International Nuclear Information System (INIS)

A pretreatment flowsheet was tested for separating key radionuclide components from the sludge stored in one of the high level waste tanks (B-110) at the Hanford Site; this sludge resulted primarily from the bismuth phosphate process, which was one of the three major plutonium separation processes used at Handford. This test involved (1) washing with water, (2) caustic leaching, (3) acid dissolution, (4) separation of transuranic elements (TRUs) by extraction with octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide(CMPO), (5) separation of Sr by extraction with di-t-butylcyclohexano-18-crown-6, (6) separation of Cs from the acid-dissolved sludge solution by treatment with ammonium molybdophosphate (AMP), and (7) separation of Cs from the sludge wash and caustic leach solutions by ion exchange ...

Energy Technology Data Exchange (ETDEWEB)

This document reports on the work done by the Separations Science and Technology Programs of the Chemical Technology Division, Argonne National Laboratory, in the period April-September 1992. This effort is mainly concerned with developing the TRUEX process for removing and concentrating actinides from acidic waste streams contaminated with transuranic (TRU) elements. The objectives of TRUEX processing are to recover valuable TRU elements and to lower disposal costs for the nonTRU waste product of the process. Two other projects are underway with the objective of developing (1) a membrane-assisted solvent extraction method for treating natural and process waters contaminated by volatile organic compounds and (2) evaporation technology for concentrating radioactive waste and product streams such as those generated by the TRUEX process.

Science.gov (United States)

Enthalpy relaxation properties of the ethylene glycol (EG) aqueous solutions confined within silica-gel void spaces of 1.1 nm in the average void thickness and 6, 12 and 52 nm in their average diameters were examined by an adiabatic calorimetry to understand the glass transition behavior of the solutions and the rearrangement processes of the molecules. The glass transition temperature Tg of EG was found to decrease with adding the water molecules which are mobile under the condition lacking in the full hydrogen-bond network. Meanwhile, the Tg in the water-rich region showed a rise towards pure water; after a phase separation in a 25 mol% (x = 0.25) EG solution, the Tg was 160 K which was higher than that derived by extrapolating the composition dependence to pure water. The Tg = 160 K is the same as observed in the pure water confined ...

International Nuclear Information System (INIS)

The 1993 Petroleum Hydrocarbons Conference was comprised of 3 days of technical presentations within the following topic areas: pollution prevention and cost control; development of remediation levels; free-phase and dissolved hydrocarbon contamination management; investigation and analysis of petroleum hydrocarbons; applications of computer modeling for remediation; design and implementation of bioventing; design and implementation of air sparging; soil vapor extraction as a remediation technique; and ground water remediation using natural bacteria. In addition, more than 100 leading companies in the ground water and petroleum industries participated in the Conference Exposition in which a variety of equipment and services for preventing, detecting and remediating ground water contaminated by petroleum hydrocarbons and other organic chemicals was showcased. Individual papers have been processed ...

Energy Technology Data Exchange (ETDEWEB)

A fusion reactor (such as NET/ITER) which breeds its own tritium fuel requires tritium recovery, purification and separation from the other isotopes. Cyclic adsorption processes are strong candidates for several of the processes involved: amongst other advantages, they promise a low tritium inventory. A good adsorbent for such processes must have high adsorption capacity, high selectivity and very low tritium retention after each cycle. Pure zeolite powder is shown to have an excellent combination of these three properties. However, in practice problems can arise from tritium which is not removed by reactivation. In this paper we show that tritium retention in zeolites can be caused either by water retained in the zeolite structure, which can be removed by ore rigorous activation, or by water tapped on binders in commercial pellets. (orig.).

International Nuclear Information System (INIS)

A chemical-looping process is proposed for the clean combustion of solid fuels for electric power or heat generation. The process is based on coal gasification with CO_2 to produce CO. The CO then reduces CaSO_4, which is used as an oxygen carrier, in a separate reactor to give CaS and CO_2. A portion of the CO_2 is recycled for the gasification stage and the rest can be sent for sequestration. The CaS is sent to another reactor for oxidation with air and to generate heat or power. The overall thermal effect is the same as direct combustion, but separation of CO_2 and other pollutants, such as sulphur, is achieved. In comparison with conventional chemical-looping combustion of natural gas, much less water is present in the CO_2 product, and hence the loss of heat energy and corrosion of the fuel-reactor system can be reduced.

Energy Technology Data Exchange (ETDEWEB)

Production of hydrogen sulfide in produced waters due to the activity of sulfate-reducing bacteria (SRB) is a potentially serious problem. The hydrogen sulfide is not only a safety and environmental concern, it also contributes to corrosion, solids formation, a reduction in produced oil and gas values, and limitations on water discharge. Waters produced from seawater-flooded reservoirs typically contain all of the nutrients required to support SRB metabolism. Surface processing facilities provide a favorable environment in which SRB flourish, converting water-borne nutrients into biomass and H{sub 2}S. This paper will present results from a field trial in which a new technology for the biochemical control of SRB metabolism was successfully applied. A slip stream of water downstream of separators on a produced water ...

International Nuclear Information System (INIS)

The ELEX process for isotopic enrichment and separation of tritium from aqueous reprocessing effluents is described. After the development of an appropriate hydrophobic catalyst and the study of the separate constituent steps of the ELEX process, an integrated bench-scale installation with a detritiation capacity of 10 mol water per hour was constructed. It comprises essentially a 1.5 kW electrolyser and two 2 cm diameter by 3 m high exchange columns. In this mini-pilot the ELEX process was successfully demonstrated by detritiating more than 1000 dm"3 water containing up to 100 mCi tritium per dm"3, which is the feed concentration expected for application of the process in a reprocessing plant. The process decontamination factor was always larger than 100 and the overall tritium balance could be kept ...

International Nuclear Information System (INIS)

The multidimensional countercurrent two-phase flow regimes that occur in a pressurized-water reactor (PWR) vessel downcomer during the refill phase of a large-break loss-of-coolant accident are studied using a transparent 1/10 scale model of a PWR vessel. The various flow regimes and their distribution in the downcomer have been identified and mapped for a range of air-water flooding experiments. The two-phase flow patterns that are identified in the downcomer included various types of film flows, droplet flows, countercurrent churn flows and cocurrent flows depending on the flooding condition. Through observation of the two-phase flow dynamics it was deduced that the physical mechanisms associated with the flooding processes could be separated into a liquid entrainment process and a film flow reversal process. In addition to the above exercise, the effect of ...

Energy Technology Data Exchange (ETDEWEB)

A new organic-inorganic hybrid membrane has been prepared with exceptional performance in dewatering applications. The only precursor used in the sol-gel synthesis of the selective layer was organically linked 1,2-bis(triethoxysilyl)ethane (BTESE). The microporous structure of this layer enables selective molecular sieving of small molecules from larger ones. In the dehydration of n-butanol with 5% of water, the membrane shows a high separation factor of over 4000 and ultra-fast water transport at a rate of more than 20 kg m{sup -2} h{sup -1} at 150C. This can be related to the high adsorption capacity of the material and the sub-micron thickness of the selective layer. The selectivity has now remained constant over almost one and a half years under continuous process testing conditions. Apart from the hydrothermal stability, the membrane exhibits a high tolerance for acid contamination. A slow ...

Energy Technology Data Exchange (ETDEWEB)

The potential for detoxification and deodorization of sulfide-laden water (sour water) by microbial treatment was evaluated at a petroleum production site under field conditions. A sulfide-tolerant strain of the chemautotroph and facultative anaerobe, Thiobacillus denitrificans, was introduced into an oil-skimming pit of the Amoco Production Company LACT 10 Unit of the Salt Creek Field, Wyoming. Field-produced water enters this pit from the oil/water separation treatment train at an average flowrate of 5,000 bbl/D (795 m{sup 3}/D) with a potential maximum of 98,000 bbl/D (15,580 m{sup 3}/D). Water conditions at the pit inlet are 4,800 mg/l TDS, 100 mg/l sulfide, pH 7.8, and 107{degrees}F. To this water an aqueous solution of ammonium nitrate and diphosphorous pentoxide was added to provide required nutrients for the bacteria. The first 20% ...

Energy Technology Data Exchange (ETDEWEB)

A numerical investigation of a humidification dehumidification desalination (HDD) process using solar energy is presented. The HDD system consists mainly of a concentrating solar water heating collector, flat plate solar air heating collector, humidifying tower and dehumidifying exchanger. Two separate circulating loops constitute the HDD system, the first for heating the feed water and the second for heating air. A mathematical model is developed, simulating the HDD system, to study the influence of the different system configurations, weather and operating conditions on the system productivity. The model validity is examined by comparing the theoretical and experimental results of the same authors. It is found that the results of the developed mathematical model are in good agreement with the experimental results and other published works. The results show also that the productivity of the unit is ...

British Library Electronic Table of Contents (United Kingdom)

In this work, chromatographic separation of niacin and niacinamide using pure water as the sole component in the mobile phase has been investigated. The separation and analysis of niacinamide have been optimized using three columns at different temperatures and various flow rates. Our results clearly demonstrate that separation and analysis of niacinamide from skincare products can be achieved using pure water as the eluent at 60^oC on a Waters XTerra MS C18 column, a Waters XBridge C18 column, or at 80^oC on a Hamilton PRP-1 column. The separation efficiency, quantification quality, and analysis time of this new method are at least comparable with those of the traditional HPLC methods. Compared with traditional HPLC, the major advantage of this newly developed green chromatography techniq...

Energy Technology Data Exchange (ETDEWEB)

This project dealt with use of condensing heat exchangers to recover water vapor from flue gas at coal-fired power plants. Pilot-scale heat transfer tests were performed to determine the relationship between flue gas moisture concentration, heat exchanger design and operating conditions, and water vapor condensation rate. The tests also determined the extent to which the condensation processes for water and acid vapors in flue gas can be made to occur separately in different heat transfer sections. The results showed flue gas water vapor condensed in the low temperature region of the heat exchanger system, with water capture efficiencies depending strongly on flue gas moisture content, cooling water inlet temperature, heat exchanger design and flue gas and cooling water flow rates. Sulfuric acid ...

Energy Technology Data Exchange (ETDEWEB)

In processes of this invention aqueous waste solutions containing a variety of mixed waste contaminants are treated to remove the contaminants by a sequential addition of chemicals and adsorption/ion exchange powdered materials to remove the contaminants including lead, cadmium, uranium, cesium-137, strontium-85/90, trichloroethylene and benzene, and impurities including iron and calcium. Staged conditioning of the waste solution produces a polydisperse system of size enlarged complexes of the contaminants in three distinct configurations: water-soluble metal complexes, insoluble metal precipitation complexes, and contaminant-bearing particles of ion exchange and adsorbent materials. The volume of the waste is reduced by separation of the polydisperse system by cross-flow microfiltration, followed by low-temperature evaporation and/or filter pressing. The water produced as filtrate is discharged if it ...

Energy Technology Data Exchange (ETDEWEB)

This project of law concerns an additional protocol to the agreement of warranties signed on September 22, 1998 between France, the European atomic energy community and the IAEA. This agreement concerns the declaration of all information relative to the R and D activities linked with the fuel cycle and involving the cooperation with a foreign country non endowed with nuclear weapons. These information include the trade and processing of nuclear and non-nuclear materials and equipments devoted to nuclear reactors (pressure vessels, fuel loading/unloading systems, control rods, force and zirconium tubes, primary coolant pumps, deuterium and heavy water, nuclear-grade graphite), to fuel reprocessing plants, to isotope separation plants (gaseous diffusion, laser enrichment, plasma separation, electromagnetic enrichment), to heavy water and deuterium production plants, and to uranium ...

Energy Technology Data Exchange (ETDEWEB)

A membrane process utilizing dialysis and selective complexation by water-soluble polymers has been developed. This process, termed affinity dialysis, has been shown to be selectively extract and concentrate both cations and anions in a manner similar to ion exchange or solvent extraction. The selective removal of calcium from sodium with selectivity of about 30, removal of chromate ion from dilute streams, and separation of transition metal ions such as Cu/Fe and Cu/Zn have all been successfully demonstrated. Effects of different polymers, polymer concentration, temperature, and flow rates have been studied. The effect of increased polymer concentration is to increase product concentration if appropriate changes in feed, polymer solution, and strip flow rates are made. A continuous polymer solution recycle and regeneration system has been constructed and operated with Cu/Zn and chromate/chloride feed ...

Energy Technology Data Exchange (ETDEWEB)

This is the final report of a two-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). This project has examined the fundamental chemistry of plutonium that affects the integration of hydrothermal technology into nuclear materials processing operations. Chemical reactions in high temperature water allow new avenues for waste treatment and radionuclide separation.Successful implementation of hydrothermal technology offers the potential to effective treat many types of radioactive waste, reduce the storage hazards and disposal costs, and minimize the generation of secondary waste streams. The focus has been on the chemistry of plutonium(VI) in solution with carbonate since these are expected to be important species in the effluent from hydrothermal oxidation of Pu-containing organic wastes. The authors investigated the structure, solubility, and stability of the key ...

Energy Technology Data Exchange (ETDEWEB)

This patent describes a process for removing carbon dioxide from a feed stream of natural gas having at least methane, ethane and heavier. It comprises: first, separating the feed stream in a first separator to form a first stream having substantially all of the propane and heavier hydrocarbons and carbon dioxide and ethane and a second stream, having methane, carbon dioxide and ethane; separating the second stream in a second separator into a stream of carbon dioxide product and a third stream having ethane, methane and carbon dioxide: mixing at least a portion of the third stream with a polar compound; stream after the mixing in an absorber; separating the vapor and liquid of the third stream after the mixing in an absorber; absorbing the remaining unabsorbed carbon dioxide in a lean portion of the polar compound in the absorber, the absorber carbon dioxide ...

International Nuclear Information System (INIS)

The possibility of separation in plasma-mass-separator POMS-E-3 spent nuclear fuel (SNF) in 3 fractions: transuranic elements, and two groups of fission products. New scheme of compact energy-mass analyzer for monitoring the separation process spent nuclear fuel in the POMS-E- 3 offered.

Science.gov (United States)

Jun 16, 2011 ... Title: Chapter 21: Oceanographic Processes and Marine Productivity in Waters Offshore of Marbled Murrelet Breeding Habitat ...

International Nuclear Information System (INIS)

Development of the engineering technology basis of pyrometallurgical reprocessing is a key issue for industrialization. For development of the transport technologies of molten salt and liquid cadmium at around 773 K, a salt transport test rig and a metal transport test rig were newly installed in an Ar glove box. Function of the salt transport test rig was confirmed with LiCl-KCl molten salt, and the transport behaviour of molten salt was found to follow that of water. The molten salt/liquid metal contactor for Ln/An separation was newly designed and installed. The test with a single-stage contactor was successful with simulated elements, and a three-stage contactor is now under development. A large-scale electro-refiner with a function to transport molten salt and liquid cadmium were newly designed, and to be installed for demonstration test with simulated materials. (authors)

Science.gov (United States)

Isotope separation of Ar, C, /sup 3/He, Kr, Ne, O, and Xe isotopes is reported. TiFeH/sub x/, TiCoH/sub x/, TiCuH/sub x/, and VH/sub x/ were studied using NMR (proton relaxation times). VD/sub x/ and VT/sub x/ were synthesized. The problem of calculating the valence state of Pu is discussed. A series solution to the plutonium (N,H) characteristic equation is suggested. Shipments of /sup 231/Pa, /sup 230/Th, and /sup 229/Th are reported. Separation and processing of /sup 234/U are also reported. Theoretical methods were developed to calculate temperature distributions as functions of water flow rate in liquid thermal diffusion columns. Diffusion coefficients were measured from 300 to 1200/sup 0/K for Kr-Xe and Kr-Ar. New thermal diffusion factors are submitted for Ne-Ar.

Energy Technology Data Exchange (ETDEWEB)

Among the membrane filtration techniques, continuous cross-flow ultrafiltration (UF) is an innovative method to separate solid/liquid or liquid/liquid phases at a lower pressure of 5--150 psi compared to reverse osmosis (RO) in which the applied pressure is an order of magnitude higher. Recently, attempts have been made to combine processes of UF and other treatments for many applications. However, there is very little knowledge about the filtration process which combined coagulation and UF, and very few attempts have been made to apply coagulated UF to the treatment of fuel oil contaminated water. During the UF treatment of organic contaminants rapid declines in flux will occur due to the membrane fouling. Oil as a foulant plants an important role in the flux decrease. However, there are very limited pretreatment processes which can effectively remove fuel oil from ...

Energy Technology Data Exchange (ETDEWEB)

A new method for the separation and determination of trace amounts of cadmium and zinc in water as their thenoyltrifluoroacetone (TTA) complexes with dibenzo-18-crown-6 (DB18C6) in o-dichlorobenzene has been established by means of synergistic extraction and back-extraction combined with atomic absorption spectrometry. The effect of various factors (synergism with TTA and DB18C6, shaking time, composition of the extracted species, and mutual separation etc.) on the extraction and back-extraction of cadmium and zinc has been in- vestigated. When the mixtures were extracted for 4 min at pH 4.9, only zinc was extracted quantitatively, whereas cadmium remained in the aqueous phase. After the phases were separated, cadmium was again extracted quantitatively at pH 7.5. Then, the two phases were each shaken with 0.05-0.1 mol/l HCl in order to back-extract cadmium and zinc from the organic phases; the ions were ...

Energy Technology Data Exchange (ETDEWEB)

Biocatalytic Desulfurization (BDS) represents an alternative approach to the reduction of sulfur in fossil fuels. The objective is to use bacteria to selectively remove sulfur from petroleum and middle distillate fractions, without the concomitant release of carbon. Recently, bacteria have been developed which have the ability to desulfurize dibenzothiophene (DBT) and other organosulfur molecules. These bacteria are being developed for use in a biocatalyst-based desulfurization process. Analysis of preliminary conceptual engineering designs has shown that this process has the potential to complement conventional technology as a method to temper the sulfur levels in crude oil, or remove the recalcitrant sulfur in middle distillates to achieve the deep desulfurization mandated by State and Federal regulations. This paper describes the results of initial feasibility studies, sensitivity analyses and conceptual design work. Feasibility studies with ...

International Nuclear Information System (INIS)

In this work, a water-soluble polymer, polyethylenimine (PEI) was used for the simultaneous separation and preconcentration of trace Cu and Mn prior to their determination by flame atomic absorption spectrometry. For this purpose, the sample and the PEI solution were mixed and the metal-bound polymer was precipitated by adding acetone. The precipitate was separated and dissolved in a minimum amounts of water and aspirated into a flame AAS. By increasing the ratio of the volumes of sample to water used in dissolving the precipitate, the analyte elements were concentrated as needed. The sorption is quantitative in the pH ?6. Detection limits were 5.2 ?g/L for Cu and 5.4 ?g/L for Mn. This method is simple, fast and precise.

Science.gov (United States)

The objectives of this project are to support the DOE direct coal liquefaction process development program and to improve the useful application of analytical chemistry to direct coal liquefaction process development. Independent analyses by well-established methods will be obtained of samples produced in direct coal liquefaction processes under evaluation by DOE. Additionally, analytical instruments and techniques which are currently underutilized for the purpose of examining coal-derived samples will be evaluated. The data obtained from this study will be used to help guide current process development and to develop an improved data base on coal and coal liquids properties. A sample bank will be established and maintained for use in this project and will be available for use by other researchers. The reactivity of the non-distillable resids toward hydrocracking at liquefaction conditions (i.e., resid ...

Energy Technology Data Exchange (ETDEWEB)

Irradiation-assisted stress corrosion cracking (IASCC) of several types of BWR field components fabricated from solution-annealed austenitic stainless steels (SSs), including a core internal weld, were investigated by means of slow-strain-rate test (SSRT), scanning electron microscopy (SEM), Auger electron spectroscopy (AES), and field-emission-gun advanced analytical electron microscopy (FEG-AAEM). Based on the results of the tests and analyses, separate effects of neutron fluence, tensile properties, alloying elements and major impurities identified in the American Society for Testing and Materials (ASTM) specifications, minor impurities, water chemistry, and fabrication-related variables were determined. The results indicate strongly that minor impurities not specified by the ASTM-specifications play important roles, probably through a complex synergism with grain-boundary Cr depletion. These impurities, typically associated with steelmaking ...

Energy Technology Data Exchange (ETDEWEB)

This is the monthly progress report for the Savannah River Technology Center, which covers the following areas of interest, Tritium, Separation processes, Environmental Issues, and Waste Management.

Science.gov (United States)

Lutein is a yellow pigment found in common foods that promotes the health of eyes and skin and is associated with reduced risk of age-related macular degeneration and cataracts. In the present study, selected high-lutein wheat and corn were milled into wholegrain flours by two mills to improve flour uniformity. The high-lutein and lutein-fortified wholegrain flours were processed into breads, cookies, and muffins to study lutein stability during baking and subsequent storage. Lutein and its isomers were separated, identified, and quantified by LC-UV/vis and LC-MS following extraction with water-saturated 1-butanol. Baking resulted in a significant reduction in all-trans-lutein and the formation of cis-lutein and cis-zeaxanthin isomers. Subsequent storage at ambient temperature had a slight impact on the content of all-trans-lutein. Effects of processing were more pronounced in lutein-fortified products, ...

International Nuclear Information System (INIS)

The results of calculated and experimental investigation of interphase isotopic exchange efficiency in countercurrent columns are given when separation processes of isotope mixtures are taken place with use of liquid-solid systems. Effect of liquid phase flow on transfer unit height in ion exchange separation of boron, lithium, nitrogen isotopes is considered. 40 refs.; 5 figs.

Energy Technology Data Exchange (ETDEWEB)

Full text of publication follows: A porous media solution PORFLO has been developed for the 3-dimensional two-phase flow by describing the process facility in Cartesian or cylindrical coordinates. The local porosity fraction is applied for distinguishing the fluid filled volumes from the solid structures. The solid structure contribute the two-phase flow through the wall friction, flow area and heat transfer. Optionally the solid structure may contain primary liquid of steam generators, steam in the higher temperature and pressure to be condensed or electrical heating power. By using these optional boundary conditions three different process facilities have been analysed. The thermohydraulic solution based on 5-equation approach, where the conservation equations are solved for the liquid and gas (vapour) mass, mixture momentum (giving the velocity only for the mixture), liquid and gas energy, is described shortly. In addition to that the ...

Energy Technology Data Exchange (ETDEWEB)

A process for separation of actinides and technetium from reprocessing high level liquid waste has been developed, the CTH-process. The main parts are three consecutive solvent extraction cycles followed by an optional step for sorption on inorganic ion exchangers. The first extraction cycle removes and recovers uranium, neptunium, and plutonium by extraction with HDEHP. The second extraction cycle separates technetium and nitric acid from the waste using TBP. In the third extraction cycle Am and Cm are separated from the waste using HDEHP. The actinide free waste is then passed through inorganic ion exchangers to remove most of remaining radionuclides. The process has been tested on an authenic HLLW solution. A decontamination factor > 10/sup 5/ for alpha emitters was measured for the solvent extraction process and the sorption on ...

Energy Technology Data Exchange (ETDEWEB)

This program is concerned with the development of an advanced method for the separation of hydrogen sulfides from coal gas. The process utilizes an electrochemical membrane which removes hydrogen sulfide without cooling the gas and with negligible pressure loss through the separator.

Science.gov (United States)

...Filter gaskets and seatings; (4) Pumps; (5) Solvent tanks and containers; (6) Water separators; (7) Muck cookers; (8) Stills; (9) Exhaust dampers; (10) Diverter valves; and (11) All Filter housings. (l)...

Energy Technology Data Exchange (ETDEWEB)

Energy from biomass is a CO{sub 2} neutral, sustainable form of energy. Anaerobic digestion is an established technology for converting biomass to biogas, which contains around 60% methane, besides CO{sub 2} and various contaminants. Most types of biomass contain material that cannot be digested; in woody biomass, this portion is particularly high. Therefore, conventional anaerobic digestion is not suited for the production of biogas from woody biomass. While wood is already being converted to energy by conventional thermal methods (gasification with subsequent methanation), dung, manure, and sewage sludge represent types of biomass whose energy potential remains largely untapped (present energetic use of manure in Switzerland: 0.4%). Conventional gas phase processes suffer from a low efficiency due to the high water content of the feed (enthalpy of vaporization). An alternative technology is the hydrothermal gasification: the ...

Energy Technology Data Exchange (ETDEWEB)

A solar energy desalination process utilizing solar radiation directly for the evaporation of salt water is described. Ambient air takes on water vapor as the air passes through an evaporative medium. It is then directed between a saline water-covered, solar absorbing surface and a solar collecting housing. The resulting heated and moisture-saturated air is cooled in a heat exchange means where condensation of fresh water occurs. Simultaneously, cool salt water is utilized as the cooling water in the heat exchange means, and takes on the heat of condensation given up by the condensing vapor. The heated salt water from the heat exchange means is partially directed over the solar absorbing surface, and at least a portion of it is also directed to wet the evaporative medium. Several optional ...

British Library Electronic Table of Contents (United Kingdom)

Using air as a carrier gas is common in humidification?dehumidification desalination processes. A computer program was written using mass and energy balances for modeling the process behavior. The parameters considered in this work were inlet air and fresh water recycle temperatures, inlet air flow rate, saline water and fresh water recycle flow rates, and saline water to air flow ratio. Results of simulation showed that increasing inlet air and fresh water recycle flow rate increases fresh water production. It was also found that heating the inlet air to humidification column or cooling the inlet water to dehumidification column increases the production rate but increasing water to air flow ratio in a humidifier leads to a lower production rate. The predicted effects of the ...

Energy Technology Data Exchange (ETDEWEB)

This report is a summary of the contribution of nitrogen and phosphorus in the eutrophication process of inland and coastal waters. Special attention was paid to the mechanisms of these nutrients in regulating biological processes and to the methods available in estimating their effects in the eutrophication of water bodies. The report includes five chapters which are entitled: Introduction, which is a general background to the subject with special attention to the requirements of the Finnish Water Act. Phosphorus and nitrogen as factors regulating biological processes. The topics included are: definition of eutrophication, forms of phosphorus and nitrogen and their sources to inland and coastal waters, effects of these nutrients as growth factors of phytoplankton and macrophytes and consequences of eutrophication. Estimation of the effects ...

KoreaScience (Korea)

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Energy Technology Data Exchange (ETDEWEB)

This report summarizes the results of research conducted during the sixteen month continuation of a program to develop rechargeable zinc-air batteries for electric vehicles. The zinc-air technology under development incorporates a metal foam substrate for the zinc electrode, with flow of electrolyte through the foam during battery operation. In this soluble'' zinc electrode the zincate discharge product dissolves completely in the electrolyte stream. Cycle testing at Lawrence Berkeley Laboratory, where the electrode was invented, and at MATSI showed that this approach avoids the zinc electrode shape change phenomenon. Further, electrolyte flow has been shown to be necessary to achieve significant cycle life (> 25 cycles) in this open system. Without it, water loss through the oxygen electrode results in high-resistance failure of the cell. The Phase I program, which focused entirely on the zinc electrode, elucidated the conditions necessary to ...

Energy Technology Data Exchange (ETDEWEB)

Water protection wetlands aim to reduce nitrogen and phosphorous concentrations either separately or simultaneously. In the latter case, a wetland must contain parts differing clearly in both function and physical condition. In efforts to reduce nitrogen the most important process is denitrification. Phosphorus is deposited with solids and bound to the vegetation and soil in wetlands. As the bulk of the solid and nutrient load comes from catchments during spring floods, wetlands should be designed on the basis of, at least, the average maximum vernal run-off (MHq). Use of higher run-offs, e.g. MHql/10 or MHql/20, in the design without reducing the target retention would require large wetlands. The efficiency of wetlands is constrained by too short retention times and low leachate temperatures. Wetlands established with special environmental support are normally designed on the basis of MHq. The average catchment area of ...

Energy Technology Data Exchange (ETDEWEB)

The desorption of uranium from the granular titanium-activated carbon composite adsorbent (concentration of uranium: 25.5 mg/l-Ad), which adsorbed uranium from natural sea water, was examined by the column process with acidic eluent at room temperature. The column operation was able to be carried out without destruction of the granular adsorbent by the generation of the carbon dioxide, and free from disturbance of the eluent flow by precipitate of calcium sulfate dihydrate with sulfuric acid eluent. The amount of acid consumption by the adsorbent was 0.87 eq/l-Ad. The alkaline earth metals were eluted in the range of elution volume below 2l/l-Ad, whereas uranium, iron, and titanium were eluted above 2l/l-Ad. Therefore, uranium was separable from the alkaline earth metals which were adsorbed in the most quantity in the adsorbent. In the range of elution volume 2 to 12l/l-Ad, the percentage of desorbed uranium and the ...

Energy Technology Data Exchange (ETDEWEB)

The goal of this project is to develop a bench-scale procedure to produce clean, desulfurized, premium-quality chars from the Illinois basin coals. This goal is achieved by utilizing the effective capabilty of smectites in combination with methane to manipulate the char yields. The major objectives are: to determine the optimum water- ground particle size for the maximum reduction of pyrite and minerals by the selective-bitumen agglomeration process; to evaluate the type of smectite and its interlamellar cation which enhances the premium-quality char yields; to find the mode of dispersion of smectites in clean coal which retards the agglomeration of char during mild gasification; to probe the conditions that maximize the desulfurized clean-char yields under a combination of methane+oxygen or helium+oxygen; to characterize and accomplish a material balance of chars, liquids, and gases produced during mild gasification; to identify the conditions ...

International Nuclear Information System (INIS)

The humidification dehumidification desalination process is viewed as a promising technique for small capacity production plants. The process has several attractive features, which include operation at low temperature, ability to utilize sustainable energy sources, i.e. solar and geothermal, and requirements of low technology level. This paper evaluates the characteristics of the humidification dehumidification desalination process as a function of operating conditions. A small capacity experimental system is used to evaluate the process characteristics as a function of the flow rate of the water and air streams, the temperature of the water stream and the temperature of the cooling water stream. The experimental system includes a packed humidification column, a double pipe glass condenser, a constant temperature water ...

Energy Technology Data Exchange (ETDEWEB)

Electrostatic beneficiation of dry coal has received significant attention in the last decade. In this process the coal is ground and then charged, either by corona charging or by triboelectrification (friction charging). Coal and minerals receive different levels of charge -- often opposite polarities in the case of triboelectrification -- and can then be separated based on differences in electrical mobility. Problems associated with the techniques include rapid deposition of particles on the electrodes, thus, effecting further separation. The goal of this project is to optimize the electrostatic coal cleaning process to remove pyrites and inorganic materials through studies of the electrostatic properties of powdered coal, in-situ measurements of the electrodynamics of coal and mineral particles inside the separator, and development of self-cleaning collector plates for continuous ...

International Nuclear Information System (INIS)

Full text of publication follows: Slightly over-stoichiometric lithium orthosilicate pebbles have been selected as one optional breeder material for the European Helium Cooled Pebble Bed (HCPB) blanket. This material has been developed in collaboration of Research Center Karlsruhe and the Schott Glass, Mainz. The lithium orthosilicate pebbles are fabricated from lithium hydroxide and silica by a melting and spraying method in a semi-industrial scale facility. Lithium hydroxide was selected as the precursor since enriched lithium hydroxide is commercially available. The lithium orthosilicate pebbles produced by the process contains oxide phases besides orthosilicate, but it was also found that the oxide phases can be decomposed by annealing at high temperatures. The lithium orthosilicate pebbles produced in this way possesses satisfactory pebble characteristics. Therefore, the authors performed out-of-pile annealing tests using the lithium orthosilicate pebbles ...

International Nuclear Information System (INIS)

On nuclear power stations with high temperature reactors and helium turbine cycles (HTR-single circuits) the residual heat from the energy conversion process in the primary and intermediate coolers is removed from cycled gas, helium. Water, which is circulated for safety reasons through a closed circuit, is used for cooling. The primary and intermediate coolers as well as other cooling equipment of the power plant are installed within the reactor building. The heat from the helium turbine cycle is removed to the environment most effectively by natural draught cooling towers. In this way a net plant efficiency of about 40% is attainable. The low quantities of residual heat thereby produced and the high (in comparison with power stations with steam turbine cycles) cooling agent pressure and cooling water reheat pressure in the circulating coolers enable an economically favourable design of the overall 'cold end' to be ...

Energy Technology Data Exchange (ETDEWEB)

Anaerobic digestion of slurry represents an environmental opportunity for both slurry management and renewable energy production in countries with high animal density. This study evaluated the environmental impacts of 4 biogas production alternatives in which slurry was the only input in the process, without supplementary addition of easily degradable carbon. This was achieved by exposing the slurry to different separation technologies. The biomass mixture input for biogas production included solid fraction from slurry separation as well as raw slurry, proportioned in order to achieve economical methane yield. The separation processes considered in this study were mechanical separation; mechanical separation combined with the addition of flocculants; and mechanical separation combined with a thermal treatment. Four ...

International Nuclear Information System (INIS)

The aim of this study is to prepare some polymeric moulds using Natural rubber latex (NRL)- portland cement composites based on a delayed-action mechanism. Factors affecting the preparation process such as concentration, mixing percentage, additives and their effects on what is regarded as a delayed-action coacervant combination was studied. The effect of Gamma-radiation on the mechanical properties of these moulds was investigated. The effect of natural aging on the prepared moulds was investigated to determine the possibility of using the prepared product in the construction field as expansion joints and cracks filling materials ...etc. The results may be summarized as follows: 1) Composites of natural rubber latex (NRL)-portland cement mould were prepared as two separate parts. The stabilized natural rubber latex (NRL) with hydroxy ethyl cellulose (HEC) as stabilizer and a delayed-action coacervant (sodium meta silicate) present in the ...

Energy Technology Data Exchange (ETDEWEB)

The addition of ZnO, depleted in the Zn-64 isotope, to the water of boiling water nuclear reactors lessens the accumulation of Co-60 on the reactor interior surfaces, reduces radioactive wastes and increases the reactor service-life because of the inhibitory action of zinc on inter-granular stress corrosion cracking. To the same effect depleted zinc in the form of acetate dihydrate is used in pressurized water reactors. Gas centrifuge isotope separation method is applied for production of depleted zinc on the industrial scale. More than 20 years of depleted zinc application history demonstrates its benefits for reduction of NPP personnel radiation exposure and combating construction materials corrosion.

Energy Technology Data Exchange (ETDEWEB)

A device for laying cut peat in drying formations is proposed consisting of separate compartments, reinforced on a common frame and with mechanisms for both vertical and horizontal mixing. In order to intensify the drying process, within the scope of laying cut peat, uniform clearances and spacing in formations is applied. The mixing compartments are joined in sections with capabilities for separate mixing in each unit. The compartments are joined together by hinges and can be turned 180 degrees on the hinges horizontal to the plane.

Energy Technology Data Exchange (ETDEWEB)

A summary of the off-gas behavior in the HARVEST pot vitrification process is presented. Experimental runs were carried out on 3 representative wastes (MAGNOX - thermal reactor, metal fuel, THORP - thermal oxide fuel and PFR - fast reactor oxide fuel) using 2 methods of feeding the glass-formers (slurry and crizzle). Materials were carried over from the vitrification vessel into the off-gas system by entrainment supplemented by volatilization. The main volatile elements were Ru, B, Cs. Some volatility was also shown by Na and Li. The overall behavior of the off-gas was consistent with the presence in it of 5 separate aerosols of particulate matter. Sources of entrainment gave rise to 3 aerosols, and a further 2 aerosols were formed as a result of chemical reaction (Ru) and condensation (Cs) proceses involving the volatile species. Entrainment was enhanced when the feed contained free alkali nitrate. The Ru volatility correlated directly with ...

International Nuclear Information System (INIS)

The sampling is described for radionuclide X-ray fluorescence analysis. Aerosols are captured with various filter materials whose properties are summed up in the table. Fine dispersed solid and liquid particles and gaseous admixtures may be captured by bubbling air through a suitable absorption solution. The concentration of small amounts of impurities from large volumes of air is done by adsorbing impurities on surfactants, e.g., activated charcoal, silica gel, etc. Aerosols may be captured using an electrostatic precipitator and aerosol fractions may be separated with a cascade impactor. Water sampling differs by the water source, i.e., ground water, surface water, rain or waste water. Soil samples are taken by probes. (ES).

Energy Technology Data Exchange (ETDEWEB)

THMs are disinfection by-products (DBPs) generated during water chlorination. Concentration of individual and total THMs, depends on treatment process and THMs precursors level. ATLL water utility has two DWTP (Llobregar and Ter) that produce and supply drinking water to Barcelona and regional area. This work studies the levels of THMs along the ATLL distribution system (450 km). Although, no differences were observed along water pipes system, changes of water resource and mix procedures were related. (Author) 12 refs.

Energy Technology Data Exchange (ETDEWEB)

Under the repository storage conditions of Eram and Konrad, waste packages designed for permanent storage must not contain or release freely mobile liquids, except for the minimum residues attainable by reasonable efforts or unavoidable. In accordance with a directive issued by the German Federal Ministry for the Environment (BMU), waste conditioning must be carried out so as to minimize waste volumes and, if possible, on the site where the waste arises. Liquid waste is conditioned most effectively by drying. At the present time, various different processes for drying liquid waste are employed as reflected by the state of the art: The Robe process; roller drying; the RDA process; Favorit; in-drum drying; and HPA liquid waste drying with make-up feed. The HPA process offers these advantages: Drying under atmospheric conditions, which means high level of dryness (freely mobile and releasable ...

Science.gov (United States)

The report describes tests to demonstrate the feasibility of using a vertical-tube, falling-film, vapor-compression evaporator to concentrate waste water from a flue gas desulfurization (FGD) process. Tests showed that waste water from the Chiyoda FGD process can be concentrated ...

Science.gov (United States)

Finely divided ash-containing coal is immersed in an aqueous solution of hydrochloric acid or citric acid, and acidic ammonium fluoride to cause the ash to react with the acid and the acidic ammonium fluoride, and the deashed coal is thereafter separated from the solution.

Energy Technology Data Exchange (ETDEWEB)

Research programs, presented at the contractor's review meeting on direct liquefaction, are presented under the following topics: two-stage liquefaction; coprocessing; and advanced research on coal liquefaction. A total of 20 reports are included. Individual projects are processed separately for the data bases. (CBS)

Energy Technology Data Exchange (ETDEWEB)

Natural sunlight induces a genotoxic response in cultured CHO cells pre-treated with shale oil retort process water. Near ultraviolet light (NUV) component of the solar spectrum is the apparent radiation responsible for photoactivation. Cultured human skin fibroblasts are acutely sensitive to the genotoxic effects of photoactivated process water. The mutagenic potential of photoactivated process water in human cells is the same as that witnessed for an equivalent killing dose of the potent skin carcinogen FUV. DNA repair processes are involved in modulating genotoxic effects of this photo-induced process. The exact magnitude of the potential health-related and environmental risks resulting from photoactivation of retort process waters and other oil shale by-products is unassessed ...

Energy Technology Data Exchange (ETDEWEB)

This paper deals with the energy required to separate ethanol from an aqueous solution in a distillation column containing a solid phase. The solid phases evaluated consisted of either an amylatious (ground corn) or a cellulose (sugar cane bagasse) absorber whit particle sizes smaller than 4 mm. The water-retention capacity of each solid phase was measured by passing vapors or ethanol-water mixtures through the solid phase. When starting with initial concentrations bellow the azeotropic point, ethanol concentrations up to 99,5% (on corn) and 97,2% (on sugar cane) were achieved. The water content was evaluated potentiometrically (Karl`Fischer). Regarding the 2-4 mm ground corn solid phase column, the energy consumed was estimated to be reduced by 15,6% and 60% (by weight) ethanol-water mixture respectively. (author) 11 refs., 2 figs., 2 tabs

Energy Technology Data Exchange (ETDEWEB)

This patent describes a nuclear system comprising a containment airspace in which a nuclear reactor pressure vessel is disposed there being a reactor core within the pressure vessel. It comprises a heat exchanger elevated a distance above the pressure vessel; a pool of water surrounding the heat exchanger; means for venting the pool of water to an environment outside the containment; a heat exchanger entry conduit within the containment, the entry conduit having an open lower end communicating with the containment space, and an upper end connected to the heat exchanger, water-containing heated fluid present in the containment airspace incident a pressure vessel loss of coolant event entering and flowing through the entry conduit into the heat exchanger for cooling the fluid to convert water vapor therein to a condensate and separate non-condensable gasses therefrom; a gravity driven ...

Energy Technology Data Exchange (ETDEWEB)

This document reports on the work done by the Separations Science and Technology Programs of the Chemical Technology Division, Argonne National Laboratory, in the period April-September 1993. This effort is mainly concerned with developing the TRUEX process for removing and concentrating actinides from acidic waste streams contaminated with transuranic (TRU) elements. The objectives of TRUEX processing are to recover valuable TRU elements and to lower disposal costs for the nonTRU waste product of the process. Other projects are underway with the objective of developing (1) evaporation technology for concentrating radioactive waste and product streams such as those generated by the TRUEX process, (2) treatment schemes for liquid wastes stored or being generated at Argonne, (3) a process based on sorbing modified TRUEX solvent on magnetic beads to be used for ...

Energy Technology Data Exchange (ETDEWEB)

Polymeric coated ferromagnetic carriers with an absorbed layer of octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO) diluted by tributyl phosphate (TBP) are being evaluated for application in the separation and the recovery of low concentrations of americium, plutonium, and uranium from nuclear waste solutions. Due to their chemical nature, these extractants selectively complex americium and plutonium contaminants onto the particles and the complexed particles can be recovered from the solution using a magnet. Physical and chemical characterization of the extractant-absorbed particles were performed by gamma and liquid scintillation counting, scanning electron microscopic (SEM) micrograph, and other physical measurements. Plutonium, americium, and uranium separations have been performed at various HNO{sub 3} and HCl concentrations. Parameters were studied to determine the limitations and capacity of the ...

Energy Technology Data Exchange (ETDEWEB)

Radionuclide X-ray fluorescence analysis was used for the determination of iron, calcium, potassium, copper, manganese and zinc in waste water from the production process of citric acid.

Energy Technology Data Exchange (ETDEWEB)

Both DOE and DOD use water and/or steam in the process of removing high explosives, resulting in large quantities of contaminated water, which is then run through activated carbon, which then has to be decontaminated. Research has been underway to utilize microorganisms to degrade RDX and HMX.

Energy Technology Data Exchange (ETDEWEB)

The behavior of Am, Cm, Bk, Cf, Es, and other actinides, as well as Zr, on anion and cation exchangers in aqueous and water-ethanol solutions of sulfuric acid as a function of the various components of the solution has been investigated. It has been discovered that the presence of ethanol in sulfuric acid solutions causes an increase in the distribution coefficients both on cation exchangers and on anion exchangers. The possibility of the use of ion exchangers for the preconcentration and separation of transplutonium elements from U, Np, Pu, Zr, and other elements which form strong complexes with sulfate ions over a broad range of concentrations of sulfuric acid has been demonstrated.

International Nuclear Information System (INIS)

The first Russian reprocessing facility, known as RT-1 (located at PA-Mayak in Ural region) was started on the radiochemical plant base in 1977. Nowadays RT-1 is the sole operating reprocessing plant in Russia. The main features of RT-1 is its broad spectrum of reprocessing spent nuclear fuels (SNF). The following spent fuel types are reprocessed: -) SNF from PWR reactors (WWER-440) and FB reactor (BN-600); -) SNF of transport ship reactors; -) production reactors SNF; -) research reactor spent nuclear fuel. The world-known technological processes are used at RT-1, but there are the following distinctive features. First, the universality of the three technological lines which allows not only the reprocessing of various SNF kinds, but also to implement the combined reprocessing of some types of them. Secondly, extraction of neptunium during SNF reprocessing which is used to implement its separate storage and for radioisotope production. Thirdly, ...

International Nuclear Information System (INIS)

To reduce the volume of radioactive wastes after evaporation, activity carriers can be separated from the inactive salt load. Boric acid separation from PWR concentrates was considered a preliminary stage for nuclide precipitation. In connection with the precipitation process, the reaction conditions for boric acid separation were determined by bench-scale experiments. After evaluating the known purification processes, crystallization was suggested as a practicable method. After inactive bench-scale experiments, mixed crystal formation with iron hexacyanoferrate for Cs removal was chosen. The disturbing effect of the complexing agents was neutralized by a pre-dose of iron-III-salts. By specifying the precipitation conditions, for Cs-134 an activity separation from 3,0 E + 06 Bg/l to 1,9 E + 02 Bg/l, and for Cs-137 from 5,9 E + 06 Bg/l to 1,2 E + 02 Bg/l was ...

British Library Electronic Table of Contents (United Kingdom)

Injections of fuel-grade ethanol (95% v/v ethanol, 5% v/v hydrocarbon mixture as a denaturant) near the water table were conducted in two-dimensional physical models tightly packed with fine sands under varying water-table conditions. As the fuel migrated in the porous media following injection, the denaturant phase separated leaving a residual Light Non-Aqueous Phase Liquid (LNAPL) phase that occupied a region with a volume similar to that of an equal-sized spill of 100% LNAPL without ethanol. When the water table was raised, as may be expected following a catastrophic release that reaches groundwater, most of the ethanol-fuel mixture was mobilized and the vertical distribution of the generated LNAPL was increased. The lower boundary of the residual LNAPL was established during the initia...

Energy Technology Data Exchange (ETDEWEB)

The operation of industrial facilities has generally resulted in contamination of the surrounding soils and ground water. A variety of methods have been proposed for the remediation of contaminated sites. This paper presents new process technology that is capable of performing treatment on ground water or soil washing leachates. The process is targeted to treat low levels of radioactivity, organics and heavy metals present in the aqueous solutions, to be easily transported and provide simple operation on-site and provide an effluent that meets the specified discharge quality. The purification process involves sequential chemical treatment and filtration. The paper will describe the development of the technology and review the current progress in its use to remediate contaminated sites at Chalk River. The application of the process technology has demonstrated ...

Science.gov (United States)

... More particularly, the invention relates to novel felted combustible cartridge cases of excellent tensile strength, water resistance and combustibility. ...

Energy Technology Data Exchange (ETDEWEB)

Several lanthanide shift reagents (LSR) were synthesized from praseodymium, europium, dysprosium, and terbium using ethylenediaminetetraacetic acid, trans-1,2-diaminocyclohexane-N,N,N[prime],N[prime]-tetraacetic acid, and diethylenetriaminepentaacetic acid for the purpose of separating overlapping [sup 31]P FT-NMR spectral signals of dissolved organic phosphorus compounds present in concentrated lake-water samples. The extent of change in signal position and line width of several known phosphorus compounds dissolved in pure water was examined as a function of solution pH and the molar ratio of LSR to phosphorus. Praseodymium ethylenediaminetetraacetate (PrEDTA) was determined to be the most effective LSR. Concentrated lake-water samples mixed with PrEDTA were examined with [sup 31]P FT-NMR. The use of PrEDTA provided separation of overlapping signals, indicated that phosphorus ...

Energy Technology Data Exchange (ETDEWEB)

The results of an investigation of the effects of several parameters on the reactivity instability of a Boiling Water Reactor (BWR) calculational model are summarized. Calculations were performed for a typical BWR operated at low flow conditions, where reactivity instabilities are more likely to occur. The parameters investigated include the axial power shape (characterized by two separate parameters), the core pressure, and operating flow. All calculations were performed using the LAPUR code which was developed at the Oak Ridge National Laboratory for the dynamic modeling of large BWR's. 4 refs., 8 figs.

Science.gov (United States)

The melting unit, consisting of a water-cooled cupola furnace, afterburner, heat exchanger, air preheater, consumes most of the supplied energy in the rockwool process. The report maps the energy flows and defines factors of merit according to thermodynam...

Science.gov (United States)

Liquid Phase Catalytic Exchange (LPCE)- Cryogenic Distillation(CD) process was studied which could be available for an optimal tritium removal process of pressurized heavy water reactor system at Wolsung nuclear power plant in the near future. Based upon ...

International Nuclear Information System (INIS)

The results of studies of radiation-thermocatalytic water decomposition in the 673-773 K temperature range in the presence of BeO and titanium Y-type zeolite are presented. It is found that radiation-thermocatalytic processes of hydrogen production from water are characterized by a lower activation energy (55.4 kJ/mole) as compared with thermocatalytic processes (88.4 kJ/mole). The radiation-thermocatalytic process rate in the presence of oxide systems is not an additive sum of rates of radiation-catalytic (at 296-300 K) and thermocatalytic processes of water decomposition. On the basis of obtained results the conclusion is made that during radiation-catalytic decomposition of water in a heterogeneous system BeO + H_2O the main contribution into this process is made by excitons, radiation-chemical ...

Energy Technology Data Exchange (ETDEWEB)

In this paper the simulation of hybrid processes containing membrane units will be discussed. For this purpose a user-defined module for simulation and design of membrane processes was implemented into the simulation program AspenPlus. The advantages can be summarized as follows: - any combination of membrane processes with all other units already implemented in AspenPlus is possible, including internal recycle streams, - utilization of the physical property models and data bases of AspenPlus is possible, - cost and sensitivity analysis can be performed. These benefits are demonstrated in detail for a membrane vapor recovery unit for the treatment of tank farm off-gas, for a two-stage reverse osmosis plant for organic/-organic separations and for a combination of distillation and pervaporation for the separation of a dimethylcarbonate/methanol mixture. (orig.)

Energy Technology Data Exchange (ETDEWEB)

This document contains papers which were presented at the First ACM International Conference on Digital Libraries. Topics processed for this document included information retrieval and index structures for structured documents. Individual papers have been processed separately for the United States Department of Energy databases.

Energy Technology Data Exchange (ETDEWEB)

A rapid and accurate method for the direct simultaneous determination of nitrate and nitrite is proposed. The method is applied to the determination of nitrate and nitrite in rainwater and wastewater without preliminary separation. The determinations are performed by a CPA matrix method with ultraviolet spectrophotometric detection. The results obtained are in agreement with those obtained by conventional methods for the determination of nitrate and nitrite.

International Nuclear Information System (INIS)

Brief summaries are given of research carried out in the following areas: absorption spectroscopy of titanium, niobium, and molybdenum in uranium alloys; atomic absorption spectroscopy of selenium in stainless steel, computer program improvements for spectrophotometer control, and detection of beryllium in stack gases; electrolysis for inactivation of bacteria in cooling-tower water; improved solvent analysis by gas chromatography; sequential radionuclide separation for various sample matrices; progress on an electron microprobe analyzer; and miscellaneous projects.

UK PubMed Central (United Kingdom)

A two-step polymerase chain reaction (PCR) procedure with two nested pairs of primers specific for the yadA gene of Yersinia enterocolitica was developed. The PCR assay identified all common pathogenic...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

This invention is a manufacturing method of a metal-hydrogen alkali battery cell consisting of a positive electrode of metal oxides, alkaline electrolyte solution and a separator containing an amide-radical, wherein the above treating solution is aqueous solution of KOH (or NaOH) which is heated at least at 40 centigrade and the separator is first immersiion-treated and then water-washed and dried. The amide-radical-containing separaator uses a nylon non-woven fabrics. Average molecular weight of nylon 66 is 12,000 - 20,000. In this invention, in order to improve the storage ability and the cycle characteristics which are caused by corrosion of a separator which takes place in the cell after its assembly, the separator is immersed in a hot alkali in order to obtain a non-woven fabric of nylon 66 consisting of alkali-stable high molecular weight portion, which is assembled into a ...

International Nuclear Information System (INIS)

Decision-making is strongly based on modelling in two of our water supply projects concerning artificial ground water. The model used is a 2-dimensional flow and transport model using the element method. Due to sharp variations in Finnish soils, the modelling process is based on careful and detailed evaluation of basic hydrogeological data before and during model calibration.

International Nuclear Information System (INIS)

The separation of humic substances by polysulfone has been done. Thisinvestigation aims at separating the humic substances contained in theestuary environment. Because of without sample pre-treatment, cheap and easythis method has been to choice. At preliminary study proved that byincreasing the pressure until 50 psia, the yield of flux was 13.5 l/m"2.jamand the reject coefficient was 90.98%, so that polysulfone membrane isappropriate to be applied. More over the pressure could be increased morethan 50 psia. The feed concentration should be lower than 150 ppm, though thevolume should be greater. The pH condition should be alkaline (pH> 7), sinceat this condition the filtration process is easily conducted and the rejectcoefficient could reach 95.09%. (author)

Energy Technology Data Exchange (ETDEWEB)

We present the synthesis, magnetic and UV spectrometry of NiZn-ferrite nanofiber. The single phase of spinel ferrite was obtained at 600 {sup o}C. The NiZn-ferrite fibers fabricated by an electrospinning process were formed as a polygonal grain growth with firing temperature in fiber matrix. It appeared that the saturation magnetization (M{sub S}) of NiZn-ferrite nanofiber was dependent on Ni/Zn molar ratio which is similar to that of the inverse spinel ferrites. The NiZn-ferrite fibers showed good DNA adsorption efficiency that can be modified and utilized for DNA separation with magnetic nanofiber as a novel material in clinical applications.

International Nuclear Information System (INIS)

Doubly-excited 2s-12p-13pnp autoionizing resonance series of Ne atom as well as autoionizing resonances in the 2s region of Na and Mg atoms have been studied with monochromatized synchrotron radiation. Use of charge-separated photoion-yield method allowed us to detect these weak resonances in a clarified way in the yield curves of doubly-charged ions. The observed resonance states have been interpreted with the help of MCDF calculations, and the decay processes of these resonance states are discussed briefly.

International Nuclear Information System (INIS)

The direct injection of steam into a water pool is a method of heat transfer used in many process industries. The amount of research in this area however is limited to the nuclear industry, with applications relating to reactor cooling systems. Electrical resistance tomography (ERT), a low cost, non-invasive and which has high temporal resolution characteristics, can be used as a visualization tool for the resistivity distribution for the steam injection into water pool such as IRWST. In this paper, three dimensional resistivity distribution of the process is obtained through ERT using iterative Gauss-Newton method. Numerical experiments are performed by assuming different resistive objects in the water pool. Numerical results show that ERT is successful in estimating the resistivity distribution for the injection of steam in the water pool

Energy Technology Data Exchange (ETDEWEB)

This article presents a humidification-dehumidification (H.D.) process suitable for desalination of sea- and brackish water. The work correlated performance characteristics of the combination of different components in such a loop. Water yield, energy requirement and design data are evaluated as functions of different parameters. The investigation covered water to air mass ratios ranging from 60 to 80, concentration ratios between 2 and 5, at a temperature difference of between 10 and 16 C, along the liquid for dehumidification. The results showed that 76% of energy consumed in the humidifier is recovered by condensation. Increase of the concentration ratio to 5 can reduce the make-up water and rejected brine by about 58% and 24% respectively. Cost calculations show that the H.D. process has significant potential as an alternative for small capacity desalination ...

British Library Electronic Table of Contents (United Kingdom)

Spherical nano-sized YSZ (yttria stabilized ZrO2) powders were successfully synthesized via a reverse microemulsion system. The water droplets in the microemulsion system of yclohexane/water/span85/Triton X-100/hexyl alcohol can act as the nano-reactors which solubilize zirconium oxychloride and ammonia water separately. The minute original reactors are favor to the formation of nano-sized spherical YSZ powders and the dispersibility of the powders can be controlled effectually by adjusting the weight ratio of the LiNO3 molten salt to the precursor. The phase transformation from cubic to monoclinic starts at and 500??C and finally monoclinic and cubic phase with increased crytallinity coexist at 800??C. The effect of LiNO3 molten salt in the formation of YSZ powders was also discussed.

Energy Technology Data Exchange (ETDEWEB)

The results from a hot test, using authentic HLLW solution, of the CTH actinide separation process are reported. The process consists of three solvent extraction cycles for separation of actinides and technetium from reprocessing high level liquid waste, utilizing HDEHP, TBP, and HDEHP in sequence, and an optional step for sorption on inorganic ion exchangers of the fission product content in the process raffinate. In general the process worked according to predictions but a malfunctioning feed pump gave a 10% loss of Pu to one stream. The hot test indicating that U and Pu can be recovered with losses below 0.1% and Am, Cm with a loss below 0.2%. Np and Tc were difficult to follow because of the low activity of /sup 237/Np and because /sup 99/Tc is a pure beta emitter, but the results indicate that also these elements behaved according to predictions, i.e., that ...

International Nuclear Information System (INIS)

During the last years one focus of German PWR safety analysis was boron dilution events with the potential of reactivity transients. Coolant with a low boron concentration could be collected in localized areas of the reactor coolant system e.g. by separation of borated reactor coolant into highly concentrated and diluted fractions (inherent dilution) which can occur during reflux- condenser heat transfer after a small break loss of coolant accident with a limited availability of the emergency core cooling systems. The TUeV NORD SysTec was charged by German supervisory authorities with the assessment of the safety analyses of boron dilution events presented by the utilities. These analyses are based on the simulation of boron dilution and transport processes in conjunction with a number of dedicated experiments. The analyses shall demonstrate that boron dilution events cannot lead to recriticality of the core. Hence the boron concentration at ...

International Nuclear Information System (INIS)

The aim of the project is to study the conditions and processes occurring in permanently frozen crystalline bedrock, with special reference to deep (i.e., several hundreds of meters) bedrock conditions. The target of the study is the Lupin mine in Nunavut Territory, Northern Canada. The results may be utilized in assessing the long-term performance of deep underground constructions (e.g., nuclear waste repositories) in cooling climatic conditions. In Phase I of the project versatile background information was collected from the site e.g., on climate, geology and on hydrogeological and hydrogeochemical conditions. During Phase II a broad range of research was conducted including (i) electromagnetic soundings to investigate the distribution of permafrost in the surroundings of the mine; (ii) drilling of three research boreholes at the base of the permafrost for groundwater research; (iii) application of borehole video surveys to study the distribution of open ...

Energy Technology Data Exchange (ETDEWEB)

Cold Heavy Oil Production with Sand (CHOPS) is an enhanced oil recovery method that induces sand production to form a network of wormholes that increase the porosity and permeability of a formation. Under proper conditions, CHOPS can improve formation flow characteristics. Integrated well completion strategies that were used to increase oil production at Fula oil field on the south flank of Mughad Basin in Sudan were described. Limited sand influx provided a means for effective sand control while eliminating the need for conventional sand control processes. Cold heavy oil production with limited sand influx requires optimized completion methods to stimulate sand production, thereby reducing oil flow resistance and prolonging the sand removal operation cycle. Completion tests were performed in terms of different formation conditions including perforating completion; perforating and full sand control completion by screen liner; and perforating and limited sand ...

International Nuclear Information System (INIS)

The Four years of the IMPACT, 'Integrated Modular Plant Analysis and Computing Technology' project Phase 1 have been completed. The verification study of Severe Accident Analysis Code SAMPSON prototype developed in Phase 1 was conducted in two steps. First, each analysis module was run independently and analysis results were compared and verified against separate-effect test data with good results. Test data are as follows: CORA-13 (FZK) for the Core Heat-up Module; VI-3 of HI/VI Test (ORNL) for the FP Release from Fuel Module; KROTOS-37 (JRC-ISPRA) for the Molten Core Relocation Module; Water Spread Test (UCSB) for the Debris Spreading Model and Benard's Melting Test for Natural Convection Model in the Debris Cooling Module; Hydrogen Burning Test (NUPEC) for the Ex-Vessel Thermal Hydraulics Module; PREMIX, PM10 (FZK) for the Steam Explosion Module; and SWISS-2 (SNL) for the Debris-Concrete Interaction Module. Second, with the Simulation ...

International Nuclear Information System (INIS)

Studies investigated whether changes in omega- and (omega-1)-hydroxylation (OH) of lauric acid (LA) occurred in renal microsomes prepared from SHR compared to Wistar-Kyoto (WK) control rats. Systolic blood pressure in age-matched adult SHR and WKR were 189 +/- 3 and 123 +/- 4 mm Hg(anti X +/- SE) respectively (p < 0.001). No significant differences between SHR and WKR were seen in body weight, kidney weight or renal microsomal protein content. Renal microsomes, prepared from whole kidneys, were incubated with 10 mM NADPH and ["1"4C]LA at concentrations between 5-50 #mu#M. The 11- and 12-OH metabolites of LA were separated by HPLC using a reverse phase column with a methanol:water:acetic acid (62:37.8:0.2) mobile phase. Apparent (app) V/sub max/ values for 12-OH in WKR and SHR were 0.87 +/- 0.19 vs 1.48 +/- .11 nmoles/mg protein/min (p < 0.05), respectively, while values for 11-OH were 0.51 +/- 0.12 vs 0.60 +/- .07, respectively. No ...

Energy Technology Data Exchange (ETDEWEB)

A small scale biomass metal contacting experiment was performed to screen the optimal plant species for biosorption and bioaccumulation of cadmium, zinc, nickel, lead, and copper. Experiments were also conducted to test the ability of the biomass to lower the metal concentrations below the US Environmental Protection Agency surface water discharge criteria. The minimum residual concentration was 0.1 mg/L for zinc, 0.004 mg/L for lead, and about 0.01 mg/L for cadmium, nickel, and lead. Results indicate that water milfoil can be used for bioremoval of metals.

British Library Electronic Table of Contents (United Kingdom)

In this paper we provide a geochemical investigation on 34 groundwater samples in the Mt. Vulture volcanic aquifer representing one of the most important groundwater resources of the southern Italy pumped for drinking and irrigation supply. The present study includes the first data on the abundance and mobility of minor and trace elements and the thermodynamic considerations on water-rock interaction processes in order to evaluate the conditions of alkali basalt weathering by waters enriched in magma-derived CO2. The results highlight the occurrence of two hydrofacies: bicarbonate alkaline-earth and alkaline waters deriving from low-temperature leaching of volcanic rocks of Mt. Vulture, and bicarbonate-sulfate-alkaline waters (high-salinity waters) related to prolonged water circulation in...

Energy Technology Data Exchange (ETDEWEB)

It is an object of the claimed invention to combine chemical treatment with microfiltration process to treat groundwater, leachate from contaminated soil washing, surface and run-off waters contaminated with toxic metals, radionuclides and trace amounts of organics from variety of sources. The process can also be used to treat effluents from industrial processes such as discharges associated with smelting, mining and refining operations. Influent contaminants amenable to treatment are from a few mg/L to hundreds of mg/L. By selecting appropriate precipitation, ion exchange and adsorption agents and conditions, efficiencies greater than 99.9 percent can be achieved for removal of contaminants. The filtered water for discharge can be targeted with either an order of magnitude greater or lower than contaminant levels for drinking water.

Energy Technology Data Exchange (ETDEWEB)

In order to remove ash from coal, it is introduced into an aqueous ash removal solution, which contains nitric acid or citric acid and ammonium hydrogen fluoride. The coal without ash is then separated from the aqueous solution. According to the process, either finely ground coal is introduced into the ash removel solution or the coal with the solution is ground in a wet pulveriser.

Energy Technology Data Exchange (ETDEWEB)

The first stage of the continuous coal hydrogenation unit has been used to test a number of coals with different processing strategies. This work has shown that conversion increases with product recycle, however after the second pass the increase is small but operability of the reactor is considerably improved. A kinetic model for the aromatic saturation of the recycle solvent in the second stage has been developed and will be used in the selection of conditions for oil upgrading processes. New insights into the structural composition of coal derived materials have been made due to the refinement of chromatographic or solubility separation analyses into routine operations and the development of a new technique in NMR spectroscopy.

Energy Technology Data Exchange (ETDEWEB)

To improve adherent properties of electrogalvanized steel (EGS) to polymeric topcoats, the surfaces of EGS were modified by polyelectrolyte-modified zinc phosphating solution. The electrochemical reaction between phosphating solution and EGS led to the complete coverage with fully grown hopeite crystals after only 5 sec treatment, thereby improving adhesion to topcoating and providing protection of EGS against corrosion. To evaluate the ability of polyphenylene sulfide (PPS) polyaryl thermoplastic coatings to protect zinc phosphate (Zn{center_dot}Ph)treated steels from corrosion in a wet, harsh environment ( 1.0 wt % H{sub 2}SO{sub 4}, 3.0 wt % NaCl and 96.0 wt % water at temperatures from 25{degrees} to 200{degree}C), we exposed them in an autoclave to attempt heating-cooling cyclic fatigue tests (1 cycle = 12 hr at 200{degrees}C + 12 hr at 25{degrees}C) up to 90 times. The major chemical reaction at the interface between the PPS and Zn in the Zn-Ph layer during ...

Energy Technology Data Exchange (ETDEWEB)

Commercial development of oil shale resources will produce vast quantities of processed shale waste. The presence of potentially toxic trace elements, inorganic salts, and potentially toxic residual organic constitutents make the disposal of vast quantities of processed shale a potential environmental problem. To be environmentally acceptable, processed shale disposal must: result in a physically stable structure, prevent or minimize release of potentially toxic compounds, and provide an economically acceptable post-land use. Water is the common element underlying all factors important to the environmental stability of disposed solid waste. The leaching and transport of solubles by water in processed shale embankments may result in degradation of local surface and groundwater quality. The major purpose of this research is to physically model, study, and describe ...

Energy Technology Data Exchange (ETDEWEB)

Research facilities and personnel in high efficiency separation processes for carbon dioxide removal from industrial sources, such as fossil fuel fired power stations, goal gasification plants, and hydrogen production units for enhanced oil recovery applications at the University of Regina were described. A brief summary of current projects, such as the determination of CO{sub 2} absorption capacity of sterically hindered amines, the formulation of high CO{sub 2} absorption capacity solvents, the search for high performance absorbers and regenerators, studies on material corrosion, and optimization and cost studies of co-production of CO{sub 2} and electricity, was also provided.

International Nuclear Information System (INIS)

An integrated beam optics-nuclear processes framework is essential for accurate simulation of fragment separator beam dynamics. The code COSY INFINITY provides powerful differential algebraic methods for modeling and beam dynamics simulations in absence of beam-material interactions. However, these interactions are key for accurately simulating the dynamics of heavy ion fragmentation and fission. We have developed an extended version of the code that includes these interactions, and a set of new tools that allow efficient and accurate particle transport: by transfer map in vacuum and by Monte Carlo methods in materials. The new framework is presented, along with several examples from a preliminary layout of a fragment separator for a facility for rare isotope beams.

Energy Technology Data Exchange (ETDEWEB)

Ependymal cells line the cerebral ventricles forming the interface that separates the cerebrospinal (CSF) and interstitial fluids (ISF). Extracellular molecules move between ependymal cells, whereas lipid soluble molecules pass both between and through cells. We measured the transfer of tritiated water (TOH) from CSF to blood across the ependymal and capillary interfaces by ventriculocisternal (VC) steady-state tissue clearance. Adult cats anesthetized with pentobarbital sodium underwent VC perfusion with the extracellular marker (/sup 14/C)sucrose and TOH added to the artificial CSF. Brain tissue was analyzed for depth of penetration of the isotopes into periventricular gray matter. We found that TOH distribution space was lower than expected from water content measurements, whereas sucrose space was normal. Using VC steady-state equations we calculated an ependymal permeability that was similar to the permeability of the ...

Energy Technology Data Exchange (ETDEWEB)

Conditions of the separation and detection of organic and inorganic anions by gradient ion chromatography and suppressed conductivity detection were studied, and the procedure of gradient elution was optimized. A detection limit of 1 x 10{sup -3} {mu}g x L{sup -1} was obtained using the pre-concentrated column and most relative standard deviations obtained in the determination of seven organic and inorganic anions were below 5%. This method was proved to be simple, rapid and accurate for the separation and determination of low-molecular-weight organic acids and inorganic anions and could be applied in the analysis of the samples from water and steam systems of thermal power plants with satisfactory results. (orig.)

Energy Technology Data Exchange (ETDEWEB)

Municipal solid waste incineration (MSWI) bottom ash contains economically significant levels of silver and gold. Bottom ashes from incinerators at Amsterdam and Ludwigshafen were sampled, processed, and analyzed to determine the composition, size, and mass distribution of the precious metals. In order to establish accurate statistics of the gold particles, a sample of heavy non-ferrous metals produced from 15 tons of wet processed Amsterdam ash was analyzed by a new technology called magnetic density separation (MDS). Amsterdam's bottom ash contains approximately 10 ppm of silver and 0.4 ppm of gold, which was found in particulate form in all size fractions below 20 mm. The sample from Ludwigshafen was too small to give accurate values on the gold content, but the silver content was found to be identical to the value measured for the Amsterdam ash. Precious metal value in particles smaller than 2 mm seems to ...

Energy Technology Data Exchange (ETDEWEB)

During the five plus years this Cooperative Agreement existed, more than 45 different projects were funded. Most projects were funded for a one year period but there were some, deemed of such quality and importance, funded for multiple years. Approximately 22 external agencies, businesses, and other entities have cooperated with or been funded through the WVU Cooperative Agreement over the five plus years. These external entities received 33% of the funding by this Agreement. The scope of this Agreement encompassed all forms of hazardous waste remediation including radioactive, organic, and inorganic contaminants. All matrices were of interest; generally soil, water, and contaminated structures. Economic, health, and regulatory aspects of technologies were also within the scope of the agreement. The highest priority was given to small businesses funded by the Federal Energy Technology Center (FETC) and Department of Energy (DOE) involved in research and development ...

Energy Technology Data Exchange (ETDEWEB)

The shortage of fresh water is increasing at alarming levels, even in temperate zones. Desalination of brackish and seawater is being considered as a solution to growing water demands. Seawater desalination can be accomplished through reverse osmosis, vapor compression, vapor absorption and thermally driven systems. The most suitable process for large-scale desalination plants is successive brine evaporation-condensation with intermediate heat recovery. However, higher process efficiency could be achieved. The use of low temperature heat sources in seawater desalination requires an efficient method of evaporation and condensation at relatively low vapor pressures. This could be achieved in a humidification-dehumidification process using circulated air to enhance evaporation of water. Simulation models, however, neglect either the heat of evaporation or the ...

International Nuclear Information System (INIS)

Active Process Water (APW) System, provided as unitized closed loop system in Tarapur Atomic Power Project Units-3 and 4, serves to remove heat from various heat exchangers. One of the important loads served by APW system is shutdown cooling heat exchangers and if APW shutdown is taken then reactor cannot be maintained in cold shutdown condition. It is estimated that after 7 days of reactor shutdown, if about 20% of the normal cooling flow to shutdown cooling heat exchangers is provided then along with keeping PHT in cold shutdown state, reactor components, moderator, end shield water, calandria vault water and calandria vault concrete temperature can be maintained within technical specification limits for extended duration. (author)

Energy Technology Data Exchange (ETDEWEB)

Photodestruction has received much attention in recent years. In particular, titanium dioxide (TiO{sub 2}) and ozonolysis have attained a position of prominence. These technologies hold promise for the destruction of trace amounts of aqueous high explosives that are generated by load and pack operations, as well as demilitarization activities. Currently this water is treated by passing through a bed of activated carbon. The carbon is then steam regenerated and reused, thus creating a second waste stream which must be disposed of, or the carbon is burned directly. Recent trends in environmental regulation have shown that this may not be a viable option for process water remediation in the future. This talk will discuss efforts to employ alternate aqueous treatment techniques that not only remove the explosives compounds but are able to transform the parent compound into carbon dioxide and water. Titanium ...

Energy Technology Data Exchange (ETDEWEB)

Recycling of the spent rinse water discharged from the wet benches commonly used in semiconductor processing is one tactic for responding to the targets for water usage published in the 1997 National Technology Roadmap for Semiconductors (NTRS). Not only does the NTRS list a target that dramatically reduces total water usage/unit area of silicon manufactured by the industry in the future but for the years 2003 and beyond, the NTRS actually touts goals which would have semiconductor manufacturers drawing less water from a regional water supply per unit area of silicon manufactured than the quantity of ultrapure water (UPW) used in the production of that same silicon. Achieving this latter NTRS target strongly implies more widespread recycling of spent rinse waters at semiconductor manufacturing sites. In spite of the fact ...

Energy Technology Data Exchange (ETDEWEB)

Chemical-looping combustion (CLC), has previously been studied as a method for separating CO{sub 2} during combustion of gaseous fuels. In this project the possibility to apply this process for direct use of solid fuels has been investigated. The following has been accomplished: A 10 kW reactor system for CLC with solid fuels has been designed and built. Tests with solid fuel and metal oxid particles in a laboratory reactor show that it is possible to oxidize solid fuels with metal oxide particles in cyclic testing, thus giving proof of basic concept. They also show how the reaction rate is affected by temperature, steam concentration etc., and, most important of all, that the rates of reaction are realistic. Tests with metal oxide materials available at low costs have been successful. Chemical-looping combustion with solid fuels has a potential to achieve very low costs for separation of CO{sub 2}, below 10 Euro/ton CO{sub ...

International Nuclear Information System (INIS)

BIBRA "t"r"a"d"e"m"a"r"k, is the new bio-technological method developed in Gundremmingen for treating radioactive waste water, using bacteria in a process analogous to the long-established principle of communal sewage treatment plants. The method exploits the behaviour of the micro-organisms found there, to establish optimum adaptation of their population for decomposing the typical pollutants found in this washing water. This procedure is particularly suitable for nuclear engineering plants, because in such plants the waste water composition changes little so that the bacteria can achieve optimum adaptation to this waste water. The organic ingredients of the washing media are decomposed by introducing air. The advantage of the procedure is not only the significant reduction of the amount of waste material, but also enhanced efficiency of the cleaning process. ...

International Nuclear Information System (INIS)

Environmental targets and saving energy have become ones of the world main concerns over the last years and it will increase and become more important in a near future. The world population growth rate is the major factor contributing for the increase in global pollution and energy and water consumption. In 2005, the world population was approximately 6.5 billion and this number is expected to reach 9 billion by 2050 [United Nations, 2008. (www.un.org), accessed on July]. Water supply systems use energy for pumping water, so new strategies must be developed and implemented in order to reduce this consumption. In addition, if there is excess of hydraulic energy in a water system, some type of water power generation can be implemented. This paper presents an optimization model that determines the best hourly operation for 1 day, according to the electricity tariff, for a pumped ...

Energy Technology Data Exchange (ETDEWEB)

A water trap system based on a thermoelectric cooling device is employed to remove a major fraction of the water from air samples, prior to analysis of these samples for chemical composition, by a variety of analytical techniques where water vapor interferes with the measurement process. These analytical techniques include infrared spectroscopy, mass spectrometry, ion mobility spectrometry and gas chromatography. The thermoelectric system for trapping water present in air samples can substantially improve detection sensitivity in these analytical techniques when it is necessary to measure trace analytes with concentrations in the ppm (parts per million) or ppb (parts per billion) partial pressure range. The thermoelectric trap design is compact and amenable to use in a portable gas monitoring instrumentation.

Energy Technology Data Exchange (ETDEWEB)

The separation of bitumens (B) and natural asphalts using a dialysis (D) method is studied. A moderately vulcanized latex of natural rubber, which was subjected to extraction by cold n-hexane prior to use, was used as the material of the membrane for dialysis. With dialysis of bitumen samples dispersed in a small quantity of n-alkane in a Soxhlet apparatus three fractions were acquired: a dialyzate, an undialyzable fraction and asphaltenes (the residue). N-pentane, n-hexane and n-heptane were used as the solvents for dialysis. Samples of oxidized road bitumen, grade AOSI 85/25, bitumens from the process of propane deasphaltization, natural asphalts from Trinidad and Albania and A80 grade bitumens from the oil distillation process were isolated using the dialysis method. The reproducability of the output of the fractions with varying suspensions and productivity of the dialysis, the dependence of the output on the length of ...

Energy Technology Data Exchange (ETDEWEB)

Certification as applied to existing computer codes includes the verification and validation process, placing the code in configuration control, establishing user qualification standards and training requirements. All software intended for use in critical calculations must be certified. This report is intended to fulfill the requirements for the certification of the SHIELD, SHLDED, GEDIT, GENPRT, FIPROD, FPCALC, and PROCES modules of the SHIELD system built February, 1992, by W.S. Parks. These modules are used for burnup, cooling, separate, and edit calculations.

Energy Technology Data Exchange (ETDEWEB)

This paper reviews the mill flowsheet applied at the COMINAK uranium mill (Compagnie Miniere d'Akouta) in Niger. For ore treatment, it focuses on the major improvements to the operations using sulfonitric pugging and solids/liquid separation using belt filter double filtration after leaching. The precipitation circuits have been improved with molybdenum elimination through caustic washing of the yellow cake. (author)

Energy Technology Data Exchange (ETDEWEB)

The Monte Carlo simulation method is applied to calculate the nucleon transfer part of the imaginary optical-model potential in colliding heavy ions. In the process of transfer of nucleons from one nucleus to the other, forward and backward neutrons and protons are treated separately by taking into consideration the effect of the Coulomb forces and the potential energy surfaces (driving forces). The Pauli exclusion principle is also incorporated properly in the calculation.

Energy Technology Data Exchange (ETDEWEB)

A krypton recovery pilot plant has been completed for the Power Reactor and Nuclear Fuel Development Corporation. This is the first industrial facility in the world to make practical use of development results for offgas treatment and storage from nuclear facilities. The cryogenic distillation process was adopted as a proven and reliable method to separate krypton and xenon, and to reduce gas effuents to a level so low that the decontamination factor amounts to more than 1000.

International Nuclear Information System (INIS)

This symposium was held February 22--24, 1995 in Las Vegas, Nevada. The purpose of this meeting was to provide a multidisciplinary forum for exchange of state-of-the-art screening methods for environmental monitoring and remedial action planning of hazardous materials. In the last few years important advances have been made in the management of hazardous materials. Individual papers have been processed separately for inclusion in the appropriate data bases.

International Nuclear Information System (INIS)

This paper describes a process for the direct production of a superconductive niobium-titanium alloy during reduction of niobium pentoxide. It comprises: mixing at least one of titanium metal powder and titanium dioxide powder with niobium pentoxide powder and aluminum powder; heating the resulting mixture to form a niobium-titanium alloy and a slag consisting essentially of aluminum oxide; and separating the alloy and the slag.

Energy Technology Data Exchange (ETDEWEB)

A sensitive and rapid automated method has been developed for the selective analysis of acid extractable sulfide in environmental samples by combining gas dialysis separation techniques with methylene blue detection procedures. Acid extractable sulfide is separated from the sample matrix by the gas dialysis membrane and subsequently trapped in a dilute sodium hydroxide receiving stream. This stream is reacted with N,N-dimethyl-p-phenylenediamine and ferric chloride to produce methylene blue which is then quantitated colorimetrically at 660 nm. For standards and nonturbid environmental samples, there is good agreement between the results obtained by this procedure and the standard methylene blue method. The effect of interferences on the accurate determination of sulfide by both methods was also examined and it was found that cupric ions significantly interfered with sulfide estimation. To obtain adequate sulfide recoveries in tap ...

International Nuclear Information System (INIS)

No-carrier-added astatine radionuclides produced in the "7Li-irradiated lead matrix were separated from bulk lead nitrate target by complexing At with insulin, followed by dialysis. The method offers simultaneous separation of At from lead as well as its complexation with insulin. The At-insulin complex might be a potential radiopharmaceutical in the treatment of hepatocellular carcinoma. The stability of At-insulin complex was checked by dialysis against deionized water and Ringer lactate (RL) solution. It has been found that the half-life of At-insulin complex is about #approx#12 h, when dialyzed against deionized water and is only 6 h, when dialyzed against RL solution having the same composition as blood serum. The 6 h half-life of this Insulin-At complex is perfect for killing cancer cells from external cell surfaces as the half-life of internalization of insulin molecule inside the cell is 7-12 h.

International Nuclear Information System (INIS)

Many countries are liberalizing their energy markets. Participants in these markets are exposed to market risk due to the characteristics of electricity price dynamics. Electricity prices are known to be mean-reverting very volatile and subject to frequent spikes. Models that describe the dynamics of electricity prices should incorporate these characteristics. In order to capture the price spikes, many researchers have introduced stochastic jump processes, but we argue and show that this specification might lead to potential problems with specifying the true amount of mean-reversion within the process. In this paper, we propose a regime-switching model that models price spikes separated from normal mean-reverting prices.

Energy Technology Data Exchange (ETDEWEB)

The DP West Plutonium Facility operated by the Los Alamos National Laboratory, Los Alamos, New Mexico, was decontaminated between April 1978 and April 1981. The facility was constructed in 1944 to 1945 to produce plutonium metal and fabricate parts for nuclear weapons. It was continually used as a plutonium processing and research facility until mid-1978. Decontamination operations included dismantling and removing gloveboxes and conveyor tunnels; removing process systems, utilities, and exhaust ducts; and decontaminating all remaining surfaces. This report describes glovebox and conveyor tunnel separations, decontamination techniques, health and safety considerations, waste management procedures, and costs of the operation.

International Nuclear Information System (INIS)

The author presents a new technique for production of yellow cake with double precipitation, thus solving a series of problems for precipitating uranium with traditional double precipitation. The new technique can not only remove ferric ions and sulfate radicals but also make solid-liquid separation easy, utilize effectively the sulfuric acid produced in ferric ions precipitation process, and increase uranium concentration of leaching liquor. To take it as producing yellow cake will save investment, simplify operation, and cut down the consumption of raw materials and energies. It is more competitive than ion-exchange or solvent extraction in the process of extracting-purifying and preparing yellow cake.

Energy Technology Data Exchange (ETDEWEB)

A highly reliable control rod drive mechanism (CRDM) installed inside the reactor vessel has developed for use of an advanced marine reactor. This CRDM contributes to compactness and simplicity of the reactor system, and it can eliminate the possibility of a rod ejection accident. The CRDM works in the high temperature and high pressure water - 310degC and 12 MPa, the same atmosphere as the primary loop. Driving force is produced by a synchronous motor with the rotor of a permanent magnet, which has been developed. An innovative latch mechanism using separable ball nuts can latch driving shaft connecting the control rod and de-latch it for scram. The rod position detector using a magnetostrictive wire type sensor on the principle of Wiedeman effect has been developed, accuracy of which is verified to have a detecting error within 1.2 mm. Ball bearings for thrust and radial supports in rotation have been developed to be capable of working under ...

British Library Electronic Table of Contents (United Kingdom)

A stable BSA blocking poly(dimethylsiloxane) (PDMS) microchannel was prepared based on in situ synthesized PDMS-gold nanoparticles composite films. The modified microchip could successfully suppress protein adsorption. The assembly was followed by contact angle, charge-coupled device (CCD) imaging, electroosmotic flow (EOF) measurements and electrophoretic separation methods. Contact angle measurements revealed the coated surface was hydrophilic, water contact angle for coated chips was 45.2^o compared to a water contact angle for native PDMS chips of 88.5^o. The coated microchips exhibited reproducible and stable EOF behavior. With FITC-labeled myoglobin incubation in the coated channel, no fluorescence was observed with CCD image, and the protein exhibited good electrophoretic effect in ...

CERN Document Server

The effect of the wind on the sustain of extreme water waves is investigated experimentally and numerically. A series of experiments conducted in the Large Air-Sea Interactions Facility (LASIF) showed that a wind blowing over a strongly nonlinear short wave group due to the linear focusing of a modulated wave train may increase the life time of the extreme wave event. The expriments suggested that the air flow separation that occurs on the leeward side of the steep crests may sustain longer the maximum of modulation of the focusing-defocusing cycle. Based on a Boundary-Integral Equation Method and a pressure distribution over the steep crests given by the Jeffreys'sheltering theory, similar numerical simulations have confirmed the experimental results

International Nuclear Information System (INIS)

Co-current stratified flow of liquid metal and water was investigated in a horizontal rectangular channel. Position of the interface pressure drop and direct contact heat transfer between these immisci ble liquids were measured in a fully developed flow. A turbulence model was proposed to explain the experimental results considering that the turbulence is damped near the liquid-liquid interface by surface tension. The analytical results showed good agreement with the experimental ones. Main results are that (1) position of the interface mainly depends on the flow rate ratio of both liquids, that (2) the pressure drop is approximately proportional to square of the average velocity of water, and that (3) heat transfer rate at direct contact interface is several times higher than that of co-current flow separated by a thin solid plate. (author).

Energy Technology Data Exchange (ETDEWEB)

A new technique has been developed for the measurement of steam mass flowrate, water mass flowrate and total enthalpy of two-phase fluids produced from geothermal wells. The method involves precisely metered injection of liquid and vapor phase tracers into the two-phase production pipeline and concurrent sampling of each phase downstream of the injection point. Subsequent chemical analysis of the steam and water samples for tracer content enables the calculation of mass flowrate for each phase given the known mass injection rates of tracer. This technique has now been used extensively at the Coso geothermal project, owned and operated by California Energy Company. Initial validation of the method was performed at the Roosevelt Hot Springs geothermal project on wells producing to individual production separators equipped with orificeplate flowmeters for each phase.

CERN Document Server

Land snails move via adhesive locomotion. Through muscular contraction and expansion of their foot, they transmit waves of shear stress through a thin layer of mucus onto a solid substrate. Since a free surface cannot support shear stress, adhesive locomotion is not a viable propulsion mechanism for water snails that travel inverted beneath the free surface. Nevertheless, the motion of the freshwater snail, Sorbeoconcha physidae, is reminiscent of that of its terrestrial counterparts, being generated by the undulation of the snail foot that is separated from the free surface by a thin layer of mucus. Here, a lubrication model is used to describe the mucus flow in the limit of small amplitude interfacial deformations. By assuming the shape of the snail foot to be a traveling sine wave and the mucus to be Newtonian, an evolution equation for the interface shape is obtained and the resulting propulsive force on the snail is calculated. This ...

Energy Technology Data Exchange (ETDEWEB)

The theme of the conference was recent developments in airborne remote sensing and their applications. The proceedings contain the papers presented at 14 general sessions and 13 interactive sessions covering airborne platforms, sensor systems, airborne/spaceborne synergy, atmospheric and oceanic measurements, land cover/land use, emergency response and reconnaissance, data handling, forestry, agriculture, water resources, geospatial reference, system calibration, environmental monitoring and planning, and information product advancements. Two papers are abstracted separately.

Energy Technology Data Exchange (ETDEWEB)

This conference provided a forum to discuss advances in the application of bioengineering principles and practices dealing with biological systems for the production of food, bioproducts and energy. The topics of discussion ranged from engineering practices in agriculture, forestry, bioresources, biochemistry and biosystems. The sessions of the conference were entitled: renewable energy; waste management; soil and water; machinery systems; building and storage systems; and bioproducts and food. The conference also featured a workshop on integrated biomass supply and logistics. In addition to 20 posters, the conference featured 67 presentations, of which 3 have been catalogued separately for inclusion in this database. refs., tabs., figs.

Energy Technology Data Exchange (ETDEWEB)

A collection of 14 papers from a June 1981 seminar assess the costs of damage caused by water pollution. The seminar focused on the economic rather than the legal standpoint by evaluating the cost of the clean-up operations themselves and other costs, such as direct or indirect economic losses, and converting into money terms the damage to the environment, the loss of recreational facilities, and biomass losses. The papers are grouped into four sections which look at the scale of risk, the clean-up costs for specific oil spills, other costs inflicted on coastal zones, and legal aspects of compensation. Separate abstracts were prepared for each of the 16 papers selected for the Energy Data Base.

Science.gov (United States)

While tritium exposure to the site-workers in Wolsung NPP is up to about 40% of the total personnel exposure, Ministry of Science and Technology has asked tritium removal facility for requirement of post heavy-water reactor construction. For the purpose o...

Energy Technology Data Exchange (ETDEWEB)

The causes and processes of contamination, as well as the possible human health implications for the main contaminants of drinking water are described. The quality of drinking water in Italy is defined through the comparison of the pollutant levels with the World Health Organization guidelines published in 1993 and the USEPA HAs (Health Advisories) of 1994 (annexed to the report).

Energy Technology Data Exchange (ETDEWEB)

The characteristics of solidification and melting are reviewed. The properties of water and ice and the phase diagram of water are discussed with special emphasis on ice density. A concise account of the freezing process and the Stefan problem is presented. To this end, the four stages of freezing are identified, supercooling, nucleation and the formation of dendritic ice, the growth of concentric rings of solid ice at 0{sup o}C and the final cooling of the solid ice are treated in some detail. The subject of bursting of pipes is given particular emphasis. Attention is drawn to a common misconception on pipe bursting and to misleading relationships for the computation of freezing time for ice blockage. Several current applications of melting and freezing systems are outlined. (author)

International Nuclear Information System (INIS)

This document is a summary of the available information on the thermo-hydro-mechanical properties of the bentonite barrier of a high-level radioactive waste repository and of the processes taking place in it during the successive repository operation phases. Mainly the thermal properties, the volume change processes (swelling and consolidation), the permeability and the water retention capacity are analysed. A review is made of the existing experimental knowledge on the modification of the these properties by the effect of temperature, water salinity, humidity and density of the bentonite, and their foreseen evolution as a consequence of the processes expected in the repository. The compiled evolution refers mostly to the FEBEX (Spain), the MX-80 (USA) and the FoCa (France) bentonite, considered as reference barrier materials in several European disposal concepts. (Author) 102 refs.

International Nuclear Information System (INIS)

On the basis of environmental considerations, a high temperature gas cooled reactor (HTGR) was proposed as the heat source for the Natuna project for CO_2 conversion. To convert CO_2 to useful products, a large amount of high quality water is required for the chemical processes, boilers and other purposes. One LNG production train (maximum of six trains) would produce 0.4 x 10"9 SCF/d of saleable gas and 1.4 x 10"9 SCF/d of CO_2 (in the case of the Exxon process). This CO_2 gas would then be converted to automobile fuel (methane, methanol), which requires a large amount of water. Natural gas from an off- shore gas field is piped to the petrochemical complex on Natuna Island (about 228 km). Natuna is a small island that, apart from sea water, does not have much available water. The desalination process is considered to be the only solution to ...

Environmental Research Database

DescriptionRemote sensing of the sea surface from satellites in near-polar orbits has contributed greatly to our understanding of the links between physical and biological processes in marine systems. However most of this progress has been made in open oceanic waters or major upwelling areas, and many unresolved problems are encountered in coastal regions and shelf seas. In these optically complex waters, quantitative remote sensing requires a more sophisticated interpretation strategy than that implemente [continued...

British Library Electronic Table of Contents (United Kingdom)

The humidification?dehumidification process is an interesting technique that has been adapted for water desalination. Previous works experimentally investigated desalination processes in the shell and tube columns, where the humidification and dehumidification were thermally coupled and simultaneously performed at the tube and shell sides, respectively. In this work, a comprehensive steady-state mathematical model was developed for such a humidification?dehumidification desalination process by taking into account the heat and mass balances on both sides of the desalting column, the mass transfer rate at the humidification side, and the heat transfer rate between the dehumidification side and humidification side. Meanwhile, the mass transfer coefficient at the humidification side and the to...

Energy Technology Data Exchange (ETDEWEB)

Tritium removal from tritiated heavy water in a PHWR is the most effective way in reducing workers` internal dose and radioactivity emissions from Wolsong NPP. The optimum design of the Wolsung TRF(Tritium Removal Facility) was carried out using an approximate short-cut method with an assumption that the TRF, designed to extract 8 MCi per year of elemental tritium from a heavy water feedstream, uses Liquid Phase Catalytic Exchange (LPCE) front-end process and Cryogenic Distillation (CD) process. 19 refs., 6 figs., 2 tabs. (author).

Energy Technology Data Exchange (ETDEWEB)

A large amount of industrial water is used for cooling the various process fluids in the petroleum purification factories as well as petroleum chemistry factories. Consequently, a lot of heat exchangers as the necessary constitutional instruments are made of carbon steel. Due to the most of the corrosions of the carbon steel occurring in such cooling water systems are pitting corrosions, the inhibition thereof is extremely important for the elongation of the life of the plants and the stable operation. In this paper, the influences of water quality fractions on pitting corrosion of carbon steel in cooling water circumstance are examined aiming at the fouling in the cooling water. The fouling in the cooling water does not only increase the amount of occurrence of pitting corrosion but also accelerates the progress of pitting corrosion ...

International Nuclear Information System (INIS)

The process of infrared multiple photon dissociation (IRMPD) of molecules is of great fundamental importance and has practical significance, such as isotope separation etc. Unfortunately, a clear insight into the process has been hindered by the bewildering array of important variables affecting MPD. The dissociation probability #gamma#(#phi#) i.e. the yield has been found to be a sensitive function of laser fluence #phi# along with numerous other parameters like laser frequency, gas pressure etc. We have shown that in single frequency IRMPD an accurate quantitative characterization of the dissociation probability can be adequately expressed by a 'power law' model with two fitting parameters namely critical fluence, #phi#c and multi photon order, m. This model was exploited in analysing our MPD results on various systems. However, the small isotope shift encountered in heavy elements and the sticking phenomenon observed in ...

International Science & Technology Center (ISTC)

Development of a Plant for Neon Isotopes Separation by Low-Temperature Rectification Method

Energy Technology Data Exchange (ETDEWEB)

The Energy Conversion and Storage Program applies chemistry and materials science principles to solve problems in (1) production of new synthetic fuels, (2) development of high-performance rechargeable batteries and fuel cells, (3) development of advanced thermochemical processes for energy conversion, (4) characterization of complex chemical processes, and (5) application of novel materials for energy conversion and transmission. Projects focus on transport-process principles, chemical kinetics, thermodynamics, separation processes, organic and physical chemistry, novel materials, and advanced methods of analysis. Electrochemistry research aims to develop advanced power systems for electric vehicle and stationary energy storage applications. Topics include identification of new electrochemical couples for advanced rechargeable batteries, improvements in battery and fuel-cell ...

Science.gov (United States)

Appendices to this summary consist of twelve individual status reports that will be available through the National Technical Information Service (NTIS) in the United States and of course limited copies will be available through NATO. The twelve report titles which are appendices to the summary are: (A) Status Report on the Limestone/Sludge Flue Gas Desulfurization Process; (B) Status Report on the Lime/Sludge Flue Gas Desulfurization Process; (C) Status Report on the Double Alkali/Sludge Flue Gas Desulfurization Process; (D) Status Report on the Sea Water Scrubbing Flue Gas Desulfurization Process; (E) Status Report on the Limestone/Gypsum Flue Gas Desulfurization Process; (F) Status Report on the Lime/Gypsum Flue Gas Desulfurization Process; (G) Status Report on the Double Alkali/Gypsum Flue Gas Desulfurization Process; ...

Energy Technology Data Exchange (ETDEWEB)

Source Philippe (on the island of La Govave, near Haiti) is described in terms of climatic, sociological, agricultural and technical background. Because of drought conditions, it became necessary to develop a solar still to provide the town with sufficient fresh water. The still, which has been in operation since 1969, is described in some detail as is the construction process. Brackish and sea water are used to produce more than 1250 liters of fresh water each day. A windmill is used to pump the brackish water from a well to an elevated storage tank; it flows by gravity to solar still basins where it is vaporized, then condensed on a sloping glass surface and collected. Benefits of the solar still to the town's economy and health are discussed. Cost of the project was $17,000. 10 references. (MJJ)

British Library Electronic Table of Contents (United Kingdom)

In radio signal-based observing systems, such as Global Positioning System (GPS) and Interferometric Synthetic Aperture Radar (InSAR), the water vapor in the atmosphere will cause delays during the signal transmission. Such delays vary significantly with terrain elevation. In the case when atmospheric delays are to be eliminated from the measured raw signals, spatial interpolators may be needed. By taking advantage of available terrain elevation information during spatial interpolation process, the accuracy of the atmospheric delay mapping can be considerably improved. This paper first reviews three elevation-dependent water vapor interpolation models, i.e., the Best Linear Unbiased Estimator in combination with the water vapor Height Scaling Model (BLUE?+?HSM), the Best Linear Unbiased Es...

British Library Electronic Table of Contents (United Kingdom)

The purpose of this paper is to establish probabilistic models for still-water loads, based on design data, and the combined still-water and wave load effects for semi-probabilistic and probabilistic design of floating production, storage and offloading vessels (FPSO). A new still-water load model for FPSOs is proposed, based on a Poisson square-wave model, with a modified Weibull distribution for load intensity, which accounts for load control during operation. The long-term variation of wave-induced load effects is modelled by a Poisson square-wave process. A new solution for the combined effect is derived. A procedure for determining characteristic extreme values for individual and combined load effects, and load combination factors, is established. The methodology is used to illustrate...

International Nuclear Information System (INIS)

The purpose of this text is to train engineers and technologists not just to understand corrosion but to control it. Materials selection, coatings, chemical inhibitors, cathodic and anodic protection, and equipment design are covered in separate chapters. High-temperature oxidation is discussed in the final two chapters ne on oxidation theory and one on controlling oxidation by alloying and with coatings. This book treats corrosion and high-temperature oxidation separately. Corrosion is divided into three groups: (1) chemical dissolution including uniform attack, (2) electrochemical corrosion from either metallurgical or environmental cells, and (3) stress-assisted corrosion. Corrosion is logically grouped according to mechanisms rather than arbitrarily separated into different types of corrosion as if they were unrelated. For those university students and industry personnel who approach corrosion theory very hesitantly, ...

Energy Technology Data Exchange (ETDEWEB)

This presentation describes a method for separating {sup 14}C-hexose from {sup 14}C-sucrose in extracts of plant tissue. Portions of ethanol extracts are treated with activated charcoal in microcentrifuge tubes. Aliquots are removed, ethanol evaporated and replaced with reaction mixture that phosphorylates hexose (HEPPS, K{sub 2}HPO{sub 4}, Mg(C{sub 2}H{sub 3}O{sub 2}){sub 2}, ovalbumen, Na{sub 2}ATP, yeast hexokinase). After a time course, the hexokinase reaction is stopped (slowed considerably) to minimize effects of contamination enzyme activities. The stopping agent used is lyxose, a nonphosphorylable analogue of glucose. The strong anionic charge of phosphate introduced through the hexokinase action results in binding (> 95%) of hexose-phosphate to anion-exchange resin. Sucrose remains unbound (> 95%) in solution. This batch ion-exchange is performed in microcentrifuge tubes to allow many samples to be processed simultaneously. ...

Energy Technology Data Exchange (ETDEWEB)

The oil shale PCTM for Modified In Situ Oil Shale Retorting combined with Lurgi Surface Retorting addresses the application of this combination of technologies to the development of oil shale resources in the western United States. This manual describes the combined plant using Lurgi surface retorting technology (developed by Lurgi Kohle and Mineralotechnik GmbH, West Germany) and the Modified In Situ process (developed by Occidental Oil Shale, Inc.) proposed by Occidental Oil Shale, Inc. and Tenneco Shale Oil Company for use in the development of their Federal oil shale lease Tract C-b in western Colorado. Since details regarding waste streams and control technologies for the Lurgi process are presented in a separate PCTM, this document focuses principally on the Modified In Situ process.

Energy Technology Data Exchange (ETDEWEB)

The improvement of the ecological conditions at waste storing reservoirs is an important task of the restoration activity at Production Association (PA) ``Mayak`` (South Urals). The radionuclides mostly {sup 90}Sr, {sup 137}Cs, and chemical pollutants deposited in the reservoir water and in the bottom sediment are very dangerous sources for the contamination of Techa River below the reservoirs and the contamination of groundwater in the surrounding formations. The spreading of radioactive contaminants has both hydrogeological and the chemical features. The thermodynamic approach used to account for physical-chemical interactions between water and the bed rocks based on Gibbs free energy minimization of multicomponent system (H-O-Ca-Mg-K-Na-S-Cl-C-Sr) permitted the authors to calculate the corresponding ionic and complex species existing in the solutions, and to characterize the processes of precipitation and dissolution. ...

International Nuclear Information System (INIS)

An experimental investigation of a humidification-dehumidification desalination (HDD) process using solar energy at the weather conditions of Suez City, Egypt, is presented. A test rig is designed and constructed to conduct this investigation under different environmental and operating conditions. The test rig consists of a solar water heater (concentrator solar collector type), solar air heater (flat plate solar collector type), humidifier tower and dehumidifier exchanger. Different variables are examined including the feed water flow rate, the air flow rate, the cooling water flow rate in the dehumidifier and the weather conditions. Comparisons between the experimental results and other published results are presented. It is found that the results of the developed mathematical model by the same authors are in good agreement with the experimental results. The tested results show that the productivity ...

Science.gov (United States)

The investigation of various Two-Stage Liquefaction (TSL) process configurations was conducted at the Wilsonville Advanced Coal Liquefaction R D Facility between July 1982 and September 1986. The facility combines three process units. There are the liquefaction unit, either thermal (TLU) or catalytic, for the dissolution of coal, the Critical Solvent Deashing unit (CSD) for the separation of ash and undissolved coal, and a catalytic hydrogenation unit (HTR) for product upgrading and recycle process solvent replenishment. The various TSL process configurations were created by changing the process sequence of these three units and by recycling hydrotreated solvents between the units. This report presents a description of the TSL configurations investigated and an analysis of the operating and performance data from the period of study. Illinois No. 6 Burning Star ...

Energy Technology Data Exchange (ETDEWEB)

Many countries which do not produce oil are rich with other sources of energy that are not fully utilised, such as tar sand, oil shale and olive cake. Limited previous work was done on producing carbonaceous matter and separating volatile matter from combinations of tar sand, oil shale and olive cake. In this study, a process is designed and tested to produce carbonaceous matter from combinations of three materials mentioned above. Results indicate that the process is successful in producing carbonaceous matter. The minimum temperatures to achieve complete carbonisation was found to be 500degC for a minimum heating time of 1.5h. Carbonised materials were tested for their calorific values, which indicated a successful carbonisation process. The proposed process can be scaled up and automated, and is expected to be economically feasible. Moreover, the process ...

Energy Technology Data Exchange (ETDEWEB)

Chemical oxidation is a treatment technology that uses powertul chemical oxidizers to destroy organic contaminants. Typical oxidizers used in chemical oxidation processes include ozone, hydrogen peroxide, chlorine, and potassium permanganate. The chemical reaction products are usually simple organic compounds, such as carboxylic acids, and/or inorganic compounds, such as carbon dioxide, water, and simple inorganic complexes (e.g., chloride salts, in the case of chemical oxidation treatment of chlorinated solvents).

Energy Technology Data Exchange (ETDEWEB)

Several shield options were analyzed for the ITER conceptual design to minimize the nuclear responses in the toroidal field (TF) coils. The total nuclear heating in the physics phase and the insulator dose in the technology phase are the most critical parameters in the design process. The first shield option has type 316 stainless steel and water shielding material. Steel and water also serve as structural material and coolant, respectively. The second option is similar to the first except that borated water is used instead of ordinary water. The other two options include a small layer of lead or boron carbide (B{sub 4}C) at the back of the shield. The last three shield options were considered to reduce the nuclear heating in the toroidal field coils relative to the steel/water shield. An optimization process was performed taking into ...

International Nuclear Information System (INIS)

Previous flow regime studies have been for horizontal, vertical, and inclined pipe flow. As such, only a few studies have been performed on bundle geometries. The present paper examines the flow regimes for a vertical hexagonal flow channel with and without a finned fuel bundle. This type of a 36 finned rod hexagonal fuel bundle in parallel hexagonal flow channels is used in a MAPLE (Multi- purpose Applied Physics Lattice Experimental) type nuclear reactor. An experiment apparatus was designed consisting of the flow channel, inlet plenum and an air-water separator. The inlet plenum is used to provide a uniform mixture of air and water before entering the hexagonal flow channel. A turbine flow meter is used to determine the water flow rate. The turbine flow meter is calibrated for a low flow range and limits the measurable flow to 50 l/min. Flow pattern observation is determined by a SONY video camera, ...

Energy Technology Data Exchange (ETDEWEB)

This paper elucidates morphological characteristics, reproduction forms and ecological characteristics of Plectus sp. and Rhabditis sp. which are most frequently detected nematodes separated from tap water. The paper also discussed experimentally establishment of cultivating conditions for these nematodes, and behavior and reproduction characteristics of nematodes under widely ranging conditions of temperatures, bacteria concentrations and pH. Plectus sp. grows in hermaphroditic individuals, while Rhabditis sp. grows only in female. An LE culture medium can cultivate nematodes that appear in tap water, and is suitable for subculture of nematodes. Conditions of temperatures from 20{degree}C to 25{degree}C, pH and inoculated concentration of bacteria at 10{sup 8} cell {center_dot} ml{sup -1} are suitable for reproduction of Plectus sp. and Rhabditis sp. Plectus sp. and Rhabditis sp. prefer mild temperatures for reproduction, ...

Energy Technology Data Exchange (ETDEWEB)

A cryogenic separation method of chloromethane (CH{sub 3}Cl) from methyl iodide (CH{sub 3}I) for {delta}{sup 37}Cl measurement with isotope ratio mass spectrometer is described. A cold trap with sealed 2,2,4-trimethylpentane (TMP) as the cryogen is used in this method. CH{sub 3}Cl can be separated from CH{sub 3}I at the TMP melting point (-107 deg. C) based on the difference in the vapor pressure between CH{sub 3}Cl (322.6 Pa) and CH{sub 3}I (lower than 1.3 Pa) at -107 deg. C. After two-step separation processes, the yields of CH{sub 3}Cl purified from CH{sub 3}Cl-CH{sub 3}I mixture are 96-101%, and the difference between the {delta}{sup 37}Cl{sub original} and {delta}{sup 37}Cl{sub Afterseparation} is from -0.06 to +0.06 per mille (0.01 {+-} 0.04 per mille ). These results suggest that CH{sub 3}Cl is completely separated from CH{sub 3}I with no change of {delta}{sup 37}Cl value. ...

Energy Technology Data Exchange (ETDEWEB)

The integrity of the RPV head and reactor internals was assessed by means of fluid-structural analyses using a coupled method to evaluate the water hammer phenomenon arising from high burnup fuel failure under RIA conditions. The fluid viscosity effect on the water column burst as well as the complex three-dimensional flow paths caused by a core shroud and standpipes were considered in this study. The three analysis scenarios were designed to investigate the above mentioned influential factors separately. In the first scenario, a two-dimensional axisymmetric reactor vessel model without any reactor internals was modeled to assess the influence of the fluid dynamics in the NSC RIA regulatory evaluation. This model has an actual RPV geometry and can be simply separated from other influential factors in order to concentrate only on investigation of the fluid viscosity effect. In the second scenario, a ...

Energy Technology Data Exchange (ETDEWEB)

A new method that allows rapid preconcentration and separation of plutonium and neptunium in water samples was developed for the measurement of {sup 237}Np and Pu isotopes by inductively-coupled plasma mass spectrometry (ICP-MS) and alpha spectrometry; a hybrid approach. {sup 238}U can interfere with {sup 239}Pu measurement by ICP-MS as {sup 238}UH{sup +} mass overlap and {sup 237}Np via peak tailing. The method provide enhanced removal of uranium by separating Pu and Np initially on TEVA Resin, then moving Pu to DGA resin for additional removal of uranium. The decontamination factor for uranium from Pu is almost 100,000 and the decontamination factor for U from Np is greater than 10,000. This method uses stacked extraction chromatography cartridges and vacuum box technology to facilitate rapid separations. Preconcentration is performed using a streamlined calcium phosphate precipitation method. ...

Energy Technology Data Exchange (ETDEWEB)

The previous judgment of eutrophic state, once proposed for the Trasimeno Lake (Umbria region, Italy), has been revised. According to Vollenweider-OECD classification criterion, the lake waters are at present to be classified as mesotrophic waters, with phosphorus limitation. However this level of moderate productivity results to be conditioned by the hydrochemical characteristics of the lake waters, that control phosphorus concentrations independently from the loading coming from the basin, and prevent dangerous and massive algal blooms. Different processes of chemical nature, regulating the phosphorus amount in the lake waters, are then reviewed: adsorption of P/P0(4) onto suspended materials, particularly clay mineral particles, and direct precipitation as hydroxylapatite or co-precipitation with carbonates, are found to be the principal mechanisms that determine chemical removal ...

Energy Technology Data Exchange (ETDEWEB)

Projected scenarios for the proposed Yucca Mountain repository include significant periods of time when high relative humidity atmospheres will be present, thus the reaction processes of interest will include those known to occur under these conditions. The ideal natural analog for the proposed Yucca Mountain repository would consist of natural borosilicate glasses exposed to expected repository conditions for thousands of years; however, the prospects for identifying such an analog are remote, but an important caveat for using natural analog studies is to relate the reaction processes in the analog to those in the system of interest, rather than a strict comparison of the glass compositions. In lieu of this, identifying natural glasses that have reacted via reaction processes expected in the repository is the most attractive option. The goal of this study is to quantify molecular water diffusion in the ...