Process for reducing the water content of coal containing bound water
Energy Technology Data Exchange (ETDEWEB)
An improved process is disclosed for reducing the water content of coal containing bound water by releasing at least a portion of the bound water by maintaining the coal at a temperature from about 220/sup 0/ to about 500/sup 0/ F. in the presence of water at a pressure sufficient to maintain at least portion of the water in a liquid phase for a time sufficient to release at least a portion of the bound water wherein the improvement comprises contacting the coal during such treatment with an active material selected from the group consisting of carboxylic organic acids containing up to about 6 carbon atoms, phenol, phenolic acids and inorganic acids.
1983-08-23
Activation of aluminium metal to evolve hydrogen from water
Energy Technology Data Exchange (ETDEWEB)
The method of aluminium metal activation by liquid eutectics Ga-In (70:30) and Ga-In-Sn-Zn (60:25:10:5) is developed. Subsequent dispersion of the obtained specimens up to a particle size of >0.5mm leads to the drastic interaction of aluminium powder and water with evolving hydrogen. In the present work the oxidation rate of activated aluminium and water is investigated depending on eutectic composition, reaction temperature, and powder particle size. The mechanism of the main eutectic's components influence on the reacting ability of aluminium is discussed. (author)
2008-06-15
On the calculation of the electrolyte aqueous solution freezing temperature
International Nuclear Information System (INIS)
Analytical expression of the dependence of freezing temperature of electrolyte (CdCl_2, CdSO_4, BeSO_4) aqueous solutions on their composition was found. Three different methods were suggested were suggested for calculation of water activity in multicomponent solution. It was established that sublinear extrapolation of freezing temperature of salt aqueous solutions was possible not up to -5 deg C, but up to -15 deg C, independently of their composition. 6 refs.; 2 figs.
Formulation and make-up of simulate dilute water, low ionic content aqueous solution
Energy Technology Data Exchange (ETDEWEB)
This procedure describes the formulation and make-up of Simulated Dilute Water (SOW), a low-ionic-content water to be used for Activity E-20-50, Long-Term Corrosion Studies. This water has an ionic content which is nominally a factor of ten higher than that of representative waters at or near Yucca Mountain. Representative waters were chosen as J-13 well water [Harrar, 1990] and perched water at Yucca Mountain [Glassley, 1996]. J-13 well water is obtained from ground water that is in contact with the Topopah Spring tuff, which is the repository horizon rock. The perched water is located in the Topopah Spring tuff, but below the repository horizon and above the water table. A nominal times ten higher ionic content was chosen to simulate ...
1997-04-04
Stability against temperature variations at the ALS
Energy Technology Data Exchange (ETDEWEB)
We have studied the effects of temperature fluctuations on the Advanced Light Source (ALS). By modeling the storage ring support structure, we find that fluctuations of {plus minus}2 to 3deg C in the tunnel will cause photon beam motion of the order of the beam size. Temperature stabilization at this level will allow the residual motion of the photon beams to be reduced by a second level of active feedback, operating on signals from photon beam position monitors. Air temperature in the experimental area and the temperature of cooling water serving the beamlines should be constant to {plus minus}1deg C. This will provide a suitable environment for experiments. (orig.).
1990-05-20
The use of activated brown coal char slurry for the removal of sulphur dioxide from flue gas
Energy Technology Data Exchange (ETDEWEB)
Slurry of activated brown coal char in water was used to remove sulphur dioxide (SO{sub 2}) from flue gases using a small slurry bed system with gas chromatograph analysis. Standard activated charcoal and brown coal char was also used in this study to remove SO{sub 2} from an air or nitrogen stream and their efficiency was compared with activated brown coal char. The results showed that the capacity of activated brown coal char to remove sulphur dioxide was much higher than the activated charcoal and brown coal char. Effects of particle size, temperature, and slurry density on the adsorptive capacity of activated brown coal char were also studied. The concepts of sulphuric acid production by continuous regeneration and recycling were also investigated.
1993-12-31
Safety considerations of active process water system shutdown for TAPP - 3 and 4
International Nuclear Information System (INIS)
Active Process Water (APW) System, provided as unitized closed loop system in Tarapur Atomic Power Project Units-3 and 4, serves to remove heat from various heat exchangers. One of the important loads served by APW system is shutdown cooling heat exchangers and if APW shutdown is taken then reactor cannot be maintained in cold shutdown condition. It is estimated that after 7 days of reactor shutdown, if about 20% of the normal cooling flow to shutdown cooling heat exchangers is provided then along with keeping PHT in cold shutdown state, reactor components, moderator, end shield water, calandria vault water and calandria vault concrete temperature can be maintained within technical specification limits for extended duration. (author)
2005-12-01
Energy Technology Data Exchange (ETDEWEB)
Pitting behavior of alloy 800 was investigated as a function of temperature and prefilming in high-temperature water. The behavior was characterized in terms of pitting potential (U{sub p}) and pit density (n{sub p}). U{sub p} decreased with increasing temperature and chloride activity. Prefilming of test coupons over a period between 100 h and 5,000 h in ammoniated water at 300 C had no apparent influence on U{sub p} at room temperature, 180 C, and 300 C. However, the number of pits in prefilmed coupons was much higher than in coupons covered with an air passive layer. The effect of prefilming on pit nucleation was investigated in detail with regard to a model and test methods developed by Bianchi, et al. Density of pits in prefilmed coupons was at least 1 order of magnitude higher than in air passive coupons. Maximum pit density was ...
1997-02-01
Energy Technology Data Exchange (ETDEWEB)
The pitting behavior of Alloy 800 was investigated as a function of temperature and prefilming in high temperature water. The pitting behavior was characterized in terms of the pitting potential and the pit density. The pitting potential decreases with increasing temperature and chloride activity. Prefilming of test coupons over a time period between 100 and 5,000 hours in ammoniated water at 300 C has no apparent influence on the pitting potential at room temperature, 180 C and 300 C. However, the number of pits in prefilmed coupons is much higher than in coupons covered with an air passive layer. The effect of prefilming on pit nucleation was investigated in more detail with regard to a model and test methods developed by Bianchi and co-workers. Density of pits in prefilmed coupons is at least one order of magnitude higher than in air ...
1995-12-31
Energy Technology Data Exchange (ETDEWEB)
This final report for the Swiss Federal Office of Energy looks at the possibilities for improved waste water utilization in the Lavey-les-Bains thermal spa, Switzerland. According to the regulations in force, the temperature of the waste water rejected into the Rhone river shall not exceed 30 {sup o}C, what is currently not the case. Also the operational cost shall be reduced and the waste water quality improved. The installations are presented. From the two geothermal wells, mineral water comes out at an average flow rate of 940 l/min and a temperature of 63 {sup o}C. Actual waste water data are reported. The measured thermal water consumption data, including seasonal variations, are analysed by computerized simulation and measures to reduce the consumed volume by the optimization of internal procedures are evaluated. ...
2004-07-01
Waste heat utilization in the thermal spa of Lavey-les-Bains
International Nuclear Information System (INIS)
This final report for the Swiss Federal Office of Energy looks at the possibilities for improved waste water utilization in the Lavey-les-Bains thermal spa, Switzerland. According to the regulations in force, the temperature of the waste water rejected into the Rhone river shall not exceed 30 "oC, what is currently not the case. Also the operational cost shall be reduced and the waste water quality improved. The installations are presented. From the two geothermal wells, mineral water comes out at an average flow rate of 940 l/min and a temperature of 63 "oC. Actual waste water data are reported. The measured thermal water consumption data, including seasonal variations, are analysed by computerized simulation and measures to reduce the consumed volume by the optimization of internal procedures are evaluated. Measures to ...
Sucrose phosphate synthase activity in rice grown at elevated CO sub 2 and temperature
Energy Technology Data Exchange (ETDEWEB)
Rice (Oryza sativa L.) was grown at 330 and 660 {mu}L CO{sub 2} L{sup {minus}1} and at 40/33/37, 34/27/31, and 28/21/25{degree}C day/night/paddy water temperatures respectively. Sucrose phosphate synthase (SPS) activity was measured at saturating substrate concentrations at 59 days after planting. SPS activity increased 2 and 3 fold with increasing CO{sub 2} at 28 and 34{degree}C air temperatures respectively. At 40{degree}C SPS activity decreased by 37% at elevated CO{sub 2} and most plants failed to reach maturity. Similar responses were found in leaf samples taken in the dark. These results indicate that SPS, an enzyme involved in the regulation of C partitioning in leaves, increases in activity at elevated CO{sub 2}. This is in contrast to previous results with soybean. The changes in SPS activity will also be ...
1990-05-01
Isotope exchange reaction between tritiated water and hydrogen on SiC
Energy Technology Data Exchange (ETDEWEB)
SiC has been considered as a primary candidate material for a first wall component in future fusion reactor because it has been claimed that SiC has excellent high-temperature properties, good chemical stability and low activation. However, the behavior of tritium on SiC has not been discussed yet. In this study, tritium trapping capacity on the surface of SiC was experimentally obtained at the temperature range of 25-800 deg. C in consideration of tritium trapping to the experimental system. The capacity, which was independent of the water vapor pressure in the gas phase and the temperature, was determined as about 10{sup 6} Bq/cm{sup 2}. The isotope exchange reaction rate between tritiated water in a gas phase and hydrogen on the surface was quantified at the temperature of 25, 500 and 700 deg. C in consideration of the behavior of tritium ...
2003-11-15
Isotope exchange reaction between tritiated water and hydrogen on SiC
International Nuclear Information System (INIS)
SiC has been considered as a primary candidate material for a first wall component in future fusion reactor because it has been claimed that SiC has excellent high-temperature properties, good chemical stability and low activation. However, the behavior of tritium on SiC has not been discussed yet. In this study, tritium trapping capacity on the surface of SiC was experimentally obtained at the temperature range of 25-800 deg. C in consideration of tritium trapping to the experimental system. The capacity, which was independent of the water vapor pressure in the gas phase and the temperature, was determined as about 10"6 Bq/cm"2. The isotope exchange reaction rate between tritiated water in a gas phase and hydrogen on the surface was quantified at the temperature of 25, 500 and 700 deg. C in consideration of the behavior of tritium trapping ...
2003-11-15
Alkylaldehyde-bisulfite adducts as cleavable surfactants
British Library Electronic Table of Contents (United Kingdom)
Alkylaldehyde-bisulfite adducts with octyl, decyl, and dodecyl groups (CnS: n=8,10,12) were synthesized and the surface-active properties of the water-soluble compounds were compared. Exchange of the counter anions of C10S and C12S from sodium to tetramethylammonium solubilized them in water. The latter ammonium salt (C12S-QA) had surface activities as good as a classical surfactant, sodium dodecylsulfate, and dissociated promptly in weakly basic solution at room temperature to be a non-surfactant. It was also found that C12S-QA solubilized a hydrophobic substrate (solid), N,N-dimethyl-3-nitroaniline, in water and then separated it as a precipitate after alkali treatment.
2007-01-01
International Nuclear Information System (INIS)
The Gross Decontamination Experiment was conducted on various levels and surfaces of the TMI-2 Reactor Building during February and March 1982 and was designed to investigate the effectiveness of various surface decontamination techniques. The polar crane, D-rings, missile shields, refueling canal, fueling bridge, major equipment, floors and some walls were flushed with low pressure water. Water lances were directed manually and applied water at temperatures between ambient and 60"0C at a flow rate of about 95 liters per minute. In addition, floor surfaces on the 305-ft elevation and floor surfaces and major equipment on the 347-ft elevation were sprayed with high pressure water (floors in the Reactor Building are designated by their elevations above sea level). The water pressure in this case varied between 13.8 and 41.4 mPa and water ...
1984-07-15
Laser-Cooling of Liquid Water by the Ar-Xe Laser Radiation
An effect of laser-cooling of water was observed for the first time with a temperature decrease dT = -2.2 K after irradiation of liquid water surface by a powerful Ar-Xe pulse laser with a pulse energy of about 1 J and wavelength L = 1.73, 2.63 and 2.65 um. The discovered effect can apparently be ascribed to the optical excitation of vibrational states of H2O molecules followed by an endothermic consolidation of chemically active excited molecules into a quasi-stable cluster-like structure. The measured time dependences of the cooling effect show that a typical life time of the new state of water amounts to hours. It has also been shown that the life time of the excited vibrational molecular states due to a radiation trapping effect can be estimated to at least hundreds of seconds.
2010-01-01
3D model for a secondary facultative pond
British Library Electronic Table of Contents (United Kingdom)
This paper describes a comprehensive model of wastewater treatment in secondary facultative ponds, which combines 3D hydrodynamics with a mechanistic water quality model. The hydrodynamics are based on the Navier-Stokes equation for incompressible fluids under shallow water and Boussinesq assumptions capturing the flow dynamics along length, breadth and depth of the pond. The water quality sub model is based on the Activated Sludge Model (ASM) concept, describing COD and nutrient removal as function of bacterial growth following Monod kinetics, except for Escherichia coli removal, which was modelled as first order decay. The model was implemented in the Delft3D software and was used to evaluate the effect of wind and the addition of baffles on the water flow pattern, temperature profiles i...
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
Composting is once again gaining interest among ecological engineers in view of greener industrial and residential activities. Uniform composting is needed to ensure decomposition and to keep the whole system at the same composting stage. A homogeneous temperature must be maintained throughout the media. A bioreactor design consisting of a heater core made of copper tubing was designed and tested. Two four-inch holes were made at the top and bottom of the barrel to allow air to flow through the system and promote aerobic composting. Once composting began and temperature increased, the water began to flow through the copper piping and the core heat was distributed throughout the medium. Three thermocouples were inserted at different heights on a 200 litre plastic barrel fitted with the aforementioned apparatus. Temperature variations were found to be considerably lower when the ...
2010-07-01
Effects of microwaves on the colony-forming capacity of haemopoietic stem cells in mice
Energy Technology Data Exchange (ETDEWEB)
A suspension of bone marrow cells from femurs of female (CBA . C57B1)F1 mice was exposed to 2450 MHz CW microwaves in a specially designed waveguide exposure system. The temperature of the suspension rose, during exposure to microwaves, from 20/sup 0/C to 45/sup 0/C, and at an interval within 20/sup 0/C to 45/sup 0/C the number of haemopoietic stem cells (CFUs) was determined by the spleen exocolony method. The time of exposure of bone marrow cells to each temperature studied was 20 s. Control suspensions of bone marrow cells were exposed to a water bath temperature. There were no significant effects of the CFUs with the water bath temperature, while after exposure to microwaves the number of spleen colonies was elevated with a nadir at the temperature of 37/sup 0/C. With a microwave-induced increase of the temperature ...
1987-01-01
Measurements of water vapor adsorption on the Geysers rocks
Energy Technology Data Exchange (ETDEWEB)
The ORNL high temperature isopiestic apparatus was adapted for adsorption measurements. The quantity of water retained by rock samples taken from three different wells of The Geysers was measured at 150 °C and at 200 °C as a function of pressure in the range 0.00 ≤ p/p0 ≤ 0.98, where p0 is the saturated water vapor pressure. The rocks were crushed and sieved into three fractions of different grain sizes (with different specific surface areas). Both adsorption (increasing pressure) and desorption (decreasing pressure) runs were made in order to investigate the nature and extent of the hysteresis. Additionally, BET surface area analyses were performed by Porous Materials Inc. on the same rock samples using nitrogen or krypton adsorption measurements at 77 K. Specific surface areas and pore volumes were determined. These parameters are important in ...
1996-01-24
Radon in unconventional natural gas from Gulf Coast geopressured-geothermal reservoirs
International Nuclear Information System (INIS)
Radon-222 has been measured in natural gas produced from experimental geopressured-geothermal test wells. Comparison with published data suggests that while radon activity of this unconventional natural gas resource is higher than conventional gas produced in the gulf coast, it is within the range found for conventional gas produced throughout the US. A method of predicting the likely radon activity of this unconventional gas is described on the basis of the data presented, methane solubility, and known or assumed reservoir conditions of temperature, fluid pressure, and formation water salinity.
Heat-transfer analysis of the plum brook reactor - NASA Technical ...
average bulk water temper ature rise, OF bulk water temperature at elevation z, OF bulk water temperature in channels 0 and 1, O F film temperature, OF ...
International Nuclear Information System (INIS)
An efficient adsorption process is developed for the decontamination of trivalent chromium from tannery effluents. A low cost activated carbon (ATFAC) was prepared from coconut shell fibers (an agricultural waste), characterized and utilized for Cr(III) removal from water/wastewater. A commercially available activated carbon fabric cloth (ACF) was also studied for comparative evaluation. All the equilibrium and kinetic studies were conducted at different temperatures, particle size, pHs, and adsorbent doses in batch mode. The Langmuir and Freundlich isotherm models were applied. The Langmuir model best fit the equilibrium isotherm data. The maximum adsorption capacities of ATFAC and ACF at 25 deg. C are 12.2 and 39.56 mg/g, respectively. Cr(III) adsorption increased with an increase in temperature (10 deg. C: ATFAC-10.97 mg/g, ACF-36.05 mg/g; 40 deg. C: ATFAC-16.10 mg/g, ACF-40.29 ...
2006-07-31
water and of the ethylene glycol-water solutions are shown as functions of temperature in figures 4 and 5, respectively. (data from reference 4). ...
Energy Technology Data Exchange (ETDEWEB)
Two perfluorosulfonic acid membranes, Nafion{sup R} 105 and Nafion{sup R} 115 with the same thickness but different equivalent weights (EW = 1000 g/eq. resp. 1100 g/eq.) were characterised by conductivity measurements at different water vapour activities in the temperature range of 25-70{sup o}C. The results demonstrate that a lower membrane equivalent weight opens the possibility to obtain the needed proton conductivity at lower water vapour activity. This is especially important for those fuel cell applications, in which the cell is operated without external humidification of the fuel gases. (author) 5 figs., 5 refs.
1999-08-01
Esterification process to synthesize isopropyl chloroacetate catalyzed by lanthanum dodecyl sulfate
International Nuclear Information System (INIS)
Isopropyl chloroacetate has been synthesized by esterification of chloroacetic acid and isopropanol, using lanthanum dodecyl sulfate (LDDS) as the catalyst. Various factors that affected the esterification have been investigated, such as reaction time, different water-carrying agent and the amount of catalyst. Under the condition of 1.2/1 molar ratio of isopropanol to chloroacetic acid, 1.0% catalyst (molar percent of chloroacetic acid), 2.5 h reaction time, 5 mL cyclohexane as water-carrying agent and reflux temperature, the esterification conversion of isopropyl chloroacetate reaches 98.3%. The catalytic activity of LDDS is almost equal to that of a Bronsted acid. LDDS, as one kind of water-tolerant Lewis acid, is an excellent catalyst compared to the traditional Lewis acid. (author)
Energy Technology Data Exchange (ETDEWEB)
Extra-fine powdered activated charcoal has been used as stationary phase (coating layer) in solid-phase microextraction (SPME). The efficiency and reliability of the prepared device have been investigated for the extraction of some volatile organic compounds such as benzene, toluene, ethylbenzene and xylene isomers (BTEX) from the headspace of water samples. Monitoring of the extracted compounds and further quantitative analysis of the real samples have been performed by capillary GC-FID. Effects of several factors such as temperature, addition of salt, and stirring speed on extraction efficiency and exposure time have been studied. Under optimum conditions, extraction recoveries for these compounds from 50 mL water were >95%. The calibration graphs were linear in the range 5 to 10{sup 4} pg mL{sup -1} and the detection limit for each BTEX compound was 1.5-2 pg mL{sup -1}. The results obtained by use ...
1997-12-31
British Library Electronic Table of Contents (United Kingdom)
The dynamics of planktonic cyanobacteria in eutrophicated freshwaters play an important role in formation of annual summer blooms, yet overwintering mechanisms of these water bloom forming cyanobacteria remain unknown. The responses to darkness and low temperature of three strains (unicellular Microcystis aeruginosa FACHB-905, colonial M.?aeruginosa FACHB-938, and a green alga Scenedesmus quadricauda FACHB-45) were investigated in the present study. After a 30-day incubation under darkness and low temperature, cell morphology, cell numbers, chlorophyll a, photosynthetic activity (ETRmax and I k), and malodialdehyde (MDA) content exhibited significant changes in Scenedesmus. In contrast, Microcystis aeruginosa cells did not change markedly in morphology, chlorophyll a, photosynthetic activi...
2008-01-01
FEBEX II Project Final report on thermo-hydro-mechanical laboratory tests
International Nuclear Information System (INIS)
The results of the thermo-hydro-mechanical (THM) study of the FEBEX bentonite performed during FEBEX II are presented. The laboratory test program continued in part with the works carried out during FEBEX I, particularly in activities related to tests aimed to the calibration of the models, the acquisition of parameters by back-analysis and the improvement of the knowledge on the behaviour of expansive clays. But the program has also included tests on new areas: investigations about the influence of the microstructure changes in bentonite, of temperature and of the solute concentration on the behaviour of clay. Besides, several tests were proposed in order to understand the unexpected behaviour observed in the mock-up test, towards the end of year 2. Temperature effects on water retention curves in confined and unconfined conditions were determined, and swelling pressure, hydraulic conductivity and ...
Extension of the EQ3/6 computer codes to geochemical modeling of brines
Energy Technology Data Exchange (ETDEWEB)
Recent modifications to the EQ3/6 geochemical modeling software package provide for the use of Pitzer's equations to calculate the activity coefficients of aqueous species and the activity of water. These changes extend the range of solute concentrations over which the codes can be used to dependably calculate equilibria in geochemical systems, and permit the inclusion of ion pairs, complexes, and undissociated acids and bases as explicit component species in the Pitzer model. Comparisons of calculations made by the EQ3NR and EQ6 compuer codes with experimental data confirm that the modifications not only allow the codes to accurately evaluate activity coefficients in concentrated solutions, but also permit prediction of solubility limits of evaporite minerals in brines at 25/sup 0/C and elevated temperatures. Calculations for a few salts can be made at ...
1984-10-23
Quantum Transition State Theory for proton transfer reactions in enzymes
We consider the role of quantum effects in the transfer of hyrogen-like species in enzyme-catalysed reactions. This study is stimulated by claims that the observed magnitude and temperature dependence of kinetic isotope effects imply that quantum tunneling below the energy barrier associated with the transition state significantly enhances the reaction rate in many enzymes. We use a path integral approach which provides a general framework to understand tunneling in a quantum system which interacts with an environment at non-zero temperature. Here the quantum system is the active site of the enzyme and the environment is the surrounding protein and water. Tunneling well below the barrier only occurs for temperatures less than a temperature $T_0$ which is determined by the curvature of potential energy surface near the top of the barrier. We argue that for most ...
2009-01-01
Radiation thermocatalytic processes of hydrogen production from water
International Nuclear Information System (INIS)
The results of studies of radiation-thermocatalytic water decomposition in the 673-773 K temperature range in the presence of BeO and titanium Y-type zeolite are presented. It is found that radiation-thermocatalytic processes of hydrogen production from water are characterized by a lower activation energy (55.4 kJ/mole) as compared with thermocatalytic processes (88.4 kJ/mole). The radiation-thermocatalytic process rate in the presence of oxide systems is not an additive sum of rates of radiation-catalytic (at 296-300 K) and thermocatalytic processes of water decomposition. On the basis of obtained results the conclusion is made that during radiation-catalytic decomposition of water in a heterogeneous system BeO + H_2O the main contribution into this process is made by excitons, radiation-chemical yields of excitons and non-equilibrium charge-carriers are ...
In situ heat transfer in man-made geothermal energy reservoirs
Energy Technology Data Exchange (ETDEWEB)
Two hot dry rock geothermal energy reservoirs were created by hydraulic fracturing of Precambrian granitic rock on the west flank of the Valles Caldera, a dormant volcanic complex, in the Jemez Mountains of northern New Mexico. Heat was extracted in a closed-loop mode of operation, injecting water into one well and extracting the heated water from a separate production well. The first reservoir was produced by fracturing the injection well at a depth of 2.75 km (9020 ft) where the indigenous rock temperature was 185/sup 0/C. The relatively rapid thermal drawdown of the water produced from the first reservoir, 100/sup 0/C in 74 days, indicated that its effective fracture radius was about 60 m (200 ft). Average thermal power extracted was 4 MW. A second, larger reservoir was created by refracturing the injection well 180 m (600 ft) deeper. Downhole measurements of the water ...
1980-01-01
Hitch code capabilities for modeling AVT chemistry
International Nuclear Information System (INIS)
Several types of corrosion have damaged alloy 600 tubing in the secondary side of steam generators. The types of corrosion include wastage, denting, intergranular attack, stress corrosion, erosion-corrosion, etc. The environments which cause attack may originate from leaks of cooling water into the condensate, etc. When the contaminated feedwater is pumped into the generator, the impurities may concentrate first 200 to 400 fold in the bulk water, depending on the blowdown, and then further to saturation and dryness in heated tube support plate crevices. Characterization of local solution chemistries is the first step to predict and correct the type of corrosion that can occur. The pH is of particular importance because it is a major factor governing the rate of corrosion reactions. The pH of a solution at high temperature is not the same as the ambient temperature, since ionic dissociation constants, ...
1985-03-01
Thermally cleavable surfactants
Energy Technology Data Exchange (ETDEWEB)
Two new surfactant molecules are reported which contain thermally labile Diels-Alder adducts connecting the polar and non-polar sections of each molecule. The two surfactants possess identical non-polar dodecyl tail segments but exhibit different polar headgroups. The surfactants become soluble in water when anionic salts are formed through the deprotonation of the surfactant headgroups by the addition of potassium hydroxide. When either surfactant is exposed to temperature above about 60.degree. C., the retro Diels-Alder reaction occurs, yielding hydrophilic and hydrophobic fragments or the aqueous solutions of the surfactants subsequently exhibit loss of all surface-active behavior.
2009-09-29
Thermally cleavable surfactants
Energy Technology Data Exchange (ETDEWEB)
Two new surfactant molecules are reported which contain thermally labile Diels-Alder adducts connecting the polar and non-polar sections of each molecule. The two surfactants possess identical non-polar dodecyl tail segments but exhibit different polar headgroups. The surfactants become soluble in water when anionic salts are formed through the deprotonation of the surfactant headgroups by the addition of potassium hydroxide. When either surfactant is exposed to temperature above about 60.degree. C., the retro Diels-Alder reaction occurs, yielding hydrophilic and hydrophobic fragments or the aqueous solutions of the surfactants subsequently exhibit loss of all surface-active behavior.
2009-11-24
Thermally cleavable surfactants
Energy Technology Data Exchange (ETDEWEB)
Two new surfactant molecules are reported which contain thermally labile Diels-Alder adducts connecting the polar and non-polar sections of each molecule. The two surfactants possess identical non-polar dodecyl tail segments but exhibit different polar headgroups. The surfactants become soluble in water when anionic salts are formed through the deprotonation of the surfactant headgroups by the addition of potassium hydroxide. When either surfactant is exposed to temperature above about 60.degree. C., the retro Diels-Alder reaction occurs, yielding hydrophilic and hydrophobic fragments and the aqueous solutions of the surfactants subsequently exhibit loss of all surface-active behavior.
2006-04-04
Corrosion behavior of iron and nickel base alloys in high temperature and pressure water
International Nuclear Information System (INIS)
In equipment industries, the equipments handling industrial water and pure water are numerous. In power generation including nuclear power generation, water serves as a working medium. Review is made on the experiences in the corrosion of iron and nickel base alloys in high temperature, high pressure water and the results of researches derived from them. Under high temperature and high pressure, carbon steel, low alloy steel, stainless steel and high nickel alloy cause corrosion even in pure water. But in the case of serious corrosion, chlorine, oxygen, alkali and others in water take part. The following matters are described: corrosion by steam; stress corrosion cracking in pure water; corrosion by impurities in high temperature, high pressure pure water, ...
Energy Technology Data Exchange (ETDEWEB)
A prototype trumpet type nonimaging secondary concentrator was designed and fabricated for use with the Cummins Power Generation (CPG) 7.5 kW{sub e} dish-Stirling system. A set of operational tests was carried out with a high temperature heat pipe receiver and gas-gap calorimeter. These tests have successfully alleviated any operational concerns about the effectiveness of active water cooling for such devices. The authors obtained over two full days of testing with the cavity receiver operating at its design temperature of 660 C while the trumpet throat temperature remained {approx_equal} or less than 100 C. In addition, these tests have shown that the thermal isolation of the trumpet from the hot receiver is very effective. Highly variable insolation, instabilities in the temperature controller on the calorimeter, and a poor match between the optical quality of ...
1997-12-31
International Nuclear Information System (INIS)
In this thesis the rate constants for a number of radical reactions in aqueous solution have been studied in a wide temperature range. The reactions of H with H_2O_2, OH and HO_2 and the reactions of HO_2 with OH, Fe"2"+ and Cu"2"+ have been studied. For each reaction rate constants have been determined as a function of temperature using the technique of high temperature, high pressure (HTP) pulse radiolysis. The rate constants were obtained by fitting a kinetic computer model to the experimental data. From an Arrhenius plot the activation energy of each reaction was determined. The data determined in this way are important for modeling of radiolysis in nuclear light water reactors. A previously developed model for calculation of the effect of water radiolysis products on oxidation and dissolution of spent nuclear fuel has been improved. In the new model, called ...
2003-01-01
Energy Technology Data Exchange (ETDEWEB)
A patent is claimed for a direct coal liquefication process which is carried out by interaction with a paste, consisting of small-fragment coal, oil and catalysts, with H/sub 2/ at increased temperatures and pressures. The catalyst is a mixture of 1 part per weight of Fe-ore that's been activated by aqueous treatment, and 0.1-1.0 powder-form S. The Fe-ore can be magnetite, limonite, hematite, pyrite, ferrous sand or ''red mud'' (byproduct of the Bayer process), with the ''red mud'' and limonite, having a particle size of about 100 mesh is preferable. Activation of Fe-ore includes aqueous treatment in boiling water for 30-120 min with subsequent drying; annealing at a temp. of 300-700/sup 0/C for 10-120 min; submerging into cold water and final drying. The catalyst is added to the paste in the amount of ...
1982-06-22
Low temperature humidification dehumidification desalination process
Energy Technology Data Exchange (ETDEWEB)
The humidification dehumidification desalination process is viewed as a promising technique for small capacity production plants. The process has several attractive features, which include operation at low temperature, ability to utilize sustainable energy sources, i.e. solar and geothermal, and requirements of low technology level. This paper evaluates the characteristics of the humidification dehumidification desalination process as a function of operating conditions. A small capacity experimental system is used to evaluate the process characteristics as a function of the flow rate of the water and air streams, the temperature of the water stream and the temperature of the cooling water stream. The experimental system includes a packed humidification column, a double pipe glass condenser, a constant temperature water ...
2006-03-01
Low temperature humidification dehumidification desalination process
International Nuclear Information System (INIS)
The humidification dehumidification desalination process is viewed as a promising technique for small capacity production plants. The process has several attractive features, which include operation at low temperature, ability to utilize sustainable energy sources, i.e. solar and geothermal, and requirements of low technology level. This paper evaluates the characteristics of the humidification dehumidification desalination process as a function of operating conditions. A small capacity experimental system is used to evaluate the process characteristics as a function of the flow rate of the water and air streams, the temperature of the water stream and the temperature of the cooling water stream. The experimental system includes a packed humidification column, a double pipe glass condenser, a constant temperature water ...
2006-03-01
General corrosion of ALLOY 800 in high temperature water and its prevention
Energy Technology Data Exchange (ETDEWEB)
General corrosion behavior of ALLOY 800 in high temperature water was studied in relation to its surface film structure. The surface film formed in water was found to decrease the corrosion rate of ALLOY 800. This film is composed of Ni ferrite, and can be obtained by oxidation in air or steam. Based on these results, air or steam oxidation treatment to inhibit Ni and Co release of ALLOY 800 into high temperature water is proposed. (author).
1989-10-01
General corrosion of ALLOY 800 in high temperature water and its prevention
International Nuclear Information System (INIS)
General corrosion behavior of ALLOY 800 in high temperature water was studied in relation to its surface film structure. The surface film formed in water was found to decrease the corrosion rate of ALLOY 800. This film is composed of Ni ferrite, and can be obtained by oxidation in air or steam. Based on these results, air or steam oxidation treatment to inhibit Ni and Co release of ALLOY 800 into high temperature water is proposed. (author).
Lipase catalyzed esterification of glycidol in organic solvents
The authors studied the resolution of racemic glycidol through esterification with butyric acid catalyzed by porcine pancreatic lipase in organic media. A screening of seven solvents (log P values between 0.49 and 3.0, P being the n-octanol-water partition coefficient of the solvent) showed that neither log P nor the logarithm of the molar solubility of water in the solvent provides good correlations between enantioselectivity and the properties of the organic media. Chloroform was one of the best solvents as regards the enantiometic purity (e.p.) of the ester produced. In this solvent, the optimum temperature for the reaction was determined to be 35C. The enzyme exhibited maximum activity at a water content of 13 [plus minus] 2% (w/w). The enantiomeric purity obtained was 83 [plus minus] 2% of (S)-glycidol butyrate and did not depend on the alcohol concentration or the enzyme ...
1993-08-05
A novel single-step synthesis of N-doped TiO"2 via a sonochemical method
British Library Electronic Table of Contents (United Kingdom)
A novel single-step synthetic method for the preparation of anatase N-doped TiO"2 nanocrystalline at low temperature has been devoleped. The N-doped anatase TiO"2 nanoparticles were synthesized by sonication of the solution of tetraisopropyl titanium and urea in water and isopropyl alcohol at 80^oC for 150min. The as-prepared sample was characterized by X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy and UV-vis absorption spectrum. The product structure depends on the reaction temperature and reaction time. The photocatalytic activity of the as-prepared photocatalyst was evaluated via the photodegradation of an azo dye direct sky blue 5B. The results show that the N-doped TiO"2 nanocrystalline prepared via sonication exhibit an excellent photocatalytic...
2011-01-01
One-electron reduction of chloroperoxidase by radiolytically generated electrons
Energy Technology Data Exchange (ETDEWEB)
Upon irradiation of aqueous ethylene glycol/water solutions of native chloroperoxidase (CPO) with {sup 60}Co-gamma rays at 77K one observes the one-electron reduction of the enzyme active site by radiolytically generated thermolyzed electrons. In the present study the first absorption spectrum of a low-spin ferrous form of CPO is reported which has peaks at 438, 532 and 563 nm, similar to those observed previously for cytochrome P-450. All previously described ferrous forms of CPO are high spin. In order to observe the final results of the CPO reaction with electrons, the spectral changes of native enzyme after room temperature-gamma-irradiation have also been investigated. Evidence of changes is also presented probably connected with disruption of the tertiary structure of enzyme, correlated with decrease of enzyme activity.
1990-05-16
One-electron reduction of chloroperoxidase by radiolytically generated electrons
International Nuclear Information System (INIS)
Upon irradiation of aqueous ethylene glycol/water solutions of native chloroperoxidase (CPO) with "6"0Co-gamma rays at 77K one observes the one-electron reduction of the enzyme active site by radiolytically generated thermolyzed electrons. In the present study the first absorption spectrum of a low-spin ferrous form of CPO is reported which has peaks at 438, 532 and 563 nm, similar to those observed previously for cytochrome P-450. All previously described ferrous forms of CPO are high spin. In order to observe the final results of the CPO reaction with electrons, the spectral changes of native enzyme after room temperature-gamma-irradiation have also been investigated. Evidence of changes is also presented probably connected with disruption of the tertiary structure of enzyme, correlated with decrease of enzyme activity.
1990-05-01
Measurements of radon concentration levels in drinking water at urban area of Curitiba, Brazil
International Nuclear Information System (INIS)
Current work presents the results of more than 100 measurements of 222Rn activity in drinking water collected at artesian bores at Curitiba region during the period of 2008 - 2009. The measurements were performed at the Laboratory of Applied Nuclear Physics of the Federal University of Technology in cooperation with the Nuclear Technology Development Center (CDTN) of Brazilian Nuclear Energy Committee (CNEN). Experimental setup was based on the Professional Radon Monitor (ALPHA GUARD) connected to specific kit of glass vessels Aqua KIT through the air pump. The equipment was adjusted with air flow of 0.5 L/min. The 222Rn concentration levels were detected and analyzed by the computer every 10 minutes using the software DataEXPERT by GENITRON Instruments. Collected average levels of 222Rn concentration were processed taking into account the volume of water sample and its temperature, atmospheric pressure ...
This site explains how temperature, pressure, and salinity work together to determine the density of ocean water. The three density layers of the ocean are described by means of text description and a graphic illustration.
MTF ' MISSISSIPPI SOUND REMOTE SENSING STUDY I 19 SEPTEMBER 1972
metric temperatures has been prepared showing the surface water temper- ... occasion, gray levels show different densities for similar water temper- ...
Fetal cardiotocography before and after water aerobics during pregnancy
UK PubMed Central (United Kingdom)
ObjectiveTo evaluate the effect of moderate aerobic physical activity in water on fetal cardiotocography patterns in sedentary pregnant women.MethodIn...Full Text Available
Regeneration of granular activated carbon using hydrothermal technology
Energy Technology Data Exchange (ETDEWEB)
The economic feasibility of using granular activated carbon (GAC) to remove organic contaminants from industrial and municipal wastewater is contingent upon its reuse during multiple adsorption-regeneration cycles. The most common process for the regeneration of GAC is the thermal method. Drawbacks associated with thermal regeneration include a 5--10% loss of carbon due to oxidation and attrition, a decrease in adsorption capacity, and high energy costs. The purpose of this study was to investigate the regeneration of GAC using hydrothermal technology. Phenol contaminated and non-contaminated GAC samples were regenerated using supercritical water (411 deg C and 26.2 MPa) with dissolved oxygen concentrations of 0 mg/L, 5 mg/L, and 100 mg/L. For comparative purposes, GAC was regenerated using subcritical water (300 deg C and 12.4 MPa) with a dissolved oxygen concentration of 5 mg/L. Regenerated GAC samples were evaluated in ...
1999-05-01
The seeded growth of calcium sulfate dihydrate crystals in NaCl solutions up to 6 m and 90 C
Energy Technology Data Exchange (ETDEWEB)
The kinetics of calcium sulfate crystal growth is of importance in various fields, such as geochemistry, desalination technology, petroleum industry, and water and wastewater treatment. The seeded crystal growth rate of calcium sulfate dihydrate was measured as a function of supersaturation in NaCl electrolyte solutions from 0 to 6 m at temperatures of 25, 50, 70, and 90 C. The growth followed a second-order parabolic rate law with activation energies greater than 53 kJ/mol which suggested the surface reaction as the rate-limiting step. It was observed that the rate constant and the activation energy are solution composition dependent. The rate constant increases with NaCl concentration up to 3 molal and then begins to fall slightly. The activation energy dropped from 61 kJ/mol in the pure Ca-SO[sub 4]H[sub 2]O system to 53 kJ/mol in 3.0 m NaCl solutions. The electrolyte effect was ...
1994-03-15
Finalisation of design provision for active process water system shut down at TAPP-3 and 4
International Nuclear Information System (INIS)
Active Process Water (APW) system is provided as a unitized system in TAPP-3 and 4. Maintenance on APW system requires shutdown of this system. As shut down heat exchangers are fed by APW system; during APW system shutdown cold shutdown state cannot be maintained. Therefore safety analysis is done to optimize the duration of reactor shutdown (which means low decay heat) after which APW shutdown can be taken with minimum water supply to the shutdown heat exchangers. Based on this analysis, it is proposed in technical specification that APW system shutdown can be taken after 7 days of reactor shutdown with shutdown heat exchangers supplied with about 20 % of normal APW flow. With this configuration, PHTS, moderator, end shield, calandria vault water temperature can be maintained within limits. A design provision is made at TAPP-3 and 4 to interconnect APW system of both units in such ...
2006-11-13
International Nuclear Information System (INIS)
In this paper, we calculated the radioactive concentration distribution of radioactive waste water, the temperature distribution of drained cooling water and the effect of implement from the Daya Bay Nuclear Power Plant on nearby waters range, discussed and analysed some problems of computational results and computation with Alternating Direction Implicit Method (ADI). The contents of the article included: the establishment of two-dimension tidal current equation, radioactive waste water pollutant dispersion equation and cooling water heat convection diffusion equation, the numerical difference calculation model of tidal current field, concentration field as well as temperature field, effect impingement with ADI method, numerical calculation results. The result of research showed that: when the Daya Bay Nuclear Power Plant is on normal ...
W1045 environment surf drip shield and waste package outer barrier
Energy Technology Data Exchange (ETDEWEB)
The environments on the drip shield and waste package outer barrier are controlled by the compositions of the waters that contact these components. the temperature (T) of these components, and the effective relative humidity (RH) at these components. Because the composition of the waters that are expected to enter the emplacement drifts (either by seepage flow or by episodic flow) have not been specified: well J13 water was chosen as the reference water (Harrar 1990). Section 6.2 discusses the accessible RH for the temperatures of interest at the repository horizon. Section 6.3 discusses the adsorption of water on metal alloys in the absence of hygroscopic salts. Because the temperatures of the DSs and the WPOBs are higher than those of the surrounding near-field environment, the relative humidity at the DSs and the ...
1999-07-14
Fingerprinting of Penicillium crustosum strains was performed using different phenotypic characteristics. Seven strains of this extremely homogenous species were selected; of these, five originated from geographical locations characterized by low temperatures, and one from a location with a low water activity. Principal component analysis (PCA) was performed using micromorphological data, temperature- and water-dependent growth rates, and extrolite profiles obtained by HPLC analysis. The micromorphological data were less informative, while the growth-rate data were informative only if the strains investigated already showed slight adaptations to the selected external parameter. In contrast, PCA analyses of the extrolite data showed groupings of the strains according to their origins and known physiological differences. These groupings are in full agreement with the clustering ...
2009-04-08
Phytoplankton in the Damariscotta River Estuary
... s excellent water quality and ideal temperature conditions. Oyster aquaculture operations on the Damariscotta lease about 100 acres ... ...
Nodule and Leaf Nitrate Reductases and Nitrogen Fixation in Medicago sativa L. under Water Stress
UK PubMed Central (United Kingdom)
The effect of water stress on patterns of nitrate reductase activity in the leaves and nodules and on nitrogen fixation were investigated in Medicago sativa L. plants watered 1 week...Full Text Available
1982-02-01
Thermosensitive TRP channel pore turret is part of the temperature activation pathway
UK PubMed Central (United Kingdom)
Temperature sensing is crucial for homeotherms, including human beings, to maintain a stable body core temperature and respond to the ambient environment. A group of exquisitely temperature-sensitive...Full Text Available
2010-04-13
British Library Electronic Table of Contents (United Kingdom)
A laboratory-scale multi-layer system was developed for the adsorption of PCDD/Fs from gas streams at various operating conditions, including gas flow rate, operating temperature and water vapor content. Excellent PCDD/F removal efficiency (>99.99%) was achieved with the multi-layer design with bead-shaped activated carbons (BACs). The PCDD/F removal efficiency achieved with the first layer adsorption bed decreased as the gas flow rate was increased due to the decrease of the gas retention time. The PCDD/F concentrations measured at the outlet of the third layer adsorption bed were all lower than 0.1ng I-TEQNm-3. The PCDD/Fs desorbed from BAC were mainly lowly chlorinated congeners and the PCDD/F outlet concentrations increased as the operating temperature was increased. In addition, the r...
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
Hydrolysis of olive oil by Chromobacterium viscosum lipase was studied in a reverse micellar system of a anionic surfactant Aerosol OT (AOT) and isooctane. Different methods of solubilization of the micellar system afford specific dependence of enzymatic activity of the lipase on the water content in the micelles. In an injection method, water content is controlled by the amount of injected water, which determines the micelle size and hydrophobicity of the micelle without salt addition and changes reversibly the conformation of lipase corresponding to the change of lipase activity. The activity reaches the maximum at a water content (water/AOT)of 7. In a phase transfer method, water content is determined by salt concentration in the aqueous phase in contact with micelles and the ...
1992-01-10
A novel domestic electric water heater model for a multi-objective demand side management program
Energy Technology Data Exchange (ETDEWEB)
This paper presents a novel domestic hot water heater model to be used in a multi-objective demand side management program. The model incorporates both the thermal losses and the water usage to determine the temperature of the water in the tank. Water heater loads are extracted from household load data and then used to determine the household water usage patterns. The benefits of the model are: (1) the on/off state of the water heater and temperature of the water in the tank can be accurately predicted, and (2) it enables the development of water usage profiles so that users can be classified based on usage behaviour. As a result, the amount of ancillary services and peak shaving that can be achieved are accurately predictable and can be maximized without adversely affecting ...
2010-12-15
Environmental data for sites in the National Solar Data Network
Energy Technology Data Exchange (ETDEWEB)
The environmental data for the NSDN are presented in the form of tables for each solar site. The solar sites are grouped into 12 zones, each of which consists of several adjacent states. The solar energy sites are in alphabetical sequence within each zone. The tables provide available meteorological data for reporting sites in the NSDN as follows: Insolation - the insolation table presents the total, diffuse, direct, maximum, and extra-terrestrial radiation for the solar site. It also shows the ratio of total extra-terrestrial radiation, as a percent. Temperature - the temperature table gives the average, daytime, nightime, maximum, minimum and inlet-water temperatures for the solar site. Additional tables are presented for some of these NSDN sites, supplying either wind or relative humidity data, or both. Wind - all of the passive and some of the active solar sites are equipped ...
1980-12-01
Pozzolanic behaviour of compound-activated red mud-coal gangue mixture
Energy Technology Data Exchange (ETDEWEB)
The pozzolanic behaviour of compound-activated red mud-coal gangue has been investigated through TG, DTA, XRD, FTIR and {sup 27}Al MAS NMR. From viewpoint of reaction kinetics, it is found that the pozzolanic reaction mechanism of the compound-activated red mud-coal gangue-lime system is clearly consistent with diffusion control up to 14 days, and the reaction rate constant calculated from Jander equation decreases with the increase of CaO addition in the system. The hydration products formed in the red mud coal gangue-lime systems at ambient temperature are essentially aluminous C-S-H and Ca{sub 3}Al{sub 2}O{sub 6} center dot xH{sub 2}O. From TG analysis results, it is thought that the high amount of Ca(OH){sub 2} in the pastes of studied system is not conducive to the continual increase of non-evaporable water content of the hydration products. Of particular interest. {sup 27}Al MAS NMR proved to be ...
2011-03-15
Pozzolanic behaviour of compound-activated red mud-coal gangue mixture
International Nuclear Information System (INIS)
The pozzolanic behaviour of compound-activated red mud-coal gangue has been investigated through TG, DTA, XRD, FTIR and 27Al MAS NMR. From viewpoint of reaction kinetics, it is found that the pozzolanic reaction mechanism of the compound-activated red mud-coal gangue - lime system is clearly consistent with diffusion control up to 14 days, and the reaction rate constant calculated from Jander equation decreases with the increase of CaO addition in the system. The hydration products formed in the red mud-coal gangue - lime systems at ambient temperature are essentially aluminous C-S-H and Ca3Al2O6.xH2O. From TG analysis results, it is thought that the high amount of Ca(OH)2 in the pastes of studied system is not conducive to the continual increase of non-evaporable water content of the hydration products. Of particular interest, 27Al MAS NMR proved to be an effective technique to obtain valuable ...
2011-03-01
Radioactive iodine absorbing properties of tetrathiafulvalene
Energy Technology Data Exchange (ETDEWEB)
For the purpose of searching some effective absorbents of gaseous radioactive iodine, 16 substances considered as having an affinity for iodine were investigated with regular iodine and /sup 125/I. In a preliminary survey, only tetrathiafulvalene (TTF) was found to have satisfactory absorbing properties comparable to activated charcoal. A further detailed comparison of the properties between TTF and activated charcoal led us to the conclusion that the former has more preferable properties as absorbent of radioactive iodine than the latter in all points studied. The results are summarized as follows: (1) The absorption of iodine on TTF in atmosphere was about twice as much as that on activated charcoal. Desorption of iodine from saturatedly absorbed iodine on TTF was practically negligible except trace amount of initial desorption, while that on activated charcoal was considerable (3%/50h) even in the ...
1989-05-01
British Library Electronic Table of Contents (United Kingdom)
The physical and antioxidant properties of alginate biodegradable film incorporating white, red and extruded white ginseng extracts were investigated. No differences in moisture contents of all alginate film samples were noticeable (p>0.05) except those film samples incorporated without ginseng extract, which had the highest moisture content. The addition of ginseng extract to alginate film decreased tensile strength and elastic modulus (p<0.05) but increased the percent elongation at break. The presence of extracts did not significantly affect the water vapor permeability of the film samples. Alginate film containing extruded white ginseng extract at a barrel temperature of 130degreeC presented the highest (61.12%) free-radical scavenging activity against the 2,2-diphenyl-1-picryhydrazyl ...
2010-01-01
Energy Technology Data Exchange (ETDEWEB)
Japanese companies have developed suitable cleansing technologies and export their know-how. Some original technologies are developed today, like: in-situ chemical oxidation, iron confinement, hot-soil process, low-temperature catalytic decomposition or dechlorination of dioxins. However, some pollutions are still poorly considered (nitrates) or badly mastered (dioxins). This situation is partly due to late legal decisions and to limited pollution abatement measures. Japan is also very active in bio-cleansing research, and this, despite the lack of dialogue and directives at the national level. Several research programs with important funds have started since 1995. However, Japan is still at the preliminary stage in open-field applications of cleansing methods. (J.S.)
1999-11-01
Energy Technology Data Exchange (ETDEWEB)
The corrosion behaviour of the stainless steels 304, 316 Ti, 25Cr-20Ni-Mo-Ti, nickel base alloys Hastelloy C4, Inconel 625, Incoloy 800, Ti and Ti-0.2% Pd alloy has been studied in the aerated or deaerated solutions at 20/sup 0/C and 90/sup 0/C whose compositions are representative of interstitial ground waters: granitic or clay waters or salt brine. The electrochemical techniques used are voltametry, polarization resistance and complexe impedance measurements. Electrochemical data show the respective influence of the parameters such as temperature, solution composition and dissolved oxygen, addition of soluble species chloride, fluoride, sulfide and carbonates, on which depend the corrosion current density, the passivation and the pitting potential. The inhibition efficiency of carbonate and bicarbonate activities against pitting corrosion is determined. In clay water at 90/sup ...
1985-01-01
Activated charcoal from coconut shell using ZnCl{sub 2} activation
Energy Technology Data Exchange (ETDEWEB)
In this study attempts have been made to utilize biomass residues in a proper and efficient way. As a part of these attempts activated charcoal has been produced from coconut shell. The effects of temperature, time and impregnation ratio on activation and yield have also been studied. Experimental results show that higher temperature produces better activation but lower yield. The optimum values for activation time and impregnation ratio in producing activated charcoal were 50 min and 40%, respectively, at 600{sup o}C. (Author)
2002-05-01
Performance of single cylinder, direct injection diesel engine using water fuel emulsions
Energy Technology Data Exchange (ETDEWEB)
A single cylinder diesel engine study of water-in-diesel emulsions was conducted to investigate the effect of water emulsification on the engine performance and gases exhaust temperature. Emulsified Diesel fuels of 0, 5, 10, 15 and 20 water/diesel ratios by volume were used in a single cylinder, direct injection diesel engine, operating at 1200-3300 rpm. The results indicate that the addition of water in the form of emulsion improves combustion efficiency. The engine torque, power and brake thermal efficiency increase as the water percentage in the emulsion increases. The average increase in the brake thermal efficiency for 20% water emulsion is approximately 3.5% over the use of diesel for the engine speed range studied. The proper brake specific fuel consumption and gases exhaust temperature decrease as the percentage ...
2004-03-01
Water You Engineering? An Activity to Develop Water-Quality Awareness
Water is one of our most precious resources. However, for many in the United States, having fresh, safe drinking water is taken for granted, and due to this perceived lack of relevance, students may not fully appreciate the luxury of having safe running water--in the home. One approach to resolving water-quality issues in the United States may reside in providing education that presents accurate information in a meaningful way. Accordingly, this article describes a unit designed to emphasize the importance of water-quality testing and purification and to introduce students to local water-quality issues. The engineering-based module of this eighth-grade science activity is particularly important due to the design-build-test component. (Contains 5 figures.)
2009-04-01
Development of a geothermal heat pump. Final report
Energy Technology Data Exchange (ETDEWEB)
In the development of a geothermal heat pump a water source heat pump was connected to a 1-1/2'' water line, 2200' long, buried in an endless loop 10' deep. The system is closed, circulating the same water continuously through the heat pump back to the field again. This water line 10' deep is the geothermal heat source. No matter how cold the air temperature gets on a winter day the water temperature to the heat pump will always be above 45/sup 0/F. This system has efficiently heated our house the past year using no supplemental heat.
1981-11-02
High quality water supply system; Joshitsusui kyokyu system
Energy Technology Data Exchange (ETDEWEB)
This paper, firstly, introduces the background in developing a high quality water supply system, in which the drinking water system is isolated inside a building. Results of questionnaire on the high quality service water are illustrated. The results of questionnaire have revealed that the high quality service water is extremely interested. Then, are described the target quality of high quality water, the constitution of high quality water supply system, the treatment process, the measures to secure safety and sanitary, and the method of maintenance. The high quality water is produced through the activated charcoal absorption treatment, membrane treatment, ozonation, cooling, mineral addition, and disinfection of city water. Furthermore, application examples of this system adopted to a department ...
1995-01-15
Energy Technology Data Exchange (ETDEWEB)
The disclosure is directed to an active magnetic regenerator apparatus and method. Brayton, Stirling, Ericsson, and Carnot cycles and the like may be utilized in an active magnetic regenerator to provide efficient refrigeration over relatively large temperature ranges.
1982-01-01
Activated wood charcoal from rubber plants
Energy Technology Data Exchange (ETDEWEB)
The conditions for the production of activated charcoal having a decolorization power (DP) of less than 160 mL/g for methylene blue solutions from the wood of rubber plants were activation temperature of 1000 degrees, rentention time of 30 minutes, and steam-char-ratio of approximately 1.7. The installation of a side-burner around the rotary kiln to decrease the temperature gradient increased the DP of the activated charcoal to 190-200 mL/g without a decrease in yield.
1982-01-01
International Nuclear Information System (INIS)
The research committee of the Atomic Energy Society of Japan on water chemistry standard aims at establishing the private standard of water chemistry of nuclear power plants. The committee gathers up 'BWR water chemistry management manual', 'PWR primary system water chemistry management manual' and 'PWR water chemical analysis standard method', and furthermore aims at the standardization of those in future. Looking back on the committee's activities for the past four years, latest results of research of water chemistry mainly contributing to safe and reliable nuclear power plants were described with the future perspective of water chemistry and a demanded break-through. (T.T.)
2007-05-01
Desorption of uranium from titanium-activated carbon composite adsorbent with acidic eluent, 2
Energy Technology Data Exchange (ETDEWEB)
The desorption of uranium from the granular titanium-activated carbon composite adsorbent (concentration of uranium: 25.5 mg/l-Ad), which adsorbed uranium from natural sea water, was examined by the column process with acidic eluent at room temperature. The column operation was able to be carried out without destruction of the granular adsorbent by the generation of the carbon dioxide, and free from disturbance of the eluent flow by precipitate of calcium sulfate dihydrate with sulfuric acid eluent. The amount of acid consumption by the adsorbent was 0.87 eq/l-Ad. The alkaline earth metals were eluted in the range of elution volume below 2l/l-Ad, whereas uranium, iron, and titanium were eluted above 2l/l-Ad. Therefore, uranium was separable from the alkaline earth metals which were adsorbed in the most quantity in the adsorbent. In the range of elution volume 2 to 12l/l-Ad, the percentage of desorbed uranium and the ...
1984-01-01
High resolution neutron imaging of water in the polymer electrolyte fuel cell membrane
Energy Technology Data Exchange (ETDEWEB)
Water transport in the ionomeric membrane, typically Nafion{reg_sign}, has profound influence on the performance of the polymer electrolyte fuel cell, in terms of internal resistance and overall water balance. In this work, high resolution neutron imaging of the Nafion{reg_sign} membrane is presented in order to measure water content and through-plane gradients in situ under disparate temperature and humidification conditions.
2009-01-01
Energy Technology Data Exchange (ETDEWEB)
The objective of this work is to determine the ability of indigenous bacteria from a Venezuelan oil field to grow under reservoir conditions inside a porous media, and to produce metabolites capable of recovering residual crude oil. For this purpose, samples of formation waters from a central-eastern Venezuelan oil reservoir were enriched with different carbon sources and a mineral basal media. Formation water was used as a source of trace metals. The enrichments obtained were incubated at reservoir temperature (71{degrees}C), reservoir pressure (1,200 psi), and under anaerobic conditions for both outside and inside porous media (Berea core). Growth and metabolic activity was followed outside porous media by measuring absorbance at 660 nm, increases in pressure, and decreases in pH. Inside porous media bacterial activity was determined by visual examination of the produced ...
1995-12-31
The inhomogeneous structure of water at ambient conditions
UK PubMed Central (United Kingdom)
Small-angle X-ray scattering (SAXS) is used to demonstrate the presence of density fluctuations in ambient water on a physical length-scale of ≈1 nm; this is retained with decreasing temperature...Full Text Available
2009-09-08
Mutagenic activity of disinfection by-products.
UK PubMed Central (United Kingdom)
Data on raw water quality, disinfection treatment practices, and the resulting mutagenic properties of the treated water were compiled from pilot- and full-scale treatment experiments to evaluate that...Full Text Available
1986-11-01
Microbial treatment of high explosives
Energy Technology Data Exchange (ETDEWEB)
Both DOE and DOD use water and/or steam in the process of removing high explosives, resulting in large quantities of contaminated water, which is then run through activated carbon, which then has to be decontaminated. Research has been underway to utilize microorganisms to degrade RDX and HMX.
1997-07-01
TRIGA spent fuel bundles safe storage
International Nuclear Information System (INIS)
TRIGA-SSR is a steady state research and material test reactor that has been in operation since 1980. The original TRIGA fuel was HEU (highly enriched uranium) with a U"2"3"5 enrichment of 93 per cent. Almost all TRIGA HEU fuel bundles are now burned-up. Part of the spent fuel was loaded and transferred to US, in a Romania - DOE arrangement. The rest of the TRIGA fuel bundles have to be temporarily stored in the TRIGA facility. As the storage conditions had to be established with caution, neutron and thermal hydraulic evaluations of the storage conditions were required. Some criticality evaluations were made based on the SAR (Safety Analysis Report) data. Fuel constant axial temperature approximation effect is usual for criticality computations. TRIGA-SSR fuel bundle geometry and materials model for SCALE5-CSAS module allows the introduction of a fuel temperature dependency for the entire fuel active height, using different ...
2007-05-13
Effects of low-intensity prolonged exercise on PGC-1 mRNA expression in rat epitrochlearis muscle.
We previously reported that the peroxisome proliferator-activated receptor gamma coactivator-1 (PGC-1) mRNA in rat epitrochlearis muscle was increased after swimming exercise training. In the present study, we demonstrated further that PGC-1 mRNA expression in the epitrochlearis muscle of 4-5-week-old male Sprague-Dawley rats was increased after a 6-h acute bout of low-intensity swimming exercise. With this increase, the expression level was approximately 8-fold of control and immersion group rats that stayed for 6-h in warm water, maintained at the identical temperature of the swimming barrel (35 degrees C) (p<0.01). Second, PGC-1 mRNA expression in the muscle was found to have increased 6-h after 30 10-s tetani contractions were induced by in vitro electrical stimulation. Finally, PGC-1 mRNA expression in the muscle incubated for 18-h with 0.5mM 5-aminoimidazole-4-carboxamide ribonucleoside (AICAR: a 5' ...
2002-08-16
A comparison study on activation safety of fusion, fission and hybrid reactor technology
Energy Technology Data Exchange (ETDEWEB)
The activation aspects of pure fusion and hybrid fusion technology is studied to assess the radioactive safety of various fusion concepts including tokamak pure fusion, fissile fuel producing hybrid and radio waste transmuting hybrid. The activation properties of breeding, coolant and structural materials in fusion reactors might be quite different from those in fission reactors because of the high energy D-T fusion neutrons from the fusion cores. A study on the involved activation reactions and the uncertainties of the associated nuclear cross-sections is carried. The activation properties of various first wall concepts and blanket concepts are discussed. The radioactive inventory during the operation lifetime and the potential hazard of the radioactive nuclides with respect to near term (reprocessing) and long term (waste disposal) aspects are calculated, with reference to ITER/NET (International ...
1994-12-31
A comparison study on activation safety of fusion, fission and hybrid reactor technology
International Nuclear Information System (INIS)
The activation aspects of pure fusion and hybrid fusion technology is studied to assess the radioactive safety of various fusion concepts including tokamak pure fusion, fissile fuel producing hybrid and radio waste transmuting hybrid. The activation properties of breeding, coolant and structural materials in fusion reactors might be quite different from those in fission reactors because of the high energy D-T fusion neutrons from the fusion cores. A study on the involved activation reactions and the uncertainties of the associated nuclear cross-sections is carried. The activation properties of various first wall concepts and blanket concepts are discussed. The radioactive inventory during the operation lifetime and the potential hazard of the radioactive nuclides with respect to near term (reprocessing) and long term (waste disposal) aspects are calculated, with reference to ITER/NET (International ...
Energy Technology Data Exchange (ETDEWEB)
Progress reports are presented for the following two areas: catalytic cracking studies with water-wet silica-alumina catalysts; and Fischer-Tropsch reactor studies where similarities and differences between fixed bed and slurry type reactors are investigated and further experiments conducted to measure mass transfer coefficients and reaction kinetics which are to be used in a model slurry reactor. The following are some of the conclusions. (1) The premise that the presence of liquid water might increase catalytic cracking activity was found to be invalid. It was demonstrated that cracking can occur at previously unobserved low temperatures (though at low conversions) and that an anomaly exists in that one of the catalysts tested shows an entirely different cracking behavior and probably follows a different cracking mechanism. (2) the diameter of a fixed-bed Fischer-Tropsch reactor critically affected ...
1981-09-01
Feedwater control device of the steam generator in an atomic power station
International Nuclear Information System (INIS)
Purpose: In a case of automatically controlling the water level at the time of generating a lower power, to impact the followability of the control necessary for the power variation of the steam generator thereby to obtain good controllability. Constitution: A signal of deviation of water level of a steam generator and its set value and a signal of a difference between the temperature of the primary coolant in the high temperature side pipeline and that of the primary coolant in the low temperature side pipeline are used to automatically or manually control the flow quantity of water fed to the steam generator. (Yoshihara, H.).
Chalon/Saint-Marcel manufacturing plant; L'usine de Chalon/Saint-Marcel
Energy Technology Data Exchange (ETDEWEB)
AREVA is the world leader in the design and construction of nuclear power plants, the manufacture of heavy components, and the supply of nuclear fuel and nuclear services such as maintenance and inspection. The Equipment Division provides the widest range of nuclear components and equipment, manufactured at its two facilities in Jeumont, northern France, and St. Marcel, in Burgundy. The St. Marcel plant, set on 35 ha (87.5 acres) near Chalon-sur-Saone, was established in 1973 in a region with a long history of specialized metalworking and mechanical activities to meet the demand for non-military nuclear requirements in France. The site offers two advantages: - excellent facilities for loading and transporting heavy components on the Saone river, - it's proximity to other group sites. Since its completion in 1975, the Chalon/St. Marcel facility has manufactured all the heavy components for French pressurized water reactors (PWRs) ...
2008-07-01
Radon grab sampling in water by means of radon transfer in activated charcoal collectors
Energy Technology Data Exchange (ETDEWEB)
The proposed portable device is suitable for radon surveys in water-bearing strata. It allows a complete transfer in activated charcoal canisters of radon dissolved in water collected with a 0.61 bottle. The detection is performed in laboratory with a low background {gamma}-ray spectrometer utilizing 3{sup x}3{sup N}aI({tau}I) scintillator only after about ten hours. This time is necessary to let radon be uniformly distributed within the activated charcoal.
1999-08-01
Energy Technology Data Exchange (ETDEWEB)
For light water reactors, loss of coolant is an important point in safety analysis, whereas for gas-cooled reactors the ingress of water into the core region is an incident of safety relevance. The applicability of the computer code system GAMTEREX to pebble beds of spherical high-temperature gas-cooled reactor fuel elements with simulated water ingress is verified by experiment. The measurements were performed at a Siemens-Argonaut reactor, using its ring core as a driver zone for a pebble-bed core in the center of the reactor.
1987-09-01
Water Temperature and Concentration Measurements Within ...
... RP-3 exploding bridgewire detonator (Teledyne RISI, 29 mg pentaerythritol tetranitrate (PETN)) and the main charge, which was either 12.7 or 25.4 ...
2011-03-15
Energy Technology Data Exchange (ETDEWEB)
We have studied freshly prepared lysozyme solutions in heavy water for two NaCl concentrations as a function of temperature. Lysozyme solubilities in this solvent are determined by static light scattering. By small angle neutron scattering, we evidence that interactions between lysozyme molecules are characterized by a second virial coefficient A{sub 2} whether the solution is under-saturated or supersaturated. From the variation of A{sub 2} as a function of temperature we have evaluated the enthalpy corresponding to the interaction between lysozyme molecules. We show that the interactions between protein molecules are higher in heavy water than in light water. (authors). 13 refs., 3 figs.
1996-04-01
International Nuclear Information System (INIS)
... University, Fracture and Reliability Research Institute, Sendai, Miyagi (Japan)
2009-05-01
British Library Electronic Table of Contents (United Kingdom)
In this work, a three-dimensional multiphase non-isothermal model incorporated with a capillary-extended sub-model in gas channels is used to investigate the coupled phenomena of water and thermal transport in proton exchange membrane fuel cells. Distributions of water and temperature along the flow path in the channel are highlighted and the pros and cons of various operating temperatures are elaborated. In addition, this work also sheds light on the impacts of temperature variations of bipolar plates induced by non-uniform cooling conditions, which have been overlooked by most previous works. An important phenomenon of water distribution, dry-out at inlets and flooding at outlets (DIFO), is observed and this non-uniform distribution is revealed to be greatly influenced by the operating t...
2011-01-01
International Nuclear Information System (INIS)
... Dozaki, Koji Takiguchi, Hideki Japan Atomic Power Company, Tokyo (Japan)
2008-05-01
International Nuclear Information System (INIS)
... Industry, Material Science Research Laboratory, Yokosuka, Kanagawa (Japan)
2010-10-01
Research Activities in the Spokane, Washington, Field Office...
other chemical applications include use in water softeners, detergents, and food additives. The development of phosphate resources as a leasable commodity provides income to...
2011-08-20
Thermal- and radiation-induced interactions of water on U02 surfaces.
Energy Technology Data Exchange (ETDEWEB)
Most plans for the disposition of surplus nuclear materials involve storage in sealed containers where the evolution of gases from reactions of adsorbed water could present both pressure and flammability hazards[l] . Despite efforts such as calcining the material to minimize the water content prior to packaging, both residual moisture and readsorbed water may be present in the final containers . Given the anticipated temperature excursions during transportation and storage, this water may thermally desorb, increasing the pressure, and/or thermally dissociate to produce H2 gas, increasing flammability hazards . In addition, the radiation from the nuclear material may induce radiolysis of the water with the likely products being water vapor, H2, 02 and H2O2. In order to better understand the relative importance of the thermal- and ...
2003-01-01
Mathematical modeling of a direct contact humidification?dehumidification desalination process
British Library Electronic Table of Contents (United Kingdom)
Using air as a carrier gas is common in humidification?dehumidification desalination processes. A computer program was written using mass and energy balances for modeling the process behavior. The parameters considered in this work were inlet air and fresh water recycle temperatures, inlet air flow rate, saline water and fresh water recycle flow rates, and saline water to air flow ratio. Results of simulation showed that increasing inlet air and fresh water recycle flow rate increases fresh water production. It was also found that heating the inlet air to humidification column or cooling the inlet water to dehumidification column increases the production rate but increasing water to air flow ratio in a humidifier leads to a lower production rate. The predicted effects of the parameters on ...
2009-01-01
Room-temperature magnetic properties of oxy- and carbonmonoxyhemoglobin
UK PubMed Central (United Kingdom)
The magnetic susceptibility and the density of human oxy-(HbO2) and carbonmonoxyhemoglobin (HbCO) solutions of various concentrations have been measured at room temperature, with pure water...Full Text Available
1978-10-01
Designer himself throws light upon high-temperature reactor
Energy Technology Data Exchange (ETDEWEB)
THe high-temperature reactor is one of the alternatives for the now predominantly employed water-reactors. In a recently published book designer Rudolf Schulten outlines his concept. In this article the book is reviewed. (author). 1 ref.; 1 fig.
1990-04-01
Designer himself throws light upon high-temperature reactor
International Nuclear Information System (INIS)
THe high-temperature reactor is one of the alternatives for the now predominantly employed water-reactors. In a recently published book designer Rudolf Schulten outlines his concept. In this article the book is reviewed. (author). 1 ref.; 1 fig.
Carboxymethylation of peat in 2-propanol
British Library Electronic Table of Contents (United Kingdom)
The effects of the time and temperature of alkaline pretreatment and the time and temperature of the carboxymethylation of peat in 2-propanol on the concentration of carboxymethyl groups and the solubility of the resulting products in water and an aqueous alkali solution were studied. The viscosity characteristics of the aqueous and aqueous alkaline solutions of peat carboxymethylation products were studied.
2011-01-01
When and how to reactivate the activated charcoal?; Quand et comment regenerer le charbon actif?
Energy Technology Data Exchange (ETDEWEB)
The activated charcoal is very appreciates for the water treatment. It do not generate by-product of treatment. In return it is saturated after some time and may releases pollutant compounds. When and how to get to its regeneration?.
2000-03-01
Energy saving self-powered industrial dehumidifier
Energy Technology Data Exchange (ETDEWEB)
An energy saving self-powered industrial dehumidifier for use in a building having a tap water conduit leading from a source of supply to utilization points is described comprising: a dehumidifying apparatus positioned in a stream of air to be dehumidified in the building. The dehumidifying apparatus comprising conduit means for diverting at least a portion of a relatively continuously moving stream of tap water from the tap water conduit through a heat exchanger positioned in a stream of air and returning the diverted portion to the tap water stream upstream of the utilization points. Water vapor in the stream of air will condense onto the heat exchanger when the tap water has a temperature below a dew point temperature of the air stream, thereby dehumidifying the air stream.
1988-07-26
Two researchers, Tom Goreau of the Discovery Laboratory in Jamaica and Raymond Hayes of Howard University, claim that they have evidence that nearly clinches the temperature connection to the bleached corals in the Caribbean and that the coral bleaching is an indication of Greenhouse warming. The incidents of scattered bleaching of corals, which have been reported for decades, are increasing in both intensity and frequency. The researchers based their theory on increased temperature of the seas measured by satellites. However, some other scientists feel that the satellites measure the temperature of only the top few millimeters of the water and that since corals lie on reefs perhaps 60 to 100 feet below the ocean surface, the elevated temperatures are not significant.
1990-10-12
International Nuclear Information System (INIS)
Radiochemical results ("2"3"4U, "2"3"8U, "2"2"6Ra and "2"2"8Ra activities; "2"3"4U/"2"3"8U, "2"2"8Ra/"2"2"6Ra and "2"2"6Ra/"2"3"8U activity ratios) are reported for 31 drinking water samples collected from 8 wells, 12 hot mineral springs, 5 cold springs, and 6 tap water samples. Activities of the Ra isotopes were measured by gamma spectrometry using a low background and high efficiency well type germanium detector. The U isotopes were counted in an alpha spectrometer. The results show that "2"3"8U activity varies between 4.46 and about 308 mBq l"-"1 in wells, 0.59 and 17.88 mBq l"-"1 in hot springs, 2.19 and 3.21 mBq l"-"1 in cold springs, and between 2.5 and 15.70 mBq l"-"1 in tap water samples. "2"3"4U/"2"3"8U activity ratio is generally higher than 1 which is the equilibrium activity ratio value ...
Enzymatic reactions in non-aqueous media have been shown to be effective in carrying out chemical transformation where the reactants are insoluble in water or water is a byproduct limiting conversion. Ionic liquids, liquid organic salts with infinitesimal vapor pressure, are potentially useful alternatives to organic solvents. It is known that the thermodynamic water activity is an important variable affecting the activity of enzymes in non-aqueous solvents. This study investigated the influence of water activity on the esterification of geraniol with acetic acid in ionic liquid [bmim]PF6 catalyzed by immobilized Candida antarctica lipase B. The conversion of geraniol in [bmim]PF6 was significant although the reaction rate was slower than in organic solvents. The profile of initial reaction rate-water ...
2006-02-01
Temperature coefficient in D_2O moderated reactor (Wolsung Unit 1)
International Nuclear Information System (INIS)
The temperature coefficient has been investigated on the Wolsung nuclear power reactor, in which fuel is natural uranium dioxide and moderator heavy water. The numerical computations are carried out in terms of changes of the effective neutron multiplication factor with respect to fuel, moderator, and coolant temperatures. Those results are compared with the computed values of temperature coefficient based on the LATREP computer code. (author).
1977-01-01
Comparison of fuzzy control systems for hypothermal brain temperature regulation
British Library Electronic Table of Contents (United Kingdom)
The automatic control system for brain tissue temperature is studied theoretically for brain hypothermia treatment. In order to realize a human-friendly control mechanism, an automatic temperature regulation system is constructed to simulate brain hypothermia treatment by introducing a fuzzy algorithm for possible characteristic changes in patients. The brain temperature model is successfully realized to follow the desired temperature course automatically. The model reference fuzzy control of brain temperature based on water-cooling blankets is verified for clinical application to brain hypothermia treatments through various kinds of simulation experiment.
2007-01-01
Study of the mechanism of electrochemical hydrogen storage in nano-porous carbons
Energy Technology Data Exchange (ETDEWEB)
An efficient method of hydrogen storage in nano-porous carbons is its reversible sorption by electrochemical decomposition of a KOH water solution according to the following equation: C + xH{sub 2}O + xe{sup -} {yields} (CH{sub x}) + xOH{sup -} where (CH{sub x}) stands for the hydrogen inserted into the nano-porous carbon during charging and oxidized during discharging. Although various carbon materials have been investigated as hydrogen adsorbents, the information about the storage mechanism as well as the nature of the hydrogen/carbon interaction is still not sufficient. In order to extend the understanding of the process, carbon samples charged electrochemically were investigated by temperature programmed desorption (TPD). The nature of the hydrogen/carbon interaction was studied by electrochemical analysis at different temperatures. The TPD experiments consist of heating the samples from room ...
2005-07-01
Energy Technology Data Exchange (ETDEWEB)
The population masses in many coastal zones in Japan, and human activities are greatly effected. The representative water area is the Tokyo Bay. The population of the Tokyo Bay reaches 26 million at present, and a mass of organic substance and nutrient salt flow into it through rivers and sewage-treatment plants, etc. With the improvement of pollution source countermeasure and sewerage in the area, the inflow load to the Bay gradually decreases, but in the inner bay, red tide is generating in the summertime mainly. And, the anoxic water areas observed in bottom layer in summertime make large effects on the seafood. It is a large theme to clarify formation process of the anoxic water area and to solve this problem for the Tokyo Bay in the twenty-first century. In this paper, changes in water qualities and human activities and fundamental approach of ...
2000-01-05
Phytoplankton primary production in a eutrophic cooling water pond
Energy Technology Data Exchange (ETDEWEB)
The effect of longer ice-free periods on the seasonal variation and total annual values of phytoplankton primary production was considered along with the efficiency and productivity of the phytoplankton communities at different water temperatures by constant light. The studied pond, Vasikkalampi, is located in the town Jvyaskyla in central Finland. The pond is slightly eutrophic and its water is used for cooling purposes by a 35 MW thermal powerplant. The cooling water is taken in the middle of the pond and it returns as heated effluent to the northern part, near the surface, about 100 m from the intake pipe. This circulation and warming of the water keeps the pond open throughout the year except during the coldest weeks in the winter when some parts freeze over. The increase of the water temperature was not sufficient to be optimal for ...
1984-01-01
Energy Technology Data Exchange (ETDEWEB)
Numerous studies have investigated degradation of individual endocrine disrupting compounds (EDCs) in lab or natural waters. However, natural variations in water matrices and mixtures of EDCs in the environment may confound analysis of the treatment efficiency. Because chemical based analytical methods cannot represent the combined or synergistic activities between water quality parameters and/or the EDC mixtures at environmentally relevant concentrations ({mu}g L{sup -1}-ng L{sup -1}), bioanalytical assessments of residual estrogenic activity in treated water were used to evaluate the performance of the UV based advanced oxidation process for estrogenic contaminants in water. Four EDCs including estradiol (E{sub 2}), ethinyl estradiol (EE{sub 2}), bisphenol-A (BPA) and nonylphenol (NP) were spiked individually or as a mixture at {mu}g L{sup ...
2007-04-15
The controllability analysis of the purification system for heavy water reactors
International Nuclear Information System (INIS)
The heavy water reactor such as Wolsung No.1 and No.2 has a purification system to purify the reactor coolant. The control system regulates the coolant temperature to protect the ion exchanger. After the fuel exchanges of operating plant, the increase of the coolant pressure makes the purification temperature control difficult. In this paper, the controllability of the control dynamics of the purification system was analysed and the optimal parameters were proposed. To reduce the effects of the flow disturbance, the feedforward control structure was proposed and analysed.
2001-10-01
Energy Technology Data Exchange (ETDEWEB)
This report discusses environmental surveillance activities conducted on the Nevada Test Site during the first calendar quarter of 1996. Surveillance activities included collection and analysis of air, noble gas, tritiated water vapor, and other water samples. Samples were analyzed for both radiological and non-radiological effluents.
1996-11-01
Influence of O{sub 2} and N{sub 2}H{sub 4} on the ECP in high temperature water
Energy Technology Data Exchange (ETDEWEB)
The ECP of construction materials in the water steam circuits of power plants is influenced by many parameters, including: reactions of oxidants, such as O{sub 2} or dissolved copper species; and reactions of reducing species, namely N{sub 2}H{sub 4}. Electrochemical measurements were performed to clarify the role of hydrazine for the open circuit potential in water/steam circuits. Current density electrode potential curves of the electrochemical oxidation of hydrazine and the reduction of oxygen in aqueous solutions were measured as a function of temperature in the range from room temperature to approximately 260{degrees}C. The electrode materials used were platinum, gold and Alloy 800 mod.. In addition, corrosion potentials were measured in water containing oxygen or hydrazine.
1992-12-31
Exergy analysis of the solar multi-effect humidification?dehumidification desalination process
British Library Electronic Table of Contents (United Kingdom)
An exergy analysis method is presented of the solar multi-effect humidification?dehumidification desalination (HDD) process. Pinch technology is used in the humidification process to determine the maximum possible saturated air temperature and the temperature of water rejected from the unit, and then the dehumidification process to determine the temperature of water leaving from the heat exchanger. The formulae to calculate the exergy of water and saturated air are given. The solar plane collector is used. From exergy analysis, the solar collector has the lowest exergy efficiency; the HDD process has a lower exergy efficiency, and the water rejected has also a large exergy loss. The energy and exergy recovery rate of the desalination process is also lower. The solar multi-effect HDD proces...
2007-01-01
The possibility for formation of macro-cell corrosion in a liquid with low electrical conductivity
International Nuclear Information System (INIS)
The possibility of electrochemical corrosion of carbon steel at the rate of 3.25 x 10"-"5 A/cm"2 in water was examined under the conditions present during an accidental pipe rupture at the Mihama nuclear power plant: liquid conductivity, 7.5 #mu#S/cm; dissolved oxygen concentration, 5 ppb or less; pH 8.6#propor to#9.3; ferrous ion concentration, 20 ppb or less; temperature, 142 C. The corrosion rate of iron in a micro-cell with a dissolved oxygen reduction cathode was estimated to be only 1/400 of the preceding rate. On the other hand, that in a micro-cell with a hydrogen ion reduction cathode was estimated to be as high as 1/10 of the preceding rate, that is, 3.25 x 10"-"6 A/cm"2. Two important factors may have influenced the corrosion rate: the remarkable wall thinning, which must have been the direct cause of the rupture of the pipe, was located close to, and downstream from, an orifice; and, the water ...
2011-05-01
The objective of the study was the kinetic modeling of the effect of storage temperature on the quality and shelf life of chilled fish, modified atmosphere-packed (MAP), and osmotically pretreated with the addition of nisin as antimicrobial agent. Fresh gilthead seabream (Sparus aurata) fillets were osmotically treated with 50% high dextrose equivalent maltodextrin (DE 47) plus 5% NaCl. Water loss, solid gain, salt content, and water activity were monitored throughout treatment and treatment conditions were selected for the shelf life study. Untreated and osmotically pretreated slices with and without nisin (2 x 10(4) IU/100 g osmotic solution), packed in air or modified atmosphere (50% CO(2)-50% air), and stored at controlled isothermal conditions (0, 5, 10, and 15 degrees C) were studied. Quality assessment and modeling were based on growth of several microbial indices, total volatile nitrogen, ...
2010-05-01
International Nuclear Information System (INIS)
#gamma# spectroscopy methods have been applied to determine the effects of two freshwater benthic macroinvertebrates, on reworking of sediments and the transfer of solutes across the sediment-water interface. Natural lake sediments and overlying water were contained in temperature-regulated rectangular plastic cells. After addition of Stylodrilus (oligochaete worms) and Pontoporeia (crustacean amphipods) to these microcosms, the vertical distribution of Cs-137 (a tracer of particle transport) and Na-22 (a tracer of solute transport) were determined. In cells with Stylodrilus, the Cs-137 layer moved downward at a rate that decreased exponentially with time. In cells with Pontoporeia, Cs-137 activity was smeared downward in time owing to eddy diffusive mixing of sediments over a small range (1-2 cm). In cells without worms, the veneer of Cs active material remained at the interface ...
Activated charcoal for water treatment which has expected demands in many fields
Energy Technology Data Exchange (ETDEWEB)
The activated charcoal treatment in the field of the water treatment is applied to water supply, sewage, industrial water supply and industrial sewage, etc.. Its main treatment effects are (1) decolorization, (2) removal of odorous substance, (3) removal of organic material which is detected as COD or BOD, (4) removal of harmful substance, (5) removal of substance which could generate muddness and tarnish and (6) removal of organic material which affects the succeeding high degree treatment badly, etc.. Many actual application examples in the above fields have been reported. As the most recent topic, a big amount of the demand of activated charcoal is expected in the treatment of water supply. Chlorine which is used as disinfectant during the water purification process generates organic halogen compounds such as trihalomethane through the ...
1988-10-01
Thermogalvanic effects on the pitting corrosion of water-cooled heat exchangers
Energy Technology Data Exchange (ETDEWEB)
Thermogalvanic corrosion of St3 steel in a temperature range from 25 to 50{degrees}C with a 3.84{degrees}C/cm gradient was studied in a neutral media flow. It is shown that the thermogalvanic effect on the pitting corrosion of water-cooled heat exchangers is decisive but dual. Depending on the composition of the cooling medium, thermogalvanic corrosion may either enhance (0.5 M NaCl) or inhibit (tap water) pitting corrosion.
1995-05-01
The building tomorrow and after..; Le batiment demain et apres-demain..
Energy Technology Data Exchange (ETDEWEB)
During its jubilee, the French building technical and scientific centre (CSTB) has organized a colloquium about the future tendencies of buildings evolution in the 20 forthcoming years: autonomy in energy production and wastes or effluents management, reduction of water consumption and management of water, hot water production and space heating, bio-sensors for the management of indoor air-quality, control of noise environment using active acoustic systems etc.. (J.S.)
1998-01-01
...INFORMATION Diarrhoeal disease Food safety and foodborne illness Enterohaemorrhagic Escherichia coli (EHEC) Cholera WHO PROGRAMMES AND ACTIVITIES Child and Adolescent Health and Development (...FOS) Initiative for Vaccine Research (IVR) TECHNICAL INFORMATION Vaccine research: diarrhoeal diseases Cholera Water-related diseases Household water treatment and safe storage WHO Global Salm-Surv ...PUBLICATIONS Diarrhoea: child and adolescent health Diarrhoea: cholera RELATED TOPICS - Child health - Water - Food safety - Cholera - Travel - Breastfeeding ...
Lamp system for uniform semiconductor wafer heating
Energy Technology Data Exchange (ETDEWEB)
A lamp system with a very soft high-intensity output is provided over a large area by water cooling a long-arc lamp inside a diffuse reflector of polytetrafluorethylene (PTFE) and titanium dioxide (TiO.sub.2) white pigment. The water is kept clean and pure by a one micron particulate filter and an activated charcoal/ultraviolet irradiation system that circulates and de-ionizes and biologically sterilizes the coolant water at all times, even when the long-arc lamp is off.
2001-01-01
British Library Electronic Table of Contents (United Kingdom)
Human activities in the karst Ozark Plateaus can impact water quality of springs where surface water is rapidly transferred to subsurface conduits. Bennett Spring, in southern Missouri, is the fourth largest spring in the state and supports local tourism activities. Questions regarding poorly functioning on-site wastewater systems (OWS) have raised concerns over the long-term water quality of the spring. This study reports the results of a surface water quality monitoring program in the recharge area where monthly samples were collected at base flow to identify potential pollution sources to the spring. Base flow hydrology of the recharge area was highly variable over the study period, which was drier than normal, causing an incomplete sampling record due to no flow conditions at some site...
2011-01-01
Temperature-induced opening of TRPV1 ion channel is stabilized by the pore domain
UK PubMed Central (United Kingdom)
SummaryTRPV1 is the founding and best-studied member of the family of temperature-activated transient receptor potential ion channels (thermoTRPs). Voltage, chemicals, and heat...Full Text Available
2010-06-01
Evolution of Thermal Response Properties in a Cold-Activated TRP Channel
UK PubMed Central (United Kingdom)
Animals sense changes in ambient temperature irrespective of whether core body temperature is internally maintained (homeotherms) or subject to environmental variation (poikilotherms). Here we show...Full Text Available
UK PubMed Central (United Kingdom)
Pseudomonas mandelii liquid cultures were studied to determine the effect of pH and temperature on denitrification gene expression, which was quantified by quantitative reverse transcription-PCR....Full Text Available
2009-06-01
UK PubMed Central (United Kingdom)
The purpose of this study was to examine relationships between weather and outdoor physical activity (PA). An online weather source was used to obtain daily max temperature [DMT], precipitation, and...Full Text Available
2011-02-01
Pore region of TRPV3 ion channel is specifically required for heat-activation
UK PubMed Central (United Kingdom)
Ion-channels can be activated (gated) by a variety of stimuli including chemicals, voltage, mechanical force or temperature. Whereas molecular mechanisms of ion-channel gating by chemicals and...Full Text Available
2008-09-01
Characterization of psychrotrophic microorganisms producing beta-galactosidase activities.
UK PubMed Central (United Kingdom)
Investigations of psychrotrophic microorganisms have been limited even though the dominant environment of the Earth is cold and enzymes with high activities at low temperatures could have commercial...Full Text Available
1994-01-01
Lithium-lead/water reaction experiments and analysis
Energy Technology Data Exchange (ETDEWEB)
An experiment has been performed to investigate the chemical reaction between the liquid phases of the eutectic lithium-lead (Li/sub 17/Pb/sub 83/) and water. The reactants and products were constrained within a closed reaction vessel, allowing the extent of reaction to be determined from the partial pressure of the hydrogen reaction product. The data from the tests showed that the extent of reaction did not depend upon the water temperature. The data also indicated that the extent of reaction passed through a maximum as the initial liquid metal temperature was varied from 350 to 500 C, and a model was developed to explain this behavior. 11 refs., 3 figs.
1988-01-01
Fluid temperature measurement technique by using Raman scattering
Energy Technology Data Exchange (ETDEWEB)
Temperature measurement technique by using Raman scattering was developed for the liquid water at temperature of 20 - 90 degree C and atmospheric pressure. Strong relationship between Raman scattering characteristics and liquid temperature change was observed. Various kinds of measurement techniques, such as Peak Intensity, Peak Wavelength, FWHM (Full Width at Half Maximum), PMCR ( Polymer Monomer Concentration RAte), TSIR (Temperature Sensitive Intensity Ratio), IDIA (Integral Difference Intensity Area) were tested. TSIR has the highest accuracy in mean error or 0.1 deg C and standard deviation of 0.1248 deg C. This report is one of the results in developing process of Raman temperature measurement technique. Next research step is to develop Raman temperature measurement technique at the high temperature and high ...
1999-06-01
International Nuclear Information System (INIS)
... calcium 47 combustion dry ashing high temperature labelled compounds lead
1972-04-10
... in full sun and in shade, using an infrared thermometer (MiniTemp Noncontact, Conrad Electronic, Nürnberg, Germany). Time intervals ... ...
Stream temperature is an important physical characteristic of headwater streams that plays a critical role in the presence and health of juvenile salmonids. Headwater stream temperature was documented in two geomorphic settings on the Kenai Peninsula, Alaska, focusing on the variation in temperature induced by diffuse groundwater discharge and variable air temperature. Eighteen headwater stream reaches were studied in four watersheds, with 11 drainageway sites and seven discharge-slope sites. In drainageway sites, low-gradient streams flow through broad valleys with groundwater-fed fen wetlands; in discharge-slope sites, high-gradient streams flow through narrow valleys with groundwater-fed slope wetlands. At all 18 sites, hourly stream temperatures were measured for one year. At one drainageway and one discharge-slope site, groundwater temperatures, stream ...
2010-12-01
Energy Technology Data Exchange (ETDEWEB)
Research activity during the 1991--1992 funding period has been concerned with the following topics relevant to carbon monoxide activation. (1) Exploratory studies of water gas shift catalysts heterogenized on polystyrene based polymers. (2) Mechanistic investigation of the nucleophilic activation of CO in metal carbonyl clusters. (3) Application of fast reaction techniques to prepare and to investigate reactive organometallic intermediates relevant to the activation of hydrocarbons toward carbonylation and to the formation of carbon-carbon bonds via the migratory insertion of CO into metal alkyl bonds.
1992-06-04
Studies relevant to the catalytic activation of carbon monoxide
Energy Technology Data Exchange (ETDEWEB)
Research activity during the 1991--1992 funding period has been concerned with the following topics relevant to carbon monoxide activation. (1) Exploratory studies of water gas shift catalysts heterogenized on polystyrene based polymers. (2) Mechanistic investigation of the nucleophilic activation of CO in metal carbonyl clusters. (3) Application of fast reaction techniques to prepare and to investigate reactive organometallic intermediates relevant to the activation of hydrocarbons toward carbonylation and to the formation of carbon-carbon bonds via the migratory insertion of CO into metal alkyl bonds.
1992-06-04
International Nuclear Information System (INIS)
In nuclear power plant Paks, Hungary, alkaline oxidative (NaOH, KMnO_4, H_2O) and acidic reductive (citric- and oxalic acid, water) liquids are using for the decontamination of primary circuit equipment (main liquid circulating pumps, steam generators, pipelines etc). The above mentioned decontamination liquids are containing "1"1"0"mAg, "9"5Nb, "5"4Mn, "5"8 Co, "6"0Co, "5"1 Cr, "1"2"4 Sb radioisotopes, summarized radioactivity is between 10"3-8x10"4 kBq/dm"3 liquid. The decontamination liquid can be cleaned with reactive adsorption (active carbon) and ion-exchange process at elevated temperature (333-368 K) in multilayered columns. After purification the summarized radioactivity for "5"4Mn, "6"0Co, and "1"1"0"mAg are in the outlet liquid below 1 kBq/dm"3. Decontamination factor DF#approx =#10"3-10"4, volumetric reduction factor VRF#approx =#50-500.
1999-11-04
Isotope separation of Ar, C, /sup 3/He, Kr, Ne, O, and Xe isotopes is reported. TiFeH/sub x/, TiCoH/sub x/, TiCuH/sub x/, and VH/sub x/ were studied using NMR (proton relaxation times). VD/sub x/ and VT/sub x/ were synthesized. The problem of calculating the valence state of Pu is discussed. A series solution to the plutonium (N,H) characteristic equation is suggested. Shipments of /sup 231/Pa, /sup 230/Th, and /sup 229/Th are reported. Separation and processing of /sup 234/U are also reported. Theoretical methods were developed to calculate temperature distributions as functions of water flow rate in liquid thermal diffusion columns. Diffusion coefficients were measured from 300 to 1200/sup 0/K for Kr-Xe and Kr-Ar. New thermal diffusion factors are submitted for Ne-Ar.
1978-05-01
Environmental Research Database
ObjectivesThe overall objective of the proposal is to test the conclusions reached in a recent article by Magnani, Mencuccini et al (2007), in which we proposed for the first time that the Net Ecosystem Productivity (NEP) of forests of the temperate and boreal region does not depend on temperature or rainfall but, rather, on nitrogen deposition (Ndep) from the atmosphere. It is widely accepted that Ndep can increase forest C sequestration, however the results from our 2007 paper reported a sensitivity dC/ [continued...]DescriptionCombustion of fossil fuels and use of fertilisers in agriculture has increased the amount of nitrogen compounds present in the atmosphere and the biosphere. More atmospheric nitrogen is converted into reactive nitrogen by anthropogenic activities than by all natural processes combined. This phenomenal historical increase in nitrogen deposition is responsible for several serious environmental problems, such as soil ...
2014-01-31
Energy Technology Data Exchange (ETDEWEB)
Introduced herein is microwave irradiation for the adsorption and desorption of environmental pollutants. Microwaves may be used in two ways, other than through elevation of temperature of a system as a whole with the adsorbent such as activated carbon serving as the heating medium. The first is the application by which desorption is caused to take place of specified molecules. For example, zeolite that has adsorbed water is regenerated when it is irradiated with microwaves in a stream of cooling gas. This is because only the moisture is heated since zeolite is a non-carbon adsorbent that absorbs microwaves but a little. Another case is reported in which microwaves are utilized to desorb H2S, H2O, CO, etc., from molecular sieves. In the second application, coexisting materials different in absorptivity are exposed to irradiation. The adsorption of microwave-absorbent materials is inhibited while that of the others is ...
1997-01-25
3-dimensional observations of atmospheric variables during the field campaign COPS
Energy Technology Data Exchange (ETDEWEB)
The Convective and Orographically-induced Precipitation Study (COPS) has the aim to advance the quality of forecasts of orographically-induced precipitation in complex terrain. COPS is a Research and Development Project of the World Weather Research Program and considered to be one of the largest field campaigns on quantitative precipitation forecasting that has been performed so far. A network of state-of-the-art active and passive remote sensing systems was combined with in total 10 airborne platforms, Meteosat rapid scans and dense networks of standard meteorological instruments during the three months long field phase (June-August, 2007) in south-western Germany/eastern France to observe atmospheric variables in the three spatial dimensions and in time. By the University of Hohenheim, two novel ground-based mobile scanning lidar systems were deployed: a scanning rotational Raman lidar which provides combined measurements of the field of atmospheric ...
2008-05-01
Recovery of Water from Boiler Flue Gas
Energy Technology Data Exchange (ETDEWEB)
This project dealt with use of condensing heat exchangers to recover water vapor from flue gas at coal-fired power plants. Pilot-scale heat transfer tests were performed to determine the relationship between flue gas moisture concentration, heat exchanger design and operating conditions, and water vapor condensation rate. The tests also determined the extent to which the condensation processes for water and acid vapors in flue gas can be made to occur separately in different heat transfer sections. The results showed flue gas water vapor condensed in the low temperature region of the heat exchanger system, with water capture efficiencies depending strongly on flue gas moisture content, cooling water inlet temperature, heat exchanger design and flue gas and cooling water flow rates. Sulfuric acid ...
2008-09-30
Energy Technology Data Exchange (ETDEWEB)
Sigma 1) examines ways to reduce the number of breakdowns of pressure-regulating stations and to minimize the energy consumed in warming the gas, 2) determines the optimal gas temperatures upstream from the pressure reduction, and 3) shows the dependence of energy consumption upon the water dewpoint. The method of calculating the optimal input temperature relies on Mollier's diagram. Tables and nomographs for natural gas and water dewpoint at 19/sup 0/F and 580 psi (-7/sup 0/C and 4 MPa) are useful in achieving the desired gas temperatures. Heating the regulators' control valves is important.
1982-04-01
Energy Technology Data Exchange (ETDEWEB)
A cooling system for rejecting waste heat consists of a cooling tower incorporating a plurality of coolant tubes provided with cooling fins and each having a plurality of cooling channels therein, means for directing a heat exchange fluid from the power plant through less than the total number of cooling channels to cool the heat exchange fluid under normal ambient temperature conditions, means for directing water through the remaining cooling channels whenever the ambient temperature rises above the temperature at which dry cooling of the heat exchange fluid is sufficient and means for cooling the water. 5 figs.
1980-01-22
Comparison of temperature and humidity profiles with elastic-backscatter lidar data
Energy Technology Data Exchange (ETDEWEB)
This contribution analyzes elastic-backscatter lidar data and temperature and humidity profiles from radiosondes acquired in Barcelona in July 1992. Elastic-backscatter lidar data reveal the distribution of aerosols within the volume of atmosphere scanned. By comparing this information with temperature and humidity profiles of the atmosphere at a similar time, we are able to asses de relationship among aerosol distribution and atmospheric stability or water content, respectively. Comparisons have shown how lidar`s revealed layers of aerosols correspond to atmospheric layers with different stability condition and water content.
1995-04-01
A water calorimeter for high energy x-rays and electrons
The current primary standards at NPL for the measurement of absorbed dose to water in high energy photon and electron beams are graphite calorimeters. However, the quantity of interest in radiation dosimetry is absorbed dose to water. Therefore, a new absorbed dose to water standard based on water calorimetry has been developed for use in high energy photon and electron beams. The calorimeter operates at 4 deg C, with temperature control being provided by liquid cooling. The sealed glass inner vessel of the calorimeter was designed to minimise the effect of non-water materials on the measurement of absorbed dose. The temperature sensing thermistor probes were designed and constructed so that glass is the only material in contact with high purity water inside the vessel. Initial measurements of absorbed dose to ...
2000-01-01
Enthalpy relaxation properties of the ethylene glycol (EG) aqueous solutions confined within silica-gel void spaces of 1.1 nm in the average void thickness and 6, 12 and 52 nm in their average diameters were examined by an adiabatic calorimetry to understand the glass transition behavior of the solutions and the rearrangement processes of the molecules. The glass transition temperature Tg of EG was found to decrease with adding the water molecules which are mobile under the condition lacking in the full hydrogen-bond network. Meanwhile, the Tg in the water-rich region showed a rise towards pure water; after a phase separation in a 25 mol% (x = 0.25) EG solution, the Tg was 160 K which was higher than that derived by extrapolating the composition dependence to pure water. The Tg = 160 K is the same as observed in the pure water confined within 1.1 nm voids; this ...
2008-02-01
Environmental data for sites in the National Solar Data Network
Energy Technology Data Exchange (ETDEWEB)
The Detartment of Energy's National Solar Data Program established solar energy systems in residential and commercial buildings across the United States. These solar sites are linked to Vitro Laboratories Division's computer in the National Solar Data Network (NSDN). Vitro collects and analyzes data from this network to determine the thermal performance of each of the solar systems. Environmental information collected at the sites for the month of August 1980 is presented. The environmental data for the NSDN are presented in the form of tables for each solar site. The solar sites are grouped into 12 zones, each of which consists of several adjacent states. The solar energy sites are in alphabetical sequence within each zone. The tables provide available meteorological data for reporting sites in the NSDN as follows: (1) Insolation: the insolation table presents the total, diffuse, direct, maximum, and extra-terrestrial radiation for the solar site. It also shows the ...
1980-08-01
International Nuclear Information System (INIS)
Some of the Indian pressurized heavy water reactors (PHWRs) which use Stellite balls in the ball and screw mechanism of the adjustor rod drive mechanism in the moderator circuit have encountered high radiation fields in the moderator system due to "6"0Co. Release of particulate Stellite is responsible for the hotspots in addition to the general uniform contamination of internal surfaces with "6"0Co. Extensive laboratory studies have shown that it is possible to dissolve these Stellite particles by adopting a three-step redox process with permanganic acid as the oxidizing agent. These investigations with inactive Stellite in powder form helped to optimize the process conditions. Permanganic acid was found to have the highest dissolution efficiency as compared to alkaline and nitric acid permanganate. The susceptibility of Stellite to corrode or dissolve was found to depend on the concentration of the permanganate, pH and temperature of the ...
2011-06-01
Uptake of atmospheric tritium by market foods
Energy Technology Data Exchange (ETDEWEB)
In this paper uptake of tritium by market foods from tritiated water vapor in the air is investigated using cereals and beans purchased in Deep River, Canada. The concentrations of tissue free water tritium (TFWT) and organically bound tritium (OBT) range from 12 to 79% and from 10 to 38% respectively, of that estimated for atmospheric water vapor of the sampling month. The specific activity ratios of OBT to TFWT were constant for cereals, but variable for beans. The elevated OBT was shown to be the result of isotopic exchange of labile hydrogen by the fact that washing the foods with tritium free-water reduced their tritium contents to levels characteristic of their production sites.
1992-03-01
The protective role of ceramic filters against natural radioactivity of water
International Nuclear Information System (INIS)
The paper presents results of measurements of the natural radioactivity of tap water where samples were taken in front of, and behind the ceramic filter commonly used in houses for the purification of tap water. Altogether, 289 samples were taken, processed and measured during 1985-1986 in Kuwait. Results reveal the fact that ceramic filters reduce substantially the natural radioactivity in water (the 'gross' alpha activity reduced by the factor 2.18 #+-# 18%; the 'gross' beta by 1.53 #+-# 1.6%. (author).
The effects of variable hardness, pH, alkalinity, humics, and suspended clay on the chemical speciation of copper and its toxicity to fathead minnow larvae in Lake Superior water were investigated. Two proposed methods (toxicity factors and chemical speciation) for predicting LC50 values in specific natural waters from laboratory toxicity data and the average site specific values of general water quality parameters were evaluated. The accuracy of the cupric ion-selective electrode in determining CU/sup +2/ activities in ambient and chemically altered Lake Superior water was also determined.
1986-03-01
British Library Electronic Table of Contents (United Kingdom)
In this paper we provide a geochemical investigation on 34 groundwater samples in the Mt. Vulture volcanic aquifer representing one of the most important groundwater resources of the southern Italy pumped for drinking and irrigation supply. The present study includes the first data on the abundance and mobility of minor and trace elements and the thermodynamic considerations on water-rock interaction processes in order to evaluate the conditions of alkali basalt weathering by waters enriched in magma-derived CO2. The results highlight the occurrence of two hydrofacies: bicarbonate alkaline-earth and alkaline waters deriving from low-temperature leaching of volcanic rocks of Mt. Vulture, and bicarbonate-sulfate-alkaline waters (high-salinity waters) related to prolonged water circulation in...
2011-01-01
Non-catalytic and catalytic wet air oxidation of pharmaceuticals in ultra-pure and natural waters
British Library Electronic Table of Contents (United Kingdom)
A wet air oxidation (WAO) process was applied to four selected pharmaceuticals (metoprolol, naproxen, amoxicillin, and phenacetin) individually dissolved in ultra-pure water, varying the temperature and oxygen pressure. Due to the moderate (amoxicillin) or low (metoprolol, naproxen, and phenacetin) efficiency found in the oxidation of these pollutants, a catalytic wet air oxidation (CWAO) process was then tested using a platinum catalyst supported on multi-walled carbon nanotubes (CNT). In this CWAO process, the pharmaceuticals were dissolved together in ultra-pure water and in four natural water matrices-a reservoir water, a groundwater, and two waters from different municipal wastewater treatment plants. On the basis of the measurements of their removals, a discussion is given of the inf...
2011-01-01
Sorption of gold by activated charcoal from cyan-containing solutions of complex salt composition
Energy Technology Data Exchange (ETDEWEB)
An evaluation was made of the effectiveness of the action of reagents used for cleaning cyan-containing waste water for conditioning of the overflow of copper concentrate thickners of the Belousovskiy enrichment before sorption extraction of gold by activated charcoal. It was established that conditioning of the overflow by iron sulfates (II), copper and zinc diminshes, and by hypochlorite increases the capacitance of the activated charcoal for gold.
1982-01-01
Method for the elimination of simple organic compounds by filtration on activated-charcoal particles
Energy Technology Data Exchange (ETDEWEB)
The use of filters of activated-charcoal particles in drinking-water purification plants assists in the elimination of organic micropollutant substances. The authors report on a study which sought to investigate the mechanism of organic matter; they describe the experimental programme, which used different size ranges of mineral-based activated charcoal, present the experimental findings and discuss the results. 16 references.
1984-12-01
Energy Technology Data Exchange (ETDEWEB)
Water from small scale purification plants is a low cost alternative for consumers in comparison to the bottled commercial presentations. Because of its low cost per liter, the consumption of this product has increased in recent years, stimulating in turn the installation of purification systems for these small businesses. The purpose of this study was to estimate the efficiency of small scale purification systems located in the cities of Zacatecas and Guadalupe, Zacatecas, to reduce the radioactive content of water. It was measured the total alpha and beta activity in water samples of entry and exit to process, through the liquid scintillation technique. In general it was observed that the process is more efficient in removing alpha that beta activity. The fraction of total alpha activity removed varied between 27 and 100%, while between 0 and 77% of the total ...
2009-10-15
International Nuclear Information System (INIS)
The construction materials used in coolant systems in nuclear power plants become covered with oxide films as a result of exposure to the aqueous environment. The susceptibility of the materials to different forms of corrosion, as well as the extent of the incorporation of radioactive species on the surfaces of the primary circuit, are greatly influenced by the physical and chemical properties of these oxide films. The composition and characteristics of the oxide films in turn depend on the applied water chemistry. This work was undertaken in order to collect and evaluate the present views on the structure and behaviour of oxide films formed on iron- and nickel-based materials in aqueous environments. This survey should serve to recognise the areas in which more understanding and research effort is needed. The review begins with a discussion on the bulk oxides of iron, nickel and chromium, as well as their mixed oxides. In addition to bulk oxides, the structure and ...
2010-03-01
Energy Technology Data Exchange (ETDEWEB)
Products having balanced melting point and decomposition temperature have been developed by employing nylon 6T fundamental molecular structure and selected copolymer components, Arlen being one of the products. It has heat resistance as good as that of super-engineering plastics, low water absorption, and excellent cost-performance which can be used for normal injection molding machines. The unit price per kilogram is low when its high heat resistance is taken into consideration. The coefficient of water absorption is as low as about 1/3 of that of nylon 66, and it can be considered to be a low water absorbing amide. The molding temperature is from 320[degree]C to 350[degree]C, the decomposition temperature is 395[degree]C at 2% weight decreasing temperature, and normal injection molding can be employed. It has excellent soldering ...
1994-05-01
Studies on water treatment by adsorption. Kyuchaku ni yoru mizushori
Energy Technology Data Exchange (ETDEWEB)
This paper summarizes studies on the water treatment by adsorption, as for the adsorption during water treatment, reactivation of activated charcoal, and clarification of heating process. Reactivation of activated charcoal for the water treatment is carried out through drying in the heating furnace. Basic problems are the recovery degree of adsorption performance of reactivated activated charcoal and the recovery yield. Behavior of the activated charcoal in the heating reactivation furnace is divided into three stages including drying process, heating process, and gasification process. Among these processes, behaviors of organic matters during heating process are described. Thermogravimetric analyses (TGA) were conducted for activated charcoals adsorbing various organic matters in aqueous solutions. Three types of ...
1994-06-05
Energy Technology Data Exchange (ETDEWEB)
The partial oxidation of 1,3-butadiene has been investigated over VMoO catalysts synthesized by sol-gel techniques. Surface areas were 9-14 m{sup 2}/g, and compositions were within the solid solution regime, i.e. below 15.0 mol % MoO{sub 3}/(MoO{sub 3} + V{sub 2}O{sub 5}). Laser Raman Spectroscopy and XRD data indicated that solid solutions were formed, and pre- and post-reaction XPS data indicated that catalyst surfaces contained some V{sup +4} and were further reduced in 1,3-butadiene oxidation. A reaction pathway for 1,3-butadiene partial oxidation to maleic anhydride was shown to involve intermediates such as 3,4-epoxy-1-butene, crotonaldehyde, furan, and 2-butene-1,4-dial. The addition of water to the reaction stream substantially increased catalyst activity and improved selectivity to crotonaldehyde and furan at specific reaction temperatures. At higher water addition concentrations, furan ...
2002-05-27
British Library Electronic Table of Contents (United Kingdom)
The agricultural sector is probably the one that will suffer most directly from the climatic variations expected at the global level. In particular, the analysis of the changes expected in water availability and demand is fundamental in order to correctly establish both the present water resource management and the definition of new strategies. In this paper the time series of some climatic and agro-climatic indices in the Region of Umbria (Central Italy) have been analyzed with the aim of finding signs of climate changes and identifying the potential impacts on the agricultural water balance. The aforesaid indices include the precipitation, the mean maximum and minimum temperatures (Tmin, Tmax), the mean temperature range (DT), the reference evapotranspiration (ET0) and two drought indice...
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
The liquid/vapor coexistence density, the partial vapor pressure, and the heat of vaporization were calculated using Gibbs ensemble Monte Carlo simulation techniques. Long-range interactions such as charge-charge, charge-dipole, and dipole-dipole were evaluated using Ewald summation techniques. A polarizable potential model was used to describe the water-water interactions (Dang and Chang, J. Chem. Phys. 106, 8149, 1997). The model yields good agreement with the corresponding experimental data in the lower temperature region and moderate agreement in the higher temperature region. The critical temperature and density were estimated to be 565 K and 0.28 g/cm3.
2001-12-01
Estimation of dry rubber content in natural rubber latex by differential scanning calorimetry
British Library Electronic Table of Contents (United Kingdom)
Differential Scanning Calorimetry (DSC) is employed to study the changes in enthalpy of natural rubber latex samples when heated under a controlled temperature program. It is found that the mass normalized areas of the DSC curves between room temperature and 170??C for different latex samples are inversely proportional to the dry rubber content (DRC) of the samples, measured following the weighing and drying method. The changes in total enthalpy of the samples in this temperature range are interpreted as due to the variations in the quantity of water present in the samples. The measurements have been repeated by diluting selected samples with known quantities of water, and it is found that the normalized areas of the DSC curves are directly proportional to the amount of water added to the ...
2010-01-01
Water demand management in areas of ground water over-exploitation
Environmental Research Database
SummaryIntended Outputs: Identification and evaluation, using participatory approaches, of demand management options:*Technical*Allocative and market based*Impact on target beneficiariesSupporting measures required when introducing water demand management options above:*Extension services & training*Water licences/rights*Institutional changes*Legal measures and regulation*Education*Support in diversifying to less water demanding activities*S [continued...]ObjectivesIdentification of the most appropriate demand management strategies for ground water abstraction, where aquifiers are being over-exploited, ensuring sustainable livelihoods of the vulnerable and poor are safeguarded. Poverty reduction strategies for areas where groundwater is being over-exploited.DescriptionProject Background: Groundwater is the principal source of both irrigation and domestic ...
2006-01-15
British Library Electronic Table of Contents (United Kingdom)
The coastal ecosystem health assessment is a field of increasing importance. In this paper, a preliminary assessment of ecosystem health in Zhejiang coastal water zone was made, mainly based on remote sensing data and GIS technique. Its spatial and quantitative evaluation was facilitated by the progress of remote sensing and GIS technique development. Firstly, human activities, hydrology and ecosystem problems in the study area were discussed and analyzed. Secondly, from 4 aspects of human stress, physical, chemical and biological responses to anthropogenic activities and natural stress, several indicators such as water transparency (Secchi Disk Depth, SDD), suspended substance concentration, dissolved inorganic nitrogen, active phosphate, chlorophyll, harmful algae bloom, as well as distr...
2010-01-01
Method of manufacturing diffusion oxygen or air carbon electrodes
Energy Technology Data Exchange (ETDEWEB)
Part of the crushed activated charcoal (about 20-50%) designed for manufacture of electrodes is made water repellant with the help of an aqueous suspension of water repelling agent containing 3-15% (preferably 10%) dry substance. After this the remaining part of the activated charcoal and the other additives are mixed with the water repelling part. The plates or tape which is rolled to an assigned thickness are pressed from the obtained mixture. The electrodes obtained by this method have a thin active layer and a porous structure and have good diffusion properties. They can be loaded by currents up to 80 mA/cm/sup 2/ without causing excessive polarization losses, and their service life is greater than or equal to 100 h.
1981-12-31
Model for simulation of freezing and thawing processes in building materials
Energy Technology Data Exchange (ETDEWEB)
This paper presents a mathematical model for simultaneous heat and moisture transfer under freezing-thawing in porous hygroscopic material. Even below O{sup o}C, unfrozen liquid water exists in the material which plays an important role in the processes. The model takes into account the existence of unfrozen liquid water. The system is treated as a three-(gas, liquid and solid) phase system of water. Moisture chemical potential is used as a moisture potential. Under freezing, moisture chemical potential is a unique function of local temperature. So, during freezing, two unknown variables to be solved are solid water content and moisture potential or temperature. A simple example of simulation for freezing processes is shown. (author)
2001-07-01
A novel process for extraction of natural sweetener from licorice (Glycyrrhiza glabra) roots
British Library Electronic Table of Contents (United Kingdom)
Pressurized hot water extraction (PHWE) is a very useful technique for recovering bioactive molecules from natural materials using subcritical compressed liquid water in the temperature range of 50-150degreeC. A novel process has been developed for making a natural sweetener from licorice (Glycyrrhiza glabra) roots involving selective chemical reaction and easy separation, for recovering mono-ammonium glycyrrhizate (MAG) using hot water with dissolved ammonia and pressurized with carbon dioxide. The performance of the novel PHWE process has been evaluated to ascertain the optimum process parameters to maximize the recovery of MAG by varying the parameters, such as temperature (30-120degreeC), pressure (1-10atm), extraction time (60-120min), water-to-feed ratio (20-40ml/g), number of stages...
2008-01-01
Water resources management in Asia. Volume 1. Main report. World Bank technical paper
Energy Technology Data Exchange (ETDEWEB)
The report, Water Resources Management in Asia, has three objectives: To describe the situation confronting the region's borrowers, devise approaches to better deal with the present and future water related problems that affect their well-being and equip the staff to actively participate in the regional and Bank-wide efforts to strengthen the sector. The principal water resources problems and issues have been placed in four categories: Institutional, long-term management and planning, real-time management and operations, and financial. Such an arrangement provides a perspective for examining concerns across all economic sectors and allows formulation of solutions that will constitute a truly comprehensive, balanced approach to the critical situation encountered in managing these resources. A summary of past Bank activities has confirmed that an historic approach is not ...
1993-01-01
Surface activity and water repellency properties of cleavable-modified silicone surfactants
British Library Electronic Table of Contents (United Kingdom)
A series of cleavable water-soluble silicone surfactants were prepared by the reaction of a hydroxyl-terminated polyester and an organopolysiloxane. Cleavable surfactants can decompose into water-insoluble moiety of silanol and two water-soluble products under acidic conditions, whereas these compounds are stable under neutral or alkaline conditions. The structure change of theses cleavage products are confirmed by IR and UV spectra analysis. The fundamental surface activity including surface tension, foaming, contact angle and viscosity are studied. The photocatalytic degradation of modified silicone surfactants with UV light over titanium oxide was investigated. Experimental results have confirmed that products are slowly degraded by direct photolysis. However, the cleavable silicone sur...
2006-01-01
Photodestruction of explosives in process water
Energy Technology Data Exchange (ETDEWEB)
Photodestruction has received much attention in recent years. In particular, titanium dioxide (TiO{sub 2}) and ozonolysis have attained a position of prominence. These technologies hold promise for the destruction of trace amounts of aqueous high explosives that are generated by load and pack operations, as well as demilitarization activities. Currently this water is treated by passing through a bed of activated carbon. The carbon is then steam regenerated and reused, thus creating a second waste stream which must be disposed of, or the carbon is burned directly. Recent trends in environmental regulation have shown that this may not be a viable option for process water remediation in the future. This talk will discuss efforts to employ alternate aqueous treatment techniques that not only remove the explosives compounds but are able to transform the parent compound into carbon dioxide and ...
1995-12-31
Experimental and theoretical studies on humidification-dehumidification-desalination
Energy Technology Data Exchange (ETDEWEB)
The shortage of fresh water is increasing at alarming levels, even in temperate zones. Desalination of brackish and seawater is being considered as a solution to growing water demands. Seawater desalination can be accomplished through reverse osmosis, vapor compression, vapor absorption and thermally driven systems. The most suitable process for large-scale desalination plants is successive brine evaporation-condensation with intermediate heat recovery. However, higher process efficiency could be achieved. The use of low temperature heat sources in seawater desalination requires an efficient method of evaporation and condensation at relatively low vapor pressures. This could be achieved in a humidification-dehumidification process using circulated air to enhance evaporation of water. Simulation models, however, neglect either the heat of evaporation or the changes in air and water ...
2006-07-01
Energy Technology Data Exchange (ETDEWEB)
The present paper explains the curve-fitting method developed as a method to estimate the geothermal equilibrium forming temperature. In the present method, that temperature is estimated by obtaining, by non-linear lest square, the model parameter to minimize the sum of remainders squared between the temperature actually measured after a lapse of certain time from the stoppage of mud water circulation and that calculated on the basis of Middleton model, mathematical model of temperature equilibrium well. In the Horner's plotting method currently in general use, temperature recovery data during a long period of about 120h are required for estimating the geothermal equilibrium forming temperature. However in the curve-fitting method, it is confirmed from the actual well data that the well recovery temperature is ...
1994-05-01
High temperature deformation behaviour of Ti-10V Alloy and associated activation energy
International Nuclear Information System (INIS)
High temperature deformation behaviour of an experimental Beta-titanium alloy Ti-10V has been studied in the temperature range 800 to 945 degree C by using the method of crosshead speed cycling. Although subgrain formation was observed but the alloy did not exhibit superplastic behaviour in the entire temperature range studied. A very large initial grain size and elongation of grains during the deformation are considered the main factors responsible for absence of superplastic behaviour. The activation energy values for regions II and III of the ln sigma vs. ln small epsilon plots are close to the lower of the two activation energy values proposed together to describe self diffusion in beta-phase suggesting that the rate controlling mechanism is that for lattice diffusion rather then grain boundary diffusion. (author)
2004-06-01
Energy Technology Data Exchange (ETDEWEB)
Activated charcoal was produced from sawdust of Pinus caribaea var. caribaea, pinus caribaea var. honduenais and pinus cocarpa, with the objective of studying a alternative of more economic uses for forest residues and the products of the first thinning. A chemical process was utilized based on Zn Cl{sub 2} at temperature of 700 deg C and 450 deg C. It was concluded that the temperature of 700 Celsius produced a activated charcoal with better quality and greater adsorption capacity. The temperature of 450 deg C produced a material with adsorption properties for utilization where greater adsorption capacity is not needed. The production of activated charcoal is possible from the three species of tropical pinus studied. (author). 16 refs., 5 tabs
1987-12-31
Chemical thermodynamics of silica: a critique on its geothermometer
Energy Technology Data Exchange (ETDEWEB)
The chemical thermodynamic concepts used in the calculation of solubility data of silica (quartz) are presented taking into account the PVT characteristics of water. The temperature-dependence trends between the thermodynamically calculated and the experimental quartz solubility data are very similar, but the values are widely different at high temperatures. The experimental solubility, especially along the saturation curve at high temperature and thermodynamic data for silica need to be reevaluated in order to use silica chemistry to understand geological processes. There could exist a wide range of values for silica solubility at a specified temperature, depending upon the amount of water in the reaction vessel. Thus the silica contents in geothermal fluid, in general, cannot be used as a geothermometer to estimate the reservoir ...
2000-06-01
Hydrothermal industrialization electric-power systems development. Final report
Energy Technology Data Exchange (ETDEWEB)
The nature of hydrothermal resources, their associated temperatures, geographic locations, and developable capacity are described. The parties involved in development, required activities and phases of development, regulatory and permitting requirements, environmental considerations, and time required to complete development activities ae examined in detail. These activities are put in proper perspective by detailing development costs. A profile of the geothermal industry is presented by detailing the participants and their operating characteristics. The current development status of geothermal energy in the US is detailed. The work on market penetration is summarized briefly. Detailed development information is presented for 56 high temperature sites. (MHR)
1982-03-01
Energy Technology Data Exchange (ETDEWEB)
The geothermal resources of the Green River basin were investigated. Oil-well bottom-hole temperatures, thermal logs of wells, and heat flow data have been interpreted within a framework of geologic and hydrologic constraints. Basic thermal data, which includes the background thermal gradient and the highest recorded temperature and corresponding depth is tabulated. It was concluded that large areas are underlain by water at temperatures greater than 120/sup 0/F. Although much of this water is too deep to be economically tapped solely for geothermal use, oil and gas wells presently provide access to this significant geothermal resource. Isolated areas with high temperature gradients exist. These areas - many revealed by hot springs - represent geothermal systems which might presently be developed economically. 34 refs., 11 figs., 8 tabs. (ACR)
1985-01-01
British Library Electronic Table of Contents (United Kingdom)
Summary There are many active functional compounds in citrus peels, such as flavonoid and phenolic acid. Scientists tried to obtain more bioactive components from citrus peels by various methods. This research investigated the effects of different drying temperatures (50, 60, 70, 80, 90 and 100-C) on changes in the flavonoid, phenolic acid and antioxidative activities of citrus fruit (Citrus sinensis (L.) Osbeck) peels. The total phenolic and flavonoid contents of drying treated orange peels were decreased by lower drying temperature (50 and 60-C) and increased by higher drying temperature (70, 80, 90 and 100-C). Amounts of phenolic compounds in the 100-C treated sample extract were significantly higher than the amounts in the samples heated at other temperatures (P-50 values of orange pee...
2011-01-01
Kinetics of uranium (VI) ions adsorption on activated charcoal from aqueous solutions
Energy Technology Data Exchange (ETDEWEB)
The temperature and concentration dependence of the kinetics of uranium(VI) ions adsorption onto activated charcoal from aqueous solutions has been studied. The adsorption proceeds via a rather fast stage followed by a slower one, with activation energies of 5.41 and 17.46 kJ . mol[sup -1] respectively. The diffusion of uranium ions into the pores of the activated charcoal controls the kinetics of adsorption which follows the Langmuir isotherm equation in the concentration range studied. The adsorption equilibrium constant k[sub c] has been derived at temperatures between 283 K and 323 K as well as [Delta] G, [Delta] H and [Delta] S. The results indicate that the adsorption of uranium ions on activated charcoal is an endothermic process. (orig.)
1994-01-01
International Nuclear Information System (INIS)
The important role of thyroid hormones in growth and development, maintenance of body temperature, digestion, cardiac function, and normal brain development can be disrupted by environmental contaminants like polychlorinated biphenyls (PCB). Polychlorinated biphenyls are environmental contaminants that are widespread, persistent, lipophilic, and bioaccumulate through food webs, concentrating in adipose tissue. Placental and lactational PCB exposure of offspring causes metabolic and endocrine disruptions including hypothyroxinemia, spatial learning and memory deficits, neurochemical and neurobehavioral alterations, and reproductive problems. Previous studies in our lab using the individual congeners PCB 47 (2,2',4,4'-tetrachlorobiphenyl, ortho-substituted) and PCB 77 (3,3',4,4'-tetrachlorobiphenyl, non-ortho-substituted) have demonstrated alterations in thyroid hormone levels, alterations in brain choline acetyltransferase (ChAT) activity, and ...
2004-10-15
Water diffusion profile measurements in epoxy using neutron radiography
International Nuclear Information System (INIS)
The diffusion characteristics of water in polymer materials have been studied for a few decades. Several methods have been developed to provide water diffusion characteristics as a function of time, temperature, pressure, or thickness of polymer. Unfortunately, most of these methods give the amount of water absorbed as a function of weight versus time at given environmental conditions. Concentration profiles of the water diffusion through the polymer have been unobtainable by these established methods. Neutron radiography is a method of non-destructive testing that has grown rapidly over the past ten years and is capable of giving these concentration profiles. Epoxy is one of the most commonly used polymers for which water diffusion information is important. In the automotive industry, epoxy is used both as a sealant and a bonder to prevent ...
International Nuclear Information System (INIS)
The guide describes a method acceptable to the NRC staff for complying with the Commission's regulations with regard to quality assurance requirements for installation, inspection, and testing of mechanical equipment and systems for water-cooled and high-temperature gas-cooled nuclear power plants.
British Library Electronic Table of Contents (United Kingdom)
In this work, chromatographic separation of niacin and niacinamide using pure water as the sole component in the mobile phase has been investigated. The separation and analysis of niacinamide have been optimized using three columns at different temperatures and various flow rates. Our results clearly demonstrate that separation and analysis of niacinamide from skincare products can be achieved using pure water as the eluent at 60^oC on a Waters XTerra MS C18 column, a Waters XBridge C18 column, or at 80^oC on a Hamilton PRP-1 column. The separation efficiency, quantification quality, and analysis time of this new method are at least comparable with those of the traditional HPLC methods. Compared with traditional HPLC, the major advantage of this newly developed green chromatography techniq...
2011-01-01
Characterizations of passive films formed on stainless steel in high temperature water
International Nuclear Information System (INIS)
Surface study techniques were used to investigate films on Type 304 stainless steel which were formed during exposure to high purity water at 288"0C. The results indicated that the film chemistry depended strongly upon the concentration of the dissolved O_2 in the water. Films formed in water having 8 ppm O_2 were stoichiometric mixed oxides; whereas those formed in water with 10 ppb O_2 were highly defective oxyhydroxides. The latter films are not as protective as the stoichiometric oxides. Auger electron spectroscopy (AES) and X-ray photoelectron spectroscopy (XPS) were used to investigate the films. (Auth.).
1983-06-03
Study of the mechanism of electrochemical hydrogen storage in nano-porous carbons
Energy Technology Data Exchange (ETDEWEB)
An efficient method of hydrogen storage in nano-porous carbons is its reversible sorption by electrochemical decomposition of a KOH water solution [1-3] according to the following equation: C + xH{sub 2}O + xe{sup -} {yields} (CH{sub x}) + xOH{sup -} where (CH{sub x}) stands for the hydrogen inserted into the nano-porous carbon during charging and oxidized during discharging. Although various carbon materials have been investigated as hydrogen adsorbents, the information about the storage mechanism as well as the nature of the hydrogen/carbon interaction is still not sufficient. In order to extend the understanding of the process, carbon samples charged electrochemically were investigated by temperature programmed desorpt(TPD). The nature of the hydrogen/carbon interaction was studied by electrochemical analysis at different temperatures. The TPD experiments consist of heating the samples from room ...
2005-07-01
British Library Electronic Table of Contents (United Kingdom)
In this paper we describe how cleavable surfactants decompose into water-insoluble silanols and two water-soluble products when subjected to vacuum plasma treatment. We used Raman spectroscopic analysis to confirm these structural changes, and we performed contact angle measurements and employed scanning electron microscopy to observe the surface morphologies of these compounds. Our contact angle measurements confirm that the products had degraded on nylon fabrics during argon gas plasma treatment. All of the PEG-silicone polyesters displayed excellent water-repellency; PEG6000-silicone exhibited the largest contact angle (130?) and, hence, the greatest water-repellency. Our results indicate that the silanols that form upon plasma treatment may be useful in coatings applications. We also f...
2006-01-01
International Nuclear Information System (INIS)
This study concerns the Souss upstream basin. The objective is to investigate the characteristics of surface water and groundwater, to assess the impact of artificial recharge as reinforcement of the natural replenishment and assess the renewal of groundwater under semi-arid area. Two major water types are observed: (i) surface waters and upstream springs (least mineralized) and (ii) all groundwater samples (prevailing calcium and magnesium bicarbonate water type). Water isotopes show a low evaporation of precipitations during infiltration. Impoverishment in heavy isotopes is the characteristic of mountain rainfalls, or of a climate colder and wetter than present. Carbon-14 activities (34-94 pmc) indicate a long residence time. The artificial recharge is low compared to the reservoir volume, due to which the renewal rate is also low.
2011-07-01
British Library Electronic Table of Contents (United Kingdom)
Banana (Musa acuminata Colla AAA) peel extracts obtained in this work had a high capacity to scavenge 2,2-diphenyl-1-picrylhydrazyl (DPPH) and 2,2prime-azino-bis(3-ethylbenzothiazoline)-6-sulfonic acid (ABTS+) free radicals, and they were also good lipid peroxidation inhibitors. Acetone:water extracts were considerably more effective (compared with methanol, ethanol, acetone, water, methanol:water or ethanol:water) at inhibiting the peroxidation of lipids in the b-carotene/linoleic acid system or scavenging free radicals. However, aqueous extracts had a high capacity to protect lipids from oxidation in the thiobarbituric acid reactive substances (TBARS) test, as well as in the b-carotene bleaching assay. In addition, acetone:water most efficiently extracted all extractable components (54+-...
2010-01-01
International Nuclear Information System (INIS)
The sampling is described for radionuclide X-ray fluorescence analysis. Aerosols are captured with various filter materials whose properties are summed up in the table. Fine dispersed solid and liquid particles and gaseous admixtures may be captured by bubbling air through a suitable absorption solution. The concentration of small amounts of impurities from large volumes of air is done by adsorbing impurities on surfactants, e.g., activated charcoal, silica gel, etc. Aerosols may be captured using an electrostatic precipitator and aerosol fractions may be separated with a cascade impactor. Water sampling differs by the water source, i.e., ground water, surface water, rain or waste water. Soil samples are taken by probes. (ES).
1983-12-01
UK PubMed Central (United Kingdom)
Micro-electrodes sensitive to Cl- have been used to measure Cl- activities in the mucous layer on the mucosal surface of an isolated oesophageal preparation of the fresh-water teleost, Phoxinus phoxinus...Full Text Available
1984-01-01
Phytoremediation Potential of Lead-Contaminated Soil Using Tropical Grasses
The global problem concerning contamination of the environment because of human activities is increasing. Most of the environmental contaminants are chemical by-products and heavy metals such as lead (Pb). Lead released into the environment makes its way into the air, soil and water. Lead contribute...
In this activity, learners light an LED with five cents. Learners use two different metals and some sour, salty water to create a cheap battery. Learners also have the option of checking the voltage of their battery if a voltmeter is available.
A novel reactor combining a flame-deposited nanostructured titanium dioxide film and a set of embedded ceramic electrodes was designed, developed and tested for degradation of methyl tert-butyl ether (MTBE) in water. On applying a voltage to the ceramic electrodes, a surface coro...
Annual Report for Gravity Collection Lysimeter Monitoring Plan - ERDF Cells 5 and 6
Energy Technology Data Exchange (ETDEWEB)
The data and analyses contained in this report reflect the initial characterization of construction and consolidation water in Cells 5 and 6 lysimeters. Therefore, the scope of this report will be to establish constituent levels and document dewatering activities completed to date.
2006-12-19
International Nuclear Information System (INIS)
The feasibility of immobilizing simulated radioactive slurry (SRS) by alkali-activated slag---clay minerals composite cement (AASCM) was studied under the experimental conditions. The results show that the dosage of SRS and water cement ratio (W/C) have significant effect on the flowability of the mixture of AASCM and SRS. The more dosage of SRS, the lower flowability. When cement/sand ratio is 1: 1 and W/C is 0.45, the flowability of the mixture meets the case of solidification engineering and the compressive strength of the waste forms containing 20% SRS meets the needs of GB 14569.1-93. The setting time of the mixture of AASCM and SRS is highly dependent on temperature while sorts of anions have little influence on it. The application of AASCM is suitable below 20 degree C. The leaching resistance of AASCM based waste forms is superior to that of OPC based waste forms. The control of the forms to Sr2+ is stronger than ...
2006-03-01
Mineralization of phenanthrene and fluoranthene in yardwaste compost
International Nuclear Information System (INIS)
PAH biomineralization measurements of yardwaste compost samples indicated heterogeneous distribution of active microorganisms and substantial sequestration of the non-polar substrate in the compost matrix. - The purpose of the study was to evaluate the potential of phenanthrene and fluoranthene biodegradation in yardwaste compost materials. These polynuclear aromatic hydrocarbons were chosen for this work because they are relatively readily biodegradable and ubiquitous in the environment. Compost samples were incubated in biometers with "1"4C-labeled phenanthrene and the evolution of "1"4CO_2 was assessed as a measure of mineralization. The "1"4CO_2 evolution varied widely among replicate biometers, possibly as the result of (1) uneven and patchy colonization of phenanthrene-degrading microorganisms on compost particles, and (2) non-uniform dispersion of the labeled substrate spike into the yardwaste microenvironment. Mineralization of phenanthrene reached about ...
2003-07-01
International Nuclear Information System (INIS)
High-intensity contact ultrasound (HICU) under MRI guidance may provide minimally invasive treatment of endocavitary digestive tumors in the esophagus, colon or rectum. In this study, a miniature receive-only coil was integrated into an endoscopic ultrasound applicator to offer high-resolution MRI guidance of thermotherapy. A cylindrical plastic support with an incorporated single element flat transducer (9.45 MHz, water cooling tip) was made and equipped with a rectangular RF loop coil surrounding the active element. The integrated coil provided significantly higher sensitivity than a four-element extracorporeal phased array coil, and the standard deviation of the MR thermometry (SDT) improved up to a factor of 7 at 10 mm depth in tissue. High-resolution morphological images (T1w-TFE and IR-T1w-TSE with a voxel size of 0.25 x 0.25 x 3 mm3) and accurate thermometry data (the PRFS method with a voxel size of 0.5 x 0.5 x 5 mm3, 2.2 s/image, 0.3 ...
2008-11-21
Boric acid effect in phenolic composites on tribological properties in brake linings
International Nuclear Information System (INIS)
In the present work, using a pad-on-disc-type wear tester, the tribological properties of the pad next to the disk made of cast iron were investigated with changing the substance of the components. As well, micro-structural characterisation of braking pads was performed using scanning electron microscopy and also temperature outcome of the pads was examined at the temperatures of 50-400 "oC in the pressure of 1050 and 3000 kPa. Finally, the effect of environment to the pads was studied in water, salty water, oil and braking liquid media.
Feasibility of creation of new markets for activated charcoal and its exploitation
Energy Technology Data Exchange (ETDEWEB)
The size of the market for pulverized activated charcoal and particulate activated charcoal prepared by the Association of Inorganic Chemicals of Japan is 55,000t/y (1987) in total. Individually, some fields showed the expansion such as water purification, water treatment and gas treatment on the one hand, but on the other hand, several fields showed the decline such as sugar refining, dextrin sugar and soda glutamate. As a whole, the market showed no marked fluctuations or a very slight increase. Many of the above usages are traditional in the chemical industry and the food industry, etc., and the new usages developed in the past several years have not grown to influence the statistics as yet. Selection of raw material is the key for determining the character of activated charcoal. And the factors of determining the characteristic features are fine pore, surface area and surface ...
1988-10-01
British Library Electronic Table of Contents (United Kingdom)
Activity concentrations of some anthropogenic radionuclides (90Sr, 137Cs, 238Pu, 239+240Pu and 241Am) have been measured in the surface of marine sediments along the Saudi coast of the Arabian (Persian) Gulf. The samples were collected at different locations and water depths. The spatial distribution of the concentrations of the measured radionuclides showed a heterogeneous pattern and is independent of location or water depth. The obtained results are discussed and some conclusions are drawn.
2007-01-01
Modeling of thermal and hydrodynamic aspects of molten jet/water interactions
Energy Technology Data Exchange (ETDEWEB)
In order to predict the effect of a fuel-coolant interaction after a hypothetical core-melt-down accident, a phenomenological model has been developed to describe the thermal and hydrodynamic behavior of a high-temperature molten jet when it interacts with saturated or subcooled water in a film boiling regime. The mechanisms of jet-material erosion were analyzed by Kelvin-Helmholtz instabilities on the coherent column and by boundary layer stripping on the leading edge. The heat transfer coefficient, vapor-film thickness, and net steam generation, all of which strongly affect the jet-breakup behavior, were solved analytically. It was found that the jet breakup (or erosion) depends strongly on the steam generation from the jet/water interaction. The jet-breakup length (i.e., penetration distance) was found to be sensitive to the initial jet temperature, water subcooling, and the ...
1989-01-01
Energy Technology Data Exchange (ETDEWEB)
12 kind of environmental samples such as soil, underground water, seawater, etc. around the Nuclear Power Plants(NPP) and surface seawater around the Korea peninsula were sampled, For the samples of rain, pine-needle, air, seawater, underground water, chinese cabbage, grain of rice and milk sampled around NPP, and surface seawater and rain sampled all around country, tritium concentration was measured, The tritium concentration in the tap water and the gamma activity in the domestic and imported beef that were sampled at ward in the large city in Korea(Seoul, Pusan, Taegu, Taejun, Inchun, Kwangju) were analyzed for the meat and drinking waters. As the results of analyzing, tritium concentration in rain and tap water were very low all around country, but a little higher around the NPP than general surrounding. At the Wolsung NPP, tritium concentration was descend ...
2001-12-15
Spattering and Crackle of Hot Cooking Oil with Water: A Classroom Demonstration and Discussion
Any student that has spent time in the kitchen knows that hot vegetable oil will pop and spatter violently after coming into contact with water such as that on the surface of foods (meat, fish, potatoes, etc.). This well-known effect can be used as an instructional resource to promote cooperative, active, and inquiry-based learning about central concepts of chemistry including boiling point, miscibility, and density of liquids. The starting point of the learning activity is a demonstration of (i) the effect of adding a drop of water to hot (as for cooking) vegetable oil and (ii) the effect of adding a drop of vegetable oil to hot water (near its boiling point). Intermolecular interactions, properties of vegetable oils, and a variety of other topics, such as the importance of other heat points (smoke, flash, and fire) for oils, the fundamental of the crackle test for checking the ...
2009-11-01
Energy Technology Data Exchange (ETDEWEB)
Ground water ranging in temperature from only 38/sup 0/ to 140/sup 0/F can supply a considerable amount of heat energy when couple with a geothermal or ground-water heat pump. The heat pump's method of operation is examined as well as its performance characteristics. (MHR)
1982-12-01
Energy Technology Data Exchange (ETDEWEB)
''Climates of the Oceans'' deals with the atmosphere over the world oceans and provides a treatment not only of the climatic elements such as temperature, pressure, wind, precipitation etc., but also of the circulation of the atmosphere and its changes throughout the year. The connection between sea and overlying air is examined through studies of the water and heat balance. Numerous maps and tables illustrate the elements and their fluctuations over the water and on islands and coasts.
1984-01-01
Cause analysis of cracks in circulating water culvert of Daya Bay Nuclear Power Station
International Nuclear Information System (INIS)
In view of the widespread cracks discovered in the reinforced-concrete circulating water culvert of Daya Bay Nuclear Power Station, cause analysis for the cracks is made in terms of construction and design. It is concluded that the cracks mainly resulted from shrinkage and temperature. Corresponding countermeasures are put forward thereafter for reference of similar projects
2000-06-01
The Performance Evaluation of a Hot Water Layer using a Numerical Simulation
International Nuclear Information System (INIS)
Most of all research reactors are immerged in the deep water pool to be a ultimate heat sink. At the neighbor of the reactor, some radio-active matters, such as Na-24, Ar-41, Mg-27, Al-28 and etc, may be generated by the neutron irradiation. Those radio-active isotopes may rise up to the pool water surface through the natural convection flow, which can make the radioactivity in the reactor hall rise high enough to concern about the health of people working in the reactor hall. When the irradiation test facilities are loaded or unloaded during a normal operation, the highly radio-activated primary coolant may flow out through the irradiation test holes on the top of the reactor. This also may be a main hazard source to make the working environment of the reactor hall bad. Making a hot water layer 1.5 ? 2.0 m thick at the top of reactor pool would be a good ...
2009-05-01
Formation of iron oxides during mechanical activation in water
International Nuclear Information System (INIS)
It has been shown that mechanical milling of iron in water results in formation of nanocrystalline magnetite Fe3O4 with an average particle size of 0.6 ?m, saturation magnetization of 77 Am2/kg and coercivity of ?150 A/cm. Along with magnetite, an antiferromagnetic Fe-O phase (?10 wt%), which is an aggregate of small iron-oxygen clusters forms.
2007-05-21
Energy Technology Data Exchange (ETDEWEB)
Contents of this report are under the following topical sections: Legal Authority; Summary and Scope; Data Collection Activities; Industry Description; Industry Subcategorization; Water Use and Wastewater Characterization; Pollutants Selected for Regulation; Pollution Prevention and Wastewater Treatment Technologies; Development of Control and Treatment Options; Costs of Technology Bases for Regulations; Pollutant Reduction Estimates; Non-Water Quality Impacts; Implementation of Proposed Effluent Limitation Guidelines and Standards; Analytical Methods; and Glossary.
1998-05-01
Conservation in the Arabian Gulf countries
In the Arabian Gulf region in general, and in Saudi Arabia in particular, demand for water in the agricultural, domestic, and industrial sectors has increased dramatically as a result of rapid development, and improved standard of living, and diversification of economic activity in agriculture and industry. This article presents an overview of supply and demand situations prevailing in the Arabian Gulf region and discusses various conventional and unconventional alternatives for meeting the growing demand for water. It also describes conservation measures and their socioeconomic effects.
1990-05-01
A method for making a drilling mud
Energy Technology Data Exchange (ETDEWEB)
A method is proposed for making a drilling mud, which includes mixing of an aqueous solution of a water soluble acrylic polymer with clay. It is distinguished by the fact that in order to reduce the corrosion activity of the clay solution, the dry clay is slaked in an aqueous solution of partially hydrolized polyacrylonitrile with the following component relationship (in percent by mass): clay, 3 to 10; hydrolized polyacrylonitrile, 3 to 5 and water, the remainder.
1983-01-01
A mathematical model for simulating shallow solar ponds for treatment of industrial wastewater
Energy Technology Data Exchange (ETDEWEB)
This paper presents a mathematical model to analyze the solar evaporation in a shallow pond in steady state, when the inlet flow rate, concentration, surface area and solar radiation are given. The simultaneous heat and mass transfer mechanisms are considered for quantifying the amount of evaporated water to the atmosphere and the actual absorbed heat by wastewater is calculated to obtain the bottom temperature of water pond. The heat losses to air by radiation and convection mechanisms are considered and the heat transmission across the water film is evaluated by the forced convection mechanism. 6 refs., 5 figs., 1 tab.
1996-12-31
International Nuclear Information System (INIS)
Design improvements are being incorporated into the heavy water management systems at Wolsong 2,3 and 4 to reduce the load on the vapour recovery driers and upgraders and the heavy water losses via the stack. There will also be improvements to monitor heavy water and tritium releases. This paper describes the improvements, gives background on heavy water balance mechanism, the historical trends for heavy water recovery/losses and estimated dose to the member of the public critical group resulting from the airborne and waterborne releases. The measured tritium activity levels in the heat transport system (HTS) and moderator system at Wolsong 1 are given. Using these activity levels and heavy water loss data, tritium losses from the dried and ventilated areas are estimated. A qualitative assessment of expected heavy ...
1994-03-01
Regulation of sucrose synthesis in water stressed leaves
Energy Technology Data Exchange (ETDEWEB)
Alteration in carbon metabolism and carbohydrate partitioning occur in drought stressed plants. Some species accumulate large quantities of starch in the chloroplast, which may be used to support sucrose synthesis under conditions of limited carbon supply. The authors monitored chemical partitioning of carbon between sugars and starch and the activity of sucrose phosphate synthase (SPS) and fructose 1,6 bisphosphatase (FBPase) in the source leaves of water stressed tomatoes. Plants were stressed by withdrawing water for 10 days and rewatered for recovery. Water potential dropped from {minus}0.8 to {minus}2.2MPA in 10 days, but recovered to control level 2 days after rewatering. Photosynthetic rates as measured by the activity of Rubisco followed similar patterns to those of water potential. After 10 days, leaf starch levels decreased to less than 50% of control. ...
1991-05-01
Reports of the Hokkaido National Industrial Research Institute, No. 63, March 1995
Energy Technology Data Exchange (ETDEWEB)
;Table of Contents: Gaseous Pollutants Emissions from Coal Combustors and Their Control Technologies in Japan; Simultaneous Determination of Cooper (II) and Iron (III) Using 8-Quinolinol by Solvent Extraction Flow-injection Method; Fundamental Studies on Red Mud as a Catalyst for Coal Liquefaction: Studies on Active Components in Red Mud and Possibilities for Improvement of Its Catalytic Activities; Elution Behavior of Coal-derived Liquids with Sephadex LG-20; Characteristic of Activated Carbon Produced from Scrap Tires at Different Activation Temperatures; Energy Saving Snow Melting System.
1995-03-01
Desorption of CO{sub 2} from MDEA and activated MDEA solutions
Energy Technology Data Exchange (ETDEWEB)
A packed column was used for investigating the desorption rate of CO{sub 2} from aqueous methyldiethanolamine (MDEA) and activated MDEA solutions. Experiments were conducted within the temperature range 30--70 C, the concentration of MDEA was 4.28 kmol/m{sup 3}, and the concentration of piperazine (PZ) was 0.10 kmol/m{sup 3} for aqueous activated MDEA solutions. Experimental data confirmed that the kinetics model of absorption CO{sub 2} into aqueous MDEA and activated MDEA solutions can be applicable to the situations in which desorption occurs, and the desorption rate of model predictions agree well with that of experimental determination.
1995-03-01
International Nuclear Information System (INIS)
Activation energy values for high temperature deformation of a beta -titanium alloy Ti-10V were determined from the flow stress strain rate data taken from the second increasing strain rate cycles, in order to find the rate controlling mechanism. Although the data obtained from first increasing strain rate cycles are considered most appropriated by the author in a previous study due to obvious reasons, the values obtained in present work are again indicative of lattice self diffusion in beta -phase as the rate controlling mechanism for this alloy and nevertheless suggest that two different activation energy values for a deformation process could be possible in a given temperature range, depending upon the data. (author)
2007-12-01
British Library Electronic Table of Contents (United Kingdom)
The heterogeneous solid catalyst, mercaptopropylsilica (MPS), has been prepared by a modified procedure in water and its structure confirmed by solid state carbon-13 CP-MAS NMR spectrum. This catalyst has been efficiently utilized for the synthesis of a wide variety of tri-, tetrasubstituted imidazoles and their bis-analogues at room temperature. The protocol was further explored for the synthesis of the drug trifenagrel.
2010-01-01
... The products can be categorised as glazed flat-plate collectors, evacuated glass-tube collectors, and unglazed plastic or low temperature collectors. Glazed flat-plate collectors and vacuum tubes are widely used for solar water heating and space heating systems in all types of buildings. Unglazed plastic collectors are used exclusively for lower temperature applications, such as outdoor swimming pools or the agrarian business. Flat-plate solar collectors are likely to ...
Energy Technology Data Exchange (ETDEWEB)
This bibliography contains citations concerning theoretical aspects and industrial applications of activated charcoal. Topics include absorption capacity and mechanism studies, kinetic and thermodynamic aspects, and properties descriptions and evaluations. Applications include utilzation in water analyses and waste treatment, air pollution control and measurement, and in nuclear facilities. (This updated bibliography contains 160 citations, 14 of which are new entries to the previous edition.)
1989-10-01
Energy Technology Data Exchange (ETDEWEB)
This bibliography contains citations concerning theoretical aspects and industrial applications of activated charcoal. Topics include absorption capacity and mechanism studies, kinetic and thermodynamic aspects, and properties descriptions and evaluations. Applications include utilization in water analyses and waste treatment, air pollution control and measurement, and in nuclear facilities. (This updated bibliography contains 150 citations, 14 of which are new entries to the previous edition.)
1988-11-01
ATP Hydrolysis in Eg5 Kinesin Involves a Catalytic Two-water Mechanism*?
UK PubMed Central (United Kingdom)
Motor proteins couple steps in ATP binding and hydrolysis to conformational switching both in and remote from the active site. In our kinesin·AMPPPNP crystal structure, closure of the active...Full Text Available
2010-02-19
British Library Electronic Table of Contents (United Kingdom)
A mechanism is proposed for the previously observed [1] jump in erythrocyte fluidity through a microcapillary 1.3 ?m in diameter at a temperature of 36.6?0.3?C. Our interpretation is based on the experimental evidence both for existence of ortho and para H2O isomers in water and on spin-selective interaction of proteins with para H2O isomers as hydration shells of biomolecules are being formed [2]. It is important that the formation of hydration shells of proteins and DNA in aqueous solutions is accompanied by an increase in the Brillouin shift to 0.4 cm?1 (?0.25 cm?1 in water), which points to the formation of icelike structures. We believe that the coincidence of the translational energy kT of the Brownian motion and the energy of the rotational quanta for the 313?202 transition of para ...
2009-01-01
Porcine pancreatic lipase immobilized on celite particles has been employed as a catalyst for the esterification of dodecanol and decanoic acid in a predominantly organic system. Solvent influence on the equilibrium position and on the catalyst activity has been studied using 20 solvents, including aliphatic and aromatic hydrocarbons, ethers, ketones, nitro- and halogenated hydrocarbons, and esters. The equilibrium constant for esterification correlates well with the solubility of water in the organic solvent, which in turn shows a good relationship with a function of Guttman's donor number and the electron pair acceptance index number of the solvent. This may be rationalized in terms of the requirements for solvation of water and of the reactants. The catalyst activity, measured as the initial rate of the esterification reaction, is best correlated as a function of both ...
1991-12-01
Conceptual fusion power monitor based on the "1"6O(n,p)"1"6N reaction
International Nuclear Information System (INIS)
The feasibility of developing a fusion power monitor based on a fluid activation detector is considered here. The activation fluid may be either a liquid or a gas and its composition can be selected from a number of candidate materials to provide desired activation and decay characterisitcs. Performance calculations indicate that ordinary water would be a nearly ideal activation fluid. The "1"6O(n,p)"1"6N reaction has a threshold at about 10 MeV and a cross section energy dependence giving it a predominant response for unmoderated D-T fusion neutrons. Adequate activation can be obtained at moderate flow rates for remote counting away from the high radiation area of the reactor. The 7.16 sec half-life of "1"6N is ideal for remote counting with subsequent decay in a small hold-up tank to eliminate activity build-up in the recycled ...
1981-07-01
[In vitro digestibility of a milk substitute produced with uncooked flour].
Milk substitutes are used for the breakfast of the recipients of the National School Feeding Programme in Chile. The major ingredients of milk substitutes are milk, sugar and cereal flours. The technical specifications to produce this type of food state, beside their proportions, that the flours must be precooked. This requisite is controlled by determining the gelatinization degree which must be 92% as a minimum. At present, a cheaper new alternative of milk substitute fabricated with uncooked flours and containing an enzymatic preparation has been presented to the Programme. It is postulated that when reconstituted in water under the manufacturer's directions (85 degrees C, 5 min settling time) precooking of the flours is reached. The objective of this work was to evaluate the in vitro digestibility, the effect of the enzymatic preparation (molecular size of starch and dextrose equivalent) and the degree of gelatinization of this product (MSE) when reconstituted ...
1996-12-01
International Nuclear Information System (INIS)
Containment is considered as ultimate safety system and is designed to enclose whole reactor system and prevent the spread of active air-borne fission products. For Pressure and Temperature calculation, Design Basis Accident (Dba) is double ended break of reactor inlet header or main steam line break but activity release studies are done to access its performance following limiting design basis accident i.e. Loss of Coolant Accident (LOCA) and Emergency Core Cooling System (ECCS). In such accident scenario, the core is severely damaged and results in production of steam and hydrogen along with release of activity to containment environment. Containment functions are maintained in such accident, and radiological consequences are within the prescribed limits. (author)
2005-12-01
Energy Technology Data Exchange (ETDEWEB)
The Coastal Zone Sector of the Canadian Climate Impact and Adaptation Research Network (C-CIARN) was established to address concerns regarding climate change in coastal areas. Coastal zones are sensitive to increases in air, sea and ground temperatures as well as to variations in sea level, precipitation, ice thickness, and storm intensity. This report presents the results of a workshop which focused on how coastal communities will be affected by climate induced water level changes, particularly sea-level rise on ocean coasts and decreasing lake levels in the Great Lakes. The workshop addressed issues such as the effects of changing water levels on coastal infrastructure, utilities, community development, and the implications of changing water levels to human safety, cultural resources, tourism, and insurance. The workshop reviewed the current state of understanding on water level ...
2004-07-01
Computer programs have been developed to define the temperature increase which would be needed to bring deep-ocean water into density equilibrium with surface water for locations where data are available. A series of continuous-flow studies on phytoplankton blooms resulting from mixtures of 80 percent deep and 20 percent surface water in 2000-liter concrete culturing vessels (''reactors'') has been completed. A quantitative determination of nutrient utilization and flow through a combined primary and secondary trophic level system has been completed. This study utilized the clam Tapes semidecussata, fed from phytoplankton grown in 80 percent deep and 20 percent surface water. An analysis of the fate of the deep water discharged from a floating OTEC plant indicates that horizontal containment of the resulting deep ...
1976-01-01
Condensation driven water hammer studies for feed water distribution pipe
International Nuclear Information System (INIS)
Special T-shaped feedwater distribution pipes were installed in steam generators at the Loviisa (Finland) and Rovno (Russia) nuclear power plants. The new shape was tested in an extensive testing programme. Since the tubes frequently suffer from corrosion damage, large-scale water hammer experiments were performed on a model facility in 1996. The main objectives of the water hammer experiments were to find out the prevailing parameters leading to water hammers, as well as the sensitivity of hammering to boundary conditions. A water hammer may occur when the mass flow rate into the steam generator exceeds 6 kg/s and the temperature difference between steam generator and feedwater exceeds 100 degC. Visual experiments and stress analyses of the pipe were also carried out. The weakest part, the T-joint, may hold against such water hammers only for a limited time of ...
1997-05-26
Strontium-90 and cesium-137 in service water from June to December, 1981
International Nuclear Information System (INIS)
Service water, 100 l each, was collected at an intake of a water treatment plant and at a tap after water was left running for five minutes. The carriers of strontium and cesium were added to water immediately after sampling, and the sample was vigorously stirred and filtered. Then it was passed through a cation exchange column at a rate of 80 ml/min. Strontium and cesium were eluted with hydrochloric acid from the cation exchange column, and separated. After the radiochemical separation, the mounted precipitates were counted for activity using low background beta counters normally for 60 min. Net sample counting rates were corrected for counter efficiency, recovery, self absorption and decay to obtain the content of strontium-90 and cesium-137 radioactivity per sample aliquot. From the results, concentrations of these nuclides in the original sample were calculated. The maximum ...
1981-12-01
International Nuclear Information System (INIS)
An attempt to determine lysozyme hydration by employing a proton nuclear magnetic resonance (NMR) spin-echo technique and to correlated such measurements with the 20 "0C sorption equilibrium data is made. Determinations of specific site hydration for lysozyme, as well as proton NMR transverse relaxation rates for five different types of water populations in the lysozyme-water system, are presented over the whole range of lysozyme concentrations. The proton spin-echo NMR results are consistent with a three-component analysis of the sorption isotherm up to 70% water content, above which two additional water populations are identified by 360-MHz proton NMR spin-echoes. On the basis of the proton NMR results, a major component (III) of the lysozyme sorption isotherm is assigned to the water trapped between lysozyem molecules, whose relaxation rate is increased by diffusion barriers. The ...
Development of a probabilistic timing model for the ingestion of tap water.
Energy Technology Data Exchange (ETDEWEB)
A contamination event in a water distribution system can result in adverse health impacts to individuals consuming contaminated water from the system. Assessing impacts to such consumers requires accounting for the timing of exposures of individuals to tap-water contaminants that have time-varying concentrations. Here we present a probabilistic model for the timing of ingestion of tap water that we developed for use in the U.S. Environmental Protection Agency's Threat Ensemble Vulnerability Assessment and Sensor Placement Tool, which is designed to perform consequence assessments for contamination events in water distribution systems. We also present a statistical analysis of the timing of ingestion activity using data collected by the American Time Use Survey. The results of the analysis provide the basis for our model, which accounts for individual ...
2009-01-01
Control of microbially generated hydrogen sulfide in produced waters
Energy Technology Data Exchange (ETDEWEB)
Production of hydrogen sulfide in produced waters due to the activity of sulfate-reducing bacteria (SRB) is a potentially serious problem. The hydrogen sulfide is not only a safety and environmental concern, it also contributes to corrosion, solids formation, a reduction in produced oil and gas values, and limitations on water discharge. Waters produced from seawater-flooded reservoirs typically contain all of the nutrients required to support SRB metabolism. Surface processing facilities provide a favorable environment in which SRB flourish, converting water-borne nutrients into biomass and H{sub 2}S. This paper will present results from a field trial in which a new technology for the biochemical control of SRB metabolism was successfully applied. A slip stream of water downstream of separators on a produced water handling facility was ...
1995-12-31
Energy Technology Data Exchange (ETDEWEB)
Petropavlovsk-Kamchatky (P-K) city in Kamchatka, Russia is operating hot-water district heating using heavy oil boilers and waste hot water of thermal power plants as heat sources. Feasibility study was made on district heating using natural geothermal hot water and/or geothermal heat pump systems as heat sources of hot water supply for reduction of greenhouse effect gas emission. Among 3 areas including geothermal hot water, use of hot water in K area was impossible because of lower temperature and less spring water. Use of hot water in P and UP areas was impossible as primary hot water because of temperature drop to 64 degrees C during hot water supply toward P-K city. The building heating operation test was carried out using the ...
1999-05-01
An exergy based test protocol for truncated pyramid type solar box cooker
British Library Electronic Table of Contents (United Kingdom)
Developing a test standard/protocol for solar box type cookers has drawn a considerable interest among the researchers throughout the world. Recent publications on solar cookers emphasize the need of introducing the thermal performance indicators determined through exergy analysis. In the present paper, the time variation of instantaneous exergy output and energy output as function of its temperature and also of the instantaneous ambient temperature have been reported for truncated pyramid type solar box cooker and compared with those of box type cooker. Further, variations in the exergy lost with temperature difference have been depicted for the selected water temperature range from 60 degreeC to 95 degreeC. Based on this study, quality factor, exergy temperature difference gap product, a...
2011-01-01
Evaluation of the humidification requirements of new proton exchange membranes for fuel cells
Measurements of PEM fuel cell device performance were made with different gas inlet temperatures and relative humidity using a newly-designed test fixture. Significant improvement in device performance was observed when the fuel inlet temperature was increased above the operating temperature of the cell. These measurements were then correlated to a model to describe energy and mass transport processes. Proton exchange membrane (PEM), fuel cells--the focus of this study--use an ion conducting polymer, especially polyperfluorosulfonic acid materials. These polymer materials, when imbibed with water, exhibit solution-like properties, but because the anions are chemically bound to the polymeric structure, the electrolyte is contained. Importantly, product water removal is simplified, as electrolyte dilution is not a concern. However, the proton transport rate is a function of the ...
1995-05-01
Development of in-vessel type control rod drive mechanism for marine reactor
Energy Technology Data Exchange (ETDEWEB)
A highly reliable control rod drive mechanism (CRDM) installed inside the reactor vessel has developed for use of an advanced marine reactor. This CRDM contributes to compactness and simplicity of the reactor system, and it can eliminate the possibility of a rod ejection accident. The CRDM works in the high temperature and high pressure water - 310degC and 12 MPa, the same atmosphere as the primary loop. Driving force is produced by a synchronous motor with the rotor of a permanent magnet, which has been developed. An innovative latch mechanism using separable ball nuts can latch driving shaft connecting the control rod and de-latch it for scram. The rod position detector using a magnetostrictive wire type sensor on the principle of Wiedeman effect has been developed, accuracy of which is verified to have a detecting error within 1.2 mm. Ball bearings for thrust and radial supports in rotation have been developed to be capable of working under ...
2001-07-01
Understanding the operation and use of high temperature electrochemical corrosion rate probes
Energy Technology Data Exchange (ETDEWEB)
Electrochemical corrosion rate probes were constructed and tested along with mass loss coupons in a N2/O2/CO2 plus water vapor environment. Temperatures ranged from 450 to 600 C. Corrosion rates for ash-covered mild steel, 304L SS, and 316L SS probes using electrochemical techniques were a function of time, temperature, and process environment. Correlation between electrochemical and mass loss corrosion rates was good.
2004-01-01
GRI's Gas Appliance Technology Center Activities at Battelle. Final report, 1986-1992
The Gas Research Institute established the Gas Appliance Technology Center (GATC) in 1982 to develop improved gas appliances. Between 1986 and 1992, the scope of GATC activities at Battelle included technology transfer and overall industry support, residential appliances, commercial appliances, and residential space conditioning. The following tasks are representative of the GATC activities described in the report; gas burner technology, appliance venting, emissions, water heating, range/oven technology, self-powered appliances, commercial cooktop burners, reconstituting ovens, appliance reliability improvement, combination space-heating/water-heating systems, condensing heat exchangers, corrosion testing, and space heating technology. The report includes references to available sources for further reading.
1993-08-01
Construction progress of the cooling & ventilation in the LHC project
After the LEP dismantling Phase the Cooling and Ventilation Group has started the LHC construction work. Year 2001 through to 2004 will certainly be the most important period of activity for the CV group in the erection phase The author will report on the current works that are in progress on the different LHC Points distinguishing between the Ventilation and the Water Cooling installations. The Ventilation work completed in the new surface buildings in Points 1, 4,5,6 and 8. The work for the Cooling plants comprehend to the pumping stations, the cooling towers and the chilled water production stations in Points 1 and 5, For all of these activities, an updated report of the progress the work, the planning and of the expenses are given. Finally, a brief overview of the future activities is presented.
2002-01-01
Construction Progress of the Cooling and Ventilation in the LHC Project
The Cooling and Ventilation Group has started the LHC construction work in September 1999 and will get into full activity when LEP will be stopped and dismantled: in total 12 major contracts for an amount of about 120 MCHF will be established to build the needed installations for the LHC. The author will report on the current works that are in progress on the different LEP Points distinguishing between the Ventilation and the Water Cooling installations. The Ventilation work, completed in the new surface buildings in Points 18, is currently held in Points 4 and 5. Point 1 will follow in the near future. The work for the Cooling plants comprehend the pumping stations, the cooling towers and the chilled water production stations in Points 1 and 5, the buried pipes in Points 1 and 4. For all of these activities, an updated report of the progress of the work, of the planning and of the expenses is given. ...
2001-01-01
Canadian R&D on oil-fired combustion systems
Energy Technology Data Exchange (ETDEWEB)
This paper describes research and development presently being conducted on oil-fired space and tap water heating systems by the Advanced Combustion Technology Group, CCRL/ERL/CANMET, in Ottawa, Canada. The presentation will focus on R&D activities at CCRL in support of the Canadian Oil Heat Association (COHA) and of the energy policy initiatives of Natural Resources Canada. Progress will be reported on activities to develop suitable oil-fired integrated systems to satisfy the low energy demands of new homes. The utilization of fuzzy logic-based control heating systems including fan coils for a complete range of old and new North American housing will be discussed. Additional activities to be discussed in the presentation will relate to the development of appropriate seasonal efficiency standards for complex integrated space/water heating systems, as well as an evaluation of ...
1996-07-01
Energy Technology Data Exchange (ETDEWEB)
The paper describes uptake of gaseous lodine-131 on silver impregnated organic resin, Amberlite IR-120, available at the Secondary Steam Generator (S.S.G.) Opening at T.A.P.S. in comparison with activated charcoal. The experiments are conducted in dry and wet conditions by soaking the impregnated resin and activated charcoal in distilled water for wet condition. The paper also describes the iodine sampler specially designed and fabricated for these experiments.
1982-01-01
Radioprotective activity in some medicinal herbs
Energy Technology Data Exchange (ETDEWEB)
Water-soluble, ethanol-insoluble extracts prepared from several medicinal herbs of the Araliaceae and other families were tested for their radioprotective activity by either measuring 30 days survival rates (a commonly applied method) or counting the thrombocytes 14 days after irradiation (an improved method) in mice. The extracts were i.p. injected once within 4 min after the whole body X-ray irradiation. Of 12 materials examined, Aralia elata, Angelica acutiloba and Morus bombysis seemed to be good starting materials for preparing radioprotective substance(s) because of their relatively high specific activity and high yields of the extracts. (author).
1993-09-01
Annual Report 2007. Nuclear Regulatory Authority
International Nuclear Information System (INIS)
The present Annual Report of Activities of the Nuclear Regulatory Authority (ARN), prepared regularly from the creation as independent institution, describes across tree parts and seven annexes the activities developed by the organism during 2007. The main topic are: the organization and the activity of the ARN; the regulatory standards; the licensing and inspection of nuclear power plants and critical facilities; the emergency systems; the occupational surveillance; the environmental monitoring; improved organizational. Also, this publication have annexes with the following content: regulatory documents; inspections to medical, industrial and training installations; regulatory guides; measurement and evaluation of the drinking water of Ezeiza.
2004-07-11
Water in polymer membranes. 4. Raman scattering from cellulose acetate films
Energy Technology Data Exchange (ETDEWEB)
Raman scattering was observed from thin film optical waveguides of cellulose acetate exposed to water vapor from 0% to 100% relative humidity (RH), and from dilute solutions of water in methyl acetate. Spectra of cellulose acetate (CA398, 39.8% acetyl) at low RH and cellulose triacetate (CTA) at low and high RH are consistent with the presence of water monomers that are weakly hydrogen bonded to acetyl C=O groups. Differences between the spectra of water in CA398 and CTA at low RH are attributed to sequential hydrogen bonding involving OH groups in CA398. At high RH, CA398 and CTA (to a lesser extent) show bands attributed to water/water interactions that are similar to those found in sequentially hydrogen-bonded hydrates. CA398 films that are annealed at high temperatures exhibit decreased water/water interactions at high RH. Exposure of ...
1985-01-17
Stable isotopes of authigenic minerals in variably-saturated fractured tuff
Energy Technology Data Exchange (ETDEWEB)
Identifying stable isotope variation and mineralogical changes in fractured rock may help establish the history of climatic and geomorphological processes that might affect the isolation properties of a waste repository site. This study examines the use of the stable isotope ratios of oxygen ({sup 18}O/{sup 16}O) and carbon ({sup 13}C/{sup 12}C) in authigenic minerals as hydrogeochemical tools tracing low-temperature rock-water interaction in variably-saturated fractured stuff. Isotopic compositions of fracture-filling and rock matrix minerals in the Apache Leap tuff, near Superior, Arizona were concordant with geothermal temperatures and in equilibrium with water isotopically similar to present-day meteoric water and groundwater. Oxygen and carbon isotope ratios of fracture-filling, in unsaturated fractured tuff, displayed an isotopic gradient believed to result from near-surface ...
1988-11-01
Energy Technology Data Exchange (ETDEWEB)
An experimental investigation of a humidification-dehumidification desalination (HDD) process using solar energy at the weather conditions of Suez City, Egypt, is presented. A test rig is designed and constructed to conduct this investigation under different environmental and operating conditions. The test rig consists of a solar water heater (concentrator solar collector type), solar air heater (flat plate solar collector type), humidifier tower and dehumidifier exchanger. Different variables are examined including the feed water flow rate, the air flow rate, the cooling water flow rate in the dehumidifier and the weather conditions. Comparisons between the experimental results and other published results are presented. It is found that the results of the developed mathematical model by the same authors are in good agreement with the experimental results. The tested results show that the productivity of the system is ...
2004-05-01
International Nuclear Information System (INIS)
An experimental investigation of a humidification-dehumidification desalination (HDD) process using solar energy at the weather conditions of Suez City, Egypt, is presented. A test rig is designed and constructed to conduct this investigation under different environmental and operating conditions. The test rig consists of a solar water heater (concentrator solar collector type), solar air heater (flat plate solar collector type), humidifier tower and dehumidifier exchanger. Different variables are examined including the feed water flow rate, the air flow rate, the cooling water flow rate in the dehumidifier and the weather conditions. Comparisons between the experimental results and other published results are presented. It is found that the results of the developed mathematical model by the same authors are in good agreement with the experimental results. The tested results show that the productivity of the system is ...
2004-05-01
Energy Technology Data Exchange (ETDEWEB)
An experimental investigation of a humidification-dehumidification desalination (HDD) process using solar energy at the weather conditions of Suez City, Egypt, is presented. A test rig is designed and constructed to conduct this investigation under different environmental and operating conditions. The test rig consists of a solar water heater (concentrator solar collector type), solar air heater (flat plate solar collector type), humidifier tower and dehumidifier exchanger. Different variables are examined including the feed water flow rate, the air flow rate, the cooling water flow rate in the dehumidifier and the weather conditions. Comparisons between the experimental results and other published results are presented. It is found that the results of the developed mathematical model by the same authors are in good agreement with the experimental results. The tested results show that the productivity of the system is ...
2004-05-01
International Nuclear Information System (INIS)
This paper presents an overview of issues related to surface water contamination arising from uranium mining activities in the Alligator Rivers Region (ARR) of northern Australia, and a program of research and monitoring that must assess the potential and actual effects on ecosystem and human health. The program of assessing effects on aquatic ecosystems involves a four-tiered approach including the derivation of local water quality guideline trigger values, direct toxicity assessment of mine waters prior to their release, creekside or in situ monitoring for early warning of adverse effects during mine water release, and longer-term monitoring of macroinvertebrate and fish communities. Bioaccumulation in aquatic biota is also assessed, and is an issue of importance not only to ecosystem health, but also to the health of local Aboriginal people. The aquatic animals they consume ...
2002-12-27
Actinides in liquid waste formed in the regeneration of nuclear fuel from a VVER-1000 reactor
International Nuclear Information System (INIS)
In the radiochemical reprocessing of spent fuel from nuclear reactors, a considerable amount of liquid, solid, and gaseous waste is formed; this waste is potentially dangerous to humans and requires the development of special and complex technological techniques for its localization and reliable long-term storage. The most hazardous are liquid wastes of high specific activity - water-tailings solutions obtained in the first cycle of extraction after the removal of uranium and plutonium. These solutions contain more than 99.9% of all the other transuranic elements - isotopes of neptunium, americium, and curium. Where necessary, some fission products and actinides may be removed from wastes of high specific activity for subsequent use. The quantity, composition, and activity of these wastes varies within broad limits, depending on the type and power of the reactor, the initial nuclide composition of the ...
Techno-economic investigation of an air humidification-dehumidification desalination process
Energy Technology Data Exchange (ETDEWEB)
This article presents a humidification-dehumidification (H.D.) process suitable for desalination of sea- and brackish water. The work correlated performance characteristics of the combination of different components in such a loop. Water yield, energy requirement and design data are evaluated as functions of different parameters. The investigation covered water to air mass ratios ranging from 60 to 80, concentration ratios between 2 and 5, at a temperature difference of between 10 and 16 C, along the liquid for dehumidification. The results showed that 76% of energy consumed in the humidifier is recovered by condensation. Increase of the concentration ratio to 5 can reduce the make-up water and rejected brine by about 58% and 24% respectively. Cost calculations show that the H.D. process has significant potential as an alternative for small capacity desalination plants and permits ...
1993-08-01
System for cooling primary gas coolers using return water stabilized by means of ammonium sulfate
Energy Technology Data Exchange (ETDEWEB)
Discusses scaling of closed systems for cooling coal gas from black coal coking. Scaling rate and factors that influence scaling are analyzed. Physical and chemical properties of scale buildup on the inner walls of pipe cooling systems are evaluated. Water pH value and its effects on scaling and solubility of chemical compounds that form scale are discussed. Use of ammonium sulfate for scale control is analyzed. Consumption rate of ammonium sulfate depends on ambient temperature, water pH value and chloride content in return water. Formulae for calculating optimum content of ammonium sulfates for scale control are derived. 3 refs.
1989-08-01
British Library Electronic Table of Contents (United Kingdom)
The objective of this study is to develop an artificial neural network (ANN) model to predict the thermal conductivity of ethylene glycol-water solutions based on experimentally measured variables. The thermal conductivity of solutions at different concentrations and various temperatures was measured using the cylindrical cell method that physical properties of the solution are being determined fills the annular space between two concentric cylinders. During the experiment, heat flows in the radial direction outwards through the test liquid filled in the annual gap to cooling water. In the steady state, conduction inside the cell was described by the Fourier equation in cylindrical coordinates, with boundary conditions corresponding to heat transfer between the solution and cooling water. ...
2009-01-01
Enantioselective separation of the carfentrazone-ethyl enantiomers in soil, water and wheat by HPLC
British Library Electronic Table of Contents (United Kingdom)
A simple enantioselective HPLC method was developed for measuring carfentrazone-ethyl enantiomers. The separation and determination was accomplished on an amylose tris[(S)-a-methylbenzylcarbamate] (Chiralpak AS) column using n-hexane/ethanol (98:2, v/v) as mobile phase at a flow rate of 1.0 mL/min with UV detection at 248 nm. The effects of mobile-phase composition and column temperature on the enantioseparation were discussed. The accuracy, precision, linearity, LODs, and LOQ of the method were also investigated. LOD was 0.001 mg/kg in water, 0.015 mg/kg in soil and wheat, with an LOQ of 0.0025 mg/kg in water and 0.05 mg/kg in soil and wheat for each enantiomer of carfentrazone-ethyl. SPE was used for the enrichment and cleanup of soil, water, and wheat samples. Recoveries for two enantio...
2010-01-01
Condensation heat transfer in a steam-water stratified flow
Energy Technology Data Exchange (ETDEWEB)
Fundamental phenomena of condensation heat transfer at a steam-water interface have been studied related to the thermo-hydrodynamics of the emergency core cooling system for light water reactors. In this study temperature fluctuations near the interface and in the liquid phase were measured using fine thermocouples for a saturated steam-subcooled water co-current stratified two-phase flow in a nearly horizontal rectangular channel, and heat transfer coefficients were determined experimentally. The values of the condensation heat transfer coefficients in this experiment are from 6 to 40 kW/m{sup 2}K. In the regions of high Reynolds numbers, as the steam Reynolds numbers become larger, the average interfacial heat transfer coefficients tend to increase. The corelations of Nusselt numbers were obtained from the heat transfer data. (author)
1999-07-01
Condensation heat transfer in a steam-water stratified flow
International Nuclear Information System (INIS)
Fundamental phenomena of condensation heat transfer at a steam-water interface have been studied related to the thermo-hydrodynamics of the emergency core cooling system for light water reactors. In this study temperature fluctuations near the interface and in the liquid phase were measured using fine thermocouples for a saturated steam-subcooled water co-current stratified two-phase flow in a nearly horizontal rectangular channel, and heat transfer coefficients were determined experimentally. The values of the condensation heat transfer coefficients in this experiment are from 6 to 40 kW/m"2K. In the regions of high Reynolds numbers, as the steam Reynolds numbers become larger, the average interfacial heat transfer coefficients tend to increase. The corelations of Nusselt numbers were obtained from the heat transfer data. (author)
1999-04-19
Ru/SiO2 AND CuRu/SiO2 PREPARED BY SOL-GEL: EFFECT OF pH AND WATER AMOUNT
Scientific Electronic Library Online (English)
Abstract in english Ru(1%)/SiO2 and Cu(1%)Ru(1%)/SiO2 catalysts were prepared by cogelation. The effect of pH and the amount of water on the physical-chemical properties and the catalytic properties of them were analyzed. The acid medium increased the formation of microporosity and the formation of small size of metallic ruthenium particle. The variation of the water quantity used in the gelation not modify considerably the texture neither the dispersion of the noble metal. The reduction lev (more) el of all prepared catalyst was similar, showing displacement in some of reduction peaks. The toluene hydrogenation indicated that the conversion and the quantity of hydrogenate product varied with the pH and the quantity of water used in the gelation. The addition of copper to Ru/SiO2 catalysts diminished the reactive conversion and their hydrogenant activity
2003-06-01
Road maps on research and development plans for water chemistry of nuclear power systems
International Nuclear Information System (INIS)
Water chemistry of nuclear power plants has played an important role in reduction of personnel doses, structural materials and fuel integrity assurance, and reduction of radioactive wastes production. Further contributions are requested for advanced utilization of the LWR, advanced fuels and aging management of plants. Since water chemistry has an effect on all structure and materials immersed and at the same time affected by them, the optimum control not sticking to specific issues and covering the whole plant is required for these requests. Taking account of roles and activities of the industry, governmental institutes and academia, road maps on research and development plans for water chemistry were compiled into identified eleven items with targets and counter measures taken, such as common basic technologies, dose reduction, SCC mitigation, fuel cans corrosion/hydrogen absorption mitigation, ...
2008-05-01
International Nuclear Information System (INIS)
An electrochemistry model was developed to analyse the J-V characteristics of a Proton Exchange Membrane (PEM) water electrolyzer for hydrogen production. The Butler-Volmer equation and water transport characteristics through electrolyte membrane were employed to simulate the electrode activation over-potential and membrane ohmic over-potential, respectively. The modeling results are found to agree reasonably well with experimental data published in the literature. The parametric simulations show that the ohmic over-potential is relatively small with typical water content in the membrane. Compared with the cathode over-potential, the anode over-potential is more significant and constitutes the major source of voltage loss. The high anode over-potential is due to the relatively slow oxidation kinetics, which is related to anode material property and microstructure. This model can be integrated with a ...
2006-06-13
Energy Technology Data Exchange (ETDEWEB)
The performance of a 6 kW proton exchange membrane (PEM) electrolyzer was modeled using a semiempirical equation. Total cell voltage was represented as a sum of the Nernst voltage, activation overpotential and ohmic overpotential. A temperature and pressure dependent Nernst potential, derived from thermodynamic principles, was used to model the 20 cell PEM electrolyzer stack. The importance of including the temperature dependence of various model components is clearly demonstrated. The reversible potential without the pressure effect decreases with increasing temperature in a linear fashion. The exchange current densities at both the electrodes and the membrane conductivity were the coefficients of the semiempirical equation. An experimental system designed around a 6 kW PEM electrolyzer was used to obtain the current-voltage characteristics at different stack temperatures. A ...
2008-12-01
International Nuclear Information System (INIS)
Tarapur Atomic Power Station 3 and 4 is a 540 MWe Pressurized Heavy Water Reactor. It uses 37 - element natural Uranium dioxide (UO_2) fuel pellets encapsulated inside the cylindrical sheath and are welded to the end plate at each end. During an postulated accident in which part of the fuel bundle are exposed to very high temperature (no means of heat removal) and other are at lower temperature (coolant temperature) possibility of failure of end plate weld due of thermal stresses developed by these relative temperature cannot be ruled out. In this report an attempt is made to study behaviour of fuel bundle under different temperature loading. Modelling of 37 element fuel bundle was done in ANSYS FEM. System was analysed for various sets of temperature loading. The system was analysed for plasticity and creep as material nonlinearity. The ...
2005-12-01
International Nuclear Information System (INIS)
At a military base in the Southeastern US, an energy services company (ESCO) has proposed to retrofit more than 1,000 family residences with geothermal heat pumps as part of an energy savings performance contract (ESPC). Each residence is to have one heat pump with its own ground heat exchanger consisting of two or more vertical bores. A design firm hired by the ESCO sized the heat pumps to meet peak cooling loads, and sized the borefields to limit the maximum entering water temperature (EWT) to the heat pumps to 95 F (35 C). Because there is some disagreement in the geothermal heat pump industry over the peak temperature to be used for design (some designers and design manuals recommend temperatures as low as 85 F[29 C], while equipment manufacturers and others specify temperatures of 100 F[38 C] or higher) the authors were requested to examine the designs in detail to determine ...
Energy Technology Data Exchange (ETDEWEB)
Pt-based ternary catalysts have been proposed as electrode materials for low temperature fuel cells. Pt-Ru-based ternary catalysts were tested as anode materials with improved CO tolerance or enhanced activity for methanol or ethanol oxidation. Ternary catalysts based on platinum alloyed with first row transition metals were tested as cathode materials with improved activity for the oxygen reduction. This paper presents an overview of the preparation methods and structural characteristics of these ternary catalysts. (author)
2007-07-31
Adsorption of phosphate from aqueous solution using activated red mud
Energy Technology Data Exchange (ETDEWEB)
Adsorption of phosphate (PO{sub 4}{sup 3{minus}}) from aqueous solution on activated red mud (ARM) was studied as a function of time, pH, temperature, concentration of adsorbent and adsorbate in acetic acid-sodium acetate buffer medium. The adsorption of phosphate follows Langmuir as well as Freundlich adsorption isotherms. The process efficiency was found to be 80--90% at room temperature. This can be extended to the treatment of industrial effluents containing phosphates like that from phosphatic fertilizer plants.
1998-08-01
International Nuclear Information System (INIS)
A typical form of change in runoff characteristics caused by the widespread use of hydroelectric power in Switzerland is the intermittent draining (torrent operation). It is the aim of the present work to help elucidate possible consequences of these changes in drain onto the benthobiocoenosis. The study was carried through on the Secklisbach at Oberrickenbach (in the semicanton of Nidwalden) and one of its side streamlets (800m above sea level). The macroinvertebrate coenosis was studied at four locations with similar conditions of drainage basin, population density and topography but varying in the degree of impairment to the draining. There were monthly benthos samples taken using a Surber sampling-device. Results show that the locations not only varied in drain, but also in temperature, this being a consequence of water storage by the power plant. The readings pointed out different values for the locations in daily average ...
Venus surface power and cooling systems
British Library Electronic Table of Contents (United Kingdom)
A mission to the surface of Venus would have high scientific value, but most electronic devices and sensors cannot operate at the 450degreeC ambient surface temperature of Venus. Power and cooling systems were analyzed for Venus surface operation. A radioisotope power and cooling system was designed to provide electrical power for a probe operating on the surface of Venus. For a mission duration of substantial length, the use of thermal mass to maintain an operable temperature range is likely impractical, and active refrigeration may be required to keep components at a temperature below ambient. Due to the high thermal convection of the high-density atmosphere, the heat rejection temperature was assumed to be at a 500degreeC radiator temperature, 50degreeC above ambient. The radioisotope S...
2007-01-01
Reversing flow catalytic converter for a natural gas/diesel dual fuel engine
Energy Technology Data Exchange (ETDEWEB)
An experimental and modelling study was performed for a reverse flow catalytic converter attached to a natural gas/diesel dual fuel engine. The catalytic converter had a segmented ceramic monolith honeycomb substrate and a catalytic washcoat containing a predominantly palladium catalyst. A one-dimensional single channel model was used to simulate the operation of the converter. The kinetics of the CO and methane oxidation followed first-order behaviour. The activation energy for the oxidation of methane showed a change with temperature, dropping from a value of 129 to 35 kJ/mol at a temperature of 874 K. The reverse flow converter was able to achieve high reactor temperature under conditions of low inlet gas temperature, provided that the initial reactor temperature was sufficiently high. (author)
2001-07-01
GaP/Al/sub x/Ga/sub 1-x/P heterojunction transistors for high-temperature electronic applications
Useful bipolar transistor action over the temperature range from -195 to 550 /sup 0/C has been demonstrated for heterojunction bipolar transistors in the GaP/AlGaP chemical system. This represents the highest temperature at which useful bipolar solid-state transistor action has ever been demonstrated in any material. Improvements in the materials technology and in the understanding of device characteristics at high temperatures were essential to the successful fabrication of these devices. These results demonstrate that the GaP/AlGaP heterojunction system is an excellent technology for active electronic components operated at high temperatures.
1983-10-01
Energy Technology Data Exchange (ETDEWEB)
We present high-quality X-ray scattering experiments on pure water taken over a temperature range of 2 to 77 C using a synchrotron beam line at the advanced light source (ALS) at Lawrence Berkeley National Laboratory. The ALS X-ray scattering intensities are qualitatively different in trend of maximum intensity over this temperature range compared to older X-ray experiments. While the common procedure is to report both the intensity curve and radial distribution function(s), the proper extraction of the real-space pair correlation functions from the experimental scattering is very difficult due to uncertainty introduced in the experimental corrections, the proper weighting of OO, OH, and HH contributions, and numerical problems of Fourier transforming truncated data in Q-space. Instead, we consider the direct calculation of X-ray scattering spectra using electron densities derived from density functional theory based on ...
2003-03-01
Energy Technology Data Exchange (ETDEWEB)
The effect of method of sulfur addition on the hydrocracking activity of coal liquefaction catalysts was investigated using a high-pressure differential thermal analyser. The three methods of sulfur addition were: 1) physical mixing of 10 wt% elemental sulfur with red mud; 2) pre-sulfidation of red mud with hydrogen sulfide; 3) use of reagent grade pyrite. The pre-sulfided catalyst was slightly less active than the catalyst prepared by physical mixing, and both of these were changed to pyrrhotite in the course of use. Although the pyrite catalyst exhibited activity at markedly lower temperatures than those required for the other two catalysts, conversions were lower than had been expected. This is thought to be due to a different catalytic mechanism being involved. 13 references.
1983-01-01
Aespoe Pillar Stability Experiment. Acoustic emission and ultrasonic monitoring
Energy Technology Data Exchange (ETDEWEB)
This report describes the results from acoustic emission (AE) and ultrasonic monitoring of the Aespoe Pillar Stability Experiment (APSE) at SKB's Hard Rock Laboratory (HRL), Sweden. The APSE is being undertaken to demonstrate the current capability to predict spalling in a fractured rock mass using numerical modelling techniques, and to demonstrate the effect of backfill and confining pressure on the propagation of micro-cracks in rock adjacent to deposition holes within a repository. An ultrasonic acquisition system has provided acoustic emission and ultrasonic survey monitoring throughout the various phases of the experiment. Results from the entire data set are provided with this document so that they can be effectively compared to several numerical modelling studies, and to mechanical and thermal measurements conducted around the pillar volume, in an 'integrated analysis' performed by SKB staff. This document provides an in-depth summary of the AE and ...
2005-12-15
Water management studies in PEM fuel cells, Part I: Fuel cell design and in situ water distributions
Energy Technology Data Exchange (ETDEWEB)
A proton exchange membrane fuel cell (PEMFC) must maintain a balance between the hydration level required for efficient proton transfer and excess liquid water that can impede the flow of gases to the electrodes where the reactions take place. Therefore, it is critically important to understand the two-phase flow of liquid water combined with either the hydrogen (anode) or air (cathode) streams. In this paper, we describe the design of an in situ test apparatus that enables investigation of two-phase channel flow within PEMFCs, including the flow of water from the porous gas diffusion layer (GDL) into the channel gas flows; the flow of water within the bipolar plate channels themselves; and the dynamics of flow through multiple channels connected to common manifolds which maintain a uniform pressure differential across all possible flow paths. These two-phase flow effects have been studied at relatively ...
2009-05-15
Energy Technology Data Exchange (ETDEWEB)
The treatment and disposal of oily waters from oil production and refining processes represent an important technological pass for attendance of the ambient legislation and to the politics of the Cia of search of the environmental excellence. The reuse or reinjection of the co-produced water has been considered an interesting strategical alternative, however, the water quality requirement for these processes demands a pretreatment step, considering the exit effluent from primary and secondary treatment processes currently used. This work presents resulted of the polymeric resin development for tertiary treatment of oily waters with low oil and grasses content and fine solids, including the dissolved fraction. These resins can adsorb, in reversible form, organic components. Its high adsorption capacity is determined by the polarity, superficial area, range of porosity and a wide distribution of particle ...
2008-07-01
Measurement of oxidation rate of sulfite in rain water in Yokohama, Japan
Energy Technology Data Exchange (ETDEWEB)
In recent years, the influences of acid rain such as the acidification of lake water, on bio-system by the heavy metals from effluent of soils with acid rain and also on the structural materials of buildings are seriously discussed. Sulfur and nitrogen that are contained in fossil fuels are released into the atmosphere by the fuel combustion as their oxides dissolve in rain drops as sulfite and nitrous ions, where they are further oxidized into sulfate and nitrate ions These ions lower the pH of rain water resulting so-called acid rain. Therefore, it is important to accurately determine these ions in rain water for the investigation of reality of acid rain. However, it is not easy to accurately determine these ions, especially for sulfite ions in rain water, since they are quickly oxidized by the catalytic action of metallic ions such as ferric and manganous ions. And light, ...
1986-04-01
Energy Technology Data Exchange (ETDEWEB)
Water and mud samples were collected from canals and rivers which were adjacent to outlets discharging warm water of 3 power plants in Berlin. Downstream samples from 1 bathing resort were also collected. Free living amoebae were isolated from 138 water and 69 mud samples. From these respectively 156 and 73 strains could be cultured and were administered intranasally to mice for pathogenicity tests. Two Acanthamoeba strains from water and 7 from mud could be reisolated from mouse brain and or lungs, although no pathological disorders could be observed. Five Naegleria strains were negative in mouse inoculation tests. Four Acanthamoeba strains which were positive in mice were cultured at + 45 degrees C; no cytopathogenic effects were observed in tissue cultures. Acanthamoeba infective for mice could also be isolated from samples at low water temperatures. Further ...
1982-05-01
Characteristics of pulse corona discharge over water surface
International Nuclear Information System (INIS)
Production of ozone and OH radical is required to advance the plasma chemical reactions in the NOx removal processes for combustion gas treatment. The corona discharge to the water surface is expected to induce the good conditions for the proceeding of the NO oxidation and the NO_2 dissolution removal into water. In order to get the fundamental data of the corona discharge over the water surface, the positive and negative V-I characteristics and the ozone production were measured with the multi needle and the saw-edge type of the discharge electrodes. The pulse corona characteristics were also measured with some different waveforms of the applied pulse voltage. The experiments were carried out under the atmospheric pressure and room temperature. Both the DC and the pulse corona to the water surface showed a stable and almost the same V-I characteristics as to plate electrodes though ...
2008-12-01
Energy Technology Data Exchange (ETDEWEB)
The merits of single stage absorption heat pumps coupled to simple distillation for effluent treatment are discussed. An experimental integrated absorption heat pump effluent purification system (IAHPEPS) was built and operated with water-lithium bromide as a working mixture. This unit has been used to raise the temperature and hence, the vapour pressure of the impure water contained in one vessel, to the point where pure water vapour will distil from impure effluent solution (tap water or brine) and condense in a second vessel used to collect pure water. Pure effluent production rates of between 0.5 and 4.3 kg h{sup -1} were obtained. The actual coefficient of performance (COP{sub A}) and the heat pump effectiveness varied from 1.1 to 1.4 and 0.58 to 0.72, respectively. The results from the small scale systems indicate the likely results from industrial scale ...
1999-05-01
Non-evaporable thin film getters of various compositions have been produced by sputtering. Among about 20 materials which have been studied, the lowest activation temperature (about 180 degree C) has been displayed by a Ti-Zr-V coating obtained from a cathode made of intertwisted elemental wires. In order to optimize the vacuum properties of this film various production parameters, including the substrate temperature during coating, have been varied. The films have been characterized by pumping speed measurement, secondary electron microscopy, and X-ray diffraction. It has been found that the substrate coating temperature affects significantly the activation temperature, the pumping speed and the gas surface capacity. The highest pumping speed values, obtained for substrate coating temperatures of 250 degree C and 300 degree C, are clearly ...
2003-01-01
Genotoxic effects of sunlight-activated waste waters
Energy Technology Data Exchange (ETDEWEB)
Natural sunlight induces a genotoxic response in cultured CHO cells pre-treated with shale oil retort process water. Near ultraviolet light (NUV) component of the solar spectrum is the apparent radiation responsible for photoactivation. Cultured human skin fibroblasts are acutely sensitive to the genotoxic effects of photoactivated process water. The mutagenic potential of photoactivated process water in human cells is the same as that witnessed for an equivalent killing dose of the potent skin carcinogen FUV. DNA repair processes are involved in modulating genotoxic effects of this photo-induced process. The exact magnitude of the potential health-related and environmental risks resulting from photoactivation of retort process waters and other oil shale by-products is unassessed at this time. Our demonstration that a significant rate of mutation occurs in cultured human cells exposed to high dilutions ...
1981-01-01
Radiation-annealing hardening of vanadium
International Nuclear Information System (INIS)
A study is made of the mechanical properties of vanadium irradiated with fast neutrons up to dose 8.6.10"-"4 dpa, as a function of the temperature of post-radiation annealing. The radiation-annealing hardening (RAH) effect is observed at 300"oC, in agreement with previous studies. It is established for the first time that RAH is accompanied by fall in ductility. A phenomenological model is described which explains the dependence of RAH on radiation dose and temperature, as well as on the content of chemically active alloying impurities. (author).
Radiation-annealing hardening of vanadium
International Nuclear Information System (INIS)
Mechanical properties of vanadium, irradiated with fast neutrons up to 8.6x10"-"4 dpa depending on postirradiation annealing temperature, are studied. It is shown that radiation-annealing hardening (RAH) is observed at 300 deg C, which agrees with earlier performed studies. It is first stated that RAH is accompanied by plasticity decrease. Phenomenological model permitting to explain RAH dependence on irradiation temperature and dose and also on content of chemically active alloying impurities is suggested.
Hydrolysis of isocyanic acid on SCR catalysts
Energy Technology Data Exchange (ETDEWEB)
Standard SCR catalysts possess high activity for the hydrolysis of HNCO and thus explain the suitability of urea as a selective reducing agent for NO{sub x}. At high space velocities HNCO-slip can get perceptible over the entire temperature range. This can be attributed to the fact that the temperature dependence is strong for the SCR reaction, but weak for the hydrolysis reaction. (author) 3 figs., 5 refs.
1999-08-01
Radon transport in an activated charcoal canister
Energy Technology Data Exchange (ETDEWEB)
The transport of Rn through activated charcoal was modelled for a charcoal canister used for surface emanation measurements. Derived Rn concentration distributions in full and half charcoal charges were compared with measured Rn profiles. The distributions were also compared with an empirical expression for the measured profiles. Close agreement was observed between the measured, empirically generated and derived profiles. The influence of temperature and humidity on Rn accumulation and transport is also discussed.
1989-02-01
International Nuclear Information System (INIS)
The Steam Generator (SG) serves as an interface between primary and secondary cycle in Pressurized Heavy Water Reactor (PHWR). Failure of steam generator tubes result in leaking of active heavy water in the secondary closed loop. In Tarapur Atomic Power Station-3 and 4 (TAPS- 3 and 4), Scintillator detectors are provided to detect on line heavy water leakages in SG and moderator heat exchangers by monitoring Nitrogen-16 (16N) and Oxygen-19 (19O) activities. Efficacy of detection of these activities at designed detector position on SG blow down line in presence of background radiation field is analysed theoretically. The count rate of 19O and 16N estimated at the detector position inside Reactor Building (RB) shows that detectors only respond to very high leak rates due to presence of high ambient radiation level even though sensitivity is appreciably good. For ...
2006-11-13
Use of activated charcoal for the purification of neon in the CLEAN experiment
Energy Technology Data Exchange (ETDEWEB)
Passage of neon gas through activated charcoal is planned to be the primary method of removing impurities from the liquid neon scintillator in the CLEAN experiment. In order to quantify this technique, the breakout curves for hydrogen, nitrogen, argon and krypton impurities in neon-saturated activated charcoal were measured. Adsorption coefficients and the number of theoretical stages were measured for hydrogen in the temperature range between 300 and 80 K, nitrogen between 300 and 200 K, and argon between 300 and 190 K. The adsorption coefficient for krypton was measured at 300 K.
2007-01-21
Sugar Ester Modified Lipase Catalyzed Esterification in Organic Media.
The esterification reaction of a long-chain fatty acid and a fatty alcohol catalyzed by sugar ester-modified lipases in organic media was studied. The reaction activity was improved when the lipases were modified with sugar esters. Among four kinds of sugar esters and six kinds of lipases, lipase CES modified with sugar ester SE-7 showed the highest reaction activity. The pH, solvent and temperature on the reaction activity of SE-7 modified lipase CES were also studied. PMID:12142919
1999-01-01
Radon measurements in dwellings using activated charcoal
Energy Technology Data Exchange (ETDEWEB)
In Sweden there is a demand for a method of measuring radon in dwellings with high accuracy and at a low cost. A method of determining radon concentration (Bq.m/sup -3/) in dwellings has been developed at the Swedish National Testing Institute. A plastic canister containing activated charcoal has been tested in a radon chamber (volume 20 m/sup 3/) to determine the effects of relative humidity, temperature and exposure time. The activated charcoal in the canister adsorbs radon from the air surrounding the canister. The radon concentration is determined by counting the gamma rays from the decay of radon and daughters. The theory and preliminary results from calibrations and field measurements are reported.
1984-01-01
Mechanism of Methanes Adsorption on Nanometer Active Carbon at Supercritical State
British Library Electronic Table of Contents (United Kingdom)
Isosteric heats and adsorption isotherms of methane on nanometer active carbon were measured at supercritical temperature (273-373 K) and pressure from 0 to 10 MPa. The measured data agreed well with Dubinin-Astakhov (DA) model at lower pressure but failed when pressure exceeded a special range. General Freundlich (GF) equation was used to modify the DA equation at high pressure and thus formed a combined bisection model GFDA. The adsorption mechanism of methane on nanometer active carbon was raised according to GFDA model and the heterogeneous energy distribution of the adsorbent was analyzed.
2008-01-01
A theoretical study of radon measurement with activated charcoal
Energy Technology Data Exchange (ETDEWEB)
Diffusion of radon in a bed of activated charcoal is described by diffusion equations. An analytical solution of these equations is presented for the case of constant radon concentration in the atmosphere. The solutions are given separately for short term and long term exposure. An analytical form of the calibration constant f for long term exposure and constant radon concentration in air, was found. A numerical method and computer code based on the method of finite elements is developed for the case of variable radon concentration in air. This program simulates radon adsorption by the activated charcoal bed, enabling determination of sensitivity. The dependence of sensitivity on different parameters, such as temperature, thickness of the charcoal, etc. was studied using this program. (orig.) 10 refs.
1998-04-11
Effects of microwaves on cell survival at elevated temperatures
Energy Technology Data Exchange (ETDEWEB)
Since microwaves are used in human cancer therapy, information on specific biological effects of microwaves at elevated temperatures is important. To help supply this information, we exposed mammalian cells (CHO) and bacteria (Serratia marcescens) to hyperthermal temperatures (43, 44, and 45/sup o/C for CHO and 48, 49, and 50/sup o/C for the bacteria) with and without microwave irradiation. Temperature control was maintained by a refrigeration-reheat system and high-velocity water recirculation. The 2450-MHz microwave source was operated in a pulsed mode with power density up to 500 mW/cm/sup 2/. As expected, the survival curve slopes for both cell types increased rapidly with temperature, doubling for each degree Celsius. Microwave irradiation produced no significant change in extrapolation number for either cell type. However, survival curves of CHO cells which received microwaves ...
1981-12-01
International Nuclear Information System (INIS)
Active oxygens produced by low-dose irradiation can induce the synthesis of proteins involved in the active oxygen reduction path and can activate the chemical self-defense mechanisms in vivo, which can alleviate the injuries caused by active oxygens themselves. The following findings suggests that it is not only by low-dose irradiation that can induce the responses described above but also by any physical and/or chemical stresses which can produce small amount of active oxygens in vivo. 1. X-irradiation with 0.5 Gy and/or water immersion and restraint induced heat shock protein (HSP)70 in rat stomach cells. HSP70 was also induced in adrenal cells by paraquat administration. 2. The SOD activity in pancreas of rat significantly increased by #gamma#-irradiation with 0.5 Gy. 0.5 Gy irradiation preceeding the alloxan administration significantly ...
International Nuclear Information System (INIS)
10%Pt/C catalysts were prepared by liquid reduction method. PTFE and Pt/ C catalysts were adhered to porous metal and hydrophobic Pt/C/PTFE catalysts were prepared. The structure and size of Pt crystal particles of Pt/C catalysts were analyzed by XRD, and their mean size was 3.1 nm. The dispersion state of Pt/C and PTFE was analyzed by SEM, and they had good dispersion mostly, but PTFE membrane could be observed on local parts of Pt/C/PTFE surface. Because of low hydrophobicity, Pt/C/ PTFE catalysts have low activity when the mass ratio of PTFE and Pt/C is 0.5: 1, and their catalytic activity increases markedly when the ratio is 1:1. When the ratio increases again, more Pt active sites would be covered by PTFE and interior diffusion effect would increase, which result in the decrease of catalytic activity of Pt/C/PTFE. By PTFE pretreatment of porous metal carrier, the activity of ...
2007-09-01
Activated charcoal and its industrial use. Aktivkohle und ihre industrielle Anwendung
Energy Technology Data Exchange (ETDEWEB)
Since the beginning of the large-scale technical manufacture of activated charcoal at the start of the century, this product has become increasingly important. Activated charcoal is a central part today of many chemical industrial processes. Furthermore, the purification of exhaust air and liquid wastes is often based on the adsorption by activated charcoal. The constantly increasing hygienic demands made of our drinking water may also often only be fulfilled by using activated charcoal. The highly developed adsorption technique of today is considerably supported by continuous improved quality of the products which can only be achieved by progress in manufacturing techniques. The large-scale use of activated charcoal has only become possible for a series of tasks by developing suitable reactivation methods. The last German-language monograph on ...
1980-01-01
Radius of thawing around an injection well and time of complete freezeback
An approximate method of calculating the radius of thawing around an injection well is presented. The method is based on the assumption that for a cylindrical system the position of the phase interface in the Stefan problem can be approximated through two functions: one function determines the position of the melting-temperature isotherm in the problem without phase transitions and the second function does not depend on time. The adjusted heating time concept was used to describe the first function. The second function is a known analytical relationship and is expressed in terms of ice content, thermal properties of thawed/frozen formations, formation temperature and the temperature of the injected fluid. Simple approximate formulae are suggested to estimate the duration of the freezeback period. To verify the proposed formulae, the results of numerical solutions were used. An example which shows that the duration of the ...
2006-06-01
British Library Electronic Table of Contents (United Kingdom)
In this paper we review and classify the various patterns of isosteric heat versus loading for adsorption of gases on graphitised thermal carbon black at temperatures ranging from below the 3D triple point to temperatures above it, but less than the 3D critical point. We have identified the features of heat curve and highlighted the microscopic origin of these features. The patterns vary with temperature and with the relative strength of the fluid-fluid interaction and solid-fluid interaction. For simple adsorptives (by simple we meant there is no strong association between fluid particles), the heat curve is typified by fluid-fluid attraction and layering phenomena. For adsorptives showing strong association such as water, ammonia and methanol, the heat curve essentially begins below the ...
2008-01-01
Energy Technology Data Exchange (ETDEWEB)
In 1996, the National Marine Fisheries Service and the University of Washington completed the fourth year of a multi-year study to estimate survival of juvenile salmonids (Oncorhynchus spp.) passing through dams and reservoirs on the Snake River. Actively migrating smolts were collected near the head of Lower Granite Reservoir and at Lower Granite Dam, tagged with passive integrated transponder (PIT) tags, and released to continue their downstream migration. Individual smolts were subsequently detected at PIT-tag detection facilities at Lower Granite, Little Goose, Lower Monumental, McNary, John Day and Bonneville Dams. Survival estimates were calculated using the Single-Release (SR) and Paired-Release (PR) Models. Timing of releases of tagged hatchery steelhead (O. mykiss) from the head of Lower Granite Reservoir and yearling chinook salmon (O. tshawytscha) from Lower Granite Dam in 1996 spanned the major portion of their juvenile migrations. Specific research ...
1998-02-01
HALO - the helium and lead observatory for supernova neutrinos
Energy Technology Data Exchange (ETDEWEB)
The Helium and Lead Observatory (HALO) is a supernova neutrino detector under development for construction at SNOLAB. It is intended to fulfill a niche as a long term, low cost, high livetime, and low maintenance, dedicated supernova detector. It will be constructed from 80 tonnes of lead, from the decommissioning of the Deep River Cosmic Ray Station, and instrumented with approximately 384 meters of {sup 3}He neutron detectors from the final phase of the SNO experiment. Charged- and Neutral-Current neutrino interactions in lead expel neutrons from the lead nuclei making a burst of detected neutrons the signature for the detection of a supernova. Existing neutrino detectors are mostly of the water Cerenkov and liquid scintillator types, which are primarily sensitive to electron anti-neutrinos via charged-current interactions on the hydrogen nuclei in these materials. By contrast, the large neutron excess of a heavy nucleus like Pb acts to Pauli-block p)n ...
2008-11-01
Advanced thermally stable jet fuels: Technical progress report, October 1994--December 1994
There are five tasks within this project on thermally stable coal-based jet fuels. Progress on each of the tasks is described. Task 1, Investigation of the quantitative degradation chemistry of fuels, has 5 subtasks which are described: Literature review on thermal stability of jet fuels; Pyrolytic and catalytic reactions of potential endothermic fuels: cis- and trans-decalin; Use of site specific {sup 13}C-labeling to examine the thermal stressing of 1-phenylhexane: A case study for the determination of reaction kinetics in complex fuel mixtures versus model compound studies; Estimation of critical temperatures of jet fuels; and Surface effects on deposit formation in a flow reactor system. Under Task 2, Investigation of incipient deposition, the subtask reported is Uncertainty analysis on growth and deposition of particles during heating of coal-derived aviation gas turbine fuels; under Task 3, Characterization of solid gums, sediments, and carbonaceous deposits, ...
1995-02-01
Energy Technology Data Exchange (ETDEWEB)
The article has three sections. The first discusses the environmental problems the tanker traffic poses to the Norwegian coastal waters and shores. Various precautionary measures and requirements are briefly presented. The size of the present marine transportation and the future Russian marine petroleum activity in the Barents area are briefly mentioned. The second named, conflicting exploration drilling, presents the conflicting interests regarding exploratory drilling in the Barents Sea in Norway. The environmental problems are large and have lead to an on-going reevaluation. Some pollution abatement measures are mentioned. The regional economic development is briefly outlined. The third deals with the Norwegian governmental safety activities and presents a brief survey of the official safety activities in the petroleum sector in Norway and the international cooperation particularly with the Russian ...
2003-07-01
Urinary catecholamines in iron deficiency anemia: effects of environmental temperature
Energy Technology Data Exchange (ETDEWEB)
Iron deficiency (ID) is associated with increased levels of norepinephrine (NE) in plasma and urine. They investigated the effect of 5-7 days exposure to three different environmental temperatures (10/sup 0/C, 24/sup 0/C, 30/sup 0/C) on urinary catecholamine levels to test the hypothesis that increased thermogenic activity is causal to this increased excretion in iron deficiency. Catecholamines were analyzed from acidified urine by HPLC-EC. The mean Hb in ID animals was 3.1 +/- .5 versus controls of 12.8 +/- 9. These data demonstrate that contrary to previous reports NE excretion is not normalized at a thermoneutral temperature and suggests a basic abnormality in peripheral SNS activity and NE metabolism in iron deficiency that is independent of environmental drive from thermogenesis.
1986-03-05
British Library Electronic Table of Contents (United Kingdom)
A solvent extraction method was developed to obtain methanolic extracts rich in antioxidants from banana peel. Central composite design ''2^3+star'' and response surface methodology were used in order to optimise the number of extraction steps, extraction temperature and extraction time. The number of extractions was statistically the most significant factor in scavenging activity against both DPPH? and ABTS?^+ radicals and in the inhibition of TBARS formation, while the extraction temperature had an important impact on the capacity to prevent b-carotene bleaching. However, the effect of the extraction time on antioxidant activity was less important. The optimum values of the factors that influence the capacity to scavenge DPPH? and ABTS?^+ radicals or to inhibit b-carotene bleaching were ...
2010-01-01
British Library Electronic Table of Contents (United Kingdom)
The winter syndrome in the gilthead sea bream Sparus aurata indicates that the species is exposed to critically low temperatures in Mediterranean aquaculture in winter. The present study of metabolic patterns and molecular stress responses during cold exposure was carried out to investigate this ?disease?, in light of the recent concept of oxygen and capacity limited thermal tolerance. The metabolic profile of fuel oxidation was examined by determining the activities of the enzymes hexokinase (HK), aldolase (Ald), pyruvate kinase (PK), l-lactate dehydrogenase (l-LDH), citrate synthase (CS), malate dehydrogenase (MDH) and 3-hydroxyacyl CoA dehydrogenase (HOAD) in heart, red and white muscle after exposure to temperatures of 10, 14 and 18?C. Especially, the increase in LDH activity combined ...
2010-01-01
Platinum-based ternary catalysts for low temperature fuel cells. Part 2. Electrochemical properties
Energy Technology Data Exchange (ETDEWEB)
The development of high performance electrode materials is currently one of the main activities in the field of the low temperature fuel cells, fuelled with H{sub 2}/CO or low molecular weight alcohols. A promising way to attain higher catalytic performance is to add a third element to the best binary catalysts actually used as anode and cathode materials. In Part I of this review an overview of the preparation and structural characteristics of Pt-based ternary catalysts was presented. This part of the review deals with the electrochemical properties of these catalysts regarding their CO tolerance and electrocatalytic activity for methanol and ethanol oxidation in the case of anode materials, and their activity for oxygen reduction and stability in fuel cell conditions when used as cathode materials. (author)
2007-07-31
Lowering the activation temperature of TiZrV non-evaporable getter films [for LHC
In order to reduce the activation temperature of the TiZrV alloy, thin films of various compositions were produced by three-cathode magnetron sputtering on stainless-steel substrates. For the characterisation of the activation behaviour the surface chemical composition has been monitored by Auger electron spectroscopy during specific in situ thermal cycles. The volume elemental composition of the film has been measured by energy dispersive X-ray spectroscopy and the morphology (crystal structure and size of the crystallites) has been investigated by X-ray diffraction. The criteria indicating the sample quality and its dependence on film structure and chemical composition are presented and discussed. (13 refs).
2001-01-01
Wax and hydrate control with electrical power
Energy Technology Data Exchange (ETDEWEB)
Electrical heating of subsea flowlines is an effective way to prevent wax and hydrate information, especially for long transportation distances and in low-temperature deep water. Systems are available for use in conjunction with bundles, pipe-in-pipe, and wet-thermal-insulation systems. These systems provide environmentally friendly fluid-temperature control without chemicals or flaring for pipeline depressurizing. Enhanced production is achieved because no time is lost by unnecessary depressurizing, pigging, heating-medium circulation, or removal of hydrate and wax blockages. The seabed temperature at 100-m and greater water depths may range from 7 to {minus}1.5 C, causing a rapid cooling of the hot well streams being transported in subsea flowlines. Under these supercooling conditions, vulnerable crude oils and multiphase compositions will deposit wax and asphalts; also the ...
1997-08-01
Energy Technology Data Exchange (ETDEWEB)
This paper elucidates morphological characteristics, reproduction forms and ecological characteristics of Plectus sp. and Rhabditis sp. which are most frequently detected nematodes separated from tap water. The paper also discussed experimentally establishment of cultivating conditions for these nematodes, and behavior and reproduction characteristics of nematodes under widely ranging conditions of temperatures, bacteria concentrations and pH. Plectus sp. grows in hermaphroditic individuals, while Rhabditis sp. grows only in female. An LE culture medium can cultivate nematodes that appear in tap water, and is suitable for subculture of nematodes. Conditions of temperatures from 20{degree}C to 25{degree}C, pH and inoculated concentration of bacteria at 10{sup 8} cell {center_dot} ml{sup -1} are suitable for reproduction of Plectus sp. and Rhabditis sp. Plectus sp. and Rhabditis sp. prefer mild ...
1996-08-10
Experimental evaluation of a non-azeotropic working fluid for geothermal heat pump system
Energy Technology Data Exchange (ETDEWEB)
Geothermal energy resources are found in many countries. A reasonable and efficient utilization of these resources has been a worldwide concern. The application of geothermal heat pump systems (GHPS) can help increase the efficiency of using geothermal energy and reduce the thermal pollution to the earth surface. However, this is only possible with a proper working fluid. In this paper, a non-azeotropic working fluid (R290/R600a/R123) is presented for a GHPS where geothermal water at 40-45{sup o}C and heating network water at 70-80{sup o}C serve as the low and high temperature heat sources. Experimental results show that the coefficient of performance (COP) of a GHPS using the working fluid is above 3.5 with the condensation temperature above 80{sup o}C and the condensation pressure below 18 bar, while the temperature of the geothermal water is reduced from ...
2004-06-01
Experimental evaluation of a non-azeotropic working fluid for geothermal heat pump system
International Nuclear Information System (INIS)
Geothermal energy resources are found in many countries. A reasonable and efficient utilization of these resources has been a worldwide concern. The application of geothermal heat pump systems (GHPS) can help increase the efficiency of using geothermal energy and reduce the thermal pollution to the earth surface. However, this is only possible with a proper working fluid. In this paper, a non-azeotropic working fluid (R290/R600a/R123) is presented for a GHPS where geothermal water at 40-45 deg. C and heating network water at 70-80 deg. C serve as the low and high temperature heat sources. Experimental results show that the coefficient of performance (COP) of a GHPS using the working fluid is above 3.5 with the condensation temperature above 80 deg. C and the condensation pressure below 18 bar, while the temperature of the geothermal water is reduced from 40-46 ...
2004-06-01
Binary heat pump system. Binary heat pump system
Energy Technology Data Exchange (ETDEWEB)
This technical report describes an outline, features, total energy efficiency, and specifications of binary heat pump system. A closed circuit distributed water heat source heat pump method is employed in the binary heat pump system. Since the circulating water, which is adjusted at a constant temperature, is used as the heat source of the indoor unit, a stable performance can be obtained regardless of outside atmospheric temperature. The binary heat pump system is mainly composed of a center heat pump unit, indoor heat pump unit, heat source water pipes, and circulating pump. The center heat pump unit and the indoor heat pump unit are connected with each other by the heat source water, and each unit can be operated independently. This system is characterized by the simultaneous operation of cooling and heating, high efficiency, high energy saving, high ...
1993-11-30
Energy Technology Data Exchange (ETDEWEB)
The pilot area of the Vyngapour oil field allotted for MIOR tests contains three injection and three producing wells. These wells were treated in summer 1993 and 1994. Before, during, and after MIOR treatments on the pilot area the chemical compounds of injected and formation waters were studied, as well as the amount and species of microorganisms entering the stratum with the injected water and indigenous bacteria presented in bottomhole zones of the wells. The results of monitoring showed that the bottomhole zone of the injection well already had biocenosis of heterotrophic, hydrocarbon-oxidizing, methanogenic, and sulfate-reducing bacteria, which were besides permanently introduced into the reservoir during the usual waterflooding. The nutritious composition activated vital functions of all bacterial species presented in the bottomhole zone of the injection well. The formation waters from producing ...
1995-12-31
Sustainable water resources management in Pakistan
International Nuclear Information System (INIS)
Total river discharge in Pakistan in summer season vary from 3 thousand to 34 thousand cusses (100 thousand Cusses to 1,200 thousand Cusses) and can cause tremendous loss to human lives, crops and property, this causes the loss of most of the flood water in the lower Indus plains to the sea. Due to limited capacity of storage at Tarbela and Mangla Dams on river Indus and Jhelum, with virtually no control on Chenab, Ravi and Sutlej, devastating problems are faced between July and October in the event of excessive rainfall in the catchments. Due to enormous amounts of sediments brought in by the feeding rivers, the three major reservoirs -Tarbela, Mangla and Chashma will lose their storage capacity, by 25 % by the end of the year 2010, which will further aggravate the water-availability situation in Pakistan. The quality of water is also deteriorating due to urbanization and industrialization and agricultural developments. On ...
2004-06-07
Energy Technology Data Exchange (ETDEWEB)
Measurements were completed on the solubility of cupric and cuprous oxides in liquid water and steam at controlled pH conditions from 25 to 400 C (77 to 752 F). The results of this study have been combined with those reported from this laboratory in two previous EPRI reports to provide a complete description of the solubility of these oxides and the speciation of copper dissolved in liquid water and steam as a function of oxidation state, temperature, pH, and in the case of steam, pressure. These constitute the first set of reliable data for cuprous oxide solubility over this range of conditions. For the more intensively studied CuO case, agreement was found between our results and those of previous studies of its solubility in steam, whereas only partial agreement was evident for its solubility in liquid water. For both oxides this disagreement often amounted to orders of magnitude. The solubility of ...
2004-05-01
Use of organic water treatment chemicals
International Nuclear Information System (INIS)
For better understanding and proper use of organic chemicals addition data are needed, including kinetic data on the scavenging reactions in actual cycles, data on ambient temperature stability and decomposition, sampling and analsyis information, data on effects in a case of fire, and more corrosion data. Use of these chemicals for layup of boilers and other equipment needs to be evaluated for each application. After a preliminary evaluation, such as outlined in this report, every new water treatment chemical should be evaluated in at least two month test in actual steam cycle. (orig.).
Energy Technology Data Exchange (ETDEWEB)
This paper describes statistical methods used to evaluate data for toluene (at several typical operating temperatures and humidity levels) and to determine which measure of humidity (relative or absolute) is more important in determining carbon adsorption efficiency. The water content of a solvent-laden stream is critical for its control via carbon adsorption, especially at relative humidities about 50-70%. (Relative humidity is the percent of saturation: absolute humidity is the total water content.)
1989-01-01
Stability constants of At(I)-complexes with thiourea, iodide and mixed ligands in ethanol and water
International Nuclear Information System (INIS)
The ion mobilities of |"2"1"1At|At(I) in dependence on thiourea (tu) concentration, iodide concentration and a mixture of both ligands were measured by the electromigration method in free electrolytes. An equilibrium model was developed for the characterization of electromigration curves which permitted the calculation of stability constants and ion mobilities of the complexes |AtI|, |AtI_2|"-, |Attu|"+, |Attu_2|"+ and |AtItu| existing in these solutions. Ethanol and water served as solvents. The temperature was 298 K and the ionic strength was about 0.05 mol/dm"3. (author) 16 refs.; 2 figs.
Lightweight bricks manufactured from water treatment sludge and rice husks.
Novel lightweight bricks have been produced by sintering mixes of dried water treatment sludge and rice husk. Samples containing up to 20 wt.% rice husk have been fired using a heating schedule that allowed effective organic burn-out. Rice husk addition increased the porosity of sintered samples and higher sintering temperatures increased compressive strengths. Materials containing 15 wt.% rice husk that were sintered at 1100 degrees C produced low bulk density and relatively high strength materials that were compliant with relevant Taiwan standards for use as lightweight bricks. PMID:19596512
2009-06-17
Drilling mud for application during the drilling of caving-prone rock
Energy Technology Data Exchange (ETDEWEB)
The authors propose a drilling solution for use in caving-prone rock formations. This solution contains clay, hydrolized polyacrylonitrile, and water. In order to improve the solution's inhibitive properties during high-temperatures, azodicarbonamide (the blowing agent ChKhZ-21) is introduced in adequate quantities. The solution's makeup is as follows, given by percentage of weight,-- Clay 5-8%; hydrolized polyacrylonitrile 0.1-0.5%; azodicarbonamide (the blowing agent ChKhZ-21) 1-3%, with the remainder being water.
1981-01-01
Comparison of Atmospheric Dispersion Models Between PHWR and PWR
International Nuclear Information System (INIS)
The radiation dose and the atmospheric dispersion for Pressurized Heavy Water Reactors (PHWR) are based on the CAN/CSA N288.2-M91 standards: for Pressurized Water Reactor (PWR) on the NRC Regulatory Guide 1.145. There are some differences between in the methodologies used in the standards, including the atmospheric dispersion model, the release height, the temperature lapse rate, the cutoff condition. This paper reports on a comparison of standards for atmospheric dispersion models of PHWRs and PWRs in order to determine which one is the more conservative. The comparison between PHWR and PWR for atmospheric dispersion factors and radiation doses confirms that there are no big differences
2010-10-01
Vegetation re-establishment on a hardwood forest site denuded by brine
Energy Technology Data Exchange (ETDEWEB)
Brine from active oil wells seeped through the soil of a forested site in north-western Pennsylvania and killed all vegetation in its path, leaving the affected area unproductive and unsightly. After the brine source was eliminated, herbaceous plants, shrubs and forest tree seedlings became established and developed rapidly. Establishment began in the first year and by Year 4 the site had developed into a healthy young forest. Results show that Allegheny hardwood forest sites damaged by brine water will rapidly revegetate once the brine water discharge is stopped if there is a seed supply and if the area is fenced to exclude deer. 3 figs., 12 refs.
1989-04-01
Energy Technology Data Exchange (ETDEWEB)
Technical Development Document supporting proposed water discharge regulations for the Coal Mining Industry authorized by the Clean Water Act. Proposed regulations include revised best practicable technology limitations, best available technology limitations and new source performance standards for the Coal Mining Industry. Industry operations include: coal preparation and amillary operations, active mining, F bituminous, anthracite and lignite coal, and the reclamation phase of mining.
1981-01-01
Energy Technology Data Exchange (ETDEWEB)
This Reference Book contains a current copy of the Clean Water Act (Section 404) and the Rivers and Harbors Act (Sections 9 and 10) and those regulations that implement those sections of the statutes and appear to be most relevant to DOE activities. The document is provided to DOE and contractor staff for informational purposes only and should not be interpreted as legal guidance. Updates that include important new requirements will be provided periodically. Questions concerning this Reference Book may be directed to Mark Petts, IH-231 (FTS 896-2609 or Commercial 202/586-2609).
1992-03-01
Clean Water Act (Section 404) and Rivers and Harbors Act (Sections 9 and 10)
Energy Technology Data Exchange (ETDEWEB)
This Reference Book contains a current copy of the Clean Water Act (Section 404) and the Rivers and Harbors Act (Sections 9 and 10) and those regulations that implement those sections of the statutes and appear to be most relevant to DOE activities. The document is provided to DOE and contractor staff for informational purposes only and should not be interpreted as legal guidance. Updates that include important new requirements will be provided periodically. Questions concerning this Reference Book may be directed to Mark Petts, IH-231 (FTS 896-2609 or Commercial 202/586-2609).
1992-03-01
International Nuclear Information System (INIS)
Problem areas in BWRs, PWRs and PHWRs, from the viewpoint of chemistry, and the problem of fission product release in nuclear reactors are discussed. These problem areas are : fuel performance, off-normal water chemistry due to condenser leaks, the transport and deposition of the activated corrosion and fission products, denting in steam generators (in the case of PWRs), ingress of air in the cover gas helium and consequent radiolysis of D_2O in the moderator circuit (in the case of PHWRs). (M.G.B.).
1981-05-01
Energy Technology Data Exchange (ETDEWEB)
Analyzing various SBLOCA with high pressure safety injection (HPSI) at VVER-440/213, we met a surprising phenomenon - a 'natural' circulation post SG heat transfer reversal. This is not usual, because normal natural circulation (NC) in primary circuit is connected with positive heat transfer at SG. If there is reverse heat transfer at SG (as soon as the break enthalpy outflow is sufficient for removal of reactor decay heat), it should obstruct any natural circulation. The question was, what is the driving force of this 'non-standard natural circulation'. After all we revealed that force - it is the density difference between the colder water in reactor downcomer (cold water from HPSI) and warmer water in inner reactor (lower plenum, core, upper plenum). This phenomenon could be confusing for operating personal, because there would be an opposite temperature difference ...
2001-07-01
International Nuclear Information System (INIS)
Analyzing various SBLOCA with high pressure safety injection (HPSI) at VVER-440/213, we met a surprising phenomenon - a 'natural' circulation post SG heat transfer reversal. This is not usual, because normal natural circulation (NC) in primary circuit is connected with positive heat transfer at SG. If there is reverse heat transfer at SG (as soon as the break enthalpy outflow is sufficient for removal of reactor decay heat), it should obstruct any natural circulation. The question was, what is the driving force of this 'non-standard natural circulation'. After all we revealed that force - it is the density difference between the colder water in reactor downcomer (cold water from HPSI) and warmer water in inner reactor (lower plenum, core, upper plenum). This phenomenon could be confusing for operating personal, because there would be an opposite temperature difference at the loop than by normal natural ...
2001-03-20
Thermoactivation of viruses by microwaves
Energy Technology Data Exchange (ETDEWEB)
Eight different viruses, suspended in drinking water, were examined for their ability to be inactivated by microwaves from a microwave oven. Up to a virus content of 10/sup 5/ TCID/sub 50//ml inactivation was successful within a few minutes of microwave treatment and occurred in parallel to the heat stability of the viruses. Evidence for direct effects of microwaves on viruses could not be detected. 7 of the viruses studied were inactivated rapidly when temperatures of 50 to 65/sup 0/C under microwave treatment were reached in the flowing water, while a bovine parvovirus was only inactivated by temperatures above 90/sup 0/C. The advantages of a thermal virus-decontamination of fluids and material by microwaves are discussed.
1981-01-01
Within the framework of the cluster approach and the semiempirical SCF MO LCAO method in the CNDO/BW valence approximation, possible pathways have been compared for the dehydroxylation of aluminosilicate systems. It has been shown that dehydroxylation as a result of splitting of a water molecule from an acidic bridge hydroxyl group and a more basic terminal group Al-OH is the most energyfavorable. Apparently, such a dehydroxylation pathway is primarily characteristic for amorphous aluminosilicates. Typical of crystalline aluminosilicates at moderate heat-treating temperature is dehydroxylation through splitting of a water molecule from an acidic bridge hydroxyl group and a neutral Si-OH group; at higher temperatures, there is a possible pathway of dehydroxylation of highsilica zeolites as a result of condensation of two acidic surface hydroxyls.
1986-07-01
Monitoring transplanting operation of rice crop using passive microwave radiometer data
British Library Electronic Table of Contents (United Kingdom)
This study highlights a methodology to detect the transplanting operation of wetland rice at a regional scale using SSM/I brightness temperature in frequencies like 19, 37 and 85 GHz with vertical polarization. A cloud removal algorithm was used to make weekly composites of the brightness temperature, which were used to estimate the soil wetness index (SWI). Flooding of rice fields with water for transplanting induces very high change in SWI due to contrasting dielectric constant of water (80) and soil (4). Different weather conditions and fractional wet area under the footprint of sensor affect SWI, hence absolute value of SWI was not adequate. Therefore, multi-year SWI anomaly was used to generate a threshold value of SWI change to detect when SWI change between two consecutive weeks was...
2011-01-01
Energy Technology Data Exchange (ETDEWEB)
Excitation of low temperature helium or helium/water plasma and subsequent exposure to air of polyacrylonitrile (PAN) ultrafiltration membranes was used to hydrophilize the surface of these materials. We analyzed the effectiveness of this approach as a function of plasma operating variables including gas phase composition, plasma power, treatment time and system pressure. Following the changes in physical and chemical composition of the PAN surface resulting from these modifications was a major aspect of this work. Techniques such as the captive bubble contact angle method, ellipsometry, ESCA, and FTIR-ATR were all used. In addition, the formation and life-time of peroxides during these processes were determined. At low powers (<25W) and short treatment periods ({<=}30 sec), the main chemical conversion of PAN surfaces was simultaneous hydrophilization and stabilization via PAN cyclization. Relatively small water ...
1995-12-01
Influence of recycling and temperature on the swelling ability of paper
British Library Electronic Table of Contents (United Kingdom)
Hornification is the loss of fiber wall swelling which is detrimental to subsequent recycling resulting from drying. It is known that dried fibers lose their conformability and swelling capacity. The effect of recycling treatment on the swelling ability of hardwood bleached kraft pulp fibers was determined. Modelling paper recycling, sheets were recycled using heat treatment (23?C, 60?C, 100?C). The results were compared with those for natural fibers from bleached kraft pulp. Swelling kinetics of sheets was measured by a modified method monitoring interactions of pulp with water. Swelling ability decreased during the recycling in comparison with never-recycled pulp at all temperatures. Recycling of sheets caused only small changes in the cupri-ethylene-diamine viscosity, however, the water...
2011-01-01
International Nuclear Information System (INIS)
The phase separation of (water + salt + polyethylene glycol 15000) systems was studied by cloud-point measurements using the particle counting method. The effect of three kinds of sulphate salt (Na2SO4, K2SO4, (NH4)2SO4) concentration, polyethylene glycol 15000 concentration, mass ratio of polymer to salt on the cloud-point temperature of these systems have been investigated. The results obtained indicate that the cloud-point temperatures decrease linearly with increase in polyethylene glycol concentrations for different salts. Also, the cloud points decrease with an increase in mass ratio of salt to polymer.
2009-07-01
Energy Technology Data Exchange (ETDEWEB)
Treatment of coal or coconut shell activated carbons with either phosgene or chlorine at 180{degree}C followed by washing with methanol or water results in chlorinated carbons with very similar pore structures to their precursors. Water adsorption experiments show that the modified materials are relatively hydrophobic, presumably as a result of replacement of oxygen-containing surface groups by chlorine. Adsorption of the model hydrophobic vapour chloropicrin from humid air is usually better for the modified carbons which, unlike the controls, do not appear to be subject to degradation in performance on ageing in a humid atmosphere. The stability of the modified carbons is probably a consequence of the chlorination of those sites on the control carbons that are prone to ready oxidation or hydroxylation. 1 tab., 2 figs., 17 refs.
1992-01-01
International Nuclear Information System (INIS)
Tarapur Atomic Power Station unit-4 is first 540 MWe pressurized heavy water reactor. Heavy water is used as the coolant and moderator. With reactor operation tritium is formed by absorption of neutron by Deuterium atoms. Experience in the 220 MWe indicates that tritium is main contributor to the internal dose of radiation workers. Study on Tritium build up in Primary Heat Transport (PHT) and Moderator (MOD) system was carried out at the initial stage of the operation of the unit-3 and 4. This paper brings out tritium activity buildup in the PHT and MOD systems and its comparison with 220 MWe reactors. This paper helps in estimation of the internal dose contribution to the radiation workers at TAPS 3 and 4. (author)
2006-11-13
International Nuclear Information System (INIS)
Tarapur Atomic Power Station unit-4 is first 540 MWe pressurized heavy water reactor. Heavy water is used as the coolant and moderator. With reactor operation tritium is formed by absorption of neutron by deuterium atoms. Experience in the 220 MWe indicates that tritium is main contributor to the internal dose of radiation workers. Study on tritium build up in Primary Heat Transport (PHT) and Moderator (MOD) system was carried out at the initial stage of the operation of the unit-4. This paper brings out tritium activity buildup in the PHT and MOD systems and its comparison with 220 MWe reactors. This paper helps in estimation of the internal dose contribution to the radiation workers at TAPS 3 and 4. (author)
2005-11-23
Photocatalytic degradation of gaseous pyridine over zeolite-supported titanium dioxide
Energy Technology Data Exchange (ETDEWEB)
The photocatalyzed degradation of pyridine in the gas phase was investigated using titanium dioxide semiconductor supported on mordenite. The complete mineralization was found to occur over a catalyst containing 75 wt% TiO{sub 2} and 25 wt% mordenite in about 180 min in the presence of saturated water vapor at O{degrees}C (4.6 Torr). Low water vapor pressure of 0.096 Torr was found to be sufficient to achieve a reasonably high percentage and rate of degradation. Diffusion of pyridine within the catalyst adversely affects the activity when the thickness of the catalyst coating exceeds the penetration depth of illumination. The activity of the zeolite-supported catalysts was higher than that of TiO{sub 2}. The photonic efficiency for the complete mineralization of pyridine to CO{sub 2} was determined to be 0.48. 29 refs., 6 refs., 1 tab.
1994-09-01
British Library Electronic Table of Contents (United Kingdom)
An impingement jet system was used to study flow-assisted corrosion (FAC) of 3003 aluminum (Al) alloy in ethylene glycol-water solutions that simulates the automotive coolant by corrosion potential and electrochemical impedance spectroscopy (EIS) measurements as well as computational fluid dynamics (CFD) simulation. The effects of solution pH and fluid impact angle on Al FAC were determined. An increase of solution pH enhances the activity of Al due to dissolution of Al oxide film in alkaline environment. Moreover, Al activity decreases with the increasing fluid impact angle to the specimen. A CFD simulation shows that, with the increase of impact angle, the electrode area under high-velocity flow field decreases and that under low-velocity flow field increases. Consequently, the shear str...
2008-01-01
Energy Technology Data Exchange (ETDEWEB)
To monitor the groundwater contamination and the effectiveness of remedial actions, over a thousand monitoring wells are in active operation (i.e., require quarterly or semi-annual sampling) at SRS. Most wells are expected to continue in operation for another 20 to 40 more years. Required sample volumes can range from a less than a liter to 10 liters. To support the long-term groundwater monitoring requirements of these wells, SRS actively seeks technologies that can maximize data acquisition and minimize costs. To meet this end, SRS has implemented the Purge Water Management System (PWMS). The key attributes of this system lie in its ability to reduce or eliminate the generation of purged groundwater, which is costly in terms of the time and management.
2004-02-10
Energy Technology Data Exchange (ETDEWEB)
Crop water demand in the Okanagan Basin was determined for 1961 to 1990, 2010 to 2039, 2040 to 2069, and 2070 to 2099. Daily station temperature data were spatially interpolated to a 1 x 1 km grid and adjusted for elevation. Daily precipitation data were estimated across four climatic regions. Output from three global climate models (GCM), CGCM2, CSIROMk2 and HadCM3 was used to create future daily climate. Daily potential evapo-transpiration (grass reference) was estimated from an empirical relationship between Bellani-plate atmometer readings, temperature and extra-terrestrial solar radiation, and then modified by crop coefficients for all crops except pasture. Depending on GCM, projected water demand increased by 12-20% (2010 to 2039), 24-38% (2040 to 2069) and 40-61% (2070 to 2099). Possible elevated CO{sub 2} effects on stomatal conductance which may reduce water demand were not ...
2006-11-15
International Nuclear Information System (INIS)
The Steam Generator (SG) serves as an interface between primary and secondary cycle in Pressurized Heavy Water Reactor (PHWR). Failure of steam generator tubes result in leaking of active heavy water in the secondary closed loop. In Tarapur Atomic Power Station-3 and 4 (TAPS- 3 and 4), Scintillator detectors are provided to detect on line heavy water leakages in SG and moderator heat exchangers by monitoring Nitrogen-16 ("1"6N) and Oxygen-19 ("1"90) activities. Efficacy of detection of these activities at designed detector position on SG blow down line in presence of background radiation field is analysed theoretically. The count rate of "1"9O and "1"6N estimated at the detector position inside Reactor Building (RB) shows that detectors only respond to very high leak rates due to presence of high background even though sensitivity is appreciably good. For ...
2005-11-23
WASTE SOLIDIFICATION BUILDING BENCH SCALE HIGH ACTIVITY WASTE SIMULANT VARIABILITY STUDY FY2008
Energy Technology Data Exchange (ETDEWEB)
The primary objective of this task was to perform a variability study of the high activity waste (HAW) acidic feed to determine the impact of feed variability on the quality of the final grout and on the mixability of the salt solution into the dry powders. The HAW acidic feeds were processed through the neutralization/pH process, targeting a final pH of 12. These fluids were then blended with the dry materials to make the final waste forms. A secondary objective was to determine if elemental substitution for cost prohibitive or toxic elements in the simulant affects the mixing response, thus providing a more economical simulant for use in full scale tests. Though not an objective, the HAW simulant used in the full scale tests was also tested and compared to the results from this task. A statistically designed test matrix was developed based on the maximum molarity inputs used to make the acidic solutions. The maximum molarity inputs were: 7.39 HNO{sub 3}, 0.11618 ...
2009-03-20
International Nuclear Information System (INIS)
Hoogenstraaten's heating rate method has generally been considered as a reliable method for determining thermoluminescence trapping parameters of first order glow peaks. However, experience has shown that in some cases the deviation between the heating rate method and glow curve fitting method can be quite significant (considering only the linear part of the heating rate plot, of course). In this study it is shown that one of the main reasons for this deviation can be a systematic increase of a temperature lag between the measured and real temperature of the sample with increasing heating rate. It appears that this systematic increase of the temperature lag affects the method in the range of low heating rates (linear part of the heating rates plots) more than has been previously realised. The effect of the temperature lag on Hoogenstraaten's heating rate method is a decrease in ...
1998-07-05
Energy Technology Data Exchange (ETDEWEB)
Hoogenstraaten's heating rate method has generally been considered as a reliable method for determining thermoluminescence trapping parameters of first order glow peaks. However, experience has shown that in some cases the deviation between the heating rate method and glow curve fitting method can be quite significant (considering only the linear part of the heating rate plot, of course). In this study it is shown that one of the main reasons for this deviation can be a systematic increase of a temperature lag between the measured and real temperature of the sample with increasing heating rate. It appears that this systematic increase of the temperature lag affects the method in the range of low heating rates (linear part of the heating rates plots) more than has been previously realised. The effect of the temperature lag on Hoogenstraaten's heating rate method is a decrease in ...
1999-07-01
High temperature strengthening mechanism of hafnium carbide in a tungsten-rhenium matrix
Energy Technology Data Exchange (ETDEWEB)
The interrelationship between the testing temperature and HfC strength increment of an arc-melted W-3.6Re-0.4HfC was determined from 1950 K to 2980 K in a vacuum of better than 1.3{times}10{sup {minus}5} Pa (10{sup {minus}7} torr). The present research was focused on the characteristic temperature at which the rapid coarsening of HfC particles occurred and the effect of the second-phase particle size on the high temperature strength properties of this material. It was found that the HfC particle strengthening was effective in a W-Re matrix up to a characteristic temperature of 2450 K in the short-term tensile test. Carbon was found to be the rate-limiting solute in the HfC particle growth. The strength of HfC strengthened alloy at temperature above 0.5 T{sub m} is proportional to the square root of particle volume fraction. The yield strengths of W-3.6Re-0.26HfC calculated based on ...
1991-01-01
High temperature strengthening mechanism of hafnium carbide in a tungsten-rhenium matrix
International Nuclear Information System (INIS)
The interrelationship between the testing temperature and HfC strength increment of an arc-melted W-3.6Re-0.4HfC was determined from 1950 K to 2980 K in a vacuum of better than 1.3x10"-"5 Pa (10"-"7 torr). The present research was focused on the characteristic temperature at which the rapid coarsening of HfC particles occurred and the effect of the second-phase particle size on the high temperature strength properties of this material. It was found that the HfC particle strengthening was effective in a W-Re matrix up to a characteristic temperature of 2450 K in the short-term tensile test. Carbon was found to be the rate-limiting solute in the HfC particle growth. The strength of HfC strengthened alloy at temperature above 0.5 T_m is proportional to the square root of particle volume fraction. The yield strengths of W-3.6Re-0.26HfC calculated based on the particle statistical ...
1991-01-06
Thermo-hydraulic characterization of an automotive intercooler for a low pressure EGR application
British Library Electronic Table of Contents (United Kingdom)
In this work an experimental study is carried out to determine the thermo-hydraulic performance of an intercooler (IC) with flat tubes provided with triangular plain internal fins and louvered external fins when it is used on a car equipped with a low pressure EGR. The main unknowns to be answered are the thermo-hydraulic characteristics of the IC working under humid conditions induced by EGR, the conditions under which the water content in the mixture of air and exhaust gases begins to condense and the conditions under which the condensed water will be retained inside the IC. The exhaust gases are here replaced by a mixture of dry air and water vapour which are mixed upstream of the IC. The IC is submitted at the following testing conditions: on the ambient air side, the air temperature i...
2011-01-01
Sodium gluconate as corrosion and scale inhibitor of ordinary steel in simulated cooling water
Energy Technology Data Exchange (ETDEWEB)
The effect of sodium gluconate anion (SG) on the corrosion and scale inhibition of ordinary steel in simulated cooling water has been studied using weight loss, polarisation curves, electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM) techniques. SG was studied in concentration from 10{sup -4} M to 10{sup -1} M. Results obtained reveal that SG perform excellently as corrosion and scaling inhibitor for ordinary steel in simulated cooling water. An increase of SG concentration leads to the increase of the corrosion potential towards the positive direction. The inhibition efficiency was a low temperature dependence. The inhibitor mechanism was treated as an adsorption process according to Langmuir adsorption isotherm. The SEM/EDAX data show that was a corrosion and scale inhibitor.
2008-06-15
Sodium gluconate as corrosion and scale inhibitor of ordinary steel in simulated cooling water
British Library Electronic Table of Contents (United Kingdom)
The effect of sodium gluconate anion (SG) on the corrosion and scale inhibition of ordinary steel in simulated cooling water has been studied using weight loss, polarisation curves, electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM) techniques. SG was studied in concentration from 10-4M to 10-1M. Results obtained reveal that SG perform excellently as corrosion and scaling inhibitor for ordinary steel in simulated cooling water. An increase of SG concentration leads to the increase of the corrosion potential towards the positive direction. The inhibition efficiency was a low temperature dependence. The inhibitor mechanism was treated as an adsorption process according to Langmuir adsorption isotherm. The SEM/EDAX data show that was a corrosion and scale inhi...
2008-01-01
British Library Electronic Table of Contents (United Kingdom)
Possible factors regulating phytoplankton variability in the Arabian (Persian) Gulf were analyzed on the basis of satellite observations and meteorological data (1997-2009), including remotely-sensed chlorophyll a concentration (CHL), sea surface temperature, wind, solar radiation, precipitation, and aerosols. Shallow waters of northwestern Gulf influenced by Shatt Al-Arab River discharge were more productive than open Gulf waters, although seasonal CHL patterns in this and other shallow regions looked unrealistic likely because the CHL signal was obscured by bottom reflection. Therefore our further analyses focused on the open Gulf waters, which show a subtropical seasonal CHL cycle with maximum in winter and minimum in spring-summer. This cycle, however, was decoupled from the seasonal e...
2010-01-01
Energy Technology Data Exchange (ETDEWEB)
Sulfuric acid hydrogen peroxide mixtures (SPM) are commonly used in the semiconductor industry to remove organic contaminants from wafer surfaces. This viscous solution is very difficult to rinse off wafer surfaces. Various rinsing conditions were tested and the resulting residual contamination on the wafer surface was measured. The addition of small amounts of a chemical base such as ammonium hydroxide to the rinse water has been found to be effective in reducing the surface concentration of sulfur and also mitigates the particle growth that occurs on SPM cleaned wafers. The volume of room temperature water required to rinse these wafers is also significantly reduced.
1997-08-01
Evaporation behavior of water and concentration of technetium and rhenium using thin film evaporator
International Nuclear Information System (INIS)
The nuclear energy cycle requires the recycling of nuclear fuel, water, chemical reagents, and the volume reduction of radioactive liquid wastes. A fundamental technique for continuous recovery of water using a thin-film evaporator was examined. Appropriate recovery measurements were: an evaporator heat temperature of 323 K, a feed rate of 0.23 cm"3 x s"-"1, a vacuum pressure of 15 mmHg (2 kPa), and impeller rotational speeds of 500#approx#600 rpm (min"-"1). The concentration of trace technetium and rhenium in aqueous solutions was also studied. A decontamination factor of 10"5 for rhenium was obtained. (author)
1999-06-01
International Nuclear Information System (INIS)
Purpose: To obtain stabilized operation by preventing over heat in emergency cooling pumps upon accidents of flow regulators. Constitution: A pressure suppression chamber pool and a pressure vessel are communicated to each other with a pipeway and the water in the suppression pool is charged by a charging pump to the pipeway. The pipeway is interposed with an emergency cooling pump so as to feed water in the pipeway to the pressure vessel and a water source and the emergency cooling pumps are connected by way of a closed pipeway. Further, the closed pipeway and the pipeway interposed with the charging pump are communicated to each other by way of a connecting pipeway, to which are interposed an instrument for detecting the increase in the temperature of the emergency cooling pumps due to abnormality in the closed pipe (such as troubles in flow regulators) and outputting control signals and an ...
Energy Technology Data Exchange (ETDEWEB)
Haemocyanin serves as normal transporter of oxygen in many Arthropods. The oxygen equilibrium curves have been described for the haemocyanins of many Arthropods and Molluscs. Oxygen equilibrium curves of the blood reveal the relationship between the oxygen tension and the percentage saturation of the haemocyanin. The shape of the oxygen equilibrium curves vary in position from sigmoid to hyperbolic in different animals or even undulatory as shown in some chitons. Oxygen equilibrium curves are known to be influenced by pH, temperature and inorganic ions. The effect of environmental pollutants like the heavy metals on the oxygen equilibrium curves of the fresh water crab has not been previously reported. One of the toxic heavy metals with regard to aquatic organisms is lead. Hence the present study was designed to determine the effect of organic and inorganic lead on the oxygen equilibrium curve of the fresh water crab, ...
1989-02-01
Device for controlling feedwater at low power of nuclear power plants
International Nuclear Information System (INIS)
Purpose: To provide a feedwater control device capable of minimizing the adverse response of steam drum level at low power. Consitution: In order to perform feedwater control at low power by the substantial control of three factors, that is, main steam flow rate, feedwater flow rate and steam drum level, the main steam flow rate is determined from the reactor output and feedwater rate is determined from the changes in the feedwater temperature due to the mixing of waters in the reactor clean up system and feedwater. If a difference is resulted between these flow rates, a starting feedwater regulator is controlled instantly to eliminate the difference. The water level in the steam drum is used for amending the difference from the final set value of the drum water level, by which the adverse response of the steam drum level can be minimized. (Seki, T.).
International Nuclear Information System (INIS)
The ISI (In-Service Inspection) system has been developed so as to maintain the structural integrity of heat transfer tubes in the primary pressurized water cooler in the HTTR (High Temperature Engineering Test Reactor). This system consists of eddy current probes, ultra-sonic probes, insertion and extraction units, positioning unit and so on. Verification and performance tests of the developed ISI system were carried out using mock-up heat transfer tubes in the primary pressurized water cooler. The constitution of the system, R and D results of the inspection probes, and verification and performance test results of the ISI system for heat transfer tubes are described in this paper. (author)
1999-08-22
Energy Technology Data Exchange (ETDEWEB)
The ISI (In-Service Inspection) system has been developed so as to maintain the structural integrity of heat transfer tubes in the primary pressurized water cooler in the HTTR (High Temperature Engineering Test Reactor). This system consists of eddy current probes, ultra-sonic probes, insertion and extraction units, positioning unit and so on. Verification and performance tests of the developed ISI system were carried out using mock-up heat transfer tubes in the primary pressurized water cooler. The constitution of the system, R and D results of the inspection probes, and verification and performance test results of the ISI system for heat transfer tubes are described in this paper. (author)
1999-08-01
British Library Electronic Table of Contents (United Kingdom)
The comprehensive theoretical and experimental study of the adsorption of water and methanol molecules on active sites (carboxyl and phenol hydroxyl groups) on the graphitized thermal carbon black is performed. It is shown that microclusters formed upon the adsorption of these molecules on such sites are characterized by the cyclic structure comprising 4?5 molecules similar to that whose existence was revealed previously in liquid water and on the surface of silver iodide. The analysis of the studied adsorption clusters demonstrated that the formation of such cycles is governed primarily by the hydrogen bonding; however, a definite role is played also by energy effects associated with the changes in the state of molecular motion during adsorption. It is shown that the generalized Langmuir ...
2008-01-01
A study of binary mixture boiling: boiling site density and subcooled heat transfer
Energy Technology Data Exchange (ETDEWEB)
(Boiling site densities and heat-transfer coefficients have been measured for ethanol-water and ethanol-benzene mixtures at 1.01 bar for a heated vertical brass disk. A strong effect of composition on the boiling site density was observed, which was attributed to the nature of the activation of the boiling surface and mass diffusion effects. The boiling heat-transfer coefficient was found to decrease with increasin subcooling, but for the mixtures at a given level of subcooling the decrease was less than that for the single components and azeotropic mixtures.) The heat-transfer coefficient at a given heat flux was seen to be quite insensitive to the very large increase in boiling site density in comparing the pure water and the ethanol-water azeotrope results, leading one to question pool boiling models that predict heat-transfer rates on the basis of boiling site density.
1985-05-01
International Nuclear Information System (INIS)
The microstructures of so called high temperature alloys, which have been developed for service temperatures up to 800"0C, are not necessarily stable at higher temperatures. The mobility of alloying elements is very high in FeCrNi alloys at 950 "0C e.g. iron, chromium or nickel can diffuse up to 0.1 mm distance in one year, which is about a grain diameter. Interstitials like carbon or nitrogen show a four orders of magnitude higher diffusivity than the alloying elements. In addition, the carbon solubility in this type of alloy is reported to be very low. Therefore the alloys are supersaturated with carbon after heat treatment above 1100 "0C and water quenching although the absolute carbon content is very low. At service temperatures around 800"0C the solubility of carbon is still about one order of magnitude lower than at heat treatment temperature. This will ...
1981-05-01
Energy Technology Data Exchange (ETDEWEB)
The purpose of this study is to identify the radiative heat transfer augmentation by a coaxial cylinder introduced in the infinite cylindrical pipe enclosing a participating gas. The gas is either a mixture of water vapor and carbon dioxide or gray. The gas is assumed to be homogeneous at a constant temperature, and has a refractive index of unity. All of the surfaces are opaque and gray, diffusely emitting and reflecting at a constant temperature. The effect of system diameter, diameter ratio, wall emittances, gas and surface temperatures, mixture component on heat transfer augmentation are studied by using the zone method with participating gas radiative properties evaluated from the weighted sum of gray gases model. From the radiative equilibrium condition, the installed wall temperature is formulated and calculated by the iteration method. If the medium is a gray gas, the ...
1992-10-01
Energy Technology Data Exchange (ETDEWEB)
The reactions of native bovine catalase with superoxide and solvated electrons have been investigated using three different methods for generating these reducing substrates: [gamma]-radiolysis of oxygenated or deaerated buffer solutions in the presence of an OH radical scavenger; either xanthine or acetaldehyde with xanthine oxidase; and low-temperature (77 K) [gamma]-radiolysis of buffered ethylene glycol/water solutions with subsequent annealing of samples at 183 K. (Author).
1992-11-01
Oil shale oxidation at subretorting temperatures
Energy Technology Data Exchange (ETDEWEB)
Green River oil shale was air oxidized at subretorting temperatures. Off gases consisting of nitrogen, oxygen, carbon monoxide, carbon dioxide, and water were monitored and quantitatively determined. A mathematical model of the oxidation reactions based on a shrinking core model has been developed. This model incorporates the chemical reaction of oxygen and the organic material in the oil shale as well as the diffusivity of the oxygen into the shale particle. Diffusivity appears to be rate limiting for the oxidation. Arrhenius type equations, which include a term for oil shale grade, have been derived for both the chemical reaction and the diffusivity.
1980-06-01
NEUTRON-ABSORBING BRICKS MADE FROM CaB$sup 6$
nsive neutron-absorbing bricks from commercially available CaB/sub 6/ powder. The bricks are 2 x 3 x 5 in., and are strong enough to withstand normal handling. They last indefinitely; the ones described are now 7 years old, used and stored under normal room temperatures and humidities. The procedure is to make a thick, dry mud with the powder and water, followed by compression in a mold at pressures of about 1 ton/in./sup 2/ or more. The bricks are then baked for 2 hours or longer at a temperature of about 750 deg C. (auth)
1960-05-01
Environmental Research Database
ObjectivesNot EnteredDescriptionMethane hydrate in an ice-like substance consisting of molecules of methane gas combined chemically with water. It is stable at high pressures and low temperatures. Since the ocean floor is normally cold, but temperatures increase with depth inside the Earth, such conditions normally prevail for a few hundred meters below the seafloor where the ocean depth is more than a few hundred metres. Methane beneath the ocean floor is formed by the decomposition of organic material. At the edges of the co [continued...
2006-01-30
Heat recovery in polyester production: a case study
Energy Technology Data Exchange (ETDEWEB)
Energy savings in the synthetic fiber industry could be realized by using autoclave reactor condensate and boiler flue gas heat recovery. The non-cellulose (polyester) production process analysis shows that condensate returning from the reactor to the steam boiler raises inlet temperature, giving a reduced fuel requirement of about 8%. Also, boiler flue gas with a sufficiently high outlet temperature for boiler feed water and combustion air preheating results in further fuel savings. The process with an economizer saves up to 8.44%, and with a combustion air preheater, 6.25%. (Author)
1997-07-01
Energetical analysis of sensitivity of hydrogen embrittlement of ordered alloys
Intermetallic compounds are regarded as highly promising for applications as high temperature structural materials. However, recent studies have demonstrated that a number of ordered alloys exhibit environmental embrittlement when tested in various environments at ambient temperature. When exposed to hydrogen gas or electrolytically charged with hydrogen, a significant ductility loss has been reported. The reaction of water vapor with reactive elements in the crack tip results in the generation of atomic hydrogen which diffuses from the surface to the interior and causes embrittlement. In this paper, the authors try to analyze the sensitivity of hydrogen embrittlement of ordered alloys based upon energetical considerations.
1993-10-01
Restoration of a forested wetland ecosystem in a thermally impacted stream corridor
Energy Technology Data Exchange (ETDEWEB)
The Savannah River Swamp is a 3,020 Ha forested wetland on the floodplain of the Savannah River and is located on the Department of Energy`s Savannah River Site (SRS). Major impacts to the swamp hydrology occurred with the completion of the production reactors and one coal-fired powerhouse at the SRS in the early 1950`s. Water was pumped from the Savannah River, through secondary heat exchangers of the reactors, and discharged into three of the tributary streams that flow into the swamp. This continued from 1954 to 1988 at various levels. The sustained increases in water volume resulted in overflow of the original stream banks and the creation of additional floodplains. Accompanying this was considerable erosion of the original stream corridor and deposition of a deep silt layer on the newly formed delta. Heated water was discharged directly into Pen Branch and water temperature in ...
1995-09-01
Energy Technology Data Exchange (ETDEWEB)
The objective of this study is to develop an artificial neural network (ANN) model to predict the thermal conductivity of ethylene glycol-water solutions based on experimentally measured variables. The thermal conductivity of solutions at different concentrations and various temperatures was measured using the cylindrical cell method that physical properties of the solution are being determined fills the annular space between two concentric cylinders. During the experiment, heat flows in the radial direction outwards through the test liquid filled in the annual gap to cooling water. In the steady state, conduction inside the cell was described by the Fourier equation in cylindrical coordinates, with boundary conditions corresponding to heat transfer between the solution and cooling water. The performance of ANN was evaluated by a regression analysis between the predicted and the experimental values. The ...
2009-10-15
Influence of fly ash on soil physical properties and turfgrass establishment
Energy Technology Data Exchange (ETDEWEB)
A field study (1993-96) assessed the benefits of applying unusually high rates of coal fly ash from power plants as a soil amendment to enhance water retention of soils without adversely affecting growth and marketability of the turf species, centipedegrass (Eremochloa ophiuroides (Munro) Hack.) A Latin Square plot design was employed that included 0 (control, no fly ash applied), 280, 560 and 1120 MgHa {sup -1} application rates of unweathered precipitator fly ash. The fly ash was spread evenly over each plot area, rototilled, and allowed to weather under natural conditions for 8 months before seeding. High levels of soluble salts, indicated by the electrical conductivity of soil extracts, in tandem with an apparent phytotoxic effect from boron, apparently inhibited initial plant establishment as shown by substantially lower germination counts in treated soil. However, plant height and rooting depth were not adversely affected, as were the dry matter yields ...
2001-04-01
Direct solar water splitting cell using water, WO3, Pt, and polymer electrolyte membrane
British Library Electronic Table of Contents (United Kingdom)
A solar water splitting cell composed of WO3, Polymer Electrolyte Membrane (PEM) and Pt was constructed for producing hydrogen from deionized water in sunlight. Spectral responsivity measurements under various temperatures and bias voltages were conducted for the cell using the Incident Photon to Current Efficiency (IPCE) method. For comparison, a known WO3 Photo Electro Chemical (PEC) cell containing H3PO4 electrolyte, WO3/H3PO4/Pt, was tested using the same test method. The WO3/PEM-H2O/Pt cell showed better Quantum Efficiency (QE) performance compared to that obtained from the cell with the chemical electrolyte. For the first time, spectral responsivity of photo water splitting process without bias power was unveiled in the new WO3 cell, demonstrating the self-sustained photo electrolysi...
2009-01-01
Energy Technology Data Exchange (ETDEWEB)
The improvement of the ecological conditions at waste storing reservoirs is an important task of the restoration activity at Production Association (PA) ``Mayak`` (South Urals). The radionuclides mostly {sup 90}Sr, {sup 137}Cs, and chemical pollutants deposited in the reservoir water and in the bottom sediment are very dangerous sources for the contamination of Techa River below the reservoirs and the contamination of groundwater in the surrounding formations. The spreading of radioactive contaminants has both hydrogeological and the chemical features. The thermodynamic approach used to account for physical-chemical interactions between water and the bed rocks based on Gibbs free energy minimization of multicomponent system (H-O-Ca-Mg-K-Na-S-Cl-C-Sr) permitted the authors to calculate the corresponding ionic and complex species existing in the solutions, and to characterize the processes of precipitation and dissolution. ...
1994-07-01
Real-time management of water quality in the San Joaquin River Basin, California.
Energy Technology Data Exchange (ETDEWEB)
In the San Joaquin River Basin, California, a realtime water quality forecasting model was developed to help improve the management of saline agricultural and wetland drainage to meet water quality objectives. Predicted salt loads from the water quality forecasting model, SJRIODAY, were consistently within +- 11 percent of actual, within +- 14 percent for seven-day forecasts, and with in +- 26 percent for 14-day forecasts for the 16-month trial period. When the 48 days dominated by rainfall/runoff events were eliminated from the data set, the error bar decreased to +- 9 percent for the model and +- 11 percent and +- 17 percent for the seven-day and 14-day forecasts, respectively. Constraints on the use of the model for salinity management on the San Joaquin River include the number of entities that control or influence water quality and the lack of a centralized authority to direct their ...
1997-09-01
Crud removal performance with ion exchange resins in BWR plants
Energy Technology Data Exchange (ETDEWEB)
It is needless to say that one of the most important roles of the condensate demineralizer in Japanese boiling water reactors (BWR) is to eliminate such impurities during accidental occurrence of sea water leakage from condensate cooling system. Ion exchange resins packed in condensate demineralizer have also been expected to decrease crud, or corrosion products (CP) in condensate water in order to finally reduce activated corrosion products (ACP) in the reactor coolant loop. It is perceived that crud removal ability of a condensate demineralizer has been improved year by year. And we call this phenomenon as `Aging Effect`. Typical property changes of aged cation exchange resin consisted of an increase of water retention capacity and a change of surface texture. Based on these findings, we formulated a new concept and developed new gel type ion exchange resins for the better crud ...
1996-01-01
Spectrophotometric determination of aluminium ion in drinking water by flow infection analysis
International Nuclear Information System (INIS)
Optimum analytical conditions of the aluminium ion were established by flow injection analysis. Eriochrome Cyanine R(ECR) dye reacts with the aluminium ion at pH 6.0 form a complex that exhibits maximum absorption at 535 nm. Reaction condition including the mixing and the reaction coil length, the concentration and the pH of the buffer solution, temperature, and injection loop volume were optimized to introduce this reaction into flow injection analysis. The results were as follows. A mixing coil length of 0.5 m and a reaction coil length of 4.0 m, the pH 6.0 and 1M of acetate buffer solution, the ECR concentration of 0.56 mM, the reaction temperature of 40 .deg. C, the injection loop volume of 300 #mu#L were chosen as optimum conditions. Under these conditions the detection limit of the aluminium ion was less than 0.05 mg/L and the repeatability was better than 1%. A sampling frequency of 24 times for an hour was achieved. Interfering ions ...
2000-10-01
Mass transfer model for two-layer TBP oxidation reactions
Energy Technology Data Exchange (ETDEWEB)
To prove that two-layer, TBP-nitric acid mixtures can be safely stored in the canyon evaporators, it must be demonstrated that a runaway reaction between TBP and nitric acid will not occur. Previous bench-scale experiments showed that, at typical evaporator temperatures, this reaction is endothermic and therefore cannot run away, due to the loss of heat from evaporation of water in the organic layer. However, the reaction would be exothermic and could run away if the small amount of water in the organic layer evaporates before the nitric acid in this layer is consumed by the reaction. Provided that there is enough water in the aqueous layer, this would occur if the organic layer is sufficiently thick so that the rate of loss of water by evaporation exceeds the rate of replenishment due to mixing with the aqueous layer. This report presents measurements of mass transfer rates for the ...
1994-09-28
Low-head air stripper treats oil tanker ballast water
Energy Technology Data Exchange (ETDEWEB)
Prototype tests conducted during the winter of 1989/90 have successfully demonstrated an economical design for air stripping volatile hydrocarbons from oily tanker ballast water. The prototype air stripper, developed for Alyeska's Ballast Water Treatment (BWT) facility in Valdez, Alaska, ran continuously for three months with an average removal of 88% of the incoming volatile organics. Initially designed to remove oil and grease compounds from tanker ballast water, the BWT system has been upgraded to a three-step process to comply with new, stringent regulations. The BWT biological oxidation process enhances the growth of bacteria present in the incoming ballast water through nutrient addition, aeration, and recirculation within a complete-mixed bioreactor. The average removal of BETX is over 95%, however, occassional upsets required the placement of a polishing air stripper downstream of the ...
1992-02-01
Study on adsorption of methanol onto carbon based adsorbents
Energy Technology Data Exchange (ETDEWEB)
This paper presents the isothermal characteristics of methanol onto two specimens of activated carbons namely Maxsorb III and Tsurumi activated charcoal. Dubinin Raduskevich (D-R) equation is used to correlate the adsorption isotherms and to form the pressure-temperature-concentration diagram for both of the assorted pairs. Experimental results show that the maximum adsorption capacity of Maxsorb III/methanol pair is 1.76 times that of activated charcoal/methanol pair. Employing a time-independent mathematical model, the performance of adsorption cooling cycle using Maxsorb III/methanol and activated charcoal/methanol pairs has been studied and compared with that of three other types of carbon based adsorbent/methanol pairs. Theoretical calculations show the superiority of Maxsorb III/methanol pair for both of air-conditioning and ice-making applications. (author)
2009-11-15
British Library Electronic Table of Contents (United Kingdom)
We describe the cloning and characterization of a mutated thermostable DNA polymerase from Thermus aquaticus (Taq) that exhibits an increased reverse transcriptase activity and is therefore designated for one-step PCR pathogen detection using established real-time detection methods. We demonstrate that this Taq polymerase mutant (Taq M1) has similar PCR sensitivity and nuclease activity as the respective Taq wild-type DNA polymerase. In addition, and in marked contrast to the wild-type, Taq M1 exhibits a significantly increased reverse transcriptase activity especially at high temperatures (>60degreeC). RNA generally hosts highly stable secondary structure motifs, such as hairpins and G-quadruplexes, which complicate, or in the worst case obviate, reverse transcription (RT). Thus, RT at hi...
2010-01-01
Transient Critical Heat Flux tests on a rod bundle simulating Pressurized Water Reactors
International Nuclear Information System (INIS)
Transients induced in nuclear power plants from many sources result in one or more fluid conditions changing with time. Fluid conditions of pressure, inlet temperature, inlet flow, or even system power many change separately or in conjunction with each other. The result of the condition change may be one which induces departure from nucleate boiling. An experimental investigation of transient which were intended to achieve Critical Heat Flux was performed at the Heat Transfer Research Facility of Columbia University for Siemens Nuclear Power Corporation. The transients were set up to include broad ranges of flow and pressure conditions near the operating range of pressurized water reactors. Transient events were dominated by varying single conditions and measuring the response of the system and of the rod thermocouples. Because of coupling effects within the test loop, secondary conditions would also vary. In order to perform controlled tests ...
Assessment of generation temperatures of crude oils
Energy Technology Data Exchange (ETDEWEB)
Biological marker maturity parameters were used to estimate the minimum HC generation temperatures of crude oils from Eastern Hungary. More than 50 oils and oil shows were analysed. Molecular- and homologous-ratios of biological marker compounds (triterpanes, steranes, mono- and triaromatic steroid hydrocarbons) were used as maturation parameters. The oils have at least five maturity stages, i.e. they have been generated under different thermal conditions. The highest reservoir temperature in each group was chosen as the best estimate of the groups' temperature just below the generation temperature, i.e. reservoirs of the group might be expected to be at shallower depths (lower temperatures) than those of the generation zone due to vertical migration into pools. For each maturation level, a threshold temperature range for genesis was inferred from ...
2000-07-01
The Preliminary GAMMA Code Thermal hydraulic Analysis for the Steady State of HTR-10 Initial Core
Energy Technology Data Exchange (ETDEWEB)
This report describes the preliminary thermalhydraulic analysis of HTR-10 steady state full power initial core to provide a benchmark calculation of VHTGR(Very High-Temperature Gas-Cooled Reactors) safety analysis code of GAMMA(GAs Multicomponent Mixture Analysis). The input data of GAMMA code are produced for the models of fluid block, wall block, radiation heat transfer and each component material properties in HTR-10 reactor. The temperature and flow distributions of HTR-10 steady state 10 MW{sub th} full power initial core are calculated by GAMMA code with boundary conditions of total reactor inlet flow rate of 4.32 kg/s, inlet temperature of 250 .deg. C, inlet pressure of 3 MPa, outlet pressure of 2.992 MPa and the fixed temperature at RCCS water cooling tube of 50 .deg C. The calculation results are compared with the measured solid material temperatures at ...
2006-07-15
Energy Technology Data Exchange (ETDEWEB)
The effect of thermal pretreatment in N[sub 2] up to 723 K and the activation treatments in H[sub 2] and an inert atmosphere on the properties of Ni and Co activated-charcoal-supported catalysts were studied. Catalysts were characterized by means of N[sub 2] adsorption at 77 K, H[sub 2] chemisorption at room temperature, thermogravimetric analysis (TGA), X-ray diffraction (XRD), and transmission electron microscopy (TEM). The catalysts' activity and selectivity for acetone hydrogenation to 2-propanol under unusual and severe conditions (473 K and high overall acetone conversion) were also measured. TGA and XRD evidence was found for the charcoal-support-promoted NiO and CoO reduction to the metallic states when the catalysts were subjected to an inert atmosphere above 723 K caused a loss of acetone hydrogenation activity (calculated on a metal load basis) for both the Ni ...
1994-02-01
International Nuclear Information System (INIS)
The performance of anaerobic biological process is heavily process conditions dependent. In this study, an attempt has been made to investigate the influence of process conditions like temperature, sludge age and hydraulic retention time (HRT) on the efficiency of an upflow anaerobic sludge blanket (UASB) reactor and upflow anaerobic sludge filter (UASF) to treat combined industrial wastewater. Reactors were operated at easing ambient temperatures (38, 30, 20 and 14 deg. C) and correspondingly increasing sludge ages (60, 90, 120 and 150 days). At temperature 38 deg. C and sludge age of 60 days, UASF showed better performance than VASE reactor. This mainly due to the enhanced filtration through well-graded sand filter and fairly good biological activity in UASF. At this stage, lack of sludge granulation in VASE reactor resulted in poor biological activity; hence, relatively poor ...
2004-06-07
This is our response to a comment by Walter Eifler on our paper `A simple model for the short-time evolution of near-surface current and temperature profiles' (arXiv:physics/0503186, accepted for publication in Deep-Sea Research II). Although Eifler raises genuine issues regarding our model's validity and applicability, we are nevertheless of the opinion that it is of value for the short-term evolution of the upper-ocean profiles of current and temperature. The fact that the effective eddy viscosity tends to infinity for infinite time under a steady wind stress may not be surprising. It can be interpreted as a vertical shift of the eddy viscosity profile and an increase in the size of the dominant turbulent eddies under the assumed conditions of small stratification and infinite water depth.
2005-01-01
British Library Electronic Table of Contents (United Kingdom)
Abstract High-crystallinity hierarchical anatase TiO2 hollow spheres were prepared by a high-temperature (350 C) and non-aqueous solvothermal method in the absence of water, templates, or additives. The hollow structures were assembled from highly crystallized TiO2 nanoparticles and exhibit superior photocatalytic properties relative to those of Degussa P25 TiO2 under irradiation with UV light. The influence of reaction temperature on the crystallinity, morphology, crystallite shape and size, band gap, specific surface area, and pore size distribution of TiO2 has been studied in detail. It is evident that reaction temperature is the most important factor to increase the crystallinity of TiO2 in order to improve its charge transfer and transport properties, which are important in photocatal...
2011-01-01
Comparisons of the SCDAP computer code with bundle data under severe accident conditions
International Nuclear Information System (INIS)
The SCDAP computer code, which is being developed under the sponsorship of the United States Nuclear Regulatory Commission, models the progression of light water reactor core damage including core heatup, core disruption and debris formation, debris heatup, and debris melting. SCDAP is being used to help identify and understand the phenomena that control core behavior during a severe accident, to help quantify uncertainties in risk assessment analysis, and to support planning and interpretation of severe fuel damage experiments and data. Comparisons between SCDAP calculations and the experimental data showed good agreement. Calculated and measured bundle temperatures for SFD-ST were within 200 K for the entire bundle and within 20 K for maximum cladding temperatures. For ESSI-2, calculated and measured maximum cladding temperatures were within 50 K, and the extensive liquefaction and relocation that was ...
1983-08-22
Analysis of the omnium-g receiver
Energy Technology Data Exchange (ETDEWEB)
A thermal analysis of the Omnium-G receiver is presented and the technique is shown to be generally applicable to solar thermal receivers utilizing a directly heated thermal mass. The thermal loss coefficient, including reradiation losses, is calculated and shown to agree quite well with the experimentally measured thermal loss coefficient. The rate of heat transfer to the working fluid is also analyzed and the analysis is used to show that the Omnium-G receiver is well matched to the water/steam working fluid because the steam outlet temperature is almost the same as the receiver temperature. A general procedure for calculating receiver performance is presented. With this procedure, the energy delivery to any working fluid, the delivered temperature of the working fluid, and the pressure drop through the receiver can be determined. An example of the calculation is also presented.
1980-03-01
British Library Electronic Table of Contents (United Kingdom)
Polycrystalline ZnO doped with Mn (5 and 10at%) was prepared by the co-precipitation method. The effect of Mn doping on the photocatalytic, antibacterial activities and the influence of doping concentration on structural, optical properties of nanoparticles were studied. Structural and optical properties of the particles elucidated that the Mn2+ ions have substituted the Zn2+ ions without changing the Wurtzite structure of ZnO. The optical spectra showed a blue shift in the absorbance spectrum with increasing dopant concentration. The photocatalytic activities of ZnO powders were evaluated by measuring the degradation of methylene blue (MB) in water under the UV region. It was found that undoped ZnO bleaches MB much faster than manganese doped ZnO upon its exposure to the U...
2010-01-01
Radioactive waste disposal for fission and fusion reactors
Energy Technology Data Exchange (ETDEWEB)
The calculated radioactive waste inventories of the Turkey Point pressurized water fission reactor (PWR) and the Starfire conceptual fusion tokamak are compared as a function of time from initial start-up to 10,000 years after decommissioning. Only material out of reactor at least one year is considered. The total activity in Ci/W(th) of the Starfire tokamak is slightly greater than that of the PWR during the active lifetimes of the two reactors and beyond 1000 years. However, using reduced activation materials in Starfire can result in about 1/2000 as much long-lived radioactivity as in the fission reactor. It is stressed that comparison of wastes on this basis is not straightforward, since the radioisotopes and methods required for their disposal are different for fusion and fission reactors. 2 refs., 1 fig., 2 tabs.
1989-01-01
Sprat Sprat in the Southwestern Baltic Sea (including Sound and Belt Sea) ...episodic salt water inflows which occur during autumn to spring.The last major inflow to the Baltic Proper ...The small inflows in spring 1986 and fall 1988 have had only effects on salinity and temperature
Recoil effects in some molybdenum complexes
International Nuclear Information System (INIS)
Molybdenum dioxo bis acetylacetonate shows a retention of about 31% for both "9"9Mo and "1"0"1Mo, with reactor irradiations at ambient temperature. But its radiolytic stability and resistance to hydrolysis are too low for application to "9"9Mo enrichment. The molybdenum (II) carboxylates and the arene molybdenum (O)tricaronyls show high retentions. These complexes are also air and water sensitive in solution. (orig.).
On the feedwater heating in a steam generator of horizontal type
International Nuclear Information System (INIS)
Design layout of horizontal steam generator (SJ) with a special feedwater heating surface (by a surface water economizer), designated for NPPs with WWER-1000 reactors, is suggested. The design enables to decrease sharply the difference between the temperatures of saturation and feedwater. Blowdown outlet is organized against PG face, which increases the efficiency of flowing. The suggested layout enables to decrease thermal stresses in structural units and PG metal content, as compared to the PGV-1000 steam generator.
1989-01-01
International Nuclear Information System (INIS)
It is shown that bending tests on microsamples can be used to study the conditions in which hydrogen brittleness develops. In such tests hydrogen brittleness develops in the VTI5 alloy within the temperature range +5 to -20"0C. The tendency of VTI5 to develop hydrogen brittleness is enhanced with bending in salt water. (author).
Demonstration of piping integrity with SMA technology
Energy Technology Data Exchange (ETDEWEB)
The safe function of a new pipe whip restraint device has been demonstrated in a full scale test. The restraint is based on using a shape memory alloy to protect a pipe and its environment in the event of a double-ended-guillotine-break. The evaluation test has been performed at boiling water reactor (BWR) operating pressure and temperature using a pipe representing BWR primary piping. (orig.) 2 refs.
1997-10-01
International Nuclear Information System (INIS)
A novel continuous powder introduction microwave-induced plasma atomic emission spectrometry method (CPI-MIP-AES) has been developed for trace determination of metals in ground and tap water samples after preconcentration on activated carbon. The experimental setup consisted of integrated rectangular cavity TE_1_0_1 and vertically positioned plasma torch. The technical arrangement of the sample introduction system has been designed based on the fluidized bed concept. The satisfactory signal stability required for sequential analysis was attained owing to the vertical plasma configuration, as well as the plasma gas flow rate compatibility with sample introduction flow rate. The elements of interest (Cd, Cu, Cr, Fe, Mn, Pb, Zn) were preconcentrated in a batch procedure at pH 8-8.5 after addition of activated carbon and then, after filtering and drying of the activated carbon suspension, introduced to the ...
2005-03-31
Measurement of time of travel in streams by dye tracing
Energy Technology Data Exchange (ETDEWEB)
The US Geological survey is active in measuring time of travel in streams using dye tracers. This manual describes methods of measuring time of travel of water and waterborne solutes by dye tracing. The fluorescent dyes, measuring equipment used, and field and laboratory procedures are also described. Methods of analysis and presentation to illustrate time of travel of streams are provided.
1989-01-01
FMDP Reactor Alternative Summary Report: Volume 2 - CANDU heavy water reactor alternative
Energy Technology Data Exchange (ETDEWEB)
The Department of Energy Office of Fissile Materials Disposition (DOE/MD) initiated a detailed analysis activity to evaluate each of ten plutonium disposition alternatives that survived an initial screening process. This document, Volume 2 of a four volume report, summarizes the results of these analyses for the CANDU reactor based plutonium disposition alternative.
1996-09-01
International Nuclear Information System (INIS)
The tritium in transpired water of plant leaves from four locations within site area (2=0.92) with that of measured values indicating that at Tarapur, the contribution to TFWT of plant is only from air activity and pick up through soil route is negligible during the period of study. (author)
2010-05-13
A study was undertaken to examine the uptake, distribution, and interaction of five activation products (Co-57, Be-7, Cs-134, Rb-83, and Mn-54) within the biotic and abiotic components surrounding the waste treatment lagoons of the Los Alamos Meson Physic...
1989-01-01
Characterisation of long-lived low and intermediate-level radioactive wastes in the Nordic Countries
International Nuclear Information System (INIS)
The present report is final report from a study on characterisation of radioactive waters in the Nordic countries. The study has mainly been focused on long-lived low and intermediate level radioactive waste. Methods to measure or estimate the activity content and the general composition are discussed. Recommendations are given regarding characterisation of waste under treatment and characterisation of already produced waste packages. (au).
2005-01-01
Biochemical changes in human cervical connective tissue after local application of prostaglandin E2
DEFF Research Database (Denmark)
Intracervical application of prostaglandin E2 in the late first trimester induces (1) softening of the cervix tissue; (2) increase in sulfated glycosaminoglycans (18 +/- 12%, mean +/- SEM); (3) no change in hyaluronic acid and water; (4) decrease in pepsin-extractable collagen, and (5) apparent decrease in collagenase. A high activity of collagenase in combination with a replacement of collagen with sulfated glycosaminoglycans may be of importance for the ripening process.
1983-01-01
A novel amphiphilic pincer palladium complex: design, preparation and self-assembling behavior.
Amphiphilic pincer palladium complexes bearing hydrophilic and hydrophobic side chains on the planar NCN palladium pincer backbone were designed and prepared via the ligand introduction route. The complexes self-assembled under aqueous conditions to form vesicles with bilayer membranes containing palladium species. The catalytic activity of the vesicles in the Miyaura-Michael reaction in water was investigated. PMID:21837316
2011-08-11
Energy Technology Data Exchange (ETDEWEB)
A great deal of current research is directed to finding a way to minimize thermal injury in the esophagus during radiofrequency catheter ablation of the atrium. A recent clinical study employing a cooling intraesophageal balloon reported a reduction of the temperature in the esophageal lumen. However, it could not be determined whether the deeper muscular layer of the esophagus was cooled enough to prevent injury. We built a model based on an agar phantom in order to experimentally study the thermal behavior of this balloon by measuring the temperature not only on the balloon, but also at a hypothetical point between the esophageal lumen and myocardium (2 mm distant). Controlled temperature (55 {sup 0}C) ablations were conducted for 120 s. The results showed that (1) the cooling balloon provides a reduction in the final temperature reached, both on the balloon surface and at a distance of 2 mm; (2) ...
2008-02-21
Energy Technology Data Exchange (ETDEWEB)
Finland has some 10 million hectares of peatland, accounting for almost a third of its total area. Macroclimatic conditions have varied in the course of the Holocene growth and development of this peatland, and with them the habitats of the peat-forming plants. Temperatures and moisture conditions have played a significant role in determining the dominant species of mire plants growing there at any particular time, the resulting mire types and the accumulation and deposition of plant remains to form the peat. While in a natural state the mires of Finland have functioned as carbon dioxide sinks throughout the post-glacial period, but the ditching of peatland for forestry and agriculture, amounting to some 5,7 million hectares in Finland, has affected their water balance, especially over the last hundred years, and has thereby altered the quantity and species composition of the mire vegetation. The invasion of trees and woody plants to replace ...
2007-07-01
Energy Technology Data Exchange (ETDEWEB)
In the wide range from brown coal to anthracite, an investigation was made of effects of heat treatment on physical/chemical properties and of coal rank dependence. For the experiment, 12 kinds of coal samples were used, and for heat treatment, the fluidized bed heated by the electric furnace and the infrared-ray gold image furnace were used. To examine characteristics of the heat-treated coal char, conducted were oxygen gasification, TPD measurement, XRD measurement, alkali metal measurement, and pore distribution measurement. The following were obtained from the experiment. The gasification reaction rate of the char heat-treated in the temperature range between 900{degree}C to 1700{degree}C decreases with a rise of the temperature of heat treatment, and the degree of decrease in the rate depends on coal rank. The order of gasification rate between coal ranks depends on the temperature of heat treatment, and the lower the ...
1996-10-28
Nuclear desalination for the petrochemical complex of the Natuna project
International Nuclear Information System (INIS)
On the basis of environmental considerations, a high temperature gas cooled reactor (HTGR) was proposed as the heat source for the Natuna project for CO_2 conversion. To convert CO_2 to useful products, a large amount of high quality water is required for the chemical processes, boilers and other purposes. One LNG production train (maximum of six trains) would produce 0.4 x 10"9 SCF/d of saleable gas and 1.4 x 10"9 SCF/d of CO_2 (in the case of the Exxon process). This CO_2 gas would then be converted to automobile fuel (methane, methanol), which requires a large amount of water. Natural gas from an off- shore gas field is piped to the petrochemical complex on Natuna Island (about 228 km). Natuna is a small island that, apart from sea water, does not have much available water. The desalination process is considered to be the only solution to the water demand ...
1997-12-01
Contaminant assimilation in newly created prairie wetlands
Energy Technology Data Exchange (ETDEWEB)
Increased use of wetlands for habitat and water quality improvement emphasize the need for further study of abiotic-biotic interactions in these systems. This research examined contaminant assimilation within the water column of two newly created Colorado prairie wetlands (RMA3 and RMA4). To examine the influence of abiotic factors (e.g., alkalinity, suspended solids), ten chronic toxicity tests were performed from December 1991 through November 1993. In the first set of tests, Ceriodaphnia dubia were exposed to water from the two wetlands which was spiked with various concentrations of zinc. These tests suggested that water from RMA4 had higher contaminant assimilative capacity than water from RMA3. Preliminary analysis suggested suspended solids, pH, conductivity, and temperature were important factors affecting neonate production by C. dubia when exposed to ...
1994-12-31
Surface-water-resources information for the Ho-Chunk Nation lands and vicinity, Wisconsin
The Ho-Chunk Nation is interested in documenting water-quality conditions in streams adjacent to their Reservation lands in Wisconsin and developing management plans to protect these water resources. The Nation uses these waterways for recreation and as a source for food, and therefore, is dedicated to maintaining and restoring their quality. Ho-Chunk lands encompass more than 10,000 acres ranging primarily over 17 counties in Wisconsin. The study areas for this report include streams adjacent to Ho-Chunk Nation residential lands: Potch-Hah-Chee, Sandpillow, Mission, Bluewing, Chakh Hah Chee, Winnebago Heights, Indian Heights, and Ho-Chunk Village. These residential areas, or housing sites, are located along or near the Middle Branch Embarrass, Black, Lemonweir, and Wisconsin Rivers or their tributaries. Water-quality data were compiled and summarized, and basin maps showing land cover and previous sampling sites are ...
2003-01-01
Energy Technology Data Exchange (ETDEWEB)
Since mid-March the Commission on Water Management, with the assistance of the appropriate ministries, visited all regions of the province in order to acquaint themselves first hand with regional water management problems. During the month of June, the Commission also organized a series of ten workshops, attended by a limited number of experts, to explore in depth certain specific questions in the area of water management. During these public sessions the Commission hoped to discuss specifically the specific questions relating to water management problems of First Nations communities, bearing in mind the essential nature of water in maintaining traditional activities. The workshop took place on the Montanard reserve of Mashteuiatsh (Pointe-Bleu). The morning session was devoted to presentations by invited experts, followed by an exchange of views between the ...
1999-08-13
Energy Technology Data Exchange (ETDEWEB)
In France, groundwater usage represents 40 per cent of volumetric use, outside of thermal power plants. Groundwater represents 60 per cent of domestic and public use, 40 per cent in the industrial sector, and is increasing in the agricultural sector where it accounts for 20 per cent. Groundwater withdrawal in France has slightly increased over the last twenty years and benefited the agricultural sector. Availability throughout the territory, the consistency of resupply and natural quality has rendered groundwater a prevailing source for drinking water. Water protection and management is important and led to the adoption of legislative and regulatory measures. The Mining Code (Code minier) allows for exploitation of underground resources starting at 10 metres. The Rural Code (Code rural) mandates the declaration of public utility for water collection for the public. Protection areas are to be provided under the Public Health ...
2001-07-01
Structure of human insulin monomer in water/acetonitrile solution
Energy Technology Data Exchange (ETDEWEB)
Here we present evidence that in water/acetonitrile solvent detailed structural and dynamic information can be obtained for important proteins that are naturally present as oligomers under native conditions. An NMR-derived human insulin monomer structure in H{sub 2}O/CD{sub 3}CN, 65/35 vol%, pH 3.6 is presented and compared with the available X-ray structure of a monomer that forms part of a hexamer (Acta Crystallogr. 2003 Sec. D59, 474) and with NMR structures in water and organic cosolvent. Detailed analysis using PFGSE NMR, temperature-dependent NMR, dilution experiments and CSI proves that the structure is monomeric in the concentration and temperature ranges 0.1-3 mM and 10-30 deg. C, respectively. The presence of long-range interstrand NOEs, as found in the crystal structure of the monomer, provides the evidence for conservation of the tertiary structure. Starting from structures calculated by the ...
2008-01-15
Report on Thermo-Hydro-Mechanical Laboratory Tests Performed by CIEMAT on Febex Bentonite 2004-2008
International Nuclear Information System (INIS)
The results of the laboratory studies performed by CIEMAT with the FEBEX bentonite in the context of WP3.2 of the NF-PRO Project and of the Agreement ENRESA-CIEMAT Anexo V are presented and analysed in this report. They refer to the effect of the hydraulic gradient on the permeability of bentonite, the effect of the thermal gradient on the hydration kinetics of bentonite, and the repercussion of temperature on the hydro-mechanical properties of bentonite (swelling, permeability and water retention capacity). In all the cases the bentonite has been used compacted to densities expected in the engineered barrier of a high-level radioactive waste repository. The existence of threshold and critical hydraulic gradients has been observed, both of them dependent on bentonite density and water pressures. After more than seven years of hydration, the 40-cm high bentonite columns are far from full saturation, the thermal gradient ...
Report on Thermo-Hydro-Mechanical Laboratory Tests Performed by CIEMAT on Febex Bentonite 2004-2008
Energy Technology Data Exchange (ETDEWEB)
The results of the laboratory studies performed by CIEMAT with the FEBEX bentonite in the context of WP3.2 of the NF-PRO Project and of the Agreement ENRESA-CIEMAT Anexo V are presented and analysed in this report. They refer to the effect of the hydraulic gradient on the permeability of bentonite, the effect of the thermal gradient on the hydration kinetics of bentonite, and the repercussion of temperature on the hydro-mechanical properties of bentonite (swelling, permeability and water retention capacity). In all the cases the bentonite has been used compacted to densities expected in the engineered barrier of a high-level radioactive waste repository. The existence of threshold and critical hydraulic gradients has been observed, both of them dependent on bentonite density and water pressures. After more than seven years of hydration, the 40-cm high bentonite columns are far from full saturation, the thermal gradient ...
2009-11-25
Production of hydrogen by radiolysis
Energy Technology Data Exchange (ETDEWEB)
The possibility of obtaining high yields of hydrogen through the exposure of calcium hydroxide to natural uranium fission fragments is confirmed experimentally. The amounts of hydrogen obtained in some experiments were determined not only from the mass-spectrometry data, but also with the use of standard chemical analysis methods. The radiolytic hydrogen yield averaged over six independent experiments comprises 20.41 hydrogen molecules per 100 eV of absorbed fission fragment energy. The corresponding energy efficiency makes up to 60.62. Since on interaction with water or water vapor calcium hydroxide enters into the exothermal reaction to liberate 15.6 kcal/mole, it can easily be regenerated; this was attested to by one of irradiation experiments. Therefore, in the long run, we are dealing with a radiolytic decomposition of water at low temperatures or at temperatures readily ...
1998-07-01
Ocean thermal energy conversion (OTEC) plants discharge large volumes of cold water into the upper ocean. A three-dimensional, limited-area model was developed to investigate the regional influence of the far-field effluent plume created by the negatively buoyant discharge. The model was applied to discharges from a 40-MW/sub e/ OTEC plant into coastal waters characterized by various ambient ocean conditions. A typical ambient temperature structure and nutrient distribution, as well as the behavior of the effluent plume itself, were strongly modified by the discharge-induced circulation. Although temperature perturbations in the plume were small, upward entrainment of nutrients from below the thermocline was significant. The regional influence of discharges from an 80-MW/sub e/ OTEC plant, the interactions between the discharges from two adjacent 40-MW/sub e/ OTEC plants, and the effects of coastal ...
1985-07-01
Energy Technology Data Exchange (ETDEWEB)
A detailed study of adsorption of automobile exhaust hydrocarbons in Ag{sup +}-exchanged zeolites under cold-start conditions (room temperature and in the presence of water) was carried out with FT-IR spectroscopy, using toluene and propylene as probes. The results show that exchanged Ag{sup +} in zeolites is unique for trapping olefin and aromatic hydrocarbons due to its resistance to water adsorption. In contrast, exchanged Cu{sup 2+} in zeolites, which has good hydrocarbon trapping properties under dry conditions, does not trap hydrocarbons under wet conditions. Here, solvation of Cu{sup 2+} screens the interactions of the cation with adsorbed hydrocarbons. The results also show that, in addition to the nature of the cation, the structure of the zeolite also plays a role in hydrocarbon trapping. Aging at high temperatures, with water vapor (=10%) and SO{sub 2} (=15ppm), leads to ...
2001-12-28
Energy Technology Data Exchange (ETDEWEB)
There is a great demand for the reduction of specific fuel consumption in diesel engines, and also of NO/sub x/ emission in especially those designed for use on land. However, while improving combustion, a problem arises in trying to reduce both simultaneously because the techniques required are contradictory. This series of experiments was done to study the correlation between specific fuel consumption and NO/sub x/ emission. The research was conducted under variations in engine parameters and operating conditions. The variations studied included effects of pressure, temperature and humidity of the charging air, temperature of the cooling water, timing and rate of fuel injection, fuel injection nozzle, EGR and water-emulsified fuel. The results of the tests clarified the characteristics of the specific fuel consumption and NO/sub x/ emission and indicated that the most-effective measures for the ...
1985-01-01
Experimental investigation on the fretting wear of alloy 800 in room remperature water
Energy Technology Data Exchange (ETDEWEB)
Fretting wear test in room temperature water was performed to evaluate the wear coefficient of CANDU (CANadian Deuterium Uranium) steam generator (SG) tube material (Alloy 800) against 410 type martensitic stainless steels. The main focus is to compare the wear behaviors between Alloy 800 and Inconel 690. Test conditions are 10{approx}30N of normal load, 200{approx}450mm of sliding amplitude and 30Hz of frequency. The result indicated that the wear rate of Alloy 800 was higher than those of Inconel 690 at various test condition such as normal loads, sliding amplitudes etc. From the results of SEM observation, there was little evidence of plastic deformation layer that were dominantly formed on the worn surfaces of Inconel 690. Also, wear particles in Alloy 800 were released from contacting asperities deformed by severe plastic flow during fretting wear. Main cause of wear rate between Alloy 800 and Inconel 690 may be due to the difference of ...
2002-05-01
Experimental investigation on the fretting wear of alloy 800 in room remperature water
International Nuclear Information System (INIS)
Fretting wear test in room temperature water was performed to evaluate the wear coefficient of CANDU (CANadian Deuterium Uranium) steam generator (SG) tube material (Alloy 800) against 410 type martensitic stainless steels. The main focus is to compare the wear behaviors between Alloy 800 and Inconel 690. Test conditions are 10#approx#30N of normal load, 200#approx#450mm of sliding amplitude and 30Hz of frequency. The result indicated that the wear rate of Alloy 800 was higher than those of Inconel 690 at various test condition such as normal loads, sliding amplitudes etc. From the results of SEM observation, there was little evidence of plastic deformation layer that were dominantly formed on the worn surfaces of Inconel 690. Also, wear particles in Alloy 800 were released from contacting asperities deformed by severe plastic flow during fretting wear. Main cause of wear rate between Alloy 800 and Inconel 690 may be due to the difference of ...
2002-05-01
Energy Technology Data Exchange (ETDEWEB)
An Allis-Chalmers, Model 2900, turbocharged diesel engine was converted to a dual-fuel engine in which ethyl alcohol was fumigated between the turbocharger and the intake manifold, and the diesel fuel was injected normally at a reduced rate. Tests were performed to determine if crankcase oil dilution that had occurred was caused by the following independent parameters: proof of the ethyl alcohol, crankcase oil temperature, engine load at maximum torque speed, and percentage of total energy in the form of ethyl alcohol. Engine tests were steady state for six hours, after which the crankcase oil was sampled for American Society for Testing and Materials (ASTM) laboratory tests for determination of flash points and fire points, water by centrifuge, water by distillation, and viscosity at room temperature. Results indicate a decrease in thermal efficiency and an increase in exhaust carbon monoxide as the ...
1982-11-01
Corrosion resistance of austenitic steels and alloys in high temperature water
International Nuclear Information System (INIS)
An ampoule corrosion tests technique is presented for making a comparative corrosion-proof estimation of austenitic steels and alloys which are candidate materials for the ITER first wall and shield blanket. Influence of Cl"- on the rate and character of corrosion cracking has been determined. The dependence of time before destruction on Cl"- contents was obtained by experiments in twice-distilled water at a Cl"- content value of less than 0.05 mg/l. Kinetics of a corrosion crack growth has been determined by way of acoustic emission and measurement of electrical resistance. It has been revealed, that corrosion cracking of 316L and 316Ti steels in water with 100 mg/l of Cl"- takes place at temperatures over 50 C. For 316L (Russian analogue), 316Ti, 08Cr18Ni10Ti (type 304), 00Cr16Ni15Mo3Nb (type 316) steels and CrNiMo-1 (42-47%Cr, 1%Mo, Ni-base) alloy corrosion long-term strength and crack-resistance characteristics were ...
Energy Technology Data Exchange (ETDEWEB)
The results of the experiments on the pressure oxidation of oil and fat in waste waters shows that the final COD and TOC values decrease with growing temperature and reaction time and decreasing initial concentration. Oxidation of oil and fat in waste water is no straight forward procedure. Therefore it should be compared in the individual case with laternative methods in terms of cost and economic efficiency. (EF) [Deutsch] Die Ergebnisse der Versuche zur Druckoxidation von Oel und Fett in Abwaessern zeigten, dass sich die CSB- und TOC- Endkonzentration verringerte mit steigender Temperatur, Reaktionszeit und verringerter Ausgangskonzentration. Die Oxidierbarkeit von Oel und Fett in Abwaessern ist sehr schwierig. Deshalb sollte in jedem Einzelfall ein Vergleich mit alternativen Verfahren bezueglich Aufwand und Wirtschaftlichkeit vorgenommen werden. (EF)
1993-03-30
British Library Electronic Table of Contents (United Kingdom)
We propose and demonstrate a facile room-temperature synthetic method for obtaining water-soluble magnetic Fe3O4 nanoparticles (NPs) by combining the in situ synthesis and decomposition of a magnetic polymer hydrogel. The Fe3O4 NPs with average diameters of 6.3-8.3nm were synthesized in a cross-linked polyacrylamide (PAAm) hydrogel by coprecipitating iron ions. The decomposition of the magnetic polymer hydrogel by an aqueous solution of sodium hydroxide led to the transfer of Fe3O4 NPs into the aqueous medium. The NPs can be dispersed stably in water for more than three months. The Fe3O4 NPs were characterized by X-ray photoelectron spectra (XPS), X-ray powder diffraction (XRD), transmission electron microscope (TEM), and Fourier transform infrared spectroscopy (FT-IR). The saturation magn...
2011-01-01
Integral severe accident analysis of light water nuclear power plants by IMPACT-SAMPSON code
Energy Technology Data Exchange (ETDEWEB)
The NUclear Power Engineering Corporation (NUPEC) has developed IMPACT-SAMPSON code to analyze integral behavior of light water nuclear power plants under severe accident conditions. IMPACT-SAMPSON's distinguishing features include interconnected hierarchical modules and mechanistic models covering a wide spectrum of scenarios ranging from normal operation to severe accident events, and high-speed simulation on parallel processing computers. The integral plant behaviors of typical PWR and BWR under severe accident conditions have been analyzed with the IMPACT-SAMPSON code. The PWR plant analyzed was the three-loop, steel-dry containment type with 2,440 MWt. The AE accident scenario was supposed, that is, LOCA by 6-inch hot leg failure followed by accumulated water injection, but no ECCS and containment spray activation. The BWR plant analyzed was the 3,293 MWt BWR-5, Mark-II containment type. The TQUV accident ...
2003-07-01
Environmental management plan for the Jhario coalfield - India
Energy Technology Data Exchange (ETDEWEB)
An Environmental Management Plan (EMP) for the Jharia Coalfield (JCF) was recently completed as part of a World Bank funded project. The JCF, 260 km west of Calcutta, comprises 450 km{sup 2}. Bharat Coking Coal Limited (BCCL) operates an area of 258 km{sup 2}. Coal mining has been conducted for more than 100 years. There are severe constraints to mining due to geology, coal fires and the large population. BCCL counterpart staff participated actively in all aspects of the work. Air and water are heavily polluted, however, mining operations contribute only to a limited extent to the total pollution. Water contamination is generally due to inadequate sewage treatment and discharge from non-mine facilities such as power plants. The large area disturbed by mining to date will increase, as open pit mining operations are expected to expand significantly. Reclamation to date is generally confined to planting of trees. Areas where ...
1997-12-31
Energy Technology Data Exchange (ETDEWEB)
During the early years of the INEL, the USGS conducted extensive studies (sitewide drilling program) of the geology and hydrology of the area collecting varied data over the years. The unsaturated zone has not received much attention until recently. The studies that have been done are a result of problems or concerns arising from liquid radioactive waste disposal. The TRA facility has the most information published about its waste disposal activities. The ICPP has less data about the unsaturated zone due to the fact that most waste water disposal has been to a well. Little is known about the effect of waste water disposal at the NRF on the unsaturated zone. Essentially no information was found about waste disposal activities at other facilities, primarily because there does not appear to be any reported problems associated with waste water disposal at these locations. The RWMC has ...
1992-01-01
Energy Technology Data Exchange (ETDEWEB)
During the early years of the INEL, the USGS conducted extensive studies (sitewide drilling program) of the geology and hydrology of the area collecting varied data over the years. The unsaturated zone has not received much attention until recently. The studies that have been done are a result of problems or concerns arising from liquid radioactive waste disposal. The TRA facility has the most information published about its waste disposal activities. The ICPP has less data about the unsaturated zone due to the fact that most waste water disposal has been to a well. Little is known about the effect of waste water disposal at the NRF on the unsaturated zone. Essentially no information was found about waste disposal activities at other facilities, primarily because there does not appear to be any reported problems associated with waste water disposal at these locations. The RWMC has ...
1992-12-31
Climate change impacts and adaptation : a Canadian perspective
International Nuclear Information System (INIS)
This book summarizes the research that has been conducted in Canada over the past five years on the issue of climate change impacts on key sectors such as water resources, agriculture, forestry, fisheries, coastal zones, transportation, and human health and well-being. The book refers to the growing evidence that climate change is occurring. The Intergovernmental Panel on Climate Change (IPCC) believes that these changes have already contributed to increases in annual precipitation, cloud cover and extreme temperatures over the last 50 years. It suggests that it in order to develop an effective strategy for adaptation, it is necessary to understand the vulnerability of each sector to climate change in terms of the nature of climate change, the climatic sensitivity of the region being considered, and the capacity to adapt to the changes. Adaptation will require a reduction in greenhouse gas emissions in order to lower the rate of climate change. ...
Incorporation of tritium into body constituent molecules
International Nuclear Information System (INIS)
Incorporation of tritium into body constituent molecules from tritiated water and its in vivo behaviors were studies using rats. In single administration of HTO, "3H behaviors were studied in lipids that are rich in hydrogen. Incorporation of "3H into the lipid fraction from HTO and its release differed by each organ and by the type of lipid components. Of routes of administration, the oral and parenteral routes showed same results, and no prominent difference was noted by inhalation. By consecutive administration, the urine "3H concentration showed no difference according to the route, but increased as the concentration of administered HTO increased. When administration was discontinued after the urine "3H concentration reached a plateau, the biological half-life was about 4.5 days, almost in agreement with the value by single administration. In relation to water intake, increase in the urine volume and accompanying promotion of urine "3H ...
1981-12-03
Proton spin lattice relaxation studies in lithium ammonium sulfate LiNH_4SO_4
International Nuclear Information System (INIS)
Lithium ammonium sulfate (LAS) undergoes a phase transition at Tsub(c1) = 459.5deg K from a paraelectric phase (phase 1) to a ferroelectric phase (phase II) and again at Tsub(c2) = 283deg K to a polar ferroelastic phase (phase III). Proton spin lattice relaxation investigations in the temperature range 480-77deg K at 10 MHz show discontinuous changes in Tsub(1) at the transition temperatures, indicating first order phase transitions. The absence of the slow motion region (#omega#sub(not)tausub(not)>>1) shows that the ammonium ions are reorienting fast enough to keep the resonance absorption line narrow down to liquid nitrogen temperatures. The possibility of a second minimum and a low activation energy, Esub(a) = 2.659 kcal/mole, in phase III suggest the possibility of tunnelling of the protons at low temperatures. The nature of the transitions have been discussed in the light ...
1978-12-31
Energy Technology Data Exchange (ETDEWEB)
The NiMo sulfide supported on Ketjen Black (KB) was more effective and yielded lighter oil products containing light fractions with their boiling point below 300{degree}C during the two stage liquefaction combining low temperature and high temperature hydrogenation the conventional NiMo/alumina catalyst and FeS2 catalyst. Although the NiMo/alumina yielded increased oil products during the two stage liquefaction, the lighter oil fractions did not increase and the heavier fractions increased mainly. This suggests that the hydrogenation of aromatic rings and successive cleavage of the rings are necessary for producing the light oil, which is derived from the sufficient hydrogenation of aromatic rings using catalysts. For the two stage reaction with NiMo/KB catalyst, it was considered that sufficient hydrogen was directly transferred to coal molecules at the first stage of the low temperature reaction, which promoted the ...
1996-10-28
Vapor phase lubrication of a Ni-based superalloy
Energy Technology Data Exchange (ETDEWEB)
In addition to ceramics, alloys such as tool steel and nickel- and iron-based superalloys are being considered for high temperature applications such as missile bearings and low heat rejection engines. Studies were made to lubricate a nickel-based superalloy at 500{degrees}C, by using a vaporized aryl phosphate ester, at a concentration of 0.1% in air. From deposition and wear studies it was found that it was impossible to form a good polymeric coating on the superalloy surface. Energy dispersive X-ray analyzer (EDXA) analysis showed that this was due to minute quantities of aluminum in the alloy segregating to the surface, upon being heated to 500{degrees}C, forming a passive oxide coating. It was necessary to activate the surface, in order to lubricate the material successfully. A method of activation by electrodepositing the surface with a layer of iron oxide was developed. Once activated, a good ...
1995-03-01
British Library Electronic Table of Contents (United Kingdom)
Solid-state fermentation of soybean hulls supplemented with wheat bran using a co-culture of Trichoderma reesei and Aspergillus oryzae was performed. Three parameters - initial moisture content, incubation temperature, and initial pH - were optimized in culture flasks using response surface methodology. Parameter optimization was carried out with respect to filter paper activity and b-glucosidase activity in the culture. Temperature of 30^oC, pH of 5, and moisture content of 70% were found to be optimum. Optimized parameters were used for laboratory scale-up in static tray fermenters. The maximum filter paper activity of 10.7FPU/g-ds and b-glucosidase of 10.7IU/g-ds were obtained after 96-h incubation period in static tray fermenters in agreement with optimized activities at shake flask le...
2010-01-01
Novel catalysts for methane activation. Final progress report, September 30, 1992--April 30, 1996
Energy Technology Data Exchange (ETDEWEB)
This final report summarizes the results of our research under Contract No. DE-AC22-92PC92112, Novel Catalysts for Methane Activation. In this research we prepared and tested fullerene soots for converting methane into higher hydrocarbons. We conducted the methane conversions using dehydrocoupling conditions, primarily in the temperature regimes of 600{degrees}-1000{degrees}C and atmospheric pressures. The research was divided into three sections. The first section focused on comparing fullerene soots with other forms of carbon such as acetylene black and Norit-A. We found that the fullerene soot was indeed more reactive than the other forms of carbon. However, due to its high reactivity, it was not selective. The second section focused on the effect of metals on the reactivity of the soots, including both transition metals and alkali metals. We found that potassium could enhance the selectivities of fullerene soot to higher hydrocarbons, but ...
1996-06-11
High Throughput Screening for the Discovery of More Efficient Catalysts for Emissions Control
Energy Technology Data Exchange (ETDEWEB)
High-throughput synthesis and screening methods have been developed for the discovery of highly active catalysts for the control of emissions from stationary and mobile sources. Low temperature CO oxidation, CO methanation, NOx abatement and the destruction of Volatile Organic Compounds (VOCs) will be discussed. The discovery libraries for primary screening consisted of both 11x11 and 16x16 catalyst arrays on 3 inch and 4 inch quartz wafers, respectively. Catalysts were prepared by robotic liquid dispensing techniques and screened for catalytic activity in Symyx's Scanning Mass Spectrometer. The screening protocols encompassed mixed metal oxides, perovskites and supported base and noble metals. Active hits were further optimized in focus libraries using shallower compositional gradients. The ScanMS is a fast serial screening tool that uses flat wafer catalyst surfaces, local laser heating, a ...
2004-03-31
Change in pore structure of coals by activation with KOH; KOH fukatsushita sekitan no saiko kozo
Energy Technology Data Exchange (ETDEWEB)
Three typical Japanese coals of non-coking coal, coking coal and anthracite were heat-treated with KOH, and change in their pore structure was examined by absorption of N2, X-ray diffraction and TEM observation. In addition, the relation between a coal rank and pore structure was also studied by absorption experiment of N2. In experiment, the mixture of coal and KOH in a nickel holder was heat-treated in N2 gas flow at heating rate of 2{degree}C/min, and held at a fixed temperature for one hour. To clarify the pore structure, N2 absorption isotherms were measured at -196{degree}C under nearly 76cmHg using a commercially available full-automatic absorption measurement equipment. Based on the X-ray diffraction and TEM observation results on activated coals, the relation between the N2 absorption and pore structure was studied. The results are summarized as follows: (1) The yield and absorption ability of coals increase with a coal rank, (2) The ...
1996-10-28
The aqueous fraction (AF) of an ethanolic extract from Chrysanthemum indicum was evaluated for analgesic activity in mice using chemical and thermal models of nociception. Given orally, AF at doses of 300 and 600 mg/kg produced significant inhibitions on chemical nociception induced by intraperitoneal acetic acid, subplantar formalin/capsaicin injections and on thermal nociception in the tail-flick test and in the hot plate test. In the pentobarbital sodium-induced sleeping time test and the open-field test, AF neither significantly enhanced the pentobarbital sodium-induced sleeping time nor impaired the motor performance, indicating that the observed analgesic activity was unlikely due to sedation or motor abnormality. In a measurement of core body temperature, AF did not affect temperature within 80 min. Moreover, the effective dose (600 mg/kg) also showed no toxicity within 7 days. These results ...
2011-07-01
Energy Technology Data Exchange (ETDEWEB)
Coal was treated at high temperature under high pressure in the binary system mixed solvent of water and organic solvent, and the solvent treated coal was liquefied. When the treated coal was treated again by the explosive method in which high temperature and pressure were released immediately, the oil yield was higher than that by the normal method in which high temperature and pressure were reduced gradually to room temperature and atmospheric pressure. In this study, an explosive treatment unit with increased scale of sample amount was newly fabricated. Illinois No.6 coal was treated by the explosive method in a mixed solvent of water and cyclohexanol using this unit. Changes in shape on the surface, specific surface area, and functional groups were analyzed. The explosively treated coal contained more amount of low boiling point components than the normally ...
1996-10-28
International Nuclear Information System (INIS)
The molar extinction coefficients at the absorption maximum of the solvated electron spectrum have been evaluated to be 900, 970, and 1000 mol-1?m2 for 1,2-ethanediol (12ED), 1,2-propanediol (12PD), and 1,3-propanediol (13PD), respectively. These values are two-third or three-fourth of the value usually reported in the published report. Picosecond pulse radiolysis studies have aided in depicting the radiolytic yield of the solvated electron in these solvents as a function of time from picosecond to microsecond. The radiolytic yield in these viscous solvents is found to be strongly different from that of the water solution. The temperature dependent absorption spectra of the solvated electron in 12ED, 12PD, and 13PD have been also investigated. In all the three solvents, the optical spectra shift to the red with increasing temperature. While the shape of the spectra does not change in 13PD, a widening on the blue side of the ...
2007-02-01
Influence of temperature on strength of cemented surrogate nitrate salt waste
Energy Technology Data Exchange (ETDEWEB)
The Rocky Flats Plant (RFP) generates large volumes of a low level aqueous waste stream high in nitrate salts. The aqueous waste is concentrated by evaporation and then mixed with Portland cement prior to transport and disposal. Planned process upgrades include a new horizontal thin film evaporator. Temperature of brine at discharge end of the new evaporator will be near boiling point. Introduction of hot water to cement can degrade the monolithic waste form. However, the RFP salt waste contains high concentrations of compounds known to retard hydration. This paper discusses impact of introducing high temperature waste to cement. The study evaluated three waste compositions: (1) highest probable nitrate composition, (2) highest probable chloride composition, and (3) current composition. Results showed that compressive strength of final waste form increased with brine temperature, and waste forms from ...
1993-01-01
Influence of temperature on strength of cemented surrogate nitrate salt waste
Energy Technology Data Exchange (ETDEWEB)
The Rocky Flats Plant (RFP) generates large volumes of a low level aqueous waste stream high in nitrate salts. The aqueous waste is concentrated by evaporation and then mixed with Portland cement prior to transport and disposal. Planned process upgrades include a new horizontal thin film evaporator. Temperature of brine at discharge end of the new evaporator will be near boiling point. Introduction of hot water to cement can degrade the monolithic waste form. However, the RFP salt waste contains high concentrations of compounds known to retard hydration. This paper discusses impact of introducing high temperature waste to cement. The study evaluated three waste compositions: (1) highest probable nitrate composition, (2) highest probable chloride composition, and (3) current composition. Results showed that compressive strength of final waste form increased with brine temperature, and waste forms from ...
1993-03-01
International Nuclear Information System (INIS)
Hydrogen is a potential alternative energy source and produced commercially by methane (natural gas) or LPG steam reforming, a process that requires high temperatures, which are produced by burning fossil fuels. However, since this process emits large amounts of CO_2, replacement of the combustion heat source with a nuclear heat source for 773-1173 K processes has been proposed in order to eliminate these CO_2 emissions. This paper proposes a novel method of low-temperature nuclear hydrogen production by reforming dimethyl ether (DME) with steam produced by a low-temperature nuclear reactor at about 573 K. The authors identified conditions that provide high hydrogen production fraction at low pressure and temperatures of about 523-573 K. By setting this low-temperature hydrogen production process at about 573K upstream from a turbine, it was found theoretically that the total energy ...
2003-09-15
Hyperspectral and Multispectral Remote Sensing at Uranium Processing Facilities
Energy Technology Data Exchange (ETDEWEB)
Many mines and processing facilities are in remote, difficult to access areas, or are in areas where access is limited or restricted for national reasons. In a joint project with Canada Centre for Remote Sensing, the Canadian Safeguards Support Program is investigating utility of multi- and hyperspectral remote sensing for remotely inspecting such site. With a view to eventually using the hyperspectral satellite data now coming available, airborne data over uranium and copper mine tailings and uranium processing facilities in northern Canada were acquired. The objective of this work is to demonstrate that multispectral and hyperspectral data can provide complementary and supplementary information to high-resolution panchromatic imagery for the following safeguards applications: Inspection aids (up-to-date maps of remote locations), change detection, evaluation of member state declarations, monitoring of reactor, mining and processing facility operations, and detection of undeclared ...
2003-05-01
Energy Technology Data Exchange (ETDEWEB)
Lithium metal-polymer electrolyte batteries with improved utilisation of the active material at a moderate-low temperature (65degC) were realised. Low molecular weight poly(ethylene glycol) (PEG, MW=2000) was used as the lithium-ion conductive matrix in the composite cathode. The cathode active material was crystalline V{sub 2}O{sub 5}. A blend of poly(ethylene oxide) (PEO, MW=4x10{sup 6}) and PEG was used as a solid polymer electrolyte (SPE). The transport properties of the SPE were evaluated at various temperatures. A specific conductivity as high as 1.0x10{sup -4} S cm{sup -1} was calculated at 45degC. The temperature dependence of the interfacial resistances between lithium/SPE and cathode material/PEG was evaluated. The lithium/SPE interfacial resistance decreases linearly with the temperature. The charge transfer resistance between cathode material and PEG ...
2001-07-01
The influence of ultrasound on the fluoroquinolones antibacterial activity
British Library Electronic Table of Contents (United Kingdom)
In this work, the antibacterial effect of fluoroquinolones (FQs) upon Escherichia coli (E.coli) was measured with and without application of 40kHz ultrasound (US) stimulation. The research results demonstrated that simultaneous application of 40kHz US apparently enhanced the antibacterial effectiveness of FQs. That is, the synergistic effect was observed and the bacterial viability was reduced when FQs and US were combined. In addition, various influencing factors, such as FQs drug concentration, US irradiation time and solution temperature, on the inhibition of E.coli were also investigated. The antibacterial activity was enhanced apparently with increasing of FQs drug concentration, US irradiation time and solution temperature. Furthermore, we discussed preliminarily the mechanism of US ...
2011-01-01
Self-diffusion of silicon in thin films of cobalt, nickel, palladium and platinum silicides
International Nuclear Information System (INIS)
Radioactive "3"1Si was used as a tracer to study silicon self-diffusion in thin film silicides of cobalt, nickel, palladium and platinum. The specimens were prepared by sequential electron beam evaporation of radioactive "3"1Si and of the metal onto cleaned silicon wafers. By vacuum annealing at the appropriate formation temperature a silicide about 250 nm thick containing a sharp radioactive band about 50 nm thick was generally formed. Subsequent heating above the formation temperature resulted in a spreading of the activity owing to silicon self-diffusion. Activity profiles in the silicides were measured by a combination of ion beam sputtering, radioactivity counting and Rutherford backscattering of charged nuclear particles. (orig.).
Adsorption of hexavalent chromium from aqueous solution by using activated red mud
Energy Technology Data Exchange (ETDEWEB)
Adsorption by activated red mud (ARM) is investigated as a possible alternative to the conventional methods of Cr(VI) removal from aqueous synthetic solutions and industrial effluents. Adsorption characteristics suggest the heterogenous nature of the adsorbent surface sites with respect to the energy of adsorption. Various factors such as pH, contact time, Cr(VI) concentration, amount of adsorbent, and temperature are taken into account, and promising results are obtained. The applicability of the Langmuir as well as Freundlich adsorption isotherms for the present system is tested. The loading factor (i.e., milligrams Cr(VI) adsorbed per gram of ARM) increased with initial Cr(VI) concentration, whereas a negative trend was observed with increasing temperature. The influence of the addition of anions on the adsorption of Cr(VI) depends on the relative affinity of the anions for the surface and the relative concentrations of ...
1999-09-01
A comparative study on thermal and catalytic degradation of polybutylene terephthalate
British Library Electronic Table of Contents (United Kingdom)
A comparative study on the thermal and catalytic degradation of polybutylene terephthalate (PBT) at atmospheric pressure was conducted. The weight loss of PBT under thermal degradation was significantly influenced by the temperature between 360degreeC and 380degreeC, but little affected by the PBT particle size. Four groups of catalysts include metal chloride, metal oxide, metal acetate, and metal copper powder were used to test PBT degradation activity. Copper (II) chloride is the most active one for increasing the percentage PBT weight loss more than 100% in comparison with the result of thermal degradation at a temperature of 360degreeC for 30min. PBT and catalyst mixtures can be prepared by impregnation and physical method, the former resulted in a better PBT degradation. The percentag...
2009-01-01
Removal of tetracycline and sulfonamide classes of antibiotic compound by powdered activated carbon
Energy Technology Data Exchange (ETDEWEB)
Removal of sulfonamide (SAs) and tetracycline (TAs) classes of antibiotic compound from deionized water and DOC water by powdered activated carbon (PAC) adsorption was evaluated in this study. According to the study results, TAs were more easily adsorbed than SAs although TAs were more hydrophilic than SAs. The phenolic compounds in TAs might be responsible for their high adsorption. Complex formation of TAs with metal and metal oxide on the surface of activated carbon might also contribute to higher adsorption. The hydrophobic effect was important for removal of SAs. More hydrophobic SAs were removed more easily. The carbon type was not important for adsorption of SAs and TAs. Coal based carbon and coconut based carbon showed similar removal efficiencies for these antibiotics. Dissolved organic materials interfered with adsorption of SAs and TAs. Organic interference was more significant for the ...
2008-03-15
Energy Technology Data Exchange (ETDEWEB)
The authors report a two-temperature RF bias stress test on nominal 1.2 W 7.5 GHz GaAs/AlGaAs HBT unit cell amplifiers. MTTF`s of 2020 and 1340 hours were obtained at Tj = 218{degrees}C and 245{degrees}C, respectively, under nominal input bias. An activation energy of 0.42 eV is estimated, consistent with published results for similar devices under DC bias stress.
1995-12-31
International Nuclear Information System (INIS)
Single-crystalline cadmium selenide nanoparticles were obtained using high-temperature solution phase synthesis (HTSPS) synthesis. X-Ray powder diffraction and transmission electron microscopy were used to confirm the crystallinity and morphology of the resulting nanoparticles. To study the action of CdSe on antioxidant activity, we selected two biotechnological important strains of microalgae: cyanobacteria Spirulina platensis and red microalgae Porphyridium cruentum. In the case of Porphyridium cruentum, the obtained results demonstrated an increase in the productivity. For Spirulina platensis, the presence of the compound in the cultivating medium decreased the productivity of cyanobacteria.
2011-07-07
British Library Electronic Table of Contents (United Kingdom)
Tb3+-activated Sr3AlO4F phosphors were synthesized by a high-temperature solid-state reaction method. The investigation of photoluminescence and cathodoluminescence indicates that these phosphors can be effectively excited by ultraviolet light and low-voltage electron beam. The phosphors exhibit a tunable-green emission. The luminescence behaviors are explained by the site occupancy of Tb3+ ions in the host crystal and the cross-relaxation of 5D3 to 5D4 state.
2011-01-01
Tb3+-activated Sr3AlO4F phosphors were synthesized by a high-temperature solid-state reaction method. The investigation of photoluminescence and cathodoluminescence indicates that these phosphors can be effectively excited by ultraviolet light and low-voltage electron beam. The phosphors exhibit a tunable-green emission. The luminescence behaviors are explained by the site occupancy of Tb3+ ions in the host crystal and the cross-relaxation of 5D3 to 5D4 state.
2011-03-01
Visualization of direct contact heat transfer between water and molten alloy
Energy Technology Data Exchange (ETDEWEB)
We have been developing an innovative Steam Generator concept of Fast Breeder Reactors by using liquid-liquid direct contact heat transfer. In this concept, the SG shell is filled with a molten alloys, which is heated by primary sodium. Water is fed into the high temperature molten alloy, and evaporates by direct contact heating. In order to obtain the fundamental information to discuss the heat transfer mechanisms of the direct contact between the water and the alloy, this phenomenon was visualized by real-time neutron radiography. JRR-3M real-time thermal neutron radiography in Japan Atomic Energy Research Institute was used. Followings are main results. (1) The vigorous evaporation occurs in the molten alloy. This phenomena is different from the known phenomenon such as the evaporation of refrigerant R-113 in the water. (2) The evaporation in the bubble has finished in a moment due to high heat ...
1996-06-01
Solar desalination using humidification dehumidification processes. Pt. 1. A numerical investigation
Energy Technology Data Exchange (ETDEWEB)
A numerical investigation of a humidification dehumidification desalination (HDD) process using solar energy is presented. The HDD system consists mainly of a concentrating solar water heating collector, flat plate solar air heating collector, humidifying tower and dehumidifying exchanger. Two separate circulating loops constitute the HDD system, the first for heating the feed water and the second for heating air. A mathematical model is developed, simulating the HDD system, to study the influence of the different system configurations, weather and operating conditions on the system productivity. The model validity is examined by comparing the theoretical and experimental results of the same authors. It is found that the results of the developed mathematical model are in good agreement with the experimental results and other published works. The results show also that the productivity of the unit is strongly influenced by the air flow rate, ...
2004-05-01
Energy Technology Data Exchange (ETDEWEB)
A numerical investigation of a humidification dehumidification desalination (HDD) process using solar energy is presented. The HDD system consists mainly of a concentrating solar water heating collector, flat plate solar air heating collector, humidifying tower and dehumidifying exchanger. Two separate circulating loops constitute the HDD system, the first for heating the feed water and the second for heating air. A mathematical model is developed, simulating the HDD system, to study the influence of the different system configurations, weather and operating conditions on the system productivity. The model validity is examined by comparing the theoretical and experimental results of the same authors. It is found that the results of the developed mathematical model are in good agreement with the experimental results and other published works. The results show also that the productivity of the unit is strongly influenced by the air flow rate, ...
2004-05-01
Removal and recovery system of hexavalent chromium from waste water by tannin gel particles
Energy Technology Data Exchange (ETDEWEB)
Tannin gel particles that have extremely high adsorption capacity for hexavalent chromium Cr(VI) have been developed by controlling gelation of Mimosa tannin extracted from the bark of plants. The gelation process is composed of two stages; partial gelation of Mimosa tannin by reaction with formaldehyde (cross-linking agent) and granulation by dispersing the partially gelated solution into a liquid mixture of decalin ad a polyether nonionic surfactant with vigorous stirring. The structure of the tannin gel particles is controlled by a combination of operating conditions such as reaction time and temperature at both stages. The water content of the tannin gel particles that reflects their structure can be widely changed from 40 to 79 %(wet basis), even for a constant composition of 23 g Mimosa tannin and 6 ml formaldehyde (37 wt %). It is found that it is very important to increase the water content without losing mechanical ...
2000-10-01
Hot water extraction with in situ wet oxidation: Kinetics of PAHs removal from soil
International Nuclear Information System (INIS)
Finding environmentally friendly and cost-effective methods to remediate soils contaminated with polycyclic aromatic hydrocarbons (PAHs) is currently a major concern of researchers. In this study, a series of small-scale semi-continuous extractions - with and without in situ wet oxidation - were performed on soils polluted with PAHs, using subcritical water (i.e. liquid water at high temperatures and pressures, but below the critical point) as the removal agent. Experiments were performed in a 300 mL reactor using an aged soil sample. To find the desorption isotherms and oxidation reaction rates, semi-continuous experiments with residence times of 1 and 2 h were performed using aged soil at 250 deg. C and hydrogen peroxide as oxidizing agent. In all combined extraction and oxidation flow experiments, PAHs in the remaining soil after the experiments were almost undetectable. In combined extraction and oxidation no PAHs could ...
2006-09-01
Generalized simulation model for reservoir system analysis. Technical paper
Energy Technology Data Exchange (ETDEWEB)
This paper overviews the general features of computer program 'HEC-5, Simulation of Flood Control and Conservation Systems', with emphasis on the capabilities of the most recent release of HEC-5, Version 7.2, dated March 1991. HEC-5 can simulate the essential features and operation goals and constraints of simple or complex systems with simulation intervals ranging from minutes to one month. Single event flood analysis and period of record conservation analysis may be accomplished with the model. Flood control analysis includes balanced system operation for downstream damage centers with consideration of forecasted local flows and hydrologic routing. In addition, induced surcharge operation based on spillway gate regulation schedules can be simulated. Hydropower analysis may include run-of-river, peaking, and pumped storage plants as well as system power operation. Water supply simulation can include reservoir and downstream flow requirements in ...
1992-03-01
As part of its long-term control plan for combined sewer overflow (CSO) abatement, the city of Buffalo, New York, maintained a network of Hydrolab Datasondes (Hydrolab-Hach Company, Loveland, Colorado) to assess receiving water-quality effects by continuously logging dissolved oxygen, pH, temperature, conductivity, and turbidity. Although the effect of individual CSOs could be visualized, turbidity levels entering the Buffalo River from the upper watershed often were greater than from CSO discharges. Turbidity data showed that the Buffalo River was a net-sediment sink. Low dissolved oxygen levels were observed in the summer during dry weather, baseflow, and watershed-wide storms and CSO events. Some CSOs did not produce dissolved oxygen sags in the receiving waters, but others did. This information, together with the sampling done for organic and inorganic contaminants, can aid the decisionmaking process when prioritizing ...
Energy Technology Data Exchange (ETDEWEB)
High energy radiation was studied as a means for destroying hazardous organic chemical wastes. Tests were conducted at bench scale with a {sup 60}Co source, and at full scale (387 l/min) with a 1.5 MV electron beam source. Bench scale tests for both benzene and phenol included 32 permutations of water quality factors. For some water qualities, as much as 99.99% of benzene or 90% of phenol were removed by 775 krads of {sup 60}Co irradiation. Full scale testing for destruction of benzene in a simulated waste-water mix showed loss of 97% of benzene following an 800 krad dose and 88% following a 500 krad dose. At these loss rates, approximately 5 Mrad of electron beam irradiation is required to reduce concentrations from 100 g/l to drinking water quality (5 {mu}g/l). Since many waste streams are also inhabited by bacterial populations which may affect filtering operations, the effect of irradiation on those ...
1993-08-01
Energy Technology Data Exchange (ETDEWEB)
A conceptual hydrodynamic model in the Holocene and upper Pleistocene beneath the Louisiana wetlands is described in terms of safety distributions. Porewater safety is calculated from electrical measurements, including resistivity soundings, electric logs, and electromagnetic profiling. Electrical measurements support the primary, basin-wide groundwater flow model; however, the data also indicate secondary contributions from expulsion of fluids under geopressure along active growth faults and from original waters of deposition. Expulsion of water from growth faults has been described previously for deeper sections of the Pleistocene, but has not been reported for the Holocene or upper Pleistocene beneath the Louisiana wetlands. Porewater chemistry variations beneath the coastal wetlands are a consequence of the following (in order of importance): (1) environment of deposition; (2) a basin-wide, regional flow system; (3) ...
1995-06-01
Recent historical changes on the Belgian Meuse
International Nuclear Information System (INIS)
When a nuclear power station was installed on the Meuse in central Belgium, the impact of thermal, radioactive, and chemical waste on the water of the Neuse and on its biocenoses was studied. Three successive periods of development of the channel bed and the flood plain in Belgium have occurred, and their hydrological, physicochemical, and ecological consequences have been examined. Since the last century, the ecosystem of the Meuse has undergone, due to the increasing activity of man, modifications of increasing importance: marked reduction of the water flow, a drastic increase in the suspended material being transported, a degree of eutrophication of the water, and the disturbance of the original floral and faunal communities. The causes of this evolution of the Meuse can be itemized as different types of human interference in descending order of importance: (1) occupation of the catchment area; (2) ...
Anticipated climate change impacts on flood characteristics : Moisie River application
International Nuclear Information System (INIS)
The issue of global warming was discussed with particular reference to the changes that may occur in the hydrological regime within the coming decades in response to predicted changes in climate. Flood events for the 2050 time horizon were investigated along with the consequences on water management and dam safety. Dams operated by Hydro-Quebec are used for flood control, water supply, recreational activities and hydroelectricity. As such, the electric utility relies on methods to evaluate the adaptability of current management plans to climate change. This paper presented the results of a study conducted at the Moisie River watershed, located in northern Quebec. The HSAMI hydrologic model was used to evaluate and compare the occurrences where stream flows and water levels exceed critical values in order to assess the effectiveness of management plans in both current and climate change scenarios. The ...
Water Quality and 401 Certification | Clean Water Act | US EPA
Clean Water Act You are here: Water Laws & Regulations Policy & Guidance Clean Water Act Water Quality and 401 Certification Water Quality and 401 Certification Water Quality...
2011-08-28
Contamination by depleted uranium (Du) in South Serbia
Energy Technology Data Exchange (ETDEWEB)
The paper present the results of the study on D.U. (depleted uranium) contamination in the environment and possible effects on animal healths in the region o f Bujanovac. Samples of soil, feed, leaves, grass, lichen, moss, honey and water were collected randomly in 2003/2004 in the vicinity of the target area (500-1000 m) and 5 km from the target area. Activity of the radionuclides ({sup 226}Ra, {sup 232}Th, {sup 40}K, {sup 210}Pb, {sup 238}U, {sup 235}U, {sup 137}Cs, {sup 7}Be) in soils, grass, lichen, moss and honey was determined on Hp Ge detector (Canberra, relative efficiency 23%) by standard gamma spectrometry. Total alpha and beta activity in water was determined on proportional alpha/beta counter (Canberra 2400, efficiency for alpha emitters 11%, efficiency for beta emitters 30%). Non significantly higher values of concentrations of {sup 226}Ra, {sup 232}Th, {sup 238}U and {sup 235}U were ...
2006-07-01
Thermal control of electric vehicle batteries
Energy Technology Data Exchange (ETDEWEB)
The need to operate electric vehicles in warm, summer conditions and also provide for long periods of standby in cold climates is a challenging problem for any battery system. All advanced batteries of high specific energy require active cooling systems because adiabatic heating will raise the temperature to a level that is deleterious to cycle life. This cooling requires efficient paths for escape of heat to cooled surfaces; cooling the exterior of modules is insufficient. If a battery is heated by its own energy, and insulated to withstand exposure to a cold climate, only vacuum insulation will afford an appreciable reduction (>10{degrees}C) in the ambient temperature that can be tolerated. Standard insulations are of little use for this purpose because the heat loss rate causes too high a drain on the battery energy even for near-ambient temperature batteries.
1995-07-01
Role of temperature in the spontaneous precipitation of calcium sulfate dihydrate
Energy Technology Data Exchange (ETDEWEB)
The spontaneous precipitation of calcium sulfate in supersaturated solutions over the temperature range between 25.0 and 80.0 C was investigated by monitoring the solution specific conductivity during desupersaturation. From measurements of the induction times preceding the onset of precipitation the surface energy of the forming solid, identified as gypsum, was found between ca. 12 and 25 mJ/m{sup 2} for the temperature range between 80.0 and 25.0 C, respectively. Kinetics analysis showed that over 50 C it is possible that anhydrous calcium sulfate is forming as a transient phase converting into the more stable calcium sulfate dihydrate. The linear dependence of the rates of precipitation on the relative solution supersaturation suggested a mechanism according to which the growth units are integrated into the active sites of the supercritical nuclei by surface diffusion. According to the morphological examination of the ...
1999-02-16
Energy Technology Data Exchange (ETDEWEB)
Kinetics of postradiation polymerization of triethylene glycol ..cap alpha.., ..omega..-dimethacrylate has been studied by calorimetric method. The low-temperature radiolysis has been studied by ESR method. The radiation-chemical yield of radicals on ..gamma..-irradiation by /sup 60/Co is determined being equal to 6+-1 1/100 ev. Transformation of the radicals spectrum into the spectrum of propagating macroradicals proceeds at 140 K. After the transition from glassy to liquid state (Tsub(g)=193 K) the intensive postpolymerization begins. During the polymerization the disappearance of radicals is observed. For the low-temperature region the effective activation energy of polymerization is determined beina equal to 50.7+-0.8 kJ/mol.
1984-04-01
Low temperature deposition and characterization of TiO{sub 2} photocatalytic film through cold spray
Energy Technology Data Exchange (ETDEWEB)
Cold spray was employed as a novel low temperature approach to deposit titanium dioxide (TiO{sub 2}) photocatalytic film. The film microstructure was characterized using X-ray diffraction and scanning electron microscopy. The photocatalytic performance was examined through acetaldehyde degradation under ultraviolet illumination. Results showed that TiO{sub 2} film was successfully deposited on substrate surface through cold spray. The film thickness reached up to 15 {mu}m. The film presented a rough surface and porous structure. Owing to the low temperature of spray powder, no phase and particle size changes occurred to TiO{sub 2} during deposition. It was found that the cold-sprayed TiO{sub 2} film was active for photodegradation of acetaldehyde.
2008-04-30
Energy Technology Data Exchange (ETDEWEB)
The performance of scanning driver circuits fabricated with self-aligned aluminum gate polysilicon thin-film transistors (TFT's) is demonstrated. After the gate electrode patterning, the fabrication process temperature is kept below 400degC to enable the use of aluminum gate electrodes. The low-temperature crystallization phenomenon, which occurs when protons are implanted simultaneously with boron or phosphorus dopants, is employed to eliminate the 600degC activation-annealing process. A maximum clock frequency of about 2.0 MHz is achieved when the driver operating voltage is 24 V and the TFT channel length is 12 [mu]m. (author).
1994-01-01
International Nuclear Information System (INIS)
The performance of scanning driver circuits fabricated with self-aligned aluminum gate polysilicon thin-film transistors (TFT's) is demonstrated. After the gate electrode patterning, the fabrication process temperature is kept below 400degC to enable the use of aluminum gate electrodes. The low-temperature crystallization phenomenon, which occurs when protons are implanted simultaneously with boron or phosphorus dopants, is employed to eliminate the 600degC activation-annealing process. A maximum clock frequency of about 2.0 MHz is achieved when the driver operating voltage is 24 V and the TFT channel length is 12 #mu#m. (author).
Spin dynamics in Ho{sub 2}Ru{sub 2}O{sub 7}
Energy Technology Data Exchange (ETDEWEB)
The spin relaxation processes within the pyrochlore Ho{sub 2}Ru{sub 2}O{sub 7} have been investigated by neutron scattering and bulk property techniques. A single-ion process, that is thermally activated, dominates the spin-spin relaxation spectrum above 2 K. Assuming Arrhenius behaviour, we found an activation energy {delta} = (329 {+-} 6) K and characteristic relaxation time {tau}{sub 0} (5.2 {+-} 0.3) x 10{sup -12} s in the paramagnetic state, akin to those found in the spin ice, Ho{sub 2}Ti{sub 2}O{sub 7}. Atlow temperature (T<95 K) the activation energy lowers and below 20 K the entropy and ac susceptibility are similar to that observed in other spin ice compounds within a 10 kOe field.
2005-11-09
International Nuclear Information System (INIS)
The spin relaxation processes within the pyrochlore Ho_2Ru_2O_7 have been investigated by neutron scattering and bulk property techniques. A single-ion process, that is thermally activated, dominates the spin-spin relaxation spectrum above 2 K. Assuming Arrhenius behaviour, we found an activation energy #DELTA# = (329 #+-# 6) K and characteristic relaxation time #tau#_0 (5.2 #+-# 0.3) x 10"-"1"2 s in the paramagnetic state, akin to those found in the spin ice, Ho_2Ti_2O_7. Atlow temperature (T<95 K) the activation energy lowers and below 20 K the entropy and ac susceptibility are similar to that observed in other spin ice compounds within a 10 kOe field.
2005-11-09
Energy Technology Data Exchange (ETDEWEB)
The enzymatic activity characterization of the cellulolytic complex obtained from Trichoderma reesei QM 9414 and the influence of the enzymatic hydrolysis conditions on the hydrolysis yield are studied. Pure cellulose and native or alkali pretreated biomass Onopordum nervosum have been used as substrates. The values of pH, temperature, substrate concentration and enzyme-substrate ratio for the optimum activity of that complex, evaluated as glucose and reducing sugars production, have been selected. Previous studies on enzymatic hydrolysis of 0. nervosum have shown a remarkable effect of the alkaline pretreatments on the final hydrolysis yield. (Author) 10 refs.
1986-07-01
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