Aqueous drilling fluids containing fluid loss additives
Energy Technology Data Exchange (ETDEWEB)
This patent describes an aqueous clay containing drilling fluid having present in an amount sufficient to reduce fluid loss of the drilling fluid, a copolymer of (1) from about 80% to about 98% by weight of acrylic acid and (2) from about 2% to about 20% by weight of itaconic acid. The copolymer has a weight average molecular weight of between about 50,000 to about 1,000,000, being in its free acid or partially or completely neutralized salt form and being at least water dispersible.
1987-03-03
Thermally cleavable surfactants
Energy Technology Data Exchange (ETDEWEB)
Two new surfactant molecules are reported which contain thermally labile Diels-Alder adducts connecting the polar and non-polar sections of each molecule. The two surfactants possess identical non-polar dodecyl tail segments but exhibit different polar headgroups. The surfactants become soluble in water when anionic salts are formed through the deprotonation of the surfactant headgroups by the addition of potassium hydroxide. When either surfactant is exposed to temperature above about 60.degree. C., the retro Diels-Alder reaction occurs, yielding hydrophilic and hydrophobic fragments or the aqueous solutions of the surfactants subsequently exhibit loss of all surface-active behavior.
2009-09-29
Thermally cleavable surfactants
Energy Technology Data Exchange (ETDEWEB)
Two new surfactant molecules are reported which contain thermally labile Diels-Alder adducts connecting the polar and non-polar sections of each molecule. The two surfactants possess identical non-polar dodecyl tail segments but exhibit different polar headgroups. The surfactants become soluble in water when anionic salts are formed through the deprotonation of the surfactant headgroups by the addition of potassium hydroxide. When either surfactant is exposed to temperature above about 60.degree. C., the retro Diels-Alder reaction occurs, yielding hydrophilic and hydrophobic fragments or the aqueous solutions of the surfactants subsequently exhibit loss of all surface-active behavior.
2009-11-24
Thermally cleavable surfactants
Energy Technology Data Exchange (ETDEWEB)
Two new surfactant molecules are reported which contain thermally labile Diels-Alder adducts connecting the polar and non-polar sections of each molecule. The two surfactants possess identical non-polar dodecyl tail segments but exhibit different polar headgroups. The surfactants become soluble in water when anionic salts are formed through the deprotonation of the surfactant headgroups by the addition of potassium hydroxide. When either surfactant is exposed to temperature above about 60.degree. C., the retro Diels-Alder reaction occurs, yielding hydrophilic and hydrophobic fragments and the aqueous solutions of the surfactants subsequently exhibit loss of all surface-active behavior.
2006-04-04
NPP steam generator: materials and water-chemical regime
International Nuclear Information System (INIS)
The main reasons of tube failures in steam generators (SG) are considered. 1.Stress corrosion craining which has 28% of SG (most of them have stainless steel tubes). 2. Corrosion loss of metal, which accounts for 24% of tubes (phosphate corrosion due to addition of PO into water). 3.Denting-peripheral pressing of tubes in the openings of the foundation plates by the corrosive products, which are formed on internal surface of drillings in the foundation plates made of carbon steel. 4.Separation of a plating layer on tube panels. 5.Dratting-corrosion. 6.Metal fatigue. A series of experiments were conducted to study the influence of material selection on tube reliability (stainless steel 304, inconel-600, mone-400, incalloy-800). The problem of increase of SG elements reliability is a complex one and can be solved by direct selection of material, proper control of water-chemical conditions and other ...
British Library Electronic Table of Contents (United Kingdom)
Abstract Jicama (Pachyrhizus erosus L.) is a root-based legume that has been cultivated in Mexico for centuries. Pectic polysaccharide from de-starched jicama pomace was extracted using an autoclave-assisted process and physicochemically characterized. The extracted polysaccharide (1.0 g L-1) was used for the formation of polyelectrolyte complexes (PECs) with water-soluble chitosan (WSCh; 0.5, 1.0 and 2.0 g L-1). The extraction yield of jicama pectic polysaccharide was 22.8 wt% (dry basis) and infrared spectroscopic analysis showed that it was methoxylated to a small degree. Thermogravimetric analysis indicated that this biopolymer was very stable, its weight loss being 51.2% after heating at 479 C. Anion-exchange chromatography showed it to have a wide and heterogeneous charge density. Th...
2011-01-01
Mass transfer model for two-layer TBP oxidation reactions: Revision 1
Energy Technology Data Exchange (ETDEWEB)
To prove that two-layer, TBP-nitric acid mixtures can be safely stored in the Canyon evaporators, it must be demonstrated that a runaway reaction between TBP and nitric acid will not occur. Previous bench-scale experiments showed that, at typical evaporator temperatures, this reaction is endothermic and therefore cannot run away, due to the loss of heat from evaporation of water in the organic layer. However, the reaction would be exothermic and could run away if the small amount of water in the organic layer evaporates before the nitric acid in this layer is consumed by the reaction. Provided that there is enough water in the aqueous layer, this would occur if the organic layer is sufficiently thick so that the rate of loss of water by evaporation exceeds the rate of replenishment due to mixing with the aqueous layer. Bubbles containing reaction products ...
1994-11-04
Mutations in TPRN Cause a Progressive Form of Autosomal-Recessive Nonsyndromic Hearing Loss
UK PubMed Central (United Kingdom)
We performed genome-wide homozygosity mapping in a large consanguineous family from Morocco and mapped the autosomal-recessive nonsyndromic hearing loss (ARNSHL) in this family to the DFNB79...Full Text Available
2010-03-12
British Library Electronic Table of Contents (United Kingdom)
Abstract Microbial cells are routinely dried and ground before they are used in metal biosorption studies. In this work, a metal biosorbent was prepared by drying biomass of the yeast Rhodotorula glutinis in an oven at 70C for 24-h followed by grinding. Two forms of the prepared biosorbent particles, washed and unwashed, were examined for their ability to remove lead from solution. It was found that the unwashed biosorbent exhibited higher lead uptake than the washed biosorbent. Analysis of the supernatant of washed cells incubated in water and that of unwashed cells incubated in lead solution revealed the presence of protein, carbohydrates, organic acids and inorganic phosphate. Overall, the washed and unwashed cells leached, respectively, 14.5 and 13.4% of their initial dry weight (100-m...
2011-01-01
Oxidation, volatilization, and redistribution of molybdenum from TZM alloy in air
Energy Technology Data Exchange (ETDEWEB)
The excellent high temperature strength and thermal conductivity of molybdenum-base alloys provide attractive features for components in advanced magnetic and inertial fusion devices. Refractory metal alloys react readily with oxygen and other gases. Oxidized molybdenum in turn is susceptible to losses from volatile molybdenum trioxide species, MoO{sub 3}(m), in air and the hydroxide, MoO{sub 2}(OH){sub 2}, formed from water vapor. Transport of radioactivity by the volatilization, migration, and re-deposition of these volatile species during a potential accident involving a loss of vacuum or inert environment represents a safety issue. In this report the authors present experimental results on the oxidation, volatilization and re-deposition of molybdenum from TZM in flowing air between 400 and 800 C. These results are compared with calculations obtained from a vaporization mass transfer model using ...
2000-01-01
Oxidation, Volatilization, and Redistribution of Molybdenum from TZM Alloy in Air
Energy Technology Data Exchange (ETDEWEB)
The excellent high temperature strength and thermal conductivity of molybdenum-base alloys provide attractive features for components in advanced magnetic and inertial fusion devices. Refractory metal alloys react readily with oxygen and other gases. Oxidized molybdenum in turn is susceptible to losses from volatile molybdenum trioxide species, (MoO3)m, in air and the hydroxide, MoO2(OH)2, formed from water vapor. Transport of radioactivity by the volatilization, migration, and re-deposition of these volatile species during a potential accident involving a loss of vacuum or inert environment represents a safety issue. In this report we present experimental results on the oxidation, volatilization and re-deposition of molybdenum from TZM in flowing air between 400 and 800°C. These results are compared with calculations obtained from a vaporization mass transfer model using chemical thermodynamic ...
2000-01-01
Water conservation in agriculture -a step in combating the water crisis
International Nuclear Information System (INIS)
In Pakistan, the agricultural sector is the largest water user with 95%, leaving only marginal quantities for households and industry. On one hand, agriculture is a very important sector in Pakistan's economic development, contributing about 23 % to the national GDP -but industry contributes slightly more using only about 2 % of the available water resources. As Pakistan faces a growing problem of water shortage, significant achievements in water conservation have to be materialized, predominantly on the agricultural sector. There is scope for a higher degree of efficiency in water use, as water losses, namely in irrigation, are still rather high. There is another good reason for water conservation in agriculture: Over-irrigation results in rising water tables and increased soil salinity, which has ...
2004-06-07
ALOPECIA AREATA IS NOT ASSOCIATED WITH HELICOBACTER PYLORI
UK PubMed Central (United Kingdom)
Background:Alopecia areata (AA) is an immune-mediated form of hair loss that occurs in all ethnic groups, ages, and both sexes. Helicobacter pylori has...Full Text Available
2009-01-01
Climate - air traffic emissions
Energy Technology Data Exchange (ETDEWEB)
In 1990, 176 million tonnes (mt) of air-traffic fuel was burned, which produced about 550 mt CO{sub 2}, 220 mt water, 3.5 mt NO{sub x} amd 0.18 mt SO{sub 2}. NO{sub x} emissions from air traffic may, by increasing ozone concentrations, be responsible for about 8% of global greenhouse warming. In the stratosphere NO{sub x} from aircraft is partly responsible for ozone depletion. With present technology 500 aircraft in the stratosphere would cause global ozone losses of 20%. Water vapour added by aircraft also contributes to global warming. In the form of ice crystals between 8 to 13 km above sea level, it acts as cirrus clouds. Probably the least damaging cruising altitude for aircraft is 9 km above sea level. Fuel consumption by aircraft is increasing. Air pollution abatement measures include substituting hydrogen fuel for kerosene, developing engines that emit less NO{sub x} and the introduction of ...
1991-11-01
Cooling facility for reactor container
International Nuclear Information System (INIS)
Cooling water is sprayed on the outer surface of an upper portion of a container, and a pool is formed by the cooling water flowing down while cooling the container. Further, the cooling water stored in the cooling water pool is recycled by a pump for spraying the cooling water on the outer surface of the upper portion of the container. Sufficient amount of cooling water is supplied for spraying the cooling water to the outer surface of the upper portion of the container so that the outer surface of the container is free from drying and a liquid membrane is formed on the entire surface. The amount of the cooling water is made greater than that of the cooling water evaporated when the entire amount of the heat generate in the reactor core of the reactor is ...
1993-05-07
International Nuclear Information System (INIS)
Design improvements are being incorporated into the heavy water management systems at Wolsong 2,3 and 4 to reduce the load on the vapour recovery driers and upgraders and the heavy water losses via the stack. There will also be improvements to monitor heavy water and tritium releases. This paper describes the improvements, gives background on heavy water balance mechanism, the historical trends for heavy water recovery/losses and estimated dose to the member of the public critical group resulting from the airborne and waterborne releases. The measured tritium activity levels in the heat transport system (HTS) and moderator system at Wolsong 1 are given. Using these activity levels and heavy water loss data, tritium losses from the dried and ventilated areas are estimated. A ...
1994-03-01
Energy Technology Data Exchange (ETDEWEB)
This thesis surveys the concepts of exergy and extends the exergy method of analysis from the standpoint of its applications to the power plant systems. After a brief historical review of exergy concepts, the general exergy equation is derived from the combined equation of First and Second Law, and it is shown that any special case of exergy equation is a simplified form of the general exergy equation. The mathematical method for the exergy analysis of a steady-state, steady-flow system, analogous to that of the First Law, is given. The exergy losses in a power plant are discussed. Then in order to examine these losses, the Second Law performance of major processes of combustion, compression, heat transfer, mixing and throttling have been analyzed analytically, and the exergy efficiencies are defined that accurately assess the thermodynamic performance of the corresponding processes. The methods for computation of exergy ...
1981-01-01
Energy Technology Data Exchange (ETDEWEB)
Anionic complexes of transition metals were stabilized in aqueous solutions containing high concentrations of various short-chain quaternary ammonium salts. Compounds with longer paraffin chains were effective in much less concentrated solution. Complex ions were detected spectrophotometrically. FeCl/sub 4//sup -/, which is usually formed in concentrated HCl, was the predominant Fe(III) complex in 30 m choline chloride containing only 0.12 M HCl. A yellow transitory Tc(VII) chloro-addition intermediate, formed in the reduction of TcO/sub 4//sup -/ by concentrated HCl, was stabilized when the solution also contained 25 m choline chloride. Its spectrum, as well as the isolation of an already known Tc(VII) bipyridyl complex, is reported. Concentrated organic electrolytes also stabilized Tc(V) oxide halides against disproportionation and Tc(IV) hexahalides against hydrolysis. Halochromates of Cr(VI) were formed and stabilized ...
1985-02-04
Investigation of Hg volatile losses from samples and standards during neutron activation analysis
International Nuclear Information System (INIS)
The losses of Hg from phenol formaldehyde resin - bound standards and hair samples in neutron activation analysis in case of their irradiation in the water filled nuclear reactor channel is studied. The mean losses of Hg during 20-30 hrs irradiation at (2-3)x10"1"8 n/cm"2 are 15-20% with their stopping at double Al-covers. The mean losses of Hg from standards at 200, 250 and 300 deg C are 30, 61 and 86% respectively and do not occur at 150 deg C after their 5 hour heating. The losses of Hg from hair samples packed in polyethylene tubes through the package walls in experimental conditions are not observed.
A novel domestic electric water heater model for a multi-objective demand side management program
Energy Technology Data Exchange (ETDEWEB)
This paper presents a novel domestic hot water heater model to be used in a multi-objective demand side management program. The model incorporates both the thermal losses and the water usage to determine the temperature of the water in the tank. Water heater loads are extracted from household load data and then used to determine the household water usage patterns. The benefits of the model are: (1) the on/off state of the water heater and temperature of the water in the tank can be accurately predicted, and (2) it enables the development of water usage profiles so that users can be classified based on usage behaviour. As a result, the amount of ancillary services and peak shaving that can be achieved are accurately predictable and can be maximized without adversely affecting users. (author)
2010-12-15
Energy Technology Data Exchange (ETDEWEB)
Vaarst Vestervang (Denmark) comprises 16 villas and 1 communal building. The complex was designed by the inhabitants themselves with the aim of polluting the environment as little as possible. The land area constitutes 69.000 square meters where it is possible to grass animals. The document reports a measuring programme concerning the overall heat consumption as one of the main aims of the inhabitants is to save energy and thus contribute to the protection of the environment. The capacity of the solar collectors predominantly used in the building complex was 235 kWh/m{sup 2}. Supplementary heating is provided by boilers fired with wood. The measuring system is described in detail. Tables show the influence of heat transmission losses, ventilation, airing out of rooms, the angle of the sun`s rays within the buildings and heating needs on energy consumption. Energy consumption data is presented in relation to the forms of space and ...
1993-10-01
Energy Technology Data Exchange (ETDEWEB)
This report contains a set of nomographs which can be used to estimate the average annual solar fraction for solar space and water heating at a large number of DOD facilities. The solar fraction estimated from the nomograph is in close agreement with F-Chart 3.0 and allows for variation of the following parameters: annual load, collector area, collector transmittance-absorptance coefficient, and collector overall loss coefficient.
1982-09-01
Energy Technology Data Exchange (ETDEWEB)
The very low-pressure expansion tank of the title invention is connected to the water in the central heating installation via a connecting pipe with a pump and valves on one side, and on the other side the tank is connected via a connecting pipe with valve to the tap water mains, so that the supply of water can be regulated automatically. Within the expansion tank contact with the outside air is not possible because of an air/water separating floater. By means of recording and control (also remote) of the contents of the expansion tank, the installation pressure and the quantity of supplied water from the expansion tank and the tap water mains, failures and water damage are prevented. 4 figs.
1995-09-01
British Library Electronic Table of Contents (United Kingdom)
A reduced-form model including nonlinearities is estimated from pooled data from nine European countries during 1982-2004 to show the effects of macroeconomic shocks and financial fragility on bank loan losses. The main ingredients of the model are unanticipated-output and interest-rate shocks estimated from published macroeconomic and naive forecasts. The model fits the data well, capturing the extremely high levels of loan losses witnessed in different financial crises.
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
A collection of 14 papers from a June 1981 seminar assess the costs of damage caused by water pollution. The seminar focused on the economic rather than the legal standpoint by evaluating the cost of the clean-up operations themselves and other costs, such as direct or indirect economic losses, and converting into money terms the damage to the environment, the loss of recreational facilities, and biomass losses. The papers are grouped into four sections which look at the scale of risk, the clean-up costs for specific oil spills, other costs inflicted on coastal zones, and legal aspects of compensation. Separate abstracts were prepared for each of the 16 papers selected for the Energy Data Base.
1982-01-01
Energy Technology Data Exchange (ETDEWEB)
This report compares the performance characteristics of /sup 10/B-lined and fission-neutron detectors in gamma-ray fluxes typical of the fields to be encountered during nondestructive testing of irradiated light-water fuel assemblies stored in water. Using the optimum time constants for each of the /sup 10/B-lined detectors, the 0.25-in.-dia detector had a 5% loss in neutron count sensitivity at 7000 rad/h. Similarly, the 0.5-in.-dia detector had a 7% loss at 13,000 rad/h and the 1-in.-dia detector had a 5% loss in sensitivity at 1000 rad/h. Uranium-235 fission chambers were operated successfully in fields above 100,000 rad/h with no loss in neutron counting sensitivity. Shielding calculations were done to determine the appropriate shield thickness needed for a /sup 10/B-lined neutron detector to operate in a 50,000 rad/h field, typical of ...
1985-03-01
Loss of flow accident analysis of a water-cooled fusion reactor
International Nuclear Information System (INIS)
Within the APROS simulation environment we have built a thermo-hydraulic model of a conceptual fusion power plant which is water cooled and uses lithium-lead for tritium breeding. For the safety assessment of this design we have studied an accident sequence which starts from a loss or coolant flow then leads to first wall breach and pressurisation of the vacuum vessel. Simulations have revealed strong pressure transients which can be alleviated by design changes. One goal is to verify the adequacy of the containment design: it remains intact at least 14 h without any mitigating efforts. Estimates for radioactive releases are obtained. (author)
2003-08-25
Natural convection cooling of a vertical channel
International Nuclear Information System (INIS)
An experimental program has been conducted to determine the feasibility of natural convection cooling of a reactor following a beyond-design-based accident. The particular application under consideration was the heavy-water new production reactor. The questions to be resolved include the verification that a natural convection cooling pattern would be established and the determination of the power limit for which convective cooling will occur for a significant period of time. In the experiment, the reactor configuration was simulated using small-diameter vertical heated tubes in parallel with a large-diameter bypass line. Following a loss-of-flow event, the flow in the bypass line will reverse direction and pass through the heated channel by means of natural convection. If, however, the channel power is too high, void formation will block the channel and prevent the reverse flow pattern from occurring. The test procedure involved the ...
1993-11-14
British Library Electronic Table of Contents (United Kingdom)
We present an innovative approach to estimating residential irrigation water demand for a large metropolitan area using GIS data, weather station data, and a water budget modeling approach commonly used by plant scientists and landscape management professionals. An important question addressed by our study is how a growing urban forest affects the overall irrigation water demand of a semiarid metropolitan area. To estimate the amount of water required by residential landscaping, we consider water demand to be a function of the areal extent of residential landscaping (i.e. tree/shrub or turf grass), the water-loss rate for different landscaping types, the efficiency with which the landscape is irrigated, and local climatic factors (i.e. reference evapotranspiration and precipitation). We es...
2011-01-01
A new Nitrogen Index to evaluate nitrogen losses in intensive forage systems in Mexico
British Library Electronic Table of Contents (United Kingdom)
Although nitrogen inputs to agricultural fields are necessary for global food sustainability, they present a major nutrient management challenge, because nitrogen inputs can increase nitrogen losses to the environment, which can negatively impact water quality across key surface and groundwater resources. The need to evaluate the potential risk of nitrogen losses for a given forage type, management scenario, and field quickly and easily can be met with new tools that assist in environmental risk assessment. An example is the Mexico Nitrogen Index: this new tool aims to help its users quickly evaluate the risk of nitrogen loss for a given field under a given set of management practices. The objective of this study was to evaluate the accuracy of the Mexico Nitrogen Index in ranking the risk...
2011-01-01
Characterizations of passive films formed on stainless steel in high temperature water
International Nuclear Information System (INIS)
Surface study techniques were used to investigate films on Type 304 stainless steel which were formed during exposure to high purity water at 288"0C. The results indicated that the film chemistry depended strongly upon the concentration of the dissolved O_2 in the water. Films formed in water having 8 ppm O_2 were stoichiometric mixed oxides; whereas those formed in water with 10 ppb O_2 were highly defective oxyhydroxides. The latter films are not as protective as the stoichiometric oxides. Auger electron spectroscopy (AES) and X-ray photoelectron spectroscopy (XPS) were used to investigate the films. (Auth.).
1983-06-03
Energy Technology Data Exchange (ETDEWEB)
For light water reactors, loss of coolant is an important point in safety analysis, whereas for gas-cooled reactors the ingress of water into the core region is an incident of safety relevance. The applicability of the computer code system GAMTEREX to pebble beds of spherical high-temperature gas-cooled reactor fuel elements with simulated water ingress is verified by experiment. The measurements were performed at a Siemens-Argonaut reactor, using its ring core as a driver zone for a pebble-bed core in the center of the reactor.
1987-09-01
Rapid preparation of pyrogen-free 2H2(18)O for human-nutrition studies
International Nuclear Information System (INIS)
We describe a compact ultrafiltration system for the removal of pyrogens and bacteria from water labeled with the stable isotopes of deuterium and oxygen-18. The ultrafiltration system is constructed from readily available commercial components and can achieve complete removal of pyrogens and bacteria from 1L contaminated water within 30 min. By use of our procedure, loss of the isotopically labeled water by retention in the filtration system was minimal. The purified water is suitable for both oral and intravenous administration to healthy human subjects participating in nutrition studies.
Agriculture as a source of phosphorus for eutrophication in southern Europe
British Library Electronic Table of Contents (United Kingdom)
Abstract Large areas of the southern European countries possess a Mediterranean climate, which influences soil properties, land use, fertilizer application practices and pathways of phosphorus (P) loss from agricultural soils. On average, inputs of fertilizer P exceed P exports from the agricultural areas in these countries; however, large differences in P surplus/deficit and soil P test values exist among regions. Losses of P in drainage water are modest except in some irrigated areas and in those regions where intensive animal production is concentrated. Losses of P in runoff water, whether as dissolved reactive or particulate P, can be substantial as a result of the significance of erosive processes under the land uses typical of the Mediterranean region, where extreme rainfall events c...
2007-01-01
Characterization of arsenic dose loss at the Si/SiO{sub 2} interface
Energy Technology Data Exchange (ETDEWEB)
Careful sample preparation and secondary ion mass spectroscopy have been used to characterize arsenic dose loss to the silicon-oxide interface. Using high resolution x-ray photoelectron spectroscopy for microprofiling, we have directly observed the pileup of arsenic at the silicon dioxide-silicon interface. At least half of the pileup is shown to be on the silicon side of the interface in the first monolayer of silicon. Monolayer chemical oxidation and etching are successfully used to profile this pileup in silicon. This pileup contains most of the arsenic dose loss that occurs during transient enhanced diffusion. This result is crucial to correctly model the dose loss and provides physical justification for using a trap/detrap model at the interface, which is necessary to account for the fact that the arsenic surface concentration remains constant during an anneal and the fact that the dose loss is ...
2000-03-01
Characterization of arsenic dose loss at the Si/SiO_2 interface
International Nuclear Information System (INIS)
Careful sample preparation and secondary ion mass spectroscopy have been used to characterize arsenic dose loss to the silicon-oxide interface. Using high resolution x-ray photoelectron spectroscopy for microprofiling, we have directly observed the pileup of arsenic at the silicon dioxide-silicon interface. At least half of the pileup is shown to be on the silicon side of the interface in the first monolayer of silicon. Monolayer chemical oxidation and etching are successfully used to profile this pileup in silicon. This pileup contains most of the arsenic dose loss that occurs during transient enhanced diffusion. This result is crucial to correctly model the dose loss and provides physical justification for using a trap/detrap model at the interface, which is necessary to account for the fact that the arsenic surface concentration remains constant during an anneal and the fact that the dose loss is ...
2000-03-01
The role of water and oxygen impurities on ozone production in a negative corona discharge of CO_2
International Nuclear Information System (INIS)
The production of ozone in a negative corona discharge fed by carbon dioxide with embedded traces of oxygen and water has been studied. The presence of traces of oxygen in both pure and dry CO_2 leads to an increase in nascent ozone concentrations. In contrast, traces of water vapour (0-800 ppm) are shown to rapidly suppress ozone concentrations with the largest decreases being observed at lowest gas pressures in the discharge (300 Torr). The presence of water vapour did not considerably affect the electrical properties of negative dc corona suggesting that a chemical process is responsible for the ozone loss. We have shown that the addition of water up to a concentration of 1500 ppm has only a marginal effect on the processes of ozone formation but the catalytic cycle of ozone destruction involving OH radicals can be the reason for observed decrease in the total ozone concentration ...
2007-11-07
International Nuclear Information System (INIS)
(Cu_4_7Zr_1_1Ti_3_4Ni_8)_1_0_0_-_xMo _x bulk metallic glasses (BMGs) with x = 0, 1 and 2 at.% and a bulk metallic glass matrix composite with x = 5 at.% were successfully prepared by water-cooled copper mold casting. The effect of the addition of a small amount of Mo on the glass forming ability (GFA), thermal properties of the base alloy (i.e. x = 0) were investigated by X-ray diffraction (XRD), differential scanning calorimetry (DSC) and differential thermal analyzer (DTA). It is found that the addition of appropriate amount of Mo can enhance the GFA of the Cu-based BMG, as indicated by the increase in the reduced glass transition temperature T _r_g (=T _g/T _l) and the parameter #gamma# (=T _x/(T _g + T _l)) with the increase of Mo. On the other hand, the corrosion resistance of the Cu-based BMGs with different Mo contents was examined by electrochemical polarization and weight loss measurement in 1 mol/L H_2SO_4 and 1 ...
2006-05-05
Energy Technology Data Exchange (ETDEWEB)
A set of nomographs is presented which can be used to estimate the average annual solar fraction for solar space and water heating at a large number of DOD facilities. The solar fraction estimated from the nomograph is in close agreement with F-Chart 3.0 and allows for variation of the following parameters: annual load, collector area, collector transmittance-absorptance coefficient, and collector overall loss coefficient.
1982-09-01
Simplified solar fraction estimation for space and water heating at DOD installations. Final report
Energy Technology Data Exchange (ETDEWEB)
A set of nomographs is provided which can be used to estimate the average annual solar fraction for solar space and water heating at a large number of DOD facilities. The solar fraction estimated from the nomograph is in close agreement with F-Chart 3.0 and allows for variation of the following parameters: annual load, collector area, collector transmittance-absorption coefficient, and collector overall loss coefficient.
1982-09-01
An evaluation of the thickness and emittance of aluminum oxide films formed in low-temperature water
Energy Technology Data Exchange (ETDEWEB)
The emittance of aluminum components exposed to low-temperature aqueous solutions were required for thermal analysis of a Loss of Cooling Accident for the Savannah River Site production reactors. Experimental data for the thickness and emittance of oxide films formed under these conditions were collected and reviewed. Correlations were developed for the oxide film thickness and corresponding total hemispherical emittance. Film thickness and emittance were also measured for the specific conditions of interest in order to verify the predictions based on the literature data. After one year of exposure in 30deg C reactor moderator, the aluminum oxide film thickness is predicted to be 6.4 [mu]m[+-]10%; this value is relatively insensitive to exposure time. Some phenomena which would tend to yield thicker oxide films in the reactor environment relative to those obtained under experimental conditions were neglected, and the predicted film thickness ...
1993-02-01
An evaluation of the thickness and emittance of aluminum oxide films formed in low-temperature water
International Nuclear Information System (INIS)
The emittance of aluminum components exposed to low-temperature aqueous solutions were required for thermal analysis of a Loss of Cooling Accident for the Savannah River Site production reactors. Experimental data for the thickness and emittance of oxide films formed under these conditions were collected and reviewed. Correlations were developed for the oxide film thickness and corresponding total hemispherical emittance. Film thickness and emittance were also measured for the specific conditions of interest in order to verify the predictions based on the literature data. After one year of exposure in 30deg C reactor moderator, the aluminum oxide film thickness is predicted to be 6.4 #mu#m#+-#10%; this value is relatively insensitive to exposure time. Some phenomena which would tend to yield thicker oxide films in the reactor environment relative to those obtained under experimental conditions were neglected, and the predicted film thickness ...
Energy Technology Data Exchange (ETDEWEB)
Three reactive materials were evaluated at laboratory scale to identify the optimum treatment reagent for use in a Permeable Reactive Barrier Treatment System at Rocky Flats Environmental Technology Site (RFETS). The contaminants of concern (COCS) are uranium, TCE, PCE, carbon tetrachloride, americium, and vinyl chloride. The three reactive media evaluated included high carbon steel iron filings, an iron-silica alloy in the form of a foam aggregate, and a peculiar humic acid based sorbent (Humasorb from Arctech) mixed with sand. Each material was tested in the laboratory at column scale using simulated site water. All three materials showed promise for the 903 Mound Site however, the iron filings were determined to be the least expensive media. In order to validate the laboratory results, the iron filings were further tested at a pilot scale (field columns) using actual site water. Pilot test results were similar to ...
2000-01-01
UK PubMed Central (United Kingdom)
Though central to our understanding of how roots perform their vital function of scavenging water and solutes from the soil, no direct genetic evidence currently exists to support the foundational model...Full Text Available
2009-05-01
Evaluation of tritiated water retention capacity of fusion reactor concrete building
Energy Technology Data Exchange (ETDEWEB)
In this paper the diffusion of tritiated water vapor into concrete walls is studied to evaluate tritiated water retention capacity of a fusion reactor concrete building. Using a model of the tritiated water diffusion determined form experimental results, depth profiles of tritiated water in concrete are calculated in the case of being exposed to air containing tritiated water vapor during the normal operational condition of a fusion reactor. A 0.5-m-thick concrete is sufficient for reactor hall walls from a viewpoint of the tritium containment.
1992-03-01
Evaluation of tritiated water retention capacity of fusion reactor concrete building
International Nuclear Information System (INIS)
In this paper the diffusion of tritiated water vapor into concrete walls is studied to evaluate tritiated water retention capacity of a fusion reactor concrete building. Using a model of the tritiated water diffusion determined form experimental results, depth profiles of tritiated water in concrete are calculated in the case of being exposed to air containing tritiated water vapor during the normal operational condition of a fusion reactor. A 0.5-m-thick concrete is sufficient for reactor hall walls from a viewpoint of the tritium containment.
Energy Technology Data Exchange (ETDEWEB)
Lead is a heavy metal which is widely used in paint industry, pigments, dyes, electrical components and electronics, plastic chemicals and in various other things. Since some of the lead salts are soluble in water, lead presents a potential threat to aquatic organisms. Studies dealing with invertebrates include those on mortality, growth and lead uptake in Lymnaea palustris and bioaccumulation of heavy metals in oysters and mussels. Little information exists regarding the effect of lead on the fresh water crustaceans. Hence the present investigation has been undertaken to study the uptake and loss of lead on exposure to subtoxic levels or organic and inorganic lead.
1987-07-01
International Nuclear Information System (INIS)
Soil erosion by water is recognised as a major soil degradation process that requires a global approach. Large regions all over the world are in need of integrated conservation strategies that sustainable prevent and remediate soil erosion. therefore, quantitative and globally interpretable data are needed in support of models and decision making. the effects of various soil and water conservation techniques (SWCT) on runoff and soil loss in Europe have been extensively studied over the last 60 years. Runoff plots are the most widely used measurement technique to study the effects of SWCT on runoff and soil loss by water erosion. Hence, many data are available. However, the insights gained hereby remain mostly local and often qualitative whereas the full potential of the available data is not exploited yet. This is mainly due to the fragmentation of knowledge and extrapolation ...
General corrosion of ALLOY 800 in high temperature water and its prevention
Energy Technology Data Exchange (ETDEWEB)
General corrosion behavior of ALLOY 800 in high temperature water was studied in relation to its surface film structure. The surface film formed in water was found to decrease the corrosion rate of ALLOY 800. This film is composed of Ni ferrite, and can be obtained by oxidation in air or steam. Based on these results, air or steam oxidation treatment to inhibit Ni and Co release of ALLOY 800 into high temperature water is proposed. (author).
1989-10-01
General corrosion of ALLOY 800 in high temperature water and its prevention
International Nuclear Information System (INIS)
General corrosion behavior of ALLOY 800 in high temperature water was studied in relation to its surface film structure. The surface film formed in water was found to decrease the corrosion rate of ALLOY 800. This film is composed of Ni ferrite, and can be obtained by oxidation in air or steam. Based on these results, air or steam oxidation treatment to inhibit Ni and Co release of ALLOY 800 into high temperature water is proposed. (author).
Energy Technology Data Exchange (ETDEWEB)
Ultratrace analysis of mercury in rain water has been investigated, including recovery of ionic mercury with the addition of acids, treatment and storage and stability studies of mercury in rain water. Recovery of ionic mercury from rain water samples increased with increased acid concentrations and increased substantially with UV-irradiation. Recovery of ionic mercury in the presence of different acids was compared. Treatment studies of rain water for the analysis of total mercury were done using different decomposition methods. More than 20% of the total mercury was found in rain water residue after filtration through 0.45 ..mu..m membrane filters. Methylmercury (MM) content in filtered and unfiltered rain water however was nearly the same. On long term storage of rain water without acids at pH = 2.0 and 4.5 loss of ...
1987-03-01
Residual water losses during determination of total water content in brown coal
Energy Technology Data Exchange (ETDEWEB)
Discusses Czechoslovak regulations for determining moisture content in brown coal. Standard formulae for determining total moisture content and residual water content are described. Factors that influence accuracy in determining moisture content under laboratory conditions are analyzed: brown coal type, season of the year, air humidity, method and duration of coal sample drying, number of coal samples simultaneously dried in 1 dryer, ash content of coal. On the basis of analysis recommendations for a modified method of determining moisture content in brown coal are made. 5 refs.
1988-01-01
A mathematical model for simulating shallow solar ponds for treatment of industrial wastewater
Energy Technology Data Exchange (ETDEWEB)
This paper presents a mathematical model to analyze the solar evaporation in a shallow pond in steady state, when the inlet flow rate, concentration, surface area and solar radiation are given. The simultaneous heat and mass transfer mechanisms are considered for quantifying the amount of evaporated water to the atmosphere and the actual absorbed heat by wastewater is calculated to obtain the bottom temperature of water pond. The heat losses to air by radiation and convection mechanisms are considered and the heat transmission across the water film is evaluated by the forced convection mechanism. 6 refs., 5 figs., 1 tab.
1996-12-31
British Library Electronic Table of Contents (United Kingdom)
In preparation for studying the hydrolytic degradation of Estane 5703 in the plastic-bonded explosive PBX 9501, the sorption (solubility) and diffusion of water in PBX 9501 and each of its components are studied experimentally and modeled theoretically. Experiments are reported that measure the weight gain or loss due to a change in the relative humidity (RH). For all of the components, the equilibrium amount of water sorbed per gram of sample is linear in the RH at low relative humidities but curves upwards at higher relative humidities. This behavior is modeled with a water cluster model. Diffusion coefficients are determined by modeling the time dependence of the water concentrations assuming Fickian diffusion, and that fits the data for some of the materials. However, all the samples t...
2007-01-01
Calculation of eddy current losses in metal parts of power transformers
Energy Technology Data Exchange (ETDEWEB)
To maintain quality, performance and competitiveness, the eddy current losses in metal parts of power transformers in the range of 50-200 MVA are investigated in a more detailed form. The finite element calculations utilize different modelling strategies for the current carrying metal parts. Several global and local results are further used to obtain simplified calculation approaches for an inclusion in the initial design and the design optimization. The results from two finite element approaches using nodal and edge based formulations will be compared with measurements. (Author)
2003-04-01
Understanding the operation and use of high temperature electrochemical corrosion rate probes
Energy Technology Data Exchange (ETDEWEB)
Electrochemical corrosion rate probes were constructed and tested along with mass loss coupons in a N2/O2/CO2 plus water vapor environment. Temperatures ranged from 450 to 600 C. Corrosion rates for ash-covered mild steel, 304L SS, and 316L SS probes using electrochemical techniques were a function of time, temperature, and process environment. Correlation between electrochemical and mass loss corrosion rates was good.
2004-01-01
Energy Technology Data Exchange (ETDEWEB)
This report is a summary of the contribution of nitrogen and phosphorus in the eutrophication process of inland and coastal waters. Special attention was paid to the mechanisms of these nutrients in regulating biological processes and to the methods available in estimating their effects in the eutrophication of water bodies. The report includes five chapters which are entitled: Introduction, which is a general background to the subject with special attention to the requirements of the Finnish Water Act. Phosphorus and nitrogen as factors regulating biological processes. The topics included are: definition of eutrophication, forms of phosphorus and nitrogen and their sources to inland and coastal waters, effects of these nutrients as growth factors of phytoplankton and macrophytes and consequences of eutrophication. Estimation of the effects of phosphorus and nitrogen. The topics ...
1992-01-01
Performance of single cylinder, direct injection diesel engine using water fuel emulsions
Energy Technology Data Exchange (ETDEWEB)
A single cylinder diesel engine study of water-in-diesel emulsions was conducted to investigate the effect of water emulsification on the engine performance and gases exhaust temperature. Emulsified Diesel fuels of 0, 5, 10, 15 and 20 water/diesel ratios by volume were used in a single cylinder, direct injection diesel engine, operating at 1200-3300 rpm. The results indicate that the addition of water in the form of emulsion improves combustion efficiency. The engine torque, power and brake thermal efficiency increase as the water percentage in the emulsion increases. The average increase in the brake thermal efficiency for 20% water emulsion is approximately 3.5% over the use of diesel for the engine speed range studied. The proper brake specific fuel consumption and gases exhaust temperature decrease as the percentage of ...
2004-03-01
Analysis of the omnium-g receiver
Energy Technology Data Exchange (ETDEWEB)
A thermal analysis of the Omnium-G receiver is presented and the technique is shown to be generally applicable to solar thermal receivers utilizing a directly heated thermal mass. The thermal loss coefficient, including reradiation losses, is calculated and shown to agree quite well with the experimentally measured thermal loss coefficient. The rate of heat transfer to the working fluid is also analyzed and the analysis is used to show that the Omnium-G receiver is well matched to the water/steam working fluid because the steam outlet temperature is almost the same as the receiver temperature. A general procedure for calculating receiver performance is presented. With this procedure, the energy delivery to any working fluid, the delivered temperature of the working fluid, and the pressure drop through the receiver can be determined. An example of the calculation is also presented.
1980-03-01
Strong and Tunable Nonlinear Optomechanical Coupling in a Low-Loss System
A major goal in optomechanics is to observe and control quantum behavior in a system consisting of a mechanical resonator coupled to an optical cavity. Work towards this goal has focused on increasing the strength of the coupling between the mechanical and optical degrees of freedom; however, the form of this coupling is crucial in determining which phenomena can be observed in such a system. Here we demonstrate that avoided crossings in the spectrum of an optical cavity containing a flexible dielectric membrane allow us to realize several different forms of the optomechanical coupling. These include cavity detunings that are (to lowest order) linear, quadratic, or quartic in the membrane's displacement, and a cavity finesse that is linear in (or independent of) the membrane's displacement. All these couplings are realized in a single device with extremely low optical loss and can be tuned over a wide range in situ; in ...
2010-01-01
Isolation condenser passive cooling of a nuclear reactor containment
Energy Technology Data Exchange (ETDEWEB)
This patent describes a nuclear system comprising a containment airspace in which a nuclear reactor pressure vessel is disposed there being a reactor core within the pressure vessel. It comprises a heat exchanger elevated a distance above the pressure vessel; a pool of water surrounding the heat exchanger; means for venting the pool of water to an environment outside the containment; a heat exchanger entry conduit within the containment, the entry conduit having an open lower end communicating with the containment space, and an upper end connected to the heat exchanger, water-containing heated fluid present in the containment airspace incident a pressure vessel loss of coolant event entering and flowing through the entry conduit into the heat exchanger for cooling the fluid to convert water vapor therein to a condensate and separate non-condensable gasses therefrom; a gravity driven ...
1991-10-22
Energy Technology Data Exchange (ETDEWEB)
The steam generator low water level trip setpoint of KORI NPP units 3 and 4(KNU 3 and 4), three-loop Westinghouse pressurized water reactor, is higher than that of OPR1000. In addition, steam generator downcomer water level in KNU 3 and 4 could fluctuate easily during a transient because of smaller downcomer water inventory, compared to the total water inventory in the steam generator. Due to these reasons, there is a higher possibility of unnecessary reactor trips caused by the steam generator low-low water level in KNU 3 and 4. Its operating history shows that most of reactor trips were caused by steam generator low-low level reactor trip signal. Such reactor trips, especially unnecessary ones, result in time and economic losses. In this paper, a feasibility study was performed to reduce unnecessary reactor trip by changing steam generator ...
2008-10-15
International Nuclear Information System (INIS)
The steam generator low water level trip setpoint of KORI NPP units 3 and 4(KNU 3 and 4), three-loop Westinghouse pressurized water reactor, is higher than that of OPR1000. In addition, steam generator downcomer water level in KNU 3 and 4 could fluctuate easily during a transient because of smaller downcomer water inventory, compared to the total water inventory in the steam generator. Due to these reasons, there is a higher possibility of unnecessary reactor trips caused by the steam generator low-low water level in KNU 3 and 4. Its operating history shows that most of reactor trips were caused by steam generator low-low level reactor trip signal. Such reactor trips, especially unnecessary ones, result in time and economic losses. In this paper, a feasibility study was performed to reduce unnecessary reactor trip by changing steam generator ...
2008-10-01
International Nuclear Information System (INIS)
Purpose: To remove excessive driving pressure applied to an unisolated control rod drive by returning excessive coolant to a condensed water storage tank or to the inlet side of a drive water pump using a coolant flow rate control pipe of a control rod driving hydraulic system. Constitution: Excessive water is returned to a condensed water tank while controlling the excessive coolant by a flow control valve in response to variations in the pressure difference between the reactor pressure and the driving water line when the control rods are isolated using a pipe from the outlet side of the drive water pump to the condensed water storage tank. Thus, the control rod to be isolated is prevented form being dropped. (Sekiya, K.).
... This is true because a shorter residence time means that ground water moves 'faster.' Thus, contamination will get to the drinking well from the recharge area (point of entry) faster if the ground water is younger. However, it has been difficult to measure the exact age of young ground water. The conventional indicator has been tritium, a radioactive form of hydrogen, but its ...
Processing of LiBH{sub 4} from its elements by ball milling method
Energy Technology Data Exchange (ETDEWEB)
Investigations of alternative renewable energy resources continue, with many studies concentrating on hydrogen storage. However, there are a few problems such as storage, transportation, delivery to the user and usage safely, to be addressed to facilitate commercialization and wide usage of the hydrogen. The absorbed form within the metal hydrides seems to be the best solution of this problem. Since Li is the lightest metal, it has the advantage as the stored amount of hydrogen mass ratio. LiBH{sub 4} production process was investigated using elemental Li, B and H{sub 2}. Spex type ball milling with tungsten carbide, stainless steel and zirconia type vessels, was used to mix the different amount of Li and B under argon atmosphere. X-ray diffraction pattern demonstrated that the LiB was obtained. A system was designed to provide a hydrogen atmosphere of 60 bars to force hydrogen into the LiB structure. FTIR analysis strongly indicated the LiBH{sub 4} compound when ...
2008-11-15
Nitrogen utilization during spring phytoplankton bloom development in the southeast Bering Sea
Energy Technology Data Exchange (ETDEWEB)
Interactions beween a high latitude, continental shelf, spring phytoplankton bloom and water column physics and chemistry were studied using /sup 15/N measured rates of nitrogen uptake. Peak bloom conditions commenced when the mixed layer shallowed and minimized respirational losses. Integrative light-mixing growth models were accurate during early bloom stages. An advection-diffusion model associated peak bloom nitrate uptake with pycnocline mixing rates of 2.1 m d/sup -1/ in an 18 m mixed layer. Maximum nitrogen specific uptake rates (hr/sup -1/), unlike those of carbon, coincided with peak bloom conditions. Although species compositions among peak bloom periods were similar, particulate C/N ratios were not. Apparently, both intercellular factors and prevailing mixing conditions influence specific uptake rates and cell composition. A large proportion of new (nitrate) to total productivity was associated with the dominance of the early bloom ...
1983-01-01
British Library Electronic Table of Contents (United Kingdom)
The effect of phosphonate anion (PHOS) on the corrosion of ordinary steel in simulated cooling water has been studied using weight loss, polarization curves and electrochemical impedance spectroscopy measurements. PHOS was studied in the concentration range from 7.5x10^-^5 to 10^-^3M. The results obtained reveal that PHOS perform excellently as corrosion inhibitor for ordinary steel in simulated cooling water. The inhibition efficiency of PHOS was increased with increasing both its concentration and water circulation velocity. These two factors seem to promote the adsorption of phosphorus and oxygen ions on the metal surface, leading to the formation of a protective layer with a greater charge transfer resistance and lower permeability. The inhibition efficiency decreased slightly with tem...
2010-01-01
Post-lens tear-film depletion due to evaporative dehydration of a soft contact lens
British Library Electronic Table of Contents (United Kingdom)
For a soft-contact-lens (SCL) wearer, corneal health and comfort are strongly influenced by water transport through the polymeric materials used in lens fabrication. In particular, evaporative water loss at the anterior lens surface is a potential cause of contact-lens dehydration and of post-lens tear-film depletion, which in turn, may lead to discomfort, dryness syndrome, and/or lens adhesion.We present a solution-diffusion model for transport of water through soft-contact-lens materials to mimic evaporative dehydration from a contact lens during blinking and to access possible SCL adhesion to the corneal surface under a variety of environmental conditions (e.g., wind speed and relative humidity). To describe the water-transport process, we use an extended version of the Maxwell-Stefan m...
2006-01-01
Exergy analysis of the solar multi-effect humidification?dehumidification desalination process
British Library Electronic Table of Contents (United Kingdom)
An exergy analysis method is presented of the solar multi-effect humidification?dehumidification desalination (HDD) process. Pinch technology is used in the humidification process to determine the maximum possible saturated air temperature and the temperature of water rejected from the unit, and then the dehumidification process to determine the temperature of water leaving from the heat exchanger. The formulae to calculate the exergy of water and saturated air are given. The solar plane collector is used. From exergy analysis, the solar collector has the lowest exergy efficiency; the HDD process has a lower exergy efficiency, and the water rejected has also a large exergy loss. The energy and exergy recovery rate of the desalination process is also lower. The solar multi-effect HDD proces...
2007-01-01
International Nuclear Information System (INIS)
An electrochemistry model was developed to analyse the J-V characteristics of a Proton Exchange Membrane (PEM) water electrolyzer for hydrogen production. The Butler-Volmer equation and water transport characteristics through electrolyte membrane were employed to simulate the electrode activation over-potential and membrane ohmic over-potential, respectively. The modeling results are found to agree reasonably well with experimental data published in the literature. The parametric simulations show that the ohmic over-potential is relatively small with typical water content in the membrane. Compared with the cathode over-potential, the anode over-potential is more significant and constitutes the major source of voltage loss. The high anode over-potential is due to the relatively slow oxidation kinetics, which is related to anode material property and microstructure. This model can be integrated with a ...
2006-06-13
British Library Electronic Table of Contents (United Kingdom)
Phreatic groundwater pumping is affecting water availability for crops in areas with a shallow water table. This can reduce crop growth and so affect farm income. There is a need for a generic and transparent method to assess the agricultural damage caused by water table drawdown. This paper proposes such a method that consists of 'damage tables' relating agricultural production losses to the groundwater regime for different soil/crop combinations found in Northern Belgium. The damage tables are constructed based on numerous simulations with the agrohydrological model SWAP, in which the bottom boundary conditions are gradually changed to reflect different groundwater regimes. The credibility of the resulting metamodel is assessed in three ways: using (1) field data, (2) an existing local e...
2010-01-01
British Library Electronic Table of Contents (United Kingdom)
Bothriochloa ischaemum L. and Lespedeza davurica (Laxm.) Schindl. are two co-dominant species of great importance in reducing soil and water loss and maintaining the distinctive natural scenery of the semiarid Loess Plateau of China. Our aim was to determine the growth and interspecific competition between these species under water stress to facilitate the prediction of community succession and guide the selection of appropriate methods of conservation and use in the area. A pot experiment was designed to investigate the effects of water stress and competition on biomass production and allocation, relative competitive ability and water use efficiency of the two species. Bothriochloa ischaemum (a C4 perennial herbaceous grass) was planted in the same pot with L. davurica (a C3 perennial leg...
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
High energy radiation was studied as a means for destroying hazardous organic chemical wastes. Tests were conducted at bench scale with a {sup 60}Co source, and at full scale (387 l/min) with a 1.5 MV electron beam source. Bench scale tests for both benzene and phenol included 32 permutations of water quality factors. For some water qualities, as much as 99.99% of benzene or 90% of phenol were removed by 775 krads of {sup 60}Co irradiation. Full scale testing for destruction of benzene in a simulated waste-water mix showed loss of 97% of benzene following an 800 krad dose and 88% following a 500 krad dose. At these loss rates, approximately 5 Mrad of electron beam irradiation is required to reduce concentrations from 100 g/l to drinking water quality (5 {mu}g/l). Since many waste streams are also inhabited by bacterial populations which may affect filtering ...
1993-08-01
The use of water-soluble hydrazones as inhibitors for the corrosion of C-steel in acidic medium
Energy Technology Data Exchange (ETDEWEB)
Inhibition efficiency of some water-soluble hydrazones for C-steel corrosion in hydrochloric acid has been tested by weight loss, polarisation measurements and open circuit technique. The inhibition effect was attributed to the adsorption of the additives on the C-steel surface as supported by adsorption measurements at Pt electrode using cyclic voltammetry. Electrochemical measurements indicated that all the additives behave as cathodic-type inhibitors. The data obtained fit well to both the Temkin adsorption isotherm and the kinetic-thermodynamic model. The inhibition behaviour and its order were explained with the help of the proposed skeletal representation.
2007-09-15
SCDAP/RELAP5/MOD 3.1 code manual: Interface theory. Volume 1
Energy Technology Data Exchange (ETDEWEB)
The SCDAP/RELAP5 code has been developed for best estimate transient simulation of light water reactor coolant systems during a severe accident. The code models the coupled behavior of the reactor coolant system, core, fission product released during a severe accident transient as well as large and small break loss of coolant accidents, operational transients such as anticipated transient without SCRAM, loss of off-site power, loss of feedwater, and loss of flow. A generic modeling approach is used that permits as much of a particular system to be modeled as necessary. Control system and secondary system components are included to permit modeling of plant controls, turbines, condensers, and secondary feedwater conditioning systems. This volume describes the organization and manner of the interface between severe accident models which are resident in the SCDAP portion of the code and ...
1995-06-01
RELAP5/MOD3 code manual. Volume 4, Models and correlations
International Nuclear Information System (INIS)
The RELAP5 code has been developed for best-estimate transient simulation of light water reactor coolant systems during postulated accidents. The code models the coupled behavior of the reactor coolant system and the core for loss-of-coolant accidents and operational transients such as anticipated transient without scram, loss of offsite power, loss of feedwater, and loss of flow. A generic modeling approach is used that permits simulating a variety of thermal hydraulic systems. Control system and secondary system components are included to permit modeling of plant controls, turbines, condensers, and secondary feedwater systems. RELAP5/MOD3 code documentation is divided into seven volumes: Volume I presents modeling theory and associated numerical schemes; Volume II details instructions for code application and input data preparation; Volume III presents the results of developmental ...
1995-08-05
Mass transfer model for two-layer TBP oxidation reactions
Energy Technology Data Exchange (ETDEWEB)
To prove that two-layer, TBP-nitric acid mixtures can be safely stored in the canyon evaporators, it must be demonstrated that a runaway reaction between TBP and nitric acid will not occur. Previous bench-scale experiments showed that, at typical evaporator temperatures, this reaction is endothermic and therefore cannot run away, due to the loss of heat from evaporation of water in the organic layer. However, the reaction would be exothermic and could run away if the small amount of water in the organic layer evaporates before the nitric acid in this layer is consumed by the reaction. Provided that there is enough water in the aqueous layer, this would occur if the organic layer is sufficiently thick so that the rate of loss of water by evaporation exceeds the rate of replenishment due to mixing with the aqueous layer. This report presents measurements of mass ...
1994-09-28
Energy Technology Data Exchange (ETDEWEB)
Loss of organic matter is one of the main forms of soil degradation in Mediterranean agricultural soils, and external sources of organic matter are required to improve soil properties. the two-phase centrifugation system in the olive-oil extraction industry produces a large amount of olive mill waste sludge (TPOMW) which can be used to add organic C to degraded soils. (Author)
2009-07-01
Fundamental aspects of gas-liquid flows
Energy Technology Data Exchange (ETDEWEB)
This book presents the papers given at a conference on two-phase flow. Topics considered at the conference included the thermal hydraulics of a feedwater pipe breakage, pressure losses, measurement of void fraction in a rod bundle, laminar filmwise condensation, natural circulation, flow models, bubble dynamics, cavitation, water hammer, and heat transfer augmentation.
1985-01-01
Fundamental aspects of gas-liquid flows
International Nuclear Information System (INIS)
This book presents the papers given at a conference on two-phase flow. Topics considered at the conference included the thermal hydraulics of a feedwater pipe breakage, pressure losses, measurement of void fraction in a rod bundle, laminar filmwise condensation, natural circulation, flow models, bubble dynamics, cavitation, water hammer, and heat transfer augmentation.
1985-11-17
FB-Line resin testing final report
Energy Technology Data Exchange (ETDEWEB)
The Dowex 50W-X8 and 50W-Xl2 resin samples are both strong acid cation materials in the hydrogen form. Each material has a water retention capacity characteristic of its respective marketed degree of cross-linking. Dowex 21K gives confirmatory responses to tests for a strong anion exchange resin in the nitrate form. All three resins have the manufacturer's specified ionic type and form, and the Dowex 50W resins have characteristic water retention capacities. These tests conclude that the ion exchange resins in use in FB-Line meet the approved safety document criteria for cross-linking, ionic form, and resin type.
1992-01-23
FB-Line resin testing final report
Energy Technology Data Exchange (ETDEWEB)
The Dowex 50W-X8 and 50W-Xl2 resin samples are both strong acid cation materials in the hydrogen form. Each material has a water retention capacity characteristic of its respective marketed degree of cross-linking. Dowex 21K gives confirmatory responses to tests for a strong anion exchange resin in the nitrate form. All three resins have the manufacturer`s specified ionic type and form, and the Dowex 50W resins have characteristic water retention capacities. These tests conclude that the ion exchange resins in use in FB-Line meet the approved safety document criteria for cross-linking, ionic form, and resin type.
1992-01-23
Energy Technology Data Exchange (ETDEWEB)
Experiments were performed to measure the transfer of trichloroethylene (TCE), a volatile organic compound (VOC), from tap water in showers to indoor air. In these experiments, the loss of TCE from tap water in the shower is based on the difference between influent and effluent concentrations.We have developed and previously published a three-compartment model, which we use to simulate the 24-h concentration history of VOCs in the shower, bathroom, and remaining household volumes resulting from the use of contaminated tap water. An important input to this model is the transfer efficiency of the VOC from water to air. The experiments reveal that the transfer efficiency of TCE from shower water to air has an arithmetic mean value of 51 percent and an arithmetic standard deviation of 9 percent. Analysis of the results shows that there is no statistically ...
1991-08-01
Sustainable water resources management in Pakistan
International Nuclear Information System (INIS)
Total river discharge in Pakistan in summer season vary from 3 thousand to 34 thousand cusses (100 thousand Cusses to 1,200 thousand Cusses) and can cause tremendous loss to human lives, crops and property, this causes the loss of most of the flood water in the lower Indus plains to the sea. Due to limited capacity of storage at Tarbela and Mangla Dams on river Indus and Jhelum, with virtually no control on Chenab, Ravi and Sutlej, devastating problems are faced between July and October in the event of excessive rainfall in the catchments. Due to enormous amounts of sediments brought in by the feeding rivers, the three major reservoirs -Tarbela, Mangla and Chashma will lose their storage capacity, by 25 % by the end of the year 2010, which will further aggravate the water-availability situation in Pakistan. The quality of water is also deteriorating due to urbanization and ...
2004-06-07
Sodium gluconate as corrosion and scale inhibitor of ordinary steel in simulated cooling water
Energy Technology Data Exchange (ETDEWEB)
The effect of sodium gluconate anion (SG) on the corrosion and scale inhibition of ordinary steel in simulated cooling water has been studied using weight loss, polarisation curves, electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM) techniques. SG was studied in concentration from 10{sup -4} M to 10{sup -1} M. Results obtained reveal that SG perform excellently as corrosion and scaling inhibitor for ordinary steel in simulated cooling water. An increase of SG concentration leads to the increase of the corrosion potential towards the positive direction. The inhibition efficiency was a low temperature dependence. The inhibitor mechanism was treated as an adsorption process according to Langmuir adsorption isotherm. The SEM/EDAX data show that was a corrosion and scale inhibitor.
2008-06-15
Sodium gluconate as corrosion and scale inhibitor of ordinary steel in simulated cooling water
British Library Electronic Table of Contents (United Kingdom)
The effect of sodium gluconate anion (SG) on the corrosion and scale inhibition of ordinary steel in simulated cooling water has been studied using weight loss, polarisation curves, electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM) techniques. SG was studied in concentration from 10-4M to 10-1M. Results obtained reveal that SG perform excellently as corrosion and scaling inhibitor for ordinary steel in simulated cooling water. An increase of SG concentration leads to the increase of the corrosion potential towards the positive direction. The inhibition efficiency was a low temperature dependence. The inhibitor mechanism was treated as an adsorption process according to Langmuir adsorption isotherm. The SEM/EDAX data show that was a corrosion and scale inhi...
2008-01-01
Method of manufacturing diffusion oxygen or air carbon electrodes
Energy Technology Data Exchange (ETDEWEB)
Part of the crushed activated charcoal (about 20-50%) designed for manufacture of electrodes is made water repellant with the help of an aqueous suspension of water repelling agent containing 3-15% (preferably 10%) dry substance. After this the remaining part of the activated charcoal and the other additives are mixed with the water repelling part. The plates or tape which is rolled to an assigned thickness are pressed from the obtained mixture. The electrodes obtained by this method have a thin active layer and a porous structure and have good diffusion properties. They can be loaded by currents up to 80 mA/cm/sup 2/ without causing excessive polarization losses, and their service life is greater than or equal to 100 h.
1981-12-31
Inherent Boron Dilution Safety Issue in the French Pressurized Water Reactor: CFD Approach
International Nuclear Information System (INIS)
Inherent boron dilution can occur in case of a Small Break LOCA when low borated water is mainly accumulated in the U-legs due to reflux boiling in the Steam Generator tubes after the loss of natural circulation. The restart of the natural circulation may lead to criticality because of the injection of these low borated slugs towards the core. To evaluate this potential risk, the boron concentration at the core inlet has to be known which makes necessary to estimate the mixing phenomena in the cold leg, in the downcomer and in the lower plenum: CFD calculations are required. First of all the validation of CFX5 CFD code on the relevant phenomena of inherent boron dilution has been established (UPTF TRAM C3 test). Then, an application to the 900 MW French Pressurized Water Reactor series has been performed. (authors)
2006-07-17
Energy Technology Data Exchange (ETDEWEB)
Contamination and blockages of the cooling tubes in the turbine condenser disturb the heat transfer, thereby causing power losses at the turbine and increasing the fuel demand. Corrosions cause tubing leakages which require operating downtimes and reduce the lifetime of the pipes. Tube cleaning systems and backflushing cooling water filters eliminate these problems. Nevertheless it can come to coatings in the condenser tubes, if the tube cleaning equipment does not operate optimally or if coarse dirt is entered. Under this aspect, the author of the contribution under consideration reports on these problems on the basis of practical examples. The author gives references to the optimized operation of the tube cleaning system and the cooling water filtration.
2010-07-01
Investigation of dominant loss mechanisms in low-temperature polymer electrolyte membrane fuel cells
Energy Technology Data Exchange (ETDEWEB)
This thesis deals with the analysis of dominant loss mechanisms in direct methanol fuel cells (DMFC) and hydrogen fed polymer electrolyte membrane fuel cells (PEFC) by means of experimental characterization and modeling work. Due to different fuels used in these two fuel cell types, the dominant loss mechanisms are different in their nature. All in-situ characterization techniques that are used in this work are based on a novel test fuel cell with embedded reference electrodes. The first part of this work presents a new concept for realizing a reference electrode configuration in a polymer electrolyte membrane fuel cell by means of laser ablation. The laser beam is used to evaporate a small gap into the electrode surface of a catalyst coated membrane (CCM) to isolate the reference electrode from the working/counter electrode (WE/CE). This method enables the simultaneous ablation of the electrodes on both sides of the CCM because the membrane is ...
2010-07-01
The Blood-Brain Barrier and Microvascular Water Exchange in Alzheimer's Disease
UK PubMed Central (United Kingdom)
Alzheimer's disease (AD) is the most common form of dementia in the elderly. Although traditionally considered a disease of neurofibrillary tangles and amyloid plaques, structural and functional changes...Full Text Available
2011-01-01
Chalk Point Cooling Tower Project: Drift Salinity Experiments.
Results of feasibility experiments for determining the mineral content of individual stains on special Sensitized Paper are presented. The stains were formed on the paper by the impaction of laboratory generated salt water droplets. Of the techniques exam...
1979-01-01
UK PubMed Central (United Kingdom)
BackgroundTrichloroethylene (TCE) is a suspected human carcinogen and a common ground-water contaminant. Chloral hydrate (CH) is the major metabolite of TCE formed in the liver by...Full Text Available
2006-08-01
UK PubMed Central (United Kingdom)
Brain edema is frequently shown after cerebral ischemia. It is an expansion of brain volume because of increasing water content in brain. It causes to increase mortality after stroke. Agmatine, formed...Full Text Available
2010-05-01
NO formation in the burnout region of a partially premixed methane-air flame with upstream heat loss
Energy Technology Data Exchange (ETDEWEB)
Measurements of temperature and NO concentration in laminar, partially premixed methane-air flames stabilized on a ceramic burner in coflow are reported. The NO concentration and temperature were determined by laser-induced fluorescence (LIF) and coherent anti-Stokes Raman scattering (CARS), respectively. Upstream heat loss to the burner was varied by changing the exit velocity of the fuel-air mixture at a constant equivalence ratio of 1,3; this alters the structure of the flame from an axisymmetric Bunsen-type to a strongly stabilized flat flame. To facilitate analysis of the results, a method is derived for separating the effects of dilution from those of chemical reaction based on the relation between the measured temperature and the local mixture fraction, including the effects of upstream heat loss. Using this method, the amount of NO formed during burnout of the hot, fuel-rich combustion products can be ascertained. ...
1999-09-01
mtDNA mutation C1494T, haplogroup A, and hearing loss in Chinese
British Library Electronic Table of Contents (United Kingdom)
Mutation C1494T in mitochondrial 12S rRNA gene was recently reported in two large Chinese families with aminoglycoside-induced and nonsyndromic hearing loss (AINHL) and was claimed to be pathogenic. This mutation, however, was first reported in a sample from central China in our previous study that was aimed to reconstruct East Asian mtDNA phylogeny. All these three mtDNAs formed a subclade defined by mutation C1494T in mtDNA haplogroup A. It thus seems that mutation C1494T is a haplogroup A-associated mutation and this matrilineal background may contribute a high risk for the penetrance of mutation C1494T in Chinese with AINHL. To test this hypothesis, we first genotyped mutation C1494T in 553 unrelated individuals from three regional Chinese populations and performed an extensive search ...
2006-01-01
International Nuclear Information System (INIS)
In patients subjected to bone marrow transplantation the aggressive measures necessarily preceding this treatment lead to drastic metabolic changes which, in turn, are a cause of marked disturbances of homeostasis. The general preparatory measures in the form of cytoreduction by cytostatic drugs are broadened for leukaemic patients to include wholebody irradiation. During the study described here investigations were carried out into the resulting strain on the metabolism. One of the most essential changes observed in those patients was a nitrogen loss of up to approx. 20 g/day that occurred during the immunosuppressive phase. This was accompanied by markedly pronounced variations in fluid elimination, which partly were of an iatrogenic nature. An immediate and sufficient substitution of amino acids in connection with complete parenteral nutrition rapidly acted to compensate for the nitrogen losses, even though these could ...
Modeling of Valveless Micropumps
British Library Electronic Table of Contents (United Kingdom)
There are two difficulties encountered in modeling valveless micropumps using lumped-element methods. The pressure loss coefficient for fluidic diodes used in valveless pumps to rectify flow depends on the flow direction. A problem arises in choosing the proper loss correlation because the flow direction is not known a priori. Another problem is the quadratic form of the equation for the flow through the fluidic diodes, which brings about multiple solutions. The above problems become even more serious in multi-chamber cases. They are overcome in this study by suitably formulating the flow resistance. In addition, the flow inertia is accounted for in the unsteady model. The steady and unsteady models are evaluated by comparing with CFD simulations, which also serve to illustrate the flow fi...
2009-01-01
International Nuclear Information System (INIS)
The volatility of some elements being determined in biological and environmental samples by NAA (neutron activation analysis) in case of their binding with phenolformaldehyde resin (PFR) is studied. Since the temperature is assumed to influence the volatility of elements stronger than radiation during irradiation of samples in nuclear pile the losses of Se, As, Sb, and Hg form samples on the basis of PFR after their heating at 100-300 deg C have been investigated. It is shown that the losses of Sb and As up to 300 deg C, Se up to 250 deg C, and Hg up to 150 deg C from PFR - based samples do not occur.
Energy Technology Data Exchange (ETDEWEB)
A residue in the production of alumina by the Bayer process is red mud. It contains oxides of Fe and Ti, active as hydrogenation catalyst in sulfided form, and whose catalytic activity can be improved by the activation method proposed by Pratt and Christoverson. The paper describes how the development of its activity and selectivity with reaction time was studied for the hydrogenation of a light fraction of an anthracene oil, and compared with untreated sulfided red mud. Catalyst samples were collected at different reaction times, and their texture, morphology and composition characterized by nitrogen adsorption, SEM and SEM-EDX. The loss of catalytic activity of activated sulfided red mud is slower than for untreated sulfided red mud. The main cause of this decrease in catalytic activity is the loss of surface area and superficial Fe.
1998-06-01
Soil erodibility and its estimation for agricultural soils in China
British Library Electronic Table of Contents (United Kingdom)
Soil erodibility (the K factor in the Universal Soil Loss Equation, USLE) is an important index to measure soil susceptibility to water erosion, and an essential parameter needed for soil erosion prediction. To evaluate the appropriateness of the nomograph and other methods for estimating the K factor for the USLE and to develop a relationship for soil erodibility estimation for Chinese soils, a set of soil erodibility values was calculated using soil loss data from natural runoff plots at 13 sites in eastern China. The definition of soil erodibility in relation to the USLE was strictly followed. Comparing these measured values to those estimated using the nomograph method, the method adopted for the EPIC model and the formula of Shirazi and Boersma, we found that all these estimated soil ...
2008-01-01
Reversible performance loss induced by sequential failed cold start of PEM fuel cells
British Library Electronic Table of Contents (United Kingdom)
This study correlates the post start cell performance and impedance with the cold start process in the subzero environment. The sequential failed cold starts are deliberately conducted as well as the start at small current density. Here the failed cold start means the cell voltage drops to or below zero within very short time during the start process. It is found that there are reversible performance losses for the sequential failed cold starts, while not obvious degradation and no recovery happen for the start at small current density. Using the thin film and agglomerate model, it is confirmed that this is due to the water blocking effect. Comparing the results from different start processes, a model with respect to the shifting of reactive region within the catalyst layer is applied to e...
2011-01-01
Loss of coolant analysis for the tower shielding reactor 2
Energy Technology Data Exchange (ETDEWEB)
The operational limits of the Tower Shielding Reactor-2 (TSR-2) have been revised to account for placing the reactor in a beam shield, which reduces convection cooling during a loss-of-coolant accident (LOCA). A detailed heat transfer analysis was performed to set operating time limits which preclude fuel damage during a LOCA. Since a LOCA is survivable, the pressure boundary need not be safety related, minimizing seismic and inspection requirements. Measurements of reactor component emittance for this analysis revealed that aluminum oxidized in water may have emittance much higher than accepted values, allowing higher operating limits than were originally expected. These limits could be increased further with analytical or hardware improvements. 5 refs., 7 figs.
1990-06-01
Effect of polyacrylamide on the erodibility factor of a loam soil
British Library Electronic Table of Contents (United Kingdom)
Despite the proven utility of the Universal Soil Loss Equation (USLE) to predict soil rainfall erosion, it has limited precision in predicting soil loss in some soil series. Also, runoff is a factor in rainfall erosion and some models, such as the modified USLE (USLE-M), include runoff in predicting soil erosion. The soil erodibility factor is an essential component in both models and this may be affected by application of soil conditioners, such as polyacrylamide (PAM). The objectives of this study were to determine the effects of different rates of PAM (0, 1, 2, 4, and 6kgha-1) applied with sprinkler irrigation water, followed by two sprinkler irrigations with no PAM, on the erodibility of a loam soil under a rainfall simulator in a laboratory. The range of erodibility factor Ku obtained...
2008-01-01
The use of oxygen isotopic composition to study water dynamics in Amazon floodplain lakes
International Nuclear Information System (INIS)
The lakes formed in the Amazon floodplain play a key role in sustaining the highest populational density in the Amazon Basin because of its high primary productivity. The water volume in these lakes vary greatly during the year and possible water sources are the feeding river during high water state of the hydrographs and local inputs from its drainage basin. As these sources are chemically distinct, to understand the nutrient dynamics in these lakes, it is very important to know the relative water contribution of different water sources. In this paper we use "1"8O as a conservative to know the water sources for the lakes and our hypothesis is that: 1) In the high water stage lake water is derived predominantly from its feeding river. Therefore their #delta#"1"8O should be similar. 2) In the low ...
1989-05-01
British Library Electronic Table of Contents (United Kingdom)
In this paper we describe how cleavable surfactants decompose into water-insoluble silanols and two water-soluble products when subjected to vacuum plasma treatment. We used Raman spectroscopic analysis to confirm these structural changes, and we performed contact angle measurements and employed scanning electron microscopy to observe the surface morphologies of these compounds. Our contact angle measurements confirm that the products had degraded on nylon fabrics during argon gas plasma treatment. All of the PEG-silicone polyesters displayed excellent water-repellency; PEG6000-silicone exhibited the largest contact angle (130?) and, hence, the greatest water-repellency. Our results indicate that the silanols that form upon plasma treatment may be useful in coatings applications. We also f...
2006-01-01
Application of ultrafiltration membranes for removal of humic acid from drinking water
British Library Electronic Table of Contents (United Kingdom)
Humic acids are primarily a result of the microbiological degradation of surrounding vegetation and animal decay and enter surface waters through rain water run-off from the surrounding land. This often gives rise to large seasonal variations, high concentrations in the wet season and lower concentrations in the dry season. Alone humic acid is just a colour problem but when present in conventional treatment processes like chlorination, carcinogenic by-products like trihalomethane and haloacetic acid are formed. This, in addition to the demand for clean potable drinking water, has sparked extensive research into alternative processes for the production of drinking water from various natural/industrial sources. One of the major areas of focus in these studies is the use of membranes in micro...
2008-01-01
Structure and stability of the anodically formed films on 304 stainless steel in sulfuric acid
Energy Technology Data Exchange (ETDEWEB)
The structure and composition of the passive films formed on 304 stainless steel in deaerated IN H{sub 2}SO{sub 4} were studied by RHEED, XPS and AES. The stability of the passive films as a function of passivation potential and passivation time were investigated. The role of bound water in affecting the stability of the passive films is discussed. 7 refs., 3 figs.
1983-01-01
Energy Technology Data Exchange (ETDEWEB)
The purpose of the study is to analyze the economic impact which could result from the application of effluent limitations guidelines and standards issued under Sections 301, 304, 306, 307, 308, and 501 of the Clean Water Act to the plastics molding and forming industry.
1984-02-01
Energy Technology Data Exchange (ETDEWEB)
The treatment and disposal of oily waters from oil production and refining processes represent an important technological pass for attendance of the ambient legislation and to the politics of the Cia of search of the environmental excellence. The reuse or reinjection of the co-produced water has been considered an interesting strategical alternative, however, the water quality requirement for these processes demands a pretreatment step, considering the exit effluent from primary and secondary treatment processes currently used. This work presents resulted of the polymeric resin development for tertiary treatment of oily waters with low oil and grasses content and fine solids, including the dissolved fraction. These resins can adsorb, in reversible form, organic components. Its high adsorption capacity is determined by the polarity, superficial area, range of porosity and a wide ...
2008-07-01
Formation of iron oxides during mechanical activation in water
International Nuclear Information System (INIS)
It has been shown that mechanical milling of iron in water results in formation of nanocrystalline magnetite Fe3O4 with an average particle size of 0.6 ?m, saturation magnetization of 77 Am2/kg and coercivity of ?150 A/cm. Along with magnetite, an antiferromagnetic Fe-O phase (?10 wt%), which is an aggregate of small iron-oxygen clusters forms.
2007-05-21
A Monte Carlo model for predicting water quality in mine pit lakes
Energy Technology Data Exchange (ETDEWEB)
A model has been developed to predict the chemical composition of lakes that form in pyrite-bearing open-pit mines. Pyrite oxidation in wall rock releases sulfuric acid and metals, which mix with ground waters in the lake. Aqueous metal concentrations are calculated using MINTEQA2.
1995-12-01
Depleted zinc: Properties, application, production
Energy Technology Data Exchange (ETDEWEB)
The addition of ZnO, depleted in the Zn-64 isotope, to the water of boiling water nuclear reactors lessens the accumulation of Co-60 on the reactor interior surfaces, reduces radioactive wastes and increases the reactor service-life because of the inhibitory action of zinc on inter-granular stress corrosion cracking. To the same effect depleted zinc in the form of acetate dihydrate is used in pressurized water reactors. Gas centrifuge isotope separation method is applied for production of depleted zinc on the industrial scale. More than 20 years of depleted zinc application history demonstrates its benefits for reduction of NPP personnel radiation exposure and combating construction materials corrosion.
2009-07-15
Energy Technology Data Exchange (ETDEWEB)
An anaerobic fermenter-decanter for the purification of residual water from the sugar industry, with recovery of methane, consists of a tank with inclined walls, with a central agitator on a vertical shaft. A flexible cover anchored by its periphery to the walls of the tank and totally submerged forms a collecting pocket for the fermentation gases. The water to be purified is introduced, after being heated to about 35, towards the bottom of the tank near the agitator. A metal collecting bell with submerged edges and with the shaft of the agitator passing axially through it is connected by its edges to a central opening of the cover. The purification yields may exceed 90%.
1981-10-06
Assessment of the effects of pixel loss on image quality in direct digital radiography
Energy Technology Data Exchange (ETDEWEB)
Modern digital radiographic 'flat panel' detectors can exhibit a progressive form of image degradation arising from non-functioning pixels. The effect of these 'dead pixels' on the quantitative image quality measures of modulation transfer function (MTF), noise power spectrum (NPS) and detective quantum efficiency (DQE) is investigated by a simulated degradation of images obtained from an Hologic EPEX system. The effects on the semi-quantitive measures obtained from contrast threshold test objects and resolution gratings are also investigated. Results suggest that the contrast-detail tests often employed in quality assurance measures are not sufficient to reveal the presence of dead pixels until well beyond the recommended replacement point for the flat panel detector. However, measurements of spatial resolution using a line pairs phantom were found to be more sensitive to pixel loss. Measurement of the MTF, ...
2004-03-21
Assessment of the effects of pixel loss on image quality in direct digital radiography
International Nuclear Information System (INIS)
Modern digital radiographic 'flat panel' detectors can exhibit a progressive form of image degradation arising from non-functioning pixels. The effect of these 'dead pixels' on the quantitative image quality measures of modulation transfer function (MTF), noise power spectrum (NPS) and detective quantum efficiency (DQE) is investigated by a simulated degradation of images obtained from an Hologic EPEX system. The effects on the semi-quantitive measures obtained from contrast threshold test objects and resolution gratings are also investigated. Results suggest that the contrast-detail tests often employed in quality assurance measures are not sufficient to reveal the presence of dead pixels until well beyond the recommended replacement point for the flat panel detector. However, measurements of spatial resolution using a line pairs phantom were found to be more sensitive to pixel loss. Measurement of the MTF, NPS and DQE can reveal small changes ...
2004-03-21
Towards a higher energy efficiency and lower carbon society the European approach and experience
International Nuclear Information System (INIS)
The use of natural energy sources and their conversion to secondary forms of energy are a crucial base for the development of our society with its continuous change of requirements due to an increase in population and the broadening of the needs in our modern life. As a consequence the consumption of primary energy resources rose drastically worldwide during the last 5 decades in particular in the industrialized regions such as Europe. Parallel in time the increasing awareness of negative effects of fuel dependent pollution on the environment and the introduction of stringent emission control regulations about 3 decades ago initiated extensive development and retrofit activities resulting in the today applied high level state of the art. As an additional challenge the worldwide debate about the potential effects of the emission of the s.c green house gases on the global climate in particular carbon dioxide from the use of predominantly fossil fuels have initiated ...
2010-07-26
A model for the calculation of vent clearing transients in pressure suppression systems
International Nuclear Information System (INIS)
For the layout of a pressure suppression system of a light water cooled reactor (boiling water reactor) it is important to know the time dependent behavior of the vent clearing transient after a loss-of-coolant accident for two main reasons: time of the end of the vent clearing transient influences strongly the pressure and temperature maxima in the drywell and wetwell. Time-dependent behavior of the vent clearing transient influences pressure loads in the condensation pool of the wetwell and therefore pressure induced stresses to the structure. The time-dependent behavior of the water masses in the vent pipes and wetwell are described by the basic equations for a nonstationary incompressible friction flow: momentum equation, continuity equation and a correlation for the variation of the state of the gas volume in the wetwell above the water level. After many algebraic operations ...
1975-09-01
A partitioned central solar receiver
International Nuclear Information System (INIS)
Else of solar energy as substitute for conventional fuels at a competitive cost requires efficient conversion from solar radiation to usable forms of energy. In solar thermal or thermochemical applications, high efficiency usually re- quires high temperature and high concentration of incoming radiation. The main form of energy loss from high temperature solar central receivers is thermal emission ('re radiation'), at an effective temperature close to the maximum receiver temperature. This loss is reduced if the aperture is divided into segments, most of which are maintained at lower temperatures. A two-stage partitioned receiver demonstrating this concept is under construction at the Weizman Solar Tower. The high-temperature stage is the DIAPR (Directly Irradiated Annular Pressurized Receiver). The low-temperature stage is made of tubular cavity receivers of simpler design. Preliminary optical and ...
1996-05-01
The use of foam to improve liquid lifting from low-pressure gas wells
Energy Technology Data Exchange (ETDEWEB)
Gas well load up is the loss of available reservoir energy due to the accumulation of liquids in the wellbore over time, and these liquids arise from liquids (hydrocarbons and water) condensed from the gas. Accumulation of these liquids near the wellbore can cause severe reduction to complete loss of available transport energy. A systematic experimental approach was undertaken to evaluate the performance of foam in removing liquids from the bottom of wells. The objectives of the research were: (1) to determine the efficiency of liquid lifting with foam; and (2) to compare the effects of surfactant type and concentration on liquid lifting. A flowloop successfully simulated the effects of completions with and without packer for low-pressure gas well with liquid production. In the base-case runs (air and water flow), the two phase flow regime was mostly annular. Liquid lifting is improved in general when a ...
1999-07-01
Numerical Simulation and Analyses of the Loss of Feedwater Transient at the Unit 4 of Kola NPP
A three-dimensional numerical simulation of the loss-of-feed water transient at the horizontal steam generator of the Kola nuclear power plant is performed. Presented numerical results show transient change of integral steam generator parameters, such as steam generation rate, water mass inventory, outlet reactor coolant temperature, as well as detailed distribution of shell side thermal-hydraulic parameters: swell and collapsed levels, void fraction distributions, mass flux vectors, etc. Numerical results are compared with measurements at the Kola NPP. The agreement is satisfactory, while differences are close to or below the measurement uncertainties. Obtained numerical results are the first ones that give complete insight into the three-dimensional and transient horizontal steam generator thermal-hydraulics. Also, the presented results serve as benchmark tests for the assessment and further improvement of one-dimensional ...
2002-07-01
An analysis of PZR and related system design features for KNGR
Energy Technology Data Exchange (ETDEWEB)
The development of KNGR (Korean Next Generation Reactor) is now in progress. KAERI is developing KNGR which is a advanced active PWR (pressurized water reactor) and 1350 MW electric capacities and is by based on UCN(Ulchin) 3 and 4 nuclear power plant which is a Korean standard PWR. In this report, the PZR (pressurizer) and Related System Design Features for KNGR which include PZR volume, PPCS (pressurizer safety valve)were analyzed. First, the Design Parameters between KNGR compared to UCH 3 and 4 were compared, and second, advanced design features of KNGR compared to UCN 3 and 4 were analyzed. After the present analysis, it has been concluded that the safety margins for the PZR level and pressure of KNGR were more increased by the larger PZR volume than those of UCN 3 and 4, for PZR minimum water level at reactor/turbine trip and PZR maximum pressure at LOCV(loss of condenser vacuum) of KNGR were higher and lower, ...
1995-12-01
International Nuclear Information System (INIS)
There has been recent interest in the United States concerning the loss of residual heat removal system (RHRS) under reduced coolant inventory conditions for pressurized water reactors. This issue is also of interest in the Federal Republic of Germany and an experiment was performed in the integral PKL-III experimental facility at Siemens-KWU to supply applicable data. Recently, an NRC-sponsored effort has been undertaken at the Idaho National Engineering Laboratory to identify and analyze the important thermal-hydraulic phenomena in pressurized water reactors following the long term loss-of-RHRS during reduced inventory operation. The thermal-hydraulic response of a closed reactor coolant system during such a transient is investigated in this report. Some of the specific processes investigated include: reflux condensation in the steam generators, the corresponding pressure increase in the reactor ...
1992-04-01
International Nuclear Information System (INIS)
There has been recent interest in the United States concerning the loss of residual heat removal system (RHRS) under reduced coolant inventory conditions for pressurized water reactors. This issue is also of interest in the Federal Republic of Germany and an experiment was performed in the integral PKL-HI experimental facility at Siemens-KWU to supply applicable data. Recently, an NRC-sponsored effort has been undertaken at the Idaho-National Engineering Laboratory to identify and analyze the important thermal-hydraulic phenomena in pressurized water reactors following the long term loss-of-RHRS during reduced inventory operation. The thermal-hydraulic response of a closed reactor coolant system during such a transient is investigated in this report. Some of the specific processes investigated include: reflux condensation in the steam generators, the corresponding pressure increase in the reactor ...
1991-10-28
Data on the postfire dynamics of soil properties in the foci of Siberian moth population outbreaks are considered. It has been shown that controlled fires set in pest-defoliated forests result in the loss of approximately 75% of carbon and 50% of nitrogen from the forest litter through their emission into the atmosphere and in the enrichment of the upper soil horizons with potassium and phosphorus (this concerns both total and movable forms). Microbiological processes in the organogenic horizon undergo significant transformation, the density of microarthropods decreases, and the abundance of mites becomes hundreds of times lower. PMID:15354965
Turbulent characteristics of a statified two-phase flow in a horisontal plane channel
International Nuclear Information System (INIS)
Experimental investigations of the turbulence characteristics of the air flow above the wave surface of the film in the horizontal rectangular channel in the 5-20 m/s velosity range of the air rate change (Reynolds number for the air 120O0-48000, 100-1000 for the film) are carried out. It is shown that intensities of turbulent pulsations of the rate increase with the growth of liquid flow rate in the film especially in the region of large squall waves. The experimental results on the pulsations are presented in the dimensionless form by a universal dependence. Distributions of tangentials of turbulent stresses above the film are obtained, turbulent stresses are compared with friction losses at the phase interface.
1982-02-01
Nonlinear vibrations and chaos in electrostatic torsional actuators
British Library Electronic Table of Contents (United Kingdom)
Electrostatic torsional micro-mirrors have wide spread use in different industries for diverse purposes. This paper investigates the development of superharmonics and chaotic responses in electrostatic torsional micro-mirrors near the pull-in condition. Appearance of nonlinear phenomena is investigated in models accounting for and disregarding the coupling of torsional and flexural deflections. Analysis of the system response to step and harmonic excitation reveals the appearance of DC and AC symmetry breaking. Increasing the amplitude of harmonic excitation, the response in the form of distinct superharmonics changes to a broad band response, where there is loss of periodicity and the response becomes chaotic. Accounting for flexural deflections in coupled model reduces the voltage thresh...
2011-01-01
Envelope correlation in (N, N) MIMO antenna array from scattering parameters
DEFF Research Database (Denmark)
A simple closed-form equation to calculate the envelope correlation between any two receiver or transmitter antennas in a multi-input multi-output (MIMO) system of an arbitrary number of elements is derived. The equation uses the scattering parameters obtained at the antenna feed point to calculate the envelope correlation coefficient. This approach has the advantage that it does not require knowledge of the antenna radiation pattern. Numerical data that include conductor and permittivity loss are shown to validate the approach. Using the scattering parameters for calculating the envelope correlation is less laborious and relatively cheaper, as compared to the radiation pattern approach.
2006-01-01
Thermal-hydraulic testing on a Mitsubishi simplified PWR
Energy Technology Data Exchange (ETDEWEB)
Mitsubishi is now developing a new Pressurized water reactor (PWR), the Mitsubishi simplified PWR (MS-PWR), which has the innovative features of hybrid safety systems (an optimum combination of passive and active systems) and cooling by horizontal steam generators. In order to confirm the feasibility of the Mitsubishi hybrid safety system, various kinds of safety analyses are performed for loss-of-coolant accident events. In parallel to these safety analysis efforts, the following thermal-hydraulic tests are to be performed: (1) thermal-hydraulic test of a horizontal steam generator; (2) integrated thermal-hydraulic test using a simulation loop for the innovative MS-PWR (SLIM).
1993-01-01
Study of physical properties of protons and "1"2C ions in medical application
International Nuclear Information System (INIS)
Depending on their unique physical properties, proton and heavy ions have taken an irreplaceable role in modern means of tumor treatment. One-step process and two-step process physical models were employed to explain the mechanism of ion energy loss. The transport process of proton and "1"2C in water was simulated by Geant4 toolkit to study the physical properties of ion beam. The calculation results were discussed, which showed the advantages and disadvantages of proton and "1"2C in the medical application. (authors)
2009-06-01
Mine-associated wetlands as avian habitat
Energy Technology Data Exchange (ETDEWEB)
Surveys for interior wetland birds at mine-associated emergent wetlands on coal surface mines in southern Illinois detected one state threatened and two state endangered species. Breeding by least bittern (Ixobrychus exilis) and common moorhen (Gallinula chloropus) was confirmed. Regional assessment of potential wetland bird habitat south of Illinois Interstate 64 identified a total of 8,109 ha of emergent stable water wetlands; 10% were associated with mining. Mine-associated wetlands with persistent hydrology and large expanses of emergent vegetation provide habitat that could potentially compensate for loss of natural wetlands in Illinois.
1998-06-01
Full-length fuel rod behavior under severe accident conditions
Energy Technology Data Exchange (ETDEWEB)
This document presents an assessment of the severe accident phenomena observed from four Full-Length High-Temperature (FLHT) tests that were performed by the Pacific Northwest Laboratory (PNL) in the National Research Universal (NRU) reactor at Chalk River, Ontario, Canada. These tests were conducted for the US Nuclear Regulatory Commission (NRC) as part of the Severe Accident Research Program. The objectives of the test were to simulate conditions and provide information on the behavior of full-length fuel rods during hypothetical, small-break, loss-of-coolant severe accidents, in commercial light water reactors.
1992-12-01
Energetical analysis of sensitivity of hydrogen embrittlement of ordered alloys
Intermetallic compounds are regarded as highly promising for applications as high temperature structural materials. However, recent studies have demonstrated that a number of ordered alloys exhibit environmental embrittlement when tested in various environments at ambient temperature. When exposed to hydrogen gas or electrolytically charged with hydrogen, a significant ductility loss has been reported. The reaction of water vapor with reactive elements in the crack tip results in the generation of atomic hydrogen which diffuses from the surface to the interior and causes embrittlement. In this paper, the authors try to analyze the sensitivity of hydrogen embrittlement of ordered alloys based upon energetical considerations.
1993-10-01
Effect of Carbon Dioxide in the Air on Zinc-air Cell
Energy Technology Data Exchange (ETDEWEB)
The electrolyte was brought into contact with air and potassium carbonate was measured with various contact time in order to check the defect of carbon dioxide in the air on zinc-air cell. The relationship between potassium carbonate concentration in electrolyte and battery capacity was also studied. The potassium carbonate concentration in the electrolyte. The rate of carbon dioxide absorption was mainly affected by the pore size of hydrophobic membrane. Our study showed that adapting the pore of hydrophobic membrane decreased the loss of cell discharge performance due to the presence of carbon dioxide or water vapor in the atmosphere. 7 refs., 12 figs., 1 tab.
1999-04-01
We study the well-posedness of the initial value problem for a wide class of singular evolution equations. We prove a general well-posedness theorem under three assumptions easy to check: the first controls the singular part of the equation, the second the behavior of the nonlinearities, and the third one assumes that an energy estimate can be found for the linearized system. We allow losses of derivatives in this energy estimate and therefore construct a solution by a Nash-Moser iterative scheme. As an application to this general theorem, we prove the well-posedness of the Serre and Green-Naghdi equation and discuss the problem of their validity as asymptotic models for the water-waves equations.
2007-01-01
International Nuclear Information System (INIS)
Electron-beam codeposition of the elements to form certain high critical temperature superconducting materials, in particular A-15 compounds, has proven to be very useful in research directed at understanding and improving their superconducting properties. This work has used the close control of three or more evaporant sources to reproducibly make specimens that permit studies across selected regions of composition and phase space. The effect of composition and phase, together with the temperature and rate of deposition, on the growth morphology and superconducting properties has been studied. The superconducting properties measured include the critical temperature, ac loss, critical current density, and tunnel junction characteristics. The particular compounds studied include Nb_3Sn, Nb_3Ge, and V_3Si.
Control of microbially generated hydrogen sulfide in produced waters
Energy Technology Data Exchange (ETDEWEB)
Production of hydrogen sulfide in produced waters due to the activity of sulfate-reducing bacteria (SRB) is a potentially serious problem. The hydrogen sulfide is not only a safety and environmental concern, it also contributes to corrosion, solids formation, a reduction in produced oil and gas values, and limitations on water discharge. Waters produced from seawater-flooded reservoirs typically contain all of the nutrients required to support SRB metabolism. Surface processing facilities provide a favorable environment in which SRB flourish, converting water-borne nutrients into biomass and H{sub 2}S. This paper will present results from a field trial in which a new technology for the biochemical control of SRB metabolism was successfully applied. A slip stream of water downstream of separators on a produced water handling facility was routed through a ...
1995-12-31
British Library Electronic Table of Contents (United Kingdom)
Erosion-corrosion (E-C) of 3003 aluminum (Al) alloy in ethylene glycol-water solutions were studied by weight-loss and electrochemical measurements as well as surface characterization through an impingement jet system. Al alloy E-C is dominated by erosion components, i.e., pure erosion and corrosion-enhanced erosion, which account for 92-97% of the total E-C rate under the various conditions in this work. Contribution from corrosion components, including pure corrosion and erosion-enhanced corrosion, is slight. With the increase of fluid flow velocity and sand concentration, the total E-C rate increases. Compared with the significant increase of the rates of erosion components, the increase of the rate of corrosion component is negligible. Upon fluid flow, passivity of Al alloy that develo...
2009-01-01
Influence of recycling and temperature on the swelling ability of paper
British Library Electronic Table of Contents (United Kingdom)
Hornification is the loss of fiber wall swelling which is detrimental to subsequent recycling resulting from drying. It is known that dried fibers lose their conformability and swelling capacity. The effect of recycling treatment on the swelling ability of hardwood bleached kraft pulp fibers was determined. Modelling paper recycling, sheets were recycled using heat treatment (23?C, 60?C, 100?C). The results were compared with those for natural fibers from bleached kraft pulp. Swelling kinetics of sheets was measured by a modified method monitoring interactions of pulp with water. Swelling ability decreased during the recycling in comparison with never-recycled pulp at all temperatures. Recycling of sheets caused only small changes in the cupri-ethylene-diamine viscosity, however, the water...
2011-01-01
International Nuclear Information System (INIS)
The loss of seal of the H9 channel in vacuum, freeing the entire cross section of the front part, leads to a fast leak that progresses rapidly. The effect of depressurizing the reflector can leads to shutdown of the shutdown rod pumps. The source changer associated with the channel fills completely before the valve closes. All of the leak water remains contained within the source changer containment. After the valves open, cooling of the fuel element is handled by natural convection, requiring a reversal of the flow between the plates. This changeover, which takes place at a relatively low pressure level, could lead to local boiling in the fuel element. Consequently, irreversible transformations cannot be excluded as possibilities for the fuel element and even for the control rod. Subsequently, the can is refilled with heavy water with establishment of the usual pressure levels.
CFX code application to the French reactor for inherent boron dilution safety issue
International Nuclear Information System (INIS)
Inherent boron dilution can occur in case of a small Break LOCA when low borated water is accumulated in the U-legs due to reflux boiling in the Steam Generator tubes after the loss of natural circulation. The restart of the natural circulation may lead to criticality because of the injection of these low borated slugs towards the core. To evaluate this potential risk, the boron concentration at the core inlet has to be known which makes necessary to estimate the mixing phenomena in the cold leg, in the downcomer and in the lower plenum: CFD calculations are required. First of all the validation of CFX5 CFD code on the relevant phenomena of inherent boron dilution has been established (UPTF TRAM C3 test). Then, an application to the 900 MW French Pressurized Water Reactor series has been performed. (authors)
2006-09-05
International Nuclear Information System (INIS)
On the basis of soil losses records during 10 years, three levels of water erosion were established for two soil (Typical Hapludox and Oxic Dystropept) located on high and medium terraces of alluvial flat plain of piedmont in the Eastern Plains in La Libertad Research Center of CORPOICA. Eighteen 3 x 10 m"2 run-off plots were fitted out on a nonrandom arrangement of nine plots by landscape and three soil use and management treatments: zero grazing Brachiaria decumbens pasture for six years, up land rice, soybean and maize rotations for six years and bare soil for 10 years. Soil losses under these treatments allowed to define three degrees of erosion: slight (N_3 moderate (N_2) and severe (N_3) respectively. From each plot soil samples were taken at two depths for physical analyses. infiltration and resistance to cone penetration were measured in the field. Without exception water erosion produced a ...
1999-12-01
Preliminary study of the effect of pumped-storage plant operation on zooplankton
Energy Technology Data Exchange (ETDEWEB)
The hydromechanical effect of hydroelectric stations on zooplankton is customarily regarded as a constantly acting and comparatively harmless factor, since its destruction is inevitable when water masses are passed through hydroelectric stations, but its capacity for restoration is high (i.e., destruction of the zooplankton of the forebay is compensated by its production in the after bay). It is not known how correct such an opinion is, or what is the true balance of losses and reproduction of zooplankton in the forebays and after bays of hydroelectric stations. However, hydroelectric plants of a new type, pumped-storage plants, have been constructed in recent years and others are planned for the Dnieper reservoirs. The operational principle and purpose of these plants is that they employ special vertical turbine-electric pumps that pump water at night from the reservoirs into pumped-storage facilities at high levels, and ...
1980-01-01
Multidimensional two-phase flow regime distribution in a PWR downcomer during an LBLOCA refill phase
Energy Technology Data Exchange (ETDEWEB)
The multidimensional countercurrent two-phase flow regimes that occur in a pressurized-water reactor (PWR) vessel downcomer during the refill phase of a large-break loss-of-coolant accident are studied using a transparent 1/10 scale model of a PWR vessel. The various flow regimes and their distribution in the downcomer have been identified and mapped for a range of air-water flooding experiments. The two-phase flow patterns that are identified in the downcomer included various types of film flows, droplet flows, countercurrent churn flows and cocurrent flows depending on the flooding condition. Through observation of the two-phase flow dynamics it was deduced that the physical mechanisms associated with the flooding processes could be separated into a liquid entrainment process and a film flow reversal process. In addition to the above exercise, the effect of non-uniform injection of water into the ...
1994-09-01
Multidimensional two-phase flow regime distribution in a PWR downcomer during an LBLOCA refill phase
International Nuclear Information System (INIS)
The multidimensional countercurrent two-phase flow regimes that occur in a pressurized-water reactor (PWR) vessel downcomer during the refill phase of a large-break loss-of-coolant accident are studied using a transparent 1/10 scale model of a PWR vessel. The various flow regimes and their distribution in the downcomer have been identified and mapped for a range of air-water flooding experiments. The two-phase flow patterns that are identified in the downcomer included various types of film flows, droplet flows, countercurrent churn flows and cocurrent flows depending on the flooding condition. Through observation of the two-phase flow dynamics it was deduced that the physical mechanisms associated with the flooding processes could be separated into a liquid entrainment process and a film flow reversal process. In addition to the above exercise, the effect of non-uniform injection of water into the ...
1993-10-01
Evaluation of a solid hydrophone cable
Energy Technology Data Exchange (ETDEWEB)
In marine seismic exploration, an approximately two-mile long hydrophone cable is towed behind the ship. The commonly employed cable consists of a kerosene-filled hose enclosing hydrophones, electrical wires, and steel ropes. The kerosene provides buoyancy while the steel ropes are for structural support. For deep-water operations, the cable is pulled through the water at a depth of 20-40 feet. For shallow water, a bottom reference configuration is used and the cable is dragged. This paper presents a comparison of electroacoustic properties between a newly designed, buoyant solid cable and those of the conventional kerosene-filled hose. The emphasis is on drag cable operations. Cable maintenance is a major problem. Jacket cuts occur because of improper handling or collisions with other ships, subsea structures, and debris. Kerosene leakage causes buoyancy loss and the need for immediate replacement. ...
1982-07-01
Energy Technology Data Exchange (ETDEWEB)
The corrosion resistance of steel-reinforced mortar specimens made from alinite cement was investigated using ordinary Portland cement (OPC) specimens as reference. The specimens were prepared and exposed in three different environments: continuous exposure in tap water, interrupted exposure in tap water, and interrupted exposure in 3.5% NaCl solution. The steel weight loss and the half cell potential were measured vs. exposure time, up to the age of 12 months. Pore solution extraction and analysis and porosity determination were also performed. In continuous exposure in tap water, alinite cement provided adequate protection against corrosion. In interrupted exposure in tap water, a higher corrosion was observed for alinite cement compared to OPC. In the case of interrupted exposure in 3.5% NaCl solution, the simultaneous action of free chlorides and oxygen resulted in the ...
1998-07-01
System for cooling primary gas coolers using return water stabilized by means of ammonium sulfate
Energy Technology Data Exchange (ETDEWEB)
Discusses scaling of closed systems for cooling coal gas from black coal coking. Scaling rate and factors that influence scaling are analyzed. Physical and chemical properties of scale buildup on the inner walls of pipe cooling systems are evaluated. Water pH value and its effects on scaling and solubility of chemical compounds that form scale are discussed. Use of ammonium sulfate for scale control is analyzed. Consumption rate of ammonium sulfate depends on ambient temperature, water pH value and chloride content in return water. Formulae for calculating optimum content of ammonium sulfates for scale control are derived. 3 refs.
1989-08-01
Removal of NO and SO2 in Corona Discharge Plasma Reactor with Water Film
In this paper, a novel type of a corona discharge plasma reactor was designed, which consists of needle-plate-combined electrodes, in which a series of needle electrodes are placed in a glass container filled with flue gas, and a plate electrode is immersed in the water. Based on this model, the removal of NO and SO2 was tested experimentally. In addition, the effect of streamer polarity on the reduction of SO2 and NO was investigated in detail. The experimental results show that the corona wind formed between the high-voltage needle electrode and the water by corona discharge enhances the cleaning efficiency of the flue gas because of the presence of water, and the cleaning efficiency will increase with the increase of applied dc voltage within a definite range. The removal efficiency of SO2 up to 98%, and about 85% of NOx removal under suitable conditions is obtained in our experiments.
2004-04-01
Energy Technology Data Exchange (ETDEWEB)
An inorganic particulate adsorbent of a titania-alumina is described for treating a superheated water containing radioactive materials such as cobalt ions, which is free from release of corrosive impruities, and which has a high adsorption capacity of radioactive materials and a high mechanical strength is prepared by hydrolyzing a titanium alkoxide and an aluminum alkoxide, thereby forming a hydrous titanium oxide and a hydrous aluminum oxide, respectively; precalcining the hydrous titanium oxide and aluminum oxide, mixing and molding the resulting titania and alumina into a particulate mixture thereof having a titania mole fraction of 0.2 to 0.9, and calcining the particulate mixture at 500/sup 0/-700/sup 0/C. This absorbent is effectively used in treat boiling water-type nuclear reactor core-circulating water to remove radioactive substances therefrom.
1981-08-04
Formation of complex Langmuir and Langmuir-Blodgett films of water soluble rosebengal
British Library Electronic Table of Contents (United Kingdom)
This communication reports the formation of complex Langmuir monolayer at the air-water interface by charge transfer types of interaction with the water soluble N-cetyl Formula Not Shown -trimethyl ammonium bromide (CTAB) molecules doped with rosebengal (RB), with the stearic acid (SA) molecules of a preformed SA Langmuir monolayer. The reaction kinetics of the formation of RB-CTAB-SA complex monolayer was monitored by observing the increase in surface pressure with time while the barrier was kept fixed. Completion of interaction kinetics was confirmed by FTIR study. This complex Langmuir films at the air-water interface was transferred onto solid substrates at a desired surface pressure to form multilayered Langmuir-Blodgett films. Spectroscopic characterizations reveal some molecular lev...
2007-01-01
British Library Electronic Table of Contents (United Kingdom)
The behavior of proton transfer facilitated by a novel thiazole derivative, N-methyl-4-(4-phenoxyphenyl)thiazol-2-amine (MPPT), across the water/1,2-dichloroethane (1,2-DCE) interface was investigated electrochemically. The ionic partition diagram for MPPT was obtained from interpretation of the cyclic voltammograms. The apparent partition coefficient of MPPT was evaluated by the shaking-flask method under experimental conditions, while that for the protonated form of MPPT was calculated from its transfer potential obtained from the ionic partition diagram. It was suggested that the mechanism for transfer of MPPT across the water/1,2-DCE) interface depends on the pH of the aqueous phase. The parameters of the facilitated proton transfer across the water/1,2-DCE interface were evaluated as ...
2011-01-01
Dynamic characteristics of mixtures of plutonium, Nevada tuff, and water
Energy Technology Data Exchange (ETDEWEB)
One of the technical options being considered for long term disposition of weapons grade plutonium is geologic storage at Yucca Mountain. Multikilogram quantities of plutonium are to be vitrified, placed within a heavy steel container, and buried in the material know as Nevada tuff. It has been postulated that after ten thousand years, geologic and chemical processes would have disintegrated the steel container and created the possibility for plutonium to form mixtures with Nevada tuff and water that could lead to a nuclear explosion in the range of kilotons. A survey and description of critical homogeneous mixtures of plutonium, silicon dioxide, Nevada tuff, and water which also identified the mixture regimes where autocatalytic dynamic behavior is possible was completed. This study is a follow up of this survey and the major objective is to examine the dynamic behavior of the worst case critical and supercritical ...
1996-02-01
Energy Technology Data Exchange (ETDEWEB)
Surface films on iron formed in methanol solutions containing various amounts of water with or without 0.1 kmol/m{sup 3} LiClO4 have been analyzed by in-situ ellipsometry and ex-situ XPS. It was found that surface films having refractive indices n2 and absorption coefficients k2 in the range of 1.8-2.2 and 0.25-0.3, respectively, are formed on iron at potentials of the passive state. The values of n2 and k2 for passive films on iron obtained in the methanol are smaller than those of passive films formed in aqueous solutions. The refractive index n2 of the surface film on iron in the methanol became larger with increasing water or dissolved oxygen content. In the deaerated methanol with the water content less than 0.07%, a surface film having a refractive index of 1.7 was formed on iron, and XPS spectrum of this film showed a spectrum which ...
1995-08-20
Actinides in liquid waste formed in the regeneration of nuclear fuel from a VVER-1000 reactor
International Nuclear Information System (INIS)
In the radiochemical reprocessing of spent fuel from nuclear reactors, a considerable amount of liquid, solid, and gaseous waste is formed; this waste is potentially dangerous to humans and requires the development of special and complex technological techniques for its localization and reliable long-term storage. The most hazardous are liquid wastes of high specific activity - water-tailings solutions obtained in the first cycle of extraction after the removal of uranium and plutonium. These solutions contain more than 99.9% of all the other transuranic elements - isotopes of neptunium, americium, and curium. Where necessary, some fission products and actinides may be removed from wastes of high specific activity for subsequent use. The quantity, composition, and activity of these wastes varies within broad limits, depending on the type and power of the reactor, the initial nuclide composition of the fuel, and its specific energy yield, the ...
Chemical evolution of formation waters in the Palm Valley gas field, Northern Territory
International Nuclear Information System (INIS)
The chemical composition and evolution of formation waters associated with gas production in the Palm Valley field, Northern Territory, has important implications for reservoir management, saline water disposal, and gas reserve calculations. Historically, the occurrence of saline formation water in gas fields has been the subject of considerable debate. A better understanding of the origin, chemical evolution and movement of the formation water at Palm Valley has important implications for future reservoir management, disposal of highly saline water and accurate gas reserves estimation. Major and trace element abundance data suggest that a significant component of the highly saline water from Palm Valley has characteristics that may have been derived from a modified evaporated seawater source such as an evaporite horizon. The most dilute ...
Solidification of DOE problem wastes
Energy Technology Data Exchange (ETDEWEB)
Sodium nitrate waste has been successfully solidified in two types of polymeric materials: polyethylene, a thermoplastic material, and polyester styrene (PES), a thermosetting material. Waste form property evaluation tests such as ANS 16.1 leaching test and compressive strength measurements were performed on the waste forms containing various amounts of sodium nitrate. A single-screw extruder was employed for incorporating dry waste into polyethylene at its melt temperature of 120/sup 0/C to produce a homogenous mixture. Results of the leaching test for polyethylene waste forms containing 30, 50, 60 and 70 wt% sodium nitrate are presented as cumulative fraction leached and leaching indices ranging from 11 to 7.8. Two PES systems are discussed. The first is for solidification of dry salt wastes and the second is a water extendible system that is compatible with wet waste streams. Leaching data for PES ...
1986-01-01
Energy Technology Data Exchange (ETDEWEB)
A method and an instrument for determining the total water content in a hydrocarbon fuel using an indicator composition, which includes calcium hydride and phenolphthaleyn, are developed. The essence of the method is fixing the presence of water with its interaction with the calcium hydride and subsequent indication of the formed Ca(OH)2 using the phenolphthallen. To make the indicator composition, a hygroscopic cotton, prewashed by rectified alcohol and dried for 30 minutes at 105 degrees, is impregnated by a 1 percent alcohol solution of phenolphthaleyn and is dried in the same conditions. Then the cotton is processed by a powder form calcium hydride (a layer thickness of 0.1 to 0.2 millimeters, and a granule size of less than or equal to 80 micromters). The indicator composition is placed in a glass tube (a diameter of 4 to 7 millimeters and a length of 80 to 100 millimeters), whose ends are sealed ...
1983-01-01
Thermal denitration and mineralization of waste constituents
Energy Technology Data Exchange (ETDEWEB)
In order to produce a quality grout from LLW using hydraulic cements, proper conditioning of the waste is essential for complete cement curing. Several technologies were investigated as options for conditions. Since the LLW is dilute, removal of all, or most, of the water will significantly reduce the final waste volume. Neutralization of the LLW is also desirable since acidic liquids to not allow cement to cure properly. The nitrate compounds are very soluble and easily leached from solid waste forms; therefore, denitration is desirable. Thermal and chemical denitration technologies have the advantages of water removal, neutralization, and denitration. The inclusion of additives during thermal treatment were investigated as a method of forming insoluable waste conditions.
1997-08-01
International Nuclear Information System (INIS)
Formation of oxidizing and reducing radicals was studied by pulse radiolysis of [Fe(CN)_6]"4"- - BrO_3"- - CN"- system in ethylene glycol - water solvent mixture. Oxidizing #centre dot#BrO_2 and BrO radicals formed by electron scavenging with #centre dot#BrO_2"- were identified and their reactions were investigated. The reaction of hydroxyl radicals with ethylene glycol leads to formation of reactive radicals with reducing properties and of compounds which reduce slowly in dark the ferricyanide formed in the reaction of #centre dot#BrO_2 radical with ferrocyanide. (author) 21 refs.; 7 figs.
1991-01-01
Effects of coolant chemistry on corrosion of 3003 aluminum alloy in automotive cooling system
British Library Electronic Table of Contents (United Kingdom)
In this work, effects of coolant chemistry, including concentrations of chloride ions and ethylene glycol and addition of various ions, on corrosion of 3003 Al alloy were investigated by electrochemical impedance spectroscopy measurements and scanning electron microscopy characterization. In chloride-free, ethylene glycol-water solution, a layer of Al-alcohol film is proposed to form on the electrode surface. With the increase of ethylene glycol concentration, more Al-alcohol film is formed, resulting in the increase in film resistance and charge-transfer resistance. In the presence of Cl- ions, they would be involved in the film formation, decreasing the stability of the film. In 50% ethylene glycol-water solution, the threshold value of Cl- concentration for pitting initiation is within ...
2010-01-01
International Nuclear Information System (INIS)
Wolsong 2,3 and 4 fuel channel analysis during a large break loss of coolant accident with loss of ECCS injection (LOCA/LOECC) is performed to obtain the heat load to moderator. Because the single channel analysis requires the establishment of the safety codes and their input decks, the present study follows the same safety analysis methodology found in FSAR of Wolsong 2,3 and 4. From this work we obtain the safety tools such as CATHENA MOD3.5b/Rev.1 and CHAN-II/A MOD2 codes, and their code modeling in a form of code input deck. The analysis consists of two parts: front-end (blowdown period) and back-end. For the front-end analysis the fuel and pressure tube (PT) temperatures, and PT circumferential strains at the end of front-end as well as fuel channel depressurization are calculated using CATHENA code and used as initial and boundary conditions for back-end analysis. The back-end period under the conditions of prolonged ...
2002-10-01
The Performance Evaluation of a Hot Water Layer using a Numerical Simulation
International Nuclear Information System (INIS)
Most of all research reactors are immerged in the deep water pool to be a ultimate heat sink. At the neighbor of the reactor, some radio-active matters, such as Na-24, Ar-41, Mg-27, Al-28 and etc, may be generated by the neutron irradiation. Those radio-active isotopes may rise up to the pool water surface through the natural convection flow, which can make the radioactivity in the reactor hall rise high enough to concern about the health of people working in the reactor hall. When the irradiation test facilities are loaded or unloaded during a normal operation, the highly radio-activated primary coolant may flow out through the irradiation test holes on the top of the reactor. This also may be a main hazard source to make the working environment of the reactor hall bad. Making a hot water layer 1.5 ? 2.0 m thick at the top of reactor pool would be a good measure to resolve that problem. The hot water ...
2009-05-01
International Nuclear Information System (INIS)
Based on the occurrence of a number of plant incidents during low power and shutdown operating conditions, the Nuclear Regulatory Commission (NRC) has initiated several programs to better quantify risk during these periods. One specific issue of interest is the loss of residual heat removal (RHR) under reduced coolant inventory conditions. This issue is also of interest in the Federal Republic of Germany and an experiment was performed in the integral PKL-3 experimental facility at Siemens-KWU to supply applicable data. Recently, an effort has been undertaken at the Idaho National Engineering Laboratory (INEL) to identify and analyze the important thermal-hydraulic phenomena in pressurized water reactors following loss of vital AC power and consequent loss of the RHR system during reduced inventory operation. The thermal-hydraulic response of a nuclear steam supply system (NSSS) with a closed reactor ...
1991-10-01
Immobilization of sodium nitrate waste with polymers: Topical report
International Nuclear Information System (INIS)
This report describes the development of solidification systems for sodium nitrate waste. Sodium nitrate waste was solidified in the polymers polyethylene, polyester-styrene (PES), and water-extendible polyester-styrene (WEP). Evaluations were made of the properties of waste forms containing various amounts of sodium nitrate by leaching immersion in water, measuring compressive strengths and by the EPA Extraction Procedure. Results of the leaching test are presented as cumulative fraction leached (CFL), incremental leaching rate, and average leaching indices (LI). For waste forms containing 30 to 70 wt% sodium nitrate, the CFL ranged from 9.0 x 10"-"3 to 7.3 x 10"-"1 and the LI from 11 to 7.8. After ninety days immersion in water, the compressive strengths ranged from 720 psi to 2550 psi. The nitrate releases from these samples using the EPA Extraction Procedure were below 500 ppM. ...
2005-06-01
Immobilization of sodium nitrate waste with polymers: Topical report
Energy Technology Data Exchange (ETDEWEB)
This report describes the development of solidification systems for sodium nitrate waste. Sodium nitrate waste was solidified in the polymers polyethylene, polyester-styrene (PES), and water-extendible polyester-styrene (WEP). Evaluations were made of the properties of waste forms containing various amounts of sodium nitrate by leaching immersion in water, measuring compressive strengths and by the EPA Extraction Procedure. Results of the leaching test are presented as cumulative fraction leached (CFL), incremental leaching rate, and average leaching indices (LI). For waste forms containing 30 to 70 wt% sodium nitrate, the CFL ranged from 9.0 x 10/sup -3/ to 7.3 x 10/sup -1/ and the LI from 11 to 7.8. After ninety days immersion in water, the compressive strengths ranged from 720 psi to 2550 psi. The nitrate releases from these samples using the EPA Extraction Procedure were below ...
1987-04-01
Solidification of problem wastes: Annual progress report, October 1985-September 1986
Energy Technology Data Exchange (ETDEWEB)
This report describes initial work on the development of solidification systems for sodium nitrate waste and compacted waste. Sodium nitrate waste has been solidified in three types of materials: polyethylene, polyester-styrene (PES), and latex cement. Evaluations of the properties of the waste form, such as the ANS 16.1 leaching test, water immersion test and compressive strength measurements were performed on the waste forms containing various amounts of sodium nitrate. 9 refs., 9 figs., 7 tabs.
1987-02-01
Process to eliminate the deposits formed in a steam generator of a pressurized water nuclear reactor
International Nuclear Information System (INIS)
The present process allows to eliminate the corrosion products formed on the tube plates and in the interstices of plate-tube crosspieces of a PWR steam generator in order to avoid a corrosion phenomenon which may cause denting by presence of oxides. The process consists in applying on these oxides at about 50-100 degrees, an aqueous solution containing 6-8% of gluconic acid, 3-5% of citric acid, about 0.5% of a corrosion inhibitor and ammonia until a pH of 3-9.5 is obtained.
1984-04-05
Effect of secondary circuit materials and water regime on steam generator reliability
International Nuclear Information System (INIS)
The mechanism of the salt concentration increase in pits and crevices formed in a steam generator due to its imperfect manufacture or to its design features is described. The probability of corrosion can be reduced by choosing a suitable steel and by securing low concentrations of salts (chlorides in particular) and corrosion products in the feedwater. Attention is paid to the distribution of salts in the water-steam circuit and to the conditions of erosion corrosion as the principal source of corrosion products in feedwater. Experience with the suppression of erosion corrosion at nuclear power plants abroad is described. (E.J.).
1989-05-01
Causes of denting. Volume 5. Contaminant threshold tests. Final report
Steam generators in PWR plants have been subject to denting corrosion as a result of nonprotective magnetite forming on the carbon steel support plate causing the voluminous corrosion product that eventually crimps (dents) the heat transfer tube at the support plate interface. This project was designed to determine the causes of denting and the usefulness of water chemistry changes meant to arrest denting. This volume of the final report describes laboratory research on the correlation of water chemistry, superheat, and oxygen ingress with denting in steam generators.
1983-12-01
Autogenous electrolyte, non-pyrolytically produced solid capacitor structure
Energy Technology Data Exchange (ETDEWEB)
A solid electrolytic capacitor having a solid electrolyte comprising manganese dioxide dispersed in an aromatic polyamide capable of further cure to form polyimide linkages, the solid electrolyte being disposed between a first electrode made of valve metal covered by an anodic oxide film and a second electrode opposite the first electrode. The electrolyte autogenously produces water, oxygen, and hydroxyl groups which act as healing substances and is not itself produced pyrolytically. Reduction of the manganese dioxide and the water molecules released by formation of imide linkages result in substantially improved self-healing of anodic dielectric layer defects.
1998-01-01
Anaerobic oxidation of carbon steel in granitic groundwaters: A review of the relevant literature
International Nuclear Information System (INIS)
This report reviews the published literature on the anaerobic oxidation of iron in aqueous solutions which are of particular relevance to Swedish granitic groundwaters. The thermodynamics of iron corrosion in water are briefly considered. Following this the experimental data found in the literature are presented and discussed. Results were found for corrosion of iron in both pure water and solutions containing mineral salts. The literature work in the nature of the films formed on iron surfaces under anaerobic conditions is reviewed and the possible mechanisms of film formation are discussed. Conclusions are drawn on the factors most likely to influence and control film growth. 32 refs.
2010-02-01
A horizontal steam generator for the Indian 235 MW heavy water nuclear power plants
International Nuclear Information System (INIS)
In this paper the thermal design of a horizontal steam generator for the Indian PHWR nuclear power plant is described. The main attraction is absence of tube sheet and use of stainless steel 'U' tubes. It is emphasised that with appropriate water chemistry it is possible to use stainless steel tubes, which is many times cheaper than the Incoloy tubes used elsewhere. The design approach, applicable equation for the design and the results of computation in the form of heat transfer area and some important dimensions of the steam generator are presented.
1993-11-01
Wetlands - A valuable resource for the '90s
Energy Technology Data Exchange (ETDEWEB)
The nation's wetlands are a valuable resource serving many important natural, industrial, commercial and recreational functions. Wetlands protect shore areas from waves and storms; act as storage areas for flood waters; remove waste from water by trapping soils or silt which settle to the bottom; improve water quality and reduce pollution; are a commercial breeding ground for fish and other foods; and provide space for recreation and habitat for wildlife. They also are located in prime industrial development areas. Recent wetlands losses have caused much public outcry, politicking and regulatory efforts to prevent this trend. During the '90s, the public will see efforts to strike a proper balance regarding wetlands use. Today, wetlands protection is a permitting issue for nearly every major industrial or commercial development and expansion project. Wetlands permit requirements affect ...
1993-04-15
Wax and hydrate control with electrical power
Energy Technology Data Exchange (ETDEWEB)
Electrical heating of subsea flowlines is an effective way to prevent wax and hydrate information, especially for long transportation distances and in low-temperature deep water. Systems are available for use in conjunction with bundles, pipe-in-pipe, and wet-thermal-insulation systems. These systems provide environmentally friendly fluid-temperature control without chemicals or flaring for pipeline depressurizing. Enhanced production is achieved because no time is lost by unnecessary depressurizing, pigging, heating-medium circulation, or removal of hydrate and wax blockages. The seabed temperature at 100-m and greater water depths may range from 7 to {minus}1.5 C, causing a rapid cooling of the hot well streams being transported in subsea flowlines. Under these supercooling conditions, vulnerable crude oils and multiphase compositions will deposit wax and asphalts; also the gas/water phase may freeze solid with hydrate ...
1997-08-01
Radiation grafting processes and properties of leathers modified with butyl acrylate
International Nuclear Information System (INIS)
Conditions for radiation induced grafting with butyl acrylate dispersed in water emulsion onto chrome-tanned pig skins have been worked out for #gamma#-rays and electron beam irradiations. The highest yield of grafting was observed at monomer concentration approximately 25% (w/w), dose equal to 25 kGy and dose rate not exceeding 10 MGy/h. At these conditions the yield of grafting attained a value approximately 25% and content of homopolymer in the leather amounted to 6%. The efficiency of monomer to polymer conversion decreases when the concentration of monomer in emulsion and dose rate increases. Yield of homopolymer is independent of the dose rate. An explanation of the observed relations has been proposed. The physical and used properties of grafted leathers were tested. Radiation processed leathers were found superior to samples finished by traditional methods. One has to point to better tolerance against chemical cleaning and reduced water ...
1982-01-01
Macrofouling control in nuclear power plants
International Nuclear Information System (INIS)
Macrofouling of cooling-water systems is one of the more significant and costly problems encountered in the nuclear power industry. Both marine and freshwater macroinvertebrates can be responsible for losses in plant availability because of plugged intakes and heat transfer equipment. There is a greater diversity of macrofouling organisms in marine waters than in fresh waters. Marine macrofouling organisms include barnacles, mollusks, bryozoans, and hydroids. Barnacles are crustaceans with feathery appendages, which allow them to attach to a variety of surfaces. They are a major cause of severe macrofouling because they can remain attached even after death. The major freshwater macrofouling organisms include the Asiatic Clam (Corbicula fluminea) and the newest freshwater macrofouler, the Zebra Mussel (Dreissena polymorpha). The introduction of the Zebra Mussel into the Great Lakes has created economic ...
1991-11-10
Energy Technology Data Exchange (ETDEWEB)
Operation safety and reliability are major guidelines in the design of city-gate units. Conventional natural gas heaters operate by a indirect mechanism, where liquid water is used to transfer heat by natural convection between the combustion chamber and the natural gas coil. In this work, the concept of vapor chamber is evaluated as an indirect gas heater. In a vapor chamber, liquid water is in contact with the heat source, and vaporizes. The vapor condenses in contact with the heat sink. A reduced scale model was built and tested in order to compare these two heating concepts where the combustion chamber was replaced by electrical cartridge heaters. This engineering model can operate either as a conventional heater or as a vapor chamber. The comparison between the concepts was done by inducing a controlled power to the cartridges and by measuring the resulting temperature distributions. In the novel design, the heat exchanger efficiency ...
2005-07-01
High performance fiber filtration and its fluid flow
Energy Technology Data Exchange (ETDEWEB)
A new filtration process using acrylic fiber has been developed which has wide applications in water works, sewage water treatment and waste water treatment facilities. Instead of sand, the common filter media in conventional systems, this new system uses long, fine acrylic fibers. Compared with a conventional system, the filtration speed and suspended solids (SS) retention of the new system have been increased 500% from 120--200 m/d to 400--1,200 m/d and from 2--3 kg/m{sup 2} to 5--20 kg/m{sup 2}, respectively. In addition, the backwash time has been decreased 60%, from 20--30 min to 10 min. As SS retention increase, the empty space between the fibers (fiber void) decreases and pressure drops due to the high filtration rate. Thus the pressure decreases rapidly after a certain period of filtration because of the increased SS retention cause fiber compression. This system is primarily based on solution clarification, but ...
1994-12-31
International Nuclear Information System (INIS)
In an existent emergency reactor core cooling device, if a ruptures should occure in a pipeline of a gravitational dropping type reactor core cooling system pool (GDCS) due to some or other causes, a portion of GDCS pool water was flown out of the ruptured port and could not be used for reactor core cooling. Then, a difference pressure detector is disposed to a GDCS pipeline at the inlet of a reactor pressure vessel. When it is judged by the detector, that coolants flow to the outside of the injection pipeline, an injection value disposed to the GDCS pipeline is closed by the difference pressure signal. Even if a rupture should occur on the side of the pressure vessel at downstream to the check value of the GDCS pipeline, since backflow is caused at the pressure container inlet of the GDCS pipeline with the rupture port, the rupture is detected by the difference pressure detector to close the injection valve. Therefore, loss of the GDCS pool ...
1990-10-29
Two types of evacuated tube solar collectors have been operated in space heating, cooling and domestic hot water heating systems in Colorado State University Solar House I. An experimental collector from Corning Glass Works supplied heat to the system from January 1977 through February 1978, and an experimental collector from Philips Research Laboratory, Aachen, which is currently in use, has been operating since August 1978. A flat absorber plate inside a single-walled glass tube is used in the Corning design, whereas heat is conducted through a single glass wall to an external heat exchanger plate in the Philips collector. In comparison with conventional flat-plate collectors, both types show reduced heat losses and improved efficiency. For space heating and hot water supply in winter, the solar delivery efficiency of the Corning collector ranged from 49% to 60% of the incident solar energy. The portion of the space ...
1979-01-01
Dalia integrated production bundle (IPB): an innovative riser solution for deep water fields
Energy Technology Data Exchange (ETDEWEB)
The Dalia field is located 210 km north west of Luanda (Angola), about 140 km from shore in 1400 meter water-depth. It was the second major discovery out of 15 made in the block 17 operated by Total. The Dalia Umbilical, Flow lines and Risers EPCI Contract was awarded in 2003. The sea-line network to connect and control the 71 wells and 9 manifolds consist of the following: 40 km of insulated pipe in pipe (12 inches into 17 inches) production flow lines; 45 km of 12 inches water and gas injection lines; 6 off 1.7 km flexible water and gas injection risers; 8 off 1.65 km flexible Integrated Production Bundle (IPB) risers; 75 km of control umbilicals. The flow assurance and associated insulation requirement of the production transport system was one of the main challenges of the project. With a crude temperature of 45 deg C at the wellhead and the required minimum temperature of 35 deg C on arrival at the FPSO, this problem ...
2008-07-01
Energy Technology Data Exchange (ETDEWEB)
This document contains summary reports of stream habitat surveys, conducted in the Cowlitz River basin, by the Bureau of Fisheries (BOF, now National Marine Fisheries Service) from 1938-1942. These surveys were part of a larger project to survey streams in the Columbia River basin that provided, or had provided, spawning and rearing habitat for salmon and steelhead. The purpose of the survey was, as described by Rich, [open quotes]to determine the present condition of the various tributaries with respect to their availability and usefulness for the migration, breeding, and rearing of migratory fishes[close quotes]. Current estimates of the loss of anadromous fish habitat in the Columbia River Basin are based on a series of reports published from 1949-1952 by the U.S. Fish and Wildlife Service. The reports were brief, qualitative accounts of over 5000 miles of stream surveys conducted by the BOF from 1934-1946. Despite their brevity, these BOF reports have ...
1995-01-01
Quantitative evaluation of bile diversion surgery utilizing /sup 99m/Tc HIDA scintigraphy
Energy Technology Data Exchange (ETDEWEB)
This is a report of 21 patients presenting with epigastric pain, bilious vomiting, upper gastrointestinal bleeding, iron-deficiency anemia, and weight loss, who had undergone Billroth II gastrectomy from 3 to 35 yr earlier. Eighteen of 21 patients were found to have significant enterogastric reflux indices varying from 60% to 95% demonstrated by /sup 99m/Tc HIDA scintigraphy. Thirteen patients had diversion antireflux surgery in the form of a Roux-en-Y procedure, and 1 patient had a Henley loop jejunal interposition. Postoperative /sup 99m/Tc HIDA scintigraphic studies showed the enterogastric reflux indices to have decreased significantly to a range of 2%-26% (p less than 0.00001). There was marked improvement of symptoms, including correction of anemia and weight gain in those patients who had been anemic or who had sustained earlier weight loss. The enterogastric reflux indices of 10 asymptomatic control patients after ...
1983-02-01
How epitaxial are Pd/sub 2/Si-Si interfaces
Energy Technology Data Exchange (ETDEWEB)
Pd/sub 2/Si layers produced by evaporation or sputtering onto silicon substrates were examined by high resolution electron microscopy, microdiffraction, X-ray, energy loss and Auger spectroscopy. The Si-Pd/sub 2/Si interfaces produced by evaporation were in all cases rougher and more polycrystalline than those produced by sputtering. X-ray microanalysis showed the predictable variation in palladium distribution across the interface but quantification did not produce the expected palladium-to-silicon ratios, primarily because of probe broadening and X-ray-induced fluorescence. Energy loss spectra showed plasmon energy shifts and changes in Si L edge shape due to bond formation with palladium. Auger data provided evidence for a small amount of oxygen at the Si-Pd/sub 2/Si interface. Electrical measurements of the ideality factor for Schottky barriers made from the materials produced higher values for the rougher ...
1983-06-17
Development of a cupola furnace process model. Final technical report
A strategic partnership was formed among the American Foundrymen`s Society and the Federal government to develop and transfer the technology needed by the US foundry industry to: increase energy efficiency of cupola melting; improve recovery of carbon, silicon, and manganese through reduced oxidation losses; and improve productivity due to more uniform and predictable iron compositions. An effective mathematical model of the cupola offers a solution to the complex and interactive chemical and heat transfer processes to melt cast iron. The transient changes in charge size, charge composition, blast rate, and coke rate are used to optimize operation to improve melting rates, minimize oxidation losses of valuable alloying elements (C, Si, and Mn), and maintain iron composition. Despite these challenges, the cupola produces iron at a lower cost, and have better environmental controls than other melting process with 70% of ...
1995-07-01
Correction for loss of track density due to overlapping track on SSNTD
Energy Technology Data Exchange (ETDEWEB)
Solid state nuclear track detectors (SSNTD) record radiation in the form of tracks. In the case of high track density, however, it is not always possible to distinguish each track separately. The track density might then be underestimated unless the loss of track number due to overlapping is compensated. An elaborated 'erosion' or curve fitting process is applied usually, for the separation of the overlapping tracks, to automatic track counting systems. This paper shows a much simpler correction method which was developed by the analogy of the correction equation for the dead time of GM counters. From a set of about 10 data obtained from high track density detectors, the equation for SSNTD can be determined by a least square fitting. Once the equation is found, true track density could be derived easily without any help of complex image processing or calculation, such as the erosion or curve fitting. This method also provides ...
1990-06-01
Energy Technology Data Exchange (ETDEWEB)
The important amount of hydration water in the ulexite (NaCaN{sub 5}O{sub 9}.8H{sub 2}O), allows using calcination methods to increase its B{sub 2}O{sub 3} content. This paper analyses the thermal decomposition reaction of a preconcentrated ulexite through weight loss measurements, which occur during the heating of samples until 1000 degree centigree, Determinations of heat content at each temperature were made using an isoperibol calorimeter. The mean specific heat was calculated from these values, and its dependence on temperature was determined. The maximum weight loss was about 32.5% and the specific heat obtained was 1,13 kJ/kg 0 C for solid samples and 1,38 kJ/kg''0 C for fluid samples. The results are useful for the design of the industrial process, in order to determine the thermal requirements for heating calcined ulexite, and to obtain smelted ulexite. (Author) 19 refs.
2006-07-01
Energy Technology Data Exchange (ETDEWEB)
When thorium was biosorbed by biomass of Rhizopus arrhizus or Aspergillus niger it could be removed by treatment using carbonate solutions, but not by phosphates or distilled water. Desorption was rapid, reaching completion in 15 and 30 min respectively. Desorption efficiency was independent of the desorbent concentration above 0.05 mol dm[sup -3] but was strongly dependent on the biomass concentration, decreasing as the biomass concentration increased for both species. Biomass from both species could be regenerated by desorption using sodium carbonate solutions and reused for biosorption. In both species, the efficiency of biosorption and desorption fell as the number of exposures increased although there was an initial rise in desorption efficiency for R. arrhizus. Biosorption and desorption efficiencies of A. niger biomass showed the steeper decline but both were severely reduced in R. arrhizus after five treatments. There was also a significant ...
1992-01-01
Drying characteristics and nitrogen loss of biogas digestate during drying process
Energy Technology Data Exchange (ETDEWEB)
The cost of transporting biogas digestate can be decreased by reducing its water content. However, the digestate emits volatile compounds during drying. This study investigated the drying behaviour and the change of digestate composition. Drying took place in a hybrid solar/waste-heat dryer that used solar energy as well as waste heat from a combined heat and power unit (CHP) and the exhaust air of a microturbine. The experiment involved the use of 60 t of liquid digestate. Climatic conditions were measured inside and outside the drying hall. Dry matter (DM) and organic dry matter (ODM) were also measured on a daily basis. In addition, the energy consumption of waste and solar heat were recorded and related to the quantity of dried feedstock. The total nitrogen, ammonium, phosphate, potassium oxide, magnesium oxide and calcium oxide in the digestate were subjected to chemical analysis before and after the drying process. Losses of nitrogen were ...
2010-07-01
A calculation model for thermo-hydraulic analyses of the PGV-1000 steam generator
International Nuclear Information System (INIS)
A calculation model was developed for the analysis of thermal and hydraulic processes in the PGV-1000 horizontal steam generator. The model makes it possible to examine the hydraulics of the primary medium, i.e., the distribution of flow velocities and mass flows in the exchanger tube system and hydraulic losses of the primary medium in the steam generator during its flow between the two connecting sites to the main circulation pipeline, spatial distribution of heat fluxes between the primary and secondary sides of the steam generator and the total transmitted thermal power, pressure on the secondary side of the generator, natural circulation of the working medium on the secondary side, and the mean circulation number, spatial distribution of the volume fraction of the steam component in the intertubular space, effect of the perforated sheet on the thermo-hydraulic processes in the steam generator, redistribution of the steam component in the compartment above the ...
1994-01-01
Simple calculation of daily photosynthesis by means of five photosynthesis-light equations
Energy Technology Data Exchange (ETDEWEB)
The performance of five well-known photosynthesis-light equations is compared by presenting a wide range of solutions in the form of dimensionless nomographs for the case where photosynthetically available radiation (PAR) reduces exponentially down the water column and is distributed sinusoidally through the photoperiod. These provide a simple means of calculating daily photosynthesis at any depth (e.g. at a benthic layer), or through a water column, avoiding the need to perform complex integrations. An examination is made of the accuracy of common approximate methods for calculating daily photosynthesis, assuming constant PAR. For optically deep water a modification is proposed to Talling's planimetric solution, to enable daily photosynthesis to be calculated more accurately, yet simply, over the whole range of possible PAR values. The errors induced by approximating the daily PAR distribution ...
1992-12-01
Remotely sensing of excavation cavity during mining
Energy Technology Data Exchange (ETDEWEB)
This patent describes a method of hydraulically mining a surface of a mining location comprising: a. determining the dimensions of the surface of the mining location from a fixed point at the location; b. constructing at a second location remote from the mining location a visual representation of the surface form the determined dimensions of the mining location with respect to the fixed point; c. jetting water under high pressure against a selected area on the surface of the mining location; d. determining changes in the dimensions of the selected area of the surface of the mining location; e. reconstructing at the second location a new visual representation of the surface from the determined changes of the location during the jetting of the water; and f. redirecting the jetted water under high pressure utilizing data from the reconstructed visual representation.
1987-11-24
Investigation of the removal efficiency of gasborne particles in a scrubber column
Energy Technology Data Exchange (ETDEWEB)
Tests on the scrubbing column have led to the following results: Use of a scrubbing column with Raschig rings is only meaningful for the sedimentation of particles exceeding diameters of 0.5 ..mu..m; drops of diameter size 1.5 ..mu..m are formed in the column; more efficient drop precipitators in the column air flow ease the load on subsequent suspended material filters thereby contributing to a longer life of these filters even at higher sodium ion concentrations in the washing water; with distillate of an 8% rather than 0.8% salt solution a decontamination factor greater than 10 can be calculated since larger particles precipitate more readily. This only applies, however, under the condition that the washing water is renewed regularly, if necessary daily where higher aerosol concentrations are present. If not, the decontamination factor will be reduced through the salt-containing secondary aerosols from the washing ...
1983-01-01
Investigation of the removal efficiency of gasborne particles in a scrubber column
International Nuclear Information System (INIS)
Tests on the scrubbing column have led to the following results: Use of a scrubbing column with Raschig rings is only meaningful for the sedimentation of particles exceeding diameters of 0.5 #mu#m; drops of diameter size 1.5 #mu#m are formed in the column; more efficient drop precipitators in the column air flow ease the load on subsequent suspended material filters thereby contributing to a longer life of these filters even at higher sodium ion concentrations in the washing water; with distillate of an 8% rather than 0.8% salt solution a decontamination factor greater than 10 can be calculated since larger particles precipitate more readily. This only applies, however, under the condition that the washing water is renewed regularly, if necessary daily where higher aerosol concentrations are present. If not, the decontamination factor will be reduced through the salt-containing secondary aerosols from the washing ...
British Library Electronic Table of Contents (United Kingdom)
The comprehensive theoretical and experimental study of the adsorption of water and methanol molecules on active sites (carboxyl and phenol hydroxyl groups) on the graphitized thermal carbon black is performed. It is shown that microclusters formed upon the adsorption of these molecules on such sites are characterized by the cyclic structure comprising 4?5 molecules similar to that whose existence was revealed previously in liquid water and on the surface of silver iodide. The analysis of the studied adsorption clusters demonstrated that the formation of such cycles is governed primarily by the hydrogen bonding; however, a definite role is played also by energy effects associated with the changes in the state of molecular motion during adsorption. It is shown that the generalized Langmuir ...
2008-01-01
British Library Electronic Table of Contents (United Kingdom)
A study of the ordinary mild steel/cooling water interface, with and without inhibitor, was carried out using electrochemical impedance spectroscopy (EIS). EIS spectra in uninhibited medium reveal that a layer of corrosion and scale products is formed naturally and evolves with the immersion time. Monosaccharides derivatives were used as corrosion inhibitors. Most of them exhibit good behaviour against corrosion of ordinary steel in simulated water systems. Their inhibiting efficiency increases with concentration rise and depends on molecular structure especially -OH groups' position on two adjacent carbons and their number. In addition, the effect of MoO4^2^- on the corrosion inhibition in the presence of the best inhibitor was also studied by EIS. The addition of MoO4^2^- enhanced the in...
2009-01-01
British Library Electronic Table of Contents (United Kingdom)
A mechanism is proposed for the previously observed [1] jump in erythrocyte fluidity through a microcapillary 1.3 ?m in diameter at a temperature of 36.6?0.3?C. Our interpretation is based on the experimental evidence both for existence of ortho and para H2O isomers in water and on spin-selective interaction of proteins with para H2O isomers as hydration shells of biomolecules are being formed [2]. It is important that the formation of hydration shells of proteins and DNA in aqueous solutions is accompanied by an increase in the Brillouin shift to 0.4 cm?1 (?0.25 cm?1 in water), which points to the formation of icelike structures. We believe that the coincidence of the translational energy kT of the Brownian motion and the energy of the rotational quanta for the 313?202 transition of para ...
2009-01-01
Assembly of a water-insoluble strontium metal-organic framework with luminescent properties
British Library Electronic Table of Contents (United Kingdom)
A new strontium metal-organic framework, [Sr2(BTEC)(H2O)4] 2H2O (1) (H4BTEC=benzene-1,2,4,5-tetracarboxylic acid), has been successfully synthesized by mixing the starting reagents. The single-crystal structure analysis showed that compound 1 displayed three-dimensional structures containing inorganic motifs with two-dimensional layers pillar-connected through organic linkers and forming water-coordinated neutral framework. Further studies revealed that compound 1 was insoluble in water and that it emitted strong luminescence at approximately 437nm after dehydration.
2011-01-01
Regeneration of granular activated carbon using hydrothermal technology
Energy Technology Data Exchange (ETDEWEB)
The economic feasibility of using granular activated carbon (GAC) to remove organic contaminants from industrial and municipal wastewater is contingent upon its reuse during multiple adsorption-regeneration cycles. The most common process for the regeneration of GAC is the thermal method. Drawbacks associated with thermal regeneration include a 5--10% loss of carbon due to oxidation and attrition, a decrease in adsorption capacity, and high energy costs. The purpose of this study was to investigate the regeneration of GAC using hydrothermal technology. Phenol contaminated and non-contaminated GAC samples were regenerated using supercritical water (411 deg C and 26.2 MPa) with dissolved oxygen concentrations of 0 mg/L, 5 mg/L, and 100 mg/L. For comparative purposes, GAC was regenerated using subcritical water (300 deg C and 12.4 MPa) with a dissolved oxygen concentration of 5 mg/L. Regenerated GAC samples were evaluated in ...
1999-05-01
In situ heat transfer in man-made geothermal energy reservoirs
Energy Technology Data Exchange (ETDEWEB)
Two hot dry rock geothermal energy reservoirs were created by hydraulic fracturing of Precambrian granitic rock on the west flank of the Valles Caldera, a dormant volcanic complex, in the Jemez Mountains of northern New Mexico. Heat was extracted in a closed-loop mode of operation, injecting water into one well and extracting the heated water from a separate production well. The first reservoir was produced by fracturing the injection well at a depth of 2.75 km (9020 ft) where the indigenous rock temperature was 185/sup 0/C. The relatively rapid thermal drawdown of the water produced from the first reservoir, 100/sup 0/C in 74 days, indicated that its effective fracture radius was about 60 m (200 ft). Average thermal power extracted was 4 MW. A second, larger reservoir was created by refracturing the injection well 180 m (600 ft) deeper. Downhole measurements of the water temperature at the reservoir ...
1980-01-01
Upper Paleozoic petroleum system, Ordos Basin, China
Energy Technology Data Exchange (ETDEWEB)
The Ordos Basin is a typical lapped basin, including three sequences of strata: early Paleozoic, late Paleozoic and Mesozoic, with a total thickness of 4000-6000m. Impermeable sealing beds are well developed at the top and base of the upper Paleozoic sequence, separating it from the Mesozoic and the lower Paleozoic strata to form an independent petroleum system. In this petroleum system, the source rocks are widely distributed coals and dark mudstones occurring in the Carboniferous-lower Permian coal measures, with a thickness of 10-15 and 40-60m, respectively. The reservoirs are mainly early Permian tight sandstones, mostly with a porosity of 4-8% and a permeability of 0.1-1.0x10{sup -3}{mu}m{sup 2}. The regional cap rock is a 100-150m thick mudstone in the upper Permian strata. The structural framework of the basin is a huge asymmetric syncline, dipping gently toward the east and north, and steeply toward the south and west. Well data show that gas-saturated, ...
2005-09-01
Restoration of a forested wetland ecosystem in a thermally impacted stream corridor
Energy Technology Data Exchange (ETDEWEB)
The Savannah River Swamp is a 3,020 Ha forested wetland on the floodplain of the Savannah River and is located on the Department of Energy`s Savannah River Site (SRS). Major impacts to the swamp hydrology occurred with the completion of the production reactors and one coal-fired powerhouse at the SRS in the early 1950`s. Water was pumped from the Savannah River, through secondary heat exchangers of the reactors, and discharged into three of the tributary streams that flow into the swamp. This continued from 1954 to 1988 at various levels. The sustained increases in water volume resulted in overflow of the original stream banks and the creation of additional floodplains. Accompanying this was considerable erosion of the original stream corridor and deposition of a deep silt layer on the newly formed delta. Heated water was discharged directly into Pen Branch and water temperature in ...
1995-09-01
International Nuclear Information System (INIS)
This paper presents an overview of issues related to surface water contamination arising from uranium mining activities in the Alligator Rivers Region (ARR) of northern Australia, and a program of research and monitoring that must assess the potential and actual effects on ecosystem and human health. The program of assessing effects on aquatic ecosystems involves a four-tiered approach including the derivation of local water quality guideline trigger values, direct toxicity assessment of mine waters prior to their release, creekside or in situ monitoring for early warning of adverse effects during mine water release, and longer-term monitoring of macroinvertebrate and fish communities. Bioaccumulation in aquatic biota is also assessed, and is an issue of importance not only to ecosystem health, but also to the health of local Aboriginal people. The aquatic animals they consume represent potential ...
2002-12-27
Effect of vasopressin on ependymal and capillary permeability to tritiated water in cat
Energy Technology Data Exchange (ETDEWEB)
Ependymal cells line the cerebral ventricles forming the interface that separates the cerebrospinal (CSF) and interstitial fluids (ISF). Extracellular molecules move between ependymal cells, whereas lipid soluble molecules pass both between and through cells. We measured the transfer of tritiated water (TOH) from CSF to blood across the ependymal and capillary interfaces by ventriculocisternal (VC) steady-state tissue clearance. Adult cats anesthetized with pentobarbital sodium underwent VC perfusion with the extracellular marker (/sup 14/C)sucrose and TOH added to the artificial CSF. Brain tissue was analyzed for depth of penetration of the isotopes into periventricular gray matter. We found that TOH distribution space was lower than expected from water content measurements, whereas sucrose space was normal. Using VC steady-state equations we calculated an ependymal permeability that was similar to the permeability of the ...
1986-09-01
Spectral characteristics of lignite open cast mining systems: a preliminary status
Energy Technology Data Exchange (ETDEWEB)
The application of a Compact Airborne Spectrographic Imager to assessment and monitoring of lakes in a lignite open cast mining area in central Germany is described. The imager was used in combination with additional ground experiments, such as field spectroscopy and water sampling. The spectral characteristics of an instrument under development for monitoring geochemical and hydrological processes are presented. Summary form only.
1999-07-01
Radiation-polymerizable mixture and recording material containing it
International Nuclear Information System (INIS)
Esters of dihydric alcohols with alkenylphosphonic or alkenylphosphinic acids which are polymerizable by free radicals are described. They are combined with polymer binders, in particular water-soluble polymers, and photoinitiators forming free radicals to give photopolymerizable mixtures which are suitable for the production of photoresists and printing plates. The mixtures display low heat-sensitivity and have long shelf lives. (author) 1 tab.
1991-01-01
Lipophilic technetium complexes. Technetium chelates of some O, N, S donor Schiff bases
Energy Technology Data Exchange (ETDEWEB)
Dianionic tridentate, O, N, S, Schiff bases derived from salicylaldehyde and 2-mercapto-amines react with Tc(V) gluconate to form radiochemically pure neutral Tc chelates. The existence of lipophilic Tc complexes could be proved by high voltage electrophoresis, thin layer chromatography and octanol/water partition coefficients. 11 refs.
1984-04-02
Lipophilic technetium complexes. Technetium chelates of some O, N, S donor Schiff bases
International Nuclear Information System (INIS)
Dianionic tridentate, O, N, S Schiff bases derived from salicylaldehyde and 2-mercapto-amines react with Tc(V) gluconate to form radiochemically pure neutral Tc chelates. The existence of lipophilic Tc complexes could be proved by high voltage electrophoresis, thin layer chromatography and octanol/water partition coefficients. (author).
1984-04-01
Environmental Research Database
DescriptionThe importance of inorganic nitrate for the nutrition and growth of marine and freshwater autotrophic phytoplankton has long been recognised, in particularly because of the 'blooms' formed in nitrate and phosphate polluted water and their possible roles as carbon dioxide sinks. By contrast, the utilisation of nitrate by heterotrophic bacteria has historically received less attention. Up until now, the primary role of heterotrophic bacteria has classically been considered to be the decomposition [continued...
2010-01-31
Design of absorption columns in the presence of surfactants
Energy Technology Data Exchange (ETDEWEB)
An equation is described to estimate the value of the liquid-phase mass-transfer coefficient of aqueous solutions of surfactants from its value for pure water. The form of the equation is obtained from Levich's theory, and it is adjusted to experiments of absorption of CO/sub 2/ in aqueous solutions of five pure surfactants. The reduction of the absorption rate is correlated with the interfacial pressure of the solution.
1986-01-01
Energy Technology Data Exchange (ETDEWEB)
The application of airborne sensors for providing environmental assessment and monitoring of a test site in an open cast mining area that is part of a lignite deposit in central Germany is described. Hyperspectral remote sensing data from three different sensors were tested. The hyperspectral scanner data was suitable for classification of different sediments and vegetation types and the water chemistry of residual mining lakes. Summary form only. 1 tab.
1999-07-01
Apoptosis and Proliferation During DicWoroacetic Acid (DCA) Induced Hepatocellular Carcinogenesis in the F344 Male Rat Chlorine, introduced into public drinking \\\\'ater supplies for disinfection, can react with organic compounds in surface waters to form toxic by-prod...
A precise structure redetermination of nickel ammonium sulfate hexahydrate, Ni(H_2O)_6.2NH_4.2SO_4
International Nuclear Information System (INIS)
The Ni(H_2O)_6 ion is located at an inversion center. Six octahedral water molecules surround the Ni"I"I ion and form hydrogen bonds with the sulfate groups. Each ammonium group binds to the sulfate groups through hydrogen bonds. (orig.).
1994-05-01
A novel amphiphilic pincer palladium complex: design, preparation and self-assembling behavior.
Amphiphilic pincer palladium complexes bearing hydrophilic and hydrophobic side chains on the planar NCN palladium pincer backbone were designed and prepared via the ligand introduction route. The complexes self-assembled under aqueous conditions to form vesicles with bilayer membranes containing palladium species. The catalytic activity of the vesicles in the Miyaura-Michael reaction in water was investigated. PMID:21837316
2011-08-11
Numerical simulation of progressive inlet orifices in boiling water reactor fuel
International Nuclear Information System (INIS)
This thesis was carried out at Forsmark Nuclear Power Plant. The power plant in Forsmark consists of three boiling water reactors (BWR) which produce about 17% of Swedish electricity. In a BWR the nuclear reactions are used to boil water inside the reactor vessel. The water works both as a coolant and as a moderator and the resulting steam is used directly to run the turbines. A problem when running a BWR at low flow conditions is the density wave oscillations that might occur to the water flow inside the fuel assemblies. These oscillations arise due to the connection between power and flow rate in a heated channel with two-phase flow. In order to improve the stability performance of the channel an orifice plate is placed at the inlet of each fuel assembly. Today these orifice plates have sharp edges and a constant resistance coefficient. Experimental work has been done with progressive orifices, the ...
2004-01-01
Thermal and radiation losses in a linear device
Energy Technology Data Exchange (ETDEWEB)
An analysis is presented of the electron temperature in a linear device which includes the effect of thermal conduction, heat flux limit, radiation, and end plugs. It is found that the thermal conduction and the heat flux limit are dominant in the initial phase of cooling, while the later phase is almost completely controlled by radiation that spatially homogenizes the temperature distribution. In the case of bremsstrahlung, within the frame of the present model, the temperature decays to zero in a finite time. This process takes the form of a cooling wave that moves from the ends of the column to the center. Impurities cause a milder, exponential decay, which is still much faster than the algebraic conduction decay. The thermal effectiveness of the end plugs is described by a convective transfer coefficient h/sub p/. Its scaling law (in terms of the coupled plamsa-plug system) reveals that a very high plug-plasma density ratio provides a simple way to ...
1980-11-01
Superconducting A-15 compounds
International Nuclear Information System (INIS)
The critical superconducting paramters of A-15 compounds are reviewed, and the trends analysed in order to predict maximum values. Experimental data on critical temperature is summarized and compared with theory. The ability to form the stoichiometric, well-ordered materials required for maximum Tsub(c) is discussed in terms of the thermodynamic stability of the A-15 phase. It is concluded that critical temperatures in excess of 25 K, in the A-15 structure, are unlikely. The upper critical field data show that, whereas the vanadium-based compounds are paramagnetically limited, the niobium-based compounds are not. The relation between critical current and microstructure is explored. Best data on critical current densities and ac losses is presented. Finally an account is given of the various methods by which actual conductors, both tapes and multifilamentary wires, are made. (author).
Emittance of boehmite and alumina films on 6061 aluminium alloy between 295 and 773 K
International Nuclear Information System (INIS)
The total hemispherical emittance of an oxide film that formed on 6061-T6 aluminium alloy parts in the Tower Shielding Reactor-II at Oak Ridge National Laboratory was measured from 295 to 773 K using an emissometer and/or a calorimeter. The emittance of this film was critically needed for heat transfer calculations in a simulated loss-of-coolant accident of the reactor. X-ray diffraction analysis identified the film as boehmite (Al_2O_3 x H_2O), which dehydrated to alumina (Al_2O_3) upon heating above 473 K. The measured emittances for the alumina film are in excellent agreement with published values for anodized aluminum films and for bulk alumina. Published values of the emittance of boehmite could not be found for comparison, but evidence is presented that some anodization processes for aluminum yield boehmite and not alumina films.
1991-01-01
ECCS integrated test in TAPP-3 and 4
International Nuclear Information System (INIS)
Emergency Core Cooling System (ECCS) is a safety critical system provided to mitigate the consequence of Loss of Coolant Accident (LOCA) in PHWR. Unlike 220MWe, all header injection has been introduced in 540MWe to simplify the logic. ECCS Integrated Test is schematic approach to establish that ECC system will behave as per design intent during actual LOCA condition. Objective of ECCS Integrated test is to ascertain that various ECC system components operate as intended in design. Additionally, the various system resistances which form the input to LOCA analysis are validated. This test has been carried out by creating actual LOCA during cold and pressurised condition of PHT system to establish all phases of injection with overlap. This paper discusses the results obtained during the Integrated Test and comparison with the prediction during the commissioning of first unit of 540 MWe. (author)
2006-11-13
International Nuclear Information System (INIS)
The Cycle 8A static tests conducted in the Fast Flux Test Facility (FFTF) during 1986 have resulted in the separation of various feedback reactivity components. These feedback components, described by closed-form equations depending only on the reactor temperature field, can be regarded as database for the validation and/or calibration of feedback mechanistic models. The SASSYS safety analysis code contains the most developed feedback reactivity models and was selected for the comparison study between database and mechanistic calculations for the FFTF. Although detailed feedback models for control rod repositioning and core radial expansion/bowing exist, only the simple models were available in SASSYS at the time of this study. The results are described in this paper.
1988-05-01
International Nuclear Information System (INIS)
Because of the environmental hazard of organic solvents such as chlorinated or aromatic hydrocarbons, water soluble and biodegradable substitutes have come into use. It should be assessed how they affect soil and aquifer when spilled in leaks or accidents. This was simulated in a model system using methanol and percolation columns, one filled with material from the unsaturated subsurface and two with different materials from aquifers. The results reveal that a spill of the substitutes can also cause problems. In homogeneous soils and at long retention times until the substance reaches the aquifer, sorption and biological degradation are most likely to prevent contamination of the groundwater. When oxygen supply in the subsurface is insufficient, reducing conditions occur and sulphide is formed. The data show that much more methanol was eliminated than reflected by the consumption of electron acceptors. This indicates that sorption and anabolic ...
1993-04-01
Effect of dissolved oxygen on denting corrosion
International Nuclear Information System (INIS)
The following conclusions are drawn from the study of the effects of dissolved oxygen on corrosion denting: 1) Following the ingress of fresh-water contamination into a PWR boiler, an acidic chloride solution can be formed in the crevice between tube and tube support plate when an oxidant such as dissolved oxygen or copper ions is present in the boiler water. 2) In the absence of copper, very high levels of dissolved oxygen and neutral chloride are necessary to initiate corrosion. 3) When copper is present in the feed system, sufficient copper ions to initiate corrosion within the crevice are released when the chloride concentration is 0.8 mg/kg and probably also at lower chloride values. Corrosion initiation however may require prior exposure of the copper to dissolved oxygen and can be suppressed by pretreatment with hydrazine. 4) The effect of dissolved oxygen on corrosion already occurring was not explored; neither was ...
1985-03-01
British Library Electronic Table of Contents (United Kingdom)
Summary - Hydraulic traits were studied in temperate, woody evergreens in a high-elevation heath community to test for trade-offs between the delivery of water to canopies at rates sufficient to sustain photosynthesis and protection against disruption to vascular transport caused by freeze-thaw-induced embolism. - Freeze-thaw-induced loss in hydraulic conductivity was studied in relation to xylem anatomy, leaf- and sapwood-specific hydraulic conductivity and gas exchange characteristics of leaves. - We found evidence that a trade-off between xylem transport capacity and safety from freeze-thaw-induced embolism affects photosynthetic activity in overwintering evergreens. The mean hydraulically weighted xylem vessel diameter and sapwood-specific conductivity correlated with susceptibility to...
2011-01-01
Wetlands: their use and regulation
Energy Technology Data Exchange (ETDEWEB)
Although destruction of United States wetlands has slowed, their continued conversion, especially in certain inland regions of the country, may pose adverse ecological effects over the next few decades. The Army Corps of Engineers' regulatory program (Section 404 of the Clean Water Act) protects most coastal wetlands, but provides no protection for 95% of the country's wetlands which remain inland. These inland, freshwater wetlands, converted for agricultural purposes, comprise 80% of the wetland losses over the past 30 years. This report outlines options for more effective federal management, such as the mapping and categorizing of wetlands to determine relative values. In effect, agencies can focus protection programs on higher-value wetlands, especially those threatened by agricultural conversion. The report also discusses the contradictory federal policies aimed at wetlands; for example, the tax code encourages the ...
1984-01-01
The efficiency of coal-fired combined-cycle powerplants
Energy Technology Data Exchange (ETDEWEB)
Concepts involving combined gas-turbine/steam-turbine power-generation plants, in which the fuel gas for the gas turbine is produced via the gasification of coal, are now extremely advanced. This technology already permits efficiencies of around 50% current development targets view 65% as achievable. In conventional technology, efficiencies are tied to conditions, such as air and cooling-water temperatures, at the particular location. In combined-cycle power plants, the properties of the fuel coal also play an important part. There are, in face, coals which can be more advantageously used in a combined-cycle power plant than in a conventional one. These differences, combined with advantageous concepts for coal-fired combined-cycle power-generating plants, are presented and analyzed. Particular attention is devoted to individual losses occurring at coal conversion, thermodynamic cycles, integration of processes and internal consumptions. 14 ...
1996-12-01
Energy Technology Data Exchange (ETDEWEB)
Since 1976, the Nuclear Engineering Laboratory of the Technical Research Centre of Finland and Lappeenranta University of Technology have cooperated in the field of nuclear reactor thermal-hydraulics. During these years, a series of experimental facilities (REWET-I, -II, -III, VEERA) simulating pressurized water reactors (PWRs) have been built. The newest facility, PACTEL (Parallel Channel Test Loop), is an experimental out-of-pile facility designed to simulate the major components and system behaviour of a commercial PWR during postulated small and medium size break loss-of-coolant accidents (LOCAs), natural circulation and operational transients. A PACTEL natural circulation experiment has been carried out as an OECD/NEA international standard problem ISP 33. (2 refs., 3 figs., 2 tabs.).
1993-12-31
Natural circulation decay heat removal experiments and analysis in an LMFBR fuel assembly
International Nuclear Information System (INIS)
Water flow experiments were conducted on natural circulation decay heat removal with an electrically heated 91-rod bundle. Experimental results were compared with analytical predictions to provide thermal hydraulic characteristics for LMFBR Fuel assemblies under a low flow, typical of the natural circulation regime. The results revealed that, at low flow rate region (Re<1,200), axial friction loss in a heated bundle increases with buoyancy effect. The radial temperature profile provides some insight regarding the concept that coolant redistribution would occur. COBRA-V-I predictions are successfully proved validity in comparison with experimental results.
1982-07-01
Estimating the erosion and deposition rates in a small watershed by the 137Cs tracing method
International Nuclear Information System (INIS)
Understanding the erosion and deposition rates in a small watershed is important for designing soil and water conservation measures. The objective of this study is to estimate the net soil loss and gain at points with various land use types and landform positions in a small watershed in the Sichuan Hilly Basin of China by the 137Cs tracing technique. Among various land use types, the order of erosion rate was bare rock > sloping cultivated land > forest land. The paddy field and Caotu (a kind of cultivated land located at the foot of hills) were depositional areas. The erosion rate under different landform was in this order: hillside > saddle > hilltop. The footslope and the valley were depositional areas. The 137Cs technique was shown to provide an effective means of documenting the spatial distribution of soil erosion and deposition within the small watershed.
2009-02-01
International Nuclear Information System (INIS)
A research was started aiming at evaluating the possible use of natural zeolites as exchange conditioners to improve and make durable the soil resilience against the adverse effects of the use of anomalous waters for irrigation purposes. This paper deals with a preliminary investigation on the comparative resilience of an Entisol with poor exchange properties and of a Neapolitan yellow tuff (NYT) sample against the adverse features of a dirty municipal sewage (DSW). Results showed that NYT treatment largely and significantly improved the poor soil exchange activity. In particular. NYT exchange sites selectively took up ammonium from DSW. As a consequence, ammonium was trapped, then protected against losses in the environment and, concurrently, exchangeable cations, such as K and Ca, were made free as plant nutrients. The results highlight the possible positive role of zeolitized tuff in restoring and sustaining soil resilience.
Clean combustion of solid fuels
International Nuclear Information System (INIS)
A chemical-looping process is proposed for the clean combustion of solid fuels for electric power or heat generation. The process is based on coal gasification with CO_2 to produce CO. The CO then reduces CaSO_4, which is used as an oxygen carrier, in a separate reactor to give CaS and CO_2. A portion of the CO_2 is recycled for the gasification stage and the rest can be sent for sequestration. The CaS is sent to another reactor for oxidation with air and to generate heat or power. The overall thermal effect is the same as direct combustion, but separation of CO_2 and other pollutants, such as sulphur, is achieved. In comparison with conventional chemical-looping combustion of natural gas, much less water is present in the CO_2 product, and hence the loss of heat energy and corrosion of the fuel-reactor system can be reduced.
2008-01-01
Characteristics of the flow-controlled accumulator
International Nuclear Information System (INIS)
Mitsubishi is developing a new type of accumulator incorporating the technology of fluidics as one of the seeds for the improved safety of the newly constructed pressurized water reactor plants. This accumulator employs a vortex flow control device, called a vortex damper, as a fluidic device to simplify the safety systems. A fundamental experimental study with a one-fifth scale model and confirmation tests with a one-third scale model to develop the vortex damper have been carried out, and satisfactory results have been achieved. The results of the confirmation tests under the prototype pressure conditions agree well with the basic tests. The flow rate ratio can be 5 to 6. The pressure loss coefficient in the large flow rate period is 8. A cavitation factor is the main parameter of the flow rate coefficient.
Aerogels: the leading edge in thermal insulation
Energy Technology Data Exchange (ETDEWEB)
Banning CFCs in foamed insulations has led to an intensive search for alternatives which do not incur the penalty of increased thickness. The most promising of these are silica aerogels, which have proven to be the leading material, when it comes to thermal insulation and environmental protection. Refrigerators insulated with aerogels have been tested and compared to conventionally insulated ones. Results showed a substantial contribution to the energy performance. Boiler manufacturers using aerogel have been able to reduce energy consumption of water heaters by 20%. Float glass elements evacuated and filled with aerogel as well as aerogel insulated polyester lightwalls and bubble skylights yield excellent U-values and significantly reduced energy losses in buildings. (author)
1995-01-01
Accelerated aging corrosion tests for buried metal structures
Energy Technology Data Exchange (ETDEWEB)
It is necessary to identify those measurable soil parameters which dictate the severity of the corrosion problem for coated irons and steels. When this is done, meaningful accelerated aging tests can be designed to validate the reduced corrosion rate for the planned coating. The following discussion introduces the important concepts and measurement parameters in the (a) design of accelerated aging tests, and (b) evaluation of the planned installation site for corrosion potential. Certain combinations of soil oxidation reduction potential (ORP) or electric potential (Eh), acidity (pH), fertilizer, water table, and soil hydraulic conductivity can result in severe corrosion of buried steel/iron vessels. If there are power lines nearby, additional loss of vessel material to the soil will occur. These factors are discussed.
1996-10-01
Energy Technology Data Exchange (ETDEWEB)
Alloy 690 and Alloy600 are used as a material for the steam generator tubing in the pressurized water reactor(PWR) of nuclear power plants due to its high corrosion resistance. Although those are a highly corrosion resistance material, their stress corrosion cracking(SCC) have been found on occasion, which are deeply related to a surface oxide film on a base material which have occurred on the primary side as well as the secondary side of a tubing. And The SCC is accelerated in the existing Pb which is the impurity of secondary steam generator components. The Oxide on a steel surface in an aqueous solution above 100 .deg. C is composed of a duplex film structure. The inner layer of the oxide is dense and less porous, which is formed by a growth of the oxide layer on the metal surface. The outer layer of the oxide is less adhesive, which is formed by a dissolution and precipitation mechanism. Growth processes of the inner ...
2008-10-15
International Nuclear Information System (INIS)
Alloy 690 and Alloy600 are used as a material for the steam generator tubing in the pressurized water reactor(PWR) of nuclear power plants due to its high corrosion resistance. Although those are a highly corrosion resistance material, their stress corrosion cracking(SCC) have been found on occasion, which are deeply related to a surface oxide film on a base material which have occurred on the primary side as well as the secondary side of a tubing. And The SCC is accelerated in the existing Pb which is the impurity of secondary steam generator components. The Oxide on a steel surface in an aqueous solution above 100 .deg. C is composed of a duplex film structure. The inner layer of the oxide is dense and less porous, which is formed by a growth of the oxide layer on the metal surface. The outer layer of the oxide is less adhesive, which is formed by a dissolution and precipitation mechanism. Growth processes of the inner ...
2008-10-01
Deployment Support Leading to Implementation
Energy Technology Data Exchange (ETDEWEB)
The following paragraphs summarize the progress of each research project funded under the WVU Cooperative Agreement during the third quarter of 1997 (July - September 1997). The projects are arranged according to their 1997 WVU task number. WVU Focus Area 1.0: Subsurface Contaminants, Containment and Remediation Task No. 1.1: Project discontinued. Task No. 1.2: Development of Standard Test Protocols and Barrier Design Models for Desiccation Barriers (K. Amininan & S. Ameri): A number of experiments were preformed this period to evaluate the ability of the dried sand-packs to act as a barrier to liquids. Water infiltration tests were done with a constant head, dispersing 80 ml of water, and by adding water in small increments. Results indicate that when the water is spilled over the sand-pack, it has the tendency to channel through the sand-pack, significantly reducing the capacity of the dried zone ...
1997-10-01
Energy Technology Data Exchange (ETDEWEB)
Plasma arc welding processes are used in off-shore industry for construction and maintenance in the wet surrounding of underwater structures and pipelines. In greater water depth the density of the plasma gas increase because of the greater hydrostatic pressure. This causes the increase of conductive heat losses to the wet surrounding. To keep up the energy flux to the workpiece to be welded, the plasma arc has to burn in a local dry area with an inside pressure of 1 bar. This requirement can be fulfilled by a rotating cylinder with a liquid film flowing down the inner wall. The flow around the rotating cylinder to create a local dry area around the plasma arc under water is experimentally investigated. The rotating cylinder is placed above the work surface which is simulated by a flat plate. According to the centrifugal forces of the rotating flow inside the gap between the lower end of the cylinder and the flat plate the ...
1994-12-31
Energy Technology Data Exchange (ETDEWEB)
Hydrogen injection into the reactor water has been applied to many BWR power stations. Since hydrogen injected accelerates recombination of oxidant generated by water radiolysis, oxidant concentration, such as dissolved oxygen concentration in reactor water can be reduced. As the result of the reduction of oxidant concentration, Electrochemical Corrosion Potential (ECP) at the surface of structural material can be lowered. Lowered ECP moderates Stress Corrosion Cracking (SCC) sensitivity of structural materials, such as stainless steels. As usual, hydrogen injection system begins to work after the plant start-up is finished, when the condition of normal operation is established. Accordingly, Hydrogen Water Chemistry (HWC) does not cover all the period of plant operation. As far as SCC crack growth is considered, loss of HWC during plant start-up does not result in significant crack ...
2004-07-01
International Nuclear Information System (INIS)
Manganese is a common contaminant of mine water and other waste waters. Due to its high solubility over a wide pH range, it is notoriously difficult to remove from contaminated waters. Previous systems that effectively remove Mn from mine waters have involved oxidising the soluble Mn(II) species at an elevated pH using substrates such as limestone and dolomites. However it is currently unclear what effect the substrate type has upon abiotic Mn removal compared to biotic removal by in situ micro-organisms (biofilms). In order to investigate the relationship between substrate type, Mn precipitation and the biofilm community, net-alkaline Mn-contaminated mine water was treated in reactors containing one of the pure materials: dolomite, limestone, magnesite and quartzite. Mine water chemistry and Mn removal rates were monitored over a 3-month period in ...
2006-08-01
Thermal convection loop study of corrosion of alloy 800 in molten NaNO/sub 3/-KNO/sub 3/
Energy Technology Data Exchange (ETDEWEB)
Maximum metal loss rate of Alloy 800 coupons was about 0.5 mil/year and occurred at the maximum temperature of 600/sup 0/C. Significantly greater oxide penetration into the alloy occurred in unabraded as-received tubing. Since the corrosion rate of unabraded tubing was less temperature sensitive than polished coupons, and attained a maximum value at temperatures in the range of 550 to 565/sup 0/C, a value of 1 mil/year should be used as the corrosion rate for design purposes. Because daily thermal cycling is inherent in solar central receiver operation, oxidation and chromium depletion rates can be expected to increase if surface oxide layers spall. The oxide layers formed on Alloy 800 appeared to be adherent, and adherence will benefit further from growth-derived compressive stresses in oxide layers on the salt-exposed inner diameter of receiver tubes. Since the lower duty factor in diurnal solar service may offset the accelerated metal ...
1983-01-01
Norepinephrine stimulates the growth of a range of bacterial species in nutritionally poor SAPI minimal salts medium containing 30% serum. Addition of size-fractionated serum components to SAPI medium indicated that transferrin was required for norepinephrine stimulation of growth of Escherichia coli. Since bacteriostasis by serum is primarily due to the iron-withholding capacity of transferrin, we considered the possibility that norepinephrine can overcome this effect by supplying transferrin-bound iron for growth. Incubation with concentrations of norepinephrine that stimulated bacterial growth in serum-SAPI medium resulted in loss of bound iron from iron-saturated transferrin, as indicated by the appearance of monoferric and apo- isoforms upon electrophoresis in denaturing gels. Norepinephrine also caused the loss of iron from lactoferrin. The pharmacologically inactive metabolite norepinephrine 3-O-sulfate, by contrast, did not result in ...
2000-11-01
Energy Technology Data Exchange (ETDEWEB)
This document presents the analysis of the simulation of the loss of coolant accident at uprate power conditions, that is 2027 MWt (105% of the current rated power of 1931MWt). This power was reached allowing an increase in the turbine steam flow rate without changing the steam dome pressure value at its rated conditions (1020 psiaJ. There are also presented the results of the simulation of the main steam isolation va/ve transient at overpressure conditions 1065 psia and 1067 MWt), for Laguna Verde Nuclear Power Station. Both simulations were performed with the best estimate computer code TRA C BF1. The results obtained in the loss of coolant accident show that the emergency core coolant systems can recover the water level in the core before fuel temperature increases excessively, and that the peak pressure reached in the drywell is always below its design pressure. Therefore it is concluded that the integrity of the ...
2001-07-01
High-efficiency solar cell and method for fabrication
A high-efficiency 3- or 4-junction solar cell is disclosed with a theoretical AM0 energy conversion efficiency of about 40%. The solar cell includes p-n junctions formed from indium gallium arsenide nitride (InGaAsN), gallium arsenide (GaAs) and indium gallium aluminum phosphide (InGaAlP) separated by n-p tunnel junctions. An optional germanium (Ge) p-n junction can be formed in the substrate upon which the other p-n junctions are grown. The bandgap energies for each p-n junction are tailored to provide substantially equal short-circuit currents for each p-n junction, thereby eliminating current bottlenecks and improving the overall energy conversion efficiency of the solar cell. Additionally, the use of an InGaAsN p-n junction overcomes super-bandgap energy losses that are present in conventional multi-junction solar cells. A method is also disclosed for fabricating the high-efficiency 3- or 4-junction solar cell by ...
1999-08-31
Enhancement of N-nitrosamine formation on granular-activated carbon from N-methylaniline and nitrite
Energy Technology Data Exchange (ETDEWEB)
Sterile aqueous N-methylaniline solutions were allowed to equilibrate at various nitrite, F-400 granular-activated carbon, and pH levels for 1 week. The aqueous and activated carbon phases were extracted and analyzed for nitrosamines relative to an added internal standard. Selected ion monitoring GC/MS, utilizing continuous monitoring of the NO/sup +/ ion (m/z 29.9980) characteristic of nitrosamines, at medium resolution (R = 2500-3000) was applied to quantitatively measure nitrosamines at picograms per microliter concentrations. This method selected for nitrosamine products only and eliminated interferences from non-nitrosamine reaction products. Results indicate that the pressure of granular-activated carbon significantly enhanced the formation of nitrosamine from N-methyl-aniline (F = 145, P< 0.0001). The amount of N-nitrosomethylaniline formed in the presence of activated carbon was 75 times more than that formed in the absence of ...
1986-10-01
Energy Technology Data Exchange (ETDEWEB)
For high-efficiency coal gasification, investigations were given on effect of coal chars with different conversion rates on coal gasification reactivity. In coal gasification, reactivity of char after pyrolysis governs the efficiency. The reference char conversion in CO2 gasification of coal (weight loss) changes linearly in the initial stage of the reaction, but the reactivity declines as the end point is approached. Char surface area is as large as 400 m{sup 2}/g in the initial stage with the conversion at 20%, but it decreases in the final stage. This phenomenon relates closely with changes in pore size and crystalline structure. Change in the Raman value R which shows incompleteness of char graphite structure and amorphous carbon ratio suggests that an active portion with high reactivity is oxidized preferentially, and a portion with low reactivity remains finally. Minerals in coal are known to accelerate the gasification. However, their catalytic effect is ...
1996-10-28
Ecological aspects of air pollution emissions from an iron ore sintering plant in Ontario
Sulfur dioxide emissions from an iron ore sintering plant have severely damaged vegetation up to 16 km northeast of the source. Concentric zones of increasing vegetation loss have formed around the point of maximum ground level concentration of the gas. Species diversity, sulfur and heavy metal concentrations in vegetation and soil amount to SO/sub 2/ injury were measured along a transect through the injury zones. Surrounding a central denuded area were zones dominated respectively by tussock-forming hair grass (Deschampsia flexuosa); low-growing shrubs and trailers (Sambucus pubens, Polygonum cilinode); higher-growing shrubs and suckering Populus tremuloides and Betula papyrifera) stunted forest tree species (Populus, Betula, Picea glauca, Abies Balsamea), and finally, normal boreal forest flora. Although SO/sub 2/ injury is continuing in this area, these zones now appear to be maintained primarily by severe erosion and ...
1975-01-01
International Nuclear Information System (INIS)
In General Electric's design of the Simplified Boiling Water Reactor (SBWR), The depressurization valves (DPV) are installed in the reactor pressure boundary: four are connected to the reactor vessel by means of nozzles, and two more are located on the main steam pipes (one DPV for each line), which act during particular transients and/or loss of coolant accidents (LOCA), consequently providing the reactor vessel with a safe quick depressurization system. Once the vessel is de pressurised, the passive gravity-driven cooling system (GDCS) starts to operate, permitting the injection of water required for continuous core cooling. DPVs are leak tight, with welded flaps, actuated by a [striker[hammer***] which is activated by an explosive mixture. The dynamic loads that open these valves include, in addition to those produced by steam (typical in any thermodynamic transient with open/close valves), other important loads that are ...
Two-fluid modeling of condensation in the presence of noncondensables in two-phase channel flows
Energy Technology Data Exchange (ETDEWEB)
Condensing two-phase channel flow occurs in many industrial applications, including heating and refrigeration systems. It can also occur in certain nuclear reactor accidents. For example, during a small-break loss-of-coolant accident in a pressurized water reactor, following the partial depletion of the primary coolant, condensation of steam on the primary side of the steam generator tubes can provide a heat sink for disposal of the decay heat generated in the reactor core. Condensing two-phase flow can also play an important role in the operation of the passive emergency cooling system in the advanced simplified boiling water reactor. Here, steady-state condensation in the presence of a noncondensable in a concurrent two-phase channel flow is analyzed using a two-fluid model. The effect of noncondensables on the combined heat transfer at the liquid-gas mixture interphase is accounted for by using the stagnant film model, ...
1995-01-01
Simulation experiments for hot-leg U-bend two-phase flow phenomena
International Nuclear Information System (INIS)
In order to study the two-phase natural circulation and flow termination during a small break loss of coolant accident in LWR, simulation experiments have been performed. Based on the two-phase flow scaling criteria developed under this program, an adiabatic hot leg U-bend simulation loop using nitrogen gas and water and a Freon 113 boiling and condensation loop were built. The nitrogen-water system has been used to isolate key hydrodynamic phenomena from heat transfer problems, whereas the Freon loop has been used to study the effect of phase changes and fluid properties. Various tests were carried out to establish the basic mechanism of the flow termination and reestablishment as well as to obtain essential information on scale effects of parameters such as the loop frictional resistance, thermal center, U-bend curvature and inlet geometry. In addition to the above experimental study, a preliminary modeling study has been ...
1986-10-27
Simulation experiments for hot-leg U-bend two-phase flow phenomena
Energy Technology Data Exchange (ETDEWEB)
In order to study the two-phase natural circulation and flow termination during a small break loss of coolant accident in LWR, simulation experiments have been performed. Based on the two-phase flow scaling criteria developed under this program, an adiabatic hot leg U-bend simulation loop using nitrogen gas and water and a Freon 113 boiling and condensation loop were built. The nitrogen-water system has been used to isolate key hydrodynamic phenomena from heat transfer problems, whereas the Freon loop has been used to study the effect of phase changes and fluid properties. Various tests were carried out to establish the basic mechanism of the flow termination and reestablishment as well as to obtain essential information on scale effects of parameters such as the loop frictional resistance, thermal center, U-bend curvature and inlet geometry. In addition to the above experimental study, a preliminary modeling study has been ...
1986-01-01
Results of two-phase natural circulation in hot-leg U-bend simulation experiments
Energy Technology Data Exchange (ETDEWEB)
In order to study the two-phase natural circulation and flow termination during a small break loss of coolant accident in LWR, simulation experiments have been performed using two different thermal-hydraulic loops. The main focus of the experiment was the two-phase flow behavior in the hot-leg U-bend typical of BandW LWR systems. The first group of experiments was carried out in the nitrogen gas-water adiabatic simulation loop and the second in the Freon 113 boiling and condensation loop. Both of the loops have been designed as a flow visualization facility and built according to the two-phase flow scaling criteria developed under this program. The nitrogen gas-water system has been used to isolate key hydrodynamic phenomena such as the phase distribution, relative velocity between phases, two-phase flow regimes and flow termination mechanisms, whereas the Freon loop has been used to study the effect of fluid properties, ...
1987-01-01
Potential for hot-dry-rock geothermal resources: experimental results
Hot dry rock (HDR) contains insufficient permeability and fluid for natural hydrothermal development, but water pumped in a circulation loop through a HDR reservoir (hydraulically fractured between two drill holes) is being tested and evaluated. The formation of such in situ heat transfer systems, and subsequent testing of the man-made geothermal reservoirs in the Jemez volcanic field, New Mexico have already indicated the technical feasibility of the hot dry rock (HDR) geothermal concept. Documented production history and heat-extraction data obtained during the period from 1978 to 1980 have confirmed heat transfer, low water loss, and predictable thermal drawdown models for the HDR systems. During a nine month test of closed-loop heat extraction operations, 15 x 10/sup 6/ kWh of thermal energy were produced. The effective heat-transfer area and volume of the reservoir increased due to secondary fracturing caused by ...
1982-01-01
Energy Technology Data Exchange (ETDEWEB)
The prediction of two-phase flow regime in the horizontal pipings during a loss-of-coolant accident (LOCA) is important for safety analysis of a pressurized water reactor (PWR). The flow regime transition conditions for a horizontal two-phase air-water flow were studied using a large-height, horizontal rectangular duct test section. The duct dimensions were 700 mm in height, 100 mm in width and 28.3 m in length. The experimental criterion for the flow regime transition from the stratified to slug flow regimes, in terms of the local void fraction and the non-dimensional gas-liquid relative velocity, agreed qualitatively with the prediction by the Mishima-Ishii model that is based on an idea that the interfacial waves with the largest growth rate will develop into a slug. However, the transition in the experiment occurred at systematically lower (by about 40 %) relative velocities than the prediction by the Mishima-Ishii ...
1992-02-01
British Library Electronic Table of Contents (United Kingdom)
Abstract BACKGROUND: Nitrate leaching and the resulting groundwater contamination from intensive cereal production has become a major concern for long-term farmland efficiency and environmental sustainability in northern China. The aim of this study was to evaluate a water-saving super-absorbent polymer (SAP) for minimising NO3- leaching from soil and optimising corn growth and yield. Thirty-six undisturbed soil lysimeters were installed in a field lysimeter facility in drought-affected northern China to study the growth and yield characteristics of summer corn (Zea mays L.) as well as the amount of NO3-leaching losses under different fertiliser (standard, medium or 75% and low, or 50% of conventional fertilisation rate) and SAP (control, 0; level-1, 15 kg ha-1 and level-2, 30 kg ha-1) tre...
2011-01-01
Terrestrial Planet Formation in Extra-Solar Planetary Systems
Terrestrial planets form in a series of dynamical steps from the solid component of circumstellar disks. First, km-sized planetesimals form likely via a combination of sticky collisions, turbulent concentration of solids, and gravitational collapse from micron-sized dust grains in the thin disk midplane. Second, planetesimals coalesce to form Moon- to Mars-sized protoplanets, also called "planetary embryos". Finally, full-sized terrestrial planets accrete from protoplanets and planetesimals. This final stage of accretion lasts about 10-100 Myr and is strongly affected by gravitational perturbations from any gas giant planets, which are constrained to form more quickly, during the 1-10 Myr lifetime of the gaseous component of the disk. It is during this final stage that the bulk compositions and volatile (e.g., water) contents of terrestrial planets are set, depending on their ...
2008-01-01
Influence of temperature on strength of cemented surrogate nitrate salt waste
Energy Technology Data Exchange (ETDEWEB)
The Rocky Flats Plant (RFP) generates large volumes of a low level aqueous waste stream high in nitrate salts. The aqueous waste is concentrated by evaporation and then mixed with Portland cement prior to transport and disposal. Planned process upgrades include a new horizontal thin film evaporator. Temperature of brine at discharge end of the new evaporator will be near boiling point. Introduction of hot water to cement can degrade the monolithic waste form. However, the RFP salt waste contains high concentrations of compounds known to retard hydration. This paper discusses impact of introducing high temperature waste to cement. The study evaluated three waste compositions: (1) highest probable nitrate composition, (2) highest probable chloride composition, and (3) current composition. Results showed that compressive strength of final waste form increased with brine temperature, and waste forms from ...
1993-01-01
Influence of temperature on strength of cemented surrogate nitrate salt waste
Energy Technology Data Exchange (ETDEWEB)
The Rocky Flats Plant (RFP) generates large volumes of a low level aqueous waste stream high in nitrate salts. The aqueous waste is concentrated by evaporation and then mixed with Portland cement prior to transport and disposal. Planned process upgrades include a new horizontal thin film evaporator. Temperature of brine at discharge end of the new evaporator will be near boiling point. Introduction of hot water to cement can degrade the monolithic waste form. However, the RFP salt waste contains high concentrations of compounds known to retard hydration. This paper discusses impact of introducing high temperature waste to cement. The study evaluated three waste compositions: (1) highest probable nitrate composition, (2) highest probable chloride composition, and (3) current composition. Results showed that compressive strength of final waste form increased with brine temperature, and waste forms from ...
1993-03-01
Incorporation of flying ashes into cold-stabilized argillaceous products
Energy Technology Data Exchange (ETDEWEB)
Clay-based materials can be cold-stabilized using binder and formed by extrusion. This paper deals with the properties of such materials under the influence of silico-aluminous flying ashes addition. Flying ashes are solid industrial wastes produced by coal combustion. Characteristics of ashes bearing clay-based products, such as dimensional stability, water and mechanical resistance, accelerated aging, are considerably improved with respect to simple clay-binder mixtures. This is principally due to a better hydration of the binder in ashes-bearing mixtures because of: a higher free-water availability as a consequence of the smaller specific surface of ash grains, the filler effect of ash grains which do not participate to the reactions, the specific property of silico-aluminous ashes that can fix the lime in presence of water to produce hydrated compounds. These ashes-bearing clay based materials can ...
1996-12-01
International Nuclear Information System (INIS)
Ozone formation by a pulse positive corona discharge generated in the gas phase between a planar high voltage electrode made from reticulated vitreous carbon and a water surface with an immersed ground stainless steel plate electrode was investigated under various operating conditions. The effects of gas flow rate (0.5-3 litre min"-"1), discharge gap spacing (2.5-10 mm), applied input power (2-45 W) and gas composition (oxygen containing argon or nitrogen) on ozone production were determined. Ozone concentration increased with increasing power input and with increasing discharge gap. The production of ozone was significantly affected by the presence of water vapour formed through vaporization of water at the gas-liquid interface by the action of the gas phase discharge. The highest energy efficiency for ozone production was obtained using high voltage pulses of approximately 150 ns duration in Ar/O_2 ...
2005-02-07
Emergency reactor core cooling device
International Nuclear Information System (INIS)
The device of the present invention improves reactor safety by suppressing lowering of water level in a shroud which surrounds a reactor core, even upon occurrence of rupture of pipelines in an emergency reactor core cooling system in a recycling pump-incorporated type reactor. Namely, an opening of each of cooling systems which forms the emergency reactor core cooling device in a reactor pressure vessel is disposed above the upper end of the reactor core. Further, it also comprises an independent high pressure water injection system, gravitational dropping type water injection system and an automatic depressurization system. With such a constitution, even if rupture of pipelines in the system should be assumed, coolants never flow directly from the shroud which surrounds the reactor core. In addition, there are no pipelines to be ruptured below the upper end of the reactor core with respect to the ...
1993-03-16
Energy Technology Data Exchange (ETDEWEB)
Chlorine is widely used in drinking water disinfection due to be a powerful and not expense disinfection. Although the benefits of disinfection, the formation of stable disinfection by-products of the health concern, is the result of the interaction of aqueous chlorine with natural organic matter presents in water. Disinfection by-products generated in major concentration are trihalomethane and haloacetic acids. Disinfection by-products generated in minor concentration are haloacetonitriles, haloketones,chloral hydrate and chloropicrin and some new groups such as cyanogen halides and trihaloacetaldydes. In this work two analytical methods.: headspace/gas chromatography/electron capture detector and liquid-liquid microextraction/gas chromatography/electron capture detector are studied and compared to determine the minor by-products and to establish finally, a systematic control of them in the different stages of the Water ...
1997-09-01
Atomistic Simulation of Water Percolation and Proton Hopping in Nafion Fuel Cell Membrane
Energy Technology Data Exchange (ETDEWEB)
We have performed a detailed analysis of water clustering and percolation in hydrated Nafion configurations generated by classical molecular dynamics simulations. Our results show that at low hydration levels H2O molecules are isolated and a continuous hydrogen-bonded network forms as the hydration level is increased. Our quantitative analysis has established a hydration level (?) between 5 and 6 H2O/SO3- as the percolation threshold of Nafion. We have also examined the effect of such a network on proton transport by studying the structural diffusion of protons using the quantum hopping molecular dynamics method. The mean residence time of the proton on a water molecule decreases by two orders of magnitude when the ? value is increased from 5 to 15. The proton diffusion coefficient in Nafion at a ? value of 15 is about 1.1x10-5 cm2/s in agreement with experiment. The results provide quantitative atomic-level evidence of ...
2010-11-04
A Cloud Computing Approach to Personal Risk Management: The Open Hazards Group
According to the California Earthquake Authority, only about 12% of current California residences are covered by any form of earthquake insurance, down from about 30% in 1996 following the 1994, M6.7 Northridge earthquake. Part of the reason for this decreasing rate of insurance uptake is the high deductible, either 10% or 15% of the value of the structure, and the relatively high cost of the premiums, as much as thousands of dollars per year. The earthquake insurance industry is composed of the CEA, a public-private partnership; modeling companies that produce damage and loss models similar to the FEMA HAZUS model; and financial companies such as the insurance, reinsurance, and investment banking companies in New York, London, the Cayman Islands, Zurich, Dubai, Singapore, and elsewhere. In setting earthquake insurance rates, financial companies rely on models like HAZUS, that calculate on risk and exposure. In California, the process begins ...
2010-12-01
Development of materials resistant to metal dusting degradation.
Energy Technology Data Exchange (ETDEWEB)
Metal dusting corrosion has been a serious problem in the petroleum and petrochemical industries, such as reforming and syngas production systems. This form of deterioration has led to worldwide material loss for 50 years. For the past three years, we have studied the mechanism of metal dusting for Fe- and Ni-base alloys. In this report, we present a correlation between the weight loss and depth of pits that form in Ni-base alloys. Nickel-base alloys were also tested at 1 and 14.8 atm (210 psi), in a high carbon activity environment. Higher system pressure was found to accelerate corrosion in most Ni-base alloys. To reduce testing time, a pre-pitting method was developed. Mechanical scratches on the alloy surface led to fast metal dusting corrosion. We have also developed preliminary data on the performance of weldments of several Ni-base alloys in a metal dusting environment. Finally, Alloy 800 tubes ...
2006-04-24
Energy Technology Data Exchange (ETDEWEB)
In the third quarterly report adsorption of heavy metals ions such as Cu(II) and Cr(VI) onto soils drawn from the laboratory-type wetland was shown to be weak. Secondly, it was shown that modified-clays did adsorb Cr(VI) ions strongly at pH 4.5. Further, studies on the pH dependence of the adsorption of {beta}-naphthoic acid, (NA), a well-documented contaminant in many oil and gas well waste waters onto modified-clays were undertaken and it was shown that uptake of NA by modified-clays was of the high affinity type at pH 4.5 and 7.0, but weak at pH 9.0. Adsorption of heavy metal ions, Cu{sup 2+}, and Cr(VI) onto algae, a proposed wetland amendment, was carried out and the results were presented and discussed in the fourth quarterly report. Uptake of NA by the soil component of the laboratory-type wetland was monitored as a function of pH. This quarterly report presents results from studies on the uptake of phenol and {beta}-naphthoic acid by laboratory-type ...
1993-10-04
The objective of the study was the kinetic modeling of the effect of storage temperature on the quality and shelf life of chilled fish, modified atmosphere-packed (MAP), and osmotically pretreated with the addition of nisin as antimicrobial agent. Fresh gilthead seabream (Sparus aurata) fillets were osmotically treated with 50% high dextrose equivalent maltodextrin (DE 47) plus 5% NaCl. Water loss, solid gain, salt content, and water activity were monitored throughout treatment and treatment conditions were selected for the shelf life study. Untreated and osmotically pretreated slices with and without nisin (2 x 10(4) IU/100 g osmotic solution), packed in air or modified atmosphere (50% CO(2)-50% air), and stored at controlled isothermal conditions (0, 5, 10, and 15 degrees C) were studied. Quality assessment and modeling were based on growth of several microbial indices, total volatile nitrogen, trimethylamine nitrogen, ...
2010-05-01
Fundamental studies of coal liquefaction
Energy Technology Data Exchange (ETDEWEB)
The authors have examined the pyrolysis of Argonne samples of Wyodak and Illinois No. 6 coal in argon, undecane, Tetralin, and water. The effects of the pyrolysis on individual particles of coal were monitored visually in a cell with diamond windows capable of operation to temperature and pressures in excess of 500{degrees}C and 3000 psi. The changes in the particles from ambient to 460{degrees}C were recorded in real time on video tape, and images were then taken from the tape record and analyzed. The study showed that in argon both coals developed tars at 350{degrees}-370{degrees}C. The tars then quickly evaporated, leaving core particles remarkably similar in size and shape to the initial particles. These observations suggest that coal does not melt nor become fully liquid when heated. Nor does the softened coal undergo crosslinking to generate coke. Rather the simple loss of volatiles leaves behind the core residue as coke. Contrary to the ...
1995-01-01
Spectrophotometric determination of aluminium ion in drinking water by flow infection analysis
International Nuclear Information System (INIS)
Optimum analytical conditions of the aluminium ion were established by flow injection analysis. Eriochrome Cyanine R(ECR) dye reacts with the aluminium ion at pH 6.0 form a complex that exhibits maximum absorption at 535 nm. Reaction condition including the mixing and the reaction coil length, the concentration and the pH of the buffer solution, temperature, and injection loop volume were optimized to introduce this reaction into flow injection analysis. The results were as follows. A mixing coil length of 0.5 m and a reaction coil length of 4.0 m, the pH 6.0 and 1M of acetate buffer solution, the ECR concentration of 0.56 mM, the reaction temperature of 40 .deg. C, the injection loop volume of 300 #mu#L were chosen as optimum conditions. Under these conditions the detection limit of the aluminium ion was less than 0.05 mg/L and the repeatability was better than 1%. A sampling frequency of 24 times for an hour was achieved. Interfering ions such as F"-, HPO_4"2"-, ...
2000-10-01
Energy Technology Data Exchange (ETDEWEB)
This paper studies the analytical application of europium (III)-morin complex which is formed in alkaline medium and has an intense color. The extent of europium extraction was determined by adding to the extract a morin solution in isoamyl alcohol in a 50-100-fold excess with respect to europium. The dependence of the optical density of the extracts on the ph in the system europium (III)-morin-water-organic solvent for different excesses of the reagent is shown: this indicates formation of two extractable complexes, one being dominant in the pH range 4-7, the other at pH greater than or equal to 8.5. The extraction of the europium (III)-morin complex from alkaline solution is used for direct extraction-photometric determination of europium(III) in compounds of elements having amphoteric properties or forming amines (Zns, Mo0/sub 3/).
1985-09-01
One-electron reduction of chloroperoxidase by radiolytically generated electrons
Energy Technology Data Exchange (ETDEWEB)
Upon irradiation of aqueous ethylene glycol/water solutions of native chloroperoxidase (CPO) with {sup 60}Co-gamma rays at 77K one observes the one-electron reduction of the enzyme active site by radiolytically generated thermolyzed electrons. In the present study the first absorption spectrum of a low-spin ferrous form of CPO is reported which has peaks at 438, 532 and 563 nm, similar to those observed previously for cytochrome P-450. All previously described ferrous forms of CPO are high spin. In order to observe the final results of the CPO reaction with electrons, the spectral changes of native enzyme after room temperature-gamma-irradiation have also been investigated. Evidence of changes is also presented probably connected with disruption of the tertiary structure of enzyme, correlated with decrease of enzyme activity.
1990-05-16
One-electron reduction of chloroperoxidase by radiolytically generated electrons
International Nuclear Information System (INIS)
Upon irradiation of aqueous ethylene glycol/water solutions of native chloroperoxidase (CPO) with "6"0Co-gamma rays at 77K one observes the one-electron reduction of the enzyme active site by radiolytically generated thermolyzed electrons. In the present study the first absorption spectrum of a low-spin ferrous form of CPO is reported which has peaks at 438, 532 and 563 nm, similar to those observed previously for cytochrome P-450. All previously described ferrous forms of CPO are high spin. In order to observe the final results of the CPO reaction with electrons, the spectral changes of native enzyme after room temperature-gamma-irradiation have also been investigated. Evidence of changes is also presented probably connected with disruption of the tertiary structure of enzyme, correlated with decrease of enzyme activity.
1990-05-01
Investigation and analytical use of rare earth ionic associates with benzilic acid and rhodamine B
International Nuclear Information System (INIS)
Ions of rare earth elements (r.e.e.) have been found to form with benzilic acid and rhodamine B precipitates hardly soluble in water and extractable by toluene. The conditions of La and Pr determination by extraction-spectrophotometry method are studied. Relative square deviation does not exceed 0.027 and 0.034 respectively. The method can be used for determination of other cerium sub-group r.e.e. in their salts and cannot be employed for determination of lighter r.e.e. in the presence of heavier r.e.e., because the latter form low soluble precipitates capturing the r.e.e. situated in the beginninq of the r.e.e. series.
1977-01-01
Interactions of SO{sub x} and NO{sub x} with soot
Energy Technology Data Exchange (ETDEWEB)
Studies of the adsorption of oxides of sulfur and nitrogen, and their coadsorption, on black carbon in the form of n-hexane soot have been carried out by microgravimetry, EPR and FTIR spectroscopy over a wide range of experimental conditions. The mechanisms of adsorption of O{sub 2} and NO{sub 2} are entirely different, as reflected by adsorption isotherms, the behavior of carbon`s unpaired electrons, the spectral features of surface species formed, mass changes during adsorption-desorption cycles, and an essential lack of competition for surface sites. Significant effects of temperature, water, SO{sub 2} and NO{sub 2} concentration, O{sub 2}, simulated solar radiation, and the presence of trace metals, have been observed and interpreted.
1996-10-01
British Library Electronic Table of Contents (United Kingdom)
The dynamics of planktonic cyanobacteria in eutrophicated freshwaters play an important role in formation of annual summer blooms, yet overwintering mechanisms of these water bloom forming cyanobacteria remain unknown. The responses to darkness and low temperature of three strains (unicellular Microcystis aeruginosa FACHB-905, colonial M.?aeruginosa FACHB-938, and a green alga Scenedesmus quadricauda FACHB-45) were investigated in the present study. After a 30-day incubation under darkness and low temperature, cell morphology, cell numbers, chlorophyll a, photosynthetic activity (ETRmax and I k), and malodialdehyde (MDA) content exhibited significant changes in Scenedesmus. In contrast, Microcystis aeruginosa cells did not change markedly in morphology, chlorophyll a, photosynthetic activi...
2008-01-01
Development of a pelleted waste form for high-level alumina wastes
Energy Technology Data Exchange (ETDEWEB)
A formulation to pelletize simulated high-level ICPP alumina waste calcine was developed. The pellets are formed on a 41-cm-diameter disc pelletizer using 5% bentonite, 2% metakaolin, and 5 wt % calcium hydroxide as a solid binder and a solution of 7M phosphoric acid and 4M nitric acid as a liquid binder. After drying and heat treatment at 800/sup 0/C for 2 hours, the average crush strength of the pellets is 3.9 MPa and the pellets have a leach resistance of 10/sup -3/ g/cm/sup 2//day, based on Soxhlet leaching for 48 h at 95/sup 0/C with distilled water.
1980-09-01
Burning ice. Methane hydrate on the sea floor; Brennendes Eis. Methanhydrat am Meeresgrund
Energy Technology Data Exchange (ETDEWEB)
In certain regions of the sea floor, water and methane from organic depositions have turned into a burnable form of ice, i.e. methane hydrates which contain more stored energy than all fossil fuel reserves. If they should desintegrate as a result of global heating, methane will be released and will contribute to further global heating. [Deutsch] Im Boden bestimmter Meeresregionen haben sich Wasser und Methan aus organischen Ablagerungen zu einer brennbaren Form von Eis vereinigt. Diese Methanhydrate speichern mehr Energie als alle fossilen Brennstoffvorraete. Wenn sie sich bei einer globalen Erwaermung zersetzen, koennte das entweichende Methan als Treibhausgas die Erde noch mehr aufheizen. (orig.)
1999-06-01
A compensating method of an imaging plate response to clinical proton beams
Energy Technology Data Exchange (ETDEWEB)
For charged particle irradiations, the response of an imaging plate (IP) changes around the Bragg peak. Therefore, an appropriate compensation is necessary for the evaluation of dose distribution formed by charged particles such as protons. In this paper, the response of IPs to clinical proton beams is investigated. An experimentally-obtained depth-dose distribution (an ordinary Bragg curve) by a silicon semiconductor detector (SSD) is employed to evaluate the compensation factors as a function of proton penetrating depth, i.e. residual range. A typical dose distribution in a water phantom formed by an L-shaped bolus is measured by IPs and corrected by using the information of those compensation factors; the residual proton range is successfully calculated by the pencil beam algorithm at an arbitrary point. The results show a good agreement with the measurements by the SSD within the rms error of 3.0%.
2002-04-01
International Nuclear Information System (INIS)
Tarapur Atomic Power Station unit-4 is first 540 MWe pressurized heavy water reactor. Heavy water is used as the coolant and moderator. With reactor operation tritium is formed by absorption of neutron by Deuterium atoms. Experience in the 220 MWe indicates that tritium is main contributor to the internal dose of radiation workers. Study on Tritium build up in Primary Heat Transport (PHT) and Moderator (MOD) system was carried out at the initial stage of the operation of the unit-3 and 4. This paper brings out tritium activity buildup in the PHT and MOD systems and its comparison with 220 MWe reactors. This paper helps in estimation of the internal dose contribution to the radiation workers at TAPS 3 and 4. (author)
2006-11-13
International Nuclear Information System (INIS)
Tarapur Atomic Power Station unit-4 is first 540 MWe pressurized heavy water reactor. Heavy water is used as the coolant and moderator. With reactor operation tritium is formed by absorption of neutron by deuterium atoms. Experience in the 220 MWe indicates that tritium is main contributor to the internal dose of radiation workers. Study on tritium build up in Primary Heat Transport (PHT) and Moderator (MOD) system was carried out at the initial stage of the operation of the unit-4. This paper brings out tritium activity buildup in the PHT and MOD systems and its comparison with 220 MWe reactors. This paper helps in estimation of the internal dose contribution to the radiation workers at TAPS 3 and 4. (author)
2005-11-23
Study of Zircaloy-2 corrosion in high temperature water using ion beam methods
Energy Technology Data Exchange (ETDEWEB)
Experiments have been carried out in water at 355 C to study transport of oxygen and hydrogen (as deuterium) in growing corrosion films. Composition of the films was also examined in 2.9 Mev and 3.9 Mev /alpha/-particle backscattering experiments. Corrosion occurs predominantly by oxygen diffusion through the film via grain boundary or similar short circuit diffusion paths, to form fresh oxide at the oxide metal interface. Increasing grain size within thick pre-breakaway films contributes to a decrease in diffusivity. The rate transition results from the generation of new diffusion pathways in previously protective oxide. Unexpectedly high concentrations of deuterium were observed. 26 refs.
1981-10-01
British Library Electronic Table of Contents (United Kingdom)
Humic acids are considered problematically in drinking water because it can react readily with chlorine to form carcinogen compounds and its biological removal is much recommended. The scanning electron microscopy morphologies and optical parameters observed for natural humic acids (NHAs) extracted from different soils at Mitidja plain (Algeria) made them different from the commercial ones. Three of the most active strains of 19 actinomycetes were isolated and selected from surface soils at this plain. These strains were identified based on cultural characteristics and chemotaxonomic analysis and classified in the genus Streptomyces. Growth of these strains was assured on a poor liquid medium containing NHAs as carbon and nitrogen sources and degradation occur only in the presence of gluco...
2010-01-01
Recriticality of a BWR core during reflood after control blade meltdown
Energy Technology Data Exchange (ETDEWEB)
In nuclear reactor safety research, the question of the possible consequences of delayed core reflood during severe accidents or anticipated transient without scram transients in boiling water reactors (BWRs) has been raised. One can envisage a very low probability accident scenario leading to core uncovery and core heat-up, followed by control blade melting and subsequential delayed reflooding of the core with unborated water before its degradation. Reflooding of the hot core causes significant increases in the peak heating, melting, and hydrogen production rates, thus increasing the probability of core degradation. However, as has been established, debris beds formed from shattered fuel rods and quenched fuel melt will be undermoderated. The reflood process of a voided, intact core was examined using the TRAC/BFI CODE.
1994-12-31
Energy Technology Data Exchange (ETDEWEB)
The behavior of Am, Cm, Bk, Cf, Es, and other actinides, as well as Zr, on anion and cation exchangers in aqueous and water-ethanol solutions of sulfuric acid as a function of the various components of the solution has been investigated. It has been discovered that the presence of ethanol in sulfuric acid solutions causes an increase in the distribution coefficients both on cation exchangers and on anion exchangers. The possibility of the use of ion exchangers for the preconcentration and separation of transplutonium elements from U, Np, Pu, Zr, and other elements which form strong complexes with sulfate ions over a broad range of concentrations of sulfuric acid has been demonstrated.
1988-05-01
Production of tetrazolium salts under conditions of phase-transfer catalysis
Energy Technology Data Exchange (ETDEWEB)
Recently the authors showed that tetrazolium salts can be obtained during the oxidation of substituted 1,3,5-triarylformazans with potassium permanganate in a two-phase organic solvent-water system. The role of phase-transfer catalyst in this reaction is played by the tetrazolium salt, which is formed in a small amount as the result of oxidation of the formazan at the phase boundary. The method is distinguished by its extreme simplicity. However, the yield of the tetrazolium salts fluctuates within wide limits and does not exceed 62%. This is due to the fact that as the reaction proceeds the pH of the aqueous phase increases from 6 to 12. At the same time it is known that tetrazolium salts are unstable in aqueous alkaline solutions. They found that if the aqueous phase is replaced by aqueous hydrochloric acid (5 wt. %) the yields of the tetrazolium salts (Ia-g) are increased to 70-87%. For convenience of isolation the readily ...
1988-06-20
Energy Technology Data Exchange (ETDEWEB)
This is a process for producing calcium sulfate dihydrate during desulfurization of stack gases from power station boilers, where the stack gases are introduced into a washing tower and are treated with a washing water suspension containing lime in the washing tower, where oxygen in the form of air or of air enriched in oxygen is also blown into the washing tower, and where the washing water suspension drawn off from the washing tower is fed back to the washing tower at a temperature of 45 to 50/sup 0/C in the circuit and at least part of the flow goes via a thickener and where calcium sulfate dihydrate slurry is drawn off from the thickener.
1986-06-12
Nuclear techniques for measuring moisture content in soil profiles
International Nuclear Information System (INIS)
The prevailing severe shortage of animal feed in most of the developing countries could, to a considerable extent, be overcome through improved range management, which includes introduction of high yielding drought-resistant forage crops, development of adequate water conservation measures, and as far as possible growing annual forage crops on part of the vast areas of arable land currently left fallow each year. Year round measurements are essential for a good understanding of soil water and nutrients dynamics, which allow for adequate evaluation of pasture management alternatives. The methods most commonly used for moisture measurements in soil profiles are discussed because such measurements are likely to form an essential part of any investigation aimed at increasing animal feed production through the development of adequate pasture management practices. (author).
Modeling of snow melting and uniform wetting front migration in a layered subfreezing snowpack
Energy Technology Data Exchange (ETDEWEB)
A method of modeling freeze-thaw cycles of naturally deposited snowpacks is presented. The model involves the Stefan condition as an independent governing equation on the exterior moving boundary to calculate snowpack thinning, flow of water through a variably saturated layered porous medium as described by the Richards equation, and heat conduction with a phase change. The heat conduction problem was treated in two ways. Local heat conduction between a snow grain and its surrounding water film was treated by using a simple energy balance. Global heat conduction with a phase change (the Stefan problem) was introduced to calculate the space-time temperature distribution. In order to handle multiple interior moving boundaries, a specific form of the enthalpy formulation was used for heat conduction with a phase change. Changing material properties were considered according to the calculated meltwater refreezing. 48 refs., 11 ...
1994-08-01
Method of reducing volume of radioactive liquid waste
International Nuclear Information System (INIS)
Purpose: To enable the solidification of liquid waste containing radioactive substance in a free shape with large volume reduction ratio without a pulverizing step by producing solute in the liquid waste as a slurry in a predetermined organic solvent and forming it into a cake by mechanical exfoliation. Method: Liquid waste containing suitably concentrated radioactive substances is supplied to a centrifugal thin film evaporator together with an organic agent having a higher boiling point than water and a non aqueous solution to evaporate the water content, the solute in the waste is produced as a slurry in the organic solvent, and removed as cake-state solute slightly residued with the organic solvent by the mechanical exfoliation such as centrifugal exfoliation or settling exfoliation from the slurry-state liquid. Accordingly, it can be increased in size as compared with the powder reduced in volume of the radioactive ...
1981-08-01
Enhancement of convective heat transfer by using microencapsulated PCM slurry
Energy Technology Data Exchange (ETDEWEB)
As a method to make use of a high latent heat of a liquid-solid phase change material in a confined convective heat transfer, a phase change material, lauric acid, was encapsulated in a tiny hollow sphere, and mixed with water, forming a slurry of microencapsulated phase-change material (MCPCM slurry). Four different sizes (200, 100, 50, and 25 {mu}m ID) of MCPCMs were tested in this study. Thermal characteristics of the pure lauric acid and lauric acid MCPCMs were tested by a differential scanning calorimeter. Viscosity of the slurries of water and the capsules was measured by a rotating viscometer. The slurries were also tested in a convective-heat-transfer-test apparatus. (author). 11 refs., 5 figs., 1 tab.
1998-11-01
Energy Technology Data Exchange (ETDEWEB)
This final report for the Swiss Federal Office of Energy (SFOE) examines a project that aimed to define standard solutions for use in buildings built to meet Minergie low energy consumption standards. These standard solutions are to provide a way of meeting Minergie standards in an easy way and thus further the use of the standard and also assure quality at the same time. The report describes how the solutions were developed on the basis of a selection of existing Minergie buildings. For various combinations of heating systems - wood, wood/solar, heat pumps (brine-water and air-water), gas/solar and oil/solar - the appropriate U-values for various building elements are listed. The resulting Minergie forms and guides are listed.
2003-07-01
Basement of the South China Sea Area: Tracing the Tethyan Realm
British Library Electronic Table of Contents (United Kingdom)
Abstract: The basement of the South China Sea (SCS) and adjacent areas can be divided into six divisions (regions) - Paleozoic Erathem graben-faulted basement division in Beibu Gulf, Paleozoic Erathem strike-slip pull-apart in Yinggehai waters, Paleozoic Erathem faulted-depression in eastern Hainan, Paleozoic Erathem rifted in northern Xisha (Paracel), Paleozoic Erathem strike-slip extending in southern Xisha, and Paleozoic-Mesozoic Erathem extending in Nansha Islands (Spratly) waters. The Pre-Cenozoic basement in the SCS and Yunkai continental area are coeval within the Tethyan tectonic domain in the Pre-Cenozoic Period. They are formed on the background of the Paleo-Tethyan tectonic domain, and are important components of the Eastern Tethyan multi-island-ocean system. Three branches of t...
2011-01-01
Atmospheric chemistry on Venus, Earth, and Mars: Main features and comparison
British Library Electronic Table of Contents (United Kingdom)
This paper deals with two common problems and then considers major aspects of chemistry in the atmospheres of Mars and Venus. (1) The atmospheres of the terrestrial planets have similar origins but different evolutionary pathways because of the different masses and distances to the Sun. Venus lost its water by hydrodynamic escape, Earth lost CO"2 that formed carbonates and is strongly affected by life, Mars lost water in the reaction with iron and then most of the atmosphere by the intense meteorite impacts. (2) In spite of the higher solar radiation on Venus, its thermospheric temperatures are similar to those on Mars because of the greater gravity acceleration and the higher production of O by photolysis of CO"2. O stimulates cooling by the emission at 15@mm in the collisions with CO"2. ...
2011-01-01
British Library Electronic Table of Contents (United Kingdom)
Coal mining activities cause an increased acidity and an associated decrease of the pH-value in mine waters. This process is also known as acid mine drainage (AMD). Due to AMD, lakes that were formed in the post mining landscapes in the lignite mining area of Central Germany are characterized by specific limnological development changes. Remote sensing is a time and cost saving technique that enables the observation of the hydrological and limnological development of the lakes ranging from a small to a mid size scale. The current research was based on Landsat TM5/ETM+7 satellite data collected between 1999 and 2004. In combination of satellite data, surface waters of the post mining lakes in Central Germany were sampled and analyzed for their physicochemical properties. The objective of th...
2011-01-01
A ZnO nanowire array film with stable highly water-repellent properties
Energy Technology Data Exchange (ETDEWEB)
Highly water-repellent surfaces have been prepared from arrayed nanowires of zinc oxide (ZnO) by a treatment with stearic acid. The layers are electrochemically deposited on a nanocrystalline seed layer from an oxygenated aqueous zinc chloride solution. An advancing contact angle (CA) as high as 176{sup 0} is obtained with a very small hysteresis {approx}1{sup 0}. These results, supplemented by infrared spectroscopy, show that the stearic acid forms a very well-packed self-assembled monolayer. The CA measurements show a very good stability of the treated surface even when exposed to harsh conditions or long-term ambient illumination.
2007-09-12
Optimization of amide-based inhibitors of soluble epoxide hydrolase with improved water solubility.
Soluble epoxide hydrolase (sEH) plays an important role in the metabolism of endogenous chemical mediators involved in the regulation of blood pressure and inflammation. 1,3-Disubstituted ureas with a polar group located on the fifth atom from the carbonyl group of urea function are active inhibitors of sEH both in vitro and in vivo. However, their limited solubility in water and relatively high melting point lead to difficulties in formulating the compounds and poor in vivo efficacy. To improve these physical properties, the effect of structural modification of the urea pharmacophore on the inhibition potencies, water solubilities, octanol/water partition coefficients (log P), and melting points of a series of compounds was evaluated. For murine sEH, no loss of inhibition potency was observed when the urea pharmacophore was modified to an amide function, while for human sEH 2.5-fold decreased ...
2005-05-19
International Nuclear Information System (INIS)
In summary, a scaling analysis of a water-cooled Reactor Cavity Cooling System (RCCS) system was performed based on generic information on the RCCS design of PBMR. The analysis demonstrates that the water-cooled RCCS can be simulated at the ANL NSTF facility at a prototypic scale in the lateral direction and about half scale in the vertical direction. Because, by necessity, the scaling is based on a number of approximations, and because no analytical information is available on the performance of a reference water-cooled RCCS, the scaling analysis presented here needs to be 'validated' by analysis of the steady state and transient performance of a reference water-cooled RCCS design. The analysis of the RCCS performance by CFD and system codes presents a number of challenges including: strong 3-D effects in the cavity and the RCCS tubes; simulation of turbulence in flows characterized by natural ...
Thermal stress cracking and the enhancement of heat extraction from fractured geothermal reservoirs
Given sufficient time, the extraction of heat from geothermal reservoirs formed by the hydraulic fracturing of competent rock will eventually result in the formation of thermal stress cracks in the reservoir. These cracks penetrate the rock in a manner such that the penetration-to-spacing ratio is approximately one. The penetration depends upon the extent of cooling and the square root of time. Initially then, the cracks are closely spaced and penetrate but little, so that a crazing pattern is apparent; but with increasing time some of these cracks, now more widely spaced, grow deeper. Eventually these larger cracks attain a critical aperture such that significant rates of water flow can be established within them and thus the newly created heat transfer area becomes useful for heat extraction. At the same time that cracks are forming within the main reservoir, thermal cracking also occurs in the wellbores that communicate ...
1978-04-01
Under the auspices of the DOE and private industry, considerable progress has been made in: preparation of coal-water fuels; combustion of low-ash coal-based fuel forms; processes to provide deeply-cleaned coal. Developments in advanced beneficiation of coal to meet stringent requirements for low ash and low sulfur can be anticipated to further complicate the problem areas associated with this product. This is attributable to the beneficiated coal being procured in very fine particles with high surface areas, modified surface characteristics, reduced particle size distribution range, and high inherent moisture. Experience in the storage, handling, and transport of highly beneficiated coal has been limited. This is understandable, as quantities of such product are only now becoming available in meaningful quantities. During this reporting period the authors have: developed a suite of empirical tests covering water retention, ...
1993-01-01
Energy Technology Data Exchange (ETDEWEB)
The present paper explains the curve-fitting method developed as a method to estimate the geothermal equilibrium forming temperature. In the present method, that temperature is estimated by obtaining, by non-linear lest square, the model parameter to minimize the sum of remainders squared between the temperature actually measured after a lapse of certain time from the stoppage of mud water circulation and that calculated on the basis of Middleton model, mathematical model of temperature equilibrium well. In the Horner's plotting method currently in general use, temperature recovery data during a long period of about 120h are required for estimating the geothermal equilibrium forming temperature. However in the curve-fitting method, it is confirmed from the actual well data that the well recovery temperature is estimable from three logging data during 24h after the stoppage of mud water ...
1994-05-01
British Library Electronic Table of Contents (United Kingdom)
A convolution/superposition method is proposed for use with primary and scatter dose kernels formed for energy bins of X-ray spectra reconstructed as a function of off-axis distance. It should be noted that the number of energy bins is usually about ten, and that the reconstructed X-ray spectra can reasonably be applied to media with a wide range of effective Z numbers, ranging from water to lead. The study was carried out for 10-MV X-ray doses in water and thorax-like phantoms with the use of open-jaw-collimated fields. The dose calculations were made separately for primary, scatter, and electron contamination dose components, for which we used two extended radiation sources: one was on the X-ray target and the other on the flattening filter. To calculate the in-air beam intensities at po...
2011-01-01
Water Quality and 401 Certification | Clean Water Act | US EPA
Clean Water Act You are here: Water Laws & Regulations Policy & Guidance Clean Water Act Water Quality and 401 Certification Water Quality and 401 Certification Water Quality...
2011-08-28
Loss of Function of E-Cadherin in Embryonic Stem Cells and the Relevance to Models of Tumorigenesis
UK PubMed Central (United Kingdom)
E-cadherin is the primary cell adhesion molecule within the epithelium, and loss of this protein is associated with a more aggressive tumour phenotype and poorer patient prognosis in many cancers. Loss...Full Text Available
2011-01-01
A Profile of Defense Manufacturing Costs and Enabling ...
... Casting Explosive forming Forging Electrohydraulic forming Extruding Magnetic forming Rolling Electroforming Drawing Powdered metal forming ...
1992-01-01
Energy Technology Data Exchange (ETDEWEB)
The reactions of native bovine catalase with superoxide and solvated electrons have been investigated using three different methods for generating these reducing substrates: [gamma]-radiolysis of oxygenated or deaerated buffer solutions in the presence of an OH radical scavenger; either xanthine or acetaldehyde with xanthine oxidase; and low-temperature (77 K) [gamma]-radiolysis of buffered ethylene glycol/water solutions with subsequent annealing of samples at 183 K. (Author).
1992-11-01
...Publications Consultations Application forms Vacancies Contact us About us Air Climate change Flooding Live flood warnings Flood map How to use it About the ...map View the map FAQs Contact us & Feedback Flooding: who does what? Flood warning - what we do Floodline Warnings Direct Flood ...risk Being prepared FAQs Floodline kids Flooding publications External links Business & Flood Risk Seminar Contact us Land Planning Radioactive substances Waste Water ... You are here: Home Page Flooding Flood map View the map View the map: terms and conditions Important information about ...
Micellar slug for oil recovery
Energy Technology Data Exchange (ETDEWEB)
A micellar slug for use in the recovery of oil is described, the slug containing a hydrocarbon, an aqueous medium, a surfactant, and a cosurfactant. The surfactant contains as an essential component an alpha-olefin sulfonate having 10 to 26 carbon atoms and containing 0.1% to 15% by weight by weight of a disulfonate. This micellar slug has an excellent salinity tolerance and hard-water resistance. Furthermore, the micellar slugs of the present invention are capable of forming micro-emulsions having a sufficiently low interfacial tension and, therefore, can improve oil recovery efficiency.
1985-08-27
Environmental Research Database
ObjectivesNot EnteredDescriptionMethane hydrate in an ice-like substance consisting of molecules of methane gas combined chemically with water. It is stable at high pressures and low temperatures. Since the ocean floor is normally cold, but temperatures increase with depth inside the Earth, such conditions normally prevail for a few hundred meters below the seafloor where the ocean depth is more than a few hundred metres. Methane beneath the ocean floor is formed by the decomposition of organic material. At the edges of the co [continued...
2006-01-30
Modelling transport of water and solutes in future wetlands in Forsmark
Energy Technology Data Exchange (ETDEWEB)
The Forsmark area consists of a number of natural wetlands. As a part of the evaluation of wetlands in the safety assessment for the area, possible future wetlands are being studied with respect to hydrology and transport mechanisms. A sensitivity analyses is performed to point out the governing parameters for the wetland hydraulics. The analysis of future wetlands is carried out using the hydrological model system Mike SHE. Mike SHE has been used to describe the near-surface hydrology for a regional model area in Forsmark. Three types of areas have been chosen. Today's lake Bolundfjaerden is because of its shallow depth likely to develop into a mire in the future. As it is situated in the downstream part of the regional model area, the runoff to the lake from upstream surface water system is significant. Lake Eckarfjaerden is situated in the upstream part of the catchment at a higher altitude and with a smaller inflow. Lake Puttan is situated above a ...
2006-03-15
Convection heat loss from a cavity receiver
Energy Technology Data Exchange (ETDEWEB)
The receiver whose convective heat loss test results are presented was designed to absorb 5 MW of solar energy, using a molten salt working fluid. During the tests, this receiver was brought to a temperature of about 343 C by a small group of heliostats. Total receiver heat loss due to emitted radiation, conduction and convection was first determined, and the convection loss was established by calculating the radiation and conduction losses analytically and subtracting their sum from the total. Losses due to convection are found to be 1.43 percent of the total heat input.
1984-02-01
The Tropical East Pacific as a Laboratory for Tropical Cyclones
The summertime tropical cyclogenesis rate per unit area in the eastern Pacific ocean is arguably higher than in any other location in the world. Many if not most of these cyclones form from African easterly waves which cross Central America into the Pacific. Of order 25% of these waves intensify into cyclones. A significant fraction of east Pacific tropical cyclones undergoes landfall on the Mexican coast. Those which do not, generally dissipate over cold ocean waters north of the east Pacific intertropical convergence zone, often not far from land. The layer of warm ocean water which supports the development of east Pacific cyclones is unusually shallow and is structured by anticyclonic vortices which form by various processes and propagate slowly to the west. These vortices locally deepen the oceanic mixed layer and support stronger convection than their surroundings, possibly promoting ...
2007-05-01
Electrochemical investigation of passive film formed on Alloy 600
Energy Technology Data Exchange (ETDEWEB)
Alloy 600 is used as a material for steam generator tubing in pressurized water reactors(PWR) due to its high corrosion resistance under PWR environment. In spite of its corrosion resistance, stress corrosion cracking(SCC) has occurred on the primary side as well as the secondary side of the tubing. Oxide on steel surfaces in aqueous solution above 100 .deg. C is composed of duplex film structure. Inner layer of the oxide is dense and less porous, which is formed by growth of oxide layer on metal surface. Outer layer of the oxide is loose adhesive, which is formed by dissolution precipitation mechanism. Growth processes occur at the metal/oxide and oxide/electrolyte interfaces and are controlled by transport of the layer forming species through the layer, i.e. by the inward diffusion of oxygen including electrolyte species and the outward diffusion of metal cations. Understanding of basic ...
2005-07-01
Energy Technology Data Exchange (ETDEWEB)
The core bypass phenomenon of borated water injected through direct vessel injection (DVI) nozzles in APR1400 (Advanced Power Reactor 1400MWe) during main steam line break (MSLB) accidents with a reactor coolant pump (RCP) running mode has been simulated using a two-channel and one-dimensional system analysis model code (MARS), and a three-dimensional computational fluid dynamics (CFD) code (FLUENT). A visualization experiment has also been performed using a scaled-down model of the APR1400. The MARS analysis has predicted a serious core bypass phenomenon of borated water, while the CFD analysis has shown results opposite to the MARS results. The CFD analysis has shown that the flow pattern in the downcomer is fully three-dimensional and that vortex flow structures are formed near the cold legs so that the borated water might pass without difficulty into the high flow region of the cold legs and flow ...
2007-04-15
Effect of wet-dry cycling on swelling and hydraulic conductivity of GCLs
Energy Technology Data Exchange (ETDEWEB)
Atterberg limits, free swell, and hydraulic conductivity tests were conducted to assess how wet-dry cycling affects the plasticity and swell of bentonite, and the hydraulic conductivity of geosynthetic clay liners (GCLs) hydrated with deionized (DI) water (pH 6.5), tap water (pH 6.8), and 0.0125-M CaCl{sub 2} solution (pH 6.2). The plasticity of bentonite hydrated with DI water increased during each wetting cycle, whereas the plasticity of bentonite hydrated with tap water and CaCl{sub 2} decreased during each wetting cycle. Wet-dry cycling in DI water and tap water had little effect on swelling of the bentonite, even after seven wet-dry cycles. However, swelling decreased dramatically after two wetting cycles with CaCl{sub 2} solution. Hydraulic conductivity of GCL specimens remained low during the first four wetting cycles ({approximately}1 x 10{sup {minus}9} ...
2000-01-01
International Nuclear Information System (INIS)
A typical form of change in runoff characteristics caused by the widespread use of hydroelectric power in Switzerland is the intermittent draining (torrent operation). It is the aim of the present work to help elucidate possible consequences of these changes in drain onto the benthobiocoenosis. The study was carried through on the Secklisbach at Oberrickenbach (in the semicanton of Nidwalden) and one of its side streamlets (800m above sea level). The macroinvertebrate coenosis was studied at four locations with similar conditions of drainage basin, population density and topography but varying in the degree of impairment to the draining. There were monthly benthos samples taken using a Surber sampling-device. Results show that the locations not only varied in drain, but also in temperature, this being a consequence of water storage by the power plant. The readings pointed out different values for the locations in daily average temperature, day ...
Hearing loss in children and adults
UK PubMed Central (United Kingdom)
ObjectiveThe purpose of this study was to characterize the sensorineural hearing losses of a group of children and adults along three parameters important to the...Full Text Available
2003-06-01
Handbook on Ground Forces Attrition in Modern Warfare
... 129 US Armored Division Casualty and Tank Loss Rates ..... 132 British Casualty and rank Loss Rates in Operation "Goodwood" . 134 Page 5. ...
1986-09-01
Chronic Pain Associated with Upper-Limb Loss
UK PubMed Central (United Kingdom)
ObjectiveTo describe the prevalence, intensity, and functional impact of the following types of pain associated with upper-limb loss: phantom limb, residual limb,...Full Text Available
2009-09-01
Analgesic Use and the Risk of Hearing Loss in Men
UK PubMed Central (United Kingdom)
BackgroundHearing loss is a common sensory disorder, yet prospective data on potentially modifiable risk factors are limited. Regularly used analgesics, the most...Full Text Available
2010-03-01
Redox reactions of Cu(II)-amine complexes in aqueous solutions
Energy Technology Data Exchange (ETDEWEB)
A number of amines can be employed for all volatile treatment (AVT) of steam generator (SG) systems of nuclear power reactors. These amines form complexes with Cu{sup 2+} and Ni{sup 2+} ions which come into water due to corrosion. The redox reactions of a number of Cu(II)-AVT amine complexes and the stability of the transient species formed have been studied by pulse radiolysis technique. Rate constants for the reaction of e{sub aq}{sup -} with a number of Cu(II)-amine complexes have been determined by following the decay of e{sub aq}{sup -} absorption. Stability of Cu(I)-amine complexes was studied by following the kinetics of the bleaching signal formed at the {lambda}{sub max} of the Cu(II) amine complex. Except for Cu(I)-triethanolamine complex all other Cu(I)-amine complexes were found to be stable. One-electron oxidation of Cu(II) amine complexes was studied using azidyl radicals for the oxidation ...
2003-03-01
Water transport in conifers occurs through single-celled tracheids that are connected to one another via intertracheid pit membranes. These membranes have two components: the porous margo, which allows water to pass through the membrane, and the impermeable torus, which functions to isolate gas-filled tracheids. During drought, tracheids can become air filled and thus hydraulically dysfunctional, a result of air entering through the pit membrane and nucleating cavitation in the water column. What are the hydraulic tradeoffs associated with cavitation resistance at the pit level, and how do they vary within the structural components of the intertracheid pit? To address these questions, we examined pit structure in 15 species of Cupressaceae exhibiting a broad range of cavitation resistances. Across species, cavitation resistance was most closely correlated to the ratio of the torus to pit aperture diameter but did not vary ...
2010-08-15
Structure of human insulin monomer in water/acetonitrile solution
Energy Technology Data Exchange (ETDEWEB)
Here we present evidence that in water/acetonitrile solvent detailed structural and dynamic information can be obtained for important proteins that are naturally present as oligomers under native conditions. An NMR-derived human insulin monomer structure in H{sub 2}O/CD{sub 3}CN, 65/35 vol%, pH 3.6 is presented and compared with the available X-ray structure of a monomer that forms part of a hexamer (Acta Crystallogr. 2003 Sec. D59, 474) and with NMR structures in water and organic cosolvent. Detailed analysis using PFGSE NMR, temperature-dependent NMR, dilution experiments and CSI proves that the structure is monomeric in the concentration and temperature ranges 0.1-3 mM and 10-30 deg. C, respectively. The presence of long-range interstrand NOEs, as found in the crystal structure of the monomer, provides the evidence for conservation of the tertiary structure. Starting from structures calculated by the program CYANA, two ...
2008-01-15
Energy Technology Data Exchange (ETDEWEB)
A new method for the preconcentration and determination of trace amounts of lead at the {mu}g/L level in natural waters has been established based on the formation of the thenoyltrifluoroacetone (TTA) complex with dibenzo-18-crown-6 (DB18C6) by means of synergistic extraction and back-extraction combined with atomic absorption spectrometry (AAS). The effect of various factors (synergism with TTA and DB18C6, shaking time, preconcentration factor, composition of the extracted species, and foreign ions etc.) on the extraction and back-extraction of lead has been investigated in detail. The lead-TTA chelate in o-dichlorobenzene forms a stable adduct with DB18C6 as Pb(TTA){sub 2} DB18C6. The stability constant ({beta}) of the adduct determined by curve fitting method was log {beta} = 4.2. The amount of lead in natural waters such as tap water (Kanazawa University) and Kakehashi river (Komatsu City) ...
1998-07-01
Nitrogen Requirements and Balance of Protected Cucumber in Coastal Lebanon
International Nuclear Information System (INIS)
Protected cultures are widespread along the Lebanese narrow coastline, encouraged by mild winter conditions. Although one of the most intensive production systems, water and nutrients managements are mostly empirical, based on the experience of the grower himself or of his workers. So far, water has been available in Lebanon, but it will become scarce within ten years. The conservation of water quality by a rational addition of nutrients is particularly relevant to protected cultures. This is important as greenhouses are developed on imported shallow soils that could be fragile and highly vulnerable to pollution. Sound management includes the amount and the forms of fertilizers as well as the modality of fertigation. An experiment was conducted during two spring seasons in a location along the northern coast in a typical unheated greenhouse. The cucumber response to two frequencies and modalities of ...
2003-10-01
Material and process improvements in condenser tubing
Energy Technology Data Exchange (ETDEWEB)
The reliability of the surface condenser is a key factor in plant performance level and maintenance cost optimization. This is especially the case for thermal nuclear plants where condenser raw wa-ter ingress can introduce contamination into the chemically-controlled, steam/water loop potentially causing damage to sensitive equipment. Two important parameters must be taken into account when attempting to optimize the quality and the reliability of condenser tubing. They include selecting the appropriate material according to the cooling water corrosion level present. A second and equally important parameter is the manufac-turing of the tubing product itself. This paper will identify methods to optimize manufacturing processes and improve tubing quality, according to VALTIMET's 30 years of condenser welded tubing production experience. Those methods complete the core manufacturing process ...
2010-07-01
Long-term corrosion study at nuclear power plant Bohunice (Slovakia)
International Nuclear Information System (INIS)
Steam generators of four VVER-440 units at nuclear power plants V-1 and V-2 in Jaslovske Bohunice (Slovakia) were gradually changed by new original 'Bohunice' design in period 1994-1998. Corrosion processes before and after these design and material changes in Bohunice secondary circuit were studied using Moessbauer spectroscopy during last 25 years. Innovations in the feed water pipeline design as well as material composition improvements were evaluated positively. Moessbauer spectroscopy studies of phase composition of corrosion products were performed on real specimens scrapped from water pipelines or in form of filter deposits. The corrosion of new feed water pipelines system (from austenitic steel) in combination to innovated operation regimes goes dominantly to magnetite. The hematite presence is mostly on the internal surface of steam generator body and its concentration increases towards the top ...
2010-03-01
Liquid zone system events at Wolsong Unit 2
International Nuclear Information System (INIS)
On June 19, 1998, after the first annual outage, Wolsung Unit 2 was shutdown at a controlled rate due to the continuous instability of Liquid Zone Control level. Investigation revealed that the Liquid Zone Control level instability was caused by water condensed inside the helium lines, generated from the moistened helium flow, especially, inside the helium balance header feed and bleed valve lines. It was found that improper installation of the diaphragm type isolation valves and the drain valve tap could easily contain the water inside the lines and be destined to form water traps causing the balance header pressure oscillation. After the lines were dried, Liquid Zone Control level instability was almost vanished, and approached the allowable equilibrium state. As the reactor power was increased, however, the zone level instability increased again. In order to compensate for the excessive, the Bulk ...
1998-09-07
Energy Technology Data Exchange (ETDEWEB)
This paper elucidates morphological characteristics, reproduction forms and ecological characteristics of Plectus sp. and Rhabditis sp. which are most frequently detected nematodes separated from tap water. The paper also discussed experimentally establishment of cultivating conditions for these nematodes, and behavior and reproduction characteristics of nematodes under widely ranging conditions of temperatures, bacteria concentrations and pH. Plectus sp. grows in hermaphroditic individuals, while Rhabditis sp. grows only in female. An LE culture medium can cultivate nematodes that appear in tap water, and is suitable for subculture of nematodes. Conditions of temperatures from 20{degree}C to 25{degree}C, pH and inoculated concentration of bacteria at 10{sup 8} cell {center_dot} ml{sup -1} are suitable for reproduction of Plectus sp. and Rhabditis sp. Plectus sp. and Rhabditis sp. prefer mild temperatures for reproduction, ...
1996-08-10
Experimental investigation on the fretting wear of alloy 800 in room remperature water
Energy Technology Data Exchange (ETDEWEB)
Fretting wear test in room temperature water was performed to evaluate the wear coefficient of CANDU (CANadian Deuterium Uranium) steam generator (SG) tube material (Alloy 800) against 410 type martensitic stainless steels. The main focus is to compare the wear behaviors between Alloy 800 and Inconel 690. Test conditions are 10{approx}30N of normal load, 200{approx}450mm of sliding amplitude and 30Hz of frequency. The result indicated that the wear rate of Alloy 800 was higher than those of Inconel 690 at various test condition such as normal loads, sliding amplitudes etc. From the results of SEM observation, there was little evidence of plastic deformation layer that were dominantly formed on the worn surfaces of Inconel 690. Also, wear particles in Alloy 800 were released from contacting asperities deformed by severe plastic flow during fretting wear. Main cause of wear rate between Alloy 800 and Inconel 690 may be due to the difference of ...
2002-05-01
Experimental investigation on the fretting wear of alloy 800 in room remperature water
International Nuclear Information System (INIS)
Fretting wear test in room temperature water was performed to evaluate the wear coefficient of CANDU (CANadian Deuterium Uranium) steam generator (SG) tube material (Alloy 800) against 410 type martensitic stainless steels. The main focus is to compare the wear behaviors between Alloy 800 and Inconel 690. Test conditions are 10#approx#30N of normal load, 200#approx#450mm of sliding amplitude and 30Hz of frequency. The result indicated that the wear rate of Alloy 800 was higher than those of Inconel 690 at various test condition such as normal loads, sliding amplitudes etc. From the results of SEM observation, there was little evidence of plastic deformation layer that were dominantly formed on the worn surfaces of Inconel 690. Also, wear particles in Alloy 800 were released from contacting asperities deformed by severe plastic flow during fretting wear. Main cause of wear rate between Alloy 800 and Inconel 690 may be due to the difference of ...
2002-05-01
Energy Technology Data Exchange (ETDEWEB)
An Allis-Chalmers, Model 2900, turbocharged diesel engine was converted to a dual-fuel engine in which ethyl alcohol was fumigated between the turbocharger and the intake manifold, and the diesel fuel was injected normally at a reduced rate. Tests were performed to determine if crankcase oil dilution that had occurred was caused by the following independent parameters: proof of the ethyl alcohol, crankcase oil temperature, engine load at maximum torque speed, and percentage of total energy in the form of ethyl alcohol. Engine tests were steady state for six hours, after which the crankcase oil was sampled for American Society for Testing and Materials (ASTM) laboratory tests for determination of flash points and fire points, water by centrifuge, water by distillation, and viscosity at room temperature. Results indicate a decrease in thermal efficiency and an increase in exhaust carbon monoxide as the percentage of total ...
1982-11-01
Slow strain-rate testing of Alloy 800 in molten-nitrate salts
Energy Technology Data Exchange (ETDEWEB)
An experimental technique has been developed to examine the interaction between deformation and the exposure of certain high temperature structural alloys to oxidizing molten salt environments. The experimental program involved performing a series of long-term tensile tests over a wide range of strain rates. Fracture strain reduction in area and ultimate strength (UTS) were monitored as parameters indicative of an alloy's susceptibility to environmental degradation. For Incoloy Alloy 800 tested at 600/sup 0/C in the salt medium and at initial strain rates between 2 x 10/sup -7/ sec/sup -1/ and 1 x 10/sup -5/ sec/sup -/1 no appreciable loss of ductility, as measured by reduction in area, was observed relative to control specimens tested in air at the same temperature and strain rates. Similarly, fracture strain and UTS were essentially unaffected by exposure to the oxidizing environment. The structure of the oxide film formed by contact ...
1982-01-01
Simulated nitrogen deposition affects wood decomposition by cord-forming fungi.
Anthropogenic nitrogen (N) deposition affects many natural processes, including forest litter decomposition. Saprotrophic fungi are the only organisms capable of completely decomposing lignocellulosic (woody) litter in temperate ecosystems, and therefore the responses of fungi to N deposition are critical in understanding the effects of global change on the forest carbon cycle. Plant litter decomposition under elevated N has been intensively studied, with varying results. The complexity of forest floor biota and variability in litter quality have obscured N-elevation effects on decomposers. Field experiments often utilize standardized substrates and N-levels, but few studies have controlled the decay organisms. Decomposition of beech (Fagus sylvatica) blocks inoculated with two cord-forming basidiomycete fungi, Hypholoma fasciculare and Phanerochaete velutina, was compared experimentally under realistic levels of simulated N deposition at Wytham Wood, Oxfordshire, ...
2011-07-01
Study on core cooling of hybrid safety system for next-generation PWR during LOCA
International Nuclear Information System (INIS)
Mitsubishi is now developing a next-generation Pressurized Water Reactor (PWR) which has the innovative feature of hybrid safety systems (optimum combination of passive safety system and active safety system) and passive core cooling by horizontal steam generators during Loss of Coolant Accident (LOCA). In order to confirm the capability of this passive core cooling system during LOCAs, the thermal-hydraulic tests of horizontal steam generator and the integral thermal-hydraulic tests simulating the LOCAs were performed. The thermal-hydraulic tests of horizontal steam generator consist of a single tube test and a multi-tubes test. On the basis of these test results, the heat transfer characteristics of steam-water two-phase flow with noncondensable gas along a long horizontal tube is understood and the heat transfer correlation including the effect of noncondensable gas is presented. The integral thermal-hydraulic tests ...
1995-04-23
Regional ecological impacts of the development of oil shale resources: a review
Energy Technology Data Exchange (ETDEWEB)
Significant development of an oil shale industry has been projected over the next few decades. The nation's largest oil shale reserves exist in the Wyoming Basin and Colorado Plateau physiographic provinces. This study presents a brief description of the environmental setting and land-use pattern of the region, with a review of the major environmental issues associated with each proposed technology for extracting shale oil. Serious effects may be expected from the modification of very large land surfaces through open-pit mining and spent-shale disposal. The impacts include habitat destruction, potential species loss, and deterioration of surface and groundwater quality. In situ retorting of shale may result in major alterations of groundwater quantity, quality, and flow regimes. Mine dewatering from in situ retorting requires the disposal of large volumes of highly saline water, threatening the quality of subsurface and surface ...
1982-08-01
Energy Technology Data Exchange (ETDEWEB)
A precise admixtures system is needed when using high-volume fly ash concrete as fresh concrete occasionally undergoes rapid slump loss after mixing, which can cause problems with casting, pumping and finishing of the concrete in hot weather. This paper provided details of a study conducted to implement high-volume fly ash concrete technology in India. Different families of admixtures were investigated to determine their water reduction capacities. A set-retarding admixture was used in some of the concrete mixtures in order to determine its efficacy. An Indian Portland cement was used to create a total of 22 different concrete mixtures. Four different fly ashes were used to replace portions of the concrete. The slump of the fresh concrete mixture was monitored for 2 to 3 hours. Unit weight and temperature of the concrete was measured. Specimens were cast in steel moulds in order to determine the compressive strength and unit weight of the ...
2006-07-01
3D-nuclear heat generation in PCC-charcoal filter in TAPP-3 and 4
International Nuclear Information System (INIS)
This paper deals with the calculations of 3D nuclear heat generation profile in the charcoal filter and subsequently the commencement time of Primary Containment Cleanup (PCC) system of 540MWe Pressurized Heavy Water Reactor (PHWR). Fuel failure is predicted due to overheating of the fuel under loss of Coolant Accident (LOCA) without Emergency Core Cooling System (LOCA without ECCS). Subsequently fission product gasses along with water vapours are released to Reactor Building (RB) atmosphere. Plate-out and water trapping mechanism stabilizes the concentration of significant fission products i.e. radioiodines in about 4 hours before being circulated through charcoal filters of Containment Cleanup system. After cleaning up the RB atmosphere, it is discharged to outside atmosphere through stack. The isotopes of radioiodine emit beta and gamma radiations. Gamma radiations are partly stopped within the ...
2006-11-13
Snow Survey & Water Supply | NRCS
Programs & Services Technical Resources Land Use Soils Water Snow Survey & Water Supply Water Management Water Quality Watersheds Wetlands Air Plants & Animals Energy Climate...
2011-08-21
Thermal stability of nanocomposite CrC/a-C:H thin films
International Nuclear Information System (INIS)
The thermal stability of low-friction Me-C/a-C:H coatings is important for their potential applications in the tool and automotive industry. Recently we showed that CrC _x/a-C:H coatings prepared by unbalanced magnetron sputtering of a Cr target in Ar + CH_4 glow discharges exhibit a nanocomposite structure where metastable fcc CrC nanocrystals are encapsulated by an a-C:H phase. Here, we present the structural evolution of these nanocomposite CrC/a-C:H coatings during annealing. High-temperature X-ray diffraction in vacuum and differential scanning calorimetry (DSC) combined with thermo-gravimetric analysis in Ar atmosphere indicate decomposition of the formed metastable fcc CrC phase and subsequent formation of Cr_3C_2 and Cr_7C_3 and structural transformation of the a-C:H matrix phase towards higher sp"2 bonding contents at temperatures above 450 deg. C. Combined DSC and mass spectrometer analysis as well as elemental profiling after annealing in vacuum by ...
2007-05-07
TRANSPORT CHARACTERISTICS OF REPRESENTATIVE DEBRIS IN A OPEN CHANNEL
Energy Technology Data Exchange (ETDEWEB)
During LOCA(Loss of Coolant Accident), emergency core coolant supplements form a recirculation sump and cooled core and containment. When the double ended guillotine Break (DEGB) at the hot leg near steam generator, due to the jet impingement discharge flow, the debris could be potentially generated at pipe or wall nearby steam generator and be transported to the recirculation sump. Therefore, the debris could be accumulated and be clogged in the recirculation sump screen. If debris blocked the sump screen, the pressure drop increased at the screen so as to increase the pressure loss of ECCS (Emergency Core Cooling System) pump NPSH (Net positive suction head). It is potentially influenced to decrease the long-term cooling capability of the recirculation sump. The recirculation sump screen clogging accident has happened in BWR at 1990. Considering the important of safety, US NRC published Regulatory Guide 1.82 Rev.3 ...
2010-05-15
Sump Pool Flow Simulation during Fill-up Phase of LOCA Using on CFD for OPR1000 Plant
Energy Technology Data Exchange (ETDEWEB)
During LOCA (Loss of Coolant Accident) in design bases accident (DBA), emergency core coolant supplements form a recirculation sump and cooled core and containment. When the double ended guillotine Break (DEGB) at the hot leg near steam generator, due to the jet impingement discharge flow, the debris could be potentially generated at pipe or wall nearby steam generator and be transported to the recirculation sump. Therefore, the debris, such as insulations and paint chips, could be accumulated and be clogged in the recirculation sump screen. If debris is blocked the sump strainer, the pressure drop is increased at the screen so as to increase the pressure loss of ECCS (Emergency Core Cooling System) pump NPSH (Net positive suction head). It is potentially influenced to decrease the long-term cooling capability of the recirculation sump. The recirculation sump screen clogging accident has happened in BWR of USA and Sweden. ...
2009-10-15
Energy Technology Data Exchange (ETDEWEB)
A joint materials test program developed by the Institute for Mining and Minerals Research (IMMR) and the Tennessee Valley Authority (TVA) involved the postexposure mechanical properties and corrosion behavior of candidate structural materials in an experimental, atmospheric fluidized-bed combustor (AFBC). This combustor was operated by Accurex Corporation at Research Triangle Park, North Carolina, under the direction of TVA. The materials studied were Type 304, Type 310, and INCOLOY alloy 800 in the form of disc coupons with and without crevice configurations. Type 304 was also used for mechanical property measurements. The alloys were exposed to the combustor environment at about840/sup 0/C for approximately 330 hours. The ranking in terms of decreasing weight loss was: (1) Type 304, (2) Type 310, and (3) INCOLOY alloy 800. The presence of tight crevices did not enhance the corrosion rate. In addition, the corrosion rates, based on the weight ...
1984-06-01
International Nuclear Information System (INIS)
Ultra-low pure Pt-based electrodes (0.04-0.12 mg_P_t/cm"2) were prepared by dual ion-beam assisted deposition (dual IBAD) method on the surface of a non-catalyzed gas diffusion layer (GDL) substrate. Film thicknesses ranged between 250 and 750 A, these are compared with a control, a conventional Pt/C (1.0 mg_P_t_(_M_E_A_)/cm"2, E-TEK). The IBAD electrode constituted a significantly different morphology, where low density Pt deposits (largely amorphous) were formed with varying depths of penetration into the gas diffusion layer, exhibiting a gradual change towards increasing crystalline character (from 250 to 750 A). Mass specific power density of 0.297 g_P_t/kW is reported with 250 A IBAD deposit (0.04 mg_P_t/cm"2 for a total MEA loading of 0.08 mg_P_t/cm"2) at 0.65 V. This is contrasted with the commercial MEA with a loading of 1 mg_P_t_(_M_E_A_)/cm"2 where mass specific power density obtained was 1.18 g_P_t/kW (at 0.65 V), a value typical of current state of the ...
2006-06-05
Energy Technology Data Exchange (ETDEWEB)
Cold plasma nitriding treatment was performed to improve the corrosion resistance of C38 carbon steel. Nitriding process was conducted using a radiofrequency nitrogen plasma discharge for different times of treatment on non-heated substrates. The modification of the corrosion resistance characteristic of the C38 steel due to the treatment in acid medium (1 M HCl) were investigated by gravimetric and electrochemical tests such as potentiodynamic polarisation curves and electrochemical impedance spectroscopy (EIS). It was shown that the plasma nitriding treatment improves the corrosion resistance. Indeed, in the gravimetric tests, nitrided samples showed lower weight loss and lower corrosion rate in comparison to untreated one. In the Tafel polarisation tests, the nitrided samples showed greatly reduced corrosion current densities, anodic dissolution and also retarded the hydrogen evolution reaction. Using EIS method, an adequate structural model of the interface was ...
2009-03-01
Irradiation-assisted stress corrosion cracking in HTH Alloy X-750 and Alloy 625
International Nuclear Information System (INIS)
In-reactor testing of bolt-loaded compact tension specimens was performed in 360 C water to determine the irradiation-assisted stress corrosion cracking (IASCC) behavior of HTH Alloy X-750 and direct-aged Alloy 625. New data confirm previous results showing that high irradiation levels reduce SCC resistance in Alloy X-750. Heat-to-heat variability correlates with boron content, with low boron heats showing improved IASCC properties. Alloy 625 is resistant to IASCC, as no cracking was observed in any Alloy 625 specimens. Microstructural, microchemical and deformation studies were performed to characterize the mechanisms responsible for IASCC in Alloy X-750 and the lack of an effect in Alloy 625. The mechanisms under investigation are: boron transmutation effects, radiation-induced changes in microstructure and deformation characteristics, and radiation-induced segregation. Irradiation of Alloy X-750 caused significant strengthening and ductility ...
1995-08-06
Energy Technology Data Exchange (ETDEWEB)
During 1991 and 1992, we studied 92 wetlands, including open water (ponds) and emergent communities, created as a result of Wyoming Abandoned Mine Lands` (AML) reclamation efforts in northeast Wyoming. Through these activities, over 300 wetlands were filled, reclaimed, created, or otherwise modified. For mitigation purposes wetlands to be filled or modified were first evaluated using a Wetland Habitat Value (WHV) Model. Using the model, wetland losses were mitigated by increasing the WHV of some wetlands or by creating new wetlands elsewhere. We evaluated model performance in offsetting wetland loss and how well the model predicted waterfowl use. We also compared post-reclamation wetland sizes to those predicted by engineering plans and submitted for Section 404 permit approval. In our study, predicted WHVs were overestimated at 100% of the wetlands for which pre-reclamation WHVs were available (n8). The most commonly ...
1994-12-01
Corrosion probes for fireside monitoring in coal-fired boilers
Energy Technology Data Exchange (ETDEWEB)
Corrosion probes are being developed and combined with an existing measurement technology to provide a tool for assessing the extent of corrosion of metallic materials on the fireside in coal-fired boilers. The successful development of this technology will provide power plant operators the ability to (1) accurately monitor metal loss in critical regions of the boiler, such as waterwalls, superheaters, and reheaters; and (2) use corrosion rates as process variables. In the former, corrosion data could be used to schedule maintenance periods and in the later, processes can be altered to decrease corrosion rates. The research approach involves laboratory research in simulated environments that will lead to field tests of corrosion probes in coal-fired boilers. Laboratory research has already shown that electrochemically-measured corrosion rates for ash-covered metals are similar to actual mass loss corrosion rates. Electrochemical tests conducted ...
2005-01-01
Updated user's guide for SAMMY: multilevel R-matrix fits to neutron data using Bayes' equation
International Nuclear Information System (INIS)
In 1980 the multilevel multichannel R-matrix code SAMMY was released for use in analysis of neutron data at the Oak Ridge Electron Linear Accelerator. Since that time, SAMMY has undergone significant modifications: (1) User-friendly options have been incorporated to streamline common operations and to protect a run from common user errors, (2) The Reich-Moore formalism has been extended to include an optional logarithmic parameterization of the external R-matrix, for which any or all parameters may be varied, (3) the ability to vary sample thickness, effective temperature, matching radius, and/or resolution-broadening parameters has been incorporated, (4) to avoid loss of information (i.e. computer round-off errors) between runs, the ''covariance file'' now includes precise values for al variables, (5) Unused but correlated variables may be included in the analysis. Because of these and earlier changes, the 1980 SAMMY manual is now hopelessly obsolete. This report ...
The effect of temperature on the passive film properties and pitting behaviour of a Fe-Cr-Ni alloy
Energy Technology Data Exchange (ETDEWEB)
The effect of temperature (60-280{sup o}C) on the properties of the oxide films formed on Alloy 800 in 0.1 M NaCl and 0.1 M Na{sub 2}SO{sub 4} aqueous solutions was studied by in situ AC impedance spectroscopy and polarization in the Fe(CN{sub 6}){sup -3}/Fe(CN){sub 6}{sup -4} redox system. The anodic behavior under the same experimental conditions was examined by potentiodynamic polarization techniques. In both solutions the passive film was found to become more porous, and hence less protective, with increasing temperature. However, at temperatures above 150{sup o}C, the loss of film protectiveness is more pronounced in chloride solutions, in which pitting occurs. Pitting morphology was found to be strongly temperature dependent: isolated and deep pits were found up to 200{sup o}C whereas at higher temperatures a broad, shallow and more generalized type of attack was detected. No effect of temperature on the defect structure of the ...
1996-06-01
The composite absolute penalties family for grouped and hierarchical variable selection
Extracting useful information from high-dimensional data is an important focus of today's statistical research and practice. Penalized loss function minimization has been shown to be effective for this task both theoretically and empirically. With the virtues of both regularization and sparsity, the $L_1$-penalized squared error minimization method Lasso has been popular in regression models and beyond. In this paper, we combine different norms including $L_1$ to form an intelligent penalty in order to add side information to the fitting of a regression or classification model to obtain reasonable estimates. Specifically, we introduce the Composite Absolute Penalties (CAP) family, which allows given grouping and hierarchical relationships between the predictors to be expressed. CAP penalties are built by defining groups and combining the properties of norm penalties at the across-group and within-group levels. Grouped selection occurs for ...
2009-01-01
Studies on the development of mossy zinc electrodeposits from flowing alkaline electrolytes
Energy Technology Data Exchange (ETDEWEB)
The initiation and characteristics of mossy zinc electrodeposits have been investigated. Batteries with zinc electrodes are candidates for electric vehicle applications; however, this electrode is prone to form non-compact deposits that contribute to capacity loss and battery failure. Moss is deposited when the current density is far from the limiting current. This morphology first appears only after the bulk deposit is approximately 1 {mu}m thick. In this investigation, the effects of flow rate (Re=0--4000), current density (0--50 mA/cm{sup 2}), concentration of the electroactive species (0.25 and 0.5 M), and the concentration of supporting electrolyte (3, 6, and 12 M) on the initiation of moss were examined. The rotating concentric cylinder electrode was employed for most of the experiments; and a flow channel was used to study the development of morphology. After the experiment, the deposit was characterized using microscopic, x-ray ...
1991-07-01
Studies on accumulation of uranium by fungus Lentinus sajor-caju
Energy Technology Data Exchange (ETDEWEB)
The untreated, heat- and alkali-treated Lentinus sajor-caju mycelia were used for the recovery of uranium from aqueous solutions. The effect of pH, temperature, initial concentration of UO{sub 2} {sup 2+} ions and contact time parameters were investigated in a batch system. The particles sizes of the fungal mycelia were ranging from 100 to 200 {mu}m. Biosorption equilibriums were established in about 30 min and the correlation regression coefficients show that the adsorption process can be well defined by the Freundlich equation. The alkali treated form had a high biosorption capacity (378 mg/g) than those of the untreated (268 mg/g) and heat-treated fungal mycelia (342 mg/g). Optimum biosorption was observed at pH 4.5 for all the tested fungal preparations and was independent of temperature (5-35 deg. C). In addition, the polarity and surface energy of the fungal biomass film preparations were determined by contact angle measurement. The fungal biomass could be ...
2006-08-21
International Nuclear Information System (INIS)
Electrodeposition of semiconducting iron oxide (Fe_2O_3) thin film was carried out from an alkaline sulphate bath. A 0.1 M ferrous sulphate (FeSO_4#centre dot#7H_2O) was complexed with 0.1 M citric acid. By addition of 1 N NaOH, pH of the solution was made alkaline (pH=9) and deposition of iron oxide (Fe_2O_3) thin films was carried out potentiostatically at room temperature (300 K). From cyclic voltametry (CV), electrochemical studies were carried out for deposition of iron oxide thin films. The XRD studies reveal that Fe_2O_3 with epsilon (#epsilon#) phase having monoclinic crystal structure is formed. By observing scanning electron microscope (SEM), it is seen that iron oxide films were homogeneous, uniform and well covered to surface of the substrate. Grain size was found to be in nanometers range from XRD analysis. The optical band gap of Fe_2O_3 thin film was estimated to be 1.90 eV. Electrical resistivity was order of 10"4 #OMEGA# cm. Dielectric constant and ...
2003-09-28
Spectral dependence of ultrasonic attenuation for hydrided Zr-2.5%Nb Alloy
International Nuclear Information System (INIS)
The cold-worked Zr-2.5%Nb alloy is used as material for the pressure tubes in CANDU nuclear reactors. During the service life in reactor, diffusion of hydrogen and/or deuterium in the pressure tubes wall occur. Below a certain temperature, a stable hydride of zirconium is formed, as a brittle phase which can lead to catastrophic failures. For this reason, it is very important to be able to investigate the hydrogen effect on the micro structural properties of zirconium alloys. In the present paper a non-destructive testing technique is used, known as ultrasonic spectral analysis. When an ultrasonic signal traverses a medium, the frequency components associated with the input signal are altered. By frequency analysing the reflected signals, it is possible to study and compare the material properties. The two major parameters measured in ultrasonic spectroscopy are the attenuation and the velocity of the waves. Attenuation is determined by the energy ...
2009-10-12
Rheology of zirconia suspensions in a nonpolar organic medium
Energy Technology Data Exchange (ETDEWEB)
Three dispersants (stearic acid, oleic acid, and poly-(12-hydroxystearic acid)) are compared for their ability to produce low-viscosity suspensions of zirconia in kerosene. Rheological measurements and sediment packing density measurements show that poly(12-hydroxystearic acid) is a better dispersant than stearic acid or oleic acid; this is explained in terms of the longer tail of the poly-(12-hydroxystearic acid) surfactant molecule. The amount of dispersant can be optimized to reduce viscosity and yield point of the suspension, and to eliminate thixotropic hysteresis. The use of a dispersion medium of lower viscosity than the dispersant makes it easy to detect when complete monolayer coverage has been achieved. The loss of pseudoplasticity, brought about by a higher degree of deflocculation, can be recovered by increasing the volume fraction of solids of a suspension and this is beneficial in the plastic forming of ceramics. Rheological ...
1995-12-01
Energy Technology Data Exchange (ETDEWEB)
The present invention concerns a negative ion source electrode which can be preferably used in a neutral particle injection device using negative ions for a thermonuclear reactor. Negative ion beams are deflected to the direction opposite to the deflecting direction by magnetic fields by using an electron suppression electrode having electrode holes with the position previously displaced before negative ion beams are accelerated to have a high energy by an accelerator thereby correcting the orbit of the negative ion beams easily. In addition, since the deflection correction electrode having the electrode holes is disposed, a proper voltage is applied to the deflection correction electrode to correct the orbit of the negative ion beams conveniently. Since the deflection correction electrode has a simple structure of a thin flat plate having electrode holes, the orbit of negative ion beams can be corrected efficiently by an extremely simple structure without inducing lowering of ...
1997-01-17
Energy Technology Data Exchange (ETDEWEB)
This work presents comparative results of a numerical investigation of four possible models for the prediction of thermal performance of fixed bed storage units and their thermal design. These models includes Schumann's model, the radial dispersion model, a model that include both axial heat conduction in the fluid phase and admits thermal gradient in the solids particles and finally a two dimensional single phase model. For each of these models a computer code was written and tested to evaluate the computing time of same data and analyze any other computational problems. The tests of thermal performance included particle size, porosity, particle material, flow rate, inlet temperature and heat losses form tank walls and extremities. Dynamics behaviour of the storage units due to transient variation in either flow rate or inlet temperature was also investigated. The results presented include temperature gradients, pressure drop and heat ...
1991-07-01
Energy Technology Data Exchange (ETDEWEB)
Piezoelectric ceramics for acoustic applications have been prepared by mixing the piezoelectric phase Pb{sub 1-1.5x}La{sub x}{open_square}{sub x/2}(Ti{sub 1-y}Zr{sub y})O{sub 3} (PLZT) with variable fractions of Al{sub 2}O{sub 3}. The samples are in form of pellets and polarized at high temperature. After thermal treatment, X-ray diffraction and scanning electron microscopy have been used to determine the phase and morphological modifications. The morphotropic PLZT initial phase disproportionates into modified PLZT and ZrO{sub 2} phases. Using electrical impedance spectroscopy, the resonance frequencies of the composite system have been determined and analyzed. As the Al{sub 2}O{sub 3} volume fractions increase, the resonance frequency and the amplitude of the electrical response both decrease. An interpretation of the role of Al{sub 2}O{sub 3} additions is proposed in terms of phase and microstructure modifications. Using LRC electrical equivalent circuits, the ...
2003-01-15
International Nuclear Information System (INIS)
We report, for the first time to our knowledge, on the active optical planar waveguides in Nd : YAG laser crystals fabricated by O3+ ion implantation at low doses of ?1014 ions cm-2. The reconstructed refractive index profiles based on the measured dark-mode spectroscopy show that an enhanced refractive index well is created in the near-surface region, forming a non-leaky waveguide structure. With thermal annealing treatment at 260 0C for 90 min, the propagation losses of the waveguides could be reduced to ?3 dB cm-1 at a wavelength of 632.8 nm. The micro-luminescence investigation reveals that the emission bands of Nd3+ ions are not significantly affected by the waveguide formation processing, which shows promising potentials for efficient waveguide laser operations at near-infrared wavelength bands.
2008-09-07
British Library Electronic Table of Contents (United Kingdom)
The photoelectron resonance capture ionization (PERCI) of cysteine (Cys) and small gas-phase neutral peptides that contain the Cys residue (Cys-Gly, g-Glu-Cys, and glutathione (g-Glu-Cys-Gly)) is reported. At an ionization energy less than 1eV two types of dissociative electron attachment ionization were observed for Cys: hydrogen atom loss, resulting in formation of the ion [Cys-H]-, and dissociation of the CH2-SH bond, resulting in formation of the ion [SH]-. The presence of these ions suggests that both the p*(-CO2H) and *(C-S) orbitals can act as low energy electrophores on Cys. This ionization trend was observed for the dipeptides Cys-Gly and g-Glu-Cys as well as glutathione, with evidence that dissociation of the CH2-SH bond in these peptides can also result in ions of the form [M-SH...
2009-01-01
British Library Electronic Table of Contents (United Kingdom)
Parkinson's disease (PD) is the most common neurodegenerative movement disorder. Mutations in PTEN-induced kinase 1 (PINK1) are a frequent cause of recessive PD. Autophagy, a pathway for clearance of protein aggregates or impaired organelles, is a newly identified mechanism for PD development. However, it is still unclear what molecules regulate autophagy in PINK1-silenced cells. Here we report that autophagosome formation is promoted in the early phase in response to PINK1 gene silencing by lentivirus transfer vectors expressed in mouse striatum. Reduced PP2A activity and increased phosphorylation of PP2A at Y307 (inactive form of PP2A) were observed in PINK1-knockdown dopaminergic cells and striatum tissues. Treatment with C2-ceramide (an agonist of PP2A) reduced autophagy levels in PINK...
2011-01-01
Local Group Dwarf Galaxies: Nature And Nurture
We investigate the formation and evolution of dwarf galaxies in a high resolution, hydrodynamical cosmological simulation of a Milky Way sized halo and its environment. Our simulation includes gas cooling, star formation, supernova feedback, metal enrichment and UV heating. In total, 90 satellites and more than 400 isolated dwarf galaxies are formed in the simulation, allowing a systematic study of the internal and environmental processes that determine their evolution. We find that 95% of satellite galaxies are gas-free at z=0, and identify three mechanisms for gas loss: supernova feedback, tidal stripping, and photo-evaporation due to re-ionization. Gas-rich satellite galaxies are only found with total masses above ~ 5x10^9 solar masses. In contrast, for isolated dwarf galaxies, a total mass of ~ 10^9 solar masses constitutes a sharp transition; less massive galaxies are predominantly gas-free at z=0, more massive, isolated dwarf galaxies are ...
2011-01-01
International Nuclear Information System (INIS)
LOCA (Loss of coolant accident) resistant heat-shrinkable polymeric products are widely used for the connection of LV cables for class 1E systems inside the containment area of nuclear power plants. The paper/presentation describes the verification of a reformulated compound for these products, where certain components of the compound formulation had to be substituted. A qualification programme with this so-called reformulated compound was undertaken to proof the equivalency of the products to the products made out of the original compound. The basic elements of this requalification project were material qualification tests including accelerated aging tests according to the arrhenius method and type tests in accordance to IEEE 383, including flammability tests. The test results showed that the products made out of the reformulated compound were similar in fit, form and function to the original products. Additional tests have also proven higher ...
2005-06-15
Energy Technology Data Exchange (ETDEWEB)
For an assessment of the future US spallation neutron source (SNS) target performance, radiation induced hardening and microstructural evolution were investigated as a function of ion dose for EC316LN stainless steel. Irradiation was carried out using 3.5 MeV Fe{sup +}, 360 keV He{sup +}, and 180 keV H{sup +} simultaneous ion-beams at 200 deg. C to simulate the damage, He and H production in the SNS target vessel wall. At low dose (< 1 dpa), the predominant defects were black dots whose number density saturated rapidly within a few dpa. This was followed by the evolution of interstitial loops whose number density saturated below 15 dpa. Although He-bubbles were not visible, severely scalloped loops suggested that the implanted He/H atoms existed in the form of small clusters. Comparison with reported neutron irradiation data showed that hardening and ductility loss occurred mostly in the black dot regime (< 1 dpa), but that good ...
2000-04-01
International Nuclear Information System (INIS)
For an assessment of the future US spallation neutron source (SNS) target performance, radiation induced hardening and microstructural evolution were investigated as a function of ion dose for EC316LN stainless steel. Irradiation was carried out using 3.5 MeV Fe"+, 360 keV He"+, and 180 keV H"+ simultaneous ion-beams at 200 deg. C to simulate the damage, He and H production in the SNS target vessel wall. At low dose (< 1 dpa), the predominant defects were black dots whose number density saturated rapidly within a few dpa. This was followed by the evolution of interstitial loops whose number density saturated below 15 dpa. Although He-bubbles were not visible, severely scalloped loops suggested that the implanted He/H atoms existed in the form of small clusters. Comparison with reported neutron irradiation data showed that hardening and ductility loss occurred mostly in the black dot regime (< 1 dpa), but that good ductility (>20% ...
2000-04-01
Frame Selected Approach for Hiding Data within MPEG Video Using Bit Plane Complexity Segmentation
Bit Plane Complexity Segmentation (BPCS) digital picture steganography is a technique to hide data inside an image file. BPCS achieves high embedding rates with low distortion based on the theory that noise-like regions in an image's bit-planes can be replaced with noise-like secret data without significant loss in image quality. . In this framework we will propose a collaborate approach for select frame for Hiding Data within MPEG Video Using Bit Plane Complexity Segmentation. This approach will invent high secure data hidden using select frame form MPEG Video and furthermore we will assign the well-built of the approach; during this review the author will answer the question why they used select frame steganography. In additional to the security issues we will use the digital video as a cover to the data hidden. The reason behind opt the video cover in this approach is the huge amount of single frames image per sec which in turn overcome the ...
2009-01-01
Extracting energy from hydraulically-fractured geothermal reservoirs
The governing equations for heat and mass transfer were derived for hydraulically fractured geothermal reservoirs. When converted to nondimensional form it was shown that the equations can be considerably simplified. The resulting equations can be strongly influenced by the effects of buoyancy; the magnitude of the effect is measured by the ratio of the Grashof and Reynolds numbers, and the ratio of the actual permeability of the fracture and the square of the fracture gap width. Significant quantities of energy can be extracted from hydraulic fractures--even without thermal stress fracturing. The amount is limited by the size of the fracture and the low thermal conductivity of rock. The viscous pressure drop in open fractures is insignificant, and depending upon losses in piping and surface equipment, the entire system could be ''self-pumped'' due to buoyancy. Thermal contraction of the rock tends to ...
1976-01-01
Emittance of boehmite and alumina films on 6061 aluminium alloy between 295 and 773 K
Energy Technology Data Exchange (ETDEWEB)
The total hemispherical emittance of an oxide film that formed on 6061-T6 aluminium alloy parts in the Tower Shielding Reactor-II at Oak Ridge National Laboratory was measured from 295 to 773 K using an emissometer and/or a calorimeter. The emittance of this film was critically needed for heat transfer calculations in a simulated loss-of-coolant accident of the reactor. X-ray diffraction analysis identified the film as boehmite (Al{sub 2}O{sub 3} {times} H{sub 2}O), which dehydrated to alumina (Al{sub 2}O{sub 3}) upon heating above 473 K. The measured emittances for the alumina film are in excellent agreement with published values for anodized aluminum films and for bulk alumina. Published values of the emittance of boehmite could not be found for comparison, but evidence is presented that some anodization processes for aluminum yield boehmite and not alumina films.
1991-02-01
Distributed Grating-Assisted Coupler for Optical All-Dielectric Electron Accelerator
Energy Technology Data Exchange (ETDEWEB)
A Bragg waveguide consisting of multiple dielectric layers with alternating index of refraction becomes an excellent option to form electron accelerating structure powered by high power laser sources. It provides confinement of a synchronous speed-of-light mode with extremely low loss. However, laser field can not be coupled into the structure collinearly with the electron beam. There are three requirements in designing input coupler for a Bragg electron accelerator: side-coupling, selective mode excitation, and high coupling efficiency. We present a side coupling scheme using a distributed grating-assisted coupler to inject the laser power into the waveguide. Side coupling is achieved by a grating with a period on the order of an optical wavelength. The phase matching condition results in resonance coupling thus providing selective mode excitation capability. The coupling efficiency is limited by profile matching between the outgoing beam and ...
2005-09-23
Direct energy conversion for IEC fusion for space applications
Energy Technology Data Exchange (ETDEWEB)
The paper describes a concept of extracting fusion power from D-{sup 3}He fueled IEC (Inertia Electrostatic Configuration) devices. The fusion system consists of a series of fusion modules and direct energy converters at an end or at both ends. This system of multiple units is linear and is connected by a magnetic field. A pair of coils anti-parallel to the magnetic field yields a field-null domain at the center of each unit as required for IEC operation. A stabilizing coil installed between the coil pairs eliminates the strong attractive force between the anti-parallel coils. Accessible regions for charged particle trajectories are essentially isolated from the coil structure. Thus, charged particles are directed along magnetic field lines to the direct energy converter without appreciable losses. A direct energy converter unit designed to be compatible to this unique system is also described. It basically consists of a separator and a traveling wave converter. A ...
2000-08-01
Development of a high performance air heater through use of an evacuated tube cover design
Development of a high performance air heater through use of an evacuated tube cover design is described. The cover design utilizes evacuated fluorescent light tubes laid parallel in a close packed array to form an inner transparent glazing over a conventional metal absorber plate with flow behind the plate. A tempered flat glass plate was used as an outer glazing. Both clear and infrared reflective (IR) tubes were investigated. Solar transmittance tests indicate that the clear tube array has a higher transmittance than two flat sheets of low-iron glass. The IR coating produced substantial transmittance loss. Thermal conductance tests indicate that the tubes behave similar to two flat glass sheets with a vacuum in between. The IR reflective coating was only marginally effective at reducing heat conductance. Final prototype designs are presented along with collector performance estimates.
1980-01-01
Composites from recycled wood and plastics. Report for May 1990-July 1993
Energy Technology Data Exchange (ETDEWEB)
The ultimate goal of this research was to develop technology to convert recycled wood fiber and plastics into durable products that are recyclable and otherwise environmentally friendly. Two processing technologies were used to prepare wood-plastic composites: air-laying and melt-blending. Research was conducted in (1) developing laboratory methods for converting waste wood, wastepaper, and waste plastics into forms suitable for processing into composites; (2) optimizing laboratory methods for making composite panels from the waste materials; (3) establishing a database on the effects of formulation and bonding agent on physical and mechanical properties of composites; (4) establishing the extent to which the composites can be recycled without unacceptable loss in properties; and (5) reaching out to industry to provide education, to develop applications, and to extend the database. Overall, the program demonstrated that both air-laid and ...
1995-01-01
An evaluation of the alternative transport fuel policies for Turkey
Energy Technology Data Exchange (ETDEWEB)
The search for alternative fuels and new fuel resources is a top priority for Turkey, as is the case in the majority of countries throughout the world. The fuel policies pursued by governmental or civil authorities are of key importance in the success of alternative fuel use, especially for widespread and efficient use. Following the 1973 petroleum crisis, many users in Turkey, especially in transportation sector, searched for alternative fuels and forms of transportation. Gasoline engines were replaced with diesel engines between the mid-1970s and mid-1980s. In addition, natural gas was introduced to the Turkish market for heating in the early 1990s. Liquid petroleum gas was put into use in the mid-1990s, and bio-diesel was introduced into the market for transportation in 2003. However, after long periods of indifference governmental action, guidance and fuel policies were so weak that they did not make sense. Entrepreneurs and users experienced great economical ...
2010-06-15
International Nuclear Information System (INIS)
The authors have previously identified a small-cell lung cancer cell line (NCI-H209) that expresses an aberrant, underphosphorylated form of the retinoblastoma protein RB1. Molecular analysis of RB1 mRNA from this cell line revealed a single point mutation within exon 21 that resulted in a nonconservative amino acid substitution (cysteine to phenylalanine) at codon 706. Stable expression of this mutant RB1 cDNA in a human cell line lacking endogenous RB1 demonstrated that this amino acid change was sufficient to inhibit phosphorylation. In addition, this cysteine-to-phenylalanine substitution also resulted in loss of RB1 binding to the simian virus 40 large tumor and adenovirus E1A transforming proteins. These results confirm the importance of exon 21 coding sequences and suggest that the cysteine residue at codon 706 may play a role in achieving a specific protein conformation essential for protein-protein interactions.
"2"1"1At-Rh(16-S4-diol) complex as a precursor for astatine radiopharmaceuticals
International Nuclear Information System (INIS)
"2"1"1At is one of the most promising radionuclides in #alpha#-radioimmunotherapy (#alpha#-RIT). Unfortunately, biomolecules labeled by direct electrophilic astatination are unstable due to the rapid loss of "2"1"1At under both in vitro and in vivo conditions. The present paper describes the results of our studies on attaching At"- to the rhodium(III) complex with thioether ligand: 1,5,9,13-etrathiacyclohexadecane-3,11-diol (16-S4-diol). Rh"3"+ was chosen as a moderately soft metal cation which should form very strong bonds with soft At"- anions, but first of all because of the kinetic inertness of low spin rhodium(III) d"6 complexes. The 16-S4-diol ligand was selected due to formation of stable complexes with Rh"3"+. The experiments related to optimization of the reaction conditions were performed with the "1"3"1I, basing on a chemical similarity of I"- to At"-. The experiments with "2"1"1At were then carried out under the conditions found ...
Zinc air battery development for electric vehicles. Final report
Energy Technology Data Exchange (ETDEWEB)
This report summarizes the results of research conducted during the sixteen month continuation of a program to develop rechargeable zinc-air batteries for electric vehicles. The zinc-air technology under development incorporates a metal foam substrate for the zinc electrode, with flow of electrolyte through the foam during battery operation. In this ``soluble`` zinc electrode the zincate discharge product dissolves completely in the electrolyte stream. Cycle testing at Lawrence Berkeley Laboratory, where the electrode was invented, and at MATSI showed that this approach avoids the zinc electrode shape change phenomenon. Further, electrolyte flow has been shown to be necessary to achieve significant cycle life (> 25 cycles) in this open system. Without it, water loss through the oxygen electrode results in high-resistance failure of the cell. The Phase I program, which focused entirely on the zinc electrode, elucidated the conditions ...
1991-07-01
Zinc air battery development for electric vehicles
Energy Technology Data Exchange (ETDEWEB)
This report summarizes the results of research conducted during the sixteen month continuation of a program to develop rechargeable zinc-air batteries for electric vehicles. The zinc-air technology under development incorporates a metal foam substrate for the zinc electrode, with flow of electrolyte through the foam during battery operation. In this soluble'' zinc electrode the zincate discharge product dissolves completely in the electrolyte stream. Cycle testing at Lawrence Berkeley Laboratory, where the electrode was invented, and at MATSI showed that this approach avoids the zinc electrode shape change phenomenon. Further, electrolyte flow has been shown to be necessary to achieve significant cycle life (> 25 cycles) in this open system. Without it, water loss through the oxygen electrode results in high-resistance failure of the cell. The Phase I program, which focused entirely on the zinc electrode, elucidated the ...
1991-07-01
Wetland creation and restoration: The status of the science
Energy Technology Data Exchange (ETDEWEB)
In the last decade, interest has increased in coastal and freshwater wetland restoration and creation at all levels of government, in the scientific community, and in the private sector. US Environmental Protection Agency personnel agreed that there was a pressing need to determine how well created and restored wetlands compensate for losses permitted under Section 404 of the Clean Water Act. An effort was made to capture information not published elsewhere and incorporate it with published literature to produce a unique resource. The status report is the first major publication resulting from research initiated on wetland creation and restoration. Conceived as a mechanism for identifying the adequacy of the available information, this status report will help set priorities for the research program and provide Agency personnel with an analytical framework for making Section 404 permit decisions based on the status of the science of wetland ...
1990-01-01
The ecology of the coastal marshes of western Lake Erie: A community profile
Energy Technology Data Exchange (ETDEWEB)
Lake Erie, the southernmost of the Laurentian Great Lakes, is narrow and relatively shallow in comparison to other Great Lakes. The lake experiences extreme water level fluctuations and storm energy restricts the development of wetlands to protected areas within embayments, lagoons, or behind barriers. However, coastal marshes of western Lake Erie fringe the shorelines of Michigan, Ohio, and Ontario and encompass an area of 268 km/sup 2/. This publication reviews the ecological data and information on the wetlands of Lake Erie, which are some of the more productive areas in the Great Lakes ecosystem. The geologic history of the Lake Erie leading to the development of wetlands, the present environment, and present wetland distribution are presented as background in the opening chapters. Biological information available for the Lake Erie wetlands is discussed in detail, and ecological processes contributing to the evolution of wetlands, biological production, and ...
1987-02-01
Steady-state film-boiling data in rod-bundle geometry and non-equilibrium correlation assessment
Energy Technology Data Exchange (ETDEWEB)
A series of 22 steady-state, rod bundle, dispersed flow film boiling experiments has been performed in the Thermal-Hydraulic Test Facility (THTF), a pressurized-water loop containing 64 full-length electrically heated rods. Test parameters in the upflow experiments cover a wide range of conditions typical of those which might be encountered during a nuclear reactor loss-of-coolant accident. Local equilibrium fluid conditions were calculated using mass and energy conservation considerations. Experimentally determined heat transfer coefficients were compared to several available film boiling heat transfer correlations: Dougall-Rohsenow, Groeneveld 5.7, Groeneveld-Delorme, Chen, Jones-Zuber, and Yoder-Rohsenow. The Groeneveld 5.7 correlation tended to predict the data better than any other correlation tested. The Dougall-Rohsenow correlation tends to overpredict the data while the Yoder-Rohsenow correlation predicted the data better than the other ...
1982-01-01
Review of fires and fire control methods for nuclear air cleaning systems
International Nuclear Information System (INIS)
The nuclear power industry has experienced four carbon based adsorbent fires in its history, one was of the Monticello Standby Gas Treatment System and other three were in various off-gas delay beds. Although, some of the latter may not be classified as a full fledged fires. There were a number of experiments performed relating to igniting carbon beds and experiments relating to attempts at extinguishing set fires reported in the literature. Review of these experiments indicates that fire resulting from decay heat of adsorbed radioactive iodine is not justified even under the somewhat unrealistic source terms still in effect. At the same time the non-nuclear chemical industry application of carbon base adsorbents for solvent recovery has resulted in numerous fires and significant property losses. Fire control systems installed in nuclear air cleaning systems in the US consists of water deluge. Accidental initiation of these systems has occurred ...
1987-05-01
International Nuclear Information System (INIS)
Results from three separate experiments that have some relevance to bound residues are reported. In the first, "1"4C-labelled paraquat was lost when applied to soil in the field, about 26% of the radioactivity disappearing in 15 months, whereas in laboratory incubation studies there was no loss of radioactivity in one year. Two possible explanations are (i) that there was photolytic decomposition in the field, (ii) the preparation of the soil for the laboratory study upset the microbial ecology of the soil to the detriment of organisms that can degrade paraquat. In an experiment with "1"4C-labelled isoproturon, there was an indication that there was slightly more "1"4C in the unextractable humin fraction in soil in which wheat plants were grown than in bare soil. Work in the UK, Federal Republic of Germany and in Switzerland has shown that the phytotoxicity of residues of atrazine, carbetamide, chloridazone, propyzamide, simazine, lenacil, monolinuron, linuron, ...
1984-04-01
Energy Technology Data Exchange (ETDEWEB)
The paper is concerned with the economic operation of power systems comprising pumped storage and thermal plants. In power systems, pumped storage plants may receive the energy required for pumping water either from the system in which they are integrated or from a neighbouring system. Therefore, two mathematical formulations of the problem are presented depending on the source of energy during pumping. In both cases, the problem is reduced to a non linear optimization problem. Two numerical techniques are suggested for the solution of this optimization problem, namely the Lagrangian Multipliers technique and the Rosen Gradient Projection technique. Numerical examples are presented to demonstrate the techniques. Although the Lagrangian Multipliers technique has the advantage of being a well known technique, however, computer wise, the Rosen Gradient Projection technique proves to be more efficient. The results of the numerical examples given show that mechanical ...
1980-12-01
Metal cation inhibitors for controlling denting corrosion in steam generators. Final report. [PWR
Metal cations of arsenic, antimony, tin, manganese, zinc, cadmium, indium, and thallium have been evaluated in a preliminary way as possible3 inhibitors for controlling denting corrision observed in steam generators used with pressurized water reactors (PWR). The rationale for this approach was based upon the well-known inhibition effects of metal cations on corrosion rates in electrolyte/metal systems. A review of corrosion inhibition by metal cations (H. Leidheiser, Jr., Corrosion 36, 339 (1982)) has identified eleven inhibition mechanisms. The major test methods used for this evaluation were: (1) Isothermal capsule tests of carbon/steel/Inconel 600 tube bulging rates at temperatures up to 288/sup 0/C in seawater/copper-nickel chloride bulge-accelerating solutions. (2) Immersion weight-loss tests of steel coupled to Inconel 600 in boiling (102/sup 0/C) 3% sodium chloride solutions. In addition, electrochemical measuremens and surface analyses ...
1982-12-01
Irradiation-assisted stress corrosion cracking of HTH Alloy X-750 and Alloy 625
International Nuclear Information System (INIS)
In-reactor testing of bolt-loaded compact tension specimens was performed in 360 C water. New data confirms previous results that high irradiation levels reduce SCC resistance in Alloy X-750. Low boron heats show improved IASCC (irradiation-assisted stress corrosion cracking). Alloy 625 is resistant to IASCC. Microstructural, microchemical, and deformation studies were carried out. Irradiation of X-750 caused significant strengthening and ductility loss associated with formation of cavities and dislocation loops. High irradiation did not cause segregation in X-750. Irradiation of 625 resulted in formation of small dislocation loops and a fine body-centered-orthorhombic phase. The strengthening due to loops and precipitates was apparently offset in 625 by partial dissolution of #gamma# precipitates. Transmutation of boron to helium at grain boundaries, coupled with matrix strengthening, is believed to be responsible for IASCC in X-750, and the ...
1995-08-06
Investigation of a mineral melting cupola furnace. Part II. Mathematical modeling
Energy Technology Data Exchange (ETDEWEB)
A mathematical model of a mineral melting cupola furnace for stone wool production has been developed for improving cupola operation. The 1-D, first-engineering-principles model includes mass and heat balances for the gas phase, five solid phases, and four liquid phases. The gas and solid/liquid phases flow countercurrently. Seven chemical reactions account for the conversions of coke, iron oxide, limestone, and gaseous species. The heterogeneous reactions of coke conversion are limited by both kinetics and mass transport. Heat transfer between phases is modeled including both convection and radiation. The model predicts gas concentrations; mass flow rates; and temperature profiles of the solid, melt, and gas in the cupola, as well as heat loss to the water-cooled walls. Inputs to the model include the coke, rock, and blast air properties, the blast air amount, and the coke percentage in the charge. The unknown model parameters are estimated on ...
2003-12-24
Improvement of local air coolers model in ISAAC
Energy Technology Data Exchange (ETDEWEB)
The purpose of this paper is to assess a new local air coolers model in ISAAC 2.0, as ISAAC 1.0 could model local air coolers only at two locations. In the new model, local air coolers up to twelve locations could be handled. Large LOCA and loss of feed water sequences were selected for the model comparison. Two cases were analyzed with ISAAC 2.0: one with 6 local air coolers in one of the fueling machine room and in the steam generator room, respectively, and the other with 3 local air coolers at both fueling machine room and 6 local air coolers in the steam generator room. The study assumes that the safety systems such as emergency core cooling system, shield cooling system and moderator cooling system are unavailable. According to the ISAAC 2.0 results, the new local air coolers model showed almost no difference between two cases. Also it was found that as the location of LACs increased, the new model worked properly and the effect of LACs ...
2004-02-01
IAEA RESEARCH CONTRACTS SECOND ANNUAL REPORT. Technical Reports Series No. 9
Summaries are presented for those research contracts which expired between December 31, 1960 and December 31, 1981. Topics covered include: factors controlling distribution of fission products in biosphere, non-destructive methods of evaluating the U/sup 235/ and Pu content of irradiated fuel elements, studies of contamination in local marine resources, tracer studies of anemia, non-destructive analysis of irradiated fuel elements using a flux integrating monitor, mechanism of proteolysis of I/sup 131/-labeled fibrinogen, radiosensitivity of spermatogonia of Drosophila melel elements by gamma scanning, uptake and loss of radioactive material by marine bacteria, factors which influence the movement of radioactive strontium from soils to plants, biological concentration of fission products in mollusks from water, decay scheme of Tl/sup 210/, calcium balance in metabolic bone disease, development of radioactive drugs ...
1962-01-01
Energy Technology Data Exchange (ETDEWEB)
The poisoning effects of various trace contaminants in the coal-derived syngas stream at ppm and sub-ppm level on the performance of Ni-YSZ/YSZ/LSM solid oxide fuel cells were studied at extended duration. The thermochemical nature of impurities such as PH{sub 3}(g) and CH{sub 3}Cl(g) in presence and absence of water steam was analyzed by a high temperature mass spectrometer. Only less than half of PH{sub 3}(g) is hydrolyzed, and CH{sub 3}Cl(g) also co-exist with HCl(g). After a certain duration of exposure, 1 ppm AsH{sub 3}(g), 0.5 ppm PH{sub 3}(g), and 2.5 ppm CH{sub 3}Cl(g) all caused some degree of degradation to the power density at 750 C. Whereas 1 ppm of H{sub 2}S(g) resulted in immediate performance loss. The mechanisms of degradation are mainly divided into two categories: surface adsorption effect (for S and Cl) and bulk reaction effect (for As and P). The controversies regarding the poisoning effect and mechanism of S are also ...
2009-09-05
Development of radioisotope tracer technology
Energy Technology Data Exchange (ETDEWEB)
The purpose of this study is to develop the radioisotope tracer technology, which can be used in solving industrial and environmental problems and to build a strong tracer group to support the local industries. In relation to the tracer technology in 1999, experiments to estimate the efficiencies of a sludge digester of a waste water treatment plant and a submerged biological reactor of a dye industry were conducted. As a result, the tracer technology for optimization of facilities related to wastewater treatment has been developed and is believed to contribute to improve their operation efficiency. The quantification of the experimental result was attempted to improve the confidence of tracer technology by ECRIN program which basically uses the MCNP simulation principle. Using thin layer activation technique, wear of tappet shim was estimated. Thin layer surface of a tappet shim was irradiated by proton beam and the correlation between the measured activity ...
2000-04-01
Development of CANDU Void Reactivity Uncertainty Evaluation Methodology
International Nuclear Information System (INIS)
One of inherent characteristics of CANDU reactor is positive void reactivity in contrast to other pressurized light water reactors. During the large break loss of coolant accident, power pulse will be occurred during short time of early phase of accident due to positive void reactivity. However the duration of this power pulse is short, energy due to power pulse would be accumulated in the cladding material and will affect the peak cladding temperature or number of failed fuel elements. Recently, Canadian Nuclear Safety Commission (CNSC) indicated that the amount of void reactivity might be larger than the assumed values in safety analysis and this indication was based on the experimental data from ZED-2 facility. Based on that, the estimation of uncertainties due to the void reactivity during LBLOCA is the most important issue for CANDU safety analysis. In this study, a framework of uncertainty evaluation methodology for CANDU void reactivity ...
2010-10-01
Corrosion in drilling and well stimulation
Energy Technology Data Exchange (ETDEWEB)
Corrosion in drilling and well stimulation is described in relation to acid corrosion inhibition, acid inhibitors, acetylenic inhibitors, synergistic blends, metallurgy, wellbore tubulars, coiled tubing, and high alloy tubular materials. Acidizing is a procedure for stimulating oil and gas wells. Factors that have an important influence on the reaction rate and the way in which acid reacts with rock include temperature, acid concentration, acid volume, injection velocity, acid viscosity, and fluid loss properties of the formation. The cost of drill pipe failures are $1 per fot of hole drilled, which is a significant fraction of the drilling cost. Steps in a test procedure are listed, as well as factors which determine the extent of acid corrosion in a given situation including acid type and strength, metal type, temperature, contact time; pressure, and volume/surface area ratio. Underbalanced drilling is a method for completing oil and gas wells that minimizes the ...
1999-07-01
Copper sulfates as cathode materials for Li batteries
Energy Technology Data Exchange (ETDEWEB)
As lithium battery technology sets out to bridge the gap between portable electronics and the electrical automotive industry, cathode materials still stand as the bottleneck regarding performances. In the realm of highly attractive polyanion-type structures as high-voltage cathode materials, the sulfate group (SO{sub 4}){sup 2-} possesses an acknowledged superiority over other contenders in terms of open circuit voltage arising from the inductive effect of strong covalent S-O bonds. In parallel, novel lithium insertion mechanisms are providing alternatives to traditional intercalation, enabling reversible multi-electron processes securing high capacities. Combining both of these advantageous features, we report here the successful electrochemical reactivity of copper sulfate pentahydrate (CuSO{sub 4}.5H{sub 2}O) with respect to lithium insertion via a two-electron displacement reaction entailing the extrusion of metallic copper at a dual voltage of 3.2 V and 2.7 V followed by its ...
2011-02-01
Energy Technology Data Exchange (ETDEWEB)
Introduced herein is microwave irradiation for the adsorption and desorption of environmental pollutants. Microwaves may be used in two ways, other than through elevation of temperature of a system as a whole with the adsorbent such as activated carbon serving as the heating medium. The first is the application by which desorption is caused to take place of specified molecules. For example, zeolite that has adsorbed water is regenerated when it is irradiated with microwaves in a stream of cooling gas. This is because only the moisture is heated since zeolite is a non-carbon adsorbent that absorbs microwaves but a little. Another case is reported in which microwaves are utilized to desorb H2S, H2O, CO, etc., from molecular sieves. In the second application, coexisting materials different in absorptivity are exposed to irradiation. The adsorption of microwave-absorbent materials is inhibited while that of the others is accelerated. For example, the adsorption of ...
1997-01-25
Constant-pressure charging of a liquid-dominated geothermal reservoir
Energy Technology Data Exchange (ETDEWEB)
A two-dimensional mathematical model of a fault controlled geothermal reservoir has been developed. Heated water rising in a fault is assumed to charge a reservoir which is overlain by a thin impermeable, thermally conducting cap rock. The mass flow rate or the pressure associated with the charging process at the fault inlet is unknown and can only be estimated. Thus, the pressure in the fault at the bottom of the reservoir is assumed to be prescribed. Quasi-analytic solutions for the distributions of velocity, pressure, and temperature are obtained in the fault-reservoir system for high Rayleigh number flow. In this approximation, the upwelling fluid does not cool off appreciably until it reaches the cold upper boundary of the reservoir and encounters conductive heat loss. The thermal boundary layer, which is thin at the top of the fault, grows outward laterally and occupies the full thickness of the aquifer in the far-field. This study shows ...
1982-03-01
Conforth Ranch Wildlife Mitigation Feasibility Study, McNary, Oregon : Annual Report.
Energy Technology Data Exchange (ETDEWEB)
The 2,860-acre Conforth Ranch near Umatilla, Oregon is being considered for acquisition and management to partially mitigate wildlife losses associated with McNary Hydroelectric Project. The Habitat Evaluation Procedures (HEP) estimated that management for wildlife would result in habitat unit gains of 519 for meadowlark, 420 for quail, 431 for mallard, 466 for Canada goose, 405 for mink, 49 for downy woodpecker, 172 for yellow warbler, and 34 for spotted sandpiper. This amounts to a total combined gain of 2,495 habitat units -- a 110 percent increase over the existing values for these species combined of 2,274 habitat units. Current water delivery costs, estimated at $50,000 per year, are expected to increase to $125,000 per year. A survey of local interest indicated a majority of respondents favored the concept with a minority opposed. No contaminants that would preclude the Fish and Wildlife Service from agreeing to accept the property were ...
1991-03-01
CATHENA simulation of the WOLSUNG D_20 spill incident of 1984 November 25
International Nuclear Information System (INIS)
The CATHENA (formerly ATHENA) has been used to simulate the thermalhydraulic behaviour of the WOLSUNG-1 CANDU-600 reactor during the D_20 spill incident of 1984 November 25. A 4-inch (nominal) Liquid Relief Valve inadvertently opened in the reactor auxiliary system during normal reactor operation, resulting in a discharge of heavy water from the primary heat transport system. The valve remained open for approximately 29 minutes. CATHENA is an advanced thermalhydraulic computer code for analysis of postulated loss-of-coolant accidents (LOCA) and transient faults in CANDU nuclear reactors. A full two-fluid (six-equation) representation of the two-phase flow is used. Component models are used to represent pumps, valves, critical discharge, etc., which are necessary to describe the behaviour of the CANDU system under upset conditions. Heat transfer between the fluid and piping walls (or fuel) is modelled using applicable correlations for boiling, ...
1986-06-09
Energy Technology Data Exchange (ETDEWEB)
A 4-loop Pressurised Water Reactor (PWR) primary coolant system has been analysed for the postulated Loss of Coolant Accident (LOCA) event in order to derive peak dynamic loads for qualifying the design of equipment supports and pipe whip restraints. Pipe whip restraints as well as pipe and equipment supports are nonlinear by nature because of the presence of gaps and the different directional stiffnesses arising from snubber, steelwork and geometric and material interaction at the concrete to steel embedment. The different structural idealisations for the supports and restraints have an influence on the dynamic response of the structure. In the first of the two part paper a range of idealisation models for the Steam Generator and Reactor Coolant Pump vertical columns ranging from elastic stiffnesses to bilinear stiffnesses with or without preload were examined. Due to both structural and loading complexity, the behaviour of these supports were ...
1993-07-01
BWNT assessment of TRAC/PF1-MOD2
International Nuclear Information System (INIS)
The TRAC/PFI-MOD2 Version 5.3 code was assessed against six FLECHT-SEASET forced reflood tests (31504, 31203, 31302, 31701, 34209, and 31922) and two cylindrical core test facility (CCTF) tests [C1-19 and C2-6]. The objective of this study was to evaluate the clad thermal response predictive capabilities of the code with the newly added reflood model under large-break loss-of-coolant accident (LOCA) conditions in a pressurized water reactor (PWR). The TRAC model for the FLECHT-SEASET test facility was developed from a RELAP5 model. The test section was modeled using a vessel component with 23 axial levels, 1 radial ring, and 1 azimuthal cell. Test inlet and exit conditions were modeled using fill and break components, respectively. The measured lower and upper plenum test conditions were input to the model. The electrically heated rod was modeled using a rod component with 22 axial mesh points. The axial boundary of each mesh point coincided ...
1993-11-14
Analysis of natural convection in narrow annular gaps of LMFBR
International Nuclear Information System (INIS)
The natural convection characteristics of gas in a vertical narrow annular gap which had its bottom opened to high temperature fluid and its upper shielding exposed to low temperature sealant have been evaluated from simulated fluid experiments using water and from calculations using the three-dimensional thermal hydraulic analysis computer code THERVIS-III. The following results were obtained: (1) The critical Rayleigh number which represented the limit of convection generation increased as the aspect ratios #epsilon#_1 (height/circumference) and #epsilon#_2 (height/gap distance) increased. (2) The flow pattern along the circumferential direction was seen to depend more strongly on the radiant heat from the side wall, rather than the aspect ratios #epsilon#_1 and #epsilon#_2. (3) The temperature difference along the circumferential direction in the annular gap obtained from the calculation code coincided with that obtained from experiments within #+-# 10 %, by ...
Geochemical and petrographic properties of some Spitsbergen coals and dispersed organic matter
Energy Technology Data Exchange (ETDEWEB)
This paper presents the characteristics of selected parameters of organic matter of the Tertiary coal samples and organic matter of Carboniferous rock samples from the Spitsbergen. The coal samples were taken from Central Coal Basin (the Longyearbyen region) and from the Forlandsundet Basin (Oscar II Land, the Kaffioyra region). Samples of dispersed organic matter were collected from Suffolk Pynten and Sergeijevfjellet area in Sorkapp Land. The optical properties of coal samples are different from properties of dispersed organic matter. Macerals of vitrinite group dominate in all of the samples. The average content of vitrinite group macerals is much lower in dipersed organic matter samples than it is in coals. The average content of liptinite group macerals is a little lower, and inertinite group macerals is much higher. The average content of mineral matter is higher in organic matter samples than in coal samples. The average value of vitrinite reflectance and standard deviation of ...
2004-02-20
One of the more-serious side effects of extended space flight is an accelerated bone loss
2004-01-01
UK PubMed Central (United Kingdom)
Using QCT, we made a longitudinal, population-based assessment of rates of bone loss over life at the distal radius, distal tibia, and lumbar spine. Cortical bone loss began in perimenopause in women...Full Text Available
2008-02-01
International Nuclear Information System (INIS)
The feasibility of immobilizing simulated radioactive slurry (SRS) by alkali-activated slag---clay minerals composite cement (AASCM) was studied under the experimental conditions. The results show that the dosage of SRS and water cement ratio (W/C) have significant effect on the flowability of the mixture of AASCM and SRS. The more dosage of SRS, the lower flowability. When cement/sand ratio is 1: 1 and W/C is 0.45, the flowability of the mixture meets the case of solidification engineering and the compressive strength of the waste forms containing 20% SRS meets the needs of GB 14569.1-93. The setting time of the mixture of AASCM and SRS is highly dependent on temperature while sorts of anions have little influence on it. The application of AASCM is suitable below 20 degree C. The leaching resistance of AASCM based waste forms is superior to that of OPC based waste forms. The control of the ...
2006-03-01
Mass-loss in 2D zero-age main-sequence stellar models
British Library Electronic Table of Contents (United Kingdom)
Abstract A large number of massive stars are known to rotate rapidly, resulting in a significant distortion and variation in surface temperature from the pole to the equator. Radiatively driven mass-loss is temperature-dependent, so rapid rotation produces a variation in the mass-loss and angular momentum loss rates across the surface of the star, which is expected to affect the evolution of rapidly rotating massive stars. In this work, we use zero-age main-sequence (ZAMS) stellar models to investigate the two-dimensional effects of rotation on stellar mass-loss, using two common prescriptions for radiatively driven mass-loss. The associated loss of angular momentum from these models is also considered. Using 2D stellar models, which give the variation in surface parameters as a function o...
2011-01-01
Fast PIN-diode beam loss monitors at Tevatron
Energy Technology Data Exchange (ETDEWEB)
The article is devoted to results of fine time structure of particle losses in Tevatron with use of fast beam loss monitors (BLM) based on PIN-diodes. An ultimate goal of the new BLMs is to distinguish losses of protons and antiprotons from neighbor bunches with 132 ns bunch spacing in the Tevatron collider upgrade. The devices studied fit well to the goal as they can recognize even seven times closer - 18.9 ns - spaced bunches` losses in the Tevatron fixed target operation regime. We have measured main characteristics of the BLM as well as studied the proton losses over 10 decades of time scale - from dozen of minutes to dozen of nanoseconds. Power spectral density of the losses is compared with spectra of the proton beam motion.
1997-07-01
A Network Coding Approach to Loss Tomography
Network tomography aims at inferring internal network characteristics based on measurements at the edge of the network. In loss tomography, in particular, the characteristic of interest is the loss rate of individual links. There is a significant body of work dedicated to this problem using multicast and/or unicast end-to-end probes. Independently, recent advances in network coding have shown that there are several advantages from allowing intermediate nodes to process and combine, in addition to just forward, packets. In this paper, we pose the problem of loss tomography in networks that have network coding capabilities. We design a framework for estimating link loss rates, which leverages network coding capabilities and we show that it improves several aspects of tomography, including the identifiability of links, the tradeoff between estimation accuracy and bandwidth efficiency, and the complexity of ...
2010-01-01
International Nuclear Information System (INIS)
The construction materials used in coolant systems in nuclear power plants become covered with oxide films as a result of exposure to the aqueous environment. The susceptibility of the materials to different forms of corrosion, as well as the extent of the incorporation of radioactive species on the surfaces of the primary circuit, are greatly influenced by the physical and chemical properties of these oxide films. The composition and characteristics of the oxide films in turn depend on the applied water chemistry. This work was undertaken in order to collect and evaluate the present views on the structure and behaviour of oxide films formed on iron- and nickel-based materials in aqueous environments. This survey should serve to recognise the areas in which more understanding and research effort is needed. The review begins with a discussion on the bulk oxides of iron, nickel and chromium, as well as their mixed oxides. In ...
2010-03-01
Effect of water chemistry improvement on flow accelerated corrosion in light-water nuclear reactor
International Nuclear Information System (INIS)
Flow Accelerated Corrosion (FAC) of Carbon Steel (CS) piping has been one of main issues in Light-Water Nuclear Reactor (LWRs). Wall thinning of CS piping due to FAC increases potential risk of pipe rupture and cost for inspection and replacement of damaged pipes. In particular, corrosion products generated by FAC of CS piping brought steam generator (SG) tube corrosion and degradation of thermal performance, when it intruded and accumulated in secondary side of PWR. To preserve SG integrity by suppressing the corrosion of CS, High-AVT chemistry (Feedwater pH9.8#+-#0.2) has been adopted to Tsuruga-2 (1160 MWe PWR, commercial operation in 1987) in July 2005 instead of conventional Low-AVT chemistry (Feedwater pH 9.3). By the High-AVT adoption, the accumulation rate of iron in SG was reduced to one-quarter of that under conventional Low-AVT. As a result, a tendency to degradation of the SG thermal efficiency was improved. On the other hand, it was clarified that ...
2009-10-01
Interaction of antimicrobial peptides with lipid membranes
International Nuclear Information System (INIS)
This study aims to investigate the difference in the interaction of antimicrobial peptides with two classes of zwitterionic peptides, phosphatidylethanolamines (PE) and phosphatidylcholines (PC). Further experiments were performed on model membranes prepared from specific bacterial lipids, lipopolysaccharides (LPS) isolated from Salmonella minnesota. The structure of the lipid-peptide aqueous dispersions was studied by small-and wide-angle X-ray diffraction during heating and cooling from 5 to 85 C. The lipids and peptides were mixed at lipid-to-peptide ratios 10-10000 (POPE and POPC) or 2-50 (LPS). All experiments were performed at synchrotron soft condensed matter beamline A2 in Hasylab at Desy in Hamburg, Germany. The phases were identified and the lattice parameters were calculated. Alamethicin and melittin interact in similar ways with the lipids. Pure POPC forms only lamellar phases. POPE forms lamellar phases at low temperatures that ...
Energy Technology Data Exchange (ETDEWEB)
{sup 60}Co is produced as an activation product and is present in the low-level aqueous radioactive waste released from the La Hague plant. At present, the concentration in the sea (non filtered at 0.45 {mu}m) at the Goury site are close to or even below, the detection limit: 0.2 mBq.l{sup -1}. The {sup 60}Co speciation depends on the type of effluent considered: in the effluent A ('active'), the cobalt is in the form of a stable trivalent complex; in the effluent V (to be checked), the cobalt is in majority (50% of the activity release) in the form of particles (>0.45 {mu}m), and then in the form of two soluble species: ionic divalent (Co{sup 2+}) and some stable complexes. The evolution of the reprocessing techniques used does not affect the speciation. So, since the nuclear reprocessing plant started at the La Hague plant in 1966, the chemical species discharged in the sea shows time variation ...
1999-07-01
Spatial structure of compound dither in L/H transition
Energy Technology Data Exchange (ETDEWEB)
To study the plasma evolution and spatial structure at the L/H transition, the double hysteresis is examined by use of the 1-dimensional transport model equations. Three mechanisms for the bipolar losses, i.e., the loss cone loss, collisional bulk viscosity loss of ions and the anomalous loss are simultaneously retained. Five-fold multiple bifurcations are found to exist at the plasma edge, similar to the previous 0-dimensional study. Double hysteresis causes a self-generated oscillation, which is attributed to the compound dither, a kind of ELMs. Spatio-temporal evolution of the compound dither is analyzed. (author)
2000-03-01
Mira variables - Pulsation, mass loss and evolution
International Nuclear Information System (INIS)
Recent developments in the analysis of Mira atmosphere, the determination of the pulsation mode, the problem of mass loss, and the evolution of the Mira variables are covered. Model atmospheres for Mira variables, including the opacities of the molecules expected in very late M-type atmospheres are discussed. The pulsation constant for Omicron Ceti is evaluated using T(eff) = 2900 + or - 200 K, and it is concluded that Miras are fundamental mode pulsators. The importance of molecular opacity to the driving of mass loss is evaluated, and it is pointed out that the radiation pressure on molecules is not a major factor in driving mass loss from Mira. Mass loss is considered as a factor in the calculations of the periods for Mira variables. 30 refs.
1990-05-28
An analysis of convective losses from cavity solar central receivers
Energy Technology Data Exchange (ETDEWEB)
A simple analytical model has been developed in order to provide a framework for designing experimental programs for convective loss determinations, for analyzing available experimental data from solar receiver test programs, and for estimating the convective loss at a relatively small cost. Analytical results and experimental evidence indicate that the convective loss from cavity receivers is appreciable, while the effects of wind on the convective loss under normal operating conditions are minimal. The proposed analytical model provides a means of determining the relative importance of the internal resistances and predicting the bulk air temperature within the convective zone inside the cavity.
1981-01-01
Energy Technology Data Exchange (ETDEWEB)
Dissolved humic substances (humic and fulvic acids) occur in surface waters and groundwaters in concentrations ranging from less than 1 mg(C)/L to more than 100 mg(C)/L. Humic substances are strong complexing agents for many trace metals in the environment and are also capable of forming stable soluble complexes or chelates with radionuclides. Concentrations of humic materials as low as 1 mg(C)/L can produce a detectable increase in the mobility of some actinide elements by forming soluble complexes that inhibit sorption of the radionuclides onto rock materials. The stability of trace metal- or radionuclide-organic complexes is commonly measured by an empirically determined conditional stability constant (K'), which is based on the ratio of complexed metal (radionuclide) in solution to the product concentration of uncomplexed metal and humic complexant. Larger values of stability constants indicate greater complex ...
1985-07-01
Formation of silk fibroin nanoparticles in water-miscible organic solvent and their characterization
Energy Technology Data Exchange (ETDEWEB)
When Silk fibre derived from Bombyx mori, a native biopolymer, was dissolved in highly concentrated neutral salts such as CaCl{sub 2}, the regenerated liquid silk, a gradually degraded peptide mixture of silk fibroin, could be obtained. The silk fibroin nanoparticles were prepared rapidly from the liquid silk by using water-miscible protonic and polar aprotonic organic solvents. The nanoparticles are insoluble but well dispersed and stable in aqueous solution and are globular particles with a range of 35-125 nm in diameter by means of TEM, SEM, AFM and laser sizer. Over one half of the {epsilon}-amino groups exist around the protein nanoparticles by using a trinitrobenzenesulfonic acid (TNBS) method. Raman spectra shows the tyrosine residues on the surface of the globules are more exposed than those on native silk fibers. The crystalline polymorph and conformation transition of the silk nanoparticles from random-coil and {alpha}-helix form ...
2007-10-15
Bitumen immobilization of aqueous radwaste by thin-film evaporation
International Nuclear Information System (INIS)
In the early 1980s, AECL built a Waste Treatment Centre (WTC) for managing low-level solid and aqueous liquid wastes for converting CANDU wastes. At present, two liquid waste streams are being treated at the WTC. The liquid waste streams are volume-reduced by a combination of continuous crossflow microfiltration (MF), spiral wound reverse osmosis (SWRO) and tubular reverse osmosis (TRO) membrane technologies. The concentrate produced from the TRO system and the volume-reduced MF backwash solutions are evaporated while simultaneously adding bitumen in a thin-film evaporator. A water-free product of chemical and radiochemical salts and bitumen is removed in 200-L galvanized steel drums for storage. The radiation field of product drums on contact typically has a value of 0.5 to 3 R/h depending upon the feed concentration of radioactivity to the evaporator. The total solids content in the 200-L drum ranges from 25 to 35%. Encapsulated in the bitumen matrix are a ...
1996-02-25
Tritium release from lithium orthosilicate pebbles deposited with palladium
International Nuclear Information System (INIS)
Full text of publication follows: Slightly over-stoichiometric lithium orthosilicate pebbles have been selected as one optional breeder material for the European Helium Cooled Pebble Bed (HCPB) blanket. This material has been developed in collaboration of Research Center Karlsruhe and the Schott Glass, Mainz. The lithium orthosilicate pebbles are fabricated from lithium hydroxide and silica by a melting and spraying method in a semi-industrial scale facility. Lithium hydroxide was selected as the precursor since enriched lithium hydroxide is commercially available. The lithium orthosilicate pebbles produced by the process contains oxide phases besides orthosilicate, but it was also found that the oxide phases can be decomposed by annealing at high temperatures. The lithium orthosilicate pebbles produced in this way possesses satisfactory pebble characteristics. Therefore, the authors performed out-of-pile annealing tests using the lithium orthosilicate pebbles irradiated in a research ...
2007-12-10
Water Quality Criteria | Water Quality Criteria | US EPA
for? Learn the Issues Science & Technology Laws & Regulations About EPA Contact Us Water: Water Quality Criteria You are here: Water Science & Technology Surface Water Standards &...
2011-08-28
Charts give vapor loss from internal floating-roof tanks
Energy Technology Data Exchange (ETDEWEB)
Nomographs have been constructed to estimate the average evaporation loss from internal floating-roof tanks. Loss determined from the charts can be used to evaluate the economics of seal conversion and to reconcile refinery, petrochemical plant, and storage terminal losses. The losses represent average standing losses only. They do not cover losses associated with the movement of product into or out of the tank. The average standing evaporation loss from an internal floating-roof tank depends on: vapor pressure of the product; type and condition of roof seal; tank diameter; and type of fixed roof support. The nomographs can estimate evaporation loss for product true vapor pressures (TVP) ranging from 1.5 to 14 psia, the most commonly used seals for average and tight fit conditions, tank diameters ranging from 50 to 250 ...
1987-03-09
Thermal wet oxidation of GaP and Al{sub 0.4}Ga{sub 0.6}P
Thermal wet oxidations of GaP and Al{sub 0.4}Ga{sub 0.6}P at 650 degree sign C for various times have been performed. Comparisons are made on oxidation rates and post oxidation morphology. Transmission electron microscopy shows that when oxidizing GaP, polycrystalline monoclinic GaPO{sub 4}{center_dot}2H{sub 2}O forms without noticeable loss of phosphorus. Oxidation for 6 h or more leads to poor morphology resulting in cracks and detachment. A thickness expansion of about 2.5-3 times is noticed as a result of oxidation. In contrast, oxidized Al{sub 0.4}Ga{sub 0.6}P exhibits much better morphology without cracks or detachment from the substrate. The oxide has an almost amorphous-like microstructure. The oxidation process shows typical diffusion-limited reaction at long anneals. Preliminary work on the oxidation of AlP indicates that the reaction leads to formation of Al{sub 2}O{sub 3} and possible volatile P{sub 2}O{sub 5} diffusing out of the ...
2000-08-21
Late-onset Stargardt-like macular dystrophy maps to chromosome 1p13
Energy Technology Data Exchange (ETDEWEB)
Stargardt`s disease (MIM 248200), originally described in 1909, is an autosomal recessive condition of childhood, characterized by a sudden and bilateral loss of central vision. Typically, it has an early onset (7 to 12 years), a rapidly progressive course and a poor final outcome. The central area of the retina (macula) displays pigmentary changes in a ring form with depigmentation and atrophy of the retinal pigmentary epithelium (RPE). Perimacular yellowish spots, termed fundus flavimaculatus, are observed in a high percentage of patients. We have recently reported the genetic mapping of Stargardt`s disease to chromosome 1p13. On the other hand, considering that fundus flavimaculatus (MIM 230100) is another form of fleck fundus disease, with a Stargardt-like retinal aspect but with a late-onset and a more progressive course, we decided to test the hypothesis of allelism between typical Stargardt`s disease and late-onset ...
1994-09-01
Key impact parameters for application of alternative source term to Kori unit 1
International Nuclear Information System (INIS)
The object of this paper is to identify the key elements that impact a radiation dose at EAB (Exclusion Area Boundary). This study is based on the AST (Alternative Source Terms) as defined in Regulatory Guide 1.183. The LOCA (Loss of Coolant Accident) and the LRA (Locked Rotor Accident) are selected as limiting cases. A sensitivity analysis of accidental behavior with respect to various parameters during LOCA and LRA at Kori Unit 1 is also undertaken for the following objectives: to determine the limiting parameters, to find the impact trend of the radiation dose, and to find the safety margin between AST and TID (Technical Information Document) methodologies. This work confirms that key parameters are particulate removal rate, decontamination factor, iodine chemical form, gap fraction, partitioning factor, and the impact of isotopes group. Comparing TID with AST, the radiation dose of TID is about 80% greater than that of AST under a LOCA, and ...
2010-08-01
HEMATOLOGICAL MALIGNANCIES IN HUMANS TYPICALLY INVOLVE TWO TYPES OF GENETIC CHANGES: those that promote hematopoietic cell proliferation and survival (often the result of activation of tyrosine kinases) and those that impair hematopoietic cell differentiation (often the result of changes in transcription factors). The multi-stage erythroleukemia induced in mice by Friend spleen focus-forming virus (SFFV) is an excellent animal model for studying the molecular basis for both of these changes. Significant progress has been made in understanding the molecular basis for the multi-stage erythroleukemia induced by Friend SFFV. In the first stage of leukemia, the envelope protein encoded by SFFV interacts with and activates the erythropoietin (Epo) receptor and the receptor tyrosine kinase sf-Stk in erythroid cells, causing their Epo-independent proliferation, differentiation and survival. In the second stage, SFFV integration into the Sfpi1 locus activates the myeloid ...
2010-10-11
Appendix W: deep sea biophysics (microbiology and amphiped studies)
International Nuclear Information System (INIS)
CNPT-3 is the laboratory designation of a strain of bacteria that reproduces best at deep-sea pressures. It was isolated from a sample collected at a 5800 m depth of the Pacific Ocean. This isolation was achieved from a sample that had been retrieved without warning. This year we demonstrated that there are similarly behaving bacteria that can be isolated from samples even when retrieved with decompression. The purpose of this project was to define the temperatures and pressures over which CNPT-3 can exist and function. (1) At 2"0C CNPT-3 is eurybathic from about 1000 to 6500 m, as judged from an only slightly pressure dependent generation time. (2) CNPT-3 is unquestionably barophilic at 2"0C, with doubling times of 9 hours at 580 bars and over 18 hours at 1 bar. (3) At 10"0C, reproduction is adversely affected at 1 bar to the extent that CNPT-3 becomes obligately barophilic at 10"0C. Yet reproduction is enhanced above 280 bars and occurs with a regeneration time of 4 hours at 690 bars ...
1981-04-01
Refining the Magnetic Forming Capability.
... Title : Refining the Magnetic Forming Capability. ... Abstract : The purpose of this project was to refine the in-house magnetic forming capability. ...
1972-04-01
CAPACITOR DISCHARGE METAL FORMING
... Report Date : JUL 1961. Pagination or Media Count : 39. Abstract : Open-ende Terms: Electrohydraulic forming, Magnetic forming. ...
1961-07-01
An investigation of the decoupling effects in a magnetic forming beryllium coil assembly.
Decoupling force exerted by magnetic forming Be coil assembly on metallic plate during forming
1968-01-01
/22k : - NASA Technical Reports Server
in pulse applications such as magnetic forming. ... In magnetic-forming electric circuitry, the ..... Aspects of Electrohydraulic land Magnetic Forming. ...
Isothermal heat measurements of TBP-nitric acid solutions
Energy Technology Data Exchange (ETDEWEB)
Net heats of reaction were measured in an isothermal calorimeter for both single phase (organic) and two phase (organic and aqueous) TBP/HNO{sub 3} reacting solutions at temperatures above 100 C. The oxidation rate constant was determined to be 5.4E-4 min{sup {minus}1} at 110 C for an open ``vented`` system as compared to 1.33 E-3 min{sup {minus}1} in the closed system. The heat released per unit material oxidized was also reduced. The oxidation in both phases was found to be first order in nitric acid and pseudo-zero order in butylnitrate and water. The hydrolysis (esterification) rate constant determined by Nichols` (1.33E-3 min{sup {minus}1}) fit the experimental data from this work well. Forced evaporation of the volatile components by the product gases from oxidation resulted in a cooling mechanism which more than balanced the heat from the oxidation reaction in the two-phased systems. Rate expressions were derived and rate constants determined for both the ...
1994-12-16
Energy Technology Data Exchange (ETDEWEB)
The procedure for field corrosion tests in sea water is decribed in DIN 50 917, Part II. Distinction is made thereby between long-term undisturbed test specimens, which remain at the exposure site up to the time of sampling, and disturbed test specimens, which are cleaned at certain time intervals for intermediate examination and subsequently exposed again. The comparability of results obtained with the two different types of test was to be investigated at the Helgoland test installation. At an exposure period of up to four years, undisturbed specimens of unalloyed and low-alloy steel grades feature considerably lower corrosion losses than disturbed specimens. At a longer exposure period of up to seven years, the corrosion rate can increase substantially again with the exposure time. This can be attributed to sulphate reduction in the anaerobic zone under the top coating. An effect of the alloying elements is also possible. With good and ...
1990-09-14
Climate change, agriculture and wetlands in Eastern Europe: vulnerability, adaptation and policy
Energy Technology Data Exchange (ETDEWEB)
Naturally-occurring wetlands perform such functions as flood control, pollution filtration, nutrient recycling, sediment accretion, groundwater recharge and water supply, erosion control, and plant and wildlife preservation. A large concentration of wetlands is located in Eastern Europe. A significant amount of Eastern European wetlands has been converted to agricultural use in the past, and remaining wetlands are subject to agricultural drainage. Drained wetlands are used as prime agriculture lands for a variety of food crops. Other agricultural uses of wetlands range from growing Phragmites australis (common reed) for thatch and livestock feed, to collecting peat for heating and cooking fuel. Altered hydrologic regimes due to global climate change could further exacerbate encroachment of agricultural land use into wetlands. The vulnerability and adaptation studies of the US Country Studies Program are used to analyze where climate change impacts to agriculture ...
1997-05-01
Energy Technology Data Exchange (ETDEWEB)
A membrane process utilizing dialysis and selective complexation by water-soluble polymers has been developed. This process, termed affinity dialysis, has been shown to be selectively extract and concentrate both cations and anions in a manner similar to ion exchange or solvent extraction. The selective removal of calcium from sodium with selectivity of about 30, removal of chromate ion from dilute streams, and separation of transition metal ions such as Cu/Fe and Cu/Zn have all been successfully demonstrated. Effects of different polymers, polymer concentration, temperature, and flow rates have been studied. The effect of increased polymer concentration is to increase product concentration if appropriate changes in feed, polymer solution, and strip flow rates are made. A continuous polymer solution recycle and regeneration system has been constructed and operated with Cu/Zn and chromate/chloride feed streams. Removal of over 95% of the desired ion in one pass and ...
1988-08-01
International Nuclear Information System (INIS)
... thermal power plants thermal reactors water cooled reactors WATER
Some applications of nuclear techniques in hydrology and water pollution studies in Norway
International Nuclear Information System (INIS)
... hydrology norway water pollution pollution scandinavia surface waters
Workshop on stems and trunks in plant form and function. Final report
Energy Technology Data Exchange (ETDEWEB)
This document is the final report on the workshop on stems and trunks in plant form and function relating to DOE grant DE-FG06-93ER20128 which took place at Oregon State University in February 1994. The resulting book is organized into four sections and a synthesis: roles of stem architecture in plant performance, roles of stems in transport and storage of water, roles of live stem cells in plant performance, and the roles of stems in preventing or reacting to response to plant injury. The synthesis stemmed from debated and discussion by the authors and a few dozen other workshop participants. The authors cover many stem functions, although the list is not exhaustive, and the focus is on terrestrial woody tree stems, primarily of temperate and boreal zones. More research on trunks, branches and twigs is important for a baseline understanding of plant biology. In the face of anticipated human-caused changes to most environments, we need not only ...
1995-03-01
Energy Technology Data Exchange (ETDEWEB)
One of the main problems facing the mining sector is the production of acid mine drainage (AMD), which is caused by the oxidation of sulphide minerals in the presence of water. AMD can have a detrimental effect on the environment. One solution is to use soil covering over the materials that cause acid to limit the gas flux by diffusion. A capillary barrier effect is generated by using various layers of different types of soil. In the composite system till and clay normally form the basis of the fine material layer. The use of low sulphide tailings to replace the use of fine grained soil was studied to evaluate its effectiveness. Following both in situ and laboratory experiments spread over an eight-year period, the results indicated that an effective method to limit the oxygen flux and generation of AMD is the use of non-acid generating tailings as the moisture retaining layer. The main concepts that form the basis of the ...
2000-07-01
Radionuclide release rates from spent fuel for performance assessment modeling
Energy Technology Data Exchange (ETDEWEB)
In a scenario of aqueous transport from a high-level radioactive waste repository, the concentration of radionuclides in water in contact with the waste constitutes the source term for transport models, and as such represents a fundamental component of all performance assessment models. Many laboratory experiments have been done to characterize release rates and understand processes influencing radionuclide release rates from irradiated nuclear fuel. Natural analogues of these waste forms have been studied to obtain information regarding the long-term stability of potential waste forms in complex natural systems. This information from diverse sources must be brought together to develop and defend methods used to define source terms for performance assessment models. In this manuscript examples of measures of radionuclide release rates from spent nuclear fuel or analogues of nuclear fuel are presented. Each example ...
1994-11-01
Processing method and processing facility for carbon steel parts in nuclear power plant
International Nuclear Information System (INIS)
In a closed circuit formed by bypassing pipelines connected to carbon steel parts, low oxygen coolants pass there through during operation. A solution containing ions of metals more noble than iron are circulated to bring the solution into contact with the carbon steel surface of the inner wall of the parts to form a deposition membrane of the metal more noble than iron on the surface to prevent acceleration of corrosion of the carbon steel parts due to low oxygen coolants. The solution containing ions of metals more noble than iron is a solution of palladium nitrate containing ions of platinum elements. This operation is conducted under a temperature condition of from 50degC to 150degC. In addition, the metal ion concentration of the solution circulating in the closed circuit is measured, it is compared with metal ion concentration previously determined, and the results are feed back to a means for controlling water ...
1996-11-27
Potential biogas scrubbing using a high rate pond
Energy Technology Data Exchange (ETDEWEB)
The potential to scrub biogas in a high rate pond (HRP) was evaluated using apparatus designed to maximize gas-liquid contact. Experiments compared the removal of carbon dioxide from synthetic biogas by an 'in-pond angled gutter' to that by a simulated 'counter-current pit'. Results showed that the counter current pit has potential for use in biogas scrubbing, with synthetic biogas carbon dioxide composition consistently reduced from 40% to<5%. The in-pond angled gutter was less effective due to bubble coalescence which reduced the total bubble surface surface area available for gas transfer. Measurement of oxygen levels in the scrubbed biogas showed that despite supersaturation of oxygen in the HRP water, there was little transfer to the biogas, so that explosive methane/oxygen mixtures would not be formed. Theoretical calculations indicated that the amount of biogas likely to be ...
2005-07-01
Energy Technology Data Exchange (ETDEWEB)
Considerations were given on typical applications of nylon resin parts to automotive use and their future trends through news topics. GF strengthened nylon resin is used in cylinder head covers substituting aluminum because of advantages in nylon resin of weight reducibility, vibration suppressibility, and noise shielding capability. Radiator tank uses N66GF 30% strengthened nylon in more than 60% of bonnet type passenger cars. Nylon resin is used most in harness connectors installed in locations that require heat resistance. External car parts such as bumpers, fenders, and wheel caps use to some extent nylon resin in the form of strengthened and up-graded polymer alloy. BMW in Germany used in its high-class production cars intake manifolds made of GF strengthened Nylon 66. The majority of engine{prime}s gas intake system parts has been replaced with Nylon blow-formed parts. The resin industry is aiming at developing Nylon resin with aromatic ...
1992-06-18
Energy Technology Data Exchange (ETDEWEB)
Oxygenated sterol compounds (OSC), when incubated for 1 hr with human erythrocytes in lipoprotein-depleted medium at concentrations of 0.625-5 x 10/sup -5/M, are inserted into the cell membrane and remain there despite subsequent washing of the cells. The insertion results in expansion of the surface area of the red cell ghost membrane, an increase in critical hemolytic volume, and as a consequence, in dimished osmotic fragility of the erythrocytes. This effect is seen with echinocyte-forming as well as with non-echinocyte-forming OSC. Erythrocytes treated with OSC do not differ from control cells with respect to their mean cell volume (MCV) in isotonic solution, water content, ion fluxes, and filterability through polycarbonate filters. The shift of the osmotic fragility curve toward lower NaCl concentrations is proportional to the amount of OSC inserted into the red cell membrane. 7BETA-Hydroxycholesterol, ...
1981-08-01
British Library Electronic Table of Contents (United Kingdom)
We performed experimental studies on the convolution/superposition method reported in the former companion paper (Iwasaki in Radiol Phys Technol 4, 2011) using 10-MV X-ray beams from open-jaw-collimated fields. The method uses primary and scatter dose kernels formed for energy bins of X-ray spectra reconstructed as a function of off-axis distance. We made a comparison of calculations and measurements in water phantoms and thorax-like phantoms with respect to percentage depth dose curves, tissue???phantom ratio curves, and dose profiles. We made the dose calculation by taking into account the beam-hardening effect with depth and the off-axis radiation-softening effect. We found that the method could be used, in general, for performing accurate dose calculations.
2011-01-01
Transportation energy data book: Edition 12
Energy Technology Data Exchange (ETDEWEB)
The Transportation Energy Data Book: Edition 12 is a statistical compendium prepared and published by Oak Ridge National Laboratory under contract with the Office of Transportation Technologies in the Department of Energy. Designed for use as a desk-top reference, the data book represents an assembly and display of statistics and information that characterize transportation activity, and presents data on other factors that influence transportation energy use. The purpose of this document is to present relevant statistical data in the form of tables and graphs. Each of the major transportation modes--highway, air, water, rail, pipeline--is treated in separate chapters or sections. Chapter 1 compares US transportation data with data from seven other countries. Aggregate energy use and energy supply data for all modes are presented in Chapter 2. The highway mode, which accounts for over three-fourths of total transportation energy consumption, is ...
1992-03-01
Project reveals CO/sub 2/ confinement problems
Energy Technology Data Exchange (ETDEWEB)
The results of the liquid CO/sub 2/ injection pilots in the Granny's Creek field permit the following findings and conclusions: The pilots demonstrated that CO/sub 2/ can be used for tertiary recovery, and it will displace oil and form a high oil-cut bank in a watered-out reservoir. Oil production response in every case was almost immediate; and after CO/sub 2/ injection was stopped and water injection was started, the oil production declined rapidly over a period of 2-3 months to very low rates. Confinement of CO/sub 2/ to the pilot area was the principal problem. CO/sub 2/ spread rapidly to virtually all of the southern part of the reservoir of about 350 acres. Except for weather, there were practically no operational problems. Corrosion from the CO/sub 2/ was not observed. Pilot results did not demonstrate economic feasibility. The ratio of CO/sub 2/ to additional oil of 19,357 cu ft (14.696 psia and 60/sup 0/ ...
1983-01-24
Mine waste disposal and managements
Energy Technology Data Exchange (ETDEWEB)
Acid Rock Drainage (ARD) is the product formed by the atmospheric oxidation of the relatively common pyrite and pyrrhotite. Waste rock dumps and tailings containing sulfide mineral have been reported at toxic materials producing ARD. Mining in sulphide bearing rock is one of activity which may lead to generation and release of ARD. ARD has had some major detrimental affects on mining areas. The purpose of this study was carried out to develop disposal method for preventing contamination of water and soil environment by waste rocks dump and tailings, which could discharge the acid drainage with high level of metals. Scope of this study was as following: environmental impacts by mine wastes, geochemical characteristics such as metal speciation, acid potential and paste pH of mine wastes, interpretation of occurrence of ARD underneath tailings impoundment, analysis of slope stability of tailings dam etc. The following procedures were used as part ...
1998-12-01
Fuel assembly and reactor core
International Nuclear Information System (INIS)
In a fuel assembly having moderator rods, an axial average value of a ratio between the total of the lateral cross sectional area of a portion to be filled with moderators and the total of the lateral cross sectional area of fuel pellets is determined as greater than 0.4, a lateral cross sectional area of a portion to be filled with moderators per one moderator rod is determined as from 14 to 50cm"2 and the ratio between the total of the lateral cross sectional area of moderators and a total of the lateral cross sectional area of fuel pellets in a horizontal cross section is determined as from 2.7 to 3.4. Since the axial average value for lateral cross sectional area of a portion to be filled with moderators/lateral cross sectional area of fuel pellets is determined as #>=# 0.4, the lateral cross sectional area of moderators of moderator rods is increased, the lateral cross sectional area of a gap water region is decreased to reduce the value of local power ...
1992-12-03
International Nuclear Information System (INIS)
Purpose: To effectively cool the reactor core in a steam atmosphere by upwardly directing several of spray nozzles attached to a ring header thereby increasing the flying distance of the spray. Constitution: Ring headers in two upper and lower stages are disposed above the outer circumference of a reactor core and each of the ring headers is mounted with spray nozzles. Among the spray nozzles, at least several nozzles mounted to the ring header at the lower stage are directed such that the center axis for each of the nozzle is raised above the horizontal axis and other several nozzles are mounted with the nozzle center axis directed downwardly from the horizontal axis. Accordingly, even if collapsing phenomenon occurs in the jetting stream due to the condensation in the steams that forms the operation atmosphere of the reactor core spray cooling device, a sufficient amount of emergency cooling water can be distributed over the entire reactor ...
1983-03-09
Electrochemical corrosion behavior of AZ91D alloy in ethylene glycol
Energy Technology Data Exchange (ETDEWEB)
The effect of concentration on the corrosion behavior of Mg-based alloy AZ91D was investigated in ethylene glycol-water solutions using electrochemical techniques i.e. potentiodynamic polarization, electrochemical impedance measurements (EIS) and surface examination via scanning electron microscope (SEM) technique. This can provide a basis for developing new coolants for magnesium alloy engine blocks. Corrosion behavior of AZ91D alloy by coolant is important in the automotive industry. It was found that the corrosion rate of AZ91D alloy decreased with increasing concentration of ethylene glycol. For AZ91D alloy in chloride >0.05 M or fluoride <0.05 M containing 30% ethylene glycol solution, they are more corrosive than the blank (30% ethylene glycol-70% water). However, at concentrations <0.05 for chloride or >0.05 M for fluoride containing ethylene glycol solution, some inhibition effect has been observed. The ...
2009-11-01
Effects of microwaves on the colony-forming capacity of haemopoietic stem cells in mice
Energy Technology Data Exchange (ETDEWEB)
A suspension of bone marrow cells from femurs of female (CBA . C57B1)F1 mice was exposed to 2450 MHz CW microwaves in a specially designed waveguide exposure system. The temperature of the suspension rose, during exposure to microwaves, from 20/sup 0/C to 45/sup 0/C, and at an interval within 20/sup 0/C to 45/sup 0/C the number of haemopoietic stem cells (CFUs) was determined by the spleen exocolony method. The time of exposure of bone marrow cells to each temperature studied was 20 s. Control suspensions of bone marrow cells were exposed to a water bath temperature. There were no significant effects of the CFUs with the water bath temperature, while after exposure to microwaves the number of spleen colonies was elevated with a nadir at the temperature of 37/sup 0/C. With a microwave-induced increase of the temperature above 41/sup 0/C the number of CFUs in the bone marrow suspension decreased. The increase in the number of colonies was related ...
1987-01-01
Energy Technology Data Exchange (ETDEWEB)
A patent is claimed for a direct coal liquefication process which is carried out by interaction with a paste, consisting of small-fragment coal, oil and catalysts, with H/sub 2/ at increased temperatures and pressures. The catalyst is a mixture of 1 part per weight of Fe-ore that's been activated by aqueous treatment, and 0.1-1.0 powder-form S. The Fe-ore can be magnetite, limonite, hematite, pyrite, ferrous sand or ''red mud'' (byproduct of the Bayer process), with the ''red mud'' and limonite, having a particle size of about 100 mesh is preferable. Activation of Fe-ore includes aqueous treatment in boiling water for 30-120 min with subsequent drying; annealing at a temp. of 300-700/sup 0/C for 10-120 min; submerging into cold water and final drying. The catalyst is added to the paste in the amount of 0.03-0.3 parts per weight to one part of ...
1982-06-22
Development of transition metal semiconductors for photoelectrolysis of water. Final report
Energy Technology Data Exchange (ETDEWEB)
This report discusses the development of transition metal oxide semiconductors for photoelectrolysis of water. More specifically, it involves preparation of TiO/sub 2/ films by sputtering and evaluating their physicochemical characteristics primarily as they relate to the behaviour of the films as photoanodes. Impedance, photoelectrochemical, and photoconduction properties of TiO/sub 2/ films sputtered in pure O/sub 2/ onto heated substrates have been determined as a function of O/sub 2/ pressure during sputtering, film thickness, Pt overcoating, and cathodic treatment. The capacitance data before cathodic treatment are of the form expected. The capacitance is essentially independent of potential, while for potentials increasingly cathodic of this value, the capacitance increases very rapidly. Cathodic treatment alters the impedance characteristics of the films but leads to either no detectible change in their photoelectrochemical properties or ...
1981-03-27
Crystallohydrate forms of trisubstituted uranyl orthophosphate
International Nuclear Information System (INIS)
The conditions of production and the stability regions have been studied for the following crystallohydrates of trisubstituted uranyl orthophosphates: (UO_2)_3(PO_4)_2x6H_2O, (UO_2)_3(PO_4)_2x4H_2O, and (UO_2)_3(PO_4)_2xH_2O. Their thermal stability has been studied. It is shown that thermal dehydration of high-water hydrates at 220-240 deg C gives (UO_2)_3(PO_4)_2xH_2O. The anion composition and crystal structure of the compound remain constant up to 1000 deg C. The mixture of the composition of U_3O_8xU_3(PO_4)_4 is the final product of decomposition at 1000 deg C. The thermodynamic constants of dehydration processes have been calculated. A conclusion has been made about the polymer structure of the compound in which water is located between the uranylphosphate layers.
Energy Technology Data Exchange (ETDEWEB)
According to an American Petroleum Institute production waste survey reported on by P.G. Wakim in 1987 and 1988, the exploration and production segment of the US oil and gas industry generated more than 360 million barrels (bbl) of drilling wastes, more than 20 billion bbl of produced water, and nearly 12 million bbl of associated wastes in 1985. Current exploration and production activities are believed to be generating comparable quantities of these oil field wastes. Wakim estimates that 28% of drilling wastes, less than 2% of produced water, and 52% of associated wastes are disposed of in off-site commercial facilities. In recent years, interest in disposing of oil field wastes in solution-mined salt caverns has been growing. This report provides information on the availability of commercial disposal companies in oil-and gas-producing states, the treatment and disposal methods they employ, and the amounts they charge. It also compares cavern ...
1997-09-01
Boiler and HRSG tube failures. Lesson 2. Corrosion fatigue
Energy Technology Data Exchange (ETDEWEB)
Fatigue damage occurs in general when a boiler tube is subject to repeat cyclic or fluctuating loading although the stress produced is below the material yield strength. The types of fatigue damage include, e.g., corrosion, thermal, mechanical, vibration, and creep fatigue. It is important to determine which form of fatigue is active, because measures to avoid repeat failures differ as the case arises. In this lesson, the focus is exclusively on corrosion fatigue. Corrosion fatigue occurs by the combined synergistic actions of cyclic loading and a corrosive environment. It is a discontinuous process with crack initiation and growth during transient periods. The excessive stresses may be caused during boiler operation by the restraint at tube attachments and by load changes (in particular during cold starts or forced cools) or during shutdown or restart of circulation boilers by thermal stratification of water along the tube length. Poor ...
2009-10-15
Energy Technology Data Exchange (ETDEWEB)
In order to gain a wider knowledge of corrosion phenomena in OFHC (oxygen free high conductivity) copper pipes of the stator cooling circuit of a power plant turboalternator, a research program was laid out which is based on the use of an experimental loop simulating real operating conditions as closely as possible. The samples examined were either copper foils or hollow conductors of the type that is normally used in the stator cooling system, and the circulating fluid was high purity water with controlled O/sub 2/, H/sub 2/ and C0/sub 2/ contents. Investigations were focused on the kinetics of O/sub 2/ removal through catalytic resins covered with metallic palladium (at different temperatures and pressures) and on the kinetics of CO/sub 2/ removal through mixed bed resins. Subsequently, attention was directed to the corrosion of copper (in the form of foils or hollow conductors) under different experimental conditions simulating either ...
1991-12-31
Energy Technology Data Exchange (ETDEWEB)
A numerical model of multiphase air-water flow and contaminant transport in the unsaturated zone is presented. The multiphase flow equations are solved using the two-pressure, mixed form of the equations with a modified Picard linearization of the equations and a finite element spatial approximation. A volatile contaminant is assumed to be transported in either phase, or in both phases simultaneously. The contaminant partitions between phases with an equilibrium distribution given by Henry`s Law or via kinetic mass transfer. The transport equations are solved using a Galerkin finite element method with reduced integration to lump the resultant matrices. The numerical model is applied to published experimental studies to examine the behavior of the air phase and associated contaminant movement under water infiltration. The model is also used to evaluate a hypothetical design for a low-level radioactive waste disposal ...
1995-05-01
International Nuclear Information System (INIS)
Heat transfer tubes of a primary pressurized water cooled (PPWC) in the high temperature engineering test reactor (HTTR) form the reactor pressure boundary of the primary coolant, therefore are important from the viewpoint of safety. To establish inspection techniques for the heat transfer tubes of the PPWC, an automatic inspection system was developed. The system employs a bobbin coil probe, a rotating probe for eddy current testing (ECT) and a rotating probe for ultrasonic testing (UT). Nondestructive test of a half of the heat transfer tubes of the PPWC was carried out by the automatic inspection system during reactor shutdown period of the HTTR (about 55% in the maximum reactor power in this paper). The nondestructive test results showed that the maximum signal-to-noise ratio was 1.8 in ECT. Pattern and phase of Lissajous wave, which were obtained for the heat transfer tube of the PPWC, were different from those obtained for the ...
Advanced water purification facility; Kodo josui shori gijutsu
Energy Technology Data Exchange (ETDEWEB)
Accelerated oxidation treatment technology is introduced for use in the treatment of poor quality water by ozone injected from the bottom of a pressurized ozone contact tank. Under study as oxidation accelerating processes using ozone center about an ozone/hydrogen peroxide treatment, ozone/UV treatment, ozone/hydrogen peroxide/UV treatment, etc. As the result of testing, important respects in accelerated oxidation are learned, which are stated below. In the ozone-aided treatment, there are some substances, such as chromatic matters, that can be removed more rapidly when in direct contact with gaseous ozone. In this case, the concentration of remnant ozone poses an important problem. In relation to the amount of injected hydrogen peroxide, what is important is the ozone/hydrogen peroxide injection ratio relative to the substance that is to be removed. In the use of UV rays, since the decomposition rate of dissolved ozone is approximately ten times higher than that ...
1997-12-19
Energy Technology Data Exchange (ETDEWEB)
Measurements were completed on the solubility of cupric and cuprous oxides in liquid water and steam at controlled pH conditions from 25 to 400 C (77 to 752 F). The results of this study have been combined with those reported from this laboratory in two previous EPRI reports to provide a complete description of the solubility of these oxides and the speciation of copper dissolved in liquid water and steam as a function of oxidation state, temperature, pH, and in the case of steam, pressure. These constitute the first set of reliable data for cuprous oxide solubility over this range of conditions. For the more intensively studied CuO case, agreement was found between our results and those of previous studies of its solubility in steam, whereas only partial agreement was evident for its solubility in liquid water. For both oxides this disagreement often amounted to orders of magnitude. The solubility of cuprous oxide is ...
2004-05-01
PLASMA JET WELDING, COATING, AND CUTTING: AN ...
... 31. New electric forming methods offer potentials for light metals; magnetic forming and plasma forming. ... 3, 25 Magnetic Forming ..... ...
1963-02-01
British Library Electronic Table of Contents (United Kingdom)
Abstract The available surface equation of state for pure pulmonary surfactant monolayers is generalised to binary mixture monolayers by introducing a group of parameters, i(i-=-1-4) in the form of $x_{r}^{\\beta _{i} } $ to express the influence of the components in new mixing rules and a new factor, I $\\left[ { = \\left( {\\prod\\limits_{i = 1}^{4} {\\beta _{i} } } \\right)^{{\\raise0.5ex\\hbox{$\\scriptstyle 1$}\\kern-0.1em/\\kern-0.15em\\lower0.25ex\\hbox{$\\scriptstyle {4}$}}} } \\right]$, is defined to represent the interaction intensity between two different components. The ---A isotherms getting by the surface equations of state agree with the experimental data for protein-lipid binary monolayers, and the average deviation is about 11.41%. The result shows the order of the interaction intensity b...
2010-01-01
British Library Electronic Table of Contents (United Kingdom)
In the present work, quaternary chitosans as water-soluble compounds were prepared based on three-step process. Schiff bases were firstly synthesized by the reaction between the amino groups of chitosan with aliphatic aldehydes followed by a reduction with sodium borohydride (NaBH4) to form N-(alkyl) chitosans. N,N,N-(dimethyl alkyl) chitosans were then obtained by a reaction of chitosan containing N-butyl, N-pentyl, N-hexyl, N-heptyl, and N-octyl substituents with methyl iodide. The compounds were characterized using IR and NMR spectroscopy. Subsequent experiments were conducted to test their antimicrobial activities against the most economic plant pathogenic bacteria of crown gall disease Agrobacterium tumefaciens, soft mold disease Erwinia carotovora, fungi of grey mold Botrytis cinerea...
2010-01-01
Spectral investigation of primary uranyl orthophosphate
International Nuclear Information System (INIS)
By methods of vibrational (infrared, Raman) and PMR spectroscopy, crystallohydrate forms of monosubstituted uranyl orthophosphate have been examined. The vibrational frequencies of the groupings from the compounds were identified. The existence of non-equivalent H_2PO_4"--groups in the substances under investigation was ascertained. It has been suggested that one of them is a bridged group, and the other is the end group. A fragment of the VO_2(H_2PO_4)_2 hydrate structure is given, its main constituents being uranylphosphate chains. The analysis of water vibrations assumes coordination of one mole of H_2O in VO_2(H_2PO_4)_2:3H_2O to uranium, while two other molecules are only hydrogen-bonded with phosphate anions. Absorption within the region of 2100-2550 cm"-"1 is assigned to vibrations of O...H...O groupings.
Silver removal process development for the MEO cleanout
Energy Technology Data Exchange (ETDEWEB)
The Mediated Electrochemical Oxidation (MEO) system is an aqueous process which treats low-level mixed wastes by oxidizing the organic components of he waste into carbon dioxide and water. As MEO system continues to run, dissolved ash and radionuclides slowly accumulate in the anolyte and must be removed to maintain process efficiency. At such time, all of the anolyte is pumped into a still feed tank, and the silver ions need to be removed before sending the solution to a thin-film evaporator for further concentration. The efficiency of removing silver ions in the solution needs to be high enough such that the residual silver sent to Final Forms would be less than 1% wt. The purpose of this work is to develop an efficient process to remove silver ions during the MEO cleanout and to demonstrate the capability of centrifugation for separating small silver chloride particles from the solution. This development work includes lab scale experiments ...
1996-02-01
Energy Technology Data Exchange (ETDEWEB)
Aqueous radioactive high-level waste slurries are combined during processing steps that ultimately produce a stable borosilicate glass waste form. Chemically treated waste slurries are combined with each other and with glass frit-water slurries to produce the melter feed. Understanding the evolution of the rheological properties of the slurries is an important aspect of removing and treating the stored waste. To a first approximation, combinations of colloidal waste slurry with {approx}0.1-mm mean diameter glass frit or glass beads act in an analogous matter to slurries of spherical beads in Newtonian liquids. The non-Newtonian rheological properties of the waste slurries without frit, however, add complexity to the hydrodynamic analysis. The use of shear rate dependent apparent viscosities with the modified Einstein equation was used to model the rheological properties of aqueous frit-waste slurries.
2009-09-02
Role of cetyltrimethylammonium bromide (cationic surfactant) on the tryptophan-MnO4- reaction
British Library Electronic Table of Contents (United Kingdom)
Upon addition of permanganate to a solution of tryptophan (Trp), yellow-brown color species appears within the time of mixing of tryptophan in absence and presence of cetyltrimethylammonium bromide (CTAB), which was stable for some days. Spectroscopic and kinetic evidences suggest the formation of water-soluble colloidal MnO2 as the most stable reduction product of MnO4-. Carbon dioxide and ammonia are not formed as the oxidation products. Carbon-carbon double bond of indole moiety of Trp is responsible for the fast reduction of permanganate. Cetyltrimethylammonium bromide catalyses the permanganate oxidation of Trp with a rate enhancement of ca. 200-fold. Sub- and postmicellar catalytic effect of CTAB ascribed to the association/incorporation/solubilization of both reactants (MnO4- and Tr...
2009-01-01
Responses of the toxic cyanobacterium Microcystis aeruginosa to iron and humic substances
British Library Electronic Table of Contents (United Kingdom)
Iron is an essential element to marine biota. Different types of dissolved organic matter (DOM), such as humic substances have impacts on the marine coastal waters iron chemistry.The aim of the study was to examine how the presence of humic substances (both aquatic and sedimentary) may affect iron bioavailability to the bloom-forming cyanobacterium Microcystis aeruginosa Kutzing incubated on standard and modified mineral BG-11 media. The final iron concentrations in the growth media ranged from 0.1 to 100mM.The results demonstrate that both the growth rate and the concentration of chlorophyll a in cultures of M. aeruginosa are limited by insufficient (a 15-fold as compared with the cultures exposed to iron only at the same concentration. Sedimentary humic acids in the presence of iron at a...
2007-01-01
International Nuclear Information System (INIS)
Peculiarities of Kurchatov Institute WWR-2 and TR research reactors spent fuel treating and transportation for radiochemical processing are stated. Spent fuels were performed as fuel assemblies of different forms and containing similar fuel elements: EhK-10 with 10% enrichment UO2-Mg fuel kernels or S-36 with 36% enrichment U-Al alloys. Spent fuel storage conditions are described. Features of developed procedures for identification of fuel assemblies by type of fuel elements are given. Transport package TUK-19 for loading and transportation of spent fuel for processing was chosen. Details of spent fuel loading in TUK-19 that is conducted by personnel under protective sheet of water in special reclaim volume are described
2009-04-01
Preparation of AgX (X = Cl, I) nanoparticles using ionic liquids
Energy Technology Data Exchange (ETDEWEB)
Nanoparticles of silver halides have been prepared by mixing silver halide powder with a single liquid phase consisting of an ionic liquid, isooctane, n-decanol and water. Much higher nanoparticle concentrations may be formed with ionic liquids using this new simple method than are found with conventionally applied surfactants. This method also emphasizes the applicability of ionic liquids as versatile components in microemulsions and as solvents for the synthesis of nanomaterials. The effect on the nanoparticles of changing the composition of the liquid mixtures and the nature of the ionic liquid is analysed. High nanoparticle concentrations were only found with chloride based ionic liquids, indicating the importance of the ionic liquid anion in the mechanism of the reaction.
2008-03-12
Preparation and evaluation of a novel glass-ionomer cement with antibacterial functions
British Library Electronic Table of Contents (United Kingdom)
Objective.The objective of this study was to use the newly synthesized poly(quaternary ammonium salt) (PQAS)-containing polyacid to formulate the light-curable glass-ionomer cements and study the effect of the PQAS on the compressive strength and antibacterial activity of the formed cements.Materials and methods.The functional QAS and their constructed PQAS were synthesized, characterized and formulated into the experimental high-strength cements. Compressive strength (CS) and Streptococcus mutans viability were used to evaluate the mechanical strength and antibacterial activity of the cements. Fuji II LC cement was used as control. The specimens were conditioned in distilled water at 37 degrees C for 24 h prior to testing. The effects of the substitute chain length, loading as well as gra...
2011-01-01
British Library Electronic Table of Contents (United Kingdom)
Background: Ecchymosis, oedema, haematoma and pain after SMAS-based facelift surgery are all the direct result of the physical trauma of surgery and subsequent inflammatory response. Hilotherapy is a novel form of cryotherapy that purports to minimise these events through single-use face masks circulating cooled, sterile water. This study was performed to assess the validity of Hilotherapy in this population of patients. Methods: Over 14 weeks fifty consecutive patients were randomised to post-operative facial cooling with Hilotherapy or management with standard dressings alone, while fifteen subsequent, consecutive patients were randomised to cooling of one side of the face but not the other. Assessment of ecchymosis, oedema, haematoma and pain was performed independently by clinical staf...
2011-01-01
Post-CHF heat transfer with water and refrigerants
Energy Technology Data Exchange (ETDEWEB)
Heat transfer experiments were performed in the post-CHF two-phase flow regime in a vertical tube. The tube inside diameter was 7.75 mm, and the boiling fluid was R-113. The experiments were performed at steady state by means of liquid heating of the test tube. Wall superheats were maintained below 70 C for heat exchanger/steam generator application. The mass flux range of the data was 379-816 kg m{sup -2} s{sup -1}. The use of R-113 significantly extended the property range of the existing low wall-superheat data base. Experimental data are presented in tabular as well as graphical form, and the results were used with low wall-superheat data from other fluids to add generality to a predictive heat transfer correlation. (orig.)
1996-06-01
Pit lakes: their characteristics and the potential for their remediation
Energy Technology Data Exchange (ETDEWEB)
Pit lakes form when open-pit mining operations are discontinued and dewatering ceases. The increase in open-pit metal mining since the 1970s will lead to the formation of numerous pit lakes over the next 50 years. Many of these lakes will develop acid sulfate conditions with high levels of dissolved metals. Approaches to remediation of these conditions that have been recommended include the addition of lime or other alkaline materials and the stimulation of sulfate-reducing bacteria. However, prevention rather than remediation is probably the preferable approach. Measures to prevent oxidation of mining waste and wall rocks, including measures to fill pits quickly with water, to inhibit the activity of acidophilic sulfur-oxidizing bacteria, and to promote anoxic conditions at the lake bottoms may minimize the formation of acids and dissolved metals. (orig.)
2000-10-01
Passivity of iron in red mud's water solutions
International Nuclear Information System (INIS)
Red mud suspensions are studied as passivating agents for iron in alkaline chloride media. Red mud particles in alkaline media are negatively charged, and can absorb considerable amounts of protons without significant changes in pH. These particles adhere easily to an iron surface forming aggregates of heterogeneous shape, smaller than 10 #mu#mx10 #mu#m. These adhered particles recrystallise on potential cycling, and hinder metal dissolution and magnetite formation. Carbon steel samples passivated in red mud suspensions become resistant to corrosion in alkaline chloride media. Corrosion potential versus time records and impedance spectroscopy measurements allow formulating some hypotheses about the inhibiting mechanism.
2004-07-30
Passivity of iron in red mud's water solutions
Energy Technology Data Exchange (ETDEWEB)
Red mud suspensions are studied as passivating agents for iron in alkaline chloride media. Red mud particles in alkaline media are negatively charged, and can absorb considerable amounts of protons without significant changes in pH. These particles adhere easily to an iron surface forming aggregates of heterogeneous shape, smaller than 10 {mu}mx10 {mu}m. These adhered particles recrystallise on potential cycling, and hinder metal dissolution and magnetite formation. Carbon steel samples passivated in red mud suspensions become resistant to corrosion in alkaline chloride media. Corrosion potential versus time records and impedance spectroscopy measurements allow formulating some hypotheses about the inhibiting mechanism.
2004-07-30
The optical and nonlinear optical properties of colloidal solutions of silver obtained by laser ablation in water and ethanol are studied. It is shown that freshly prepared colloids experience a full or partial sedimentation by changing their nonlinear optical properties. Aqueous colloids undergo a partial sedimentation and their nonlinear optical absorption changes to nonlinear optical transmission. The obtained results are interpreted using the Drude model for metal particles taking the particle size into account and can be explained by the sedimentation of larger silver particles accompanied by the formation of a stable colloid containing silver nanoparticles with a tentatively silver oxide shell. The characteristic size of particles forming such a stable colloid is determined and its optical nonlinearity is estimated.
2004-07-01
British Library Electronic Table of Contents (United Kingdom)
Meiji (Mischief) coral atoll, in Nansha (Spratly) Islands, South China Sea, consists of an annular reef rim surrounding a central lagoon. On the atoll rim there are either protuberant ?motu? (small coral patch reefs on the rim of atoll) islets or lower sandy cays that contain modern microbialite deposits on the corals in pinnacles and surrounding bottoms of the atoll. Microbialites, including villiform, hairy, and thin spine growth forms, as well as gelatinous masses, mats and encrustation, developed on coral colonies and atoll rim sediments between 0 and 15 m deep-water settings. The microbialites were produced by natural populations of filamentous cyanobacteria and grew on (1) bulbous corals together with Acropora sp., (2) on massive colonies of Galaxea fascicularis, (3) on dead Montipor...
2008-01-01
British Library Electronic Table of Contents (United Kingdom)
Dissolved microcystins (MCs) are regularly present in water dominated by microcystin-producing, bloom-forming cyanobacteria. In vitro experiments with environmentally feasible concentrations (5 ? 10?7 M) of the three most common microcystins, MC-LR, MC-RR, and MC-YR, revealed that they influence the metabolism of different representative phytoplanktons. At light intensities that are close to the cyanobacterial bloom environment (50??mol m?2 s?1), they produce morphological and physiological changes in both microcystin-producing and -nonproducing Microcystis aeruginosa strains and also have similar effects on the green alga Scenedesmus quadricauda that is frequently present in cyanobacterial blooms. All three microcystin variants tested induce cell aggregation, increase in cell volume, and ...
2006-01-01
Laboratory-scale simulation of energy extraction from tidal currents
Energy Technology Data Exchange (ETDEWEB)
The energy available from tidal currents is substantial and considerable work has been conducted into determining the size of the resource and what the large-scale consequences of extraction might be. This paper describes the work conducted to establish a laboratory-scale model, by using the commercial computational fluid dynamics (CFD) code FLUENT trademark, in order to predict local-flow consequences resulting from the extraction of energy in two and three dimensions from within the water column in a tidal flow. As might be expected, a wake is formed but there is considerable localized flow acceleration around and, most especially, under an extraction zone. The wake behind the device is shown to be associated with a drop in the free surface which, in turn, is associated with the decline in the wake itself. (author)
2008-06-15
Energy Technology Data Exchange (ETDEWEB)
An experimental and theoretical study of heat and mass transfer analogy and a comparison of that to a binary liquid mixture evaporation is presented. Common organic solvents, ethanol and n-heptane, were used to form an alcohol - hydrocarbon mixture. Studies were carried out in a horizontal rectangular channel having air flow velocities of 0.2 - 0.9 m/s. Heat transfer coefficients were measured with a copper plate resistor and mass transfer coefficients with a square pool. The heat and mass transfer analogy is presented for a system having two evaporating compounds with a fixed value of air flow and verified by measuring and comparing mass transfer coefficients for distilled water with air flow velocities of 0.2 - 0.9 m/s. An illustrative example of the use of the theory for industrial ventilation is presented. (author)
1995-12-31
Formation and control of non-trihalomethane by-products
Energy Technology Data Exchange (ETDEWEB)
Hundreds of organic byproducts of chlorination are now known to occur in drinking water along with the trihalomethanes. About twenty of these appear to be found with sufficient frequency and in sufficient concentration to attract consideration for regulations. These include chloral hydrate, chloropicrin, a trichloropropanone, haloacetonitriles, and haloacetic acids. Trihalomethane concentrations do not serve as good predictors of concentrations of these other byproducts because their conditions of formation vary widely. This is especially true when pH is changed. Treatment strategies for control of these byproducts including the trihalomethanes are: Remove the compounds after they are formed; Remove precursors; and Use other disinfectants. Current evidence supports the idea that precursor removal processes effective for trihalomethane control may be effective for the other byproducts as well.
1989-01-01
The calculations of Gay et al. of the terminal velocities of charged hydrormeteors in the presence of electric fields have formed the basis of computations of the charging current density J flowing through a thunder-cloud as a result of the operation of a precipitative mechanism of cloud electrification. Values of J were calculated for a range of values of field strength E, precipitation rate pO, precipitation content L, cloud water content C, charge distribution, total separated charge, and the fraction of the small particles that have undergone a charging event.It is found that the estimated field required for the initiation of a lightning stroke (3.5 kV cm1 can be achieved only over a narrow range of conditions. The ease with which precipitative mechanisms can produce breakdown fields is considerably increased, however, if account is taken of spatial inhomogenities in the field.
1975-05-01
British Library Electronic Table of Contents (United Kingdom)
AbstractBackground In recent years nano-metaloxides which easily penetrate into the cells with special interest due to their higher chemical reactivity as compared to that of similar materials in the bulk form. Of particular interest are nano-TiO2 and ZnO, which have been widely used for their bactericidal and anticancerous properties. Purpose The aim of the present study was to examine the bactericidal properties of nano-TiO2 and ZnO combined with visible light on S. aureus and S. epidermitis, known for their high prevalence in infected wounds. Study Using the technique of electron-spin resonance (ESR) coupled with spin trapping, we examined the ability of TiO2 and ZnO nanoparticle suspensions in water to produce reactive oxygen species (ROS) with and without visible light irradiation. Th...
2011-01-01
DOE Plutonium Disposition Study: Pu consumption in ALWRs. Volume 1, Final report
Energy Technology Data Exchange (ETDEWEB)
The Department of Energy (DOE) has contracted with Asea Brown Boveri-Combustion Engineering (ABB-CE) to provide information on the capability of ABB-CE`s System 80 + Advanced Light Water Reactor (ALWR) to transform, through reactor burnup, 100 metric tonnes (MT) of weapons grade plutonium (Pu) into a form which is not readily useable in weapons. This information is being developed as part of DOE`s Plutonium Disposition Study, initiated by DOE in response to Congressional action. This document, Volume 1, presents a technical description of the various elements of the System 80 + Standard Plant Design upon which the Plutonium Disposition Study was based. The System 80 + Standard Design is fully developed and directly suited to meeting the mission objectives for plutonium disposal. The bass U0{sub 2} plant design is discussed here.
1993-05-15
Chemical composition of passive films on AISI 304 stainless steel
Energy Technology Data Exchange (ETDEWEB)
Chemical characterization of passive films formed on AISI 304 austenitic stainless steel, in a borate/boric acid solution at pH 9.2, under various conditions of potential, temperature, and polarizations time, was made by Auger electron spectroscopy combined with ion sputtering, and x-ray photoelectron spectroscopy (XPS). The depth chemical composition, thickness, and duplex character of the passive layers were determined after processing AES sputter profiles by their quantitative approach based on the sequential layer sputtering model. Moreover, separated contributions of elements in their oxidized and unoxidized state could be disclosed from part to part of the oxide-alloy interface. The XPS study specified the chemical bondings which take placed inside the film, between Fe and oxygen (and water).
1994-12-01
Energy Technology Data Exchange (ETDEWEB)
The North Dakota Energy & Environmental Research Center (EERC) approach to removing NO{sub x} from flue gas emitted by coal-fired utility boilers or for the control of NO{sub x} formation by advanced combustion techniques involves the development of a catalytic fabric filter (CFF) for simultaneous NO{sub x} and particulate control. The NO{sub x}is removed by catalytic reduction with ammonia to form nitrogen and water. Bench-scale experimental results have shown that over 90% NO{sub x} removal can be achieved. This report details the strengths and areas for for development in this project.
1994-04-01
Energy Technology Data Exchange (ETDEWEB)
The project was initiated in 1985 with the goal of studying existing federal, state, and local programs for protecting and preserving Cape Cod's sole-source aquifer. To meet this need, the Massachusetts Department of Environmental Quality Engineering and the U.S. Environmental Protection Agency's Region 1 in cooperation with the Cape Cod Planning and Economic and Development Commission and the U.S. Geological Survey initiated a two-year study to determine the adequacy of current ground-water protection programs and to recommend improvements. In the process of gathering and evaluating hydrogeological data from the Towns of Barnstable and Eastham, the CCAMP Aquifer Assessment Committee developed the papers which are the subject of this publication. These studies formed the technical basis for groundwater resource management decision making.
1988-09-01
Barriers for radon in uranium mines. Report of investigations 1977
International Nuclear Information System (INIS)
Water-based epoxy sealants were examined during a 2-year period to determine their effectiveness as barriers to radon release in uranium mines. Radon emanation rates from uranium ore samples were monitored for extended periods in the laboratory before and after sealant application. Reduction of radon flux due to the coating of lab samples was approximately 80 percent. Test chambers in a dormant uranium mine were monitored to determine both short and long-term barrier effectiveness. These field studies of the sealants indicated reductions greater than 50 percent relatively soon after application and nearly 75 percent more than 1 year later. An unexpected complication to early monitoring in the form of a large radon emanation increase, believed due to added moisture, is discussed.
Application of electrochemically dissolved iron in the removal of tannic acid from water
British Library Electronic Table of Contents (United Kingdom)
Effects of some experimental parameters (supporting electrolyte, initial pH and current density) on the performance of electrocoagulation process using iron electrodes were investigated. Results of experiments showed that dissolution of iron is purely electrochemical and fits well with Faraday's law and leads to Fe^2^+ which are chemically oxidized into Fe^3^+ in aerated conditions. In neutral and alkaline conditions, the reaction between hydroxyl ions generated at the cathode and dissolved iron ions forms insoluble hydroxo-iron species. Potentiodynamic polarization tests showed that the formation of passive film on iron anode limits the continuous electrochemical dissolution of iron. Corrosion and pitting potentials largely depend on the nature of supporting electrolyte. The dissolution o...
2011-01-01
A study on the comparative method using AHP and GIS based distributed runoff model
British Library Electronic Table of Contents (United Kingdom)
Research in the field of river hydrology has been mainly concerned with the investigation of the rainfall-runoff phenomenon through the analysis of hydrological factors such as meteorology and geography, with the focus being on each river basin. Recently, various forms of digital information such as GIS (Geographic Information System) and RS (Remote Sensing) data have been made available in worldwide digital map format. Therefore, there has been a shift in focus from lumped-parameter models to distributed runoff models, as the latter can consider temporal and spatial variations in water quantity. Distributed runoff models have made possible the comparison of runoff field and rainfall-runoff characteristics considering spatial distribution. Hydrological conditions are differently distribute...
2010-01-01
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