There is a need to reduce air pollutantemissions in some U.S. urban regions to meet federal and state air quality guidelines. Opportunities exist for reducing pollutantemissions from natural gas appliances in the residential sector. A cost-benefit analysis on various pollutant-reducing strategies is needed to evaluate these opportunities. The effectiveness of these pollutant-reducing strategies (e.g., low-emission burners, energy conservation) can then be ranked among themselves and compared with other pollutant-reducing strategies available for the region. A key step towards conducting a cost-benefit analysis is to collect information on pollutantemissions from existing residential natural gas appliances. An extensive literature search was conducted to collect data on ...
This paper investigates the relationship between environmental pollution and economic growth in China based on the environmental Kuznets curve hypothesis, using Chinese provincial data over 1985?2005. Waste gas, waste water and solid wastes are used as environmental indicators and GDP is used as the economic indicator. It is found by panel cointegration test that there is a long-run cointegrating relationship between the per capita emission of three pollutants and the per capita GDP. According to comparisons with the dynamic OLS estimator and the Within OLS estimator, we find that panel cointegration estimation is preferable for all pollutants except for solid wastes. The results also show that all three pollutants are inverse U-shaped, and waterpollution has been improved earlier than ga...
This report focuses on air quality at the Nevada Test Site (NTS) for 1994. A general description of the effluent sources are presented. Each potential source of NTS emissions was characterized by one of the following: (1) by monitoring methods and procedures previously developed at NTS; (2) by a yearly radionuclide inventory of the source, assuming that volatile radionuclides are released to the environment; (3) by the measurement of tritiated water concentration in liquid effluents discharged to containment ponds and assuming all the effluent evaporates over the course of the year to become an air emission; or (4) by using a combination of environmental measurements and CAP88-PC to calculate emissions. Appendices A through J describe the methods used to determine the emissions from the sources. These National Emission Standards for Hazardous Air ...
This study revisits the environmental Kuznets curve (EKC) hypothesis for waterpollution by using a recent dynamic technique, which is the generalized method of moments (GMM) approach, for a board sample of 97 countries during the period 1980-2001. On a global scale, as we cannot obtain the EKC relationship between real income and biological oxygen demand (BOD) emissions, this paper further classifies these countries into four regional groups - Africa, Asia and Oceania, America, and Europe - to explore whether the different regions have different ECK relationships. The empirical results show evidence of the inverted U-shaped EKC relationships' existence in America and Europe, but not in Africa and Asia and Oceania. Thus, the regional difference of EKC for waterpollution is supported. Furthermore, the estimated turning points are, approximately, US$13,956 and US$38,221 for ...
This study revisits the environmental Kuznets curve (EKC) hypothesis for waterpollution by using a recent dynamic technique, which is the generalized method of moments (GMM) approach, for a board sample of 97 countries during the period 1980-2001. On a global scale, as we cannot obtain the EKC relationship between real income and biological oxygen demand (BOD) emissions, this paper further classifies these countries into four regional groups - Africa, Asia and Oceania, America, and Europe - to explore whether the different regions have different ECK relationships. The empirical results show evidence of the inverted U-shaped EKC relationships' existence in America and Europe, but not in Africa and Asia and Oceania. Thus, the regional difference of EKC for waterpollution is supported. Furthermore, the estimated turning points are, approximately, US$13,956 and US$38,221 for America ...
This study revisits the environmental Kuznets curve (EKC) hypothesis for waterpollution by using a recent dynamic technique, which is the generalized method of moments (GMM) approach, for a board sample of 97 countries during the period 1980-2001. On a global scale, as we cannot obtain the EKC relationship between real income and biological oxygen demand (BOD) emissions, this paper further classifies these countries into four regional groups - Africa, Asia and Oceania, America, and Europe - to explore whether the different regions have different ECK relationships. The empirical results show evidence of the inverted U-shaped EKC relationships' existence in America and Europe, but not in Africa and Asia and Oceania. Thus, the regional difference of EKC for waterpollution is supported. Furthermore, the estimated turning points are, approximately, US$13,956 and US$38,221 for ...
Deregulation of the electric power industry in Alberta holds the prospect of providing greater choice for customers. One such option will be `green power` which is provided by renewable energy technologies. The energy produced would be without environmental impacts such as air emissions, waterpollution, flooding, thermal emissions or waste by-products. Wind power, small scale hydro power, photovoltaics and biomass technologies have been termed as `green power`. The choices that customers make will not be focused on price alone. Market forces are emerging to demand reduction in emissions which will result in a market for `green energy` products and facilitate achieving goals for a sustainable future.
The exergy method is used to compare different production processes and various methods for emission abatement with respect to their overall environmental impact. Some ammonium nitrate production processes are studied as examples, because the pollutants (ammonia and ammonium nitrate), emitted from these processes into the air and/or into the water, are really a feedstock and a product from the production process. Therefore, the essential result of the waste flows treatment is the recycling of the pollutants (ammonia and ammonium nitrate) back into the production process, decreasing simultaneously the exergy input and cumulative exergy consumption. (author)
Air pollution abatement measures are not an end in themselves, and undesirable side effects should be taken into account. The proposed emission index takes into account the total emissions caused by a technical project as well as the effects of the individual pollutants.
This book is mainly a comparison of the cost of pollution with the cost of environmental protection. As to the causes of pollution, a difference is made between pollutants that accumulate and pollutants that do not accumulate. Because of pollutant accumulation it is necessary to carry out both subsequent pollution abatement measures and to take preventive action which helps to avoid pollutantemission. Growth models serve to substantiate why such preventive action is both ecologically and economically useful as a rule. Finally the study makes a comparison between some tools of environmental protection. It stresses in particular that, if a duty on emissions is levied, the polluter has to bear all the cost of the pollution, while at the same time the quality of ...
Maps transformed so as to have constant density of residential population were used to analyze the spatial distribution of disease in three specific areas. Each area had received recent attention because of suspected environmental pollution. The area adjacent to the Rocky Flats Facility (CO) was examined to identify any association between possible plutonium releases and increases in lung cancer or leukemia incidence. The industrial area of northern Contra Costa County (CA) was studied to explore a relationship between petrochemical industrial emissions and histologic-specific lung cancers. Finally, a suspected increase in the risk of congenital cardiac defects possibly related to pollution of the Santa Clara County (CA) water supply was investigated. No evidence of elevated risk of disease was found to be associated with either the Rocky Flats Facility or the polluted ...
The document presents an overview on atmospheric pollution in Lebanon, with an analysis of sources of pollution, their impact on local and global environment and their control.Local causes of pollution are mainly: -Thermal power plants of electric power production which produce 75% SO_2 emission and 60% dust - Industries, especially cement industry - Land transportation which produces 70% NOX emission and 50% CO_2 A description of air pollution caused by these three sectors is revealed. Pollutants derived from fuel combustion are analyzed. It is estimated that in 2010, Co_2 emission will reach 5204450 tons, SO_2 emission will be 136470 tons, NOX emissions 96870 and dust estimated to 4130 tons. CFC consumption and measures of control according to Montreal Protocol are described. ...
The effect of liquefied natural gas on pollutantemissions was evaluated experimentally with used and new appliances in the laboratory and with appliances installed in residences, targeting information gaps from previous studies. Burner selection targeted available technologies that are projected to comprise the majority of installed appliances over the next decade. Experiments were conducted on 13 cooktop sets, 12 ovens, 5 broiler burners, 5 storage water heaters, 4 forced air furnaces, 1 wall furnace, and 6 tankless water heaters. Air-free concentrations and fuel-based emission factors were determined for carbon monoxide, nitrogen oxides, nitrogen dioxide, and the number of (predominantly ultrafine) particles over complete burns?including transient effects (device warm-up and intermittent firing of burners) following ignition--and during more stable end-of-burn conditions. ...
Survey report: The Petroleum Association for the Conservation of the Canadian Environment is an organization of petroleum refiners that works closely with the Canadian government to set realistic air pollution control standards for refinery emissions. To date, the refiners have made a substantial investment in pollution abatement equipment. As a result, there have been no major pollution incidents traceable to refinery emissions. In the future, it will be essential that refiners continue to invest in air pollution abatement measures and continue to cooperate with the government in setting achievable pollution control standards. (1 photo, 1 table)
A numerical technique is developed for estimating water quality violation frequencies due to pollutant discharges from urban areas during combined sewer overflow events. The first four moments of in-stream pollutant concentration are found by integrating a pollutant loading - wat...
The paper reports a work-in-progress outlook of a R and D project aimed at developing an advanced boiler for the combustion of virgin and exhaust olive husks at small scale. Fluidized bed technology has been preferred because of its well known advantages that include large thermal inertia, high combustion efficiency, low NOx emissions and considerable heat transfer rate. A 100 kW atmospheric bubbling fluidized bed combustor has been designed and built. The facility is equipped with devices for continuous fuel feeding as well as heat extraction from the bed region. Measurements of temperature and gas concentrations are obtained by using thermocouples and gas-analyzer. Steady state tests of combustion were carried out at typical fluidized bed combustion temperatures. Tests proved that not only exhaust olive husks but also the virgin ones - with a water content larger than 50% by mass - can be reliably fed onto the fluidized bed. Further, they ...
The current situation in the development of nuclear power in the world and in Czechoslovakia is briefly outlined and the possibilities are discussed of alternative energy resources. The environmental impact is described of conventional power plants firing coal; sulphur and nitrogen oxides are mentioned and their environmental impacts shown. Their quantities and the quantities of other gaseous, liquid and soid wastes produced by coal power plants are given. Annual estimates are presented of radioactive material emissions; trace amount emissions of toxic metals and their ecological risks are shown. Concern over the increasing concentration of CO_2 in the atmosphere is voiced. For nuclear power plants, the amount of radionuclides in stack emission and of those released into water flows is tabulated. Their effect on the aqueous ecosystem is characterized as is thermal pollution of ...
In the prevention of atmospheric pollution by sulfur dioxide emissions from acid absorbers in contact process sulfuric acid plants in which the unconverted SO/sub 2/ is accumulated by adsorption in a zeolite adsorbent bed and desorbed back into the acid production system, it is found that ambient moist air, after partial dehydration in an acid scrubber is suitably used both to cool down and hot purge desorb the zeolite beds. In addition the pure water derived from the ambient air is advantageously used in the acid-making system.
The production of atmospheric pollutants in combustion processes depends on plant characteristic, combustion conditions and fuel quality. The influence of fuel quality on the emission of sulphur oxides, nitrogen oxides, carbon monoxide, dust and carbon dioxide and on the emission of some toxic pollutants, such as heavy metals and polycyclic aromatic hydrocarbons, is analysed. The comparison between the emission limits, fixed by the Italian legislation, and the uncontrolled pollutantemissions, produced by fossil fuel combustion in power plants and industrial use, shows that, in order to comply with the limits, a reduction of pollutantemissions is required through the use of abatement systems and cleaner fuels where natural gas has a primary role. The use of cleaner fuels is particularly required in ...
Pollutantemissions due to fossil fuel and biomass energy utilization in Turkey have been estimated. Standard emission factors were used for estimating the levels of particulate matter, sulfur oxides, nitrogen oxides, carbon monoxide, volatile organic compounds, and aldehydes. The results are presented for different fuels and energy-consuming sectors for the reference year 1987. Total Turkish emissions vs energy consumption are presented for every fifth year since. 1960. (author).
The article is an overview on atmospheric pollution in Lebanon. It presents an analysis of sources of pollution in the country and their impacts on local and global environment and describes their control. Air pollution is mainly due to the industrial, electrical and transportation sectors. Pollutants from fuel combustion are analyzed. It is estimated that in 2010, CO_2 emissions will reach 5987250 tons, SO_2 emissions is estimated to be 182950 tons, Nox to 105180 and dusts to 4965 tons. CFC consumption and measures of control according to Montreal protocol are described. Consumption of primary energy, consumption of petroleum products, quantity of petroleum in refineries and production of cement in Lebanon are also presented in tables
The main pollutants from marine diesel engines are oxides of nitrogen (NOx), sulfur oxides (SOx) and particulates (soot). However, the proposed marine diesel engine emission regulations will primarily focus on the levels of NOx and SOx. In the future, once the proposed regulations are met, the limits and levels of other emissions will come under increasing scrutiny, such as particulates, hydrocarbons and carbon monoxide. Regardless of the type of pollutant, there are generally two classes of emission control: (1) techniques that reduce the amount of pollutant formed in the combustion process, or (2) prevent the pollutants from reaching the atmosphere. Unfortunately, some of these control techniques will not be able to meet the incoming regulations. Therefore, this paper identifies the diesel engine emissions of concern, ...
This paper summarizes substance flow analyses for four organic substances in the City of Stockholm, Sweden: diethylhexyl phthalate (DEHP), alkylphenolethoxylates (APEO), polybrominated diphenylethers (PBDE) and chlorinated paraffins (CP). The results indicate that the stocks of APEO, PBDE and CP all are approximately 200-250 tonnes, whereas the DEHP stock is two orders of magnitude larger. Emissions can be linked to imported consumer goods such as electronics (PBDE) and textiles (APEO), and to construction materials (DEHP, CP). For several of the substances considerable amounts remain in the technosphere for a long time, even after use of the substance in new products has been eliminated. For example, the use of DEHP as plasticizer for PVC plastics in cables and floorings has more or less been phased-out, but still these applications make up a stock of some 20,000 tonnes (85% of the total DEHP stock in Stockholm) and emit 28 tonnes of DEHP annually (93% of overall ...
The 7 conference papers in Vol. 9 review the implications of environmental problems and discuss the consequences of pollution abatement measures, especially for the economics of energy conversion. The future developments of pollutantemissions are assessed.
Much as it is accepted for pollution control reasons air pollution abatement still is the subject of heated debates. Pollutantemissions can considerably be reduced with the help of electric power supplies. In order not to prejudice electric power users tariffs have to be adapted to the prices of other energy sources available on the market. There is a general need for energy conservation, resource conservation and the reduction of carbon dioxide emissions. Thermal insulation is among the remedial measures. Fundamental air pollution abatement measures will have to be avoiding smog warnings which are known to considerably interfere with both economic and private activities.
Air pollution abatement measures are being intensified at the moment: Power plants and district heating systems are being retrofitted with high-efficiency desulphurisation and NO/sub 2/ reduction systems, the 3rd amendment of the Clean Air Technical Guide sets more rigid emission limits, and unleaded petrol and catalysts will significantly reduce car exhaust emissions. The author presents pollutant balances from 1966 to 1982 to contradict the popular notion that pollutant emitters formerly failed to take preventive measures.
The paper discusses a number of recent studies investigating into the energy conservation and environmental impacts of electric heating systems (off-peak storage systems). In future, i.e. in and after 1993, off-peak storage systems will be evaluated through comparative analyses of oil-fired heating systems, pollutantemission analyses, the eventual success of pollution abatement measures designed for power plant emissions to keep within the legal limiting values, and the possible abandonment of pollution abatement measures abroad. Opposing the electric heating studies submitted by the electric power industry the author refutes their favourable results referring to the palliative selection of inadequate or vague parameters. Assuming average power plant pollutantemissions of 180 mg/standard/sup 3/ the nitrogen oxide ...
The European Commission recently has adopted a new European Strategy for Environment and Health focusing on the growing concern over the adverse health effects caused by environmental pollution. Based on the results of various studies carried out in recent years polychlorinated dioxins and furans (PCDD/Fs) and PCBs are playing an important role in this strategy. In view of the enlargement of the European Union (EU) to include Candidate Countries (CCs) the Commission stressed the need to involve the Candidate Countries from an early stage on in the development of such a strategy. Thus two studies have been commissioned which are particularly directed to provide a) an overview on environmental levels and human exposure of dioxins and PCBs and b) an harmonised PCDD/F emission inventory for the target matrices air, water and land The latter study, entitled ''Dioxin Emissions in Candidate ...
A hydrogen peroxide injection system was designed and installed in the stack of a 5,274 million J/hr industrial pilot plant scale combustion chamber using natural gas as fuel. The concentration of peroxide in the gas stream was precisely controlled by continuous injection using an electromagnetic dosage pump, the liquid 50% peroxide solution was finely dispersed into the gases by a water cooled custom designed delivery system with a spray nozzle at the tip. Residence times between 0.1 and 1.8 seconds and concentrations of H{sub 2}O{sub 2} between 280 ppm and 4,000 ppm were used during the test runs. CEMS for total hydrocarbons, carbon monoxide, nitrogen oxides, as well as an ultrasonic gas flow monitor were used to measure the effect of hydrogen peroxide in reducing the emissions of these pollutants. Destruction removal efficiencies between 25% and 100% were observed for hydrocarbons, and concentrations of CO, as well as ...
In 1990, 176 million tonnes (mt) of air-traffic fuel was burned, which produced about 550 mt CO{sub 2}, 220 mt water, 3.5 mt NO{sub x} amd 0.18 mt SO{sub 2}. NO{sub x} emissions from air traffic may, by increasing ozone concentrations, be responsible for about 8% of global greenhouse warming. In the stratosphere NO{sub x} from aircraft is partly responsible for ozone depletion. With present technology 500 aircraft in the stratosphere would cause global ozone losses of 20%. Water vapour added by aircraft also contributes to global warming. In the form of ice crystals between 8 to 13 km above sea level, it acts as cirrus clouds. Probably the least damaging cruising altitude for aircraft is 9 km above sea level. Fuel consumption by aircraft is increasing. Air pollution abatement measures include substituting hydrogen fuel for kerosene, developing engines that emit less NO{sub x} and the introduction of ...
The emission of air pollutants from road vehicles is the most significant source of air pollution in towns. The chemical composition of these pollutive substances is dependent on the fuel, the type of vehicle and the character of the traffic system. The pollution concentration was measured, (nitrogen oxides and carbon monoxide) in relation to each type of vehicle, in four streets in the Copenhagen area. The system of measurement used was the ''Operational Street Pollution Model'' (OSPM). Results are presented in the form of tables and charts. (AB) 11 refs.
This paper investigates the relationship between economic growth and pollutantemissions for a small and open developing country, Tunisia, during the period 1961-2004. The investigation is made on the basis of the environmental Kuznets curve hypothesis, using time series data and cointegration analysis. Carbon dioxide (CO{sub 2}) and sulfur dioxide (SO{sub 2}) are used as the environmental indicators, and GDP as the economic indicator. Our results show that there is a long-run cointegrating relationship between the per capita emissions of two pollutants and the per capita GDP. An inverted U relationship between SO{sub 2} emissions and GDP has been found, with income turning point approximately equals to $1200 (constant 2000 prices) or to $3700 (in PPP, constant 2000 prices). However, a monotonically increasing relationship with GDP is found more appropriate for CO{sub 2} ...
This paper investigates the relationship between economic growth and pollutantemissions for a small and open developing country, Tunisia, during the period 1961-2004. The investigation is made on the basis of the environmental Kuznets curve hypothesis, using time series data and cointegration analysis. Carbon dioxide (CO2) and sulfur dioxide (SO2) are used as the environmental indicators, and GDP as the economic indicator. Our results show that there is a long-run cointegrating relationship between the per capita emissions of two pollutants and the per capita GDP. An inverted U relationship between SO2 emissions and GDP has been found, with income turning point approximately equals to $1200 (constant 2000 prices) or to $3700 (in PPP, constant 2000 prices). However, a monotonically increasing relationship with GDP is found more appropriate for CO2 emissions. ...
This paper investigates the relationship between economic growth and pollutantemissions for a small and open developing country, Tunisia, during the period 1961-2004. The investigation is made on the basis of the environmental Kuznets curve hypothesis, using time series data and cointegration analysis. Carbon dioxide (CO{sub 2}) and sulfur dioxide (SO{sub 2}) are used as the environmental indicators, and GDP as the economic indicator. Our results show that there is a long-run cointegrating relationship between the per capita emissions of two pollutants and the per capita GDP. An inverted U relationship between SO{sub 2} emissions and GDP has been found, with income turning point approximately equals to 1200 (constant 2000 prices) or to 3700 (in PPP, constant 2000 prices). However, a monotonically increasing relationship with GDP is found more appropriate for CO{sub 2} ...
The production of and emission factors for the air-polluting matters sulfur dioxide, nitrogen oxides, carbon monoxide, hydrocarbons (esp. benz(a)pyrene), aldehyde and soot with regard to natural gas, excluding process furnaces, are dealt with. The comparison with other fuels indicates that only as to nitrogen oxides and carbon monoxide are emission factors equal in order of magnitude. As a summary measure of all air-polluting matters the emission index as proposed already in 1972 is applied. It shows emissions with single-room furnaces for heating oil EL to be six times as high as with natural gas; with black-coal briquettes the factor is at least 33, with wood chimneys about 200.
Proposed features of the competitive electricity market in Ontario were reviewed. The speaker predicted that demand for renewable energy in Ontario`s competitive electricity market will be affected by green power, emissions trading, labelling, and renewables portfolio standard. Under current regulations retailers can charge customers a premium for purchasing electricity generated by `green` sources. The existing limits on emissions of sulphur dioxide, nitrogen oxides and carbon dioxides will remain in place, but an emissions cap and trading program for all Ontario-based generation is an option to consider. Ontario`s Market Design Committee (MDC) has recommended the implementation of emissions trading for electricity-related air pollutants for all generators located in Ontario. The complex mechanics of emission trading are explained. The MDC recommendation of the ...
The use of concentrated solar energy for co-producing Zn and synthesis gas from Zn O and natural gas upgrades the calorific value of the initial reactants by 39% and, when compared to the traditional carbothermic reduction of Zn O, has the potential of reducing CO{sub 2} emissions by up to 78%. An economic assessment for an industrial thermochemical plant, 30 to 51 MW solar input, indicates that the cost of solar production of zinc ranges between 89-133 $/t (excluding the cost of Zn O feed and credit for pollution abatement), and thus might be competitive with conventional fossil-fuel-based processes at current fuel prices. The cost of solar H{sub 2}, produced by splitting water with zinc, is estimated to be in the range 0.10-0.14 $/kWh, and it is a favorable long term prospect once the cost of energy will account for the environmental externalities from fossil fuel burning such as the costs for CO{sub 2} mitigation and ...
Proper estimation of shipping emissions is essential for an impact assessment of shipping on air quality and health in port cities and coastal regions. In the Netherlands shipping is an important source of particulate matter. This report provides an internationally accessible and transparent summary and description of the methodologies used in the Netherlands Pollutant Release and Transfer Register (PRTR) to estimate PM emissions from shipping, including recently implemented updates.
Lebanon has imported in 1996 5000 Kt of carburants causing about 80 Kt of SO_x; 40 Kt of NO_x; 3 Kt of dusts and 3.5 million tons of CO_2. The atmospheric pollution in Lebanon is due to three main sources: - Thermal central of electric production - Industries (cement) - Transportation sector The document describes in tables: the inventory of pollutants and pollutantemissions in 1993 and 2010; industrial and heating gas oil; liquified petroleum gas commercial propane; fuel oil for EDL; consumption of energy in 1996; sectorial distribution of pollutants PPM; emissions of CO_2 per tons per habitant in 1993; consumption in 1993 broken down by use and application. Finally, three projects concerning public transportation were presented
The first part of the study goes into the determination of efficient strategies for the reduction of air pollutants. The developed method is not only derived theoretically but is tested with the concrete example of emissions sources of a German state. The second part goes into the question what the government can do in order to attain that air pollution abatement measures recognized as being efficient will be put into practice. As market economy mechanisms have advantages over central state planning in the allocation of economic resources the question arises if not also for environmental protection market economy tools may contribute to an improvement of the efficiency of air pollution abatement. Therefore the suitability of different tools of environmental policy for the realization of efficient air pollution abatement is investigated and evaluated. This is again not done ...
Lectures were held on forest and wood management, the forest as an energy source and the emission problem of wood combustion, future emission limitating regulations for wood firing, influence of firing technique on air pollution abatement and constructive and operational air pollution abatement measures with manually and continuously fuelled furnaces.
There is renewed interest in the development of natural gas vehicles in response to the challenge to reduce urban air pollution and consumption of petroleum. The natural gas/diesel dual fuel engine is one way to apply natural gas to the conventional diesel engine. Dual fuel engines operating on natural gas and diesel emit less nitrogen oxides, and less carbon soot to the air compared to conventional diesel engines. The problem is that at light loads, fuel efficiency is reduced and emissions of hydrocarbons and carbon monoxide are increased. This thesis focused on control methods for emissions of hydrocarbons and carbon monoxide in the dual fuel engine at light loads. This was done by developing a reverse flow catalytic converter to complement dual fuel engine exhaust characteristics. Experimental measurements and numerical simulations of reverse flow catalytic converters were conducted. Reverse flow creates a high reactor ...
This paper examines how robust economic, political, and demographic variables are related to water and air pollution. Employing Bayesian Averaging of Classical Estimates (BACE) for a cross section of 47 countries, 34 variables and 3 proxies for air and waterpollution over a period from 1980 to 2000 we confirm the environmental Kuznets curve hypothesis and highlight the relevance of variables that are not directly related to production.
Contents of this report are under the following topical sections: Legal Authority; Summary and Scope; Data Collection Activities; Industry Description; Industry Subcategorization; Water Use and Wastewater Characterization; Pollutants Selected for Regulation; Pollution Prevention and Wastewater Treatment Technologies; Development of Control and Treatment Options; Costs of Technology Bases for Regulations; Pollutant Reduction Estimates; Non-Water Quality Impacts; Implementation of Proposed Effluent Limitation Guidelines and Standards; Analytical Methods; and Glossary.
The measurement of air pollutants is no more sufficient. It is necessary to assess the risk induced by air pollution, and then to put in place actions to reduce it. The air quality monitoring takes into account different pollutants: nitrogen oxides, carbon monoxide, particulates for the traffic; sulfur dioxide and particulates for use of fuel or coal or chemical transformations in air; ozone and nitrogen dioxide from hydrocarbon and nitrogen oxides emissions; the use of simulation methods allow to calculate the concentrations levels for these pollutants taken as indicators. (N.C.)
Progress reports on the European Research Centre for Air Pollution Control Measures project are presented. Topics covered were: assessment and analysis of the impacts of airborne pollutants on forest trees, and distinction from other potential causes of recent forest dieback; research into atmospheric dispersion, conversion and deposition of airborne pollutants; development and optimization of industrial technical processes to reduce or avoid emissions; and providing instruments and making recommendations to the industrial and political sectors.
The release of any potential radioactive pollutant to the environment during routine operation of a Nuclear Power Plant should be the subject of appropriate controls and assessments. It is impossible to monitor directly the dose contribution of normal releases because the environmental radioactivity levels are very small but source monitoring provides a means of assessing the radiation exposure of population groups, critical groups and individual members of the public. Derived emissions limits ( DELs ) are used to quantify the relationship between releases of radioactivity and doses to public - critical groups. CNE Cernavoda DELs are based on a pathway analysis conducted for Cernavoda site specific conditions and they were computed using a compartment transfer model. Annual air and wateremissions for the most significant radionuclides between 1997 and 2008 are presented in terms of doses and can be ...
Small-scale stoves, producing heat and hot water, are suited for domestic purposes. In order to optimise their efficiency when using lignocellulosic pellets, an important task is to do research on their real performance. The general behaviour depends on many operational factors (air flow and humidity, pressure, etc), dimension and pellet characteristics (moisture, size, raw material, density, friability, etc). In this paper, the first results and general performance of a 24 kW pellet fixed bed stove pilot plant are presented. The plant has been designed to study pellet combustion in the laboratory. The main targets are to reduce emissions of pollutants and to improve energy efficiency. Different situations can be simulated and tested due to its flexible design. Temperatures, pressures, flows and emissions are measured and analysed. An extensive study of different load conditions is presented through the ...
This report made for the Swiss Federal Office of Energy (SFOE) discusses the conception, planning and construction of an easy-to-operate pilot heating plant that uses chicken litter as its fuel. The plant, which is installed at a chicken farm in Boesingen, Switzerland, produces 250 - 350 kW and not only supplies heat for two chicken sheds and two households, but also provides energy for a drying plant in summer. The results of measurements made on emissions are discussed and, within the framework of an eco-balance analysis, comparisons are made between the direct use of the droppings as manure or as a fuel. The cost-effectiveness of the plant is examined and the influence of plant size and other factors discussed. Further, legal questions concerning the use of chicken litter as a fuel for heating installations are discussed; the use of the droppings as a fuel is not foreseen in the legislation concerning water protection and airborne ...
The bibliography contains selected abstracts of research reports covering studies dealing with waterpollution from estuarine and coastal development, the effects of this pollution, and its control. The reports are general in nature so as to be of interest to any coastal area. The topics include pollution as related to urbanization, government actions, coastal planning, natural resource development, and sewage and solid waste disposal. Specific biological and oceanographic studies have been excluded. (This updated bibliography contains 112 citations, 42 of which are new entries to the previous edition.)
Divergence between aircraft engine emission regulations proposed by EPA and ICAO is discussed. Every engine, upon entering service, requires a certificate as to its compliance with emission standards. It is shown that despite the large variability in the measurements, it is possible to devise a certification procedure requiring the testing of one engine only. Statistical modeling of such a test at the 5% significance level is described. Values of the parameter standard deviation/mean recommended as certification standards for various pollutants are given. Features of a rational certification scheme to be formulated are outlined.
Canada's environmental performance is compared to the 28 other nations in the Organization for Economic Cooperation and Development (OECD). Twenty-five environmental indicators in ten categories are examined. These are: air, water, energy, biodiversity, waste, climate change, ozone depletion, agriculture, transportation and miscellaneous. Results show Canada with the poorest environmental record of all OECD countries, except the United States. The statistical information, compiled from data verified and published by the OECD, shows Canada among the worst three countries on nine indicators (per capita GHG emissions, CO and VOCs emissions, water consumption, energy consumption, energy efficiency, volume of timber logged, generation of nuclear waste, and the highest amount of energy consumed per unit of GDP). Tracking Canada's energy performance over the past two decades reveals that the situation is ...
;Table of Contents: Legal authority; Summary of proposed regulations; Industry definition and waste streams; Industry description; Data and information gathering; Selection of pollutant parameters; Drilling wastes-characterization, control, and treatment technologies; Produced water-characterization, control, and treatment technologies; Miscellaneous waste-characterization, control, and treatment technologies; Cost and pollutant loading determination of drilling fluids and drill cuttings; Compliance cost and pollutant load determination of produced water; Compliance cost and pollutant load determination of well treatment, workover, and completion fluids; Cost and pollutant loading determination of deck drainage; Options selection-rationale and total costs; Pretreatment standards; Non-water quality environmental impacts ...
Activities of the Referenzlaboratorium Reinhaltung der Luft at Magdeburg as well as existing air pollution standards in the German Democratic Republic are reviewed. The laboratroy coordinates research and standardization in the field of industrial air pollution for the Ministry of Health. The standards provide orientation for emission control by state district health inspectorates. Emission limits (in g/m/sup 3/) which are international standards for 15 selected industries are listed. Emission limits (in g/m/sup 3/) of GDR standards, issued between 1971 and 1984 are also provided. They concern emission of brown coal dust from coal preparation plants, dust and chemical compound emission from metallurgical plants, dust emission from plants of the limestone and cement industry as well as from cupola furnace plants, boiler ...
The investigations showed that the new adsorber/catalyst composites are well suited for chemical degradation of persistent waterpollutants. Compared with alternative processes, the reaction selectivity and the consumption of oxidant are more favourable as the reaction now takes place on/inside the solid. The process, which was developed originally for purification of contaminated water, can be transferred to many other systems of materials. For example, it is expected that the soot emissions of diesel engines will be reduced significantly after efficient hydrogenation of the aromatics contained in the diesel engine on molybdenum-charged mesoporous composites. [German] Mit den vorliegenden Untersuchungen konnte ein erster Nachweis gefuehrt werden, dass die neu entwickelten Adsorber/Katalysator-Komposite fuer den chemischen Abbau persistenter Wasserschadstoffe geeignet sind. Im Vergleich zu alternativen ...
Synthetic detergents constitute one of the most important waterpollutants by contaminating the lakes and rivers through domestic and industrial use. Considerable information is now available for the adverse effects of detergents an aquatic fauna including fish, algae, and higher aquatic plants. Marked inhibition of germination in orchids and brinjals and of seedlings growth in raddish suggest that rapidly growing systems could be sensitive to detergent pollutedwater. The present study of the effect of linear alkyl benzene sulphonate on germination of the spores of a fern, Diplazium esculentum aims at the understanding of the effects of waterpollution on pteridophytes and the development of spore germination assay for phytoxicity evaluation.
Significant development of an oil shale industry has been projected over the next few decades. The nation's largest oil shale reserves exist in the Wyoming Basin and Colorado Plateau physiographic provinces. This study presents a brief description of the environmental setting and land-use pattern of the region, with a review of the major environmental issues associated with each proposed technology for extracting shale oil. Serious effects may be expected from the modification of very large land surfaces through open-pit mining and spent-shale disposal. The impacts include habitat destruction, potential species loss, and deterioration of surface and groundwater quality. In situ retorting of shale may result in major alterations of groundwater quantity, quality, and flow regimes. Mine dewatering from in situ retorting requires the disposal of large volumes of highly saline water, threatening the quality of subsurface and surface water ...
Policy makers are turning to market-based mechanisms to engender innovative ways of reducing polluting air emissions. As with any emerging market, environmental policies must be carefully crafted so that the institutions and incentives needed to form working markets are developed. Attention must be paid to creating avenues for communities and other 'non-moneyed' or unorganised interests to be involved in the new market processes. This paper proposes a strategy to create sustainable, community-based methods to reduce polluting air emissions within the context of market-based incentive programs. By enabling communities to effectively participate in environmental solutions, they will truly be able to 'think globally, act locally'. (author)
Provisions (a) NPDES field personnel shall be currently trained and certified in CPR and basic first-aid procedures. (b) NPDES field personnel shall be aware of the...
Water and soil samples from the area were therefore analyzed for their lead and zinc content. Computation of pollution statuses of lead and zinc revealed topsoil lead geoaccumulation indices of ?0.143 and ?0.069 and zinc geoaccumulation indices of 1.168 and 0.713 for Ishiagu and Uburu respectively. The pollution indices were determined to be 0.499 and 0.3564 for soil in Ishiagu and Uburu respectively and also 5.11 and 2.42 for water in Ishiagu and Uburu communities respectively. Water/soil concentration ratio were found to be 0.0018 and 0.0014 for lead in Ishiagu and Uburu respectively. On the other hand, the water/soil concentration ratio for zinc was computed to be 0.001 and 0.0008 for Ishiagu and Uburu respectively. These results seem to suggest that the pollution of the environment by ...
The document reports the results of a cost-effectiveness analysis of alternative waterpollution control regulations of the battery manufacturing industry. These regulations include effluent limitations and standards based on best practical control technology currently available, best available technology economically achievable, and pretreatment standards for new sources. For each of these regulations, EPA has identified several pollution control options, each with different levels of pollution abatement and compliance cost. The analysis is a tool for evaluating the options.
This report provides information to government and industry to enable decision-making and management of local environmental quality conditions. The need for a summary air quality report has arisen in recent years due to growing concerns about air quality. Increased growth in population and the tourism industry is placing additional pressures on environmental quality. The report summarized meteorological and air quality data collected by the British Columbia Ministry of Water, Land and Air Protection in the Sea-to-Sky airshed from 1984 to 2001. The airshed is located in the Lower Mainland region of British Columbia. Air quality monitoring was conducted for various periods at 18 different stations and meteorological monitoring was conducted at 4 locations. A list of both provincial and national air quality objectives and standards was provided, with definitions and reference levels from the Canadian Environmental Protection Act. Meteorological data was presented on a ...
The article presents the comparative bench testing results of a naturally aspirated four stroke, four cylinder, water cooled, direct injection Diesel engine when running on shale oil that has been treated with multi-functional fuel additives. The purpose of the research is to evaluate the effectiveness of the fuel additives Marisol FT (Sweden) and SO-2E (Estonia) as well as to verify their ability to increase energy conversion and reduce brake specific fuel consumption, contamination and smoke opacity of the exhausts when fuelling the Diesel engine with shale oil. Test results show that application of these additives could be a very efficient means to improve diesel engine performance on shale oil, especially when operating at the light load range. The brake specific fuel consumption at light loads and speeds of 1400-2000 min{sup -1} reduces by 18.3-11.0% due to the application of the Marisol FT. The additive SO-2E proves to produce nearly the same effect. The ...
The first part of the conference dealt with environmental effects of using coal. Papers dealt with the use of fly ash in agriculture and its effect on plant growth; the effect of airborne emissions on fish and wildlife resources, on watersheds, and on airsheds; the effects of surface mining on the ecology; blast effects; and health hazards associated with coal. The session on policy studies addressed the issue of cost of synthetic fuels and discussed the state and federal pollution regulations on burning coal and waste disposal. The session on combustion presented papers on atmospheric and pressurized fluidized-bed combustion for industrial and utility boilers. It also included papers on MHD power plants, coal-oil and coal-water mixtures, emission characterization and control, and catalytic combustors. The design of gasification plants, reaction kinetics, specific heats of coals and chars, simultaneous ...
The first part of the conference dealt with environmental effects of using coal. Papers dealt with the use of fly ash in agriculture and its effect on plant growth; the effect of airborne emissions on fish and wildlife resources, on watersheds, and on airsheds; the effects of surface mining on the ecology; blast effects; and health hazards associated with coal. The session on policy studies addressed the issue of cost of synthetic fuels and discussed the state and federal pollution regulations on burning coal and waste disposal. The session on combustion presented papers on atmospheric and pressurized fluidized-bed combustion for industrial and utility boilers. It also included papers on MHD power plants, coal-oil and coal-water mixtures, emission characterization and control, and catalytic combustors. The design of gasification plants, reaction kinetics, specific heats of coals and chars, simultaneous ...
This presentation gives the results of a research programme aimed at evaluating exhaust emissions from ships moving within confined coastal zones, as in Piraeus harbour. The level of various exhaust emissions were estimated on the basis of a mathematical model applied for each sea traffic element (ship). Hourly and daily records of all ships` movements in different parts of the harbour were compiled, covering extended periods of time and associated with different shipping operational characteristics (peaks, lows, etc). In order to correlate the exhaust emissions from shipping with the quality of the air in the area of interest, land-based measurements for the same pollutants were carried out in selected locations, near the port and in the greater Athens area. This enabled the investigation of time and spatial diffusion of exhaust emissions from shipping within the area of interest, ...
The document gives statistics on the pollutiveemissions from Danish power plants during the period 1987-1996, the main pollutants being sulphur dioxide, nitrogen oxides and carbon dioxide. Data on efficiency levels relative to the production of electricity and heating and on the power plants` contribution to the total emission of CO{sub 2}, NO{sub x}, and SO{sub 2} from energy consumption in Denmark, are presented, and also as corrected for the net import of electricity. Other data on the emission of each of these chemicals by power plants are presented as factual, and corrected in accordance with the net import of electricity, and as factual per consumed and produced energy unit at the power plants. Short notes on related Danish legislation are found in addition to information on sources, methods and definitions used as a basis for the production of this document. ...
The implementation of satellite remote sensing data for monitoring anthropogenic pollution in the USSR is described. Space-based monitoring systems offer the opportunity to identify pollution sources, track the spread of pollutants on the surface and in the air, and characterize land use patterns that cause erosion. Furthermore, vegetation under attack by polluting agents can be recognized by color changes, and waterpollution in lakes, coastal zones, and in rivers near industrial areas and ports can be measured for the total affected area. The data have thus far been taken with instrumentation on board the Salyut space station, the Meteor-Priroda satellite, and from the Landsat MSS scanner. It is noted that the transboarder transport of pollutants necessitates sharing data with agencies of other nations, and that a data base must be ...
The Eiric Raude offshore drilling rig is a powerful machine that is suitable for drilling in harsh environments in ultra deep water. It has a total drilling depth of 8,200 to 10,000 metres and an operational displacement of 53,400 mt. The rig complies with the regulatory regimes of Norway, the United Kingdom and Canada. The Eiric Raude has drilled 5 deepwater wells offshore eastern Canada, 1 well offshore Cuba, 1 well west of Shetland, and 3 offshore Norway. The environmental criteria for extreme weather conditions consider wave, current and wind forces. The general operational guidelines were discussed along with key areas for prevention of environmental impact, including emissions from well testing, air emissions from diesel engines, cooling water, bunkering operations, discharges from drilling, accidental discharges, drain water, and domestic sewage. It was noted that the zero ...
Economic and performance criteria that should be used in the selection of a scrubber system are presented. Selection should be based on the type of emissions put out by a plant and the removal efficiency required by pollution control standards. Costs and efficiencies for 10 different scrubber systems are reported. (10 diagrams)
...wood smoke, emissions, pollution, heaters, environment, Earthbeat - 25/5/2002: Woodsmoke, Health & the Environment Love that Planet All in the Mind The Buzz Health Report In Conversation Ockhams Razor Science Show The Lab Health Matters Catalyst Quantum ...
The report gives background design data for a specific copper smelter. The data is sufficiently detailed to allow air pollution control system engineering studies to be conducted. These studies will be concerned primarily with lean SO2 streams that curren...
Remote sensing data over North America document the ubiquity of secondary aerosols resulting from a combination of primary biogenic and anthropogenic emissions. The spatial and temporal distribution...Full Text Available
A link is made in this paper between proposed low energy scenarios for different Western European countries and the amount of pollutants that may result from these scenarios. Air pollutantemissions are calculated for the ten countries for which low energy scenarios are available. These scenarios emphasize stringent energy efficiency, maximizing the use of renewable (other than nuclear) energy, and minimizing the use of fossil fuels. Under these low energy scenarios, the average per capita energy use (year 2030) in the ten countries is estimated as 97 GJ/person, which is a decrease of 38% relative to 1980. Using the energy consumption figures from the low energy scenarios, together with sector- and fuel-specific emission factors from Europe, the resulting emissions of SO_2 , NO_x , and CO_2 were computed. These estimates do not take into account any add-on ...
Soil contamination by liquid organic pollutants represents a serious threat to phreatic ground water. These organic liquids get into the ground and migrate through the porous medium until they finally reach the aquifer. After a critical study of the literature, we listed various existing multiple displacements under three-phase conditions of a disconnected polluting phase that may or not spread over water. The aim of this thesis is to model (at pore scale level) and integrate in the pore network model the various flows that occur when three phases (gas, pollutant and air) are present in a porous medium. The porous medium is supposed completely water-wet. The polluting phase may be connected or not, and the spreading coefficient of the pollutant over water may either be positive or negative. The goal ...
The Advanced Statistical Trajectory Regional Air Pollution (ASTRAP) model simulates long-term transport and deposition of oxides of and nitrogen. t is a potential screening tool for assessing long-term effects on regional visibility from sulfur emission sources. owever, a rigorou...
Discusses the resolution of the 2. Congress of the Polish Nuclear Society on the energy situation in Poland and recommendations for energy policy. Recommendations for use of nuclear power plants in Poland are made considering environmental pollution from coal combustion (air pollution by sulfur dioxide, nitrogen oxides and carbon dioxide as well as waterpollution by salt from mine water discharged to rivers), development of the Polish economy, forecast increase in energy consumption and the role of nuclear energy in other European countries. Research on nuclear power plants, safety and environmental aspects as well as comparative efficiency of coal-fired power plants and nuclear power plants is evaluated.
This book provides discusses recent developments in oil pollution control instrumentation. Some of the topics covered are as follows: 1. Technical requirements of the IMCO International Performance and Test Specification A393x concerning oil content meters; and 2. Oil in water detection; and 3. Methods for the disposal of recovered oil and oily sludge; and 4. Oil content monitoring at ballast water treatment facilities and offshore production platforms.
In accordance with Public Law 95-217, Section 314 (the 'Clean Lakes' section of the 1977 Amendments to the Federal WaterPollution Control Act), the Massachusetts Division of WaterPollution Control developed a lake classification program based upon the trophic condition of all publicly owned freshwater lakes and ponds in the Commonwealth. This publication, produced and updated on an annual basis since 1976, is the result of that program.
The critical concentrations correspond to contamination thresholds of environments over which noxious effects can occur and deteriorate soils, water and vegetation. They are defined according to the type of pollutants and their mode of action. The aim of this document is to provide a scientific framework to the policies of reduction of atmospheric pollution negotiated at Geneva`s convention. The methodology of evaluation, the results obtained for surface waters and forest soils, the perspectives of French research and the integration of French knowledge in the European database are presented. (J.S.)
Geological clay formations are investigated for use as final underground deposit for heat producing nuclear waste. Special kinds of clay (e.g. bentonite) can also be used for the construction of geotechnical barriers. For the long time safety prognosis of the nuclear waste repositories the development of geochemical transport models is indispensable. The transport of aqueous solutions in clay is a complex process. The three-layer-minerals bentonite and illite swell by the adsorption of water, if the volume is restricted a high swelling pressure develops. The excellent barrier effect of natural clay formations and geotechnical clay barriers is based on the high swelling pressure and the high adsorption capacity for radionuclides and other pollutants. The two-layer-mineral kaolinite has no swelling capacity. In contrast to sandy layers a special geochemical transport potential exists in clay besides the well known matrix potential which ...
This thesis is in the field of gas emission control from automobile and stationary sources. Out of the possible approaches to the elimination of pollutant gases, such as nitrogen oxides (NO{sub x}), one consists in the selective catalytic reduction (SCR) of these NO{sub x} on a suitable heterogeneous catalyst. Ammonia or hydrocarbons are employed as reducing agents. The most important catalysts active in the SCR of NO{sub x} are based on ions of transition metal either supported on several oxides or dispersed in zeolites. The catalysts have been characterized by electron magnetic resonance techniques (EPR, ENDOR, ESEEM) and the interaction of catalysts with nitrogen oxides, with reducing and poisoned agents have been followed with the same techniques. Copper dispersed on alumina and its interaction with both NO and ammonia has been investigated. Also the interaction between both water and ammonia with copper dispersed in ...
In the frame of the comprehensive assessment of Swiss energy systems, air quality simulations were performed by using a 3-dimensional photo-chemical dispersion model. The objective is to investigate the impacts of pollutants in Switzerland for future options of Swiss energy systems. Four scenarios were investigated: Base Case: simulations with the projected emissions for the year 2030, Scenario 1) all nuclear power plants were replaced by oil-driven combined cycle plants (CCP), Scenarios 2 to 4) traffic emissions were reduced in whole Switzerland as well as in the cities and on the highways separately. Changes in the pollutant concentrations and depositions, and the possible short-term impacts are discussed on the basis of exceedences of critical levels for plants and limits given to protect the public health. (author) 2 figs., 7 refs.
This document includes the following topics: Background; Data Collection; Scope/Applicability of the Proposed Regulation; Description of the Industry; Industry Subcategorization; Pollutants of Concern for the Centralized Waste Treatment Industry; Pollutants Selected for Regulation; Wastewater Treatment Technologies; Regulatory Options Considered and Selected for Basis of Regulation; Long-Term Averages, Variability Factors, and Limitations and Standards; Cost of Treatment Technologies; Pollutant Loading and Removal Estimates; Non-Water Quality Impacts; Implementation; Analytical Methods and Baseline Values; List of Definitions; List of Acronyms; Appendix A--Pollutant Groups; Appendix B--Listing of Characerization Data From Non-Hazardous Oils Facilities; Appendix C--Listing of Daily Influent and Effluent Measuements; Appendix D--Facility-Specific Compliance Costs; Appendix ...
EPA has proposed effluent limitations guidelines and standards for the centralized waste treatment (CWT) industry. This report investigates the cost-effectiveness of all possible combinations of proposed control options for the three subcategories of CWT operations. EPA considered three control options for metals, two for oils and two for organics, with 12 possible combinations of these options. The report measures cost-effectiveness through a comparison of compliance costs to the quantity of pollutants removed under each combination of control options. The effectiveness of the regulations is measured in terms of reductions in the pounds of pollutants discharged to surface waters, weighted to account for the pollutants` toxicity. Some pollutants removed are specifically addressed by the regulation, while others and not directly regulated but are removed incidentally as a result of ...
New York City data indicate that seasonal and annual variations in dispersion-normalized air pollutant concentrations appear to accurately reflect changes in source emission patterns. The normalized concentrations make it possible to observe the impact of regulatory changes on ambient air quality without these impacts being obscured by meteorological fluctuations. It is found that numerical modeling techniques and regression analysis can be powerful tools for extracting information from large sets of air quality data. The use of differential, as opposed to absolute, pollutant concentration values will reduce artifact correlations caused by seasonal, weekly, or daily meteorological fluctuations and will permit more accurate estimation of the regression coefficients. This technique was successfully applied to a set of daily pollution measurements whose absolute concentrations were found not to yield a ...
New York City data indicate that seasonal and annual variations in dispersion-normalized air pollutant concentrations appear to accurately reflect changes in source emission patterns. The normalized concentrations make it possible to observe the impact of regulatory changes on ambient air quality without these impacts being obscured by meteorological fluctuations. It is found that numerical modeling techniques and regression analysis can be powerful tools for extracting information from large sets of air quality data. The use of differential, as opposed to absolute, pollutant concentration values will reduce artifact correlations caused by seasonal, weekly, or daily meteorological fluctuations and will permit more accurate estimation of the regression coefficients. This technique was successfully applied to a set of daily pollution measurements whose absolute concentrations were found not to yield a ...
This paper presents research work concerning the mathematical modelling of air pollution in the Athens basin. A mathematical model based on aerodynamics and conservation equations together with turbulence modelling in body-fitted coordinates is used to provide the necessary input information to a similar but more detailed (i.e. small scale) model around Athens. Both models consist of solving the full Navier-Stokes equations and take into account the precise topography of the region. Different roughness heights are used for sea, coastal regions and land. The smaller scale model makes use of a two-equation turbulence model ({kappa}-{epsilon}) and the large scale model assumes a constant turbulence viscosity. The pollutant sources used in these models are based on actual emissions in the Athens area and are distributed in space. The results of this work appear promising and demonstrate the capability of the model as a tool for ...
New market based approaches are becoming increasingly important as instruments of environmental policy. The two main market approaches, i.e., transferable pollution permits (experimented in America), and 'green' energy surcharges (European philosophy), are described and discussed. An analysis of information on their state of implementation shows that, in the case of the former method, the greatest sources of difficulty arise in the determination of acceptable ceiling levels of emissions, in the distribution of permits among the various polluting firms, and in the legality of granting rights to pollute. Instead, the European experience has evidenced that energy surcharges motivated by environmental policy cannot have an appreciable positive impact on consumers or the economic system in general unless they are accompanied by well defined measures geared towards the promotion or creation ...
An analysis on landscape level was performed to investigate the growth of Scots pine stands (Pinus sylvestris L.) in the research area of 'Duebener Heide' under the impact of rapidly changing pollution loads and to evaluate their further development. Central to the work was a spatial database, installed using a geographic information system (GIS). This database enabled the statistical analysis of relationships and correlations between the growth of the pine stands, the influence of pollution impacts and the natural site characteristics. The results of emission and immission modelling gave detailed evaluation of the pollution load over the investigated area. The spatial information database was linked with a process-based growth model called FORSANA. The resulting regional model was used to simulate forest growth on stand level for variable time periods. The plausibility of the ...
The growing global public concern over deteriorating air quality and greenhouse gases emissions released from various combustion processes, and particularly power plants and transportation system, led governments and local authorities, especially in industrialised countries into taking these issues seriously and establishing standards to reduce air pollution down to acceptable levels, (clean air act, earth summit,...). The transportation sector has another unwanted product, noise pollution caused by different segments of this sector including the noise produced by the engine, tires noise and exhaust noise, in addition to the noise product by private standby generals operating during electricity cut-off periods. To be able to estimate the environmental impacts of the national power plants and the transportation sector, it is necessary to collect enough data (samples of lead emissions, SO_2 concentration, ...
'Within 15 years the energy consumption bottleneck has shifted from the supply side to emissions, i.e. to the waste side.' Reflecting this statement one may realize the importance of lending more weight to energy conservation but may also be induced to critically analyze the corresponding measures. First results of such reflections are given with regard to the payback periods of air pollution abatement measures relative to the additional emissions they cause. (orig.).
Validity of fern spore germination bioassays for the effects of environmental pollution was established by many researchers. Some workers studied the phytotoxicity of linear alkyl benzene sulfonate (LAS) on the spores of Diplazium esculentum and observed that LAS levels above 0.001% are toxic to fern spores. Waterpollution due to synthetic detergents has been increasing continuously during the last few years due to their extensive use in domestic life, agriculture and industry. These detergents are among the most common pollutants responsible for waterpollution. In view of this fact, the phytotoxicity of LAS on germination of an aquatic fern Ceratopteris thalictroides spores was studied. However, in these studies, only germination pattern was taken as index and no observations were made on the developmental stages.
To predict air quality properly at a given location, it is necessary to identify all emission sources that will have significant impact at that location. Furthermore, the atmospheric pollutants that are emitted by these sources must be identified and quantitatively characterized. Once the air-quality predictions have been made, it is desirable to have some historical air-quality data for comparison. An efficient means of obtaining this information is through the use of detailed emission inventories and an inventory of air-quality-monitoring stations. Therefore, as part of the Alberta Government/Industry Acid Deposition Research Program (ADRP), three comprehensive inventories have been developed, namely: a sulfur dioxide (SO/sub 2/) emission inventory, a nitrogen oxides (NOx) emission inventory, and an inventory of air-quality-monitoring stations. Volume 2, Design of the ...
After the devastating natural disasters that have hit China recently, another crisis is looming, Drought, pollution and heavy usage in the fast-developing megacities have resulted in a shortage of water. A huge construction effort is underway to divert water from the south to the north. But experts warn that it will not solve China's structural water problems.
During spring and autumn, the total number of amoebae and the number of acanthamoeba species able to grow at 37 degrees C were determined in six thermally polluted factory discharges and the surrounding surface waters. The isolated Acanthamoeba strains were studied for growth in axenic medium, cytopathic effect in Vito cell cultures, and virulence in mice. Although more amoebae were isolated in autumn, the number of Acanthamoeba species was lower than in spring, when the percent of pathogenic strains among the isolates was highest. Higher concentrations of amoebae were found in warm discharges, and more virulent strains occurred in thermal discharges than in surface waters.
Finland has set up several national air pollution control programmes in order to implement international conventions. As a rule these programmes have focused on one pollutant. The national second carbon dioxide commission is at present working on a new programme to curb carbon dioxide emissions, and this will unavoidably affect other programmes, too. This study presents the existing programmes and their respective implementation costs. The aim has been to focus on the interaction between different air pollution combatting measures and the possibilities of setting priorities on a cost basis. The main result is that it will be difficult to integrate overall aims for general welfare and subsequent energy consumption with environmental considerations, especially in air pollution control. If the increase in energy generation follows current scenarios, the costs for air ...
Fugitive dust emissions from stockpiles in the open storage yards of industrial zones and the subsequent atmospheric dust dispersion have brought about many ecological and economical problems. This paper introduces a new approach to reduce pollutantemissions by simply changing pile configuration and without affecting the operational activity on these parks. Flow around piles of different geometries and for various wind conditions was studied using previously validated Computational Fluid Dynamic (CFD) simulations. Different pile height scenarios were investigated corresponding to a constant material volume and a fixed angle of repose under various wind magnitudes. The results obtained were integrated in order to evaluate the rate of dust emissions for the various configurations considered. It was found that, for the range of wind conditions and pile dimensions tested, an optimal geometry exists which ...
Although various legislation and regulations have been adopted to promote the use of alternative-fuel vehicles for curbing urban air pollution problems, there is a lack of systematic comparisons of emission control cost-effectiveness among various alternative-fuel vehicle types. In this paper, life-cycle emission reductions and life-cycle costs were estimated for passenger cars fueled with methanol, ethanol, liquefied petroleum gas, compressed natural gas, and electricity. Vehicle emission estimates included both exhaust and evaporative emissions for air pollutants of hydrocarbon, carbon monoxide, nitrogen oxides, and air-toxic pollutants of benzene, formaldehyde, 1,3-butadiene, and acetaldehyde. Vehicle life-cycle cost estimates accounted for vehicle purchase prices, vehicle life, fuel costs, and vehicle maintenance costs. ...
The work described in the following is a portion of the MEET project (Methodologies for Estimation Air PollutantEmissions from Transport). The overall goal of the MEET project is to consolidate and present methodologies which can be used to estimate air pollutantemissions from various types of traffic sources. One of the goals of MEET is to provide methodologies to be used in the COMMUTE project also funded by DG VII. COMMUTE is developing computer software which can be used to provide emissions inventories on the European scale. Although COMMUTE is viewed as a prime user of the information generated in MEET, the MEET results are intended to be used in a broader area, and on both smaller and larger spatial scales. The methodologies and data presented will be useful for planners on a more local scale than a national or continental basis. While most attention in previous years has ...
The UFIP (French Petroleum Industry Association) studies concerning polluted sites and soils and their rehabilitation are presented: characterization of the admissible maximum fuel or gas oil content in the ground, the issue of time effects, and the risks it may induce for public health; study on the various pollutant impacts on the environment (underground waters, biotope...); approach to the development of a dynamical model describing these phenomena and their influence on man, in order to derive consistent and reasonable decontamination objectives
Reinforcement of the legislation concerning the emission of atmospheric pollutants, aerosols, refrigerants, solvents etc and the reduction of the greenhouse effect, has led to the development of performing instruments for the survey and control of ambient air quality and for the limitation of exhaust gases, combustion products, volatile organic compounds (VOC), particulates and noxious compounds in the atmosphere. This study is divided in 4 main parts. The first part describes the context of the air quality control: the problems linked with the environment and health, the pollutants characteristics, the pollution levels and the detection sensitivity of instruments according to the different type of pollutants (petroleum products, VOCs, ozone compounds, particulates, smells..), the protocols of air pollution measurements and their application (chimney smokes, ...
An improved method of counting acoustic emission (AE) events from water-stressed stems of cedar (Thuja occidentalis L.) is presented. Amplified AEs are analyzed on a real time basis...Full Text Available
This paper very briefly outlines hazardous waste management issues, including regulations, in Mongolia. Air, water, and soil pollutants are identified and placed in context with climatic, social, and economic circumstances. The primary need identified is technology for the collection and disposal of solid wastes. Municipal waste problems include rapid urbanization and lack of sanitary landfills. Industrial wastes of concern are identified from the mining and leather industries. 4 refs., 2 tabs.
Los Alamos National Laboratory is subject to annual emissions-reporting requirements for regulated air contaminants under Title 20 of the New Mexico Administrative Code, Chapter 2, Part 73 (20.2.73 NMAC), Notice of Intent and Emissions Inventory Requirements. The applicability of the requirements is based on the Laboratory's potential to emit 100 tons per year of suspended particulate matter, nitrogen oxides, carbon monoxide, sulfur oxides, or volatile organic compounds. For calendar year 2001, the Technical Area 3 steam plant was the primary source of criteria air pollutants from the Laboratory, while research and development activities were the primary source of volatile organic compounds. Emissions of beryllium and aluminum were reported for activities permitted under 20.2.72 NMAC. Hazardous air pollutantemissions from chemical use for research and ...
Due to the 'novel forest diseases' the political parties of the Federal Republic of Germany unanimously attend to the reduction of emissions. The transportation sector is considered to be a major emission source. A study discussed in the publication abstracted did therefore aim at giving a detailed account and description of the recently ratified technical requirements and tax credits expected to reduce vehicle exhaust gas air pollution. Moreover, the study researches into the regulations' importance as to the low emission properties of individual automobiles. Based on the results obtained the study arrives at assumptions as to emissions to be expected from the transportation sector. It tries to assess the financial import with respect to the individual citizen, overall internal revenues and federal motor vehicle taxes. The introductory chapter is followed ...
This study examined the atmospheric pollution created by some waste treatment and disposal facilities in the State of Kuwait. Air monitoring was conducted in a municipal wastewater treatment plant, an industrial wastewater treatment plant established in a petroleum refinery, and at a landfill site used for disposal of solid wastes. Such plants were selected as models for waste treatment and disposal facilities in the Arabian Gulf region and elsewhere. Air measurements were made over a period of 6 months and included levels of gaseous emissions as well as concentrations of volatile organic compounds (VOCs). Samples of gas and bioaerosols were collected from ambient air surrounding the treatment facilities. The results obtained from this study have indicated the presence of VOCs and other gaseous pollutants such as methane, ammonia, and hydrogen sulphide in air surrounding the waste treatment and disposal facilities. In some ...
The paper demonstrates an application of advanced decision support tools within the framework of the environmental information system of the Province of Milan. These tools include environmental simulation models, multi criteria analysis, risk analysis and environmental accounting for marketable emission permits. After describing the general structure of the system, three demonstrational case studies are introduced concerning: groundwater pollution management; atmospheric pollution management; urban environmental quality perception and management. In the conclusion, potential use of tools like the ones implemented by the province of Milan within the framework of Local Agenda 21 processes is recalled.
In this paper the problem of developing optimal bidding strategies for the participants of oligopolistic energy markets is studied. Special attention is given to the impacts of suppliers' emission of pollutants on their bidding strategies. The proposed methodology employs supply function equilibrium (SFE) model to represent the strategic behavior of each supplier and locational marginal pricing mechanism for the market clearing. The optimal bidding strategies are developed mathematically using a bilevel optimization problem where the upper-level subproblem maximizes individual supplier payoff and the lower-level subproblem solves the Independent System Operator's market clearing problem. In order to solve market clearing mechanism the multiobjective optimal power flow is used with supplier emission of pollutants, as an extra objective, subject to the supplier physical constraints. This ...
The activated charcoal is very appreciates for the water treatment. It do not generate by-product of treatment. In return it is saturated after some time and may releases pollutant compounds. When and how to get to its regeneration?.
Increased construction of residential canal communities along the southern coastline of the United States has led to a concern about their impact on water quality. Pollution of such dead-end canals...Full Text Available
This document is a technical background document for proposed regulations to limit effluent discharges to waters of the United States and introductions of pollutants into publicly owned treatment works from facilities engaged in porcelain enameling. The p...
The report describes tests to demonstrate the feasibility of using a vertical-tube, falling-film, vapor-compression evaporator to concentrate waste water from a flue gas desulfurization (FGD) process. Tests showed that waste water from the Chiyoda FGD process can be concentrated ...
Ammonia is a common and highly toxic pollutant which, in sufficient quantities, will adversely affect aquatic organisms. This ammonia criteria document for salt water will allow establishment of regulatory standards for ammonia discharge into estuaries, near coastal zones and oceans. Possible adverse impacts in highly sensitive and abundant ecosystems such as estuaries make regulation particularly important.
The article describes the energy in Lebanon. In 1995, 97% of the imported energy was based on hydrocarbons. Fuel and gas oil present 66% of the final energy. Air pollution is mainly caused by the transportation sector (vehicles and buses...) which presents 70% of the global atmospheric pollution. Renewable energy such as biomass, fossil energy, hydro-energy, solar energy... are also described. The solar energy was defined as a best solution that preserve health in Lebanon. The different applications of the solar for energy production is discussed: photovoltaic , thermal heating, sanitary hot water, electrical heaters, solar water heaters...In conclusion, solar heaters economize 80% of the annual energy expenses
Within the framework of efforts to optimize state-of-the-art waste disposal methods, this research project makes a theoretical analysis of the propagation behaviour of pollutants from landfills and waste incineration plants into the immediate vicinity of such plants. In order to judge the propagation of pollutants near the above-mentioned waste disposal facilities, a calculation program was developed within the framework of this research project which permits simulation of the propagation of such emissions in a three-dimensional space by application of an Eulerian grid model. It is capable of realistically representing fluid flow conditions and pollutant concentrations for certain points of times within the complex building patterns of such plants, for randomly chosen atmospheric conditions. (orig.)
This paper tests the Environmental Kuznets Curve hypothesis for four local (SOx, NOx, CO, VOC) and two global (CO2, GHG) air pollutants. Using a new panel data set of thirty OECD countries, the paper finds that the postulated inverted U-shaped relationship between income and pollution does not hold for all gases. A meaningful Environmental Kuznets Curve exists only for CO, VOC and NOx, where for CO2 the curve is monotonically increasing. For GHG there is indication of an inverted U-shaped relationship between income and pollution, but still most countries are on the increasing path of the curve and hence the future development of the curve is uncertain. For SOx it was found that emissions follow an U-shaped curve. Based on the empirical results, the paper concludes that the Environmental Kuznets Curve does not hold for all gases, it is rather an empirical artefact than a regularity.
This paper tests the Environmental Kuznets Curve hypothesis for four local (SOx, NOx, CO, VOC) and two global (CO2, GHG) air pollutants. Using a new panel data set of thirty OECD countries, the paper finds that the postulated inverted U-shaped relationship between income and pollution does not hold for all gases. A meaningful Environmental Kuznets Curve exists only for CO, VOC and NOx, where for CO2 the curve is monotonically increasing. For GHG there is indication of an inverted U-shaped relationship between income and pollution, but still most countries are on the increasing path of the curve and hence the future development of the curve is uncertain. For SOx it was found that emissions follow an U-shaped curve. Based on the empirical results, the paper concludes that the Environmental Kuznets Curve does not hold for all gases, it is rather an empirical artefact than a regularity.
A new prototype model system named AirGIS has been developed to support local authorities in air quality management for big Danish cities. The system is based on the Danish operational street pollution model (OSPM), technical and cadastral digital maps and Danish national administrative databases on buildings, cadastres and populations. It applies a geographic information system (GIS). AirGIS estimates ambient air pollution levels at high temporal and spatial resolutions. The model system enables mapping of traffic emissions, air quality levels and human exposures at residence addresses, at workplace addresses and in streets. Mapping and scenario results can be compared with air quality limits. Impact assessment of traffic air pollution abatement measures can also be carried out. (author)
The Toxicological Evaluation of Realistic Emissions of Source Aerosols (TERESA) study involved withdrawal, aging, and atmospheric transformation of emissions of three coal-fired power plants. Toxicological evaluations were carried out in rats exposed to different emission scenarios with extensive exposure characterization. Data generated had multiple levels of resolution: exposure, scenario, and constituent chemical composition. Here, we outline a multilayered approach to analyze the associations between exposure and health effects beginning with standard ANOVA models that treat exposure as a categorical variable. The model assessed differences in exposure effects across scenarios (by plant). To assess unadjusted associations between pollutant concentrations and health, univariate analyses...
Los Alamos National Laboratory (the Laboratory) is subject to emissions reporting requirements for regulated air contaminants under Title 20 of the New Mexico Administrative Code, Chapter 2, Part 73 (20 NMAC 2.73), Notice of Intent and Emissions Inventory Requirements. The Laboratory has the potential to emit 100 tons per year of suspended particulate matter, nitrogen oxides, carbon monoxide, sulfur oxides, and volatile organic compounds. For 1998, combustion products from the industrial sources contributed the greatest amount of criteria air pollutants from the Laboratory. Research and development activities contributed the greatest amount of volatile organic compounds. Emissions of beryllium and aluminum were reported for activities permitted under 20 NMAC 2.72 Construction Permits.
Water quality of the Citarum River and the Jatiluhur Reservoir in Indonesia was evaluated using C-14 radioisotope. A close relationship between the abiotic (physical and chemical) and the biotic (algal growth potential, primary productivity, chlorophylla and diversity index of planktonic and benthic macroinvertebrate) parameters was obtained. Algal growth potential to abiotic parameters relationship has the highest correlation coefficient and can be used as a pollution indicator. The other biotic parameters do not show clear relationship with the abiotic parameters. The Citarum water quality is the lowest in those locations which receive human and industrial waste from Bandung and its environment. This water cannot be used for drinking purposes and fishery. The water quality in other locations of the river, however, meets the criteria for agriculture. Agricultural waste does not ...
An increasing share of natural gas supplies distributed to residential appliances in the U.S. may come from liquefied natural gas (LNG) imports. The imported gas will be of a higher Wobbe number than domestic gas, and there is concern that it could produce more pollutantemissions at the point of use. This report will review recently undertaken studies, some of which have observed substantial effects on various appliances when operated on different mixtures of imported LNG. While we will summarize findings of major studies, we will not try to characterize broad effects of LNG, but describe how different components of the appliance itself will be affected by imported LNG. This paper considers how the operation of each major component of the gas appliances may be impacted by a switch to LNG, and how this local impact may affect overall safety, performance and pollutantemissions.
The increasing diffusion of small-scale energy systems within the distributed generation (DG) paradigm is raising the need for studying the environmental impact due to the different DG solutions in order to assess their sustainability. Addressing the environmental impact calls for building specific models for studying both local and global emissions. In this framework, the adoption of natural gas-fueled DG cogeneration technologies may provide, as a consequence of cogeneration enhanced overall energy efficiency and of natural gas relatively low carbon content, a significant reduction of global impact in terms of CO2 emissions with respect to the separate production of electricity and heat. However, a comprehensive evaluation of the DG alternatives should take into account as well the impact due to the presence of plants spread over the territory that could increase the local pollution, in particular due to CO and NOx, and ...
The World Bank is analyzing the role of economic policy instruments for the control of air pollution in Poland, in cooperation with Polish and international experts. The first stage, covering Poland as a whole, was recently completed, jointly financed with the U.S. E.P.A. and the Government of the Netherlands. The second stage, now under way, will extend the analysis into a specific regional framework. Stage 2 is financed by the World Bank, the Polish Government, and the U.K. Environment Know-How Fund. Air Pollution in Poland is overwhelmingly caused by energy production and uses, due to the fact that the Polish economy depends heavily on coal and lignite. At present, vehicles contribute less to total emissions than do coal burning and industrial processes, although they account for 25-35% of nitrogen oxides, carbon monoxide, hydrocarbons and lead; and the concentrated in areas of high population density. The paper shows ...
Abstract The aim of this study is to study the effects of Boron (B) pollution in Buyuk Menderes river on planted crops and agricultural areas constructed in the irrigation schemes by the State Hydraulic Works (DSI) of the Lower Buyuk Menderes basin, Turkey. The studied irrigation schemes in the basin are Saraykoy, Pamukkale, Nazilli, Aydin, Sultanhisar, Koarli, and Soke. Mean B concentrations of river water used in the irrigation schemes ranged from 0.10 to 0.43 mgB L-1 for the period of 2008 to 2009. A total of 100,556 ha of the agricultural area and the basin groundwater resources are under the influence of B pollution from the Buyuk Menderes river. The amount of B accumulating in soils and seepage in the groundwater due to the used irrigation water was 18,495,350 and 9153 kgB yr-1, resp...
The use of natural energy sources and their conversion to secondary forms of energy are a crucial base for the development of our society with its continuous change of requirements due to an increase in population and the broadening of the needs in our modern life. As a consequence the consumption of primary energy resources rose drastically worldwide during the last 5 decades in particular in the industrialized regions such as Europe. Parallel in time the increasing awareness of negative effects of fuel dependent pollution on the environment and the introduction of stringent emission control regulations about 3 decades ago initiated extensive development and retrofit activities resulting in the today applied high level state of the art. As an additional challenge the worldwide debate about the potential effects of the emission of the s.c green house gases on the global climate in particular carbon dioxide from the use of ...
The Tennessee Valley Authority (TVA), the Electric Power Research Institute (EPRI), and the Department of Energy-National Energy Technologies Laboratory (DOE-NETL) are evaluating and demonstrating integration of terrestrial carbon sequestration techniques at a coal-fired electric power plant through the use of Flue Gas Desulfurization (FGD) system gypsum as a soil amendment and mulch, and coal fly ash pond process water for periodic irrigation. From January to March 2002, the Project Team initiated the construction of a 40 ha Carbon Capture and WaterEmissions Treatment System (CCWESTRS) near TVA's Paradise Fossil Plant on marginally reclaimed surface coal mine lands in Kentucky. The CCWESTRS is growing commercial grade trees and cover crops and is expected to sequester 1.5-2.0 MT/ha carbon per year over a 20-year period. The concept could be used to meet a portion of the timber industry's needs while ...
The paper gives an overview on the technologies and applications of automatic wood furnaces. The combustion systems are defined by the flow condition: With increasing gas velocity, fixed bed, stationary fluidized bed (SFB), circulating fluidized bed (CFB), and entrained flow reactors are distinguished. The furnace design and typical applications are described. Further, a comparison is presented which gives data of the typical size range and fuel types for the different combustion systems. The most common fixed bed reactors are under-stoker and grate furnaces. While under-stoker furnaces are applied in the size range from 20 kW to 2.5 MW, grate furnaces cover the size range from a few 100 kW up to more than 50 MW. Under-stoker furnaces are well suited for wood fuel with low ash content, moderate water content and limited fuel size. Grate furnaces are also suited for fuel with high ash and water content and large fuel sizes. Hence grate furnaces ...
The population masses in many coastal zones in Japan, and human activities are greatly effected. The representative water area is the Tokyo Bay. The population of the Tokyo Bay reaches 26 million at present, and a mass of organic substance and nutrient salt flow into it through rivers and sewage-treatment plants, etc. With the improvement of pollution source countermeasure and sewerage in the area, the inflow load to the Bay gradually decreases, but in the inner bay, red tide is generating in the summertime mainly. And, the anoxic water areas observed in bottom layer in summertime make large effects on the seafood. It is a large theme to clarify formation process of the anoxic water area and to solve this problem for the Tokyo Bay in the twenty-first century. In this paper, changes in water qualities and human activities and fundamental approach of water quality ...
The report gives results of a project conducted to create a file containing comprehensive data on all electric utilities in the US. The National Acid Precipitation Assessment Program's (NAPAP's) emissions inventory activities focus on the estimation of emissions from pollutants that contribute to acid deposition. Electric utilities, which emit a large share of total acid deposition precursor emissions, are important for modeling analyses. Data reported by states to the National Emissions Data System (NEDS) for the 1985 NAPAP Emissions Inventory and data reported to the U.S. Department of Energy (DOE) on EIA Form 759, EIA Form 767, FERC Form 423, and the Integrated Data Base System (IDBS) were matched and combined. The resulting 1985 National Utility Reference File (NURF) contains detailed unit level data for nearly 10,000 electricity generating ...
This report is an assessment of emission-control costs for municipal-waste combustors (MWCs). The details of the cost estimates, including their development, components, and cost premises, are addressed. A model-plant approach was used in the sizing and costing of the emission control systems. Due to differences in the feed-waste characteristics, combustion parameters, and emissions, separate cost estimates were required for mass burning (MB), modular (MOD), refuse-derived fuel (RDF), and fluid-bed combustion (FBC) type furnaces. Cost estimates were developed for control of particulate matter (PM) emissions only and for control of both acid gas and PM emissions from the MWC model plants. Controlled PM emission levels of 0.03, 0.02, and 0.01 gr/dscf, corrected to 12% CO/sub 2/, and 90 and 70% reductions of HC1 and SO2, respectively, were used to develop the ...
The exhaust emissions of a Diesel direct injection Perkins engine fueled with waste olive oil methyl ester were studied at several steady-state operating conditions. Emissions were characterized with neat biodiesel from used olive oil and conventional Diesel fuel. Results revealed that the use of biodiesel resulted in lower emissions of CO (up to 58.9%), CO{sub 2} (up to 8.6%, excepting a case which presented a 7.4% increase), NO (up to 37.5%), and SO{sub 2} (up to 57.7%), with increase in emissions of NO{sub 2} (up to 81%, excepting a case which presented a slight reduction). Biodiesel also presented a slight increase in brake-specific fuel consumption (lower than 8.5%) that may be tolerated due to the exhaust emission benefits. Combustion efficiency remained constant using either biodiesel or Diesel fuel. The proposed alternative for Diesel fuel could significantly decrease the ...
Historically, the bulk production of electricity has been achieved by burning fossil fuels, with unavoidable gaseous emissions, including large quantities of carbon dioxide: an average-sized modern coal-burning power station is responsible for more than 10 Mt of CO{sub 2} each year. This paper details typical emissions from present-day power stations and discusses the options for their reduction. Acknowledging that the cuts achieved in the past decade in the UK CO{sub 2} emissions have been achieved largely by fuel switching, the remaining possibilities offered by this method are discussed. Switching to less-polluting fossil fuels will achieve some measure of reduction, but the basic problem of CO{sub 2} emissions continues. Of the alternatives to fossil fuels, only nuclear power represents a zero-carbon large-scale energy source. Unfortunately, public concerns over safety and ...
A study was undertaken to determine experimentally the uptake of pollutants into of the different parts of the water hyacinth (Eichhornia crassipes) found in 'Jose Antonio Alzate' dam in the State of Mexico, Mexico. There is evidence for efficient and significant root accumulation of Ti, Mn, Fe, and Ba; but in the upper parts concentrations was consistently determined by the degree of watering. However, a significant input could be derived from a common generic source, such as the atmospheric deposition. The experimental study would, therefore, indicate that water hyacinth species can be highly effective in providing a control and treatment buffer for toxic discharges to the dam. (author)
Some general topical information (generating capacity and electric power generation, development and structure of electric power consumption, frequency and peak load, exchange of electricity) is followed by an account of the situation of coal-fired power plants, hydroelectric power plants and nuclear power plants, and a brief discussion of the environmental situation (emissions and wastes, immissions, and air pollution abatement measures for power plants). (orig./UA).
The paper abstracted gives a tabular survey of the suppliers and applications of measuring equipment. Equipment is available for the following fields of application: Continuous measuring instruments for stationary operation, laboratory equipment for sampling and hand equipment for mobile measurement, sampling equipment for examining emissions and gases, detectors, storage and evaluation equipment and meteorological instruments. (PW).
DescriptionProgramme background Nanotechnology is the design and manufacture of substances typically between one and several hundred billionths of a metre in size. In this size range the properties of substances can change quite radically, offering potentially large socio-economic, health and environmental benefits. For example, nanofuel additives could help reduce emissions and particles from diesel engines. Nanoparticles may also be able to help remove persistent pollutants in soils and groundwaters. Th [continued...
This document provides details on a $120.2 million package of initiatives to implement the Ozone Annex, an agreement signed in December 2000 between Canada and the United States to significantly reduce transboundary smog causing pollutants and to improve air quality. Taking action under the Ozone Annex will address health and environmental challenges by reducing emissions of nitrogen oxides and volatile organic compounds which are precursors to ground-level ozone. This document described the actions that will be taken by the Government of Canada to reduce emissions from vehicles and the fuels that power them. It also described the measures that will be taken to improve air quality monitoring networks. The National Pollutant Release Inventory will be used to meet new reporting commitments contained in the Annex. This document also highlights the initial actions that will be taken to reduce ...
The role of macroinvertebrates and diatoms as indicator for metal pollution was investigated by assessing both biota along a metal gradient in the Belgian river the Dommel. Macroinvertebrates and diatoms were sampled in summer and winter and physical-chemical characteristics of the water were measured at four different sample periods and related to sediment characteristics. Although metal concentrations, except cadmium, in the water nowhere exceeded water quality standards, high metal concentrations were measured in the sediment, indicating historical contamination of the Dommel. At the sites that were situated downstream of the pollution source, high levels of conductivity and chloride were measured in the water. Redundancy Analysis (RDA) indicated pH, phosphate and zinc as the significant environmental variables explaining each respectively 7.7%, 11.6% and ...
Air toxics from the industrial wastewater treatment plants (IWTPs) impose serious health concerns on its surrounding residential neighborhoods. To address such health concerns, one of the key challenges is to quantify the air emissions from the IWTPs. The objective here is to characterize the air emissions from the IWTPs and quantify its associated uncertainty. An IWTP receiving the wastewaters from an airplane maintenance facility is used for illustration with focus on the quantification of air emissions for benzyl alcohol, phenol, methylene chloride, 2-butanone, and acetone. Two general fate models, i.e., WATER9 and TOXCHEM+V3.0 were used to model the IWTP and quantify the air emissions. Monte Carlo and Bootstrap simulation were used for uncertainty analysis. On average, air emissions fr...
This report documents radionuclide air emission from the Hanford Site in 1997, and the resulting effective dose equivalent to the maximally exposed member of the public, referred to as the MEI. The report has been prepared in accordance with reporting requirements in the Code of Federal Regulations, Title 40, Protection of the Environment, Part 61, National Emissions Standards for Hazardous Air Pollutants, Subpart H, National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities. This report has also been prepared in accordance with the reporting requirements of the Washington Administrative Code Chapter 246-247, Radiation Protection-Air Emissions. The effective dose equivalent to the MEI from the Hanford Site`s 1997 point source emissions was 1.2 E-03 mrem (1.2 E-05 mSv), which is well below ...
More than 660 synthetic aperture radar (SAR) images acquired over the southern Baltic Sea, the North Sea, and the Gulf of Lyon in the Mediterranean Sea by the Second European Remote Sensing Satellite (ERS-2) have been analyzed since December 1996 with respect to radar signatures of marine pollution and other phenomena causing similar signatures. First results of our analysis reveal that the seas are most polluted along the main shipping routes. SAR images acquired during descending (morning) and ascending (evening) satellite passes show different percentages of oil pollution, because most of this pollution occurs during night time and is still visible on the SAR images acquired in the morning time. Moreover, we found a higher amount of oil spills on SAR images acquired during summer (April-September) than on SAR images acquired during winter (October-March). We attribute this finding to the higher mean ...
To mitigate damages caused by agricultural runoff, private lake owners' associations are paying for inlake and instream pollution abatement measures and on land-conservation practices. This phenomenon supports the notion that individuals who benefit from improved water quality should be willing to pay part of the abatement costs. The research suggests that on land-conservation measures can substantially reduce sediment delivery at low cost. The Sediment Economics (SEDEC) model was modified and then used to select and to site management systems that achieved stated sediment goals at least cost. Other resource policies such as T value, no-till, and contouring were compared with the least-cost frontier and shown to be more costly. The noncropland areas substantially reduced sediment delivery to water channels and lowered abatement costs. Further research is needed for long-range watershed-planning models such as ...
The report identifies and analyzes the economic impacts of waterpollution control regulations on the battery manufacturing industry. These regulations include effluent limitations and standards based on BPT (best practical control technology currently available), BAT (best available technology economically achievable), PSES (pretreatment standards existing sources), NSPS (new source performance standards), and PSNS (pretreatment standards new sources), that have been promulgated under authority of Sections 301, 304, 306, 307, 308, and 501 of the Federal WaterPollution Control Act, as Amended (the Clean Water Act). The primary economic impact variables of interest include price changes, plant closures, substitution effects, changes in employment, shifts in the balance of foreign trade, changes in industry profitability, structure, and competition, and impacts on small business.
Denting studies have been undertaken in order to assess the influence of the most important parameters which could initiate corrosion of the carbon-steel occurring in the tube-tube support plate crevices of some PWR steam generators. Tests have been carried out in model boilers, feedwater being polluted with sea or river water. Specific effect of chloride or sulfate and influence of oxygen content, magnetite addition and pH value were investigated. In magnetite prepacked crevices, denting is obtained within 1000 hours for sea-waterpollution of 0.3 ppm chloride at the blowdown. In neutral chloride or in river water denting is observed only with oxygen addition. Denting prevention is effective in the case of an on-line addition of phosphate, boric acid or calcium hydroxide. For denting stopping, boric acid or calcium hydroxide is efficient even with a high ...
Olive oil mill wastewaters (OMW) cause disposal problems because they contain powerful pollutants such as phenolic compounds. Complete biodegradation or removal of these compounds is hardly achieved by a single treatment method. In this work, we investigated 2 integrated technologies for the treatment of the recalcitrant contaminants of OMW, allowing water recovery and reuse for agricultural purposes. (Author)
The phytomanagement of Se-polluted soil and water is one strategy that may be environmentally sustainable and cost-effective for soils and waters enriched with natural-occurring Se. Several plant species, including Indian mustard (Brassica juncea), pickleweed (Salicornia bigelovii), and other salt/S...
In-situ air stripping employs horizontal wells to inject or sparge air into the ground water and vacuum extract VOC`S from vadose zone soils. The horizontal wells provide better access to the subsurface contamination, and the air sparging eliminates the need for surface ground water treatment systems and treats the subsurface in-situ. A full-scale demonstration was conducted at the Savannah River Plant in an area polluted with trichloroethylene and tetrachloroethylene. Results are described.
The fossil fuel consumption and pollutantemissions in a coal fired fluidized bed boiler could be reduced by biomass pyrolysis gas reburning. The influence of three kinds of biomass pyrolysis gases on the emission of N2O in a laboratory scale fluidized bed was investigated using the mechanism of GRI3.0 in this paper. The results showed that: the effect of sawdust pyrolysis gas reburning on N2O was more significant than that of rice husk and orange peel under the same conditions; the increase of initial oxygen content from 1% to 8% in flue gas would restrain the decomposition of N2O; the N2O decomposition was enhanced by increasing reaction temperature from 1073.15 K to 1323.15 K, and the decomposition rate may reach 99% at 1223.15 K.
Ozone is the most important regional-scale air pollutant causing risks for vegetation and human health in many parts of the world. Ozone impacts on yield and quality of crops and pastures depend on precursor emissions, atmospheric transport and leaf uptake and on the plant?s biochemical defence capacity, all of which are influenced by changing climatic conditions, increasing atmospheric CO2 and altered emission patterns. In this article, recent findings about ozone effects under current conditions and trends in regional ozone levels and in climatic factors affecting the plant?s sensitivity to ozone are reviewed in order to assess implications of these developments for future regional ozone risks. Based on pessimistic IPCC emission scenarios for many cropland regions elevated mean ozone lev...
The article profiles developments in pollution control resulting from the strict emissions control standards due to be set by the European Commission in 1992. In particular technology to meet new emissions targets for mercury and dioxins is described. Control technologies covered included fixed-bed, direct injection, circulating fluidized bed and spray adsorption all of which use activated charcoal to absorb dioxin and mercury. Unfortunately activated charcoal processes still leave waste to be disposed of. Options include recycling the spent activated charcoal to the incinerator, vitrifying the activated charcoal and fly ash into a glassy unleachable substance and cracking the dioxins catalytically. It is hoped the developments will increase public acceptance of incineration. 4 figs., 1 tabs.
California and the Northeast states have passed laws requiring 2% of 1998 cars be `0` emissions vehicles such as electric cars. Electric vehicle technology also can move emissions to less crowd and less polluted locations. However, some other problems remain. The authors focus on the environmental consequences of producing and reprocessing large quantities of batteries to power electric cars, including discussions of both characteristics of Electric Vehicles and batteries and the life cycle of lead and the problems of environmental releases. The authors conclude that electric vehicles will not be in the public interest until they pose no greater threat to public health and the environment than do alternative technologies such as vehicles using low-emission gasoline. 19 refs., 1 tab.
Disclosed is a gas-fired cooktop for a range which provides high thermal efficiency and low emissions of air pollutants, particularly low levels of NO{sub x}. The cooktop includes a perforated tile burner which radiates infrared energy upward at a high flux rate to rapidly quench burner gas temperatures and inhibit the formation of NO{sub x}. A perforated glass-ceramic jet plate positioned between the burner and a cooking vessel transmits most of the radiant infrared energy from the burner to the vessel and also forms jets of combustion products which are directed against the bottom of the vessel fo convective heating. Thermal efficiencies of up to about 70% and NO{sub x} emissions as low as about 15ppM are achieved by the cooktop.
The US Environmental Protection Agency (EPA) conducted a cost-effectiveness (CE) analysis to estimate the incremental cost of complying with the proposed effluent limitation guidelines (ELGs) for the coastal oil and gas industry (EPA 1995a). EPA`s CE analysis calculates the pounds of each pollutant that would be removed if the chosen discharge option is selected. In 1993, EPA issued final ELGs for the offshore oil and gas industry and published an offshore CE analysis. The chemical characteristics of produced water from the offshore region are essentially the same as those of produced water from the coastal region. It was surprising, therefore, that EPA chose a much longer list of pollutants and generally stricter weighting factors for the coastal CE analysis. This report reviews the data, assumptions, and analyses used in EPA`s coastal CE analysis and identifies alternate data, assumptions, and ...
The growing concern of the population with regards to the problem of atmospheric pollution has induced a change in the role of air quality monitoring networks, especially those monitoring air pollution in large cities which suffer from summer smog. The population is no longer satisfied with real-time measurements but wants to be warmed of high pollutants concentrations in advance. Some countries have been forecasting air pollution, and especially ozone, for a large number of years. Although most of them use statistical models based on the analyses of past conditions which induced high pollution episodes, some predict ozone levels using only their knowledge of the meteorological situation. Nowadays two trends appear regarding ozone forecasting: either very basic statistical methods, such as regression, or more sophisticated ones, such as neural networks. The paper then reviews ...
Like other Central European countries, Poland faces the twin challenges of improving environmental quality while also fostering sustainable economic development. In this study we examine the costs of different standards for air pollution control, and the cost savings from using incentive-based policy instruments in lieu of more rigid command-and-control policies. The comparisons are based on the results of a simulation model of energy use and air pollution control for the Polish economy over 1990-2015. The model simulates least-cost energy supply decisions under different environmental policy assumptions, the corresponding emissions, and the cost of achieving the specified policy objectives. The model results suggest that incentive-based policies will have efficiency gains over command policies that are at least worthy of consideration and may be quite substantial. The size of the gains in practice depends in part on how ...
Cesium recovery from the polluted layers in the 1/3 scale hydrogen negative ion source for LHD-NBI system has tested. It was found, that the cesium recovery can be produced by additional discharges as from the cesium layer, aged by tungsten and residual gas, so as from the cesium layers, polluted by an occasional water leak. The highest cesium recovery to NI production was produced by a xenon arc, while glow discharge and arcing in hydrogen were less effective. The mechanism of recovery is the ejection of cesium from the underlying enriched layer by the arc and its transport to the surface. (author)
This bibliography contains citations concerning the control and mitigation of radon pollution in homes and commercial buildings. Citations cover radon transport studies in buildings and soils, remedial action proposals on contaminated buildings, soil venting, building ventilation, sealants, filtration systems, water degassing, reduction of radon sources in building materials, and evaluation of existing radon mitigation programs including their cost effectiveness. Analysis and detection of radon and radon toxicity are covered in separate published bibliographies. (Contains 129 citations fully indexed and including a title list.).
Examples are given of reference materials for radionuclide X-ray fluorescence analysis (RXFA) of the environment processed by the National Bureau of Standards and the IAEA. Methods are described used for preparing standard materials for RXFA. For determining air pollutants the sample is prepared by dry or wet mineralization. Water samples have to be preserved prior to analysis. Insoluble components are separated by filtration or centrifugation. Biological materials must be dehydrated and homogenized. Samples of soil, sludges, sediments and solid wastes will sometimes have to be converted into a solution in some cases a leachate will have to be obtained. (ES).
This environmental assessment quantifies the water quality-related benefits for Transportation Equipment Cleaning (TEC) facilities based on site-specific analyses of current conditions and the conditions that would be achieved by process changes under proposed BAT (Best Available Technology) and PSES (Pretreatment Standards for Existing Sources) controls. The US Environmental Protection Agency (EPA) estimated instream pollutant concentrations for 157 priority and nonconventional pollutants from three subcategories (barge-chemical and petroleum, rail-chemical, and truck-chemical) of direct and indirect discharges using stream dilution modeling. The potential impacts and benefits to aquatic life are projected by comparing the modeled instream pollutant concentrations to published EPA aquatic life criteria guidance or to toxic effect levels.
Present and potential future changes to the global environment have important implications for marine pollution and for the air-sea exchange of both anthropogenic and natural substances. This report addresses three issues related to the potential impact of global change on the air-sea exchange of chemicals: Global change and the air-sea transfer of the nutrients nitrogen and iron. Global change and the air-sea exchange of gases. Oceanic responses to radiative and oxidative changes in the atmosphere. The deposition of atmospheric anthropogenic nitrogen has probably increased biological productivity in coastal regions along many continental margins. Atmospheric deposition of new nitrogen may also have increased productivity somewhat in mid-ocean regions. The projected future increases of nitrogen oxide emissions from Asia, Africa and South America will provide significant increases in the rate of deposition of oxidized nitrogen to the central ...
The world's 500 million road vehicles using internal combustion engines account for roughly half of global oil consumption and, in Italy, for about 50% of all nitrogen oxide and 90% of carbon monoxide emissions. In efforts to conserve petroleum reserves and reduce air pollution, research programs are being conducted to develop hydrogen fueled automotive engines. Hydrogen combustion products are carbon dioxide free, and when burned with a large excess of air, this fuel produces water vapour and only small amounts of nitrogen oxides. Hydrogen fueled vehicles can be made to operate in a dual fuel mode so as to allow the use of petrol or diesel fuel in travel over long distances. Currently, because technical and economic difficulties relevant to hydrogen fuel storage limit driving range and payload (there are bulk and weight problems in compressed gas and metal hydride storage systems, and cost problems in cryogenic storage), ...
A wet air oxidation (WAO) process was applied to four selected pharmaceuticals (metoprolol, naproxen, amoxicillin, and phenacetin) individually dissolved in ultra-pure water, varying the temperature and oxygen pressure. Due to the moderate (amoxicillin) or low (metoprolol, naproxen, and phenacetin) efficiency found in the oxidation of these pollutants, a catalytic wet air oxidation (CWAO) process was then tested using a platinum catalyst supported on multi-walled carbon nanotubes (CNT). In this CWAO process, the pharmaceuticals were dissolved together in ultra-pure water and in four natural water matrices-a reservoir water, a groundwater, and two waters from different municipal wastewater treatment plants. On the basis of the measurements of their removals, a discussion is given of the inf...
In this paper, we calculated the radioactive concentration distribution of radioactive waste water, the temperature distribution of drained cooling water and the effect of implement from the Daya Bay Nuclear Power Plant on nearby waters range, discussed and analysed some problems of computational results and computation with Alternating Direction Implicit Method (ADI). The contents of the article included: the establishment of two-dimension tidal current equation, radioactive waste waterpollutant dispersion equation and cooling water heat convection diffusion equation, the numerical difference calculation model of tidal current field, concentration field as well as temperature field, effect impingement with ADI method, numerical calculation results. The result of research showed that: when the Daya Bay Nuclear Power Plant is on normal operation and after the ...
The major purpose of the work described in this report was to use diffusion modeling techniques to calculate the impact on ambient air quality of SO2 emissions from the ASARCO copper smelter in Tacoma, Washington for the existing smelter configuration (51-percent constant emissions control) and for 20 alternative smelter configurations with varying degrees of constant emissions control. The accuracy of the modeling techniques was established by the close correspondence obtained between calculated and observed short-term ground-level SO2 concentrations for 20 selected historical cases, when high hourly SO2 concentrations were measured in the area surrounding the smelter, as well as by the close agreement between calculated and observed annual average concentrations for 1972. The results of the model calculations show that the maximum allowable constant SO2 emission rate consistent with maintaining the ...
There are several concerns which bring to consider natural gas as a viable alternative to liquid fuels in transport. First, natural gas allows the curbing of global pollution in this steadily growing industry. Indeed, decoupling greenhouse gas emissions from transport growth has become a major issue in tackling climate change. Second, a more extensive use of natural gas would relieve city air quality, which is presently at levels harmful of human health. Nonetheless, this is just one side of the coin. The other side entails building a refuelling station network, and this carries financial requirements. The financing fraction holds a pivotal role in deciding whether natural gas for automotive purposes is an efficient solution. The final aim of this work is, therefore, to compare the natural gas advantages, stemming from avoided global and local emission, with the economic rationale of engaging in supplementary model network ...
The causes and processes of contamination, as well as the possible human health implications for the main contaminants of drinking water are described. The quality of drinking water in Italy is defined through the comparison of the pollutant levels with the World Health Organization guidelines published in 1993 and the USEPA HAs (Health Advisories) of 1994 (annexed to the report).
The objectives of this paper are to document the physicochemical and aquatic toxicological quality of a beneficial-use produced-water discharge and its effect on a receiving stream in Wyoming. Fish and water-flea survival, growth, and reproduction tests indicated that the discharge and all other sampling stations passed the state effluent biomonitoring acute toxicity testing endpoints. while benthic macroinvertebrates were absent at the discharge point designated by the Natl. Pollutant Discharge Elimination System (NPDES), productive and reproducing populations were present at all other downstream and mixing-zone stations. This investigation confirmed the validity of the beneficial-use subcategory for this oilfield discharge.
Increasing economic and recreational opportunities, attractive scenery and a perception of a better quality of life are luring people to the coast. Unfortunately, these activities together with the commensurate increase in population in the area inevitably result in pollution of coastal waters with excessive microorganisms and other pollutants. Microbial pollutants not only contaminate the coastal water but also aquatic food sources, thus posing a health risk to consumers. Fish is a major source of protein in Cameroon, especially in the coastal areas. In this study, we investigated the microbiological quality of fish from the Limbe and Tiko beaches in South West Cameroon from May to October 2007. We isolated human pathogenic bacteria from three anatomic sites (skin, gills, intestine) of 50 fish (150 specimens) and investigated their susceptibility patterns to a battery of ...
Mechanisms that govern transport, accumulation and toxicity of persistent pollutants at interfaces in aquatic ecosystems were the foci of this thesis. Specific attention was paid to humic substances, their occurrence, composition, and role in exchange processes across interfaces. It was concluded that: The composition of humic substances in aquatic surface microlayers is different from that of the subsurface water and terrestrial humic matter. Levels of dissolved organic carbon (DOC) in the aquatic surface microlayer reflect the DOC levels in the subsurface water. While the levels and enrichment of DOC in the microlayer generally show small variations, the levels and enrichment of particulate organic carbon (POC) vary to a great extent. Similarities exist between aquatic surface films, artificial semi-permeable and biological membranes regarding their structure and functioning. Acidification and liming of freshwater ...
The As Pontes coal-fired power plant in northwest Spain is the largest single emitter of sulphur dioxide in the 'old' EU15. The plant is also among the largest emitters of nitrogen oxides and carbon dioxide in the region, according to the EPER (European PollutantEmission Register). But Spain has also several other large emitters of air pollutants. The Andorra which is located in the province of Teruel is one of them. The Andorra power plant emitted 209,148 tones of SO{sub 2} in 2002 which makes it the second largest single emitter of SO{sub 2} in the EU15. It also emitts large quantities of NOx. Also in the northwest of Spain, the Composilla and La Robla power plants are the SO{sub 2} and NOx emitters.
The ventilation requirements for decontamination are normally determined with a static calculation method. In some cases, the pollutantemission is intermittent, for example in the car park of an office building, where all the cars enter and leave the place nearly at the same time. Generally, in such a case, the volume of the garage is large, consequently the time constant of the system has a high value. So a static approach would no longer stay accurate and a dynamic evaluation is needed. With the help of some assumptions, calculations remain rather simple and results can be plotted on nomographs or computed on a programmable handheld calculator. The amount of energy saved may appear very large in some cases. A sizing optimization will be required but also remains easy to compute. The paper presents the method of calculation for a single ventilation level and the optimization of a two-level ventilation.
From the beginning of the 90s the analysis of the relationships between economic growth and environmental pressures has been influenced by the Environmental Kuznets Curve hypothesis or inverted-U shaped relationship between environmental pressure and per capita income. Following this hypothesis, once achieved certain income level, more economic growth is followed by environmental quality improvement. In this paper, we analyse and discuss the theories that support this hypothesis as well as the empirical evidence on this subject. Further on we analyse the relationship between per capita income and the main environmental pollutants for the case does not support the hypothesis. The empirical evidence shows that economic growth, by itself, does not entail a pollution reduction. (Author) 35 refs.
This paper summarizes an investigation carried out on Polish terrain occupied by Russian Federation military troops. The investigation identified natural environmental devastation, pollution, and contamination. Quantitative estimation of the devastation and its economic evaluation are provided. The results of the investigation are as follows: 406 ha have been contaminated by petrochemical products; 22.7 ha are chemically polluted; and 6,500 ha of underground water, as well as 17.5 ha of surface water, cannot be classified. On 15,300 ha the soil has been degraded, of which landfills comprise an area of 98 ha. No toxic warfare agents have been detected, nor any radioactivity levels exceeding those characteristic of the given region.
Purpose Nonpoint sources (NPS) pollution has been an important cause for water quality impairment worldwide. To take the temporal variations of both NPS pollution and in-stream attenuation into consideration, an inverse modeling approach and the load duration curve (LDC) method were combined for variable nutrient total maximum daily load (TMDL) development. Methods Water quality and hydrological parameters were monitored monthly along the ChangLe River system in 2004?2008. The catchment NPS export load (EL) and TMDL for total nitrogen (TN) were estimated by the inverse format of an existing stream nutrient transport equation. The LDC method was used to describe the variability of EL, TMDL, requiring load (RLR) and percent (the ratio between the RLR and the EL, RPR) reduction, and then to s...
Summary 1. The EU -Nitrates Directive- (Directive 91/676/EEC) and the WFD (Water Framework Directive 2000/60/EEC) introduced a series of measures designed to reduce and prevent waterpollution caused or induced by nitrates from agricultural sources. Therefore, there is an urgent requirement to control the nitrate concentration in freshwater. The objective of this paper was to verify the potential capacity of a specifically designed afforested riparian zone in removing the excess of nitrogen from river water. 2. A buffer zone was set with irrigation ditches, to produce a subsurface water flow carrying water from the study river through the buffer strip to drainage ditches. This experimental system enables the co-occurrence of two main processes: vegetation/microbial nitrogen uptake and deni...
The 1993 Petroleum Hydrocarbons Conference was comprised of 3 days of technical presentations within the following topic areas: pollution prevention and cost control; development of remediation levels; free-phase and dissolved hydrocarbon contamination management; investigation and analysis of petroleum hydrocarbons; applications of computer modeling for remediation; design and implementation of bioventing; design and implementation of air sparging; soil vapor extraction as a remediation technique; and ground water remediation using natural bacteria. In addition, more than 100 leading companies in the ground water and petroleum industries participated in the Conference Exposition in which a variety of equipment and services for preventing, detecting and remediating ground water contaminated by petroleum hydrocarbons and other organic chemicals was showcased. Individual papers have been processed ...
In designing automatic water quality monitoring networks for a river basin, determination of measurement locations and items is critical to the effectiveness of the total system. In this paper we studied how to decide these two design factors when a monitoring network is designed for the purpose of water quality surveillance and emergency alarm. For measurement locations, candidate sites are chosen based on the intake amount for water supply and the point sources of contamination. Then, detailed locations are decided according to the contaminant flow distance. As for measurement items, characteristics and the accident history of waterpollution in the basin must be taken into account. Considering economic aspects, we proposed a two-stage measurement plan: basic components for all locations and selective ones variable for different locations. Proposed methodology is demonstrated ...
Human activities in the karst Ozark Plateaus can impact water quality of springs where surface water is rapidly transferred to subsurface conduits. Bennett Spring, in southern Missouri, is the fourth largest spring in the state and supports local tourism activities. Questions regarding poorly functioning on-site wastewater systems (OWS) have raised concerns over the long-term water quality of the spring. This study reports the results of a surface water quality monitoring program in the recharge area where monthly samples were collected at base flow to identify potential pollution sources to the spring. Base flow hydrology of the recharge area was highly variable over the study period, which was drier than normal, causing an incomplete sampling record due to no flow conditions at some site...
For Stage II of the European Dioxin Project the following objectives were set: - Amendment of existing emission data collected for most relevant emission sources in order to reduce uncertainties of emission estimates. Collecting first emission data from countries not yet performing dioxin emission measurement programs. Extending the inventory of dioxin emissions to ambient air produced in Stage I by a complementary study on emissions to land and water. Extending the regional scope of data collection to countries in Central Europe. The report of Stage II of the European Dioxin Project is presented in 3 Volumes. Volume 1 contains an overview on the background and approach of different activities carried out and on the results obtained. These results are put into a broader view regarding the dioxin reduction measures in ...
In May 1985, a National Pollutant Discharge Elimination System permit was issued for the Oak Ridge Y-12 Plant, a nuclear weapons components production facility located in Oak Ridge, Tennessee, and operated by Martin Marietta Energy Systems, Inc., for the US Department of Energy. As a condition of the permit, a Biological Monitoring and Abatement Program (BMAP) was developed to demonstrate that the effluent limitations established for the Oak Ridge Y-12 Plant protect the classified uses of the receiving stream (East Fork Poplar Creek), in particular, the growth and propagation of fish and aquatic life, as designated by the Tennessee Department of Health and Environment. A second purpose for the BMAP is to document the ecological effects resulting from implementation of a waterpollution control program that will include construction of nine new wastewater treatment facilities over the next 4 years. Because of the complex ...
There is a great demand for the reduction of specific fuel consumption in diesel engines, and also of NO/sub x/ emission in especially those designed for use on land. However, while improving combustion, a problem arises in trying to reduce both simultaneously because the techniques required are contradictory. This series of experiments was done to study the correlation between specific fuel consumption and NO/sub x/ emission. The research was conducted under variations in engine parameters and operating conditions. The variations studied included effects of pressure, temperature and humidity of the charging air, temperature of the cooling water, timing and rate of fuel injection, fuel injection nozzle, EGR and water-emulsified fuel. The results of the tests clarified the characteristics of the specific fuel consumption and NO/sub x/ emission and indicated that the most-effective ...
Since the 1970s, Danish electricity supply has been dependent on imported coal. This has lead to greater reliability of supply, as could be seen during the Gulf War when Danish electricity prices remained stable in contrast to conditions in other countries. The disadvantage is the air pollution caused by coal combustion. This is regulated, it is stated, by several international laws and agreements, and these are named here. The nature of this form of pollution is explained in relation to actual Danish power plants and their efforts to reduce emissions of sulphur dioxide and nitrogen oxides. Carbon dioxide, which is a greenhouse gas, is also emitted. Danish environmental policy concentrates on these problems. The efforts of the electric power companies to reduce air pollution are detailed, both nationally and internationally, and their positive consequences are described. Desulphurization and ...
An analysis is given of the problems which can be solved by the use of electric-powered vehicles. A detailed comparison is made of the energy consumption and the air pollutingemissions of electric and conventional vehicles, taking into account the energy consumption of the vehicles and the primary energy consumption of electric power generation and automotive fuels production. Also the air pollution, as a result of power generation and fuel production are considered. In chapter 1 an outline is given of the traffic and transportation sector in the Netherlands with special attention to data on the energy consumption and the air pollution of this sector. Based on these data the problems can be formulated for which the application of electric vehicles can be a solution. In chapter three a brief description is given of the technical specifications and characteristics of electric vehicles. Special attention ...
The Executive Body adopted the Protocol on Heavy Metals on 24 June 1998 in Aarhus (Denmark). It targets three particularly harmful metals: cadmium, lead and mercury. According to one of the basic obligations, parties will have to reduce their emissions for these three metals below their levels in 1990. The Protocol aims to cut emissions from industrial sources, combustion process and waste incineration. It lays down strighten limit values for emissions from stationary sources and suggests best available techniques (BAT) for these sources, such as special filters or scrubbers for combustion sources or mercury-free processes. The Protocol requires parties to phase out leaded petrol. It also introduces measures to lower heavy metal emissions from other products, such as mercury in batteries, and proposes the introduciton of management measures for other mercury-containing products, such as electrical ...
Increasingly stringent pollution regulations have spurred a broad interest in the reduction of engine emissions. Two strategies can be considered: after-treatment or engine emissions reduction. For Diesel engines, after-treatment has a high cost induced by the required technology and implementation issues. In this context, the Highly Premixed Combustion combustion mode (HP C) has emerged as a topic of major interest in recent years. It represents one of the most promising ways for new generation of CI engines using high Exhaust Gas Recirculation (EGR) rates. Experimentation on the test bench brought the proof of significant emission reduction. However, actual vehicle implementation implies frequent transient which fall far beyond steady state experimentation on the test bench. Several key challenges have to be addressed. With this combustion technology; accurate torque balancing at all engine modes is a ...
Oil and gas resources in the offshore areas of the US constitute a significant portion of US recoverable hydrocarbon resources. The exploration, development and production of these offshore resources in California, however, could have significant air quality implications for coastal air basins. This study was developed to address a problem that frequently arises with offshore air quality assessments. Typically, such assessments are performed for a specific activity scenario (e.g., a Federal OCS Lease Sale involving a projected number of drilling rigs, platforms, pipelines, etc.) and assume a projected (but uncertain) level of recoverable oil and gas resources. This study enables interested parties to estimate air emissions and impacts for a wide range of OCS-related development scenarios. The modular emission calculation procedure and the generic impact assessment provide for maximum flexibility in reassessing the emissions ...
The concept of oxygen enriched air applied to reciprocating engines is getting renewed attention in the context of the progress made in the enrichment methods and the tougher emissions regulations imposed on diesel and gasoline engines. An experimental project was completed in which a direct injection diesel engine was tested with intake oxygen levels of 21% -- 35%. Since an earlier study indicated that it is necessary to use a cheaper fuel to make the concept economically attractive, a less refined fuel was included in the test series. Since a major objection to the use of oxygen enriched combustion air had been the increase in NO{sub x} emissions, a method must be found to reduce NO{sub x}. Introduction of water into the engine combustion process was included in the tests for this purpose. Fuel emulsification with water was the means used here even though other methods could also be used. The teat ...
...limited to, emission control devices, pumps, filters, muck cookers, stills, solvent tanks, solvent containers, water separators...facility that meets the conditions of § 63.320(g). Muck cooker means a device for heating perchloroethylene-laden...
In February 2001, the Minister of Environment Canada outlined a series of measures to be implemented over the next decades to reduce emissions from vehicles, engines and fuels. The agenda includes the development of new regulations under the authority of Part 7, Division 5 of the Canadian Environmental Protection Act (CEPA) to align Canada's emission standards for on-road vehicles with those of the United States Environmental Protection Agency. This paper presents a detailed summary of comments received by the interested parties that appeared at a public consultation in November 2001 to discuss and raise issues about the proposed regulations. The parties that provided submissions included: governments; the vehicle and engine manufacturing industry; the oil industry; other groups of associations such as the Canadian Trucking Alliance, David Suzuki Foundation, and West Coast Environmental Law; and, five private individuals. The report ...
The Clean Air Act establishes New Source Review (NSR) programs that apply to the construction or modification of major stationary emissions sources. In 2002 and 2003, the U.S. Environmental Protection Agency revised its rules to narrow the applicability of NSR to facility renovations. Congress then mandated a National Research Council study of the effects of the rules. An electricity-sector model - the Integrated Planning Model (IPM) - was used to explore the possible effects of the equipment replacement provision (ERP), the principal NSR change that was to affect the power-generation industry. The studies focused in particular on coal-fired electricity generating units, EGUs, for two reasons. First, coal-fired EGUs are important contributors of these pollutants, accounting for approximately 70 and 20% of nations SO{sub 2} and NOx emissions in 2004, respectively. Second, the shares of total capacity of large coal-fired EGUs ...
This paper reviews three key initiatives undertaken in the historical city of Oxford to bring about reductions in energy-related CO_2 emissions on a city-wide scale. The author has been part of all the three initiatives. In 2002, a collaborative partnership between academia, industry and city council started the Oxford Solar Initiative (OSI) which uses a community-based approach to help households and organisations in Oxford, financially and technically, to install solar energy systems and energy efficiency measures in buildings. So far OSI has facilitated the installation of 80 active solar systems, over 450 energy efficiency measures and 3,000 low energy bulbs. The scientific basis of OSI is a GIS-based DECoRuM model which estimates and maps baseline energy use and CO_2 emissions on a house-by house level, identifies 'pollution' hotspots, predicts the potential for reductions in CO_2 emissions and ...
Full text.Lead is a toxic heavy metal. Nevertheless, it has been mined and used for more than 800 years. Among the different contemporary sources of lead pollution, emissions from the combustion of leaded gasoline is of particular concern, as it can constitutes more than 90 percent of total lead emissions into the atmosphere in congested urban areas. Concentrations of lead in air and blood are strongly correlated with gasoline lead content and traffic volume. As a result of the increasing awareness about the dangers of lead to human health and the measures to manage urban air pollution, the use of leaded gasoline has been decreasing worldwide. In Lebanon, in the absence of policies to reduce the use of lead in gasoline or to favor the use of unleaded gasoline, leaded gasoline is the predominant grade. The objective of this research work is to analyze the current status of gasoline, and to assess the ...
To diversify the mix of domestic energy resources and to reduce dependence on imported oil, ethanol is widely investigated for applying in combination with Diesel fuel to reduce pollutants, including smoke and NOx. Present work aims at developing a fumigation system for introduction of ethanol in a small capacity Diesel engine and to determine its effects on emission. Fumigation was achieved by using a constant volume carburetor. Different percentages of ethanol fumes with air were then introduced in the Diesel engine, under various load conditions. Ethanol is an oxygenated fuel and lead to smooth and efficient combustion. Atomization of ethanol also results in lower combustion temperature. During the present study, gaseous emission has been found to be decreasing with ethanol fumigation. ...
The report gives background design data for a specific copper smelter. The data is sufficiently detailed to allow air pollution control system engineering studies to be conducted. These studies will be concerned primarily with lean SO/sub 2/ streams that currently are not being captured. Physical layout of the smelter and the surrounding area is presented, along with existing control equipment. Ductwork that would be considered for future system tie-in is defined. Emissions from operating equipment, gas flow rates, temperatures, sulfur balance, and a process flow sheet are included. Utilities, stack dimensions, footing requirements, and solid waste handling are defined. Available area for new control equipment, gas characteristic variation, and potential new control equipment installation problems are discussed. Portions of this document are not fully legible. (GRA)
The report gives background design data for a specific copper smelter. The data is sufficiently detailed to allow air pollution control system engineering studies to be conducted. These studies will be concerned primarily with lean SO/sub 2/ streams that currently are not being captured. Physical layout of the smelter and the surrounding area is presented, along with existing control equipment. Ductwork that would be considered for future system tie-in is defined. Emissions from operating equipment, gas flow rates, temperatures, sulfur balance, and a process flow sheet are included. Utilities, stack dimensions, footing requirements, and solid waste handling are defined. Available area for new control equipment, gas characteristic variation, and potential new control equipment installation problems are discussed. (GRA)
We investigate how corruption influences the income level at the turning point of the relationship between sulfur emissions and income, using a wide cross-national panel of countries, at different levels of development and with different degrees of corruption. Our results support the Environmental Kuznets Curve hypothesis for sulfur. We find evidence that the higher the country's degree of corruption, the higher the per capita income at the turning point, suggesting different income-pollution paths across countries due to corruption. We build upon a new specification for the EKC developed by Bradford et al. (2005) that avoids using nonlinear transformations of potentially nonstationary regressors in panel estimation. Also, we account for the indirect impact of corruption on emissions throu...
Volatile organic compounds (VOC) are an important group of pollutants with adverse effects on humans and the environment. Primary air pollution abatement measures aim at prevention or reduction of pollutant production in industrial production processes, e.g. by improved processes but also by other methods (closed cycle processes, different process materials, etc.). If these measures have been implemented and emissions are still too high, an off-air purification unit must be installed. Biological purification is the method of choice for low pollutant concentrations. Biological purification processes are based on the activity of microorganisms which are capable of biochemical oxidation of organic and some inorganic gaseous compounds into non-polluting or non-odorous compounds. These processes have the advantage that they work at ambient conditions and therefore ...
Denting studies have been undertaken in order to assess the influence of the most important parameters which could initiate corrosion of the carbon steel occurring in the tube-tube support plate crevices of some PWR steam generators. Tests have been carried out in model boilers where feedwater was polluted with sea or river water. Specific effects of chloride or sulfate and influence of oxygen content, magnetite addition and pH value were investigated. In magnetite prepacked crevices, denting is obtained within 1000 hrs for seawater pollution of 0.3 ppm chloride at the blowdown. In neutral chloride or in river water, denting is observed only with oxygen addition. Denting prevention is effective in the case of an on-line addition of phosphate, boric acid, or calcium hydroxide. For denting stopping, boric acid or calcium hydroxide is efficient even with a high seawater pollution. ...
A case study is presented where an integrated, ecologically relevant exposure assessment is presented for a polluted lowland river. Using partial least squares regression of latent structures (PLS), an analysis of the impact of two effluents on physico-chemical water quality measures, macroinvertebrate and diatom communities, and in situ bioassay responses with four different test species are combined into an integrative exposure assessment. Bioassays focussed on growth and condition related endpoints, because they are key functional processes of organisms and populations. Integrating these multiple lines of evidence, we were able to discriminate among the impact of both effluents, link changes in physico-chemical water quality with bioassay endpoints and ecological quality of the ecosystem, and address the importance of integrating all information into one exposure assessment framework. The bioassays under field conditions ...
;Table of Contents: Gaseous PollutantsEmissions from Coal Combustors and Their Control Technologies in Japan; Simultaneous Determination of Cooper (II) and Iron (III) Using 8-Quinolinol by Solvent Extraction Flow-injection Method; Fundamental Studies on Red Mud as a Catalyst for Coal Liquefaction: Studies on Active Components in Red Mud and Possibilities for Improvement of Its Catalytic Activities; Elution Behavior of Coal-derived Liquids with Sephadex LG-20; Characteristic of Activated Carbon Produced from Scrap Tires at Different Activation Temperatures; Energy Saving Snow Melting System.
This work develops and demonstrates a laboratory-scale high temperature natural gas furnace that can operate with/without oxygen enrichment to significantly improve energy efficiency and reduce emissions. The laboratory-scale is 5ft in diameter & 8ft tall. This furnace was constructed and tested. This report demonstrates the efficiency and pollutant prevention capabilities of this test furnace. The project also developed optical detection technology to control the furnace output.
Environmental targets and saving energy have become ones of the world main concerns over the last years and it will increase and become more important in a near future. The world population growth rate is the major factor contributing for the increase in global pollution and energy and water consumption. In 2005, the world population was approximately 6.5 billion and this number is expected to reach 9 billion by 2050 [United Nations, 2008. (www.un.org), accessed on July]. Water supply systems use energy for pumping water, so new strategies must be developed and implemented in order to reduce this consumption. In addition, if there is excess of hydraulic energy in a water system, some type of water power generation can be implemented. This paper presents an optimization model that determines the best hourly operation for 1 day, according to the electricity ...
The physical foundations and methodology are described of radionuclide X-ray fluorescence analysis. The sources are listed of air, water and soil pollution, and the transfer of impurities into biological materials is described. A detailed description is presented of the sampling of air, soil and biological materials and their preparation for analysis. Greatest attention is devoted to radionuclide X-ray fluorescence analysis of the components of the environment. (ES).
This book presents the papers given at a conference on offshore platforms. Topics considered in this book include risk assessment, crack propagation, fracture control, stress corrosion, the reliability of pile foundations, the thermal conductivity of offshore pipeline coating material, economic analysis, hydrodynamics, simulation, Arctic structure design, composite materials, buoys, deep water drilling, corrosion protection, pollution control equipment, and subsea exhaust gas compressors.
Besides industrial agglomerations suffering from excessive pollution of water, air, and soil, there are areas in the German Democratic Republic where beautiful scenery at first glance seems to be intact owing to the absence of large industries. That environmental problems exist also in the coastal regions of the German Democratic Republic is shown in this report. Some of the environmental sins mentioned, which are due to human failure, would seem to the editor to be not just GDR specific. (orig.).
This report assesses the water quality related benefits that would be expected if the US Environmental Protection Agency (EPA) adopts the proposed effluent limitations, guidelines and pretreatment standards for the Centralized Waste Treatment (CWT) Industry. EPA estimates that under baseline conditions 205 CWT facilities discharge approximately 5.22 million lbs/year of metal and organic pollutants.
DescriptionThe importance of inorganic nitrate for the nutrition and growth of marine and freshwater autotrophic phytoplankton has long been recognised, in particularly because of the 'blooms' formed in nitrate and phosphate pollutedwater and their possible roles as carbon dioxide sinks. By contrast, the utilisation of nitrate by heterotrophic bacteria has historically received less attention. Up until now, the primary role of heterotrophic bacteria has classically been considered to be the decomposition [continued...
A study was made of the timber products processing point source category, for the purpose of developing information to assist the EPA in establishing effluent limitations guidelines and standards to implement sections 301, 304, 306, and 307 of the Federal WaterPollution Control Act Amendments of 1972. The document is the result of that study.
High nitrate contents (up to 200 mgl) has been observed in wells drilled into fractured aquifers lying beneath layers of weathered and decayed rock in the humid tropics where annual rainfall is over 1,000 mm and where there is no notable pollution. The source of the nitrates is linked mainly with localized deforestation by man.
This bibliography contains citations concerning theoretical aspects and industrial applications of activated charcoal. Topics include absorption capacity and mechanism studies, kinetic and thermodynamic aspects, and properties descriptions and evaluations. Applications include utilzation in water analyses and waste treatment, air pollution control and measurement, and in nuclear facilities. (This updated bibliography contains 160 citations, 14 of which are new entries to the previous edition.)
This bibliography contains citations concerning theoretical aspects and industrial applications of activated charcoal. Topics include absorption capacity and mechanism studies, kinetic and thermodynamic aspects, and properties descriptions and evaluations. Applications include utilization in water analyses and waste treatment, air pollution control and measurement, and in nuclear facilities. (This updated bibliography contains 150 citations, 14 of which are new entries to the previous edition.)
Polyethylene pipes and connections are being widely used in treated water distribution services. Migration of low molecular weight compounds from the polyethylene into the water can change its final quality. This paper is about the concentrations and identification of the migration compounds found in treated water after staying in contact with low and high-density polyethylene. Identification and quantification were carried out using CLSA (Closed Loop Stripping Analysis) extraction technique and gas chromatography coupled to mass spectrometry (HRGC/HRMS). (Author) 12 refs.
The article describes the state of the energy in Lebanon. In 1996, Lebanon consumed 4647 Ktoe as a primary energy. 97% of this energy is imported mainly polluting oil products: 1623 Ktons fuel-oil, 1379 Ktons gasoline, 930 Ktons diesel, 200 Ktons coal, 124 Ktons LPG, 107 Ktons jet-fuel/Kerosene, 109 Ktons Asphaltic products. The remaining 3% of the energy consumption is renewable energy. As for production, the state owns two refineries which are not used anymore. The year 2000 plan includes an expansion project for the Tripoli refinery and an alternative plan for the Zahrani refinery. These refineries require a total investment in order to reach a production capacity of 50000 barrels a day. The article is a description of the pollution type sources and location in Lebanon. The combustion of the total energy produces yearly more than 15 Ktons of dust, 85 Ktons of SO_2, 40 Ktons of NOX and 3500 Ktons of CO_2. Another risk of ...
This report documents radionuclide air emissions from the Hanford Site in I998 and the resulting effective dose equivalent to the maximally exposed individual (MEI) member of the public. The report has been prepared in accordance with the Code of Federal Regulations, Title 40, Protection of the Environment, Part 61, National Emission Standards for Hazardous Air Pollutants (40 CFR SI), Subpart H, ''National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities,'' and with the Washington Administrative Code Chapter 246-247, Radiation Protection--Air Emissions. The federal regulations in 40 CFR 61, Subpart H; require the measurement and reporting of radionuclides emitted from Department of Energy facilities and the resulting offsite dose from those emissions. ...
The article has three sections. The first discusses the environmental problems the tanker traffic poses to the Norwegian coastal waters and shores. Various precautionary measures and requirements are briefly presented. The size of the present marine transportation and the future Russian marine petroleum activity in the Barents area are briefly mentioned. The second named, conflicting exploration drilling, presents the conflicting interests regarding exploratory drilling in the Barents Sea in Norway. The environmental problems are large and have lead to an on-going reevaluation. Some pollution abatement measures are mentioned. The regional economic development is briefly outlined. The third deals with the Norwegian governmental safety activities and presents a brief survey of the official safety activities in the petroleum sector in Norway and the international cooperation particularly with the Russian Federation. The emphasis is on the maritime ...
Among the several chemical processes conducted for the removal of organic matter present in wastewaters coming from some agro-industrial plants (wine distilleries, olive oil mills, etc), the oxidation by ozone has shown a great effectiveness in the destruction of specially refractory pollutants: it is demonstrated that the biodegradability of those wastewaters increases aflcer an ozonation pretreatment. Their great pollutant character is imputed to the presence of some organic compounds, like phenols and polyphenols, which are toxic and inhibit the latter biological treatments. In this research, a competitive kinetic procedure reported by Clurol and Nekouinaini is applied to determine the degradation rate constants by ozone of several phenolic acids which are present in the wastewaters from the olive oil obtaining process. The resulting kinetic expressions for the ozonation reactions are useful for the successful design and operation of ozone ...
Japanese companies have developed suitable cleansing technologies and export their know-how. Some original technologies are developed today, like: in-situ chemical oxidation, iron confinement, hot-soil process, low-temperature catalytic decomposition or dechlorination of dioxins. However, some pollutions are still poorly considered (nitrates) or badly mastered (dioxins). This situation is partly due to late legal decisions and to limited pollution abatement measures. Japan is also very active in bio-cleansing research, and this, despite the lack of dialogue and directives at the national level. Several research programs with important funds have started since 1995. However, Japan is still at the preliminary stage in open-field applications of cleansing methods. (J.S.)
NO{sub x} compounds, specifically NO and NO{sub 2}, are pollutants and potent greenhouse gases. Compact and inexpensive NO{sub x} sensors are necessary in the next generation of diesel (CIDI) automobiles to meet government emission requirements and enable the more rapid introduction of more efficient, higher fuel economy CIDI vehicles. Because the need for a NO{sub x} sensor is recent and the performance requirements are extremely challenging, most are still in the development phase. Currently, there is only one type of NO{sub x} sensor that is sold commercially, and it seems unlikely to meet more stringent future emission requirements. Automotive exhaust sensor development has focused on solid-state electrochemical technology, which has proven to be robust for in-situ operation in harsh, high-temperature environments (e.g., the oxygen stoichiometric sensor). Solid-state sensors typically rely on yttria-stabilized zirconia ...
An Environmental Management Plan (EMP) for the Jharia Coalfield (JCF) was recently completed as part of a World Bank funded project. The JCF, 260 km west of Calcutta, comprises 450 km{sup 2}. Bharat Coking Coal Limited (BCCL) operates an area of 258 km{sup 2}. Coal mining has been conducted for more than 100 years. There are severe constraints to mining due to geology, coal fires and the large population. BCCL counterpart staff participated actively in all aspects of the work. Air and water are heavily polluted, however, mining operations contribute only to a limited extent to the total pollution. Water contamination is generally due to inadequate sewage treatment and discharge from non-mine facilities such as power plants. The large area disturbed by mining to date will increase, as open pit mining operations are expected to expand significantly. Reclamation to date is generally confined to planting of ...
Development was explained of non-phosphate detergent with zeolite (Z) and alpha-olefin sulfonate (AOS). 4A type Z was taken notice of as a builder to replace phosphate. In calcium ion trapping power, conventional sodium tripolyphosphate (STP) and Z are 158mgCaO/g and 150mg/g, respectively. However, because Z by the conventional method is large in crystal diameter, coagulates and adheres to matter to be washed, was newly developed fine Z, 0.9 {mu} m in primary grain diameter, which does not give abrasion nor occlusion to the washing machine, nor precipitate in the river. Because linear alkylbenzene sulfonate, combined with Z, is poorer in washing power than that, done with STP, was developed AOS, new non-phoshate use interfacial active detergent, which is excellent in all washing power, biodegradation speed and physical powder property. Improvement was variously made also in powdery detergent production technology. Though the non-phosphate detergent controlled water ...
Polycyclic aromatic hydrocarbons (PAH`s) are ubiquitous hydrophobic organic pollutants in the marine environment. Many of the PAM`s are classified as possible carcinogens or mutagens, therefore they are of considerable concern to human and environmental health. The highest concentrations are found in coastal regions due to anthropogenic activities including oil spills, tanker operations, incomplete fossil fuel combustion and runoff. The sources and distribution of PAM`s in sediments are fairly well known, while the fate and transport of PAH`s in the marine environment are less known. Desorption is an important factor influencing the fate and transport of hydrophobic molecules at the seawater/sediment interface. The desorption of PAH`s from contaminated marine sediments to the water column/pore water affects the availability of the pollutant to biota. The sorption of PAH`s is determined in part by the ...
Macroinvertebrate communities in Rietvlei nature reserve wetland area and their relationship with water quality were studied with the aim to evaluate their use as potential indicators of pollution. Sampling locations were selected to include outlets from swage effluent, agricultural and informal residential runoff. A large increase in nutrient concentrations was observed downstream from discharged treated sewage with an associated decrease in species richness. Bioassays performed included: Daphnia magna, Hydra attenuate, Lactuca sativa, Allium cepa and Pyxicephalus adspersus. The highest percentage of lethality response to a screen (100% concentration) of sampled wetland water by test specimens were observed at the point source input of the Hartbeespoort treated sewage plant. Data generated from the AUSRIVAS method and multitrophic level bioassays revealed the deterioration of the wetland possibly due to factors such as ...
The evolution of the technology of waste combustion, energy recovery and flue gas treatment allows to redefine the role of the incineration plant as a basic component of integrated waste management systems. Starting with an overview of the evaluation of emission limits and of the new Best Available Techniques (BAT) approach, strongly recommended by the European Union, the paper reports an overview of the stack emission concentrations measured in recent plants in Italy compared to older ones, with special attention to the dioxin issue. Concerning this topic, it is demonstrated that BAT-equipped plants can act as actual dioxin destroyer rather than producers, even when all the fluxes released in the environment (gaseous, solid and liquid residues) are taken into account. The second part of the paper deals with the evolution of the flue gas control technologies of the last 20 years, pointing out the major trends and the future perspectives for ...
Nuclear energy provides a third of Europe's electricity with nearly no greenhouse-gas emissions. Sustained efforts are now being conducted to harmonize regulations all over Europe through WENRA and to converge on technical nuclear safety practices within the TSO network ETSON (European Technical Safety Organizations Network). In CANDU type NPP the tritiated water occurs by the neutron bombardment of deuterium. The tritiated water vapors imply health hazard (in the critical organs of the body the water presents a 10 day average biological half-life) and the early detection in nuclear plants of tritium emissions is important because the tritiated water vapors have the same characteristics as of atmospheric water vapors. By detecting tritiated vapors, the monitoring system ensures the following objectives: (a) indicates levels of tritium ...
In 2003, Vehicle Emissions Team of the Clean Air Strategic Alliance (CASA) decided to explore ways to reduce vehicle emissions such as particulate matter, nitrogen oxides, carbon monoxide, and hydrocarbons from diesel engines. One of the options for reducing emissions from diesel engines, a diesel particulate filter (DPF), is the subject of a demonstration project to test the effectiveness of the Johnson Matthey diesel particulate filter called Continuously Regenerating Technology (CRT) under cold weather conditions. The project involved filter testing between January 2003 and January 2004 on two diesel buses in Edmonton Transit System's (ETS) fleet. Vehicle exhaust emissions were tested for total hydrocarbons, nitrogen oxides, carbon monoxide, carbon dioxide, and particulate matter. The objectives of the project were to: prove the effectiveness of DPF under cold weather conditions in Alberta; ...
Agricultural runoff is a major non-point source pollutant and is the leading impairment of streams and rivers in the USA. This study examined the effects of agricultural, forest and urban land cover on water quality at the watershed level. Forty-three catchments ranging from 12 to 50?km2 were selected based on a land cover gradient within Lower Kaskaskia River Watershed in Illinois. Grab samples were collected and analyzed for nutrients, bacteria, and total suspended solids (TSS). Forest land cover was included in six of the ten regression models produced. Four of these regression models were for base flow conditions, suggesting that forest land cover had a significant impact on base flow water quality. Urban land cover was also included in six of the regression models. However, the majori...
Haemocyanin serves as normal transporter of oxygen in many Arthropods. The oxygen equilibrium curves have been described for the haemocyanins of many Arthropods and Molluscs. Oxygen equilibrium curves of the blood reveal the relationship between the oxygen tension and the percentage saturation of the haemocyanin. The shape of the oxygen equilibrium curves vary in position from sigmoid to hyperbolic in different animals or even undulatory as shown in some chitons. Oxygen equilibrium curves are known to be influenced by pH, temperature and inorganic ions. The effect of environmental pollutants like the heavy metals on the oxygen equilibrium curves of the fresh water crab has not been previously reported. One of the toxic heavy metals with regard to aquatic organisms is lead. Hence the present study was designed to determine the effect of organic and inorganic lead on the oxygen equilibrium curve of the fresh water crab, ...
After a brief review of the degradations occurring on tubes of Inconel 600 in steam generators of PWR power stations emphasis is put on the conditioning of the secondary water and more particularly on the condensate treatment in the units of Doel which work on heavily polluted brackish water. The important role of non-destructive testing and eddy-current testing is also pointed out, method developed by Laborelec. The operational experience shows that Belgian stations are nearly not concerned by the degradations mostly found in power stations in other countries which shows the efficiency of the conditioning of the secondary water. On the other hand, other problems have occurred, resulting from: damage caused by foreign objects; fouling of tube before commissioning, cracking of bends and at the limit of the dudgeoning and leaking plugs. (AF).
This paperwork explain the method of water sampling to obtain the precipitate of BaCO3 solutions that will be used to analyze 13C from field work in Kelana Jaya, Selangor, Langkawi, Kedah and Taiping, Perak. The sampling involves collecting of water samples for groundwater from boreholes and surface water from canal, river, pond and ex-mining pond from several locations at the study sites. This study also elaborates the instruments and chemicals used. The main purpose of this sampling is to obtain the precipitate of BaCO3 for 13C analysis of dissolved inorganic carbon (DIC). A correct sampling method according to standard is very important to ensure an accurate and precise result. With this, the data from the laboratory analysis result can be fully utilized to make the interpretation of the pollutants movement. (Author)
A field survey on cadmium, lead, copper, and zinc was performed in Semarang, the fifth largest city in Indonesia. Water, sediment, and fish samples were collected from 101 grids of 2 x 2 km. The objectives of the study were (1) to identify the spatial distribution of metals in the sediments of the greater Semarang area, (2) to estimate the background concentrations of the metals present in Semarang, (3) to provide a simple tool for deriving standards for metals in the sediment, and (4) to explore the potential use of the guppy (Lebistes reticulatus) as a bioindicator of urban metal pollution. To map the spatial distribution of the metals, concentrations of each metal in sediment were plotted against the corresponding city coordinate. On the basis of these plots, background concentrations of the metals were estimated. A combined pollution index can be derived thereafter by calculating the difference between metals ...
Water and mud samples were collected from canals and rivers which were adjacent to outlets discharging warm water of 3 power plants in Berlin. Downstream samples from 1 bathing resort were also collected. Free living amoebae were isolated from 138 water and 69 mud samples. From these respectively 156 and 73 strains could be cultured and were administered intranasally to mice for pathogenicity tests. Two Acanthamoeba strains from water and 7 from mud could be reisolated from mouse brain and or lungs, although no pathological disorders could be observed. Five Naegleria strains were negative in mouse inoculation tests. Four Acanthamoeba strains which were positive in mice were cultured at + 45 degrees C; no cytopathogenic effects were observed in tissue cultures. Acanthamoeba infective for mice could also be isolated from samples at low water temperatures. Further investigations have ...
Since 1984 the Environmental Protection Agency (LfU) of the State of Baden-Wuerttemberg has been investigating the heavy metal burden of earthworms from representative long-term forest observation plots. These investigations are aimed at elucidating and assessing adverse effects of pollutants on the soil biocenosis. Methods: At first only lead and cadmium were measured in the worms; in repetitive measurements over the years further metals or metalloid elements such as aluminum, arsenic, chromium, cobalt, copper, manganese, mercury, nickel, thallium, vanadium, and zinc were added to the agenda. Results and conclusion: The frequency distribution of the metals in the earthworms was characterized statistically. For the first time state-wide background values, normal values and threshold values were established for all the elements measured. A comparable study with a similar range of parameters is known neither nationally nor internationally. Time trend studies have ...
In 2004, the Southeastern France regional council asked the regional health observatory to conduct an environmental health inventory to i) identify environmental health problems in this area; ii) examine the relations between environmental exposure to pollutants and human health; and iii) help public officials to identify priorities in this area. We collected and validated data from national, regional and local institutions, constructed environmental (levels of emissions and pollutants), health (mortality, incidence, prevalence) and behavioral indicators (e.g., complaints about odors), and compared these over time and between places when possible. For each topic, we summarized current knowledge about the links between environment and health. In southeastern France, as in other French areas, indoor air pollution, home and leisure injuries and other home-related risks are public health issues. Other ...
The study area is located in the Bekaa plain of Lebanon totaling about 12753 ha. It lies between the eastern foothills of Mount Lebanon chain and expands across the Litani River towards the foothills of the eastern Anti-Lebanon Mountains. Its characteristics, i.e. natural terrain, climate and socio-economy, make it vulnerable especially due to soil pollution. This paper tries to identify the nature and level of soil pollution by heavy metals. Valley slopes represent a complex landform and lithology that contributed to the formation of different soil. Agriculture in the plain is being practiced mainly with cash, field crops and vegetables. Throughout the central part of the plain, groundwater table is abundant and relatively high (<1.0 m. locally) that multiplies the vulnerability of the soil-groundwater system. There are different sources of pollution, such as industrial (tanneries, batteries, leather manufacturing), ...
Current hydrocarbon-based energy systems, current energy consumption and the push towards the utilization of renewable energy sources, fuelled by global warming and the need to reduce atmospheric pollution are discussed. The consequences of climatic change and the obligation of Annex B countries to reduce their greenhouse gas emissions in terms of the Kyoto Protocols are reviewed. The role that renewable energy sources such as hydrogen, solar and wind energy could play in avoiding the most catastrophic consequences of rapidly growing energy consumption and atmospheric pollution in the face of diminishing conventional fossil fuel resources are examined. The focus is on hydrogen energy as a means of storing and transporting primary energy. Some favorable characteristics of hydrogen is its abundance, the fact that it can be produced utilizing renewable or non-renewable sources, and the further fact that its combustion produces ...
In car parks of considerable length, the removal of exhaust emissions, is carried out by air-conditioning systems mainly through transverse ventilation over short routes. The required air-conditioning ducts frequently produce a reduction in the available parking space simply due to their presence, resulting in restrictive effects on the level of acceptance by the users. In such cases, remedial action can be taken by creating ductless longitudinal ventilation. Depending on the required room air quality in the zones with the highest level of pollution, the volumetric flows for longitudinal disposal are no greater than those for conventional transverse ventilation. In conjunction with architecturally clear and positive lighting designs, clearly laid out car parks with a friendly atmosphere can be created which the user will be pleased to accept. (orig./BWI)
Based on wind tunnel experiments, theoretical considerations and measurements the dispersion model CAR (Calculation of Air pollution from Road traffic) has been developed for determining air quality in city streets. CAR International is a simple parameterized model using readily available input data and calculating annual percentile values and average concentrations close to streets (at the kerb side) for non-reactive air pollutants and NO{sub 2}. Originally the model was set up for the Dutch situation (traffic, meteorology) with a system of fixed parameters. In order to extend its application to other countries the program has been made more flexible and user friendly. User defined system data can now be changed interactively, such as emission factors of passenger cars and trucks, fraction of directly emitted NO{sub 2}, city and regional background concentration, and average regional wind speed. The accuracy of the model ...
The DOE is conducting a comprehensive technical analysis of a flexible-fuel transportation system in the United States -- that is, a system that could easily switch between petroleum and another fuel, depending on price and availability. The DOE Alternative Fuels Assessment is aimed directly at questions of energy security and fuel availability, but covers a wide range of issues. This report examines environmental, health, and safety concerns associated with a switch to alternative- and flexible-fuel vehicles. Three potential alternatives to oil-based fuels in the transportation sector are considered: methanol, compressed natural gas (CNG), and electricity. The objective is to describe and discuss qualitatively potential environmental, health, and safety issues that would accompany widespread use of these three fuels. This report presents the results of exhaustive literature reviews; discussions with specialists in the vehicular and fuel-production industries and with Federal, State, ...
A high-temperature flow reactor and different technical plants were tested within the framework of this research project. Anthropogenic N{sub 2}O emissions form during secondary flue gas or waste gas purification as secondary emissions during denitrification and pollution abatement measures. N{sub 2}O forms as an intermediate product as NO is reduced to N{sub 2}. Under certain operating conditions N{sub 2}O is not decomposed completely. Different secondary flue gas purification measures, i.e. selective noncatalytic reduction (SNCR), selective catalytic reduction (SCR), and nonselective catalytic reduction (NSCR) were investigated testing several technical plants and the high-temperature flow reactor. (orig./EF) [Deutsch] Das Forschungsprojekt ``Messung der N{sub 2}O-Emissionen von Verbrennungsanlagen und Untersuchung von Moeglichkeiten zur Emissionsminderung`` wurde an einem Hochtemperatur-Stroemungsreaktor und an ...
A hydrogen combustion and exhaust emissions in a supercharged gas engine ignited with micro pilot diesel fuel was discussed in this presentation. A schematic diagram of the experimental study was first presented. The single cylinder, water-cooled, supercharged test engine was illustrated. Results were presented for the following: fuel energy and energy share (hydrogen and diesel fuel); pressure history and rate of heat release; engine performance and exhaust emissions; effect of nitrogen dilution on heat value per cycle; effect of N_2 dilution on pressure history and rate of heat release; and engine performance and exhaust emissions. This presentation demonstrated that smooth and knock-free engine operation results from the use of hydrogen in a supercharged dual-fuel engine for leaner fuel-air equivalence ratios maintaining high thermal efficiency. It was possible to attain mor3 than 90 per cent ...
This report describes results from emissions testing of a prototype diesel engine, developed by Volvo Truck Corporation of Sweden, which uses pilot injection of diesel fuel for compression ignition of alcohol fuel injection for main combustion. In addition to this dual-fuel engine, emission testing was also conducted on a heavy-duty diesel engine of similar design. Both engines were tested over the 1979 13-mode FTP, or shorter versions of this modal test, and over the 1984 Transient FTP as well as an experimental bus cycle. The dual-fuel engine was characterized with methanol, ethanol and ethanol with 30 percent water (wt %). An oxidation catalyst was also used with methanol and ethanol. Emission characterization included regulated emissions (HC, CO, and NOX) along with total particulate, unburned alcohols, individual hydrocarbons, aldehydes, phenols, and odor. The particulate ...
The first volume of the report covers the state of implementation of primary and secondary measures for SO{sub 2}- and NO{sub x} control applied in the most important industrial sectors in Germany. Integrated pollution abatement techniques, called primary measures in this report, such as process integrated measures and low emission processes, have gained increased importance in recent years. The end-of-pipe processes, described here as secondary measures, are generally highly effective. They represent mature technologies, which are capable of achieving significant reductions in SO{sub 2}- and NO{sub x} emissions, and which have been used in particular for retrofitting existing plants. At first, an overview is given regarding the development of SO{sub 2}- and NO{sub x} emissions in selected European countries during the last 20 years and in Europe. Current national and European ...
Recent changes in the US liability regime for oil pollution damage have intensified a policy debate about environmental liability limits. Economic theory suggests that some type of limit may be needed under certain conditions, and that such a limit should be set so that the marginal social benefit and cost are equal. However, it is unclear how a liability limit may be determined specifically for tanker shipping in US waters. We first examine conditions under which corner solutions (no liability or unlimited liability) are desirable. We then formulate a model to determine a socially optimal liability limit for oil pollution damage in US waters when a non-zero, finite liability limit is desirable. The model captures the tradeoff between less expensive energy supply and more stringent protection of the marine environment. Numerical simulations illustrate the properties of the model and major factors ...
The focus of the present Great Lakes water quality agreement between Canada and the United States is on transboundary pollution and particularly the injury to health and property from exposures to persistent toxic substances. Several scientists and policy advisors have suggested, on the basis of the Ecosystem Approach and systems theory, that the agenda should move on to other demanding topics, such as the introduction of exotic species, biodiversity, habitat restoration, fisheries management, sustainable development, and governance of the Great Lakes basin. None of these issues, however, poses the same scale of threat to national sovereignty and bilateral interests as does transboundary pollution. Thus, none warrants the degree of attention that has been and should be paid, despite declining budgets, to assessing and controlling releases of persistent toxic substances that continue to injure fish, wildlife, and human ...
The improvement of the ecological conditions at waste storing reservoirs is an important task of the restoration activity at Production Association (PA) ``Mayak`` (South Urals). The radionuclides mostly {sup 90}Sr, {sup 137}Cs, and chemical pollutants deposited in the reservoir water and in the bottom sediment are very dangerous sources for the contamination of Techa River below the reservoirs and the contamination of groundwater in the surrounding formations. The spreading of radioactive contaminants has both hydrogeological and the chemical features. The thermodynamic approach used to account for physical-chemical interactions between water and the bed rocks based on Gibbs free energy minimization of multicomponent system (H-O-Ca-Mg-K-Na-S-Cl-C-Sr) permitted the authors to calculate the corresponding ionic and complex species existing in the solutions, and to characterize the processes of precipitation and dissolution. ...
In this study, considering that Hg(2+) in wet flue gas desulfurization (FGD) systems can easily be reduced and then released into atmosphere, causing secondary pollution, the researches about Hg(2+) reduction and Hg(0) re-emission mechanism were carried out. The effects of several experimental parameters on the reduction were studied, including initial pH, temperature, and concentrations of Cl(-) and S(IV). Our experimental results indicated that Cl(-) had a restraining effect on the Hg(2+) reduction and Hg(0) re-emission, after 24h reaction, only 20.5% of Hg(2+) was reduced with 100mM Cl(-) in simulated desulfurization solution. Cl(-) can slow Hg(2+) reduction and Hg(0) re-emissions dramatically through changing reaction mechanism, with formation of new intermediate: ClHgSO(3)(-), which can decompose to Hg(0), but much more slowly than Hg(SO(3))(2)(2-) or HgSO(3). Simulating the conditions of the ...
This report documents the development and use of the Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) model. The model, developed in a spreadsheet format, estimates the full fuel- cycle emissions and energy use associated with various transportation fuels for light-duty vehicles. The model calculates fuel-cycle emissions of five criteria pollutants (volatile organic compounds, carbon monoxide, nitrogen oxides, sulfur oxides, and particulate matter measuring 10 microns or less) and three greenhouse gases (carbon dioxide, methane, and nitrous oxide). The model also calculates the total fuel-cycle energy consumption, fossil fuel consumption, and petroleum consumption using various transportation fuels. The GREET model includes 17 fuel cycles: petroleum to conventional gasoline, reformulated gasoline, clean diesel, liquefied petroleum gas, and electricity via residual oil; ...
This bill was introduced into the US House of Representatives on February 19, 1992 to amend the Federal WaterPollution Control Act for the protection of wetlands. One of the key elements of the bill revolves around the expansion of scope and clarification of the permit program and its effects on wetlands. Additional sections address the following: exemptions for agriculture and other activities; rulemaking on prior converted wetlands; citizen suits amendments; improvement of administration of wetlands permitting; study of wetlands delineation; and wetlands restoration pilot program.
A collection of 14 papers from a June 1981 seminar assess the costs of damage caused by waterpollution. The seminar focused on the economic rather than the legal standpoint by evaluating the cost of the clean-up operations themselves and other costs, such as direct or indirect economic losses, and converting into money terms the damage to the environment, the loss of recreational facilities, and biomass losses. The papers are grouped into four sections which look at the scale of risk, the clean-up costs for specific oil spills, other costs inflicted on coastal zones, and legal aspects of compensation. Separate abstracts were prepared for each of the 16 papers selected for the Energy Data Base.
In this study, we investigate the relationship between income and environmental quality for Turkey at two levels. First, the relationship between the CO2 emissions and per capita income is examined by the help of a time series model using cointegration techniques. In the second stage, the relationship between income and air pollution is investigated by using PM10 and SO2 measurements in Turkish provinces. In this part of the study panel data estimation techniques are utilized. The time series model covers 1968-2003, and the panel data model covers 1992-2001 including observations from 58 provinces. A monotonically increasing relationship between CO2 and income is found in the long-run according to time series analysis. On the other hand, panel data analysis indicates an N-shape relationshi...
Most analyses of the alternative strategies used by utilities to comply with Title IV requirements have focused on factors directly related to controlling sulfur dioxide (SO{sub 2}) emissions. However, utilities must meet a number of additional environmental requirements at the same tune they comply with the acid rain program. To illuminate the potential synergies and conflicts that might exist between the other regulatory mandates and the acid rain program, a thorough examination of all the various programs and their interrelationships must be conducted. This paper reviews the environmental mandates that utilities will have to plan to meet in the next decade concurrently with the acid rain program, and it analyzes the interactions among the various programs to identify potential synergies and conflicts.
Environmental pollution has become a bottleneck for the sustainable economic development of China. A 'business-as-usual' energy system in Chian is not suitable for meeting sustainability needs. It is well known that China has to use coal as the main primary energy source over the long term. Under such special conditions, to plan and construct an integrated sustainable energy system with optimal benefits in resource and energy utilization and environmental emissions is urgent. By introducing international studies and new developments in sustainable energy systems, this paper puts forward the concept that a polygeneration strategy based on coal gasification is the trend for future development of China's domestic energy industry. The framework of a polygeneration system based on oxygen-blown gasification is described and its benefits are analyzed. Finally, the starting procedure, government role, and policies for ...
A survey was undertaken of literature on the conversion of coke-fired cupola furnaces so that they can be fuelled, either wholly or partially, with natural gas. The aim was to determine the most suitable method for a specific furnace. Substitution with natural gas can result in speedier adjustment and control of the smelting process and in addition operational costs are reduced as natural gas is a cheaper fuel. The payback period would be one year. Pollutiveemissions would be reduced. It was concluded that the most satisfactory solution would be that 3-4 gas burners should be placed immediately above the smelting zone in the furnace. Each burner should be placed in a separate combustion box in which the complete combustion process could take place. The burners should be placed symmetrically about the furnace, pointing at a small degree downwards. In this way the combustion chamber will not be filled with materials from the furnace and the ...
A compression ignition engine was operated on dual fuel principle inducting two commercial fuels and four pure hydrocarbon fuels in turn through intake manifold along with air and injecting diesel fuel to initiate the combustion in the conventional manner. The engine was operated at different loads and at each load the quantity of inducted fuel was increased gradually till knocking set in. The engine performance and exhaust pollutantemissions were recorded at different operating conditions. It was observed that the extent of induction and the effect on the performance depend on the properties of the inducted fuel such as volatility, self ignition temperature and oxidation characteristics. The energy release during the cycle was also observed to shift depending on the properties of inducted fuel. With the dual fuel operation, the thermal efficiency at part loads was observed to be less compared to neat diesel operation. The thermal efficiency ...
In evaluating commercialization prospects for natural gas fuelled vehicles, this paper compares the performance and emission quality of these innovative vehicles with those using conventional fuels - gasoline and diesel fuels. Assessments are made of the state-of-the-art of current technology relative to fuel storage, air/fuel mixture preparation, in cylinder combustion processes and pollution control. The analysis evidences that while natural gas is an excellent fuel for spark ignition engines, in transport applications its use is hampered by large storage volume requirements and weight. Moreover, the air/fuel mixture preparation, combustion process and exhaust-gas cleaning require a greater research and development effort to make this alternative fuel economically and environmentally competitive with conventional fuels.
The general objective of the presented work is process intensification by means of reduced furnace chamber volumes in combination with the use of low-NOx burner technologies. Fundamental experimental investigations of the reaction zone of different burner types were made. For the development of new burner designs the CFD code FLUENT was used. Throughout the investigations it was possible to increase the furnace heating density from 62 kW/m3 up to 1133 kW/m3. To demonstrate possible technical applications two simulated industrial furnaces designs have been investigated. One main conclusion the work gave is that process intensification without an increase of pollutantemissions is possible by optimizing furnace and burner design and also position and geometry of the furnace load in a combined strategy. (author)
The general objective of the presented work is process intensification by means of reduced furnace chamber volumes in combination with the use of low-NOx burner technologies. Fundamental experimental investigations of the reaction zone of different burner types were made. For the development of new burner designs the CFD code FLUENT was used. Throughout the investigations it was possible to increase the furnace heating density from 62 kW/m3 up to 1133 kW/m3. To demonstrate possible technical applications two simulated industrial furnaces designs have been investigated. One main conclusion the work gave is that process intensification without an increase of pollutantemissions is possible by optimizing furnace and burner design and also position and geometry of the furnace load in a combined strategy. (author)
This publication contains the Ordinance on Heating Costs, the Ordinance on Heating Installations, and the 1st Federal Ordinance on Emission Control (BImSchV) concerning Small-Scale Furnaces, in each case with notes and explanations. All these ordinances aim at reducing energy consumption in connection with heating; the 1st BImSchV also at air pollution abatement by lowering the permissible limiting values for soot and flue gas. The three ordinances also apply to housing property. (HSCH).
Efforts in industry concerning pollution abatement up to nowadays were aimed at: solid particles contained in gaseous effluents, SO_2 effluent reduction, nitrogen oxide effluent limitation through combustion technology enhancement. Various CO_2 emission scenarios with different energy production means (same or increased nuclear plant number, energy consumption reduction) show that energy conservation schemes for the developed countries are the best solution to CO_2 control. Different solutions for greenhouse gas abatement from industrial plant are reviewed: effluent processing, burner technological enhancement, heat transfer optimization on industrial processes, computer assisted management for industrial processes, plasma technic for refining, substitution of gas to oil in chemistry, etc.
According to the environmental Kuznets curve hypothesis, the relationship between per-capita GDP and per-capita pollutantemissions has an inverted-U shape. This implies that, past a certain point, economic growth may actually be profitable for environmental quality. Most studies on this subject are based on estimating fully parametric quadratic or cubic regression models. While this is not technically wrong, such an approach somewhat lacks flexibility since it may fail to detect the true shape of the relationship if it happens not to be of the specified form. We use semiparametric and flexible nonlinear parametric modeling methods in an attempt to provide more robust inferences. We find little evidence in favour of the environmental Kuznets curve hypothesis. Our main results could be inte...
In order to quantify the biomass burning emissions, the main atmospheric pollution source of tropical and subtropical regions, we carried out the analysis of ashes that are also formed during these fires. To this end, we developed analytical methods to characterize the composition of savannah grass burning ashes by using X-ray fluorescence for mineral elements and microanalysis for C, H, O and N. Samples used in this work have been collected during laboratory combustion experiments, with chemically well-defined natural savannah grasses from Ivory Coasts and South Africa. The reproducibility and efficiency of different developed procedures have been studies. The analytical relative precision is generally better than 5%. This development has allowed to establish, for the first time, the global mass balance of ashes resulting from savannah grass burning. (authors). 16 refs., 3 figs., 8 tabs.
The project is focusing on the formation and growth mechanisms of atmospheric aerosol and cloud droplets. Both aerosol particles and cloud droplets affect strongly on the atmospheric radiation fluxes by scattering and absorption. The droplet formation results from physical and chemical processes occurring simultaneously. The studies concerning the tropospheric cloud droplet formation, laboratory experiments with a cloud chamber and stratospheric cloud formation are summarized. The recent studies summarized in this presentation indicate that both aerosol particles and cloud droplets have a significant role in climatic change and ozone depletion problems. The anthropogenic emissions of gaseous and particulate pollutants change the properties of atmospheric aerosols and cloud droplets. The research in this field will be continued and more quantitative understanding based both experimental and theoretical studies is required
Immobilization of a model liquid organic pollutant, i.e. the 2-chloroaniline (2-CA), into a cement matrix using organoclays as pre-sorbent agents was investigated. Five cement-clay pastes were prepared with different nominal water-to-cement ratios (w/c=0.40, 0.25 and 0.15 wt/wt) and various amounts of waste (waste-to-cement o/c=0.20, 0.60 and 1.00 wt/wt); for comparison, a neat cement paste was also prepared. Dynamic leach tests were performed on solidified monoliths in order to assess the successful immobilization of the 2-CA. In monoliths at constant w/c ratio (0.40) the total amount of pollutant released increases with its initial content, and ranges from 15 to 35% with respect to it. By lowering w/c from 0.40 to 0.15 at constant o/c, the performances improved (<25% released). The microstructure of the hardened cement-clay pastes was characterized by quantitative X-ray diffraction (QXRD) and electronic microscopy ...
Forced convection boiling of subcooled water was performed in a horizontal rectangular channel with heated surface on the bottom. The experiment was conducted for heating surfaces, 10 mm, 20 mm and 40mm in length. Microbubble Emission Boiling, MEB, was observed in subcooled transition boiling and easy to be generated for the shorter heating surfaces. In higher flow velocity of subcooled water, MEB was generated at even lower subcooling. Stormy MEB was observed at both the higher subcooling and the higher flow velocity of water. In the stormy MEB, the heat flux rose up rapidly above CHF (Critical Heat Flux) with larger acoustic noise and vibration. (author)
Combined sewer overflows (CSOs) have been recognised as one of the serious sources of pollution to the water environment during rain events, although field surveys to investigate the effect of their magnitude and duration on receiving waters have been very limited. The fates of enteric viruses (norovirus G1, G2, enteroviruses) and coliforms were determined in the wastewater treatment plant on a fine day and on a rainy day. Not all microorganisms were reduced in the primary treatment, but were reduced in the secondary treatment. Occurrences of enteric viruses and levels of coliforms were surveyed in the receiving coastal area after a CSO event, with the profiles of the enteric viruses in the coastal seawater being almost at the same positive ratio for 4 d after the CSO event. PMID:15318519
Environmental data were collected for most environmental media including air, Columbia River water, external radiation, foodstuffs (milk, beef, eggs, poultry, and produce) and wildlife (deer, fish, and game birds), as well as soil and vegetation samples. In general, offsite levels of radionuclides attributable to Hanford operations during 1979 were indistinguishable from background levels. The data are summarized in the following highlights. Air quality measurements of NO/sub 2/ in the vicinity of the Hanford Site and releases of SO/sub 2/ onsite were well within the applicable federal and state standards. Particulate air concentrations exceed the standards primarily because of agricultural activities in the area. Discharges of waste water from Hanford facilities in the Columbia River under the National Pollution Discharge Elimination System (NPDES) permit were all within the parameter limits on the permit.
The Lawrence Livermore National Laboratory has developed a mobile field laboratory for remote measurement of atmospheric processes and observables that are important in global climate change, dispersal of hazardous materials, and atmospheric pollution. Specific observables of interest are water vapor, trace gases, aerosol size and density, wind, and temperature. The goal is to study atmospheric processes continuously for extended periods in remote field locations. This laboratory has just reached field ready status with sensors for aerosol and trace gas measurement based on established techniques. A development program is underway to enhance the sensor suite with several new techniques and instruments that are expected to significantly extend the state of the art in remote trace gas analysis. The new sensors will be incorporated into the lab during the next two years.
In this study, we investigate the relationship between income and environmental quality for Turkey at two levels. First, the relationship between the CO{sub 2} emissions and per capita income is examined by the help of a time series model using cointegration techniques. In the second stage, the relationship between income and air pollution is investigated by using PM{sub 10} and SO{sub 2} measurements in Turkish provinces. In this part of the study panel data estimation techniques are utilized. The time series model covers 1968-2003, and the panel data model covers 1992-2001 including observations from 58 provinces. A monotonically increasing relationship between CO{sub 2} and income is found in the long-run according to time series analysis. On the other hand, panel data analysis indicates an N-shape relationship for SO{sub 2} and PM{sub 10} emissions. Therefore, the results of our time series and panel data analyses do ...
In this study, we investigate the relationship between income and environmental quality for Turkey at two levels. First, the relationship between the CO2 emissions and per capita income is examined by the help of a time series model using cointegration techniques. In the second stage, the relationship between income and air pollution is investigated by using PM10 and SO2 measurements in Turkish provinces. In this part of the study panel data estimation techniques are utilized. The time series model covers 1968-2003, and the panel data model covers 1992-2001 including observations from 58 provinces. A monotonically increasing relationship between CO2 and income is found in the long-run according to time series analysis. On the other hand, panel data analysis indicates an N-shape relationship for SO2 and PM10 emissions. Therefore, the results of our time series and panel data analyses do not support the Environmental Kuznets ...
In this study, we investigate the relationship between income and environmental quality for Turkey at two levels. First, the relationship between the CO{sub 2} emissions and per capita income is examined by the help of a time series model using cointegration techniques. In the second stage, the relationship between income and air pollution is investigated by using PM{sub 10} and SO{sub 2} measurements in Turkish provinces. In this part of the study panel data estimation techniques are utilized. The time series model covers 1968-2003, and the panel data model covers 1992-2001 including observations from 58 provinces. A monotonically increasing relationship between CO{sub 2} and income is found in the long-run according to time series analysis. On the other hand, panel data analysis indicates an N-shape relationship for SO{sub 2} and PM{sub 10} emissions. Therefore, the results of our time series and panel data analyses do ...
France has committed herself to keep in 2010 the same levels of greenhouse gas emissions as those of 1990, i.e. 144 millions of tons of carbon equivalent (MtCe). However, taking into account the existing pollution abatement measures and the measurements performed so far, the greenhouse gases level should reach 160 MtCe in 2010. Therefore, the inter-ministry commission on greenhouse effect decided on November 27, 1998 to elaborate a new national plan of fight against greenhouse effect. The elaboration of the new plan has fallen under the responsibility of the inter-ministry mission of greenhouse effect (MIES). The new plan was presented by the prime minister, L. Jospin, on January 19, 2000. This document summarises the content of the new plan: architecture (modalities of elaboration, content), measures for the reduction of greenhouse gas emissions (industry, transportation sector, buildings, agriculture-forestry, wastes ...
Studies are made on coal in terms of its effective utilization, coal cleaning, fluidization and production of new fuel, and issues globally raised. Coal is abundant in reserves and high in supply stability and economic efficiency. However, it is much in CO2 emission per calorific value. To control as much CO2 emission as possible, effective utilization such as increasing of power generation efficiency has been proceeded with. In addition to ultra supercritical pressure and fluidized bed combustion, cited are coal gasification combined cycle power generation and high temperature type fuel cell. Coal has 5-20% ash and impurities like sulfur/nitrogen. Coal should be used clean by pollution abatement measures such as dust collecting, desulfurization and denitrification. Japan is at a world top level of these technologies. Coal is solid, and therefore, is more difficult to handle than liquid fuel. To use it easily, coal is ...
Many Asian countries have experienced rapid economic growth during recent years and this trend is expected to continue. The economic growth is accompanied by increasing energy demand, with coal as the dominant energy source. For the first time a model has been specifically developed and applied for integrated assessment of future SO{sub 2} emissions in Asia. The report deals with the RAINS-ASIA model developed in Norway offering an opportunity to assess sulphur deposition and ecosystem protection levels resulting from different energy pathways and different emission control strategies. The cost of various control strategies are also provided. During the project an impressive database has been collected for the region (23 countries, 94 subregions and 355 large point sources). This was made possible through dedicated work by the project team, in close collaboration with scientific and technical institutions in several Asian countries. A further ...
Investigations have been carried out at the three Corus UK sinter plants over the period 2002-2004 to characterise the emissions of both 2,3,7,8-PCDD/Fs and WHO-12 PCBs, to estimate annual mass releases of these organic micro-pollutants using the I-TEF and WHO-TEF schemes, and to investigate the formation of PCBs in the iron ore sintering process. Results showed that the sintering of iron ore produces a characteristic WHO-12 PCB and PCDD/F congener pattern that is substantially the same for all UK sinter plants. With regard to WHO-12 PCBs, the most abundant congeners were typically PCBs 118 (6-9ngNm-3), 105 (2-4ngNm-3) and 77 (2-3ngNm-3). All other WHO-12 PCBs were also detected at concentrations around 1ngNm-3. All sinter plants investigated exhibited very similar TEQ concentrations. WHO-...
This paper examines the global impacts of a policy that internalizes the external costs (related to air pollution damage, excluding climate costs) of electricity generation using a combined energy systems and macroeconomic model. Starting point are estimates of the monetary damage costs for SO{sub 2}, NO {sub X} , and PM per kWh electricity generated, taking into account the fuel type, sulfur content, removal technology, generation efficiency, and population density. Internalizing these externalities implies that clean and advanced technologies increase their share in global electricity production. Particularly, advanced coal power plants, natural gas combined cycles, natural gas fuel cells, wind and biomass technologies gain significant market shares at the expense of traditional coal- and gas-fired plants. Global carbon dioxide emissions are lowered by 3% to 5%. Sulfur dioxide emissions drop significantly below the ...
This paper examines the global impacts of a policy that internalizes the external costs (related to air pollution damage, excluding climate costs) of electricity generation using a combined energy systems and macroeconomic model. Starting point are estimates of the monetary damage costs for SO{sub 2}, NOX, and PM per kWh electricity generated, taking into account the fuel type, sulfur content, removal technology, generation efficiency, and population density. Internalizing these externalities implies that clean and advanced technologies increase their share in global electricity production. Particularly, advanced coal power plants, natural gas combined cycles, natural gas fuel cells, wind and biomass technologies gain significant market shares at the expense of traditional coal- and gas-fired plants. Global carbon dioxide emissions are lowered by 3% to 5%. Sulfur dioxide emissions drop significantly below the already low ...
Sulfur dioxide emissions from an iron ore sintering plant have severely damaged vegetation up to 16 km northeast of the source. Concentric zones of increasing vegetation loss have formed around the point of maximum ground level concentration of the gas. Species diversity, sulfur and heavy metal concentrations in vegetation and soil amount to SO/sub 2/ injury were measured along a transect through the injury zones. Surrounding a central denuded area were zones dominated respectively by tussock-forming hair grass (Deschampsia flexuosa); low-growing shrubs and trailers (Sambucus pubens, Polygonum cilinode); higher-growing shrubs and suckering Populus tremuloides and Betula papyrifera) stunted forest tree species (Populus, Betula, Picea glauca, Abies Balsamea), and finally, normal boreal forest flora. Although SO/sub 2/ injury is continuing in this area, these zones now appear to be maintained primarily by severe erosion and destruction of suitable habitats for ...
The consequences of converting a facility from brown coal fuel to gas fuel were analyzed by model simulation. Treated were a district heating plant with an output of 700 TJ/yr and minor local heating sources (stoves) at a density of 1 family house per 100 m"2. Emissions of particulate matter, sulfur dioxide, nitrogen oxides, carbon monoxide, and hydrocarbons before and after the conversion are given for the two types of source. Conversion of a major air pollution source to gas fuel would result in a reduction of the contribution of sulfur dioxide emissions of the order of 10"-"4, of particulate matter and carbon monoxide of the order of 10"-"3, and of hydrocarbons of the order of 10"-"2. The decrease will be lowest for nitrogen oxides, viz. about 40%. Analogous data for local heating sources in towns would be 10"-"5 for sulfur dioxide, 10"-"4 for particulate matter, 10"-"3 for carbon monoxide and hydrocarbons, and roughly ...
The piston bowl design is one of the most important factors that affect the air-fuel mixing and the subsequent combustion and pollutant formation processes in a direct-injection diesel engine. The bowl geometry and dimensions, such as the pip region, bowl lip area, and toroidal radius, are all known to have an effect on the in-cylinder mixing and combustion process. In order to understand better the effect of re-entrant geometry, three piston bowls with different toroidal radii and lip shapes were investigated using computational fluid dynamics engine modelling. KIVA3V with improved submodels was used to model the in-cylinder flows and combustion process, and it was validated on a high-speed direct-injection engine with a second-generation common-rail fuel injection system. The engine's performance, in-cylinder flow, and combustion, and emission characteristics were analysed at maximum power and maximum torque conditions and at ...
The EPA proposed air emission guidelines for existing Municipal Waste Combustion (MWC) facilities on December 20, 1989. The regulation, 40 CFR Subpart Ca, was eventually issued on February 11, 1991, but Section 129 of the Clean Air Act Amendments of 1990 required the EPA to review and revise the regulations. On October 31, 1995, Subpart Ca was withdrawn and replaced by a more stringent regulation, 40 CFR Subpart Cb. The new guidelines apply to all existing MWC facilities for which construction began before September 20, 1994 and have a capacity to combust over 35 megagrams per day. Most facilities will be required to be in compliance with the new regulations four years from the date Subpart Cb was issued, or by December 19, 1999. Subpart Cb requires significant capital expenditures and increases in operating costs. The major modifications EPA based the guidelines on are summarized. Pollutants of concern include sulfur dioxide, hydrochloric ...
The Outstanding Achievement Award in WaterPollution Control' is intended to recognize the waterpollution control program that best demonstrates achieving significant, lasting, and measurable excellence in water-quality improvement in preventing water-quality degradation in a region, basin, or water body. This article is about the 1991 Award. This year, WPCF honored Los Angeles Hyperion Treatment Plant with a citation of outstanding achievement. To qualify for this honor, Hyperion has remarkably improved the quality of wastewater discharged to Santa Monica Bay since 1985. Capital programs developed by Los Angeles to achieve this rapid improvement, coined the Hyperion Improvement Program (HIP), reflect the city's commitment to protect the valuable resource of Santa Monica Bay. The HIP was conceived in 1986 to cease sludge ...
The environmental impacts of uranium mining and milling activities are of great concern in many countries for the last three decades. These impacts range from the creation of massive stockpiles of radioactive and toxic waste rock and sand-like tailings to serious contamination of surface and groundwater with radioactive and toxic pollutants, and releases of conventional, toxic and radioactive air pollutants. Uranium mining is also associated with high concentrations of highly toxic heavy metals, which are a major source of surface and groundwater contamination. Depending upon the hydraulic properties of the fractures involved, contaminated ground water may be transported many miles from its point of origin before feeding into an aquifer. Tailings pond may contaminate the groundwater regime by continuous seepage and leaching of radionuclides and other toxic metals due to interaction of rain water through ...
Tritium removal from tritiated heavy water in a PHWR is the most effective way in reducing workers` internal dose and radioactivity emissions from Wolsong NPP. The optimum design of the Wolsung TRF(Tritium Removal Facility) was carried out using an approximate short-cut method with an assumption that the TRF, designed to extract 8 MCi per year of elemental tritium from a heavy water feedstream, uses Liquid Phase Catalytic Exchange (LPCE) front-end process and Cryogenic Distillation (CD) process. 19 refs., 6 figs., 2 tabs. (author).
Tritium removal from tritiated heavy water in a PHWR is the most effective way in reducing workers' internal dose and radioactivity emissions from Wolsong NPP. The optimum design of the Wolsung TRF(Tritium Removal Facility) was carried out using an approximate short-cut method with an assumption that the TRF, designed to extract 8 MCi per year of elemental tritium from a heavy water feedstream, uses Liquid Phase Catalytic Exchange (LPCE) front-end process and Cryogenic Distillation (CD) process. 19 refs., 6 figs., 2 tabs. (author).
This feasibility study of the uve Institut fuer Technische Chemie und Umweltschutz GmbH discusses the scientific and technical fundamentals of a catalytic process for complete removal of organic pollutants (PAH, H-HC, PCB, phenols, nitro-aromatics and organometallic compounds, e.g. from polluted soil and groundwater) by thermal-catalytic cracking and conversion into simple gases. The process is based on the catalytic reaction of the hydrocarbon compounds with water vapour in the temperature range of 700-900 degrees centigrade. The resulting gas mixtures consist mainly of hydrogen, carbon monoxide, carbon dioxide and methane which can be used as fuels, e.g. for heating or in gas engines. The process is an alterntive to combustion. It is therefore well suited whenever the pollutant to be removed is already mixed with water or water vapour and wherever in-situ ...
Sediment trap fluxes of solids, organic carbon, polycyclic aromatic hydrocarbons (PAHs), and polychlorinated biphenyls (PCBs) were measured in Lake Superior in 1984 and 1985. Mass fluxes from surface waters ranged from 0.14 to 1.1 g/m{sup 2}{center dot}day and increased near the lake floor due to resuspension of surficial sediment and horizontal transport in the benthic nepheloid layer. Organic matter fluxes from surface water ranged from 60 to 90 mg of C/m{sup 2}{center dot}day, with {approximately}5% of organic carbon settling from surface waters accumulating in bottom sediments. Concentrations of PCBs and PAHs are enriched 10-100 times on settling particles relative to those on suspended particles. Resultant settling fluxes are 10-100 times greater for several PCB and PAH compounds than net accumulation rates in bottom sediments, indicating the effective and rapid recycling in the benthic region. Biological packaging of ...
When a nuclear power station was installed on the Meuse in central Belgium, the impact of thermal, radioactive, and chemical waste on the water of the Neuse and on its biocenoses was studied. Three successive periods of development of the channel bed and the flood plain in Belgium have occurred, and their hydrological, physicochemical, and ecological consequences have been examined. Since the last century, the ecosystem of the Meuse has undergone, due to the increasing activity of man, modifications of increasing importance: marked reduction of the water flow, a drastic increase in the suspended material being transported, a degree of eutrophication of the water, and the disturbance of the original floral and faunal communities. The causes of this evolution of the Meuse can be itemized as different types of human interference in descending order of importance: (1) occupation of the catchment area; (2) encroachment on the ...
Microbial indicators in the environmental water are categorized as follows. 1. Index for pathogenic microbial contamination, especially enteric canal based ones. 2. Index for the ordinary microbial contamination. 3. Index for nutritive assessment. 4. Index for the treating effect of final effluent discharged into an environmental water. 5. Index for distinction of of the contamination source. Above 1 and 2'' are among the indices which cannot be replaced by other physico-chemical substances or indices. Up to the present time, 1'' is assessed by a coliform group and 2'' by the bacteria. Recently, however, the status on the microbial contamination of the environmental water is changing, thus urging the reexamination of the assessment systems. This report describes the following items. Characteristics and the elements of the indices (enteric canal based pathogenic microbial ...
Due to severe drought conditions in Pakistan over the past several years, most of the areas are facing extinction of its potable water reserves and inadequate replenishment of groundwater aquifers. Due to over exploitation, the groundwater flow dynamics is changing and water quality is degrading due to induced infiltration from polluted surface sources. Isotope hydrology is relatively a new discipline having great potential for studying various water-related problems. RIAD, PINSTECH has established analytical facilities for commonly used environmental isotopes and applied to investigate various hydrological problems. This paper briefly describes practical examples on recharge mechanism and dating of groundwater in Lahore and Ziarat areas using isotopes like deuterium (/sup 2/H), Oxygen-18 (/sup 18/O), Tritium (/sup 3/H) and CFCs in water. In Lahore, the areas having different ...
Finding environmentally friendly and cost-effective methods to remediate soils contaminated with polycyclic aromatic hydrocarbons (PAHs) is currently a major concern of researchers. In this study, a series of small-scale semi-continuous extractions - with and without in situ wet oxidation - were performed on soils polluted with PAHs, using subcritical water (i.e. liquid water at high temperatures and pressures, but below the critical point) as the removal agent. Experiments were performed in a 300 mL reactor using an aged soil sample. To find the desorption isotherms and oxidation reaction rates, semi-continuous experiments with residence times of 1 and 2 h were performed using aged soil at 250 deg. C and hydrogen peroxide as oxidizing agent. In all combined extraction and oxidation flow experiments, PAHs in the remaining soil after the experiments were almost undetectable. In combined extraction and oxidation no PAHs could ...
From June to September 2004 a water research was carried out in six stations that are located at the following microbasins: La Laucha (S1), La Lejia (S2, S3 and S6) and La Rastrojera (S4 and S5). Those microbasins are localized at the Durania municipality in Norte de Santander Department. This study was carried out in order to evaluate water quality at the microbasins above mentioned using macroinvertebrates as bioindicators. For physical, chemical and microbiological parameters a sample was taken at each station. The results were correlated with biologic parameters and it may be concluded that the station 5 closer to the town of Durania is the most polluted by organic matter and that those stations that belong to the ritral zone are less contaminated. The final result showed that the stations 1. 2. 3. 4 and 6 have conditions that can be classified as very clear to clear water and station 5 presents ...
Specific structure of biota community condition can used as indicator for the ecosystem stability value or the waterspollution level where the aquatic biota exist. the macro invertebrates as bio indicator organism can used to assess the upper Cisadane Sub River Basin water quality. The grouping and calculation result from family number, Ept presences (sensitive macro invertebrate), Diversity index (H"'), DO value and TOC value showed 5 criteria of water quality as reference site. This criteria is used to determine water quality level from ten branches of rivers in the upper Cisadane Sub River Basin, Cijeruk districts. The biotic index calculation for ASPT (Average Score Per Taxon) and T and T (index Trihadiningrum and Tjindronegoro) is used to asses water quality based on macro invertebrate composition indicator. Both biotic index system support and give the ...
BIBRA "t"r"a"d"e"m"a"r"k, is the new bio-technological method developed in Gundremmingen for treating radioactive waste water, using bacteria in a process analogous to the long-established principle of communal sewage treatment plants. The method exploits the behaviour of the micro-organisms found there, to establish optimum adaptation of their population for decomposing the typical pollutants found in this washing water. This procedure is particularly suitable for nuclear engineering plants, because in such plants the waste water composition changes little so that the bacteria can achieve optimum adaptation to this waste water. The organic ingredients of the washing media are decomposed by introducing air. The advantage of the procedure is not only the significant reduction of the amount of waste material, but also enhanced efficiency of the cleaning process. The decontamination ...
This book is divided into the following chapters: the atmospheric boundary layer; atmospheric diffusion; pollutants and their properties; and environmental monitoring and impact.
Nitrogen oxides play a critical role in the chemistry of the atmosphere and indirectly influence global warming through the production of ozone. At Barrow, Alaska, the NOAA long-term surface ozone record indicates an increase of about 2% per year during the summer months. Since NO_x (NO+NO_2) concentrations above about 30 ppt (parts per trillion) result in net ozone production in the presence of sunlight, the authors propose that the observed Barrow surface ozone increase is related to anthropogenic nitrogen oxide emissions. A high-sensitivity chemiluminescent instrument for measurements of nitrogen oxides has been built to test this hypothesis. Measurement campaigns have been conducted during summer 1988 and spring 1989, and are continuing during spring and summer 1990. Periods during which the NOV concentrations measured at the GMCC site were unaffected by local (Barrow) emissions were selected from the data record. Observations during these ...
Three new partially-aerated burners have been developed for Australian cooktops fired with natural gas, with maximum thermal inputs of 12, 7.5 and 5.5 MJ h{sup -1}. These novel burner designs minimise the NO{sub 2} emission per unit of useful energy, since NO{sub 2} is the more toxic nitrogen oxide of concern for indoor air pollution. They provide lower values of the ratio of NO{sub 2} emission to thermal efficiency than production burners, with respective reductions of 42, 13 and 23% compared with production burners of corresponding size. The traditional combustion diagrams of these prototype burners have been defined, on plots of primary aeration versus thermal input, to identify the regions of stable flame operation. However, the regions of satisfactory operation are further limited at low primary aeration by the Australian Gas Association requirement for CO/CO{sub 2} ratio <0.01 and at low thermal inputs by the ...
Shortened excerpt from the head notes: The emission limits laid down in the TA Luft concretize the scope of the measures ordered by the law to provide for protection against harmful effects on the environment. Air pollution abatement measures imposed by the competent authority as post-licensing requirements based on the BImSchG (German Federal Emission Control Act) in general are in compliance with the principle of reasonableness considering the terms allowed by the TA Luft for backfitting measures. With this decision, the court qualified the emission limits defined in the TA Luft to be substantial and legally binding standards, to be applied by the competent authorities in licensing and post-licensing administrative procedures, also in order to fulfill the intended task of concretizing the less definite concepts of law laid down in the relevant legislation. (orig./CB) [Deutsch] Verkuerzte Zitierung aus ...
Advances made in understanding the chemistry and dynamics of the atmosphere in the approximate altitude range of 50 to 90 km are addressed. Attention is given to mesospheric structure and seasonal variations, gravity waves and gravity wave saturation, the effects of gravity waves on thermal, momentum and constituent fluxes, and the effect of gravity waves on airglow emissions. A review of research on tides and planetary waves and their effects on the mesosphere are presented as well as discussions on ozone hydroxyl, water vapor, and noctilucent cloud research. 217 refs.
An historic Strontianite-type specimen from Strontian, Scotland, UK, was characterized to broaden our knowledge on luminescence properties of common carbonates. These fibrous aggregates are Strontianite (Sr{sub x}Ca{sub 1-x}CO{sub 3}) with circa 6% of CaO, interfacial water, hydrosilicate anions and substitutional divalent cations, e.g., Ca{sup 2+}, Mn{sup 2+}, Fe{sup 2+} in structural Sr{sup 2+} positions. The specimen was analyzed by X-ray Fluorescence Spectrometry (XRF), Environmental Scanning Electron Microscopy coupled with an Energy Dispersive X-ray Spectroscopy (ESEM-EDS) probe, Spatially-resolved Cathodoluminescence under the Scanning Electron Microscope (SEM-CL), Differential-Thermal Analyses (DTA), Thermogravimetry (TG), Thermoluminescence (TL), Radioluminescence (RL) and High Resolution Spectra Thermoluminescence (3DTL), to gain an overview of the spectral emissions, the defect linkages were modified by heating from room temperature ...
Total river discharge in Pakistan in summer season vary from 3 thousand to 34 thousand cusses (100 thousand Cusses to 1,200 thousand Cusses) and can cause tremendous loss to human lives, crops and property, this causes the loss of most of the flood water in the lower Indus plains to the sea. Due to limited capacity of storage at Tarbela and Mangla Dams on river Indus and Jhelum, with virtually no control on Chenab, Ravi and Sutlej, devastating problems are faced between July and October in the event of excessive rainfall in the catchments. Due to enormous amounts of sediments brought in by the feeding rivers, the three major reservoirs -Tarbela, Mangla and Chashma will lose their storage capacity, by 25 % by the end of the year 2010, which will further aggravate the water-availability situation in Pakistan. The quality of water is also deteriorating due to urbanization and industrialization and agricultural developments. On ...
Except nuclear industry, diverse structures (hospitals, of research or manufacturers) can have appeal to the use of radioisotopes conditioned under unsealed shape. Such practices lead to tolerate releases in environment in the respect of a statutory device. So the collective network can contain radioisotopes the future of which is going to depend partially on the cleaning applied to waste water. This study through the analysis of a concrete case, has for objective to inform about the future of gamma radioelements present in waste water treated by a wastewater treatment plant. The contamination of the network is essentially due to Tc{sup 99} and I{sup 131}, radioelements present whatever the working day and the hour considered. The total estimated in-load for a day is important, of the order of 4000 MBq for Tc{sup 99} and 15 to 300 MBq for I{sup 131}. The assessment of cleaning of the station shows that this one plays a role towards this ...
In France, groundwater usage represents 40 per cent of volumetric use, outside of thermal power plants. Groundwater represents 60 per cent of domestic and public use, 40 per cent in the industrial sector, and is increasing in the agricultural sector where it accounts for 20 per cent. Groundwater withdrawal in France has slightly increased over the last twenty years and benefited the agricultural sector. Availability throughout the territory, the consistency of resupply and natural quality has rendered groundwater a prevailing source for drinking water. Water protection and management is important and led to the adoption of legislative and regulatory measures. The Mining Code (Code minier) allows for exploitation of underground resources starting at 10 metres. The Rural Code (Code rural) mandates the declaration of public utility for water collection for the public. Protection areas are to be provided under the Public Health ...
Increased use of wetlands for habitat and water quality improvement emphasize the need for further study of abiotic-biotic interactions in these systems. This research examined contaminant assimilation within the water column of two newly created Colorado prairie wetlands (RMA3 and RMA4). To examine the influence of abiotic factors (e.g., alkalinity, suspended solids), ten chronic toxicity tests were performed from December 1991 through November 1993. In the first set of tests, Ceriodaphnia dubia were exposed to water from the two wetlands which was spiked with various concentrations of zinc. These tests suggested that water from RMA4 had higher contaminant assimilative capacity than water from RMA3. Preliminary analysis suggested suspended solids, pH, conductivity, and temperature were important factors affecting neonate production by C. dubia when exposed to zinc-spiked wetland ...
Natural resource valuation has always had a fundamental role in the practice of cost-benefit analysis of health, safety, and environmental issues. Today, this role is becoming all the more apparent in the conduct of natural resource damage assessments (NRDA) and cost-benefit analyses of environmental restoration (ER) and waste management (WM) activities. As such, environmental professionals are more interested in how natural resource values are affected by ER and WM activities. This professional interest extends to the use of NRDA values as measures of liability and legal causes of action under such environmental status as the Clean Water Act (CWA); the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA, as amended); and the Oil Pollution Act (OPA) of 1990. Also, environmental professionals are paying closer attention to NRDA values in cost-benefit analyses of risk and pollution-abatement ...
Microbial degradation of aromatic hydrocarbons has been studied with the aim of developing applications for the removal of toxic compounds. Efforts have been directed toward the genetic manipulation of mesophilic bacteria to improve their ability to degrade pollutants, even though many pollution problems occur in sea waters and in effluents of industrial processes which are characterized by low temperatures. From these considerations the idea of engineering a psychrophilic microorganism for the oxidation of aromatic compounds was developed.In a previous paper it was demonstrated that the recombinant Antarctic Pseudoalteromonas haloplanktis TAC125 (PhTAC/tou) expressing a toluene-o-xylene monooxygenase (ToMO) is able to convert several aromatic compounds into corresponding catechols. In our work we improved the metabolic capability of PhTAC/tou cells by combining action of recombinant ToMO enzyme with that of the endogenous ...
The importance of soil heterogeneity for methane emission from a wetland soil is assessed by in situ point measurements of depth-specific O2 and CH4 concentrations and simultaneous soil CH4 fluxes at contrasting water levels. Profile measurements, and associated assumptions in their interpretation, were validated in a controlled mesocosm drainage and saturation experiment applying planar O2 optodes and membrane inlet mass spectrometry. Results show that peat soil is heterogeneous containing dynamic macropore systems created by both macrofauna and flora, which facilitate preferential flow of water, O2 and CH4 and vary temporally with changes in the moisture regime. The O2 content above the water table after drainage varied horizontally from 0 to 100% air saturation within few mm. Oxic zones...
The nation's wetlands are a valuable resource serving many important natural, industrial, commercial and recreational functions. Wetlands protect shore areas from waves and storms; act as storage areas for flood waters; remove waste from water by trapping soils or silt which settle to the bottom; improve water quality and reduce pollution; are a commercial breeding ground for fish and other foods; and provide space for recreation and habitat for wildlife. They also are located in prime industrial development areas. Recent wetlands losses have caused much public outcry, politicking and regulatory efforts to prevent this trend. During the '90s, the public will see efforts to strike a proper balance regarding wetlands use. Today, wetlands protection is a permitting issue for nearly every major industrial or commercial development and expansion project. Wetlands permit requirements affect ...
Because of the environmental hazard of organic solvents such as chlorinated or aromatic hydrocarbons, water soluble and biodegradable substitutes have come into use. It should be assessed how they affect soil and aquifer when spilled in leaks or accidents. This was simulated in a model system using methanol and percolation columns, one filled with material from the unsaturated subsurface and two with different materials from aquifers. The results reveal that a spill of the substitutes can also cause problems. In homogeneous soils and at long retention times until the substance reaches the aquifer, sorption and biological degradation are most likely to prevent contamination of the groundwater. When oxygen supply in the subsurface is insufficient, reducing conditions occur and sulphide is formed. The data show that much more methanol was eliminated than reflected by the consumption of electron acceptors. This indicates that sorption and anabolic turnover of the ...
Protected cultures are widespread along the Lebanese narrow coastline, encouraged by mild winter conditions. Although one of the most intensive production systems, water and nutrients managements are mostly empirical, based on the experience of the grower himself or of his workers. So far, water has been available in Lebanon, but it will become scarce within ten years. The conservation of water quality by a rational addition of nutrients is particularly relevant to protected cultures. This is important as greenhouses are developed on imported shallow soils that could be fragile and highly vulnerable to pollution. Sound management includes the amount and the forms of fertilizers as well as the modality of fertigation. An experiment was conducted during two spring seasons in a location along the northern coast in a typical unheated greenhouse. The cucumber response to two frequencies and modalities of ...
A $200 million paper mill being built in Hagerstown, Md., is expected to produce 150,000 bone-dry short tons per year of de-inked, market-grade pulp for writing and printing paper. The 1st Urban Fibers facility, the largest capital project in Hagerstown's history, is slated for completion in the spring. Landegger Recycled Fiber Corp. will operate and maintain the 200,000-square-foot recycling mill and 60,000-square-foot water reclamation plant. The wastepaper recycling mill plans to minimize waste and pollution by: reclaiming 635 tons per day of 100 percent post-consumer mixed office waste from the solid waste stream; saving more than 16 million cubic feet of landfill area per year; conserving the fiber equivalent of 6,700 trees per day; using no chlorine; saving about 2,000 gallons of water and 4,000 kilowatt hours of electricity per ton of throughput, compared to virgin fiber mills; reusing treated wastewater, ...
Geothermal energy resources are found in many countries. A reasonable and efficient utilization of these resources has been a worldwide concern. The application of geothermal heat pump systems (GHPS) can help increase the efficiency of using geothermal energy and reduce the thermal pollution to the earth surface. However, this is only possible with a proper working fluid. In this paper, a non-azeotropic working fluid (R290/R600a/R123) is presented for a GHPS where geothermal water at 40-45{sup o}C and heating network water at 70-80{sup o}C serve as the low and high temperature heat sources. Experimental results show that the coefficient of performance (COP) of a GHPS using the working fluid is above 3.5 with the condensation temperature above 80{sup o}C and the condensation pressure below 18 bar, while the temperature of the geothermal water is reduced from 40-46{sup o}C to 31-36{sup o}C. (author)
Geothermal energy resources are found in many countries. A reasonable and efficient utilization of these resources has been a worldwide concern. The application of geothermal heat pump systems (GHPS) can help increase the efficiency of using geothermal energy and reduce the thermal pollution to the earth surface. However, this is only possible with a proper working fluid. In this paper, a non-azeotropic working fluid (R290/R600a/R123) is presented for a GHPS where geothermal water at 40-45 deg. C and heating network water at 70-80 deg. C serve as the low and high temperature heat sources. Experimental results show that the coefficient of performance (COP) of a GHPS using the working fluid is above 3.5 with the condensation temperature above 80 deg. C and the condensation pressure below 18 bar, while the temperature of the geothermal water is reduced from 40-46 deg. C to 31-36 deg. C.
The results of the experiments on the pressure oxidation of oil and fat in waste waters shows that the final COD and TOC values decrease with growing temperature and reaction time and decreasing initial concentration. Oxidation of oil and fat in waste water is no straight forward procedure. Therefore it should be compared in the individual case with laternative methods in terms of cost and economic efficiency. (EF) [Deutsch] Die Ergebnisse der Versuche zur Druckoxidation von Oel und Fett in Abwaessern zeigten, dass sich die CSB- und TOC- Endkonzentration verringerte mit steigender Temperatur, Reaktionszeit und verringerter Ausgangskonzentration. Die Oxidierbarkeit von Oel und Fett in Abwaessern ist sehr schwierig. Deshalb sollte in jedem Einzelfall ein Vergleich mit alternativen Verfahren bezueglich Aufwand und Wirtschaftlichkeit vorgenommen werden. (EF)
The direct injection Diesel engine with its specific fuel consumption of about 200 g/kWh is one of the most efficient thermal engines. However in case of relatively low CH- und CO-emission the soot- and NO{sub x} concentration in the exhaust gas turns out to be a problem with respect to the legislation on emission limits. At the department of piston- and turbo-machines of the Trier University of Applied Sciences, a single-cylinder testing engine with two injection-systems (fuel and water) has been developed. This engine has been constructed to analyse the effect of stratified water-injection on the soot- and NO{sub x} emissions of exhaust gases of a Diesel engine. (orig.) [German] Der Dieselmotor mit Direkteinspritzung stellt mit spezifischen Kraftstoffverbraeuchen in der Groessenordnung von 200 g/kWh eine der wirtschaftlichsten thermischen Kraftmaschinen dar. Bei relativ niedrigen ...
More than 80% of the people of Nepal are farmers and 90% of the farmers do farming for subsistence. Agricultural productions contribute about 50% of country's GDP. Agricultural sector has been categorized as the top priority sector since many years. The environment of the country has also deteriorated substantially by the unplanned and unscientific use of natural resources such as air, soil, water, air and forest. Fertility of the soil has also been declining and studies show that productions in mountains is decreasing at a rate of 40 Kg/ha. Yr (1). The Terai, a narrow strip of land in the south, is in heavy pressure due to over exploitation and population growth (both natural and migratory). Shallow groundwater (shallow tube wells) is the main source of drinking water in Terai (the lowland region of Nepal). A study conducted by Department of Water Supply and Sewerage (DWSS) showed that more than 55% of Terai tube wells are ...
Petropavlovsk-Kamchatky (P-K) city in Kamchatka, Russia is operating hot-water district heating using heavy oil boilers and waste hot water of thermal power plants as heat sources. Feasibility study was made on district heating using natural geothermal hot water and/or geothermal heat pump systems as heat sources of hot water supply for reduction of greenhouse effect gas emission. Among 3 areas including geothermal hot water, use of hot water in K area was impossible because of lower temperature and less spring water. Use of hot water in P and UP areas was impossible as primary hot water because of temperature drop to 64 degrees C during hot water supply toward P-K city. The building heating operation test was carried out using the geothermal heat pump system ...
This paper reports on current dual fuel engines utilizing standard mechanical (Bosch type) fuel injection systems set to 5--6 percent pilot delivery that do not appear capable of reducing NO{sub x} emissions much below the current minimum of 4 g/bhp-h without incurring substantial penalties in efficiency and operability. A prototype Electronic Pilot Fuel Injector (EPFI) was designed that overcomes the shortcomings of the mechanical injection system, consistently delivering 3 percent or less pilot at pressures as high as 20,000 psi. The EPFI was installed and tested in one cylinder of a standard production dual fuel engine operating at a waste water treatment facility.
Studies addressed to a deep understanding of the structure/property relationship on the near infrared (NIR)-emissive erbium-quinolinolate complexes, which are of interest for low-cost photonic systems, are reviewed. The role of the 8-quinolinolate ligand (Q), which studies also as sensitizer to overcome the weak absorptivity of lanthanide ion, is discussed. Synthetic and structural aspects are reported to revise the old assumption that these complexes are analogous in structure to AlQ3 and to point out the specificity of the lanthanide coordination chemistry. In fact depending on reaction conditions, species with high coordination numbers and differing for nuclearity and stoichiometry have been isolated and fully characterized. In some instances it has been shown that coordinated water mol...
Existing oil reservoirs might be more fully exploited if the properties of the flow of oil and water in porous media were better known. In laboratory experiments it is important to collect as much information as possible to make a descriptive model of the system, including position imaging and chemical binding information. This thesis develops nuclear methods for obtaining position image and chemical binding information from flow experiments of porous media. A combined positron emission tomography and single photon emission computed tomography system to obtain position images, and a time-differential perturbed angular correlation system to obtain chemical binding information, have been built and thoroughly tested. 68 refs., 123 figs., 14 tabs.
The precipitation of heavy metals as hydroxides is the standard technique for the decontamination of waste water streams polluted by these elements. On the other side, progress in research has been made concerning the biosorption onto dead biomass and bioprecipitation supported by physiologically active bacteria. As the aim of this study, a flexible strategy has been envisaged cleaning a waste water with definite heavy metal load underlying the process mentioned above. Suitable bacteria were enriched and the process was tested in a technical plant. As result, a very high efficiency of heavy metal elimination has been found. The field of application covered by the acquired process is identical with the whole range of the waste water streams polluted by heavy metals. In addition, a second stage may be necessary if there are any further contaminants to be removed. (orig.) [Deutsch] Bei ...
Compared to the reference year of 1990, CO{sub 2} emissions of the Federal Republic of Germany have been curbed by about 12%, primarily as a result of industrial backfitting and pollution abatement measures accomplished in the industrial infrastructure of the new Federal Laender of Germany. Federal Government policy sticks to the previous commitment, to reduce carbon dioxide emissions by 25% by the year 2005. Current forecasts and scenarios of future greenhouse gas emissions show that only immediate adherence to a very stringent reduction policy might ensure that this ambitious goal will be achieved. In this context, any change of the baseline data and scenarios hitherto used for progonostic assessments is a crucial factor, so that the article here discusses the impacts of a change in the nuclear generation scenario, as recently ventilated by the German Federal Government, and expected effects on public ...
It is very difficult to compare environmental impacts of various electricity generation technologies and fuel types because they are extremely divergent. The most widely accepted common denominator today is the so-called external cost by which a monetary value is associated with environmental damage. In this paper, damages to human health resulting from Croatian thermal power plants annual operation are presented. Stack emissions have been translated into ambient concentrations by atmospheric dispersion modelling. Existing data on relations between human health degradation and ground concentrations of the analysed pollutants have been used. Geographic information software has been used in order to account for spatially dependent data. Monetary values have been assigned to the estimated human health damage. External costs resulting from impact of Croatian thermal power plants airborne emissions on human health have been ...
The aim of this study was to estimate the sensitivity of biomarkers of stress and exposure in the bivalve mollusk Anodonta cygnea to spontaneous anthropogenic activities typical for the Western Ukraine. Three sites were examined during spring, summer and autumn: an agricultural site (A); the cooling pond of nuclear power plant (N) and a forestry close to the municipal water inlet (F). Common temporal changes of a battery of biochemical markers in the gills and hemolymph and morphological characteristics were shown by discriminant functional analysis. Classification trees built on the basis of the screened biomarkers demonstrated persistent peculiarities at each site: genotoxicity (nuclear abnormalities) at site A and endocrine disruption (high levels of vitellogenin-like proteins (Vtg-LP) ...
A new process for the removal of tar from biosyngas, OLGA (Oil and Gas Washer), is presented. This gas cleaning technology is based on physical principles and is designed to eliminate tar problems that relate to fouling and er pollution. The applied principles are confirmed by experimental validation. OLGA can be operated without suffering from harmful effects on important gasification characteristics as cold gas efficiency, gasifier simplicity, and feedstock flexibility. Some fundamental considerations in the development of OLGA are discussed. Amongst these is a different approach to the tar problem. This approach does not consider the total tar content as decisive in the evaluation of gas cleaning equipment. Instead, evaluation is focussed on whether tar properties as condensation behaviour and water solubility can still occur. A biosyngas free of tar should therefore be synonymous to a biosyngas that is free of tar related problems.
Abstract:- The demand for Lithium-ion batteries as a major power source in portable electronic devices and vehicles is rapidly increasing. I use cumulative data of vehicle, mobile phone, laptop, and digital camera production to show that demand will overshoot the available global Lithium resources before 2025. Even if 100% of all Lithium-ion batteries were recycled today, recycling could not prevent this resource depletion in time. As the increasing Lithium scarcity will increase the price, it will be feasible to mine diluted resources with a strong environmental impact. I highlight these impacts in Lithium-rich Bolivia, the potential new -Saudi Arabia of Lithium.- Lithium extraction is likely to cause substantial waterpollution, and-through impacts on native diversity-facilitate human he...
The operation of the Bullhouse Minewater System, used to treat iron-rich minewaters discharged from long-abandoned coal mines, was studied to minimise pollution of the Upper Don river in the UK. Tests were carried out to determine optimal operating conditions. Ochre flocculation with polyacrylamide was efficient in batch tests as the ochre self-flocculated and sedimented in the lagoon without the need for chemical enhancement. The rate of accretion of the pipework in the system was modified by partial dewatering, reshaping and hardening of the deposits during ageing. Samples of ochre recovered from the drying beds and sump deposits were converted to ferric sulphate coagulant by dissolution with sulphuric acid and used with a polyelectrolyte to successfully purify reservoir water and pretreat wastewater. There was considerable local interest in the scheme with educational opportunities for schools and colleges.
This study serves to investigate the uptake of POPs in the different trophic levels (scrapers, collectors, predators, shredders) of macroinvertebrate communities sampled from a glacial and a non-glacial stream in the Italian Alps. The presented results show that the contaminant concentrations in glacial communities are generally higher compared to those from non-glacial catchments, highlighting the importance of glaciers as temporary sinks of atmospherically transported pollutants. Moreover, the data also suggests that in mountain systems snow plays an important role in influencing macroinvertebrate contamination. The main chemical uptake process to the macroinvertebrates is considered to be bioconcentration from water, as similar contaminant profiles were observed between the different trophic levels. The role of biomagnification/bioaccumulation is thought to be absent or negligible. The enrichment of chemicals observed in the predators is ...
Abstract Bioluminescent bacteria have been used for many years for biotoxicological analysis. One of the main concerns with this microorganism is the low experimental repeatability when subjected to external factors. The aim of the present study was to obtain accurate, sensitive, and repeatable measurements with stable signals (during the detection and over days) for application in a water-analysis device for the detection of pollutants. Growth conditions were tested and optimized. An optimal freeze-drying procedure for the constitutive bioluminescent bacteria Vibrio fischeri and Photobacterium phosphoreum was developed. The luminescence stability after rehydration was also investigated. Freeze drying was found to be a critical process in survival and signal stability of luminescent bacter...
Natural rubber (NR) and its derivatives as renewable and biodegradable materials have attracted considerable attention because of the serious pollution problems caused by synthetic materials and a shortage of resources. A new semi-interpenetrating polymer network (semi-IPN) based on epoxidised natural rubber and polyvinyl alcohol containing maleic acid as a crosslinking reagent was synthesized and characterized by FTIR, XRD, SEM, swelling ratio in both distilled water and toluene, and mechanical properties. The curing time and dose of maleic acid were varied from 10 to 60min, and from 10 to 60% (w/w), respectively. An IR spectroscopic study indicated the presence of an ester linkage at 1730cm-1 in maleic acid crosslinked with PVA in semi-IPN films. In addition, the crystalline content of P...
Humans are exposed to chemicals in contaminated groundwaters that are used as sources of drinking water. Chemicals contaminate groundwater resources as a result of waste disposal methods for toxic chemicals, overuse of agricultural chemicals, and leakage of chemicals into the subsurface from buried tanks used to hold fluid chemicals and fuels. In the process, both the solid portions of the subsurface and the groundwaters that flow through these porous structures have become contaminated. Restoring these aquifers and minimizing human exposure to the parent chemicals and their degradation products will require the identification of suitable biomarkers of human exposure; better understandings of how exposure can be related to disease outcome; better understandings of mechanisms of transport of pollutants in the heterogeneous structures of the subsurface; and field testing and evaluation of methods proposed to restore and cleanup contaminated ...
A chemical-looping process is proposed for the clean combustion of solid fuels for electric power or heat generation. The process is based on coal gasification with CO_2 to produce CO. The CO then reduces CaSO_4, which is used as an oxygen carrier, in a separate reactor to give CaS and CO_2. A portion of the CO_2 is recycled for the gasification stage and the rest can be sent for sequestration. The CaS is sent to another reactor for oxidation with air and to generate heat or power. The overall thermal effect is the same as direct combustion, but separation of CO_2 and other pollutants, such as sulphur, is achieved. In comparison with conventional chemical-looping combustion of natural gas, much less water is present in the CO_2 product, and hence the loss of heat energy and corrosion of the fuel-reactor system can be reduced.
After a presentation of methods and tools for the basic and extensive characterization of polluted sites and the study of evolution and transfer of current organic pollutants in the ground, the example of the rehabilitation of an old Rhone-Poulenc site (at Chauny, France) polluted with metals and arsenic, is described: soil and aquifer diagnosis, risk analysis and determination of migration schemes
The assessment of greenhouse gas impacts in the US shows that against a baseline gasoline vehicle, the impact of including the full fuel cycle generally reduces the relative advantages of alternative transportation fuels. While a switch to diesel is estimated to save 30% as compared to gasoline, the savings from natural gas/LPG are (around 20%), for ethanol from corn (8%) and for battery electricity vehicles using power from coal (6%) are much smaller. This is largely due to the use of LCA rather than end-use comparisons. However, the results also show that there would be large savings from the use of ethanol from fuel cells using methanol (39%) or natural gas (50%), while ethanol from wood in a conventional engine appears to have the greatest savings (63%). In external costs of motor vehicle use, analysis results were presented for both air pollution and energy security impacts (including SPR, military expenditures, macro-economic costs and pecuniary costs) as ...
Nuclear analytical techniques were applied to determine the elemental compositions of suspended and bottom sediments, collected at different sites in Haiphong harbor area (North Viet nam). The study was aimed at: 1/Understanding the origin of the sediment filling up the access channel and causing large expenditures for dredging operations. 2/Determining the background concentrations of trace elements in sediment. This would allow to detect in the future any pollution caused by the discharge of industrial wastes in the water due to the growing industrialization of the area. 3/Identifying the elements, which can be served as activatable tracers in sediment transport studies. The results obtained for the concentrations of nearly 30 elements show rather similar elemental compositions, reflecting a common origin of the sediments taken from different locations in the harbour area. The results could not allow to identify the pathway of the sediment ...
Findings indicate an urgent need to establish a monitoring program for persistent organic pollutants in water and sediment. - Marine culture is thriving in China and represents a major component of the regional economy in coastal zones, yet the environmental quality of many of those areas has never been studied. This paper attempts to investigate the quality status of Daya Bay, a key aquaculture area in China. The levels of 16 polycyclic aromatic hydrocarbons (PAHs) were determined in water and sediment samples of the bay. The total concentrations of 16 PAHs varied from 4228 to 29325 ng l"-"1 in water, and from 115 to 1134 ng g"-"1 dry weight in sediments. In comparison to many other marine systems studied, the PAH levels in Daya Bay waters were relatively high, and at six sites they were sufficiently high (>10 #mu#g l"-"1) to cause acute toxicity. The PAH composition pattern in ...
In the report the results of the estimations of radiological risk of various stages of decommissioning of nuclear submarines are presented. At occurrence on nuclear submarine the heavy failure, relating to the class hypotetical volume of acting of radionuclides in atmosphere can reach 1.6E(15) Bq. Results of estimations probable doses on an axis of a trace of a radioactive loop show, that at distribution of radionuclides during atmospheric carry to 'agreed' settlement (500-1000 m) the maximum doses on its territory can make: about 6.0E(-3) Sv (for the whole body); 3.0E(-3) Gy for the leather (basal layer); 6.3E(-2) Gy for the lungs (acute exposure) and up to 1.8 Gy for the thyroid gland. Hypotetical failure for the estimation of the greatest possible radioecological consequences for hydrobiocenosis is considering, connected with single discharge of liquid radioactive waste (LRW) in water area. At navigating failure of the tanker with LRW in ...
Full text.Changes in land use and urbanization yield more pressure put on limited soil and water resources, including the risk of pollution with toxic heavy metals. The study area lies in the Bekaa valley totaling about 12753 ha. The valley receives from the west torrential fan deposits and a mixture of colluvial and alluvial material. The principal soil classes are Fluvisols, Cambisols, Regosols, Vertisols and Luvisols. The area is populated and also the most important agricultural part of the plain. Agriculture in the plain is being practiced mainly with cash, field crops and vegetables. The western surrounding area is being used mainly for terraced fruit trees. This Arab-German Technical Cooperation Project (ACSAD-BGR) aimed, following the ISO standards and Eikman-Klocke recommendations, at investigating the nature of the extends of soil pollution by heavy metals in two pilot areas: The central Bekaa-Lebanon and ...
Our long-term goal is to enable highly productive plant species to extract, resist, detoxify, and/or sequester toxic heavy metal pollutants as an environmentally friendly alternative to physical remediation methods. We have focused this phytoremediation research on soil and water-borne ionic and methylmercury. Mercury pollution is a serious world-wide problem affecting the health of human and wild-life populations. Methylmercury, produced by native bacteria at mercury-contaminated wetland sites, is a particularly serious problem due to its extreme toxicity and efficient biomagnification in the food chain. We engineered several plant species (e.g., Arabidopsis, tobacco, canola, yellow poplar, rice) to express the bacterial genes, merB and/or merA, under the control of plant regulatory sequences. These transgenic plants acquired remarkable properties for mercury remediation. (1) Transgenic plants expressing merB ...
We report on the detection of SiO and water masers toward a newly found bipolar nebula, IRAS 19312+1950. This object exhibits extreme red IRAS color log (F25/F12)=0.5 and log (F60/F25)=0.7 and a nebulosity having a size of about 30" extended to the South-West in the 2MASS near-infrared image. Toward this object, we have detected emission from the H2O 6(1,6)-5(2,3) transition, the SiO J=1-0, v=1 and 2, and J=2-1, v=1 transitions, and the SO 2(2)--1(1) and H13CN J=1-0 transitions. The thermal lines of SO and H13CN are shifted by about 12 km/s in radial velocity with respect to the maser lines, indicating that thermal emission comes from the background molecular cloud. However, the SiO J=2-1, v=2 spectrum shows another component of SiO emission separated by 26 km/s from the main component, that might be formed in a rotating or expanding shell.
The MISR instrument aboard NASA's Terra satellite participated in the UAE-2 campaign, August-October 2004. This campaign represented a unique opportunity to study the complex aerosol situation in the Arabian Gulf region, in the context of a first-rate collection of aircraft and surface-based instruments, giving us the opportunity to do some groundbreaking satellite aerosol validation work. We aimed (1) to validate MISR aerosol retrieval results for dust and pollution particles over dark and light surfaces, and (2) to contribute regional maps of aerosol optical thickness (AOT) and particle micro-physical properties, giving spatial context to the field-instrument measurements, and moving toward a satellite-based regional aerosol climatology. The validation effort benefited from the combination of an instrumented aircraft and a regional network of surface-based sun photometers. We obtained high-quality sub-orbital data coincident with MISR overpasses on three days: ...
In the paper, a fuzzy decision-making methodology is presented to decide the generation schedule of long-term hydrothermal problems with explicit recognition of statistical uncertainties in system production cost data, NO{sub x} emission data, system load demand and hydro reservoir water inflows. In deciding the optimal operation, three objectives operating cost, NO{sub x} emission and unsatisfied load demand over the whole of the planning period are simultaneously minimised. Specific technique is put forth to convert the stochastic models into their deterministic equivalents. The weighted minimax method is used to simulate the tradeoff relation between the conflicting objectives in the non-inferior domain. The fuzzy set theory is exploited to choose the best operating point over the tradeoff curve. An efficient decomposition technique is applied to reduce the complexity of the problem. In each subproblem, thermal ...
The genetic systems of bacteria that have the ability to use organic pollutants as carbon and energy sources can be adapted to create bacterial biosensors for the detection of industrial pollution....Full Text Available
The causality of observed associations between air pollution and respiratory health in children is still subject to debate. If reduced air pollution exposure resulted in improved respiratory health...Full Text Available
Studies of the associations between air pollution and hospital admissions and emergency room use are reviewed, including studies of air pollution episodes, time-series analyses, and cross-sectional...Full Text Available
Meteorological and air-quality data, as well as surface tracer concentration values, were collected during 1990 to assess the impact of Navajo Generating Station (NGS) emissions on Grand Canyon National Park (GCNP) air quality. These data have been used in the present investigation to determine between direct and indirect transport routes taken by the NGS plume to produce measured high-tracer concentration events at GCNP. Results show that complex-terrain features affect local wind-flow patterns during winter in the Grand Canyon area. Local channelling, decoupled canyon winds, and slope and valley flows dominate in the region when synoptic systems are weak. Direct NGS plume transport to GCNP occurs with northeasterly plume-height winds, while indirect transport to the park is caused by wind direction shifts associated with passing synoptic systems. Calculated polluted airmass positions along the modeled streak lines match measured ...
Results of an investigation aiming to study the effects of the burner cap design factors on flame stability are presented in this paper. Flame stability is an essential part of the operation of all domestic burners, including natural gas-fired cooktops. At high thermal inputs flame lifts are encountered above certain levels of primary aeration, whereas flashback only takes place at low thermal inputs, due to natural gas low flame speed, above certain levels of primary aeration. In this work, flame lift limits were measured at 3.3 kW thermal input and the highest primary aeration above which flame lifts started to become visible was the stability limit at this thermal input. Around 60% primary aeration was desired to minimize pollutantemissions. Turndown tests were done at 40% primary aeration. The `Factorial Experimental Design` method with statistical analysis was used. This enabled detection of interactions between factors as well as the ...
The effects on engine emissions resulting from the intake manifold fumigation of oxygenated fuel and the addition of oxygenates to the fuel have been investigated using a direct-injection diesel engine. The results show that carefully selected oxygenated fuels effectively work to increase the ignition delay because of their low ignition quality and to decrease the combustion temperature due to the low compression gas temperature produced from their large heat of vaporization, thereby reducing levels of Bosch smoke and nitrogen oxides simultaneously. However, supplementary injection of the oxygenates into the intake air causes a drastic increase in the levels of exhaust total hydrocarbons and CO; thus, it can be said that the addition of oxygenates to the fuel is more practical and effective than fumigation if phase separation of the blended fuel may not be occurred. In the case of addition of the oxygenates to the fuel, it is clarified that smoke is directly ...
Simplifying hypotheses are required when combustion and aerodynamic phenomena are considered simultaneously. In this paper, a turbulent combustion model is proposed, in which the combustion chemistry is reduced to a single reaction. In this way, only two variables are needed to describe the problem and combustion can be characterized by the consumption of one of the two reactive species. In a first step, the instantaneous consumption rate is obtained using the Lagrangian form of the mass fraction equation of the species under consideration, and by considering the equilibrium state only. This state is determined in order to preserve the consistency with results that should be obtained using a complete kinetics scheme. In a second step, the average rate is determined using the instantaneous consumption term and a probabilistic density function. This model was tested on various configurations and in particular on an experimental main chamber and on a reheating chamber. Results indicate ...
Working in partnership with industry, the US Department of Energy`s (DOE`s) Office of Industrial Technologies (OIT) is helping reduce industrial energy use, emissions, and waste while boosting productivity. Operating within the Office of Energy Efficiency and Renewable Energy (EE), OIT conducts research, development, demonstration, and technology transfer efforts that are producing substantial, measurable benefits to industry. This document summarizes some of the impacts of OIT`s programs through 1997. OIT tracks energy savings as well as other benefits associated with the successfully commercialized technologies resulting from OIT-supported research partnerships. Specifically, a chart shows current and cumulative energy savings as well as cumulative reductions of various air pollutants including particulates, volatile organic compounds (VOCs), nitrogen oxides (NO{sub x}), sulfur oxides (SO{sub x}), and the greenhouse gas, carbon dioxide ...
A push for electric vehicles has occurred in the past several decades due to various concerns about air pollution and the contribution of emissions to global climate change. Although electric cars and buses have been the focus of much of electric vehicle development, smaller vehicles are used extensively for transportation and utility purposes in many countries. In order to explore the viability of fuel cell - battery hybrid electric vehicles, empirical fuel cell system data has been incorporated into the NREL's vehicle design and simulation tool, ADVISOR (ADvanced Vehicle SimulatOR), to predict the performance of a low-speed, fuel cell - battery electric vehicle through MATLAB Simulink. The modelling and simulation provide valuable feedback to the design optimization of the fuel cell power system. A sampling based optimization algorithm was used to explore the viability and options of a low cost design for urban use. (author)
The mining and energy industry is under assault today for reasons that have less to do with alleged technical failures and much more to do with ethical complaints about a rate of growth in population that industrial products from mining resources have made possible. The political agendas of Western industrialized nations have been driven during the past quarter century by those whose social philosophy advocates a new ethic of biocentric equality, whereby humans must be forced to being `living as if Nature mattered`. A Green ethic requires that `a violent, plundering humankind` must abandon its alleged rape of the earth and derive its ethical norms from pre-existing ecosystemic harmonies to preserve a fragile and precarious balance existing in Nature. From the perspective of history, there is nothing new about such complaints, current complaints about the use of fossil fuels and pollution from mining, echo similar complaints in past periods. Current Green thinking ...
A three-dimensional mathematical model has been developed as a tool for furnace structure design and operation conditions optimization when the straw combustion is in oxygen-enriched or conventional air atmospheres. Mathematical methods have been used based on a combination of FLIC (A fluid Dynamic Incinerator Code) code for the in-bed incineration and commercial software FLUENT for the over-bed combustion. Oxygen-enriched atmospheres promote the destruction of most pollutants due to the high oxygen partial pressures and temperatures, which is reflected by very low residual amounts of organic combustion by-products in the bottom ash and flue gas of the straw-fired boiler unit. The predictions indicated that the maximum combustion temperature is around 1500 K, CO emission is 201 vppm and O{sub 2} concentration is about 6.9 vol% at furnace exit, and it is shown that mathematical models can serve as a reliable tool for detailed analysis of straw ...
This Public Design Report provides, in a single document, available nonproprietary design -information for the ``Innovative Coke Oven Gas Cleaning System for Retrofit Applications`` Demonstration Project at Bethlehem Steel Corporation`s Sparrows Point, Maryland coke oven by-product facilities. This project demonstrates, for the first time in the United States, the feasibility of integrating four commercially available technologies (processes) for cleaning coke oven gas. The four technologies are: Secondary Gas Cooling, Hydrogen Sulfide and Ammonia Removal, Hydrogen Sulfide and Ammonia Recovery, and Ammonia Destruction and Sulfur Recovery. In addition to the design aspects, the history of the project and the role of the US Department of,Energy are briefly discussed. Actual plant capital and projected operating costs are also presented. An overview of the integration (retrofit) of the processes into the existing plant is presented and is followed by detailed non-proprietary descriptions ...
The new multi-purpose oxygen cupola furnace is a coke-fired shaft furnace that is operated on pure oxygen. The top gas is recirculated, and the fumes are drawn off at temperatures ranging from 800 to 1 000 C. The furnace offers the possibility of melting down contaminated and zinc-bearing scrap without the occurrence of any environment-polluting gas emissions. The absence of nitrogen ballast permits a high energy efficiency. (orig.) [Deutsch] Der neue Mehrzweck-Sauerstoff-Kupolofen ist ein koksbeheizter Schachtofen, der mit reinem Sauerstoff betrieben wird. Das Gichtgas wird im Kreislauf gefuehrt, und das Abgas wird aus einem Bereich mit Temperaturen von 800 bis 1 000 C abgefuehrt. Der Ofen bietet die Moeglichkeit, verunreinigte und zinkhaltige Schrotte einzuschmelzen, ohne dass umweltbelastende Gasemissionen auftreten. Der fehlende Stickstoffbalast bewirkt einen hohen energetischen Wirkungsgrad. (orig.)
This study is part of a greater project from IPT (Sao Paulo's Institute of Technology), which foresaw an energetic use for elephant-grass (Pennisetum purpureum). Biomass gasification is an sustainable option for energy supply, which presents low pollutantsemission rate and allows - through the global cycle of growing and consumption of feedstock (vegetables), a balance between consumption and production of carbonic gas, preventing an increase of the carbonic gas levels in the atmosphere. A gasifier was built with internal diameter of 400 mm and total height of 4600 mm . The equipment was tested for gasification of elephant-grass (Pennisetum purpureum) at a 100 kg/h rate. The equipment was tested and some constructive faults were detected. In the countryside, this biomass is commonly used for cattle feeding It was evaluated an adequate diesel-electric-generator. to work at hybrid regime, using 70% biomass gas and 30% diesel. With the ...
The Pacific Northwest National Laboratory (PNNL) operates a number of research and development (R and D) facilities for the Department of Energy on the Hanford Site. According to DOE Order 5400.1, a Facility Effluent Monitoring Plan is required for each site, facility, or process that uses, generates, releases, or manages significant pollutants or hazardous materials. Three of the R and D facilities: the 325, 331, and 3720 Buildings, are considered major emission points for radionuclide air sampling and thus individual Facility Effluent Monitoring Plans (FEMPs) have been developed for them. Because no definition of ''significant'' is provided in DOE Order 5400.1 or the accompanying regulatory guide DOE/EH-0173T, this FEMP was developed to describe monitoring requirements in the DOE-owned, PNNL-operated facilities that do not have individual FEMPs. The remainder of the DOE-owned, PNNL-operated facilities are ...
Full text.This paper is to investigate the potentials and possibilities of electrical generation via wind turbine. Special attention is directed to the interpretation of wind generation characteristics and parameters found in Lebanon and linking the electrical energy to the Lebanese slectric grid. Although much of the wind energy research is very well established and boomed globally (USA, Europe, India and China), in Lebanon is never used. At a time when climate scientists are increasingly concerned about carbon dioxide emissions from coal and diesel plants, and the nuclear industry is drying, the significance of a major new source os electricity is clear. there are many motives and feasibility criteria for qind power generation in Lebanon. They include the need for increasing the Lebanese electrical capacity, reducing air pollution, alternative energy sources and prices and availability of oil. The work will include literature survey on ...
The need for a hydrogen economy is driven by increasing fuel prices, depleting oil reserves and uncertainty over supplies, and concerns about global warming and environmental pollution. Alternative methods to portable energy sources such as fossil fuels are being developed that are more efficient and carbon-emission-neutral. A prospective method is to produce hydrogen as an energy carrier. This paper presented a study on the degradation of materials under conditions of the sulphur-iodine (SI) thermochemical cycle. The paper provided background information on the study and presented a schematic of the SI cycle. A literature review was presented along with materials selected, such as refractory metals, reactive metals, superalloys, glassy metals, ceramics, cermets, polymers, composites, and coatings. The experimental method was then described. A capsule method was developed to rapidly quantify the decomposition rate of the candidate materials ...
In response to the decisions adopted at the Third Session of the Conference of the Parties to the United Nations Framework Convention on Climate Change (Kyoto conference for the prevention of global warming) of 1997, hybrid vehicles, electric vehicles, and the like are being announced of their completion or placed on the market one after another as low pollution vehicles with CO2 emission to cause global warming reduced. Fuji Electric Co., Ltd., is engaged in the development of a DC-DC converter for hybrid vehicles in cooperation with Nissan Motor Co., Ltd. The product is characterized in (1) that it is small in size and light in weight because a step-down converter and an emergency step-up converter are integrated; (2) that it enjoys a high efficiency rate of 89%; (3) that its service life is long thanks to its design free of aluminum electrolytic capacitors; and (4) that it is provided with various reliability improving features, such as ...
One wonders how a facility will cope with the new Clean Air Act Amendments (CAAA). Environmental engineers working in large companies' facilities and in corporate engineering groups already have an idea of how to comply with the regulations for chemical plant equipment leaks. (In fact, the rules will also affect process bins, wastewater, transfer and storage.) But those who work for smaller companies or who have assignments not directly tied to environmental affairs may not have access to the latest thinking on compliance. One of the first challenges in becoming aware of the CAAA regulations is learning the new language, which consists of acronyms, some containing other acronyms. NESHAP, for example, stands for national emissions standards for hazardous air pollutants. Prior to the CAAA, NESHAPs applied to a few specific chemicals, such as benzene. Now the proposed rules establish a HON, a hazardous organic NESHAP. According to David Gustafson, ...
In a water well sunk in the Grafschaft Bentheim region of northern Germany, small volumes of methane were emitted regularly and large volumes of methane in eruptions at irregular intervals. After some extreme gas eruptions in 2002 and 2004, the Grafschaft Bentheim district government initiated a project to investigate underground conditions in the region between Nordhorn and Bad Bentheim in order to prevent potential hazards to the locals population. The main purpose of the project was to provide information on underground mechanisms as far as possible in order to develop long-term safety strategies for freshwater supply in the region. (orig.)
The Gas Research Institute established the Gas Appliance Technology Center (GATC) in 1982 to develop improved gas appliances. Between 1986 and 1992, the scope of GATC activities at Battelle included technology transfer and overall industry support, residential appliances, commercial appliances, and residential space conditioning. The following tasks are representative of the GATC activities described in the report; gas burner technology, appliance venting, emissions, water heating, range/oven technology, self-powered appliances, commercial cooktop burners, reconstituting ovens, appliance reliability improvement, combination space-heating/water-heating systems, condensing heat exchangers, corrosion testing, and space heating technology. The report includes references to available sources for further reading.
This paper deals with two common problems and then considers major aspects of chemistry in the atmospheres of Mars and Venus. (1) The atmospheres of the terrestrial planets have similar origins but different evolutionary pathways because of the different masses and distances to the Sun. Venus lost its water by hydrodynamic escape, Earth lost CO"2 that formed carbonates and is strongly affected by life, Mars lost water in the reaction with iron and then most of the atmosphere by the intense meteorite impacts. (2) In spite of the higher solar radiation on Venus, its thermospheric temperatures are similar to those on Mars because of the greater gravity acceleration and the higher production of O by photolysis of CO"2. O stimulates cooling by the emission at 15@mm in the collisions with CO"2. ...
The oil sands industry in Canada was said to be committed to environmentally sustainable economic development, i.e. a development that recognizes the mutual dependence of a healthy environment and a healthy economy. To indicate progress toward this goal, the report pointed out the investment of millions of dollars in environmental research and tens of millions of dollars in plant equipment already made. These infrastructure investments have paid dividends in terms of energy conservation, reduction of greenhouse gas emissions, land reclamation, air quality monitoring, water conservation, and water quality and biodiversity protection. A number of recommendations governing provincial jurisdictions over regulations were made. Particular concern was expressed over fairness, and overlapping of regulations by different levels of government.
NIST radon standards are hermetically sealed polyethylene capsules filled with {sup 226}Ra solution. Recently, four new series of standards with activities 5, 50, 500, and 5000Bq were prepared. The measured emanation fraction agrees with a calculation that accounts for the radon accumulated inside the polyethylene walls of the capsule. Obtained solubility of radon in polyethylene is approximately 45 of the solubility of radon in water. The radon diffusion coefficient in low-density polyethylene is 7.2x10{sup -8}cm{sup 2}/s.
Lanthanide-ion doped oxide nanoparticles were functionalized for use as fluorescent biological labels. These nanoparticles are synthesized directly in water which facilitates their functionalization, and are very photostable without emission intermittency. Nanoparticles functionalized with guanidinium groups act as artificial toxins and specifically target sodium channels. They are individually detectable in cardiac myocytes, revealing a heterogeneous distribution of sodium channels. Functionalized oxide nanoparticles appear as a novel tool particularly well adapted to long-term single-molecule tracking.
Absorption with aqueous amine solvents is at present the most viable technology for CO{sub 2} capture. While this is a proven technology, efforts are ongoing to improve it in order to make it a more attractive technology for large scale use to reduce CO{sub 2} emissions. Finding solvents with better properties is one approach to improving the technology. In this thesis methods in computational chemistry are used to improve the understanding of the chemistry of CO{sub 2} absorption in amine-water systems. The work is also intended to provide models that can be used to predict the performance of new solvents. Such predictive models are intended to facilitate the screening for new solvents
Case studies are presented for treatment of refinery wastes in a pilot-scale thin-film evaporator, the removal of volatiles from industrial wastewater for two steam strippers, and the removal of semivolatiles from water by steam stripping followed by liquid-phase carbon adsorption. The report provides data on removal efficiency, air emissions, process residuals, treatment costs, and process limitations. Details on sampling and analytical procedures, quality assurance, and process data are contained in the Appendixes (Volume II).
Case studies are presented for treatment of refinery wastes in a pilot-scale thin-film evaporator, the removal of volatiles from industrial wastewater for two steam strippers, and the removal of semivolatiles from water by steam stripping followed by liquid-phase carbon adsorption. The report provides data on removal efficiency, air emissions, process residuals, treatment costs, and process limitations. Details on sampling and analytical procedures, quality assurance, and process data are contained in the Appendixes (Volume II).
Seasonal traffic on intercity corridors often creates severe congestion at various bottlenecks, such as land-drops and drawbridges. A Traffic Simulation And Optimization model (TSAO) has been developed in order to 1) evaluate traffic impacts (including travel time, vehicle operating costs, accidents, air pollution and fuel consumption) of a given routing pattern on a network, and 2) determine the optimal flow pattern. In its latest version, the TSAO model uses: 1) a macroscopic simulation approach to trace vehicle platoons through a network; 2) Greenshield's equation to represent volume-speed relationship on freeways and multi-lane highways, and Highway Capacity Manual method for two-lane rural highways; 3) Lighthill's shockwave function to simulate queue propagation; 4) event-scan time management for simulation; 5) variable link capacity for two-lane rural highways or to stimulate incidents; 6) AASHTO Guideline for determining vehicle operating ...
Mon R2, at a distance of 830 pc, is the only ultracompact HII region (UC HII) where the photon-dominated region (PDR) between the ionized gas and the molecular cloud can be resolved with Herschel. HIFI observations of the abundant compounds 13CO, C18O, o-H2-18O, HCO+, CS, CH, and NH have been used to derive the physical and chemical conditions in the PDR, in particular the water abundance. The 13CO, C18O, o-H2-18O, HCO+ and CS observations are well described assuming that the emission is coming from a dense (n=5E6 cm-3, N(H2)>1E22 cm-2) layer of molecular gas around the UC HII. Based on our o-H2-18O observations, we estimate an o-H2O abundance of ~2E-8. This is the average ortho-water abundance in the PDR. Additional H2-18O and/or water lines are required to derive the water abundance profile. A lower density envelope (n~1E5 cm-3, N(H2)=2-5E22 cm-2) is responsible for the ...
This article presents the comparative bench testing results of a naturally aspirated, four stroke, four cylinder, water cooled, direct injection Diesel engine when running on diesel fuel and shale oil that is produced in Estonia from local oil shale. The purpose of this research is to investigate the possibility of practical usage of the shale oil as the alternative fuel for a high speed Diesel engine as well as to evaluate the combustion efficiency, brake specific fuel consumption, emission composition changes and the smoke opacity of the exhausts. Test results show that when fuelling a fully loaded engine with shale oil, the brake specific fuel consumption at the maximum torque and rated power is correspondingly higher by 12.3% and 20.4%. However, the brake thermal efficiencies do not differ widely and their maximum values remain equal to 0.36-0.37 for Diesel fuel and 0.32-0.33 for shale oil. The total nitrogen oxide ...
Thermal conductivity is an important property that governs the behaviour of leaf compost biofilters used in treating gaseous pollutants. Measurements were carried out for the thermal conductivity (K) of 44 samples of leaf compost, covering wide ranges of the volume fractions of water (#xi#_w), solids (#xi#_s) and air (#xi#_a), at 20 deg. C using an unsteady state thermal probe. The results indicated that the compost thermal conductivity increased with an increase in #xi#_w, with a decrease in #xi#_a, and with an increase in the degree of saturation (defined as the volumetric fraction of water in the total void space). The predictions from the Woodside-Messmer quadratic parallel (QP) model for the thermal conductivity of leaf compost were higher than the experimental values. A simple linear relationship was developed between the thermal conductivity and the degree of saturation, which provided a satisfactory correlation for ...
The criterion the study is based on in evaluating environmental risks is the possibility of harmful changes in air, water and soils rather than the harmful environmental impacts these changes are caused by. The two significant criteria, i.e. the evaluated environmental hazards potentials or 'value parameters', and the evaluated damage-to-the-environment probabilities or 'safety parameters', reveal the respective environmental risks or 'risk factors'. These risk factors are classified by 23 environmental risk parameters for differentiation between low-risk and high-aid for pollution abatement measures provided that one fixes acceptance limits for the environmental parameters. As a rule the environmental risks of technical facilities which handle hazardous materials can be evaluated appropriately and the results can be compared. (orig./HSCH).
This report is an appraisal of the state of the European Union`s environment. It was requested by the European Commission as part of the review process of the Fifth Environmental Action Programme `Toward sustainability`. Main sections of the report are headed: societal developments and driving forces; environmental themes and topics; integration economy and environment. Themes covered are: climate change, ozone depletion, acidification, air pollution and quality, waste management, urban-issues, inland water resources, coastal zones and marine waters, risk management, soil quality, and nature and diversity. The main conclusions of this report are that the European Union is making progress towards reducing certain pressures on the environment, though this is not enough to improve the general quality of the environment and represents even less progress towards sustainability. Without accelerated policies, pressures on the ...
Crude oil-polluted soil (five parts of weathered crude oil per 100 parts of soil; equivalent to 50,000 mg oil kg{sup -}1 soil) samples were slurried in deionised water (300% of the water retention capacity of the soil) and treated with various amounts of natural-rubber processing sludge (nitrogen content 62.15 mgkg{sup -1} and phosphorus contents 8.75 mgkg{sup -1}) in a well-stirred, continuously-aerated tank at 29{sup o}C. Changes in the total hydrocarbon content of the soil sample were determined, using a spectrophotometric technique, as a function of time. The extent of crude oil degradation was markedly higher (by up to 100%) in the sludge-treated soil than in the untreated soil sample. The efficiency of biodegradation of the crude oil hydrocarbons using the slurry-phase technique was compared with that of solid-phase technique. (author)
Contaminated wood treatment sites can result in adverse health effects to nearby residents. Environmental exposure can be estimated by measuring concentrations of pollutants in air, water, food, or wipe tests. This environmental exposure value can be used as a surrogate to estimate individual exposure. The objective of this study was to determine whether or not pentachlorophenol (PCP) could be found in potentially exposed residents and if the dioxin levels are consistent with PCP exposure. A further objective of the study was to determine whether or not PAH-DNA adducts could be found in the potentially exposed residents. We present results of biomonitoring studies in residents living near a wood treatment plant that used coal-derived creosote and PCP to process and treat wood for over 100 years. The plant was built in 1904 and used creosote and PCP. Creosote is a complex mixture that contains numerous polycyclic aromatic hydrocarbons (PAHs). ...
The purpose of this assessment is to develop a versatile process that will provide a mechanism for evaluating both present and future risks to this environment. Much of the regulatory and environmental interest in the port has centered around a Ballast Water Treatment facility that treats and discharges up to 30 mgd of oily ballast water brought in by crude oil tankers. However, six point discharges and other potential sources of pollution exist in the area. The authors have delineated eleven subareas in the port in order to identify the potential anthropogenic stressors, as well as the receptors that could be exposed to these stressors. Potential effects were then characterized for each exposure. Each component is ranked and integrated, resulting in a relative risk estimate in each subarea. Both the discernible risks, based on available data, and the data gaps are presented. Uncertainty is expressed as a range of high and ...
This Fact Sheet presents the mission of the West Valley Demonstration Project and information on the 1994 pollution prevention and recycling accomplishments.
Eukaryotes may influence pollutant degradation processes in groundwater ecosystems by activities such as predation on bacteria and recycling of nutrients. Culture-independent community profiling and...Full Text Available
This update of a system concept entitled ``Maritime hazard prevention and water protection`` makes full use of the technical room for maneuver while considering that reasonable financial and economic conditions must be provided. The update allows on to continue or start the exploitation of feasible technical, logistic and information-technology development potentials. The same applies to the national maritime traffic safety measures developed for the German waterways. Considering the maritime hazards that have been prevailing in the coastal areas of the German North Sea, the conducted damage risk investigations suggest that a large-scale, disastrous oil contamination of the mud flats ecosystem cannot be excluded or controlled definitely in spite of the numerous measures taken. (orig.) [Deutsch] Mit der vorgelegten Fortschreibung zum Systemkonzept ``Gefahrenabwehr und Gewaesserschutz im Seeverkehr`` werden die technisch realisierten Handlungsspielraeume unter ...
Impact of some heavy metals like zinc, lead, copper, chromium and cadmium were studied at four spots on the macro-invertebrate fauna of the Thaddo stream, a tributary of Malir River. This was in correlation with an earlier study on the physico-chemical aspects of water which showed a severe pollution in this stream. Present data for the qualitative and quantitative analyses of macro-invertebrates and the ranges of heavy metals (Zn 0.5-3.5, Pb 0.90-1.42, Cu 0.35-0.93, Cr 0.0-0.08 and Cd 0.003-0.01 ppm) in the water samples also indicate high level of pollution in the stream. Macro-invertebrate fauna comprises only of aquatic insects which include larvae of Chironomus spp., adults of the Notonectus sp., and nymphs of Gomphus sp. (dragon fly) belonging to the order Diptera , Hemiptera and Odonata, respectively. Quantitatively Notonectus sp. predominated and followed by Chironomus larvae. The maximum ...
Corrosion characteristics of Al and Cu thin films have been studied in cyclic fog tests using tap water fog and fog created with 0.1% NaCl solution in tap water. Likewise, their corrosion features have been analyzed in continuous immersion testing in the laboratory in distilled water, tap water, in 0.1% NaCl and 3.5% NaCl solutions in distilled water. The corrosion potentials and the corrosion currents of these thin films change and reach steady state values after some time. However, steady state is not realized in 3.5% NaCl solutions. The corrosion current density data have been used to calculate lifetime of 1 {mu}m thick thin films of Al and Cu in the various tests, and assuming that the fog test data would hold under normal exposure conditions, life spans for these thin film sensor elements in actual exterior exposure have also been calculated. According to estimates, an Al-TF of ...
Full text: In heavy-water-moderated power reactors, tritium is primarily produced by neutron capture in deuterium nuclei in the moderator and coolant. For CANDU 6 reactors, the estimated steady-state values are #approx# 3 TBq#centre dot#kg"-"1 D_2O in the moderator and #approx# 74 GBq#centre dot#kg"-"1 D_2O in the coolant. Tritium removal is one option available to reactor operators for use in their heavy water and tritium management strategies. The WTRF is designed to remove tritium from tritiated heavy water in each of the four CANDU units at the Wolsung Site, to immobilize the tritium and to store it on site. The detritiation process is based on three steps: the first one (front-end) involves the transfer of tritium from heavy water to deuterium gas; the second one (enrichment) concentrates the tritium in a cryogenic distillation system to produce essentially pure D_2 and T_2 streams; and in the ...
Aerosol and gas measurements were made with the University of Minnesota Mobile Laboratory (UMML) during the VISTTA programme near Page, Arizona. The UMML was stationed on Zilnez Mesa approx. 65 km east of the Navajo coal-fired power plant. Measurements were made both in and out of the power plant plume and were made during the day and night. Measured parameters included aerosol size distributions, Aitken nuclei count, ozone and sulphur dioxide concentrations, the aerosol light scattering coefficient, and meteorological parameters including ultraviolet radiation intensity. Concentrations of NO and NO/SUB/x were occasionally measured. Data show clear evidence of gas-to-particle conversion in the plume with aerosol volume being added in the 0.01 MUm - 0.32 MUm dia. range and new particles being formed. The observed excess aerosol volume depends strongly upon the SO/SUB/2 concentrations and the time of day with none observed in plume parcels which were not exposed to sunlight. This implies ...
Off-grid power generation is meant to supply remote or rural area, where grid connection is almost impossible in terms of cost and geography, such as island, aborigine's villages, and areas where nature preservation is concern. Harnessing an abundance renewable energy sources using versatile hybrid power systems can offer the best, least-cost alternative solution for extending modern energy services to remote and isolated communities. The conventional method for off-grid power generation is using diesel generator with a renewable energy (RE) technology utilizing solar photovoltaic, wind, biomass, biogas and/or mini/micro hydro. A hybrid technology is a combination of multiple source of energy; such as RE and diesel generator and may also include energy storage such as battery. In our design, the concept of solar hybrid system is a combination of solar with diesel genset and battery as an energy storage. The main objective of the system are to reduce the cost of operation and ...
In China, the conventional utilization of oil shale is concentrated mainly on oil shale retorting, and burning oil shale in pulverized furnaces, or bubbling fluidized beds. To improve the availability of oil shale, many specialists have advocated burning oil shale in a circulating fluidized bed (CFB), which has a satisfactory combustion efficiency, low NOx and SO{sub 2} emission, adaptability to low-grade coal, etc. In Huadian, China, a plant incorporating three units of 65 th{sup -1} oil shale-fired CFB began successful commercial operation in 1996, proving that burning oil shale in a CFB produces both high combustion efficiency and environmental protection. For effective utilization of oil shale, its pyrolysis and combustion characteristics, emission performance of gaseous pollutants from an oil shale-fired CFB pilot setup, co-combustion characteristics of oil shale and high sulfur coal as well as the operating ...
The present project examined the operating characteristics and application possibilities of a new, compact combined heating and electricity generating unit with a thermal output of 14,5 kW and a generating capacity of 5,5 kW. Such a module was installed in a plant in Arlesheim (Canton of Basel-Country) and subject to performance measurements. The small heating and generating plant is designed for cyclic operation (without heat storage) and is very compact and low in cost. The heating and generating unit conforms to all Swiss regulations relating to electrical installations and air pollution control. The NO{sub x} emissions of the unit (400 mg/m{sup 3} in steady state operation) are above the limits of LRV 92 (80 mg/m{sup 3}), but the regulation does not apply for units in this power range. The electricity generation costs are approximately CHF 0.16/kWh. It therefore makes sense to install the module in regions with average supply tariffs of at ...
The aim was to compare the energy consumption by private and commercial vehicles with that of public transport facilities constituting urban street traffic, and to evaluate the influence of various traffic related plans such as green waves (where cars are able to drive through the town with relatively few accelerations and braking) streets with lower speed limits and special lanes and priorities for buses. The traffic pattern in four Copenhagen streets (Jagtvej, Soelvgade, Bredgade and Strandvejen) were measured and analyzed both in, and not in, the rush hour, and a special model was used to calculate the energy consumption. The model defines degree of acceleration and slow-down and speed when calculating energy consumption with regard to various driving patterns. It also calculates carbon dioxide emission. It was found that energy consumption decreased with increasing driving speed at 10-60 km/h for all vehicles. The case of buses is a little different because of ...
The aim was to compare the energy consumption by private and commercial vehicles with that of public transport facilities constituting urban street traffic, and to evaluate the influence of various traffic related plans such as green waves (where cars are able to drive through the town with relatively few accelerations and braking) streets with lower speed limits and special lanes and priorities for buses. The traffic pattern in four Copenhagen streets (Jagtvej, Soelvgade, Bredgade and Strandvejen) were measured and analyzed both in, and not in, the rush hour, and a special model was used to calculate the energy consumption. The model defines degree of acceleration and slow-down and speed when calculating energy consumption with regard to various driving patterns. It also calculates carbon dioxide emission. It was found that energy consumption decreased with increasing driving speed at 10-60 km/h for all vehicles. The case of buses is a little different because of ...
In its current configuration, the IECM provides a capability to model various conventional and advanced processes for controlling air pollutantemissions from coalfired power plants before, during, or after combustion. The principal purpose of the model is to calculate the performance, emissions, and cost of power Plant configurations employing alternative environmental control methods. The model consists of various control technology modules, which may be integrated into a complete utility plant in any desired combination. in conuwt to conventional deterministic models, the IECM offers the unique capability to assign probabilistic values to all model input parameters, and to obtain probabilistic outputs in the form of cumulative distribution functions indicating the likelihood of different costs and performance results. The most recent version of the IECM, implemented on a Macintosh II computer and containing a number of ...
In its current configuration, the IECM provides a capability to model various conventional and advanced processes for controlling air pollutantemissions from coalfired power plants before, during, or after combustion. The principal purpose of the model is to calculate the performance, emissions, and cost of power Plant configurations employing alternative environmental control methods. The model consists of various control technology modules, which may be integrated into a complete utility plant in any desired combination. in conuwt to conventional deterministic models, the IECM offers the unique capability to assign probabilistic values to all model input parameters, and to obtain probabilistic outputs in the form of cumulative distribution functions indicating the likelihood of different costs and performance results. The most recent version of the IECM, implemented on a Macintosh II computer and containing a number of ...
Composting is one of the waste disposal methods adopted for disposal of livestock waste in Hong Kong. The composting livestock waste normally undergoes 6-8 weeks fermentation, followed by 16-20 weeks maturation. The matured compost is sold as soil conditioner in the local market. In 2006, feedstock material and a time-series of compost samples were collected throughout the fermentation and maturation process from the Sha Ling Composting Plant in the New Territories. The feedstock material and compost samples were analyzed for contents of three unintentional persistent organic pollutants (POPs), i.e. dioxins/furans, dioxin-like PCBs and total PCBs. These POPs are unintentionally produced by-products of chemical industrial processes and combustion processes. Selected heavy metals were also analyzed, which served as conservative tracers to determine potential mass loss during the composting process. Levels of contamination by these POPs were found to be low in the ...
A novel continuous powder introduction microwave-induced plasma atomic emission spectrometry method (CPI-MIP-AES) has been developed for trace determination of metals in ground and tap water samples after preconcentration on activated carbon. The experimental setup consisted of integrated rectangular cavity TE_1_0_1 and vertically positioned plasma torch. The technical arrangement of the sample introduction system has been designed based on the fluidized bed concept. The satisfactory signal stability required for sequential analysis was attained owing to the vertical plasma configuration, as well as the plasma gas flow rate compatibility with sample introduction flow rate. The elements of interest (Cd, Cu, Cr, Fe, Mn, Pb, Zn) were preconcentrated in a batch procedure at pH 8-8.5 after addition of activated carbon and then, after filtering and drying of the activated carbon suspension, introduced to the MIP by the CPI system. An enrichment ...
A fast and simple flow-through optosensor was designed and characterized for the direct screening of four tetracycline (TCC) antibiotics (tetracycline, oxytetracycline, chlortetracycline and doxycycline) in water and bovine milk samples. The proposed optosensor provides rapid binary yes/no overall responses, being appropriate for the screening of this family of antibiotics above or below a pre-set concentration threshold. The experimental set-up is based on a flow-injection manifold coupled on-line to a phosphorescence detector. Aliquots of the samples are pretreated with Eu(III) to form room temperature phosphorescent metal chelates and injected in the flow manifold. Those chelates are then on-line retained on a conventional flow-cell (packed with polymeric Amberlite XAD-4 particles) which is placed inside the cell holder of the phosphorimeter. After the emission is registered, the antibiotic-metal complexes are eluted from the packed resin ...
Forests on the Kola Peninsula in Northern Russia grow close to the northern tree line. They are subjected to both natural and anthropogenic stress factors. The Cu-Ni smelter 'Severonikel' (Lat. 67 deg 55'N; Long. 32 deg 57'E) near Monchegorsk is one of the two major sources of sulphur dioxide and heavy metals emissions on the Kola Peninsula. These emissions have caused significant deterioration of the surrounding vegetation. The thesis demonstrates how methods of Remote sensing, ground survey and mathematical modelling can be integrated for monitoring of the smelter's environmental impact on the surrounding vegetation: ground truth data are used for calibration of remote-sensed data, which further serve to verify mathematical models. The study aims were: * to estimate the scale of airborne sulphur pollution from the smelting industry on the Kola Peninsula and its effect on ...
Papers presented at a meeting on indoor and outdoor climates on sites polluted with volatile organic chemicals. The papers deal with the subject of evaporation of organic chemicals on the polluted sites in relation to the influence on indoor and outdoor climates. Themes dealt with are diffusion through soils and transport of pollutants from the soil into buildings. (AB).
Climate change is not only dangerous but also expensive. On the other hand, air pollution abatement measures are costly as well. Scientists of the Microeconomics Department investigated how air pollution abatement and cost efficiency can best be combined. (orig.)
The developed countries are implementing a policy minimizing damage from environmental pollution by reducing discharge in advance as well as the aftermath of a pollutant. The typical example is to use BAT (Best Available Technology). This is to prevent environmental damage by reducing the discharge of pollutants with available technology and to secure environmental margin to enable industrial activities of future generation. Therefore, the feasibility of introducing BAT requirement system was reviewed by considering foreign examples and Korean situation. 38 refs., 8 figs., 69 tabs.
The generation of thermal energy is the great importance for the agribusiness of dairy industry to conservation the quality of milk, taking into account that the electricity is the main source currently used for the thermal energy input. The small agribusiness dairy industry currently practiced in Brazil faces several problems related to the cost of electricity and the distance of rural properties of networks of power. In the current scenario of Brazilian dairy production, there is need for the generation of cold for the milk cooling, and also the heat for the production of hot water around 50 deg C to 60 deg C and also for cleaning of equipment used for milk production and processing. The main objective of this study is the modeling and simulation of integrated recovery process of solid waste, effluents and bioconversion. The specific project objectives are: comparison study of options and technological routes of low cost material for power generation using ...
An ampoule corrosion tests technique is presented for making a comparative corrosion-proof estimation of austenitic steels and alloys which are candidate materials for the ITER first wall and shield blanket. Influence of Cl"- on the rate and character of corrosion cracking has been determined. The dependence of time before destruction on Cl"- contents was obtained by experiments in twice-distilled water at a Cl"- content value of less than 0.05 mg/l. Kinetics of a corrosion crack growth has been determined by way of acoustic emission and measurement of electrical resistance. It has been revealed, that corrosion cracking of 316L and 316Ti steels in water with 100 mg/l of Cl"- takes place at temperatures over 50 C. For 316L (Russian analogue), 316Ti, 08Cr18Ni10Ti (type 304), 00Cr16Ni15Mo3Nb (type 316) steels and CrNiMo-1 (42-47%Cr, 1%Mo, Ni-base) alloy corrosion long-term strength and crack-resistance characteristics were ...
Apart from presenting the marginal legal conditions the research program contains a brief description of current pollution abatement measures, representative heating systems and individually suitable pollution abatement technologies and an account of the determination of the concentration of major pollutants. The comparative evaluation of heating systems assesses their environmental effects, i.e. air pollution caused by heating systems. The determination of the costs of available heat is followed by an overall evaluation of the results obtained with special regard to the costs involved by pollution abatement measures.
The X-ray diffraction (XRD) and environmental scanning electron microscopy (ESEM) analyses of plasters collected from the courtyard walls of Djehuty's tomb show anhydrite, calcite, dolomite, quartz, alkali feldspars and accessorial amounts of halite and illite. The external outer bed is mainly composed by anhydrite, since the original hydrous phases of gypsum plaster were desiccated during thirty centuries in the dry land environment of the Luxor area, under low relative humidity and high temperatures. The luminescence analyses by thermoluminescence (TL) and cathodoluminescence (CL) demonstrate as one plaster sample (m8), i.e., 95% anhydrite, displays a gigantic TL emission of 33 555 a.u. and a SEM/CL emission of 2319 a.u. maxima peak. The spectra CL also exhibits a 484 nm peak attributable to the classic {sup 4}F{sub 9/2}{yields}{sup 6}H{sub 15/2} transition circa 490 nm of Dy{sup 3+} and a 573 nm emission of ...
While the expenses of pollution abatement measures are clearly defined at least by orders of magnitude there are no similar - not even internationally comprehensive and methodologically secured data available on the total economic cost of environmental pollution. The research program ' the cost of environmental pollution (efficiency of environmental policies)' aims at establishing a reliable data base. It is expected to be terminated in 1988. Evaluations are being complicated by a still incomplete knowledge and information. It is therefore obvious that economic losses as a result of air pollution can at present not be expressed in concrete figures and that extrapolations, too, are out of the question. (org./HSCH).
The major inquiry of the political party 'Die Gruenen' touches all problems connected with air pollution. The Federal Government states that an extensive air pollution abatement program, i.e. the revision of existing regulations and implementation of new ones has been allowing the realization of all essential environmental aims originally headed for three years ago in the field of air pollution abatement. Achievements such as these will bring about another obvious improvement of the air quality of the Federal Republic of Germany in the coming years. The recent development of energy economy has also proved to be having an obivously positive effect on the environment and pollution abatement. (HSCH).
This study explores the effects of atmospheric CO2 enrichment and climate change on soil moisture (W{sub r} ) and biome-level water limitation (L{sub TA}), using a dynamic global vegetation and water balance model forced by five different scenarios of change in temperature, precipitation, radiation, and atmospheric CO2 concentration, all based on the same IS92a emission scenario. L{sub TA} is defined as an index that quantifies the degree to which transpiration and photosynthesis are co-limited by soil water shortage (high values indicate low water limitation). Soil moisture decreases in many regions by 2071-2100 compared to 1961-1990, though the regional pattern of change differs substantially among the scenarios due primarily to differences in GCM-specific precipitation changes. In terms of L{sub TA}, ecosystems in northern temperate latitudes are at greatest risk of increasing ...
This book summarizes the research that has been conducted in Canada over the past five years on the issue of climate change impacts on key sectors such as water resources, agriculture, forestry, fisheries, coastal zones, transportation, and human health and well-being. The book refers to the growing evidence that climate change is occurring. The Intergovernmental Panel on Climate Change (IPCC) believes that these changes have already contributed to increases in annual precipitation, cloud cover and extreme temperatures over the last 50 years. It suggests that it in order to develop an effective strategy for adaptation, it is necessary to understand the vulnerability of each sector to climate change in terms of the nature of climate change, the climatic sensitivity of the region being considered, and the capacity to adapt to the changes. Adaptation will require a reduction in greenhouse gas emissions in order to lower the rate of climate change. ...
This paper investigates various usages of natural gas (NG) as an energy source for different hydrogen production technologies. A comparison is made between the different methods of hydrogen production, based on the total amount of natural gas needed to produce a specific quantity of hydrogen, carbon dioxide emissions per mole of hydrogen produced, water requirements per mole of hydrogen produced, and a cost sensitivity analysis that takes into account the fuel cost, carbon dioxide capture cost and a carbon tax. The methods examined are the copper-chlorine (Cu-Cl) thermochemical cycle, steam methane reforming (SMR) and a modified sulfur-iodine (S-I) thermochemical cycle. Also, an integrated Cu-Cl/SMR plant is examined to show the unique advantages of modifying existing SMR plants with new hydrogen production technology. The analysis shows that the thermochemical Cu-Cl cycle out-performs the other conventional methods with respect to fuel ...
This paper investigates various usages of natural gas (NG) as an energy source for different hydrogen production technologies. A comparison is made between the different methods of hydrogen production, based on the total amount of natural gas needed to produce a specific quantity of hydrogen, carbon dioxide emissions per mole of hydrogen produced, water requirements per mole of hydrogen produced, and a cost sensitivity analysis that takes into account the fuel cost, carbon dioxide capture cost and a carbon tax. The methods examined are the copper-chlorine (Cu-Cl) thermochemical cycle, steam methane reforming (SMR) and a modified sulfur-iodine (S-I) thermochemical cycle. Also, an integrated Cu-Cl/SMR plant is examined to show the unique advantages of modifying existing SMR plants with new hydrogen production technology. The analysis shows that the thermochemical Cu-Cl cycle out-performs the other conventional methods with respect to fuel ...
A procedure for the determination of carboxylic acids (benzoic and C{sub 8}-C{sub 16} aliphatic acids) in oxidised engine oils is described. It is based on a simple and selective derivatisation of the acids with a fluorescent label 9-anthracene-methanol followed by reverse-phase separation on an ODS column with a water-acetonitrile-tetrahydrofuran (20:40:40 by volume) mobile phase and post-column reaction with bis(2,4-dinitrophenyl) oxalate and hydrogen peroxide. The chemiluminiscence emission from the reaction was monitored using a lamina flow-through detector. Analysis of oxidised oils showed that although there was quenching of chemiluminiscence emission by the oil matrix, the acids could be determined over the range 0-0.4% (m/v) in the oil with a detection limit of 0.013% (m/v) (130 pmol on-column with a 20 {mu}l injection) for lauric acid. 8 figs., 2 tabs., 17 refs.
A series of meteorological and tracer experiments, was conducted during May and June 1984 over the 20-km wide /O/resund strait between Denmark and Sweden for the purpose of studying atmospheric dispersion processes over cold water and warm land surfaces and providing the data needed to evaluate meso-scale models in a coastal environment. In concert with these objectives the data from these experiments have been used as part of a continuing effort to evaluate the capability of the three-dimensional MATHEW/ADPIC (M/A) atmospheric dispersion models to simulate pollutant transport and diffusion characteristics of the atmospheric during a wide variety of meteorological conditions. Since previous studies have focused primarily on M/A model evaluations over rolling and complex terrain at inland sites, the /O/resund experiments provide a unique opportunity to evaluate the models in a coastal environment. The M/A models are used by the Atmospheric ...
The feasibility study was conducted on a model project in Vietnam, aimed at solving the environmental pollution problems resulting from use of coal by demonstrating and disseminating the Japan's environmental technologies in the Southeast Asian countries. The feasibility study was conducted for the Cua Ong Coal Preparation Enterprise, which has the largest coal preparation capacity in Vietnam and port facilities. It is treating raw coal from 10 coal mines for classification and preparation, and shipping coal of various types that meet the standards for domestic use and export. The survey results point out that unrecovered coal remains in waste water discharged from the coal preparation plants to pollute the sea area, and that quantity of the refuse increases because of the unrecovered coal it contains. The environmental technologies needed to introduce include modification to variable wave pattern type jigging ...
Tanzania has recently developed a comprehensive environmental policy which has put high priority on several specific environmental issues. One of the issues is the quality of waste water. A special priority is given to the pollution from the sisal industry. The East-African agro-industries generate very large quantities of organic residues from production and processing of different crops. These residues form a major contribution to the pollution of air, soil and waterways, but, at the same time they constitute a large potential for production of bioenergy through anaerobic digestion as well as potential substrate for other biological fermentation processes. Generally, these residues are regarded as having no or very little value and the different disposal methods are mainly a matter of getting rid of the waste. The generation of residues are very often concentrated on few large units, which makes the exploitation of these ...
Full text: Mt Morgan was mined for copper and gold from 1882 to 1982 and subsequent tailings re-processing ceased in 1990. Direct and accidental deposition of tailings into the adjacent Dee River and acid mine drainage from the mine site continues to impact the Dee River. The Queensland Department of Natural Resources gauging and monitoring station at Kenbula (adjacent to the mine) continuously monitors pH of around 2.8. Twenty kilometres downstream of the mine the pH improves to 3.5. Elevated sediment metal concentrations have been recorded over 50 kilometres downstream in investigations conducted by CSIRO (Jones et al. 1995, 1996) and others. Biological monitoring by Mackey (1988) and subsequently by Duivendoorden (1995,1997), confirmed significant impact on the fish, macrophyte of macro invertebrate populations downstream of the mine. The current AINSE sponsored project will investigate the use of mussels (genus Allathryia) to archive the pollutant load in the ...
Sources of industrial emissions of 1,3-butadiene are discussed both by process (production, consumers) and type (equipment leaks, point sources). Quantification of the emissions are presented, as reported...Full Text Available
In the present paper a procedure is proposed for the determination of traces of Cd, Co, Mn and Cr in petroleum industry produced water by inductively coupled plasma optical emission spectrometry. The procedure is based on cloud point extraction of these metals, as their dithizonate complexes, into the surfactant-rich phase of octylphenoxypolyethoxyethanol surfactant (Triton X-114). Extractions were carried out in solutions with salinities between 10 per mille and 70 per mille. Since residual salinity in the surfactant-rich phase caused differences in its transport to the plasma, yttrium was used as an internal standard to correct for this effect. The simultaneous metal extraction procedure was optimized by response surface methodology using a Doehlert design and desirability function. Enhancement factors of 21, 21, 9 and 19, along with limits of quantification of 0.093, 0.20, 0.73 and 1.2 #mu#g L"-"1, and precision expressed as relative ...
BackgroundPolicies on waste disposal in Europe are heterogeneous and rapidly changing, with potential health implications that are largely unknown. We conducted a health impact assessment of landfilling and incineration in three European countries: Italy, Slovakia and England.MethodsA total of 49 (Italy), 2 (Slovakia), and 11 (England) incinerators were operating in 2001 while for landfills the figures were 619, 121 and 232, respectively. The study population consisted of residents living within 3 km of an incinerator and 2 km of a landfill. Excess risk estimates from epidemiological studies were used, combined with air pollution dispersion modelling for particulate matter (PM10) and nitrogen dioxide (NO2). For incinerators, we estimated attributable cancer incidence and years of life lost (YoLL), while for landfills we estimated attributable cases of congenital anomalies and low birth weight infants.ResultsAbout 1,000,000, 16,000, and 1,200,000 subjects lived ...
An initial draft of an environmental and natural resource strategy for the Asia Near/East region in the 1990's is presented. The report contains five chapters. Chapter I provides an analytic framework that links natural resources, their extent, quality, and management with economic growth in the region. Chapter II contains a more detailed description and analysis of key resource problems that are restricting economic growth and have a severe negative impact on standard of living and quality of life. The most serious of these are soil and water degradation; destruction of natural forests, wetlands, and coastal zones; inefficient energy use and industrial pollution; and lack of environmental services. Chapters III and IV describe 20 specific opportunities for working toward sustainable economic growth through protection and enhancement of the natural resource base. Opportunities for action were chosen on the basis of the urgency and ...
Vaarst Vestervang (Denmark) comprises 16 villas and 1 communal building. The complex was designed by the inhabitants themselves with the aim of polluting the environment as little as possible. The land area constitutes 69.000 square meters where it is possible to grass animals. The document reports a measuring programme concerning the overall heat consumption as one of the main aims of the inhabitants is to save energy and thus contribute to the protection of the environment. The capacity of the solar collectors predominantly used in the building complex was 235 kWh/m{sup 2}. Supplementary heating is provided by boilers fired with wood. The measuring system is described in detail. Tables show the influence of heat transmission losses, ventilation, airing out of rooms, the angle of the sun`s rays within the buildings and heating needs on energy consumption. Energy consumption data is presented in relation to the forms of space and water heating ...
The average American generates four pounds of solid waste per day, yet increasing constraints are being placed on the ability of municipalities to handle waste disposal. Most cities face a scarcity of acceptable landfill sites and conventional incineration and landfill methods have come under strict air, water and soil pollution standards. City administrators are being encouraged to select from a variety of proposed technologies that supplant traditional waste disposal methods, some of which offer the promise of revenues from energy and resource recovery. The problem is to select from available near-term technologies those systems that will fit into a city's long-term solid-waste management program. Broadly, waste-to-energy recovery systems now available to cities may be classified as combustion, pyrolysis, biodegradation, and mechanical front-end systems. It is important to notice that operations used for mechanical front-end systems ...
Full text.Surficial sediment samples were collected from seventeen springs distributed all over Lebanon (east, west, north and south). Concentrations of metals Ca, Fe, Mn, Ni, Cu, Cr, Zn and Pb were determined by energy dispersive x-ray fluorescence technique. Irradiation was done by the radioisotope source Cd-109 and the detection by an EG and G Si(Li) detector. These analysis was done in attempt to assess the impact of anthropogenic sources on ground water quality. Metals concentration in sediment were found to be (Ca:0.05-47%, Fe:0.24-4.2%, Cr:
This review updates a previous review entitled ''Impact of Oil on the Marine Environment''. It covers oil and individual hydrocarbons, used lubricating oils, chemical control agents for oil spills, and wastes from offshore petroleum operations. It considers all major knowledge generated since the mid-1970s. The review covers its topics comprehensively, from a consideration of the composition, sources and inputs of oil to its ecological and human health effects and its effects on man's use of the sea. The review addresses several key questions on the present levels of contamination, the impact of hydrocarbons and related chemicals on marine biota, the recovery potential of marine ecosystems exposed to these contaminants, the degree of protection required for marine ecosystems known to be vulnerable and sensitive, and recommended research and other actions to fill gaps in knowledge. The review describes the hazards of marine oil pollution and associated chemicals and ...
Palladium/magnetite nanoparticulate catalysts were developed for efficient elimination of halogenated organic pollutants from contaminated wastewater. Particle recovery from treated water can be ensured via magnetic separation. However, in worst-case scenarios, this catalyst removal step might fail, leading to particle release into the environment. Therefore, a toxicological study was conducted to investigate the impact of both pure magnetite and palladium/magnetite nanoparticle exposure upon human skin (HaCaT) and human colon (CaCo-2) cell lines and a cell line from rainbow trout gills (RTgill-W1). To quantify cell viability after particle exposure, three endpoints were examined for all tested cell lines. Additionally, the formation of reactive oxygen species was studied for the human cells. The results showed only minor effects of the particles on the tested cell systems and support the assumption that palladium/magnetite nano-catalysts can ...
There are certain factors to take into account when determining the suitability of a healthy house site. Power lines, agricultural spraying, vehicle exhaust, and industrial pollution are all potential sources of indoor air contamination. It is recommended that a environmental assessment be done to determine whether there are specific sources of contamination. Good drainage is required. The surrounding landscaping should be open and sunlit, and with low maintenance requirements. Decks and fences made from pressure-treated or chemical treated lumber should be avoided. One of the early decisions in the design process is the choice of the structural system. The key with all foundation types is to control moisture, whether from rain, from the ground, or the condensation of moisture from the air with cooling. The construction frame is sealed away from the occupants by the air/vapor barrier, so only in extreme cases is it essential to use alternatives to softwood lumber ...
Introduced herein is microwave irradiation for the adsorption and desorption of environmental pollutants. Microwaves may be used in two ways, other than through elevation of temperature of a system as a whole with the adsorbent such as activated carbon serving as the heating medium. The first is the application by which desorption is caused to take place of specified molecules. For example, zeolite that has adsorbed water is regenerated when it is irradiated with microwaves in a stream of cooling gas. This is because only the moisture is heated since zeolite is a non-carbon adsorbent that absorbs microwaves but a little. Another case is reported in which microwaves are utilized to desorb H2S, H2O, CO, etc., from molecular sieves. In the second application, coexisting materials different in absorptivity are exposed to irradiation. The adsorption of microwave-absorbent materials is inhibited while that of the others is accelerated. For example, ...
Three abiotic systems are described that catalyze the reductive dehalogenation of heavily halogenated environmental pollutants, including carbon tetrachloride, trichloroethene, and perchloroethene. These systems include (a) an electrolytic reactor in which the potential on the working electrode (cathode) is fixed by using a potentiostat, (b) a light-driven system consisting of a semiconductor and (covalently attached) macrocycle that can accept light transmitted via an optical fiber, and a light-driven, two-solvent (isopropanol/acetone) system that promotes dehalogenation reactions via an unknown mechanism. Each is capable of accelerating reductive dehalogenation reactions to very high rates under laboratory conditions. Typically, millimolar concentrations of aqueous-phase targets can be dehalogenated in minutes to hours. The description of each system includes the elements of reaction mechanism (to the extent known), typical kinetic data, and a discussion of the ...
Changes in physical and chemical characteristics of aquatic habitats made to reduce or eliminate ecological risks can sometimes have unforeseen consequences. Environmental management activities on the U.S. Dept. of Energy reservation in Oak Ridge, Tennessee,have succeeded in improving water quality in streams impacted by discharges fi-om industrial facilities and waste disposal sites. The diversity and abundance of pollution-sensitive components of the benthic macroinvertebrate communities of three streams improved after new waste treatment systems or remedial actions reduced inputs of various toxic chemicals. Two of the streams were known to be mercury-contaminated from historical spills and waste disposal practices. Waterborne mercury concentrations in the third were typical of uncontaminated systems. In each case, concentrations of mercury in fish, or the apparent biological availability of mercury increased over the period during which ...
Organic materials released from energy-related activities could affect human health and the environment. To better assess possible impacts, we developed a model to predict the fate of spills or discharges of pollutants into flowing or static bodies of fresh water. A computer code, Aquatic Pathways Model (APM), was written to implement the model. The computer programs use compartmental analysis to simulate aquatic ecosystems. The APM estimates the concentrations of chemicals in fish tissue, water and sediment, and is therefore useful for assessing exposure to humans through aquatic pathways. The APM will consider any aquatic pathway for which the user has transport data. Additionally, APM will estimate transport rates from physical and chemical properties of chemicals between several key compartments. The major pathways considered are biodegradation, fish and sediment uptake, photolysis, and evaporation. The model has been ...
This paper explores the potential of combining substance-flow modelling with water and wastewater sampling to trace consumption-related substances emitted through the urban wastewater. The method is exemplified on sucralose. Sucralose is a chemical sweetener that is 600 times sweeter than sucrose and has been on the European market since 2004. As a food additive, sucralose has recently increased in usage in a number of foods, such as soft drinks, dairy products, candy and several dietary products. In a field campaign, sucralose concentrations were measured in the inflow and outflow of the local wastewater treatment plant in Linkoping, Sweden, as well as upstream and downstream of the receiving stream and in Lake Roxen. This allows the loads emitted from the city to be estimated. A method c...
To get a considerable reduction of the radiotoxicity due to americium, a thermal neutron fluence of 2.10{sup 22} cm{sup -2} or a fast neutron fluence of 2.10{sup 24} cm{sup -2} is required. Irradiation in a thermal neutron flux leads to lower masses of {sup 234}U and precursors and of {sup 237}Np and precursors, but to higher curium masses and much higher neutron emission rates than irradiation in a fast neutron flux. Therefore, irradiation in a fast neutron flux has preference when multiple recycling is adopted. When once-through burning is applied, irradiation in a thermal neutron flux can be applied. Then irradiation in a heavy water reactor (HWR) has preference above irradiation in a PWR or in a high temperature gas-cooled reactor (HTGR). (authors) 4 refs.
Adding capacity to coal-fired plants in small increments of an overall integrated program may be the solution to the 10-year lead time required for the construction of a new plant. A preliminary study evaluates the technical and economic feasibility of a modular natural gas and coal-fired combined-cycle power plant which can be installed in three distinct phases. The plant sizes are suitable for large industrial and utility applications. The Modular Block Power Plant (MBPP) concept offers the advantages of phase construction, lower capital cost, lower cost electricity, lower air emissions, lower water requirements, and reduced solid waste discharge. Other advantages include part load availability, reduced coal inventory requirements, and easier plant siting. 11 figures, 4 tables.
A detailed knowledge about the dynamics of phytoplanktonic photosynthesis and respiration is crucial for the determination of primary productivity in open oceans as well as for biotechnological applications. The dynamics are best studied in photobioreactors that are able to simulate natural conditions in such, that light can be modulated not only diurnally but also mimicking effects of solar elevation angle from sunrise to sunset, variable cloudiness, light modulation in refractory sun flecks due to water waves, or light intermittence due to turbulent flow in dense suspensions. In addition, high performance photobioreactors ought to be able to monitor in real time photosynthetic and respiratory activities as well as culture growth. Here, we demonstrate performance of a newly designed bench...
This paper investigates various usages of natural gas (NG) as an energy source for different hydrogen production technologies. A comparison is made between the different methods of hydrogen production, based on the total amount of natural gas needed to produce a specific quantity of hydrogen, carbon dioxide emissions per mole of hydrogen produced, water requirements per mole of hydrogen produced, and a cost sensitivity analysis that takes into account the fuel cost, carbon dioxide capture cost and a carbon tax. The methods examined are the copper-chlorine (Cu-Cl) thermochemical cycle, steam methane reforming (SMR) and a modified sulfur-iodine (S-I) thermochemical cycle. Also, an integrated Cu-Cl/SMR plant is examined to show the unique advantages of modifying existing SMR plants with new h...
A electrogenerated chemiluminescence (ECL) sensor for itopride was developed based on tris(2,2-bipyridyl)ruthenium(II) (Ru(bpy)32+)-doped silica (RuDS) nanoparticles/biopolymer chitosan composites membrane modified glassy carbon electrode (GCE). The RuDS nanoparticles (52+-5nm) were prepared by a modified Stber synthesis method and were characterized by electrochemical, fluorometric and transmission electron microscopy technology. The Ru(bpy)32+ encapsulation interior of the silica nanoparticle maintains its electrochemical activities and also reduces Ru(bpy)32+ leaching from the silica matrix when immersed in water due to the electrostatic interaction. The ECL analytical performances of this ECL sensor for itopride based on its enhancement ECL emission of Ru(bpy)32+ were investigated in d...
The cost incurred every year in West Germany due to air pollution is investigated. Damage to buildings, materials, and vegetation are evaluated as well as the cost of additional cleaning work and changes of location with the objective of getting a picture of the economic value of air pollution abatement. The findings are based on data of immission damage in high-exposure areas. Damage is assessed in consideration of the frequency of repair measures in industrial and country atmosphere. Further research will be necessary in view of the many problems concerning methods and availability of basic statistical data. The sequential cost estimated for a few selected cases of damage show that economic losses due to air pollution amount to several thousand million DM. Air pollution abatement measures thus do not only improve our quality of life but also help to save considerable cost to our national economy.
The Kyoto Protocol foresees emission trading but does not yet specify verification of (uncertain) emissions. This paper analyses a setting in which parties can meet their emission targets by reducing emissions, by investing in monitoring (reducing uncertainty of emissions) or by (bilaterally) trading permits. We derive the optimality conditions and carry out various numerical simulations. Our applications suggest that including uncertainty could increase compliance costs for the USA, Japan and the European Union. Central Europe and the Former Soviet Union might be able to gain from trading due to higher permit prices. Emissions trading could also lower aggregate uncertainty on emissions.
The Transportation Energy Data Book: Edition 12 is a statistical compendium prepared and published by Oak Ridge National Laboratory under contract with the Office of Transportation Technologies in the Department of Energy. Designed for use as a desk-top reference, the data book represents an assembly and display of statistics and information that characterize transportation activity, and presents data on other factors that influence transportation energy use. The purpose of this document is to present relevant statistical data in the form of tables and graphs. Each of the major transportation modes--highway, air, water, rail, pipeline--is treated in separate chapters or sections. Chapter 1 compares US transportation data with data from seven other countries. Aggregate energy use and energy supply data for all modes are presented in Chapter 2. The highway mode, which accounts for over three-fourths of total transportation energy consumption, is dealt with in Chapter ...
The ROTAMIX process for the treatment of contaminated soils, developed by GSI Environment of Sherbrooke, Quebec, is described. The technology combines the use of a self-propelled rotary turner with bioactivating nutrients and structuring agents. Results of various trials using this process showed that soils contaminated with pentachlorophenol and heavy petroleum hydrocarbons, substances that do not easily break down, were decontaminated to a level that corresponds to the C criterion of the Quebec Ministry of the Environment. The ROTAMIX process was found to improve solid/liquid/gas exchanges, and increased water retention capacity of the treated soil. The technology is not constrained by the fine particle concentration that may result from the addition of structuring agents. It produces no leachate water or gaseous emissions. It broadens the range of contaminants that can be treated, including contaminants that resist ...
A workshop on radioactivity in coal use was held on September 15 through 17, 1981, under the auspices of the US Department of Energy, Office of Environmental Programs, and the Los Alamos National Laboratory. The purpose of the workshop was to identify research issues associated with radioactivity resulting from the use of coal for electric power generation. The concensus of the 10 scientists participating in the workshop was that a moderate to strong need exists for research in solubility of fly ash in different fluids and for determination of radioactivity in construction materials. Several additional research issues were identified but were given a lower priority. Summaries of each presentation are included. Titles are: some effects of coal combustion on the radiation environment; radionuclides in western coal at Mound; low-level radiation in coals utilized and ashes produced at New York State electric utilities; radioactivity from coal use - where are the problems; chemistry of ...
Measurements of dissolved and atmospheric nitrous oxide (N{sub 2}O) are presented for three coastal environments: (1) the central North Sea, (2) the German Bight, and (3) the Gironde estuary. The contribution of coastal regions to the oceanic emissions of atmospheric N{sub 2}O were also determined. N{sub 2}O was measured with a gas chromatograph equipped with an electron capture detector and analyzed. The surface waters of the central North Sea and the German bight were found to be near equilibrium with the overlying atmosphere, while the mean saturation in the Gironde estuary was 132%. Mean saturations in coastal regions without estuaries or upwelling phenomena were only slightly higher than in the open ocean. When estuaries and regions with upwelling are included, however, approximately 60% of the oceanic N{sub 2}O flux is attributable to coastal regions. A review of published data indicated that previous studies have seriously underestimated ...
With regard to a fracture system in the Hijiori hot dry rock artificial reservoir, an attempt was made on an interpretation which integrates different data. Major factors that characterize development and performance of an artificial reservoir are composed of a fracture system in rocks, which acts as circulating water paths, a heat exchange face and a reservoir space. The system relates not only with crack density distribution, but also with cracks activated by water pressure fracturing, cracks generating acoustic emission (AE), and cracks working as major flow paths, all of which are characterized by having respective behaviors and roles. Characteristics are shown on AE cluster distribution, crack distribution, production zone and estimated stress fields. Mutual relationship among these elements was discussed based on the Coulomb`s theory. The most important paths are characterized by distribution of slippery cracks. ...
The distribution of environmental tritium and the correlation coefficients between tritium concentrations in several environmental samples and the emissions of tritiated water vapor from Wolsong NPP 1 were studied. The annual mean concentrations of atmospheric HTO were in the range 1#centre dot#31-29#centre dot#2 Bq m"-"3 and the long-term atmospheric dilution factors were in the range 10"-"7-10"-"6 s m"-"3. Annual mean concentrations of tritium in ground water were in the range 19#centre dot#2-27#centre dot#9 Bq l"-"1 at N-1 and 64#centre dot#1-189 Bq l"-"1 at S-2, and were generally less than 0#centre dot#2% of MPC_w (222 kBq l"-"1). The concentrations of tritium in precipitation decreased exponentially with distance from Wolsong NPP 1, falling to current global levels at about 25 km off-site. The highest concentration of tritium in soil moisture was observed in May and June, when the relative humidity was high. The ...
A beta microprobe was successfully applied to monitor arterial input function for quantification of regional cerebral blood flow (rCBF) in the monkey brain with {sup 15}O-water and positron emission tomography (PET). The sensitivity of the probe was approximately 0.83 to 1.67 cps/kBq/ml depending on the studies. A preliminary study was performed to find a suitable use and to evaluate the performance of the system and data analysis procedure. The results showed that dispersion correction of measured input function was unnecessary if microprobes were connected directly to the arterial catheter. Then multiple CBF measurements were done in three monkeys under anesthesia. Identical regions of interest were placed with the aid of magnetic resonance imaging (MRI) of each monkey and rCBF values were estimated. Estimated rCBFs were reproducible for several measurements. The mean CBF value for a pentobarbital anesthetized monkey was 46.0 ml/min/100 g ...
This 2-page fact sheet gives statistics on routine waste generation and projected reduction by waste type, and 1994 pollution prevention and recycling accomplishments at ORNL.
The pollutants from the exhausts of internal combustion engines cause a range of illnesses and are the main source of atmospheric contamination. This article explores the options for curbing pollution in the UK including catalytic converters, electric cars, and natural gas cars. It is likely that the onus will remain with the car manufacturers for developing solutions. (UK)
A schematic diagram of the decision making process for air pollution control equipment for the conversion of a fossil-fired generating unit from oil to coal is presented and explained.
This report presents by state the status of awarded grants, requested grants, and the estimated time required to achieve required control of combined sewer overflow pollution. It also compares discharges of pollutants from treated municipal effluent with ...
The obligations under international law to reduce transfrontier air pollution is discussed in five chapters from various aspects. Consequences for the European Communities are gone into in five further chapters. (orig./HP)
The highly variable and intermittent pollutant concentrations and flowrates associated with wet-weather events in combined sewersheds necessitates the use of storage-treatment systems to control pollution.An optimized combined-sewer-overflow (CSO) control system requires a manage...
A multidisciplinary approach was used to study the effects of pollution from a marine fish farm on nitrification rates and on the community structure of ammonia-oxidizing bacteria in the underlying...Full Text Available
Air pollution measurements were conducted over a 1-year period in 24 North American communities participating in a respiratory health study. Ozone, particle strong acidity, sulfate, and mass (PM10 and...Full Text Available
This design manual contains descriptions of design procedures and operating experience to date, including results obtained, for secondary flow pollution control devices. Two types of combined sewer overflow regulators are described: the swirl and the helical bend regulator/separa...
This cost-effectiveness analysis presents an evaluation of the technical efficiency of pollutant control options for the proposed Effluent Limitations Guidelines and Standards for the Transportation Equipment Cleaning Industry based on Best Available Technology Economically Achievable (BAT) and Pretreatment Standards for Existing Sources (PSES). Section 2 discusses EPA`s cost-effectiveness methodology and identifies the pollutants included in the analysis. This section also presents EPA`s toxic weighting factors for each pollutant and considers the removal efficiency of each pollution control option. Section 3 describes the options evaluated for each subcategory. Section 4 presents the results of the cost-effectiveness analysis. In Section 5, cost-effectiveness values for proposed TEC industry options are compared to cost-effectiveness values for other promulgated rules. Section 6 discusses the two-part ...
Hundreds of thousands of people worldwide live or work in close proximity to steel mills. Integrated steel production generates chemical pollution containing compounds that can induce genetic damage...Full Text Available
Lawrence Livermore, Sandia Livermore and Los Alamos National Laboratories have a joint project to develop an optimized hydrogen fueled engine for series hybrid automobiles. The major divisions of responsibility are: system analysis, engine design and kinetics modeling by LLNL; performance and emission testing, and friction reduction by SNL; computational fluid mechanics and combustion modeling by LANL. This project is a component of the Department of Energy, Office of Utility Technology, National Hydrogen Program. We report here on the progress on system analysis and preliminary engine testing. We have done system studies of series hybrid automobiles that approach the PNGV design goal of 34 km/liter (80 mpg), for 384 km (240 mi) and 608 km (380 mi) ranges. Our results indicate that such a vehicle appears feasible using an optimized hydrogen engine. The impact of various on-board storage options on fuel economy are evaluated. Experiments with an available engine at ...
Lawrence Livermore, Sandia Livermore and Los Alamos National Laboratories have a joint project to develop an optimized hydrogen fueled engine for series hybrid automobiles. The major divisions of responsibility are: system analysis, engine design and kinetics modeling by LLNL; performance and emission testing, and friction reduction by SNL; computational fluid mechanics and combustion modeling by LANL. This project is a component of the Department of Energy, Office of Utility Technology, National Hydrogen Program. We report here on the progress on system analysis and preliminary engine testing. We have done system studies of series hybrid automobiles that approach the PNGV design goal of 34 km/liter (80 mpg), for 384 km (240 mi) and 608 km (380 mi) ranges. Our results indicate that such a vehicle appears feasible using an optimized hydrogen engine. The impact of various on-board storage options on fuel economy are evaluated. Experiments with an available engine at ...
We present deep images of dust continuum emission at 450, 800, and 850 micron of the dark cloud LDN 1689N which harbors the low-mass young stellar objects (YSOs) IRAS 16293-2422A and B (I16293A and I16293B) and the cold prestellar object I16293E. Toward the positions of I16293A and E we also obtained spectra of CO-isotopomers and deep submillimeter observations of chemically related molecules with high critical densities. To I16293A we report the detection of the HDO 1_01 - 0_00 and H2O 1_10 - 1_01 ground-state transitions as broad self-reversed emission profiles with narrow absorption, and a tentative detection of H2D+ 1_10 - 1_11. To I16293E we detect weak emission of subthermally excited HDO 1_01 - 0_00. Based on this set of submillimeter continuum and line data we model the envelopes around I16293A and E. The density and velocity structure of I16293A is fit by an inside-out collapse model, yielding a sound speed of ...
In front of the risks linked with the increase of the greenhouse gas emissions in the atmosphere, the decision makers must take into consideration first, the scientific advice of climatic change experts, and second, the considerable inertia of the climatic system. Thus, any action implemented so far will have an impact all along the 21. century and later whatever the future human activities. The aim of this memento is to sensibilize the decision makers about the possible consequences of their choice in terms of volume of greenhouse gases and of medium- and long-term evolution: 1 - stakes, role of local decision-makers (greenhouse effect and climatic change, France's international commitment, stakes, liabilities of local decision makers, decentralization laws, local plans of fight against greenhouse effect, public information and dialogue); 2 - urbanism and transports (urban displacements, alternatives to individual cars, collective transportation systems, ...
We have done system studies of series hydrogen hybrid automobiles that approach the PNGV design goal of 34 km/liter (80 mpg), for 384 km (240 mi) and 608 km (380 mi) ranges. Our results indicate that such a vehicle appears feasible using an optimized hydrogen engine. We have evaluated the impact of various on-board storage options on fuel economy. Experiments in an available engine at the Sandia CRF demonstrated NO{sub x} emissions of 10 to 20 ppM at an equivalence ratio of 0.4, rising to about 500 ppm at 0.5 equivalence ratio using neat hydrogen. Hybrid simulation studies indicate that exhaust NO{sub x} concentrations must be less than 180 ppM to meet the 0.2 g/mile ULEV or Federal Tier II emissions regulations. LLNL has designed and fabricated a first generation optimized hydrogen engine head for use on an existing Onan engine. This head features 15:1 compression ratio, dual ignition, water cooling, two valves and open ...
Clean Water Act You are here: Water Laws & Regulations Policy & Guidance Clean Water Act Water Quality and 401 Certification Water Quality and 401 Certification Water Quality...
A modelling approach is presented that appears to have the potential to provide reliable assessments of pollution concentration in coastal zones and complex terrain, where the assumptions behind current operational air quality models often are inadequate. With the use of a numerical mesoscale model (NMM), physically consistent flow fields can be predicted, thereby providing higher spatial and temporal resolution in the meteorological fields than would be available from a limited number of observation points. These predictions are used to calculate mean trajectories of pollutant parcels, as well as to provide quantitative estimates of pollution concentration using two techniques.
The booklet presents general information and practical hints for the task of acquiring and evaluating the data describing investments and other expenditure and activities for pollution abatement measures taken by electric utilities. The information is intended as an aid for establishing standard criteria for assignment and evaluation, and for comparison and classification of pollution abatement measures. As a line of orientation, a catalogue of pollution control measures is given, arranged into the following sections: Fossil-fueled power plants; nuclear power plants (BWR and PWR); hydroelectric power plants; power transmission and distribution. (HSCH)
Cultured fish and human cells have been used as bioassay systems for the evaluation of the toxicity of aquatic pollutants. Numerous assays using bacteria and yeast have also been used for such purposes. The authors report the toxicity of aquatic pollutants (Cd, Hg, and Ni), using cell culture systems and the yeast Saccharomyces cervisiae test. Cd, Hg, and Ni were chosen as model compounds of pollutants because the related toxicity is now fairly well established.
Landscape visive pollution due to photo-biodegradable plastic bags is assessed in an ideal case, the most favorable to their use. The result is that mean permanent visive pollution is 100 times higher than established norms. Both photo and biodegradability of plastic bags in the real world are discussed. The conclusion is that photo-biodegradability does not solve the problem of landscape visive pollution due to plastic bags.
The author is exploring the efficiency of pulsed plasma processing in the removal of nitrogen dioxide, nitrogen oxide, and other pollutants. This process uses an electrical discharge to create chemical radicals from air molecules. These radicals can react with pollutants and form harmless compounds. Additives such as hydrocarbons are also used to improve the efficiency of the removal. The efficient removal of nitrogen dioxide has required the presence of dilute aqueous solution of ammonia.
Vietnam is beginning its industrialization process, and it currently lacks the capital necessary for expensive pollution control and treatment systems. Pollution strategies are critical for the country. This study evaluates the present status of industry and the pollution problems associated with industrial development in Vietnam. The purpose of the study is to identify sectors that may have potential for promoting cleaner production practices. 4 refs.
Most of the Turkish lignites have undesired fuel properties and they are extremely polluting. In this study, Sweet Sorghum was chosen as the energy plant. Combustion experiments of lignite and lignite-Sweet Sorghum mixtures were carried out in a fluidised bed system. The fuel-feeding ratio was set such that the thermal output of the system remained constant. Addition of Sweet Sorghum to the lignite reduces the pollutant concentration. The results were supported by experimental results.
Within the EU-Project VOTALP (Vertical Ozone Transports in the Alps), we have shown that deep alpine valleys like the Mesolcina Valley very efficiently transport air out of the polluted valley up to altitudes between 2000 and near 4000 m asl (above sea level). Pollutants emitted in these valleys are very efficiently transported up to high altitudes. (author) 2 figs., 1 tab., 2 refs.
The paper describes the Integrated Air Pollution Control System (IAPCS), a computerized program that can be used to estimate the cost and performance of pre-combustion, in situ, and post-combustion air pollution control configurations in pulverized-coal-fired utility boilers of 1...
The development of emmissions, the measures planned and carried out and the present state of research in the Federal Republic of Germany into air pollution effects and abatement technology is reported. Possible starting points and solutions for air pollution abatement measures are explored within the legal framework.
This Pollution Prevention Design Assessment (PPDA) provides data for cost-benefit analysis of the potential environmental impact of the APT, is an integral part of pollution prevention/waste minimization, and is required by DOE for any activity generating radioactive, hazardous, and mixed wastes. It will also better position the APT to meet future requirements, since it is anticipated that regulatory and other requirements will continue to become more restrictive and demanding.
The Asia-Pacific region will see tremendous growth in demand for electricity in the next few decades and will be an important market for generation equipment and associated services. The Association of Southeast Asian Nations (ASEAN) countries alone anticipate additional power demand of more than 37,000 NM by the year 2000, with an estimated total expenditure of US $85 billion. Trends in recent years show natural gas-fired combined cycle in plants to be fast gaining in popularity over conventional thermal plants. The advantages include increased primary energy conversion efficiency coupled with significant reduction in pollutantemissions, shorter construction times, faster loading rates and reduced staffing requirements. In the computer model used for generation capacity expansion planning in Tenaga Nasional Berhad, clean coal technology models are not used as candidate plants. In the opinion of the authors, this results from a lack of ...
The Burrard Thermal Generating Station is located at Port Moody, British Columbia, and burns natural gas to supply steam to six turbine units for generating up to 912 MW of electricity. The Burrard plant accounts for ca 8.7% of the provincial generating capability. Burrard is expected to continue to fill a vital role as a supplier of displaceable firm energy to the British Columbia Hydro system. In parallel with a renewed focus on Burrard from a system planning perspective, there have also been concerns about air pollution from the plant in the context of its possible effect on the region's air quality. To address this and other issues surrounding Burrard's future, B.C. Hydro established a project team to conduct a utilization study. The team's work focused on the role of Burrard in providing a reliable and profitable role in electricity generation, the options for dealing with the air quality issue, and the implications of choosing one ...
Carbonyl compounds constitute an important reactive class of non methane volatile organic compounds. They can be emitted directly to the atmosphere from primary sources such as combustion engines, landfills and wastewater surfaces or as secondary products by the photochemical oxidation of hydrocarbons and other volatile organic compounds 1-3. Carbonyls photo-oxidize during the day to produce toxic radicals such as OH, HO_2, RO and RO_2. These species react with nitrogen oxides (NOx) and other VOCs present in the atmosphere to form tropospheric ozone (O_3); a highly reactive oxidizing agent that is harmful to human health, agricultural products and climate 4, 5. Hence identifying the levels and sources of ozone precursors such as low carbonyls, carbon monoxide (CO) and NOx derivatives, and understanding their physical and chemical transformation in the troposphere is an important task due to their atmospheric and adverse health implications. Diurnal variations of aldehydes and ketones ...
This paper deals with the combustion process of the turbocharged dual-fuel engine with regard to improvement to thermal efficiency and exhaust gas emissions. It describes the method of charge-air control used to achieve optimal operation in either a pure diesel engine or a gas engine using the pilot-ignition process (dual-fuel principle). The change-over from gas to diesel operation and vice versa can be made automatically even under full load, i. e. the engine can be changed over from one mode of operation to the other without interruption. The exhaust gas constituents emitted by the dual-fuel engine are less detrimental to the environment than those of other internal-combustion engines: CO is hardly present at all; NOx is no higher than that from good diesel engines, or even lower; SO/sub 2/ does not occur since the natural gas, which is used most frequently, and the pilot fuel are practically free of sulfur; CH (hydrocarbons) in this case are non-toxic and ...
Interest in renewable and clean energies such as hydrogen has increased because of the high level of pollutingemissions, increasing costs associated with petroleum and the escalating problems of global climate change. In the presence of a light source, a microbial photosynthetic process provides a system for the conversion of some organic compounds into biomass and hydrogen. Using Rhodopseudomonas palustris as a cell-factory, hydrogen photo-evolution was investigated in a photobioreactor (PBR) irradiated either from one or two opposite sides. Irradiating the photobioreactor from only one side, in the presence of malic acid, a reactor hydrogen production of 2.786 l(H{sub 2}) PBR{sup -1} was achieved. When the PBR was irradiated from two opposite sides, hydrogen photo-evolution increased to 3.162 l(H{sub 2}) PBR{sup -1}. Experiments were carried out using inoculum from either the retardation or the exponential growth phases. Using the latter, ...
Extensive research into the treatment and control of Volatile Organic Compounds (VOCs) from semiconductor industry manufacturing processes has identified the need for alternatives to existing combustion devices. Specifically, semiconductor manufacturing design is moving toward exploiting effective, small-scale, abatement control technologies for specific point-of-use (POU) waste streams associated with a particular component or manufacturing tool. The Silent Discharge Plasma (SDP) developed at Los Alamos National Laboratory is a nonthermal plasma technology created by a dielectric-ballasted electrical discharge. Influent gas-phase pollutants are destroyed in the reactor by the free radicals or electrons generated by the plasma. This paper examines the potential for SDP to be used in niche circumstances for POU control of VOC exhaust streams specific to the semiconductor industry. A sensitivity analysis is presented, showing how SDP cost of ownership is affected by ...
Selective catalytic reduction (SCR) of nitrogen oxides(NO{sub x}) in flue gas or engine exhaust gas with hydrocarbons as the reductant has great potential for less expense, less pollution, and easier operation than SCR with ammonia. Methane is the preferred reducing gas because of its low cost and low toxicity. Stable, low-cost catalysts for SCR with methane are required to demonstrate this technology for controlling NO{sub x} emissions. Several cobalt and nickel catalysts on synthetic clay and uranium oxide supports were investigated for their activities in reducing NO{sub x} with methane in the presence of air. The efficiency of the synthetic clay-supported nickel and cobalt catalysts for nitric oxide (NO) reduction with methane as the reducing gas was poor. The nickel oxide-uranium oxide catalyst, which was chosen for its high stability, was also ineffective. Results from the two-step experiments conducted at two-temperatures produced some ...
Three independent studies have been conducted for assessing the impact of rocket launches on the earth`s environment. These studies have addressed issues of acid rain in the troposphere, ozone depletion in the stratosphere, toxicity of chemical rocket exhaust products, and the potential impact on global warming from carbon dioxide emissions from rocket launches. Local, regional, and global impact assessments were examined and compared with both natural sources and anthropogenic sources of known atmospheric pollutants with the following conclusions: (1) Neither solid nor liquid rocket launches have a significant impact on the earth`s global environment, and there is no real significant difference between the two. (2) Regional and local atmospheric impacts are more significant than global impacts, but quickly return to normal background conditions within a few hours after launch. And (3) vastly increased space launch activities equivalent to 50 ...
A two-year demonstration run of a 500 C/100kgf/cm{sup 2}{center_dot}g high-efficiency waste-to-energy pilot plant has been started from February 1998; this plant represents as the final stage of the NEDO project of development of a high-efficiency waste-to-energy plant. Alloy 625 (SB444) and 310 HCbN tubings were selected for the 3rd and 2nd superheater of the pilot plant, respectively, and ten kinds of conventional and new solid-wall tubings, weld overlayed tubings, composite tubings, and cermet spray coated tubings were tested. By means of 6000-hour field corrosion test in three typical domestic plants, material life and corrosion environment for superheater tubings installed in the pilot plant were evaluated. Also, the effect of alloying elements Cr, Ni, Mo, corrosion rate law, etc. were investigated in detail. Furthermore, the design conception and basic performance of the pilot plant regarding pollution control and corrosion prevention were determined, based ...