Radiometric X-ray fluorescence analysis was used for the determination of Mn, Fe, Cu, Zn and Pb in wastewater and sludges from three wastewatertreatment plants in Bratislava (SR). Metals were determined in wastewaters after preconcentration by 8-hydroxyquinoline and in sludges by drying and pressing to pellets. "2"3"8Pu and "1"0"9Cd was used for excitation of fluorescence radiation. (author).
TOXCHEM is a microcomputer based modelling system for predicting the fate of toxic contaminants in wastewatertreatment plants. The package evaluates concentrations of toxics in final effluent and waste sludge, and mass air emissions from municipal or industrial activated sludgewastewatertreatment plants. Maximum allowable influent concentrations of toxics required to meet effluent discharge or air emission limits can also be estimated. The package contains a read-only database with treatability parameters for over 100 contaminants, including organic compounds and metals. If effluent or sludge quality limits have been specified, treatment plant owners and operators can use the package to estimate the permissable discharge limits for dischargers to their collection system. A hypothetical example is provided of ...
Anaerobic treatment of a volatile fatty acid (VFA) mixture was investigated under psychrophilic (3 to 8°C) conditions in two laboratory-scale expanded granular sludge bed reactor stages in series....Full Text Available
A full scale co-digestion system for sludge and Olive oil mill effluent (OME) and a regional sludge management plan has been set-up to solve urgent environmental problems, modifying an existing cold municipal digester, by means of simple and effective technology. Monitoring of the full scale system demonstrated good compatibility between OME and sludge, up to 20% mixture, and high removal of organics compounds. Coagulant compounds present in OME (mainly Fats), promoted aggregation and settling of anaerobic sludge and also its acetoclastic activity, minimizing the load returned to the wastewatertreatment line and improving also the activated sludge system. The co-digestion of OME with sludge agreed the project purposes, and produced large quantity of biogas and electric energy.
The pattern of biodegradation and the chemical changes occurring in the macromolecular fraction of domestic sludge during autothermal thermophilic aerobic digestion (ATAD) was monitored and characterised...Full Text Available
As wastewater travels through a sewer system it undergoes changes in composition. The changes in composition may be caused by chemical, physical and/or biological processes. At present engineers do not take into consideration the impacts of these processes on the wastewater quality when designing wastewatertreatment systems. However, the impact of these processes on the chemical oxygen demand, biochemical oxygen demand, nitrogen and phosphorus content of the wastewater can be significant. In the case of the biological processes, microorganisms present in the water as it travels through the sewer system are similar to those found in an activated sludge process. Given that the microorganism population and the hydraulic retention time often resembles that of an activated sludge process, it would seem only reasonable to look further into the ...
Examining the relationship between biodiversity and functional stability (resistance and resilience) of activated sludge bacterial communities following disturbance is an important first step towards developing strategies for the design of robust biological wastewatertreatment systems. This study investigates the relationship between functional resistance and biodiversity of dominant bacterial taxa by subjecting activated sludge samples, with different levels of biodiversity, to toxic shock loading with cupric sulfate (Cu[II]), 3,5-dichlorophenol (3,5-DCP), or 4-nitrophenol (4-NP). Respirometric batch experiments were performed to determine the functional resistance of activated sludge bacterial community to the three toxicants. Functional resistance was estimated as the 30?min IC50 or th...
Increasingly, governments enact more stringent regulations governing nitrogen and phosphorus in the discharge effluent of wastewatertreatment plants. Scientists know that nitrogen and phosphorus accelerates the eutrophication of lakes and reservoirs and stimulates algal growth. Ammonia has proven to be toxic to aquatic life forms, including fish. Engineers favour Biological Nutrient Removal (BNR) over chemical addition to wastewatertreatment. Sequencing Batch Reactors (SBRs), a type of bioreactor requiring less land, provide the anaerobic, anoxic, and aerobic zones necessary for BNR. Methanol was used as an effective external source of carbon for denitrification but lacked research. The authors remedied this situation and some of the results were available. They indicated that the addition of methanol in the SBR increased solids production in the SBR, leading to increased sludge ...
The performance of anaerobic biological process is heavily process conditions dependent. In this study, an attempt has been made to investigate the influence of process conditions like temperature, sludge age and hydraulic retention time (HRT) on the efficiency of an upflow anaerobic sludge blanket (UASB) reactor and upflow anaerobic sludge filter (UASF) to treat combined industrial wastewater. Reactors were operated at easing ambient temperatures (38, 30, 20 and 14 deg. C) and correspondingly increasing sludge ages (60, 90, 120 and 150 days). At temperature 38 deg. C and sludge age of 60 days, UASF showed better performance than VASE reactor. This mainly due to the enhanced filtration through well-graded sand filter and fairly good biological activity in UASF. At this stage, lack of sludge granulation in VASE reactor resulted in poor ...
Anaerobic treatment of olive oil mill wastewaters (COD up to 220 kg/cubic m) is feasible, and the most promising results were obtained on UASB reactors, both at laboratory and pilot scale (tank capacity 15 litres and 5 cubic m), fed on diluted waste (COD = 13-18 kg/cubic m). Volumetric loading rates ranging from 16-21.5 kg COD/cubic m/day and 70% removal efficiencies were obtained with these digesters. Start-up of UASB reactors fed on olive oil mill waste is a delicate step which still has to be fully controlled and optimized. The best results were obtained by starting with very diluted waste (COD = 5 kg/cubic m). Granulation of the sludge, as achieved in Dutch UASB digesters fed on sugar beet wastewaters, was not obtained, but, even so, the settleability of the sludge was very good. 22 references.
Biosorption using activated sludge biomass (ASB) as a potentially sustainable technology for the treatment of wastewater containing different metal ions (Cd(II), Pb(II) and Zn(II)) was investigated. ASB metal uptake clearly competed with protons consumed by microbial biomass compared with control tests with non-activated sludge biomass. Biosorption tests confirmed maximum exchange between metal ions and protons at pH 2.0-4.5. It was revealed by the study that the amount of metal ions released from the biomass increased with biomass sludge concentration. The result showed that maximum absorption of metal ions was observed for Cd(II) at pH 3.5, Pb(II) at pH 4.0, and pH 4.5 for Zn(II) ions. The maximum absorption capacities of ASB for Cd(II), Pb(II) and Zn(II) were determined to be 59.3, 68.5 and 86.5%, respectively. The biosorption of heavy metals was directly proportional to ASB ...
Radionuclide X-ray fluorescence method with a Si/Li semiconductor detector and "2"3"8Pu exciting source was used in the determination of Cr, Fe, Ni, Cu, and Zn content in industrial wastewaters. Simultaneously, the effects of the wastewaters on activated sludge biocenose were evaluated. (author) 6 refs.; 1 fig.; 1 tab.
Wastewater from a food-manufacturing plant with a low concentration of organic matter was treated at 37 centigrade in an anaerobic fluidized-bed reactor or in an upflow anaerobic sludge blanket. As the influent TOC (total organic carbon) concentration decreased, the TOC removal efficiency in these reactors decreased from 85% to 65%. The concentration of suspended solids in the effluent could be reduced to 20 mg/l, which corresponded to 7% of that in the influent. The effluent from both reactors was treated aerobically in a fixed-bed reactor. The TOC concentration and optical density of effluent from the aerobic treatment were reduced to 5 mg/l and 0.005, respectively. When the effluent treated anaerobically or aerobically was passed over an activated carbon column, the effluent TOC concentration was reduced to 2 to 3 mg/l. The conductivity in raw wastewater was remarkably reduced on an ion-exchange ...
Recent central processing of domestic wastewater in Malaysia has initiated investigations into the disposal/utilization of the sewage sludge produced. We had conducted an experiment to investigate the feasibility of using dewatered sewage sludge and coconut coir as a peat substitute in a potting medium for chrysanthemum. The experiment involved 9 treatments with sewage sludge (SS) and coconut coir (CC) mixed in different ratios (v/v) to replace peat in the standard potting medium of 3:2:1 (soil: peat: sand).The potting medium contained the following treatments, T1: peat + recommended rates of Agroblend (Ag), a slow release fertilizer, and Grofas (Gf), a foliar fertilizer (commonly used medium and fertilization), T2: [1SS:1CC] + Ag, T3: [1SS:1CC] + half recommended rates of Agroblend and Grofas (1/2Ag + 1/2Gf), T4: [2SS:1CC] + Ag, T5: [2SS:1CC] + 1/2Ag + 1/2Gf, ...
The Outstanding Achievement Award in Water Pollution Control' is intended to recognize the water pollution control program that best demonstrates achieving significant, lasting, and measurable excellence in water-quality improvement in preventing water-quality degradation in a region, basin, or water body. This article is about the 1991 Award. This year, WPCF honored Los Angeles Hyperion Treatment Plant with a citation of outstanding achievement. To qualify for this honor, Hyperion has remarkably improved the quality of wastewater discharged to Santa Monica Bay since 1985. Capital programs developed by Los Angeles to achieve this rapid improvement, coined the Hyperion Improvement Program (HIP), reflect the city's commitment to protect the valuable resource of Santa Monica Bay. The HIP was conceived in 1986 to cease sludge ocean disposal by the end of 1987 and expedite effluent quality improvement before ...
Anaerobic processes have been widely used for the treatment of various high-strength industrial wastewaters. However, application has been limited for the treatment of sulfate-rich industrial wastewaters, such as those from the petrochemical, and mining industries. Wastewaters containing benzoate and sulfate were treated in two upflow anaerobic sludge blanket (UASB) reactors at 34--37 C for 320 d. The sulfate concentration was increased stepwise in Reactor-A up to 7,500 mg/L, and was kept mostly constant at 3,000 mg/L in Reactor-B. Both reactors removed over 98% of organic chemical-oxygen demand (COD) for sulfate up to 6,000 mg/L, despite the fact that the mixed liquor contained up to 769 mg S/L of total sulfides and up to 234 mg S/L of dissolved H{sub 2}S. Sulfate0reducing efficiency decreased with the increase in sulfate concentration, but increased with time ...
A series of modifications which increased the capacity of Canadian Electrolytic Zinc's Valleyfield plant from 220,000 MT/year to 260,000 MT/year during the last decade is discussed, combined with an an overview of the plant's operations. The modifications included modernisation of the waste disposal methods and facilities, such as a new high-density sludgewastewatertreatment process, a new process to remove selenium from weak acid solutions and the jarofix process. Roasting capacity also has been improved by recent investments in new cooling coils, rebricking, oxygen enrichment and process automation. In addition to increases in refining capacity, the improvements also enabled the company to minimize its impact on the environment and the community.
Red mud is a by-product of bauxite processing through Bayer process. The amount of red mud generated depends largely on the type of ore used and the processing. Use of red mud as a catalyst can be a good alternative to the existing commercial catalysts. Its properties such as iron content in form of ferric oxide (Fe{sub 2}O{sub 3}), high surface area, sintering resistance, resistance to poisoning and low cost make it an attractive potential catalyst for many reactions. Besides red mud, ferric ion sludge from wastewatertreatment plant has also been studied for its catalytic properties, mainly due to its ferric oxide constituent. This paper reviews the studies on red mud as a catalyst. The catalyst characteristics, reaction mechanisms involved and performance are examined and compared with iron oxide catalyst and commercial catalysts. (author)
This paper describes a comprehensive model of wastewatertreatment in secondary facultative ponds, which combines 3D hydrodynamics with a mechanistic water quality model. The hydrodynamics are based on the Navier-Stokes equation for incompressible fluids under shallow water and Boussinesq assumptions capturing the flow dynamics along length, breadth and depth of the pond. The water quality sub model is based on the Activated Sludge Model (ASM) concept, describing COD and nutrient removal as function of bacterial growth following Monod kinetics, except for Escherichia coli removal, which was modelled as first order decay. The model was implemented in the Delft3D software and was used to evaluate the effect of wind and the addition of baffles on the water flow pattern, temperature profiles i...
This study describes the feasibility of anaerobic treatment of complex phenolics mixture from a simulated synthetic coal wastewater using four identical 13.5 L (effective volume) bench scale hybrid up-flow anaerobic sludge blanket (HUASB) (combining UASB + anaerobic filter) reactors at four different hydraulic retention times (HRT) under mesophilic (27 #+-# 5 "oC) conditions. Synthetic coal wastewater with an average chemical oxygen demand (COD) of 2240 mg/L and phenolics concentration of 752 mg/L was used as substrate. The phenolics contained phenol (490 mg/L); m-, o-, p-cresols (123.0, 58.6, 42 mg/L); 2,4-, 2,5-, 3,4- and 3,5-dimethyl phenols (6.3, 6.3, 4.4 and 21.3 mg/L) as major phenolic compounds. The study demonstrated that at optimum HRT, 24 h, and phenolic loading rate of 0.75 g COD/(m"3-d), the phenolics and COD removal efficiency of the reactors were 96% and 86%, respectively. Bio-kinetic ...
N-substituted aromatics are important priority pollutants entering the environment primarily through anthropogenic activities associated associated with the industrial production of dyes, explosives, pestides, and pharmaceuticals. Anaerobic treatment of wastewaters discharged by these industries could potentially be problematical as a result of the high toxicity of N-substituted aromatics. The objective of this study was to examine the structure-toxicity relationship of N-substituted aromatic compounds to acetoclastic methanogenic bacteria. The toxicity was assayed to serum flasks by measuring methane production in granular sludge. Unacclimated cultures were used to minimize the biotransformation of the toxic organic chemicals during the test. The nature and the degree of the aromatic substitution were observed to have a profound effect on the toxicity of the test compound. Nitroaromatic compounds were, on the average, over ...
We investigated the effects of wastewatertreatment plant (WWTP) discharge on the ecology of bacterial communities in the sediment of a small, low-gradient stream in South Australia. The quantification...Full Text Available
...Tota-MaharajE-Mail: Interests: water and wastewatertreatment, environmental engineering and sustainable systems; sustainable water management; sustainable urban drainage systems (SUDS); combined renewable energy applications with reverse osmosis desalination; microbial fuel cells for bioenergy production and treatment of urban wastewater; solar photocatalytic treatment and disinfection of water/wastewater Dr. Simon Toze CSIRO Land and Water, Queensland Bioscience Precinct - St Lucia, 306 Carmody Road, St Lucia QLD 4067,...
The purpose of this study is to develop the radioisotope tracer technology, which can be used in solving industrial and environmental problems and to build a strong tracer group to support the local industries. In relation to the tracer technology in 1999, experiments to estimate the efficiencies of a sludge digester of a waste water treatment plant and a submerged biological reactor of a dye industry were conducted. As a result, the tracer technology for optimization of facilities related to wastewatertreatment has been developed and is believed to contribute to improve their operation efficiency. The quantification of the experimental result was attempted to improve the confidence of tracer technology by ECRIN program which basically uses the MCNP simulation principle. Using thin layer activation technique, wear of tappet shim was estimated. Thin layer surface of a tappet shim was irradiated by ...
Background, aim and scope Treatment performance of constructed wetlands (CWs) is largely dependent on the characteristics of the wastewater. Although livestock wastewater is readily biodegradable in general, its variety in biodegradability can still be significant in practice. In addition, it is a common practice to periodically use disinfectants in livestock activities for health concerns. Obviously, the residual of the disinfectants in livestock wastewater may have serious inhibitory effect on the microbial activities during wastewatertreatment. Thus, the main objective of this study was to examine the variety of livestock wastewater in biodegradability and its effect on the performance of a pilot scale tidal flow CWs (TFCWs) in organic matter and nitrogen removal. Furthermore, investig...
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We report the isolation of a new bacterium species (named as DN-06) that degrades pyridine, a model compound containing both carbon and nitrogen, from the aerobic activated sludge in a coking wastewatertreatment plant. DN-06 was identified as Achromobacter sp. using 16S rDNA sequence analysis. In batch culture, more than 95% of pyridine (500?mg/L) was degraded within 18?h by DN-06 grown at 35?C and pH?8 with agitation at 170?rpm. Degradation experiments of pyridine at different initial concentrations (50?4,300?mg/L) revealed that pyridine was an inhibitory substrate, and that neither yield coefficient Y nor endogenous decay coefficient K d was a constant. The values of Y and K d were 0.55?0.74 and 0.0032?0.0057?h?1, respectively. Five kinetic models (Haldane, Yano, Aiba, Webb, and Monod) ...
This paper reported on a study in which hydrogen was produced by fermentation of biomass. A continuous process using a non-sterile substrate with a readily available mixed microflora was used on heat treated digested sewage sludge from a wastewatertreatment plant. Hydrogen was produced from waste sugar at a pH of 5.2 and a temperature of 37 degrees C. An experimental setup of three 5.5 L working volume continuously stirred tank reactors (CSTR) in different stirring speeds were constructed and operated at 7 different hydraulic retention times (HRTs) and different organic loading rates (OLR). Dissolved organic carbon was examined. The results showed that the stirring speed of 135 rpm had a beneficial effect on hydrogen fermentation. The best performance was obtained in 135 rpm and 8 h of HRT. The amount of gas varied with different OLRs, but could be stabilized on a high level. Methane was not detected when the HRT was less ...
The Korea Atomic Energy Research Institute has launched a decommissioning program of uranium conversion plant. One of the important tasks in the decommissioning program is the treatment of the sludge, which was generated during operation and stored in the two ponds of the lagoon. The treatment requires the volume reduction of lagoon sludges for the low cost of the program and the conversion of the chemical forms, including uranium, for the acceptance at the final disposal site. The physical properties, such as densities, were measured and chemical compositions and radiological properties were analyzed. The denitration was a candidate process which would satisfy the requirements for sludgetreatment, and the characteristics of thermal decomposition and dissolution with water were analyzed. The main compounds of the sludge were ammonium and ...
Olive oil mill wastewaters (OMW) cause disposal problems because they contain powerful pollutants such as phenolic compounds. Complete biodegradation or removal of these compounds is hardly achieved by a single treatment method. In this work, we investigated 2 integrated technologies for the treatment of the recalcitrant contaminants of OMW, allowing water recovery and reuse for agricultural purposes. (Author)
Radionuclide x-ray fluorescence method was used in the determination of Cr, Ni and other heavy metals content in wastewater of an engineering plant taken both before and after chemical treatment. Toxic effects of the wastewaters using Allium cepa root tip cells were tested. (author) 8 refs.; 2 tabs.
Among the several chemical processes conducted for the removal of organic matter present in wastewaters coming from some agro-industrial plants (wine distilleries, olive oil mills, etc), the oxidation by ozone has shown a great effectiveness in the destruction of specially refractory pollutants: it is demonstrated that the biodegradability of those wastewaters increases aflcer an ozonation pretreatment. Their great pollutant character is imputed to the presence of some organic compounds, like phenols and polyphenols, which are toxic and inhibit the latter biological treatments. In this research, a competitive kinetic procedure reported by Clurol and Nekouinaini is applied to determine the degradation rate constants by ozone of several phenolic acids which are present in the wastewaters from the olive oil obtaining process. The resulting kinetic expressions for the ozonation reactions are useful for the ...
Olive mill effluent (OMW) is an example of a wastewaters containing high concentrations of recalcitrant and toxic compounds which are polyphenolics of different molecular weight. It causes disposal problems because they contain powerful pollutants. Treatment and detoxification of phenolic fraction extracted from olive mill wastewaters as well as a synthetic phenolic mixture was investigated by electro-Fenton method. Results shows that this method is highly efficient in polymerising low molecular mass phenolics and removing a large amount of recalcitrant polyphenolic compounds. This treatment decreased 78% of the toxicity which sustained a good anaerobic post-treatment. (orig.)
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Discussed are various aspects of heating oil `sludge`: How it forms, typical problems it causes, how sludge-control additives work, what should be expected of them, and what happens in a contaminated system when such additives are used. Test results from laboratory and field experiments demonstrate that performance of commercially available additives varies greatly. The concept of `end-of-the-line` treatment is described and compared with bulk fuel treatment. A procedure is described whereby a retailer can test additives himself, and thus determine just what those additives will or will not do for his business. Finally, the economics of an effective treatment program are outlined.
This paper is dedicated to the treatment of sludge occurring in frame of the Egyptian produced from oil and gas production. The activity levels of three radium isotopes: Ra-226 (of U-series), Ra-228 and Ra-224 (of Th-series) in the solid TENORM waste (sludge) were first evaluated and followed by a sequential treatment for all radium species (fractions) presented in TENORM. The sequential treatment was carried out based on two approaches `A' and `B' using different chemical solutions. The results obtained indicate that the activity levels of all radium isotopes (Ra-226, Ra-228 and Ra-224) of the environmental interest in the TENORM waste sludge were elevated with regard to exemption levels established by IAEA [International Atomic Energy Agency (IAEA), International basic safety standards f...
A pretreatment flowsheet was tested for separating key radionuclide components from the sludge stored in one of the high level waste tanks (B-110) at the Hanford Site; this sludge resulted primarily from the bismuth phosphate process, which was one of the three major plutonium separation processes used at Handford. This test involved (1) washing with water, (2) caustic leaching, (3) acid dissolution, (4) separation of transuranic elements (TRUs) by extraction with octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide(CMPO), (5) separation of Sr by extraction with di-t-butylcyclohexano-18-crown-6, (6) separation of Cs from the acid-dissolved sludge solution by treatment with ammonium molybdophosphate (AMP), and (7) separation of Cs from the sludge wash and caustic leach solutions by ion exchange using a phenol-formaldehyde resin (CS-100). The results of the radionuclide ...
... Biodegradable plastics have the potential to be used in various flushable sanitary product applications such as sanitary towels, colostomy bags and other absorbent products. In addition, effluent from recycling activities must be treated in wastewatertreatment plants and may contain biodegradable plastics. Flushable biodegradable plastics can have an adverse impact on wastewatertreatment plants due to the very fast throughputs, typically 4 to 8 hours, from the drain to the plant. This length of time is insufficient for many biodegradable plastics to lose their structure. Such plastics can ...
Contents of this report are under the following topical sections: Legal Authority; Summary and Scope; Data Collection Activities; Industry Description; Industry Subcategorization; Water Use and Wastewater Characterization; Pollutants Selected for Regulation; Pollution Prevention and WastewaterTreatment Technologies; Development of Control and Treatment Options; Costs of Technology Bases for Regulations; Pollutant Reduction Estimates; Non-Water Quality Impacts; Implementation of Proposed Effluent Limitation Guidelines and Standards; Analytical Methods; and Glossary.
The high nutrient nitrogen and organic matter contents of sewage sludge (SS) make it a potential organic fertilizer for sandy soil. In this study, "1"5N-labelled ammonium sulphate was used to investigate the availability of nitrogen from irradiated and non-irradiated sewage sludge to tomato plants. The application of sewage sludge to sandy soil increased dry matter production (DMP), nitrogen yield (NY) and nitrogen recovery (NR) over two successive years. A positive relationship was found between sludge application rate and DMP and NY. The increase was significantly higher (P=0.05) in irradiated than non-irradiated sewage sludge. Total nitrogen derived from non-irradiated sewage sludge are : 48.0, 63.7, 73.5, 105.2 Kg/ha, whereas, the total nitrogen derived from irradiated sewage sludge are: 55.1, 72.5, 88.9, 141.4 Kg/ha corresponding to ...
The Tank Waste Remediation System (TWRS) Program mission is to store, treat, and immobilize highly radioactive Hanford Site waste (current and future tank waste and the strontium/cesium capsules) in an environmentally sound, safe, and cost-effective manner. The scope of the TWRS Waste Pretreatment Program is to treat tank waste and separate that waste into HLW and LLW fractions and provide additional treatment as required to feed LLW and HLW immobilization facilities. Enhanced sludge washing was chosen as the baseline process for separating Hanford tank waste sludge. Section 1.0 briefly discusses the purpose of the evaluation plan and provides the background that led to the choice of enhanced sludge washing as the baseline process. Section 2.0 provides a brief summary of the evaluation plan details. Section 3.0 discusses, in some detail, the technical work planned to support the evaluation of enhanced ...
The AFGD process as demonstrated by Pure Air at the Bailly Station offers a reliable and cost-effective means of achieving a high degree of SO{sub 2} emissions reduction when burning high-sulfur coals. Many innovative features have been successfully incorporated in this process, and it is ready for widespread commercial use. The system uses a single-loop cocurrent scrubbing process with in-situ oxidation to produce wallboard-grade gypsum instead of wet sludge. A novel wastewater evaporation system minimizes effluents. The advanced scrubbing process uses a common absorber to serve multiple boilers, thereby saving on capital through economies of scale. Major results of the project are: (1) SO{sub 2} removal of over 94 percent was achieved over the three-year demonstration period, with a system availability exceeding 99.5 percent; (2) a large, single absorber handled the combined flue gas of boilers generating 528 MWe of power, and no spares were ...
Radionuclide X-ray fluorescence analysis was used for the determination of Cr, Fe, Cu, Zn and Ph in industrial wastewaters (from surface treatment of metals and glasses) after precipitation of determined elements by 8-hydroxyquinoline. (author).
Purge water from a typical wet flue gas desulfurization system contains myriad chemical constituents and heavy metals whose mixture is determined by the fuel source and combustion products as well as the stack gas treatment process. A well-designed water treatment system can tolerate upstream fuel and sorbent arranged in just the right order to produce wastewater acceptable for discharge. This article presents state-of-the-art technologies for treating the waste water that is generated by wet FGD systems. 11 figs., 3 tabs.
The possibility of oxidizing at a PbO{sub 2} anode the phenols and polyphenols, present in the olive oil mill wastewater, has been studied as a pre-treatment for the submission of such wastewater to the traditional biological treatments. The results obtained operating at current densities ranging 500 to 2000 A/m{sup 2} show that it is possible to reduce the concentration of the phenolic components, which interfere with the biological treatments, down to low values without decreasing too much the total organic content of the wastewater. [Italian] E' stata studiata la possibilita' di ossidare anodicamente i componenti fenolici delle acque reflue di frantoio, quale pretrattamento delle stesse prima del loro invio ai processi di trattamento biologico. I risultati ottenuti impiegando PbO{sub 2} quale materiale anodico e operando con ...
Air toxics from the industrial wastewatertreatment plants (IWTPs) impose serious health concerns on its surrounding residential neighborhoods. To address such health concerns, one of the key challenges is to quantify the air emissions from the IWTPs. The objective here is to characterize the air emissions from the IWTPs and quantify its associated uncertainty. An IWTP receiving the wastewaters from an airplane maintenance facility is used for illustration with focus on the quantification of air emissions for benzyl alcohol, phenol, methylene chloride, 2-butanone, and acetone. Two general fate models, i.e., WATER9 and TOXCHEM+V3.0 were used to model the IWTP and quantify the air emissions. Monte Carlo and Bootstrap simulation were used for uncertainty analysis. On average, air emissions fr...
Biomass can provide a substantial energy source. Liquids are preferred for use as transportation fuels because of their high energy density and handling ease and safety. Liquid fuel production from biomass can be accomplished by any of several different processes including hydrolysis and fermentation of the carbohydrates to alcohol fuels, thermal gasification and synthesis of alcohol or hydrocarbon fuels, direct extraction of biologically produced hydrocarbons such as seed oils or algae lipids, or direct thermochemical conversion of the biomass to liquids and catalytic upgrading to hydrocarbon fuels. This report discusses direct thermochemical conversion to achieve biomass liquefaction and the requirements for wastewatertreatment inherent in such processing. 21 refs.
The results of the investigations show that magnetic treatment is a quite practical and effective method of intensifying certain technological processes in the coking industry. Magnetic treatment was utilized for improving the production of ammonium sulfate, refining of the naphthalene fraction, removal of sludge from wash oil in the benzol division, and the treatment of tar before fractionation. 2 references, 3 tables.
Novel lightweight bricks have been produced by sintering mixes of dried water treatmentsludge and rice husk. Samples containing up to 20 wt.% rice husk have been fired using a heating schedule that allowed effective organic burn-out. Rice husk addition increased the porosity of sintered samples and higher sintering temperatures increased compressive strengths. Materials containing 15 wt.% rice husk that were sintered at 1100 degrees C produced low bulk density and relatively high strength materials that were compliant with relevant Taiwan standards for use as lightweight bricks. PMID:19596512
The bibliography contains citations concerning the use of dialysis in the treatment of wastewaters. Techniques for the removal of metals, ammonia, waste acids, nitrates, and phosphates are described. Special attention is given to the desalination of liquid wastes. Applications of this technology to the treatment of effluent from the agrochemical, petrochemical, tanning, and electroplating industries are discussed. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)
Since 1975 All Volatile Treatment (AVT) has been the preferred method for controlling the secondary system operating environment in Westinghouse PWR plants. However, since AVT provides no buffering action against corrodent species present in the water as trace contaminants, utilities have initiated programs which combine control of contaminant ingress with total steam generator sludge management. The earliest applications of boric acid, to control denting type corrosion, began in 1978 and have continued up to the present time. Boric Acid has also been added as an inhibitor for SCC/IGA type corrosion since 1985. There are now approximately 30 plants operating with boric acid or boric acid/morpholine chemistry in the secondary system, and a growing number of plants where morpholine is being used as an additive to maintain pH and reduce iron transport attributable to erosion/corrosion. The impact of these modifications in the operating chemistry ...
This paper explores the potential of combining substance-flow modelling with water and wastewater sampling to trace consumption-related substances emitted through the urban wastewater. The method is exemplified on sucralose. Sucralose is a chemical sweetener that is 600 times sweeter than sucrose and has been on the European market since 2004. As a food additive, sucralose has recently increased in usage in a number of foods, such as soft drinks, dairy products, candy and several dietary products. In a field campaign, sucralose concentrations were measured in the inflow and outflow of the local wastewatertreatment plant in Linkoping, Sweden, as well as upstream and downstream of the receiving stream and in Lake Roxen. This allows the loads emitted from the city to be estimated. A method c...
In this study, the use of the weakly basic anion exchange resins of phenol-formaldehyde (Amberlyst A 23), polyacrylate (Amberlite IRA 67) and polystyrene (Lewatit MonoPlus MP 62) matrices for removal of the reactive dye Remazol Black B (RBB) from aqueous solution and wastewater were investigated. RBB sorption on the anion exchangers was a time dependent process. Color reduction percentiles of 75.2, 33.9 and 25.1% in wastewatertreatment were found after 216 h of phase contact time with Lewatit MonoPlus MP 62, Amberlyst A 23 and Amberlite IRA 67, respectively. Inorganic salts and anionic surfactant action influenced RBB uptake by the anion exchangers. The amounts of dye retained by the anion exchangers increased with a rise in temperature. The maximum sorption capacities calculated from the...
SummaryInitial results from the use of activated dolomite from QUESTOR project L1 have proved extremely encouraging in terms of metallic ion (also phosphate, nitrate and dye) removal from wastewater, with capacities in some instances in excess of commercially available activated carbons.This new project involves investigating actual plant effluent in laboratory scale columns and the design of a pilot scale rig for on site trials. The project also involves investigating disposal options and an economic [continued...
Magnetic separation of several classes of antibiotics was investigated using electrochemical magnetic seeding. Electrocoagulation with a sacrificial anode followed by addition of magnetite particles was applied for the magnetic seeding of antibiotics. With electrochemical magnetic seeding using an iron anode, tetracycline antibiotics (oxytetracycline, chlortetracycline, doxycycline and tetracycline) and cephalosporin antibiotic (cefdinir) were rapidly removed from synthetic wastewater by magnetic separation using a neodymium magnet. Iron and aluminium anodes were suitable for magnetic seeding of the antibiotics. The results indicated that the ability of antibiotics to form strong complex with iron and aluminium allowed the higher removal by magnetic separation. This method would be appropriate for rapid treatment of antibiotics in wastewater.
This paper presents a mathematical model to analyze the solar evaporation in a shallow pond in steady state, when the inlet flow rate, concentration, surface area and solar radiation are given. The simultaneous heat and mass transfer mechanisms are considered for quantifying the amount of evaporated water to the atmosphere and the actual absorbed heat by wastewater is calculated to obtain the bottom temperature of water pond. The heat losses to air by radiation and convection mechanisms are considered and the heat transmission across the water film is evaluated by the forced convection mechanism. 6 refs., 5 figs., 1 tab.
Laboratory {open_quotes}jar{close_quotes} tests compared eleven different fuel oil and diesel fuel sludge-control additives. Factors studied included (1) ability to disperse and prevent buildup of sludge deposits on surfaces, (2) ability to protect steel from corrosion, (3) ability to inhibit growth and proliferation of bacteria, and (4) ability to disperse water. Results varied greatly, and it was found that many commercial products do not do what they claim. It is concluded that fuel retailers should not believe manufacturers` claims for their additive products, but rather should test such products themselves to be sure that the benefits of treatment are real. A simplified form of the procedure used here is proposed as one way for dealers to do such testing.
This study examined the atmospheric pollution created by some waste treatment and disposal facilities in the State of Kuwait. Air monitoring was conducted in a municipal wastewatertreatment plant, an industrial wastewatertreatment plant established in a petroleum refinery, and at a landfill site used for disposal of solid wastes. Such plants were selected as models for waste treatment and disposal facilities in the Arabian Gulf region and elsewhere. Air measurements were made over a period of 6 months and included levels of gaseous emissions as well as concentrations of volatile organic compounds (VOCs). Samples of gas and bioaerosols were collected from ambient air surrounding the treatment facilities. The results obtained from this study have indicated the presence of VOCs and other gaseous pollutants such as methane, ammonia, and ...
A permeable reactive mixture has been developed using low cost, readily available materials that is capable of providing effective, long-term phosphorous treatment in areas impacted by on-land wastewater disposal. The reactive mixture creates a geochemical environment suitable for P-attenuation by both adsorption and precipitation reactions. Potential benefits include significant reductions in phosphorous loading to receiving groundwater and surface water systems, and the accumulation of P-mass in a finite and accessible volume of material. The mixture may be applied as a component within surface treatment systems or in subsurface applications such as horizontal or vertical permeable reactive walls. The mixture averaged > 90% treatment efficiency over 3.6 years of continuous-flow laboratory column experiments. The mixture was further evaluated at the pilot-scale to treat municipal ...
A novel bioelectrochemical membrane reactor (BEMR), which takes advantage of a membrane bioreactor (MBR) and microbial fuel cells (MFC), is developed for wastewatertreatment and energy recovery. In this system, stainless steel mesh with biofilm formed on it serves as both the cathode and the filtration material. Oxygen reduction reactions are effectively catalyzed by the microorganisms attached on the mesh. The effluent turbidity from the BEMR system was low during most of the operation period, and the chemical oxygen demand and NH(4)(+)-N removal efficiencies averaged 92.4% and 95.6%, respectively. With an increase in hydraulic retention time and a decrease in loading rate, the system performance was enhanced. In this BEMR process, a maximum power density of 4.35 W/m(3) and a current density of 18.32 A/m(3) were obtained at a hydraulic retention time of 150 min and external resister of 100 ?. The Coulombic efficiency was 8.2%. Though the ...
Chemoheterotrophic thermophilic bacteria were used to achieve enhanced hydrocarbon degradation during slurry-phase treatment of oily waste sludges from petroleum refinery operations. Aerobic and anaerobic bacterial cultures were examined under thermophilic conditions to assess the effects of mode of metabolism on the potential for petroleum hydrocarbon degradation. The study determined that both aerobic and anaerobic thermophilic bacteria are capable of growth on petroleum hydrocarbons. Thermophilic methanogenesis is feasible during the degradation of hydrocarbons when a strict anaerobic condition is achieved in a slurry bioreactor. Aerobic thermophilic bacteria achieved the largest apparent reduction in chemical oxygen demand, freon extractable oil, total and volatile solid,s and polycyclic aromatic hydrocarbons (PAHs) when treating oily waste sludges. The observed shift with time in the molecular weight distribution of ...
Chemoheterotrophic thermophilic bacteria were used to achieve enhanced hydrocarbon degradation during slurry-phase treatment of oily waste sludges from petroleum refinery operations. Aerobic and anaerobic bacterial cultures were examined under thermophilic conditions to assess the effects of mode of metabolism on the potential for petroleum hydrocarbon degradation. The study determined that both aerobic and anaerobic thermophilic bacteria are capable of growth on petroleum hydrocarbons. Thermophilic methanogenesis is feasible during the degradation of hydrocarbons when a strict anaerobic condition is achieved in a slurry bioreactor. Aerobic thermophilic bacteria achieved the largest apparent reduction in chemical oxygen demand, freon extractable oil, total and volatile solid,s and polycyclic aromatic hydrocarbons (PAHs) when treating oily waste sludges. The observed shift with time in the molecular weight distribution of ...
The Kemp's Ridley sea turtle, Lepidochelys kempi, is an endangered species. The National Marine Fisheries Service's Head Start program is part of an international operation to save the turtles from extinction. Under the Head Start program, eggs from the Ridley's only known wild nesting beach at Rancho Nuevo in Mexico are transported to Padre Island on the Texas coast to be hatched. The head start enables the turtles to develop a survival advantage. The principal objective was to develop baseline waste-characterization data required to design a waste-watertreatment scheme for the Galveston Head Start facility. As a secondary objective, preliminary testing of some filtration components was undertaken to determine which units were most appropriate for inclusion in a wastewatertreatment scheme.
Palladium/magnetite nanoparticulate catalysts were developed for efficient elimination of halogenated organic pollutants from contaminated wastewater. Particle recovery from treated water can be ensured via magnetic separation. However, in worst-case scenarios, this catalyst removal step might fail, leading to particle release into the environment. Therefore, a toxicological study was conducted to investigate the impact of both pure magnetite and palladium/magnetite nanoparticle exposure upon human skin (HaCaT) and human colon (CaCo-2) cell lines and a cell line from rainbow trout gills (RTgill-W1). To quantify cell viability after particle exposure, three endpoints were examined for all tested cell lines. Additionally, the formation of reactive oxygen species was studied for the human cells. The results showed only minor effects of the particles on the tested cell systems and support the assumption that palladium/magnetite nano-catalysts can be implemented for a ...
The objectives of this study are to make a biosensor on a trial basis which can instantaneously measure the nitrogen in wastewater, and to develop a wastewatertreatment system which is capable of on-line measurement and controlling. The system provides easier operational control relating to such a high efficient treatment as the removal of nitrogen content in wastewater, serving as a solution to the eutrophication problem. It can be applied also to the analysis of fertilizer components for agriculture. Ammonia oxidizing bacteria were immobilized with cellulose acetate film, which is mounted on a diaphragm type oxygen electrode to make a sensor, and its responsibility was studied. The gradient is slow in high concentration but sharp in low concentration, and it seems possible to use it for the measurement for less than 20 ppm nitrogen concentration. The dependence of the sensor ...
The purpose of this study is to extend the knowledge base for wetland treatment to include processes and substances of particular importance to small, on-site systems receiving oil and gas well waste water. Collection of data on the sorption of heavy metals and the degradation of toxic organics is one of the key tasks. The toxic organics phenolics and anthracene, and chromium and copper have been selected as target adsorbates. An information search was performed on oil refinery waste treatment wetland systems.
Case studies are presented for treatment of refinery wastes in a pilot-scale thin-film evaporator, the removal of volatiles from industrial wastewater for two steam strippers, and the removal of semivolatiles from water by steam stripping followed by liquid-phase carbon adsorption. The report provides data on removal efficiency, air emissions, process residuals, treatment costs, and process limitations. Details on sampling and analytical procedures, quality assurance, and process data are contained in the Appendixes (Volume II).
Case studies are presented for treatment of refinery wastes in a pilot-scale thin-film evaporator, the removal of volatiles from industrial wastewater for two steam strippers, and the removal of semivolatiles from water by steam stripping followed by liquid-phase carbon adsorption. The report provides data on removal efficiency, air emissions, process residuals, treatment costs, and process limitations. Details on sampling and analytical procedures, quality assurance, and process data are contained in the Appendixes (Volume II).
This paper is dedicated to the treatment of sludge occurring in frame of the Egyptian produced from oil and gas production. The activity levels of three radium isotopes: Ra-226 (of U-series), Ra-228 and Ra-224 (of Th-series) in the solid TENORM waste (sludge) were first evaluated and followed by a sequential treatment for all radium species (fractions) presented in TENORM. The sequential treatment was carried out based on two approaches 'A' and 'B' using different chemical solutions. The results obtained indicate that the activity levels of all radium isotopes (Ra-226, Ra-228 and Ra-224) of the environmental interest in the TENORM waste sludge were elevated with regard to exemption levels established by IAEA [International Atomic Energy Agency (IAEA), International basic safety standards for the protection against ionizing radiation and for the safety of ...
This paper is dedicated to the treatment of sludge occurring in frame of the Egyptian produced from oil and gas production. The activity levels of three radium isotopes: Ra-226 (of U-series), Ra-228 and Ra-224 (of Th-series) in the solid TENORM waste (sludge) were first evaluated and followed by a sequential treatment for all radium species (fractions) presented in TENORM. The sequential treatment was carried out based on two approaches 'A' and 'B' using different chemical solutions. The results obtained indicate that the activity levels of all radium isotopes (Ra-226, Ra-228 and Ra-224) of the environmental interest in the TENORM waste sludge were elevated with regard to exemption levels established by IAEA [International Atomic Energy Agency (IAEA), International basic safety standards for the protection against ionizing ...
In situ toxicity tests were designed for Ceriodaphnia dubia and Chironomus tentans as part of a larger study designed to assess the effectiveness of constructed wetlands for the treatment of wastewater produced by oil production at Suncor OSG. The artificial wetlands were 50m long by 3m wide, with three replicates of the control and the treatment. Each wetland had four sample sites equidistant along its length, creating a gradient of treatment from site A being the most toxic to site D being the least toxic. Each test was conducted twice during the summer of 1994. Both the Ceriodaphnia and Chironomus test cages were a flow through design to allow for maximal exposure to the water within the wetlands. Mortality and reproduction were used as endpoints for Ceriodaphnia, whereas mortality and growth were used as endpoints for the Chironomus test. Test durations were fifteen and ten days respectively. ...
Modec International Inc has selected Siemens Water Technologies to provide sea-water reverse osmosis (SWRO) systems for several floating, production, storage and offloading (FPSO) vessels that are to be operated in deep-water locations. Siemens is also supplying a wastewater reuse system to one of Brazils largest refineries.
This proceedings CD ROM contains 127 papers on developing and evaluating engineering approaches to wetlands and river restoration. The latest engineering developments are discussed, providing valuable insights to successful approaches for river restoration, wetlands restoration, watershed management, and constructed wetlands for stormwater and wastewatertreatment. Potential solutions to a wide variety of ecosystem concerns in urban, suburban, and coastal environments are presented.
This report reviews coal conversion processes which may be introduced in Canada within the next decade if interest in alternate energy technologies continues. A detailed review was conducted on coal liquefaction and gasification projects worldwide including information on individual proprietors, process technologies used, their present status and available environmental data. Further assessment of emissions and wastes emanating from commercial-scale plants was used to determine significant or potentially significant wastestreams connected to the various technologies, particularly wastewater discharges. Emphasis was placed on those technologies that are close to commercialization in Canada, i.e. SASOL II-type liquefaction facility at Hat Creek. Available information on wastewatertreatment/reuse is also included in this report.
Abstract In this research, the efficiency of electrocoagulation treatment process using aluminum electrodes to treat synthetic wastewater containing Reactive Red198 (RR198) was studied. The effects of parameters such as voltage, time of reaction, electrode connection mode, initial dye concentration, electrolyte concentration, and inter electrode distance on dye removal efficiency were investigated. In addition, electrical energy consumption, electrode consumption, and operating cost at optimum condition have been investigated. The results showed that dye and chemical oxygen demand removals were 98.6 and 84%, respectively. Electrode consumption, energy consumption and operating cost were 0.052-kg/m3, 1.303-kWh/m3 and 0.256-US$/m3, respectively. Dye removal kinetic followed first order kinet...
This book provides discusses recent developments in oil pollution control instrumentation. Some of the topics covered are as follows: 1. Technical requirements of the IMCO International Performance and Test Specification A393x concerning oil content meters; and 2. Oil in water detection; and 3. Methods for the disposal of recovered oil and oily sludge; and 4. Oil content monitoring at ballast water treatment facilities and offshore production platforms.
A study was made of employee exposure to oil sludge and vapors during oil-sludge removal and maintenance activities at the Alyeska Pipeline Service Company's Ballast Water Treatment Facility, Valdez, Alaska. Total hydrocarbons, except benzene, toluene, and xylene, showed concentrations from 371 to 1228mg/m3. Of eight maintenance workers, five reported headache, dizziness, or nausea when working without a respirator. The authors conclude that workers were potentially exposed to benzene vapors and total hydrocarbon vapors exceeding the evaluation criteria for these substances. The authors recommend the use of respiratory protection measures to reduce exposures during work operations.
The technology developed here will exploit the ability of microorganisms to remove dissolved metals from aqueous solutions. Microbial sorbents for uranium will be immobilized biosorbents will be deployed ex situ within flow-through reactors for the continuous or semicontinuous treatment of recovered wastewaters. The proposed technology will primarily be applied within a pump-and-treat process using immobilized biosorbents for the large-scale, long-term remediation of uranium-laden surface water or groundwater impoundments (environmental restoration). The technology may be equally useful as an ``end-of-pipe`` treatment of process effluents (waste management). Successful operation of this process will achieve immobilization of the targeted waste and accompanying volume reduction.
The importance of indigenous soil Mn level on plant Mn uptake from metal salt or sewage sludge amended soils was investigated. Twelve soil materials, six surface and six subsurface, were amended with either varying rates of a composite of Cd, Cu, Ni, and Zn sulfate salts, equivalent to the total of these metals present in a digested sewage sludge (Washington, DC) at rates of 0 to 896 dry metric tons/ha or with the sludge itself, at 224 dry metric tons/ha. Corn (Zea mays L.) was grown in the greenhouse for 30 days, 1 year after amendment application. Two pH levels of about 5.5 and 6.5 were maintained during the experiment on the metal salt amended soil materials. Plant tissue Mn levels increased with the application of Cd, Cu, Ni, and Zn (in combination) as metal salts or as sewage sludge over the range of soil materials used. The amount of increase with a given increase in applied metals was greater for ...
This report estimates the economic and financial effects and the benefits of compliance with the proposed effluent limitations guidelines and standards for the Centralized Waste Treatment (CWT) industry. The Environmental Protection Agency (EPA) has measured these impacts in terms of changes in the profitability of waste treatment operations at CWT facilities, changes in market prices to CWT services, and changes in the quantities of waste management at CWT facilities in six geographic regions. EPA has also examined the impacts on companies owning CWT facilities (including impacts on small entities), on communities in which CWT facilities are located, and on environmental justice. EPA examined the benefits to society of the CWT effluent limitations guidelines and standards by examining cancer and non-cancer health effects of the regulation, recreational benefits, and cost savings to publicly owned treatment works (POTWs) to ...
This document includes the following topics: Background; Data Collection; Scope/Applicability of the Proposed Regulation; Description of the Industry; Industry Subcategorization; Pollutants of Concern for the Centralized Waste Treatment Industry; Pollutants Selected for Regulation; WastewaterTreatment Technologies; Regulatory Options Considered and Selected for Basis of Regulation; Long-Term Averages, Variability Factors, and Limitations and Standards; Cost of Treatment Technologies; Pollutant Loading and Removal Estimates; Non-Water Quality Impacts; Implementation; Analytical Methods and Baseline Values; List of Definitions; List of Acronyms; Appendix A--Pollutant Groups; Appendix B--Listing of Characerization Data From Non-Hazardous Oils Facilities; Appendix C--Listing of Daily Influent and Effluent Measuements; Appendix D--Facility-Specific Compliance Costs; Appendix E--Attachements to Chapter 10; ...
Applications using microwave energy in the chemical processing industry have increased within the last ten years. Recently, interest in waste treatment applications process development, especially solidification, has grown. Microwave waste processing offers many advantages over conventional waste treatment technologies. These advantages include a high density, leach resistant, robust waste form, volume and toxicity reduction, favorable economics, in-container treatment, good public acceptance, isolated equipment, and instantaneous energy control. The results from the {open_quotes}cold{close_quotes} demonstration scale testing at the Rocky Flats nuclear weapons facility are described. Preliminary results for a transuranic (TRU) precipitation sludge indicate that volume reductions of over 80% are achievable over the current immobilization process. An economic evaluation performed demonstrated cost savings ...
From 1991 to 1996, key studies on the reutilization, treatment, and disposal technology of hazardous wastes have been incorporated into the national plan for environmental protection science and technology. At present, the research achievements have been accomplished, have passed national approval, and have been accepted. The author of this paper, as leader of the national group for this research work, expounds the newest achievements of the studies involving four parts: (1) the reutilization technology of electroplating sludge, including the ion-exchange process for recovering the sludge and waste liquor for producing chromium tanning agent and extracting chromium and colloidal protein from tanning waste residue; on the recovery of heavy metals from the electroplating waste liquor with microbic purification; on the demonstration project of producing modified plastics from the sludge and the waste ...
The complexity and diversity of the microbial communities in biogranules from an upflow anaerobic sludge blanket (UASB) bioreactor were determined in response to short-term changes in substrate feeds. The reactor was fed simulated brewery wastewater (SBWW) (70% ethanol, 15% acetate, 15% propionate) for 1.5 months (phase 1), acetate / sulfate for 2 months (phase 2), acetate-alone for 3 months (phase 3), and then a return to SBWW for 2 months (phase 4). Performance of the reactor remained relatively stable throughout the experiment as shown by COD removal and gas production. 16S rDNA, methanogen-associated mcrA and sulfate reducer-associated dsrAB genes were PCR amplified, then cloned and sequenced. Sequence analysis of 16S clone libraries showed a relatively simple community composed mainly of the methanogenic Archaea (Methanobacterium and Methanosaeta), members of the Green Non-Sulfur (Chloroflexi) group of Bacteria, followed by fewer numbers ...
Combined sewer overflows (CSOs) have been recognised as one of the serious sources of pollution to the water environment during rain events, although field surveys to investigate the effect of their magnitude and duration on receiving waters have been very limited. The fates of enteric viruses (norovirus G1, G2, enteroviruses) and coliforms were determined in the wastewatertreatment plant on a fine day and on a rainy day. Not all microorganisms were reduced in the primary treatment, but were reduced in the secondary treatment. Occurrences of enteric viruses and levels of coliforms were surveyed in the receiving coastal area after a CSO event, with the profiles of the enteric viruses in the coastal seawater being almost at the same positive ratio for 4 d after the CSO event. PMID:15318519
FuelCell Energy in Connecticut has sold 4.5 MW worth of power plants to California renewable energy company BioFuels Fuel Cells, part of New Energy Capital and BioFuels Energy. Three molten carbonate fuel cell power plants - a 2.8 MW DFC3000 unit, a 1.4 MW DFC1500 system, and a 300 kW DFC300 unit - will be installed at three locations in the San Diego area, and utilize purified biogas from the Point Loma wastewatertreatment plant as their primary fuel source.
A measurement of environmental radioactivity in Tokyo was started from 1974. We have been executing fixed time and fixed point observation since 1983 in Tokyo continuously. Measurement item is rain water, airborne dust, activated sludge at sewage treatment plants and external dose rate. Measurement data from 1983 to 1995 is reported in this paper. Moreover, we have been carried out the measurement of radon concentration in air from 1988 to 1991 in different types of residental buildings. The measurement results of rain water, airborne dust, external dose rate were approximately a background level respectively except for the Chernobyl nuclear power plant accident. Radionuclides used as radiopharmaceuticals were detected in the activated sludge at every sewage treatment plant but its concentration was lower than concentration limit in Japan. From a result of radon concentration measurements, there were no ...
The VerTech Pit Method for wet oxidation of municipal sewage sludge offers an ecologically and economically advantageous alternative for dealing with sewage and special sludges. Europe`s first commercial plant has now been commissioned in Apeldoorn in the Netherlands following industrial-scale trials in the USA. Up to its present stage of operation the plant has achieved a high degree of reduction of solid residues and a favourable resource and environmental profile, thus impressively confirming earlier results. It is amply in keeping with the landfill criteria laid down in the Household Waste Technical Code. Furthermore, the potential sludge throughput has been found to exceed the projected value. [Deutsch] Mit dem VerTech-Tiefschachtverfahren zur Nassoxidation kommunaler Klaerschlaemme steht ein alternatives Verfahren zur Behandlung von Klaer- und Sonderschlaemmen zur Verfuegung, das oekologische und wirtschaftliche ...
The purpose of this document is to use existing documentation to review the effectiveness of subsurface flow and surface flow constructed wetlands in treating wastewater and to demonstrate the viability of treating effluent from Savannah River Site outfalls H-02 and H-04 with a subsurface flow constructed wetland to lower copper, lead and zinc concentrations to within National Pollutant Discharge Elimination System (NPDES) Permit limits. Constructed treatment wetlands are engineered systems that have been designed and constructed to use the natural functions of wetlands for wastewatertreatment. Constructed wetlands have significantly lower total lifetime costs and often lower capital costs than conventional treatment systems. The two main types of constructed wetlands are surface flow and subsurface flow. In surface flow constructed wetlands, water flows above ground. Subsurface ...
Constructed wetlands may be used for removal of high nutrient loads in greenhouse wastewater prior to discharge into the environment. Temperature affects both the physical and biological activities in wetland systems. Since nitrification and denitrification are temperature-dependent processes, effluent nitrate concentrations will fluctuate due to changes in air and wetland temperature. In a cold climate, constructed wetlands can function in a temperature-controlled, greenhouse environment year-round. This work evaluates four temperature treatments on nitrate removal rates in five planted and five unplanted laboratory-scale wetlands. Wetlands were supplied with a nutrient solution similar to the fertigation runoff solution (100 PPM nitrate-N) used in greenhouse crop production. A first-order kinetic model was used to describe experimental nitrate depletion data and to predict nitrate removal rate constants (k) in the wetlands planted with Iris ...
A method of using fungi in removing heavy metal from wastewater was discussed. Fungi for this purpose can be obtained inexpensively, and on a constant basis from industrial fermentation processes. The biosorption of lead, cadmium and nickel on fungal stock cultures, was investigated. In these experiments, the fungal stock used was Aspergillus niger and Rhizopus stolonfier. Alkali pre-treatment of the fungal biomass improved the metal biosorptive capacity in comparison to live cells. The effect of alkali treatment, however, varied,showing highest biosorptive capacity for lead and least for nickel. Results showed that metal biosorption of metallic ions increased with an increase in pH from 3.2 to 4.0. Equilibrium times of five hours were observed for the biosorption of lead and cadmium, while the equilibrium time for nickel was three hours. 10 refs., 3 tabs., 7 figs.
Biogas, produced from anaerobic digestion of organic matter in domestic, industrial and rural wastewaters and residuals, represent an alternative and renewable source of energy, with growing use worldwide. In Brazil, high population and its spatial concentration and expressive agricultural and agricultural-industrial production indicate a substantial potential of biogas production. The results presented in this work show a potential of biogas production of almost 2 billion cubic feet a day of CH{sub 4}. Viability of biogas production and use depends substantially on project scale. Generally, biogas projects are viable from landfills and domestic wastewatertreatment for populations higher than 50,000 inhabitants and swine and dairy farms with at least 5,000 and 1,000 animals, respectively. Biogas is also competitive when compared to fossil fuels used in industry and transport. Despite incentive mechanisms for biogas ...
This report summarizes the major activities conducted in the Chemical and Energy Research Section of the Chemical Technology Division at Oak Ridge National Laboratory (ORNL) during the period October--December 1997. The section conducts basic and applied research and development in chemical engineering, applied chemistry, and bioprocessing, with an emphasis on energy-driven technologies and advanced chemical separations for nuclear and waste applications. The report describes the various tasks performed within six major areas of research: Hot Cell Operations, Process Chemistry and Thermodynamics, Separations and Materials Synthesis, Fluid Structure and Properties, Biotechnology Research, and Molecular Studies. The name of a technical contact is included with each task described, and readers are encouraged to contact these individuals if they need additional information. Activities conducted within the area of Hot Cell Operations included efforts to optimize the processing conditions ...
Most waste water treatment plants have processes to remove nutrients in order to avoid eutrophication in water receiving bodies. Regarding phosphorus removal. the most common option is chemical precipitation with ferric or aluminical precipitation with ferric or aluminium salts. We show here the successful experience carried out by the WWTP of Blanes and the company Safloc. A method ato remove phosphorus from waste water was developed by adding sodium aluminate. The use of this compound has turned out to be a sustainable way for this purpose in terms of costs, reliability and minimization of sludge production. (Author)
For the treatment of dam waste water containing micro quantities of uranium, the so-called chemical precipitation method is conventionally used, that is, acidic sodium phosphate is added to it and so the uranium (UO_2"2"+) is removed in coprecipitation with the then occurring calcium phosphate (solid). The method, however, has several problems, such as the large space required and large quantities of sludge. For the pupose of eliminating such difficulties and removal and recovery of the uranium, development of the new uranium adsorption method was started. Of the many uranium adsorbents available, excellent ones were selected and then the continuous treatment test was made with small apparatus. Subsequently, the dam waste water uranium recovery facility was completed in 1983. (Mori, K.).
The Department of Energy selected caustic-side solvent extraction (CSSX) as the preferred cesium-removal technology for SRS high-level waste. In the pretreatment step of the CSSX flowsheet, the incoming salt solution, which contains entrained sludge, is contacted with MST to adsorb strontium and selected actinides. An alternative approach replaces MST with the addition of sodium permanganate, strontium nitrate, and hydrogen peroxide. The pretreatment operation then filters the resulting slurry to remove the sludge and MST or manganese oxide and strontium carbonate solids. The filtrate receives further treatment in the solvent extraction system. SRTC personnel coordinated tests using a SpinTek rotary microfilter at the vendor location in FY01. These tests demonstrated a significant improvement - 2.5 to 6 times increase - in performance relative to the conventional cross-flow filter units. Rotary microfilter testing used a ...
Vertical U-tube steam generators in Pressurized Water Reactors (PWRs) operating an All Volatile Treatment (AVT) secondary chemistry have experienced corrosion problems, particularly denting and sludges. The studies reported evaluate the feasibility of using a low-concentration (0.5 wt%) chemical cleaning process to remove corrosion product deposits from steam generator surfaces and magnetite from tube-to-support plate crevices of PWR steam generators. The process potentially may be applied at schedule intervals, such as during normal refueling outages, to maintain a steam generator in clean operating condition. This report describes the results of testing to evaluate the effectiveness of several chelant acids for dissolving steam generator sludges and crevice magnetite. Corrosion of carbon steel by the chelant acids and the effects of various inhibitors are evaluated. The effectiveness of ion-exchange regeneration of ...
In response to the need for a comprehensive and consistent approach to the complex issue of mixed waste management, a generalized methodology for remediation of a mixed waste site has been developed. The methodology is based on requirements set forth in the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) and the Resource Conservation and Recovery Act (RCRA) and incorporates ``lessons learned`` from process design, remediation methodologies, and remediation projects. The methodology is applied to the treatment of 32,000 drums of mixed waste sludge at the Oak Ridge K-25 Site. Process technology options are developed and evaluated, first with regard to meeting system requirements and then with regard to CERCLA performance criteria. The following process technology options are investigated: (1) no action, (2) separation of hazardous and radioactive species, (3) dewatering, (4) drying, and (5) ...
Results are presented of analysis of the dust content of air and the resources for removing sludge at the mines of the Kuzbass during drilling of ascending shafts. A design is proposed for sludge removing devices with automatic opening and closing of the valve hinges.
This project addresses the problem of flue gas desulfurization (FGD) sludge disposal to land. Specifically, the chemical species of FGD sludge constituents are thermodynamically modeled using the equilibrium constant approach, in an attempt to predict the constituent concentratio...
An examination of chemical and radiological characteristics of RI organic liquid waste, wet oxidation by Fenton reaction and decomposition liquid waste treatment process were studied. These items will be applied to develop the equipment of wet oxidation and decomposition liquid waste treatment mixed processes for the safe treatment of RI organic liquid waste which is consisted of organic solvents such as toluene, alcohol and acetone. Two types of toluene solutions were selected as a candidate decomposition material. As for the first type, the concentration of toluene was above 20 vol percent. As for the second type, the solubility of toluene was considered. The decomposition ration by Fenton reaction was above 95 percent for both of them. From the adsorption equilibrium tests, a -Na{sup +} substituted/acid treated activated carbon and Zeocarbon mixed adsorbent was selected for the fixed adsorption column. This mixed ...
The Specific Methanogenic Activity (SMA) and sludge biodegradability of an anaerobic sludge depends on various operational and environmental conditions imposed to the anaerobic reactor. However, the effects of hydraulic retention time (HRT), influent COD concentration (COD_inf) and sludge retention time (SRT) on those two parameters need to be elucidated. This knowledge about SMA can provide insights about the capacity of the UASB reactors to withstand organic and hydraulic shock loads, whereas the biodegradability gives information necessary for final disposal of the sludge. (Author)
Batch and dynamic flow biosorption studies were carried out using the waste biomass entrapped in silica-gel matrix for the removal of nickel(II) ions from synthetic solutions and real wastewater. Batch biosorption conditions were examined with respect to initial pH, S/L ratio, contact time, and initial nickel ion concentration. Zeta potential measurements showed that immobilized biosorbent was negatively charged in the pH range of 3.0-8.0. The immobilized biomass was found to possess relatively high biosorption capacity (98.01 mg g{sup -1}), and biosorption equilibrium was established in a short time of operation (5 min). The equilibrium data were followed by Langmuir, Freundlich, and Dubinin-Radushkevich isotherm models. Scanning electron microscope analysis was used to screen the changes on the surface structure of the waste biomass after immobilization and nickel(II) biosorption. Sorbent-sorbate interactions were confirmed by Fourier transform infrared ...
The K site near Seoul began landfilling in 1992. The landfilled wastes include municipal solid waste (66.4%), construction residues (20.4%), water and wastewatersludges (trace levels), and hazardous waste (trace levels). The water content of the municipal solid waste is very high (47.3%); as a result, the leachate level (average E.L.) of the landfill, the design value of which is 7.0 m, was measured at 10.3 m in January 1995 and is increasing. The increase of leachate level in the landfill site causes a problem with slope stability. The leachate level at each disposal stage divided by the intermediate cover layer was calculated with the HELP (Hydrologic Evaluation of Landfill Performance) model and calibrated with the data measured from February 1993 to June 1995. Also, the hydraulic conductivities of the waste layer and the intermediate cover layer in each stage were calibrated continuously with HELP model analysis. To verify these results, ...
The methods introduced for the field of cleaning waste water can be classified under various processes. Chemical oxidation is done with ozone, hydrogen peroxide and ultraviolet irradiation with subsequent biological decomposition. Another method is ultra-filtration with recovery of valuable materials or waste water ponds with algae biomass to decompose ammonium compounds, nitrates and phosphates. (EF) [Deutsch] Die auf dem Gebiet der Abwasserreinigung vorgestellten Methoden kann man in verschiedene Verfahren einordnen. Die chemische Oxidation erfolgt mit Ozon, Wasserstoff-Peroxid, UV Bestrahlung und anschliessenden biologischen Abbau. Eine andere Methode ist die Ultrafiltration mit Rueckgewinnung von Wertstoffen oder Abwasserteiche mit Algenbiomasse zum Abbau von Ammoniumverbindungen, Nitraten und Phosphaten. (EF)
Even the presence of very low concentrations of dyes (1mgL-1) in the effluent is highly visible and is considered aesthetically undesirable. It must be removed from wastewater completely. This study systematically evaluates the performance of adsorption (three kinds of powdered activated carbons), coagulation (AlCl36H2O) and membrane (submerged hollow fiber microfiltration) processes individually in treating two kinds of reactive dyes (Orange 16 and Black 5) and then using a hybrid process with combined coagulation-adsorption-membrane treatment system. Adsorption capacity and kinetics of Orange 16 were much higher and faster than those of Black 5. The dye removal efficiency by coagulation was highly dependent on dye concentration and solution pH. The hybrid process performance was far more...
A wet air oxidation (WAO) process was applied to four selected pharmaceuticals (metoprolol, naproxen, amoxicillin, and phenacetin) individually dissolved in ultra-pure water, varying the temperature and oxygen pressure. Due to the moderate (amoxicillin) or low (metoprolol, naproxen, and phenacetin) efficiency found in the oxidation of these pollutants, a catalytic wet air oxidation (CWAO) process was then tested using a platinum catalyst supported on multi-walled carbon nanotubes (CNT). In this CWAO process, the pharmaceuticals were dissolved together in ultra-pure water and in four natural water matrices-a reservoir water, a groundwater, and two waters from different municipal wastewatertreatment plants. On the basis of the measurements of their removals, a discussion is given of the inf...
A novel wastewatertreatment technique has been investigated, for reactive dye removal, in batch kinetic systems. These experimental studies have indicated that charred dolomite has the potential to act as an adsorbent for the removal of Brilliant Red reactive dye from aqueous solution. The effect of initial dye concentration, adsorbent mass:liquid volume ratio, and agitation speed on dye removal have been determined with the experimental data mathematically described using empirical external mass transfer and intra-particle diffusion models. The experimental data show conformity with an adsorption process, with the removal rate heavily dependent on both external mass transfer and intra-particle diffusion. PMID:12691893
The treatment of Be-contaminated wastewater has been paid little attention, although beryllium (Be) and its compounds are of high toxicity. In this research, aerobic granule was for the first time introduced to remove Be from aqueous solution. Influencing factors including reaction time, initial Be concentration, pH, biosorbent dosage, and coexistent metal ions (Cd, Cu, and Fe) were investigated in batch experiments. The aerobic granule, characterized by element analysis and CLSM, was abundant in carboxyl, phosphoryl, amine and hydroxyl groups. Potentiometric titration experiment demonstrated that the pH effect on biosorption depended on the surface charge of granule (pHzpc=2.4) and the species of Be (Be^2^+, Be(OH)^+, and Be(OH)2) in solution. The coexistent metal ions would either inhibi...
This sampling and analysis plan (SAP) identifies characterization objectives pertaining to sample collection, laboratory analytical evaluation, and reporting requirements for vapor samples obtained during the operation of mixer pumps in tank 241-AZ-101. The primary purpose of the mixer pump test (MPT) is to demonstrate that the two 300 horsepower mixer pumps installed in tank 241-AZ-101 can mobilize the settled sludge so that it can be retrieved for treatment and vitrification. Sampling will be performed in accordance with Tank 241-AZ-101 Mixer Pump Test Data Quality Objective (Banning 1999) and Data Quality Objectives for Regulatory Requirements for Hazardous and Radioactive Air Emissions Sampling and Analysis (Mulkey 1999). The sampling will verify if current air emission estimates used in the permit application are correct and provide information for future air permit applications.
Accumulation of Chloride and Cupric ions under the sludge on the steam generator tubing surface in the area between tube sheet and the first tube support is known to be the main reason for the pitting corrosion. In addition to those ions, oxygen, pH, temperature, heat treatment history, contests of minor elements such as C, S or Ti in the alloy are also influencing the material's the pitting corrosion resistance. a series of autoclave pitting test was conducted to evaluate the pitting corrosion characteristics of the domestically produced alloy 690 tubing material and compare with that of INCO manufactured material. 16 refs., 44 figs., 5 tabs. (Author)
Coal bed natural gas (CBNG) development in the Powder River (PR) Basin produces modestly saline, highly sodic wastewater. This study assessed impacts of wetting four textural groups (0-11%, 12-22%, 23 -33%, and > 33% clay (g clay/100 g soil) x 100%))with simulated PR or CBNG water on water retention. Soils received the following treatments with each water quality: a single wetting event, five wetting and drying events, or five wetting and drying events followed by leaching with salt-free water. Treated samples were then resaturated with the final treatment water and equilibrated to -10, -33, -100, -500, or -1,500 kPa. At all potentials, soil water retention increased significantly with increasing clay content. Drought-prone soils lost water-holding capacity between saturation and field capacity with repeated wetting and drying, whereas finer textured soils withstood this treatment better and had ...
The coke plant at the Sparrows Point Plant consist of three coke oven batteries and two coal chemical plants. The by-product coke oven gas (COG) consists primarily of hydrogen, methane, carbon monoxide, nitrogen and contaminants consisting of tars, light oils (benzene, toluene, and xylene) hydrogen sulfide, ammonia, water vapor and other hydrocarbons. This raw coke oven gas needs to be cleaned of most of its contaminants before it can be used as a fuel at other operations at the Sparrows Point Plant. In response to environmental concerns, BSC decided to replace much of the existing coke oven gas treatment facilities in the two coal chemical Plants (A and B) with a group of technologies consisting of: Secondary Cooling of the Coke oven Gas; Hydrogen Sulfide Removal; Ammonia Removal; Deacification of Acid Gases Removed; Ammonia Distillation and Destruction; and, Sulfur Recovery. This combination of technologies will replace the existing ammonia removal system, the ...
The coke plant at the Sparrows Point Plant consist of three coke oven batteries and two coal chemical plants. The by-product coke oven gas (COG) consists primarily of hydrogen, methane, carbon monoxide, nitrogen and contaminants consisting of tars, light oils (benzene, toluene, and xylene) hydrogen sulfide, ammonia, water vapor and other hydrocarbons. This raw coke oven gas needs to be cleaned of most of its contaminants before it can be used as a fuel at other operations at the Sparrows Point Plant. In response to environmental concerns, BSC decided to replace much of the existing coke oven gas treatment facilities in the two coal chemical Plants (A and B) with a group of technologies consisting of: Secondary Cooling of the Coke oven Gas; Hydrogen Sulfide Removal; Ammonia Removal; Deacification of Acid Gases Removed; Ammonia Distillation and Destruction; and, Sulfur Recovery. This combination of technologies will replace the existing ammonia removal system, the ...
The high-purity-oxygen activated sludge process will be used to expand secondary treatment capacity and improve water quality in Santa Monica Bay. The facility is operated by the city of Los Angeles Department of Public Works` Bureau of Sanitation. The overall Hyperion Full Secondary Project is 30% complete, including a new headworks, a new primary clarifier battery, an electrical switch yard, and additional support facilities. The upgrading of secondary facilities is 50% complete, and construction of the digester facilities, the waste-activated sludge thickening facility, and the second phase of the three-phase modification to existing primary clarifier batteries has just begun. The expansion program will provide a maximum monthly design capacity of 19,723 L/s(450 mgd). Hyperion`s expansion program uses industrial treatment techniques rarely attempted in a municipal facility, particularly on such a ...
The potential to scrub biogas in a high rate pond (HRP) was evaluated using apparatus designed to maximize gas-liquid contact. Experiments compared the removal of carbon dioxide from synthetic biogas by an 'in-pond angled gutter' to that by a simulated 'counter-current pit'. Results showed that the counter current pit has potential for use in biogas scrubbing, with synthetic biogas carbon dioxide composition consistently reduced from 40% to<5%. The in-pond angled gutter was less effective due to bubble coalescence which reduced the total bubble surface surface area available for gas transfer. Measurement of oxygen levels in the scrubbed biogas showed that despite supersaturation of oxygen in the HRP water, there was little transfer to the biogas, so that explosive methane/oxygen mixtures would not be formed. Theoretical calculations indicated that the amount of biogas likely to be formed during anaerobic treatment of ...
Atomic Energy of Canada Limited (AECL) operates the Waste Treatment Centre (WTC) to treat and immobilize some of the low- level radioactive waste (LLRW) streams at the Chalk River Laboratories (CRL). The WTC at treats low- level radioactive liquid waste by removing the contaminants from the wastewater, concentrating them, and immobilizing them. The fundamental design concept for the WTC is to process the waste streams using forced circulation type liquid waste evaporation (LWE), to solidify the concentrates using thin film evaporator and to discharge the purified effluent into the Ottawa River following verification monitoring. The solidified product drums are stored in existing storage facilities in the CRL. The LWE was installed in the WTC to treat the LLRW. After about four (4) years of design, construction and cold commissioning, the active commissioning of the evaporator process using radioactive waste streams commenced in February 2000. ...
Atomic Energy of Canada Limited (AECL) operates the Waste Treatment Centre (WTC) to treat and immobilize some of the low- level radioactive waste (LLRW) streams at the Chalk River Laboratories (CRL). The WTC at treats low- level radioactive liquid waste by removing the contaminants from the wastewater, concentrating them, and immobilizing them. The fundamental design concept for the WTC is to process the waste streams using forced circulation type liquid waste evaporation (LWE), to solidify the concentrates using thin film evaporator and to discharge the purified effluent into the Ottawa River following verification monitoring. The solidified product drums are stored in existing storage facilities in the CRL. The LWE was installed in the WTC to treat the LLRW. After about four (4) years of design, construction and cold commissioning, the active commissioning of the evaporator process using radioactive waste streams commenced in February 2000. ...
In the first part of the symposium, experts reviewed the state of the art of decentralized waste water treatment in Europe. In the second part, exemplary solutions in Poland and the Czech Republic were presented. The final part was dedicated to future concepts and strategies. [German] Im Herbst letzten Jahres hat die Kommunale Umwelt-AktioN U.A.N. in einer Abfolge von drei Abwasserfachsymposien Expertenrunden zum Austausch ueber den aktuellen Stand des Wissens zum Thema dezentrale Abwasserbehandlung veranstaltet. Mit dem Internationalen Symposium 'Konzepte zur Abwasserbehandlung im laendlichen Raum Europas' in Celle hat das Projekt der U.A.N. seinen Abschluss gefunden. Der Konzeption des Projektes entsprechend haben im 1. Teil des Symposiums Experten ueber den Stand der Entwicklung auf dem Sektor der dezentralen Abwasserbehandlung in Deutschland berichtet. Im 2. Teil unserer Fachtagung wurden europaeische Beispiele fuer dezentrale Loesungen aus ...
Industrial segments as plant of mining, hospitals and university generate considerable volumes of radioactive wastewater containing uranium. The increasing development of the use of the nuclear energy to lead away to an expansion of the sectors of the nuclear fuel cycle, but it leads to security problems and it appears the necessity of control of the removing of uranium and radioactive effluent treatments. Researches evaluate if the technique of the biosorption would promote an alternative process with attractive characteristics of cost-benefit. The residual biomass from agricultural activities has been studied and used as adsorbent of metals and organic composts by low cost, abundance and for being biodegradable. In this work, it is presented the efficiency of the coir pith for the adsorption of ions UO_2"2"+. The coir pith is a by-product of the harvest of the coconut, a renewable natural source. The study was accomplished using the batch ...
Molten salt oxidation (MSO) is a good alternative to incineration for the treatment of a variety of organic wastes such as explosives, low-level mixed waste streams, PCB contaminated oils, spent resins and carbon. Since mid-1990s, the U.S. Army Defense Ammunition Center (DAC) and the Department of Energy (DOE) have jointly invested in MSO development at the Lawrence Livermore National Laboratory (LLNL). LLNL first demonstrated the MSO process for the effective destruction of explosives, explosives-contaminated materials, and other wastes on a 1.5-kg/hr bench-scale unit, and then in an integrated MSO facility capable of treating 8 kg/hr of low-level radioactive mixed wastes. Several MSO systems have been built with sizes up to 10 ft in height and 16 inches in diameter. LLNL in 2001 completed a MSO plant for DAC for the destruction of explosives-contaminated sludge and explosives-contaminated carbon. We will present in this paper our latest ...
Decomposition of organic compounds contained in the spent ion exchange resins is considered effective in reducing the waste volume. A system using the wet-oxidation process has been studied for the treatment of the spent resins stored at Trino Nuclear Power Plant owned by SOGIN. Compared with various processes for treating sludge and resin, the wet-oxidation system is rather simple and the process conditions are mild. Not contaminated ion exchange resin samples similar to those ones used in Trino NPP were processed by wet-oxidation and appropriate decomposition of the organic compounds was verified. After decomposition the residue can be solidified with cement for final disposal. When compared with direct solidification without decomposition, the number of waste packages can be significantly reduced. Additional measures for conditioning secondary waste products have also been studied, and their applicability to the Trino Nuclear Power Plant was ...
The energy recovery by anaerobic purification of wastewaters from olive oil manufactured is reported. The process efficiency is 82%, and the gas (CH4-CO2) yield is 850 L/kg eliminated BOD.
Thermophilic propionate-oxidizing, proton-reducing bacteria were enriched from the granular methanogenic sludge of a bench-scale upflow anaerobic sludge bed reactor operated at 55°C with a mixture...Full Text Available
The industrial application of anaerobic digestion is a relatively new, yet proven waste treatment technology. Anaerobic digestion reduces and upgrades organic waste, and is a good way to control air pollution as it reduces methane and nitrous gas emissions. For environmental and energy considerations, anaerobic digestion is a nearly perfect waste treatment process. However, its economic viability is still in question. A number of parameters - type of waste (solid or liquid), digester system, facility size, product quality and end use, environmental requirements, cost of alternative treatments (including labor), and interest rates - define the investment and operating costs of an anaerobic digestion facility. Therefore, identical facilities that treat the same amount and type of waste may, depending on location, legislation, and end product characteristics, reveal radically different costs. A good approach for evaluating the ...
The kinetics of calcium sulfate crystal growth is of importance in various fields, such as geochemistry, desalination technology, petroleum industry, and water and wastewatertreatment. The seeded crystal growth rate of calcium sulfate dihydrate was measured as a function of supersaturation in NaCl electrolyte solutions from 0 to 6 m at temperatures of 25, 50, 70, and 90 C. The growth followed a second-order parabolic rate law with activation energies greater than 53 kJ/mol which suggested the surface reaction as the rate-limiting step. It was observed that the rate constant and the activation energy are solution composition dependent. The rate constant increases with NaCl concentration up to 3 molal and then begins to fall slightly. The activation energy dropped from 61 kJ/mol in the pure Ca-SO[sub 4]H[sub 2]O system to 53 kJ/mol in 3.0 m NaCl solutions. The electrolyte effect was similar to the crystal solubility behavior in aqueous ...
In May 1985, a National Pollutant Discharge Elimination System permit was issued for the Oak Ridge Y-12 Plant, a nuclear weapons components production facility located in Oak Ridge, Tennessee, and operated by Martin Marietta Energy Systems, Inc., for the US Department of Energy. As a condition of the permit, a Biological Monitoring and Abatement Program (BMAP) was developed to demonstrate that the effluent limitations established for the Oak Ridge Y-12 Plant protect the classified uses of the receiving stream (East Fork Poplar Creek), in particular, the growth and propagation of fish and aquatic life, as designated by the Tennessee Department of Health and Environment. A second purpose for the BMAP is to document the ecological effects resulting from implementation of a water pollution control program that will include construction of nine new wastewatertreatment facilities over the next 4 years. Because of the complex nature of the effluent ...
Phosphorus sorption capacities of several different materials including Merribrook soil (a loamy sand) and some industrial solid wastes (red mud neutralized with gypsum, fly ash, bottom ash and black oxide) were determined in sorption isotherms by Langmuir and Freundlich equations. The materials were characterized by bulk density, particle density, total porosity and particle size distributions. Red mud gypsum possessed the best sorption capacity based on the Langmuir maxima. Alkaline fly ash and Merribrook soil had lower sorption maxima compared to the red mud gypsum. Bottom ash and acidic fly ash had very low sorption capacity at low concentrations. Merribrook soil had the highest hydraulic conductivity. The results suggested that alkaline fly ash may be a promising amendment for coarse sand bed to enhance phosphorus removal. Merribrook soil appears to be suitable for on-site wastewatertreatment.
After the construction of its wastewatertreatment plants, the City of Quebec began to implement overflow control in wet weather to ultimately meet the effluent discharge objectives, i.e. no more than two overflows per summer season in the St. Lawrence River and no more than four in the St-Charles River. After several years of studies to determine which management strategies would best suit the purpose, and to propose optimum solutions, a first project to implement optimal and predictive management in real time, called "Pilot", came to life in 1999. Construction in phases soon followed and the work was completed in the fall of 2009. As a result, requirements with regard to environmental rejects were met in two sectors, namely the St-Charles River and the Jacques-Cartier Beach, and aquatic recreational activities could resume. Meanwhile, the City also worked at giving back access to the water courses to the public by developing sites at the ...
The Process Waste Treatment Plant (PWTP) at the Oak Ridge National Laboratory is designed to remove radioactive contaminants, principally {sup 90}Sr, from process wastewater. Planned upgrades to the PWTP will use chabazite zeolite columns. Pilot-scale studies have shown that mass transfer zone lengths increase from 10 to about 30 cm as the superficial velocity increases from 5.5 to 22 cm/min. Calculations with a multicomponent equilibrium model showed that the distribution coefficient for strontium remains essentially constant over the process conditions, suggesting that a simple kinetic model (the Rosen long-bed solution) should adequately represent breakthrough behavior. Using a distribution coefficient of 4.87 L/g predicted by the equilibrium model, good agreement was found between experimental breakthrough curves and those calculated with the Rosen solution. This model allows prediction of bed depths and cycle times necessary to achieve the ...
The Raywell Process Plants unit, which reclaims a wide range of organic solvents, including chlorinated hydrocarbons, is based on thin film evaporation and distillation rather than steam distillation, thus reducing the risk of contamination by water. Henry Balfour and Co.'s Pfaudler Solvent Recovery System gives 96% or better solvent recovery and produces a near-solid waste suitable for landfill disposal; like the Raywell system, it uses a mechanically wiped thin-film evaporator. Midland Oil Refineries uses sa Raywell thin-film evaporator for recovery of waste lubricating oils rather than the conventional sulfuric acid/clay treatment, thus avoiding formation of sulfuric acid sludge waste. The Henry Balfour Bioenergy anaerobic digestion system gives yields of fuel gas with 65-75% methane as high as 0.8 cu m/kg BOD; it achieves 95-98% BOD removal with no pH control or nutrient addition because it separates solids from liquid effluent and ...
PWR steam generators have suffered from a variety of degradation phenomena. This paper identifies the corrosion-related defects and their probable causes and suggests approaches to correct and prevent corrosive activity. In the attempt to solve the degradation problems, research programs have concentrated on modifying materials, stresses, and the chemical environment in both new and operating steam generators. The following corrosion-related defects have been studied: tube wastage, denting, primary side (ID) intergranular stress corrosion cracking (IGSCC), OD-initiated intergranular attack (IGA), pitting, and corrosion fatigue. Plants affected by wastage have greatly reduced their problem by adopting an all volatile treatment (AVT). In the case of denting, a less aggressive chemical environment is recommended. Primary side IGSCC responds to temperature reduction, stress relief, and material improvements, while flushing and boric acid addition minimizes OD-initiated ...
PWR steam generators have suffered from a variety of degradation phenomena. This paper identifies the corrosion-related defects and their probable causes and suggests approaches to correct and prevent corrosive activity. In the attempt to solve the degradation problems, research programs have concentrated on modifying materials, stresses, and the chemical environment in both new and operating steam generators. The following corrosion-related defects have been studied: tube wastage, denting, primary side (ID) intergranular stress corrosion cracking (IGSCC), OD-initiated intergranular attack (IGA), pitting, and corrosion fatigue. Plants affected by wastage have greatly reduced their problem by adopting an all volatile treatment (AVT). In the case of denting, a less aggressive chemical environment is recommended. Primary side IGSCC responds to temperature reduction, stress relief, and material improvements, while flushing and boric acid addition minimizes OD-initiated ...
A programme has been initiated by the Coordinating Office for Monitoring of enhanced natural radioactivity of the Federal Office for Radiation Protection to investigate different kinds of sample materials with enhanced naturally occurring radioactivity (NORM) such as scales from oilfield and naturally gasfield pipes, blast furnace sludge and sinter dust from the production of pig iron, as well as bauxit and red mud from the production of aluminium oxide. The aim of these investigations is to find proper preparation and measuring methods which allow, in particular, a sample treatment with optimised effort combined with a reliable determination of the specific activities of the dominating radionuclides. Of particular interest is the method of gamma-ray spectrometry, since this method has been used for most of our studies of sample materials. Due to different compositions of calibration and NORM-samples, e.g. different densities, and the analysis ...
Except nuclear industry, diverse structures (hospitals, of research or manufacturers) can have appeal to the use of radioisotopes conditioned under unsealed shape. Such practices lead to tolerate releases in environment in the respect of a statutory device. So the collective network can contain radioisotopes the future of which is going to depend partially on the cleaning applied to waste water. This study through the analysis of a concrete case, has for objective to inform about the future of gamma radioelements present in waste water treated by a wastewatertreatment plant. The contamination of the network is essentially due to Tc{sup 99} and I{sup 131}, radioelements present whatever the working day and the hour considered. The total estimated in-load for a day is important, of the order of 4000 MBq for Tc{sup 99} and 15 to 300 MBq for I{sup 131}. The assessment of cleaning of the station shows that this one plays a role towards this ...
The biodegradation of one of the most commonly used commercially available dispersants in the treatment of hydrocarbon out-flow was studied. The culture mediums employed were sea water, sterile sea water, and medium M19 (Merck). The latter two were inoculated with two kinds of microorganisms of the Pseudomona genus isolated from sludge from a waste treatment plant. The dispersants used is a commercial product made of anionic sulphated dispersants (1.710% by weight); anionic sulphonated dispersants (0.144%) and non-ionic dispersants (8.146%), both accompained by hidrocarbonated solvent (90%). The degradation processes occurred at differents temperatures (20, 30 and 37). The greatest degradation was obtained at 30 degree centigree. The degradation percentages obtained with the miscroorganisms were 40% of the anionic total and 70% of the non-ionic total after 56 hours for the 5:2 strain and 40% of the anionic total and 9.3% of ...
Recent molecular characterizations of Cryptosporidium parasites make it possible to differentiate the human-pathogenic Cryptosporidium parasites from those that do...Full Text Available
Limited field trial results of a heating oil additive package developed to minimize unscheduled maintenance indicate that it achieves its goal of keeping heating oil systems cleaner. The multifunctional additive package was developed to provide improved fuel oxidation stability, improved corrosion protection, and dispersency. This combination of performance benefits was chosen because we believed it would retard the formation of sludge, as well as allow sludge already present to be carried through the system without fouling the fuel system components (dispersency should keep sludge particles small so they pass through the filtering system). Since many unscheduled maintenance calls are linked to fouling of the fuel filtering system, the overall goal of this technology is to reduce these maintenance calls. Photographic evidence shows that the additive package not only reduces the amount of sludge formed, ...
The US Department of Energy (DOE) has millions of gallons of high level nuclear waste stored in underground tanks at Hanford, Washington and Savannah River, South Carolina. These tanks will eventually be emptied and decommissioned. This will leave a residue of sludge adhering to the interior tank surfaces that may contaminate nearby groundwaters with radionuclides and RCRA metals. Performance assessment (PA) calculations must be carried out prior to closing the tanks. This requires developing radionuclide release models from the sludges so that the PA calculations can be based on credible source terms. These efforts continued to be hindered by uncertainties regarding the actual nature of the tank contents and the distribution of radionuclides among the various phases. In particular, it is of vital importance to know what radionuclides are associated with solid sludge components. Experimentation on actual tank ...
PUREX high-level waste (HLW) is contained at the West Valley Demonstration Project (WVDP) in an underground carbon-steel storage tank. The HLW consists of a precipitated sludge and an alkaline supernate. This report describes the system that the WVDP has developed and implemented to resuspend and wash the HLW sludge from the tank. The report discusses Sludge Mobilization and Wash System (SMWS) equipment design, installation, and testing. The storage tank required modifications to accommodate the SMWS. These modifications are discussed as well.
The US Department of Energy (DOE) has millions of gallons of high level nuclear waste stored in underground tanks at Hanford, Washington and Savannah River, South Carolina. These tanks will eventually be emptied and decommissioned. This will leave a residue of sludge adhering to the interior tank surfaces that may contaminate groundwaters with radionuclides and RCRA metals. Experimentation on such sludges is both dangerous and prohibitively expensive so there is a great advantage to developing artificial sludges. The US DOE Environmental Management Science Program (EMSP) has funded a program to investigate the feasibility of developing such materials. The following text reports on the success of this program, and suggests that much of the radioisotope inventory left in a tank will not move out into the surrounding environment. Ultimately, such studies may play a significant role in developing safe and cost effective tank ...
Hexavalent Cr has been identified as one of the toxic metals commonly present in industrial effluents. Among the treatment techniques developed for removing Cr(VI) from waste waters, sorption is most commonly applied, due to its simplicity and efficiency. However, few adsorbents can be recycled and reused cost-effectively. In this study, the removal and recovery of Cr(VI) from water using Li/Al LDH was investigated. The removal of Cr(VI) by Li/Al LDH was evaluated in a batch mode. The results demonstrated that Cr(VI) adsorption onto Li/Al LDH occurs by replacing the Cl{sup -} that originally exists in the interlayer of the adsorbent. The degree of Cr(VI) adsorption observed for Li/Al LDH was relatively high and the process occurred rapidly; however, a portion of adsorbed Cr(VI) was gradually desorbed, due to the Li de-intercalation of Li/Al LDH. Lithium de-intercalation from Li/Al LDH with interlayer Cl{sup -} and interlayer Cr(VI) follows the first order kinetics ...
We wanted to determine the technical and clinical efficacy of using a PTFE-covered self-expandable nitinol stent for the palliative treatment of malignant biliary obstruction. Thirty-seven patients with common bile duct strictures caused by malignant disease were treated by placing a total of 37 nitinol PTFE stents. These stents were covered with PTFE with the exception of the last 5 mm at each end; the stent had an unconstrained diameter of 10 mm and a total length of 50 80 mm. The patient survival rate and stent patency rate were calculated by performing Kaplan-Meier survival analysis. The bilirubin, serum amylase and lipase levels before and after stent placement were measured and then compared using a Wilcoxon signed-rank test. The average follow-up duration was 27.9 weeks (range: 2 81 weeks). Placement was successful in all cases. Seventy-six percent of the patients (28/37) experienced adequate palliative drainage for the remainder of their lives. There were ...
Untreated landfill leachates and wastes from metal plating and mining operations are sources of environmental contamination by heavy metals. Because of their toxicity and potential for accumulation, the discharge of heavy metals must be controlled. Standard physical and chemical treatments used to remove metals from wastes such as concentration by electro-precipitation, ion exchange, solvent extraction, evaporative recovery, and conventional precipitation, are usually expensive and produce high quantities of sludge. Biosorption is the removal of metals from aqueous solutions by microorganisms. It is called biosorption rather than bioadsorption or bioaccumulation because the mechanisms of removal are not restricted to adsorption or metabolic uptake and so the more general term is preferable and has come to be accepted. In this thesis the focus is one two microorganisms and two metals. However, the possible combinations of conditions such as pH, ...
We previously showed that very thin filamentous bacteria affiliated with the division green non-sulfur bacteria were abundant in the outermost layer of thermophilic methanogenic sludge granules fed...Full Text Available
The Clean Water Act of 1977 directed EPA to establish standards for use and disposal of sewage sludge (biosolids). The application of biosolids to non-agricultural lands is becoming increasingly important as a method of waste disposal. Ecological endpoints at the population, community, and/or ecosystem level have not previously been emphasized in the development of regulatory standards for municipal sewage sludge. This risk assessment focuses on terrestrial endpoints in four ecosystem types to which substantial quantities of sludge have been applied or are expected to be applied in the future: northwest Douglas-fir forest, southeastern loblolly pine plantation, eastern deciduous forest, and semi-arid rangeland. Conceptual models suitable for all ecosystems were developed that depict the links among assessment endpoints. Estimates of risks to wildlife from contaminants and simulations of impacts of nitrogen in sewage ...
Bio gasification, i. e. anaerobic digestion, is a well known sustainable option for the management of organic solid wastes and sludges. the produced biogas is a valuable bio fuel to replace fossil fuels in different technical applications (like heating, electricity, transport fuel generation) which in turn determine its quality requirements. (Author)
Glass produced during the Purex 4 campaigns of the Integrated DWPF Melter System (IDMS) and the 774 Research Melter contained a lower fraction of sludge components than targeted by the Product Composition Control System (PCCS). Purex 4 glass was more durable than the benchmark (EA) glass, but was less durable than most other simulated SRS high-level waste glasses. Further, the measured durability of Purex 4 glass was not as well correlated with the durability predicted from the DWPF process control algorithm, probably because the algorithm was developed to predict the durability of SRS high-level waste glasses with higher sludge content than Purex 4. A melter run, designated Purex 4 Remediation, was performed using the 774 Research Melter to determine if the initial PCCS target composition determined for Purex 4 would produce acceptable glass whose durability could be accurately modeled by the DWPF glass durability algorithm. Reagent grade ...
A solution based on sludge and Olive oil mill effluent (OME) co-digestion, coupled with a management plan, has been implemented, to treat and dispose safely, the mixed residues, into the natural forest and agricultural land. The mixture of up to 25% OME to the sludge improved anaerobic degradation of phenols and fats. High density fat compounds, present in OME, enhanced aggregation, settling and acetoclastic activity of anaerobic sludge. The full scale unit, obtained by modification of a cold digester, allowed to set-up a low capital cost system. The system produced large quantity of biogas and electric energy. Anaerobic degradation of the mixture improved fertilizing properties, making feasible land application of the digested mixture. Regional plan based in Geographical Information System (GIS) selected 800 ha of adequate land area for application near the WWTP. The experience is technically and economically successful. ...
In the third quarterly report adsorption of heavy metals ions such as Cu(II) and Cr(VI) onto soils drawn from the laboratory-type wetland was shown to be weak. Secondly, it was shown that modified-clays did adsorb Cr(VI) ions strongly at pH 4.5. Further, studies on the pH dependence of the adsorption of {beta}-naphthoic acid, (NA), a well-documented contaminant in many oil and gas well waste waters onto modified-clays were undertaken and it was shown that uptake of NA by modified-clays was of the high affinity type at pH 4.5 and 7.0, but weak at pH 9.0. Adsorption of heavy metal ions, Cu{sup 2+}, and Cr(VI) onto algae, a proposed wetland amendment, was carried out and the results were presented and discussed in the fourth quarterly report. Uptake of NA by the soil component of the laboratory-type wetland was monitored as a function of pH. This quarterly report presents results from studies on the uptake of phenol and {beta}-naphthoic acid by laboratory-type wetlands designed and built ...
Valdez, Alaska achieved worldwide attention with the Exxon Valdez oil spill. This exacerbated an already polarized situation (industry, government, citizens, environmental groups) regarding the Valdez Terminal of the Trans Alaska Pipeline System. Other than spills, the major focus of environmental concern was and remains the Terminal`s Ballast Water Treatment Plant (BWTP) which discharges into Port Valdez. The previous NPDES wastewater discharge permits for this facility have been contentious for almost the entire period of pipeline operation. The draft NPDES permit is scheduled to be proposed for reissuance this year. However, a significant change has been initiated which so far is resulting in cooperation rather than confrontation between the various primary stakeholders. This presentation will explain how this change was initiated, how it is being maintained, and how what is happening could be a model for progress through cooperation. ...
Biosorption of heavy metals by various biological materials has been studied extensively in the last decade due to its potential particularly in wastewatertreatment. The presence of a large number of metals in industrial metal-bearing solutions makes it necessary to investigate their effect on the final metal uptake by individual biosorbent materials. Nonliving biomass of Sargassum, a brown marine alga, is capable of binding more than 10% of its dry weight in toxic cadmium ions. Although ubiquitous iron interferes with Cd uptake, only approximately 4.5% of it is sequestered (biomass dry weight). Biosorption of both metals at pH 4.5 could be described by Langmuir-type isotherms with b, the affinity-related coefficient (Cd: b = 0.015; Fe: b = 0.027). The interference of Fe with Cd uptake, and vice versa, was assessed by deriving three-dimensional equilibrium two-metal sorption isotherm surfaces, smoothed and cut to reveal the inhibition effect ...
This publication compiles five documents on volatile organic compounds (VOCs) in wastewater collection systems. The first is a thesis describing experiments conducted to obtain parameters for determining the significance of biodegradation relative to volatilization as a VOC fate mechanism in sewers. The second is a compilation of three papers from the 1992-94 conferences of the Air & Waste Management Association (AWMA). The papers concern VOC emissions at sewer drop structures and an estimation method for determining VOC emissions from industrial sewers. The third is a compilation of two papers from the AWMA 1992 and 1994 conferences, covering the formation of chloroform from household sources. The fourth is a thesis on post-discharge formation of chloroform in untreated municipal wastewater. The final document is a report detailing the derivation of fate mechanism models in the TOXCHEM model.
After periodic testing of a large-scale spray calciner/ceramic melter vitrification system over a 2-yr period, sufficient corrosion was noted on various parts of the vitrification system to warrant its disassembly and inspection. A majority of the 316 SS sintered metal filters on the spray calciner were damaged by chemical corrosion and/or high temperature oxidation. Inconel-601 portions of the melter lid were attacked by chlorides and sulfates which volatilized from the molten glass. The refractory blocks, making up the walls of the melter, were attacked by the waste glass. This attack was occurring when operating temperatures were >1200/sup 0/C. The melter floor was protected by a sludge layer and showed no corrosion. Corrosion to the Inconel-690 electrodes was minimal, and no corrosion was noted in the offgas treatment system downstream of the sintered metal filters. It is believed that most of the melter corrosion occurred during one ...
Radiation technology offers a very wide scope for utilisation and commercial exploitation in various field. All over the world, this technology is being favourably considered for different applications like radiation sterilisation of medical products, preservation of food by controlling the physiological processes for extending shelf-life and eradication of microbial and insect pests, radiation processing of polymeric materials and treatment of sewage sludge. Bangladesh Atomic Energy Commission has taken radiation processing programmes in a big way right from its inception. This paper describes the studies carried out by various research groups in Bangladesh Atomic Energy Commission mainly using Cobalt-60 gamma radiation. The investigation covers medical sterilisation, food preservation and development and modification of polymeric materials by gamma radiation. Both food preservation and radiation sterilisation of medical products are now being ...
Digested sewage sludge was applied to pastures and tree plantations at 19 to 44 Mg/ha (dry weight) as part of a municipal sludge disposal program. The sludge had low concentrations of heavy metals and traces of /sup 137/Cs and /sup 60/Co. Monitoring of soils, soil solutions, and runoff indicated that N, P, heavy metals, and radionuclides were largely retained in the upper 15cm of the soil. Soil solutions had elevated NO/sub 3//sup /minus// concentrations often >100 mg/L, but no significant increases in groundwater NO/sub 3//sup /minus// were found during the first year. Runoff from active sites had elevated concentrations of NO/sub 3//sup /minus// (20--30 mg/L), soluble P (1 mg/L), BOD/sub 5/ (5--30 mg/L), and fecal coliform (up to 14,000 colonies per 100 ml), not unlike runoff from pastures with cattle. Enrichment of organic N (2 times), available (inorganic) N (5 to 10 times), and Bray-P in the upper soils persisted ...
Separation of the bulk soluble chemical salts from the insoluble metal hydroxides and radionuclides is central to the strategy of disposing Hanford tank waste. Sludge washing and caustic leaching have been selected as the primary methods for processing the 230 million L (61,000,000 gal) of Hanford tank waste. These processes are very similar to those selected for processing waste at the West Valley Site in New York and the Savannah River Site in South Carolina. The purpose of sludge washing is to dissolve and remove the soluble salts in the waste. Leaching of the insoluble solids with caustic will be used to dissolve aluminum hydroxide and chromium hydroxide, and convert insoluble bismuth phosphate to soluble phosphate. The waste will be separated into a high-level solids fraction and a liquid fraction that can be disposed of as low-level waste after cesium removal. The washing and leaching operations involve batchwise mixing, settling, and ...
Understanding the dynamic of soil C is a key to managing soil organic matter to enhance soil fertility and ecosystem functioning and reduce trace gas emission from soils. Our objective was to determine the influence of thermically-dry sewage sludge (TSL) and municipal waste compost and the application management on soil (mixed or on soil surface) applied at sludge (TSL) and municipal waste compost and the application management on soil (mixed or on soil surface) applied at two rates of 30 t ha"-1 and 60 t ha"-1, on CO_2 fluxes, microbial biomass C (MBC) and dehydrogenase activity (DH), during an incubation study. (Author)
The kinetics of biosorption and desorption of lindane by live activated sludge and the fungus R. arrhizus was studies. The results from the use of live activated sludge suggest that besides biosorption, other lindane removal mechanisms acted in parallel. Most probably, biodegradation. A relationship between biodegradation and bisorption-desorption was established. Mass spectroscopy and gas chromatography studies suggested the presence of lindane biodegradation by products. Lindane accumulated by the live activated sludge could be desorbed while being biodegraded at the same time. Values for lindane biokinetic constants were estimated. Biosorption of lindane by live R. arrhizus is a rapid and reversible process with no indication of biodegradation. Values for the lindane biotransformation kinetic coefficients were estimated. (orig.).
Wet-weather flow (WWF), including combined-sewer overflow (CSO, sanitary-sewer overflow, and stormwater (SW), is a significant contributor of microbial contamination to surface water and ground water. By using effective wastewater or SW disinfection, introduction of pathogen con...
Background and AimsPlants from the family Lemnaceae are widely used in ecological engineering projects to purify wastewater and eutrophic water bodies. However, the biology of nutrient...Full Text Available
Olive tree (Olea european L.) cultivation, the major tree crops in Mediterranean countries is being extended to irrigated lands. However, the limited water availability, the severe climatic conditions and the increased need for good water quality for urban and industrial sector uses are leading to the urgent use of less water qualities (brackish water and recycled wastewater) for olive tree irrigation. The aim of this work was to asses the effects of long term irrigation with treated waste water (TWW) on the soil chemical properties, on olive tree growth and on oil quality characteristics. (Author)
N-substituted aromatics are important priority pollutants entering the environment primarily through anthropogenic activities associated with the industrial production of dyes, explosives, pesticides,...Full Text Available
This Environmental Assessment evaluates the proposed action to operate two laboratory-size muffle furnaces in glovebox HC-21C, located in the Plutonium Finishing Plant (PFP), Hanford Site, Richland, Washington. The muffle furnaces would be used to stabilize chemically reactive sludges that contain approximately 25 kilograms (55 pounds) of plutonium by heating to approximately 500 to 1000{degrees}C (900 to 1800{degrees}F). The resulting stable powder, mostly plutonium oxide with impurities, would be stored in the PFP vaults. The presence of chemically reactive plutonium-bearing sludges in the process gloveboxes poses a risk to workers from radiation exposure and limits the availability of storage space for future plant cleanup. Therefore, there is a need to stabilize the material into a form suitable for long-term storage. This proposed action would be an interim action, which would take place prior to completion of an Environmental Impact ...
Glass produced during the Purex 4 campaigns of the Integrated Defense Waste Processing Facility (DWPF) Melter System (IDMS) and the 774 Research Melter contained a lower fraction of sludge components than targeted by the Product Composition Control System (PCCS). Purex 4 glass was more durable than the benchmark (EA) glass, but less durable than most simulated SRS high-level waste glasses. Also, Purex 4 glass was considerably less durable than predicted by the algorithm which will be used to control production of DWPF glass. A melter run was performed using the 774 Research Melter to determine if the initial PCCS target composition determined for Purex 4 would produce acceptable glass whose durability could be accurately modeled by Hydration Thermodynamics. Reagent grade oxides and carbonates were added to Purex 4 melter feed stock to simulate a higher sludge loading. Each canister of glass produced was sampled and the composition, ...
A thermophilic methanogen was isolated from enrichment cultures originally inoculated with sludge from an anaerobic kelp digester (55°C). This isolate exhibited a temperature optimum of 55 to...Full Text Available
The effects of freeze-thaw cycling on the strength and durability of samples of compacted, stabilized, wet flue gas desulfurization (FGD) by-products are reported. The results of laboratory tests show a clear relationship between higher water contents and...
Nitrite is to be used to inhibit pitting corrosion during Extended Sludge Processing (ESP) at the Savannah River Plant. The required nitrite concentrations are expressed as a function of the slurries' nitrate ion concentration and temperature. In the most dilute slurries, the nitrite inhibitor requirement is independent of the nitrate ion concentration and depends only on the temperature of the waste. The nitrate-independent concentration ensures that there is sufficient inhibitor, in sludge slurries whose nitrate has been depleted by radiolysis, to prevent pitting corrosion induced by other corrosive anions (e.g., sulfate and chloride). The threshold nitrate concentration at which the nitrite level is expressed as a function only of temperature is 0.02 M.
Nitrite is to be used to inhibit pitting corrosion during Extended Sludge Processing (ESP) at the Savannah River Plant. The required nitrite concentrations are expressed as a function of the slurries` nitrate ion concentration and temperature. In the most dilute slurries, the nitrite inhibitor requirement is independent of the nitrate ion concentration and depends only on the temperature of the waste. The nitrate-independent concentration ensures that there is sufficient inhibitor, in sludge slurries whose nitrate has been depleted by radiolysis, to prevent pitting corrosion induced by other corrosive anions (e.g., sulfate and chloride). The threshold nitrate concentration at which the nitrite level is expressed as a function only of temperature is 0.02 M.
The concentrations of uranium, arsenic, and radium remain well below the maximum permissible values of < 0.1 mg/l (uranium), < 0.1 mg/l (arsenic) and < 100 mBq/l (radium) due to two separation stages with barium sulfate and GoPur 3000 precipitation and due to iron hydroxide/iron arsenate precipitation. The radioactive arsenates can be separated from the toxic ones by separating the sludge which is analyzed. Processing of radioactive sludges leaves reusable GoPur 3000, sulfuric solutions which contain uranium or solutions which contain carbonate, and radioactive barium sulfate whose radiation intensity of 12 mBq/g is due to the presence of radium. The sludge produced contains adsorbed salts in addition to the dosed chemicals (floated sludges: 40 g/m"3, iron sludges < 20 g/m"3). A solids content < 100 g/m"3 can be selected for both sludge portions. ...
The main purposes of this research was to investigate the feasibility of incineration of wool-scouring sludge in a novel vertical-axis-rotating fluidised bed (RFB). The experiment was carried out in a RFB with an internal diameter (ID) of 200 mm and height of 50 mm. A cold test was first conducted to investigate the fluidization performance of the RFB via parameters such as the bubbling, gas distribution, bed shape and pressure drop. The tumbling phenomena was observed in the bed, and this effectively enhanced the axial mixing. The appropriate range of bed thickness, rotating speed and sand particle size were identified to ensure the full fluidization and reduce the particle elutriation. Four wool-scouring sludges from different processes were incinerated in the RFB. With 5% support methane, all sludges with a maximum moisture up to 70% as received could be successfully burned in the RFB at rotating speeds of 200 and 300 ...
A kinetic study of the degradation by ozone of eight phenolic acids present in wastewaters from olive oil mills has been performed by using a competition kinetic method. The selected phenolic acids are: caffeic, p-coumaric, syringic, vanillic, 3,4,5-trimethoxybenzoic, veratric, p-hydroxy-benzoic, and protocatechuic. The influence of the operating variables (temperature, pH, and ozone partial pressure in the gas stream) is established, and the stoichiometric ratios for the individual direct reactions between ozone and each acid are determined. Once the reaction rate constants are evaluated, they are correlated as a function of temperature and pH into kinetic expressions which are provided for every phenolic acid. The global process occurs in the fast and pseudo-first-order kinetic regime of absorption, a condition required by the competition model to be used.
The lipid obtained by the toluene extraction of a dried raw Atlanta sewage sludge by the Soxhlet method, was pyrolyzed over activated alumina at atmospheric pressure. A range of weight hourly space velocities (WHSV) from 0.22-1.60/h and a range of temperatures from 400-480[degree]C were selected. A 70 wt % yield of light liquid hydrocarbons was obtained at a WHSV of 0.46/h and 450[degree]C. The sulfur and nitrogen contents of the pyrolysis products were much lower than products from direct liquefaction of sludge. Infrared spectra and [sup 13]C nuclear magnetic resonance confirmed the absence of carbonyl groups in the products. Gas chromatography showed a uniform hydrocarbon chain length distribution across the C[sub 7] to C[sub 17] mass range. The gas product consisted mainly of carbon dioxide and hydrocarbons. Lauric acid was used as a model to study the decarboxylation. The effects of catalyst loading and catalyst moisture content were ...
Appendices to this summary consist of twelve individual status reports that will be available through the National Technical Information Service (NTIS) in the United States and of course limited copies will be available through NATO. The twelve report titles which are appendices to the summary are: (A) Status Report on the Limestone/Sludge Flue Gas Desulfurization Process; (B) Status Report on the Lime/Sludge Flue Gas Desulfurization Process; (C) Status Report on the Double Alkali/Sludge Flue Gas Desulfurization Process; (D) Status Report on the Sea Water Scrubbing Flue Gas Desulfurization Process; (E) Status Report on the Limestone/Gypsum Flue Gas Desulfurization Process; (F) Status Report on the Lime/Gypsum Flue Gas Desulfurization Process; (G) Status Report on the Double Alkali/Gypsum Flue Gas Desulfurization Process; (H) Status Report on Flue Gas Desulfurization by Scrubbing with Dilute Sulfuric Acid; (I) Status Report ...
Crude oil-polluted soil (five parts of weathered crude oil per 100 parts of soil; equivalent to 50,000 mg oil kg{sup -}1 soil) samples were slurried in deionised water (300% of the water retention capacity of the soil) and treated with various amounts of natural-rubber processing sludge (nitrogen content 62.15 mgkg{sup -1} and phosphorus contents 8.75 mgkg{sup -1}) in a well-stirred, continuously-aerated tank at 29{sup o}C. Changes in the total hydrocarbon content of the soil sample were determined, using a spectrophotometric technique, as a function of time. The extent of crude oil degradation was markedly higher (by up to 100%) in the sludge-treated soil than in the untreated soil sample. The efficiency of biodegradation of the crude oil hydrocarbons using the slurry-phase technique was compared with that of solid-phase technique. (author)
Hydrogen production from desugared molasses (DM) was investigated in both batch and continuous reactors using thermophilic mixed cultures enriched from digested manure by load shock (loading with DM concentration of 50.1 g-sugar/L) to suppress methanogens. H"2 gas, free of methane, was produced during batch cultivations, at different (DM) concentrations ranging from 1.5 g-sugars/L to 50.1 g-sugars/L. The highest yield of 237 ml-H"2/g-sugar was achieved during the DM batch fermentation at concentration of 2.1 g-sugars/L, whereafter the yield decreased with increasing DM concentration. The enriched hydrogen producing mixed culture achieved from the 16.7 g-sugars/L DM batch cultivation was immobilized on heat treated anaerobic sludge granules in an up-flow anaerobic sludge blanket (UASB) reac...
Red mud, the by-product of alumina fabricating industry by the Bayer process, was investigated to produce light-weight aggregates for structural concrete. Owing to very high concentration of Fe{sub 2}O{sub 3} in the red mud, no light-weight aggregates could be sintered from the red mud alone. Thus, red mud being mixed with sewage sludge that is in its chemical composition very similar to the clay mineral, very light-weight aggregates with the apparent density smaller than 1.0 g/cm{sup 3} was able to be fired at 1,200 deg. C, by the bloating effect. For this purpose, the mixing ratio of red mud to sewage sludge must be held less than a unity. On the other hand, a mixture containing more red mud than sewage sludge required the addition of, for instance, limestone in 20-30 percent, so that medium-light weight aggregates of the apparent density ranging from 1.4 to 1.9 g/cm{sup 3} were prepared. The suitable sintering ...
Studies technological safety of installing a water spray pressure vessel between electrostatic dedusters and coal sludge ducts. These sprays are in use elsewhere for steam generator ash removal. Dust ignition and explosion tests were carried out to examine flame and pressure wave propagation through the vessel into ducts. Water jet diameter, amount of water sprayed and coal dust removed were varied. Pressure waves exceeded 250 Pa. Test results show the vessel to be suitable for installation in briquetting plants due to its flame and explosion barrier effect and extermination of smoldering dust fires. The only disadvantage of the vessel is seen as its water and electric power consumption; about 8/sup 3//h of water and 1.5 kW/h of power per vessel serving dedusters of a 2,200 m/sup 2/ rotary brown coal dryer.
A technology for removal of undissolved impurities from a horizontal steam generator using purge water is developed on the basis of a theoretical analysis. A purge with a maximal flow rate is drawn off from the zone with the highest accumulation of sludge in the lower part of the steam generator after the main circulation pump of the corresponding loop is shut off and the temperatures of the heat transfer medium at the inlet and outlet of the steam generator have equilibrated. An improved purge configuration is used for this technology; it employs shutoff and regulator valves, periodic purge lines separated by a cutoff fixture, and a D y 100 drain union as a connector for the periodic purge. Field tests show that the efficiency of this technology for sludge removal by purge water is severa...
A rapid and accurate method for the direct simultaneous determination of nitrate and nitrite is proposed. The method is applied to the determination of nitrate and nitrite in rainwater and wastewater without preliminary separation. The determinations are performed by a CPA matrix method with ultraviolet spectrophotometric detection. The results obtained are in agreement with those obtained by conventional methods for the determination of nitrate and nitrite.
The hazardous and toxic nature of some of the constituent such as nitrite in the aquaculture wastewater is of major concern. Present study focuses the removal of nitrite from the aquaculture wastewater prior to disposal. Effect of certain operational parameters such as electrode material, current density, initial pH, and electrode spacing on nitrite removal from aquaculture wastewater was elucidated. Better nitrite removal efficiency achieved when nickel used as compared to stainless steel, graphite and aluminum electrodes. Nitrite removal is positively related to the current density however, increase is up to 31.4% when current density increased from 2.5 to 9.3 mA/cm/sup 2/. Further increase in current density does not improve the process efficiency. Removal efficiency of electrochemical process decreased with the increase in initial pH of test solution. However, with the passage of time this difference is diminishing. ...
The bibliography contains citations concerning Federal and state laws and management programs for the protection and use of inland wetlands. Utilization of wetlands to control highway runoff and community wastewater is discussed. Wetlands protection programs, restoration projects, resource planning, and wetlands identification methods are cited. References to coastal and salt water wetlands are not included in this bibliography. (Contains 250 citations and includes a subject term index and title list.)
...Chapter 11 Aqueous Solutions Chapter 11 Aqueous Solutions Download the entire chapter (PDF-136k) Drilling to China More water than rivers Saving the aquifer Drying with Xeriscapes Everywhere in the house Rainwater and graywater Creating urban watersheds Wastewater equals ...3851 Powered by Intrcomm Technology's SMC ...
Aluminum is a principal element in alkaline nuclear sludge waste stored in high level waste (HLW) tanks at the Savannah River Site. The mass of sludge in a HLW tank can be reduced through the caustic leaching of aluminum, i.e. converting aluminum oxides (gibbsite) and oxide-hydroxides (boehmite) into soluble hydroxides through reaction with a hot caustic solution. The temperature limits outlined by the chemistry control program for HLW tanks to prevent caustic stress corrosion cracking (CSCC) in concentrated hydroxide solutions will potentially be exceeded during the sludge mass reduction (SMR) campaign. Corrosion testing was performed to determine the potential for CSCC under expected conditions. The experimental test program, developed based upon previous test results and expected conditions during the current SMR campaign, consisted of electrochemical and mechanical testing to determine the susceptibility of ASTM A516 ...
Some of the origins of corrosion encountered in the secondary side of pressurized water reactor steam generators are:-sludge accumulation (a mixture of metal oxides, primarily magnetite and copper) on tube sheet and attack of tube support plates by aggressive impurities leading to denting. Although Electricite de France has not suffered from these problems, it has developed a chemical cleaning process to dissolve corrosion products at both locations. (author).
Loss of organic matter is one of the main forms of soil degradation in Mediterranean agricultural soils, and external sources of organic matter are required to improve soil properties. the two-phase centrifugation system in the olive-oil extraction industry produces a large amount of olive mill waste sludge (TPOMW) which can be used to add organic C to degraded soils. (Author)
The anaerobic transformation and degradation of nitrophenols by granular sludge was investigated in upflow anaerobic sludge blanket (UASB) reactors continuously fed with a volatile fatty acid (VFA) mixture as the primary substrate. During the start-up, subtoxic concentrations of 2-nitrophenol (2-NP), 4-nitrophenol (4-NP), and 2, 4-dinitrophenol (2, 4-DNP) were utilized. 4-NP and 2, 4-DNP were readily converted to the corresponding aromatic amine; whereas 2-NP was converted to nonaromatic products via intermediate formation of 2-aminophenol (2-AP). These conversions led to a dramatic detoxification of the mononitrophenols because the reactors treated the nitrophenolics at the concentrations which were over 25 times higher than those that caused severe inhibition. VFA removal efficiencies greater than 99% were achieved in both reactors at loading rates greater than 11.4 g COD per liter of reactor volume per day even at volumetric loading of ...
Considering the fact that more than 40% of all household wastes are organic wastes composting could be an excellent relief and complement to other waste disposal methods (e.g. combustion or direct landfills). Provided the right conditions household wastes could be composted together with sewage sludges and manures. The paper discusses the legal aspects, quantitative evaluations, conveying systems, as well as the compost utilization and marketing aspects valid for the Federal Republic of Germany.
Federal and California regulations governing the disposal of sludges and liquid wastes associated with the production of electricity from geothermal resources were evaluated. Current disposal practices, near/far term disposal requirements, and the potential for alternate disposal methods or beneficial uses for these materials were determined. 36 refs., 3 figs., 15 tabs. (ACR)
Alloy 800 has been used for steam generator (SG) tubing for more than 30 years, primarily in CANDU reactors and in reactors in Germany. The grade of Alloy 800 tubing used for this service has a controlled Ti/C ratio ({>=}12 for CANDU SGs), and this specification is sometimes termed Alloy 800 M or Alloy 800 NG . There have been very few corrosion-related flaws detected in this material in SG service, and, until recently, no incidences of cracking. There has been extensive R and D carried out on Alloy 800 tubing, both in Canada and elsewhere, under a variety of operating conditions, including shutdowns, which show that it has excellent resistance to corrosion-related degradation under specified and appropriate operating conditions. These R and D findings are reflected in the in-service experience. It has been shown from the R and D that Alloy 800 is susceptible to corrosion under acidic conditions, in particular those that can arise as a consequence of phosphate water ...
Alloy 800 has been used for steam generator (SG) tubing for more than 30 years, primarily in CANDU reactors and in reactors in Germany. The grade of Alloy 800 tubing used for this service has a controlled Ti/C ratio (#>=#12 for CANDU SGs), and this specification is sometimes termed Alloy 800 M or Alloy 800 NG . There have been very few corrosion-related flaws detected in this material in SG service, and, until recently, no incidences of cracking. There has been extensive R and D carried out on Alloy 800 tubing, both in Canada and elsewhere, under a variety of operating conditions, including shutdowns, which show that it has excellent resistance to corrosion-related degradation under specified and appropriate operating conditions. These R and D findings are reflected in the in-service experience. It has been shown from the R and D that Alloy 800 is susceptible to corrosion under acidic conditions, in particular those that can arise as a consequence of phosphate water ...
Heat transfer processes use fluids which are generally not pure and can react with transfer surfaces. These surfaces are subject to deposits which can be sediments harmful to heat transfer and to integrity of materials. For nuclear plant steam generators, sludge build-up accelerates secondary side corrosion by concentrating chemical species. A major safety problem involved with such a corrosion is the growing of circumferential cracks which are very difficult to detect and size with eddy current probes. With a view to understand and control this problem, it is necessary to develop a mathematical model for the prediction of sludge behavior in PWR steam generators. Based on fundamental principles, this work intends to use different models available in literature for the prediction of the phenomenon leading to the accumulation of sludge particles at the bottom (the tubesheet) of a PWR. For that, a three-dimensional simulation ...
This Corrective Action Investigation Plan contains the U.S. Department of Energy, Nevada Operations Office's approach to collect the data necessary to evaluate corrective action alternatives appropriate for the closure of Corrective Action Unit (CAU) 409 under the Federal Facility Agreement and Consent Order. Corrective Action Unit 409 consists of three Corrective Action Sites (CASs): TA-53-001-TAB2, Septic Sludge Disposal Pit No.1; TA-53-002-TAB2, Septic Sludge Disposal Pit No.2; and RG-24-001-RGCR, Battery Dump Site. The Septic Sludge Disposal Pits are located near Bunker Two, close to Area 3, on the Tonopah Test Range. The Battery Dump Site is located at the abandoned Cactus Repeater Station on Cactus Peak. The Cactus Repeater Station was a remote, battery-powered, signal repeater station. The two Septic Sludge Disposal Pits were suspected to be used through the late 1980s as disposal sites ...
In a study where the removal of heavy metals from wastewater is the primary aim, the biosorption of heavy metals onto biosolids prepared as Pseudomonas aeruginosa immobilized onto granular activated carbon was investigated in batch and column systems. In the batch system, adsorption equilibriums of heavy metals were reached between 20 and 50 min, and the optimal dosage of biosolids was 0.3 g/L. The biosorption efficiencies were 84, 80, 79, 59 and 42 % for Cr(VI), Ni(II), Cu(II), Zn(II) and Cd(II) ions, respectively. The rate constants of biosorption and pore diffusion of heavy metals were 0.013-0.089 min{sup -1} and 0.026-0.690 min{sup -0.5}. In the column systems, the biosorption efficiencies for all heavy metals increased up to 81-100 %. The affinity of biosorption for various metal ions towards biosolids was decreased in the order: Cr = Ni > Cu > Zn > Cd. (Abstract Copyright [2006], Wiley Periodicals, Inc.)
An efficient adsorption process is developed for the decontamination of trivalent chromium from tannery effluents. A low cost activated carbon (ATFAC) was prepared from coconut shell fibers (an agricultural waste), characterized and utilized for Cr(III) removal from water/wastewater. A commercially available activated carbon fabric cloth (ACF) was also studied for comparative evaluation. All the equilibrium and kinetic studies were conducted at different temperatures, particle size, pHs, and adsorbent doses in batch mode. The Langmuir and Freundlich isotherm models were applied. The Langmuir model best fit the equilibrium isotherm data. The maximum adsorption capacities of ATFAC and ACF at 25 deg. C are 12.2 and 39.56 mg/g, respectively. Cr(III) adsorption increased with an increase in temperature (10 deg. C: ATFAC-10.97 mg/g, ACF-36.05 mg/g; 40 deg. C: ATFAC-16.10 mg/g, ACF-40.29 mg/g). The kinetic studies were conducted to delineate the effect of temperature, ...
The use of municipal sewage sludge as a fertilizer in agriculture is a convenient method of disposal. However, sludge is often contaminated with toxic organic compounds such as dioxins, polychlorinated biphenyls (PCBs), and polycyclic aromatic hydrocarbons (PAHs), with implications for soil fertility and quality of crops for human and animal consumption. These compounds can be assimilated by intact plants or in-vitro cell-Culture systems. The amount of uptake depends on the plant species and on the physico-chemical conditions that influence, for example, molecular configuration; uptake rates are higher with low-molecular-weight and polar compounds. The xenobiotic can be converted to polar conjugates and hydroxylated metabolites that may also be toxic. In some cases, large amounts of the compound and/or its metabolic products are incorporated into non-extractable residues. The bound residues, especially those associated with carbohydrate ...
Products of a power plant flue gas desulfurization scrubber are discharged into a pond as sludge consisting of calcite (initial delta13C 3.2-3.8 per thousand), gypsum (initial delta34S 7.6-8.6 per thousand), and aqueous solution. Reducing conditions exist below a boundary that appears to move vertically as a function of changes in pond water level. Under reducing conditions, bacteria partially reduce aqueous sulfate to low-delta34S sulfide, consuming organic carbon and generating low-delta13C bicarbonate. Under oxidizing conditions, sulfide is converted to sulfate, leading to calcite dissolution, gypsum precipitation, and isotopic re-equilibration of remaining calcite with dissolved bicarbonate near the pond surface. The gypsum has delta34S near 6 per thousand, and calcite has delta13C as low as -1.7 per thousand; the changes from initial values correspond to predictions based on isotopic balance and reaction stoichiometry. The pond largely contains the products of ...
Stabilization/solidification of hazardous wastes is used to convert hazardous metal hydroxide waste sludge into a solid mass with better handling properties. This study investigated the pore size development of ordinary portland cement pastes containing metal hydroxide waste sludge and rice husk ash using mercury intrusion porosimetry. The effects of acre and the addition of rice husk ash on pore size development and strength were studied. It was found that the pore structures of mixes changed significantly with curing acre. The pore size shifted from 1,204 to 324 {angstrom} for 3-day old cement paste, and from 956 to 263 {angstrom} for a 7-day old sample. A reduction in pore size distribution for different curing ages was also observed in the other mixtures. From this limited study, no conclusion could be made as to any correlation between strength development and porosity. 10 refs., 6 figs., 3 tabs.
Five corrosion probes were received from West Valley Nuclear Services for evaluation in simulated tank 8D-2 3rd-stage sludge wash slurry. The same waste slurry simulated was also used in a series of ongoing corrosion studies assessing the effects of in-tank sludge washing on the integrity of tank 8D-2. Two of the corrosion probes were installed in the coupon corrosion test vessels operating at {approximately}150{degrees}F to compare performance of the probes with that observed by coupon tests conducted in the same vessels. Corrosion rate data calculated from electrical resistance measurements of the corrosion probes were evaluated for this study using two slightly different approaches. One approach uses the total length of exposure of the probe to give a ``time-averaged`` value of the corrosion rate. The other approach uses a shorter period of time (relative to the length of the test) in the calculation of corrosion rate, and is referred to as ...
A field study was conducted to investigate the absorption of various elements into oats and carrots cultivated in brown forest soil after three years' applications of chemical fertilizer and two types of sewage sludge compost mixed with sawdust (SD compost) or rice husk (RH compost). The results obtained in this study are summarized as follows. 1) The application of SD compost led to a significant increase on the concentrations of Mn, Zn, Ag and Ba in oat root, of Zn and Br in oat shoot, of Cl and Zn in oat ears, of Mg, Sc, Mn, Zn, Br, Ba and La in carrot peel, of Mn, Fe, Co and Zn in carrot edible portion and of Na, Sc, Mn, Fe, Co and Sm in carrot shoot. 2) The application of RH compost increased the concentrations of Mn, Zn, and Ag in oat root, of K, Cr, Mn, Zn and Br in oat shoot, of Zn and Br in oat ears, of Mg, Mn and Br in carrot peel, of Cl, Mn, Zn and Br in carrot edible portion and of Na, Mn, Zn, Br and Sm in carrot shoot. (author)
The publication is an economic evaluation of the Bureau of Mines electrolytic process for recovering lead from scrap lead-acid batteries. In this process, scrap batteries are crushed and separated into metal and sludge fractions. The metal fraction is cast as anodes and electro-refined. Lead in the sludge fraction is converted to lead carbonate by reaction with an ammonium carbonate-ammonium bisulfite solution. The lead carbonate is then dissolved in a fluosilicic acid electrolyte from which pure lead metal is electrowon. A cost estimate is presented for a plant capable of processing 10,000 scrap batteries per day. The fixed capital cost for the plant is estimated to be $14 million on a fourth quarter 1984 basis. Operating costs are estimated to be $0.15/lb Pb recovered. Assuming a lead selling price of $0.17/lb, the interest rate of return on investment after taxes is 11 pct. A lead selling price of about $0.21/lb is needed to obtain a ...
The objectives of this project were to develop technologies to manufacture self-reducing briquettes out of waste iron oxides and to recycle them in an electric arc furnace or a cupola furnace. CRM has investigated and determined the optimal characteristics (binder, size, grain size, compositions and activator for the reduction reaction) for briquettes containing mixtures of mill scales, mill sludges, electric arc furnace (EAF) dust and coal as reduction agent. The goal of obtaining briquettes, in which iron oxides are totally reduced when these briquettes are loaded with the scrap into an electric arc furnace, was achieved. Trials at ProfilARBED have shown that it is possible to recycle mill and EAF by-products conditioned in self-reducing briquettes in an electric arc furnace without influence on the performance and on the environment. The iron content of the slag does not increase as the iron of the by-product is almost completely reduced. Zinc is completely ...
This paper presents anew design concept for a gamma irradiation plant for the continuous processing of pumpable liquids. Typical applications of such a plant include: the irradiation vulcanisation of natural latex rubber; disinfection of municipal sewage sludge for agricultural use; sterilisation of liquids in the pharmaceutical and cosmetics industries; industrial processing of bulk liquids The authors describe the design and operation of the latex irradiator now operating on a small production scale in Malaysia and proposed developments. The design allows irradiation processing to be carried out under an inert or other gaseous environment. State-of-the-art computer control system ensures the fully automatic processing operation needed by industrial computers.
The DOE`s clean-up of its nuclear complex require the development of innovative technologies to convert soils contaminated by hazardous and/or radioactive wastes to forms which can be readily disposed in accordance with current waste disposal methods. The unique features of Votec CMS technology should make it particularly cost-effective process for the vitrification of soils, sediments, sludges, and mill tailings containing organic metallic and/or radioactive contaminants. This article describes the technology (Votec`s combustion and melting system), the results of testing, the demonstration plant system, and summarizes the future schedule and the equipment needed. 3 figs., 3 tabs.
Calcium sulfate dihydrate in large crystal form is produced by maintaining the circulation of the lime containing scrubbing solution in the desulfurization scrubbing of flue gases from a power plant boiler so that it has a residence time of 5 to 25 hours, preferably 15 hours. The crystals are moved by passing a portion of the recirculation through a thinner in which a sludge containing crystals with a mean particle size of which 90% is in excess of 100 microns is removed. This product can be dewatered and treated with sulfuric acid and steam to convert it to the alpha semihydrate and is free from sulfite.
This Corrective Action Decision Document/Closure Report (CADD/CR) has been prepared for Corrective Action Unit (CAU) 409: Other Waste Sites, Tonopah Test Range (TTR), Nevada, in accordance with the Federal Facility Agreement and Consent Order. Located near Area 3 on the TTR approximately 140 miles northwest of Las Vegas, Nevada, CAU 409 is comprised of three Corrective Action Sites (CASs): CAS RG-24-001-RGCR, Battery Dump Site; CAS TA-53-001-TAB2, Septic Sludge Disposal Pit (referred to as Septic Sludge Disposal Pit No.1); CAS TA-53-002-TAB2, Septic Sludge Disposal Pit (referred to as Septic Sludge Disposal Pit No.2). This CADD/CR identifies and rationalizes the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Operations Office's (NNSA/NV's) recommendation that no corrective action is deemed necessary for CAU 409. The CADD/CR have been combined into one ...
Examples are given of reference materials for radionuclide X-ray fluorescence analysis (RXFA) of the environment processed by the National Bureau of Standards and the IAEA. Methods are described used for preparing standard materials for RXFA. For determining air pollutants the sample is prepared by dry or wet mineralization. Water samples have to be preserved prior to analysis. Insoluble components are separated by filtration or centrifugation. Biological materials must be dehydrated and homogenized. Samples of soil, sludges, sediments and solid wastes will sometimes have to be converted into a solution in some cases a leachate will have to be obtained. (ES).
Improving patient compliance with physicians’ treatment or prescription recommendations is an important goal in medical practice. We examine the relationship between treatment progress...Full Text Available
Interest and research into the mechanisms and treatment of neuropathic pain have increased during recent years, but current treatment is still far from satisfactory (Dworkin...Full Text Available
BackgroundThe aim of this study is to examine how clinicians and patients negotiate clinical need and treatment decisions within a context of finite resources. Dental implant treatment...Full Text Available
During the first and second quarters of 1994 air samples were collected and analyzed from 54 air particulate/halogen sampling stations, 10 noble gas sampling stations and 19 tritiated water vapor sampling stations. Surface water samples were collected and analyzed from 12 open water supply reservoirs, 8 natural springs, 2 wastewater containment ponds and 9 sewage lagoons. Groundwater samples were obtained brom 10 potable and 1 non-potable supply wells, and 8 drinking water consumption points. Ambient radiation levels were measured at 193 locations.
The extent to which a novel wash-off process using polyamide beads removed five different types of dye from three different types of fibre was similar to that achieved using conventional aftertreatments. Whilst bead wash-off and the conventional aftertreatments were of similar duration and temperature, conventional aftertreatment employed a 10:1 or 20:1 liquor ratio whereas bead wash-off used a < 1:1 liquor ratio. As vagrant dye was adsorbed onto the bead material during wash-off, the low amount of wastewater generated contained little residual dye, thereby offering the potential of reduced environmental and cost benefits. Bead wash-off did not impair the fastness of two non-metallised acid dyes on nylon 6,6 to washing at 60 ?C.
The operation of the Bullhouse Minewater System, used to treat iron-rich minewaters discharged from long-abandoned coal mines, was studied to minimise pollution of the Upper Don river in the UK. Tests were carried out to determine optimal operating conditions. Ochre flocculation with polyacrylamide was efficient in batch tests as the ochre self-flocculated and sedimented in the lagoon without the need for chemical enhancement. The rate of accretion of the pipework in the system was modified by partial dewatering, reshaping and hardening of the deposits during ageing. Samples of ochre recovered from the drying beds and sump deposits were converted to ferric sulphate coagulant by dissolution with sulphuric acid and used with a polyelectrolyte to successfully purify reservoir water and pretreat wastewater. There was considerable local interest in the scheme with educational opportunities for schools and colleges.
The lignin, one of the main by-products of the pulp industry, can be used to remove dyes from textile wastewaters. The potential of the lignin for Brilliant Red HE-3B reactive dye removal from aqueous solutions at pH=1.5 was examined by the batch technique as a function of dye concentration, solution temperature and contact time. The Freundlich, Langmuir, Dubinin-Radushkevich and Tempkin adsorption isotherms were used to describe the data of sorption equilibrium and to determine its corresponding isotherm constants. The thermodynamic parameters DG, DH and DS were also determined; the obtained values show that the sorption of reactive dye on lignin is a spontaneous, endothermic and entropy-driven process. The kinetic of reactive dye sorption was analyzed using the pseudo-first order and pse...
To elucidate biosorption mechanism and removal efficiency of plant residues as a biosorbent to abate polycyclic aromatic hydrocarbons (PAHs) in wastewater, sorption of PAHs onto wood chips (WC), ryegrass roots (RR), orange peels (OP), bamboo leaves (BL), and pine needles (PN) were investigated. The structural characterization of the biosorbents was analyzed by elemental composition, BET-N2 surface area, and Fourier transform infrared spectroscopy. PAHs sorption to the selected biosorbents were compared and correlated with their structures. Biosorption isotherms fit well with Freundlich equation and the mechanism was dominated by partition process. The magnitude of phenanthrene partition coefficients (Kd) followed the order of PN>BL>OP>RR>WC, ranged from 2484+/-24.24 to 5306+/-92.49L/kg. Ex...
A 1 MWe power plant using waste wood fuel is to be installed at a US Marine Corps base, which will supply all wood from a landfill site. The core energy conversion technology is a down-draft gasifier supplying approximately 150 Btu/scf gas to both spark ignition and diesel dual-fuel engine-generator sets. Features of the plant design include: (1) grinding wood fuel from a wide range of waste resources, (2) specialized screening for fines removal, (3) complete tar and other waste product control without landfill disposal, and (4) use of process heat for bulk fuel drying, gasifier air pre-heating, and wastewater evaporation.
Human activities in the karst Ozark Plateaus can impact water quality of springs where surface water is rapidly transferred to subsurface conduits. Bennett Spring, in southern Missouri, is the fourth largest spring in the state and supports local tourism activities. Questions regarding poorly functioning on-site wastewater systems (OWS) have raised concerns over the long-term water quality of the spring. This study reports the results of a surface water quality monitoring program in the recharge area where monthly samples were collected at base flow to identify potential pollution sources to the spring. Base flow hydrology of the recharge area was highly variable over the study period, which was drier than normal, causing an incomplete sampling record due to no flow conditions at some site...
The goal of this project is to demonstrate that, by combining state-of-the-art technology, highly efficient plant operation and maintenance capabilities and by-product gypsum sales, significant reductions of SO{sub 2} emissions can be achieved at approximately one-half the life cycle cost of a conventional Flue Gas Desulfurization (FGD) system. Further, this emission reduction is achieved without generating solid waste and while minimizing liquid wastewater effluent. Basically, this project entails the design, construction and operation of a nominal 600 MWe AFGD facility to remove SO{sub 2} from coal-fired power plant flue gas at the Northern Indiana Public Service Company`s Bailly Generating Station.
Wastes and dusts from steel industry, non-ferrous metallurgy and other branches can be utilised e.g. in agglomeration processes (sintering, pelletising or briquetting) and by injection into shaft furnaces. This paper deals with the second way. Combustion and reduction behaviour of iron- and carbon-rich metallurgical dusts and sludges containing lead, zinc and alkali as well as other wastes with and without pulverised coal (PC) has been studied when injecting into shaft furnaces. Following shaft furnaces have been examined: blast furnace, cupola furnace, OxiCup furnace and imperial-smelting furnace. Investigations have been done at laboratory and industrial scale. Some dusts and wastes under certain conditions can be not only reused but can also improve combustion efficiency at the tuyeres as well as furnace performance and productivity.
Large quantities of organic chemicals used in reprocessing spent nuclear-fuels at the Hanford Site have accumulated in underground high-level radioactive waste tanks. The organic content of these tanks must he known so that the potential for hazardous reactions between organic components and sodium nitrate/nitrite salts in the waste can he evaluated. The solubilities of organic compounds described in this report will help determine if they are present in the solid phases (salt cake and sludges) as well as the liquid phase (interstitial liquor/supernate) in the tanks. The solubilities of five significant sodium salts of carboxylic acids and aminocarboxylic acids [sodium oxalate, formate, citrate, nitrilotriacetate (NTA) and ethylendiaminetetraacetate (EDTA)] were measured in a simulated supernate solution at 25 degrees C, 30 degrees C, 40 degrees C, and 50 degrees C.
This study is one element of a larger engineering study effort by WHC to examine the feasibility of irradiated fuel and sludge consolidation in the KW Basin in response to TPA Milestone (target date) M-34-00-T03. The study concludes that up to 11,500 fuel storage canisters could be accommodated in the KW Basin with modifications. These modifications would include provisions for multi-tiered canister storage involving the fabrication and installation of new storage racks and installation of additional decay heat removal systems for control of basin water temperature. The ability of existing systems to control radionuclide concentrations in the basin water is examined. The study discusses requirements for spent nuclear fuel inventory given the proposed multi-tiered storage arrangement, the impact of the consolidated mass on the KW Basin structure, and criticality issues associated with multi-tiered storage.
The steam generator availability is one of the important problems encountered during the pressurized water nuclear plant operation. Various kinds of corrosion phenomena were observed in the past. These phenomena result from the concentration of impurities mainly in three locations in the steam generators: the tubesheet crevices, the tube support plate crevices, and the sludge pile. Corrections were made in the design and the materials used but a number of steam generators suffer or will suffer from corrosion processes inducing in many cases forcing their replacement. In order to prevent or to retard the corrosions several laboratories have performed experiments to reproduce and to study the corrosion processes. The first step of the degradation is the concentration of chemical species. A method using /sup 24/Na as a radioactive tracer was used to establish the concentration kinetics of caustic which was identified as the major cause of the intergranular attack ...
A reasonable understanding of PWR steam generator corrosion mechanisms such as denting and wastage has been developed, and adequate chemistry control programs defined to obviate the magnitude and effects of these modes of attack. However, relatively unique corrosion attack modes have been encountered at several plants notwithstanding the presence of a reasonable to very good chemistry control program when considered in light of the Steam Generator Owners Group chemistry guidelines. The uniqueness of attack also suggests that parameters not routinely measured or monitored may be playing a significant role. In the authors opinions, the only reasonable method of routinely identifying corrosion accelerating species present in crevices, sludge piles, and deposits in PWR steam generators is by performing detailed chemical return studies during power transients, shutdowns, and long term layups. Although it would be preferable to obtain samples from regions of attack, such ...
The authors study technological safety of installing a water spray pressure vessel between electrostatic deduster and coal sludge ducts. These sprays are in use elsewhere for steam generator ash removal. Dust ignition and explosion tests were carried out to examine flame and pressure wave propagation through the vessel into ducts. Water jet diameter, amount of water sprayed and coal dust removed were varied. Pressure waves exceeded 250 Pa. Test results show the vessel to be suitable for installation in briquetting plants due to its flame and explosion barrier effect and extermination of smoldering dust fires. The only disadvantage of the vessel is seen as its water and electric power consumption: about 8 m/sup 3//h of water and 1.5 kW/h of power per vessel serving dedusters of a 2,200 m/sup 2/ rotary brown coal dryer. (MOS).
Oil and gas production and processing operations sometimes cause naturally occurring radioactive materials (NORM) to accumulate at elevated concentrations in by-product waste streams. The sources of most of the radioactivity are isotopes of "2"3"8U and "2"3"2Th series, which are naturally present in the subsurface formations from which oil and gas are produced. NORM waste may cause problems in the operations of installations by plugging perforations, clogging tubular and valves then restricting flow. Therefore, plants or equipment have to be refurbished and decontaminated before reuse to avoid radioactive waste or surface contaminated object. There are two options for safe disposal of scale and sludge produced from NORM Descaling Facility : 1- Injection into an abandoned production well. 2- The construction of a near surface depository. These options are assumed to be environmental friendly disposal options. (author)
The introduction of automation technology into the analytical laboratory holds the promise of higher efficiency, improved productivity, and lower costs. However, the conventional ''laboratory robot'' widely used today may not offer the work envelope or reliability required in a high workload laboratory performing quality control or environmental analytical services. To address this need, a demonstration workcell was assembled utilizing an industrial-class robotics system to automate a standard EPA acid digestion protocol. With further development of graphical user interfaces and error recovery software, the technology will significantly enhance the ability of laboratories to meet increasingly complex environmental demands. 7 refs., 2 figs., 1 tab.
Composting of sawdust and paper mill sludge, using a 'Kneer' process reactor, was studied in an attempt to elaborate upon organic matter transformation during the process and to define parameters to measure the compost maturity level. Temperature, electron paramagnetic resonance data, ash and C, H, N and S contents, and a spectroscopic method using ultraviolet-visible (UV-VIS) for alkaline (pH = 8.5) and solid samples was used to study the maturity of the compost samples. These parameters were measured in 6 humic acids extracted from the compost samples during 29 days. The results of this work show that the 'Kneer' process is efficient in transforming ligno-celulitic residues in a short time (29 days), into an organic fertilizer material with application perspectives (author)
This final report for the Swiss Federal Office of Energy (SFOE) reports on work done in the area of gasification of biomass. The use of dung, manure and sewage sludge as sources of energy is described and discussed. Hydrothermal gasification is proposed as an alternative to conventional gas-phase processes. The aim of the project in this respect is discussed. Here, a catalytic process that demonstrates the gasification of wet biomass to synthetic natural gas (SNG) in a continuously operating plant on a laboratory scale is being looked at. Difficulties encountered in preliminary tests are discussed. Long-term catalyst stability and the installations for the demonstration of the process are discussed, and gasification tests with ethanol are commented on.
Increasing quantities of chicken waste concerns the poultry industry because of escalating disposal costs and the potential for environmental pollution. Biological conversion of these wastes to valuable products such as methane and/or chemical feed-stocks appears to be feasible. Biomethanation of chicken waste by a sewage sludge microbial consortium produced as much as 69 mol% methane in the gas phase. Acetic and propionic acids were the major acids produced during the bioconversion. Addition of chelating agents and other micro-nutrients enhanced methane production and shifted the ratios of intermediates accumulated. Preliminary data indicate that more than 60% of the chicken waste carbon was converted and that the nitrogen-rich residue may have potential as a soil additive. (author).
Generated annually from the Edison Electric Institute's POWER STATISTICS Data Base, the EEI Power Directory provides state-by-state data on all utility-owned steam-electric plants in the US. The 1988 directory contains the following information for approximately 2500 units located at 1000 generating sites around the country: unit age, capacity, fuel type, and operating status. In addition, solid waste disposal methods for fly ash, bottom ash, and sludge are covered for approximately 1500 US coal-fired units. The directory contains a listing of more than 800 environmental managers and key environmental staff at over 300 utilities, with names, addresses, and telephone numbers. Special indices list plants and utility owner-operators.
The operation of nuclear processing facilities and defense-related nuclear activities has resulted in contamination of near-surface and deep-subsurface sediments with both radionuclides and metals. The presence of mixed inorganic contaminants may result in undetectable microbial populations or microbial populations that are different from those present in uncontaminated sediments. To determine the impact of mixed radionuclide and metal contaminants on sediment microbial communities, we sampled a processing pond that was used from 1948 to 1975 for the disposal of radioactive and metal-contaminated wastewaters from laboratories and nuclear fuel fabrication facilities on the Hanford Site in Washington State. Because the Hanford Site is located in a semiarid environment with average rainfall of 159 mm/year, the pond dried and a settling basin remained after wastewater input into the pond ceased in 1975. This processing pond basin offered a unique ...
The utilization of wood-shaving bottom ash (WBA) for the removal of Red Reactive 141 (RR141), an azo reactive dye, was investigated. WBA/H(2)O and WBA/H(2)SO(4) were made by treating WBA with water and 0.1M H(2)SO(4), respectively, to increase adsorption capacity. Adsorption of RR141 from reactive dye solution (RDS) and reactive dye wastewater (RDW) by WBA/H(2)O and WBA/H(2)SO(4) involved the BET surface area and pore size diameter. Properties of adsorbents, effect of contact time, initial pH of solution, dissolved metals and elution studies indicated that the decolorisation mechanism involved both chemical adsorption and precipitation with calcium ions. In addition, the WBA/H(2)SO(4) surface might contain sulphate-cation complexes that were specific to enhancing dye adsorption from RDW. The adsorption isotherm had a best fit by the Freundlich model. Freundlich parameters showed that WBA/H(2)O used more heterogeneous surface than WBA/H(2)SO(4) and activated carbon ...
The impingement of a fluid jet onto a surface has broad applications across many industries. Within the UK nuclear industry, during the final stages of fuel reprocessing, impinging fluid jets are utilised to mobilise settled sludge material within storage tanks and ponds in preparation for transfer and ultimate immobilisation through vitrification. Despite the extensive applications of impinging jets within the nuclear and other industries, the study of two-phase, solid loaded, impinging jets is limited, and generally restricted to computational modelling. Surprisingly, very little fundamental understanding of the turbulence structure within such fluid flows through experimental investigation is found within the literature. The physical modelling of impinging jet systems could successfully serve to aid computer model validation, determine operating requirements, evaluate plant throughput requirements, optimise process operations and support design. Within this ...
In this article, the technical feasibility of the use of activated carbon, synthetic resins, and various low-cost natural adsorbents for the removal of phenol and its derivatives from contaminated water has been reviewed. Instead of using commercial activated carbon and synthetic resins, researchers have worked on inexpensive materials such as coal fly ash, sludge, biomass, zeolites, and other adsorbents, which have high adsorption capacity and are locally available. The comparison of their removal performance with that of activated carbon and synthetic resins is presented in this study. From our survey of about 100 papers, low-cost adsorbents have demonstrated outstanding removal capabilities for phenol and its derivatives compared to activated carbons. Adsorbents that stand out for high adsorption capacities are coal-reject, residual coal treated with H{sub 3}PO{sub 4}, dried activated sludge, red mud, and cetyl-trimethylammonium ...
BackgroundAttention-deficit/hyperactivity disorder (ADHD) is a common condition that often results in child and family functional impairments. Although there are evidence-based treatment...Full Text Available
In a Swedish community-based program for the treatment of dental phobic patients, a clinical trial was performed among 99 severely phobic individuals with long-standing avoidance of dental treatment....Full Text Available
Medical treatment of heroin addiction with methadone and other pharmacotherapies has important benefits for individuals and society. However, regulatory policies have separated this treatment from the...Full Text Available
BackgroundLittle is known about the acceptability of internet and telephone treatments, or what factors might influence patient interest in receiving treatments via...Full Text Available
The possibility of rapid heat treatment (RHT) application to titanium castings has been studied. It was shown that such treatment provides a significant improvement of intragrain structure and mechanical properties of cast ({alpha}+{beta})-titanium alloys. ((orig.))
ObjectiveThe aim of this study was to ascertain whether all cervical cancer patients who received adjuvant concurrent chemoradiation (CCRT) for high risk of treatment failure after...Full Text Available
Background and ObjectivePulsed dye laser (PDL) treatment of cutaneous vascular lesions is associated with variable and unpredictable efficacy. Thus, alternative treatment...Full Text Available
PurposeTo describe etiologies and clinical characteristics of corneal opacities leading patients to seek cosmetic treatments.MethodsThe medical records...Full Text Available
The objective of this project was to develop new photocatalytic or other innovative process chemistry for the treatment of pink water and related contaminated water.
OBJECTIVE: New surgical procedures designed to assist in the treatment of peritoneal surface malignancy were sought. BACKGROUND: Decisions regarding the treatment of cancer depend on the anatomic location...Full Text Available
The purpose of this article is to review the literature for clinical presentation, treatment, outcome and complications of using radiotherapy for the treatment of orbital lymphoma. For this, MEDLINE,...Full Text Available
BackgroundStump and phantom pains are debilitating sequelae of amputations that are often resistant to treatment. The efficacy of pharmacologic therapies, including...Full Text Available
BackgroundAlthough local excision (ampullectomy) was first described by Halsted in 1899, its adequacy as an alternative surgical treatment for the ampullary tumors is still a matter...Full Text Available
ObjectiveThis study investigated transitions between drinking and nondrinking during the first 12 months following treatment and whether transitions in posttreatment...Full Text Available
An acute exudative Escherichia coli pyelonephritis rat model was used to study the influence of progressive pyelonephritis on the efficacy of antibiotic treatment. In this model, transient ureteral...Full Text Available
Previous research with individuals undergoing surgery or diagnostic procedures provided a conceptual framework for analysis of radiation therapy, a common form of cancer treatment. The present...Full Text Available
Hydrogen (H) plasma treatment, oxygen (O) plasma treatment and water (H_2O)-vapor heat treatment for polycrystalline-silicon (poly-Si) thin-film transistors (TFTs) have been analyzed by separately extracting trap density at a front silicon-oxide interface (D_F) and trap density at a back interface (D_B). It is found that the H plasma treatment is apt to generate D_F and D_B. The O plasma treatment reduces D_F, while the H_2O-vapor heat treatment reduces both D_F and D_B. Improvement of transistor characteristics of poly-Si TFTs depends on understanding these results.
Fuel treatments are being implemented on public and private lands across the western United States. Although scientists and managers have an understanding ... ...
The results of treatment of 53 cases of pediatric localized Ewing's sarcoma and bone reticulosarcoma were analized. Chemoradiotherapy is a procerdure of choice in bone marrow sarcoma treatment: while overall five-year survival was 28.4#+-#6.2%, it was as high as 64.9% in cases of combined treatment (total focal dose of at least 50 Gy+polychemotherapy). Two cases of osteo- and chondrosarcoma development in exposed bone are described.
The proton therapy gives an irradiation adapted to the shape and the depth of tumors ( eyes, head and neck) with a millimetric, even sub millimetric precision for the ophthalmological tumors. It is equally an excellent tool for the pediatrics tumors. For numerous treatments in France the proton therapy is associated to the photons treatments (x radiation). however, others physical treatments could modulate the medical offer, such thermal therapy or treatments by ultrasonic waves. (N.C.)
Thermohydrogen treatment effect on microstructure and mechanical properties is studied for a cast heat resistant pseudo-#alpha#-titanium alloy Ti-6242 (Ti-6Al-2Sn-4Zn-2Mo) widely used as a heat resistant material with operating temperature up to 500 deg C. It is shown that reversible hydrogen alloying is a promising alternative to thermomechanical treatment for transformation of (#alpha#+#beta#)-titanium alloy structure. The application of thermohydrogen treatment is noted to be of particular efficiency for shaped casting technology as it allows a noticeable increase of mechanical properties at a lower cost. The alloy after thermohydrogen treatment and subsequent heat treatment in the (#alpha#+#beta#) - range possesses high values of yield strength fatigue properties, creep resistance and has a satisfactory ductility. A consideration is also given to thermohydrogen ...
This article presents an orthognathic treatment case after severe apical root resorption of maxillary anterior teeth using anterior segmental osteotomy. This case involved a 20-year-old female with the chief complaint of maxillary protruding and irregularly aligned mandibular anterior teeth. Her medical history showed no allergies or medical problems. The overbite was +3.0mm, and the overjet +3.0mm. After extraction of the four first premolars, a multi-bracket treatment was started. A severe root resorption of the maxillary anterior teeth was found 12 months after active treatment. The maxillary anterior segmental osteotomy was chosen as the compensatory treatment. The total treatment period was 2 years and 7 months. The post-retention panoramic radiograph showed no developmental root reso...
High energy radiation was studied as a means for destroying hazardous organic chemical wastes. Tests were conducted at bench scale with a {sup 60}Co source, and at full scale (387 l/min) with a 1.5 MV electron beam source. Bench scale tests for both benzene and phenol included 32 permutations of water quality factors. For some water qualities, as much as 99.99% of benzene or 90% of phenol were removed by 775 krads of {sup 60}Co irradiation. Full scale testing for destruction of benzene in a simulated waste-water mix showed loss of 97% of benzene following an 800 krad dose and 88% following a 500 krad dose. At these loss rates, approximately 5 Mrad of electron beam irradiation is required to reduce concentrations from 100 g/l to drinking water quality (5 {mu}g/l). Since many waste streams are also inhabited by bacterial populations which may affect filtering operations, the effect of irradiation on those populations was also studied. {sup 60}Co and electron beam ...
Biosorption has been developed as an effective and economic method to treat wastewater containing low concentrations of metal pollutants. In this study, a bacterium, Citrobacter freudii, was used as a biosorbent to adsorb uranium ions. The thermodynamics and kinetics of this adsorption, as well as its mechanism, were investigated. The results indicated that the biosorption rate could be better described by a pseudo 2nd-order model than a pseudo 1st-order model. The adsorption of U (VI) proceeded very rapidly in the first 30 min and subsequently slowed down continuously for a long period. The biosorption isotherm of uranium by C. freudii could be described well by the Langmuir or Freundlich isotherm, and the latter was better. The thermodynamics parameters, {delta}H{sup o}, {delta}G{sup o}, and {delta}S{sup o} were calculated according to the results of the experiment, which showed this biosorption as being endothermic and spontaneous. The authors investigated the ...
The objective of the Hanford Environmental Dose Reconstruction Project (HEDR) is to estimate the potential radiation doses received by people living within the sphere of influence of the Hanford Site. A potential critical pathway for human radiation exposure is through the consumption of waterfowl that frequent onsite waste-water ponds or through eating of fish, shellfish, and waterfowl that reside in/on the Columbia River and its tributaries downstream of the reactors. This document summarizes information on fish, shellfish, and waterfowl radiation contamination for samples collected by Hanford monitoring personnel and offsite agencies for the period 1945 to 1972. Specific information includes the types of organisms sampled, the kinds of tissues and organs analyzed, the sampling locations, and the radionuclides reported. Some tissue concentrations are also included. We anticipate that these yearly summaries will be helpful to individuals and organizations ...
The objective of the Hanford Environmental Dose Reconstruction Project (HEDR) is to estimate the potential radiation doses received by people living within the sphere of influence of the Hanford Site. A potential critical pathway for human radiation exposure is through the consumption of waterfowl that frequent onsite waste-water ponds or through eating of fish, shellfish, and waterfowl that reside in/on the Columbia River and its tributaries downstream of the reactors. This document summarizes information on fish, shellfish, and waterfowl radiation contamination for samples collected by Hanford monitoring personnel and offsite agencies for the period 1945 to 1972. Specific information includes the types of organisms sampled, the kinds of tissues and organs analyzed, the sampling locations, and the radionuclides reported. Some tissue concentrations are also included. We anticipate that these yearly summaries will be helpful to individuals and organizations ...
The objective of the Hanford Environmental Dose Reconstruction Project (HEDR) is to estimate the potential radiation doses received by people living within the sphere of influence of the Hanford Site. A potential critical pathway for human radiation exposure is through the consumption of waterfowl that frequent onsite waste-water ponds or through eating of fish, shellfish, and waterfowl that reside in/on the Columbia River and its tributaries downstream of the reactors. This document summarizes information on fish, shellfish, and waterfowl radiation contamination for samples collected by Hanford monitoring personnel and offsite agencies for the period 1945 to 1972. Specific information includes the types of organisms sampled, the kinds of tissues and organs analyzed, the sampling locations, and the radionuclides reported. Some tissue concentrations are also included. We anticipate that these yearly summaries will be helpful to individuals and organizations ...
A combination of measuring instruments, consisting of a Beta-Sedimeter and a radionuclide X-ray fluorescence instrument, is described. With the Beta-Sedimeter the C-14-radiation is measured. Through direct irradiation with photons of a Pu238-source in an ancillary irradiation chamber and energy dispersing measurement of the K- and L-radiation resp. of the excited heavy metals with the aid of a Si(Li)-semiconductor detector and a 4-channel analyzer the heavy metal concentrations of the heavy metals Zn, Cr, Ni and Pb are determined. For the determination of cadmium the indirect excitation with Am-241 and Dy-targets is described. The system produces records and operates fully automatically in a step-by-step mode with a testing cycle of 45 minutes. In connection with the process monitoring of the wastewater from a zinc plating plant during a period of 8 months the concentration of the solid material and of the metals Cr and Zn, which were considered to be ...
A $200 million paper mill being built in Hagerstown, Md., is expected to produce 150,000 bone-dry short tons per year of de-inked, market-grade pulp for writing and printing paper. The 1st Urban Fibers facility, the largest capital project in Hagerstown's history, is slated for completion in the spring. Landegger Recycled Fiber Corp. will operate and maintain the 200,000-square-foot recycling mill and 60,000-square-foot water reclamation plant. The wastepaper recycling mill plans to minimize waste and pollution by: reclaiming 635 tons per day of 100 percent post-consumer mixed office waste from the solid waste stream; saving more than 16 million cubic feet of landfill area per year; conserving the fiber equivalent of 6,700 trees per day; using no chlorine; saving about 2,000 gallons of water and 4,000 kilowatt hours of electricity per ton of throughput, compared to virgin fiber mills; reusing treated wastewater, reducing effluent discharge by 65 percent; ...
This paper presents a summary of the first phase of the EPA project, which encompasses surveys of residues from industrial sources in Alexandria. Studies to date indicate that wastes from various industries can be recovered economically. Wastes such as tin cans, glass, wastepaper, and food residues from processing of fruits, starch, and beer are examples of reusable industrial wastes in Egypt. The results of experimental studies for reuse of residues from oil refining, starch and yeast processing, and steel pickling are presented. Spent clay from edible oil refining is currently discarded, causing both handling and disposal problems. This clay contains as much as 40% oil; 90% can be recovered by extraction. The recovered oil can be successfully used in soap production, and the spent clay can be reused in oil bleaching. Other examples include starch and yeast wastes, which can be used for animal feed, and spent pickling liquor, which can be used as a coagulant aid for treating paper ...
The objective this work was to evaluate the gamma radiation processing for elimination of organic contaminants on industrial wastewater. Standard samples with 17 hydrocarbons (acetophenone, anisole, benzene, chlorobenzene, cyclohexanone, N, N-dimethylaniline, phenol, naphtalene, 1-chloronaphtalene, n-octadecane, p-nitrotoluene, toluene, tetrachloroethane, tetramethylbenzene, n-undecane, m-xylene and o-xylene) was preparated in hexane with total concentration of 1 #mu# g/ #mu# l which was analyzed by gas chromatography. Other sample with the same concentration of these hydrocarbons in acetone was used to contaminate water samples, which were irradiated with gamma radiation from Co-60 between doses 5.0 to 20.0 KGy and dose rate of 1.162 KGy/h. The activity of source was 1470 Ci. Percents destruction of hydrocarbons were: 79.76 % to 5.0 KGy, 85.97 % to 7.5 KGy, 86.24 % to 10.0 KGy, 86.72 % to 12.5 KGy, 88.92 % to 15.0 KGy, 91.74 % to 17.5 KGy and 92.38 % to 20.0 KGy. ...
This project will determine whether electrolytic dialysis has promise in the separation of charged particles in an aqueous solution. The ability to selectively move ions from one aqueous solution to another through a semipermeable membrane will be studied as a function of emf, amperage, and particle electrical charge. The ions selected for the study are Cl{sup -} and SO{sub 4}{sup 2-}. These ions are of particular interest because of their electrical conduction properties in aqueous solution resulting with their association with the corrosive action of metals. The studies will be performed with commercial membranes on solutions prepared in the laboratory from reagent salts. pH adjustments will be made with dilute reagent acid and base. Specific objectives of the project include testing a selected membrane currently available for electrolytic dialysis, membrane resistance to extreme pH conditions, the effectiveness of separating a mixture of two ions selected on the basis of size, the ...
One wonders how a facility will cope with the new Clean Air Act Amendments (CAAA). Environmental engineers working in large companies' facilities and in corporate engineering groups already have an idea of how to comply with the regulations for chemical plant equipment leaks. (In fact, the rules will also affect process bins, wastewater, transfer and storage.) But those who work for smaller companies or who have assignments not directly tied to environmental affairs may not have access to the latest thinking on compliance. One of the first challenges in becoming aware of the CAAA regulations is learning the new language, which consists of acronyms, some containing other acronyms. NESHAP, for example, stands for national emissions standards for hazardous air pollutants. Prior to the CAAA, NESHAPs applied to a few specific chemicals, such as benzene. Now the proposed rules establish a HON, a hazardous organic NESHAP. According to David Gustafson, environmental air ...
In 1990, field studies of water quality and stream macroinvertebrate communities were initiated in Sandia Canyon at Los Alamos National Laboratory. The studies were designed to establish baseline data and to determine the effects of routine discharges of industrial and sanitary waste. Water quality measurements were taken and aquatic macroinvertebrates sampled at three permanent stations within the canyon. Two of the three sample stations are located where the stream regularly receives industrial and sanitary waste effluents. These stations exhibited a low diversity of macroinvertebrates and slightly degraded water quality. The last sample station, located approximately 0.4 km (0.25 mi) downstream from the nearest wastewater outfall, appears to be in a zone of recovery where water quality parameters more closely resemble those found in natural streams in the Los Alamos area. A large increase in macroinvertebrate diversity was also observed at the third station. ...
This book describes one approach to building and operating biogas systems. The biogas systems include raw material preparation, digesters, separate gas storage tanks, use of the gas to run engines, and the use of the sludge as fertilizer. Chapters included are: (1) "Introduction"; (2) "Biogas Systems are Small Factories"; (3) "The Raw Materials of Biogas Digestion"; (4) "The Daily Operation of a Biogas Factory"; (5) "The Once a Year Cleaning of the Digester"; (6) "Tanks and Pipes: Storing and Moving Biogas"; (7) "The Factory's Products: Biogas"; (8) "The Factory's Products: Biofertilizer"; (9) "The ABCs of Safety"; and (10) "Conclusion: Profiting from an Appropriate Technology." Many diagrams are provided throughout this handbook. New ideas, composting, bioinsecticides, ferrocement, facts and figures, sources and resources, feasibility studies, problem solving, and vocabulary are presented in the appendices. (YP)
Metal contaminated crops from contaminated soils are possible hazards for the food chain. The aim of this study was to find practical and cost-effective measures to reduce metal uptake in crops grown on metal contaminated soils near a former metal smelter in Austria. Metal-inefficient cultivars of crop plants commonly grown in the area were investigated in combination with in-situ soil amendments. A laboratory batch experiment using 15 potential amendments was used to select 5 amendments to treat contaminated soil in a pot study using two Barley (Hordeum vulgare L.) cultivars that differed in their ability to accumulate cadmium. Results from this experiment identified 3 of these amendments for use in a field trial. In the pot experiment a reduction in ammonium nitrate extractable Cd (<41%) and Pb (<49%) compared to the controls was measured, with a concurrent reduction of uptake into barley grain (Cd < 62%, Pb < 68%). In the field extractable fractions of Cd, Pb, and Zn ...
Meltdown and gasification of waste in an oxygen atmosphere ('2sv' process) is an economically efficient alternative to energetic and thermal utilisation of biomass. Organic pollutants are split at temperatures up to 2000 C in a reducing atmosphere. The process uses elements of the oxygen cupola furnace for melting and gasification of many different waste fractions, e.g. polluted waste wood, household refuse and bulk waste, old tyres, light shredder fractions, sewage sludge, etc. [German] Die Sauerstoff-Schmelz-Vergasung ('2sv') stellt eine wirtschaftliche Alternative zur energetischen Nutzung von Biomassen wie auch zur thermischen Abfallverwertung dar. Organische Schadstoffe werden bei diesem neuen Verfahren bei Temperaturen bis zu 2000 C unter reduzierenden Bedingungen aufgespalten. Das Verfahren nutzt Elemente des Sauerstoff-Kupolofens fuer die Schmelzvergasung und eignet sich fuer zahlreiche Abfallarten wie z.B. belastetes ...
Both ammonium and nitrite act as substrates as well as potential inhibitors of anoxic ammonium-oxidizing (Anammox) bacteria. To satisfy demand of substrates for Anammox bacteria and to prevent substrate inhibition simultaneously; two strategies, namely high or low substrate concentration, were carefully compared in the operation of two Anammox upflow anaerobic sludge blanket (UASB) reactors fed with different substrate concentrations. The reactor working at relatively low influent substrate concentration (NO(2)(-)-N, 240 mg-NL(-1)) was shown to avoid the inhibition caused by nitrite and free ammonia. Using the strategy of low substrate concentration, a record super high volumetric nitrogen removal rate of 45.24 kg-Nm(-3) day(-1) was noted after the operation of 230 days. To our knowledge, such a high value has not been reported previously. The evidence from transmission electron microscopy (TEM) showed that the morphology and ultrastructure of the Anammox cells in ...
A test methodology for measuring temperature, impedance, pH, and electrochemical potential distributions within a sludge-packed tube support plate crevice in a laboratory test is described. The method successfully showed that there were large concentration gradients between the tube and tube support plate sides of the crevice. The testing also showed that strong bases concentrated more effectively than strong acids, and that the crevice pH, when exposed to seawater-based solutions, increased with increasing superheat and decreasing bulk concentration. The large variations in the crevice chemistry observed under heat transfer were eliminated upon shutdown. These new test data suggest that it might be beneficial to evaluate the variation in the extent of stress corrosion cracking with tube support plate elevation found in some steam generators in light of local chemistry changes, as well as the variation in tubing temperature. Because of the large crevice chemistry ...
The application of chemical cleaning for dissolving and removing scale and sludge is being planned in the Japanese pressurized water reactor (PWR) plant in order to maintain high heat transfer performance and to prevent steam generator (SG) tube degradation. In this paper, the effectiveness of the Electric Power Research Institute (EPRI) and German Kraftwerk Union (KWU) processes on the integrity of structural materials other than SG tubes and the comprehensive applicability of chemical cleaning are discussed. The integrity of structural materials such as carbon steel, low-alloy steel and stainless steel was maintained after the EPRI and KWU processes. KWU chemical cleaning tailored for crevice cleaning has been studied to improve its cleaning effectiveness in crevices and to control the corrosion depth of structural materials less than the criterion for corrosion depth. (author)
The adsorption of mercury vapor on particles was studied by using soot particles generated by incineration of sewage sludge (EP-ash) and activated carbon particles. Through the experiments, it was found that, at 298 K, the EP-ash has a fairly high adsorption capacity for mercury vapor in the order of 10/sup -6/g/g, which is between that of the ordinary soils and that of activated carbon particles. Furthermore, it was found that physical adsorption of mercury vapor on the studied particles at high temperature is described by Dubinin's equation. On the basis of the equation, it was shown that EP-ash physically adsorbs very little mercury at high temperature, and therefore, most mercury in the EP-ash is chemically adsorbed or contained in a form of mercury compounds. Nevertheless, the total amount of mercury contained in the particles is very little compared to the total mercury in the exhaust gases so that most mercury behaves as a vapor in the presence of ...
Production treatment chemicals represent a diverse collection of chemical classes, added at various points from the wellhead to the final flotation cell, to prevent operational upsets and enhance the separation of oil from water. Information in the literature indicates that while many treatment chemicals are thought to partition into oil and not into the produced water, there are cases where a sufficiently water soluble treatment chemical is added at high enough concentrations to suggest that the treatment chemical may add to the aquatic toxicity of the produced water. A study was conducted to evaluate the potential effect of production treatment chemicals on the toxicity of produced waters using the US EPA Seven-day Mysidopsis bahia Survival, Growth and Fecundity Test. Samples of produced water were collected and tested for toxicity from three platforms under normal operating ...
Many alternative therapies are used as first aid treatment for burns, despite limited evidence supporting their use. In this study, Aloe vera, saliva and a tea tree oil impregnated dressing (Burnaid) were applied as first aid to a porcine deep dermal contact burn, compared to a control of nothing. After burn creation, the treatments were applied for 20 min and the wounds observed at weekly dressing changes for 6 weeks. Results showed that the alternative treatments did significantly decrease subdermal temperature within the skin during the treatment period. However, they did not decrease the microflora or improve re-epithelialisation, scar strength, scar depth or cosmetic appearance of the scar and cannot be recommended for the first aid treatment of partial thickness burns. PMID:18603378
This case report presents a case that underwent orthognathic treatment with anterior segmental osteotomies on both jaws. The patient was a 26-year-old female with maxillary protrusion, lip incompetence with an everted vermilion border. The overbite was +1.0mm, overjet +1.0mm. The pre-surgical orthodontic treatment included the extraction of the four first premolars and a multi-bracket treatment was started. After 12 months of pre-surgical orthodontic treatment, both the anterior maxillary and the anterior mandibular segments were retracted surgically by 5.5mm. The total treatment period was 18 months. An anterior segmental osteotomy can induce the remarkable structural changes for bimaxillary lip protrusion patients.
This guidebook concerns the design of air-conditioning and air-treatment installations in recent and old buildings. The design of indoor atmosphere treatment systems is based on a rigorous and safe methodology. The following aspects are reviewed: situation of ambient air treatment, different aspects of a project, humid-air technique, principles of air treatment, basic conditions for a successful project, determination of enthalpy and hydric loads of rooms, design of ambient treatment systems, cold water production using a thermodynamical system, aeraulics, hydraulics, acoustics, logics of operation, forecasting of energy consumptions, global management of air-conditioning installations, ambient air-treatment systems. (J.S.)
This review briefly discusses the clinical and basic science rationale for vagus nerve stimulation (VNS) in treatment-resistant depression (TRD). As the number of treatment failures for depression increases, the likelihood of achieving remission during acute treatment decreases, and the risk of relapse increases with the number of treatment failures. Two open trials of adjunctive VNS for TRD showed positive acute results and a growing benefit over time. The results of the acute randomized controlled trial were not significant for the primary outcome (response by HRSD-24), but the secondary measure (IDS-SR-30) was significant for VNS. A 12-month nonrandomized comparative analysis of patients receiving adjunctive VNS with TRD patients receiving treatment as usual showed significant results f...
The activated charcoal is very appreciates for the water treatment. It do not generate by-product of treatment. In return it is saturated after some time and may releases pollutant compounds. When and how to get to its regeneration?.
The primary objective of our study is to describe urinary symptoms in women treated for endometrial cancer. We performed a cross-sectional survey of women who had undergone surgical treatment...Full Text Available
PURPOSECost-sharing, intended to control the “over-use” of healthcare resources, may also reduce utilization of necessary services. The influence...Full Text Available
Gas turbine component protection remains essential but environmental regulations emphasize the gas-turbine efficiency. Heating and cooling are features often integrated into the GI air intake packages to provide the optimum operating conditions. This paper describes modern inlet air treatment systems and discusses their effectiveness. (author)
Nine patients with renal osteodystrophy were tested for 6.5 to 35 months with 1,25-dihydroxycholecalciferol (1,25-DHCC). A close biochemical follow-up was performed during the first 6 months of treatment,...Full Text Available
PurposeAssessment of safety and efficacy of extracorporeal shockwave lithotripsy versus semi-rigid ureteroscope with lithoclast for treatment of large proximal ureteral stones.Materials...Full Text Available
AIM: To evaluate the effects of percutaneous ozone injection via the posterior-lateral route and inner margin of the facet joint in the treatment of large lumbar disc herniation.METHODS:...Full Text Available
Treatment with sorafenib prolongs both the median survival and time to progression by nearly 3 months in patients with advanced hepatocellular carcinoma. Although the effects of combining sorafenib...Full Text Available
After lifestyle and behavioral measures to control overactive bladder, the mainstay of pharmacological treatment is the use of antimuscarinic therapy. Overactive bladder predominantly affects older...Full Text Available
Verapamil administered before treatment, but not after treatment, had a beneficial effect on a 90-minute warm ischemia-reperfusion rat liver injury model. The possible activation of proteases converting...Full Text Available
BackgroundPatients’ general tendency to adhere to health care provider-recommended treatments is associated with a number of health outcomes, but whether it influences pain...Full Text Available
The treatment for erectile dysfunction (ED) was revolutionized with the development of phosphodiesterase type 5 (PDE5) inhibitors. Tadalafil (Cialis®; Eli Lilly and Company, Indianapolis,...Full Text Available
The effects of response effort on safe behaviors (i.e., glove wearing, hand sanitizing, and electrical outlet replacement) exhibited by therapists at an autism treatment center were examined. Participants...Full Text Available
ObjectivesObjectives Not AvailableDescriptionA collaborative study of the anaerobic treatment of wastes containing recalcitrant and inhibitory compounds using the SERC Anaerobic facility, in particular biomass structure, monitoring and control, catabolism and toxicity, pre-acidification and microbial growth and mesophilic and thermophilic lignocellulose degradation.~%~
Chronic pain patients who show aberrant drug-related behavior often are discontinued from treatment when they are noncompliant with their use of opioids for pain. The purpose of this study was...Full Text Available
A statistical treatment has been applied to interpret the experimental data on the Xe M-shell vacancy production in slow 1.05 MeV Xe-Xe collisions and is shown to give better agreement with experiment than that of the molecular-orbital models.
OJECTIVEThis study seeks to identify practices of self-medication in the treatment of ocular emergencies. We examine patients’ use of both homemade preparations and manufactured...Full Text Available
China’s methadone maintenance treatment program was initiated in 2004 as a small pilot project in just eight sites. It has since expanded into a nationwide program encompassing more than 680...Full Text Available
Lower urinary tract symptoms (LUTS) associated with benign prostatic hyperplasia (BPH) are highly prevalent in older men. Medical therapy is the first-line treatment for LUTS associated with BPH. Mainstays...Full Text Available
Atypical antipsychotic medications have assumed growing importance for the treatment of bipolar disorder, an illness that affects approximately 1.2%–3.7% of the general population in a given...Full Text Available
BackgroundPresumptive treatment of all febrile patients with anti-malarials leads to massive over-treatment. The aim was to assess the effect of implementing malaria rapid diagnostic...Full Text Available
Systemic chemotherapy has been relatively ineffective in the treatment of malignant brain tumors even though systemic chemotherapy drugs are small molecules that can readily extravasate across the porous...Full Text Available
BackgroundThe optimal treatment for locally recurrent rectal cancer (LRRC) is still a matter of debate. This study assessed the outcome of LRRC patients treated with multimodality...Full Text Available
The effect of adriamycin in combination with radiation on the skin reactions of mouse feet has been examined under a variety of experimental conditions including: (a) hyperthermic treatment of the foot immediately following adriamycin administration, with the former given either just before or just after x irradiation, and (b) fractionated treatments of drug and radiation in a variety of sequences over an 18-day period. In the case of the most severe hyperthermic treatment, no increased radiation reactions were observed in the presence of adriamycin. However, in the case of the less severe hyperthermic treatment a small but significant increase in skin reactions was observed. In the study of fractionated drug and radiation treatments, an enhancement of reaction in those animals receiving combined modality treatment over those receiving radiation alone was seen ...
This is a report of surgical treatment of thoracoabdominal aortic aneurysms and aneurysms of the abdominal aorta from which the visceral vessels arise during the 18 year period from April 5, 1960,...Full Text Available
Treatment of functional bowel disorders of irritable bowel-type (IBS) in children remains a difficult task because of a lack of drugs with low adverse event profile. We here report the results of a...Full Text Available
While most cancer survivors are at risk for being lost in the transition from treatment to survivorship, rural breast cancer survivors face special challenges that might place them at particular...Full Text Available
Low dose methotrexate has been used effectively for various rheumatic and non-rheumatic diseases. Three cases of Pneumocystis carinii pneumonia occurring during treatment of rheumatoid arthritis with...Full Text Available
This report results from a contract tasking Eindhoven University of Technology as follows: The contractor will investigate the plasma treatment of surfaces and plasma enhanced deposition using EUT's cascade arc source as the basis for this effort.
Nowadays, percutaneous pulmonary valve implantation is a successful alternative to surgery for patients requiring treatment of pulmonary valve dysfunction. However, owing to the wide variety of implantation...Full Text Available
Opioids have been regarded for millennia as among the most effective drugs for the treatment of pain. Their use in the management of acute severe pain and chronic pain related to advanced medical...Full Text Available
Telbivudine is a novel nucleoside drug recently approved for the treatment of patients with chronic hepatitis B. Its nonclinical safety was evaluated in a comprehensive program of studies, including...Full Text Available
BackgroundAllogeneic hematopoietic cell transplantation is a potentially curative treatment for patients with acute lymphoblastic leukemia. However, the majority of older adults...Full Text Available
Data on raw water quality, disinfection treatment practices, and the resulting mutagenic properties of the treated water were compiled from pilot- and full-scale treatment experiments to evaluate that...Full Text Available
Adaptive radiation therapy (ART) is the incorporation of daily images in the radiotherapy treatment process so that the treatment plan can be evaluated and modified to maximize the amount of radiation...Full Text Available
Cancer treatment with ionizing radiation is often compromised by organ motion, in particular for lung cases. Motion uncertainties can significantly degrade an otherwise optimized treatment plan....Full Text Available
BackgroundMass treatment to trachoma endemic communities is a critical part of the World Health Organization SAFE strategy. However, non-participation may not be at random, affecting...Full Text Available
Investigation of Interaction of Laser Radiation with Radioactive Deposits on the metal Surface and Creation of Experimental Stand for Development of Laser Technology for Remote Treatment of Materials Contaminated with Radioactive Substances at the Atomic Power Plants
BackgroundWe have recently reported successful treatment of patients with chronic pain syndromes using human pooled intravenous immunoglobulin (IVIG) in a prospective, open-label...Full Text Available
Tracheobronchial balloon dilation and stent placement have been well used in the treatment of patients with benign and/or malignant diseases. Balloon dilation is the first option in the treatment of...Full Text Available
Objectives: The purpose of the study was to discover how women found out about uterine fibroid embolization (UFE) for the treatment of symptomatic uterine fibroids.Methods:...Full Text Available
SummaryConvection-enhanced delivery (CED) of substances within the human brain is becoming a more frequent experimental treatment option in the management of brain tumors, and...Full Text Available
OBJECTIVE:To evaluate the profile of osteoporosis treatment among patients hospitalized due to hip fractures at a tertiary-level university hospital. To compare the impact of hospitalization...Full Text Available
ABSTRACTObjectivesTo test the feasibility of human immune globulin (IG, Gamimune N, 10%) as a new treatment for endophthalmitis, the ocular tolerance, distribution,...Full Text Available
AimsTranscatheter treatment of heart valve disease is well established today. However, for the treatment of tricuspid regurgitation (TR), no effective catheter-based approach is...Full Text Available
Forty-two patients with frozen shoulder were followed up closely for eight months. They were all taught pendular exercises and randomly allocated to one of four treatment groups: (a) intraarticular...Full Text Available
A 17-year-old H1N1-positive patient was successfully extubated after 25 days of ventilatory support for treatment of viral pneumonia which was complicated by empyema thoracis due to Candida...Full Text Available
Several drugs are available for the management of postmenopausal osteoporosis. This may, in daily practice, confuse the clinician. This manuscript offers an evidence-based update of previous treatment...Full Text Available
Pseudoaneurysms related to the superior mesenteric artery (SMA) are a recognised complication of trauma to the vessel, and successful treatment with stenting has been previously described. We report...Full Text Available
BackgroundAn artemisinin-based combination therapy, artesunate (AS) plus sulphadoxine-pyrimethamine (SP), was compared to SP monotherapy to provide evidence of further treatment...Full Text Available
The mechanical properties of laminated window profiles manufactured using two types of adhesives were determined. The objective of this study is to evaluate the effects of heat treatment on some mechanical...Full Text Available
Antivenoms are the currently available agents for treatment of snake venom intoxication in humans. The development of therapeutic strategies employing more generally available drugs could improve treatment of invenomation by reducing hypersensitive reacti...
This report estimates the economic and financial effects of compliance with the proposed effluent limitations guidelines and standards for the Centralized Waste Treatment (CWT) industry. The Environmental Protection Agency (EPA) has measured these impacts...
IntroductionFlow diversion is a new approach to the endovascular treatment of intracranial aneurysms which uses a high density mesh stent to induce sac thrombosis. These devices...Full Text Available
The aim of this study is to develop an Automatic Post-processing Tool for four-dimensional (4D) treatment planning (APT4D) that enables the user to perform some necessary procedures related...Full Text Available
BACKGROUND AND AIMS:In view of increasing therapeutic efficacy, the delivery of hepatitis C virus (HCV) antiviral treatment is expected to increase. Yet practical experience reveals...Full Text Available
The results of clinical trials conducted in Europe and North America have been incorporated into treatment strategies for breast cancer in Japan. Despite the use of similar treatment regimens, why has...Full Text Available
There has been a major interest in the drug treatment of osteoporosis and an increase in the number of drugs available in most countries. The ideal drug (one which increases or restores bone density...Full Text Available
This analysis, submitted in support of proposed effluent limitations guidelines and standards for the centralized waste treatment (CWT) industry, investigates the cost-effectiveness of 24 regulatory options, representing all possible combinations of nine ...
This article describes the processes for the treatment of plastic waste: sampling, sorting, comminution. The requirements for the different processes for waste treatment (as recycling, utilization as raw material, energy recovery, combustion) are listed. (SR)
Clinical features and treatment outcome were compared in depressed outpatients with and without a history of emotional and physical abuse (EPA), including childhood maltreatment. Patients were...Full Text Available
IntroductionApproximately 25–30% of breast cancers are assumed to be HER-2/neu positive. It is well known that HER-2/neu-positive cancers after treatment with trastuzumab...Full Text Available
This article outlines research and progress into the liquefaction of coal by solvent treatment, being conducted at the National Research Institute for Pollution and Resources, Japan. (In Japanese)
IntroductionThe goal of this study was to identify serum markers that are modulated by treatment with golimumab with or without methotrexate (MTX) and are associated with clinical...Full Text Available
Purposes1. To determine the optimal pelvic nodal clinical target volume for post-operative treatment of endometrial cancer. 2. To compare the DVH of different treatment planning...Full Text Available
Despite being free of charge, treatment adherence to 7-day primaquine for the radical cure of Plasmodium vivax was estimated at 62.2% among patients along the Iquitos-Nauta road in...Full Text Available
Oncolytic viruses (OVs) represent a relatively novel anti-cancer modality. Like other new cancer treatments, effective OV therapy will likely require combination with conventional treatments. In order...Full Text Available
BACKGROUND AND OBJECTIVE:For treatment of benign prostatic hyperplasia (BPH), Plasma Kinetic loop Resection of the Prostate (PKRP) is an alternative to conventional monopolar...Full Text Available
Selective phosphodiesterase type 5 inhibitors (PDE5Is) have revolutionized the treatment of erectile dysfunction (ED) in men. As an on-demand treatment, PDE5Is have excellent efficacy and safety in...Full Text Available
OBJECTIVES: Although the tricyclic antidepressant amitriptyline is extensively used in the prophylactic treatment of chronic tension-type headache, only few studies have investigated the efficacy of...Full Text Available
Fuel treatments are being widely implemented on public and private lands across the western U.S. While scientists and managers have an understanding of how ... ...
Erectile dysfunction (ED) affects up to 50% of men between the ages of 40 and 70. Treatment with PDE-5 inhibitors is effective in the majority of men with ED. However, PDE-5 inhibitors are not effective...Full Text Available
BackgroundThere are various treatment options for congenital melanocytic nevus (CMN), including surgical excision, dermabrasions, curettage, laser treatment, chemical peels and cryosurgery....Full Text Available
Lupus pernio of the nose is the most characteristic cutaneous lesion of sarcoidosis. It is cosmetically disfiguring and can be the cause of significant morbidity. In particular, the affected skin is often red or purple due to increased vasculature. It is particularly resistant to both surgical and medical therapy. We describe a patient with lupus pernio affecting her nose, which showed a dramatic improvement following treatment with the pulse dye laser (PDL). A biopsy taken after treatment showed the continued presence of sarcoidal granulomas. We therefore feel that treatment with the PDL is an effective tool in improving the cosmetic appearance of lupus pernio, but does not influence the underlying disease process. PMID:11360426
The incidence of hepatocellular carcinoma (HCC) is increasing in developed countries and the general status of HCC patients is now by far better than a few years ago, allowing physicians to propose some different treatments of these patients. Among these treatments, intra-arterial injection of 131-iodine-labelled Lipiodol could be used in palliative, curative or adjuvant settings. After a brief summary of the modalities of this treatment, requiring the collaboration of Gastro-enterologists, Oncologists, Radiologists and Nuclear Medicine physicians, the different possibilities of therapeutic uses of this new approach are described and an outlook of these developments is proposed. (author)
... Treatment of electrical systems for pumped storage plants is not covered in the manual, although much of the information is applicable to pumped ...
This paper describes a system for biogas conversion to electric power and heat by using a micro turbine and three Otto cycle engines. The benefit of the energy from a treatment process residue aims the improvement of the global performance of the system, reducing the the emission of the greenhouse gases and contributing to the global energetic efficiency of the sewage treatment station and the basic sanitation in Brazil.
Prostate cancer can be successfully treated using dynamic adaptive external beam radiation techniques along with interstitial brachytherapy to deliver curative therapies with low urinary, rectal and erectile function morbidity. Through the use of sophisticated, state-of-the art radiographic imaging for staging and treatment planning, a precise, individual design for treatment is accomplished. Symptom management and patient education are of paramount importance and are integrated throughout the treatment process.
Clinical questionWhat is the best treatment for bacterial conjunctivitis?ResultsTopical antibiotics expedite recovery from bacterial conjunctivitis....Full Text Available
The method of treatment of uteral cancer by the brake irradiation of 25 MeV betatrone using original devices which promote forming therapeutic figured bunches is presented. The binding of the protective blocks with a special adjusting frame within the aperture of the diaphragm provided for low relative entering dose which is the advantage of high energy irradiation bunch. The use of the forming devices makes it possible to practice individual treatment and decrease the levels of irradiation doses for intact organs and tissues.
Methylene chloride is an organic solvent with many industrial uses. Inhalation of methylene chloride fumes can result in toxicity, caused by hepatic biotransformation of methylene chloride to carbon monoxide. A case of acute methylene chloride poisoning is presented, including successful treatment of this patient with the use of hyperbaric oxygenation. The rationale for the use of hyperbaric oxygenation in the treatment of methylene chloride poisoning is discussed. (aw)
The concept of unstable burst fracture has been discussed since over 50 years and this injury has received much attention in the literature as regards its radiological diagnosis and clinical treatment. The purpose of this article is to review the way we use imaging to diagnose the injury and to guide treatment.
Radiation therapy has shown definite technical improvement due to application of proton beam irradiation. Clinical results of proton beam therapy also suggested enlargement of indication ranges in radial treatment and decrease of post radiation damages of the treatment of cancers in deep-seated organs. Inprovement of result in cancer therapy could be expected by this treatment technique in the future.
The main aim of sanitary pass-control regime is to prevent propagation of radioactive contamination outside the area of emergency-rescue works and guarantee of sanitary treatment of all persons having radioactive contamination. The paper has studied the questions of organization of sanitary pass-control regime, arrangement of sanitary treatment of the injured persons and rendering first aid in case of radioactive contamination of wounds. 5 refs.
Chemical oxidation is a treatment technology that uses powertul chemical oxidizers to destroy organic contaminants. Typical oxidizers used in chemical oxidation processes include ozone, hydrogen peroxide, chlorine, and potassium permanganate. The chemical reaction products are usually simple organic compounds, such as carboxylic acids, and/or inorganic compounds, such as carbon dioxide, water, and simple inorganic complexes (e.g., chloride salts, in the case of chemical oxidation treatment of chlorinated solvents).
In this article carbon co-implantation and step-by-step thermal treatments of shallow p"+-n-junctions formation were used with the purpose of extended defect suppression and reduction of boron transient enhanced diffusion. A substantial improvement of the structural and electrical parameters of shallow p"+-n-junctions has been achieved by using the additional carbon implantation and step-by-step thermal treatments. (authors)
This document presents the details of the implementation of the Site Treatment Plan developed by Ames Laboratory in compliance with the Federal Facilities Compliance Act. Topics discussed in this document include: implementation of the plan; milestones; annual updates to the plan; inclusion of new waste streams; modifications of the plan; funding considerations; low-level mixed waste treatment plan and schedules; and TRU mixed waste streams.
A method for the hydroconversion of coal by solvent treatment at elevated temperatures and pressure wherein an alcohol having an alpha -hydrogen atom, particularly a secondary alcohol such as isopropanol, is utilized as a hydrogen donor solvent. In a particular embodiment, a base capable of providing a catalytically effective amount of the corresponding alcoholate anion under the solvent treatment conditions is added to catalyze the alcohol-coal reaction.
The effect of heat treatment on the corrosion behavior of reactive plasma sprayed TiN coatings in simulated seawater was investigated by electrochemical methods such as the corrosion potential-time curve (Ecorr-t), potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and SEM, etc. The results showed that the corrosion potential of TiN coatings increased after heat treatment; the corrosion current of the TiN coatings after heat treatment (be hereafter referred to as HT-TiN) was 13.3% of the untreated coatings (be hereafter referred to as UT-TiN), and the polarization resistance of HT-TiN was 20 times of UT-TiN, which indicated that the heat treatment had significantly increased the corrosion resistance of the coatings. The corrosion behavior of the coatings was mainly ...
Pai ALH, Gray E, Kurivial K, Ross J, Schoborg D, Goebel J. The Allocation of Treatment Responsibility scale: A novel tool for assessing patient and caregiver management of pediatric medical treatment regimens. Pediatr Transplantation 2010: 14:993 999. 2010 John Wiley & Sons A/S. Abstract: The purpose of the current study is to report preliminary psychometric properties of the ATR scale, a brief measure of the distribution of treatment tasks across the family members of children with a kidney transplant. Pediatric patients with renal transplants (ages 7 18 yr) and their caregivers completed the ATR and measures of adherence and family functioning. Internal consistency for the ATR (total score and subscales) was strong (range = 0.75 0.93). Validity for the ATR was supported by significant co...
Using the infrared spectroscopy method, we have studied the effect of thermal dehydration (under vacuum and in air) and treatment with water vapor on the acid centers of very high silicon zeolites of the ZSM type. We have shown that dehydration under vacuum and in air completely and irreversibly removes the OH groups at 1120/sup 0/K, while treatment with water vapor removes these groups at 770/sup 0/K. The Lewis acid centers of dehydrated zeolites (represented by two types of centers) are more heat-stable than the Bronsted acid centers, but the vapor treatment at 1020/sup 0/K leads to the disappearance of the Lewis acid centers. In this work, we discuss the reasons for destruction of the acid centers of the zeolites under different treatment conditions.
A new method of plasma treatment for powder particles was investigated. A glass bottle horizontally held on a rotating system was used for the treatment. The outside of the bottle was covered by the grounded metal net, and the rod electrode was provided at the center of the bottle, which was connected to an ac high voltage source. Powder particles were placed in the bottle with stainless steel beads of large diameter and the plasma was generated between two electrodes and while the bottle was rotating. Using this system, powder particles were uniformly plasma-treated without coagulation. After 40 seconds treatment with plasma of 0.55 W in Ar gas, the charge to mass ratio for polyethylene powder particles having 160 {mu}m mean diameter generated by stainless before treatment. (author)
When biomass is used as fuel for thermal conversion plants, minerals from the fuel can be responsible for major problems. Generally, these problems are associated with the existence and development of low melting compounds or eutectics, which form sticky layers. In a fluidised bed, this can result in bed-agglomeration and defluidisation. This causes local high temperature, which often accelerates the process. It ultimately can lead to a completely sintered bed content with a glassy phase gluing the bed particles together and shut-down of the plant. The main objective of the title project is to develop a methodology to predict ash/bed agglomeration and sintering problems, to indicate related problems and, furthermore, to identify solution methods to make different types of biomass streams more viable for energy production. Within the present study, selected fuels are subjected to different existing methods together with some new ones, in order to determine the agglomeration temperature. ...
Full text: Tumour ablation with radiofrequency (RF) energy is a relatively new procedure for the treatment of focal malignant disease. At our institution this is currently being used in the treatment of certain liver and lung lesions with the patients involved being enrolled in clinical trials. The poster describes the technique used at our institution for the placement of the radiofrequency ablation electrode using CT fluoroscopy. Criteria for patient selection are included. Complications from the procedure are described, as well as follow up appearances and results. Our results from the treatment of primary and secondary lesions in the liver correlate well with published literature. Treatment is still not as successful as surgical resection but there is significantly less morbidity. Where this method may be appropriate is when the patient is not a candidate for surgical resection. The ...
This paper, firstly, introduces the background in developing a high quality water supply system, in which the drinking water system is isolated inside a building. Results of questionnaire on the high quality service water are illustrated. The results of questionnaire have revealed that the high quality service water is extremely interested. Then, are described the target quality of high quality water, the constitution of high quality water supply system, the treatment process, the measures to secure safety and sanitary, and the method of maintenance. The high quality water is produced through the activated charcoal absorption treatment, membrane treatment, ozonation, cooling, mineral addition, and disinfection of city water. Furthermore, application examples of this system adopted to a department store and a bachelor apartment house are introduced. For the high quality water supply system in the department store, the ...
The structural, morphological and optical properties of vacuum-evaporated CdTe thin films were investigated as a function of substrate temperature and post-deposition annealing without and with CdCl2/treatment at 400 C for 30 min. Diffraction patterns are almost the same exhibiting higher preferential orientation corresponding to (111) plane of the cubic phase. The intensity of the (111) peak increased with the CdCl2/annealing treatment. The microstructure observed for all films following the CdCl2/annealing treatment are granular, regardless of the as-deposited microstructure. The grain sizes are increased after the CdCl2/annealing treatment but now contain voids around the grain boundaries. The optical band gaps, Eg, were found to be 1.50, 1.50 and 1.48 eV for films deposited at 200 K and annealed without and with CdCl2/treatment at 400 C for 30 min respectively. A progressive ...
Accelerated oxidation treatment technology is introduced for use in the treatment of poor quality water by ozone injected from the bottom of a pressurized ozone contact tank. Under study as oxidation accelerating processes using ozone center about an ozone/hydrogen peroxide treatment, ozone/UV treatment, ozone/hydrogen peroxide/UV treatment, etc. As the result of testing, important respects in accelerated oxidation are learned, which are stated below. In the ozone-aided treatment, there are some substances, such as chromatic matters, that can be removed more rapidly when in direct contact with gaseous ozone. In this case, the concentration of remnant ozone poses an important problem. In relation to the amount of injected hydrogen peroxide, what is important is the ozone/hydrogen peroxide injection ratio relative to the substance that is to be removed. In the use ...
Studies of the effectiveness of operant, relaxation, cognitive, and multimodal behavioural approaches to the treatment of chronic benign pain other than headache were evaluated. In general, the quality of the studies was poor, and most investigations lacked appropriate and adequate control conditions, outcome measures, and/or follow-ups. While outcome reports for all four behavioural treatments have been mainly positive, few data were found which conclusively demonstrate that any of the approaches are effective or that they are the treatment of choice. The data do, however, imply that behavioural approaches may help patients lead more normal and productive lives. Specifically, the literature suggests that: (1) the operant method leads to increased activity levels and decreased pain and drug intake, (2) the relaxation approach results in decreased EMG levels and some pain reductions, (3) the cognitive techniques are ...
Purpose: The purpose of this course is to review the physical principles underlying design, clinical application and execution of interstitial and intracavitary implants in the classical low dose-rate (LDR) range. This year, the course will focus on quality assurance of sources, applicators and treatment planning software. In addition, development of procedures and QA checks designed optimize treatment delivery accuracy and patient safety during each individual procedure will be reviewed. The level of presentation will be designed to accommodate both physicists and physicians. Implementation of recently published AAPM Task Group reports (no. 40, 'Comprehensive Quality Assurance' and No. 43, 'Dosimetry of Interstitial Brachytherapy Sources') will be reviewed. Outline: (A) General Principles (1) QA endpoints: temporal accuracy, positional accuracy, dose delivery accuracy, and safety of the patient, personnel, and the institution (2) QA procedure ...
The aim of this retrospective analysis was to evaluate feasibility and effectiveness of definitive chemoradiotherapy without split-course technique in anal cancer patients. From 1993 to 2003, 81 patients were treated; 13 were excluded due to various chemotherapeutic regimes, thus 68 patients were analysed. In case of acute grade 3 toxicities, treatment was halted until improvement or resolution independent of dose. Short interruption was defined as completing treatment without exceeding eight cumulative treatment days beyond scheduled plan, other patients were considered to have had prolonged interruption. Median follow-up was 46 months. Median overall treatment time was 53 days corresponding to an interruption of eight cumulative treatment days. Thirty-five patients (51%) had treatment interruption of <8 days. No acute grade 4 toxicities were observed; ...
Reclaimed Energy Company, Inc., Connersville, IN, receives waste generated from a wide variety of industrial applications which include paint, printing and degreasing companies. The wastes are stored in separate tanks and then distilled in batches (pot distillation). The recovered solvents can be returned to the originator. The residue, left after the solvents are distilled, is disposed of using an environmentally safe, economical procedure. The company worked with an engineering and fabrication firm to develop a continuous processing system that employs a mechanically agitated thin-film evaporator to distill the solvents. Successful performance of the evaporator was ensured by processing samples of solvents through the evaporator manufacturer's pilot plant facilities before the full-sized system was designed. Reclaimed Energy Company, Inc., has realized a number of advantages by going from pot distillation to the agitated thin-film evaporator system to distill solvents. ...
An approach of acidification was examined on formation of hydrogen-producing granules and biofilms in upflow column-shaped reactors. The reactors were fed with synthetic glucose wastewater and operated at 37 C and pH 5.5. The acclimated anaerobic culture was inoculated in four reactors designated R1, R2, R3 and R4, with R3 and R4 filled with granular activated carbon as support medium. To unveil the roles of acidification, microbial culture in R2 and R3 was subject to an acid incubation for 24 h by shifting the culture pH from 5.5 to 2.0. The experimental results suggested that the acidification substantially accelerated microbial granulation, but not biofilm formation. Microbial activities were inhibited by the acid incubation for about 78 h, resulting in the retarded formation of biofilms of the acidified culture. Reducing culture pH resulted in improvement in cell surface physicochemical properties favoring microbial adhesion and immobilization. Zeta potential ...
The economic feasibility of using granular activated carbon (GAC) to remove organic contaminants from industrial and municipal wastewater is contingent upon its reuse during multiple adsorption-regeneration cycles. The most common process for the regeneration of GAC is the thermal method. Drawbacks associated with thermal regeneration include a 5--10% loss of carbon due to oxidation and attrition, a decrease in adsorption capacity, and high energy costs. The purpose of this study was to investigate the regeneration of GAC using hydrothermal technology. Phenol contaminated and non-contaminated GAC samples were regenerated using supercritical water (411 deg C and 26.2 MPa) with dissolved oxygen concentrations of 0 mg/L, 5 mg/L, and 100 mg/L. For comparative purposes, GAC was regenerated using subcritical water (300 deg C and 12.4 MPa) with a dissolved oxygen concentration of 5 mg/L. Regenerated GAC samples were evaluated in terms of adsorption capacity, BET surface ...
Carbonyl compounds constitute an important reactive class of non methane volatile organic compounds. They can be emitted directly to the atmosphere from primary sources such as combustion engines, landfills and wastewater surfaces or as secondary products by the photochemical oxidation of hydrocarbons and other volatile organic compounds 1-3. Carbonyls photo-oxidize during the day to produce toxic radicals such as OH, HO_2, RO and RO_2. These species react with nitrogen oxides (NOx) and other VOCs present in the atmosphere to form tropospheric ozone (O_3); a highly reactive oxidizing agent that is harmful to human health, agricultural products and climate 4, 5. Hence identifying the levels and sources of ozone precursors such as low carbonyls, carbon monoxide (CO) and NOx derivatives, and understanding their physical and chemical transformation in the troposphere is an important task due to their atmospheric and adverse health implications. Diurnal variations of ...
The Department of Energy (DOE) Subsurface Contamination Focus Area (SCFA) sponsored a technology demonstration of non-traditional in situ vitrification (NTISV) at Los Alamos National Laboratory (LANL). The project team for this demonstration included MSE Technology Applications, Inc., Geosafe Corporation, and LANL. The technology demonstration involved the performance of two large-scale test melts. The first, referred to as the ''cold'' test, was performed on a simulated absorption bed that contained surrogate contaminants. The cold test was conducted in April 1999. The second demonstration, referred to as the ''hot'' test, took place at LANL's Material Disposal Area (MDA) V in April 2000. The hot test was conducted on a portion of an absorption bed that received radionuclide and metal-contaminated wastewater from a laundry facility and a research laboratory from the mid-1940s to the ...
Sorption studies of cesium, strontium, and cobalt (Cs, Sr, and Co) on bentonite under various experimental conditions, such as contact time, pH, sorbent and sorbate concentration, and temperature, have been performed. The sorption data for all these metals have been interpreted in terms of Freundlich, Langmuir, and Dubinin-Radushkevich equations. Thermodynamics parameters, such as heat of sorption {Delta}H{degrees}, free energy change {Delta}G{degrees}, and entropy change {Delta}S{degrees}, for the sorption of these metals on bentonite have been calculated. The value of {Delta}H{degrees} shows that the sorption of Cs was exothermic, while the sorption of Sr and Co on bentonite were endothermic in nature. The value of {Delta}G{degrees} for their sorption was negative, showing the spontaneity of the process. The maximum loading capacity of Cs, Sr, and Co were 75.5, 22, and 27.5 meq, respectively, for 100 g of bentonite. The mean free energy E of Cs, Sr, and Co sorption on bentonite was ...
Biosorption is presented as an alternative choice to traditional physicochemical means for removing toxic metals from groundwater and wastewaters. Removal of lead (Pb) from solutions was studied using Escherichia coli (parental) and Vitreoscilla hemoglobin (VHb)-expressing E. coli (transformed) cells. Pb biosorption was increased in bacterial hemoglobin-expressing E. coli cells grown in Luria broth B containing different concentrations of Pb{sup 2+}. The maximum Pb{sup 2+} biosorption of transformed and parental cells was determined to be 612 and 370 {mu}g Pb/g biomass, respectively. The inhibitory effect of Pb{sup 2+} on the parental strain was determined at 10 ppm. However, in transformed cells, Pb{sup 2+} was lethal at 100 ppm. The optimum aeration required for the transformed cells was lower than that for the parental strain on a growth yield basis. A linear correlation was established between the biosorption and uptake amounts. The biosorption process was ...
Acidic constituents in crude oil are associated with the formation of stable emulsions during production and present a challenge for efficient oil recovery and processing. Acid molecules, including naphthenic acids and acidic sulfur in crude oil cause corrosion in refineries and pipelines. Naphthenic acids are also significant because of their surface activity and marginal water solubility, so that they may leach to wastewaters and cause adverse environmental effects. Acidic components of oil are not limited to carboxylic acids but also molecules that contain sulfur and nitrogen. As such, an improved understanding of the chemistry and physics of petroleum at the molecular level is needed in order to understand the range of problems associated with acidic oil components and to design better solutions. The applications of negative-ion electrospray ionization (ESI) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) for speciation of acidic oil ...
During cleanup of contaminated sites, Sandia National Laboratories, New Mexico (SNL/NM) frequently encounters soils with low-level radioactive contamination. The contamination is not uniformly distributed, but occurs within areas of clean soil. Because it is difficult to characterize heterogeneously contaminated soils in detail and to excavate such soils precisely using heavy equipment, it is common for large quantities of uncontaminated soil to be removed during excavation of contaminated sites. This practice results in the commingling and disposal of clean and contaminated material as low-level waste (LLW), or possibly low-level mixed waste (LLMW). Until recently, volume reduction of radioactively contaminated soil depended on manual screening and analysis of samples, which is a costly and impractical approach and does not uphold As Low As Reasonably Achievable (ALARA) principles. To reduce the amount of LLW and LLMW generated during the excavation process, SNL/NM is evaluating two ...
The turbulent history of legislature concerned with the waste-management industry and the amount of material on this subject as well as the significance of the material in its own right led to the decision to publish all legal regulations on waste in one volume. It includes above all the Waste Law, Regulations on Determination of Waste, Regulations on Determination of Residual Products, Technical Instructions for Waste, Regulations for Monitoring Waste and Residual Products, Regulations on Probition from the Use of Chlorofluorohydrocarbons and Halon, Regulations on Packaging and Regulations on Sewage Sludge. The introduction explains the development and the role of the Waste Law and its applicability, goals and principles: The concept of waste, avoidance of waste, avoidance of waste tourism, the general welfare of the public; regulations on waste management, governmental means of monitoring waste management: Obligations to dispose of waste, compulsory ...
This report is a summary of the Steam Generator Group Project progress for 1985. Statistical analyses are presented of data from nondestructive examination (NDE) round robin tests that were performed on the Surry generator in 1984. In the first round robin, teams acquired and analyzed their own data on a selected 10% subset of tubes. In the second round robin, analysts from each participating team analyzed identical sets of data which were provided to them by the Project. Results from several examinations utilizing advanced/alternate NDE technologies including alternate eddy current probes and techniques, ultrasonics, and profilometry are also reported. Criteria are listed for selecting tube specimens that will be removed from the generator. A sampling plan based on these criteria is detailed graphically in the report. The initial steps that have been taken to carry out the plan are described; tooling fabricated for the sample removals is discussed. Successful removal of three 9-tube ...
This report is a summary of the Steam Generator Group Project progress for 1985. Statistical analyses are presented of data from nondestructive examination (NDE) round robin tests that were performed on the Surry generator in 1984. In the first round robin, teams acquired and analyzed their own data on a selected 10% subset of tubes. In the second round robin, analysts from each participating team analyzed identical sets of data which were provided to them by the Project. Results from several examinations utilizing advanced/alternate NDE technologies including alternate eddy current probes and techniques, ultrasonics, and profilometry are also reported. Criteria are listed for selecting tube specimens that will be removed from the generator. A sampling plan based on these criteria is detailed graphically in the report. The initial steps that have been taken to carry out the plan are described; tooling fabricated for the sample removals is discussed. Successful removal of three 9-tube ...
The Production of crushed sand in 1996 reached 8% of the total fine aggregates which was more or less 1% in 1994. This research concentrated to develop the up-to-data and economical system for producing crushed sand. To do this, the efficiency survey has been carried out for crusher, classifiers and dewatering devices. From the survey, it was known that rock on rock type V.S.I., and Hydrocyclone type sand unit are the most efficient crusher and classifier which are taking over 50% of the present market According to the quality evaluation, 33.4% was satisfied KSF 2558 standard in finish modulus (F.M) and size distribution and 66.6% appeared under the standard. In pilot test of crushed sand for better quality, the recovery of 56.9-57.9% could be achieved which had been only 55% as of now. And the finish modulus could be increased up to 2.86-3.23 which was 2.60-3.59 before. Accordingly, finish modulus of bellow 3.1 can be achieved when the wet type and appropriate system to the ...
Radioactive waste has been stored in large underground storage tanks at the Hanford Site since 1944. Approximately 212 million liters of waste containing approximately 240,000 metric tons of processed chemicals and 177 mega-curies of radionuclides are now stored in 177 tanks. These caustic wastes are in the form of liquids, slurries, saltcakes, and sludge. In 1991, the Tank Waste Remediation System (TWRS) Program was established to manage, retrieve, treat, immobilize, and dispose of these wastes in a safe, environmentally sound, and cost-effective manner. The Department of Energy (DOE) has believes that it is feasible to privatize portions of the TWRS Program. Under the privatization strategy embodied in the Request for Proposal (RFP), DOE will purchase services from a contractor-owned, contractor-operated facility under a fixed-price contract. Phase I of the TWRS privatization strategy is a proof-of-concept/commercial demonstration-scale effort. The objectives of ...
The germination and growth of Pinus radials Don. plantlets in solid residues deriving from a Kraft pulp industry was evaluated. Plant conditions were monitored by histological studies of roots and shoot-tips, as well as by plant analyses of several essential and non essential elements. The solids employed consisted of ashes, fly-ashes, dregs, grits, primary sludge, brown stock screening rejects and various mixtures of them. Their addition, in a range of combinations to sandy/metamorphic or marine terrace/clay soils, resulted in effective and sustained growth under greenhouse conditions. Low proportions of wastes favored growth in most cases, indicating that they may act as fertilisers. In some experiments, especially in those where waste was added in proportions ranging from 50% to 60%, germination and/or development were slightly affected. Two-year old field experiments have confirmed that in spite of the high pH values, Na ion content or elevated water retention ...
As part of our ongoing research to provide quality improvements to heating oil, Mobil Oil together with Santa Fuel, Inc., conducted a field trial to investigate the performance of a new premium heating oil. This premium heating oil contains an additive system designed to minimize sludge related problems in the fuel delivery system of residential home heating systems. The additive used was similar to others reported at this and earlier BNL conferences, but was further developed to enhance its performance in oil heat systems. The premium heating oil was bulk additized and delivered to a subset of the customer base. Fuel related, unscheduled service calls were monitored in this test area, as well as in a similar baseline area that did not receive the premium heating oil. Overall, the premium fuel provided a 45% reduction in the occurrence of fuel related, unscheduled service calls as compared to the baseline area. Within this population, there was a reduction of 38% ...
Since the first operation of nuclear steam generator early 1960s, its performance requirements have been met but the steam generator problems have been met but the steam generator problems have been major cause of reducing the operational reliability, plant safety and availability. U-tube assembly of steam generator forms the primary system pressure boundary of the plant and have experienced several types of tube degradation problems. Tube failure and leakage resulting from the degradation will cause radioactive contamination of secondary system by the primary coolant, and this may lead to unplanned plant outages and costly repair operations such as tube plugging or steam generator replacement. For the case of steam generators for heavy water reactors, e.g. Wolsong 2, 3, and 4 NPP, a high cost of heavy water will be imposed additionally. During the plant operation, steam generator tubes can potentially be subject to adverse environmental conditions which will cause damages to U-tube ...
In order to lower the costs for second generation bioethanol from lignocellulosic biomass anaerobic digestion of the effluent from ethanol fermentation was implemented using an upflow anaerobic sludge blanket (UASB) reactor system in a pilot-scale biorefinery plant. Both thermophilic (53 degrees C) and mesophilic (38 degrees C) operation of the UASB reactor was investigated. At an OLR of 3.5 kg-VS/(m(3) day) a methane yield of 340 L/kg-VS was achieved for thermophilic operation (53 degrees C) while 270 L/kg-VS was obtained under mesophilic conditions (38 degrees C). For loading rates higher than 5 kg-VS/(m(3) day) the methane yields were, however, higher under mesophilic conditions compared to thermophilic conditions. The conversion of dissolved organic matter (VS(diss)) was between 68% and 91%. The effluent from the ethanol fermentation showed no signs of toxicity to the anaerobic microorganisms. However, a high content of suspended matter reduced the degradation ...
Process solvent was hydrogenated in the brown coal liquefaction, to investigate the influence of it on the prethermal treatment and liquefaction. Consequently, it was found that the n-hexane soluble (HS) yield was improved. In this study, capacity of hydrogen transfer from solvent during prethermal treatment and effects of catalyst were investigated. Since prethermal treatment in oil was effective for improving the oil yield in the presence of hydrogen/catalyst or high hydrogen-donor solvent, influence of hydrogen-donor performance of solvent or addition of catalyst on the hydrogenation behavior of coal and the characteristics of products during prethermal treatment were investigated in relation to successive liquefaction results. As a result, it was found that the increase of HS yield was due to the acceleration of conversion of THF-insoluble using high hydrogen-donor solvent and/or by adding catalyst. ...
Simultaneous nitriding and ageing heat treatments of precipitation hardenable tool steel was carried out inside a DC-pulsed plasma nitriding reactor. A single heat treatment cycle was done, as the plasma nitriding and age hardening processes occur approximately at the same ranges of temperatures and times. Specimens of Cr-Ni-Mo-Al age hardenable steel, in the solubilized and solubilized and aged conditions, were tested. Plasma nitriding and ageing, carried out at 500 deg. C for times ranging between 2 and 8 h, increased the surface hardness up to 1000 HV, producing case depths between 100 and 200 {mu}m. The core hardness of solubilized samples increased from 30 to 39 Rockwell C after the plasma nitriding treatment proving the possibility of nitriding and ageing at the same treatment cycle. The pre-aged samples did not show any overageing after the simultaneous plasma nitriding and ageing ...
Simultaneous nitriding and ageing heat treatments of precipitation hardenable tool steel was carried out inside a DC-pulsed plasma nitriding reactor. A single heat treatment cycle was done, as the plasma nitriding and age hardening processes occur approximately at the same ranges of temperatures and times. Specimens of Cr-Ni-Mo-Al age hardenable steel, in the solubilized and solubilized and aged conditions, were tested. Plasma nitriding and ageing, carried out at 500 deg. C for times ranging between 2 and 8 h, increased the surface hardness up to 1000 HV, producing case depths between 100 and 200 #mu#m. The core hardness of solubilized samples increased from 30 to 39 Rockwell C after the plasma nitriding treatment proving the possibility of nitriding and ageing at the same treatment cycle. The pre-aged samples did not show any overageing after the simultaneous plasma nitriding and ageing ...
Dose reconstruction is a process that re-creates the treatment-time dose deposited in a patient provided there is knowledge of the delivered energy fluence and the patient's anatomy at the time of treatment. A method for reconstructing dose is presented. The process starts with delivery verification, in which the incident energy fluence from a treatment is computed using the exit detector signal and a transfer matrix to convert the detector signal to energy fluence. With the verified energy fluence and a CT image of the patient in the treatment position, the treatment-time dose distribution is computed using any model-based algorithm such as convolution/superposition or Monte Carlo. The accuracy of dose reconstruction and the ability of the process to reveal delivery errors are presented. Regarding accuracy, a reconstructed dose distribution was compared with a measured film ...
Near-ideal Schottky barrier contacts to n-type Al0.22Ga0.78N have been developed by a two-step surface treatment technique. Plasma etching of the AlxGa1-xN surface prior to Schottky metal deposition, combined with sequential chemical treatment of the etched surface, holds promise for developing high quality low-leakage Schottky contacts for low noise applications and for recessed gate high electron mobility transistors. In this work, the effect of postetch chemical treatment of the n-type Al0.22Ga0.78N surface on the performance of the Ni/Au based Schottky contact has been investigated. Three different types of chemical treatment: viz, reactive ion etching, reactive ion etching plus dipping in hot aqua regia, and reactive ion etching plus dipping in hot KOH, are studied. Detailed current-voltage studies of three different surface treated diodes and a comparison with as-deposited diodes reveal ...
In the wide range from brown coal to anthracite, an investigation was made of effects of heat treatment on physical/chemical properties and of coal rank dependence. For the experiment, 12 kinds of coal samples were used, and for heat treatment, the fluidized bed heated by the electric furnace and the infrared-ray gold image furnace were used. To examine characteristics of the heat-treated coal char, conducted were oxygen gasification, TPD measurement, XRD measurement, alkali metal measurement, and pore distribution measurement. The following were obtained from the experiment. The gasification reaction rate of the char heat-treated in the temperature range between 900{degree}C to 1700{degree}C decreases with a rise of the temperature of heat treatment, and the degree of decrease in the rate depends on coal rank. The order of gasification rate between coal ranks depends on the temperature of heat ...
The activated charcoal treatment in the field of the water treatment is applied to water supply, sewage, industrial water supply and industrial sewage, etc.. Its main treatment effects are (1) decolorization, (2) removal of odorous substance, (3) removal of organic material which is detected as COD or BOD, (4) removal of harmful substance, (5) removal of substance which could generate muddness and tarnish and (6) removal of organic material which affects the succeeding high degree treatment badly, etc.. Many actual application examples in the above fields have been reported. As the most recent topic, a big amount of the demand of activated charcoal is expected in the treatment of water supply. Chlorine which is used as disinfectant during the water purification process generates organic halogen compounds such as trihalomethane through the reaction with precursor such as humic acid. ...
The U.S. Department of Energy (DOE) Headquarters and associated contractors have developed an IBM PC-based software package that estimates costs, schedules, and public and occupational health risks for a range of mixed-waste management options. A key application of the software package is the comparison of various waste-treatment options documented in the draft Site Treatment Plans prepared in accordance with the requirements of the Federal Facility Compliance Act of 1992. This automated Systems Analysis Methodology consists of a user interface for configuring complexwide or site-specific waste-management options; calculational algorithms for cost, schedule and risk; and user-selected graphical or tabular output of results. The mixed-waste management activities modeled in the automated Systems Analysis Methodology include waste storage, characterization, handling, transportation, treatment, and disposal. Analyses of ...
The possibility of surface modification of high-speed steel cutting tool by means of vacuum-plasma treatment including ion nitriding in gas plasma followed by the deposition of wear resistant (Ti, Al)N coatings in metal-gas plasma of a vacuum arc discharge is studied. The regularities of nitrided layer formation and the structure of these layers under various operation conditions of cutting tool are investigated. Optimum conditions of vacuum-plasma treatment providing the best wear resistance of cutting are determined
Three samples of dusts generated by the non ferrous metallurgical industries are treated between 200 and 800 degree centigree in controlled oxidizing and reducing atmospheres. The objective of this study is to recover the valuable metals from these wastes. The treatments of these solids under oxidizing conditions at 700 degree centigree are well adapted for two samples. The totality of valuable elements are concentrated in the treatments residues. The use of hydrogen at 600 degree centigree, permits the removal of up to 100 % of valuable metals contained in the treated industrial wastes. The recovery rate of valuable metals (Pb, Zn, Cu) as well as the Global Decontamination Factor are reported. (Author) 9 refs.
Interferons, a group of cytokines with antiangiogenic, direct antitumour and immunostimulating properties, have shown significant activity against osteosarcoma in vitro and in xenograft models. They have also been used in osteosarcoma clinical trials as a single adjuvant to surgery, with an apparent increase in relapse-free survival. In the ongoing EURAMOS 1 clinical trial, interferon a-2b is evaluated as an adjuvant treatment in osteosarcoma. This article reviews the rationale for the use of interferon in cancer with special reference to the treatment of osteosarcoma, including all published data of clinical efficacy in this disease. Pediatr Blood Cancer 2010;54:350-354. Copyright 2009 Wiley-Liss, Inc.
Advances in the diagnosis of Ewing's sarcoma of the rib were considered and retrospective analysis of the treatment of 32 patients (76% of them were children at the age of 10-15 y.o.) in the clinic of children oncology was performed. It was shown that the diagnosis of Ewing's sarcoma of the rib in children ought to be combined taking into account the course, morphology and radiation examination techniques. Most optimum treatment consisted of combined therapy (cyclic polychemotherapy, lesion focus irradiation at the summary focus dose of 57 Gy, surgery with subsequent polychemotherapy for not less than 1.5 years
Brachytherapy is a radiotherapeutic modality that makes use of radionuclides to deliver a high radiation dose to a well-defined volume while sparing surrounding healthy structures. At the National Institute for Cancer Research of Genova a High Dose Rate remote afterloading system provides Ir(192) endocavitary brachytherapy treatments. We studied the possibility to use the Geant4 Monte Carlo simulation toolkit in brachytherapy for calculation of complex physical parameters, not directly available by experiment al measurements, used in treatment planning dose deposition models.
These Appendices describe various technologies that may be applicable to the Mixed Waste Treatment Plant (MWTP) Chemical/Physical Treatment System (CPTS). These technologies were identified by the CPTS Technical Support Group (TSG) as potentially applicable to a variety of separation, volume reduction, and decontamination requirements. The purpose was to identify all available and developing technologies, and their characteristics, for subsequent evaluation for specific requirements identified for the CPTS. However, the technologies described herein are not necessarily all inclusive, nor are they necessarily all applicable.
As a consequence of the expanded use of long term hemodialysis and continuous ambulatory peritoneal dialysis (CAPD) treatments and extended life spans, complications of end-stage renal disease and dialysis treatments are being encountered with increasing frequency in these patients. Computed tomography can accurately depict many of the potential complications of end-stage renal disease on dialysis. This article presents the abdominal CT findings of 429 end-stage renal disease patients who are on either hemodialysis or continuous ambulatory peritoneal dialysis treatment.
For over 50 years, electron beams have been an important modality for providing an accurate dose of radiation to superficial cancers and disease and for limiting the dose to underlying normal tissues and structures. This review looks at many of the important contributions of physics and dosimetry to the development and utilization of electron beam therapy, including electron treatment machines, dose specification and calibration, dose measurement, electron transport calculations, treatment and treatment-planning tools, and clinical utilization, including special procedures. Also, future changes in the practice of electron therapy resulting from challenges to its utilization and from potential future technology are discussed. (review)
Acute agitation is a frequent reason for emergency psychiatric intervention. It is important to intervene early to avoid escalation of agitation to aggression. Reducing risk by using effective treatments will result in fewer instances of seclusion and restraint, and fewer injuries to staff and patients. This paper will first review the epidemiology of aggressive behavior and mental disorders, followed by a discussion of assessment and diagnostic considerations. The pathophysiology of safety risk is discussed within the context of the model of the "triune brain." Pharmacological treatment strategies for acute episodes of agitated behavior will be discussed in detail. This includes newer formulations of novel antipsychotics such as liquids and rapidly disintegrating tablets, as well as intramuscular preparations. PMID:15335224
The results of treatment of 134 cases of morphologically-verified localized Ewing's sarcoma were evaluated. A comparative analysis showed relapse-free survival to be significantly lower for radiation treatment (23 %) than for its combination with various cytostatic drugs. Two-year relapse-free survival rate was as high as 43 % in cases receiving sarcolysin or cyclophosphamide as adjuvants. This was matched by 47 % for adjuvant ardiamycin or carminomycin and 56 % for adriamycin plus cyclophosphamide and vincristine. Evaluation of long-term results of adjuvant chemotherapy showed sex, age and site involvement to be of certain prognostic value.
The CyberKnife Robotic Radiosurgery System (Accuracy Incorporated, Sunnyvale, CA, USA) is used worldwide to treat tumors and neurological disorders anywhere in the body with sub-millimetre beam delivery accuracy. Accuracy has developed a number of new technologies in recent years to enhance the treatment of cancer patients. Such new technologies include a fast Monte Carlo Dose Calculation algorithm, Sequential Optimization dose planning, the IrisTM Variable Aperture Collimator, an 800 MU/min Linear Accelerator, and Optimized Path Traversal. These technologies enable physicists and physicians to plan treatments quickly and easily and deliver them with unrivalled accuracy and precision
The automatic control system for brain tissue temperature is studied theoretically for brain hypothermia treatment. In order to realize a human-friendly control mechanism, an automatic temperature regulation system is constructed to simulate brain hypothermia treatment by introducing a fuzzy algorithm for possible characteristic changes in patients. The brain temperature model is successfully realized to follow the desired temperature course automatically. The model reference fuzzy control of brain temperature based on water-cooling blankets is verified for clinical application to brain hypothermia treatments through various kinds of simulation experiment.