The phlebotomine sand fly Lutzomyia longipalpis is the most important vector of American visceral leishmaniasis (AVL), the disseminated and most serious form of the disease in Central...Full Text Available
Banana (Musa acuminata Colla AAA) peel extracts obtained in this work had a high capacity to scavenge 2,2-diphenyl-1-picrylhydrazyl (DPPH) and 2,2prime-azino-bis(3-ethylbenzothiazoline)-6-sulfonic acid (ABTS+) free radicals, and they were also good lipid peroxidation inhibitors. Acetone:water extracts were considerably more effective (compared with methanol, ethanol, acetone, water, methanol:water or ethanol:water) at inhibiting the peroxidation of lipids in the b-carotene/linoleic acid system or scavenging free radicals. However, aqueous extracts had a high capacity to protect lipids from oxidation in the thiobarbituric acid reactive substances (TBARS) test, as well as in the b-carotene bleaching assay. In addition, acetone:water most efficiently extracted all extractable components (54+-...
A novel approach using reactive processing is explored that eliminates the labour-intensive separation of post-consumer polyolefin waste from the mixed plastics waste stream. The reactive compatibiliser BMI has been used to form a modified blend of PCPW with 40% improved tensile strength relative to the uncompatibilised control. Addition of 60 wt.-% magnesium hydroxide [Mg(OH)2] during reactive compatibilisation with BMI gave rise to an even more significant enhancement (up to 100%) of the tensile strength. BMI was also able to usefully enhance the properties of a composite based on calcium carbonate and the polyolefin waste.
Waste cooking oil can be recovered and processed into animal feed additives after purification. Unfortunately, the traditional purification processes are insufficient for the removal of the harmful compounds formed during frying, mainly about malondialdehyde and other 2-thiobarbituric acid reactive substances. In the present paper, firstly, a simple and reliable HPLC method was developed to measure the content of malondialdehyde in purified waste cooking oil. The detection limit and the standard recovery of the analysis method are 1.20x10-5gl-1 and 96.5-99.2%, respectively, which is accurate and valid enough for the detection of malondialdehyde in waste cooking oil. Furthermore, the removal of malondialdehyde and other 2-thiobarbituric acid reactive substances from waste cooking oil was in...
Abstract Superoxide dismutase (SOD) is ubiquitous in aerobic organisms and constitutes the first link in the enzyme scavenging system of reactive oxygen species. In the present study, species and organ diversity of SOD activity in a solution and in an in-gel assay system, as well as the effects of hydrogen peroxide (H2O2) on SOD activity, were investigated. In a solution assay system, SOD activity of jackfruit root, shoot, leaves, axes, and cotyledons, of maize embryos and endosperms, of mung bean leaves and seeds, of sacred lotus axes and cotyledons, and of rice and wheat leaves was increased by 1-15 mmol/L H2 O2. However, SOD activity in rice root and seeds, maize roots and leaves, mung bean roots and shoots, and wheat seeds was decreased by 1-15 mmol/L H2O2. The SOD activity of wheat ro...
Formation of oxidizing and reducing radicals was studied by pulse radiolysis of [Fe(CN)_6]"4"- - BrO_3"- - CN"- system in ethylene glycol - water solvent mixture. Oxidizing #centre dot#BrO_2 and BrO radicals formed by electron scavenging with #centre dot#BrO_2"- were identified and their reactions were investigated. The reaction of hydroxyl radicals with ethylene glycol leads to formation of reactive radicals with reducing properties and of compounds which reduce slowly in dark the ferricyanide formed in the reaction of #centre dot#BrO_2 radical with ferrocyanide. (author) 21 refs.; 7 figs.
The potential of waste seashells powder, as a new adsorbent for Brilliant Red HE-3B reactive dye removal from aqueous solutions, was examined by the batch technique. The Freundlich, Langmuir, and Dubinin-Radushkevich adsorption models were applied to describe the equilibrium sorption data and to determine the corresponding isotherm constants. The values of the thermodynamic parameters, ?G, ?H, and ?S, indicate that the sorption of reactive dye is a spontaneous and endothermic process. The kinetic data evaluated by pseudo-first order, pseudo-second order, and intraparticle diffusion kinetic models suggested that the sorption of reactive dye onto seashell is a complex process and both surface sorption and intraparticle diffusion contributes to the rate limiting step.
This project was conducted to evaluate novel approaches for removing radioactive strontium (Sr) and cesium (Cs) from the tank wastes. The bulk of the Sr removal research conducted as part of this project investigated adsorption of Sr onto a novel adsorbent known as iron-oxide-coated sand. The second major focus of the work was on the removal of cesium. Since the chemistries of strontium and cesium have little commonality, different materials (namely, cesium scavengers known as hexacyanoferrates, HCFs) were employed in these tests. This study bridged several scientific areas and yielded valuable knowledge for implementing new technological processes. The applicability of the results extends beyond the highly specialized application niches investigated experimentally to other issues of potential interest for EMSP programs (e.g., separation of chromium from a variety of wastes using IOCS, separation of Cs from neutral and ...
The aim of present study was to evaluate antioxidant property of Glycyrrhiza glabra root extracts using in vitro models. The dose-dependent aqueous and ethanolic extracts demonstrated the scavenging activity against nitric oxide (concentration that caused 50% inhibition of nitric oxide radicals [IC(50)]=72 and 62.1 microg/ml, respectively), superoxide (IC(50)=64.2 and 38.4 microg/ml, respectively), hydroxyl (IC(50)=81.9 and 63 microg/ml, respectively), DPPH (IC(50)=43.6 and 28.3 microg/ml, respectively) and ABTS(*+) (IC(50)=77.3 and 57.2 microg/ml, respectively) radicals. Further, both extracts showed strong reducing power and iron-chelating capacities. In the Fe(2+)/ascorbate system, both extracts were found to inhibit mitochondrial fraction lipid peroxidation. In copper-catalyzed human serum and low-density lipoprotein oxidation models, both extracts significantly (P<0.05) lengthened the lag phase along with a decline in the oxidation rate, conjugated dienes, ...
The utilization of wood-shaving bottom ash (WBA) for the removal of Red Reactive 141 (RR141), an azo reactive dye, was investigated. WBA/H(2)O and WBA/H(2)SO(4) were made by treating WBA with water and 0.1M H(2)SO(4), respectively, to increase adsorption capacity. Adsorption of RR141 from reactive dye solution (RDS) and reactive dye wastewater (RDW) by WBA/H(2)O and WBA/H(2)SO(4) involved the BET surface area and pore size diameter. Properties of adsorbents, effect of contact time, initial pH of solution, dissolved metals and elution studies indicated that the decolorisation mechanism involved both chemical adsorption and precipitation with calcium ions. In addition, the WBA/H(2)SO(4) surface might contain sulphate-cation complexes that were specific to enhancing dye adsorption from RDW. The adsorption isotherm had a best fit by the Freundlich model. Freundlich parameters showed that WBA/H(2)O used more ...
Potential of spent biomass of a cyanobacterium, Nostoc linckia HA 46, from a hydrogen bioreactor was studied for biosorption of a textile dye, reactive red 198. The waste biomass was immobilized in calcium alginate and used for biosorption of the dye from aqueous solution using response surface methodology (RSM). Kinetics of the dye in aqueous solution was studied in batch mode. Interactive effects of initial dye concentration (100-500mg/L), pH (2-6) and temperature (25-45^oC) on dye removal were examined using Box-Behnken design. Maximum adsorption capacity of the immobilized biomass was 93.5mg/g at pH 2.0, initial concentration of 100mg/L and 35^oC temperature, when 94% of the dye was removed. Fourier transform infrared (FT-IR) studies revealed that biosorption was mainly mediated by fun...
In order to develop modern two-stroke engines with low fuel consumption, respectively with low exhaust emissions, two alternative development areas -- the mixture formation and the scavenging system -- have been correlated. For a satisfying mixture formation without fuel losses by scavenging, the direct injection seems to be one of the best solution for the high speed two-stroke engine of the future. On the other hand the modern development of two-stroke scavenging systems shows a large field of application and improvement methods of cross and loop scavenging. Based on the specific optimization factors of the injection system, respectively of the scavenging system, the aim off this common work of the Universities of Pisa and Zwickau is to correlate both the optimization fields in an advantageous mixture formation process. The principal elements of this correlation are the design of ...
Porosity evolution at reactive interfaces is a key process that governs the evolution and performances of many engineered systems that have important applications in earth and environmental sciences. This is the case, for example, at the interface between cement structures and clays in deep geological nuclear waste disposals. Although in a different transport regime, similar questions arise for permeable reactive barriers used for biogeochemical remediation in surface environments. The COMEDIE project aims at investigating the coupling between transport, hydrodynamics and chemistry when significant variations of porosity occur. The present work focuses on a numerical benchmark used as a design exercise for the future COMEDIE-2D experiment. The use of reactive transport simulation tools like Hytec and Crunch provides predictions of the physico-chemical evolutions that are expected during the future ...
In situ treatment has been proposed as a remediation alternative for surface water and groundwater contaminated with uranium and nitrate as a result of former waste disposal practices in the S-3 Ponds. Interceptor trenches containing reactive media have been proposed to treat groundwater, and constructed wetlands and/or algal mats are potential alternatives for treating surface water. This report presents the results from testing of ten different reactive media, and combinations of media, that are candidates for use in the proposed interceptor trenches to remove uranium and nitrate from groundwater. It also presents the results of testing and evaluation of algal mats and wetlands for removing uranium and nitrate from surface water.
The extracts from kinnow peel, kinnow seeds, litchi pericarp, litchi seeds, grape seeds, and banana peel were screened for total phenolic content (TPC), trolox equivalent antioxidant capacity (TEAC), 1,1 diphenyl-2-picryl hydrazyl (DPPH) radical scavenging activity, as well as reducing power. Kinnow peel extract exhibited the highest reducing power, TEAC, and DPPH free radical scavenging activity, whereas, the phenolic content of 37.4 mg GAE/g-dw was highest for grape seed extract. Banana peel extract with a low TPC showed the lowest reducing power, TEAC as well as DPPH free radical scavenging activity among the fruit residue extracts examined in the present study. Correlation analysis between the reducing power and DPPH radical scavenging ability; reducing power and ABTS radical scavengin...
In early 2004, the U.S. Department of Energy (DOE) Richland and Fluor Hanford requested technical assistance from the DOE Headquarters EM-23 Technical Assistance Program to provide a team of technical experts to develop recommendations for mending the In Situ Redox Manipulation (ISRM) Barrier in the 100-D Area of the Hanford Site in Washington State. To accommodate this request, EM-23 provided support to convene a group of technical experts from industry, a national laboratory, and a DOE site to participate in a 2 1/2-day workshop with the objective of identifying and recommending options to enhance the performance of the 100-D Area reactive barrier and of a planned extension to the northeast. This report provides written documentation of the team's findings and recommendations. In 1995, a plume of dissolved hexavalent chromium [Cr(VI)], which resulted from operation of the D/DR Reactors at the Hanford site, was discovered along the Columbia River ...
Full text of publication follows: Large-scale problems such as nuclear waste disposal are increasingly recognized to be interconnected to small scale-mechanisms. Thus, synchrotron-based high-resolution analytical X-ray probes become important tools for exploring the micro-scale chemical reactivity of heterogeneous barrier materials used in nuclear waste repositories. In this study the layout of the micro-XAS beamline at the Swiss Light Source (SLS) will be presented. The beamline is optimized towards micro beam experiments ({approx}1 x 1 {mu}m{sup 2}) in the hard-X-ray regime (4 - {approx}22 keV) and allows to combine micro X-ray fluorescence (micro-XRF), micro X-ray absorption spectroscopy (micro- XAS), and micro X-ray diffraction (micro-XRD) investigations with radioactive samples. Furthermore, the potential of micro-XRF/XAS/XRD for acquiring spatially resolved molecular level information on the speciation and structural ...
Long term integrated in situ experiments are performed in the HADES underground research facility (Mol, Belgium) in order to study the coupled reactivity between the different components of an underground repository for vitrified high level radioactive waste (HLW): glass, compacted clay, and stainless steel containers, at 90 degrees C and under gamma irradiation. Studies pertaining to the behaviour of silicon, a major element released during glass alteration, are presented here. Data collected from the integrated experiment, from simplified tests, and from modelling are put together, giving complementary information. The integrated experiment is used to investigate overall reactivity, whereas diffusion experiments coupled with modelling focused on the precipitation of silica in clay media. In the integrated in situ experiment, a bentonite clay (FoCa7) mixed with 5 wt.% of powdered glass frit was put in contact with ...
Preshocking delays initiation of PBX-9404 and PBX-9501, relative to unshocked material. In PBX-9404 preshock experiments, a first shock of 2.3 GPa was followed 0.65 {mu}s later by a second shock of 5.6 GPa. In PBX-9501, a preshock of 2.8 GPa and 0.32 us duration was followed by an initiating shock of 6.0 GPA. Both PBX explosives show clear desensitization while the preshock persists. In PBX-9404, initiation of detonation occurs nearly as anticipated for the material, after coalescence of the preshock and main shock into a single wave. Multiple embedded magnetic gauges were used to measure the shock histories. Our data indicates a slightly longer run to detonation than expected, even though a single wave is initiating the material. A slight stress reduction at coalescence, as required by the shock dynamics, may be responsible for the overrun. A reactivewaste is clearly evident while the preshock persists. The long run to detonation indicates ...
Since the beginning of the large-scale technical manufacture of activated charcoal at the start of the century, this product has become increasingly important. Activated charcoal is a central part today of many chemical industrial processes. Furthermore, the purification of exhaust air and liquid wastes is often based on the adsorption by activated charcoal. The constantly increasing hygienic demands made of our drinking water may also often only be fulfilled by using activated charcoal. The highly developed adsorption technique of today is considerably supported by continuous improved quality of the products which can only be achieved by progress in manufacturing techniques. The large-scale use of activated charcoal has only become possible for a series of tasks by developing suitable reactivation methods. The last German-language monograph on activated charcoal appeared 18 years ago. The present work wishes to close this gap and in particular ...
Though central to our understanding of how roots perform their vital function of scavenging water and solutes from the soil, no direct genetic evidence currently exists to support the foundational model...Full Text Available
Red cell transfusions are associated with the development of acute lung injury in the critically ill. Recent evidence suggests that storage induced alterations of the red blood cell (RBC) collectively...Full Text Available
Exteriorized phosphatidylserine (PS) residues in apoptotic cells trigger rapid phagocytosis by macrophage scavenger receptor pathways. Mimicking apoptosis with liposomes containing PS may represent...Full Text Available
BackgroundTrichloroethylene (TCE) may induce oxidative stress which generates free radicals and alters antioxidants or oxygen-free radical scavenging enzymes.MethodsTwenty...Full Text Available
B lymphocytes can function independently as efficient APCs. However, our previous studies demonstrate that both dendritic cells and macrophages are necessary to propagate immune responses initiated...Full Text Available
Cd36 is a small-molecular-weight integral membrane protein expressed in a diverse, but select, range of cell types. It has an equally diverse range of ligands and physiological functions, which has...Full Text Available
Role of microelements in coal in connection with their combustion in power stations, gasification and hydrogenation is discussed from the standpoint of environmental pollution and effects on technological parameters. In the wastes from fossil-fuel power stations there are biogenic and toxic elements (Be, B, Pb, etc.) present, which eventually go into the soil. Analyses showed that coal from the Kuznetsk, Donetsk, Ehkibastuz and Kansk-Achinsk basins which are used for power, have a relatively low level of biogenic and toxic microelements, e.g. Ba, B, Mn, Pb, Co, Ni, V, Cu, Y. Coal reactivity in gasification and hydrogenation is discussed. The catalytic effect of several microelements in coal gasification and hydrogenation is established. A geochemical multiplicative indicator is presented which makes quantitative evaluation of the suitability of coals for hydrogenation possible. 17 references.
For the reuse of a waste salt from an electrorefining process of a spent oxide fuel, a separation of rare earth elements by an oxidative precipitation in a LiCl-KCl molten salt was tested without using precipitate agents. From the results obtained from the thermochemical calculations by HSC Chemistry software, the most stable rare earth compounds in the oxygen-used rare earth chlorides system were oxychlorides (EuOCl, NdOCl, PrOCl) and oxides (CeO{sub 2}, PrO{sub 2}), which coincide well with results of the Gibbs free energy of the reaction. In this study, similar to the thermochemical results, regardless of the sparging time and molten salt temperature, oxychlorides and oxides were formed as a precipitant by a reaction with oxygen. The structure of the rare earth precipitates was divided into two shapes: small cubic (oxide) and large plate-like (tetragonal) structures. The conversion efficiencies of the rare earth elements to their molten salt-insoluble ...
For the reuse of a waste salt from an electrorefining process of a spent oxide fuel, a separation of rare earth elements by an oxidative precipitation in a LiCl-KCl molten salt was tested without using precipitate agents. From the results obtained from the thermochemical calculations by HSC Chemistry software, the most stable rare earth compounds in the oxygen-used rare earth chlorides system were oxychlorides (EuOCl, NdOCl, PrOCl) and oxides (CeO2, PrO2), which coincide well with results of the Gibbs free energy of the reaction. In this study, similar to the thermochemical results, regardless of the sparging time and molten salt temperature, oxychlorides and oxides were formed as a precipitant by a reaction with oxygen. The structure of the rare earth precipitates was divided into two shapes: small cubic (oxide) and large plate-like (tetragonal) structures. The conversion efficiencies of the rare earth elements to their molten salt-insoluble precipitates were ...
Grout has been evaluated as a means of containing low-level radioactive waste for long-term disposal. Concerns about hydrogen and reactive gas generation in the Hanford Site grout disposal facility lead to the development of the G3 model, which has predicted buildup of radiolytically formed gases in the grout region and their migration to air-filled regions. The G3 model is a one-dimensional code that couples models of gas diffusion with two-phase gas and liquid flow. It was coupled to a compartment diffusion model and these models predicted the concentrations of hydrogen I nitrous oxide, and other gases in air-filled regions of the grout disposal facility. The results have served as the technical basis for safety studies. A unique finding of the G3 model was that a liquid return, or expulsion of unbound liquid from the grout region, could occur. This liquid return is driven by displacement caused by gas bubbles that form within the grout`s ...
The underground storage tanks at the Hanford Complex contain mixed wastes generated over many years from plutonium production and recovery processes. The chemical changes of the organic materials used in the extraction processes and disposed to the tanks have a direct bearing on several specific safety issues, including potential energy releases from these tanks. This paper will give details of a study that is directed towards elucidating thermal and radiological decomposition mechanisms and products of the organic contents of the tanks. The study is being conducted in two parts. The first part, an aging study, will determine kinetics and products of the degradation of a simulated waste subjected to #gamma#-radiation from an external source. Although the simulant will not contain radioactive elements, it will contain other representative inorganic compounds and the primary organic compounds thought to have been disposed to the tanks. The second ...
Acid mine drainage is a serious environmental problem caused by the oxidation of sulfide minerals that releases highly acidic, sulfate, and metals-rich drainage. In this study, alkaline industrial wastes were mixed with acid mine tailings in order to obtain neutral conditions. A series of column leaching tests were performed to evaluate the behavior of reactive mine tailings amended with alkaline-additions under dynamic conditions. Column tests were conducted of oxidized mine tailings combined with cement kiln dust, red mud bauxite, and mixtures of cement kiln dust with red mud bauxite. The pH results show the addition of 10% of alkaline materials permits the maintenance of near neutral conditions. In the presence of 10% alkaline material, the concentration of toxic metals such as Al, Cu, Fe, Zn are significantly reduced as well as the number of viable cells (Thiobacillus ferrooxidans) compared to control samples.
A fermentation waste, Corynebacterium glutamicum, was successfully employed as a biosorbent for Reactive Black 5 (RB5) from aqueous solution. This paper initially studied the effect of pretreatment on the biosorption capacity of C. glutamicum toward RB5, using several chemical agents, such as HCl, H{sub 2}SO{sub 4}, HNO{sub 3}, NaOH, Na{sub 2}CO{sub 3}, CaCl{sub 2} and NaCl. Among these reagents, 0.1 M HNO{sub 3} gave the maximum enhancement of the RB5 uptake, exhibiting 195 mg/g at pH 1 with an initial RB5 concentration of 500 mg/l. The solution pH and temperature were found to affect the biosorption capacity, and the biosorption isotherms derived at different pHs and temperatures revealed that a low pH (pH 1) and high temperature (35 deg. C) favored biosorption. The biosorption isotherm was well represented using three-parameter models (Redlich-Peterson and Sips) compared to two-parameter models (Langmuir and Freundlich models). As a result, ...
Reactive power plays an important role in supporting the real power transfer by maintaining voltage stability and system reliability. It is a critical element for a transmission operator to ensure the reliability of an electric system while minimizing the cost associated with it. The traditional objectives of reactive power dispatch are focused on the technical side of reactive support such as minimization of transmission losses. Reactive power cost compensation to a generator is based on the incurred cost of its reactive power contribution less the cost of its obligation to support the active power delivery. In this paper an efficient Particle Swarm Optimization (PSO) based reactive power optimization approach is presented. The optimal reactive power dispatch problem is a nonlinear optimization problem with several constraints. The ...
The Feynman-#alpha# method was applied to measurement of reactivity and the ability of this method for a real-time reactivity monitoring system was assessed. In the experiment, all measured data by BF_3 detectors were stored in a multi-channel scaler controlled by a personal computer, and they were analyzed to obtain prompt neutron decay constant (#alpha#) and reactivity with consideration of dead time of detector. It was found that #alpha# could be obtained almost in a real-time even for both positive and negative reactivities by the present experimental technique. (author).
The efficacy of gamma irradiation as a method of decontamination for food and herbal materials is well established. In the present study, Glycyrrhiza glabra roots were irradiated at doses 5, 10, 15, 20 and 25 kGy in a cobalt-60 irradiator. The irradiated and un-irradiated control samples were evaluated for phenolic contents, antimicrobial activities and DPPH scavenging properties. The result of the present study showed that radiation treatment up to 20 kGy does not affect the antifungal and antibacterial activity of the plant. While sample irradiated at 25 kGy does showed changes in the antibacterial activity against some selected pathogens. No significant differences in the phenolic contents were observed for control and samples irradiated at 5, 10 and 15 kGy radiation doses. However, phenolic contents increased in samples treated with 20 and 25 kGy doses. The DPPH scavenging activity significantly (p<0.05) increased in all irradiated ...
This book examines some of the basic principles behind chemical reaction kinetics. Topics considered include the classical trajectory approach to reactive scattering; periodic orbits and theory of reactive scattering; and semiclassical reactive scattering.
A solvent extraction method was developed to obtain methanolic extracts rich in antioxidants from banana peel. Central composite design ''2^3+star'' and response surface methodology were used in order to optimise the number of extraction steps, extraction temperature and extraction time. The number of extractions was statistically the most significant factor in scavenging activity against both DPPH? and ABTS?^+ radicals and in the inhibition of TBARS formation, while the extraction temperature had an important impact on the capacity to prevent b-carotene bleaching. However, the effect of the extraction time on antioxidant activity was less important. The optimum values of the factors that influence the capacity to scavenge DPPH? and ABTS?^+ radicals or to inhibit b-carotene bleaching were ...
Abstract Acid-treated cobia (Rachycentron canadum) skin was extracted in a retort (121C) to obtain retorted skin gelatin hydrolysates (RSGHs) containing antioxidant peptides with noticeable antioxidant properties. To improve the antioxidant activity of cobia RSGHs, five processing factors including alkali concentration, alkali pretreatment time, phosphoric acid concentration (PC), water/skin ratio (WS) and retorting time (RT) in RSGH production were screened using a fractional factorial design to identify critical factors. It indicated that PC, WS and RT had significant effects on ,-diphenyl--picrylhydrazyl (DPPH) scavenging by RSGHs. Subsequently, the optimization of PC, WS and RT on the DPPH scavenging of RSGHs was studied using a central composite design to collect data that resulted in...
Abstract Green tea extract showed false-negative results in the determination of glucose via glucose oxidase (GOD) test. This investigation was undertaken to verify and find out the precise mechanism underlying this interference by determining the reaction kinetics of production and reduction of end-point chromophore. The peroxidase step of the GOD test was found to be interfered and phenols of the green tea were the interfering compounds. Green tea interfered and exerted its influence in a dual fashion. A part of the interference was observed as a result of the reduction of the finally formed chromophore, whereas the other form of interference was due to its hydrogen peroxide/free radical-scavenging activity. Reducing potential and the free radical-scavenging activity of the phenols in th...
Three alternative extraction procedures were carried out in order to separate the antioxidant components and isolate an efficient extract from Origanum dictamnus. Procedure A included sequential extractions with petroleum ether (PE), diethyl ether (DE) and ethanol; procedure B sequential extractions with PE and ethyl acetate (EAc); procedure C a single step extraction with ethanol. The most efficient radical scavengers, according to the DPPH method, were isolated in ethanol extract of procedure A (mainly rosmarinic acid), followed by ethanol extract of procedure C. However, both ethanol extracts had low solubility in oil and could not protect it. EAc and DE extracts, containing mainly apigenin and epirosmanol ethyl ether, presented lower radical scavenging activity but were very effective ...
... of waste food generated at McMurdo Station. Some of the difficulties of disposing of waste food ... change waste generation or management at the site? Yes. This will be a temporary waste management ...
Coupled modeling of subsurface multiphase fluid and heat flow, solute transport and chemical reactions can be used for the assessment of acid mine drainage remediation, mineral deposition, waste disposal sites, hydrothermal convection, contaminant transport, and groundwater quality. Here they present a numerical simulation model, TOUGHREACT, which considers non-isothermal multi-component chemical transport in both liquid and gas phases. A wide range of subsurface thermo-physical-chemical processes is considered. The model can be applied to one-, two- or three-dimensional porous and fractured media with physical and chemical heterogeneity. The model can accommodate any number of chemical species present in liquid, gas and solid phases. A variety of equilibrium chemical reactions is considered, such as aqueous complexation, gas dissolution/exsolution, cation exchange, and surface complexation. Mineral dissolution/precipitation can proceed either subject to local ...
ObjectivesThe overall aim of the project is to understand whether natural Mn oxides can be used to remediate land contaminated with both metals and POPs. The major objectives are:~%~~%~1.Establishment of whether and how metals, POPs and SOM compete for reactive Mn oxide surface.~%~~%~2.Delineate the mechanisms of contaminant immobilisation and degradation.~%~~%~3.Identify the fate of the contaminants in Mn oxide treated soils.~%~~%~4.Measure positive and/or negative effects in the soil system of addition [continued...]DescriptionLand is a valuable but finite resource. The Environment Agency estimates that there are approximately 300,000 hectares of land in the UK affected to some extent by contamination left by industrial activity and worldwide, the extent of the problem is much greater as contaminated land is inextricably linked to poverty. In the UK, the increasing demand for new housing ...
Trying to achieve the optimal utilization of oil shale resources, and the production of a more environmentally acceptable fuel, as well as a solid waste with a low a sulphur content, thereby reducing acidic leachates, has led to this investigation. In this article, the influences of the bed temperature and the choice of fluidizing gas on the quality and quantity of the produced fuel gas, using a continuous feed fluidized bed reactor, were investigated. The composition and calorific value of the generated gas were determined. There was a nearly linear increase in the amount of fuel gas produced as a function of temperature, reaching {approx}350 kg per 10{sup 3} kg of dry raw shale and the gross calorific value ranged from 15 to 23 MJ-kg{sup -1} with CO and H{sub 2} being the major constituents. Subsequent experiments were carried out, employing a thermogravimetric analyser under similar conditions as applied to the fluidized bed reactor. Gasification of the ...
The mechanism for afterglow suppression in codoped CsI:Tl,Eu reported in the preceding paper was investigated by combined radioluminescence and thermoluminescence experiments. Model rate equations informed by these experiments were employed to simulate afterglow. It was found that codoping with europium introduces deep electron traps, with room-temperature glow peaks, that effectively scavenge the electrons from shallow traps associated with thallium, thus suppressing afterglow in the time domain of tens of milliseconds.
Effects of gamma irradiation on the physiological effectiveness of Korean medicinal herbs were investigated. The physiological effectiveness including antioxidant and anticomplement function, nitrite scavenging and electron donating ability of Korean medicinal herbs by gamma irradiation at 10 kGy did not differ from that of the nonirradiated control.
This paper reports Palladium alloy compositions investigated for suitability as a nonreactive material for the processing of ceramic superconductors. Barium-based superconductors were tested on Pd-Au and Pd-Ag alloys for reactivity. Bismuth-based superconductors were tested on a Pd-Ag alloy. The least reactive was found to be 70% Pd-30% Ag for the barium-based high-temperature superconductors (HTSC), whereas 30% Pd-70% Ag was found to be least reactive for bismuth-based HTSC.
Overloaded transmission lines are only part of the problem. The ability of the network to carry power is also limited by the supply of reactive power and by frequency stability. Reactive power problems must be corrected in minutes, frequency stability problems in seconds. There is no way that market forces can handle these problems. Reactive power must be supplied to all long transmission and distribution lines to compensate for the loss of reactive volt-amperes - and resulting voltage drop - in the reactance along the line`s length. 7 figs.
The theory of a method of determination of reactivity from power spectral density measurements with /sup 252/Cf and the results of experiments with a critical assembly mockup of a liquid-metal fast breeder reactor (LMFBR) and with uranium (93.2 wt % /sup 235/U) metal cylinders and a sphere are presented. This method of reactivity determination has an advantage over existing methods in that it determines the reactivity only from properties of the reactor at the subcritical state of interest and thus does not require a calibration near delayed criticality. In these experiments, the reactivity was varied by changing the fissile loading or the amount of neutron absorber inserted; for the LMFBR mockup, the reactivity varied to approximately 75 dollars subcritical, and for the uranium metal assemblies to approximately 30 dollars subcritical. These experiments verified for the first time ...
A method to reduce the fuel composition heterogeneity effect on the core performance parameters has been studied for the DUPIC fuel which is made of spent pressurized water reactor (PWR) fuels by a dry refabrication process. This study focuses on the reactivity control method which uses either slightly enriched, depleted, or natural uranium to minimize the cost rise effect on the manufacturing of DUPIC fuel, when adjusting the excess reactivity control by slightly enriched and depleted uranium, reactivity control by natural uranium for high reactivity spent PWR fuels, and reactivity control by natural uranium for linear reactivity spent PWR fuels. The results of this study have shown that the reactivity control by slightly enriched and depleted uranium, all the spent PWR fuels can be utilized as the DUPIC fuel and the fraction of fresh ...
As part of studies into the siting of a deep repository for nuclear waste, Swedish Nuclear Fuel and Waste Management Company (SKB) has commissioned the Alternative Models Project (AMP). The AMP is a comparison of three alternative modeling approaches for geosphere performance assessment for a single hypothetical site. The hypothetical site, arbitrarily named Aberg is based on parameters from the Aespoe Hard Rock Laboratory in southern Sweden. The Aberg model domain, boundary conditions and canister locations are defined as a common reference case to facilitate comparisons between approaches. This report presents the results of a discrete fracture pathways analysis of the Aberg site, within the context of the SR 97 performance assessment exercise. The Aberg discrete fracture network (DFN) site model is based on consensus Aberg parameters related to the Aespoe HRL site. Discrete fracture pathways are identified from canister locations in a ...
A method is described for immobilizing or solidifying waste material, which includes blending the waste material with powdered metal and subjecting the mixture of waste material and powdered metal to high pressure. (author).
The theory of a method of determination of the reactivity from power spectral density measurements with /sup 252/Cf and the results of experiments with a critical assembly mock-up of a liquid-metal fast breeder reactor and with uranium (93.2 wt % /sup 235/U) metal cylinders and a sphere are presented. This method of reactivity determination has an advantage over existing methods in that it determines the reactivity only from properties of the reactor at the subcritical state of interest and thus does not require a calibration near delayed criticality. In these experiments the reactivity was varied by changing the fissile loading or the amount of neutron absorber inserted; for the LMFBR mock-up, the reactivity varied to approximately 75 dollars subcritical, and for the uranium metal assemblies, to approximately 30 dollars subcritical.
...Species - see CITES Trade of Dangerous Chemicals Transport and Environment U Urban Environment Use of natural resources V Volatile Organic Compounds W Waste Landfills Waste electrical and electronic equipment - see WEEE Waste incineration Waste legislation - reporting Waste management planning Waste oils Waste shipments Waste water - see Urban waste water Water Bathing Water Drinking water Floods Marine environment Urban waste water Water Framework Directive WEEE - Waste Electric and Electronic Equipment Wildlife ...
The purpose was to study the toxicity of drugs known to generate free radicals on isolated pancreatic islets. The accumulattion of "8"6Rb"+ by mouse pancreatic islets was measured in vitro. Exposing the islets to 6-hydroxydopamine, minhydrin, or phenazine methosulphate + NADH inhibited the Rb"+ uptake, whereas paraquat or acetylphenylhydrazine had no effect. This effect of 6-hydroxydopamine was prevented by either of the hydroxyl radical scavengers, sodium benzoate and mannitol, but not by the non-scavenger,urea; ninhydrin was partially protected against by mannitol but not by benzoate. Protection against 6-hydroxydopamine was also afforded by D-glucose but not by L-glucose or 3-O-methyl-D-glucose; none of the sugars protected against ninhydrin. In damaging islet beta-cells and in being protected against by D-glucose, 6-hydroxydopamine closely resembles the diabetogenic drug, alloxan. It is suggested that protection against alloxan may involve ...
The radiation reduction of bis(1-ethylimidazole)tartratoplatinum(II) (EITPt(II)) complexes in methanol-water solution have been examined. The yields of Pt(I) depend on the presence of O{sub 2} in solutions as well as the dose applied. The rate constants of e{sub s}{sup -} scavenging by EITPt(II) and cis(diammine-1,1-cyclobutanedicarboxylato) platinum(II) (CBDCAPt(II)) have been determined by pulse radiolysis to be equal to 5.4 x 10{sup 9} and 6.4 x 10{sup 9} M{sup -1} s{sup -1}, respectively. The efficiencies of e{sub t}{sup -} scavenging by EITPt(II) and the rate of e{sub t}{sup -} photobleaching have also been determined in LiCl : H{sub 2}O : CH{sub 3}OH and MgCl{sub 2} : H{sub 2}O : CH{sub 3}OH glasses, respectively. (author).
Sulfate attack of cement-based materials remains an important problem for the durability assessment of containers and disposal engineering barriers dedicated to the long-term storage of radioactive wastes since underground water which may reach these elements contains small quantities of sulfates (7-31 mmol/1). This work contributes to the study of sulfate-induced damage mechanisms, to their understanding and modelling. The experimental phases of this study aimed at the understanding of the different physico-chemical phenomena involved during an external sulfate attack at following their evolution and their impact on the transport and mechanical properties of the material. Leaching experiments in pure water and in a solution of sodium sulfate (with a sulfate content of 15 mmol/1), have been performed simultaneously on OPC paste (w/c 0,4)in order to allow a comparison of test results. The frequent analysis of the leachant has shown a consumption of sulfate ions by ...
The hippocampus is thought to coordinate memory consolidation by reactivating traces from behavioral experience when the brain is not actively processing new input. In fact, during slow-wave...Full Text Available
Charge-charge interactions dramatically influence the dissociation and proton transfer reactivity of large multiply protonated ions. In combination with tandem mass spectrometry, proton transfer...Full Text Available
Neuronal death is known to trigger reactive microgliosis. However, little is known regarding the manner by which microglia are activated by injured neurons and how microgliosis participates...Full Text Available
The reactive airways dysfunction syndrome (RADS), the reactive upper airways dysfunction syndrome (RUDS), the sick building syndrome (SBS), and the multiple chemical sensitivity syndrome (MCS) are overlapping...Full Text Available
... Optimisation of reactive dye removal by sequential electrocoagulation-flocculation... The removal of Reactive Black 5 dye in an aqueous solution by electrocoagulation (EC) as well... »Read more By M. Mohsen Nourouzi, T. G. Chuah, Thomas S....
Increased production of reactive oxygen species (ROS) in mitochondria underlies major systemic diseases, and this clinical problem stimulates a great scientific interest in the mechanism of ROS generation....Full Text Available
For better understanding and proper use of organic chemicals addition data are needed, including kinetic data on the scavenging reactions in actual cycles, data on ambient temperature stability and decomposition, sampling and analsyis information, data on effects in a case of fire, and more corrosion data. Use of these chemicals for layup of boilers and other equipment needs to be evaluated for each application. After a preliminary evaluation, such as outlined in this report, every new water treatment chemical should be evaluated in at least two month test in actual steam cycle. (orig.).
The reactions of native bovine catalase with superoxide and solvated electrons have been investigated using three different methods for generating these reducing substrates: [gamma]-radiolysis of oxygenated or deaerated buffer solutions in the presence of an OH radical scavenger; either xanthine or acetaldehyde with xanthine oxidase; and low-temperature (77 K) [gamma]-radiolysis of buffered ethylene glycol/water solutions with subsequent annealing of samples at 183 K. (Author).
Conduction-band electrons, formed by pulse radiolysis of Degussa P25 TiO_2 particles, have been monitored by time-resolved microwave conductivity and found to undergo equilibrium localization and eventual recombination at the particle surface. In the presence of isopropyl alcohol recombination is retarded due to surface hole scavenging. The particle bulk can then be pumped with mobile electrons, which survive for seconds.
The effect of UV radiation in the wavelength region 230 nm to 302 nm on the ability of an irradiated mammalian cell to reactivate UV-irradiated mammalian virus was tested. An action spectrum for radiation enhanced reactivation (RER) is presented. The shape of the action spectrum points to a combined nucleic acid-protein target for UV radiation effects on this cellular parameter. An analysis of the results of others involving the biochemical and photobiological events involved in RER does not allow us to distinguish which macromolecule is the major contributor to this effect. Studies involving an analogous phenomenon in bacteris (Weigle reactivation) imply that RER and WR amy involve similar mechanisms. (author).
The method of reactivity determination using noise analysis correlation measurements with /sup 252/Cf was used to determine the reactivity for subcritical 17.77-cm-dia uranium (93.2 wt percent /sup 235/U) metal cylinders with reactivities as low as 25 dollars. Far subcritical tests were performed with right circular cylinders of uranium metal for which the subcritical reactivity was known from other inverse kinetics and prompt neutron decay constant measurements.
Insect host/parasitoid interactions are co-evolved systems in which host defenses are balanced by parasitoid mechanisms to disable or hide from host immune effectors. Although there is a rich literature on these systems, parasitoid immune-disabling mechanisms have not been fully elucidated. Here we report on a newly discovered immune-disabling mechanism in the Pieris rapae/Pteromalus puparum host/parasitoid system. Because venom injections and parasitization suppresses host phagocytosis, we turned attention to the P. rapae scavenger receptor (Pr-SR), posing the hypothesis that P. puparum venom suppresses expression of the host Pr-SR gene. To test our hypothesis, we cloned a full-length cDNA of the Pr-SR. Multiple sequences alignment showed the deduced amino acid sequence of Pr-SR is similar to scavenger receptors of other lepidopterans. Bacterial and bead injections induced Pr-SR mRNA and protein expression, which peaked at 4h post-bead ...
This volume contains 5 appendices. Title listing are: technologies for recovery of transuranics; nondestructive assay of TRU contaminated wastes; miscellaneous waste characteristics; acceptance criteria for TRU waste; and TRU waste treatment technologies.
This Process Waste Assessment was conducted to evaluate the two largest hazardous waste streams generated on-site at Sandia National Laboratory (SNL)/California -- ``Other Inorganic Solid Waste`` and ``Empty Containers <30 Gallons.``
1 to the operator of a waste collective system by an agreement or contract. The conditions for the ...Fees of the waste collective system are subject to the supervision of the authority responsible for market surveillance. ...The operator of waste collection system collects wastes from producers and holder and transports these to a collection
The gasification reactivities of six typical Chinese anthracite chars with steam and CO{sub 2} at 0.02-0.1 MPa and 920-1050{sup o}C were investigated by using thermogravimetric analysis (TGA). The reactivities of anthracite chars during steam gasification were found to have a good correlation to the coal volatile matter contents. The higher the coal volatile matter content, the higher the reactivity. The difference in reactivities of anthracite chars during CO{sub 2} gasification seems to be more dependent on the catalytic effect of inherent minerals in anthracite. The results show that the greater the alkali index, the higher the reactivity. The reactivities of demineralized anthracite chars vary very little compared with those the undemineralized chars at higher temperatures, whereas the reactivities of demineralized chars from Jincheng ...
This report is a compilation of worksheets from the waste management units of Savannah River Plant. Information is presented on the following: Solid Waste Management Units having received hazardous waste or hazardous constituents with a known release to the environment; Solid Waste Management Units having received hazardous waste or hazardous constituents with no known release to the environment; Solid Waste Management Units having received no hazardous waste or hazardous constituents; Waste Management Units having received source; and special nuclear, or byproduct material only.
{sup 60}Co is produced as an activation product and is present in the low-level aqueous radioactive waste released from the La Hague plant. At present, the concentration in the sea (non filtered at 0.45 {mu}m) at the Goury site are close to or even below, the detection limit: 0.2 mBq.l{sup -1}. The {sup 60}Co speciation depends on the type of effluent considered: in the effluent A ('active'), the cobalt is in the form of a stable trivalent complex; in the effluent V (to be checked), the cobalt is in majority (50% of the activity release) in the form of particles (>0.45 {mu}m), and then in the form of two soluble species: ionic divalent (Co{sup 2+}) and some stable complexes. The evolution of the reprocessing techniques used does not affect the speciation. So, since the nuclear reprocessing plant started at the La Hague plant in 1966, the chemical species discharged in the sea shows time variation related to the evolution of the type of ...
The present emphasis on inherent safety for LMR designs has resulted in a need to represent the various reactivity feedback mechanisms as accurately as possible. The dominant negative reactivity feedback has been found to result from radial expansion of the core for most postulated ATWS events. For this reason, a more detailed model for calculating the reactivity feedback from radial core expansion has been recently developed for use with the SASSYS/SAS4A Code System. The purpose of this summary is to present an extension to the model so that it is more suitable for handling a core restraint design as used in FFTF, and to compare the SASSYS/SAS4A results using this model to the empirical correlation presently being used to account for radial core expansion reactivity feedback to FFTF.
In this study, Reactive Red, Remazol Blue, and Reactive Black B removal capacities of Synechocystis sp. and Phormidium sp. were investigated. The microorganisms were cultivated in 100ml BG 11 medium and incubated at 30^oC under continuous illumination (12.5wm^-^2 (2400lx)) for 20 days in plant growth chamber. Trials were carried out at pH 9.5 for Reactive Red, pH 8.5 for Remazol Blue and Reactive Black B removal in media without and with triacontanol (TRIA). Removal capacities of Synechocystis sp. and Phormidium sp. were found higher in media containing TRIA. So that, Synechocystis sp. and Phormidium sp. removed Reactive Red with 25.7% and 35.4%, Remazol Blue with 37.5% and 25.5%, and Reactive Black B with 29.2% and 28.3% yield at 25mgl^-^1 dye concentrations, respectively. There is no rep...
This report consists of a broad overview of activities at Los Alamos National Laboratory (LANL). The following topics are discussed: The growth of the waste management group; what we do today; the mission of the waste management group; the liquid waste treatment section; the radioactive liquid waste project office; the chemical waste section; the radioactive waste section; and the technical support section.
The paper deals with the disposal of radioactive waste and the plans for dealing with solid wastes of intermediate and low levels of activity, which are the responsibility of NIREX. NIREX is an executive body which co-ordinates the waste-disposal plans of the main radioactive waste producers. The disposal routes for the active wastes are described including the deep disposal of wastes containing material that will remain active for thousands of years. Requirements for deep burial are outlined with reference to the geology and hydrogeology of the site. Monitoring, maintenance and surveillance are mentioned for the protection of the public.
As the result of 15 years of research (50 staff years of effort) Argonne National Laboratory (ANL), through its involvement in fluidized-bed combustion, magnetohydrodynamics, and a variety of environmental programs, has produced extensive computational fluid dynamics (CFD) software and models to predict the multiphase hydrodynamic and reactive behavior of fluid-solids motions and interactions in complex fluidized-bed reactors (FBRS) and slurry systems. This has resulted in the FLUFIX, IRF, and SLUFIX computer programs. These programs are based on fluid-solids hydrodynamic models and can predict information important to the designer of atmospheric or pressurized bubbling and circulating FBR, fluid catalytic cracking (FCC) and slurry units to guarantee optimum efficiency with minimum release of pollutants into the environment. This latter issue will become of paramount importance with the enactment of the Clean Air Act Amendment (CAAA) of 1995. Solids motion is also ...
This is the first volume in a series of books to be published by Prentice Hall on Environmental and Intelligent Manufacturing Systems. The editors have assembled an interdisciplinary collection of authors from industry, government, and academia, that provide a broad range of expertise on robotics and remote systems. Readily accessible to practicing engineers, the book provides case studies and introduces new technology applicable to remote operations in unstructured and/or hazardous environments. Chapter 1 gives an overview of the US Environmental Protection Agency's efforts to apply robotic technology to assist in the operations at hazardous waste sites. The next chapter focuses on the theory and implementation of robust impedance control for robotic manipulators. Chapter 3 presents a discussion on the integration of failure tolerance into robotic systems. The next two chapters address the issue of sensory feedback and its indispensable role in remote and/or ...
Geologic sequestration represents a promising strategy for isolating CO{sub 2} waste streams from the atmosphere. Successful implementation of this approach hinges on our ability to predict the relative effectiveness of subsurface CO{sub 2} migration and sequestration as a function of key target-formation and cap-rock properties, which will enable us to identify optimal sites and evaluate their long-term isolation performance. Quantifying this functional relationship requires a modeling capability that explicitly couples multiphase flow and kinetically controlled geochemical processes. We have developed a unique computational package that meets these criteria, and used it to model CO{sub 2} injection at Statoil's North-Sea Sleipner facility, the world's first saline-aquifer storage site. The package integrates a state-of-the-art reactive transport simulator (NUFT) with supporting geochemical software and databases (SUPCRT92). ...
This document is a collection of spreadsheets detailing on a county by county basis the agricultural crop, agricultural wastes, municipal wastes, and industrial wastes of Virginia that are potential biomass energy sources.
This document is a collection of spreadsheets detailing in a county by county manner the agricultural crop, agricultural wastes, municipal wastes and industrial wastes in Florida that are potential biomass energy sources.
This document is a collection of spreadsheets detailing on a county by county basis the agricultural crop, agricultural wastes, municipal wastes and industrial wastes of Alabama that are potential biomass energy sources.
Waste Technology and Innovation Study Final Report ...Waste Technology and Innovation Study Final Report 21/18569/150554 ...Survey of waste and resource recovery related technology and innovation, including products and product uses
Reactive Magnetron Sputtering is a complex process and huge efforts are made addressing the understanding of its fundamental phenomena and the simulation of the deposition process by e.g. Particle in Cell/Monte Carlo (PIC/MC). One of the most uncertain parameters in this reactive sputtering process is the incorporation coefficient of the reactive gas in the growing layer, i.e. the real-time sticking coefficient during deposition. In this work, mass spectrometry is used to deliver more insights on this complex matter. Earlier, a method was developed to determine the incorporation coefficient of the reactive gas molecules in the growing metal film, using mass spectrometry combined with thin film analysis techniques (electron probe microanalysis and x-ray photoelectron spectroscopy). This method delivers a global, realistic incorporation coefficient which can be used in models for the ...
This revision of the APT Waste Management Plan details the waste management requirements and issues specific to the APT plant for design considerations, construction, and operation. The APT Waste Management Plan is by its nature a living document and will be reviewed at least annually and revised as required.
The scope of our problems with nuclear waste management is outlined. Present and future inventories of nuclear wastes are assessed for risk. A discussion of what is presently being done to solve waste management problems and what might be done in the future are presented. (DC)
Electronic waste or e-waste is one of the rapidly growing problems of the world. E-waste comprises of a multitude of components, some containing toxic substances that can have an adverse impact on human...Full Text Available
The purpose of the Hanford Waste Management Plan (HWMP) is to provide an integrated plan for the safe storage, interim management, and disposal of existing waste sites and current and future waste streams at the Hanford Site. The emphasis of this plan is, however, on the disposal of Hanford Site waste. The plans presented in the HWMP are consistent with the preferred alternative which is based on consideration of comments received from the public and agencies on the draft Hanford Defense Waste Environmental Impact Statement (HDW-EIS). Low-level waste was not included in the draft HDW-EIS whereas it is included in this plan. The preferred alternative includes disposal of double-shell tank waste, retrievably stored and newly generated TRU waste, one pre-1970 TRU solid waste site near the Columbia River ...
From out of the numerous technical alternatives the manual develops a waste management concept with emphasis on methods which can be coordinated for maximum ecological use and minimum economic costs. A clear-cut analysis of the present state of waste utilization and waste disposal in the Federal Republic of Germany (chapter 1) is followed by a detailed description of conventional and modern state-of-the-art waste utilization methods based on ecological evaluation criteria (chapter 3). An optimum waste utilization concept for defined quantities of wastes is derived from the ecological and economic comparison of waste utilization techniques given in chapter 3. Chapter 4 points out different variants of waste utilization and waste disposal methods and shows how to determine the optimum variant of the ...
The Waste Management Project manages and integrates (non-TWRS) waste management activities at the site. Activities include management of Hanford wastes as well as waste transferred to Hanford from other DOE, Department of Defense, or other facilities. This work includes handling, treatment, storage, and disposal of radioactive, nonradioactive, hazardous, and mixed solid and liquid wastes. Major Waste Management Projects are the Solid Waste Project, Liquid Effluents Project, and Analytical Services. Existing facilities (e.g., grout vaults and canyons) shall be evaluated for reuse for these purposes to the maximum extent possible.
Drastic changes in waste management procedures are expected from the German Municipal Waste Disposal Regulations which became effective on June 1, 1993. Waste disposal will be subject to certain restrictions which, e.g. demand that wastes must be pretreated and inerted before they are stored. These regulations favor thermal waste disposal methods such as the carbonization/combustion method which is planned for a commercial-scale plant in the city of Fuerth. (orig./BBR)
Sep 2, 2008 ... Abstract: This tutorial is intended to serve as a guide towards proper hazardous waste management. Knowing the regulations, different ...
For high-efficiency coal gasification, investigations were given on effect of coal chars with different conversion rates on coal gasification reactivity. In coal gasification, reactivity of char after pyrolysis governs the efficiency. The reference char conversion in CO2 gasification of coal (weight loss) changes linearly in the initial stage of the reaction, but the reactivity declines as the end point is approached. Char surface area is as large as 400 m{sup 2}/g in the initial stage with the conversion at 20%, but it decreases in the final stage. This phenomenon relates closely with changes in pore size and crystalline structure. Change in the Raman value R which shows incompleteness of char graphite structure and amorphous carbon ratio suggests that an active portion with high reactivity is oxidized preferentially, and a portion with low reactivity remains finally. Minerals in ...
One of inherent characteristics of CANDU reactor is positive void reactivity in contrast to other pressurized light water reactors. During the large break loss of coolant accident, power pulse will be occurred during short time of early phase of accident due to positive void reactivity. However the duration of this power pulse is short, energy due to power pulse would be accumulated in the cladding material and will affect the peak cladding temperature or number of failed fuel elements. Recently, Canadian Nuclear Safety Commission (CNSC) indicated that the amount of void reactivity might be larger than the assumed values in safety analysis and this indication was based on the experimental data from ZED-2 facility. Based on that, the estimation of uncertainties due to the void reactivity during LBLOCA is the most important issue for CANDU safety analysis. In this study, a framework of uncertainty ...
This request is submitted to seek interim approval to operate a Toxic Substances Control Act (TSCA) of 1976 chemical waste landfill for the disposal of polychlorinated biphenyl (PCB) waste. Operation of a chemical waste landfill for disposal of PCB waste ...
This Radioactive and Mixed Waste Management Plan for the Hazardous Waste Handling Facility at Lawrence Berkeley Laboratory is written to meet the requirements for an annual report of radioactive and mixed waste management activities outlined in DOE Order 5820.2A. Radioactive and mixed waste management activities during FY 1994 listed here include principal regulatory and environmental issues and the degree to which planned activities were accomplished.
Considering the fact that more than 40% of all household wastes are organic wastes composting could be an excellent relief and complement to other waste disposal methods (e.g. combustion or direct landfills). Provided the right conditions household wastes could be composted together with sewage sludges and manures. The paper discusses the legal aspects, quantitative evaluations, conveying systems, as well as the compost utilization and marketing aspects valid for the Federal Republic of Germany.
Implementation of a plan to charge waste management costs to the facility that generates such waste requires a long-term commitment and consistent administration. The benefit is that generators are provided the incentive to optimize waste management practices if the charges are appropriately applied. This paper summarizes (1) a plan to charge waste generators, (2) the administrative structure of the plan, (3) a comparison between the rate structure and changes in waste disposal operations, and (4) issues that have surfaced as the plan is implemented. 2 refs., 1 fig., 1 tab.
Following the executive summary, this document contains the following: (1) waste management facilities design objectives; (2) AVLIS production plant wastes; (3) waste management design criteria; (4) waste management plan description; and (5) waste management plan implementation. 17 figures, 18 tables.
Hydantoin (imidazolidine-2,4-dione) is a 2,4-diketotetrahydroimidazole discovered by Baeyer in 1861. Thiohydantoins and derivatives were prepared, having chemical properties similar to the corresponding carbonyl compounds. Some biological activities (antimicrobial, anticonvulsant, schistosomicidal) are attributed to the chemical reactivity and consequent affinity of hydantoinic rings towards biomacromolecules. Therefore, knowledge about the chemistry of hydantoins has increased enormously. In this review, we present important aspects such as reactivity of hydantoins, acidity of hydantoins, spectroscopy and crystallographic properties, and biological activities of hydantoin and its derivatives. (author)
Independent drilling contractors own all offshore drilling rigs, which they lease to oil and gas companies for use in their pursuit of their exploration and development plans. Oil and gas companies' demand for these rigs can vary quickly and dramatically in response to changes in the world market for oil and natural gas. As a result, drilling contractors often try to manage excess capacity by idling rigs (known in the industry as "stacking" a rig), reactivating them when demand recovers. This paper examines these decisions over the course of a price cycle in 1998-2000 to investigate the role of firm and rig heterogeneity in determining drillers' decisions about idling and reactivating capacity.
Division of Remote Handling and Robotics (DRHR) at Bhabha Atomic Research Centre (BARC) has been working on design and development of Reactivity Control Mechanisms for Nuclear Research Reactors (Dhruva, KAMINI and recently Critical Facility of Advanced Heavy Water Reactor (AHWR)) as well as Power Reactors in India (Pressurized Heavy Water Reactors of 220 MWe at Narora and recently India's first 540 MWe PHWR Unit -1 and 2 at Tarapur). This paper gives a brief account of evolution of reactivity control mechanisms for nuclear research and power reactors in India. (author)
Monthly sampling of slightly alkaline arsenic-rich stream in the Mokrsko gold deposit revealed seasonal variations in dissolved Zn, Cu, As and Mo. Concentrations of trace metal cations (Zn, Cu) increased as much as 330 and 178%, respectively, from minimum mean values at autumn to maximum mean values at spring. In contrast, concentrations of trace element oxyanions (As, Mo) revealed opposite seasonal pattern with increase to 189% (As) and 123% (Mo) during summer?autumn, indicating that in-stream biogeochemical process(es) played the main role in controlling the seasonal variations of these trace elements. The trace elements were mainly scavenged by low crystalline Mn oxyhydroxide and Fe oxyhydroxide (ferrihydrite). Results are consistent with sorption and coprecipitation processes controlli...
We quantified the resistance levels of transgenic rice plants, expressing Myxococcus xanthus protoporphyrinogen oxidase (PROTOX) in chloroplasts and mitochondria, to PROTOX inhibitors, acifluorfen, oxyfluorfen, carfentrazone-ethyl, and oxadiazon. We also determined whether active oxygen species-scavenging enzymes are involved in the resistance mechanism of transgenic rice. The transgenic rice line M4 was about >200-fold more resistant to oxyfluorfen than the wild-type (WT). M4 was also resistant to acifluorfen, carfentrazone-ethyl, and oxadiazon, but did not show multiple resistance to imazapyr and paraquat, which have different target sites. Acifluorfen, oxyfluorfen, carfentrazone-ethyl, and oxadiazon reduced the chlorophyll content in leaves of WT, but had minimal or no effect on M4. The...
Microgel-clay composite particles were prepared by one-step surfactant-free precipitation polymerization. Laponite nanoparticles present in the reaction mixture become encapsulated during the microgel formation process. Microgel-clay composites based on poly(N-vinylcaprolactam-co-acetoacetoxyethyl methacrylate) containing different amount of incorporated clay nanoparticles were synthesized. The clay content was varied from 2 wt% to 18 wt%. The extremely high incorporation efficiency of the clay nanoparticles into microgels was detected. The size of the hybrid microgels was decreased from 700 nm to 100 nm by increase of the clay concentration in the reaction mixture. Obtained hybrid microgels exhibit negative surface charge and excellent colloidal stability. Microgel-clay composite particle...
The degradation of irradiated human insulin in aqueous solutions was investigated in order to protect the protein against ionizing radiation. The influence of the drug concentration, excipients and irradiation temperature were studied.Aqueous solutions at pH 2 were irradiated by gamma rays or by accelerated electrons. Two different high-performance liquid chromatography (HPLC) methods were used: reverse-phase high-performance liquid chromatography (RP-HPLC)/UV and size exclusion liquid chromatography (SEC/UV) to investigate both the fragmentation and the formation of higher molecular weight proteins.In solution without excipients irradiated at ambient temperature at 10kGy, the loss of human insulin is almost complete. Addition of radio-protecting excipients (free radicals scavengers) and c...
The performance of the gaseous fuel supply and its influence on hydrocarbon (HC) emissions of dual-fuel engines have been investigated. A new design of manifold respirators with mixers is also presented in the paper. The design of the gaseous fuel supply system has a great influence on HC emissions in the dual-fuel engine at light load. The problem of scavenging is discussed and solved by using the manifold respirators in the dual-fuel engine. It performs the function of retarding the gaseous fuel entry timing from the moment of intake valve opening, and its delaying effects have been measured and tested. Experimental results show that the manifold respirator gives the best performance in reducing HC emissions compared with a common pipe mixer and a respirator with bo miser. In addition, the mixing effects are sensitive to the mixer configuration. (Author)
Using hydrogen at high pressures of up to 150 bar as an OH scavenger in aqueous MV"2"+ solutions (pH 1) it is possible to differentiate between two kinds of transient formed simultaneously by H-atom attack on methyl viologen. One of them is assigned to an H adduct on the N atom, MV"+H"+, with absorption bands identical to those of the radical cation, MV"+. The MV"+H"+ species deprotonates forming the long-lived radical cation, MV"+. The second type of transient produced is attributed to an H-adduct on the ring carbon, MV"2"+H, decaying by second-order kinetics. The formation of MV"+ by electron transfer from the propan-2-ol radical has been reinvestigated (pH 0 to 7); its absorption spectrum does not change in this pH range. Rate constants and molar extinction coefficients are presented. (U.K.).
ObjectivesTo assess the influence of epigallocatechin-3-gallate (EGCG) on the efficacy of ionizing radiation on prostate cancer cells because of the increased use of dietary interventions, especially by patients with prostate cancer. Radiotherapy is used to treat localized prostate cancer. Some people consume green tea (EGCG) as a chemopreventive agent against prostate cancer. Green tea can act as an antioxidant and induce superoxide dismutase enzymes, which could scavenge the free oxygen radicals generated by radiotherapy. MethodsProstate cancer cell line DU145 cells were treated with EGCG or radiotherapy, or both. Cell death was assessed using trypan blue cell counting, and apoptosis was confirmed by assessing poly (adenosine phosphate ribose) polymerase cleavage. The antioxidant potenti...
The function of selenium in an organism is mediated mostly by selenoproteins including glutathione peroxidase. Glutathione peroxidase is a potent anti-oxidative enzyme, scavenging a variety of peroxides. The green alga Scenedesmus quadricauda was used to investigate the relationship between the toxicity of selenium and the glutathione peroxidase activity. Selenium resistant strains SeIV and SeVI were synchronized and grown in high concentrations of Se (selenite or selenate). As a measure of selenium toxicity the EC50 values were determined. During growth of the untreated wild type, glutathione peroxidase activity increased slightly and then declined gradually until the end of the cell cycle. A similar pattern was observed in untreated resistant strains and when resistant strains were grown...
The antioxidant properties of magnolol and honokiol were evaluated in the experimental systems of reducing ONOO^- and ^1O"2, bleaching @b-carotene in linoleic acid (LH) emulsion, and trapping 2,2'-azinobis(3-ethylbenzothiazoline-6-sulfonate) cationic radical (ABTS^+?) and 2,2'-diphenyl-1-picrylhydrazyl radical (DPPH), and then were applied to inhibit the oxidation of DNA induced by Cu^2^+/glutathione (GSH) and 2,2'-azobis(2-amidinopropane hydrochloride) (AAPH). Magnolol and honokiol were active to reduce ONOO^- and ^1O"2. Honokiol showed a little higher activity to protect LH and to inhibit Cu^2^+/GSH-induced oxidation of DNA than magnolol. In addition, honokiol exhibited higher activities to trap ABTS^+? and DPPH than magnolol. In particular, honokiol trapped 2.5 radicals while magnolol o...
The physical and antioxidant properties of alginate biodegradable film incorporating white, red and extruded white ginseng extracts were investigated. No differences in moisture contents of all alginate film samples were noticeable (p>0.05) except those film samples incorporated without ginseng extract, which had the highest moisture content. The addition of ginseng extract to alginate film decreased tensile strength and elastic modulus (p<0.05) but increased the percent elongation at break. The presence of extracts did not significantly affect the water vapor permeability of the film samples. Alginate film containing extruded white ginseng extract at a barrel temperature of 130degreeC presented the highest (61.12%) free-radical scavenging activity against the 2,2-diphenyl-1-picryhydrazyl ...
Oxidative degradation of methylene blue (MB) by Co^2^+-HCO3^- system with H2O2 in aqueous solution was studied. Nearly complete decolorization of the dye was obtained in less than 50min in diluted NaHCO3 solution (25mM) in the presence of only 20mM Co^2^+ ions. Meanwhile, the conjugated structure and phenyl rings of the MB molecule were destroyed or even broken down into small organic acids and inorganic ions, as indicated by FT-IR spectra and ion-chromatography. Photoluminescence probing and radical scavenging technologies suggested that the reaction of MB degradation in this system mainly involved the generation and participation of hydroxyl radicals. Furthermore, by cyclovoltammetric measurements, the in situ formed different complexes between Co^2^+ and HCO3^- were observed at differen...
4-Methylcoumarins that possess two hydroxyl groups ortho to each other in the benzenoid ring have shown to have excellent antioxidant and radical-scavenging properties in different experimental models. Furthermore, they cannot be metabolized by the liver P450 monoxygenases and thus cannot form 3,4-coumarin epoxides, which are believed to be mutagenic. Herein, we present a study on the structure activity relationship of eight synthetic 4-methylcoumarins, carried out by employing a series of different chemical cell-free tests. These compounds were tested by means of three assays involving one redox reaction with the oxidant (DPPH assay, ABTS+ assay and FRAP). Other assays were employed to evaluate the antioxidant properties of the coumarins under investigation against NO, O2- and HClO, which...
Hospital wastes comprises approximately 80% domestic waste components, also known as non-risk waste and 20% hazardous or risk waste. The 20% of the hospital waste stream or the risk waste (also known as infectious, medical, clinical wastes) comprises components which could be potentially contaminated with infections, chemical or radioactive agents. Therefore, it should be handled and disposed of in such a manner as to minimize potential human exposure and cross-contamination. Hospital risk waste and be subdivided into seven general categories as follows: infections, anatomical/pathological, chemical, pharmaceutical, radioactive waste, sharps and pressurised containers. These waste categories are generated by many types of health care establishments, including hospitals, clinics, ...
Mitochondrial superoxide production is an important source of reactive oxygen species in cells, and may cause or contribute to ageing and the diseases of ageing. Seven major sites of superoxide...Full Text Available
IntroductionThe outbreak of cholera in Zimbabwe intensified interest in the control and prevention of cholera. While there is agreement that safe water, sanitation, and personal...Full Text Available
Abstract In this study, surfactant-modified zeolite (SMZ) was used to remove Remazol Brillant Blue R and Remazol Yellow reactive dyes from aqueous solutions. The influences of suspension pH, temperature, agitation rate, and the SMZ dosage on reactive dyes removal and adsorption capacity were investigated by conducting a series of batch adsorption experiments. The adsorption kinetics was tested for pseudo-first-order, pseudo-second order, intraparticle diffusion model, Elovich, and Bangham models, and rate constants of the kinetic models were calculated. Equilibrium isotherms for the adsorption of reactive dyes were analyzed by the Freundlich, Langmuir, Dubinin-Radushkevich, and Tempkin isotherm models. The Langmuir monolayer adsorption capacities of Remazol Brillant Blue R and Remazol Yell...
The lignin, one of the main by-products of the pulp industry, can be used to remove dyes from textile wastewaters. The potential of the lignin for Brilliant Red HE-3B reactive dye removal from aqueous solutions at pH=1.5 was examined by the batch technique as a function of dye concentration, solution temperature and contact time. The Freundlich, Langmuir, Dubinin-Radushkevich and Tempkin adsorption isotherms were used to describe the data of sorption equilibrium and to determine its corresponding isotherm constants. The thermodynamic parameters DG, DH and DS were also determined; the obtained values show that the sorption of reactive dye on lignin is a spontaneous, endothermic and entropy-driven process. The kinetic of reactive dye sorption was analyzed using the pseudo-first order and pse...
A complex modulated structure is described for reactive elements that have the capability of considerably more heat than organic explosives while generating a working fluid or gas. The explosive and method of fabricating same involves a plurality of very thin, stacked, multilayer structures, each composed of reactive components, such as aluminum, separated from a less reactive element, such as copper oxide, by a separator material, such as carbon. The separator material not only separates the reactive materials, but it reacts therewith when detonated to generate higher temperatures. The various layers of material, thickness of 10 to 10,000 angstroms, can be deposited by magnetron sputter deposition. The explosive detonates and combusts a high velocity generating a gas, such as CO, and high temperatures. 2 figs.
Metastable yttrium-oxide films are synthesized using reactive sputter deposition. The yttrium concentration of the as-deposited film is found to vary as a function of the sputter deposition rate. In addition to the synthesis of the cubic equilibrium phase...
1. A high degree of homology in the positions of tyrosine residues in glyceraldehyde 3-phosphate dehydrogenase from lobster and pig muscle, and from yeast, prompted an examination of the reactivity...Full Text Available
PurposeEarly detection of appendicitis has increased due to development of computed tomography and ultrasonography, yet we are frequently meeting complicated appendicitis, including...Full Text Available
The effects of antimalarials, chloroquine and quinacrine, on the generation of reactive oxygen species were examined both in polymorphonuclear leucocytes and in the xanthine-xanthine oxidase system....Full Text Available
Chemically reactive compounds in tissues can be monitored through their products of reaction with biomacromolecules. For the purpose of in vivo dose monitoring, hemoglobin (Hb) has been preferred to...Full Text Available
A predictive reactivity of Cp_2An(IV)Me_2 (with An = uranium [U], neptunium [Np] and plutonium [Pu]) with pyridine N-oxide has been studied at the theoretical level. The predictive reaction, which consists in the formation of a formaldehyde complex, begins after the initial formation of a cyclo-metalated complex produced by a C-H activation of the pyridine N-oxide. A difference of reactivity between U/Pu and Np has been observed and has been attributed to the presence of a more covalent bond between Np and the carbene group in the transition state of formation of a transient carbene intermediate. (authors)
Some comments are given on the recycling of waste, mainly plastics, as evaluated from the viewpoint of energy environment. Discussed about the waste in general are the definition and classification, generation and resource recovery rates, current state of recycling, problems about recycling, related legislation, and current conditions overseas. Discussed about the treatment and recycling of plastics waste are the characters and use of plastic product, current state of waste plastics treatment, current state of waste plastics recycling (material recycling, thermal recycling), energy recovery by thermal recycling, quantity recyclable from waste plastics, energy consumption and cost for waste plastics recycling, effect and impact of increase in waste plastics in case material recycling is forwarded, and prospect of ...
The Hanford Waste Vitrification Plant Project has been established to convert the high-level radioactive waste associated with nuclear defense production at the Hanford Site into a waste form suitable for disposal in a deep geologic repository. The Hanford Waste Vitrification Plant will mix processed radioactive waste with borosilicate material, then heat the mixture to its melting point (vitrification) to forin a glass-like substance that traps the radionuclides in the glass matrix upon cooling. The Hanford Waste Vitrification Plant Quality Assurance Program has been established to support the mission of the Hanford Waste Vitrification Plant. This Quality Assurance Program Description has been written to document the Hanford Waste Vitrification Plant Quality Assurance Program.
The turbulent history of legislature concerned with the waste-management industry and the amount of material on this subject as well as the significance of the material in its own right led to the decision to publish all legal regulations on waste in one volume. It includes above all the Waste Law, Regulations on Determination of Waste, Regulations on Determination of Residual Products, Technical Instructions for Waste, Regulations for Monitoring Waste and Residual Products, Regulations on Probition from the Use of Chlorofluorohydrocarbons and Halon, Regulations on Packaging and Regulations on Sewage Sludge. The introduction explains the development and the role of the Waste Law and its applicability, goals and principles: The concept of waste, avoidance of waste, avoidance of ...
Oil and gas companies operate in many countries around the world. Their exploration and production (E&P) operations generate many kinds of waste that must be carefully and appropriately managed. Some of these wastes are inherently part of the E&P process; examples are drilling wastes and produced water. Other wastes are generic industrial wastes that are not unique to E&P activities, such as painting wastes and scrap metal. Still other wastes are associated with the presence of workers at the site; these include trash, food waste, and laundry wash water. In some host countries, mature environmental regulatory programs are in place that provide for various waste management options on the basis of the characteristics of the wastes and the environmental ...
In response to US Department of Energy directives, Argonne National Laboratory (ANL) has developed a waste minimization plan aimed at reducing the amount of wastes at this national research and development laboratory. Activities at ANL are primarily research- oriented and as such affect the amount and type of source reduction that can be achieved at this facility. The objective of ANL's waste minimization program is to cost-effectively reduce all types of wastes, including hazardous, mixed, radioactive, and nonhazardous wastes. The ANL Waste Minimization Plan uses a waste minimization audit as a systematic procedure to determine opportunities to reduce or eliminate waste. To facilitate these audits, a computerized bar-coding procedure is being implemented at ANL to track hazardous wastes ...
The potential hazard of landfill wastes was previously evaluated by examining the extraction procedures for individual waste, although various wastes were co-disposed of in actual landfills. This paper investigates the reduction of extraction-procedure toxicity by co-disposing various combinations of two wastes. When two wastes are mixed homogeneously, the extraction of heavy metals from the waste mixture is critically affected by the extract pH. Thus, co-disposal wastes will have a resultant pH between the pH values of its constituent. The lower the resultant pH, the lower the concentrations of heavy metals in the extract. When these wastes are extracted sequentially, the latter extracted waste has a stronger influence on the final concentration of heavy metals in the extract. Small-scale lysimeter ...
Results of a survey conducted by Concawe on 75 oil refineries in Europe show that the total quantity of waste requiring disposal in 1986 was 0.5 million metric tons. This quantity of waste is but 0.13% of the total refinery throughput of 387 million metric tons during 1986. The survey revealed a wide range of disposal costs, depending on the particular properties of the waste and local conditions. A summary of total waste generation and how the waste is disposed of is shown. Details on the types of waste disposed, the disposal methods used, and the costs of disposal are detailed in this excerpt from the Concawe survey.
The primary purpose of the Waste Management Program Plan is to provide an annual report of how Waste Management's operations are conducted, what facilities are being used to manage wastes, what forces are acting to change current waste management systems, and what plans are in store for the coming fiscal year. In addition, this document projects activities for several years beyond the coming fiscal year in order to adequately plan for safe handling, storage, and disposal of radioactive wastes generated at the Savannah River Site and for developing technology for improved management of wastes. In this document, work descriptions and milestone schedules are current as of December 1991.
This Waste Management Plan functions as a management and planning tool for managing waste streams generated as a result of operations at the Idaho CERCLA Disposal Facility (ICDF) Complex. The waste management activities described in this plan support the selected remedy presented in the Waste Area Group 3, Operable Unit 3-13 Final Record of Decision for the operation of the Idaho CERCLA Disposal Facility Complex. This plan identifies the types of waste that are anticipated during operations at the Idaho CERCLA Disposal Facility Complex. In addition, this plan presents management strategies and disposition for these anticipated waste streams.
This document presents a detailed schedule for the implementation of the strategy for managing defense remote-handled (RH) transuranic (TRU) waste. The baseline management strategy was defined in the Defense Remote-Handled Transuranic Waste Cost/Schedule Optimization Study and is summarized in this document. Also included are revised RH TRU waste inventory projections, current site management plans, a list of key decision points and milestones, and a discussion of uncertainties associated with management of RH TRU waste. The plans are summarized in a detailed schedule diagram and in an RH TRU waste work off diagram. 9 refs., 5 figs., 4 tabs.
Sida cordifolia is a plant belonging to the Malvaceae family used in many ayurvedic preparations. This study aimed at assessing the effects of ethanolic extract of Sida cordifolia root on quinolinic acid (QUIN) induced neurotoxicity and to compare its effect with the standard drug deprenyl in rat brain. Rats were divided into six groups: (1) control group (2) QUIN (55 microg/100 g bwt/day) (3) 50% ethanolic plant extract treated group (50 mg/100 g bwt/day) (4) Deprenyl (100 microg/100 g bwt/day) (5) QUIN (55 microg/100 g bwt/day) + 50% ethanolic plant extract treated group (50 mg/100 g bwt/day) (6) QUIN (55 microg/100 g bwt/day) + Deprenyl (100 microg/100 g bwt/day). At the end of the experimental period a status of lipid peroxidation products, protein peroxidation product, activities of the scavenging enzymes and the activities of the inflammatory markers were analyzed. Results revealed that the lipid peroxidation products decreased and the activities of the ...
The follow-up system for wastes (JAeSTI), developed at the end of the 1990s, forms a basis for today's followup activities in Finland. JAeSTI relies on an environmental protection database, the compliance monitoring system VAHTI operated by the environmental authorities. Waste followup and waste statistics depend very much on the annual waste quantities recorded in the VAHTI system. In the KYJ-project the coverage and reliability of the data in the VAHTI system was evaluated as for the streams of solid municipal waste. The project also included the compiling of national statistics on municipal waste for the year 2000. The project used other information sources, too, such as statistics compiled when the National Waste Plan and regional waste plans were revised in 2002. In addition, the extent and quantity of ...
A microcosm laboratory experiment was conducted to determine the impact of biological reworking by the ragworm Nereis diversicolor on the redistribution of particle-bound radionuclides deposited at the sediment-water interface. Over the course of the 40-day experiment, as much as 35% of a {sup 137}Cs-labelled particulate tracer deposited on the sediment surface was redistributed to depths of up to 11 cm by the polychaete. Three different reworking models were employed to model the profiles and quantify the biodiffusion and biotransport coefficients: a gallery-diffuser model, a continuous sub-surface egestion model and a biodiffusion model. Although the biodiffusion coefficients obtained for each model were quite similar, the continuous sub-surface egestion model provided the best fit to the data. The average biodiffusion coefficient, at 1.8 {+-} 0.9 cm{sup 2} y{sup -1}, is in good agreement with the values quoted by other workers on the bioturbation effects of this polychaete species. ...
A microcosm laboratory experiment was conducted to determine the impact of biological reworking by the ragworm Nereis diversicolor on the redistribution of particle-bound radionuclides deposited at the sediment-water interface. Over the course of the 40-day experiment, as much as 35% of a "1"3"7Cs-labelled particulate tracer deposited on the sediment surface was redistributed to depths of up to 11 cm by the polychaete. Three different reworking models were employed to model the profiles and quantify the biodiffusion and biotransport coefficients: a gallery-diffuser model, a continuous sub-surface egestion model and a biodiffusion model. Although the biodiffusion coefficients obtained for each model were quite similar, the continuous sub-surface egestion model provided the best fit to the data. The average biodiffusion coefficient, at 1.8 #+-# 0.9 cm"2 y"-"1, is in good agreement with the values quoted by other workers on the bioturbation effects of this polychaete species. The ...
The work is devoted to a microscopic analysis of the reactive capacity of chitin. An algorithm for modeling the deacetylation reaction in a monomeric unit of chitin is described. The reaction coordinate and the potential energy surface topography are determined taking into account the electron-vibrational interaction and low-symmetry perturbations within Jahn-Teller theory. Based on this algorithm, the topological modeling of the deacetylation process is performed for the first time and a mechanism of the biological activity of chitosan is proposed.
This book examines some of the basic principles behind chemical reactions kinetics. Topics considered include ab initio determination of potential energy for chemical reactions; semi-empirical potential energy surfaces; general theory of reactive scattering: different equation approach; and integral equation approach to reactive scattering.
The application of kinetic probes that allow one to determine relative reactivities of biologically relevant substrates with oxidizing intermediates in the Fenton reagent (H2O2 plus Fe2+ in acidic aqueous...Full Text Available
ObjectivesThis programme aims; To rethink how waste is thought about in social science; To provide a global analysis of waste; To examine how rethinking waste impinges on core social science concerns, notably: economies, researching globalisation, hazards and risk, and materiality. Social science understandings of waste position waste as the end-point of production and consumption, and see waste as a question of disposal.DescriptionThe Waste of the World is a five year research programme funded under ESRC's Large Grant Scheme. It brings together researchers in geography, anthropology and materials science from the University of Sheffield, Durham University, University College London and Goldsmiths College London, and connects the UK with South Asia (particularly India and Bangladesh), as well as the US, Europe and Kazakhstan. The ...
This Waste Management Plan describes waste management and waste minimization activities for Group 3, Other Surface Soils Remediation Sets 4-6 (Phase II) at the Idaho Nuclear Technology and Engineering Center located within the Idaho National Laboratory. The waste management activities described in this plan support the selected response action presented in the Final Record of Decision for Idaho Nuclear Technology and Engineering Center, Operable Unit 3-13. This plan identifies the waste streams that will be generated during implementation of the remedial action and presents plans for waste minimization, waste management strategies, and waste disposition.
On the basis of the analysis of chemical components of the natural limestones from different deposits in China, the pore structures of the typical limestones, with the different CaCO3 content, were examined. The reactivity of the limestones was investigated by sulfuric acid titration and gas-liquid absorption methods. The research results showed that the specific surface area of the natural limestones studied in this work was about 1.8 m2/g. It was seen that the pH of the limestone slurry rapidly decreased and then back up when the sulfuric acid was added. The higher the CaCO3 content was, or the smaller the particle size was, the larger the pH back-up rate was, and similarly the faster the SO2 concentration of the reactor outlet increased. The Reactivity of the limestone obtained by the sulfuric acid titration had the same features as that obtained by the gas liquid absorption. Compared with the specific surface area, the CaCO3 content had ...
A permeable reactive mixture has been developed using low cost, readily available materials that is capable of providing effective, long-term phosphorous treatment in areas impacted by on-land wastewater disposal. The reactive mixture creates a geochemical environment suitable for P-attenuation by both adsorption and precipitation reactions. Potential benefits include significant reductions in phosphorous loading to receiving groundwater and surface water systems, and the accumulation of P-mass in a finite and accessible volume of material. The mixture may be applied as a component within surface treatment systems or in subsurface applications such as horizontal or vertical permeable reactive walls. The mixture averaged > 90% treatment efficiency over 3.6 years of continuous-flow laboratory column experiments. The mixture was further evaluated at the pilot-scale to treat municipal wastewater, and the field-scale to treat ...
TiAl with between 0 and 20 volume percent (v%)Ti5Si3 was produced by reactive sintering of cold pressed compacts of elemental Ti, Al and Si powder mixtures at 700C for 15 minutes in vacuum. The results show that adding Si to Ti and Al reduces the swelling associated with reactive sintering of TiAl, as composites containing more than 5 v%Ti5Si3 densified during reactive sintering. However, composites containing more than 10v% Ti5Si3 did not retain their shape during processing, and the TiAl+20v% Ti5Si3 composite completely melted during the sintering process. The formation of pre-reaction liquid phase and the increase in adiabatic flame temperature with simultaneous compound formation resulted in the melting that occurred and the enhanced densification (minimization of swelling) during reactive sintering of the insitu composites.
The present emphasis on inherent safety for liquid-metal reactor designs has resulted in a need to represent the various reactivity feedback mechanisms as accurately as possible. The dominant negative reactivity feedback has been found to result from radial expansion of the core for most postulated anticipated transient without scram events. For this reasons, a more detailed model for calculating the reactivity feedback from radial core expansion, including subassembly bowing has been recently developed for use with the SASSYS/SAS4A code system. The purpose of this summary is to present an extension to the model so that it is more suitable for handling a core restraint design as used in the Fast Flux Test Facility (FFTF), and to compare the SASSYS/SAS4A results using this model to the empirical correlation presently being used to account for radial core expansion reactivity feedback in the FFTF.
The applicability of the electro-slag melting method for treating plutonium contaminated metallic waste was studied. A 100kg test furnace was built and simulated metallic waste was melted and solidified in this furnace. Waste volume was reduced to 1/25 with a decontamination factor of 25 and the slag and the copper mold are repeatedly usable. The process is expected to be employed in the project of PWTF (Plutonium contaminated Waste Treatment Facilities).
This request is submitted to seek interim approval to operate a chemical waste landfill for the disposal of polychlorinated biphenyl (PCB) wastes. This request covers only the disposal of small quantities of solid PCB wastes contained in decommissioned su...
The Waste Acceptance Preliminary Specifications (WAPS) require that the DWPF estimate the inventory of long-lived radionuclides present in the waste glass, and report the values in the Waste Form Qualification Report. In this report, conservative (biased high) estimates of the radionuclide inventory of glass produced from waste currently in the Tank Farm are provided. In most cases, these calculated values compare favorably with actual data. In those cases where the agreement is not good, the values reported here are conservative.
This paper very briefly outlines hazardous waste management issues, including regulations, in Mongolia. Air, water, and soil pollutants are identified and placed in context with climatic, social, and economic circumstances. The primary need identified is technology for the collection and disposal of solid wastes. Municipal waste problems include rapid urbanization and lack of sanitary landfills. Industrial wastes of concern are identified from the mining and leather industries. 4 refs., 2 tabs.
A supplementary report to the plan for waste disposal in the Copenhagen area, Denmark. It presents a mapping of wastes and waste flow in invidual areas, a description of recycling methods and waste collection systems. In addition legislative demands and potentials are dealth with. (CLS).
This 2-page fact sheet gives statistics on routine waste generation and projected reduction by waste type, and 1994 pollution prevention and recycling accomplishments at ORNL.
This document is a collection of spreadsheets detailing in a county by county manner the agricultural crop, agricultural wastes, municipal wastes, and industrial wastes of South Carolina that are potential biomass energy sources.
This document is a collection of spreadsheets detailing in a county by county manner the agricultural crop, agricultural wastes, municipal wastes and industrial wastes of North Carolina that are potential biomass energy sources.
This report shows the probability of a catastrophic accident involving the WIPP waste hoist system. Calculations and mitigation to reduce the probability of an accident and to minimize the impact of such an accident should be included. 10 refs., 8 figs., 4 tabs.
This report documents site remediation at ORNL, including ORNL site characterization technologies, waste management and robotics and automation of the laboratory for waste processing and analysis.
Research progress is reported in 20 activities under the headings: spent fuels, defense waste management, commercial waste management, remedial action, and conventional reactors. Separate entries were prepared for each activity.
The population growth, changing consumption patterns, and rapid urbanization contribute significantly to the growing volumes of solid waste that are generated in urban settings. As the rate of urbanization increases, demand on the services of solid waste management increases. The rapid urban growth in Langkawi Island, Malaysia, combined with the increasing rates of solid waste production has provided evidence that the traditional solid waste management practices, particularly the methods of waste collection and disposal, are inefficient and quite nonsustainable. Accordingly, municipal managers and planners in Langkawi ...
Quantities and compositions of non-tritium radioactive waste are estimated for some current conceptual fusion reactor designs, and disposal of large amounts of radioactive waste appears necessary. Although the initial radioactivity of fusion reactor and f...
The DOE strategy recognizes that public perception of low-level waste management practices is not positive. Actions are included that are aimed at opening the system to the public. A better informed public will be able to better assess the performance of the low-level waste management system.
This report describes mathematical predictions for the migration of radionuclides from an emplaced radioactive waste container. The model assumes a spherical-equivalent waste solid surrounded by backfill but neglects the effect of decay heat. 7 refs., 2 tabs. (TEM)
This article describes the processes for the treatment of plastic waste: sampling, sorting, comminution. The requirements for the different processes for waste treatment (as recycling, utilization as raw material, energy recovery, combustion) are listed. (SR)
To estimate the waste management needs of a fusion power reactor, a scheme for handling radioactive waste from a fusion plant has been devised. The handling scheme proceeds with radioactive waste, primarily from blanket replacement, being stored on-site; waste in cooled and shielded casks is then isolated off-site; finally, the materials are recycled. Using activities and component lifetimes supplied by designers, several conceptual fusion power reactors have been analyzed and their waste streams compared to fission reactors with regard to total activity, specific activity, and lifetimes of activity.
To estimate the waste management needs of a fusion power reactor, a scheme for handling radioactive waste from a fusion plant has been devised. The handling scheme proceeds with radioactive waste, primarily from blanket replacement, being stored on-site; waste in cooled and shielded casks is then isolated off-site; finally, the materials are recycled. Using activities and component lifetimes supplied by designers, several conceptual fusion power reactors have been analyzed and their waste streams compared to fission reactors with regard to total activity, specific activity, and lifetimes of activity.
This report describes initial work on the development of solidification systems for sodium nitrate waste and compacted waste. Sodium nitrate waste has been solidified in three types of materials: polyethylene, polyester-styrene (PES), and latex cement. Evaluations of the properties of the waste form, such as the ANS 16.1 leaching test, water immersion test and compressive strength measurements were performed on the waste forms containing various amounts of sodium nitrate. 9 refs., 9 figs., 7 tabs.
Since 1976 the Austrian Research Centre Seibersdorf has the task to collect, treat and store radioactive waste (Radwaste) arising in Austria. Within the Department of Waste Management a variety of appropriate treatment systems are installed. For storing unconditioned and conditioned waste proper storage-halls are available. The collection of Radwaste is carried out using 100 l drums, for the conditioned waste the 200 l drum concept is used. The interim storage of conditioned waste is done at Seibersdorf until a final repository is built. The present plan foresees one to be in operation at the year 2012. (author).
This plan outlines the procedures and operations used at LLNL's Site 300 for the management of the hazardous waste generated. This waste consists primarily of depleted uranium (a by-product of U-235 enrichment), beryllium, small quantities of analytical chemicals, industrial type waste such as solvents, cleaning acids, photographic chemicals, etc., and explosives. This plan details the operations generating this waste, the proper handling of this material and the procedures used to treat or dispose of the hazardous waste. A considerable amount of information found in this plan was extracted from the Site 300 Safety and Operational Manual written by Site 300 Facility personnel and the Hazards Control Department.
By presenting some case studies, this paper analyzes China`s situation with regard to hazardous waste: its environmental trade, treatment, and management. The paper describes China`s experiences with the environmental trade of hazardous waste in both the internal and international market. Regulations for managing the import of waste are discussed, as are China`s major approaches to the trading of hazardous waste both at home and overseas. The major reasons for setting up the Asian-Pacific Regional Training Center for Technology Transfer and Environmental Sound Management of Wastes in China and the activities involved in this effort are also described. 1 tab.
In the experimental fast Reactor JOYO, gripper of Fuel Handling Machine and Ex-Vessel Transfer Machine that the sodium adhered is being washed with alcohol. This radioactive alcohol waste that was used to the washing is stored to the tank. If it is able to separate the alcohol and sodium in the alcohol waste it becomes possible to dispose of the alcohol waste. Japan Nuclear Institute and Fuji Electric Systems CO., LTD. Developed the device that adds carbonic acid gas to the alcohol waste and cause the sodium in the alcohol waste separated as carbonate and remove this carbonate by using the thin film evaporator. (author)
An experiment was performed with a mock-up of the core of the Fast Flux Test Facility (FFTF) reactor to evaluate three reactivity measurement methods for application to liquid-metal fast breeder reactors (LMFBR): modified source multiplication measurements with the low-level flux monitor for refueling (35 dollars subcritical) of FFTF, noise analysis to 35 dollars subcritical, and inverse kinetics rod drop to 12 dollars subcritical. To investigate the spatial dependence of these measurement methods and to resolve discrepancies previously reported, detectors were placed in the core, reflector, and radial shield, and experimental data were collected with the reactivity at near delayed criticality to 35 dollars subcritical. Conclusions from this experiment are the following. Low-level flux monitors in the shield of the FFTF will be adequate for reactivity surveillance during refueling, using the modified source multiplication ...
Three reactive materials were evaluated at laboratory scale to identify the optimum treatment reagent for use in a Permeable Reactive Barrier Treatment System at Rocky Flats Environmental Technology Site (RFETS). The contaminants of concern (COCS) are uranium, TCE, PCE, carbon tetrachloride, americium, and vinyl chloride. The three reactive media evaluated included high carbon steel iron filings, an iron-silica alloy in the form of a foam aggregate, and a peculiar humic acid based sorbent (Humasorb from Arctech) mixed with sand. Each material was tested in the laboratory at column scale using simulated site water. All three materials showed promise for the 903 Mound Site however, the iron filings were determined to be the least expensive media. In order to validate the laboratory results, the iron filings were further tested at a pilot scale (field columns) using actual site water. Pilot test results were similar to ...
The Savannah River Site (SRS) is a key installation for the production and research of nuclear materials for national defense and peace time applications and has been operating a full nuclear fuel cycle since the early 1950s. Wastes generated include high level radioactive, transuranic, low level radioactive, hazardous, mixed, sanitary, and aqueous wastes. Much progress has been made during the last several years to reduce these wastes including management systems, characterization, and technology programs. The reduction of wastes generated and the proper handling of the wastes have always been a part of the Site's operation. This paper summarizes the current status and future plans with respect to waste reduction to waste reduction and reviews some specific examples of successful activities.
The Savannah River Site (SRS) is a key installation for the production and research of nuclear materials for national defense and peace time applications and has been operating a full nuclear fuel cycle since the early 1950s. Wastes generated include high level radioactive, transuranic, low level radioactive, hazardous, mixed, sanitary, and aqueous wastes. Much progress has been made during the last several years to reduce these wastes including management systems, characterization, and technology programs. The reduction of wastes generated and the proper handling of the wastes have always been a part of the Site`s operation. This paper summarizes the current status and future plans with respect to waste reduction to waste reduction and reviews some specific examples of successful activities.
This program deals with solid waste disposal with topics/services covering: Reusable Building Materials and Large Household Items Exchange, Beneficial Use Determination, Biosolids, Certification, Compost Facil...
Aqueous radioactive high-level waste slurries are combined during processing steps that ultimately produce a stable borosilicate glass waste form. Chemically treated waste slurries are combined with each other and with glass frit-water slurries to produce the melter feed. Understanding the evolution of the rheological properties of the slurries is an important aspect of removing and treating the stored waste. To a first approximation, combinations of colloidal waste slurry with {approx}0.1-mm mean diameter glass frit or glass beads act in an analogous matter to slurries of spherical beads in Newtonian liquids. The non-Newtonian rheological properties of the waste slurries without frit, however, add complexity to the hydrodynamic analysis. The use of shear rate dependent apparent viscosities with the modified Einstein equation was used to model the rheological ...
A brief article considers the possible result of the enquiry into Nirex`s plan to build an underground rock laboratory at Sellafield in relation to radioactive waste disposal in the UK. (UK).
The fundamental points to be considered in a waste treatment system for a country like Japan, where the final disposal method has not been decided and the wastes have to be stored in the power plants, are volume reduction of the wastes, safe storage of the wastes in the plant, and flexibility regarding the final disposal. A system has been developed that consists of a thin film evaporator for the direct solidification of the liquid waste, a pelletizer for producing hard pellets from the powdered wastes, a pellet storage unit, and a solidification unit for the final disposal. A pilot plant with waste treatment capacity of 200 kg/h was built in 1976 and has proved the system feasibility. This paper reports on pilot plant tests of the thin film evaporator and other components, tests on pellet deterioration during long term storage, and ...
The fundamental points to be considered in a waste treatment system for a country like Japan, where the final disposal method has not been decided and the wastes have to be stored in the power plants, are volume reduction of the wastes, safe storage of the wastes in the plant, and flexibility regarding the final disposal. A system has been developed that consists of a thin film evaporator for the direct solidification of the liquid waste, a pelletizer for producing hard pellets from the powdered wastes, a pellet storage unit, and a solidification unit for the final disposal. A pilot plant with waste treatment capacity of 200 kg/h was built in 1976 and has proved the system feasibility. This paper reports on pilot plant tests of the thin film evaporator and other components, tests on pellet deterioration during long term storage, and ...
The use of nondestructive evaluation (NDE) methods is proposed for characterization of transuranic (TRU) waste stored at the Radioactive Waste Management Complex. These NDE methods include real-time x-ray radiography, real-time neutron radiography, x-ray and neutron computed tomography, thermal imaging, container weighing, visual examination, and acoustic measurements. An integrated NDE system is proposed for characterization and certification of TRU waste destined for eventual shipment to the Waste Isolation Pilot Plant in New Mexico. Methods for automating both the classification waste and control of a complete nondestructive evaluation/nondestructive assay system are presented. Feasibility testing of the different NDE methods, including real-time x-ray radiography, and development of automated waste classification techniques are covered as part of a five year ...
Jun 4, 2004 ... On a two-year trip to Mars, according to one estimate, a crew of six humans will generate more than six tons of solid organic waste--much of ...
... Waste Collection Systems Products and Equipment Find and compare a variety of waste collection systems products and equipment on the world's largest environmental industry portal. View product ...
Jun 16, 2011 ... Description: Most of the approximately 25 to 30 million tons of industrial wood waste generated in the United States per year is burned for ...
The need for efficient management of industrial chemical wastes, especially those considered hazardous or radioactive, is receiving increased attention in the United States. During the past five years, several federal laws have addressed the establishment of stronger programs for the control of hazardous and residual wastes. At a facility such as Oak Ridge National Laboratory (ORNL), an efficient waste management program is an absolute necessity to ensure protection of human health and compliance with regulatory requirements addressing the treatment and disposal of hazardous, nonhazardous, and radioactive wastes. This report highlights the major regulatory requirements under which the Laboratory must operate and their impact on ORNL facilities. Individual waste streams, estimates of quantities of waste, and current waste management ...
Conversion of Idaho National Engineering and Environmental Laboratory radioactive sodium-bearing waste into a single solid waste form by evaporation was demonstrated in both flask-scale and pilot-scale agitated thin film evaporator tests. A sodium-bearing waste simulant was adjusted to represent an evaporator feed in which the acid from the distillate is concentrated, neutralized, and recycled back through the evaporator. The advantage to this flowsheet is that a single remote-handled transuranic waste form is produced in the evaporator bottoms without the generation of any low-level mixed secondary waste. However, use of a recycle flowsheet in sodium-bearing waste evaporation results in a 50% increase in remote-handled transuranic volume in comparison to a non-recycle flowsheet.
...Systems by IPEX Enfield electrofusion acid waste systems give you the proven corrosion resistance of polypropylene, along with our patented, state-of-the-art electrofusion system....
The object of this research is to study reactivity at superthermal collision energies using a fast neutral beam that is generated by photodetachment. Systems scheduled for initial study include basic oxygen-hydrogen reactions. Unfortunately, we can not yet report realization of this goal, but during this funding period we have made advances that are anticipated to lead to successful measurements during the next year. The parameters described below refer to the model system O + H{sub 2} {yields} OH + H. The basic design involves the collision of fast neutrals, created by photodetachment of the corresponding negative molecular ion, with a stable reactant gas in a collision cell. Products are detected by ionization and mass analysis. We are equipped to study rotational effects on reactivity by comparing results for rotational levels J = 0 and 1 of H{sub 2}. Highlights during the funding period are given in this report.
Reference failures, and their increase in affectively negative conditions (known as affective reactivity of speech), are more frequently observed in schizophrenia patients than in normal controls, but no information is available comparing schizophrenia with depression, ie, a mental disorder closely linked to the concept of affective reactivity. To address this gap in the literature, the present study compared 24 schizophrenia inpatients, 21 unipolar depression inpatients and 21 normal controls. Two 10-minute conversational speech samples (1 on negative and 1 on positive memories) were collected from each patient. The transcripts of the audiotaped interviews were analyzed blindly for frequencies of 6 types of referential failures, employing the Communication Disturbances Index, adapted for ...
A novel wastewater treatment technique has been investigated, for reactive dye removal, in batch kinetic systems. These experimental studies have indicated that charred dolomite has the potential to act as an adsorbent for the removal of Brilliant Red reactive dye from aqueous solution. The effect of initial dye concentration, adsorbent mass:liquid volume ratio, and agitation speed on dye removal have been determined with the experimental data mathematically described using empirical external mass transfer and intra-particle diffusion models. The experimental data show conformity with an adsorption process, with the removal rate heavily dependent on both external mass transfer and intra-particle diffusion. PMID:12691893
In the present contribution, the innovative in situ Raman micro-spectroscopy was applied to investigate the in vitro reactivity of various bioactive glasses. All the investigated glasses belonged to the Na2O\\K2O-CaO-P2O5-SiO2 system, but contained sensibly different percentages of network modifiers. The glasses were immersed for increasing times, up to 96h, in simulated body fluid (SBF) and in tris-buffered (TRIS) solution. In this way, two fundamental items were addressed, i.e. the effect of the glass composition and the nature of the soaking fluid on the overall reactivity. As regards the SBF, all the glasses were able to promote the formation of a hydroxyl-carbonate apatite (HCA) surface layer in very short times. The reaction rate was particularly quick for the 45S5 Bioglass and for it...
This paper aims to study fundamentally the impacts of membrane properties on the reactive dye removal from dye/salt mixtures by nanofiltration membranes. To begin with, two types of nanofiltration membranes of similar pore size, namely asymmetric cellulose acetate membrane and thin-film composite polyamide membrane were fabricated, and their key physical, chemical and performance properties were characterized. After that, these resultant membranes were employed to perform dye removal experiments with aqueous solutions of reactive black 5 and NaCl under different operational parameters. The dye removal rate and steady permeate flux were determined and correlated with the measured membrane properties. It was found that there were significant differences between the dye removal performances o...
The Cycle 8A static tests conducted in the Fast Flux Test Facility (FFTF) during 1986 have resulted in the separation of various feedback reactivity components. These feedback components, described by closed-form equations depending only on the reactor temperature field, can be regarded as database for the validation and/or calibration of feedback mechanistic models. The SASSYS safety analysis code contains the most developed feedback reactivity models and was selected for the comparison study between database and mechanistic calculations for the FFTF. Although detailed feedback models for control rod repositioning and core radial expansion/bowing exist, only the simple models were available in SASSYS at the time of this study. The results are described in this paper.
The benchmark calculations have been performed for MCNP-4B code using the measurement data of Wolsong nuclear power plant 2. In this study, the benchmark calculations have been performed for the criticality, boron worth, reactivity device worth, reactivity coefficient, and flux scan. Cross-section libraries were newly generated from ENDF/B-VI release 3 through NJOY97.114 data processing system and a three-dimensional full core model was developed for MCNP calculation. The simulation results have shown that the criticality is estimated within 4 mkn and the estimated reactivity worth of the control devices are generally consistent with the measurement data. In certain cases, the simulation results have shown large discrepancies against the measurement data, which will be sturdied further in the near future.
This report is a review of waste form options for the immobilization of high-level-liquid wastes from the nuclear fuel cycle. This review covers the status of international research and development on waste forms as of May 1979. Although the emphasis in this report is on waste form properties, process parameters are discussed where they may affect final waste form properties. A summary table is provided listing properties of various nuclear waste form options. It is concluded that proposed waste forms have properties falling within a relatively narrow range. In regard to crystalline versus glass waste forms, the conclusion is that either glass of crystalline materials can be shown to have some advantage when a single property is considered; however, at this date no single waste form offers optimum ...
US Department of Energy (DOE) Order 5820.2A was promulgated in final form on September 26, 1988. The order requires heads of field organizations to prepare and to submit updates on the waste management plans for all operations under their purview according to the format in Chap. 6, {open_quotes}Waste Management Plan Outline.{close_quotes} These plans are to be submitted by the DOE Oak Ridge Operations Office (DOE-ORO) in December of each year and distributed to the DP-12, ES&H-1, and other appropriate DOE Headquarters (DOE-HQ) organizations for review and comment. This document was prepared in response to this requirement for fiscal year (FY) 1994. The Oak Ridge National Laboratory (ORNL) waste management mission is reduction, collection, storage, treatment, and disposal of DOE wastes, generated primarily in pursuit of ORNL missions, in order to protect human health and safety and the environment. ...
Ultraviolet (UV) photoirradiation of Ag(I) compounds in the presence of an aqueous Triton X-100 solution has been exploited for the first time to prepare reproducible yellow silver hydrosol. The evolution of nanosized silver particles has been examined critically under the influence of different anions/ligands. Hence, time dependent evolution of silver hydrosol from different silver compounds in micelle via photochemical reduction is observed. Anions/ligands of precursor salts have been found to show profound influence (due to electron scavenging property, solubility, stability etc.) on the evolution route and efficiency of photochemical reduction of Ag(I) to Ag(O) in micelle and thereby classification of silver compounds becomes possible. Kinetic results reveal that the formation of silver particles proceeds via autocatalytic growth mechanism. The observed variation in rate constant values for the evolution of nanoparticles from different silver compounds have ...
A gas injection diesel engine was developed as an approaching measure to the diversification of fuel. Contrary to the usual low pressure gas application engine, this engine applies a so-called diffuse combustion method, in which high pressure (24.7Mpa) gas fuel is injected directly in the cylinder and is ignited and combusted by a little pilot fuel injected almost at the same time. The engine have following features. As a principle, it can attain the same heat efficiency and output rate as a diesel engine in any load range. It is excellent in responsibility to load fluctuation. There is no internal leakage of gas fuel to the scavenging chamber (the crank chamber) in the compression stroke. Not only a wide range of mixed combustion of gas fuel and heavy oil fuel, but also single combustion of heavy oil is possible. It is, therefore, drawing attention as an engine for an LNG ship and also for a power generation plant with the recent increasing demand of gas fuel ...
The adsorption capacity of radionuclides onto suspended sediment was experimented on each of the coastal seawater sampled around the Kori and the Wolsung nuclear power plant. During the experiment the quantity and size fraction of suspended sediment were adjusted and the seawater and sediment chemistry is approximated to the expected field condition. Because the sorption capacity depends on the specific minerals, ocean chemistry and radionuclide involved, it is necessary to analyze sediment mineralogy. Clay mineral is dominant in seabed mineral and suspended sediment as the result of x-ray diffraction. Radionuclide sorbed to silty-clay mineral can be rather transported to ocean than scavenged to seabed because of low quantity and fine grained suspended sediment in the coast around the Kori and the Wolsung. The result of adsorption examinations shows that {sup 139}Ce and {sup 51}Cr and {sup 110m}Ag are strongly sorbed to suspended particle, while {sup 137}Cs is less ...
The adsorption capacity of radionuclides onto suspended sediment was experimented on each of the coastal seawater sampled around the Kori and the Wolsung nuclear power plant. During the experiment the quantity and size fraction of suspended sediment were adjusted and the seawater and sediment chemistry is approximated to the expected field condition. Because the sorption capacity depends on the specific minerals, ocean chemistry and radionuclide involved, it is necessary to analyze sediment mineralogy. Clay mineral is dominant in seabed mineral and suspended sediment as the result of x-ray diffraction. Radionuclide sorbed to silty-clay mineral can be rather transported to ocean than scavenged to seabed because of low quantity and fine grained suspended sediment in the coast around the Kori and the Wolsung. The result of adsorption examinations shows that "1"3"9Ce and "5"1Cr and "1"1"0"mAg are strongly sorbed to suspended particle, while "1"3"7Cs is less sorbed and ...
Poly(methyl methacrylate), PMMA, Acrigel, a Brazilian polymer, is used in the manufacture of medical supplies sterelizable by ionizing radiation. However, when PMMA is gamma-irradiated it undergoes main chain scissions, which promote molecular degradation causing reduction in its mechanical properties. Therefore, radiolytic of PMMA is important for it to become commercially radiosterizable. In this work some commercial additives, originally used in photo-and thermo-oxidate stabilization of polymers, were tested. Only two additives, type HALS (Hindered Amine Light Stabilizer), denoted Scavenger, showed a good protective quality. The investigation of radiation-induced main scissions was carried out by viscosimetric method. The most effective additive, added to the polymer system at 0.3 w/w%, promotes a great molecular radioprotection of 93%. That means a reduction of G-value (scissions/100 eV) from 0.611 to 0.053. In addition, the glassy transition temperature (T{sub ...
Inductively coupled plasma etching of InGaP, AlInP and AlGaP in BI{sub 3} or BBr{sub 3} discharges was investigated as a function of source power, dc chuck bias and plasma composition. InGaP etches at the fastest rates ({gt}6000thinsp{Angstrom}thinspmin{sup {minus}1}) in both chemistries, followed by AlGaP. It is found that AlInP provides an excellent etch stop for the other two materials in both mixtures. The InGaP surface morphology improves with increasing BI{sub 3} or BBr{sub 3} content, and with increasing dc chuck bias. The etched features for this material are highly anisotropic. Etch selectivities for InGaP over SiO{sub 2} and SiN{sub x} of {ge}8 are obtained in both plasma chemistries, and there is no etch incubation time with either mixture, indicating that both can scavenge the native oxide on InGaP, AlGaP and AlInP. {copyright} {ital 1998 American Vacuum Society.}
Inductively coupled plasma etching of InGaP, AlInP and AlGaP in BI_3 or BBr_3 discharges was investigated as a function of source power, dc chuck bias and plasma composition. InGaP etches at the fastest rates (>6000 Angstrom min"-"1) in both chemistries, followed by AlGaP. It is found that AlInP provides an excellent etch stop for the other two materials in both mixtures. The InGaP surface morphology improves with increasing BI_3 or BBr_3 content, and with increasing dc chuck bias. The etched features for this material are highly anisotropic. Etch selectivities for InGaP over SiO_2 and SiN_x of #>=#8 are obtained in both plasma chemistries, and there is no etch incubation time with either mixture, indicating that both can scavenge the native oxide on InGaP, AlGaP and AlInP. copyright 1998 American Vacuum Society.
Summary The antioxidant properties and toxicity profile of roasted noni (Morinda citrifolia L.) leaf infusion were evaluated. The 2,2-diphenylpicrylhydrazyl (DPPH) radical scavenging activity was greater than green tea infusion (81.6 +- 0.9% vs. 57.5 +- 1.8%, P < 0.001). The mean quercetin and kaempferol contents of roasted noni leaf infusion, as prepared by the consumer, were 0.24 +- 0.01 and 0.14 +- 0.01 mg mL-1, respectively. Tannic acid content was 10 +- 1 mg mL-1. The infusion was non-mutagenic in the reverse mutation test in Salmonella typhimurium and did not induce primary DNA damage in E. coli PQ37. Further, no significant primary DNA damage was induced by 5,15-dimethylmorindol, which was the only detectable anthraquinone in noni leaves. The infusion was not cytotoxic in the 24 h b...
The side effects of cancer therapy on normal tissues limit the success of therapy. Generation of reactive oxygen species (ROS) has been implicated for numerous chemotherapeutic agents including doxorubicin...Full Text Available
The activated charcoal is very appreciates for the water treatment. It do not generate by-product of treatment. In return it is saturated after some time and may releases pollutant compounds. When and how to get to its regeneration?.
Objective:The identification of biological markers in order to assess different aspects of COPD is an area of growing interest. The objective of this study was to investigate whether...Full Text Available
Background: Differentiation between reactive, but morphologically atypical, mesothelial cells and adenocarcinoma in effusions can be problematic. Elaborate immunohistochemical...Full Text Available
Mitochondria and peroxisomes execute some analogous, nonredundant functions including fatty acid oxidation and detoxification of reactive oxygen species, and, in response to select metabolic cues, undergo...Full Text Available
1. Seven unique carboxymethylcysteine-containing peptides have been isolated from tryptic digests of rabbit muscle aldolase carboxymethylated with iodo[2-14C]acetic acid in 8m-urea....Full Text Available
Reactive oxygen species (ROS), inevitable byproducts of aerobic metabolism, are known to cause oxidative damage to cells and molecules. This, in turn, is widely accepted as a pivotal determinant of...Full Text Available
BackgroundInflammatory markers may be associated with recurrent vascular events after stroke. We aimed to: (1) determine the association between interleukin-6, C-reactive...Full Text Available
This paper summarizes studies on the water treatment by adsorption, as for the adsorption during water treatment, reactivation of activated charcoal, and clarification of heating process. Reactivation of activated charcoal for the water treatment is carried out through drying in the heating furnace. Basic problems are the recovery degree of adsorption performance of reactivated activated charcoal and the recovery yield. Behavior of the activated charcoal in the heating reactivation furnace is divided into three stages including drying process, heating process, and gasification process. Among these processes, behaviors of organic matters during heating process are described. Thermogravimetric analyses (TGA) were conducted for activated charcoals adsorbing various organic matters in aqueous solutions. Three types of organic matters were classified from the TGA pattern, i.e., organic matters with ...
Reactive blue 2 (RB-2) had been characterized as a relatively potent ectonucleoside triphosphate diphosphohydrolase (E-NTPDase) inhibitor with some selectivity for NTPDase3. In search for the pharmacophore...Full Text Available
Generation of reactive oxygen species by the NADPH oxidase complex is an important bactericidal weapon of phagocytes. Phorbol myristate acetate (PMA) is a potent agonist for this “respiratory...Full Text Available
Experiments on Xanthium leaf discs were carried out to determine whether concomitant photoreactivation could be detected and if so, to compare its effects with photoreactivation due...Full Text Available
New approaches to the risk assessment process are needed that might be more definitive and satisfying to the scientific community, interest groups, and the public at large. This commentary examines...Full Text Available
AbstractBackgroundIonizing radiation (IR) initiates intracellular oxidative stress through enhanced formation of reactive oxygen species (ROS) that attack DNA leading...Full Text Available
BackgroundTelephone quit lines are accessible to many smokers and are used to engage motivated smokers to make quit attempts. Smoking cessation counselling provided via telephone...Full Text Available
Thiobenzamide (TB) is a potent hepatotoxin in rats, causing dose-dependent hyperbilirubinemia, steatosis, and centrolobular necrosis. These effects arise subsequent to and appear to result from...Full Text Available
It has been sixty years since the Millers first described the covalent binding of carcinogens to tissue proteins. Protein covalent binding was gradually overshadowed by the emergence of DNA...Full Text Available
IntroductionThe aim of this study was to evaluate the effects of red blood cell (RBC) transfusions on muscle tissue oxygenation, oxygen metabolism and microvascular reactivity in...Full Text Available
Mitochondrial DNA is constantly exposed to oxidative injury. Due to its location close to the main site of reactive oxygen species, the inner mitochondrial membrane, mtDNA is more susceptible...Full Text Available
Nitric oxide (NO) and related reactive nitrogen species (RNS) play a major role in the pathophysiology of stroke and other neurodegenerative diseases. One of the poorly understood consequences...Full Text Available
Decitabine, an epigenetic modifier that reactivates genes otherwise suppressed by DNA promoter methylation, is effective for some, but not all cancer patients, especially those with solid tumors. It...Full Text Available
AimTo assess the progression of bronchial reactivity (BR) and incidence of bronchial hyperreactivity (BH), exercise‐induced bronchoconstriction (EIB) and asthma in triathletes...Full Text Available
Although most self-reactive T cells are eliminated in the thymus, mechanisms to inactivate or control T cells specific for extrathymic antigens are required and exist in the periphery. By investigating...Full Text Available
The major neuropathological correlate of cerebral palsy in premature infants is periventricular leukomalacia (PVL), a disorder of the immature cerebral white matter. Cerebral ischemia leading...Full Text Available
Increasing numbers of human cowpox virus infections that are being observed and that particularly affect young non-vaccinated persons have renewed interest in this zoonotic disease. Usually causing...Full Text Available
Cigarette smoke (CS) induces recruitment of inflammatory cells in the lungs leading to the generation of reactive oxygen species (ROS), which are involved in lung inflammation and injury. Nicotinamide...Full Text Available
Evaluation of the protective efficacy of recombinant T-cell-reactive proteins of Coccidioides posadasii in a murine model of coccidioidomycosis has led to the discovery of potential...Full Text Available
In the present study mixed cultures that could grew in the molasses media were isolated from textile dye effluent and its decolorization activity was studied in a batch system under anaerobic conditions, in order to determine the optimal conditions required for the highest decolorization activity. The optimum pH value for decolorization was determined as 8 for all the dyes tested. In the experiment with pH 8 dye decolorizations by mixed cultures were investigated at about 96.2-1031.3mgl-1 initial dye concentrations. The highest dye removal rates of mixed cultures were 94.9% for Reactive Red RB, 91.0% for Reactive Black B and 63.6% for Remazol Blue at 953.2, 864.9 and 1031.3mgl-1 initial dye concentrations respectively within 24h incubation period. When the Reactive Red RB was used, approxi...
Cooperative research in coal liquefaction from Auburn University, University of Kentucky, University of Pittsburgh, West Virginia University, University of Utah, and the UK Center for Applied Energy Research, are briefly discussed. Topics covered include desulfurization, chemical reactivity, coprocessing, and catalysis. (CBS)
Significant progress was made in the May 1990--May 1991 contract period in three primary coal liquefaction research areas: catalysis, structure-reactivity studies, and novel liquefaction processes. A brief summary of the accomplishments in the past year in each of these areas is given.
Mechanism-based inhibition of cytochrome P450 (CYP) 3A4 is characterized by NADPH-, time-, and concentration-dependent enzyme inactivation, occurring when some drugs are converted by CYPs to reactive...Full Text Available
A survey was conducted at 15 textile plants with dyehouses in western Sweden. Employees with a history of work related rhinitis, asthma, or skin symptoms were offered a clinical and immunological investigation...Full Text Available
Numerous xenobiotics, including therapeutics agents, are substrates for bioactivation to electrophilic reactive intermediates that may covalently modify biomolecules. Selective estrogen receptor...Full Text Available
Platelet reactivity plays a pivotal role in the pathogenesis of ischemic adverse events during and after acute coronary syndromes (ACS), and percutaneous coronary intervention (PCI). Glycoprotein (GP)...Full Text Available
Increased oxidative stress with elevated levels of reactive oxygen and nitrogen species (ROS/RNS) plays an important role in the pathophysiology of many disease states. Increased ROS/RNS can...Full Text Available
Seven mutants of Escherichia coli were isolated that are sensitive to methyl methane sulfonate but not to UV light. They exhibited decreased host cell reactivation capacity for methyl methane sulfonate-treated...Full Text Available
Observational evidence is presented for the nucleation of condensation nuclei (CN) in the clear air adjacent to an isolated, marine, cumulus cloud. Two separate regions of particle nucleation are identified: one located above the cloud top, and the second located downwind of the cloud near the level of the anvil outflow. The regions of high CN concentrations were located in extremely clean marine air, with unactivated aerosol surface area (excluding the nucleation mode) less than 2 sq micrometers/cu cm, air temperature -31 C, and higher relative humidities than the undisturbed environment. Vertical profile measurements downwind of the cloud showed that CN concentrations at the level of the anvil outflow (4.9 km) were 8 times greater than at any other level between the surface and 5.3 km. A conceptual model is formulated in which aerosol particles, sulfur dioxide (SO2), sulfuric acid vapor (H2SO4), dimethyl sulfide (DMS), and ozone (O3) from the boundary layer are entrained into the ...
This report contains preconceptual designs and planning level life-cycle cost estimates for managing hazardous waste. The report`s information on treatment, storage, and disposal modules can be integrated to develop total life-cycle costs for various waste management options. A procedure to guide the US Department of Energy and its contractor personnel in the use of cost estimation data is also summarized in this report.
...diversion generates a host of environmental, financial, and social benefits, including conserving energy, reducing disposal costs, and reducing the burden on landfills and other waste disposal methods . Waste Diversion at EPA For many years, EPA has established waste diversion goals that exceed current federal requirements. EPA ...
This article describes the utilization of plastic wastes in a blast furnace. The plastic waste is a substitution for petroleum and coal as a raw material for synthesis gas production. The synthesis gas is the reducing agent in the blast furnace for the reduction of iron ores. You can find here an ecological and economical analysis of this process in comparison to the utilization of petroleum and coal. (SR)
... MUNICIPAL SOLID WASTES (MANAGEMENT AND HANDLING) RULES, 2000 Plastic Bag ban in Dhaka City, Bangladesh Private Sector Participation in Municipal Solid Waste Management SKAT 2000 TECHNICAL GUIDELINES ON MUNICIPAL SOLID WASTE MANAGEMENT Hazardous Waste Management Unit, Environmental Pollution Control Division, Central Environmental Authority, Sri Lanka 2004 Subregional ...
This request is submitted to seek interim approval to operate a chemical waste landfill for the disposal of polychlorinated biphenyl (PCB) waste. Interim approval is requested for a period not to exceed 5 years. This request covers only the disposal of sm...
This report summarizes the information gathered by CONCAVE in a 1993 survey of waste generation and disposal by the oil refineries in Western Europe. The survey covered the types of waste produced, their quantities, disposal routes and costs of disposal. The results are compared with those from a 1986 survey, but because of the increased numbers of refineries reporting, comparison is difficult. The survey revealed wide variations in disposal costs depending on waste type and local circumstances.
In this study, we investigate an inter-industrial and inter-regional recycling system for industrial waste by the cement industry in Japan. We develop a linear programming model that represents cement production processes and waste transportation of all cement factories in Japan. We simulate cost and CO{sub 2}-minimizing systems. The result implies that making waste transportation more efficient in cost is an effective means for CO{sub 2} reduction. (author)
Cattle and pig wastes, orange peels, compost, and grain husks were hydrolyzed in an alkaline medium to investigate the CH4 generation capacity. The respective CH4 production capacities from pig wastes and rice hulls were approximately 1 and approximately 0.1 L/g. The CH4 produced can be used to supplement energy requirements of farms.
This document provides detailed data and graphics on airborne and liquid effluent releases, fuel oil and coal consumption, water usage, and hazardous and mixed waste generated for calendar year 1992. This report summarizes industrial waste data records compiled since 1971 for the Idaho National Engineering Laboratory (INEL). The data presented are from the INEL Nonradiological Waste Management Information System.
A summary is given of the 1983 NRPB-GS1 Report on the 'Radiological protection objectives for the disposal of solid radioactive wastes'. The two principal difficulties in applying the ICRP system of dose limitation to some solid waste disposal methods are outlined. Despite these difficulties three radiological protection objectives for waste disposal were recommended based on the same fundamental principle as ICRP recommendations.
Biomass is a potential source of energy that can reduce our dependency on oil as the main source of energy. In addition to municipal solid waste, animal and olive wastes are the main sources of organic waste in Jordan. In 2005, there were more than 2.4 million heads of sheep, about 72 thousand cows, and 40 million hens being raised in farms distributed in all governorates of Jordan. These animals produce 5.3 million tons (as exerted) of solid waste per year. If these quantities can be effectively collected they may constitute a valuable source of energy. This paper is aiming to estimate the amounts of animal and solid wastes generated in Jordan and their energy potential. The total amount of BOD from animal waste is estimated at 200,000 tons per year. Significant quantities of organic waste can also be collected from olive mills distributed ...
Focuses on the application of remote sensing techniques to the study of coal waste mounds. The situation at the coal waste mounds in Fukuoka, Japan is cited. Guidelines on film parameters, photographic keys and tasks required to inventory, monitor and manage coal waste mounds in Japan are addressed. Application of photogrammetry, remote sensing, aerial photography and satellite imagery techniques in monitoring spoil banks is reviewed. Applicability of the techniques is discussed. 24 refs.
Revolving type fluidized-bed technology, developed by Ebara Corp., is installed in more than 100 facilities worldwide. The technology is applied for waste, coal and in situations where a conventional fluidized bed is difficult to use. Waste and/or coal can be treated and valuable energy can be recovered from a non-renewable source. This paper describes the application of the revolving fluidized bed for waste, coal and tyres.
Specifically this report: 1. Compares requirements of the WAP that are pertinent from a technical viewpoint with the WIPP pre-Permit waste characterization program, 2. Presents the results of a risk analysis of the currently emplaced wastes. Expected and bounding risks from routine operations and possible accidents are evaluated; and 3. Provides conclusions and recommendations.
All the tests have been finished up in the Waste Management and Disposal Facility which has been used for the safety tests of solidified radioactive waste on sea dumping disposal. The decommissioning of this facility was performed for use of radioisotopes. This report describes the plan on decommissioning of facility for use of radioisotopes, the contamination checking methods and measurement of radioactivity, the fore case and practice for amount of generated radioactive wastes, the operation procedures for dismantlement, the safety measures, the expenses for decommissioning and so on. (author)
The present report is final report from a study on characterisation of radioactive waters in the Nordic countries. The study has mainly been focused on long-lived low and intermediate level radioactive waste. Methods to measure or estimate the activity content and the general composition are discussed. Recommendations are given regarding characterisation of waste under treatment and characterisation of already produced waste packages. (au).
The Joint Convention on the Safety of Spent Fuel management and on the Safety of Radioactive Waste Management is the first legal instrument to directly address the safety of spent fuel and radioactive waste management on a global scale. The Joint Convention entered into force in 2001. This paper describes its process and its main achievements to date. The perspectives to establish of a Global Waste Safety Regime based on the Joint Convention are also discussed. (authors)
More important than waste generation numbers, the pollution prevention and waste minimization successes achieved at Hanford in 1993 have reduced waste and improved operations at the Site. Just a few of these projects are: A small research nuclear reactor, unused and destined for disposal as low level radioactive waste, was provided to a Texas University for their nuclear research program, avoiding 25 cubic meters of waste and saving $116,000. By changing the slope on a asphalt lot in front of a waste storage pad, run-off rainwater was prevented from becoming mixed low level waste water, preventing 40 cubic meters of waste and saving $750,000. Through more efficient electrostatic paint spraying equipment and a solvent recovery system, a paint shop reduced hazardous waste by 3,500 kilograms, saving ...
The thermonuclear reactivity of deuterium(D) - tritium(T) fusion plasma with spin-polarized fuel has been studied. Two mechanisms of depolarization, collisions and waves, in the high temperature fusion plasma have been considered. The binary collisions have been found not to change the nuclear spin states. The waves with a frequency of a few GHz, however, changes the spin states appreciably, when {delta}B/B{sub 0} (the ratio of the amplitude of the fluctuating magnetic field to the external field) becomes larger than 10{sup -5}. (author)
Reactive sticking coefficients (RSCs) were measured for silane and disilane on polycrystalline silicon for a wide range of temperature and flux (pressure) conditions. The data were obtained from deposition-rate measurements using molecular beam scattering and a very low-pressure cold-wall reactor. The RSCs have nonlinear Arrhenius temperature dependencies and decrease with increasing flux at low (710 /sup 0/C) temperatures. Several simple models are proposed to explain these observations. The results are compared with previous studies of the SiH/sub 4//Si(s) reaction and low-pressure chemical vapor deposition-rate measurements.
The removal of Reactive Black 5 dye in an aqueous solution by electrocoagulation (EC) as well as addition of flocculant was investigated. The effect of operational parameters, i.e. current density, treatment time, solution conductivity and polymer dosage, was investigated. Two models, namely the artificial neural network (ANN) and the response surface method (RSM), were used to model the effect of independent variables on percentage of dye removal. The findings of this work showed that current density, treatment time and dosage of polymer had the most significant effect on percentage of dye removal (p0.8). PMID:21411950
The 'Electrochemical Potentiokinetic Reactivation' method has been employed to quantify the degree of intergranular corrosion of Alloy 800, with different Ti + Al content, aged in the range 500-650/sup 0/C for times up to 5000 hours. The results were compared with the classical Rollason's curves obtained by means of the Strauss' test and a satisfactory agreement was found. An explanation of the slight differences between both methods has been proposed on the basis of the passivity film morphology.
Various schemes of cooling have been investigated for the purpose of assessing potential benefits on the operational characteristics of the Syrian MNSR reactor. A detailed thermal hydraulic model for the analysis of MNSR has been developed. The analysis shows that an auxiliary cooling system, installed in the pool which surrounds the lower section of the reactor vessel, will significantly offset the consumption of excess reactivity due to the negative reactivity temperature coefficient, Hence, the maximum operating time of the reactor is extended. Compared with experimental data, the suggested model proves to be valid for the analysis of MNSR behavior under both steady state and transient conditions. (author)
A probabilistic method for assessing the profitability of reactive power compensation devices such as capacitors, static VAR compensators and generators, which improve network security, was described. Since network development is limited by environmental constraints, power networks are operated close to their limits. Because of this fact transmission network planning increasingly relies on techno-economic models to improve network security and profitability. The proposed method consists of analyzing large numbers of constrained power system states, extracted from power system simulation exercises. The paper describes details of the method and provides an example of a numerical application on a part of the French power transmission system. 10 refs., 8 figs.
The results of an investigation of the effects of several parameters on the reactivity instability of a Boiling Water Reactor (BWR) calculational model are summarized. Calculations were performed for a typical BWR operated at low flow conditions, where reactivity instabilities are more likely to occur. The parameters investigated include the axial power shape (characterized by two separate parameters), the core pressure, and operating flow. All calculations were performed using the LAPUR code which was developed at the Oak Ridge National Laboratory for the dynamic modeling of large BWR's. 4 refs., 8 figs.
One important factor frustrating optimal management of Department of Energy (DOE)-complex wastes is the inability to use licensed and permitted facilities systematically. Achieving the goal of optimal use of DOE`s waste management facilities is politically problematic for two reasons. First, no locale wants to bear a disproportionate burden from DOE wastes. Second, the burden imposed by additional wastes transported from one site to another is difficult to characterize. To develop a viable framework for equitably distributing these burdens while achieving efficient use of all DOE waste management facilities, several implementation and equity issues must be addressed and resolved. This paper discusses stakeholder and equity issues and proposes a framework for joint research and action that could facilitate equity negotiations among stakeholder and move toward a more optimal use of ...
The Low-Level Radioactive Waste Forum is an association of representatives of states and compacts established to facilitate state and compact commission implementation of the Low-Level Radioactive Waste Policy Act of 1980 and the Low-Level Radioactive Waste Policy Amendments Act of 1985 and to promote the objectives of low-level radioactive waste regional compacts. The Forum provides an opportunity for states and compacts to share information with one another and to exchange views with officials of federal agencies. The Forum participants include representatives from regional compacts, designated host states, unaffiliated states, and states with currently-operating low-level radioactive waste facilities. This report contains information synthesizing the accomplishments of the Forum, as well as any new advances that have been made in the management of low-level radioactive ...
This engineering report compiles information on types and quantities of liquid waste discharged from B-Plant directly to cribs, ditches, reverse wells, etc., that are associated with B-Plant. Waste discharges to these cribs via overflow form 241-B, 241-BX, and 241-BY tank farms, and waste discharged to these cribs from sources other than B-Plant are discussed.Discharges from B-Plant to other cribs, unplanned releases, or waste remaining in tanks are not included in the report. Waste stream composition information is used to predict quantities of individual chemicals sent to cribs. This provides an accurate mass balance of waste streams from B-Plant to these cribs. These predictions are compared with known crib inventories as a verification of the process.
Waste is a cost of doing business. This cost can be considered in terms of the potential adverse health and environmental impacts, or the waste management costs associated with avoiding, minimizing, and controlling those impacts. There is an anticipated increase in the cost of waste management as a result of the increasing requirements for regulatory compliance. To meet the total waste management capacity needs of the organization and the compliance requirements, low-level radioactive, hazardous, and mixed waste management will need demonstrated technologies strategically managed as a technology portfolio. The role of the decision maker is to select the optimum mix of technologies and facilities to provide the waste management capacity needed for the next twenty years. The waste management system resulting from this mix includes multiple ...
For prolonged storage and eventual disposal radioactive wastes will be solidified to reduce the problems which accompany liquid waste whilst solid wastes will be encapsulated in an immobilising matrix. In the solidification and encapsulation process it will be important to produce a material in a form which is chemically stable, mechanically strong and which will not react with or allow free passage of groundwater. To this end a continuous check will be required to ensure that the various wastes are chemically compatible with the solidifying and binding matrices and that the associated processes are performed against a strict Quality Programme. The Quality Programme will be extensive requiring the specification of procedures for assessing the quality and nature of the wastes, the detailed operation of the solidification and/or encapsulation, the overpack requirements for ...
This paper presents the status of the Los Alamos National Laboratory (LANL) project for remediation of transuranic (TRU) and TRU mixed waste from Pads 1, 2, and 4. Some of the TRU waste packages retrieved from Pad I are anticipated to be part of LANL`s initial inventory to be shipped to the Waste Isolation Pilot Plant (WIPP) in April 1998. The TRU Waste Inspectable Storage Project (TWISP) was initiated in February 1993 in response to the New Mexico Environment Department`s (NMED`s) Consent Agreement for Compliance Order, ``New Mexico Hazardous Waste Agreement (NMHWA) 93-03.`` The TWISP involves the recovery of approximately 16,865 TRU and TRU-mixed waste containers currently under earthen cover on Pads 1, 2, and 4 at Technical Area 54, Area G, and placement of that waste into inspectable storage. All waste will be moved ...
Two of the US Department of Energy's (DOE) nuclear waste management-related goals are to ensure that waste management is not an obstacle to the further development of light-water reactors and the closure of the nuclear fuel cycle and to fulfill its institutional responsibility for providing safe storage and disposal of existing and future nuclear wastes. As part of its approach to achieving these goals, the Office of Remedial Action and Waste Technology of DOE established what is now called the Nuclear Waste Treatment Program (NWTP) at the Pacific Northwest Laboratory during the second half of FY 1982. To support DOE's attainment of its goals, the NWTP is to provide technology necessary for the design and operation of nuclear waste treatment facilities by commercial enterprises as part of a licensed waste management system ...
The Rocky Flats Plant (RFP) generates large volumes of a low level aqueous waste stream high in nitrate salts. The aqueous waste is concentrated by evaporation and then mixed with Portland cement prior to transport and disposal. Planned process upgrades include a new horizontal thin film evaporator. Temperature of brine at discharge end of the new evaporator will be near boiling point. Introduction of hot water to cement can degrade the monolithic waste form. However, the RFP salt waste contains high concentrations of compounds known to retard hydration. This paper discusses impact of introducing high temperature waste to cement. The study evaluated three waste compositions: (1) highest probable nitrate composition, (2) highest probable chloride composition, and (3) current composition. Results showed that compressive strength of final waste ...
The Rocky Flats Plant (RFP) generates large volumes of a low level aqueous waste stream high in nitrate salts. The aqueous waste is concentrated by evaporation and then mixed with Portland cement prior to transport and disposal. Planned process upgrades include a new horizontal thin film evaporator. Temperature of brine at discharge end of the new evaporator will be near boiling point. Introduction of hot water to cement can degrade the monolithic waste form. However, the RFP salt waste contains high concentrations of compounds known to retard hydration. This paper discusses impact of introducing high temperature waste to cement. The study evaluated three waste compositions: (1) highest probable nitrate composition, (2) highest probable chloride composition, and (3) current composition. Results showed that compressive strength of final waste ...
The Department of Energy currently has over 100 million liters of high-level radioactive waste in storage at the Savannah River Site (SRS). In the late 1970's, the Department of Energy recognized that there were significant safety and cost advantages associated with immobilizing the high-level waste in a stable solid form. Several alternative waste forms were evaluated in terms of product quality and reliability of fabrication. This evaluation led to a decision to build the Defense Waste Processing Facility (DWPF) at SRS to convert the easily dispersed liquid waste to borosilicate glass. In accordance with the NEPA (National Environmental Policy Act) process, an Environmental Impact Statement was prepared for the facility, as well as an Environmental Assessment of the alternative waste forms, and issuance of a Record of Decision (in December, 1982) on ...
The Department of Energy currently has over 100 million liters of high-level radioactive waste in storage at the Savannah River Site (SRS). In the late 1970`s, the Department of Energy recognized that there were significant safety and cost advantages associated with immobilizing the high-level waste in a stable solid form. Several alternative waste forms were evaluated in terms of product quality and reliability of fabrication. This evaluation led to a decision to build the Defense Waste Processing Facility (DWPF) at SRS to convert the easily dispersed liquid waste to borosilicate glass. In accordance with the NEPA (National Environmental Policy Act) process, an Environmental Impact Statement was prepared for the facility, as well as an Environmental Assessment of the alternative waste forms, and issuance of a Record of Decision (in December, 1982) on the ...
Many Pacific Basin countries rely on oil for electricity production. Alternative fuel sources such as coal, which is available in the Pacific Basin, can help mitigate adverse impacts of sudden price increases or supply disruptions. Coal combustion produces solid and potentially hazardous wastes of concern to environmental regulators and utility managers. This paper identifies issues associated with managing coal combustion wastes in the Pacific Basin, using the state of Hawaii as a case study. Hawaii is typical of many Pacific Basin locations in that it depends on oil, has limited sites, for waste management operations, and is subject to domestic and international waste management regulations. The paper discusses coal-fired utility wastes, environmental impacts of coal combustion waste disposal, and regulatory requirements that impact coal ...
A reliability approach for probabilistic modeling of one-dimensional non-reactive and reactive transport in porous media provides two important quantitative results: (1) an estimate of the probability that dimensionless concentration equals or exceeds some specified level and, (2) the sensitivity of the probabilistic outcome to likely changes in each uncertain variable. The reliability approach is particularly attractive because it can incorporate various marginal probability density functions (PDF) for any of the uncertain variables. In this work uncertain variables include: groundwater flow velocity, diffusion coefficient, dispersivity, distribution coefficient, porosity and bulk density. The primary objective is to examine how the probabilistic outcome is influenced by choice of marginal PDF, correlation and magnitude of uncertainty for the variables. Because little information exists concerning the statistical characteristics of these ...
The efficiency of basic, direct and reactive dye removal from water by narrow-leaved cattail (NLC) powder treated with distilled water (DW-NLC), 37% formaldehyde+0.2 N sulfuric acid (FH-NLC), or 0.1 N sodium hydroxide (NaOH-NLC) at various pH levels (3, 5, 7, and 9) was tested. Desorption of the adsorbed dyes was also investigated. The type of NLC treatment and pH of the dye solution had little effect on removal of basic dyes, and efficiencies ranged from 97% to 99% over the range of pH used. Over a wide range of pH levels, all types of treated cattail powder had negative charges and probably attracted the basic dyes possessing positive charges. Efficiency of removal by the three NLC treatments ranged from 37% to 42% for direct dyes and from 22% to 54% for direct dyes at pH 7. The pH of the dye solution had substantial effects on the efficiency of removal in direct and reactive dyes. Dye removal was highest at pH 3, with 99% for a direct dye ...
Yucca Mountain in Nevada represents the proposed solution to what has been a lengthy national effort to dispose of high-level radioactive waste, waste which must be isolated from the biosphere for tens of thousands of years. This chapter reviews the background of that national effort and includes some discussion of international work in order to provide a more complete framework for the problem of waste disposal. Other chapters provide the regional geologic setting, the geology of the Yucca Mountain site, the tectonics, and climate (past, present, and future). These last two chapters are integral to prediction of long-term waste isolation.
In recent years, there has been increasing demand for resource-recycling of waste plastic, especially due to the introduction of legislation on recycling of materials used for packages of household goods. Methods of recycling waste plastic from household goods are currently still under development, and appropriate techniques to deal with such waste are required. Toshiba has developed a technique to dehydrochlorinate plastic containing polyvinyl chloride (PVC). This paper introduces our petrolization and dehydrochlorination system for waste plastic containing PVC. (author)
There is a model on the Oak Ridge Reservation which provides requirements for determining capacities and capabilities related to low-level, hazardous, and mixed wastes. In FY 1987, the model will be sufficiently advanced to provide various waste management scenarios. These scenarios will be compared technically, operationally, and financially by use of waste characterization data and process simulators that are currently under development. The results of the process simulations will be used to help identify waste treatment, storage, and disposal technologies that need to be demonstrated prior to full-scale development for DOE use. The information derived from this effort will be made available to all DOE facilities.
A method for encapsulating and immobilizing waste for disposal. Waste, preferably, biologically, chemically and radioactively hazardous, and especially electronic wastes, such as circuit boards, are placed in a crucible and heated by microwaves to a temperature in the range of approximately 300{degrees}C to 800{degrees}C to incinerate organic materials, then heated further to a temperature in the range of approximately 1100{degrees}C to 1400{degrees}C at which temperature glass formers present in the waste will cause it to vitrify. Glass formers, such as borosilicate glass, quartz or fiberglass can be added at the start of the process to increase the silicate concentration sufficiently for vitrification.
This document presents the basic Quality Assurance (QA) requirements which shall be included in the Quality Assurance Program established by sites planning to certify Transuranic (TRU) Waste to Waste Isolation Pilot Plant (WIPP) Waste Acceptance Criteria. These QA requirements were modeled after ANSI/ASME NQA-1-1979. The application of quality assurance to Waste Certification Programs is required by WIPP-DOE-069 and DOE Order 5700.6A, as implemented by DOE Order AL 5700.6A.
The Waste Acceptance Preliminary Specifications (WAPS) require that the DWPF estimate the inventory of long-lived radionuclides present in the waste glass, and report the values in the Waste Form Qualification Report. In this report, conservative (biased high) estimates of the radionuclide inventory of glass produced from waste currently in the Tank Farm are provided. In most cases, these calculated values compare favorably with actual data. In those cases where the agreement is not good, the values reported here are conservative.
In a treatment system of radioactive waste solution including sodium sulfate generated from a boiling water type nuclear reactor, waste solution is fed into a thin film evaporator where the waste solution is evaporated and made into powder while precipitating in a peripheral surface of the evaporator vessel. The surface of the precipitated solid is wiped by rotating wiper blades and removed off as radioactive solid powder. The rotational speed of a rotor to which the wiper blades are secured is controlled at a minimum and necessary rotational speed which contributes to make the waste solution into the powder so that the rate of worn out of the wiper blade is decreased.
This document establishes the minimum training requirements for the Plutonium Finishing Plant (PFP) personnel who are responsible for management of dangerous waste. The training plan outlines training requirements for handling of solid dangerous waste during generator accumulation and liquid dangerous waste during treatment and storage operations. The implementation of this training plan will ensure the PFP facility compliance with the training plan requirements of Dangerous Waste Regulation. Chapter 173-303-330. Washington Administrative Code (WAC). The requirements for such compliance is described in Section 11.0 of WHC-CM-7-5 Environmental Compliance Manual.
In October 1992, the US Department of Energy, Richland Field Office (RL) requested that Westinghouse Hanford Company (WHC) respond to a letter from EM-331 asking for completion of a survey of items in storage but not categorized as waste (Roberts 1992). The letter contained an attachment with instructions on how to fill out the attached form and what to exclude from the survey (Appendix A). This report is a summary of the information from the response issued to RL. This report primarily is for use in estimating future waste volumes that may have been overlooked because of the nature of their classification as material not categorized as waste (MNCAW) (i.e., not yet declared Waste).
The ANDRA, the French national agency of radioactive wastes, is organizing today the information needs of tomorrow. The aim is to allow the future generations to have access to the knowledge of the existence of subsurface radioactive waste facilities and to understand the context and technologies of such facilities. The storage of this information is made on 'permanent paper', a high resistant paper with a lifetime of 600 to 1000 years. An updating of these data is made every 5 years for each waste disposal center. Another project, still in progress, concerns the memory management of deep geologic waste disposal facilities for which the time scale to be considered is of the order of millennia. (J.S.)
In January, 1985, the Government of Thailand sought assistance from the United States Trade and Development Program (USTDP) to undertake a feasibility study to review and update the solid waste management master plan, with particular emphasis to be placed on waste disposal methods. In April, 1985, the USTDP engaged the firm of Engineering and Economic Research, Inc. to carry out a definitional/prefeasibility study to assess the potential of a project for solid waste management and energy production using municipal solid waste as fuel.
An estimated 265 million tons of hazardous waste are generated annually in the United States. Traditional waste disposal methods are inadequate, and many are no longer environmentally acceptable. Still, the waste increases along with demands for clean, environmentally safe methods for dealing with it. Faced with these demands, many hazardous waste generators are turning for help to co-processing,'' technology that goes beyond a no-impact solution to one of net positive impact, both environmentally and economically. This paper describes co-processing.
The bituminzation of decontamination and ion exchange resin stripping wastes with four grades of asphalt was investigated to determine the effects of asphalt type on the properties of the final products. All waste forms deformed readily under light loads indicating they would flow if not restrained. It was observed in all cases that product leaching rates increased as the hardness of the asphalt used to treat the waste increased. If bituminization is adopted for any Ontario Hydro aqueous radioactive wastes they should be treated with soft asphalt to obtain optimum leaching resistance and mechanical stability during interim storage should be provided by a corrosion resistant container.
The anaerobic biogasification of organic wastes generates two useful products: a medium-Btu fuel gas and a compost-quality organic residue. Although commercial-scale digestion systems are used to treat municipal sewage wastes, the disposal of solid organic wastes, including municipal solid wastes (MSW), requires a more cost-efficient process. Modern biogasification systems employ high-rate, high-solids fermentation methods to improve process efficiency and reduce capital costs. The design criteria and development stages are discussed. These systems are also compared with conventional low-solids fermentation technology.
The paper presents the progress of the Radioactive Waste Management Plan which accompanies the Decommissioning Plan for research reactor WWR-S located in Magurele, Ilfov, near Bucharest, Romania. The new variant of the Decommissioning Plan was elaborated taking into account the IAEA recommendation concerning radioactive waste management. A new feasibility study for WWR-S decommissioning was also developed. The preferred safe management strategy for radioactive wastes produced by reactor decommissioning is outlined. The strategy must account for reactor decommissioning, as well as rehabilitation of the existing Radioactive Waste Treatment Plant and the upgrade of the Radioactive Waste Disposal Facility at Baita-Bihor. Furthermore, the final rehabilitation of the laboratories and reusing of cleaned reactor building is envisaged. An inventory of each type of radioactive ...
A review of the various solidification agents and techniques that are currently available or potentially applicable for the solidification of low-level radioactive wastes is presented. An overview of the types and quantities of low-level wastes produced is presented. Descriptions of waste form matrix materials, the wastes types for which they have been or may be applied and available information concerning relevant waste form properties and characteristics follow. Also included are descriptions of the processing techniques themselves with an emphasis on those operating parameters which impact upon waste form properties. The solidification agents considered in this survey include: hydraulic cements, thermoplastic materials, thermosetting polymers, glasses, synthetic minerals and composite materials. This survey is part of a program supported by the United States ...
Sodium nitrate waste has been successfully solidified in two types of polymeric materials: polyethylene, a thermoplastic material, and polyester styrene (PES), a thermosetting material. Waste form property evaluation tests such as ANS 16.1 leaching test and compressive strength measurements were performed on the waste forms containing various amounts of sodium nitrate. A single-screw extruder was employed for incorporating dry waste into polyethylene at its melt temperature of 120/sup 0/C to produce a homogenous mixture. Results of the leaching test for polyethylene waste forms containing 30, 50, 60 and 70 wt% sodium nitrate are presented as cumulative fraction leached and leaching indices ranging from 11 to 7.8. Two PES systems are discussed. The first is for solidification of dry salt wastes and the second is a water extendible system that is compatible with ...
recycling of waste polypropylene (WPP) and waste rubber (WR) originated from rejected worn-out tires present very important problem due to their huge amount and their negative impact on environment. many communities in the world are struggling with this problem of how to manage waste disposal, in order to eliminate or reduce waste rubber from the environment and to reduce costs of some rubber and polypropylene articles. trials to reuse waste rubber and waste polypropylene, have encountered some difficulties.such two substrate polymers differ from each other in nature, since waste polypropylene is thermoplastic while waste rubber exists in thermosetting state. accordingly, the study and use of their mixtures should be very interesting.the aim of this work is to modify the physical and chemical properties of WR and WPP ...
Features particular to the technology of using a blast furnace for the recycling of plastic waste are reported, and the behavior of plastic waste injected into a blast furnace is described. The plastic waste is injected into the furnace borne on a 1200degC hot blast through the tuyere. The plastic is converted into a reducing gas in the furnace, and the gas on its way up in the furnace is utilized as a reducing agent in the iron ore reducing reaction. The process is described below. All kinds of plastic waste may be utilized in this fashion, with the exception of polyvinyl chloride. As for polyvinyl chloride, efforts are under way to develop a technology to recycle this plastic. The method using the blast furnace tolerates a wide range of impurities, and the plastic waste is only to be crushed and granulated before use in the furnace. Plastic waste coarsely ...
The Oak Ridge National Laboratory (ORNL) is developing a treatment process for remote-handled (RH) liquid transuranic mixed waste governed by the concept of minimizing the volume of waste requiring disposal. This task is to be accomplished by decontaminating the bulk components so the process effluent can be disposed with less risk and expense. Practical processes have been demonstrated on the laboratory scale for removing cesium 137 and strontium 90 isotopes from the waste, generating a concentrated waste volume, and rendering the bulk of the waste nearly radiation free for downstream processing. The process is projected to give decontamination factors of 10{sup 4} for cesium and 10{sup 3} for strontium. Because of the extent of decontamination, downstream processing will be contact handled. The transuranic, radioactive fraction of the mixed waste stream will ...
Waste form dissolution studies and preliminary performance analyses were carried out to contribute a part of the data needed for the selection of a waste form for the disposal of Savannah River Plant defense waste in a deep geologic repository. The first portion of this work provides descriptions of the chemical interactions between the waste form and the geologic environment. We reviewed critically the dissolution/leaching data for borosilicate glass and SYNROC. Both chemical kinetic and thermodynamic models were developed to describe the dissolution process of these candidate waste forms so as to establish a fundamental basis for interpretation of experimental data and to provide directions for future experiments. The complementary second portion of this work is an assessment of the impacts of alternate waste forms upon the consequences of disposal in various ...
Atomic Energy of Canada Limited (AECL) operates the Waste Treatment Centre (WTC) to treat and immobilize some of the low- level radioactive waste (LLRW) streams at the Chalk River Laboratories (CRL). The WTC at treats low- level radioactive liquid waste by removing the contaminants from the wastewater, concentrating them, and immobilizing them. The fundamental design concept for the WTC is to process the waste streams using forced circulation type liquid waste evaporation (LWE), to solidify the concentrates using thin film evaporator and to discharge the purified effluent into the Ottawa River following verification monitoring. The solidified product drums are stored in existing storage facilities in the CRL. The LWE was installed in the WTC to treat the LLRW. After about four (4) years of design, construction and cold commissioning, the active commissioning of the evaporator ...
Atomic Energy of Canada Limited (AECL) operates the Waste Treatment Centre (WTC) to treat and immobilize some of the low- level radioactive waste (LLRW) streams at the Chalk River Laboratories (CRL). The WTC at treats low- level radioactive liquid waste by removing the contaminants from the wastewater, concentrating them, and immobilizing them. The fundamental design concept for the WTC is to process the waste streams using forced circulation type liquid waste evaporation (LWE), to solidify the concentrates using thin film evaporator and to discharge the purified effluent into the Ottawa River following verification monitoring. The solidified product drums are stored in existing storage facilities in the CRL. The LWE was installed in the WTC to treat the LLRW. After about four (4) years of design, construction and cold commissioning, the active commissioning of the evaporator ...
According to an American Petroleum Institute production waste survey reported on by P.G. Wakim in 1987 and 1988, the exploration and production segment of the US oil and gas industry generated more than 360 million barrels (bbl) of drilling wastes, more than 20 billion bbl of produced water, and nearly 12 million bbl of associated wastes in 1985. Current exploration and production activities are believed to be generating comparable quantities of these oil field wastes. Wakim estimates that 28% of drilling wastes, less than 2% of produced water, and 52% of associated wastes are disposed of in off-site commercial facilities. In recent years, interest in disposing of oil field wastes in solution-mined salt caverns has been growing. This report provides information on the availability of commercial disposal companies in oil-and gas-producing ...
This paper described the basic design of Alpha Aqueous Waste Treatment Process in NUCEF. Since various experiments using the TRU (transuranium) elements are carried out in NUCEF, wastes containing TRU elements arise. The liquid wastes in NUCEF are categorized into three types. Decontamination and volume reduction of the liquid waste mainly of recovery water from acid recovery process which has lowest radioactive concentration is the most important task, because the arising rate of the waste is large. The major function of the Alpha Aqueous Waste Treatment Process is to decontaminate the radioactive concentration below the level which is allowed to discharge into sea. Prior the process design of this facility, the followings are evaluated:property and arising rate of the liquid waste, room space to install and licensing condition. Considering ...
The U.S. Department of Energy (DOE)-Carlsbad Field Office (CBFO) has developed draft documentation to present the proposed Waste Isolation Pilot Plant (WIPP) remote-handled (RH-) transuranic (TRU) waste characterization program to its regulators, the U.S. Environmental Protection Agency and the New Mexico Environment Department. Compliance with Title 40, Code of Federal Regulations, Parts 191 and 194; the WIPP Land Withdrawal Act (PL 102-579); and the WIPP Hazardous Waste Facility Permit, as well as the Certificates of Compliance for the 72-B and 10-160B Casks, requires that specific waste parameter limits be imposed on DOE sites disposing of TRU waste at WIPP. The DOE-CBFO must control the sites' compliance with the limits by specifying allowable characterization methods. As with the established WIPP contact handled TRU waste characterization program, ...
The bibliography contains citations concerning waste treatment and disposal in the food processing industry. Methods, equipment, and technology are considered. References discuss waste heat recovery and examine treatment of wastes resulting from meat and seafood processing, dairy and beverage production, and fruit and vegetable processing. The citations explore conversion of the treated waste to fertilizer and for use in animal feeds, combustion for energy production, biogas production, and composting. The recovery and recycling of usable chemicals from the food waste are also covered. Food packaging recycling is considered in a related bibliography. (Contains 250 citations and includes a subject term index and title list.)
Many nations and international agencies are working to develop improved technology and industrial capability for neuclear fuel cycle and waste management operations. The effort in some countries is limited to research in university laboratories on treating low-level waste from reactor plant operations. In other countries, national nuclear research institutes are engaged in major programs in all phases of the fuel cycle and waste management, and there is a national effort to commercialize fuel cycle operations. Since late 1976, staff members of Pacific Northwest Laboratory have been working under US Department of Energy sponsorship to assemble and consolidate openly available information on foreign and international nuclear waste management programs and technology. This report summarizes the information collected on the status of fuel cycle and waste management programs in selected ...
Information about current and projected waste generation as well as available treatment, storage, and disposal (TSD) capabilities and needs is crucial for effective, efficient, and safe waste management. This is especially true for large corporations that are responsible for multisite operations involving diverse and complex industrial processes. Such information is necessary not only for day-to-day operations, but also for strategic planning to ensure safe future performance. This paper reports on some methods developed and successfully applied to obtain requisite information and to assist waste management planning at the corporate level in a nationwide system of laboratories and industries. Waste generation and TSD capabilities at selected US Department of Energy (DOE) sites were studied. 1 ref., 2 tabs.
Separation of the bulk soluble chemical salts from the insoluble metal hydroxides and radionuclides is central to the strategy of disposing Hanford tank waste. Sludge washing and caustic leaching have been selected as the primary methods for processing the 230 million L (61,000,000 gal) of Hanford tank waste. These processes are very similar to those selected for processing waste at the West Valley Site in New York and the Savannah River Site in South Carolina. The purpose of sludge washing is to dissolve and remove the soluble salts in the waste. Leaching of the insoluble solids with caustic will be used to dissolve aluminum hydroxide and chromium hydroxide, and convert insoluble bismuth phosphate to soluble phosphate. The waste will be separated into a high-level solids fraction and a liquid fraction that can be disposed of as low-level waste after cesium ...
In this report, research and development results on the bituminization of radioactive wastes are closely reviewed, especially those regarding waste treatment technologies, waste solidifying procedures and the characteristics of asphalt and solidified forms. A new concept of the bituminization method is suggested in this report which can improve the characteristics of solidified forms. Stable solid forms with high leach resistance, high thermal resistance and good compression strength were produced by the suggested bituminization method, in which spent polyethylene from agricultural farms was added. This report can help further research and development of improved bituminized forms of radioactive wastes that will maintain long term stabilities in disposal sites. (author). 59 refs., 19 tabs., 18 figs
After the publication of the 2nd progress report of geological disposal of TRU waste in Japan, policy and general scheme of future study for the waste disposal in Japan was published by ANRE and JAEA. This annual report summarized aim and progress of individual problem, which was assigned into JAEA in the published policy and general scheme. The problems are as follows; characteristics of TRU waste and its geologic disposal, treatment and waste production, quality control and inspection methodology for waste, mechanical analysis of near-field, data acquisition and preparation on radionuclides migration, cementitious material transition, bentonite and rock alteration in alkaline solution, nitrate effect, performance assessment of the disposal system and decomposition of nitrate as an alternative technology. (author)
The Soviet Union does not currently have an overall radioactive waste management program or national laws that define objectives, procedures, and standards, although such a law is being developed, according to the Soviets. Occupational health and safety does not appear to receive major attention as it does in Western nations. In addition, construction practices that would be considered marginal in Western facilities show up in Soviet nuclear power and waste management operations. The issues involved with radioactive waste management and environmental restoration are being investigated at several large Soviet institutes; however, there is little apparent interdisciplinary integration between them, or interaction with the USSR Academy of Sciences. It is expected that a consensus on technical solutions will be achieved, but it may be slow in coming, especially for final disposal of high-level radioactive ...
The Soviet Union does not currently have an overall radioactive waste management program or national laws that define objectives, procedures, and standards, although such a law is being developed, according to the Soviets. Occupational health and safety does not appear to receive major attention as it does in Western nations. In addition, construction practices that would be considered marginal in Western facilities show up in Soviet nuclear power and waste management operations. The issues involved with radioactive waste management and environmental restoration are being investigated at several large Soviet institutes; however, there is little apparent interdisciplinary integration between them, or interaction with the USSR Academy of Sciences. It is expected that a consensus on technical solutions will be achieved, but it may be slow in coming, especially for final disposal of high-level radioactive ...
The Department of Energy has issued a Quality Assurance (QA) specification for organizations involved in making a canistered high-level waste form product that is acceptable for storage in a deep geologic federal repository. The logic for the waste form acceptance process is described. In addition to NQA-1 requirements, fourteen supplemental QA requirements have been drafted to fit the waste form production process. A review plan for assuring complicance with the QA specification is provided. Guidelines for preparation of a waste form producer QA program are also presented. It is expected that the QA program description that result will be influential in supporting the acceptybility of the product to OCRWM and for ultimate disposal of the high-level waste in a deep geologic repository. (author) 3 figs., 4 refs.
A detergent-containing radioactive liquid waste originating from atomic power plants is concentrated to have about 10 wt. % detergent concentration, then dried in a thin film evaporator, and converted into powder. Powdered activated carbon is added to the radioactive waste in advance to prevent the liquid waste from foaming in the evaporator by the action of surface active agents contained in the detergent. The activated carbon is added in accordance with the COD concentration of the radioactive liquid waste to be treated, and usually at a concentration 2-4 times as large as the COD concentration of the liquid waste to be treated. A powdery product having a moisture content of not more than 15 wt. % is obtained from the evaporator, and pelletized and then packed into drums to be stored for a predetermined period.
A detergent-containing radioactive liquid waste originating from atomic power plants is concentrated to have about 10 wt. % detergent concentration, then dried in a thin film evaporator, and converted into powder. Powdered activated carbon is added to the radioactive waste in advance to prevent the liquid waste from foaming in the evaporator by the action of surface active agents contained in the detergent. The activated carbon is added in accordance with the COD concentration of the radioactive liquid waste to be treated, and usually at a concentration 2-4 times as large as the COD concentration of the liquid waste to be treated. A powdery product having a moisture content of not more than 15 wt. % is obtained from the evaporator, and pelletized and then packed into drums to be stored for a predetermined period.
In the spring of 1991, the Environmental Protection Agency, Region 10 (EPA), launched an investigation into tanker waste disposal practices for vessels discharging ballast water at the Alyeska Pipeline Services Company's Ballast Water Treatment (BWT) facility and marine terminal in Valdez, Alaska. It had been alleged that the Exxon Shipping Company was transferring 'toxic wastes originating in California' to Valdez. In response, EPA decided to examine all waste streams generated on board and determine what the fate of these wastes were in addition to investigating the Exxon specific charges. An extensive Information Request was generated and sent to the shipping companies that operate vessels transporting Alaska North Slope Crude. Findings included information on cargo and fuel tank washings, cleaning agents, and engine room waste.
Purpose: To enable the solidification of liquid waste containing radioactive substance in a free shape with large volume reduction ratio without a pulverizing step by producing solute in the liquid waste as a slurry in a predetermined organic solvent and forming it into a cake by mechanical exfoliation. Method: Liquid waste containing suitably concentrated radioactive substances is supplied to a centrifugal thin film evaporator together with an organic agent having a higher boiling point than water and a non aqueous solution to evaporate the water content, the solute in the waste is produced as a slurry in the organic solvent, and removed as cake-state solute slightly residued with the organic solvent by the mechanical exfoliation such as centrifugal exfoliation or settling exfoliation from the slurry-state liquid. Accordingly, it can be increased in size as compared with the powder reduced in volume of ...
Liquid radioactive waste treatment method of using evaporator was widely used from Kori 1 to Uljin 3 and 4, but a liquid radioactive waste treatment equipment that uses an ion exchange method instead of an evaporator was adopted aiming to minimize amount of radioactive waste and radiation exposure. However, the same equipment was introduced and applied for the first time in Korea and had experienced difficulties in securing credibility for the equipment and handling of liquid radioactive waste with inadequate data about performance and experience in operation and maintenance. In this study, examination, application and effect analysis was performed on the optimization measure for handling liquid radioactive waste of Yonggwang Nuclear Power Unit 5 and 6(YGN 5 and 6) that applies an ion exchange method
Negligent hazardous waste management has resulted in real threats to public health. The Federal Government has responded to the situation with laws and regulations aimed at the producers of hazardous waste, including clinical laboratories. The Resources Conservation and Recovery Act (RCRA) imposes controls on hazardous waste management through the Code of Federal Regulations (CFR). The Environmental Protection Agency (EPA) and the Department of Transportation (DOT) regulate these activities through 40 CFR and 49 CFR. Most clinical laboratories can operate satellite accumulation points and accumulate, store, transport, and dispose of waste in accordance with EPA and DOT regulations. Regulations pertaining to infectious waste, sure to affect many clinical laboratories, are being developed now by he EPA. The cradle to grave tracking system mandated by the Federal Government can be ...
The aim of this study is to compare, from an environmental point of view, different alternatives for the management of municipal solid waste generated in the town of Castellon de la Plana (Spain). This town currently produces 207ton of waste per day and the waste management system employed today involves the collection of paper/cardboard, glass and light packaging from materials banks and of rest waste at street-side containers. The proposed alternative scenarios were based on a combination of the following elements: selective collection targets to be accomplished by the year 2015 as specified in the Spanish National Waste Plan (assuming they are reached to an extent of 50% and 100%), different collection models implemented nationally, and diverse treatments of both the separated biodegrad...
Waste electrical and Electronic Equipment (WEEE) constitutes 4% of the municipal waste in Europe, being increased by 16-28% every five years. Nowadays, Europe produces 6,5 million tonnes of WEEE per year and currently 90% goes to landfill. WEEE waste is growing 3 times faster than municipal waste and this figure is expected to be increased up to 12 million tones by 2015. Applying a new technology to separate non-ferrous metal Waste from WEEE is the aim of this paper, by identifying multi-and hyper-spectral materials and inserting them in a recycling plant. This technology will overcome the shortcomings passed by current methods, which are unable to separate valuable materials very similar in colour, size or shape. For this reason, it is necessary to develop new algorithms able to distinguish among these materials and to face the timing requirements. (Author). 22 refs.
The Belgian radioactive waste management agency NIRAS/ONDRAF has undertaken a comparative assessment study on long-term waste management options for the high-level and/or long-lived radioactive waste that should be managed as a result of the use of nuclear energy in Belgium. This study is one of the supportive documents to a Strategic Environmental Assessment (SEA) process initiated end of 2008 and geared towards a decision in principle by the Belgian Government in 2010 on the long-term management of such radioactive waste. NIRAS/ONDRAF, together with Belgian and international research organisations, has developed a reference option for such high-level and long-lived radioactive waste, called Category B and C Waste, consisting of the disposal of such waste in a clay formation [SAFIR-2]. More than 30 years of R and D have been undertaken ...
In the past years I have been dealing with the following aspects of waste planning: a) waste reduction (regarding particularly home composting); b) transformation and reorganisation of waste collection systems; c) experimental introduction of a new way to pay for waste collection and treatment services, from ''tax'' to ''tariff''. In these years, I have been a consultant for municipalities in the planning of these three points. In the city (Venice) and in the Region I come from (''Veneto'') there are some of the most important Italian experiences about them. (orig).
Thermoplastic encapsulation has been extensively studied at Brookhaven National Laboratory`s (BNL) Environmental and Waste Technology Center (EWTC) as a waste encapsulation technology applicable to a wide range of waste types including radioactive, hazardous and mixed wastes. Encapsulation involves processing thermoplastic and waste materials into a waste form product by heating and mixing both materials into a homogeneous molten mixture. Cooling of the melt results in a solid monolithic waste form in which contaminants have been completely surrounded by a polymer matrix. Heating and mixing requirements for successful waste encapsulation can be met using proven technologies available in various types of commercial equipment. Processing techniques for thermoplastic materials, such as low density polyethylene (LDPE), are ...
At Los Alamos National Laboratory (LANL), a recent effort in waste minimization has focused on scrap metal from radiological controlled areas (RCAs). In particular, scrap metal from RCAs needs to be dispositioned in a reasonable and cost effective manner. Recycling of DOE scrap metals from RCAs is currently under a self-imposed moratorium. Since recycling is not available and reuse is difficult, often metal waste from RCAs, which could otherwise be recycled, is disposed of as low-level waste. Estimates at LANL put the cost of low-level waste disposal at $550 to $4000 per cubic meter, depending on the type of waste and the disposal site. If the waste is mixed, the cost for treatment and disposal can be as high as $50,000 per cubic meter. Disposal of scrap metal as low-level waste uses up valuable space in the low-level ...
This report discusses the safety approach of the Advanced Liquid Metal reactor program, sponsored by the US Department of Energy, which relies upon passive reactor responses to off-normal condition to limit power and temperature excursions to levels that allow safety margins. Gas expansion modules (GEM) have included in the design to provide negative reactivity to enhance these margins in the extremely unlikely event that pumping power is lost and the highly reliable scram system fails to operate. The feasibility and beneficial features of these devices were first demonstrated in the core of the Fast Flux Test Facility (FFTF) in 1986. Preapplication safety evaluations by the US Nuclear Regulatory Commission have identified areas that must be addressed if these devices are to be relied on. One of these areas is the response of the reactor when it is critical and the pumps are turned on, resulting in positive reactivity being added to the core. ...
The safety approach of the Advanced Liquid Metal Reactor program, sponsored by the U.S. Department of Energy, relies upon passive reactor responses to off-normal conditions to limit power and temperature excursions to levels that allow large safety margins. Gas expansion modules (GEM) have been included in the design to provide negative reactivity to enhance these margins in the extremely unlikely event that pumping power is lost and the highly reliable scram system fails to operate. The feasibility and beneficial features of these devices were first demonstrated in the core of the Fast Flux Test Facility (FFTF) in 1986. Pre-application safety evaluations by the U.S. Nuclear Regulatory Commission have identified areas that must be addressed if these devices are to be relied on. One of these areas is the response of the reactor when it is critical and the pumps are turned on, resulting in positive reactivity being added to the core. Tests to ...
An examination of chemical and radiological characteristics of RI organic liquid waste, wet oxidation by Fenton reaction and decomposition liquid waste treatment process were studied. These items will be applied to develop the equipment of wet oxidation and decomposition liquid waste treatment mixed processes for the safe treatment of RI organic liquid waste which is consisted of organic solvents such as toluene, alcohol and acetone. Two types of toluene solutions were selected as a candidate decomposition material. As for the first type, the concentration of toluene was above 20 vol percent. As for the second type, the solubility of toluene was considered. The decomposition ration by Fenton reaction was above 95 percent for both of them. From the adsorption equilibrium tests, a -Na{sup +} substituted/acid treated activated carbon and Zeocarbon mixed adsorbent was selected for the fixed adsorption ...
ObjectivesObjectives Not AvailableDescriptionA collaborative study of the anaerobic treatment of wastes containing recalcitrant and inhibitory compounds using the SERC Anaerobic facility, in particular biomass structure, monitoring and control, catabolism and toxicity, pre-acidification and microbial growth and mesophilic and thermophilic lignocellulose degradation.~%~
The Office of Civilian Radioactive Waste-Management in the Department of Energy (DOE) is responsible for disposing of this nation`s spent fuel and high-level radioactive waste in a manner that protects the health and safety of the public and the quality of the environment. Although embodied in the Federal repository program that began with studies in the late 1950s, this mission was explicitly established by the Nuclear Waste Policy Act of 1982 and reaffirmed by the Nuclear Waste Policy Amendments Act of 1987. To fulfill our mission, we are developing a waste management system consisting of a geologic repository for permanent disposal deep beneath the surface of the earth, a facility for monitored retrievable storage, and a system for transporting the waste. This discussion draft was developed to help involve parties affected by or interested in the ...
We have demonstrated that the SSSE pulverization process can convert multicomponent plastic waste into a powder with very promising properties. A variety of mixed color plastic chips have been pulverized.
Radionuclide X-ray fluorescence analysis was used for the determination of iron, calcium, potassium, copper, manganese and zinc in waste water from the production process of citric acid.
Radionuclide X-ray fluorescence analysis was used for the determination of iron, calcium, potassium, copper, manganese and zinc in waste water from the production process of citric acid. (author).
The calculated radioactive waste inventories of the Turkey Point pressurized water fission reactor (PWR) and the Starfire conceptual fusion tokamak are compared as a function of time from initial start-up to 10,000 years after decommissioning. Only materi...
This paper discusses the quality assurance requirements for high-level canistered waste form products which would be acceptable for disposal in a deep geologic repository. A review plan and guidelines are provided.
This two-volume proceedings summarize the results of fifteen innovations that were funded through the US Department of Energy`s Innovative Concept Program. The fifteen innovations were presented at the sixth Innovative Concepts Fair, held in Austin, Texas, on April 22--23, 1993. The concepts in this year`s fair address innovations that can substantially reduce or use waste streams. Each paper describes the need for the proposed concept, the concept being proposed, and the concept`s economics and market potential, key experimental results, and future development needs. The papers are divided into two volumes: Volume 1 addresses innovations for industrial solid waste processing and municipal waste reduction/recycling, and Volume 2 addresses industrial liquid waste processing and industrial gaseous waste processing. Individual reports are indexed separately.
Today`s industrial processes generate many types of waste products that constitute risks to human health and the surrounding environment. While proper waste management procedures can lower this risk, prevention of the waste`s generation will eliminate the risk. For this reason, the United States has established pollution prevention as a national objective, through the passage of its Pollution Prevention Act of 1990. Pollution prevention involves a wide range of approaches, all with the same objective: to reduce or eliminate the creation of waste at its source in other words, within the process that generates it. This objective, so beneficial to the environment, also coincides with industrial economic interests. Pollution prevention measures and greater process efficiency go hand in hand, and typically result in lower operating costs as well as greatly reduced waste management ...
The association of Finnish Plastics Industry examined the possibilities to utilize energy content of plastic wastes in spring 1990. A bark fuelled boiler plant of forest industry was used as test power plant. The power of the plant was 60 Mw. This report discusses shortly the theory of combustion of plastics. About 130 000-15 000 tons of plastic waste, corresponding to 7 % of the solid municipal waste, is dumped annually in Finland. Utilization of the plastic waste recovered from municipal wastes for energy production is technically viable in present power plants among present energy production. The chipping and mixing of the plastic in the other fuel are the only pretreatment required for the plastic waste. In Finland there are several power plants using suitable fuels for plastic mixture combustion. The portion of the plastic of the total fuel power was 10 %. ...
This report is organized in a fashion that is intended to explain the legal duties imposed on officials responsible for hazardous waste at each stage of its existence. Section 2 describes federal hazardous waste laws, explaining the legal meaning of hazardous waste and the protective measures that are required to be taken by its generators, transporters, and storers. In addition, penalties for violation of the standards are summarized, and a special discussion is presented of so-called imminent hazard provisions for handling hazardous waste that immediately threatens public health and safety. Although the focus of Sec. 2 is on RCRA, which is the principal federal law regulating hazardous waste, other federal statutes are discussed as appropriate. Section 3 covers state regulation of hazardous waste. First, Sec. 3 explains the system of state enforcement of the ...
The experiments at the incinerator for low-level wastes processing, (containing transuranium radionuclides) are described. Air decontamination factors and detector readings correction factors for efficiency and absorption are indicated.
The experiments at the incinerator for low-level wastes processing, (containing transuranium radionuclides) are described. Air decontamination factors and detector readings correction factors for efficiency and absorption are indicated.
This report reviews neurotoxicological principles relevant to situations of hazardous waste disposal. Some of the diagnostic techniques currently used for field assessment of nervous system dysfunction...Full Text Available
A testing program has been conducted by the Westinghouse Hanford Company to confirm the baseline waste form selection for use in Waste Receiving and Processing (WRAP) Module 2A. WRAP Module 2A will provide treatment required to properly dispose of containerized contact-handled, mixed low-level waste at the US Department of Energy Hanford Site in south-central Washington State. Solidification/stabilization has been chosen as the appropriate treatment for this waste. This work is intended to test cement-based, thermosetting polymer, and thermoplastic polymer solidification media to substantiate the technology approach for WRAP Module 2A. Screening tests were performed using the major chemical constituent of each waste type to measure the gross compatibility with the immobilization media and to determine formulations for more detailed testing. Surrogate materials representing each of ...
The aim of this work is to the application of a methodology to evaluate the energy associated to the industrial solid wastes in the metropolitan region of Campinas. The methodological route proposed is: the characterization of the research area and the production/management of the industrial solid wastes; the energetic classification and the qualitative/quantitative research of the energy associated to the industrial solid wastes; and, the valuation of the applicability of the energetic utilization mechanisms proposed to the region. This methodology when applied at the Campinas metropolitan region proved to be valid and it resulted in a synthetically presentation of the social and environmental reality of the industrial sector and the destination of the wastes, as well as it indicated the potentialities related to the energetic utilization of the industrial solid waste in the ...
The purpose of the methodology provided in this report is to select the optimal way to manage particular sets of waste streams from generation to disposal in a safe and cost-effective manner. The methodology described is designed to review the entire waste management system, assess its performance, ensure that the performance objectives are met, compare different LLW management alternatives, and select the optimal alternative. The methodology is based on decision analysis approach, in which costs and risk are considered for various LLW management alternatives, a comparison of costs, risks, and benefits is made, and an optimal system is selected which minimizes costs and risks and maximizes benefits. A ''zoom-lens'' approach is suggested, i.e., one begins by looking at gross features and gradually proceeds to more and more detail. Performance assessment requires certain information about the characteristics of ...
Logistics modeling is a powerful analytical technique for effective planning of waste storage, treatment, and disposal activities. Logistics modeling facilitates analyses of alternate scenarios for future waste flows, facility schedules, and processing or handling capacities. These analyses provide an increased understanding of the specific needs for waste storage, treatment, and disposal while adequate time remains to plan accordingly. They also help to determine the sensitivity of these needs to various system parameters. This paper discusses a logistics modeling system developed by the Pacific Northwest Laboratory (PNL) to aid in solid waste planning for a large industrial complex managing many different types and classifications of waste. The basic needs for such a system are outlined, and the approach adopted in developing the system is described. A key component of this ...
...The Political Evolution of the Landfill Tax in the UK wm-1996-03 Green Taxes, Waste Management and Political Economy 1995 ^ Top ...on civil engineering Lifecycle assessment - an overlooked opportunity Refereed Journal Articles: Green taxes, waste management and political economy Reports: Environmental cost benefit ...
The Defense TRU Waste Program (DTWP) is the focal point for the Department of Energy in national planning, integration, operation, and technical development for TRU waste management. The scope of this program extends from the point of TRU waste generation through delivery to a permanent repository. The TRU program maintains a close interface with repository development to ensure program compatibility and coordination. The defense TRU program does not directly address commercial activities that generate TRU waste. Instead, it is concerned with providing alternatives to manage existing and future defense TRU wastes. The FY 87 Program Plan is consistent with the Defense TRU Waste Program goals and objectives stated in the Defense Transuranic Waste Program Strategy Document, January 1984. The roles of participants, the responsibilities and ...
A corrosion-testing program has been initiated in Purex and Redox storage tnnks to obtain corrosion data on carbon steel and three associated materials in neutralized process wastes. (C.W.H.)
Aims: To investigate the exposure to dinitrotoluene (DNT) and trinitrotoluene (TNT) and the resulting effects in workers which occur during the disposal of military waste. Methods:...Full Text Available
This report estimates the economic and financial effects of compliance with the proposed effluent limitations guidelines and standards for the Centralized Waste Treatment (CWT) industry. The Environmental Protection Agency (EPA) has measured these impacts...
disposal through HC, and the effects of kerbside collection (KC) of recyclable materials, by measuring ...waste equivalent to 12 % could be attributed to HC and KC.Comparisons between the residual weight data for ...Control showed that the contributions of HC and KC to the overall reduction in residual waste were
A room-temperature process for stabilizing mineral waste streams has been developed, based on acid-base reaction between MgO and H3PO4 or acid phosphate solution. The resulting waste form sets into a hard ceramic in a few hours. In this way, various alumina industry wastes, such as red mud and treated potliner waste, can be solidified into ceramics which can be used as structural materials in waste management and construction industry. Red mud ceramics made by this process were low-porosity materials ({approx}2 vol%) with a compression strength equal to portland cement concrete (4944 psi). Bonding mechanism appears to be result of reactions of boehmite, goethite, and bayerite with the acid solution, and also encapsulation of red mud particles in Mg phosphate matrix. Possible applications include liners for ponds and thickned tailings disposal, dikes for waste ...
The development of structural barriers for nuclear waste packages involves selection of candidate materials, their screening by mechanical and corrosion testing, rigorous accelerated testing, and evaluation and comparison with other package elements. This document presents results from work conducted on titanium and ferrous alloys.
A suspension-firing type radioactive waste incineration system is developed and cold demonstration testing of ceramic filters for the system are carried out. The incineration system, which is useful for a wide variety of waste materials, can serve to simplify the facilities and to reduce the costs for waste disposal. The incineration system can be used for drying-processing of concentrated waste liquids and disposal of flame resistant materials including ion exchange resins and rubber, as well as for ordinary combustible solid materials. An on-line backwash system is adopted to allow the ceramic filters to operate stably for a long period of time. For one-step filtering using the ceramic filter, the decontamination factor is greater than 10"5 for the processing of various wastes. In a practical situation, there exist vapor produced by the spray drier and the cladding in used ion ...
This analysis, submitted in support of proposed effluent limitations guidelines and standards for the centralized waste treatment (CWT) industry, investigates the cost-effectiveness of 24 regulatory options, representing all possible combinations of nine ...
Chronic wasting disease (CWD) is a contagious, fatal prion disease of deer and elk that continues to emerge in new locations. To explore the means by which prions are transmitted with high efficiency...Full Text Available
The use of cement based systems for solidification and stabilization of hazardous wastes has been proposed. The stabilization of Cr contaminated paint removal wastes in ordinary Portland cement and in a Portland cement and blast furnace slag matrix was investigated. A loading by volume of 75% waste and 25% cement (or cement + slag) was used. The expression of pore solution was utilized to determine the chemical environment encountered by the waste species in the cement matrix. The highly alkaline conditions of ordinary Portland cement determined the stability of the metal species, with Cr being highly soluble. The replacement of 25% of the Portland cement by blast furnace slag was found to decrease the [OH-] of the pore solution resulting in a decrease of the Cr concentration. For cement wastes forms hydrated for 28 days, the Cr concentration decreased in the expressed pore ...
UK Nirex has announced four sites which it wishes to assess for the disposal of low-level and short-lived intermediate-level radioactive wastes. There is local opposition at all four of the potential sites. (U.K.).
On February 27, 1990, standards for Benzene were promulgated for benzene transfer and benzene waste operations. The benzene enabling document summarizes these standards. The basic purpose of the document is to assist the EPA regional enforcement personnel...
This report describes research performed by the Morgantown Energy Technology Center in the following areas: oil and gas; advanced systems describing a coal solid fuel and an eastern shale oil residue waste program; environmental remediation; and waste management technologies.
Secretariat of the Basel Convention United Nations Office at Geneva ...such as public utilities, waste disposal sites, large energy dependent facilities including factories, institutions (hospitals, ...it provides immediate identification of PCB wastes, informs company officials of any special handling or disposal techniques
The report gives an initial assessment of the feasibility of disposing of flue gas desulfurization wastes in mines and in the ocean. The purpose of the assessment was to evaluate environmental, technical, regulatory, and economic aspects of the use of such disposal sites. Availab...
The results of studies on: (1) development of suitable glass compositions for solidification and vitrification of high level radioactive wastes, and (2) the characteristics of these compositions, namely, leaching, mechanical properties, thermal conductivity, viscosity and homogeneity evaluation are reported. Inactive simulated purex waste was used for compositions reported herein. The data generated on leaching and other product characteristics of the selected vitrified waste products was used to evaluate the performance of corresponding experimental units and techniques with respect to their reproducibility and reliability.
The Systems Design Study (SDS) identified technologies available for the remediation of low-level and transuranic waste stored at the Radioactive Waste Management Complex's Subsurface Disposal Area at the Idaho National Engineering Laboratory. The SDS study intentionally omitted the costs of transportation and disposal of the processed waste and the cost of decommissioning the processing facility. This report provides a follow-on analysis of the SDS to explore the basis for life-cycle cost segments of transportation, disposal, and facility decommissioning; to determine the sensitivity of the cost segments; and to quantify the life-cycle costs of the 10 ex situ concepts of the Systems Design Study.
The Systems Design Study (SDS) identified technologies available for the remediation of low-level and transuranic waste stored at the Radioactive Waste Management Complex`s Subsurface Disposal Area at the Idaho National Engineering Laboratory. The SDS study intentionally omitted the costs of transportation and disposal of the processed waste and the cost of decommissioning the processing facility. This report provides a follow-on analysis of the SDS to explore the basis for life-cycle cost segments of transportation, disposal, and facility decommissioning; to determine the sensitivity of the cost segments; and to quantify the life-cycle costs of the 10 ex situ concepts of the Systems Design Study.
According to the Principles of Radioactive Waste Management, the IAEA SAFETY SERIES NO-111-F, IAEA declared 9 doctrines. The IAEA advised a country that operates nuclear power plant to adopt the principles. As a member of the IAEA, Korea has also discussed about a unified policy and enacting law for radioactive waste management to follow the doctrines. This study analyzed the recently enacted Korea Radioactive Waste Management Act and verified whether the Act successfully follows the doctrine or not
Purpose - The aim of the present study is to present in a systematic way the subject of industrial hazardous waste from the point-of-view of definitions in engineering, science and legislation. This analysis is necessary, as many different approaches and overlapping definitions are used for the classification of waste, leading to different results, a situation that often complicates the collection and interpretation of data on waste. Design/methodology/approach - The study is conducted by bringing together the extended experience of the authors and other experts in the field of environmental legislation and a wide variety of scientific and legislative sources as well as articles and research reports. The focus is the European Union, while several approaches from the international area are ...
Abstract: The Hanford Tanks Initiative (HTI) is a five-year project resulting from the technical and financial partnership of the U.S. Department of Energy`s Office of Waste Management (EM-30) and Office of Science and Technology Development (EM-50). The HTI project accelerates activities to gain key technical, cost performance, and regulatory information on two high-level waste tanks. The HTI will provide a basis for design and regulatory decisions affecting the remainder of the Tank Waste Remediation System`s tank waste retrieval Program.
This study examines the effects of blasting on waste dumps at open pit mining operations. Of specific concern were mining operations at the base of a five hundred foot high waste dump such as the operation at the South Pit of the Smoky-River Coal Ltd. property near Grande Cache, Alberta. An assessment of waste dump stability including factors such as quasi-static deformation behaviour, historical dump deformation behaviours and potential blasting effects was undertaken. It is concluded that safe blasting may be carried out in proximity to waste dumps, but monitoring of dump behaviour is recommended to ensure operational safety. 22 refs., 4 apps.
We developed the technology of using a waste plastic as fuel in the rotary kiln from reducing the fuel cost and recycling resource point of view. It has established based upon the research of a primary combustion characteristics on waste plastics, the research of the combustion mode of the fuel in the rotary kiln by simulation and the actual examination of kiln. The first rotary kiln equipped with the waste plastic injection system has been operating since 1994, and has achieved a good operating result. (author)
A major objective of the DOE Advanced Fuel Cycle Initiative, AFCI, is to explore technologies that may reduce the long-term environmental burden of nuclear energy through more efficient disposal of waste materials. In this work, the potential impact of the AFCI technology and its beneficial effects on waste management and its ability to meet waste management objectives are demonstrated. In addition, practical scenarios to improve permanent disposal utilization and/or reduce the temporary spent nuclear fuel (SNF) storage inventory by closing the fuel cycle through transition to fast reactor (FR) converters are also discussed. (authors)
A large amount of radioactive waste has been stored safely at the Savannah River and Hanford sites over the past 46 years. The aim of this report is to review the experimental corrosion studies at Savannah River and Hanford with the intention of identifying the types and rates of corrosion encountered and indicate how these data contribute to tank failure predictions. The compositions of the High-Level Wastes, mild steels used in the construction of the waste tanks and degradation-modes particularly stress corrosion cracking and pitting are discussed. Current concerns at the Hanford Site are highlighted.
An important component of the overall program to validate WIMS-AECL for use with RFSP in the analysis of CANDU-6 reactors for design and safety analysis calculations is the validation of calculations of incremental cross sections used to represent reactivity devices. A method has been developed for the calculation of the three-dimensional neutron flux distribution in and around CANDU reactor fuel channels and reactivity control devices. The methods is based on one- and two dimensional transport calculations with the WIMS-AECL lattice cell code, SPH homogenization, and three-dimensional flux calculations with finite-difference diffusion theory using the MULTICELL code. Simulations of Wolsung 1 Phase-B commissioning measurements and Point Lepreau restart tests have been performed, as a part of the program to validate WIMS-AECL lattice cell calculations for application to CANDU reactor simulations in RFSP. The incremental cross section properties ...
The dispersion of more than 20 vol pct submicrometer ceramic particles within a metallic matrix and the deposition of such a cermet to form a thick and tough coating presents problems. Most of the coating techniques have failed in attempting to homogeneously disperse very fine and hard particles in large amounts while avoiding their decomposition or reaction with the metal matrix during the deposition process. A simple and efficient method has been developed for producing ceramic-containing composite coatings. It consists in synthesizing cermet-based materials and in depositing them by a rapid solidification process, such as thermal spraying. Boride- and carbide-based materials have been successfully obtained by plasma spraying reactive powders comprising the basic reagents. These materials, with a microstructure of submicrometer ceramic particles dispersed in a metallic matrix, exhibit good wear-resistant properties (abrasion and sliding wear). Finally, ...
The reaction of the retinylidene Schiff base in bacteriorhodopsin (bR) to the water-soluble reagent hydroxylamine is enhanced by greater than 2 orders of magnitude under illumination. We have used this reaction as a probe for changes in Schiff base reactivity during the photocycle of wild-type bR and mutants defective in proton transport. We report here that under illumination at pH 6, the D85N mutant has a 20-fold lower rate and the D212N mutant has a greater than 4-fold higher rate for the light-dependent reaction with hydroxylamine compared with wild-type bR. In contrast, the reactivities of wild-type bR and the D96N and T46V mutants are similar. It has been previously shown that the D96N and T46V replacements have no significant effect on the kinetics of M formation but have dramatic effects on rate of the decay of M. We therefore conclude that the hydroxylamine reaction occurs before formation of the M intermediate. Most likely it occurs ...
The reactive evaporation process was successfully used to deposit films of the A-15 Nb_3Ge phase. This is the first report, to the best of our knowledge, illustrating the use of such processes for the deposition of A-15 compounds. In this process, niobium vapors from an electron-beam-heated evaporation source react with germane gas introduced into the vacuum chamber at low partial pressures (approximately 10"-"4 Torr) to produce Nb_3Ge deposits. The process variables studied were the deposition temperature, the niobium-to-germanium impingement ratio on the substrate and the plasma-enhanced deposition, in this case the activated reactive evaporation process. At low deposition temperatures (below 450"0C) the deposit is amorphous (or microcrystalline) and can be crystallized to the Nb_3Ge phase by heat treatment, e.g. at 850"0C for 1 h in vacuum. The ratio of niobium to germanium in the deposit can be varied by changing the process parameters. The ...
A stochastic-convective reactive (SCR) transport method is developed for one-dimensional steady transport in physically heterogeneous media with nonlinear degradation. The method is free of perturbation amplitude limitations and circumvents the difficulty of scale dependence of phenomenological parameters by avoiding volume-averaged specifications of diffusive/dispersive fluxes. The transport system is conceptualized as an ensemble of independent convective-reactive streamlines, each characterized by a randomized convective velocity (or travel time). Dispersive effects are treated as a component of the randomness in the streamline velocity ensemble, so no explicit expression for hydrodynamic dispersive flux is written in the streamline transport equation. The expected value of the transport over the stream tube ensemble is obtained as an average of solutions to the reactive convection equation according to the stream tube ...
This Environmental Assessment evaluates the proposed action to operate two laboratory-size muffle furnaces in glovebox HC-21C, located in the Plutonium Finishing Plant (PFP), Hanford Site, Richland, Washington. The muffle furnaces would be used to stabilize chemically reactive sludges that contain approximately 25 kilograms (55 pounds) of plutonium by heating to approximately 500 to 1000{degrees}C (900 to 1800{degrees}F). The resulting stable powder, mostly plutonium oxide with impurities, would be stored in the PFP vaults. The presence of chemically reactive plutonium-bearing sludges in the process gloveboxes poses a risk to workers from radiation exposure and limits the availability of storage space for future plant cleanup. Therefore, there is a need to stabilize the material into a form suitable for long-term storage. This proposed action would be an interim action, which would take place prior to completion of an Environmental Impact ...
This final report summarizes the results of our research under Contract No. DE-AC22-92PC92112, Novel Catalysts for Methane Activation. In this research we prepared and tested fullerene soots for converting methane into higher hydrocarbons. We conducted the methane conversions using dehydrocoupling conditions, primarily in the temperature regimes of 600{degrees}-1000{degrees}C and atmospheric pressures. The research was divided into three sections. The first section focused on comparing fullerene soots with other forms of carbon such as acetylene black and Norit-A. We found that the fullerene soot was indeed more reactive than the other forms of carbon. However, due to its high reactivity, it was not selective. The second section focused on the effect of metals on the reactivity of the soots, including both transition metals and alkali metals. We found that potassium could enhance the selectivities of fullerene soot to ...
Under typical conditions found in Pressurized Fluidized Bed Combustion (PFBC), the calcination reaction of limestones is thermodynamically inhibited, and the sorbent reacts with SO{sub 2} by a direct mechanism. Direct sulfation reactivity of different Spanish sorbents was studied by high-pressure thermogravimetric analysis. It was found that the physical structure of the surface of the particles influence the sulfation behaviour of the sorbents. Total pore volume and pore surface area correlated well with the reactivity of the sorbents. Temperatures between 800 and 925{degree}C, and pressure between 12 and 25 bar, promoted an increase in reactivity, while the gas composition had no effect when changed from 15% CO{sub 2}, 3% O{sub 2}, 0.5% SO{sub 2}, balance N{sub 2} to 12% CO{sub 2}, 7% O{sub 2}, 0.5% SO{sub 2}, balance N{sub 2}. It was found that the unreacted shrinking core model could not satisfactorily describe the ...
The Fast Flux Test Facility (FFTF) was designed to test fast-reactor fuels and other nonfuel materials. In its 37 reactor cycles of operations, the FFTF reactor has performed very well and successfully completed all the irradiation testings with an operating efficiency factor as high as 98%. Since FFTF is an experimental reactor, its core loading changed from cycle to cycle. Depending on the number of test assemblies in the core and their location, the core loading can change significantly from an essentially homogeneous core loading to a relatively nonhomogeneous or even highly localized heterogeneous loading. Consequently, the core reload design and initial criticality analyses were required for each operating cycle. The zero power initial critical control rod bank height was predicted before each reactor startup. The initial critical prediction depends on the reactivity conditions at the end of the previous cycle, the temperature feedback ...
The purpose of this study is to determine the suitability of producing agro-fiber reinforced plastic composite (agro-FRPC) from rubber wood fiber blended in polypropylene matrix. The effects of varying fiber dimension and fiber content on the physical and mechanical properties of the composite were evaluated to provide an insight into the fiber matrix adhesion. The effects of reactive additives on the physical and mechanical properties of the composite were evaluated which provides the insight on the reinforcement of the composite. Rubber wood fiber used in this study is currently being used in the manufacturing of medium density fiber (MDF) board. Two sizes of rubber wood fiber were used i.e. 0.5-1.0 mm and 1.0-2.0 mm. Homopolymer polypropylene of MFI 14.0 was used as a matrix. The irradiation work was carried out using electron beam accelerator, 3.0 MeV, 3.0 mA. Various types of reactive additives (RA) with mono-functional, di-functional, ...
Near-ideal Schottky barrier contacts to n-type Al0.22Ga0.78N have been developed by a two-step surface treatment technique. Plasma etching of the AlxGa1-xN surface prior to Schottky metal deposition, combined with sequential chemical treatment of the etched surface, holds promise for developing high quality low-leakage Schottky contacts for low noise applications and for recessed gate high electron mobility transistors. In this work, the effect of postetch chemical treatment of the n-type Al0.22Ga0.78N surface on the performance of the Ni/Au based Schottky contact has been investigated. Three different types of chemical treatment: viz, reactive ion etching, reactive ion etching plus dipping in hot aqua regia, and reactive ion etching plus dipping in hot KOH, are studied. Detailed current-voltage studies of three different surface treated diodes and a comparison with as-deposited diodes reveal significant improvement in the ...
The bibliography contains citations concerning the use of dialysis in the treatment of wastewaters. Techniques for the removal of metals, ammonia, waste acids, nitrates, and phosphates are described. Special attention is given to the desalination of liquid wastes. Applications of this technology to the treatment of effluent from the agrochemical, petrochemical, tanning, and electroplating industries are discussed. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)
The waste monitoring system in use at Los Alamos National Laboratory`s Plutonium Facility, TA-55, is a computer-based system that proves real-time information on industrial effluents. Remote computers monitor discharge events and data moves from one system to another via a local area network. This report describes the history, system design, summary, instrumentation list, displays, trending screens, and layout of the waste monitoring system.
Radioactive wastes are generally classified into 3 type depending on their physical property: liquid, solid and gaseous type. State-of -the art concerning liquid waste treatment has already been published; KAERI/TR-1315/99. Solid wastes classification package and treatment method will be studied to effectively manage them during the practical decommissioning work. All of the spent fuel produced during the operation of the TRIGA Mark-2 and 3 have been transported to the US last year, 1998, according to the spent fuel management strategy set-up by the US government for the non-proliferation of nuclear energy. Solid wastes are mainly all equipment existing inside of the reactors, activated concrete among the bio-shielded concrete, pipes, pimps, resin filter and it's housings, heat-exchangers, liquid waste storage tanks, to radioactive waste storage ...
Current European and the US experiences in waste management are reviewed in the perspective of sustainable development. This publication questions the validity of the current approach taken by the Germany at ``closing the loop`` based on the example of packaging and packaging waste. The product item focus of current German legislation is compared with Danish and US approaches that are based on an integrated policy which covers the whole of waste generation and handling and is not product/item oriented. 1 fig., 2 tabs.
Research at the Savannah River Technology Center aided development of a technical design basis for a Waste Treatment Plant (WTP) to pre-treat and vitrify Hanford tank waste as part of the River Protection Project (RPP). The research addresses safety concerns, process optimization, and waste form compliance. This program will provide technical data to ensure that the process functions as it was designed and minimizes costs.
such as public utilities, waste disposal sites, large energy dependent facilities including factories, institutions ( ...provides immediate identification of PCB wastes, informs company officials of any special handling or disposal techniques ...provides immediate identification of PCB wastes, informs company officials of any special handling or disposal techniques
The paper industry needs alternative waste disposal methods rather than dumping sites. The combustion properties of these waste materials make them suitable for thermal disposal. A process has been developed in which the waste materials are burnt on an oscillating bar grate without supplying external energy. Electrical energy and process steam are generated while small amounts of a sintered slag remain behind. (orig.).
This document contains eleven papers on various aspects of low-level radioactive waste regulation. Topics include: EPA environmental standards; international exemption principles; the concept of below regulatory concern; envirocare activities in Utah; mixed waste; FUSRAP and the Superfund; and a review of various incentive programs. Individual papers are processed separately for the data base. (TEM)
Pollutants resulting from the management of solid waste have been shown to affect the air, land, oceans, and waterways. In addition, solid wastes have other, more indirect impacts such as reduction in feedstocks of natural resources, because useful materials are disposed of rather than recycled. The objective of this study is to evaluate solid waste management practices that have negative implications on the global environment and develop recommendations for reducing such impacts. Recommendations identifying needed changes are identified that will reduce global impacts of solid waste practices in the future. The scope of this study includes the range of non-hazardous solid wastes produced within our society, including municipal solid waste (MSW) and industrial solid waste (ISW), as well as industry-specific wastes from ...
The IWA and ISWA congresses organized in Paris in july showed the latest research developments in the field of water and wastes management. The water sector is more mature than the waste sector but for both a closer association of the public and private is increasing. A summary of the presentations in successively the water and the wastes management is proposed bringing an analysis of the international situation and regulations. (A.L.B.)
Full text.This study focuses on the management of municipal solid waste (MSW) in Lebanon. It addresses the current status of MSW management in Lebanon in terms of collection, transport and disposal, infers the associated impacts of such practices and discusses mitigation measures and finally proposes basic guidelines for a national strategy for solid waste management in the country. The study is based on available previous investigations and on a field survey of 113 villages in four different countries. The study revealed the absence of an effective environmental policy and poor collection and disposal methods throughout the country, except for the Greater Beirut Area (G A), where better solid waste management practices are employed. Although collection of MSW outside GBA was found to be acceptable by local authorities, resources (labor and equipment) were not used efficiently. Furthermore, treatment of collected ...
A range of lessons have been identified from previous attempts to implement long term radioactive waste management policy in the UK and internationally. Many of these relate to the way the decision-making process is undertaken and the fact that there needs to be an open, transparent process that enables continuous stakeholder involvement. Nirex believes that using the SEA and EIA frameworks will help to incorporate the lessons learned into the future decision-making process relating to long-term radioactive waste management.
The mission of the Waste Management Institute is two-fold: (1) to enhance awareness and understanding of waste problems and their management in our society and, (2) to provide leadership in research, instruction and outreach to improve the quality of life on a global scale and protect the environment.
This product provides detailed data and graphics on airborne and liquid effluent releases, fuel oil consumption, and water usage for the calendar year 1990. It summarizes industrial waste data records compiled since 1971 for the Idaho National Engineering Laboratory (INEL). The data presented are from the INEL Industrial Waste Management Information System (IWMIS).
This document presents the details of the implementation of the Site Treatment Plan developed by Ames Laboratory in compliance with the Federal Facilities Compliance Act. Topics discussed in this document include: implementation of the plan; milestones; annual updates to the plan; inclusion of new waste streams; modifications of the plan; funding considerations; low-level mixed waste treatment plan and schedules; and TRU mixed waste streams.
Research programs from the following sections and programs are summarized: aquatic ecology, environmental resources, earth sciences, terrestrial ecology, advanced fossil energy program, toxic substances program, environmental impacts program, biomass, low-level waste research and development program, US DOE low-level waste management program, and waste isolation program.
...htm Waste Framework Directive 75/442/EEC (amended by Directive 91/156/EEC) and Waste Management Planning http://ec.europa.eu/environment/waste/plans/index.htm Selected EC commissioned/supported projects including LCA IPP Pilot Product exercise on mobile phones and on tropical garden furniture http://ec.europa.eu/environment/ipp/pilot.htm \\
We propose a system for the on-line monitoring of short and medium term radioactive waste repositories. Such a system is distributed, fine-grained, robust, reliable, and must be based on low-cost components. It could, in principle, open new perspectives on the modality of waste packaging and storage. In particular we propose to employ a new family of cheap and powerful micro sensors to be placed in shape of a fine grid around each single drum. (authors)
Most of the low-level liquid radioactive wastes generated from PWR plants are classified into high or low total suspended solid(HTDS or LTDS), radio-chemical waste and radioactive laundry waste. Although the evaporation process has a high decontamination ability, it has several problems such as corrosion, foaming, and congestion. A new liquid waste disposal process using the ion-exchange demineralizer(IED) has been introduced into the Yonggwang NPP 5 and 6 to complement the current evaporation process. To determine the differences, these two methods have been compared in this study. Those aspects compared here were the released radioactivity volume of the liquid radioactive wastes, The dose of off-site residents, the decontamination factor, and the amount of the solid radioactive wastes. While it was expected that the liquid radioactive ...
Even the presence of very low concentrations of dyes (1mgL-1) in the effluent is highly visible and is considered aesthetically undesirable. It must be removed from wastewater completely. This study systematically evaluates the performance of adsorption (three kinds of powdered activated carbons), coagulation (AlCl36H2O) and membrane (submerged hollow fiber microfiltration) processes individually in treating two kinds of reactive dyes (Orange 16 and Black 5) and then using a hybrid process with combined coagulation-adsorption-membrane treatment system. Adsorption capacity and kinetics of Orange 16 were much higher and faster than those of Black 5. The dye removal efficiency by coagulation was highly dependent on dye concentration and solution pH. The hybrid process performance was far more...
Wild and tissue cultured plants of Portulaca grandiflora Hook. have shown to be able to decolorize a sulfonated diazo dye Navy Blue HE2R (NBHE2R) up to 98% in 40h. A significant induction in the activities of lignin peroxidase, tyrosinase and DCIP reductase was observed in the roots during dye decolorization. The wild plants and tissue cultures could independently decolorize and degrade NBHE2R into metabolites viz. N-benzylacetamide and 6-diazenyl-4-hydroxynaphthalene-2-sulfonic acid. A dye mixture and a textile effluent were also decolorized efficiently by P. grandiflora. The phytotoxicity study revealed reduction in the toxicity due to metabolites formed after dye degradation.
The treatment of chronic pain conditions continue to present a challenge to the medical field. Physical therapy treatment needs to approach the management of chronic pain differently than the approach used to resolve acute pain. Patients with chronic pain often have many factors that have perpetuated the pain condition. These factors, as well as pain itself, influence their ability to reactivate and perform functional daily activities. Physical therapists can begin to address some of the factors, including fear and deconditioning, by building confidence and body awareness in a self-care model including a slow graduated reactivation program. There is evidence that patients with chronic pain conditions have altered motor control that may be influencing reoccurrences and possible flares of pa...
Nitric oxide (NO) and related molecules such as peroxynitrite, S-nitrosoglutathione (GSNO), and nitrotyrosine, among others, are involved in physiological processes as well in the mechanisms of response to stress conditions. In sunflower seedlings exposed to five different adverse environmental conditions (low temperature, mechanical wounding, high light intensity, continuous light, and continuous darkness), key components of the metabolism of reactive nitrogen species (RNS) and reactive oxygen species (ROS), including the enzyme activities L-arginine-dependent nitric oxide synthase (NOS), S-nitrosogluthathione reductase (GSNOR), nitrate reductase (NR), catalase, and superoxide dismutase, the content of lipid hydroperoxide, hydrogen peroxide, S-nitrosothiols (SNOs), the cellular level of N...
AbstractBackground In recent years nano-metaloxides which easily penetrate into the cells with special interest due to their higher chemical reactivity as compared to that of similar materials in the bulk form. Of particular interest are nano-TiO2 and ZnO, which have been widely used for their bactericidal and anticancerous properties. Purpose The aim of the present study was to examine the bactericidal properties of nano-TiO2 and ZnO combined with visible light on S. aureus and S. epidermitis, known for their high prevalence in infected wounds. Study Using the technique of electron-spin resonance (ESR) coupled with spin trapping, we examined the ability of TiO2 and ZnO nanoparticle suspensions in water to produce reactive oxygen species (ROS) with and without visible light irradiation. Th...
Lithium phosphorous oxynitride(Lipon) thin films as a lithium ion conductive electrolyte were prepared by radio frequency reactive sputtering in N2 plasma. The properties of the amorphous Lipon solid electrolyte were investigated as a function of N2 pressure during reactive sputtering. The ionic conductivity and the electrochemical stability of Lipon thin films improved drastically as the N2 pressure decreased. The ionic conductivity closed to 10?6 S cm?1 and obtained a stability window of 1.0?5.0 V with an N2 pressure of 5 mTorr, where the number of nitrogen bonds between the phosphate groups were more than those formed at higher pressure. It was possible to fabricate the Li//LiCoO2 complete thin film battery using this Lipon solid electrolyte, which exhibited excellent discharge characte...
A detailed chemical kinetic reaction mechanism is developed to describe incineration of the chemical warfare nerve agent sarin (GB), based on commonly used principles of bond additivity and hierarchical reaction mechanisms. The mechanism is based on previous kinetic models of organophosphorus compounds such as TMP, DMMP and DIMP that are often used as surrogates to predict incineration of GB. Kinetic models of the three surrogates and GB are then used to predict their consumption in a perfectly stirred reactor fueled by natural gas to simulate incineration of these chemicals. Computed results indicate that DIMP is the only one of these surrogates that adequately describes combustion of GB under comparable conditions. The kinetic pathways responsible for these differences in reactivity are identified and discussed. The most important reaction in GB and DIMP that makes them more reactive than TMP or DMMP is found to be a six-center molecular ...
A core-wide in-phase neutron flux oscillation, which took place, for example, at LaSalle-2 in the USA in 1988, is one of the nuclear-coupled thermal hydraulic instabilities in boiling water reactors (BWRs). In this study, an analysis has been performed focusing on the excitation of this type of instability in BWRs due to seismically induced resonance, within the scope of a point kinetics model. For this purpose, the TRAC-BF1 code has been modified to take into account the external acceleration in addition to gravity. As a result of this analysis, it is shown that reactivity insertion can occur accompanied by in-surge of the coolant into the core resulting from excitation. It is also shown that the amount of reactivity inserted largely depends on the degree of stability of the initial state and the amplitude of the seismic wave, whose frequency is the same as the characteristic frequency of the instability. (orig.).
The effect of various diallyl (diallyl ortho phthalate, diallyl terephthalate and diethylene glycol diallyl carbonate) and triallyl monomers (triallyl cyanurate and triallyl isocyanurate) on the processability of polyphenylene oxide (PPO) was studied. The solubility parameters of the monomers indicated that diallyl orthophalate, dially terephthalate and triallyl cyanurate should be miscible with PPO suggesting their applicability as reactive plasticizers to improve the processability of PPO. Rheological studies of 60:40 wt:wt PPO:allylic blends indicate that the addition of 40wt% of allylic monomers significantly improved processability - blends of 60PPO:40DEGDAC indicates the highest viscosity and the highest T"g. Rheological studies and dynamic mechanical analysis on various PPO/DAOP ble...
Biomass fly ash was treated with alkaline solution to enhance its adsorption capacity of Reactive Black 5 dye. The results revealed that the alkaline concentration, solution to fly ash ratio, treatment temperature and treatment time had a positive effect on the dye adsorption capacity of the treated fly ash (TFA), due to dissolving SiO2 and increasing the proportion of unburned carbon. In addition, the dye adsorption behavior of the TFA in aqueous solution was investigated. The effects of various experimental parameters (initial pH, initial dye concentration and contact time) were determined spectrophotometrically. The dye adsorption capacity of the TFA was maximized at an alkaline pH (8.2-10.4). The adsorption capacity of dye by the TFA increased with increasing initial dye concentration....
Methylation of the DNA bases in the Watson-Crick GC and AT base pairs by the methyldiazonium ion was investigated employing density functional and second order Moller-Plesset (MP2) perturbation theories. Methylation at the N3, N7 and O6 sites of guanine, N1, N3 and N7 sites of adenine, O2 and N3 sites of cytosine and the O2 and O4 sites of thymine were considered. The computed reactivities for methylation follow the order N7(guanine)>N3(adenine)>O6(guanine) which is in agreement with experiment. The base pairing in DNA is found to play a significant role with regard to reactivities of the different sites.