Science.gov (United States)

... Title : Effect of Yttrium on the Microstructure of Titanium Alloys,. ... The yttrium was added in the melting stage as an oxide or in the elemental form. ...

Science.gov (United States)

Pore Fraction in Yttrium-Barium-Copper-Oxide and. Other Polycrystalline. Materials ...... Properties of Yttrium Ceramic. Sov. J. LowTemp.Phys. 14:395-402 . ...

Science.gov (United States)

Results showed that a simple yttrium coating offered more potential for ... was from 70 to 150 K (125' to 200' F) above that for the yttrium coating. ...

Science.gov (United States)

... Accession Number : ADD257320. Title : Sputter Deposition of Yttrium-Oxides. Descriptive Note : Journal article,. Corporate ...

International Nuclear Information System (INIS)

The effect of the rare earth element, yttrium, on the mechanical properties of 9Cr-2WVTa low active martensite steel for fusion reactor was studied and the metallurgical behavior of yttrium in the steel was primarily analyzed. The results show that it is easy for yttrium to aggregate and form the blocky yttrium rich inclusions in the steel, which can dissever the continuity of the matrix and produce micro-cracks for fracture. The yttrium rich inclusions were distributed along the rolling direction, which made the fracture surface delaminated in the tensile and impact samples, and reduced the mechanical properties of the steel. (authors)

Science.gov (United States)

... Accession Number : ADA137272. Title : Effects of Yttrium Microalloying on the Epitaxial Grain Growth in Ti-6Al-4V Weld Fusion Zones. ...

Medline Plus

... There has been a role for placement of yttrium or radioactive phosphorous in a tumor called craniopharyngioma, ...

Energy Technology Data Exchange (ETDEWEB)

We report a templated-synthetic approach based on apoferritin to prepare radionuclide nanoparticle (NP) conjugates. Non-radioactive yttrium (89Y) was used as model target and surrogate for radioyttrium (90Y) to prepare the nanoparticle conjugate. The center cavity and multiple channel structure of apoferritin offer a fast and facile method to precipitate yttrium phosphate by diffusing yttrium and phosphate ions into the cavity of apofrritin, resulting a core-shell nanocomposite. The yttrium phosphate/apoferritin nanoparticle was functionalized with biotin for further application. The synthesized nanoparticle was characterized by transmission electron microscopy (TEM) and x-ray photoelectron spectroscopy (XPS). We found that the resulting nanoparticles were uniform in size, with a diameter of around 8 nm. We tested the pre-targeting capability of the biotin-modified yttrium ...

International Nuclear Information System (INIS)

The usage of biosorbents allows separation of scandium and yttrium from each other and from Fe, Al, Ti, Si, and Ca in hydrometallurgical processing of ores and wastes. It was shown that sorption of scandium and yttrium increased with the increase of pH of solution. Initial rate of scandium sorption depended on the biomass type; however 85-98% of scandium was sorbed within 10-30 min with most biomass types tested. The presence of aluminium, iron (III), and titanium in the solution inhibited sorption of scandium and particularly yttrium. After four cycles of sorption, 98.8% of scandium and 87% of yttrium was extracted from red mud leach solution by the biomass of Saccharomyces cerevisiae and Aspergillus terreus, respectively. Selectively of the process of scandium and yttrium recovery could be achieved during sorption and also desorption, when solubilization of sorbed associated ...

Science.gov (United States)

Manganese, Iodine and Sulfide Concentrations and Peroxide to Oxygen Ratio Measured during the U.S. JGOFS Arabian Sea Process Study ...

Science.gov (United States)

... ADD137758. Title : The Oxidation Behavior of CoCrAlY, CoCrAl and Yttrium-Implanted CoCrAl Alloys Compared and Contrasted,. ...

International Nuclear Information System (INIS)

Carrier-free "8"8Y radioisotope, which has the longest half life (T=106.6 d) of yttrium radioisotopes and is a #gamma#-ray emitter, was obtained by proton irradiation of strontium, followed by cooling for one month. Then, "8"8Y was purified by precipitating strontium as strontium nitrate and extracting yttrium with tri-n-butyl phosphate (TBP). The decontamination factor of strontium to yttrium was more than 4x10"3 and chemically pure yttrium radioisotope was obtained. (author) 6 refs.

Energy Technology Data Exchange (ETDEWEB)

This paper advances hypotheses on the chemistry of the interaction of thorium and yttrium with organic-inorganic salts of molybdenum polyacids. On the basis of an analysis of the data of an adsorption experiment and the quantitative relationships that follow from the law of mass action, it is shown that thorium is absorbed by the solid phase by coprecipitation with the participation of complex formation, while the coprecipitation of yttrium with salts of polyacids is due to a reaction of ion exchange chemisorption.

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This patent describes a method of reducing the hydrogen sulfide level in streams containing hydrogen sulfide at concentrations from about 2 ppm up to about 1,000 ppm. It comprises reacting the hydrogen sulfide with an unsaturated hydrocarbon in the presence of an acidic solid catalyst selected from the group consisting of polymeric sulfonic acid resins, solid polyphosphoric acid, supported sulfuric acid, supported boric acid, silica-aluminas, clays, faujasite, mordenite, and L, omega, X or Y zeolites at mercaptan-forming concentrations, and recovering a stream having a reduced hydrogen sulfide concentration and containing no more than 5 ppm hydrogen sulfide.

UK PubMed Central (United Kingdom)

The effects of ammonia and hydrogen sulfide on the physical and biochemical properties of the claw horn of Holstein cows were evaluated. Significant (P < 0.05, 0.01) decreases...Full Text Available

KoreaScience (Korea)

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Science.gov (United States)

We report significant enhancement in superconducting properties of yttrium substituted Ce1-xYxOFFeAs superconductors. The polycrystalline samples were prepared by two step solid state reaction technique. X-ray diffraction confirmed tetragonal ZrCuSiAs structure with decrease in both a and c lattice parameters on increasing yttrium substitution (with fixed F content). With smaller ion Y in place of Ce, the transition temperature increased by 6 K. Yttrium doping also lead to higher critical fields as well as broader magnetization loops, particularly at elevated temperature.

British Library Electronic Table of Contents (United Kingdom)

Sulfur pollution can lead to serious problems in freshwater wetlands, including phosphorus eutrophication and sulfide toxicity. We tested the effects of anaerobic iron-rich groundwater discharge in fens, simulated by iron injection, on two characteristic species (Juncus effusus and Caltha palustris) in a sulfidic environment. Biomass production of C. palustris roots showed an optimum response to the combined addition of iron and sulfide, with highest values at intermediate concentrations of both substances. Iron deficiency apparently occurred at low iron concentrations, while at high iron concentrations, growth was decreased. For J. effusus, in contrast, no toxic effects were found of both iron and sulfide. This could be explained by larger radial oxygen loss (ROL) of J. effusus and could ...

Energy Technology Data Exchange (ETDEWEB)

It is well known that the solubilization of coal can be accelerated by adding sulfur or hydrogen sulfide during direct liquefaction of difficult coals. From the studies of authors on the coal liquefaction under the conditions at rather low temperatures between 300 and 400{degree}C, liquefaction products with high quality can be obtained by suppressing the aromatization of naphthene rings, but it was a problem that the reaction rate is slow. For improving this point, results obtained by changing solvents have been reported. In this study, to accelerate the liquefaction reaction, Illinois No.6 coal was liquefied in tetralin at temperature range from 300 to 400{degree}C by adding a given amount of sulfur or hydrogen sulfide at the initial stage of liquefaction. The addition of sulfur or hydrogen sulfide provided an acceleration effect of liquefaction reaction at temperature range between 300 and 400{degree}C. The addition of ...

Energy Technology Data Exchange (ETDEWEB)

A sensitive and rapid automated method has been developed for the selective analysis of acid extractable sulfide in environmental samples by combining gas dialysis separation techniques with methylene blue detection procedures. Acid extractable sulfide is separated from the sample matrix by the gas dialysis membrane and subsequently trapped in a dilute sodium hydroxide receiving stream. This stream is reacted with N,N-dimethyl-p-phenylenediamine and ferric chloride to produce methylene blue which is then quantitated colorimetrically at 660 nm. For standards and nonturbid environmental samples, there is good agreement between the results obtained by this procedure and the standard methylene blue method. The effect of interferences on the accurate determination of sulfide by both methods was also examined and it was found that cupric ions significantly interfered with sulfide estimation. To obtain ...

Energy Technology Data Exchange (ETDEWEB)

Improvements in critical current capacity for superconducting film structures are disclosed and include the use of a superconducting RE-BCO layer including a mixture of rare earth metals, e.g., yttrium and europium, where the ratio of yttrium to europium in the RE-BCO layer ranges from about 3 to 1 to from about 1.5 to 1.

Energy Technology Data Exchange (ETDEWEB)

Carbonyl sulfide (COS), a colorless gas, is a side product of industrial procedures sure as coal hydrogenation and gasification. It is structurally related to and is a metabolite of carbon disulfide. COS is metabolized in the body by carbonic anhydrase to hydrogen sulfide (H{sub 2}S), which is thought to be responsible for COS toxicity. No threshold limit value for COS has been established. Results of these studies indicate COS (with an LC{sub 50} of 590 ppm) is slightly less acutely toxic than H{sub 2}S (LC{sub 50} of 440 ppm).

International Nuclear Information System (INIS)

Low-porosity #alpha#- and #beta#-SiAlON composite material was prepared when the powder mixture intended for preparation of yttrium #alpha#-SiAlON, with the formula Y_0_._4Si_1_2_-_m_+_nAl_m_+_nO_nN_1_6_- _n, was attritor milled in isopropyl alcohol or contained excess oxygen (n > 0.6). The region of stability of single-phase yttrium #alpha#-SiAlON was smaller at lower temperatures. Wet milling (in isopropyl alcohol) of AlN powder was found to introduce excess oxygen into the milled powder.

Science.gov (United States)

Magmatic sulfide deposits are the most significant source of platinum-group elements (PGE) in the world. Key to understanding their genesis is determining the processes and timing of sulfide saturation, metal enrichment and crustal contamination. In this study, we have identified droplets of magmatic sulfide from the Platreef, South Africa, where droplets of sulfide have been trapped in the earliest crystallising phase, chromite. Due to their early entrapment at high temperatures, metal concentrations and ratios that they display are indicative of a very early-stage sulfide liquid in the system, as they will have cooled and fractionated within an essentially closed system, unlike interstitial blebs that crystallise in an open system as the magma cools. Analysis of these droplets in an opaque mineral like chromite by LA-ICP-MS is problematic as some of the fractionated inclusion is ...

British Library Electronic Table of Contents (United Kingdom)

In the present study the optical properties of co-evaporated indium sulfide thin films are investigated. Before being optically characterized, the composition as well as the crystalline properties of the film have been checked with the help of energy dispersive spectroscopy (EDX) and X-Ray diffraction (XRD) analyses. The optical absorption coefficient ? of this indium sulfide film has been deduced from reflectivity R(?) and transmission T(?) measurements. The fit of the curve representing ?(h?) suggests that the ?-In2S3 has an indirect bandgap of 2.01?eV. Density functional theory (DFT) calculations are performed on this indium sulfide compound, using TB-LMTO code. Through these band structure investigations, an indirect bandgap is predicted as observed experimentally. The top of the valen...

International Nuclear Information System (INIS)

This study presents a rapid and selective method for the recovery of lanthanides and yttrium, existing in economically interesting concentrations, from red mud, the byproduct of the alumina production. The leaching process is based on the extraction of these elements with diluted nitric acid from red mud under moderate conditions and without using any preliminary treatment. Several parameters such as leaching agents, contact time, temperature, pressure and solid to liquid ratio were investigated in order to achieve an optimum recovery. The process followed here was selected taking into account its efficiency for the selective recovery of yttrium and lanthanides, but also its suitability for the subsequent liquid-liquid extraction of the leaching solution for the separation of the individual lanthanides. The achieved recovery percentages were for Y about 90%, for the investigated heavy lanthanides (Dy, Er, Yb) up to 70%, for the middle ones (Nd, ...

Science.gov (United States)

Significant progress has been achieved recently in the growth of Yttrium Calcium Oxyborate (YCOB) crystals. Boules have been grown capable of producing large aperture nonlinear crystal plates suitable for high average power frequency conversion or optical parametric chirped pulse amplification (OPCPA). With a large aperture (5.5 cm x 8.5 cm) YCOB crystal we have demonstrated a record 227 W of 523.5nm light (22.7 J/pulse, 10 Hz, 14 ns). We have also demonstrated the applicability of YCOB for 1053 nm OPCPA.

International Nuclear Information System (INIS)

Magnetic materials such as yttrium iron garnet (YIG) are of great importance for its magneto-optic properties and for their potential applications in the domain of optical telecommunications. The deposition of thin films of YIG, on quartz or GGG (gadolinium gallium garnet) substrate, was performed using radio frequency non reactive magnetron sputtering, followed by high temperature annealing which is needed to enhance the crystallinity of the layers. Rutherford backscattering spectrometry RBS was used to determine the thickness and stoichiometry of the performed layers in order to investigate correlations between growth conditions and the quality of the final material. RBS measurements showed the influence of the deposition time and the temperature substrate on the film growth and its stoichiometry. (author)

International Nuclear Information System (INIS)

The paramagnetic susceptibility of single crystals of dysprosium-yttirum alloys is measured in the basal plane and along the hexagonal axis. It is shown that the susceptibility of the alloys obeys the Curie-Weiss law, the effective magnetic moments allong the different directions being the same and the paramagnetic Curie temperatures being different. The difference between the paramagnetic Curie temperatures in the basal plane and along the hexagonal axis is independent of the dysprosium concentration in the alloy. As a comparison with the theoretical models of magnetic anisotropy shows, this is an indication that the magnetic anisotropy of dysprosium - yttrium alloys is of a single-ion nature.

Energy Technology Data Exchange (ETDEWEB)

This program is concerned with the development of an advanced method for the separation of hydrogen sulfides from coal gas. The process utilizes an electrochemical membrane which removes hydrogen sulfide without cooling the gas and with negligible pressure loss through the separator.

British Library Electronic Table of Contents (United Kingdom)

Indium sulfide thin films consisting of porous network of nanoplatelets, have been deposited using chemical bath deposition (CBD) method onto the tin-doped indium oxide (ITO) coated glass substrate. Aqueous solutions of indium sulfate and thioacetamide have been used as indium and sulfur precursors. As a complexing agent, acetic acid was used. The chemically deposited indium sulfide thin films were examined for their structural, surface morphological and optical characterizations. The X-ray diffraction analysis revealed the formation of the cubic b-In2S3 onto the substrate. From scanning electron micrograph, it is observed that the surface of substrate is covered by nanoporous platelets type morphology. The optical studies showed a direct band gap of 2.84eV for indium sulfide platelets. Ph...

British Library Electronic Table of Contents (United Kingdom)

The transformation of ferrihydrite to siderite (FeCO3) in the presence of supercritical CO2 (scCO2) and aqueous sulfide has been investigated by in situ attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) and ex situ X-ray diffraction (XRD). The chemical transformation of iron-bearing minerals to form iron carbonates may play a role in the chemistry related to the geological sequestration of carbon dioxide in the Earth's (sub)surface. The iron oxyhydroxide ferrihydrite in an aqueous solution containing sodium sulfide in contact with scCO2 at 100^oC reacts within 24h to form siderite and elemental sulfur. In situ studies of this reaction with ATR-FTIR show that ferrihydrite exists with an adsorbed layer of carbonate. However, the presence of the carbonate adsorbat...

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The effect of method of sulfur addition on the hydrocracking activity of coal liquefaction catalysts was investigated using a high-pressure differential thermal analyser. The three methods of sulfur addition were: 1) physical mixing of 10 wt% elemental sulfur with red mud; 2) pre-sulfidation of red mud with hydrogen sulfide; 3) use of reagent grade pyrite. The pre-sulfided catalyst was slightly less active than the catalyst prepared by physical mixing, and both of these were changed to pyrrhotite in the course of use. Although the pyrite catalyst exhibited activity at markedly lower temperatures than those required for the other two catalysts, conversions were lower than had been expected. This is thought to be due to a different catalytic mechanism being involved. 13 references.

Science.gov (United States)

Thin film solar cells and solar cell testing - photovoltaic cells, radiation damage to cadmium sulfide solar cells, and airplane testing of solar cells

Energy Technology Data Exchange (ETDEWEB)

Correlations between structural aspects of solid materials and their behavior as catalysts are relatively recent. This 20-chapter book focuses on understanding of solid-state mechanisms in heterogeneous catalysis and relationship between catalytic behavior and solid state structure, emphasizing catalysis with oxides, sulfides, and zeolites.

Energy Technology Data Exchange (ETDEWEB)

A process for the recovery of nitrilotriacetic acid values from solutions containing polyvalent metal complexes of nitrilotriacetic and the decomposition products thereof is described, the process being characterized by the addition to such solutions of sufficient strong acid to dissociate the complex under conditions to precipitate the nitrilotriacetic acid.

UK PubMed Central (United Kingdom)

Marine sediments are frequently covered by mats of the filamentous Beggiatoa and other large nitrate-storing bacteria that oxidize hydrogen sulfide using either oxygen or nitrate, which...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Concentration of an amine solution for removal of hydrogen sulfides and carbon dioxide from natural gas, is tested by carbon dioxide absorption measurement in an apparatus allowing complete reaction to give reliable results.

British Library Electronic Table of Contents (United Kingdom)

Cadmium sulfide particles have been synthesized in the aqueous medium using the amino acid histidine as a stabilizing agent. These particles demonstrate the phenomenon of size quantization effect. The fluorescence of histidine-stabilized CdS was found to be enhanced and quenched by the addition of DNA bases adenine and guanine, respectively. The fluorescence enhancement of CdS in the presence of adenine has been explained on the basis of interaction between the quantum dot stabilizer and the amino group of adenine. Quenching of CdS fluorescence by guanine occurs due to interaction of the substrate with the quantum dot surface.

Energy Technology Data Exchange (ETDEWEB)

Self-consistent electronic structure calculations have been performed on two compositions of scandium sulfide ScS and Sc/sub 3/S/sub 4/. The results of the calculation of ScS are similar to those obtained for other transition metal chalcogenides and are in excellent agreement with heat capacity and reflectance measurements as well as UPS experiments. The calculation of the defect structure indicates the creation of sulfur p nonbonding states in metal-deficient ScS. The valency of the metal ions remains unchanged upon the creation of vacancies.

International Nuclear Information System (INIS)

This paper presents results of studying the thermo-transferred thermoluminescence (TTTl) phenomenon in potassium-yttrium double fluoride doped with terbium (K_2YF_5_:Tb) at different impurity concentrations (0.8%, 0.95% and 0.99%). Previously to study the TTTl phenomenon, structural characterization and chemical composition of the materials were determined. The structural studies were conducted using a scanning electron microscope; meanwhile, chemical composition was analyzed using energy dispersive X-ray spectroscopy. Thermoluminescence kinetics was studied irradiating the samples with "1"3"7Cs gamma rays as well as with "9"0Sr/"9"0Y beta rays, analyzing the glow curves by the deconvolution method for obtaining the kinetic parameters. (Author)

British Library Electronic Table of Contents (United Kingdom)

Regularities of deformation-induced dissolution of a surface layer of iron oxides in matrixes of iron-based alloys with bcc and fcc lattices have been studied by the methods of M?ssbauer spectroscopy, transmission electron microscopy, and X-ray diffraction. A method of producing iron alloys strengthened by dispersed oxide nanoparticles and alloyed with elements possessing a high affinity to oxygen (titanium and yttrium) has been proposed, which implies a dynamic dissolution of a surface layer of iron oxides upon strong cold deformation and a precipitation of secondary yttrium and titanium nanooxides upon a subsequent high-temperature sintering of mechanically alloyed powders. There has been demonstrated a possibility of oxide strengthening of pure iron upon its interaction with air without...

Energy Technology Data Exchange (ETDEWEB)

It is demonstrated that highly dispersed molybdenum sulfide catalysts are prepared by using Mo(CO){sub 6} adsorbed on the support. The structure of ultradispersed molybdenum sulfide is suggested by EXAFS techniques to be different from that of MoS{sub 2}. The TOF of the thiophene HDS is almost invariant with the dispersion of molybdenum sulfide at a high molybdenum dispersion, whereas the TOF of the hydrogenation greatly increases with increasing dispersion. On the basis of the HDS activity and optimum Co/Mo ratio of Co-Mo/Al{sub 2}O{sub 3} catalysts having a variety of molybdenum dispersion fabricated by using carbonyl complexes, it is demonstrated that highly active HDS catalysts are prepared by highly dispersing molybdenum sulfide phases. Edge decorations of molybdenum sulfides by cobalt are suggested for the synergy generation between cobalt and molybdenum ...

International Nuclear Information System (INIS)

Y2Te4O11:Eu3+ and Y2Te5O13:Eu3+ single crystals in sub-millimeter scale were synthesized from the binary oxides (Y2O3, Eu2O3 and TeO2) using CsCl as fluxing agent. Crystallographic structures of the undoped yttrium oxotellurates(IV) Y2Te4O11 and Y2Te5O13 have been determined and refined from single-crystal X-ray diffraction data. In Y2Te4O11, a layered structure is present where the reticulated sheets consisting of edge-sharing [YO8]13- polyhedra are interconnected by the oxotellurate(IV) units, whereas in Y2Te5O13 only double chains of condensed yttrium-oxygen polyhedra with coordination numbers of 7 and 8 are left, now linked in two crystallographic directions by the oxotellurate(IV) entities. The Eu3+ luminescence spectra and the decay time from different energy levels of the doped compounds were investigated and all detected emission levels were identified. Luminescence properties of the Eu3+ cations have been interpreted in consideration ...

International Nuclear Information System (INIS)

To determine a suitable combination of X-ray filter and tube kilovoltage for Fuji Computed Radiography (FCR), provide better detection of pulmonary nodules, and reduce patient exposure, we compared observer performance with different X-ray filters and tube voltages. Radiographs were obtained with a copper filter backed by aluminium, with a tungsten filter backed by yttrium and aluminium, and with a lead filter backed by yttrium and aluminium, at both 100 kVp and 135 kVp. Observer performance in detecting simulated lung nodules, which were placed on the posterior aspect of a chest phantom, was compared using receiver operating characteristic (ROC) techniques for each combination of the X-ray filter and tube voltage. The results of the study indicated that 1) nodule detection was superior for the images obtained with 135 kVq as compared with 100 kVp; 2) approximately equal detection rates were obtained for the three X-ray filter sets, although ...

Energy Technology Data Exchange (ETDEWEB)

Metals for potential use in the dissociator and the synthesizer reactors of a distributed solar receiver thermochemical transport loop utilizing SO/sub 3//SO/sub 2//O/sub 2/ molecular chemistry includes stainless steels and iron-base, nickel-base and cobalt-base superalloys. We tested these alloys in SO/sub 2//O/sub 2/ mixtures and SO/sub 3/ gas at 500/sup 0/C and 900/sup 0/C, respectively, for times of up to four weeks. Weight gain measurements were used to determine the oxidation/sulfidation kinetics and electron microprobe analysis was used to measure penetration of oxygen and sulfur into the metal and to identify the formation of internal oxides and sulfides. Results of these tests showed that the most promising candidates are those containing sufficient quantities of both aluminum and chromium alloying additions to be alumina and chromia formers, such as Kanthal A-1, Nimonic 105 and Cabot 214.

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The coke plant at the Sparrows Point Plant consist of three coke oven batteries and two coal chemical plants. The by-product coke oven gas (COG) consists primarily of hydrogen, methane, carbon monoxide, nitrogen and contaminants consisting of tars, light oils (benzene, toluene, and xylene) hydrogen sulfide, ammonia, water vapor and other hydrocarbons. This raw coke oven gas needs to be cleaned of most of its contaminants before it can be used as a fuel at other operations at the Sparrows Point Plant. In response to environmental concerns, BSC decided to replace much of the existing coke oven gas treatment facilities in the two coal chemical Plants (A and B) with a group of technologies consisting of: Secondary Cooling of the Coke oven Gas; Hydrogen Sulfide Removal; Ammonia Removal; Deacification of Acid Gases Removed; Ammonia Distillation and Destruction; and, Sulfur Recovery. This combination of technologies will replace the existing ammonia ...

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Production of hydrogen sulfide in produced waters due to the activity of sulfate-reducing bacteria (SRB) is a potentially serious problem. The hydrogen sulfide is not only a safety and environmental concern, it also contributes to corrosion, solids formation, a reduction in produced oil and gas values, and limitations on water discharge. Waters produced from seawater-flooded reservoirs typically contain all of the nutrients required to support SRB metabolism. Surface processing facilities provide a favorable environment in which SRB flourish, converting water-borne nutrients into biomass and H{sub 2}S. This paper will present results from a field trial in which a new technology for the biochemical control of SRB metabolism was successfully applied. A slip stream of water downstream of separators on a produced water handling facility was routed through a bioreactor in a side-steam device where microbial growth was allowed to develop fully. This ...

British Library Electronic Table of Contents (United Kingdom)

This paper presents studies carried out on tin-doped indium sulfide films prepared using Chemical Spray Pyrolysis (CSP) technique. Effect of both in-situ and ex-situ doping were analyzed. Ex-situ doping was done by thermal diffusion, which was realized by annealing Sn/In2S3 bilayer films. In-situ doping was accomplished by introducing Sn into the spray solution by using SnCl45H2O. Interestingly, it was noted that by ex-situ doping, conductivity of the sample enhanced considerably without affecting any of the physical properties such as crystallinity or band gap. Analysis also showed that higher percentage of doping resulted in samples with low crystallinity and negative photosensitivity. In-situ doping resulted in amorphous films. In contrast to ex-situ doping, `in- situ doping' resulted i...

British Library Electronic Table of Contents (United Kingdom)

Sulfur mustard (HD) is an alkylating and cytotoxic chemical warfare agent, which inflicts severe skin toxicity and an inflammatory response. Effective medical countermeasures against HD-caused skin toxicity are lacking due to limited knowledge of related mechanisms, which is mainly attributed to the requirement of more applicable and efficient animal skin toxicity models. Using a less toxic analog of HD, chloroethyl ethyl sulfide (CEES), we identified quantifiable inflammatory biomarkers of CEES-induced skin injury in dose- (0.05-2 mg) and time- (3-168 h) response experiments, and developed a CEES-induced skin toxicity SKH-1 hairless mouse model. Topical CEES treatment at high doses caused a significant dose-dependent increase in skin bi-fold thickness indicating edema. Histopathological e...

Energy Technology Data Exchange (ETDEWEB)

Alkanol-amine is used for removing hydrogen sulfide and carbon dioxide from the gas stream. Contaminated amine is the amine which is contaminated by hydrocarbon, organic acid or iron sulfide, etc.. In addition, in the case when an antifoaming agent is excessively added to it or when it is decomposed chemically or thermally, it is considered that it is contaminated. When an amine solution becomes contaminated, several problems concerning operation control occur which would influence the effect of the amine treatment in consequence. By using activated charcoal, it is possible to decrease the additional amount of the antifoaming agent or corrosion inhibitor. This is because activated charcoal removes the decomposed product which causes the foaming phenomenon. In order to derive economical profit sufficiently, an activated charcoal system properly designed is necessary. In this article, the CALGON CLEANAMINE SYSTEM of Calgon Co. is introduced which ...

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YIG precursor powder was obtained by homogeneous precipitation in chloride salt solution by thermal decomposition of urea. It was found that ferric ions precipitated prior to yttrium ions. The precipitate was minute and spherical in shape. The precipitate formed consisted of the mixture of amorphous and ferric oxyhydroxide. Crystallization of YIG was proceeded by solid state reaction of intermediate YFeO{sub 3} and Fe{sub 2}O{sub 3} in the temperature range of 850 deg. C to 1400 deg. C. Single phase of YIG was obtained by heat-treatment of the powder at 1400 deg. C for 6 hrs in air. The powder calcined was molded into pellets and sintered in air. The maximum density of 4.92 g/cm{sup 3} (95.1% of theoretical density) was obtainable for the pellet sintered at 1450 deg. C using the powder calcined at 900 deg. C. (author) 20 refs., 8 figs., 1 tab.

Energy Technology Data Exchange (ETDEWEB)

There are two non-equivalent sites of yttrium in the lattice of Y{sub 2}SiO{sub 5}. Both of them may be occupied substitutionally by Er{sup 3+}, resulting in a laser active material. We measured absorption spectra of Y{sub 2}SiO{sub 5}:Er{sup 3+} at several low temperatures and we studied its emission spectrum at 4.2 K following selective excitation of individual Stark components of the {sup 4}I{sub 13}2/ to {sup 4}I{sub 15}2/ transition by the light of a tunable colour centre laser. The results of these two experiments allow classification of the absorption and emission lines into two independent systems, thus yielding two energy level schemes 1 and 2. Moreover, simple crystal field calculations strongly suggest from which Y{sub 2}SiO{sub 5} crystallographic site spectrum 1 arises, and from which one spectrum 2. (author)

International Nuclear Information System (INIS)

Determination of principal and impurity components in monocrystals of erbium and yttrium formates grown on the basis of high-pure formates from oriental primers, using the method of isothermal evaporation of the salt aqueous solutions with pH 4.4 - 4.5, is described. Er and Y were determined complexonometrically by the titration of the complex with arsenazo 1 by EDTA solution, and formate-ion was determined iodometrically. Impurities were analyzed by atomic-absorption and titrimetric methods. The atomic-absorption method permits to determine in the monocrystal from 1 x 10"-"4 to 5 x 10"-"3 % Mg at relative standard deviation S_r = 0.05; from 1 x 10"-"3 to 2.5 x 10"-"2 % Ca at S_r = 0.07 and from 2 x 0"-"4 to 5 x 10"-"3 % Pb ar S_r = 0.08.

Energy Technology Data Exchange (ETDEWEB)

The authors present the emitter efficiency results for the thin film 25 percent Ho YAG (Yttrium Aluminum Garnet, Y3Al5O12) selective emitter from 1000 to 1700 K with a platinum substrate. Spectral emittance and emissive power measurements were made (1.2 less than lambda less than 3.2 microns) and used to calculate the radiative efficiency. The radiative efficiency and power density of rare earth doped selective emitters are strongly dependent on temperature and experimental results indicate an optimum temperature (1650 K for Ho YAG) for thermophotovoltaic (TPV) applications.

International Nuclear Information System (INIS)

The prospect for the recovery of rare earths from red mud, the bauxite tailings from the production of alumina is examined. The Jamaican red mud by far has the higher trace concentrations of lanthanum, cerium, neodymium, and yttrium. Scandium is also present. The dissolution of the rare earth is a major extraction problem because of the large volume of other materials. The recovery processes that have been proposed include the production of co-products such as iron, alumina, and titanium concentrates, with the rare earths going with the titanium. In this paper a critical examination of the possible processes are presented with the recommended research projects to be carried out.

Energy Technology Data Exchange (ETDEWEB)

Thin films of high temperature garnet materials such as yttrium aluminum garnet (YAG) doped with rare earths are currently being investigated as selective emitters. This paper presents a radiative transfer analysis of the thin film emitter. From this analysis the emitter efficiency and power density are calculated. Results based on measured extinction coefficients for erbium-YAG and holmium-YAG are presented. These results indicated that emitter efficiencies of 50 percent and power densities of several watts/sq cm are attainable at moderate temperatures (less than 1750 K).

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A temperature gradient across a thick ({ge}.1mm) film selective emitter will produce a significant reduction in the spectral emittance from the no temperature gradient case. Thick film selective emitters of rare earth doped host materials such as yttrium-aluminum-garnet (YAG) are examples where temperature gradient effects are important. In this paper a model is developed for the spectral emittance assuming a linear temperature gradient across the film. Results of the model indicate that temperature gradients will result in reductions the order of 20{percent} or more in the spectral emittance. {copyright} {ital 1997 American Institute of Physics.}

International Nuclear Information System (INIS)

In one of the first uses of high Tc superconductors in an end-use product, Lake Shore Cryotronics and a Swiss lab have developed a liquid nitrogen level sensor using a high Tc thin film. The probe is manufactured using a seamless stainless steel tube with an yttrium-based zirconium oxide flame-sprayed on the tube. A plasma-sprayed superconductor compound is deposited on top of that. The probe is coated with a sealant that protects the superconducting film from the atmosphere. This manufacturing method has yielded an extremely durable product. Unaffected by ice formation and related mechanical problems, the superconducting level sensor can be kept in the dewar for long periods of time.

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This report summarizes the objectives, background, technical progress, and status of ANL electric vehicle battery R&D tasks for DOE-EHP during the period of January 1 through March 31, 1991. The work is organized into the following six task areas: Project management; battery systems technology; lithium/sulfide batteries; advanced sodium/metal chloride battery; aqueous batteries; and EV Battery performance/life evaluation.

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A multiple metal oxide sorbent supported on a zeolite of substantially silicon oxide is used for the desulfurization of process gas streams, such as from a coal gasifier, at temperatures in the range of about 1200.degree. to about 1600.degree. F. The sorbent is provided by a mixture of copper oxide and manganese oxide and preferably such a mixture with molybdenum oxide. The manganese oxide and the molybdenum are believed to function as promoters for the reaction of hydrogen sulfide with copper oxide. Also, the manganese oxide inhibits the volatilization of the molybdenum oxide at the higher temperatures.

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Reaction kinetics for the displacement of 5-aminoquinoline (5-Aq) and diethyl sulfide (SEt{sub 2}) from cis-[PtPh{sub 2}(CO)(L)] (L = 5-Aq or SEt{sub 2}) by aliphatic amines was measured for a wide array of amines. Reaction products were characterized by IR and NMR spectroscopies and crystalk structures of selected products were reported. Steric effects on the substitutions were discussed.

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It is demonstrated that normal pitting can occur during oxidizing conditions in the repository. It is also concluded that a new theory for pitting corrosion has to be developed, as the present theory is not in accordance with all practical and experimental observations. A special variant of pitting, based on the growth of sulfide whiskers, is suggested to occur during reducing conditions. However, such a mechanism needs to be demonstrated experimentally. A simple calculational model of canister corrosion was developed based on the results of this study. 69 refs, 3 figs.

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The effect of treatment with hydrogen, hydrogen sulfide, and steam on the catalytic properties of NaY zeolites has been studied. A mechanism has been proposed for activation of the zeolites, which explains the appearance of Broensted acid centers on modified samples. The influence of modification temperature and the degree of decationization of the zeolites on the promoting capacity of the latter in the cumene cracking reaction has been studied.

International Nuclear Information System (INIS)

A historical overview of corrosion problems found in power plant condensers and mitigation procedures is presented. The paper is organized according to alloy type and failure mode. Alloys considered are copper-base alloys, stainless steels and titanium. Failure modes discussed include erosion-corrosion, sulfide attack, environmentally assisted cracking, galvanic corrosion, steam condensate corrosion, pitting corrosion, and dealloying. Mitigation procedures discussed include cathodic protection, ferrous ion injection, as well as tube cleaning and layup practices.

British Library Electronic Table of Contents (United Kingdom)

The electrical characteristics of thin TiO2 films prepared by metal?organic chemical vapor deposition grown on a p-type InP substrate were studied. For a TiO2 film of 4.7?nm on InP without and with ammonium sulfide treatment, the leakage currents are 8.8?10?2 and 1.1?10?4?A/cm2 at +2 V bias and 1.6?10?1 and 8.3?10?4?A/cm2 at ?2?V bias. The lower leakage currents of TiO2 with ammonium sulfide treatment arise from the improvement of interface quality. The dielectric constant and effective oxide charge number density are 33 and 2.5?1013?cm2, respectively. The lowest mid-gap interface state density is around 7.6?1011?cm?2?eV?1. The equivalent oxide thickness is 0.52?nm. The breakdown electric field increases with decreasing thickness in the range of 2.5 to 7.6?nm and reaches 9.3?MV/cm at 2.5?n...

International Nuclear Information System (INIS)

High general corrosion resistance of high-alloy OCTG (oil country tubular goods) to CO_2 may be limited by pitting corrosion in presence of chlorides and sulfides. The pitting resistance of 13% Cr steel, duplex and high Ni austenitic stainless steels have been examined by electrochemical measurements in a high temperature, high pressure autoclave simulating the well conditions. Each steel shows the pitting potential in CO_2-NaCl-H_2O system, the value of which being less noble as the Cl"- concentration and the temperature increase. The presence of H_2S is also detrimental. High alloying additions of Cr and Mo enhance pitting resistance whether or not H_2S is present. The corrosion potentials of these steels in the simulating well conditions in which oxygen is absent do not exceed the pitting potential. Therefore, pitting corrosion can not occur by the passivity break through mechanism.

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This Public Design Report provides, in a single document, available nonproprietary design -information for the ``Innovative Coke Oven Gas Cleaning System for Retrofit Applications`` Demonstration Project at Bethlehem Steel Corporation`s Sparrows Point, Maryland coke oven by-product facilities. This project demonstrates, for the first time in the United States, the feasibility of integrating four commercially available technologies (processes) for cleaning coke oven gas. The four technologies are: Secondary Gas Cooling, Hydrogen Sulfide and Ammonia Removal, Hydrogen Sulfide and Ammonia Recovery, and Ammonia Destruction and Sulfur Recovery. In addition to the design aspects, the history of the project and the role of the US Department of,Energy are briefly discussed. Actual plant capital and projected operating costs are also presented. An overview of the integration (retrofit) of the processes into the existing plant is presented and is followed ...

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Corrosion test, as a material selection test method of nozzle to be used in the marine diesel engine, was adopted and discussed. Due to the heightening in output power and lengthening in stroke of the marine diesel engine, the fuel injection nozzle became so severe in working condition that the nozzle tip became in lift 1/6 to 1/18 time as long as that of short stroke type in past. Then upon investigating cause of damage, the damage was confirmed to be mainly caused by the high temperature sulfidization corrosion. Then by preparing 20 kinds of candidate test piece and making sulfidization corrosion test in accordance with the high temperature corrosion test procedure, corrosiveness was evaluated through change in weight between before and after testing. As a result of testing, three kinds of test piece, inclusive of high Ni-Cr-Al alloy's, showed a high anti-corrosiveness. Those kinds of test piece were then field tested on board of ...

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The industrial standard process for the purification of natural gas is to remove acid gases, mainly hydrogen sulfide and carbon dioxide, by the absorption and reaction of these gases with alkanolamines. Inadequate data for vapor -- liquid equilibrium (VLE) hinder the industry from converting operations to more energy efficient amine mixtures and conserving energy. Some energy reductions have been realized in the past decade by applying such amine systems as ``hindered`` amines, methyldiethanolamine (MDEA), and MDEA based amine mixtures. However, the lack of reliable and accurate fundamental VLE data impedes the commercial application of these more efficient alkanolamine systems. The first project objective is to improve the accuracy of vapor -- liquid equilibrium measurements at low hydrogen sulfide concentrations. The second project objective is to measure the VLE for amine mixtures. By improving the accuracy of the VLE measurements on MDEA ...

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Options for successfully using biogas depend on project scale. Almost all biogas from anaerobic digesters must first go through a gas handling system that pressurizes, meters, and filters the biogas. Additional treatment, including hydrogen sulfide-mercaptan scrubbing, gas drying, and carbon dioxide removal may be necessary for specialized uses, but these are complex and expensive processes. Thus, they can be justified only for large-scale projects that require high-quality biogas. Small-scale projects (less than 65 cfm) generally use biogas (as produced) as a boiler fuel or for fueling internal combustion engine-generators to produce electricity. If engines or boilers are selected properly, there should be no need to remove hydrogen sulfide. Small-scale combustion turbines, steam turbines, and fuel cells are not used because of their technical complexity and high capital cost. Biogas cleanup to pipeline or transportation fuel specifications is ...

Science.gov (United States)

The study of the intrinsic behavior of high transition temperature copper-oxide superconductors (HTSC) has proven to be challenging because of the extreme sensitivity of their transport properties on material quality. These compounds are characterized by a high degree of structural and electrical anisotropy, and a very short superconductive coherence length of the same order as the size of the crystalline unit cell (~5-30 A). As a result, microscopic defects such as oxygen vacancies, cationic disorder, and the presence of minute impurities have a significant effect on electrical transport in these materials. Therefore, much effort has been expended in synthesizing sizable samples that are homogeneous, well characterized, and emenable to the study of the anisotropic properties of the HTSC. We have demonstrated that thin films of HTSC compounds such as rm YBa_2Cu_3O_{7 -delta}, which is a 92 K superconductor, can be synthesized easily by a technique known as pulsed laser deposition, and ...

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This invention refers to the organic geochemistry and can be used in prospecting for oil and gas. The method includes taking samples of rocks, extracting from them the chloroform bitumoid and its thermal processing. In order to improve the accuracy, the equal quantities of bitumoid taken are exposed to gradual thermal treatment to temperatures exceeding the thresholds of thermal stability of sulfur-containing compounds, in each temperature interval, the content of hydrogen sulfide released in this case is revealed, and by its drastic increase at temperatures corresponding to the temperatures of the productive part of the section, a conclusion is drawn about the epigenetic nature of the bitumoid. The method makes it possible to improve the resolution of the bituminological prospecting for oil and gas.

International Nuclear Information System (INIS)

Corrosion testings of model alloys, corresponding by chemical composition to simple and complex-alloyed #gamma#- and #gamma#'-phases of nickel heat-resistant alloys are conducted in sodium sulfate and chloride melts. It is ascertained that heat resistant nickel alloys containing over 50 % of hardening #gamma#'-phase, are subject to disastrous sulfide corrosion (SC). Resistance against SC alloys containing below 50 % of #gamma#'-phase is determined by the resistance of #gamma#-solid solution. 10 refs., 3 figs., 2 tabs.

Science.gov (United States)

B-cell Chronic Lymphocytic Leukemia; Nodal Marginal Zone B-cell Lymphoma; Recurrent Adult Burkitt Lymphoma; Recurrent Adult Diffuse Large Cell Lymphoma; Recurrent Adult Diffuse Mixed Cell Lymphoma; Recurrent Adult Diffuse Small Cleaved Cell Lymphoma; Recurrent Adult Grade III Lymphomatoid Granulomatosis; Recurrent Adult Immunoblastic Large Cell Lymphoma; Recurrent Adult Lymphoblastic Lymphoma; Recurrent Grade 1 Follicular Lymphoma; Recurrent Grade 2 Follicular Lymphoma; Recurrent Grade 3 Follicular Lymphoma; Recurrent Mantle Cell Lymphoma; Recurrent Marginal Zone Lymphoma; Recurrent Small Lymphocytic Lymphoma; Splenic Marginal Zone Lymphoma; Waldenstrom Macroglobulinemia

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Recent progress in yttrium-based oxide high-temperature superconductors has enabled the production of a large diameter bulk with a strong flux-pinning force. A combination of this superconductor and a permanent magnet makes it feasible to fabricate a noncontact, non-controlled superconducting magnetic bearing with a very small rotational loss, applicable to a flywheel energy storage system. A conceptual design of an 8 MWh flywheel energy storage system using the new bearing has been developed, based on measured data on a miniature bearing model, which proved to be potentially capable of achieving a high energy storage efficiency of 84 pc. A 100 W h-class experimental system was then built, which attained a high revolution rate of 17000 rpm, with a rotational loss of about 0.6 W. (authors). 2 refs., 7 figs., 3 tabs.

International Nuclear Information System (INIS)

With the assistance of mechanical activation, yttrium-stabilized #alpha#-SiAlON was prepared by combustion synthesis in air, instead of high-pressure N_2 atmosphere for the first time. The reaction activity of metallic particles was remarkably enhanced by mechanical activation, which conduced the reduction of grain size, increased the total surface area and formation of fresh surface. The formation of #alpha#-SiAlON by combustion synthesis in air was explained by a kinetically induced reaction mechanism, in which both initial formation of #alpha#-SiAlON and following avoidance of oxidation were fulfilled by the retardation of O_2 infiltration owing to the short reaction period and fast cooling rate.

British Library Electronic Table of Contents (United Kingdom)

Abstract Background and Purpose: During laser lithotripsy, working instruments are often in close proximity to the distal fiber tip and may be damaged accidentally or even intentionally. The aim of this study was to compare the amount of damage to a standard guidewire and the nitinol wires of endourologic retrieval baskets that were affected by three different clinically available laser systems. Materials and Methods: The impact of pulsed laser irradiation on a standard hydrophilic guidewire and a retrieval basket were investigated. One infrared (IR) laser system (holmium:yttrium-aluminum-garnet [Ho:YAG]: ????=???2100???nm) and two laser systems emitting light in the visible (VIS) spectral range (frequency-doubled double-pulse neodymium:YAG [FREDDY]: ????=???532???nm/1064???nm and flashl...

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The authors examine the relationship of the structure and mechanical properties of similar alloys of tungsten with rhenium produced by the powder metallurgy method by sintering powders. Since the alloys were deformed by rolling, we examine the effect of the resultant anisotropy of the structure on the properties of the metal in various directions. The tests were conducted on an alloy of tungsten with 2 wt.% rhenium and, for comparison purposes, an alloy of tungsten with additions of oxides of yttrium and hafnium. The mechanical properties of the alloys, i.e., strength, cracking resistance, cold shortness temperature, were determined in the bend test. Structural examination was carried out using an optical microscope, electron scanning microscopy, and the method of transmission electron microscopy.

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The use of aqueous methyldiethanolamine (MDEA) for selective removal of hydrogen sulfide from acid gas streams has been studied in a 2 inch column packed with 1/4 inch ceramic Intalox saddles. The column was operated in a counter-current, steady state fashion. The feed gas composition varied between 1 and 5 mole % hydrogen sulfide and between 0 and 50 mole % carbon dioxide. In order to assist the development of packed column absorption models, the rate at which pure carbon dioxide absorbs into 2 M MDEA was measured as a function of pressure, liquid flow rate and packed bed length. The importance of end effects was carefully evaluated. In addition, draining and tracer methods were used to estimate the amount of static holdup present in the column. Using classical draining methods, as much as 50 % of the total holdup was found to be static. However, according to the step decrease in tracer method, less than 5 % of the total holdup was static. ...

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In this report, we outline the progress achieved in two distinct under the DOE-sponsored cross section project: the initial results obtained from the pulsed 14 MeV neutron facility, and a cooperative effort with Argonne National Laboratory in the measurement of fast neutron cross sections in yttrium. In the 14 MeV neutron laboratory, this year has seen the maturation of the project into one in which initial scattering measurements are now underway. We have improved the accelerator and ion source in several significant ways, so that neutron intensities have now been proven to be adequate for our series of elastic scattering angular distribution measurements outlined in our initial proposal of two years ago. We have successfully tested all components of the time-of-flight spectrometer and recorded initial neutron spectra from the ring targets that we have obtained for our first angular distribution measurements. Examples of the time-of-flight spectra that have been ...

International Nuclear Information System (INIS)

A spectrophotometric study of the extraction with isobutanol of rare-earth elements in the form of complexes with quinoilizarin and N-benzene-N-phenylhydroxylamine has been made. The purpose of the study is to find out whether this reaction can be used in determining the concentration of elements in the presence of other rare-earth elements. In determining the relationship between the pH and light absorption the pH of the solution is measured after the extraction. The extraction of complexes begins at pH approximately 4 and reaches a maximum at pH7-8 (for La) and pH6-9 (for Er). The complexes underge decomposition when pH of the solution increased. The composition of complex compounds is determined by spectrophotometric methods for isomolar series, molar ratios and from the slope of logarithmic plots. Under optimal conditions (pH7.5) aAd at the measured ratio of the component for each ion of rare-earth elements, the molar extinction coefficients are determined for complexes in ...

British Library Electronic Table of Contents (United Kingdom)

In this paper, we study the optical properties of indium sulfide thin films to establish the best conditions to obtain a good solar cell buffer layer. The In2S3 buffer layers have been prepared by chemical bath deposition (CBD) and thermal evaporation (PVD). Optical behavior differences have been found between CBD and PVD In2S3 thin films that have been explained as due to structural, morphological and compositional differences observed in the films prepared by both methods. The resultant refractive index difference has to be attributed to the lower density of the CBD films, which can be related to the presence of oxygen. Its higher refractive index makes PVD film better suited to reduce overall reflectance in a typical CIGS solar cell.

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Colloidal nanocrystals attract significant interest due to their potential applications in electronic, magnetic, and optical devices. Nanocrystal supercrystals (NCSCs) are particularly appealing for their well ordered structure and homogeneity. The interactions between organic ligands that passivate the inorganic nanocrystal cores critically influence their self-organization into supercrystals, By investigating the mechanical properties of supercrystals, we can directly characterize the particle-particle interactions in a well-defined geometry, and gain insight into both the self-assembly process and the potential applications of nanocrystal supercrystals. Here we report nanoindentation studies of well ordered lead-sulfide (Pbs) nanocrystal supercrystals. Their modulus and hardness were found to be similar to soft polymers at 1.7 GPa and 70 MPa respectively and the fractures toughness was 39 KPa/m1/2, revealing the extremely brittle nature of these materials.

International Nuclear Information System (INIS)

This paper describes stable strontium as composed of four stable isotopes ( Sr 88, Sr 87, Sr 86, and Sr 84), of which Sr 88 contributes more than 82% to its composition. Strontium exists in three crystalline, plymorphic forms; face-centered cubic alpha form, hexagonal beta form and body-centered cubic gamma form. Strontium occupies in many physicochemical aspects an intermediate position between calcium and barium, as does the solubility of strontium salts. As a result of its oxidation potential, strontium readily forms oxides, halides, and sulfide. The author proposes that the slight discrimination against strontium incorporation into bony tissues may be due to the difference in ionic potential (14%) between strontium and calcium. Ionic potential is an indicator of the strength of ionic bonds: strontium has a smaller ratio of ionic charge to ionic radius when compared with calcium.

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In this paper, it is shown that (In1?xAlx)2S3 thin films can be grown through the co-evaporation of elemental indium, aluminum and sulfur. It is nevertheless observed that the introduction of aluminum within the indium sulfide thin films hinders the crystallites size and even yields almost amorphous films when x is 0.2. The investigations of the optical properties of the films reveal that contrary to what could be expected, the band gap increase is low; the highest values measured do not exceed 2.2eV. However, as suggested by X-ray photoelectron spectroscopy measurements, such widening most probably affects the lower conduction band states.

British Library Electronic Table of Contents (United Kingdom)

We have recently introduced several important improvements in the measurement of distillation curves for complex fluids. The modifications include a composition-explicit data channel for each distillate fraction (for both qualitative and quantitative analysis) and corrosivity assessment of each distillate fraction. The composition-explicit information is achieved with a new sampling approach that allows precise qualitative as well as quantitative analyses of each fraction, on the fly. We have applied the new method to a variety of fluids, including simple n-alkanes, rocket propellant, gasoline, jet fuels, and a hydrocarbon fluid made corrosive with dissolved hydrogen sulfide. In the current contribution, we present the application of the advanced distillation curve method to two samples of...

International Nuclear Information System (INIS)

Ultraviolet (UV) upconversion (UC) luminescence in Yb3+/Er3+-codoped yttrium oxide (Y2O3) nanocrystals can be enhanced by orders of magnitude via tridoping further with Li+ ions under diode laser excitation of 970 nm. Sensitized three-photon UC radiations at 390 and 409 nm, corresponding to the 4G11/2?4I15/2 and 4H9/2?4I15/2 of Er3+ ions, respectively, present an enhancement time of about 33 times, which is larger than the 24 times enhancement for the UC green radiation. The UV UC radiation at 320 nm that corresponds to the 2P3/2?4I15/2 of Er3+ ions has also been greatly enhanced. Theoretical calculations interpret that all the observed enhancement times of UV UC radiations arise from the prolonged lifetimes of their intermediate states.

International Nuclear Information System (INIS)

Research highlights: #-># The Y-intermetallic can accelerate corrosion and Y can increase the protectiveness of the surface layer. #-># In 0.1 M NaCl, the corrosion rate of Mg-Y alloys increased with increasing Y due to the Y intermetallic. #-># In 0.1 M NaCl, there was filiform corrosion. #-># In 0.1 M Na_2SO_4, the corrosion rate of Mg-Y alloys decreased with increasing Y in the range 3-7%Y. #-># Hydrogen evolution was observed from particular parts of the alloy surface. - Abstract: Corrosion of Mg-Y alloys was studied using electrochemical evaluations, immersion tests and direct observations. There were two important effects. In 0.1 M NaCl, the corrosion rate increased with increasing Y content due to increasing amounts of the Y-containing intermetallic. In 0.1 M Na_2SO_4, the corrosion rate decreased with increasing Y content above 3%, attributed to a more protective surface film, despite the intermetallic. The corrosion rate evaluated by electrochemical impedance ...

CERN Document Server

We point out that electromagnetic one-way edge modes analogous to quantum Hall edge states, originally predicted by Raghu and Haldane in 2D gyroelectric photonic crystals possessing Dirac point-derived bandgaps, can appear in more general settings. In particular, we show that the TM modes in a gyromagnetic photonic crystal can be formally mapped to electronic wavefunctions in a periodic electromagnetic field, so that the only requirement for the existence of one-way edge modes is that the Chern number for all bands below a gap is non-zero. In a square-lattice gyromagnetic Yttrium-Iron-Garnet photonic crystal operating at microwave frequencies, which lacks Dirac points, time-reversal breaking is strong enough that the effect should be easily observable. For realistic material parameters, the edge modes occupy a 10% band gap. Numerical simulations of a one-way waveguide incorporating this crystal show 100% transmission across strong defects, such as perfect ...

Science.gov (United States)

Certain materials, especially Sn, passivate the rare earth-exchanged Y zeolite (REY) used in petrochemical fluid-cracking catalysts against vanadium degradation caused by V impurities in the feed oil. The mechanism of passivation was investigated here from the standpoint of high-temperature oxide acid-base reaction; i.e., where the controlling factors were considered to be Lewis acid-base reactions between V{sub 2}O{sub 5}, the RE oxides, SnO{sub 2}, etc. Molten salt tests at 680{degree}C showed SnO{sub 2}, presumably because of its acidic nature, to be essentially nonreactive with V{sub 2}O{sub 5} or Na{sub 2}O-V{sub 2}O{sub 5} compounds. A hypothesis was developed to explain how the passivation effect by Sn might result from the unique resistivity of SnO{sub 2} to reaction with V{sub 2}O{sub 5}.

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A heat resistant nickel base alloy which is excellent in not only hot and cold workability but also high temperature strength properties and which also possesses satisfactory oxidation resistance. The nickel base alloy consists essentially of 0.001-0.15 percent carbon, 0.0005-0.05 percent calcium, 20.0-126.0 percent chromium, 4.7-9.4 percent cobalt, 5.0-16.0 percent molybdenum, 0.5-4.0 percent tungsten, with the total of molybdenum plus tungsten being from 9.0 to 16.5 percent, and the balance nickel and inevitable impurities. The alloy may further contain one selected from the group consisting of (1) 0.3-1.5 percent aluminum and 0.1-1.0 percent titanium, (2) 0.001-0.30 percent at least one of yttrium and rare earth elements, and (3) 0.001-1.0 percent at least one of niobium, vanadium and tantalum, whereby the aforementioned characteristics are further enhanced.

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By magnetron sputtering model steel films with specific properties can be prepared for purposive surveys. By changing the deposition parameters certain properties of these films can be influenced. For this thesis steel films with 18% Cr and 8% Ni have been prepared in order to study specific parameters on the corrosion resistance of bulk stainless steel. Chemical composition, microstructure, and surface morphology of these films have been characterized. In comparison to bulk steel sheets with the same chemical composition they have a smaller grain size and a ferritic structure. In contrast to bulk steel sheets they don`t contain any nonmetallic inclusions like Mn-sulfides. The influence of these structural differences on the corrosion resistance has been studied. For this purpose the electrochemical properties of the sputter-deposited steels have been compared with the properties of steel sheets with a similar chemical composition (DIN 1.4301, AISI 304) in neutral ...

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Late plagiogranite bodies in the Semail ophiolite have been previously suggested to represent late stage fractionates within an episodic spreading center magma chamber or the roots of seamount chains. Field and lab observations suggest that these late silicic magma chambers represent zones of repeated injection by dikes of intermediate to mafic composition. Multiple generations of intrusion, partial resorption and reintrusion are preserved in the plagiogranite as 1) relict phantom xenoliths, 2) angular xenoliths with quartz-rich margins, 3) deformed fine-grained dikes with distinct chilled margins, and 4) planes of rectangular blocks with cuspate margins or ellipsoids of similar fine grained mafic materials. The blocks and ellipsoids are actually dismembered mafic dikes that chilled by intruding a cooler silicic liquid and were either thermally fractured or pinched out. All of the dikes are hydrothermally altered to assemblages including amph., qtz., epi., preh., and chl. and are ...

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The novel optical, electronic, and/or magnetic properties of metal and semiconductor nanoparticles have resulted in extensive research on new methods for their preparation. An ideal preparation method would allow the particle size, size distribution, crystallinity, and particle shape to be easily controlled, and would be applicable to a wide variety of material systems. Numerous preparation methods have been reported, each with its inherent advantages and disadvantages; however, an ideal method has yet to emerge. The most widely applied methods for nanoparticle preparation include the sonochemical reduction of organometallic reagents,(1&2) the solvothermal method of Alivisatos,(3) reactions in microemulsions,(4-6) the polyol method (reduction by alcohols),(7-9) and the use of polymer and solgel materials as hosts.(10-13) In addition to these methods, there are a variety of methods that take advantage of the unique properties of a supercritical fluid.(14&15) Through simple ...

Science.gov (United States)

This report presents the operating results for Run 245 at the Advanced Coal Liquefaction R and D Facility in Wilsonville, Alabama. This run was made in an all-distillate Integrated Two-Stage Liquefaction (ITSL) mode using Illinois 6 coal from the Burning Star mine. The primary run objective was to obtain steady-state ITSL performance by replacing spent HTR reactor catalyst with fresh, sulfided catalyst. Secondary objectives were to maintain an all-distillate (minimum resid production) product slate and to demonstrate the effects of catalyst addition on the net gas production and hydrogen consumption. Run 245 began on 7 November, 1983, and continued through 12 February, 1984. During this period, 179.0 tons of coal was fed in 2045 hours of operation. Eight special product workup material balances were defined, and the results are presented herein. 6 references, 28 figures, 20 tables.

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The Electrochemical Program at Argonne National Laboratory (ANL) provides technical and programmatic support to DOE`s Electric and Hybrid Propulsion Division (DOE-EHP). The goal of DOE-EHP is to advance promising electric-vehicle (EV) propulsion technologies to levels where industry will continue their commercial development and thereby. significantly reduce petroleum consumption in the transportation sector of the economy. In support of this goal, ANL provides research, development, testing/evaluation, post-test analysis, modeling, database management, and technical management of industrial R&D contracts on advanced battery and fuel cell technologies for DOE-EHP. This report summarizes the battery-related activities undertaken during the period of October 1, 1991 through March 31, 1992. In this report, the objective, background, technical progress, and status are described for each task. These tasks are structured into the following task areas: 1.0 Project Management and ...

Energy Technology Data Exchange (ETDEWEB)

The Electrochemical Program at Argonne National Laboratory (ANL) provides technical and programmatic support to DOE's Electric and Hybrid Propulsion Division (DOE-EHP). The goal of DOE-EHP is to advance promising electric-vehicle (EV) propulsion technologies to levels where industry will continue their commercial development and thereby. significantly reduce petroleum consumption in the transportation sector of the economy. In support of this goal, ANL provides research, development, testing/evaluation, post-test analysis, modeling, database management, and technical management of industrial R D contracts on advanced battery and fuel cell technologies for DOE-EHP. This report summarizes the battery-related activities undertaken during the period of October 1, 1991 through March 31, 1992. In this report, the objective, background, technical progress, and status are described for each task. These tasks are structured into the following task areas: 1.0 Project Management and ...

Energy Technology Data Exchange (ETDEWEB)

The Electrochemical Technology Program at Argonne National Laboratory (ANL) provides technical and programmatic support to DOE's Electric and Hybrid Propulsion Division (DOE-EHP). The goal of DOE-EHP is to advance promising electric-vehicle (EV) propulsion technologies to levels where industry will continue their commercial development and thereby significantly reduce petroleum consumption in the transportation sector of the economy. In support of this goal, ANL provides research, development, testing/evaluation, post-test analysis, modeling, database management, and technical management of industrial R D contracts on advanced battery technologies for DOE-EHP. This report summarizes the battery-related activities undertaken during the period of July 1, 1992 through September 30, 1992. In this report, the objective, background, technical progress, and status are described for each task. The work is organized into the following task areas: Project Management and Coordination; ...

International Nuclear Information System (INIS)

Sediment treatment and sediment storage may alter sediment toxicity, and consequently biotic response. Purpose of our study was to combine these three aspects (treatment-toxicity-biotic response) in one integrated approach. We used Acid Volatile Sulfide (AVS) concentrations as a proxy of the disturbance of the sediment. AVS and Simultaneously Extracted Metal (SEM) concentrations were compared to bioassay responses with the freshwater benthic macroinvertebrate Asellus aquaticus. Storage conditions and sediment treatment affected AVS but not SEM levels. AVS can be used as a proxy for sediment disturbance. The best way to pretreat the sediment for use in a bioassay in order to maintain initial AVS conditions was to sample the sediment with an Ekman grab, immediately store it in a jar without headspace, and freeze it as soon as possible. In a survey using seven different sediments, bioassay responses of A. aquaticus were correlated with SEM and AVS characteristics. - ...

Energy Technology Data Exchange (ETDEWEB)

The effects of thiosulfate ion and solution pH on pitting corrosion of Alloy 690 in chloride solution were explored. Potentiodynamic polarization measurements were conducted to evaluate pitting corrosion susceptibility of Alloy 690 in these environments. The results showed that pitting corrosion occurred in the mill-annealed (1050 deg. C/5min) Alloy 690 in 1 wt% NaCl solution but not in 0.1 M Na{sub 2}S{sub 2}O{sub 3} solution. The value of pitting nucleation potential (E{sub np}) determined in 1 wt% NaCl solution (without Na{sub 2}S{sub 2}O{sub 3} ) increased with increasing solution pH value in the range of 2-10. The addition of Na{sub 2}S{sub 2}O{sub 3} to 1 wt% NaCl solution greatly affected the pitting corrosion behavior, which was dependent on concentration. The preformed nickel sulfide surface film due to the presence of Na{sub 2}S{sub 2}O{sub 3} caused Alloy 690 to become more susceptible to pitting corrosion in 1 wt% NaCl solution.

Energy Technology Data Exchange (ETDEWEB)

Metallic components within or immediately adjacent to gasifiers, such as gas distributors, thermowells, transfer lines, and cyclones, are subjected to severe of temperature, pressure, and hostile multicomponent gas environments. Metallic heat exchangers/waste-heat boilers resistant to sulfidation, corrosion. and erosion in low- and medium-Btu gas environments are essential components in large-scale gasification schemes, in both dry ash and slogging type gasifiers. Components, in general. must be resistant to corrosion, erosion, and high-temperature creep. A substantial data base is needed on the mechanical properties of materials exposed to complex gas environments to provide a more viable basis for establishing long-term reliability of components. This work examines high-temperature creep of Alloy 800, a high-chromium alloy widely used in coal conversion systems, after exposure to oxygen and oxygen/sulfur mixed-gas environments over a wide temperature range. In ...

Energy Technology Data Exchange (ETDEWEB)

The NiMo sulfide supported on Ketjen Black (KB) was more effective and yielded lighter oil products containing light fractions with their boiling point below 300{degree}C during the two stage liquefaction combining low temperature and high temperature hydrogenation the conventional NiMo/alumina catalyst and FeS2 catalyst. Although the NiMo/alumina yielded increased oil products during the two stage liquefaction, the lighter oil fractions did not increase and the heavier fractions increased mainly. This suggests that the hydrogenation of aromatic rings and successive cleavage of the rings are necessary for producing the light oil, which is derived from the sufficient hydrogenation of aromatic rings using catalysts. For the two stage reaction with NiMo/KB catalyst, it was considered that sufficient hydrogen was directly transferred to coal molecules at the first stage of the low temperature reaction, which promoted the solubilization of coal and the successive ...

Energy Technology Data Exchange (ETDEWEB)

An advanced process for the separation of hydrogen sulfide (H{sub 2}S) from coal gasification product streams through an electrochemical membrane is being developed. H{sub 2}S is removed from the syn-gas stream, split into hydrogen, which enriches the exiting syn-gas, and sulfur, which is condensed from an inert sweep gas stream. The process allows removal of H{sub 2}S without cooling the gas stream and with negligible pressure loss through the separator. The process is made economically attractive by the lack of need for a Claus process for sulfur recovery. Membrane manufacturing coupled with full-cell experimentation was the primary focus this quarter. A tape-casted zirconia membrane was developed and utilized in one full-cell experiment (run 25); run 24 utilized a fabricated membrane purchased from Zircar Corporation. Results are discussed.

International Nuclear Information System (INIS)

The fundamental optical properties of dysprosium (Dy) doped strontium sulfide bulk samples for various dopant concentrations from 0.1 to 1.0 at.% were investigated by X-ray diffraction (XRD), electron paramagnetic resonance spectroscopy (EPR), room temperature photoluminescence (PL), photoluminescence excitation (PLE) and diffuse reflectance spectroscopy (DRS). Investigations by electron paramagnetic resonance yielded the state of Dy in the sample as Dy3+. An additional ESR line due to F+ center was observed. The PL emission spectrum consisted of several intense lines and a number of weaker ones which were identified as transitions between energy levels of Dy3+. The optimum doping concentration for maximum intensity was found to be 0.25 at.%. Blue shift of the absorption edge energy and red shift of the PLE spectrum were observed with increasing doping concentration. The former is due to Burstein-Moss (BM) effect and the latter is attributed due to the presence of ...

International Nuclear Information System (INIS)

Previous corrosion studies identified the materials Hastelloy C4, Ti 99.8-Pd, and carbon steels as promising for the manufacture of long-lived high-level waste containers that could act as an engineered barrier in a rock-salt repository. Here, the efficiency of the corrosion-resistant concept using surface-welded Hastelloy C4 as corrosion protection of carbon steel containers is compared with the corrosion-allowance concept using unalloyed or low-alloyed steels. The materials are examined in three disposal relevant brines (two rich in MgCl_2, one rich in NaCl) at 150 C. The results indicate that welded Hastelloy C4 is highly resistant to corrosion in the NaCl-rich brine. In the presence of sulfides or MgCl_2-rich brines, however, severe pitting corrosion occurs. The three steels investigated are resistant to pitting corrosion in all brines, and their general corrosion rates imply corrosion allowances acceptable for thick-walled containers. In view of these results, ...

Energy Technology Data Exchange (ETDEWEB)

Acid mine drainage is a serious environmental problem caused by the oxidation of sulfide minerals that releases highly acidic, sulfate, and metals-rich drainage. In this study, alkaline industrial wastes were mixed with acid mine tailings in order to obtain neutral conditions. A series of column leaching tests were performed to evaluate the behavior of reactive mine tailings amended with alkaline-additions under dynamic conditions. Column tests were conducted of oxidized mine tailings combined with cement kiln dust, red mud bauxite, and mixtures of cement kiln dust with red mud bauxite. The pH results show the addition of 10% of alkaline materials permits the maintenance of near neutral conditions. In the presence of 10% alkaline material, the concentration of toxic metals such as Al, Cu, Fe, Zn are significantly reduced as well as the number of viable cells (Thiobacillus ferrooxidans) compared to control samples.

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Simultaneously extracted metals (SEM) and acid volatile sulfide (AVS) show the potential for toxicity on the basis of their ratio. Accordingly, the authors spiked cadmium in a range for which Cd/AVS ratios were from 0.2 to 10 in the sediment with its weight about 8 kg in each batch. Dialysis samplers with a cation ion-exchange resin (Dowex 50W-X4) collection were used in a laboratory for the determination of free cadmium concentrations in pore water of the collected sediment. When equilibrium was reached among cadmium in pore water, sediment, and ion-exchange resin, cadmium exchanged onto resin phase was regenerated with 1 N hydrochloric acid (OPTIMA grade) and determined using an atomic absorption spectrophotometer (Zeeman 5000) with a graphite furnace accessory. Cadmium determined using the dialysis sampler is considered as free cadmium which is related to the metal bioavailability toward aquatic biota. The developed methodology provides a new technique for ...

Energy Technology Data Exchange (ETDEWEB)

This report presents the results of Run 260 performed at the Advanced Coal Liquefaction R D Facility in Wilsonville. The run was started on July 17, 1990 and continued until November 14, 1990, operating in the Close-Coupled Integrated Two-Stage Liquefaction mode processing Black Thunder mine subbituminous coal (Wyodak-Anderson seam from Wyoming Powder River Basin). Both thermal/catalytic and catalytic/thermal tests were performed to determine the methods for reducing solids buildup in a subbituminous coal operation, and to improve product yields. A new, smaller interstage separator was tested to reduce solids buildup by increasing the slurry space velocity in the separator. In order to obtain improved coal and resid conversions (compared to Run 258) full-volume thermal reactor and 3/4-volume catalytic reactor were used. Shell 324 catalyst, 1/16 in. cylindrical extrudate, at a replacement rate of 3 lb/ton of MF coal was used in the catalytic stage. Iron oxide was used as slurry catalyst ...

Energy Technology Data Exchange (ETDEWEB)

The Electrochemical Technology Program at Argonne National Laboratory (ANL) provides advanced battery R D; technology transfer to industry; technical analyses, assessments, modeling, and databases; and independent testing and post-test analyses of advanced batteries. These capabilities and services are being offered to the US Advanced Battery Consortium (USABC) and Cooperative Research and Development Agreements (CRADA) are being negotiated for USABC-sponsored work at ANL. A small portion of DOE's cost share for USABC projects has been provided to ANL to continue R D and testing activities on key technologies that were previously supported directly by DOE. This report summarizes progress on these USABC projects during the period of April I through September 30, 1992. In this report, the objective, background, technical progress, and status are described for each task. The work is organized into the following task areas: 1.0 Lithium/Sulfide Batteries; 2.0 ...

British Library Electronic Table of Contents (United Kingdom)

Platinum Group Element (PGE) concentrations in garnet pyroxenite xenoliths from Oahu, Hawaii, are significantly lower than those in mantle peridotites and show fractionated patterns (e.g. PdN/OsN=2-10, PdN/IrN=4-24; N=chondrite normalized) and very high ReN/OsN ratios (9-248). Mass balance calculations show that the bulk rock pyroxenite PGE inventory is controlled by the presence of sulfide phases. The 187Os/188Os ratios of these pyroxenites vary from subchondritic to suprachondritic (0.123-0.164); and the 187Os/188Os ratios show good correlations with bulk rock and clinopyroxene major and trace element compositions, and bulk rock PGE and sulfur abundances. These observations suggest that the Os isotope compositions in these pyroxenites largely reflect primary processes in the oceanic mant...

Science.gov (United States)

One of the NASA research activities was to identify, characterize, and simulate a series of technologies that could be used for hydrogen production at NASA Kennedy Space Center (KSC) using locally available sources. This project examined the production of hydrogen from solar energy. To produce hydrogen by water splitting, the operating voltage of conventional photovoltaic (PV) cells cannot supply the overvoltage required. Thus, the objective of this project was to research and develop photoelectrochemical (PEC) cells that can supply the required voltage for water splitting by constructing a multiple bandgap tandem PV cell and a photocatalyst that can be activated by infrared (IR) photons transmitted through the PV cell. The proposed concept is different from conventional PEC water splitting by using multiple band gap combinations. The advantages for this PEC cell concept is that the PV cells are not in contact with the electrolyte solution, thus reducing the problems of corrosion and ...

International Nuclear Information System (INIS)

We recently found that injection of 2 mCi of yttrium 90 (90Y; approximately 23,000 rads) into normal canine knees stimulated glycosaminoglycan (GAG) synthesis by femoral condylar cartilage. The present investigation was conducted to determine whether radiation affects cartilage metabolism directly. Rates of GAG synthesis and degradation in normal canine articular cartilage were studied following irradiation. Cultured synovium from the same knees was treated similarly, to determine the effects of irradiation on hyaluronic acid synthesis. Twenty-four hours after exposure to 1,000 rads, 10,000 rads, or 50,000 rads, 35S-GAG synthesis by the cartilage was 93%, 69%, and 37%, respectively, of that in control, nonirradiated cartilage. The effect was not rapidly reversible: 120 hours after exposure to 50,000 rads, GAG synthesis remained at only 28% of the control level. Autoradiography showed marked suppression of 35S uptake by chondrocytes after irradiation. Cartilage GAG ...

Energy Technology Data Exchange (ETDEWEB)

The processing characteristics, tensile properties, and oxidation response of two Nb-Ti-Al-Cr alloys were investigated. One creep tests at 650{degrees}C and 172 MPa was conducted on the base alloy which contained 40Nb-40-Ti-10Al-10Cr. A second alloy was modified with 0.11 at. % carbon and 0.07 at. % yttrium. Alloys were arc melted in a chamber backfilled with argon, drop cast into a water-cooled copper mold, and cold rolled to obtain a 0.8-mm sheet. The sheet was annealed at 1100{degrees}C for 0.5 h. Longitudinal tensile specimens and oxidation specimens were obtained for both the base alloy and the modified alloy. Tensile properties were obtained for the base alloy at room temperature, 400, 600, 700, 800, 900, and 1000{degrees}C, and for the modified alloy at room temperature, 400, 600, 700, and 800{degrees}C. Oxidation tests on the base alloy and modified alloy, as measured by weight change, were carried out at 600, 700, 800, and 900{degrees}C. Both the base ...

International Nuclear Information System (INIS)

?-Y(IO3)3 and ?-Y(IO3)3 are transparent until 12.8 and 13.4 ?m, respectively; thus they are interesting as a potential laser matrix in the mid- and beginning of the far-infrared. So, in order to investigate the properties of lanthanides- doped anhydrous yttrium iodate, polycrystalline samples of ?-Y1-xNdx(IO3)3 (0.01?x?0.05), ?-Y1-xNdx(IO3)3 (0.001?x?0.1), ?-Y1-xYbx(IO3)3 (0.01?x?0.33) and ?-Y1-xYbx(IO3)3 (0.01?x?0.25) were synthesized. For Nd3+ ions, fluorescent emissions from the 4F3/2 multiplet were observed at 300 K under pulsed laser excitations at 750 nm and for Yb3+, fluorescent emissions from the 2F5/2 multiplet were observed at 300 K under pulsed laser excitations at 980 nm. The decays of all these emissions were measured. They are exponential and the fluorescence lifetimes are in the range 0.093-0.193 ms for Nd3+ and 0.370-0.541 ms for Yb3+, depending on the nature of the host and the concentration of doping.

International Nuclear Information System (INIS)

In the present paper a procedure is proposed for the determination of traces of Cd, Co, Mn and Cr in petroleum industry produced water by inductively coupled plasma optical emission spectrometry. The procedure is based on cloud point extraction of these metals, as their dithizonate complexes, into the surfactant-rich phase of octylphenoxypolyethoxyethanol surfactant (Triton X-114). Extractions were carried out in solutions with salinities between 10 per mille and 70 per mille. Since residual salinity in the surfactant-rich phase caused differences in its transport to the plasma, yttrium was used as an internal standard to correct for this effect. The simultaneous metal extraction procedure was optimized by response surface methodology using a Doehlert design and desirability function. Enhancement factors of 21, 21, 9 and 19, along with limits of quantification of 0.093, 0.20, 0.73 and 1.2 #mu#g L"-"1, and precision expressed as relative standard deviation (n = 8, ...

International Nuclear Information System (INIS)

Different SiAlON composites based on #alpha#'-SiAlON are investigated, with respect to the phase relationships, densification behavior, and mechanical properties. The compositions are located on a phase-diagram line parallel to the Si_3N_4-Y_2O_3#centre dot#9AlN compound in the Si_3N_4-SiO_2-AlN-Al_2O_3-Y_2O_3-YN system. Analysis of the reaction sequences shows that the formation of the composites is associated with the transient appearance of Y_4Al_2O_9 (YAM), yttrium-aluminum-garnet (YAG), melilite, and a nitrogen-rich liquid phase. The small shift of compositions on the Si_3N_4-Y_2O_3#centre dot#9AlN compound phase-diagram line toward the Al_2O_3-rich side offers the advantage of a higher sinterability and the removal of the melilite phase from a wide range of compositions containing #alpha#'-SiAlON and polytypes. The #alpha#'/#beta#'-SiAlON composites show better mechanical properties in comparison to pure #alpha#'-SiAlON and composites of #alpha#'-SiAlON and ...

Energy Technology Data Exchange (ETDEWEB)

The corrosion behaviour of the stainless steels 304, 316 Ti, 25Cr-20Ni-Mo-Ti, nickel base alloys Hastelloy C4, Inconel 625, Incoloy 800, Ti and Ti-0.2% Pd alloy has been studied in the aerated or deaerated solutions at 20/sup 0/C and 90/sup 0/C whose compositions are representative of interstitial ground waters: granitic or clay waters or salt brine. The electrochemical techniques used are voltametry, polarization resistance and complexe impedance measurements. Electrochemical data show the respective influence of the parameters such as temperature, solution composition and dissolved oxygen, addition of soluble species chloride, fluoride, sulfide and carbonates, on which depend the corrosion current density, the passivation and the pitting potential. The inhibition efficiency of carbonate and bicarbonate activities against pitting corrosion is determined. In clay water at 90/sup 0/C, Ti and Ti-Pd show very high passivation aptitude and a broad passive potential ...

Energy Technology Data Exchange (ETDEWEB)

The design of separation devices, particularly for solvent-based selective removal of H{sub 2}S from CO{sub 2}, requires an accurate mathematical model. Unfortunately, this requirement for high accuracy is often in conflict with the need for efficient computation. The addition of more and more complicated analyses, such as a move from Henry's law to a method incorporating gas and liquid activities for computing vapor liquid equilibria, may give a more accurate solution, but only at the cost of decreased computational efficiency. The efforts in this work have been directed toward two goals. The first was to develop an accurate mathematical model for the aqueous methyldiethanolamine (MDEA) system. The steady-state packed column model developed in this work has been tested with data from Schubert (1988) to verify its accuracy. The second goal was to modify the model to improve its computational efficiency. Areas such as vapor-liquid equilibrium calculations, flow hydrodynamics, ...

Energy Technology Data Exchange (ETDEWEB)

The theoretical and experimental investigation of the mechanism of SO2 and H2S removal by CaCO3 -based sorbents (limestones and dolomites) in pressurized uidized-bed coal combustors (PFBC) and high pressure gasiers, respectively, is the main objective of this study. It is planned to carry out reactivity evolution experiments under simulated high pressure conditions or in high pressure thermogravimetric and, if needed, uidized- bed reactor (high pressure) arrangements. The pore structure of fresh, heat-treated, and half-calcined solids (dolomites) will be analyzed using a variety of methods. Our work will focus on limestones and dolomites whose reaction with SO2 or H2S under atmospheric conditions has been studied by us or other research groups in past studies. Several theoret- ical tools will be employed to analyze the obtained experimental data including a variable diusivity shrinking-core model and models for diusion, reaction, and structure evolution in chemically reacting porous ...

International Nuclear Information System (INIS)

Cinnabar, a naturally occurring mercuric sulfide (HgS), has long been used in combination with traditional Chinese medicine as a sedative for more than 2000 years. Up to date, its pharmacological and toxicological effects are still unclear, especially in clinical low-dose and long-term use. In this study, we attempted to elucidate the effects of cinnabar on the time course of changes in locomotor activities, pentobarbital-induced sleeping time, motor equilibrium performance and neurobiochemical activities in mice during 3- to 11-week administration at a clinical dose of 10 mg/kg/day. The results showed that cinnabar was significantly absorbed by gastrointestinal (G-I) tract and transported to brain tissues. The spontaneous locomotor activities of male mice but not female mice were preferentially suppressed. Moreover, frequencies of jump and stereotype-1 episodes were progressively decreased after 3-week oral administration in male and female mice. ...

Science.gov (United States)

Most of the synthetic gypsum generated from wet flue gas desulfurization (FGD) scrubbers is currently being used for wallboard production. Because oxidized mercury is readily captured by the wet FGD scrubber, and coal-fired power plants equipped with wet scrubbers desire to benefit from the partial mercury control that these systems provide, some mercury is likely to be bound in with the FGD gypsum and wallboard. In this study, the feasibility of identifying mercury species in the FGD gypsum and wallboard samples was investigated using a large sample size thermal desorption method. Potential candidates of pure mercury standards including mercuric chloride (HgCl2), mercurous chloride (Hg2Cl2), mercury oxide (HgO), mercury sulfide (HgS), and mercuric sulfate (HgSO4) were analyzed to compare their results with those obtained from FGD gypsum and dry wallboard samples. Although any of the thermal evolutionary curves obtained from these pure mercury standards did not ...

Energy Technology Data Exchange (ETDEWEB)

In order to design catalysts suitable for primary liquefaction stage and secondary upgrading stage respectively in the multi-stage liquefaction process, various carbon-supported catalysts were prepared. Catalytic activities of them were investigated for the hydrogenation of 1-methylnaphthalene, to discuss the influences of metals and carbon species on the catalytic activity. Various water soluble and oil soluble Mo and Ni salts were used for NiMo supported catalysts. Among various carbon supports, Ketjen Black (KB) was effective for preparing the catalyst showing the most excellent hydrogenation activity. The KB and Black Pearl 2000 (BP2000) showing high hydrogenation activity were fine particles having high specific surface area more than 1000 m{sup 2}/g and primary particle diameter around 30 nm. This was inferred to contribute to the high dispersion support of active metals. Since such fine particles of carbon exhibited hydrophobic surface, they were suitable for preparing catalysts ...

International Nuclear Information System (INIS)

The environmental problem of ground level ozone is discussed, and the Canadian strategy for dealing with it is explained. Ozone in the troposphere can cause serious health problems in susceptible persons, and is estimated to cause up to $70 million in crop damage per year. The Canadian Council of Ministers of the Environment (CCME) Plan calls for less than 82 ppB by volume of ozone in any one-hour period in all areas of Canada by 2005. Three areas of Canada regularly exceed this value: the Lower Frazer valley in British Columbia, Saint John in New Brunswick, and the Windsor-Quebec corridor along the lower Great Lakes and the St. Lawrence River. Ozone is formed by a photochemical reaction of ammonia gases, nitrogen oxides, hydrogen sulfide or sulfur dioxide. Historically, ozone control has concentrated on controlling hydrocarbon emissions, but to little effect. In most locations close to large cities, ozone production is nitrogen oxide-limited, and the most recent ...

Energy Technology Data Exchange (ETDEWEB)

This report presents the work performed at the Institute of Gas Technology (IGT) during the second program quarter from October 1, 1993 to December 31, 1993, under Department of Energy (DOE) Contract No. DE-AC22-93PC92114. This program has co-ordinated funding for Task 1 from IGT`s Sustaining Membership Program (SMP), while DOE is funding Tasks 2--8. Progress in all tasks are reported. The overall objective of this research project is to develop a catalytic process to convert natural gas to liquid transportation fuels. The process consists of two steps that each utilize catalysts and sulfur containing intermediates: (1) to convert natural gas to CS{sub 2} and (2) to convert CS{sub 2} to gasoline range liquids. Experimental data will be generated to demonstrate the potential of catalysts and the overall process. During this quarter, progress in the following areas has been made. An existing unit at IGT was modified to accommodate the sulfur feedstocks and the higher temperatures ...

Energy Technology Data Exchange (ETDEWEB)

Low-temperature catalytic pretreatment is a promising approach to the development of an improved liquefaction process- This work is a fundamental study on effects of pretreatments on coal structure and reactivity in liquefaction. The main objectives of this project are to study the coal structural changes induced by low-temperature catalytic and thermal pretreatments by using spectroscopic techniques; and to clarify the pretreatment-induced changes in reactivity or convertibility of coals in the subsequent liquefaction. This report describes the recent progress of our work. Substantial progress has been made in the spectroscopic characterization of structure and pretreatment-liquefaction reactions of a Montana subbituminous Coal (DECS-9), and thermochemical analysis of three mw and reacted bituminous coals. Temperature programmed liquefaction has been performed on three low-rank coals both in the presence and absence of dispersed molybdenum sulfide catalyst. We ...

Energy Technology Data Exchange (ETDEWEB)

Chemical looping combustion (CLC) of simulated coal-derived synthesis gas was conducted with NiO oxygen carriers supported on SiO2, ZrO2, TiO2, and sepiolite. The effect of H2S on the performance of these samples for the CLC process was also evaluated. Five-cycle thermogravimetric analysis (TGA) tests at 800 C indicated that all oxygen carriers had a stable performance at 800 C, except NiO/SiO2. Full reduction/oxidation reactions of the oxygen carrier were obtained during the five-cycle test. It was found that support had a significant effect on reaction performance of NiO both in reduction and oxidation rates. The reduction reaction was significantly faster than the oxidation reaction for all oxygen carriers, while the oxidation reaction is fairly slow due to oxygen diffusion on NiO layers. The reaction profile was greatly affected by the presence of H2S, but there was no effect on the capacity due to the presence of H2S in synthesis gas. The presence of H2S decreased reduction ...

Energy Technology Data Exchange (ETDEWEB)

FeAl, which has high oxidation and sulfidation resistance, was shown to be thermodynamically compatible with WC. Calculations indicate that soly. of WC in liq. Fe-40at.%Al at 1450 C is about 2 at.%. Since liquid FeAl wets WC very well, the WC/FeAl system lends itself to liquid-phase sintering, resulting in close to theoretical densities. Almost fully dense cermets with 20.6 wt% FeAl binder were produced. With one-step infiltration, 98% dense cermets with only 7 wt% FeAl binder were fabricated. RT bend strengths and fracture toughness for WC-20.6 wt% FeAl reached 1680 MPa and 22 MPa{center_dot}m{sup 1/2}. Ductile binder fracture was observed on the fracture surfaces. Pores containing oxide inclusions were found, suggesting that improvements in processing are likely to further improve the mechanical properties. Insufficient process control may explain why WC/FeAlNi cermets did not show improved mechanical properties, although Ni strengthens FeAl. For WC bonded with ...

Energy Technology Data Exchange (ETDEWEB)

We have recently introduced several important improvements in the measurement of distillation curves for complex fluids. The modifications include a composition-explicit data channel for each distillate fraction (for both qualitative and quantitative analysis) and corrosivity assessment of each distillate fraction. The composition-explicit information is achieved with a new sampling approach that allows precise qualitative as well as quantitative analyses of each fraction, on the fly. We have applied the new method to a variety of fluids, including simple n-alkanes, rocket propellant, gasoline, jet fuels, and a hydrocarbon fluid made corrosive with dissolved hydrogen sulfide. In the current contribution, we present the application of the advanced distillation curve method to two samples of crude oil. A primary motivation behind the work is to precisely measure the distillation curves of these oils using our advanced distillation apparatus; these low uncertainty ...

Energy Technology Data Exchange (ETDEWEB)

Major advances in 'Energy and Materials Cycles' have been achieved in the removal of heavy metals from the solid residues of municipal waste incineration. It has been conclusively shown that the oxidation/reduction conditions established during the thermal treatment of filter ash have a decisive influence on the evaporation of groups of heavy metals. With respect to biomass gasification, studies have been carried out with respect to the best way of extracting pure hydrogen from the low calorific value gas that is typically obtained from a biomass gasifier. The overarching goal of the laboratory 'High Temperature Solar Technology' is the use of solar energy for the production of solar fuels, or for the reduction of CO{sub 2} emissions in large scale industrial processes that are conventionally carried out with the use of fossil fuels. In a short-term project targeted at the solar production of lime, highly encouraging results (98% degree of ...

International Nuclear Information System (INIS)

In laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS), the properties of laser-generated aerosols, such as size and composition, are crucial for matrix-independent quantification. In this study, the aerosol particle morphology and elemental composition generated by two state-of-the-art laser systems (ArF excimer nanosecond-UV laser and Ti:sapphire femtosecond-IR laser) were investigated by electron microscopic techniques. Electrostatic sampling of the aerosols directly onto transmission electron microscopy (TEM) grids allowed us to study the morphology and elemental composition of the aerosols using TEM and TEM-EDX (energy dispersive X-ray spectroscopy) analyses, respectively. The results of the electron microscopic studies were finally compared to the LA-ICPMS signals of the main matrix components. The investigations were carried out for non-conducting materials (glass and zircon), metallic samples (steel and brass) and semiconductors ...

Science.gov (United States)

Observational evidence is presented for the nucleation of condensation nuclei (CN) in the clear air adjacent to an isolated, marine, cumulus cloud. Two separate regions of particle nucleation are identified: one located above the cloud top, and the second located downwind of the cloud near the level of the anvil outflow. The regions of high CN concentrations were located in extremely clean marine air, with unactivated aerosol surface area (excluding the nucleation mode) less than 2 sq micrometers/cu cm, air temperature -31 C, and higher relative humidities than the undisturbed environment. Vertical profile measurements downwind of the cloud showed that CN concentrations at the level of the anvil outflow (4.9 km) were 8 times greater than at any other level between the surface and 5.3 km. A conceptual model is formulated in which aerosol particles, sulfur dioxide (SO2), sulfuric acid vapor (H2SO4), dimethyl sulfide (DMS), and ozone (O3) from the boundary layer are ...

Energy Technology Data Exchange (ETDEWEB)

The purpose of this document is to use existing documentation to review the effectiveness of subsurface flow and surface flow constructed wetlands in treating wastewater and to demonstrate the viability of treating effluent from Savannah River Site outfalls H-02 and H-04 with a subsurface flow constructed wetland to lower copper, lead and zinc concentrations to within National Pollutant Discharge Elimination System (NPDES) Permit limits. Constructed treatment wetlands are engineered systems that have been designed and constructed to use the natural functions of wetlands for wastewater treatment. Constructed wetlands have significantly lower total lifetime costs and often lower capital costs than conventional treatment systems. The two main types of constructed wetlands are surface flow and subsurface flow. In surface flow constructed wetlands, water flows above ground. Subsurface flow constructed wetlands are designed to keep the water level below the top of the rock or gravel media, ...

Energy Technology Data Exchange (ETDEWEB)

Energy from biomass is a CO{sub 2} neutral, sustainable form of energy. Anaerobic digestion is an established technology for converting biomass to biogas, which contains around 60% methane, besides CO{sub 2} and various contaminants. Most types of biomass contain material that cannot be digested; in woody biomass, this portion is particularly high. Therefore, conventional anaerobic digestion is not suited for the production of biogas from woody biomass. While wood is already being converted to energy by conventional thermal methods (gasification with subsequent methanation), dung, manure, and sewage sludge represent types of biomass whose energy potential remains largely untapped (present energetic use of manure in Switzerland: 0.4%). Conventional gas phase processes suffer from a low efficiency due to the high water content of the feed (enthalpy of vaporization). An alternative technology is the hydrothermal gasification: the water contained within the biomass serves as reaction ...