Energy Technology Data Exchange (ETDEWEB)

Research activity during the 1991--1992 funding period has been concerned with the following topics relevant to carbon monoxide activation. (1) Exploratory studies of water gas shift catalysts heterogenized on polystyrene based polymers. (2) Mechanistic investigation of the nucleophilic activation of CO in metal carbonyl clusters. (3) Application of fast reaction techniques to prepare and to investigate reactive organometallic intermediates relevant to the activation of hydrocarbons toward carbonylation and to the formation of carbon-carbon bonds via the migratory insertion of CO into metal alkyl bonds.

Energy Technology Data Exchange (ETDEWEB)

This report details the status of the Biological Conversion of Synthesis Gas Project. The following tasks are described as being completed: (1) the test plan, (2) culture development, and (3) the mass transfer/kinetic studies. The bioreactor studies (Task 4) are underway. The continuous stirred tank reactor system for the conversion of H{sub 2}S to elemental sulfur using Chlorobium thiosulfatophilum has been studied for varying light intensities. The system was also modified to include both sulfur recovery and cell recycle using ceramic membranes. Studies were also performed to observe the effects of cell recycle using a polysulfone hollow filter membrane module. Work on Task 5, limiting conditions/scale-up, includes a scale-up study with three different size reactors to establish the optimum operating conditions for hydrogen production from synthesis gas by the biological water-gas shift reaction using ...

Science.gov (United States)

In the course of observing by means of Auger spectroscopy graphite gasification reactions catalyzed by metals, it has been found that in the presence of hydrogen, nickel appears to diffuse from the surface into the bulk of the graphite. When potassium is deposited on graphite, it is volatilized above 400/sup 0/C. Surprisingly the production of methane and carbon dioxide from the reaction of graphite and steam was catalyzed by potassium at as low a temperature as 250/sup 0/C. It has been shown that literature on the alkylation of benzene with synthesis gas is erroneous and that the products reported are due to Lewis acid catalyzed cracking of benzene. A novel cobalt mediated, reversible cleavage of a vinyl-hydrogen bond has been discovered. All products from the thermal decomposition of tetralin have been identified. The stereochemistry of cis-1, 2 dihydrotetralin was determined. In the utilization of the water gas ...

International Nuclear Information System (INIS)

We examined the spectral behaviors of lasing from a asymmetrically deformed liquid jet (a ? 14 ?m) which is induced by a laterally flowing gas. Th liquid sample was methanols which contains DCM dye. When n distortion is induced, the lasing spectrum appears as two periodic peaks which are corresponding to the resonance modes of cylindrical cavity. As the distortion parameter exceeds about 4%, the lasing spectrum shifts continuously to short wavelength. When the distortion parameter reaches ? 10%, the amount of blue shift was ? 30 nm. The blue shift can be explained as the shift of optimum wavelength of threshold curves. From the absorption and fluorescence curve of liquid sample, we estimated the spoiled Q with the distortion parameter.

Energy Technology Data Exchange (ETDEWEB)

No abstract prepared.

Energy Technology Data Exchange (ETDEWEB)

A Lurgi baseline study was requested by the DOE/GRI Operating Committee of the Joint Coal Gasification Program for the purpose of updating the economics of earlier Lurgi coal gasification plant studies for the production of substitute natural gas (SNG) based on commercially advanced technologies. The current study incorporates the recent experience with large size Lurgi plants in an effort to improve capital and operating costs of earlier plant designs. The present coal gasification study is based on a mine mouth plant producing 250 billion Btu (HHV) per day of SNG using the Lurgi dry bottom coal gasification technology. A Western subbituminous coal was designated as the plant food, obtained from the Rosebud seam at Colstrip, Montana. This study presents the detailed description of an integrated facility which utilizes coal, air, and water to produce 250 billion Btu (HHV) per day of SNG. The plant consists of coal handling and preparation, ...

Science.gov (United States)

A laser pyrolysis technique has been used to produce ultrafine particles of iron carbide with diameters ranging from 2 to 20 nm. Catalysis using iron carbide was investigated in the liquefaction of Wyodak subbituminous coal; yields were determined. A study was carried out to examine the possibility of using an ultrasonic extraction technique as a rapid method of product work-up of samples following pretreatment or liquefaction experiments. A similar study had shown that extraction of coal-derived products by an ultrasonic method was rapid and gave yields and product distributions comparable to those obtained by Soxhlet extraction. On another project, three different types of supported catalysts were used to test activity for the combined water-gas shift hydrogenation of a synthetic donor solvent. The three catalysts tested were: (1) Alumina supported NiMo catalyst-Shell 324m; (2) Bulk hydrous TiO NiMo catalyst; (3) Thin film hydrous TiO ...

International Nuclear Information System (INIS)

We performed density functional calculations to examine the effects of solvation, hydrogen bonding, backbone conformation, and the side chain on 15N chemical shielding in proteins. We used N-methylacetamide (NMA) and N-formyl-alanyl-X (with X being one of the 19 naturally occurring amino acids excluding proline) as model systems. In addition, calculations were performed for selected fragments from protein GB3. The conducting polarizable continuum model was employed to include the effect of solvent in the density functional calculations. Our calculations for NMA show that the augmentation of the polarizable continuum model with the explicit water molecules in the first solvation shell has a significant influence on isotropic 15N chemical shift but not as much on the chemical shift anisotropy. The difference in the isotropic chemical shift between the standard ?-sheet and ?-helical conformations ranges ...

Energy Technology Data Exchange (ETDEWEB)

Makeup water is distilled internally in an amine gas treating unit by adding it to the reclaimer used to process a slipstream of lean amine from the stripper.

International Nuclear Information System (INIS)

The tendency of welded joints from 10Kh14AG15 and 10Kh14AG9 steels to pitting corrosion under the conditions of operating blast-furnace gas purification scrubbers has been investigated. Water in scrubbers contains various quantities of chlorides and sulfates, has pH from 6 to 9 and temperature 65-75 deg. The laboratory corrosion tests have been carried out also on samples turned from the heat-affected zone (h.a.z.) of welded plates at 20 and 65 deg. Anode polarization curves have been read from the Vk corrosion potential at potential shifting rate 0.01 V/min. It is established that in most rigid conditions of scrubbers operating pitting corrosion (PC) rate of chrome-manganese nitrogen-containing steel can reach 2.5 mm/year. At high content of chlorides in water the elevated temperature and external tensile stresses intensify PC. The resistance of welded joints to PC when using welding materials on ...

Energy Technology Data Exchange (ETDEWEB)

This project dealt with use of condensing heat exchangers to recover water vapor from flue gas at coal-fired power plants. Pilot-scale heat transfer tests were performed to determine the relationship between flue gas moisture concentration, heat exchanger design and operating conditions, and water vapor condensation rate. The tests also determined the extent to which the condensation processes for water and acid vapors in flue gas can be made to occur separately in different heat transfer sections. The results showed flue gas water vapor condensed in the low temperature region of the heat exchanger system, with water capture efficiencies depending strongly on flue gas moisture content, cooling water inlet temperature, heat exchanger design and flue ...

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For light water reactors, loss of coolant is an important point in safety analysis, whereas for gas-cooled reactors the ingress of water into the core region is an incident of safety relevance. The applicability of the computer code system GAMTEREX to pebble beds of spherical high-temperature gas-cooled reactor fuel elements with simulated water ingress is verified by experiment. The measurements were performed at a Siemens-Argonaut reactor, using its ring core as a driver zone for a pebble-bed core in the center of the reactor.

Science.gov (United States)

The Morris water maze is widely used to evaluate to evaluate the spatial learning ability of rodents under laboratory settings. The present study demonstrates that reproductive male meadow voles, Microtus pennsylvanicus, are able to acquire and retain a spatial water maze task using celestial cues. Voles were able to acquire a modified outdoor Morris water maze task over 4 trials per day, whereby they had to learn and remember the location of a submerged hidden platform, using the position of the sun and associated celestial cues. Their proficiency on this task was related to the availability of the celestial cues, with voles displaying significantly poorer spatial navigation on overcast than clear days and when the testing time (and position of the sun and associated celestial cues) was shifted from morning to afternoon. These findings with meadow voles support the ecological relevance of the ...

International Nuclear Information System (INIS)

This paper describes a semi-empirical calculation of the air-broadened half-widths and the air pressure-induced frequency shifts for the H_2"1"6O isotopologue. This semi-empirical calculation is based on fits of several recent high-quality measurements and theoretical calculations to the first-order terms in the expansion of the complex Robert-Bonamy (CRB) equations, which yields a second- and first-order polynomial function of the differences in the upper- and lower-state vibrational quantum numbers for the half-width and line shift, respectively. The aim of this work was to obtain a complete set of air-broadened half-widths and air pressure-induced frequency shifts for transitions of H_2"1"6O present in the HITRAN database from microwave to the visible in order to supplement the observed and calculated values. For around 700 sets of rotational quantum numbers (J"'K_a"'K_c"'<-J"''K_a"''K_c"''), semi-empirical ...

Energy Technology Data Exchange (ETDEWEB)

Several lanthanide shift reagents (LSR) were synthesized from praseodymium, europium, dysprosium, and terbium using ethylenediaminetetraacetic acid, trans-1,2-diaminocyclohexane-N,N,N[prime],N[prime]-tetraacetic acid, and diethylenetriaminepentaacetic acid for the purpose of separating overlapping [sup 31]P FT-NMR spectral signals of dissolved organic phosphorus compounds present in concentrated lake-water samples. The extent of change in signal position and line width of several known phosphorus compounds dissolved in pure water was examined as a function of solution pH and the molar ratio of LSR to phosphorus. Praseodymium ethylenediaminetetraacetate (PrEDTA) was determined to be the most effective LSR. Concentrated lake-water samples mixed with PrEDTA were examined with [sup 31]P FT-NMR. The use of PrEDTA provided separation of overlapping signals, indicated that phosphorus compounds were becoming ...

International Nuclear Information System (INIS)

A high sensitivity, high bandwidth, two-color interferometer (1064 and 532 nm) has been tested on the Hawk pulsed power generator at the Naval Research Laboratory. The phase resolution is 10"-"5 waves with a rise time of 3 ns, a new capability for diagnosing plasmas, and neutrals in pulsed power experiments. The two-color feature is used to distinguish phase shifts from free (plasma) electrons and bound (neutral and ion) electrons. Simultaneous electron and neutral density measurements were demonstrated in a plasma opening switch (POS) experiment. The ability to measure small phase shifts with fast rise time were demonstrated in a plasma filled diode experiment. The high sensitivity and vibration isolation enable neutral gas distribution measurements from supersonic nozzles used in plasma radiation source experiments. Examples of these measurements and future applications are described. copyright 1997 American Institute of ...

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Gas hydrates are crystalline substances composed of water and gas, in which a solid-water-lattice accommodates gas molecules in a cage-like structure. Gas hydrates are globally widespread in permafrost regions and beneath the sea in sediment of outer continental margins. While methane, propane, and other gases can be included in the clathrate structure, methane hydrates appear to be the most common in nature. The amount of methane sequestered in gas hydrates is probably enormous, but estimates are speculative and range over three orders of magnitude from about 100,000 to 270,000,000 trillion cubic feet. The amount of gas in the hydrate reservoirs of the world greedy exceeds the volume of known conventional gas reserves. Gas hydrates also represent a significant drilling and ...

Science.gov (United States)

The effects of freeze-thaw cycling on the strength and durability of samples of compacted, stabilized, wet flue gas desulfurization (FGD) by-products are reported. The results of laboratory tests show a clear relationship between higher water contents and...

Energy Technology Data Exchange (ETDEWEB)

This article reports on the UN Environment Programme's (UNEP's) work in supporting the banking and financing sector by creating clean energy finance markets in developing countries. Details are given of the shifting of cash markets to credit, financing solar home systems in India, solar thermal lending in Tunisia, the financing of hotel based solar water heating in Morocco, and the Green Village Credit initiatives in the Yunnan province of China. The importance of providing banks with information needed to gain awareness and experience of renewable energy systems is stressed. The fundamentals of a bank engagement programme, financial catalysts, structuring market oriented approaches, and linking bank lending to policy making are discussed along with the need to shift to credit enhancements to help banks set up their first loan portfolios.

Energy Technology Data Exchange (ETDEWEB)

Isotope shift measurements have been performed for the {sup 242{ital f}}Am fission isomer with target production rates of only a few per second. The method is based on resonance ionization spectroscopy (RIS) in a buffer gas cell with radioactive decay detection of the ionization process (RADRIS). A relative isotope shift ratio X{sub {ital exp}}=IS{sup 242{ital f},241}/IS{sup 243,241}=41.7{plus_minus}0.9 has been measured for the 500.02 nm transition corresponding to a nuclear parameter A{sup 242{ital f},241}=(5.4{plus_minus}0.3) fm{sup 2}. A preliminary analysis of the quadrupole moment based on the deformed Fermi model of the nuclear charge distribution results in Q{sub 20}=35.9{plus_minus}1.1({sup +0.3}{sub {minus}0.7}) {sub model} eb. {copyright} 1995 {ital American} {ital Institute} {ital of} {ital Physics}

UK PubMed Central (United Kingdom)

Objectives. Thousands of Louisiana residents were asked to boil water because of widespread disruptions in electricity and natural gas services after Hurricane Rita. We sought to assess...Full Text Available

International Nuclear Information System (INIS)

The chemical composition and evolution of produced waters associated with gas production in the Palm Valley gas field, Northern Territory, has important implications for issues such as gas reserve calculations, reservoir management and saline water disposal. The occurrence of saline formation water in the Palm Valley field has been the subject of considerable debate. There were no occurrences of mobile water early in the development of the field and only after gas production had reduced the reservoir pressure, was saline formation water produced. Initially this was in small quantities but has increased dramatically with time, particularly after the initiation of compression in November 1996. The produced waters range from highly saline (up to 300,000 mg/L TDS), with unusual ...

British Library Electronic Table of Contents (United Kingdom)

The effect of water shortage on growth and gas exchange of maize grown on sandy soil (SS) and clay soil was studied. The lower soil water content in the SS during vegetative growth stages did not affect plant height, above-ground biomass, and leaf area index (LAI). LAI reduction was observed on the SS during the reproductive stage due to early leaf senescence. Canopy and leaf gas exchanges, measured by eddy correlation technique and by a portable photosynthetic system, respectively, were affected by water stress and a greater reduction in net photosynthetic rate (A N) and stomatal conductance (g s) was observed on SS. Chlorophyll and carotenoids content was not affected by water shortage in either condition. Results support two main conclusions: (1) leaf photosynthetic capacity was unaffec...

Energy Technology Data Exchange (ETDEWEB)

The report identifies and analyzes the economic impacts of water pollution control regulations on the battery manufacturing industry. These regulations include effluent limitations and standards based on BPT (best practical control technology currently available), BAT (best available technology economically achievable), PSES (pretreatment standards existing sources), NSPS (new source performance standards), and PSNS (pretreatment standards new sources), that have been promulgated under authority of Sections 301, 304, 306, 307, 308, and 501 of the Federal Water Pollution Control Act, as Amended (the Clean Water Act). The primary economic impact variables of interest include price changes, plant closures, substitution effects, changes in employment, shifts in the balance of foreign trade, changes in industry profitability, structure, and competition, and impacts on small business.

Science.gov (United States)

The developments of fields in deep waters (5000 ft and more) is a common occurrence. It is inevitable that production systems will operate under multiphase flow conditions (simultaneous flow of gas-oil-and water possibly along with sand, hydrates, and wax...

Energy Technology Data Exchange (ETDEWEB)

In situ Auger sputter depth profiles of saturation implants of 3 keV N/sub 2//sup +/ in silicon at room temperature exhibit a sharp peak in the nitrogen concentration in the outermost layers, followed by a monotonic decrease. No broad plateau was observed. The energy of the Auger line corresponding to the Si(2p) core electron excitation, monitored throughout the profiling, exhibits a chemical shift of up to 7 eV at the surface peak concentration. Inert gas ion post-bombardment of unsaturated implants significantly modifies the profile, and supports the suggestion that the surface peak arises through radiation enhanced diffusion of implanted atoms.

Energy Technology Data Exchange (ETDEWEB)

Most plans for the disposition of surplus nuclear materials involve storage in sealed containers where the evolution of gases from reactions of adsorbed water could present both pressure and flammability hazards[l] . Despite efforts such as calcining the material to minimize the water content prior to packaging, both residual moisture and readsorbed water may be present in the final containers . Given the anticipated temperature excursions during transportation and storage, this water may thermally desorb, increasing the pressure, and/or thermally dissociate to produce H2 gas, increasing flammability hazards . In addition, the radiation from the nuclear material may induce radiolysis of the water with the likely products being water vapor, H2, 02 and H2O2. In order to better understand the relative importance of the thermal- and ...

International Nuclear Information System (INIS)

Ozone formation by a pulse positive corona discharge generated in the gas phase between a planar high voltage electrode made from reticulated vitreous carbon and a water surface with an immersed ground stainless steel plate electrode was investigated under various operating conditions. The effects of gas flow rate (0.5-3 litre min"-"1), discharge gap spacing (2.5-10 mm), applied input power (2-45 W) and gas composition (oxygen containing argon or nitrogen) on ozone production were determined. Ozone concentration increased with increasing power input and with increasing discharge gap. The production of ozone was significantly affected by the presence of water vapour formed through vaporization of water at the gas-liquid interface by the action of the gas phase discharge. The highest energy efficiency for ozone production ...

Energy Technology Data Exchange (ETDEWEB)

Environmental studies in slip-stream process development units at SCGP-1, Shell's advanced coal gasification demonstration plant, located near Houston, Texas, have demonstrated that the gas and water effluents from the Shell Coal Gasification Process (SCGP) are environmentally benign on a broad slate of coals. This report presents the results of those environmental studies. It contains two major subjects, which describe, respectively, the experiments on gas treating and the experiments on water treating. Gas treatment focused on the performance of aqueous methyldiethanolamine (MDEA) and sulfinol-M. 8 refs., 24 figs., 13 tabs.

International Nuclear Information System (INIS)

The chemical composition and evolution of formation waters associated with gas production in the Palm Valley field, Northern Territory, has important implications for reservoir management, saline water disposal, and gas reserve calculations. Historically, the occurrence of saline formation water in gas fields has been the subject of considerable debate. A better understanding of the origin, chemical evolution and movement of the formation water at Palm Valley has important implications for future reservoir management, disposal of highly saline water and accurate gas reserves estimation. Major and trace element abundance data suggest that a significant component of the highly saline water from Palm Valley has characteristics that may have been derived from a modified evaporated ...

Energy Technology Data Exchange (ETDEWEB)

Raman scattering was observed from thin film optical waveguides of cellulose acetate exposed to water vapor from 0% to 100% relative humidity (RH), and from dilute solutions of water in methyl acetate. Spectra of cellulose acetate (CA398, 39.8% acetyl) at low RH and cellulose triacetate (CTA) at low and high RH are consistent with the presence of water monomers that are weakly hydrogen bonded to acetyl C=O groups. Differences between the spectra of water in CA398 and CTA at low RH are attributed to sequential hydrogen bonding involving OH groups in CA398. At high RH, CA398 and CTA (to a lesser extent) show bands attributed to water/water interactions that are similar to those found in sequentially hydrogen-bonded hydrates. CA398 films that are annealed at high temperatures exhibit decreased water/water interactions at high RH. Exposure of CA398 films to D/sub ...

Energy Technology Data Exchange (ETDEWEB)

The purpose of this study is to identify the radiative heat transfer augmentation by a coaxial cylinder introduced in the infinite cylindrical pipe enclosing a participating gas. The gas is either a mixture of water vapor and carbon dioxide or gray. The gas is assumed to be homogeneous at a constant temperature, and has a refractive index of unity. All of the surfaces are opaque and gray, diffusely emitting and reflecting at a constant temperature. The effect of system diameter, diameter ratio, wall emittances, gas and surface temperatures, mixture component on heat transfer augmentation are studied by using the zone method with participating gas radiative properties evaluated from the weighted sum of gray gases model. From the radiative equilibrium condition, the installed wall temperature is formulated and calculated by the iteration method. If the medium is a ...

International Nuclear Information System (INIS)

Reliable and consistent characterization of the stable isotope composition of atmospheric water vapour and its temporal variability are important prerequisites to the wider application of isotope mass balance methods in atmospheric and water balance studies. A new approach is proposed which utilizes standard class-A evaporation pans, which have sufficient volume to buffer short-term transient variations in atmospheric conditions, justifying the assumption of constant kinetic isotopic fractionation effects in concert with precisely measured temperature and relative humidity to derive vapour isotopic composition. The results of the studies suggest that isotopic sampling of existing, conventionally operated class-A evaporation pans could offer a straightforward and cost-effective solution to the problem of documenting the shifting isotopic distribution in atmospheric moisture

Energy Technology Data Exchange (ETDEWEB)

Conversion of coal gas into liquid products is a multistep process which involves numerous unit processes. Compared with similar processes using natural gas as feedstock, there are challenges, particularly with the gas purification. There are, however, also advantages when using a carbon-monoxide-rich gas which ultimately may result in a greatly simplified process. This paper discusses the challenges when converting a gas from an entrained coal gasifier into a liquid product and the paper presents the various options available. The following issues will be touched upon: sour gas shift and adjustment of the H{sub 2}/CO ratio; acid Gas Removal (AGR) - when and how; syngas purification; methanol and combined methanol/DME synthesis; gasoline synthesis; future integrated processes. Here, various options are available ...

International Nuclear Information System (INIS)

Short-lived fission gas release from fuel pellets during irradiation was investigated based on the experimental results of the gas-flow rigs irradiated in the Halden Heavy Water Reactor (HBWR). The release-to-birth (R/B) rates of short-lived fission gas were measured by means of gas-flow measurement during the irradiation experiments. Surface-to-volume (S/V) ratios of fuel pellets and diffusion coefficients of short-lived fission gas release were evaluated from the obtained (R/B) values. The increase of (S/V) ratio agreed well with the point where the fuel temperature exceeded the threshold of 1% fission gas release. This indicates that the interlinkage of fission gas bubbles occurred there. The evaluated diffusion coefficients scattered in the range between 10"-"2"3 and 10"-"1"7 m"2/s, and the effects of fuel type (UO_2 ...

Energy Technology Data Exchange (ETDEWEB)

Discusses scaling of closed systems for cooling coal gas from black coal coking. Scaling rate and factors that influence scaling are analyzed. Physical and chemical properties of scale buildup on the inner walls of pipe cooling systems are evaluated. Water pH value and its effects on scaling and solubility of chemical compounds that form scale are discussed. Use of ammonium sulfate for scale control is analyzed. Consumption rate of ammonium sulfate depends on ambient temperature, water pH value and chloride content in return water. Formulae for calculating optimum content of ammonium sulfates for scale control are derived. 3 refs.

Energy Technology Data Exchange (ETDEWEB)

Nanoparticles of AgBr were prepared by precipitating AgBr in the water pools of microemulsions consisting of CTAB, n-butanol, isooctane and water. An aqueous solution of AgNO{sub 3} added to the microemulsion was the source of Ag{sup +} ions. The formation of AgBr nanoparticles in microemulsions through direct reaction with the surfactant counterion is a novel approach aimed at decreasing the role of intermicellar nucleation on nanoparticle formation for rapid reactions. The availability of the surfactant counterion in every reverse micelle and the rapidity of the reaction with the counterion trigger nucleation within individual reverse micelles. The effect of the following variables on the particle size and size distribution was investigated: the surfactant and cosurfactant concentrations, moles of AgNO{sub 3} added, and water to surfactant mole ratio, R. High concentration of the surfactant or cosurfactant, or high ...

International Nuclear Information System (INIS)

The production of ozone in a negative corona discharge fed by carbon dioxide with embedded traces of oxygen and water has been studied. The presence of traces of oxygen in both pure and dry CO_2 leads to an increase in nascent ozone concentrations. In contrast, traces of water vapour (0-800 ppm) are shown to rapidly suppress ozone concentrations with the largest decreases being observed at lowest gas pressures in the discharge (300 Torr). The presence of water vapour did not considerably affect the electrical properties of negative dc corona suggesting that a chemical process is responsible for the ozone loss. We have shown that the addition of water up to a concentration of 1500 ppm has only a marginal effect on the processes of ozone formation but the catalytic cycle of ozone destruction involving OH radicals can be the reason for observed decrease in the total ozone concentration ...

International Nuclear Information System (INIS)

On the basis of environmental considerations, a high temperature gas cooled reactor (HTGR) was proposed as the heat source for the Natuna project for CO_2 conversion. To convert CO_2 to useful products, a large amount of high quality water is required for the chemical processes, boilers and other purposes. One LNG production train (maximum of six trains) would produce 0.4 x 10"9 SCF/d of saleable gas and 1.4 x 10"9 SCF/d of CO_2 (in the case of the Exxon process). This CO_2 gas would then be converted to automobile fuel (methane, methanol), which requires a large amount of water. Natural gas from an off- shore gas field is piped to the petrochemical complex on Natuna Island (about 228 km). Natuna is a small island that, apart from sea water, does not have much available water. The desalination ...

International Nuclear Information System (INIS)

The guide describes a method acceptable to the NRC staff for complying with the Commission's regulations with regard to quality assurance requirements for installation, inspection, and testing of mechanical equipment and systems for water-cooled and high-temperature gas-cooled nuclear power plants.

Energy Technology Data Exchange (ETDEWEB)

Operation safety and reliability are major guidelines in the design of city-gate units. Conventional natural gas heaters operate by a indirect mechanism, where liquid water is used to transfer heat by natural convection between the combustion chamber and the natural gas coil. In this work, the concept of vapor chamber is evaluated as an indirect gas heater. In a vapor chamber, liquid water is in contact with the heat source, and vaporizes. The vapor condenses in contact with the heat sink. A reduced scale model was built and tested in order to compare these two heating concepts where the combustion chamber was replaced by electrical cartridge heaters. This engineering model can operate either as a conventional heater or as a vapor chamber. The comparison between the concepts was done by inducing a controlled power to the cartridges and by measuring the resulting temperature ...

Energy Technology Data Exchange (ETDEWEB)

A new process for the removal of tar from biosyngas, OLGA (Oil and Gas Washer), is presented. This gas cleaning technology is based on physical principles and is designed to eliminate tar problems that relate to fouling and er pollution. The applied principles are confirmed by experimental validation. OLGA can be operated without suffering from harmful effects on important gasification characteristics as cold gas efficiency, gasifier simplicity, and feedstock flexibility. Some fundamental considerations in the development of OLGA are discussed. Amongst these is a different approach to the tar problem. This approach does not consider the total tar content as decisive in the evaluation of gas cleaning equipment. Instead, evaluation is focussed on whether tar properties as condensation behaviour and water solubility can still occur. A biosyngas free of tar should therefore be ...

Energy Technology Data Exchange (ETDEWEB)

Two-phase flow in horizontal parallel channels has been experimentally investigated under fuel cell related operating conditions. Pronounced hysteresis is observed in the pressure drop versus flow characteristic curve when starting from either flooded or dry conditions. When gas is introduced into channels initially filled with water (flooded initial condition), both gas and liquid tend to flow predominantly in one channel at low gas or liquid flow velocities. As the gas flow velocity increases, even distribution of gas and liquid flow in both channels is observed, accompanied with a sudden decrease in the pressure drop. On the other hand, even gas and liquid flow distribution between both channels is found at comparatively lower gas flow velocities when starting with dry-gas flow conditions with ...

Energy Technology Data Exchange (ETDEWEB)

This document contains the outline and viewgraphs used in the speech. Topics covered are: conventional oil and gas recovery; unconventional oil and gas sources; oil shale resources; conventional coal combustion; advanced fossil power systems; fluidized bed combustion; coal/oil or coal/water mixtures; and gaseous and liquid fuels from coal. (DMC)

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This article describes a new natural-gas-fired combined cycle cogeneration plant in Bellingham, Washington. The topics of the article include community impact, siting constraints, natural gas fuel, the flexibility provided by the steam turbine, the cooling tower and pumps, air-quality, noise, and cooling water system constraints, and community relations program.

Energy Technology Data Exchange (ETDEWEB)

Increasing quantities of chicken waste concerns the poultry industry because of escalating disposal costs and the potential for environmental pollution. Biological conversion of these wastes to valuable products such as methane and/or chemical feed-stocks appears to be feasible. Biomethanation of chicken waste by a sewage sludge microbial consortium produced as much as 69 mol% methane in the gas phase. Acetic and propionic acids were the major acids produced during the bioconversion. Addition of chelating agents and other micro-nutrients enhanced methane production and shifted the ratios of intermediates accumulated. Preliminary data indicate that more than 60% of the chicken waste carbon was converted and that the nitrogen-rich residue may have potential as a soil additive. (author).

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This article describes the state-of-the-art HVAC system at the Philadelphia Marriott Hotel. Thermal comfort and indoor air quality are emphasized. The system uses a hybrid gas absorption/electric centrifugal chilled water plant, variable flow pumping, water-side economizers to provide free cooling, central air handling units with air-side economizers and flow monitoring equipment.

Energy Technology Data Exchange (ETDEWEB)

A proton exchange membrane fuel cell (PEMFC) must maintain a balance between the hydration level required for efficient proton transfer and excess liquid water that can impede the flow of gases to the electrodes where the reactions take place. Therefore, it is critically important to understand the two-phase flow of liquid water combined with either the hydrogen (anode) or air (cathode) streams. In this paper, we describe the design of an in situ test apparatus that enables investigation of two-phase channel flow within PEMFCs, including the flow of water from the porous gas diffusion layer (GDL) into the channel gas flows; the flow of water within the bipolar plate channels themselves; and the dynamics of flow through multiple channels connected to common manifolds which maintain a uniform pressure differential across all possible flow paths. These two-phase ...

British Library Electronic Table of Contents (United Kingdom)

Solid-phase extraction and gas chromatography with electron-capture detection has been used for sensitive, simple, and reliable analysis of carfentrazone-ethyl residues in water. Carfentrazone-ethyl was enriched by use of multiwalled carbon nanotubes (MWCNT), a new adsorptive material. Several conditions affecting recovery of the analyte, for example polarity and volume of eluents, pH of water samples, and sample volume, were studied. Recovery from fortified samples, linear range, and limit of detection were evaluated. The results showed that MWCNT are an efficient SPE adsorbent for preconcentration of carfentrazone-ethyl in water. Under the optimized SPE conditions, recovery of carfentrazone-ethyl from fortified water was 81.49?91.08%, with RSD from 1.66 to 8.21%. The limits of detection ...

British Library Electronic Table of Contents (United Kingdom)

Survival and growth of terrestrial plants is negatively affected by complete submergence. This is mainly the result of hampered gas exchange between plants and their environment, since gas diffusion is severely reduced in water compared with air, resulting in O2 deficits which limit aerobic respiration. The continuation of photosynthesis could probably alleviate submergence-stress in terrestrial plants, but its potential under water will be limited as the availability of CO2 is hampered. Several submerged terrestrial plant species, however, express plastic responses of the shoot which may reduce gas diffusion resistance and enhance benefits from underwater photosynthesis. In particular, the plasticity of the flooding-tolerant terrestrial species Rumex palustris turned out to be remarkable,...

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The Lawrence Livermore National Laboratory has developed a mobile field laboratory for remote measurement of atmospheric processes and observables that are important in global climate change, dispersal of hazardous materials, and atmospheric pollution. Specific observables of interest are water vapor, trace gases, aerosol size and density, wind, and temperature. The goal is to study atmospheric processes continuously for extended periods in remote field locations. This laboratory has just reached field ready status with sensors for aerosol and trace gas measurement based on established techniques. A development program is underway to enhance the sensor suite with several new techniques and instruments that are expected to significantly extend the state of the art in remote trace gas analysis. The new sensors will be incorporated into the lab during the next two years.

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The addition of ZnO, depleted in the Zn-64 isotope, to the water of boiling water nuclear reactors lessens the accumulation of Co-60 on the reactor interior surfaces, reduces radioactive wastes and increases the reactor service-life because of the inhibitory action of zinc on inter-granular stress corrosion cracking. To the same effect depleted zinc in the form of acetate dihydrate is used in pressurized water reactors. Gas centrifuge isotope separation method is applied for production of depleted zinc on the industrial scale. More than 20 years of depleted zinc application history demonstrates its benefits for reduction of NPP personnel radiation exposure and combating construction materials corrosion.

Energy Technology Data Exchange (ETDEWEB)

Better understanding and modelling of three-phase flow through porous media is of great interest, especially for improved oil recovery methods such as gas injection processes. Early theoretical and experimental studies have already demonstrated that the wettability characteristics of the solid surface and the spreading characteristics of the fluid system hold the key roles. This observation is confirmed by our theoretical results using DLP theory on the stability and the thickness of static oil films. In most of the works related to three-phase flow processes, homogeneous wettability is assumed. There exist only a few studies demonstrating the tremendous impact of the wettability heterogeneities on gas injection. The objective of the present work is twofold: to demonstrate the effect of small scale wettability heterogeneities on gas injection efficiency, and to develop a tool to predict this impact for various patterns and ...

UK PubMed Central (United Kingdom)

Using observational and interview approaches, we evaluated the usability of a web-based communication tool that allows managers to announce open work shifts and staff to request work shifts....Full Text Available

Energy Technology Data Exchange (ETDEWEB)

The thermal stability of wood polymer composites made with extractive-free wood from four different wood species was studied. Hot water (HW) extractives, ethanol/cyclohexane (E/C) extractives and both types of extractives were eliminated from A. cyclops, E. grandis, P. radiata and Q. alba. Composites of LLDPE and 10 wt% of wood were prepared, using poly vinyl alcohol-co-ethylene (EVOH) as a compatibilizer. The thermal degradation behavior of the composites was characterized with thermogravimetric analysis (TGA). The obtained results showed that in all cases, the degradation temperatures shifted to higher values after removal of the extractives. The removal of E/C extractives was less effective in its improvement of the thermal stability than the removal of HW extractives. The largest improvement on the thermal stability of WPCs was achieved when both types of extractives (E/C and HW) were removed.

British Library Electronic Table of Contents (United Kingdom)

This study correlates the post start cell performance and impedance with the cold start process in the subzero environment. The sequential failed cold starts are deliberately conducted as well as the start at small current density. Here the failed cold start means the cell voltage drops to or below zero within very short time during the start process. It is found that there are reversible performance losses for the sequential failed cold starts, while not obvious degradation and no recovery happen for the start at small current density. Using the thin film and agglomerate model, it is confirmed that this is due to the water blocking effect. Comparing the results from different start processes, a model with respect to the shifting of reactive region within the catalyst layer is applied to e...

Energy Technology Data Exchange (ETDEWEB)

A two-phase flow regime map is developed experimentally and theoretically for a vertical hexagonal flow channel with and without a 36-finned rod hexagonal bundle. This type of flow channel is of interest to MAPLE-type nuclear research reactors. The flow regime maps are determined by visual observations and observation of waveforms shown by a capacitance-type void fraction meter. The experimental results show that the inclusion of the finned hexagonal bundle shifts the flow regime transition boundaries toward higher water flow rates. Existing flow regime maps based on pipe flow require slight modifications when applied to the hexagonal flow channel with and without a MAPLE-type finned hexagonal bundle. The proposed theoretical model agrees well with experimental results.

British Library Electronic Table of Contents (United Kingdom)

Research in the field of river hydrology has been mainly concerned with the investigation of the rainfall-runoff phenomenon through the analysis of hydrological factors such as meteorology and geography, with the focus being on each river basin. Recently, various forms of digital information such as GIS (Geographic Information System) and RS (Remote Sensing) data have been made available in worldwide digital map format. Therefore, there has been a shift in focus from lumped-parameter models to distributed runoff models, as the latter can consider temporal and spatial variations in water quantity. Distributed runoff models have made possible the comparison of runoff field and rainfall-runoff characteristics considering spatial distribution. Hydrological conditions are differently distribute...

Energy Technology Data Exchange (ETDEWEB)

The 380 MW combined cycle gas turbine power station in Peterborough changed its water supply from town mains to high purity reverse osmosis permeate in October 2000. The high purity water is produced from secondary treated sewage effluent using advanced membrane technology. Alpheus Environmental and British Gas staff have recently completed a study of the power station's demineralization plant to identify the differences in operating costs associated with the change in feedwater. The results show that the ultrapure water produced after the change to a high purity feed is of improved quality and that the demineralization plant regeneration operating costs have been reduced by over 90%. The demineralization plant availability has increased from 78 to 98% enabling almost 20% more ultra pure water to be produced. The change in feedwater has also improved ...

Energy Technology Data Exchange (ETDEWEB)

The ''Enabling & Information Technology To Increase RAM for Advanced Powerplants'' program, by DOE request, was re-directed, de-scoped to two tasks, shortened to a 2-year period of performance, and refocused to develop, validate and accelerate the commercial use of enabling materials technologies and sensors for coal/IGCC powerplants. The new program was re-titled ''Enabling Technology for Monitoring & Predicting Gas Turbine Health & Performance in IGCC Powerplants''. This final report summarizes the work accomplished from March 1, 2003 to March 31, 2004 on the four original tasks, and the work accomplished from April 1, 2004 to July 30, 2005 on the two re-directed tasks. The program Tasks are summarized below: Task 1--IGCC Environmental Impact on high Temperature Materials: The first task was refocused to address IGCC environmental impacts on high temperature materials used in ...

Energy Technology Data Exchange (ETDEWEB)

Production of hydrogen sulfide in produced waters due to the activity of sulfate-reducing bacteria (SRB) is a potentially serious problem. The hydrogen sulfide is not only a safety and environmental concern, it also contributes to corrosion, solids formation, a reduction in produced oil and gas values, and limitations on water discharge. Waters produced from seawater-flooded reservoirs typically contain all of the nutrients required to support SRB metabolism. Surface processing facilities provide a favorable environment in which SRB flourish, converting water-borne nutrients into biomass and H{sub 2}S. This paper will present results from a field trial in which a new technology for the biochemical control of SRB metabolism was successfully applied. A slip stream of water downstream of separators on a produced water handling facility was ...

Energy Technology Data Exchange (ETDEWEB)

Polyethylene pipes and connections are being widely used in treated water distribution services. Migration of low molecular weight compounds from the polyethylene into the water can change its final quality. This paper is about the concentrations and identification of the migration compounds found in treated water after staying in contact with low and high-density polyethylene. Identification and quantification were carried out using CLSA (Closed Loop Stripping Analysis) extraction technique and gas chromatography coupled to mass spectrometry (HRGC/HRMS). (Author) 12 refs.

Energy Technology Data Exchange (ETDEWEB)

This paper presents a mathematical model for simultaneous heat and moisture transfer under freezing-thawing in porous hygroscopic material. Even below O{sup o}C, unfrozen liquid water exists in the material which plays an important role in the processes. The model takes into account the existence of unfrozen liquid water. The system is treated as a three-(gas, liquid and solid) phase system of water. Moisture chemical potential is used as a moisture potential. Under freezing, moisture chemical potential is a unique function of local temperature. So, during freezing, two unknown variables to be solved are solid water content and moisture potential or temperature. A simple example of simulation for freezing processes is shown. (author)

Energy Technology Data Exchange (ETDEWEB)

Precondition for the low-NO operation of gas turbine burners is the generation of as homogeneous as possible a gaseous fuel/air mixture. Such a burner behavior can be achieved by selective adaptation of the flow and injection. A computing model is introduced that calculates the dynamically balanced GASs/droplet flow through numerical solution of the transport equations in a curved orthogonal coordinate system. The feedback reaction of the fuel droplets to the gas phase is considered by source terms and/or sink terms. Test computations were carried out for comparison with analytical solutions from the flow mechanics and validated by comparison with measurement results. Droplet motion and evaporation were checked by means of published experimental results on single droplets. For the validation of the developed computing technique, model tests were carried out with water in place of fuel. It is pointed out that the choice of ...

International Nuclear Information System (INIS)

The major driver to enhance the efficiency of the simple gas turbine cycle has been the increase in process conditions through advancements in materials and cooling methods. Thermodynamic cycle developments or cycle integration are among the possible ways to further enhance performance. The current paper presents the possibilities and advantages from the LOTHECO natural gas-fired combined cycle concept. In the LOTHECO cycle, low-temperature waste heat or solar heat is used for the evaporation of injected water droplets in the compressed air entering the gas turbine's combustion chamber. Following a description of this innovative cycle, its advantages are demonstrated by comparison between different gas turbine power generation systems for small and large-scale applications, including thermodynamic and economic analysis. A commercial gas turbine (ALSTOM GT10C) ...

International Nuclear Information System (INIS)

In a fuel assembly having moderator rods, an axial average value of a ratio between the total of the lateral cross sectional area of a portion to be filled with moderators and the total of the lateral cross sectional area of fuel pellets is determined as greater than 0.4, a lateral cross sectional area of a portion to be filled with moderators per one moderator rod is determined as from 14 to 50cm"2 and the ratio between the total of the lateral cross sectional area of moderators and a total of the lateral cross sectional area of fuel pellets in a horizontal cross section is determined as from 2.7 to 3.4. Since the axial average value for lateral cross sectional area of a portion to be filled with moderators/lateral cross sectional area of fuel pellets is determined as #>=# 0.4, the lateral cross sectional area of moderators of moderator rods is increased, the lateral cross sectional area of a gap water region is decreased to reduce the value of local power ...

Energy Technology Data Exchange (ETDEWEB)

In a PWR type reactor, a primary coolant circuit system using a steam generator is adopted in order to accelerate depressurization of a primary coolant circuit upon small rupture LOCA in which the pressure of the primary coolant circuit is moderately depressurized. A secondary coolant circuit depressurization valve is disposed to a main steam pipeline. The valve has a performance of automatically opening to remove heat by evaporation of water stored in SG for a short period of time when the pressure in the primary circuit is decreased to about 50kg/cm[sup 2] upon occurrence of LOCA or the like. Then, the secondary side of the SG is depressurized to about atmospheric pressure and gravitational water injection from a condensate tank is started. Further, a gas vent valve is disposed to a water chamber of the steam generator. The valve has a performance of automatically opening to discharge incondensible ...

Science.gov (United States)

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Energy Technology Data Exchange (ETDEWEB)

Gas well load up is the loss of available reservoir energy due to the accumulation of liquids in the wellbore over time, and these liquids arise from liquids (hydrocarbons and water) condensed from the gas. Accumulation of these liquids near the wellbore can cause severe reduction to complete loss of available transport energy. A systematic experimental approach was undertaken to evaluate the performance of foam in removing liquids from the bottom of wells. The objectives of the research were: (1) to determine the efficiency of liquid lifting with foam; and (2) to compare the effects of surfactant type and concentration on liquid lifting. A flowloop successfully simulated the effects of completions with and without packer for low-pressure gas well with liquid production. In the base-case runs (air and water flow), the two phase flow regime was mostly annular. Liquid lifting is ...

Energy Technology Data Exchange (ETDEWEB)

Gas distribution companies have long since paid great attention to improving the quality and safety of the gas supply service to the consumer. In particular the management of gas emergencies has always been a responsibility taken seriously by all sectors of the gas industry. Over the last few years, however, the concept and practices in risk management have been changing rapidly. This has involved gas companies in an on-going attempt to successfully define and establish clear computer assisted risk management practices. Risk management is the systematic use of management policy, procedures and means, with the aim to protect employees, the public, the environment and properties at an acceptable cost. This paper has the purpose of presenting: - the computer software of gas emergency management in use at Italgas S.p.A. for testing the performance of ...

Science.gov (United States)

Rubber lining is used as a corrosion protection material in European flue gas desulfurization plants, for scrubbers, tanks, pipe systems, etc. Although these rubber linings can last more than 15 years, relining still is necessary. The difficulty of shutting down power station units requires that the time scale of this replacement be kept to a minimum. High-pressure water systems have proven successful as an efficient method for removal of the old lining. The working steps and time scale are demonstrated for one such relining case.

Energy Technology Data Exchange (ETDEWEB)

Energy savings in the synthetic fiber industry could be realized by using autoclave reactor condensate and boiler flue gas heat recovery. The non-cellulose (polyester) production process analysis shows that condensate returning from the reactor to the steam boiler raises inlet temperature, giving a reduced fuel requirement of about 8%. Also, boiler flue gas with a sufficiently high outlet temperature for boiler feed water and combustion air preheating results in further fuel savings. The process with an economizer saves up to 8.44%, and with a combustion air preheater, 6.25%. (Author)

International Nuclear Information System (INIS)

Results of ongoing research project at the McMaster Nuclear Reactor Facility on real-time neutron radiography for the visualization of interfacial geometry, movements and phase distributions in gas-liquid and gas-liquid-metal multi-phase flows are presented. Experiments were conducted with bubble column tubes with boiling liquid nitrogen, air-water and air-mercury mixtures. Discussions are also focused on air-water flowing within a tube containing a CANDU type 37 rod fuel bundle assembly positioned both horizontally and vertically. Computer processing using a digital image format to enhance the real-time images was used. Imaging techniques include frame averaging, background substraction, edge enhancement (spatial filtering), contrast enhancement and video densitometry. (orig.).

Energy Technology Data Exchange (ETDEWEB)

In an attempt to overcome inadequacies perceived in the approach to providing energy to village communities using the conventional Khadi and Village Industries Commission biogas plant as well as the Janata model, a biogas digester has been developed suitable for a farmer having only one hectare of land. The information on gas yields and other data from a variety of substrates in a laboratory digester are presented. The digester itself consists of a chamber underground into which the influent flows through a channel. Gas is collected in a dome which constitutes the upper part of the digestion chamber and is maintained under pressure by water. The dome can be made of any suitable material such as plastic, ferrocement and brick and mortar. The upper part of the chamber itself is exposed to sun light which enhances microbial growth. Water which surrounds the dome ensures a minimum of temperature variation. ...

International Nuclear Information System (INIS)

SiC has been considered as a primary candidate material for a first wall component in future fusion reactor because it has been claimed that SiC has excellent high-temperature properties, good chemical stability and low activation. However, the behavior of tritium on SiC has not been discussed yet. In this study, tritium trapping capacity on the surface of SiC was experimentally obtained at the temperature range of 25-800 deg. C in consideration of tritium trapping to the experimental system. The capacity, which was independent of the water vapor pressure in the gas phase and the temperature, was determined as about 10"6 Bq/cm"2. The isotope exchange reaction rate between tritiated water in a gas phase and hydrogen on the surface was quantified at the temperature of 25, 500 and 700 deg. C in consideration of the behavior of tritium trapping at change of experimental condition by the numerical curve ...

International Nuclear Information System (INIS)

Nuclear energy provides a third of Europe's electricity with nearly no greenhouse-gas emissions. Sustained efforts are now being conducted to harmonize regulations all over Europe through WENRA and to converge on technical nuclear safety practices within the TSO network ETSON (European Technical Safety Organizations Network). In CANDU type NPP the tritiated water occurs by the neutron bombardment of deuterium. The tritiated water vapors imply health hazard (in the critical organs of the body the water presents a 10 day average biological half-life) and the early detection in nuclear plants of tritium emissions is important because the tritiated water vapors have the same characteristics as of atmospheric water vapors. By detecting tritiated vapors, the monitoring system ensures the following objectives: (a) indicates levels of tritium generally due to heavy ...

Energy Technology Data Exchange (ETDEWEB)

This paper discussed the lithological characteristics of tight gas reservoirs, including the diagenetic characteristics, diagenetic environment and diagenetic sequence. The link between porosity, the sedimentary environment, lithology, diagenesis and basin tectonics was examined in order to determine how tight reservoirs were formed. The study focused on the Changbei gas field located in Yishan Slope of the Ordos Basin in China. The main pay zone reservoir is the Upper Paleozoic Lower Permian Shanxi sandstone which lies at a depth of 2700-2950 m. This low porosity, low permeability tight gas reservoir was deposited in a coal bearing acid environment which controlled the diagenesis sequence. The early carbonate cement was not well developed because the original pore water was acidic with non saturated calcium carbonate. However, compaction has significantly reduced the original pore and pore volume. The ...

Energy Technology Data Exchange (ETDEWEB)

Many mining regions in the United States contain extensive areas of flooded underground mines. The water within these mines represents a significant and widespread opportunity for extracting low-grade, geothermal energy. Based on current energy prices, geothermal heat pump systems using mine water could reduce the annual costs for heating to over 70 percent compared to conventional heating methods (natural gas or heating oil). These same systems could reduce annual cooling costs by up to 50 percent over standard air conditioning in many areas of the country. (Formatted full-text version is released by permission of publisher)

Energy Technology Data Exchange (ETDEWEB)

Visualizations by real-time neutron radiography are demonstrated of various flow patterns of nitrogen gas-water two-phase flow in a stainless-steel tube, water inverted annular flow in a stainless-steel tube, flashing flow in an aluminium nozzle and fluidized bed in aluminium tube and vessels. Photographs every 1/60 s are presented by an image processing method to show the dynamic behaviours of the various flow patterns. It is shown that this visualization method can be applied efficiently to multiphase flow researches and will be applicable to multiphase flows in industrial machines. (author).

British Library Electronic Table of Contents (United Kingdom)

In this study, the effects of channel surface wettability, cross-sectional geometry and orientation on the two-phase flow in parallel gas channels of proton exchange membrane fuel cells (PEMFCs) are investigated. Ex situ experiments were conducted in flow channels with three different surface wettability (hydrophilically coated, uncoated, and hydrophobically coated), three cross-sectional geometries (rectangular, sinusoidal and trapezoidal), and two orientations (vertical and horizontal). Flow pattern map, individual channel flow variation due to maldistribution, pressure drop and flow visualization images were used to analyze the two-phase flow characteristics. It is found that hydrophilically coated gas channels are advantageous over uncoated or slightly hydrophobic channels regarding un...

Energy Technology Data Exchange (ETDEWEB)

Concepts involving combined gas-turbine/steam-turbine power-generation plants, in which the fuel gas for the gas turbine is produced via the gasification of coal, are now extremely advanced. This technology already permits efficiencies of around 50% current development targets view 65% as achievable. In conventional technology, efficiencies are tied to conditions, such as air and cooling-water temperatures, at the particular location. In combined-cycle power plants, the properties of the fuel coal also play an important part. There are, in face, coals which can be more advantageously used in a combined-cycle power plant than in a conventional one. These differences, combined with advantageous concepts for coal-fired combined-cycle power-generating plants, are presented and analyzed. Particular attention is devoted to individual losses occurring at coal conversion, thermodynamic cycles, integration of ...

Energy Technology Data Exchange (ETDEWEB)

A headspace gas chromatographic (GC) method, which can be automated, has been developed for determination of methyl bromide. This method has been applied to wheat, flour, cocoa, and peanuts. Samples to be analyzed are placed in headspace sample vials, water is added, and the vials are sealed with Teflon-lined septa. After an appropriate equilibration time at 32 degrees C, the samples are analyzed within 10 h. A sample of the headspace is withdrawn and analyzed on a gas chromatograph equipped with an electron capture detector (ECD). Methyl bromide levels were quantitated by comparison of peak area with a standard. The standard was generated by adding a known amount of methyl bromide to a portion of the matrix being analyzed and which was known to be methyl bromide free. The detection limit of the method was 0.4 ppb. The coefficient of variation (CV) was 6.5% for wheat, 8.3% for flour, 3.3% for cocoa, and 11.6% for peanuts.

Energy Technology Data Exchange (ETDEWEB)

The coke plant at the Sparrows Point Plant consist of three coke oven batteries and two coal chemical plants. The by-product coke oven gas (COG) consists primarily of hydrogen, methane, carbon monoxide, nitrogen and contaminants consisting of tars, light oils (benzene, toluene, and xylene) hydrogen sulfide, ammonia, water vapor and other hydrocarbons. This raw coke oven gas needs to be cleaned of most of its contaminants before it can be used as a fuel at other operations at the Sparrows Point Plant. In response to environmental concerns, BSC decided to replace much of the existing coke oven gas treatment facilities in the two coal chemical Plants (A and B) with a group of technologies consisting of: Secondary Cooling of the Coke oven Gas; Hydrogen Sulfide Removal; Ammonia Removal; Deacification of Acid Gases Removed; Ammonia Distillation and Destruction; and, Sulfur Recovery. This ...

International Nuclear Information System (INIS)

Accurate prediction of ribbed duct flow and heat transfer is of importance to the gas turbine industry. The present study comprehensively validates the use of large eddy simulations (LES) for predicting flow and heat transfer with measured flowfield data in a stationary duct with 90"o ribs and elucidates on the detailed physics encountered in the developing flow region, the fully developed region, and the 180"o bend region. Among the major flow features predicted with accuracy are flow transition at the entrance of the duct; the distribution of mean and turbulent quantities in the developing, fully developed, and 180"o bend; the development of secondary flows in the duct cross-section and the 180"o bend; and friction and heat transfer augmentation. At the duct inlet, both the computations and experiments show that the peak turbulence intensities reach values as high as 40% in the streamwise and spanwise directions and 32% in the vertical direction, and a comparison ...

Energy Technology Data Exchange (ETDEWEB)

Petropavlovsk-Kamchatky (P-K) city in Kamchatka, Russia is operating hot-water district heating using heavy oil boilers and waste hot water of thermal power plants as heat sources. Feasibility study was made on district heating using natural geothermal hot water and/or geothermal heat pump systems as heat sources of hot water supply for reduction of greenhouse effect gas emission. Among 3 areas including geothermal hot water, use of hot water in K area was impossible because of lower temperature and less spring water. Use of hot water in P and UP areas was impossible as primary hot water because of temperature drop to 64 degrees C during hot water supply toward P-K city. The building heating operation test was carried out using the geothermal heat pump system ...

British Library Electronic Table of Contents (United Kingdom)

A study was conducted to determine the fitting soil moisture for the normal growth of two-year-old W. sinensis (Sims) Sweets by using gas exchange technique. Remarkable threshold values of net photosynthetic rate (Pn), transpiration rate (Tr) and water use efficiency (WUE) were observed in the W. sinensis leaves treated by various soil moisture and photosynthetic available radiation (PAR). The fitting soil moisture for maintaining a high level of Pn and WUE was in range of 15.3%?26.5% of volumetric water content (VWC), of which the optimal VWC was 23.3%. Under the condition of fitting soil moisture, the light saturation point of leaves occurred at above 800?mol?m?2?s?1, whereas under the condition of water deficiency (VWC, 11.9% and 8.2%) or oversaturation (VWC, 26.5%), the light saturatio...

International Nuclear Information System (INIS)

An attempt to develop a simple framework for financial evaluation of renewable energy technologies (RETs) such as photovoltaic (PV) pump, windmill pump, biogas and producer gas-driven dual fuel engine pumps for irrigation water pumping has been made. The unit cost of water and unit cost of useful energy delivered by the RETs have been estimated. The monetary benefits that accrued to the end-user have been quantified in terms of the amount of diesel or electricity saved. Financial figures of merit for the investments made in the RETs have been estimated. The effect of fuel price escalation on these measures of financial performance has also been evaluated along with the estimation of the break-even prices of fuels likely to be substituted by RETs. Results of some exemplifying calculations are presented and briefly discussed.

International Nuclear Information System (INIS)

Marker experiments for studying the mass transport through a palladium silicide layer on a crystalline substrate during thermal oxidation at 700 to 850 deg C have been reported recently. In this work argon gas embedded in amorphous silicon during sputtering was implemented as the inert marker and the oxidation of PdSi was processed above 900 deg C. At this high-temperature oxidation silicon-rich silicide PdSisub(y), with y exceeding 5, may be obtained. This can be anticipated by considering the Pd-Si phase diagram which shows the liquid phase may appear at an annealing temperature above 892 deg C. As a result, a non-stoichiometric and non-uniform silicide layer may develop at the sample surface. Marker analysis showed that both palladium and silicon dissociated at the Pdsub(x)Si/ SiO_2 interface and moved to the substrate with the silicon being the dominant diffuser. The Rutherford backscattering spectra (RBS) showing the oxide film and composition isothermally ...

International Nuclear Information System (INIS)

Local properties and heat transfer have been investigated in a NaK-nitrogen two-phase flow in a vertical tube under transverse magnetic field. An objective two-phase flow regime identification was also carried out systematically, using the probability distribution function of two-phase electromagnetic flowmeter signals. The application of a magnetic field was bound to bring about a drastic change in the void fraction profile, i.e., asymmetric profile perpendicular to the field direction. This effect was more remarkably observed in bubbly flows. The magnetic field was also observed to decrease the number of bubbles, by promoting the agglomeration of small bubbles into larger ones and also break-up of large slugs, and, thus, to shift the flow regime boundaries. It has been also shown that the two-phase Nusselt number increases in bubbly flows, while it decreases in slug flows. This trend however reduces in the presence of a magnetic field.

International Nuclear Information System (INIS)

Brief summaries are given of research carried out in the following areas: absorption spectroscopy of titanium, niobium, and molybdenum in uranium alloys; atomic absorption spectroscopy of selenium in stainless steel, computer program improvements for spectrophotometer control, and detection of beryllium in stack gases; electrolysis for inactivation of bacteria in cooling-tower water; improved solvent analysis by gas chromatography; sequential radionuclide separation for various sample matrices; progress on an electron microprobe analyzer; and miscellaneous projects.

Energy Technology Data Exchange (ETDEWEB)

The conductivity of the membrane is a limiting factor for the efficiency and power density of PEFCs. Because this conductivity is strongly dependent on the membrane hydration, water management is an important aspect of PEFC optimisation. Single cell model experiments were made in order to determine the in-plane hydration of a Nafion{sup R} membrane under fuel cell conditions as function of the gas humidities. (author) 4 fig., 3 refs.

Energy Technology Data Exchange (ETDEWEB)

This book presents the papers given at a conference on two-phase flow. Topics considered at the conference included the thermal hydraulics of a feedwater pipe breakage, pressure losses, measurement of void fraction in a rod bundle, laminar filmwise condensation, natural circulation, flow models, bubble dynamics, cavitation, water hammer, and heat transfer augmentation.

Wastenet

... IN-STORE PROCUREMENT SERVICES - Energy (Electric/Gas) - Telecoms (Call/Lines/Switchboards/Mobiles) - Waste & waste compliance (Cleaning/Collection/Compliance) - Carrier bags (Plastic/Paper) - Stationery (Supplies) - Catering (Consumables/Equipment) - Insurance (Business/Legal/Personal) - Water (Rates/Coolers) - Personnel (Staff Uniforms/Recruitment/Training) - Security (Patrols/Surveillance Equipment) - Instore ...

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Field and laboratory work sponsored by the Gas Research Institute (GRI) and the Department of Energy (DOE) have shown that calcium-carbonate scale formation in waters produced with natural gas and oil can be prevented by injection of phosphonate inhibitor into the formation, even if the formation is sandstone without calcite binding material. Inhibitor squeeze jobs have been carried out on DOE's geopressured-geothermal Gladys MaCall brine-gas well and GRI's co-production wells in the Hitchcock field. Following the inhibitor squeeze on Gladys McCall, the well produced over five million barrels of water at a rate of approximately 30,000 BPD without calcium-carbonate scaling. Before the inhibitor squeeze, the well could not be produced above 15,000 BPD without significant scale formation. In the GRI brine-gas co-production field tests, inhibitor ...

Energy Technology Data Exchange (ETDEWEB)

The phenomenology of wire chamber aging is discussed and fundamentals of proportional counters are presented. Free-radical polymerization and plasma polymerization are discussed. The chemistry of wire aging is reviewed. Similarities between wire chamber plasma (>1 atm dc-discharge) and low-pressure rf-discharge plasmas, which have been more widely studied, are suggested. Construction and use of a system to allow study of the plasma reactions occurring in wire chambers is reported. A proportional tube irradiated by an {sup 55}Fe source is used as a model wire chamber. Condensable species in the proportional tube effluent are concentrated in a cryotrap and analyzed by gas chromatography/mass spectrometry. Several different wire chamber gases (methane, argon/methane, ethane, argon/ethane, propane, argon/isobutane) are tested and their reaction products qualitatively identified. For all gases tested except those containing methane, use of hygroscopic filters to ...

Energy Technology Data Exchange (ETDEWEB)

A sensitive and rapid automated method has been developed for the selective analysis of acid extractable sulfide in environmental samples by combining gas dialysis separation techniques with methylene blue detection procedures. Acid extractable sulfide is separated from the sample matrix by the gas dialysis membrane and subsequently trapped in a dilute sodium hydroxide receiving stream. This stream is reacted with N,N-dimethyl-p-phenylenediamine and ferric chloride to produce methylene blue which is then quantitated colorimetrically at 660 nm. For standards and nonturbid environmental samples, there is good agreement between the results obtained by this procedure and the standard methylene blue method. The effect of interferences on the accurate determination of sulfide by both methods was also examined and it was found that cupric ions significantly interfered with sulfide estimation. To obtain adequate sulfide recoveries in tap ...

Energy Technology Data Exchange (ETDEWEB)

The US Environmental Protection Agency (EPA) conducted a cost-effectiveness (CE) analysis to estimate the incremental cost of complying with the proposed effluent limitation guidelines (ELGs) for the coastal oil and gas industry (EPA 1995a). EPA`s CE analysis calculates the pounds of each pollutant that would be removed if the chosen discharge option is selected. In 1993, EPA issued final ELGs for the offshore oil and gas industry and published an offshore CE analysis. The chemical characteristics of produced water from the offshore region are essentially the same as those of produced water from the coastal region. It was surprising, therefore, that EPA chose a much longer list of pollutants and generally stricter weighting factors for the coastal CE analysis. This report reviews the data, assumptions, and analyses used in EPA`s coastal CE analysis and identifies alternate data, assumptions, and ...

International Nuclear Information System (INIS)

Nitrite was measured in atmospheric liquid phase samples between 1998 and 2005 to investigate the heterogeneous formation of nitrous acid in the lower atmosphere, as well as to assess the quality of water recovered from dew. The samples were collected during ground-based cloud field experiments at different German mountain sites (Brocken, Schmucke, and Hohenpeissenberg) and at a site south of the Bordeaux urban area (France). Concentrations found in Bordeaux dew samples (up to 2800 ?gl-1) are comparable to those found elsewhere in urban fog and dew water and considerably higher than those detected in cloud water or rain. Particulate nitrite (and nitrate) as well as HNO2 (HNO3) data in air masses from a foothill site of Mt. Schmucke, before involved in cloud processing, are also presented. In clouds at Mt. Brocken, both the interstitial HNO2 gas and the aqueous phase nitrite concentration have been ...

International Nuclear Information System (INIS)

The helium-cooled HTGR (High Temperature Gas-cooled Reactor) will take an important position in the global energy strategy. It is expected to supply not only electricity but also high quality thermal energy for various industries and local utilities without exhausting any green house effect gas or acid rain gas. The key R and D issue of the HTGR is economical competitiveness, particularly against light water reactors. Due to the poor heat transfer of the single phase helium, the HTGR's volumetric power density is restricted to tenth of corresponding PWR's value so that increasing the power density by improving heat transfer is strongly desired. The standstill can be broken through by adopting gas-solid suspension medium. Its heat transfer performance is quite excellent. Its heat capacity can be increased drastically without excessive pressurization. Although the thermal radiation is ...

Energy Technology Data Exchange (ETDEWEB)

The potential for detoxification and deodorization of sulfide-laden water (sour water) by microbial treatment was evaluated at a petroleum production site under field conditions. A sulfide-tolerant strain of the chemautotroph and facultative anaerobe, Thiobacillus denitrificans, was introduced into an oil-skimming pit of the Amoco Production Company LACT 10 Unit of the Salt Creek Field, Wyoming. Field-produced water enters this pit from the oil/water separation treatment train at an average flowrate of 5,000 bbl/D (795 m{sup 3}/D) with a potential maximum of 98,000 bbl/D (15,580 m{sup 3}/D). Water conditions at the pit inlet are 4,800 mg/l TDS, 100 mg/l sulfide, pH 7.8, and 107{degrees}F. To this water an aqueous solution of ammonium nitrate and diphosphorous pentoxide was added to provide required nutrients for the bacteria. The first 20% of the pit was aerated ...

Energy Technology Data Exchange (ETDEWEB)

A large temperature differential (10K) thermal storage system in a small (4400 m{sup 2}) 8-storey office building is discussed and the monitoring results are analyzed in comparison with computer simulations. Requirements were a comfortable indoor environment and system cost effectiveness. Out of four potential system concepts, the Large Temperature Differential System was chosen. It comprises a flat-type thermal stratification heat storage tank in the under floor pit of the building as the heat source for a variable flow heat pump chiller. The heat sink is a set of serially connected air handling and fan coil units. The tank`s capacity is sized for one day operation and is made as large as possible to shift the electricity demand to night time. To avoid a large size and high cost, the water temperature differential was enlarged. The role of Tokyo Electric Power Company (TEPCO) was to develop the chiller and its control system. It is concluded ...

Energy Technology Data Exchange (ETDEWEB)

Oxygenated sterol compounds (OSC), when incubated for 1 hr with human erythrocytes in lipoprotein-depleted medium at concentrations of 0.625-5 x 10/sup -5/M, are inserted into the cell membrane and remain there despite subsequent washing of the cells. The insertion results in expansion of the surface area of the red cell ghost membrane, an increase in critical hemolytic volume, and as a consequence, in dimished osmotic fragility of the erythrocytes. This effect is seen with echinocyte-forming as well as with non-echinocyte-forming OSC. Erythrocytes treated with OSC do not differ from control cells with respect to their mean cell volume (MCV) in isotonic solution, water content, ion fluxes, and filterability through polycarbonate filters. The shift of the osmotic fragility curve toward lower NaCl concentrations is proportional to the amount of OSC inserted into the red cell membrane. 7BETA-Hydroxycholesterol, 22-ketocholesterol, and 20 ..cap ...

International Nuclear Information System (INIS)

The classical theory of collisional broadening and shift parameters (?, ?) of an isolated spectral line was used to obtain simple analytical formulas for calculating both ? and ?. These formulas were obtained on the assumption that the short range interaction is effective only in the broadening while the long range is effective in the shift of the spectral line. These parameters ? and ? depend on the limiting phase shifts responsible for broadening ?b and shift ??. It was found that the values of ?b and ?? are not equal to each other as was proposed by Weisskopf ?b=??=1. The maximum and average values of ?b (?bmax, ?bav) and ?? (??max, ??av) were obtained by numerical evaluation, using different inverse power potentials. By introducing these parameters into the approximated formulas for ? and ? using Van der Waals and Lennard-Jones potential, it was found that the results of calculations for (? and ?) ...

UK PubMed Central (United Kingdom)

Proposals that adaptation with left-shifting prisms induces neglect-like symptoms in normal individuals rely on a dissociation between the post-adaptation performance of individuals trained...Full Text Available

Energy Technology Data Exchange (ETDEWEB)

A mathematical model of a mineral melting cupola furnace for stone wool production has been developed for improving cupola operation. The 1-D, first-engineering-principles model includes mass and heat balances for the gas phase, five solid phases, and four liquid phases. The gas and solid/liquid phases flow countercurrently. Seven chemical reactions account for the conversions of coke, iron oxide, limestone, and gaseous species. The heterogeneous reactions of coke conversion are limited by both kinetics and mass transport. Heat transfer between phases is modeled including both convection and radiation. The model predicts gas concentrations; mass flow rates; and temperature profiles of the solid, melt, and gas in the cupola, as well as heat loss to the water-cooled walls. Inputs to the model include the coke, rock, and blast air properties, the blast air amount, and the coke ...

Energy Technology Data Exchange (ETDEWEB)

North Slope of Alaska has huge oil deposits in heavy oil reservoirs such as Ugnu, West Sak and Shrader Bluff etc. The viscosity of the last two reservoir oils vary from {approx}30 cp to {approx}3000 cp and the amount in the range of 10-20 billion barrels. High oil viscosity and low formation strength impose problems to high recovery and well productivity. Water-alternate-gas injection processes can be effective for the lower viscosity end of these deposits in West Sak and Shrader Bluff. Several gas streams are available in the North Slope containing NGL and CO{sub 2} (a greenhouse gas). The goal of this research is to develop tools to find optimum solvent, injection schedule and well-architecture for a WAG process in North Slope shallow sand viscous oil reservoirs. In the last quarter, we have developed streamline generation and convection subroutines for miscible gas injection. The WAG injection ...

British Library Electronic Table of Contents (United Kingdom)

Purpose - The purpose of this paper is to elicit the subtle but progressive shift in organizational/institutional interaction with its rivals within a competitive framework, and thereby discusses and analyses paradigm shifts in competition and competitiveness. The paper argues that interorganizational networks and the recent concept of supply chain management may have induced a change in how competitiveness is viewed at the national, industry, and firm levels of interaction. Design/methodology/approach - The paper conceptualizes extant literature into distinct themes of (organizational and institutional) analysis - micro, macro, and meso - and based on this review the paper seeks to identify emerging logics and shifts within mainstream competitiveness literature over the last decade. Findi...

Energy Technology Data Exchange (ETDEWEB)

Values of frequency splittings in the lithium isotopes have been determined with the aid of laser-induced fluorescene in a supersonic beam, perpendicularly irradiated by a CW ring dye laser. The residual 2s-2p isotope shift has been found to bw 4721.8 +- 2.0 MHz, leading to a specific mass shift for the 2p level of -3610.8 +- 5 MHz.

Energy Technology Data Exchange (ETDEWEB)

Owing to their key function in power production the technology of gas- and steam turbines has a very high importance. Gas turbines in particular have become much more efficient and show higher performance in cogeneration plants. The VDI group on materials engineering puts these issues at the centre of this report whose focus is on measures necessary to increase plant availability: damage analysis, materials optimisation, supervision of construction and repair. The report which looks at applications and practical experience is adressed to operators of gas-, steam-, and water turbine plants, manufacturers of turbines and their components as well as maintenance companies, experts and insurance engineers. (orig.) [German] Aufgrund ihrer Schluesselposition bei der Stromerzeugung kommen den Gas- und Dampfturbinen eine sehr hohe technische Bedeutung zu. Insbesondere die Gasturbine macht in ...

Energy Technology Data Exchange (ETDEWEB)

The Lincoln Public School District, in Lincoln, Nebraska, recently installed vertical-bore geothermal heat pump systems in four, new, elementary schools. Because the district has consistent maintenance records and procedures, it was possible to study repair, service and corrective maintenance requests for 20 schools in the district. Each school studied provides cooling to over 70% of its total floor area and uses one of the following heating and cooling systems: vertical-bore geothermal heat pumps (GHPs), air-cooled chiller with gas-fired hot water boiler (ACUGHWB), water-cooled chiller with gas-fired hot water boiler (WCCYGHWB), or water-cooled chiller with gas-fired steam boiler (WCUGSB). Preventative maintenance and capital renewal activities were not included in the available database. GHP schools reported average total costs at 2.13 ...

International Nuclear Information System (INIS)

LEDF (Large Equipment Dismantling Facility) will be constructed for the purpose of decontaminating the high level #alpha# solid waste generated in oarai engineering center of JNC. And, main processing process of LEDF is incineration and melting system. LEDF will be intended to reduce the secondary waste that occurs along with the operation of the off gas processing equipment of incineration and melting system. It assumed that we are able to eliminate the adsorption tower using silica gel, if the decontamination factor to volatile ruthenium is able to expect in the packed scrubber that is established to remove harmful gas. Thereupon, we carried out this tests that eliminates the adsorption tower and reduces the secondary waste. The decontamination factor (DF) to the volatile ruthenium by the water scrubber is confirmed in the established institution which is in Tokai Works. However, decontamination factor differs and depends ...

Energy Technology Data Exchange (ETDEWEB)

Soil contamination by liquid organic pollutants represents a serious threat to phreatic ground water. These organic liquids get into the ground and migrate through the porous medium until they finally reach the aquifer. After a critical study of the literature, we listed various existing multiple displacements under three-phase conditions of a disconnected polluting phase that may or not spread over water. The aim of this thesis is to model (at pore scale level) and integrate in the pore network model the various flows that occur when three phases (gas, pollutant and air) are present in a porous medium. The porous medium is supposed completely water-wet. The polluting phase may be connected or not, and the spreading coefficient of the pollutant over water may either be positive or negative. The goal of our study is to obtain macroscopic parameters such as relative permeabilities and ...

Energy Technology Data Exchange (ETDEWEB)

Slurry of activated brown coal char in water was used to remove sulphur dioxide (SO{sub 2}) from flue gases using a small slurry bed system with gas chromatograph analysis. Standard activated charcoal and brown coal char was also used in this study to remove SO{sub 2} from an air or nitrogen stream and their efficiency was compared with activated brown coal char. The results showed that the capacity of activated brown coal char to remove sulphur dioxide was much higher than the activated charcoal and brown coal char. Effects of particle size, temperature, and slurry density on the adsorptive capacity of activated brown coal char were also studied. The concepts of sulphuric acid production by continuous regeneration and recycling were also investigated.

British Library Electronic Table of Contents (United Kingdom)

To analyze the effect of containment spray on gas mixing and depressurization, two experiments (ST3_1 and ST3_2) were performed with two interconnected vessels. These experiments were conducted in the frame of the OECD/SETH-2 project using the PANDA facility. The vessels were preconditioned such that a helium-rich layer is formed in the upper section of the first vessel, henceforth referred to as Vessel-1. In the case of the first experiment (ST3_1), the remaining volume of Vessel-1 and the entirety of the second vessel, Vessel-2, were filled with pure steam. For ST3_2, the second experiment presented here, pure steam was replaced with a steam-air mixture instead. Water was injected from the top of Vessel-1 with a spray nozzle projecting downwards. Transient behavior of system pressure, as...

Energy Technology Data Exchange (ETDEWEB)

Measurements of local mass fluxes of liquid, local number fluxes of the drop and local drop size distributions at various locations in the test column were made for wide ranges of liquid flow rates and gas flow rates. An empirical correlation for the volume mean diameter of the drop at the nozzle exit was proposed. Measurements of the rates of absorption of carbon dioxide from carbon dioxide-air mixtures with water sprays (physical absorption) and aqueous sodium hydroxide sprays (chemical absorption) were made for wide range so fluid flow rates, feed gas concentrations, and initial alkali concentrations. The observed dimensionless rates of absorption were compared with the theoretical values by assuming penetration model with second-order irreversible reaction. 11 refs., 7 figs.

Energy Technology Data Exchange (ETDEWEB)

The shifts induced by equimolar mixture of typical lanthanide shift reagent such as 2,2-dimethyl-6,6,7,7,8,8,8-heptafluoro-3,5-octadionato europium with silver trifluoroacetate in /sup 1/H NMR spectra of aromatic hydrocarbons have been used for analytical purposes; the NMR determination of m- and p-xylenes in mixtures has been chosen as an example. The use has been made of the difference between induced shifts of methyl group signals in the /sup 1/H NMR spectra of m- and p-xylenes. The magnitude of induced shifts of methyl groups signal in m-xylene is always larger than that of p-isomer, irrespective of contents of m- and p-xylenes in mixture.

CERN Document Server

Mon R2, at a distance of 830 pc, is the only ultracompact HII region (UC HII) where the photon-dominated region (PDR) between the ionized gas and the molecular cloud can be resolved with Herschel. HIFI observations of the abundant compounds 13CO, C18O, o-H2-18O, HCO+, CS, CH, and NH have been used to derive the physical and chemical conditions in the PDR, in particular the water abundance. The 13CO, C18O, o-H2-18O, HCO+ and CS observations are well described assuming that the emission is coming from a dense (n=5E6 cm-3, N(H2)>1E22 cm-2) layer of molecular gas around the UC HII. Based on our o-H2-18O observations, we estimate an o-H2O abundance of ~2E-8. This is the average ortho-water abundance in the PDR. Additional H2-18O and/or water lines are required to derive the water abundance profile. A lower density envelope (n~1E5 cm-3, N(H2)=2-5E22 cm-2) is ...

International Nuclear Information System (INIS)

This paper describes a series of tests investigating two-phase flow regimes in a transparent model of a PWR hot leg. Test conditions were selected to cover a wide range of gas and liquid superficial velocities (.01 m/s 2 m/s) were also performed for comparison with semi-analytical predictions. Results include average void fractions, flow rates, and visual characterizations of the two-phase flow phenomena. Results show generally good agreement with Taitel and Duckler flow regime map and Zuber-Findlay correlation for average void fraction in vertical pipes. Results also indicate that flow regimes and collapsed liquid level (void fraction) are more strongly dependent on air flow rate (air superficial velocity) than water flow rate (water superficial velocity).

International Nuclear Information System (INIS)

Ppercase(femaxi-iv) is a computer code for the analysis of thermal and mechanical behavior of light water reactor fuel rods during steady-state and transient conditions. The main purpose of ppercase(femaxi-iv) is to calculate the stress and strain distributions in the fuel and cladding due to the pellet-cladding mechanical interaction, and the fission gas release rate during operations, especially power transients. The capability of ppercase(femaxi-iv) was extensively tested with a number of experimental results obtained in some international fuel irradiation programs. This paper provides a general description of the various models involved in ppercase(femaxi-iv) and some results of applications on the experimental data. ((orig.)).

Energy Technology Data Exchange (ETDEWEB)

Excitation of low temperature helium or helium/water plasma and subsequent exposure to air of polyacrylonitrile (PAN) ultrafiltration membranes was used to hydrophilize the surface of these materials. We analyzed the effectiveness of this approach as a function of plasma operating variables including gas phase composition, plasma power, treatment time and system pressure. Following the changes in physical and chemical composition of the PAN surface resulting from these modifications was a major aspect of this work. Techniques such as the captive bubble contact angle method, ellipsometry, ESCA, and FTIR-ATR were all used. In addition, the formation and life-time of peroxides during these processes were determined. At low powers (<25W) and short treatment periods ({<=}30 sec), the main chemical conversion of PAN surfaces was simultaneous hydrophilization and stabilization via PAN cyclization. Relatively small water ...

Energy Technology Data Exchange (ETDEWEB)

The geothermal resources of the Green River basin were investigated. Oil-well bottom-hole temperatures, thermal logs of wells, and heat flow data have been interpreted within a framework of geologic and hydrologic constraints. Basic thermal data, which includes the background thermal gradient and the highest recorded temperature and corresponding depth is tabulated. It was concluded that large areas are underlain by water at temperatures greater than 120/sup 0/F. Although much of this water is too deep to be economically tapped solely for geothermal use, oil and gas wells presently provide access to this significant geothermal resource. Isolated areas with high temperature gradients exist. These areas - many revealed by hot springs - represent geothermal systems which might presently be developed economically. 34 refs., 11 figs., 8 tabs. (ACR)

Science.gov (United States)

A 65-yr-old female developed cough, fever and dyspnoea following repeated exposure to a home ultrasonic humidifier. High-resolution computed tomography showed ground-glass opacity in both lung fields. Arterial blood gas analysis gave an oxygen tension of 8.38 kPa (63 Torr). Pulmonary function testing revealed restrictive ventilatory impairment with a reduction in the diffusing capacity. The diagnosis of extrinsic allergic alveolitis (EAA) was confirmed by radiographic findings, pathological evidence of alveolitis and reproductive development by a provocation test to the humidifier water. The yeast Debaryomyces Hansenii was the only microorganism cultured from the water of the humidifier. The double diffusion precipitating test and lymphocyte proliferative response was positive for an extract of D. Hansenii, providing evidence to incriminate this fungus. This is the first described case of EAA caused by D. Hansenii. ...

Energy Technology Data Exchange (ETDEWEB)

The oil sands industry in Canada was said to be committed to environmentally sustainable economic development, i.e. a development that recognizes the mutual dependence of a healthy environment and a healthy economy. To indicate progress toward this goal, the report pointed out the investment of millions of dollars in environmental research and tens of millions of dollars in plant equipment already made. These infrastructure investments have paid dividends in terms of energy conservation, reduction of greenhouse gas emissions, land reclamation, air quality monitoring, water conservation, and water quality and biodiversity protection. A number of recommendations governing provincial jurisdictions over regulations were made. Particular concern was expressed over fairness, and overlapping of regulations by different levels of government.

International Nuclear Information System (INIS)

This paper reports on steam injection cycle which is similar to supplementary fired combined cycle, but for the utilized steam medium produced by HRSG, its temperature is higher and pressure is lower than in the combined cycle. In comparison with the thermodynamic advantage of the two cycles, a clear understanding of physical concept can be gotten simply by energy balance. The difference of total power output between them is subtraction of enthalpy difference of exhaust steam and feed water of HRSG in steam injection cycle from the rejected heat by water coolant of condenser in combined cycle, when using the identical gas turbine and the same amount of total fuel consumption. In general case, formulas and data are given to indicate this comparison by the ratio of steam mass flow supplied by HRSG of the two cycles. The analysis of Cheng Cycle Series 7 is applied as an example to give the practical result.

International Nuclear Information System (INIS)

Full text: In heavy-water-moderated power reactors, tritium is primarily produced by neutron capture in deuterium nuclei in the moderator and coolant. For CANDU 6 reactors, the estimated steady-state values are #approx# 3 TBq#centre dot#kg"-"1 D_2O in the moderator and #approx# 74 GBq#centre dot#kg"-"1 D_2O in the coolant. Tritium removal is one option available to reactor operators for use in their heavy water and tritium management strategies. The WTRF is designed to remove tritium from tritiated heavy water in each of the four CANDU units at the Wolsung Site, to immobilize the tritium and to store it on site. The detritiation process is based on three steps: the first one (front-end) involves the transfer of tritium from heavy water to deuterium gas; the second one (enrichment) concentrates the tritium in a cryogenic distillation system to produce essentially pure D_2 and T_2 ...

International Nuclear Information System (INIS)

In order to study the two-phase natural circulation and flow termination during a small break loss of coolant accident in LWR, simulation experiments have been performed. Based on the two-phase flow scaling criteria developed under this program, an adiabatic hot leg U-bend simulation loop using nitrogen gas and water and a Freon 113 boiling and condensation loop were built. The nitrogen-water system has been used to isolate key hydrodynamic phenomena from heat transfer problems, whereas the Freon loop has been used to study the effect of phase changes and fluid properties. Various tests were carried out to establish the basic mechanism of the flow termination and reestablishment as well as to obtain essential information on scale effects of parameters such as the loop frictional resistance, thermal center, U-bend curvature and inlet geometry. In addition to the above experimental study, a preliminary modeling study has been ...

Energy Technology Data Exchange (ETDEWEB)

In order to study the two-phase natural circulation and flow termination during a small break loss of coolant accident in LWR, simulation experiments have been performed using two different thermal-hydraulic loops. The main focus of the experiment was the two-phase flow behavior in the hot-leg U-bend typical of BandW LWR systems. The first group of experiments was carried out in the nitrogen gas-water adiabatic simulation loop and the second in the Freon 113 boiling and condensation loop. Both of the loops have been designed as a flow visualization facility and built according to the two-phase flow scaling criteria developed under this program. The nitrogen gas-water system has been used to isolate key hydrodynamic phenomena such as the phase distribution, relative velocity between phases, two-phase flow regimes and flow termination mechanisms, whereas the Freon loop has been used to study the effect of fluid properties, phase changes and ...

Energy Technology Data Exchange (ETDEWEB)

Traditional two-phase flow-regime criteria based on the gas and liquid superficial velocities may not be suitable to the analyses of rapid transient or entrance flows by the two-fluid model. Under these conditions, it is postulated that direct geometrical parameters such as the void fraction are conceptually simpler and therefore more reliable parameters to be used in flow-regime criteria than the traditional parameters. From this point of view, new flow-regime criteria for upward gas-liquid flow in vertical tubes have been developed considering the mechanisms of flow-regime transitions. These new criteria can be compared to existing criteria and experimental data under steady-state and fully developed flow conditions by using relative velocity correlations. The criteria showed reasonable agreements with the existing data for atmospheric air-water flows. Further comparisons with data for steam-water in ...

Energy Technology Data Exchange (ETDEWEB)

The objective of this project was to develop a explosion suppression system capable to confine and extinguish gas explosions of the type produced in sub level caving faces when blasting to the coal pillar. Existing systems, such as triggered barriers, were considered not to be valid because of size, weight, cost, and other operational constraints. The research activities have been focused in the development of a mixed water/air spray system that should be manually activated some second before blasting. Two prototypes have been developed and tested, the first one using nozzle operating at the standard ranges of pressure that are normally available in underground coal mines, and a second one based in high-pressure nozzles. In this case, bottles containing a pressurized air/water mixtures are required. The works carried out included theoretical studies, hydraulic nozzles characterization, and modelling of the explosion ...

Energy Technology Data Exchange (ETDEWEB)

According to an American Petroleum Institute production waste survey reported on by P.G. Wakim in 1987 and 1988, the exploration and production segment of the US oil and gas industry generated more than 360 million barrels (bbl) of drilling wastes, more than 20 billion bbl of produced water, and nearly 12 million bbl of associated wastes in 1985. Current exploration and production activities are believed to be generating comparable quantities of these oil field wastes. Wakim estimates that 28% of drilling wastes, less than 2% of produced water, and 52% of associated wastes are disposed of in off-site commercial facilities. In recent years, interest in disposing of oil field wastes in solution-mined salt caverns has been growing. This report provides information on the availability of commercial disposal companies in oil-and gas-producing states, the treatment and disposal methods they employ, and the ...

Energy Technology Data Exchange (ETDEWEB)

Chemical-looping combustion is an indirect combustion technology with inherent separation of the greenhouse gas CO{sub 2}. The feasibility of using NiO as an oxygen carrier during chemical-looping combustion of coal has been investigated experimentally at 800-960{degree}C in the present work. The experiments were carried out in a fluidized bed, where the steam acted as the gasification-fluidization medium. Coal gasification and the reaction of oxygen carrier with the water gas take place simultaneously in the reactor. The oxygen carrier particles exhibit high reactivity above 900{degree}C, and the dry basis concentration of CO{sub 2} in the exit gas of the reactor is nearly 95%. The flue gas composition as a function of the reactor temperature and cyclic reduction number is discussed. At 800-960{degree}C, the dry basis concentration of CO{sub 2} in the flue gas ...

Energy Technology Data Exchange (ETDEWEB)

There is renewed interest in the development of natural gas vehicles in response to the challenge to reduce urban air pollution and consumption of petroleum. The natural gas/diesel dual fuel engine is one way to apply natural gas to the conventional diesel engine. Dual fuel engines operating on natural gas and diesel emit less nitrogen oxides, and less carbon soot to the air compared to conventional diesel engines. The problem is that at light loads, fuel efficiency is reduced and emissions of hydrocarbons and carbon monoxide are increased. This thesis focused on control methods for emissions of hydrocarbons and carbon monoxide in the dual fuel engine at light loads. This was done by developing a reverse flow catalytic converter to complement dual fuel engine exhaust characteristics. Experimental measurements and numerical simulations of reverse flow catalytic converters were conducted. Reverse flow ...

Energy Technology Data Exchange (ETDEWEB)

X-ray crystal structures of L-3,4-dihydroxy-2-butanone-4-phosphate synthase from Magnaporthe grisea are reported for the E-SO{sub 4}{sup 2-}, E-{sub 4}{sup 2-}-Mg{sup 2+}, E-SO{sub 4}{sup 2-}-Mn{sup 2+}, E-SO{sub 4}{sup 2-}-Mn{sup 2+}-glycerol, and E-SO{sub 4}{sup 2-}-Zn{sup 2+} complexes with resolutions that extend to 1.55, 0.98, 1.60, 1.16, and 1.00 {angstrom}, respectively. Active-site residues of the homodimer are fully defined. The structures were used to model the substrate ribulose 5-phosphate in the active site with the phosphate group anchored at the sulfate site and the placement of the ribulose group guided by the glycerol site. The model includes two Mg{sup 2+} cations that bind to the oxygen substituents of the C2, C3, C4, and phosphate groups of the substrate, the side chains of Glu37 and His153, and water molecules. The position of the metal cofactors and the substrate's phosphate group are further stabilized by an extensive hydrogen-bond ...

Energy Technology Data Exchange (ETDEWEB)

A safety analysis code to design a pressurized water reactor and to obtain the licenses including entire proprietary rights is under development in domestic R and D project. The tasks of KAERI is to develop the constitutive relations including models for defining flow regimes and flow regime related models for inter-phase friction, wall frictions, wall heat transfer, and interphase heat and mass transfer in the two-phase three-field equations. In this paper, the process will be presented for choosing the best flow regime maps which occur in gas-liquid two-phase flow in horizontal and vertical tubes.

Energy Technology Data Exchange (ETDEWEB)

Cesium recovery from the polluted layers in the 1/3 scale hydrogen negative ion source for LHD-NBI system has tested. It was found, that the cesium recovery can be produced by additional discharges as from the cesium layer, aged by tungsten and residual gas, so as from the cesium layers, polluted by an occasional water leak. The highest cesium recovery to NI production was produced by a xenon arc, while glow discharge and arcing in hydrogen were less effective. The mechanism of recovery is the ejection of cesium from the underlying enriched layer by the arc and its transport to the surface. (author)

Science.gov (United States)

In the prevention of atmospheric pollution by sulfur dioxide emissions from acid absorbers in contact process sulfuric acid plants in which the unconverted SO/sub 2/ is accumulated by adsorption in a zeolite adsorbent bed and desorbed back into the acid production system, it is found that ambient moist air, after partial dehydration in an acid scrubber is suitably used both to cool down and hot purge desorb the zeolite beds. In addition the pure water derived from the ambient air is advantageously used in the acid-making system.

Energy Technology Data Exchange (ETDEWEB)

A back-up system is provided for a pumping plant or a pressure reservoir system used to maintain insulating oil under pressure in high voltage submarine power cables which includes a gas driven membrane pump to insure a small outflow of oil at a rupture point in the power cable to prevent water from penetrating the cable. The proper operation of the membrane pump is insured by introducing degasified oil at the drive side of the pump during the stand-by and test modes of operation of the back-up system. 11 drawings.

Energy Technology Data Exchange (ETDEWEB)

The UFIP (French Petroleum Industry Association) studies concerning polluted sites and soils and their rehabilitation are presented: characterization of the admissible maximum fuel or gas oil content in the ground, the issue of time effects, and the risks it may induce for public health; study on the various pollutant impacts on the environment (underground waters, biotope...); approach to the development of a dynamical model describing these phenomena and their influence on man, in order to derive consistent and reasonable decontamination objectives

Energy Technology Data Exchange (ETDEWEB)

The South White Rose oilfield, offshore Newfoundland, owned jointly by Husky Oil (82.5 per cent ) and Petro-Canada (17.5 per cent) is being developed using a floating production storage and offloading (FPSO) system. Some industry stakeholders claim that the oil should be produced using a concrete gravity base system as used in the Hibernia Field. However, Husky Oil officials are confident that the choice of the FPSO is well justified, based on its cost effectiveness and economic viability. Several production facility options have been assessed, taking into account feasibility, deliverability, economic attributes. risk and safety . The assessment results clearly pointed to FPSO as the preferred system based on its commercial and technical flexibility, proven track record in harsh environments, its ability to produce both oil and gas in sequential development, its promise of production at full capacity earlier than a gravity base system, and easier decommissioning ...

Energy Technology Data Exchange (ETDEWEB)

A hydrogen peroxide injection system was designed and installed in the stack of a 5,274 million J/hr industrial pilot plant scale combustion chamber using natural gas as fuel. The concentration of peroxide in the gas stream was precisely controlled by continuous injection using an electromagnetic dosage pump, the liquid 50% peroxide solution was finely dispersed into the gases by a water cooled custom designed delivery system with a spray nozzle at the tip. Residence times between 0.1 and 1.8 seconds and concentrations of H{sub 2}O{sub 2} between 280 ppm and 4,000 ppm were used during the test runs. CEMS for total hydrocarbons, carbon monoxide, nitrogen oxides, as well as an ultrasonic gas flow monitor were used to measure the effect of hydrogen peroxide in reducing the emissions of these pollutants. Destruction removal efficiencies between 25% and 100% were observed for hydrocarbons, and concentrations ...

International Nuclear Information System (INIS)

This paper investigates various usages of natural gas (NG) as an energy source for different hydrogen production technologies. A comparison is made between the different methods of hydrogen production, based on the total amount of natural gas needed to produce a specific quantity of hydrogen, carbon dioxide emissions per mole of hydrogen produced, water requirements per mole of hydrogen produced, and a cost sensitivity analysis that takes into account the fuel cost, carbon dioxide capture cost and a carbon tax. The methods examined are the copper-chlorine (Cu-Cl) thermochemical cycle, steam methane reforming (SMR) and a modified sulfur-iodine (S-I) thermochemical cycle. Also, an integrated Cu-Cl/SMR plant is examined to show the unique advantages of modifying existing SMR plants with new hydrogen production technology. The analysis shows that the thermochemical Cu-Cl cycle out-performs the other conventional methods with ...

International Nuclear Information System (INIS)

To increase further the accuracy of flow regime and considering the non-stationary characteristics of differential pressure fluctuation signals of gas-liquid two-phase flow, the flow regime identification method based on recurrence quantification analysis (RQA) and multi-sensor data fusion techniques is put forward. First of all, the recurrence quantification analysis method is used to extract the nonlinear feature parameters of the differential pressure fluctuation signals of gas-liquid two-phase flow, and data fusion of feature layer is conducted by QRA feature parameters of differential pressure signals of three pressure measure intervals, and composes the fusion feature vectors. The fused characteristic vector are input into the support vector machine for identify flow regime. The identification results for four typical flow regimes of air-water two-phase flow in horizontal pipe has shown that the reliability of the ...

Energy Technology Data Exchange (ETDEWEB)

This report describes the design of a well test to determine two-phase hydraulic properties of a low permeability, low porosity formation. Estimation of gas-related parameters in such formations is difficult using standard pumping tests mainly because of the strong fluctuations in the pressure and flow rate data which are a consequence of gas bubbles evolving in the test interval. Even more important is the fact that the data do not allow distinguishing among alternative conceptual models. The estimated parameters are therefore uncertain, highly correlated, and ambiguous. In this study we examine a test sequence that could be appended to a standard hydraulic testing program. It is shown that performing a series of water and gas injection tests significantly reduces parameter correlations, thus decreasing the estimation error. Moreover, the extended test sequence makes possible the identification of the ...

International Nuclear Information System (INIS)

This work describes the radon in soil gas measurements performed during the last two years in cooperation between the Laboratory of Applied Nuclear Physics of the Federal University of Technology (UTFPR), the Nuclear Technology Development Center (CDTN) and the Institute of Radiation Protection and Dosimetry (IRD) from the Brazilian Nuclear Energy Commission (CNEN). Following previously concluded measurements of radon concentration in dwellings and the measurements of 222Rn activity in drinking water collected at artesian bores of Curitiba urban area, present step of activities has been dedicated to measurements of radon concentration in soil gas. Experimental setup was based on the Professional Radon Monitor (ALPHA GUARD) connected to specially developed for such measurements Soil Gas Probe through the air pump and filter system. After the Probe was inserted, the ground has been tamped down around the ...

Energy Technology Data Exchange (ETDEWEB)

Biomass contains nitrogen that is converted to NOx on combustion. Conversion of biomass into producer gas by thermal gasification offers an opportunity to reduce NOx-emissions by NH3 removal from the producer gas with water. Waste water will have to be treated before it can be drained. Recovered NH3 may have value as base chemical, but usually will have to be disposed off as waste. Recycling within the gasification process is an option to dispose off NH3 waste, provided NH3 is broken down under gasification conditions. We present experimental data on NH3 destruction in a CFB gasifier at temperatures from 780C to 860C, when NH3 is injected into the gasification air. Within that temperature range, the fraction of NH3 that is broken down increases from less than 50% to nearly 100%. Clearly, the presence of O2 at the injection point leads to a much higher rate of NH3 destruction than observed for purely ...

Energy Technology Data Exchange (ETDEWEB)

Improvement in efficiency and profitability of hydrogenation reaction of heavy hydrocarbon resources is the most important matter to be done. In this study, coprocessing of coal and heavy oil vacuum residue was conducted using syngas-water as a hydrogen source. For the investigation of effect of the reaction temperature during the coprocessing of Wandoan coal and Arabian heavy vacuum residue using Fe(CO)5 as a catalyst, the conversion, 66.0% was obtained at 425{degree}C. For the investigation of effect of reaction time, the yield of light fractions further increased during the two stage reaction at 400{degree}C for 60 minutes and at 425{degree}C for 60 minutes. Finally, almost 100% of THF-soluble matter was obtained through the reaction using 2 mmol of Fe(CO)5 catalyst at 400{degree}C for 60 minutes, and hydrogenation of heavy oil was proceeded simultaneously. When comparing coprocessing reactions using three kinds of hydrogen sources, i.e., hydrogen, ...

International Nuclear Information System (INIS)

This book summarizes the research that has been conducted in Canada over the past five years on the issue of climate change impacts on key sectors such as water resources, agriculture, forestry, fisheries, coastal zones, transportation, and human health and well-being. The book refers to the growing evidence that climate change is occurring. The Intergovernmental Panel on Climate Change (IPCC) believes that these changes have already contributed to increases in annual precipitation, cloud cover and extreme temperatures over the last 50 years. It suggests that it in order to develop an effective strategy for adaptation, it is necessary to understand the vulnerability of each sector to climate change in terms of the nature of climate change, the climatic sensitivity of the region being considered, and the capacity to adapt to the changes. Adaptation will require a reduction in greenhouse gas emissions in order to lower the rate of climate change. ...

Energy Technology Data Exchange (ETDEWEB)

Electrical heating of subsea flowlines is an effective way to prevent wax and hydrate information, especially for long transportation distances and in low-temperature deep water. Systems are available for use in conjunction with bundles, pipe-in-pipe, and wet-thermal-insulation systems. These systems provide environmentally friendly fluid-temperature control without chemicals or flaring for pipeline depressurizing. Enhanced production is achieved because no time is lost by unnecessary depressurizing, pigging, heating-medium circulation, or removal of hydrate and wax blockages. The seabed temperature at 100-m and greater water depths may range from 7 to {minus}1.5 C, causing a rapid cooling of the hot well streams being transported in subsea flowlines. Under these supercooling conditions, vulnerable crude oils and multiphase compositions will deposit wax and asphalts; also the gas/water phase may freeze solid with hydrate ...

Energy Technology Data Exchange (ETDEWEB)

Experiments were completed to study intermittent coal-water slurry (CWS) fuel sprays injected from an electronically-controlled accumulator injector system. A new synchronization technique was developed using the light extinction signal as a triggering source for the data taking initiation with a laser diffraction particle analyzing (LDPA) technique. This technique allowed measurement of SMDs near the spray tip where the light extinction was low and the data were free from the multiscattering bias. Coal-water slurry fuel with 50% coal loading in mass containing 5 {mu}m mass median diameter coal particulates was considered. A correlation of the SMD with the injection conditions was determined which should show a satisfactory agreement with the measured SMD data. The spray SMD showed an increase with the distance of the axial measurement location and with the ambient gas density, and showed a decrease with increasing ...

Science.gov (United States)

Clean Water Act You are here: Water Laws & Regulations Policy & Guidance Clean Water Act Water Quality and 401 Certification Water Quality and 401 Certification Water Quality...

International Nuclear Information System (INIS)

The resonance line shift of a series of A-15 structures (V_3Pt, Vsub(0.76)Ptsub(0.24) and Vsub(0.62)Irsub(0.38) is measured as a function of temperature in the superconducting state. A method will be described to separate the contribution of the diamagnetism of the superconductor (Meissner effect) and that of the Knight shift to this line shift. From the temperature dependence of the Knight shift of the V atoms the sum of the s and d contribution to the Knight shift can be determined. In these three compounds the s and d contributions appear to cancel out nearly. Moreover the temperature dependence of kappa_2 can be calculated from the measurements. The values of kappa_2 extrapolated at T=Tsub(c) are about 70 for these samples. From the obtained sum of Ksub(s) and Ksub(d) and the data of the susceptibility or of the specific heat of these samples Ksub(s) and Ksub(d) can be ...

Energy Technology Data Exchange (ETDEWEB)

There is a need to reduce air pollutant emissions in some U.S. urban regions to meet federal and state air quality guidelines. Opportunities exist for reducing pollutant emissions from natural gas appliances in the residential sector. A cost-benefit analysis on various pollutant-reducing strategies is needed to evaluate these opportunities. The effectiveness of these pollutant-reducing strategies (e.g., low-emission burners, energy conservation) can then be ranked among themselves and compared with other pollutant-reducing strategies available for the region. A key step towards conducting a cost-benefit analysis is to collect information on pollutant emissions from existing residential natural gas appliances. An extensive literature search was conducted to collect data on residential natural-gas-appliance pollutant emission factors. The literature primarily describes laboratory tests and may not reflect actual emission ...

Science.gov (United States)

Gas evolution in aluminum electrolytic capacitors constitutes one of their main drawbacks in comparison to other types of capacitors lacking a liquid electrolyte. In this respect, one of the most common causes of failure shown by liquid electrolyte capacitors is electrolyte leakage through the seal or even explosions produced by internal pressure buildup. In order to prevent these hazards, some substances, known as depolarizers, are usually added to the capacitor electrolyte with the purpose of absorbing the hydrogen evolved at the cathode (1, 2). Although the gas evolution problem in electrolytic capacitors has been known for a long time, there is a lack of literature on both direct measurements of the gas evolved and assessments of the amount of depolarizer active for the hydrogen absorption process. Aluminum electrolytic capacitors of 100..mu..F and 40V nominal voltage, miniature type (diam 8 mm, height 18.5 mm), were ...

Science.gov (United States)

Spontaneous emission in photonic crystals with anisotropic three-dimensional dispersion relation is studied. If the upper level is below a characteristic frequency omega(1), or above omega(2), or between omega(1) and omega(2), the radiation is a localized field with a frequency in the band gap, or a propagating field with a frquency in the band, or a diffusion field, respectively. An analytical expression for the Lamb shift is obtained. The Lamb shift for the current case is small compared to that in an ordinary vacuum or in one- or two-dimensional photonic crystals due to lower density of states. PMID:11017227

International Nuclear Information System (INIS)

A cross-flow atmospheric plasma jet with distilled water or analyte solution nebulization has been investigated. The plasma gas flows perpendicularly to the RF powered electrode (11.21 MHz) and a grounded electrode was added for plasma stabilization. The working parameters of the plasma generator can be controlled in order to maximize either the plasma power (75 W) or the voltage on the RF powered electrode (plasma power, 40 W). The plasma gas, pure argon (0.4 l min-1) or a mixture of argon (0.3-0.4 l min-1) and helium (0-0.2 l min-1), was also used for liquid nebulization. Optical emission of the plasma, collected in the normal viewing mode, was used for plasma diagnostics and for evaluating its excitation capabilities. The influence of helium content in the mixed-gas plasma on the plasma characteristics and on the emission axial profiles of the plasma gas constituents and of the ...

UK PubMed Central (United Kingdom)

BackgroundSister species divergence and reproductive isolation commonly results from ecological adaptation. In mimetic Heliconius butterflies, shifts in colour pattern...Full Text Available

International Nuclear Information System (INIS)

(Jan - Feb 1981). United Kingdom Kung, HF Tramposch, K. Blau, M. Buffalo

UK PubMed Central (United Kingdom)

Several studies of facilitated communication have demonstrated that the facilitators were controlling and directing the typing, although they appeared to be unaware of doing so. Such results shift...Full Text Available

Science.gov (United States)

... Biomedical measures were also collected. Four 82nd Airborne Division teams performed high workload operations without shifts. ...

International Nuclear Information System (INIS)

The process of infrared multiple photon dissociation (IRMPD) of molecules is of great fundamental importance and has practical significance, such as isotope separation etc. Unfortunately, a clear insight into the process has been hindered by the bewildering array of important variables affecting MPD. The dissociation probability #gamma#(#phi#) i.e. the yield has been found to be a sensitive function of laser fluence #phi# along with numerous other parameters like laser frequency, gas pressure etc. We have shown that in single frequency IRMPD an accurate quantitative characterization of the dissociation probability can be adequately expressed by a 'power law' model with two fitting parameters namely critical fluence, #phi#c and multi photon order, m. This model was exploited in analysing our MPD results on various systems. However, the small isotope shift encountered in heavy elements and the sticking phenomenon observed in small light molecules ...

Energy Technology Data Exchange (ETDEWEB)

Si nanocrystal floating gate MOS capacitors were formed on p-Si (100) wafers by thermal plasma jet (TPJ) annealing of SiO{sub 2}/SiO{sub x} /SiO{sub 2}/Si(100) stacked structure. The chemical composition of SiO{sub x} layer was controlled by changing the SiH{sub 4}, He, and O{sub 2} gas flow ratio during plasma enhanced chemical vapour deposition. The MOS capacitors showed clear hysteresis in capacitance-voltage (CV) characteristics after TPJ annealing. The hysteresis width shows maximum value when initial composition x =1.7, which shows the maximum photoluminescence (PL) intensity. The maximum hysteresis width of 6.8 V was observed with gate voltage swept between 20 and -20 V in x = 1.7 sample. The result means 7.4 x 10{sup 12} cm{sup -2} carriers are injected to or emitted from Si nanocrystals. The duration of 1 V shift in flatband voltage was {proportional_to}0.1 ms with 20 V pulse, and charged carriers were stably maintained for ...

Energy Technology Data Exchange (ETDEWEB)

Field studies were conducted May 28-June 1, 1979, to determine the chemical composition and physical behavior of discharges from an offshore gas drilling rig in the central basin of Lake Erie. The drilling operation was observed for four days, from rig jackup to the circulation of mud through the borehole after drilling had been completed. Resuspension studies using nephelometry, supplemented with chemical analyses, indicated little resuspension of lake bottom materials or release of metals to the water column during rig jack-up. Portions of the turbidity plumes generated during drilling were buoyant. Three surface turbidity plumes were mapped with nephelometry to a point at which particulate concentrations reached background levels in the Lake. Detectable plumes were approx. 400 to 1500 m in length and had maximum widths < 230 m. A chemical survey conducted in the plume during early gas shows indicated that discharged ...

Energy Technology Data Exchange (ETDEWEB)

Atmospheric impact of peatlands is a sum of their gas fluxes. In contrast to carbon dioxide, peatlands are net sources for methane (CH{sub 4}). Methane is an end product in the anaerobic decomposition processes and it has greater capacity to absorb infrared radiation than carbon dioxide. Most of the data on the CH{sub 4} release from northern peatlands is from North America. The total amount of methane released from wetlands is calculated to be 110 Tg yr{sup -1} of which 34 percent (38 Tg yr{sup -1}) is estimated to be emitted from the northern peatlands. Peat with high content of nitrogen is a potential source for gaseous nitrogen oxides, i.e. nitrous oxide (N{sub 2}O) and nitric oxide (NO). However, the importance of peatlands in producing these trace gases is poorly known. Nitrous oxide and nitric oxide are important components in the atmospheric chemistry and N{sub 2}O also is an effective greenhouse gas. Land-use activities and ...

Energy Technology Data Exchange (ETDEWEB)

The invention relates to a method for purifying a gas mixture containing at least one undesirable gas compound utilizing certain sulfonamide or sulfamide solvents.

International Nuclear Information System (INIS)

Mitsubishi is now developing a next-generation Pressurized Water Reactor (PWR) which has the innovative feature of hybrid safety systems (optimum combination of passive safety system and active safety system) and passive core cooling by horizontal steam generators during Loss of Coolant Accident (LOCA). In order to confirm the capability of this passive core cooling system during LOCAs, the thermal-hydraulic tests of horizontal steam generator and the integral thermal-hydraulic tests simulating the LOCAs were performed. The thermal-hydraulic tests of horizontal steam generator consist of a single tube test and a multi-tubes test. On the basis of these test results, the heat transfer characteristics of steam-water two-phase flow with noncondensable gas along a long horizontal tube is understood and the heat transfer correlation including the effect of noncondensable gas is presented. The integral ...

DEFF Research Database (Denmark)

Previous investigations have shown promising results in using the directional cross-correlation method to estimate velocity vectors. The velocity vector estimate provides information on both velocity direction and magnitude. The direction is estimated by beamforming signals along directions in the range $[0^{\\circ}; 180^{\\circ}[$ and identifying the direction that produces the largest correlation across emissions. An estimate of the velocity magnitude is obtained from the spatial shift between signals beamformed along the estimated direction. This paper expands these investigations to include estimations of the vector velocities of a larger region by combining the estimations along several scan lines. In combination with a B-mode image, the vector velocities are displayed as an image of the investigated region with a color indicating the magnitude, and arrows showing the direction of the flow. Using the RASMUS experimental ultrasound scanner, measurements have ...

Energy Technology Data Exchange (ETDEWEB)

A technique involving shifting of core fuel loadings was investigated as a method for reducing the neutron flux at points of high damage accumulation in the pressure vessel wall of a light water reactor. Calculations were run for six types of commercial generic PWR. Information is provided on the progress being made to develop and apply the Solid State Track Recorder (SSTR) method for in-situ in- and ex-vessel measurements of neutron exposure parameter values, such as fluence (E > 1.0 MeV) and dpa in iron. A new technique of quantitative track counting, the Buffon needle method, is advanced. It is based on random sampling of the SSTR surface. A desensitized etching technique was developed that resulted in an excellent differential energy response for alpha particles in the 3- to 14-MeV energy range. The optical efficiency of Muscovite mica for manual fission track counting is being redetermined to form a data base for comparison with ...

International Nuclear Information System (INIS)

A quantitative comparison of tissue distribution and excretion of an orally administered sublethal dose of [3H]diacetoxyscirpenol (anguidine) was made in rats and mice 90 min, 24 hr, and 7 days after treatment. Total recoveries of 95-100% were obtained. Approximately 90% of the dose was excreted in urine and feces during the first 24 hr with a feces:urine ratio of about 1:4.5 in both species. Carcass and tissue radioactivity dropped rapidly during the first 24 hr but remained relatively constant at low, but detectable, levels over the course of the experiment. Few substantive interspecies differences were noted in tissue distribution. At 90 min the highest percentage of dose was in tissues involved in sequestering diacetoxyscirpenol because of high body water/lipid content or the absorption, metabolism, or excretion of the toxin. The rank order of these tissues was generally stable over the course of the experiment. When data were expressed as specific ...

Energy Technology Data Exchange (ETDEWEB)

The basic feature in the functional ecology of any mire ecosystem is retardation of the effective decay of organic material resulting in a conspicuous accumulation of plant debris as peat overtime. The carbon accumulation process is slow, and climatic change may have an impact on the carbon cycle of peatlands, therefore, it has been of interest to study the rate of carbon accumulation by geological methods from dated peat strata. The approach is hampered by several facts. First, the mires vary enormously as to their vegetation and hydrology and hence their production and decay properties. It follows that a great number of study sites are needed. Second, the peat in mires expands both vertically and laterally, and this requires a spatial reconstruction of carbon accumulation within a mire basin. Third, simple geological methods cannot account for the actual rate of carbon accumulation in peat, and finally, an additional carbon sink in the mire ecosystems can be the mineral subsoil ...

International Nuclear Information System (INIS)

Phenomenological accountancy of quanta-electrodynamic corrections by means of introduction into multielectron theory of short-term potential, the parameters whereof are calibrated in such a way that provides for correct reproduction of the Lamb shift of the 1s-orbital energy for a correspondingly selected effective charge is developed by example of d-line of Na-like multicharged ions.

Energy Technology Data Exchange (ETDEWEB)

The inevitability of sustainable economic development and its linkage to a gradual shift to renewable energy sources, especially solar energy, was discussed. Means to measure sustainability of technology were described, and policy instruments (essentially research, development and demonstration, and punitive taxes on conventional energy carriers) to accelerate the shift to renewable energy sources were outlined.

Science.gov (United States)

As a result of the large limestone deposits available in Poland, the low cost of reagent acquisition for the largescale technological use and relatively well-documented processes of flue gas desulfurization (FGD) technologies based on limestone sorbent slurry, wet scrubbing desulfurization is a method of choice in Poland for flue gas treatment in energy production facilities, including power plants and industrial systems. The efficiency of FGD using the above method depends on several technological and kinetic parameters, particularly on the pH value of the sorbent (i.e., ground limestone suspended in water). Consequently, many studies in Poland and abroad address the impact of various parameters on the pH value of the sorbent suspension, such as the average diameter of sorbent particles (related to the limestone pulverization degree), sorbent quality (in terms of pure calcium carbonate [CaCO3] content of the sorbent ...

Energy Technology Data Exchange (ETDEWEB)

The SGTR project has been carried out within the fifth EURATOM Framework Programme (Contract No FIKS-CT-1999-0007). Its main objective was to provide an experimental database and to develop and/or verify models to support definition of accident management measures in the hypothetical case of a Steam Generator tube Rupture (SGTR) sequence. The project addressed both vertical and horizontal steam generator designs. This report summarises the main results obtained in the intermediate scale experimentation that addressed Western type steam generators. The specific goal of this test programme was to investigate aerosol retention in the break stage of the secondary side of a water-empty steam generator. The test matrix consisted of 12 tests that explored the influence of variables such as break type and orientation and inlet gas flow rate. This work was performed in the PECA facility of the Laboratory for Analysis of Safety Systems (LASS). Aerosol ...

Energy Technology Data Exchange (ETDEWEB)

The release of {sup 14}C as {sup 14}CO{sub 2} from partly failed spent fuel containers has been analyzed by the flow of gases into and out of the containers. This flow of gases is driven by pressure differences, which are in turn caused by heating by the spent fuel. In this analysis, the timing and size of holes in the containers are assumed to be given. A better means of predicting the time distribution and sizes of penetrations in nuclear waste containers is needed. For the purposes of far-field transport calculations, we have adopted release rates that are shown to be bonding for the large range of hole sizes studied. The transport of released {sup 14}CO{sub 2} has been analyzed by transport in equivalent porous medium. The peak {sup 14}CO{sub 2} concentration in pore gas at 350 m above the repository does not depend on the time of hole occurrence, although the time of penetration obviously affects the arrival and duration of exposure to {sup 14}C. Nor does ...

CERN Document Server

The origin of life and the origin of the universe represent two of the most important problems of science. Both are resolved by hydro-gravitational dynamics (HGD) cosmology (Gibson 1996, Schild 1996, Gibson 2009ab), which predicts frozen primordial hydrogen-helium gas planets in clumps as the dark matter of galaxies. Merging Earth-mass planets formed stars, moons and comets to incubate and cosmically seed the first life. Cometary panspermia (Hoyle and Wickramasinghe 1981, 1982; Wickramasinghe et al. 2009) occurs naturally by HGD mechanisms. Comets and moons are fragments from mergers of stardust covered frozen gas planets in their step-wise growth to star mass. Supernovae from stellar over-accretion of planets produce stardust (C, N, O, P etc.) chemical fertilizer. Planets collect this infected radioactive dust gravitationally, to provide liquid water domains in contact with life nutrients seeded with life prototypes. The ...

Science.gov (United States)

The largest solar heating and cooling system undertaken to date is now operating at the George A. Towns Elementary School in Atlanta, Georgia. It is expected to provide more than 60 percent of the building's heating and cooling requirements, using commercially available components and techniques. The Towns project is a United States Energy Research and Development Administration-sponsored experiment. The principal components of the solar heating and cooling system designed for the school--the solar collector array, the existing gas-fired boiler, the absorption chiller, and hot and cold water underground tanks to provide thermal storage--are described. To derive maximum benefit from the experiment, the system is fully instrumented for accurate measurement of performance. Environmental data, including insolation and ambient temperture, humidity, and wind conditions will be recorded. The inlet temperatures, outlet temperatures, and the ...