Energy Technology Data Exchange (ETDEWEB)

The Electrohydrodynamic (EHD) is an active heat transfer augmentation technique which utilizes the effect of secondary motions generated through the application of an electrostatic potential to a dielectric fluid. Net result is better momentum and heat transfer between the fluid and the heat transfer wall through destabilization of the thermal boundary layer and better mixing of the fluid adjacent to the heat transfer surface. EHD enhancement of refrigerant/refrigerant oil mixtures heat transfer using the Electrohydrodynamic (EHD) technique is the subject of a three-year experimental investigation in a project funded by the US Department of Energy, effective June 1, 1993. For the interim period between November 1992 and June 1993 when the DOE funds became available, the Air-Conditioning and Refrigeration Technology Institute (ARTI) provided partial funding for our EHD research program with the aim of accomplishing three ...

Energy Technology Data Exchange (ETDEWEB)

Critical properties of a fluid or fluid mixtures are important for describing fluid phase behavior, predicting physical properties, developing equations of state, and designing supercritical-fluid extraction processes, and compression and refrigeration units. The predictive capability of the Peng-Robinson-Styjek-Vera (PRSV-2) equation of state (1986) for critical properties of binary mixtures was investigated. The procedure adopted by Heidemann and Khalil (1980) and discussed by Abu-Eishah et al. (1998) was followed. An optimized value for the binary interaction parameter based on minimization of error between experimental and predicted critical temperatures was used. The standard and the average of the absolute relative deviations in critical properties are included. The predicted critical temperature and pressure for several nonpolar and polar systems agree well with experimental data and are always better than those ...

UK PubMed Central (United Kingdom)

A field study of 89 refrigerator repairmen was carried out to ascertain whether occupational exposure to fluorocarbons induces cardiac arrhythmia. The concentrations of fluorocarbons in the breathing...Full Text Available

KoreaScience (Korea)

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International Nuclear Information System (INIS)

The refrigerant two-phase flows in a capillary tube and a distributor used in a compression-type refrigerator were visualized by real-time neutron radiography. The thermal neutron radiography system of JRR-3M at the Japan Atomic Energy Research Institute was used. In the visualization experiments of the two-phase flow in the capillary tube of 2 mm I.D., a cooled CCD camera was used, and the axial one-dimensional distributions of void fraction were measured. For the distributor, a high sensitivity video camera with a silicone intensified target tube was used. From the visualized images, the refrigerant behaviors in the distributor were clearly shown, and the liquid fraction in each tube was measured. As a result, it was shown that the refrigerant behaviors in the distributor effected the distributing performance of the refrigerant flow.

Energy Technology Data Exchange (ETDEWEB)

Condensing two-phase channel flow occurs in many industrial applications, including heating and refrigeration systems. It can also occur in certain nuclear reactor accidents. For example, during a small-break loss-of-coolant accident in a pressurized water reactor, following the partial depletion of the primary coolant, condensation of steam on the primary side of the steam generator tubes can provide a heat sink for disposal of the decay heat generated in the reactor core. Condensing two-phase flow can also play an important role in the operation of the passive emergency cooling system in the advanced simplified boiling water reactor. Here, steady-state condensation in the presence of a noncondensable in a concurrent two-phase channel flow is analyzed using a two-fluid model. The effect of noncondensables on the combined heat transfer at the liquid-gas mixture interphase is accounted for by using the stagnant film model, and closure relations ...

Energy Technology Data Exchange (ETDEWEB)

A compact and energy independent solar-powered refrigeration unit was to be developed to store and transport small quantities of high-quality commodities needing refrigeration. This unit comprises the following matched components: thermo-electrical refrigerator unit, solar generator and transport equipment. The solar generator is a specially developed panel with 36 cells. This unit may best be used in human medicine, veterinary medicine, environmental protection analysis, laboratories and leisure time activities. (BWI)

Energy Technology Data Exchange (ETDEWEB)

A number of binary geothermal cycles utilizing mixed hydrocarbon working fluids were analyzed with the overall objective of finding a working fluid which can produce low-cost electrical energy using a moderately low temperature geothermal resource. Both boiling and supercritical shell-and-tube cycles were considered. The performance of a dual-boiling isobutane cycle supplied by a 280/sup 0/F hydrothermal resource (corresponding to the 5MW pilot plant at the Raft River site in Idaho) was selected as a reference. To investigate the effect of resource temperature on the choice of working fluid, several analyses were conducted for a 360/sup 0/F hydrothermal resource, which is representative of the Heber resource in California. The hydrocarbon working fluids analyzed included methane, ethane, propane, isobutane, isopentane, hexane, heptane, and mixtures of those pure hydrocarbons. For comparison, two fluorocarbon refrigerants were also analyzed. ...

International Nuclear Information System (INIS)

A diagnosis of the refrigerant flows in a refrigerator was carried out by real-time neutron radiography. The thermal neutron radiography system of JRR-3M in Japan Atomic Energy Research Institute and the real-time image processing system developed by Musashi Institute of Technology were used. Freon evaporating flows in the evaporator, condensing flows in the condenser, flashing flows in the capillary tube and flows in the accumulator were visualized and the dynamic behaviors under practical conditions were clarified. In the case of the capillary tube of 0.8 mm i.d., a cooled-CCD camera was utilized. (orig.).

International Nuclear Information System (INIS)

This report discusses: shape coexistence in "1"8"4Pt; nuclear structure of "1"8"7Ir; g-factors of excited states; OLNO-2; and refrigerator development.

Energy Technology Data Exchange (ETDEWEB)

Desiccants have been used in many applications to provide dehumidification. This paper describes an application of desiccants which provide both dehumidification and sensible cooling, with little or no use of conventional vapour-compression refrigeration plant. Through a parametric study, the energy consumption and costs of a desiccant cooling system are compared with those of a conventional vapour-compression refrigeration-based air-conditioning system. (author)

Energy Technology Data Exchange (ETDEWEB)

Calculations of refrigerant thermal properties are desired to be very fast and stable in cases of simulation of refrigeration system, etc. The traditional method based on equation of state cannot meet such requirement because of unavoidable iterations in calculation. In this paper, a new calculation method for refrigerant thermal properties is presented. Low order implicit polynomial equations are got by using curve-fitting method at first, and then explicit formulae for calculating refrigerant thermal properties quickly are obtained by getting the analytical solution of these implicit equations. Explicit fast calculation formulae for thermal properties of R22 and R407C, covering the saturated temperature of -60{approx}80 {sup o}C and superheat of 0-65 {sup o}C, are presented as examples. The calculation speeds of the formulae of R22 are about 140 times faster than those of REFPROP 6.01 while the ...

British Library Electronic Table of Contents (United Kingdom)

In the last years, the growing demand for air conditioning has caused a significant increase in demand for primary energy resources. Solar-powered cooling is one of the technologies which allows to obtain, by using the renewable solar source, an important energy saving compared to traditional air conditioning plants. The paper describes different technical installations for solar cooling, their way of operation, advantages and limits. The objective of the present study has been to analyze the technical and economic feasibility of solar absorption cooling systems, designed for two different application fields: industrial refrigeration and air conditioning. The possibility to replace or integrate the existing plants is studied, by considering the refrigeration requirements of a company, whic...

Energy Technology Data Exchange (ETDEWEB)

The implicit curve-fitting method has been used for fast and stable calculations of thermodynamic properties of subcritical refrigerants, and it has to use the saturated liquid or vapor state as the reference state. In order to extend the application range of this method in supercritical region, an isothermal state in the supercritical region is used as the reference state, and the implicit equations for supercritical refrigerants in this state and out of this state are established, respectively. The new calculation method can be used in the entire supercritical region. With the new method, thermodynamic properties of supercritical CO{sub 2} and R410A are predicted and compared with REFPROP 8. It shows that the total mean relative deviations of the fast calculation formulae from REFPROP 8 are less than 1%, while the mean calculation speeds of the fast calculation formulae are more than 100 times faster than those of REFPROP 8. (author)

Energy Technology Data Exchange (ETDEWEB)

This report discusses: shape coexistence in {sup 184}Pt; nuclear structure of {sup 187}Ir; g-factors of excited states; OLNO-2; and refrigerator development.

Energy Technology Data Exchange (ETDEWEB)

In most countries, residential electricity consumption typically ranges from 20% to 40% of total electricity consumption. This energy is used for heating, cooling, refrigeration and other end-uses. Significant energy savings are possible if new appliance purchases are for models with higher efficiency than that of existing models. There are several ways to ensure or encourage such an outcome, for example, appliance rebates, innovative procurement, and minimum efficiency standards. This paper focuses on the latter approach. At the present time, the US is the only country with comprehensive appliance energy efficiency standards. However, many other countries, such as Australia, Canada, the European Community (EC), Japan and Korea, are considering enacting standards. The greatest potential impact of minimum efficiency standards for appliances is in the developing countries (e.g., China and India), where saturations of household appliances are relatively low but ...

Energy Technology Data Exchange (ETDEWEB)

The disclosure is directed to an active magnetic regenerator apparatus and method. Brayton, Stirling, Ericsson, and Carnot cycles and the like may be utilized in an active magnetic regenerator to provide efficient refrigeration over relatively large temperature ranges.

Energy Technology Data Exchange (ETDEWEB)

This original volume of the Appliances Atlas includes discussion of residential appliances, commercial refrigeration and cooking, and office equipment. (The residential appliances section has since been updated in the E Source 1994 Residential Appliances Technology Atlas.) The commercial refrigeration section contains details on efficiency opportunities through load reduction and mechanical system improvements, while commercial cooking covers improvements to electric and gas fryers, griddles, ovens, cooktops, broilers, and steam equipment. The office equipment section offers discussion of trends and energy use of computers and their components, imaging technologies, and communication equipment. (Published under the former name, Competitek.)

Energy Technology Data Exchange (ETDEWEB)

This work evaluated the effect of gamma radiation on reducing the population of Staphylococcus aureus, Escherichia coli nd Salmonella typhimurium in ground chicken breast stored under refrigeration. The experiment included a control and 4 doses of gamma radiation ( 2.0, 4.0, 6.0 and 8.0 kGy) along with 5 periods of storage under refrigeration ( 1, 7 14, 21 and 28 days). Samples of ground chicken breast were inoculated with Staphylococcus aureus (ATCC 14458), Escherichia coli (ATCC 11105) and Salmonella typhimurium (ATCC 0626), irradiated at temperatures between 4 and 8 deg C and stored under refrigeration (5 deg C) for 28 days. The increased radiation dose and period of storage under refrigeration caused a reduction of Staphylococcus aureus, Escherichia coli and Salmonella typhimurium populations in the ground chicken breast. Mean radiation D values determined for Staphylococcus aureus and Escherichia ...

Energy Technology Data Exchange (ETDEWEB)

A state of the art review of two-phase void fraction models in smooth horizontal tubes is provided and a probabilistic two-phase flow regime map void fraction model is developed for refrigerants under condensation, adiabatic, and evaporation conditions in smooth, horizontal tubes. Time fraction information from a generalized probabilistic two-phase flow map is used to provide a physically based weighting of void fraction models for different flow regimes. The present model and void fraction models in the literature are compared to data from multiple sources including R11, R12, R134a, R22, R410A refrigerants, 4.26-9.58 mm diameter tubes, mass fluxes from 70 to 900 kg/m{sup 2} s, and a full quality range. The present model has a mean absolute deviation of 3.5% when compared to the collected database. (author)

Energy Technology Data Exchange (ETDEWEB)

The superconducting magnets and associated cryogenic components in A-sector represent the initial phase of installation of the Fermilab superconducting accelerator, designed to accelerate proton beams to energies of 1 TeV. Installation of the magnets, comprising one-eighth of the ring, was completed in December, 1981. Cooldown and power tests took place in the first half of 1982, concurrent with main ring use for 400 GeV high energy physics. The tests described in this paper involved 151 cryogenic components in the tunnel: 94 dipoles, 24 quadrupoles, 25 spool pieces, 3 feed cans, 4 turn-around boxes and 1 bypass. Refrigeration was supplied by three satellite refrigerators, the Central Helium Liquefier, and two compressor buildings. The magnets were powered by a single power supply.

Energy Technology Data Exchange (ETDEWEB)

The invention relates to a method for purifying a gas mixture containing at least one undesirable gas compound utilizing certain sulfonamide or sulfamide solvents.

International Nuclear Information System (INIS)

Page 1. ANALYSIS OF REACTION MIXTURE OF LAURIC ACID WITH MONO-

Energy Technology Data Exchange (ETDEWEB)

This overview of research conducted at ORNL in 1991 presents information on the subjects of biology, physics, and the environment. Specific topics include gene mutations in kidney disease, technology assessments in thermonuclear fusion, submarine hunting technology, ozone-safe refrigerants, optical data storage via surface enhanced raman spectroscopy, and waste mitigating microbes. (GHH)

Energy Technology Data Exchange (ETDEWEB)

Cassava is cultivated almost all over the world and it is considered one of the most important nutritious sources of calories in the human diet. Cassava is a viable food against starvation in several poor areas of the world because it is an extremely resistant culture and may reach satisfactory economical yield. We utilized vacuum packed industrialized cassava irradiated with 0,1 kGy, 3kGy and 5kGy and stored under refrigeration for 1, 21, 30 and 50 days. Our objective was to analyse the synergistic effect of vacuum packing, irradiation and refrigeration on the preservation of minimally processed cassava. The samples were analyzed for pH, acidity, weight, humidity, texture and color. The irradiation did not affect the chemical characteristics of the cassava. Neither the pH nor the acidity, the most relevant variables to verify deterioration in cassava, presented significant alterations during the period of storage. Comparing the irradiated ...

KoreaScience (Korea)

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KoreaScience (Korea)

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KoreaScience (Korea)

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KoreaScience (Korea)

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Energy Technology Data Exchange (ETDEWEB)

Molar excess volumes have been determined by means of a vibrating-tube densimeter for binary liquid mixtures of cycloalkanones (cyclopentanone and cyclohexanone) + cyclohexane, + benzene, and + tetrachloromethane. The V/sup E/ data are reported over the complete mole fraction range at 288.15, 298.15, and 308.15{Kappa}. The obtained excess volumes are positive for mixtures of cyclopentanone with cyclohexane and are negative for mixtures of the cycloalkanones with benzene and tetrachloromethane; for the system cyclohexanone-cyclohexane the V/sup E/ values are positive for a wide range of mole fraction, but at very low cyclohexane mole fraction an inversion of the sign of V/sup E/ is observed. The data show that in the considered range of temperature the values of the temperature coefficient ({partial derivative}V/sup E//{partial derivative}T) are negative for mixtures of the cycloalkanones with benzene ...

Energy Technology Data Exchange (ETDEWEB)

The stirling cryocooler ILK 15 is a machine with simple drive concept. This machine works with a conventional built-in electric motor and crank drive and needs a power input of about 500 W. The refrigerating capacity is 15 W at 80 K with a cooldown time of 12 minutes. The cooler is somehow a replacement for the Gifford-McMahon cycle coolers, which are bigger and heavier. The Stirling cryocooler was designed to cool HTSC-components. (orig.) [Deutsch] Der Stirlingkuehler ILK 15 ist eine Kaeltemaschine mit einfachem Antriebskonzept. Die Maschine arbeitet mit einem konventionellen Elektroeinbaumotor und Kurbeltrieb. Sie benoetigt eine Antriebsleistung von 500 W und hat eine Kaelteleistung von 15 W bis 80 K und eine Einkuehlzeit von 12 Minuten. Die Maschine kann als Alternative zur wesentlich groesseren und schweren Gifford-McMahon-Maschine gesehen und bei der Kuehlung von HTSL-Komponenten eingesetzt werden. (orig.)

Energy Technology Data Exchange (ETDEWEB)

This document summarizes work done at the Astronautics Technology Center of the Astronautics Corporation of America (ACA) in Phase 1 of a four phase program leading to the development of a magnetic liquefier for hydrogen. The project involves the design, fabrication, installation, and operation of a hydrogen liquefier providing significantly reduced capital and operating costs, compared to present liquefiers. To achieve this goal, magnetic refrigeration, a recently developed, highly efficient refrigeration technology, will be used for the liquefaction process. Phase 1 project tasks included liquefier conceptual design and analysis, preliminary design of promising configurations, design selection, and detailed design of the selected design. Fabrication drawings and vendor specifications for the selected design were completed during detailed design. The design of a subscale, demonstration magnetic hydrogen liquefier represents a significant ...

Energy Technology Data Exchange (ETDEWEB)

Compact heat exchangers have traditionally found wide application in the transportation industry, where they are used as evaporators and condensers in vapor compression cycles for air conditioning and refrigeration. Such heat exchangers possess numerous attractive features including high thermal effectiveness, small size, low weight, design flexibility, and pure counterflow, and they can accommodate multiple streams. Today, there is a widespread interest in expanding the range of application of compact heat exchangers to include phase-change heat transfer in the process industries, among others. An overall objective of this effort is to provide the basis for establishing design technology in this area. In the present study, small channel flow boiling heat transfer was extended to a rectangular channel (4.06 {times} 1.70 mm) using refrigerant 12 (R-12). As with the circular tube studies, the flow channel wall was electrically heated providing a ...

UK PubMed Central (United Kingdom)

A general method is described to sequester peptides containing azides from complex peptide mixtures, aimed at facilitating mass spectrometric analysis to study different aspects of proteome...Full Text Available

UK PubMed Central (United Kingdom)

Convolutive mixtures of signals, which are common in acoustic environments, can be difficult to separate into their component sources. Here we present a uniform probabilistic framework to separate...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

The dispersion mechanism of highly loaded coal-water mixture (CWM) in the presence of a polyelectrolyte additive was investigated. Two important factors have been found: the ability of the additive to apply a sufficient electric repulsive force to the coal particles, and an appropriate affinity of the additive to the coal surface.

UK PubMed Central (United Kingdom)

There is increasing concern for the potential adverse health effects of human exposures to chemical mixtures. To better understand the complex interactions of chemicals within a mixture, it is essential...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Once again residual austenite as one component of the microstructure of steels is the basis for discussion among experts. Very often the phenomen of the stabilisation of residual austenite is the focus of interest. In this paper the influence of ageing on residual austenite transformations is discussed, with ageing taking place in a temperature range between ambient and M/sub s/-temperature after quenching from different austenitizing temperatures by means of subzero refrigeration. Results which are typical for 100Cr6 steel are presented and discussed.

Energy Technology Data Exchange (ETDEWEB)

A comprehensive presentation is made of state-of-the-art configurations and design methodologies for heat transfer devices applicable to industrial processes, automotive systems, air conditioning/refrigeration, cryogenics, and petrochemicals refining. Attention is given to topics in heat exchanger mechanical design, single-phase convection processes, thermal design, two-phase exchanger thermal design, heat-transfer augmentation, and rheological effects. Computerized analysis and design methodologies are presented for the range of heat transfer systems, as well as advanced methods for optimization and performance projection.

Energy Technology Data Exchange (ETDEWEB)

Limited demand and high cost has prevented the construction of hard rock caverns in this country for a number of years. The storage of natural gas in mined caverns may prove technically feasible if the geology of the targeted market area is suitable; and economically feasible if the cost and convenience of service is competitive with alternative available storage methods for peak supply requirements. It is believed that mined cavern storage can provide the advantages of high delivery rates and multiple fill-withdrawal cycles in areas where salt cavern storage is not possible. In this research project, PB-KBB merged advanced mining technologies and gas refrigeration techniques to develop conceptual designs and cost estimates to demonstrate the commercialization potential of the storage of refrigerated natural gas in hard rock caverns. Five regions of the U.S.A. were studied for underground storage development and PB-KBB reviewed the literature ...

KoreaScience (Korea)

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Energy Technology Data Exchange (ETDEWEB)

Over the past 40 years, cavern storage of LPG's, petrochemicals, such as ethylene and propylene, and other petroleum products has increased dramatically. In 1991, the Gas Processors Association (GPA) lists the total U.S. underground storage capacity for LPG's and related products of approximately 519 million barrels (82.5 million cubic meters) in 1,122 separate caverns. Of this total, 70 are hard rock caverns and the remaining 1,052 are caverns in salt deposits. However, along the eastern seaboard of the U.S. and the Pacific northwest, salt deposits are not available and therefore, storage in hard rocks is required. Limited demand and high cost has prevented the construction of hard rock caverns in this country for a number of years. The storage of natural gas in mined caverns may prove technically feasible if the geology of the targeted market area is suitable; and economically feasible if the cost and convenience of service is competitive with alternative available ...

International Nuclear Information System (INIS)

Esters of dihydric alcohols with alkenylphosphonic or alkenylphosphinic acids which are polymerizable by free radicals are described. They are combined with polymer binders, in particular water-soluble polymers, and photoinitiators forming free radicals to give photopolymerizable mixtures which are suitable for the production of photoresists and printing plates. The mixtures display low heat-sensitivity and have long shelf lives. (author) 1 tab.

Energy Technology Data Exchange (ETDEWEB)

The paper presents a compilation of data and model interpretation of CO{sub 2} with mixtures of amines. The data includes both absorption and desorption conditions in the 288-313K range. The combined mass transfer/equilibrium model can effectively represent CO{sub 2} mass transfer rates for the various mixtures under a wide range of conditions.

International Nuclear Information System (INIS)

Molar excess volumes, VE and molar excess enthalpies, HE of 1,3-dioxolane (D) (i) + propan-1-ol, 1,3-dioxolane (i) + butan-1-ol and 1,3-dioxolane (i) + butan-2-ol (j) binary mixtures have been measured as a function of composition at 308.15 K. The analysis of VE data by graph, theoretical approach reveals that while propan-1-ol, butan-1-ol exist as associated entities in the pure state; 1,3-dioxolane and butanol exist as monomers in their pure state. These (i+j) binary mixtures are characterized by interactions between ethereal oxygen atom of D(i) and hydrogen atom of alkanols. The IR studies lend additional support to the proposed structure of molecular entitles in these mixtures. The energetics of the mixtures have also been studied.

British Library Electronic Table of Contents (United Kingdom)

To test whether the dose addition and independent action models can predict the combined toxicity of the mixtures of phenol and aniline derivatives, six phenolic and two aniline derivatives were selected as the test components. The inhibition toxicity of the derivatives and their mixtures to Vibrio qinghaiensis sp.-Q67 indicated that all dose?response relationships could be effectively described by the Weibull function with correlation coefficients greater than 0.99. The combined toxicity of two equivalent-effect concentration ratio mixtures and eight uniform design concentration ratio mixtures could be predicted successfully by the dose addition model within 95% confidence intervals. However, it was also well predicted by the independent action model, especially at lower concentrations.

Energy Technology Data Exchange (ETDEWEB)

This report identifies individual contaminants and contaminant mixtures that have been measured in the ground at 91 waste sites at 18 US Department of Energy (DOE) facilities within the weapons complex. The inventory of chemicals and mixtures was used to identify generic chemical mixtures to be used by DOE's Subsurface Science Program in basic research on the subsurface geochemical and microbiological behavior of mixed contaminants (DOE 1990a and b). The generic mixtures contain specific radionuclides, metals, organic ligands, organic solvents, fuel hydrocarbons, and polychlorinated biphenyls (PCBs) in various binary and ternary combinations. The mixtures are representative of in-ground contaminant associations at DOE facilities that are likely to exhibit complex geochemical behavior as a result of intercontaminant reactions and/or microbiologic activity stimulated by ...

Energy Technology Data Exchange (ETDEWEB)

Many attempts have been made to generate reliable thermodiffusion coefficient models for binary mixtures. This paper presented a simple analytical model for the prediction of thermal diffusion coefficients in linear chain hydrocarbon binary mixtures using the thermodynamics of irreversible process. More specifically, the model represented the net heat transport, or the energy of detaching a molecule from its neighbours in the region of the binary mixture minus the energy given up in that region when one molecule fills a hole, and examined its accuracy by comparing theoretical results with available experimental data for linear chain hydrocarbon binary mixtures. The new model was based on phenomenological and kinetic approaches which have been found to be the most reliable. The paper discussed the net heat of transport for each component in the binary mixtures and presented the ...

British Library Electronic Table of Contents (United Kingdom)

A mission to the surface of Venus would have high scientific value, but most electronic devices and sensors cannot operate at the 450degreeC ambient surface temperature of Venus. Power and cooling systems were analyzed for Venus surface operation. A radioisotope power and cooling system was designed to provide electrical power for a probe operating on the surface of Venus. For a mission duration of substantial length, the use of thermal mass to maintain an operable temperature range is likely impractical, and active refrigeration may be required to keep components at a temperature below ambient. Due to the high thermal convection of the high-density atmosphere, the heat rejection temperature was assumed to be at a 500degreeC radiator temperature, 50degreeC above ambient. The radioisotope S...

Science.gov (United States)

The Micro-X instrument is a NASA funded, rocket borne X-ray imaging spectrometer planned for launch in January 2011. An array of Transition Edge Sensors (TESs) will observe incoming photons in the 0.2-3 keV energy band with an energy resolution of 2-4 eV at 1 keV. This will be a substantial improvement over current non-dispersive detectors for X-ray spectroscopy of extended sources and will be the first demonstration of a TES-based microcalorimeter in space. The TESs will utilize the 50 mK stage of an Adiabatic Demagnetization Refrigerator (ADR) as a heat sink, and will be read out by a SQUID time division multiplexer. X-rays will be focused onto the TES array of 128 pixels on a 600 micron pitch by a conically approximated Wolter optic with an effective area of 200 cm2. The spectrometer will have a field of view of 11.8 arcmin. We describe the design and development progress of the instrument.

Energy Technology Data Exchange (ETDEWEB)

This study describes the construction of a simple mathematical model its validation through the simulation in transient state of a real cycle performed by a solar refrigerator based on physical adsorption using an activated carbon/methanol pair. The deviation from experimental results was 4% for the cycled mass of methanol, 2.2 % for maximum collector average temperature, and 3 x 10{sup -3} for the theoretical cycle coefficient of performance. Additional simulations of the same cycle inputting values representing different types and larger amounts of activated carbon showed the possibility of increasing the cycled methanol mass up to about 150%. (author) 26 refs., 16 figs., 9 tabs.

Energy Technology Data Exchange (ETDEWEB)

This manual is presented in 8 chapters plus appendices. Chapters 1 and 2 are included as background information. The economic insulation thickness is found using the following chapters: Chapter 3, cost of energy (heat and refrigeration); Chapter 4, cost of insulation, and Chapter 5, economic thickness determination. Each of these chapters contains a worksheet, which provides a step-by-step procedure for solving the problem. Nomographs are included in each section for simplifying the required calculations. For subambient temperature systems, the economic insulation thickness calculated with Chapters 3 to 5 should be compared to the thickness required to prevent condensation (sweating), as calculated with Chapter 6. Chapter 7 presents the procedure for calculating economic insulation for retrofit situations. Sample problems are included in Chapter 8.

Energy Technology Data Exchange (ETDEWEB)

This two-tomes book brings together the 108 presentations given at the first conference of the international institute of refrigeration (IIF/IIR) about air conditioning in high rise office buildings. The main themes are: general design and control systems, including split systems, radiant panels, fluctuating and gravity ventilation etc..; energy consumption, optimization and heat recovery; cold storage for peak shaving, including ice slurry circulation; indoor air quality; fire and smokes protection, protection against chimney effects and lighting spots; use of fuzzy logic and of neural networks. It includes also a description of the high rise building situation and works in progress in China, Japan and in some other countries. (J.S.)

British Library Electronic Table of Contents (United Kingdom)

An evaporative cooling system developed for operation and qualification testing of silicon pixel and microstrip detectors for the inner tracking detector of the CERN ATLAS spectrometer is described. Silicon detector substrates must be continuously operated between 0 and ???7?C in the high radiation environment near the circulating beams at the CERN Large Hadron Collider (LHC). This requirement imposes unusual constraints on the cooling system and has led to the choice of perfluoro-n-propane (C3F8) refrigerant, which combines good chemical stability under ionizing radiation with high dielectric strength and nonflammability. Since the silicon detectors must also be of extremely light construction to minimize undesirable physics background, coolant tubes are of thin (200 ?m) aluminum wall, wh...

Energy Technology Data Exchange (ETDEWEB)

Using gasoline as an example of additives for cold start improvement, fuel vapor composition of methanol-gasoline mixtures, fuel evaporation rate in consideration of temperature drop due to heat of fuel evaporation, air fuel ratio, stoichiometric air fuel ratio and excess air ratio of fuel vapor were calculated. The mixture formation of methanol-gasoline mixtures at low temperature in otto cycle engines was studied. Van Laar's empirical formula was used to estimate the partial pressure of high-percentage methanol blends. It was found that the most part of fuel vapor is occupied by gasoline, even when a small amount of gasoline is added to methanol resulting to an extremely small excess air ratio. It is obvious that this vapor pressure adjustment using gasoline is the dominant factor for improvement in cold startability. (10 figs, 1 tab, 10 refs)

UK PubMed Central (United Kingdom)

A binary mixture of imipramine HCl and chlordiazepoxide was determined by three different spectrophotometric methods. The first method involved determination of imipramine HCl and chlordiazepoxide using...Full Text Available

Science.gov (United States)

... The phenol and cresylic acid stream is flashed in a thin film evaporator over a concentrated sulfuric acid mixture to remove pyridine type substances ...

Energy Technology Data Exchange (ETDEWEB)

The passivity and breakdown of passivity of 1018 carbon steel in propylene carbonate (PC) and 1,2-dimethoxyethane (DME) mixtures with 0.5 molar lithium hexafluoroarsenate supporting electrolyte were examined via several electrochemical and surface analytical methods. The PC-DME/0.5 M LiAsF{sub 6} mixtures ranged from 10 to 90 mol % PC. The results from the PC/DME mixtures were compared to passivating mechanisms found in pure PC and DME solutions. In PC-rich mixtures, the breakdown of passivity occurred near the oxidation potentials of either organic solvent. Premature breakdown of the carbon steel in PC-DME mixtures occurred at sulfide inclusions as was observed earlier in PC/0.5 M LiAsF{sub 6} solutions although passive films attempted to form at these inclusion sites in mixtures containing at least 10 mol % DME. As the DME content increased in the PC-DME ...

Energy Technology Data Exchange (ETDEWEB)

The light gain due to S/sub 2/ molecules in a supersonically cooled gas mixture is calculated. The S/sub 2/ molecules formed due to the recombination of the sulfur atoms, and the combustion gas mixture was preheated in a precombustion chamber. Optimal gas flow and nozzle parameters are found which correspond to the highest possible light gain using Cs/sub 2/-Ar and S/sub 2/-Ar gas mixtures. The steady state gas flow in the nozzle was calculated, taking into account the chemical reactions in the one-dimensional approximation. It is shown that the maximum gain values vary in the 0.0001-0.002 range for gas pressures in the precombustion chamber in the range 10-100 atm. The optimal initial relative concentration of Cs/sub 2/ molecules and S/sub 2/ molecules are given. 32 references.

UK PubMed Central (United Kingdom)

BackgroundIn biomedical ontologies, mereological relations have always been subject to special interest due to their high relevance in structural descriptions of anatomical entities,...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

One of the unsolved problems of the natural gas dual fuel engine is that there is too much exhaust of Total Hydrogen Carbon(THC) at a low equivalent mixture ratio. To fix it, a natural gas mixed with hydrogen was applied to engine test. The results showed that the higher the mixture ratio of hydrogen to natural gas, the higher the combustion efficiency. And when the amount of the intake air is reached to 90% of WOT, the combustion efficiency was promoted. But, like a case making the injection timing earlier, the equivalent mixture ratio for the nocking limit decreases and the produce of NOx increases. 5 refs., 9 figs., 1 tab.

British Library Electronic Table of Contents (United Kingdom)

The effects of five extraction solvents and their mixtures on the yield of metabolites in crude and fractionated extracts of Annona muricata L. leaves were investigated by direct comparison. Extraction media were prepared using simplex centroid mixtures of ethanol, ethyl acetate, dichloromethane, acetone, and chloroform. The effects of the mobile phase solvent strength and the analysis wavelength on the chromatographic separation were also investigated. Solvent mixtures rather than pure solvents were found to be the most efficient extractors for the different fractions. The results indicated that the mobile phase composed of methanol/acetonitrile/water (26:27:47 v/v/v) was most suitable for the basic fraction analysis at 254 nm, whereas the mobile phase composed of methanol/acetonitrile/wa...

International Nuclear Information System (INIS)

AISI 5140 steel was plasma nitrided at various gas mixtures of nitrogen, hydrogen, and argon to investigate the actions of hydrogen and argon on plasma nitriding. The structural and mechanical properties of ion-nitrided AISI 5140 steel have been assessed by evaluating composition of phases, surface hardness, compound layer thickness, and case depth by using X-ray diffraction (XRD), microhardness tests, and scanning electron microscopy (SEM). It was found that the growth of compound layer can be controlled and the diffusion improved when the gas mixture includes H_2 gas. Additionally, it was determined that the amount of Ar in dual gas mixture must be at 20% minimum to obtain distinctive surface hardness and compound layer thickness.

Energy Technology Data Exchange (ETDEWEB)

Fhe ECOTRONIC system developed by Bosch und Pierburg System oHG is an electronic system for mixture formation for Otto-cycle engines complying with high operational requirements. Engineers incorporated electronic control of the quantity of mixture and mixture enrichment for supplementary functions into a reliable, low-cost system, which will also comply with future requirements concerning fuel consumption, emissions and driveability. The author of the present article reduces the carburetor down to its basic systems, explains how supplementary functions were converted from mechanical to either open or closed-loop electronic control, and describes the newly developed actuators, the control unit making use of digital technology, and the results achieved.

British Library Electronic Table of Contents (United Kingdom)

Summary Although risk assessments are typically conducted on a chemical-by-chemical basis, the 1996 Food Quality Protection Act required the US Environmental Protection Agency to consider cumulative risk of chemicals that act via a common mechanism of toxicity. To this end, we are conducting studies with mixtures of chemicals to elucidate mechanisms of joint action at the systemic level with the goal of providing a framework for assessing the cumulative effects of reproductive toxicants. Previous mixture studies conducted with antiandrogenic chemicals are reviewed briefly and two new studies are described. In all binary mixture studies, rats were dosed during pregnancy with chemicals, singly or in pairs, at dosage levels equivalent to approximately one-half of the ED50 for hypospadias or e...

International Nuclear Information System (INIS)

Russian (Jan 1978). USSR Chorna, IM Beshta, EI Kvitkovskij, LN L'vovskij

Energy Technology Data Exchange (ETDEWEB)

(Boiling site densities and heat-transfer coefficients have been measured for ethanol-water and ethanol-benzene mixtures at 1.01 bar for a heated vertical brass disk. A strong effect of composition on the boiling site density was observed, which was attributed to the nature of the activation of the boiling surface and mass diffusion effects. The boiling heat-transfer coefficient was found to decrease with increasin subcooling, but for the mixtures at a given level of subcooling the decrease was less than that for the single components and azeotropic mixtures.) The heat-transfer coefficient at a given heat flux was seen to be quite insensitive to the very large increase in boiling site density in comparing the pure water and the ethanol-water azeotrope results, leading one to question pool boiling models that predict heat-transfer rates on the basis of boiling site density.

International Nuclear Information System (INIS)

Thermodynamic consideration and process calculations at equilibrium conditions showed that processes for separating gas mixtures by partial condensation at low temperatures using turboexpanders have got less energy losses than processes with quasi isobar partial condensation. Compared to the low-pressure parts of condensing steam turbines in turboexpanders less erosion problems are to expected for such separating processes. Separation of liquid in the machine, however, is more difficult withouf additional measures. (orig.).

Energy Technology Data Exchange (ETDEWEB)

A multiple metal oxide sorbent supported on a zeolite of substantially silicon oxide is used for the desulfurization of process gas streams, such as from a coal gasifier, at temperatures in the range of about 1200.degree. to about 1600.degree. F. The sorbent is provided by a mixture of copper oxide and manganese oxide and preferably such a mixture with molybdenum oxide. The manganese oxide and the molybdenum are believed to function as promoters for the reaction of hydrogen sulfide with copper oxide. Also, the manganese oxide inhibits the volatilization of the molybdenum oxide at the higher temperatures.

CERN Document Server

The Rayleigh scattering length has been calculated for rare-gas liquids in the ultraviolet for the frequencies at which they luminesce. The calculations are based on the measured dielectric constants in the gas phase, except in the case of xenon for which measurements are available in the liquid. The scattering length mayplace constraints on the design of some large-scale detectors, using uv luminescence, being proposed to observe solar neutrinos and dark matter. Rayleigh scattering in mixtures of rare-gas mixtures is also discussed.

British Library Electronic Table of Contents (United Kingdom)

Results are given of numerical simulation of three-dimensional pattern of flow of a two-phase steam-water mixture in the house of a PGV-1000 horizontal steam generator obtained using the BAGIRA best-estimate thermohydrodynamic computer codes. The space distributions of velocities and local void fractions in the steam generator housing for different modes of operation of power-generating unit are calculated and compared with available experimental data.

International Nuclear Information System (INIS)

A mathematical and physical model was constructed describing the hydrodynamics of the two-phase mixture in the horizontal steam generator. The HP 9830 A desk-top calculator was used for the computations. The output variable of the solution was the level shape. A quantitative and qualitative comparison was made of the results of computations and experimental data. (author).

Energy Technology Data Exchange (ETDEWEB)

The explosive known under the name Saletrol (mixture of ammonium nitrate and hydrocarbon fuel or a mixture of ammonium nitrate, hydrocarbon fuel and aluminum powder) is characterized by the absence of physical stability during storage (the oily fluid flows from the upper layers of the explosive downward) and as a consequence of this, decrease in the required effectiveness of blasting and increased release of toxic gaseous blasting products. In order to eliminate this shortcoming, lightening clay is added to Saletrol in a quantity of 3-12% by weight of the total explosive mass.

International Nuclear Information System (INIS)

A simple model is described to simulate kinetic processes in dielectric barrier discharges for O_2/NO_x mixtures. A threshold of ozone production found experimentally is confirmed by the calculations of this modeling, and the underlying chemical reaction mechanisms are discussed. It is also found that the effects of diffusion processes in the period of the lifetime of O atoms are not important to micro-discharge channels with a large radius, i.e. larger than 150 #mu#m

Energy Technology Data Exchange (ETDEWEB)

The Flory model is applied to predict the isobaric expansion coefficients, {alpha}{sub P}, isentropic, {kappa}{sub S}, and isothermal, {kappa}{sub T}, compressibilities and speeds of sound, u, of the highly complex mixtures: hydroxyether + alkane, + dibutylether, + 1-butanol or + 2-methoxyethanol, 1-alkanol + alkane, and 1-alkanol + dibutylether. Predictions were obtained using the energetic parameter, {chi}{sub 12}, determined from values of excess enthalpies, H{sup E}, and from values of the excess isochoric internal energies, U{sub V}{sup E}, at equimolar composition. No meaningful differences exist between such predictions. Deviations between experimental and calculated values are lower than 2% for mixtures containing alkoxyethanols. Poorer results are obtained for 1-alkanol + dibutylether mixtures with deviations up to 5%. It is shown that predictions on {alpha}{sub P}, {kappa}{sub S}, {kappa}{sub T}, and u essentially ...

Energy Technology Data Exchange (ETDEWEB)

The characteristics of diesel fuel jet atomization in carburetors depend on dynamic viscosity (v) density (d) and surface tension (st) of fuel, grouped in the combined functions v/d; st/v and st/d. Values of these combined functions for binary mixtures of a farm diesel fuel with a crude vegetable oil (sunflower, soybean, cotton and foot-cake olive oils) as well as with a used frying olive oil, are calculated. Three different diesel fuels have been studied. Combined function values of these mixtures are influenced by the characteristics of their diesel fuel. Mixtures containing less than 24% of any studied crude oils show kinematic viscosity values at 40 degrees C not exceeding 5.8 squared millimeters/s. This value is the higher limit for typical United States farm diesel fuels, according to specifications of the Cummins Engine Company. Mixture with 21% of the used frying olive oil shows at 40 degrees C ...

International Nuclear Information System (INIS)

The preparation of wood-plastic combinations (WPC) using combined methods for curing intermediate products and final products is described. In the first step, impregnated wood was irradiated using doses of 1 to 10 kGy in the presence of chemical initiators of polymerization. Thereafter, curing of this partly cured impregnating mixture was accomplished in the wood at elevated temperatures with the aid of chemical initiators of polymerization. Impregnation mixtures based on unsaturated polyester resins and methyl methacrylate, and the wood species European Beech (Fagus silvatica) and Black Alder (Alnus glutinosa) were used. The results indicate that this method of preparing WPC allows substantially lower radiation doses to be used, i.e., doses in the range of 1 to 2.5 kGy. These doses gelatinate the impregnation mixture in the wood so that the subsequent curing by chemical polymerization initiators proceeds without the ...

Energy Technology Data Exchange (ETDEWEB)

Real fuels are complex mixtures of thousands of hydrocarbon compounds including linear and branched paraffins, naphthenes, olefins and aromatics. It is generally agreed that their behavior can be effectively reproduced by simpler fuel surrogates containing a limited number of components. In this work, an improved version of the kinetic model by the authors is used to analyze the combustion behavior of several components relevant to gasoline surrogate formulation. Particular attention is devoted to linear and branched saturated hydrocarbons (PRF mixtures), olefins (1-hexene) and aromatics (toluene). Model predictions for pure components, binary mixtures and multicomponent gasoline surrogates are compared with recent experimental information collected in rapid compression machine, shock tube and jet stirred reactors covering a wide range of conditions pertinent to internal combustion engines (3-50 atm, 650-1200K, ...

Energy Technology Data Exchange (ETDEWEB)

In the United States, estimates show that more than 30,000 hazardous waste disposal sites exist, not including military installations, U.S. Department of Energy nuclear facilities, and hundreds and thousands of underground fuel storage tanks; these sites undoubtedly have their own respective hazardous waste chemical problems. When so many sites contain hazardous chemicals, how does one study the health effects of the chemicals at these sites? There could be many different answers, but none would be perfect. For an area as complex and difficult as the study of chemical mixtures associated with hazardous waste disposal sites, there are no perfect approaches and protocols. Human exposure to chemicals, be it environmental or occupational, is rarely, if ever, limited to a single chemical. Therefore, it is essential that we consider multiple chemical effects and interactions in our risk assessment process. Systematic toxicity testing of chemical ...

Energy Technology Data Exchange (ETDEWEB)

Numerous studies have investigated degradation of individual endocrine disrupting compounds (EDCs) in lab or natural waters. However, natural variations in water matrices and mixtures of EDCs in the environment may confound analysis of the treatment efficiency. Because chemical based analytical methods cannot represent the combined or synergistic activities between water quality parameters and/or the EDC mixtures at environmentally relevant concentrations ({mu}g L{sup -1}-ng L{sup -1}), bioanalytical assessments of residual estrogenic activity in treated water were used to evaluate the performance of the UV based advanced oxidation process for estrogenic contaminants in water. Four EDCs including estradiol (E{sub 2}), ethinyl estradiol (EE{sub 2}), bisphenol-A (BPA) and nonylphenol (NP) were spiked individually or as a mixture at {mu}g L{sup -1}-ng L{sup -1} in laboratory or natural river water. The removal rates of ...

British Library Electronic Table of Contents (United Kingdom)

This paper seeks to investigate the liquefaction of clayey soils, a phenomenon that has been the trigger for many natural disasters in the last few decades, including landslides. Research was conducted on artificial clay?sand mixtures and natural clayey soils collected from the sliding surfaces of earthquake-induced landslides. The undrained response of normally consolidated clayey soils to cyclic loading was studied by means of a ring-shear apparatus. For the artificial clay?sand mixtures, it was found that the presence of a small amount of bentonite (?7%) would cause rapid liquefaction, while a further increase in bentonite content (?11%) produced the opposite effect of raising soil resistance to liquefaction by a significant degree. It was demonstrated that the bentonite?sand mixture wa...

British Library Electronic Table of Contents (United Kingdom)

The characteristics of diffuse glow discharges in pure argon and the Ar + 1%N2 mixture at pressures of 2?80 Torr were studied experimentally and numerically. The discharge operated in a molybdenumglass tube with an inner diameter of 2.8 cm and interelectrode distance of 75 cm. The current-voltage characteristic of the discharge and the populations of the N2(B3? g ) and N2(C3? u ) states were measured. It is shown that, at relatively low pressures (P 15 Torr), the current-voltage characteristic of a discharge in the mixture lies lower than that in pure argon. As the pressure increases, the effect of the reduction in the discha...

Energy Technology Data Exchange (ETDEWEB)

Formulas were developed based on an aqueous solution of hydrolyzed polyacrylonitrile widely used in the oil industry. The additive used consisted of products of industrial production: synthetic resin TEG-1 with hardening agent PEPA (polyehtylene polyamine) and technical formalin. The mixtures containing about 80-85% by volume 5% hydrolyzed polyacrylonitrile, 10-15% by volume of resin TEG-1 with hardening agent PEPA and 3-5% by volume formalin satisfy the requirements made for the plugging materials. The initial mixtures are distinguished by technological efficiency of preparation and have controllable hardening periods. Physical-chemical properties are given for the gel polymers. In the set of properties, the mixtures based on hydrolyzed polyacrylonitrile, resin TEG-1 with hardening agent PEPA and formalin can be recommended as plugging materials of temporary action with complex treatment of the heterogeneous beds.

Energy Technology Data Exchange (ETDEWEB)

The characteristic rich shifting of the maximum adiabatic flame temperature from the stoichiometric value for mixtures of hydrocarbon and air is demonstrated to be caused by product dissociation and hence reduced amount of heat release. Since the extent of dissociation is greater on the lean side as a result of the stoichiometry of dissociated products, the peaking occurs on the rich side. The specific heat per unit mass of the mixture is shown to increase monotonically with increasing fuel concentration, and as such tends to shift the peak toward the lean side. It is further shown that this is the cause for the lean shifting of the adiabatic flame temperature of oxidizer-enriched mixtures of N{sub m}H{sub n} and F{sub 2} and of NH{sub 3} and O{sub 2}, with various amounts of inert dilution, even though their maximum heat release still peaks on the rich side. (author)

Energy Technology Data Exchange (ETDEWEB)

This invention is comprised of an improved combustion system for an internal combustion engine is disclosed wherein a rich air/fuel mixture is furnished at high pressure to one or more jet plume generator cavities adjacent to a cylinder and then injected through one or more orifices from the cavities into the head space of the cylinder to form one or more turbulent jet plumes in the head space of the cylinder prior to ignition of the rich air/fuel mixture in the cavity of the jet plume generator. The portion of the rich air/fuel mixture remaining in the cavity of the generator is then ignited to provide a secondary jet, comprising incomplete combustion products which are injected into the cylinder to initiate combustion in the already formed turbulent jet plume. Formation of the turbulent jet plume in the head space of the cylinder prior to ignition has been found to yield a higher maximum combustion pressure in the ...

Energy Technology Data Exchange (ETDEWEB)

An experimental and theoretical study of heat and mass transfer analogy and a comparison of that to a binary liquid mixture evaporation is presented. Common organic solvents, ethanol and n-heptane, were used to form an alcohol - hydrocarbon mixture. Studies were carried out in a horizontal rectangular channel having air flow velocities of 0.2 - 0.9 m/s. Heat transfer coefficients were measured with a copper plate resistor and mass transfer coefficients with a square pool. The heat and mass transfer analogy is presented for a system having two evaporating compounds with a fixed value of air flow and verified by measuring and comparing mass transfer coefficients for distilled water with air flow velocities of 0.2 - 0.9 m/s. An illustrative example of the use of the theory for industrial ventilation is presented. (author)

International Nuclear Information System (INIS)

Experimental data on density, viscosity, and refractive index at T = (298.15, 303.15, and 308.15) K, while speed of sound values at T = 298.15 K are presented for the binary mixtures of (methylcyclohexane + benzene), methylbenzene (toluene), 1,4-dimethylbenzene (p-xylene), 1,3,5-trimethylbenzene (mesitylene), and methoxybenzene (anisole). From these data of density, viscosity, and refractive index, the excess molar volume, the deviations in viscosity, molar refraction, speed of sound, and isentropic compressibility have been calculated. The computed values have been fitted to Redlich-Kister polynomial equation to derive the coefficients and estimate the standard errors. Variations in the calculated excess quantities for these mixtures have been studied in terms of molecular interactions between the component liquids and the effects of methyl and methoxy group substitution on benzene ring.

CERN Document Server

In a recent paper [4], Duarte and Jutten investigated the Blind Source Separation (BSS) problem, for the nonlinear mixing model that they introduced in that paper. They proposed to solve this problem by using information-theoretic tools, more precisely by minimizing the mutual information (MI) of the outputs of the separating structure. When applying the MI approach to BSS problems, one usually determines the analytical expressions of the derivatives of the MI with respect to the parameters of the considered separating model. In the literature, these calculations were mainly reported for linear mixtures up to now. They are more complex for nonlinear mixtures, due to dependencies between the considered quantities. Moreover, the notations commonly employed by the BSS community in such calculations may become misleading when using them for nonlinear mixtures, due to the above-mentioned dependencies. We claim that the ...

British Library Electronic Table of Contents (United Kingdom)

Leptospirillum ferriphilum and Acidithiobacillus caldus are two important acidophilic microorganisms involved in iron and sulfur oxidation during bioleaching. Cell adsorption to mineral surfaces is important for the direct leaching or contact leaching of minerals. In this study, we report the competitive adsorption of binary mixtures of L. ferriphilum LF-104 and A. caldus MTH-04 onto pyrite surfaces. The Langmuir adsorption parameter (CAm) indicated that these two bacteria underwent competitive adsorption to pyrite. Real-time quantitive PCR was used to quantify the relative amounts of L. ferriphilum and A. caldus adsorbed onto the surfaces of pyrite following exposure to a mixture of these two organisms. The adsorption of L. ferriphilum was not affected by A. caldus. However, adsorption of...

Science.gov (United States)

This report presents the results of a survey of the uses of the refrigeration available from vaporizing liquefied natural gas. The major emphasis of the study is on peakshaving plants, which liquefy and regasify domestic gas; the minor emphasis is on base-load terminals, which gasify imported LNG continuously. There are 54 full-scale LNG peakshaving plants in the US and several others under construction. The US has three operating base-load import terminals. One more is under construction and several more large terminals have been proposed. There are at least 12 foreign base-load import terminals in operation, and more are under construction or are proposed. The report presents a survey of operating conditions for about 15 large domestic peakshaving plants. It also presents published design data for the existing US import terminals, for the major proposed import terminals, and for the major overseas import terminals. The second section of the report presents the ...

British Library Electronic Table of Contents (United Kingdom)

Abstract Salmonella Typhimurium and Listeria monocytogenes are major bacterial pathogens associated with poultry products. A controlled released ClO2 sachet applied with modified atmosphere packaging (MAP) was evaluated for its ability to control the growth of S. Typhimurium and L. monocytogenes on raw chicken breast during refrigerated storage. The fresh chicken samples were inoculated with one or the other of the pathogens at 104-cfu/g, and the packages (with and without ClO2 sachet) were flushed with ambient air or 30% CO2/70% N2 before sealing, and then stored at 4C for up to 21 days. The maximum reduction in MAP plus ClO2 (compared with MAP alone) was 0.68-log-cfu/g for S. Typhimurium and 1.87-log-cfu/g for L. monocytogenes. Color and pH changes of the chicken breast were observed at ...

Energy Technology Data Exchange (ETDEWEB)

France has committed herself to keep in 2010 the same levels of greenhouse gas emissions as those of 1990, i.e. 144 millions of tons of carbon equivalent (MtCe). However, taking into account the existing pollution abatement measures and the measurements performed so far, the greenhouse gases level should reach 160 MtCe in 2010. Therefore, the inter-ministry commission on greenhouse effect decided on November 27, 1998 to elaborate a new national plan of fight against greenhouse effect. The elaboration of the new plan has fallen under the responsibility of the inter-ministry mission of greenhouse effect (MIES). The new plan was presented by the prime minister, L. Jospin, on January 19, 2000. This document summarises the content of the new plan: architecture (modalities of elaboration, content), measures for the reduction of greenhouse gas emissions (industry, transportation sector, buildings, agriculture-forestry, wastes valorization, development of renewable energies, ...

Energy Technology Data Exchange (ETDEWEB)

A system for real-time neutron radiography of moving objects is described. It comprise a source adapted to generate a continuous uninterrupted series of neutron pulses. Each pulse has a predetermined peak power and duration compatible with the framing times of a real-time video imaging system. A transporter moves an object to be examined to bring sequentially position selected portions of the object in the path of the pulses. Where the object itself has moving components, pulses are sequentially incident on the object. According to any dissimilarities, the object will alter the intensity of the neutrons passing therethrough. In order to record separately the changes in the neutron intensity, for each pulse, an imager is positioned to receive the neutron beam pulses which have been altered by their passage through the object and produce images indicating intensity alterations. A refrigerated beryllium filter can be used to effectively eliminate thermal neutrons from ...

Energy Technology Data Exchange (ETDEWEB)

The Synchrotron Resource of the Howard Hughes Medical Institute will be dedicated to structural analyses of biological macromolecules, primarily through crystallography. This facility is under construction at the X4 port of the National Synchrotron Light Source at Brookhaven National Laboratory, and it will comprise three beamlines. The first line to be built has been devised to apply the multiwavelength anomalous diffraction method which provides direct estimates for the phases of reflections. The second line will be devoted to rapid and essentially routine diffraction measurements, mainly through the rotation method. These two experimental stations are contained within refrigerated radiation enclosures that will maintain clean environments, narrowly defined constant temperatures, and protection against biohazard at biosafety level BL-2. At the same time as the second line will be developed, the swath center is planned to first serve as a monitor of the white ...

Energy Technology Data Exchange (ETDEWEB)

This report presents a reassessment of the design of Resistive Cryogenic Cable Systems with regard to dielectric material selection, thermal insulation selection, conductor design, and refrigeration subsystem design. An algorithm using test data generated as part of the program and available from the literature was developed and used to assess the driving parameters for system cost analysis. The results of this cost sensitivity analysis are presented. An electric utility, Public Service Electric and Gas of New Jersey (PSE and G), performed an economic viability evaluation comparing two selected Resistive Cryogenic Cable Systems to a conventional cable system (high pressure oil-filled). The comparison was made for a 35-mile network application on the PSE and G transmission system scheduled to be placed in service in 1995. Consideration was given to equipment capital, installation, and operating costs. It was concluded that a Multilayer Vacuum Insulated Resistive ...

Energy Technology Data Exchange (ETDEWEB)

This paper presents the performance analysis on a hybrid air-conditioning system according to the hybrid building energy system of the green building demonstration project in Shanghai, in which a 150 m{sup 2} solar collector is used to power two 10 kW adsorption chillers, a vapor compression heat pump is used to cool air in the evaporating end while the condensing heating at about 80{sup o}C is fully used to regenerate a liquid desiccant dehumidification system. In the hybrid system, the sensible cooling to the air is treated mainly by solar adsorption cooling and vapor compression cooling, whereas the latent heat is treated by the liquid desiccant dehumidification system with regeneration from the condensing heat of the heat pump. The results show that the performance of this system is 44.5% higher than conventional vapor compression system at a latent load of 30% and this improving can be achieved by 73.8% at a 42% latent load. The optimal ratio of adsorption ...

Science.gov (United States)

The Micro-X instrument is a rocket borne, X-ray imaging spectrometer planned for launch in October 2011. An array of 128 Transition Edge Sensors (TESs) on a 600 micron pitch will observe incoming photons in the 0.2-3 keV energy band with an energy resolution of 2-4 eV at 1 keV. X-rays will be focused onto the TES array by a conically approximated Wolter optic with an effective area of 300 cm^2 giving the instrument a field of view of 11.8 arcmin. This performance will constitute a substantial improvement over current non-dispersive detectors for X-ray spectroscopy of extended sources and will be the first demonstration of a TES-based microcalorimeter in space. The TESs will utilize the 50 mK stage of an Adiabatic Demagnetization Refrigerator (ADR) as a heat bath, and will be read out by a SQUID time division multiplexer. The first flight of the Micro-X instrument will observe the Puppis A supernova remnant. Future targets include the core of the Virgo cluster and ...

Energy Technology Data Exchange (ETDEWEB)

A centrifugal pump was developed for the efficient and reliable transfer of liquid helium in space. The pump can be used to refill cryostats on orbiting satellites which use liquid helium for refrigeration at extremely low temperatures. The pump meets the head and flow requirements of on-orbit helium transfer: a flow rate of 800 L/hr at a head of 128 J/kg. The overall pump efficiency at the design point is 0.45. The design head and flow requirements are met with zero net positive suction head, which is the condition in an orbiting helium supply Dewar. The mass transfer efficiency calculated for a space transfer operation is 0.99. Steel ball bearings are used with gas fiber-reinforced teflon retainers to provide solid lubrication. These bearings have demonstrated the longest life in liquid helium endurance tests under simulated pumping conditions. Technology developed in the project also has application for liquid helium circulation in terrestrial facilities and for ...

Energy Technology Data Exchange (ETDEWEB)

A study has been performed for the development and assessment of a subchannel analysis code which is purposed to be used for the analysis of advanced reactor conditions with various configurations of reactor core and several kinds of reactor coolant fluids. The subchannel analysis code was developed on the basis of MATRA code which is being developed at KAERI. A GUI (Graphic User Interface) system was adopted in order to reduce input error and to enhance user convenience. The subchannel code was complemented in the property calculation modules by including various fluids such as heavy liquid metal, gas, refrigerant,and supercritical water. The subchannel code was applied to calculate the local thermal hydraulic conditions inside the non-square test bundles which was employed for the analysis of CHF. The applicability of the subchannel code was evaluated for a high temperature gas cooled reactor condition and supercritical pressure conditions with water and Freon. A ...

British Library Electronic Table of Contents (United Kingdom)

Abstract:- Escherichia coli-O157:H7 and-Salmonella-spp. are bacterial pathogens often associated with beef, and cause many cases of foodborne illness each year in the United States. During beef slaughter and processing, these bacteria may spread from the hide or intestines to the carcass. The objective of this research was to investigate the use of naturally occurring compounds citrus essential oils (CEOs) extracted from orange peel to reduce or eliminate these pathogens at the chilling stage of processing, or during fabrication. Brisket flats (used to simulate beef subprimals) were spot inoculated with approximately 6 log of surrogate generic-E. coli-cocktail (previously shown to be identical in growth and survival parameters to-E. coli-O157:H7 and-Salmonella-spp.). Following drying, CEOs...

UK PubMed Central (United Kingdom)

1. Eight deuteranopes matched a mixture of a monochromatic light on the long wave side of the neutral point and a violet (450 nm) primary to a fixed white as well as a monochromatic light on the short...Full Text Available

International Nuclear Information System (INIS)

Molar excess volumes, VE, molar excess enthalpies, HE, and speeds of sound data, u, of chloroform (i) + aniline or o-toluidine (j) binary mixtures have been measured as a function of composition at 308.15 K. Isentropic compressibility changes of mixing, ?SE have been determined by employing speed of sound data. Topological investigations of VE data reveals that aniline, chloroform and o-toluidine are associated entities and these (i + j) mixtures contain a 1:1 molecular complex. The IR studies lend further support to the nature and extent of interaction for the proposed molecular entity in the mixtures. HE and ?SE values have also been calculated by employing Moelwyn-Huggins concept [Polymer 12 (1971) 387] taking topology of the constituents of the mixtures. It has been observed that calculated HE and ?SE values compare well with their corresponding experimental values. The observed VE, HE and ?SE data ...

International Nuclear Information System (INIS)

Molar excess volumes, VE, molar excess enthalpies, HE, and speeds of sound, u, of o-toluidine (i) + cyclohexane or n-hexane or n-heptane (j) binary mixtures have been determined over entire range of composition at 308.15 K. Speeds of sound data have been utilized to predict isentropic compressibility changes of mixing, ?SE of (i + j) mixtures. The observed VE, HE and ?SE data have been analyzed in terms of Graph theory. The analysis of VE data by Graph theory reveals that o-toluidine exists as an associated molecular entity and (i + j) mixtures contain 1:1 molecular complex. It has been observed that VE, HE and ?SE values calculated by Graph theory compare well with their corresponding experimental values. The observed data have also been analyzed in term of Flory theory.

UK PubMed Central (United Kingdom)

The world's oceans contain a complex mixture of micro-organisms that are for the most part, uncharacterized both genetically and biochemically. We report here a metagenomic study of the marine planktonic...Full Text Available

British Library Electronic Table of Contents (United Kingdom)

Rheological properties of moderately concentrated solutions of cellulose in methylmorpholine N-oxide-dimethylformamide mixtures containing hydrophilic montmorillonite nanoparticles were studied. Film composite materials were prepared, and their physicomechanical properties and structural organization were studied.

UK PubMed Central (United Kingdom)

Amphibian populations are declining globally at an alarming rate. Pesticides are among a number of proposed causes for these declines. Although a sizable database examining effects of pesticides on...Full Text Available

UK PubMed Central (United Kingdom)

Although two-dimensional polyacrylamide gel electrophoresis (2D-PAGE) has been used as the standard proteomic approach for separating proteins in a complex mixture, this technique has many drawbacks....Full Text Available

British Library Electronic Table of Contents (United Kingdom)

In this work, coals of various ranks were dissolved in an acid melange. With the use of IR spectroscopy, it was found that the mechanism of coal dissolution consists in the grafting of polar groups to the peripheral benzene rings of graphite-like systems.

Energy Technology Data Exchange (ETDEWEB)

A combination of degenerate four-wave mixing spectroscopy and a low-pressure sampling technique has been studied for isotopic analysis in an air-acetylene flame. Hyperfine spectra of D lines of sodium and several mixtures of lithium isotopes obtained in this way are presented.

Energy Technology Data Exchange (ETDEWEB)

New alloys of Cu.sub.x Ag.sub.(1-x) InSe.sub.2 (where x ranges between 0 and 1 and preferably has a value of about 0.75) and CuIn.sub.y Ga.sub.(1-y) Se.sub.2 (where y ranges between 0 and 1 and preferably has a value of about 0.90) in the form of single crystals with enhanced structure perfection, which crystals are substantially free of fissures are disclosed. Processes are disclosed for preparing the new alloys of Cu.sub.x Ag.sub.(1-x) InSe.sub.2. The process includes placing stoichiometric quantities of a Cu, Ag, In, and Se reaction mixture or stoichiometric quantities of a Cu, In, Ga, and Se reaction mixture in a refractory crucible in such a manner that the reaction mixture is surrounded by B.sub.2 O.sub.3, placing the thus loaded crucible in a chamber under a high pressure atmosphere of inert gas to confine the volatile Se to the crucible, and heating the reaction mixture to its melting point. The ...

UK PubMed Central (United Kingdom)

Anaerobic treatment of a volatile fatty acid (VFA) mixture was investigated under psychrophilic (3 to 8°C) conditions in two laboratory-scale expanded granular sludge bed reactor stages in series....Full Text Available

Energy Technology Data Exchange (ETDEWEB)

This book contains papers relating to the 1990 Future Transportation Technology Conference and Exposition. Included are the following papers; Examination of rich mixtures operation of a dual fuel engine, A hybrid natural gas vehicles, Performance analysis of a spark ignited engine with ETBE as a blending agent.

UK PubMed Central (United Kingdom)

The aromas of fruits, vegetables, and flowers are mixtures of volatile metabolites, often present in parts per billion levels or less. We show here that tomato (Lycopersicon esculentum...Full Text Available

UK PubMed Central (United Kingdom)

BackgroundSupplementation of nutritional deficiencies helps to improve immune function and resistance to infections in malnourished subjects. However, the suggested benefits of dietary...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

In the development of the specific mathematical modeling for heavy and ultra heavy petroleum fractions in a molecular distiller is very important the definition of physical and chemical parameters as density and specific heat of the mixture, the enthalpy of vaporization, among others, since they are used in the energy balance. Information on these properties and their variation with temperature are found in the open literature for mixture with few components (simple mixtures). However, for multicomponent solutions consisting of complex mixtures such as oil and its heavy and ultraheavy fractions, available data are few, or are limited to low temperatures. The specific heat is an important property in the energy balance. This property can be measured by Differential Scanning Calorimetry (DSC), which gives results with great sensitivity and accuracy. This paper presents the variation of specific heat with ...

Energy Technology Data Exchange (ETDEWEB)

The industrial standard process for the purification of natural gas is to remove acid gases, mainly hydrogen sulfide and carbon dioxide, by the absorption and reaction of these gases with alkanolamines. Inadequate data for vapor -- liquid equilibrium (VLE) hinder the industry from converting operations to more energy efficient amine mixtures and conserving energy. Some energy reductions have been realized in the past decade by applying such amine systems as hindered'' amines, methyldiethanolamine (MDEA), and MDEA based amine mixtures. However, the lack of reliable and accurate fundamental VLE data impedes the commercial application of these more efficient alkanolamine systems. The first project objective is to improve the accuracy of vapor -- liquid equilibrium measurements at low hydrogen sulfide concentrations. The second project objective is to measure the VLE for amine mixtures. By improving the ...

UK PubMed Central (United Kingdom)

The monoterpene fraction of the lemon-scented sweet basil (Ocimum basilicum) cv Sweet Dani consists mostly of citral (a mixture of geranial and neral), with lower levels of geraniol...Full Text Available

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A process is claimed for selectively preparing alpha-olefins having from 2 to about 22 carbon atoms by contacting a gaseous mixture containing carbon monoxide and hydrogen with an iron titanate alkali metal hydroxide catalyst at reaction conditions correlated so as to favor the formation of a substantial proportion of such alpha-olefin product.

Science.gov (United States)

A method of producing blast furnace coke from bituminous coals, particularly coals having poor coking capacities in which the coal to be carbonized is ground, predried or preheated, mixed with binders, compressed or formed into briquets having small mechanical resistances and charged into oven chambers, is characterized by fine coals or fine coal mixtures having a swelling index in mixture according to DIN 51741, smaller than 7, and preferably, below 6, and comprising more than 50% of poorly or non-baking coal having a content of volatile matter in excess of 30% or less than 20% which coals or coal mixtures are ground up to attain a surface per unit mass, according to DIN 66145, of from 400 cm/sup 2/ to 1200 cm/sup 2/ per gram, with from 3% to 8% by weight of organic binders, compressing the mixture to form it into a briquet at a temperature range of from 70/sup 0/C to 300/sup 0/C and charging the ...

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A sequential port injection, lean-burn, fully electronically-controlled compressed natural gas (CNG)/diesel dual-fuel engine has been developed based on a turbo-charged and inter-cooled direct injection (D.I.) diesel engine. During the optimisation of engine overall performance, the effects of pilot diesel and premixed CNG/air mixture equivalence ratio on emissions (CO, HC, NO{sub x}, soot), knocking, misfire and fuel economy are studied. The rich and lean boundaries of the premixed CNG/air mixture versus engine load are also provided, considering the acceptable values of NO{sub x} and THC emissions, respectively. It is interesting to find that there is a critical amount of pilot diesel for each load and speed point, which proved to be the optimum amount of pilot fuel. Any decrease in the amount of pilot diesel from this optimum amount results in an increase of NO{sub x} emissions, because the premixed CNG/air mixture must ...

Science.gov (United States)

The study is concerned with the Stefan problem of evaporation of a volatile component from its solution with a virtually non-volatile material. The analysis provides an analytical solution to the problem based on mass-transfer fundamentals. Results yield the evaporation rate, interfacial mole fractions, concentration profiles in the gas and liquid phases, and the location of the evaporation front. The analysis can be used to provide the binary liquid diffusion coefficient of the volatile component based on experimental data for the liquid gas interface position as a function of time. The requirements for such a measurement are discussed in terms of the volatility of the evaporating component and its initial concentration in the liquid mixture.[Figure not available: see fulltext.

Energy Technology Data Exchange (ETDEWEB)

Densities were measured with a vibrating-tube densimeter for binary mixtures of dimethyl sulfoxide + thiophene at temperatures from 293.15 to 313.15 K as a function of composition. Molar excess volumes V[sup E] for the mixtures, determined from the density data, are negative and become more negative with an increase in temperature. The coefficients of thermal expansion were also evaluated from the temperature dependence of the density.

British Library Electronic Table of Contents (United Kingdom)

The effect of the degree of degradation of the components of a model municipal plastic waste (a mixture of low-density polyethylene, high-density polyethylene, polypropylene and high-impact polystyrene) on the toughness and stability of recyclates compatibilised with a cooperative compatibilisation system (a mixture of ethylene-propylene statistical and styrene-butadiene block copolymers with a secondary amine-based stabiliser) was studied. It was shown that good impact strength was achieved for recyclates having components with a low or medium degree of degradation. Mechanical properties of recyclates having the components with a high degree of degradation are deteriorated. The addition of the cooperative compatibilisation system leads to a higher thermo-oxidative stability of recyclates ...

Science.gov (United States)

A method of making high strength coke briquettes suitable for use as blast furnace coke comprising, (A) providing coal, (B) heating the coal at a temperature at or above the softening point of the coal to form partially carbonized char, (C) cooling the partially carbonized char below the softening point of the coal, (D) mixing the cooled partially carbonized char and tar to form a mixture of tar and partially carbonized char, (E) briquetting the mixture of tar and partially carbonized char to form briquettes of tar and partially carbonized char, (F) calcinating the briquettes to form high strength briquettes.

CERN Document Server

We propose a mechanism to explain what occurs when a mixture of grains of different sizes and different shapes (i.e. different repose angles) is poured into a quasi-two-dimensional cell. Specifically, we develop a model that displays spontaneous stratification of the large and small grains in alternating layers. We find that the key requirement for stratification is a difference in the repose angles of the two pure species, a prediction confirmed by experimental findings. We also identify a kink mechanism that appears to describe essential aspects of the dynamics of stratification.

Energy Technology Data Exchange (ETDEWEB)

This patent describes a nitrogen oxides decreasing combustion method which comprises: a first step of mixing a fuel and air with each other; a second step of bringing the mixture obtained in the first step into contact with a packed catalyst such that only catalytic combustion occurs; and a third step of adding a fresh supply of the fuel to a stream obtained from the second step to form a mixed gas and causing the mixed gas to undergo non-catalytic thermal combustion. The temperature of the packed catalyst is lower than the ignition temperature of the mixture and the adiabatic flame temperature of the mixed gas is lower than a temperature at which the nitrogen oxides occur.

International Nuclear Information System (INIS)

A mixture of powders of silica and aluminum nitride is subjected to high-energy ball milling for different milling times. This material is subsequently compacted by uniaxial pressing and sintered at 1450 deg. C. The resulting pellets are crushed and analysed by X-ray diffraction. For short milling times, the amount of phase transformation is minimal and the resulting material mostly consists of cristobalite and aluminum nitride. For long milling times, nanocrystalline #beta#-SiAl_2O_2N_2 is mainly produced.

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A dual fuel engine control system for controlling the power output of a dual fuel compression ignition engine. The engine includes mixing means for combining an oxidizer and a primary fuel at a substantially constant ratio of oxidizer to primary fuel. The power output of the engine is controlled through the use of a throttle valve controlling the quantity of combustible mixture delivered to the combustion chamber. The fuel control system minimizes the quantity of ignition fuel required by controlling the quantity of combustible mixture rather than the fuel of air ratio. (author) figs.

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An analysis based on Jaroniec's theory of mixed gas adsorption showed that for two arbitrary adsorbing gas components the ratio of their surface coverages is a simple power function of the ratio of their partial pressures. This result was verified with available experimental data on the adsorption of C/sub 1/-C/sub 4/ hydrocarbon binary mixtures, CO/sub 2//C/sub 2/H/sub 4/, and N/sub 2//CO on various carbons, silica gel, and cesium iodide.

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Close coupled expressions for phenomenological cross sections which describe transport properties of atom--diatom mixtures are obtained in the total-J coupling scheme and are related to the bracket integrals of kinetic theory. Coupled states and infinite order sudden expressions for the generalized phenomenological cross sections using initial, final, and average l-labeling are also given. Particular care is taken to use a phase convention for the CS and IOS approximations which is consistent with the Arthurs--Dalgarno formalism and which gives the correct behavior of degeneracy averaged differential cross sections.

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This is the first time that the adsorption of binary mixtures of polycyclic aromatic hydrocarbons (PAHs) has been studied. This study was carried out at laboratory scale in an experimental apparatus specially designed for this aim: with gas-phase fluorescence, a new detection procedure was used. Experimental conditions, mainly in terms of temperature (150C) and contaminant concentration (approximately 1 ppmv), close to the ones observed in energy generation systems, were applied. The PAH adsorption process interpretation was carried out by recording the experimentally obtained breakthrough curves. After the detection parameter optimization, the influence of adsorbate characteristics in the hot gas cleaning of PAH was studied. In this system, the adsorption of 10 binary mixtures of five PAH (naphthalene (Np), fluorene (Fu), phenanthrene (Phe), fluoranthene (Fl), and pyrene (Py)) on an activated carbon was investigated. It was found that the ...

International Nuclear Information System (INIS)

Volumetric properties of liquid mixtures of neon and hydrogen have been calculated using path integral hybrid Monte Carlo simulations. Realistic potentials have been used for the three interactions involved. Molar volumes and excess volumes of these mixtures have been evaluated for various compositions at 29 and 31.14 K, and 30 atm. Significant quantum effects are observed in molar volumes. Quantum simulations agree well with experimental molar volumes. Calculated excess volumes agree qualitatively with experimental values. However, contrary to the existing understanding that large positive deviations from ideal mixtures are caused due to quantum effects in Ne - H_2 mixtures, both classical as well as quantum simulations predict the large positive deviations from ideal mixtures. Further investigations using two other Ne - H_2 potentials of Lennard - Jones (LJ) type show that excess ...

Science.gov (United States)

The mixture of 1,3-dichloropropene (1,3-D) and chloropicrin (CP) is used as a preplant soil fumigant. In comparison with individual fumigants, application of a mixture may affect the environmental dissipation and fate of each chemical, such as emission and degradation. We investigated the degradation of CP, 1,3-D, and their mixture in fresh soils and sterile soils, and evaluated the competitive characteristic of fumigants in the mixture. The degradation of low concentrations of CP in fresh soil was accelerated at early times in the presence of 1,3-D, whereas the addition of CP reduced the degradation rate of trans-1,3-D, possibly by inhibiting the activity of trans-1,3-D degrading microorganisms. The potential of applying amendments to the soil to increase the rate of CP and 1,3-D degradation was also illustrated. The degradation of both fumigants was significantly enhanced in soils amended with ...

Energy Technology Data Exchange (ETDEWEB)

Although polybrominated naphthalenes (PBNs) are contaminants of the commercial fire retardant fireMaster BP-6, the individual PBN isomers have not been identified. In order to study PBNs possessing an analogous level of bromination to those found in fireMaster BP-6, three synthetic PBN mixtures, averaging 5.0, 5.3, and 5.6 bromines per naphthalene were synthetized and partially characterized. The PBN mixtures were administered to immature male Wistar rats and found to be potent inducers of cytochrome P-450-dependent monooxygenases. At the lowest dose tested, 30 mumol X kg-1, each PBN mixture caused maximal induction of benzo(a)pyrene hydroxylase activity. On the basis of enzyme activities, ligand-binding spectra and sodium dodecyl sulfate-polyacrylamide gel electrophoresis, the PBN mixtures were determined to be 3-methylcholanthrene-type inducers of cytochrome P-450 (P-448), resembling qualitatively the ...

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Large scale experiments were performed to determine the effectiveness of thermal glow plug igniters to burn hydrogen in a condensing steam environment due to the presence of water sprays. The experiments were designed to determine if a detonation or accelerated flame could occur in a hydrogen-air-steam mixture which was initially nonflammable due to steam dilution but was rendered flammable by rapid steam condensation due to water sprays. Eleven Hydrogen Igniter Tests were conducted in the test vessel. The vessel was instrumented with pressure transducers, thermocouple rakes, gas grab sample bottles, hydrogen microsensors, and cameras. The vessel contained two prototypic engineered systems: (1) a deliberate hydrogen ignition system and (2) a water spray system. Experiments were conducted under conditions scaled to be nearly prototypic of those expected in Advanced Light Water Reactors (such as the Combustion Engineering (CE) System 80+), with prototypic spray drop ...

International Nuclear Information System (INIS)

The excess molar volumes V_m"E for binary liquid mixtures containing dipropylene glycol monomethyl ether or dipropylene glycol monobutyl ether and methanol, 1-propanol, 1-pentanol and 1-heptanol have been measured as a function of composition using a continuous dilution dilatometer at T=(288.15, 298.15, and 308.15) K and atmospheric pressure over the whole concentration range. The excess volume results allowed the following mixing quantities to be reported in all range of concentrations or at equimolar concentrations: #alpha#, volume expansivity; (#partial deriv#V_m"E/#partial deriv#T)_p; (#partial deriv#H"E/#partial deriv#P)_T at T=298.15 K. The obtained results have been compared at T=298.15 K with the calculated values by using the Flory theory of liquid mixtures. The theory predicts the #alpha#, and #alpha#"E values rather well, while the calculated values of (#partial deriv#V_m"E/#partial deriv#T)_p and (#partial deriv#H"E/#partial ...

Energy Technology Data Exchange (ETDEWEB)

Cryogenic distillation is the main industrial method for separating hydrogen's isotopes, because it presents the advantage of high separating factors and also the possibility of processing great quantities of gases. In the case of multicomponent mixtures the determination of transport for molecular species between the two phases is very difficult owing to the particularities of physical characteristics of each component from the mixture. The transport of molecular species is also strongly influenced by the hydrodynamics of two phases, in strong connection with the dimension of the interface between the vapor and liquid phase. The characteristics of the interface depend on the type and geometry of the separation area: plates or package. The traditional methods of analysis for exchange processes use the concept 'theoretic plate', a physical entity for which the values of concentrations for vapors and liquid that leaves ...

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This paper deals with the energy required to separate ethanol from an aqueous solution in a distillation column containing a solid phase. The solid phases evaluated consisted of either an amylatious (ground corn) or a cellulose (sugar cane bagasse) absorber whit particle sizes smaller than 4 mm. The water-retention capacity of each solid phase was measured by passing vapors or ethanol-water mixtures through the solid phase. When starting with initial concentrations bellow the azeotropic point, ethanol concentrations up to 99,5% (on corn) and 97,2% (on sugar cane) were achieved. The water content was evaluated potentiometrically (Karl`Fischer). Regarding the 2-4 mm ground corn solid phase column, the energy consumed was estimated to be reduced by 15,6% and 60% (by weight) ethanol-water mixture respectively. (author) 11 refs., 2 figs., 2 tabs

Energy Technology Data Exchange (ETDEWEB)

Clay-based materials can be cold-stabilized using binder and formed by extrusion. This paper deals with the properties of such materials under the influence of silico-aluminous flying ashes addition. Flying ashes are solid industrial wastes produced by coal combustion. Characteristics of ashes bearing clay-based products, such as dimensional stability, water and mechanical resistance, accelerated aging, are considerably improved with respect to simple clay-binder mixtures. This is principally due to a better hydration of the binder in ashes-bearing mixtures because of: a higher free-water availability as a consequence of the smaller specific surface of ash grains, the filler effect of ash grains which do not participate to the reactions, the specific property of silico-aluminous ashes that can fix the lime in presence of water to produce hydrated compounds. These ashes-bearing clay based materials can have the same qualities as classical ...

Energy Technology Data Exchange (ETDEWEB)

Combustion of extremely fuel-rich ({phi}=4) methane/air mixtures at elevated pressures is investigated as a potential means to generate molecular hydrogen by non-catalytic partial oxidation. This system is investigated both computationally and experimentally. The computations use a perfectly-stirred reactor model and an explicit methane cool-flame mechanism to investigate the effects of reactor parameters on reaction time and product composition. Under adiabatic conditions, such mixtures are predicted to autoignite at low temperatures {approx}700 K for pressures exceeding 8.5 atm. Above 15 atm, conversion to products is complete in roughly 1 s. The dependence of reaction time and hydrogen yield is investigated as a function of inlet temperature, system pressure, and flame equivalence ratio. Actual product yields are measured in a tube reactor facility, and many of the predictions of the model, including long relaxation times to chemical ...

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The impact of a mixture of oxytetracycline, chlortetracycline, tetracycline and doxycycline on Myriophyllum sibiricum and Lemna gibba was investigated using fifteen 12,000-L microcosms (k = 5, n = 3). Significant concentration-response relationships were only found for M. sibiricum, where dry mass was 69, 47, 30, and 7% of controls at respective treatment concentrations of 0.080, 0.218, 0.668, and 2.289 {mu}mol/L. Somatic endpoints were strongly and negatively correlated with percent light transmission, except plant length, which was positively correlated. Treated microcosms experienced a reduction in the percent of surface irradiance penetrating the water column as high as 99.8% at a depth of 70 cm, relative to controls. Position relative to the water column was likely responsible for the differential effects observed between floating (L. gibba) and submerged (M. sibiricum) species of macrophytes. A hazard quotient assessment of the lowest EC{sub 10} value ...

Energy Technology Data Exchange (ETDEWEB)

In order to develop modern two-stroke engines with low fuel consumption, respectively with low exhaust emissions, two alternative development areas -- the mixture formation and the scavenging system -- have been correlated. For a satisfying mixture formation without fuel losses by scavenging, the direct injection seems to be one of the best solution for the high speed two-stroke engine of the future. On the other hand the modern development of two-stroke scavenging systems shows a large field of application and improvement methods of cross and loop scavenging. Based on the specific optimization factors of the injection system, respectively of the scavenging system, the aim off this common work of the Universities of Pisa and Zwickau is to correlate both the optimization fields in an advantageous mixture formation process. The principal elements of this correlation are the design of the combustion chamber, the position of ...

Energy Technology Data Exchange (ETDEWEB)

The industrial standard process for the purification of natural gas is to remove acid gases, mainly hydrogen sulfide and carbon dioxide, by the absorption and reaction of these gases with alkanolamines. The natural gas industry requires vapor-liquid equilibrium (VLE) data to develop more energy efficient amine mixtures. Some energy reductions have been realized in the past decade by applying such amine systems as hindered amines, methyldiethanolamine (MDEA), and MDEA based amine mixtures. However, the lack of reliable and accurate VLE data impedes the commercial application of these more efficient alkanolamine systems. The first objective of this project is to improve the accuracy of vapor-liquid equilibrium measurements at low hydrogen sulfide concentrations. The second objective is to make VLE measurements for amine mixtures. By improving the accuracy of the VLE data on MDEA and other amines, energy savings can be ...

Energy Technology Data Exchange (ETDEWEB)

Basic experimental investigations were carried out with an aqueous solution of a mixture of KOH and NaOH for use as an absorbent in absorption heat pumps. Due to its thermophysical properties this mixture allows temperature lifts from evaporator to absorber of more than 75 K (135 F) in a single-stage absorption chiller. Thermophysical and hydrodynamical properties of the solution were measured. Vapor-liquid-equilibrium data and specific heat capacities were determined for concentrations ranging from 35% up to 75% and temperatures up to 200 C (392 F). From these data the enthalpy of the solution was calculated. Additionally the crystallization temperatures, the density, and the viscosity of the solution were determined. The experimental equipment is described. The data are presented as polynomials and diagrams including experimental accuracy. An apparatus was constructed to measure heat and mass transfer coefficients of the absorption process ...

International Nuclear Information System (INIS)

Alloy 800 and Alloy 600 are well known for their resistance to corrosion in an aqueous medium at high pressure and temperature, for which they have been widely used for more than 3 decades in different structural components of water refrigerated nuclear reactors, especially as material for the steam generator tubes (SG) in these nuclear plants. The SG tubes in the Atucha I and Embalse Nuclear Plants are made with Alloy 800. The speed of corrosion of these materials in a reactor's refrigerant medium, while very small is perfectly measurable and can be described by parabolic or logarithmic type kinetics. In other words this speed is high in the first states of growth during the formation of a protective oxide film but then drops to almost stationary values. One characteristic of these films is the formation of a double layer (or duplex): i) an internal adhering layer, of approximately constant thickness, formed by small microcrystals (#<=#0.05 ...

International Nuclear Information System (INIS)

On all steam turbines operating with condensation the air leakage penetrating from the part of the plant which is under vacuum must be eliminated, in order to maintain the vacuum created by physical conditions. In order to attain effective air bleed-off, the water-steam-air mixture is conveyed via the super-cooling bundles in the condenser. In this way the steam partial pressure decreases and the air partial pressure increases at a constant condenser pressure. In this procedure the mixture is supercooled by about 4"0C compared with the saturate steam temperature appertaining to the condenser pressure. The values of volume of air leakage are the result of a year's experience on existing plant. (orig.).

British Library Electronic Table of Contents (United Kingdom)

In this work an experimental study is carried out to determine the thermo-hydraulic performance of an intercooler (IC) with flat tubes provided with triangular plain internal fins and louvered external fins when it is used on a car equipped with a low pressure EGR. The main unknowns to be answered are the thermo-hydraulic characteristics of the IC working under humid conditions induced by EGR, the conditions under which the water content in the mixture of air and exhaust gases begins to condense and the conditions under which the condensed water will be retained inside the IC. The exhaust gases are here replaced by a mixture of dry air and water vapour which are mixed upstream of the IC. The IC is submitted at the following testing conditions: on the ambient air side, the air temperature i...

International Nuclear Information System (INIS)

The extraction of Am(III) and Eu(III) has been investigated using mixtures of synthesized aromatic dithiophosphinic acids (R_2PSSH) and tributylphosphate (TBP), trioctylphosphine oxide (TOPO) or tributylphosphine oxide (TBPO) in toluene from nitric acid (0.01-1.5 mol l"-"1). There was no detectable extraction when R_2PSSHs were used alone as extractants for either Am(III) or Eu(III) (D_A_m_,_E_u<10"-"4) under the experimental conditions used in this study. High separation factors (D_A_m/D_E_u>20) with D_A_m>1 were achieved in the nitric acid range 0.1-1 moll"-"1 by means of a synergistic mixture of bischlorodithiophosphinic acid with TBP, TOPO or TBPO. (orig.)

International Nuclear Information System (INIS)

Hydrostatic weighing was used to measure the pre-melt density of crystalline eutectic mixtures of alkaline metal chlorides of the compositions (mole fractions): 0.605 LiCl + 0.395 CsCl, 0.585 LiCl + 0.415 KCl, 0.297 NaCl + 0.246 KCl + 0.457 CsCl, and 0.348 NaCl + 0.652 CsCl with melting points 598, 628, 753, 763 K, respectively, as a function of temperature. In the same temperature ranges, the compressibility and molar volume of eutectics as well as their sudden change upon melting were estimated. Unusual variations of these properties were revealed near the crystal/liquid phase transition, which were related to local disordering of particle configuration

British Library Electronic Table of Contents (United Kingdom)

Classical methods for the study of complex fluid phase behavior include static and dynamic equilibrium cells that usually require vapor and liquid recirculation. These are sophisticated, costly apparatus that require highly trained operators, usually months of labor-intensive work per mixture, and the data analysis is also rather complex. Simpler approaches to the fundamental study of azeotropes are highly desirable, even if they provide only selected cuts through the phase diagram. Recently, we introduced an advanced distillation curve measurement method featuring: (1) a composition explicit data channel for each distillate fraction (for both qualitative and quantitative analysis), (2) temperature measurements that are true thermodynamic state points that can be modeled with an equation o...

British Library Electronic Table of Contents (United Kingdom)

Oxygenated fuels increase fuel consumption due to their low enthalpy of combustion; however, their high antiknock index renders them suitable for use in engines with a high compression rate, increasing their thermal yield. This study evaluated the performance of biorenewable oxygenated fuels (ethanol and isoamyl alcohol) and partially renewable fuels (ETBE: ethyl tert-butyl ether, TAEE: tert-amyl ethyl ether and di-TAE: di-tert-amyl ether) with high degree of purity and in mixtures with automotive gasoline, based on tests with Otto cycle engines. Among the oxygenated fuels evaluated here, di-TAE was found to present the best characteristics of performance, both individually and in mixtures with gasoline.

Energy Technology Data Exchange (ETDEWEB)

A simple method is presented for the separation of lead-203 from copper-backed thallium cyclotron targets. The procedure involves cation-exchange chromatography in hydrochloric acid and hydrochloric acid-acetone mixtures. Further purification involves anion-exchange chromatography in nitric acid-hydrobromic acid mixtures. A cation-exchange column containing 3.0 g of resin can handle as much as 15 g of thallium and 160 mg of copper. An anion-exchange column containing 3.0 g of resin can separate lead from up to 200 mg of thallium and 10 mg of copper. Separations are extremely sharp and less than 0.1 ..mu..g of thallium and less than 0.1 ..mu..g of copper remain in the lead-203 fraction.

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All measurements were made with the NBS high-pressure photoionization mass spectrometer. The fractional of C/sub 5/H/sub 10//sup +/ions in a cyclopentane-cyclohexane mixture were determined as a function of pressure in order to define the fraction of the ions which did charge exchange with cyclohexane; i.e. the fraction which remained cyclic after ionization. The data for mixtures of various compositions (2.5 to 10% cyclohexane) are summarized for measurements performed at 10.62 eV: (a) 292K, > 96% cyclic; 347 K, greater than or equal to 94% cyclic; 386 K, 84 +- 4% cyclic; and 412 K, 78 +- 6% cyclic; entropy, enthalpy, and activation energy were determined; 10.49 eV was obtained as the ionization potential of cyclopentane. 1 figure.

International Nuclear Information System (INIS)

This study was the analyse the relationship between properties of ion nitrided Fe sintered material and parameters of plasma nitriding process. Pure fe sintered materials (relative density : 92%) were fabricated by hot-pressing and nitrided under pulsed DC plasma for 4 hours. The large number of parameters in plasma diffusion treatment allows close control of the process so that surface layers with defined microstructures and properties can be obtained. The number of micropores in nitriding layer can be reduced in pulsed DC plasma by reducing the plasma power and by varying the gas mixture. The phase constitution of compound layer of nitrided Fe sintered material were influenced by gas mixture (N_2 : H_2) and pulsed ratio (pulse on/off time ratio).

Energy Technology Data Exchange (ETDEWEB)

Atmospheric pressure tests were performed in which a palladium catalyst ignites and stabilizes the homogeneous combustion of methane. Palladium exhibited a reversible deactivation at temperatures above 750 C, which acted to ``self-regulate`` its operating temperature. A properly treated palladium catalyst could be employed to preheat a methane/air mixture to temperatures required for ignition of gaseous combustion (ca. 800 C) without itself being exposed to the mixture adiabatic flame temperature. The operating temperature of the palladium was found to be relatively insensitive to the methane fuel concentration or catalyst inlet temperature over a wide range of conditions. Thus, palladium is well suited for application in the ignition and stabilization of methane combustion.

International Nuclear Information System (INIS)

In evaluating commercialization prospects for natural gas fuelled vehicles, this paper compares the performance and emission quality of these innovative vehicles with those using conventional fuels - gasoline and diesel fuels. Assessments are made of the state-of-the-art of current technology relative to fuel storage, air/fuel mixture preparation, in cylinder combustion processes and pollution control. The analysis evidences that while natural gas is an excellent fuel for spark ignition engines, in transport applications its use is hampered by large storage volume requirements and weight. Moreover, the air/fuel mixture preparation, combustion process and exhaust-gas cleaning require a greater research and development effort to make this alternative fuel economically and environmentally competitive with conventional fuels.

British Library Electronic Table of Contents (United Kingdom)

We have studied the nature of continuum emitted in the visible spectral range from a noncontracted positive column of discharge in a cesium vapor-xenon mixture at a pressure of 45 Torr and at a degree of ionization below 3 ? 10?6. The main contribution to the continuous emission under such conditions is due to electron-xenon atom bremsstrahlung. The intensity of emission has been experimentally and theoretically studied as a function of the electric field strength and electron density in the positive column. It is established that an increase in the visible emission intensity with the electric field strength is related to an increase in the number of hot electrons in plasma.

British Library Electronic Table of Contents (United Kingdom)

This paper aims to study fundamentally the impacts of membrane properties on the reactive dye removal from dye/salt mixtures by nanofiltration membranes. To begin with, two types of nanofiltration membranes of similar pore size, namely asymmetric cellulose acetate membrane and thin-film composite polyamide membrane were fabricated, and their key physical, chemical and performance properties were characterized. After that, these resultant membranes were employed to perform dye removal experiments with aqueous solutions of reactive black 5 and NaCl under different operational parameters. The dye removal rate and steady permeate flux were determined and correlated with the measured membrane properties. It was found that there were significant differences between the dye removal performances o...

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Certain fluorocarbons, such as difluorodichloromethane (FC 12), depress the cardiovascular system by diminution of all the transmembrane ionic conductances in cardiac tissues. Does FC 12 also inhibit active transport and thus enzymatic activity and cellular energy. We measured phosphocreatine (PC), adenosine triphosphate (ATP) and cyclic adenosine monophosphate (AMPc) in rat hearts. Rats were randomly divided into 4 groups; 2 control groups: one breathing a mixture of oxygen (21%) and nitrogen (79%) (group C) and the other breathing the same mixture but simultaneously perfused with 1 microgram/kg/min. epinephrine (groupe E-C); 2 trial groups T and E-T where nitrogen was replaced by FC 12. The maximal FC 12 concentration of 720 micrograms/ml in arterial blood produced no significant difference in the concentrations of these three metabolites compared with controls.

Energy Technology Data Exchange (ETDEWEB)

Effect of alcohol solvent in mixing process on process on the microstructure and sintering behavior of ceramic-based composites was inestigated in detail. The mixture of fine ceramic powders was prepared through the conventional ball-milling method with various alcohol media. The particle distributions of fine ceramic powders were strongly dependent on the kind of alcohol employed during ball-milling. Ceramic-based composites were fabricated by hot-pressing the mixture of fine ceramic powders. Their microstructures and some mechanical properties of the ceramic-based composites were evaluated. It was found that the viscosity of alcohol, surface tension and contat angle greatly affect the sinterbility and some of the mechanical properties of ceramic-based somposites. (author)

British Library Electronic Table of Contents (United Kingdom)

Injections of fuel-grade ethanol (95% v/v ethanol, 5% v/v hydrocarbon mixture as a denaturant) near the water table were conducted in two-dimensional physical models tightly packed with fine sands under varying water-table conditions. As the fuel migrated in the porous media following injection, the denaturant phase separated leaving a residual Light Non-Aqueous Phase Liquid (LNAPL) phase that occupied a region with a volume similar to that of an equal-sized spill of 100% LNAPL without ethanol. When the water table was raised, as may be expected following a catastrophic release that reaches groundwater, most of the ethanol-fuel mixture was mobilized and the vertical distribution of the generated LNAPL was increased. The lower boundary of the residual LNAPL was established during the initia...

International Nuclear Information System (INIS)

Composite materials of synthetics (based on monomers, oligomers and thermoplastics) and of natural polymers (wood and other fibrous cellulosics) prepared by radiation processing, offer valuable structural materials with enhanced coupling forces between the components. The applied polymer chemistry of such composites shows several common features with that of radiation grafting, e.g. the polymerization rate of oligomer-monomer mixtures in wood remains in most cases proportional to the square-root of the initiating dose-rate, just as in the simultaneous grafting, demonstrating that the chain termination kinetics remain regularly bimolecular in the corresponding dose-rate ranges. In the processing experiences of such composites, low dose requirement, easy process-control, and good technical feasibility have been found for composites of wood with oligomer-monomer mixtures, for coconut fibres with unsaturated polyesters and for pretreated wood fibre ...

International Nuclear Information System (INIS)

The phytochemical investigation of Chomelia obtusa leaves led to the isolation of four triterpenes (3-O-#beta#-D-quinovopyranosyl-28-O-#beta#-D-glycopyranosyl quinovic acid, 3-O-#beta#-D-quinovopyranosyl-28-O-#beta#-D-glycopyranosyl cincholic acid, and a mixture of ursolic and oleanolic acids), two flavonoids (3-O-#beta#-D-glycopyranosyl quercetin, 3-O-[#alpha#-L-rhamnopyranosyl-(1#->#6)-#beta#-D-galactopyranoside] quercetin), besides bornesitol and a mixture of 3,5- and 4,5-O-dicaffeoyl quinic acids. The structures of the isolated compounds were assigned on the basis of spectroscopic data, including two-dimensional NMR methods. The anti-inflammatory and antioxidant activities of the crude methanolic extract and of its fractions were evaluated. This is the first report on the chemical and biological investigation of the Chomelia genus. (author)

British Library Electronic Table of Contents (United Kingdom)

Bio-inspired silver nanoparticles were synthesized with the aid of a novel, non-toxic, eco-friendly biological material namely, banana peel extract (BPE). Boiled, crushed, acetone precipitated, air-dried peel powder was used for reducing silver nitrate. Silver nanoparticles were formed when the reaction conditions were altered with respect to pH, BPE content, concentration of silver nitrate and incubation temperature. The colorless reaction mixtures turned brown and displayed UV-visible spectra characteristic of silver nanoparticles. Scanning electron microscope (SEM) observations revealed the predominance of silver nanosized crystallites after short incubation periods. When the reaction mixtures were incubated for 15 days, some micro-aggregates were also observed. Energy dispersive spectr...

Energy Technology Data Exchange (ETDEWEB)

The catalytically stabilised thermal combustion (CST) of lean hydrogen-air mixtures was investigated numerically in a turbulent channel flow configuration using a two-dimensional elliptic model with detailed heterogeneous and homogeneous chemical reactions. Comparison between turbulent and laminar cases having the same incoming mean properties shows that turbulence inhibits homogeneous ignition due to increased heat transport away from the near-wall layer. The peak root-mean-square temperature and species fluctuations are always located outside the extent of the homogeneous reaction zone indicating that thermochemical fluctuations have no significant influence on gaseous combustion. (author) 4 figs., 6 refs.

Energy Technology Data Exchange (ETDEWEB)

The bulk removal of CO/sub 2/ from industrial gases is a frequently applied process in the field of gas-treating. Usually chemical solvents are used in order to increase both the solvent-loading capacity and the absorption rate. These solvents often are aqueous solutions of alkanolamines. The loaded-liquid is regenerated at high temperatures with the aid steam. In the present study absorption rates are experimentally determined in various mixtures of amines over a wide range of concentrations. Simultaneously, a model was developed for the description of mass transfer accompanied by parallel reversible chemical reactions. The equations of this mass transfer model could not be solved analytically and therefore numerical techniques were used to obtain an exact description of this process. This model also includes the asymptotic situations of homogeneous catalysts and shuttle mechanism for which in the literature several approximate solutions have been presented. The ...

International Nuclear Information System (INIS)

Austenitic stainless steel AISI 304 has been nitrided by radio frequency (rf) plasma containing various nitrogen-hydrogen gas mixtures, in order to study the effect of hydrogen on structure and magnetic properties of the formed compound layer. The thermal temperature has been measured at the vicinity of the samples. The compound layer thus produced has been characterized using, X-ray diffractometer and vibration sample magnetometer. Providing the total pressure of nitrogen and hydrogen is held constant, the addition of hydrogen up to 50% gives new structural phases. The magnetization values of the plasma treated samples are strongly dependent on the percentage of H_2 in the gas phase. An excessive amount of hydrogen (#approx#75%) on the other hand, retards the nitriding process. The surface temperature of the sample and plasma condition is crucial factors for nitriding process.

International Nuclear Information System (INIS)

Carbon monoxide can be produced in severe accidents from interaction of ex-vessel molten core with concrete. Depending on the particular core-melt scenario, the type of concrete and geometric factors affecting the interaction, the quantities of carbon monoxide produced can vary widely, up to several volume percent in the containment. Carbon monoxide is a combustible gas. The carbon monoxide thus produced is in addition to the hydrogen produced by metal-water reactions and by radiolysis, and represents a possibly significant contribution to the combustible gas inventory in the containment. Assessment of possible accident loads to containment thus requires knowledge of the combustion properties of both CO and H_2 in the containment atmosphere. Extensive studies have been carried out and are still continuing in the nuclear industry to assess the threat of hydrogen in a severe reactor accident. However the contribution of carbon monoxide to the combustion threat has received less ...

Energy Technology Data Exchange (ETDEWEB)

In this work theoretical investigations are carried out for cooling systems, which are used in fuel cell vehicles. This work focuses mainly on the capability of increasing the heat rejection rate by using new alternative cooling systems and by improving the conventional cooling system. Fuel cell vehicles have a higher demand of heat rejection to the ambient than comparable vehicles with combustion engine. The performance of conventional liquid cooling systems, especially at high loads and high ambient temperatures, is often not sufficient anymore. Hence, cooling systems with improved performance are necessary for fuel cell vehicles. The investigations in this work are based on DaimlerChrysler's ''A-Class'' having a PEM-Fuel Cell system integrated. Specific computational models are developed for radiators and condensers to evaluate the performance of different cooling concepts. The models are validated with experimental data. Based on an ...

Energy Technology Data Exchange (ETDEWEB)

Natural Resources Canada commissioned an informal survey in which 18 organizations, mainly utilities from across Canada were contacted by letter or fax to gather data regarding unit energy consumption (UEC) of space heating, domestic hot water (DHW) heating and appliances. The data was used in updating and refining the residential energy end-use model used at NRCan. The survey included energy load, UEC, efficiency, and per cent saturation for both space heating and water heating equipment for all fuel types including electric, natural gas, oil, wood and propane used in single detached, single attached, apartment and mobile homes. A list of UEC and per cent saturation for major appliances such as refrigerators, freezers, clothes washers and dryers, cooktop/ovens, central air-conditioners, and lighting is also included in the survey. The collected data was presented separately for each organization. The UEC estimates for appliances range from 6255 to 8744 kWh/year. ...

Energy Technology Data Exchange (ETDEWEB)

The problem of buried steelwork in cargo hold insulation has been investigated by several using empirical methods. These efforts have resulted in correction factors that serve as a useful aid in the complex task of estimating the K-value of a ship`s cargo holds for the correct dimensioning of the refrigeration plant. Today, the advent of the digital computer has established numerical methods of analysis as a common working tool among practicing engineers. For estimating the flow in cases of buried steelwork that cannot be handled by correction factors, this is an effective approach. This study is an analytical/numerical investigation of the effect that buried steelworks have on the heat leakage across cargo hold walls. It aims at providing enlightenment on the physical significance of the parameters influencing the problem and developing practically simple methods for predicting the heat leakage across the hold walls. The study is set in the steady temperature in a ...

Energy Technology Data Exchange (ETDEWEB)

Heat transfer augmentation techniques (passive, active or a combination of passive and active methods) are commonly used in areas such as process industries, heating and cooling in evaporators, thermal power plants, air- conditioning equipment, refrigerators, radiators for space vehicles, automobiles, etc. Passive techniques, where inserts are used in the flow passage to augment the heat transfer rate, are advantageous compared with active techniques, because the insert manufacturing process is simple and these techniques can be easily employed in an existing heat exchanger. In design of compact heat exchangers, passive techniques of heat transfer augmentation can play an important role if a proper passive insert configuration can be selected according to the heat exchanger working condition (both flow and heat transfer conditions). In the past decade, several studies on the passive techniques of heat transfer augmentation have been reported. The present paper is a ...

International Nuclear Information System (INIS)

A prototype for a quasi-cw, and high-average power free electron laser (FEL) driven by a 15 MeV superconducting rf linac has been developed, and constructed at Tokai, JAERI since 1989. Cryogenic and accelerating fields' performances of four JAERI superconducting accelerator modules have been realized without any serious problem in the FEL accelerator vault and experimental hall. Since modification and related maintenance of the cryogenic refrigerator system for the driver were completed in the middle of October 1995, the system has run with no trouble, and the driver has been continuously run very successfully up to now. The optical resonator system and related electron beam transport system have been modified to realize larger acceptance than the old for both of the undulator radiation and energetic electron beam in 1995 Japanese fiscal year. In the modification, an alignment and distance measurement system has been newly developed, and successfully applied to ...

International Nuclear Information System (INIS)

In the present paper, experimental study of forced convection boiling were performed to investigate the post-CHF characteristics of a vertical annular channel with one heated rod and four spacer grids for new refrigerant R-134a. The experiments were conducted under outlet pressure of 11.6, 13, 16 and 20 bar, mass fluxes of 100-600 kg/m2s, and inlet temperatures of 25-51 .deg. C. The parametric trend of the post-CHF data was well consistent with previous studies. The two phase flow regime in tube flow occurring downstream of the CHF has been called post-CHF, dispersed flow, liquid-deficient flow, mist flow and film boiling. This regime is characterized by a continuous vapor phase with discrete liquid drops and a non-wetted heated surface. This regime has a considerable importance in the areas of light water reactor(LWR) accident analysis and other film boiling applications. The post-CHF region occurs by design in heat exchangers operating in the once-through mode ...

Energy Technology Data Exchange (ETDEWEB)

This report describes progress made during the extended final year (April 1, 1992 to December 31, 1993) and summarizes the accomplishments of the entire three-year period (April 1, 1990 through December 31, 1993) of the current US Department of Energy grant DE-FG06-87ER40345. This work is carried out primarily at the UNISOR (University Isotope Separator at Oak Ridge) facility of the Holifield Heavy-Ion Research Facility of the Oak Ridge National Laboratory. The primary mission of this work is the study of the structure and properties of nuclei far from stability through on-line nuclear orientation using the UNISOR Nuclear Orientation Facility, a helium dilution refrigerator coupled on-line to the UNISOR mass separator. The author`s group was one of the original proposers of this facility and played a central role in its design, construction, and development. The structure of nuclei far from stability is in general poorly known. Knowledge from heavy-ion reactions is ...

Energy Technology Data Exchange (ETDEWEB)

The paper reported the results of fiscal 1994 studies on solar energy in the New Sunshine Project. Relating to the technical development for the practical use of photovoltaic power systems, the development of manufacturing technologies for low-cost substrates and the development of element technology for manufacturing low-cost polycrystalline cells/modules were reported as the development of technology for thin substrate polycrystalline solar cells for practical use. As to the research on fabrication technology for thin film solar cells for practical use, reports were made on the research on low-cost fabrication technology for large-area modules and the technological development for qualitative improvement, etc. In respect to the technological development for super-high efficiency solar cells, reported were the technological development for super-high efficiency single crystalline silicon solar cells and the technological development for crystalline compound solar cells, etc. ...

Energy Technology Data Exchange (ETDEWEB)

Section 127 of the Energy Policy Act requires that the Department of Energy (DOE) prepare a report to Congress on the potential for the development and commercialization of appliances that substantially exceed the present federal or state efficiency standards. Candidate high-efficiency appliances must meet several criteria including: the potential exists for substantial improvement (beyond the minimum established in law) of the appliance`s energy efficiency; electric, water, or gas utilities are prepared to support and promote the commercialization of such appliances; manufacturers are unlikely to undertake development and commercialization of such appliances on their own, or development and production would be substantially accelerated by support to manufacturers. This report describes options to improve the efficiency of residential appliances, including water heaters, clothes washers and dryers, refrigerator/freezers, dishwashers, space heating and cooling ...

Energy Technology Data Exchange (ETDEWEB)

The microbiological safety, refrigeration shelf-life, and nutritional quality of chicken breast meat were investigated following combined electron-beam irradiation and cooking under vacuum (sous-vide). Chicken breast meat inoculated with 10{sup 6} CFU/g of Listeria monocytogenes was irradiated with an electron beam at doses up to 3.1 kGy under vacuum in barrier bags, cooked in a boiling water bath for 3 min 45 s (previously determined to achieve an internal temperature of 71.1{sup o}C), and stored at 8{sup o}C for up to 5 weeks. Listeria was undetectable in samples treated with combined sous-vide and irradiation at 3.1 kGy, but the organism survived the sous-vide treatment without irradiation and multiplied during storage. A similar study, conducted with uninoculated chicken breast meat, revealed that the product which received both irradiation (3 kGy) and sous-vide treatment had a shelf-life of at least 8 weeks at 8{sup o}C, whereas the unirradiated samples ...

Energy Technology Data Exchange (ETDEWEB)

This handbook provides the necessary tools for the engineer to design forced-cooled HPOF pipe-type cable systems. It represents the final objective of a major project which included an extensive research program at the Waltz Mill Forced-Cooling Test Facility. The formulas and procedures presented in this handbook are consistent with the results of this program as well as other full-scale and model investigations. Introductory material, including historical information, general design concepts and basic heat transfer and fluid dynamics theory is given for those who are unfamiliar with the fundamental principles of forced-cooling. The nucleus of the handbook consists of equations and calculating procedures for determining forced-cooled parameters and thermal/hydraulic performance levels. Both simple and sophisticated procedures have been provided, with the more complex procedures treating such areas as the thermal interaction between cable pipes as well as the transient aspects of ...

Science.gov (United States)

Cryogenic coolers are often used in modern spacecraft in conjunction with sensitive electronics and sensors of military, commercial and scientific instrumentation. The typical space requirements are: power efficiency, low vibration export, proven reliability, ability to survive launch vibration/shock and long-term exposure to space radiation. A long-standing paradigm of exclusively using "space heritage" equipment has become the standard practice for delivering high reliability components. Unfortunately, this conservative "space heritage" practice can result in using outdated, oversized, overweight and overpriced cryogenic coolers and is becoming increasingly unacceptable for space agencies now operating within tough monetary and time constraints. The recent trend in developing mini and micro satellites for relatively inexpensive missions has prompted attempts to adapt leading-edge tactical cryogenic coolers for suitability in the space environment. The primary emphasis has been on ...

Energy Technology Data Exchange (ETDEWEB)

This patent describes a preflush fluid for preventing lost circulation during the cementing of a well, the fluid consisting essentially of: (a) water; (b) about 10 to about 30 percent by weight of water (% BWOW) cement; (c) about 5 to about 30% BWOW calcium sulfate selected from the group consisting of calcium sulfate hemihydrate, calcium sulfate dihydrate, and mixtures thereof; and (d) an alkali metal-containing quick-hardening accelerator.

Energy Technology Data Exchange (ETDEWEB)

Equations are derived to permit calculation of the work required for the isentropic compression of a two phase fuel-air mixture. Methanol evaporation during compression is shown to substantially reduce compression work and thereby improve cycle efficiency and maximum power. Effects of evaporative cooling in the intake manifold are calculated. 14 refs.

Energy Technology Data Exchange (ETDEWEB)

In order to predict thermal hazards of high-energy materials, accurate kinetics constants must be determined. Predictions of thermal hazards for mixtures of high-energy materials require measurements on the mixtures, because interactions among components are common. A differential-scanning calorimeter (DSC) can be used to observe rate processes directly, and isothermal methods enable detection of mechanism changes. Rate-controlling processes will change as components of a mixture are depleted, and the correct depletion function must be identified for each specific stage of a complex process. A method for kinetics measurements on mixed explosives can be demonstrated with Composition B is an approximately 60/40 mixture of RDX and TNT, and is an important military explosive. Kinetics results indicate that the mator process is the decomposition of RDX in solution in TNT with a perturbation caused by ...

Energy Technology Data Exchange (ETDEWEB)

The resistance to microbe damages of aqueous solutions of cutting fluids (SOZh), which contain dual and more complex mixtures of known compounds, is studied. Lauric acid, myristic and tridecanic acid give microbic resistance to the compositions of synthetic cutting fluids. A complexing of the compositions as a rule does not support precisely expressed effects of synergism or antagonism.

Energy Technology Data Exchange (ETDEWEB)

The multi-spray direct injection diesel engine has the best efficiency of all combustion systems. The optimization of the air-fuel mixture parameters, especially of the fuel injection, enables the forming of the combustion process in a way, that all requirements and legislative regulations concerning power output, noise and exhaust emissions can be fulfilled. Electronic controlled unit injector systems, as developed by Voest-Alpine Automotive GmbH, Linz, offer the necessary potential to meet the complex requirements.

Energy Technology Data Exchange (ETDEWEB)

Short communication

International Nuclear Information System (INIS)

In-situ compaction method is an alternative technology for the construction of a buffer at HLW final disposal. Understanding of the compaction characteristics of the proposed material is important for this method of construction. In this report, paying attention to the relation between compaction energy and the achieved maximum dry density, dynamic compaction characteristic of bentonite and silica sand mixture material is examined. (author)

International Nuclear Information System (INIS)

A description is given of sinterable powders and methods of producing sintered products using such powders. The powders consist of (a) a particulate ceramic material, e.g. SiC, having specified particle size and surface area; (b) a carbon source material, e.g. sugar or a phenol-formaldehyde resin; and (c) a residue from a solution of H3BO3, B2O3, or mixtures of these as sintering aid. (U.K.).

Energy Technology Data Exchange (ETDEWEB)

Using the example of perhydrophenanthrene, perhydroanthracene and cyclopentanodecalin isomers a possibility is shown to use packed capillary columns containing graphitized thermal carbon black for a complete separation of high-boiling mixtures of polycyclic saturated hydrocarbon isomers in accordance with the geometric structure of their molecules.

Energy Technology Data Exchange (ETDEWEB)

A process is claimed for stabilizing fuels during storage by blending therewith oxalic acid derivatives of mono- or bis-succinimides of polyalkylpolyamines. The fuels are stabilized by the presence of 10 to 100 parts per thousand barrels of these oxamides. For particular applications mixtures of monoand bis-succinimides in varying proportions can be used.

Energy Technology Data Exchange (ETDEWEB)

A cathode of improved discharge characteristics for a zinc-air battery is prepared from mixtures containing gamma-MnO/sub 2/ 33-67 wt%, C 12-40 wt% and KOH 20-28 wt%.

International Nuclear Information System (INIS)