KoreaScience (Korea)

Full Text Available

Science.gov (United States)

While tritium exposure to the site-workers in Wolsung NPP is up to about 40% of the total personnel exposure, Ministry of Science and Technology has asked tritium removal facility for requirement of post heavy-water reactor construction. For the purpose o...

Energy Technology Data Exchange (ETDEWEB)

Case studies are presented for treatment of refinery wastes in a pilot-scale thin-film evaporator, the removal of volatiles from industrial wastewater for two steam strippers, and the removal of semivolatiles from water by steam stripping followed by liquid-phase carbon adsorption. The report provides data on removal efficiency, air emissions, process residuals, treatment costs, and process limitations. Details on sampling and analytical procedures, quality assurance, and process data are contained in the Appendixes (Volume II).

Energy Technology Data Exchange (ETDEWEB)

Tritium removal from tritiated heavy water in a PHWR is the most effective way in reducing workers` internal dose and radioactivity emissions from Wolsong NPP. The optimum design of the Wolsung TRF(Tritium Removal Facility) was carried out using an approximate short-cut method with an assumption that the TRF, designed to extract 8 MCi per year of elemental tritium from a heavy water feedstream, uses Liquid Phase Catalytic Exchange (LPCE) front-end process and Cryogenic Distillation (CD) process. 19 refs., 6 figs., 2 tabs. (author).

Energy Technology Data Exchange (ETDEWEB)

The Mediated Electrochemical Oxidation (MEO) system is an aqueous process which treats low-level mixed wastes by oxidizing the organic components of he waste into carbon dioxide and water. As MEO system continues to run, dissolved ash and radionuclides slowly accumulate in the anolyte and must be removed to maintain process efficiency. At such time, all of the anolyte is pumped into a still feed tank, and the silver ions need to be removed before sending the solution to a thin-film evaporator for further concentration. The efficiency of removing silver ions in the solution needs to be high enough such that the residual silver sent to Final Forms would be less than 1% wt. The purpose of this work is to develop an efficient process to remove silver ions during the MEO cleanout and to demonstrate the capability of ...

Wastenet

...AquaMagna Water Conditioner and Descaler OCETA Environmental Technology & Business Profiles AQUAMAGNA WATER CONDITIONER AND DESCALER CAT. #03-018 CONTACT: Magna-Tek ...removal high-strength ceramic magnet no energy input The AquaMagna Water Conditioner and Descaler is a non-chemical method of water treatment. The technology uses ... Figure 1: The AquaMagna Water Conditioner and Descaler PROCESS/ PRODUCT APPLICATION: hard water domestic water process water reverse osmosis heat exchangers cooling ... For once-through or recirculating heating or cooling equipment, the AquaMagna descaler improves thermal efficiencies and reduces downtime. Figure 2 illustrates a cross-section ...

Energy Technology Data Exchange (ETDEWEB)

It is an object of the claimed invention to combine chemical treatment with microfiltration process to treat groundwater, leachate from contaminated soil washing, surface and run-off waters contaminated with toxic metals, radionuclides and trace amounts of organics from variety of sources. The process can also be used to treat effluents from industrial processes such as discharges associated with smelting, mining and refining operations. Influent contaminants amenable to treatment are from a few mg/L to hundreds of mg/L. By selecting appropriate precipitation, ion exchange and adsorption agents and conditions, efficiencies greater than 99.9 percent can be achieved for removal of contaminants. The filtered water for discharge can be targeted with either an order of magnitude greater or lower than contaminant levels for drinking water.

British Library Electronic Table of Contents (United Kingdom)

A wet air oxidation (WAO) process was applied to four selected pharmaceuticals (metoprolol, naproxen, amoxicillin, and phenacetin) individually dissolved in ultra-pure water, varying the temperature and oxygen pressure. Due to the moderate (amoxicillin) or low (metoprolol, naproxen, and phenacetin) efficiency found in the oxidation of these pollutants, a catalytic wet air oxidation (CWAO) process was then tested using a platinum catalyst supported on multi-walled carbon nanotubes (CNT). In this CWAO process, the pharmaceuticals were dissolved together in ultra-pure water and in four natural water matrices-a reservoir water, a groundwater, and two waters from different municipal wastewater treatment plants. On the basis of the measurements of their removals, a discussion is given of the inf...

Energy Technology Data Exchange (ETDEWEB)

Water from small scale purification plants is a low cost alternative for consumers in comparison to the bottled commercial presentations. Because of its low cost per liter, the consumption of this product has increased in recent years, stimulating in turn the installation of purification systems for these small businesses. The purpose of this study was to estimate the efficiency of small scale purification systems located in the cities of Zacatecas and Guadalupe, Zacatecas, to reduce the radioactive content of water. It was measured the total alpha and beta activity in water samples of entry and exit to process, through the liquid scintillation technique. In general it was observed that the process is more efficient in removing alpha that beta activity. The fraction of total alpha activity removed varied between 27 and 100%, while between 0 ...

Energy Technology Data Exchange (ETDEWEB)

A fusion reactor (such as NET/ITER) which breeds its own tritium fuel requires tritium recovery, purification and separation from the other isotopes. Cyclic adsorption processes are strong candidates for several of the processes involved: amongst other advantages, they promise a low tritium inventory. A good adsorbent for such processes must have high adsorption capacity, high selectivity and very low tritium retention after each cycle. Pure zeolite powder is shown to have an excellent combination of these three properties. However, in practice problems can arise from tritium which is not removed by reactivation. In this paper we show that tritium retention in zeolites can be caused either by water retained in the zeolite structure, which can be removed by ore rigorous activation, or by water tapped on binders in commercial pellets. (orig.).

Energy Technology Data Exchange (ETDEWEB)

Experiments on manganese removal using an aerated granular filter with mean particle size of 3.68 mm and 5.21 mm anthracite were conducted at a filtration rate of 100 m d{sup -1}. Air, with a rate of 0 to 366 m d{sup -1}, was supplied through nozzles positioned 100 mm above the filter column bottom. From the experiments that were conducted, it was found that manganese removal is completed at a pH of 9.6 or above. In addition, the oxidation and removal rate of dissolved manganese were expressed as a first-order reaction. The smaller the filter media particles were, the higher the manganese removal efficiency was. The aeration rate of dissolved oxygen in raw water is sufficient for the manganese removal process. The manganese removal rate increased with time due to the catalytic effect of manganese dioxide (MnO{sub 2}) ...

Science.gov (United States)

A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass ...

International Nuclear Information System (INIS)

An investigation of decay heat removal by the reflux boiling process was performed on a 1/18 linear-scaled test facility simulating the Three Mile Island (TMI-2) primary system. The objective was to clarify reflux boiling phenomena and core cooling effectiveness. Principal test variables included: core power, primary system water and gas inventories, and steam generator secondary-side coolant flow rate. Of 49 tests conducted, 43 achieved a steady-state heat rejection mode within 3 hours. Subsequent analyses identified two distinct reflux boiling modes. Based upon our current understanding, reflux boiling appears to be an effective process for removing decay heat in a broad range of the conditions investigated for a plant of the TMI configuration.

Science.gov (United States)

Five cycles of loading, elution, and regeneration were performed to remove technetium from a Hanford waste sample retrieved from Tank 241-AW-101 using SuperLig 639 resin. The waste sample was diluted to 4.95 M Na plus and then was processed to remove 137Cs through dual ion exchange columns each containing 15 mL of SuperLig 644. To remove 99Tc, the cesium decontaminated solution was processed downwards through two ion exchange columns, each containing 12 mL of SuperLig 639 resin. The columns, designated as lead and lag, each had an inside diameter of 1.45 cm and a height of 30 cm. The columns were loaded in series, but were eluted and then regenerated separately. The average technetium loading for the cycles was 250 BV at 10 percent breakthrough. There was no significant difference in the loading performances among the five cycles. The percent removal of 99Tc was ...

KoreaScience (Korea)

Full Text Available

Energy Technology Data Exchange (ETDEWEB)

In processes of this invention aqueous waste solutions containing a variety of mixed waste contaminants are treated to remove the contaminants by a sequential addition of chemicals and adsorption/ion exchange powdered materials to remove the contaminants including lead, cadmium, uranium, cesium-137, strontium-85/90, trichloroethylene and benzene, and impurities including iron and calcium. Staged conditioning of the waste solution produces a polydisperse system of size enlarged complexes of the contaminants in three distinct configurations: water-soluble metal complexes, insoluble metal precipitation complexes, and contaminant-bearing particles of ion exchange and adsorbent materials. The volume of the waste is reduced by separation of the polydisperse system by cross-flow microfiltration, followed by low-temperature evaporation and/or filter pressing. The water produced as filtrate ...

International Nuclear Information System (INIS)

Active Process Water (APW) System, provided as unitized closed loop system in Tarapur Atomic Power Project Units-3 and 4, serves to remove heat from various heat exchangers. One of the important loads served by APW system is shutdown cooling heat exchangers and if APW shutdown is taken then reactor cannot be maintained in cold shutdown condition. It is estimated that after 7 days of reactor shutdown, if about 20% of the normal cooling flow to shutdown cooling heat exchangers is provided then along with keeping PHT in cold shutdown state, reactor components, moderator, end shield water, calandria vault water and calandria vault concrete temperature can be maintained within technical specification limits for extended duration. (author)

Energy Technology Data Exchange (ETDEWEB)

Photodestruction has received much attention in recent years. In particular, titanium dioxide (TiO{sub 2}) and ozonolysis have attained a position of prominence. These technologies hold promise for the destruction of trace amounts of aqueous high explosives that are generated by load and pack operations, as well as demilitarization activities. Currently this water is treated by passing through a bed of activated carbon. The carbon is then steam regenerated and reused, thus creating a second waste stream which must be disposed of, or the carbon is burned directly. Recent trends in environmental regulation have shown that this may not be a viable option for process water remediation in the future. This talk will discuss efforts to employ alternate aqueous treatment techniques that not only remove the explosives compounds but are able to transform the parent compound into carbon dioxide and ...

Energy Technology Data Exchange (ETDEWEB)

A water trap system based on a thermoelectric cooling device is employed to remove a major fraction of the water from air samples, prior to analysis of these samples for chemical composition, by a variety of analytical techniques where water vapor interferes with the measurement process. These analytical techniques include infrared spectroscopy, mass spectrometry, ion mobility spectrometry and gas chromatography. The thermoelectric system for trapping water present in air samples can substantially improve detection sensitivity in these analytical techniques when it is necessary to measure trace analytes with concentrations in the ppm (parts per million) or ppb (parts per billion) partial pressure range. The thermoelectric trap design is compact and amenable to use in a portable gas monitoring instrumentation.

International Nuclear Information System (INIS)

Production of ozone and OH radical is required to advance the plasma chemical reactions in the NOx removal processes for combustion gas treatment. The corona discharge to the water surface is expected to induce the good conditions for the proceeding of the NO oxidation and the NO_2 dissolution removal into water. In order to get the fundamental data of the corona discharge over the water surface, the positive and negative V-I characteristics and the ozone production were measured with the multi needle and the saw-edge type of the discharge electrodes. The pulse corona characteristics were also measured with some different waveforms of the applied pulse voltage. The experiments were carried out under the atmospheric pressure and room temperature. Both the DC and the pulse corona to the water surface showed a stable and almost the same V-I ...

Energy Technology Data Exchange (ETDEWEB)

Hundreds of organic byproducts of chlorination are now known to occur in drinking water along with the trihalomethanes. About twenty of these appear to be found with sufficient frequency and in sufficient concentration to attract consideration for regulations. These include chloral hydrate, chloropicrin, a trichloropropanone, haloacetonitriles, and haloacetic acids. Trihalomethane concentrations do not serve as good predictors of concentrations of these other byproducts because their conditions of formation vary widely. This is especially true when pH is changed. Treatment strategies for control of these byproducts including the trihalomethanes are: Remove the compounds after they are formed; Remove precursors; and Use other disinfectants. Current evidence supports the idea that precursor removal processes effective for trihalomethane control may be effective for the other ...

International Nuclear Information System (INIS)

Full text: In heavy-water-moderated power reactors, tritium is primarily produced by neutron capture in deuterium nuclei in the moderator and coolant. For CANDU 6 reactors, the estimated steady-state values are #approx# 3 TBq#centre dot#kg"-"1 D_2O in the moderator and #approx# 74 GBq#centre dot#kg"-"1 D_2O in the coolant. Tritium removal is one option available to reactor operators for use in their heavy water and tritium management strategies. The WTRF is designed to remove tritium from tritiated heavy water in each of the four CANDU units at the Wolsung Site, to immobilize the tritium and to store it on site. The detritiation process is based on three steps: the first one (front-end) involves the transfer of tritium from heavy water to deuterium gas; the second one (enrichment) concentrates the tritium in a cryogenic distillation system ...

Energy Technology Data Exchange (ETDEWEB)

Hexavalent Cr has been identified as one of the toxic metals commonly present in industrial effluents. Among the treatment techniques developed for removing Cr(VI) from waste waters, sorption is most commonly applied, due to its simplicity and efficiency. However, few adsorbents can be recycled and reused cost-effectively. In this study, the removal and recovery of Cr(VI) from water using Li/Al LDH was investigated. The removal of Cr(VI) by Li/Al LDH was evaluated in a batch mode. The results demonstrated that Cr(VI) adsorption onto Li/Al LDH occurs by replacing the Cl{sup -} that originally exists in the interlayer of the adsorbent. The degree of Cr(VI) adsorption observed for Li/Al LDH was relatively high and the process occurred rapidly; however, a portion of adsorbed Cr(VI) was gradually desorbed, due to the Li de-intercalation of Li/Al LDH. Lithium ...

Energy Technology Data Exchange (ETDEWEB)

This document reports on the work done by the Separations Science and Technology Programs of the Chemical Technology Division, Argonne National Laboratory, in the period April-September 1992. This effort is mainly concerned with developing the TRUEX process for removing and concentrating actinides from acidic waste streams contaminated with transuranic (TRU) elements. The objectives of TRUEX processing are to recover valuable TRU elements and to lower disposal costs for the nonTRU waste product of the process. Two other projects are underway with the objective of developing (1) a membrane-assisted solvent extraction method for treating natural and process waters contaminated by volatile organic compounds and (2) evaporation technology for concentrating radioactive waste and product streams such as those generated by the TRUEX process.

Energy Technology Data Exchange (ETDEWEB)

Tannin gel particles that have extremely high adsorption capacity for hexavalent chromium Cr(VI) have been developed by controlling gelation of Mimosa tannin extracted from the bark of plants. The gelation process is composed of two stages; partial gelation of Mimosa tannin by reaction with formaldehyde (cross-linking agent) and granulation by dispersing the partially gelated solution into a liquid mixture of decalin ad a polyether nonionic surfactant with vigorous stirring. The structure of the tannin gel particles is controlled by a combination of operating conditions such as reaction time and temperature at both stages. The water content of the tannin gel particles that reflects their structure can be widely changed from 40 to 79 %(wet basis), even for a constant composition of 23 g Mimosa tannin and 6 ml formaldehyde (37 wt %). It is found that it is very important to increase the water content without losing mechanical ...

International Nuclear Information System (INIS)

The removal of tritiated water vapour was tested by use of a small burning apparatus and a clinoptilolite filter. It was found that decontamination factor of about 10"4 could be obtained by a clinoptilolite filter. The adsorption of HTO in the clinoptilolite is caused by the diffusion, so it is necessary that filtration velocity is maintained below 0.01 m/sec. Decontamination factor was not influence by the moisture content of a clinoptilolite and tritiated water vapour once adsorbed on a filter was hardly removed. (auth.).

Energy Technology Data Exchange (ETDEWEB)

When thorium was biosorbed by biomass of Rhizopus arrhizus or Aspergillus niger it could be removed by treatment using carbonate solutions, but not by phosphates or distilled water. Desorption was rapid, reaching completion in 15 and 30 min respectively. Desorption efficiency was independent of the desorbent concentration above 0.05 mol dm[sup -3] but was strongly dependent on the biomass concentration, decreasing as the biomass concentration increased for both species. Biomass from both species could be regenerated by desorption using sodium carbonate solutions and reused for biosorption. In both species, the efficiency of biosorption and desorption fell as the number of exposures increased although there was an initial rise in desorption efficiency for R. arrhizus. Biosorption and desorption efficiencies of A. niger biomass showed the steeper decline but both were severely reduced in R. arrhizus after five treatments. There was also a ...

Energy Technology Data Exchange (ETDEWEB)

The objective of this project was to develop new photocatalytic or other innovative process chemistry for the treatment of pink water and related contaminated water.

Energy Technology Data Exchange (ETDEWEB)

A membrane process utilizing dialysis and selective complexation by water-soluble polymers has been developed. This process, termed affinity dialysis, has been shown to be selectively extract and concentrate both cations and anions in a manner similar to ion exchange or solvent extraction. The selective removal of calcium from sodium with selectivity of about 30, removal of chromate ion from dilute streams, and separation of transition metal ions such as Cu/Fe and Cu/Zn have all been successfully demonstrated. Effects of different polymers, polymer concentration, temperature, and flow rates have been studied. The effect of increased polymer concentration is to increase product concentration if appropriate changes in feed, polymer solution, and strip flow rates are made. A continuous polymer solution recycle and regeneration system has been constructed and operated with Cu/Zn and ...

Energy Technology Data Exchange (ETDEWEB)

Since artificial organs are intended to replicate chemical processes, knowledge of chemical engineering is essential in their design so that they will function with the maximum efficiency. The most commonly used artificial organ is the artificial kidney, a machine that performs a treatment known as hemodialysis. This process cleanses the bodies of renal failure patients by dialysis and filtration which are simple physiochemical processes. Hemodialysis membranes act to remove accumulated uremia toxins, excess ions and water from the patient via the dialysate, and to supply from the dialysate those ions that are insufficient. This paper describes dialysis membranes and dialyzers for blood purification, the solute transport mechanism of the membrane, and a technical evaluation of the dialysis membrane. Lastly, the next generation of artificial kidney is reviewed. 71 refs., 12 figs., 7 ...

Energy Technology Data Exchange (ETDEWEB)

Biocatalytic Desulfurization (BDS) represents an alternative approach to the reduction of sulfur in fossil fuels. The objective is to use bacteria to selectively remove sulfur from petroleum and middle distillate fractions, without the concomitant release of carbon. Recently, bacteria have been developed which have the ability to desulfurize dibenzothiophene (DBT) and other organosulfur molecules. These bacteria are being developed for use in a biocatalyst-based desulfurization process. Analysis of preliminary conceptual engineering designs has shown that this process has the potential to complement conventional technology as a method to temper the sulfur levels in crude oil, or remove the recalcitrant sulfur in middle distillates to achieve the deep desulfurization mandated by State and Federal regulations. This paper describes the results of initial feasibility studies, sensitivity analyses and ...

Energy Technology Data Exchange (ETDEWEB)

Among the membrane filtration techniques, continuous cross-flow ultrafiltration (UF) is an innovative method to separate solid/liquid or liquid/liquid phases at a lower pressure of 5--150 psi compared to reverse osmosis (RO) in which the applied pressure is an order of magnitude higher. Recently, attempts have been made to combine processes of UF and other treatments for many applications. However, there is very little knowledge about the filtration process which combined coagulation and UF, and very few attempts have been made to apply coagulated UF to the treatment of fuel oil contaminated water. During the UF treatment of organic contaminants rapid declines in flux will occur due to the membrane fouling. Oil as a foulant plants an important role in the flux decrease. However, there are very limited pretreatment processes which can effectively remove fuel oil from ...

Energy Technology Data Exchange (ETDEWEB)

While tritium exposure to the site-workers in Wolsung NPP is upto about 40 % of the total personnel exposure, Korea Institute of Nuclear Safety has asked tritium removal facility, as one of the requirements for post reactor construction, after operation of four CANDU reactors in Wolsung site. For the purpose of essential removal of tritium from the heavy water system of the heavy water reactors, an experiment of Ar-N{sub 2} cryogenic distillation tower was carried out as a preliminary study for development of liquid-phase catalytic exchange - cryogenic hydrogen distillation process. The steady-state reached after 50 minutes under 90 K in the Ar-N{sub 2} distillation column (inner diameter 20 mm, height 500 mm) packed with Dixon ring ({phi} 3 mm x H 3 mm), and the ratios of Ar-concentration at the top and at the bottom measured by gas chromatography within {+-}1 % relative error was ...

International Nuclear Information System (INIS)

Peculiarities of Kurchatov Institute WWR-2 and TR research reactors spent fuel treating and transportation for radiochemical processing are stated. Spent fuels were performed as fuel assemblies of different forms and containing similar fuel elements: EhK-10 with 10% enrichment UO2-Mg fuel kernels or S-36 with 36% enrichment U-Al alloys. Spent fuel storage conditions are described. Features of developed procedures for identification of fuel assemblies by type of fuel elements are given. Transport package TUK-19 for loading and transportation of spent fuel for processing was chosen. Details of spent fuel loading in TUK-19 that is conducted by personnel under protective sheet of water in special reclaim volume are described

International Nuclear Information System (INIS)

The author is exploring the efficiency of pulsed plasma processing in the removal of nitrogen dioxide, nitrogen oxide, and other pollutants. This process uses an electrical discharge to create chemical radicals from air molecules. These radicals can react with pollutants and form harmless compounds. Additives such as hydrocarbons are also used to improve the efficiency of the removal. The efficient removal of nitrogen dioxide has required the presence of dilute aqueous solution of ammonia.

Environmental Research Database

ObjectivesThe specific objectives of the research are to: 1. Determine the concentrations of N2O, NO and NO2 in tropical coastal waters in relation to nutrients and salinities. 2. Determine, with excess nitrate present, the potential for nitrate reduction and denitrification in sediments along tropical estuaries, and whether NO, NO2, N2O, N2 or NH4+ are significant products. 3. Establish the balance between denitrification, nitrate ammonification and anammox in tropical estuarine sediments, relative to [continued...]DescriptionThe coastal zone is extremely important in the biogeochemical processes which control the natural cycle of elements of the Earth. In particular, the coastal zone contributes significantly to the nitrogen cycle, removing nitrogen washed in from the land by rivers and so reducing its fertilizing impact on the coastal seas. However, these removal processes, ...

Energy Technology Data Exchange (ETDEWEB)

No abstract available.

Energy Technology Data Exchange (ETDEWEB)

This paper describes the development, design, and fabrication of the crude oil process facilities, and the conversion of an existing tanker for use at the Liuhua 11-1 Field. Over a 16-month period spanning 1994 and 1995, Amoco Orient Petroleum Company, and partners, China Offshore Oil Nanhai East Corporation (CONHE), and Kerr-McGee China Petroleum Ltd., converted a crude oil tanker originally built in 1975 to the Nanhai Sheng Li, the floating production, storage and offloading (FPSO) facility for the Liuhua 11-1 Field. The FPSO will process up to 65,000 BOPD produced from 20 subsea wells located 1.7 miles away. In addition to the processing facilities for produced oil and water, the FPSO has a processed crude oil storage capacity of 715,000 bbls. The ship`s propulsion system was removed during the conversion, because the FPSO is permanently moored at site by ...

Energy Technology Data Exchange (ETDEWEB)

Explosives have been used in the removal of offshore wellhead devices for a number of years. In 1975, the first liquid explosives were run to remove wellheads and have proved to be a safe and reliable method of severing and salvaging the wellhead equipment from most depths of water. Methods of explosive wellhead removal and the areas of safety, reliability, and economics are discussed.

Energy Technology Data Exchange (ETDEWEB)

This project evaluated the feasibility of using a low-concentration (approx. 0.5 wt %) chemical cleaning process to remove corrosion product deposits from steam generator surfaces and magnetite from tube-to-support plate crevices of PWR steam generators. The primary objective was to develop a dilute process that could be safely applied at scheduled intervals, such as during normal refueling outages, to maintain a clean operating condition in the steam generator. The dilute chemical cleaning process developed in this project was demonstrated successfully on two model generators which were operated on faulted chemistry by DOE/CRC at Commonwealth's State Line Facility. Unit 5 was cleaned after 48 days of operation with 1% seawater fouling, and Unit 6 was cleaned after 112 days of operations with Lake Michigan water. This report describes work leading to the model generator ...

Energy Technology Data Exchange (ETDEWEB)

The Korea Atomic Energy Research Institute has launched a decommissioning program of uranium conversion plant. One of the important tasks in the decommissioning program is the treatment of the sludge, which was generated during operation and stored in the two ponds of the lagoon. The treatment requires the volume reduction of lagoon sludges for the low cost of the program and the conversion of the chemical forms, including uranium, for the acceptance at the final disposal site. The physical properties, such as densities, were measured and chemical compositions and radiological properties were analyzed. The denitration was a candidate process which would satisfy the requirements for sludge treatment, and the characteristics of thermal decomposition and dissolution with water were analyzed. The main compounds of the sludge were ammonium and sodium nitrate from conversion plant and calcium nitrate, calcium carbonate from Ca precipitation and ...

International Nuclear Information System (INIS)

There has been recent interest in the United States concerning the loss of residual heat removal system (RHRS) under reduced coolant inventory conditions for pressurized water reactors. This issue is also of interest in the Federal Republic of Germany and an experiment was performed in the integral PKL-HI experimental facility at Siemens-KWU to supply applicable data. Recently, an NRC-sponsored effort has been undertaken at the Idaho-National Engineering Laboratory to identify and analyze the important thermal-hydraulic phenomena in pressurized water reactors following the long term loss-of-RHRS during reduced inventory operation. The thermal-hydraulic response of a closed reactor coolant system during such a transient is investigated in this report. Some of the specific processes investigated include: reflux condensation in the steam generators, the corresponding pressure increase in the reactor ...

Energy Technology Data Exchange (ETDEWEB)

When performing trenchless pipe renovation work - whichever process you use - the success of the job depends on the careful removal of all scale, sediments and rust from the innerwall surfaces. The VACUJET process - in which the pipe is cleaned with water at pressures of up to 2 500 bar using a technique jointly developed by Preussag Rohrsanierung GmbH and Fabex GmbH - meets all requirements. The equipment includes a mobile waste water treatment unit which is small enough to fit on a standard trailer. Despite its compact dimensions this plant is so effective that it can treat all the waste water generated during the high pressure cleaning jobs so that it is suitable for reuse in the cleaning process or for release into the sewerage system. (orig.) [Deutsch] Bei der grabenlosen Rohrsanierung, ganz gleich nach welchem Verfahren saniert wird, ...

Science.gov (United States)

In order to decrease tritium exposure to workers, the ratio of which is up to 40% of total exposure, tritium removal facility is getting to be one of the considerable parameters in Korea, due to the next CANDUs to be operated at Wolsung NPP. For investiga...

Energy Technology Data Exchange (ETDEWEB)

A novel acidizing process is used to increase the permeability of carbonate rock cores in the laboratory and to remove drilling fluid damage from cores and wafers. Field results show the benefits of the technology as applied both to injector and producer wells.

British Library Electronic Table of Contents (United Kingdom)

The extent to which a novel wash-off process using polyamide beads removed five different types of dye from three different types of fibre was similar to that achieved using conventional aftertreatments. Whilst bead wash-off and the conventional aftertreatments were of similar duration and temperature, conventional aftertreatment employed a 10:1 or 20:1 liquor ratio whereas bead wash-off used a < 1:1 liquor ratio. As vagrant dye was adsorbed onto the bead material during wash-off, the low amount of wastewater generated contained little residual dye, thereby offering the potential of reduced environmental and cost benefits. Bead wash-off did not impair the fastness of two non-metallised acid dyes on nylon 6,6 to washing at 60 ?C.

International Nuclear Information System (INIS)

The ALPHA project is centered around the experimental and analytical investigation of the long-term decay heat removal from the containments of the next generation of open-quotes passiveclose quotes ALWRs. The project includes integral system tests in the large-scale (1:25 in volume) PANDA facility as well as several other series of tests and supporting analytical work. The first series of experiments to be conducted in PANDA have become a required experimental element in the certification process for the General Electric Simplified Boiling Water Reactor (SBWR). The PANDA general experimental philosophy, facility design, scaling, and instrumentation are described. Steady-state PCCS condenser performance tests and extensive facility characterization tests were already conducted. The transient system behavior tests are underway; preliminary results from the first transient test M3 are reviewed.

Energy Technology Data Exchange (ETDEWEB)

Calcium sulfate dihydrate which is co-produced in the scrubbing of waste gases from bituminous coal power plants is employed in the underground road securing after recrystallization. Beta-sulfate semi hydrate is obtained from the dihydrate by recrystallisation and it is used as such or as a stiff mixture with additives as a stowing material. Particularly fly ash from coal combustion units, washery refuses and development rocks from coal mining or slags from the metallurgical industry can be used as additives. The compressive and the bending tensile strength of the stowing material can be adjusted by the water content in case beta sulfate semihydrate is used as such.

British Library Electronic Table of Contents (United Kingdom)

Mowing a meadow is an example of an equalizing process that reduces differences among species by removing aboveground biomass approximately 5?cm above ground. This regular disturbance that affects all plants prevents competitive exclusion of small species and thus allows coexistence of numerous species differing in shoot size. In this paper we search for the mechanism behind this by comparing the shoot biomass of 41 common species in dry and wet species-rich meadows in mown and recently abandoned plots in June (before mowing) and in October. We asked the following questions: i) Do the plants differ in proportion of biomass lost by mowing? ii) Are the mown plants able to compensate for biomass lost by mowing? iii) Is the compensatory ability of mown plants related to their size? iv) Is the ...

British Library Electronic Table of Contents (United Kingdom)

Effects of some experimental parameters (supporting electrolyte, initial pH and current density) on the performance of electrocoagulation process using iron electrodes were investigated. Results of experiments showed that dissolution of iron is purely electrochemical and fits well with Faraday's law and leads to Fe^2^+ which are chemically oxidized into Fe^3^+ in aerated conditions. In neutral and alkaline conditions, the reaction between hydroxyl ions generated at the cathode and dissolved iron ions forms insoluble hydroxo-iron species. Potentiodynamic polarization tests showed that the formation of passive film on iron anode limits the continuous electrochemical dissolution of iron. Corrosion and pitting potentials largely depend on the nature of supporting electrolyte. The dissolution o...

International Nuclear Information System (INIS)

Manganese is a common contaminant of mine water and other waste waters. Due to its high solubility over a wide pH range, it is notoriously difficult to remove from contaminated waters. Previous systems that effectively remove Mn from mine waters have involved oxidising the soluble Mn(II) species at an elevated pH using substrates such as limestone and dolomites. However it is currently unclear what effect the substrate type has upon abiotic Mn removal compared to biotic removal by in situ micro-organisms (biofilms). In order to investigate the relationship between substrate type, Mn precipitation and the biofilm community, net-alkaline Mn-contaminated mine water was treated in reactors containing one of the pure materials: dolomite, limestone, magnesite and quartzite. Mine water ...

Energy Technology Data Exchange (ETDEWEB)

The following paragraphs summarize the progress of each research project funded under the WVU Cooperative Agreement during the third quarter of 1997 (July - September 1997). The projects are arranged according to their 1997 WVU task number. WVU Focus Area 1.0: Subsurface Contaminants, Containment and Remediation Task No. 1.1: Project discontinued. Task No. 1.2: Development of Standard Test Protocols and Barrier Design Models for Desiccation Barriers (K. Amininan & S. Ameri): A number of experiments were preformed this period to evaluate the ability of the dried sand-packs to act as a barrier to liquids. Water infiltration tests were done with a constant head, dispersing 80 ml of water, and by adding water in small increments. Results indicate that when the water is spilled over the sand-pack, it has the tendency to channel through the sand-pack, significantly reducing the capacity of the dried zone ...

International Nuclear Information System (INIS)

The application of chemical cleaning for dissolving and removing scale and sludge is being planned in the Japanese pressurized water reactor (PWR) plant in order to maintain high heat transfer performance and to prevent steam generator (SG) tube degradation. In this paper, the effectiveness of the Electric Power Research Institute (EPRI) and German Kraftwerk Union (KWU) processes on the integrity of structural materials other than SG tubes and the comprehensive applicability of chemical cleaning are discussed. The integrity of structural materials such as carbon steel, low-alloy steel and stainless steel was maintained after the EPRI and KWU processes. KWU chemical cleaning tailored for crevice cleaning has been studied to improve its cleaning effectiveness in crevices and to control the corrosion depth of structural materials less than the criterion for corrosion depth. (author)

British Library Electronic Table of Contents (United Kingdom)

This paper explores the through-/in-plane characteristics of water transport in the cathode gas diffusion layer (GDL) of a polymer electrolyte fuel cell (PEFC). Theoretical analysis is performed on the non-isothermal two-phase flow under flow channels. A dimensionless group Da (Damkohler number for PEFC operation), defined as the ratio of water generation rate to water vapor-phase removal rate, is formulated to characterize the flow regimes in a PEFC. This group, lumping geometrical parameters and physical properties, compares the water vapor-phase removal capability (via water diffusion and holding capacity) with the rate of water production by the oxygen reduction reaction. We find that this dimensionless group can be used to characterize the non-isothermal, two-phase phenomena: when Da&...

Energy Technology Data Exchange (ETDEWEB)

The removal of toxic metals and alkalis from gas streams at high temperatures was investigated. This is important for the development of coal-fired combined cycle power generation systems.

Energy Technology Data Exchange (ETDEWEB)

The phenomenology of wire chamber aging is discussed and fundamentals of proportional counters are presented. Free-radical polymerization and plasma polymerization are discussed. The chemistry of wire aging is reviewed. Similarities between wire chamber plasma (>1 atm dc-discharge) and low-pressure rf-discharge plasmas, which have been more widely studied, are suggested. Construction and use of a system to allow study of the plasma reactions occurring in wire chambers is reported. A proportional tube irradiated by an {sup 55}Fe source is used as a model wire chamber. Condensable species in the proportional tube effluent are concentrated in a cryotrap and analyzed by gas chromatography/mass spectrometry. Several different wire chamber gases (methane, argon/methane, ethane, argon/ethane, propane, argon/isobutane) are tested and their reaction products qualitatively identified. For all gases tested except those containing methane, use of hygroscopic filters to ...

International Nuclear Information System (INIS)

A schematic diagram shows the various processing steps to be performed during feed preparation in the Hanford Waste Vitrification Plant (HWVP). The pretreated NCAW is transferred to the slurry receipt adjustment tank (SRAT) in the HWVP for concentration. Water removed during boildown is collected in the slurry mix evaporator condensate tank (SMECT). After waste treatment the water is returned to the storage tanks for eventual disposal. The pretreated Neutralized Current Acid Waste (NCAW) is concentrated in the SRAT to approximately 125 g waste oxides/ liter. Formic acid is then added at a controlled rate to improve rheological properties and achieve a required reduction/oxidation state. Reflux boiling is initiated and continued for several hours. The concentrated slurry is cooled and pumped to the slurry mix evaporator (SME). In the SME, glass frit is added, and the slurry is further concentrated to ...

Energy Technology Data Exchange (ETDEWEB)

The precipitation of heavy metals as hydroxides is the standard technique for the decontamination of waste water streams polluted by these elements. On the other side, progress in research has been made concerning the biosorption onto dead biomass and bioprecipitation supported by physiologically active bacteria. As the aim of this study, a flexible strategy has been envisaged cleaning a waste water with definite heavy metal load underlying the process mentioned above. Suitable bacteria were enriched and the process was tested in a technical plant. As result, a very high efficiency of heavy metal elimination has been found. The field of application covered by the acquired process is identical with the whole range of the waste water streams polluted by heavy metals. In addition, a second stage may be necessary if there are any further contaminants to be ...

International Nuclear Information System (INIS)

Vertical U-tube steam generators in Pressurized Water Reactors (PWRs) operating an All Volatile Treatment (AVT) secondary chemistry have experienced corrosion problems, particularly denting and sludges. The studies reported evaluate the feasibility of using a low-concentration (0.5 wt%) chemical cleaning process to remove corrosion product deposits from steam generator surfaces and magnetite from tube-to-support plate crevices of PWR steam generators. The process potentially may be applied at schedule intervals, such as during normal refueling outages, to maintain a steam generator in clean operating condition. This report describes the results of testing to evaluate the effectiveness of several chelant acids for dissolving steam generator sludges and crevice magnetite. Corrosion of carbon steel by the chelant acids and the effects of various inhibitors are evaluated. The effectiveness of ion-exchange ...

International Science & Technology Center (ISTC)

New Catalysts and Sorbents on the Basis of Pillared Clays for the Processes of Hydrocarbons Conversion and Water Purification

International Nuclear Information System (INIS)

Based on the occurrence of a number of plant incidents during low power and shutdown operating conditions, the Nuclear Regulatory Commission (NRC) has initiated several programs to better quantify risk during these periods. One specific issue of interest is the loss of residual heat removal (RHR) under reduced coolant inventory conditions. This issue is also of interest in the Federal Republic of Germany and an experiment was performed in the integral PKL-3 experimental facility at Siemens-KWU to supply applicable data. Recently, an effort has been undertaken at the Idaho National Engineering Laboratory (INEL) to identify and analyze the important thermal-hydraulic phenomena in pressurized water reactors following loss of vital AC power and consequent loss of the RHR system during reduced inventory operation. The thermal-hydraulic response of a nuclear steam supply system (NSSS) with a closed reactor coolant system (RCS) to loss of residual ...

Energy Technology Data Exchange (ETDEWEB)

The authors study technological safety of installing a water spray pressure vessel between electrostatic deduster and coal sludge ducts. These sprays are in use elsewhere for steam generator ash removal. Dust ignition and explosion tests were carried out to examine flame and pressure wave propagation through the vessel into ducts. Water jet diameter, amount of water sprayed and coal dust removed were varied. Pressure waves exceeded 250 Pa. Test results show the vessel to be suitable for installation in briquetting plants due to its flame and explosion barrier effect and extermination of smoldering dust fires. The only disadvantage of the vessel is seen as its water and electric power consumption: about 8 m/sup 3//h of water and 1.5 kW/h of power per vessel serving dedusters of a 2,200 m/sup 2/ rotary brown coal dryer. (MOS).

Energy Technology Data Exchange (ETDEWEB)

Removal of sulfonamide (SAs) and tetracycline (TAs) classes of antibiotic compound from deionized water and DOC water by powdered activated carbon (PAC) adsorption was evaluated in this study. According to the study results, TAs were more easily adsorbed than SAs although TAs were more hydrophilic than SAs. The phenolic compounds in TAs might be responsible for their high adsorption. Complex formation of TAs with metal and metal oxide on the surface of activated carbon might also contribute to higher adsorption. The hydrophobic effect was important for removal of SAs. More hydrophobic SAs were removed more easily. The carbon type was not important for adsorption of SAs and TAs. Coal based carbon and coconut based carbon showed similar removal efficiencies for these antibiotics. Dissolved organic materials interfered with adsorption of SAs and TAs. Organic ...

British Library Electronic Table of Contents (United Kingdom)

Four advanced oxidation processes (UV/TiO2, UV/IO4^-, UV/S2O8^2^-, and UV/H2O2) were tested for their ability to mineralize naphthenic acids to inorganic carbon in a model oil sands process water containing high dissolved and suspended solids at pH values ranging from 8 to 12. A medium pressure mercury (Hg) lamp was used, and a Quartz immersion well surrounded the lamp. The treatment goal of 5mg/L naphthenic acids (3.4mg/L total organic carbon (TOC)) was achieved under four conditions: UV/S2O8^2^- (20mM) at pH 8 and 10, and UV/H2O2 (50mM) at pH 8 (all with the Quartz immersion well). Values of electrical energy required to meet the treatment goal were about equal for UV/S2O8^2^- (20mM) and UV/H2O2 (50mM) at pH 8, but three to four times larger for treatment by UV/S2O8^2^- (20mM) at pH 10. ...

Energy Technology Data Exchange (ETDEWEB)

A process for the removal of H/sub 2/S from sour gas streams is disclosed, the process being characterized by the utilization of washing solutions containing oxidizing metal chelates of nitrilotriacetic acid, and by the electrolytic regeneration of the spent solutions.

Energy Technology Data Exchange (ETDEWEB)

The development of crud removal technology has started with the finding of the resin aging effect that an old ion exchange resin, aged by long year of use in the condensate demineralizer, had an enhanced crud removal capability. It was confirmed that some physical properties such as specific surface area and water retention capacity were increased due to degradation caused by long year of contact with active oxygens in the condensate water. So, it was speculated that those degradation in the resin matrix enhanced the adsorption of crud particulate onto the resin surface, hence the crud removal capability. Based on this, crud removal resin with greater surface area was first developed. This resin has shown an excellent crud removal efficiency in an actual power plant, and the crud iron concentration in the condensate effluent was drastically ...

UK PubMed Central (United Kingdom)

Effects of physical environment on plasma membrane semipermeability and osmotic induction of changes in aqueous cytoplasmic volume were studied in vegetative and spore cells of a plant pathogenic fungus,...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

This report summarizes work performed on this project from October 2004 through March 2005. In previous work, a surfactant modified zeolite (SMZ) was shown to be an effective system for removing BTEX contaminants from produced water. Additional work on this project demonstrated that a compost-based biofilter could biodegrade the BTEX contaminants found in the SMZ regeneration waste gas stream. However, it was also determined that the BTEX concentrations in the waste gas stream varied significantly during the regeneration period and the initial BTEX concentrations were too high for the biofilter to handle effectively. A series of experiments were conducted to determine the feasibility of using a passive adsorption column placed upstream of the biofilter to attenuate the peak gas-phase VOC concentrations delivered to the biofilter during the SMZ regeneration process. In preparation for the field test of the SMZ/VPB treatment ...

British Library Electronic Table of Contents (United Kingdom)

Abstract In this research, the efficiency of electrocoagulation treatment process using aluminum electrodes to treat synthetic wastewater containing Reactive Red198 (RR198) was studied. The effects of parameters such as voltage, time of reaction, electrode connection mode, initial dye concentration, electrolyte concentration, and inter electrode distance on dye removal efficiency were investigated. In addition, electrical energy consumption, electrode consumption, and operating cost at optimum condition have been investigated. The results showed that dye and chemical oxygen demand removals were 98.6 and 84%, respectively. Electrode consumption, energy consumption and operating cost were 0.052-kg/m3, 1.303-kWh/m3 and 0.256-US$/m3, respectively. Dye removal kinetic followed first order kinet...

International Nuclear Information System (INIS)

LEDF (Large Equipment Dismantling Facility) will be constructed for the purpose of decontaminating the high level #alpha# solid waste generated in oarai engineering center of JNC. And, main processing process of LEDF is incineration and melting system. LEDF will be intended to reduce the secondary waste that occurs along with the operation of the off gas processing equipment of incineration and melting system. It assumed that we are able to eliminate the adsorption tower using silica gel, if the decontamination factor to volatile ruthenium is able to expect in the packed scrubber that is established to remove harmful gas. Thereupon, we carried out this tests that eliminates the adsorption tower and reduces the secondary waste. The decontamination factor (DF) to the volatile ruthenium by the water scrubber is confirmed in the established institution which is in Tokai Works. However, ...

Energy Technology Data Exchange (ETDEWEB)

The thermal stability of wood polymer composites made with extractive-free wood from four different wood species was studied. Hot water (HW) extractives, ethanol/cyclohexane (E/C) extractives and both types of extractives were eliminated from A. cyclops, E. grandis, P. radiata and Q. alba. Composites of LLDPE and 10 wt% of wood were prepared, using poly vinyl alcohol-co-ethylene (EVOH) as a compatibilizer. The thermal degradation behavior of the composites was characterized with thermogravimetric analysis (TGA). The obtained results showed that in all cases, the degradation temperatures shifted to higher values after removal of the extractives. The removal of E/C extractives was less effective in its improvement of the thermal stability than the removal of HW extractives. The largest improvement on the thermal stability of WPCs was achieved when both types of extractives (E/C and HW) were ...

Science.gov (United States)

... should give full con- As for the effects of the Three Gorges on the mouth of sideration to the rising water process and water temper- the river, the ...

International Nuclear Information System (INIS)

Eight years ago, corrosion and tube denting seriously threatened the reliability and design life of steam generators, especially for closed loop arrangements in pressurized water reactors (PWRs). Concentrated research by the Steam Generator Owners Group (SGOG) diagnosed the causes and produced effective solutions, notably guidelines for water chemistry control in the secondary loop. The guidelines recommend specific levels of water impurities and remedial actions to prevent cooling-water leaks in the condenser, prevent air leaks, limit corrosion product buildup, and remove some impurities while neutralizing others. Continued research in SGOB-II is investigating intergranular corrosion and stress corrosion cracking. 3 figures.

Energy Technology Data Exchange (ETDEWEB)

Mechanistic models of aerosol decontamination by an overlying water pool during core debris/concrete interactions and spray removal of aerosols from a Mark I drywell atmosphere are developed. Eighteen uncertain features of the pool decontamination model and 19 uncertain features of the model for the rate coefficient of spray removal of aerosols are identified. Ranges for values of parameters that characterize these uncertain features of the models are established. Probability density functions for values within these ranges are assigned according to a set of rules. A Monte Carlo uncertainty analysis of the decontamination factor produced by water pools 30 and 50 cm deep and subcooled 0--70 K is performed. An uncertainty analysis for the rate constant of spray removal of aerosols is done for water fluxes of 0.25, 0.01, and 0.001 cm{sup 3} H{sub 2}O/cm{sup 2}-s ...

Energy Technology Data Exchange (ETDEWEB)

The Raywell Process Plants unit, which reclaims a wide range of organic solvents, including chlorinated hydrocarbons, is based on thin film evaporation and distillation rather than steam distillation, thus reducing the risk of contamination by water. Henry Balfour and Co.'s Pfaudler Solvent Recovery System gives 96% or better solvent recovery and produces a near-solid waste suitable for landfill disposal; like the Raywell system, it uses a mechanically wiped thin-film evaporator. Midland Oil Refineries uses sa Raywell thin-film evaporator for recovery of waste lubricating oils rather than the conventional sulfuric acid/clay treatment, thus avoiding formation of sulfuric acid sludge waste. The Henry Balfour Bioenergy anaerobic digestion system gives yields of fuel gas with 65-75% methane as high as 0.8 cu m/kg BOD; it achieves 95-98% BOD removal with no pH control or nutrient addition because it separates solids ...

International Nuclear Information System (INIS)

The RADionuclide Transport, Removal, And Dose (RAD-TRAD) code is designed for U.S. Nuclear Regulatory Commission (USNRC) use to calculate the radiological consequences to the off-site population and to control room operators following a design-basis accident at light water reactor (LWR) power plants. This code utilizes updated reactor accident source terms published in draft NUREG-1465. The code will track the transport of radionuclides as they are released from the reactor pressure vessel, travel through the primary containment and other buildings, and are released to the environment. As the radioactive material is transported through the primary containment and other buildings, credit for several removal mechanisms may be taken, including sprays, suppression pools, overlying pools, filters, and natural deposition. Simple models are available for these different removal mechanisms that use, as input, ...

Science.gov (United States)

The long operating cycle simplified boiling water reactor is a reactor concept that pursues both safety and the economy by employing a natural circulation reactor core without a refueling, a passive decay heat removal, and an integrated building for the reactor and turbine. Throughout the entire spectrum of the design basis accident, the reactor core is kept covered by the passive emergency core cooling system. The decay heat is removed by the conventional active low-pressure residual heat removal system. As for a postulated severe accident, the suppression pool water floods the lower part of the reactor pressure vessel (RPV) in the case when core damage occurs, and the in-vessel retention that keeps the melt inside the RPV is achieved by supplying the coolant. The containment adopts a parallel-double-steel-plate structure similar to a hull structure, which contains coolant between ...

Energy Technology Data Exchange (ETDEWEB)

The dry desulfurization, denitrification and air toxics removal process using activated coke (AC) has been commercially adapted for flue gas clean up of a power plant, an oil refinery plant, an iron ore sintering plant, and a refuse incinerator. This process can achieve 100% removal of SO{sub x}, over 80% removal of NO{sub x} and effective removal of air toxics such as Hg, HCL, dioxines, etc., by contacting flue gas with AC and injecting NH{sub 3} for DeNO{sub x} at temperature range of about 100-200{degrees}C. For flue gas treatment, AC has several functions, which basically depends on the chemical surface group on AC inner surface. As adsorbent, AC can adsorb SO{sub x} at the relatively basic oxygen group site, where the adsorbed SO{sub x} is stored as sulfuric acid into micropore structure of AC. As catalyst, AC can decompose NO{sub x} catalytically with ...

Energy Technology Data Exchange (ETDEWEB)

A solar energy desalination process utilizing solar radiation directly for the evaporation of salt water is described. Ambient air takes on water vapor as the air passes through an evaporative medium. It is then directed between a saline water-covered, solar absorbing surface and a solar collecting housing. The resulting heated and moisture-saturated air is cooled in a heat exchange means where condensation of fresh water occurs. Simultaneously, cool salt water is utilized as the cooling water in the heat exchange means, and takes on the heat of condensation given up by the condensing vapor. The heated salt water from the heat exchange means is partially directed over the solar absorbing surface, and at least a portion of it is also directed to wet the evaporative medium. Several optional ...

Energy Technology Data Exchange (ETDEWEB)

The pyrometallurgic method consisting in introduction of refining agent into the liquid cadmium has been presented. The refining agent consisting of silicon nitride, carbon dust and sodium hydroxide has been added in several portion into the liquid cadmium. Iron has been removed from the cadmium surface in the form of floating slag.

Energy Technology Data Exchange (ETDEWEB)

In situ treatment has been proposed as a remediation alternative for surface water and groundwater contaminated with uranium and nitrate as a result of former waste disposal practices in the S-3 Ponds. Interceptor trenches containing reactive media have been proposed to treat groundwater, and constructed wetlands and/or algal mats are potential alternatives for treating surface water. This report presents the results from testing of ten different reactive media, and combinations of media, that are candidates for use in the proposed interceptor trenches to remove uranium and nitrate from groundwater. It also presents the results of testing and evaluation of algal mats and wetlands for removing uranium and nitrate from surface water.

Energy Technology Data Exchange (ETDEWEB)

This report is a summary of the contribution of nitrogen and phosphorus in the eutrophication process of inland and coastal waters. Special attention was paid to the mechanisms of these nutrients in regulating biological processes and to the methods available in estimating their effects in the eutrophication of water bodies. The report includes five chapters which are entitled: Introduction, which is a general background to the subject with special attention to the requirements of the Finnish Water Act. Phosphorus and nitrogen as factors regulating biological processes. The topics included are: definition of eutrophication, forms of phosphorus and nitrogen and their sources to inland and coastal waters, effects of these nutrients as growth factors of phytoplankton and macrophytes and consequences of eutrophication. Estimation of the effects ...

International Nuclear Information System (INIS)

Concentrations of tritium in environmental waters (precipitation, rivers, lakes, tap water) have been determined using electrolytic enrichment and liquid scintillation counting. In waters of big rivers (the Vistula and the Odra rivers), lakes and tap water the annual average concentrations were similar to each other being from 1.4 to 1.9 Bq x dm"-"3. These concentrations were similar to those in the precipitation in which they ranged from 1.7 to 2.2 Bq x dm"-"3. The lowest tritium concentrations were found in waters of the Seashore Region rivers (average for 1994-1999 was 1.1 Bq x dm"-"3). The tritium concentrations in surface waters and in precipitation are still higher than that of natural level. The data obtained show that tritium concentration in the water of rivers might depend on the size of drainage area. The observed seasonal ...

Energy Technology Data Exchange (ETDEWEB)

The humidification dehumidification desalination process is viewed as a promising technique for small capacity production plants. The process has several attractive features, which include operation at low temperature, ability to utilize sustainable energy sources, i.e. solar and geothermal, and requirements of low technology level. This paper evaluates the characteristics of the humidification dehumidification desalination process as a function of operating conditions. A small capacity experimental system is used to evaluate the process characteristics as a function of the flow rate of the water and air streams, the temperature of the water stream and the temperature of the cooling water stream. The experimental system includes a packed humidification column, a double pipe glass condenser, a constant temperature water ...

Energy Technology Data Exchange (ETDEWEB)

The removal of heavy metal by microbial biomass have been investigated as an alternative to the traditional methods. The removal of the heavy metals copper and iron from discarded lubricating-oil was studied using the biosorbent Sargassum sp. It was chosen a discarded lubricating-oil of a bus fleet from the city of Natal-RN-Brazil. The oil was characterized to determine and quantify the heavy metals present. The effect of biomass protonation was performed in order to increase the removal efficiency of the metals. The equilibrium time between the oil and the biomass was determined. It was found that after 10 hours the equilibrium was reached. It was also studied the influence of biomass quantity. The results showed that the biomass quantity is an important parameter to the efficiency and biosorption capacity. The protonated biomass was shown more efficient to removal of Fe and Cu, ...

Energy Technology Data Exchange (ETDEWEB)

In Situ Bioremediation (ISB), which is the term used in this report for Gaseous Nutrient Injection for In Situ Bioremediation, remediates soils and ground water contaminated with volatile organic compounds (VOCs) both above and below the water table. ISB involves injection of air and nutrients (sparging and biostimulation) into the ground water and vacuum extraction to remove .VOCs from the vadose zone concomitant with biodegradation of VOCs. The innovation is in the combination of 3 emerging technologies, air stripping, horizontal wells, and bioremediation via gaseous nutrient injection with a baseline technology, soil vapor extraction, to produce a more efficient in situ remediation system.

Energy Technology Data Exchange (ETDEWEB)

The overall objective of this project was to use molecular genetics to develop strains of bacteria with enhanced ability to remove sulfur from coal, and to obtain data that will allow the performance and economics of a coal biodesulfurization process to be predicted. (VC)

British Library Electronic Table of Contents (United Kingdom)

Feasibility of using fixed bed column of conventional ion exchangers/sorbent and chemical precipitation based processes have been examined for the effective removal of the very low levels of 106Ru activity from NH4NO3 effluent generated during wet processing of rejected sintered depleted uranium fuel pellets. Based on the results, a simple process involving precipitation of cobalt sulphide along with ferric hydroxide was selected and further optimization of process variables was carried out. The optimized process has been found to be highly efficient in reducing 106Ru activity down to extremely low levels.

Energy Technology Data Exchange (ETDEWEB)

The coke plant at the Sparrows Point Plant consist of three coke oven batteries and two coal chemical plants. The by-product coke oven gas (COG) consists primarily of hydrogen, methane, carbon monoxide, nitrogen and contaminants consisting of tars, light oils (benzene, toluene, and xylene) hydrogen sulfide, ammonia, water vapor and other hydrocarbons. This raw coke oven gas needs to be cleaned of most of its contaminants before it can be used as a fuel at other operations at the Sparrows Point Plant. In response to environmental concerns, BSC decided to replace much of the existing coke oven gas treatment facilities in the two coal chemical Plants (A and B) with a group of technologies consisting of: Secondary Cooling of the Coke oven Gas; Hydrogen Sulfide Removal; Ammonia Removal; Deacification of Acid Gases Removed; Ammonia Distillation and Destruction; and, Sulfur Recovery. This combination of ...

Energy Technology Data Exchange (ETDEWEB)

Reduction of occupational radiation exposure dose in a BWR plant is achieved by an elimination of crud in a BWR primary loop condensate stream by condensate demineralizer. Crud removal by condensate polisher improves year by year, a phenomenon called the Aging Effect of Ion Exchange Resins. The cause of this phenomenon is assumed to be mainly due to changes in the cation resin property becoming more crud adsorptive, where a typical change in physical property of aged cation resin is an increase in water retention capacity. Assuming that the crud removal efficiency was influenced by a crosslinkage of cation resin, an attempt was made to enhance this removal efficiency by decreasing the crosslinkage and satisfactory results were obtained. As a result, new gel type cation resins were developed with lower crosslinkage and larger surface areas, as compared with conventional gel type resins. The crosslinkage ...

Energy Technology Data Exchange (ETDEWEB)

1. Cyanide degradation: Of the cyanide- and thiocyanate-degrading bacteria, Burkholderia cepacia and Pseudomonas spec. were the most effective. 2. Biosorption: Of the isolates suited for biosorption of heavy metals, 597-A (non-identifiable) and 597-A2 (Aspergillus fumigatis) had the biggest potential. The sorption capacity of the fungi for metals varied with the C source used for their growth: apple juice > molasses > glucose. The fungi are not cyanide-sensitive and can even degrade cyanide. Living biomass had better metal sorption efficiencies than dead mycelium. The biosorption rates in waste water were usually higher than in broth. Depending on the metal composition and concentrations and on the exposure time and volume of the mycelia, up to 85 % of the initial concentration was removed from the liquid phase. The capacity of different biomasses for the sorption of metal mixtures was between 65 and 80 mg/g of dry matter ...

Energy Technology Data Exchange (ETDEWEB)

The Tennessee Valley Authority (TVA), the Electric Power Research Institute (EPRI), and the Department of Energy-National Energy Technologies Laboratory (DOE-NETL) are evaluating and demonstrating integration of terrestrial carbon sequestration techniques at a coal-fired electric power plant through the use of Flue Gas Desulfurization (FGD) system gypsum as a soil amendment and mulch, and coal fly ash pond process water for periodic irrigation. From January to March 2002, the Project Team initiated the construction of a 40 ha Carbon Capture and Water Emissions Treatment System (CCWESTRS) near TVA's Paradise Fossil Plant on marginally reclaimed surface coal mine lands in Kentucky. The CCWESTRS is growing commercial grade trees and cover crops and is expected to sequester 1.5-2.0 MT/ha carbon per year over a 20-year period. The concept could be used to meet a portion of the timber industry's needs while ...

Energy Technology Data Exchange (ETDEWEB)

A summary of the off-gas behavior in the HARVEST pot vitrification process is presented. Experimental runs were carried out on 3 representative wastes (MAGNOX - thermal reactor, metal fuel, THORP - thermal oxide fuel and PFR - fast reactor oxide fuel) using 2 methods of feeding the glass-formers (slurry and crizzle). Materials were carried over from the vitrification vessel into the off-gas system by entrainment supplemented by volatilization. The main volatile elements were Ru, B, Cs. Some volatility was also shown by Na and Li. The overall behavior of the off-gas was consistent with the presence in it of 5 separate aerosols of particulate matter. Sources of entrainment gave rise to 3 aerosols, and a further 2 aerosols were formed as a result of chemical reaction (Ru) and condensation (Cs) proceses involving the volatile species. Entrainment was enhanced when the feed contained free alkali nitrate. The Ru volatility correlated directly with the amount of salt ...

Science.gov (United States)

EPA has proposed effluent limitations guidelines and standards for the centralized waste treatment (CWT) industry. This report investigates the cost-effectiveness of all possible combinations of proposed control options for the three subcategories of CWT operations. EPA considered three control options for metals, two for oils and two for organics, with 12 possible combinations of these options. The report measures cost-effectiveness through a comparison of compliance costs to the quantity of pollutants removed under each combination of control options. The effectiveness of the regulations is measured in terms of reductions in the pounds of pollutants discharged to surface waters, weighted to account for the pollutants` toxicity. Some pollutants removed are specifically addressed by the regulation, while others and not directly regulated but are removed incidentally as a result of controlling for other ...

International Nuclear Information System (INIS)

The harmful effect of phosphate in yellow cake on the TBP purification process and its removal methods are dealed with. The reason of more uranium loss in residue was analyzed. The harmful effect of phosphate on TBP extraction efficiency and operaton of extraction column was discussed. The limit value of uranium concentration in digestion solution was presented. For TBP purification process, the presence of phosphate in yellow cake does more harm than good. (authors)

Energy Technology Data Exchange (ETDEWEB)

Under the repository storage conditions of Eram and Konrad, waste packages designed for permanent storage must not contain or release freely mobile liquids, except for the minimum residues attainable by reasonable efforts or unavoidable. In accordance with a directive issued by the German Federal Ministry for the Environment (BMU), waste conditioning must be carried out so as to minimize waste volumes and, if possible, on the site where the waste arises. Liquid waste is conditioned most effectively by drying. At the present time, various different processes for drying liquid waste are employed as reflected by the state of the art: The Robe process; roller drying; the RDA process; Favorit; in-drum drying; and HPA liquid waste drying with make-up feed. The HPA process offers these advantages: Drying under atmospheric conditions, which means high level of dryness (freely mobile and releasable ...

Energy Technology Data Exchange (ETDEWEB)

The Institute of Gas Technology (IGT) has conducted a fundamental research program to determine the technical feasibility of a process concept that involves pressurized CO{sub 2}-coal gasification followed by a high-temperature CO{sub 2} removal step, using a MgO-based sorbent. To investigate a hot-CO{sub 2}-removal process, various MgO-containing materials were tested for their reactivity and capacity for removing CO{sub 2} from hot gas streams in a high-pressure thermobalance. No naturally-occurring materials were found to be acceptable, but a KOH-promoted magnesia was found to be sufficiently active for CO{sub 2} removal and to have a good capacity for CO{sub 2} absorption. Tests were conducted at pressures and temperatures in the ranges of 100--300 psig and 850{degree}--1170{degree}F. The CO{sub 2} absorption/desorption cycle was shown to be achievable by a ...

Energy Technology Data Exchange (ETDEWEB)

Biomass contains nitrogen that is converted to NOx on combustion. Conversion of biomass into producer gas by thermal gasification offers an opportunity to reduce NOx-emissions by NH3 removal from the producer gas with water. Waste water will have to be treated before it can be drained. Recovered NH3 may have value as base chemical, but usually will have to be disposed off as waste. Recycling within the gasification process is an option to dispose off NH3 waste, provided NH3 is broken down under gasification conditions. We present experimental data on NH3 destruction in a CFB gasifier at temperatures from 780C to 860C, when NH3 is injected into the gasification air. Within that temperature range, the fraction of NH3 that is broken down increases from less than 50% to nearly 100%. Clearly, the presence of O2 at the injection point leads to a much higher rate of NH3 destruction than observed for purely ...

British Library Electronic Table of Contents (United Kingdom)

An exergy analysis method is presented of the solar multi-effect humidification?dehumidification desalination (HDD) process. Pinch technology is used in the humidification process to determine the maximum possible saturated air temperature and the temperature of water rejected from the unit, and then the dehumidification process to determine the temperature of water leaving from the heat exchanger. The formulae to calculate the exergy of water and saturated air are given. The solar plane collector is used. From exergy analysis, the solar collector has the lowest exergy efficiency; the HDD process has a lower exergy efficiency, and the water rejected has also a large exergy loss. The energy and exergy recovery rate of the desalination process is also lower. The solar multi-effect HDD proces...

British Library Electronic Table of Contents (United Kingdom)

Humic acids are considered problematically in drinking water because it can react readily with chlorine to form carcinogen compounds and its biological removal is much recommended. The scanning electron microscopy morphologies and optical parameters observed for natural humic acids (NHAs) extracted from different soils at Mitidja plain (Algeria) made them different from the commercial ones. Three of the most active strains of 19 actinomycetes were isolated and selected from surface soils at this plain. These strains were identified based on cultural characteristics and chemotaxonomic analysis and classified in the genus Streptomyces. Growth of these strains was assured on a poor liquid medium containing NHAs as carbon and nitrogen sources and degradation occur only in the presence of gluco...

Science.gov (United States)

Using the infrared spectroscopy method, we have studied the effect of thermal dehydration (under vacuum and in air) and treatment with water vapor on the acid centers of very high silicon zeolites of the ZSM type. We have shown that dehydration under vacuum and in air completely and irreversibly removes the OH groups at 1120/sup 0/K, while treatment with water vapor removes these groups at 770/sup 0/K. The Lewis acid centers of dehydrated zeolites (represented by two types of centers) are more heat-stable than the Bronsted acid centers, but the vapor treatment at 1020/sup 0/K leads to the disappearance of the Lewis acid centers. In this work, we discuss the reasons for destruction of the acid centers of the zeolites under different treatment conditions.

Science.gov (United States)

An interest in electronic materials has led me to investigate new synthetic approaches to III-V' type semiconducting (13-15, current IUPAC designation for B and N groups in the Periodic Table) and magnetic (3-15) compounds. It is now possible to prepare binary (GaAs and GdP) and ternary mixed-metal (Al[sub x]Ga[sub 1-x]As) and mixed-pnictide (GaP[sub x]As[sub 1-x]) compounds in seconds from rapid, low-temperature-initiated metathesis reactions between a metal (III) trihalide and a trisodium pnictide, exemplified by MX[sub 3] + Na[sub 3]Pn [yields] MPn + 3 NaX, where M is Al, Ga, In, (Al,Ga), or a lanthanide; X is F, Cl, or I; and Pn is P, As, Sb, or (P,As). The precursors are mixed together in a dry box and ignited by light grinding with a mortar and pestle, or by brief, local heating from a hot filament. These reactions are very exothermic (calculated [Delta]H[sub rxn] (GaAs) = 138 kcal/mol) and typically reach temperatures in excess of 700[degrees]C within seconds of ...

Energy Technology Data Exchange (ETDEWEB)

A Lurgi baseline study was requested by the DOE/GRI Operating Committee of the Joint Coal Gasification Program for the purpose of updating the economics of earlier Lurgi coal gasification plant studies for the production of substitute natural gas (SNG) based on commercially advanced technologies. The current study incorporates the recent experience with large size Lurgi plants in an effort to improve capital and operating costs of earlier plant designs. The present coal gasification study is based on a mine mouth plant producing 250 billion Btu (HHV) per day of SNG using the Lurgi dry bottom coal gasification technology. A Western subbituminous coal was designated as the plant food, obtained from the Rosebud seam at Colstrip, Montana. This study presents the detailed description of an integrated facility which utilizes coal, air, and water to produce 250 billion Btu (HHV) per day of SNG. The plant consists of coal handling and preparation, twenty-six Lurgi dry ...

Energy Technology Data Exchange (ETDEWEB)

Biosorption means the storage of substances at the cell envelope. Different microbial biomasses were tested for the separation of radionuclides from mining waters. Results of a pilot plant demonstrate the ability of these techniques for water cleaning processes. An effluent concentration of lower than 1 mg/l (in most cases 0.1 mg/1) could be realized in a pilot plant by using pure cells of a methylotrophic strain of bacteria as well as using of a fungal mycelia.

Energy Technology Data Exchange (ETDEWEB)

Natural sunlight induces a genotoxic response in cultured CHO cells pre-treated with shale oil retort process water. Near ultraviolet light (NUV) component of the solar spectrum is the apparent radiation responsible for photoactivation. Cultured human skin fibroblasts are acutely sensitive to the genotoxic effects of photoactivated process water. The mutagenic potential of photoactivated process water in human cells is the same as that witnessed for an equivalent killing dose of the potent skin carcinogen FUV. DNA repair processes are involved in modulating genotoxic effects of this photo-induced process. The exact magnitude of the potential health-related and environmental risks resulting from photoactivation of retort process waters and other oil shale by-products is unassessed ...

International Nuclear Information System (INIS)

The ultra-high pressure waterjet technology was being evaluated at Florida International University (FIU) as a baseline technology. In conjunction with FIU's evaluation of efficiency and cost, this report covers the evaluation conducted for safety and health issues. It is a commercially available technology and has been used for various projects at locations throughout the country. The ultra-high pressure waterjet technology acts as a cutting tool for the removal of surface substrates. The Husky trademark pump feeds water to a lance that directs the high pressure water at the surface to be removed. The safety and health evaluation during the testing demonstration focused on two main areas of exposure. These were dust and noise. The dust exposure was found to be minimal, which would be expected due to the wet environment inherent in the technology, but noise exposure was at a significant level. Further ...

International Nuclear Information System (INIS)

Finding environmentally friendly and cost-effective methods to remediate soils contaminated with polycyclic aromatic hydrocarbons (PAHs) is currently a major concern of researchers. In this study, a series of small-scale semi-continuous extractions - with and without in situ wet oxidation - were performed on soils polluted with PAHs, using subcritical water (i.e. liquid water at high temperatures and pressures, but below the critical point) as the removal agent. Experiments were performed in a 300 mL reactor using an aged soil sample. To find the desorption isotherms and oxidation reaction rates, semi-continuous experiments with residence times of 1 and 2 h were performed using aged soil at 250 deg. C and hydrogen peroxide as oxidizing agent. In all combined extraction and oxidation flow experiments, PAHs in the remaining soil after the experiments were almost undetectable. In combined extraction and oxidation no PAHs could ...

International Nuclear Information System (INIS)

This is a slide-based oral presentation given to the COG/IAEA: Fifth technical committee meeting on 'Exchange of operating experience of pressurized heavy water reactors' held in Mangalia, Romania on 7-10 September 1998. Since energization of Wolsung Unit 3 station service transformer on July 12, 1996 a line of initial test program was conducted as follows: 1. ILRT/SIT; 2. Pre-operational and Hot Functional testing with a Light Water and without Fuel in Systems; 3. Load D_2O in Moderator System; 4. Initial fuel loading; 5. Load D_2O in PHT System; 6. Hot Functional Testing with Heavy Water and Fuel in Systems; 7. Criticality and Low Power Physics Testing; 8. Power Ascension Test and, then finally, phase-D test; the plant acceptance test was accomplished after having a Mini-Overhaul to prepare for Commercial Operation. These documents contain not only both overall introduction of commissioning and the first TBN rolling and ...

Energy Technology Data Exchange (ETDEWEB)

Implementation of Noble Metal Chemical Application (NMCA) in a Boiling Water Reactor (BWR) requires injection of a noble metal compound while the reactor is idle at hot shutdown conditions. In order to minimize outage time, utilities are very pro-actively finding ways to reduce the number of critical path tasks. One of these tasks is to remove some containment vessel drywell head bolts during the NMCA idle time. This, thereby, saves the utilities outage time, or they can perform other tasks as desired. Using design basis conditions and state-of-the-art analytical techniques, detailed finite element stress analyses of the closure region are performed. Two acceptance criteria are evaluated. The first is that contained within Section III of the ASME Code for allowable stresses. The second relates to leak tightness, i.e., with bolt removal the joint must still remain leak tight. This paper describes the activities performed to ...

Energy Technology Data Exchange (ETDEWEB)

Oxyanions of uranium, selenium, chromium, arsenic, technetium, and chlorine (as perchlorate) are frequently found as contaminants on many DOE sites, and in other areas of the U.S.. A potential remediation method is to react the contaminated water with zero-valent iron (ZVI). We are performing fundamental investigations of the interactions of the relevant compounds with Fe filings and single- and poly-crystalline surfaces. The aim of this work is to develop the physical and chemical understanding that is necessary for the development of cleanup techniques and procedures.

British Library Electronic Table of Contents (United Kingdom)

The lignin, one of the main by-products of the pulp industry, can be used to remove dyes from textile wastewaters. The potential of the lignin for Brilliant Red HE-3B reactive dye removal from aqueous solutions at pH=1.5 was examined by the batch technique as a function of dye concentration, solution temperature and contact time. The Freundlich, Langmuir, Dubinin-Radushkevich and Tempkin adsorption isotherms were used to describe the data of sorption equilibrium and to determine its corresponding isotherm constants. The thermodynamic parameters DG, DH and DS were also determined; the obtained values show that the sorption of reactive dye on lignin is a spontaneous, endothermic and entropy-driven process. The kinetic of reactive dye sorption was analyzed using the pseudo-first order and pse...

British Library Electronic Table of Contents (United Kingdom)

Electrochemical discharge machining (ECDM) is a promising hybrid process for high-performance machining of non-conductive glass. ECDM drilling has been found to have different characteristics and material removal mechanisms in discharge regime (less than 300??m in depth) and hydrodynamic regime (more than 300??m in depth); however, these regimes are never separately modeled in existing ECDM models, which leads to large prediction error, especially at low applied voltages and high machining depths. Until now, no model is particularly designed for discharge regime, where most material is removed. In this paper, a finite element based model for ECDM drilling in discharge regime is presented. Material removal subjected to a single spark was simulated using finite element method. The drilling d...

Energy Technology Data Exchange (ETDEWEB)

Separation of the bulk soluble chemical salts from the insoluble metal hydroxides and radionuclides is central to the strategy of disposing Hanford tank waste. Sludge washing and caustic leaching have been selected as the primary methods for processing the 230 million L (61,000,000 gal) of Hanford tank waste. These processes are very similar to those selected for processing waste at the West Valley Site in New York and the Savannah River Site in South Carolina. The purpose of sludge washing is to dissolve and remove the soluble salts in the waste. Leaching of the insoluble solids with caustic will be used to dissolve aluminum hydroxide and chromium hydroxide, and convert insoluble bismuth phosphate to soluble phosphate. The waste will be separated into a high-level solids fraction and a liquid fraction that can be disposed of as low-level waste after cesium removal. The washing and ...

Energy Technology Data Exchange (ETDEWEB)

This dissertation deals with membrane gas absorption in the application of CO{sub 2} removal by aqueous alkanolamines, using microporous PTFE hollow fiber membranes. A new lab-scale apparatus was constructed and an extensive experimental study executed to determine the performance of the membrane gas absorber, with aqueous solutions of monoethanolamine (MEA) and methyldiethanolamine (MDEA) as absorbents. The important operation parameters CO{sub 2} partial pressure, gas velocity, liquid velocity, temperature and liquid CO{sub 2} loading were systematically varied within the range typically experienced in a process for exhaust gas CO{sub 2}-removal

International Nuclear Information System (INIS)

Radionuclide X-ray fluorescence analysis was used for the determination of iron, calcium, potassium, copper, manganese and zinc in waste water from the production process of citric acid. (author).

Energy Technology Data Exchange (ETDEWEB)

This program is concerned with the development of an advanced method for the separation of hydrogen sulfides from coal gas. The process utilizes an electrochemical membrane which removes hydrogen sulfide without cooling the gas and with negligible pressure loss through the separator.

Energy Technology Data Exchange (ETDEWEB)

The purpose of this research is to develop a technically and economically feasible process for biologically producing H(sub 2) from synthesis gas while, at the same time, removing harmful sulfur gas compounds. Six major tasks are being studied: 1. Culture development, where the best cultures are selected and conditions optimized for simultaneous hydrogen production and sulfur gas removal; 2. Mass transfer and kinetic studies in which equations necessary for process design are developed; 3. Bioreactor design studies, where the cultures chosen in Task 1 are utilized in continuous reaction vessels to demonstrate process feasibility and define operating conditions; 4. Evaluation of biological synthetic gas conversion under limiting conditions in preparation for industrial demonstration studies; 5. Process scale-up where laboratory data are scaled to larger-size ...

International Nuclear Information System (INIS)

The production of ozone in a negative corona discharge fed by carbon dioxide with embedded traces of oxygen and water has been studied. The presence of traces of oxygen in both pure and dry CO_2 leads to an increase in nascent ozone concentrations. In contrast, traces of water vapour (0-800 ppm) are shown to rapidly suppress ozone concentrations with the largest decreases being observed at lowest gas pressures in the discharge (300 Torr). The presence of water vapour did not considerably affect the electrical properties of negative dc corona suggesting that a chemical process is responsible for the ozone loss. We have shown that the addition of water up to a concentration of 1500 ppm has only a marginal effect on the processes of ozone formation but the catalytic cycle of ozone destruction involving OH radicals can be the reason for observed decrease in the ...

Energy Technology Data Exchange (ETDEWEB)

The operation of industrial facilities has generally resulted in contamination of the surrounding soils and ground water. A variety of methods have been proposed for the remediation of contaminated sites. This paper presents new process technology that is capable of performing treatment on ground water or soil washing leachates. The process is targeted to treat low levels of radioactivity, organics and heavy metals present in the aqueous solutions, to be easily transported and provide simple operation on-site and provide an effluent that meets the specified discharge quality. The purification process involves sequential chemical treatment and filtration. The paper will describe the development of the technology and review the current progress in its use to remediate contaminated sites at Chalk River. The application of the process technology has demonstrated ...

Science.gov (United States)

... More particularly, the invention relates to novel felted combustible cartridge cases of excellent tensile strength, water resistance and combustibility. ...

International Nuclear Information System (INIS)

One of the most effective removing processes of iodine species is what is called ''Iodox Process'', which contains oxidation and absorption of iodine species by highly concentrated nitric acid. The result of fundamental test with bubble column in this process had been reported. Present paper describes the fundamental experiment by the use of packed column. This experiment has been carried out to clear the effect of feed gas flow rate, nitric acid flow rate, nitric acid concentration, and methyl iodide concentration on removal efficiency of methyl iodide. The following results were obtained. The decontamination factor of methyl iodide (DF) increases exponentially with nitric acid concentration, which agrees with the result obtained by using the bubble column. The factor is in inverse proportion to feed gas flow rate, and is also almost independent of nitric acid flow rate and methyl ...

International Nuclear Information System (INIS)

A pyrochemical process has been introduced and utilized so that the transmutation of spent PWR fuel in PEACER can produce mainly low and intermediate level waste for near surface disposal. Major radioactive nuclides from PEACER pyro-processing are composed of TRU and LLFP. In this study, the requirement for the final waste from PEACER is evaluated based on the methodology for establishment of waste acceptance criteria. Also, sensitivity analysis for several input parameters is conducted in order to determine acceptable decontamination factor (DF) and LLFP removal efficiency and to find out input parameter that extremely have an effect on DF. As a result of the study, LLFP removal efficiency, especially Sr-90 and Tc-99, is proved to be a major nuclide which contributes to annual dose by human intrusion scenario rather than TRU DF. More than 98.5% of LLFP have to be removed to meet ...

International Nuclear Information System (INIS)

A series of tests has been carried out to determine the operating conditions required to remove the corrosion deposit from samples cut from Winfrith Steam Generating Heavy Water Reactor (WSGHWR) primary circuit pipework by submerged water jetting. Two types of samples were used - one set subjected to the normal annual reactor decontamination using TURCO reagents, the other set having been given a LOMI treatment in addition. Tests showed that useful decontamination factors could be achieved on both types of sample, but significantly less severe operating conditions were required to decontaminate the LOMI treated samples. A decontamination factor of 10 was achieved on TURCO treated samples at 360 Bar; only 200 Bar was required to achieve the same decontamination factor on LOMI treated samples. No metal erosion of the stainless steel substrate was found to occur at these pressures. (author).

Energy Technology Data Exchange (ETDEWEB)

Sulfuric acid hydrogen peroxide mixtures (SPM) are commonly used in the semiconductor industry to remove organic contaminants from wafer surfaces. This viscous solution is very difficult to rinse off wafer surfaces. Various rinsing conditions were tested and the resulting residual contamination on the wafer surface was measured. The addition of small amounts of a chemical base such as ammonium hydroxide to the rinse water has been found to be effective in reducing the surface concentration of sulfur and also mitigates the particle growth that occurs on SPM cleaned wafers. The volume of room temperature water required to rinse these wafers is also significantly reduced.

International Nuclear Information System (INIS)

Tests on the scrubbing column have led to the following results: Use of a scrubbing column with Raschig rings is only meaningful for the sedimentation of particles exceeding diameters of 0.5 #mu#m; drops of diameter size 1.5 #mu#m are formed in the column; more efficient drop precipitators in the column air flow ease the load on subsequent suspended material filters thereby contributing to a longer life of these filters even at higher sodium ion concentrations in the washing water; with distillate of an 8% rather than 0.8% salt solution a decontamination factor greater than 10 can be calculated since larger particles precipitate more readily. This only applies, however, under the condition that the washing water is renewed regularly, if necessary daily where higher aerosol concentrations are present. If not, the decontamination factor will be reduced through the salt-containing secondary aerosols from the washing water. ...

International Nuclear Information System (INIS)

Due to the large number of chemicals in commerce without adequate toxicity characterization data, coupled with an ineffective federal policy for chemical management in the United States, many states are grappling with the challenge to identify toxic chemicals that may pose a risk to human health and the environment. Specific populations (e.g., children, elderly) are particularly sensitive to these toxic chemicals. In 2008, the Children's Safe Product Act (CSPA) was passed in Washington State. The CSPA included specific requirements to identify High Priority Chemicals (HPCs) and Chemicals of High Concern to Children (CHCCs). To implement this legislation, a methodology was developed to identify HPCs from authoritative scientific and regulatory sources on the basis of toxicity criteria. Another set of chemicals of concern was then identified from authoritative sources, based on their potential exposure to children. Exposure potential was evaluated by identifying chemicals detected in ...

Energy Technology Data Exchange (ETDEWEB)

Cold Heavy Oil Production with Sand (CHOPS) is an enhanced oil recovery method that induces sand production to form a network of wormholes that increase the porosity and permeability of a formation. Under proper conditions, CHOPS can improve formation flow characteristics. Integrated well completion strategies that were used to increase oil production at Fula oil field on the south flank of Mughad Basin in Sudan were described. Limited sand influx provided a means for effective sand control while eliminating the need for conventional sand control processes. Cold heavy oil production with limited sand influx requires optimized completion methods to stimulate sand production, thereby reducing oil flow resistance and prolonging the sand removal operation cycle. Completion tests were performed in terms of different formation conditions including perforating completion; perforating and full sand control completion by screen liner; and perforating ...

Science.gov (United States)

The melting unit, consisting of a water-cooled cupola furnace, afterburner, heat exchanger, air preheater, consumes most of the supplied energy in the rockwool process. The report maps the energy flows and defines factors of merit according to thermodynam...

Energy Technology Data Exchange (ETDEWEB)

A significant number of biosorption studies on the removal of heavy metal from aqueous solutions have been conducted worldwide. Nearly all of them have been directed towards optimizing biosorption parameters to obtain the highest removal efficiency while the rest of them are concerned with the biosorption mechanism. Combinations of FTIR, SEM-EDX, TEM as well as classical methods such as titrations are extremely useful in determining the main processes on the surfaces of biosorbents. Diverse functional groups represented by carboxyl, hydroxyl, sulfate and amino groups play significant roles in the biosorption process. Solution pH normally has a large impact on biosorption performance. In brief, ion exchange and complexation can be pointed out as the most prevalent mechanisms for the biosorption of most heavy metals. (Abstract Copyright [2008], Wiley Periodicals, Inc.)

International Nuclear Information System (INIS)

Water flow experiments were conducted on natural circulation decay heat removal with an electrically heated 91-rod bundle. Experimental results were compared with analytical predictions to provide thermal hydraulic characteristics for LMFBR Fuel assemblies under a low flow, typical of the natural circulation regime. The results revealed that, at low flow rate region (Re<1,200), axial friction loss in a heated bundle increases with buoyancy effect. The radial temperature profile provides some insight regarding the concept that coolant redistribution would occur. COBRA-V-I predictions are successfully proved validity in comparison with experimental results.

International Nuclear Information System (INIS)

The results of studies of radiation-thermocatalytic water decomposition in the 673-773 K temperature range in the presence of BeO and titanium Y-type zeolite are presented. It is found that radiation-thermocatalytic processes of hydrogen production from water are characterized by a lower activation energy (55.4 kJ/mole) as compared with thermocatalytic processes (88.4 kJ/mole). The radiation-thermocatalytic process rate in the presence of oxide systems is not an additive sum of rates of radiation-catalytic (at 296-300 K) and thermocatalytic processes of water decomposition. On the basis of obtained results the conclusion is made that during radiation-catalytic decomposition of water in a heterogeneous system BeO + H_2O the main contribution into this process is made by excitons, radiation-chemical ...

Energy Technology Data Exchange (ETDEWEB)

An advanced process for the separation of hydrogen sulfide (H{sub 2}S) from coal gasification product streams through an electrochemical membrane is being developed. H{sub 2}S is removed from the syn-gas stream, split into hydrogen, which enriches the exiting syn-gas, and sulfur, which is condensed from an inert sweep gas stream. The process allows removal of H{sub 2}S without cooling the gas stream and with negligible pressure loss through the separator. The process is made economically attractive by the lack of need for a Claus process for sulfur recovery. Membrane manufacturing coupled with full-cell experimentation was the primary focus this quarter. A tape-casted zirconia membrane was developed and utilized in one full-cell experiment (run 25); run 24 utilized a fabricated membrane purchased from Zircar Corporation. Results are discussed.

Energy Technology Data Exchange (ETDEWEB)

The WIT telemanagement system simply, reliably and efficient by makes available to us in real time processed, ordered and managed data. Such information has been used to optimise the performance of the drinking water distribution networks on a number of housing estates. This has led to major saving in consumption and on equipment maintenance, thereby improving customer service and obtaining a more rational use of piped water. (Author)

Energy Technology Data Exchange (ETDEWEB)

The mission of the Heavy Water portion of D Area (or 400 Area) at SRS is to purify the site inventory of heavy water for storage in the Reactor Areas for future DOE missions.

Energy Technology Data Exchange (ETDEWEB)

This article presents a humidification-dehumidification (H.D.) process suitable for desalination of sea- and brackish water. The work correlated performance characteristics of the combination of different components in such a loop. Water yield, energy requirement and design data are evaluated as functions of different parameters. The investigation covered water to air mass ratios ranging from 60 to 80, concentration ratios between 2 and 5, at a temperature difference of between 10 and 16 C, along the liquid for dehumidification. The results showed that 76% of energy consumed in the humidifier is recovered by condensation. Increase of the concentration ratio to 5 can reduce the make-up water and rejected brine by about 58% and 24% respectively. Cost calculations show that the H.D. process has significant potential as an alternative for small capacity desalination ...

Energy Technology Data Exchange (ETDEWEB)

The construction and use of a portable, microprocessor controlled anodic stripping voltameter for on-site simultaneous metal analysis of copper, lead and cadmium in tap water is discussed. The instrumental system is comprised of a programmable controller which permits keying in analytical parameters such as sparge time and plating time: a rotating cell for efficient oxygen removal and amalgam formation; and, data handling via a minicomputer or analog pen recorder. Plating and stripping potentials are controlled by a digital potentiostat; stripping is done using a staircase waveform with measurement of the current after a one msec delay. In this way charging current effects are minimized. Results of tap water analysis showed 3 +- 1 ..mu..g/L lead, 22 +- 0.3 ..mu..g/L copper, and less than 0.2 ..mu..g/L cadmium for a Berkeley, California tap water, and 1-1000 ..mu..g/L Cu, 1 -2 ..mu..g/L Pb for ten ...

Energy Technology Data Exchange (ETDEWEB)

We describe the synthesis and characterization of superparamagnetic iron oxide nanoparticle based heavy metal sorbents with various surface chemistries that demonstrate an excellent affinity for the separation of heavy metals in contaminated water systems (i.e. spiked Columbia river water). The magnetic nanoparticle sorbents are prepared from an easy to synthesize iron oxide precursor, followed by a simple, one-step ligand exchange technique to introduce the organic surface functionality of interest chosen to target either specific or broader classes of heavy metals. Functionalized superparamagnetic nanoparticles are excellent sorbent materials for the extraction of heavy metal contaminants from environmental and clinical samples since they are easily removed from the media once bound to the contaminant by simply applying a magnetic field. These engineered magnetic nanoparticle sorbents have an inherently high active ...

Science.gov (United States)

A developed flue gas desulfurization and dust removal process with a cross-flow moving bed filled with activated coke (AC) was tested on a pilot scale with the gas treatment capacity of 1000 mg x h(-t). The results show that a easy-operating and stable-running pilot-scale testing equipment can be reached, and under the conditions of testing space velocity, the feed gas temperature of 120 degrees C, SO2 concentrations of 3232-6006 mg x m(-3) and dust concentration of 89.3-1599.7 mg x m(-3), the high efficiency of flue gas desulfurization and dust removal is reached with the purity of dust less than 50 mg x m(-3). In the technology, the spent AC was regenerated by heating, and the SO2 concentration in the desorption gas is about 40.1%, which can be efficiently recovered as a sulfur resource. Favorable economy benefit can be reached by using the process. PMID:16850821

Energy Technology Data Exchange (ETDEWEB)

Conventional methods for removing metals from aqueous solutions include chemical precipitation, chemical oxidation or reduction, ion exchange, reverse osmosis, electrochemical treatment and evaporation. The removal of radionuclides from aqueous waste streams has largely relied on ion exchange methods which can be prohibitively costly given increasingly stringent regulatory effluent limits. The use of microbial cells as biosorbants for heavy metals offers a potential alternative to existing methods for decontamination or recovery of heavy metals from a variety of industrial waste streams and contaminated ground waters. The toxicity and the extreme and variable conditions present in many radionuclide containing waste streams may preclude the use of living microorganisms and favor the use of non-living biomass for the removal of actinides from these waste streams. In the work presented here, we have ...

Energy Technology Data Exchange (ETDEWEB)

COGNIS TERRAMET{reg_sign} soil leaching and Bescorp soil washing systems have been successfully combined to remediate an ammunition test burn area at the Twin Cities Army Ammunition Plant (TCAAP), New Brighton, MN. This cleanup is the first in the country to combine these two technologies, and this approach offers a permanent remedial solution. In Fall 1993, 1,600 tons of soil were remediated with an additional 10,000+ tons treated in 1994. The cleaned soil remained on-site, and the heavy metal contaminants were removed, recovered, and recycled. Eight heavy metals were removed from the contaminated soil achieving the very stringent cleanup criteria of <175 ppm for residual lead and achieving background concentrations for seven other heavy metals (antimony, cadmium, chromium, copper, mercury, nickel, and silver). In addition, both live and spent ordnance had to be removed in the soil treatment plant to meet the cleanup ...

British Library Electronic Table of Contents (United Kingdom)

This paper presents a hybrid solar desalination process of the multi-effect humidification dehumidification and the basin-type unit. The sketch of the hybrid solar desalination process is given. The solar vacuated tube collector is employed in the desalination system, multi-effect humidification dehumidification desalination (HDD) process is plotted according to pinch technology, and then the water rejected from multi-effect HDD process is reused to desalinate in a basin-type unit further. The gain output ratio (GOR) of this system will rise by 2?3 at least through reusing the rejected water. The research proves that the multi-effect HDD has much room to be improved. A hybrid solar desalination process of the multi-effect humidification dehumidification and the basin-type unit should be no...

Energy Technology Data Exchange (ETDEWEB)

Water vapor is well known to be a critical component in many aspects of atmospheric research, such as radiative transfer and cloud and aerosol processes. This requires both improved measurements of the columnar water vapor and its profiles in the atmosphere in a wide range of conditions, and adjustment of water vapor parameterizations in radiation codes including the perfection of spectroscopic parameters. In this paper we will present the results of comparison of our calculations and downward solar fluxes measured with Rotating Shadowband Spectroradiometer under conditions of horizontally homogeneous clouds. We also will discuss the sensitivity of atmospheric radiation characteristics to variations of water vapor in the band 940 nm: these results may be useful for development of new methods of retrieval of the total column water vapor content (WVC) in the ...

International Nuclear Information System (INIS)

The commercial Modular High Temperature Gas-Cooled Reactor (MHTGR) achieves improved reactor safety performance and reliability by utilizing an integrated sequence of completely passive thermal storage and heat transfer mechanisms to reject decay heat in the event that all its active cooling systems fail to operate. During such events, the initial heatup transient in the core is followed by a quasi-steady state cooldown process which, if uninterrupted, can continue for several days. A buoyancy-driven natural convection cooling system called the RCCS facilitates the continuous heat removal by circulating ambient air through the reactor cavity, where it is heated and then exhausted to the outside environment. The peak thermal load on the RCCS occurs approximately at the time that the vessel reaches its highest temperature. To confirm the adequacy of the RCCS design, detailed analytical models were developed to simulate the decay heat ...

Energy Technology Data Exchange (ETDEWEB)

The continuous bioprocessing of simulated steam-stripped sulfite pulp mill evaporator condensates using Candida utilis to produce single cell protein has been studied. At 32 degrees C, processing can be conducted at space velocities of up to 0.43 hr/sup -1/ with over 90% removal of acetic acid present at an initial concentration of 2 g/liter. (Refs. 16).

Energy Technology Data Exchange (ETDEWEB)

Sputter-removal rates of overlayer and interfacial species on silicon are analyzed to determine sputtering yields for the species involved. Sputtering yields up to two orders of magnitude lower than those measured for silicon are found, and the results are interpreted in terms of a cascade mixing process which continually reburies much of the overlayer material beyond the escape depth of the sputtered atoms.

Science.gov (United States)

The report gives results of a pilot-plant study of the ammonia absorption/ammonium bisulfate regeneration process for removing SO2 from the stack gas of coal-fired power plants. Data were developed on the effects of such operating variable in the absorption of SO2 by ammoniacal l...

Energy Technology Data Exchange (ETDEWEB)

Commercial development of oil shale resources will produce vast quantities of processed shale waste. The presence of potentially toxic trace elements, inorganic salts, and potentially toxic residual organic constitutents make the disposal of vast quantities of processed shale a potential environmental problem. To be environmentally acceptable, processed shale disposal must: result in a physically stable structure, prevent or minimize release of potentially toxic compounds, and provide an economically acceptable post-land use. Water is the common element underlying all factors important to the environmental stability of disposed solid waste. The leaching and transport of solubles by water in processed shale embankments may result in degradation of local surface and groundwater quality. The major purpose of this research is to physically model, study, and describe ...

International Nuclear Information System (INIS)

Nitric acid leaching from the weak base anion (WBA) exchanger had been evaluated and based on this a 5% mixture of nitric acid loaded weak base anion exchanger with fresh weak base anion exchanger (NLWBA) at the bottom of the ion exchange column has been devised to maintain an outlet pH in the range of 5.0 to 5.5 during Gd removal from the moderator system of TAPP - 3 and 4. A three layered bed had been constituted wherein strong acid cation (SAC) exchanger is placed as the top layer while a mixed bed of SAC and WBA or pure WBA is used as the middle layer and the 5% NLWBA was used as the bottom most layer. This bed configuration would result in an iso-pH regime in the moderator system during the Gd removal along with quantitative removal of Gd. Two three-layer bed columns were prepared at TAPS - 3 and 4 in July 07. The resin was loaded in batches and after preparing the column, the column was deuterated with heavy ...

International Nuclear Information System (INIS)

PANDA is a large scale facility for investigating the long-term decay heat removal from the containment of a next generation of 'passive' Advanced Light Water Reactors (ALWR). PANDA was used to examine the long-term LOCA response of the Passive Containment Cooling System (PCCS) for the General Electric (GE) Simplified Boiling Water Reactor (SBWR). The first PANDA test series had the dual objectives of demonstrating the performance of the SBWR PCCS and extending the data base available for containment analysis code qualification. The test objectives also include the study of the effects of mixing and stratification of steam and noncondensible gases in the drywell (DW) and in the suppression chamber or wetwell (WW). Ten tests were conducted in the course of the PANDA SBWR Program. The tests demonstrated a favorable and robust overall PCCS performance under different conditions. The present paper focuses on the main phenomena ...

Energy Technology Data Exchange (ETDEWEB)

The US Environmental Protection Agency (EPA) conducted a cost-effectiveness (CE) analysis to estimate the incremental cost of complying with the proposed effluent limitation guidelines (ELGs) for the coastal oil and gas industry (EPA 1995a). EPA`s CE analysis calculates the pounds of each pollutant that would be removed if the chosen discharge option is selected. In 1993, EPA issued final ELGs for the offshore oil and gas industry and published an offshore CE analysis. The chemical characteristics of produced water from the offshore region are essentially the same as those of produced water from the coastal region. It was surprising, therefore, that EPA chose a much longer list of pollutants and generally stricter weighting factors for the coastal CE analysis. This report reviews the data, assumptions, and analyses used in EPA`s coastal CE analysis and identifies alternate data, assumptions, and analyses that could lead to ...

Energy Technology Data Exchange (ETDEWEB)

Biosorption is an important removal mechanism in treating hydrophobic toxic organics in biological reactors. Equilibrium sorption isotherms and sorption kinetics of 2,4-dichlorophenol on live and chemically inactive anaerobic granules were studied. A metabolic inhibitor was used to inactivate the biological activity of the biomass. Results showed that the difference in the biosorption of live and chemically inactive anaerobic granules is not significant. This would suggest that anaerobic biosorption is mainly a physical-chemical process and that metabolic-mediated diffusion in the process is negligible. 12 refs., 3 tabs., 7 figs.

International Nuclear Information System (INIS)

The author presents a new technique for production of yellow cake with double precipitation, thus solving a series of problems for precipitating uranium with traditional double precipitation. The new technique can not only remove ferric ions and sulfate radicals but also make solid-liquid separation easy, utilize effectively the sulfuric acid produced in ferric ions precipitation process, and increase uranium concentration of leaching liquor. To take it as producing yellow cake will save investment, simplify operation, and cut down the consumption of raw materials and energies. It is more competitive than ion-exchange or solvent extraction in the process of extracting-purifying and preparing yellow cake.

Science.gov (United States)

Rubber lining is used as a corrosion protection material in European flue gas desulfurization plants, for scrubbers, tanks, pipe systems, etc. Although these rubber linings can last more than 15 years, relining still is necessary. The difficulty of shutting down power station units requires that the time scale of this replacement be kept to a minimum. High-pressure water systems have proven successful as an efficient method for removal of the old lining. The working steps and time scale are demonstrated for one such relining case.

Energy Technology Data Exchange (ETDEWEB)

The removal of paraffinic bottom accumulations from refinery storage tanks represents an increasingly costly area of petroleum storage management. Microorganisms can be used to reduce paraffinic bottoms by increasing the solubility of bottom material and by increasing the wax-carrying capacity of carrier oil used in the cleaning process. The economic savings of such treatments are considerable. The process is also intrinsically safer than alternative methods, as it reduces and even eliminates the need for personnel to enter the tank during the cleaning process. Both laboratory and field sample analyses can be used to document changes in tank material during the treatment process. These changes include increases in volatile content and changes in wax distribution. Several case histories illustrating these physical and chemical changes are presented along with the economics of ...

Energy Technology Data Exchange (ETDEWEB)

Coal may be used to generate electrical energy by any of several processes, most of which involve combustion or gasification. Combustion in a coal-fired boiler and power generation using a steam- cycle is the conventional conversion method; however, total energy conversion efficiencies for this type of process are only slightly over 30{percent}. Integration of a gas-cycle in the process (combined cycle) may increase the total conversion efficiency to 40{percent}. Conversion processes based on gasification offer efficiencies above 50{percent}. H{sub 2}S is the predominant gaseous contaminant in raw coal gas. Problems arise due to the corrosive nature of H{sub 2}S on metal components contained in these cycles. Because of this, H{sub 2}S concentrations must be reduced to low levels corresponding to certain power applications. An advanced process for the separation of hydrogen sulfide ...

Energy Technology Data Exchange (ETDEWEB)

This study is one element of a larger engineering study effort by WHC to examine the feasibility of irradiated fuel and sludge consolidation in the KW Basin in response to TPA Milestone (target date) M-34-00-T03. The study concludes that up to 11,500 fuel storage canisters could be accommodated in the KW Basin with modifications. These modifications would include provisions for multi-tiered canister storage involving the fabrication and installation of new storage racks and installation of additional decay heat removal systems for control of basin water temperature. The ability of existing systems to control radionuclide concentrations in the basin water is examined. The study discusses requirements for spent nuclear fuel inventory given the proposed multi-tiered storage arrangement, the impact of the consolidated mass on the KW Basin structure, and criticality issues associated with multi-tiered storage.

British Library Electronic Table of Contents (United Kingdom)

This study highlights a methodology to detect the transplanting operation of wetland rice at a regional scale using SSM/I brightness temperature in frequencies like 19, 37 and 85 GHz with vertical polarization. A cloud removal algorithm was used to make weekly composites of the brightness temperature, which were used to estimate the soil wetness index (SWI). Flooding of rice fields with water for transplanting induces very high change in SWI due to contrasting dielectric constant of water (80) and soil (4). Different weather conditions and fractional wet area under the footprint of sensor affect SWI, hence absolute value of SWI was not adequate. Therefore, multi-year SWI anomaly was used to generate a threshold value of SWI change to detect when SWI change between two consecutive weeks was...

Energy Technology Data Exchange (ETDEWEB)

Tests on a sample of trench water from the Maxey Flats burial ground effectively demonstrated the new Reverse Osmosis Pilot Plant. The effluent from the 50% salt-rejection membrane was decontaminated well enough with the exception of tritium to be discharged to the environment. The performance of the 97% salt-rejection membrane was superior to that of the 50% membrane. A breakthrough and capacity experiment was conducted with Durasil 10 on a simulated Three Mile Island solution. The maximum decontamination factor was extrapolated to be 10/sup 6/, which would reduce the cesium level of TMI water to below the discard limit. Capacity (1/DF = 0.5) was reached at 1260 column volumes. Several adsorbents were tested in the engineering columns for decontamination of cesium-bearing solutions. Under the conditions of the experiment, these adsorbents were ineffective in removing cesium from the solution.

Energy Technology Data Exchange (ETDEWEB)

This study report presents the shutdown chemistry of PWR primary system to reduce and remove the radioactive corrosion products which were deposited on the nuclear fuel rods surface and the outside of core like steam generator channel head, RCS pipings etc. The major research results are the follows ; the deposition radioactive mechanism of corrosion products, the radiochemical composition, the condition of coolant chemistry to promote the dissolution of radioactive cobalt and nickel ferrite, the control method of dissolved hydrogen concentration in the coolant by the mechanical and chemical methods. The another part of study is to investigate the removal characteristics of corrosion product ions and particles by the demineralization system to suggest the method which the system could be operate effectively in shut-down purification period. (author). 19 refs., 25 figs., 48 tabs.

British Library Electronic Table of Contents (United Kingdom)

To elucidate biosorption mechanism and removal efficiency of plant residues as a biosorbent to abate polycyclic aromatic hydrocarbons (PAHs) in wastewater, sorption of PAHs onto wood chips (WC), ryegrass roots (RR), orange peels (OP), bamboo leaves (BL), and pine needles (PN) were investigated. The structural characterization of the biosorbents was analyzed by elemental composition, BET-N2 surface area, and Fourier transform infrared spectroscopy. PAHs sorption to the selected biosorbents were compared and correlated with their structures. Biosorption isotherms fit well with Freundlich equation and the mechanism was dominated by partition process. The magnitude of phenanthrene partition coefficients (Kd) followed the order of PN>BL>OP>RR>WC, ranged from 2484+/-24.24 to 5306+/-92.49L/kg. Ex...

British Library Electronic Table of Contents (United Kingdom)

Purpose - To study the optimization of a randomized control problem in an M/G/1 queue in which a removable and unreliable server may provide two phases of heterogeneous service to arriving customers. Design/methodology/approach - Arriving customers follow a Poisson process and require the first essential service (FES). As soon as FES of a customer is completed, the customer may leave the system or opt for the second optional service (SOS). The service times of FES channel and SOS channel are assumed to be general distribution functions. The server requires a startup time with random length before starting service. When the server is working, he may meet unpredictable breakdowns but is immediately repaired. The inter-breakdown time and repair time of the removable server are exponentially r...

Energy Technology Data Exchange (ETDEWEB)

In order to investigate pitting corrosion of copper coiled tubes for air conditioning systems with an open heat storage water tank, the effect of carbon films on the inner surface of copper tubes and fine corrosion-product particles in water as environmental corrosion factor on pitting corrosion was studied by field test under real environmental conditions. As a result, pitting corrosion of copper tubes was caused by synergistic effect of fine corrosion-product particles in water and carbon films. Generation of pitting corrosion was derived from deposition of the films and particles, while considerable growth of pitting corrosion was dependent on the particles. Time variation of spontaneous electrode potential also showed the effect of the film and particle. Pitting corrosion potential was estimated to be nearly 100mV vs. SCE. The following measures against pitting corrosion were considered to be effective: (1) ...

Energy Technology Data Exchange (ETDEWEB)

The exergy method is used to compare different production processes and various methods for emission abatement with respect to their overall environmental impact. Some ammonium nitrate production processes are studied as examples, because the pollutants (ammonia and ammonium nitrate), emitted from these processes into the air and/or into the water, are really a feedstock and a product from the production process. Therefore, the essential result of the waste flows treatment is the recycling of the pollutants (ammonia and ammonium nitrate) back into the production process, decreasing simultaneously the exergy input and cumulative exergy consumption. (author)

Energy Technology Data Exchange (ETDEWEB)

A new industrial process allowing to reach very high cooling rates in the cooling section after soaking of a continuous annealing line for steel sheets is presented. This process constitutes the successful conclusion of a long term research programme, jointly carried out at CRM and Arcelor Cockerill-Sambre for three years, including laboratory experiments, pilot scale trials and several industrial campaigns. It is running on from developments performed in the framework of the HOWAQ (Hot Water Quench) process. The process successively combines a moderate cooling step (600 deg C/s for 0.8 mm thick strips), in boiling water, and a faster cooling step (above 700 deg C/s), by impinging turbulent cold water in a box. Its main features are simplicity, resulting from advanced developments, soundness, flexibility and cooling homogeneity. As treated ...

Energy Technology Data Exchange (ETDEWEB)

Crystalline MnMoO{sub 4} was synthesized using a conventional solid reaction method and investigated for its physical and electrochemical properties as an anode material for Li secondary battery. The reversible amount of Li insertion/removal of MnMoO{sub 4} anode during the first cycle was about 800 mA h/g, accompanied by irreversible structural transformation into amorphous material. The amorphization during the first Li insertion was investigated by structural analysis using XRD of electrode. The charge compensation during Li insertion/removal was examined by measurement of X-ray Absorption Near Edge Structure (XANES) spectroscopy. Despite its irreversible structural transformation to amorphous during the first lithiation, subsequent cycles showed a reasonable cyclability. This paper presents the electrochemical properties of MnMoO{sub 4} and discusses the mechanism underlying the Li insertion/removal ...

Energy Technology Data Exchange (ETDEWEB)

Inventories of emissions and removals of greenhouse gases will be used under the United Nations Framework Convention on Climate Change and the Kyoto Protocol to demonstrate compliance with obligations. During the negotiation process of the Kyoto Protocol it has been a concern that uptake of carbon in forest sinks can be difficult to verify. The reason for large uncertainties are high temporal and spatial variability and lack of representative estimation parameters. Additional uncertainties will be a consequence of definitions made in the Kyoto Protocol reporting. In the Nordic countries the national forest inventories will be very useful to estimate changes in carbon stocks. The main uncertainty lies in the conversion from changes in tradable timber to changes in total carbon biomass. The uncertainties in the emissions of the non-CO{sub 2} carbon from forest soils are particularly high. On the other hand the removals ...

International Nuclear Information System (INIS)

A pyrochemical process has been introduced and utilized so that the transmutation of spent PWR fuel in PEACER can produce mainly low and intermediate level waste for near surface disposal. Major radioactive nuclides from PEACER pyroprocessing are composed of TRU and LLFP. In this study, the requirement for the final waste from PEACER is evaluated based on the methodology for establishment of waste acceptance criteria. Also, sensitivity analysis for several input parameters is conducted in order to determine acceptable decontamination factor (DF) and LLFP removal efficiency and to find out input parameter that extremely have an effect on DF. As a result of the study, LLFP removal efficiency, especially Sr-90 and Tc-99, is proved to be a major nuclide which contributes to annual dose by human intrusion scenario rather than TRU DF. More than 98.5% of LLFP have to be removed to meet below dose constraint ...

Energy Technology Data Exchange (ETDEWEB)

In the past three years, we followed the work plan as we suggested in the proposal and made every efforts to fulfill the project objectives. Based on our large amount of creative and productive work, including both of experimental and theoretic aspects, we received important technical breakthrough on naphthenic acid removal process and obtained deep insight on catalytic decarboxylation chemistry. In detail, we established an integrated methodology to serve for all of the experimental and theoretical work. Our experimental investigation results in discovery of four type effective catalysts to the reaction of decarboxylation of model carboxylic acid compounds. The adsorption experiment revealed the effectiveness of several solid materials to naphthenic acid adsorption and acidity reduction of crude oil, which can be either natural minerals or synthesized materials. The test with crude oil also received promising results, which can be potentially ...

International Nuclear Information System (INIS)

Environmental research related to uranium tailings is being carried out within the Mining Research Laboratories and Mineral Sciences Laboratories of CANMET, EMR. Field-related research on uranium tailings has been conducted at Elliot Lake for over five years. Much of the work has been focused on a program to rehabilitate pyritic tailings. This has resulted in developing a practicable technology for growing vegetation on such wastes. Limitations have been small size of the test-plots and the relatively short period during which experiments have been carried out. A research program aimed at identifying and reducing acidic and radioactive effluents is also underway at Elliot Lake. These liquid effluents have been identified as the most serious threat to the environment. Research at the Mineral Sciences Laboratories and its predecessor divisions relating to the processing of uranium and thorium ores is outlined. A process has been developed for ...

International Nuclear Information System (INIS)

BIBRA "t"r"a"d"e"m"a"r"k, is the new bio-technological method developed in Gundremmingen for treating radioactive waste water, using bacteria in a process analogous to the long-established principle of communal sewage treatment plants. The method exploits the behaviour of the micro-organisms found there, to establish optimum adaptation of their population for decomposing the typical pollutants found in this washing water. This procedure is particularly suitable for nuclear engineering plants, because in such plants the waste water composition changes little so that the bacteria can achieve optimum adaptation to this waste water. The organic ingredients of the washing media are decomposed by introducing air. The advantage of the procedure is not only the significant reduction of the amount of waste material, but also enhanced efficiency of the cleaning process. ...