Brachytherapy refers to short distance treatment of cancer with radiation from small, encapsulated radionuclide sources. This type of treatment is given by placing sources directly into or near the volume to be treated. The dose is then delivered continuously, either over a short period of time (temporary implants) or over the lifetime of the source to a complete decay (permanent implants). This technique is extensively used in the treatments of gynecological, breast, prostate, head and neck, and other soft tissue cancers. The clinical outcomes of this treatment depend on accurate dosimetry and dose delivery. The patient is generally considered to be water equivalent. So the treatment planning system software generally is based on measured or calculated dose distributions in homogenous water medium. In real situation, the treatment volume is not homogenous water medium, but it is a heterogeneous medium consisting of bone, ...
A safety analysis code, named as SPACE, for a pressurized water reactor is under development to obtain a licensing to be used for the PWR design and to hold entire proprietary rights. The task of KAERI is to develop the physical models and correlations which are required to solve the field equations. It can be divided into four parts; i) flow regime determination, ii) wall heat transfer, iii) wall and interfacial friction, iv) interfacial heat and mass transfer. This paper will describe the process to develop the models for the two-phase flow regime maps in the horizontal and vertical pipes.
A safety analysis code, named as SPACE, for a pressurized water reactor is under development to obtain a licensing to be used for the PWR design and to hold entire proprietary rights. The task of KAERI is to develop the physical models and correlations which are required to solve the field equations. It can be divided into four parts; i) flow regime determination, ii) wall heat transfer, iii) wall and interfacial friction, iv) interfacial heat and mass transfer. This paper will describe the process to develop the models for the two-phase flow regime maps in the horizontal and vertical pipes.
An experimental investigation of a humidification-dehumidification desalination (HDD) process using solar energy at the weather conditions of Suez City, Egypt, is presented. A test rig is designed and constructed to conduct this investigation under different environmental and operating conditions. The test rig consists of a solar water heater (concentrator solar collector type), solar air heater (flat plate solar collector type), humidifier tower and dehumidifier exchanger. Different variables are examined including the feed water flow rate, the air flow rate, the cooling water flow rate in the dehumidifier and the weather conditions. Comparisons between the experimental results and other published results are presented. It is found that the results of the developed mathematical model by the same authors are in good agreement with the experimental results. The tested results show that the productivity of the system is ...
An experimental investigation of a humidification-dehumidification desalination (HDD) process using solar energy at the weather conditions of Suez City, Egypt, is presented. A test rig is designed and constructed to conduct this investigation under different environmental and operating conditions. The test rig consists of a solar water heater (concentrator solar collector type), solar air heater (flat plate solar collector type), humidifier tower and dehumidifier exchanger. Different variables are examined including the feed water flow rate, the air flow rate, the cooling water flow rate in the dehumidifier and the weather conditions. Comparisons between the experimental results and other published results are presented. It is found that the results of the developed mathematical model by the same authors are in good agreement with the experimental results. The tested results show that the productivity of the system is ...
Apart from the vulnerability implied by the START II treaty, it will bear the burden of the general political opposition to the Yeltsin administration. START II will be seen as part of an overall Yeltsin-Andrei Kozyrev foreign policy that is under fire for selling out Russian national interests in Yugoslavia, the Persian Gulf, and elsewhere. This article discusses public opinion concerning START II, the cost of its implementation, and the general purpose of the treaty.
The subject of this volume is remote sensing for environmental monitoring and resource management. This session is divided in eight parts. First part is on general topics, methodology and meteorology. Second part is on geology, environment and land cover. Third part is on disaster monitoring. Fourth part is on operational status of remote sensing. Fifth part is on coastal zones and inland waters. Sixth and seventh parts are on forestry and agriculture. Eighth part is on instrumentation and systems. (A.B.). refs., figs., tabs.
Biosorption using activated sludge biomass (ASB) as a potentially sustainable technology for the treatment of wastewater containing different metal ions (Cd(II), Pb(II) and Zn(II)) was investigated. ASB metal uptake clearly competed with protons consumed by microbial biomass compared with control tests with non-activated sludge biomass. Biosorption tests confirmed maximum exchange between metal ions and protons at pH 2.0-4.5. It was revealed by the study that the amount of metal ions released from the biomass increased with biomass sludge concentration. The result showed that maximum absorption of metal ions was observed for Cd(II) at pH 3.5, Pb(II) at pH 4.0, and pH 4.5 for Zn(II) ions. The maximum absorption capacities of ASB for Cd(II), Pb(II) and Zn(II) were determined to be 59.3, 68.5 and 86.5%, ...
The chemical operational concept originally established for the water-steam circuit of Angra II nuclear power plant has undergone several modifications throughout the development of the project. This work discusses the two main modifications giving special attention to the costs involved and analyses the main points and the consequences of such modifications 1 ref., 4 figs., 2 tabs.
Titanate nanotubes were hydrothermally synthesized and their adsorption performances for lead(II) ion removal were studied. The results showed that titanate nanotubes ruptured in the adsorption process resulting in two distinct adsorption stages, thus achieving a maximum adsorption capacity of 3.752mmolg^-^1 of lead(II). Furthermore, it was found that the regeneration of titanate nanotubes loaded with the lead(II) ions can be readily achieved using the saturated EDTA disodium salt aqueous solution, thereby avoiding the trouble of disposal of adsorbent. The adsorption mechanism was also discussed in detail.
Passage through dams is a major source of mortality of anadromous juvenile salmonids because some populations must negotiate up to eight dams in Columbia and Snake rivers. Dams cause direct mortality when fish pass through turbines, but dams may also cause indirect mortality by altering migration conditions in rivers. Forebays immediately upstream of dams have decreased the water velocity of rivers and may contribute substantially to the total migration delay of juvenile salmonids. Recently, Coutant (2001a) suggested that in addition to low water velocities, lack of natural turbulence may contribute to migration delay by causing fish to lose directional cues. Coutant (2001a) further hypothesized that restoring turbulence in dam forebays may reduce migration delay by providing directional cues that allow fish to find passage routes more quickly (Coutant 2001a). Although field experiments have yielded proof of the concept of using induced ...
The subfornical organ is a major receptor area for one of the principal stimuli of thirst, the octapeptide, angiotensin II. In conscious water-sated rats, the authors examined the effects of intravenous infusion of angiotensin II on the rate of glucose utilization in the subfornical organ and in structures anatomically and functionally connected with it. Angiotensin II produced pressor and drinking responses and increased glucose utilization selectively in the subfornical organ and pituitary neural lobe and in no other brain structure. Treatment with the angiotensin II antagonist, sar1-leu8-angiotensin II, before intravenous administration of angiotensin II prevented metabolic stimulation of the subfornical organ and neural lobe. Captopril, an inhibitor of angiotensin-converting enzyme, reduced subfornical organ glucose metabolism to a level ...
The results of the thermo-hydro-mechanical (THM) study of the FEBEX bentonite performed during FEBEX II are presented. The laboratory test program continued in part with the works carried out during FEBEX I, particularly in activities related to tests aimed to the calibration of the models, the acquisition of parameters by back-analysis and the improvement of the knowledge on the behaviour of expansive clays. But the program has also included tests on new areas: investigations about the influence of the microstructure changes in bentonite, of temperature and of the solute concentration on the behaviour of clay. Besides, several tests were proposed in order to understand the unexpected behaviour observed in the mock-up test, towards the end of year 2. Temperature effects on water retention curves in confined and unconfined conditions were determined, and swelling pressure, hydraulic conductivity and swelling and ...
The radiation reduction of bis(1-ethylimidazole)tartratoplatinum(II) (EITPt(II)) complexes in methanol-water solution have been examined. The yields of Pt(I) depend on the presence of O{sub 2} in solutions as well as the dose applied. The rate constants of e{sub s}{sup -} scavenging by EITPt(II) and cis(diammine-1,1-cyclobutanedicarboxylato) platinum(II) (CBDCAPt(II)) have been determined by pulse radiolysis to be equal to 5.4 x 10{sup 9} and 6.4 x 10{sup 9} M{sup -1} s{sup -1}, respectively. The efficiencies of e{sub t}{sup -} scavenging by EITPt(II) and the rate of e{sub t}{sup -} photobleaching have also been determined in LiCl : H{sub 2}O : CH{sub 3}OH and MgCl{sub 2} : H{sub 2}O : CH{sub 3}OH glasses, respectively. (author).
By the time of primary 21st century, water hyacinth had become a serious environmental problem in China. Water hyacinth contributes to the major part of ecological hazards from the invasion of foreign...Full Text Available
A mathematical model of a mineral melting cupola furnace for stone wool production has been developed for improving cupola operation. The 1-D, first-engineering-principles model includes mass and heat balances for the gas phase, five solid phases, and four liquid phases. The gas and solid/liquid phases flow countercurrently. Seven chemical reactions account for the conversions of coke, iron oxide, limestone, and gaseous species. The heterogeneous reactions of coke conversion are limited by both kinetics and mass transport. Heat transfer between phases is modeled including both convection and radiation. The model predicts gas concentrations; mass flow rates; and temperature profiles of the solid, melt, and gas in the cupola, as well as heat loss to the water-cooled walls. Inputs to the model include the coke, rock, and blast air properties, the blast air amount, and the coke percentage in the charge. The unknown model parameters are estimated on the basis of ...
Physicochemical and benthos data were collected from 12 marine monitoring stations in Daya Bay, during 2001-2004. 12 stations in Daya Bay could be grouped into three clusters: cluster I consisted of stations in the southern part of Daya Bay (stations S1, S2 and S6); cluster II consisted of stations in the cage culture areas (stations S3, S4, S5 and S8); cluster III consisted of stations in the southwest, the middle and the northeast of the Bay (stations S7, S9, S10, S11 and S12). Calculation with bivariate correlations between benthos and major physicochemical factors showed that the density of benthos in all stations correlated positively with temperature, DO, pH, NH4-N, SiO3-Si, SiO3-Si /PO4-P and chlorophyll a and was negatively correlated with salinity, Secchi, COD, NO3-N, NO2-N, TIN, ...
The poisoning effects of various trace contaminants in the coal-derived syngas stream at ppm and sub-ppm level on the performance of Ni-YSZ/YSZ/LSM solid oxide fuel cells were studied at extended duration. The thermochemical nature of impurities such as PH{sub 3}(g) and CH{sub 3}Cl(g) in presence and absence of water steam was analyzed by a high temperature mass spectrometer. Only less than half of PH{sub 3}(g) is hydrolyzed, and CH{sub 3}Cl(g) also co-exist with HCl(g). After a certain duration of exposure, 1 ppm AsH{sub 3}(g), 0.5 ppm PH{sub 3}(g), and 2.5 ppm CH{sub 3}Cl(g) all caused some degree of degradation to the power density at 750 C. Whereas 1 ppm of H{sub 2}S(g) resulted in immediate performance loss. The mechanisms of degradation are mainly divided into two categories: surface adsorption effect (for S and Cl) and bulk reaction effect (for As and P). The controversies regarding the poisoning effect and mechanism of S are also discussed with the aid of ...
The world's oceans contain a complex mixture of micro-organisms that are for the most part, uncharacterized both genetically and biochemically. We report here a metagenomic study of the marine planktonic...Full Text Available
SUMMARYReplication timing is frequently discussed superficially in terms of its relationship to transcriptional activity via chromatin structure. However, so little is known about...Full Text Available
Human longevity is in part genetically determined, and the insulin/IGF-1 signal transduction (IIS) pathway has consistently been implicated. In humans, type 2 diabetes is a frequent disease that results...Full Text Available
Realization that dental caries is a reversible, dynamic biochemical event at a micron level has changed the way the profession recognizes the caries disease and the caries lesion. The diagnosis of dental...Full Text Available
The paper is Part 2 of the study on the thermodynamic and thermoeconomic analyses of trigeneration system with a gas-diesel engine. In Part 1, thermodynamic and thermoeconomic methodologies for such a comprehensive analysis were provided, while this paper applies the developed methodology to an actual TRIGEN system with a rated output of 6.5 MW gas-diesel engine installed in the Eskisehir Industry Estate Zone, Turkey. Energy and exergy efficiencies, equivalent electrical efficiency, the Public Utility Regulatory Policies Act (PURPA) efficiency, fuel energy saving ratio, fuel exergy saving ratio and other thermodynamic performance parameters are determined for the TRIGEN system. The efficiencies of energy, exergy, PURPA and equivalent electrical efficiency of the entire system are found to be 58.97%, 36.13%, 45.7% and 48.53%, respectively. For the whole system and its components, exergetic cost allocations and various exergoeconomic performance ...
The paper is Part 2 of the study on the thermodynamic and thermoeconomic analyses of trigeneration system with a gas-diesel engine. In Part 1, thermodynamic and thermoeconomic methodologies for such a comprehensive analysis were provided, while this paper applies the developed methodology to an actual TRIGEN system with a rated output of 6.5 MW gas-diesel engine installed in the Eskisehir Industry Estate Zone, Turkey. Energy and exergy efficiencies, equivalent electrical efficiency, the Public Utility Regulatory Policies Act (PURPA) efficiency, fuel energy saving ratio, fuel exergy saving ratio and other thermodynamic performance parameters are determined for the TRIGEN system. The efficiencies of energy, exergy, PURPA and equivalent electrical efficiency of the entire system are found to be 58.97%, 36.13%, 45.7% and 48.53%, respectively. For the whole system and its components, exergetic cost allocations and various exergoeconomic performance ...
Water-resources data for the 1993 water year for Minnesota consists of records of stage, discharge and water quality of streams; stage, contents, and water quality of lakes and reservoirs; and water levels and water quality in wells and springs. This volume contains discharge records for 58 gaging stations; stage and contents for 9 lakes and reservoirs; water quality 15 stream stations, 1 lakes station, 1 precipitation station, and water levels for 15 observation wells. Also included are 61 high-flow partial-record stations. Additional water data were collected at various sites, not part of the systematic data collection program and are pulished as miscellaneous measurements.
Water-resources data for the 1991 water year for Minnesota consist of records of stage, discharge and water quality of streams; stage, contents, and water quality of lakes and reservoirs; and water levels and water quality in wells and springs. The volume contains discharge records for 60 gaging stations; stage and contents for 9 lakes and reservoirs; water quality for 18 stream stations, 1 lake station, 22 partial-record sites, 1 precipitation station, 108 wells; and water levels for 119 observation wells. Also included are 59 high-flow partial-record stations. Additional water data were collected at various sites, not part of the systematic data collection program and are published as miscellaneous measurements or low-flow investigations.
The KENTORT II process includes integral fluidized bed zones for pyrolysis, gasification, and combustion of the oil shale. The purpose of this program is to design and test the KENTORT II process at the 50-lb/hr scale. Along with the major activity of assembling the components of the 50-lb/hr retort, work was also completed in other areas this quarter. Basic studies of the cracking and coking kinetics of model compounds in a fixed bed reactor were continued. Additionally, as part of the effort to investigate niche market applications for KENTORT II-derived products, a study of the synthesis of carbon fibers from the heavy fraction of KENTORT II shale oil was initiated.
BackgroundMultiple lines of evidence have suggested that valproic acid (VPA) might benefit patients with spinal muscular atrophy (SMA). The SMA CARNIVAL TRIAL was a two part prospective...Full Text Available
A number of alloys of zirconium have been investigated as part of a program aimed at improving the high-temperature tensile and creep strength of zirconium. These alloys include aluminum, beryllium, lead, magnesium, molybdenum, niobium, tantalum, tin, titanium, tungsten, vanadium, and zinc, binary and ternary alloys. The data indicate that aluminum, lead, molybdenum niobium, tin, titanium, tungsten, and vanadium can be used successfully to harden zirconium, and that aluminum, tin, titanium, and vanadium are particularly effective in maintaining the strength of zirconium at elevated temperatures.
Eight years ago, corrosion and tube denting seriously threatened the reliability and design life of steam generators, especially for closed loop arrangements in pressurized water reactors (PWRs). Concentrated research by the Steam Generator Owners Group (SGOG) diagnosed the causes and produced effective solutions, notably guidelines for water chemistry control in the secondary loop. The guidelines recommend specific levels of water impurities and remedial actions to prevent cooling-water leaks in the condenser, prevent air leaks, limit corrosion product buildup, and remove some impurities while neutralizing others. Continued research in SGOB-II is investigating intergranular corrosion and stress corrosion cracking. 3 figures.
Eight years ago, corrosion and tube denting seriously threatened the reliability and design life of steam generators, especially for closed loop arrangements in pressurized water reactors (PWRs). Concentrated research by the Steam Generator Owners Group (SGOG) diagnosed the causes and produced effective solutions, notably guidelines for water chemistry control in the secondary loop. The guidelines recommend specific levels of water impurities and remedial actions to prevent cooling-water leaks in the condenser, prevent air leaks, limit corrosion product buildup, and remove some impurities while neutralizing others. Continued research in SGOB-II is investigating intergranular corrosion and stress corrosion cracking. 3 figures.
A study was undertaken to determine experimentally the uptake of pollutants into of the different parts of the water hyacinth (Eichhornia crassipes) found in 'Jose Antonio Alzate' dam in the State of Mexico, Mexico. There is evidence for efficient and significant root accumulation of Ti, Mn, Fe, and Ba; but in the upper parts concentrations was consistently determined by the degree of watering. However, a significant input could be derived from a common generic source, such as the atmospheric deposition. The experimental study would, therefore, indicate that water hyacinth species can be highly effective in providing a control and treatment buffer for toxic discharges to the dam. (author)
The procedure for field corrosion tests in sea water is decribed in DIN 50 917, PartII. Distinction is made thereby between long-term undisturbed test specimens, which remain at the exposure site up to the time of sampling, and disturbed test specimens, which are cleaned at certain time intervals for intermediate examination and subsequently exposed again. The comparability of results obtained with the two different types of test was to be investigated at the Helgoland test installation. At an exposure period of up to four years, undisturbed specimens of unalloyed and low-alloy steel grades feature considerably lower corrosion losses than disturbed specimens. At a longer exposure period of up to seven years, the corrosion rate can increase substantially again with the exposure time. This can be attributed to sulphate reduction in the anaerobic zone under the top coating. An effect of the alloying elements is also possible. ...
The study area is located in the Bekaa plain of Lebanon totaling about 12753 ha. It lies between the eastern foothills of Mount Lebanon chain and expands across the Litani River towards the foothills of the eastern Anti-Lebanon Mountains. Its characteristics, i.e. natural terrain, climate and socio-economy, make it vulnerable especially due to soil pollution. This paper tries to identify the nature and level of soil pollution by heavy metals. Valley slopes represent a complex landform and lithology that contributed to the formation of different soil. Agriculture in the plain is being practiced mainly with cash, field crops and vegetables. Throughout the central part of the plain, groundwater table is abundant and relatively high (<1.0 m. locally) that multiplies the vulnerability of the soil-groundwater system. There are different sources of pollution, such as industrial (tanneries, batteries, leather manufacturing), solid and liquid wastes, and agricultural due ...
The study investigates the possibility of enhancing crop water productivity in the parts of Northwest India where groundwater quality is marginal and canal water supply is severely scarce. Soil, Water, Atmosphere and Plant (SWAP) model was calibrated and validated in three farmers' fields with varying canal water availability and groundwater quality in the Kaithal Irrigation Circle of the Bhakra Canal system, Haryana. On the basis of predicted and observed soil water content, pressure heads, salt concentration at 2 week intervals and crop yields, the model was found suitable for use in the region. A few nomographs were prepared to provide a graphical method to predict the effect of different combinations of water quality and depth of water application on crop yield and soil salinity and to...
In equipment industries, the equipments handling industrial water and pure water are numerous. In power generation including nuclear power generation, water serves as a working medium. Review is made on the experiences in the corrosion of iron and nickel base alloys in high temperature, high pressure water and the results of researches derived from them. Under high temperature and high pressure, carbon steel, low alloy steel, stainless steel and high nickel alloy cause corrosion even in pure water. But in the case of serious corrosion, chlorine, oxygen, alkali and others in water take part. The following matters are described: corrosion by steam; stress corrosion cracking in pure water; corrosion by impurities in high temperature, high pressure pure water, i.e. chlorine ions, dissolved oxygen, and ...
The JUPITER-II Program is the Joint Physics Large Heterogeneous Core Critical Experiments Program between the U.S. Department of Energy (US DOE) and PNC, Japan. The experiments began in May 1982 and ended in April 1984, as a part of the ZPPR-13 program. The ZPPR-13 is a series of critical assemblies designed to study the fundamental neutronic behavior of large, radially-heterogeneous LMFBR cores. This report describes the results of analysis of ZPPR-13A and preliminary analysis of ZPPR-13B, and some topics of recent activities in fast reactor physics.
This report summarizes the progress made on the development of an integrated multistage fluidized bed retorting process (KENTORT II) during the period of October 1, 1992 through September 30, 1993 under Cooperative Agreement No. DE-FC21-90MC27286 with the Morgantown Energy Technology Center, US Department of Energy. The KENTORT II process includes integral fluidized bed zones for pyrolysis, gasification, and combustion of the oil shale. The purpose of this program is to design and test the KENTORT II process at the 50-lb/hr scale. The PDU was assembled, instrumented and tested during this fiscal year. Along with the major activity of commissioning the 50-lb/hr retort, work was also completed in other areas. Basic studies of the cracking and coking kinetics of model compounds in a fixed bed reactor were continued. Additionally, as part of the effort to investigate niche market applications for KENTORT ...
A total of 86 experimental fuel pins with various fuel, liner, and cladding candidate materials have been irradiated in the Experimental Breeder Reactor-II (EBR-II) and the Fast Flux Test Facility (FFTF) reactor as part of the SP-100 fuel pin irradiation testing program. Postirradiation examination results from these fuel pin are key in establishing performance correlations and demonstrating the lifetime and safety of the reactor fuel system. This paper provides a brief description of the in-reactor fuel pin tests and presents the most recent irradiation data on the performance of wrought rhenium (Re) liner material and high density UN fuel at goal burnup of 6 atom percent (at. %). It also provides an overview of the significant variety of other fuel/liner/cladding combinations which were irradiated as part of this program and which may be of interest to more advanced efforts.
The transport of liquid water and gaseous reactants through a gas diffusion layer (GDL) is one of the most important water management issues in a proton exchange membrane fuel cell (PEMFC). In this work, the liquid water breakthrough dynamics, characterized by the capillary pressure and water saturation, across GDLs with and without a microporous layer (MPL) are studied in an ex-situ setup which closely simulates a real fuel cell configuration and operating conditions. The results reveal that recurrent breakthroughs are observed for all of the GDL samples tested, indicating the presence of an intermittent water drainage mechanism in the GDL. This is accounted for by the breakdown and redevelopment of the continuous water paths during water drainage as demonstrated by Haines jumps. For GDL ...
The river Saale cascade consists of seven reservoirs with a total capacity of approx. 415 Mio. m[sup 3]. The entire reservoir system covers a catchment area of 1665 km[sup 2]. The water management tasks extend to the following main fields: flood protection upkeep of minimum water stock, salt load control and power generation. The energy supply capacity of the cascade is mainly used by pumped storage plants. The last of these plants, Hohenwarte II, was put into service in 1963. (orig.)
A number of amines can be employed for all volatile treatment (AVT) of steam generator (SG) systems of nuclear power reactors. These amines form complexes with Cu{sup 2+} and Ni{sup 2+} ions which come into water due to corrosion. The redox reactions of a number of Cu(II)-AVT amine complexes and the stability of the transient species formed have been studied by pulse radiolysis technique. Rate constants for the reaction of e{sub aq}{sup -} with a number of Cu(II)-amine complexes have been determined by following the decay of e{sub aq}{sup -} absorption. Stability of Cu(I)-amine complexes was studied by following the kinetics of the bleaching signal formed at the {lambda}{sub max} of the Cu(II) amine complex. Except for Cu(I)-triethanolamine complex all other Cu(I)-amine complexes were found to be stable. One-electron oxidation of Cu(II) amine complexes was studied using azidyl ...
This study concerns the Souss upstream basin. The objective is to investigate the characteristics of surface water and groundwater, to assess the impact of artificial recharge as reinforcement of the natural replenishment and assess the renewal of groundwater under semi-arid area. Two major water types are observed: (i) surface waters and upstream springs (least mineralized) and (ii) all groundwater samples (prevailing calcium and magnesium bicarbonate water type). Water isotopes show a low evaporation of precipitations during infiltration. Impoverishment in heavy isotopes is the characteristic of mountain rainfalls, or of a climate colder and wetter than present. Carbon-14 activities (34-94 pmc) indicate a long residence time. The artificial recharge is low compared to the reservoir volume, due to which the renewal rate is also low.
A water trap system based on a thermoelectric cooling device is employed to remove a major fraction of the water from air samples, prior to analysis of these samples for chemical composition, by a variety of analytical techniques where water vapor interferes with the measurement process. These analytical techniques include infrared spectroscopy, mass spectrometry, ion mobility spectrometry and gas chromatography. The thermoelectric system for trapping water present in air samples can substantially improve detection sensitivity in these analytical techniques when it is necessary to measure trace analytes with concentrations in the ppm (parts per million) or ppb (parts per billion) partial pressure range. The thermoelectric trap design is compact and amenable to use in a portable gas monitoring instrumentation.
The effect of longer ice-free periods on the seasonal variation and total annual values of phytoplankton primary production was considered along with the efficiency and productivity of the phytoplankton communities at different water temperatures by constant light. The studied pond, Vasikkalampi, is located in the town Jvyaskyla in central Finland. The pond is slightly eutrophic and its water is used for cooling purposes by a 35 MW thermal powerplant. The cooling water is taken in the middle of the pond and it returns as heated effluent to the northern part, near the surface, about 100 m from the intake pipe. This circulation and warming of the water keeps the pond open throughout the year except during the coldest weeks in the winter when some parts freeze over. The increase of the water temperature was not sufficient to be optimal for ...
When exposure-calibrated ionization chambers are used to calibrate megavoltage X-ray and electron beam therapy machines, the calibration factor can be divided into a chamber-dependent and a chamber-independent component. Until recently, only the chamber-independent part, which has been derived theoretically, has been used; the chamber-dependent component has been ignored. Recent experimental and theoretical considerations, however, have indicated that the dependent component must be taken into account and can affect the calibration by as much as 4%. The calibration can change due to (i) the thickness of the chamber wall, (ii) the chamber wall composition, i.e. whether the chamber is constructed of air-equivalent material, or tissue- or water-equivalent material, and (iii) the size of the chamber changing the displacement factor. Theoretical and experimental evidence indicates that the third factor varies from approximately ...
In the design of natural gas compressor stations, a check valve is a critical element which is commonly placed on the discharge side of the compressor to prevent reverse flow that can cause serious damage to the compressor itself and other components such as seals and bearings. One of the selection criteria of the check valve for this particular application is the valve flow characteristics in steady flow, and its dynamic characteristics in unsteady flow operation. With regards to steady flow valve characteristics, current models for the determination of the check valve open angle vs. mean flow velocity are based on semi-empirical data obtained from water tests, which were found to deviate from measurements in compressible flows. This paper presents results of steady compressible flow testing of an NPS 4 swing type check valve in air. Mean flow velocities vs. disc angles were measured together with several local pressure measurements at the back side of the valve ...
This study quantifies the external water footprint of the Netherlands by partner country and import product and assesses the impact of this footprint by contrasting the geographically-explicit water footprint with water scarcity in the different parts of the world. The total water footprint of the Netherlands is estimated to be about 2300 m^3/year/cap, of which 67% relates to the consumption of agricultural goods, 31% to the consumption of industrial goods, and 2% to domestic water use. The Dutch water footprint related to the consumption of agricultural goods, is composed as follows: 46% related to livestock products; 17% oil crops and oil from oil crops; 12% coffee, tea, cocoa and tobacco; 8% cereals and beer; 6% cotton products; 5% fruits; and 6% other agricultural products. About 11% o...
In this paper, results on ozone production by atmospheric pulsed discharge, are reported. In the research, two types of ozonizer (Type I and Type II) have been used to investigate improvements of ozone concentration and production efficiency. The ozonizer has plane-to-plane metal electrodes structure, and pre-ionization electrodes are placed on the high voltage electrodes (Type I). In Type II, the surface of grounded electrode with 20 mm of width is covered partly by dielectric (thin rubber) with 11 mm of width, while the geometry of both metal electrodes is same to Type I. In the case of Type I, maximum concentration of about 100 ppm and maximum yield of 70 g/kWh were obtained at input power of 0.3 W. On the other hands, in the case of Type II, 800 ppm and 100 g/kWh were obtained at input power of 1.5 W. It was found that the ozone concentration and production yield were improved by using electrode ...
Silicones have many desirable properties and as a result are incorporated into a wide range of products. However, they present unique problems that result from their propensity to outgas resulting in residue formation at unexpected places. Hence, the silicone conundrum?when to use these materials and when to beware of potential pitfalls. In this article, an outgassing mechanism unique to ?low outgassing? silicones is discussed. Examples are given where this has led to failures and remediation steps are highlighted.
The main objective of the present thermal hydraulic analysis is to determine the thermal hydraulic characteristics of Wolsung-1 600 MWe CANDU-PHW reactor under normal operation. This is to verify and expedite the development of the nuclear fuel design and...
The Synthoil process for producing heavy desulfurized fuel oil from coal has been under development at Pittsburgh Energy Research Center since 1969. The status of development and technical feasibility of the process are reviewed. This is part of an engineering and economic evaluation based on the conceptual design of a 100,000-bbl/day commercial Synthoil facility. Experimental data are discussed with regard to their adequacy for the formulation of a basis for the process design of such a facility. Potential engineering and equipment problems are analyzed.
This paper studies on the modelling of a butterfly-type control valve actuating by an on-off pneumatic solenoid valve. The mathematical model is composed of nonlinear differential equations three parts: (i) a solenoid valve, (ii) a pneumatic cylinder, (iii) a rotary-type butterfly valve. The flow characteristics of the butterfly control valve is analysed by a computer simulator, then its simple transfer function is identified from the step responses.
Platinum(II) complexes (1-4) with bidentate N,Nprime-ligands, O,Oprime-dialkyl esters (alkyl = ethyl, n-propyl, n-butyl and n-pentyl), of (S,S)-ethylenediamine-N,Nprime-di-2-(4-methyl)pentanoic acid were synthesized and characterized by IR, 1H NMR and 13C NMR spectroscopy and elemental analysis. DFT calculations were performed for the complexes and it was found that only one diastereoisomer could be formed. Cytotoxic activity of complexes 1-4 was determined against chronic lymphocytic leukemia cells (CLL) and compared to the activity of ligand precursors L12HCl-L42HCl and corresponding palladium(II) complexes, [PdCl2L] (L = L1-L4). The complexes were found to exhibit significantly higher antitumor activities than cisplatin on CLL cells. Cytotoxic effect of platinum(II) complexes on CLL cel...
Part of the crushed activated charcoal (about 20-50%) designed for manufacture of electrodes is made water repellant with the help of an aqueous suspension of water repelling agent containing 3-15% (preferably 10%) dry substance. After this the remaining part of the activated charcoal and the other additives are mixed with the water repelling part. The plates or tape which is rolled to an assigned thickness are pressed from the obtained mixture. The electrodes obtained by this method have a thin active layer and a porous structure and have good diffusion properties. They can be loaded by currents up to 80 mA/cm/sup 2/ without causing excessive polarization losses, and their service life is greater than or equal to 100 h.
A methane catalytic decomposition reactor-direct carbon fuel cell-internal reforming solid oxide fuel cell (MCDR-DCFC-IRSOFC) energy system is highly efficient for converting the chemical energy of methane into electrical energy. A gas turbine cycle is also used to output more power from the thermal energy generated in the IRSOFC. In part I of this work, models of the fuel cells and the system are proposed and validated. In this part, exergy conservation analysis is carried out based on the developed electrochemical and thermodynamic models. The ratio of the exergy destruction of each unit is examined. The results show that the electrical exergy efficiency of 68.24% is achieved with the system. The possibility of further recovery of the waste heat is discussed and the combined power-heat exergy efficiency is over 80%. (author)
A methane catalytic decomposition reactor-direct carbon fuel cell-internal reforming solid oxide fuel cell (MCDR-DCFC-IRSOFC) energy system is highly efficient for converting the chemical energy of methane into electrical energy. A gas turbine cycle is also used to output more power from the thermal energy generated in the IRSOFC. In part I of this work, models of the fuel cells and the system are proposed and validated. In this part, exergy conservation analysis is carried out based on the developed electrochemical and thermodynamic models. The ratio of the exergy destruction of each unit is examined. The results show that the electrical exergy efficiency of 68.24% is achieved with the system. The possibility of further recovery of the waste heat is discussed and the combined power-heat e...
This article is the second part of a review of recent empirical and theoretical developments usually grouped under the heading Econophysics. In the first part, we reviewed the statistical properties of financial time series, the statistics exhibited in order books and discussed some studies of correlations of asset prices and returns. This second part deals with models in Econophysics from the point of view of agent-based modeling. Of the large number of multi-agent-based models, we have identified three representative areas. First, using previous work originally presented in the fields of behavioral finance and market microstructure theory, econophysicists have developed agent-based models of order-driven markets that we discuss extensively here. Second, kinetic theory models designed to ...
In Situ Bioremediation (ISB) is the term used in this report for Gaseous Nutrient Injection for In Situ Bioremediation. This process (ISB) involves injection of air and nutrients (sparging and biostimulation) into the ground water and vacuum extraction to remove Volatile Organic Compounds (VOCs) from the vadose zone concomitant with biodegradation of the VOCs. This process is effective for remediation of soils and ground water contaminated with VOCs both above and below the water table. A full-scale demonstration of ISB was conducted as part of the Savannah River Integrated Demonstration: VOCs in Soils and Ground Water at Nonarid Sites. This demonstration was performed at the Savannah River Site from February 1992 to April 1993.
This paper summarizes studies on the water treatment by adsorption, as for the adsorption during water treatment, reactivation of activated charcoal, and clarification of heating process. Reactivation of activated charcoal for the water treatment is carried out through drying in the heating furnace. Basic problems are the recovery degree of adsorption performance of reactivated activated charcoal and the recovery yield. Behavior of the activated charcoal in the heating reactivation furnace is divided into three stages including drying process, heating process, and gasification process. Among these processes, behaviors of organic matters during heating process are described. Thermogravimetric analyses (TGA) were conducted for activated charcoals adsorbing various organic matters in aqueous solutions. Three types of organic matters were classified from the TGA pattern, i.e., organic matters with relatively low boiling point ...
;Contents: Energy Use; Building Fabric Performance; Ventilation and Infiltration; Passive Solar Design; Heating Systems and Controls; Hot and Cold Water Provision; and Lighting and Electrical Appliances.
Contents: Energy Use; Building Fabric Performance; Ventilation and Infiltration; Passive Solar Design; Heating Systems and Controls; Hot and Cold Water Provision; and Lighting and Electrical Appliances.
This paper explores the through-/in-plane characteristics of water transport in the cathode gas diffusion layer (GDL) of a polymer electrolyte fuel cell (PEFC). Theoretical analysis is performed on the non-isothermal two-phase flow under flow channels. A dimensionless group Da (Damkohler number for PEFC operation), defined as the ratio of water generation rate to water vapor-phase removal rate, is formulated to characterize the flow regimes in a PEFC. This group, lumping geometrical parameters and physical properties, compares the water vapor-phase removal capability (via water diffusion and holding capacity) with the rate of water production by the oxygen reduction reaction. We find that this dimensionless group can be used to characterize the non-isothermal, two-phase phenomena: when Da&...
This report made for the Swiss Federal Office of Energy (SFOE) discusses the conception, planning and construction of an easy-to-operate pilot heating plant that uses chicken litter as its fuel. The plant, which is installed at a chicken farm in Boesingen, Switzerland, produces 250 - 350 kW and not only supplies heat for two chicken sheds and two households, but also provides energy for a drying plant in summer. The results of measurements made on emissions are discussed and, within the framework of an eco-balance analysis, comparisons are made between the direct use of the droppings as manure or as a fuel. The cost-effectiveness of the plant is examined and the influence of plant size and other factors discussed. Further, legal questions concerning the use of chicken litter as a fuel for heating installations are discussed; the use of the droppings as a fuel is not foreseen in the legislation concerning water protection and airborne emissions of pollutants. ...
Coal-water-slurry (CWS) engine tests designed to evaluate a new accumulator-based injection system are described in this paper The new injection system was found to improve CWS burnout considerably at both full and part engine loads. The peak cylinder firing pressure when operating with CWS was no higher than when operating with diesel oil. These data demonstrates the improved engine performance that can be achieved with the accumulator-based injection system.
The twin-cities of El Paso and Juarez share the water resources of the Hueco Bolson aquifer and overlying Rio Grande aquifer. Both aquifers span the international border between Mexico and the United States. Salinity in the Rio Grande aquifer varies widely, some parts of the shallow aquifer containing less than 1,000 mg/L total dissolved solids (TDS), other parts of the aquifer exceeding 5,000 mg/L TDS. One sizable part of the "Lower Valley" area, approximately 45 km below El Paso contains very dilute water near the outer edge of the floodplain. Historically it had been thought that the dilute waters in this location were derived from recharge from arroyos that drained proximal parts of the Hueco Bolson. Instead, our hydrogen and oxygen isotope data and carbon-14 data indicate that these dilute waters were derived ...
An evaluation was made of the effectiveness of the action of reagents used for cleaning cyan-containing waste water for conditioning of the overflow of copper concentrate thickners of the Belousovskiy enrichment before sorption extraction of gold by activated charcoal. It was established that conditioning of the overflow by iron sulfates (II), copper and zinc diminshes, and by hypochlorite increases the capacitance of the activated charcoal for gold.
The polysaccharide components from cultured cells of Rhizobium fredii USDA205 and Rhizobium meliloti AK631 were extracted with hot phenol-water and separated by repetitive gel filtration chromatography....Full Text Available
Molybdenum dioxo bis acetylacetonate shows a retention of about 31% for both "9"9Mo and "1"0"1Mo, with reactor irradiations at ambient temperature. But its radiolytic stability and resistance to hydrolysis are too low for application to "9"9Mo enrichment. The molybdenum (II) carboxylates and the arene molybdenum (O)tricaronyls show high retentions. These complexes are also air and water sensitive in solution. (orig.).
Distribution of Lipiodol within hepatic tumor was evaluated using serial computed tomography. Imagistic Lipiodol transition into the tumor via hepatic artery was slower than that of water soluble contrast medium, spreading to central part first and turn to peripheral part of the tumor. This method was thought to be useful to clarify Lipiodol distribution in hepatic tumor and to decide the method or necessity of additional trans-arterial therapy. (author).
The concept of preliminary transmutation of minor actinides before placement to the long-term storage is considered. The purpose of such preliminary transmutation before ultimate storage is to incinerate a part of actinides and to transform another part into new actinides providing low level of radiotoxicity accumulated in the storage. Modes of transmutation in reactors of PWR, PHWR (CANDU), and Superfenix types are compared. Among power reactors, heavy-water PHWR type reactor is most acceptable for preliminary transmutation. (author)
The intermediate silicon layers detector (ISL) was proposed as a part of the upgraded CDF detector at the RUN-II of the Tevatron mean value of pp collider at Fermilab, scheduled to start in year 2000. The ISL is a large-radius (20-30 cm) silicon tracker with a total active area of about 3.5 m. Located in the region between the silicon vertex detector and the central outer tracker, the ISL will allow tracking in the forward region and significantly improve it in the central area. Together with the SVX II the ISL forms a standalone, 3D silicon tracker. The challenge is to build a low-cost device which provides precise 3 D tracking in a approximately equal to 2 m long area with a minimal amount of material for the supporting structure. The conceptual design and the status of the project are reviewed.
Luminescent transition metal complexes are enjoying a growing interest because of their ubiquitous applications in, e.g., the fields of material science, sensors and (biomedical) diagnostics, and iridium(III) and ruthenium(II) complexes are among the best studied. Due to their long-living excited states, these complexes can have a strong interaction with dioxygen, resulting in luminescence quenching. This oxygen quenching might be regarded as an unwanted effect in luminescence imaging, but, on the other hand, it can be exploited for diagnostic and therapeutic applications as well. After a theoretical introduction concerning the dioxygen quenching mechanism and the parameters involved, in the second part of this review we focus on the possibility of tailoring this quenching by modifying sel...
Summary Background The seventh amendment of the European Union (EU) Cosmetics Directive (March 2005) and the Detergents Regulations of the EU (October 2005) are now legal requirements in Europe. Cosmetic products and detergents must be labelled for 26 individual named fragrances, when present at concentrations of > 10 parts per million (p.p.m.) in leave-on products and > 100 p.p.m. in rinse-off products. Objectives To make an assessment of the exposure pattern to fragrance of the U.K. consumer and to determine the frequency with which the constituent fragrances of fragrance mix I (FM I) and fragrance mix II (FM II) are included in products currently sold in the U.K. Methods A study of perfumed cosmetic and household products available on the shelves of U.K. retailers was carried out in Jan...
As part of the national survey to evaluate natural radioactivity in the environment, concentration levels of natural uranium and "2"2"6Ra have been analyzed in over 300 drinking water samples taken from different locations in Argentina. "2"2"6Ra was determined by "2"2"2Rn emanation and liquid scintillation counting, and natural uranium by a fluorimetric procedure. Values ranging from 0.03 to 24 #mu#g.l"-"1 of natural uranium and from 0.06 to 50 #mu#g.l"-"1, were measured on drinking water samples taken from tap water systems and private wells, respectively. Concentrations up to 15 mBq.l"-"1 and to 22 mBq.l"-"1 of "2"2"6Ra were found in drinking water samples taken from tap water systems and private wells, respectively. These values are compared with the reference values accepted for drinking water. Based on the water ...
Any student that has spent time in the kitchen knows that hot vegetable oil will pop and spatter violently after coming into contact with water such as that on the surface of foods (meat, fish, potatoes, etc.). This well-known effect can be used as an instructional resource to promote cooperative, active, and inquiry-based learning about central concepts of chemistry including boiling point, miscibility, and density of liquids. The starting point of the learning activity is a demonstration of (i) the effect of adding a drop of water to hot (as for cooking) vegetable oil and (ii) the effect of adding a drop of vegetable oil to hot water (near its boiling point). Intermolecular interactions, properties of vegetable oils, and a variety of other topics, such as the importance of other heat points (smoke, flash, and fire) for oils, the fundamental of the crackle test for checking the presence of ...
The stability of a solid ice cover subjected to rapidly varying water levels and discharge was investigated. The support from the bank limits the stress in the ice cover and consequently bank contact must be maintained to ensure ice cover stability. An analysis was required of the stability of ice hinges, a flexible connection between a solid ice cover and the riverbank. Phase II and phase III of the research involved a field study of the Peace River, investigating the evolution of ice hinges with water level variation, from initial ice cover cracking parallel to the banks, to a fully developed hinge. A test program of midwinter discharge variations was undertaken to gather specific data and measurements of ice hinge link length, ice thickness, hinge joint behavior, riverbank geometry, and response of ice hinging to water level variation. This volume of appendices to the study presents detailed ...
When completed, Lawrence Livermore National Laboratory's (LLNL) National Ignition Facility (NIF) will be the world's largest laser with experimental capabilities applicable to stockpile stewardship, energy research, science and astrophysics. As construction of the conventional facilities nears completion, operations supporting the installation of specialized laser equipment have come online. Playing a critical role in the precision cleaning of mechanical parts from the NIF beamline are three pieces of aqueous cleaning equipment. Housed in the Optics Assembly Building (OAB), adjacent to NIF's laser bay, are the large mechanical parts gross cleaner (LMPGC), the large mechanical parts precision cleaner (LMPPC), and the small mechanical parts gross and precision cleaner (SMPGPC). These aqueous units, designed and built by Sonic Systems, Inc., of Newtown, Pennsylvania, not only ...
Experiments on aqueous TiO{sup 2} photocatalytic reaction characteristics of 4 nitrogen-containing and 12 aromatic organic compounds were carried out. Based on the values calculated for the distribution of ionic species and atomic charge, the characteristics of their photocatalytic decomposition were estimated. It was shown that the dependence of decomposition of the N-containing compounds were linearly proportional to their nitrogen atomic charge values, while that of the aromatic compounds were inversely proportional. The effects of aqueous pH, oxygen content and concentration on the TiO{sup 2} photocatalytic characteristics of EDTA-Cu(II) and EDTA-Fe(III) were experimentally investigated. All EDTA systems were decomposed better in the pH range of 2.5{approx}3.0 and with more dissolved oxygen. These results could be applied to a unit process for removal of organic impurities dissolved in a source water of the system ...
An experimental investigation on the air/water counter-current two-phase flow in a horizontal rectangular channel connected to an inclined riser has been conducted. This test-section representing a model of the hot leg of a pressurized water reactor is mounted between two separators in a pressurized experimental vessel. The cross-section and length of the horizontal part of the test-section are (0.25mx0.05m) and 2.59m, respectively, whereas the inclination angle of the riser is 50degree. The flow was captured by a high-speed camera in the bended region of the hot leg, delivering a detailed view of the stratified interface as well as of dispersed structures like bubbles and droplets. Countercurrent flow limitation (CCFL), or the onset of flooding, was found by analyzing the water levels mea...
This study evaluated whether differences in design of 3-dimensional polylactic acid barriers (EPi-Guide and Guidor) would influence hard tissue results in the treatment of Grade II furcations in humans. A multicenter study was conducted, using 40 patients with moderate to advanced bilateral chronic adult periodontitis of the mandibular first or second molars. After flap access, debridement, and root preparation, surgical bone level measurements were taken and membranes were placed on a random basis. Surgical reentry occurred at 1 year. Data collected from all 3 investigative centers were pooled and analyzed using an analysis of variance appropriate for a counterbalancing design. Both barrier materials resulted in significant gains of attachment level and defect reduction. The composite reduction in the vertical component of the osseous defects was greater in the sites treated with Epi-Guide as compared to those treated with Guidor; the difference between barriers ...
A total of 272 tap water samples were collected from 68 homes throughout the city of Tehran. Analysis for cadmium, zinc, lead, copper, arsenic, iron and manganese showed some accumulation of these metals in household piping overnight. However, the concentration of all metals was in the parts per billion (ug/l) range and well below international standards. Heavy metals in Tehran's drinking water therefore, do not pose a significant acute health hazard. 19 references, 2 tables.
Outcrops of Tertiary coal-bearing units in sea cliffs of the Kenai Peninsula provide an excellent study area for volcanic ash partings in coals. Twenty mid-to late-Miocene, 50-cm to 3-m thick coal seams exposed in the sea cliffs about 10 km west of Homer contain an average of 10 volcanic ash or lapilli tuff partings each. The bedding relationships of the coal with any one parting cannot be predicted, and the contacts of the partings with the coal range from very sharp to predominantly gradational. These bedding relationships provide clues about the surface on which the ashes fell and on which the coal was accumulating. For example, some ashes fell in standing water, others on irregular subaerial surfaces. The partings are in various stages of alteration to kaolinite and bentonite, and vary in thickness from a few millimeters to about 10 cm. The consistency and ...
The hydration behavior of a number of square planar Pt(II) bis(cyano) complexes has been examined, and the limiting stoichiometries are related to the steric requirements of the dinitrogen bidentate ligands coordinated to the metal center. In particular, the IR, UV/vis, and [sup 1]H, [sup 13]C, and [sup 195]Pt NMR spectroscopic data for the compound Pt[sup II]dtbipy(CN)[sub 2] [dtbipy = 4,4[prime]-[l brace]C(CH[sub 3])[sub 3][r brace][sub 2]-2,2[prime]-bpy] have been determined and show that, at relative humidities (rh) above [approximately]40%, this complex sorbs five water molecules at room temperature. The sorption process consists of a rapid step in which one H[sub 2]O adds to the complex and which appears to be independent of rh, followed by a slower, rh-dependent step leading to the final stoichiometry. In contrast, the analogous 2,2[prime]-bpy complex sorbs no water under these conditions, while ...
To investigate the variation in the fine structure of polyamide thin-film composite (TFC) membranes prepared via two different interfacial polymerization conditions (IP-I and IP-II), experiments on Scanning Electron Microscopy (SEM), Atomic Force Microscopy (AFM), water contact angle, and positron annihilation spectroscopy (PAS) coupled to a slow positron beam were conducted. Polyamide TFC membranes were prepared via the interfacial polymerization reaction between triethylenetetramine (TETA) and trimesoyl chloride (TMC) on the surface of a modified polyacrylonitrile (mPAN) membrane. Compared with the polyamide TFC membrane prepared via IP-I, the polyamide layer prepared via IP-II showed a shorter S plateau length (thinner thickness), a higher o-Ps intensity I3 value (higher free-volume con...
This study evaluates the degree to which surface impoundments at licensed facilities comply with significant changes in NRC requirements initiated by enactment of EPA's final environmental standards for uranium recovery facilities (40 CFR Part 192). Impoundment liner requirements, ground-water protection standards, ground-water monitoring and corrective action programs, and site closure standards are the most significant regulatory modifications. The compliance status of 30 conventional mills and 31 in-situ mines is determined from a review of Nuclear Regulatory Commission and agreement state docket files through November, 1983. Results of this review show that a majority of conventional uranium mill tailings management systems are deficient with respect to liner requirements for new impoundments or proposed expansions to existing impoundments, as well as with respect to some aspects of ground-water ...
A nucleoside triphosphate binding site on calf thymus RNA polymerase II was identified by using photoaffinity analogues of adenosine 5'-triphosphate and guanosine 5'-triphosphate. Both radiolabeled 8-azidoadenosine 5'-triphosphate (8-N3ATP) and radiolabeled 8-azidoguanosine 5'-triphosphate (8-N3GTP) bound to a single polypeptide of this enzyme. This polypeptide has a molecular mass of 37 kilodaltons and an isoelectric point of 5.4. Ultraviolet (UV) irradiation was necessary for photolabeling to occur. In addition, no labeling occurred when the probe was prephotolyzed or when the enzyme was inactivated. Furthermore, photolabeling of the enzyme could be decreased by preincubation with natural substrates. To provide evidence that the radiolabeled polypeptide forms a part of the domain of the nucleoside triphosphate binding site, experiments were performed using unlabeled 8-N3ATP. Although this unlabeled analogue ...
This is the seventh report by the Advisory Committee on Reactor Safeguards (ACRS) in response to the Congressional requirement for an annual report on the Nuclear Regulatory Commission (NRC) Reactor Safety Research Program. As previously requested by the Congress, the timing of this report has been adjusted to enable the ACRS to address the proposed budget for FY 1985 that has been submitted to the Congress by the President. Part I is a compilation of our comments and recommendations regarding the NRC Safety Research Program budget for FY 1985. It is intended to serve as an Executive Summary. PartII is divided into eight chapters, each of which represents a Decision Unit of the NRC research program. In each chapter, specific comments are included on the research involved in the Decision Unit, an assessment of priorities, and recommendations regarding new directions and levels of funding.
This is the sixth report by the Advisory Committee on Reactor Safeguards (ACRS) that has been prepared in response to the Congressional requirement for an annual report on the Nuclear Regulatory Commission (NRC) Reactor Safety Research Program. Part I is a compilation of our general comments and recommendations regarding the NRC Safety Research Program, and includes budget recommendations and an identification of matters of special importance that deserve increased emphasis. It is intended to serve as an Executive Summary. PartII is divided into ten chapters, each of which represents a Decision Unit of the NRC research program. In each chapter, specific comments are included on the research involved in the Decision Unit, an assessment of priorities, and recommendations regarding new directions and levels of funding.
A new controlled-clearance pressure balance is under development with the aim of improving the hydraulic high-pressure standard up to 1 GPa. This pressure balance consists of three parts: (i) a pressure generation device up to 1 GPa, (ii) a weight-loading unit which can load/unload weights automatically and independently, (iii) a controlled-clearance piston-cylinder which is designed to allow the jacket pressure to be applied independently. Some adjustments were made for loading heavy weights on/off the piston safely, keeping them in balance, then generating the pressure stably. Stability of the generated pressure was checked for several piston-cylinders, and it was found that pressure fluctuation was less than a few parts per million. The jacket pressure coefficient of a 500 MPa controlled-clearance piston-cylinder was precisely evaluated as a function of both the system pressure and the jacket pressure.
The Idaho Chemical Processing Plant (ICPP) Water inventory Study was initiated in September 1993 with the formation of a joint working group consisting of representatives from DOE-ID, State of Idaho INEL Oversight Program, US Geological Survey, and INEL employees to investigate three issues that had been identified by the INEL Oversight Program at ICPP: (1) the water inventory imbalance at ICPP, (2) the source of water infiltrating into the Tank Farm vault sumps, and (3) the source of water providing potential recharge to perched water bodies underlying ICPP. These issues suggested that water was being lost from the ICPP distribution system. The INEL Oversight Program was concerned that the unaccounted for water at ICPP could be spreading contaminants that have been released over the past 40 years of operations of ICPP, possibly to the Snake ...
The model of `ecological forestry' has evolved as a part of the development of the concept of ecosystem management. `Ecological forestry' emphasises that manipulation of a forest ecosystem should consider, and as far as practicable work within the limits of, natural disturbance patterns prior to extensive human alteration of the landscape. This paper evaluates the extent to which forest management practices in jarrah (Eucalyptus marginata) and karri (Eucalyptus diversicolor) forests of south-western Australia align with this view of the characteristics and appropriate silviculture of `ecological forestry'. Characteristics and appropriate silviculture of `ecological forestry' are evaluated in relation to (i) the stand level decisions of stand structure and harvest timing and (ii) the landsc...
In-situ sodium activated organo modified bentonite clay was also used for partial replacement of the carbon black (N330). Detailed study with the black filled compound revealed that, with slight modification of the curing package, up to 10 phr of the carbon black replacement is possible. At equivalent loading of 5 and 10 phr of in-situ sodium activated organo modified bentonite clay exhibited better properties in comparison to carbon black filled compound.
We analyse several amorphous Pdsub(1-x)Sisub(x) alloys obtained by simulation. The metalloid atoms environments can be studied in the same way as that described in the first paper of this series. The main part of this paper is devoted to the evolution of the density as a function of the concentration. In order to interpret the values obtained by the simulation, we develop two models: the first one assumes a complete disorder: the second one, which is shown to be better, assumes a tendency to a local ordering: Si atoms are assumed to have only Pd neighbours.
As part of a project to complete a comprehensive catalogue of astrophysically relevant emission lines in support of new-generation X-ray observatories using the Lawrence Livermore electron beam ion traps EBIT-I and EBIT-II, we studied emission lines of argon and sulfur in the soft X-ray and extreme ultraviolet region. Here we present observations of Ar IX through Ar XVI and S VII through S XIV between 20 and 75 {angstrom} to illustrate our work.
The single specimen unloading compliance technique has become the preferred method for evaluating J-integrals. It involves data acquisition and analysis using a computer. This paper describes in detail the development of a simple experimental system and related software that can be used in a laboratory equipped with a microcomputer and with access to a minicomputer. The effects of loading rate, test temperature, specimen geometry and material composition can be readily evaluated using this system. The results on a pressure vessel steel and an #alpha#-#beta# titanium alloy are discussed in PartII. (author).
Experience at SRS, ORNL, BNL, and Georgia Institute of Technology involving irradiated aluminum clad fuel and target elements, as well as studies of non-irradiated aluminum indicate that some types of aluminum assemblies can be kept in a continually well-deionized water atmosphere for up to 25 years without problems. SRS experience ranges from 2.75 years for the L-1.1 charge kept in deionized D[sub 2]O[sup 1] to greater than 10 years for assemblies stored in the Receiving Basin for Off-site Fuel (RBOF)[sup 2]. Experience at Georgia Institute of Technology reactor in Atlanta yielded the longest value of 25 years without problems. The common denominators in all of the reports is that the water is continually deionized to approximately 2 M[Omega] (2 [times] 10[sup 6]ohms) resistivity and the containers for the water are stainless steel or other non-porous material. This resistivity value is equivalent to a value of 0.5 ...
Experience at SRS, ORNL, BNL, and Georgia Institute of Technology involving irradiated aluminum clad fuel and target elements, as well as studies of non-irradiated aluminum indicate that some types of aluminum assemblies can be kept in a continually well-deionized water atmosphere for up to 25 years without problems. SRS experience ranges from 2.75 years for the L-1.1 charge kept in deionized D{sub 2}O{sup 1} to greater than 10 years for assemblies stored in the Receiving Basin for Off-site Fuel (RBOF){sup 2}. Experience at Georgia Institute of Technology reactor in Atlanta yielded the longest value of 25 years without problems. The common denominators in all of the reports is that the water is continually deionized to approximately 2 M{Omega} (2 {times} 10{sup 6}ohms) resistivity and the containers for the water are stainless steel or other non-porous material. This resistivity value is equivalent to a value of 0.5 ...
Considerations were given on typical applications of nylon resin parts to automotive use and their future trends through news topics. GF strengthened nylon resin is used in cylinder head covers substituting aluminum because of advantages in nylon resin of weight reducibility, vibration suppressibility, and noise shielding capability. Radiator tank uses N66GF 30% strengthened nylon in more than 60% of bonnet type passenger cars. Nylon resin is used most in harness connectors installed in locations that require heat resistance. External car parts such as bumpers, fenders, and wheel caps use to some extent nylon resin in the form of strengthened and up-graded polymer alloy. BMW in Germany used in its high-class production cars intake manifolds made of GF strengthened Nylon 66. The majority of engine{prime}s gas intake system parts has been replaced with Nylon blow-formed parts. The resin industry is aiming ...
Effect of water injection/draining on elastic waves penetrating through cracks is examined by measuring elastic waves before, during, and after the injection/draining of water into/from cracks in presence in granite. Two blocks of rock, with their crack-containing surfaces in contact with each other, are placed in a vessel, and water injection/draining is done through a hole on a vessel bottom side so that water will penetrate into the cracks. When the blocks are dry, there is almost no contact between the cracks, and so no crack penetrating waves are observed. Crack penetrating waves are produced when water is injected, and the position of the receiver sensing the penetrating waves changes as the water level rises. When the water level is lowered from the high water level, the waveform changes again as the level ...
This is Volume 3 in a series of documents on energy efficiency of consumer products. This volume discusses energy efficiency of water heaters. Water heaters are defined by NAECA as products that utilize oil, gas, or electricity to heat potable water for use outside the heater upon demand. These are major appliances, which use a large portion (18% on average) of total energy consumed per household (1). They differ from most other appliances in that they are usually installed in obscure locations as part of the plumbing and are ignored until they fail. Residential water heaters are capable of heating water up to 180{degrees}F, although the setpoints are usually set lower.
Special T-shaped feedwater distribution pipes were installed in steam generators at the Loviisa (Finland) and Rovno (Russia) nuclear power plants. The new shape was tested in an extensive testing programme. Since the tubes frequently suffer from corrosion damage, large-scale water hammer experiments were performed on a model facility in 1996. The main objectives of the water hammer experiments were to find out the prevailing parameters leading to water hammers, as well as the sensitivity of hammering to boundary conditions. A water hammer may occur when the mass flow rate into the steam generator exceeds 6 kg/s and the temperature difference between steam generator and feedwater exceeds 100 degC. Visual experiments and stress analyses of the pipe were also carried out. The weakest part, the T-joint, may hold against such water hammers only for a limited time of ...
This document describes products which the US EPA Wetlands Research Program proposes to develop during the years 1989-1994. The general protocols used to develop these products are also described. All these products are intended to address concerns about the wetlands and water quality, and are part of a larger set of products EPA is developing to deal with other aspects of wetlands. EPA's highly interrelated concerns about wetlands and water quality can be generally categorized as follows: water quality criteria to protect wetland function; ecological status of the wetland resource; and waste-assimilation limits of wetlands.
For optimal performances, proton exchange membrane fuel cells require fine water and thermal management. Accurate modelling of the physical phenomena occurring in the fuel cell is a key issue to improve fuel cell technology. Here, an analytic steady state diphasic 2D model of heat and mass transfer is presented. Through this model, the aim of this work is to study the influence of local events on the global performances of a fuel cell. A part of the complete model is a microscopic representation of the coupling between water transport and charge transfers in the electrodes. The thickness of the liquid layer around the reactive agglomerates is deduced from the saturation. The evolution of the quantity of water within the catalyst layer is monitored and its influence on the global performanc...
Perinatal exposure to cadmium (Cd) or methylmercury (MeHg) results in impaired neurodevelopment. Thyroid hormone is essential for normal brain development. However, the issue whether Cd or MeHg, especially at low doses, interrupts thyroid hormone action remains to be investigated. In the present study, effects of perinatal exposure to low levels of Cd or MeHg on thyroid hormone metabolism were examined using metallothionein I and II (MT-I/II) null or wild-type neonatal mice. Dams were exposed to 10 mg/L water of Cd or 5 mg/kg chow of MeHg from gestational day 0 to post-natal day 10 (PND 10). Sera, livers and brains were collected from neonates on PND 10. Iodothyronine deiodinase activities and serum thyroxine (T4) concentrations were measured. MeHg exposure failed to induce changes in serum T4 levels and liver type 1 deiodinase (D1) and brain type 2 deiodinase (D2) activities regardless of the MT genotype. However, exposure ...
To evaluate the feasibility and clinical effectiveness of using a polyurethane-covered expandable nitinol stent in the palliative treatment of malignant duodenal obstruction. Under fluoroscopic guidance, a polyurethane-covered expandable nitinol stent was placed in 12 consecutive patients with malignant duodenal obstructions. All presented with severe nausea and recurrent vomiting. The underlying causes of obstruction were duodenal carcinoma (n=4), pancreatic carcinoma (n=4), gall bladder carcinoma (n=2), distal CBD carcinoma (n=1), and uterine cervical carcinoma (n=1). The sites of obstruction were part I (n=1), partII (n=8), and III (n=3). Due to pre-existing jaundice, eight patients with partII obstructions underwent biliary decompression prior to stent placement. An introducer sheath with a 6-mm outer diameter and stents 16 mm in diameter were employed, and to place the stent, ...
Case studies are presented for treatment of refinery wastes in a pilot-scale thin-film evaporator, the removal of volatiles from industrial wastewater for two steam strippers, and the removal of semivolatiles from water by steam stripping followed by liquid-phase carbon adsorption. The report provides data on removal efficiency, air emissions, process residuals, treatment costs, and process limitations. Details on sampling and analytical procedures, quality assurance, and process data are contained in the Appendixes (Volume II).
Case studies are presented for treatment of refinery wastes in a pilot-scale thin-film evaporator, the removal of volatiles from industrial wastewater for two steam strippers, and the removal of semivolatiles from water by steam stripping followed by liquid-phase carbon adsorption. The report provides data on removal efficiency, air emissions, process residuals, treatment costs, and process limitations. Details on sampling and analytical procedures, quality assurance, and process data are contained in the Appendixes (Volume II).
The manual was prepared for State and local government officials, local emergency planning committee (LEPCs), and other community groups that want to make Title III work. It is intended as a practical guide for those who have little or no previous experience in the field of communication, whose time must be snatched from home and office, and whose resources are limited. The manual has three major sections: Part I discusses planning, which is vital to the success of a communication program; PartII suggests ways to get and keep people involved, especially important because Title III affects so many different sectors of the community; Part III, a how-to-do-it section, talks about specific tasks, such as giving a speech or writing a press release. Appendices include a detailed explanation of the law, a glossary, a list of recent studies related to Title III communications, a list of educational materials, ...
A new three-dimensional treatment planning system (TPS) based on convolution/superposition algorithms (TMS-Radix from HELAX AB, Uppsala, Sweden) was recently installed at the University Hospital in Lund. The purpose of the present study was to design a quality assurance and acceptance testing programme to meet the specific characteristics of this convolution model. The model is based on parametrization of a non-measurable quantity - the polyenergetic pencil beam. However, the verification of the treatment planning model is still dependent on numerous comparisons of measured depth-doses and dose profiles. The test programme was divided in two basic parts: (i) model implementation and beam data consistency and (ii) model performance and limitations in special situations. The first part was scheduled for all photon beam qualities available before they could be used for clinical treatment planning. The second ...
In this updated second edition, the order of contents of the textbook has been reorganized. It has been divided into main parts: Basic Science and Clinical Nuclear Medicine. Basic Science, Part I, encompasses basic physics, radiation protection, interaction of radiation with matter and radiation detection, imaging, nuclear pharmacy, and radiation biology. PartII, Clinical Nuclear Medicine, covers the central nervous system, bone, gastroenterology (liver/spleen), cardiovascular system, pulmonary system, genitourinary system, thyroid and endocrine systems, gallium studies, radioassay, hematology, and therapy. The total number of pages of the current edition is increased to 250 from the 213 of the first edition but there are fewer questions because those in the basic science area have been carefully selected to 60 of the original 98 questions. Compared with the previous edition, there are two advantages ...
This paper describes a new method, HGV2C, for pattern analysis. The HGV2C method involves the construction of a computer ego (CE) based on an individual object that can be either a part of the system under analysis or a newly created object based on a certain hypothesis. The CE provides a capability to analyze data from a specific standpoint, e.g. from a viewpoint of a certain object. The CE is constructed from two identical copies of a query object, and its functioning mechanism involves: a hypothesis-parameter (HP) and infothyristor (IT). HP is a parameter that is introduced into an existing set of parameters. The HP value for one of the clones of a query object is set to equal 1, whereas for another clone it is greater than 1. The IT is based on the previously described algorithm of iterative averaging and performs three functions: 1) computation of a similarity matrix for the group of three objects including two clones of a query object and a target object; 2) ...
The objectives of this contract are to conduct exploratory coal liquefaction research on modified solvents with slurry phase catalysts and on coal pretreatment. This report describes a review of the existing literature as well as currently on-going research in the areas of: (1) solvent quality effects on coal liquefaction; (2) role of heteroatoms in liquefaction of coal; (3) heteroatoms removal through solvent treatment, extraction and hydrogenation; (4) slurry phase catalysts in hydroprocessing of coal; and (5) effect of coal preparation and pretreatment on liquefaction. The review encompasses both technical papers and presentations as well as the patent literature. This report is comprised of two distinct parts. In Part I all the literature available on the effect of solvent quality, heteroatoms, heteroatoms removal, and slurry phase catalysts on coal liquefaction is incorporated. The existing literature and currently on-going research in the ...
A few metal complexes of isatin-isonicotinoylhydrazone with Ni(II), Cr(III), Co(II), Cu(II), Zn(II) and Cd(II) have been prepared and characterized on the basis of elemental analyses, infrared and electronic spectra as well as "1H NMR spectra, conductivity and magnetic measurements. In view of the results obtained, it has been found that two molecules of isatin-isonicotinoylhydrazone are chelated to the central metal ion as bis-uninegative ONO tridentate ligand forming non-electrolytic octahedral metal complexes. (author)
The prevailing severe shortage of animal feed in most of the developing countries could, to a considerable extent, be overcome through improved range management, which includes introduction of high yielding drought-resistant forage crops, development of adequate water conservation measures, and as far as possible growing annual forage crops on part of the vast areas of arable land currently left fallow each year. Year round measurements are essential for a good understanding of soil water and nutrients dynamics, which allow for adequate evaluation of pasture management alternatives. The methods most commonly used for moisture measurements in soil profiles are discussed because such measurements are likely to form an essential part of any investigation aimed at increasing animal feed production through the development of adequate pasture management practices. (author).
This article reports on the world's first gas turbine to top 40% thermal efficiency in simple cycle and is now operating commercially as part of a natural-gas-fired combined-cycle cogeneration (CC) plant serving the Ottawa Health Sciences Center, Ottawa, Ont, Canada. Owned and operated by TransAlta Energy Corp, Calgary, Alta, the CC plant supplies steam and hot and chilled water to the health center and another thermal user while the electricity is sold to Ontario Hydro. Part of the project included the conversion of 15-psig steam-carrying equipment to hot-water service. Commercial success of this installation heralds a new era in the application of efficient gas turbines for power generation.
In an attempt to overcome inadequacies perceived in the approach to providing energy to village communities using the conventional Khadi and Village Industries Commission biogas plant as well as the Janata model, a biogas digester has been developed suitable for a farmer having only one hectare of land. The information on gas yields and other data from a variety of substrates in a laboratory digester are presented. The digester itself consists of a chamber underground into which the influent flows through a channel. Gas is collected in a dome which constitutes the upper part of the digestion chamber and is maintained under pressure by water. The dome can be made of any suitable material such as plastic, ferrocement and brick and mortar. The upper part of the chamber itself is exposed to sun light which enhances microbial growth. Water which surrounds the dome ensures a minimum of temperature variation. ...
In marine seismic exploration, an approximately two-mile long hydrophone cable is towed behind the ship. The commonly employed cable consists of a kerosene-filled hose enclosing hydrophones, electrical wires, and steel ropes. The kerosene provides buoyancy while the steel ropes are for structural support. For deep-water operations, the cable is pulled through the water at a depth of 20-40 feet. For shallow water, a bottom reference configuration is used and the cable is dragged. This paper presents a comparison of electroacoustic properties between a newly designed, buoyant solid cable and those of the conventional kerosene-filled hose. The emphasis is on drag cable operations. Cable maintenance is a major problem. Jacket cuts occur because of improper handling or collisions with other ships, subsea structures, and debris. Kerosene leakage causes buoyancy loss and the need for immediate replacement. Salt ...
We present sensitive high angular resolution (0.''57-0.''78) SO, SO_2, CO, C_2H_5OH, HC_3N, and HCOCH_2OH line observations at millimeter and submillimeter wavelengths of the young O-type protostar W51 North made with the Submillimeter Array. We report the presence of a large (about 8000 AU) and hot molecular circumstellar disk around this object, which connects the inner dusty disk with the molecular ring or toroid reported recently and confirms the existence of a single bipolar outflow emanating from this object. The molecular emission from the large disk is observed in layers with the transitions characterized by high excitation temperatures in their lower energy states (up to 1512 K) being concentrated closer to the central massive protostar. The molecular emission from those transitions with low or moderate excitation temperatures is found in the outermost parts of the disk and exhibits an inner cavity with an angular size of around 0.''7. We modeled all lines ...
This article is divided in five parts, the first one having nothing to do with tachyons. In fact, to prepare the ground, in part I (sect.2) we shall merely show that special relativity - even without tachyons - can be given a form such to describe both particles and antiparticles. PartII is the largest one: initially, after some historical remarks and having revisited the postulates of special relativity, we presnt a review of the elegant ''model theory'' of tachyons in two dimensions; passing then to four dimensions, we review the main results of the classical theory of tachyons that do not depend on the existence of Superluminal reference frames (or that are at least independent of the explicit form of the Superluminal Lorentz ''transformations''). In particular, we discuss how tachyons would look like, i.e. their apparent ...
Hydrologic data were collected in early 1985 from the northern part of the Hueco Bolson in Dona Ana County, New Mexico, and El Paso County, Texas, and in adjacent areas in the Tularosa Basin in New Mexico. Water-level measurements made in 50 wells are presented in this report. Information is also presented on groundwater withdrawals from the Hueco Bolson by El Paso and Ciudad Juarez municipal wells, by industrial and military wells, and by wells in the Chaparral, New Mexico, area that have been used for both irrigation and municipal purposes. Lithologic logs and geophysical logs are included for four test wells that were drilled as part of this project during August and September 1985. (USGS)
This report describes an investigation of the performance of air-augmented waterjet thrusters. The investigation is divided into two parts. Part one describes a study of the injection of large diameter air bubbles to reduce heat transfer between the air and water and, thus, increase the thrust. This study is done analytically by solving the appropriate, governing equations. The results indicate that the approach is very worth-while since thrust can be increased ten percent as compared to air-augmentation with small bubbles. Several practical systems are discussed for injecting large air bubbles. Part two is an experimental investigation of the thrust produced under a wind range of conditions. The results show that a thrust increase of more than 20 percent can be achieved by air-augmentation. Further, the performance improves for larger thrust nozzles.
A virtual balancing axis arrangement is described for multi-cylinder reciprocating piston machines for effectively balancing out imbalanced forces and minimizing residual imbalance moments acting on the crankshaft of such machines without requiring the use of additional parallel-arrayed balancing shafts or complex and expensive gear arrangements. The novel virtual balancing axis arrangement is capable of being designed into multi-cylinder reciprocating piston and crankshaft machines for substantially reducing vibrations induced during operation of such machines with only minimal number of additional component parts. Some of the required component parts may be available from parts already required for operation of auxiliary equipment, such as oil and water pumps used in certain types of reciprocating piston and crankshaft machine so that by appropriate location and dimensioning in accordance with the ...
The water culture experiment of Houttuynia cordata of the medicinal plant was carried out, and basic study on {sup 137}Cs accumulation characteristic and internal circulation in H. cordata in the fruiting stage was investigated since the flowering season. H. cordata accumulated 80% of {sup 137}Cs absorbed unlike K to the root, rhizome, terminal bud of the underground part for the rhizome reproduction. {sup 137}Cs content to the young leaf, spike, involucre increased in the flowering season. Thereafter, {sup 137}Cs was recirculated to the developing organs in second generations such as the rhizome and bud. (author)
The McMaster Neutron Radiography Facility (MNRF) is fortunate to own the only Real-Time Neutron Radiography system in Canada. Current research at the MNRF involves the visualization of gas-liquid and gas-solid two-phase flow in complex channels, such as nuclear fuel channels, using light water, heavy water, freon-134A, slurries, and other fluids. Other research at the MNRF has examined single-phase flow, material purity, film deposition, turbine blades, and automotive parts.
Actinides other than the main uranium or plutonium isotopes take a growing part in the different stages of the nuclear cycle. For the French nuclear power program based on the development of light water reactors and fast breeders, many evaluations of the secondary actinides build up are made for the both reactor types using mainly the existing reactor codes. The comparison of these foreseen compositions with experimental results allows to perform some adjustments of the neutronic data. The secondary actinide compositions are given for some typical fuels and their consequences on the nuclear cycle are discussed. An hypothetical burning of these wastes in fast reactors has been studied and the main conclusions are reported.
A proton exchange membrane fuel cell (PEMFC) must maintain a balance between the hydration level required for efficient proton transfer and excess liquid water that can impede the flow of gases to the electrodes where the reactions take place. Therefore, it is critically important to understand the two-phase flow of liquid water combined with either the hydrogen (anode) or air (cathode) streams. In this paper, we describe the design of an in situ test apparatus that enables investigation of two-phase channel flow within PEMFCs, including the flow of water from the porous gas diffusion layer (GDL) into the channel gas flows; the flow of water within the bipolar plate channels themselves; and the dynamics of flow through multiple channels connected to common manifolds which maintain a uniform pressure differential across all possible flow paths. These two-phase flow effects have been studied at relatively ...
The required introduction of on board diagnosis II in the USA from the 94 models onward has led vehicle manufacturers and system suppliers to develop corresponding diagnosis processes at the beginning of the 1990`s. These systems are now in mass production for TLEV and partly for LEV requirements. Based on experience from the wide use of these functions, new knowledge has been obtained, which must be taken into account in the development of future systems. The additionally more severe emission and diagnosis requirements make further minimisation of the overall tolerances on the one hand, and a revision of the existing diagnosis algorithms necessary. In parallel with this, the Law must create the necessary outline conditions, where the requirements for the vehicle manufacturer and system suppliers must also be met. The OBD II development must therefore certainly not be regarded as complete. [Deutsch] Die in den USA ab ...
Manganese is a common contaminant of mine water and other waste waters. Due to its high solubility over a wide pH range, it is notoriously difficult to remove from contaminated waters. Previous systems that effectively remove Mn from mine waters have involved oxidising the soluble Mn(II) species at an elevated pH using substrates such as limestone and dolomites. However it is currently unclear what effect the substrate type has upon abiotic Mn removal compared to biotic removal by in situ micro-organisms (biofilms). In order to investigate the relationship between substrate type, Mn precipitation and the biofilm community, net-alkaline Mn-contaminated mine water was treated in reactors containing one of the pure materials: dolomite, limestone, magnesite and quartzite. Mine water chemistry and Mn removal rates were monitored over a 3-month ...
In 10 cases of femoral neck fracture treated with prosthetic replacement, the preoperative sup(99m)Tc-MDP scintigraphs were investigated and then compared with each histological findings of the extracted femoral head. The appearances of the scintigraphs were classified into following 3 patterns; increased activity pattern of sup(99m)Tc-MDP uptake in the overall femoral head (type I) in 4 cases, deficient activity pattern at the lateral side correspond to weight-bearing area (type II) in 2 cases and considerably deficient activity pattern in the whole femoral head (type III) in remaining 4 cases. Histological examination of the extracted femoral heads revealed the narrow part of ischemic necrosis in type I. However type II showed extensive necrosis in the portion of deficient activity by scintigraphs and in type III, the femoral heads except articular cartilage were entirely necrotic. This classification of sup(99m)Tc-MDP ...
In IO cases of femoral neck fracture treated with prosthetic replacement, the preopera tive sup(99m)Tc-MDP scintigraphs were investigated and then compared with each histological findings of the extracted femoral head. The appearances of the scintigraphs were classified into following 3 patterns; increased activity pattern of sup(99m)Tc-MDP uptake in the overall femoral head (type I) in 4 cases, deficient activity pattern at the lateral side correspond to weight-bearing area (type II) in 2 cases and considerably deficient activity pattern in the whole femoral head (type III) in remaining 4 cases. Histological examination of the extracted femoral heads revealed the narrow part of ischemic necrosis in type I. However type II showed extensive necrosis in the portion of deficient activity by scintigraphs and in type III, the femoral heads except articular cartilage were entirely necrotic. This classification of sup(99m)Tc-MDP ...
In the 5th year of the Japan International Cooperation Agency (JICA) Technical Cooperation Project 'Seismic Risk Reduction for Buildings and Structures in Romania', the implementing agency - National Center for Seismic Risk Reduction (NCSRR) and JICA jointly organized the International Symposium on Seismic Risk Reduction (ISSRR-2007) held in Bucharest at the Romanian Academy Library in the period April 26-27, 2007. The present volume contains the Proceedings of the International Symposium on Seismic Risk Reduction, ISSRR-2007. The Proceedings are organized in three parts: (I) keynote lectures, (II) papers on the results of JICA Project in Romania and (III) contributions from authors. Eight keynote lectures by specialists from Japan, USA, France and Greece, and fourteen papers on the results of JICA Project are included. The contributions from authors are divided in five sections: (i) Seismicity, Seismic Hazard and Site Effects, ...
The American Natural Resources System has been attempting to obtain the financing commitments and regulatory approvals necessary to construct the nation's first commercial-scale coal-gasification plant. It would employ the same technology as Sasol plants of South Africa and much of the same hardware as the Sasol II plant now approaching completion. But instead of converting the gas that comes out of the gasifier vessels into liquid hydrocarbons, the proposed plant would upgrade the gas to a Btu-content equivalent to that of natural gas. It could be mixed, transported, and utilized as a constituent part of the natural gas stream. The plant would be located in North Dakota and would utilize coal as the feedstock. North Dakota lignite gasifies very efficiently and, since the plant would be located at the mine mouth, the low-Btu quality of the coal is not a particularly adverse factor. The gas produced by the plant would be transported by ...
Cu"2"+ ions are alternatively bridged by end-on and asymmetrical end-to-end (EE) azido groups in copper (II)-azido compound [#left brace#Cu(L)(N_3)_2#right brace#_n] (L=benzylamine). The electronic structure of its ferromagnetic ground state has been calculated using the self-consistent full-potential linearized augmented plane wave method based on the density functional theory. The spin populations have been found to be strongly positive on the Cu"2"+ ions, weakly positive on the terminal nitrogen atoms of the azido groups as well as on the nitrogen atoms of the benzylamine, and feeble on the central nitrogen atoms of the azido groups. Based on the spin distribution obtained from calculation, the ferromagnetic coupling through the azido groups has been analyzed as resulting from a spin delocalization from the Cu"2"+ ions toward the azido groups. But the result also indicates that the spin polarization effect may also take part in the magnetic ...
The report examines the scientific progress which has been made over the past years on the climate change issue. It examines shifts in emphasis on climate change debates and the implications of scientific uncertainty for the policy maker. Information on the impact of climate on various sectors, such as agriculture and coastal zones is also provided, as well as a case study on the UK. Regional impacts of climate change and associated economic implications are considered. The report also documents some different considerations for a climate change policy in the context of the latest meeting of contracting parties to the Un Framework Convention on Climate Change, held in Kyoto in December 1997. The report is divided into five sections: Introduction; Scientific progress; Climate change policy - the dilemma with implementation; Summary and conclusions; Summary of Kyoto`s results. 146 refs., 4 figs., 14 tabs., 2 apps.
In the year 1996 the spheres of competence of several DLR-Institutes working in the areas of fluid dynamics, reaction kinetics, combustion, numerical methods and laser measuring techniques have been brought together while contributing to the internal DLR project 'combustion chamber modelling (BKM)', in order to proceed with the computational simulation of combustion processes in combustion chambers of gas turbines. The main issue was the development of a research code for numerical simulation of fluid flow in real combustion chambers. Here the development of computational models of physical and chemical processes was emphasized, among other processes the formation of soot was treated. Moreover, a worldwide outstanding database of measured data for the purpose of code validation has been created within the framework of the BKM project using the laboratory facilities of the DLR, which are in Germany unique for the experimental investigation of the various processes in ...
To mitigate damages caused by agricultural runoff, private lake owners' associations are paying for inlake and instream pollution abatement measures and on land-conservation practices. This phenomenon supports the notion that individuals who benefit from improved water quality should be willing to pay part of the abatement costs. The research suggests that on land-conservation measures can substantially reduce sediment delivery at low cost. The Sediment Economics (SEDEC) model was modified and then used to select and to site management systems that achieved stated sediment goals at least cost. Other resource policies such as T value, no-till, and contouring were compared with the least-cost frontier and shown to be more costly. The noncropland areas substantially reduced sediment delivery to water channels and lowered abatement costs. Further research is needed for long-range watershed-planning models such as ...
Experimental wetlands are being constructed on mined lands in the United States as an inexpensive alternative to conventional acid mine water treatment facilities. The US Bureau of Mines is conducting an inventory of these constructed wetlands as part of a long-term evaluative study. Preliminary results, based on the 20 sites surveyed to date, indicate that the wetlands dominated by emergent species are out-performing the Sphagnum-dominated wetlands, and that much of the water treatment is accomplished by other aspects of the wetland, including bacteria, algae, amendments and other plants. Iron concentrations as high as 85 mg/l are reduced to less than 3 mg/l after flow through the constructed wetlands. Manganese is also removed, though somewhat less efficiently. 12 refs., 1 fig., 1 tab.
In order to obtain the electronic structure of leucine (Leu) in aqueous solution, we studied three systems: Leu+7H2O, Leu+8H2O and Leu+9H2O. The results indicated that the system Leu+8H2O was the only choice which was both acceptable and doable: its computational effort was affordable, and it could simulate a main part of the solvent effect on the electronic structure of Leu in solution. Based on the system Leu+8H2O, all-electron, ab initio calculations were performed to construct an equivalent potential of water for the electronic structure of Leu with dipoles. The results showed that the main effect of water on the electronic structure of Leu was raising the occupied states about 0.0824 Ry on average, and broadening the energy gap by 11%. The water effect on the electronic structure of L...
Horizontal steam generators are typical parts of nuclear power plants with pressure water reactor type VVER. By means of this computer program, a detailed thermal-hydraulic study of the horizontal steam generator PGV-1000 has been carried out and a special attention has been paid to the thermal-hydraulics of the secondary side. A set of important steam generator characteristics has been obtained and analyzed. Some of the interesting results of the analysis are presented in the paper. (author)
The application of airborne sensors for providing environmental assessment and monitoring of a test site in an open cast mining area that is part of a lignite deposit in central Germany is described. Hyperspectral remote sensing data from three different sensors were tested. The hyperspectral scanner data was suitable for classification of different sediments and vegetation types and the water chemistry of residual mining lakes. Summary form only. 1 tab.
Platinum(II) complexes have been investigated in the hydration of alkynes. These catalysts offer improved regioselectivity over Hg(II) counterparts. 1 fig., 2 tabs.
In this study, we propose a new bioactive bone cement (BBC), composed of natural bone powder (hydroxyapatite; HA), chitosan powder, and the currently available polymethylmethacrylate (PMMA) bone cement, for use in orthopedic surgeries such as vertebroplasty or as bone filler. Three types of BBCs (BBC I, BBC II, and BBC III) were prepared with different composition ratios. In vitro tests and animal studies were performed with the new BBCs, and with a currently available commercial PMMA bone cement. Surface morphology, chemical composition, changes in pH over time, exothermic temperatures, intrusion, and cellular responses were investigated in vitro. Scanning electron microscopy (SEM) and radiological and histological examinations were performed in animal studies. The results showed that the major components of the BBCs were C, O, Ca, P, Cl, Si, S, Ba, and Mg. The pH values of the BBCs decreased after 1 day, but eventually recovered to 7.2-7.4. The ...
For Stage II of the European Dioxin Project the following objectives were set: - Amendment of existing emission data collected for most relevant emission sources in order to reduce uncertainties of emission estimates. Collecting first emission data from countries not yet performing dioxin emission measurement programs. Extending the inventory of dioxin emissions to ambient air produced in Stage I by a complementary study on emissions to land and water. Extending the regional scope of data collection to countries in Central Europe. The report of Stage II of the European Dioxin Project is presented in 3 Volumes. Volume 1 contains an overview on the background and approach of different activities carried out and on the results obtained. These results are put into a broader view regarding the dioxin reduction measures in Europe leading to conclusions and recommendation for future work. Volume 2 of the report contains a detailed ...
During the years 1995-1999, an international effort was going on under the title DECOVALEX II, in order to study the coupled thermo-hydro-mechanical (THM) effects in the water containing fractured rock mass caused by the heat generation of spent fuel canisters in a repository. The project was a continuation project of DECOVALEX (1991-1996). The name comes from the acronym 'an international co-operative project for the DEvelopment of COupled models and their VALidation against EXperiments in nuclear waste isolation'. Radiation and Nuclear Safety Authority (STUK) was one of the eleven Funding Organizations in the international project. STUK's Research Team was the Technical Research Centre of Finland, VTT Communities and Infrastructure. To support and coordinate the national research work, STUK formed a National DECOVALEX II Group (NDG). The group had representatives from six research organisations ...
Aqueous solutions of Al/sub 2/(SO/sub 4/)/sub 3/ (1.05 g/100 ml), AlCl/sub 3/ (0.82 g/100 ml) and Ca(OH)/sub 2/ slurry (0.94 g/50 ml) were mixed in various volume ratios and passed through a filter. White cakes left on the filter consisted mainly of ettringite (6CaO.Al/sub 2/O/sub 3/.3SO/sub 3/.32H/sub 2/O). The cakes were then calcined at various temperatures of 300/sup 0/ -- 1000/sup 0/C for 30 and 60 min and pulverized to 80 -- 200 mesh powders. The adsorption capacity of the powders for U(VI) ions dissolved in aqueous solutions was determined by immersing 0.100 g of their powders in 50 ml of the aqueous solution containing 100 ppm of U(VI) ions mainly in the form of (UO/sub 2/(CO/sub 3/)/sub 3/)/sup 4 -/ for 2 hours. The results obtained were summarized as follows. 1) Among the powders prepared, those of the oxide compositions, 2.9CaO.Al/sub 2/O/sub 3/.1.4SO/sub 3/ and 2.5CaO.Al/sub 2/O/sub 3/.1.2SO/sub 3/, all fired at 500/sup 0/C or 600/sup 0/C showed high adsorption capacity for ...
The aim of this study is to prepare some polymeric moulds using Natural rubber latex (NRL)- portland cement composites based on a delayed-action mechanism. Factors affecting the preparation process such as concentration, mixing percentage, additives and their effects on what is regarded as a delayed-action coacervant combination was studied. The effect of Gamma-radiation on the mechanical properties of these moulds was investigated. The effect of natural aging on the prepared moulds was investigated to determine the possibility of using the prepared product in the construction field as expansion joints and cracks filling materials ...etc. The results may be summarized as follows: 1) Composites of natural rubber latex (NRL)-portland cement mould were prepared as two separate parts. The stabilized natural rubber latex (NRL) with hydroxy ethyl cellulose (HEC) as stabilizer and a delayed-action coacervant (sodium meta silicate) present in the rubber mixture was ...
The Forsmark area consists of a number of natural wetlands. As a part of the evaluation of wetlands in the safety assessment for the area, possible future wetlands are being studied with respect to hydrology and transport mechanisms. A sensitivity analyses is performed to point out the governing parameters for the wetland hydraulics. The analysis of future wetlands is carried out using the hydrological model system Mike SHE. Mike SHE has been used to describe the near-surface hydrology for a regional model area in Forsmark. Three types of areas have been chosen. Today's lake Bolundfjaerden is because of its shallow depth likely to develop into a mire in the future. As it is situated in the downstream part of the regional model area, the runoff to the lake from upstream surface water system is significant. Lake Eckarfjaerden is situated in the upstream part of the catchment at a higher altitude ...
A patent is claimed for a direct coal liquefication process which is carried out by interaction with a paste, consisting of small-fragment coal, oil and catalysts, with H/sub 2/ at increased temperatures and pressures. The catalyst is a mixture of 1 part per weight of Fe-ore that's been activated by aqueous treatment, and 0.1-1.0 powder-form S. The Fe-ore can be magnetite, limonite, hematite, pyrite, ferrous sand or ''red mud'' (byproduct of the Bayer process), with the ''red mud'' and limonite, having a particle size of about 100 mesh is preferable. Activation of Fe-ore includes aqueous treatment in boiling water for 30-120 min with subsequent drying; annealing at a temp. of 300-700/sup 0/C for 10-120 min; submerging into cold water and final drying. The catalyst is added to the paste in the amount of 0.03-0.3 parts per ...
The deportation of trophoblast debris from the placenta was first documented over 100 years ago, and today we know that the deported material ranges from multinucleated syncytial knots/sprouts to trophoblast-derived nanoparticles. However little is known about the effect of trophoblast debris on maternal physiology since it is difficult to investigate these effects in vivo in women. Animal models have been reported but they have provided relatively little information. Most of our current knowledge regarding the effects of trophoblast debris on maternal systems is provided by studies using trophoblast debris obtained from in vitro models of the human placenta. Herein we review the animal models and the in vitro studies, which, between them, suggest that deported trophoblast material may pla...
The contribution of ear photosynthesis to grain filling in wheat (Triticum aestivum L.) is not well known. The main objective of this work was to evaluate this contribution through three different experimental approaches: (1) ear photosynthesis was reduced by removing awns or shading the ears (in combination with a defoliation treatment), (2) grain weight per ear was compared in an 'all shaded' crop versus plants where only the vegetative parts were shaded ('ear emerging'), and (3) ear photosynthesis was reduced with DCMU (3-(3,4-dichlorophenyl)-1,1-dimethylurea), a specific inhibitor of photosystem II. In field experiments in La Plata (Argentina), cultivars Klein Escudo and BioINTA 3000 were subjected to awn removal and ear shading treatments, with or without severe defoliation, and to 'a...
For the safety of astronauts and to ensure the stability and integrity of the genome of microorganisms and plants used in bioregenerative life support systems, it is important to improve our knowledge of the combined action of (space) radiation and microgravity. The SOS-LUX-TOXICITY test, as part of the TRIPLE-LUX project (accepted for flight at Biolab in Columbus on the International Space Station, (ISS)), will provide an estimation of the health risk resulting from exposure of astronauts to the radiation environment of space in microgravity. The project will: (i) increase our knowledge of biological/health threatening action of space radiation and enzymatic DNA repair; (ii) uncover cellular mechanisms of synergistic interaction of microgravity and space radiation; (iii) provide specified...
Severe accident analysis has been performed for the Wolsung nuclear power= plants in Korea to investigate severe accident phenomena of CANDU-600 reactors as a part of Level II PSA study. The accident sequence analyzed in this paper is loss of active heat sinks (LOAH) which is caused by loss of off-site power, diesel generators, and DC power. ISAAC (Integrated Severe Accident Analysis Code) computer code developed by KAERI (Korea Atomic Energy Research Institute) was used in this analysis. This paper describes the important thermal-hydraulics and source term behaviors in the primary system and inside containment, and the failure mechanisms of calandria vessel and containment. In addition, some insights for accident management program (AMP) are also given. (Author) 5 refs., 1 tab., 12 figs.
Severe accident analysis has been performed for the Wolsung nuclear power plants in Korea to investigate severe accident phenomena of CANDU-600 reactors as a part of Level II PSA study. The accident sequence analyzed in this paper is loss of active heat sinks (LOAH) which is caused by loss of off-site power, diesel generators, and DC power, ISAAC(Integrated Severe Accident Analysis Code) computer code developed by KAERI (Korea Atomic Energy Research Institute) was used in this analysis. This paper describes the important thermal-hydraulics and source term behaviors in the primary system and inside containment, and the failure mechanisms of calandria vessel and containment. In addition, some insights for accident management program (AMP) are also given.
The point at which the common final pathway for induction of cancer by chemical carcinogens and ionizing radiation has not been identified. Although common molecular targets are suggested by recent findings about the role of oncogenes, the mechanism by which the deposition of radiation energy and the formation of adducts or other DNA lesions induced by chemicals affects the changes in the relevant targets may be quite different. The damage to DNA that plays no part in the transformation events, but that influences the stability of the genome, and therefore, the probability of subsequent changes that influence tumorigenesis may be more readily induced by some agents than others. Similarly, the degree of cytotoxic effects that disrupt tissue integrity and increase the probability of expression of initiated cells may be dependent on the type of carcinogen. Also, evidence was presented that repair of the initial lesions could be demonstrated after exposure to low-LET ...
The total hemispherical emittance of an oxide film that formed on 6061-T6 aluminium alloy parts in the Tower Shielding Reactor-II at Oak Ridge National Laboratory was measured from 295 to 773 K using an emissometer and/or a calorimeter. The emittance of this film was critically needed for heat transfer calculations in a simulated loss-of-coolant accident of the reactor. X-ray diffraction analysis identified the film as boehmite (Al_2O_3 x H_2O), which dehydrated to alumina (Al_2O_3) upon heating above 473 K. The measured emittances for the alumina film are in excellent agreement with published values for anodized aluminum films and for bulk alumina. Published values of the emittance of boehmite could not be found for comparison, but evidence is presented that some anodization processes for aluminum yield boehmite and not alumina films.
We investigated the magnet field dependence of the X-ray pulse height and the critical current of a Ti/Au bilayer TES micro-calorimeter. The pulse height was strongly affected by the magnetic field intensity applied perpendicularly to the TES surface. We found that the critical current at zero temperature, I c0, decreased by a factor of two by applying a magnet field of ?10??T. Our data are consistent with a TES sensitivity proportional to (I/I c0)?2/3, as predicted by the Ginzburg-Landau theory. This fact implies that the shape of the R?T curve of the TES is partly determined by the critical current of the superconductor. In order to make our TES microcalorimeters less sensitive to the external magnetic field, we fabricated devices equipped with on-chip magnetic shielding. One device has ...
This report is part of a four-volume study of Darrieus vertical axis wind turbine (VAWT) economics. This volume describes a computer model of VAWT cost and performance factors useful for system design and optimization. The content and limitations of the model are outlined. Output data are presented to demonstrate selection of optima and to indicate sensitivity of energy cost to design parameter variations. Optimized specifications generated by this model for six point designs are summarized. These designs subsequently receive a detailed economic analysis discussed in Volume IV. An appendix is included with a FORTRAN IV listing of the model and a description of the input/output characteristics.
This three-part article describes the early years of one of the mother-baby-children groups of the Project for Mothers, Infants, and Young Children of September 11, 2001. The goal of the group was to help prevent the effects of trauma and loss from disrupting the relationships among the mothers, their infants, and growing children. View I by Anni Bergman describes the mothers' states of minds as the group began, when they felt that their worlds had collapsed under them. View II by Sally Moskowitz focuses on the clinical experience of working in the group, transference and countertransference themes, helping the mothers and children with their mourning process, and helping the mothers' relationships to each other, their babies, older children, family, and friends. The evolution of a casual,...
The concept of sustainable consumption (SC) has been proposed as a way of operationalising sustainable development (SD). However, until now, in view of the difficulties in conceptualising SC, emphasis has been placed mainly on a pragmatic approach. In an a-conceptual and pragmatic account of SC, many problems remain unaddressed, such as the danger of the notion becoming empty and lack of integration between the different dimensions of sustainability. In this paper, we propose that the informational space provided by the capability approach (CA) offers a conceptual framework to elaborate SC. The CA is employed here (i) to discuss the philosophical underpinnings of SC as part of a strategy for enhancing quality-of-life and (ii) to investigate the links between the different dimensions of SC....
The progression of hip dysplasia was investigated in 116 military working dogs. Medical records were reviewed for any clinical history of hind-limb lameness. Pelvic radiographs were studied for evidence and degree of hip dysplasia, degenerative joint disease, or both. The number of months each dog worked was determined. Each dog's age at termination from service and cause of death (or euthanasia) were recorded. The mean months of work for normal and dysplastic dogs were evaluated using the Student's t-test. No significant difference was found in the total number of months worked between normal and dysplastic dogs (p greater than 0.05). PMID:8875358
A theory has been developed for the mechano-catalytic water-splitting, which is the system of simultaneous H{sub 2} and O{sub 2} evolution by stirring the powder of an oxide semiconductor in pure water under the condition that the stirring rod must be kept in contact with the surface of the glass vessel. The kinetic equations and the coupling strength of the frictional energy conversion between mechanical and electrical systems are calculated . The total system composed of the formation of the dangling bonds on the glass surface, the trapping of the semiconductor particles at the microcrevice of the glass surface, the strong field inside the fine particles due to the frictional electricity, the mechanism of charge transfer from the semiconductor to the stirring rod, the hopping conduction of positive hole, the electric current density injected into water from the semiconductors, and the tunnel chemical reaction for ...
The VE (ventilation) test carried out at the Mont Terri underground laboratory in Switzerland intended to evaluate in situ the behaviour of a consolidated clay formation when subjected to alternate periods of flow of wet and dry air during several months. For that, a 10-m gallery was excavated in the Opalinus Clay formation and carefully instrumented. Before and after a second ventilation phase boreholes were drilled. Samples were taken from the drill cores and were analysed from mineralogical and geochemical points of view. Also, the retention curves of these samples were determined in the laboratory following drying paths performed under free volume conditions at 20 degree centigrade, what is the content of this report. Although there are not large differences in the WRC of samples taken from different boreholes, at different distances from the gallery wall or before or after ventilation, those samples taken near the gallery wall and after ventilation tend to show a higher ...
A new method for the preconcentration and determination of trace amounts of lead at the {mu}g/L level in natural waters has been established based on the formation of the thenoyltrifluoroacetone (TTA) complex with dibenzo-18-crown-6 (DB18C6) by means of synergistic extraction and back-extraction combined with atomic absorption spectrometry (AAS). The effect of various factors (synergism with TTA and DB18C6, shaking time, preconcentration factor, composition of the extracted species, and foreign ions etc.) on the extraction and back-extraction of lead has been investigated in detail. The lead-TTA chelate in o-dichlorobenzene forms a stable adduct with DB18C6 as Pb(TTA){sub 2} DB18C6. The stability constant ({beta}) of the adduct determined by curve fitting method was log {beta} = 4.2. The amount of lead in natural waters such as tap water (Kanazawa University) and Kakehashi river (Komatsu City) determined by the present ...
The NUclear Power Engineering Corporation (NUPEC) has developed IMPACT-SAMPSON code to analyze integral behavior of light water nuclear power plants under severe accident conditions. IMPACT-SAMPSON's distinguishing features include interconnected hierarchical modules and mechanistic models covering a wide spectrum of scenarios ranging from normal operation to severe accident events, and high-speed simulation on parallel processing computers. The integral plant behaviors of typical PWR and BWR under severe accident conditions have been analyzed with the IMPACT-SAMPSON code. The PWR plant analyzed was the three-loop, steel-dry containment type with 2,440 MWt. The AE accident scenario was supposed, that is, LOCA by 6-inch hot leg failure followed by accumulated water injection, but no ECCS and containment spray activation. The BWR plant analyzed was the 3,293 MWt BWR-5, Mark-II containment type. The TQUV accident ...
Efficient and precise ablation of soft tissue is needed for non-invasive dermatological and corneal surgeries. Previous research has revealed that smooth and efficient cutting of certain soft tissues and gelatin is possible using a Free Electron Laser (FEL) with a wavelength of #lambda#=6.45 #mu#m, tuned to the amide-II band of protein. Gelatin ablation experiments have been carried out using a mid-infrared FEL within the waveband #lambda#=5.6-6.7 #mu#m by changing the primary absorbers such as water (#lambda#=6.1 #mu#m) and protein (#lambda#=6.45 #mu#m). The gelatin with 80 wt% water was efficiently ablated by FEL irradiation with the waveband #lambda#=#approx#5.95-6.19 #mu#m. On the other hand, using irradiation within #lambda#=#approx#6.4-6.6 #mu#m, many small bubbles were observed in the irradiated volume, and the gelatin was not ablated but significantly melted. Thus, it was found that the most effective wavelength was ...
The stability of a solid ice cover subjected to rapidly varying water levels and discharge was investigated. The support from the bank limits the stress in the ice cover and consequently bank contact must be maintained to ensure ice cover stability. An analysis was required of the stability of ice hinges, a flexible connection between a solid ice cover and the riverbank. Phase II and phase III of the research involved a field study of the Peace River, investigating the evolution of ice hinges with water level variation, from initial ice cover cracking parallel to the banks, to a fully developed hinge. A test program of midwinter discharge variations was undertaken to gather specific data and measurements of ice hinge link length, ice thickness, hinge joint behavior, riverbank geometry, and response of ice hinging to water level variation. As a result of the program, concepts developed throughout the ...
Copper(II) complex coordinated with cyclam-type macrocyclic tetramine, C-meso-1,5,8,12-tetramethyl-1,4,8,11-tetraazacyclotetradecane (2Cdmc) has been synthesized and characterized by single crystal X-ray crystallographic analysis and UV?Vis absorption spectra. Solved molecular structure of [Cu(2Cdmc)(H2O)]Cl2?2H2O (1) revealed that macrocyclic ligand 2Cdmc was in the most stable trans-III structure, but the C-methyl groups of 2Cdmc adopted energetically unfavorable axial configuration (C-axial). This complex 1 is the second example of complex of cyclam-type tetramine with only axially oriented C-methyl groups. This complex adopted five-coordinated square-pyramidal geometry with one water molecule occupying one of the two apical sites. Network of hydrogen bonds involving counter anions (Cl?...
The report was prepared for the IPCC by Working Group II. The remit of Working Group II was to describe the environmental and socioeconomic implications of possible climate changes over the next decades caused by increasing concentrations of greenhouse gases. The scenarios used include the following features: an effective doubling of atmospheric CO{sub 2} between now and 2025-2050; a consequent increase of global mean temperature of 1.5-4.5{degree}C; an unequal global distribution of the temperature increase; a sea level rise of 0.3 to 0.5m by 2050. The impacts of possible climate change were assessed for the following: agriculture and forestry; natural terrestrial ecosystems; hydrology and water resources; human settlements including the energy, transport and industrial sectors; human health; air quality and changes in UV-B radiation; oceans and coastal zones; seasonal snow cover; ice and permafrost. Further action is ...
In a closed circuit formed by bypassing pipelines connected to carbon steel parts, low oxygen coolants pass there through during operation. A solution containing ions of metals more noble than iron are circulated to bring the solution into contact with the carbon steel surface of the inner wall of the parts to form a deposition membrane of the metal more noble than iron on the surface to prevent acceleration of corrosion of the carbon steel parts due to low oxygen coolants. The solution containing ions of metals more noble than iron is a solution of palladium nitrate containing ions of platinum elements. This operation is conducted under a temperature condition of from 50degC to 150degC. In addition, the metal ion concentration of the solution circulating in the closed circuit is measured, it is compared with metal ion concentration previously determined, and the results are feed back to a means for controlling ...
This is the eighth report by the Advisory Committee on Reactor Safeguards (ACRS) that has been prepared in response to the Congressional requirement for an annual report on the Nuclear Regulatory Commission (NRC) Reactor Safety Research Program. As previously requested by the Congress, the timing of this report has been adjusted to enable the ACRS to address the proposed budget for FY 1986 and 1987 that has been submitted to the Congress by the President. Detailed comments and recommendations are provided for the research programs and budget proposed for FY 1986. Because both the budget for FY 1987 and the research programs for that period are highly uncertain at this time, comments on these are not provided. Part I is a compilation of general comments and recommendations regarding the NRC Safety Research Program budget for FY 1986. It is intended to serve as the Executive Summary. PartII is divided into five chapters, ...
In many parts of the United States, as well as other regions of the world, competing demands for fresh water or water suitable for desalination are outstripping sustainable supplies. In these areas, new water supplies are necessary to sustain economic development and agricultural uses, as well as support expanding populations, particularly in the Southwestern United States. Increasing the supply of water will more than likely come through desalinization of water reservoirs that are not suitable for present use. Surface-deployed seismic and electromagnetic (EM) methods have the potential for addressing these critical issues within large volumes of an aquifer at a lower cost than drilling and sampling. However, for detailed analysis of the water quality, some sampling utilizing boreholes would be required with geophysical methods being ...
The Army Reactor Area (ARA) II was constructed in the late 1950s as a test site for the Stationary Low Power Reactor No. 1 (SL-1). The SL-1 was a prototype power and heat source developed for use at remote military bases using a direct cycle, boiling water, natural circulation reactor designed to operate at a thermal power of 3,000 kW. The ARA II compound encompassed 3 acres and was comprised of (a) the SL-1 Reactor Building, (b) eight support facilities, (c) 50,000-gallon raw water storage tank, (d) electrical substation, (e) aboveground 1,400-gallon heating oil tank, (f) underground 1,000-gallon hazardous waste storage tank, and (g) belowground power, sewer, and water systems. The reactor building was a cylindrical, aboveground facility, 39 ft in diameter and 48 ft high. The lower portion of the building contained the reactor pressure vessel surrounded by gravel shielding. Above ...
Wolsong 2,3 and 4 fuel channel analysis during a large break loss of coolant accident with loss of ECCS injection (LOCA/LOECC) is performed to obtain the heat load to moderator. Because the single channel analysis requires the establishment of the safety codes and their input decks, the present study follows the same safety analysis methodology found in FSAR of Wolsong 2,3 and 4. From this work we obtain the safety tools such as CATHENA MOD3.5b/Rev.1 and CHAN-II/A MOD2 codes, and their code modeling in a form of code input deck. The analysis consists of two parts: front-end (blowdown period) and back-end. For the front-end analysis the fuel and pressure tube (PT) temperatures, and PT circumferential strains at the end of front-end as well as fuel channel depressurization are calculated using CATHENA code and used as initial and boundary conditions for back-end analysis. The back-end period under the conditions of prolonged low steam flow is ...
The following paragraphs summarize the progress of each research project funded under the WVU Cooperative Agreement during the third quarter of 1997 (July - September 1997). The projects are arranged according to their 1997 WVU task number. WVU Focus Area 1.0: Subsurface Contaminants, Containment and Remediation Task No. 1.1: Project discontinued. Task No. 1.2: Development of Standard Test Protocols and Barrier Design Models for Desiccation Barriers (K. Amininan & S. Ameri): A number of experiments were preformed this period to evaluate the ability of the dried sand-packs to act as a barrier to liquids. Water infiltration tests were done with a constant head, dispersing 80 ml of water, and by adding water in small increments. Results indicate that when the water is spilled over the sand-pack, it has the tendency to channel through the sand-pack, significantly reducing the capacity of the dried zone ...
Vehicle heating requires a substantial amount of energy. Engines in conventional cars produce enough waste heat to provide comfort heating and defogging/defrosting, even under very extreme conditions. Electric vehicles (EVs), however, generate little waste heat. Using battery energy for heating may consume a substantial fraction of the energy storage capacity, reducing the vehicle range, which is one of the most important parameters in determining EV acceptability. Water vapor generated by the vehicle passengers is in large part responsible for the high heating loads existing in vehicles. In cold climates, the generation of water vapor inside the car may result in water condensation on the windows, diminishing visibility. Two strategies are commonly used to avoid condensation on windows: windows are kept warm, and a large amount of ambient air is introduced in the vehicle. Either strategy results in a ...
There is now a scientific consensus that current rates of accumulation of greenhouses gases in the atmosphere will result in significant global warming and climate change. These changes are likely to have important impacts on a wide range of human activities and the natural environment. There has now been a considerable weight of literature published on the impacts of global warming, much of it very recent. This report seeks to summarise the important results, to analyse the uncertainties and to make a preliminary analysis of the feasibility of monetarising these environmental costs. The impacts of global warming are divided into ten major categories: agriculture, forests and forestry, terrestrial ecosystems and biodiversity, hydrology and water resources, sea level rise and coastal zones, energy, infrastructure/transport/industry, human health and air quality, oceans, and cryospheric impacts. The results of major summary reports are analysed, notably the report of ...
Abstract The available surface equation of state for pure pulmonary surfactant monolayers is generalised to binary mixture monolayers by introducing a group of parameters, i(i-=-1-4) in the form of $x_{r}^{\\beta _{i} } $ to express the influence of the components in new mixing rules and a new factor, I $\\left[ { = \\left( {\\prod\\limits_{i = 1}^{4} {\\beta _{i} } } \\right)^{{\\raise0.5ex\\hbox{$\\scriptstyle 1$}\\kern-0.1em/\\kern-0.15em\\lower0.25ex\\hbox{$\\scriptstyle {4}$}}} } \\right]$, is defined to represent the interaction intensity between two different components. The ---A isotherms getting by the surface equations of state agree with the experimental data for protein-lipid binary monolayers, and the average deviation is about 11.41%. The result shows the order of the interaction intensity b...
Since 1976, the Nuclear Engineering Laboratory of the Technical Research Centre of Finland and Lappeenranta University of Technology have cooperated in the field of nuclear reactor thermal-hydraulics. During these years, a series of experimental facilities (REWET-I, -II, -III, VEERA) simulating pressurized water reactors (PWRs) have been built. The newest facility, PACTEL (Parallel Channel Test Loop), is an experimental out-of-pile facility designed to simulate the major components and system behaviour of a commercial PWR during postulated small and medium size break loss-of-coolant accidents (LOCAs), natural circulation and operational transients. A PACTEL natural circulation experiment has been carried out as an OECD/NEA international standard problem ISP 33. (2 refs., 3 figs., 2 tabs.).
A protective film has been developed on the surface of carbon steel in low chloride aqueous environment using a synergistic mixture of an environmentally friendly phosphonic acid, N,N-bis(phosphonomethyl) glycine (BPMG), and zinc ions. Impedance studies of the metal/solution interface indicated that the surface film is highly protective against the corrosion of carbon steel in the chosen environment. Potentiodynamic polarization studies showed that the inhibitor is a mixed inhibitor. X-ray photoelectron spectroscopic analysis (XPS) of the film showed the presence of the elements iron, phosphorus, nitrogen, oxygen, carbon, and zinc. Deconvolution spectra of these elements in the surface film showed the presence of oxides/hydroxides of iron(III), Zn(OH)2, and [Zn(II)-BPMG] complex. This infe...
This is our response to a comment by Walter Eifler on our paper `A simple model for the short-time evolution of near-surface current and temperature profiles' (arXiv:physics/0503186, accepted for publication in Deep-Sea Research II). Although Eifler raises genuine issues regarding our model's validity and applicability, we are nevertheless of the opinion that it is of value for the short-term evolution of the upper-ocean profiles of current and temperature. The fact that the effective eddy viscosity tends to infinity for infinite time under a steady wind stress may not be surprising. It can be interpreted as a vertical shift of the eddy viscosity profile and an increase in the size of the dominant turbulent eddies under the assumed conditions of small stratification and infinite water depth.
The rate was studied of radiation destruction of phenol aqueous solutions at a concentration range of 1 to 100 ppm. Irradiated were model solutions containing additions of some organic and inorganic substances typical of the petrochemical industry. In view of the fact that the radiation destruction kinetics is determined by the amount of dissolved oxygen in the sample and by the phenol concentration, relatively low doses were used. Thus, a sufficient amount of oxygen in the sample and therefore the oxidation mechanism of radiolysis were ensured. The dose-response relationships for phenol destruction were studied using doses of 50, 100, 200 and 400 J.kg"-"1; the limit dose was 500 J.kg"-"1. From the results obtained, a kinetic model was constructed of radiation phenol oxidation in aqueous solutions in the presence of various organic and inorganic additions. (B.S.).
Objective.The objective of this study was to use the newly synthesized poly(quaternary ammonium salt) (PQAS)-containing polyacid to formulate the light-curable glass-ionomer cements and study the effect of the PQAS on the compressive strength and antibacterial activity of the formed cements.Materials and methods.The functional QAS and their constructed PQAS were synthesized, characterized and formulated into the experimental high-strength cements. Compressive strength (CS) and Streptococcus mutans viability were used to evaluate the mechanical strength and antibacterial activity of the cements. Fuji II LC cement was used as control. The specimens were conditioned in distilled water at 37 degrees C for 24 h prior to testing. The effects of the substitute chain length, loading as well as gra...
Mowing a meadow is an example of an equalizing process that reduces differences among species by removing aboveground biomass approximately 5?cm above ground. This regular disturbance that affects all plants prevents competitive exclusion of small species and thus allows coexistence of numerous species differing in shoot size. In this paper we search for the mechanism behind this by comparing the shoot biomass of 41 common species in dry and wet species-rich meadows in mown and recently abandoned plots in June (before mowing) and in October. We asked the following questions: i) Do the plants differ in proportion of biomass lost by mowing? ii) Are the mown plants able to compensate for biomass lost by mowing? iii) Is the compensatory ability of mown plants related to their size? iv) Is the ...
A electrogenerated chemiluminescence (ECL) sensor for itopride was developed based on tris(2,2-bipyridyl)ruthenium(II) (Ru(bpy)32+)-doped silica (RuDS) nanoparticles/biopolymer chitosan composites membrane modified glassy carbon electrode (GCE). The RuDS nanoparticles (52+-5nm) were prepared by a modified Stber synthesis method and were characterized by electrochemical, fluorometric and transmission electron microscopy technology. The Ru(bpy)32+ encapsulation interior of the silica nanoparticle maintains its electrochemical activities and also reduces Ru(bpy)32+ leaching from the silica matrix when immersed in water due to the electrostatic interaction. The ECL analytical performances of this ECL sensor for itopride based on its enhancement ECL emission of Ru(bpy)32+ were investigated in d...
We report a solution-phase synthetic route to copper nanoparticles with controllable size and shape. The synthesis of the nanoparticles is achieved by the reduction of copper(II) salt in aqueous solution with hydrazine under air atmosphere in the presence of poly(acrylic acid) (PAA) as capping agent. The results suggest that the pH plays a key role for the formation of pure copper nanoparticles, whereas the concentration of PAA is important for controlling the size and geometric shape of the nanoparticles. The average size of the copper nanoparticles can be varied from 30 to 80 nm, depending on the concentration of PAA. With a moderate amount of PAA, faceted crystalline copper nanoparticles are obtained. The as-synthesized copper nanoparticles appear red in color and are stable for weeks, ...
Since mid-March the Commission on Water Management, with the assistance of the appropriate ministries, visited all regions of the province in order to acquaint themselves first hand with regional water management problems. During the month of June, the Commission also organized a series of ten workshops, attended by a limited number of experts, to explore in depth certain specific questions in the area of water management. During these public sessions the Commission hoped to discuss specifically the specific questions relating to water management problems of First Nations communities, bearing in mind the essential nature of water in maintaining traditional activities. The workshop took place on the Montanard reserve of Mashteuiatsh (Pointe-Bleu). The morning session was devoted to presentations by invited experts, followed by an exchange of views between the experts and the ...
This paper provides information on activities undertaken in a non- production oriented metal finishing operation to minimize waste and conserve resources. The facility is a 6000 sq foot shop that typically only deals with prototype parts. Utilizing a plan that includes employee awareness, common sense and existing technology, a noticeable reduction in waste volume has been obtained. Initiatives that are covered include: segregation of cyanide plating solutions, elimination of copper cyanide plating, elimination of hexavalent chromium plating, elimination of vapor degreasing, changing of rinsing practices, and changing a process for cleaning of aluminum parts. Some discussion is also presented on the effectiveness of combining the technologies of physical vapor deposition and electrodeposition to help minimize waste. Plans for additional initiatives including water recycling, elimination of cyanide plating and substitution ...
The carbonate rocks of the Lower Ordovician Majiagou Formation represent important hydrocarbon reservoirs in the Ordos basin in the western part of the North China plate. Cores and thin sections from more than 60 wells were examined. The main reservoir in the Majiagou Formation consists of fine crystalline dolomite, which was altered by meteoric water during an extended subaerial exposure. Three phreatic zones have been identified in the Majiagou Formation in the northern part of the basin. Oxygen isotopes and fluid inclusion microthermometry data indicates that the porosity developed during the early karst event was considerably reduced by the late-stage, coarse crystalline calcite cements that appear to be related to hydrothermal fluids during deep burial. It was concluded that the main factors that determine the porosity and permeability of these carbonate reservoirs are dolomitization, karstification, and calcite ...
Chemical characterization of passive films formed on AISI 304 austenitic stainless steel, in a borate/boric acid solution at pH 9.2, under various conditions of potential, temperature, and polarizations time, was made by Auger electron spectroscopy combined with ion sputtering, and x-ray photoelectron spectroscopy (XPS). The depth chemical composition, thickness, and duplex character of the passive layers were determined after processing AES sputter profiles by their quantitative approach based on the sequential layer sputtering model. Moreover, separated contributions of elements in their oxidized and unoxidized state could be disclosed from part to part of the oxide-alloy interface. The XPS study specified the chemical bondings which take placed inside the film, between Fe and oxygen (and water).
A numerical investigation of a humidification dehumidification desalination (HDD) process using solar energy is presented. The HDD system consists mainly of a concentrating solar water heating collector, flat plate solar air heating collector, humidifying tower and dehumidifying exchanger. Two separate circulating loops constitute the HDD system, the first for heating the feed water and the second for heating air. A mathematical model is developed, simulating the HDD system, to study the influence of the different system configurations, weather and operating conditions on the system productivity. The model validity is examined by comparing the theoretical and experimental results of the same authors. It is found that the results of the developed mathematical model are in good agreement with the experimental results and other published works. The results show also that the productivity of the unit is strongly influenced by the air flow rate, ...
This report presents the record of the workshop Water Treeing and Aging.'' The workshop was held in Phoenix, Arizona on December 9--11, 1990 and was sponsored by the Distribution Program of the Electrical Systems Division of the Electric Power Research Institute (EPRI). Attendance at the workshop was by invitation only. Twenty two attendees from seven countries, from universities, research organizations, electric utilities and polymeric materials suppliers took part in this workshop. The workshop was designed to assess progress in the understanding of water treeing phenomena and polymeric cable insulation aging since the last meeting of a similar forum of experts, which was organized by the Office of Exploratory Research of EPRI in December 1985. The objective of the present workshop was to assess progress and to provide direction for further studies in this field. The discussions covered a wide range of ...
The hydromechanical effect of hydroelectric stations on zooplankton is customarily regarded as a constantly acting and comparatively harmless factor, since its destruction is inevitable when water masses are passed through hydroelectric stations, but its capacity for restoration is high (i.e., destruction of the zooplankton of the forebay is compensated by its production in the after bay). It is not known how correct such an opinion is, or what is the true balance of losses and reproduction of zooplankton in the forebays and after bays of hydroelectric stations. However, hydroelectric plants of a new type, pumped-storage plants, have been constructed in recent years and others are planned for the Dnieper reservoirs. The operational principle and purpose of these plants is that they employ special vertical turbine-electric pumps that pump water at night from the reservoirs into pumped-storage facilities at high levels, and then release this ...
Measurements of PEM fuel cell device performance were made with different gas inlet temperatures and relative humidity using a newly-designed test fixture. Significant improvement in device performance was observed when the fuel inlet temperature was increased above the operating temperature of the cell. These measurements were then correlated to a model to describe energy and mass transport processes. Proton exchange membrane (PEM), fuel cells--the focus of this study--use an ion conducting polymer, especially polyperfluorosulfonic acid materials. These polymer materials, when imbibed with water, exhibit solution-like properties, but because the anions are chemically bound to the polymeric structure, the electrolyte is contained. Importantly, product water removal is simplified, as electrolyte dilution is not a concern. However, the proton transport rate is a function of the polymer geometry, which is set, in part, by the ...
As part of its long-term control plan for combined sewer overflow (CSO) abatement, the city of Buffalo, New York, maintained a network of Hydrolab Datasondes (Hydrolab-Hach Company, Loveland, Colorado) to assess receiving water-quality effects by continuously logging dissolved oxygen, pH, temperature, conductivity, and turbidity. Although the effect of individual CSOs could be visualized, turbidity levels entering the Buffalo River from the upper watershed often were greater than from CSO discharges. Turbidity data showed that the Buffalo River was a net-sediment sink. Low dissolved oxygen levels were observed in the summer during dry weather, baseflow, and watershed-wide storms and CSO events. Some CSOs did not produce dissolved oxygen sags in the receiving waters, but others did. This information, together with the sampling done for organic and inorganic contaminants, can aid the decisionmaking process when prioritizing ...
10 papers are presented with the following titles: coal fueled diesel engine development update at GE transportation systems; features and performance data of Cooper-Bassemer coal-fueled six-cylinder LSB engine; preliminary test data and systems analysis of a high pressure coal fuel processor/engine system concept; study for coal-water-slurry fuel combustion in a high speed diesel engine; design and operation of a medium speed 12-cylinder coal-fueled diesel engine; progress on the investigation of coal water slurry fuel combustion in a medium speed diesel engine: part 5 - combustion studies; injection characteristics of coal-water slurries in medium speed diesel equipment; coal-water slurry spray characteristics of a positive displacement fuel injection system; novel injector techniques for coal-fueled diesel engines; and investigation of break-in wear, ring loading and oil supply ...
Site studies for CANDU type NPP began in a careful manner since 1982 as a first part of the Nuclear Power Plant Romanian Program adopted by political and governmental authorities at the time. A team was charged to develop all packages of the necessary main studies. The first Romanian NPP CANDU 6 type reactor gone to erection on Cernavoda site, planned to have 5 units and, like Wolsong NPP, applied the same design for the nuclear island. For the BOP parts the ANSALDO-GE project was applied with a thorough concern about requirements raised by connection to NSP. The first mission of design and research multi-branch team was to adapt the NPP Cernavoda project having an open water cooling circuit 'once-through' to the new parameters of a close recirculation water cooling circuit. Also, the structural design was re-evaluated for the case of soft foundation strata instead of hard rock ones. The close ...
Developed under the PN II Project 71-009 - MONA, the pre-operational monitoring program of the LIL waste disposal site presented in this paper covers the main elements requested for a continuous improvement of site characterization and safety assessment, as well as for the set up of the baseline data requested for the future operational and post-operational monitoring and surveillance. These elements are: vadose and saturated zones hydrogeology, surface erosion, meteorology and radionuclides content in waters, soil and biota. Pairs of TDR (Time Domain Reflectometry) and pressure sensors, coupled with a meteorological station have been installed on site for the continuously measurement of the water content and matric potential changes due to the climate variations. The data will be used to follow the water balance, the pores water velocity and to calculate the infiltration rate. A ...
The purpose of this thesis is to study the behaviour of the simultaneous flow of oil and water in horizontal pipes. In this connection, two test facilities are used. Both facilities have horizontal test sections with inner pipe diameters equal to 2 inches. The largest facility, called the model oil facility, has reservoirs of 1 m{sub 3} of each medium enabling flow rates as high as 30 m{sub 3}/h, which corresponds to mixture velocities as high as 3.35 m/s. The flow rates of oil and water can be varied individually producing different flow patterns according to variations in mixture velocity and input water cut. Two main classes of flows are seen, stratified and dispersed. In this facility, the main focus has been on stratified flows. Pressure drops and local phase fractions are measured for a large number of flow conditions. Among the instruments used are differential pressure transmitters and a traversing gamma ...
The aim of the project is to study the conditions and processes occurring in permanently frozen crystalline bedrock, with special reference to deep (i.e., several hundreds of meters) bedrock conditions. The target of the study is the Lupin mine in Nunavut Territory, Northern Canada. The results may be utilized in assessing the long-term performance of deep underground constructions (e.g., nuclear waste repositories) in cooling climatic conditions. In Phase I of the project versatile background information was collected from the site e.g., on climate, geology and on hydrogeological and hydrogeochemical conditions. During Phase II a broad range of research was conducted including (i) electromagnetic soundings to investigate the distribution of permafrost in the surroundings of the mine; (ii) drilling of three research boreholes at the base of the permafrost for groundwater research; (iii) application of borehole video surveys to study the ...
On all steam turbines operating with condensation the air leakage penetrating from the part of the plant which is under vacuum must be eliminated, in order to maintain the vacuum created by physical conditions. In order to attain effective air bleed-off, the water-steam-air mixture is conveyed via the super-cooling bundles in the condenser. In this way the steam partial pressure decreases and the air partial pressure increases at a constant condenser pressure. In this procedure the mixture is supercooled by about 4"0C compared with the saturate steam temperature appertaining to the condenser pressure. The values of volume of air leakage are the result of a year's experience on existing plant. (orig.).
In the GE 7FDL single cylinder research diesel engine, in-cylinder high-speed photographic studies were conducted on coal-water slurry (CWS) fuel combustion. Distinct flames of pilot and CWS combustion were noticed. It was proven that the coal fuel burns after piston impingement and secondary atomization. Agglomerated particles will develop when combustion conditions are not favorable. Cylinder pressure data were simultaneously recorded for each film frame. Heat release data can thus be produced for each photo study. Most of the findings of earlier combustion studies on engine performance were confirmed.
A micronized de-ashed coal-water slurry (CWS) fuel of approximately 50% coal loading has been successfully ignited and burned in one GE 7FDL engine cylinder at 1050 rpm. For this study, only about one-third of the full load fuel energy was supplied due to limitations of the fuel injection equipment used. Three types of ignition methods have been investigated. They were: Compression ignition with no ignition aid; Separate deisel pilot fuel injection to ignite the CWS fuel; Combined CWS and pilot diesel fuel injection (stratified pilot ignition). Conditions of ignition and the burning characteristics that immediately followed using the above three ignition methods are described.
This is a process for producing calcium sulfate dihydrate during desulfurization of stack gases from power station boilers, where the stack gases are introduced into a washing tower and are treated with a washing water suspension containing lime in the washing tower, where oxygen in the form of air or of air enriched in oxygen is also blown into the washing tower, and where the washing water suspension drawn off from the washing tower is fed back to the washing tower at a temperature of 45 to 50/sup 0/C in the circuit and at least part of the flow goes via a thickener and where calcium sulfate dihydrate slurry is drawn off from the thickener.
A technology for removal of undissolved impurities from a horizontal steam generator using purge water is developed on the basis of a theoretical analysis. A purge with a maximal flow rate is drawn off from the zone with the highest accumulation of sludge in the lower part of the steam generator after the main circulation pump of the corresponding loop is shut off and the temperatures of the heat transfer medium at the inlet and outlet of the steam generator have equilibrated. An improved purge configuration is used for this technology; it employs shutoff and regulator valves, periodic purge lines separated by a cutoff fixture, and a D y 100 drain union as a connector for the periodic purge. Field tests show that the efficiency of this technology for sludge removal by purge water is severa...
This report consists of appendices A-F containing the biological data which were collected from Lake Roosevelt, Washington. The data are to be used in the design of a computer model that would predict biological responses of reservoir operations as part of the System Operation Review program. Major components of the model included: Quantification of impacts to phytoplankton, zooplanktons, benthic invertebrates, and fish caused by reservoir drawdowns and low water retention times; quantification of number, distribution, and use of fish food organisms in the reservoir by season; determination of seasonal growth of fish species as related to reservoir operations, prey abundance and utilization; and quantification of entrainment levels of zooplankton and fish as related to reservoir operations and water retention times.
Graphical Abstract A Southward view of the Dead Sea western coast. The steep western escarpment of the Dead Sea basin, composed mainly of Upper Cretaceous limestone and dolomite, can be seen on the right. Beach terraces left by the shrinking lake run parallel to the shore. The larger part of the area between the present water line and the mountains was still under Dead Sea water just 50?60?years ago. The current fall of the lake?s stand is around 1?m?year?1. Three on-shore sinkholes can be seen in the front of the photo, as well as two submerged ones near its lower left corner. These were caused by dissolution of a Holocene salt layer located tens of meters below the surface, resulting in the collapse of the overlying sediments. The retreat of the Dead Sea in recent years was followed by e...
Shallow-water zooplanktivorous fish rely on their vision for foraging. In shallow water, feeding efficiency decreases in dim light and thus the fish cease foraging at crepuscular hours. Creatures living in the lower parts of their depth ranges are expected to be exposed to limited light levels for longer hours. However, observations of the zooplanktivore Dascyllus marginatus showed little change in foraging duration down to 40m deep. We asked whether the visual system's functionality changes with depth along the depth range of this damselfish; we examined eye and retina anatomy for changes in visual acuity and light sensitivity and used the optomotor response to test for spatial and temporal light summation. We found only minor changes in the anatomy of the eye that are not expected to aff...
In June 2003, we conducted a two-part field exercise to examine biogeochemical characteristics of water in the lower Mississippi river during the 4 days prior to discharge and in the Mississippi river plume over 2 days after discharge. Here we describe the fates of materials immediately after their discharge through Southwest Pass of the Mississippi delta into the northern Gulf of Mexico. Changes in surface water properties immediately after discharge were much larger and more rapid than changes prior to discharge. Total suspended matter (TSM) declined, probably due to sinking, dissolved macronutrients were rapidly diminished by mixing and biological uptake, and phytoplankton populations increased dramatically, and then declined. This decline appeared to begin at salinities of approximatel...
The loss of seal of the H9 channel in vacuum, freeing the entire cross section of the front part, leads to a fast leak that progresses rapidly. The effect of depressurizing the reflector can leads to shutdown of the shutdown rod pumps. The source changer associated with the channel fills completely before the valve closes. All of the leak water remains contained within the source changer containment. After the valves open, cooling of the fuel element is handled by natural convection, requiring a reversal of the flow between the plates. This changeover, which takes place at a relatively low pressure level, could lead to local boiling in the fuel element. Consequently, irreversible transformations cannot be excluded as possibilities for the fuel element and even for the control rod. Subsequently, the can is refilled with heavy water with establishment of the usual pressure levels.
The investigation of steam, water, and air flow characteristics in horizontal channel is a part of major investigations program at the Lithuanian Energy Institute. The objective of this program is to identify condensation effects on two-phase flow stability and to predict conditions when rapid condensation could be induced in two-phase condensable flow. This article presents investigation of steam-water and air multiphase flow in nearly horizontal rectangular channel. The experimental data for pressure drop and interfacial and wall shear stresses in the channel with uniform distribution of void fraction are presented in this paper. Overall channel dimensions are length = 1.2 m, width = 0.02 m, height = 0.1 m; however, the test section was about 0.84 m in length. Three different flow types ...
The possible long-term effects of chronic radiation exposure have been studied. Rats were given tritiated drinking water (3 #mu#Ci/ml) before and during pregnancy and thereafter continuously through five generations. The brains were studied at 30 and 120 days postnatally. Significant decreases in weight and DNA and protein contents of specific parts of the brain were found, the most pronounced decreases being in the diencephalon. The decrease in protein content were more pronounced than the decreases in DNA content; the decreases were also more pronounced at 30 days than at 120 days, and more pronounced in the fith generation than in previous generations.
This paper proposes an integrated method for using experimental data and CFD modeling to develop engineering correlations for atrium smoke management. Part I focused on the experimental program and validation of a CFD model of the experimental facility. PartII describes the extension of this model to a parametric study of balcony spill plumes. Smoke management in buildings during fire events often uses mechanical ventilation systems to maintain smoke layer elevation above a safe evacuation path. Design of these systems requires accurate correlations for the smoke production or mass flow rate of the buoyant fire plume. One design issue is the mass flow rate of fire plumes which spill out from a fire compartment, under a balcony and up through an atrium or other large volume. Current engineering correlations for these balcony spill plumes (BSPs) are based on a combination of one-tenth scale test data and theoretical ...
This paper proposes an integrated method for using experimental data and CFD modeling to develop engineering correlations for atrium smoke management. Part I focused on the experimental program and validation of a CFD model of the experimental facility. PartII describes the extension of this model to a parametric study of balcony spill plumes. Smoke management in buildings during fire events often uses mechanical ventilation systems to maintain smoke layer elevation above a safe evacuation path. Design of these systems requires accurate correlations for the smoke production or mass flow rate of the buoyant fire plume. One design issue is the mass flow rate of fire plumes which spill out from a fire compartment, under a balcony and up through an atrium or other large volume. Current engineering correlations for these balcony spill plumes (BSPs) are based on a combination of one-tenth scale test data and theoretical ...
New palladium(II) complexes (2), bearing NHC/TPPTS ligands, (NHC=benzimidazol-2-ylidene; TPPTS=triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt) have been prepared and characterized by elemental analyses and spectroscopic methods. Their ability to catalyze the Suzuki-Miyaura reaction in neat water has been studied at 100^oC. Very high activities have been observed in the coupling of phenylboronic acid with aryl chlorides in the presence of 1% of the catalyst. We have compared the electronic properties of cis-[PdBr2(NHC)(TPPTS)] with the related complexes, [PdX2(NHC)]2 and [trans-PdBr2(NHC)(pdca)] (pdca=pyridine-2,6-dicarboxyic acid) (3) via three different techniques: cyclic voltammetry, thermogravimetric analysis and ^1^3C NMR spectroscopy.
Understanding of the thermal hydraulic phenomena is now the key issue in solving the severe accident problems of light water reactors. The Atomic Energy Society of Japan has organized a special committee on the evaluation of the thermal hydraulic phenomena in severe accident. The committee has continued the investigation of present status of thermal hydraulics in severe accident. Industries have completed the detailed implementation of the accident management measures, and industries have established also a self-regulatory document mainly on phase II accident management for the containment design of the future reactors. Present paper reviews the current status of evaluation activity referring to severe accident research in Japan. The phenomena included in this paper are (1) molten core behavior in lower plenum of pressure vessel, (2) fuel-coolant interaction, (3) molten core-concrete interaction, (4) direct containment heating, (5) hydrogen ...
Crude oil-polluted soil (five parts of weathered crude oil per 100 parts of soil; equivalent to 50,000 mg oil kg{sup -}1 soil) samples were slurried in deionised water (300% of the water retention capacity of the soil) and treated with various amounts of natural-rubber processing sludge (nitrogen content 62.15 mgkg{sup -1} and phosphorus contents 8.75 mgkg{sup -1}) in a well-stirred, continuously-aerated tank at 29{sup o}C. Changes in the total hydrocarbon content of the soil sample were determined, using a spectrophotometric technique, as a function of time. The extent of crude oil degradation was markedly higher (by up to 100%) in the sludge-treated soil than in the untreated soil sample. The efficiency of biodegradation of the crude oil hydrocarbons using the slurry-phase technique was compared with that of solid-phase technique. (author)
The performance of the Magma Power Company's reinjection well No. 46-7 at East Mesa has been examined. Water was cooled to 100/sup 0/F(+-) to simulate total heat extraction and then tested using membrane filter flow procedures. The cooled water contains particles which are in the high colloid size range, and formation impairment by these particles is unlikely. There is evidence that acid soluble corrosion products and calcium compounds constitute about two thirds of the particulates, and that the acid insoluble residue contains precipitated silica, insoluble corrosion products, and possibly formation fines carried in the produced water. Under stabilized conditions, the suspended solids content of the water is less than 2 parts per million. However, during the frequent production well start ups, a higher concentration of suspended solids is carried in the produced ...
An experimental investigation on the air/water counter-current two-phase flow in a horizontal rectangular channel connected to an inclined riser has been conducted. This test-section representing a model of the hot leg of a pressurized water reactor is mounted between two separators in a pressurized experimental vessel. The cross-section and length of the horizontal part of the test-section are (0.25 m x 0.05 m) and 2.59 m, respectively, whereas the inclination angle of the riser is 50 deg. The flow was captured by a high-speed camera in the bended region of the hot leg, delivering a detailed view of the stratified interface as well as of dispersed structures like bubbles and droplets. Countercurrent flow limitation (CCFL), or the onset of flooding, was found by analyzing the water levels measured in the separators. The counter-current flow limitation is defined as the maximum air mass flow rate at ...
An analytical study of the ice-formation process associated with heat-conducting plates located perpendicularly to isothermally heated and cooled surfaces with some clearance is presented. It is proposed that the onset conditions, which describe whether the ice-volume fraction in a steady state is greater than or less than that without heat-conducting plates, are defined by the dimensionless distances between the heated/cooled walls and the heat-conducting plates. It is shown that the onset conditions are dependent on the pitch and the thickness of the heat-conducting plates and are less dependent on the thermal conductivity of the plates.
In order to realize improve of reliability and economy by duplicate production, rapid supply of repair parts from standardized storage, such were expected as to have continuous order of standardized plant, to ignore site condition, to avoid expansion of regulatory requirement. Standardization program was planned to limitedly promote standardization of safety-related design concept, major specification and basic system composition of reactor and primary systems. The area of standardization had been tried to expand to BOP such as general arrangement and rad-waste system.
This paper describes the design, operation, and performance of an HVAC system installed as part of a project to demonstrate energy efficiency and environmental responsibility in commercial buildings. The systems installed in the 2180 m{sup 2} office building provide superior air quality and thermal comfort while requiring only half the electrical energy of conventional systems primarily because of the hydronic heating and cooling system. Gas use for the building is higher than expected because of longer operating hours and poor performance of the boiler/absorption chiller.
This document presents an assessment of the severe accident phenomena observed from four Full-Length High-Temperature (FLHT) tests that were performed by the Pacific Northwest Laboratory (PNL) in the National Research Universal (NRU) reactor at Chalk River, Ontario, Canada. These tests were conducted for the US Nuclear Regulatory Commission (NRC) as part of the Severe Accident Research Program. The objectives of the test were to simulate conditions and provide information on the behavior of full-length fuel rods during hypothetical, small-break, loss-of-coolant severe accidents, in commercial light water reactors.
The present Annual Report of Activities of the Nuclear Regulatory Authority (ARN), prepared regularly from the creation as independent institution, describes across tree parts and seven annexes the activities developed by the organism during 2007. The main topic are: the organization and the activity of the ARN; the regulatory standards; the licensing and inspection of nuclear power plants and critical facilities; the emergency systems; the occupational surveillance; the environmental monitoring; improved organizational. Also, this publication have annexes with the following content: regulatory documents; inspections to medical, industrial and training installations; regulatory guides; measurement and evaluation of the drinking water of Ezeiza.
We study the well-posedness of the initial value problem for a wide class of singular evolution equations. We prove a general well-posedness theorem under three assumptions easy to check: the first controls the singular part of the equation, the second the behavior of the nonlinearities, and the third one assumes that an energy estimate can be found for the linearized system. We allow losses of derivatives in this energy estimate and therefore construct a solution by a Nash-Moser iterative scheme. As an application to this general theorem, we prove the well-posedness of the Serre and Green-Naghdi equation and discuss the problem of their validity as asymptotic models for the water-waves equations.
Full text of publication follows: Large-scale problems such as nuclear waste disposal are increasingly recognized to be interconnected to small scale-mechanisms. Thus, synchrotron-based high-resolution analytical X-ray probes become important tools for exploring the micro-scale chemical reactivity of heterogeneous barrier materials used in nuclear waste repositories. In this study the layout of the micro-XAS beamline at the Swiss Light Source (SLS) will be presented. The beamline is optimized towards micro beam experiments ({approx}1 x 1 {mu}m{sup 2}) in the hard-X-ray regime (4 - {approx}22 keV) and allows to combine micro X-ray fluorescence (micro-XRF), micro X-ray absorption spectroscopy (micro- XAS), and micro X-ray diffraction (micro-XRD) investigations with radioactive samples. Furthermore, the potential of micro-XRF/XAS/XRD for acquiring spatially resolved molecular level information on the speciation and structural coordination environment of radionuclides in heterogeneous ...
The corrosion behavior of steel in water from certain oil fields with various organic inhibitors was studied by applying potentiodynamic technique at pH 5.9. The inhibitors which were used include 2-methylbenzimidazole (I), 2-mercaptobenzimidazole (II), 2-mercapto-5-methylbenzimidazole (III), and 2-mercaptothiazole (IV). The inhibiting efficiency of the different additives was evaluated from their anodic and cathodic polarization curves at different temperatures. A comparative study of curve fitting procedures using the kinetic thermodynamic model and those utilizing well-known adsorption isotherms was undertaken. Three types of isotherms were used, Langmuir, Frumkin and Flory-Huggins isotherm. The results show that the kinetic-thermodynamic model and Flory-Huggins isotherms are more suitable to fit the data for the four inhibitors, at all applied temperatures. From the values of binding constants, K, the order of inhibitor efficiency is: III ...
Results are presented from studies on the quality of cast parts made by counterpressure casting of high-strength aluminum alloy AMKh-605, and Al-Cu-Mn-Cr alloys (5.6-6.4% Cu, 0.25-0.55% Mn, 0.20-0.55% Cr, 0.20-0.45% Ti, 0.08-0.25% Zr, less than or equal to0.25% Fe, less than or equal to0.25% Si, less than or equal to0.05% Mg). Chill castings were heat treated by quenching from 450/sup 0/C (20 hours) in water, aging at 160/sup 0/C for five hours with cooling in air. Fractograms of tensile specimens are presented. Scanning electron microscopy allows an ambiguous determination of the cause of failure of a part, be it at initial crystallization crack defects or burns, and also allows a relationship to be established between structure and mechanical properties.
In the first part of the symposium, experts reviewed the state of the art of decentralized waste water treatment in Europe. In the second part, exemplary solutions in Poland and the Czech Republic were presented. The final part was dedicated to future concepts and strategies. [German] Im Herbst letzten Jahres hat die Kommunale Umwelt-AktioN U.A.N. in einer Abfolge von drei Abwasserfachsymposien Expertenrunden zum Austausch ueber den aktuellen Stand des Wissens zum Thema dezentrale Abwasserbehandlung veranstaltet. Mit dem Internationalen Symposium 'Konzepte zur Abwasserbehandlung im laendlichen Raum Europas' in Celle hat das Projekt der U.A.N. seinen Abschluss gefunden. Der Konzeption des Projektes entsprechend haben im 1. Teil des Symposiums Experten ueber den Stand der Entwicklung auf dem Sektor der dezentralen Abwasserbehandlung in Deutschland berichtet. Im 2. Teil unserer Fachtagung ...
New tetradentate N(2)O(2) donor Schiff bases and their mononuclear Co(II), Ni(II), Cu(II), and Pd(II) complexes were synthesized and characterized extensively by IR, (1)H-, (13)C-NMR, mass, ESR, conductivity measurements, elemental and thermal analysis. Specifically the magnetic and electronic spectral measurements demonstrate the octahedral structures of cobalt(II), nickel(II) complexes and square planar geometries of copper(II), palladium(II) complexes. All the ligands and complexes were screened for their in vitro antibacterial activity against two gram-positive bacteria (Bacillus subtilis, Staphylococcus aureus) and two gram-negative bacteria (Escherichia coli, Klebsiella pneumonia). In this study, Pd(II) complexes exhibited potent antibacterial activity against B. subtilis, S. aureus whereas ...
The purpose of this project was to demonstrate targeted infill and extension drilling opportunities, better determinations of oil-in-place, and methods for improved completion efficiency. The investigations and demonstrations were focussed on Red River and Ratcliffe reservoirs in the Williston Basin within portions of Montana, North Dakota and South Dakota. Both of these formations have been successfully explored with conventional 2-dimensional (2D) seismic. Improved reservoir characterization utilizing 3-dimensional (3D) seismic was investigated for identification of structural and stratigraphic reservoir compartments. These seismic characterizations were integrated with geological and engineering studies. The project tested lateral completion techniques, including high-pressure jetting lance technology and short-radius lateral drilling to enhance completion efficiency. Lateral completions should improve economics for both primary and secondary oil where low permeability is a problem ...
It is planned to use the tritium dose model, DCART (Doses from Chronic Atmospheric Releases of Tritium), to reconstruct dose to the hypothetical maximally exposed individual from annual routine releases of tritiated water (HTO) and tritiated hydrogen gas (HT) from all Lawrence Livermore National Laboratory (LLNL) facilities and from the Sandia National (SNL) Laboratory's Tritium Research Laboratory over the last fifty years. DCART has been described in Part 1 of ''Historical Doses From Tritiated Water And Tritiated Hydrogen Gas Released To The Atmosphere from Lawrence Livermore National Laboratory (LLNL)'' (UCRL-TR-205083). This report (Part 2) summarizes information about annual routine releases of tritium from LLNL (and SNL) since 1953. Historical records were used to derive facility-specific annual data (e.g., source terms, dilution factors, ambient air ...
The work of this association is cut according to 6 axes. Three publications: radiological quality of marine and continental waters of the Normandy coast (synthesis 1997 and 1998); preliminary study of the iodine 129 distribution in the environment of the reprocessing plant of La Hague with terrestrial moss (Homalotecium sericeum); radiological surveillance of the aquatic environment of the nuclear facilities on the area of La Hague (1997 and 1998). The second axis concerns the radiation protection with a campaign of radon measures in a school of the Vire rural district (june 1999). The third part is devoted to the radioecology with the surveillance of radioactivity in the aquatic continental environment of nuclear facilities and the radioecological surveillance (1999) of the building site of Cogema la Hague in the area of tidal range of the Moulinets cove. The fourth part concerns the radioactive waste and environment, with ...
Some acylhydrazine derived ONO donor Schiff bases and their Co(II) and Ni(II) complexes have been prepared having the same metal ion (cation) but different anions. These synthesized metal(II)...Full Text Available
The uptake of "2"3"8U and "2"3"2Th in different parts of some selected plants used in traditional treatment of hypertension and diabetes in south-eastern Morocco (Errachidia area) has been studied using two different types of solid state nuclear track detectors (SSNTDs) LR-115 type II and CR-39. Plant uptake of radionuclides is one of many vectors for introduction of contaminants into the human food chain. Thus, it is critical to understand soil-plant relationships that control nuclide bioavailability. Soil concentrations of uranium ranged from 6.10 to 11.62 ppm, with a mean of 7.90 ppm. Soil concentrations of thorium ranged from 2.70 to 4.80 ppm, with a mean of 3.41 ppm. Mean uranium specific activities were 8.38 Bq kg"-"1 in root tissue, 5 Bq kg"-"1 in stem tissue and 6.02 Bq kg"-"1 in leaf tissue. Mean thorium specific activities were 2.53 Bq kg"-"1 in root tissue, 1.64 Bq kg"-"1 in stem tissue and 1.96 Bq kg"-"1 in leaf tissue. The transfer ...
Part I of this thesis is on long-term iceberg collision-risk assessment methods for fixed offshore structures. Estimates for the long-term probability that an iceberg will hit a fixed offshore structure are based on estimates of the total volume of produced iceberg, a model for the size distribution of icebergs and a description of how iceberg trajectories ``fill`` the plane (the ocean`s surface). PartII of the thesis discusses methods for analysis of low resolution data in the sense that the size of the area covered by each pixel is not small compared to the dominating floes. Still, this type of data can provide estimates of the ice extent (and hence the ice edge) and ice concentration. The estimates of the ice edge (at least) seem to be physically significant in the sense that ``in some way`` they can reflect ice drift in an image time sequence. A priori this is far from obvious. A central idea is that the ``ice edge`` ...
The objective of this research project is to demonstrate sensing, communication, information and control technologies to achieve a seamless integration of multivendor distributed energy resource (DER) units at aggregation levels that meet individual user requirements for facility operations (residential, commercial, industrial, manufacturing, etc.) and further serve as resource options for electric and natural gas utilities. The fully demonstrated DER aggregation system with embodiment of communication and control technologies will lead to real-time, interactive, customer-managed service networks to achieve greater customer value. Work on this Advanced Communication and Control Project (ACCP) consists of a two-phase approach for an integrated demonstration of communication and control technologies to achieve a seamless integration of DER units to reach progressive levels of aggregated power output. Phase I involved design and proof-of-design, and Phase II involves ...
In 1996, a field-scale phytoremediation demonstration project was initiated and managed by the U.S. Air Force at a site in western Fort Worth, Texas, using a plantation of 1-year-old stems harvested from branches of eastern cottonwoods during the dormant season (whips) and a plantation of 1-year-old eastern cottonwood seedlings (calipers). The primary objective of the demonstration project was to determine the effectiveness of eastern cottonwoods at reducing the mass of dissolved trichloroethene transported within an alluvial aquifer. The U.S. Geological Survey conducted a study, in cooperation with the U.S. Air Force, to determine water-level variations and their effects on tree growth and mortality and on the biogeochemical system at the phytoremediation site. As part of the study, water-level and water-quality data were collected throughout the duration of the project. This report presents ...
Nuclear fuel cycle activities of the former Soviet Union (FSU) have resulted in massive contamination of the environment in western Siberia. We are developing three-dimensional numerical models of the hydrogeology and potential contaminant migration in the West Siberian Basin. Our long-term goal at Pacific Northwest Laboratory is to help determine future environmental and human impacts given the releases that have occurred to date and the current waste management practices. In FY 1993, our objectives were to (1) refine and implement the hydrogeologic conceptual models of the regional hydrogeology of western Siberia developed in FY 1992 and develop the detailed, spatially registered digital geologic and hydrologic databases to test them, (2) calibrate the computer implementation of the conceptual models developed in FY 1992, and (3) develop general geologic and hydrologic information and preliminary hydrogeologic conceptual models relevant to the more detailed models of contaminated ...
Beyond a great number of applications in mineral process, the hydrocyclone separation has been used recently in an increasing number of fields, such as: environmental engineering, petrochemical engineering, food engineering, electrochemical engineering, pulp bioengineering, processes and paper industries, among others. Nowadays, the produced water is treated and then reinjected in the surface and also in return to the formation. In the offshore platforms, the produced water can be directly discarded in the ocean, since the dispersed phase concentration (oil) is according to Brazilian regulating agency limits. The basic principle used in hydrocyclone separation is the centrifugal sedimentation machine: the suspended particles are submitted to centrifugal acceleration, which separates them from the fluid. The basic geometry of a hydrocyclone consists of four parts: a cylindrical section for feeding, a conical section for ...
Here we present evidence that in water/acetonitrile solvent detailed structural and dynamic information can be obtained for important proteins that are naturally present as oligomers under native conditions. An NMR-derived human insulin monomer structure in H{sub 2}O/CD{sub 3}CN, 65/35 vol%, pH 3.6 is presented and compared with the available X-ray structure of a monomer that forms part of a hexamer (Acta Crystallogr. 2003 Sec. D59, 474) and with NMR structures in water and organic cosolvent. Detailed analysis using PFGSE NMR, temperature-dependent NMR, dilution experiments and CSI proves that the structure is monomeric in the concentration and temperature ranges 0.1-3 mM and 10-30 deg. C, respectively. The presence of long-range interstrand NOEs, as found in the crystal structure of the monomer, provides the evidence for conservation of the tertiary structure. Starting from structures calculated by the program CYANA, two ...
The long operating cycle simplified boiling water reactor is a reactor concept that pursues both safety and the economy by employing a natural circulation reactor core without a refueling, a passive decay heat removal, and an integrated building for the reactor and turbine. Throughout the entire spectrum of the design basis accident, the reactor core is kept covered by the passive emergency core cooling system. The decay heat is removed by the conventional active low-pressure residual heat removal system. As for a postulated severe accident, the suppression pool water floods the lower part of the reactor pressure vessel (RPV) in the case when core damage occurs, and the in-vessel retention that keeps the melt inside the RPV is achieved by supplying the coolant. The containment adopts a parallel-double-steel-plate structure similar to a hull structure, which contains coolant between the inner and outer walls to absorb the ...
There is a great demand for the reduction of specific fuel consumption in diesel engines, and also of NO/sub x/ emission in especially those designed for use on land. However, while improving combustion, a problem arises in trying to reduce both simultaneously because the techniques required are contradictory. This series of experiments was done to study the correlation between specific fuel consumption and NO/sub x/ emission. The research was conducted under variations in engine parameters and operating conditions. The variations studied included effects of pressure, temperature and humidity of the charging air, temperature of the cooling water, timing and rate of fuel injection, fuel injection nozzle, EGR and water-emulsified fuel. The results of the tests clarified the characteristics of the specific fuel consumption and NO/sub x/ emission and indicated that the most-effective measures for the reduction of specific fuel consumption and NOx ...
An Environmental Management Plan (EMP) for the Jharia Coalfield (JCF) was recently completed as part of a World Bank funded project. The JCF, 260 km west of Calcutta, comprises 450 km{sup 2}. Bharat Coking Coal Limited (BCCL) operates an area of 258 km{sup 2}. Coal mining has been conducted for more than 100 years. There are severe constraints to mining due to geology, coal fires and the large population. BCCL counterpart staff participated actively in all aspects of the work. Air and water are heavily polluted, however, mining operations contribute only to a limited extent to the total pollution. Water contamination is generally due to inadequate sewage treatment and discharge from non-mine facilities such as power plants. The large area disturbed by mining to date will increase, as open pit mining operations are expected to expand significantly. Reclamation to date is generally confined to planting of trees. Areas where ...
Polycyclic aromatic hydrocarbons (PAH`s) are ubiquitous hydrophobic organic pollutants in the marine environment. Many of the PAM`s are classified as possible carcinogens or mutagens, therefore they are of considerable concern to human and environmental health. The highest concentrations are found in coastal regions due to anthropogenic activities including oil spills, tanker operations, incomplete fossil fuel combustion and runoff. The sources and distribution of PAM`s in sediments are fairly well known, while the fate and transport of PAH`s in the marine environment are less known. Desorption is an important factor influencing the fate and transport of hydrophobic molecules at the seawater/sediment interface. The desorption of PAH`s from contaminated marine sediments to the water column/pore water affects the availability of the pollutant to biota. The sorption of PAH`s is determined in part by the organic carbon content ...
During 17 years since the start of operation of the first commercial LWR in Japan, many LWRs have experienced various corrosion damages, but the causes of them were clarified, and the counter-measures were executed effectively in actual plants, as the results, the cause of corrosion damage decreased remarkably, and now, the high rate of operation has become to be maintained. In this paper, the major cases of corrosion damage experienced in LWRs in Japan and foreign countries, the causes of them and the countermeasures, the problems of hereafter and so on are described. The corrosion damage of metallic materials in the environment of LWRs occurs in the parts in contact with high temperature, high pressure water and steam, such as stainless steel piping in the primary cooling system of BWRs, and nickel alloy heating tubes of steam generators, carbon steel feed water piping and zirconium alloy fuel cladding tubes in PWRs. ...
During 17 years since the start of operation of the first commercial LWR in Japan, many LWRs have experienced various corrosion damages, but the causes of them were clarified, and the counter-measures were executed effectively in actual plants, as the results, the cause of corrosion damage decreased remarkably, and now, the high rate of operation has become to be maintained. In this paper, the major cases of corrosion damage experienced in LWRs in Japan and foreign countries, the causes of them and the countermeasures, the problems of hereafter and so on are described. The corrosion damage of metallic materials in the environment of LWRs occurs in the parts in contact with high temperature, high pressure water and steam, such as stainless steel piping in the primary cooling system of BWRs, and nickel alloy heating tubes of steam generators, carbon steel feed water piping and zirconium alloy fuel cladding tubes in PWRs. ...
The hydroelectric industry's recognition of the importance of avoiding unexpected failure, or forced outages, led to the development of probabilistic, or risk-based, methods in order to attempt to quantify exposures. Traditionally, such analysis has been carried out by qualitative assessments, relying on experience and sound engineering judgment to determine the optimum time to maintain, repair or replace a part or system. Depending on the nature of the problem, however, and the level of experience of those included in the decision making process, it is difficult to find a balance between acting proactively and accepting some amount of risk. The development of a practical means for establishing the probability of failure of any part or system, based on the determination of the statistical distribution of engineering properties such as acting stresses, is discussed. The capacity-demand analysis methodology, coupled with probablistic, ...
A structurally conserved element, the trigger loop, has been suggested to play a key role in substrate selection and catalysis of RNA polymerase II (pol II) transcription elongation. Recently resolved...Full Text Available
The insulin/IGF-1 signaling (IIS) pathway is a conserved regulator of longevity, development, and metabolism. In Caenorhabditis elegans IIS involves activation of DAF-2 (insulin/IGF-1...Full Text Available
DNA from the peripheral blood mononuclear cells of 17 different individuals infected with human T-cell lymphoma/leukemia virus type II (HTLV-II) was successfully amplified by the polymerase chain reaction...Full Text Available
This dissertation is concerned with the development, experimental diagnostics and mathematical modelling and simulation of polymer electrolyte fuel cells (PEFC). The central themes throughout this thesis are the closely interlinked phenomena of mass and charge transfer. In the face of developing a PEFC system for vehicle propulsion these phenomena are scrutinized on a broad range of relevant scales. Starting from the material related level of the membrane and the gas diffusion layer (GDL) we turn to length scales, where structural features of the cell additionally come into play. These are the scale of flow channels and ribs, the single cell and the cell stack followed by the cell, stack, and system development for an automotive power train. In Chapter 3 selected fundamental material models and properties, respectively, are explored that are crucial for the mathematical modelling and simulation of PEFC, as needed in some succeeding parts of this work. First, ...
Measurements were completed on the solubility of cupric and cuprous oxides in liquid water and steam at controlled pH conditions from 25 to 400 C (77 to 752 F). The results of this study have been combined with those reported from this laboratory in two previous EPRI reports to provide a complete description of the solubility of these oxides and the speciation of copper dissolved in liquid water and steam as a function of oxidation state, temperature, pH, and in the case of steam, pressure. These constitute the first set of reliable data for cuprous oxide solubility over this range of conditions. For the more intensively studied CuO case, agreement was found between our results and those of previous studies of its solubility in steam, whereas only partial agreement was evident for its solubility in liquid water. For both oxides this disagreement often amounted to orders of magnitude. The solubility of cuprous oxide is ...
The microbial transport simulator (MTS) is a three-dimensional, three-phase, multiple-component numerical model that permits the study of the transport of microorganisms and nutrients in porous media. Microbial parameters incorporated into MTS include: Microbial growth and decay, microbial deposition, chemotaxis, diffusion, convective dispersion, tumbling, and nutrient consumption. Governing equations for microbial and nutrient transport are coupled with continuity and flow equations under conditions appropriate for a black oil reservoir. The model`s mathematical formulations and preparation procedures of data files for conducting simulations using MTS are described. A general background of microbial transport simulation is given in Section I and the governing equations, mechanisms, and numerical solutions of MTS are given in Section II. Explanations for preparing an input data file with reservoir and microbial transport data are described in Section III, and ...
A computational model has been developed to calculate the potential and current distributions in the electrolyte phase and on the electrode surface for a system in which a part of the anode is passivated while the rest remains in the active dissolution state. The computation employs the finite element method allied with a boundary variation and a trial and error technique. From the obtained distributions, the location of the boundary between the active and passive regions on the anode can be predicted. In the case of a crevice, this means that a critical distance into the crevice exists beyond which active corrosion (crevice corrosion) takes place. In addition to the active/passive behavior of the material, solution conductivity, applied potential at the sample's outer surface, crevice gap and depth dimensions, and passive current density influence this critical distance to different degrees. The developed software package may also be used for (i) ...
Material related to routine as well as sensitive aspects of parent/day care center relationships is presented in this training module, one of a series providing staff development information for programs operated for dependents of military personnel. The module offers a brief discussion of ways caregivers can help parents feel at ease about leaving their children in child care and presents a set of multiple-choice skill-building exercises for effectively working with parents. Exercises focus on various topics, including how parents can be approached when their child may have a health problem, when child abuse or neglect is suspected, and when parental cooperation is needed to stop a child's undesirable or disruptive behavior. Exercises are also devoted to the questions of whether or not caregivers should act as advisors to parents or tell parents about their child's behavior at the center. Concluding exercises indicate how caregivers can handle parent requests for privileges or ...
This study reviews past assessments of world oil, natural gas, and oil-shale resources. It identifies the methods used in making these assessments (historical statistics, geological analogy, engineering, and probabilistic), the geographical coverage, the time horizons, and the major assumptions about such factors as discovery rates, and recovery factor. The period covered extends from the end of World War II to the end of 1980. Conclusions are presented on the current state of knowledge and understanding concerning each of these three hydrocarbon resources. Regarding world oil resources, an assumed consensus on 2000 billion barrels ultimately recoverable is, in fact, only weakly supported. Close examination of its component parts reveals widespread disagreement. World natural gas resources are even less well understood. And it is premature to venture a meaningful assessment of world oil-shale resources. Thus, our knowledge and scientific ...
Electron and ion beam dynamics of the PF-1000 facility were investigated for the first time at its upper energy limit (?1 MJ) in relation to neutron emission, the pinch's plasma ('target') characteristics and some other parameters with the help of a number of diagnostics with ns temporal resolution. Special attention was paid to the temporal and the spatial cross correlations of different phenomena. Results of these experiments are in favour of a neutron emission model based on ion beam-plasma interaction with three important features: (1) the plasma target is hot and confined during a few 'inertial confinement times'; (2) the ions of the main part of the beam are magnetized and entrapped around the pinch plasma target for a period longer than the characteristic time of the plasma inductive storage system and (3) ion-ion collisions (both fusion collisions, due to head-on impacts and Coulomb collisions) are responsible for neutron emission. Analysis has shown that ...
In this work, a model for determining the optimal inspection and replacement periods of the safety system in Wolsung Nuclear Power Plant Unit 1 is developed, which is to minimize economic loss caused by inadvertent trip and the system failure. This model uses cost benefit analysis method and the part for optimal inspection period considers the human error. The model is based on three factors as follows: (i) The cumulative failure distribution function of the safety system, (ii) The probability that the safety system does not operate due to failure of the system or human error when the safety system is needed at an emergency condition and (iii) The average probability that the reactor is tripped due to the failure of system components or human error. The model then is applied to evaluate the safety system in Wolsung Nuclear Power Plant Unit 1. The optimal replacement periods which are calculated with proposed model differ from those used in ...
The plastic displacements around Knoop indentations made in hard titanium/aluminum multilayered films on soft aluminum alloy substrates have been studied. Indentations were cross-sectioned and imaged using the focused-ion-beam (FIB) milling and high-resolution scanning electron microscopy (SEM), respectively. The FIB milling method has the advantage of removing material in a localized region without producing mechanical damage to the specimen. The micrographs of the cross-sectioned indentations indicate that most of the plastic deformation around the indentation is dominated by the soft aluminum substrate. There is a very small change in the multilayered film thickness around the indentation{emdash}less than 10{percent}. The plastic deformation of the thin film resembles a membrane being deflected by a localized pressure gradient across the membrane. Stress-induced voids are also observed in the multilayered film, especially in the area around the indentation apex. The density and the ...
Coal direct chemical looping (CDCL) substitutes the gasification process in syngas chemical looping (SCL), thus eliminating the need for higher oxygen consumption. In this study, operating conditions are assessed for CDCL and SCL, directed towards hydrogen production from coal. The main objective is to increase the overall H{sub 2}/CO{sub 2} ratio for a given amount of coal, based on the various conditions. The operating variables considered as part of a resource optimization analysis include: (i) inlet conditions to the primary reactors, (ii) minimum resource requirements (air, steam and iron oxide), (iii) hydrogen-to-component ratios, and (iv) effect of coal carrier gas. The results suggest that CDCL has a higher hydrogen-to-CO{sub 2} ratio than SCL along with advantages such as low overall resource requirements (steam and air) and fewer intermediate processes. The coal carrier gas affects the hydrogen production only in the SCL system by ...
The authors characterized nine human actin genes that they isolated from a library of cloned human DNA. Measurements of the thermal stability of hybrids formed between each cloned actin gene and ..cap alpha..-, ..beta..-, and ..gamma..-actin mRNA demonstrated that only one of the clones is most homologous to sarcomeric actin mRNA, whereas the remaining eight clones are most homologous to cytoplasmic actin mRNA. By the following criteria they show that these nine clones represent nine different actin gene loci rather than different alleles or different parts of a single gene: (i) the restriction enzyme maps of the coding regions are dissimilar; (ii) each clone contains sufficient coding region to encode all or most of an entire actin gene; and (iii) each clone contains sequences homologous to both the 5' and 3' ends of the coding region of a cloned chicken ..beta..-actin cDNA. They conclude, therefore, that the human ...
This research report discusses the radiation hardening of a commercially available mobile robot, the REMOTEC ANDROS. This hardening effort is culminating in the availability of a megarad hardened mobile platform to access areas in nuclear facilities with extremely high levels of radiation (0.1 to 1 Mrad). These radiation levels may be encountered both during routine repair and monitoring activities and accident situations. The project has completed a phase-I U.S. Department of Energy Small Business Innovative Research contract and is now in a phase-II effort with completion scheduled in early 1995. The research involves the evaluation of the material and electrical components of an ANDROS robot to determine the anticipated radiation hardness of the current production version and evaluation of the components that must be replaced or modified to harden the system to higher radiation levels. The work being reported is based on an evaluation of the complete list of all ...
The total hemispherical emittance of an oxide film that formed on 6061-T6 aluminium alloy parts in the Tower Shielding Reactor-II at Oak Ridge National Laboratory was measured from 295 to 773 K using an emissometer and/or a calorimeter. The emittance of this film was critically needed for heat transfer calculations in a simulated loss-of-coolant accident of the reactor. X-ray diffraction analysis identified the film as boehmite (Al{sub 2}O{sub 3} {times} H{sub 2}O), which dehydrated to alumina (Al{sub 2}O{sub 3}) upon heating above 473 K. The measured emittances for the alumina film are in excellent agreement with published values for anodized aluminum films and for bulk alumina. Published values of the emittance of boehmite could not be found for comparison, but evidence is presented that some anodization processes for aluminum yield boehmite and not alumina films.
In order to develop competitive and reliable nuclear power generation systems, development of innovative structural design methods is indispensable and risk-based design approach based on the assessment of failure probability is being developed. Fatigue is commonly considered as an important contributor to failure probability in many components of reactor systems and its assessment gives a large influence on total reliability of the plants. In order to assess its effect on the reliability, propagation of cracks needs to be evaluated as well as their initiation and pre-existence probability. As a part of new design approach, efforts are being taken to develop a simplified estimation method for fatigue crack growth under cyclic application of thermal and thermo-mechanical loading. A simplified estimation method of J-integral based on reference stress method and elastic follow-up factor was developed based on many finite element analyses and evaluation of crack growth ...
One of the major limitations of the nickel (Ni) - yttria-stabilized zirconia (YSZ) anode support for solid oxide fuel cells (SOFC) is its low capability to withstand transients between reducing and oxidizing atmospheres (''RedOx'' cycle), owing to the Ni-to-NiO volume expansion. This work presents results on different anode supports fabricated by tape casting. Three compositions are prepared, as the outcome of a preceding design of experiment approach. The NiO proportion is 40, 50 and 60wt% of the anode composite. The anode support characteristics like shrinkage during sintering, in-situ conductivity at high temperature, electrochemical performance and tolerance against RedOx cycles have been measured. Performance up to 0.72Wcm^-^2 (0.62V, 800^oC) is recorded for the 60wt% NiO sample on sm...
Recently the D{\\O} Collaboration reported an observation of like-sign charge asymmetry (CA), which is about $3.2 \\sigma$ deviation from the standard model (SM) prediction. Inspired by the observation we investigate the scalar unparticle effects, under the color charge of $SU(3)_c$ symmetry, in the CP violation in neutral B meson oscillations as well as the dispersive and absorptive parts of $\\bar B_q\\leftrightarrow B_q$ transition, which can be related to the CA directly. In order to illustrate the peculiar properties of unparticle, our analysis is carried out in two scenarios for the right-handed section: (I) $\\lambda_R=\\lambda_L$ and $U_D^R=U_D^L$, where $\\lambda_{L,R}$ and $U_D^{L,R}$ are the couplings and flavor mixing matrix of left- and right-handed section, respectively; (II) $\\lambda_R >> \\lambda_L$ and $U_D^R$ is completely a free parameter. In scenario I we found that the wrong- and like-sign CA cannot be changed ...
The aim of this paper is to investigate the possible displacement of natural gypsum (CaSO{sub 4}2H{sub 2}O) in cement with an alternative setting retarder, such as the industrial by-product derived from flue gas desulfurization process called FGD gypsum. These calcium-sulfate-bearing materials (CSBM), alone or in mixtures, were ground with clinker both in laboratory and industrial scale to examine their influence on the physical and mechanical properties of cement, as well as on the industrial production line of cement. From the present work, it is extracted that the use of mixtures of sulfate-bearing materials with gypsum seems to be advantageous for the actual control of setting time. The addition of FGD gypsum increases setting time without affecting compressive strength profile. During the industrial trial, the formation of hemihydrate form of calcium sulfate dihydrate has a profound regulatory effect on the setting and strength performance of the cement partially replaced with FGD ...
The results of this research centered on the experimental studies of a single superconducting persistent current qubit, the implementation of type-II algorithms using these qubits, and the proposal for adiabatic quantum computing using these qubits. The m...
The in vivo photochemical activity of photosystem II was inferred from modulated chlorophyll fluorescence and photoacoustic measurements in intact leaves of several plant species (Lycopersicon...Full Text Available
Woolfolk, C. A. (University of Washington, Seattle). Reduction of inorganic compounds with molecular hydrogen by Micrococcus lactilyticus. II. Stoichiometry with inorganic...Full Text Available
... and high-quality photospheric-phase Type II SN spectra to constrain core- collapse SN explosions, massive star evolution, and distances in the Universe ...
This document describes payload control at LLNL to ensure that all shipments of CH-TRU waste in the TRUPACT-II (Transuranic Package Transporter-II) meet the requirements of the TRUPACT-II SARP (safety report for packaging). This document also provides specific instructions for the selection of authorized payloads once individual payload containers are qualified for transport. The physical assembly of the qualified payload and operating procedures for the use of the TRUPACT-II, including loading and unloading operations, are described in HWM Procedure No. 204, based on the information in the TRUPACT-II SARP. The LLNL TRAMPAC, along with the TRUPACT-II operating procedures contained in HWM Procedure No. 204, meet the documentation needs for the use of the TRUPACT-II at LLNL. Table 14-1 provides a summary of the LLNL waste generation and ...
The increasing complexity of the real-time data acquisition and processing systems (TDAQ: the so called Trigger and Data AcQuisition systems) in high energy physics calls for an appropriate evolution of development tools. This work is about the interplay between in principle specifications of TDAQ systems and their actual design and realization on a concrete hardware and software platform. The basis of our work is to define a methodology for the development of TDAQ systems that meets the specific demands for the development of such systems. The result is the detailed specification of a 'methodological framework' based on the Unified Modeling Language (UML) and designed to manage a development process. The use of this UML-based methodological framework progressively leads to the setting up of a 'home-made' framework, i.e. a development tool that comprises reusable components and generic architectural elements adapted to TDAQ systems. The main ...
(Materials and Methods) (I) VX/sub 2/ carcinoma was transplanted to the rabbit tibia, sup(99m)Tc-MDP was intravenously injected when bone destruction was radiologically seen. Preoperative scintigraphs, postoperative one of the resected tibia and fibra and scintigraphs of sliced tumor were compared with each other. Tissue fragments were collected from the sliced tumor, and RI was measured to compare concentration rates at different parts together with histological investigations. (II) Tetracycline was given to the rabbit of Experiment (I) to compare with the concentration of sup(99m)Tc-MDP. (III) Microautoradiography method was done on the experimental animals for investigation of the concentration of sup(99m)Tc-MDP. (Results) (I) Localization of sup(99m)Tc-MDP was increased at the sites of tumorous bone formation, of reactive bone formation at tumor edges, and of cartilage calcification, with little concentration at tumor cells or necrotic ...
Clean Water Act You are here: Water Laws & Regulations Policy & Guidance Clean Water Act Water Quality and 401 Certification Water Quality and 401 Certification Water Quality...
Analyzing various SBLOCA with high pressure safety injection (HPSI) at VVER-440/213, we met a surprising phenomenon - a 'natural' circulation post SG heat transfer reversal. This is not usual, because normal natural circulation (NC) in primary circuit is connected with positive heat transfer at SG. If there is reverse heat transfer at SG (as soon as the break enthalpy outflow is sufficient for removal of reactor decay heat), it should obstruct any natural circulation. The question was, what is the driving force of this 'non-standard natural circulation'. After all we revealed that force - it is the density difference between the colder water in reactor downcomer (cold water from HPSI) and warmer water in inner reactor (lower plenum, core, upper plenum). This phenomenon could be confusing for operating personal, because there would be an opposite temperature difference at the loop than by ...
Analyzing various SBLOCA with high pressure safety injection (HPSI) at VVER-440/213, we met a surprising phenomenon - a 'natural' circulation post SG heat transfer reversal. This is not usual, because normal natural circulation (NC) in primary circuit is connected with positive heat transfer at SG. If there is reverse heat transfer at SG (as soon as the break enthalpy outflow is sufficient for removal of reactor decay heat), it should obstruct any natural circulation. The question was, what is the driving force of this 'non-standard natural circulation'. After all we revealed that force - it is the density difference between the colder water in reactor downcomer (cold water from HPSI) and warmer water in inner reactor (lower plenum, core, upper plenum). This phenomenon could be confusing for operating personal, because there would be an opposite temperature difference at the loop than by normal natural circulation (under ...
{sup 14}C is a is a long-lived beta-emitting nuclide (T{sub 1/2} = 5730 years) produced naturally in the upper atmosphere as a result of reactions between neutrons and stable {sup 14}N({sup 14}N(n,p){sup 14}C). Although in a lesser extent, nuclear power plants produce {sup 14}C as well during their routine operation. Since it is converted in {sup 14}CO{sub 2} and mixed throughout the atmosphere, it is incorporated into plant tissues, via photosynthesis process, and hence in food chain. Because of the biological importance of {sup 14}C and long half-life, it is of interest to quantify the amounts released by nuclear industry. The Brazilian nuclear central named Nuclear Central Admiral Alvaro Alberto (CNAAA) has two nuclear reactors of PWR type in operation, Angra I (657 MWe) and Angra II (1350 MWe), and one under construction, Angra III (1309 MWe PWR). The aim of this study was to determine the strength of the sources and the {sup 14}C content in the environment ...
A method of assembling two or more parts together that may be metal, ceramic, metal and ceramic parts, or parts that have different CTE. Individual parts are formed and sintered from particles that leave a network of interconnecting porosity in each sintered part. The separate parts are assembled together and then a fill material is infiltrated into the assembled, sintered parts using a method such as capillary action, gravity, and/or pressure. The assembly is then cured to yield a bonded and fully or near-fully dense part that has the desired physical and mechanical properties for the part's intended purpose. Structural strength may be added to the parts by the inclusion of fibrous materials.
Full text.Changes in land use and urbanization yield more pressure put on limited soil and water resources, including the risk of pollution with toxic heavy metals. The study area lies in the Bekaa valley totaling about 12753 ha. The valley receives from the west torrential fan deposits and a mixture of colluvial and alluvial material. The principal soil classes are Fluvisols, Cambisols, Regosols, Vertisols and Luvisols. The area is populated and also the most important agricultural part of the plain. Agriculture in the plain is being practiced mainly with cash, field crops and vegetables. The western surrounding area is being used mainly for terraced fruit trees. This Arab-German Technical Cooperation Project (ACSAD-BGR) aimed, following the ISO standards and Eikman-Klocke recommendations, at investigating the nature of the extends of soil pollution by heavy metals in two pilot areas: The central Bekaa-Lebanon and Ghouta-Damascus. Different ...
The convolution/superposition algorithm for computing dose from photon beams in radiation therapy planning requires knowledge of the energy spectrum. The algorithm can compute the dose for a polyenergetic beam as the weighted sum of the individual dose contributions from monoenergetic beams. In this study we exploit interface effects apparent in the dose distributions to discriminate among spectra of high energy photon beams. We have studied the sensitivity of the depth dose distribution to the energy components using a hypothetical beam for various field sizes and depths in water and water-lung-water media. Six theoretical spectra were simulated. We compared depth dose data from these spectra using three quantitative measures which are inherently free of normalization ambiguities: for homogeneous water, the ratio D_2_0/D_1_0 and a logarithmic derivative in the buildup region LD_b_u_i_l_d_-_u_p and for inhomogeneous ...
Full text of publication follows: As the coolant experiences no phase change in the core, SCWRs, unlike LWRs, cannot use design criteria based on the critical heat flux concept. The commonly accepted practice in SCWRs is to specify cladding temperature limits that must be met during transient and accident events. Therefore for the design of the SCWR, it is very important to predict the heat transfer coefficient to the supercritical water coolant with great accuracy. Our recent study focuses on the critical issue of measuring heat transfer to supercritical water at prototypical SCWR conditions and to develop the tools to predict the SCWR thermal behavior. A heat transfer test loop using a surrogate fluids, CO_2, is under construction. The reason of using CO_2 instead of water is that (i) valuable insight of the physical phenomena can be obtained with this fluid, and (ii) some existing facilities already ...
Organic materials released from energy-related activities could affect human health and the environment. To better assess possible impacts, we developed a model to predict the fate of spills or discharges of pollutants into flowing or static bodies of fresh water. A computer code, Aquatic Pathways Model (APM), was written to implement the model. The computer programs use compartmental analysis to simulate aquatic ecosystems. The APM estimates the concentrations of chemicals in fish tissue, water and sediment, and is therefore useful for assessing exposure to humans through aquatic pathways. The APM will consider any aquatic pathway for which the user has transport data. Additionally, APM will estimate transport rates from physical and chemical properties of chemicals between several key compartments. The major pathways considered are biodegradation, fish and sediment uptake, photolysis, and evaporation. The model has been implemented with ...
The Maybell uranium mill tailings site is 25 miles (mi) (40 kilometers [km]) west of the town of Craig, Colorado, in Moffat County, in the northwestern part of the state. The unincorporated town of Maybell is 5 road mi (8 km) southwest of the site. The designated site covers approximately 110 acres (ac) (45 hectares [ha]) and consists of a concave-shaped tailings pile and rubble from the demolition of the mill buildings buried in the former mill area. Contaminated materials at the Maybell processing site include the tailings pile, which has an average depth of 20 feet (ft) (6 meters [m]) and contains 2.8 million cubic yards (yd{sup 3}) (2.1 million cubic meters [m{sup 3}]) of tailings. The former mill processing area is on the north side of the site and contains 20,000 yd{sup 3} (15,000 m{sup 3}) of contaminated demolition debris. Off-pile contamination is present and includes areas adjacent to the tailings pile, as well as contamination dispersed by wind and ...
Three algal bioassay experiments were conducted from March 1992 through September 1993 in an area of Lake Mead that has experienced problems associated with severe nutrient enrichment. The first experiment determined the effects of elevated CO2 (700 ppm) (2xCO2), vs ambient CO2 on the natural algal assemblage without nutrient enrichment. The second experiment determined the effects of 2xCO2 on nutrient enriched bioassays and if nutrients were limiting. The third experiment examined elevated temperatures and 2xCO2. Nested climate models were used to predict changes in water temperatures and thermocline development in Las Vegas Bay. The lake model predicted an increase in mean water temperatures of 1.8 deg under a 2xCO2 scenario. A thermocline definition of 1 deg. C change per 2-m depth was applied to water temperatures developed by a lake model coupled to nested general circulation and regional-scale atmospheric models in ...
Full text: Groundwater in rural agricultural area of South Korea is an important source of drinking and agricultural water. The study area is located in mid-western coastal parts and has fractured bedrock aquifers whose lithologies are composed of Jurassic granites, Paleozoic sedimentary rocks, Precambrian schists and gneiss. Bedrock groundwater was slightly alkaline and had electrical conductivity of 40 to 1570 #mu#S/cm with median values of 322 #mu#S/cm. Water types based on major ions showed that Ca-HCO_3 and Ca-CI types are dominant and Na-HCO_3 and Na-CI types are minor. Intense agricultural activities resulted in significant nitrate contamination of groundwater. 22% and 40% of wells have exceeded drinking water standards (DWS) for bedrock and shallow wells, respectively. In coastal areas, slightly saline groundwater is observed for both bedrock and shallow wells. Groundwater in granitic rocks may ...
This paper deals with the calculations of 3D nuclear heat generation profile in the charcoal filter and subsequently the commencement time of Primary Containment Cleanup (PCC) system of 540MWe Pressurized Heavy Water Reactor (PHWR). Fuel failure is predicted due to overheating of the fuel under loss of Coolant Accident (LOCA) without Emergency Core Cooling System (LOCA without ECCS). Subsequently fission product gasses along with water vapours are released to Reactor Building (RB) atmosphere. Plate-out and water trapping mechanism stabilizes the concentration of significant fission products i.e. radioiodines in about 4 hours before being circulated through charcoal filters of Containment Cleanup system. After cleaning up the RB atmosphere, it is discharged to outside atmosphere through stack. The isotopes of radioiodine emit beta and gamma radiations. Gamma radiations are partly stopped within the ...
Aqueous deoxyhemoglobin solutions (2 mg/ml) were gamma-irradiated by a "6"0Co source in the presence of methanol, ethanol, 1-butanol and t-butanol under N_2O or argon. The effects of the interaction of the particular alcohol radical species with hemoglobin were determined according to the detected spectral alterations in the visible range. The amounts of stable final products in the form of methemoglobin (MetHb) and the sum of hemichromes and cholehemichromes (Hemichr) were estimated in irradiated preparations. For preparations irradiated under N_2O, the radiation yield for MetHb formation was three-fold lower in the presence of ethanol and 1-butanol [G(MetHb) = 0.33[ compared with preparations irradiated in the presence of t-butanol or without alcohol [G(MetHb) = 1.00[. The yield of hemichromes and cholehemichromes in preparations irradiated under N_2O increased in the order: ethanol (G = 0.38), 1-butanol (B = 0.52), t-butanol (G = 0.59), and in the absence of alcohol (G 0.72). The ...
Two neutron emesis experiments were conducted at the Armed Forces Radiobiology Research Institute (AFRRI). In both experiments (described as Phase I and Phase II) the radiation dose required to cause emesis in 50% of subjects (ED50) was determined for both neutron reactor and gamma reactor source radiation. Emesis onset, offset and duration times post-exposure are reported. Neutrons were maximized from the reactor by passing the beam through a 15.25 cm (6 in.) thick lead wall to filter out gamma photons. Gamma rays were maximized by thermalizing neutrons in 30.5 cm (12 in.) of water, then absorbing the thermal neutrons in a gadolinium-cadmium shield. In Phase I, 28 dogs were exposed to radiation: 12 were exposed to gamma photons at the rate of 0.69 Gy/min and 16 were exposed to neutrons at 1.2 Gy/min. In Phase II, 58 dogs in 3 groups were exposed to radiation: 19 were exposed in the gamma group at 0.75 Gy/min, 20 were ...
The liquid-phase synthesis of metal oxide nanoparticles in organic solvents under exclusion of water is nowadays a well-established alternative to aqueous sol-gel chemistry. In this article, we highlight some of the advantages of these routes based on selected examples. The first part reviews some recent developments in the synthesis of ternary metal oxide nanoparticles by surfactant-free nonaqueous sol-gel routes, followed by the discussion of the morphology-controlled synthesis of lanthanum hydroxide nanoparticles, and the presentation of structural peculiarities of manganese oxide nanoparticles with an ordered Mn vacancy superstructure. These examples show that nonaqueous systems, on the one hand, allow the preparation of compositionally complex oxides, and, on the other hand, make use of the organic components (initially present or formed in situ) in the reaction mixture to tailor the morphology. Furthermore, obviously even the crystal ...
The upgraded CDF II detector has collected first data during the initial operation of the Tevatron accelerator in Run II. The simulation of the CDF electromagnetic and hadronic central and upgraded plug (forward) calorimeter is based on the Gflash calorimeter parameterization package used within the GEANT based detector simulation of the Run II CDF detector. We present the results of tuning the central and plug calorimeter response to test beam data.
PRESTO-II is a computer code developed to evaluate possible health effects from shallow land disposal of low level radioactive wastes. PRESTO-PREP is a data preprocessor that has been developed to expedite the formation of input data sets for PRESTO-II. PRESTO-PREP utilizes a library of nuclide and risk-specific data. Given an initial waste inventory, the code creates the radionuclide portion of the associated input data set for PRESTO-II. 2 references.
The purpose of this paper is to describe the embedded computer systems approach taken at Experimental Breeder Reactor II (EBR-II) for non-safety related systems. The hardware and software structures for typical embedded systems are presented The embedded systems development process is described. Three examples are given which illustrate typical embedded computer applications in EBR-II.
Angiotensin II (Ang II) is a key proapoptotic factor in fibrotic tissue diseases. However, the mechanism of Ang-II-induced cell death in endothelial cells has not been previously elucidated....Full Text Available
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The measuring series was performed from November 1991 through April 1992 in seven drinking-water conditioning plants of the Fichtel mountains area in the north-eastern part of Bavaria, and the results revealed as an annual average a dose of about 1 - 40 WLM. The area of interest is a drinking-water catchment area where the ground water and other water resources include waters particularly rich in radon content, which explains this relatively high dose range. This is why comprehensive, specific local and long-term mearurements were carried out in order to assess the occupational radiation dose in the drinking-water conditioning plants, taking as a model site the conditioning plant of the municipal utilities of Hof in Weissenstadt. These more specific measurements were performed by the Technical Inspectorates (TUeV) of Bavaria and Saxony and ...
Using the phasmid vector pSL5, the genomic DNA fragment of T. aquaticus YT1 which contained the thermostable DNA polymerase (Taq-polymerase) gene was cloned. The BglII fragment of this genome locus was subcloned in the BamHI site of the pUC19 plasmid. To optimize the Taq-polymerase gene expression in E. coli cells, the gene was cloned in the correct reading frame regarding the initiation ATG codon of the pPR-TGATG-1 expression vector. The gene expression in this vector was controlled by the phage lambda PR promoter and the temperature-sensitive phage lambda repressor. We used PCR to amplify the short 5'-end fragment of the Taq-polymerase gene coding for the part into which an artificial SacI site was introduced. This site has been used for cloning the PCR product into the pPR-TGATG-1 vector, and the missing gene part was cloned into the KpnI site of the PCR product from the natural cloned gene. The cells of the E. coli ...
From 1946 - 1990, i.e. from shortly after the end of World War II and the rise of the cold war until the German reunification, there had been extensive uranium mining both in Saxony and Thuringia, which formed the southern parts of the former German Democratic Republic. Mining activities started in Saxony in the Ore Mountains (German: Erzgebirge). Mining was conducted by a Soviet, since 1954 by a Soviet- German Incorporated Company named Wismut. It is estimated that about 400,000 persons may have worked in this time period with the company, most of them underground or in uranium ore processing facilities. In the early years, exposure to radiation and dust was particularly high for underground workers. After introduction of several ventilation measures and wet drilling from 1955 onwards, the levels of exposures to the various agents steadily decreased. After German reunification, it was decided by the German Federal Ministry for the Environment ...
Airborne fine particle sulfur data from the summer intensive of Project MOHAVE (Measurement of Haze and Visual Effects) was analyzed by the Receptor Model Applied to Patterns in Space (RMAPS) model, a novel multivariate receptor-oriented model that applies to secondary and primary species. The sulfur data from 17 sites were found to be well predicted by three spatial patterns interpreted as sources along the valley of the Colorado River (including the large Mohave coal-fired power plant, a smaller power plant and the city of Las Vegas); transport from sources located to the southwest; and transport from sources located to the southeast. The model was tested by using parameters derived from the 17-site data set to apportion sulfur for six sites that were not part of the original data set. The sulfur apportionment for these site sites was in agreement with the original apportionment and the physical interpretation of the spatial patterns given above. The effects of ...
This is the 1st revision of the INIS/ETDE Joint Thesaurus. It contains 20 953 valid descriptors and 8 600 forbidden terms. It was last updated in December 2003. The Joint Thesaurus contains the controlled terminology for indexing all information within the subject scope of both INIS (International Nuclear Information System) and ETDE (Energy Technology Data Exchange) information systems. The terminology is intended for use in subject description for input or retrieval of information in those systems. The thesaurus is a terminological control device used in translating from the natural language of documents, indexers or users into a more constrained system language It is also a controlled and dynamic vocabulary of semantically and generically related terms which covers a specific domain of knowledge. The domain of knowledge covered by this Thesaurus includes physics (in particular, plasma physics, atomic and molecular physics, and especially nuclear and high-energy physics), chemistry, ...
Early in the Cold War, the United States adopted a policy of ''extended nuclear deterrence'' to protect its allies by threatening a nuclear strike against any state that attacks these allies. This threat can (in principle) be used to try to deter an enemy attack using conventional weapons or one using nuclear, chemical, or biological weapons. The credibility of a nuclear threat has long been subject to debate and is dependent on many complex geopolitical factors, not the least of which is the military capabilities of the opposing sides. The ending of the Cold War has led to a significant decrease in the number of strategic nuclear weapons deployed by the United States and Russia. START II, which was recently ratified by the Russian Duma, will (if implemented) reduce the number deployed strategic nuclear weapons on each side to 3500, compared to a level of over 11,000 at the end of the Cold War in 1991. The tentative limit ...
This report summarizes the results of research conducted during the sixteen month continuation of a program to develop rechargeable zinc-air batteries for electric vehicles. The zinc-air technology under development incorporates a metal foam substrate for the zinc electrode, with flow of electrolyte through the foam during battery operation. In this ``soluble`` zinc electrode the zincate discharge product dissolves completely in the electrolyte stream. Cycle testing at Lawrence Berkeley Laboratory, where the electrode was invented, and at MATSI showed that this approach avoids the zinc electrode shape change phenomenon. Further, electrolyte flow has been shown to be necessary to achieve significant cycle life (> 25 cycles) in this open system. Without it, water loss through the oxygen electrode results in high-resistance failure of the cell. The Phase I program, which focused entirely on the zinc electrode, elucidated the conditions necessary to increase ...
This report summarizes the results of research conducted during the sixteen month continuation of a program to develop rechargeable zinc-air batteries for electric vehicles. The zinc-air technology under development incorporates a metal foam substrate for the zinc electrode, with flow of electrolyte through the foam during battery operation. In this soluble'' zinc electrode the zincate discharge product dissolves completely in the electrolyte stream. Cycle testing at Lawrence Berkeley Laboratory, where the electrode was invented, and at MATSI showed that this approach avoids the zinc electrode shape change phenomenon. Further, electrolyte flow has been shown to be necessary to achieve significant cycle life (> 25 cycles) in this open system. Without it, water loss through the oxygen electrode results in high-resistance failure of the cell. The Phase I program, which focused entirely on the zinc electrode, elucidated the conditions necessary to ...
The main objective of the present study is twofold: (i) to analyze thermal loads of the geothermally and passively heated solar greenhouses; and (ii) to investigate wind energy utilization in greenhouse heating which is modeled as a hybrid solar assisted geothermal heat pump and a small wind turbine system which is separately installed in the Solar Energy Institute of Ege University, Izmir, Turkey. The study shows 3.13% of the total yearly electricity energy consumption of the modeled system (3568 kWh) or 12.53% of the total yearly electricity energy consumptions of secondary water pumping, brine pumping, and fan coil (892 kWh) can be met by using small wind turbine system (SWTS) theoretically. According to this result, modeled passive solar pre heating technique and combined with geothermal heat pump system (GHPS) and SWTS can be economically preferable to the conventional space heating/cooling systems used in agricultural and residential ...
An initial draft of an environmental and natural resource strategy for the Asia Near/East region in the 1990's is presented. The report contains five chapters. Chapter I provides an analytic framework that links natural resources, their extent, quality, and management with economic growth in the region. Chapter II contains a more detailed description and analysis of key resource problems that are restricting economic growth and have a severe negative impact on standard of living and quality of life. The most serious of these are soil and water degradation; destruction of natural forests, wetlands, and coastal zones; inefficient energy use and industrial pollution; and lack of environmental services. Chapters III and IV describe 20 specific opportunities for working toward sustainable economic growth through protection and enhancement of the natural resource base. Opportunities for action were chosen on the basis of the urgency and ...
The main objectives of this study was to determine the bone density for the purposes of i) determining the age of peak bone mass in each study group and ii) quantifying the differences in bone density as functions of age and sex. The results of estimating the age dependence of mineral density for the femoral neck, spine and total body of healthy women and men using DEXA are given. The age changes in concentrations of major minerals and electrolytes found for compact and trabecular bones of healthy male femoral neck with regard for the wet and dry tissue calculations are represented. Information about femoral neck water content depending on the age of healthy men is tabulated. The number of performed observations and analyses is evidently insufficient to make any final decision, however some preliminary conclusions can be drawn. In accordance with DEXA results, BMD maximum for the femoral neck, spine and total body of healthy women is found for ...
The RELAP5 code has been developed for best-estimate transient simulation of light water reactor coolant systems during postulated accidents. The code models the coupled behavior of the reactor coolant system and the core for loss-of-coolant accidents and operational transients such as anticipated transient without scram, loss of offsite power, loss of feedwater, and loss of flow. A generic modeling approach is used that permits simulating a variety of thermal hydraulic systems. Control system and secondary system components are included to permit modeling of plant controls, turbines, condensers, and secondary feedwater systems. RELAP5/MOD3 code documentation is divided into seven volumes: Volume I presents modeling theory and associated numerical schemes; Volume II details instructions for code application and input data preparation; Volume III presents the results of developmental assessment cases that demonstrate and verify the models used ...
Results from three separate experiments that have some relevance to bound residues are reported. In the first, "1"4C-labelled paraquat was lost when applied to soil in the field, about 26% of the radioactivity disappearing in 15 months, whereas in laboratory incubation studies there was no loss of radioactivity in one year. Two possible explanations are (i) that there was photolytic decomposition in the field, (ii) the preparation of the soil for the laboratory study upset the microbial ecology of the soil to the detriment of organisms that can degrade paraquat. In an experiment with "1"4C-labelled isoproturon, there was an indication that there was slightly more "1"4C in the unextractable humin fraction in soil in which wheat plants were grown than in bare soil. Work in the UK, Federal Republic of Germany and in Switzerland has shown that the phytotoxicity of residues of atrazine, carbetamide, chloridazone, propyzamide, simazine, lenacil, monolinuron, linuron, ...
Argentina has two operating PHWR nuclear power plants. Atucha I NPP is a pressure vessel type heavy water reactor of 360 MW e with 25 years of operation and Embalse NPP is a pressure tube type CANDU-600 reactor of 640 MW e. Atucha II, a third plant of 600 MW e of the pressure vessel type similar to Atucha I, is being constructed. NASA (Nucleoelectrica Argentina S.A.) currently operates both nuclear power plants. The National Atomic Energy Commission (Comision Nacional de Energia Atomica - CNEA) provides operational support to the plants, including research and development assistance, and actual technical services and maintenance work in different areas. The Chemistry Department, formerly the Reactor Chemistry Department has carried out project and support activities to the plants during the past 20 years. The aim of this work is to describe the present organization and the activities in reactor chemistry of the Chemistry Department. In ...
Current light water reactor (LWR) steam generators have been affected by a variety of corrosion and mechanical damage degradation mechanisms. Included are wear caused by tube vibration, intergranular corrosion, pitting, and thinning or wastage of the steam generator tubing and accelerated corrosion of carbon steel supports (denting). The Electric Power Research Institute (EPRI) and the Steam Generator Owners Groups (I, II) have sponsored laboratory and field studies to provide ameliorative actions for the majority of the damage forms experienced to date. Some of the current corrosion mechanisms are aggravated or caused by unique materials choices or materials interactions. New materials have been proposed and at least partially qualified for use in replacement model steam generators, including an advanced LWR design. In so far as possible, the materials choices for the advanced LWR steam generator avoid the corrosion pitfalls seemingly inherent ...
A laboratory differential simulation method is used for the design of carbonization columns at coal-tar processing in which phenols are regenerated from phenolate solution by carbon dioxide absorption. The design method is based on integration of local absorption rates of carbon dioxide along the column. The local absorption rates into industrial phenolate mixture are measured in a laboratory model contactor for various compositions of the gas and liquid phases under the conditions that ensure the absorption rates in the laboratory absorber simulate the local rates in the industrial column. On the bases of the calculations, two-step carbonization columns were designed for 30000 t/year of the phenolate solution treatment by carbon dioxide. The absorption proceeds at higher pressure of 500 kPa and temperatures from 50 to 65 C, pure carbon dioxide is used and toluene is added. These conditions have the following favourable effects: (I) significant size reduction of the columns, ...
Flow structures and heat transfer at the liquid-liquid interface are investigated experimentally and analytically in the entrance region of a liquid metal-water stratified flow in a horizontal rectangular channel. The two-equation model and the mixing length mode, including a damping turbulent region near the interface, are used to obtain analytical results for pressure drop, position of the interface, and heat transmission coefficients across the interface. Analytical results are compared with experimental results. Conclusions are presented and include the following: (1) vertical position of the interface increases or decreases along the stream according to the fluid flow rate of both fluids, and then approaches a constant value in the fully developed region; (2) pressure drop increases along the stream from the minimum value at the inlet; and (3) heat transmission coefficients across the interface decrease in the entrance region to a minimum value and then ...
Four species of nanocomposites organized by hydroxyapatite (HAp), hyaluronic acid (HyA), chondroitin sulfate (ChS) and type II collagen (Col), i.e. HAp/HyA, HAp/ChS, HAp/HyA/Col and HAp/ChS/Col composites, were synthesized by coprecipitation methods. The composites could retain lots of water: 40%, 32%, 42% and 58% for the HAp/HyA, HAp/ChS, HAp/HyA/Col and HAp/ChS/Col composites, respectively. Transmission electron microscopy observations revealed that the HAp/HyA and HAp/ChS composites consisted of island-like aggregations whose sizes were 300 nm in length and 30 nm in width, and 150 nm in length and 30 nm in width, respectively. In the aggregations, there were many HAp nanocrystals of 20 nm in length, and their c-axes were aligned along the respective polymer molecules through a self-organization process. Animal tests showed that chondrocyte-like cells penetrated into the HAp/ChS/Col composites 4 weeks after implantation. It was shown that the ...
To make the doubly labelled water method for determining energy expenditure more applicable in a free-living population, collection of a single daily urine or breath sample would have advantages compared to a 24-hr urine collection. Coward et al. reported the use of a single daily urine sample. In the previously described study, a single urine collection and a fasting morning breath sample were collected from four men during two 21-day periods (fall, F, spring, S) while maintaining their body wts. on controlled diets (20% calories from protein, 40% from fat, 60% from CHO [F]; 20% protein, 20% fat, 60% CHO [S]). Urine and breath samples were analyzed to determine disappearance rates of D and "1"8O for up to 21 days. Values were compared with metabolizable energy intake levels (EI), with or without corrections for estimated changes in body composition assessed by several methods. Preliminary evaluations suggest that the single daily urine sample values may ...
A novel method for the determination of metoclopramide (MCP) using electrogenerated chemiluminescence (ECL) is presented. A tris(2,2prime-bipyridyl)dichlororuthenium(II) (Ru(bpy)32+)-doped silica (RuDS) nanoparticle/perfluoinated ion-exchange resin (Nafion) with nanocomposite membrane modified glassy carbon electrode (GCE) is used. The Ru(bpy)32+ encapsulation interior of the silica nanoparticle maintains its electrochemical activities and also reduces Ru(bpy)32+ leaching from the silica matrix when immersed in water due to the electrostatic interaction. The analytical performance of this ECL sensor for MCP is shown in detail. Under optimal experimental conditions, it has good linearity in the concentration range from 2x10-8mol/L to 1x10-5mol/L (R=0.9989) with a detection limit of 7x10-9mo...
The release rate of a nuclide from a reactor or a radioactive waste disposal plant at the accident is not steady, but varies with time. The various parameters of a nuclide migration into environment vary also day after day, or with the seasons. In such cases, dynamic behavior of the nuclide in the environment must be taken into consideration. It is difficult for a mathematical model to involve all of mechanisms for the nuclide migration. The environment for evaluation of doses are usually divided into some of compartments in which a nuclide concentration is uniform. Time variations of the nuclide concentration in the compartment are described in simultaneous differential equations. The nuclide concentration can be solved as a time function, and the radiation doses, therefore, can be estimated as a time function. Generic analysis code for dynamic compartment model (GACOM) is developed for the nuclide migration and the evaluation of doses in terrestrial biosphere. The code contains many ...
Tritium, a beta emitting gas at room temperature causes a biological hazard in the locations where it is present beyond acceptable limits. The hazard can be due to inhalation, and absorption by skin. Hence is the necessity of Tritium monitoring instruments/systems for ensuring safety in the PHWRs and the nuclear research plants and laboratories. It is desirable that the instruments address satisfactorily to certain factors like the following: (i) Wide range of Tritium concentrations - 1 to 104 DAC ( Derived Air Concentration) (ii) On-line monitoring features (iii) Small response time (On-spot instantaneous measurements) (iv) Portability (v) Mitigation of memory effects. This paper presents an overview of the Online Tritium in Air Monitoring Systems manufactured by ECIL for Pressurised Heavy Water Reactors at Tarapur, Kaiga, and Rawatbhata. Significant aspects of design, function, testing, limitations of the detectors and electronics and the ...
Discussions were given on the characteristics of a diesel engine to emit unburned hydrocarbon (HC) created in a long idling operation. The engine tested in the experiment is a direct injection diesel engine with six water-cooled were investigated varying the jet hole diameter and length of the jet nozzle. In the initial operation period, the HC showed high values. This is thought because part of the injected fuel has deposited on the wall because of low combustion chamber wall temperature, and the fuel deposit that did not evaporate during combustion evaporated during expansion process and emitted unburned. The head was dismantled to investigate the carbon flowers deposited on the nozzle and the relationship between the carbon and the HC deposited on the head face and the combustion chamber wall. It was clarified that the HC increase was phenomenal compared with that of the carbon. This is because the injected fuel was adsorbed into the carbon, ...
This invention relates with a pot-type catalyst carrier which excels as a catalyst carrier when such heavy oils as ordinary pressure distillation residue, oil sand oil, and shale oil are decomposed or treated by hydrogenation. The conventional pot-type carrier is produced by dropping a small drop of a slurry (containing a catalyst component) onto a particle bed and drying it. But the demerit is a large particle size and less catalyst activity or strength. In this invention, a mixture of such carrier components as allophane, red mud, bauxite and latellite, etc.. 60 - 80 weight parts. and a binder 20 - 40 weight parts is added with water to form a slurry of 10 - 30 weight% solid concentration. Slurry is wet-crushed to make the average particle size 0.6 - 2.0 micron, then spray-dried and burned to obtain a pot-type catalyst carrier with average particle size 30 - 200 micron and abrasion index below 10. This catalyst showed ...
Two of the US Department of Energy's (DOE) nuclear waste management-related goals are to ensure that waste management is not an obstacle to the further development of light-water reactors and the closure of the nuclear fuel cycle and to fulfill its institutional responsibility for providing safe storage and disposal of existing and future nuclear wastes. As part of its approach to achieving these goals, the Office of Remedial Action and Waste Technology of DOE established what is now called the Nuclear Waste Treatment Program (NWTP) at the Pacific Northwest Laboratory during the second half of FY 1982. To support DOE's attainment of its goals, the NWTP is to provide technology necessary for the design and operation of nuclear waste treatment facilities by commercial enterprises as part of a licensed waste management system and problem-specific treatment approaches, waste form and treatment process ...
New physical objects, ispalators based on free soap films, exhibit persistent flows of the soap solution in open and closed volumes in air with additions of gases of the C_8F_1_8 type (p = 20 Torr) at temperature drops on the films of the order of tenths and hundredths of kelvin. The flows move continuously at a velocity of 5 - 20 cm s"-"1. It is found that the parts of an inclined ispalator film show anomalous behaviour upon heating: their weight increases and they move downward over the film, whereas the unheated parts of the film move upward. Continuous radial vortex flows accompanied by the formation and washing of the regions of a thin black film are observed on circular films in closed volumes upon their uniform external cooling by evaporating water for 5 - 10 hours. The rapid flows make film ispalators the efficient heat carriers, which operate at small temperature drops (tenths and hundredths of kelvin) and surpass ...
The presentation summarises the highlights of experimental results obtained for VVER type horizontal steam generator heat transfer, primary side flow pattern, and mixing in the hot collector during secondary side boil-off with primary at single-phase natural circulation. The experiments were performed using the PACTEL facility with Large Diameter (LD) steam generator models, with collector instrumentation designed specifically for these tests. The key findings are as follows: (1) the primary to secondary heat transfer degrades as the secondary water inventory is depleted, following closely the wetted tube area; (2) a circulatory flow pattern exists in the tube bundle, resulting in reversed flow (from cold to the hot collector) in the lower part of the tube bundle, and continuous flow through the upper part, including the tubes that have already dried out; and (3) mixing of the hot leg flow entering the hot collector and ...
The analyses were carried out using real climate data for the years 1987 and 1989. The course of the indoor climate for year-round free ventilation with a constant flow volume is discussed. Numerous diagrams inform on ambient temperature, water vapour content, the condition of space air, and temperature drops below dew point. For the event of heating of the central part of the church, space air condition, the annual air humidification requirement, and the temperature field in this part of the building are described. (MSK) [Deutsch] Die Untersuchungen wurden mit aktuellen Klimadaten fuer die Jahre 1987 und 1989 durchgefuehrt. Der Verlauf des Raumklimas bei ganzjaehrig freier Klimatisierung mit konstantem Foerderstrom wird erlaeutert. Dabei wird die Raumlufttemperatur, der Wasserdampfgehalt, der Raumluftzustand sowie die Taupunktunterschreitung in zahlreichen Diagrammen aufgezeigt. Weiter werden fuer den Fall der Beheizung ...
This paper described the basic design of Alpha Aqueous Waste Treatment Process in NUCEF. Since various experiments using the TRU (transuranium) elements are carried out in NUCEF, wastes containing TRU elements arise. The liquid wastes in NUCEF are categorized into three types. Decontamination and volume reduction of the liquid waste mainly of recovery water from acid recovery process which has lowest radioactive concentration is the most important task, because the arising rate of the waste is large. The major function of the Alpha Aqueous Waste Treatment Process is to decontaminate the radioactive concentration below the level which is allowed to discharge into sea. Prior the process design of this facility, the followings are evaluated:property and arising rate of the liquid waste, room space to install and licensing condition. Considering varieties of liquid wastes and their large volume, the very high decontamination factor was proposed by a process of multiple ...
In summary, a scaling analysis of a water-cooled Reactor Cavity Cooling System (RCCS) system was performed based on generic information on the RCCS design of PBMR. The analysis demonstrates that the water-cooled RCCS can be simulated at the ANL NSTF facility at a prototypic scale in the lateral direction and about half scale in the vertical direction. Because, by necessity, the scaling is based on a number of approximations, and because no analytical information is available on the performance of a reference water-cooled RCCS, the scaling analysis presented here needs to be 'validated' by analysis of the steady state and transient performance of a reference water-cooled RCCS design. The analysis of the RCCS performance by CFD and system codes presents a number of challenges including: strong 3-D effects in the cavity and the RCCS tubes; simulation of turbulence in flows characterized by natural ...
Carbalkoxylation of vinyl electrophiles was investigated using platinum complexes. This reaction occurs in two steps: (a) carbonyl insertion of {sigma}-vinyl Pt(II) halides and (b) alcoholysis of vinylic acyl Pt(II) complexes. Alcoholysis of vinylic acyl Pt(II) triflate complexes is investigated kinetically. Vinylic acyl Pt(II) complexes were isolated and characterized. 51 refs., 5 figs., 6 tabs.
In this study, the effects of channel surface wettability, cross-sectional geometry and orientation on the two-phase flow in parallel gas channels of proton exchange membrane fuel cells (PEMFCs) are investigated. Ex situ experiments were conducted in flow channels with three different surface wettability (hydrophilically coated, uncoated, and hydrophobically coated), three cross-sectional geometries (rectangular, sinusoidal and trapezoidal), and two orientations (vertical and horizontal). Flow pattern map, individual channel flow variation due to maldistribution, pressure drop and flow visualization images were used to analyze the two-phase flow characteristics. It is found that hydrophilically coated gas channels are advantageous over uncoated or slightly hydrophobic channels regarding un...
The Kemp's Ridley sea turtle, Lepidochelys kempi, is an endangered species. The National Marine Fisheries Service's Head Start program is part of an international operation to save the turtles from extinction. Under the Head Start program, eggs from the Ridley's only known wild nesting beach at Rancho Nuevo in Mexico are transported to Padre Island on the Texas coast to be hatched. The head start enables the turtles to develop a survival advantage. The principal objective was to develop baseline waste-characterization data required to design a waste-water treatment scheme for the Galveston Head Start facility. As a secondary objective, preliminary testing of some filtration components was undertaken to determine which units were most appropriate for inclusion in a wastewater treatment scheme.
The extent to which a novel wash-off process using polyamide beads removed five different types of dye from three different types of fibre was similar to that achieved using conventional aftertreatments. Whilst bead wash-off and the conventional aftertreatments were of similar duration and temperature, conventional aftertreatment employed a 10:1 or 20:1 liquor ratio whereas bead wash-off used a < 1:1 liquor ratio. As vagrant dye was adsorbed onto the bead material during wash-off, the low amount of wastewater generated contained little residual dye, thereby offering the potential of reduced environmental and cost benefits. Bead wash-off did not impair the fastness of two non-metallised acid dyes on nylon 6,6 to washing at 60 ?C.
Concepts involving combined gas-turbine/steam-turbine power-generation plants, in which the fuel gas for the gas turbine is produced via the gasification of coal, are now extremely advanced. This technology already permits efficiencies of around 50% current development targets view 65% as achievable. In conventional technology, efficiencies are tied to conditions, such as air and cooling-water temperatures, at the particular location. In combined-cycle power plants, the properties of the fuel coal also play an important part. There are, in face, coals which can be more advantageously used in a combined-cycle power plant than in a conventional one. These differences, combined with advantageous concepts for coal-fired combined-cycle power-generating plants, are presented and analyzed. Particular attention is devoted to individual losses occurring at coal conversion, thermodynamic cycles, integration of processes and internal consumptions. 14 ...
This paper reports on current dual fuel engines utilizing standard mechanical (Bosch type) fuel injection systems set to 5--6 percent pilot delivery that do not appear capable of reducing NO{sub x} emissions much below the current minimum of 4 g/bhp-h without incurring substantial penalties in efficiency and operability. A prototype Electronic Pilot Fuel Injector (EPFI) was designed that overcomes the shortcomings of the mechanical injection system, consistently delivering 3 percent or less pilot at pressures as high as 20,000 psi. The EPFI was installed and tested in one cylinder of a standard production dual fuel engine operating at a waste water treatment facility.
Preliminary plans for the 90 to 100-MW coal-fired combined cycle plant due to be built by a team headed by Southern California Edison and Texaco in the mid-1980s are reviewed. The basic operating goals call for having a gasifier with a 1,000 ton coal capacity per day feeding a 70-MW turbine which then provides waste heat to run a 30-MW steam turbine. Texaco will have responsibility for the gasifier part of the facility with the turbine-generator vendor charged with providing both gas and steam turbine equipment. If the 100-MW demonstration plant achieves 32 to 33% design efficiency, then a commercial plant with expansion turbines and steam reheat should hit 38% and require 20 to 30% less water than a conventional coal fired plant.
Adding capacity to coal-fired plants in small increments of an overall integrated program may be the solution to the 10-year lead time required for the construction of a new plant. A preliminary study evaluates the technical and economic feasibility of a modular natural gas and coal-fired combined-cycle power plant which can be installed in three distinct phases. The plant sizes are suitable for large industrial and utility applications. The Modular Block Power Plant (MBPP) concept offers the advantages of phase construction, lower capital cost, lower cost electricity, lower air emissions, lower water requirements, and reduced solid waste discharge. Other advantages include part load availability, reduced coal inventory requirements, and easier plant siting. 11 figures, 4 tables.
The aquatic monitoring program consists of onsite monitoring of surface runoff, monitoring of point source discharges identified in the NPDES permit, and limited instream biological monitoring. The program is tied to a feedback mechanism for implementing corrective action before significant adverse impacts occur in the Holston River. This report evaluates the aquatic monitoring program for the second year (October 19, 1978 through October 18, 1979) of construction as required by the NPDES permit, Part III, Section I. Included in this report are data from peripheral runoff monitoring, selected heavy rainfall sampling, ground water monitoring, instream aquatic macroinvertebrate monitoring, and aquatic macrophyte monitoring.
The concentrations of iron, chromium, zinc, and aluminum were measured by atomic absorption spectroscopy in the lipid-soluble fractions of tar from the process stream of an experimental coal gasifier as part of large study on the health risks of coal gasification. Lipid solubility was inferred from octanol/water-partitioning and benzene-solubility tests. The properties of the lipid-soluble metals were compared to reference compounds by Sephadex LH-20 chromatography. The ability of the lipid-soluble metals to remain lipid soluble after treatment with acid and base was also tested. Lipid-soluble iron, chromium, zinc, and aluminum were present at 360, 12, 3, and 1 ppM, respectively, in the gasifier coal tar. The presence of these metals in lipid-soluble form may have important consequences relative to the potential toxicity of the tar if persons are exposed to it.
Landslides on ancient embankments, burial mounds of Imashiro-zuka and Nishimotome-zuka, induced by historical earthquakes related to the tectonic movement of active fault systems located between northern Osaka and Kobe, are discussed. The geological conditions of the foundation of the mounds, the lithology, stiffness, and the position of the mound relative to the fault systems, contributed to the collapse of the mounds. Obvious interior structures of landslides revealed the inherent deformation process, and provided significant insight into landslide mechanisms. Rapid increasing pore water pressure was necessary to facilitate sliding along the almost horizontal slip surfaces developed in the main part of the landslide bodies on the Imashiro-zuka mound. Liquefaction analysis using both the ...
Utilisation of geothermal energy may soon become an important factor in power supply in Germany. The contribution discusses the utilisation of hydrothermal low-pressure systems, the geological boundary conditions, the technical design of the thermal water cycle, and the current status of the hot dry rock technology. [German] Die Nutzung der Energie ausd Erdwaerme kann in naher Zukunft eine wichtige Rolle in der Energieversorgung Deutschlands spielen. Der vorliegende Artikel gibt einen Ueberblick ueber die Nutzung hydrothermaler Niederdrucksysteme, die geologischen Rahmenbedingungen, den technischen Aufbau des Thermalwasserkreislaufes sowie zum aktuellen Stand des Hot Dry Rock Verfahrens.
The aim of this work is the study of the heat transfer and of thermal behaviour of the HF (high frequency) components (in fact capacitors) of the ITER-proto-2005-FCI antenna. Preliminary results carried out with the Castem software show that it is possible to cool the hottest part of the antenna efficiently. A water flow (1 bar, 25 Celsius degrees) or an helium flow (10 bars, 50 Celsius degrees) permit to limit the maximal value of the temperature to 270 Celsius degrees. A second software Ansys has allowed the author to simulate capacitors with more complicated shapes. (A.C.)
Electrical penetration assemblies mounted on the containment wall are used to carry electrical power and signals from the equipment inside this containment (e.g. recirculation pumps, control rod position indications etc.) Todays BWR nuclear power plants apply epoxy resin sealed electric penetration. Contrariwise, the epoxy resin (organic sealant) was replaced with sodium barium glass (inorganic) by way of trial in search for a quality sealant. The glass sealant has been proved to have high temperature airtightness at 300 degC above from an evaluation test involving full-scale model parts. Environmental tests were conducted continuously as to heat cycle, vibration and LOCA etc. the specimens (module) of five types. They were made certain of conformity to the design requirements for boiling water operation. (author).
The Department of Energy (DOE) has contracted with Asea Brown Boveri-Combustion Engineering (ABB-CE) to provide information on the capability of ABB-CE`s System 80 + Advanced Light Water Reactor (ALWR) to transform, through reactor burnup, 100 metric tonnes (MT) of weapons grade plutonium (Pu) into a form which is not readily useable in weapons. This information is being developed as part of DOE`s Plutonium Disposition Study, initiated by DOE in response to Congressional action. This document, Volume 1, presents a technical description of the various elements of the System 80 + Standard Plant Design upon which the Plutonium Disposition Study was based. The System 80 + Standard Design is fully developed and directly suited to meeting the mission objectives for plutonium disposal. The bass U0{sub 2} plant design is discussed here.
On Oct. 24, 2005, Hurricane Wilma, a category 5 storm, made landfall at Cape Romano, Florida. Three days later, the Center for Robot-Assisted Search and Rescue at the University of South Florida deployed an iSENYS helicopter and a prototype unmanned water surface vehicle, AEOS-1, to survey damage in parts of Marco Island, 14 km from landfall. The effort was the first known use of unmanned sea surface vehicles (USVs) for emergency response and established their suitability for the recovery phase of disaster management by detecting damage to seawalls and piers, locating submerged debris (moorings and handrails), and determining safe lanes for sea navigation. It provides a preliminary domain theory of postdisaster port and littoral inspection with unmanned vehicles for use by the human-robot ...
Japanese companies have developed suitable cleansing technologies and export their know-how. Some original technologies are developed today, like: in-situ chemical oxidation, iron confinement, hot-soil process, low-temperature catalytic decomposition or dechlorination of dioxins. However, some pollutions are still poorly considered (nitrates) or badly mastered (dioxins). This situation is partly due to late legal decisions and to limited pollution abatement measures. Japan is also very active in bio-cleansing research, and this, despite the lack of dialogue and directives at the national level. Several research programs with important funds have started since 1995. However, Japan is still at the preliminary stage in open-field applications of cleansing methods. (J.S.)
The possible long term effects of chronic radiation exposure have been studied. Rats were given tritiated drinking water (3#mu#Ci/ml) before pregnancy, during pregnancy and threafter, continuously through 5 generations. The brains were studied at 30 and 120 days postnatally. Significant decreases in weight, DNA and protein contents of specific parts of the brain were found, the most pronounced decreases being in the diencephalon. The decreases in protein content were more pronounced than the decreases in DNA content; the decreases were also more pronounced at 30 days than at 120 days, and more pronounced in the fifth generation than in previous generations. An attempt was made to explain these complex phenomena on the basis of known periods of proliferation of various brain cells, damage to mothers themselves in each generation, and damage and repair of nucleic acids caused by radioactivity.
A one-dimensional, steady-state, two-phase direct methanol fuel cell (DMFC) model is developed to precisely investigate complex physiochemical phenomena inside DMFCs. In this model, two-phase species transport through the porous components of a DMFC is formulated based on Maxwell-Stefan multi-component diffusion equations, while capillary-induced liquid flow in the porous media is described by Darcy's equation. In addition, the model fully accounts for water and methanol crossover through the membrane, which is driven by the effects of electro-osmotic drag, diffusion, and the hydraulic pressure gradient. The developed model is validated against readily available experimental data in the literature. Then, a parametric study is carried out to investigate the effects of the operating temperat...
Two major developments have given impetus to wider adoption of variable-speed turbine/generators in hydroelectric plants, both essentially environmental: (1) the need for stream-bed stability below river dams, and (2) the need to minimize fish damage. Also, the need to stabilize pumped-storage and generating efficiencies to match extreme changes in head levels has been a driving force. Variable-speed operation in hydro applications is relatively new to North America. In other parts of the world, it has been used in pumped-storage plants since 1971. In the US, and increasing potential exists for variable-speed hydro, considering the 30 pumped-storage plants already in operation and several river plants struggling with high head fluctuations--including four at stations operated by the Bonneville Power Administration. Several modifications to hydro-plant hardware and operating procedures are actively being considered at Bonneville--all of them practical but costly. ...
The US Nuclear Regulatory Commission is currently considering revision of rule 10 CFR Part 20, which covers disposal of solid wastes containing minimal radioactivity. In support of these revised rules, we have evaluated the consequences of disposing of four waste streams at four types of disposal areas located in three different geographic regions. Consequences are expressed in terms of human exposures and associated health effects. Each geographic region has its own climate and geology. Example waste streams, waste disposal methods, and geographic regions chosen for this study are clearly specified. Monetary consequences of minimal activity waste disposal are briefly discussed. The PRESTO methodology was used to evaluate radionuclide transport and health effects. This methodology was developed to assess radiological impacts to a static local population for a 1000-year period following disposal. Pathways and processes of transit from the trench to exposed ...
Complete text of publication follows. At the Geomagnetic Institute, in the Laboratory for paleomagnetism and archeomagnetism research and at the Geomagnetic Observatory, Grocka (GCK) during the period from November 2004 to February 2008 the researchers carried out experimental magnetic measurements of the total-intensity gradient of the magnetic field vector (changes in the total magnetisation vector) of various biomaterials. Measurements of the gradient total intensity of the magnetic field vector were carried out by GSM-19 magnetometers of high accuracy and recording resolution (accuracy: #DELTA#F=0.1 nT; sampling rate: 1-5 per second). During these experimental biomagnetic measurements samples of water, tissue, blood, cotton, wool, pitch and magnetite-powder were used. In this study, the part of the biomagnetic measurement results relate to the water, blood and tissue. The results of the measurements of gradient ...
The deep waterparts of the Moere and Southern Voering Basins are large frontier areas, which are considered to contain significant undiscovered hydrocarbon resources, within Cretaceous and Paleogene reservoirs. PGS Reservoir AS have evaluated the Cretaceous and Paleogene successions of the shallow and deep water areas offshore Mid-Norway using high-resolution sequence stratigraphic techniques. The successions have been subdivided into about 20 stratigraphic sequences. The results are: (1) A more acurate and higher resolution stratigraphy, (2) Greater constraints on basin palaeoenvironmental and palaeogeographic reconstructions, (4) Fully integrated sandstone fairway models, with increased ability to reservoir and seal quality and continuity, (5) In addition to several obvious giant domal traps, subtler yet significant structural and stratigraphic leads and prospects can be identified, (6) The timing, volume and phase of ...
Husky Oil Operations Ltd (Husky) is considering the development of the South White Rose Expansion (SWRX) area, located approximately 4 km south of the current Southern Glory Hole (SGH) in approximately 120 m of water. Within the new glory hole, one new drill centre will be constructed with wells tied back and into the SGH manifolds. The SWRX drill centre will comprise three horizontal production wells and two horizontal water injection wells with expansion capacity for eight wells. Husky is intending to submit a Development Plan Amendment to the Canada-Newfoundland and Labrador Offshore Petroleum Board (C-NLOPB) as part of the development. This document presented the results of a study that assessed the potential impact of the new development on existing White Rose safety studies. The study reviewed existing safety studies that were developed for the White Rose project to determine the potential impact of the new SWRX ...
The 3001 Storage Canal is located under portions of Buildings 3001 and 3019 at Oak Ridge National Laboratory (ORNL) and has a capacity of approximately 62,000 gallons of water. The term canal has historically been used to identify this structure, however, the canal is an in-ground reinforced concrete structure satisfying the regulatory definition of a tank. From 1943 through 1963, the canal in Building 3001 was designed to be an integral part of the system for handling irradiated fuel from the Oak Ridge Graphite Reactor. Because one of the main initial purposes of the reactor was to produce plutonium for the chemical processing pilot plant in Building 3019, the canal was designed to be the connecting link between the reactor and the pilot plant. During the war years, natural uranium slugs were irradiated in the reactor and then pushed out of the graphite matrix into the system of diversion plates and chutes which directed the fuel into the deep ...
The results of the liquid CO/sub 2/ injection pilots in the Granny's Creek field permit the following findings and conclusions: The pilots demonstrated that CO/sub 2/ can be used for tertiary recovery, and it will displace oil and form a high oil-cut bank in a watered-out reservoir. Oil production response in every case was almost immediate; and after CO/sub 2/ injection was stopped and water injection was started, the oil production declined rapidly over a period of 2-3 months to very low rates. Confinement of CO/sub 2/ to the pilot area was the principal problem. CO/sub 2/ spread rapidly to virtually all of the southern part of the reservoir of about 350 acres. Except for weather, there were practically no operational problems. Corrosion from the CO/sub 2/ was not observed. Pilot results did not demonstrate economic feasibility. The ratio of CO/sub 2/ to additional oil of 19,357 cu ft (14.696 psia and 60/sup 0/ ...
This paper discusses the potential for geothermal energy use in the central part of Southern Poland, such as the availability of thermal aquifers and the techniques for putting the latter to practical use. The geological and geothermal features of the region are presented within the context of the existence of aquifers containing geothermal resources that could be used in space heating. Also discussed are the three main geological units where thermal waters are known to exist: the Carpathians, the Miechow Trough, and the Silesian-Cracow Monocline. Particularly favourable hydrogeological conditions exist in the Inner Carpathians, in the Podhale Trough, where there is already one geothermal company using geothermal energy, Geotermia Podhalanska S.A. Equally interesting from the geothermal point of view are the areas north of the Cracow-Tarnow line, where, in Mesozoic aquifers, water temperatures range from 20 to 60 {sup o}C. ...
The Crown of the Continent is one of the premiere ecosystems in North America containing Waterton-Glacier International Peace Park, the Bob Marshall-Great Bear-Scapegoat Wilderness Complex in Montana, various Provincial Parks in British Columbia and Alberta, several national and state forest lands in the USA, and Crown Lands in Canada. The region is also the headwater source for three of the continent's great rivers: Columbia, Missouri and Saskatchewan that flow to the Pacific, Atlantic and Arctic Oceans, respectively. While the region has many remarkably pristine headwater streams and receiving rivers, there are many pending threats to water quality and quantity. One of the most urgent threats comes from the coal and gas fields in the northern part of the Crown of the Continent, where coal deposits are proposed for mountain-top removal and open-pit mining operations. This will have significant effects on the ...
Diffusion magnetic resonance imaging (MRI) has become an important tool in the radiologic diagnosis of diseases of the brain as it measures molecular motion of water that characterizes the microstructure of tissues. Its most important clinical use to date is the early detection of cerebral ischemia by revealing the ischemic injury shortly after vessel occlusion and simultaneously providing therapy-relevant information on the tissue at risk. Furthermore, diffusion MRI is diagnostically promising in other diseases of the brain and is thus increasingly becoming part of routine clinical protocols in the diagnosis of tumors, inflammation, trauma, demyelination, dysmyelination and neurodegeneration. Although abnormalities of diffusion are generally not pathognomonic, diffusion MRI affords information about tissue changes for specific disorders that complements information obtained with standard MR techniques and frequently shows pathology earlier. In ...
Acid Rock Drainage (ARD) is the product formed by the atmospheric oxidation of the relatively common pyrite and pyrrhotite. Waste rock dumps and tailings containing sulfide mineral have been reported at toxic materials producing ARD. Mining in sulphide bearing rock is one of activity which may lead to generation and release of ARD. ARD has had some major detrimental affects on mining areas. The purpose of this study was carried out to develop disposal method for preventing contamination of water and soil environment by waste rocks dump and tailings, which could discharge the acid drainage with high level of metals. Scope of this study was as following: environmental impacts by mine wastes, geochemical characteristics such as metal speciation, acid potential and paste pH of mine wastes, interpretation of occurrence of ARD underneath tailings impoundment, analysis of slope stability of tailings dam etc. The following procedures were used as part ...
The three-dimensional (3-D), multiphase, computational fluid dynamic (CFD) code FLUENT is used to simulated two-phase flow behaviour in a CANDU header manifold under low (natural circulation) flow conditions. This behaviour was previously inferred from experimental data. The CFD simulations reported here are being used to support these inferences and to obtain a better understanding of phase distribution in the header manifold. The simulations seem to show that the vapor-water mixture models in the FLUENT code do not capture properly phase separation in the header and proper phase branching at the header-feeder connections that have been observed in experiments at low flows. The simulations using discrete-phase model in FLUENT, which tracks the pathlines of the individual vapor bubbles in the water continuum phase, show interesting, complicated and, in some cases, unexpected bubble trajectories from the point of injection of the bubbles at a ...
The Heavy Water Reactor Facility (HWRF), as part of the defense-in-depth philosophy to mitigate the effect of design-basis and severe accidents, is equipped with a passive containment cooling system (PCCS). The function of the PCCS is to provide a safety-grade path to the ultimate heat sink for the removal of the reactor coolant system sensible heat and core decay heat. Ambient air enters an annular space between the steel containment shell and the surrounding concrete shield building through inlets in the shield building wall, is heated via natural convection, rises, and exits the building through a chimney located above the containment dome. A test program is in place to access parameters important to the effective operation of the PCCS. This paper focuses on the large-scale tests (LSTs). The objectives of these tests are as follows: (1) demonstrate natural circulation cooling with more prototypic cylinder and dome surface area ratios than ...
The Heavy Water Reactor Facility (HWRF), as part of the defense-in-depth philosophy to mitigate the effect of design-basis and severe accidents, is equipped with a passive containment cooling system (PCCS). The function of the PCCS is to provide a safety-grade path to the ultimate heat sink for the removal of the reactor coolant system sensible heat and core decay heat. Ambient air enters an annular space between the steel containment shell and the surrounding concrete shield building through inlets in the shield building wall, is heated via natural convection, rises, and exits the building through a chimney located above the containment dome. A test program is in place to access parameters important to the effective operation of the PCCS. This paper focuses on the large-scale tests (LSTs). The objectives of these tests are as follows: (1) demonstrate natural circulation cooling with more prototypic cylinder and dome surface area ratios than ...
Oil and gas companies operate in many countries around the world. Their exploration and production (E&P) operations generate many kinds of waste that must be carefully and appropriately managed. Some of these wastes are inherently part of the E&P process; examples are drilling wastes and produced water. Other wastes are generic industrial wastes that are not unique to E&P activities, such as painting wastes and scrap metal. Still other wastes are associated with the presence of workers at the site; these include trash, food waste, and laundry wash water. In some host countries, mature environmental regulatory programs are in place that provide for various waste management options on the basis of the characteristics of the wastes and the environmental settings of the sites. In other countries, the waste management requirements and authorized options are stringent, even though the infrastructure to ...
On November 2, 1974, Skelly and Loy submitted recommendations to the United States Environmental Protection Agency concerning establishment of effluent limitations for the Coal Mining Point Source Category, culminating an exhaustive study of water treatment technology within the coal industry. Members of the National Coal Association alleged that the efficiency of acid mine drainage treatment plants and settling basins is seriously reduced during winter and spring seasons. The original study was conducted during the summer months, and review of historical seasonal effluent data indicated there may be validity to this claim. To validate and confirm the conclusions and proposed effluent limitations established in part from this historical data, a further sampling program was conducted during the winter and spring of 1975. This report presents the findings of that sampling program, and correlates previously collected sample data into a ...
This report is an appraisal of the state of the European Union`s environment. It was requested by the European Commission as part of the review process of the Fifth Environmental Action Programme `Toward sustainability`. Main sections of the report are headed: societal developments and driving forces; environmental themes and topics; integration economy and environment. Themes covered are: climate change, ozone depletion, acidification, air pollution and quality, waste management, urban-issues, inland water resources, coastal zones and marine waters, risk management, soil quality, and nature and diversity. The main conclusions of this report are that the European Union is making progress towards reducing certain pressures on the environment, though this is not enough to improve the general quality of the environment and represents even less progress towards sustainability. Without accelerated policies, pressures on the ...
The gross calorific value (H{sub o}) is the amount of heat which is generated by total combustion of a type of fuel. It also includes that part of heat which is generated by steam from evaporated water contained in heating gas. In conventional heating boilers, this heat portion is not being utilized at all. To utilize the gross calorific value, it is necessary to extract from the exhaust gas the evaporation heat bound in steam and to return this to the heating system. This means that the exhaust gas has to be chilled by the return water of the heating system and condensed in suitable heat exchangers to well below the dew point. (orig.) [Deutsch] Waermelieferanten im Bereich der Nahwaermeversorgung koennen durch die Anwendung verfuegbarer und bewaehrter Brennwerttechnik ihre Kosten senken und einen zusaetzlichen Beitrag zum Umweltschutz leisten. Mit dem richtigen Brennwertkessel amortisieren sich Mehrkosten in weniger als 2 ...
In 1990, 176 million tonnes (mt) of air-traffic fuel was burned, which produced about 550 mt CO{sub 2}, 220 mt water, 3.5 mt NO{sub x} amd 0.18 mt SO{sub 2}. NO{sub x} emissions from air traffic may, by increasing ozone concentrations, be responsible for about 8% of global greenhouse warming. In the stratosphere NO{sub x} from aircraft is partly responsible for ozone depletion. With present technology 500 aircraft in the stratosphere would cause global ozone losses of 20%. Water vapour added by aircraft also contributes to global warming. In the form of ice crystals between 8 to 13 km above sea level, it acts as cirrus clouds. Probably the least damaging cruising altitude for aircraft is 9 km above sea level. Fuel consumption by aircraft is increasing. Air pollution abatement measures include substituting hydrogen fuel for kerosene, developing engines that emit less NO{sub x} and the introduction of internationally ...
This paper presents the characteristics of selected parameters of organic matter of the Tertiary coal samples and organic matter of Carboniferous rock samples from the Spitsbergen. The coal samples were taken from Central Coal Basin (the Longyearbyen region) and from the Forlandsundet Basin (Oscar II Land, the Kaffioyra region). Samples of dispersed organic matter were collected from Suffolk Pynten and Sergeijevfjellet area in Sorkapp Land. The optical properties of coal samples are different from properties of dispersed organic matter. Macerals of vitrinite group dominate in all of the samples. The average content of vitrinite group macerals is much lower in dipersed organic matter samples than it is in coals. The average content of liptinite group macerals is a little lower, and inertinite group macerals is much higher. The average content of mineral matter is higher in organic matter samples than in coal samples. The average value of vitrinite reflectance and ...
The verification test program on zinc injection applicability to Japanese BWRs was started in 1997. Laboratory tests using high temperature water loops under BWR reactor water conditions are in progress. This paper is an interim report on results obtained so far. Co-58 and Zn-65 were simultaneously used in the Co radioactivity buildup test to evaluate zinc injection suppression effects towards cobalt deposition on pre-oxidized stainless steel. The following results were obtained. The Co deposition was suppressed effectively by Zn injection, even when there was a pre-oxide film. For the test piping that had the pre-oxide film formed under the NWC (normal water chemistry) condition, when soaked under the HWC (hydrogen water chemistry) condition a large amount of Co-58 was taken into a small part of the inner layer. The distribution ratio of Co-58 in the inner layer and outer layer of ...
The corrosion behaviour of the stainless steels 304, 316 Ti, 25Cr-20Ni-Mo-Ti, nickel base alloys Hastelloy C4, Inconel 625, Incoloy 800, Ti and Ti-0.2% Pd alloy has been studied in the aerated or deaerated solutions at 20/sup 0/C and 90/sup 0/C whose compositions are representative of interstitial ground waters: granitic or clay waters or salt brine. The electrochemical techniques used are voltametry, polarization resistance and complexe impedance measurements. Electrochemical data show the respective influence of the parameters such as temperature, solution composition and dissolved oxygen, addition of soluble species chloride, fluoride, sulfide and carbonates, on which depend the corrosion current density, the passivation and the pitting potential. The inhibition efficiency of carbonate and bicarbonate activities against pitting corrosion is determined. In clay water at 90/sup 0/C, Ti and Ti-Pd show very high passivation ...
The titanium stabilized austenitic steel similar to the type of 321 is sensitive to the stress corrosion crackingunder horizontal steam generator operating condition. SCC was observed under crevice corrosion parameters and has resulted in the transgranular or intergranular cracking at the both, components primary collectors and heat exchange tubes. The crevice environment is characterized by aggressive impurities and 'non aggressive' compounds. Sulfates and chlorides as aggressive species and silicates and alumino-silicates as 'non aggressive' species on the other hand are present in significant amount in the crevice environment under operating condition. Local water chemistry parameters were evaluated with MULTEQ Code. As input data the measured operational values of local and bulk environments have been used. The determined parameters were compared with the results of thread hole environment analyses and tube surface ...
At a military base in the Southeastern US, an energy services company (ESCO) has proposed to retrofit more than 1,000 family residences with geothermal heat pumps as part of an energy savings performance contract (ESPC). Each residence is to have one heat pump with its own ground heat exchanger consisting of two or more vertical bores. A design firm hired by the ESCO sized the heat pumps to meet peak cooling loads, and sized the borefields to limit the maximum entering water temperature (EWT) to the heat pumps to 95 F (35 C). Because there is some disagreement in the geothermal heat pump industry over the peak temperature to be used for design (some designers and design manuals recommend temperatures as low as 85 F[29 C], while equipment manufacturers and others specify temperatures of 100 F[38 C] or higher) the authors were requested to examine the designs in detail to determine whether the 95 F (35 C) limit was adequate to ensure occupant ...
Water power plants mean the design, configuration, execution and operation of buildings and of hydraulic and electrical machines. Their many types are due to the stages of development and the technical alternatives of the use of waterpower and the associated energy economy aspects. The main points of this work are the use of water power, different hydro-electric powerstations, water collection, machines and electrotechnical equipment. In the 2nd revised edition parts on electrical engineering, environment, minimum water run-off pumped storage plants, small scole plants, economical aspects and finite elements were broadened. It is a comprehensive textbook and technical book for students of civil engineering and particularly suitable for engineers active in the theory and practice of waterpower construction. (orig./GL) [Deutsch] Wasserkraftanlagen bedeuten Planung, Gestaltung, ...
Water power plants mean the design, configuration, execution and operation of buildings and of hydraulic and electrical machines. Their many types are due to the stages of development and the technical alternatives of the use of waterpower and the associated energy economy aspects. The main points of this work are the use of water power, different hydro-electric powerstations, water collection, machines and electrotechnical equipment. In the 2nd revised edition parts on electrical engineering, environment, minimum water run-off pumped storage plants, small scole plants, economical aspects and finite elements were broadened. It is a comprehensive textbook and technical book for students of civil engineering and particularly suitable for engineers active in the theory and practice of waterpower construction. (orig./GL) [German] Dieses Standardwerk der Wasserkraft liegt hiermit bereits ...
Approximately 700m of deep water clastic deposits of Mt. Messenger Formation are superbly exposed along the Taranaki coast of North Island, New Zealand. Biostratigraphy indicates the interval was deposited during the time span 10.5-9.2m.y. in water depths grading upward from lower bathyal to middle-upper bathyal. This interval is considered part of a 3rd order depositional sequence deposited under conditions of fluctuating relative sea-level, concomitant with high sedimentation rates. Several 4th order depositional sequences, reflecting successive sea-level falls, are recognized within the interval. Sequence boundaries display a range of erosive morphologies from metre-wide canyons to scours several hundred metres across. All components of a generic lowstand systems tract--basin floor fan, channel-levee complex and progading complex--are present in logical and temporal order. They are repetitive through the interval, with ...
Many mines and processing facilities are in remote, difficult to access areas, or are in areas where access is limited or restricted for national reasons. In a joint project with Canada Centre for Remote Sensing, the Canadian Safeguards Support Program is investigating utility of multi- and hyperspectral remote sensing for remotely inspecting such site. With a view to eventually using the hyperspectral satellite data now coming available, airborne data over uranium and copper mine tailings and uranium processing facilities in northern Canada were acquired. The objective of this work is to demonstrate that multispectral and hyperspectral data can provide complementary and supplementary information to high-resolution panchromatic imagery for the following safeguards applications: Inspection aids (up-to-date maps of remote locations), change detection, evaluation of member state declarations, monitoring of reactor, mining and processing facility operations, and detection of undeclared ...
Adsorptive removal of Pb(II) ions from aqueous solution onto a non-activated charcoal (CC) of oak wood origin was studied in comparison with an activated carbon of coal origin. The adsorption capacity for Pb(II) of the non-activated charcoal increased significantly with deceasing particle diameter, whereas the activated carbon (AC) exhibited approximately constant capacity for Pb(II) adsorption as a function of particle size. Adsorption to the ashes prepared from the non-activated charcoal and the activated carbon was also investigated to examine the role of mineral ash. Although the ash from the activated carbon did not show any Pb(II) adsorption, the ash from the charcoal was very effective for Pb(II) adsorption. Furthermore, Pb(II) was hardly adsorbed when the ash was removed from the non-activated charcoal by acid treatment. Based on the results, the ...
The isotherms, kinetics and thermodynamics of Cd(II), Zn(II) and Pb(II) biosorption by Penicillium simplicissimum were investigated in a batch system. The effects of pH, initial metal ions concentration, biomass dose, contact time, temperature and co-ions on the biosorption were studied. Adsorption data were well described by both the Redlich-Peterson and Langmuir model. Chemical ion-exchange was found to be an important process based on free energy value from Dubini-Radushkevich isotherm for all metal ions. The results of the kinetic studies of all metal ions at different temperature showed that the rate of adsorption followed the pseudo second-order kinetics well. The thermodynamics constants {delta}G{sup o}, {delta}H{sup o} and {delta}S{sup o} of the adsorption process showed that biosorption of Cd(II), Zn(II) and Pb(II) ions on Penicillium simplicissimum ...
This study reports on the physical-chemical behaviour of swelling di-octahedral clays (smectites) and their interaction with aqueous solutions and bacteria (Shewanella putrefaciens). Experimental results are presented for compacted clays, hydrated under confined volume conditions, using a new type of reaction-cell (the 'wet-cell' of Warr and Hoffman, 2004) that was designed for in situ X-ray diffraction (XRD) measurement. For comparison, dispersed clay systems were studied using standard batch solutions subjected to varying degrees of agitation. The combination of time-dependent in situ XRD measurements with gravimetric measurements and calculated diffraction patterns using the CALCMIX software (Plancon and Drits, 1999) allowed to successful quantification of the dynamics of water uptake and storage. This analytical procedure combined with published water vapour adsorption data enabled determination of the abundance of ...
The GEOFLOW I experiment has been successfully performed on the International Space Sta-tion (ISS) in 2008 in the Columbus module in order to study the stability, pattern formation and transition to turbulence in a viscous incompressible fluid layer enclosed in two concentric co-rotating spheres subject to a radial temperature gradient and a radial volumetric force field. The objective of the study is the experimental investigation of large scale astrophysical and geophysical phenomena in spherical geometry stipulated by rotation, thermal convections and radial gravity fields. These systems include earth outer core or mantle convection, differen-tial rotation effects in the sun, atmosphere of gas planets as well as a variety of engineering applications. The GEOFLOW I experimental instrument consists of an experiment insert for operation in the Fluid Science Laboratory, which is part of the Columbus Module of the ISS. It was first launched in February 2008 together ...
After 3 years of construction the trial run of the heating power station HKW 2 ended in November 1997 on time. No extraordinary damage occured during construction, assembly or commissioning. The plant has been operating according to schedule since November 1997. A brief inspection carried out in the summer of 1998 in order to assess warranty claims showed no damage to any part except one valve. Experience shows that all aforementioned activities were necessary. The paper reports about success and negative experience. Certification according to DIN EN ISO 9000ff., however, affords to guarantee of high-quality construction. Builders of such plants therefore need to set up their own quality assurance centre and ensure its technical competence. If necessary,additional experts should be called in.Quality assurance costs for HKW 2 came to about 0.5-0.6 percent of total costs. In view of the success and long life of this investment these expenses are more than justified. ...
In the third quarterly report adsorption of heavy metals ions such as Cu(II) and Cr(VI) onto soils drawn from the laboratory-type wetland was shown to be weak. Secondly, it was shown that modified-clays did adsorb Cr(VI) ions strongly at pH 4.5. Further, studies on the pH dependence of the adsorption of {beta}-naphthoic acid, (NA), a well-documented contaminant in many oil and gas well waste waters onto modified-clays were undertaken and it was shown that uptake of NA by modified-clays was of the high affinity type at pH 4.5 and 7.0, but weak at pH 9.0. Adsorption of heavy metal ions, Cu{sup 2+}, and Cr(VI) onto algae, a proposed wetland amendment, was carried out and the results were presented and discussed in the fourth quarterly report. Uptake of NA by the soil component of the laboratory-type wetland was monitored as a function of pH. This quarterly report presents results from studies on the uptake of phenol and {beta}-naphthoic acid by ...
When Silk fibre derived from Bombyx mori, a native biopolymer, was dissolved in highly concentrated neutral salts such as CaCl{sub 2}, the regenerated liquid silk, a gradually degraded peptide mixture of silk fibroin, could be obtained. The silk fibroin nanoparticles were prepared rapidly from the liquid silk by using water-miscible protonic and polar aprotonic organic solvents. The nanoparticles are insoluble but well dispersed and stable in aqueous solution and are globular particles with a range of 35-125 nm in diameter by means of TEM, SEM, AFM and laser sizer. Over one half of the {epsilon}-amino groups exist around the protein nanoparticles by using a trinitrobenzenesulfonic acid (TNBS) method. Raman spectra shows the tyrosine residues on the surface of the globules are more exposed than those on native silk fibers. The crystalline polymorph and conformation transition of the silk nanoparticles from random-coil and {alpha}-helix form (Silk I) into ...
The paper begins with an introduction on the reasons that lead to the use of HVDC submarine cable links. The main aspects for the choice of direct current are presented as well as the advantages deriving from the utilization of submarine cables. The second part is dedicated to a discussion on the various type of insulation that could be used in power cables and their possible application to HVDC submarine cables. In the following there is a description of the main characteristics and technical details of some particular project that at present time (1995) are in progress. Two projects are briefly presented: Spain-Morocco, a 26 km long interconnection for the transmission, in a first phase, of 700 MW from Spain to Morocco at 400 kV a.c. by means of three cables, plus one spare, of the fluid filled type. The cables are designed for a future change to d.c. 450 kV, allowing a transmission of 500 MW each (i.e., 2 GW total). One of the peculiarities of the link is the ...
Embracing the notion of going green, an affluent school district in Pennsylvania spent $83 million as part of the high school's renovation and expansion project. The three-level addition is now equipped with self-dimming lights, energy-efficient windows, a rooftop solar water heater, and a geothermal cooling and heating system. As a bonus for going green, the school district received a $250,000 grant from the Pennsylvania Department of Environmental Protection. The district used that money to create an information center in the lobby of the building where a touch-screen computer provides students, staff, and visitors with data related to the operation of the school's energy-efficient water and electrical systems. The system will graphically depict utility use over the course of a year. The monitoring system and touch-screen computer can turn this school into a living lab, with science, math, and economics teachers using the ...
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The construction materials used in coolant systems in nuclear power plants become covered with oxide films as a result of exposure to the aqueous environment. The susceptibility of the materials to different forms of corrosion, as well as the extent of the incorporation of radioactive species on the surfaces of the primary circuit, are greatly influenced by the physical and chemical properties of these oxide films. The composition and characteristics of the oxide films in turn depend on the applied water chemistry. This work was undertaken in order to collect and evaluate the present views on the structure and behaviour of oxide films formed on iron- and nickel-based materials in aqueous environments. This survey should serve to recognise the areas in which more understanding and research effort is needed. The review begins with a discussion on the bulk oxides of iron, nickel and chromium, as well as their mixed oxides. In addition to bulk oxides, the structure and ...
The objective of this project was to develop new photocatalytic or other innovative process chemistry for the treatment of pink water and related contaminated water.
As part of the demonstration testing of the Purge Water Management System (PWMS) technology at the Savannah River Site (SRS), four wells were equipped with PWMS units in 1997 and a series of sampling events were conducted at each during 1997-1998. Three of the wells were located in A/M Area while the fourth was located at the Old Radioactive Waste Burial Ground in the General Separations Area.The PWMS is a ''closed-loop'', non-contact, system used to collect and return purge water to the originating aquifer after a sampling event without having significantly altered the water quality. One of the primary concerns as to its applicability at SRS, and elsewhere, is whether the PWMS might resample groundwater that is returned to the aquifer during the previous sampling event. The purpose of the present investigation was to compare groundwater chemical analysis data ...
Purpose/Objective: With the advent of computed tomography and magnetic resonance imaging, the three dimensional representation of the patient anatomy has become an invaluable resource for better diagnosis and delineation of the target volume and sensitive structures in radiation therapy. Although the therapeutic linear accelerator industry has made available highly sophisticated equipment, the aggressiveness in dose prescription and delivery has to be complimented by accurate dose computation methods. We have adopted a convolution/superposition algorithm for the calculation of absolute dose that fully accounts for the external shape and internal structure of the patient for photon treatment radiotherapy. In this paper, we will discuss the principles of the convolution algorithm and we will show how the computed dose compares to clinically relevant treatment techniques. Materials and Methods: A computer controlled data acquisition system and a water tank where used ...
Aqueous solutions (mixed waste) generated from various LLNL operations, such as debris washing, sample preparation and analysis, and equipment maintenance and cleanout, were combined for storage in the B695 tank farm. Prior to combination the individual waste streams had different codes depending on the particular generating process and waste characteristics. The largest streams were CWC 132, 791, 134, 792. Several smaller waste streams were also included. This combined waste stream was treated at LLNL's waste treatment facility using a vacuum filtration and cool vapor evaporation process in preparation for discharge to sanitary sewer. Prior to discharge, the treated waste stream was sampled and the results were reviewed by LLNL's water monitoring specialists. The treated solution was discharged following confirmation that it met the discharge criteria. A major source, accounting for 50% for this waste stream, is metal machining, cutting and ...
An exact cosmological solution of Einstein's equations which has time-dependent rotation is presented. The t-constant sections are of Bianchi type II. The source of this geometry is a fluid which has not been thermalized. (Author).
Exposure of albumin to Cu(II) (10-100 microM) and ascorbate (0.1-2 mM) results in extensive molecular modifications, indicated by decreased fluorescence and chain breaks. The rate of utilization of...Full Text Available
ObjectivesThe updated Rome III criteria for pediatric functional gastrointestinal disorders (FGIDs) include new FGID categories and changes to the Rome II criteria...Full Text Available
Interleukin 2 (IL-2) and B-cell growth factors I and II (BCGF I and BCGF II) are lymphokines produced by T cells that play a major role in T- and B-cell cooperation. Peripheral blood lymphocytes from...Full Text Available
In this article are presented main results on electric potential investigations in stellarator/torsatron TJ-II and tokamak T-10 in a comparable regimes of device operation.
Aminopeptidase II, one of the two major aminopeptidases in the giant alga Chara australis, was partially purified. Its molecular weight was estimated to be about 80,000 by gel permeation...Full Text Available
New palladium(II) and platinum(II) complexes of saccharinate (sac), trans-[Pd(py)"2(sac)"2] (1), cis-[Pt(py)"2(sac)"2] (2), trans-[Pd(3-acpy)"2(sac)"2] (3) and cis-[Pt(3-acpy)"2(sac)"2] (4) (py=pyridine and 3-acpy=3-acetylpyridine) have been synthesized. Elemental analysis, UV-Vis, IR, NMR and TG/DTA characterizations have been carried out. The structures of 1-4 were determined by X-ray diffraction. The palladium(II) and platinum(II) ions are coordinated by two N-bonded sac ligands, and two nitrogen atoms of py or 3-acpy, forming a distorted square-planar geometry. The palladium(II) complexes (1 and 3) are trans isomers, while the platinum(II) complexes (2 and 4) are cis isomers. The mononuclear species in the solid state are connected by weak intermolecular C-H...O hydrogen bonds, C-H...@...
BackgroundThe binding of peptide fragments of antigens to class II MHC is a crucial step in initiating a helper T cell immune response. The identification of such peptide epitopes...Full Text Available
The aim of this article was to investigate the interactions of metal cations in aqueous solutions with the biomass of the freshwater macroalga Vaucheria sp. This problem is important when elaborating new applications of biosorption, e.g. the production of mineral feed additives for livestock from the biomass of algae enriched with microelement ions. Potentiometric titration was applied as a quick and cheap screening test to search for new efficient biosorbents. It revealed a variety of functional groups capable of cation exchange on the macroalgal surface, including carboxyl, phosphate, hydroxyl or amino groups. Fourier transform infrared spectroscopy on natural and chromium-loaded Vaucheria sp. confirmed that carboxyl groups played a dominant role in the biosorption. The study also showed that Ca(II), Na(I), K(I), and Mg(II) ions were released from the biomass after biosorption of Cu(II), Mn(II), ...
BackgroundPromoter region plays an important role in determining where the transcription of a particular gene should be initiated. Computational prediction of eukaryotic Pol II promoter...Full Text Available
Rotazyme II, which is a shorter version of Rotazyme (less than 3 h), was compared with electron microscopy and Rotazyme for sensitivity and specificity on 229 human stool specimens. Compared with electron...Full Text Available
The biosorption of lead (II) and copper (II) ions, single component and binary systems, by dried P. putida was investigated in a batch system. The effects of initial pH, temperature, initial single and binary mixture concentrations on the biosorption kinetics and equilibrium uptake of each component, both single and binary mixtures were investigated. The bacterial biomass exhibited the highest single and binary lead (II) and copper (II) ions uptake capacity at 25 and 30 deg. C, respectively, the initial pH value of 5.5 and at the initial metal ions concentration of 100 mg dm{sup -3}. The Freundlich and Langmuir adsorption models were used for the mathematical description of the biosorption equilibrium and isotherm constants were evaluated at different temperatures. Adsorption data were well described by the Langmuir model, although they could be modeled by the Freundlich equation. The thermodynamics ...
BackgroundPerfluorocarbons (PFC) are used to improve gas exchange in diseased lungs. PFC have been shown to affect various cell types. Thus, effects on alveolar type II (ATII) cells...Full Text Available
ATP-binding cassette A3 (ABCA3) is a lipid transport protein required for synthesis and storage of pulmonary surfactant in type II cells in the alveoli. Abca3 was conditionally deleted...Full Text Available
Cytokinesis in animal and fungal cells utilizes a contractile actomyosin ring (AMR). However, how myosin II is targeted to the division site and promotes AMR assembly, and how the AMR coordinates with...Full Text Available
Anaerobic reactions of Rhus vernicifera laccase and its type-2 copper-depleted derivatives with hexacyanoferrate(II) were investigated by absorption and e.s.r. spectroscopy. When native laccase was...Full Text Available
Photobilirubin II, a stereoisomer of bilirubin, binds to human serum albumin at a single binding site (K = 2.2 x 10(6)M-1), presumably the high-affinity bilirubin-binding site. Binding in the secondary...Full Text Available
The identification of MHC class II restricted peptide epitopes is an important goal in immunological research. A number of computational tools have been developed for this purpose, but there is a lack...Full Text Available
ii) Flammability: (iii) A capacity to oxidise: (iv) Corrosiveness: (v) Toxicity (including chronic ...an explosion or fire: (d) For substances with corrosive properties: (i) To reduce the ...likelihood of any unintended corrosion:(ii) To control the adverse effects of any corrosion:
45 Public Welfare 3 2010-10-01 2010-10-01 false Appendix A to Part 611 A Appendix A to Part 611 Public Welfare Regulations Relating to Public Welfare (Continued) NATIONAL SCIENCE...
... Screening Adjudication Monitoring Applicants of Information Behavior II I Conducting Investigations ... Applicants of Information Behavior Conducting ...
The interaction between N-donor adsorbates such as ammonia and pyridine with Cu(II)-exchanged montmorillonite, beidellite, flourohectorite into smectite clays has been studied by electron spin resonance. Cu(II) cations exchanged into smectites coordinate five ammonia or pyridine molecules in beidellite, four ammonia of pyridine molecules in hydroxyhectorite. Thus, the Cu(II) cations bound to the interior surfaces of these smectite clays constitute strong Lewis acid sites. 26 refs., 7 figs., 1 tab.
The aim of the study is to prepare ionic exchangers using the polymerization of unsaturated polyster with monomeric styrene units in a ratio of 60%: 40% respectively. The type of method involved in this preparation, is called An Emulsion Polymerization. Such type of polymerization was carried out by two techniques: chemical and irradiation techniques. The first techniques requires the formation of free radical monomers by use of methyl Ethy Ketone Peroxide capable of decomposing into free radicals upon heating, while the other technique involves the use of gamma rays (using Co-60 source) capable of activating monomers towards free radical formations. A number of very effective chemical parameters and physical factors were used and investigated throughout the reactions such as: dispersant matrix, viscosity, rate of mixing, and irradiation dose. Besides, the study has included the study of the rate of Resin Beads Swelling which is thought to be another important part ...
SKB is currently performing site investigations at two potential sites for a final repository for spent nuclear fuel. This report presents results of water flow and solute transport modelling of the Forsmark site. The modelling reported in this document focused on the near-surface groundwater, i.e. groundwater in Quaternary deposits and shallow rock, and surface water systems, and was performed using the MIKE SHE tool. The most recent site data used in the modelling were delivered in the Forsmark 2.3 dataset, which had its 'data freeze' on March 31, 2007. The present modelling is performed in support of the final version of the Forsmark site description that is produced during the site investigation phase. In this work, the hydrological modelling system MIKE SHE has been used to describe near-surface groundwater flow and the contact between groundwater and surface water at the Forsmark site. The surface ...
The US Department of the Army, Baltimore District Corps of Engineers, oversees a long-term monitoring study to assess and evaluate effects of the Jennings-Randolph reservoir on biota in the North Branch Potomac River. The reservoir was intended, in part, to mitigate effects of acid mine drainage originating in upstream and headwater area. The present study assessed recovery of benthos and fish in this system, six years after completion of the reservoir. Higher pH and lower iron and sulfate concentrations were observed upstream of the reservoir compared to preimpoundment conditions, suggesting better overall water quality in the upper North Branch. Water quality improved slightly directly downstream of the reservoir. However, the reservoir itself was poorly colonized by macrophytes and benthic organisms, and plankton composition suggested either metal toxicity and/or nutrient limitation. One large tributary to the North ...
The primary coolant oxidises the surfaces of construction materials in nuclear power plants. The properties of the oxide films influence significantly the extent of incorporation of actuated corrosion products into the primary circuit surfaces, which may cause additional occupational doses for the maintenance personnel. The physical and chemical properties of the oxide films play also an important role in different forms of corrosion observed in power plants. This report gives a short overview of the factors influencing activity build-up and corrosion phenomena in nuclear power plants. Furthermore, the most recent modifications in the water chemistry to decrease these risks are discussed. A special focus is put on zinc water chemistry, and a preliminary discussion on the mechanism via which zinc influences activity build-up is presented. Even though the exact mechanisms by which zinc acts are not yet known, it is assumed that Zn may block the ...
The summertime tropical cyclogenesis rate per unit area in the eastern Pacific ocean is arguably higher than in any other location in the world. Many if not most of these cyclones form from African easterly waves which cross Central America into the Pacific. Of order 25% of these waves intensify into cyclones. A significant fraction of east Pacific tropical cyclones undergoes landfall on the Mexican coast. Those which do not, generally dissipate over cold ocean waters north of the east Pacific intertropical convergence zone, often not far from land. The layer of warm ocean water which supports the development of east Pacific cyclones is unusually shallow and is structured by anticyclonic vortices which form by various processes and propagate slowly to the west. These vortices locally deepen the oceanic mixed layer and support stronger convection than their surroundings, possibly promoting cyclogenesis and cyclone intensification. Cyclones ...
The U.S. Geological Survey, in cooperation with the U.S. Department of Energy, is conducting a study to determine the natural geochemistry of the Snake River Plain aquifer system at the Idaho National Engineering Laboratory (INEL), Idaho. As part of this study, a group of geochemical reactions that partially control the natural chemistry of ground water at the INEL were identified. Mineralogy of the aquifer matrix was determined using X-ray diffraction and thin-section analysis and theoretical stabilities of the minerals were used to identify potential solid-phase reactants and products of the reactions. The reactants and products that have an important contribution to the natural geochemistry include labradorite, olivine, pyroxene, smectite, calcite, ferric oxyhydroxide, and several silica phases. To further identify the reactions, analyses of 22 representative water samples from sites tapping the Snake River Plain aquifer ...
A Norwegian Research Program on Improved Oil Recovery (IOR) in North Sea reservoirs was launched in 1992. Microbial methods, applied in this context, is a part of this program. The scope, the methodological approach, and results from the three first years are presented. Water profile control, using biomass to block high permeable zones of a reservoir, has been investigated using nitrate-reducing bacteria in the injected sea water as plugging agents. Emphasis has been put on developing a process that does not have disadvantages secondary to the process itself, such as souring and impairment of the overall injectivity of the field. Data from continuous culture studies indicate that souring may successfully be mitigated by adding nitrite to the injected seawater. The morphology and size of generic-nitrate-reducing seawater bacteria have been investigated. Screening of growth-promoting nutrients has been carried out, and some ...
A large part of mechanical and durability characteristics of cement-based materials comes from the performances of the hydrated cement, cohesive matrix surrounding the granular skeleton. Experimental studies, in situ or in laboratory, associated to models, have notably enhanced knowledge on the cement material and led to adapted formulations to specific applications or particularly aggressive environments. Nevertheless, these models, developed for precise cases, do not permit to specifically conclude for other experimental conclusions. To extend its applicability domain, we propose a new evolutive approach, based on reactive transport expressed at the microstructure scale of the cement. In a general point of view, the evolution of the solid compounds of the cement matrix, by dissolutions or precipitations, during chemical aggressions can be related to the pore solution evolution, and this one relied to the ionic exchanges with the external environment. By the ...
In large samples, the {gamma}-ray count rate of a prompt gamma neutron activation analysis system is a multi-variable function of the elemental dry composition, density, water content and thickness of the material. The experimental calibration curves require tremendous laboratory work, using a great number of standards with well-known compositions. Although a Monte Carlo simulation study does not avoid the experimental calibration work, it reduces the number of experimental calibration standards. This paper is part of a feasibility study for a PGNAA system for on-line continuous characterisation of cement raw material conveyed on a belt (Oliveira, C., Salgado, J. and Carvalho, F. G. (1997) Optimisation of PGNAA instrument design for cement raw materials using the MCNP code. J. Radioanal. Nucl. Chem. 216(2), 191-198; Oliveira, C., Salgado, J., Goncalves, I. F., Carvalho, F. G. and Leitao, F. (1997a) A Monte Carlo study of the influence of ...
We report the of the existence of RV Tauri stars in the Large Magellanic Cloud (LMC). This class of variable star has hitherto been unidentified in the Magellanic Clouds. In light and color curve behavior the RV Tauri stars appear to be an extension of the Type II Cepheids to longer periods. A single period-luminosity-color relationship is seen to describe both the Type II Cepheids and the RV Tauri stars in the LMC.
Incorporation of /sup 32/P from (gamma-32P)ATP into tyrosine residues of the insulin-like growth factor (IGF)-II receptor was observed in a Triton X-100-insoluble fraction of rat adipocyte plasma membranes. IGF-II receptor phosphorylation proceeded to a stoichiometry of approximately 0.5 mol of phosphate/IGF-II binding site after 10 min of incubation at 4 degrees C. A Km for ATP of 6 microM was calculated for this phosphorylation reaction. Addition of IGF-II caused an approximately 2-fold increase in tyrosine phosphorylation of the IGF-II receptor in this preparation. In contrast, phosphorylation of angiotensin II by the Triton X-100 washed membranes was not stimulated by IGF-II. Incubation of purified receptor immobilized on IGF-II agarose or of receptor-enriched low density microsomal membranes with (gamma-32P)ATP did ...
Fragrance mix II (FM II) is a relatively new screening marker for fragrance contact allergy. It was introduced in the patch test baseline series in Denmark in 2005 and contains six different fragrance chemicals commonly present in cosmetic products and which are known allergens.
Fatty acid biosynthesis is crucial for all living cells. In contrast to higher organisms, bacteria use a type II fatty acid synthase (FAS II) composed of a series of individual proteins, making...Full Text Available
Volume 2 of the water resources data for the 1992 water year for Oklahoma consists of record of stage, discharge, and water quality of streams; stage, contents, and water quality of lakes or reservoirs; and water levels of ground-water well. The report contains discharge records for 136 gaging stations; stage and contents for 31 lakes or reservoirs; water quality for 50 gaging stations. Also included are 61 partial-record or miscellaneous streamflow stations and 28 ground-water sites.
Studies were conducted of the bifunctional oxygen electrode. The development of a rechargeable metal-oxygen (air) cell has been hampered to a great extent by the lack of a stable and cost effective oxygen electrode capable of use during both charge and discharge. The first type of bifunctional electrode consists of two distinct catalytifc layers. The oxygen reduction catalyst layer containing a supported gold catalyst is in contact with a hydrophilic nickel layer in which evolution of oxygen takes place. Loadings of gold from 0.5 to 1.0 mg/cm/sup 2/ were investigated; carbon, graphite, metal, and spinel oxides were evaluated as substrates. The second part of the research effort was centered on developing a reversible oxygen electrode containing only one catalytic layer for both reduction and evolution of oxygen. The work was directed specifically to the study of perovskite type of oxides with the composition AA/sup 1/BO/sub 3/ where A is an element of the ...
This report highlights four main points. (1) A residue substitution in phosphoribulokinase of Synechocystis PCC 6803 renders the mutant light-sensitive. The authors isolated a light-sensitive mutant (BRLS) of the photosynthetic cyanobacterium Synechocystis 6803 that does not survive exposure to bright light; 70% of BRLS cells die upon exposure to light of > 3000 lux for 2 hr. (2) Excitation energy transfer from phycocyanin to chlorophyll in an apcA-defective mutant of Synechocystis sp. PCC 6803. A greenish mutant of the normally bule-green cyanobacterium Synechocystis sp. PC 6803, designated UV6p, was isolated and characterized. UV6p possesses functional photosystems I and II but lacks normal light harvesting phycobilisomes because allophycocyanin is absent and core-specific linker proteins are almost entirely absent. (3) Deletion of the psbG1 gene of the cyanobacterium Synechocystis sp. PCC 6803 leads to the activation of the cryptic psbG2 gene. The genes psbG1 ...
Metagenomics projects based on shotgun sequencing of populations of micro-organisms yield insight into protein families. We used sequence similarity clustering to explore proteins with a comprehensive dataset consisting of sequences from available databases together with 6.12 million proteins predicted from an assembly of 7.7 million Global Ocean Sampling (GOS) sequences. The GOS dataset covers nearly all known prokaryotic protein families. A total of 3,995 medium- and large-sized clusters consisting of only GOS sequences are identified, out of which 1,700 have no detectable homology to known families. The GOS-only clusters contain a higher than expected proportion of sequences of viral origin, thus reflecting a poor sampling of viral diversity until now. Protein domain distributions in the GOS dataset and current protein databases show distinct biases. Several protein domains that were previously categorized as kingdom specific are shown to have GOS examples in other kingdoms. About ...
Future insertion quadrupoles with large apertures and high gradients will be required for the Phase II luminosity upgrade (10{sup 35} cm{sup -2}s{sup -1}) of the Large Hadron Collider (LHC). Although improved designs, based on NbTi, are being considered as an intermediate step for the Phase I upgrade, the Nb{sub 3}Sn conductor is presently the best option that meets the ultimate performance goals for both operating field and temperature margin. As part of the development of Nb{sub 3}Sn magnet technology, the LHC Accelerator Research Program (LARP) developed and tested several 1-meter long, 90-mm aperture Nb{sub 3}Sn quadrupoles. The first two series of magnet used OST MJR 54/61 (TQ01 series) and OST RRP 54/61 (TQ02 series) strands. The third series (TQ03) used OST RRP 108/127 conductor. The larger number of sub-elements and the consequent reduction of the effective filament size, together with an increased fraction of copper and a lower Jc were ...
The authors have interpreted 1,400 km of industry and government multichannel seismic reflection data from eastern Lake Superior. Seismic sequences have been identified by using reflection character and reflector terminations and truncations. This framework, coupled with outcrop information, has allowed them to assign lithologic units to some of these reflectors and reconstruct the timing and geometry of structures within the basin. The authors have mapped the Base Jacobsville-Bayfield Group/Top oronto Group, Base oronto Group/Top Keweenawan volcanics, and Basement as well as several reflectors internal to these groups. Integration of gravity and magnetic data with the seismic grid permits regional mapping of faults and folds between seismic lines. In the eastern part of the basin, high-angle basement-involved reverse faults, such as the southeastern combination of the Keweenaw fault, trend NNW-SSE, while broad folds trend E-W. The Keweenaw fault is a complex ...
The neutron-capture cross sections of "1"6"8Yb, "1"8"0W, "1"8"4Os, "1"9"0Pt, and "1"9"6Hg have been measured by means of the activation technique. The samples were irradiated in a quasistellar neutron spectrum of kT=25 keV, which was produced at the Karlsruhe 3.7-MV Van de Graaff accelerator via the "7Li(p,n)"7Be reaction. Systematic uncertainties were investigated in repeated activations with different samples and by variation of the experimental parameters, that is, irradiation times, neutron fluxes, and #gamma#-ray counting conditions. The measured data were converted into Maxwellian-averaged cross sections at kT=30 keV, yielding 1214#+-#61, 624#+-#54, 590#+-#43, 511#+-#46, and 201#+-#11 mb for "1"6"8Yb, "1"8"0W, "1"8"4Os, "1"9"0Pt, and "1"9"6Hg, respectively. The present results either represent first experimental data ("1"6"8Yb, "1"8"4Os, and "1"9"6Hg) or could be determined with significantly reduced uncertainties ("1"8"0W and "1"9"0Pt). These measurements are ...
This technical memorandum (TM) documents the 1995 characterization of eight underground radioactive waste tanks at Oak Ridge National Laboratory (ORNL). These tanks belong to the Gunite and Associated Tanks (GAAT) operable unit, and the characterization is part of the ongoing GAAT remedial investigation/feasibility study (RI/FS) process. This TM reports both field observations and analytical results; analytical results are also available from the Oak Ridge Environmental Information System (OREIS) data base under the project name GAAT (PROJ-NAME = GAAT). This characterization effort (Phase II) was a follow-up to the {open_quotes}Phase I{close_quotes} sampling campaign reported in Results of Fall 1994 Sampling of Gunite and Associated Tanks at the Oak Ridge National Laboratory, Oak Ridge, Tennessee, ORNL/ER/Sub/87-99053/74, June 1995. The information contained here should be used in conjunction with that in the previous TM. The sampling plan is ...
Methane (CH{sub 4}) produced microbially in sediments of marshes is emitted to the atmosphere primarily by flowing through and out of emergent aquatic plants. The magnitude of such emission rates and factors controlling those rates are not well understood. We evaluated CH{sub 4} emission from the widely distributed aquatic emergent plant cattail (Typha latifolia L.) in several wetlands in the United States using a field gas-exchange system that concurrently estimated stomatal aperture (i.e., conductance) on the surface of leaves and net photosynthesis. We compared gas exchange among plants of different age and from sites with different soil and atmospheric conditions. The mean rate of CH{sub 4} emission was 0.22{mu}mol m{sup -2} [leaf] s{sup -1}, which is 940 mg CH{sub 4} m{sup -2} d{sup -1} on a ground-area basis, with individual rates ranging from 0.01 to 1.49 {mu}mol m{sup -2} [leaf] s{sup -1}. For individual plants, we found emission rates were (i) highest for the ...
This report is composed of the following two parts and appendix. (I) Improvement of the Method for Evaluating Reactivity Based on Monte Carlo Perturbation Theory: Theoretical formulation in Monte Carlo perturbation method had been checked, and then introduced into a calculation code. There are some cases that the results of the change of eigenvalues becomes positive or negative by changing the estimator, and there is no reasonable difference in the results between the conventional method, which does not consider the change of neutron source distribution caused by a perturbation, and the new method, which consider that change. Thus it is still necessary to check the Monte Carlo perturbation code. (II) Improvement of Nodal Transport Method for 3-D Hexagonal Geometry: We can accurately evaluate hexagonal geometry FBR core by nodal transport calculation code for hexagonal-Z geometry named `NSHEX`. However it is also found that in very heterogeneous ...
After each archwire was ligated into a bracket with a 0.010-in stainless steel wire, both stainless steel and beta-titanium archwires (0.017- x 0.025-in) were slid through commercially pure titanium brackets (0.018-in slot size) at 34 degrees C in both the dry and wet conditions. As controls, stainless steel archwire versus stainless steel bracket couples were used with comparable dimensions. The drawing forces were measured at 5 angulations (0 degrees, 3 degrees, 7 degrees, 9 degrees, and 11 degrees ) for 5 normal forces (nominally 0.2, 0.4, 0.6, 0.8, and 1.0 kg). Regression lines were determined for each frictional couple (P <.05). In the passive configuration, the kinetic frictional coefficients of control and test couples in the dry condition were comparable to previously reported values at 0.11 +/- 0.01 for stainless steel versus stainless steel, 0.12 +/- 0.00 for stainless steel versus titanium, and 0.26 +/- 0.02 for beta-titanium versus titanium. As the angulation was ...
The general principles of Cu(II) binding to algal waste from agar extraction, composite material and algae Gelidium, and different modelling approaches, are discussed. FTIR analyses provided a detailed description of the possible binding groups present in the biosorbents, as carboxylic groups (D-glucuronic and pyruvic acids), hydroxyl groups (cellulose, agar and floridean starch) and sulfonate groups (sulphated galactans). Potentiometric acid-base titrations showed a heterogeneous distribution of two major binding groups, carboxyl and hydroxyl, following the quasi-Gaussian affinity constant distribution suggested by Sips, which permitted to estimate the maximum amount of acid functional groups (0.36, 0.25 and 0.1 mmol g{sup -1}) and proton binding parameters (pK{sup '}{sub H}=5.0,5.3and4.4;m{sub H} = 0.43, 0.37, 0.33), respectively for algae Gelidium, algal waste and composite material. A non-ideal, semi-empirical, thermodynamically consistent (NICCA) ...
Human Reliability Analysis (HRA) is a very important part of Probabilistic Risk Analysis (PRA), and constant work is dedicated to improving methods, guidance and data in order to approach realism in the results as well as looking for ways to use these to reduce accident frequency at plants. Further, in order to advance in these areas, several HRA studies are being performed globally. Mexico has participated in the International HRA Empirical study with the objective of -benchmarking- HRA methods by comparing HRA predictions to actual crew performance in a simulator, as well as in the empirical study on a US nuclear power plant currently in progress. The focus of the first study was the development of an understanding of how methods are applied by various analysts, and characterize the methods for their capability to guide the analysts to identify potential human failures, and associated causes and performance shaping factors. The HRA benchmarking study has been ...
Some acylhydrazine derived ONO donor Schiff bases and their Co(II) and Ni(II) complexes have been prepared having the same metal ion (cation) but different anions. These synthesized metal(II) complexes have been characterized on the basis of their elemental analyses, magnetic moment, molar conductance, and IR and electronic spectral data. All of the Schiff base ligands function as tridentates and the deprotonated enolic form is preferred for coordination. In order to evaluate the effect of anions on the bactericidal activity, these synthesized complexes, in comparison to the uncomplexed Schiff bases have been screened against bacterial species., Escherichia coli, Staphylococcus aureus and Pseudomonas aeruginosa and the results are reported. PMID:18475936
High-temperature LiCl-KCl molten salt medium provides an efficient way to produce the paramagnetic Eu(II) ion to be magnetically diluted into a diamagnetic host medium. Eu(II) was formed by a dissolution and an auto-reduction processes in a high-temperature LiCl-KCl eutectic melt at 723 K by using Eu{sub 2}O{sub 3} as a starting material. By using EPR and luminescence spectroscopic method, we studied the nature of the magnetically isolated paramagnetic Eu(II) ion diluted in a LiCl-KCl medium. With the aid of these spectroscopic tools, it was found that stable Eu(II) species was formed spontaneously at 723 K under anaerobic conditions. EPR and luminescence spectroscopy provided detailed information regarding the nature of the europium ion in a molten salt.
High-temperature LiCl-KCl molten salt medium provides an efficient way to produce the paramagnetic Eu(II) ion to be magnetically diluted into a diamagnetic host medium. Eu(II) was formed by a dissolution and an auto-reduction processes in a high-temperature LiCl-KCl eutectic melt at 723 K by using Eu_2O_3 as a starting material. By using EPR and luminescence spectroscopic method, we studied the nature of the magnetically isolated paramagnetic Eu(II) ion diluted in a LiCl-KCl medium. With the aid of these spectroscopic tools, it was found that stable Eu(II) species was formed spontaneously at 723 K under anaerobic conditions. EPR and luminescence spectroscopy provided detailed information regarding the nature of the europium ion in a molten salt.
High-temperature LiCl-KCl molten salt medium provides an efficient way to produce the paramagnetic Eu(II) ion to be magnetically diluted into a diamagnetic host medium. Eu(II) was formed by a dissolution and an auto-reduction processes in a high-temperature LiCl-KCl eutectic melt at 723K by using Eu2O3 as a starting material. By using EPR and luminescence spectroscopic method, we studied the nature of the magnetically isolated paramagnetic Eu(II) ion diluted in a LiCl-KCl medium. With the aid of these spectroscopic tools, it was found that stable Eu(II) species was formed spontaneously at 723K under anaerobic conditions. EPR and luminescence spectroscopy provided detailed information regarding the nature of the europium ion in a molten salt.
We determined the chromosomal localization and structure of the gene encoding human type II inosine 5{prime}-monophosphate dehydrogenase (IMPDH, EC 1.1.1.205), an enzyme associated with cellular proliferation, malignant transformation, and differentiation. Using polymerase chain reaction (PCR) primers specific for type II IMPDH, we screened a panel of human-Chinese hamster cell somatic hybrids and a separate deletion panel of chromosome 3 hybrids and localized the gene to 3p21.1{yields}p24.2. Two overlapping yeast artificial chromosome clones containing the full gene for type II IMPDH were isolated and a physical map of 117 kb of human genomic DNA in this region of chromosome 3 was constructed. The gene for type II IMPDH was localized and oriented on this map and found to span no more than 12.5 kb.
In this study we compared various maturity dependent aromatic, steroid and triterpenoid hydrocarbon ratios in bitumens that are freely extractable from sedimentary rocks (Bitumen I) with those in second extracts that comprised hydrocarbons closely associated with the kerogen/mineral matrix (Bitumen II). Bitumen II was released through kerogen isolation and demineralisation using HCl and HF/H3BO3. The samples studied, although of similar age, come from different localities. They represent a range of facies and two kerogen types (II and III), and all were deposited under marine conditions. The results show that the more stable b isomers of methylnaphthalene (MN) and methylphenanthrene (MP) are relatively more abundant in Bitumen II. The difference between the methylnaphthalene ratio (MNR) of...
This report describes modelling where the hydrological modelling system MIKE SHE has been used to describe surface hydrology, near-surface hydrogeology, advective transport mechanisms, and the contact between groundwater and surface water within the SKB site investigation area at Laxemar. In the MIKE SHE system, surface water flow is described with the one-dimensional modelling tool MIKE 11, which is fully and dynamically integrated with the groundwater flow module in MIKE SHE. In early 2008, a supplementary data set will be available and a process of updating, rebuilding and calibrating the MIKE SHE model based on this data set will start. Before the calibration on the new data begins, it is important to gather as much knowledge as possible on calibration methods, and to identify critical calibration parameters and areas within the model that require special attention. In this project, the MIKE SHE model has been further developed. The model ...
Soil gas, soil, and water were assessed for organic and inorganic constituents at the former 19th Street landfill at Fort Gordon, Georgia, from February to September 2010. Passive soil-gas samplers were analyzed to evaluate organic constituents in the hyporheic zone and flood plain of a creek and soil gas within the estimated boundaries of the former landfill. Soil and water samples were analyzed to evaluate inorganic constituents in soil samples, and organic and inorganic constituents in the surface water of a creek adjacent to the landfill, respectively. This assessment was conducted to provide environmental constituent data to Fort Gordon pursuant to requirements of the Resource Conservation and Recovery Act Part B Hazardous Waste Permit process. The passive soil-gas samplers deployed in the water-saturated hyporheic zone and flood plain of the creek adjacent to the former ...
In this study, the biosorption of Cd(II), Ni(II) and Pb(II) on Aspergillus niger in a batch system was investigated, and optimal condition determined by means of central composite design (CCD) under response surface methodology (RSM). Biomass inactivated by heat and pretreated by alkali solution was used in the determination of optimal conditions. The effect of initial solution pH, biomass dose and initial ion concentration on the removal efficiency of metal ions by A. niger was optimized using a design of experiment (DOE) method. Experimental results indicated that the optimal conditions for biosorption were 5.22 g/L, 89.93 mg/L and 6.01 for biomass dose, initial ion concentration and solution pH, respectively. Enhancement of metal biosorption capacity of the dried biomass by pretreatment with sodium hydroxide was observed. Maximal removal efficiencies for Cd(II), Ni(III) and ...
Water protection wetlands aim to reduce nitrogen and phosphorous concentrations either separately or simultaneously. In the latter case, a wetland must contain parts differing clearly in both function and physical condition. In efforts to reduce nitrogen the most important process is denitrification. Phosphorus is deposited with solids and bound to the vegetation and soil in wetlands. As the bulk of the solid and nutrient load comes from catchments during spring floods, wetlands should be designed on the basis of, at least, the average maximum vernal run-off (MHq). Use of higher run-offs, e.g. MHql/10 or MHql/20, in the design without reducing the target retention would require large wetlands. The efficiency of wetlands is constrained by too short retention times and low leachate temperatures. Wetlands established with special environmental support are normally designed on the basis of MHq. The average catchment area of such wetlands is 1.86 ...
This report presents the status of development of a three-dimensional conceptual model for the unconfined aquifer system at Hanford. A conceptual model is needed to support development of a realistic three-dimensional numerical model for predicting ground-water flow and the transport of contaminants. The report focuses on developing a hydrogeologic framework, assessing available hydraulic property data, describing flow-system boundaries, and evaluating areal recharge and leakage. Geologic descriptions of samples obtained during well drilling were used to prepare cross sections that correlate relatively continuous layers. The layers were defined based on textural differences that are expected to reflect differences in hydraulic properties. Assigning hydraulic properties to the layers is a critical part of the conceptual model. Available hydraulic property data for the study area were compiled and were correlated with the geologic layers where ...
As part of their corporate policy on environmental protection, Chevron, has taken an approach to work collaboratively with other industry members, universities and government agencies in phytoremediation research. The petroleum industry is interested in the integration of phytoremediation with the many biotechnology treatment technologies currently being used by the industry. Phytoremediation is a complex technology that does not just transfer wastes to another site, but offers in-situ final use and disposal treatment at sites anywhere in the world. Sites for potential remediation range from abandoned large refineries, chemical plants, or small urban gas stations. Research has focused on the cleanup of metals and hydrocarbons in diverse types of soil, water and groundwater conditions. This includes research into remediation of petroleum contaminants such as total petroleum hydrocarbon (TPH), polynuclear aromatic hydrocarbons as well as benzene ...
ANCAP (Government's Oil Company of Uruguay) owns a 4000 DWT oil coastal tanker which is mainly used for oil transport in the River Plate, Uruguay and Parana rivers. Availability of the ship is critical because of shortage of available vessels in the region. Full maximum draught of the vessel is 4m , so it can navigate in very shallow waters as it is the case of some places in the Uruguay and Parana rivers. Although the ship was built in 1979, it is a complete double hull, powered by two twin main engines and propellers. Since 1994, several changes in maintenance management have been introduced, in order to increase the availability, thus increasing the total oil volume yearly transported. These changes affected several maintenance items and they also included a modification in the design of part of the cargo tank floors of the ship. As a result of these changes, an increase of 60% of the oil derivatives volume transported yearly was ...
The first section of this Handbook describes hydro-electric projects currently under construction or recently commissioned in a number of countries. The major part of the Handbook is devoted to lists of data relating to hydro-electric plants and hydromachinery. These include: data for 1990 submitted by national power authorities on hydro-electric and pumped-storage plants in operation, under construction or planned; more detailed data for pumped-storage plants; country by country data on the dimensions, and reservoir and electrical capacity of major dams and hydro plant; a listing of roller compacted concrete dams; a listing of the world's largest turbines giving data on the largest unit at each scheme in rank order ranging from a unit capacity of 838 MV down to 147 MV; a similar list of the largest hydrogenerators ranging from a unit capacity of 825 MVA down to 150 MVA; details of turbine and generator contracts. The handbook concludes with an address ...
As part of on-going study of acid mine drainage (AMD), a comprehensive ecological risk assessment was conducted in the Leading Creek Watershed in southeast Ohio. The watershed is influenced by agriculture and active and abandoned coal-mining operations. This work presents a broad overview of several quantitative measures of hydrology and hydraulic watershed properties available for in risk assessment and evaluates their relation to metrics of ecology. Data analysis included statistical comparisons of metrics of ecology, ecotoxicology, water quality, and physically based parameters describing land use, geomorphology, flow, velocity, and particle size. A multiple regression analysis indicated that abandoned mining operations dominated impacts upon aquatic ecology. It also indicated low flow velocity measurements and a ratio of maximum velocity to average velocity at low flow where helpful in describing variation in macroinvertebrate Total Taxa ...
US Department of Energy (DOE) Order 5400.1 requires the preparation of environmental monitoring plans and implementation of environmental monitoring programs for all DOE facilities. The order identifies two distinct components of environmental monitoring, namely effluent monitoring and environmental surveillance. In general, effluent monitoring has the objectives of characterizing contaminants and demonstrating compliance with applicable standards and permit requirements, whereas environmental surveillance has the broader objective of monitoring the effects of DOE activities on on- and off-site environmental and natural resources. The purpose of this document is to support the Environmental Monitoring Plan for the Oak Ridge Reservation (ORR) by describing the groundwater component of the environmental surveillance program for the DOE facilities on the ORR. The distinctions between groundwater effluent monitoring and groundwater surveillance have been defined in the Martin Marietta ...
In situ toxicity tests were designed for Ceriodaphnia dubia and Chironomus tentans as part of a larger study designed to assess the effectiveness of constructed wetlands for the treatment of wastewater produced by oil production at Suncor OSG. The artificial wetlands were 50m long by 3m wide, with three replicates of the control and the treatment. Each wetland had four sample sites equidistant along its length, creating a gradient of treatment from site A being the most toxic to site D being the least toxic. Each test was conducted twice during the summer of 1994. Both the Ceriodaphnia and Chironomus test cages were a flow through design to allow for maximal exposure to the water within the wetlands. Mortality and reproduction were used as endpoints for Ceriodaphnia, whereas mortality and growth were used as endpoints for the Chironomus test. Test durations were fifteen and ten days respectively. Chironomus had very high mortality along the ...
10%Pt/C catalysts were prepared by liquid reduction method. PTFE and Pt/ C catalysts were adhered to porous metal and hydrophobic Pt/C/PTFE catalysts were prepared. The structure and size of Pt crystal particles of Pt/C catalysts were analyzed by XRD, and their mean size was 3.1 nm. The dispersion state of Pt/C and PTFE was analyzed by SEM, and they had good dispersion mostly, but PTFE membrane could be observed on local parts of Pt/C/PTFE surface. Because of low hydrophobicity, Pt/C/ PTFE catalysts have low activity when the mass ratio of PTFE and Pt/C is 0.5: 1, and their catalytic activity increases markedly when the ratio is 1:1. When the ratio increases again, more Pt active sites would be covered by PTFE and interior diffusion effect would increase, which result in the decrease of catalytic activity of Pt/C/PTFE. By PTFE pretreatment of porous metal carrier, the activity of Pt/C/PTFE catalysts decreases when the mass ratio of PTFE and Pt/C is 0.5:1, and their ...
Since the beginning of the large-scale technical manufacture of activated charcoal at the start of the century, this product has become increasingly important. Activated charcoal is a central part today of many chemical industrial processes. Furthermore, the purification of exhaust air and liquid wastes is often based on the adsorption by activated charcoal. The constantly increasing hygienic demands made of our drinking water may also often only be fulfilled by using activated charcoal. The highly developed adsorption technique of today is considerably supported by continuous improved quality of the products which can only be achieved by progress in manufacturing techniques. The large-scale use of activated charcoal has only become possible for a series of tasks by developing suitable reactivation methods. The last German-language monograph on activated charcoal appeared 18 years ago. The present work wishes to close this gap and in particular ...