WorldWideScience

Sample records for water injection oil

  1. Radiotracer investigations in oil production and water injection wells

    International Nuclear Information System (INIS)

    Injection of gamma emitting radiotracers into oil wells followed by logging provides information on several aspects such as the identification of zones of seepage of water in the water injection wells and also the location of source of water entering oil producting wells. The experience gained in the application of bromine-82 and rubidium-86 as radiotracers in such studies at the Ankleshwar and Kalol oil fields in Gujarat and Nazira in Assam has been briefly reported. (author)

  2. Water injection in viscous oil through horizontal well

    Energy Technology Data Exchange (ETDEWEB)

    Martini, R.F.; Bonet, E.J.; Schiozer, D.J. [Society of Petroleum Engineers, Richardson, TX (United States)]|[Unicamp (Brazil)

    2005-11-01

    The economic success of heavy-oil, deep water fields depends upon the placement of wells, particular in reservoirs where water injection is used as a recovery method. This study analyzed the behavior of heavy oil displacement by water injection into viscous oil. The porous media was also characterized using simulation studies of an experimental and numerical design. A rock plate, filled with porous media, an Eolian sandstone from Botucatu formation, was prepared for laboratory tests. Its porosity, permeability distribution, relative permeabilities and capillary pressure were measured. Two horizontal wells were used and the laboratory tests included an oil saturation phase and a displacement phase. To analyse distortions in the horizontal wells due to friction effects, saturation maps were developed. A numerical simulation model then reproduced the observed behavior from the experiment and pressure drop effects were compared. This was then used as the foundation of a hypothetical field scale reservoir prototype. The simulation results demonstrated that despite the high oil viscosity, friction pressure losses in the wellbore did not seem to affect the flow. 17 refs., 1 tab., 17 figs.

  3. Inline gas/oil/water separation technology integrated with water injection facilities

    Energy Technology Data Exchange (ETDEWEB)

    Verbeek, Paul; Schook, Rob

    2006-07-01

    The presentation presents applications of separation technology with water injection possibilities. The main conclusions are: Processing direct well streams requires control and monitoring in order to cater for: Dynamics of in-line equipment in a full process from production wells to oil export line and water injection wells. Short-residence time and small inventory in-line processing should be robust against process upsets. Control of slugging of feed through upstream ''conditioning''. Process control of flow splits e.g. by on-line monitoring of quality of fluid outlets (tk)

  4. Modeling Reservoir Formation Damage due to Water Injection for Oil Recovery

    OpenAIRE

    Yuan, Hao

    2011-01-01

    The elliptic equation for non-Fickian transport of suspension in porous media is applied to simulate the reservoir formation damage due to water injection for oil recovery. The deposition release (erosion of reservoir formation) and the suspension deposition (pore plugging) are both taken into account. 1-D numerical simulations are carried out to reveal the erosion of reservoir formation due to water injection. 2-D numerical simulations are carried out to obtain the suspension and deposition ...

  5. Modeling Reservoir Formation Damage due to Water Injection for Oil Recovery

    DEFF Research Database (Denmark)

    Yuan, Hao

    2010-01-01

    The elliptic equation for non-Fickian transport of suspension in porous media is applied to simulate the reservoir formation damage due to water injection for oil recovery. The deposition release (erosion of reservoir formation) and the suspension deposition (pore plugging) are both taken into account. 1-D numerical simulations are carried out to reveal the erosion of reservoir formation due to water injection. 2-D numerical simulations are carried out to obtain the suspension and deposition profiles around the injection wells. These preliminary results indicate the non-Fickian behaviors of suspended reservoir fines and the corresponding formation damage due to erosion and relocation of reservoir fines.

  6. Feasibility study of non-radioactive tracers for monitoring injected water in oil reservoirs

    International Nuclear Information System (INIS)

    This paper discusses the results of analyses conducted on non-radioactive tracers that can be used in combination with the sea water injected into a well for monitoring the water permeating through the oil reservoir by a nuclear logging tool utilizing a pulsed neutron generator. The model of the pulsed neutron tool is constructed to permit Monte Carlo Simulations to be performed of the tool response to the presence of non-radioactive tracers to achieve a desirable level of the neutron absorbing cross sections in the sea water injected into and permeating through the oil reservoirs. Sensitivity analyses of the tool response of the nuclear logging tool were performed for two types of non-radioactive tracers, ammonium tetraborate and gadolinium chloride. (orig.)

  7. Managing Injected Water Composition To Improve Oil Recovery: A Case Study of North Sea Chalk Reservoirs

    DEFF Research Database (Denmark)

    Zahid, Adeel; Shapiro, Alexander

    2012-01-01

    In recent years, many core displacement experiments of oil by seawater performed on chalk rock samples have reported SO42–, Ca2+, and Mg2+ as potential determining ions for improving oil recovery. Most of these studies were carried out with outcrop chalk core plugs. The objective of this study is to investigate the potential of the advanced waterflooding process by carrying out experiments with reservoir chalk samples. The study results in a better understanding of the mechanisms involved in increasing the oil recovery with potential determining ions. We carried out waterflooding instead of spontaneous imbibition, which has been applied in most of the previous studies. Two different flooding schemes (with and without aging) were used for flooding North Sea reservoir chalk samples. For comparison, two tests were also carried out with Stevns Klint core plugs. The flooding tests were carried out with the following injecting fluids: distilled water, brine with and without sulfate, and brine containing only magnesium ions. The total oil recovery, recovery rate, and interaction mechanisms of ions with rock were studied for different injecting fluids at different temperatures and wettability conditions. Studies of the temperature dependence of the oil recovery indicated that the interaction of the ions contained in brine with the rock cannot be the only determining mechanism of enhanced recovery. We observed no substitution of Ca2+ ions with Mg2+ ions at high temperatures for both rocks. Not only the injection brine composition but also the formation water composition affected the oil recovery at high temperatures from the Stevns Klint chalk rock.

  8. Scale Formation in Oil Reservoir During Water Injection at High-Salinity Formation Water

    OpenAIRE

    Amer Badr Bin Merdhah; Abu Azam Mohd Yassin

    2007-01-01

    This study presents the results of Laboratory experiments carried out to investigate the formation of calcium and strontium sulfates in sandstone cores from mixing injected sea water and formation water contain high concentration of calcium and strontium ions at various temperatures (50 and 80°C) and differential pressures (100 and 200 psig). The morphology of scaling crystals as shown by Scanning Electron Microscopy (SEM) is presented. Results show a large extent of permeability damage cause...

  9. Barium Sulfate Scale Formation in Oil Reservoir During Water Injection at High-Barium Formation Water

    OpenAIRE

    Amer Badr Bin Merdhah; Abu Azam Mohd Yassin

    2007-01-01

    This study presents the results of laboratory experiments carried out to investigate the formation of barium sulfate in sandstone cores from mixing injected sea water and formation water contain high concentration of barium at various temperatures (50 and 80°C) and differential pressures (100, 150 and 200 psig). The morphology of scaling crystals as shown by Scanning Electron Microscopy (SEM) is presented. Results show a large extent of permeability damage caused by barium sulfate deposits on...

  10. Barium Sulfate Scale Formation in Oil Reservoir During Water Injection at High-Barium Formation Water

    Directory of Open Access Journals (Sweden)

    Amer Badr Bin Merdhah

    2007-01-01

    Full Text Available This study presents the results of laboratory experiments carried out to investigate the formation of barium sulfate in sandstone cores from mixing injected sea water and formation water contain high concentration of barium at various temperatures (50 and 80°C and differential pressures (100, 150 and 200 psig. The morphology of scaling crystals as shown by Scanning Electron Microscopy (SEM is presented. Results show a large extent of permeability damage caused by barium sulfate deposits on the rock pore surface. The rock permeability decline indicates the influence of the concentration of barium ions.

  11. Influence of Steam Injection and Water-in-Oil Emulsions on Diesel Fuel Combustion Performance

    Science.gov (United States)

    Sung, Meagan

    Water injection can be an effective strategy for reducing NOx because water's high specific heat allows it to absorb heat and lower system temperatures. Introducing water as an emulsion can potentially be more effective at reducing emissions than steam injection due to physical properties (such as microexplosions) that can improve atomization and increase mixing. Unfortunately, the immiscibility of emulsions makes them difficult to work with so they must be mixed properly. In this effort, a method for adequately mixing surfactant-free emulsions was established and verified using high speed cinematography. As the water to fuel mass ratio (W/F) increased, emulsion atomization tests showed little change in droplet size and spray angle, but a shorter overall breakup point. Dual-wavelength planar laser induced fluorescence (D-PLIF) patternation showed an increase in water near the center of the spray. Steam injection flames saw little change in reaction stability, but emulsion flames experienced significant losses in stability that limited reaction operability at higher W/F. Emulsions were more effective at reducing NOx than steam injection, likely because of liquid water's latent heat of vaporization and the strategic injection of water into the flame core. OH* chemiluminescence showed a decrease in heat release for both methods, though the decrease was greater for emulsions. Both methods saw decreases in flame length for W/F 0.15. Lastly, flame imaging showed a shift towards a redder appearance with the addition or more water, as well as a reduction in flame flares.

  12. Selective water injection completion

    Energy Technology Data Exchange (ETDEWEB)

    Aldaz Cifuentes, Santiago [Schlumberger Smith Completions, Celle (Germany)

    2010-12-15

    This article presents the development and applications of modern completion systems for Selective Water Injection. It is based on a field study performed in Argentina adding records of successful technology application and development over time as well as benefits for the oil industry. A Selective Completion System used and developed by Schlumberger Smith Completions is defined as a set of tools characterized by isolating a single or more zones of interest along the oil well in order to take absolute control of the zone of interest. The principle of the technological development is based on replacing traditional mechanical packers by hydraulic systems bringing a new generation of tools developed for challenging well architecture. A Selective Completion System also implies the interaction of logging tools, tubing conveyed perforations and proper reservoir management systems. This article also highlights reservoir management concepts and water injection benefits for recovery factor improvements based on development from simple completion systems up to selective completion systems as part of the successful operational development of Schlumberger Smith Completions in Argentina. (orig.)

  13. Characterization and Alteration of Wettability States of Alaskan Reserviors to Improve Oil Recovery Efficiency (including the within-scope expansion based on Cyclic Water Injection - a pulsed waterflood for Enhanced Oil Recovery)

    Energy Technology Data Exchange (ETDEWEB)

    Abhijit Dandekar; Shirish Patil; Santanu Khataniar

    2008-12-31

    Numerous early reports on experimental works relating to the role of wettability in various aspects of oil recovery have been published. Early examples of laboratory waterfloods show oil recovery increasing with increasing water-wetness. This result is consistent with the intuitive notion that strong wetting preference of the rock for water and associated strong capillary-imbibition forces gives the most efficient oil displacement. This report examines the effect of wettability on waterflooding and gasflooding processes respectively. Waterflood oil recoveries were examined for the dual cases of uniform and non-uniform wetting conditions. Based on the results of the literature review on effect of wettability and oil recovery, coreflooding experiments were designed to examine the effect of changing water chemistry (salinity) on residual oil saturation. Numerous corefloods were conducted on reservoir rock material from representative formations on the Alaska North Slope (ANS). The corefloods consisted of injecting water (reservoir water and ultra low-salinity ANS lake water) of different salinities in secondary as well as tertiary mode. Additionally, complete reservoir condition corefloods were also conducted using live oil. In all the tests, wettability indices, residual oil saturation, and oil recovery were measured. All results consistently lead to one conclusion; that is, a decrease in injection water salinity causes a reduction in residual oil saturation and a slight increase in water-wetness, both of which are comparable with literature observations. These observations have an intuitive appeal in that water easily imbibes into the core and displaces oil. Therefore, low-salinity waterfloods have the potential for improved oil recovery in the secondary recovery process, and ultra low-salinity ANS lake water is an attractive source of injection water or a source for diluting the high-salinity reservoir water. As part of the within-scope expansion of this project, cyclic water injection tests using high as well as low salinity were also conducted on several representative ANS core samples. These results indicate that less pore volume of water is required to recover the same amount of oil as compared with continuous water injection. Additionally, in cyclic water injection, oil is produced even during the idle time of water injection. It is understood that the injected brine front spreads/smears through the pores and displaces oil out uniformly rather than viscous fingering. The overall benefits of this project include increased oil production from existing Alaskan reservoirs. This conclusion is based on the performed experiments and results obtained on low-salinity water injection (including ANS lake water), vis-a-vis slightly altering the wetting conditions. Similarly, encouraging cyclic water-injection test results indicate that this method can help achieve residual oil saturation earlier than continuous water injection. If proved in field, this would be of great use, as more oil can be recovered through cyclic water injection for the same amount of water injected.

  14. Fluid injection for salt water disposal and enhanced oil recovery as a potential problem for the WIPP: Proceedings of a June 1995 workshop and analysis

    Energy Technology Data Exchange (ETDEWEB)

    Silva, M.K.

    1996-08-01

    The Waste Isolation Pilot Plant (WIPP) is a facility of the U.S. Department of Energy (DOE), designed and constructed for the permanent disposal of transuranic (TRU) defense waste. The repository is sited in the New Mexico portion of the Delaware Basin, at a depth of 655 meters, in the salt beds of the Salado Formation. The WIPP is surrounded by reserves and production of potash, crude oil and natural gas. In selecting a repository site, concerns about extensive oil field development eliminated the Mescalero Plains site in Chaves County and concerns about future waterflooding in nearby oil fields helped eliminate the Alternate II site in Lea County. Ultimately, the Los Medanos site in Eddy County was selected, relying in part on the conclusion that there were no oil reserves at the site. For oil field operations, the problem of water migrating from the injection zone, through other formations such as the Salado, and onto adjacent property has long been recognized. In 1980, the DOE intended to prohibit secondary recovery by waterflooding in one mile buffer surrounding the WIPP Site. However, the DOE relinquished the right to restrict waterflooding based on a natural resources report which maintained that there was a minimal amount of crude oil likely to exist at the WIPP site, hence waterflooding adjacent to the WIPP would be unlikely. This document presents the workshop presentations and analyses for the fluid injection for salt water disposal and enhanced oil recovery utilizing fluid injection and their potential effects on the WIPP facility.

  15. Fluid injection for salt water disposal and enhanced oil recovery as a potential problem for the WIPP: Proceedings of a June 1995 workshop and analysis

    International Nuclear Information System (INIS)

    The Waste Isolation Pilot Plant (WIPP) is a facility of the U.S. Department of Energy (DOE), designed and constructed for the permanent disposal of transuranic (TRU) defense waste. The repository is sited in the New Mexico portion of the Delaware Basin, at a depth of 655 meters, in the salt beds of the Salado Formation. The WIPP is surrounded by reserves and production of potash, crude oil and natural gas. In selecting a repository site, concerns about extensive oil field development eliminated the Mescalero Plains site in Chaves County and concerns about future waterflooding in nearby oil fields helped eliminate the Alternate II site in Lea County. Ultimately, the Los Medanos site in Eddy County was selected, relying in part on the conclusion that there were no oil reserves at the site. For oil field operations, the problem of water migrating from the injection zone, through other formations such as the Salado, and onto adjacent property has long been recognized. In 1980, the DOE intended to prohibit secondary recovery by waterflooding in one mile buffer surrounding the WIPP Site. However, the DOE relinquished the right to restrict waterflooding based on a natural resources report which maintained that there was a minimal amount of crude oil likely to exist at the WIPP site, hence waterflooding adjacent to the WIPP would be unlikely. This document presents the workshop presentations and analyses for the fluid injection for salt water disposal and enhanced oil recovery utilizing fluid injection and their potential effects on the WIPP facility

  16. Managing Injected Water Composition To Improve Oil Recovery: A Case Study of North Sea Chalk Reservoirs

    DEFF Research Database (Denmark)

    Zahid, Adeel; Shapiro, Alexander; Stenby, Erling Halfdan; Yan, Wei

    2012-01-01

    In recent years, many core displacement experiments of oil by seawater performed on chalk rock samples have reported SO42–, Ca2+, and Mg2+ as potential determining ions for improving oil recovery. Most of these studies were carried out with outcrop chalk core plugs. The objective of this study is to investigate the potential of the advanced waterflooding process by carrying out experiments with reservoir chalk samples. The study results in a better understanding of the mechanisms involved in inc...

  17. Injection Design for Simultaneous Enhanced Oil Recovery and Carbon Storage in a Heavy Oil Reservoir

    OpenAIRE

    Sobers, Lorraine Elizabeth

    2012-01-01

    We have identified a CO2 and water injection strategy to recover moderately heavy oil and store carbon dioxide (CO2) simultaneously. We propose the use of counter-current injection of gas and water to improve reservoir sweep and trap CO2; water is injected in the upper portion of the reservoir and gas is injected in the lower portion. This process is referred to as water over gas injection or modified simultaneous water alternating gas injection (SWAG). This thesis is based on ...

  18. Effects of cold water injection on injectivity impairment due to suspended particles

    Energy Technology Data Exchange (ETDEWEB)

    Bedrikovetsky, Pavel; Fonseca, Diogo R. [Universidade Estadual do Norte Fluminense (UENF), Campos dos Goytacases, RJ (Brazil); Paiva, Ronaldo O. [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2004-07-01

    This paper presents an analytical model to interpret pressure injection data following cold-water injection into a hot-oil reservoir. The injected water contains solid and liquid particles causing permeability decline. The relative permeability characteristics of the porous medium are accounted for, as is the temperature dependence of the fluid mobilities. It is shown that the temperature difference between injected and formation waters and the water-oil mobility variation have significant effects on the pressure data during the impairment of rock by particles from the injected suspension. The matching of field data to type curves generated from analytical solutions provides estimates of the formation damage parameters - filtration and formation damage coefficients, critical porosity ratio and cake permeability. The effect of injected water temperature on well injectivity decline is particularly sounded for cold water injection into heavy oil reservoirs. (author)

  19. Water injection profiling

    International Nuclear Information System (INIS)

    A method of neutron-gamma logging is described, in which water, injected in a cased well borehole with peforations, is irradiated with neutrons of 10 MeV or greater, and subsequent gamma radiation is detected by a pair of detectors along the borehole. Counting rates of detectors are analyzed in terms of two gamma ray energy windows. Linear flow velocity of fluid moving downward within the casing is used in conjunction with count rate data to determine volume flow rates of water moving in other directions. Apparatus includes a sonde with a neutron source and appropriate gamma sensors

  20. Intramuscular Injection of “Site Enhancement Oil

    DEFF Research Database (Denmark)

    Petersen, Maria Louise; Colville-Ebeling, Bonnie; Jensen, Thomas Hartvig Lindkær; Hougen, Hans Petter

    2015-01-01

    The use of intramuscular injection of foreign substances for aesthetic purposes is well known. Complications are usually local to the site of injection but can be potentially lethal. Here, we present a case of "site enhancement oil" use in a 42-year-old man who died from asphyxia due to hanging. Macroscopic and microscopic changes as well as computed tomographic changes in injected musculature are described and the potentially lethal adverse effects after site enhancement oil use are warranted.

  1. Cooling water injection system

    International Nuclear Information System (INIS)

    In a BWR type reactor, ECCS system is constituted as a so-called stand-by system which is not used during usual operation and there is a significant discontinuity in relation with the usual system. It is extremely important that ECCS operates upon occurrence of accidents just as specified. In view of the above in the present invention, the stand-by system is disposed along the same line with the usual system. That is, a driving water supply pump for supplying driving water to a jet pump is driven by a driving mechanism. The driving mechanism drives continuously the driving water supply pump in a case if an expected accident such as loss of the function of the water supply pump, as well as during normal operation. That is, all of the water supply pump, jet pump, driving water supply pump and driving mechanism therefor are caused to operate also during normal operation. The operation of them are not initiated upon accident. Thus, the cooling water injection system can perform at high reliability to remarkably improve the plant safety. (K.M.)

  2. Water quality considerations resulting in the impaired injectivity of water injection and disposal wells

    International Nuclear Information System (INIS)

    An environmentally responsible way to improve hydrocarbon recovery is to maintain pressure by water injection. This is a desirable method because unwanted produced water from oil and gas wells can be re-injected into producing or disposal formations. The success of the operation, however, depends on injecting the necessary volume of water economically, below the fracture gradient pressure of the formation. Well placement, geometry and inherent formation quality and relative permeability characteristics are some of the many other factors which influence the success of any injection project. Poor injection or poor quality of disposal water can also compromise the injectivity for even high quality sandstone or carbonate formations. This would necessitate costly workovers and recompletions. This paper presented some leading edge diagnostic techniques and evaluation methods to determine the quality of injected water. The same techniques could be used to better understand the effect of potential contaminants such as suspended solids, corrosion products, skim/carryover oil and grease, scales, precipitates, emulsions, oil wet hydrocarbon agglomerates and many other conditions which cause injectivity degradation. 14 refs., 1 tab., 15 figs

  3. Study on the Fine Optimization of Water Injection in SZ Oilfield of Bohai Bay

    OpenAIRE

    SUN Guangyi; MA Kuiqian; Yang, Jing

    2014-01-01

    Bohai SZ Oilfield has entered into high water cut stage, how to realize the goal of fine optimization of water injection to enhance oil recovery is an important problem for reservoir engineers. Fine optimization of water injection needs ‘inject enough’, ‘inject well’ and ‘inject effectively’. The paper gets relationship between annual oil production rate and annual water production rate of different water cut stages of SZ Oilfield with the life cycle theory and draws the annual water injectio...

  4. Oil injection into the blast furnace

    Energy Technology Data Exchange (ETDEWEB)

    Dongsheng Liao; Mannila, P.; Haerkki, J.

    1997-12-31

    Fuel injection techniques have been extensively used in the commercial blast furnaces, a number of publications concerning the fuels injection have been reported. This present report only summarizes the study achievements of oil injection due to the research need the of authors, it includes the following parts: First, the background and the reasons reducing coke rate of oil injection are analyzed. Reducing coke rate and decreasing the ironmaking costs are the main deriving forces, the contents of C, H and ash are direct reasons reducing coke rate. It was also found that oil injection had great effects on the state of blast furnace, it made operation stable, center gas flow develop fully, pressure drop increase, descent speed of burden materials decrease and generation of thermal stagnation phenomena, the quality of iron was improved. Based on these effects, as an ideal mean, oil injection was often used to adjust the state of blast furnace. Secondly, combustion behavior of oil in the raceway and tuyere are discussed. The distribution of gas content was greatly changed, the location of CO, H{sub 2} generation was near the tuyere; the temperature peak shifts from near the raceway boundary to the tuyere. Oxygen concentration and blast velocity were two important factors, it was found that increasing excess oxygen ratio 0.9 to 1.3, the combustion time of oil decreases 0.5 msec, an increase of the blast velocity results in increasing the flame length. In addition, the nozzle position and oil rate had large effects on the combustion of oil. Based on these results, the limit of oil injection is also discussed, soot formation is the main reason limiting to further increase oil injection rate, it was viewed that there were three types of soot which were generated under blast furnace operating conditions. The reason generating soot is the incomplete conversion of the fuel. Finally, three methods improving combustion of oil in the raceway are given: Improvement of oil atomization, increased blast temperature and oxygen and injection of reducing gases into the bosh zone. (orig.) 25 refs.

  5. Economics of water injected air screw compressor systems

    Science.gov (United States)

    Venu Madhav, K.; Kova?evi?, A.

    2015-08-01

    There is a growing need for compressed air free of entrained oil to be used in industry. In many cases it can be supplied by oil flooded screw compressors with multi stage filtration systems, or by oil free screw compressors. However, if water injected screw compressors can be made to operate reliably, they could be more efficient and therefore cheaper to operate. Unfortunately, to date, such machines have proved to be insufficiently reliable and not cost effective. This paper describes an investigation carried out to determine the current limitations of water injected screw compressor systems and how these could be overcome in the 15-315 kW power range and delivery pressures of 6-10 bar. Modern rotor profiles and approach to sealing and cooling allow reasonably inexpensive air end design. The prototype of the water injected screw compressor air system was built and tested for performance and reliability. The water injected compressor system was compared with the oil injected and oil free compressor systems of the equivalent size including the economic analysis based on the lifecycle costs. Based on the obtained results, it was concluded that water injected screw compressor systems could be designed to deliver clean air free of oil contamination with a better user value proposition than the oil injected or oil free screw compressor systems over the considered range of operations.

  6. Influence of Gamma Radiation on the Treatment of Sulfate Reducing Bacteria in the Injection Water Used for the Enhanced Oil Recovery

    International Nuclear Information System (INIS)

    The counts of sulfate reducing bacteria (SRB) in the water samples collected from the well head (formation water) and outlet of petroleum treatment plant (Produced water) in a petroleum field in middle delta- Egypt were determined. The data showed a low count of (SRB) in the collected formation water sample and there was an obvious increase in the bacterial counts which appeared in the produced water, that may reveal that the presence of appropriate conditions for the growth of (SRB) in the closed system in treatment plant. Two scale inhibitors were tested through jar test, the scale inhibitor I had maximum efficiency at 20 ppm, two SRB biocides were screened for their bactericidal activities. It was found that the biocides A was slightly superior in respect to the antibacterial efficacy compared to B in presence of 20 ppm scale inhibitor. These biocides were test for the study of the combined treatment with gamma radiation to maximize the efficiency on sulfate reducing bacteria using the minimum effective dose of both radiation and biocides to eliminate the negative impacts of the chemicals used and the radiation applied. The results demonstrated that, the lethal doses of biocides were (300 ppm) of biocides A or (400 ppm) of biocides B at 1 kGy irradiation dose. The treated produced water was evaluated in respect of enhanced oil recovery, the data showed increase of the recovery capacity by the irradiation and chemical treatment. This technology could be used for the water that are injected into reservoirs, and suitable for oil field and pipeline operators, and presented a viable bacteria control method

  7. Geochemical effects of CO2 injection on produced water chemistry at an enhanced oil recovery site in the Permian Basin of northwest Texas, USA: Preliminary geochemical and Li isotope results

    Science.gov (United States)

    Pfister, S.; Gardiner, J.; Phan, T. T.; Macpherson, G. L.; Diehl, J. R.; Lopano, C. L.; Stewart, B. W.; Capo, R. C.

    2014-12-01

    Injection of supercritical CO2 for enhanced oil recovery (EOR) presents an opportunity to evaluate the effects of CO2 on reservoir properties and formation waters during geologic carbon sequestration. Produced water from oil wells tapping a carbonate-hosted reservoir at an active EOR site in the Permian Basin of Texas both before and after injection were sampled to evaluate geochemical and isotopic changes associated with water-rock-CO2 interaction. Produced waters from the carbonate reservoir rock are Na-Cl brines with TDS levels of 16.5-34 g/L and detectable H2S. These brines are potentially diluted with shallow groundwater from earlier EOR water flooding. Initial lithium isotope data (?7Li) from pre-injection produced water in the EOR field fall within the range of Gulf of Mexico Coastal sedimentary basin and Appalachian basin values (Macpherson et al., 2014, Geofluids, doi: 10.1111/gfl.12084). Pre-injection produced water 87Sr/86Sr ratios (0.70788-0.70795) are consistent with mid-late Permian seawater/carbonate. CO2 injection took place in October 2013, and four of the wells sampled in May 2014 showed CO2 breakthrough. Preliminary comparison of pre- and post-injection produced waters indicates no significant changes in the major inorganic constituents following breakthrough, other than a possible drop in K concentration. Trace element and isotope data from pre- and post-breakthrough wells are currently being evaluated and will be presented.

  8. Water issues associated with heavy oil production.

    Energy Technology Data Exchange (ETDEWEB)

    Veil, J. A.; Quinn, J. J.; Environmental Science Division

    2008-11-28

    Crude oil occurs in many different forms throughout the world. An important characteristic of crude oil that affects the ease with which it can be produced is its density and viscosity. Lighter crude oil typically can be produced more easily and at lower cost than heavier crude oil. Historically, much of the nation's oil supply came from domestic or international light or medium crude oil sources. California's extensive heavy oil production for more than a century is a notable exception. Oil and gas companies are actively looking toward heavier crude oil sources to help meet demands and to take advantage of large heavy oil reserves located in North and South America. Heavy oil includes very viscous oil resources like those found in some fields in California and Venezuela, oil shale, and tar sands (called oil sands in Canada). These are described in more detail in the next chapter. Water is integrally associated with conventional oil production. Produced water is the largest byproduct associated with oil production. The cost of managing large volumes of produced water is an important component of the overall cost of producing oil. Most mature oil fields rely on injected water to maintain formation pressure during production. The processes involved with heavy oil production often require external water supplies for steam generation, washing, and other steps. While some heavy oil processes generate produced water, others generate different types of industrial wastewater. Management and disposition of the wastewater presents challenges and costs for the operators. This report describes water requirements relating to heavy oil production and potential sources for that water. The report also describes how water is used and the resulting water quality impacts associated with heavy oil production.

  9. Air injection low temperature oxidation process for enhanced oil recovery from light oil reservoirs

    International Nuclear Information System (INIS)

    This paper represents EOR (Enhanced Oil Recovery) methods to recover unswept oil from depleted light oil reservoirs. The essential theme here is the removal of oxygen at LTO (Low Temperature Oxidation) from the injected air for a light oil reservoir by means of some chemical reactions occurring between oil and oxygen. In-situ combustion process, HTO (High Temperature Oxidation) is not suitable for deep light oil reservoirs. In case of light oil reservoirs LTO is more suitable to prevail as comparative to HTO. Few laboratory experimental results were obtained from air injection process, to study the LTO reactions. LTO process is suitable for air injection rate in which reservoir has sufficiently high temperature and spontaneous reaction takes place. Out comes of this study are the effect of LTO reactions in oxygen consumption and the recovery of oil. This air injection method is economic compared to other EOR methods i.e. miscible hydrocarbon gas, nitrogen, and carbon dioxide flooding etc. This LTO air injection process is suitable for secondary recovery methods where water flooding is not feasible due to technical problems. (author)

  10. Cooling of oil injected screw compressors by oil atomisation

    International Nuclear Information System (INIS)

    This paper addresses the effect of oil atomisation in an oil-injected screw compressor. A test rig was built to assess the performance of different types of atomisers. Atomisers varying from fine atomisation to coarse atomisation were tested. Experiments on the test rig show that lowering the oil droplet diameter results in a considerably higher heat transfer. Growing oil flow rate, also gives a better cooling effectiveness. In parallel with the experiments, a thermodynamic model is developed by which the compression process can be calculated for every degree of revolution of the male-rotor. This way the influence of cooling oil temperature, cooling oil mass flow rate and injection point can be analysed. Having a better heat transfer effectiveness does not give a considerable gain in specific work. Lowering oil temperature gives better results, while changing the oil flow rate only gives small gains. Furthermore it is shown that cooling oil coming from the bearings has a negative influence on the performance. This paper shows that trying to reach isothermal compression through oil atomisation is not possible. The importance of the cooling effectiveness in the thermodynamic process is too small to have a significant influence

  11. Aerobic biological treatment of produced water from oil production

    OpenAIRE

    Knutsen, Trine

    2011-01-01

    Produced water is the largest waste stream generated from the oil and gas industry. Water of varying quantities is always produced along with oil and has to be separated from the oil. The amount of produced water generated generally increases as the oil field gets older, because more water has to be injected into the reservoir in order to force the oil out. The produced water can either be injected back into the reservoirs or be treated, typically by floatation units or hydrocyclones, and eve...

  12. Production of light oil by injection of hot inert gas

    Science.gov (United States)

    Ruidas, Bidhan C.; Ganguly, Somenath

    2015-07-01

    Hot inert gas, when injected into an oil reservoir is capable of generating a vaporization-condensation drive and as a consequence, a preferential movement of the lighter components to the production well. This form of displacement is an important unit mechanism in hot flue-gas injection, or in thermal recovery from a watered-out oil reservoir. This article presents the movement of heat front vis-à-vis the changes in the saturation profile, and the gas-phase composition. The plateau in the temperature profile due to the exchange of latent heat, and the formation of water bank at the downstream are elaborated. The broadening of the vaporization-condensation zone with continued progression is discussed. The effect of inert gas temperature on the cumulative production of oil is reviewed. The results provide insight to the vaporization-condensation drive as a stand-alone mechanism. The paper underscores the relative importance of this mechanism, when operated in tandem with other processes in improved oil recovery and CO2 sequestration.

  13. Measuring and Modeling the Displacement of Connate Water in Chalk Core Plugs during Water Injection

    DEFF Research Database (Denmark)

    Korsbech, Uffe C C; Aage, Helle Karina

    2006-01-01

    The movement of connate water spiked with gamma emitting 22Na was studied during laboratory water flooding of oil saturated chalk from a North Sea oil reservoir. Using a one dimensional gamma monitoring technique is was observed that connate water is piled-up at the front of the injection water and forms a mixed water bank with almost 100% connate water in the front behind which a gradual transition to pure injection water occurs. This result underpins log interpretations from waterflooded chalk reservoirs. An ad hoc model was set up by use of the results, and the process was examined theoretically at a larger scale.

  14. Acetate Production from Oil under Sulfate-Reducing Conditions in Bioreactors Injected with Sulfate and Nitrate

    OpenAIRE

    Callbeck, Cameron M.; Agrawal, Akhil; Voordouw, Gerrit

    2013-01-01

    Oil production by water injection can cause souring in which sulfate in the injection water is reduced to sulfide by resident sulfate-reducing bacteria (SRB). Sulfate (2 mM) in medium injected at a rate of 1 pore volume per day into upflow bioreactors containing residual heavy oil from the Medicine Hat Glauconitic C field was nearly completely reduced to sulfide, and this was associated with the generation of 3 to 4 mM acetate. Inclusion of 4 mM nitrate inhibited souring for 60 days, after wh...

  15. Intramuscular injection of "site enhancement oil" : forensic considerations

    DEFF Research Database (Denmark)

    Petersen, Maria Louise; Colville-Ebeling, Bonnie

    2015-01-01

    The use of intramuscular injection of foreign substances for aesthetic purposes is well known. Complications are usually local to the site of injection but can be potentially lethal. Here, we present a case of "site enhancement oil" use in a 42-year-old man who died from asphyxia due to hanging. Macroscopic and microscopic changes as well as computed tomographic changes in injected musculature are described and the potentially lethal adverse effects after site enhancement oil use are warranted.

  16. Effect Of Hot Water Injection On Sandstone Permeability

    DEFF Research Database (Denmark)

    Rosenbrand, Esther; Fabricius, Ida Lykke

    2012-01-01

    The seasonal imbalance between supply and demand of renewable energy requires temporary storage, which can be achieved by hot water injection in warm aquifers. This requires that the permeability and porosity of the aquifer are not reduced significantly by heating. We present an overview of published results regarding the effect of temperature on sandstone permeability. These tests are performed with mineral oil, nitrogen gas, distilled water and solutions of NaCl, KCl, CaCl2 as well as brines t...

  17. Scale Formation Due to Water Injection in Berea Sandstone Cores

    OpenAIRE

    A.B.B. Merdhah; A.A.M. Yassin

    2009-01-01

    This study was conducted to investigate the permeability reduction caused by deposition of calcium, strontium and barium sulfates in Berea sandstone cores from mixing of injected Malaysian sea waters (Angsi and Barton) and formation water that contained high concentration of calcium, barium and strontium ions at various temperatures (60-90°C) and differential pressures (75-100 psig). The solubility of common oil field scales formed and how their solubilities were affected by changes in salini...

  18. Produced water management - clean and safe oil and gas production

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    The conference contains 22 presentations on topics within pollution sources and abatement, discharge reductions, water analysis and monitoring, water production, treatment and injection, enhanced recovery, condensate water, produced water markets, separation technologies for oil/gas/condensate and water, oil removal from solids, environmental risks of oil and gas production and environmental impacts on ecosystems and fisheries. Some oil field case histories are presented. The main focus is on the northern areas such as the North Sea, the north Atlantic Ocean and the Barents Sea, and technological aspects (tk)

  19. Produced water management - clean and safe oil and gas production

    International Nuclear Information System (INIS)

    The conference contains 22 presentations on topics within pollution sources and abatement, discharge reductions, water analysis and monitoring, water production, treatment and injection, enhanced recovery, condensate water, produced water markets, separation technologies for oil/gas/condensate and water, oil removal from solids, environmental risks of oil and gas production and environmental impacts on ecosystems and fisheries. Some oil field case histories are presented. The main focus is on the northern areas such as the North Sea, the north Atlantic Ocean and the Barents Sea, and technological aspects (tk)

  20. Injection of heavy fuel oil into the blast furnace

    Energy Technology Data Exchange (ETDEWEB)

    Paloposki, T. [Helsinki Univ. of Technology, Otaniemi (Finland); Hakala, J.; Mannila, P.; Laukkanen, J. [Oulu Univ. (Finland)

    1996-12-31

    This study deals with the injection and combustion of heavy fuel oil in blast furnaces. The injection of the oil was studied experimentally in a small-scale test rig. The combustion of the oil was analysed with a commercial computer program for flow and combustion simulations. Results from computer simulations show that the combustion of the oil can be improved by decreasing the size of the oil drops and by enhancing the mixing between the oil drops and the hot blast. The devolatilization rate of the oil mainly depends on the size of the oil drops. The combustion rate of the volatiles mainly depends on the effectiveness of turbulent mixing with combustion air. Methods to decrease the size of the oil drops were sought in the experimental part of the study. Experimental results show that the size of the oil drops increases with increasing mass flow rate of the oil and decreases with increasing velocity of the hot blast. Methods to improve the mixing between the oil drops and the hot blast are suggested but have not yet been experimentally tested. (author) (4 refs.)

  1. Homogeneous Charge Compression Ignition with Water Injection

    OpenAIRE

    Christensen, Magnus; Johansson, Bengt

    1999-01-01

    The use of water injection in a homogeneous charge compression ignition (HCCI) engine was experimentally investigated. The purpose of this study was to examine whether it is possible to control the ignition timing and slow down the rate of combustion with the use of water injection. The effects of different water flows, air/fuel ratios and inlet pressures were studied for three different fuels, iso-octane, ethanol and natural gas. It is possible to control the ignition timing in a narr...

  2. The Hot Water Oil Expulsion Technique for Geothermal Resources

    OpenAIRE

    Xuezhong Wang

    2012-01-01

    With the rapid development of Chinese petroleum industry, Oil production way of burning crude oil to produce steam need change. Heavy oil reservoir with thin layer or edgewater is unsuitable thermal recovery, electric heating leads to considerable electrical consumption, low injection water temperature decreases reservoir temperature and increased crude oil viscosity. The prolonged temperature difference break up reservoir pore throat cement and framework minerals. To improve high-capacity ch...

  3. Investigation of cyclic solvent injection process for heavy oil recovery

    Energy Technology Data Exchange (ETDEWEB)

    Ivory, J.; Chang, J.; Coates, R.; Forshner, K. [Alberta Research Council, Edmonton, AB (Canada)

    2009-07-01

    Numerical and experimental studies of a cyclic solvent injection (CSI) process were presented. The study formed part of a larger research program investigating the use of solvents as a follow-up process in Cold Lake and Lloydminster reservoirs pressure-depleted using cold heavy oil production with sand (CHOPS). The CSI process consisted of a primary production process followed by 6 solvent injection cycles using 28 per cent propane and 72 per cent carbon dioxide (CO{sub 2}). Results of the experiments demonstrated a recovery rate of 50 per cent using the CSI process. A numerical model was developed to represent the physical characteristics of the experiments. Non-equilibrium rate equations were used to simulate the delay in the solvent reaching equilibrium concentration as it dissolved or exsolved in the oil in response to pressure and gas phase composition changes. A history match of the primary production portion of the experiment was then obtained using a foamy oil model. The history match was used validate the numerical model of the CSI process. The study showed that the quantity of gas injected in an injection period was insensitive to oil phase diffusion coefficients, but sensitive to solvent solubility in oil, dissolution rates and gas phase relative permeability. It was concluded that gas injections are also sensitive to molar densities in the oil phase and capillary pressure. 20 refs., 40 figs.

  4. Quantification of the recovered oil and water fractions during water flooding laboratory experiments

    DEFF Research Database (Denmark)

    Katika, Konstantina; Halim, Amalia Yunita; Shapiro, Alexander; Fabricius, Ida Lykke

    2015-01-01

    During core flooding experiments where water is injected in residual oil saturated core plugs, the fluids are often produced in small amounts. Oil and water come out of the core and are collected in glass vials using a fraction collector. Quantification of these fluids is often difficult since the volume might be less than a few microliters. In this study, we approach the determination of the oil volumes in flooding effluents using predetermined amounts of the North Sea oil with synthetic seawat...

  5. Mechanical instability induced by water weakening in laboratory fluid injection tests

    Science.gov (United States)

    David, C.; Dautriat, J.; Sarout, J.; Delle Piane, C.; Menéndez, B.; Macault, R.; Bertauld, D.

    2015-06-01

    To assess water-weakening effects in reservoir rocks, previous experimental studies have focused on changes in the failure envelopes derived from mechanical tests conducted on rocks fully saturated either with water or with inert fluids. So far, little attention has been paid to the mechanical behavior during fluid injection under conditions similar to enhanced oil recovery operations. We studied the effect of fluid injection on the mechanical behavior of the weakly consolidated Sherwood sandstone in laboratory experiments. Our specimens were instrumented with 16 ultrasonic P wave transducers for both passive and active acoustic monitoring during loading and fluid injection to record the acoustic signature of fluid migration in the pore space and the development of damage. Calibration triaxial tests were conducted on three samples saturated with air, water, or oil. In a second series of experiments, water and inert oil were injected into samples critically loaded up to 80% or 70% of the dry or oil-saturated compressive strength, respectively, to assess the impact of fluid migration on mechanical strength and elastic properties. The fluids were injected with a low back pressure to minimize effective stress variations during injection. Our observations show that creep takes place with a much higher strain rate for water injection compared to oil injection. The most remarkable difference is that water injection in both dry and oil-saturated samples triggers mechanical instability (macroscopic failure) within half an hour whereas oil injection does not after several hours. The analysis of X-ray computed tomography images of postmortem samples revealed that the mechanical instability was probably linked to loss of cohesion in the water-invaded region.

  6. Radial oil injection applied to main engine bearings: evaluation of injection control rules

    DEFF Research Database (Denmark)

    Estupiñan, EA; Santos, Ilmar

    2012-01-01

    The performance of main bearings in a combustion engine affects key functions such as durability, noise and vibration. Thus, with the aim of reducing friction losses and vibrations between the crankshaft and the bearings, the work reported here evaluates different strategies for applying controllable radial oil injection to main crankshaft journal bearings. In an actively lubricated bearing, conventional hydrodynamic lubrication is combined with controllable hydrostatic lubrication, where the oil injection pressures can be modified depending on the operational conditions. In this study, the dynamic behaviour of the main bearing of a medium-size engine is theoretically analysed when the engine operates with controllable radial oil injection and four different injection control rules. The theoretical investigation is based on a single-cylinder combustion engine model. The performance of the actively lubricated bearing is compared with the performance of the conventional lubricated bearing, giving some insights into the minimum fluid film thickness, maximum fluid film pressure, friction losses and maximum vibration levels.

  7. Oil and rising water

    International Nuclear Information System (INIS)

    Middle Eastern oil producers have an obligation to future generations to tackle the causes of global warming. In the Middle East, we have a special need to pay attention to these warnings. As many of the countries of the region are low-lying and short of water, we are under threat from rising sea levels and desertification. Earlier this year the Intergovernmental Panel on Climate Change concluded that by the end of this century sea levels could rise by as much as 88 centimetres. This could flood not only coastal areas of the United Arab Emirates (UAE), but also much of the heavily populated Nile Delta in Egypt and the lower reaches of the Tigris and Euphrates river system in Iraq

  8. Investigation of oil injection into brine for the Strategic Petroleum Reserve : hydrodynamics and mixing experiments with SPR liquids.

    Energy Technology Data Exchange (ETDEWEB)

    Castaneda, Jaime N.; Cote, Raymond O.; Torczynski, John Robert; O' Hern, Timothy John

    2004-05-01

    An experimental program was conducted to study a proposed approach for oil reintroduction in the Strategic Petroleum Reserve (SPR). The goal was to assess whether useful oil is rendered unusable through formation of a stable oil-brine emulsion during reintroduction of degassed oil into the brine layer in storage caverns. An earlier report (O'Hern et al., 2003) documented the first stage of the program, in which simulant liquids were used to characterize the buoyant plume that is produced when a jet of crude oil is injected downward into brine. This report documents the final two test series. In the first, the plume hydrodynamics experiments were completed using SPR oil, brine, and sludge. In the second, oil reinjection into brine was run for approximately 6 hours, and sampling of oil, sludge, and brine was performed over the next 3 months so that the long-term effects of oil-sludge mixing could be assessed. For both series, the experiment consisted of a large transparent vessel that is a scale model of the proposed oil-injection process at the SPR. For the plume hydrodynamics experiments, an oil layer was floated on top of a brine layer in the first test series and on top of a sludge layer residing above the brine in the second test series. The oil was injected downward through a tube into the brine at a prescribed depth below the oil-brine or sludge-brine interface. Flow rates were determined by scaling to match the ratio of buoyancy to momentum between the experiment and the SPR. Initially, the momentum of the flow produces a downward jet of oil below the tube end. Subsequently, the oil breaks up into droplets due to shear forces, buoyancy dominates the flow, and a plume of oil droplets rises to the interface. The interface was deflected upward by the impinging oil-brine plume. Videos of this flow were recorded for scaled flow rates that bracket the equivalent pumping rates in an SPR cavern during injection of degassed oil. Image-processing analyses were performed to quantify the penetration depth and width of the oil jet. The measured penetration depths were shallow, as predicted by penetration-depth models, in agreement with the assumption that the flow is buoyancy-dominated, rather than momentum-dominated. The turbulent penetration depth model overpredicted the measured values. Both the oil-brine and oil-sludge-brine systems produced plumes with hydrodynamic characteristics similar to the simulant liquids previously examined, except that the penetration depth was 5-10% longer for the crude oil. An unexpected observation was that centimeter-size oil 'bubbles' (thin oil shells completely filled with brine) were produced in large quantities during oil injection. The mixing experiments also used layers of oil, sludge, and brine from the SPR. Oil was injected at a scaled flow rate corresponding to the nominal SPR oil injection rates. Injection was performed for about 6 hours and was stopped when it was evident that brine was being ingested by the oil withdrawal pump. Sampling probes located throughout the oil, sludge, and brine layers were used to withdraw samples before, during, and after the run. The data show that strong mixing caused the water content in the oil layer to increase sharply during oil injection but that the water content in the oil dropped back to less than 0.5% within 16 hours after injection was terminated. On the other hand, the sediment content in the oil indicated that the sludge and oil appeared to be well mixed. The sediment settled slowly but the oil had not returned to the baseline, as-received, sediment values after approximately 2200 hours (3 months). Ash content analysis indicated that the sediment measured during oil analysis was primarily organic.

  9. Hydrocarbons in hens injected with inactivated oil adjuvant vaccine

    Energy Technology Data Exchange (ETDEWEB)

    Franchini, A.; Piretti, M.V.; Tubertini, O.; Govoni, S.; Sapigni, R.

    1984-12-01

    The radioactivity of different organs and tissues of laying hens injected with inactivated oil adjuvant vaccine containing (n-1-/sup 14/C) octadecane was measured. It was shown that the hydrocarbons injected with the vaccination diffuse in relatively short periods of time to all the tissues, especially to those of the organs with greater blood supply, and that the hydrocarbons are largely eliminated by means of the eggs.

  10. Hydrocarbons in hens injected with inactivated oil adjuvant vaccine

    International Nuclear Information System (INIS)

    The radioactivity of different organs and tissues of laying hens injected with inactivated oil adjuvant vaccine containing [n-1-14C] octadecane was measured. It was shown that the hydrocarbons injected with the vaccination diffuse in relatively short periods of time to all the tissues, especially to those of the organs with greater blood supply, and that the hydrocarbons are largely eliminated by means of the eggs

  11. Bubble scrub : process aims to reduce oil content and dispose of solids in produced water

    Energy Technology Data Exchange (ETDEWEB)

    Harrison, L.

    2008-03-15

    The oil and water separation processes used by the petroleum industry typically leave behind between 5000 and 30,000 parts per million of oil in its produced water. The water is then injected back into the ground or disposed of in tailings ponds. This article described a water-oil remediation technology designed to reduce the hydrocarbon content in injected water to less than 5 parts per million. The process used aeration in a tank configuration that injected gas into the produced water. The aeration process created micron-sized gas bubbles that super-saturated the produced water in order to break the oil-water interfaces. A prototype unit has been designed to process 1000 bbls per day of water-oil mixture and is currently being used by an Alberta producer. It was concluded that the new system will help to reduce the massive amounts of water used in oil sands production. 1 fig.

  12. Pachometry before and after vitrectomy with silicone oil injection

    DEFF Research Database (Denmark)

    Buch, Helena; Nielsen, N V

    1999-01-01

    PURPOSE: To evaluate differences in central corneal thickness (CCT) before and after vitrectomy with injection of silicone oil as vitreous substitution material in order to determine whether silicone oil causes more frequent and/or pronounced corneal decompensation than other substitution materials. METHODS: CCT was measured by ultrasonic pachometry in 42 eyes. 25 eyes received injection of silicone oil and 17 eyes C3F8, atmospheric air or saline. Measurements were performed 24 hours pre operatively, during anaesthesia pre operatively and 24 hours, 48 hours and five months post operatively. RESULTS: A progressive central corneal thickening could be demonstrated in both groups. Eyes which received silicone oil showed maximum CCT increase of 0.083 mm (14.1%) 48 hours post operatively. At follow-up CCT had decreased to baseline value in both groups. Silicone oil did not induce CCT changes that were significantly different from those induced by other substitution materials. CONCLUSION: Silicone oil injection in detachment surgery induces reversible corneal decompensation to the same degree as other substitution materials within the first five months post operatively.

  13. Distribution of Complex Chemicals in Oil-Water Systems

    DEFF Research Database (Denmark)

    Riaz, Muhammad

    2011-01-01

    The deepwater energy sector represents one of the major growth areas of the oil and gas industry today. In order to meet the challenges of hydrate formation, corrosion, scaling and foaming the oil and gas industry uses many chemicals and their use has increased significantly over the years. In order to inhibit gas hydrate formation in subsea pipelines monoethylene glycol (MEG) and methanol are injected in large amounts. It is important to know the distribution of these chemicals in oil and water...

  14. Effects of nitrate injection on microbial enhanced oil recovery and oilfield reservoir souring.

    Science.gov (United States)

    da Silva, Marcio Luis Busi; Soares, Hugo Moreira; Furigo, Agenor; Schmidell, Willibaldo; Corseuil, Henry Xavier

    2014-11-01

    Column experiments were utilized to investigate the effects of nitrate injection on sulfate-reducing bacteria (SRB) inhibition and microbial enhanced oil recovery (MEOR). An indigenous microbial consortium collected from the produced water of a Brazilian offshore field was used as inoculum. The presence of 150 mg/L volatile fatty acids (VFA´s) in the injection water contributed to a high biological electron acceptors demand and the establishment of anaerobic sulfate-reducing conditions. Continuous injection of nitrate (up to 25 mg/L) for 90 days did not inhibit souring. Contrariwise, in nitrogen-limiting conditions, the addition of nitrate stimulated the proliferation of ?-Proteobacteria (including SRB) and the associated sulfide concentration. Denitrification-specific nirK or nirS genes were not detected. A sharp decrease in water interfacial tension (from 20.8 to 14.5 mN/m) observed concomitantly with nitrate consumption and increased oil recovery (4.3 % v/v) demonstrated the benefits of nitrate injection on MEOR. Overall, the results support the notion that the addition of nitrate, at this particular oil reservoir, can benefit MEOR by stimulating the proliferation of fortuitous biosurfactant-producing bacteria. Higher nitrate concentrations exceeding the stoichiometric volatile fatty acid (VFA) biodegradation demands and/or the use of alternative biogenic souring control strategies may be necessary to warrant effective SRB inhibition down gradient from the injection wells. PMID:25149457

  15. Water injection device of cooling water and nuclear reactor

    International Nuclear Information System (INIS)

    A jet pump is disposed to a water injection flow channel below a pressure accumulation vessel incorporating cooling water and pressurized gases. A driving water nozzle in the jet pump is connected to a driving water flow channel having an opening below the liquid surface of cooling water in the pressure accumulation vessel. A sucking channel in communication with the diffuser guide portion of the jet pump is disposed to the bottom of the pressure accumulation vessel. Upon reactor accident, cooling water in the driving water channel is jetted from the driving water nozzle to a throat of the diffuser of the jet pump. With such a procedure, cooling water in the sucking flow channel is sucked into the throat of the diffuser and mixed with the cooling water from the driving water nozzle. As a result, a great amount of cooling water flows to the water injection channel and is injected into a reactor pressure vessel. If the water level in the pressure accumulation vessel is reduced lower than the opening of the driving water flow channel, the operation of the jet pump is stopped. The flow rate of the water injection is changed to small amount only from the sucking flow channel by the stoppage of the jet pump. (I.N.)

  16. Microbially Enhanced Oil Recovery by Sequential Injection of Light Hydrocarbon and Nitrate in Low- And High-Pressure Bioreactors.

    Science.gov (United States)

    Gassara, Fatma; Suri, Navreet; Stanislav, Paul; Voordouw, Gerrit

    2015-10-20

    Microbially enhanced oil recovery (MEOR) often involves injection of aqueous molasses and nitrate to stimulate resident or introduced bacteria. Use of light oil components like toluene, as electron donor for nitrate-reducing bacteria (NRB), offers advantages but at 1-2 mM toluene is limiting in many heavy oils. Because addition of toluene to the oil increased reduction of nitrate by NRB, we propose an MEOR technology, in which water amended with light hydrocarbon below the solubility limit (5.6 mM for toluene) is injected to improve the nitrate reduction capacity of the oil along the water flow path, followed by injection of nitrate, other nutrients (e.g., phosphate) and a consortium of NRB, if necessary. Hydrocarbon- and nitrate-mediated MEOR was tested in low- and high-pressure, water-wet sandpack bioreactors with 0.5 pore volumes of residual oil in place (ROIP). Compared to control bioreactors, those with 11-12 mM of toluene in the oil (gained by direct addition or by aqueous injection) and 80 mM of nitrate in the aqueous phase produced 16.5 ± 4.4% of additional ROIP (N = 10). Because toluene is a cheap commodity chemical, HN-MEOR has the potential to be a cost-effective method for additional oil production even in the current low oil price environment. PMID:26406569

  17. Optimization of injection timing and injection pressure of a DI diesel engine fueled with preheated rice bran oil

    OpenAIRE

    R. Raghu1, G. Ramadoss

    2011-01-01

    In the present study experiments were carried out in a constant speed, stationary direct injection diesel engine and the performance was investigated. Initially the engine fueled with diesel, rice bran biodiesel (methyl ester), raw rice bran oil and preheated rice bran oil with standard injection timing and injection pressures at different load conditions and the performances were compared. With the help of a heat exchanger and using the exhaust gases, the rice bran oil was preheated. It was ...

  18. Application of log-inject-log in Granny's Creek oil field

    Energy Technology Data Exchange (ETDEWEB)

    Ahmad, M.M.; Ovies, S.L.

    1981-10-01

    The purpose of this study was to apply principles of the log-inject-log technique through utilization of the thermal neutron decay time log (TDT) to ascertain resevoir parameters necessary for an evaluation of a perspective secondary/tertiary flood. This technique provides in-situ measurements for determination of residual oil saturation and estimates of bulk volume movable oil and gas saturation. To achieve this purpose log-inject-log was employed in conjunction with open hole log data in a heterogeneous, pressure depleted Big Injun Sandstone Reservoir. This study represents the first application of the log-inject-log method in the Appalachian Basin. The log-inject-log process required multiple TDT logging runs following alternate injection of low and high salinity waters. Well site procedures for acquisition of the necessary raw data are presented with a description of the interpretation model. A computer analysis of the data used open hole log measurements as a data base for reservoir characteristics needed to obtain residual oil saturation from the log-inject-log data.

  19. A fast alternative to core plug tests for optimising injection water salinity for EOR

    DEFF Research Database (Denmark)

    Hassenkam, Tue; Andersson, Martin Peter; Hilner, Emelie Kristin Margareta; Matthiesen, Jesper; Dobberschütz, Sören; Dalby, Kim Nicole; Bovet, Nicolas Emile; Stipp, Susan Louise Svane; Salino, P.; Reddick, C.; Collins, I. R.

    2014-01-01

    Core tests have demonstrated that decreasing the salinity of injection water can increase oil recovery. Although recovery is enhanced by simply decreasing salt content, optimising injection water salinty would offer a clear economic advantage for several reasons. Too low salinity risks swelling of the clays which would lead to permanent reservoir damage but evidence of effectiveness at moderate salinity would offer the opportunity to dispose of produced water. The goal is to define boundary cond...

  20. Optimizing geologic CO2 sequestration by injection in deep saline formations below oil reservoirs

    International Nuclear Information System (INIS)

    The purpose of this research is to present a best-case paradigm for geologic CO2 storage: CO2 injection and sequestration in saline formations below oil reservoirs. This includes the saline-only section below the oil-water contact (OWC) in oil reservoirs, a storage target neglected in many current storage capacity assessments. This also includes saline aquifers (high porosity and permeability formations) immediately below oil-bearing formations. While this is a very specific injection target, we contend that most, if not all, oil-bearing basins in the US contain a great volume of such strata, and represent a rather large CO2 storage capacity option. We hypothesize that these are the best storage targets in those basins. The purpose of this research is to evaluate this hypothesis. We quantitatively compared CO2 behavior in oil reservoirs and brine formations by examining the thermophysical properties of CO2, CO2-brine, and CO2-oil in various pressure, temperature, and salinity conditions. In addition, we compared the distribution of gravity number (N), which characterizes a tendency towards buoyancy-driven CO2 migration, and mobility ratio (M), which characterizes the impeded CO2 migration, in oil reservoirs and brine formations. Our research suggests competing advantages and disadvantages of CO2 injection in oil reservoirs vs. brine formations: (1) CO2 solubility in oil is significantly greater than in brine (over 30 times); (2) the tendency of buoyancy-driven CO2 migration is smaller in oil reservoirs because density contrast between oil and CO2 is smaller than it between brine and oil (the approximate density contrast between CO2 and crude oil is ?100 kg/m3 and between CO2 and brine is ?350 kg/m3); (3) the increased density of oil and brine due to the CO2 dissolution is not significant (about 7-15 kg/m3); (4) the viscosity reduction of oil due to CO2 dissolution is significant (from 5790 to 98 mPa s). We compared these competing properties and processes by performing numerical simulations. Results suggest that deep saline CO2 injection immediately below oil formations reduces buoyancy-driven CO2 migration and, at the same time, minimizes the amount of mobile CO2 compared to conventional deep saline CO2 injection (i.e., CO2 injection into brine formations not below oil-bearing strata). Finally, to investigate practical aspects and field applications of this injection paradigm, we characterized oil-bearing formations and their thickness (capacity) as a component of the Southwest Regional Partnership on Carbon Sequestration (SWP) field deployments. The field-testing program includes specific sites in Utah, New Mexico, Wyoming, and western Texas of the United States. (author)

  1. Optimizing geologic CO2 sequestration by injection in deep saline formations below oil reservoirs

    International Nuclear Information System (INIS)

    The purpose of this research is to present a best-case paradigm for geologic CO2 storage: CO2 injection and sequestration in saline formations below oil reservoirs. This includes the saline-only section below the oil-water contact (OWC) in oil reservoirs, a storage target neglected in many current storage capacity assessments. This also includes saline aquifers (high porosity and permeability formations) immediately below oil-bearing formations. While this is a very specific injection target, we contend that most, if not all, oil-bearing basins in the US contain a great volume of such strata, and represent a rather large CO2 storage capacity option. We hypothesize that these are the best storage targets in those basins. The purpose of this research is to evaluate this hypothesis. We quantitatively compared CO2 behavior in oil reservoirs and brine formations by examining the thermophysical properties of CO2, CO2-brine, and CO2-oil in various pressure, temperature, and salinity conditions. In addition, we compared the distribution of gravity number (N), which characterizes a tendency towards buoyancy-driven CO2 migration, and mobility ratio (M), which characterizes the impeded CO2 migration, in oil reservoirs and brine formations. Our research suggests competing advantages and disadvantages of CO2 injection in oil reservoirs vs. brine formations: (1) CO2 solubility in oil is significantly greater than in brine (over 30 times); (2) the tendency of buoyancy-driven CO2 migration is smaller in oil reservoirs because density contrast between oil and CO2 is smaller than it between brine and oil (the approximate density contrast between CO2 and crude oil is ?100 kg/m3 and between CO2 and brine is ?350 kg/m3); (3) the increased density of oil and brine due to the CO2 dissolution is not significant (about 7-15 kg/m3); (4) the viscosity reduction of oil due to CO2 dissolution is significant (from 5790 to 98 mPa s). We compared these competing properties and processes by performing numerical simulations. Results suggest that deep saline CO2 injection immediately below oil formations reduces buoyancy-driven CO2 migration and, at the same time, minimizes the amount of mobile CO2 compared to conventional deep saline CO2 injection (i.e., CO2 injection into brine formations not below oil-bearing strata). Finally, to investigate practical aspects and field applications of this injection paradigm, we characterized oil-bearing formations and their thickness (capacity) as a component of the Southwest Regional Partnership on Carbon Sequestration (SWP) field deployments. The field-testing program includes specific sites in Utah, New Mexico, Wyoming, and western Texas of the United States.

  2. Muscle enhancement using intramuscular injections of oil in bodybuilding

    DEFF Research Database (Denmark)

    Schäfer, Ch. N.; Hvolris, Jørgen Jesper; Karlsmark, Tonny; Plambech, M

    2012-01-01

    BACKGROUND: Self-administered intramuscular injection of site enhancement oil (SEO) is a cosmetic and performance-enhancing procedure used to reshape muscles in the bodybuilder subculture, but its consequences and complications are only sporadically described. Methods: A systematic search in MEDLINE and EMBASE databases during the spring of 2009 and 2010. Internet searches were performed, and bodybuilder pharmacopoeias were consulted to describe SEO use and the clinical complications known. Resu...

  3. Water Local Volume Fraction on Oil in Water Dispersion

    OpenAIRE

    siti aslina hussain; Xiao Y. Xu; Geoffrey F. Hewitt

    2008-01-01

    The phase distribution of water-oil flows was studied experimentally from a separated flow without mixer to a oil in water or water in oil dispersed in horizontal tubes. Under most conditions the pattern was oil continuous in water dispersed or water continuous in oil dispersed flow continuously and there is entrainment in the form of drops of phase into the other. The investigations were carried out through the cross-sectional phase distribution in the flow of mixtures of...

  4. Performance indicators for water injections projects; Indicadores de desempenho para projetos de injecao de agua

    Energy Technology Data Exchange (ETDEWEB)

    Hastenreiter, Livia; Correa, Antonio C. de F.; Mendes, Roberta A. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil)

    2008-07-01

    Currently, the water injection process into oil reservoirs is the method of secondary recovery more important to increase the recovery factor. Thus, it is necessary an efficient project management, with constant data acquisitions and interpretation. This paper aims to present some indicators to evaluate the performance of water injection projects. Each indicator is presented based on a methodology that transforms the data collected in information. The results are expressed in graphical form for better viewing of the indicators measurement. (author)

  5. STUDYING OF THE EFFECTIVE PARAMETERS ON ENHANCED HEAVY OIL RECOVERY BY STEAM INJECTION

    Directory of Open Access Journals (Sweden)

    Kh.Mohamadbeigy

    2006-06-01

    Full Text Available High viscosity of some crude oil makes difficult to recover with primary or secondary production methods. Therefore, thermal oil recovery techniques are recommended for the Enhanced Oil Recovery (EOR of heavy oil. In this experimental study, steam injection was used to investigate the effectiveness parameters on heavy oil production rate. The result is shown that, by increasing pressure, steam reaches the breakthrough point sooner, but recovery decreases. If the oils are a little different in viscosity, recovery in the light oil is more than that in heavy oil. Also in the highly viscous oils and light oils, recovery in the heavy oil is much higher than in light oil.

  6. The shift of microbial population composition accompanying the injected water flowing in the water-flooding petroleum reservoirs

    Directory of Open Access Journals (Sweden)

    P. K. Gao

    2014-12-01

    Full Text Available In water-flooding petroleum reservoir, microbial populations in injected water are expected to migrate into oil-bearing strata and reach production wells. To demonstrate this, we firstly investigated microbial compositions in a homogeneous sandstone reservoir. The results indicated that the injected water harbored more microbial cells than produced water, and the shared populations and their abundance accounted for a minor fraction in injected water, while dominated in produced water, suggesting that most populations in injected water did hardly reach production wells in this reservoir. We further investigated microbial communities in water samples collected from wellhead and downhole of injection wells and production wells in a heterogeneous conglomerate reservoir. The results indicated that, except for the community reconstruction mainly resulted from dissolved oxygen, most populations were simultaneously detected in the wellhead and downhole of injection wells and production wells, suggesting that most microbial populations in injected water reached the production wells. This study suggest that microbial populations in injected water can pass through reservoir strata and reach production wells, but the reservoir heterogeneity, interwell spacing, sieve effect of strata and dissolved oxygen exert significant influence on microbial migration and distribution in reservoirs.

  7. The shift of microbial population composition accompanying the injected water flowing in the water-flooding petroleum reservoirs

    Science.gov (United States)

    Gao, P. K.; Li, G. Q.; Tian, H. M.; Wang, Y. S.; Sun, H. W.; Ma, T.

    2014-12-01

    In water-flooding petroleum reservoir, microbial populations in injected water are expected to migrate into oil-bearing strata and reach production wells. To demonstrate this, we firstly investigated microbial compositions in a homogeneous sandstone reservoir. The results indicated that the injected water harbored more microbial cells than produced water, and the shared populations and their abundance accounted for a minor fraction in injected water, while dominated in produced water, suggesting that most populations in injected water did hardly reach production wells in this reservoir. We further investigated microbial communities in water samples collected from wellhead and downhole of injection wells and production wells in a heterogeneous conglomerate reservoir. The results indicated that, except for the community reconstruction mainly resulted from dissolved oxygen, most populations were simultaneously detected in the wellhead and downhole of injection wells and production wells, suggesting that most microbial populations in injected water reached the production wells. This study suggest that microbial populations in injected water can pass through reservoir strata and reach production wells, but the reservoir heterogeneity, interwell spacing, sieve effect of strata and dissolved oxygen exert significant influence on microbial migration and distribution in reservoirs.

  8. Radial oil injection applied to main engine bearings: evaluation of injection control rules

    DEFF Research Database (Denmark)

    Estupiñan, EA; Santos, Ilmar

    2012-01-01

    The performance of main bearings in a combustion engine affects key functions such as durability, noise and vibration. Thus, with the aim of reducing friction losses and vibrations between the crankshaft and the bearings, the work reported here evaluates different strategies for applying controllable radial oil injection to main crankshaft journal bearings. In an actively lubricated bearing, conventional hydrodynamic lubrication is combined with controllable hydrostatic lubrication, where the oi...

  9. Evaluating oil/water separators

    International Nuclear Information System (INIS)

    Four commercially available oil/water separators were tested at an oil refinery test facility. The separators were the Alfa-Laval OFPX 413 disk-stack centrifuge, the Conoco Vortoil hydrocyclone system, International Separation Technology's Intr-Septor 250, and a modified Flo Trend gravity separator. Each machine was tested against mixtures of salt water and crude oil, and mixtures of salt water and a water-in-oil emulsion. The impact on separator performance from simulated sea motion, and from the addition of emulsion breakers and debris to the influent, were also evaluated. The test equipment, instrumentation, analysis facilities, test plans, and procedures to conduct the tests are described, but test results are not reported. Recommendations for improved test procedures are included. The inability to accurately monitor flow rates was found to have the greatest negative impact on test performance and results. Aspects of the test program that worked well included the use of flexible and semi-rigid hoses for customizing the test setups, the use of modular and leased tanks, and the sea motion simulator swing table design. 3 refs., 2 tabs

  10. Experimental investigation of the effect of steam injection rate on recovery of an Iranian heavy oil reservoir using sand packed and core samples

    Energy Technology Data Exchange (ETDEWEB)

    Tabatabaei-Nejad, S.A.R. [Sahand University of Technology and Sahand Petroleum Research Center (Iran, Islamic Republic of)

    2011-07-01

    Heavy oils and tar sands reserves worldwide account for more than half of Earth's oil resources and, world-wide, these are primarily located in north and south America, Asia and the Middle East. Enhanced oil recovery techniques are a crucial aspect for these heavy oil reservoirs, the predominant one being the steam injection method. This presentation reports the results of an experimental investigation into the effect of the steam injection rate on oil efficiency recovery at an Iranian heavy oil reservoir. The steam injection method is briefly presented and an efficiency up to 50-60% in oil recovery is mentioned, depending on the operating temperature. Eleven tests were then conducted, with different steam injection rates, oil samples, and saturation pressures. Results show that an increased steam injection rate leads to a reduction of the steam-to-oil ratio and of the overall oil recovery time; it also requires a smaller volume of water for equivalent operation. In short, increase in the steam injection rate leads to better oil recovery efficiency in heavy oil reservoirs.

  11. Enhanced oil recovery by nanoparticles injection: Modeling and simulation

    KAUST Repository

    El-Amin, Mohamed

    2013-01-01

    In the present paper, a mathematical model and numerical simulation to describe the nanoparticles-water suspension imbibes into a water-oil two-phase flow in a porous medium is introduced. We extend the model to include the negative capillary pressure and mixed relative permeabilities correlations to fit with the mixed-wet system. Also, buoyancy and capillary forces as well as Brownian diffusion are considered. Throughout this investigation, we monitor the changing of the fluids and solid properties due to addition of the nanoparticles and check for possible enhancement of the oil recovery process using numerical experiments.

  12. Produced water from off-shore oil and gas production, a new challenge in marine pollution monitoring

    International Nuclear Information System (INIS)

    Produced water consists of water naturally present in the oil and gas reservoir (formation water), flood water previously injected into the formation, and/or, in the case of some gas production, condensed water. Produced water is part of the well stream together with oil and/or gas

  13. Can Oil Float Completely Submerged in Water?

    CERN Document Server

    Nath, Saurabh; Chatterjee, Souvick

    2013-01-01

    Droplet formation in a system of two or more immiscible fluids is a celebrated topic of research in the fluid mechanics community. In this work, we propose an innovative phenomenon where oil when injected drop-wise into a pool of water moves towards the air-water interface where it floats in a fully submerged condition. The configuration, however, is not stable and a slight perturbation to the system causes the droplet to burst and float in partially submerged condition. The droplet contour is analyzed using edge detection. Temporal variation of a characteristic length of the droplet is analyzed using MATLAB image processing. The constraint of small Bond Number established the assumption of lubrication regime in the thin gap. A brief theoretical formulation also showed the temporal variation of the gap thickness

  14. Hot-fluid injection into heavy oil reservoirs intercepted by a stationary vertical fracture

    Energy Technology Data Exchange (ETDEWEB)

    Agena, B.M.

    1986-01-01

    An analytical and a numerical model for the injection of hot fluid into stationary vertical fractures are developed. For both models, the fracture is assumed to have infinite conductivity and fully penetrate the reservoir thickness. The conductive heat flux in the overburden and underburden is considered one dimensional and symmetric with respect to the reservoir. The analytical model solves the energy equation in an infinite system with constant properties of the system and zero thermal conductivity in the reservoir. Fluid flow in the reservoir is considered elliptical which is physically more sound than the linear models described in the literature. The obtained solution for the temperature distribution is used to develop expressions for the thermal efficiency and oil rate and recovery. The numerical model involves the simultaneous solution of mass and energy balances for an oil-water system in two dimensions. The model utilizes the IMPES method of solution and suggests a new procedure for eliminating the saturations from the mass and energy balance equations. The relative permeabilities and enthalpies at the grid boundaries are shifted upstream in order to avoid possible oscillations in the solutions. The primary objective of this study is to (i) present a detailed description in the numerical and analytical models, (ii) analyze pressure response in the fracture and temperature distribution in the reservoir, (iii) study effects of injection conditions and fluid and reservoir characteristics on the performance of hot water injection, including oil recovery and thermal efficiency, and (iv) examine the analytical solution for a practical range of injection temperature, oil viscosity and reservoir permeability.

  15. Quantification of the recovered oil and water fractions during water flooding laboratory experiments

    DEFF Research Database (Denmark)

    Katika, Konstantina; Halim, Amalia Yunita

    2015-01-01

    During core flooding experiments where water is injected in residual oil saturated core plugs, the fluids are often produced in small amounts. Oil and water come out of the core and are collected in glass vials using a fraction collector. Quantification of these fluids is often difficult since the volume might be less than a few microliters. In this study, we approach the determination of the oil volumes in flooding effluents using predetermined amounts of the North Sea oil with synthetic seawater. The UV/visible spectroscopy method and low-field NMR spectrometry are compared for this determination, and an account of advantages and disadvantages of each method is given. Both methods are reproducible with high accuracy. The NMR method was capable of direct quantification of both oil and water fractions, while the UV/visible spectroscopy quantifies only the oil fraction using a standard curve.

  16. Scale Formation Due to Water Injection in Berea Sandstone Cores

    Directory of Open Access Journals (Sweden)

    A.B.B. Merdhah

    2009-01-01

    Full Text Available This study was conducted to investigate the permeability reduction caused by deposition of calcium, strontium and barium sulfates in Berea sandstone cores from mixing of injected Malaysian sea waters (Angsi and Barton and formation water that contained high concentration of calcium, barium and strontium ions at various temperatures (60-90°C and differential pressures (75-100 psig. The solubility of common oil field scales formed and how their solubilities were affected by changes in salinity and temperatures (40-90°C were also studied. The morphology and particle size of scaling crystals formed as shown by Scanning Electron Microscopy (SEM were also presented. The results showed that a large extent of permeability damage caused by calcium, strontium and barium sulfates that deposited on the rock pore surface. The rock permeability decline indicates the influence of the concentration of calcium, barium and strontium ions. At higher temperatures, the deposition of CaSO4 and SrSO4 scales increases and the deposition of BaSO4 scale decreases, since the solubilities of CaSO4 and SrSO4 scales decreases and the solubility of BaSO4 increases with increasing temperature. The deposition of CaSO4, SrSO4 and BaSO4 scales during flow of injection waters into porous media was shown by Scanning Electron Microscopy (SEM micrographs.

  17. Brine crude oil interactions at the oil-water interface

    DEFF Research Database (Denmark)

    Chakravarty, Krishna Hara; Fosbøl, Philip Loldrup; Thomsen, Kaj

    2015-01-01

    The impact of brine salinity and its ionic composition on oil displacement efficiency has been investigated extensively in recent years due to the potential of enhanced oil recovery (EOR). Wettability alterations through relative interactions at the mineral surface have been the basis of proposed mechanisms. The ion specific interaction between fines and polar fractions of crude oil at the oil-water interface has been less explored. In this study the relative affinity between different ions and ...

  18. Brine crude oil interactions at the oil-water interface

    DEFF Research Database (Denmark)

    Chakravarty, Krishna Hara; FosbØl, Philip Loldrup

    2015-01-01

    The impact of brine salinity and its ionic composition on oil displacement efficiency has been investigated extensively in recent years due to the potential of enhanced oil recovery (EOR). Wettability alterations through relative interactions at the mineral surface have been the basis of proposed mechanisms. The ion specific interaction between fines and polar fractions of crude oil at the oil-water interface has been less explored. In this study the relative affinity between different ions and the oil surface was determined. The experiments prove the importance of Ca2+, SO42-, and HPO42- ions in enhancing oil emulsion formation by increasing interactions between polar acids and brine solutions. The results propose the potential use of HPO42- ions in reservoirs having inactive mineral surfaces. The relative oil affinity of different ions including K+, Na+, Mg2+, and Ca2+ (cations), and Cl-, SO42-, HPO42-, and HCO3- (anions), were studied through gas chromatographic analysis. Crude oil from the North Sea was doped with various fractions of organic acids to mimic different polar behavior. Increased brine concentration showed up to 15% upsurge of polar fractions on the oil-water emulsion formation. During emulsion formation the relative interactions at the oil-water interface are proved to follow the Hofmeister series: K+oil. Experiments demonstrate that the brine solution can alter the micro forces at the oil-water interface, and this ion specific interaction leads to oil emulsion formation and thus reduces the interfacial viscoelasticity of the trapped oil. These results show significant correlation between oil emulsion formation and increased oil recovery. Copyright 2015; Society of Petroleum Engineers

  19. Did CO2 injection induce 2006-2011 earthquakes in the Cogdell oil field, Texas?

    Science.gov (United States)

    GAN, W.; Frohlich, C.

    2013-12-01

    Induced seismicity related to underground injection of liquids has been widely reported. However, earthquakes triggered by gas injection, particularly having magnitudes M3 and larger, haven't been observed. Davis and Pennington (1) concluded that earthquakes occurring 1974-1982 in the Cogdell oil field north of Snyder, TX were induced by water flooding for secondary recovery that took place between 1956 and 1982. Subsequently the National Earthquake Information Center (NEIC) reported no further seismicity between 1983 and 2005, but between 2006 and 2011 reported 18 earthquakes having magnitudes 3 and greater. In the present study we analyzed data recorded by six temporary seismograph stations deployed by the USArray program. We identified and carefully relocated 93 well-recorded earthquakes occurring between March 2009 and December 2010. Relocated epicenters occur within several NE-SW-trending linear clusters, with trends corresponding to nodal planes of regional focal mechanisms, possibly indicating the presence of previously unidentified subsurface faults. Moreover, both the rate and b value for the 2009-2011 activity differs from the values for earlier activity, possibly suggesting a different physical origin. We have evaluated data concerning injection and extraction of oil, water, and gas in the Cogdell field. Fluid injection doesn't explain the 2006-2011 earthquakes, especially as net volumes (injection minus extraction) are significantly less than in the 1957-1982 period, and don't appear to have undergone significant recent changes. However, since 2004 significant volumes of CO2 have been injected into the Cogdell fields. The timing of gas injection suggests it may have triggered the recent seismic activity. If so, this is the first reported instance where gas injection has triggered earthquakes having magnitudes M3 and larger. Further analysis may help to evaluate recent concerns about possible risks associated with large-scale carbon capture and storage as a strategy for managing climate change. 1. Davis SD, Pennington WD (1989) Induced seismic deformation in the Cogdell oil field of west Texas. Bull Seismol Soc Amer 79:1477-1495.

  20. STUDYING OF THE EFFECTIVE PARAMETERS ON ENHANCED HEAVY OIL RECOVERY BY STEAM INJECTION

    OpenAIRE

    Kh. Mohamadbeigy; M. Monavarian

    2006-01-01

    High viscosity of some crude oil makes difficult to recover with primary or secondary production methods. Therefore, thermal oil recovery techniques are recommended for the Enhanced Oil Recovery (EOR) of heavy oil. In this experimental study, steam injection was used to investigate the effectiveness parameters on heavy oil production rate. The result is shown that, by increasing pressure, steam reaches the breakthrough point sooner, but recovery decreases. If the oils are a little different i...

  1. The Influence of CO2 Solubility in Brine on Simulation of CO2 Injection into Water Flooded Reservoir and CO2 WAG

    DEFF Research Database (Denmark)

    Yan, Wei; Stenby, Erling Halfdan

    2010-01-01

    Injection of CO2 into depleted oil reservoirs is not only a traditional way to enhance oil recovery but also a relatively cheaper way to sequester CO2 underground since the increased oil production can offset some sequestration cost. CO2 injection process is often applied to water flooded reservoirs and in many situations alternating injection of water and CO2 is required to stabilize the injection front. Both scenarios involve a large amount of water, making CO2 solubility in brine, which is ar...

  2. Fast water oil spill response

    International Nuclear Information System (INIS)

    Of the many manuals currently available for oil spill response, few have any information on fast-water conditions even though just more than half of all oil spilled by volume in the United States between 1992 and 1997 happened in waterways with currents exceeding one knot. The Coast Guard recognized the absence of standard terminology that could be used for fast-water responses. For that reason, an initiative was undertaken to create a document that addresses only fast-water issues. Two major parts of the project were to provide information on deployment strategies and techniques to identify equipment that could improve recovery capabilities where existing systems do not work well. This paper described field demonstrations where boom deflectors and boom vanes were used. Efforts to increase the capability of booms and skimmers were also described. A field guide was developed for training and response purposes for spills in fast-water which makes it possible for on-scene commanders and area supervisors to define techniques and terminology for responders in the field. It is particularly useful for Coast Guard Marine Safety Units when working with Coast Guard operational units during an emergency response. 20 refs., 4 figs

  3. Performance and exhaust emission characteristics of direct-injection Diesel engine when operating on shale oil

    International Nuclear Information System (INIS)

    This article presents the comparative bench testing results of a naturally aspirated, four stroke, four cylinder, water cooled, direct injection Diesel engine when running on Diesel fuel and shale oil that is produced in Estonia from local oil shale. The purpose of this research is to investigate the possibility of practical usage of the shale oil as the alternative fuel for a high speed Diesel engine as well as to evaluate the combustion efficiency, brake specific fuel consumption, emission composition changes and the smoke opacity of the exhausts. Test results show that when fuelling a fully loaded engine with shale oil, the brake specific fuel consumption at the maximum torque and rated power is correspondingly higher by 12.3% and 20.4%. However, the brake thermal efficiencies do not differ widely and their maximum values remain equal to 0.36-0.37 for Diesel fuel and 0.32-0.33 for shale oil. The total nitrogen oxide emissions from the shale oil at engine partial loads remain considerably lower although when running at the maximum torque and rated power, the NOx emissions become correspondingly higher by 21.8% and 27.6%. The smoke opacity of the fully loaded engine at a wide range of speeds is lower by 30-35%, whereas the carbon monoxide and unburned hydrocarbon emissions in the exhausts at moderate and full load regimes do not undergo significant changes

  4. Geomechanics of subsurface water withdrawal and injection

    Science.gov (United States)

    Gambolati, Giuseppe; Teatini, Pietro

    2015-06-01

    Land subsidence and uplift, ground ruptures, and induced seismicity are the principal geomechanic effects of groundwater withdrawal and injection. The major environmental consequence of groundwater pumping is anthropogenic land subsidence. The first observation concerning land settlement linked to subsurface processes was made in 1926 by the American geologists Pratt and Johnson, who wrote that "the cause of subsidence is to be found in the extensive extraction of fluid from beneath the affected area." Since then, impressive progress has been made in terms of: (a) recognizing the basic hydrologic and geomechanic principles underlying the occurrence; (b) measuring aquifer compaction and ground displacements, both vertical and horizontal; (c) modeling and predicting the past and future event; and (d) mitigating environmental impact through aquifer recharge and/or surface water injection. The first milestone in the theory of pumped aquifer consolidation was reached in 1923 by Terzaghi, who introduced the principle of "effective intergranular stress." In the early 1970s, the emerging computer technology facilitated development of the first mathematical model of the subsidence of Venice, made by Gambolati and Freeze. Since then, the comprehension, measuring, and simulation of the occurrence have improved dramatically. More challenging today are the issues of ground ruptures and induced/triggered seismicity, which call for a shift from the classical continuum approach to discontinuous mechanics. Although well known for decades, anthropogenic land subsidence is still threatening large urban centers and deltaic areas worldwide, such as Bangkok, Jakarta, and Mexico City, at rates in the order of 10 cm/yr.

  5. Microbial diversity in long-term water-flooded oil reservoirs with different in situ temperatures in China

    OpenAIRE

    Fan Zhang; Yue-Hui She; Lu-Jun Chai; Banat, Ibrahim M.; Xiao-Tao Zhang; Fu-Chang Shu; Zheng-Liang Wang; Long-Jiang Yu; Du-Jie Hou

    2012-01-01

    Water-flooded oil reservoirs have specific ecological environments due to continual water injection and oil production and water recycling. Using 16S rRNA gene clone library analysis, the microbial communities present in injected waters and produced waters from four typical water-flooded oil reservoirs with different in situ temperatures of 25°C, 40°C, 55°C and 70°C were examined. The results obtained showed that the higher the in situ temperatures of the oil reservoirs is, the less the effec...

  6. Steam injection into water-saturated porous rock

    Scientific Electronic Library Online (English)

    J., Bruining; D., Marchesin; C.J., Van Duijn.

    Full Text Available We formulate conservation laws governing steam injection in a linear porous medium containing water. Heat losses to the outside are neglected. We find a complete and systematic description of all solutions of the Riemann problem for the injection of a mixture of steam and water into a water-saturate [...] d porous medium. For ambient pressure, there are three kinds of solutions, depending on injection and reservoir conditions. We show that the solution is unique for each initial data.

  7. Use of chemical additives with steam injection to increase oil recovery. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Handy, L.L.

    1984-09-01

    Surfactants and certain inorganic bases have been evaluated as possible chemical additives to improve performance of steamfloods. Special emphasis was given to chemicals which would reduce the residual oil saturation in regions flooded by hot water below the steam zone. Problems considered were the effect of prolonged exposure to steam temperature on the stability of petroleum sulfonates, the effect of temperature on surfactant adsorption and the effect of temperature on interfacial tensions. Methods were developed for measuring quantitatively the thermal stability of the aryl sulfonate class of surfactant. This class includes the petroleum sulfonates. The best of the surfactants evaluated in this study had marginal stability for use with steamfloods. The surfactants in combination with elevated temperatures do reduce residual oil saturations. Data are presented on the temperature effects on interfacial tensions and on adsorption. Certain inorganic chemicals which give high pH are effective and inexpensive but hydroxyl ions react with silica in the reservoir. This reaction is accentuated at higher temperatures. Data show that the pH of the injected hot water with caustic decreases with contact time. The experiments did not permit determining if an equilibrium pH would be obtained which would be high enough to be effective in recovering oil. Core floods showed that pH's in excess of 12 would be required to reduce residual oil saturations if sodium hydroxide was the injected chemical. The addition of surfactants with caustic or the use of sodium carbonate may permit recovery of oil at lower pH's. A reservoir simulator is being developed to predict performance of steamfloods with chemical additives. This has been completed for simple linear floods but is being extended to three dimensions and to more complicated flooding operations. 31 references, 43 figures, 2 tables.

  8. High efficiency, high reliability, improved oil injected helium screw compressor

    International Nuclear Information System (INIS)

    The adaptation of recent developments for enhancement of the two stage oil injected helium screw compressors efficiency and reliability relate to reducing power demand by modifying discharge ports and sizing each stage for total lowest energy input. Also increasing volumetric efficiency by minimizing internal gas leakages accomplished by the use of proper lube and by increase of low stage speed. Magnitude of expected improvements in performance attributed to each key factor is estimated at 11% lower BHP for reduction of hydraulic effects; 6% lower BHP for best lo-hi displacement ratio; 3% higher VE for optimization of lube supply; and 3% higher VE for increasing low stage tip speed. Based on present technology isothermal efficiency of 60% is readily attainable. The continued investigations of these matters in the lab and field should provide new innovations, some proprietary, for new helium screw systems design and applications with isothermal efficiency approaching 65%

  9. Oil-water separator for pretreating petroleum-contaminated water

    International Nuclear Information System (INIS)

    An oil-water separator with inclined corrugated-plate packing was developed. Because of the special passageway formed by the corrugated plates, more opportunities are provided for collisions and coagulation among the oil droplets and for adhesion and coalescence between the oil droplets and the corrugated plates. This separator has, therefore, greatly increased the efficiency of oil removal. Based on the results of the experiments, a mathematical model has been developed for predicting the oil removal efficiency

  10. Diffusion as an Oil Recovery Mechanism During CO2 Injection in Fractured Reservoirs

    OpenAIRE

    Lie, Stig Holme

    2013-01-01

    This thesis is part of an ongoing study of enhanced oil recovery by CO2 injection in the Reservoir Physics research group at the Department of Physics and Technology (IFT) at the University of Bergen. This work investigates the feasibility of oil recovery from diffusion during miscible CO2 injection in fractured core plugs by conducting appropriate laboratory tests and numerical simulations. A total of 10 miscible CO2 injection tests were conducted in the laboratory using artificially fractur...

  11. Characterization of crude oil-water and solid -water interfaces and adsorption / desorption properties of crude oil fractions: The effect of low salinity water and pH

    Energy Technology Data Exchange (ETDEWEB)

    Farooq, Umer

    2010-09-15

    The reservoirs of conventional oil are rapidly depleting because of increased production and consumption of crude oil in the world. Mature and mostly depleted oil reservoirs require advanced recovery techniques to sustain the production rates. During the past years, a variety of enhanced oil recovery (EOR) methods have been developed and implemented to increase the oil recovery from mature reservoirs. Low Salinity Waterflooding (LSW) is an emerging EOR process of injecting water containing low concentrations (<4000 ppm) of total dissolved solids into the reservoir. This moderate cost process yields relatively higher incremental recoveries than other water based recovery methods. Investigation of mechanisms for increased recovery is quite challenging because this process depends upon complex crude oil/water/rock properties. This work was done to study the surface chemistry of typical reservoir surfaces where LSW can be used for EOR. The oil water and solid-water interfaces were characterised in low salinity aqueous solutions and investigated how the electrolytes and pH of solutions affect the interfacial and surface properties. The influence of low saline aqueous solution on the desorption behaviour of different fractions (acid-free oil and base-free oil) of crude oils was also explored. Reservoir minerals are sensitive to small changes in solution properties and therefore model, outcrop and reservoir particles were characterized in low salinity aqueous solutions. The extent of ionic adsorption on the mineral surfaces was found by various techniques. Particles were also characterized with respect to their elemental compositions. Asphaltene adsorption/desorption on reservoir rock surfaces play an important role in EOR processes. Various injection sequences of low saline aqueous solution of Na +, Ca2+ and sea water were considered to study the desorption of asphaltenes from silica surfaces. Composition of the aqueous phase influenced the interfacial properties of crude oil. Acids, bases and asphaltenes were selectively removed from crude oils and demonstrated the significance of each component on the interfacial behaviour in the aqueous phase under various electrolyte concentrations, type of electrolytes and pH ranges. It was determined that the crude oil acids and electrolyte type played an important role for interfacial properties at high pH conditions. Adsorption/desorption properties of various crude oil fractions on silica coated quartz surfaces were also studied. The influence of electrolyte types and pH conditions of low salinity aqueous solutions on desorption behaviour of different oil fractions was considered. Finally, the dynamic interfacial behaviour of two different crude oils and their fractions were evaluated in different aqueous solutions. The effects of mono and divalent ionic concentrations on interfacial properties were compared. (Author)

  12. Oil, Gas, and Injection Wells in Louisiana, Geographic NAD83, LDNR (2007) [oil_gas_wells_LDNR_2007

    Data.gov (United States)

    Louisiana Geographic Information Center — This is a point dataset containing the location of over 230,000 oil and gas and injection wells in the state of Louisiana. It was developed from the DNR Office of...

  13. Application of naturally occurring isotopes and artificial radioactive tracer for monitoring water flooding in oil field

    International Nuclear Information System (INIS)

    Water flooding is an important operation to enhance oil recovery. Water is injected in the oil formation under high pressure through an injection well. Movement of the injected water is needed to be traced to test the performance of water flood, investigate unexpected anomalies in flow and verify suspected geological barriers or flow channels, etc. In the present study environmental isotopes and artificial radiotracer (tritium) were used at Fimkassar Oil Field of Oil and Gas Development Company Limited (OGDCL) where water flooding was started in March 1996 in Sakessar formation to maintain its pressure and enhance the oil recovery. Environmental isotopes: /sup 18/O, /sup 2/H and /sup 3/H, and chloride contents were used to determine the breakthrough/transit time and contribution of fresh injected water. Water samples were collected from the injection well, production well and some other fields for reference indices of Sakessar Formation during June 1998 to August 1999. These samples were analyzed for the /sup 18/O, /sup 2/H and /sup 3/H, and chloride contents. Results show that the water of production well is mixture of fresh water and formation water. The fresh water contribution varied from 67% to 80%, while remaining component was the old recharged formation water. This percentage did not change significantly from the time of break-through till the last sampling which indicates good mixing in the reservoir and absence of any quick channel. The initial breakthrough time was 27 months as the fresh water contributed significantly in the first appearance of water in the production well in June 1998. Tritium tracer, which was injected in November 1998, appeared in the production well after 8 months. It show that breakthrough time decreased with the passage of time. /sup 14/C of inorganic carbon in the water in Chorgali and Sakessar Formations was also analyzed which indicates that the water is at least few thousand years old. (author)

  14. Aqueous misdirection following pars plana vitrectomy and silicone oil injection

    Directory of Open Access Journals (Sweden)

    Ghoraba HH

    2015-05-01

    Full Text Available Hammouda H Ghoraba,1,2 Ali Ahmed Ghali,3 Hosam Othman Mansour2,3 1Tanta University, Tanta, Egypt; 2Magrabi Eye Hospital, Cairo, Egypt; 3Al-Azhar University, Cairo, Egypt Purpose: To report a retrospective series of seven phakic eyes of seven patients suffering from a malignant glaucoma-like syndrome following pars plana vitrectomy and silicone oil (SO injection.Materials and methods: Seven eyes with retinal detachment treated with pars plana vitrectomy with or without scleral buckling with SO tamponade. This was followed by cataract extraction to manage the elevated intraocular pressure (IOP.Results: This was a retrospective review of seven cases that received pars plana vitrectomy and SO with or without scleral buckling for different causes of retinal detachment (three were rhegmatogenous and four were tractional. After a period ranging from 1 week to 1 month, they presented with malignant glaucoma-like manifestations; high IOP, shallow axial anterior chamber, and remarkable decrease of visual acuity. Atropine eye drops and anti-glaucoma medical treatment (topical and systemic had been tried but failed to improve the condition. Dramatic decrease of IOP and deepening of the axial anterior chamber was observed in all cases in the first postoperative day after phacoemulsification and posterior chamber foldable intraocular lens implantation with posterior capsulotomy.Conclusion: Aqueous misdirection syndrome may be observed following pars plana vitrectomy and SO tamponade. This must be differentiated from other causes of post vitrectomy glaucoma. Cataract extraction with posterior capsulotomy controls the condition. Keywords: malignant glaucoma, pars plana vitrectomy, silicone oil

  15. Detecting oil on water using polarimetric imaging

    Science.gov (United States)

    Iler, Amber L.; Hamilton, Patrick D.

    2015-05-01

    Integrity Applications Incorporated (IAI) collected electro-optical polarimetric imagery (PI) to evaluate its effectiveness for detecting oil on water. Data was gathered at multiple sun angles for vegetable oil and crude oil to demonstrate PI sensitivity to different liquids and collection geometries. Unique signatures for oil relative to water were observed. Both oils consistently displayed higher degree of linear polarization (DOLP) values than water, which was expected based on the lower index of refraction of water (1.33) relative to vegetable oil and crude oil (1.47 and 1.47-1.57, respectively). The strength of the polarimetric signatures was found to vary as a function of collection angle relative to the sun, with peak linear polarizations ranging from 40-70% for crude oil and 20-50% for vegetable oil. IAI found that independently scaled DOLP was particularly useful for discriminating these liquids, because it demonstrated the least sensitivity to collection angle, compared to other PI products. Specifically, the DOLP signature of vegetable oil was approximately 20% lower than for crude oil, regardless of collection angle. This finding is consistent with the lower index of refraction values for vegetable oil compared to crude. Based on the promising results presented here, IAI recommends further testing and development of PI for oceanic remote sensing applications such as oil spill/leak detection and for supporting oil cleanup efforts. With additional work, PI may also be applicable to other oceanic environmental issues such as detection of agricultural runoff or effluent from industrial facilities or watercraft.

  16. Dispersibility of crude oil in fresh water

    Energy Technology Data Exchange (ETDEWEB)

    Wrenn, B.A.; Virkus, A.; Mukherjee, B. [Department of Energy, Environmental, and Chemical Engineering, Washington University, St. Louis, MO 63130 (United States); Venosa, A.D., E-mail: venosa.albert@epa.go [U.S. Environmental Protection Agency, National Risk Management Research Laboratory, Cincinnati, OH 45268 (United States)

    2009-06-15

    The effects of surfactant composition on the ability of chemical dispersants to disperse crude oil in fresh water were investigated. The objective of this research was to determine whether effective fresh water dispersants can be designed in case this technology is ever considered for use in fresh water environments. Previous studies on the chemical dispersion of crude oil in fresh water neither identified the dispersants that were investigated nor described the chemistry of the surfactants used. This information is necessary for developing a more fundamental understanding of chemical dispersion of crude oil at low salinity. Therefore, we evaluated the relationship between surfactant chemistry and dispersion effectiveness. We found that dispersants can be designed to drive an oil slick into the freshwater column with the same efficiency as in salt water as long as the hydrophilic-lipophilic balance is optimum. - This study was conducted to advance our understanding of dispersion chemistry in fresh waters.

  17. Particle retention in porous media: Applications to water injectivity decline

    Energy Technology Data Exchange (ETDEWEB)

    Wennberg, Kjell Erik

    1998-12-31

    This thesis studies the problem of migration and deposition of colloidal particles within porous media, theoretically and by computerized simulation. Special emphasis is put on the prediction of injectivity decline in water injection wells due to inherent particles in the injection water. The study of particle deposition within porous media requires a correct prediction of the deposition rate or filtration coefficient. A thorough review of the modeling approaches used in the past are combined with new ideas in order to arrive at an improved model for the prediction of the filtration coefficient. A new way of determining the transition time for the dominant deposition mechanism to change from internal deposition to external cake formation is proposed. From this fundamental theory, equations are given for water injectivity decline predictions. A computer program called WID for water injectivity decline predictions was developed. Using water quality, formation properties, injection rate/pressure and completion information as input, WID predicts decline in vertical and horizontal injection wells with openhole, perforated and fractured completions. The calculations agree fairly well with field data; in some cases the agreement is excellent. A poor match in a few cases indicates that more mechanisms may be responsible for injectivity decline than those presently accounted for by the simulator. The second part of the study deals with a theoretical investigation of the multi-dimensional nature of particle deposition in porous media. 112 refs., 100 figs., 9 tabs.

  18. Measurement of electrical impedance of a Berea sandstone core during the displacement of saturated brine by oil and CO2 injections

    Science.gov (United States)

    Liu, Yu; Xue, Ziqiu; Park, Hyuck; Kiyama, Tamotsu; Zhang, Yi; Nishizawa, Osamu; Chae, Kwang-seok

    2015-12-01

    Complex electrical impedance measurements were performed on a brine-saturated Berea sandstone core while oil and CO2 were injected at different pressures and temperatures. The saturations of brine, oil, and CO2 in the core were simultaneously estimated using an X-ray computed tomography scanner. The formation factor of this Berea core and the resistivity indexes versus the brine saturations were calculated using Archie's law. The experimental results found different flow patterns of oil under different pressures and temperatures. Fingers were observed for the first experiment at 10 MPa and 40 °C. The fingers were restrained as the viscosity ratio of oil and water changed in the second (10 MPa and 25 °C) and third (5 MPa and 25 °C) experiments. The resistivity index showed an exponential increase with a decrease in brine saturation. The saturation exponent varied from 1.4 to 4.0 at different pressure and temperature conditions. During the oil injection procedure, the electrical impedance increased with oil saturation and was significantly affected by different oil distributions; therefore, the impedance varied whether the finger was remarkable or not, even if the oil saturation remained constant. During the CO2 injection steps, the impedance showed almost no change with CO2 saturation because the brine in the pores became immobile after the oil injection.

  19. Reduction of Altitude Diffuser Jet Noise Using Water Injection

    Science.gov (United States)

    Allgood, Daniel C.; Saunders, Grady P.; Langford, Lester A.

    2014-01-01

    A feasibility study on the effects of injecting water into the exhaust plume of an altitude rocket diffuser for the purpose of reducing the far-field acoustic noise has been performed. Water injection design parameters such as axial placement, angle of injection, diameter of injectors, and mass flow rate of water have been systematically varied during the operation of a subscale altitude test facility. The changes in acoustic far-field noise were measured with an array of free-field microphones in order to quantify the effects of the water injection on overall sound pressure level spectra and directivity. The results showed significant reductions in noise levels were possible with optimum conditions corresponding to water injection at or just upstream of the exit plane of the diffuser. Increasing the angle and mass flow rate of water injection also showed improvements in noise reduction. However, a limit on the maximum water flow rate existed as too large of flow rate could result in un-starting the supersonic diffuser.

  20. Stability Proxies for Water-in-Oil Emulsions and Implications in Aqueous-based Enhanced Oil Recovery

    OpenAIRE

    Mehrnoosh Moradi; Xiuyu Wang; Vladimir Alvarado

    2011-01-01

    Several researchers have proposed that mobility control mechanisms can positively contribute to oil recovery in the case of emulsions generated in Enhanced-Oil Recovery (EOR) operations. Chemical EOR techniques that use alkaline components or/and surfactants are known to produce undesirable emulsions that create operational problems and are difficult to break. Other water-based methods have been less studied in this sense. EOR processes such as polymer flooding and LoSalTM injection require a...

  1. Simulation bidimensional of water and gas alternative injection; Simulacao bidimensional de injecao alternada de agua e gas

    Energy Technology Data Exchange (ETDEWEB)

    Santana, Ana Paula Silva C. de

    1999-07-01

    This dissertation presents a study of the unidimensional of water and gas alternate injection (WAG) using the stream line theory. It is considered incompressible fluid., unit mobility ratio, negligible capillary and gravitational effects, homogeneous and isotropic reservoir, isothermal flow two phases, oil and water, and three components, oil, water and gas. In the stream line theory, the following injection schemes are considered: staggered line five-spot, direct line and seven-spot. It is also considered that there is no flow among the streams. In the WAG calculations it is used the fractional flow theory and the method of characteristics, which consists of shock waves and rarefactions. The composition of these waves is said compatible if it satisfies the entropy condition. The solution goes through a certain path from the left to the right side constrained by the initial and boundary conditions. The gas injection is at a high pressure to ensure miscible displacement. It is considered first injection of a water bank and then, injection of a gas bank. We concluded that the gas injection at a high pressure recoveries all residual oil and the water saturation remains is greater than initial saturation. (author)

  2. Study about oil displacement efficiency of different position in very high water cut reservoir

    Science.gov (United States)

    Zhong, Yihua; Bing, Shaoxian; Tian, Yan

    2015-03-01

    The key to enhancing oil recovery of very high water cut oilfield lies in analyzing oil displacement efficiency in different position of reservoir, which mainly focus on the analysis of dimensionless cumulative flowing into water volume and oil displacement efficiency distribution. In order to get the oil displacement efficiency distribution characteristics to future analyze influence on oil displacement efficiency by changing well pattern, oil displacement efficiency in different position of homogeneous reservoir is studied by combining the analysis of core displacement experiment with oilfield practice in this paper. Firstly, streamline function and streamline distribution between injection-production well in homogeneous reservoir is researched by the potential function and potential distribution with the five-point well pattern. Secondly, the method of flow distribution on the streamline between the injection-production well is studied according to change law of seepage resistance. Thirdly, dimensionless cumulative flowing into water volume along the streamline is calculated based on the core size to analyze its distribution characteristics about homogeneous reservoir and obtain dimensionless cumulative flowing into water volume at different position of the reservoir matching the core displacement experiment. Finally, the distribution characteristics of oil displacement efficiency are got by statistical analysis for the change of oil displacement efficiency as the dimensionless cumulative flowing into water volume in real oilfield. This study may provide technical measure with oilfield enterprise to enhance the oil recovery of very high water cut oilfield.

  3. Factors influencing time course of pain after depot oil intramuscular injection of testosterone undecanoate

    OpenAIRE

    Sartorius, Gideon; Fennell, Carolyn; Spasevska, Sasa; Turner, Leo; Conway, Ann J.; Handelsman, David J

    2010-01-01

    Pain following depot intramuscular (IM) injection of oil vehicle-based drugs has been little studied. This study aimed to determine prospectively the prevalence, determinants, severity and functional consequences of pain during the week after IM injection of 1 000 mg testosterone undecanoate (TU) in a 4-mL castor oil vehicle. Androgen-deficient men receiving regular T replacement therapy at an academic andrology clinic were recruited to report pain scores using a coloured visual linear analog...

  4. Dielectric Properties of Flocculated Water-in-Oil Emulsions

    Energy Technology Data Exchange (ETDEWEB)

    Skodvin, T.

    1995-12-31

    When an offshore oil field is near completion, water occupies a large fraction of the available pore volume. Thus, in collecting the oil and gas reserves, one has to deal with a high co-production of either formation- or injected water. This doctoral thesis focuses on the effect of water-in-oil emulsions on the dielectric properties, in particular the effect of flocculation. Various dielectric models are applied to obtain methods for qualitative and quantitative characterization of the flocculated state. Permittivity and measurement of dielectric properties are discussed as a basis for the interpretation of the dielectric properties of the emulsions. Various flocculation models are presented. It is concluded that the dielectric properties of water-in-oil emulsions are strongly influenced by continuously ongoing processes in the system. Because of flocculation and sedimentation the traditional dielectric mixture models cannot satisfactorily predict the dielectric behaviour. The experimentally obtained permittivities for the emulsions can be reproduced by including flocculation in the models and treating the floc aggregates as spheroids or subsystems with dielectric properties given by the degree of flocculation. The models discussed have difficulties reproducing the complete frequency behaviour found experimentally. This is probably because the dielectric relaxation may be influenced by processes not included in the models, such as the effects of dipolar or multipolar interactions between the droplets. For further research it is recommended that rheological and dielectric measurements be combined. 227 refs., 61 figs., 16 tabs.

  5. Geothermal water temperature distribution trough a injection-production well system

    Energy Technology Data Exchange (ETDEWEB)

    Budzynski, R.; Nowak, W.; Sobanski, R. [Politechnika Szczecinska, Szczecin (Poland)

    1993-12-31

    In the paper is considered problem of mineralized geothermal water utilisation through a one-well injection-production system. This kind of system is especially suitable for utilisation of existing former oil production`s wells, and for supplying the nearest receivers of produced heat. For concentric assembled pipes there are presented equations for geothermal water temperature distribution depending on system geometry, heat transfer resistance, temperature profile in the depth of the earth as well as rate of geothermal water flow. (Authors). 1 ref., 2 figs.

  6. Enhanced Oil Recovery (EOR by Miscible CO2 and Water Flooding of Asphaltenic and Non-Asphaltenic Oils

    Directory of Open Access Journals (Sweden)

    Edwin A. Chukwudeme

    2009-09-01

    Full Text Available An EOR study has been performed applying miscible CO2 flooding and compared with that for water flooding. Three different oils are used, reference oil (n-decane, model oil (n-C10, SA, toluene and 0.35 wt % asphaltene and crude oil (10 wt % asphaltene obtained from the Middle East. Stearic acid (SA is added representing a natural surfactant in oil. For the non-asphaltenic oil, miscible CO2 flooding is shown to be more favourable than that by water. However, it is interesting to see that for first years after the start of the injection (< 3 years it is shown that there is almost no difference between the recovered oils by water and CO2, after which (> 3 years oil recovery by gas injection showed a significant increase. This may be due to the enhanced performance at the increased reservoir pressure during the first period. Maximum oil recovery is shown by miscible CO2 flooding of asphaltenic oil at combined temperatures and pressures of 50 °C/90 bar and 70 °C/120 bar (no significant difference between the two cases, about 1% compared to 80 °C/140 bar. This may support the positive influence of the high combined temperatures and pressures for the miscible CO2 flooding; however beyond a certain limit the oil recovery declined due to increased asphaltene deposition. Another interesting finding in this work is that for single phase oil, an almost linear relationship is observed between the pressure drop and the asphaltene deposition regardless of the flowing fluid pressure.

  7. Integrated use of NMR, petrel and modflow in the modeling of SAGD produced water re-injection

    Energy Technology Data Exchange (ETDEWEB)

    Campbell, K. [Miswaco(CANADA); Phair, C [Mneme Corp, CALGARY (Canada); Alloisio, S [SWS, Vancouver (CANADA); Novotny, M [SWS, Denver, (United States); Raven, S [Oilsands Quest Inc., Calgary (CANADA)

    2011-07-01

    In the oil industry, steam assisted gravity drainage (SAGD) is a method used to enhance oil recovery in which production water disposal is a challenge. During this process, production water is re-injected into the reservoir and operators have to verify that it will not affect the quality of the surrounding fresh groundwater. This research aimed at determining the flow path and the time that produced water would take to reach an adjacent aquifer. This study was carried out on a horizontal well pair at the Axe Lake Area in northwestern Saskatchewan, using existing site data in Petrel to create a static hydrogeological model which was then exported to Modflow to simulate injection scenarios. This innovative method provided flow path of the re-injected water and time to reach the fresh with advantages over conventional hydrogeological modeling. The innovative workflow presented herein successfully provided useful information to assess the feasibility of the SAGD project and could be used for other projects.

  8. Integrated use of NMR, petrel and modflow in the modeling of SAGD produced water re-injection

    International Nuclear Information System (INIS)

    In the oil industry, steam assisted gravity drainage (SAGD) is a method used to enhance oil recovery in which production water disposal is a challenge. During this process, production water is re-injected into the reservoir and operators have to verify that it will not affect the quality of the surrounding fresh groundwater. This research aimed at determining the flow path and the time that produced water would take to reach an adjacent aquifer. This study was carried out on a horizontal well pair at the Axe Lake Area in northwestern Saskatchewan, using existing site data in Petrel to create a static hydrogeological model which was then exported to Modflow to simulate injection scenarios. This innovative method provided flow path of the re-injected water and time to reach the fresh with advantages over conventional hydrogeological modeling. The innovative workflow presented herein successfully provided useful information to assess the feasibility of the SAGD project and could be used for other projects.

  9. Water management in Siri oil field in Iran: A comprehensive case study

    Energy Technology Data Exchange (ETDEWEB)

    Masoudi, Zahedzadeh M.; Abbasian, Ataei A.; Shokrollahzadeh, S.; Raadmehr, M.

    2006-03-15

    Successful water management and dealing with produced water is a crucial part of any oil and gas production scenarios. This paper investigates the role of comprehensive study in water management and produced water re-injection in an Iranian offshore oil field. Appropriate method can be chosen by taking into account various effective parameters such as reservoir properties, laboratory experiment, and learning from already done projects and etc. In this work, produced water reinjection in Siri oil field in Iran has been investigated by examining the effective parameters including reservoir characterization such as permeability, porosity, petrophysical properties as well as performing relevant laboratory experiments and reservoir parameters like aquifer support and carbonated rock reservoir issues. Finally, it was concluded that comprehensive study together with proper laboratory investigation has a significant effect in success of produced water re-injection process. (author) (tk)

  10. A Performance, Emission and Combustion Investigation on Hot Air Assisted Eucalyptus Oil Direct Injected Compression Ignition Engine

    OpenAIRE

    D. TAMILVENDHAN; ILANGOVAN.V

    2011-01-01

    A diesel engine modified for eucalyptus oil direct injection (EuDI) has been tested to study eucalyptus oil behavior. Since the eucalyptus oil possesses low cetane number fails to auto ignite, the test engine was modified to supply hot air during suction stroke which helps to auto-ignite the injected eucalyptus oil. The engine with this facility was operated using eucalyptus oil under various load conditions and at various intake temperatures. The results of the investigation were proved that...

  11. Injection of Emulsified Vegetable Oil for Long-Term Bioreduction of Uranium

    Science.gov (United States)

    Brooks, S. C.; Watson, D. B.; Schadt, C. W.; Jardine, P. M.; Gihring, T. M.; Zhang, G.; Mehlhorn, T.; Lowe, K.; Phillips, J.; Earles, J.; Wu, W.; Criddle, C. S.; Kemner, K. M.; Boyanov, M.

    2011-12-01

    In situ bioremediation of a uranium and nitrate-contaminated aquifer with the slow-release electron donor, emulsified vegetable oil (EVO), was tested at the US DOE Subsurface Biogeochemical Research Program (SBR) Integrated Field Research Challenge (IFRC) site, in Oak Ridge, TN. The EVO injection took place in Area 2 of the IFRC located about 300 m downgradient of the former S-3 disposal ponds. Liquid wastes, disposed in the ponds from 1951 to 1983, were primarily composed of nitric acid, plating wastes containing various metals (Cr, Ni) radionuclides (U, Tc), inorganics (nitrate, sulfate) and organic contaminants (tetrachloroethylene, acetone). Prior pond closure in 1987, large volumes of waste fluids migrated into the subsurface, down Bear Creek Valley and into Bear Creek. Contaminants detected at Area 2 were transported through a high permeability gravelly fill that is considered a preferred transport pathway for U to Bear Creek. Groundwater in the gravelly fill is contaminated with U (1-3 mg/L), sulfate (95-130 mg/L), and nitrate (20-40 mg/L) and 500 mg/kg or higher U has been detected on the solid phase of the fill material. The objective of this study is to investigate the feasibility and long-term sustainability of U(VI) reduction and immobilization, and nitrate degradation in the high permeability, high flow gravel fill using EVO as the electron donor. A one-time EVO injection was conducted over a 2 hour period in the highly permeable gravel (hydraulic conductivity 0.08 cm/sec) in the well instrumented IFRC Area 2 field plot. Extensive monitoring of geochemical parameters, dissolved gases and microbial populations were conducted during the test. A bromide tracer test was conducted prior to the injection of the EVO to assess transport pathways and rates. Geochemical analysis of site groundwater demonstrated the sequential bioreduction of oxygen, nitrate, Mn(IV), Fe(III) and sulfate. Transient accumulation of acetate was observed as an intermediate in the oil degradation. Reduction and removal of U and nitrate from groundwater was observed in all wells in hydraulic connection to the injection wells after 2-4 weeks. U concentrations in groundwater were reduced to below 30 ppb (US EPA drinking water standard) at some well locations and nitrate was reduced to below detectable levels. Rebound of U in groundwater was observed together with the rebound of sulfate concentrations as the EVO was consumed. The flux of U and nitrate contamination from groundwater to the surface water receptor (Bear Creek) was significantly reduced by the EVO injection over a one year period. Uranium (VI) reduction to U(IV) in the field tests was confirmed by X-ray absorption near-edge spectroscopy (XANES) analysis. The reduced U(IV) was determined by X-ray absorption fine structure (XAFS) to be in an Fe-U complex, not uraninite. The activities of major Fe(III)- and sulfate-reducing bacteria with U(VI)-reducing capability as well as methanogens was stimulated after injection of the oil.

  12. A probabilistic assessment of waste water injection induced seismicity in central California

    Science.gov (United States)

    Goebel, T.; Hauksson, E.; Ampuero, J. P.; Aminzadeh, F.; Cappa, F.; Saleeby, J.

    2014-12-01

    The recent, large increase in seismic activity within the central and eastern U.S. may be connected to an increase in fluid injection activity since ~2001. Anomalous seismic sequences can easily be identified in regions with low background seismicity rates. Here, we analyze seismicity in plate boundary regions where tectonically-driven earthquake sequences are common, potentially masking injection-induced events. We show results from a comprehensive analysis of waste water disposal wells in Kern county, the largest oil-producing county in California. We focus on spatial-temporal correlations between seismic and injection activity and seismicity-density changes due to injection. We perform a probabilistic assessment of induced vs. tectonic earthquakes, which can be applied to different regions independent of background rates and may provide insights into the probability of inducing earthquakes as a function of injection parameters and local geological conditions. Our results show that most earthquakes are caused by tectonic forcing, however, waste water injection contributes to seismic activity in four different regions with several events above M4. The seismicity shows different migration characteristics relative to the injection sites, including linear and non-linear trends. The latter is indicative of diffusive processes which take advantage of reservoir properties and fault structures and can induce earthquakes at distances of up to 10 km. Our results suggest that injection-related triggering processes are complex, possibly involving creep, and delayed triggering. Pore-pressure diffusion may be more extensive in the presence of active faults and high-permeability damage zones thus altering the local seismic hazard in a non-linear fashion. As a consequence, generic "best-practices" for fluid injections like a maximum distance from the nearest active fault may not be sufficient to mitigate a potential seismic hazard increase.

  13. Water Local Volume Fraction on Oil in Water Dispersion

    Directory of Open Access Journals (Sweden)

    siti aslina hussain

    2008-01-01

    Full Text Available The phase distribution of water-oil flows was studied experimentally from a separated flow without mixer to a oil in water or water in oil dispersed in horizontal tubes. Under most conditions the pattern was oil continuous in water dispersed or water continuous in oil dispersed flow continuously and there is entrainment in the form of drops of phase into the other. The investigations were carried out through the cross-sectional phase distribution in the flow of mixtures of water and kerosene such as EXXSOL-D80 in a horizontal 25.4 mm bore stainless steel section. The phase fraction distribution was determined using a traversing beam gamma densitometer, with the beam being traversed in three directions (00, 450 and 900 of the vertical line passing through the axis of the tube. Measurements were made at three positions spaced along the 9.7 m test section length (1.0 m, 5.85 m and 7.72 m along the horizontal tube. The measurements were done in the Two-phase Oil Water Experimental Rig (TOWER facility. This facility allows the two fluids to be fed to the test section before they are separated and returned once more to the test line. The flow developed naturally from an initial stratified flow in which the oil and water were introduced separately at the top and the bottom of the test section respectively. It was found that the liquids were fully inter-dispersed by the end of the test section. The results were also used to define the flow patterns in water-oil liquid-liquid flow system. The phase fraction distribution was shown to be homogeneously mixed near to the outlet of the test section.

  14. Investigating New Innovations to Detect Small Salt-Water Fraction Component in Mineral Oil and Small Oil Fraction Component in Salt-Water Projects

    Directory of Open Access Journals (Sweden)

    E.R.R. Mucunguzi-Rugwebe

    2011-09-01

    Full Text Available The main purpose of this study is to present the key findings on the effects of small salt-water fraction component, ? expressed in volume % per L on rotation are presented in the temperature range of 19.0 to 24.0ºC. It was found that rotations in oils with low boiling point known as light oils like Final diesel No. 2 were greater than the rotations which occurred in oils with high boiling point called heavy oils such as Esso diesel. Small oil fraction components, ?s expressed in mL/L of salt water down to 10 ppm were detected. The greatest impact on rotation of these oils was found in light oils like Fina No. 2 diesel. At 40 ppm which is the oil content level below which the environment authority considers process water to be free from oil environmental hazards, the observed rotation angles were 23.2º for Esso, 36.7º for Nors Hydro AS, and 71.8º in Fina No. 2 diesel. It was observed that light oils molecules have drastic effect on optical properties of the mixture in which they exist. It was found that for all oils, oil fractions greater than 100 ppm, caused the medium to be optically dense. This technology has shown a very high potential of being used as an environmental monitor to detect oil fractions down to 10 ppm and the technique can use laser beam to control re-injected process water with oil fractions between 100-2000 ppm.

  15. Water injected fuel cell system compressor

    Science.gov (United States)

    Siepierski, James S. (Williamsville, NY); Moore, Barbara S. (Victor, NY); Hoch, Martin Monroe (Webster, NY)

    2001-01-01

    A fuel cell system including a dry compressor for pressurizing air supplied to the cathode side of the fuel cell. An injector sprays a controlled amount of water on to the compressor's rotor(s) to improve the energy efficiency of the compressor. The amount of water sprayed out the rotor(s) is controlled relative to the mass flow rate of air inputted to the compressor.

  16. The Influence of CO2 Solubility in Brine on Simulation of CO2 Injection into Water Flooded Reservoir and CO2 WAG

    DEFF Research Database (Denmark)

    Yan, Wei; Stenby, Erling Halfdan

    2010-01-01

    Injection of CO2 into depleted oil reservoirs is not only a traditional way to enhance oil recovery but also a relatively cheaper way to sequester CO2 underground since the increased oil production can offset some sequestration cost. CO2 injection process is often applied to water flooded reservoirs and in many situations alternating injection of water and CO2 is required to stabilize the injection front. Both scenarios involve a large amount of water, making CO2 solubility in brine, which is around ten times higher than methane solubility, a non-negligible factor in the relevant reservoir simulations. In our previous study, a 1-D slimtube simulator, which rigorously accounts for both CO2 solubility in brine and water content in hydrocarbon phases using the Peng-Robinson EoS modified by Soreide and Whitson, has been used to investigate the influence of CO2 solubility on the simulation of continuous CO2 flooding with uniform initial water saturation. As a follow-up of the previous study, this study extends theinvestigation to two more realistic scenarios (1) CO2 injection into water flooded reservoir and (2) water-alternating-gas (WAG) injection with CO2 as the injection gas. A series of 1-D simulations were made for seven oil samples within a wide range of temperature, pressure and salinity. The results were analyzed in terms of the change in oil recovery due to different phase equilibrium descriptions, the delay in breakthrough and the CO2 lost to the aqueous phase. The influence of different factors, including temperature, pressure, salinity, water injection pore volume, WAG ratio and CO2 slug size, on the simulation results was also discussed. In addition, the results for CO2 injection into water flooded reservoirs were also compared with those from the previous study.

  17. Mine Drainage and Oil Sand Water.

    Science.gov (United States)

    Wei, Xinchao; Wolfe, F Andrew; Li, Yanjun

    2015-10-01

    Mine drainage from the mining of mineral resources (coal, metals, oil sand, or industrial minerals) remains as a persistent environmental problem. This review summarizes the scientific literature published in 2014 on the technical issues related to mine drainage or mine water in active and abandoned coal/hard rock mining sites or waste spoil piles. Also included in this review is the water from oil sand operations. This review is divided into the four sections: 1) mine drainage characterization, 2) prediction and environmental impact, 3) treatment technologies, 4) oil sand water. Many papers presented in this review address more than one aspect and different sections should not be regarded as being mutuallyexclusive or all-inclusive. PMID:26420092

  18. Adsorption of diatoms at the oil-water interface

    Science.gov (United States)

    Fathollahi, Niloofar; Sheng, Jian

    2013-11-01

    Statistically robust experimental observations on 3D trajectory of diatoms approaching an oil-water interface is crucial for understanding sorption mechanisms of active particles, and interfacial rheology with over-arching implications in interfacial dynamics, droplet break and coalescence. Digital Holographic Cinematography is utilized to measure 3-D trajectories of diatoms, Thalassiosira pseudomona and T. weissflogii and simultaneously track the interface. Experiments are conducted in a 300 × 100 × 100 mm chamber containing 32 ppt artificial seawater. A stationary pendant drop is created on the tip of a needle located at the center of the chamber. Three oil samples, Louisiana crude, hexadecane, and mineral oil, are used. Diatoms are injected at a height above the drop with a negligible velocity, where Diatom precipitates freely on its excess weight. Holograms of diatom and drop are recorded at 5 fps with a magnification of 1.3X and are streamed in real time allowing for long-term study of sorption onto a slowly aging interface. A novel autofocus algorithm enables us to determine 3D locations within an uncertainty of 0.05 particle diameter. This allows us to perform super-resolution measurement to determine the effects of location and orientation of diatoms on the adsorption rate at the oil-water interface. Funded by GoMRI.

  19. Determination of oil and water compositions of oil/water emulsions using low field NMR relaxometry

    Energy Technology Data Exchange (ETDEWEB)

    Mirotchnik, K; Allsopp, K.; Kantzas, A. [Calgary Univ., AB (Canada)

    2000-06-01

    Low field Nuclear Magnetic Resonance (NMR) relaxometry techniques were developed in the laboratory to enhance and support comparable NMR logging tools now in use downhole. In heavy oil and bitumen formations where thermal recovery methods are utilized, the fluids produced during the production operations are often in the form of emulsions. Although to a lesser degree, it is also the case in non-thermal recovery methods whenever oil and water are co-produced. Conventional flow measuring methods are adequate for the measurement of segregated oil and water streams, but are not capable of producing appropriate results when oil-in-water or water-in-oil emulsions are present. The same is true in the case of solids flowing in the stream. The accurate measurement of oil and water content of streams with and without emulsions in the samples were successfully tested using low field NMR relaxometry. The results obtained were at least as good as conventional extraction methods. The validation was carried out with artificially and naturally occurring emulsified streams. The accuracy of the results was 96 per cent or better. These favorable results favorably influenced the design of an on-line NMR relaxometer for oil/water stream measurements under the same conditions present during the production of heavy oil and bitumen. 6 refs., 7 figs.

  20. Investigations on matrix recovery during steam injection into heavy-oil containing carbonate rocks

    Energy Technology Data Exchange (ETDEWEB)

    Babadagli, Tayfun [University of Alberta, Department of Civil and Environmental Engineering, School of Mining and Petroleum, 3-112 Markin CNRL-NREF, Edmonton, AB (Canada); Al-Bemani, Ali [Sultan Qaboos University, College of Eng. Department of Petroleum and Chemical Eng., PO Box 33, Al-Khod, Muscat 123 (Oman)

    2007-08-15

    We studied the steam injection potential of heavy-oil containing fractured carbonate reservoirs and analyzed the effects and contribution of different mechanisms on matrix recovery. Qarn Alam field, located in the central part of Oman, was considered as a specific case. Static (capillary) imbibition experiments at different temperatures varying between 20 C and 200 C were conducted using aged Berea sandstone, Indiana limestone, and original - preserved and unpreserved - core samples from the Qarn Alam field. The recovery from the Qarn Alam rock samples at the temperature below the bubble point of water (90 C) is expected to be dominated by three mechanisms, i.e., thermal expansion, capillary imbibition and gravity drainage. Based on the amount measured as the recovery and thermal expansion potential of Qarn Alam crude, the recovery was predominantly controlled by the thermal expansion over the time period applied for respective experiments. Other two mechanisms require longer time than applied in this study to be effective for weakly-water-wet/oil-wet Qarn Alam cores. Some tests at higher temperatures were conducted to gain some ideas about the recovery potential as well as having background information for further studies. The temperature value was selected as 200 C-212 C by nearly doubling the previous applied value (90 C). At the temperature of 200 C significant increase in the recovery was observed. No capillary imbibition recovery was added because no fluid (water or steam condensate) surrounded the matrix and the samples were exposed only to heating. Therefore, only thermal expansion and internal drive (any recovery mechanism caused by the change in the fluid properties in the rock due to thermal effect, i.e., gas, generation, steam distillation, solution gas-drive etc.) were the effective recovery mechanisms. Gravity drainage was thought to be ineffective as the duration of experiments was too short in order for this mechanism to play a role (1-2 h). Finally, the results were used to test the scaling relationships. (author)

  1. Performance and emissions characteristics of Jatropha oil (preheated and blends) in a direct injection compression ignition engine

    International Nuclear Information System (INIS)

    The scarce and rapidly depleting conventional petroleum resources have promoted research for alternative fuels for internal combustion engines. Among various possible options, fuels derived from triglycerides (vegetable oils/animal fats) present promising ''greener'' substitutes for fossil fuels. Vegetable oils, due to their agricultural origin, are able to reduce net CO2 emissions to the atmosphere along with import substitution of petroleum products. However, several operational and durability problems of using straight vegetable oils in diesel engines reported in the literature, which are because of their higher viscosity and low volatility compared to mineral diesel fuel. In the present research, experiments were designed to study the effect of reducing Jatropha oil's viscosity by increasing the fuel temperature (using waste heat of the exhaust gases) and thereby eliminating its effect on combustion and emission characteristics of the engine. Experiments were also conducted using various blends of Jatropha oil with mineral diesel to study the effect of reduced blend viscosity on emissions and performance of diesel engine. A single cylinder, four stroke, constant speed, water cooled, direct injection diesel engine typically used in agricultural sector was used for the experiments. The acquired data were analyzed for various parameters such as thermal efficiency, brake specific fuel consumption (BSFC), smoke opacity, CO2, CO and HC emissions. While operating the engine on Jatropha oil (preheated and blends), performance and emission parameters were found to be very close to mineral diesel for lower blend concentrations. However, for higher blend concentrations, performance and emissions were observed to be marginally inferior. (author)

  2. Oil spill research : salt water and fresh water

    International Nuclear Information System (INIS)

    The difference in oil spill response activities between marine and freshwater environments were reviewed. Although containment, recovery and in-situ burning remain the same in both environments, the fate of oil is different due to water density and salinity considerations. The lower energy of lakes and the lack of major currents changes the advection of the oil. Rivers have high currents, and wind speed and direction are highly influenced by topographic effects. Tidal action is not a consideration for the inland situation, but water levels in rivers can change due to sudden rain events or the action of control devices upstream from the spill. Typically, the volume of oil released in freshwater environments is lower than in marine tanker situations, but spills from pipelines or a major train derailment can exceed 1000 m3. Since the use of water for human consumption and irrigation is another important factor in inland spills, it is important to have a means of obtaining information on the dynamics of spills and a system for archiving the response activities, such as the shoreline cleanup assessment technique (SCAT)and resulting cleanup. It was suggested that research studies must be undertaken to improve response strategies for freshwater spills. These include the dynamics of oil in freshwater environments such as rivers, lakes and sloughs; the role of oil-fine interactions in freshwater situations; the process involved in the formation of tar balls; and, the dynamics of oil in a freshwater situation. The response techniques that must be developed to improve the response to freshwater spills include techniques to remove oil from the bottom; techniques to filter and remove oil from the water column; and, development and testing of dispersants for freshwater environments

  3. Use of tobacco seed oil methyl ester in a turbocharged indirect injection diesel engine

    International Nuclear Information System (INIS)

    Vegetable oils and their methyl/ethyl esters are alternative renewable fuels for compression ignition engines. Different kinds of vegetable oils and their methyl/ethyl esters have been tested in diesel engines. However, tobacco seed oil and tobacco seed oil methyl ester have not been tested in diesel engines, yet. Tobacco seed oil is a non-edible vegetable oil and a by-product of tobacco leaves production. To the author's best knowledge, this is the first study on tobacco seed oil methyl ester as a fuel in diesel engines. In this study, potential tobacco seed production throughout the world, the oil extraction process from tobacco seed and the transesterification process for biodiesel production were examined. The produced tobacco seed oil methyl ester was characterized by exposing its major properties. The effects of tobacco seed oil methyl ester addition to diesel No. 2 on the performance and emissions of a four cycle, four cylinder turbocharged indirect injection (IDI) diesel engine were examined at both full and partial loads. Experimental results showed that tobacco seed oil methyl ester can be partially substituted for the diesel fuel at most operating conditions in terms of performance parameters and emissions without any engine modification and preheating of the blends. (Author)

  4. Keratopathy and pachymetric changes after photorefractive keratectomy and vitrectomy with silicone oil injection

    DEFF Research Database (Denmark)

    Buch, H; Vesti Nielsen, N

    2000-01-01

    We present a man who, after bilateral excimer laser photorefractive keratectomy (PRK) for high myopia in the right eye, had repeated retinal detachment surgery with lensectomy and injection of silicone oil. Visual acuity fluctuated in accordance with significant central corneal thickness diurnal variation. The case illustrates the possibility of PRK as a predisposing factor for keratopathy after retinal detachment surgery with silicone injection in an aphakic eye.

  5. Development of Improved Oil Field Waste Injection Disposal Techniques

    Energy Technology Data Exchange (ETDEWEB)

    Terralog Technologies

    2002-11-25

    The goals of this project have was to: (1) assemble and analyze a comprehensive database of past waste injection operations; (2) develop improved diagnostic techniques for monitoring fracture growth and formation changes; (3) develop operating guidelines to optimize daily operations and ultimate storage capacity of the target formation; and (4) to apply these improved models and guidelines in the field.

  6. Irreversible muscle damage in bodybuilding due to long-term intramuscular oil injection.

    Science.gov (United States)

    Banke, I J; Prodinger, P M; Waldt, S; Weirich, G; Holzapfel, B M; Gradinger, R; Rechl, H

    2012-10-01

    Intramuscular oil injections generating slowly degrading oil-based depots represent a controversial subject in bodybuilding and fitness. However they seem to be commonly reported in a large number of non-medical reports, movies and application protocols for 'site-injections'. Surprisingly the impact of long-term (ab)use on the musculature as well as potential side-effects compromising health and sports ability are lacking in the medical literature. We present the case of a 40 year old male semi-professional bodybuilder with systemic infection and painful reddened swellings of the right upper arm forcing him to discontinue weightlifting. Over the last 8 years he daily self-injected sterilized sesame seed oil at numerous intramuscular locations for the purpose of massive muscle building. Whole body MRI showed more than 100 intramuscular rather than subcutaneous oil cysts and loss of normal muscle anatomy. 2-step septic surgery of the right upper arm revealed pus-filled cystic scar tissue with the near-complete absence of normal muscle. MRI 1 year later revealed the absence of relevant muscle regeneration. Persistent pain and inability to perform normal weight training were evident for at least 3 years post-surgery. This alarming finding indicating irreversible muscle mutilation may hopefully discourage people interested in bodybuilding and fitness from oil-injections. The impact of such chronic tissue stress on other diseases like malignancy remains to be determined. PMID:22592548

  7. Effect of advanced injection timing on the performance of rapeseed oil in diesel engines

    International Nuclear Information System (INIS)

    Combustion studies on both diesel fuel and vegetable oil fuels, with the standard and advanced injection timing, were carried out using the same engine and test procedures so that comparative assessments may be made. The diesel engine principle demands self-ignition of the fuel as it is injected at some degrees before top dead centre (BTDC) into the hot compressed cylinder gas. Longer delays between injection and ignition lead to unacceptable rates of pressure rise with the result of diesel knock because too much fuel is ready to take part in premixed combustion. Alternative fuels have been noted to exhibit longer delay periods and slower burning rate especially at low load operating conditions hence resulting in late combustion in the expansion stroke. Advanced injection timing is expected to compensate these effects. The engine has standard injection timing of 30degC BTDC. The injection was first advanced by 5.5degC given injection timing of 35.5degC BTDC. The engine performance was very erratic on this timing. The injection was then advanced by 3.5degC and the effects are presented in this paper. The engine performance was smooth especially at low load levels. The ignition delay was reduced through advanced injection but tended to incur a slight increase in fuel consumption. Moderate advanced injection timing is recommended for low speed operations. (Author)

  8. Oil recovery from naturally fractured reservoirs by steam injection methods. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Reis, J.C.; Miller, M.A.

    1995-05-01

    Oil recovery by steam injection is a proven, successful technology for nonfractured reservoirs, but has received only limited study for fractured reservoirs. Preliminary studies suggest recovery efficiencies in fractured reservoirs may be increased by as much as 50% with the application of steam relative to that of low temperature processes. The key mechanisms enhancing oil production at high temperature are the differential thermal expansion between oil and the pore volume, and the generation of gases within matrix blocks. Other mechanisms may also contribute to increased production. These mechanisms are relatively independent of oil gravity, making steam injection into naturally fractured reservoirs equally attractive to light and heavy oil deposits. The objectives of this research program are to quantify the amount of oil expelled by these recovery mechanisms and to develop a numerical model for predicting oil recovery in naturally fractured reservoirs during steam injection. The experimental study consists of constructing and operating several apparatuses to isolate each of these mechanisms. The first measures thermal expansion and capillary imbibition rates at relatively low temperature, but for various lithologies and matrix block shapes. The second apparatus measures the same parameters, but at high temperatures and for only one shape. A third experimental apparatus measures the maximum gas saturations that could build up within a matrix block. A fourth apparatus measures thermal conductivity and diffusivity of porous media. The numerical study consists of developing transfer functions for oil expulsion from matrix blocks to fractures at high temperatures and incorporating them, along with the energy equation, into a dual porosity thermal reservoir simulator. This simulator can be utilized to make predictions for steam injection processes in naturally-fractured reservoirs. Analytical models for capillary imbibition have also been developed.

  9. In situ generation of steam and alkaline surfactant for enhanced oil recovery using an exothermic water reactant (EWR)

    Science.gov (United States)

    Robertson, Eric P

    2011-05-24

    A method for oil recovery whereby an exothermic water reactant (EWR) encapsulated in a water soluble coating is placed in water and pumped into one or more oil wells in contact with an oil bearing formation. After the water carries the EWR to the bottom of the injection well, the water soluble coating dissolves and the EWR reacts with the water to produce heat, an alkali solution, and hydrogen. The heat from the EWR reaction generates steam, which is forced into the oil bearing formation where it condenses and transfers heat to the oil, elevating its temperature and decreasing the viscosity of the oil. The aqueous alkali solution mixes with the oil in the oil bearing formation and forms a surfactant that reduces the interfacial tension between the oil and water. The hydrogen may be used to react with the oil at these elevated temperatures to form lighter molecules, thus upgrading to a certain extent the oil in situ. As a result, the oil can flow more efficiently and easily through the oil bearing formation towards and into one or more production wells.

  10. Study of the effect of Illite and Kaolinite on low salinity water injection

    Directory of Open Access Journals (Sweden)

    Sina Rezaei-Gomari

    2015-07-01

    Full Text Available Low salinity water flooding as an Enhanced Oil Recovery (EOR Technique refers to the injection of brine with a lower salt content or ionic strength into an oil reservoir. Although the mechanisms have not yet been verified, the solution and surface chemistry as well as rock/fluid interactions have important roles that can be attributed to reservoir minerals being sensitive to small changes in solution properties. Among the proposed mechanisms, the clay content of rock and type of clay has been of significant interest in shedding light on the low salinity water flooding process. In this paper, two clay types (illite and kaolinite have been selected to investigate the individual contribution of each on the rock surface characterization andlow salinity water flooding performance. The results from contact angle measurement on the oil-wet calcite by low salinity water at room temperature show that the presence of low content of illite in the rock materials, in contrast to the kaolinite, reduces the contact angle significantly. This observation demonstrates that the low salinity water flooding performance depends strongly on the type of clay not on the amount of clay.

  11. Stability Proxies for Water-in-Oil Emulsions and Implications in Aqueous-based Enhanced Oil Recovery

    Directory of Open Access Journals (Sweden)

    Mehrnoosh Moradi

    2011-07-01

    Full Text Available Several researchers have proposed that mobility control mechanisms can positively contribute to oil recovery in the case of emulsions generated in Enhanced-Oil Recovery (EOR operations. Chemical EOR techniques that use alkaline components or/and surfactants are known to produce undesirable emulsions that create operational problems and are difficult to break. Other water-based methods have been less studied in this sense. EOR processes such as polymer flooding and LoSalTM injection require adjustments of water chemistry, mainly by lowering the ionic strength of the solution or by decreasing hardness. The decreased ionic strength of EOR solutions can give rise to more stable water-in-oil emulsions, which are speculated to improve mobility ratio between the injectant and the displaced oil. The first step toward understanding the connection between the emulsions and EOR mechanisms is to show that EOR conditions, such as salinity and hardness requirements, among others, are conducive to stabilizing emulsions. In order to do this, adequate stability proxies are required. This paper reviews commonly used emulsion stability proxies and explains the advantages and disadvantage of methods reviewed. This paper also reviews aqueous-based EOR processes with focus on heavy oil to contextualize in-situ emulsion stabilization conditions. This context sets the basis for comparison of emulsion stability proxies.

  12. Differences in microbial community composition between injection and production water samples of water flooding petroleum reservoirs

    Science.gov (United States)

    Gao, P. K.; Li, G. Q.; Tian, H. M.; Wang, Y. S.; Sun, H. W.; Ma, T.

    2015-06-01

    Microbial communities in injected water are expected to have significant influence on those of reservoir strata in long-term water flooding petroleum reservoirs. To investigate the similarities and differences in microbial communities in injected water and reservoir strata, high-throughput sequencing of microbial partial 16S rRNA of the water samples collected from the wellhead and downhole of injection wells, and from production wells in a homogeneous sandstone reservoir and a heterogeneous conglomerate reservoir were performed. The results indicate that a small number of microbial populations are shared between the water samples from the injection and production wells in the sandstone reservoir, whereas a large number of microbial populations are shared in the conglomerate reservoir. The bacterial and archaeal communities in the reservoir strata have high concentrations, which are similar to those in the injected water. However, microbial population abundance exhibited large differences between the water samples from the injection and production wells. The number of shared populations reflects the influence of microbial communities in injected water on those in reservoir strata to some extent, and show strong association with the unique variation of reservoir environments.

  13. Fractal-like charge injection kinetics in transformer oil stressed by high-voltage pulses

    Science.gov (United States)

    Zhang, X.; Zahn, M.

    2014-04-01

    Kerr electro-optic measurements are taken to study the transient electrode charge injection in high voltage pulsed transformer oil. It is found that the injection current densities from two stainless-steel parallel-plate electrodes with distinct surface roughness display fractal-like kinetics, i.e., power-law time dependence. Our measurement data agree with numerical simulation results of the time-dependent drift-diffusion model with the experimentally determined injection current boundary conditions. The fractal-like kinetics implies that the electric double layer processes contributing to injection are diffusion-limited. Physical mechanisms based on formative steps of adsorption-reaction-desorption reveal possible connections between geometrical characteristics of electrode surfaces and fractal-like kinetics of charge injection.

  14. Distribution of Complex Chemicals in Oil-Water Systems

    DEFF Research Database (Denmark)

    Riaz, Muhammad

    2011-01-01

    The deepwater energy sector represents one of the major growth areas of the oil and gas industry today. In order to meet the challenges of hydrate formation, corrosion, scaling and foaming the oil and gas industry uses many chemicals and their use has increased significantly over the years. In order to inhibit gas hydrate formation in subsea pipelines monoethylene glycol (MEG) and methanol are injected in large amounts. It is important to know the distribution of these chemicals in oil and water systems for economical operation of a production facility and to evaluate their impact on marine life. Furthermore distribution of chemicals is important information for downstream processing of oil and gas. The purpose of this project is the experimental measurement and the thermodynamic modeling of distribution of these complex chemicals in oil-water systems. Traditionally distribution of chemicals in oil-water system is calculated using octanol-water partition coefficients. But experiments carried out by StatoilR & D have shown that octanol-water partition coefficients (Kow) do not always mimic oil-water partition coefficients (Koil-water) and therefore calculations may not be always correct. In the first phase of this project experimental data on Kow, Koil-water and Khw (hexane-water partition coefficients) are collected and investigations were carried out to develop correlations so that Koil-water can be predicted using Kow and Khw. However, due to scarcity of experimental data and limited information about the molecular structure of production chemicals the correlation could only be obtained for few families like alcohols, glycols and alkanolamines with varying degree of reliability. In order to develop a thermodynamic model for the distribution of chemicals in oil-water systems experimental data are required but such data with natural gas-condensate/oil systems are very rare in the literature. In this project experimental work has been carried at Statoil R & D and an experimental method has been established and tested for such measurements. The mutual solubility of two North Sea condensates, MEG and water has been measured in the temperature range of 275-326 K at atmospheric pressure. The detailed composition of condensates is measured by GC analysis and 85 components are identified up to n-nonane and hundreds of ill-defined components in decane plus fraction. In order to develop a thermodynamic model for the distribution of chemicals in oil-water systems experimental data are required but such data with natural gas-condensate/oil systems are very rare in the literature. In this project experimental work has been carried at Statoil R & D and an experimental method has been established and tested for such measurements. The mutual solubility of two North Sea condensates, MEG and water has been measured in the temperature range of 275-326 K at atmospheric pressure. The detailed composition of condensates is measured by GC analysis and 85 components are identified up to n-nonane and hundreds of ill-defined components in decane plus fraction. When methanol and MEG are used as gas hydrate inhibitors, the most significant disadvantage, especially for methanol, is their loss in hydrocarbon phase(s). The successful estimation of inhibitor loss would enable the inhibitors injection optimization as a function of the system parameters such as temperature and water cut. In this project the distribution of water and inhibitors (methanol, MEG) in various phases is modeled using the CPA EoS. The hydrocarbon phase consists of mixture-1 (methane, ethane, n-butane) or mixture-2 (methane, ethane, propane, n-butane, n-heptane, toluene and n-decane). CPA can satisfactorily predict water content in the gas phase of the multicomponent systems containing mixture-1 over a range of temperature and pressure. Similarly the methanol content in gas phase of mixture-1 + water + methanol systems is predicted satisfactorily with accuracy in the range of experimental uncertainty. For VLLE of mixture-2 + water, mixture-2 + MEG + water and mixture-2 + methano

  15. Coherence of accelerated water bulk induced by rapid air injection

    International Nuclear Information System (INIS)

    Experiment of pressurized air injection into water-filled vessel with inner diameter 2 m was examined, to evaluate magnitude of water hammer induced by strike of accelerated water bulk due to steam explosion in ex-vessel coolant pool. And correlation of the bulk movement observed in past and this experiment, predicted water hammer pressure in the vessel. And, index to investigate degree of coherence, which affects the magnitude, was suggested and applied to two-dimensional analysis with two components. Two conclusions are highlighted. (1) Experiment of pressurized air injection into water filled vessel with inner diameter, 2 m, declared scale independent factor and scale effect of water bulk acceleration, compared with past experiments by smaller vessel. And expected water hammer pressure in the vessel was estimated based on the experiments. (2) Relative difference between velocity of bulk and that of bulk unit as vector was suggested as index to evaluate coherence of water bulk movement quantitatively. And application of the index to result of analysis with RELAP5-3D indicated this index was available and influence of growing bubble shape to the coherence was evidenced. (authors)

  16. Enhanced oil recovery using improved aqueous fluid-injection methods: an annotated bibliography. [328 citations

    Energy Technology Data Exchange (ETDEWEB)

    Meister, M.J.; Kettenbrink, G.K.; Collins, A.G.

    1976-10-01

    This annotated bibliography contains abstracts, prepared by the authors, of articles published between 1968 and early 1976 on tests of improved aqueous fluid injection methods (i.e., polymer and surfactant floods). The abstracts have been written and organized to facilitate studies of the oil recovery potential of polymer and surfactant floods under known reservoir conditions. 328 citations.

  17. 40 CFR 61.347 - Standards: Oil-water separators.

    Science.gov (United States)

    2010-07-01

    ...2010-07-01 false Standards: Oil-water separators. 61.347 Section 61... § 61.347 Standards: Oil-water separators. (a) Except as provided...following standards for each oil-water separator in which waste is placed...

  18. 40 CFR 63.686 - Standards: Oil-water and organic-water separators.

    Science.gov (United States)

    2010-07-01

    ...control of air emissions from oil-water separators and organic-water separators...National Emission Standards for Oil-Water Separators and Organic-Water Separators...National Emission Standards for Oil-Water Separators and Organic-Water...

  19. Co2 injection into oil reservoir associated with structural deformation

    KAUST Repository

    El-Amin, Mohamed

    2012-01-01

    In this work, the problem of structural deformation with two-phase flow of carbon sequestration is presented. A model to simulate miscible CO2 injection with structural deformation in the aqueous phase is established. In the first part of this paper, we developed analytical solution for the problem under consideration with certain types of boundary conditions, namely, Dirichlet and Neumann boundary conditions. The second part concerns to numerical simulation using IMPDES scheme. A simulator based on cell-centered finite difference method is used to solve this equations system. Distributions of CO2 saturation, and horizontal and vertical displacements have been introduced.

  20. Investigation of oil injection into brine for the strategic petroleum reserve : hydrodynamics experiments with simulant liquids.

    Energy Technology Data Exchange (ETDEWEB)

    Castaneda, Jaime N.; Shollenberger, Kim Ann (California Polytechnic State University, San Luis Obispo, CA); Torczynski, John Robert; Cote, Raymond O.; Barney, Jeremy; O' Hern, Timothy John

    2003-10-01

    An experimental program is being conducted to study a proposed approach for oil reintroduction in the Strategic Petroleum Reserve (SPR). The goal is to assess whether useful oil is rendered unusable through formation of a stable oil-brine emulsion during reintroduction of degassed oil into the brine layer in storage caverns. This report documents the first stage of the program, in which simulant liquids are used to characterize the buoyant plume that is produced when a jet of crude oil is injected downward from a tube into brine. The experiment consists of a large transparent vessel that is a scale model of the proposed oil injection process at the SPR. An oil layer is floated on top of a brine layer. Silicon oil (Dow Corning 200{reg_sign} Fluid, 5 cSt) is used as the simulant for crude oil to allow visualization of the flow and to avoid flammability and related concerns. Sodium nitrate solution is used as the simulant for brine because it is not corrosive and it can match the density ratio between brine and crude oil. The oil is injected downward through a tube into the brine at a prescribed depth below the oil-brine interface. Flow rates are determined by scaling to match the ratio of buoyancy to momentum between the experiment and the SPR. Initially, the momentum of the flow produces a downward jet of oil below the tube end. Subsequently, the oil breaks up into droplets due to shear forces, buoyancy dominates the flow, and a plume of oil droplets rises to the interface. The interface is deflected upward by the impinging oil-brine plume. Two different diameter injection tubes were used (1/2-inch and 1-inch OD) to vary the scaling. Use of the 1-inch injection tube also assured that turbulent pipe flow was achieved, which was questionable for lower flow rates in the 1/2-inch tube. In addition, a 1/2-inch J-tube was used to direct the buoyant jet upwards rather than downwards to determine whether flow redirection could substantially reduce the oil-plume size and the oil-droplet residence time in the brine. Reductions of these quantities would inhibit emulsion formation by limiting the contact between the oil and the brine. Videos of this flow were recorded for scaled flow rates that bracket the equivalent pumping rates in an SPR cavern. Image-processing analyses were performed to quantify the penetration depth of the oil jet, the width of the jet, and the deflection of the interface. The measured penetration depths are shallow, as predicted by penetration-depth models, in agreement with the assumption that the flow is buoyancy-dominated, rather than momentum-dominated. The turbulent penetration depth model provided a good estimate of the measured values for the 1-inch injection tube but overpredicted the penetration depth for the 1/2-inch injection tube. Adding a virtual origin term would improve the prediction for the 1/2-inch tube for low to nominal injection flow rates but could not capture the rollover seen at high injection flow rates. As expected, the J-tube yielded a much narrower plume because the flow was directed upward, unlike the downward-oriented straight-tube cases where the plume had to reverse direction, leading to a much wider effective plume area. Larger surface deflections were caused by the narrower plume emitted from the J-tube. Although velocity was not measured in these experiments, the video data showed that the J-tube plume was clearly faster than those emitted from the downward-oriented tubes. These results indicate that oil injection tube modifications could inhibit emulsion formation by reducing the amount of contact (both time and area) between the oil and the brine. Future studies will employ crude oil, saturated brine, and interfacial solids (sludge) from actual SPR caverns.

  1. Effect of Combined Low Salinity and Surfactant Injection on Oil Recovery in Aged Bentheimer Sandstones at Different Temperatures

    OpenAIRE

    Riisøen, Solveig

    2012-01-01

    A moderate increase in crude oil recovery by reduction in salinity of the injection brine has been observed for numerous laboratory core flood experiments. The underlying mechanisms behind increased recovery by low salinity injection are not fully understood and are suggested to relate to complex crude oil/rock/brine interactions. Recent studies have also shown a positive effect by combining injection of low salinity brine and surfactant flooding. In this study, ...

  2. Radiating chemical decomposition of oil hydrocarbons in water environment

    International Nuclear Information System (INIS)

    Full text: Water resources purification problems from natural oil and mineral oils has an important value as for extracting additional oil resources from oilcontained waste waters, so for safeguard of water resources from pollution. For the past 150 years there were 250 artificial lakes formed on the territory of Absheron peninsula of Azerbaijan as a result of oil deposits exploitation, concentration of which sometimes exceeds 25 mg/l. Every year enterprises of Azerbaijan oil industry reset more than 4-5 tons of waste waters to an environment during production of 1 ton of oil. Taking into account the fact that the larger danger for environment represents an oil slicks and emulsified mineral oils in it, the possibility of application of ionizing radiation for mineral oils of waste waters becomes the more important circumstance during solving of some ecological problems. The possibilities radiation-chemical technology application while purification of waste waters from oil pollutions had been studied and also it is studied some legitimacies of radiation-chemical molding of oil hydrogens in water sphere. In case of radiation purification of water from oil impurities it is possible the radiation-chemical molding of oil hydrogens during the process and removal of molding products from water. Data given in this article proves that there are happens an effective interaction between active particles of different origin.

  3. EMISSION ANALYSIS OF DI-DIESEL ENGINE AT DIFFERENT INJECTION PRESSURES USING JATROPHA AND RUBBER SEED OIL BLENDED WITH DIESEL

    OpenAIRE

    S. Mahalingam; B. R. RameshBapu

    2014-01-01

    Biodiesel as a renewable fuel has been considered as the best alternate for diesel fuel now a days.This fossil fuel can be used in diesel engine with or without any modi?cation.The injection pressure and injection timing are the major influencing parameters forthe performance and emission of diesel engine.In thispresentstudy,the emission analysis of vegetable oil, Jatropha oil and rubber seed oil crushed from the seed, esterified and blended with pure diesel fuel. A single cyl...

  4. The effect of hot water injection on sandstone permeability

    DEFF Research Database (Denmark)

    Rosenbrand, Esther; Haugwitz, Christian; Jacobsen, Peter Sally Munch; Kjøller, Claus; Fabricius, Ida Lykke

    2014-01-01

    Seasonal energy storage can be achieved by hot water injection in geothermal sandstone aquifers. We present an analysis of literature data in combination with new short-term flow through permeability experiments in order to address physical and physico-chemical mechanisms that can alter permeability when sandstones are heated from 20°C to 70–200°C. The pore surface area per unit pore volume was used to normalise permeability data, so that the temperature effect on samples with different pore siz...

  5. Experimental study of low flow steam injection into subcooled water

    International Nuclear Information System (INIS)

    In an experimental study of low-flow vapor injection, three different modes of steam chugging were observed. For one of these modes, the encapsulating bubble chug, photos are presented from detailed motion pictures of the steam/water interface; and the pressure oscillations at the pool solid boundaries are plotted. The results indicate that the hydrodynamic motion is not severely affected by the heat transfer except when turbulence is generated at the interface. 9 refs

  6. Study of processes involved in oil spill gathering in water

    International Nuclear Information System (INIS)

    Separate flow of an oil/water mixture along a tray has been found possible only at very low rates. Higher flowrates cause surges where some oil globules begin running away from the bulk of blocked oil, skipping under the boom used in experiments. It has been found that booms used for gathering oil spills on the water surface will be efficient of water flows below 0.16 m/sec. 2 figs

  7. Combination of low salinity water flooding with surfactant injection : a new hybrid EOR process

    Energy Technology Data Exchange (ETDEWEB)

    Alagic, Edin

    2010-03-15

    This work addresses different aspects related to the hybrid EOR process, low salinity surfactant injection including closely connected topics such as low salinity water injection and physicochemical properties of micro emulsions. In the first part, measurements of self-diffusion, ultrasonic speed, density and viscosity (i.e., shear dependency) are evaluated as methods to detect the structural changes in the micro emulsions imposed with a variation of the brine salinity. The viscosity measurements on Winsor type micro emulsions and adjacent excess phases all show Newtonian behaviour for shear controlled measurements in the interval 1- 1 000 s-1. The microemulsion viscosity reaches a maximum at the phase transition between Winsor I and Winsor III, which is likely to be coupled to structural changes (i.e., clustering of the oil-in-water droplets where attractive interactions between separate aggregates lead to the formation of increasing number of transient clusters) or existence of a percolation threshold. Microemulsion densities seem to be a good indicator for the phase transitions. The results obtained from speed of sound and self-diffusion measurements indicate, however, structural changes of the surfactant aggregates within the Winsor I region. The diffusion coefficient of the surfactant reaches a maximum in the middle of the Winsor III phase, which coincide well with the optimal salinity, SP found in static phase behaviour studies. All investigated parameters indicate changes at the phase transition boundary from Winsor III to Winsor II. In the second part, we sought a better understanding of low salinity water injection method by conducting core displacement experiments using the same COBR ensemble. The results from both secondary and tertiary injections proves that injection of low salinity water (LS) into aged Berea core samples give a moderate increase in oil recovery compared to the results obtained with sea water (SW) as the displacing fluid. This is attributed to destabilisation of adsorbed oil layers by the injection of brine lower in salinity than the connate water. A comparison of the performance of tertiary LS floods versus secondary LS floods indicates that in both cases the total oil recovery falls roughly into the same range. It has also been shown that secondary LS floods performed on the aged core samples affect output parameters (i.e., oil recovery profile, water breakthrough (WBT), endpoint permeability to water k{sub w}(S{sub 0r}) and differential pressure) in another fashion than secondary SW floods. Further, the results from secondary SW floods conducted on the aged cores were used to confirm that aging process with crude oil at elevated temperature for extended time period has indeed managed to decrease the water-wetness of the core samples. By establishing this reference and exploiting the close relationship between the aforementioned parameters and wettability, a qualitative differentiation of wettability regimes is thus used to elucidate the observed difference in behaviour of water floods. Features accompanied with secondary LS floods such as delayed WBT, reduced two-phase production period after WBT, lower k{sub w}(S{sub 0r}) after LS floods at lower S{sub 0r}compared to k{sub w}(S{sub 0r}) after SW floods at higher S{sub 0r}, indicate a wettability change toward more water-wet state during LS injections. An attempt to relate low k{sub w}(S{sub 0r}) after LS floods to possible fines migration and subsequent blocking in pore constrictions, revealed that turbidity of the effluent from a more water-wet core (i.e., used in its natural state) was significantly higher than from the aged core. Increased turbidity of effluent indicates a larger quantity of eluted fine particles from the core matrix in the former case. Partially, these results infer that fines migration is not the predominant mechanism explaining increased oil recovery by LS injection in our experiments. The effluent ion analysis from secondary LS floods showed that Mg2+ were strongly retained in the aged cores while Ca2+ were being

  8. Conceptual design of safety injection tanks using saturated water

    Energy Technology Data Exchange (ETDEWEB)

    Park, Hae Min; Jeong, Yong Hoon; Chang, Won Joon [Korea Advanced Institute of Science and Technology, Daejeon (Korea, Republic of)

    2009-07-01

    Safety Injection Tanks (SITs) which is the one of Safety Injection System (SIS) play an important role in mitigating the Loss of Coolant Accidents (LOCAs) in Pressurized Water Reactor (PWR). APR1400 has the advanced 4 SITs directly connected to a reactor vessel. We expect the capacity of the SITs is getting more important since the coolant from SITs equipped with a FD during LBLOCA can replace the injection from low pressure safety injection pumps (LPSIPs). In designing a larger capacity SIT, we may have three problems; the excessively large volume for pressurized N{sub 2} gas, which is about 1/3 of the total volume, the difficulties controlling injection flowrate and the solubility of the non-condensable N{sub 2} gas in the coolant. In here, there is the contradiction which is 'there must be nitrogen gas for pressurization but there must not be nitrogen gas for more coolant.' For this problem, the axiomatic design (AD) theory enabled us to define or regularize the intrinsic problem which is termed the coupling and the contradiction. TRIZ facilitates creating solutions on the contradiction. This study proposes a conceptual design of SITs which are pressurized by steam from the saturated water as a demonstration of the conceptual design framework, AD theory and TRIZ. The purpose of this conceptual design is to increase coolant volume and to reduce N{sub 2} gas volume in SITs. In order to investigate the feasibility of the proposed design, we derived an analytical model to find the heat loss of saturated water and thermo-hydraulic safety analysis using MARS3.1. To confirm the safety and integrity of core, we conducted LBLOCA simulation to find peak cladding temperature (PCT) of design using the proposed SITs comparing with the conventional SITs. From the analysis results, the benefits of the new SIT design were observed in terms of the PCT, the quenching time and the size. And the new SIT design may enable emergency core cooling water to be injected efficiently and can be applicable to SIT which has smaller size than the existing and simplified design of SIS.

  9. Modeling and detection of oil in sea water

    DEFF Research Database (Denmark)

    Xenaki, Angeliki; Gerstoft, Peter; Mosegaard, Klaus

    2013-01-01

    The challenge of a deep-water oil leak is that a significant quantity of oil remains in the water column and possibly changes properties. There is a need to quantify the oil settled within the water column and determine its physical properties to assist in the oil recovery. There are currently no methods to map acoustically submerged oil in the sea. In this paper, high-frequency acoustic methods are proposed to localize the oil polluted area and characterize the parameters of its spatial covaria...

  10. Modelling the effect of gas injections on the stability of asphaltene-containing crude oils

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, X.; Moorwood, T. [Infochem, Munich (Germany); Merino Garcia, D.; Pena Diez, J.L. [Repsol YPF, Madrid (Spain)

    2008-07-01

    In oil fields where asphaltene deposits occur, they present major remediation problems and can halt production due to flow blockage. Crude oils which precipitate asphaltenes generally contain both asphaltene molecules and lighter resin molecules. Resins are thought to solvate the asphaltene molecules, thus stabilizing the solution, while light gases have the opposite effect. In order to model asphaltene phase behaviour, it is important to understand the impact of adding gas to asphaltene-containing crudes. This study presented several experimental investigations of gas injection into asphaltene-containing crudes. The trends of asphaltene destabilization were discussed. The injection gases ranged from pure gases to a gas condensate. The data were modelled using a conventional equation of state together with an extra term that considered the association between asphaltene molecules and their solvation by resins. Since the model could simultaneously described the gas, oil and asphaltene phases, it was possible to calculate phase stability and phase equilibria. However, a different model had to be used to obtain the gas-oil equilibrium because the use of solubility parameters only allows the stability of the asphaltene phase to be calculated. The model correctly predicted that the gases will promote asphaltene precipitation. In its original form, the model tended to over-predict the trend. The optimal parameter values needed to represent all the available experimental data were determined. The extent to which the effect of gas injection on asphaltenes can be predicted was then discussed.

  11. COMBUSTION ANALYSIS OF ALGAL OIL METHYL ESTER IN A DIRECT INJECTION COMPRESSION IGNITION ENGINE

    Directory of Open Access Journals (Sweden)

    HARIRAM V.

    2013-02-01

    Full Text Available Algal oil methyl ester was derived from microalgae (Spirulina sp. The microalga was cultivated in BG 11 media composition in a photobioreactor. Upon harvesting, the biomass was filtered and dried. The algal oil was obtained by a two step solvent extraction method using hexane and ether solvent. Cyclohexane was added to biomass to expel the remaining algal oil. By this method 92% of algal oil is obtained. Transesterification process was carried out to produce AOME by adding sodium hydroxide and methanol. The AOME was blended with straight diesel in 5%, 10% and 15% blend ratio. Combustion parameters were analyzed on a Kirloskar single cylinder direct injection compression ignition engine. The cylinder pressure characteristics, the rate of pressure rise, heat release analysis, performance and emissions were studied for straight diesel and the blends of AOME’s. AOME 15% blend exhibits significant variation in cylinder pressure and rate of heat release.

  12. Impact of iodized oil injection during pregnancy on thyroid function tests of offspring

    International Nuclear Information System (INIS)

    Previous studies have shown that injection of iodized oil in pregnant women can be used as a prophylactic strategy for iodine deficiency disorders and may improve the growth indices of their offspring. Since administration of pharmacological doses of iodine may lead occasionally to large goiter and rarely to hypothyroidism, in the present study the thyroid function tests of neonates and infants born to women who had received 480 mg iodized oil intramuscularly during pregnancy were assessed and compared to those of a control group. Off 277 cord blood samples obtained from Mazandaran and Khohkiluyeh-Boyerahmad provinces, 125 made up the case (injected) and 152 the control (non-injected) group. Of 1026 blood samples of the neonates and infants from Mazandaran province. 544 made up the case and 482 the control group. Serum T4, T3 and TSH concentrations were measured with RIA kits. in the cord blood samples, mean serum T4 in cases who had received iodized oil was lower than that of the control group:140± 32 vs. 149± 33 nmol/L, respectively; p3 and TSH were not however different. In the neonates and infants, T4 and T3 concentrations were significantly higher in the case than control group:178± 40 vs. 168± and 3.5±0,02 nmol/L, respectively, both p3 and decreased TSH were seen in infants of mothers who were injected in the second and third trimesters of pregnancy. Injection of iodized oil in pregnant women does not cause hypothyroidism in the offsprings, however it does cause a transient increase in serum thyroid hormones and a decrease in TSH concentrations

  13. 21 CFR 522.2005 - Propofol injection.

    Science.gov (United States)

    2010-04-01

    ...2010-04-01 2010-04-01 false Propofol injection. 522.2005 Section 522...FORM NEW ANIMAL DRUGS § 522.2005 Propofol injection. (a) Specifications...oil-in-water emulsion containing 10 milligrams of propofol per milliliter. (b)...

  14. Planning of tritium injections for ground water recharge measurements

    International Nuclear Information System (INIS)

    Groundwater recharge takes place through various sources and it depends upon the local soil composition, vegetative cover, surface topography, subsurface geology and hydrological conditions, etc. The measurement of recharge of groundwater reservoir using tritium tracer is based on the principle of a piston-type flow. The downward movement of soil moisture in the unsaturated zone is followed by tagging a layer of soil with tritiated water (10 ?Ci/ml) below the root zone before the onset of monsoon rains or any other recharge source. The experiments were conducted in Haryana during 1973-74 by adopting a layout of 2 points at 2 m apart in a row with a close group of 5 injections in 10 cm radial distance at each point at one site. This study was done on an extensive scale by having 26 injections sites spread over 44222 sq.km area of the state. Although the tritium injections layout adopted was an improved version of the similar experiments earlier conducted in the Uttar Pradesh and Punjab, further modifications in layout seem to be imperative to obtain realistic data on recharge rates in case of comprehensive microlevel investigations. The determination of the soil moisture and density was done with conventional methods. It is felt that the use of nucleonic gauges should have been more suitable. This paper discusses the modifications in the layout of tritium injections and suggests necessary improvements. (author)

  15. Study of disbudding goat kids following injection of clove oil essence in horn bud region.

    Science.gov (United States)

    Molaei, Mohammad Mahdi; Mostafavi, Ali; Kheirandish, Reza; Azari, Omid; Shaddel, Mohsen

    2015-01-01

    This study was performed to evaluate the efficacy of injection of essential oil of Eugenia caryophyllata in the kid horn buds, as a new chemical technique for disbudding. Five-day-old healthy goat kids from both sexes (n = 16) were divided randomly into 4 equal groups. In groups 1, 2 and 3, 0.2 mL of clove essence and in group 4 (control) 0.2 mL of normal saline was injected into the left horn bud of goat kids. Right horn bud in all kids was considered to ensure that they are horned. During the study, the rate of horn growth were evaluated in determined time intervals between groups 1 and 4. Tissue samples were taken from right and left horn bud in groups 2 and 3, at five and ten days after clove essence injection, for microscopic study. The results of the study showed that the clove essence stopped horn growth, whereas there was no significant difference in horn growth rate between left and right horns after injection of normal saline, in group 4. Histopathological study showed that injection of clove essence caused complete necrosis of epidermis and underlying dermis with collagenolysis in horn bud tissues, 5 days after injection and then progress in healing process was observed after 10 days. According to the results of this study, it can be concluded that the injection of clove essence is an effective method to stop horn growth without any undesirable effects on clinical parameters in goat kids. PMID:25992247

  16. Hot gas injection as an artificial lift system through a concentric tubing completion in a heavy oil well, Pilon field, Faja Petrolifera del Orinoco

    Energy Technology Data Exchange (ETDEWEB)

    Marfissi, S.; Lujan, A. [PDVSA EandP (Venezuela)

    2011-07-01

    The Pilon Field in the Morichal District, Venezuela is producing heavy oil with numerous gas lift wells. Some of these wells are now inactive due to casing damage. The purpose of this paper is to assess the benefits of using hot gas injection as an artificial lift system through a concentric tubing completion in such wells. A pilot test was conducted on a well presenting a low water cut and 12 degree API, an indirect fire heater was installed near the wells. Results showed that heat losses were minimized thanks to the concentric pipe completion. In addition hot gas injection resulted in an oil production increase of 57%. The hot gas injection method used with a concentric tubing completion was proved to be a good alternative to the use of diluent but an economic analysis is nevertheless recommended to determine the costs of installing heating equipment.

  17. Performance evaluation of common rail direct injection (CRDI engine fuelled with Uppage Oil Methyl Ester (UOME

    Directory of Open Access Journals (Sweden)

    D.N. Basavarajappa

    2015-02-01

    Full Text Available For economic and social development of any country energy is one of the most essential requirements. Continuously increasing price of crude petroleum fuels in the present days coupled with alarming emissions and stringent emission regulations has led to growing attention towards use of alternative fuels like vegetable oils, alcoholic and gaseous fuels for diesel engine applications. Use of such fuels can ease the burden on the economy by curtailing the fuel imports. Diesel engines are highly efficient and the main problems associated with them is their high smoke and NOx emissions.  Hence there is an urgent need to promote the use of alternative fuels in place of high speed diesel (HSD as substitute. India has a large agriculture base that can be used as a feed stock to obtain newer fuel which is renewable and sustainable. Accordingly Uppage oil methyl ester (UOME biodiesel was selected as an alternative fuel. Use of biodiesels in diesel engines fitted with mechanical fuel injection systems has limitation on the injector opening pressure (300 bar. CRDI system can overcome this drawback by injecting fuel at very high pressures (1500-2500 bar and is most suitable for biodiesel fuels which are high viscous. This paper presents the performance and emission characteristics of a CRDI diesel engine fuelled with UOME biodiesel at different injection timings and injection pressures. From the experimental evidence it was revealed that UOME biodiesel yielded overall better performance with reduced emissions at retarded injection timing of -10° BTDC in CRDI mode of engine operation.

  18. Performance evaluation of common rail direct injection (CRDI engine fuelled with Uppage Oil Methyl Ester (UOME

    Directory of Open Access Journals (Sweden)

    D.N. Basavarajappa

    2015-02-01

    Full Text Available For economic and social development of any country energy is one of the most essential requirements. Continuously increasing price of crude petroleum fuels in the present days coupled with alarming emissions and stringent emission regulations has led to growing attention towards use of alternative fuels like vegetable oils, alcoholic and gaseous fuels for diesel engine applications. Use of such fuels can ease the burden on the economy by curtailing the fuel imports. Diesel engines are highly efficient and the main problems associated with them is their high smoke and NOx emissions. Hence there is an urgent need to promote the use of alternative fuels in place of high speed diesel (HSD as substitute. India has a large agriculture base that can be used as a feed stock to obtain newer fuel which is renewable and sustainable. Accordingly Uppage oil methyl ester (UOME biodiesel was selected as an alternative fuel. Use of biodiesels in diesel engines fitted with mechanical fuel injection systems has limitation on the injector opening pressure (300 bar. CRDI system can overcome this drawback by injecting fuel at very high pressures (1500-2500 bar and is most suitable for biodiesel fuels which are high viscous. This paper presents the performance and emission characteristics of a CRDI diesel engine fuelled with UOME biodiesel at different injection timings and injection pressures. From the experimental evidence it was revealed that UOME biodiesel yielded overall better performance with reduced emissions at retarded injection timing of -10° BTDC in CRDI mode of engine operation.

  19. Numerical and experimental study of water/oil emulsified fuel combustion in a diesel engine

    OpenAIRE

    Samec, Niko; Kegl, Breda; Dibble, Robert W.

    2012-01-01

    Numerical and experimental studies were made on some of the chemical and physical properties of wateržoil emulsified fuel (W/OEF) combustion characteristics. Numerical investigations of W/OEF combustion's chemical kinetic aspects have been performed by simulation of water/n-heptane mixture combustion, assuming a model of a homogenous reactor's concentric shells. The injection and fuel spray characteristics are analyzed numerically also in order to study indirectly the physical effects of wate...

  20. Study of disbudding goat kids following injection of clove oil essence in horn bud region

    OpenAIRE

    Molaei, Mohammad Mahdi; Mostafavi, Ali; Kheirandish, Reza; AZARI, Omid; Shaddel, Mohsen

    2015-01-01

    This study was performed to evaluate the efficacy of injection of essential oil of Eugenia caryophyllata in the kid horn buds, as a new chemical technique for disbudding. Five-day-old healthy goat kids from both sexes (n = 16) were divided randomly into 4 equal groups. In groups 1, 2 and 3, 0.2 mL of clove essence and in group 4 (control) 0.2 mL of normal saline was injected into the left horn bud of goat kids. Right horn bud in all kids was considered to ensure that they are horned. During t...

  1. Water Injection on Commercial Aircraft to Reduce Airport Nitrogen Oxides

    Science.gov (United States)

    Daggett, David L.; Hendricks, Robert C.; Fucke, Lars; Eames, David J. H.

    2010-01-01

    The potential nitrogen oxide (NO(x) reductions, cost savings, and performance enhancements identified in these initial studies of waterinjection technology strongly suggest that it be further pursued. The potential for engine maintenance cost savings from this system should make it very attractive to airline operators and assure its implementation. Further system tradeoff studies and engine tests are needed to answer the optimal system design question. Namely, would a low-risk combustor injection system with 70- to 90-percent NO(x) reduction be preferable, or would a low-pressure compressor (LPC) misting system with only 50-percent NO(x) reduction but larger turbine inlet temperature reductions be preferable? The low-pressure compressor injection design and operability issues identified in the report need to be addressed because they might prevent implementation of the LPC type of water-misting system. If water-injection technology challenges are overcome, any of the systems studied would offer dramatic engine NO(x) reductions at the airport. Coupling this technology with future emissions-reduction technologies, such as fuel-cell auxiliary power units will allow the aviation sector to address the serious challenges of environmental stewardship, and NO(x) emissions will no longer be an issue at airports.

  2. 40 CFR 60.693-2 - Alternative standards for oil-water separators.

    Science.gov (United States)

    2010-07-01

    ... Alternative standards for oil-water separators. 60.693-2 Section... Alternative standards for oil-water separators. (a) An owner or operator...operate a floating roof on an oil-water separator tank, slop oil tank,...

  3. Portable water filtration system for oil well fractionation

    Energy Technology Data Exchange (ETDEWEB)

    Seibert, D. L.

    1985-08-13

    The invention comprises a portable, multi-stage filtration system utilized in filtering water for an oil and gas stimulation process commonly known as fracking. Three stages are used, the first being a straining operation reducing the size of particulate matter in the water to about three-eighths of an inch. The second stage is a centrifugal separator, reducing the particle size to about 50 microns. The final stage utilizes a cartridge-type filter giving a final particle size in the water of about 5 microns. In this manner, water which is injected into the well head during the fracking process and which is obtained from readily available sources such as ponds, streams and the like is relatively free of particulate matter which can foul the fracking process. The invention, by virtue of being mounted on a trailer, is portable and thus can be easily moved from site to site. Water flow rates obtained using the invention are between 250 and 300 gallons per minute, sufficient for processing a small to medium sized well.

  4. Performance of Scroll-Type Helium Compressor with Oil Injection Cooling Device

    Science.gov (United States)

    Shiibayashi, Masao; Tomita, Yoshikatsu; Izunaga, Yasushi; Maeda, Naoki

    In the cryoelectronics field where the helium gas is utilized as a working field, rotary-type and reciprocating-type compressors are popular for the discharge capacity of less than 200Nm3/h and screw-type compressor for a larger capacity. In this study, scroll-type fluid machinery, featuring both high efficiency and high reliability, is applied to a helium compressor with the discharge capacity of 50 Nm3/h. Experimental investigations are performed about oil injection cooling methods and improvement of the compression efficiency. As a result, a volumetric efficiency of 92 % and an overall adiabatic efficiency of 79 % are obtained under the condition of a theoretical compression ratio of 5.2 by a developed scroll compressor with a nominal motor output 2.2 kW. At the same time an effective cooling method with a single oil injection port is obtained.

  5. Mathematical modeling of the working cycle of oil injected rotary twin screw compressor

    Energy Technology Data Exchange (ETDEWEB)

    Seshaiah, N. [Cryogenics and Gas dynamics Laboratory, Department of Mechanical Engineering, National Institute of Technology, Sector-2, NIT Campus, Rourkela 769008, Orissa (India)]. E-mail: seshuet@yahoo.com; Ghosh, Subrata Kr. [Cryogenics and Gas dynamics Laboratory, Department of Mechanical Engineering, National Institute of Technology, Sector-2, NIT Campus, Rourkela 769008, Orissa (India); Sahoo, R.K. [Cryogenics and Gas dynamics Laboratory, Department of Mechanical Engineering, National Institute of Technology, Sector-2, NIT Campus, Rourkela 769008, Orissa (India); Sarangi, Sunil Kr. [Cryogenics and Gas dynamics Laboratory, Department of Mechanical Engineering, National Institute of Technology, Sector-2, NIT Campus, Rourkela 769008, Orissa (India)

    2007-01-15

    Oil injected twin-screw air and gas compressors are widely used for medium pressure applications in many industries. Low cost air compressors can be adopted for compression of helium and special gases, leading to significant cost saving. Mathematical analysis of oil injected twin-screw compressor is carried out on the basis of the laws of perfect gas and standard thermodynamic relations. Heat transfer coefficient required for computer simulation is experimentally obtained and used in performance prediction, when the working medium being air or helium. A mathematical model has been developed for calculating the compressor performance and for validating the results with experimental data. The flow coefficients required for numerical simulation to calculate leakage flow rates are obtained from efficiency verses clearance curves. Effect of some of the compressor operating and design parameters on power and volumetric efficiencies have been analyzed and presented.

  6. Mathematical modeling of the working cycle of oil injected rotary twin screw compressor

    International Nuclear Information System (INIS)

    Oil injected twin-screw air and gas compressors are widely used for medium pressure applications in many industries. Low cost air compressors can be adopted for compression of helium and special gases, leading to significant cost saving. Mathematical analysis of oil injected twin-screw compressor is carried out on the basis of the laws of perfect gas and standard thermodynamic relations. Heat transfer coefficient required for computer simulation is experimentally obtained and used in performance prediction, when the working medium being air or helium. A mathematical model has been developed for calculating the compressor performance and for validating the results with experimental data. The flow coefficients required for numerical simulation to calculate leakage flow rates are obtained from efficiency verses clearance curves. Effect of some of the compressor operating and design parameters on power and volumetric efficiencies have been analyzed and presented

  7. Stabilization Mechanisms of Water-in-Crude Oil Emulsions

    OpenAIRE

    Abdurahman H. Nour; Suliman, A.; Mahmmoud M. Hadow

    2008-01-01

    During the lifting and production of crude oil, water/oil emulsions are created. They are stabilized by asphaltenes and resins which are colloidally dispersed in the crude oil. Asphaltenes consist mainly of polar heterocompounds. It is known that they decrease the interfacial tension between oil and water and form stable interfacial films. Both effects favour the formation and stabilization of emulsions. Resins are complex high-molecular-weight compounds that are not soluble in ethylacetate, ...

  8. Prokaryotic community structure and activity of sulfate reducers in production water from high-temperature oil reservoirs with and without nitrate treatment

    DEFF Research Database (Denmark)

    Gittel, Antje; Sørensen, Ketil; Skovhus, Torben L.; Ingvorsen, Kjeld; Schramm, Andreas

    2009-01-01

    Sulfate-reducing prokaryotes (SRP) cause severe problems like microbial corrosion and reservoir souring in seawater-injected oil production systems. One strategy to control SRP activity is the addition of nitrate to the injection water. Production waters from two adjacent, hot (80°C) oil reservoirs, one with and one without nitrate treatment, were compared for prokaryotic community structure and activity of SRP. Bacterial and archaeal 16S rRNA gene analyses revealed higher prokaryotic abundance ...

  9. Cold water injection into two-phase mixtures

    International Nuclear Information System (INIS)

    This report presents the results of a review of the international literature regarding the dynamic loadings associated with the injection of cold water into two-phase mixtures. The review placed emphasis on waterhammer in nuclear power plants. Waterhammmer incidence data were reviewed for information related to thermalhydraulic conditions, underlying causes and consequential damage. Condensation induced waterhammer was found to be the most significant consequence of injecting cold water into a two-phase system. Several severe waterhammer incidents have been attributed to slug formation and steam bubble collapse under conditions of stratified steam and cold water flows. These phenomena are complex and not well understood. The current body of experimental and analytical knowledge is not large enough to establish maps of expected regimes of condensation induced waterhammer. The Electric Power Research Institute, in the United States, has undertaken a major research and development programme to develop the knowledge base for this area. The limited models and data currently available show that mechanical parameters are as important as thermodynamic conditions for the initiation of condensation induced waterhammer. Examples of bounds for avoiding two-phase waterhammer are given. These bounds are system specific and depend upon parameters such as pump capacity, pipe length and pipe orientation

  10. Sustainable water management in Alberta's oil sands

    Energy Technology Data Exchange (ETDEWEB)

    Byers, Bill; Usher, Robyn; Roach, Andrea [CH2M HILL, Englewood, CO (United States); Lambert, Gord; Kotecha, Prit [Suncor Energy Inc., Calgary (Canada)

    2012-07-01

    The Canadian Association of Petroleum Producers forecast published in 2011 predicts that oil production from oil sands will increase by 50% in the next 3 years and double by 2020. This rate of growth will result in significant pressure on water resources; water use per barrel of oil sands production is comparable to other energy resources - about 2.5 barrels of fresh water per barrel of oil produced are used by mining operations and 0.5 barrels by in-situ operations. Suncor Energy Inc. (Suncor) was the first company to develop the oil sands in northern Alberta and holds one of the largest oil sands positions in Canada. In 2010, Suncor announced plans to increase production to more than 1 million barrels of oil equivalent per day by 2020, which it plans to achieve through oil sands production growth of approximately 10% per year. Because water supply and potential impacts to water quality are critical to its future growth, in 2010-2011 Suncor conducted a risk assessment to identify water-related business risks related to its northern Alberta operations. The assessment identified more than 20 high level business risks in strategic water risk areas including water supply, water reuse, storm water management, groundwater, waste management and river water return. The risk assessment results prompted development of a strategic roadmap to guide water stewardship across Suncor's regional operations. The roadmap describes goals, objectives, and specific activities for each of six key water risk areas, and informs prioritization and selection of prospective water management activities. Suncor is not only exploring water within its own boundaries, but is also collaborating with other oil sands producers to explore ways of integrating its water systems through industry consortia; Suncor is a member of the Oil Sands Leadership Initiative and of the recently formed Canadian Oil Sands Innovation Alliance, among others. (author)

  11. Comparison of different injection modes in edible oil minor components analysis.

    Science.gov (United States)

    Purcaro, Giorgia; Barp, Laura; Conte, Lanfranco

    2015-07-01

    Waxes and fatty acid alkyl esters are minor components used as official parameters to control the authenticity and quality of a high-value olive oil product. A poor measurement can lead to a misleading classification of the oil. The official method requires their analysis together by capillary gas chromatography equipped with a flame ionization detector and an on-column injector to avoid discrimination and thermal degradation. The degradation can occur to a different extent if different (and not properly optimized) injectors are used. However, other injection techniques, such as programmed-temperature vaporizer, are much more versatile and more widespread. The aim of the present work was to compare the performance of a programmed-temperature vaporizer injector, in on-column and splitless mode, with the on-column injector to analyze alkyl esters and waxes. Discrimination among high-boiling compounds was evaluated, as well as the occurrence of thermal degradation, especially of sterols and diterpene alcohol (phytyl and geranylgeraniol) esters. A proper optimization of a programmed-temperature vaporizer injection, with particular attention to the liner selection, was proven to provide comparable results to the traditional on-column injection. A performance comparison was carried out both on standard mixtures and on real oil samples. PMID:25903351

  12. The effect of hot water injection on sandstone permeability

    DEFF Research Database (Denmark)

    Rosenbrand, Esther; Haugwitz, Christian

    2014-01-01

    Seasonal energy storage can be achieved by hot water injection in geothermal sandstone aquifers. We present an analysis of literature data in combination with new short-term flow through permeability experiments in order to address physical and physico-chemical mechanisms that can alter permeability when sandstones are heated from 20°C to 70–200°C. The pore surface area per unit pore volume was used to normalise permeability data, so that the temperature effect on samples with different pore size could be compared. In sandstones containing the clay mineral kaolinite, heating reduced permeability, suggesting that the observed permeability reduction was due to kaolinite mobilisation. The effect was partly reversible.

  13. Aging study of boiling water reactor high pressure injection systems

    Energy Technology Data Exchange (ETDEWEB)

    Conley, D.A.; Edson, J.L.; Fineman, C.F. [Lockheed Idaho Technologies Co., Idaho Falls, ID (United States)

    1995-03-01

    The purpose of high pressure injection systems is to maintain an adequate coolant level in reactor pressure vessels, so that the fuel cladding temperature does not exceed 1,200{degrees}C (2,200{degrees}F), and to permit plant shutdown during a variety of design basis loss-of-coolant accidents. This report presents the results of a study on aging performed for high pressure injection systems of boiling water reactor plants in the United States. The purpose of the study was to identify and evaluate the effects of aging and the effectiveness of testing and maintenance in detecting and mitigating aging degradation. Guidelines from the United States Nuclear Regulatory Commission`s Nuclear Plant Aging Research Program were used in performing the aging study. Review and analysis of the failures reported in databases such as Nuclear Power Experience, Licensee Event Reports, and the Nuclear Plant Reliability Data System, along with plant-specific maintenance records databases, are included in this report to provide the information required to identify aging stressors, failure modes, and failure causes. Several probabilistic risk assessments were reviewed to identify risk-significant components in high pressure injection systems. Testing, maintenance, specific safety issues, and codes and standards are also discussed.

  14. Aging study of boiling water reactor high pressure injection systems

    International Nuclear Information System (INIS)

    The purpose of high pressure injection systems is to maintain an adequate coolant level in reactor pressure vessels, so that the fuel cladding temperature does not exceed 1,200 degrees C (2,200 degrees F), and to permit plant shutdown during a variety of design basis loss-of-coolant accidents. This report presents the results of a study on aging performed for high pressure injection systems of boiling water reactor plants in the United States. The purpose of the study was to identify and evaluate the effects of aging and the effectiveness of testing and maintenance in detecting and mitigating aging degradation. Guidelines from the United States Nuclear Regulatory Commission's Nuclear Plant Aging Research Program were used in performing the aging study. Review and analysis of the failures reported in databases such as Nuclear Power Experience, Licensee Event Reports, and the Nuclear Plant Reliability Data System, along with plant-specific maintenance records databases, are included in this report to provide the information required to identify aging stressors, failure modes, and failure causes. Several probabilistic risk assessments were reviewed to identify risk-significant components in high pressure injection systems. Testing, maintenance, specific safety issues, and codes and standards are also discussed

  15. Optimal design of a novel oil-water separator for raw oil produced from ASP flooding

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Lu-hong; Zhang, Dan [School of Chemical Engineering and Technology of Tianjin University, Tianjin, 300072 (China); Xiao, Hong; Zhang, Hai-tao; Xu, Li-juan [School of Chemical Engineering and Technology of Tianjin University, Tianjin, 300072 (China); National Engineering Research Center for Distillation Technology, Tianjin, 300072 (China)

    2007-11-15

    Oil recovery can be greatly enhanced with the ASP (Alkali/Surfactant/Polymer) flooding technology by increasing sweeping efficiency and displacing efficiency. But the emulsification of the residual chemical in the recovered oil from ASP flooding makes it very difficult to separate water from oil. To make the oil-water separation of ASP products more efficient to meet the discharge standards, some improvements need to be made on regular oil-water separators. Based on the physical properties of ASP products in Daqing Oilfield, novel packing and newly designed Crude oil-water separator are studied in this paper. Orthogonal test is used to optimize the design of the novel separator, including the structure and material of coalescent packing, as well as the operating conditions. Experiment results suggest that the separation efficiency of the new type separator is higher than 98%. Both the outlet oil phase and the water phase have met the corresponding standards. Oil concentration in the discharge water is reduced to 600 mg L{sup -} {sup 1} and average drop size is about 6 {mu}m. It can be easily concluded that the new type separator has a better performance on the oil-water separation of ASP products. At the end of this paper, the drop size distribution (DSD) in the outlet water is analyzed to provide data for the wastewater treatment process following the crude oil-water separation. (author)

  16. Simultaneous injection of polymer and surfactant for improving oil recovery; Injecao simultanea de polimero e surfactante para aumento da recuperacao de petroleo

    Energy Technology Data Exchange (ETDEWEB)

    Medeiros, Ana C.R.; Valentim, Adriano C.M.; Marcelino, Cleuton P.; Fagundes, Fabio P.; Girao, Joaquim H.S.; Garcia, Rosangela B. [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil). Lab. de Pesquisa em Petroleo (LAPET)

    2004-07-01

    The injection of polymeric solutions in petroleum reservoirs is a supplemental method of petroleum recovery, that seeks to increase the volumetric efficiency of swept of the oil with the decrease of the mobility of the injection water. In the contact between two non miscible fluids, superficial tensions are established, that can influence the relations between the rock and the fluids, depending on the nature of both. Therefore, the combined injection of a surfactant and a polymer can promote improvements in the injectivity and in the global recovery efficiency. In this work it was used samples of commercial polyacrylamide, which were characterized through hydrolysis degree, molecular weight and rheological behavior. From these results it was chosen one sample to be used associated to a polymeric surfactant. Through a core flood system, the following tests were done: injection of polymer solution; injection of surfactant solution followed by polymer solution and injection of surfactant / polymer mixture. The results showed that the injection of surfactant / polymer mixture promoted a significant increase in the residual resistance factor, in relation to the other situations. (author)

  17. Spontaneous Formation of Water Droplets at Oil-Solid Interfaces

    OpenAIRE

    Yang, Zhongqiang; Abbott, Nicholas L.

    2010-01-01

    We report observations of spontaneous formation of micrometer-sized water droplets within micrometer-thick films of a range of different oils (isotropic and nematic 4-cyano-4’-pentylbiphenyl (5CB), and silicone, olive and corn oil) that are supported on glass substrates treated with octadecyltrichlorosilane (OTS) and immersed under water. Confocal imaging was used to determine that the water droplets nucleate and grow at the interface between the oils and OTS-treated glass with a contact angl...

  18. Crack Extension in Hydraulic Fracturing of Shale Cores Using Viscous Oil, Water, and Liquid Carbon Dioxide

    Science.gov (United States)

    Bennour, Ziad; Ishida, Tsuyoshi; Nagaya, Yuya; Chen, Youqing; Nara, Yoshitaka; Chen, Qu; Sekine, Kotaro; Nagano, Yu

    2015-07-01

    We performed hydraulic fracturing experiments on cylindrical cores of anisotropic shale obtained by drilling normal to the sedimentary plane. Experiments were conducted under ambient condition and uniaxial stresses, using three types of fracturing fluid: viscous oil, water, and liquid carbon dioxide (L-CO2). In the experiments using water and oil, cracks extended along the loading direction normal to the sedimentary plane under the uniaxial loading and extended along the sedimentary plane without loading. These results suggest that the direction of crack extension is strongly affected by in situ stress conditions. Fluorescent microscopy revealed that hydraulic fracturing with viscous oil produced linear cracks with few branches, whereas that with water produced cracks with many branches inclining from the loading axis. Statistical analysis of P wave polarity of acoustic emission waveforms showed that viscous oil tended to induce Mode I fracture, whereas both water and L-CO2 tended to induce Mode II fracture. Crack extension upon injection of L-CO2 was independent of loading condition unlike extension for the other two fluids. This result seemed attributable to the low viscosity of L-CO2 and was consistent with previous observations for granite specimens that low-viscosity fluids like CO2 tend to induce widely extending cracks with many branches, with Mode II fractures being dominant. These features are more advantageous for shale gas production than those induced by injection of conventional slick water.

  19. Multisyringe flow injection spectrophotometric determination of uranium in water samples

    International Nuclear Information System (INIS)

    A multisyringe flow injection analysis method for the determination of uranium in water samples was developed. The methodology was based on the complexation reaction of uranium with arsenazo (III) at pH 2.0. Uranium concentrations were spectrophotometrically detected at 649 nm using a light emitting diode. Under the optimized conditions, a linear dynamic range from 0.1 to 4.0 ?g mL-1, a 3? detection limit of 0.04 ?g mL-1, and a 10? quantification limit of 0.10 ?g mL-1 were obtained. The reproducibility (%) at 0.5, 2.5, and 4.0 ?g mL-1 was 2.5, 0.9, and 0.6%, respectively (n = 10). The interference effect of some ions was tested. The proposed method was successfully applied to the determination of uranium in water samples. (author)

  20. Alternating Injection of Steam and CO2 For Thermal Recovery of Heavy Oil

    OpenAIRE

    Lawal, Kazeem Akintayo

    2011-01-01

    A combination of rising oil demand and declining supply from the conventional sources is drawing global attention to the vast heavy-oil resources. These are commonly developed with steam-based processes which, in most cases, burn fossil fuel to generate the required steam. However, tightening constraints on fuel, water, and the environment are some of the factors currently fuelling the interests in enhancements to the traditional steaming operations. To mitigate some of the ste...

  1. Methodology for surge pressure evaluation in a water injection system

    Energy Technology Data Exchange (ETDEWEB)

    Meliande, Patricia; Nascimento, Elson A. [Universidade Federal Fluminense (UFF), Niteroi, RJ (Brazil). Dept. de Engenharia Civil; Mascarenhas, Flavio C.B. [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Lab. de Hidraulica Computacional; Dandoulakis, Joao P. [SHELL of Brazil, Rio de Janeiro, RJ (Brazil)

    2009-07-01

    Predicting transient effects, known as surge pressures, is of high importance for offshore industry. It involves detailed computer modeling that attempts to simulate the complex interaction between flow line and fluid in order to ensure efficient system integrity. Platform process operators normally raise concerns whether the water injection system is adequately designed or not to be protected against possible surge pressures during sudden valve closure. This report aims to evaluate the surge pressures in Bijupira and Salema water injection systems due to valve closure, through a computer model simulation. Comparisons among the results from empirical formulations are discussed and supplementary analysis for Salema system were performed in order to define the maximum volumetric flow rate for which the design pressure was able to withstand. Maximum surge pressure values of 287.76 bar and 318.58 bar, obtained in Salema and Bijupira respectively, using empirical formulations have surpassed the operating pressure design, while the computer model results have pointed the greatest surge pressure value of 282 bar in Salema system. (author)

  2. EMISSION ANALYSIS OF DI-DIESEL ENGINE AT DIFFERENT INJECTION PRESSURES USING JATROPHA AND RUBBER SEED OIL BLENDED WITH DIESEL

    Directory of Open Access Journals (Sweden)

    S. Mahalingam

    2014-04-01

    Full Text Available Biodiesel as a renewable fuel has been considered as the best alternate for diesel fuel now a days.This fossil fuel can be used in diesel engine with or without any modi?cation.The injection pressure and injection timing are the major influencing parameters forthe performance and emission of diesel engine.In thispresentstudy,the emission analysis of vegetable oil, Jatropha oil and rubber seed oil crushed from the seed, esterified and blended with pure diesel fuel. A single cylinder constant speed direct injection (DI diesel engine has been used to analyze the emission characteristics of biodiesel.The diesel engine for various fuel injection pressures (210,220 and 240 bar at no load to full load wasinvestigated. The injection pressure was changed in the engine head by adjusting the fuel injector spring tension. The two proportions of biodiesel were used in diesel engine such as 20% of biodiesel (Jatropha oil and Rubber seed oil with 80% of pure diesel fuel named as B20 and 40% of biodiesel with 60% of pure diesel fuel named as B40.From the test result,the nitric oxide (NOx was analyzed for different injection pressures. In emission characteristicsanalysis, it was found that the increase in injector opening pressure increases the NOxemission. The injection pressure of 240 bar and B20 proportion gives better emission reduction compared to other blended fuels.

  3. Integrated oil sands tailings pond water treatment

    Energy Technology Data Exchange (ETDEWEB)

    Guo, Z. [Saskatchewan Research Council, Saskatoon, SK (Canada)

    2010-07-01

    This PowerPoint presentation discussed research currently being conducted to treat oil sands tailings pond water (TPW). The treatment of TPW is challenged by the high level of naphthenic acids (NAs), the slow settling rate of fine particulate materials, and the complex chemistry of the water. The treatment process consisted of bioflocculation, sludge blanket assisted clarification, ozonation, and oil sands coke assisted hybrid biodegradation. The aggregation and adsorption process bound small particles and cells together while also ensuring the passive uptake of pollutants using microbial masses. The mixed liquor then passed through a sludge blanket to ensure enhanced particle capture. An ozonation process was used to increase the biodegradability of the TPW as well as to increase the biodegradability of the residual NAs after ozonation. The process used a hybrid bioreactor that consisted of both suspended and fixed microbial communities. The coke served as a biofilm carrier for the waste. Further studies are being conducted to investigate the efficiency and capability of the process. tabs., figs.

  4. The water footprint of olives and olive oil in Spain

    OpenAIRE

    Salmoral Portillo, Gloria; Aldaya, Maite M.; Chico Zamanillo, Daniel; Garrido Colmenero, Alberto; Llamas Madurga, Manuel Ramón

    2011-01-01

    This paper evaluates the water footprint of Spanish olives and olive oil over the period 1997-2008. In particular, it analyses the three colour components of the water footprint: green (rainwater stored in the soil), blue (surface and groundwater) and grey (freshwater required to assimilate load of pollutants). Apparent water productivity and virtual water embedded in olive oil exports have also been studied. Results show more than 99.5% of the water footprint of one liter of bottled olive oi...

  5. Dynamic graphene filters for selective gas-water-oil separation

    Science.gov (United States)

    Bong, Jihye; Lim, Taekyung; Seo, Keumyoung; Kwon, Cho-Ah; Park, Ju Hyun; Kwak, Sang Kyu; Ju, Sanghyun

    2015-09-01

    Selective filtration of gas, water, and liquid or gaseous oil is essential to prevent possible environmental pollution and machine/facility malfunction in oil-based industries. Novel materials and structures able to selectively and efficiently filter liquid and vapor in various types of solutions are therefore in continuous demand. Here, we investigate selective gas-water-oil filtration using three-dimensional graphene structures. The proposed approach is based on the adjustable wettability of three-dimensional graphene foams. Three such structures are developed in this study; the first allows gas, oil, and water to pass, the second blocks water only, and the third is exclusively permeable to gas. In addition, the ability of three-dimensional graphene structures with a self-assembled monolayer to selectively filter oil is demonstrated. This methodology has numerous potential practical applications as gas, water, and/or oil filtration is an essential component of many industries.

  6. Dynamic graphene filters for selective gas-water-oil separation

    Science.gov (United States)

    Bong, Jihye; Lim, Taekyung; Seo, Keumyoung; Kwon, Cho-Ah; Park, Ju Hyun; Kwak, Sang Kyu; Ju, Sanghyun

    2015-01-01

    Selective filtration of gas, water, and liquid or gaseous oil is essential to prevent possible environmental pollution and machine/facility malfunction in oil-based industries. Novel materials and structures able to selectively and efficiently filter liquid and vapor in various types of solutions are therefore in continuous demand. Here, we investigate selective gas-water-oil filtration using three-dimensional graphene structures. The proposed approach is based on the adjustable wettability of three-dimensional graphene foams. Three such structures are developed in this study; the first allows gas, oil, and water to pass, the second blocks water only, and the third is exclusively permeable to gas. In addition, the ability of three-dimensional graphene structures with a self-assembled monolayer to selectively filter oil is demonstrated. This methodology has numerous potential practical applications as gas, water, and/or oil filtration is an essential component of many industries. PMID:26394930

  7. The density behaviour of heavy oils in water

    International Nuclear Information System (INIS)

    The recent concern regarding the difficulty of cleaning up Low API gravity oils (LAPIO) spilled in water was discussed. Sinking and overwashing are 2 phenomena related to the behaviour of these heavy oils in water. Sinking refers to the complete submergence of the oil to the bottom of a waterbody, while over-washing refers to the overflowing of a layer of water over dense oil at sea when the oil is still close to the surface. The latter is important because even a micron-layer of water could render the oil undetectable, particularly at acute viewing angles, such as from a ship. This paper reviewed the properties of heavy oil, the prediction of density changes and the sinking/over-washing of heavy oil. In particular, it discussed a spill which occurred in August 2005 when 11 tank cars from train derailment spilled 800,000 litres of Bunker fuel mixed with high PAH-containing pole-treating oil into Lake Wabamun, Alberta. The behaviour of the oil included submergence, neutral buoyancy, resurfacing and formation of several types of aggregates of oil. This study summarized the behaviours and processes that transformed the particles of oil into small tar balls, larger logs, sheets, and large lumps into a slick. Sediment uptake or loss was found to be the major process that caused the changes in density. The behaviour of the oils was compared with respect to density and uptake of various types of sediment. The paper also reviewed the literature on dense oil behaviour. Weathering experiments performed on dense oils to determine if extensive weathering could render oils heavier than water showed that rarely is weathering the only factor in the bulk sinking of oil. Once an oil is submerged, little weathering occurs, either by dissolution or volatilization. The uptake of particulate matter is the most important process in increasing density. This study reviewed over-washing experiments to develop a mathematical solution of the conditions required for oil to be covered by a layer of water. The study showed by over-washed oils generally have a density of 0.99 to 1.02 g/ml. The mechanisms for oil submergence in water include evaporation, temperature change, uptake of solid matter, photooxidation and extreme weathering. 23 refs., 2 tabs., 13 figs

  8. Hot solvent injection for heavy oil-bitumen recovery : an experimental investigation

    Energy Technology Data Exchange (ETDEWEB)

    Pathak, V.; Babadagli, T. [Alberta Univ., Edmonton, AB (Canada); Edmunds, N.R. [Laricina Energy Ltd., Calgary, AB (Canada)

    2010-07-01

    Steam injection and generation costs can have a significant influence on the overall economics of thermal heavy oil and bitumen recovery processes. The economic feasibility of miscible recovery methods is based on the use of effective solvent retrieval procedures. This study investigated the performance of solvents at higher temperatures. Glass bead packs and Berea sandstone cores were used to represent different types of pore structures in a series of laboratory experiments. The samples were saturated with heavy oil and exposed to paraffinic solvent vapors at temperatures above boiling point at a pressure of 1500 kPa. The solvents were then collected from each sample and analyzed in order to determine composition, viscosity, and asphaltene content. The amounts of oil recovered were also analyzed and the quantity of the asphaltene precipitated with each of the tested solvents was determined. Results of the study were then used to determine optimal conditions for each solvent type and to assess which solvents had the highest recovery rates. Butane diluted the oil more than propane, which resulted in a lower asphaltene content and decreased viscosity in the oil samples. 18 refs., 4 tabs., 11 figs.

  9. A fast alternative to core plug tests for optimising injection water salinity for EOR

    DEFF Research Database (Denmark)

    Hassenkam, Tue; Andersson, Martin Peter

    2014-01-01

    Core tests have demonstrated that decreasing the salinity of injection water can increase oil recovery. Although recovery is enhanced by simply decreasing salt content, optimising injection water salinty would offer a clear economic advantage for several reasons. Too low salinity risks swelling of the clays which would lead to permanent reservoir damage but evidence of effectiveness at moderate salinity would offer the opportunity to dispose of produced water. The goal is to define boundary conditions so injection water salinity is high enough to prevent reservoir damage and low enough to induce the low salinity effect while keeping costs and operational requirements at a minimum. Traditional core plug testing for optimising conditions has some limitations. Each test requires a fresh sample, core testing requires sophisticated and expensive equipment, and reliable core test data requires several months because cores must be cleaned, restored and aged before the tests can begin. It is also difficult to compare data from one core with results from another because no two cores are identical, making it difficult to distinguish between effects resulting from different conditions and effects resulting from different cores. Gathering statistics is limited by the time required for each test and the fact that core material is in short supply. Thus, our aim was to explore the possibility of a cheaper, faster alternative. We developed a method that uses atomic force microscopy (AFM) to investigate the relationship between the wettability of pore surfaces and water salinity. We functionalise AFM tips with organic molecules and use them to represent tiny oil droplets of nonpolar or polar molecules and we use sand grains removed from core plugs to represent the pore walls in sandstone. We bring our "oil" close to the sand grain surface and measure the work of adhesion between the tip and the surface. Repeated "feeling" the surface with the tip produces data that can be converted to maps of adhesion and contact angle. Adhesion work is proportional to wettability and is directly correlated with the salinity of the fluid in contact with the tip and the particle surface. From our measurements, the threshold values for the onset of the low salinity response is 5,000 to 8,000 ppm, which benchmarks remarkably well with observations from core plug tests. Changing either the type of "oil" on our probe or the character of the grain surface both affect the adhesion response. From a mechanistic perspective, the correlation between salinity and adhesion provides evidence for the role of electrical double layer expansion in the low salinity response; expansion of the double layer decreases oil wettability. Because AFM experiments can be done relatively quickly on very little material, it gives the possibility of testing salinity response on samples from throughout a reservoir and for gathering statistics. Our approach provides a range of data that can be used to screen core plug testing conditions and to provide extra data that would be too time consuming or too expensive using traditional methods alone. © 2014, Society of Petroleum Engineers.

  10. Influence of pumpkin seed oil in continuous phase on droplet size and stability of water-in-oil emulsions

    OpenAIRE

    Nikolovski Branislava G.; Ili? Jelena D.; Sovilj Milan N.; Nikoli? Milan P.; Milanovi? Jadranka L.

    2011-01-01

    The aim of this work was to contribute to the optimized production of water-in-oil emulsions with pumpkin seed oil in the oil phase using a high-speed homogenizer. Pumpkin seed oil is a valuable natural source of essential fatty acids and biologically active micronutrients that contribute to its nutritive value and medical uses, and reduce interfacial tension between water and the oil phases. Therefore, pumpkin seed oil can be considered as a prosperous oil phase whose use can possibly ...

  11. Panorama 2011: Water in fuel production Oil production and refining

    International Nuclear Information System (INIS)

    Water plays a vital role in the production of fuels. Against a background of extremely high pressure to do with the need to protect the environment, better manage energy use and operate in a socially responsible manner - as well as the need to protect water as a resource and reduce greenhouse gas emissions, water management has become a major issue for the oil industry. These issues have all more or less been factored into the integrated water management programmes which have been introduced both in oil production and oil refining. These programmes have been designed to keep waste and emissions to a minimum, and to reduce the quantities of water required. (author)

  12. Oxidative Stability and Rheological Properties of Oil-In-Water Emulsions with Walnut Oil

    OpenAIRE

    Kremena Nikovska

    2010-01-01

    The oxidative stability of walnut oil and oil-in-water (O/W) emulsions with walnut oil stabilized bysoy protein isolate (SI) and Whey Protein Isolate (W PI) was evaluated. The food emulsions w ere more stablethan walnut oil, as indicated by measuring the formation of primary and secondary oxidation products. It wasshown that the emulsions with WPI had a better oxidative stability than the emulsions with SI, probably dueto the ability of whey proteins to inactivate peroxil radicals. In additio...

  13. Poroelastic modeling to assess the effect of water injection for land subsidence mitigation

    Science.gov (United States)

    Aichi, M.; Tokunaga, T.

    2015-11-01

    The possible effect of water injection to mitigate land subsidence was studied through numerical simulations based on the theory of poroelasticity. The Kujukuri Plain, Japan, was chosen as a study area. The effect of past injection was evaluated by comparing a model with injection and the one without injection. The calculated results suggested that the past injection played a significant role to reduce land subsidence. For achieving more effective mitigation practices in the future, we proposed to install injection wells in shallower formations. The effect of proposed injection method to mitigate land subsidence from 2014 to 2030 was also investigated. The calculated results show that the proposed method can work similarly by lesser water injection than the past method. The results also indicate that the upper limit of injection rate should be carefully determined to control the pore pressure build-up in the formation to be small enough to avoid formation failure.

  14. Operation Clean Feather: Reducing oil pollution in Newfoundland waters

    International Nuclear Information System (INIS)

    Oil pollution of marine waters around Newfoundland, and particularly in the vicinity of Placentia Bay, is a frequent occurrence. Many oiled seabirds are found on beaches in the bay, particularly in winter. The most likely pollution sources are ship operators who dump waste oils from bilges and slop tanks. In an effort to reduce the chronic discharge of waste oil into Placentia Bay, and thus the incidence of bird oiling, Operation Clean Feather was launched in 1991-92 and consisted of weekly surveys of Placentia Bay beaches, sampling of oil from vessels using the bay and from oiled birds and beaches, and experimentation to determine possible recovery rates of birds oiled at sea. The operation was considered a success at a number of levels. Significant reductions in numbers of oiled birds were noted in both 1991 and 1992 compared to 1989 or 1990. Estimated oil-related mortality was reduced to ca 25% of levels seen in the two years prior to the operation. The operation also provided the opportunity to test and refine an organizational framework designed to deal with the problem of chronic oil pollution reports. Communication efforts heightened the awareness of the oil pollution problem in Newfoundland waters. These efforts included distribution of pamphlets in various languages to ship operators, describing the seriousness of oil-related marine bird mortality and warning of the substantial fines that can be imposed under the Canada Shipping Act. 6 refs., 3 figs., 1 tab

  15. Absorption of water and lubricating oils into porous nylon

    Science.gov (United States)

    Bertrand, P. A.

    1995-01-01

    Oil and water absorption from air into sintered porous nylon can be described by infiltration into the pores of the material. This process can be modeled by a diffusion-like mechanism. For water absorption, we find a formal diffusion coefficient of 1.5 x 10(exp -4)sq cm/min when the nylon is initially dry. The diffusion coefficient is 4 x 10(exp -6)sq cm/min when the nylon is oil-impregnated prior to air exposure. In a 52% RH atmosphere, dry nylon absorbs 3% w/w water, and oil-impregnated nylon absorbs 0.6% w/w water. For oil absorption there are three steps: (1) surface absorption and infiltration into (2) larger and (3) smaller pores. Surface absorption is too fast to be measured in these experiments. The diffusion coefficient for the second step is 6 x 10(exp -4)sq cm/min for SRG-60 oil into dry nylon and 4 x 10(exp -4)sq cm/min for air-equilibrated nylon. The diffusion coefficient for the third step is about 1 x 10(exp -6)sq cm/min for both cases. The total amount of oil absorbed is 31% w/w. The interaction between water and nylon is not as strong as that between water and cotton-phenolic: oil can replace water, and only a small amount of water can enter previously oil-impregnated nylon.

  16. Experimental Studies on Performance and Emission Characteristics of Fish Oil Methyl Ester and its blends at different injection opening pressures in a direct injection CI engine

    Directory of Open Access Journals (Sweden)

    Chandrashekar A.M

    2015-04-01

    Full Text Available Biodiesel is one of the most versatile alternative fuel options for direct injection CI engine applications. In the recent research of biodiesel in India receives its attention towards fish oil based biodiesel. The present work aimed at production of biodiesel from the fish oil extracted from marine fish species by transesterification process which is used as fuel in direct injection CI engine to evaluate its performance, and emission characteristics at different injection opening pressures of 190bar, 200bar, 210bar. The different blends of fish oil biodiesel with diesel, B10, B20, B30, B40, B50 and B100 were used in the experiments and the results indicate that brake thermal efficiency were higher with B30 blend fuel than that of diesel at 210bar as compared at 190bar and 200bar. The brake specific energy consumption for B30 blend at 210bar shows better results than that of diesel. By considering these two performance parameters B30 blend at 210 bar injection opening pressure is taken as optimum. At full load for B30 fuel at 210bar injection opening pressure the emission results shows that there is increase in NOx and CO2 emission but reduction in CO and HC emissions by 20% and 15.55% respectively with reference to diesel fuel.

  17. Advanced Membrane Filtration Technology for Cost Effective Recovery of Fresh Water from Oil & Gas Produced Brine

    Energy Technology Data Exchange (ETDEWEB)

    David B. Burnett

    2005-09-29

    This study is developing a comprehensive study of what is involved in the desalination of oil field produced brine and the technical developments and regulatory changes needed to make the concept a commercial reality. It was originally based on ''conventional'' produced water treatment and reviewed (1) the basics of produced water management, (2) the potential for desalination of produced brine in order to make the resource more useful and available in areas of limited fresh water availability, and (3) the potential beneficial uses of produced water for other than oil production operations. Since we have begun however, a new area of interest has appeared that of brine water treatment at the well site. Details are discussed in this technical progress report. One way to reduce the impact of O&G operations is to treat produced brine by desalination. The main body of the report contains information showing where oil field brine is produced, its composition, and the volume available for treatment and desalination. This collection of information all relates to what the oil and gas industry refers to as ''produced water management''. It is a critical issue for the industry as produced water accounts for more than 80% of all the byproducts produced in oil and gas exploration and production. The expense of handling unwanted waste fluids draws scarce capital away for the development of new petroleum resources, decreases the economic lifetimes of existing oil and gas reservoirs, and makes environmental compliance more expensive to achieve. More than 200 million barrels of produced water are generated worldwide each day; this adds up to more than 75 billion barrels per year. For the United States, the American Petroleum Institute estimated about 18 billion barrels per year were generated from onshore wells in 1995, and similar volumes are generated today. Offshore wells in the United States generate several hundred million barrels of produced water per year. Internationally, three barrels of water are produced for each barrel of oil. Production in the United States is more mature; the US average is about 7 barrels of water per barrel of oil. Closer to home, in Texas the Permian Basin produces more than 9 barrels of water per barrel of oil and represents more than 400 million gallons of water per day processed and re-injected.

  18. Application of tritiated water as a tracer for quantitative determination of water flow distribution in an oil-field

    International Nuclear Information System (INIS)

    In order to study the flow of water in an underground oil reservoir, tritiated water was injected in a well and, subsequently, tritium was determined in the water produced by the surrounding wells. Since the specific radioactivity of the water produced by the more remote wells appeared to be rather low, partly owing to dilution of the tritium water by the water present in the formation, enrichment methods were used, in order to increase counting sensitivity. Three methods of enrichment were examined: exchange with ethanol, conversion to toluene, and electrolysis. The latter method proved to be the most useful. The tritium was determined with a liquid scintillation counter; the scintillator consisted of a toluene-ethanol (2:1) mixture with DPO and POPOP, the water sample being dissolved in this liquid. Some statistical problems in connexion with the minimum detectable specific activity and the reduction of background are discussed briefly. (author)

  19. Injector-internal thermal desorption from edible oils performed by programmed temperature vaporizing (PTV) injection.

    Science.gov (United States)

    Fankhauser-Noti, Anja; Grob, Koni

    2006-10-01

    Injector-internal thermal desorption is a promising technique for the analysis of a wide range of food components (e.g., flavors) or food contaminants (e.g., solvent residues, pesticides, or migrants from packaging materials) in edible oils and fats or fatty food extracts. Separation from the fatty matrix occurs during injection. Using programmed temperature vaporizing (PTV) injection, the oily sample or sample extract was deposited on a small pack of glass wool from which the components of interest were evaporated and transferred into the column in splitless mode, leaving behind the bulk of the matrix. Towards the end of the analysis, the oil was removed by heating out the injector and backflushing the precolumn. The optimization dealt with the gas supply configuration enabling backflush, the injector temperature program (sample deposition, desorption, and heating out), separation of the sample liquid from the syringe needle and positioning it on a support, deactivation of the support surface, holding the plug of fused silica wool by a steel wire, and the analytical sequence maintaining adsorptivity at the desorption site low. It was performed for a mixture of poly(vinyl chloride) (PVC) plasticizers in oil or fatty food. Using MS in SIM, the detection limit was below 0.1 mg/kg for plasticizers forming single peaks and 1 mg/kg for mixtures like diisodecyl phthalate. For plasticizers, RSDs of the concentrations were below 10%; for the slip agents, oleamide and erucamide, it was 12%. The method of incorporating PTV injection was used for about one year for determining the migration from the gaskets of lids for glass jars into oily foods. PMID:17120821

  20. Technique for locating injected gas in oil bearing formations behind casing

    International Nuclear Information System (INIS)

    A method is described for determining the location of injected gas in an oil well comprising the steps of: obtaining data representing a near count rate from a compensated neutron logging tool; obtaining data representing a far count rate from a compensated neutron logging tool; scaling the near count rate and the far count rate; plotting the scaled near count rate and the scaled far rate; comparing the scaled near count rate plot and the scaled far count rate plot and; determining the location of injected gas whenever the plot of the scaled near count rate and the plot of the scaled far count rate differ by a predetermined factor; obtaining data representing a second near count rate for a compensated neutron logging tool at a second time; obtaining data representing a second far count rate from a compensated neutron logging tool at the second time; scaling the second near count rate and the second far count rate; plotting the scaled second near count rate and the scaled second far count rate; comparing the scaled second near count rate plot and the scaled second far count rate plot; determining a second location of injected gas whenever the plot of the scaled second near count rate and the plot of the scaled second far count rate differ by a predetermined factor; and determining the migration of the injected gas by comparing the location with the second location

  1. Numerical modeling of oil spills in continental and estuarine waters

    International Nuclear Information System (INIS)

    The application of the European Water Framework Directive on water quality for human consumption and industrial activities creates a need for water quality assessment and monitoring systems. The MIGR'HYCAR research project (http://www.migrhycar.com) was initiated to provide decisional tools for risks connected to oil spills in continental waters (rivers, lakes and estuaries), which represent more than 50% of accidental spills in France. Within the framework of this project, a new numerical oil spill model has been developed, as part of the TELEMAC hydro-informatics system (http://www.opentelemac.org), by combining Lagrangian and Eulerian methods. The Lagrangian model describes the transport of an oil spill near the free surface. The oil spill model enables to simulate the main processes driving oil plumes: advection, diffusion, oil beaching, oil re-floating, evaporation, dissolution, spreading and volatilization. Though generally considered as a minor process, dissolution is important from the point of view of toxicity. To model dissolved oil in water, an Eulerian advection-diffusion model is used. The fraction of dissolved oil is represented by a passive tracer. This approach is able to follow dissolved hydrocarbons in the water column. Laboratory experiments were conducted to characterise the numerous kinetics of the processes listed above. In addition, meso-scale dynamic experiments in artificial channels and test cases derived from the literature are used to validate the numerical model. (author)

  2. BP philosophy to PWRI and field experiences. Benefits and risks of produced water re-injection[Produced water re-injection (PWRI)

    Energy Technology Data Exchange (ETDEWEB)

    Sweeney, Frank

    2005-07-01

    The presentation discusses that water injection performance can be successfully modeled with a high degree of confidence. This applies to PW as well as SW and there is needs to understand the parameters that impact injection performance, how changing fluid type influences this. The key factors which influence PWRI are injection pressure, temperature and water quality (in particular solids). Furthermore the PWRI should be considered as part of an overall water management strategy, rather than as a retrofit option and as such there are needs to design surface facilities for PWRI operation (s and management) (tk)

  3. An oil removal system for an oil-injected screw compressor on helium

    International Nuclear Information System (INIS)

    The recent emergence of small capacity closed cycle helium refrigeration used in conjunction with industrial superconducting devices has placed great emphasis on the long term reliability of the refrigerator. Formerly the limitations of the refrigeration plant were in the reciprocating expansion machines. With the advent of the gas-lubricated expansion turbine, which, when operated with a reasonably clean gas supply, has a virtually infinite life, the limitations of the compressor have become dominant. Developments are discussed in the improvement of oil removal equipment used in conjunction with a rotary screw compressor having an overall potential reliability of that presently being achieved by the refrigerator turboexpanders. (author)

  4. Test of an improved oil injected helium screw compressor at Fermilab

    International Nuclear Information System (INIS)

    Fermilab has tested a modified helium oil injected two-stage Mycom screwcompressor for possible use in the Tevatron. The tests are part of a joint venture with Mycom. Modifications to the compressor include a new modified rotor profile and new generation lubricant which resulted in increased performance and efficiency. The effects of the modifications on shaft-power and isothermal efficiency are included. The results of these tests will determine the practicality of incorporating these modifications to the thirty-four existing screw compressors of the Tevatron

  5. Influence of fuel additives on performance of direct-injection Diesel engine and exhaust emissions when operating on shale oil

    International Nuclear Information System (INIS)

    The article presents the comparative bench testing results of a naturally aspirated four stroke, four cylinder, water cooled, direct injection Diesel engine when running on shale oil that has been treated with multi-functional fuel additives. The purpose of the research is to evaluate the effectiveness of the fuel additives Marisol FT (Sweden) and SO-2E (Estonia) as well as to verify their ability to increase energy conversion and reduce brake specific fuel consumption, contamination and smoke opacity of the exhausts when fuelling the Diesel engine with shale oil. Test results show that application of these additives could be a very efficient means to improve Diesel engine performance on shale oil, especially when operating at the light load range. The brake specific fuel consumption at light loads and speeds of 1400-2000 min-1 reduces by 18.3-11.0% due to the application of the Marisol FT. The additive SO-2E proves to produce nearly the same effect. The total NO x emission from the fully loaded Diesel engine fuelled with the treated shale oil reduces by 29.1% (SO-2E) and 23.0% (Marisol FT). It is important that the lower NO x is obtained due to reducing both harmful pollutants, NO and NO2. The CO emission at rated power increases by 16.3% (SO-2E) and 48.0% (Marisol FT), whereas the smoke opacity of the exhausts increases by 35% and over 2 times, respectively. The effect of the fuel additives on the HC emission seems to be complicated and ambiguous

  6. Combustion of waste oils simulating their injection in blast furnace tuyeres

    Directory of Open Access Journals (Sweden)

    Cores, A.

    2009-04-01

    Full Text Available A study has been made of the combustion of different waste oils produced in an iron and steel works. Combustion is achieved by injecting the waste oil at flows of 10-20 kg/h in a combustion chamber that simulates the conditions of the blast furnace tuyere zone. The waste oil is preheated to 65-90 °C in order to achieve conditions of fluidity and is injected by spraying into the combustion chamber. During combustion the temperatures and the CO2, O2, CO N2 and H2 contents of the gases in the combustion chamber are constantly recorded. The efficiency of the combustion of each waste oil is determined.

    Se realiza un estudio de la combustión de diferentes aceites residuales que se producen en las plantas siderúrgicas. La combustión se consigue al inyectar el aceite residual, con caudales de 10-20 kg/h, en una cámara de combustión que simula las condiciones del horno alto en la zona de toberas. El aceite residual se precalienta a 65-90 °C para conseguir las condiciones de fluidez y se inyecta en la cámara de combustión. Durante la combustión, se registran de modo continuo las temperaturas y los contenidos de CO2, O2, CO, N2 y H2 en los gases de la cámara de combustión. Se calcula la eficiencia de la combustión de cada aceite residual.

  7. 40 CFR 61.352 - Alternative standards for oil-water separators.

    Science.gov (United States)

    2010-07-01

    ... Alternative standards for oil-water separators. 61.352 Section 61... Alternative standards for oil-water separators. (a) As an alternative to the standards for oil-water separators specified in §...

  8. 40 CFR 63.137 - Process wastewater provisions-oil-water separators.

    Science.gov (United States)

    2010-07-01

    ...false Process wastewater provisions-oil-water separators. 63.137 Section 63.137 Protection...137 Process wastewater provisions—oil-water separators. (a) For each oil-water separator that receives, manages, or...

  9. Experimental and Analytical Determination of the Motion of Hydraulically Operated Valve Stems in Oil Engine Injection Systems

    Science.gov (United States)

    Gelalles, A G; Rothrock, A M

    1930-01-01

    This research on the pressure variations in the injection system of the N.A.C.A. Spray Photography Equipment and on the effects of these variations on the motion of the timing valve stem was undertaken in connection with the study of fuel injection systems for high-speed oil engines. The methods of analysis of the pressure variations and the general equation for the motion of the spring-loaded stem for the timing valve are applicable to a spring-loaded automatic injection valve, and in general to all hydraulically operated valves. A sample calculation for a spring-loaded automatic injection valve is included.

  10. Three-phase pressure drop in heavy oil, water and gas flow in a horizontal pipe for application in heavy oil transportation

    Energy Technology Data Exchange (ETDEWEB)

    Trevisan, Francisco E.; Bannwart, Antonio Carlos [Universidade Estadual de Campinas, SP (Brazil)

    2003-07-01

    A significant extent of the Brazilian oil reserves consists of heavy oil, and its importance and economic value have been increasing in the last years. However, these oils, besides their elevated densities (API degree lower than 20), have viscosities higher than 100 mPa.s , which makes it more difficult to transport them through pipelines. A solution for this problem is the injection of water in the pipe, in such a way to reduce friction and, consequently, the energy expend for a given oil flow rate. The two-phase flow of heavy oil and water has been the object of a number of recent studies, and concepts such as the core-flow technology can be useful for heavy oil transportation. But in production operations, gas is also present, initially dissolved in the oil phase then leaving the solution to form a free gas phase if the pressure is below the bubble point pressure. Thus the study of three-phase flow of heavy oil, water and gas is in order. The present paper presents the three-phase flow pressure drop measured in a horizontal glass tube of 2.84 cm i.d. at several combinations of the individual flow rates. Initially, for the development of the experiment, two-phase flow of heavy oil-water and gas-water were studied to establish the flow rate ranges that cover the main patterns already known. The superficial velocities used varied from 0.04 to 0.5 m/s for water, 0.04 to 9.0 m/s for gas and 0.02 to 1.2 m/s for oil. For each test run, the three-phase flow pressure drop was determined with the help of absolute and differential pressure transducers. The results are shown in the form of maps in terms of superficial velocities. (author)

  11. Produced water: Market and global trends - oil production - water production - choice of technology

    International Nuclear Information System (INIS)

    The presentation discusses various aspects of the world oil production, the energy demand, the future oil supply, the oil prices and the production growth. Some problems with produced water are also discussed as well as aspects of the market for produced water technology (tk)

  12. Nano-and microstructure of air/oil/water interfaces

    International Nuclear Information System (INIS)

    Full text: We report the creation of air/oil/water interfaces with variable thickness oil films, using polyisobutylen based (PIB) surfactants co-spread with long-chain paraffinic alkanes on clean water surfaces. The resultant stable oil layers are readily measurable with simple surface techniques, exhibit physical densities the same as expected for bulk oils, and are up to - 100A thick above the water surface as determined using x-ray reflectometry. This provides a ready system for studying the competition of surfactants at the oil/water interface. Results from the competition of a non-ionic polyamide surfactant or an anionic sodium dodecyl sulfate with the PIB surfactant are reported. However, this smooth oil layer does not account for the total volume of spread oil, nor is the increase in thickness proportional to the film compression. Brewster angle microscopy (BAM) reveals surfactant and oil structures on the scale of 1 to 10?m at the interface. At low surface pressure (? mNm-1) large, -10?m inhomogeneities are observed. Beyond a phase transition observed at ? 24mNm-1 a structure with a spongy appearance and a micron-scale texture develops. These structures have implications for understanding the microstructure at the oil/water interface in emulsions.

  13. The separation of stable water-in-oil emulsions

    International Nuclear Information System (INIS)

    Stable oil-in-water emulsions are a major problem in the recovery of spilled oils. Such emulsions can contain as little as 10% oil and can have properties very different from the original oils, making their storage and disposal difficult. These problems have led to experiments testing the feasibility of a process for separating these stable emulsions into dischargeable water and reusable oil. The technique investigated involves use of a recyclable solvent to remove the oil and subsequent distillation and/or membrane treatment to recover the oil and recycle the solvent. Results of preliminary tests show that stable water-in-oil emulsions can be separated quite readily with a regenerated solvent system. The only products of these systems are oil, which can be sent to a refinery, and dischargeable water. The recycled solvent can be used many times without any significant decrease in separation efficiency. In order to enhance the throughput of the system, a solvent vapor stripping method was invented. This stripping method also improves the quality of the products and the recycled solvent. Membrane methods can be used as a post-treatment for the produced water in order to achieve more adequate compliance with discharge limits. 4 refs., 3 figs., 5 tabs

  14. A new Experimental Rig for Oil Burning on Water : Results for Crude and Pure Oils

    DEFF Research Database (Denmark)

    Brogaard, Nicholas L.; SØrensen, Martin X.

    2014-01-01

    A new experimental apparatus, the Crude Oil Flammability Apparatus (COFA), has been developed to study in-situ burning of crude and pure oils spilled on water in a controlled laboratory environment with large water-to-oil ratios. The parameters and phenomena studied for an asphaltic crude oil (Grane) and two pure oils (n-Octane and dodecane) with different initial oil layer thicknesses include burning efficiency, burning rate, regression rate, flame height and boilover. Pyrex glass cylinders (157 and 260 mm ID) placed on top of a steel foot in a water basin (1m x 1m x 0.5m) enabled free circulation of the water, which, along with the large water-to-oil ratios (up to 10,000) ensured that the oil burning barely increased the temperature of the surrounding water environment, which created more realistic offshore conditions than seen in many other laboratory studies. The burning efficiency was found to be nearly 100% for n-Octane and of dodecane, whereas the crude oil burning efficiency ranged between 35% and 65%. The main reason for this variation proved to be the onset of an extremely violent boilover, which occurs for oils with relatively high boiling temperatures when the water sub layer is superheated. When the initial crude oil layer thickness exceeded 20 mm the oil became solid and no boilover occurred. The heat-loss to the water sub-layer also had an effect on the burning efficiency and the regression rate was found to reach a constant value after increasing continuously as the oil was heated. Similar results were found regarding the flame height which reached a steady flame height. The pure fuels, n-Octane and dodecane, produced a much higher steady flame height than the crude oil, however they did not reach boilover, though dodecane showed boilover tendencies. Theoretical predictions with existing correlations and input data specific for the current oils generally compared well with the experimental data for both the time to boilover and the regression rates. As such, the COFA is envisioned to produce high-fidelity results in the future and thereby contribute to the further development of in-situ burning as an alternative response technique for oil spills on water.

  15. Resolution of oil-in-water emulsions containing uranium

    International Nuclear Information System (INIS)

    A method of resolving oil-in-water emulsions resulting from the organic solvent extraction of uranium from aqueous acidic leach liquors which comprises treating the emulsions in accordance with the following steps: (a) adding to the emulsions a water-in-oil emulsion which contains from 2 to 50% by weight of a water-soluble acrylamide copolymer which contains from 5 to 50% by weight of a lower alkyl substituted tertiary aminoethyl methacrylate and quaternary ammonium salts thereof in an amount to provide at least 20 parts per million of the acrylamide copolymer; (b) adjusting the pH of the emulsion being treated with ammonia to at least 9; (c) adding to the ammonia treated emulsion a water-soluble surfactant which is capable of inverting the water-in-oil emulsion which contains the polymer; and then (d) slowly mixing the treated oil-in-water emulsion for at least one-half hour to obtain good resolution thereof

  16. Experimental Evaluation of Water Content In Transformer Oil

    OpenAIRE

    PANKAJSHUKLA; Y.R Sood; R.K.JARIAL

    2013-01-01

    This paper presents experimental research on temperature dependency of water content in mineral transformer oils. Moisture sensor measurements (online measurement) and absolute water content determination by Karl Fisher titration method(off-line method) were performed in the laboratory to investigate solubility of different types of mineral transformer oils. Results of experiments explain that preset moisture solubility model of moisture sensor affects the accuracy of water content determinat...

  17. Optimizing Injection Molding Processing Parameters for Enhanced Mechanical Performance of Oil Palm Empty Fruit Bunch High Density Polyethylene Composites

    Directory of Open Access Journals (Sweden)

    M.S. Ramli

    2011-01-01

    Full Text Available This study reports on the influence of injection molding processing parameters on mechanical properties of oil palm Empty Fruit Bunch (EFB filled High Density Poly Ethylene (HDPE. The biocomposite pellets were first prepared using an extruder with 20 wt% EFB content before being processed in an injection-molding machine for specimen fabrication. Two processing parameters were varied systematically and independently during the composite sample fabrication. The holding pressure was increased from 60 to 90 bars while the injection temperature was varied from 150 to 210°C. The highest tensile strength of the composites was achieved at 70 bar holding pressure and 150°C injection temperature. However, the highest fracture strength was achieved at 80 bars whilst maintaining the injection temperature at 150°C. Flexural strength was shown to be unaffected by the varying pressure. The optimal processing parameters for highest mechanical performance were found to be at holding pressure of 80 bars and injection tempera

  18. Comparative toxicity test of water-accommodated fractions of oils and oil dispersants to marine organisms

    International Nuclear Information System (INIS)

    This reference method describes a simple procedure for comparing the toxicity of oil, oil dispersants, and mixtures thereof, to marine animals. It allows the toxicity of different dispersants to be rapidly compared to that of oil, or of a mixture of oil an oil dispersant. It is designed for routine monitoring and screening purposes and is not appropriate as a research method. The physical and chemical properties of oil dispersants create many difficulties in the measurements of their toxicity to marine organisms. Strictly speaking, their toxicity can only be accurately estimated using complex procedures and apparatus. (A relatively simple apparatus for preparing oil/water or oil/water/oil dispersant emulsions is described in Appendix B). Simpler methods can provide useful information, provided their limitations are clearly understood and taken into consideration in the assessment and application of their results. Some of the special considerations relating to the measurement of the toxicity of oil and oil dispersants are described in Appendix A. The Appendix also explains the rationale and limitations of the method described here. 3 refs, 4 figs, 2 tabs

  19. Chemical and ecotoxicological characterisation of oil-water systems

    International Nuclear Information System (INIS)

    An ongoing chemical and ecotoxicological study of Water Accommodated Fraction of oils is presented and the preliminary findings are discussed. The study aims at obtaining improved and realistic data on potential environmental effects of various oils released and weathered at sea. Such data will be used for improving algorithms in present fate and effect models for damage assessment studies and 'Net Environmental Benefit Analysis' of response alternatives in various spill scenarios. Preliminary results show that models used to assess effects in the water column will need to resolve the water soluble fraction of oils into more than one single bulk parameter to produce realistic estimates of effects. (Author)

  20. Chemical and ecotoxicological characterisation of oil-water systems

    Energy Technology Data Exchange (ETDEWEB)

    Hokstad, Jorunn Nerboe; Daling, Per S. [SINTEF Applied Chemistry, Environmental Engineering, Trondheim (Norway); Buffagni, Melania [Agip Lapo Environmental Labs., Milan (Italy); Johnsen, Staale [Statoil Research Centre, Trondheim (Norway)

    1999-07-01

    An ongoing chemical and ecotoxicological study of Water Accommodated Fraction of oils is presented and the preliminary findings are discussed. The study aims at obtaining improved and realistic data on potential environmental effects of various oils released and weathered at sea. Such data will be used for improving algorithms in present fate and effect models for damage assessment studies and 'Net Environmental Benefit Analysis' of response alternatives in various spill scenarios. Preliminary results show that models used to assess effects in the water column will need to resolve the water soluble fraction of oils into more than one single bulk parameter to produce realistic estimates of effects. (Author)

  1. Oil and water: a two-type internal aggregation model

    OpenAIRE

    Candellero, Elisabetta; Ganguly, Shirshendu; Hoffman, Christopher; Levine, Lionel

    2014-01-01

    We introduce a two-type internal DLA model which is an example of a non-unary abelian network. Starting with n "oil" and n "water" particles at the origin, the particles diffuse in Z according to the following rule: whenever some site x has at least 1 oil and at least 1 water particle present, it "fires" by sending 1 oil particle and 1 water particle each to an independent random neighbor x+1 or x-1. Firing continues until every site has at most one type of particles. We est...

  2. Study of enhanced oil field recovery through polymer injection in field scales; Estudo da recuperacao avancada de petroleo via injecao de polimeros em escala de campo

    Energy Technology Data Exchange (ETDEWEB)

    Manichand, Renuka N.; Garcia, Rosangela B.; Mata, Ana L.M.L.; Mata, Wilson da [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil)

    2004-07-01

    Polymer flooding as an enhanced oil recovery method consists in increasing the aqueous phase viscosity by addition of polymer, reducing in this way its mobility compared with the oleic phase, leading to an increase in reservoir's sweep efficiency. However, polymer flooding still requires more research to develop polymers that are more resistant to the injection and reservoir conditions, e.g. high temperature, high salinity, biological and mechanical degradation. Computational simulations are executed to validate the results. The objective of this paper is to study the performance of polymer flooding in enhancing the reservoir's recovery factor. Computational simulations were done for polymer flooding in filed scale using the STARS simulator (CMG). Simulations for water flooding also were done for the same reservoir. In this way, it was possible to compare, for the same reservoir, the performance of water injection and polymer flooding. The economical analysis of these recovery methods was done to evaluate their viability. (author)

  3. Breaking of Oil -Water Emulsion for the Improvement of Oil Recovery Operations in the Niger Delta Oilfields

    OpenAIRE

    C. Ijogbemeye Oseghale; Akpabio E. J; Udottong, G

    2012-01-01

    Emulsified water is generally present in crude oil as a result of mixing occurring during production operations. The formation of emulsion leads to problems in production and also transportation. Therefore the need to break oil/water emulsions system through demulsification process using chemical surfactants for improved oil recovery operations. Selected cationic surfactants were effective in separating oil-water emulsions expected during a surfactant/polymer (SP) process for improved oil rec...

  4. Successful water management for the oil sands industry

    International Nuclear Information System (INIS)

    Water is a key requirement to produce oil from thermal oil sands projects. Historically, water was considered as a renewable resource that could be used when necessary. Water use is currently examined in a wider context. Canadian Natural Resources Limited has used fresh water for thermal projects in the past, including its thermal operations at Primrose and Wolf Lake. However, technical advancements have made it possible to use recycled water. This allows companies to survive within their licenses while increasing production. Other advances include the use of brackish water, and innovations such as using depleted reservoir sections to store water to increase the use of recycled water. It was noted that brackish water resources need to be mapped and understood in greater detail. The objective is to use brackish water at a cost equal to, or less, than fresh water

  5. Oil spill dispersants. Risk assessment for Swedish waters

    Energy Technology Data Exchange (ETDEWEB)

    Lindgren, C.; Lager, H.; Fejes, J.

    2001-12-01

    IVL has compiled a list of the international usage of oil spill dispersants and presents the technical limitations with the use of such agents as well as the biological effects of these chemical products. IVL, has also conducted an analysis of the pros and cons to using dispersants against oil spills in waters and has applied this with a risk assessment of chemical methods to combat oil spills in the Kattegat and Skagerrak and the Baltic Sea.

  6. Heating of Oil Well by Hot Water Circulation

    CERN Document Server

    Jurak, M; Jurak, Mladen; Prnic, Zarko

    2005-01-01

    When highly viscous oil is produced at low temperatures, large pressure drops will significantly decrease production rate. One of possible solutions to this problem is heating of oil well by hot water recycling. We construct and analyze a mathematical model of oil-well heating composed of three linear parabolic PDE coupled with one Volterra integral equation. Further on we construct numerical method for the model and present some simulation results.

  7. Oil spill dispersants. Risk assessment for Swedish waters

    International Nuclear Information System (INIS)

    IVL has compiled a list of the international usage of oil spill dispersants and presents the technical limitations with the use of such agents as well as the biological effects of these chemical products. IVL, has also conducted an analysis of the pros and cons to using dispersants against oil spills in waters and has applied this with a risk assessment of chemical methods to combat oil spills in the Kattegat and Skagerrak and the Baltic Sea

  8. Assembly of transmembrane proteins on oil-water interfaces

    Science.gov (United States)

    Yunker, Peter; Landry, Corey; Chong, Shaorong; Weitz, David

    2015-03-01

    Transmembrane proteins are difficult to handle by aqueous solution-based biochemical and biophysical approaches, due to the hydrophobicity of transmembrane helices. Detergents can solubilize transmembrane proteins; however, surfactant coated transmembrane proteins are not always functional, and purifying detergent coated proteins in a micellar solution can be difficult. Motivated by this problem, we study the self-assembly of transmembrane proteins on oil-water interfaces. We found that the large water-oil interface of oil drops prevents nascent transmembrane proteins from forming non-functional aggregates. The oil provides a hydrophobic environment for the transmembrane helix, allowing the ectodomain to fold into its natural structure and orientation. Further, modifying the strength or valency of hydrophobic interactions between transmembrane proteins results in the self-assembly of spatially clustered, active proteins on the oil-water interface. Thus, hydrophobic interactions can facilitate, rather than inhibit, the assembly of transmembrane proteins.

  9. Effect Of Hot Water Injection On Sandstone Permeability : An Analysis Of Experimental Literature

    DEFF Research Database (Denmark)

    Rosenbrand, Esther; Fabricius, Ida Lykke

    2012-01-01

    The seasonal imbalance between supply and demand of renewable energy requires temporary storage, which can be achieved by hot water injection in warm aquifers. This requires that the permeability and porosity of the aquifer are not reduced significantly by heating. We present an overview of published results regarding the effect of temperature on sandstone permeability. These tests are performed with mineral oil, nitrogen gas, distilled water and solutions of NaCl, KCl, CaCl2 as well as brines that contain a mixture of salts. Thirteen sandstone formations, ranging from quartz arenites to formations with a significant fraction of fine particles including clay minerals are investigated. The porosities range from 0.10 to 0.30 and permeabilities span the range from 1 to 1000 md. To compare different rock types, specific surface is determined from permeability and porosity using Kozeny’s equation. Heating causes thermal expansion, which results in porosity reduction if the sandstone is confined. The maximum effect of porosity reduction as a result of thermal expansion on permeability is modelled and compared the change in specific surface that is computed from the reported data. This does not account for all the permeability reductions observed. Permeablity reduction occurs both when distilled water is the saturating fluid as well as in tests with NaCl, KCl or CaCl2 solutions, however, this is not the case in tests with mineral oil or nitrogen gas. The formation of a filter cake or influx of colloidal particles due to corrosion of the apparatus at elevated temperature causes permeability reduction in a number of investigations. Mobilisation of internal particles, particularly kaolinite particles, is considered a probable mechanism of permeability reduction for the other experiments reviewed here. The parameters that strongly affect the success of heat storage therefore include the quality of the equipment and particularly the prevention of corrosion, as well as the sandstone lithology and its interaction with the reservoir fluid.

  10. Additional Reserve Recovery Using New Polymer Treatment on High Water Oil Ratio Wells in Alameda Field, Kingman County, Kansas

    Energy Technology Data Exchange (ETDEWEB)

    James Spillane

    2005-10-01

    The Chemical Flooding process, like a polymer treatment, as a tertiary (enhanced) oil recovery process can be a very good solution based on the condition of this field and its low cost compared to the drilling of new wells. It is an improved water flooding method in which high molecular-weight (macro-size molecules) and water-soluble polymers are added to the injection water to improve the mobility ratio by enhancing the viscosity of the water and by reducing permeability in invaded zones during the process. In other words, it can improve the sweep efficiency by reducing the water mobility. This polymer treatment can be performed on the same active oil producer well rather than on an injector well in the existence of strong water drive in the formation. Some parameters must be considered before any polymer job is performed such as: formation temperature, permeability, oil gravity and viscosity, location and formation thickness of the well, amount of remaining recoverable oil, fluid levels, well productivity, water oil ratio (WOR) and existence of water drive. This improved oil recovery technique has been used widely and has significant potential to extend reservoir life by increasing the oil production and decreasing the water cut. This new technology has the greatest potential in reservoirs that are moderately heterogeneous, contain moderately viscous oils, and have adverse water-oil mobility ratios. For example, many wells in Kansas's Arbuckle formation had similar treatments and we have seen very effective results. In addition, there were previous polymer treatments conducted by Texaco in Alameda Field on a number of wells throughout the Viola-Simpson formation in the early 70's. Most of the treatments proved to be very successful.

  11. Optimizing Injection Molding Processing Parameters for Enhanced Mechanical Performance of Oil Palm Empty Fruit Bunch High Density Polyethylene Composites

    OpenAIRE

    M. S. Ramli; M.R. Abdul Latif; P.S.M. Megat-Yusoff

    2011-01-01

    This study reports on the influence of injection molding processing parameters on mechanical properties of oil palm Empty Fruit Bunch (EFB) filled High Density Poly Ethylene (HDPE). The biocomposite pellets were first prepared using an extruder with 20 wt% EFB content before being processed in an injection-molding machine for specimen fabrication. Two processing parameters were varied systematically and independently during the composite sample fabrication. The holding pressure was increased ...

  12. Effect of mixed gas solvent injection on performance of the Vapex process in an Iranian heavy oil sample

    Energy Technology Data Exchange (ETDEWEB)

    Derakhshanfar, M.; Kharrat, R.; Rostami, B. [Petroleum Univ. of Technology, Abadan (Iran, Islamic Republic of); Etminan, S.R. [Calgary Univ., AB (Canada)

    2009-07-01

    The vapor extraction (VAPEX) process involves the injection of vaporized hydrocarbon solvents into oil reservoirs in order to decrease in-situ oil viscosity. The solvents are often used with non-condensable gases in high pressure reservoirs to lower the dew point of the gas mixture and prevent condensation. This study investigated the effects of mixed gas solvent injection on the VAPEX process with an Iranian heavy oil sample. A set of experiments were conducted at low, medium, and high pressure rates on a 2-D visual model. A transparent face was used in the model in order to monitor the size of the vapor chamber and the position of the gas-oil interface. Production and injection wells were placed above each other and at the center of the model. The effects of solvent concentration, and carrier gas type on production parameters and produced oil properties were also investigated. Propane was used as a solvent, and methane and carbon dioxide (CO{sub 2}) were used as carrier gases. Results of the study showed that high injection pressures caused fluctuations in system behaviour. The solvent chamber grew in a lateral direction, and less asphaltene precipitation was observed. It was concluded that the VAPEX process can be used in high pressure reservoirs when combined with non-condensable carrier gases. 14 refs., 3 tabs., 12 figs.

  13. Modeling and detection of oil in sea water

    DEFF Research Database (Denmark)

    Xenaki, Angeliki; Gerstoft, Peter

    2013-01-01

    The challenge of a deep-water oil leak is that a significant quantity of oil remains in the water column and possibly changes properties. There is a need to quantify the oil settled within the water column and determine its physical properties to assist in the oil recovery. There are currently no methods to map acoustically submerged oil in the sea. In this paper, high-frequency acoustic methods are proposed to localize the oil polluted area and characterize the parameters of its spatial covariance, i.e., variance and correlation. A model is implemented to study the underlying mechanisms of backscattering due to spatial heterogeneity of the medium and predict backscattering returns. An algorithm for synthetically generating stationary, Gaussian random fields is introduced which provides great flexibility in implementing the physical model of an inhomogeneous field with spatial covariance. A method for inference of spatial covariance parameters is proposed to describe the scattering field in terms of its second-order statistics from the backscattered returns. The results indicate that high-frequency acoustic methods not only are suitable for large-scale detection of oil contamination in the water column but also allow inference of the spatial covariance parameters resulting in a statistical description of the oil field.

  14. The analytic instrument for surface water of oil field

    International Nuclear Information System (INIS)

    The analytic instrument for surface water of oil field is an intelligent measuring instrument, integrating light, machine and electricity. It bases on 8031 SCP and makes full use of CASIO printing calculate's functions of calculation, keyboard and printing

  15. Oil field produced water discharges into wetlands in Wyoming

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — Approximately 600 oil field produced water discharges are permitted in Wyoming by the States Department of Environmental Qualitys WDEQ National Pollutant Discharge...

  16. Hydrodynamic characteristics of water-jet pump for removing oils

    International Nuclear Information System (INIS)

    The hydrodynamic characteristics of a bend-type of water-jet pump for removing oils and solid materials with water are discussed theoretically and experimentally. This type of water-jet pump is composed of a bend and a water-jet nozzle. The water-jet nozzle is connected directly to the bend at the outside of bend. The transportation characteristics are derived theoretically using the continuity, momentum and energy equations. The experiments for 45o bend-type of water-jet pump are carried out. The solid spheres with the specific gravity about 1.00 were used. The theoretically-predicted characteristics for removing solid materials agree well with the experimental results. The experimental results for transporting various heavy oils are discussed comparing with the theoretical results. The flows for transporting various heavy oils are visualized. (author)

  17. Oil/water separation in a novel cyclone separator

    OpenAIRE

    Stone, Andrew Colin

    2007-01-01

    Conventional bulk oil-water separation is performed in large gravity separators that take up large areas and potentially contain large volumes of hazardous material. An intensified bulk separator has the potential to provide significant benefit in saving space, especially where this is at a premium, and in improving safety. The I-SEP, a novel geometry of Axial-Flow Cyclone (also known as Uniflow or straight-through) separator, has been tested as an intensified bulk oil-water se...

  18. Spontaneous Formation of Water Droplets at Oil-Solid Interfaces

    Science.gov (United States)

    Yang, Zhongqiang; Abbott, Nicholas L.

    2010-01-01

    We report observations of spontaneous formation of micrometer-sized water droplets within micrometer-thick films of a range of different oils (isotropic and nematic 4-cyano-4’-pentylbiphenyl (5CB), and silicone, olive and corn oil) that are supported on glass substrates treated with octadecyltrichlorosilane (OTS) and immersed under water. Confocal imaging was used to determine that the water droplets nucleate and grow at the interface between the oils and OTS-treated glass with a contact angle of ~130°. A simple thermodynamic model based on macroscopic interfacial energetic arguments consistent with the contact angle of 130°, however, fails to account for the spontaneous formation of the water droplets. ?-potential measurements performed with OTS-treated glass (? 59.0 ± 16.4 mV) and hydrophobic monolayers formed on gold films (2.0 ± 0.7 mV), when combined with the observed absence of droplet formation under films of oil supported on the latter surfaces, suggest that the charge of the oil-solid interface promotes partitioning of water to the interfacial region. The hydrophobic nature of the OTS-treated glass promotes dewetting of water accumulated in the interfacial region into droplets (a thin film of water is seen to form on bare glass). The inhibitory effect on droplet formation of both salt (NaCl) and sucrose (0.1mM to 500mM) added to the aqueous phase was similar, indicating that both solutes lower the chemical potential of the bulk water (osmotic effect) sufficiently to prevent partitioning of the water to the interface between the oil and supporting substrates. These results suggest that charged, hydrophobic surfaces can provide routes to spontaneous formation of surface-supported, water-in-oil emulsions. PMID:20712383

  19. In Vitro and In Vivo Evaluation of a Water-in-Oil Microemulsion System for Enhanced Peptide Intestinal Delivery

    OpenAIRE

    LIU, DONGYUN; Kobayashi, Taku; Russo, Steven; Li, Fengling; Plevy, Scott E.; Gambling, Todd M.; Carson, Johnny L.; Mumper, Russell J.

    2012-01-01

    Peptide and protein drugs have become the new generation of therapeutics, yet most of them are only available as injections, and reports on oral local intestinal delivery of peptides and proteins are quite limited. The aim of this work was to develop and evaluate a water-in-oil (w/o) microemulsion system in vitro and in vivo for local intestinal delivery of water-soluble peptides after oral administration. A fluorescent labeled peptide, 5-(and-6)-carboxytetramethylrhodamine labeled HIV transa...

  20. Rotor clearance design and evaluation for an oil injected twin screw compressor

    Science.gov (United States)

    Buckney, D.; Kovacevic, A.; Stosic, N.

    2015-08-01

    Designing twin screw compressors to safely operate at higher than normal temperatures poses a challenge as the compressor must accommodate larger peak thermal distortions while ideally maintaining efficiency at nominal operating conditions. This paper will present a case study of an oil injected compressor tested at elevated discharge temperatures with original and revised clearances. The local thermal distortions occurring within the compressor during operation were estimated using a procedure developed by the authors - thermodynamic results from a chamber model were used to approximate component temperature distributions that are then used to predict possible thermal distortions and the resulting affect on clearance gaps. The original and revised clearance designs are evaluated and performance penalties incurred due to the modifications are discussed.

  1. Study and application of gelled foam for in-depth water shutoff in a fractured oil reservoir

    Energy Technology Data Exchange (ETDEWEB)

    Qing, Y.; Yefei, W.; Wei, Z.; Ziyuan, Q.; Fulin, Z. [China Univ. of Petroleum, Beijing (China)

    2009-12-15

    Most oil fields in China are in a high water cut period whereby injection water and edge water breaks through into the oil wells along high permeability zones causing a decrease in well productivity. Since high permeability zones cannot be plugged effectively with foam agents, this study focused on the feasibility of using gelled foam for in-depth water shutoff. A gelled foam consists of water, a foaming agent, a foaming stabilizer and a cross-linking agent. A gelled foam is more stable than conventional foam and therefore prolongs the effective period of water shutoff. The Ross Foamer Device was used in this study to determine the foaming and stability characteristics of a gelled foam. The best foaming agent was 0.3 per cent YG240. The stable foam agent was 0.2 to 0.4 per cent HPAM. The cross-linking agent was 0.09 per cent sodium dichromate and 0.16 per cent sodium sulphite and nitrogen. A pilot test was conducted on a well in the Huoshaoshan fractured reservoir. The workover program involved washing large fissures with a high efficiency oil displacement agent and injecting the gelled foam. Good blocking efficiency was obtained in the well, resulting in a decrease in water cut of 20 to 50 per cent. Oil production increased by 3.7 to 11.0 cubic metres per day after gelled foam treatment. 5 refs., 9 tabs., 3 figs.

  2. Behavior of Malondialdehyde in Oil-in-Water Emulsions.

    Science.gov (United States)

    Vandemoortele, Angelique; De Meulenaer, Bruno

    2015-06-17

    The impact of temperature, emulsifier, and protein type on the reactivity of malondialdehyde in oil-in-water emulsions was elucidated. Malondialdehyde recoveries in aqueous buffer, protein solutions, saturated oil, and fully hydrogenated coconut oil-in-water emulsions stabilized by whey proteins or Tween 20 at 4 or 40 °C were compared. At both temperatures, the reactivity of malondialdehyde in aqueous buffer was the same. In protein solutions, malondialdehyde concentrations were reduced further and its decrease was protein-dependent. Similar trends were found for emulsions. Surprisingly, malondialdehyde was very reactive in saturated oil because only 15% was recovered at 40 °C. However, the degradation in oil proved to be strongly temperature-dependent; at 4 °C, losses amounted to only 8%. This study revealed that malondialdehyde is a very reactive molecule, both in the presence and absence of proteins. Its use as a general oxidation marker should therefore be considered with care. PMID:26016781

  3. Petrophysical and rock-mechanics effects of CO2 injection for enhanced oil recovery

    DEFF Research Database (Denmark)

    Alam, Mohammad Monzurul; Hjuler, Morten Leth; Christensen, Helle Foged; Fabricius, Ida Lykke

    2014-01-01

    Enhanced oil recovery by CO2 injection (CO2-EOR) is a tertiary oil recovery process which has a prospective for being used, at the same time, as an effective technique for carbon dioxide storage. There is a huge potential for additional oil production and CO2 storage in the North Sea depleted chalk reservoirs. North Sea chalk is characterized by high porosity but also high specific surface causing low permeability. A high porosity provides room for CO2 storage, while a high specific surface caus...

  4. Water layer height measurement in oil-water two-phase flows

    Science.gov (United States)

    Huang, S.-F.; Lu, J.; Zhang, B. D.; Wang, D.

    2012-03-01

    Water layer height was measured by a single-wire capacitance probe in horizontal oil-water two-phase flows. The viscosity of oil was up to 140 mPa.s to simulate the actual flow in oil production logging. Typical water-layer-height curves with time were obtained when water was continuous. The accuracy was estimated by a quick-closing valve (QCV) system. Time traces of water layer height were completely consistent with the corresponding flow structures. The statistic parameters, such as amplitude, average, and frequency, were different from each other, which can describe the features of the flow patterns. The single-wire capacitance probe can only detect continuous water, instead of emulsified water in oil. However, the emulsified water had effect on flow structure, indirectly influencing the measurement results. On the basis of the measurements in different flows, the same principle was obeyed including air-water, and oil-water two-phase flows with oil of different viscosities. The detection ability of the probe decreased as interfacial velocity increasing or the size decreasing of the discrete phase, and flow patterns determined the measurement accuracy. The error of estimated water holdup by the probe was -35~10% and 5~25% for stratified and dispersed oil in water flows, respectively.

  5. Stable highly hydrophobic and oleophilic meshes for oil water separation

    Science.gov (United States)

    Wang, Qingjun; Cui, Zhe; Xiao, Yi; Chen, Qingmin

    2007-09-01

    This paper describes a simple method for fabricating both highly hydrophobic and oleophilic meshes by coating thin fluoro-containing films. The static contact angle of such meshes is greater than 150° for water, and close to 0° for kerosene, xylene and toluene. These meshes can separate water from oil effectively without resorting to any extra power or chemical agent. Moreover, they exhibited stable water resisting, anti-chemical erosion and anti-hot aging properties. It promises as a candidate for the separation of oil and water.

  6. Theoretical analysis of the effect of water and ethanol injection on axial compressor instabilities

    International Nuclear Information System (INIS)

    Two types of instabilities that occur in compression systems rotating stall and surge have an adverse effect on the compressor performance. Several techniques have been explored to minimize the effect of these instabilities. It has been observed that injection of a liquid into the compressor not only improves thermodynamic efficiencies but also results in stabilizing the system. Therefore, water and ethanol injection has been investigated as an effective tool for controlling these compressor instabilities. In the present paper a modified Moore-Greitzer model has been proposed for wet compression-based system using water and ethanol. Under this work the effect of injection of water (1) at various stages of compressor, (2) at different altitudes and (3) by varying amounts has also been presented. The effect of various parameters on wet compression such as (a) Optimum stage for liquid injection (b) Optimum amount of liquid injection and (c) Effect of altitude on liquid injection is also examined in the present work which shows that the liquid injection helps in improving the performance of compression systems in terms of increase in the stall margin and pressure rise coefficient. - Highlights: ? We model the effect of liquid injection on the performance of axial flow compressors. ? The basic Moore-Grietzer's model has been appropriately modified. ? Injection of liquid in the later stages of the compressor resulted in improved stall margin and pressure rise. ? Use of ethanol was found to give better performance than water.

  7. Effects of graphene coating and charge injection on water adsorption of solid surfaces

    Science.gov (United States)

    Guo, Yufeng; Guo, Wanlin

    2013-10-01

    The adhesion and cohesion of water molecules on graphene-coated and bare copper and mica substrates under charge injection have been extensively studied by first-principles calculations. Water adsorption on graphene-coated copper surface is weakened by injecting negative charges into the substrate, while enhanced by positive charges. Both negatively and positively charge injecting on graphene-coated mica strengthen the adsorption between water and the surface. While the adhesive and cohesive energies of water adsorption on charged bare copper and mica exhibit similar trends and much stronger response to charge injection. The charge sensitivity of water adsorbing on positively charged surfaces is significantly weakened by the graphene coating layer, mainly due to lower interfacial charge exchange. Our results suggest a viable way to modify water adsorption on a graphene-coated surface and unveil the role of graphene as a passivation layer for the wetting of a charged substrate.The adhesion and cohesion of water molecules on graphene-coated and bare copper and mica substrates under charge injection have been extensively studied by first-principles calculations. Water adsorption on graphene-coated copper surface is weakened by injecting negative charges into the substrate, while enhanced by positive charges. Both negatively and positively charge injecting on graphene-coated mica strengthen the adsorption between water and the surface. While the adhesive and cohesive energies of water adsorption on charged bare copper and mica exhibit similar trends and much stronger response to charge injection. The charge sensitivity of water adsorbing on positively charged surfaces is significantly weakened by the graphene coating layer, mainly due to lower interfacial charge exchange. Our results suggest a viable way to modify water adsorption on a graphene-coated surface and unveil the role of graphene as a passivation layer for the wetting of a charged substrate. Electronic supplementary information (ESI) available. See DOI: 10.1039/c3nr02867d

  8. Optimal waste heat recovery in micro gas turbine cycles through liquid water injection

    International Nuclear Information System (INIS)

    Water injection in the compressor exhaust, to recuperate waste heat, is considered a possible route to improve the electric efficiency and overall performance of the micro Gas Turbine turbine (mGT). Many research exists on water injection in mGTs, however a generic study to determine the optimal route for waste heat recovery is still missing. To determine the optimal cycle settings for waste heat recovery through water injection, we have performed simulations using a two-step method. In a first step, the thermodynamic limit for water injection is sought using a black box method. In a second step, the cycle layout is designed by means of composite curve theory. This paper summarizes the results of two scenarios. In the first scenario, the black box is considered as adiabatic and no fixed stack temperature is imposed (thus allowing condensation of the exhaust gasses). One of the major concerns when injecting water is the water consumption, which can be compensated in some cases through condensation and recycling the condensate. Therefore, in the second scenario, the cycle is made self-sufficient with water. In this case, the black box is no longer considered adiabatic and heat exchange with the environment is allowed for condensation of the flue gasses. Black box simulations showed that lowering the stack temperature to 53 °C results in an injection of 17 %wt of water and an increase in electric efficiency of 9% absolute. To keep the mGT cycle layout simple, low cost and not too complex, a maximum of two heat exchangers was imposed for the heat exchanger network design. Although black box analysis indicated a large potential for water introduction, this potential could not be achieved with the considered networks in this paper. Finally, injection of preheated water was identified as the optimal water injection scheme for waste heat recovery resulting in 4.6% absolute electric efficiency increase and a final stack temperature of 62 °C. Results of simulations of the second case indicate that the stack temperature needs to be lowered under 26 °C in order to make the cycle self-sufficient with water. - Highlights: • Adiabatic black box method was used to find the optimal route for waste heat recovery through water injection. • Full water recovery was added as a constraint for the black box analysis. • Composite curve theory was used to design the heat exchange and injection network. • Direct injection of water results in an absolute efficiency increase of 4.6%. • Stack temperature needs to be below 26 °C to have full recovery of water

  9. Factors in the Design of Centrifugal Type Injection Valves for Oil Engines

    Science.gov (United States)

    Joachim, W F; Beardsley, E G

    1928-01-01

    This research was undertaken in connection with a general study of the application of the fuel injection engine to aircraft. The purpose of the investigation was to determine the effect of four important factors in the design of a centrifugal type automatic injection valve on the penetration, general shape, and distribution of oil sprays. The general method employed was to record the development of single sprays by means of special high-speed photographic apparatus capable of taking 25 consecutive pictures of the moving spray at a rate of 4,000 per second. Investigations were made concerning the effects on spray characteristics, of the helix angle of helical grooves, the ratio of the cross-sectional area of the orifice to that of the grooves, the ratio of orifice length to diameter, and the position of the seat. Maximum spray penetration was obtained with a ratio of orifice length to diameter of about 1.5. Slightly greater penetration was obtained with the seat directly before the orifice.

  10. Determining the water cut and water salinity in an oil-water flowstream by measuring the sulfur content of the produced oil

    International Nuclear Information System (INIS)

    A technique for detecting water cut and water salinity in an oil/water flowstream in petroleum refining and producing operations is described. The fluid is bombarded with fast neutrons which are slowed down and then captured producing gamma spectra characteristic of the fluid material. Analysis of the spectra indicates the relative presence of the elements sulfur, hydrogen and chlorine and from the sulfur measurement, the oil cut (fractional oil content) of the fluid is determined, enabling the water cut to be found. From the water cut, water salinity can also be determined. (U.K.)

  11. Finding Balance Between Biological Groundwater Treatment and Treated Injection Water

    Energy Technology Data Exchange (ETDEWEB)

    Carlson, Mark A.; Nielsen, Kellin R.; Byrnes, Mark E.; Simmons, Sally A.; Morse, John J.; Geiger, James B.; Watkins, Louis E.; McFee, Phillip M.; Martins, K.

    2015-01-14

    At the U.S. Department of Energy’s Hanford Site, CH2M HILL Plateau Remediation Company operates the 200 West Pump and Treat which was engineered to treat radiological and chemical contaminants in groundwater as a result of the site’s former plutonium production years. Fluidized bed bioreactors (FBRs) are used to remove nitrate, metals, and volatile organic compounds. Increasing nitrate concentrations in the treatment plant effluent and the presence of a slimy biomass (a typical microorganism response to stress) in the FBRs triggered an investigation of nutrient levels in the system. Little, if any, micronutrient feed was coming into the bioreactors. Additionally, carbon substrate (used to promote biological growth) was passing through to the injection wells, causing biological fouling of the wells and reduced specific injectivity. Adjustments to the micronutrient feed improved microorganism health, but the micronutrients were being overfed (particularly manganese) plugging the injection wells further. Injection well rehabilitation to restore specific injectivity required repeated treatments to remove the biological fouling and precipitated metal oxides. A combination of sulfamic and citric acids worked well to dissolve metal oxides and sodium hypochlorite effectively removed the biological growth. Intensive surging and development techniques successfully removed clogging material from the injection wells. Ultimately, the investigation and nutrient adjustments took months to restore proper balance to the microbial system and over a year to stabilize injection well capacities. Carefully tracking and managing the FBRs and well performance monitoring are critical to balancing the needs of the treatment system while reducing fouling mechanisms in the injection wells.

  12. Determination of oil/water and octanol/water distribution coefficients from aqueous solutions from four fossil fuels. [MS thesis; in oil-water and octanol-water

    Energy Technology Data Exchange (ETDEWEB)

    Thomas, B.L.

    1984-07-01

    Liquid fossil fuels, both petroleum and synthetically derived oils, are exceedingly complex mixtures of thousands of components. The effect of many of these energy-related components on the environment is largely unknown. Octanol/water distribution coefficients relate both to toxicity and to the bioaccumulation potential of chemical components. Use of these partition data in conjunction with component concentrations in the oils in environmental models provides important information on the fate of fossil fuel components when released to the environment. Octanol/water distribution data are not available for many energy-related organic compounds, and those data that are available have been determined for individual components in simple, one-component octanol/water equilibrium mixtures. In this study, methods for determining many octanol/water distribution coefficients from aqueous extracts of oil products were developed. Sample aqueous mixtures were made by equilibrating liquid fossil fuels with distilled water. This approach has the advantage of detecting interactions between components of interest and other sample components. Compound types studied included phenols, nitrogen bases, hydrocarbons, sulfur heterocyclic compounds, and carboxylic acids. Octanol/water distribution coefficients that were determined in this study ranged from 9.12 for aniline to 67,600 for 1,2-dimethylnaphthalene. Within a compound type, distribution coefficients increased logarithmically with increasing alkyl substitution and molecular weight. Additionally, oil/water distribution data were determined for oil components. These data are useful in predicting maximum environmental concentrations in water columns. 96 references, 26 figures, and 40 tables.

  13. Surfactant controlled switching of water-in-oil wetting behaviour of porous silica films grown at oil-water interfaces

    Indian Academy of Sciences (India)

    Manish M Kulkarni; Rajdip Bandyopadhyaya; Ashutosh Sharma

    2008-11-01

    Selective permeation of oil and water across a porous medium, as in oil recovery operations, depends on the preferential wetting properties of the porous medium. We show a profound influence of surfactants in wetting of porous media and thus demonstrate a new route for the control of water-in-oil wetting of porous substrates by changing the concentration of surfactants in an aqueous sub-phase below the substrate. This strategy is employed to engineer partial reversible wetting transitions on a porous silica film. The film itself is grown and stabilized on a flat, macroscopic interface between an oil phase and an aqueous sub-phase. On increasing the surfactant (CTAB) concentration in the sub-phase, contact angle of a water drop (placed on the oil side of the film) changes from 140° to 16° in 25 min by diffusion of the surfactant across the porous film. On further replacement of the sub-phase with pure water, diffusion of the surfactant from the water drop back to the sub-phase was slower, increasing the contact angle in the process from 16° to 90° in 2 h. Wettability control by a cationic surfactant (CTAB) was found to be much faster (6 deg/min) than that offered by an anionic surfactant, SDS (0.05 deg/min). Switching of the surface wettability due to the surfactant diffusion may have implications in oil-water separation, chemical bed reactors and microfluidic devices.

  14. Bacteria motility at oil-water interfaces

    Science.gov (United States)

    Juarez, Gabriel; Smirga, Steven; Fernandez, Vicente; Stocker, Roman

    2012-11-01

    The swimming dynamics of bacteria are strongly influenced by interfaces: Motile bacteria often accumulate at rigid boundaries, such as liquid-solid interfaces, and at soft boundaries, such as liquid-air or liquid-liquid interfaces. Attachment of bacteria to these interfaces is crucial for the formation of biofilms (liquid-solid), pellicles (liquid-air), and oil-degrading communities (liquid-liquid). We investigated the motility of the oil-degrading bacteria Marinobacter aquaeolei in the presence of oil droplets. We created individual oil droplets using dedicated microfluidic devices and captured the swimming behavior of individual bacteria near the interface and their attachment dynamics to the droplets with high-speed and epifluorescent microscopy. We find that Marinobacter aquaeolei has a high affinity towards interfaces and their swimming dynamics at soft interfaces differ from both those in the bulk and at rigid boundaries. Characterizing the interaction and attachment of motile bacteria to liquid-liquid interfaces will promote a fundamental understanding to oil-microbe interactions in aquatic environments and potentially lead to improved oil bioremediation strategies.

  15. Policy Analysis of Water Availability and Use Issues for Domestic Oil Shale and Oil Sands Development

    Energy Technology Data Exchange (ETDEWEB)

    Ruple, John; Keiter, Robert

    2010-12-31

    Oil shale and oil sands resources located within the intermountain west represent a vast, and as of yet, commercially untapped source of energy. Development will require water, and demand for scarce water resources stands at the front of a long list of barriers to commercialization. Water requirements and the consequences of commercial development will depend on the number, size, and location of facilities, as well as the technologies employed to develop these unconventional fuels. While the details remain unclear, the implication is not – unconventional fuel development will increase demand for water in an arid region where demand for water often exceeds supply. Water demands in excess of supplies have long been the norm in the west, and for more than a century water has been apportioned on a first-come, first-served basis. Unconventional fuel developers who have not already secured water rights stand at the back of a long line and will need to obtain water from willing water purveyors. However, uncertainty regarding the nature and extent of some senior water claims combine with indeterminate interstate river management to cast a cloud over water resource allocation and management. Quantitative and qualitative water requirements associated with Endangered Species protection also stand as barriers to significant water development, and complex water quality regulations will apply to unconventional fuel development. Legal and political decisions can give shape to an indeterminate landscape. Settlement of Northern Ute reserved rights claims would help clarify the worth of existing water rights and viability of alternative sources of supply. Interstate apportionment of the White River would go a long way towards resolving water availability in downstream Utah. And energy policy clarification will help determine the role oil shale and oil sands will play in our nation’s future.

  16. Effect of water injection on sustained combustion in a porous medium

    Energy Technology Data Exchange (ETDEWEB)

    Beckers, H.L.; Harmsen, G.J.

    1970-06-01

    A theoretical description is presented of the various semisteady states that may develop in an in situ combustion process if water is injected together with the air. The investigation has been restricted to cases of one- dimensional flow without heat losses, such as would occur in a narrow, perfectly insulated tube. Different types of behavior can be distinguished for specific ranges of the water/air injection ratio. At low values of this ratio, the injected water evaporates before it reaches the combustion zone, while at high values it passes through the combustion zone without being completely evaporated, but without extinguishing combustion. At intermediate values and at sufficiently high fuel concentrations, intermediate situations are possible, in which all water entering the combustion zone evaporates before leaving it. Formulas are presented that give the combustion zone velocity as a function of water/air injection ratio for each of the possible situations. (17 refs.)

  17. Numerical Study of Water Control with Downhole Oil-Water Separation Technology

    OpenAIRE

    Yin Khor Yin; Al-Kayiem Hussain H.; Pao William

    2014-01-01

    The maturing oil fields with increasing water production can pose a challenging produced water handling and disposal issues. This paper presents a numerical study of a motorless hydrocyclone to enhance understanding of the downhole oil-water separation. The turbulence of fluid flow is obtained using K-? Realizable Turbulence model for complex swirl dominated flow, while the interface between hydrocarbon and water is described using the Discrete Phase model. In this approach, factors which con...

  18. Oil palm plantation effects on water quality in Kalimantan, Indonesia

    Science.gov (United States)

    Carlson, K. M.; Curran, L. M.

    2011-12-01

    Global demand for palm oil has stimulated a 7-fold increase in oil palm (Elaeis guineensis) plantation area in Indonesia since 1990. Expansion will continue as Indonesia plans to double current production by 2020. Oil palm fertilizers, effluent from oil palm mills, and erosion from land clearing and roads threaten river water quality near plantations. These rivers provide essential ecosystem services including water for drinking, cooking, and washing. Robust empirical measurements of plantation expansion impacts on water resources are necessary to discern the effects of agribusiness on local livelihoods and ecosystems. In Ketapang District, West Kalimantan, Indonesian Borneo, we evaluated the effects of land cover change on water quality by assessing water chemistry in streams draining four end-member watersheds ( ~600-1900 ha watershed-1): Logged forest, mixed agro-forest dominated by rubber and upland rice fallows, young oil palm forest (0-5 years), and old oil palm forest (10-15 years). To assess land cover change, we used CLASLite software to derive fractional cover from a time series (1989-2008) of Landsat data. Nearest neighbor classification and post-classification change detection yielded classes including primary forest, logged forest, secondary forest regrowth, smallholder agriculture, and oil palm. Stream water quality (temperature, dissolved oxygen, turbidity, optical chlorphyll, and pH) and quantity (discharge) were quantified with the YSI 6600-V2 sonde. The sonde was deployed in each stream for month-long intervals 2-3 times from 2009-2010. Such extended deployment captures episodic events such as intense storms and allows examination of interdiel dynamics by sampling continuously and at high frequency, every 10 minutes. We find that across the Ketapang District study region (~12,000 km2), oil palm has cleared mostly forests (49%) and agroforests (39%). What are the impacts of such land cover changes on water quality? Compared to forests and agroforests, streams draining oil palm show greater biological activity, as indicated by elevated pH and reduced dissolved oxygen levels. Moreover, turbidity is elevated in young oil palm plantations watersheds compared to forest, agroforest, and old oil palm land covers. We discuss the implications of these findings for communities and ecosystems.

  19. 40 CFR 60.4335 - How do I demonstrate compliance for NOX if I use water or steam injection?

    Science.gov (United States)

    2010-07-01

    ...demonstrate compliance for NOX if I use water or steam injection? 60.4335 Section 60.4335...demonstrate compliance for NOX if I use water or steam injection? (a) If you are using water or steam injection to control NOX emissions,...

  20. Cleaning of Oil Fouling with Water Enabled by Zwitterionic Polyelectrolyte Coatings: Overcoming the Imperative Challenge of Oil-Water Separation Membranes.

    Science.gov (United States)

    He, Ke; Duan, Haoran; Chen, George Y; Liu, Xiaokong; Yang, Wensheng; Wang, Dayang

    2015-09-22

    Herein we report a self-cleaning coating derived from zwitterionic poly(2-methacryloyloxylethyl phosphorylcholine) (PMPC) brushes grafted on a solid substrate. The PMPC surface not only exhibits complete oil repellency in a water-wetted state (i.e., underwater superoleophobicity), but also allows effective cleaning of oil fouled on dry surfaces by water alone. The PMPC surface was compared with typical underwater superoleophobic surfaces realized with the aid of surface roughening by applying hydrophilic nanostructures and those realized by applying smooth hydrophilic polyelectrolyte multilayers. We show that underwater superoleophobicity of a surface is not sufficient to enable water to clean up oil fouling on a dry surface, because the latter circumstance demands the surface to be able to strongly bond water not only in its pristine state but also in an oil-wetted state. The PMPC surface is unique with its described self-cleaning performance because the zwitterionic phosphorylcholine groups exhibit exceptional binding affinity to water even when they are already wetted by oil. Further, we show that applying this PMPC coating onto steel meshes produces oil-water separation membranes that are resilient to oil contamination with simply water rinsing. Consequently, we provide an effective solution to the oil contamination issue on the oil-water separation membranes, which is an imperative challenge in this field. Thanks to the self-cleaning effect of the PMPC surface, PMPC-coated steel meshes can not only separate oil from oil-water mixtures in a water-wetted state, but also can lift oil out from oil-water mixtures even in a dry state, which is a very promising technology for practical oil-spill remediation. In contrast, we show that oil contamination on conventional hydrophilic oil-water separation membranes would permanently induce the loss of oil-water separation function, and thus they have to be always used in a completely water-wetted state, which significantly restricts their application in practice. PMID:26260326

  1. An alternative water supply for heavy oil steam generation plants : potential sources of brackish water from the Cretaceous Mannville Group in the Cold Lake region

    Energy Technology Data Exchange (ETDEWEB)

    Horne, E.; Sun, S.; Nichols, L.; Agatonovic, V. [Terracon Geotechnique Ltd., Calgary, AB (Canada)

    2002-07-01

    Large quantities of freshwater are needed for processing oil sands in the Athabasca, Cold Lake and Peace River regions of Alberta. The largest in-situ bitumen recovery project where oil sands are heated by steam injection to extract bitumen to the surface is found in the Cold Lake region. This paper focused on five heavy oil plants in the area. Surface water and shallow groundwater are the two sources of water supply that are currently used for steam injection processes such as cyclic steam stimulation (CSS) and steam assisted gravity drainage (SAGD). However, brackish water is being considered as an alternative source of water. Brackish water from basal aquifers is found in the lower portion of the Mannville Group and below the heavy oil horizons. Source water for heavy oil production must have acceptable salinity and total dissolved solid (TDS) levels to reduce the risk of corrosion and precipitation. It must also have a balanced flow equilibrium to sustain long term yield. TDS and salinity can be estimated from electrical logs using empirical formulae. Chloride concentration can also be used as an indicator of both groundwater salinity and TDS. In this study, the chloride concentration and TDS of formation brackish water were calculated from formation resistivity using an empirical formula. The formation water resistivity was calculated from spontaneous potential readings and formation temperature. The objective was to determine the best locations for a long term water well to supply brackish water for steam generation in the Cold Lake area. The ideal locations were found to be in the northeastern quarter of the study area. 5 refs., 6 figs.

  2. Selection of potential cold water marine species for testing of oil dispersants, and chemically dispersed oil

    International Nuclear Information System (INIS)

    A study regarding marine species for toxicity testing for Alaska conditions was presented and the potential adverse impacts of a large marine oil spill in cold water were discussed with the objective to determine if the spill should be treated by the use of oil dispersants. Without dispersion, the oil can pollute marine epifauna and can deposit on beaches. The decision to apply dispersants to a marine oil spill requires knowledge of the toxicity of the undispersed oil to pelagic marine life occurring via natural dispersion as opposed to the toxicity of the oil-dispersant mixture. Most standard toxicity tests apply to warm water species. This paper discussed the need to have a standard test species relevant to Alaska waters for toxicity testing. In this study, toxicity testing was done according to the methods of the Chemical Response to Oil Spills : Ecological Effects Research Forum (CROSERF). The testing included capturing adult species in the winter and holding them until larval hatching. Toxicity testing was completed in a narrow time frame before hatching ceased. Many chemical samples were tested. Topsmelt, urchins, shellfish, mysids, copepods, pink salmon fry, and tidepool sculpin were considered by the author to be the most useful for certain types of toxicity testing. 29 refs

  3. CHARACTERIZATION OF OIL SHALE MINE WATERS, CENTRAL PICEANCE BASIN, COLORADO

    Science.gov (United States)

    A study was conducted to characterize the oil shale mine waters in the Piceance Basin. The study sites were Federal Prototype Lease Tracts C-a and C-b, located in the central portion of the basin. The objective was to collect water quality data in order to characterize the mine w...

  4. Determination of Zinc-Based Additives in Lubricating Oils by Flow-Injection Analysis with Flame-AAS Detection Exploiting Injection with a Computer-Controlled Syringe

    Directory of Open Access Journals (Sweden)

    Gustavo Pignalosa

    2005-01-01

    Full Text Available A flow-injection system is proposed for the determination of metal-based additives in lubricating oils. The system, operating under computer control uses a motorised syringe for measuring and injecting the oil sample (200 μL in a kerosene stream, where it is dispersed by means of a packed mixing reactor and carried to an atomic absorption spectrometer which is used as detector. Zinc was used as model analyte. Two different systems were evaluated, one for low concentrations (range 0–10 ppm and the second capable of providing higher dilution rates for high concentrations (range 0.02%–0.2% w/w. The sampling frequency was about 30 samples/h. Calibration curves fitted a second-degree regression model (r2 = 0.996. Commercial samples with high and low zinc levels were analysed by the proposed method and the results were compared with those obtained with the standard ASTM method. The t test for mean values showed no significant differences at the 95% confidence level. Precision (RSD% was better than 5% (2% typical for the high concentrations system. The carryover between successive injections was found to be negligible.

  5. Design and operation of laboratory combustion cell for air injection into light oil reservoirs: potential application in Sindh field

    International Nuclear Information System (INIS)

    Historical experimental work on the combustion oil recovery processes consists of both laboratory and field studies. Although field experiments are the ultimate test of any oil recovery process, they are costly, time consuming and difficult to analyze quantitatively. Laboratory CC (Combustion Cell) experiments are cost effective and less time consuming, but are subject to scaling and interpretation challenges. Experimental set up has been developed to understand air injection process for improving oil recovery from light oil reservoirs taking into account the sand pack petro physical and fluid properties. Some important design problems; operational criteria and considerations important to interpretation of results are pointed out. To replicate subsurface reservoir conditions or pressure and temperature, experiments up to 6895 KPa, at non-isothermal conditions with 5 deg. C/min ramp-up are performed on unconsolidated cores with reservoir oil samples. Correlations were obtained for low temperature oxidation rate of oil, the fuel deposition rate and the rate of burning fuel as a fuel concentration. Various parameters such as (sand pack, pressure, oil saturation and flow rate/air flux) were changed to investigate their impact on reaction and chemical nature of the fuel burned. To determine the importance of distribution and pyrolysis on these reactions, he hydrogen-carbon ratio and m-ratio was calculated. For further confirmation Arrhenius graphs were drawn by assuming 1.0 order of reaction with carbon concentration which is also confirmed.This research will contribute to the overall understanding of air injection process; help to determine the most appropriate lOR (Improved Oil Recovery) technique in the development of the tertiary phase of production in light oil reservoirs in Lower Indus Basin (Sindh) fields. (author)

  6. Subcritical Water Extraction of Monosaccharides from Oil Palm Fronds Hemicelluloses

    International Nuclear Information System (INIS)

    Oil palm plantations in Malaysia generate more than 36 million tones of pruned and felled oil palm fronds (OPF) and are generally considered as waste. The composition of monosaccharide in oil palm frond can be extracted using hydrothermal treatment for useful applications. The objectives of this study were to quantify the yield of monosaccharides at various reaction conditions; temperature 170 to 200 degree Celsius, pressure from 500 psi to 800 psi, reaction time from 5 to 15 min using subcritical water extraction and to determine the composition of oil palm frond hemicelluloses at optimum condition. The monosaccharides composition of oil palm frond hemicelluloses were analysed using High Performance Liquid Chromatography (HPLC). The highest yield of monosaccharides can be extracted from OPF at temperature of 190 degree Celsius, pressure of 600 psi and 10 min of contact time which is xylose the most abundant composition (11.79 %) followed with arabinose (2.82 %), glucose (0.61 %) and mannose (0.66 %). (author)

  7. Comparative toxicity of water-accommodated fractions of oil and dispersed oil to marine fish larvae

    Energy Technology Data Exchange (ETDEWEB)

    Couillard, C.M.; Legare, B.; St-Pierre, S. [Department of Fisheries and Oceans, Mont-Joli, PQ (Canada). Maurice Lamontagne Inst.; Lee, K. [Department of Fisheries and Oceans, Dartmouth, NS (Canada). Bedford Inst. of Oceanography

    2003-07-01

    The use of chemical dispersants to clean oil spills on water can increase the risk of toxic effects to early life stages of fish by increasing their exposure to polycyclic aromatic hydrocarbons (PAHs). In this study, water-accommodated fractions of dispersed crude oil were prepared with weathered Mesa light crude oil and filtered seawater with and without Corexit 9500. Newly hatched larvae of mummichog, Fundulus heteroclitus, were exposed to the mixtures to examine the biological effects on the larvae. For an oil loading of 0.2 g/L, the addition of dispersant caused a 2-fold and 7-fold increase in total PAH and high molecular weight PAH with 3 or more benzene rings. A 5-fold increase in ethoxyresorufin-O-deethylase (EROD) activity was observed in larvae exposed to dispersed crude oil water accommodated fractions at a loading of 0.05 g/L. A 4-fold increase was noted when the crude oil water accommodated fractions were loaded at 1 g/L. Both mixtures resulted in reduced body length. The study confirmed that dispersants increase the risk of toxic effects for the early life stage of fish.

  8. Comparative toxicity of water-accommodated fractions of oil and dispersed oil to marine fish larvae

    International Nuclear Information System (INIS)

    The use of chemical dispersants to clean oil spills on water can increase the risk of toxic effects to early life stages of fish by increasing their exposure to polycyclic aromatic hydrocarbons (PAHs). In this study, water-accommodated fractions of dispersed crude oil were prepared with weathered Mesa light crude oil and filtered seawater with and without Corexit 9500. Newly hatched larvae of mummichog, Fundulus heteroclitus, were exposed to the mixtures to examine the biological effects on the larvae. For an oil loading of 0.2 g/L, the addition of dispersant caused a 2-fold and 7-fold increase in total PAH and high molecular weight PAH with 3 or more benzene rings. A 5-fold increase in ethoxyresorufin-O-deethylase (EROD) activity was observed in larvae exposed to dispersed crude oil water accommodated fractions at a loading of 0.05 g/L. A 4-fold increase was noted when the crude oil water accommodated fractions were loaded at 1 g/L. Both mixtures resulted in reduced body length. The study confirmed that dispersants increase the risk of toxic effects for the early life stage of fish

  9. 40 CFR 60.692-3 - Standards: Oil-water separators.

    Science.gov (United States)

    2010-07-01

    ... Emissions From Petroleum Refinery Wastewater Systems § 60.692-3 Standards: Oil-water separators. (a) Each oil-water separator tank, slop oil tank, storage vessel, or other auxiliary equipment subject to the... identified, except as provided in § 60.692-6. (b) Each oil-water separator tank or auxiliary equipment with...

  10. Analysis of nitrogen injection as alternative fluid to steam in heavy oil reservoir; Analise da injecao de nitrogenio como fluido alternativo ao vapor em reservatorio de oleo pesado

    Energy Technology Data Exchange (ETDEWEB)

    Rodrigues, Marcos Allyson Felipe; Galvao, Edney Rafael Viana Pinheiro; Barillas, Jennys Lourdes; Mata, Wilson da; Dutra Junior, Tarcilio Viana [Universidade Federal do Rio Grande do Norte (UFRN), RN (Brazil)

    2012-07-01

    Many of hydrocarbon reserves existing in the world are formed by heavy oils (deg API between 10 and 20). Moreover, several heavy oil fields are mature and, thus, offer great challenges for oil industry. Among the thermal methods used to recover these resources, steam flooding has been the main economically viable alternative. Latent heat carried by steam heats the reservoir, reducing oil viscosity and facilitating the production. This method has many variations and has been studied both theoretically and experimentally (in pilot projects and in full field applications). In order to increase oil recovery and reduce steam injection costs, the injection of alternative fluid has been used on three main ways: alternately, co-injected with steam and after steam injection interruption. The main objective of these injection systems is to reduce the amount of heat supplied to the reservoir, using cheaper fluids and maintaining the same oil production levels. In this paper, the use of N{sub 2} as an alternative fluid to the steam was investigated. The analyzed parameters were oil recoveries and net cumulative oil productions. The reservoir simulation model corresponds to an oil reservoir of 100 m x 100 m x 28 m size, on a Cartesian coordinates system (x, y and z directions). It is a semi synthetic model with some reservoir data similar to those found in Potiguar Basin, Brazil. All studied cases were done using the simulator STARS from CMG (Computer Modelling Group, version 2009.10). It was found that N{sub 2} injection after steam injection interruption achieved the highest net cumulative oil compared to others injection system. Moreover, it was observed that N2 as alternative fluid to steam did not present increase on oil recovery. (author)

  11. Air-water mixing experiments for direct vessel injection of KNGR

    International Nuclear Information System (INIS)

    Two air-water mixing experiments are conducted to understand the flow behavior in the downcomer for Direct Vessel Injection (DVI) of Korean Next Generation Reactor (KNGR). In the first experiment which is an air-water experiment in the rectangular channel with the gap size of 1cm, the width of water film is proportional to the water and air velocities and the inclined angle is proportional to the water velocity only, regardless of the water velocity injected in the rectangular channel. It is observed that the amount of entrained water is negligible. In the second experiment which is a full-scaled water jetting experiment without air flow, the width of water film is proportional to the flow rate injected from the pipe exit and the film thickness of water varies from 1.0mm to 5.0mm, and the maximum thickness does not exceed 5.0mm. The amount of water separated from the liquid film after striking of water jetting on the wall is measured. The amount of separation water is proportional to the flow rate, but the separation ratio in the full-scaled water jetting is not over 15%. A simplified physical model, which is designed to predict the trajectories of the width of water film, is validated through the comparison with experiment results. The 13 .deg. upward water droplet of the water injected from the pipe constitutes the outermost boundary at 1.7m below from pipe level, after the water impinges against the wall. In the model, the parameter, ? which represents the relationship between the jetting velocity and the initial spreading velocity, is inversely proportional to the water velocity when it impinges against the wall. The error of the predictions by the model is decreased within 14% to the experimental data through use of exponential fitting of ? for the jetting water velocity

  12. Mechanics and upscaling of heavy oil bitumen recovery by steam-over-solvent injection in fractured reservoirs method

    Energy Technology Data Exchange (ETDEWEB)

    Singh, R.; Babadagli, T. [Alberta Univ., Edmonton, AB (Canada)

    2011-01-15

    This paper discussed a numerical modelling scheme applied to the steam-over-solvent injection in fractured reservoirs (SOS-FR) method for a single-matrix block. After modelling the process at the core scale, sensitivity tests were performed to determine the optimal injection conditions for efficient oil recovery and solvent retrieval. The basic mechanisms and physics of the process were described along with the amount of injectant and the time required for recovering target oil for field-scale application. In the physics of the recovery mechanism, gravity was found to have a substantial effect on oil recovery when the matrix was exposed to solvent. Special attention was paid to the solvent retrieval rate and amount in the third cycle and the permeability reduction caused by asphaltene precipitation in the solvent injection phase; the latter factor was observed to be substantially critical for the process. An upscaling analysis yielded an encouraging straight-line relationship between the time value to reach ultimate recovery and the matrix size with a non-integer exponent less than 2. 21 refs., 1 tab., 15 figs.

  13. Determination of naturally occurring radioactive materials (NORM) in formation water during oil exploration

    International Nuclear Information System (INIS)

    The present study is conducted, in order to contribute to a future waste management policy related to the presence of technologically enhanced natural occurring radioactive material (TENORM) in Iran petroleum industry. Samples were collected from offshore oil company for analysis of 238U, 235U, and 232Th series in produced waters. The activities of samples were determined by high-purity germanium detector, well for low level activity ?-spectrometry. The results have shown that, 226Ra concentration ranges from 5.26 Bq/L to 27.93 Bq/L. Also the total activity in produced water is in the range of 16-840 Bq/L were mainly due to enhanced levels of dissolved 226Ra, 214Pb, 214Bi ions. Also, enhanced dissolution of elements such as radium by increasing of salinity, result in higher concentration of NORM in old oil region. Measured values are above EPA regulation (40 CFR 141055) and aqueous Derived Release Limit (DRL) of Canadian guideline for the management of (NORM). Therefore produced water has to dispose in pits which have to design for decrease the environmental effects. Also according to this study, re-injection of produced water in to abandon well of Iran Offshore Oil Company in Persian Gulf, have preference over discharging to the pits. (author)

  14. Soil water repellency at old crude oil spill sites

    International Nuclear Information System (INIS)

    This thesis presents the current state of knowledge regarding the cause of soil water repellency and characterizes disaggregated nonwettable surface soils found at old crude oil spill sites. Pollution-induced water repellency generally develops following prolonged exposures of soil to liquid- or vapour-phase petroleum hydrocarbons. The condition varies significantly in terms of severity and persistence. Soil water repellency retards plant growth and disturbs the hydrological balance of ecosystems. Disaggregated water-repellent soils are also very susceptible to dispersal by erosion, posing a threat to the productivity of surrounding soils. The author described the probable causes of soil water repellency under the following three main themes: (1) accumulation of hydrophobic organic material in soil, (2) redistribution and re-organisation of this material in soil, and (3) stabilisation of the hydrophobic organic material. This final process is necessary to ensure persistence of induced water repellency symptoms. Petroleum residues as water-repellent substances in weathered nonwettable oil-contaminated soils were also discussed and a hypothesis about soil water repellency was presented which deals with flexible conformation in organic matter coatings. Processes leading to the development of soil water repellency following crude oil contamination were also described. It was determined that soil water repellency is a function of the packing density and the chain conformation of amphiphilic organic molecules in the outermost layer of soil organic matter coatings. This research suggests that the fractional coverage of alkyl chains on soil particle surfaces determines the degree of water repellency that is displayed by soil. It was shown that prompt remediation of some oil-contaminated plots can effectively prevent the development of soil water repellency. 4 refs., 32 tabs., 22 figs., 5 appendices

  15. Retention of polar oil components in low salinity water flooding

    OpenAIRE

    Sokama-Neuyam, Yen Adams

    2013-01-01

    The influence of brine chemistry, salinity and composition on the retention of polar oil components onto reservoir rock mineral surface in relation to low salinity water flooding (LSWF) was studied and evaluated in this piece of work using ultra-violet visible (UV-Vis) spectroscopy. Five different brine compositions; sea water (SW), formation water (FW), LSW1 (FW diluted 100 times), LSW2 (FW diluted 1000 times) and KCl low salinity brine were studied and their effect on the retention of polar...

  16. Approaching viscosity control: electrical heating of extra heavy oil as alternative to diluent injection in down hole in Cerro Negro Field, Faja Petrolifera del Orinoco

    Energy Technology Data Exchange (ETDEWEB)

    Salazar, Manuel [Petroleos de Venezuela SA, PDVSA (Venezuela)

    2011-07-01

    Electrical heating is a method used to enhance oil recovery in extra heavy oil reservoirs. This method can be used when diluent injection or other methods are not able to reduce oil viscosity sufficiently or when problems of product quality or quantity arise. The aim of this paper is to evaluate the performance of electrical heating, individually and simultaneously with injection of diluents. For this purpose, simulations were undertaken in one well with integrated electrical heating and diluent injection in Cerro Negro Field in the Orinoco oil belt, Venezuela. Results have shown that the application of both methods together is more profitable than the application of electrical heating alone. This paper demonstrated that the use of electrical heating and diluent injection combined is a valid alternative to diluent injection alone, reducing production loss.

  17. Quantifying the concentration of crude oil microdroplets in oil-water preparations.

    Science.gov (United States)

    Redman, Aaron D; McGrath, Joy A; Stubblefield, William A; Maki, Al W; Di Toro, Dominic M

    2012-08-01

    Dissolved constituents of crude oil, particularly polycyclic aromatic hydrocarbons (PAHs), can contribute substantially to the toxicity of aquatic organisms. Measured aqueous concentrations of high-molecular weight PAHs (e.g., chrysenes, benzo[a]pyrene) as well as long-chain aliphatic hydrocarbons can exceed the theoretical solubility of these sparingly soluble compounds. This is attributed to the presence of a "microdroplet" or colloidal oil phase. It is important to be able to quantify the dissolved fraction of these compounds in oil-in-water preparations that are commonly used in toxicity assays because the interpretation of test results often assumes that the compounds are dissolved. A method is presented to determine the microdroplet contribution in crude oil-in-water preparations using a comparison of predicted and measured aqueous concentrations. Measured concentrations are reproduced in the model by including both microdroplets and dissolved constituents of petroleum hydrocarbons. Microdroplets were found in all oil-water preparation data sets analyzed. Estimated microdroplet oil concentrations typically ranged from 10 to 700 µg oil/L water. The fraction of dissolved individual petroleum hydrocarbons ranges from 1.0 for highly soluble compounds (e.g., benzene, toluene, ethylbenzene, and xylene) to far less than 0.1 for sparingly soluble compounds (e.g., chrysenes) depending on the microdroplet oil concentration. The presence of these microdroplets complicates the interpretation of toxicity test data because they may exert an additional toxic effect due to a change in the exposure profile. The implications of the droplet model on toxicity are also discussed in terms of both dissolved hydrocarbons and microdroplets. PMID:22585433

  18. 40 CFR 146.5 - Classification of injection wells.

    Science.gov (United States)

    2010-07-01

    ...drinking water. (3) Radioactive waste disposal wells...connection with conventional oil or natural gas production...used for the purpose of oil or natural gas production...inject fluids into a non-oil or gas producing zone...fresh water; (11) Radioactive waste disposal...

  19. Permeability of fissured rock - an experimental study with special regard to the water injection test

    International Nuclear Information System (INIS)

    The permeability to water of fissured rock is one of the most important design parameters for many underground projects, such as, e.g. the final deposition of radioactive waste. Because the conventional water injection test according to LUGEON for the calculation of permeability to water is associated with a high degree of uncertainty, new test equipment was developed. This equipment works on the principle of the water injection tracer test and multi-level measurements, enabling detailed measurement of the flow process at injection site and in the rock. The tests were carried out in Bunter sandstone and granite. The LUGEON test concept was varied in short-term and long-term tests at identical geological boundary conditions, and with test control at constant pressure on the one hand and at constant injection volume on the other. The test results show that non-steady-state flow occurs with short injection times, whereby the range is limited to the local rock at injection site. An increasing in injection time can lead to an increase in range by a number of factors as well as to steady-state flow conditions. The permeability of the rock types investigated is inhomgeneous and anistropic as a result of the fissured structure. (orig./HP) With 114 figs., 4 tabs

  20. Subacute fat-embolism-like syndrome following high-volume intramuscular and accidental intravascular injection of mineral oil

    DEFF Research Database (Denmark)

    Hjort, Mathias; Hoegberg, Lotte Christine Groth

    2015-01-01

    Objective. We present a rare case of subacute fat-embolism-like syndrome (FES-like) following intravascular injection of mineral oil-steroid solution with delayed diagnosis, acute onset of pulmonary distress, and transient clinical deterioration. Case report. A 40-year-old man was admitted following as a pedestrian being hit by a car. Examinations revealed sternum fracture and lung contusion. The patient was discharged with oral analgesics. Seven days later he returned presenting with coughing, hemoptysis, elevated leucocytes, and increased C-reactive protein. Chest radiograph revealed basal infiltrations. Suspecting pneumonia, the patient was discharged with antibiotics. Unkown to the clinicians, the patient had self-administered a mineral oil with added anabolic steroids by intramuscular injections for cosmetic purposes. The patient had observed blood on aspiration, and then relocated the needle before injecting 140 ml in his biceps muscle. Shortly after, the patient described near fainting and hemoptysis suggesting an accidental intravascular injection. Over the next 3 days the patient experienced increasing shortness of breath and hemoptysis. Examinations confirmed the diagnosis and the patient was treated with organ-specific supportive measures, tranexamic acid, and prednisolone and discharged after 11 days in the hospital. Conclusion. Subacute FES-like was associated with injection of body filler in muscle tissue. FES-like can mimic pneumonia, posttraumatic lung injury, and other more frequent causes to respiratory failure.

  1. Downhole oil-water separation technology : present scenario and future outlook

    Energy Technology Data Exchange (ETDEWEB)

    Anchliya, A.; Goel, P. [Indian School of Mines, Dhanbad (India)

    2006-07-01

    Technologies that can bring oil to the surface at a lower cost or with less impact on the environment are increasingly being considered by the oil and gas industry. Downhole oil water separators (DOWS) can provide a greater degree of environmental protection while reducing operating costs. The quantity of produced water that is handled at the surface is separated from the oil downhole and simultaneously injected underground with DOWS technology. DOWS technology and the benefits of DOWS are presented. The paper also addressed how DOWS has been used in the past as well as what current types of DOWS and related technology are being used by the industry. It also explained why DOWS have not been more widely used, the future outlook for DOWS technology, and the steps that DOWS developers, producers, and government must follow to expand the usage of DOWS systems. The paper concluded that failures in the past with the technology were mainly due to poor choice of candidate wells or inexperienced field staff. It was suggested that the technical staff involved in handling and installation of DOWS system should be properly trained or experienced for successful implementation of this technology. 21 refs., 4 figs.

  2. Estimation of gas/liquid and oil/water interface levels in an oil/water/gas separator based on pressure measurements and regression modelling

    OpenAIRE

    Arvoh, Benjamin Kaku; Skeie, Nils Olav; Halstensen, Maths

    2013-01-01

    Abstract Gravity separators are widely used for separation of gas/oil/water/sand from both offshore and onshore oil production facilities. Estimation of the gas/liquid and oil/water interface levels in gravity separators have been a concern since these parameters are important for reliable operation. Most of the instruments on the market today do not provide reliable measurements of both gas/liquid and oil/water interface levels. The few instruments that do provide reliable measurements ar...

  3. CO2 Injection in Hydrate Bearing Sandstone with Excess Water

    OpenAIRE

    Hågenvik, Christian

    2013-01-01

    It has previously been shown that methane can be produced from gas hydrates by exposing it to carbon dioxide. Since CO2 is the preferred hydrate former below 10 °C it will spontaneously replace CH4 as the guest molecule in the hydrate without introducing heat. This production method is beneficial because it offers long term storage of CO2 with the added benefit of produced methane without dissociating the hydrate. Previous experimental research on production from gas hydrates by CO2 inject...

  4. Enhanced Oil Recovery (EOR) by Miscible CO2 and Water Flooding of Asphaltenic and Non-Asphaltenic Oils

    OpenAIRE

    Edwin A. Chukwudeme; Aly A. Hamouda

    2009-01-01

    An EOR study has been performed applying miscible CO2 flooding and compared with that for water flooding. Three different oils are used, reference oil (n-decane), model oil (n-C10, SA, toluene and 0.35 wt % asphaltene) and crude oil (10 wt % asphaltene) obtained from the Middle East. Stearic acid (SA) is added representing a natural surfactant in oil. For the non-asphaltenic oil, miscible CO2 flooding is shown to be more favourable than that by water. However, it is interesting to see that fo...

  5. Anxiogenic Effects of Acute Injection of Sesame oil May be Mediated by ?-1 Adrenoceptors in the Basolateral Amygdala

    OpenAIRE

    Mahnaz Kesmati; Maysam Mard-Soltani; Lotfolah Khajehpour

    2013-01-01

    Purpose: A few studies have indicates that the sesame oil influences anxiety, but many reports show that ?-1 adrenoceptors (ARs) of the basolateral amygdala (BLA) plays a pivotal role in this regard. Therefore, in this study the effect of acute injection of sesame oil on anxiety-like behavior in the presence and absence of the BLA ?-1 ARs in the male Wistar rats were investigated. Methods: Guide cannulas, for seven groups of rats, were implanted bilaterally into the BLA. Two weeks after th...

  6. Cooling Effect of Water Injection on a High-Temperature Supersonic Jet

    Directory of Open Access Journals (Sweden)

    Jing Li

    2015-11-01

    Full Text Available The high temperature and high pressure supersonic jet is one of the key problems in the design of solid rocket motors. To reduce the jet temperature and noise, cooling water is typically injected into the exhaust plume. Numerical simulations for the gas-liquid multiphase flow field with mixture multiphase model were developed and a series of experiments were carried out. By introducing the energy source terms caused by the vaporization of liquid water into the energy equation, a coupling solution was developed to calculate the multiphase flow field. The temperature data predictions agreed well with the experimental results. When water was injected into the plume, the high temperature core region area was reduced, and the temperature on the head face was much lower than that without water. The relationship between the reduction of temperature on the bottom plate and the momentum ratio is developed, which can be used to predict the cooling effect of water injection in many cases.

  7. A high efficiency oxyfuel internal combustion engine cycle with water direct injection for waste heat recovery

    International Nuclear Information System (INIS)

    This paper presents a novel concept of combining water injection process with an oxyfuel internal combustion engine cycle to enhance thermal efficiency. Since the emission of NOx is eliminated by using oxygen instead of air as oxidant, the exhaust gas is CO2–water vapor mixture, and CO2 is recovered through condensation of the exhaust gas at low cost. In this way, an ultra-low emission working cycle is achieved. The evaporation of injected water not only moderates the peak in-cylinder temperature, but also increases the mass of working gas inside the cylinder, therefore improves the thermal efficiency of the cycle. An ideal thermodynamic model combining an oxyfuel Otto cycle with water injection process was established to investigate the potential of the cycle thermal efficiency. Calculation results show that thermal efficiency reaches 53% when water injection temperature is 120 °C and 67% when water injection temperature reaches 200 °C. Moreover, bench tests were carried out on prototype engine based on this working cycle. Experimental results show that the thermal efficiency improves with the increase of both engine load and water injection mass, and indicated thermal efficiency increases from 32.1% to 41.5% under appropriate test condition. - Highlights: • We present an oxy-fuel combustion cycle coupled with water injection for IC engines. • High thermo efficiency can be realized with the potential of CO2 capture. • Steam is employed as working gas of an reciprocating engine cycle. • An efficiency increase of 33% is achievable based on thermodynamic analysis. • Thermo efficiency increases from 32.1% to 41.5% through engine tests

  8. Testing research for oil-gas-water flow pattern in Daqing oilfield

    Science.gov (United States)

    Liu, Xiaoyan; Mao, Qianjun; Liu, Lijun; Xu, Ying; Chen, Wei

    2013-07-01

    During the period of the high water cut later stage, it is significant for decreasing energy consumption of gathering system to research oil-gas-water flow pattern. At the moment, the studies on oil-gas-water flow pattern are mainly focused on the temperature range of crude oil freezing point. A experimental system is designed, constructed and operated in oilfields in horizontal pipeline., which is used for experimental investigation and analysis of oil-gas-water flow pattern under freezing point in horizontal pipeline. According to the crude oil condition, the results show that oil-gas-water flow pattern includes four types that are oil contact wave flow, oil-oil particle dispersion flow, oil lamellar flow, oil puddle slugging flow.

  9. Conversion of Crude Oil to Methane by a Microbial Consortium Enriched From Oil Reservoir Production Waters

    Directory of Open Access Journals (Sweden)

    LisaGieg

    2014-05-01

    Full Text Available The methanogenic biodegradation of crude oil is an important process occurring in petroleum reservoirs and other oil-containing environments such as contaminated aquifers. In this process, syntrophic bacteria degrade hydrocarbon substrates to products such as acetate, and/or H2 and CO2 that are then used by methanogens to produce methane in a thermodynamically dependent manner. We enriched a methanogenic crude oil-degrading consortium from production waters sampled from a low temperature heavy oil reservoir. Alkylsuccinates indicative of fumarate addition to C5 and C6 n-alkanes were identified in the culture (above levels found in controls, corresponding to the detection of an alkyl succinate synthase gene (assA in the culture. In addition, the enrichment culture was tested for its ability to produce methane from residual oil in a sandstone-packed column system simulating a mature field. Methane production rates of up 5.8 ?mol CH4/g of oil/day were measured in the column system. Amounts of produced methane were in relatively good agreement with hydrocarbon loss showing depletion of more than 50% of saturate and aromatic hydrocarbons. Microbial community analysis revealed that the enrichment culture was dominated by members of the genus Smithella, Methanosaeta, and Methanoculleus. However, a shift in microbial community occurred following incubation of the enrichment in the sandstone columns. Here, Methanobacterium sp. were most abundant, as were bacterial members of the genus Pseudomonas and other known biofilm forming organisms. Our findings show that microorganisms enriched from petroleum reservoir waters can bioconvert crude oil components to methane both planktonically and in sandstone-packed columns as test systems. Further, the results suggest that different organisms may contribute to oil biodegradation within different phases (e.g., planktonic versus sessile within a subsurface crude oil reservoir.

  10. Persistence of crude oil spills on open water

    International Nuclear Information System (INIS)

    A survey of reports on oil spill incidents around the world was conducted. A Microsoft access database was then compiled in which spill information parameters were identified. These include general information about when and where the spill occurred, weather, sea conditions, oil properties and cleanup methods. The available information was assessed to determine statistically significant relationships between spill persistence, spill size and spill persistence factors. The objective was to identify links between dissipation times for spills and spill size. Another objective was to determine quantitative relationships between on-water spill persistence and associated environmental factors; physical and chemical properties of the spilled oil; and, response effort parameters. A mathematical description of the persistence of crude oil spills at sea was developed using historical spill data. The results are used by the Minerals Management Services (MMS) to estimate probable durations for spill trajectories in the MMS Oil Spill Risk Analysis for Alaska Outer Continental Shelf (OCS) waters. This study also refined the spill-size/spill-persistence correlation in terms of other variables such as oil type, weather and sea conditions and spill type. Correlation analyses were conducted on 3 data sets, indicating the importance of different variables and their dependencies. 3 refs., 8 tabs., 15 figs

  11. Enhancement of Biogenic Coalbed Methane Production and Back Injection of Coalbed Methane Co-Produced Water

    Energy Technology Data Exchange (ETDEWEB)

    Song Jin

    2007-05-31

    Biogenic methane is a common constituent in deep subsurface environments such as coalbeds and oil shale beds. Coalbed methane (CBM) makes significant contributions to world natural gas industry and CBM production continues to increase. With increasing CBM production, the production of CBM co-produced water increases, which is an environmental concern. This study investigated the feasibility in re-using CBM co-produced water and other high sodic/saline water to enhance biogenic methane production from coal and other unconventional sources, such as oil shale. Microcosms were established with the selected carbon sources which included coal, oil shale, lignite, peat, and diesel-contaminated soil. Each microcosm contained either CBM coproduced water or groundwater with various enhancement and inhibitor combinations. Results indicated that the addition of nutrients and nutrients with additional carbon can enhance biogenic methane production from coal and oil shale. Methane production from oil shale was much greater than that from coal, which is possibly due to the greater amount of available Dissolved Organic Carbon (DOC) from oil shale. Inconclusive results were observed from the other sources since the incubation period was too low. WRI is continuing studies with biogenic methane production from oil shale.

  12. Immiscible displacement of oil by water in a microchannel: asymmetric flow behavior and nonlinear stability analysis of core-annular flow.

    Science.gov (United States)

    Foroughi, Hooman; Abbasi, Alireza; Das, Kausik S; Kawaji, Masahiro

    2012-02-01

    The immiscible displacement of oil by water in a circular microchannel was investigated. A fused silica microchannel with an inner diameter of 250 ?m and a length of 7 cm was initially filled with a viscous silicone oil. Only water then was injected into the channel. We describe our flow observations based on the two-dimensional images captured in the middle of the channel. The water finger displaced the oil and left an oil film on the channel wall. While the oil was being displaced at the core, the flow resistance decreased, which resulted in increases in water flow rate and inertia. Eventually, the water finger reached the channel exit and formed a core-annular flow pattern. The wavelength of the waves formed at the oil-water interface also increased with the increase in inertia. The initially symmetric interfacial waves became asymmetric with time. Also, the water core shifted from the center of the channel and left a thinner oil film on one side of the microchannel. Under all flow rates tested in this study, as long as the water was continuously injected, the water core was stable and no breakup into droplets was observed. We also discuss the flow stability based on nonlinear and linear stability analyses performed on the core-annular flow. Compared to the linear analysis, which ignores the inertia effects, the nonlinear analysis, which includes the inertia effects, predicts longer interfacial wavelengths by a factor of 1/sqrt[1-a(o)/2(We(w) + We(o)a(o)(2)/1-a(o)(2))] where We(w) and We(o) are the Weber numbers of the water and the oil phases, respectively, and a(o) is the unperturbed water core radius made dimensionless by the channel radius. PMID:22463319

  13. Seawater injection barrier recharge with advanced reclaimed water at Llobregat delta aquifer (Spain)

    OpenAIRE

    Ortuño Gobern, Felip; Molinero Huguet, Jorge Jose; Garrido, Teresa; Custodio Gimena, Emilio

    2012-01-01

    The main aquifer of the Llobregat delta (Barcelona, Spain) has been affected by seawater intrusion since the 1960s. The Catalan Water Agency (ACA) has sponsored the construction of a positive hydraulic barrier in order to stop the progress of seawater intrusion advance due to the intensive aquifer development. The hydraulic barrier consists of 15 wells into which highly treated reclaimed water from the waste water treatment plant of the Baix Llobregat is injected. Water is subjected, prior to...

  14. Mechanics and upscaling of heavy oil bitumen recovery by steam-over-solvent injection in fractured reservoir method

    Energy Technology Data Exchange (ETDEWEB)

    Singh, R.; Badadagli, T. [University of Alberta, Edmonton, AB (Canada)

    2011-01-15

    In fractured reservoirs, heavy matrix oil recovery is a big challenge; the steam over solvent injection method was developed to enhance recovery. This method consists in three phases: steam is injected, then the solvent and finally steam again to recover more oil and retrieve the solvent. Previous studies have proved this method to be both technically feasible and economical but have not been able to determine the recovery mechanisms involved. Thus this study focused on identifying these mechanisms and efficient application conditions, using a numerical model and then performing an upscaling analysis. The results determined the asphaltene precipitation to be important to the process and showed that solvent mostly escape from the core in its gas form. In addition gravity was identified as controlling the process in the matrix and that it is enhanced by solvent diffusion. This research showed encouraging results and further studies should be undertaken to obtain a universal scaling relationship.

  15. Stabilizing oil-in-water emulsions with regenerated chitin nanofibers.

    Science.gov (United States)

    Zhang, Ying; Chen, Zhigang; Bian, Wenyang; Feng, Li; Wu, Zongwei; Wang, Peng; Zeng, Xiaoxiong; Wu, Tao

    2015-09-15

    Natural chitin is a highly crystalline biopolymer with poor aqueous solubility. Thus direct application of chitin is rather limited unless chemical modifications are made to improve its solubility in aqueous media. Through a simple dissolution and regeneration process, we have successfully prepared chitin nanofibers with diameters around 50nm, which form a stable suspension at concentrations higher than 0.50% and a self-supporting gel at concentrations higher than 1.00%. Additionally, these nanofibers can stabilize oil-in-water emulsions with oil fraction more than 0.50 at chitin usage level of 0.01g/g oil. The droplet sizes of the resulting emulsions decrease with increasing chitin concentrations and decreasing oil fraction. Confocal laser scanning micrographs demonstrate the adsorption of chitin nanofibers on the emulsion droplet surface, which indicates the emulsion stabilization is through a Pickering mechanism. Our findings allow the direct application of chitin in the food industry without chemical modifications. PMID:25863618

  16. Subacute fat-embolism-like syndrome following high-volume intramuscular and accidental intravascular injection of mineral oil

    DEFF Research Database (Denmark)

    Hjort, Mathias; Hoegberg, Lotte Christine Groth; Jansen, Tejs; Almind, Merete

    2015-01-01

    Objective. We present a rare case of subacute fat-embolism-like syndrome (FES-like) following intravascular injection of mineral oil-steroid solution with delayed diagnosis, acute onset of pulmonary distress, and transient clinical deterioration. Case report. A 40-year-old man was admitted following as a pedestrian being hit by a car. Examinations revealed sternum fracture and lung contusion. The patient was discharged with oral analgesics. Seven days later he returned presenting with coughing, ...

  17. Generation of water-in-oil and oil-in-water microdroplets in polyester-toner microfluidic devices

    OpenAIRE

    Piccin, Evandro; Ferraro, Davide; Sartori, Paolo; Chiarello, Enrico; Pierno, Matteo; Mistura, Giampaolo

    2014-01-01

    This paper demonstrates that disposable polyester-toner microfluidic devices are suitable to produce either water-in-oil (W/O) or oil-in-water (O/W) droplets without using any surface treatment of the microchannels walls. Highly monodisperse W/O and O/W emulsions were generated in T-junction microdevices by simply adding appropriate surfactants to the continuous phase. The dispersion in size of droplets generated at frequencies up to 500 Hz was always less than about 2% over...

  18. Chitosan microspheres applied for removal of oil from produced water in the oil industry

    Scientific Electronic Library Online (English)

    Izabel Cristina da Silva, Grem; Bianca Natividade Barreto, Lima; Wiliam Ferreira, Carneiro; Yure Gomes de Carvalho, Queirós; Claudia Regina Elias, Mansur.

    Full Text Available The discharge of oily wastewaters in the environment is steadily increasing, causing serious damages. Among various treatment methods, adsorption is generally considered the most appropriate, since it can remove both organic and inorganic pollutants. Adsorption using low-cost alternative biopolymers [...] for removal of contaminants from wastewater has been widely investigated. In this context, chitosan has been drawing particular attention because, among its many applications, it can be used in the treatment of aqueous effluents. In this study, microspheres were prepared by reticulation of chitosan with sodium triphosphate (STP) and studied for the treatment of water containing crude oil. The microspheres were regular and had surface pores. These microspheres were packed in treatment columns and their ability to remove oil was measured with a fluorometer, by the difference in the oil concentration before and after passing through the column. The microspheres that presented porosity about 80 % were highly efficient in oil removal, with rates above 90%.

  19. Exploring methods improving oil removal from waste waters

    Energy Technology Data Exchange (ETDEWEB)

    Boetzkaya, K.P.; Ioffe, E.M.

    1982-03-01

    This paper evaluates experiments carried out at the Zhdanov coking by-product plant involving adding synthetic aliphatic acid to waste water and using fiberglass in the filtration process. Later fiberglass is regenerated with contaminated or raw benzene. Experiment results are given in a table showing that oil removal reaches 69.3-95.8%. Residual oil content is described as a function of filtration speed and initial oil concentration. Waste water purification using fiberglass rinsed in benzene is 14.6% more effective than that using fresh fiberglass, with filtration speed increased by 45 ml/min. Fiberglass adsorption capacity remains the same whether it is regenerated with uncontaminated or already used benzene. It is concluded that using fiberglass is profitable from both financial and qualitative points of view.

  20. Determination of colloid silver in drinking water by flow injection analysis with TLS spectrometric UV detection

    International Nuclear Information System (INIS)

    In this work flow injection analysis coupled to collinear dual beam thermal lens spectrometric UV detection was used for determination of silver in water. The detection is based on the increase in absorbance resulting from the formation of colloidal elemental silver due to reduction of Ag+ after reaction with BH4-. The optimal performance of the experimental setup was achieved with 500 ?L sample injection loops or larger and the flow rate of 0.6 mL/min. The estimated limit of detection (LOD) for silver in water was 0.01 mg/L what compares favorably with the maximum contaminant level (MCL) for silver in drinking water.

  1. Massive dominance of Epsilonproteobacteria in formation waters from a Canadian oil sands reservoir containing severely biodegraded oil

    OpenAIRE

    Casey R J Hubert; Oldenburg, Thomas B P; Fustic, Milovan; Gray, Neil D; Larter, Stephen R.; Penn, Kevin; Rowan, Arlene K.; Seshadri, Rekha; Sherry, Angela; Swainsbury, Richard; Voordouw, Gerrit; Voordouw, Johanna K.; Head, Ian M.

    2012-01-01

    The subsurface microbiology of an Athabasca oil sands reservoir in western Canada containing severely biodegraded oil was investigated by combining 16S rRNA gene- and polar lipid-based analyses of reservoir formation water with geochemical analyses of the crude oil and formation water. Biomass was filtered from formation water, DNA was extracted using two different methods, and 16S rRNA gene fragments were amplified with several different primer pairs prior to cloning and sequencing or commun...

  2. Research on the performance of water-injection twin screw compressor

    International Nuclear Information System (INIS)

    Due to the development of the automotive fuel cell systems, the study on water-injection twin screw compressor has been aroused again. Twin screw compressors with water injection can be used to supply the clean compressed air for the Proton Exchange Membrane (PEM) fuel cell systems. In this research, a thermodynamic model of the working process of water-injection twin screw compressor was established based on the equations of conservation of mass and energy. The effects of internal leakage and air-water heat transfer were taken into account simultaneously in the present mathematical model. The experiments of the performance of a prototype compressor operating under various conditions were conducted to verify the model. The results show that the predictions of the model are in reasonable agreement with the experimental data.

  3. Viscosity of water-in-oil emulsions. Variation with temperature and water volume fraction

    Energy Technology Data Exchange (ETDEWEB)

    Farah, Marco A.; Caldas, Jorge Navaes [Petroleo Brasileiro S.A., Rua General Canabarro, 500, Maracana, Rio, CEP 2057-900 (Brazil); Oliveira, Roberto C. [Petroleo Brasileiro S.A., Cenpes, Cidade Universitaria (Brazil); Rajagopal, Krishnaswamy [LATCA-Laboratorio de Termodinamica e Cinetica Aplicada-Escola de Quimica, Departamento de Engenharia Quimica, Universidade Federal do Rio de Janeiro, UFRJ, Cidade Universitaria, C.P. 68452, CEP 21949-900, Rio de Janeiro (Brazil)

    2005-09-15

    Water-in-oil emulsions are important in the petroleum industry in production operations, where the water content of the emulsion can be as high as 60% in volume, also in petroleum refining operations where generally the water content is low. The effective viscosity of water-in-oil emulsions depends mainly on the volume fraction of dispersed phase and temperature, along with several minor effects, such as shear rate, average droplet size, droplet size distribution, viscosity and density of oil. Using six different crude oils, the effective viscosities of several synthetic water-in-oil emulsions are measured at atmospheric pressure using a dynamic viscosimeter for different shear rates, temperatures and volume fractions of the dispersed phase. The ASTM equation, method D-341, for describing viscosity as a function of temperature is extended to include the variation of dispersed phase volume fraction. The proposed equation gives good correlation between the measured viscosities of water-in-oil emulsions as a function of temperature and the volume fraction of water.

  4. Device for separating oil from water and solid particles

    Energy Technology Data Exchange (ETDEWEB)

    Richards, M.S.; Copeland, S.B.

    1979-08-02

    In separating oil from water and solid particles, one can achieve a considerable improvement of the well known process and devices by providing a first separation, a coalescing effect and filtration. An example of the invention is explained using several detailed drawings. The device has a hollow chamber with a sediment bowl in the bottom and a replaceable filter element.

  5. Mannans as stabilizers of oil-in-water beverage emulsions

    Science.gov (United States)

    Plant polysaccharides and gums such as gum arabic (GA) are commonly used as stabilizers of oil-in-water emulsions. O-acetyl-galactoglucomannan (GGM), a by-product from mechanical pulping of spruce wood, is able to stabilize colloidal wood resin emulsions (Hannuksela and Holmbom, 2004), but its use a...

  6. Thermodynamic behavior of nitrogen gas used in pressurized water reactor boron injection tanks

    International Nuclear Information System (INIS)

    The boron injection tank (BIT) of a pressurized water reactor safety system is filled with borated water and pressurized by a nitrogen blanket. Accurate evaluation of the gas polytropic index (n) during the injection process is important to assure required flow from such tanks. An experimental setup simulating a typical BIT system was built and used to evaluate n of the gas under different test conditions. When the N2 regulator valve was left open, n at the end of the injection process was much lower than 1.0. For the conservative situation with a closed N2 regulator valve, however, n was close to 1.0 under all test conditions. Test duration, which was a strong function of initial gas properties and gas expansion rate, had a noticeable effect on n at the endpoint. Although heat transfer from tank walls had a minor effec at the endpoint, its effect on n after time t from starting injection was noticeable

  7. Construction of a Direct Water-Injected Two-Stroke Engine for Phased Direct Fuel Injection-High Pressure Charging Investigations

    Science.gov (United States)

    Somsel, James P.

    1998-01-01

    The development of a water injected Orbital Combustion Process (OCP) engine was conducted to assess the viability of using the powerplant for high altitude NASA aircraft and General Aviation (GA) applications. An OCP direct fuel injected, 1.2 liter, three cylinder, two-stroke engine has been enhanced to independently inject water directly into the combustion chamber. The engine currently demonstrates low brake specific fuel consumption capability and an excellent power to weight ratio. With direct water injection, significant improvements can be made to engine power, to knock limits/ignition advance timing, and to engine NO(x) emissions. The principal aim of the testing was to validate a cyclic model developed by the Systems Analysis Branch at NASA Ames Research Center. The work is a continuation of Ames' investigations into a Phased Direct Fuel Injection Engine with High Pressure Charging (PDFI-ITPC).

  8. The estimation of oil water displacement functions

    Scientific Electronic Library Online (English)

    G. B., Savioli; E. M., Fernández-Berdaguer.

    2007-09-01

    Full Text Available We introduce an algorithm to solve an inverse problem for a non-linear hyperbolic partial differential equation. It can be used to estimate the oil-fractional flow function from the Buckley-Leverett equation. The direct model is non-linear: the sought for parameter is a function of the solution of t [...] he equation. Traditionally, the estimation of functions requires the election of a fitting parametric model. The algorithm that we develop does not require a predetermined parameter model. Therefore, the estimation problem is carried out over a set of parameters which are functions. The parameter is inferred from measurements of saturation at different spatial points as a function of time. The estimation procedure is carried out linearizing the solution of the direct model with respect to the parameter and then computing the least-squares solution in functional spaces. The sensitivity equations are derived. We test the algorithm with several numerical experiments.

  9. An X-ray Scattering Study of Water-Conditioned Injection- Molded Starch during Isothermal Heating

    OpenAIRE

    Cagiao, M.E.; Bayer, R. K.; Rueda, D. R.; Baltá Calleja, F. J.

    2003-01-01

    The in situ structure variation of injection molded starch (as processed and after water conditioning)during heat treatment was investigated by means of wideangle X-ray scattering using synchrotron radiation. Results confirm that the crystal structure of potato starch is destroyed after injection molding, while as-processed corn starch preserves some degree of crystallinity. This residual crystallinity in corn starch is related to the crystalline Vh form,made of complexes of amylose with l...

  10. Management of Water for Unconventional Oil and Gas Operations Enhanced with the Expanded U.S.Geological Survey Produced Waters Geochemical Database

    Science.gov (United States)

    Gans, K. D.; Blondes, M. S.; Thordsen, J. J.; Thomas, B.; Reidy, M. E.; Engle, M.; Kharaka, Y. K.; Rowan, E. L.

    2014-12-01

    Increases in hydraulic fracturing practices for shale gas and tight oil reservoirs have dramatically increased petroleum production in the USA, but have also made the issue of water management from these operations a high priority. Hydraulic fracturing requires ~ 10,000 to 50,000 m3 of water per well for injection in addition to water used to drill the well. Initially much of the water used for hydraulic fracturing was fresh water, but attitudes and operations are changing in response to costs and concerns. Concerns about groundwater depletion and contamination have prompted operators to increase the amount of produced water that can be recycled for hydraulic fracturing and to find suitable locations for salt-water injection. Knowledge of the geochemistry of produced waters is valuable in determining the feasibility of produced water recycling. Water with low salinity can be reclaimed for use outside of the petroleum industry (e.g. irrigation, municipal uses, and industrial operations). The updated and expanded USGS Produced Waters Database available at http://eerscmap.usgs.gov/pwapp/ will facilitate and enhance studies on management of water, including produced water, for unconventional oil and gas drilling and production. The USGS database contains > 160,000 samples. Expanding on the 2002 database, we have filled in state and regional gaps with information from conventional and unconventional wells and have increased the number of constituents to include minor and trace chemicals, isotopes, and time series data. We currently have produced water data from 5,200 tight gas wells, 4,500 coal-bed methane (CBM) wells, 3,500 shale gas wells, and 700 tight oil wells. These numbers will increase as we continue to receive positive responses from oil companies, state oil and gas commissions, and scientists wanting to contribute their data. This database is an important resource for a wide range of interested parties. Scientists from universities, government agencies, public municipalities and citizens can determine the geochemical nature of deep groundwater supplies, contamination sources, and impacts of hydraulic fracturing. Energy companies can utilize the database for determining the suitability of water reuse and for identifying regions where non-potable hydraulic fracturing water may be obtainable.

  11. Optimization of planetary cooler operation by accurately controlled injection of water. Optimierung des Satellitenkuehlerbetriebs durch gezielte Einduesung von Wasser

    Energy Technology Data Exchange (ETDEWEB)

    Schuermann, W.; Scheuer, A.; Sylla, H.M. (Forschungsinstitut der Zementindustrie, Duesseldorf (Germany))

    1991-08-01

    The cold clinker temperature in a rotary kiln system with planetary cooler was lowered by up to 60 K by injecting water into the cooling tubes. This required 31 g water per kg clinker. There was no increase in fuel energy consumption. The differences between the shell temperatures of the individual cooling tubes were also reduced by using a injection of water adapted to suit the different clinker mass flows in the tubes. This accurately controlled injection also permitted the quantity of water injected to be increased significantly without producing any wet clinker. The quantity of water was controlled by shell temperature measurement and a process computer. (orig.).

  12. Oil spill clean-up system using hot water

    International Nuclear Information System (INIS)

    The process of hot water extraction of tar sand was modified and adapted for removal of heavy oil from bottom tank petroleum sludges, and was submitted to a laboratory feasibility study. This process can also be utilized to clean beach sands contaminated by accidental heavy oil spills. The process mainly consists of a hot-water extraction (digestion), extruding the oil particles from their support of sand or clay. In the case of oil contaminated sands, a single stage extraction yielded a total recovery of hydrocarbons of 99% and a clean sand (hardly containing 0.1% of hydrocarbons), thus safe to be returned to the environment. In the case of heavy oil from bottom tank petroleum sludges, it was necessary to proceed with a double stage extraction with the addition of wetting agents: the utilization of Na2SiO3 aqueous solution of 1% in weight was proven efficient, allowing a 82% recovery of hydrocarbons, with only 0.5% hydrocarbons in the solid residues. 21 refs., 8 figs., 4 tabs

  13. A study of water-in-oil emulsification

    International Nuclear Information System (INIS)

    The basic mechanisms by which asphaltenes, resins, and waxes stabilize water-in-oil emulsions are examined. Experiments were conducted on the emulsification behavior of model oils which consisted of an alkane component, an aromatic component, and the emulsifying agents. Results from this study clearly demonstrate the importance that the physical state of an emulsifying agent has upon its ability to stabilize emulsions. It was found that to be effective emulsifiers, asphaltenes, resins, and waxes must be in the form of sub-micron particles. In addition, it was shown that the solvency strength of an oil, which is determined by its alkane and aromatic components, controls the solubility/precipitation behavior of these emulsifiers. The chemical composition of the oil determines not only the amount and size of precipitated particles, but also the composition and wetting properties of the particles. All these factors were found to have an influence upon emulsification. The potential application of a solubility model, using the Hildebrand-Scatchard equation, to predict the physicochemical conditions which favor water-in-oil emulsification, is discussed. Theories on various emulsification processes are also discussed in terms of mousse formation at sea. 52 refs., 46 figs., 1 tab

  14. INFLUENCE OF INJECTION TIMING ON EMISSION ANALYSIS OF A DI ENGINE RUNNING ON RUBBER SEED AND JATROPHA OIL FUELLED WITH DIESEL FUEL

    OpenAIRE

    S. Mahalingam; B. R. RameshBapu

    2014-01-01

    The petroleum fuels availability and cost concerns the nonedible oils used as raw materials can be obtained from different oil crops that may be used to reduce the environmental pollution.In the development of alternative, biodegradable, and renewable fuels used forinternal combustion (IC) engines to obtain the power. Therefore, in this present study, in?uence of fuel injection timing on the exhaust emission of a single cylinder, four stroke, and direct injection(DI) diesel en...

  15. In situ water and gas injection experiments performed in the Hades Underground Research Facility

    International Nuclear Information System (INIS)

    The movement of water and gas through plastic clay is an important subject in the research at SCK-CEN on the possible disposal of high level radioactive waste in the Boom clay layer at Mol. Since the construction of the Hades underground research facility in 1983, SCK-CEN has developed and installed numerous piezometers for the geohydrologic characterization and for in situ radionuclide migration experiments. In situ gas and water injection experiments have been performed at two different locations in the underground laboratory. The first location is a multi filter piezometer installed vertically at the bottom of the shaft in 1986. The second location is a three dimensional configuration of four horizontal multi piezometers installed from the gallery. This piezometer configuration was designed for the MEGAS (Modelling and Experiments on GAS migration through argillaceous rocks) project and installed in 1992. It contains 29 filters at distances between 10 m and 15 m from the gallery in the clay. Gas injection experiments show that gas breakthrough occurs at a gas overpressure of about 0.6 MPa. The breakthrough occurs by the creation of gas pathways along the direction of lowest resistance i.e. the zone of low effective stress resulting from the drilling of the borehole. The water injections performed in a filter -- not used for gas injection -- show that the flow of water is also influenced by the mechanical stress conditions. Low effective stress leads to higher hydraulic conductivity. However, water overpressures up to 1.3 MPa did not cause hydrofracturing. Water injections performed in a filter previously used for gas injections, show that the occluded gas hinders the water flow and reduces the hydraulic conductivity by a factor two

  16. Influence of pumpkin seed oil in continuous phase on droplet size and stability of water-in-oil emulsions

    Directory of Open Access Journals (Sweden)

    Nikolovski Branislava G.

    2011-01-01

    Full Text Available The aim of this work was to contribute to the optimized production of water-in-oil emulsions with pumpkin seed oil in the oil phase using a high-speed homogenizer. Pumpkin seed oil is a valuable natural source of essential fatty acids and biologically active micronutrients that contribute to its nutritive value and medical uses, and reduce interfacial tension between water and the oil phases. Therefore, pumpkin seed oil can be considered as a prosperous oil phase whose use can possibly decrease the amount of some emulsifier that is normally involved in every emulsification process. A central composite rotatable experimental design was implemented to analyze the impact of the contents of polyglycerol polyricinoleate and pumpkin seed oil in the continuous phase, as well as water phase content in the emulsion on droplet size distribution and the response surface methodology was used to obtain optimal conditions for water-in-oil emulsion preparation. Mean size diameter of water droplets was in a range from 400 to 850 nm, with mean peak width of 100 to 220 nm, respectively. The influence of all three investigated factors on the emulsification was determined. Additionally, the emulsions prepared with pumpkin seed oil showed a higher stability during the storage time compared to the emulsions with sunflower oil.

  17. Water Pollution, and Treatments Part III: Biodegradation of Oil in Refineries Waste Water and Oils Adsorbed in Agricultural Wastes by Selected Strains of Cyanobacteria

    International Nuclear Information System (INIS)

    The main objective of this study is to determine the biological degradation of oil hydrocarbons and sulfur compounds of Marine Balayim crude oil and its refined products by selected indigenous Cyanobacteria strains. The oils used were Marine Balayim crude oil, skimmed oil and some refined products such as gasoline, kerosene, gas oil, fuel oil and petroleum coke. The selected organisms in the current study are the Blue-Green Algae Cyanobacteria, Oscillatoria limentica. This organism was collected from the hyper saline environment of the solar lake in Taba, Sinai, Egypt. The results obtained revealed that the utilization of such strains can be used for the bioremediation of oily waste water.

  18. Transfer of orlistat through oil-water interfaces.

    Science.gov (United States)

    Tiss, Ali; Lengsfeld, Hans; Hadváry, Paul; Cagna, Alain; Verger, Robert

    2002-10-01

    The transfer of radiolabelled orlistat ([14C]orlistat), a potent gastrointestinal lipase inhibitor, through an oil-water interface from a single oil droplet to an aqueous phase was investigated, using an oil drop tensiometer. The absolute transfer fluxes were found to be very low, even in the presence of micellar concentrations of bile salts, which increased their values from 0.2 to 2.5 and 6.5 pmol cm(-2) min(-1) in the presence of 0, 4 and 15 mM NaTDC, respectively. Adding either a lipid emulsion or pure human pancreatic lipase (HPL) or human serum albumin or beta-lactoglobulin had no effect on the flux of transfer of orlistat. The presence of colipase or a mixture of colipase and HPL was found, however, to reduce the flux of orlistat transfer, probably because it partly covered the single oil drop surface, even in the presence of bile salts. Using a finely emulsified system, we investigated the partitioning of orlistat between the aqueous and oil phases, in the absence or presence of bile salts above their CMC (4 mM NaTDC, final concentration). Under these emulsified conditions, orlistat was found to be mostly associated with the oil phase, since more than 98.8% of the total radioactivity was recovered after decantation with the oil phase. The low transfer rates of orlistat, as well as its partitioning coefficient between the oil and the aqueous phases, should help us to better understand the inhibitory effects of orlistat on lipid digestion in humans. PMID:12270672

  19. Fault Diagnosis Of A Water For Injection System Using Enhanced Structural Isolation

    DEFF Research Database (Denmark)

    Laursen, Morten; Blanke, Mogens; Düstegör, Dilek

    2008-01-01

    A water for injection system supplies chilled sterile water as solvent to pharmaceutical products. There are ultimate requirements to the quality of the sterile water, and the consequence of a fault in temperature or in flow control within the process may cause loss of one or more batches of the production. Early diagnosis of faults is hence of considerable interest for this process. This study investigates the properties of multiple matchings with respect to isolability and it suggests to explo...

  20. Bacterial motility near crude oil and water interface

    Science.gov (United States)

    Rodríguez, Jomayra E. Sánchez; Molaei, Mehdi; Sheng, Jian

    2013-11-01

    Study of biodegradation of crude oil by microbes requires profound understanding of their movement near oil-water interface as well as in/out of phase movement. Bacterial motilities are known to be modified by the presence of an interface through hydrodynamic interactions in addition to the chemotactic behavior towards the oil phase. Using digital holographic microscopy and phase contrast microscopy, we study locomotion of Pseudomonas sp (P62), a well-known hydrocarbon degrader under various chemo- and mechano-environmental conditions. Baseline experiments have been performed at different nutrient levels and Ion levels to identify effects of chemical environment on cell motility. Utilizing novel microfluidics and surface functionalization, we have established a stable vertical oil-water interface between top and bottom surfaces of the microfluidics, which allow clear optical access to observe bacterial movement near the interface. Three-dimensional trajectories of bacteria, obtained by analyzing recorded by digital holography microscopy, enable us to characterize bacterial swimming and orientation near interfaces. Chemotaxis velocity and swimming induced dispersion are measured directly as well as cell concentration distributions with respect to the distance to the interface. Study of biodegradation of crude oil by microbes requires profound understanding of their movement near oil-water interface as well as in/out of phase movement. Bacterial motilities are known to be modified by the presence of an interface through hydrodynamic interactions in addition to the chemotactic behavior towards the oil phase. Using digital holographic microscopy and phase contrast microscopy, we study locomotion of Pseudomonas sp (P62), a well-known hydrocarbon degrader under various chemo- and mechano-environmental conditions. Baseline experiments have been performed at different nutrient levels and Ion levels to identify effects of chemical environment on cell motility. Utilizing novel microfluidics and surface functionalization, we have established a stable vertical oil-water interface between top and bottom surfaces of the microfluidics, which allow clear optical access to observe bacterial movement near the interface. Three-dimensional trajectories of bacteria, obtained by analyzing recorded by digital holography microscopy, enable us to characterize bacterial swimming and orientation near interfaces. Chemotaxis velocity and swimming induced dispersion are measured directly as well as cell concentration distributions with respect to the distance to the interface. NIH, NSF, GoMRI.

  1. Heat pump system utilizing produced water in oil fields

    International Nuclear Information System (INIS)

    As the alternative to the heating furnace for crude oil heating, a heat pump system utilizing produced water, a main byproduct, in oil fields was proposed and the thermodynamic model of the system was established. A particular compression process with inner evaporative spray water cooling was applied in the screw compressor and an analysis method for the variable-mass compression process was introduced. The simulation results showed that the efficiency of the screw compressor, the temperature of produced water and the temperature difference in flash process are key parameters affecting the system performance. The energy cost of the heat pump system was compared to that of the heating furnace, revealing that the heat pump system with EER, 4.67, would save over 20% energy cost as compared with the heating furnace. Thus, the heat pump system was energy saving, money saving and environmentally benign

  2. Electrolytic separation of tars and oils from waste water

    Energy Technology Data Exchange (ETDEWEB)

    Filonenko, Yu.Ya.; Konev, N.L.; Rzhavichev, S.P.; Myachin, G.V.; Sobolev, S.Ya.; Kuznetsov, V.Ya.; Ivantsov, V.A.

    1991-08-01

    Discusses the feasibility of separating oils and tars from coking waste-water using electrocoagulation. Soluble electrodes made of St3 steel were used. Waste water was treated by flotation (by hydrogen bubbles evolving from a cathode) as well as coagulation (by ions of iron Fe{sup 2+}) formed during catalytic dissolution of an anode. Efficiency of oil and tar separation from waste water using electrocoagulation was tested under laboratory conditions: voltage 15 V, current 62.2. A, current density 1,666.7 A/m{sup 2}, four 11x11 cm electrodes situated at intervals of 3 mm, volume of an electrolyzer 4.42 l, electrolysis time 15 s, output 1.0 m{sup 3}/h. Energy consumption was 1.25 kWxh/m{sup 3}. 3 refs.

  3. A water-in-oil emulsion containing Kelex-100 for the speciation analysis of trace heavy metals in water

    International Nuclear Information System (INIS)

    A water-in-oil (w/o) emulsion containing Kelex-100 (7-dodecenyl-8-quinolinol) and Span-80 (sorbitan monooleate, non-ionic surfactant) was ultrasonically prepared from 1.0 mol l-1 hydrochloric acid and a (1 + 3) mixture of toluene and n-heptane. The resulting emulsion was gradually injected into water sample and dispersed as numerous tiny globules (0.01-0.1 mm in diameter). Dissolved inorganic species (free metal species) of heavy metals (e.g., Fe, Co, Cu, Cd, and Pb) were selectively transported through the oil layer into the internal aqueous phase of the emulsion, leaving other species, such as humic complexes and suspended particles (larger than 1 ?m), in the sample solution. After collecting the dispersed emulsion globules, they were demulsified and the heavy metals in the segregated aqueous phase were determined by graphite-furnace atomic absorption spectrometry. The emulsion-based separation method allowed the selective collection of free metal species with a high concentration factor of 100, whereas the conventional solvent extraction did not offer such discrimination. This unique property of the emulsion method was successfully applied to the selective determination of free species of heavy metals in fresh water samples

  4. Purification of trona ores by conditioning with an oil-in-water emulsion

    Science.gov (United States)

    Miller, J. D. (Salt Lake City, UT); Wang, Xuming (Salt Lake City, UT); Li, Minhua (Salt Lake City, UT)

    2009-04-14

    The present invention is a trona concentrate and a process for floating gangue material from trona ore that comprises forming an emulsion, conditioning the trona ore at a high solids content in a saturated trona suspension, and then floating and removing the gangue material. The process for separating trona from gangue materials in trona ore can include emulsifying an oil in an aqueous solution to form an oil-in-water emulsion. A saturated trona suspension having a high solids content can also be formed having trona of a desired particle size. The undissolved trona in the saturated suspension can be conditioned by mixing the saturated suspension and the oil-in-water emulsion to form a conditioning solid suspension of trona and gangue material. A gas can be injected through the conditioning solid suspension to float the gangue material. Thus, the floated gangue material can be readily separated from the trona to form a purified trona concentrate without requirements of additional heat or other expensive processing steps.

  5. Analysis of method of polarization surveying of water surface oil pollution

    Science.gov (United States)

    Zhukov, B. S.

    1979-01-01

    A method of polarization surveying of oil films on the water surface is analyzed. Model calculations of contrasted oil and water obtained with different orientations of the analyzer are discussed. The model depends on the spectral range, water transparency and oil film, and the selection of observational direction.

  6. 33 CFR 157.33 - Water ballast in fuel oil tanks.

    Science.gov (United States)

    2010-07-01

    ...2010-07-01 2010-07-01 false Water ballast in fuel oil tanks. 157.33 Section...Vessel Operation § 157.33 Water ballast in fuel oil tanks. A new vessel may not carry ballast water in a fuel oil tank. [CGD...

  7. Performance Characteristics and Analysis of 4-Stroke Single Cylinder Diesel Engine Blend With 50% of Honne Oil at Various Fuel Injection Pressures

    Directory of Open Access Journals (Sweden)

    R. Bhaskar Reddy

    2014-08-01

    Full Text Available In future demand for fossil fuels and environmental effects, a number of renewable sources of energy have been studied in worldwide. An attempt is made to apt of vegetable oil for diesel engine operation, without any change in its old construction. One of the important factors which influence the performance and emission characteristics of D.I diesel engine is fuel injection pressure. In this project honne oil has to be investigated in a constant speed, on D.I diesel engine with different fuel injection pressures. The scope of the project is to investigate the effect of injection pressures on a blend of 50% honne oil with 50% diesel and compare with pure diesel on performance and emission characteristics of the diesel engine. Two tested fuels were used during experiments like 100 % diesel and a blend of 50% honne oil mixing in the diesel. The performance tests were conducted at constant speed with variable loads. From experiment results it was found that with honne oil- diesel blend the performance of the engine is better compared with diesel. The break thermal efficiency and mechanical efficiencies were found to be maximum at 200 bar injection pressure with both honne oil- diesel blend, compared with 180 bar and 220 bar. The brake specific fuel consumption was to be minimum at 220bar compared with 180 bar and 200 bar. Hydro carbon emissions of honne oil-diesel operation were less than the diesel fuel mode at all fuel injection pressures.

  8. Water injection into vapor- and liquid-dominated reservoirs: Modeling of heat transfer and mass transport

    Energy Technology Data Exchange (ETDEWEB)

    Pruess, K.; Oldenburg, C.; Moridis, G.; Finsterle, S. [Lawrence Berkeley National Lab., CA (United States)

    1997-12-31

    This paper summarizes recent advances in methods for simulating water and tracer injection, and presents illustrative applications to liquid- and vapor-dominated geothermal reservoirs. High-resolution simulations of water injection into heterogeneous, vertical fractures in superheated vapor zones were performed. Injected water was found to move in dendritic patterns, and to experience stronger lateral flow effects than predicted from homogeneous medium models. Higher-order differencing methods were applied to modeling water and tracer injection into liquid-dominated systems. Conventional upstream weighting techniques were shown to be adequate for predicting the migration of thermal fronts, while higher-order methods give far better accuracy for tracer transport. A new fluid property module for the TOUGH2 simulator is described which allows a more accurate description of geofluids, and includes mineral dissolution and precipitation effects with associated porosity and permeability change. Comparisons between numerical simulation predictions and data for laboratory and field injection experiments are summarized. Enhanced simulation capabilities include a new linear solver package for TOUGH2, and inverse modeling techniques for automatic history matching and optimization.

  9. Rapid and non-destructive identification of water-injected beef samples using multispectral imaging analysis.

    Science.gov (United States)

    Liu, Jinxia; Cao, Yue; Wang, Qiu; Pan, Wenjuan; Ma, Fei; Liu, Changhong; Chen, Wei; Yang, Jianbo; Zheng, Lei

    2016-01-01

    Water-injected beef has aroused public concern as a major food-safety issue in meat products. In the study, the potential of multispectral imaging analysis in the visible and near-infrared (405-970 nm) regions was evaluated for identifying water-injected beef. A multispectral vision system was used to acquire images of beef injected with up to 21% content of water, and partial least squares regression (PLSR) algorithm was employed to establish prediction model, leading to quantitative estimations of actual water increase with a correlation coefficient (r) of 0.923. Subsequently, an optimized model was achieved by integrating spectral data with feature information extracted from ordinary RGB data, yielding better predictions (r = 0.946). Moreover, the prediction equation was transferred to each pixel within the images for visualizing the distribution of actual water increase. These results demonstrate the capability of multispectral imaging technology as a rapid and non-destructive tool for the identification of water-injected beef. PMID:26213059

  10. Determination of nitrate in water by flow-injection analysis.

    Czech Academy of Sciences Publication Activity Database

    Mikuška, Pavel; Ve?e?a, Zbyn?k

    2001-01-01

    Ro?. 8, ?. 1 (2001), s. 115-120. ISSN 1231-7098 R&D Projects: GA ?R GA203/98/0943 Grant ostatní: COPERNICUS(BE) SUB-AERO EVK2-1999-000327 Institutional research plan: CEZ:AV0Z4031919 Keywords : nitrate * chemiluminescence * water Subject RIV: CB - Analytical Chemistry, Separation

  11. Preserving drinking water quality in geotechnical operations: predicting the feedback between fluid injection, fluid flow, and contamination

    Science.gov (United States)

    Schilling, Frank R.

    2014-05-01

    Not only in densely populated areas the preservation of drinking water quality is of vital interest. On the other side, our modern economies request for a sustained energy supply and a secure storage of waste materials. As energy sources with a high security of supply, oil, natural gas, and geothermal energy cover ca. 60% of Europe's energy demand; together with coal more than 75% (IEA 2011). Besides geothermal energy, all of the resources have a high greenhouse gas footprint. All these production activities are related to fluid injection and/or fluid production. The same holds true for gas storage operations in porous reservoirs, to store natural gases, oil, or greenhouse gases. Different concerns are discussed in the public and geoscientific community to influence the drinking water quality: - wastewater discharges from field exploration, drilling, production, well treatment and completion - wastewater sequestration - gas storage - tight gas and tight oil production (including hydraulic fracturing) - Shale gas production (including hydraulic fracturing) - mine drainage This overview contribution focusses on strategies to systematically reduce the risk of water pollution in geotechnical operations of deep reservoirs. The principals will be exemplarily revealed for different geotechnical operations. - How to control hydraulic fracturing operations to reduce the risk of enhanced seismic activity and avoiding the connection of originally separated aquifers. The presented approach to quantitatively predict the impact of stimulation activities is based on petrophysical models taking the feedback of geomechanical processes and fluid flow in porous media, fissures and faults into account. The specific flow patterns in various rock types lead to distinguished differences in operational risk. - How can a proper planning of geotechnical operations reduce the involved risks. A systematic risk reduction strategy will be discussed. On selected samples the role of exploration, operation, monitoring, and proper abandonment will be presented. - Which critical parameters can be monitored? The chances and limitation of different monitoring technologies will be discoursed for a storage site. - How can public involvement reduce risks? This will be shown for hydraulic fracturing operations. - How can geotechnical operation reduce the risk for the groundwater and environment? Some examples will be given to show, that geotechnical operations have the inherent capability to enhance the security of our drinking water. The presentation will discuss how the use of underlying physical and chemical principles can significantly reduce geotechnical risks during fluid injection.

  12. Treatment of produced water by means of a new technology (MDIF): application for waters containing oil at low concentrations; Tratamento de aguas produzidas por meio de nova tecnologia (MDIF): aplicacao para aguas contendo baixas concentracoes em oleo

    Energy Technology Data Exchange (ETDEWEB)

    Fernandes Junior, Wilaci Eutropio [PETROBRAS S.A., Mossoro, RN (Brazil). Unidade de Negocio de Exploracao e Producao. Ativo de Producao Mossoro]. E-mail: wilaci@petrobras.com.br; Paulo, Joao Bosco de Araujo; Moraes, Norberto Araujo de Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil). Programa de Pos-graduacao em Engenharia Quimica). E-mails: jbosco@eq.ufrn.br; norberto@eq.ufrn.br; Lima, Antonio Faria; Lacerda, Geraldo de Moura [PETROBRAS S.A., Natal, RN (Brazil). Unidade de Negocio de Exploracao e Producao. Gerencia de Engenharia de Instalacoes, Processamento e Automacao]. E-mails: farialima@petrobras.com.br; geraldoml@petrobras.com.br

    2006-12-15

    The production of oil is associated with waters which exist naturally at the reservoirs or were injected into wells. These waters, named produced waters, contain beside free oil, emulsioned or micro-emulsioned oil which can not be discharged directly at the environment. The conventional decanters are not efficient to separate this kind of oil dispersed as fine droplets. In this case, a promising alternative to solve the problem of oil/water separation is accomplished by means of the phase inversion method. This method is the basis of working of a new model of mixer-settler which has a vertical disposition and occupies a small surface area. The last characteristic becomes especially important when exist a limitation of place, for example, over the maritime platforms to explore oil. The device of laboratory of the equipment named MDIF (mixer-settler based on phase inversion) has been efficient for treat waters containing up to 2 000 mg/L of emulsioned oil. This equipment on a semi-industrial scale was installed in the entrance of oil/water separator (OWS) from effluent treatment plant from Guamare, Rio Grande do Norte (ETP/GMR) and treats produced waters contaminated with oil at low concentrations (ranging from 30 to 150 mg/L) and throughputs of 320 m3/d (47,4 m3 m-2 h-1). Good results were obtained on oil/water separation which leads to the necessary specification to discharge waters. Besides, the non dependence of the efficiency of separation in the face of the salinity of the medium becomes the equipment a new technology to treat wastewaters containing oil at low concentrations. In this condition conventional equipment do not present a good efficiency of separation, till dispersed droplets are very small (less than 100 {mu}m) requiring a long time of sedimentation. (author)

  13. Mechanisms behind injecting the combination of nano-clay particles and polymer solution for enhanced oil recovery

    Science.gov (United States)

    Khalili Nezhad, Seyyed Shahram; Cheraghian, Goshtasp

    2015-09-01

    Laboratory investigations and field applications have proved injection of polymer solution to be an effective means to improve oil recovery for reservoirs of medium oil viscosity. The incremental oil produced in this case is the result of an increase in areal and vertical sweep efficiencies. Biopolymers and synthetic polymers are the major categories used in the petroleum industry for specific reasons. Biopolymers like xanthan are limited in their application as they are more susceptible to biodegradation. Synthetic polymers like Hydrolyzed PolyAcrylaMide (HPAM) have a much wider application as they are less susceptible to biodegradation. Furthermore, development of nanotechnology has successfully provided technical and economical viable alternatives for present materials. The objective of this study is to investigate the effect of combining clay nanoparticles with polymer solution on oil recovery. This paper includes a history match of both one-dimensional and two-dimensional polymer floods using a three-dimensional numerical model for fluid flow and mass transport. Results indicated that the amount of polymer adsorption decreased when clay nanoparticles were added to the PolyAcrylaMide solution; however, mobility ratio improvement is believed to be the main contributor for the proposed method in order to enhance much oil recovery compared to xanthan flood and HPAM flood.

  14. Study on Technical Measures of Romashkino Oil Field after Entering Ultra-High Water Cut Stage

    OpenAIRE

    Liuli Lu; Zhibin Liu; Haohan Liu; Yongqin Yan

    2013-01-01

    Romashkino oil field has large oilfield area, small formation dip, many reservoir layers, wide oil-water transition zone and complicated sedimentary environment. Since development, 3 overall development plannings and adjustments of individual block have been established. This achieves a high oil production. However, the recoverable reserves of major oil layer with high production become smaller and smaller and the water cut increases over time, the production ability of oil layer decreases. ...

  15. The risk of surface water contamination by oil products

    Directory of Open Access Journals (Sweden)

    Samešová Dagmar

    2013-01-01

    Full Text Available The aim of this paper is to assess the surface water contamination by oil substances in forest. The usage of forest mechanisms for felling, loading, and wood transportation belong to the activities which affect small but long-term natural environment contamination caused by mineral oil substances. These substances impact negatively on all components of the forest ecosystem. The oil substances were determined as non-polar extractable substances (NES by spectrophotometric method in infrared spectrum. The progress of NES concentrations and harvest intensity in all sampled locations shows evident connection with harvest intensity and season of the year. We tested biodegradability of selected petroleum products for better understanding the interaction of hydrocarbons in forest ecosystem.

  16. Coupled Flow and Geomechanical Modeling of Fluid Production and Injection in the Cavone Oil Field, Northern Italy: an Assessment of the Potential for Induced Seismicity

    Science.gov (United States)

    Jha, B.; Plesch, A.; Shaw, J. H.; Hager, B. H.; Juanes, R.

    2014-12-01

    There has been a recent increase in the number of earthquakes reported in proximity of active oil and gas fields. In particular, the occurrence of a sequence of damaging earthquakes in May 2012 near the Cavone oil field, in Northern Italy, raised the question of whether these earthquakes might have been triggered, or, if not, if future activities might trigger other damaging events. Production and injection of fluids in the underground reservoirs are known to be capable of triggering seismicity by inducing slip on seismogenic faults. However, the effects of injection and production on fault stability in real fields are not always intuitively obvious, and require the development of new-generation coupled flow-geomechanical models that capture the effect of multiphase poromechanics on faults. We study, by way of numerical modeling and simulation, the potential for induced seismicity at the Cavone field. Using a coupled flow and geomechanics model of the field that honors reservoir geology and historical well schedule, we simulate oil production and water injection in the field for a period of three decades leading up to the earthquake sequence. We calculate the change in Coulomb stress on the bounding Mirandola fault, which sourced the May 29, 2012 M 5.8 earthquake. This quantity varies in space and evolves in time with changing pore pressure and total stress in the reservoir. A novel and important aspect of our work is the identification of a potential instability mechanism for a bounding fault at the edge of a reservoir experiencing pressure depletion. The discontinuity in pore pressure across the fault means that there is a discontinuity in effective normal stress and that, therefore, the Coulomb failure criterion must be evaluated locally on both sides of the fault. We track the evolution of the Coulomb stress at the earthquake hypocenter and compare it with the regional tectonic stressing rate to conclude in favor of tectonic origin of the earthquake. In addition, analysis of the locations of aftershocks of the May 2012 sequence shows a lack of seismicity in the area where the stressing rates from contraction of the reservoir are largest. This observed lack of seismic activity within 1-2 km from the reservoir suggests that fluid production and injection from the Cavone field was not an important driver for the observed seismicity.

  17. Petrophysical and rock-mechanics effects of CO2 injection for enhanced oil recovery : Experimental study on chalk from South Arne field, North Sea

    DEFF Research Database (Denmark)

    Alam, Mohammad Monzurul; Hjuler, Morten Leth

    2014-01-01

    Enhanced oil recovery by CO2 injection (CO2-EOR) is a tertiary oil recovery process which has a prospective for being used, at the same time, as an effective technique for carbon dioxide storage. There is a huge potential for additional oil production and CO2 storage in the North Sea depleted chalk reservoirs. North Sea chalk is characterized by high porosity but also high specific surface causing low permeability. A high porosity provides room for CO2 storage, while a high specific surface causes a high risk for chemical reaction and consequently for mechanical weakening. In order to address this issue we studied two types of chalk from South Arne field, North Sea: (1) Ekofisk Formation having >12% non-carbonate and (2) Tor Formation, which has less than 5% non-carbonate. We performed a series of laboratory experiments to reveal the changes in petrophysical and rock-mechanics properties due to the injection of CO2 at supercritical state. We analyzed these changes with respect to the differences in porosity, specific surface, pore stiffness, wettability, mineralogy and mechanical strength. We observed a 2–3% increase in porosity, a minor decrease of specific surface and consequently a small increase in permeability. A decrease in elastic stiffness is indicated by an increase of Biot?s effective stress coefficient (?) by 1–2%. Nuclear Magnetic Resonance (NMR) data indicated no change in wettability and the samples remained water wet. We found that the effect of CO2 injection on both petrophysical and mechanical properties of chalk depends on carbonate content. Pure chalk with high carbonate content was found to be vulnerable to mechanical weakening due to CO2 injection, whereas, no significant mechanical effect was observed in the impure chalk of Ekofisk Formation. It should in this context be noted that the experiments spanned only 8 days, therefore long term effects cannot be ruled out. In spite of weakening of the chalk, we expect only minor mechanical effects, because the weakening also causes a lowering of effective stress due to an increase in effective stress coefficient. Extensive time-lapse monitoring strategies are required during a CO2-EOR process for the measurement of changes in reservoir properties that may cause deformation of and leakage from a reservoir. Results of this study will provide data for designing future monitoring strategies based on 4D seismic.

  18. Effects of Three Types of Oil Dispersants on Biodegradation of Dispersed Crude Oil in Water Surrounding Two Persian Gulf Provinces

    OpenAIRE

    Azadeh Zolfaghari-Baghbaderani; Mozhgan Emtyazjoo; Parinaz Poursafa; Sedigheh Mehrabian; Samira Bijani; Daryoush Farkhani; Parisa Mirmoghtadaee

    2012-01-01

    Objective. To determine the most effective and biodegradable dispersant of spilled oil in water surrounding two Persian Gulf provinces. Methods. This study compared the effects of three dispersants, Pars 1, Pars 2, and Gamlen OD4000 on removal of oil in two Persian Gulf provinces' water. Overall, 16 stations were selected. Using the Well method, the growth rate of isolated bacteria and fungi was identified. To specify the growth rate of microorganisms and their usage of oil in the presence of...

  19. Efecto de la inyección de vapor sobre la composición de crudos / Effects of steam injection on chemical composition of oils

    Scientific Electronic Library Online (English)

    Liliana, López; Karla, Quintero; Patricia, Lugo; Salvador, Lo Mónaco.

    2011-09-01

    Full Text Available Con la finalidad de conocer los cambios en la composición SARA (saturados, aromáticos, resinas y asfaltenos), elementos mayoritarios (C, S), traza (V, Ni), grupos funcionales en la fracción de asfaltenos y biomarcadores (terpanos y esteranos) en crudos de pozos sometidos a inyección de vapor, se est [...] udiaron 20 muestras provenientes de Campo Lagunillas (Cuenca de Maracaibo) tomadas de un pozo sin inyección de vapor (LS-SE), dos pozos en un primer ciclo (LS-A, LS-B) y un pozo en segundo ciclo (LS-C) de inyección de vapor. Los crudos analizados son extra-pesados ( Abstract in english In order to know the changes in SARA composition (saturated, aromatics, resins and asphaltenes), major (C, S), trace (V, Ni) elements, functional groups in the asphaltenes fraction and biomarkers (terpanes and steranes) in oils from wells under steam injection, 20 samples were studied from Lagunilla [...] s field (Maracaibo Basin) taken from a well without stem injection (LS-SE), two wells in a first cycle (LS-A, LS- B), and a well in the second cycle (LS-C) of steam injection. Oils analyzed are extra heavy ones (

  20. Effects of caffeic acid and bovine serum albumin in reducing the rate of development of rancidity in oil-in-water and water-in-oil emulsions

    OpenAIRE

    Conde, Enma; Gordon, Micheal H.; Moure, Andres; Dominguez, Herminia

    2011-01-01

    The antioxidant properties of caffeic acid and bovine serum albumin in oil-in-water and water-in-oil emulsions were studied. Caffeic acid (5 mmol/kg emulsion) showed good antioxidant properties in both 30% sunflower oil-in-water (OW) and 20% water-in-sunflower oil emulsions (WO), pH 5.4, during storage at 50 ºC. Although bovine serum albumin (BSA) (0.2%) had a slight antioxidant effect, the combination of caffeic acid and BSA showed a synergistic reduction in the rate of development of rancid...

  1. Chemical equilibrium models: Their use in simulating the injection of incompatible waters

    Energy Technology Data Exchange (ETDEWEB)

    Bertero, L.; Chierici, G.L.; Gottardi, G.; Mesini, E.; Mormino, G.

    1988-02-01

    One of the problems encountered in waterflooding projects is scale formation caused by chemical incompatibility between potential injection waters and reservoir brine. Chemical compatibility evaluation through laboratory experiments on cores at reservoir conditions is of limited value because only first-contact phenomena are reproduced. A numerical model is presented that couples a reservoir-fluid-flow/thermal-equilibrium simulator with a chemical-equilibrium computer code. This model, AGIPS, enables us to calculate the evolution in time of the amount of scale formed at any point in the reservoir and inside the wells when changes occur in the temperature of the injected water and when the injection water mixes with reservoir brine. Moreover, the model calculates temperature and pressure profiles in the reservoir, together with their evolution in time, taking into account the permeability reduction caused by scale formation. Results are presented for the chemical-equilibrium code validation by matching experimental data on scale formation in mixtures of incompatible waters. An example is also given of the use of AGIPS in simulating a five-spot waterflood where incompatible water is injected.

  2. Novel preparation method for sustained-release PLGA microspheres using water-in-oil-in-hydrophilic-oil-in-water emulsion

    Directory of Open Access Journals (Sweden)

    Hong X

    2013-07-01

    Full Text Available Xiaoyun Hong,1,2,* Liangming Wei,3,* Liuqing Ma,2 Yinghui Chen,4 Zhenguo Liu,1 Weien Yuan2,* 1Department of Neurology, Xinhua Hospital affiliated to Shanghai JiaoTong University, School of Medicine, Shanghai, People's Republic of China; 2School of Pharmacy, Shanghai JiaoTong University, 3Key Laboratory for Thin Film and Microfabrication Technology, Ministry of Education, Research Institute of Micro/Nanometer Science and Technology, Shanghai JiaoTong University, Shanghai, People's Republic of China; 4Department of Neurology, Jinshan Hospital, Fudan University, Shanghai, People's Republic of China *These authors contributed equally to this work Abstract: An increasing number of drugs are needing improved formulations to optimize patient compliance because of their short half-lives in blood. Sustained-release formulations of drugs are often required for long-term efficacy, and microspheres are among the most popular ones. When drugs are encapsulated into microsphere formulations, different methods of preparation need to be used according to specific clinical requirements and the differing physicochemical characteristics of individual drugs. In this work, we developed a novel method for sustained-release drug delivery using a water-in-oil-in-hydrophilic oil-in-water (w/o/oh/w emulsion to encapsulate a drug into poly(lactic-co-glycolic acid (PLGA microspheres. Different effects were achieved by varying the proportions and concentrations of hydrophilic oil and PLGA. Scanning electron and optical microscopic images showed the surfaces of the microspheres to be smooth and that their morphology was spherical. Microspheres prepared using the w/o/oh/w emulsion were able to load protein efficiently and had sustained-release properties. These results indicate that the above-mentioned method might be useful for developing sustained-release microsphere formulations in the future. Keywords: protein, microspheres, water-in-oil-in-hydrophilic oil-in-water emulsion, sustained-release

  3. Stabilization Mechanisms of Water-in-Crude Oil Emulsions

    Directory of Open Access Journals (Sweden)

    Abdurahman H. Nour

    2008-01-01

    Full Text Available During the lifting and production of crude oil, water/oil emulsions are created. They are stabilized by asphaltenes and resins which are colloidally dispersed in the crude oil. Asphaltenes consist mainly of polar heterocompounds. It is known that they decrease the interfacial tension between oil and water and form stable interfacial films. Both effects favour the formation and stabilization of emulsions. Resins are complex high-molecular-weight compounds that are not soluble in ethylacetate, but are soluble in n-heptane. Their interfacial activity is less than that of asphaltenes. The role of resins in stabilizing emulsions has also been debated in literature. This study reports the results of experimental investigation of various factors affecting the stability of emulsions which are considered to be undesirable for a number of reasons, including both up-stream and down-stream operation in the petroleum industry. It was found that, the (R/A ratio affects the emulsion and dispersion stabilities. High resin/asphaltene ratios decrease the emulsion stability.

  4. Stabilization Mechanisms of Water-in-Crude Oil Emulsions

    Science.gov (United States)

    Nour, Abdurahman H.; Suliman, A.; Hadow, Mahmmoud M.

    During the lifting and production of crude oil, water/oil emulsions are created. They are stabilized by asphaltenes and resins which are colloidally dispersed in the crude oil. Asphaltenes consist mainly of polar heterocompounds. It is known that they decrease the interfacial tension between oil and water and form stable interfacial films. Both effects favour the formation and stabilization of emulsions. Resins are complex high-molecular-weight compounds that are not soluble in ethylacetate, but are soluble in n-heptane. Their interfacial activity is less than that of asphaltenes. The role of resins in stabilizing emulsions has also been debated in literature. This study reports the results of experimental investigation of various factors affecting the stability of emulsions which are considered to be undesirable for a number of reasons, including both up-stream and down-stream operation in the petroleum industry. It was found that, the (R/A) ratio affects the emulsion and dispersion stabilities. High resin/asphaltene ratios decrease the emulsion stability.

  5. Comparative performance of direct injection diesel engine operating on ethanol, petrol and rapeseed oil blends

    Energy Technology Data Exchange (ETDEWEB)

    Labeckas, Gvidonas; Slavinskas, Stasys [Department of Transport and Power Machinery, Lithuanian University of Agriculture, Student Street 15, P.O. Box LT-53361, Kaunas Academy (Lithuania)

    2009-03-15

    This article presents the bench testing results of a four stroke, four cylinder, direct injection, unmodified, diesel engine operating on pure rapeseed oil (RO) and its 2.5 vol%, 5 vol%, 7.5 vol% and 10 vol% blends with ethanol (ERO), petrol (PRO) and both improving agents applied in equal proportions as 50:50 vol% (EPRO). The purpose of the research is to examine the effect of ethanol and petrol addition into RO on the biofuel kinematical viscosity, brake mean effective pressure (bmep), brake specific fuel consumption (bsfc) of a diesel engine and its brake thermal efficiency (bte). Addition into RO from 2.5 to 7.5 vol% of ethanol and petrol its viscosity at ambient temperature of 20 C diminishes by 9.2-28.3% and 14.1-31.7%, respectively. Heating up to the temperature of 60 C the viscosity of pure RO, blends ERO2.5-7.5 and PRO2.5-10 further diminishes 4.2, 3.9-3.8 and 3.9-3.6 times. At 1800 min{sup -1} speed, the maximum brake mean effective pressure (bmep) higher up to 1.6% comparing with that of pure RO (0.77 MPa) ensure three agent blends EPRO5-7.5, whereas at rated 2200 min{sup -1} speed, the bmep higher by 5.6% can be obtained when fuelling the engine with blend PRO2.5. Brake specific fuel consumption (bsfc) at maximum torque (240.2 g/kWh) and rated power (234.0 g/kWh) is correspondingly lower by 3.4% and 5.5% in comparison with pure RO when biofuel blends EPRO5 and PRO2.5 are used. The biggest brake thermal efficiency at maximum torque (0.40-0.41) and rated power (0.42-0.43) relative to that of RO (0.39) suggest blends PRO2.5 and EPRO5-7.5, respectively. (author)

  6. Comparative performance of direct injection diesel engine operating on ethanol, petrol and rapeseed oil blends

    International Nuclear Information System (INIS)

    This article presents the bench testing results of a four stroke, four cylinder, direct injection, unmodified, diesel engine operating on pure rapeseed oil (RO) and its 2.5 vol%, 5 vol%, 7.5 vol% and 10 vol% blends with ethanol (ERO), petrol (PRO) and both improving agents applied in equal proportions as 50:50 vol% (EPRO). The purpose of the research is to examine the effect of ethanol and petrol addition into RO on the biofuel kinematical viscosity, brake mean effective pressure (bmep), brake specific fuel consumption (bsfc) of a diesel engine and its brake thermal efficiency (bte). Addition into RO from 2.5 to 7.5 vol% of ethanol and petrol its viscosity at ambient temperature of 20 deg. C diminishes by 9.2-28.3% and 14.1-31.7%, respectively. Heating up to the temperature of 60 deg. C the viscosity of pure RO, blends ERO2.5-7.5 and PRO2.5-10 further diminishes 4.2, 3.9-3.8 and 3.9-3.6 times. At 1800 min-1 speed, the maximum brake mean effective pressure (bmep) higher up to 1.6% comparing with that of pure RO (0.77 MPa) ensure three agent blends EPRO5-7.5, whereas at rated 2200 min-1 speed, the bmep higher by 5.6% can be obtained when fuelling the engine with blend PRO2.5. Brake specific fuel consumption (bsfc) at maximum torque (240.2 g/kWh) and rated power (234.0 g/kWh) is correspondingly lower by 3.4% and 5.5% in comparison with pure RO when biofuel blends EPRO5 and PRO2.5 are used. The biggest brake thermal efficiency at maximum torque (0.40-0.41) and rated power (0.42-0.43) relative to that of RO (0.39) suggest blends PRO2.5 and EPRO5-7.5, respectively

  7. Low-Sulfate Seawater Injection into Oil Reservoir to Avoid Scaling Problem

    Directory of Open Access Journals (Sweden)

    Amer Badr Bin Merdhah

    2008-01-01

    Full Text Available This study presents the results of laboratory experiments carried out to investigate the formation of calcium, strontium and barium sulfates from mixing Angsi seawater or low sulfate seawater with the following sulfate contents (75, 50, 25, 5 and 1% and formation water contain high concentration of calcium, strontium and barium ions at various temperatures (40-90°C and atmospheric pressure. The knowledge of solubility of common oil field scale formation and how their solubilities are affected by changes in salinity and temperatures is also studied. Results show a large of precipitation occurred in all jars containing seawater while the amount of precipitation decreased when the low sulfate seawater was used. At higher temperatures the mass of precipitation of CaSO4 and SrSO4 scales increases and the mass of precipitation of BaSO4 scale decreases since the solubilities of CaSO4 and SrSO4 scales decreases and the solubility of BaSO4 increases with increasing temperature. It can be concluded that even at sulfate content of 1% there may still be a scaling problem.

  8. Recovery of oil from oil-in-water emulsion using biopolymers by adsorptive method.

    Science.gov (United States)

    Elanchezhiyan, S Sd; Sivasurian, N; Meenakshi, Sankaran

    2014-09-01

    In the present study, it is aimed to identify, a low cost sorbent for the recovery of oil from oil-in-water emulsion using biopolymers such as chitin and chitosan. Chitin has the greater adsorption capacity than chitosan due to its hydrophobic nature. The characterizations of chitin and chitosan were done using FTIR, SEM, EDAX, XRD, TGA and DSC techniques. Under batch equilibrium mode, a systematic study was performed to optimize the various equilibrium parameters viz., contact time, pH, dosage, initial concentration of oil, and temperature. The adsorption process reached equilibrium at 40 min of contact time and the percentage removal of oil was found to be higher (90%) in the acidic medium. The Freundlich and Langmuir models were applied to describe the equilibrium isotherms and the isotherm constants were calculated. Thermodynamic parameters such as ?G°, ?H° and ?S° were calculated to find out the nature of the sorption mechanism. The kinetic studies were investigated with reaction-based and diffusion-based models. The suitable mechanism for the removal of oil has been established. PMID:25017179

  9. Stability of Water-in-Crude Oil Emulsion Using Cocamide Surfactant

    OpenAIRE

    Rasha Mohammed Abd; Abdurhman H. Nour; Ahmad Ziad Sulaiman

    2014-01-01

    The formation of water-in-crude oil emulsion can be encountered in many stages such as drilling, transporting and processing of crude oil. To enhance and control these processes, it is necessary to understand the emulsion mechanisms. In this study, two types of Malaysian crude oil namely; heavy crude oil and light-heavy blended crude oil (40-60 vol%) were characterized physically to use as the oil phase. Cocaamide DEA was used as a natural surfactant. The stability of water-in-crude oil emuls...

  10. A study of gas lift on oil/water flow in vertical risers

    OpenAIRE

    Brini Ahmed, Salem Kalifa

    2014-01-01

    Gas lift is a means of enhancing oil recovery from hydrocarbon reservoirs. Gas injected at the production riser base reduces the gravity component of the pressure drop and thereby, increases the supply of oil from the reservoir. Also, gas injection at the base of a riser helps to mitigate slugging and thus, improving the performance of the topside facility. In order to improve the efficiency of the gas lifting technique, a good understanding of the characteristics of gas-liq...

  11. In-situ burning of oil in coastal marshes. 2. Oil spill cleanup efficiency as a function of oil type, marsh type, and water depth.

    Science.gov (United States)

    Lin, Qianxin; Mendelssohn, Irving A; Carney, Kenneth; Miles, Scott M; Bryner, Nelson P; Walton, William D

    2005-03-15

    In-situ burning of spilled oil, which receives considerable attention in marine conditions, could be an effective way to cleanup wetland oil spills. An experimental in-situ burn was conducted to study the effects of oil type, marsh type, and water depth on oil chemistry and oil removal efficiency from the water surface and sediment. In-situ burning decreased the totaltargeted alkanes and total targeted polycyclic aromatic hydrocarbons (PAHs) in the burn residues as compared to the pre-burn diesel and crude oils. Removal was even more effective for short-chain alkanes and low ring-number PAHs. Removal efficiencies for alkanes and PAHs were >98% in terms of mass balance although concentrations of some long-chain alkanes and high ring-number PAHs increased in the burn residue as compared to the pre-burn oils. Thus, in-situ burning potentially prevents floating oil from drifting into and contaminating adjacent habitats and penetrating the sediment. In addition, in-situ burning significantly removed diesel oil that had penetrated the sediment for all water depths. Furthermore, in-situ burning at a water depth 2 cm below the soil surface significantly removed crude oil that had penetrated the sediment. As a result, in-situ burning may reduce the long-term impacts of oil on benthic organisms. PMID:15819247

  12. Land uplift due to subsurface fluid injection

    OpenAIRE

    Teatini, Pietro; Gambolati, Giuseppe; Ferronato, Massimiliano; Settari, A. (Tony); Walters, Dale

    2010-01-01

    Abstract The subsurface injection of fluid (water, gas, vapour) occurs worldwide for a variety of purposes, e.g. to enhance oil production (EOR), store gas in depleted gas/oil fields, recharge overdrafted aquifer systems (ASR), and mitigate anthropogenic land subsidence. Irrespective of the injection target, some areas have experienced an observed land uplift ranging from a few millimetres to tens of centimetres over a time period of a few months to several years depending on the q...

  13. Ultrasonic splitting of oil-in-water emulsions

    DEFF Research Database (Denmark)

    Hald, Jens; König, Ralf; Benes, Ewald; Gröschl, Martin

    1999-01-01

    Standing resonant ultrasonic wave fields can be utilized for liquid–liquid separation of the dispersed particles and the fluid caused by the acoustic radiation pressure and the induced particle agglomeration or coagulation/coalescence process. For the splitting of oil-in-water emulsions, the available piezoelectric composite transducer technology was improved and a dedicated resonator with crossed plane wave sonication geometry has been developed. The resonator chamber is entirely made of alumin...

  14. Factors governing partial coalescence in oil-in-water emulsions

    OpenAIRE

    Fredrick, E.; WALSTRA, P.; Dewettinck, K.

    2010-01-01

    The consequences of the instability mechanism partial coalescence in oil-in-water food emulsions show a discrepancy. On the one hand, it needs to be avoided in order to achieve an extended shelf life in food products like sauces, creams and several milk products. On the other hand, during the manufacturing of products like ice cream. butter and whipped toppings partial coalescence is required to achieve the desired product properties. It contributes to the structure formation, the physicochem...

  15. Ultrasonic splitting of oil-in-water emulsions

    OpenAIRE

    Hald, Jens; König, Ralf; Benes, Ewald; Gröschl, Martin

    1999-01-01

    Standing resonant ultrasonic wave fields can be utilized for liquid–liquid separation of the dispersed particles and the fluid caused by the acoustic radiation pressure and the induced particle agglomeration or coagulation/coalescence process. For the splitting of oil-in-water emulsions, the available piezoelectric composite transducer technology was improved and a dedicated resonator with crossed plane wave sonication geometry has been developed. The resonator chamber is entirely made of alu...

  16. Mathematical Modeling of Coalescence of Oil Droplets in Water Flow

    OpenAIRE

    Kufås, Eirik

    2008-01-01

    Liquid-liquid coalescers are devices used for increasing the droplet size of the dispersed phase in continuous phase flow, such as oil droplets in water flow. The efficiency of separation technologies is strongly dependent on the droplet size, which is desirable to shift into larger droplet diameters. Theory behind coalescence and its modeling is studied in this Maser?s thesis. Aker Process Systems AS, Division of Advanced Separation Technology, provided the assignment proposal.The scope of t...

  17. Muscle enhancement using intramuscular injections of oil in bodybuilding : review on epidemiology, complications, clinical evaluation and treatment

    DEFF Research Database (Denmark)

    Schäfer, Ch. N.; Hvolris, JØrgen Jesper

    2012-01-01

    BACKGROUND: Self-administered intramuscular injection of site enhancement oil (SEO) is a cosmetic and performance-enhancing procedure used to reshape muscles in the bodybuilder subculture, but its consequences and complications are only sporadically described. Methods: A systematic search in MEDLINE and EMBASE databases during the spring of 2009 and 2010. Internet searches were performed, and bodybuilder pharmacopoeias were consulted to describe SEO use and the clinical complications known. Results: One review and seven case reports were identified. Eight case reports describe oleomas caused by repeated intramuscular injections of anabolic steroids. Conclusions: SEOs cause sclerosing lipogranulomatosis and its progression may lead to lifelong complications. Thorough radiologic evaluation is important to plan surgical revisions in active phases. Also antibiotics, steroids, and compression therapy have been successful and should be employed at different stages.

  18. Monitoring, characterization and comparison. Operation-project of oil and oil water systems in platforms

    International Nuclear Information System (INIS)

    During the process of petroleum production, water are also commonly produced. Usually, a standard oil-water separation process will not lead to water phase ready to be discharged - the present legislation requires oily contents (oil and/or greases) bellow 20 mg/L concentration level value. Thus, secondary treatment is required to bring such oily concentration to the allowed level or lower, prior to the water discard in the environment. This paper describes the adopted systematic work in the Campos Basin Petroleum Production Platforms, which has allowed to evaluate and optimize the water treatment performed in there. Such description includes the typical water treatment systems installed, the typical physical-chemistry of the effluents and also presents comparisons between the basic designs that guided such systems construction and their present operational conditions and set-ups. The analysis of such results has allowed the introduction of minor modifications leading to the process optimization. The common use of Pilot Plants in such optimization process is also described and their contribution reported. (author)

  19. Monitoring of fluid-rock interaction and CO2 storage through produced fluid sampling at the Weyburn CO2-injection enhanced oil recovery site, Saskatchewan, Canada

    International Nuclear Information System (INIS)

    The Weyburn Oil Field is a carbonate reservoir in south central Saskatchewan, Canada and is the site of a large CO2 injection project for purposes of enhanced oil recovery. The Weyburn Field, in the Mississippian Midale Formation, was discovered in 1954 and was under primary production until secondary recovery by water flood began in 1964. The reservoir comprises two units, the Vuggy and the Marly, and primary and secondary recovery are thought to only have significantly depleted the Vuggy zone, leaving the Marly with higher oil saturations. In 2000, PanCanadian Resources (now EnCana), the operator of the field, began tertiary recovery by injection of CO2 and water, primarily into the Marly. The advent of this project was an opportunity to study the potential for geological storage of CO2. Using 43 Baseline samples collected in August 2000, before CO2 injection at Weyburn, and 44 monitoring samples collected in March 2001, changes in the fluid chemistry and isotope composition have been tracked. The initial fluid distribution showed water from discovery through water flood in the Midale Formation with Cl ranging from 25,000 to 60,000 mg/L, from the NW to the SE across the Phase 1A area. By the time of Baseline sampling the produced water had been diluted to Cl of 25,000-50,000 mg/L as a result of the addition of make up water from the low TDS Blairmore Formation, but the pattern of distribution was still present. The Cl distribution is mimicked by the distribution of other dissolved ions and variables, with Ca (1250-1500 mg/L) and NH3(aq) increasing from NW to SE, and alkalinity (700-300 mg/L), resistivity, and H2S (300-100 mg/L) decreasing. Based on chemical and isotopic data, the H2S is interpreted to result from bacterial SO4 reduction. After 6 months of injection of CO2, the general patterns are changed very little, except that the pH has decreased by 0.5 units and alkalinity has increased, with values over 1400 mg/L in the NW, decreasing to 500 mg/L in the SE. Calcium has increased to range from 1250 to 1750 mg/L, but the pattern of NW-SE distribution is altered. Chemical and isotopic data suggest this change in distribution is caused by the dissolution of calcite due to water-rock reactions driven by CO2. The Baseline samples varied from -22 to -12%o ? 13C (V-PDB) for CO2 gas. The injected CO2 has an isotope ratio of -20%o. The Monitor-1 samples of produced CO2 ranged from -18 to -13%o, requiring a heavy source of C, most easily attributed to dissolution of carbonate minerals. Field measured pH had increased and alkalinity had decreased by the second monitoring trip (July 2001) to near Baseline values, suggesting continued reaction with reservoir minerals. Addition of CO2 to water-rock mixtures comprising carbonate minerals causes dissolution of carbonates and production of alkalinity. Geochemical modeling suggests dissolution is taking place, however more detail on water-oil-gas ratios needs to be gathered to obtain more accurate estimates of pH at the formation level. Geological storage of CO2 relies on the potential that, over the longer term, silicate minerals will buffer the pH, causing any added CO2 to be precipitated as calcite. Some initial modeling of water-rock reactions suggests that silica sources are available to the water resident in the Midale Formation, and that clay minerals may well be capable of acting as pH buffers, allowing injected CO2 to be stored as carbonate minerals. Further work is underway to document the mineralogy of the Midale Formation and associated units so as to define more accurately the potential for geological storage

  20. Radiation-thermal purification of waste water from oil pollution

    International Nuclear Information System (INIS)

    Full text: During the extraction, preparation, transportation and refining of oil the sewages containing oil contaminations are produced. The concentration of oil content in the water depends on used technology and may vary from a thousandths parts up to tens percents. There is a necessity of cleaning this pollution up to a permissible level. There are numerous methods (adsorption, mechanical, chemical and etc) of treating of waster water from oil contaminations. Radiation-chemical method is one of the effective among the above mentioned methods. The results of radiation-thermal decomposition of n-heptane micro-admixtures in water medium are adduced. The main parameters of radiolysis change within the intervals: temperature 20-400oC, absorbed dose - 0†10.8 kGy at dose rate 3.6 kGy/h. The correlation of n-heptane concentration and water steam changed within [C5H12]/[H2O] (1-100) 10-5. Total concentration of steam was about 1020 molec/ml. As a product of decomposition are observed H2, CO, CH4, C2H4, C2H6, C3H8, C3H6, C4H8, hydrocarbons C5, and C6. The changes of n-heptane concentration in the reactor also were established. The chain regime of n-heptane decomposition at high temperatures in the irradiated mixture is observed. The critical value of temperature and mixture ratio of components, under which the break of chain process of normal n-heptane occurs are defined. The mechanisms of proceeding radiation thermal processes in hydrocarbons-water system are discussed. At the temperatures higher than 300oC the radiation-thermal decompositions of hydrocarbon micro-impurities in water into gas products occurs according a chain mechanism and the radiation-chemical yield of the decomposition exceeds 100 molec/100eV. This method can be used for purification of sewages from oil contaminations

  1. Ellipsoidal Janus nanoparticles assembled at spherical oil/water interfaces.

    Science.gov (United States)

    Luu, Xuan-Cuong; Striolo, Alberto

    2014-11-26

    The equilibrium behavior of ellipsoidal Janus nanoparticles adsorbed at spherical oil/water interfaces was investigated using dissipative particle dynamics simulations. Several phenomena were documented that were not observed on similar simulations for planar oil/water interfaces. The nanoparticles were found to yield isotropic, radial nematic phases, and axial nematic domains, depending on the nanoparticle characteristics (aspect ratio and surface chemistry), particle density at the interface, and droplet properties (curvature of the interface, and surprisingly, liquid type). When adsorbed on water droplets, the nanoparticles with high aspect ratio and few nonpolar beads on their surface can show two preferred orientation angles. Only one equilibrium orientation was found for such nanoparticles adsorbed on oil droplets. These observations might help explain a discrepancy previously reported between experimental and simulation results concerning the preferential orientation of particles at liquid-liquid interfaces. Different driving forces are responsible for the phenomena just summarized, including nanoparticle-nanoparticle and nanoparticle-solvent interactions, nanoparticle density at the interface, and droplet curvature via the Laplace pressure. The simulation results we present could be useful for engineering Pickering emulsions toward practical applications, and perhaps also for guiding new technologies for material synthesis. PMID:25358124

  2. Ultrasonic splitting of oil-in-water emulsions

    DEFF Research Database (Denmark)

    Hald, Jens; König, Ralf

    1999-01-01

    Standing resonant ultrasonic wave fields can be utilized for liquid–liquid separation of the dispersed particles and the fluid caused by the acoustic radiation pressure and the induced particle agglomeration or coagulation/coalescence process. For the splitting of oil-in-water emulsions, the available piezoelectric composite transducer technology was improved and a dedicated resonator with crossed plane wave sonication geometry has been developed. The resonator chamber is entirely made of aluminium or tempax glass and the PZT piezoceramic transducer delivers an acoustic energy flow density of up to 24 W/cm2 into the sonication volume. The chosen resonance frequency is kept stable by automatic frequency control utilizing the maximum true power criterion. Physically and chemically well-defined low and high density pure laboratory and also industrially used cooling-lubricating oil-in-water emulsion samples have been investigated. The quality of the ultrasonic-induced particle separation/coagulation process is characterized by physical–chemical analysis of the separated oil- and water phase and by determining the change of the particle size distribution of the initial emulsion due to the ultrasonic treatment. [Work supported by the European Commission, Contract Nos. ERBFMBICT960916 and ERBFMRXCT970156.

  3. Injection and Combustion of RME with Water Emulsions in a Diesel Engine

    Directory of Open Access Journals (Sweden)

    J. Cisek

    2010-01-01

    Full Text Available This paper presents ways of using the fully-digitised triggerable AVL VideoScope 513D video system for analysing the injection and combustion inside a diesel engine cylinder fuelled by RME with water emulsions.The research objects were: standard diesel fuel, rapeseed methyl ester (RME and RME – water emulsions. With the aid of a helical flow reactor, stable emulsions with the water fraction up to 30 % weight were obtained, using an additive to prevent the water from separating out of the emulsion.An investigation was made of the effect of the emulsions on exhaust gas emissions (NOX, CO and HC, particulate matter emissions, smoke and the fuel consumption of a one-cylinder HD diesel engine with direct injection. Additionally, the maximum cylinder pressure rise was calculated from the indicator diagram. The test engine was operated at a constant speed of 1 600 rpm and 4 bar BMEP load conditions. The fuel injection and combustion processes were observed and analysed using endoscopes and a digital camera. The temperature distribution in the combustion chamber was analysed quantitatively using the two-colour method. The injection and combustion phenomena were described and compared.A way to reduce NOX formation in the combustion chamber of diesel engines by adding water in the combustion zone was presented. Evaporating water efficiently lowers the peak flame temperature and the temperature in the post-flame zone. For diesel engines, there is an exponential relationship between NOX emissions and peak combustion temperatures. The energy needed to vaporize the water results in lower peak temperatures of the combusted gases, with a consequent reduction in nitrogen oxide formation. The experimental results show up to 50 % NOX emission reduction with the use of 30% water in an RME emulsion, with unchanged engine performance.

  4. Lube-oil dilution of gasoline direct-injection engines with ethanol fuels; Schmieroelverduennung von direkteinspritzenden Ottomotoren unter Kaltstartrandbedingungen

    Energy Technology Data Exchange (ETDEWEB)

    Kuepper, Carsten; Pischinger, Stefan [RWTH Aachen Univ. (Germany). Lehrstuhl fuer Verbrennungskraftmaschinen (VKA); Artmann, Chrsitina; Rabl, Hans-Peter [Hochschule Regensburg (Germany). Labor fuer Verbrennungsmotoren und Abgasnachbehandlung

    2013-09-15

    Ethanol fuel mixtures account for the majority of biofuels used worldwide. However, their properties make these fuels more difficult to use in cold conditions and especially when starting a cold engine. As part of the FVV research project 'Lubricant Dilution with Ethanol Fuels under Cold Start Conditions', the Institute for Combustion Engines (VKA) at RWTH Aachen University and the Combustion Engines and Emission Control Laboratory at Regensburg University of Applied Sciences have investigated the influence of the ethanol content in fuels on the dilution of the lubricating oil in modern direct-injection gasoline engines. (orig.)

  5. Study of performance and emission characteristics of a direct injection diesel engine using rice bran oil ethanol and petrol blends

    OpenAIRE

    G. Venkata Subbaiah; K. Raja Gopal; B. Durga Prasad

    2010-01-01

    In this study, influence on the engine performance and exhaust emissions of a naturally aspirated, single cylinder direct injection diesel engine has been experimentally investigated using pure rice bran oil (RBO), and its 2.5%, 5% and 7.5% blends with ethanol (ERBO) and petrol (PRBO). The influence on the viscosity of the RBO with the addition of the ethanol and petrol from 200C to 700C has also been studied. The tests conducted from no load to full load of the engine with an increment of ...

  6. Experimental Investigations of CI Engine by using Different Blends of Neat Karanja Oil and Diesel at Different Injection Pressures

    Directory of Open Access Journals (Sweden)

    Dr. A. G. Matani

    2014-06-01

    Full Text Available In the present Investigation experimental work has been carried out to analyze the performance characteristics of single cylinder compression ignition direct ignition fuelled with blends of neat Karanja oil and diesel at different injection pressure. As the blending with diesel increases the viscosity decreases. Brake thermal efficiency of diesel fuel is nearly equal to the brake thermal efficiency of blends10B and 20B. Brake specific fuel consumption increases as the blending proportion increases due to low calorific value of blends.

  7. The possible influences of dietary oil supplementation in ameliorating metabolic disturbances and oxidative stress in Alloxan injected rats

    International Nuclear Information System (INIS)

    Diabetes mellitus (DM) is a multifactor disease that is associated with a number of different metabolic abnormalities. Clinical research has confirmed the efficacy of several plant extracts in the modulation of oxidative stress associated with DM. The present work was conducted to examine the protective or treating effects of two different dietary oils rich in medium chain fatty acids (MCFA) as coconut oil (CO) or omega-3-polyunsaturated fatty acids (?-3-PUFAs)as flaxseed oil (FO) on the severity of DM induced experimentally by alloxan injection. Wistar strain albino rats (17 Og) were fed commercial rat chow diet supplemented with either CO or FO for four weeks. A single dose of alloxan (150 mg/kg) resulted in hyperglycemia, decreases in serum insulin, thyroxine (T4), and high density lipoprotein-cholesterol levels, elevated triglycerides, total cholesterol and low density lipoprotein-cholesterol concentrations. Concurrent with those changes, an increased liver malonaldehyde (MDA) level was observed. This oxidative stress was related to decreases in superoxide dismutase (SOD) activity and glutathione (GSH) content in the liver of alloxan diabetic rats. Oils supplementation after diabetes induction ameliorated hyperglycemia, increased insulin and thyroxine hormone levels, improved lipid profiles, blunted the increase in MDA, modulated the levels of hepatic SOD activity and GSH content of alloxan treated rats. It could be suggested that each of CO or FO could be used as antidiabetic complement in case of DM. This may be related to their anti oxidative properties

  8. Effects of fresh lubricant oils on particle emissions emitted by a modern gasoline direct injection passenger car.

    Science.gov (United States)

    Pirjola, Liisa; Karjalainen, Panu; Heikkilä, Juha; Saari, Sampo; Tzamkiozis, Theodoros; Ntziachristos, Leonidas; Kulmala, Kari; Keskinen, Jorma; Rönkkö, Topi

    2015-03-17

    Particle emissions from a modern turbocharged gasoline direct injection passenger car equipped with a three-way catalyst and an exhaust gas recirculation system were studied while the vehicle was running on low-sulfur gasoline and, consecutively, with five different lubrication oils. Exhaust particle number concentration, size distribution, and volatility were determined both at laboratory and on-road conditions. The results indicated that the choice of lubricant affected particle emissions both during the cold start and warm driving cycles. However, the contribution of engine oil depended on driving conditions being higher during acceleration and steady state driving than during deceleration. The highest emission factors were found with two oils that had the highest metal content. The results indicate that a 10% decrease in the Zn content of engine oils is linked with an 11-13% decrease to the nonvolatile particle number emissions in steady driving conditions and a 5% decrease over the New European Driving Cycle. The effect of lubricant on volatile particles was even higher, on the order of 20%. PMID:25679531

  9. Evaluation of WAG injection at Ekofisk

    OpenAIRE

    Knappskog, Ole Andreas

    2012-01-01

    In the North Sea many fields are water flooded. Subsequent to water flooding large amounts of water flood residual oil will be left in reservoirs. The challenge is how to improve the oil recovery. On the Ekofisk field such a challenge is to be addressed. The entire reservoir on the Ekofisk field is currently water flooded. The current plan is to continue water injection until the end of license in 2028. To improve oil recovery, EOR mechanisms have been proposed. The EOR mechanism hydrocarbon ...

  10. Prenatal toxicology of shale oil retort water in mice.

    Science.gov (United States)

    Gregg, C T; Tietjen, G; Hutson, J Y

    1981-01-01

    Shale oil retort water, a by-product of the production of oil from shale, potentially amounts to tens of millions of gallons per year and must be treated or recycled with regard for public health. Such retort water was given to 98 female ICR/DUB mice in their drinking water at concentrations of 0, 0.1, 0.3, and 1.0% for periods up to 203 d. Seven of 75 treated animals developed adenomalike lesions that were not seen in the control animals. These ranged from adenomas and an adenomatoid nodule in the lung to the rectal adenocarcinoma. Although the incidence of adenomalike lesions was not statistically significant, this appearance of neoplasia requires further investigation. Eighty-five animals became pregnant. The proportion of animals pregnant, weights of nonpregnant animals, weight gain during pregnancy, average fetal weight, number of live fetuses per liter, and proportion of male fetuses were unaffected by drinking retort water. Early and late fetal deaths and preimplantation losses were likewise unaffected, except for a significant increase in preimplantation losses in animals consuming 1.0% retort water. A variety of palatal defects were seen in treated animals, however, including single and multiple cleft palates and a defect, to our knowledge not previously reported, in which the posterior portion of one or both palatal shelves appeared not to have formed. The palatal defects, as a group, were dose-dependent and statistically significant. PMID:7338942

  11. Water in soybean oil microemulsions as medium for electrochemical measurements

    Directory of Open Access Journals (Sweden)

    Mendonça Carla R. B.

    2003-01-01

    Full Text Available Microemulsions of water in soybean oil (w/o ME were prepared with sodium dodecyl sulfate (SDS as surfactant and amyl or isoamyl alcohol, as co-surfactants. Microemulsions containing 40.0% oil, 43.2% alcohol, 10.8% SDS and 6.0% water in weight, in the ratio 1:4 [SDS]:[alcohol] showed the highest thermodynamic stability. The aqueous droplet size and its diffusion coefficient Dw/o in the ME were determined through dynamic light scattering (DLS. Voltammetric measurements in the ME at a Pt disk ultramicroelectrode (ume evidenced the oxidation of both water and ferrocene (Fc, and the reduction of oleic acid. The Dw/o values calculated from the limiting current being lower than the ones obtained from DLS indicate that water oxidation probably requires diffusion towards the electrode of both the droplets and the water molecules from inside the droplets. The results show that electroanalytical determinations can be carried out in w/o ME.

  12. Origin of late pleistocene formation water in Mexican oil reservoirs

    International Nuclear Information System (INIS)

    Brine water invasion into petroleum reservoirs, especially in sedimentary basins, are known from a variety of global oil field, such as the Western Canada sedimentary basin and, the central Mississippi Salt Dome basin (Kharaka et al., 1987). The majority of oil wells, especially in the more mature North American fields, produce more water than they do oil (Peachey et al., 1998). In the case of Mexican oil fields, increasing volumes of invading water into the petroleum wells were detected during the past few years. Major oil reserves in the SE-part of the Gulf of Mexico are economically affected due to decreases in production rate, pipeline corrosion and well closure. The origin of deep formation water in many sedimentary basins is still controversial: Former hypothesis mainly in the 60's, explained the formation of formation water by entrapment of seawater during sediment deposition. Subsequent water-rock interaction processes explain the chemical evolution of hydrostatic connate water. More recent hydrodynamic models, mainly based on isotopic data, suggest the partial migration of connate fluids, whereas the subsequent invasion of surface water causes mixing processes (Carpenter 1978). As part of the presented study, a total of 90 oil production wells were sampled from 1998 to 2004 to obtain chemical (Major and trace elements) and isotopic composition (2H, 13C, 14C, 18O 36Cl, 37Cl, 87Sr, 129I, tritium) of deep formation water at the Mexican Gulf coast. Samples were extracted from carbonate-type reservoirs of the oil fields Luna, Samaria-Sitio Grande, Jujo-Tecominoac (on-shore), and Pol-Chuc (off-shore, including Abkatun, Batab, Caan, and Taratunich) at a depth between 2,900 m b.s.l. and 6,100 m b.s.l. During the field work, the influence of atmospheric contamination e.g. by CO2-atmospheric input was avoided by using an interval sampler to get in-situ samples from the extraction zone of selected bore holes. For wellhead samples, a 20 liter-sampling-reagent was previously filled with N2-gas for the collection and phase separation of the pressurized gas-water-crude oil mixture. No differences in 14C-concentrations were detected applying, both, conventional and AMS-techniques. In contradiction to the expected 'fossil age' of reservoir water as part of a stagnant hydraulic system, measured 14C-concentrations between 0.89 pmC and 31.86 pmC indicate a late Pleistocene-early Holocene, regional event for the infiltration of surface water into the reservoir. The variety in water mineralization from meteoric (TDSmax = 0.5 g/l) to hyper-saline composition (TDSmax = 338 g/l) is not caused by halite dissolution from adjacent salt domes, as shown by elevated Br/Cl ratios. In contrary, the linear correlation between 18O and Cl values reflect varying mixing proportions of two components - meteoric water and evaporated seawater. Instead of water/rock-interaction, evaporation of seawater at the surface prior to infiltration represents the principal process for fluid enrichment in 18O and chlorine, with maximum values of 17.2 %o and 228 g/l, respectively. The young residence time of formation water in Mexican oil reservoirs implies following: - The common assumption of 'hydraulically-frozen' reservoirs is not correct, as main descending fluid migration occurred during glacial period. Probably, major infiltration processes are related to periods with climatic changes and increased humidity - as observed for the adjacent Yucatan region in SE-Mexico during early-mid Holocene (6,000 yr BP) (Metcalfe et al. 2000) - with the probable transgression of Mexican Gulf seawater into the recent Mexican coastal plain. - The common hypothesis of hydrocarbon maturation within Jurassic organic-rich layers, and its subsequent expulsion and migration into Cretaceous/Tertiary sedimentary units must be expanded by a last-step-process: As glacial ground water level is actually located below the hydrocarbon column (due to differences in density), a general mobilization of the entire column of reservoir fluids and the displacement of the organic phase must be pos

  13. Ground-Water Nutrient Flux to Coastal Waters and Numerical Simulation of Wastewater Injection at Kihei, Maui, Hawaii

    Science.gov (United States)

    Hunt, Charles D., Jr.

    2007-01-01

    Water sampling and numerical modeling were used to estimate ground-water nutrient fluxes in the Kihei area of Maui, where growth of macroalgae (seaweed) on coral reefs raises ecologic concerns and accumulation on beaches has caused odor and removal problems. Fluxes and model results are highly approximate, first-order estimates because very few wells were sampled and there are few field data to constrain model calibration. Ground-water recharge was estimated to be 22.6 Mgal/d (million gallons per day) within a 73-square-mile area having a coastline length of 8 miles or 13 km (kilometers). Nearly all of the recharge discharges at the coast because ground-water withdrawals are small. Another 3.0 Mgal/d of tertiary-treated wastewater effluent is injected into the regional aquifer at a County treatment plant midway along the coast and about a mile from shore. The injection plume is 0.93 miles wide (1.5 km) at the shore, as estimated from a three-dimensional numerical ground-water model. Wastewater injected beneath the brackish ground-water lens rises buoyantly and spreads out at the top of the lens, diverting and mixing with ambient ground water. Ground water discharging from the core of the injection plume is less than 5 years old and is about 60 percent effluent at the shore, according to the model. Dissolved nitrogen and phosphorus concentrations in treated effluent were 7.33 and 1.72 milligrams per liter, roughly 6 and 26 times background concentrations at an upgradient well. Background nitrogen and phosphorus fluxes carried by ground water are 7.7 and 0.44 kg/d-km (kilograms per day per kilometer of coast). Injected wastewater fluxes distributed across the plume width are 55 and 13 kg/d-km nitrogen and phosphorus, roughly 7 and 30 times background flux. However, not all of the injected load reaches coastal waters because nutrients are naturally attenuated in the oxygen-depleted effluent plume. Water from a downgradient well reflects this attenuation and provides a more conservative estimate of injection flux approaching the shore: 27 and 1.5 kg/d-km nitrogen and phosphorus, roughly one-half and one-ninth the injection-source estimates, and 3.5 and 3.4 times background flux. Effluent has 8 O and 2 H stable-isotope signatures that are distinct from local ground water, as well as 15 N and 11 B signatures diagnostic of domestic waste and laundry detergents, respectively. Pharmaceuticals and organic wastewater compounds also were present in effluent and the downgradient well. These isotopes and chemicals served as wastewater tracers in Kihei ground water and may be useful tracers in nearshore marine waters and aquifers elsewhere in Hawaii.

  14. Recovery of oil from subterranean formations

    Energy Technology Data Exchange (ETDEWEB)

    Bernard, G.G.; Holbrook, O.C.

    1965-05-25

    This is a method of secondary recovery of oil using surfactants. The surfactant has the ability to lower the surface tension between the oil and water, enabling the floodwater to remove a larger portion of the oil held in the pores of the formation. A solvent, miscible with the reservoir oil, is injected in an amount equivalent to about 5-30 volume % of the oil in the reservoir. The first reactant injected may be ricinoleic acid and ricinoleic acid amine. Immediately thereafter an aqueous solution of ethylene oxide, in an amount of 5-30 volume % of the oil in the reservoir, is injected. The 2 reactants, under reservoir conditions, form a surfactant. Thereafter, water, free from surfactant, is injected in sufficient quantity to produce oil from the reservoir. (1 claim)

  15. Unit Operation Optimization for the Manufacturing of Botanical Injections Using a Design Space Approach: A Case Study of Water Precipitation

    OpenAIRE

    Gong, Xingchu; Chen, Huali; Chen, Teng; Qu, Haibin

    2014-01-01

    Quality by design (QbD) concept is a paradigm for the improvement of botanical injection quality control. In this work, water precipitation process for the manufacturing of Xueshuantong injection, a botanical injection made from Notoginseng Radix et Rhizoma, was optimized using a design space approach as a sample. Saponin recovery and total saponin purity (TSP) in supernatant were identified as the critical quality attributes (CQAs) of water precipitation using a risk assessment for all the p...

  16. Performance of single cylinder, direct injection Diesel engine using water fuel emulsions

    International Nuclear Information System (INIS)

    A single cylinder Diesel engine study of water-in-Diesel emulsions was conducted to investigate the effect of water emulsification on the engine performance and gases exhaust temperature. Emulsified Diesel fuels of 0, 5, 10, 15 and 20 water/Diesel ratios by volume, were used in a single cylinder, direct injection Diesel engine, operating at 1200-3300 rpm. The results indicate that the addition of water in the form of emulsion improves combustion efficiency. The engine torque, power and brake thermal efficiency increase as the water percentage in the emulsion increases. The average increase in the brake thermal efficiency for 20% water emulsion is approximately 3.5% over the use of Diesel for the engine speed range studied. The proper brake specific fuel consumption and gases exhaust temperature decrease as the percentage of water in the emulsion increases

  17. Partition of selected food preservatives in fish oil-water systems

    DEFF Research Database (Denmark)

    Cheng, Hongyuan; Friis, Alan; Leth, Torben

    2010-01-01

    The partition coefficients (Kow) of benzoic acid and sorbic acid in systems of fish oil (sand eel)–water, fish oil–buffer solution, rape oil–water and olive oil–water were experimentally determined in a temperature range from 5 to 43 °C and pH from 4.5 to 6.5 °C. The dimerization of benzoic acid in fish oil–water system was observed at 25 °C. Two modifications have been made to the Nordic Food Analysis Standard for the determination of sorbic acid by HPLC. The experimental results show that the ...

  18. Viscous-Gravity Spreading of Oil on Water: Modeling and Challenges

    Directory of Open Access Journals (Sweden)

    R. Chebbi

    2014-04-01

    Full Text Available Oil spreading is one of the major factors affecting the fate of oil spills on water. Modeling spreading is required to study the impact of oil slicks on the environment and plants using sea water including desalination units. Spreading of oil on water undergoes three stages. In the second stage, gravity acts as the main driving force against the viscous force, which is the main resisting force in stages 2 and 3. The paper presents the state of the art in modeling the second stage of spreading. Challenges in analyzing viscous-gravity spreading of continuously discharged oil on water are also presented

  19. Investigating the factors influencing recovery of asphaltenic oil by water and miscible CO{sub 2} flooding

    Energy Technology Data Exchange (ETDEWEB)

    Chukwudeme, Edwin Andrew

    2009-09-15

    Conclusions that may be drawn from this work on the influence of CO{sub 2}, temperature, pressure and water composition on the recovery of asphaltenic oil by water and CO{sub 2} flooding are as follows: Asphaltene is found to alter outcrop chalk wettability from water-wet to more oil wet, which influence oil recovery by miscible CO{sub 2} and water flooding. Modification of Hirschberg solubility model for predicting asphaltene deposition has been done to account for the effect of CO{sub 2} fraction in the liquid phase during miscible flooding. This is done based on data from this work and literature. This model made it possible to isolate the effect of CO{sub 2} fraction in liquid phase on asphaltene deposition during miscible flooding. Hence, determine the critical fraction of CO{sub 2} that initiate the asphaltene deposition. The critical fraction of CO{sub 2} is estimated to be between 17 to 42 mol percent (mol%), with 33 mol% as average value. A ternary diagram is developed and is based on solubility parameter ratio (S.P.R) and molar volume ratio (V{sub CO2}/V{sub L}) and their relation to asphaltene deposition using data from this work and literature. From this data, it may be suggested that S.P.R is a determining factor for asphaltene deposition during CO{sub 2} flooding, which is not unreasonable since it is influenced by the molar volume ratio, hence temperature, pressure and composition. It is interesting to see a linear relationship between asphaltene precipitation and pressure drop regardless of the flowing pressure at isothermal condition. This is tested for under-saturated fluids. Oil recovery by miscible CO{sub 2} flooding shows low ultimate oil recovery with increasing temperature and pressure for asphaltenic oil compared to non-asphaltenic. CO{sub 2} flooding is found to be plausible for asphaltenic reservoir at lower temperature (< 70 C). From simulation studies, EOR by CO{sub 2} initiated after at least three years of water injection show the benefit of miscible flooding. Water containing magnesium or sulfate ions has shown to alter modified oil- wet chalk to more water-wet which indicates their potential in improving oil recovery from asphaltenic oil reservoir. (Author)

  20. Assessment of nitrification potential in ground water using short term, single-well injection experiments

    Science.gov (United States)

    Smith, R.L.; Baumgartner, L.K.; Miller, D.N.; Repert, D.A.; Böhlke, J.K.

    2006-01-01

    Nitrification was measured within a sand and gravel aquifer on Cape Cod, MA, using a series of single-well injection tests. The aquifer contained a wastewater-derived contaminant plume, the core of which was anoxic and contained ammonium. The study was conducted near the downgradient end of the ammonium zone, which was characterized by inversely trending vertical gradients of oxygen (270 to 0 ??M) and ammonium (19 to 625 ??M) and appeared to be a potentially active zone for nitrification. The tests were conducted by injecting a tracer solution (ambient ground water + added constituents) into selected locations within the gradients using multilevel samplers. After injection, the tracers moved by natural ground water flow and were sampled with time from the injection port. Rates of nitrification were determined from changes in nitrate and nitrite concentration relative to bromide. Initial tests were conducted with 15N-enriched ammonium; subsequent tests examined the effect of adding ammonium, nitrite, or oxygen above background concentrations and of adding difluoromethane, a nitrification inhibitor. In situ net nitrate production exceeded net nitrite production by 3- to 6- fold and production rates of both decreased in the presence of difluoromethane. Nitrification rates were 0.02-0.28 ??mol (L aquifer)-1 h-1 with in situ oxygen concentrations and up to 0.81 ??mol (L aquifer)-1 h-1 with non-limiting substrate concentrations. Geochemical considerations indicate that the rates derived from single-well injection tests yielded overestimates of in situ rates, possibly because the injections promoted small-scale mixing within a transport-limited reaction zone. Nonetheless, these tests were useful for characterizing ground water nitrification in situ and for comparing potential rates of activity when the tracer cloud included non-limiting ammonium and oxygen concentrations. ?? Springer Science+Business Media, Inc. 2005.

  1. The Use of Demulsifiers for Separating Water from Anthracene Oil

    Directory of Open Access Journals (Sweden)

    Ze?evi?, N.

    2008-03-01

    Full Text Available The main feedstocks for the production of oil-furnace carbon black are different kinds of liquid hydrocarbons. The quality and utilization of oil-furnace carbon black mainly depends on the type of liquid hydrocarbons contained in the oil feedstocks.In practice, both carbochemical and petrochemical oils are used as feedstock sources. Carbochemical oils are fractions obtained during coal tar distillation. Anthracene oil is one of these oils. Depending on the conditions of distillation, coal tars contain up to w = 18·10 –2 highly aromatic fractions, which can be used as carbon black feedstock. The sulphur fraction of these oils can vary between w = 0.5 and 0.7·10 –2, depending on the origin of the coal. The availability of carbochemical oils obtained from coal tar is largely dependent on the production of coke used in the manufacture of steel. The quantities available today are insufficient to satisfy the demand for carbon black feedstock. In addition, in highly industrialized countries, production of carbochemicaloils is declining.Although, carbochemical oils are preferred in terms of efficiency, petrochemical oils are more important in terms of quantities available, particularly in the production of furnace blacks. These are residual oils resulting either from catalytic cracking processes or from the production of olefins in steam crackers using naphtha or gas oil as raw material. Nevertheless, the choice of carbon black feedstock is not determined merely by price and efficiency, but also by specific quality criteria. However, due to their origin, the feedstocks are mixtures of a large number of individual substances and are, therefore, not easy to characterize. More than 200 different components have been recorded in the range detectable by gas chromatography.Some important components of carbon black feedstock are listed in table 1.1 An important parameter for the evaluation of carbon black feedstock is density, since it increases with increasing aromaticity. It is also used for determination of the Bureau of Mines Correlation Index (BMCI,2 which is obtained either from density and midboiling point, or from density andviscosity for those feedstocks which cannot be distilled completely. This index is used by the carbon black industry as an important criteria for feedstock evaluation.The sulphur fraction in feedstocks should not exceed w = 2.5 ·10–2, because a higher content greatly affects the quality of carbon black, pollutes the atmosphere, and accelerates corrosion of the facility. The maximum sulphur content in the typical hydrocarbon feedstock is w = 1.2 · 10–2.3. A very important factor of hydrocarbon feedstock is the fraction of alkaline earth metals, especially sodium and potassium. The maximum sodium fraction may be w = 20·10–6, while the maximum potassium fraction is w = 2·10 –6.The maximum fraction of asphalthenes is w = 15 ·10–2. Asphalthenes, determined as pentane-insoluble matter, provide indications concerning the possibility of grit formation. Another very important factor is the temperature range of distillation, which should be low enough, because the hydrocarbon feedstock must evaporize before entering the hot region of the reactor. The viscosity, the pour point, and for safety reasons, the flash point determines the handling properties and storage conditions of the feedstock.In addition, the water fraction in the hydrocarbon feedstock is one of the most important factors. The water fraction in hydrocarbon feedstock influences the handling properties of the same. The maximum water fraction in hydrocarbon feedstock may be w = 2.0·10–2, and desirably below w = 1.0·10–2. A higher water fraction represent a considerable impact on the financial construction. Also, it is very difficult to manipulate such feedstock, especially unloading, and in the production of oil-furnace carbon black. Namely, every water fraction higher than w = 2.0·10–2 in the hydrocarbon feedstock, causes the phenomenon of cavitations.In the oil-furnace carbon black plant of Petrokemija d.

  2. Biological treatments and uses of geothermal water as alternatives to injection

    Energy Technology Data Exchange (ETDEWEB)

    Breckenridge, R.P.; Cahn, L.S.; Thurow, T.L.

    1982-04-01

    The feasibility of using geothermal fluids to support various biological systems prior to, or as an alternative to, direct injection at the DOE's Raft River goethermal site is discussed. Researchers at the Raft River site studied the feasibility of using geothermal fluid for establishign methods and for irrigating trees and agricultural crops. The emphasis of these studies has been on the bioaccumulative potential of the plants, their survivability, production rates, and water-purification potential. The possible adverse impacts associated with not injecting the fluid back into the geothermal reservoir have not been addressed. (MJF)

  3. Matrix injection of relative permeability modifier for water control applied in Brazil basins; Injecao matricial de modificadores de permeabilidade relativa para controle de producao de agua aplicado nas bacias petroliferas brasileiras

    Energy Technology Data Exchange (ETDEWEB)

    Marchi, Flavio; Stefan, Rodolfo; Mendonca, Paulo; Ferreira, Antonio; Silva, Charles; Fonseca, Ana Isoila [BJ Services do Brasil Ltda., Macae, Rio de Janeiro, RJ (Brazil); Melo, Ricardo C.B. [BJ Services Company Africa Ltd., Angola (Angola)

    2008-07-01

    One of the biggest challenges for the oil industry, even at the beginning of well's production, and principally when the well is producing, is how to reduce and handling the produced water on this process. A conservative estimation says for each barrel of produced oil you have 5 or 6 barrels of formation's water. Some factors must be considerable to establish and maintain a carefully management of this effluent, for example the volume of produced water, which is always growing due to the reservoir maturation and for the secondary recovery process; salt content; residual oil and chemical products presence. Water production is the cause of several problems on wells, like scales, organic deposits or starting the process of formation's sand production induced by fines migration. As a consequence, a cost increment of production is observed due to hydrocarbon/water separation and destination of produced water. The same way, is extremely expensive to manage the even bigger volume, which demands efforts to re-inject the water, treatment which avoid or minimize possible environment impacts, development of new equipment and materials which helps and resists to the effects of produced water. Not inherent reservoir's cause can be several, like bad isolated water zones by cement fail, wrong determination of perforated interval, which is easier to use aid methods. When the water production is directly associated to reservoir, by conning, channeling and/or fingering, generally associated to mobility difference between water and oil, the nowadays most efficient treatment is the injection of relative permeability modifier. This paper will present techniques and results obtained with matrix injection in some fields by the use of the last generation of RPM (relative permeability modifier). (author)

  4. Toxicity of water-soluble fractions of biodiesel fuels derived from castor oil, palm oil, and waste cooking oil.

    Science.gov (United States)

    Leite, Maria Bernadete Neiva Lemos; de Araújo, Milena Maria Sampaio; Nascimento, Iracema Andrade; da Cruz, Andrea Cristina Santos; Pereira, Solange Andrade; do Nascimento, Núbia Costa

    2011-04-01

    Concerns over the sustained availability of fossil fuels and their impact on global warming and pollution have led to the search for fuels from renewable sources to address worldwide rising energy demands. Biodiesel is emerging as one of the possible solutions for the transport sector. It shows comparable engine performance to that of conventional diesel fuel, while reducing greenhouse gas emissions. However, the toxicity of products and effluents from the biodiesel industry has not yet been sufficiently investigated. Brazil has a very high potential as a biodiesel producer, in view of its climatic conditions and vast areas for cropland, with consequent environmental risks because of possible accidental biodiesel spillages into water bodies and runoff to coastal areas. This research determined the toxicity to two marine organisms of the water-soluble fractions (WSF) of three different biodiesel fuels obtained by methanol transesterification of castor oil (CO), palm oil (PO), and waste cooking oil (WCO). Microalgae and sea urchins were used as the test organisms, respectively, for culture-growth-inhibition and early-life-stage-toxicity tests. The toxicity levels of the analyzed biodiesel WSF showed the highest toxicity for the CO, followed by WCO and the PO. Methanol was the most prominent contaminant; concentrations increased over time in WSF samples stored up to 120 d. PMID:21184529

  5. Carbon Dioxide-Water Emulsions for Enhanced Oil Recovery and Permanent Sequestration of Carbon Dioxide

    Energy Technology Data Exchange (ETDEWEB)

    Ryan, David; Golomb, Dan; Shi, Guang; Shih, Cherry; Lewczuk, Rob; Miksch, Joshua; Manmode, Rahul; Mulagapati, Srihariraju; Malepati, Chetankurmar

    2011-09-30

    This project involves the use of an innovative new invention ? Particle Stabilized Emulsions (PSEs) of Carbon Dioxide-in-Water and Water-in-Carbon Dioxide for Enhanced Oil Recovery (EOR) and Permanent Sequestration of Carbon Dioxide. The EOR emulsion would be injected into a semi-depleted oil reservoir such as Dover 33 in Otsego County, Michigan. It is expected that the emulsion would dislocate the stranded heavy crude oil from the rock granule surfaces, reduce its viscosity, and increase its mobility. The advancing emulsion front should provide viscosity control which drives the reduced-viscosity oil toward the production wells. The make-up of the emulsion would be subsequently changed so it interacts with the surrounding rock minerals in order to enhance mineralization, thereby providing permanent sequestration of the injected CO{sub 2}. In Phase 1 of the project, the following tasks were accomplished: 1. Perform laboratory scale (mL/min) refinements on existing procedures for producing liquid carbon dioxide-in-water (C/W) and water-in-liquid carbon dioxide (W/C) emulsion stabilized by hydrophilic and hydrophobic fine particles, respectively, using a Kenics-type static mixer. 2. Design and cost evaluate scaled up (gal/min) C/W and W/C emulsification systems to be deployed in Phase 2 at the Otsego County semi-depleted oil field. 3. Design the modifications necessary to the present CO{sub 2} flooding system at Otsego County for emulsion injection. 4. Design monitoring and verification systems to be deployed in Phase 2 for measuring potential leakage of CO{sub 2} after emulsion injection. 5. Design production protocol to assess enhanced oil recovery with emulsion injection compared to present recovery with neat CO{sub 2} flooding. 6. Obtain Federal and State permits for emulsion injection. Initial research focused on creating particle stabilized emulsions with the smallest possible globule size so that the emulsion can penetrate even low-permeability crude oilcontaining formations or saline aquifers. The term ?globule? refers to the water or liquid carbon dioxide droplets sheathed with ultrafine particles dispersed in the continuous external medium, liquid CO{sub 2} or H{sub 2}O, respectively. The key to obtaining very small globules is the shear force acting on the two intermixing fluids, and the use of ultrafine stabilizing particles or nanoparticles. We found that using Kenics-type static mixers with a shear rate in the range of 2700 to 9800 s{sup -1} and nanoparticles between 100-300 nm produced globule sizes in the 10 to 20 ?m range. Particle stabilized emulsions with that kind of globule size should easily penetrate oil-bearing formations or saline aquifers where the pore and throat size can be on the order of 50 ?m or larger. Subsequent research focused on creating particle stabilized emulsions that are deemed particularly suitable for Permanent Sequestration of Carbon Dioxide. Based on a survey of the literature an emulsion consisting of 70% by volume of water, 30% by volume of liquid or supercritical carbon dioxide, and 2% by weight of finely pulverized limestone (CaCO{sub 3}) was selected as the most promising agent for permanent sequestration of CO{sub 2}. In order to assure penetration of the emulsion into tight formations of sandstone or other silicate rocks and carbonate or dolomite rock, it is necessary to use an emulsion consisting of the smallest possible globule size. In previous reports we described a high shear static mixer that can create such small globules. In addition to the high shear mixer, it is also necessary that the emulsion stabilizing particles be in the submicron size, preferably in the range of 0.1 to 0.2 ?m (100 to 200 nm) size. We found a commercial source of such pulverized limestone particles, in addition we purchased under this DOE Project a particle grinding apparatus that can provide particles in the desired size range. Additional work focused on attempts to generate particle stabilized emulsions with a flow through, static mixer based apparatus under a variety

  6. Low-head air stripper treats oil tanker ballast water

    International Nuclear Information System (INIS)

    Prototype tests conducted during the winter of 1989/90 have successfully demonstrated an economical design for air stripping volatile hydrocarbons from oily tanker ballast water. The prototype air stripper, developed for Alyeska's Ballast Water Treatment (BWT) facility in Valdez, Alaska, ran continuously for three months with an average removal of 88% of the incoming volatile organics. Initially designed to remove oil and grease compounds from tanker ballast water, the BWT system has been upgraded to a three-step process to comply with new, stringent regulations. The BWT biological oxidation process enhances the growth of bacteria present in the incoming ballast water through nutrient addition, aeration, and recirculation within a complete-mixed bioreactor. The average removal of BETX is over 95%, however, occassional upsets required the placement of a polishing air stripper downstream of the aeration tanks. Packed-tower air stripping was investigated but deemed economically unfeasible for a facility that would only occasionally be used. Twelve feet of excess gravity head in the existing BWT hydraulic gradeline were employed to drive the air stripper feed. This limited the stripper packing depth to 8 feet and imposed constraints on the design of the inlet water and air distributors. Water distribution, air flow, temperature effects, and fouling from constituents in the ballast water were investigated. The prototype was operated under water and air flow conditions similar to those specified for the full-scale unit, and at a range of test conditions above and below the normal design conditions

  7. Effect of low-capacity injection systems on transient-initiated loss of vessel-water injection at Browns Ferry Unit One

    International Nuclear Information System (INIS)

    Probabilistic risk assessment (PRA) analyses have indicated the transient-initiated loss of vessel-water injection (TQUV sequence) to be a dominant accident scenario for BWR plants. The PRA studies assumed the low-capacity injection systems to be unimportant in severe accidents. The results of a Severe Accident Sequence Analysis (SASA) Program study have shown that these systems are capable of preventing or significantly delaying core damage in a TQUV sequence

  8. Numerical Study of Water Control with Downhole Oil-Water Separation Technology

    Directory of Open Access Journals (Sweden)

    Yin Khor Yin

    2014-07-01

    Full Text Available The maturing oil fields with increasing water production can pose a challenging produced water handling and disposal issues. This paper presents a numerical study of a motorless hydrocyclone to enhance understanding of the downhole oil-water separation. The turbulence of fluid flow is obtained using K-? Realizable Turbulence model for complex swirl dominated flow, while the interface between hydrocarbon and water is described using the Discrete Phase model. In this approach, factors which contribute to the hydrocyclone separation instability were discussed. Discussion is then extended to the relationship of residence time with pressure difference between overflow and underflow. These pressure differences are able to relate to pressure condition for high water cut well which require downhole separation.

  9. Effect of water injection on nitric oxide emissions of a gas turbine combustor burning natural gas fuel

    Science.gov (United States)

    Marchionna, N. R.; Diehl, L. A.; Trout, A. M.

    1973-01-01

    The effect of direct water injection on the exhaust gas emissions of a turbojet combustor burning natural gas fuel was investigated. The results are compared with the results from similar tests using ASTM Jet-A fuel. Increasing water injection decreased the emissions of oxides of nitrogen (NOX) and increased the emissions of carbon monoxide and unburned hydrocarbons. The greatest percentage decrease in NOX with increasing water injection was at the lowest inlet-air temperature tested. The effect of increasing inlet-air temperature was to decrease the effect of the water injection. The reduction in NOX due to water injection was almost identical to the results obtained with Jet-A fuel. However, the emission indices of unburned hydrocarbons, carbon monoxide, and percentage nitric oxide in NOX were not.

  10. Versatile fabrication of magnetic carbon fiber aerogel applied for bidirectional oil-water separation

    Science.gov (United States)

    Li, Yong; Zhu, Xiaotao; Ge, Bo; Men, Xuehu; Li, Peilong; Zhang, Zhaozhu

    2015-09-01

    Fabricating functional materials that can solve environmental problems resulting from oil or organic solvent pollution is highly desired. However, expensive materials or complicated procedures and unidirectional oil-water separation hamper their applications. Herein, a magnetic superhydrophobic carbon fiber aerogel with high absorption capacity was developed by one-step pyrolysis of Fe(NO3)3-coated cotton in an argon atmosphere. The obtained aerogel can selectively collect oils from oil-polluted region by a magnet bar owing to its magnetic properties and achieves fast oil-water separation for its superhydrophobicity and superoleophilicity. Furthermore, the aerogel performs recyclable oil absorption capacity even after ten cycles of oil-water separation and bears organic solvent immersion. Importantly, the obtained aerogel turns to superhydrophilic and underwater superoleophobic after thermal treatment, allowing it as a promising and efficient material for bidirectional oil-water separation and organic contaminants removal.

  11. Micromodel Study of Influence of Pore Geometry on Water-Oil Displacement with and without Surfactant

    Science.gov (United States)

    Yin, X.; Xu, W.; Ok, J.; Neeves, K.

    2012-12-01

    Using oil-wet Polydimethylsiloxane (PDMS) based microfluidic micromodels, we studied the effect of pore geometry on water-oil drainage efficiency. The porosity and permeability of micromodels are 0.19 and about 200md, respectively; the size of the micromodels is 3 cm by 3 mm, with the longer dimension aligned with the flow direction. The pore geometries compared include a random network of uniformly sized channels (6 ?m), a network with a channel size distribution (4-8 ?m), and a geometry with large vugs (200-300 ?m) embedded in a network of uniformly sized channels (8 ?m); the last one was designed to simulate the vuggy texture of oil-wet carbonate rocks. Regular patterns with periodically arranged squares and hexagons were also made. Water saturations were measured at the point of water breakthrough as well as at intervals of 0.5 pore volume injection up to a total of three pore volumes. We found that both pore size distribution and vugs decreased the drainage efficiency. In addition, while application of surfactant (5000 ppm ethoxylated alcohol) increased the drainage efficiency in all geometries by increasing the Capillary number, the gain was less for geometries with vugs. From videos, we noted withdrawal of non-wetting fluid from channels while the vugs were filled due to disparity in the capillary pressure. The preference for the non-wetting fluid to fill the vugs caused early breakthrough and trapping of the wetting fluid that is difficult to remove even at increased Capillary numbers.

  12. Development of Polymer Gel Systems to Improve Volumetric Sweep and Reduce Producing Water/Oil Ratios

    Energy Technology Data Exchange (ETDEWEB)

    G. Paul Willhite; Stan McCool; Don W. Green; Min Cheng; Feiyan Chen

    2005-12-31

    Gelled polymer treatments are applied to oil reservoirs to increase oil production and to reduce water production by altering the fluid movement within the reservoir. This report describes the results of a 42-month research program that focused on the understanding of gelation chemistry and the fundamental mechanisms that alter the flows of oil and water in reservoir rocks after a gel treatment. Work was conducted on a widely applied system in the field, the partially hydrolyzed polyacrylamide-chromium acetate gel. Gelation occurs by network formation through the crosslinking of polyacrylamide molecules as a result of reaction with chromium acetate. Pre-gel aggregates form and grow as reactions between chromium acetate and polyacrylamide proceed. A rate equation that describes the reaction between chromium acetate and polymer molecules was regressed from experimental data. A mathematical model that describes the crosslinking reaction between two polymer molecules as a function of time was derived. The model was based on probability concepts and provides molecular-weight averages and molecular-weight distributions of the pre-gel aggregates as a function of time and initial system conditions. Average molecular weights of pre-gel aggregates were measured as a function of time and were comparable to model simulations. Experimental methods to determine molecular weight distributions of pre-gel aggregates were unsuccessful. Dissolution of carbonate minerals during the injection of gelants causes the pH of the gelant to increase. Chromium precipitates from solution at the higher pH values robbing the gelant of crosslinker. Experimental data on the transport of chromium acetate solutions through dolomite cores were obtained. A mathematical model that describes the transport of brine and chromium acetate solutions through rocks containing carbonate minerals was used to simulate the experimental results and data from literature. Gel treatments usually reduce the permeability to water to a greater extent than the permeability to oil is reduced. This phenomenon is referred to as disproportionate permeability reduction (DPR). Flow experiments were conducted in sandpacks to determine the effect of polymer and chromium concentrations on DPR. All gels studied reduced the permeability to water by a greater factor than the factor by which the oil permeability was reduced. Greater DPR was observed as the concentrations of polymer and chromium were increased. A conceptual model of the mechanisms responsible for DPR is presented. Primary features of the model are (1) the development of flow channels through the gel by dehydration and displacement of the gel and by re-connection of pre-treatment, residual oil volume and (2) high flow resistance in the channels during water flow is caused by significant saturations of oil remaining in the channels. A similar study of DPR was conducted in Berea sandstone cores. Both oil and water permeabilities were reduced by much smaller factors in Berea sandstone cores than in similar treatments in sandpacks. Poor maturation of the gelant in the Berea rock was thought to be caused by fluid-rock interactions that interfered with the gelation process.

  13. An Experimental Study of Oil / Water Flow in Horizontal Pipes

    Energy Technology Data Exchange (ETDEWEB)

    Elseth, Geir

    2001-07-01

    The purpose of this thesis is to study the behaviour of the simultaneous flow of oil and water in horizontal pipes. In this connection, two test facilities are used. Both facilities have horizontal test sections with inner pipe diameters equal to 2 inches. The largest facility, called the model oil facility, has reservoirs of 1 m{sub 3} of each medium enabling flow rates as high as 30 m{sub 3}/h, which corresponds to mixture velocities as high as 3.35 m/s. The flow rates of oil and water can be varied individually producing different flow patterns according to variations in mixture velocity and input water cut. Two main classes of flows are seen, stratified and dispersed. In this facility, the main focus has been on stratified flows. Pressure drops and local phase fractions are measured for a large number of flow conditions. Among the instruments used are differential pressure transmitters and a traversing gamma densitometer, respectively. The flow patterns that appear are classified in flow pattern maps as functions of either mixture velocity and water cut or superficial velocities. From these experiments a smaller number of stratified flows are selected for studies of velocity and turbulence. A laser Doppler anemometer (LDA) is applied for these measurements in a transparent part of the test section. To be able to produce accurate measurements a partial refractive index matching procedure is used. The other facility, called the matched refractive index facility, has a 0.2 m{sub 3} reservoir enabling mainly dispersed flows. Mixture velocities range from 0.75 m/s to 3 m/s. The fluids in this facility are carefully selected to match the refractive index of the transparent part of the test section. A full refractive index matching procedure is carried out producing excellent optical conditions for velocity and turbulence studies by LDA. In addition, pressure drops and local phase fractions are measured. (author)

  14. Operation and Combustion Characteristics of a Direct Injection Diesel Engine Fuelled with Esterified Cotton Seed Oil

    OpenAIRE

    Murugu Mohan Kumar Kandasamy; Sarangan Jeganathan; Rajamohan Ganesan

    2009-01-01

    Vegetable oils are renewable in nature and can be directly used as fuels in diesel engines.  However, their high viscosity and poor volatility lead to reduced thermal efficiency and increased hydrocarbon, carbon monoxide and smoke emissions. Transesterification is one of the methods by which viscosity could be drastically reduced and the fuel could be adopted for use in diesel engine.  This Esterified vegetable oil is popularly known as Bio-diesel and that is commercially available in the dev...

  15. Study on MELCOR Modeling for Emergency External Water Injection Scenario of SBO in APR1400

    Energy Technology Data Exchange (ETDEWEB)

    Heo, Junl; Kim, Wontae [Heungdeok IT Valley, Yongin (Korea, Republic of); Kim, Hanchul; Lee, Sunghan [Korea Institute of Nuclear Safety, Daejeon (Korea, Republic of)

    2014-05-15

    In the present study, a MELCOR model for APR1400 was developed and applied to analyze a SBO scenario selected to confirm the effectiveness of the means. In this analysis, the primary and secondary emergency cooling water injection were considered. Leakage from the Reactor Coolant Pump (RCP) seal and opening of the Atmosphere Dump Valve (ADV) were modeled as well to simulate the external pump injection strategy. In this study, the analysis results showed that the external injection strategy with an ADV manual opening could successfully cool down the reactor for a station blackout accident through its effective implementation. It was found that the RCP seal leakage rate is a sensitive parameter for depressurization of the RCS. In this regard, further study is needed to develop a realistic RCP seal leakage model, referring to detailed technical data.

  16. Dynamic investigation of nutrient consumption and injection strategy in microbial enhanced oil recovery (MEOR) by means of large-scale experiments.

    Science.gov (United States)

    Song, Zhiyong; Zhu, Weiyao; Sun, Gangzheng; Blanckaert, Koen

    2015-08-01

    Microbial enhanced oil recovery (MEOR) depends on the in situ microbial activity to release trapped oil in reservoirs. In practice, undesired consumption is a universal phenomenon but cannot be observed effectively in small-scale physical simulations due to the scale effect. The present paper investigates the dynamics of oil recovery, biomass and nutrient consumption in a series of flooding experiments in a dedicated large-scale sand-pack column. First, control experiments of nutrient transportation with and without microbial consumption were conducted, which characterized the nutrient loss during transportation. Then, a standard microbial flooding experiment was performed recovering additional oil (4.9 % Original Oil in Place, OOIP), during which microbial activity mostly occurred upstream, where oil saturation declined earlier and steeper than downstream in the column. Subsequently, more oil remained downstream due to nutrient shortage. Finally, further research was conducted to enhance the ultimate recovery by optimizing the injection strategy. An extra 3.5 % OOIP was recovered when the nutrients were injected in the middle of the column, and another additional 11.9 % OOIP were recovered by altering the timing of nutrient injection. PMID:25895095

  17. Chaotic behavior of water column oscillator simulating pressure balanced injection system in passive safety reactor

    International Nuclear Information System (INIS)

    Japan Atomic Energy Research Institute (JAERI) proposed a passive safety reactor called the System-integrated Pressurized Water Reactor (SPWR). In a loss of coolant accident, the Pressurizing Line (PL) and the Injection Line (IL) are passively opened. Vapor generated by residual heat pushes down the water level in the Reactor Vessel (RV). When the level is lower than the inlet of the PL, the vapor is ejected into the Containment Vessel (CV) through the PL. Then boronized water in the CV is injected into the RV through the IL by the static head. In an experiment using a simple apparatus, gas ejection and water injection were found to occur alternately under certain conditions. The gas ejection interval was observed to fluctuate considerably. Though stochastic noise affected the interval, the experimental results suggested that the large fluctuation was produced by an inherent character in the system. A set of piecewise linear differential equations was derived to describe the experimental result. The large fluctuation was reproduced in the analytical solution. Thus it was shown to occur even in a deterministic system without any source of stochastic noise. Though the derived equations simulated the experiment well, they had ten independent parameters governing the behavior of the solution. There appeared chaotic features and bifurcation, but the analytical model was too complicated to examine the features and mechanism of bifurcation. In this study, a new simple model is proposed which consists of a set of piecewise linear ordinary differential equations with only four independent parameters. (authors)

  18. Chaotic behavior of water column oscillator simulating pressure balanced injection system in passive safety reactor

    Energy Technology Data Exchange (ETDEWEB)

    Morimoto, Y.; Madarame, H.; Okamoto, K. [Tokyo Univ., Tokai, Ibaraki (Japan). Nuclear Engineering Research Lab.

    2001-07-01

    Japan Atomic Energy Research Institute (JAERI) proposed a passive safety reactor called the System-integrated Pressurized Water Reactor (SPWR). In a loss of coolant accident, the Pressurizing Line (PL) and the Injection Line (IL) are passively opened. Vapor generated by residual heat pushes down the water level in the Reactor Vessel (RV). When the level is lower than the inlet of the PL, the vapor is ejected into the Containment Vessel (CV) through the PL. Then boronized water in the CV is injected into the RV through the IL by the static head. In an experiment using a simple apparatus, gas ejection and water injection were found to occur alternately under certain conditions. The gas ejection interval was observed to fluctuate considerably. Though stochastic noise affected the interval, the experimental results suggested that the large fluctuation was produced by an inherent character in the system. A set of piecewise linear differential equations was derived to describe the experimental result. The large fluctuation was reproduced in the analytical solution. Thus it was shown to occur even in a deterministic system without any source of stochastic noise. Though the derived equations simulated the experiment well, they had ten independent parameters governing the behavior of the solution. There appeared chaotic features and bifurcation, but the analytical model was too complicated to examine the features and mechanism of bifurcation. In this study, a new simple model is proposed which consists of a set of piecewise linear ordinary differential equations with only four independent parameters. (authors)

  19. Experimental evaluation of desuperheating and oil cooling process through liquid injection in two-staged ammonia refrigeration systems with screw compressors

    International Nuclear Information System (INIS)

    This paper examines the problem of achieving desuperheating through liquid injection in two-staged refrigeration systems based on screw compressors. The oil cooling process by refrigerant injection is also included. The basic thermodynamic principles of desuperheating and compressor cooling as well as short comparison with traditional method with a thermosyphon system have also been presented. Finally, the collected data referring to a big refrigeration plant are analyzed in the paper. Specific ammonia system concept applied in this refrigeration plant has demonstrated its advantages and disadvantages. - Highlights: ? An experiment was setup during a frozen food factory refrigeration system reconstruction and adaptation. ? Desuperheating and low-stage compressors oil cooling process were investigated. ? Efficiency of compression process and high-stage compressors functioning were examined. ? Evaporation temperature reduction has great influence on the need for injected liquid refrigerant. ? Several cases in which desuperheating and oil cooling process application are justified were determined.

  20. Oil and Water Don't Mix: The Gulf Coast Oil Disaster as a Preschool Social Studies Lesson

    Science.gov (United States)

    Kruse, Tricia

    2010-01-01

    On April 20, 2010, an offshore oil-drilling platform exploded, spilling millions of gallons of oil into the gulf. From Louisiana to the Gulf Coast of Florida the effects are being felt by fisherman, shrimpers, dive charters, and other hardworking folks who depend on the water for their livelihood. But there is another population in these coastal…

  1. A facile method to fabricate functionally integrated devices for oil/water separation

    Science.gov (United States)

    An, Qi; Zhang, Yihe; Lv, Kaikai; Luan, Xinglong; Zhang, Qian; Shi, Feng

    2015-02-01

    In this paper, we present a facile method for the fabrication of a functionally integrated device, which has the multi-functions of the oil-containment boom, oil-sorption material, and water/oil-separating film, through a single immersion step in an ethanol solution of stearic acid. During the simple immersion process, the two dominant factors of superhydrophobicity, surface roughness and low-surface-energy coatings, could be accomplished simultaneously. The as-prepared functionally integrated device with superhydrophobicity/superoleophilicity displayed a lower density than that of water, such that it could float on water and act as an oil-containment boom; an efficient oil-absorbing property, which was attributed to the capillary effect caused by micrometer-sized pore structures and could be used as oil-sorption materials; a high oil/water separating efficiency which was suitable for water/oil-separating film. In this way, the functions of oil collection, absorption, and water/oil separation are integrated into a single device, and these functions could work independently, reducing the cost in terms of energy consumption and being versatile for a wide range of applications.In this paper, we present a facile method for the fabrication of a functionally integrated device, which has the multi-functions of the oil-containment boom, oil-sorption material, and water/oil-separating film, through a single immersion step in an ethanol solution of stearic acid. During the simple immersion process, the two dominant factors of superhydrophobicity, surface roughness and low-surface-energy coatings, could be accomplished simultaneously. The as-prepared functionally integrated device with superhydrophobicity/superoleophilicity displayed a lower density than that of water, such that it could float on water and act as an oil-containment boom; an efficient oil-absorbing property, which was attributed to the capillary effect caused by micrometer-sized pore structures and could be used as oil-sorption materials; a high oil/water separating efficiency which was suitable for water/oil-separating film. In this way, the functions of oil collection, absorption, and water/oil separation are integrated into a single device, and these functions could work independently, reducing the cost in terms of energy consumption and being versatile for a wide range of applications. Electronic supplementary information (ESI) available. See DOI: 10.1039/c5nr00026b

  2. A cost-benefit analysis of produced water management opportunities in selected unconventional oil and gas plays

    Science.gov (United States)

    Marsters, P.; Macknick, J.; Bazilian, M.; Newmark, R. L.

    2013-12-01

    Unconventional oil and gas production in North America has grown enormously over the past decade. The combination of horizontal drilling and hydraulic fracturing has made production from shale and other unconventional resources economically attractive for oil and gas operators, but has also resulted in concerns over potential water use and pollution issues. Hydraulic fracturing operations must manage large volumes of water on both the front end as well as the back end of operations, as significant amounts of water are coproduced with hydrocarbons. This water--often called flowback or produced water--can contain chemicals from the hydraulic fracturing fluid, salts dissolved from the source rock, various minerals, volatile organic chemicals, and radioactive constituents, all of which pose potential management, safety, and public health issues. While the long-term effects of hydraulic fracturing on aquifers, drinking water supplies, and surface water resources are still being assessed, the immediate impacts of produced water on local infrastructure and water supplies are readily evident. Produced water management options are often limited to underground injection, disposal at centralized treatment facilities, or recycling for future hydraulic fracturing operations. The costs of treatment, transport, and recycling are heavily dependent on local regulations, existing infrastructure, and technologies utilized. Produced water treatment costs also change over time during energy production as the quality of the produced water often changes. To date there is no publicly available model that evaluates the cost tradeoffs associated with different produced water management techniques in different regions. This study addresses that gap by characterizing the volume, qualities, and temporal dynamics of produced water in several unconventional oil and gas plays; evaluating potential produced water management options, including reuse and recycling; and assessing how hydraulic fracturing and produced water issues relate to the larger water-energy nexus. Specifically, this study develops a play-specific model to compare the decision factors and costs involved in managing produced water. For example, when transport distances to a wastewater disposal site are far enough, options for recycling water become more favorable, depending on the characteristics of each play. This model can provide policymakers and other interested parties with cost estimates of different water management options, including a better understanding of the costs and opportunities associated with recycling produced water. This work provides a cross-play assessment of produced water management options and costs and could serve as the foundation for more detailed analyses of opportunities to minimize hydraulic fracturing's impacts on freshwater resources.

  3. An experimental study of tracers for labelling of injection gas in oil reservoirs

    International Nuclear Information System (INIS)

    This work demonstrates the feasibility of the PMCP and PMCH as tracers in field experiments. These compounds have properties which make them as well suited for well to well studies as the more common tracers CH3T and 85Kr. In an injection project carried out at the Gullfaks field in the North Sea the two PFCs verified communication between wells. This implies communication between different geological layers in the reservoir and also communication across faults within the same layers. Laboratory studies carried out have focused on the retention of the tracers in dynamic flooding experiments under conditions comparable with those in the petroleum reservoirs. Simultaneous injection of a variety of tracers has shown individual variations in tracer retention which are caused by important reservoir parameters as fluid saturation and rock properties. By proper design of field injection programs the tracers response may therefore be used to estimate fluid saturation if actual rock properties are known. 45 refs., 20 figs., 13 tabs

  4. Coagulation-flocculation pretreatment of oil sands process affected water

    Energy Technology Data Exchange (ETDEWEB)

    Pourrezaei, P.; El-Din, M.G. [Alberta Univ., Edmonton, AB (Canada). Dept. of Civil and Environmental Engineering

    2008-07-01

    This presentation addressed the issue of water use in the oil sands industry and efforts to use this limited resource more efficiently. Three wastewater treatment schemes for oil sands tailings ponds were proposed, notably primary, secondary and tertiary treatment. Primary treatment involves the removal of suspended solids using physical-chemical treatments. Secondary treatment involves the removal of dissolved solids and organics using chemical oxidation, ultrafiltration or nanofiltration. Tertiary treatment involves removal of residual organics/solids using biological activated carbon filtration, sand filtration or reverse osmosis. The composition of oil sands process water (OSPW) was also discussed with reference to suspended solids, salts, hydrocarbons, other dissolved organics (such as naphthenic acids and phenols), ammonia, inorganic compounds and trace elements. The conventional coagulation/flocculation process is essential in industrial wastewater treatment. It is cost effective, easy to operate and energy efficient. The process is used because small suspended and colloidal particles and dissolved constituents cannot be removed quickly by sedimentation. A chemical method must be used. Coagulation/flocculation brings small suspended and colloidal particles into contact so that they collide, stick and grow to a size that settles readily. Alum is the predominant and least expensive water treatment coagulant used for the coagulation/flocculation process. It provides positively charged ions to neutralize the negative charge of colloidal particles resulting in aggregation. It creates big settling flocs that enmesh colloids as it settles. The factors affecting the process include pH, chemical type, chemical concentration, rapid mixing intensity, slow mixing intensity and time. tabs., figs.

  5. Essentials of water systems design in the oil, gas, and chemical processing industries

    CERN Document Server

    Bahadori, Alireza; Boyd, Bill

    2013-01-01

    Essentials of Water Systems Design in the Oil, Gas and Chemical Processing Industries provides valuable insight for decision makers by outlining key technical considerations and requirements of four critical systems in industrial processing plants—water treatment systems, raw water and plant water systems, cooling water distribution and return systems, and fire water distribution and storage facilities. The authors identify the key technical issues and minimum requirements related to the process design and selection of various water supply systems used in the oil, gas, and chemical processing industries. This book is an ideal, multidisciplinary work for mechanical engineers, environmental scientists, and oil and gas process engineers.

  6. The N.A.C.A. Photographic Apparatus for Studying Fuel Sprays from Oil Engine Injection Valves and Test Results from Several Researches

    Science.gov (United States)

    Beardsley, Edward G

    1928-01-01

    Apparatus for recording photographically the start, growth, and cut-off of oil sprays from injection valves has been developed at the Langley Memorial Aeronautical Laboratory. The apparatus consists of a high-tension transformer by means of which a bank of condensers is charged to a high voltage. The controlled discharge of these condensers in sequence, at a rate of several thousand per second, produces electric sparks of sufficient intensity to illuminate the moving spray for photographing. The sprays are injected from various types of valves into a chamber containing gases at pressures up to 600 pounds per square inch. Several series of pictures are shown. The results give the effects of injection pressure, chamber pressure, specific gravity of the fuel oil used, and injection-valve design, upon spray characteristics.

  7. Watered down : overcoming federal inaction on the impact of oil sands development to water resources

    International Nuclear Information System (INIS)

    The oil sands industry is having a negative impact on Canada's fresh water resources and aquatic ecosystems. Members of the Government of the Northwest Territories (NT) and experts from scientific, non-governmental, and First Nations groups have stated at federal hearings that the federal government must involve itself in the protection of Canada's water resources. This report discussed compelling testimony from recent federal hearings by the House of Commons Standing Committee on Environment and Sustainable Development.The federal government must establish enforceable standards for key toxic substances created by oil sands activity. A water-sharing agreement must be established between Alberta, NT, Saskatchewan, and First Nations governments. Other recommendations included the establishment of a peer-reviewed assessment of the health impacts of industrial oil sands development on First Nations communities; the establishment of cumulative effects assessment procedures; the identification and protection of listed species at risk; and the establishment of proactive measures designed to ensure that oil sands operators pay for the environmental damage caused to water resources. 94 refs., 4 figs.

  8. Capillary-driven spontaneous oil/water separation by superwettable twines

    Science.gov (United States)

    Xu, Li-Ping; Dai, Bing; Fan, Junbing; Wen, Yongqiang; Zhang, Xueji; Wang, Shutao

    2015-07-01

    A superwettable twine showing excellent absorption and self-removal capacity of oil and water from oil/water mixtures is reported. Superwettable materials are fabricated by simple modification of commercial twines with plasma and hydrophobic silica nanoparticles, respectively. We show that the absorption and self-transportation of oil and water are driven by the capillary force resulting from the microgaps and microgrooves on twines.A superwettable twine showing excellent absorption and self-removal capacity of oil and water from oil/water mixtures is reported. Superwettable materials are fabricated by simple modification of commercial twines with plasma and hydrophobic silica nanoparticles, respectively. We show that the absorption and self-transportation of oil and water are driven by the capillary force resulting from the microgaps and microgrooves on twines. Electronic supplementary information (ESI) available: Experimental details, characterization and XPS. See DOI: 10.1039/c5nr03670d

  9. Emission control for a glow plug direct injection CI engine using preheated coconut oil blended diesel

    Directory of Open Access Journals (Sweden)

    Suresh R

    2009-10-01

    Full Text Available This paper discusses the experimental study on the reduction of energy utilisation and thereby abiding an indirect control on the emission strategies for a CI engine. Three different methods for the control of emission were carried out and the results were compared. The first method was to improve the combustion by incorporating a copper perforated medium beneath the atomised fuel spray and thereby improve the combustion through vaporisation. The second method was to use coconut oil directly as an additive to diesel. The last method was to preheat the coconut oil blended diesel. The analysis showed that of all the coconut blends, namely, 10% to 50%, 20% blended ratio found a good place in both fuel efficiency and reduced emissions. Similarly, the preheated blends showed still drastic reductions in emissions even for higher proportions of coconut oil.

  10. Titanium Dioxide Nanoparticles Produced in Water-in-oil Emulsion

    International Nuclear Information System (INIS)

    Titanium dioxide (titania) particles were prepared by a water-in-oil emulsion system, and studied for the photodecomposition property of methylene blue. Microemulsion (ME) consisted of water, cyclohexane or octane, and surfactant, such as polyoxyethylene (10) octylphenyl ether (TX-100), polyoxyethylene lauryl ether, or bis (2-ethylhexyl) sodium sulfosuccinate. Titanium tetraisopropoxide (TTIP) was dropped into the ME solution and then titania particles were formed by the hydrolysis reaction between TTIP in the organic solvent and the water in the core of ME. It was found that ME could be classified to the reversed micelle (RM) region and the swelling reversed micelle (SM) region according to the water content. The water droplets in RM were almost monodispersed, where the water content was small. On the other hand, the water droplets in SM had a size distribution, although most of the water molecules associated with surfactant molecules. The size of the particles prepared in the RM region was smaller than the ME size. In contrast, the size of the particles formed in the SM region was larger than the ME size, and coagulation of the particles was observed within a few hours. The smallest diameter of the particles was 2 nm in the system of cyclohexane with TX-100 surfactant when the molar ratio of water to surfactant was 2. Titania particles prepared in this condition were collected as amorphous powder, and converted to anatase phase at less than 500 K, which is lower than the ordinal phase transition temperature. These anatase phase titania particles only showed a significant photodecomposition of methylene blue by illumination with a Xenon lamp

  11. Titanium Dioxide Nanoparticles Produced in Water-in-oil Emulsion

    Energy Technology Data Exchange (ETDEWEB)

    Mori, Yasushige, E-mail: ymori@mail.doshisha.ac.jp; Okastu, Yasuhiro; Tsujimoto, Yuki [Doshisha University, Department of Chemical Engineering and Materials Science (Japan)

    2001-06-15

    Titanium dioxide (titania) particles were prepared by a water-in-oil emulsion system, and studied for the photodecomposition property of methylene blue. Microemulsion (ME) consisted of water, cyclohexane or octane, and surfactant, such as polyoxyethylene (10) octylphenyl ether (TX-100), polyoxyethylene lauryl ether, or bis (2-ethylhexyl) sodium sulfosuccinate. Titanium tetraisopropoxide (TTIP) was dropped into the ME solution and then titania particles were formed by the hydrolysis reaction between TTIP in the organic solvent and the water in the core of ME. It was found that ME could be classified to the reversed micelle (RM) region and the swelling reversed micelle (SM) region according to the water content. The water droplets in RM were almost monodispersed, where the water content was small. On the other hand, the water droplets in SM had a size distribution, although most of the water molecules associated with surfactant molecules. The size of the particles prepared in the RM region was smaller than the ME size. In contrast, the size of the particles formed in the SM region was larger than the ME size, and coagulation of the particles was observed within a few hours. The smallest diameter of the particles was 2 nm in the system of cyclohexane with TX-100 surfactant when the molar ratio of water to surfactant was 2. Titania particles prepared in this condition were collected as amorphous powder, and converted to anatase phase at less than 500 K, which is lower than the ordinal phase transition temperature. These anatase phase titania particles only showed a significant photodecomposition of methylene blue by illumination with a Xenon lamp.

  12. Effects of garlic oil and two of its major organosulfur compounds, diallyl disulfide and diallyl trisulfide, on intestinal damage in rats injected with endotoxin

    International Nuclear Information System (INIS)

    Garlic and its active components are known to possess antioxidant and antiinflammatory effects. The present study investigated the effects of garlic oil and its organosulfur compounds on endotoxin-induced intestinal mucosal damage. Wistar rats received by gavage 50 or 200 mg/kg body weight garlic oil (GO), 0.5 mmol/kg body weight diallyl disulfide or diallyl trisulfide, or the vehicle (corn oil; 2 ml/kg body weight) every other day for 2 weeks before being injected with endotoxin (i.p., 5 mg/kg body weight). Control rats were administered with corn oil and were injected with sterile saline. Samples for the measurement of proinflammatory cytokines were collected 3 h after injection, and all other samples were collected 18 h after injection. The low dose of GO suppressed endotoxin-induced inducible nitric oxide synthase (iNOS) activity, ulceration, and apoptosis in the intestinal mucosa (P < 0.05). The high dose of GO significantly lowered the peripheral level of nitrate/nitrite and endotoxin-induced iNOS activity in the intestinal mucosa (P < 0.05) but worsened intestinal mucosal damage accompanied by elevated peripheral proinflammatory cytokines. Diallyl trisulfide but not diallyl disulfide showed similar toxic effect as that of high-dose GO. These results suggest the preventive effect and possible toxicity of garlic oil and its organosulfur compounds in endotoxin-induced systemic inflammation and intestinal damage

  13. An intelligent superwetting PVDF membrane showing switchable transport performance for oil/water separation.

    Science.gov (United States)

    Tao, Mimi; Xue, Lixin; Liu, Fu; Jiang, Lei

    2014-05-01

    A superamphiphilic poly(vinylidene fluoride) (PVDF) membrane with superoleophobicity under water and superhydrophobicity under oil is successfully prepared. Due to the switchable transport performance, the membrane is applicable to the separation of various oil-in-water and water-in-oil emulsions with a droplet size greater than 20 nm, and shows superior permeability and antifouling properties, as well as a high separation efficiency. PMID:24677285

  14. A Microfluidic Method to Assess Emulsion Stability in Crude-Oil/Water Separators

    OpenAIRE

    Krebs, T.; Schroën, C.G.P.H.; Boom, R. M.

    2011-01-01

    The control of emulsion stability and droplet size is of crucial importance for oil production, especially for the processes of crude/oil water separation and cleanup of produced water. To recover pure oil and water, coalescence between droplets needs to take place, the extent of which will depend on the flow parameters as well as on the presence of emulsifying agents. For a successful separation, the demulsification time of the mixture must be smaller than its residence time in the separator...

  15. Preparation and Characterization of Salbutamol Sulphate Loaded Ethyl Cellulose Microspheres using Water-in-Oil-Oil Emulsion Technique

    OpenAIRE

    Nath, Bipul; Kanta Nath, Lila; Mazumder, Bhaskar; Kumar, Pradeep; Sharma, Niraj; Pratap Sahu, Bhanu

    2010-01-01

    The aim of this study was to formulate and evaluate microencapsulated controlled release preparations of a highly water/soluble drug, salbutamol sulphate by (water in oil) in oil emulsion technique using ethyl cellulose as the retardant material. Various processing and formulation parameters such as drug/polymer ratio, stirring speed, volume of processing medium were optimized to maximize the entrapment. The release of salbutamol sulphate from ethyl cellulose microsphere was compared and poss...

  16. Effects of Water Injection into Fractured Geothermal Reservoirs: A Summary of Experience Worldwide

    Energy Technology Data Exchange (ETDEWEB)

    Horne, Roland N.

    1982-06-01

    Reinjection of water into fractured geothermal reservoirs holds potential both for improvement and degradation of total energy recovery. The replacement of reservoir fluid can mean support of placement of reservoir pressures and also more efficient thermal energy recovery, but at the same time the premature invasion of reinjected water back into production wells through high permeability fractures can reduce discharge enthalpy and hence deliverability and useful energy output. Increases in reservoir pressure and maintenance of field output have been observed in operating fields, but unfortunately so too have premature thermal breakthroughs. The design of reinjection schemes, therefore, requires careful investigation into the likely effects, using field experimentation. This paper summarizes field experience with reinjection around the world, with the intention of elucidating characteristics of possible problems. The results summarized in this paper fall into three categories of interest: permeability changes dye to injection (both increases and decreases); the path followed by injected water (as indicated by tracer tests); and the thermal and hydraulic influences of injection on the reinjection well itself and on surrounding producers. [DJE-2005

  17. Experimentally studying TV3-117 gas-turbine unit characteristics at superheated water injection into a compressor

    Science.gov (United States)

    Favorskii, O. N.; Alekseev, V. B.; Zalkind, V. I.; Zeigarnik, Yu. A.; Ivanov, P. P.; Marinichev, D. V.; Nizovskii, V. L.; Nizovskii, L. V.

    2014-05-01

    The results from experimentally studying TV3-117 gas-turbine unit (GTU) characteristics at injection of cold and superheated (metastable) water to the inlet of the GTU compressor are presented. In the latter case, the finer water atomization is obtained. The water injection makes it possible to considerably increase the unit power. At a constant temperature of the working fluid downstream of the turbine combustion chamber, water injection in an amount of 1% of the air flow rate provides an increase in the turbine power by approximately 12% and expands GTU controlling potentialities. The use of the metastable superheated water atomization enables one to more reliably implement the technology of water injection into a compressor, especially into intermediate compressor stages. However, it requires accounting for operational conditions of particular installation. Due to small water droplet residence time in the compressor flow path, even with fine water atomization, in aircraft engine derivative power turbines, about 15-20% of moisture injected have no time to completely evaporate within the compressor. When injecting cold water, this figure is from 5 to 10% larger.

  18. Performance Characteristics and Analysis of 4-Stroke Single Cylinder Diesel Engine Blend With 50% of Honne Oil at Various Fuel Injection Pressures

    OpenAIRE

    R. Bhaskar Reddy; B. Siddeswararao

    2014-01-01

    In future demand for fossil fuels and environmental effects, a number of renewable sources of energy have been studied in worldwide. An attempt is made to apt of vegetable oil for diesel engine operation, without any change in its old construction. One of the important factors which influence the performance and emission characteristics of D.I diesel engine is fuel injection pressure. In this project honne oil has to be investigated in a constant speed, on D.I diesel engine wit...

  19. PERFORMANCE, EMISSION AND COMBUSTION CHARACTERISTICS OF A METHYL ESTER SUNFLOWER OILEUCALYPTUS OIL IN A SINGLE CYLINDER AIR COOLED AND DIRECT INJECTION DIESEL ENGINE

    OpenAIRE

    TAMILVENDHAN.D,; ILANGOVAN.V

    2011-01-01

    Biomass derived fuels are preferred as alternative fuels for IC engine due to its abundant availability and renewable nature. In the present work the performance, emission and combustion characteristics of a single cylinder constant speed , direct injection diesel engine using methyl ester of sun flower oil – eucalyptus oil blend as an alternative fuel were studied and the results are compared with thestandard diesel fuel operation. Result indicated that 50% reduction in smoke, 34% reduction ...

  20. Multicommuted flow injection method for fast photometric determination of phenolic compounds in commercial virgin olive oil samples.

    Science.gov (United States)

    Lara-Ortega, Felipe J; Sainz-Gonzalo, Francisco J; Gilbert-López, Bienvenida; García-Reyes, Juan F; Molina-Díaz, Antonio

    2016-01-15

    A multicommuted flow injection method has been developed for the determination of phenolic species in virgin olive oil samples. The method is based on the inhibitory effect of antioxidants on a stable and colored radical cation formation from the colorless compound N,N-dimethyl-p-phenylenediamine (DMPD(•+)) in acidic medium in the presence of Fe(III) as oxidant. The signal inhibition by phenolic species and other antioxidants is proportional to their concentration in the olive oil sample. Absorbance was recorded at 515nm by means of a modular fiber optic spectrometer. Oleuropein was used as the standard for phenols determination and 6-hydroxy-2,5,7,8-tetramethylchroman-2-carboxylic acid (trolox) was the reference standard used for total antioxidant content calculation. Linear response was observed within the range of 250-1000mg/kg oleuropein, which was in accordance with phenolic contents observed in commercial extra virgin olive oil in the present study. Fast and low-volume liquid-liquid extraction of the samples using 60% MeOH was made previous to their insertion in the flow multicommuted system. The five three-way solenoid valves used for multicommuted liquid handling were controlled by a homemade electronic interface and Java-written software. The proposed approach was applied to different commercial extra virgin olive oil samples and the results were consistent with those obtained by the Folin Ciocalteu (FC) method. Total time for the sample preparation and the analysis required in the present approach can be drastically reduced: the throughput of the present analysis is 8 samples/h in contrast to 1sample/h of the conventional FC method. The present method is easy to implement in routine analysis and can be regarded as a feasible alternative to FC method. PMID:26592643

  1. Oil-water liquid flow rate determined from measured pressure drop and water hold-up in horizontal pipes

    OpenAIRE

    René Oliemans

    2011-01-01

    Stimulated by rapid progress in down-hole measuring techniques production engineers wonder whether in the near-future monitoring of oil/water production rates for horizontal wells can become possible on the basis of measured oil/water pressure losses and water hold-ups. A complicating issue is that these measured data depend on the oil and water flow patterns. The question then is if we use a flow-pattern-dependent model for pressure drop and water hold-up in an inverse mode, what then will b...

  2. A multi-functional oil-water separator from a selectively pre-wetted superamphiphobic paper.

    Science.gov (United States)

    Ge, Dengteng; Yang, Lili; Wang, Chenbo; Lee, Elaine; Zhang, Yongquan; Yang, Shu

    2015-04-11

    A multi-functional oil-water separator is prepared from a paper towel spray coated with superamphiphobic (i.e., superhydrophobic and superoleophobic) nanoparticles. After the separator is pre-wetted with ethanol, followed by water, water can be removed from the light oil-water mixture and emulsions by gravity with high separation efficiency (99.9%) and separation flux. Vice versa, heavy oil can be removed by gravity on an ethanol-oil pre-wetted SA-paper. PMID:25750982

  3. The Geopolitics of Water and Oil in Turkey

    International Nuclear Information System (INIS)

    Throughout history, few nations have been as successful in leveraging their geographic location as Turkey. As the center of two of the most powerful civilizations of all time, the Byzantine and Ottoman Empires, Turkey was the bridge between East and West, a bustling center of trade and a strategic economic and political nexus between regions of the world. In addition to its geographic power, Turkey has historically possessed substantial water resources. Unlike many water parched areas of the Middle East, Turkey's water capacity has allowed it to grow large populations and build elaborate cities. In the modern era, Turkey once again has an opportunity to regain its historical role, as the state where today's geopolitics of energy coincides with Turkey's traditional geopolitics of water. Turkey's central location, this time not between East and West, but between producers and consumers of energy, gives it a central, geopolitical role in world affairs, both in oil and gas. Moreover, Turkey's water resources can be utilized to reinforce Turkey's strategic energy role in the region, by building a strategy of cooperation with water-poor countries from the Levant to the Arabian Peninsula. Throughout history, water and energy have been among the most fundamental resources of civilization, at the very base of Maslow's hierarchy of needs essential to fostering human growth and development for thousands of years. It is seldom appreciated how linked water and energy truly are. Producing, transferring, and supplying energy requires a significant amount of water, just as the extraction, purification, and even desalination of water requires a significant amount of energy. As both energy and water grow scarcer throughout the future, nations such as Turkey can gain considerable influence as a result of their geographic locations and natural endowments. Turkey can benefit from pipeline diplomacy, taking advantage of its geographical location to make it a crossroads of multiple commodity pipeline projects. Through a series of water and energy pipelines, Turkey can gain significant political, economic, and social influence, while contributing to regional integration and stability. This paper addresses the background to Turkey's geopolitical future, with regard to both energy and water resources. It also aims to provide some suggestions as to how Turkey can take greater advantage of its geopolitical potential. Section I of the paper discusses Turkey's geopolitical potential; Section II details Turkey's complex and conflicted political relationships with regional nations; Section III examines specific pipeline projects held back by political conflicts; Section IV conclusively analyzes the situation and offers policy suggestions for Turkey. (author)

  4. The Geopolitics of Water and Oil in Turkey

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-07-01

    Throughout history, few nations have been as successful in leveraging their geographic location as Turkey. As the center of two of the most powerful civilizations of all time, the Byzantine and Ottoman Empires, Turkey was the bridge between East and West, a bustling center of trade and a strategic economic and political nexus between regions of the world. In addition to its geographic power, Turkey has historically possessed substantial water resources. Unlike many water parched areas of the Middle East, Turkey's water capacity has allowed it to grow large populations and build elaborate cities. In the modern era, Turkey once again has an opportunity to regain its historical role, as the state where today's geopolitics of energy coincides with Turkey's traditional geopolitics of water. Turkey's central location, this time not between East and West, but between producers and consumers of energy, gives it a central, geopolitical role in world affairs, both in oil and gas. Moreover, Turkey's water resources can be utilized to reinforce Turkey's strategic energy role in the region, by building a strategy of cooperation with water-poor countries from the Levant to the Arabian Peninsula. Throughout history, water and energy have been among the most fundamental resources of civilization, at the very base of Maslow's hierarchy of needs essential to fostering human growth and development for thousands of years. It is seldom appreciated how linked water and energy truly are. Producing, transferring, and supplying energy requires a significant amount of water, just as the extraction, purification, and even desalination of water requires a significant amount of energy. As both energy and water grow scarcer throughout the future, nations such as Turkey can gain considerable influence as a result of their geographic locations and natural endowments. Turkey can benefit from pipeline diplomacy, taking advantage of its geographical location to make it a crossroads of multiple commodity pipeline projects. Through a series of water and energy pipelines, Turkey can gain significant political, economic, and social influence, while contributing to regional integration and stability. This paper addresses the background to Turkey's geopolitical future, with regard to both energy and water resources. It also aims to provide some suggestions as to how Turkey can take greater advantage of its geopolitical potential. Section I of the paper discusses Turkey's geopolitical potential; Section II details Turkey's complex and conflicted political relationships with regional nations; Section III examines specific pipeline projects held back by political conflicts; Section IV conclusively analyzes the situation and offers policy suggestions for Turkey. (author)

  5. The Determination of Several Spray Characteristics of a High-Speed Oil Engine Injection System with an Oscilloscope

    Science.gov (United States)

    Hicks, Chester W; Moore, Charles S

    1928-01-01

    An investigation was conducted to determine the injection lag, duration of injection, and spray start and cut-off characteristics of a fuel injection system operated on an engine and injecting fuel into the atmosphere.

  6. A simulation study on the enhancement of the shift reaction by water injection into a gasifier

    International Nuclear Information System (INIS)

    Although coal gasification is a clean and efficient use of coal, a reduction of CO2 emissions is needed to mitigate global warming. The aim of this study was to improve the thermal efficiency of fuel production and electricity generation by dry coal feed gasification. The primary cause of thermal efficiency loss is steam use in a water-gas shift reactor. The shift reactor, installed downstream from the gasifier, uses a catalyst to adjust the H2/CO ratio of the syngas. We have proposed a new process in which water is injected at the outlet of the gasifier and is vaporized to enhance the extent of the shift reaction. This process utilizes the high temperature of the syngas, which is sufficient for the shift reaction to occur without a catalyst. We have developed a model that incorporates the shift reaction velocity to evaluate our proposed process. In an optimized 5-stage water supply case, we found that the CO conversion reaches 9.9% at a water/syngas ratio of 0.14 mol/mol (water/CO = 0.25 mol/mol); the CO conversion needed for dimethyl ether production is 31%. This new process can improve the efficiency and reduce the cost of coal gasification. -- Highlights: ? The process enhancing the shift reaction by water injection into a Gasifier was proposed. ? Five-stage water supply to prevent a rapid temperature drop is optimal. ? CO conversion reaches 9.9% at a water/syngas ratio of 0.14 mol/mol (water/CO = 0.25 mol/mol). ? Amount of steam required for the shift reactor in fuel production process can be reduced.

  7. Factors governing partial coalescence in oil-in-water emulsions.

    Science.gov (United States)

    Fredrick, Eveline; Walstra, Pieter; Dewettinck, Koen

    2010-01-15

    The consequences of the instability mechanism partial coalescence in oil-in-water food emulsions show a discrepancy. On the one hand, it needs to be avoided in order to achieve an extended shelf life in food products like sauces, creams and several milk products. On the other hand, during the manufacturing of products like ice cream, butter and whipped toppings partial coalescence is required to achieve the desired product properties. It contributes to the structure formation, the physicochemical properties (stability, firmness,...) and the sensory perception, like fattiness and creaminess of the final food products. This review critically summarises the findings of partial coalescence in oil-in-water emulsions in order to provide insight in how to enhance and retard it. Next to the pioneering work, a large set of experimental results of more recent work is discussed. First, the general mechanism of partial coalescence is considered and a distinction is made between partial and 'true' coalescence. The main differences are: the required solid particles in the dispersed oil phase, the formation of irregular clusters and the increased aggregation rate. Second, the kinetics of partial coalescence is discussed. In more detail, potential parameters affecting the rate of partial coalescence are considered by means of the encounter frequency and capture efficiency of the fat globules. The flow conditions, the fat volume fraction and the physicochemical properties of continuous aqueous phase affect both the encounter frequency and capture efficiency while the actual temperature, temperature history and the composition and formulation of the emulsion mainly affect the capture efficiency. PMID:19913777

  8. Separation mechanisms and fluid flow in oil/water separation

    Energy Technology Data Exchange (ETDEWEB)

    Celius, H.K.; Knudsen, B. [IKU Petroleumsforskning A/S, Trondheim (Norway); Hafskjold, B.; Hansen, E.W. [Selskapet for Industriell og Teknisk Forskning, Trondheim (Norway)

    1996-12-31

    This paper describes work aimed at physical and numerical modeling of separation rates of oil/water systems in order to establish better tools for design and operation of offshore operators. This work aims to integrate the chemical and physical phenomena behind coalescence and settling with those of fluid flow in the system, in order to develop tools for design and operational analysis of separation equipment. The work includes the development of a high pressure, bench-scale test rig to perform separation tests on live oil and water samples, and a rationale in the form of a computer code that can be used to interpret the test results and transform them to a form siutable for operational purposes. This involves a formulation of a mathematical description of the chemical and physical mechanisms behind the emulsification and separation process, and to establish a link to the hydrdynamic properties of the separator vessel. The Emucol computer program is used in the analysis. 12 refs., 5 figs.

  9. Breaking of Oil -Water Emulsion for the Improvement of Oil Recovery Operations in the Niger Delta Oilfields

    Directory of Open Access Journals (Sweden)

    C. Ijogbemeye Oseghale

    2012-11-01

    Full Text Available Emulsified water is generally present in crude oil as a result of mixing occurring during production operations. The formation of emulsion leads to problems in production and also transportation. Therefore the need to break oil/water emulsions system through demulsification process using chemical surfactants for improved oil recovery operations. Selected cationic surfactants were effective in separating oil-water emulsions expected during a surfactant/polymer (SP process for improved oil recovery. The aqueous phase of the emulsion contained an anionic surfactant blend, alcohol and partially hydrolyzed polyacrylamide. Brine composition was a suitable mixture of formation brine with brine from polymer drive. The crude oil had an API gravity of 47.2. Bottle tests were conducted at ambient temperature, which is near the reservoir temperature. Both oil and water phases of acceptable quality were obtained after settling upon addition of 200ppm of octytrimethylammonium bromide (C8TAM at ambient temperature. Microscopy image showed significant coalescence after only 1 minute in C8TAM system as the cationic surfactant reduced electrostatic repulsion among drops and shifted system behavior towards the balanced state between hydrophilic and lipohilic effect well-known to reduce emulsion stability. The amount of cationic surfactant may be reduced by reduced by adding it simultaneously with anionic demulsifier resin.

  10. Laboratory evaluation and field application of a water swellable polymer for fracture shutoff in injection wells

    Energy Technology Data Exchange (ETDEWEB)

    Creel, Prentice [Kinder Morgan, Houston, TX (United States); Vasquez, Julio; Eoff, Larry [Halliburton, Rio de Janeiro, RJ (Brazil)

    2008-07-01

    This paper presents the laboratory evaluation and field application of a water swelling polymer (WSP) that can be bullheaded to shut off fractures in injection wells. The WSP is capable of absorbing 30 to 400 times its own weight in water. The material was evaluated for its effectiveness in providing controllable swelling rates, shutting off the flow of water in synthetic cores with simulated fractures, and providing long-term stability in H{sub 2}S and CO{sub 2} environments. In addition, this paper presents the field implementation of this technology along with successful case histories in west Texas. The water swellable material is mixed on the fly, entering fissures and fracture systems as they swell without invading the matrix of the rock. The rate of absorption can be controlled based on the specified particle size ranging from 600-mesh size up to 14 mm and the type of carrier fluid. This WSP presents an innovative technology for fracture, fissure, and highly eroded out permeability shutoff to improve the sweep efficiency of water and gas injection. In addition, the WSP is resistant to acid contamination and CO{sub 2} and H{sub 2}S environments. To date, more than 200 jobs have been performed with this technology. (author)

  11. Remediation of an Organic Fluid Present Below the Water Table by Steam Injection Above

    Science.gov (United States)

    Gudbjerg, J.; Jensen, K. H.; Sonnenborg, T. O.

    2001-12-01

    Injection of steam in the subsurface has been utilized to remediate contaminated sites where nonaqeuous phase liquid (NAPL) was present both above and below the water table. Steam injection is efficient because the vapor pressure of contaminants increase dramatically with temperature. Futhermore, since two immiscible liquids will boil when the sum of their vapor pressures is equal to the surrounding pressure all NAPLs will start to boil below the boiling point of water. This may be a dominant mechanism for the mass transfer of NAPL into the steam zone. In many cases a steady-state steam zone will be present above a saturated zone containing NAPL, which then will be heated by conduction. At a certain temperature boiling will occur and due to bouyancy gas will be transported from the saturated zone into the steam zone. This mass transfer mechanism is orders of magnitude faster than diffusionevaporation. Two-dimensional experiments in a sand box with the interior dimensions 122 \\times 58 \\times 8.5 cm were carried out to investigate this mechanism. The sand box was packed with a low permeable bottom layer and a high permeable top layer. TCE was injected at the top of the low permeable layer, which prevented it from further downward migration. The water table was located in the high permeable layer above the contaminant. Steam was injected in the left hand side of the sand box and effluent gasses were extracted at the right hand side. A steady-state steam zone formed in the top of the high permeable layer and the saturated zone below was only heated by conduction. When the temperature in the contaminated area reached approximately 74 oC boiling of TCE and water occured and the vapors were transported up in the unsaturated steam zone. This could be registered from the outflow of steam where separate phase TCE appeared in the condenser. The experiment was modeled using the numerical code T2VOC, which simulates multidimensional, non-isothermal, multiphase flow and transport in porous media. For these experiments it was shown that when heating from above with steam injection, TCE present below the water table was transported upwards to the steam zone and not further downward.

  12. Study of the fluid dynamic and the efficiency of displacement in oil-water systems; Estudo da fluidodinamica e da eficiencia de deslocamento em sistemas agua-oleo

    Energy Technology Data Exchange (ETDEWEB)

    Fiorese, Eliana K.; Quadri, Marintho B.; Machado, Ricardo A.F.; Nogueira, Andre L.; Lopes, Toni J. [Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil). Dept. de Engenharia Quimica e de Alimentos; Baptista, Renan M. [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES)

    2004-07-01

    Several operations and procedures in the oil industry are related to immiscible displacement of a fluid by another one. Some examples can be listed: the natural and artificial oil elevation from wells, the pumping of high viscosity oils through pipelines using water injection and secondary oil recovery. The performance of the last one is a direct consequence of the interfacial phenomena inherent to oil/water systems. As occur in oil leakages from submarine pipelines, the phase inversion phenomenon can also be considered in this context. Therefore, it is of major importance to realize experimental analysis of the oil/water interface stability and the facts that leads to the fingering phenomenon appearance. This phenomenon is represented into the other one like one or more fingers. The mathematical model used to describe the immiscible displacement of another one is initially developed to Hele-Shaw cells. Experimental observations with a Hele-Shaw cell enable the evaluation of the proposed model and its capability to adequately describe the viscous fingering phenomenon related to physical (density, viscosity and interfacial tension) and geometric properties of the system. (author)

  13. 75 FR 76742 - Detecting Oil Leaks From Vessels Into the Water

    Science.gov (United States)

    2010-12-09

    ...device to detect loss of oil from a vessel into the...the size and impact of an oil spill by alerting the vessel's...not stop the outflow of oil into the water. Between...Guard conducted a study of technology used to detect the...

  14. Natural oil slicks fuel surface water microbial activities in the northern Gulf of Mexico

    Directory of Open Access Journals (Sweden)

    KaiZiervogel

    2014-05-01

    Full Text Available We conducted a series of roller tank incubations with surface seawater from the Green Canyon oil reservoir, northern Gulf of Mexico, amended with either a natural oil slick (GCS-oil or pristine oil. The goal was to test whether bacterial activities of natural surface water communities facilitate the formation of oil-rich marine snow (oil snow. Although oil snow did not form during any of our experiments, we found specific bacterial metabolic responses to the addition of GCS-oil that profoundly affected carbon cycling within our 4-days incubations. Peptidase and ?-glucosidase activities indicative of bacterial enzymatic hydrolysis of peptides and carbohydrates, respectively, were suppressed upon the addition of GCS-oil relative to the non-oil treatment, suggesting that ascending oil and gas initially inhibits bacterial metabolism in surface water. Biodegradation of physically dispersed GCS-oil components indicated by the degradation of lower molecular weight n-alkanes as well as the rapid transformation of particulate oil-carbon (C: N >40 into the DOC pool, led to the production of carbohydrate- and peptide-rich degradation byproducts and bacterial metabolites such as transparent exopolymer particles (TEP. TEP formation was highest at day 4 in the presence of GCS-oil; in contrast, TEP levels in the non-oil treatment already peaked at day 2. Cell-specific enzymatic activities closely followed TEP concentrations in the presence and absence of GCS-oil. These results demonstrate that the formation of oil slicks and activities of oil-degrading bacteria result in a temporal offset of microbial cycling of organic matter, affecting food web interactions and carbon cycling in surface waters over cold seeps.

  15. Morphology of soy protein isolate at oil/water and oil/air interfaces

    Scientific Electronic Library Online (English)

    Samira J., Fayad; Betina G., Zanetti-Ramos; Pedro L. M., Barreto; Valdir, Soldi; Edson, Minatti.

    2013-06-01

    Full Text Available Neste artigo, as propriedades emulsificantes da proteína isolada de soja (SPI) foram evidenciadas mostrando que estas macromoléculas sofrem mudanças conformacionais quando adsorvidas em interfaces. Investigou-se a conformação das cadeias proteicas ancoradas nas regiões interfaciais de emulsões de ól [...] eo em água (o/a) através de técnicas de espalhamento de raios X (SAXS) e de imagem (microscopia eletrônica de varredura (SEM)). O valor médio do raio de giro (Rg) da SPI (aq) é 20 nm e aumenta para 30 nm em emulsões o/a; as proteínas atuam como moléculas anfifílicas expondo seus núcleos hidrofóbicos ao óleo e os resíduos hidrofílicos à fase aquosa. Este valor ainda é maior após o spray drying das emulsões, na interface o/ar das respectivas microcápsulas. As paredes das microcápsulas são fractais de objetos agregados com superfícies rugosas, que são alisadas pela presença de um agente de reticulação. Abstract in english Herein, the emulsifying properties of soy protein isolate (SPI) were highlighted by showing that the macromolecules undergo conformational changes when adsorbed at interfaces. The conformation of protein chains nested at the interfacial region of oil in water (o/w) emulsions by means of X-ray scatte [...] ring (SAXS) and direct imaging (scanning electron microscopy (SEM)) techniques was investigated. The mean radius of gyration (Rg) for SPI (aq) is 20 nm and increases up to 30 nm in o/w emulsions; the proteins act as amphiphilic molecules by exposing their hydrophobic core to the oil and their hydrophilic amino acid residues to the water phase. By spray drying the emulsions, it was also possible to measure the size (Rg = 40 nm) and to evaluate the morphology of these proteins at the oil/air interface of the respective microcapsules. The walls of microcapsules are fractals of clustered objects with rough surfaces, which are smoothed by the presence of a cross-linking agent.

  16. Systematic bias in the measurement of water in oils by tubular oven evaporation and azeotropic distillation.

    Science.gov (United States)

    Margolis, S A; Mele, T

    2001-10-15

    Water in oil has been measured by tubular oven evaporation and by azeotropic distillation into a coulometric moisture analyzer. The results of these measurements were compared to the results obtained by volumetric titration of water in oil. The volumetric measurements were consistently higher than the measurements made by tubular oven evaporation or azeotropic distillation. A mass balance study was performed by volumetric Karl Fischer titration of the water in the oil that remained in the tubular oven and in the distillation apparatus. This study indicated that measurable amounts of water were not removed after exhaustive evaporation or distillation. The sum of the water removed by distillation from toluene and that remaining in the distillation chamber was equal to the amount of water measured in the oil by the volumetric method. The data are consistent with the existence of an oil-water azeotrope that does not release water upon evaporation at 160 degrees C or upon dissolution in toluene and distillation of the water-toluene azeotrope. These results were obtained for oils varying in viscosity from 8 to 850 m2/s, and the amount of water remaining associated with the oil appears to be dependent upon the composition of the oil and the method of analysis. PMID:11681452

  17. Decontamination of water polluted with oil through the use of tanned solid wastes

    International Nuclear Information System (INIS)

    The ability of chrome shavings (CS) and buffing dusts of crust leather (BDCL) to remove oily wastes from demineralized water and natural seawater was investigated. The aim of the study was to discover environmentally friendly alternatives for the disposal of solid tannery wastes. The specific surface area of the CS and the BDCL were examined to determine ash content; chromium oxide; fat; and the pH of soluble matter. Scanning electron microscopy (SEM) was then used to examine the structure and morphology of the samples. Three types of oil were used in the experiment: diesel motor oil; premium motor oil; and used motor oil. Sorbent materials were added to a beaker containing 1000 ml of water and 5.5 g of oil. The amount of residual oil in the water was then extracted with petroleum ether. The amount of oil sorbed on the wastes was calculated by subtracting the amount of residual oil in water from the initial mass of oil added to the beakers. Results suggested that the tanned solid wastes efficiently removed the oil from the water. It was concluded that the waste materials were able to absorb many times their weight in oil. 21 refs., 4 tabs., 2 figs

  18. Smart Fiber Membrane for pH-Induced Oil/Water Separation.

    Science.gov (United States)

    Li, Jin-Jin; Zhou, Yin-Ning; Luo, Zheng-Hong

    2015-09-01

    Wastewater contaminated with oil or organic compounds poses threats to the environment and humans. Efficient separation of oil and water are highly desired yet still challenging. This paper reports the fabrication of a smart fiber membrane by depositing pH-responsive copolymer fibers on a stainless steel mesh through electrospinning. The cost-effective precursor material poly(methyl methacrylate)-block-poly(4-vinylpyridine) (PMMA-b-P4VP) was synthesized using copper(0)-mediated reversible-deactivation radical polymerization. The pH-responsive P4VP and the underwater oleophilic/hydrophilic PMMA confer the as-prepared membrane with switchable surface wettability toward water and oil. The three-dimensional network structure of the fibers considerably strengthens the oil/water wetting property of the membrane, which is highly desirable in the separation of oil and water mixtures. The as-prepared fiber membrane accomplishes gravity-driven pH-controllable oil/water separations. Oil selectively passes through the membrane, whereas water remains at the initial state; after the membrane is wetted with acidic water (pH 3), a reverse separation is realized. Both separations are highly efficient, and the membrane also exhibits switchable wettability after numerous cycles of the separation process. This cost-effective and easily mass-produced smart fiber membrane with excellent oil-fouling repellency has significant potential in practical applications, such as water purification and oil recovery. PMID:26293145

  19. 40 CFR 60.4340 - How do I demonstrate continuous compliance for NOX if I do not use water or steam injection?

    Science.gov (United States)

    2010-07-01

    ...compliance for NOX if I do not use water or steam injection? 60.4340 Section 60.4340...compliance for NOX if I do not use water or steam injection? (a) If you are not using water or steam injection to control NOX emissions,...

  20. Characterization of Emulsions of Fish Oil and Water by Cryo Scanning Electron Microscopy

    DEFF Research Database (Denmark)

    Jensen, Louise Helene Søgaard; Horn, Anna Frisenfeldt; Jacobsen, Charlotte; Nielsen, Nina Skall; Horsewell, Andy

    2010-01-01

    Addition of fish oil to industrially prepared food products is attractive to the food industry because of the well-documented health effects of the omega 3 fatty acids in the fish oil [1]. Polyunsaturated Fatty Acids including omega 3 fatty acids are highly susceptible to lipid oxidation due to the many double bonds. Emulsions of fish oil in water are potential candidates for a delivery system of fish oil to food products. It has been suggested that oxidation of oil-in-water emulsions is initiat...

  1. Polymer treatments for D Sand water injection wells: Sooner D Sand Unit Weld County, Colorado. Final report, April 1997

    Energy Technology Data Exchange (ETDEWEB)

    Cannon, T.J.

    1998-10-01

    Polymer-gel treatments in injection wells were evaluated for improving sweep efficiency in the D Sandstone reservoir at the Sooner Unit, Weld County, Colorado. Polymer treatments of injection wells at the Sooner Unit were expected to improve ultimate recovery by 1.0 percent of original-oil-in-place of 70,000 bbl of oil. The Sooner D Sand Unit was a demonstration project under the US Department of Energy Class I Oil Program from which extensive reservoir data and characterization were obtained. Thus, successful application of polymer-gel treatments at the Sooner Unit would be a good case-history example for other operators of waterfloods in Cretaceous sandstone reservoirs in the Denver Basin.

  2. Water-rock interaction in CO2 sequestration in a depleted oil reservoir pilot test

    International Nuclear Information System (INIS)

    A field test of CO2 sequestration in the Neogene Minghuazhen Formation in the Bohai Bay Basin (BBB-Nm test) is presented, where the first Chinese pilot project of CO2 storage in a depleted oil reservoir was implemented. A total of 305 t CO2 was injected into the sandstone reservoir. The process of injection and pre/post-injection monitoring are described, especially for the geochemical monitoring in the field test. Results show that CO2 flux monitoring successfully tracked the injected CO2. Chemical analyses of post-injection brine samples indicate brine may have not been affected by CO2 injection during the monitoring period, which needs to be confirmed with further investigations before extending the results to deep saline aquifers. (authors)

  3. Experimental investigations of a four-stroke single cylinder direct injection diesel engine operated on dual fuel mode with producer gas as inducted fuel and Honge oil and its methyl ester (HOME) as injected fuels

    Energy Technology Data Exchange (ETDEWEB)

    Banapurmath, N.R.; Tewari, P.G. [Department of Mechanical Engineering, B.V.B. College of Engineering and Technology, Hubli 580031, Karnataka (India); Hosmath, R.S. [Department of Mechanical Engineering, K.L.E Society' s College of Engineering and Technology, Belgaum, Karnataka (India)

    2008-09-15

    In order to meet the energy requirements, there has been growing interest in alternative fuels like biodiesels, methyl alcohol, ethyl alcohol, biogas, hydrogen and producer gas to provide a suitable diesel oil substitute for internal combustion engines. Vegetable oils present a very promising alternative to diesel oil since they are renewable and have similar properties. Vegetable oils offer almost the same power output with slightly lower thermal efficiency when used in diesel engine [Srivastava A, Prasad R. Triglycerides-based diesel fuels. Renew Sustain Energy Rev 2000;4:111-33.; Vellguth G. Performance of vegetable oils and their monoesters as fuels for diesel engines. SAE 831358, 1983.; Demirbas A. Biodiesel production from vegetable oils via catalytic and non-catalytic supercritical methanol transesterification methods. Int J Prog Energy Combust Sci 2005;31:466-87.; Jajoo BN, Keoti RS. Evaluation of vegetable oils as supplementary fuels for diesel engines. In: Proceedings of the XV national conference on IC engines and combustion, Anna University Chennai, 1997.; Altin R, Cetinkaya S, Yucesu HS. The potential of using vegetable oil fuels as fuel for diesel engines. Int J Energy Convers Manage 2000;42:529-38, 248.; Gajendra Babu MK, Chandan Kumar Das LM. Experimental investigations on a Karanja oil methyl ester fuelled DI diesel engine. SAE 2006-01-0238, 2006.; Agarwal D, Kumar Agarwal A. Performance and emission characteristics of a Jatropha oil (preheated and blends) in a direct injection compression ignition engine. Int J Appl Therm Eng 2007;27:2314-23. ]. Research in this direction with edible oils have yielded encouraging results, but their use as fuel for diesel engine has limited applications due to higher domestic requirement [Scholl Kyle W, Sorenson Spencer C. Combustion Analysis of soyabean oil methyl ester in a direct injection diesel engine. SAE 930934, 1993.; Nwafor OMI. Effect of advanced injection timing on the performance of rapeseed oil in diesel engines. Int J Renew Energy 2000;21:433-44.; Nwafor OMI. The effect of elevated fuel inlet temperature on performance of diesel engine running on neat vegetable oil at constant speed conditions. Renew Energy 2003;28:171-81. ]. In view of this, Honge oil (Pongamia Pinnata Linn) being non-edible oil could be regarded as an alternative fuel for CI engine applications. The viscosity of Honge oil is reduced by transesterification process to obtain Honge oil methyl ester (HOME). Gasification is a process in which solid biomass is converted into a mixture of combustible gases, which complete their combustion in an IC engine. Hence, producer gas can act as a promising alternative fuel, especially for diesel engines by substituting considerable amount of diesel fuels. Downdraft moving bed gasifiers coupled with IC engine are a good choice for moderate quantities of available biomass, up to 500 kW of electric power. Hence, bioderived gas and vegetable liquids appear more attractive in view of their friendly environmental nature. Since vegetable oils produce higher smoke emissions, dual fuel operation could be adopted for improving their performance. (author)

  4. Effects of crossflow velocity and transmembrane pressure on microfiltration of oil-in-water emulsions

    CERN Document Server

    Darvishzadeh, Tohid

    2012-01-01

    This study addresses the issue of oil removal from water using hydrophilic porous membranes. The effective separation of oil-in-water dispersions involves high flux of water through the membrane and, at the same time, high rejection rate of the oil phase. The effects of transmembrane pressure and crossflow velocity on rejection of oil droplets and thin oil films by pores of different cross-section are investigated numerically by solving the Navier-Stokes equation. We found that in the absence of crossflow, the critical transmembrane pressure, which is required for the oil droplet entry into a circular pore of a given surface hydrophilicity, agrees well with analytical predictions based on the Young-Laplace equation. With increasing crossflow velocity, the shape of the oil droplet is strongly deformed near the pore entrance and the critical pressure of permeation increases. We determined numerically the phase diagram for the droplet rejection, permeation, and breakup depending of the transmembrane pressure and...

  5. Development of a Fully Automated Flow Injection Analyzer Implementing Bioluminescent Biosensors for Water Toxicity Assessment

    Directory of Open Access Journals (Sweden)

    Constantinos Georgiou

    2010-07-01

    Full Text Available This paper describes the development of an automated Flow Injection analyzer for water toxicity assessment. The analyzer is validated by assessing the toxicity of heavy metal (Pb2+, Hg2+ and Cu2+ solutions. One hundred ?L of a Vibrio fischeri suspension are injected in a carrier solution containing different heavy metal concentrations. Biosensor cells are mixed with the toxic carrier solution in the mixing coil on the way to the detector. Response registered is % inhibition of biosensor bioluminescence due to heavy metal toxicity in comparison to that resulting by injecting the Vibrio fischeri suspension in deionised water. Carrier solutions of mercury showed higher toxicity than the other heavy metals, whereas all metals show concentration related levels of toxicity. The biosensor’s response to carrier solutions of different pHs was tested. Vibrio fischeri’s bioluminescence is promoted in the pH 5–10 range. Experiments indicate that the whole cell biosensor, as applied in the automated fluidic system, responds to various toxic solutions.

  6. Rheological Study of Petroleum Fluid and Oil-in-Water Emulsion

    OpenAIRE

    Liyana Nadirah,; M.S; Abdurahman

    2014-01-01

    he rheological behavior of two types of crude oil and oil-in-water (o/w) emulsion were thoroughly studied. These rheological properties were investigated including steady flow behavior, shear stress, shear rate, and fluid flow behavior by using a Brookfield Rotational Digital Rheometer. Both of crude oils were prepared by homogenized at 10,000 rpm in 5-10 min, thermodynamically stable. The pure heavy and blend oil exhibit a Newtonian character for the temperature between 30°C ...

  7. Molecular dynamics investigation into the adsorption of oil-water-surfactant mixture on quartz

    Science.gov (United States)

    Xuefen, Zhang; Guiwu, Lu; Xiaoming, Wen; Hong, Yang

    2009-04-01

    Molecular dynamics (MD) simulations have been carried out to investigate the adsorption behavior of different surfactants-water-oil mixture on quartz surfaces. The effects of rhamnolipid, sodium dodecyl benzene sulfonate and sodium hexadecyl sulfonate on binding energy and radial distribution function (RDF) of oil-quartz are calculated at molecular level. The study shows that these surfactants can reduce binding energy between oil molecules and quartz surface, which plays a role of oil-displacing agent.

  8. The effect of water injection on nitric oxide emissions of a gas turbine combustor burning ASTM Jet-A fuel

    Science.gov (United States)

    Marchionna, N. R.; Diehl, L. A.; Trout, A. M.

    1973-01-01

    Tests were conducted to determine the effect of water injection on oxides of nitrogen (NOx) emissions of a full annular, ram induction gas turbine combustor burning ASTM Jet-A fuel. The combustor was operated at conditions simulating sea-level takeoff and cruise conditions. Water at ambient temperature was injected into the combustor primary zone at water-fuel ratios up to 2. At an inlet-air temperature of 589 K (600 F) water injection decreased the NOx emission index at a constant exponential rate: NOx = NOx (o) e to the -15 W/F power (where W/F is the water-fuel ratio and NOx(o) indicates the value with no injection). The effect of increasing combustor inlet-air temperature was to decrease the effect of the water injection. Other operating variables such as pressure and reference Mach number did not appear to significantly affect the percent reduction in NOx. Smoke emissions were found to decrease with increasing water injection.

  9. Injection Molding of Titanium Alloy Implant For Biomedical Application Using Novel Binder System Based on Palm Oil Derivatives

    Directory of Open Access Journals (Sweden)

    R. Ibrahim

    2010-01-01

    Full Text Available Problem statement: Titanium alloy (Ti6Al4V has been widely used as an implant for biomedical application. In this study, the implant had been fabricated using high technology of Powder Injection Molding (PIM process due to the cost effective technique for producing small, complex and precision parts in high volume compared with conventional method through machining. Approach: Through PIM, the binder system is one of the most important criteria in order to successfully fabricate the implants. Even though, the binder system is a temporary, but failure in the selection and removal of the binder system will affect on the final properties of the sintered parts. Therefore, the binder system based on palm oil derivative which is palm stearin had been formulated and developed to replace the conventional binder system. Results: The rheological studies of the mixture between the powder and binders system had been determined properly in order to be successful during injection into injection molding machine. After molding, the binder held the particles in place. The binder system had to be removed completely through debinding step. During debinding step, solvent debinding and thermal pyrolysis had been used to remove completely of the binder system. The debound part was then sintered to give the required physical and mechanical properties. The in vitro biocompatibility also was tested using Neutral Red (NR and mouse fibroblast cell lines L-929 for the direct contact assay. Conclusion: The results showed that the properties of the final sintered parts fulfill the Standard Metal Powder Industries Federation (MPIF 35 for PIM parts except for tensile strength and elongation due to the formation of titanium carbide. The in vitro biocompatibility on the extraction using mouse fibroblast cell line L-929 by means of NR assays showed non toxic for the sintered specimen titanium alloy parts.

  10. Evaluation of thermal performance in fields subjected to steam injection (SW-SAGD mode), Orinoco oil belt, Venezuela

    Energy Technology Data Exchange (ETDEWEB)

    Armas, F.; Mago, R.; Franco, L.; Rodriguez, J.; Gil, E. [PDVSA EandP (Venezuela)

    2011-07-01

    The first well to operate the SW-SAGD process in the Orinoco oil belt in Venezuela was built in 2006 by Petroleos de Venezuela S.A (PDVSA). SW-SAGD is a thermal recovery process consisting in the injection of steam through a horizontal well pipe insulation. In order to follow the behavior of steam and the movement of heated fluids in such a process better, PDVSA installed a monitoring system composed of high temperature fiber optic and thermocouple type sensors. The aim of this paper is to assess the thermal behavior of reservoirs in wells under the SW-SAGD process. A pilot test has been conducted over the last 3 years. Results show an increase in production and estimations show a recovery factor twice as high as in other wells. This study demonstrated that SW-SAGD is an excellent alternative solution to stimulate reservoirs in the Orinoco oil belt and valuable information on the reservoir's thermal behavior was established.

  11. Metallurgical investigation of safety injection system pipe cracking at Sequoyah unit 2 pressurized water reactor station

    International Nuclear Information System (INIS)

    During the May 1996 refueling outage, while conducting a routine Ultrasonic Examination as part of the Section Xl ISI inspection, a, crack in the safety injection (Sl) system pipe was detected at Sequoyah Unit 2 Station. A ten-inch long spool piece of the affected region of the pipe containing the weld and the crack, was sectioned out of the Sl line and was transported to the Westinghouse hot cell facilities in Pittsburgh, Pa., USA for evaluation. Based on the overall results of the investigation, it is concluded that the Sl line pipe cracking occurred by an intergranular stress corrosion cracking (IGSCC) mechanism caused by the exposure of sensitized heat affected zone of the pipe weld to the oxygenated boric acid water in the safety injection system. (authors)

  12. Uniform and non-uniform inlet temperature of a vertical hot water jet injected into a rectangular tank

    KAUST Repository

    El-Amin, Mohamed

    2010-12-01

    In most of real-world applications, such as the case of heat stores, inlet is not kept at a constant temperature but it may vary with time during charging process. In this paper, a vertical water jet injected into a rectangular storage tank is measured experimentally and simulated numerically. Two cases of study are considered; one is a hot water jet with uniform inlet temperature (UIT) injected into a cold water tank, and the other is a cold water jet with non-uniform inlet temperature (NUIT) injected into a hot water tank. Three different temperature differences and three different flow rates are studied for the hot water jet with UIT which is injected into a cold water tank. Also, three different initial temperatures with constant flow rate as well as three different flow rates with constant initial temperature are considered for the cold jet with NUIT which is injected into a hot water tank. Turbulence intensity at the inlet as well as Reynolds number for the NUIT cases are therefore functions of inlet temperature and time. Both experimental measurements and numerical calculations are carried out for the same measured flow and thermal conditions. The realizable k-? model is used for modeling the turbulent flow. Numerical solutions are obtained for unsteady flow while pressure, velocity, temperature and turbulence distributions inside the water tank are analyzed. The simulated results are compared to the measured results, and they show a good agreement at low temperatures. © 2010 IEEE.

  13. INFLUENCE OF INJECTION TIMING ON EMISSION ANALYSIS OF A DI ENGINE RUNNING ON RUBBER SEED AND JATROPHA OIL FUELLED WITH DIESEL FUEL

    Directory of Open Access Journals (Sweden)

    S. Mahalingam

    2014-03-01

    Full Text Available The petroleum fuels availability and cost concerns the nonedible oils used as raw materials can be obtained from different oil crops that may be used to reduce the environmental pollution.In the development of alternative, biodegradable, and renewable fuels used forinternal combustion (IC engines to obtain the power. Therefore, in this present study, in?uence of fuel injection timing on the exhaust emission of a single cylinder, four stroke, and direct injection(DI diesel engine was considered. It has been experimentally investigated using rubber seed and jatropha seed oil blended diesel fuel from 20%(B20to 40%(B40 with an increment of 10%. The engine was tested at different loads from no load to full load conditions with diesel fuel at normal injection pressure of 220 bar and fuel injection timing of 240CA BTDC. The experimental tests were performed at 210CA BTDC injection timings by changing the thickness of advance shim. The experimental results obtained show that CO and UHC emissions were decreasedfor the proportion of B20,NOx and exhaust gas temperatureincreased with increasing amount of biodiesel concentration in the fuel mixture.

  14. Radiation-thermal purification of waster water from oil pollution

    International Nuclear Information System (INIS)

    Full text: During the extraction, refining and transportation of oil sewages arise, which contain oil in various concentrations depending on used technology. At present different methods for cleaning of these wastes from oil pollution are used. The radiation- thermal method is one of the effective ways of decomposition of carbohydrogens admixtures. The chain decomposition of carbohydrogens during the joint impact of radiation and heat in certain conditions was established early. On an example of individual carbohydrogens - n-heptane, hexadecane, pentadecane were shown that radiation chemical yield of decomposition can reach hundreds molecules. In this work the results of radiation-thermal decomposition of heptane admixtures in water medium are adduced. The main parameters of radiolysis changes within the bounds: temperature 20-400 degrees centigrade, absorbed dose -0-10.8 kGy on dose rate 3.6 kGy/h. The correlation of n.heptane concentration and water steam changed within [carbon5H12] [H2O]=(0.6-60)10-4. Total concentration of steam was about 1020 mol/ml. As a product of decomposition are observed hydrogen2, carbon oxide, carbonhydrogen4, carbon2hydrogen4, carbon2hydrogen6, carbon3hydrogen8, carbon3hydrogen6, carbon4hydrogen8, traces of carbohydrogens carbon5, carbon6. The changes of n.heptane concentration in the reactor also were established. The chain regime of n.heptane decomposition in irradiated mixture was observed. The critical meaning of temperature and mixture of components are defined, on which the break of chain of process of normal n.heptane occurs. Maximal radiation-chemical yields of products are : G(hydrogen2)=19,8, G(carbon oxide)=7,3, G(carbonhydrogen4)=237,1, G(carbon2hydrogen4)=383,9, G(carbon2hydrogen6)=248,1, G(carbon3hydrogen6)=167,8, G(carbon3hydrogen8)=196,8, G(carbon4hydrogen8)=143,8 mol/100 eV. The mechanisms of proceeding radiation thermal processes in carbohydrogen-water system are discussed

  15. A self-cleaning underwater superoleophobic mesh for oil-water separation

    OpenAIRE

    Zhang, Lianbin; Zhong, Yujiang; Cha, Dongkyu; Wang, Peng

    2013-01-01

    Oil–water separation has recently become a global challenging task because of the frequent occurrence of oil spill accidents due to the offshore oil production and transportation, and there is an increasing demand for the development of effective and inexpensive approaches for the cleaning-up of the oily pollution in water system. In this study, a self-cleaning underwater superoleophobic mesh that can be used for oil-water separation is prepared by the layer-by-layer (LbL) assembly of sodium ...

  16. Water footprint assessment of oil palm in Malaysia: A preliminary study

    Science.gov (United States)

    Muhammad-Muaz, A.; Marlia, M. H.

    2014-09-01

    This study evaluates the water footprint of growing oil palm in Malaysia based on the water footprint method. The crop water use was determined using the CROPWAT 8.0 model developed by the Land and Water Development Division of FAO. The total water footprint for growing oil palm is 243 m3/ton. The result of this study showed that the green water footprint is 1.5 orders of magnitude larger compared to the blue water footprint. Besides providing updated status of total water used from the oil palm plantation, our result also shows that this baseline information helps in identifying which areas need to be conserved and what type of recommendation that should be drawn. As the results of the water footprint can differ between locations, the inclusion of local water stress index should be considered in the calculation of water footprint.

  17. Experimental Design: Application to the Development of a Treatment to Inhibit the Deposition of Barium Sulfate Liable to Be Formed in Enhanced Oil Recovery by Waterflooding Planification d'expériences : application à la mise au point d'un traitement inhibiteur du depôt de sulfate de baryum susceptible de se former en récupération assistée du pétrole par injection d'eau

    OpenAIRE

    Roque C.; Girou A.; Messaoudene N.; Puech-Costes E.; Maurette M. T.

    2006-01-01

    For technical and economic reasons, waterflooding is the most widely-used method in enhanced oil recovery [1]. In many situations, unfortunately, the formation water is incompatible with the injection water. The deposits and corrosion induced by the various reactions of this incompatibility cause irreversible damage, which is especially dangerous for the reservoir rock and the downhole and surface production facilities. This study is concerned exclusively with barium sulfate deposits liable t...

  18. Comparative performance and emissions study of a direct injection Diesel engine using blends of Diesel fuel with vegetable oils or bio-diesels of various origins

    International Nuclear Information System (INIS)

    An extended experimental study is conducted to evaluate and compare the use of various Diesel fuel supplements at blend ratios of 10/90 and 20/80, in a standard, fully instrumented, four stroke, direct injection (DI), Ricardo/Cussons 'Hydra' Diesel engine located at the authors' laboratory. More specifically, a high variety of vegetable oils or bio-diesels of various origins are tested as supplements, i.e. cottonseed oil, soybean oil, sunflower oil and their corresponding methyl esters, as well as rapeseed oil methyl ester, palm oil methyl ester, corn oil and olive kernel oil. The series of tests are conducted using each of the above fuel blends, with the engine working at a speed of 2000 rpm and at a medium and high load. In each test, volumetric fuel consumption, exhaust smokiness and exhaust regulated gas emissions such as nitrogen oxides (NO x), carbon monoxide (CO) and total unburned hydrocarbons (HC) are measured. From the first measurement, specific fuel consumption and brake thermal efficiency are computed. The differences in the measured performance and exhaust emission parameters from the baseline operation of the engine, i.e. when working with neat Diesel fuel, are determined and compared. This comparison is extended between the use of the vegetable oil blends and the bio-diesel blends. Theoretical aspects of Diesel engine combustion, combined with the widely differing physical and chemical properties of these Diesel fuel supplements against the normal Diesel fuel, are used to aid the correct interpretation of the observed engine behavior

  19. Increasing hydro turbine operation range and efficiencies using water injection in draft tubes

    Energy Technology Data Exchange (ETDEWEB)

    Francke, Haakon Hjort

    2010-09-15

    It is a well known fact that most Francis turbines, because of the fixed blade design, faces challenges when running at partial load operation. Especially in the operating range below approximately 50 % of the rated output, it is common to observe severe pressure pulsations and surge in the draft tube. These pressure fluctuations are believed to be related to the swirling flow exiting the runner. By using water jets in the draft tube cone directed towards the swirling flow, the swirl strength is believed to be reduced and thereby also the pressure fluctuations produced by the swirl. This system thus has a potential of increasing the turbine operating range. The system can be activated when needed, and will not affect the turbine when running at its best efficiency point.Based on the main hypothesis, a simplified swirl rig was designed and constructed in order to investigate the nozzle influence on the swirling flow and on the pressure pulsations in a simplified environment. To expand the understanding of the nozzle performance in a Francis turbine, experiments were conducted in a model turbine with a prototype of movable nozzles. To establish a link between laboratory nozzle measurements and full scale nozzle measurements, field measurements were carried out on full scale Francis turbines running at partial discharge. For this purpose the turbines installed at Skarsfjord Power Station and Skibotn Power Station were used, where full scale nozzle injection systems were installed. The test results suggested that the concept of water injection worked, but not unconditionally. A reduction in pressure fluctuations was achieved both in laboratory and field experiments, as well as a noticeable reduction regarding fluctuations in the shaft run-out at Skibotn. In addition, water injection gave a surprisingly positive effect at overload conditions in the model turbine, even though the nozzle angle was directed in the same direction as the overload swirl. Ideally, the results from this project should be presented as a linear equation to give the ideal nozzle configuration for a given operating condition. This has not yet been possible because of the complexity of the system and its variable factors. However, several effects from changing nozzle variables individually have been detected, and are summarized in chapter 1- Conclusions and Achievements. Efficiency measurements in the laboratory and in the field experiments indicated a possibility of increasing the hydraulic efficiency with the water injection system activated. This positive feature was believed to be caused by improvement of the velocity field in the draft tube. However, the total efficiency was always decreased because of the nozzle water bypass. (Author)

  20. Simple flow injection colorimetric system for determination of paraquat in natural water.

    Science.gov (United States)

    Chuntib, Prakit; Jakmunee, Jaroon

    2015-11-01

    A simple and low cost flow injection colorimetric system has been developed for determination of paraquat in natural water. The developed method is based on the reduction of paraquat by using sodium dithionite as a reducing agent in an alkaline medium to produce a blue free radical ion that can be detected by a simple light emitting diode-light dependent resistor (LED-LDR) colorimeter. The standard or sample solution was injected via a set of 3-way solenoid valves into a water carrier stream and flowed to merge with reagent to generate a colored product which is proportional to the concentration of paraquat ion in the solution. Under the optimum condition of the system, i.e., mixing coil length 30cm, flow rate 2.0mLmin(-1), sample volume 100?L, concentrations of dithionite 0.1% (w/v) and sodium hydroxide 0.06molL(-1), a linear calibration graph in the range of 0.2-10.0mgL(-1) with a correlation coefficient of 0.9996, and a limit of detection of 0.15mgL(-1) were achieved. Relative standard deviation for 9 replicate injections of 1mgL(-1) paraquat is 3.7%. A sample throughput of 40 injectionsh(-1) was achieved. The limit of detection can be improved by off-line preconcentration of paraquat employing a column packed with Dowex 50WX8-100 (H) cation exchange resin and eluted with 10% (w/v) ammonium chloride in ammonium buffer solution pH 10. The eluting solution was then injected into the FI system for paraquat determination. The proposed system did not suffer from interferences of some possible ions in natural water and other herbicides. Recoveries obtained by spiking 0.5 and 5.0mgL(-1) paraquat standard into water samples were in the range of 104-110% and 101-105%, respectively. The developed system can be conveniently applied for screening of paraquat contaminated in natural water. PMID:26452844

  1. Water in soybean oil microemulsions as medium for electrochemical measurements

    Scientific Electronic Library Online (English)

    Carla R. B., Mendonça; Clara I. D., Bica; Clarisse M. S., Piatnicki.

    2003-08-01

    Full Text Available Microemulsões de água em óleo de soja (w/o ME) foram preparadas com dodecil sulfato de sódio (SDS) como surfactante e com os álcoois amílico ou isoamílico, como co-surfactantes. A composição 40,0% de óleo, 43,2% de álcool, 10,8% de SDS e 6,0% de água, em massa, na razão 1:4 [SDS]:[álcool], apresento [...] u a maior estabilidade termodinâmica. O tamanho das gotículas e seu coeficiente de difusão nas microemulsões, Dw/o, foram determinados por medidas de espalhamento de luz dinâmico (DLS). As reações de oxidação de ferroceno (Fc) e de água, e a redução de ácido oleico foram observadas nas ME por voltametria em um ultramicroeletrodo (ume) de disco de Pt. Os valores de Dw/o determinados a partir de medidas eletroquímicas são menores do que os calculados a partir daquelas por DLS. Isto indica que a oxidação da água requer a difusão para o eletrodo tanto das gotículas como das moléculas de água nelas contidas. Os resultados evidenciam a possibilidade de determinação de analitos em óleos vegetais por métodos eletroanalíticos. Abstract in english Microemulsions of water in soybean oil (w/o ME) were prepared with sodium dodecyl sulfate (SDS) as surfactant and amyl or isoamyl alcohol, as co-surfactants. Microemulsions containing 40.0% oil, 43.2% alcohol, 10.8% SDS and 6.0% water in weight, in the ratio 1:4 [SDS]:[alcohol] showed the highest th [...] ermodynamic stability. The aqueous droplet size and its diffusion coefficient Dw/o in the ME were determined through dynamic light scattering (DLS). Voltammetric measurements in the ME at a Pt disk ultramicroelectrode (ume) evidenced the oxidation of both water and ferrocene (Fc), and the reduction of oleic acid. The Dw/o values calculated from the limiting current being lower than the ones obtained from DLS indicate that water oxidation probably requires diffusion towards the electrode of both the droplets and the water molecules from inside the droplets. The results show that electroanalytical determinations can be carried out in w/o ME.

  2. The Orientation and Charge of Water at the Hydrophobic Oil Droplet - Water Interface.

    Czech Academy of Sciences Publication Activity Database

    Vácha, R.; Rick, S. W.; Jungwirth, Pavel; de Beer, A. G. F.; de Aguiar, H. B.; Samson, J.; Roke, S.

    2011-01-01

    Ro?. 133, ?. 26 (2011), s. 10204-10210. ISSN 0002-7863 R&D Projects: GA MŠk LC512 Grant ostatní: DFG(DE) 560398; European Research Council(XE) 240556; NSF(US) CHE-0611679 Institutional research plan: CEZ:AV0Z40550506 Keywords : oil/water interface * sum frequency scattering * molecular dynamics Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 9.907, year: 2011

  3. Wireless device protects waters from oil rig contamination

    International Nuclear Information System (INIS)

    A small submersible ion-trap mass spectrometer has been developed by Voda LLC to detect pollution from offshore drilling. Two Manta units have been sold to a technology company in Florida and Voda plans to demonstrate the unit for Canadian environmental officials and for the offshore oil industry in Canada. The self-contained and autonomous tool is designed to sit on open water, be deployed in open air or be transported through a site to continuously sniff for any given set of chemicals or compounds. Real-time results are transmitted wirelessly to an investigator's computer. Voda has also developed multisensor systems linked to underwater video cameras where Wi-Fi networks then transmit real-time data of conductivity, temperature, pressure, and salinity to onshore stations. 1 fig

  4. Detailed evaluation of the natural circulation mass flow rate of water propelled by using an air injection

    International Nuclear Information System (INIS)

    One-dimensional (1D) air-water two-phase natural circulation flow in the thermohydraulic evaluation of reactor cooling mechanism by external self-induced flow - one-dimensional' (THERMES-1D) experiment has been verified and evaluated by using the RELAP5/MOD3 computer code. Experimental results on the 1D natural circulation mass flow rate of water propelled by using an air injection have been evaluated in detail. The RELAP5 results have shown that an increase in the air injection rate to 50% of the total heat flux leads to an increase in the water circulation mass flow rate. However, an increase in the air injection rate from 50 to 100% does not affect the water circulation mass flow rate, because of the inlet area condition. As the height increases in the air injection part, the void fraction increases. However, the void fraction in the upper part of the air injector maintains a constant value. An increase in the air injection mass flow rate leads to an increase in the local void fraction, but it has no influence on the local pressure. An increase in the coolant inlet area leads to an increase in the water circulation mass flow rate. However, the water outlet area does not have an influence on the water circulation mass flow rate. As the coolant outlet moves to a lower position, the water circulation mass flow rate decreases. (author)

  5. Partition of selected food preservatives in fish oil-water systems

    DEFF Research Database (Denmark)

    Cheng, Hongyuan; Friis, Alan

    2010-01-01

    The partition coefficients (Kow) of benzoic acid and sorbic acid in systems of fish oil (sand eel)–water, fish oil–buffer solution, rape oil–water and olive oil–water were experimentally determined in a temperature range from 5 to 43 °C and pH from 4.5 to 6.5 °C. The dimerization of benzoic acid in fish oil–water system was observed at 25 °C. Two modifications have been made to the Nordic Food Analysis Standard for the determination of sorbic acid by HPLC. The experimental results show that the Kow of benzoic acid and sorbic acid in fish oil–buffer system is ca. 100 times lower than that in fish oil–water system. The Kow values of benzoic acid and sorbic acid in fish oil and water system decrease with increasing system pH values. The partition coefficients of plant origin and fish origin oils are in the same order of magnitude even though their molecular structures are very different.

  6. Fungi isolated from produced water and water-soluble fraction of crude oil

    International Nuclear Information System (INIS)

    This study was sought to determine the fungi present in the produced water (PW) and water-soluble fraction (WSF) of crude oil as a preliminary approach to determining that fungi can survive in crude oil polluted water and their possible use in bioremediation. Different concentrations of PW and WSF of crude oil samples from Ughelli East Flow Station in Delta State of Nigeria were exposed to onion (Allium cepa) primordial cells at different concentrations for twelve days. Thereafter; samples of the PW and WSF were cultured on Potato Dextrose Agar. Isolates of Thamnidium sp, Gelasinospora sp, Zygorhynchu. sp and Colletotrichum sp were found. Zygorhynchus and Colletotrichum were associated with PW while thaminidium and Gelasinospora associated with the WSF. There were changes in the pH and turbidity of the PW and WSF before and after exposure to Allium cepa cells. At 25% level of treatments there were significant differences in pH and turbidity values of the PW and WSF at P 0.01 before and after exposure to the plant. (author)

  7. A 2-D Visualisation Study of the Mechanisms behind Increased Recovery due to Polymer Injection in Sandstone

    OpenAIRE

    Grønnestad, Svenn Erik

    2011-01-01

    The potential of synthetic polymer injection, such as hydrolysed polyacrylamide (HPAM), in reservoirs has been a field of study since the 1960's [1]. The main intension of polymer injection is to improve the problems with water injection due to high mobility ratio between oil and water and reservoir heterogeneity. Polymers are added to injection water in order to increase the viscosity and reduce the mobility ratio. Though polymers have been thought to only improve ...

  8. Modeling of Droplet Evaporation for Gas Turbine Inlet Fogging Systems with Different Water Injection Ratios

    Science.gov (United States)

    Kim, Kyoung Hoon; Ko, Hyung-Jong; Park, Young Sun

    2009-09-01

    The evaporative cooling of air by inlet fogging is a well proven technology for enhancing the power of gas turbine engines since it decreases with the increase of ambient temperature. In this work the inlet fogging process is modeled based on the evaporation of droplets. By considering heat and mass transfer and thermodynamic relations, analytic expressions are obtained for transient behaviors of air and droplet temperatures, and droplet diameter. They depend on ambient conditions, water injection ratio and initial droplet diameter. Results are given for the high fogging case as well as low fogging case.

  9. Flow injection spectrophotometric determination of low concentrations of orthosphate in natural waters employing ion exchange resin

    International Nuclear Information System (INIS)

    A simple and fast method for the determination of low concentrations of orthophosphate in natural waters is described. Ion exchange is incorporated into a flow injection system by usina a resin column in the sample loop of a proportion injector. Effects of sample aspiration rate, sampling time, eluting agent concentration, pumping rate of the sample carrier stream and interfaces, were investigated both using 32PO3-4 or 31PO3-4 with columns coupled to a gerger-muller detector and incorporated in a flow system with molybdenum blue colorinetry. (M.A.C.)

  10. Water washing pre-treatment on empty fruit bunches oil palm wastes

    International Nuclear Information System (INIS)

    Full text: The water washing pre-treatment on empty fruit bunches oil palm [EFB] wastes is investigated in this study. The objective is to remove ash from EFB wastes in order to improve the quality of bio-oil and to increase bio-oil yields. It was found that the feedstock with ash content less than about 3 mf wt % is required to produce homogenous bio-oil via fast pyrolysis technology [1]. The optimum parameter of water washing pre-treatment is required to produce the feedstock with ash content approximately about 1 mf wt %. Therefore, this study is investigating the effectiveness of water washing to remove ash by using variable of water washing pre-treatments. Tap water is used through out the work as washing in tap water would have a significant economic advantage over washing in distilled water. (author)

  11. Quantifying saline groundwater seepage to surface waters in the Athabasca oil sands region

    International Nuclear Information System (INIS)

    Western Canadian oil sands contain over 170 billion barrels of proven unconventional petroleum reserves currently extracted at 1.8 million barrels per day by either surface mining, or by in situ techniques that require subsurface injection of steam and hydrocarbon solvents. Natural high-salinity springs are known to add water and entrained inorganic and organic constituents to the Athabasca River and its tributaries in the region of ongoing bitumen production. However, the magnitude and synoptic distribution of these saline inputs has remained unquantified. Here, a chloride mass balance is used to estimate saline groundwater discharge to the Athabasca River from 1987 to 2010. Results show that the highest saline water discharge rate to the Athabasca River occurs between Ft. McMurray and the Peace-Athabasca Delta, supported by subcrop exposure of lower Cretaceous- and Devonian-aged formations bearing saline waters. Further, the input of saline groundwater is found to be an important control on the chemistry of the lower Athabasca River, despite comprising 10?1 to 3% of the Athabasca River’s discharge. The flux of natural saline groundwater entering the Athabasca does not appear to have increased or decreased from 1987 to 2010. The origin of seep salinity is interpreted as relict subglacial meltwater that has dissolved Devonian-aged evaporites, supported by saline Na-Cl type waters with low 18O/16O and 2H/1H ratios relative to modern precipitation. The magnitude of groundwater discharge and its impact on the Athabasca River’s chemistry in the area of ongoing bitumen development warrants the incorporation of natural groundwater seepages into surface water quality monitoring networks.

  12. Detecting total toxicity in water using a mediated biosensor system with flow injection.

    Science.gov (United States)

    Yong, Daming; Liu, Changyu; Zhu, Chengzhou; Yu, Dengbin; Liu, Ling; Zhai, Junfeng; Dong, Shaojun

    2015-11-01

    A novel total toxicity detection method based on a mediated biosensor system with flow injection (MB-FI) was developed to rapidly and reliably detect respiration inhibitors (i.e., As2O3, KCN, salicylic acid (SA), 2,4-dintirophenol (DNP)) in water. The mediated biosensor toxicity assessment using microorganisms immobilized in calcium alginate filaments can greatly simplify the testing process and save time. In the MB-FI system, ferricyanide together with a respiration inhibitor was injected into the bioreactor, inhibiting the respiration of the immobilized microorganisms. The degree of inhibition was measured by determining the ferrocyanide generated in the effluent, expressed as the 50% inhibition concentration (IC50). The IC50 values for the four respiration inhibitors obtained using this method were comparable to those obtained using the classic method, confirming that this approach is an alternative alert method. More importantly, this constructed biosensor system with flow injection will facilitate the application and commercialization of this toxicity monitoring technology. PMID:26071865

  13. Characterization Of Metal Injection Molding (MIM Feedstock Based On Water Soluble Binder System

    Directory of Open Access Journals (Sweden)

    Norhamidi Muhamad

    2008-08-01

    Full Text Available Metal Injection Molding (MIM is a new manufacturing technique especially to produce small and complex precision parts. Characterization of feedstock is one of the important tasks in order to evaluate the homogeneity level of the feedstock prepared and to control the quality of the parts during injection molding process. This paper attempts to investigate the characteristics of the MIM feedstock by performing rheological test using the feedstock consisted of 316L stainless steel powder with a mean particle size of 12 micrometer and a major fraction of water soluble binder system known as polyethylene glycol (PEG. Three different weight percentage of PEG at 65, 75, and 85 respectively were used during the investigation. The viscosity of MIM feedstock at different temperatures and shear rates were measured and evaluated. Results show that increasing the PEG content would decrease the viscosity of the feedstock. The rheological properties of the feedstock showed that the proposed method of mixing is adequate to produce a homogeneous feedstock that is favorable for injection molding process.

  14. Stability of Water-in-Crude Oil Emulsion Using Cocamide Surfactant

    Directory of Open Access Journals (Sweden)

    Rasha Mohammed Abd

    2014-01-01

    Full Text Available The formation of water-in-crude oil emulsion can be encountered in many stages such as drilling, transporting and processing of crude oil. To enhance and control these processes, it is necessary to understand the emulsion mechanisms. In this study, two types of Malaysian crude oil namely; heavy crude oil and light-heavy blended crude oil (40-60 vol% were characterized physically to use as the oil phase. Cocaamide DEA was used as a natural surfactant. The stability of water-in-crude oil emulsion were investigated at different water volume fractions (50 and 20% with four volume fractions of Cocamide DEA (0.2 , 0.5, 1 and 1.5%. These emulsions were tested for relative rates of water separation and for rheology studies to demonstrate the viscosity behavior on the emulsion stability. Brookfield Viscometer was used to study the effects of shear rate, temperature, rotation speed (rpm and water content on the viscosity at varying temperature (30-90°C and rotation speed (50-250 rpm. Results showed that higher concentration of Cocamide DEA and lower water volume fraction were effective in stabilizing the water-in-crude oil emulsion at room temperature. In addition, the viscosity of the emulsion stabilized by Cocamide DEA showed non-Newtonian behavior.

  15. Debinding behaviour of a water soluble PEG/PMMA binder for Ti metal injection moulding

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Gang [Department of Chemical and Materials Engineering, The University of Auckland, Private Bag 92019, Auckland 1142 (New Zealand); Cao, Peng, E-mail: p.cao@auckland.ac.nz [Department of Chemical and Materials Engineering, The University of Auckland, Private Bag 92019, Auckland 1142 (New Zealand); Wen, Guian [Department of Chemical and Materials Engineering, The University of Auckland, Private Bag 92019, Auckland 1142 (New Zealand); Edmonds, Neil [School of Chemical Science, The University of Auckland, Private Bag 92019, Auckland 1142 (New Zealand)

    2013-05-15

    Polyethylene glycol (PEG) has been becoming a common component in the design of water soluble binder systems for metal injection moulding. Similar to solvent debinding, PEG can be leached out by water and the mechanism of debinding was proposed in the literature with somehow misleading information about the debinding mechanism, particularly about the formation of PEG gel. This work investigates the debinding behaviours of a PEG-based binder in titanium compacts. Titanium powder is formulated with PEG, poly(methyl methacrylate) (PMMA) and stearic acid (SA) to formulate titanium feedstock. To determine the debinding kinetics, the PEG removal percentages are measured at three different temperatures and for various specimen thicknesses. A mathematic model based on diffusion-controlled debinding process is established. The evolution of porous microstructure during the water debinding process is observed using scanning electron microscopy. Based on these observations, a water debinding mechanism for titanium alloy compacts formulated with PEG-based binders is proposed. - Highlights: ? The water-debinding behaviours of the PEG binder system were investigated. ? PEG dissolution and transportation, and the pore structure development. ? A water debinding mechanism of PEG-based binders is proposed. ? Incorrect explanation of PEG gelling in the literature is corrected. ? Correction/modification made as per the reviewers' comments and suggestions.

  16. 33 CFR 155.440 - Segregation of fuel oil and ballast water on new oceangoing ships of 4,000 gross tons and above...

    Science.gov (United States)

    2010-07-01

    ... false Segregation of fuel oil and ballast water on new oceangoing ships...440 Segregation of fuel oil and ballast water on new oceangoing ships...a clean ballast in any fuel oil tank, that ballast water must be discharged...

  17. 3D Simulation of a High Pressure Water Injection into a Circular Cold Leg Pipe Flow

    International Nuclear Information System (INIS)

    Injection of a water stream into a circular pipe flow of a different orientation appears in many important engineering applications, such as in nuclear reactor safety analysis, the mixing of two fluids at a T-shaped junction, etc. In this regard, the analysis of pressurized thermal shock (PTS) in the nuclear industry is a special issue. One of the major efforts concerning this issue is to predict the mixing behavior and stratification of a round cold jet from the safety high-pressure injection (HPIS) line with a hot loop flow circulating in the cold-leg pipe. Typically, in Westinghouse pressurized water reactor (PWR) systems, high-pressure water from 60 degrees injector is charged into the horizontal cold leg. The paper will discuss the 3D finite volume simulation, using CFD (computational fluid dynamic) code FLUENT, of the EPRI/Creare experimental results (one-fifth-scale model of PWR HPIS and cold-leg mixing), test numbers 42 and 46. The reason for this work is to validate FLUENT capability on benchmarked test results, as a preparation for its use in the more complex 3D finite volume analysis of full scale water mixing in the reactor vessel downcomer. It is part of the study mentioned to observe the most severe design basis accident sequences conditions for NPP Krsko and re-evaluate their PTS potential. The most important factors needed for PTS analysis are the following: the final temperature in downcomer, the temperature decrease rate, non uniform cooling of the reactor pressure vessel wall (characterized by cold plume of SI water) and the RCS pressure. (author)

  18. Antioxidant Activity of Potato Peel Extracts in a Fish-RapeseedOil Mixture and in Oil-in-Water Emulsions

    DEFF Research Database (Denmark)

    Farvin, Sabeena; Nielsen, Nina Skall

    2010-01-01

    The objectives of the present work were (a) to extract the phenolic fraction from the peels of two Danish varieties of potatoes, viz. Sava and Bintje, and examine their antioxidant capacity in in-vitro systems (b) to evaluate the effect of these extracts on the storage stability of a fish- rapeseed oil mixture and oil-in-water emulsions. Multiple antioxidant activity of the potato peel extracts was evident from in-vitro systems as they showed strong reducing power, radical scavenging ability, ferrous ion chelating activity and prevented oxidation in a liposome model system. The Sava variety, which showed strong antioxidant activity in in-vitro systems, was tested in oil and oil-in- water emulsions. Ethanolic extracts of Sava (C1,600 mg/kg) prevented lipid oxidation in emulsions and in oil. Water extracts showed no antioxidant activity in oil whereas it showed pro-oxidant activity in emulsions. Thus, the results of the present study show the possibility of utilizing waste potato peel as a promising source ofnatural antioxidants for retarding lipid oxidation.

  19. Radioactivity in Oily Sludge and Produced Waste Water from Oil: Environmental Concerns and Potential Remedial Measures

    OpenAIRE

    Avin E. Pillay; Fadhil M. Salih; Muthana I. Maleek

    2010-01-01

    Produced water separated from oil is usually returned to the environment and could permeate through the water table. If such water is contaminated with radioactive substances, it could create a definite threat to the water supply, especially in arid regions where ground water and overhead streams are sources of potable water. Low-level radioactive contamination of oily sludge is equally hazardous and also leads to detrimental pollution of water resources. We investigated the distribution of 2...

  20. A Review of Laboratory-Scale Research on Upgrading Heavy Oil in Supercritical Water

    Directory of Open Access Journals (Sweden)

    Ning Li

    2015-08-01

    Full Text Available With the growing demand for energy and the depletion of conventional crude oil, heavy oil in huge reserve has attracted extensive attention. However, heavy oil cannot be directly refined by existing processes unless they are upgraded due to its complex composition and high concentration of heteroatoms (N, S, Ni, V, etc.. Of the variety of techniques for heavy oil upgrading, supercritical water (SCW is gaining popularity because of its excellent ability to convert heavy oil into valued, clean light oil by the suppression of coke formation and the removal of heteroatoms. Based on the current status of this research around the world, heavy oil upgrading in SCW is summarized from three aspects: Transformation of hydrocarbons, suppression of coke, and removal of heteroatoms. In this work, the challenge and future development of the orientation of upgrading heavy oil in SCW are pointed out.

  1. Filters for water purification from oil products and radionuclides

    International Nuclear Information System (INIS)

    Full text: Purification of waste water and drinking water from radionuclides, heavy metal ions, and organic contaminants is one of the most important problems at present day. One of widely used methods for solving this problem is the ionic exchange method based on using different types of resins and fibroid sorbents. The paper deals with new chemically modified polyester fibroid filters having satisfactory adsorption characteristics. The process of the filter production includes their treatment by acrylo nitrilic emulsion for improving mechanical characteristics. An advantage of the fibroid ion-exchange sorbents over resin is in high rate of a sorption process, effective regeneration and small value of pressure drop of the sorbent layer for purified water. The specific surface of the fibroid sorbents is (2 - 3). 10'4 m2/ kg, i.e. about 102 times greater than that of the resin (102 m2/ kg). Owing to that fact the rate of the sorption process on the developed fibroid sorbents is much greater than that on the resin. The developed cation- and anion-exchange filters can be used for removing metal ions (Zn, Ni, Cu, Sb, Co, Cd, Cr, etc.) and organic compounds (M- P 32, M- I 131, M-Mo 99 mTc+99, etc.) from water. Capacity of the cation-exchange sorbents is 0.25 meq/g (Cu2+) and that of the anion - exchange is 0.45 meq/g (Cr6+). The cation- and anion-exchange filters are also selective for removing radionuclides Cs 134,137, Sr 90, Co 60 and I 129 in presence of Na+, K+, Ca2+, Mg2+, Cl- ions in water at concentrations up to 500 mg/L. New developed ionic-exchange sorbents have been used in drinking water filters and mini-systems for removing organic and inorganic contaminants, in the equipment for waste water purification from oil products (at atomic power stations, car-washing stations, etc), from heavy metal ions (in electronic industry, match fabrics, leather processing plants etc)

  2. Optimization of polymer flood performance by preflush injection - numerical investigation

    Directory of Open Access Journals (Sweden)

    M. ABEDI

    2013-09-01

    Full Text Available Currently, many reservoirs in the region approach the end of primary recovery phase where new techniques are needed to enhance recovery. Therefore, the need to optimize oil recovery from the current resources is very well understood by regional oil companies. To enhance oil recovery from current oil resources, field operators need to overcome the forces responsible for oil entrapment. Enhanced Oil Recovery techniques (EOR introduce new energy into oil reservoirs to reduce the influence of these forces. Most of these resources contain light oil and are considered suitable candidates for either miscible or chemical EOR techniques. The first technique is challenged by the availability of suitable miscible gas. While, chemical EOR techniques are challenges by the high salt concentrations in the maturing oil reservoirs. The high salinity conditions encourage deficiencies in the performance of chemical EOR processes. Therefore, minimizing the effect of in situ salt on the injected chemical would impose tremendous improvement that leads to higher oil recovery. One way to diminish salt effect is to condition the oil reservoirs by injecting a slug of preflush water prior to chemical injection.In this paper, the performance of polymer flooding, after preflush slug, in high salinity reservoir is investigated by numerical simulation means. The injected slugs, both preflush and polymer, are driven by water. The objective is to identify the relationship between preflush, polymer, and drive water characteristics and oil recovery. Seven parameters were considered: preflush slug size, preflush salinity, polymer slug size, polymer concentration, polymer slug salinity, and drive water salinity. The results show that these parameters have various degree of influence on oil recovery. For example, increasing the preflush slug size would results in more oil recovery especially during the early time. Detailed findings will be presented in the paper.

  3. Petroleum coke adsorption as a water management option for oil sands process-affected water

    Energy Technology Data Exchange (ETDEWEB)

    Zubot, Warren [Syncrude Canada Ltd., Research and Development, Edmonton, Alberta, Canada T6N 1H4 (Canada); MacKinnon, Michael D. [OSPM Solutions Ltd., Hamilton, Ontario, Canada L8H 6X2 (Canada); Chelme-Ayala, Pamela; Smith, Daniel W. [University of Alberta, Department of Civil and Environmental Engineering, Edmonton, Alberta, Canada T6G 2W2 (Canada); Gamal El-Din, Mohamed, E-mail: mgamalel-din@ualberta.ca [University of Alberta, Department of Civil and Environmental Engineering, Edmonton, Alberta, Canada T6G 2W2 (Canada)

    2012-06-15

    Water is integral to both operational and environmental aspects of the oil sands industry. A water treatment option based on the use of petroleum coke (PC), a by-product of bitumen upgrading, was examined as an opportunity to reduce site oil sands process-affected water (OSPW) inventories and net raw water demand. Changes in OSPW quality when treated with PC included increments in pH levels and concentrations of vanadium, molybdenum, and sulphate. Constituents that decreased in concentration after PC adsorption included total acid-extractable organics (TAO), bicarbonate, calcium, barium, magnesium, and strontium. Changes in naphthenic acids (NAs) speciation were observed after PC adsorption. A battery of bioassays was used to measure the OSPW toxicity. The results indicated that untreated OSPW was toxic towards Vibrio fischeri and rainbow trout. However, OSPW treated with PC at appropriate dosages was not acutely toxic towards these test organisms. Removal of TAO was found to be an adsorption process, fitting the Langmuir and Langmuir-Freundlich isotherm models. For TAO concentrations of 60 mg/L, adsorption capacities ranged between 0.1 and 0.46 mg/g. This study demonstrates that freshly produced PC from fluid cokers provides an effective treatment of OSPW in terms of key constituents' removal and toxicity reduction. - Highlights: Black-Right-Pointing-Pointer Treatment of oil sands process-affected water (OSPW) using petroleum coke (PC) adsorption was investigated. Black-Right-Pointing-Pointer PC was effective at adsorbing naphthenic acids with higher cyclicity. Black-Right-Pointing-Pointer OSPW treated with PC at appropriate dosages was not toxic towards Vibrio fisheri and rainbow trout. Black-Right-Pointing-Pointer The adsorption of organic acids fitted the Langmuir and Langmuir-Freundlich isotherm models. Black-Right-Pointing-Pointer PC has the potential to be an effective adsorbent to treat OSPW either directly or as a pretreatment step.

  4. Petroleum coke adsorption as a water management option for oil sands process-affected water

    International Nuclear Information System (INIS)

    Water is integral to both operational and environmental aspects of the oil sands industry. A water treatment option based on the use of petroleum coke (PC), a by-product of bitumen upgrading, was examined as an opportunity to reduce site oil sands process-affected water (OSPW) inventories and net raw water demand. Changes in OSPW quality when treated with PC included increments in pH levels and concentrations of vanadium, molybdenum, and sulphate. Constituents that decreased in concentration after PC adsorption included total acid-extractable organics (TAO), bicarbonate, calcium, barium, magnesium, and strontium. Changes in naphthenic acids (NAs) speciation were observed after PC adsorption. A battery of bioassays was used to measure the OSPW toxicity. The results indicated that untreated OSPW was toxic towards Vibrio fischeri and rainbow trout. However, OSPW treated with PC at appropriate dosages was not acutely toxic towards these test organisms. Removal of TAO was found to be an adsorption process, fitting the Langmuir and Langmuir–Freundlich isotherm models. For TAO concentrations of 60 mg/L, adsorption capacities ranged between 0.1 and 0.46 mg/g. This study demonstrates that freshly produced PC from fluid cokers provides an effective treatment of OSPW in terms of key constituents' removal and toxicity reduction. - Highlights: ? Treatment of oil sands process-affected water (OSPW) using petroleum coke (PC) adsorption was investigated. ? PC was effective at adsorbing naphthenic acids with higher cyclicity. ? OSPW treated with PC at appropriate dosages was not toxic towards Vibrio fisheri and rainbow trout. ? The adsorption of organic acids fitted the Langmuir and Langmuir–Freundlich isotherm models. ? PC has the potential to be an effective adsorbent to treat OSPW either directly or as a pretreatment step.

  5. Water, oil, climate: a dried-up broken down world

    International Nuclear Information System (INIS)

    Climate crisis, oil crisis, water crisis, food crisis: the 21. century has started badly. Climate is deteriorating under man's action and natural resources are drying up while demand is still on the rise under the double effect of demographic and economic growth. Even worse, tensions are working together and worsen each other in a climate of financial crisis. All warning lights are on the red and a huge challenge has been launched which involves all countries, developed and developing. Solutions are urgently needed, otherwise our civilization would be threatened. The reasoned use of technologies, but also the abatement of poverty and inequalities and the education of people are essential points to take up the challenge. The authors examine the interconnections between energy, water, food at the time of climate change and explore the possible alternative solutions. The lesson that should be learnt from their analysis is that everyone should contribute to the complex decisions that will have an impact on the future of humanity. (J.S.)

  6. Automated IR determination of petroleum products in water based on sequential injection analysis.

    Science.gov (United States)

    Falkova, Marina; Vakh, Christina; Shishov, Andrey; Zubakina, Ekaterina; Moskvin, Aleksey; Moskvin, Leonid; Bulatov, Andrey

    2016-02-01

    The simple and easy performed automated method for the IR determination of petroleum products (PP) in water using extraction-chromatographic cartridges has been developed. The method assumes two stages: on-site extraction of PP during a sampling by using extraction-chromatographic cartridges and subsequent determination of the extracted PP using sequential injection analysis (SIA) with IR detection. The appropriate experimental conditions for extraction of the dissolved in water PP and for automated SIA procedure were investigated. The calibration plot constructed using the developed procedure was linear in the range of 3-200?gL(-1). The limit of detection (LOD), calculated from a blank test based on 3? was 1µgL(-1). The sample volume was 1L. The system throughput was found to be 12h(-1). PMID:26653498

  7. Effects of temperature on SCC propagation in high temperature water injected with hydrogen peroxide

    International Nuclear Information System (INIS)

    To understand the stress corrosion cracking (SCC) behaviour of austenitic stainless steels (SSs) in the boiling water reactor (BWR) coolant environment, it is significant to investigate the effect of hydrogen peroxide (H2O2) produced by the radiolysis of water on SCC under the various water chemistry and operational conditions. At the start-up or shut-down periods, for example, the conditions of radiation and temperature on the structural materi