KoreaScience (Korea)

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International Nuclear Information System (INIS)

The heavy water reactor such as Wolsung No.1 and No.2 has a purification system to purify the reactor coolant. The control system regulates the coolant temperature to protect the ion exchanger. After the fuel exchanges of operating plant, the increase of the coolant pressure makes the purification temperature control difficult. In this paper, the controllability of the control dynamics of the purification system was analysed and the optimal parameters were proposed. To reduce the effects of the flow disturbance, the feedforward control structure was proposed and analysed.

KoreaScience (Korea)

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International Nuclear Information System (INIS)

... Figure 4. Production Flowsheets based on Purification of Yellow Cake

KoreaScience (Korea)

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Wastenet

as a by-product during the purification of molten magnesium chloride prior to its electrolysis and during the

Science.gov (United States)

... percent by interbasin ground-water flow into the Hueco Bolson, and 2 percent by flow into creeks and ... ...

International Nuclear Information System (INIS)

Short communications only.

UK PubMed Central (United Kingdom)

Methanol dehydrogenases isolated from bacteria belonging to different classes of methylotrophs contain the same prosthetic group. A procedure for its purification from whole cells is given. The reduced...Full Text Available

UK PubMed Central (United Kingdom)

We have studied the functions of the intracellular RNAs of mouse mammary tumor virus (MMTV) by purification and translation in vitro. Two major size classes of MMTV RNA, 35S and 24S RNA, were isolated...Full Text Available

UK PubMed Central (United Kingdom)

A procedure is described for the purification of the enzyme indol-3-ylacetylglucose:myo-inositol indol-3-ylacetyltransferase (IAA-myo-inositol synthase). This enzyme...Full Text Available

Science.gov (United States)

... II. Nuclear Purification Nuclear purity is achieved with the help of the treatment of commercial concentrates of uranium ("yellow cake"). ...

International Nuclear Information System (INIS)

The harmful effect of phosphate in yellow cake on the TBP purification process and its removal methods are dealed with. The reason of more uranium loss in residue was analyzed. The harmful effect of phosphate on TBP extraction efficiency and operaton of extraction column was discussed. The limit value of uranium concentration in digestion solution was presented. For TBP purification process, the presence of phosphate in yellow cake does more harm than good. (authors)

International Nuclear Information System (INIS)

Due to severe drought conditions in Pakistan over the past several years, most of the areas are facing extinction of its potable water reserves and inadequate replenishment of groundwater aquifers. Due to over exploitation, the groundwater flow dynamics is changing and water quality is degrading due to induced infiltration from polluted surface sources. Isotope hydrology is relatively a new discipline having great potential for studying various water-related problems. RIAD, PINSTECH has established analytical facilities for commonly used environmental isotopes and applied to investigate various hydrological problems. This paper briefly describes practical examples on recharge mechanism and dating of groundwater in Lahore and Ziarat areas using isotopes like deuterium (/sup 2/H), Oxygen-18 (/sup 18/O), Tritium (/sup 3/H) and CFCs in water. In Lahore, the areas having different contribution of the river Ravi in ...

Science.gov (United States)

This study is an evaluation of the potential environmental impacts of contaminated groundwater from the ASARCO metals refining facility adjacent to the ...

Energy Technology Data Exchange (ETDEWEB)

This groundwater quality report (GWQR) contains an evaluation of the groundwater quality data obtained during the 1993 calendar year (CY) at several hazardous and non-hazardous waste management facilities associated with the US DOE Y-12 Plant located on the DOE Oak Ridge Reservation (ORR) southeast of Oak Ridge, Tennessee. The groundwater quality data are presented in Part 1 of the GWQR submitted by Martin Marietta Energy Systems, Inc. to the Tennessee Department of Environment and Conservation (TDEC) in February 1994. Groundwater quality data evaluated in this report were obtained at several hazardous and non-hazardous waste management sites located within the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). The Chestnut Ridge Regime encompasses a section of Chestnut Ridge south of the Y-12 Plant and is one of three hydrogeologic regimes defined for the purposes of ...

International Nuclear Information System (INIS)

Borrelia burgdorferi sensu lato genospecies were differentiated by PCR-based sequencing of the borrelial flagellin gene. To evaluate the usefulness of KingFisher"T"M magnetic particle processor in PCR product purification, borrelia PCR products were purified with KingFisher"T"M magnetic particle processor prior to cycle sequencing and the quality of the sequence data received was analyzed. KingFisher was found to offer a rapid and reliable alternative for borrelial PCR product purification.

UK PubMed Central (United Kingdom)

A rapid and highly reproducible chromatographic technique has been developed for analysis and purification of complex mixtures of oligoribonucleotides. The method utilizes a column of microparticulate...Full Text Available

Science.gov (United States)

Reactor Effluent Purification System. 7.4.3. Filter Reactor Outlet Gas (FROG). 7.5. Instrumentation and Controls for NSS Tests ...

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Waste Management Area U (WMA U) includes the U Tank Farm, is currently regulated under RCRA interim-status regulations, and is scheduled for closure probably post-2030. Groundwater monitoring has been under an evaluation program that compared general contaminant indicator parameters from downgradient wells to background values established from upgradient wells. One of the indicator parameters, specific conductance, exceeded its background value in one downgradient well triggering a change from detection monitoring to a groundwater quality assessment program. The objective of the first phase of this assessment program is to determine whether the increased concentrations of nitrate and chromium in groundwater are from WMA U or from an upgradient source. Based on the results of the first determination, if WMA U is not the source of contamination, then the site will revert to detection monitoring. If WMA U is the source, then a ...

Energy Technology Data Exchange (ETDEWEB)

Water from small scale purification plants is a low cost alternative for consumers in comparison to the bottled commercial presentations. Because of its low cost per liter, the consumption of this product has increased in recent years, stimulating in turn the installation of purification systems for these small businesses. The purpose of this study was to estimate the efficiency of small scale purification systems located in the cities of Zacatecas and Guadalupe, Zacatecas, to reduce the radioactive content of water. It was measured the total alpha and beta activity in water samples of entry and exit to process, through the liquid scintillation technique. In general it was observed that the process is more efficient in removing alpha that beta activity. The fraction of total alpha activity removed varied between 27 and 100%, while between 0 and 77% of the total beta activity was removed by the analyzed plants. In all cases, ...

Science.gov (United States)

contaminated groundwater from the ASARCO metals refining facility ... ditch or creek crossing the ASARCO property at its northern end) and one at its ...

British Library Electronic Table of Contents (United Kingdom)

This study presents monthly estimates of groundwater anomalies in a large river basin dominated by extensive floodplains, the Negro River Basin, based on the synergistic analysis using multisatellite observations and hydrological models. For the period 2003-2004, changes in water stored in the aquifer is isolated from the total water storage measured by GRACE by removing contributions of both the surface reservoir, derived from satellite imagery and radar altimetry, and the root zone reservoir simulated by WGHM and LaD hydrological models. The groundwater anomalies show a realistic spatial pattern compared with the hydrogeological map of the basin, and similar temporal variations to local in situ groundwater observations and altimetry-derived level height measurements. Results highlight th...

UK PubMed Central (United Kingdom)

Eukaryotes may influence pollutant degradation processes in groundwater ecosystems by activities such as predation on bacteria and recycling of nutrients. Culture-independent community profiling and...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Humans are exposed to chemicals in contaminated groundwaters that are used as sources of drinking water. Chemicals contaminate groundwater resources as a result of waste disposal methods for toxic chemicals, overuse of agricultural chemicals, and leakage of chemicals into the subsurface from buried tanks used to hold fluid chemicals and fuels. In the process, both the solid portions of the subsurface and the groundwaters that flow through these porous structures have become contaminated. Restoring these aquifers and minimizing human exposure to the parent chemicals and their degradation products will require the identification of suitable biomarkers of human exposure; better understandings of how exposure can be related to disease outcome; better understandings of mechanisms of transport of pollutants in the heterogeneous structures of the subsurface; and field testing and evaluation of methods proposed to restore and ...

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To monitor the groundwater contamination and the effectiveness of remedial actions, over a thousand monitoring wells are in active operation (i.e., require quarterly or semi-annual sampling) at SRS. Most wells are expected to continue in operation for another 20 to 40 more years. Required sample volumes can range from a less than a liter to 10 liters. To support the long-term groundwater monitoring requirements of these wells, SRS actively seeks technologies that can maximize data acquisition and minimize costs. To meet this end, SRS has implemented the Purge Water Management System (PWMS). The key attributes of this system lie in its ability to reduce or eliminate the generation of purged groundwater, which is costly in terms of the time and management.

Energy Technology Data Exchange (ETDEWEB)

This report summarizes the Groundwater Monitoring Program conducted by the Savannah River site during fourth quarter 1999. It includes the analytical data, field data, data review, quality control, and other documentation for this program; provides a record of the program's activities; and serves as an official records of the analytical results.

Energy Technology Data Exchange (ETDEWEB)

Purification parameters of the vacuum distillation process for AM50A and AZ31B magnesium alloy were studied. The vacuum distillation tests were kept at 580 C to 620 C up to 10 h under a vacuum pressure of about 1 Pa. The purification ratio for AM50A magnesium alloy increases with increasing the purification time. The chemical compositions of materials deposited purifying at 580 C for AM50A magnesium alloy almost satisfy the values for pure magnesium specified by JIS standard specification. The chemical compositions of deposited materials at 600 C for AZ31B magnesium alloy satisfy the values specified by the standard specification except for Zn. (orig.)

UK PubMed Central (United Kingdom)

We have synthesized a novel stable precursor, saligenin phosphorotrichloridate, which, on reaction with N-monobiotinyldiamines, generates a series of biotinylated covalent inhibitors of serine esterases....Full Text Available

UK PubMed Central (United Kingdom)

The chloroplast and cytoplasmic isoenzymes of phosphoglycerate kinase (PGK) (EC. 2.7.2.3) from Hordeum vulgare leaves have been separated and purified for the first time to apparent...Full Text Available

UK PubMed Central (United Kingdom)

Phospho-beta-galactosidase (P-beta-gal), the enzyme which catalyzes the first step in the metabolism of intracellular lactose phosphate, occurred at high specific activity in the cytoplasm in 12 of...Full Text Available

UK PubMed Central (United Kingdom)

mRNA guanylyltransferase has been extensively purified from calf thymus. A GTP-binding assay was used based on the observations by Shuman and Hurwitz (1981) and Venkatesan and Moss (1982) that vaccinia...Full Text Available

UK PubMed Central (United Kingdom)

1. The penicillinases formed by penicillinase-constitutive mutant strains from two closely related varieties (749 and 6346) of Bacillus licheniformis have been isolated, characterized...Full Text Available

Science.gov (United States)

We recently found that many RNA polymerase II transcription factors are modified with N-acetylglucosamine residues. These sugar moieties confer upon transcription factors an ability to bind the lectin wheat germ agglutinin. We have taken advantage of this interaction to devise a purification procedure for the "GC-box" binding transcription factor Sp1. Crude nuclear extracts are first subjected to wheat germ agglutinin affinity chromatography and then subjected to sequence-specific DNA affinity chromatography. The Sp1 protein purified by this procedure is at least 95% pure, and the overall recovery is greater than 80%. In addition to yielding larger quantities of Sp1 than conventional schemes, the new purification procedure is also simpler and more rapid. We show that wheat germ agglutinin affinity chromatography can also be used to purify the glycosylated forms of the CCAAT-binding transcription factor. Thus, wheat germ agglutinin affinity ...

UK PubMed Central (United Kingdom)

A Monascus pilosus strain was selected for production of intracellular α-galactosidase. Optimum conditions for mycelial growth and enzyme induction were determined. Galactose...Full Text Available

UK PubMed Central (United Kingdom)

The clotting activity of Staphylococcus aureus strain 104 was purified 46,000-fold, but absolute purity was not achieved. Carbohydrate content of the purified material was not more than 5%. Elution...Full Text Available

UK PubMed Central (United Kingdom)

Organisms in the genus Mycobacterium cause a variety of human diseases. One member of the genus, M. ulcerans, causes a necrotizing skin disease called Buruli ulcer....Full Text Available

UK PubMed Central (United Kingdom)

Basal segments taken from Old Home and Bartlett pear hardwood cuttings collected at intervals during the rooting period in September were extracted with ethanol and fractionated by paper chromatography...Full Text Available

UK PubMed Central (United Kingdom)

Glandular trichomes of the wild tomato species Lycopersicon pennellii secrete 2,3,4-O-tri-acyl-glucose (-Glc), which contributes to insect resistance. A Glc acyltransferase...Full Text Available

UK PubMed Central (United Kingdom)

The functional and thermodynamic characteristics of the ubiquinolcytochrome (Cyt) c oxidoreductase in a Cyt b/c₁-enriched fraction (defined...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

Biodiesel is derived from triacylglycerides and is produced primarily through transesterification, a chemical reaction of vegetable oils with alcohol, methanol or ethanol. The cost of raw material should be considered since 85 per cent of production cost is related to vegetable oil. The purpose of this study was to evaluate oil expression of sunflower seed. It also examined the sunflower crude oil as a raw material for biodiesel by transesterification in both laboratory and pilot scale studies. Three different biodiesel purification methods were examined. The best result for oil expelling (68.4 per cent) at the experimental stage was obtained for seeds with a moisture content of 6.9 per cent at 25 degrees C and at a screw speed of 114 rpm. For biodiesel production at the laboratory scale, the best result for oil expelling was 87.5 per cent. It was obtained with an ethanol:oil molar ratio of 4.7:1 and with a 4.42 per cent catalyst concentration related to the ...

UK PubMed Central (United Kingdom)

Teleost gut associated lymphoid tissue (GALT) consists of leucocyte populations located both intraepithelially and in the lamina propria with no structural organization. The present study aims to assess...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

We prove that the 1984 protocol of Bennett and Brassard (BB84) for quantum key distribution is secure. We first give a key distribution protocol based on entanglement purification, which can be proven secure using methods from Lo and Chau's proof of security for a similar protocol. We then show that the security of this protocol implies the security of BB84. The entanglement purification based protocol uses Calderbank-Shor-Steane codes, and properties of these codes are used to remove the use of quantum computation from the Lo-Chau protocol. (c) 2000 The American Physical Society.

Energy Technology Data Exchange (ETDEWEB)

Methods and apparatus are described for efficient photodetachment and purification of negative ion beams. A method of purifying an ion beam includes: inputting the ion beam into a gas-filled multipole ion guide, the ion beam including a plurality of ions; increasing a laser-ion interaction time by collisional cooling the plurality of ions using the gas-filled multipole ion guide, the plurality of ions including at least one contaminant; and suppressing the at least one contaminant by selectively removing the at least one contaminant from the ion beam by electron photodetaching at least a portion of the at least one contaminant using a laser beam.

British Library Electronic Table of Contents (United Kingdom)

The study investigates the possibility of enhancing crop water productivity in the parts of Northwest India where groundwater quality is marginal and canal water supply is severely scarce. Soil, Water, Atmosphere and Plant (SWAP) model was calibrated and validated in three farmers' fields with varying canal water availability and groundwater quality in the Kaithal Irrigation Circle of the Bhakra Canal system, Haryana. On the basis of predicted and observed soil water content, pressure heads, salt concentration at 2 week intervals and crop yields, the model was found suitable for use in the region. A few nomographs were prepared to provide a graphical method to predict the effect of different combinations of water quality and depth of water application on crop yield and soil salinity and to...

Energy Technology Data Exchange (ETDEWEB)

In situ treatment has been proposed as a remediation alternative for surface water and groundwater contaminated with uranium and nitrate as a result of former waste disposal practices in the S-3 Ponds. Interceptor trenches containing reactive media have been proposed to treat groundwater, and constructed wetlands and/or algal mats are potential alternatives for treating surface water. This report presents the results from testing of ten different reactive media, and combinations of media, that are candidates for use in the proposed interceptor trenches to remove uranium and nitrate from groundwater. It also presents the results of testing and evaluation of algal mats and wetlands for removing uranium and nitrate from surface water.

Energy Technology Data Exchange (ETDEWEB)

This document, which is prepared as directed by the Compliance Order on Consent (COOC) issued by the New Mexico Environment Department, identifies and outlines a process to evaluate remedial alternatives to identify a corrective measure for the Sandia National Laboratories New Mexico Technical Area (TA)-V Groundwater. The COOC provides guidance for implementation of a Corrective Measures Evaluation (CME) for the TA-V Groundwater. This Work Plan documents an initial screening of remedial technologies and presents a list of possible remedial alternatives for those technologies that passed the screening. This Work Plan outlines the methods for evaluating these remedial alternatives and describes possible site-specific evaluation activities necessary to estimate remedy effectiveness and cost. These methods will be reported in the CME Report. This Work Plan outlines the CME Report, including key components and a description of the corrective ...

International Nuclear Information System (INIS)

There are several methods of generating OH free radicals from ozone and/or hydrogen peroxide and ultraviolet light. They all have in common that the OH free radicals originate in one single source only whereas in the combination of ozone with ionizing radiation two simultaneous working sources for the OH free radicals exist. The resulting higher OH free radical concentration makes this process especially apt for the remediation of low level contaminated groundwater as for example trichloroethylene (TCE) contamination in the sub-ppm range. A cost comparison between O_3/UV and O_3/electron beam for remediation of a groundwater contaminated with 100 ppb TCE indicated that for a throughput of about 5 million gallons/day the O_3/electron beam process is more cost-effective. (authors).

Energy Technology Data Exchange (ETDEWEB)

This report describes modelling where the hydrological modelling system MIKE SHE has been used to describe surface hydrology, near-surface hydrogeology, advective transport mechanisms, and the contact between groundwater and surface water within the SKB site investigation area at Laxemar. In the MIKE SHE system, surface water flow is described with the one-dimensional modelling tool MIKE 11, which is fully and dynamically integrated with the groundwater flow module in MIKE SHE. In early 2008, a supplementary data set will be available and a process of updating, rebuilding and calibrating the MIKE SHE model based on this data set will start. Before the calibration on the new data begins, it is important to gather as much knowledge as possible on calibration methods, and to identify critical calibration parameters and areas within the model that require special attention. In this project, the MIKE SHE model has been further developed. The model ...

International Nuclear Information System (INIS)

This study evaluates the degree to which surface impoundments at licensed facilities comply with significant changes in NRC requirements initiated by enactment of EPA's final environmental standards for uranium recovery facilities (40 CFR Part 192). Impoundment liner requirements, ground-water protection standards, ground-water monitoring and corrective action programs, and site closure standards are the most significant regulatory modifications. The compliance status of 30 conventional mills and 31 in-situ mines is determined from a review of Nuclear Regulatory Commission and agreement state docket files through November, 1983. Results of this review show that a majority of conventional uranium mill tailings management systems are deficient with respect to liner requirements for new impoundments or proposed expansions to existing impoundments, as well as with respect to some aspects of ground-water monitoring and ...

Energy Technology Data Exchange (ETDEWEB)

The purpose of the piezometer network is to establish baseline hydraulic head data for the water table aquifer at the F- and H-Area seeplines prior to startup of the groundwater extraction/injection remediation system.

Energy Technology Data Exchange (ETDEWEB)

In an effort to develop cost-efficient techniques for remediating uranium contaminated groundwater at DOE Uranium Mill Tailing Remedial Action (UMTRA) sites nationwide, Sandia National Laboratories (SNL) deployed a pilot scale research project at an UMTRA site in Durango, CO. Implementation included design, construction, and subsequent monitoring of an in situ passive reactive barrier to remove Uranium from the tailings pile effluent. A reactive subsurface barrier is produced by emplacing a reactant material (in this experiment various forms of metallic iron) in the flow path of the contaminated groundwater. Conceptually the iron media reduces and/or adsorbs uranium in situ to acceptable regulatory levels. In addition, other metals such as Se, Mo, and As have been removed by the reductive/adsorptive process. The primary objective of the experiment was to eliminate the need for surface treatment of tailing pile effluent. Experimental design, and ...

UK PubMed Central (United Kingdom)

During the summer of 2003, a gastroenteritis outbreak spread throughout a holiday resort in central Italy. Fecally contaminated groundwater and seawater were leaking into the non–drinking-water...Full Text Available

UK PubMed Central (United Kingdom)

BackgroundTrichloroethylene (TCE) is a suspected human carcinogen and a common ground-water contaminant. Chloral hydrate (CH) is the major metabolite of TCE formed in the liver by...Full Text Available

Science.gov (United States)

This report is a compilation of the groundwater sampling results from the Area 5 Radioactive Waste Management Site (RWMS) for calendar year 2006. Pilot wells UE5PW-1, UE5PW-2, and UE5PW-3 were sampled in April and October 2006 for the following indicators of contamination: pH, specific conductance, total organic carbon, total organic halides, and tritium. Indicators of general water chemistry (cations and anions) were also monitored. Results from all samples collected in 2006 were within the limits established by agreement with the Nevada Division of Environmental Protection for each analyte. These data indicate that there has been no measurable impact to the uppermost aquifer from the Area 5 RWMS. There were no significant changes in measured groundwater parameters compared to previous years. Other information in the report includes an updated Cumulative Chronology for the Area 5 RWMS Groundwater Monitoring Program and a ...

Energy Technology Data Exchange (ETDEWEB)

Volume VI of the documentation for the Phase I Data Analysis Task performed in support of the current Regional Flow Model, Transport Model, and Risk Assessment for the Nevada Test Site Underground Test Area Subproject contains the groundwater flow model data. Because of the size and complexity of the model area, a considerable quantity of data was collected and analyzed in support of the modeling efforts. The data analysis task was consequently broken into eight subtasks, and descriptions of each subtask's activities are contained in one of the eight volumes that comprise the Phase I Data Analysis Documentation.

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Yucca Mountain, Nevada is a potential site for a high-level radioactive-waste repository. Uncertainty and sensitivity analyses were performed to estimate critical factors in the performance of the site with respect to a criterion in terms of pre-waste-emplacement ground-water travel time. The degree of failure in the analytical model to meet the criterion is sensitive to the estimate of fracture porosity in the upper welded unit of the problem domain. Fracture porosity is derived from a number of more fundamental measurements including fracture frequency, fracture orientation, and the moisture-retention characteristic inferred for the fracture domain.

Energy Technology Data Exchange (ETDEWEB)

In France, groundwater usage represents 40 per cent of volumetric use, outside of thermal power plants. Groundwater represents 60 per cent of domestic and public use, 40 per cent in the industrial sector, and is increasing in the agricultural sector where it accounts for 20 per cent. Groundwater withdrawal in France has slightly increased over the last twenty years and benefited the agricultural sector. Availability throughout the territory, the consistency of resupply and natural quality has rendered groundwater a prevailing source for drinking water. Water protection and management is important and led to the adoption of legislative and regulatory measures. The Mining Code (Code minier) allows for exploitation of underground resources starting at 10 metres. The Rural Code (Code rural) mandates the declaration of public utility for water collection for the public. Protection areas are to be provided ...

International Nuclear Information System (INIS)

A simple and rapid procedure was developed for the purification of cyclotron-produced "2"0"3Pb via the "2"0"3Tl(d,2n) "2"0"3Pb reaction. A Pb(II) selective ion-exchange resin, with commercial name Pb Resin from Eichrom Technologies, Inc., was used to purify "2"0"3Pb from the cyclotron-irradiated Tl target with excellent recovery of the enriched Tl target material. The purified "2"0"3Pb was used to radiolabel the monoclonal antibody Herceptin. The in vitro and in vivo properties of the "2"0"3Pb radioimmunoconjugate were evaluated.

British Library Electronic Table of Contents (United Kingdom)

We have developed a process for chemical purification of carbon nanotubes for solution-processable thin-film transistors (TFTs) having high mobility. Films of the purified carbon nanotubes fabricated by simple drop coating showed carrier mobilities as high as 164 cm2V?1s?1, normalized transconductances of 0.78 Sm?1, and on/off current ratios of 106. Such high performance requires the preparation of a suspension of micrometer-long and highly purified semiconducting single-walled carbon nanotubes (SWCNTs). Our purification process includes length and electronic-type selective trapping of SWCNTs using recycling gel filtration with a mixture of surfactants. The results provide an important milestone toward printed high-speed and large-area electronics with roll-to-roll and ink-jet device fabri...

British Library Electronic Table of Contents (United Kingdom)

Waste cooking oil can be recovered and processed into animal feed additives after purification. Unfortunately, the traditional purification processes are insufficient for the removal of the harmful compounds formed during frying, mainly about malondialdehyde and other 2-thiobarbituric acid reactive substances. In the present paper, firstly, a simple and reliable HPLC method was developed to measure the content of malondialdehyde in purified waste cooking oil. The detection limit and the standard recovery of the analysis method are 1.20x10-5gl-1 and 96.5-99.2%, respectively, which is accurate and valid enough for the detection of malondialdehyde in waste cooking oil. Furthermore, the removal of malondialdehyde and other 2-thiobarbituric acid reactive substances from waste cooking oil was in...

British Library Electronic Table of Contents (United Kingdom)

Phycocyanin - a major phycobiliprotein constitutively produced by many cyanobacteria hold several promising applications in diagnostics, biomedical research, and therapeutics. This paper discusses a novel rapid method for the purification of cyanobacterial phycocyanin (C-PC) from Phormidium fragile using hydrophobic interaction chromatography. The protein was extracted and concentrated by grinding under liquid nitrogen and ammonium sulfate fractionation. C-PC was purified by single step hydrophobic interaction chromatography. Purified phycocyanin showed absorbance maximum (lmax) at 624nm. The criterion of purity (R) achieved was 4.52. Phycocyanin to phycoerythrin and phycocyanin to allophycocyanin purity ratio were 3.85 and 7.49, respectively. The purified protein showed a pI of 5.2 and ha...

Energy Technology Data Exchange (ETDEWEB)

This report is a compilation of the calendar year 2003 groundwater sampling results from the Area 5 Radioactive Waste Management Site, Nevada Test Site. Wells Ue5PW-1, Ue5PW-2, and Ue5PW-3 were sampled semi-annually for the required analytes: pH, specific conductance, total organic carbon (TOC), total organic halides (TOX), tritium, and major cations/anions. Results from all samples collected in 2003 were within established criteria. These data indicate that there has been no measurable impact to the uppermost aquifer from the Resource Conservation and Recovery Act (RCRA) regulated unit within the Area 5 Radioactive Waste Management Site and confirm that any previous detections of TOC and TOX were false positives. Contamination indicator data are presented in control chart and tabular form with investigation levels indicated. Gross water chemistry data are presented in graphical and tabular form. There were no major changes noted in the monitored ...

Energy Technology Data Exchange (ETDEWEB)

Lectures were held on forest and wood management, the forest as an energy source and the emission problem of wood combustion, future emission limitating regulations for wood firing, influence of firing technique on air pollution abatement and constructive and operational air pollution abatement measures with manually and continuously fuelled furnaces.

International Nuclear Information System (INIS)

Crude N,N-dialkylcarbamoylmethylphosphonates and phosphine oxide extractants, and particularly crude dihexyl N,N-diethylcarbamoylmethylphosphonate and octylphenyl N,N-diisobutylcarbamoyl phosphine oxide, are purified by distilling the crude materials in a thin film evaporator. Preferably, the crude materials are reacted with concentrated hydrochloric acid and then with aqueous sodium hydroxide prior to distillation in the thin film evaporator to hydrolyze impurities contained in them. The purified extractants are useful for extracting actinides and lanthanides from liquid waste streams. (author).

UK PubMed Central (United Kingdom)

A new sugarcane (Saccharum officinarum L.) fructanase which hydrolyzes both high molecular weight polysaccharides ∣Fructose₄:Galactitol₅∣_n...Full Text Available

Science.gov (United States)

The thermostable Thermus aquaticus DNA polymerase (Taq Pol) has been the key factor in transforming the initial PCR method into one with huge impact in molecular biology and biotechnology. Therefore, the development of effective affinity adsorbents for the purification of Taq Pol, as well as other DNA polymerases, attracts the attention of the enzyme manufacturers and the research laboratories. In this report we describe a simple protocol for the purification of Taq Pol from E. coli lysates, leading to enzymes of high specific activity and purity. The protocol is based on a single affinity chromatography step, featuring an immobilized ligand selected from a structure-biased combinatorial library of dNTP-mimetic synthetic ligands. The ligand library was screened for its ability to bind and purify Taq Pol from E. coli lysates. One immobilized ligand (mABSGu) of the general formula X-Trz-Y, bearing 9-aminoethylguanine (AEGu) and aniline-2-sulfonic ...

Energy Technology Data Exchange (ETDEWEB)

The use of filters of activated-charcoal particles in drinking-water purification plants assists in the elimination of organic micropollutant substances. The authors report on a study which sought to investigate the mechanism of organic matter; they describe the experimental programme, which used different size ranges of mineral-based activated charcoal, present the experimental findings and discuss the results. 16 references.

Energy Technology Data Exchange (ETDEWEB)

Conversion of coal gas into liquid products is a multistep process which involves numerous unit processes. Compared with similar processes using natural gas as feedstock, there are challenges, particularly with the gas purification. There are, however, also advantages when using a carbon-monoxide-rich gas which ultimately may result in a greatly simplified process. This paper discusses the challenges when converting a gas from an entrained coal gasifier into a liquid product and the paper presents the various options available. The following issues will be touched upon: sour gas shift and adjustment of the H{sub 2}/CO ratio; acid Gas Removal (AGR) - when and how; syngas purification; methanol and combined methanol/DME synthesis; gasoline synthesis; future integrated processes. Here, various options are available depending on the gasifier; not only dry or slurry feed but also the question of quench as well as the selected scrubbing temperature ...

Energy Technology Data Exchange (ETDEWEB)

Discussion is presented of world CO{sub 2} emissions and the effect rising population and population distribution has on this. Possible ways of decreasing emissions are presented, including potential for heat recovery, exhaust-air purification as an energy supply, shared power supply in industry, the use of cogeneration, and multiple use of heat in industry. 9 refs., 10 figs., 3 tabs.

International Nuclear Information System (INIS)

[5'-"3H]-3'-Azido-3'-deoxythymidine (3) was prepared at a specific activity of 14.0 Ci/mmol by a two-step synthetic sequence involving controlled oxidation of the unlabelled compound (1) to the 5'-aldehyde (2) followed by reduction with ["3H]-NaBH_4. Purification was performed by preparative TLC. The radiochemical purity was 99.2%. (author).

Energy Technology Data Exchange (ETDEWEB)

In accordance with the Nuclear Regulatory Commission regulation regarding groundwater travel times at geologic repositories, various models of unsaturated flow in fractured tuff have been developed and implemented to assess groundwater travel times at the potential repository at Yucca Mountain, Nevada. Kaplan used one-dimensional models to describe the uncertainty and sensitivity of travel times to various processes at Yucca Mountain. Robey and Arnold et al. used a two-dimensional equivalent continuum model (ECM) with inter- and intra-unit heterogeneity in an attempt to assess fast-flow paths through the unsaturated, fractured tuff at Yucca Mountain (GWTT-94). However, significant flow through the fractures in previous models was not simulated due to the characteristics of the ECM, which requires the matrix to be nearly saturated before flow through the fractures is initiated. In the current study (GWTT-95), four two-dimensional cross-sections ...

Energy Technology Data Exchange (ETDEWEB)

A series of experiments involving high explosives and radioactive materials were conducted at Los Alamos, New Mexico, primarily to understand certain safety aspects of operational nuclear weapons. The experiments were conducted underground in large diameter holes as deep as 120 ft. The location was selected because it had geologic and hydrologic characteristics that assured complete containment of the experiments and precluded any possible contamination of groundwater. Important features verified by the USGS included the absence of any recharge and about 1200 feet of dry rock above the groundwater aquifer. Residual materials dispersed by detonation of the high explosives remain at the bottom of the experimental holes. The materials of significance from an environmental standpoint include about 40 kg of plutonium, 93 kg of enriched uranium, at least 82 kg of depleted uranium, 13 kg of beryllium, and an undetermined amount of lead. Environmental ...

British Library Electronic Table of Contents (United Kingdom)

Water?rock interaction is one of the prime factors affecting the fluoride contents of surface and groundwater. If fluoride concentration of drinking water has been neglected, excess fluoride can cause serious dental and medical problems on human health, which is well known at Golcuk-Isparta region. In the research area, Egirdir lake, Golcuk lake and surrounding springs have been utilized as drinking water sources. Golcuk lake water and surrounding groundwaters have high fluoride content (1.4?4.6?mg/l), which is above the WHO standards. Fluoride is predominantly supplied by dissolution of fluoride within the fluormicas of volcanics during the circulation of water. Fluoride concentrations of waters have shown variations for dry and rainy seasons depending on the degree of interaction between...

Energy Technology Data Exchange (ETDEWEB)

Ground-water monitoring near the Raft River site was initiated in 1974 by the IDWR. This effort consisted of semiannual chemical sampling of 22 irrigation wells near the Raft River geothermal development area. This program yielded useful baseline chemical data; however, several problems were inherent. For example, access to water pumped from the wells is limited to the irrigation season (April through September). All the wells are not continuously pumped; thus, some wells that are sampled one season cannot be sampled the next. In addition, information on well construction, completion, and production is often unreliable or not available. These data are to be supplemented by establishing a series of monitor wells in the proposed geothermal withdrawal and injection area. These wells were to be located and designed to provide data necessary for evaluating and predicting the impact of geothermal development on the Shallow Aquifer system.

Energy Technology Data Exchange (ETDEWEB)

This report presents the results of an experimental programme to determine the mass transfer and sorptive properties of selected glacial sand and clays from the Drigg Disposal Site operated by British Nuclear Fuels plc. The hydraulic conductivity of both the sand and clay has been determined and the sensitivity of this parameter to changing water chemistry investigated. The hydrodynamic dispersion properties of the glacial sand were measured in order to aid the interpretation of column sorption experiments. The sorption of strontium and uranium from groundwater onto clay and sand samples has been studied using through-diffusion, column and batch techniques. Employing the batch technique, the effect of a series of humic acid concentrations on distribution ratios for uranium and plutonium has also been investigated. Groundwater and trench leachate were used with both clay and sand. (author).

Energy Technology Data Exchange (ETDEWEB)

A plant for the fixation of high-level wastes in borosilicate glass has been operating in France since 1978. A large plant is under construction in the U.S. for the fixation of defence high-level waste and plans for other glass fixation plants are well advanced at several sites around the world. Among the reasons for the selection of borosilicate glass as a fixation medium are the relative ease of processing wastes of variable composition by means of well established technology, and the long-term radiation and thermal stability of the glass. Well formulated glass also has sufficient resistance to the action of groundwater so that it can serve as an important barrier against the spread of radionuclides via groundwater in any forseeable situation. Research is continuing to quantify the reactions of waste glass in site-specific geological repository environments.

British Library Electronic Table of Contents (United Kingdom)

Abstract The aim of this study is to study the effects of Boron (B) pollution in Buyuk Menderes river on planted crops and agricultural areas constructed in the irrigation schemes by the State Hydraulic Works (DSI) of the Lower Buyuk Menderes basin, Turkey. The studied irrigation schemes in the basin are Saraykoy, Pamukkale, Nazilli, Aydin, Sultanhisar, Koarli, and Soke. Mean B concentrations of river water used in the irrigation schemes ranged from 0.10 to 0.43 mgB L-1 for the period of 2008 to 2009. A total of 100,556 ha of the agricultural area and the basin groundwater resources are under the influence of B pollution from the Buyuk Menderes river. The amount of B accumulating in soils and seepage in the groundwater due to the used irrigation water was 18,495,350 and 9153 kgB yr-1, resp...

International Nuclear Information System (INIS)

The combination of zero-valent iron (Fe0) and iron oxide-coated sand (IOCS) was used to remove Cr(VI) and As(V) from groundwater in this study. The efficiency and the removal mechanism of Cr(VI) and As(V) by using this combination, with the influence of humic acid (HA), were investigated using batch experiments. Results showed that, compared to using Fe0 or IOCS alone, the Fe0-IOCS can perform better on the removal of both Cr(VI) and As(V). Metal extraction studies showed that As(V) was mainly removed by IOCS and iron corrosion products while Cr(VI) was mainly removed by Fe0 and its corrosion products. Competition was found between Cr(VI) and As(V) for the adsorption sites on the iron corrosion products. HA had shown insignificant effects on Cr(VI) removal but some effects on As(V) removal kinetics. As(V) was adsorbed on IOCS at the earlier stage, but adsorbed/coprecipitated with the iron corrosion products at the later stage. - Research Highlights: ? Fe0-IOCS is ...

Energy Technology Data Exchange (ETDEWEB)

This conference provided a forum for more than 500 delegates from industry, government universities and research centres to share their professional knowledge on research and development that affects all sectors of geotechnical engineering, applied geology and hydrogeology. Accomplishments in the geoenvironmental field were also highlighted. The geotechnical sessions were entitled: pile foundations and load testing; excavations and special foundation issues; reinforced soil and soil-structure interactions; advances in modelling, constitutive issues; advances in modelling, consolidation and other applications; advances in modelling, discrete elements and slope stability; embankments and dams; landfills and barriers; fundamental soil mechanics; soil mechanics and ground movement; GIS and remote sensing; landslides and slopes; cone penetration tests and liquefaction assessment; rock mechanics; engineering geology; geoenvironmental sustainability; oilsand and petroleum geomechanics; and, ...

Science.gov (United States)

This report is a compilation of the groundwater sampling results from three monitoring wells located near the Area 5 Radioactive Waste Management Site (RWMS) at the Nevada Test Site (NTS), Nye County, Nevada, for calendar year 2007. The NTS is an approximately 3,561 square kilometer (1,375 square mile) restricted-access federal installation located approximately 105 kilometers (65 miles) northwest of Las Vegas, Nevada (Figure 1). Pilot wells UE5PW-1, UE5PW-2, and UE5PW-3 are used to monitor the groundwater at the Area 5 RWMS (Figure 2). In addition to groundwater monitoring results, this report includes information regarding site hydrogeology, well construction, sample collection, and meteorological data measured at the Area 5 RWMS. The disposal of low-level radioactive waste and mixed low-level radioactive waste at the Area 5 RWMS is regulated by U.S. Department of Energy (DOE) Order 435.1, 'Radioactive Waste ...

Energy Technology Data Exchange (ETDEWEB)

Chemical oxidation is a treatment technology that uses powertul chemical oxidizers to destroy organic contaminants. Typical oxidizers used in chemical oxidation processes include ozone, hydrogen peroxide, chlorine, and potassium permanganate. The chemical reaction products are usually simple organic compounds, such as carboxylic acids, and/or inorganic compounds, such as carbon dioxide, water, and simple inorganic complexes (e.g., chloride salts, in the case of chemical oxidation treatment of chlorinated solvents).

Energy Technology Data Exchange (ETDEWEB)

The proposed design for a final repository for spent fuel and other long-lived residues in Sweden is based on the multi-barrier principle. The waste will be encapsulated in sealed cylindrical canisters, which will then be placed in granite bedrock and surrounded by compacted bentonite clay. The canister design is based on a thick cast inner container fitted inside a corrosion-resistant copper canister. During fabrication of the outer copper canisters there will be some unavoidable grain growth in the welded areas. As grains grow they will tend to concentrate impurities within the copper at the new grain boundaries. The work described in this report was undertaken to determine whether there is any possibility of enhanced corrosion at grain boundaries within the copper canister. The potential for grain boundary corrosion was investigated by exposing copper specimens, which had undergone different heat treatments and hence had different grain sizes, to aerated artificial ...

Environmental Research Database

DescriptionProgramme background Nanotechnology is the design and manufacture of substances typically between one and several hundred billionths of a metre in size. In this size range the properties of substances can change quite radically, offering potentially large socio-economic, health and environmental benefits. For example, nanofuel additives could help reduce emissions and particles from diesel engines. Nanoparticles may also be able to help remove persistent pollutants in soils and groundwaters. Th [continued...

Energy Technology Data Exchange (ETDEWEB)

An examination of chemical and radiological characteristics of RI organic liquid waste, wet oxidation by Fenton reaction and decomposition liquid waste treatment process were studied. These items will be applied to develop the equipment of wet oxidation and decomposition liquid waste treatment mixed processes for the safe treatment of RI organic liquid waste which is consisted of organic solvents such as toluene, alcohol and acetone. Two types of toluene solutions were selected as a candidate decomposition material. As for the first type, the concentration of toluene was above 20 vol percent. As for the second type, the solubility of toluene was considered. The decomposition ration by Fenton reaction was above 95 percent for both of them. From the adsorption equilibrium tests, a -Na{sup +} substituted/acid treated activated carbon and Zeocarbon mixed adsorbent was selected for the fixed adsorption column. This mixed adsorbent will be used to obtain the basic design data of liquid waste ...

Energy Technology Data Exchange (ETDEWEB)

The {sup 176}Ybn,{gamma}{sup 177}Yb-{beta}{sup -}{yields}{sup 177}Lu process was investigated to provide no-carrier-added (nca) {sup 177}Lu. The radiochemical separation of the {sup 177}Lu from the macro-amounts of the ytterbium target based on the cementation process, i.e. the selective extraction of Yb by Na(Hg) amalgam from Cl{sup -}/CH{sub 3}COO{sup -} electrolytes, followed by a final cation exchange purification. The cementation separation process provides a decontamination factor of Yb(III) of 10{sup 4}, the cation exchange purification adding a decontamination factor of >10{sup 2}. The nca {sup 177}Lu is available in radiochemically pure form despite the chemical similarity of the lanthanides with 75{+-}5% overall separation yield within 4-5 h. It can be used to synthesise nca {sup 177}Lu labelled radiotherapeuticals.

Energy Technology Data Exchange (ETDEWEB)

This R and D project is planed to supply domestic demands of Mo-99 through fission route, and consequently this project will be expected to rise up utilization of HANARO and KAERI's capability for marketing extension into domestic and oversea radiopharmaceutical market. HEU and LEU target types are decided and designed for fission Mo-99 production in domestic. Experimental study of target fabrication technology was performed and developed processing equipments. And conceptual design of target loading/unloading in/from HANARO device are performed. Tracer test of Mo-99 separation and purification process was performed, test results reach to Mo-99 recovery yield above 80% and decontamination factor above 1600. Combined Mo-99 separation and purification process was decided for hot test scheduled from next year, and performance test was performed. Conceptual design for modification of existing hot cell for fission Mo-99 production facility ...

Energy Technology Data Exchange (ETDEWEB)

The industrial standard process for the purification of natural gas is to remove acid gases, mainly hydrogen sulfide and carbon dioxide, by the absorption and reaction of these gases with alkanolamines. Inadequate data for vapor -- liquid equilibrium (VLE) hinder the industry from converting operations to more energy efficient amine mixtures and conserving energy. Some energy reductions have been realized in the past decade by applying such amine systems as ``hindered`` amines, methyldiethanolamine (MDEA), and MDEA based amine mixtures. However, the lack of reliable and accurate fundamental VLE data impedes the commercial application of these more efficient alkanolamine systems. The first project objective is to improve the accuracy of vapor -- liquid equilibrium measurements at low hydrogen sulfide concentrations. The second project objective is to measure the VLE for amine mixtures. By improving the accuracy of the VLE measurements on MDEA and mixtures with other ...

Energy Technology Data Exchange (ETDEWEB)

The merits of single stage absorption heat pumps coupled to simple distillation for effluent treatment are discussed. An experimental integrated absorption heat pump effluent purification system (IAHPEPS) was built and operated with water-lithium bromide as a working mixture. This unit has been used to raise the temperature and hence, the vapour pressure of the impure water contained in one vessel, to the point where pure water vapour will distil from impure effluent solution (tap water or brine) and condense in a second vessel used to collect pure water. Pure effluent production rates of between 0.5 and 4.3 kg h{sup -1} were obtained. The actual coefficient of performance (COP{sub A}) and the heat pump effectiveness varied from 1.1 to 1.4 and 0.58 to 0.72, respectively. The results from the small scale systems indicate the likely results from industrial scale units which could be operated with low quality heat such as waste heat, solar or geothermal resources. ...

Energy Technology Data Exchange (ETDEWEB)

Passage of neon gas through activated charcoal is planned to be the primary method of removing impurities from the liquid neon scintillator in the CLEAN experiment. In order to quantify this technique, the breakout curves for hydrogen, nitrogen, argon and krypton impurities in neon-saturated activated charcoal were measured. Adsorption coefficients and the number of theoretical stages were measured for hydrogen in the temperature range between 300 and 80 K, nitrogen between 300 and 200 K, and argon between 300 and 190 K. The adsorption coefficient for krypton was measured at 300 K.

International Nuclear Information System (INIS)

The paper presents results of measurements of the natural radioactivity of tap water where samples were taken in front of, and behind the ceramic filter commonly used in houses for the purification of tap water. Altogether, 289 samples were taken, processed and measured during 1985-1986 in Kuwait. Results reveal the fact that ceramic filters reduce substantially the natural radioactivity in water (the 'gross' alpha activity reduced by the factor 2.18 #+-# 18%; the 'gross' beta by 1.53 #+-# 1.6%. (author).

International Nuclear Information System (INIS)

The main activities developed at 'Instituto de Energia Atomica' Sao Paulo, Brazil, on the recovery of uranium from ores, the purification of uranium and thorium raw concentrates and their transformation in nuclear grade compounds, are reviewed. The design and assemble of pilot facilities for ammonium diuranate (ADV) uranium tetrafluoride, uranium trioxide, uranium oxide microspheres, uranyl nitrate denitration, uranim hexafluoride and thorium compounds are discussed. The establishment of analytical procedures are emphasized.

International Nuclear Information System (INIS)

We present a simple protocol to purify a coherent-state superposition that has undergone a linear lossy channel. The scheme constitutes only a single beam splitter and a homodyne detector, and thus is experimentally feasible. In practice, a superposition of coherent states is transformed into a classical mixture of coherent states by linear loss, which is usually the dominant decoherence mechanism in optical systems. We also address the possibility of producing a larger amplitude superposition state from decohered states, and show that in most cases the decoherence of the states are amplified along with the amplitude.

International Nuclear Information System (INIS)

Processes of production and purification (necessary for fabricating fuel elements) of powdery uranium dioxide with particle size up to 1000 #mu#m and more have been studied. Developed is continuous process of UO_2 production with above particle size by converting uranium hexafloride into UO_2 solid particles in fluidized bed while their interaction with water vapor and hydrogen on the uranium dioxide nucleus material. The method allows to conduct continuous selection from the apparatus of UO_2 powder fraction with particle size near 1000 #mu#m without nucleus material additional feed.

Energy Technology Data Exchange (ETDEWEB)

An experimental verification for long-term performance of a Pd-Ag permeation in ITER tritium fusion cleanup units (FCU) is needed. In addition, information is required on the influence of tritium and {sup 3}He decay on the physical and chemical properties of Pd-Ag alloys (V-1). The results of the investigations of alloys (V-1) (mechanical properties and microstructure) after long-term usage exposition in tritium are given in this report. The experimental conditions (temperature, pressure, clearance, {sup 3}He concentrations) and the previous conclusions on the V-1 alloy performance are presented. (orig.).

International Nuclear Information System (INIS)

A useful method for preparing radioiodinated photoaffinity labels from alkyl anilines which offer significant advantages over present methods is described. The one-pot synthesis gives good radiochemical yields (40-64%) of pure, high specific activity (350-1500 mCi/#mu#mol) "1"2"4I labelled iodaryl azides while minimising manipulation of radioactive materials. Purification of the ["1"2"5I]iodoazido photoaffinity labels is achieved by high performance liquid chromatography. (author).

Energy Technology Data Exchange (ETDEWEB)

Trichloroethene (TCE), a common groundwater contaminant, can be degraded under certain conditions by microorganisms that occur naturally in the subsurface. TCE can be degraded under anaerobic conditions to less chlorinated compounds and ultimately into the non-chlorinated, non-hazardous end product, ethene, via anaerobic reductive dechlorination (ARD). ARD is widely recognized as a TCE degradation mechanism, and occurs in active groundwater remediation and can occur during monitored natural attenuation (MNA). MNA relies on natural processes, such as dispersion and degradation, to reduce contaminant concentrations to acceptable levels without active human intervention other than monitoring. TCE can also be biodegraded under aerobic conditions via cometabolism, in which microbial enzymes produced for other purposes fortuitously also react with TCE. In cometabolism, TCE is oxidized directly to non-hazardous products. Cometabolism as a ...

Energy Technology Data Exchange (ETDEWEB)

The U.S. Department of Energy Order 435.1, Radioactive Waste Management, requires a disposal authorization statement authorizing operation (or continued operation) for low-level waste disposal facilities. In fulfillment of these requirements, a disposal authorization statement was issued on October 25, 1999, authorizing the Hanford Site to transfer, receive, possess, and dispose of low-level radioactive waste at the 200 East Area burial grounds and the 200 West Area burial grounds. One of the conditions is that monitoring plans for the 200 East Area and 200 West Area low-level burial grounds be written and approved by the Richland Operations Office. As a result of a record of decision for the Hanford Site Solid Waste Program and acceptance of the Hanford Site Solid Waste Environmental Impact Statement, the use of the low-level burial ground (LLBG) as a disposal facility for low-level and mixed low-level wastes has been restricted to lined trenches and the Navy reactor-compartment ...

Energy Technology Data Exchange (ETDEWEB)

The US Department of Enregy (DOE) Subsurface Contaminants Focus Area is developing technologies to address environmental problems associated with hazardous and radioactive contaminants in soil and groundwater that exist throughout the DOE complex, including radionuclides, heavy metals; and dense non-aqueous phase liquids (DNAPLs). More than 5,700 known DOE groundwater plumes have contaminated over 600 billion gallons of water and 200 million cubic meters of soil. Migration of these plumes threatens local and regional water sources, and in some cases has already adversely impacted off-site rsources. In addition, the Subsurface Contaminants Focus Area is responsible for supplying technologies for the remediation of numerous landfills at DOE facilities. These landfills are estimated to contain over 3 million cubic meters of radioactive and hazardous buried Technology developed within this specialty area will provide efective methods to contain ...

Energy Technology Data Exchange (ETDEWEB)

The US Department of Energy (DOE) established the Office of Technology Development (EM-50) as an element of the Office of Environmental Management (EM) in November 1989. In an effort to focus resources and address priority needs, EM-50 introduced the concept of integrated programs (IPs) and integrated demonstrations (IDs). The In Situ Remediation Integrated Program (ISR IP) focuses research and development on the in-place treatment of contaminated environmental media, such as soil and groundwater, and the containment of contaminants to prevent the contaminants from spreading through the environment. Using in situ remediation technologies to clean up DOE sites minimizes adverse health effects on workers and the public by reducing contact exposure. The technologies also reduce cleanup costs by orders of magnitude. This report summarizes project work conducted in FY 1994 under the ISR IP in three major areas: treatment (bioremediation), treatment (physical/chemical), ...

Energy Technology Data Exchange (ETDEWEB)

This report presents the methodology and the results from the modelling of an open repository for spent nuclear fuel in Laxemar. Specifically, the present work analyses the hydrological effects of the planned repository during the construction and operational phases when it is open, i.e. air-filled, and hence may cause a disturbance of the hydrological conditions in the surroundings. The numerical modelling is based on the SDM-Site Laxemar MIKE SHE model. The modelling was divided into three steps. The first step was to update the SDM-Site Laxemar model with a new hydrogeological bedrock model. The other main updates were an increase of the depth of the MIKE SHE model domain, enhanced vertical computational resolution and that the drainage of the Aespoe Hard Rock Laboratory was included in the model. The resulting model was used to simulate undisturbed natural conditions. The next step was to describe the open repository conditions, using Laxemar layout D2, by implementing the access ...

International Nuclear Information System (INIS)

This paper explores the potential implications of climate change for the use and management of water resources in Britain. It is based on a review of simulations of changes in river flows, groundwater recharge and river water quality. These simulations imply, under feasible climate change scenarios, that annual, winter and summer runoff will decrease in southern Britain, groundwater recharge will be reduced and that water quality - as characterised by nitrate concentrations and dissolved oxygen contents - will deteriorate. In northern Britain, river flows are likely to increase throughout the year, particularly in winter. Climate change may lead to increased demands for water, over and above that increase which is forecast for non-climatic reasons, primarily due to increased use for garden watering. These increased pressures on the water resource base will impact not only upon the reliability of water supplies, but also upon navigation, aquatic ...

British Library Electronic Table of Contents (United Kingdom)

The relationships between soil salinization and the zonal and provincial bioclimatic conditions, the lithological composition of the sediments, and the geomorphic features of the territory have been analyzed for the Southern federal okrug of Russia. It is shown that the lithological and geomorphic conditions (relief, salinity of parent materials, degree of drainage, and the depth of saline groundwater) play an important role in the distribution of salt-affected soils against the background of the more general regularities specified by the climate. The participation of salt-affected soils in the soil cover of the Southern federal okrug increases in the eastward direction from the forest-steppe zone to the semidesert zone in agreement with an increase in the aridity and continentality of the...

Energy Technology Data Exchange (ETDEWEB)

This report is the first revision to ``Radiological Performance Assessment for the E-Area Vaults Disposal Facility, Revision 0'', which was issued in April 1994 and received conditional DOE approval in September 1994. The title of this report has been changed to conform to the current name of the facility. The revision incorporates improved groundwater modeling methodology, which includes a large data base of site specific geotechnical data, and special Analyses on disposal of cement-based wasteforms and naval wastes, issued after publication of Revision 0.

Energy Technology Data Exchange (ETDEWEB)

Air pollution constraints continue to intensify, resulting in solid waste volume increases. An example of this is coal burning power plant flue gas desulfurization by scrubbing. The aqueous suspensions of calcium sulfate hemihydrate or calcium sulfate dihydrate will exceed 200 million tons annually by the year 2000. Disposal of these wastes can have massive environmental effects, due to physical instability and leaching to groundwater. One alternate disposal technique is sulfopozzolanic fixation, converting the FGD waste by addition of fine coal ash and an alkaline earth additive, into a monolithic mass. 6 refs., 17 figs., 3 tabs.

International Nuclear Information System (INIS)

The paper demonstrates an application of advanced decision support tools within the framework of the environmental information system of the Province of Milan. These tools include environmental simulation models, multi criteria analysis, risk analysis and environmental accounting for marketable emission permits. After describing the general structure of the system, three demonstrational case studies are introduced concerning: groundwater pollution management; atmospheric pollution management; urban environmental quality perception and management. In the conclusion, potential use of tools like the ones implemented by the province of Milan within the framework of Local Agenda 21 processes is recalled.

Science.gov (United States)

The Rio Grande alluvial floodplain aquifer between El Paso/Juarez and Fort Quitman, Texas has been intensively tilled and irrigated since 1910. Almost since that time, the Rio Grande and its interconnected alluvial aquifer in this stream reach have been affected by excessive salinity problems. Presently, salinity of surface water and groundwater increases from 800 to 2000 mg/L total dissolved solids (TDS) near El Paso, Texas to 2500 to 5500 mg/L TDS near Fort Quitman, Texas, approximately 115 km downstream. Chloride (Cl) and Chloride/Bromide (Cl/Br) ratios increase downstream, with a marked increase in salinity beginning about 45 km below El Paso. Groundwater sampling in an intensively investigated reach of the floodplain aquifer, extending from 35 to 60 km below El Paso identified two distinct water types. The first water type (17 samples) is a relatively dilute groundwater containing 1000 to 2000 mg/L TDS, 250 to 600 ...

International Nuclear Information System (INIS)

The Savannah River Site (SRS) is a 310-square-mile United States Department of Energy nuclear facility located along the Savannah River near Aiken, South Carolina. During operations, which started in 1951, hazardous substances (chemicals and radionuclides) were released to the environment. The releases occurred as a result of inadvertent spills and waste disposal in unlined pits and basins which was common practice before environmental regulations existed. The hazardous substances have migrated to the vadose zone and groundwater in many areas of the SRS, resulting in 515 waste units that are required by environmental regulations, to undergo characterization and, if needed, remediation. In the initial years of the SRS environmental cleanup program (early 1990's), the focus was to use common technologies (such as pump and treat, air stripping, excavation and removal) that actively and tangibly removed contamination. Exclusive use of these technologies required ...

Energy Technology Data Exchange (ETDEWEB)

Prompted by a $10 million Congressional allocation to identify supplemental actions to protect the Columbia River from groundwater contamination beneath the Hanford Reservation, the U. S. Department of Energy (DOE) Environmental Management (EM) Office of Clean-up Technology identified twenty-three potential technical projects and then down-selected ten of these for further evaluation. An independent expert peer review was conducted for the ten down-selected proposals. The review panel consisted of twenty-three recognized subject matter experts that broadly represented academia, industry, and federal laboratories. Of the initial ten proposals reviewed, one was given unconditional support, six were given conditional support, and three were not supported as proposed. Three additional proposals were then submitted by DOE for review--these proposals were structured, in part, to respond to the initial round of technical peer review comments. Peer reviews of these ...

Energy Technology Data Exchange (ETDEWEB)

This study of the hydrogeology of Chicken Creek Canyon wasconducted by the Environmental Restoration Program (ERP) at LawrenceBerkeley National Laboratory (LBNL). This canyon extends downhill fromBuilding 31 at LBNL to Centennial Road below. The leading edge of agroundwater tritium plume at LBNL is located at the top of the canyon.Tritium activities measured in this portion of the plume during thisstudy were approximately 3,000 picocuries/liter (pCi/L), which issignificantly less than the maximum contaminant level (MCL) for drinkingwaterof 20,000 pCi/L established by the Environmental ProtectionAgency.There are three main pathways for tritium migration beyond theLaboratory s boundary: air, surface water and groundwater flow. Thepurpose of this report is to evaluate the groundwater pathway.Hydrogeologic investigation commenced with review of historicalgeotechnical reports including 35 bore logs and 27 test pit/trench logsas well as existing ERP ...

Energy Technology Data Exchange (ETDEWEB)

This report to the Nuclear Regulatory Commission (NRC) describes the development and application of a methodology to systematically and quantitatively assess predictive uncertainty in groundwater flow and transport modeling that considers the combined impact of hydrogeologic uncertainties associated with the conceptual-mathematical basis of a model, model parameters, and the scenario to which the model is applied. The methodology is based on a n extension of a Maximum Likelihood implementation of Bayesian Model Averaging. Model uncertainty is represented by postulating a discrete set of alternative conceptual models for a site with associated prior model probabilities that reflect a belief about the relative plausibility of each model based on its apparent consistency with available knowledge and data. Posterior model probabilities are computed and parameter uncertainty is estimated by calibrating each model to observed system behavior; prior parameter estimates ...

International Nuclear Information System (INIS)

The study area is located in the Bekaa plain of Lebanon totaling about 12753 ha. It lies between the eastern foothills of Mount Lebanon chain and expands across the Litani River towards the foothills of the eastern Anti-Lebanon Mountains. Its characteristics, i.e. natural terrain, climate and socio-economy, make it vulnerable especially due to soil pollution. This paper tries to identify the nature and level of soil pollution by heavy metals. Valley slopes represent a complex landform and lithology that contributed to the formation of different soil. Agriculture in the plain is being practiced mainly with cash, field crops and vegetables. Throughout the central part of the plain, groundwater table is abundant and relatively high (<1.0 m. locally) that multiplies the vulnerability of the soil-groundwater system. There are different sources of pollution, such as industrial (tanneries, batteries, leather manufacturing), solid and liquid wastes, ...

International Nuclear Information System (INIS)

Total river discharge in Pakistan in summer season vary from 3 thousand to 34 thousand cusses (100 thousand Cusses to 1,200 thousand Cusses) and can cause tremendous loss to human lives, crops and property, this causes the loss of most of the flood water in the lower Indus plains to the sea. Due to limited capacity of storage at Tarbela and Mangla Dams on river Indus and Jhelum, with virtually no control on Chenab, Ravi and Sutlej, devastating problems are faced between July and October in the event of excessive rainfall in the catchments. Due to enormous amounts of sediments brought in by the feeding rivers, the three major reservoirs -Tarbela, Mangla and Chashma will lose their storage capacity, by 25 % by the end of the year 2010, which will further aggravate the water-availability situation in Pakistan. The quality of water is also deteriorating due to urbanization and industrialization and agricultural developments. On the Environmental Front the main problems are water-logging ...

Science.gov (United States)

Water is one of our most precious resources. However, for many in the United States, having fresh, safe drinking water is taken for granted, and due to this perceived lack of relevance, students may not fully appreciate the luxury of having safe running water--in the home. One approach to resolving water-quality issues in the United States may reside in providing education that presents accurate information in a meaningful way. Accordingly, this article describes a unit designed to emphasize the importance of water-quality testing and purification and to introduce students to local water-quality issues. The engineering-based module of this eighth-grade science activity is particularly important due to the design-build-test component. (Contains 5 figures.)

British Library Electronic Table of Contents (United Kingdom)

Mono- and disubstituted novel derivatives of the heptaene nystatin analog 28,29-didehydronystatin A1 (S44HP, 1) were obtained by chemical modification of the exocyclic C-16 carboxyl and/or an amino group of mycosamine moiety. The strategy of preparation of mono- and double-modified polyene macrolides was based on the use of intermediate hydrophobic N-Fmoc (9-fluorenylmethoxycarbonyl) derivatives that facilitated the procedures of isolation and purification of new compounds. The antifungal activity of the new derivatives was first tested in vitro against yeasts and filamentous fungi, allowing the selection of the most active compounds that were subsequently tested for acute toxicity in mice. 2-(N,N-dimethylamino)ethylamide of 1 (2) and 2-(N,N-dimethylamino)ethylamide of N-fructopyranosyl-28...

Energy Technology Data Exchange (ETDEWEB)

This study report presents the shutdown chemistry of PWR primary system to reduce and remove the radioactive corrosion products which were deposited on the nuclear fuel rods surface and the outside of core like steam generator channel head, RCS pipings etc. The major research results are the follows ; the deposition radioactive mechanism of corrosion products, the radiochemical composition, the condition of coolant chemistry to promote the dissolution of radioactive cobalt and nickel ferrite, the control method of dissolved hydrogen concentration in the coolant by the mechanical and chemical methods. The another part of study is to investigate the removal characteristics of corrosion product ions and particles by the demineralization system to suggest the method which the system could be operate effectively in shut-down purification period. (author). 19 refs., 25 figs., 48 tabs.

International Nuclear Information System (INIS)

A simple method is presented for the separation of lead-203 from copper-backed thallium cyclotron targets. The procedure involves cation-exchange chromatography in hydrochloric acid and hydrochloric acid-acetone mixtures. Further purification involves anion-exchange chromatography in nitric acid-hydrobromic acid mixtures. A cation-exchange column containing 3.0 g of resin can handle as much as 15 g of thallium and 160 mg of copper. An anion-exchange column containing 3.0 g of resin can separate lead from up to 200 mg of thallium and 10 mg of copper. Separations are extremely sharp and less than 0.1 #mu#g of thallium and less than 0.1 #mu#g of copper remain in the lead-203 fraction. (author).

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Process residues are generated at both the Rocky Flats Plant (RFP) and the Savannah River Plant (SRP) during aqueous chemical and pyrochemical operations. Frequently, process operations will result in either impure products or produce residues sufficiently contaminated with transuranics to be nondiscardable as waste. Purification and recovery flowsheets for process residues have been developed to generate solutions compatible with subsequent Purex operations and either solid or liquid waste suitable for disposal. The ''scrub alloy'' and the ''anode heel alloy'' are examples of materials generated at RFP which have been processed at SRP using the developed recovery flowsheets. Examples of process residues being generated at SRP for which flowsheets are under development include LECO crucibles and alpha-contaminated hydraulic oil.

International Nuclear Information System (INIS)

Radiological and environmental protection experience associated with the reactor cover gas processing system at the Fast Flux Test Facility (FFTF) has been excellent. Personnel radiation exposures received from operating and maintaining the reactor cover gas processing system have been very low, the system has remained free of radioactive particulate contamination through the first seven operating cycles (cesium contamination was detected at the end of Cycle 8A), and releases of radioactivity to the environment have been very low, well below environmental standards. This report discusses these three aspects of fast reactor cover gas purification over the first eight operating cycles of the FFTF (a duration of a little more than four years, from April 1982 through July 1986).

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Previous studies from this laboratory have shown that certain N-substituted phthalimides (NSPs) exhibit GA-like activity in a range of specific bioassays and that bioactive NSPs compete with ({sup 3}H)-GA{sub 4} for soluble binding sites in cucumber homogenates. As such, these compounds may prove useful in the purification and characterization of GA receptor proteins. To this end, five azido-NSPs have been synthesized and are currently being screened for biological activity and photochemical stability. Three azido-NSPs elicit {alpha}-amylase production in barley half-seeds and stimulate tissue elongation in d{sub 5} maize, lettuce, sunflower, and soybean. Further evaluations are in progress and these data as well as the utility of these compounds as photo-affinity ligands will be discussed.

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Two sodium cooled reactors are currently being operated in the United States of America for the US Department of Energy. These are Experimental Breeder Reactor 11, EBR-11, and the Fast Flux Test Facility, FFTF. EBR-11 is located near Idaho Falls, Idaho, and the FFTF is near Richland, Washington. These reactors are currently engaged in a wide range of testing including fuels and materials tests, and plant system performance and safety development. The US DOE program also includes designs of a next generation sodium cooled power reactor. The FFTF and EBR-11 communities are providing input to these designs. This paper discusses the efforts to develop and operate cover gas systems for the sodium cooled nuclear reactor program in the USA.

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Extraction of 25 L fermentation broth of the newly isolated Streptomyces sp. strain TN58 and various separation and purification steps led to the isolation of five bioactive metabolites, namely brevianamide F (C1), reported from a streptomycete for the first time, N?-acetyltryptamine (C2), thiazolidomycin (C3), and two rhamnopyranosides (C4 and C5). These two rhamnopyranosides were produced directly, without precursor addition. The chemical structure of these five active compounds was established on the basis of 1H, 13C/APT and 2D NMR spectra, ESI and EI-MS data, and by comparison with data from the literature. According to the biological studies, we show in this work that the compounds C1, C2, C4 and C5 possess antimicrobial activities.

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Forensic signatures are present in any Pu sample that can determine the sample`s origin: isotopic ratio of Pu, progeny species that grow into the sample, and contaminant species left over from incomplete purification of the Pu in fuel reprocessing. In the context of intelligence information, this can result in attribution of responsibility for the product of clandestine proliferant operations or material smuggled from existing stockpiles. A list of signature elements and what can be determined from them have been developed. Work needs to be done in converting concentrations of signature species into a quantitative forensic analysis, particularly in regard to reactor performance, but this should require only a small effort. A radiochemical analysis scheme has been developed for measuring these nuclides; more work is needed, particularly for determining fission product concentrations. A sample of Pu metal has been analyzed and several parameters determined that are ...

International Nuclear Information System (INIS)

In the electrorefining step of the pyrochemical process, actinide ions dissolved in the LiCl-KCl eutectic salt are recovered as pure actinide metals at a cathode for a re-use as a nuclear fuel from the aspect of its nonproliferation of the nuclear fuel cycles. The lanthanide species dissolved in the LiCl-KCl eutectic salt play an important role in an effective metal purification during the electrorefining step, so it is necessary to understand the chemical and physical behaviors of lanthanides in molten salt. The in situ spectroscopic measurement system and studies according to temperature changes are essential for better understandable information. To our knowledge, the absorption studies of lanthanides at high temperatures have been reported before, but the fluorescence studies of those at high temperature are not reported yet. We will discuss here the fluorescence behaviors of lanthanides in LiCl-KCl molten salt medium according to a changing temperature.

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The reference method used to analyse polychlorodibenzo-p-dioxins (PCDDs), polychlorodibenzofurans (PCDFs) and dioxin-like polychlorinated biphenyls (dl-PCBs) is chromatography with high resolution mass spectrometry (GC-HRMS). It is interesting to check the suitability of screening methods that are faster and less expensive. Different matrices (milk, fish oil, chicken compound feed, pork tissue, chicken tissue, sepiolitic clay, whole egg and herring tissue) were analysed in the frame of the European project DIFFERENCE1. One of the aims of this project is to optimise screening methods. The CALUX bio-assay was one of the screening techniques used. This paper presents the extraction and purification methods used for the analyses. The CALUX results for dioxins and for dl-PCBs were compared to the corresponding GC-HRMS results.

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A compilation of all universities, industrial and governmental agencies in Quebec which are actively involved in research and development of chemical products and industrial materials derived from biomass products, was presented. Each entry presented in a standard format that included a description of the major research activities of the university or agency, the principal technologies used in the research, available research and analytical equipment, a description of the research personnel, names, and addresses of contact persons for the agency or university. Thirty entries were presented. These covered a wide diversity of activities including biotechnological research such as genetic manipulations, bioconversion, fermentation, enzymatic hydrolysis and physico-chemical applications such as bleaching, de-inking, purification and synthesis. tabs.

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This is a report of extraction and identification of 1-O-alkyl glycerol present in the dried leaves of Bauhinia scandens. Fifty percent aqueous ethanolic extract of the plant at room temperature was fractionated over petroleum ether and diethyl ether. The diethyl ether soluble fraction showed positive bioactivity in Brine Shrimp bioassay. Isolation and purification of the active principle was subsequently done from diethyl ether fraction. The diethyl ether fraction was separated into acidic and neutral part. The acid free fraction was screened to be positive in Brine Shrimp bioassay. The NMR spectra (in CDCl3) indicated the probability of its lipoidal nature. The total lipid fraction was resolved into neutral, glyco, and phospho-lipids by column chromatography. Only the neutral fraction sh...

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Research at the interface between biomolecules and inorganic nanocrystals has resulted in a great number of new discoveries. In part this arises from the synergistic duality of the system: biomolecules may act as self-assembly agents for organizing inorganic nanocrystals into functional materials; alternatively, nanocrystals may act as microscopic or spectroscopic labels for elucidating the behavior of complex biomolecular systems. However, success in either of these functions relies heavily uponthe ability to control the conjugation and assembly processes.In the work presented here, we first design a branched DNA scaffold which allows hybridization of DNA-nanocrystal monoconjugates to form discrete assemblies. Importantly, the asymmetry of the branched scaffold allows the formation of asymmetric2assemblies of nanocrystals. In the context of a self-assembled device, this can be considered a step toward the ability to engineer functionally distinct inputs and outputs.Next we develop an ...

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A high-temperature flow reactor and different technical plants were tested within the framework of this research project. Anthropogenic N{sub 2}O emissions form during secondary flue gas or waste gas purification as secondary emissions during denitrification and pollution abatement measures. N{sub 2}O forms as an intermediate product as NO is reduced to N{sub 2}. Under certain operating conditions N{sub 2}O is not decomposed completely. Different secondary flue gas purification measures, i.e. selective noncatalytic reduction (SNCR), selective catalytic reduction (SCR), and nonselective catalytic reduction (NSCR) were investigated testing several technical plants and the high-temperature flow reactor. (orig./EF) [Deutsch] Das Forschungsprojekt ``Messung der N{sub 2}O-Emissionen von Verbrennungsanlagen und Untersuchung von Moeglichkeiten zur Emissionsminderung`` wurde an einem Hochtemperatur-Stroemungsreaktor und an verschiedenen technischen ...

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Water is the most important limiting factor in the development of arid environments; therefore, optimization of water use is a necessity in desert reclamation projects. Evapotranspiration of a 6-year-old river red gum (Eucalyptus camaldulensis Dehnh.) plantation, located in a sedimentation basin of an artificial recharge of the Gareh Bygone Plain groundwater system in Iran?s southern Zagros Mountains, was studied during a 7-month period. A neutron moisture probe was used to monitor soil water changes in the root zone. Soil water depletion following rapid drainage for blocks receiving relatively high, medium and low volumes of floodwater were 809.6, 312.4, and 203.1 mm, respectively, for a 150-day period. Soil water potential during most of the study period was below ?1.5 MPa. This study pr...

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This report provides a user's manual for PROTOCOL, a comprehensive coupled kinetic/equilibrium computer program for analyzing the dissolution reactions of solids with aqueous solutions, specifically applied to the potential corrosion of vitrified nuclear waste by groundwater. The capabilities and available options are summarized as well as instructions for setting up and running problems. Also described in this report and included in the PROTOCOL software package are MASTER, a master file of species thermodynamic data, MANEQL, a preprocessor program and POSTP, a postprocessor. POSTP provides offline plotting using the CRAY-1 DISSPLA 9.0 graphics library. PROTOCOL is operational on the CDC-7600 and CRAY-1 computers at the Lawrence Livermore National Laboratory. 7 references, 10 figures, 2 tables.

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Storage of thermal energy in aquifers has obvious benefits of saving energy and decreasing the consumption of fossil fuels. However, aquifer thermal energy storage (ATES), which involves groundwater aquifers as the storage medium for heat or chill, impinges on the environment. A literature review of pertinent microbiology publications (Hicks and Stewart, 1988) identified the potential for the interaction of ATES systems and microbiological processes to create a source of infectious diseases and the potential for damage to the environment. In addition, the review identified a potential for microbiological processes to develop conditions that would interfere with the operation of an ATES system. As a result of this research effort, investigators from Finland, Germany, Switzerland, and the United States have examined several ATES systems in operation and have observed that the ATES systems studied do not contribute to infectious disease transmission, do not adversely ...

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Summary 1. The EU -Nitrates Directive- (Directive 91/676/EEC) and the WFD (Water Framework Directive 2000/60/EEC) introduced a series of measures designed to reduce and prevent water pollution caused or induced by nitrates from agricultural sources. Therefore, there is an urgent requirement to control the nitrate concentration in freshwater. The objective of this paper was to verify the potential capacity of a specifically designed afforested riparian zone in removing the excess of nitrogen from river water. 2. A buffer zone was set with irrigation ditches, to produce a subsurface water flow carrying water from the study river through the buffer strip to drainage ditches. This experimental system enables the co-occurrence of two main processes: vegetation/microbial nitrogen uptake and deni...

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Greenhouse-effect induced climate change repercussions will, via the catchment areas of big rivers, eventually arrive in amplified form at the far downstream coastal zones of the world. In the coastal zone these imported problems will add to the locally exerted climate change effects, while the climate change induced sea-level rise will attack the coastal zone from the other side, both by flooding and by saline groundwater intrusion. These multiple problems will hit the coastal zone, which is already under increasing stress. The combined threats require fast and massive support for national Coastal Zone Management capabilities, which could help to limit the damage and to support planning for sustainable development. Recommendations are presented to facilitate implementation of Coastal Zone Management units in all coastal countries by the year 2000.

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The Savannah River Site disposes of low-level radioactive waste within on-site engineered disposal facilities. The Savannah River Site must demonstrate that these disposals meet the requirements of DOE Order 435 . 1 through a process known as performance assessment (PA). The objective of this document is to provide the radionuclide -specific data needed for the PA calculations . This work is part of an on-going program to periodically review and update existing PA work as new data becomes available. Revision of the E -Area Low-Level Waste Facility PA is currently underway. The number of radionuclides selected to undergo detailed analysis in the PA is determined by a screening process. The basis of this process is described. Radionuclide-specific data for half-lives, decay modes, daughters, dose conversion factors and groundwater concentration limits are presented with source references and methodologies.

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A wet air oxidation (WAO) process was applied to four selected pharmaceuticals (metoprolol, naproxen, amoxicillin, and phenacetin) individually dissolved in ultra-pure water, varying the temperature and oxygen pressure. Due to the moderate (amoxicillin) or low (metoprolol, naproxen, and phenacetin) efficiency found in the oxidation of these pollutants, a catalytic wet air oxidation (CWAO) process was then tested using a platinum catalyst supported on multi-walled carbon nanotubes (CNT). In this CWAO process, the pharmaceuticals were dissolved together in ultra-pure water and in four natural water matrices-a reservoir water, a groundwater, and two waters from different municipal wastewater treatment plants. On the basis of the measurements of their removals, a discussion is given of the inf...

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It has been shown that not only there are abundant oil, gas, coal, coal-bed gas, groundwater and giant uranium deposits but also there are abundant oil shale resources in Ordos basin. It has been shown also that the thickness of oil shale is, usually, 4-36m, oil-bearing 1.5%-13.7%, caloric value 1.66-20.98MJ/kg. The resource amount of oil shale with burial depth less than 2000 m is over 2000x108t (334). Within it, confirmed reserve is about 1x108t (121). Not only huge economic benefit but also precious experience in developing oil shale may be obtained in Ordos basin.

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Reactive chemical transport models developed over the past decade have generally relied on the assumption that local thermodynamic equilibrium is achieved at all times between aqueous species in a given system. Consequently, homogeneous aqueous systems characterized by a number of kinetically slow reactions, particularly problems involving organic species, cannot be satisfactorily modeled. In this study, we present a prototype computer model, KINETRAN, which is designed to handle kinetically-controlled homogeneous reactions in the aqueous phase, along with the transport of the various species involved, through geologic media. 31 refs., 53 figs., 10 tabs.

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The primary objective of this study was to evaluate the potential environmental effects (both adverse and beneficials) of aquifer thermal energy storage (ATES) technology pertaining to microbial communities indigenous to subsurface environments (i.e., aquifers) and the propagation, movement, and potential release of pathogenic microorganisms (specifically, Legionella) within ATES systems. Seasonal storage of thermal energy in aquifers shows great promise to reduce peak demand; reduce electric utility load problems; contribute to establishing favorable economics for district heating and cooling systems; and reduce pollution from extraction, refining, and combustion of fossil fuels. However, concerns that the widespread implementation of this technology may have adverse effects on biological systems indigeneous to aquifers, as well as help to propagate and release pathogenic organisms that enter thee environments need to be resolved. 101 refs., 2 tabs.

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Evaluations were done to determine conditions that could permit nuclear criticality with fissile uranium in low-level waste (LLW) facilities and to estimate potential radiation exposures to personnel if there were such an accident. Simultaneous hydrogeochemical and nuclear criticality studies were done (1) to identity realistic scenarios for uranium migration and concentration increase at LLW disposal facilities, (2) to model groundwater transport of uranium and subsequent concentration via sorption or precipitation, (3) to evaluate the potential for nuclear criticality resulting from potential increases in uranium concentration over disposal limits, and (4) to estimate potential radiation exposures to personnel resulting from criticality consequences. This paper presents the details of the radiation exposure calculations relying on the conditions as determined from the preceding studies detailed in a cited reference.

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Sulfur pollution can lead to serious problems in freshwater wetlands, including phosphorus eutrophication and sulfide toxicity. We tested the effects of anaerobic iron-rich groundwater discharge in fens, simulated by iron injection, on two characteristic species (Juncus effusus and Caltha palustris) in a sulfidic environment. Biomass production of C. palustris roots showed an optimum response to the combined addition of iron and sulfide, with highest values at intermediate concentrations of both substances. Iron deficiency apparently occurred at low iron concentrations, while at high iron concentrations, growth was decreased. For J. effusus, in contrast, no toxic effects were found of both iron and sulfide. This could be explained by larger radial oxygen loss (ROL) of J. effusus and could ...

British Library Electronic Table of Contents (United Kingdom)

Abstract The present study makes use of a detailed water balance to investigate the hydrological status of a peatland with a basal clay-rich layer overlying an aquifer exploited for drinking water. The aim is to determine the influence of climate and groundwater extraction on the water balance and water levels in the peatland. During the two-year period of monitoring, the hydrological functioning of the wetland showed a hydric deficit, associated with a permanent unsaturated layer and a deep water table. At the same time, a stream was observed serving as a recharge inflow instead of draining the peatland, as usually described in natural systems. Such conditions are not favourable for peat accumulation. Field investigations show that the clay layer has a high hydraulic conductivity (from 11...

British Library Electronic Table of Contents (United Kingdom)

This paper presents a study on Manasbal lake, which is one of the high altitude lakes in the Kashmir Valley, India. Eighteen water samples were analysed for major ions and trace elements to assess the variability of water quality of the lake for various purposes. Geostatistics, the theory of regionalized variables, was then used to enhance the dataset and estimate some missing spatial values. Results indicated that the concentration of major ions in the water samples in winter was higher than in summer. The scatter diagrams suggested the dominance of alkaline earths over the alkali elements. Three types of water were identified in the lake that are referred to as Ca?HCO3, Mg?HCO3 and hybrid types. The lake water was found to be controlled by rock?water interaction with carbonate lithology ...

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Although nitrogen inputs to agricultural fields are necessary for global food sustainability, they present a major nutrient management challenge, because nitrogen inputs can increase nitrogen losses to the environment, which can negatively impact water quality across key surface and groundwater resources. The need to evaluate the potential risk of nitrogen losses for a given forage type, management scenario, and field quickly and easily can be met with new tools that assist in environmental risk assessment. An example is the Mexico Nitrogen Index: this new tool aims to help its users quickly evaluate the risk of nitrogen loss for a given field under a given set of management practices. The objective of this study was to evaluate the accuracy of the Mexico Nitrogen Index in ranking the risk...

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Numerical simulations are used to predict the migration of radionuclides from the disposal units at Material Disposal Area G through the vadose zone and into the main aquifer in support of a radiological performance assessment and composite analysis for the site. The calculations are performed with the finite element code, FEHM. The transport of nuclides through the vadose zone is computed using a three-dimensional model that describes the complex mesa top geology of the site. The model incorporates the positions and inventories of thirty-four disposal pits and four shaft fields located at Area G as well as those of proposed future pits and shafts. Only three nuclides, C-14, Tc-99, and I-129, proved to be of concern for the groundwater pathway over a 10,000-year period. The spatial and temporal flux of these three nuclides from the vadose zone is applied as a source term for the three-dimensional saturated zone model of the main aquifer that underlies the site. The ...

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In recent years, several larger geothermal heat pump plants for offices or commercial areas have been designed and built in the central region of Germany, mainly in the Rhein-Main area. Systems with borehole heat exchangers (BHE; in the USA the term Vertical Loop is commonly used) as well as with shallow geothermal doublets (groundwater wells) are operational. New solutions had to be found to adapt the technology to certain site constraints, and innovative components such as thermally-enhanced grouting material have been used. This paper reviews the early development of Ground Source Heat Pumps (GSHP) for commercial buildings, gives details on a number of recent plants and discusses problems that arose during their realisation: UEG Wetzlar, a building with chemical laboratories and one of the first examples of direct cooling from BHE; DFS Langen (German Air Traffic Control Headquarters), with 154 BHE for heating and cooling, operating without antifreeze; Baseler ...

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Faults in shallow, unconsolidated sediments, particularly in coastal plain settings, are very difficult to discern during subsurface exploration yet have critical impact to groundwater flow, contaminant transport and geotechnical evaluations. This paper presents a case study using cross-over geophysical technologies in an area where shallow faulting is probable and known contamination exists. A comparison is made between Wenner and dipole-dipole resistivity data, ground penetrating radar, and high resolution seismic data. Data from these methods were verified with a cone penetrometer investigation for subsurface lithology and compared to existing monitoring well data. Interpretations from these techniques are compared with actual and theoretical shallow faulting found in the literature. The results of this study suggests that (1) the CPT study, combined with the monitoring well data may suggest that discontinuities in correlatable zones may indicate that faulting ...

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This document presents a conceptual design for a contingency interim measure (IM) for treatment of the public water supply system at Barnes, Kansas, should this become necessary. The aquifer that serves the public water supply system at Barnes has been affected by trace to low concentrations of carbon tetrachloride and its degradation product, chloroform. Investigations conducted on behalf of the CCC/USDA by Argonne National Laboratory (Argonne 2008a) have demonstrated that groundwater at the Barnes site is contaminated with carbon tetrachloride at concentrations exceeding the Kansas Tier 2 risk-based screening level (RBSL) and the EPA maximum contaminant level (MCL) of 5.0 {micro}g/L for this compound. The Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) formerly operated a grain storage facility in Barnes, approximately 800 ft east-southeast of the public water supply wells. Carbon tetrachloride was used in the treatment of grain. ...

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The presence of the nitrogen-fixing shrub, Alnus incana ssp. rugosa, influences the concentration of inorganic nitrogen in surface waters in the Adirondack Mountain region of northern New York. - The purpose of this research was to determine the abundance of the nitrogen-fixing shrub, Alnus incana ssp. rugosa (speckled alder), in shrub wetlands of the Adirondack Mountain region of New York State and to determine whether its abundance affects the concentration or accumulation of inorganic nitrogen in wetland substrates. Alder/willow wetlands are the second most common wetland type in the Adirondack region. The Adirondack Park Agency's digital GIS database of wetland types was used to determine the areal extent of alder/willow wetlands in the Adirondacks. Randomly selected wetlands were sampled to determine the size and abundance of alder. Alder densities averaged {approx}7000 stems ha{sup -1} and alder was present in 75% of the wetlands. As an indication of short-term ...

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''S-220'' white oil is used currently to impregnate and fill high voltage cables for 110-500 kilovolts; it has high electrical characteristics and meets production and use standards. High pressure and cooling problems, however, require filling cables with lower viscosity oils, while insulation needs still demand high viscosity. The authors developed a new white oil similar to S-220 using a neutral oil made in producing sulfonate additives. The process involved vacuum distillation, low-temperature paraffination, sulfation with oleum, neutralizing with ammonium hydroxide and simultaneous extraction of sulfo-salts and contact purification. The lowest content of aromatic hydrocarbons was sought. Dielectric qualities varied with viscosity. Satisfactory thermooxidational capability was found at 50/sup 0/C with an oil of no less than 50 mm/sup 2//sec viscosity. The final white oil had no more than 2% aromatic hydrocarbons, thus assuring ...

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A method was developed to synthesize /sup 14/C-labelled n-alkanes for use in cigarette smoke studies. Specifically, n-(18-/sup 14/C)-octatriacontane was synthesized from 1 mCi (1-/sup 14/C)stearic acid in a radiochemical yield of 20%. The key features of this synthesis were two consecutive alkylations of tosylmethyl isocyanide followed by acid hydrolysis to (18-/sup 14/C)-19-octatriacontanone and modified Wolff-Kishner reduction to the n-alkane. After purification on silica gel 25 mg of (18-/sup 14/C)octatriacontane was obtained with a total radioactivity of 200 ..mu..Ci, a specific activity of 4.3 mCi/mmol, and a radiochemical purity in excess of 98% by thin layer radiochromatography. The method has also been applied to the synthesis of unlabeled n-pentatriacontane and is considered to be generally applicable to the synthesis of radiolabeled alkanes from radiolabeled fatty acids.

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Adsorption of uranium onto various solids is important from purification, environmental, and radioactive waste disposal points of view. Adsorption of uranium on activated charcoal has been studied as a function of shaking time, amount of adsorbent, pH, concentration of adsorbate, and temperature. Uranium adsorption obeys the Langmuir isotherm. {Delta}H{degrees} and {Delta}S{degrees} were calculated from the slope and intercept of plots ln K{sub D} vs 1/T. The influence of different anions and cations on uranium adsorption has been examined. The adsorption of other metal ions on activated charcoal has been studied under specified conditions to check its selectivity; consequently, uranium was removed from Cs, Ba, Zn, and Co. More than 98% adsorbed uranium on activated charcoal can be recovered with 65 ml of 3 M HNO{sub 3} solution. A wavelength dispersive x-ray fluorescence spectrometer was used for measuring uranium concentration.

International Nuclear Information System (INIS)

The operation of industrial facilities has generally resulted in contamination of the surrounding soils and ground water. A variety of methods have been proposed for the remediation of contaminated sites. This paper presents new process technology that is capable of performing treatment on ground water or soil washing leachates. The process is targeted to treat low levels of radioactivity, organics and heavy metals present in the aqueous solutions, to be easily transported and provide simple operation on-site and provide an effluent that meets the specified discharge quality. The purification process involves sequential chemical treatment and filtration. The paper will describe the development of the technology and review the current progress in its use to remediate contaminated sites at Chalk River. The application of the process technology has demonstrated that the ambitious goal of setting the effluent targets to meet the drinking water standards was realized. A ...

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Four extracellular keratinases (designated KI, KII, KIII, and KIV) were produced during submerged aerobic cultivation in a medium containing native human foot skin (NHFS) for enzyme synthesis. The molecular weights, determined by SDS-PAGE, were 25, 50, 34, and 19kDa, respectively. Gel filtration of the four purified enzymes in native conditions indicated that active keratinase KI is a novel homo-octamer, KII a homo-dimer, and KIII and KIV monomers. All four keratinases exhibited high activities at pH 8.0-10.0 with an optimal pH of 9.0. The optimal temperature for keratinolytic activity of KI, KII, and KIII was approximately 50, and 60degreeC for KIV. One millimolar of PMSF completely inhibited the keratinolytic activities of the four enzymes. The N-terminal sequences of KI, KII, and KIII s...

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The potential to scrub biogas in a high rate pond (HRP) was evaluated using apparatus designed to maximize gas-liquid contact. Experiments compared the removal of carbon dioxide from synthetic biogas by an 'in-pond angled gutter' to that by a simulated 'counter-current pit'. Results showed that the counter current pit has potential for use in biogas scrubbing, with synthetic biogas carbon dioxide composition consistently reduced from 40% to<5%. The in-pond angled gutter was less effective due to bubble coalescence which reduced the total bubble surface surface area available for gas transfer. Measurement of oxygen levels in the scrubbed biogas showed that despite supersaturation of oxygen in the HRP water, there was little transfer to the biogas, so that explosive methane/oxygen mixtures would not be formed. Theoretical calculations indicated that the amount of biogas likely to be formed during anaerobic treatment of municipal wastewater could ...

International Nuclear Information System (INIS)

As part of our program in radiopharmaceutical chemistry we have prepared and evaluated a series of radioiodinated 1-alkyl-4-phenylpiperazines as potential brain-imaging agents. The compounds were chosen on the basis of their synthetic versatility, activation toward electrophilic substitution, and ease of purification. The intermediates 1-6 were readily obtained and converted to the corresponding radioiodinated products 7-12 in 76-91% isolated radiochemical yields. The tissue distribution in rats indicated that the 1-N-butyl derivative 9 possesses the best combination of brain uptake (0.28-0.35% ID X kg/g), retention, and selectivity (brain/blood greater than 20) over the 4-h evaluation period. A subsequent imaging and tissue distribution study in the dog using 131I-labeled 9 supported the results observed in the rat and suggested the potential of this agent as a brain-imaging agent.

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A large amount of industrial water is used for cooling the various process fluids in the petroleum purification factories as well as petroleum chemistry factories. Consequently, a lot of heat exchangers as the necessary constitutional instruments are made of carbon steel. Due to the most of the corrosions of the carbon steel occurring in such cooling water systems are pitting corrosions, the inhibition thereof is extremely important for the elongation of the life of the plants and the stable operation. In this paper, the influences of water quality fractions on pitting corrosion of carbon steel in cooling water circumstance are examined aiming at the fouling in the cooling water. The fouling in the cooling water does not only increase the amount of occurrence of pitting corrosion but also accelerates the progress of pitting corrosion enlarging the rust due to its deposition near the anode. Since only the inhibitor is not sufficient to inhibit the pitting corrosion ...

International Nuclear Information System (INIS)

Recent nuclear power plants require high purity water to protect nuclear reactors or steam generators from SCC and maintain in good condition. In this connection, it is especially important to minimize sulfate, which is a corrosive chemical originated from oxidative degradation of cation exchange resins during operation. Recently, uniform particle size (UPS) strong acid cation gel resin with 14% cross-linkage, which has excellent stability against oxidization, has been applied to several condensate purification systems. For further improvement of water quality, some methods for changing the configuration of condensate demineralizer's resin bed have been examined. For example, these methods correspond to anion under layer and cation over layer. We have tested these methods by cold column tests. Furthermore, we have developed the newly anion exchange resin having higher efficiency and capacity for absorbing leachables from cation exchange resins. In this paper, we ...

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The size of the market for pulverized activated charcoal and particulate activated charcoal prepared by the Association of Inorganic Chemicals of Japan is 55,000t/y (1987) in total. Individually, some fields showed the expansion such as water purification, water treatment and gas treatment on the one hand, but on the other hand, several fields showed the decline such as sugar refining, dextrin sugar and soda glutamate. As a whole, the market showed no marked fluctuations or a very slight increase. Many of the above usages are traditional in the chemical industry and the food industry, etc., and the new usages developed in the past several years have not grown to influence the statistics as yet. Selection of raw material is the key for determining the character of activated charcoal. And the factors of determining the characteristic features are fine pore, surface area and surface activity (catalystic activity). Furthermore, the function requirement from the ...

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An evaporator using a hydrophobic membrane made from a polytetrafluoroethylene (PTFE) was developed to improve DF (Decontamination Factor) and to reduce evaporator size. The membrane distillation, provided by the evaporator, is a new technique for liquid purification. Fundamental experiments were carried out to develop the membrane filter (tube type, outer diameter, 8 mm; membrane thickness, 500 {mu}m) for radioactive liquid treatment. The continuous operation test using actual liquid waste was also made during about 3,000 h. (This is almost equal to the operation time of an actual evaporator per year.) The evaporation rate decreased with increase an operation time due to contamination of waste impurity. But the rate was recovered by washing the membrane with hot water and then drying it. DF was over 10{sup 4} which is ten times larger than that for a conventional system. A pilot plant (capacity, 200 kg-liquid waste/h) was constructed and its performance test was ...

Energy Technology Data Exchange (ETDEWEB)

Studies have been conducted to determine the feasibility of using collisional cooling for reducing emittances and energy spreads in negative-ion beams to levels commensurate with effective isobaric purification with conventional high-resolution electromagnetic isobar separators as required for use at the Holifield Radioactive Ion Beam Facility (HRIBF). We have designed a gas-filled radio frequency quadrupole ion cooler equipped with provisions for retarding energetic negative-ion beams to energies below thresholds for electron detachment at injection and for re-acceleration to initial energies after the cooling process. The device has been used to cool several ion beams with initial energy spreads, {delta}E>10 eV to final energy spreads, {delta}E{approx}2 eV FWHM, including O{sup -} and F{sup -}. Overall transmission efficiencies of {approx}14% for F{sup -} beams have been obtained. Experimental results show that electron detachment is the major loss ...

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Chemical-looping combustion (CLC), has previously been studied as a method for separating CO{sub 2} during combustion of gaseous fuels. In this project the possibility to apply this process for direct use of solid fuels has been investigated. The following has been accomplished: A 10 kW reactor system for CLC with solid fuels has been designed and built. Tests with solid fuel and metal oxid particles in a laboratory reactor show that it is possible to oxidize solid fuels with metal oxide particles in cyclic testing, thus giving proof of basic concept. They also show how the reaction rate is affected by temperature, steam concentration etc., and, most important of all, that the rates of reaction are realistic. Tests with metal oxide materials available at low costs have been successful. Chemical-looping combustion with solid fuels has a potential to achieve very low costs for separation of CO{sub 2}, below 10 Euro/ton CO{sub 2}. In summary the studies of metal oxides and tests with ...

Energy Technology Data Exchange (ETDEWEB)

The investigations showed that the new adsorber/catalyst composites are well suited for chemical degradation of persistent water pollutants. Compared with alternative processes, the reaction selectivity and the consumption of oxidant are more favourable as the reaction now takes place on/inside the solid. The process, which was developed originally for purification of contaminated water, can be transferred to many other systems of materials. For example, it is expected that the soot emissions of diesel engines will be reduced significantly after efficient hydrogenation of the aromatics contained in the diesel engine on molybdenum-charged mesoporous composites. [German] Mit den vorliegenden Untersuchungen konnte ein erster Nachweis gefuehrt werden, dass die neu entwickelten Adsorber/Katalysator-Komposite fuer den chemischen Abbau persistenter Wasserschadstoffe geeignet sind. Im Vergleich zu alternativen Verfahrensloesungen kann die Selektivitaet der Reaktion und der ...

Energy Technology Data Exchange (ETDEWEB)

Since the beginning of the large-scale technical manufacture of activated charcoal at the start of the century, this product has become increasingly important. Activated charcoal is a central part today of many chemical industrial processes. Furthermore, the purification of exhaust air and liquid wastes is often based on the adsorption by activated charcoal. The constantly increasing hygienic demands made of our drinking water may also often only be fulfilled by using activated charcoal. The highly developed adsorption technique of today is considerably supported by continuous improved quality of the products which can only be achieved by progress in manufacturing techniques. The large-scale use of activated charcoal has only become possible for a series of tasks by developing suitable reactivation methods. The last German-language monograph on activated charcoal appeared 18 years ago. The present work wishes to close this gap and in particular to give a survey on ...

Energy Technology Data Exchange (ETDEWEB)

Water-resources data for the 1993 water year for Texas are presented in four volumes, and consist of records of stage, discharge, and water quality of streams and canals; and stage, contents, and water quality of lakes and reservoirs; and water levels and water quality of ground-water wells. Volume 3 contains records for water discharge at 134 gaging stations; stage only at 1 gaging stations; stage and contents at 13 lakes and reservoirs; water quality at 81 gaging stations; and data for 30 partial-record and 4 flood-hydrograph partial-record stations. Also included are lists of discontinued surface-water discharge or stage-only stations and discontinued surface-water-quality stations; crest-stage and flood-hydrograph partial-record stations, reconnaissance partial-record stations, and low-flow partial-record stations.

Energy Technology Data Exchange (ETDEWEB)

The US Nuclear Regulatory Commission is currently considering revision of rule 10 CFR Part 20, which covers disposal of solid wastes containing minimal radioactivity. In support of these revised rules, we have evaluated the consequences of disposing of four waste streams at four types of disposal areas located in three different geographic regions. Consequences are expressed in terms of human exposures and associated health effects. Each geographic region has its own climate and geology. Example waste streams, waste disposal methods, and geographic regions chosen for this study are clearly specified. Monetary consequences of minimal activity waste disposal are briefly discussed. The PRESTO methodology was used to evaluate radionuclide transport and health effects. This methodology was developed to assess radiological impacts to a static local population for a 1000-year period following disposal. Pathways and processes of transit from the trench to exposed populations included the ...

Energy Technology Data Exchange (ETDEWEB)

Work of the Geothermal Heat Pump Consortium (GHPC), a joint program of the US Department of Energy, the US Environmental Protection Agency, the US electric utilities and industry was described. The consortium was established to improve energy efficiency and reduce CO{sub 2} emissions by moving ground source and groundwater source heat pumps from niche products to ten percent of the new and retrofit HVAC market in less than a decade. The GHPC program focuses on : (1) reducing first costs through technology innovation and innovative financing, (2) strengthening the infrastructure though education, training and work codes and regulations, and (3) building confidence in the technology through demonstrations of cost-effectiveness, low maintenance efforts and through marketing programs. Results of the first two years of operations were described. Results indicate that the objectives are being achieved, the number of installations is increasing and a solid foundation is ...

International Nuclear Information System (INIS)

For prolonged storage and eventual disposal radioactive wastes will be solidified to reduce the problems which accompany liquid waste whilst solid wastes will be encapsulated in an immobilising matrix. In the solidification and encapsulation process it will be important to produce a material in a form which is chemically stable, mechanically strong and which will not react with or allow free passage of groundwater. To this end a continuous check will be required to ensure that the various wastes are chemically compatible with the solidifying and binding matrices and that the associated processes are performed against a strict Quality Programme. The Quality Programme will be extensive requiring the specification of procedures for assessing the quality and nature of the wastes, the detailed operation of the solidification and/or encapsulation, the overpack requirements for transportation and the routines to be adopted with respect to storage or final disposal in the ...

International Nuclear Information System (INIS)

This report primarily deals with three issues: the health consequences of the use of ammunition with depleted uranium cores; the health damage that radar staff may have suffered through stray X-radiation; and the way hazardous materials such as asbestos are handled in the German army. As regards uranium ammunition, the present findings suggest that there is neither reason for concern nor blame on anyone. The 31,000 American DU rounds that were fired over Kosovo in 1999 neither pose a health hazard to soldiers nor to the civil population. All that remains is a minimal risk of future groundwater contamination. The radar equipment currently in use in the German army poses no danger to operators, inspectors, service personnel or instructors provided that the relevant safety rules are observed. However, this cannot be said with the same degree of certainty with regard to the equipment used in the 1960s and 1970s. It is quite possible that X-radiation was emitted and ...

International Nuclear Information System (INIS)

Long-term disposal and management of low and intermediate-level radioactive waste is a major project of the nuclear power industry. Therefore, the selection of an underground waste repository has to be a geologically and seismologically stable storage. Easy transportation and emplacement is essential. The Wolsung nuclear power plant (NPP) of unit no. 1/2/ 3/ 4, which is responsible for the future of the energy industry, has already been constructed at the Wolsung site and a New NPP has recently been created at the Sinwolsung site. Radioactive waste used in the plant facilities, has piled up increasingly every year, but it should be taken to be managed at long-term underground storage disposal facilities. The Wolsung site for radioactivity waste repository was known to be relatively stable through various geological surveys, earthquakes, groundwater, engineering testing and analysis, but still more research related to the stability of the structure, in deep ...

Energy Technology Data Exchange (ETDEWEB)

Soils and groundwater beneath an abandoned Process sewer line in the A/M Area of the Savannah River Site (SRS) contain elevated levels of volatile organic compounds, specifically trichloroethylene (TCE) and tetrachloroethylene (PCE), two common chlorinated solvents. These compounds have low aqueous solubilities, thus when released to the subsurface in sufficient quantity, tend to exist as immiscible fluids or nonaqueous phase liquids (NAPLs). Because chlorinated solvents are also denser than water, they are referred to by the acronym DNAPLS, or dense non aqueous Phase liquids. Technologies targeted at the efficient characterization or removal of DNAPL are not currently proven. For example, most DNAPL studies rely on traditional soil and water sampling and the fortuitous observation of immiscible solvent. Once DNAPL is identified, soil excavation (which is only applicable to small contained spill sites) is the only ``proven`` cleanup method. New cleanup approaches ...

Energy Technology Data Exchange (ETDEWEB)

Geothermal energy pile foundations are an alternative energy source for heating and cooling needs. Utilising this source of energy has great potential due to the environmental, economic and social benefits. This paper looks at an extensive amount of literature on the technology behind the system including the overall process, primary considerations for each of the main components including latest developments as well as design implications such as the integration of ground energy systems into structural piles of buildings. Environmental considerations including performance-dependent parameters of the subsurface are described. Main parameters include thermal conductivity, thermal diffusivity, specific heat capacity and moisture content. Temperature and groundwater effects are also discussed and design considerations are provided. Mathematical models are available to aid in the design of these systems but there are various other issues and complex parameters that ...

Energy Technology Data Exchange (ETDEWEB)

This report presents the status of development of a three-dimensional conceptual model for the unconfined aquifer system at Hanford. A conceptual model is needed to support development of a realistic three-dimensional numerical model for predicting ground-water flow and the transport of contaminants. The report focuses on developing a hydrogeologic framework, assessing available hydraulic property data, describing flow-system boundaries, and evaluating areal recharge and leakage. Geologic descriptions of samples obtained during well drilling were used to prepare cross sections that correlate relatively continuous layers. The layers were defined based on textural differences that are expected to reflect differences in hydraulic properties. Assigning hydraulic properties to the layers is a critical part of the conceptual model. Available hydraulic property data for the study area were compiled and were correlated with the geologic layers where possible. Flow-system ...

International Nuclear Information System (INIS)

Atrazine and phenanthrene (Phen) sorption by nonhydrolyzable carbon (NHC), black carbon (BC), humic acid (HA) and whole sediment and soil samples was examined. Atrazine sorption isotherms were nearly linear. The single-point organic carbon (OC)-normalized distribution coefficients (K_O_C) of atrazine for the isolated HA1, NHC1 and BC1 from sediment 1 (ST1) were 36, 550, and 1470 times greater than that of ST1, respectively, indicating the importance of sediment organic matter, particularly the condensed fractions (NHC and BC). Similar sorption capacity of atrazine and Phen by NHC but different isotherm nonlinearity indicated different sorption domains due to their different structure and hydrophobicity. The positive relationship between (O + N)/C ratios of NHC and atrazine log K_O_C at low concentration suggests H-bonding interactions. This study shows that sediment is probably a less effective sorbent for atrazine than Phen, implying that atrazine applied in sediments or soils may be ...

Energy Technology Data Exchange (ETDEWEB)

A conceptual hydrodynamic model in the Holocene and upper Pleistocene beneath the Louisiana wetlands is described in terms of safety distributions. Porewater safety is calculated from electrical measurements, including resistivity soundings, electric logs, and electromagnetic profiling. Electrical measurements support the primary, basin-wide groundwater flow model; however, the data also indicate secondary contributions from expulsion of fluids under geopressure along active growth faults and from original waters of deposition. Expulsion of water from growth faults has been described previously for deeper sections of the Pleistocene, but has not been reported for the Holocene or upper Pleistocene beneath the Louisiana wetlands. Porewater chemistry variations beneath the coastal wetlands are a consequence of the following (in order of importance): (1) environment of deposition; (2) a basin-wide, regional flow system; (3) expulsion from deep-seated growth faults; and ...

Energy Technology Data Exchange (ETDEWEB)

The US Department of Energy (DOE) has millions of gallons of high level nuclear waste stored in underground tanks at Hanford, Washington and Savannah River, South Carolina. These tanks will eventually be emptied and decommissioned. This will leave a residue of sludge adhering to the interior tank surfaces that may contaminate nearby groundwaters with radionuclides and RCRA metals. Performance assessment (PA) calculations must be carried out prior to closing the tanks. This requires developing radionuclide release models from the sludges so that the PA calculations can be based on credible source terms. These efforts continued to be hindered by uncertainties regarding the actual nature of the tank contents and the distribution of radionuclides among the various phases. In particular, it is of vital importance to know what radionuclides are associated with solid sludge components. Experimentation on actual tank sludges can be difficult, dangerous and prohibitively ...

Energy Technology Data Exchange (ETDEWEB)

Commercial development of oil shale resources will produce vast quantities of processed shale waste. The presence of potentially toxic trace elements, inorganic salts, and potentially toxic residual organic constitutents make the disposal of vast quantities of processed shale a potential environmental problem. To be environmentally acceptable, processed shale disposal must: result in a physically stable structure, prevent or minimize release of potentially toxic compounds, and provide an economically acceptable post-land use. Water is the common element underlying all factors important to the environmental stability of disposed solid waste. The leaching and transport of solubles by water in processed shale embankments may result in degradation of local surface and groundwater quality. The major purpose of this research is to physically model, study, and describe the redistribution and movement of water and percolates in lifts of disposed processed oil shale under ...

Energy Technology Data Exchange (ETDEWEB)

This study examines the sensitivity of the travel time distribution predicted by a reference case model to (1) scale of representation of the model parameters, (2) size of the model domain, (3) correlation range of log-transmissivity, and (4) cross correlations between transmissivity and effective thickness. The basis for the reference model is the preliminary stochastic travel time model previously documented by the Basalt Waste Isolation Project. Results of this study show the following. The variability of the predicted travel times can be adequately represented when the ratio between the size of the zones used to represent the model parameters and the log-transmissivity correlation range is less than about one-fifth. The size of the model domain and the types of boundary conditions can have a strong impact on the distribution of travel times. Longer log-transmissivity correlation ranges cause larger variability in the predicted travel times. Positive cross correlation between ...

Energy Technology Data Exchange (ETDEWEB)

This Baseline Risk Assessment report is the second volume in a set of three volumes for operable Unit 1 (OU-1). The companion documents contain the Remedial Investigation and the Feasibility Study. Operable Unit 1 (OU-1) is one of several groups of hazardous waste sites located at Eielson Air Force Base (AFB) near Fairbanks, Alaska. The operable units at Eielson are typically characterized by petroleum, oil, lubricant/solvent contamination, and by the presence of organics floating at the water table. In 1989 and 1990, firms under contract to the Air Force conducted field studies to gather information about the extent of chemical contamination in soil, groundwater, and soil air pore space (soil gas) at the site. This report documents the results of a baseline risk assessment, which uses the 1989 and 1991 site characterization database to quantify the potential human health risk associated with past Base industrial activities in the vicinity of OU-1. Background data ...

Energy Technology Data Exchange (ETDEWEB)

The Department of Energy`s Office of Technology Development initiated an Integrated Demonstration Program at the Savannah River Site in 1989. The objective of this program is to develop, demonstrate, and evaluate innovative technologies that can improve present-day environmental restoration methods. The Integrated Demonstration Program at SRS is entitled ``Cleanup of Organics in Soils and Groundwater at Non-Arid Sites.`` New technologies in the areas of drilling, characterization, monitoring, and remediation are being demonstrated and evaluated for their technical performance and cost effectiveness in comparison with baseline technologies. Present site characterization and monitoring methods are costly, time-consuming, overly invasive, and often imprecise. Better technologies are required to accurately describe the subsurface geophysical and geochemical features of a site and the nature and extent of contamination. More efficient, nonintrusive characterization and ...

Energy Technology Data Exchange (ETDEWEB)

An innovative horizontal drilling system was used to install two horizontal wells as part of an integrated demonstration project at the Savannah River Site (SRS), Aiken, South Carolina. The SRS is located in south-central South Carolina in the upper Coastal Plain physiographic province. The demonstration site is located near the A/M Area, and is currently known as the Integated Demonstration Site. The Department of Energy`s Office of Technology Development initiated an integrated demonstration of innovative technologies for cleanup of volatile organic compounds (VOCS) in soils and groundwater at the SRS in 1989. The overall goal of the program is to demonstrate, at a single location, multiple technologies in the fields of drilling, characterization, monitoring, and remediation. Innovative technologies are compared to one another and to baseline technologies in terms of technical performance and cost effectiveness. Transfer of successfully demonstrated technologies ...

Energy Technology Data Exchange (ETDEWEB)

This paper provides an overview of environmental cleanup at the Los Alamos National Laboratory (LANL) and some of the unique aspects and challenges. Cleanup of the 65-year old Department of Energy Laboratory is being conducted under a RCRA Consent Order with the State of New Mexico. This agreement is one of the most recent cleanup agreements signed in the DOE complex and was based on lessons learned at other DOE sites. A number of attributes create unique challenges for LANL cleanup -- the proximity to the community and pueblos, the site's topography and geology, and the nature of LANL's on-going missions. This overview paper will set the stage for other papers in this session, including papers that present: Plans to retrieve buried waste at Material Disposal Area B, across the street from oen of Los Alamos' commercial districts and the local newspaper; Progress to date and joint plans with WIPP for disposal of the remaining inventory of legacy transuranic ...

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WASAG DECON developed a concept for the biological in situ remediation of an TNT-contaminated former seepage pond. This pond is located on the site of an ammunition factory in Lower Saxony. Unit 1982 all the waste water from the production buildings was directed into this pond, including TNT-contaminated water from the flushing of shells. Due to this practice, the sediment of the pond, the underlying soil and the groundwater became contaminated with TNT. The area of the soil contamination adds to abut 2.000 m{sup 2}. The remediation concept includes three steps: 1. Excavation of the most highly contaminated soil with TNT-concentrations above 1000 mg/kg. 2. Reduction of the remaining contamination by a biological in situ treatment using organic and inorganic amendments and mechanical tillage. After about to years of treatment, remediation goals of 50 mg/kg are expected to be reached on most of the area. 3. Contaminations eventually remaining in deeper soil layers ...

Science.gov (United States)

In this study, adjoint sensitivity theory is developed for equations of two-dimensional steady-state flow in a confined aquifer. Both the primary flow equation and the adjoint sensitivity equation are solved using the Galerkin finite element method. The developed computer code is used to investigate the regional flow parameters of the Leadville Formation of the Paradox Basin in Utah and the Wolcamp carbonate/sandstone aquifer of the Palo Duro Basin in the Texas Panhandle. Two performance measures are evaluated, local heads and velocity in the vicinity of potential high-level nuclear waste repositories. The results illustrate the sensitivity of calculated local heads to the boundary conditions. Local velocity-related performance measures are more sensitive to hydraulic conductivities. The uncertainty in the performance measure is a function of the parameter sensitivity, parameter variance and the correlation between parameters. Given a parameter covariance matrix, the uncertainty of the ...

International Nuclear Information System (INIS)

Full text.Changes in land use and urbanization yield more pressure put on limited soil and water resources, including the risk of pollution with toxic heavy metals. The study area lies in the Bekaa valley totaling about 12753 ha. The valley receives from the west torrential fan deposits and a mixture of colluvial and alluvial material. The principal soil classes are Fluvisols, Cambisols, Regosols, Vertisols and Luvisols. The area is populated and also the most important agricultural part of the plain. Agriculture in the plain is being practiced mainly with cash, field crops and vegetables. The western surrounding area is being used mainly for terraced fruit trees. This Arab-German Technical Cooperation Project (ACSAD-BGR) aimed, following the ISO standards and Eikman-Klocke recommendations, at investigating the nature of the extends of soil pollution by heavy metals in two pilot areas: The central Bekaa-Lebanon and Ghouta-Damascus. Different institutions cooperate in the implementation ...

Energy Technology Data Exchange (ETDEWEB)

In early 2004, the U.S. Department of Energy (DOE) Richland and Fluor Hanford requested technical assistance from the DOE Headquarters EM-23 Technical Assistance Program to provide a team of technical experts to develop recommendations for mending the In Situ Redox Manipulation (ISRM) Barrier in the 100-D Area of the Hanford Site in Washington State. To accommodate this request, EM-23 provided support to convene a group of technical experts from industry, a national laboratory, and a DOE site to participate in a 2 1/2-day workshop with the objective of identifying and recommending options to enhance the performance of the 100-D Area reactive barrier and of a planned extension to the northeast. This report provides written documentation of the team's findings and recommendations. In 1995, a plume of dissolved hexavalent chromium [Cr(VI)], which resulted from operation of the D/DR Reactors at the Hanford site, was discovered along the Columbia River shoreline and in the 100-D ...

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TRITEX was a pumped loop with Pb-15.8Li, fabricated from steel 1.4922. In contact with the molten eutectic were also molybdenum, vanadium and armco-iron. The loop was originally designed to investigate tritium extraction using solid getter metals. Over the years the goal changed to the study of metals, corrosion products and purification of the eutectic mixture. Therefore many modifications were done. The first part of this report describes TRITEX. All parts were enclosed in thermoboxes for a homogeneous temperature. One test section was in an argon glove box and could be opened during operation. Other special equipment`s were: permeation membranes and liquid-metal-covergas-interfaces to study the transport of H{sub 2}, D{sub 2} and {sup 3}H, different purification devices, a quartz observation window to see the liquid metal surface, 4 different kinds of flow measurements, level indicators, freeze valves. The second part describes loop ...

Science.gov (United States)

PCR detection of genetic material of the parasites present in faeces may be an alternative for microscopic and serological tests routinely used for diagnosing parasitic enteral infections. However, small amount of target DNA combined with low efficiency of total DNA extraction, and presence of PCR inhibitors in the samples to be amplified, may cause false negative detection results. The aim of this work was to evaluate the impact of DNA isolation procedure used on the amplification of DNA fragments from the genomes of protozoan Cryptosporidium parvum and the nematode Trichinella spiralis. Two methods based on different principles of biological material lysis were evaluated; NucliSENS miniMAG employing simultaneously applied chemical lysis and mechanical disruption or mechanical disruption followed by enzymatic lysis in case of QIAamp DNA Stool Mini Kit. Both of the analyzed systems for nucleic acids purification allowed isolation of DNA from purified ...

Energy Technology Data Exchange (ETDEWEB)

From 1991 to 1996, key studies on the reutilization, treatment, and disposal technology of hazardous wastes have been incorporated into the national plan for environmental protection science and technology. At present, the research achievements have been accomplished, have passed national approval, and have been accepted. The author of this paper, as leader of the national group for this research work, expounds the newest achievements of the studies involving four parts: (1) the reutilization technology of electroplating sludge, including the ion-exchange process for recovering the sludge and waste liquor for producing chromium tanning agent and extracting chromium and colloidal protein from tanning waste residue; on the recovery of heavy metals from the electroplating waste liquor with microbic purification; on the demonstration project of producing modified plastics from the sludge and the waste plastics; and on the demonstration of the recovery of heavy metals ...

Energy Technology Data Exchange (ETDEWEB)

Coal liquefaction investigations required the availability of model compounds for mechanistic investigations. Towards this end, IITRI was funded to develop an approach for the synthesis of one of the target compound. This study was carried out in several phases as outlined here. Initial synthetic investigations on obtaining 2-tetrolol was carried out using high pressure and temperature reduction with Raney nickel catalyst. The next step consisted in incorporation of a hydroxymethyelene group at the C-3 position. This was successfully carried out utilizing 2-tetrolol, formaldehyde, and calcium oxide. An alternate improved method was developed using 3-carboxyl-2-naphthol. This required less time, gave a cheer product in higher yield. Efforts at the introduction of a chloromethylene group only yielded polymeric material or starting material in spite of protection the phenolic group by various groups. They synthesis of 3, 5-dimethyl-6- bromobenzyl chloride was successfully carried out by ...

Science.gov (United States)

The strategy for building SASOL plants reflects a commitment to long-range planning. The first plant, which represented a large investment for a moderate production capacity, was built to establish a technology for reducing South Africa's dependence on imported motor fuels. After the success of the plant, SASOL made plans for a larger plant, which had to be justified solely on economic grounds. At that time, petroleum crude was cheap and plentiful, and the second plant was cancelled. But when OPEC formed and the price of petroleum crude was increased, the South African government reconsidered the plans for another SASOL plant. Furthermore, because the cost of fuels produced at Sasol I proved to be significantly insensitive to inflation and future OPEC price increases were expected, SASOL projected that a new, larger plant should make a profit within a few years after its initial operation. But OPEC prices and inflation have risen even faster than anticipated, and the products ...

International Nuclear Information System (INIS)

Full text: There are following general tendencies linking to SNF and radioactive waste management (RWM) in the Russian nuclear industry now. The intention to use the closed nuclear fuel cycle based on power water reactors and fast reactor. The intensification of measures aimed at the solution of 'nuclear legacy' from defenses programs of USSR. The intention to improve the existing national RW management infrastructure in the near years by means of the creation of a centralized national system (including managing corporation responsible for operation of long-storage and disposal facilities of conditioned RW). The main aims radioactive waste management (RWM) in nuclear power plants (NPP) for the next 10-15 years are to equip all NPPs with the necessary set of facilities for conditioning of the stored and currently generated RW with packaging the end-product into containers, to build regional NPPs RW repositories and to introduce evaporator bottoms selective ...

Energy Technology Data Exchange (ETDEWEB)

A cryogenic separation method of chloromethane (CH{sub 3}Cl) from methyl iodide (CH{sub 3}I) for {delta}{sup 37}Cl measurement with isotope ratio mass spectrometer is described. A cold trap with sealed 2,2,4-trimethylpentane (TMP) as the cryogen is used in this method. CH{sub 3}Cl can be separated from CH{sub 3}I at the TMP melting point (-107 deg. C) based on the difference in the vapor pressure between CH{sub 3}Cl (322.6 Pa) and CH{sub 3}I (lower than 1.3 Pa) at -107 deg. C. After two-step separation processes, the yields of CH{sub 3}Cl purified from CH{sub 3}Cl-CH{sub 3}I mixture are 96-101%, and the difference between the {delta}{sup 37}Cl{sub original} and {delta}{sup 37}Cl{sub Afterseparation} is from -0.06 to +0.06 per mille (0.01 {+-} 0.04 per mille ). These results suggest that CH{sub 3}Cl is completely separated from CH{sub 3}I with no change of {delta}{sup 37}Cl value. This method using the cold trap with sealed TMP is very safe and not harmful, because the liquid organic ...

International Nuclear Information System (INIS)

The tendency of welded joints from 10Kh14AG15 and 10Kh14AG9 steels to pitting corrosion under the conditions of operating blast-furnace gas purification scrubbers has been investigated. Water in scrubbers contains various quantities of chlorides and sulfates, has pH from 6 to 9 and temperature 65-75 deg. The laboratory corrosion tests have been carried out also on samples turned from the heat-affected zone (h.a.z.) of welded plates at 20 and 65 deg. Anode polarization curves have been read from the Vk corrosion potential at potential shifting rate 0.01 V/min. It is established that in most rigid conditions of scrubbers operating pitting corrosion (PC) rate of chrome-manganese nitrogen-containing steel can reach 2.5 mm/year. At high content of chlorides in water the elevated temperature and external tensile stresses intensify PC. The resistance of welded joints to PC when using welding materials on chromonickel molybdenum base is determined in the first place by ...

International Nuclear Information System (INIS)

Addition of Gadolinium Nitrate as chemical shim to moderator heavy water of 540 MWe PHWR, at 15 mg/kg level (at a pH of 5.0) is practiced for reactor shutdown purposes. Presently a strong acid cation exchanger column is used for this purpose. During this operation, the moderator pH of 3.8, with the IX column outlet pH of ?3.5-3.6 was observed against the technical specification demand that when Gd is present, the pH of moderator must be in the range of 5.0-5.5. In order to achieve an iso-pH regime during Gd removal, studies were conducted using a mixed bed of strong acid cation resin plus a weak base anion resin (loaded in the volume ratio of 1 : 6), backed up in the same column (bottom most layer) by a 5 % nitric acid loaded weak base resin and topped by a strong acid cation resin (uppermost layer) simulating system flow velocity and percentage loading of resin. Using such a column it is demonstrated that Gd removal could be achieved simultaneously maintaining the water chemistry ...

Science.gov (United States)

From the dried fruiting bodies of the mushroom Armillaria luteo-virens, a dimeric lectin with a molecular mass of 29.4 kDa has been isolated. The purification procedure involved (NH{sub 4}){sub 2}SO{sub 4} precipitation, ion exchange chromatography on DEAE-cellulose, CM-cellulose, and Q-Sepharose, and gel filtration by fast protein liquid chromatography on Superdex 75. The hemagglutinating activity of the lectin could not be inhibited by simple sugars but was inhibited by the polysaccharide inulin. The activity was stable up to 70 {sup o}C but was acid- and alkali-labile. Salts including FeCl{sub 3}, AlCl{sub 3}, and ZnCl{sub 2} inhibited the activity whereas MgCl{sub 2}, MnCl{sub 2}, and CaCl{sub 2} did not. The lectin stimulated mitogenic response of mouse splenocytes with the maximal response achieved by 1 {mu}M lectin. Proliferation of tumor cells including MBL2 cells, HeLa cells, and L1210 cells was inhibited by the lectin with an IC{sub 5} of 2.5, 5, and 10 ...

Energy Technology Data Exchange (ETDEWEB)

Rapid detection and characterization of food borne pathogens such as Escherichia coli O157:H7 is crucial for epidemiological investigations and food safety surveillance. As an alternative to conventional technologies, we examined the sensitivity and specificity of nucleic acid microarrays for detecting and genotyping E. coli O157:H7. The array was composed of oligonucleotide probes (25-30 mer) complementary to four virulence loci (intimin, Shiga-like toxins I and II, and hemolysin A). Target DNA was amplified from whole cells or from purified DNA via single or multiplexed polymerase chain reaction (PCR), and PCR products were hybridized to the array without further modification or purification. The array was 32-fold more sensitive than gel electrophoresis and capable of detecting amplification products from < 1 cell equivalent of genomic DNA (1 fg). Immunomagnetic capture, PCR and a microarray were subsequently used to detect 55 CFU ml-1 (E. coli O157:H7) ...

Energy Technology Data Exchange (ETDEWEB)

A cytochrome P450 that hydroxylates lauric acid at the 12 position (P450LA omega) was isolated from liver microsomes of clofibrate treated rats. P450LA omega was immunologically distinct from P450s a,b,c,d,e,f,g,h,j,PB1, and PCN1. Polyclonal antibody against P450LA omega was utilized to screen a gt11 cDNA library. A clone (pP450LA omega), was isolated and its sequence determined. The P450LA omega mRNA is a minimum 2387 nts in length and codes for a P450 of Mr.58,222 daltons. This protein shares less than 35% amino acid similarity with P450s b,c,d,e,f,PB1, and PCN1; however, it does contain a hydrophobic amino terminal peptide and a conserved sequence surrounding the Cys residue at position 456, which is similar to other microsomal P450s. P450LA omega is present at high levels in untreated rat kidney and is induced by clofibrate in both kidney and liver. This induction is the result of an accumulation of mRNA through a rapid transcriptional activation of the P450LA gene. Southern ...

Science.gov (United States)

MnO2 in pyrolusite can react with SO2 in flue gas and obtain by-product MnSO4 x H2O. A pilot scale jet bubbling reactor was applied in this work. Different factors affecting both SO2 absorption efficiency and Mn2+ extraction rate have been investigated, these factors include temperature of inlet gas flue, ration of liquid/solid mass flow rate (L/S), pyrolusite grade, and SO2 concentration in the inlet flue gas. In the meantime, the procedure of purification of absorption liquid was also discussed. Experiment results indicated that the increase of temperature from 30 to 70 K caused the increase of SO2 absorption efficiency from 81.4% to 91.2%. And when SO2 concentration in the inlet flue gas increased from 500 to 3000 ppm, SO2 absorption efficiency and Mn2+ extraction rate decreased from 98.1% to 82.2% and from 82.8% to 61.7%, respectively. The content of MnO2 in pyrolusite had a neglectable effect on SO2 absorption efficiency. Low L/S was good for both removal of ...

Science.gov (United States)

Understanding climate development in the central Andes is important in determining the relationship between mountain range uplift and climate change. Recent work along the western margin of the central Andes has led to the development of two competing hypotheses: 1) that climate change is directly responsible for uplift or 2) that uplift controls climate change. In the first scenario, uplift results from increased friction at the plate boundary due to sediment-starvation of the trench which is a function of decreased run-off (particularly post 14 Ma) due to global cooling. In the second scenario progressive uplift of the Andean Cordillera during the Miocene resulted in a strong orographic effect with a concomitant rainshadow west of the Andes. To determine the relationship between climate change and uplift it is necessary to ascertain precisely, when the climate changed, the nature of that change and when uplift occurred. With respect to climate change a key question that has been ...