metal hydride battery; sealed-type batteries for electric vehicles; high-temperature-durable calcium-type battery for automobiles; sealed lead acid batteries for upss; solar cell power unit; solid oxide fuel cell (1); battery management system.

1994-08-01

492

Modeling of batteries and fuel cells; Proceedings of the Symposium, Phoenix, AZ, Oct. 13-19, 1991  

Energy Technology Data Exchange (ETDEWEB)

The present volume on modeling of batteries and fuel cells discusses the significance of the effectiveness factor for flooded porous electrodes, active pore distribution spectroscopy for characterizing porous battery electrodes, the agglomerate model for porous electrodes, and dynamic-performance measurements of battery cells for electric vehicles and other applications. Attention is given to mathematical modeling of a primary zinc/air battery, mathematical modeling of Grace Li-TiS2 cells, modeling of electrocrystallization processes in battery systems, and rotating disk electrode studies in molten Li/K carbonate eutectic. Topics addressed include the variability of nickel oxide cathode dissolution in molten carbonate fuel cells, water transport properties of fuel cell ionomers, modeling water content effects in polymer electrolyte fuel cells, and computer algebra applied in electrochemistry and fuel cell modeling.

1991-01-01

493

Mathematical modeling of a primary zinc/air battery  

Energy Technology Data Exchange (ETDEWEB)

This paper reports on the mathematical model developed by Sunu and Bennion that has been extended to include the separator, precipitation of both solid ZnO and K{sub 2}Zn(OH){sub 4}, and the air electrode, and has been used to investigate the behavior of a primary Zn-Air battery with respect to battery design features. Predictions obtained from the model indicate that anode material utilization is predominantly limited by depletion of the concentration of hydroxide ions. The effect of electrode thickness on anode material utilization is insignificant, whereas material loading per unit volume has a great effect on anode material utilization; a higher loading lowers both the anode material utilization and delivered capacity. Use of a thick separator will increase the anode material utilization, but may reduce the cell voltage.

1992-04-01

494

Long-distance transport, vacuolar sequestration, tolerance, and transcriptional responses induced by cadmium and arsenic  

British Library Electronic Table of Contents (United Kingdom)

Iron, zinc, copper and manganese are essential metals for cellular enzyme functions while cadmium, mercury and the metalloid arsenic lack any biological function. Both, essential metals, at high concentrations, and non-essential metals and metalloids are extremely reactive and toxic. Therefore, plants have acquired specialized mechanisms to sense, transport and maintain essential metals within physiological concentrations and to detoxify non-essential metals and metalloids. This review focuses on the recent identification of transporters that sequester cadmium and arsenic in vacuoles and the mechanisms mediating the partitioning of these metal(loid)s between roots and shoots. We further discuss recent models of phloem-mediated long-distance transport, seed accumulation of Cd and As and rec...

2011-01-01

495

Exploiting unique germplasm resources of leguminous trees: Prosopis, leucaena and acacia. Final report, August 31, 1982-August 30, 1992  

Energy Technology Data Exchange (ETDEWEB)

In Haiti, and other semiarid regions of the world, the need for fuelwood and forage is critical. The report summarizes research conducted over a ten year period on developing replicable plantations of leguminous trees in semiarid lands, especially in areas near seawater salinity levels. Research included greenhouse and laboratory work followed by field trials in Haiti and focused on two species: Prosopis and Leucaena. (Acacia is mentioned in the report's title but not in the report itself.) Results were as follows. (1) Greenhouse experiments identified leaf diagnostic criteria indicating mineral nutrient deficiencies in field trees. It also established the importance of micronutrients, especially zinc, in permitting growth in high pH (9.0) soils.

1992-01-01

496

Electrically rechargeable zinc/air battery: a high specific energy system  

Energy Technology Data Exchange (ETDEWEB)

This contribution describes our research and development efforts towards the demonstration of a light-weight, low-cost 12 V/20 Ah electrically rechargeable Zn/air battery. We successfully developed electrodes having active areas of up to 200 cm{sup 2}. Deep discharge cycles at different currents as well as current-voltage curves are reported for a 10 cell Zn/air battery (serial connection) with a rated capacity of 20 Ah. Based on the discharge cycle at a power of 19 W, and the weight of the battery, a specific energy of more than 90 Wh/kg could be evaluated for the whole system. (author) 4 figs., 1 tab., 5 refs.

1999-08-01

497

Chemical plant factors affecting resistance in sugarcane in against Scirpophaga Nivella f  

International Nuclear Information System (INIS)

The study was conducted during 2000 to determine the role of various chemical plant factors viz., total minerals, nitrogen, fat contents, carbohydrate, macro an micro nutrients in the leaves of five genotypes of sugarcane i.e., BF-162, SPSG-26, L-118, CP-43/33 and CP-72/2086 by correlating the infestation of top borer, Scirpophaga Nivella F. at tillering stage. None of the genotype was found completely resistant to the pest. CP-43/33 and BF-162 proved susceptible and resistant varieties, respectively. Total mineral, manganese and copper contents did not show significant correlation with the pest infestation, whereas nitrogen, potassium, calcium, magnesium and ferrous contents played a positive and significant role. Phosphorous, carbohydrates, fats and zinc contents played a significant and negative effect on the pest infestation at tillering stage. (author)

498

Catalytic desulfurization of organic sulfur compounds over zeolite catalysts  

Energy Technology Data Exchange (ETDEWEB)

In the dehydrodesulfurization of ethanethiol at 400/sup 0/C, the activities of sodium X, Y, and A zeolites decreased in the order given as did the activities of nickel, cobalt, zinc, cadmium, copper, silver, lead, manganese, barium, calcium, sodium, and iron Y zeolite catalysts. A volcano-shape order was observed between the catalytic activity and the electronegativity of the metal ions. The changes in the activity of hydrogen Y zeolite catalyst in ethanethiol dehydrodesulfurization and cumene dealkylation by calcination agreed with the decrease in the Broensted acidity but were independent of Lewis acidity. For hydrodesulfurization of thiophene, the activities of nickel, cobalt, copper, and silver Y zeolite catalysts decreased in the order given and were greater than for a commercial hydrodesulfurization catalyst; reduced and presulfided catalysts showed selective hydrodesulfurization activity. Addition of 5% of nickel or molybdenum oxides to cobalt or nickel Y ...

1980-01-01

499

A study on effects of parameters in the Lagrangian code based on F.E.M. through oblique dual-plates perforation phenomena  

International Nuclear Information System (INIS)

This study is concerned to the perforation phenomena of the oblique dual-plate by projectile. Experiment and simulation related to that was carried out. the variables considered in this phenomena include the electrolytic zinc coated steel sheet and carbon steel rod. In the former, the confirmation and projectile velocity possible phenomena of real phenomena is done, the latter, the effect of parameter such as time-step and grid space length is analyzed by using the three-dimensional Lagrangian explicit time-integration finite element code, HEMP. This code use the eight node hexahedral elements and in this study, Von-Mises Criteria is used as the strength model, Mie-Gruneisen is as the Equation of State. The simulation was performed by contrast with the experiment. Through the calibration of the parameter of Lagrangian code, reasonable result was approached.

2004-11-03